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Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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1

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case Production of Gasoline and Diesel from Biomass via Fast Pyrolysis,...

2

Catalytic fast pyrolysis of lignocellulosic biomass  

SciTech Connect (OSTI)

Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy Q3 carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectively convert lignocellulose into a liquid fuel—bio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating values, high corrosiveness, high viscosity, and instability; they also greatly Q4 limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.

Liu, Changjun; Wang, Huamin; Karim, Ayman M.; Sun, Junming; Wang, Yong

2014-11-21T23:59:59.000Z

3

Specialists' workshop on fast pyrolysis of biomass  

SciTech Connect (OSTI)

This workshop brought together most of those who are currently working in or have published significant findings in the area of fast pyrolysis of biomass or biomass-derived materials, with the goal of attaining a better understanding of the dominant mechanisms which produce olefins, oxygenated liquids, char, and tars. In addition, background papers were given in hydrocarbon pyrolysis, slow pyrolysis of biomass, and techniques for powdered-feedstock preparation in order that the other papers did not need to introduce in depth these concepts in their presentations for continuity. In general, the authors were requested to present summaries of experimental data with as much interpretation of that data as possible with regard to mechanisms and process variables such as heat flux, temperatures, partial pressure, feedstock, particle size, heating rates, residence time, etc. Separate abstracts have been prepared of each presentation for inclusion in the Energy Data Base. (DMC)

Not Available

1980-01-01T23:59:59.000Z

4

Understanding the product distribution from biomass fast pyrolysis.  

E-Print Network [OSTI]

??Fast pyrolysis of biomass is an attractive route to transform solid biomass into a liquid bio-oil, which has been envisioned as a renewable substitute for… (more)

Patwardhan, Pushkaraj Ramchandra

2010-01-01T23:59:59.000Z

5

Chemical analysis of biomass fast pyrolysis oils  

SciTech Connect (OSTI)

This paper reviews the development of the field of chemical analysis of biomass fast pyrolysis oils. The techniques applied to pyrolysis oil analysis are reviewed including proximate and ultimate analysis, water (moisture) analysis, and chemical component analysis by various forms of chromatography, solvent separations, and spectrophotometric analyses, like infrared and ultraviolet. Advanced analytical techniques such as nuclear magnetic resonance and molecular beam -- mass spectrometry are also discussed. This paper reviews and compares the methods and the results of the analyses. The advantages and shortcomings of the various methods applied are identified. Comparisons derived from the IEA Round Robin are incorporated.

Elliott, D.C.

1994-09-01T23:59:59.000Z

6

Bio-mass for biomass: biological mass spectrometry techniques for biomass fast pyrolysis oils.  

E-Print Network [OSTI]

??Biomass fast pyrolysis oils, or bio-oils, are a promising renewable energy source to supplement or replace petroleum-based products and fuels. However, there is a current… (more)

Dalluge, Erica A.

2013-01-01T23:59:59.000Z

7

Transportation fuels from biomass via fast pyrolysis and hydroprocessing  

SciTech Connect (OSTI)

Biomass is a renewable source of carbon, which could provide a means to reduce the greenhouse gas impact from fossil fuels in the transportation sector. Biomass is the only renewable source of liquid fuels, which could displace petroleum-derived products. Fast pyrolysis is a method of direct thermochemical conversion (non-bioconversion) of biomass to a liquid product. Although the direct conversion product, called bio-oil, is liquid; it is not compatible with the fuel handling systems currently used for transportation. Upgrading the product via catalytic processing with hydrogen gas, hydroprocessing, is a means that has been demonstrated in the laboratory. By this processing the bio-oil can be deoxygenated to hydrocarbons, which can be useful replacements of the hydrocarbon distillates in petroleum. While the fast pyrolysis of biomass is presently commercial, the upgrading of the liquid product by hydroprocessing remains in development, although it is moving out of the laboratory into scaled-up process demonstration systems.

Elliott, Douglas C.

2013-09-21T23:59:59.000Z

8

The effects of biomass pretreatments on the products of fast pyrolysis.  

E-Print Network [OSTI]

??Fast pyrolysis thermochemically degrades lignocellulosic material into solid char, organic liquids, and gaseous products. Using fast pyrolysis to produce renewable liquid bio-oil to replace crude… (more)

Kasparbauer, Randall Dennis

2009-01-01T23:59:59.000Z

9

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case  

SciTech Connect (OSTI)

The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using similar methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The "as received" feedstock to the pyrolysis plant will be "reactor ready". This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps: feed prep, fast pyrolysis, and upgrading. Stabilized, upgraded pyrolysis oil is transferred to the refinery for separation and finishing into motor fuels. The off-gas from the hydrotreaters is also transferred to the refinery, and in return the refinery provides lower-cost hydrogen for the hydrotreaters. This reduces the capital investment. Production costs near $2/gal (in 2007 dollars) and petroleum industry infrastructure-ready products make the production and upgrading of pyrolysis oil to hydrocarbon fuels an economically attractive source of renewable fuels. The study also identifies technical areas where additional research can potentially lead to further cost improvements.

Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

2009-02-25T23:59:59.000Z

10

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case  

SciTech Connect (OSTI)

The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using the same methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The “as received” feedstock to the pyrolysis plant will be “reactor ready.” This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps: feed prep, fast pyrolysis, and upgrading. Stabilized, upgraded pyrolysis oil is transferred to the refinery for separation and finishing into motor fuels. The off-gas from the hydrotreaters is also transferred to the refinery, and in return the refinery provides lower-cost hydrogen for the hydrotreaters. This reduces the capital investment. Production costs near $2/gal (in 2007 dollars) and petroleum industry infrastructure-ready products make the production and upgrading of pyrolysis oil to hydrocarbon fuels an economically attractive source of renewable fuels. The study also identifies technical areas where additional research can potentially lead to further cost improvements.

Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

2009-02-28T23:59:59.000Z

11

Biomass pyrolysis for chemicals.  

E-Print Network [OSTI]

??Biomass Pyrolysis for Chemicals The problems associated with the use of fossil fuels demand a transition to renewable sources (sun, wind, water, geothermal, biomass) for… (more)

Wild, Paul de

2011-01-01T23:59:59.000Z

12

BIOMASS PRETREATMENT FOR INCREASED ANHYDROSUGARS YIELD DURING FAST PYROLYSIS.  

E-Print Network [OSTI]

??Production of liquid fuels is a high national priority to provide transporation fuels. Production of liquid bio-fuels from biomass has been idenfied as a viable… (more)

Li, Qi

2009-01-01T23:59:59.000Z

13

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: 2011 State of Technology and Projections to 2017  

SciTech Connect (OSTI)

Review of the the status of DOE funded research for converting biomass to liquid transportation fuels via fast pyrolysis and hydrotreating for fiscal year 2011.

Jones, Susanne B.; Male, Jonathan L.

2012-02-01T23:59:59.000Z

14

Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and Hydroprocessing In fast pyrolysis and hydrotreating, biomass is rapidly heated in a fluidized bed to create...

15

Resole resin products derived from fractionated organic and aqueous condensates made by fast-pyrolysis of biomass materials  

DOE Patents [OSTI]

A process for preparing phenol-formaldehyde resole resins by fractionating organic and aqueous condensates made by fast-pyrolysis of biomass materials while using a carrier gas to move feed into a reactor to produce phenolic-containing/neutrals in which portions of the phenol normally contained in said resins are replaced by a phenolic/neutral fractions extract obtained by fractionation.

Chum, Helena L. (8448 Allison Ct., Arvada, CO 80005); Black, Stuart K. (4976 Raleigh St., Denver, CO 80212); Diebold, James P. (57 N. Yank Way, Lakewood, CO 80228); Kreibich, Roland E. (4201 S. 344th, Auburn, WA 98001)

1993-01-01T23:59:59.000Z

16

Resole resin products derived from fractionated organic and aqueous condensates made by fast-pyrolysis of biomass materials  

DOE Patents [OSTI]

A process for preparing phenol-formaldehyde resole resins by fractionating organic and aqueous condensates made by fast-pyrolysis of biomass materials while using a carrier gas to move feed into a reactor to produce phenolic-containing/neutrals in which portions of the phenol normally contained in said resins are replaced by a phenolic/neutral fractions extract obtained by fractionation.

Chum, H.L.; Black, S.K.; Diebold, J.P.; Kreibich, R.E.

1993-08-10T23:59:59.000Z

17

Design, optimization and evaluation of a free-fall biomass fast pyrolysis reactor and its products.  

E-Print Network [OSTI]

??The focus of this work is a radiatively heated, free-fall, fast pyrolysis reactor. The reactor was designed and constructed for the production of bio-oil from… (more)

Ellens, Cody James

2009-01-01T23:59:59.000Z

18

Catalytic Hydroprocessing of Biomass Fast Pyrolysis Bio-oil to Produce Hydrocarbon Products  

SciTech Connect (OSTI)

Catalytic hydroprocessing has been applied to biomass fast pyrolysis liquid product (bio-oil) in a bench-scale continuous-flow fixed-bed reactor system. The intent of the research was to develop process technology to convert the bio-oil into a petroleum refinery feedstock to supplement fossil energy resources and to displace imported feedstock. The project was a cooperative research and development agreement among UOP LLC, the National Renewable Energy Laboratory and the Pacific Northwest National Laboratory (PNNL). This paper is focused on the process experimentation and product analysis undertaken at PNNL. The paper describes the experimental methods used and relates the results of the product analyses. A range of catalyst formulations were tested over a range of operating parameters including temperature, pressure, and flow-rate with bio-oil derived from several different biomass feedstocks. Effects of liquid hourly space velocity and catalyst bed temperature were assessed. Details of the process results were presented including mass and elemental balances. Detailed analysis of the products were provided including elemental composition, chemical functional type determined by mass spectrometry, and product descriptors such as density, viscosity and Total Acid Number (TAN). In summation, the paper provides an understanding of the efficacy of hydroprocessing as applied to bio-oil.

Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Zacher, Alan H.

2009-10-01T23:59:59.000Z

19

Experimental Investigation of the Effects of Fuel Aging on Combustion Performance and Emissions of Biomass Fast Pyrolysis Liquid-Ethanol Blends in a Swirl Burner.  

E-Print Network [OSTI]

??Biomass fast pyrolysis liquid is a renewable fuel for stationary heat and power generation; however degradation of bio-oil by time, a.k.a. aging, has an impact… (more)

Zarghami-Tehran, Milad

2012-01-01T23:59:59.000Z

20

Experimental Investigation of the Effects of Fuel Properties on Combustion Performance and Emissions of Biomass Fast Pyrolysis Liquid-ethanol Blends in a Swirl Burner.  

E-Print Network [OSTI]

??Biomass fast pyrolysis liquid, also known as bio-oil, is a promising renewable fuel for heat and power generation; however, implementing crude bio-oil in some current… (more)

Moloodi, Sina

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions  

SciTech Connect (OSTI)

Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some potential for blending into finished fuels. Fractions from the lowest oxygen content oil exhibited some phenolic acidity, but generally contained very low levels of oxygen functional groups. These materials would likely be suitable as refinery feedstocks and potentially as fuel blend components. PIONA analysis of the Light and Naphtha fractions shows benzene content of 0.5 and 0.4 vol%, and predicted (RON + MON)/2 of 63 and 70, respectively.

Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

2011-10-06T23:59:59.000Z

22

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-Oil Pathway  

SciTech Connect (OSTI)

This report describes a proposed thermochemical process for converting biomass into liquid transportation fuels via fast pyrolysis followed by hydroprocessing of the condensed pyrolysis oil. As such, the analysis does not reflect the current state of commercially-available technology but includes advancements that are likely, and targeted to be achieved by 2017. The purpose of this study is to quantify the economic impact of individual conversion targets to allow a focused effort towards achieving cost reductions.

Jones, Susanne B.; Meyer, Pimphan A.; Snowden-Swan, Lesley J.; Padmaperuma, Asanga B.; Tan, Eric; Dutta, Abhijit; Jacobson, Jacob; Cafferty, Kara

2013-11-01T23:59:59.000Z

23

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-oil Pathway  

SciTech Connect (OSTI)

This report describes a proposed thermochemical process for converting biomass into liquid transportation fuels via fast pyrolysis followed by hydroprocessing of the condensed pyrolysis oil. As such, the analysis does not reflect the current state of commercially-available technology but includes advancements that are likely, and targeted to be achieved by 2017. The purpose of this study is to quantify the economic impact of individual conversion targets to allow a focused effort towards achieving cost reductions.

Jones, S.; Meyer, P.; Snowden-Swan, L.; Padmaperuma, A.; Tan, E.; Dutta, A.; Jacobson, J.; Cafferty, K.

2013-11-01T23:59:59.000Z

24

APPLICATION OF PYROLYSIS-GC/MS TO THE STUDY OF BIOMASS AND BIOMASS CONSTITUENTS.  

E-Print Network [OSTI]

??Fast pyrolysis, the rapid thermal decomposition of organic material in the absence of oxygen, is a process that can be used to convert biomass into… (more)

Ware, Anne E

2013-01-01T23:59:59.000Z

25

Experimental investigation into fast pyrolysis of biomass using an entrained-flow reactor  

SciTech Connect (OSTI)

Pyrolysis experiments were performed using 30 and 90cm entrained-flow reactors, with steam as a carrier gas and two different feedstocks - wheat straw and powdered material drived from municipal solid waste (ECO-II TM). Reactor wall temperature was varied from 700/sup 0/ to 1400/sup 0/C. Gas composition data from the ECO-II tests were comparable to previously reported data but ethylene yield appeared to vary with reactor wall temperature and residence time. The important conclusion from the wheat straw tests is that olefin yields are about one half that obtained from ECO-II. Evidence was found that high olefin yields from ECO-II are due to the presence of plastics in the feedstock. Batch experiments were run on wheat straw using a Pyroprobe/sup TM/. The samples were heated at a high rate (20,000/sup 0/ C/sec) to 1000/sup 0/ and held at 1000/sup 0/C for a variable period of time from 0.05 to 4.95s. For times up to 0.15s volume fractions of ethylene, propylene, and methane increase while that of carbon dioxide decreases. Subsequently, only carbon monoxide and hydrogen are produced. The change may be related to poor thermal contact and suggests caution in using the Pyroprobe.

Bohn, M.; Benham, C.

1981-02-01T23:59:59.000Z

26

The best use of biomass? Greenhouse gas lifecycle analysis of predicted pyrolysis biochar systems   

E-Print Network [OSTI]

to pessimistic scenarios are used for system operation. Slow pyrolysis is compared to fast pyrolysis and biomass co-firing for GHG abatement and electricity production, using various scenarios for availability of indigenous Scottish feedstocks....

Hammond, James A R

2009-01-01T23:59:59.000Z

27

Feedstock Supply System Design and Economics for Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels Conversion Pathway: Fast Pyrolysis and Hydrotreating Bio-Oil Pathway "The 2017 Design Case"  

SciTech Connect (OSTI)

The U.S. Department of Energy promotes the production of liquid fuels from lignocellulosic biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass sustainable supply, logistics, conversion, and overall system sustainability. As part of its involvement in this program, Idaho National Laboratory (INL) investigates the feedstock logistics economics and sustainability of these fuels. Between 2000 and 2012, INL quantified and the economics and sustainability of moving biomass from the field or stand to the throat of the conversion process using conventional equipment and processes. All previous work to 2012 was designed to improve the efficiency and decrease costs under conventional supply systems. The 2012 programmatic target was to demonstrate a biomass logistics cost of $55/dry Ton for woody biomass delivered to fast pyrolysis conversion facility. The goal was achieved by applying field and process demonstration unit-scale data from harvest, collection, storage, preprocessing, handling, and transportation operations into INL’s biomass logistics model.

Kevin L. Kenney; Kara G. Cafferty; Jacob J. Jacobson; Ian J. Bonner; Garold L. Gresham; J. Richard Hess; William A. Smith; David N. Thompson; Vicki S. Thompson; Jaya Shankar Tumuluru; Neal Yancey

2014-01-01T23:59:59.000Z

28

Lignin Fast Pyrolysis: Results from an International Collaboration  

SciTech Connect (OSTI)

An international study of fast pyrolysis of lignin was undertaken. Fourteen laboratories in eight different countries contributed. Two lignin samples were distributed to the laboratories for analysis and bench-scale process testing in fast pyrolysis. Analyses included proximate and ultimate analysis, thermogravimetric analysis, and analytical pyrolysis. The bench-scale test included bubbling fluidized bed reactors and entrained flow systems. Based on the results of the various analyses and tests it was concluded that a concentrated lignin (estimated at about 50% lignin and 50% cellulose) behaved like a typical biomass, producing a slightly reduced amount of a fairly typical bio-oil, while a purified lignin material was difficult to process in the fast pyrolysis reactors and produced a much lower amount of a different kind of bio-oil. It was concluded that for highly concentrated lignin feedstocks new reactor designs will be required other than the typical fluidized bed fast pyrolysis systems.

Nowakowski, Daniel J.; Bridgwater, Anthony V.; Elliott, Douglas C.; Meier, Dietrich; de Wild, Paul

2010-05-01T23:59:59.000Z

29

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

30

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

31

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: 2012 State of Technology and Projections to 2017  

SciTech Connect (OSTI)

This report summarizes the economic impact of the work performed at PNNL during FY12 to improve fast pyrolysis oil upgrading via hydrotreating. A comparison is made between the projected economic outcome and the actual results based on experimental data. Sustainability metrics are also included.

Jones, Susanne B.; Snowden-Swan, Lesley J.

2013-08-27T23:59:59.000Z

32

Stabilization of Fast Pyrolysis Oil: Post Processing Final Report  

SciTech Connect (OSTI)

UOP LLC, a Honeywell Company, assembled a comprehensive team for a two-year project to demonstrate innovative methods for the stabilization of pyrolysis oil in accordance with DOE Funding Opportunity Announcement (FOA) DE-PS36-08GO98018, Biomass Fast Pyrolysis Oil (Bio-oil) Stabilization. In collaboration with NREL, PNNL, the USDA Agricultural Research Service (ARS), Pall Fuels and Chemicals, and Ensyn Corporation, UOP developed solutions to the key technical challenges outlined in the FOA. The UOP team proposed a multi-track technical approach for pyrolysis oil stabilization. Conceptually, methods for pyrolysis oil stabilization can be employed during one or both of two stages: (1) during the pyrolysis process (In Process); or (2) after condensation of the resulting vapor (Post-Process). Stabilization methods fall into two distinct classes: those that modify the chemical composition of the pyrolysis oil, making it less reactive; and those that remove destabilizing components from the pyrolysis oil. During the project, the team investigated methods from both classes that were suitable for application in each stage of the pyrolysis process. The post processing stabilization effort performed at PNNL is described in this report. The effort reported here was performed under a CRADA between PNNL and UOP, which was effective on March 13, 2009, for 2 years and was subsequently modified March 8, 2011, to extend the term to December 31, 2011.

Elliott, Douglas C.; Lee, Suh-Jane; Hart, Todd R.

2012-03-01T23:59:59.000Z

33

Biomass Feedstocks for Renewable Fuel Production: A review of the impacts of feedstock and pretreatment on the yield and product distribution of fast pyrolysis bio-oils and vapors  

SciTech Connect (OSTI)

Renewable transportation fuels from biomass have the potential to substantially reduce greenhouse gas emissions and diversify global fuel supplies. Thermal conversion by fast pyrolysis converts up to 75% of the starting plant material (and its energy content) to a bio-oil intermediate suitable for upgrading to motor fuel. Woody biomass, by far the most widely-used and researched material, is generally preferred in thermochemical processes due to its low ash content and high quality bio-oil produced. However, the availability and cost of biomass resources, e.g. forest residues, agricultural residues, or dedicated energy crops, vary greatly by region and will be key determinates in the overall economic feasibility of a pyrolysis-to-fuel process. Formulation or blending of various feedstocks, combined with thermal and/or chemical pretreatment, could facilitate a consistent, high-volume, lower-cost biomass supply to an emerging biofuels industry. However, the impact of biomass type and pretreatment conditions on bio-oil yield and quality, and the potential process implications, are not well understood. This literature review summarizes the current state of knowledge regarding the effect of feedstock and pretreatments on the yield, product distribution, and upgradability of bio-oil.

Daniel Carpenter; Stefan Czernik; Whitney Jablonski; Tyler L. Westover

2014-02-01T23:59:59.000Z

34

Fluidized bed pyrolysis of terrestrial biomass feedstocks  

SciTech Connect (OSTI)

Hybrid poplar, switchgrass, and corn stover were pyrolyzed in a bench scale fluidized-bed reactor to examine the influence of storage time on thermochemical converting of these materials. The influence of storage on the thermochemical conversion of the biomass feedstocks was assessed based on pyrolysis product yields and chemical and instrumental analyses of the pyrolysis products. Although char and gas yields from corn stover feedstock were influenced by storage time, hybrid poplar and switchgrass were not significantly affected. Liquid, char, and gas yields were feedstock dependent. Total liquid yields (organic+water) varied from 58%-73% depending on the feedstock. Char yields varied from 14%-19% while gas yields ranged from 11%-15%. The chemical composition of the pyrolysis oils from hybrid polar feedstock was slightly changed by storage, however, corn stover and switchgrass feedstock showed no significant changes. Additionally, stored corn stover and hybrid poplar pyrolysis oils showed a significant decrease in their higher heating values compared to the fresh material.

Besler, S.; Agblevor, F.A.; Davis, M.F. [National Renewable Energy Lab., Golden, CO (United States)] [and others

1994-12-31T23:59:59.000Z

35

Hydrocarbon Liquid Production from Biomass via Hot-Vapor-Filtered Fast Pyrolysis and Catalytic Hydroprocessing of the Bio-oil  

SciTech Connect (OSTI)

Hot-vapor filtered bio-oils were produced from two different biomass feedstocks, oak and switchgrass, and the oils were evaluated in hydroprocessing tests for production of liquid hydrocarbon products. Hot-vapor filtering reduced bio-oil yields and increased gas yields. The yields of fuel carbon as bio-oil were reduced by ten percentage points by hot-vapor filtering for both feedstocks. The unfiltered bio-oils were evaluated alongside the filtered bio-oils using a fixed bed catalytic hydrotreating test. These tests showed good processing results using a two-stage catalytic hydroprocessing strategy. Equal-sized catalyst beds, a sulfided Ru on carbon catalyst bed operated at 220°C and a sulfided CoMo on alumina catalyst bed operated at 400°C were used with the entire reactor at 100 atm operating pressure. The products from the four tests were similar. The light oil phase product was fully hydrotreated so that nitrogen and sulfur were below the level of detection, while the residual oxygen ranged from 0.3 to 2.0%. The density of the products varied from 0.80 g/ml up to 0.86 g/ml over the period of the test with a correlated change of the hydrogen to carbon atomic ratio from 1.79 down to 1.57, suggesting some loss of catalyst activity through the test. These tests provided the data needed to assess the suite of liquid fuel products from the process and the activity of the catalyst in relationship to the existing catalyst lifetime barrier for the technology.

Elliott, Douglas C.; Wang, Huamin; French, Richard; Deutch, Steve; Iisa, Kristiina

2014-08-14T23:59:59.000Z

36

Fast Pyrolysis Conversion Tests of Forest Concepts’ Crumbles.  

SciTech Connect (OSTI)

The report describes the work done by PNNL on assessing Forest Concept's engineered feedstock using the bench-scale continuous fast pyrolysis system to produce liquid bio-oil, char and gas. Specifically, bio-oil from the following process were evaluated for its yield and quality to determine impact of varying feed size parameters. Furthermore, the report also describes the handling process of the biomass and the challenges of operating the system with above average particle size.

Santosa, Daniel M.; Zacher, Alan H.; Eakin, David E.

2012-04-02T23:59:59.000Z

37

Evaluation of Catalysts from Different Origin for Vapor Phase Upgrading in Biomass Pyrolysis  

SciTech Connect (OSTI)

Liquid fuels and chemicals from biomass resources arouse much interests in research and development. Fast pyrolysis of biomass has the potential to effectively change solid biomass materials into liquid products. However, bio-oil from traditional pyrolysis processes is difficult to apply in industry, because of its complicated composition, high oxygen content, low stability, etc. Upgrading or refining of the bio-oil should be performed for industrial application of biomass pyrolysis. Often, the process would be done in a separate reactor downstream of the pyrolysis process. In this paper, a laboratory scale micro test facility was constructed, wherein the pyrolysis of pine and catalytic upgrading of the resulting vapors were closely coupled in one reactor. The composition of vapor effluent was monitored with a molecular beam mass spectrometer (MBMS) for the online evaluation of the catalyst performance. Catalysts from different origin were tested and compared for the effectiveness of pyrolysis vapor upgrading, namely commercial zeolites, Ni based steam reforming catalyst, CaO, MgO, and several laboratory-made catalysts. The reaction temperature for catalytic upgrading varied between 400 and 600 centigrade, and the gaseous residence time ranged from 0.1 second to above 2 second, to simulate the conditions in industrial application. It is revealed that some catalysts are active in transform most of primary biomass pyrolysis vapors into hydrocarbons, resulting in nonoxygenated products, which is beneficial for downstream utilization. Others are not as effective, results in minor improvement compared with blank test results.

Zhang, X.; Mukarakate, C.; Zheng, Z.; Nimlos, M.

2012-01-01T23:59:59.000Z

38

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS  

E-Print Network [OSTI]

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS Kimberly established that biomass pyrolysis oil could be steam-reformed to generate hydrogen using non pyrolysis oil could be almost stoichiometrically converted to hydrogen. However, process performance

39

INTEGRATED PYROLYSIS COMBINED CYCLE BIOMASS POWER SYSTEM CONCEPT DEFINITION  

SciTech Connect (OSTI)

Advanced power systems based on integrated gasification/combined cycles (IGCC) are often presented as a solution to the present shortcomings of biomass as fuel. Although IGCC has been technically demonstrated at full scale, it has not been adopted for commercial power generation. Part of the reason for this situation is the continuing low price for coal. However, another significant barrier to IGCC is the high level of integration of this technology: the gas output from the gasifier must be perfectly matched to the energy demand of the gas turbine cycle. We are developing an alternative to IGCC for biomass power: the integrated (fast) pyrolysis/ combined cycle (IPCC). In this system solid biomass is converted into liquid rather than gaseous fuel. This liquid fuel, called bio-oil, is a mixture of oxygenated organic compounds and water that serves as fuel for a gas turbine topping cycle. Waste heat from the gas turbine provides thermal energy to the steam turbine bottoming cycle. Advantages of the biomass-fueled IPCC system include: combined cycle efficiency exceeding 37 percent efficiency for a system as small as 7.6 MW{sub e}; absence of high pressure thermal reactors; decoupling of fuel processing and power generation; and opportunities for recovering value-added products from the bio-oil. This report provides a technical overview of the system including pyrolyzer design, fuel clean-up strategies, pyrolysate condenser design, opportunities for recovering pyrolysis byproducts, gas turbine cycle design, and Rankine steam cycle. The report also reviews the potential biomass fuel supply in Iowa, provide and economic analysis, and present a summery of benefits from the proposed system.

Eric Sandvig; Gary Walling; Robert C. Brown; Ryan Pletka; Desmond Radlein; Warren Johnson

2003-03-01T23:59:59.000Z

40

Fuel and fuel blending components from biomass derived pyrolysis oil  

DOE Patents [OSTI]

A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

2012-12-11T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Study of the mechanism of pyrolysis and gasification of Mallee biomass.  

E-Print Network [OSTI]

??Mechanisms of pyrolysis/gasification (steam and carbon dioxide) of mallee biomass were investigated. Wood biochar obtained under slow pyrolysis kept botanical structure but lost its original… (more)

Yang, Yanwu

2012-01-01T23:59:59.000Z

42

Combustion Properties of Biomass Flash Pyrolysis Oils: Final Project Report  

SciTech Connect (OSTI)

Thermochemical pyrolysis of solid biomass feedstocks, with subsequent condensation of the pyrolysis vapors, has been investigated in the U.S. and internationally as a means of producing a liquid fuel for power production from biomass. This process produces a fuel with significantly different physical and chemical properties from traditional petroleum-based fuel oils. In addition to storage and handling difficulties with pyrolysis oils, concern exists over the ability to use this fuel effectively in different combustors. The report endeavors to place the results and conclusions from Sandia's research into the context of international efforts to utilize pyrolysis oils. As a special supplement to this report, Dr. Steven Gust, of Finland's Neste Oy, has provided a brief assessment of pyrolysis oil combustion research efforts and commercialization prospects in Europe.

C. R. Shaddix; D. R. Hardesty

1999-04-01T23:59:59.000Z

43

A review of the toxicity of biomass pyrolysis liquids formed at low temperatures  

SciTech Connect (OSTI)

The scaleup of biomass fast pyrolysis systems to large pilot and commercial scales will expose an increasingly large number of personnel to potential health hazards, especially during the evaluation of the commercial use of the pyrolysis condensates. Although the concept of fast pyrolysis to optimize liquid products is relatively new, low-temperature pyrolysis processes have been used over the aeons to produce charcoal and liquid by-products, e.g., smoky food flavors, food preservatives, and aerosols containing narcotics, e.g., nicotine. There are a number of studies in the historical literature that concern the hazards of acute and long-term exposure to smoke and to the historical pyrolysis liquids formed at low temperatures. The reported toxicity of smoke, smoke food flavors, and fast pyrolysis oils is reviewed. The data found for these complex mixtures suggest that the toxicity may be less than that of the individual components. It is speculated that there may be chemical reactions that take place that serve to reduce the toxicity during aging. 81 refs.

Diebold, J.P. [Thermalchemie, Inc., Lakewood, CO (United States)

1997-04-01T23:59:59.000Z

44

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline , diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

45

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

46

"Optimization of Zero Length Chromatographic System and Measuring Properties of Model Compounds from Biomass Pyrolysis"  

E-Print Network [OSTI]

Compounds from Biomass Pyrolysis" Ross Kendall Faculty Mentor: Dr. Paul Dauenhauer, Chemical Engineering by using what he made to measure many of the compounds involved in biomass pyrolysis. If we can understand to retrieve diffusion coefficients of many intermediates of the biomass pyrolysis reaction. From this data

Mountziaris, T. J.

47

Low oxygen biomass-derived pyrolysis oils and methods for producing the same  

SciTech Connect (OSTI)

Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

2013-08-27T23:59:59.000Z

48

State-of-the-Art of Fast Pyrolysis in IEA Bioenergy Member Countries  

SciTech Connect (OSTI)

Fast pyrolysis of biomass is becoming increasingly important in some member countries of the International Energy Agency(IEA). Six countries have joined the IEA Task 34 of the Bioenergy Activity: Canada, Finland, Germany, Netherlands, UK, and USA. The National Task Leaders give an overview of the current activities in their countries both on research, pilot and demonstration level.

Meier, Dietrich; van de Beld, Bert; Bridgwater, Anthony V.; Elliott, Douglas C.; Oasmaa, Anja; Preto, Fernando

2013-04-01T23:59:59.000Z

49

Total Acid Value Titration of Hydrotreated Biomass Fast Pyrolysis Oil: Determination of Carboxylic Acids and Phenolics with Multiple End-Point Detection  

SciTech Connect (OSTI)

Total acid value titration has long been used to estimate corrosive potential of petroleum crude oil and fuel oil products. The method commonly used for this measurement, ASTM D664, utilizes KOH in isopropanol as the titrant with potentiometric end point determination by pH sensing electrode and Ag/AgCl reference electrode with LiCl electrolyte. A natural application of the D664 method is titration of pyrolysis-derived bio-oil, which is a candidate for refinery upgrading to produce drop in fuels. Determining the total acid value of pyrolysis derived bio-oil has proven challenging and not necessarily amenable to the methodology employed for petroleum products due to the different nature of acids present. We presented an acid value titration for bio-oil products in our previous publication which also utilizes potentiometry using tetrabutylammonium hydroxide in place of KOH as the titrant and tetraethylammonium bromide in place of LiCl as the reference electrolyte to improve the detection of these types of acids. This method was shown to detect numerous end points in samples of bio-oil that were not detected by D664. These end points were attributed to carboxylic acids and phenolics based on the results of HPLC and GC-MS studies. Additional work has led to refinement of the method and it has been established that both carboxylic acids and phenolics can be determined accurately. Use of pH buffer calibration to determine half-neutralization potentials of acids in conjunction with the analysis of model compounds has allowed us to conclude that this titration method is suitable for the determination of total acid value of pyrolysis oil and can be used to differentiate and quantify weak acid species. The measurement of phenolics in bio-oil is subject to a relatively high limit of detection, which may limit the utility of titrimetric methodology for characterizing the acidic potential of pyrolysis oil and products.

Christensen, E.; Alleman, T. L.; McCormick, R. L.

2013-01-01T23:59:59.000Z

50

Pyrolysis and ignition behavior of coal, cattle biomass, and coal/cattle biomass blends  

E-Print Network [OSTI]

derived from biomass. Current research at Texas A&M University is focused on the effectiveness of using cattle manure biomass as a fuel source in conjunction with coal burning utilities. The scope of this project includes fuel property analysis, pyrolysis...

Martin, Brandon Ray

2009-05-15T23:59:59.000Z

51

Detailed kinetic study of anisole pyrolysis and oxidation to understand tar formation during biomass  

E-Print Network [OSTI]

biomass combustion and gasification Milena Nowakowska, Olivier Herbinet, Anthony Dufour, Pierre. Methoxyphenols are one of the main precursors of PAH and soot in biomass combustion and gasification. Keywords: Anisole; Pyrolysis; Oxidation; Tars; Biomass; Kinetic modeling Corresponding author

Paris-Sud XI, Université de

52

Biomass pyrolysis processes: performance parameters and their influence on biochar system benefits   

E-Print Network [OSTI]

This study focuses on performance of biomass pyrolysis processes for use in biochar systems. Objectives are to understand the range of control of such processes and how this affects potential benefits of pyrolysis biochar ...

Brownsort, Peter A

2009-01-01T23:59:59.000Z

53

Autothermal oxidative pyrolysis of biomass feedstocks over noble metal catalysts to liquid products.  

E-Print Network [OSTI]

??Two thermal processing technologies have emerged for processing biomass into renewable liquid products: pyrolysis and gasification/Fischer-Tropsch processing. The work presented here will demonstrate oxidative pyrolysis… (more)

Balonek, Christine Marie

2011-01-01T23:59:59.000Z

54

Flash pyrolysis and hydropyrolysis of biomass  

SciTech Connect (OSTI)

Process chemistry data on the flash pyrolysis and hydropyrolysis of wood is being obtained in a 1'' downflow entrained tubular reactor. The data indicates that at residence times of <1 second, and 900 to 1000/sup 0/C and 500 psi pressure, the flash hydropyrolysis of wood yields mainly methane and water. As the residence time increases to >3 seconds, the products are methane and CO. Almost complete conversion of the carbon to methane and CO are obtained in these experiments. At lower temperatures, in the order of 800/sup 0/C, 500 psi and residence times <4 seconds, significant amounts of benzene and ethane are produced. The experimental process chemistry data have been used to design and evaluate two processes in a preliminary manner. One process converts wood to high BTU pipeline gas and the other to methanol and chemical feedstocks consisting of benzene and ethylene. Reasonable plant investments which compare favorably with coal conversion plant estimates are derived.

Not Available

1982-08-01T23:59:59.000Z

55

Biomass pyrolysis processes: performance parameters and their influence on biochar system benefits.  

E-Print Network [OSTI]

??This study focuses on performance of biomass pyrolysis processes for use in biochar systems. Objectives are to understand the range of control of such processes… (more)

Brownsort, Peter A

2009-01-01T23:59:59.000Z

56

Summary of Fast Pyrolysis and Upgrading GHG Analyses  

SciTech Connect (OSTI)

The Energy Independence and Security Act (EISA) of 2007 established new renewable fuel categories and eligibility requirements (EPA 2010). A significant aspect of the National Renewable Fuel Standard 2 (RFS2) program is the requirement that the life cycle greenhouse gas (GHG) emissions of a qualifying renewable fuel be less than the life cycle GHG emissions of the 2005 baseline average gasoline or diesel fuel that it replaces. Four levels of reduction are required for the four renewable fuel standards. Table 1 lists these life cycle performance improvement thresholds. Table 1. Life Cycle GHG Thresholds Specified in EISA Fuel Type Percent Reduction from 2005 Baseline Renewable fuel 20% Advanced biofuel 50% Biomass-based diesel 50% Cellulosic biofuel 60% Notably, there is a specialized subset of advanced biofuels that are the cellulosic biofuels. The cellulosic biofuels are incentivized by the Cellulosic Biofuel Producer Tax Credit (26 USC 40) to stimulate market adoption of these fuels. EISA defines a cellulosic biofuel as follows (42 USC 7545(o)(1)(E)): The term “cellulosic biofuel” means renewable fuel derived from any cellulose, hemicellulose, or lignin that is derived from renewable biomass and that has lifecycle greenhouse gas emissions, as determined by the Administrator, that are at least 60 percent less than the baseline lifecycle greenhouse gas emissions. As indicated, the Environmental Protection Agency (EPA) has sole responsibility for conducting the life cycle analysis (LCA) and making the final determination of whether a given fuel qualifies under these biofuel definitions. However, there appears to be a need within the LCA community to discuss and eventually reach consensus on discerning a 50–59 % GHG reduction from a ? 60% GHG reduction for policy, market, and technology development. The level of specificity and agreement will require additional development of capabilities and time for the sustainability and analysis community, as illustrated by the rich dialogue and convergence around the energy content and GHG reduction of cellulosic ethanol (an example of these discussions can be found in Wang 2011). GHG analyses of fast pyrolysis technology routes are being developed and will require significant work to reach the levels of development and maturity of cellulosic ethanol models. This summary provides some of the first fast pyrolysis analyses and clarifies some of the reasons for differing results in an effort to begin the convergence on assumptions, discussion of quality of models, and harmonization.

Snowden-Swan, Lesley J.; Male, Jonathan L.

2012-12-07T23:59:59.000Z

57

Life Cycle Assessment of Gasoline and Diesel Produced via Fast Pyrolysis and Hydroprocessing  

SciTech Connect (OSTI)

In this work, a life cycle assessment (LCA) estimating greenhouse gas (GHG) emissions and net energy value (NEV) of the production of gasoline and diesel from forest residues via fast pyrolysis and hydroprocessing, from production of the feedstock to end use of the fuel in a vehicle, is performed. The fast pyrolysis and hydrotreating and hydrocracking processes are based on a Pacific Northwest National Laboratory (PNNL) design report. The LCA results show GHG emissions of 0.142 kg CO2-equiv. per km traveled and NEV of 1.00 MJ per km traveled for a process using grid electricity. Monte Carlo uncertainty analysis shows a range of results, with all values better than those of conventional gasoline in 2005. Results for GHG emissions and NEV of gasoline and diesel from pyrolysis are also reported on a per MJ fuel basis for comparison with ethanol produced via gasification. Although pyrolysis-derived gasoline and diesel have lower GHG emissions and higher NEV than conventional gasoline does in 2005, they underperform ethanol produced via gasification from the same feedstock. GHG emissions for pyrolysis could be lowered further if electricity and hydrogen are produced from biomass instead of from fossil sources.

Hsu, D. D.

2011-03-01T23:59:59.000Z

58

A component based model for the prediction of the product yields of the pyrolysis of a biomass particle.  

E-Print Network [OSTI]

??Pyrolysis of biomass can produce several useful, renewable products: biochar for soil amendment and long-term carbon sequestration; tars for chemicals and biofuels; and syngas as… (more)

Eberly, Brian C.

2010-01-01T23:59:59.000Z

59

Modelling and experimental studies of biomass and organic pyrolysis.  

E-Print Network [OSTI]

??Pyrolysis is a thermal conversion process that decomposes organic materials into liquid hydrocarbons, carbonaceous residues and combustible gases in the absence of oxygen. Depending on… (more)

Lam, Ka Leung

2012-01-01T23:59:59.000Z

60

Co-pyrolysis of low rank coals and biomass: Product distributions  

SciTech Connect (OSTI)

Pyrolysis and gasification of combined low rank coal and biomass feeds are the subject of much study in an effort to mitigate the production of green house gases from integrated gasification combined cycle (IGCC) systems. While co-feeding has the potential to reduce the net carbon footprint of commercial gasification operations, the effects of co-feeding on kinetics and product distributions requires study to ensure the success of this strategy. Southern yellow pine was pyrolyzed in a semi-batch type drop tube reactor with either Powder River Basin sub-bituminous coal or Mississippi lignite at several temperatures and feed ratios. Product gas composition of expected primary constituents (CO, CO{sub 2}, CH{sub 4}, H{sub 2}, H{sub 2}O, and C{sub 2}H{sub 4}) was determined by in-situ mass spectrometry while minor gaseous constituents were determined using a GC-MS. Product distributions are fit to linear functions of temperature, and quadratic functions of biomass fraction, for use in computational co-pyrolysis simulations. The results are shown to yield significant nonlinearities, particularly at higher temperatures and for lower ranked coals. The co-pyrolysis product distributions evolve more tar, and less char, CH{sub 4}, and C{sub 2}H{sub 4}, than an additive pyrolysis process would suggest. For lignite co-pyrolysis, CO and H{sub 2} production are also reduced. The data suggests that evolution of hydrogen from rapid pyrolysis of biomass prevents the crosslinking of fragmented aromatic structures during coal pyrolysis to produce tar, rather than secondary char and light gases. Finally, it is shown that, for the two coal types tested, co-pyrolysis synergies are more significant as coal rank decreases, likely because the initial structure in these coals contains larger pores and smaller clusters of aromatic structures which are more readily retained as tar in rapid co-pyrolysis.

Soncini, Ryan M.; Means, Nicholas C.; Weiland, Nathan T.

2013-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Preparation of brightness stabilization agent for lignin containing pulp from biomass pyrolysis oils  

DOE Patents [OSTI]

A process for producing a brightness stabilization mixture of water-soluble organic compounds from biomass pyrolysis oils comprising: a) size-reducing biomass material and pyrolyzing the size-reduced biomass material in a fluidized bed reactor; b) separating a char/ash component while maintaining char-pot temperatures to avoid condensation of pyrolysis vapors; c) condensing pyrolysis gases and vapors, and recovering pyrolysis oils by mixing the oils with acetone to obtain an oil-acetone mixture; d) evaporating acetone and recovering pyrolysis oils; e) extracting the pyrolysis oils with water to obtain a water extract; f) slurrying the water extract with carbon while stirring, and filtering the slurry to obtain a colorless filtrate; g) cooling the solution and stabilizing the solution against thermally-induced gelling and solidification by extraction with ethyl acetate to form an aqueous phase lower layer and an organic phase upper layer; h) discarding the upper organic layer and extracting the aqueous layer with ethyl acetate, and discarding the ethyl acetate fraction to obtain a brown-colored solution not susceptible to gelling or solidification upon heating; i) heating the solution to distill off water and other light components and concentrating a bottoms fraction comprising hydroxyacetaldehyde and other non-volatile components having high boiling points; and j) decolorizing the stabilized brown solution with activated carbon to obtain a colorless solution.

Agblevor, Foster A. (Blacksburg, VA); Besler-Guran, Serpil (Flemington, NJ)

2001-01-01T23:59:59.000Z

62

Hydrogen from Biomass Catalytic Reforming of Pyrolysis Vapors  

E-Print Network [OSTI]

kg H2/day) with catalyst attrition rates Biomass Feedstocks 6 CO2 +6 H2O C6 waste Issues: Biomass Availability and Costs Georgia Biomass Feedstock Supply 0 3 6 9 12 2000 2010 2020

63

A Generalized Pyrolysis Model for Combustible Solids  

E-Print Network [OSTI]

processes of wood and biomass pyrolysis,” to appear ineffect during biomass pyrolysis,” Industrial & Engineeringprocesses during pyrolysis of a large biomass particle,”

Lautenberger, Chris

2007-01-01T23:59:59.000Z

64

CATALYTIC MICROWAVE PYROLYSIS OF BIOMASS FOR RENEWABLE PHENOLS AND FUELS .  

E-Print Network [OSTI]

??Bio-oil is an unstable intermediate and needs to be upgraded before its use. This study focused on improving the selectivity of bio-oilby catalytic pyrolysis of… (more)

[No author

2013-01-01T23:59:59.000Z

65

Large-Scale Pyrolysis Oil Production: A Technology Assessment and Economic Analysis  

SciTech Connect (OSTI)

A broad perspective of pyrolysis technology as it relates to converting biomass substrates to a liquid bio-oil product and a detailed technical and economic assessment of a fast pyrolysis plant.

Ringer, M.; Putsche, V.; Scahill, J.

2006-11-01T23:59:59.000Z

66

Ab Initio Dynamics of Cellulose Pyrolysis: Nascent Decomposition Pathways at 327 and 600 C  

E-Print Network [OSTI]

reserves in lignocellulosic biomass.1 Fast pyrolysis of lignocellulosic biomass, which involves rapidAb Initio Dynamics of Cellulose Pyrolysis: Nascent Decomposition Pathways at 327 and 600 °C Vishal pyrolysis at 327 and 600 °C using Car-Parrinello molecular dynamics (CPMD) simulations with rare events

Auerbach, Scott M.

67

Molecular beam mass spectrometric characterization of biomass pyrolysis products for fuels and chemicals  

SciTech Connect (OSTI)

Converting biomass feedstocks to fuels and chemicals requires rapid characterization of the wide variety of possible feedstocks. The combination of pyrolysis molecular beam mass spectrometry (Py-MBMS) and multivariate statistical analysis offers a unique capability for characterizing these feedstocks. Herbaceous and woody biomass feedstocks that were harvested at different periods were used in this study. The pyrolysis mass spectral data were acquired in real time on the MBMS, and multivariate statistical analysis (factor analysis) was used to analyze and classify Py-MBMS data into compound classes. The effect of harvest times on the thermal conversion of these feedstocks was assessed from these data. Apart from sericea lespedeza, the influence of harvest time on the pyrolysis products of the various feedstocks was insignificant. For sericea lespedeza, samples harvested before plant defoliation were significantly different from those harvested after defoliation. The defoliated plant samples had higher carbohydrate-derived pyrolysis products than the samples obtained from the foliated plant. Additionally, char yields from the defoliated plant samples were lower than those from the foliated plant samples.

Agblevor, F.A.; Davis, M.F.; Evans, R.J. [National Renewal Energy Lab., Golden, CO (United States)

1994-12-31T23:59:59.000Z

68

MINIMIZING NET CO2 EMISSIONS BY OXIDATIVE CO-PYROLYSIS OF COAL / BIOMASS BLENDS  

SciTech Connect (OSTI)

This study presents a set of thermodynamic calculations on the optimal mode of solid fuel utilization considering a wide range of fuel types and processing technologies. The technologies include stand-alone combustion, biomass/coal cofiring, oxidative pyrolysis, and straight carbonization with no energy recovery but with elemental carbon storage. The results show that the thermodynamically optimal way to process solid fuels depends strongly on the specific fuels and technologies available, the local demand for heat or for electricity, and the local baseline energy-production method. Burning renewable fuels reduces anthropogenic CO{sub 2} emissions as widely recognized. In certain cases, however, other processing methods are equally or more effective, including the simple carbonization or oxidative pyrolysis of biomass fuels.

Todd Lang; Robert Hurt

2001-12-23T23:59:59.000Z

69

Design Case Summary: Production of Gasoline and Diesel from Biomass...  

Energy Savers [EERE]

Design Case Summary: Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating, and Hydrocracking Design Case Summary: Production of Gasoline and Diesel from...

70

Well-to-wheels analysis of fast pyrolysis pathways with the GREET model.  

SciTech Connect (OSTI)

The pyrolysis of biomass can help produce liquid transportation fuels with properties similar to those of petroleum gasoline and diesel fuel. Argonne National Laboratory conducted a life-cycle (i.e., well-to-wheels [WTW]) analysis of various pyrolysis pathways by expanding and employing the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model. The WTW energy use and greenhouse gas (GHG) emissions from the pyrolysis pathways were compared with those from the baseline petroleum gasoline and diesel pathways. Various pyrolysis pathway scenarios with a wide variety of possible hydrogen sources, liquid fuel yields, and co-product application and treatment methods were considered. At one extreme, when hydrogen is produced from natural gas and when bio-char is used for process energy needs, the pyrolysis-based liquid fuel yield is high (32% of the dry mass of biomass input). The reductions in WTW fossil energy use and GHG emissions relative to those that occur when baseline petroleum fuels are used, however, is modest, at 50% and 51%, respectively, on a per unit of fuel energy basis. At the other extreme, when hydrogen is produced internally via reforming of pyrolysis oil and when bio-char is sequestered in soil applications, the pyrolysis-based liquid fuel yield is low (15% of the dry mass of biomass input), but the reductions in WTW fossil energy use and GHG emissions are large, at 79% and 96%, respectively, relative to those that occur when baseline petroleum fuels are used. The petroleum energy use in all scenarios was restricted to biomass collection and transportation activities, which resulted in a reduction in WTW petroleum energy use of 92-95% relative to that found when baseline petroleum fuels are used. Internal hydrogen production (i.e., via reforming of pyrolysis oil) significantly reduces fossil fuel use and GHG emissions because the hydrogen from fuel gas or pyrolysis oil (renewable sources) displaces that from fossil fuel natural gas and the amount of fossil natural gas used for hydrogen production is reduced; however, internal hydrogen production also reduces the potential petroleum energy savings (per unit of biomass input basis) because the fuel yield declines dramatically. Typically, a process that has a greater liquid fuel yield results in larger petroleum savings per unit of biomass input but a smaller reduction in life-cycle GHG emissions. Sequestration of the large amount of bio-char co-product (e.g., in soil applications) provides a significant carbon dioxide credit, while electricity generation from bio-char combustion provides a large energy credit. The WTW energy and GHG emissions benefits observed when a pyrolysis oil refinery was integrated with a pyrolysis reactor were small when compared with those that occur when pyrolysis oil is distributed to a distant refinery, since the activities associated with transporting the oil between the pyrolysis reactors and refineries have a smaller energy and emissions footprint than do other activities in the pyrolysis pathway.

Han, J.; Elgowainy, A.; Palou-Rivera, I.; Dunn, J.B.; Wang, M.Q. (Energy Systems)

2011-12-01T23:59:59.000Z

71

Analysis and comparison of biomass pyrolysis/gasification condensates: Final report  

SciTech Connect (OSTI)

This report provides results of chemical and physical analysis of condensates from eleven biomass gasification and pyrolysis systems. The samples were representative of the various reactor configurations being researched within the Department of Energy, Biomass Thermochemical Conversion program. The condensates included tar phases and aqueous phases. The analyses included gross compositional analysis (elemental analysis, ash, moisture), physical characterization (pour point, viscosity, density, heat of combustion, distillation), specific chemical analysis (gas chromatography/mass spectrometry, infrared spectrophotometry, proton and carbon-13 nuclear magnetic resonance spectrometry) and biological activity (Ames assay and mouse skin tumorigenicity tests). These results are the first step of a longer term program to determine the properties, handling requirements, and utility of the condensates recovered from biomass gasification and pyrolysis. The analytical data demonstrates the wide range of chemical composition of the organics recovered in the condensates and suggests a direct relationship between operating temperature and chemical composition of the condensates. A continuous pathway of thermal degradation of the tar components as a function of temperature is proposed. Variations in the chemical composition of the organic components in the tars are reflected in the physical properties of tars and phase stability in relation to water in the condensate. The biological activity appears to be limited to the tars produced at high temperatures. 56 refs., 25 figs., 21 tabs.

Elliott, D.C.

1986-06-01T23:59:59.000Z

72

Guidelines for Transportation, Handling, and Use of Fast Pyrolysis Bio-Oil. Part 1. Flammability and Toxicity  

SciTech Connect (OSTI)

An alternative sustainable fuel, biomass-derived fast pyrolysis oil or 'bio-oil', is coming into the market. Fast pyrolysis pilot and demonstration plants for fuel applications producing tonnes of bio-oil are in operation, and commercial plants are under design. There will be increasingly larger amounts of bio-oil transportation on water and by land, leading to a need for specifications and supporting documentation. Bio-oil is different from conventional liquid fuels, and therefore must overcome both technical and marketing hurdles for its acceptability in the fuels market. A comprehensive Material Safety Data Sheet (MSDS) is required, backed with independent testing and certification. In order to standardise bio-oil quality specifications are needed. The first bio-oil burner fuel standard in ASTM (D7544) was approved in 2009. CEN standardisation has been initiated in Europe. In the EU a new chemical regulation system, REACH (Registration, Evaluation and Authorisation of Chemicals) is being applied. Registration under REACH has to be made if bio-oil is produced or imported to the EU. In the USA and Canada, bio-oil has to be filed under TOSCA (US Toxic Substances Control Act). In this paper the state of the art on standardisation is discussed, and new data for the transportation guidelines is presented. The focus is on flammability and toxicity.

Oasmaa, Anja; Kalli, Anssi; Lindfors, Christian; Elliott, Douglas C.; Springer, David L.; Peacocke, Cordner; Chiaramonti, David

2012-05-04T23:59:59.000Z

73

Influence of inorganic compounds on char formation and quality of fast pyrolysis oils  

SciTech Connect (OSTI)

Inorganic compounds, especially potassium, calcium, sodium, silicon, phosphorus, and chlorine, are the main constituents of ash in biomass feedstocks. The concentrations of ash in biomass feedstocks range from less than 1% in softwoods to 15% in herbaceous biomass and agricultural residues. During biomass pyrolysis, these inorganics, especially potassium and calcium, catalyze both decomposition and char formation reactions. Decomposition reactions may either result in levoglucosan-rich or hydroxyacetaldehyde-rich pyrolysis products depending on the concentration of the ash in the feedstocks. The catalytic effect of the ash levels off at high organic ion concentrations. Chars formed during these reactions invariably end up in the pyrolysis oils (biofuel oils). A high proportion of the alkali metals in the ash are sequestered in the chars. The presence of high concentrations of alkali metals in the biofuel oils make them unsuitable for combustion in boilers, diesel engines, and in turbine operations. The highest concentration of alkali metals are found in herbaceous feedstocks and agricultural residue biofuel oils. Leaching studies conducted on the chars suspended in the oils showed no leaching of the alkali metals from the chars into the oils. Our data suggest that hot gas filtration of the oils can effectively reduce the alkali metals contents of the biofuel oils to acceptable levels to be used as turbine, diesel engine, and boiler fuels.

Agbleyor, F.A.; Besler, S.; Montane, D. [National Renewable Energy Lab., Golden, CO (United States)

1995-12-01T23:59:59.000Z

74

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis,  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergyDepartment ofOil'sofAppendix B, September 2010 |November 3, 1999Hydrotreating

75

KINETIC STUDY OF COAL AND BIOMASS CO-PYROLYSIS USING THERMOGRAVIMETRY  

SciTech Connect (OSTI)

The objectives of this study are to investigate thermal behavior of coal and biomass blends in inert gas environment at low heating rates and to develop a simplified kinetic model using model fitting techniques based on TGA experimental data. Differences in thermal behavior and reactivity in co-pyrolysis of Powder River Basin (PRB) sub-bituminous coal and pelletized southern yellow pine wood sawdust blends at low heating rates are observed. Coal/wood blends have higher reactivity compared to coal alone in the lower temperature due to the high volatile matter content of wood. As heating rates increase, weight loss rates increase. The experiment data obtained from TGA has a better fit with proposed two step first order reactions model compared single first order reaction model.

Wang, Ping; Hedges, Sheila; Chaudharib, Kiran; Turtonb, Richard

2013-10-29T23:59:59.000Z

76

Chemical and Structural Features of Plants That Contribute to Biomass Recalcitrance  

E-Print Network [OSTI]

of the Pyrolysis of Biomass. 1. Fundamentals. Energy Fuelsof the Pyrolysis of Biomass. 1. Fundamentals. Energy Fuelsfor analytical pyrolysis. 7.5.2 Biomass analysis All biomass

DeMartini, Jaclyn Diana

2011-01-01T23:59:59.000Z

77

Analysis and comparison of biomass pyrolysis/gasification condensates: an interim report  

SciTech Connect (OSTI)

This report provides results of chemical and physical analysis of condensates from eleven biomass gasification and pyrolysis systems. The analyses were performed in order to provide more detailed data concerning these condensates for the different process research groups and to allow a determination of the differences in properties of the condensates as a function of reactor environment. The samples were representative of the various reactor configurations being researched within the Department of Energy, Biomass Thermochemical Conversion program. The condensates included tar phases, aqueous phases and, in some cases, both phases depending on the output of the particular reactor system. The analyses included gross compositional analysis (elemental analysis, ash, moisture), physical characterization (pour point, viscosity, density, heat of combustion, distillation), specific chemical analysis (gas chromatography/mass spectrometry, infrared spectrophotometry, proton and carbon-13 nuclear magnetic resonance spectrometry) and biological activity (Ames assay). The analytical data demonstrate the wide range of chemical composition of the organics recovered in the condensates and suggests a direct relationship between operating temperature and chemical composition of the condensates. A continuous pathway of thermal degradation of the tar components as a function of temperature is proposed. Variations in the chemical composition of the organic components in the tars are reflected in the physical properties of tars and phase stability in relation to water in the condensate. The biological activity appears to be limited to the tars produced at high temperatures as a result of formation of polycyclic aromatic hydrocarbons in high concentrations. 55 refs., 13 figs., 6 tabs.

Elliott, D.C.

1985-09-01T23:59:59.000Z

78

Novel Fast Pyrolysis/Catalytic Technology for the Production of Stable Upgraded Liquids  

SciTech Connect (OSTI)

The objective of the proposed research is the demonstration and development of a novel biomass pyrolysis technology for the production of a stable bio-oil. The approach is to carry out catalytic hydrodeoxygenation (HDO) and upgrading together with pyrolysis in a single fluidized bed reactor with a unique two-level design that permits the physical separation of the two processes. The hydrogen required for the HDO will be generated in the catalytic section by the water-gas shift reaction employing recycled CO produced from the pyrolysis reaction itself. Thus, the use of a reactive recycle stream is another innovation in this technology. The catalysts will be designed in collaboration with BASF Catalysts LLC (formerly Engelhard Corporation), a leader in the manufacture of attrition-resistant cracking catalysts. The proposed work will include reactor modeling with state-of-the-art computational fluid dynamics in a supercomputer, and advanced kinetic analysis for optimization of bio-oil production. The stability of the bio-oil will be determined by viscosity, oxygen content, and acidity determinations in real and accelerated measurements. A multi-faceted team has been assembled to handle laboratory demonstration studies and computational analysis for optimization and scaleup.

Ted Oyama, Foster Agblevor, Francine Battaglia, Michael Klein

2013-01-18T23:59:59.000Z

79

The best use of biomass? Greenhouse gas lifecycle analysis of predicted pyrolysis biochar systems.  

E-Print Network [OSTI]

??Life cycle analysis is carried out for 11 predicted configurations of pyrolysis biochar systems to determine greenhouse gas balance, using an original spreadsheet model. System… (more)

Hammond, James A R

2009-01-01T23:59:59.000Z

80

Investigation of the Effect of In-Situ Catalyst on the Steam Hydrogasification of Biomass  

E-Print Network [OSTI]

G. , An overview of biomass pyrolysis, Energy Sources, 2002,Spliethoff, H. , Biomass pyrolysis/gasification for productreactor for the study of biomass pyrolysis chemistry at high

FAN, XIN

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

The flash pyrolysis and methanolysis of biomass (wood) for production of ethylene, benzene and methanol  

SciTech Connect (OSTI)

The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H{sub 2} and CH{sub 4} and with the non-reactive gases He and N{sub 2} is being determined in a 1 in. downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000{degrees}C. With hydrogen, flash hydropyrolysis leads to high yields of methane and CO which can be used for SNG and methanol fuel production. With methane, flash methanolysis leads to high yields of ethylene, benzene and CO which can be used for the production of valuable chemical feedstocks and methanol transportation fuel. At reactor conditions of 50 psi and 1000{degrees}C and approximately 1 sec residence time, the yields based on pine wood carbon conversion are up to 25% for ethylene, 25% for benzene, and 45% for CO, indicating that over 90% of the carbon in pine is converted to valuable products. Pine wood produces higher yields of hydrocarbon products than Douglas fir wood; the yield of ethylene is 2.3 times higher with methane than with helium or nitrogen, and for pine, the ratio is 7.5 times higher. The mechanism appears to be a free radical reaction between CH{sub 4} and the pyrolyzed wood. There appears to be no net production or consumption of methane. A preliminary process design and analysis indicates a potentially economical competitive system for the production of ethylene, benzene and methanol based on the methanolysis of wood. 10 refs., 18 figs., 1 tab.

Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

1990-02-01T23:59:59.000Z

82

Oil production by entrained pyrolysis of biomass and processing of oil and char  

DOE Patents [OSTI]

Entrained pyrolysis of lignocellulosic material proceeds from a controlled pyrolysis-initiating temperature to completion of an oxygen free environment at atmospheric pressure and controlled residence time to provide a high yield recovery of pyrolysis oil together with char and non-condensable, combustible gases. The residence time is a function of gas flow rate and the initiating temperature is likewise a function of the gas flow rate, varying therewith. A controlled initiating temperature range of about 400.degree. C. to 550.degree. C. with corresponding gas flow rates to maximize oil yield is disclosed.

Knight, James A. (Atlanta, GA); Gorton, Charles W. (Atlanta, GA)

1990-01-02T23:59:59.000Z

83

Flash Pyrolysis of Biomass with Reactive and Non-Reactive Gases: Summary Report for Period July 1983 through September 1984  

SciTech Connect (OSTI)

The purpose of this program is to study the conversion of biomass to liquid and gaseous hydrocarbon fuels and chemical feedstocks by a flash or rapid pyrolysis technique. During this period of study pine wood was flash pyrolyzed in atmospheres of methane and helium at a pressure of 50 psi and at temperatures up to 1050 C. The 1-inch I.D. entrained downflow tubular reactor was used in these experiments. Product yields of methane, ethane, ethylene, BTX, carbon monoxide and carbon dioxide were determined as a function of temperature and gas to wood ratio. Of particular interest were the ethylene and BTX yields. These represented as much as 29.6% and 24.6% of the carbon contained in the feed wood respectively when flash pyrolyzing in methane (flash methanolysls) and 14.7% and 9.7% when pyrolyzing in helium. In the case of flash methanolysis of wood the yields of ethylene and benzene increased with increasing methane to wood feed ratios. In the case of flash pyrolysis in helium the yields of ethylene and BTX decreased with increasing helium gas to wood feed ratios. These results indicate a mechanism by which a free radical reactive species originating from the wood interacts with the methane pyrolyzing gas to produce an enhanced yield of ethylene and benzene. The flash methanolysis of lignin extract from wood produced lower yields of ethylene, indicating the yields mainly originate from the cellulosic fractions of the wood. Some work was also performed on substituting wood ash for sillca flour (Cab-O-Sil) to allow free flow of wood particles through the entrained flow reactor. Preliminary process design and analysis indicates an economically competitive process for the flash methanolysis of wood for the production of methanol, benzene and ethylene. Future plans include completing the studies on obtaining the process chemistry of the flash methanolysis of woods, to obtain a better understanding of the enhanced ethylene and benzene yield and to investigate other biomass forms.

Steinberg M.; Fallon, P.T.; Sundaram, M.S.

1984-10-01T23:59:59.000Z

84

E-Print Network 3.0 - analytical on-line pyrolysis Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Scrap tire pyrolysis: experiment and modelling Summary: developped for wood and biomass pyrolysis, integral balance techniques provide approximate analytical... .....

85

Phenolic compounds containing/neutral fractions extract and products derived therefrom from fractionated fast-pyrolysis oils  

DOE Patents [OSTI]

A process is described for preparing phenol-formaldehyde novolak resins and molding compositions in which portions of the phenol normally contained in said resins are replaced by a phenol/neutral fractions extract obtained from fractionating fast-pyrolysis oils. The fractionation consists of a neutralization stage which can be carried out with aqueous solutions of bases or appropriate bases in the dry state, followed by solvent extraction with an organic solvent having at least a moderate solubility parameter and good hydrogen bonding capacity. Phenolic compounds-containing/neutral fractions extracts obtained by fractionating fast-pyrolysis oils from a lignocellulosic material, is such that the oil is initially in the pH range of 2-4, being neutralized with an aqueous bicarbonate base, and extracted into a solvent having a solubility parameter of approximately 8.4-9.11 [cal/cm[sup 3

Chum, H.L.; Black, S.K.; Diebold, J.P.; Kreibich, R.E.

1993-06-29T23:59:59.000Z

86

Quality Control in Fast Pyrolysis Bio-Oil Production and Use  

SciTech Connect (OSTI)

This paper will focus on norms and standards for fast pyrolysis bio-oils. It will include the present status and address what still has to be done on bio-oil specifications and relevant test methods. The paper will address industrial needs in commercialization of the fuel oil use of bio-oil, including the registration application to the REACH program and its consequences within the European Union, as well as development of a standard within ASTM. The paper will discuss the most important properties of bio-oil and the variation in these properties among various bio-oils. It will address the issue of quality follow-up in bio-oil production, including the properties to be followed and the laboratory and on-line monitoring methods. The paper will provide a state of the art of fuel oil specifications, test methods, and testing procedures as they are applied to bio-oil. It will review the effort in support of the implementation of an ASTM standard including the methods validation work.

Oasmaa, Anja; Elliott, Douglas C.; Muller, Stefan

2009-10-01T23:59:59.000Z

87

Methods and apparatuses for preparing upgraded pyrolysis oil  

DOE Patents [OSTI]

Methods and apparatuses for preparing upgraded pyrolysis oil are provided herein. In an embodiment, a method of preparing upgraded pyrolysis oil includes providing a biomass-derived pyrolysis oil stream having an original oxygen content. The biomass-derived pyrolysis oil stream is hydrodeoxygenated under catalysis in the presence of hydrogen to form a hydrodeoxygenated pyrolysis oil stream comprising a cyclic paraffin component. At least a portion of the hydrodeoxygenated pyrolysis oil stream is dehydrogenated under catalysis to form the upgraded pyrolysis oil.

Brandvold, Timothy A; Baird, Lance Awender; Frey, Stanley Joseph

2013-10-01T23:59:59.000Z

88

Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils  

SciTech Connect (OSTI)

This University of Massachusetts, Amherst project, "Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils" started on 1st February 2009 and finished on August 31st 2011. The project consisted following tasks: Task 1.0: Char Removal by Membrane Separation Technology The presence of char particles in the bio-oil causes problems in storage and end-use. Currently there is no well-established technology to remove char particles less than 10 micron in size. This study focused on the application of a liquid-phase microfiltration process to remove char particles from bio-oil down to slightly sub-micron levels. Tubular ceramic membranes of nominal pore sizes 0.5 and 0.8 ���µm were employed to carry out the microfiltration, which was conducted in the cross-flow mode at temperatures ranging from 38 to 45 C and at three different trans-membrane pressures varying from 1 to 3 bars. The results demonstrated the removal of the major quantity of char particles with a significant reduction in overall ash content of the bio-oil. The results clearly showed that the cake formation mechanism of fouling is predominant in this process. Task 2.0 Acid Removal by Membrane Separation Technology The feasibility of removing small organic acids from the aqueous fraction of fast pyrolysis bio-oils using nanofiltration (NF) and reverse osmosis (RO) membranes was studied. Experiments were carried out with a single solute solutions of acetic acid and glucose, binary solute solutions containing both acetic acid and glucose, and a model aqueous fraction of bio-oil (AFBO). Retention factors above 90% for glucose and below 0% for acetic acid were observed at feed pressures near 40 bar for single and binary solutions, so that their separation in the model AFBO was expected to be feasible. However, all of the membranes were irreversibly damaged when experiments were conducted with the model AFBO due to the presence of guaiacol in the feed solution. Experiments with model AFBO excluding guaiacol were also conducted. NF membranes showed retention factors of glucose greater than 80% and of acetic acid less than 15% when operated at transmembrane pressures near 60 bar. Task 3.0 Acid Removal by Catalytic Processing It was found that the TAN reduction in bio-oil was very difficult using low temperature hydrogenation in flow and batch reactors. Acetic acid is very resilient to hydrogenation and we could only achieve about 16% conversion for acetic acid. Although it was observed that acetic acid was not responsible for instability of aqueous fraction of bio-oil during ageing studies (described in task 5). The bimetallic catalyst PtRe/ceria-zirconia was found to be best catalyst because its ability to convert the acid functionality with low conversion to gas phase carbon. Hydrogenation of the whole bio-oil was carried out at 125���°C, 1450 psi over Ru/C catalyst in a flow reactor. Again, negligible acetic acid conversion was obtained in low temperature hydrogenation. Hydrogenation experiments with whole bio-oil were difficult to perform because of difficulty to pumping the high viscosity oil and reactor clogging. Task 4.0 Acid Removal using Ion Exchange Resins DOWEX M43 resin was used to carry out the neutralization of bio-oil using a packed bed column. The pH of the bio-oil increased from 2.43 to 3.7. The GC analysis of the samples showed that acetic acid was removed from the bio-oil during the neutralization and recovered in the methanol washing. But it was concluded that process would not be economical at large scale as it is extremely difficult to regenerate the resin once the bio-oil is passed over it. Task 5.0 Characterization of Upgraded Bio-oils We investigated the viscosity, microstructure, and chemical composition of bio-oils prepared by a fast pyrolysis approach, upon aging these fuels at 90���ºC for periods of several days. Our results suggest that the viscosity increase is not correlated with the acids or char present in the bio-oils. The

George W. Huber, Aniruddha A Upadhye, David M. Ford, Surita R. Bhatia, Phillip C. Badger

2012-10-19T23:59:59.000Z

89

Hydrotreating of fast pyrolysis oils from protein-rich pennycress seed presscake q  

E-Print Network [OSTI]

- icantly more nitrogen than do most lignocellulosic feedstocks. Examples of potential proteinaceous biomass feedstocks include oil seed presscakes (meals), manures, legume residues, and aquatic species such as algae

Reichenbach, Stephen E.

90

Proceedings of the Biomass Pyrolysis Oil Properties and Combustion Meeting, 26-28 September 1994, Estes Park, Colorado  

SciTech Connect (OSTI)

The increasing scale-up of fast pyrolysis in North America and Europe, as well as the exploration and expansion of markets for the energy use of biocrude oils that now needs to take place, suggested that it was timely to convene an international meeting on the properties and combustion behavior of these oils. A common understanding of the state-of-the-art and technical and other challenges which need to be met during the commercialization of biocrude fuel use, can be achieved. The technical issues and understanding of combustion of these oils are rapidly being advanced through R&D in the United States. Canada, Europe and Scandinavia. It is obvious that for the maximum economic impact of biocrude, it will be necessary to have a common set of specifications so that oils can be used interchangeably with engines and combustors which require minimal modification to use these renewable fuels. Fundamental and applied studies being pursued in several countries are brought together in this workshop so that we can arrive at common strategies. In this way, both the science and the commercialization are advanced to the benefit of all, without detracting from the competitive development of both the technology and its applications. This United States-Canada-Finland collaboration has led to the two and one half day specialists meeting at which the technical basis for advances in biocrude development is discussed. The goal is to arrive at a common agenda on issues that cross national boundaries in this area. Examples of agenda items are combustion phenomena, the behavior of trace components of the oil (N, alkali metals), the formation of NOx in combustion, the need for common standards and environmental safety and health issues in the handling, storage and transportation of biocrudes.

Milne, T.

1995-01-01T23:59:59.000Z

91

Biomass Thermochemical Conversion Program. 1983 Annual report  

SciTech Connect (OSTI)

Highlights of progress achieved in the program of thermochemical conversion of biomass into clean fuels during 1983 are summarized. Gasification research projects include: production of a medium-Btu gas without using purified oxygen at Battelle-Columbus Laboratories; high pressure (up to 500 psia) steam-oxygen gasification of biomass in a fluidized bed reactor at IGT; producing synthesis gas via catalytic gasification at PNL; indirect reactor heating methods at the Univ. of Missouri-Rolla and Texas Tech Univ.; improving the reliability, performance, and acceptability of small air-blown gasifiers at Univ. of Florida-Gainesville, Rocky Creek Farm Gasogens, and Cal Recovery Systems. Liquefaction projects include: determination of individual sequential pyrolysis mechanisms at SERI; research at SERI on a unique entrained, ablative fast pyrolysis reactor for supplying the heat fluxes required for fast pyrolysis; work at BNL on rapid pyrolysis of biomass in an atmosphere of methane to increase the yields of olefin and BTX products; research at the Georgia Inst. of Tech. on an entrained rapid pyrolysis reactor to produce higher yields of pyrolysis oil; research on an advanced concept to liquefy very concentrated biomass slurries in an integrated extruder/static mixer reactor at the Univ. of Arizona; and research at PNL on the characterization and upgrading of direct liquefaction oils including research to lower oxygen content and viscosity of the product. Combustion projects include: research on a directly fired wood combustor/gas turbine system at Aerospace Research Corp.; adaptation of Stirling engine external combustion systems to biomass fuels at United Stirling, Inc.; and theoretical modeling and experimental verification of biomass combustion behavior at JPL to increase biomass combustion efficiency and examine the effects of additives on combustion rates. 26 figures, 1 table.

Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

1984-08-01T23:59:59.000Z

92

Feedstock Logistics of a Mobile Pyrolysis System and Assessment of Soil Loss Due to Biomass Removal for Bioenergy Production  

E-Print Network [OSTI]

The purpose of this study was to assess feedstock logistics for a mobile pyrolysis system and to quantify the amount of soil loss caused by harvesting agricultural feedstocks for bioenergy production. The analysis of feedstock logistics...

Bumguardner, Marisa

2012-10-19T23:59:59.000Z

93

Thermochemical Conversion Research and Development: Gasification and Pyrolysis (Fact Sheet)  

SciTech Connect (OSTI)

Biomass gasification and pyrolysis research and development activities at the National Renewable Energy Laboratory and Pacific Northwest National Laboratory.

Not Available

2009-09-01T23:59:59.000Z

94

Design Case Summary: Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating, and Hydrocracking  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct, Parent Company Agrees to CooperateJapan

95

Upgrading of Biomass Fast Pyrolysis Oil (Bio-oil) Presentation for BETO 2015 Project Peer Review  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of EnergyTheTwo New12.'6/0.2 ...... 13:27DepartmentUpdating theUpgrading

96

Catalytic microwave torrefaction and pyrolysis of Douglas fir pellet to improve biofuel quality .  

E-Print Network [OSTI]

??The aims of this dissertation were to understand the effects of torrefaction as pretreatment on biomass pyrolysis and catalytic pyrolysis for improving biofuel quality, and… (more)

[No author

2012-01-01T23:59:59.000Z

97

E-Print Network 3.0 - aerosol spray pyrolysis Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by the endothermic pyrolysis reactions is transferred from the combustor... (MFR) for Biomass Pyrolysis briens, Cedric Institute for Chemicals and Fuels from Alternative...

98

Fast Pyrolysis and Hydrotreating 2013 State of Technology R&D and Projections to 2017  

SciTech Connect (OSTI)

This report documents the FY13 modeled costs and experimental basis for those costs for fast pyrolyis and hydrotreating to liquid fuels. The report also documents the projected costs to 2013.

Jones, Susanne B.; Snowden-Swan, Lesley J.; Meyer, Pimphan A.; Zacher, Alan H.; Olarte, Mariefel V.; Drennan, Corinne

2014-04-16T23:59:59.000Z

99

Liquid-phase Processing of Fast Pyrolysis Bio-oil using Pt/HZSM-5 Catalyst  

E-Print Network [OSTI]

such as switchgrass, sorghum and miscanthus, agriculture crops such as corn and sugarcane, municipal solid waste, agriculture wastes and forest residues. Energy crops are more preferred since they produce high yield, low fertilizer application requirements and low...), plastic wastes (Bhattacharya et al., 2009; Karaduman et al., 2001; Rutkowski and 7 Kubacki, 2006; Scott et al., 1990), waste biomass like oil cakes (?zbay et al., 2001), energy crops (He et al., 2009), and forest residues (Ingram et al., 2007...

Santos, Bjorn Sanchez

2013-05-01T23:59:59.000Z

100

Ris har udgivet en rapport om moderne bioenergi. Den slr fast, at biomasse er en  

E-Print Network [OSTI]

Risø har udgivet en rapport om moderne bioenergi. Den slår fast, at biomasse er en ligeså værdifuld eventyret med moderne bioenergi i hovedrollen. På Risø skubber vi eventyret i gang ved at udvikle nye større skala, end man troede det muligt for bare få år siden. Andre perspektiver for bioenergien er

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

In-Situ Catalytic Fast Pyrolysis Technology Pathway | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy Health andofIan Kalin About Us Ian KalinEditionIn-Situ Catalytic Fast

102

Investigation of the Effect of In-Situ Catalyst on the Steam Hydrogasification of Biomass  

E-Print Network [OSTI]

Yi, W. , Li, B. , Flash pyrolysis of agricultural residuesalthough fast or flash pyrolysis technologies can achieve a

FAN, XIN

2012-01-01T23:59:59.000Z

103

1 Solvent-Extractable Polycyclic Aromatic Hydrocarbons in Biochar: 2 Influence of Pyrolysis Temperature and Feedstock  

E-Print Network [OSTI]

combustion (or 30 pyrolysis) of plant biomass are important natural constituents 31 of soils and sediments.1 45 different starting materials. 46 Pyrolysis of biomass is known to produce a wide variety of 47 low and high molecular weight (LMW and HMW, respectively) 48 PAHs depending on the biomass type, pyrolysis

104

NREL: Biomass Research - Josh Schaidle  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of pyrolysis products to produce fungible transportation fuels. Research Interests Biomass conversion to fuels and chemicals Environmentally-sustainable engineering practices...

105

SYNTHESIS GAS UTILIZATION AND PRODUCTION IN A BIOMASS LIQUEFACTION FACILITY  

E-Print Network [OSTI]

Biomass from feed hopper Feed distributor cone with ultrasonic level indication P~~~ ~at Pyrolysis

Figueroa, C.

2012-01-01T23:59:59.000Z

106

NREL: Biomass Research - Jack Ferrell, Ph.D.  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

analytical development for pyrolysis oil, and on kinetic and hydrodynamic modeling of biomass-to-biofuels processes. Research Interests Thermochemical conversion of biomass to...

107

Preliminary Economics for the Production of Pyrolysis Oil from Lignin in a Cellulosic Ethanol Biorefinery  

SciTech Connect (OSTI)

Cellulosic ethanol biorefinery economics can be potentially improved by converting by-product lignin into high valued products. Cellulosic biomass is composed mainly of cellulose, hemicellulose and lignin. In a cellulosic ethanol biorefinery, cellulose and hemicellullose are converted to ethanol via fermentation. The raw lignin portion is the partially dewatered stream that is separated from the product ethanol and contains lignin, unconverted feed and other by-products. It can be burned as fuel for the plant or can be diverted into higher-value products. One such higher-valued product is pyrolysis oil, a fuel that can be further upgraded into motor gasoline fuels. While pyrolysis of pure lignin is not a good source of pyrolysis liquids, raw lignin containing unconverted feed and by-products may have potential as a feedstock. This report considers only the production of the pyrolysis oil and does not estimate the cost of upgrading that oil into synthetic crude oil or finished gasoline and diesel. A techno-economic analysis for the production of pyrolysis oil from raw lignin was conducted. comparing two cellulosic ethanol fermentation based biorefineries. The base case is the NREL 2002 cellulosic ethanol design report case where 2000 MTPD of corn stover is fermented to ethanol (NREL 2002). In the base case, lignin is separated from the ethanol product, dewatered, and burned to produce steam and power. The alternate case considered in this report dries the lignin, and then uses fast pyrolysis to generate a bio-oil product. Steam and power are generated in this alternate case by burning some of the corn stover feed, rather than fermenting it. This reduces the annual ethanol production rate from 69 to 54 million gallons/year. Assuming a pyrolysis oil value similar to Btu-adjusted residual oil, the estimated ethanol selling price ranges from $1.40 to $1.48 (2007 $) depending upon the yield of pyrolysis oil. This is considerably above the target minimum ethanol selling price of $1.33 for the 2012 goal case process as reported in the 2007 State of Technology Model (NREL 2008). Hence, pyrolysis oil does not appear to be an economically attractive product in this scenario. Further research regarding fast pyrolysis of raw lignin from a cellulosic plant as an end product is not recommended. Other processes, such as high-pressure liquefaction or wet gasification, and higher value products, such as gasoline and diesel from fast pyrolysis oil should be considered in future studies.

Jones, Susanne B.; Zhu, Yunhua

2009-04-01T23:59:59.000Z

108

CORROSIVITY AND COMPOSITION OF RAW AND TREATED PYROLYSIS OILS  

SciTech Connect (OSTI)

Fast pyrolysis offers a relatively low cost method of processing biomass to produce a liquid product that has the potential for conversion to several types of liquid fuels. The liquid product of fast pyrolysis, known as pyrolysis oil or bio-oil, contains a high oxygen content primarily in the form of water, carboxylic acids, phenols, ketones and aldehydes. These oils are typically very acidic with a Total Acid Number that is often in the range of 50 to 100, and previous studies have shown this material to be quite corrosive to common structural materials. Removal of at least some of the oxygen and conversion of this oil to a more useful product that is considerably less corrosive can be accomplished through a hydrogenation process. The product of such a treatment is considered to have the potential for blending with crude oil for processing in petroleum refineries. Corrosion studies and chemical analyses have been conducted using as produced bio-oil samples as well as samples that have been subjected to different levels of oxygen removal. Chemical analyses show treatment affected the concentrations of carboxylic acids contained in the oil, and corrosion studies showed a positive benefit of the oxygen removal. Results of these studies will be presented in this paper.

Keiser, Jim; Howell, Michael; Connatser, Raynella M.; Lewis, Sam; Elliott, Douglas C.

2012-10-14T23:59:59.000Z

109

NREL: Biomass Research - Thermochemical Conversion Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fuel synthesis reactor. NREL investigates thermochemical processes for converting biomass and its residues to fuels and intermediates using gasification and pyrolysis...

110

Physical and Chemical Characterization of Particulate and Gas phase Emissions from Biomass Burning  

E-Print Network [OSTI]

pyrolysis of wood: Applications to thermochemical processing of newsprint and biomass.of pyrolysis of cellulose, is a well-established biomasspyrolysis products (such as levoglucosan). In contrast, laboratory combustion of biomass

Hosseini, Seyedehsan

2012-01-01T23:59:59.000Z

111

Results of the IEA Round Robin on Viscosity and Aging of Fast Pyrolysis Bio-oils: Long-Term Tests and Repeatability  

SciTech Connect (OSTI)

An international round robin study of the viscosity and aging of fast pyrolysis bio-oil has been undertaken recently and this work is an outgrowth from that effort. Two bio-oil samples were distributed to the laboratories for aging tests and extended viscosity studies. The accelerated aging test was defined as the change in viscosity of a sealed sample of bio-oil held for 24 h at 80 °C. The test was repeated 10 times over consecutive days to determine the repeatability of the method. Other bio-oil samples were placed in storage at three temperatures, 21 °C, 4 °C and -17 °C for a period up to a year to evaluate the change in viscosity. The variation in the results of the aging test was shown to be low within a given laboratory. Storage of bio-oil under refrigeration can minimize the amount of change in viscosity. The accelerated aging test gives a measure of change similar to that of 6-12 months of storage at room temperature. These results can be helpful in setting standards for use of bio-oil, which is just coming into the marketplace.

Elliott, Douglas C.; Oasmaa, Anja; Meier, Dietrich; Preto, Fernando; Bridgwater, Anthony V.

2012-11-06T23:59:59.000Z

112

Sustainable use of California biomass resources can help meet state and national bioenergy targets  

E-Print Network [OSTI]

power plant. and pyrolysis of biomass by heating underpyrolysis oils) Producer gas Synthesis gas (syngas) Substitute natural gas (SNG) Hydrogen Biochemical Biosolids Physiochemical Densified biomass

Jenkins, Bryan M; Williams, Robert B; Gildart, Martha C; Kaffka, Stephen R.; Hartsough, Bruce; Dempster, Peter G

2009-01-01T23:59:59.000Z

113

E-Print Network 3.0 - activated sludge biomass Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

, Orlando, Florida, USA NAWTEC18-3521 STATUS OF EXISTING BIOMASS GASIFICATION AND PYROLYSIS FACILITIES... , the companies' existing installations focus on processing biomass...

114

Fluidizable Catalysts for Hydrogen Production from Biomass  

E-Print Network [OSTI]

Fluidizable Catalysts for Hydrogen Production from Biomass Pyrolysis/Steam Reforming K. Magrini/Objective Develop and demonstrate technology to produce hydrogen from biomass at $2.90/kg plant gate price based Bio-oil aqueous fraction CO H2 CO2 H2O Trap grease Waste plastics textiles Co-processing Pyrolysis

115

Flash Pyrolysis -A Powerful Method for Characterization of Polymers Helge Egsgaard  

E-Print Network [OSTI]

;Analytical flash pyrolysis Direct analysis of polymers including biopolymers & biomass Products detectedFlash Pyrolysis - A Powerful Method for Characterization of Polymers Helge Egsgaard Biosystems Department Risø National Laboratory DK-4000 Roskilde, Denmark The rational behind the pyrolysis technique

116

Technical Information Exchange on Pyrolysis Oil: Potential for...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Exchange on Pyrolysis Oil: Potential for a Renewab;e Heating Oil Substation Fuel in New England April 2012 Biomass Program News Blast June 2012 News Blast: Algae on the Mind...

117

HYDROGEN FROM BIOMASS FOR URBAN TRANSPORTATION  

E-Print Network [OSTI]

biomass, such as peanut shells, for urban transportation. The process involves pyrolysis of the biomassHYDROGEN FROM BIOMASS FOR URBAN TRANSPORTATION Collaborating Project Team Y. Yeboah (PI) and K and liquid fuels) · Potential sources of hydrogen include biomass, natural gas and other fossil fuels. #12

118

Effect of Using Inert and Non-Inert Gases on the Thermal Degradation and Fuel Properties of Biomass in the Torrefaction and Pyrolysis Region  

E-Print Network [OSTI]

to N? and Ar (which are entirely inert), making it better suited for use as a fuel for co-firing with coal or gasification. Three different biomasses were investigated: Juniper wood chips, Mesquite wood chips, and forage Sorghum. Experiments were...

Eseltine, Dustin E.

2012-02-14T23:59:59.000Z

119

The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification  

E-Print Network [OSTI]

overview of fast pyrolysis of biomass, Organic Geochemistry,presented a Pyrolysis and Gasification of Biomass and waste,

Luo, Qian

2012-01-01T23:59:59.000Z

120

Measuring and moderating the water resource impact of biofuel production and trade  

E-Print Network [OSTI]

from   biomass  via  fast  pyrolysis,  hydrotreating  and  2.3   gal/gal  for  pyrolysis  of  woody  biomass  (Jones,  

Fingerman, Kevin Robert

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds  

SciTech Connect (OSTI)

There is considerable world-wide interest in discovering renewable sources of energy that can substitute for fossil fuels. Lignocellulosic biomass, which is the most abundant and inexpensive renewable feedstock on the planet, has a great potential for sustainable production of fuels, chemicals, and carbon-based materials. Fast pyrolysis integrated with hydrotreating is one of the simplest, most cost-effective and most efficient processes to convert lignocellulosic biomass to liquid hydrocarbon fuels for transportation, which has attracted significant attention in recent decades. However, effective hydrotreating of pyrolysis bio-oil presents a daunting challenge to the commercialization of biomass conversion via pyrolysis-hydrotreating. Specifically, development of active, selective, and stable hydrotreating catalysts is the bottleneck due to the poor quality of pyrolysis bio-oil feedstock (high oxygen content, molecular complexity, coking propensity, and corrosiveness). Significant research has been conducted to address the practical issues and provide the fundamental understanding of the hydrotreating/hydrodeoxygenation (HDO) of bio-oils and their oxygen-containing model compounds, including phenolics, furans, and carboxylic acids. A wide range of catalysts have been studied, including conventional Mo-based sulfide catalysts and noble metal catalysts, with the latter being the primary focus of the recent research because of their excellent catalytic performances and no requirement of environmentally unfriendly sulfur. The reaction mechanisms of HDO of model compounds on noble metal catalysts as well as their efficacy for hydrotreating or stabilization of bio-oil have been recently reported. This review provides a survey of the relevant literatures of recent 10 years about the advances in the understanding of the HDO chemistry of bio-oils and their model compounds mainly on noble metal catalysts.

Wang, Huamin; Male, Jonathan L.; Wang, Yong

2013-05-01T23:59:59.000Z

122

Pilot-Scale Biorefinery: Sustainable Transport Fuels from Biomass...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Pilot-Scale Biorefinery: Sustainable Transport Fuels from Biomass via Integrated Pyrolysis, Catalytic Hydroconversion and Co-processing with Vacuum Gas Oil Raymond G. Wissinger...

123

Catalytic pyrolysis using UZM-39 aluminosilicate zeolite  

SciTech Connect (OSTI)

A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub.1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christopher P; Boldingh, Edwin P

2014-10-07T23:59:59.000Z

124

Catalytic pyrolysis using UZM-39 aluminosilicate zeolite  

DOE Patents [OSTI]

A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christpher P; Boldingh, Edwin P

2013-12-17T23:59:59.000Z

125

Synthesis of Mixed Metal Oxides for Hydrodeoxygenation of Pyrolysis Oil for Alternative Fuels Sarah McNew, Tiorra Ross and Carsten Sievers  

E-Print Network [OSTI]

· Flash pyrolysis on biomass [1] · Short residence times and flexible feed · Bio-oils produced are close to dissociate hydrogen Goal: synthesize metal free, sulfur free, catalysts for HDO Biomass Pyrolysis OilSynthesis of Mixed Metal Oxides for Hydrodeoxygenation of Pyrolysis Oil for Alternative Fuels Sarah

Das, Suman

126

Online Supplementary Material Biomass availability, energy consumption and biochar production in  

E-Print Network [OSTI]

is the pyrolysis chamber while the inner cylinder is the combustion chamber (Figure S3). Biomass is placedOnline Supplementary Material Biomass availability, energy consumption and biochar production pieces of wood. 1.3 Pyrolysis stove The pyrolysis stove is an anila-type stove developed by U

Lehmann, Johannes

127

Hydrothermal Liquefaction of Biomass  

SciTech Connect (OSTI)

Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international collaboration with Canada to investigate kelp (seaweed) as a biomass feedstock. The collaborative project includes process testing of the kelp in HydroThermal Liquefaction in the bench-scale unit at PNNL. HydroThermal Liquefaction at PNNL is performed in the hydrothermal processing bench-scale reactor system. Slurries of biomass are prepared in the laboratory from whole ground biomass materials. Both wet processing and dry processing mills can be used, but the wet milling to final slurry is accomplished in a stirred ball mill filled with angle-cut stainless steel shot. The PNNL HTL system, as shown in the figure, is a continuous-flow system including a 1-litre stirred tank preheater/reactor, which can be connected to a 1-litre tubular reactor. The product is filtered at high-pressure to remove mineral precipitate before it is collected in the two high-pressure collectors, which allow the liquid products to be collected batchwise and recovered alternately from the process flow. The filter can be intermittently back-flushed as needed during the run to maintain operation. By-product gas is vented out the wet test meter for volume measurement and samples are collected for gas chromatography compositional analysis. The bio-oil product is analyzed for elemental content in order to calculate mass and elemental balances around the experiments. Detailed chemical analysis is performed by gas chromatography-mass spectrometry and 13-C nuclear magnetic resonance is used to evaluate functional group types in the bio-oil. Sufficient product is produced to allow subsequent catalytic hydroprocessing to produce liquid hydrocarbon fuels. The product bio-oil from hydrothermal liquefaction is typically a more viscous product compared to fast pyrolysis bio-oil. There are several reasons for this difference. The HTL bio-oil contains a lower level of oxygen because of more extensive secondary reaction of the pyrolysis products. There are less amounts of the many light oxygenates derived from the carbohydrate structures as they have been further reacted to phenolic Aldol condensation products. The bio-oil

Elliott, Douglas C.

2010-12-10T23:59:59.000Z

128

Metal Oxide Laser Ioniza2on Mass Spectrometry for the Direct Profiling of Pyrolysis Oil Cons2tuents  

E-Print Network [OSTI]

from the anoxic pyrolysis of biomass (py-oils) represent a promising, renewable of Pyrolysis Oil Cons2tuents Casey R. McAlpin and Kent J. Voorhees Colorado School: ·MOLI MS produces profiles of pyrolysis oil consGtuents without separa

129

FAST  

Energy Science and Technology Software Center (OSTI)

002363MLTPL00 FAST - A Framework for Agile Software Testing v. 2.0  https://software.sandia.gov/trac/fast 

130

Biofuels from Pyrolysis: Catalytic Biocrude Production in a Novel, Short-Contact Time Reactor  

SciTech Connect (OSTI)

Broad Funding Opportunity Announcement Project: RTI is developing a new pyrolysis process to convert second-generation biomass into biofuels in one simple step. Pyrolysis is the decomposition of substances by heating—the same process used to render wood into charcoal, caramelize sugar, and dry roast coffee and beans. RTI’s catalytic biomass pyrolysis differs from conventional flash pyrolysis in that its end product contains less oxygen, metals, and nitrogen—all of which contribute to corrosion, instability, and inefficiency in the fuel-production process. This technology is expected to easily integrate into the existing domestic petroleum refining infrastructure, making it an economically attractive option for biofuels production.

None

2010-01-01T23:59:59.000Z

131

IEA/H2/TR-02/001 Hydrogen from Biomass  

E-Print Network [OSTI]

........................................................... 14 Biomass Pyrolysis to Hydrogen and Carbon or Methanol................................. 17-Derived Pyrolysis Oils............................................ 18 Hydrogen from Biomass-Derived MethanolIEA/H2/TR-02/001 Hydrogen from Biomass State of the Art and Research Challenges Thomas A. Milne

132

Biomass Gasification using Solar Thermal Energy M. Munzinger and K. Lovegrove  

E-Print Network [OSTI]

. In the first step, pyrolysis, volatile components of the biomass are vaporised at elevated temperatures from. #12;Biomass gasification using solar thermal energy Munzinger Figure 1 Pyrolysis pathways (Milne et alBiomass Gasification using Solar Thermal Energy M. Munzinger and K. Lovegrove Solar Thermal Group

133

Assessment of Biomass Resources in Afghanistan  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

almond and walnut shells, as well as olive pits, can be used to produce charcoal through pyrolysis of biomass, which could be used for cooking and as a soil amendment. Processing...

134

Scrap tire pyrolysis: Experiment and modelling  

SciTech Connect (OSTI)

Pyrolysis of waste, usually organic solids like tires, plastics or composite materials, is an alternative thermal waste treatment technology. Three main physical and chemical mechanisms - i.e.: chemical kinetics, internal heat transfer and external heat transfer - have to be considered when modelling the degradation of solid waste particles. Because of the lack of physical properties for wastes most of the models described in the literature use basic data obtained on the pyrolysis of coal, wood and biomass. In this work, the authors report basic information on the thermal degradation of tire samples at small scale: Thermogravimetric analyser (TGA) and differential scanning calorimeter (DSC), as well as direct and indirect measurements of thermal and physical properties (thermal conductivity of the tire and of the char, porosity, density, specific heat). Pyrolysis experiments on tire samples are performed in an imaging furnace. The experimental results are compared to theoretical values deduced from models that take into account physical property measurements.

Napoli, A.; Soudais, Y.; Lecomte, D. [Ecole des Mines d`Albi - Carmaux, Albi (France); Castillo, S. [Universite Paul Sabatier, Toulouse (France)

1997-12-01T23:59:59.000Z

135

Catalytic pyrolysis using UZM-44 aluminosilicate zeolite  

DOE Patents [OSTI]

A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula Na.sub.nM.sub.m.sup.k+T.sub.tAl.sub.1-xE.sub.xSi.sub.yO.sub.z where "n" is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, "m" is the mole ratio of M to (Al+E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-44 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christopher P; Boldingh, Edwin P

2013-12-17T23:59:59.000Z

136

Catalytic pyrolysis using UZM-44 aluminosilicate zeolite  

DOE Patents [OSTI]

A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.k+T.sub.tAl.sub.1-xE.sub.xSi.sub.yO.sub.z where "n" is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, "m" is the mole ratio of M to (Al+E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-44 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christopher P; Boldingh, Edwin P

2014-04-29T23:59:59.000Z

137

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents [OSTI]

A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

1996-04-02T23:59:59.000Z

138

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents [OSTI]

A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

Diebold, James P. (Lakewood, CO); Scahill, John W. (Evergreen, CO); Chum, Helena L. (Arvada, CO); Evans, Robert J. (Lakewood, CO); Rejai, Bahman (Lakewood, CO); Bain, Richard L. (Golden, CO); Overend, Ralph P. (Lakewood, CO)

1996-01-01T23:59:59.000Z

139

A Low-cost, High-yield Process for the Direct Productin of High Energy Density Liquid Fuel from Biomass  

SciTech Connect (OSTI)

The primary objective and outcome of this project was the development and validation of a novel, low-cost, high-pressure fast-hydropyrolysis/hydrodeoxygenation (HDO) process (H{sub 2}Bioil) using supplementary hydrogen (H{sub 2}) to produce liquid hydrocarbons from biomass. The research efforts under the various tasks of the project have culminated in the first experimental demonstration of the H2Bioil process, producing 100% deoxygenated >C4+ hydrocarbons containing 36-40% of the carbon in the feed of pyrolysis products from biomass. The demonstrated H{sub 2}Bioil process technology (i.e. reactor, catalyst, and downstream product recovery) is scalable to a commercial level and is estimated to be economically competitive for the cases when supplementary H{sub 2} is sourced from coal, natural gas, or nuclear. Additionally, energy systems modeling has revealed several process integration options based on the H{sub 2}Bioil process for energy and carbon efficient liquid fuel production. All project tasks and milestones were completed or exceeded. Novel, commercially-scalable, high-pressure reactors for both fast-hydropyrolysis and hydrodeoxygenation were constructed, completing Task A. These reactors were capable of operation under a wide-range of conditions; enabling process studies that lead to identification of optimum process conditions. Model compounds representing biomass pyrolysis products were studied, completing Task B. These studies were critical in identifying and developing HDO catalysts to target specific oxygen functional groups. These process and model compound catalyst studies enabled identification of catalysts that achieved 100% deoxygenation of the real biomass feedstock, sorghum, to form hydrocarbons in high yields as part of Task C. The work completed during this grant has identified and validated the novel and commercially scalable H2Bioil process for production of hydrocarbon fuels from biomass. Studies on model compounds as well as real biomass feedstocks were utilized to identify optimized process conditions and selective HDO catalyst for high yield production of hydrocarbons from biomass. In addition to these experimental efforts, in Tasks D and E, we have developed a mathematical optimization framework to identify carbon and energy efficient biomass-to-liquid fuel process designs that integrate the use of different primary energy sources along with biomass (e.g. solar, coal or natural gas) for liquid fuel production. Using this tool, we have identified augmented biomass-to-liquid fuel configurations based on the fast-hydropyrolysis/HDO pathway, which was experimentally studied in this project. The computational approach used for screening alternative process configurations represents a unique contribution to the field of biomass processing for liquid fuel production.

Agrawal, Rakesh

2014-02-21T23:59:59.000Z

140

A Generalized Pyrolysis Model for Combustible Solids  

E-Print Network [OSTI]

processes such as flash pyrolysis [187], but it has not yetreaction model for flash wood pyrolysis,” Fuel 68: 1408–

Lautenberger, Chris

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Facilities: NHMFL 9.4 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation: Characterization of Pine Pellet and Peanut Hull Pyrolysis of Bio-Oils by Negative-Ion Electrospray Ionization Fourier  

E-Print Network [OSTI]

with greater than 1% relative abundance in either phase are shown. Pyrolysis of solid biomass, in this case: Characterization of Pine Pellet and Peanut Hull Pyrolysis of Bio-Oils by Negative-Ion Electrospray Ionization of nitrogen-containing species identified in the peanut hull pyrolysis oil by FT-ICR mass spectrometry

Weston, Ken

142

Using mobile distributed pyrolysis facilities to deliver a forest residue resource for bio-fuel production.  

E-Print Network [OSTI]

??Distributed mobile conversion facilities using either fast pyrolysis or torrefaction processes can be used to convert forest residues to more energy dense substances (bio-oil, bio-slurry… (more)

Brown, Duncan

2013-01-01T23:59:59.000Z

143

NREL: Vehicles and Fuels Research - Alternative Fuels Characterization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

as well as combustion and emissions impacts. Biomass Pyrolysis-Derived Diesel Fast pyrolysis of biomass produces a high-oxygen-content liquid that can be upgraded to...

144

NITROGEN EVOLUTION AND SOOT FORMATION DURING SECONDARY COAL PYROLYSIS  

E-Print Network [OSTI]

reactor to provide a high temperature, oxygen-free post-flame environment to study secondary reactions analysis, gas species distributions were determined using FTIR, and the chemical structure of the tar secondary pyrolysis, an enrichment of nitrogen in tar was first observed, followed by a subsequent fast

Fletcher, Thomas H.

145

Black Carbon’s Properties and Role in the Environment: A Comprehensive Review  

E-Print Network [OSTI]

soot ? aromatics PYROLYSIS biomass lignin ? ? ? ? ? guaiacylVigouroux, R.Z. Pyrolysis of Biomass; Ph.D. Thesis, RoyalPeacoke, G.V.C. Fast pyrolysis for biomass. Renew. Sust.

Shrestha, Gyami

2010-01-01T23:59:59.000Z

146

Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation  

E-Print Network [OSTI]

R. Co-pyrolysis and cogasification of coal and biomass inand liquefaction of biomass through fast pyrolysis can alsofast pyrolysis (400-600 şC) to produce bio-oil from biomass

Lu, Xiaoming

2012-01-01T23:59:59.000Z

147

90 Seconds of Discovery: Fast Pyrolysis  

ScienceCinema (OSTI)

Fossil fuels have provided a time-proven, energy-dense fuel for more than a century. The challenge facing America today is developing alternatives that work within our existing infrastructure; to decrease environmental impact; and to increase energy security.

Weber, Robert; Elliot, Douglas

2014-06-13T23:59:59.000Z

148

90 Seconds of Discovery: Fast Pyrolysis  

SciTech Connect (OSTI)

Fossil fuels have provided a time-proven, energy-dense fuel for more than a century. The challenge facing America today is developing alternatives that work within our existing infrastructure; to decrease environmental impact; and to increase energy security.

Weber, Robert; Elliot, Douglas

2013-01-08T23:59:59.000Z

149

Solar coal gasification reactor with pyrolysis gas recycle  

DOE Patents [OSTI]

Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

Aiman, William R. (Livermore, CA); Gregg, David W. (Morago, CA)

1983-01-01T23:59:59.000Z

150

Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier  

E-Print Network [OSTI]

Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier DOE Hydrogen Program Contractors biomass #12;Approach Outline Gasifier Pilot Plant· Develop subsystems for the hydrogen production system and pyrolysis occur simultaneously in a single reactor · Exothermic combustion provides heat · Endothermic

151

Pyrolysis and hydrolysis of mixed polymer waste comprising polyethyleneterephthalate and polyethylene to sequentially recover  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1998-01-01T23:59:59.000Z

152

Hydrogen from Biomass for Urban Transportation Y. D. Yeboah (PI), K. B. Bota and Z. Wang  

E-Print Network [OSTI]

conversion and 2) pyrolysis of biomass to form a bio-oil that can be subsequently converted to hydrogen viaHydrogen from Biomass for Urban Transportation Y. D. Yeboah (PI), K. B. Bota and Z. Wang Clark amounts of fossil-derived CO2 are released to the atmosphere. Renewable biomass is an attractive

153

Recovery of valuable chemical feedstocks from waste automotive plastics via pyrolysis processes  

SciTech Connect (OSTI)

Each year in North America over 9 million scrap vehicles are shredded to recover approximately 10 million tons of ferrous metal. The process also produces 3 million tons of waste known as automobile shredder residue (ASR) which consists of plastics, rubber, foams, textiles, glass, dirt, rust, etc. This waste is currently landfilled. In this study the authors present the results obtained in three different pyrolysis processes when ASR was used as the pyrolysis feedstock. The pyrolysis processes examined included: (1) a fast pyrolysis process, featuring rapid heat transfer and short residence times. This process produced primarily a gas stream that was rich in C{sub 1} to C{sub 3} hydrocarbons; (2) a screw kiln unit, characterized by slow heating and long residence times. This process produced a liquid stream that was high in aromatics; (3) a bench-scale autoclave reactor which, in the presence of water, produced a pyrolysis liquid containing large quantities of oxygenated hydrocarbons.

Shen, Z.; Day, M.; Cooney, D. [National Research Council Canada, Ottawa, Ontario (Canada). Inst. for Environmental Research and Technology

1995-11-01T23:59:59.000Z

154

Kinetic Model Development for Lignin Pyrolysis  

SciTech Connect (OSTI)

Lignin pyrolysis poses a significant barrier to the formation of liquid fuel products from biomass. Lignin pyrolyzes at higher temperatures than other biomass components (e.g. cellulose and hemi-cellulose) and tends to form radicals species that lead to cross-linking and ultimately char formation. A first step in the advancement of biomass-to-fuel technology is to discover the underlying mechanisms that lead to the breakdown of lignin at lower temperatures into more stable and usable products. We have investigated the thermochemistry of the various inter-linkage units found in lignin (B-O4, a-O4, B-B, B-O5, etc) using electronic structure calculations at the M06-2x/6-311++G(d,p) on a series of dimer model compounds. In addition to bond homolysis reactions, a variety of concerted elimination pathways are under investigation that tend to produce closed-shell stable products. Such a bottom-up approach could aid in the targeted development of catalysts that produce more desirable products under less severe reactor conditions.

Clark, J.; Robichaud, D.; Nimlos, M.

2012-01-01T23:59:59.000Z

155

Pyrolysis of polystyrene - polyphenylene oxide to recover styrene and useful products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a polystyrene and polyphenylene oxide plastic waste to a given polystyrene and polyphenylene oxide prior to pyrolysis of other plastic components therein comprising: selecting a first temperature range to cause pyrolysis of given polystyrene and polyphenylene oxide and its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and a support and treating the feed stream with the catalyst to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of high value monomeric constituent of styrene from polystyrene and polyphenylene oxide in the first temperature range; differentially heating the feed stream at a heat rate within the first temperature range to provide differential pyrolysis for selective recovery of the high value monomeric constituent of styrene from polystyrene and polyphenylene oxide prior to pyrolysis of other plastic components; separating the high value monomer constituent of styrene; selecting a second higher temperature range to cause pyrolysis to a different derived high value product of polyphenylene oxide from the plastic waste and differentially heating the feed stream at the higher temperature range to cause pyrolysis of the plastic into a polyphenylene oxide derived product; and separating the different derived high value polyphenylene oxide product.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1995-01-01T23:59:59.000Z

156

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of polycarbonate and plastic waste to recover monomers  

DOE Patents [OSTI]

A process is described using fast pyrolysis to convert a plastic waste feed stream containing polycarbonate and ABS to high value monomeric constituents prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of a given polymer to its high value monomeric constituents prior to a temperature range that causes pyrolysis of other plastic components; selecting an acid or base catalysts and an oxide or carbonate support for treating the feed stream to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of the high value monomeric constituents of polycarbonate and ABS in the first temperature program range; differentially heating the feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituents prior to pyrolysis or other plastic components; separating the high value monomeric constituents from the polycarbonate to cause pyrolysis to a different high value monomeric constituent of the plastic waste and differentially heating the feed stream at the second higher temperature program range to cause pyrolysis of different high value monomeric constituents; and separating the different high value monomeric constituents. 68 figs.

Evans, R.J.; Chum, H.L.

1994-06-14T23:59:59.000Z

157

Controlled catalystic and thermal sequential pyrolysis and hydrolysis of polycarbonate and plastic waste to recover monomers  

DOE Patents [OSTI]

A process of using fast pyrolysis to convert a plastic waste feed stream containing polycarbonate and ABS to high value monomeric constituents prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of a given polymer to its high value monomeric constituents prior to a temperature range that causes pyrolysis of other plastic components; selecting an acid or base catalysts and an oxide or carbonate support for treating the feed stream to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of the high value monomeric constituents of polycarbonate and ABS in the first temperature program range; differentially heating the feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituents prior to pyrolysis or other plastic components; separating the high value monomeric constituents from the polycarbonate to cause pyrolysis to a different high value monomeric constituent of the plastic waste and differentially heating the feed stream at the second higher temperature program range to cause pyrolysis of different high value monomeric constituents; and separating the different high value monomeric constituents.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1994-01-01T23:59:59.000Z

158

Federal Biomass Activities  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Budget Federal Biomass Activities Federal Biomass Activities Biopower Biopower Biofuels Biofuels Bioproducts Bioproducts Federal Biomass Activities Federal Biomass...

159

Biomass Rapid Analysis Network (BRAN)  

SciTech Connect (OSTI)

Helping the emerging biotechnology industry develop new tools and methods for real-time analysis of biomass feedstocks, process intermediates and The Biomass Rapid Analysis Network is designed to fast track the development of modern tools and methods for biomass analysis to accelerate the development of the emerging industry. The network will be led by industry and organized and coordinated through the National Renewable Energy Lab. The network will provide training and other activities of interest to BRAN members. BRAN members will share the cost and work of rapid analysis method development, validate the new methods, and work together to develop the training for the future biomass conversion workforce.

Not Available

2003-10-01T23:59:59.000Z

160

Pyrolysis and hydrolysis of mixed polymer waste comprising polyethylene-terephthalate and polyethylene to sequentially recover [monomers  

DOE Patents [OSTI]

A process is described for using fast pyrolysis in a carrier gas to convert a plastic waste feed stream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feed stream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

Evans, R.J.; Chum, H.L.

1998-10-13T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of phenolic resin containing waste streams to sequentially recover monomers and chemicals  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a waste phenolic resin containing feedstreams in a manner such that pyrolysis of said resins and a given high value monomeric constituent occurs prior to pyrolyses of the resins in other monomeric components therein comprising: selecting a first temperature program range to cause pyrolysis of said resin and a given high value monomeric constituent prior to a temperature range that causes pyrolysis of other monomeric components; selecting, if desired, a catalyst and a support and treating said feedstreams with said catalyst to effect acid or basic catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said first temperature program range to utilize reactive gases such as oxygen and steam in the pyrolysis process to drive the production of specific products; differentially heating said feedstreams at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantity of said high value monomeric constituent prior to pyrolysis of other monomeric components therein; separating said high value monomeric constituent; selecting a second higher temperature program range to cause pyrolysis of a different high value monomeric constituent of said phenolic resins waste and differentially heating said feedstreams at said higher temperature program range to cause pyrolysis of said different high value monomeric constituent; and separating said different high value monomeric constituent.

Chum, Helena L. (Arvada, CO); Evans, Robert J. (Lakewood, CO)

1992-01-01T23:59:59.000Z

162

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of phenolic resin containing waste streams to sequentially recover monomers and chemicals  

DOE Patents [OSTI]

A process is described for using fast pyrolysis in a carrier gas to convert a waste phenolic resin containing feedstreams in a manner such that pyrolysis of said resins and a given high value monomeric constituent occurs prior to pyrolyses of the resins in other monomeric components therein comprising: selecting a first temperature program range to cause pyrolysis of said resin and a given high value monomeric constituent prior to a temperature range that causes pyrolysis of other monomeric components; selecting, if desired, a catalyst and a support and treating said feedstreams with said catalyst to effect acid or basic catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said first temperature program range to utilize reactive gases such as oxygen and steam in the pyrolysis process to drive the production of specific products; differentially heating said feedstreams at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantity of said high value monomeric constituent prior to pyrolysis of other monomeric components therein; separating said high value monomeric constituent; selecting a second higher temperature program range to cause pyrolysis of a different high value monomeric constituent of said phenolic resins waste and differentially heating said feedstreams at said higher temperature program range to cause pyrolysis of said different high value monomeric constituent; and separating said different high value monomeric constituent. 11 figs.

Chum, H.L.; Evans, R.J.

1992-08-04T23:59:59.000Z

163

Biomass pretreatment  

DOE Patents [OSTI]

A method is provided for producing an improved pretreated biomass product for use in saccharification followed by fermentation to produce a target chemical that includes removal of saccharification and or fermentation inhibitors from the pretreated biomass product. Specifically, the pretreated biomass product derived from using the present method has fewer inhibitors of saccharification and/or fermentation without a loss in sugar content.

Hennessey, Susan Marie; Friend, Julie; Elander, Richard T; Tucker, III, Melvin P

2013-05-21T23:59:59.000Z

164

AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND UPGRADE CONDITIONS WITH SPECIAL CONSIDERATION TO PIPELINE SHIPMENT  

SciTech Connect (OSTI)

One factor limiting the development of commercial biomass pyrolysis is challenges related to the transportation of the produced pyrolysis oil. The oil has different chemical and physical properties than crude oil, including more water and oxygen and has lower H/C ratio, higher specific gravity and density, higher acidity, and lower energy content. These differences could limit its ability to be transported by existing petroleum pipelines. Pyrolysis oil can also be treated, normally by catalytic hydrodeoxygenation, and approaches crude oil and petroleum condensates at higher severity levels. This improvement also results in lower liquid yield and high hydrogen consumption. Biomass resources for pyrolysis are expected to become plentiful and widely distributed in the future, mainly through the use of crop residuals and growing of energy crops such as perennial grasses, annual grasses, and woody crops. Crude oil pipelines are less well distributed and, when evaluated on a county level, could access about 18% of the total biomass supply. States with high potential include Texas, Oklahoma, California, and Louisiana. In this study, published data on pyrolysis oil was compiled into a data set along with bio-source source material, pyrolysis reactor conditions, and upgrading conditions for comparison to typical crude oils. Data of this type is expected to be useful in understanding the properties and chemistry and shipment of pyrolysis oil to refineries, where it can be further processed to fuel or used as a source of process heat.

Bunting, Bruce G [ORNL] [ORNL; Boyd, Alison C [ORNL] [ORNL

2012-01-01T23:59:59.000Z

165

YEAR 2 BIOMASS UTILIZATION  

SciTech Connect (OSTI)

This Energy & Environmental Research Center (EERC) Year 2 Biomass Utilization Final Technical Report summarizes multiple projects in biopower or bioenergy, transportation biofuels, and bioproducts. A prototype of a novel advanced power system, termed the high-temperature air furnace (HITAF), was tested for performance while converting biomass and coal blends to energy. Three biomass fuels--wood residue or hog fuel, corn stover, and switchgrass--and Wyoming subbituminous coal were acquired for combustion tests in the 3-million-Btu/hr system. Blend levels were 20% biomass--80% coal on a heat basis. Hog fuel was prepared for the upcoming combustion test by air-drying and processing through a hammer mill and screen. A K-Tron biomass feeder capable of operating in both gravimetric and volumetric modes was selected as the HITAF feed system. Two oxide dispersion-strengthened (ODS) alloys that would be used in the HITAF high-temperature heat exchanger were tested for slag corrosion rates. An alumina layer formed on one particular alloy, which was more corrosion-resistant than a chromia layer that formed on the other alloy. Research activities were completed in the development of an atmospheric pressure, fluidized-bed pyrolysis-type system called the controlled spontaneous reactor (CSR), which is used to process and condition biomass. Tree trimmings were physically and chemically altered by the CSR process, resulting in a fuel that was very suitable for feeding into a coal combustion or gasification system with little or no feed system modifications required. Experimental procedures were successful for producing hydrogen from biomass using the bacteria Thermotoga, a deep-ocean thermal vent organism. Analytical procedures for hydrogen were evaluated, a gas chromatography (GC) method was derived for measuring hydrogen yields, and adaptation culturing and protocols for mutagenesis were initiated to better develop strains that can use biomass cellulose. Fly ash derived from cofiring coal with waste paper, sunflower hulls, and wood waste showed a broad spectrum of chemical and physical characteristics, according to American Society for Testing and Materials (ASTM) C618 procedures. Higher-than-normal levels of magnesium, sodium, and potassium oxide were observed for the biomass-coal fly ash, which may impact utilization in cement replacement in concrete under ASTM requirements. Other niche markets for biomass-derived fly ash were explored. Research was conducted to develop/optimize a catalytic partial oxidation-based concept for a simple, low-cost fuel processor (reformer). Work progressed to evaluate the effects of temperature and denaturant on ethanol catalytic partial oxidation. A catalyst was isolated that had a yield of 24 mole percent, with catalyst coking limited to less than 15% over a period of 2 hours. In biodiesel research, conversion of vegetable oils to biodiesel using an alternative alkaline catalyst was demonstrated without the need for subsequent water washing. In work related to biorefinery technologies, a continuous-flow reactor was used to react ethanol with lactic acid prepared from an ammonium lactate concentrate produced in fermentations conducted at the EERC. Good yields of ester were obtained even though the concentration of lactic acid in the feed was low with respect to the amount of water present. Esterification gave lower yields of ester, owing to the lowered lactic acid content of the feed. All lactic acid fermentation from amylose hydrolysate test trials was completed. Management activities included a decision to extend several projects to December 31, 2003, because of delays in receiving biomass feedstocks for testing and acquisition of commercial matching funds. In strategic studies, methods for producing acetate esters for high-value fibers, fuel additives, solvents, and chemical intermediates were discussed with several commercial entities. Commercial industries have an interest in efficient biomass gasification designs but are waiting for economic incentives. Utility, biorefinery, pulp and paper, or o

Christopher J. Zygarlicke

2004-11-01T23:59:59.000Z

166

Biomass and Other Unconventional Energy Resources  

E-Print Network [OSTI]

. The primary technologies used to convert biomass to energy are direct combustion systems and Ithe gasification/pyrolysis method. IThe latter method creates a gaseous, li~uid or solid fuel to be used by an industry. Gasification involves the destr...: The Eastman Kodak Company in Rochester, New York investigated resource recovery when faced with a deteriorating incinerator that could no longer comply with regulations concerning air pollution emissions. The plant producing photographic equipment...

Gershman, H. G.

1982-01-01T23:59:59.000Z

167

SENT TO LSU AGCENTER/LOUISIANA FOREST PRODUCTS DEVELOPMENT CENTER -FOREST SECTOR / FORESTY PRODUCTS INTEREST GROUP Biomass Outlook 2014: Is Biomass About To Go Bang?  

E-Print Network [OSTI]

PRODUCTS INTEREST GROUP 1 Biomass Outlook 2014: Is Biomass About To Go Bang? Biomass offers a multitude can bio go? David Appleyard, Contributing Editor February 06, 2014 LONDON -- Traditional biomass renewables collectively. Nonetheless, modern renewables, and modern biomass with it, is catching up fast

168

CATALYTIC BIOMASS LIQUEFACTION  

E-Print Network [OSTI]

Solvent Systems Catalystic Biomass Liquefaction Investigatereactor Product collection Biomass liquefaction process12-13, 1980 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,

Ergun, Sabri

2013-01-01T23:59:59.000Z

169

An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated  

E-Print Network [OSTI]

-oils from biomass pyrolysis4 and because of its promising role in hydrogen storage through the fixationAn efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol,2-deoxygenation method, involving an unexpected mechanism, was found for simple diols and for biomass

170

Distributed Reforming of Biomass Pyrolysis Oils (Presentation) | Department  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct, Parent(CRADA and DOW Area 5(Presentation) | Departmentof

171

AGCO Biomass Solutions: Biomass 2014 Presentation  

Broader source: Energy.gov [DOE]

Plenary IV: Advances in Bioenergy Feedstocks—From Field to Fuel AGCO Biomass Solutions: Biomass 2014 Presentation Glenn Farris, Marketing Manager Biomass, AGCO Corporation

172

Autothermal pyrolysis of waste tires  

SciTech Connect (OSTI)

The main objective of this research was to study the operating parameters of autothermal pyrolysis of scrap tires in a laboratory-scale fluidized bed reactor with a 100-cm bed height (10 cm I.D.) and a 100-cm freeboard (25 cm I.D.). Scrap tires were pyrolyzed in a limited oxygen supply, so that the heat for pyrolysis of the scrap tires was provided by combustion of some portion of the scrap tires. The operating parameters evaluated included the effect on the pyrolysis oil products and their relative proportions of (1) the air factor (0.07-0.035); (2) the pyrolysis temperature (370-570{degree}C); and (3) the catalyst added (zeolite and calcium carbonate). The results show that: (1) the composition of the liquid hydrocarbon obtained is affected significantly by the air factor; (2) the higher operating temperature caused a higher yield of gasoline and diesel; (3) the yield of gasoline increased due to the catalyst zeolite added, and the yield of diesel increased due to the addition of the catalyst calcium carbonate; (4) the principal constituents of gasoline included dipentene and diprene. 30 refs., 10 figs., 5 tabs.

Wey, M.Y.; Liou, B.H. [National Chung-Hsing Univ., Taichung (Taiwan, Province of China); Wu, S.Y.; Zhang, C.H. [Feng-Chia Univ., Taichung (Taiwan, Province of China)

1995-11-01T23:59:59.000Z

173

Energy Blog | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

is working to understand the chemistry behind fast pyrolysis for creating bio-oil from biomass. Fast pyrolysis quickly heats up biomass (such as corn stalks and leaves) in the...

174

A Review on Biomass Torrefaction Process and Product Properties  

SciTech Connect (OSTI)

Biomass Torrefaction is gaining attention as an important preprocessing step to improve the quality of biomass in terms of physical properties and chemical composition. Torrefaction is a slow heating of biomass in an inert or reduced environment to a maximum temperature of approximately 300 C. Torrefaction can also be defined as a group of products resulting from the partially controlled and isothermal pyrolysis of biomass occurring in a temperature range of 200-280 C. Thus, the process can be called a mild pyrolysis as it occurs at the lower temperature range of the pyrolysis process. At the end of the torrefaction process, a solid uniform product with lower moisture content and higher energy content than raw biomass is produced. Most of the smoke-producing compounds and other volatiles are removed during torrefaction, which produces a final product that will have a lower mass but a higher heating value. The present review work looks into (a) torrefaction process and different products produced during the process and (b) solid torrefied material properties which include: (i) physical properties like moisture content, density, grindability, particle size distribution and particle surface area and pelletability; (ii) chemical properties like proximate and ultimate composition; and (iii) storage properties like off-gassing and spontaneous combustion.

Jaya Shankar Tumuluru; Shahab Sokhansanj; Christopher T. Wright; J. Richard Hess; Richard D. Boardman

2011-08-01T23:59:59.000Z

175

An economic analysis of mobile pyrolysis for northern New Mexico forests.  

SciTech Connect (OSTI)

In the interest of providing an economically sensible use for the copious small-diameter wood in Northern New Mexico, an economic study is performed focused on mobile pyrolysis. Mobile pyrolysis was selected for the study because transportation costs limit the viability of a dedicated pyrolysis plant, and the relative simplicity of pyrolysis compared to other technology solutions lends itself to mobile reactor design. A bench-scale pyrolysis system was used to study the wood pyrolysis process and to obtain performance data that was otherwise unavailable under conditions theorized to be optimal given the regional problem. Pyrolysis can convert wood to three main products: fixed gases, liquid pyrolysis oil and char. The fixed gases are useful as low-quality fuel, and may have sufficient chemical energy to power a mobile system, eliminating the need for an external power source. The majority of the energy content of the pyrolysis gas is associated with carbon monoxide, followed by light hydrocarbons. The liquids are well characterized in the historical literature, and have slightly lower heating values comparable to the feedstock. They consist of water and a mix of hundreds of hydrocarbons, and are acidic. They are also unstable, increasing in viscosity with time stored. Up to 60% of the biomass in bench-scale testing was converted to liquids. Lower ({approx}550 C) furnace temperatures are preferred because of the decreased propensity for deposits and the high liquid yields. A mobile pyrolysis system would be designed with low maintenance requirements, should be able to access wilderness areas, and should not require more than one or two people to operate the system. The techno-economic analysis assesses fixed and variable costs. It suggests that the economy of scale is an important factor, as higher throughput directly leads to improved system economic viability. Labor and capital equipment are the driving factors in the viability of the system. The break-even selling price for the baseline assumption is about $11/GJ, however it may be possible to reduce this value by 20-30% depending on other factors evaluated in the non-baseline scenarios. Assuming a value for the char co-product improves the analysis. Significantly lower break-even costs are possible in an international setting, as labor is the dominant production cost.

Brady, Patrick D.; Brown, Alexander L.; Mowry, Curtis Dale; Borek, Theodore Thaddeus, III

2011-12-01T23:59:59.000Z

176

Comparison of Biological and Thermal (Pyrolysis) Pathways for Conversion of Lignocellulose to Biofuels  

E-Print Network [OSTI]

D study. This journey was great because of her and Tinku being around! Thanks to my advisor Dr. Capareda for the diverse bio-energy research opportunity at BETA lab, Dr. El-Halwagi for the unconditional care in every step since I joined TX A... to produce bio-energy from biomass ....................... 3 1.2.2 Pretreatment and hydrolysis in lignocellulose breakdown ....................... 5 1.2.3 Pyrolysis oil upgrade technology...

Imam, Tahmina 1983-

2012-11-30T23:59:59.000Z

177

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1993-01-01T23:59:59.000Z

178

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1994-01-01T23:59:59.000Z

179

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process is described for using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents, selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 87 figures.

Evans, R.J.; Chum, H.L.

1994-04-05T23:59:59.000Z

180

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents, selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

Evans, R.J.; Chum, H.L.

1994-10-25T23:59:59.000Z

182

D o s s i e r Second and Third Generation Biofuels: Towards Sustainability and Competitiveness  

E-Print Network [OSTI]

Historical Review of Fast Pyrolysis of Biomass D. Radlein1 * and A. Quignard2 1 632 Grange Cres., Waterloo valeur ajoute´ e. Abstract -- A Short Historical Review of Fast Pyrolysis of Biomass -- In this short. In this short review, we shall attempt to summarise the modern history of the fast pyrolysis of biomass over

Paris-Sud XI, Université de

183

Study of Surface Cleaning Methods and Pyrolysis Temperature on...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Surface Cleaning Methods and Pyrolysis Temperature on Nano-Structured Carbon Films using X-ray Photoelectron Study of Surface Cleaning Methods and Pyrolysis Temperature on...

184

Biomass Surface Characterization Laboratory  

E-Print Network [OSTI]

the recalcitrant nature of biomass feedstocks and the performance of techniques to deconstruct biomass NREL of biomass feedstocks. BSCL imaging capabilities include: · Confocal microscopy and Raman microscopy

185

Biomass Feedstocks  

Broader source: Energy.gov [DOE]

A feedstock is defined as any renewable, biological material that can be used directly as a fuel, or converted to another form of fuel or energy product. Biomass feedstocks are the plant and algal materials used to derive fuels like ethanol, butanol, biodiesel, and other hydrocarbon fuels. Examples of biomass feedstocks include corn starch, sugarcane juice, crop residues such as corn stover and sugarcane bagasse, purpose-grown grass crops, and woody plants. The Bioenergy Technologies Office works in partnership with the U.S. Department of Agriculture (USDA), national laboratories, universities, industry, and other key stakeholders to identify and develop economically, environmentally, and socially sustainable feedstocks for the production of energy, including transportation fuels, electrical power and heat, and other bioproducts. Efforts in this area will ultimately support the development of technologies that can provide a large and sustainable cellulosic biomass feedstock supply of acceptable quality and at a reasonable cost for use by the developing U.S. advanced biofuel industry.

186

Life-Cycle Assessment of Pyrolysis Bio-Oil Production  

SciTech Connect (OSTI)

As part ofthe Consortium for Research on Renewable Industrial Materials' Phase I life-cycle assessments ofbiofuels, lifecycle inventory burdens from the production of bio-oil were developed and compared with measures for residual fuel oil. Bio-oil feedstock was produced using whole southern pine (Pinus taeda) trees, chipped, and converted into bio-oil by fast pyrolysis. Input parameters and mass and energy balances were derived with Aspen. Mass and energy balances were input to SimaPro to determine the environmental performance of bio-oil compared with residual fuel oil as a heating fuel. Equivalent functional units of 1 MJ were used for demonstrating environmental preference in impact categories, such as fossil fuel use and global warming potential. Results showed near carbon neutrality of the bio-oil. Substituting bio-oil for residual fuel oil, based on the relative carbon emissions of the two fuels, estimated a reduction in CO2 emissions by 0.075 kg CO2 per MJ of fuel combustion or a 70 percent reduction in emission over residual fuel oil. The bio-oil production life-cycle stage consumed 92 percent of the total cradle-to-grave energy requirements, while feedstock collection, preparation, and transportation consumed 4 percent each. This model provides a framework to better understand the major factors affecting greenhouse gas emissions related to bio-oil production and conversion to boiler fuel during fast pyrolysis.

Steele, Philp; Puettmann, Maureen E.; Penmetsa, Venkata Kanthi; Cooper, Jerome E.

2012-02-01T23:59:59.000Z

187

DANISHBIOETHANOLCONCEPT Biomass conversion for  

E-Print Network [OSTI]

DANISHBIOETHANOLCONCEPT Biomass conversion for transportation fuel Concept developed at RISĂ? and DTU Anne Belinda Thomsen (RISĂ?) Birgitte K. Ahring (DTU) #12;DANISHBIOETHANOLCONCEPT Biomass: Biogas #12;DANISHBIOETHANOLCONCEPT Pre-treatment Step Biomass is macerated The biomass is cut in small

188

Pyrolysis of Woody Residue Feedstocks: Upgrading of Bio-Oils from Mountain-Pine-Beetle-Killed Trees and Hog Fuel  

SciTech Connect (OSTI)

Liquid transportation fuel blend-stocks were produced by pyrolysis and catalytic upgrading of woody residue biomass. Mountain pine beetle killed wood and hog fuel from a saw mill were pyrolyzed in a 1 kg/h fluidized bed reactor and subsequently upgraded to hydrocarbons in a continuous fixed bed hydrotreater. Upgrading was performed by catalytic hydrotreatment in a two-stage bed at 170°C and 405°C with a per bed LHSV between 0.17 and 0.19. The overall yields from biomass to upgraded fuel were similar for both feeds: 24-25% despite the differences in bio-oil (intermediate) mass yield. Pyrolysis bio-oil mass yield was 61% from MPBK wood, and subsequent upgrading of the bio-oil gave an average mass yield of 41% to liquid fuel blend stocks. Hydrogen was consumed at an average of 0.042g/g of bio-oil fed, with final oxygen content in the product fuel ranging from 0.31% to 1.58% over the course of the test. Comparatively for hog fuel, pyrolysis bio-oil mass yield was lower at 54% due to inorganics in the biomass, but subsequent upgrading of that bio-oil had an average mass yield of 45% to liquid fuel, resulting in a similar final mass yield to fuel compared to the cleaner MPBK wood. Hydrogen consumption for the hog fuel upgrading averaged 0.041 g/g of bio-oil fed, and the final oxygen content of the product fuel ranged from 0.09% to 2.4% over the run. While it was confirmed that inorganic laded biomass yields less bio-oil, this work demonstrated that the resultant bio-oil can be upgraded to hydrocarbons at a higher yield than bio-oil from clean wood. Thus the final hydrocarbon yield from clean or residue biomass pyrolysis/upgrading was similar.

Zacher, Alan H.; Elliott, Douglas C.; Olarte, Mariefel V.; Santosa, Daniel M.; Preto, Fernando; Iisa, Kristiina

2014-12-01T23:59:59.000Z

189

Biomass shock pretreatment  

SciTech Connect (OSTI)

Methods and apparatus for treating biomass that may include introducing a biomass to a chamber; exposing the biomass in the chamber to a shock event to produce a shocked biomass; and transferring the shocked biomass from the chamber. In some aspects, the method may include pretreating the biomass with a chemical before introducing the biomass to the chamber and/or after transferring shocked biomass from the chamber.

Holtzapple, Mark T.; Madison, Maxine Jones; Ramirez, Rocio Sierra; Deimund, Mark A.; Falls, Matthew; Dunkelman, John J.

2014-07-01T23:59:59.000Z

190

Environmental impacts of thermochemical biomass conversion. Final report  

SciTech Connect (OSTI)

Thermochemical conversion in this study is limited to fast pyrolysis, upgrading of fast pyrolysis oils, and gasification. Environmental impacts of all types were considered within the project, but primary emphasis was on discharges to the land, air, and water during and after the conversion processes. The project discussed here is divided into five task areas: (1) pyrolysis oil analysis; (2) hydrotreating of pyrolysis oil; (3) gas treatment systems for effluent minimization; (4) strategic analysis of regulatory requirements; and (5) support of the IEA Environmental Systems Activity. The pyrolysis oil task was aimed at understanding the oil contaminants and potential means for their removal. The hydrotreating task was undertaken to better define one potential means for both improving the quality of the oil but also removing contaminants from the oil. Within Task 3, analyses were done to evaluate the results of gasification product treatment systems. Task 4 was a review and collection of regulatory requirements which would be applicable to the subject processes. The IEA support task included input to and participation in the IEA Bioenergy activity which directly relates to the project subject. Each of these tasks is described along with the results. Conclusions and recommendations from the overall project are given.

Elliott, D.C.; Hart, T.R.; Neuenschwander, G.G.; McKinney, M.D.; Norton, M.V.; Abrams, C.W. [Pacific Northwest Lab., Richland, WA (United States)

1995-06-01T23:59:59.000Z

191

Microwave pyrolysis of distillers dried grain with solubles (DDGS) for biofuel production  

SciTech Connect (OSTI)

Microwave pyrolysis of distillers dried grain with solubles (DDGS) was investigated to determine the effects of pyrolytic conditions on the yields of bio-oil, syngas, and biochar. Pyrolysis process variables included reaction temperature, time, and power input. Microwave pyrolysis of DDGS was analyzed using response surface methodology to ?nd out the effect of process variables on the biofuel (bio-oil and syn- gas) conversion yield and establish prediction models. Bio-oil recovery was in the range of 26.5–50.3 wt.% of the biomass. Biochar yields were 23.5–62.2% depending on the pyrolysis conditions. The energy con- tent of DDGS bio-oils was 28 MJ/kg obtained at the 650 oC and 8 min, which was about 66.7% of the heat- ing value of gasoline. GC/MS analysis indicated that the biooil contained a series of important and useful chemical compounds: aliphatic and aromatic hydrocarbons. At least 13% of DDGS bio-oil was the same hydrocarbon compounds found in regular unleaded gasoline.

Lei, Hanwu; Ren, Shoujie; Wang, Lu; Bu, Quan; Julson, James; Holladay, Johnathan E.; Ruan, Roger

2011-05-01T23:59:59.000Z

192

Waste tire recycling by pyrolysis  

SciTech Connect (OSTI)

This project examines the City of New Orleans' waste tire problem. Louisiana State law, as of January 1, 1991, prohibits the knowing disposal of whole waste tires in landfills. Presently, the numerous waste tire stockpiles in New Orleans range in size from tens to hundreds of tires. New Orleans' waste tire problem will continue to increase until legal disposal facilities are made accessible and a waste tire tracking and regulatory system with enforcement provisions is in place. Tires purchased outside of the city of New Orleans may be discarded within the city's limits; therefore, as a practical matter this study analyzes the impact stemming from the entire New Orleans metropolitan area. Pyrolysis mass recovery (PMR), a tire reclamation process which produces gas, oil, carbon black and steel, is the primary focus of this report. The technical, legal and environmental aspects of various alternative technologies are examined. The feasibility of locating a hypothetical PMR operation within the city of New Orleans is analyzed based on the current economic, regulatory, and environmental climate in Louisiana. A thorough analysis of active, abandoned, and proposed Pyrolysis operations (both national and international) was conducted as part of this project. Siting a PMR plant in New Orleans at the present time is technically feasible and could solve the city's waste tire problem. Pending state legislation could improve the city's ability to guarantee a long term supply of waste tires to any large scale tire reclamation or recycling operation, but the local market for PMR end products is undefined.

Not Available

1992-10-01T23:59:59.000Z

193

Volatile constituents in a wood pyrolysis oil  

E-Print Network [OSTI]

Science VOLATILE CONSTITUTENTS IN A WOOD PYROLYSIS OIL A Thesis SHIH-CHIEN LIN Appro d as to style and content by: (Chairman of Committee) Head of epa tmen (Member Member Nay 1978 442936 ABSTRACT Volatile Constituents in a Wood Pyrolysis Oil.../120 Supelcoport. Other trace constituents of volatile acid were also 'dentifi="' by trap- ping the substances from the C. C. column into i: n;- 0-sh ped capillary tube and subjecting to mass spectrometry. The corrosivity of pyrolysis oil and it, volati'e acids...

Lin, Shih-Chien

1978-01-01T23:59:59.000Z

194

Biomass Thermochemical Conversion Program. 1984 annual report  

SciTech Connect (OSTI)

The objective of the program is to generate scientific data and conversion process information that will lead to establishment of cost-effective process for converting biomass resources into clean fuels. The goal of the program is to develop the data base for biomass thermal conversion by investigating the fundamental aspects of conversion technologies and by exploring those parameters that are critical to the conversion processes. The research activities can be divided into: (1) gasification technology; (2) liquid fuels technology; (3) direct combustion technology; and (4) program support activities. These activities are described in detail in this report. Outstanding accomplishments during fiscal year 1984 include: (1) successful operation of 3-MW combustor/gas turbine system; (2) successful extended term operation of an indirectly heated, dual bed gasifier for producing medium-Btu gas; (3) determination that oxygen requirements for medium-Btu gasification of biomass in a pressurized, fluidized bed gasifier are low; (4) established interdependence of temperature and residence times on biomass pyrolysis oil yields; and (5) determination of preliminary technical feasibility of thermally gasifying high moisture biomass feedstocks. A bibliography of 1984 publications is included. 26 figs., 1 tab.

Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

1985-01-01T23:59:59.000Z

195

1982 annual report: Biomass Thermochemical Conversion Program  

SciTech Connect (OSTI)

This report provides a brief overview of the Thermochemical Conversion Program's activities and major accomplishments during fiscal year 1982. The objective of the Biomass Thermochemical Conversion Program is to generate scientific data and fundamental biomass converison process information that, in the long term, could lead to establishment of cost effective processes for conversion of biomass resources into clean fuels and petrochemical substitutes. The goal of the program is to improve the data base for biomass conversion by investigating the fundamental aspects of conversion technologies and exploring those parameters which are critical to these conversion processes. To achieve this objective and goal, the Thermochemical Conversion Program is sponsoring high-risk, long-term research with high payoff potential which industry is not currently sponsoring, nor is likely to support. Thermochemical conversion processes employ elevated temperatures to convert biomass materials into energy. Process examples include: combustion to produce heat, steam, electricity, direct mechanical power; gasification to produce fuel gas or synthesis gases for the production of methanol and hydrocarbon fuels; direct liquefaction to produce heavy oils or distillates; and pyrolysis to produce a mixture of oils, fuel gases, and char. A bibliography of publications for 1982 is included.

Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

1983-01-01T23:59:59.000Z

196

Selection and performance of Materials for Biomass Gasifiers  

SciTech Connect (OSTI)

Production of syngas through gasification or pyrolysis offers one of the more efficient routes for utilization of biomass resources; however, the containment structures used for many of these thermochemical processes are exposed to severe environments that limit their longevity and reliability. Studies have been conducted for three of these systems, and superior alternative materials have been identified. Improved materials will be of even greater importance in proposed gasification systems, many of which will generate even more extreme operating conditions.

Keiser, James R [ORNL] [ORNL; Hemrick, James Gordon [ORNL] [ORNL; Meisner, Roberta A [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)] [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL); Blau, Peter J [Oak Ridge National Laboratory (ORNL)] [Oak Ridge National Laboratory (ORNL); Pint, Bruce A [ORNL] [ORNL

2010-01-01T23:59:59.000Z

197

Waste tire recycling by pyrolysis  

SciTech Connect (OSTI)

This project examines the City of New Orleans` waste tire problem. Louisiana State law, as of January 1, 1991, prohibits the knowing disposal of whole waste tires in landfills. Presently, the numerous waste tire stockpiles in New Orleans range in size from tens to hundreds of tires. New Orleans` waste tire problem will continue to increase until legal disposal facilities are made accessible and a waste tire tracking and regulatory system with enforcement provisions is in place. Tires purchased outside of the city of New Orleans may be discarded within the city`s limits; therefore, as a practical matter this study analyzes the impact stemming from the entire New Orleans metropolitan area. Pyrolysis mass recovery (PMR), a tire reclamation process which produces gas, oil, carbon black and steel, is the primary focus of this report. The technical, legal and environmental aspects of various alternative technologies are examined. The feasibility of locating a hypothetical PMR operation within the city of New Orleans is analyzed based on the current economic, regulatory, and environmental climate in Louisiana. A thorough analysis of active, abandoned, and proposed Pyrolysis operations (both national and international) was conducted as part of this project. Siting a PMR plant in New Orleans at the present time is technically feasible and could solve the city`s waste tire problem. Pending state legislation could improve the city`s ability to guarantee a long term supply of waste tires to any large scale tire reclamation or recycling operation, but the local market for PMR end products is undefined.

Not Available

1992-10-01T23:59:59.000Z

198

Pyrolysis of waste tyres: A review  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Pyrolysis of waste tyres produces oil, gas and char, and recovered steel. • Batch, screw kiln, rotary kiln, vacuum and fluidised-bed are main reactor types. • Product yields are influenced by reactor type, temperature and heating rate. • Pyrolysis oils are complex and can be used as chemical feedstock or fuel. • Research into higher value products from the tyre pyrolysis process is reviewed. - Abstract: Approximately 1.5 billion tyres are produced each year which will eventually enter the waste stream representing a major potential waste and environmental problem. However, there is growing interest in pyrolysis as a technology to treat tyres to produce valuable oil, char and gas products. The most common reactors used are fixed-bed (batch), screw kiln, rotary kiln, vacuum and fluidised-bed. The key influence on the product yield, and gas and oil composition, is the type of reactor used which in turn determines the temperature and heating rate. Tyre pyrolysis oil is chemically very complex containing aliphatic, aromatic, hetero-atom and polar fractions. The fuel characteristics of the tyre oil shows that it is similar to a gas oil or light fuel oil and has been successfully combusted in test furnaces and engines. The main gases produced from the pyrolysis of waste tyres are H{sub 2}, C{sub 1}–C{sub 4} hydrocarbons, CO{sub 2}, CO and H{sub 2}S. Upgrading tyre pyrolysis products to high value products has concentrated on char upgrading to higher quality carbon black and to activated carbon. The use of catalysts to upgrade the oil to a aromatic-rich chemical feedstock or the production of hydrogen from waste tyres has also been reported. Examples of commercial and semi-commercial scale tyre pyrolysis systems show that small scale batch reactors and continuous rotary kiln reactors have been developed to commercial scale.

Williams, Paul T., E-mail: p.t.williams@leeds.ac.uk

2013-08-15T23:59:59.000Z

199

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of polymer waste comprising nylon 6 and a polyolefin or mixtures of polyolefins to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

Evans, R.J.; Chum, H.L.

1994-10-25T23:59:59.000Z

200

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of polymer waste comprising nylon 6 and a polyolefin or mixtures of polyolefins to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Biomass Feedstock and Conversion Supply System Design and Analysis  

SciTech Connect (OSTI)

Idaho National Laboratory (INL) supports the U.S. Department of Energy’s bioenergy research program. As part of the research program INL investigates the feedstock logistics economics and sustainability of these fuels. A series of reports were published between 2000 and 2013 to demonstrate the feedstock logistics cost. Those reports were tailored to specific feedstock and conversion process. Although those reports are different in terms of conversion, some of the process in the feedstock logistic are same for each conversion process. As a result, each report has similar information. A single report can be designed that could bring all commonality occurred in the feedstock logistics process while discussing the feedstock logistics cost for different conversion process. Therefore, this report is designed in such a way that it can capture different feedstock logistics cost while eliminating the need of writing a conversion specific design report. Previous work established the current costs based on conventional equipment and processes. The 2012 programmatic target was to demonstrate a delivered biomass logistics cost of $55/dry ton for woody biomass delivered to fast pyrolysis conversion facility. The goal was achieved by applying field and process demonstration unit-scale data from harvest, collection, storage, preprocessing, handling, and transportation operations into INL’s biomass logistics model. The goal of the 2017 Design Case is to enable expansion of biofuels production beyond highly productive resource areas by breaking the reliance of cost-competitive biofuel production on a single, low-cost feedstock. The 2017 programmatic target is to supply feedstock to the conversion facility that meets the in-feed conversion process quality specifications at a total logistics cost of $80/dry T. The $80/dry T. target encompasses total delivered feedstock cost, including both grower payment and logistics costs, while meeting all conversion in-feed quality targets. The 2012 $55/dry T. programmatic target included only logistics costs with a limited focus on biomass quantity, quality and did not include a grower payment. The 2017 Design Case explores two approaches to addressing the logistics challenge: one is an agronomic solution based on blending and integrated landscape management and the second is a logistics solution based on distributed biomass preprocessing depots. The concept behind blended feedstocks and integrated landscape management is to gain access to more regional feedstock at lower access fees (i.e., grower payment) and to reduce preprocessing costs by blending high quality feedstocks with marginal quality feedstocks. Blending has been used in the grain industry for a long time; however, the concept of blended feedstocks in the biofuel industry is a relatively new concept. The blended feedstock strategy relies on the availability of multiple feedstock sources that are blended using a least-cost formulation within an economical supply radius, which, in turn, decreases the grower payment by reducing the amount of any single biomass. This report will introduce the concepts of blending and integrated landscape management and justify their importance in meeting the 2017 programmatic goals.

Jacob J. Jacobson; Mohammad S. Roni; Patrick Lamers; Kara G. Cafferty

2014-09-01T23:59:59.000Z

202

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat PumpRecord ofESPCof EnergyHouse11 DOE Hydrogen andProgram T OStaffparteEx-Situ

203

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S. Improving Fan System PerformanceIn

204

Biomass to Gasoline and DIesel Using Integrated Hydropyrolysis and Hydroconversion  

SciTech Connect (OSTI)

Cellulosic and woody biomass can be directly converted to hydrocarbon gasoline and diesel blending components through the use of integrated hydropyrolysis plus hydroconversion (IH2). The IH2 gasoline and diesel blending components are fully compatible with petroleum based gasoline and diesel, contain less than 1% oxygen and have less than 1 total acid number (TAN). The IH2 gasoline is high quality and very close to a drop in fuel. The DOE funding enabled rapid development of the IH2 technology from initial proof-of-principle experiments through continuous testing in a 50 kg/day pilot plant. As part of this project, engineering work on IH2 has also been completed to design a 1 ton/day demonstration unit and a commercial-scale 2000 ton/day IH2 unit. These studies show when using IH2 technology, biomass can be converted directly to transportation quality fuel blending components for the same capital cost required for pyrolysis alone, and a fraction of the cost of pyrolysis plus upgrading of pyrolysis oil. Technoeconomic work for IH2 and lifecycle analysis (LCA) work has also been completed as part of this DOE study and shows IH2 technology can convert biomass to gasoline and diesel blending components for less than $2.00/gallon with greater than 90% reduction in greenhouse gas emissions. As a result of the work completed in this DOE project, a joint development agreement was reached with CRI Catalyst Company to license the IH2 technology. Further larger-scale, continuous testing of IH2 will be required to fully demonstrate the technology, and funding for this is recommended. The IH2 biomass conversion technology would reduce U.S. dependence on foreign oil, reduce the price of transportation fuels, and significantly lower greenhouse gas (GHG) emissions. It is a breakthrough for the widespread conversion of biomass to transportation fuels.

Marker, Terry; Roberts, Michael; Linck, Martin; Felix, Larry; Ortiz-Toral, Pedro; Wangerow, Jim; Tan, Eric; Gephart, John; Shonnard, David

2013-01-02T23:59:59.000Z

205

CATALYTIC BIOMASS LIQUEFACTION  

E-Print Network [OSTI]

LBL-11 019 UC-61 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,Catalytic Liquefaction of Biomass,n M, Seth, R. Djafar, G.of California. CATALYTIC BIOMASS LIQUEFACTION QUARTERLY

Ergun, Sabri

2013-01-01T23:59:59.000Z

206

CATALYTIC LIQUEFACTION OF BIOMASS  

E-Print Network [OSTI]

liquid Fuels from Biomass: "Catalyst Screening and KineticUC-61 (l, RCO osn CDL or BIOMASS CATALYTIC LIQUEFACTION ManuCATALYTIC LIQUEFACTION OF BIOMASS Manu Seth, Roger Djafar,

Seth, Manu

2012-01-01T23:59:59.000Z

207

Mixed-integer programming methods for supply chain optimization Christos Maravelias, University of Wisconsin -Madison  

E-Print Network [OSTI]

Zeolite upgrading Phenols &BTX Phenols &BTX AromaticsAromatics Fast pyrolysis Fast pyrolysis ­ industrial gases ­ chemicals SC under power constraints Biomass to fuels and chemicals #12;Mixed

Grossmann, Ignacio E.

208

Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis The in-situ catalytic fast pyrolysis pathway involves rapidly heating biomass with a catalyst to create bio-oils,...

209

Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis In ex-situ catalytic fast pyrolysis, biomass is heated with catalysts to create bio-oils, which are then used to...

210

Biomass Densification Workshop Overview  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

supply systems that ensure high- volume, reliable, and on-spec availability of biomass feedstocks. The United States has a diverse and abundant potential of biomass resources...

211

Biomass Analytical Library  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

diversity and performance, The chemical and physical properties of biomass and biomass feedstocks are characterized as they move through the supply chain to various conversion...

212

Pyrolysis Research: Bioenergy Testing and Analysis Laboratory BIOENERGY PROGRAM  

E-Print Network [OSTI]

Pyrolysis Research: Bioenergy Testing and Analysis Laboratory BIOENERGY PROGRAM Pyrolysis research is conducted at Texas A&M University at the Bioenergy Testing and Analysis Laboratory. Our researchers create

213

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

SciTech Connect (OSTI)

A process of using fast pyrolysis in a carrier gas to convert a polyamide containing a plastic waste feed stream having a mixed polymeric composition in a manner such that pyrolysis of a given polyamide and its high value monomeric constituent or derived high value products occurs prior to pyrolysis of other plastic components is described therein comprising: (a) selecting a first temperature program range to cause pyrolysis of said given polyamide and its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; (b) selecting a catalyst and a support and treating said feed stream with said catalyst to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent or high value product of said polyamide in said first temperature program range; (c) differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of said high value monomeric constituent or high value product of said polyamide prior to pyrolysis of other plastic components therein; (d) separating said high value monomer constituent or derived high value product of said polyamide; (e) selecting a second higher temperature program range to cause pyrolysis to a different high value monomeric constituent of said plastic waste and differentially heating said feed stream of said higher temperature program range to cause pyrolysis of said plastic into a different high value monomeric constituent or derived product; and (f) separating said different high value monomeric constituent or derived high value product.

Evans, R.J.; Chum, H.L.

1993-06-01T23:59:59.000Z

214

PYROLYSIS OF METHANE IN A SUPERSONIC, ARC-HEATED FLOW  

E-Print Network [OSTI]

1 PYROLYSIS OF METHANE IN A SUPERSONIC, ARC-HEATED FLOW F.K. Lu,* C.M. Roseberry, J.M. Meyers and D arc pyrolysis of methane at supersonic conditions, representative of conditions in the reformer- cate the feasibility of arc pyrolysis of methane. Introduction he high specific enthalpy of combustion

Texas at Arlington, University of

215

The direct observation of alkali vapor species in biomass combustion and gasification  

SciTech Connect (OSTI)

This report summarizes new data from screening various feedstocks for alkali vapor release under combustion conditions. The successful development of a laboratory flow reactor and molecular beam, mass spectrometer interface is detailed. Its application to several herbaceous and woody feedstocks, as well as a fast-pyrolysis oil, under 800 and 1,100{degrees}C batch combustion, is documented. Chlorine seems to play a large role in the facile mobilization of potassium. Included in the report is a discussion of relevant literature on the alkali problem in combustors and turbines. Highlighted are the phenomena identified in studies on coal and methods that have been applied to alkali speciation. The nature of binding of alkali in coal versus biomass is discussed, together with the implications for the ease of release. Herbaceous species and many agricultural residues appear to pose significant problems in release of alkali species to the vapor at typical combustor temperatures. These problems could be especially acute in direct combustion fired turbines, but may be ameliorated in integrated gasification combined cycles.

French, R.J.; Dayton, D.C.; Milne, T.A.

1994-01-01T23:59:59.000Z

216

Biomass treatment method  

DOE Patents [OSTI]

A method for treating biomass was developed that uses an apparatus which moves a biomass and dilute aqueous ammonia mixture through reaction chambers without compaction. The apparatus moves the biomass using a non-compressing piston. The resulting treated biomass is saccharified to produce fermentable sugars.

Friend, Julie (Claymont, DE); Elander, Richard T. (Evergreen, CO); Tucker, III; Melvin P. (Lakewood, CO); Lyons, Robert C. (Arvada, CO)

2010-10-26T23:59:59.000Z

217

Techno Economic Analysis of Hydrogen Production by gasification of biomass  

SciTech Connect (OSTI)

Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more general term, and includes heating as well as the injection of other ''ingredients'' such as oxygen and water. Pyrolysis alone is a useful first step in creating vapors from coal or biomass that can then be processed in subsequent steps to make liquid fuels. Such products are not the objective of this project. Therefore pyrolysis was not included in the process design or in the economic analysis. High-pressure, fluidized bed gasification is best known to GTI through 30 years of experience. Entrained flow, in contrast to fluidized bed, is a gasification technology applied at much larger unit sizes than employed here. Coal gasification and residual oil gasifiers in refineries are the places where such designs have found application, at sizes on the order of 5 to 10 times larger than what has been determined for this study. Atmospheric pressure gasification is also not discussed. Atmospheric gasification has been the choice of all power system pilot plants built for biomass to date, except for the Varnamo plant in Sweden, which used the Ahlstrom (now Foster Wheeler) pressurized gasifier. However, for fuel production, the disadvantage of the large volumetric flows at low pressure leads to the pressurized gasifier being more economical.

Francis Lau

2002-12-01T23:59:59.000Z

218

Mapping Biomass Distribution Potential  

E-Print Network [OSTI]

Mapping Biomass Distribution Potential Michael Schaetzel Undergraduate ? Environmental Studies ? University of Kansas L O C A T S I O N BIOMASS ENERGY POTENTIAL o According to DOE, Biomass has the potential to provide 14% of... the nation’s power o Currently 1% of national power supply o Carbon neutral? combustion of biomass is part of the natural carbon cycle o Improved crop residue management has potential to benefit environment, producers, and economy Biomass Btu...

Schaetzel, Michael

2010-11-18T23:59:59.000Z

219

Dual Layer Monolith ATR of Pyrolysis Oil for Distributed Synthesis Gas Production  

SciTech Connect (OSTI)

We have successfully demonstrated a novel reactor technology, based on BASF dual layer monolith catalyst, for miniaturizing the autothermal reforming of pyrolysis oil to syngas, the second and most critical of the three steps for thermochemically converting biomass waste to liquid transportation fuel. The technology was applied to aged as well as fresh samples of pyrolysis oil derived from five different biomass feedstocks, namely switch-grass, sawdust, hardwood/softwood, golden rod and maple. Optimization of process conditions in conjunction with innovative reactor system design enabled the minimization of carbon deposit and control of the H2/CO ratio of the product gas. A comprehensive techno-economic analysis of the integrated process using in part, experimental data from the project, indicates (1) net energy recovery of 49% accounting for all losses and external energy input, (2) weight of diesel oil produced as a percent of the biomass to be ~14%, and (3) for a �demonstration� size biomass to Fischer-Tropsch liquid plant of ~ 2000 daily barrels of diesel, the price of the diesel produced is ~$3.30 per gallon, ex. tax. However, the extension of catalyst life is critical to the realization of the projected economics. Catalyst deactivation was observed and the modes of deactivation, both reversible and irreversible were identified. An effective catalyst regeneration strategy was successfully demonstrated for reversible catalyst deactivation while a catalyst preservation strategy was proposed for preventing irreversible catalyst deactivation. Future work should therefore be focused on extending the catalyst life, and a successful demonstration of an extended (> 500 on-stream hours) catalyst life would affirm the commercial viability of the process.

Lawal, Adeniyi [Stevens Institute of Technology, Castle Point Hoboken NJ 07030

2012-09-29T23:59:59.000Z

220

Alternative Resources The Institute for Chemicals and Fuels from Alternative Resources (ICFAR)  

E-Print Network [OSTI]

fast pyrolysis of biomass · Developing fast pyrolysis of palm oil residues · Developing a new reactor-generation biofuels and chemicals using forestry residues, non-food crops and other sources of biomass, like municipal Briens to develop a mobile pyrolysis unit being tested at the institute · The Agri-Therm unit transforms

Denham, Graham

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Pyrolysis of Organic Molecules Relevant to Combustion as Monitored by Photoionization Time-of-Flight Mass Spectrometry  

E-Print Network [OSTI]

of Small Molecules by Flash Pyrolysis, University ofapproach of coupling flash pyrolysis of the compound ofZhang, Chairperson Flash pyrolysis coupled to molecular beam

Weber, Kevin Howard

2010-01-01T23:59:59.000Z

222

Thermal Decomposition of Molecules Relevant to Combustion and Chemical Vapor Deposition by Flash Pyrolysis Time-of-Flight Mass Spectrometry  

E-Print Network [OSTI]

of Small Molecules by Flash Pyrolysis, University ofwas performed using flash pyrolysis vacuum-ultraviolet time-Vapor Deposition by Flash Pyrolysis Time-of-Flight Mass

Lemieux, Jessy Mario

2013-01-01T23:59:59.000Z

223

Research on the pyrolysis of hardwood in an entrained bed process development unit  

SciTech Connect (OSTI)

An atmospheric flash pyrolysis process, the Georgia Tech Entrained Flow Pyrolysis Process, for the production of liquid biofuels from oak hardwood is described. The development of the process began with bench-scale studies and a conceptual design in the 1978--1981 timeframe. Its development and successful demonstration through research on the pyrolysis of hardwood in an entrained bed process development unit (PDU), in the period of 1982--1989, is presented. Oil yields (dry basis) up to 60% were achieved in the 1.5 ton-per-day PDU, far exceeding the initial target/forecast of 40% oil yields. Experimental data, based on over forty runs under steady-state conditions, supported by material and energy balances of near-100% closures, have been used to establish a process model which indicates that oil yields well in excess of 60% (dry basis) can be achieved in a commercial reactor. Experimental results demonstrate a gross product thermal efficiency of 94% and a net product thermal efficiency of 72% or more; the highest values yet achieved with a large-scale biomass liquefaction process. A conceptual manufacturing process and an economic analysis for liquid biofuel production at 60% oil yield from a 200-TPD commercial plant is reported. The plant appears to be profitable at contemporary fuel costs of $21/barrel oil-equivalent. Total capital investment is estimated at under $2.5 million. A rate-of-return on investment of 39.4% and a pay-out period of 2.1 years has been estimated. The manufacturing cost of the combustible pyrolysis oil is $2.70 per gigajoule. 20 figs., 87 tabs.

Kovac, R.J.; Gorton, C.W.; Knight, J.A.; Newman, C.J.; O'Neil, D.J. (Georgia Inst. of Tech., Atlanta, GA (United States). Research Inst.)

1991-08-01T23:59:59.000Z

224

Nitrogen chemistry during oil shale pyrolysis  

SciTech Connect (OSTI)

Real time evolution of ammonia (NH{sub 3}) and hydrogen cyanide (HCN), two major nitrogen-containing volatiles evolved during oil shale pyrolysis, was measured by means of a mass spectrometer using chemical ionization and by infrared spectroscopy. While the on-line monitoring of NH{sub 3} in oil shale pyrolysis games was possible by both techniques, HCN measurements were only possible by IR. We studied one Green River Formation oil shale and one New Albany oil shale. The ammonia from the Green River oil shale showed one broad NH{sub 3} peak maximizing at a high temperature. For both oil shales, most NH{sub 3} evolves at temperatures above oil-evolving temperature. The important factors governing ammonia salts such as Buddingtonite in Green River oil shales, the distribution of nitrogen functional groups in kerogen, and the retorting conditions. The gas phase reactions, such as NH{sub 3} decomposition and HCN conversion reactions, also play an important role in the distribution of nitrogen volatiles, especially at high temperatures. Although pyrolysis studies of model compounds suggests the primary nitrogen product from kerogen pyrolysis to be HCN at high temperatures, we found only a trace amount of HCN at oil-evolving temperatures and none at high temperatures (T {gt} 600{degree}C). 24 refs., 6 figs., 2 tabs.

Oh, Myongsook S.; Crawford, R.W.; Foster, K.G.; Alcaraz, A.

1990-01-10T23:59:59.000Z

225

Biomass Gasification | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Production Biomass Gasification Biomass Gasification Photo of switchgrass being swathed. The Program anticipates that biomass gasification could be deployed in the...

226

Sandia National Laboratories: Lignocellulosic Biomass  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ProgramLignocellulosic Biomass Lignocellulosic Biomass It is estimated that there is over 1 billion tons of non-food lignocellulosic biomass currently available on a sustainable...

227

BIOMASS ENERGY CONVERSION IN HAWAII  

E-Print Network [OSTI]

Report, (unpublished, 1979). Biomass Project Progress 31.Operations, vol. 2 of Biomass Energy (Stanford: StanfordPhotosynthethic Pathway Biomass Energy Production," ~c:_! _

Ritschard, Ronald L.

2013-01-01T23:59:59.000Z

228

Optimization of the pyrolysis process of empty fruit bunch (EFB) in a fixed-bed reactor through a central composite design (CCD)  

SciTech Connect (OSTI)

The production of crude palm oil from the processing of palm fresh fruit bunches in the palm oil mills in Malaysia hs resulted in a huge quantity of empty fruit bunch (EFB) accumulated. The EFB was used as a feedstock in the pyrolysis process using a fixed-bed reactor in the present study. The optimization of process parameters such as pyrolysis temperature (factor A), biomass particle size (factor B) and holding time (factor C) were investigated through Central Composite Design (CCD) using Stat-Ease Design Expert software version 7 with bio-oil yield considered as the response. Twenty experimental runs were conducted. The results were completely analyzed by Analysis of Variance (ANOVA). The model was statistically significant. All factors studied were significant with p-values < 0.05. The pyrolysis temperature (factor A) was considered as the most significant parameter because its F-value of 116.29 was the highest. The value of R{sup 2} was 0.9564 which indicated that the selected factors and its levels showed high correlation to the production of bio-oil from EFB pyrolysis process. A quadratic model equation was developed and employed to predict the highest theoretical bio-oil yield. The maximum bio-oil yield of 46.2 % was achieved at pyrolysis temperature of 442.15 °C using the EFB particle size of 866 ?m which corresponded to the EFB particle size in the range of 710–1000 ?m and holding time of 483 seconds.

Mohamed, Alina Rahayu; Hamzah, Zainab; Daud, Mohamed Zulkali Mohamed [School of Bioprocess Engineering, Jejawi Complex of Academics (3), UniMAP, 02600 Arau Perlis (Malaysia)

2014-07-10T23:59:59.000Z

229

Original article Root biomass and biomass increment in a beech  

E-Print Network [OSTI]

Original article Root biomass and biomass increment in a beech (Fagus sylvatica L.) stand in North ­ This study is part of a larger project aimed at quantifying the biomass and biomass increment been developed to estimate the biomass and biomass increment of coarse, small and fine roots of trees

Paris-Sud XI, Université de

230

Pretreated densified biomass products  

SciTech Connect (OSTI)

A product comprising at least one densified biomass particulate of a given mass having no added binder and comprised of a plurality of lignin-coated plant biomass fibers is provided, wherein the at least one densified biomass particulate has an intrinsic density substantially equivalent to a binder-containing densified biomass particulate of the same given mass and h a substantially smooth, non-flakey outer surface. Methods for using and making the product are also described.

Dale, Bruce E; Ritchie, Bryan; Marshall, Derek

2014-03-18T23:59:59.000Z

231

AVAILABLE NOW! Biomass Funding  

E-Print Network [OSTI]

AVAILABLE NOW! Biomass Funding Guide 2010 The Forestry Commission and the Humber Rural Partnership (co-ordinated by East Riding of Yorkshire Council) have jointly produced a biomass funding guide fuel prices continue to rise, and the emerging biomass sector is well-placed to make a significant

232

Accepted Manuscript Kinetic modelling of high density polyethylene pyrolysis: Part 2. Reduction of existing  

E-Print Network [OSTI]

Accepted Manuscript Kinetic modelling of high density polyethylene pyrolysis: Part 2. Reduction density polyethylene pyrolysis: Part 2. Reduction of existing detailed mechanism, Polymer Degradation Modelling of High Density PolyEthylene Pyrolysis: Part 2. Reduction of existing detailed mechanism. N

Paris-Sud XI, Université de

233

Effects of torrefaction and densification on switchgrass pyrolysis products  

SciTech Connect (OSTI)

Abstract The pyrolysis behaviors of four types of pretreated switchgrass (torrefied at 230 and 270 °C, densification, and torrefaction at 270 şC followed by densification) were studied at three temperatures (500, 600, 700 şC) using a pyroprobe attached to a gas chromatogram mass spectroscopy (Py-GC/MS). The torrefaction of switchgrass improved its oxygen to carbon ratio and energy content. Contents of anhydrous sugars and phenols in pyrolysis products of torrefied switchgrass were higher than those in pyrolysis products of raw switchgrass. As the torrefaction temperature increased from 230 to 270 °C, the contents of anhydrous sugars and phenols in pyrolysis products increased whereas content of guaiacols decreased. High pyrolysis temperature (600 and 700 °C as compared to 500 °C) enhanced decomposition of lignin and anhydrous sugars, leading to increase in phenols, aromatics and furans. Densification enhanced depolymerization of cellulose and hemicellulose during pyrolysis.

Yang, Z; Sarkar, M; Kumar, A; Jaya Shankar Tumuluru; R.L. Huhnke

2014-10-01T23:59:59.000Z

234

Fast Beam Studies of Free Radical Photodissociation  

E-Print Network [OSTI]

radicals. 37 They employ a flash pyrolysis source, having abond on undergoing flash pyrolysis. Our approach to the

Cyr, D.R.

2010-01-01T23:59:59.000Z

235

Char reactions during kraft black liquor pyrolysis  

SciTech Connect (OSTI)

The pyrolysis characteristics of dried black liquor particles were investigated at high heating rates in a laminar entrained-flow reactor at temperatures of 600-1100{degrees}C. Primary pyrolysis of the organic fraction occurred very rapidly, in less 0.5 seconds. Char yields at the end or volatiles evolution were 58-72%. The decreased with increasing reactor temperature to 900{degrees}C but remained constant at higher temperatures. 35-65% of the fuel nitrogen was volatilized, nearly all in less than 0.5 s. Relatively little fuel nitrogen was evolved from the char. Significant alkali metal chloride volatization from the char occurred at all temperatures, while additional sodium volatilization became important above 900{degrees}C. Reduction of sulfur species in the char increased rapidly with increasing temperature. A temperature-dependent delay time in the onset of Na{sub 2}S formation was observed.

Frederick, W.J.; Sricharoenchaikul, V.; Reis, V.V. [Oregon State Univ., Corvallis, OR (United States)

1995-12-01T23:59:59.000Z

236

A study of pyrolysis of Texas lignites  

E-Print Network [OSTI]

better correlation for Dulong's formula. Yegua and Dakota lignites are readily obtainable and would provide a good check on the results derived from the Calvert Bluff lignites. The present equ1pment would also be used to study gasification of lignite...A STUDY OF PYROLYSIS OF TEXAS LIGNITES A Thesis by Robert A. Clark, Jr. Submitted to the Graduate College of Texas AAN University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE Nay 1979 Major Subject...

Clark, Robert A

1979-01-01T23:59:59.000Z

237

Utilization of pyrolysis oil in industrial scale boilers.  

E-Print Network [OSTI]

??The performance of pyrolysis oil in a large-scale combustion system is investigated to determine the feasibility of displacing fuel oil or natural gas in current… (more)

Redfern, Kyle D.

2013-01-01T23:59:59.000Z

238

Process for minimizing solids contamination of liquids from coal pyrolysis  

DOE Patents [OSTI]

In a continuous process for recovery of liquid hydrocarbons from a solid carbonaceous material by pyrolysis of the carbonaceous material in the presence of a particulate source of heat, particulate contamination of the liquid hydrocarbons is minimized. This is accomplished by removing fines from the solid carbonaceous material feed stream before pyrolysis, removing fines from the particulate source of heat before combining it with the carbonaceous material to effect pyrolysis of the carbonaceous material, and providing a coarse fraction of reduced fines content of the carbon containing solid residue resulting from the pyrolysis of the carbonaceous material before oxidizing carbon in the carbon containing solid residue to form the particulate source of heat.

Wickstrom, Gary H. (Yorba Linda, CA); Knell, Everett W. (Los Alamitos, CA); Shaw, Benjamin W. (Costa Mesa, CA); Wang, Yue G. (West Covina, CA)

1981-04-21T23:59:59.000Z

239

Understanding Biomass Feedstock Variability  

SciTech Connect (OSTI)

If the singular goal of biomass logistics and the design of biomass feedstock supply systems is to reduce the per ton supply cost of biomass, these systems may very well develop with ultimate unintended consequences of highly variable and reduced quality biomass feedstocks. This paper demonstrates that due to inherent species variabilities, production conditions, and differing harvest, collection, and storage practices, this is a very real scenario that biomass producers and suppliers as well as conversion developers should be aware of. Biomass feedstock attributes of ash, carbohydrates, moisture, and particle morphology will be discussed. We will also discuss specifications for these attributes, inherent variability of these attributes in biomass feedstocks, and approaches and solutions for reducing variability for improving feedstock quality.

Kevin L. Kenney; William A. Smith; Garold L. Gresham; Tyler L. Westover

2013-01-01T23:59:59.000Z

240

Understanding Biomass Feedstock Variability  

SciTech Connect (OSTI)

If the singular goal of biomass logistics and the design of biomass feedstock supply systems is to reduce the per-ton supply cost of biomass, these systems may very well develop with ultimate unintended consequences of highly variable and reduced quality biomass feedstocks. This paper demonstrates that, due to inherent species variabilities, production conditions and differing harvest, collection and storage practices, this is a very real scenario that biomass producers and suppliers as well as conversion developers should be aware of. Biomass feedstock attributes of ash, carbohydrates, moisture and particle morphology will be discussed. We will also discuss specifications for these attributes, inherent variability of these attributes in biomass feedstocks, and approaches and solutions for reducing variability for improving feedstock quality.

Kevin L. Kenney; Garold L. Gresham; William A. Smith; Tyler L. Westover

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

NREL: Biomass Research - Biomass Characterization Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biomass Characterization Projects A photo of a magnified image on a computer screen. Many blue specks and lines in different sizes and shapes are visible on top of a white...

242

E-Print Network 3.0 - aromatic compounds Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

243

E-Print Network 3.0 - aromatic rings synthesis Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

244

E-Print Network 3.0 - aromatic compounds part Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for Energy Innovation, an Energy... Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

245

E-Print Network 3.0 - aromatic compounds derived Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

246

E-Print Network 3.0 - aromatic plant production Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

"Production of green aromatics... Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

247

E-Print Network 3.0 - aromatic molecules suggested Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

results have shown that these new... Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

248

E-Print Network 3.0 - aromatic c48n12 azafullerene Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

249

E-Print Network 3.0 - aromatic blending compounds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

250

E-Print Network 3.0 - aromatic compounds progress Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

251

E-Print Network 3.0 - aromatic compound mixtures Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

252

E-Print Network 3.0 - aromatic compounds effects Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

253

E-Print Network 3.0 - aromatic molecules mini-review Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

results have shown that these new... Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

254

Hydrogen Generation for Refineries  

Broader source: Energy.gov (indexed) [DOE]

bottoms (VTB), vacuum resid) * Dilbit (tar sand bitumen diluted with 30% condensate) * Biomass fast pyrolysis oil (whole raw oil) * Norpar 12 (C 11 C 12 paraffinic solvent -...

255

E-Print Network 3.0 - aromatic geranyl derivatives Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

256

E-Print Network 3.0 - aromatic substitution reaction Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

257

E-Print Network 3.0 - aromatic reactive intermediates Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and allene as intermediates... Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

258

E-Print Network 3.0 - aromatic molecules application Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

results have shown that these new... Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

259

ef501714j 1..9  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

yielding approximately 310 million oven dry Megagrams for bioenergy production. 2 Fast-pyrolysis technologies to convert woody biomass to bio- oil and biochar are becoming more...

260

Determining the Effect of Concerted Elimination Reactions in the Pyrolysis of Lignin Using Model Compounds  

SciTech Connect (OSTI)

Lignin pyrolysis is a significant impediment in forming liquid fuel from biomass. Lignin pyrolyzes at a higher temperature than other biomass components (ie cellulose, hemicellulose) and tends to form radicals which lead to cross linking and ultimately char formation. A primary step in advances biomass-to-fuel technology will be to discover mechanisms that can disassemble lignin at lower temperatures and depolymerize lignin into more stable products. We have investigated the thermochemistry of the various inter-linkage units found in lignin ({beta}-O4, {alpha}-O4, {beta}-{beta}, {beta}-O5, etc) using electronic structure calculations at the M06-2x/6-311++G(d,p) on a series of dimer model compounds. In addition to the usually-assumed bond homolysis reactions, we have investigated a variety of concerted elimination pathways that will tend to produce closed-shell stable products. Such a bottom-up approach could aid in the targeted development of catalysts that produce more desirable products under less severe reactor conditions.

Robichaud, D.; Clark, J.; Nimlos, M.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Modeling of Coal Drying before Pyrolysis Damintode Kolani1, a  

E-Print Network [OSTI]

in the coal without chemical decomposition and pyrolysis converts dry coal into gas and coke [1]. The final1 Modeling of Coal Drying before Pyrolysis Damintode Kolani1, a , Eric Blond1, b , Alain Gasser1 Forbach, France a damintode.kolani@univ-orleans.fr, b eric.blond@univ-orleans.fr Keywords: coal, drying

Paris-Sud XI, Université de

262

Complex pendulum biomass sensor  

DOE Patents [OSTI]

A complex pendulum system biomass sensor having a plurality of pendulums. The plurality of pendulums allow the system to detect a biomass height and density. Each pendulum has an angular deflection sensor and a deflector at a unique height. The pendulums are passed through the biomass and readings from the angular deflection sensors are fed into a control system. The control system determines whether adjustment of machine settings is appropriate and either displays an output to the operator, or adjusts automatically adjusts the machine settings, such as the speed, at which the pendulums are passed through the biomass. In an alternate embodiment, an entanglement sensor is also passed through the biomass to determine the amount of biomass entanglement. This measure of entanglement is also fed into the control system.

Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Perrenoud, Ben C. (Rigby, ID)

2007-12-25T23:59:59.000Z

263

Biomass Processing Photolibrary  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

Research related to bioenergy is a major focus in the U.S. as science agencies, universities, and commercial labs seek to create new energy-efficient fuels. The Biomass Processing Project is one of the funded projects of the joint USDA-DOE Biomass Research and Development Initiative. The Biomass Processing Photolibrary has numerous images, but there are no accompanying abstracts to explain what you are seeing. The project website, however, makes available the full text of presentations and publications and also includes an exhaustive biomass glossary that is being developed into an ASAE Standard.

264

Co-firing biomass  

SciTech Connect (OSTI)

Concern about global warming has altered the landscape for fossil-fuel combustion. The advantages and challenges of co-firing biomass and coal are discussed. 2 photos.

Hunt, T.; Tennant, D. [Hunt, Guillot & Associates LLC (United States)

2009-11-15T23:59:59.000Z

265

Biomass 2013 Attendee List | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Attendee List Biomass 2013 Attendee List This is a list of attendees for the Biomass 2013 conference. biomass2013attendeelist.pdf More Documents & Publications Biomass 2013...

266

Biomass Torrefaction Process Review and Moving Bed Torrefaction System Model Development  

SciTech Connect (OSTI)

Torrefaction is currently developing as an important preprocessing step to improve the quality of biomass in terms of physical properties, and proximate and ultimate composition. Torrefaction is a slow heating of biomass in an inert or reduced environment to a maximum temperature of 300°C. Torrefaction can also be defined as a group of products resulting from the partially controlled and isothermal pyrolysis of biomass occurring in a temperature range of 200–230şC and 270–280şC. Thus, the process can also be called a mild pyrolysis as it occurs at the lower temperature range of the pyrolysis process. At the end of the torrefaction process, a solid uniform product with lower moisture content and higher energy content than raw biomass is produced. Most of the smoke-producing compounds and other volatiles are removed during torrefaction, producing a final product that will have a lower mass but a higher heating value. An important aspect of research is to establish a degree of torrefaction where gains in heating value offset the loss of mass. There is a lack of literature on torrefaction reactor designs and a design sheet for estimating the dimensions of the torrefier based on capacity. This study includes a) conducting a detailed review on the torrefaction of biomass in terms of understanding the process, product properties, off-gas compositions, and methods used, and b) to design a moving bed torrefier, taking into account the basic fundamental heat and mass transfer calculations. Specific objectives include calculating the dimensions like diameter and height of the moving packed bed for different capacities, designing the heat loads and gas flow rates, and developing an interactive excel sheet where the user can define design specifications. In this report, 25–1000 kg/hr are used in equations for the design of the torrefier, examples of calculations, and specifications for the torrefier.

Jaya Shakar Tumuluru; Shahab Sokhansanj; Christopher T. Wright

2010-08-01T23:59:59.000Z

267

Biomass Torrefaction Process Review and Moving Bed Torrefaction System Model Development  

SciTech Connect (OSTI)

Torrefaction is currently developing as an important preprocessing step to improve the quality of biomass in terms of physical properties, and proximate and ultimate composition. Torrefaction is a slow heating of biomass in an inert or reduced environment to a maximum temperature of 300 C. Torrefaction can also be defined as a group of products resulting from the partially controlled and isothermal pyrolysis of biomass occurring in a temperature range of 200-230 C and 270-280 C. Thus, the process can also be called a mild pyrolysis as it occurs at the lower temperature range of the pyrolysis process. At the end of the torrefaction process, a solid uniform product with lower moisture content and higher energy content than raw biomass is produced. Most of the smoke-producing compounds and other volatiles are removed during torrefaction, producing a final product that will have a lower mass but a higher heating value. An important aspect of research is to establish a degree of torrefaction where gains in heating value offset the loss of mass. There is a lack of literature on torrefaction reactor designs and a design sheet for estimating the dimensions of the torrefier based on capacity. This study includes (a) conducting a detailed review on the torrefaction of biomass in terms of understanding the process, product properties, off-gas compositions, and methods used, and (b) to design a moving bed torrefier, taking into account the basic fundamental heat and mass transfer calculations. Specific objectives include calculating the dimensions like diameter and height of the moving packed bed for different capacities, designing the heat loads and gas flow rates, and developing an interactive excel sheet where the user can define design specifications. In this report, 25-1000 kg/hr are used in equations for the design of the torrefier, examples of calculations, and specifications for the torrefier.

Jaya Shakar Tumuluru; Shahab Sokhansanj; Christopher T. Wright; Richard D. Boardman

2010-08-01T23:59:59.000Z

268

Biomass One Biomass Facility | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarre BiomassTHIS PAGE IS UNDER(Redirected fromOne Biomass

269

NREL: Biomass Research - Projects in Biomass Process and Sustainabilit...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Projects in Biomass Process and Sustainability Analyses Researchers at NREL use biomass process and sustainability analyses to understand the economic, technical, and global...

270

Biomass Research Program  

ScienceCinema (OSTI)

INL's mission is to achieve DOE's vision of supplying high-quality raw biomass; preprocessing biomass into advanced bioenergy feedstocks; and delivering bioenergy commodities to biorefineries. You can learn more about research like this at the lab's facebook site http://www.facebook.com/idahonationallaboratory.

Kenney, Kevin; Wright, Christopher; Shelton-Davis, Colleen

2013-05-28T23:59:59.000Z

271

Biomass Research Program  

SciTech Connect (OSTI)

INL's mission is to achieve DOE's vision of supplying high-quality raw biomass; preprocessing biomass into advanced bioenergy feedstocks; and delivering bioenergy commodities to biorefineries. You can learn more about research like this at the lab's facebook site http://www.facebook.com/idahonationallaboratory.

Kenney, Kevin; Wright, Christopher; Shelton-Davis, Colleen

2011-01-01T23:59:59.000Z

272

Module Handbook Specialisation Biomass Energy  

E-Print Network [OSTI]

Module Handbook Specialisation Biomass Energy 2nd Semester for the Master Programme REMA/EUREC Course 2008/2009 University of Zaragoza Specialisation Provider: Biomass Energy #12;Specialisation Biomass Energy, University of Zaragoza Modul: Introduction and Basic Concepts

Damm, Werner

273

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY to treatment prescriptions and anticipated outputs of sawlogs and biomass fuel? How many individual operations biomass fuel removed. Typically in plantations. 50% No harvest treatment

274

Computational Analysis of the Pyrolysis of ..beta..-O4 Lignin Model Compounds: Concerted vs. Homolytic Fragmentation  

SciTech Connect (OSTI)

The thermochemical conversion of biomass to liquid transportation fuels is a very attractive technology for expanding the utilization of carbon neutral processes and reducing dependency on fossil fuel resources. As with all such emerging technologies, biomass conversion through gasification or pyrolysis has a number of obstacles that need to be overcome to make these processes cost competitive with the refining of fossil fuels. Our current efforts have focused on the investigation of the thermochemistry of the linkages between lignin units using ab initio calculations on dimeric lignin model compounds. All calculations were carried out using M062X density functional theory at the 6-311++G(d,p) basis set. The M062X method has been shown to be consistent with the CBS-QB3 method while being significantly less computationally expensive. To date we have only completed the study on the b-O4 compounds. The theoretical calculations performed in the study indicate that concerted elimination pathways dominate over bond homolysis reactions under typical pyrolysis conditions. However, this does not mean that concerted elimination will be the dominant loss process for lignin. Bimolecular radical chemistry could very well dwarf the unimolecular pathways investigated in this study. These concerted pathways tend to form stable, reasonably non-reactive products that would be more suited producing a fungible bio-oil for the production of liquid transportation fuels.

Clark, J. M.; Robichaud, D. J.; Nimlos, M. R.

2012-01-01T23:59:59.000Z

275

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY Citation: USDA Forest Service, Pacific Southwest Research Station. 2009. Biomass to Energy: Forest

276

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY study. The Biomass to Energy (B2E) Project is exploring the ecological and economic consequences

277

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY .................................................................................... 33 3.3 BIOMASS POWER PLANT OPERATION MODELS AND DATA

278

NREL: Biomass Research - Thomas Foust  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Photo of Thomas Foust Dr. Thomas Foust is an internationally recognized expert in the biomass field. His areas of expertise include feedstock production, biomass-to-fuels...

279

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY and continuously between the earth's biomass and atmosphere. From a greenhouse gas perspective, forest treatments

280

NREL: Biomass Research - Video Text  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

common corn grain ethanol. Cellulosic ethanol is made from organic plant matter called biomass. The video shows different forms of biomass such as switchgrass, corn stalks, and...

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

NREL: Biomass Research - Amie Sluiter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Center in Golden, Colorado. Research Interests Amie Sluiter began research in the biomass-to-ethanol field in 1996. She joined the Biomass Analysis Technologies team to...

282

Bioconversion of biomass to methane  

SciTech Connect (OSTI)

The conversion of biomass to methane is described. The biomethane potentials of various biomass feedstocks from our laboratory and literature is summarized.

Hashimoto, A.G. [Oregon State Univ., Corvallis, OR (United States)

1995-12-01T23:59:59.000Z

283

Biomass Energy Resources and Technologies  

Broader source: Energy.gov [DOE]

This page provides a brief overview of biomass energy resources and technologies supplemented by specific information to apply biomass within the Federal sector.

284

NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC.  

E-Print Network [OSTI]

, including 10% post consumer waste. #12;iii Executive Summary Pyrolysis of biomass followed Cycle Assessment of Gasoline and Diesel Produced via Fast Pyrolysis and Hydroprocessing David D. Hsu Fast Pyrolysis and Hydroprocessing David D. Hsu Prepared under Task No. BB07.7511 Technical Report NREL

285

WP 3 Report: Biomass Potentials Biomass production potentials  

E-Print Network [OSTI]

WP 3 Report: Biomass Potentials 1 Biomass production potentials in Central and Eastern Europe under different scenarios Final report of WP3 of the VIEWLS project, funded by DG-Tren #12;WP 3 Report: Biomass Potentials 2 Report Biomass production potentials in central and Eastern Europe under different scenarios

286

Fluidized bed selective pyrolysis of coal  

DOE Patents [OSTI]

The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyses the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step. 9 figs.

Shang, J.Y.; Cha, C.Y.; Merriam, N.W.

1992-12-15T23:59:59.000Z

287

Pyrolysis of shale oil vacuum distillate fractions  

SciTech Connect (OSTI)

The freezing point of US Navy jet fuel (JP-5) has been related to the amounts of large n-alkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how the n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30, and 32 ppM in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

Hazlett, R.N.; Beal, E.

1983-01-01T23:59:59.000Z

288

Pyrolysis of shale oil vacuum distillate fractions  

SciTech Connect (OSTI)

The freezing point of U.S. Navy jet fuel (JP-5) has been related to the amounts of large nalkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how th n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30 and 32 ppm in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

Hazlett, R.N.; Beal, E.

1983-02-01T23:59:59.000Z

289

Technical Information Exchange on Pyrolysis Oil: Potential for...  

Broader source: Energy.gov (indexed) [DOE]

Renewab;e Heating Oil Substation Fuel in New England Technical Information Exchange on Pyrolysis Oil: Potential for a Renewab;e Heating Oil Substation Fuel in New England This...

290

Review on Biomass Torrefaction Process and Product Properties and Design of Moving Bed Torrefaction System Model Development  

SciTech Connect (OSTI)

A Review on Torrefaction Process and Design of Moving Bed Torrefaction System for Biomass Processing Jaya Shankar Tumuluru1, Shahab Sokhansanj2 and Christopher T. Wright1 Idaho National Laboratory Biofuels and Renewable Energy Technologies Department Idaho Falls, Idaho 83415 Oak Ridge National Laboratory Bioenergy Resource and Engineering Systems Group Oak Ridge, TN 37831 Abstract Torrefaction is currently developing as an important preprocessing step to improve the quality of biomass in terms of physical properties, and proximate and ultimate composition. Torrefaction is a slow heating of biomass in an inert or reduced environment to a maximum temperature of 300 C. Torrefaction can also be defined as a group of products resulting from the partially controlled and isothermal pyrolysis of biomass occurring in a temperature range of 200-230 C and 270-280 C. Thus, the process can also be called a mild pyrolysis as it occurs at the lower temperature range of the pyrolysis process. At the end of the torrefaction process, a solid uniform product with lower moisture content and higher energy content than raw biomass is produced. Most of the smoke-producing compounds and other volatiles are removed during torrefaction, which produces a final product that will have a lower mass but a higher heating value. There is a lack of literature on the design aspects of torrefaction reactor and a design sheet for estimating the dimensions of the torrefier based on capacity. This study includes (a) conducting a detailed review on the torrefaction of biomass in terms of understanding the process, product properties, off-gas compositions, and methods used, and (b) to design a moving bed torrefier, taking into account the basic fundamental heat and mass transfer calculations. Specific objectives include calculating the dimensions like diameter and height of the moving packed bed torrefier for different capacities ranging from 25-1000 kg/hr, designing the heat loads and gas flow rates, and developing an interactive excel sheet where the user can define design specifications.

Jaya Shankar Tumuluru; Christopher T. Wright; Shahab Sokhansanj

2011-08-01T23:59:59.000Z

291

Strategic Biomass Solutions (Mississippi)  

Broader source: Energy.gov [DOE]

The Strategic Biomass Solutions (SBS) was formed by the Mississippi Technology Alliance in June 2009. The purpose of the SBS is to provide assistance to existing and potential companies, investors...

292

DOE 2014 Biomass Conference  

Broader source: Energy.gov [DOE]

Breakout Session 1C—Fostering Technology Adoption I: Building the Market for Renewables with High Octane Fuels DOE 2014 Biomass Conference Jim Williams, Senior Manager, American Petroleum Institute

293

Biomass Energy Production Incentive  

Broader source: Energy.gov [DOE]

In 2007 South Carolina enacted the ''Energy Freedom and Rural Development Act'', which provides production incentives for certain biomass-energy facilities. Eligible systems earn $0.01 per kilowatt...

294

BIOMASS ACTION PLAN FOR SCOTLAND  

E-Print Network [OSTI]

BIOMASS ACTION PLAN FOR SCOTLAND #12; #12;© Crown copyright 2007 ISBN: 978 0 7559 6506 9 Scottish% recyclable. #12;A BIOMASS ACTION PLAN FOR SCOTLAND #12;#12;1 CONTENTS FOREWORD 3 1. EXECUTIVE SUMMARY 5 2. INTRODUCTION 9 3. WIDER CONTEXT 13 4. SCOTLAND'S ROLE IN THE UK BIOMASS STRATEGY 17 5. BIOMASS HEATING 23 6

295

Auto shredder residue recycling: Mechanical separation and pyrolysis  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer In this work, we exploited mechanical separation and pyrolysis to recycle ASR. Black-Right-Pointing-Pointer Pyrolysis of the floating organic fraction is promising in reaching ELV Directive targets. Black-Right-Pointing-Pointer Zeolite catalyst improve pyrolysis oil and gas yield. - Abstract: sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a 'waste-to-chemicals' perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

Santini, Alessandro [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Passarini, Fabrizio, E-mail: fabrizio.passarini@unibo.it [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Vassura, Ivano [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Serrano, David; Dufour, Javier [Department of Chemical and Energy Technology, ESCET, Universidad Rey Juan Carlos, c/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Instituto IMDEA Energy, c/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Morselli, Luciano [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy)

2012-05-15T23:59:59.000Z

296

Production of valuable hydrocarbons by flash pyrolysis of oil shale  

DOE Patents [OSTI]

A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

Steinberg, M.; Fallon, P.T.

1985-04-01T23:59:59.000Z

297

The effect of clay catalyst on the chemical composition of bio-oil obtained by co-pyrolysis of cellulose and polyethylene  

SciTech Connect (OSTI)

Highlights: • Non-catalytic and catalytic fast pyrolysis of cellulose/polyethylene blend was carried out in a laboratory scale reactor. • Optimization of process temperature was done. • Optimization of clay catalyst type and amount for co-pyrolysis of cellulose and polyethylene was done. • The product yields and the chemical composition of bio-oil was investigated. - Abstract: Cellulose/polyethylene (CPE) mixture 3:1, w/w with and without three clay catalysts (K10 – montmorillonite K10, KSF – montmorillonite KSF, B – Bentonite) addition were subjected to pyrolysis at temperatures 400, 450 and 500 °C with heating rate of 100 °C/s to produce bio-oil with high yield. The pyrolytic oil yield was in the range of 41.3–79.5 wt% depending on the temperature, the type and the amount of catalyst. The non-catalytic fast pyrolysis at 500 °C gives the highest yield of bio-oil (79.5 wt%). The higher temperature of catalytic pyrolysis of cellulose/polyethylene mixture the higher yield of bio-oil is. Contrarily, increasing amount of montmorillonite results in significant, almost linear decrease in bio-oil yield followed by a significant increase of gas yield. The addition of clay catalysts to CPE mixture has a various influence on the distribution of bio-oil components. The addition of montmorillonite K10 to cellulose/polyethylene mixture promotes the deepest conversion of polyethylene and cellulose. Additionally, more saturated than unsaturated hydrocarbons are present in resultant bio-oils. The proportion of liquid hydrocarbons is the highest when a montmorillonite K10 is acting as a catalyst.

Solak, Agnieszka; Rutkowski, Piotr, E-mail: piotr.rutkowski@pwr.wroc.pl

2014-02-15T23:59:59.000Z

298

Biomass 2014 Poster Session  

Broader source: Energy.gov [DOE]

The U.S. Department of Energy’s Bioenergy Technologies Office (BETO) invites students, researchers, public and private organizations, and members of the general public to submit poster abstracts for consideration for the annual Biomass Conference Poster Session. The Biomass 2014 conference theme focuses on topics that are advancing the growth of the bioeconomy, such as improvements in feedstock logistics; promising, innovative pathways for advanced biofuels; and market-enabling co-products.

299

Biomass | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarre BiomassTHIS PAGE IS UNDER(RedirectedBiomass: Organic

300

Northeast Regional Biomass Program  

SciTech Connect (OSTI)

The Northeast Regional Biomass Program has been in operation for a period of nine years. During this time, state managed programs and technical programs have been conducted covering a wide range of activities primarily aim at the use and applications of wood as a fuel. These activities include: assessments of available biomass resources; surveys to determine what industries, businesses, institutions, and utility companies use wood and wood waste for fuel; and workshops, seminars, and demonstrations to provide technical assistance. In the Northeast, an estimated 6.2 million tons of wood are used in the commercial and industrial sector, where 12.5 million cords are used for residential heating annually. Of this useage, 1504.7 mw of power has been generated from biomass. The use of wood energy products has had substantial employment and income benefits in the region. Although wood and woodwaste have received primary emphasis in the regional program, the use of municipal solid waste has received increased emphasis as an energy source. The energy contribution of biomass will increase as potentia users become more familiar with existing feedstocks, technologies, and applications. The Northeast Regional Biomass Program is designed to support region-specific to overcome near-term barriers to biomass energy use.

Lusk, P.D.

1992-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Isothermal pyrolysis and char combustion of oil shales  

SciTech Connect (OSTI)

Yields and rates of hydrocarbons evolved during pyrolysis of oil shales have been measured with improved accuracy. Green River and New Albany oil shales were heated in a fluidized sand bed, and volatile pyrolysis products were transferred to a combustion tube and burned. Resulting H/sub 2/O and CO/sub 2 were detected in real time by mass spectrometry. Residual char was subsequently burned to allow complete C and H balances. Good closure was obtained. Proportions of organic C and H released as pyrolysis products and retained as char were determined. Shale oil loss due to the presence of oxidized shale in the fluidized bed was measured accurately. We find that all of the experimental apparatus that the pyrolysis gas contacts must be near pyrolysis temperature to avoid condensation of heavy oil which subsequently forms coke and secondary products. We observe a faster release of products with all transfer lines 450/degree/C than when they are at 300/degree/C. The current uncertainty in pyrolysis rates is due in part to such difficulties with experimental techniques. 12 refs., 7 figs., 1 tab.

Coburn, T.T.; Taylor, R.W.; Morris, C.J.; Duval, V.

1988-02-03T23:59:59.000Z

302

Working Group Meeting Presentation Guidance at a Glance Distributed Reforming of Biomass Pyrolysis Oils  

E-Print Network [OSTI]

(75%) Char (13%) Gas (12%) Catalytic Auto-thermal Reforming of Bio-Oil at 650oC: 0.71 CH1.98O0.76 + 0 Case (Ethanol Case) Bio-oil Storage Tank $106,040 Reformer $803,000 Shift Reactor, PSA, BOP $1 Oils DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting November 6

303

Renewable Hydrogen Production from Biomass Pyrolysis Aqueous Phase Presentation for BETO 2015 Project Peer Review  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L dDepartmentnews-flashes OfficeTexasEnergyFuel VehicleEnergy7,

304

NREL: Biomass Research - Biomass Characterization Capabilities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the Contributions and Achievements of Women |hitsAwards and Honors(PPS)WebmasterBiomass

305

Tracy Biomass Biomass Facility | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:Seadov Pty LtdSteen,LtdInformation Dixie Valley Geothermal Area (Reed,Tracy Biomass

306

A REVIEW ON BIOMASS DENSIFICATION TECHNOLOGIE FOR ENERGY APPLICATION  

SciTech Connect (OSTI)

The world is currently facing challenges to reduce the dependence on fossil fuels and to achieve a sustainable renewable supply. Renewable energies represent a diversity of energy sources that can help to maintain the equilibrium of different ecosystems. Among the various sources of renewable energy, biomass is finding more uses as it is considered carbon neutral since the carbondioxide released during its use is already part of the carbon cycle (Arias et al., 2008). Increasing the utilization of biomass for energy can help to reduce the negative CO2 impact on the environment and help to meet the targets established in the Kyoto Protocol (UN, 1998). Energy from biomass can be produced from different processes like thermochemical (combustion, gasification, and pyrolysis), biological (anaerobic digestion, fermentation) or chemical (esterification) where direct combustion can provide a direct near-term energy solution (Arias et al., 2008). Some of the inherent problems with raw biomass materials, like low bulk density, high moisture content, hydrophilic nature and low calorific value, limit the ease of use of biomass for energy purposes (Arias et al., 2008). In fact, due to its low energy density compared to fossil fuels, high volumes of biomass will be needed; adding to problems associated with storage, transportation and feed handling at a cogeneration plant. Furthermore, grinding biomass pulverizes, can be very costly and in some cases impractical. All of these drawbacks have given rise to the development of new technologies in order to increase the quality of biomass fuels. The purpose of the work is mainly in four areas 1) Overview of the torrefaction process and to do a literature review on i) Physical properties of torrefied raw material and torrefaction gas composition. 2) Basic principles in design of packed bed i) Equations governing the flow of material in packed bed ii) Equations governing the flow of the gases in packed bed iii) Effect of physical properties of the raw materials on the packed bed design 3) Design of packed bed torrefier of different capacities. 4) Development of an excel sheet for calculation of length and diameter of the packed bed column based on the design considerations.

JAYA SHANKAR TUMULURU; CHRISTOPHER T. WRIGHT

2010-08-01T23:59:59.000Z

307

November 2011 Model documentation for biomass,  

E-Print Network [OSTI]

1 November 2011 Model documentation for biomass, cellulosic biofuels, renewable of Education, Office of Civil Rights. #12;3 Contents Biomass.....................................................................................................................................................4 Variables in the biomass module

Noble, James S.

308

NREL: International Activities - Biomass Resource Assessment  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biomass Resource Assessment Map showing annual productivity of marginal lands in APEC economies. Biomass resource assessments quantify the existing or potential biomass material in...

309

NREL: Biomass Research - David W. Templeton  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

W. Templeton Photo of David Templeton David Templeton is the senior biomass analyst on the Biomass Analysis team (Biomass Compositional Analysis Laboratory) within the National...

310

UCSD Biomass to Power Economic Feasibility Study  

E-Print Network [OSTI]

Biofuels, LLC  UCSD Biomass to Power  Economic Feasibility Figure 1: West Biofuels Biomass Gasification to Power rates..……………………. ……31  UCSD Biomass to Power ? Feasibility 

Cattolica, Robert

2009-01-01T23:59:59.000Z

311

Transcript: Biomass Clean Cities Webinar - Workforce Development...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transcript: Biomass Clean Cities Webinar - Workforce Development Transcript: Biomass Clean Cities Webinar - Workforce Development Transcript of the BiomassClean Cities Workforce...

312

Comparison of concepts for thermal biomass utilization, with the example of the Netherlands  

SciTech Connect (OSTI)

Biomass and waste, which are the focus of the activities at the Thermal Power Engineering section of the TU Delft, are the most important renewable energies today. They will maintain their role in the future. There are different ways to convert biomass and waste to power and heat. The combustion of biomass can be considered state-of-the-art technology and plants ranging in capacity from a few kW up to several MW are available on the market. The selection of the combustion technology is dependent on the scale and the kind of biomass. Power can be produced by means of a steam turbine, which is attractive in units above 1 MW. Gasification, in contrast, is a technology that has yet to find a wide use. But, in combination with gas engines, gas turbines or fuel cells, gasification has the advantage of a high electrical efficiency. Direct co-combustion of biomass in coal-fired steam power plants is the most economic choice and it is widely applied in the Netherlands. By an additional pyrolysis or gasification step, it is possible to separately remove and utilize the ashes of coal and biomass, and expected operational problems, such as corrosion, can possibly be avoided. 3 refs., 4 figs., 2 tabs.

Spliethoff, H. [Technical University, Delft (Netherlands). Thermal Power Engineering Section

2004-07-01T23:59:59.000Z

313

Sustainable Biomass Supply Systems  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) aims to displace 30% of the 2004 gasoline use (60 billion gal/yr) with biofuels by 2030 as outlined in the Energy Independence and Security Act of 2007, which will require 700 million tons of biomass to be sustainably delivered to biorefineries annually. Lignocellulosic biomass will make an important contribution towards meeting DOE’s ethanol production goals. For the biofuels industry to be an economically viable enterprise, the feedstock supply system (i.e., moving the biomass from the field to the refinery) cannot contribute more that 30% of the total cost of the biofuel production. The Idaho National Laboratory in collaboration with Oak Ridge National Laboratory, University of California, Davis and Kansas State University are developing a set of tools for identifying economical, sustainable feedstocks on a regional basis based on biorefinery siting.

Erin Searcy; Dave Muth; Erin Wilkerson; Shahab Sokansanj; Bryan Jenkins; Peter Titman; Nathan Parker; Quinn Hart; Richard Nelson

2009-04-01T23:59:59.000Z

314

Biomass Scenario Model  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd: ScopeDepartment1, 2011 (BETO)and Fuel09BiomassAct ofBiomass

315

Biomass Anaerobic Digestion Facilities and Biomass Gasification Facilities (Indiana)  

Broader source: Energy.gov [DOE]

The Indiana Department of Environmental Management requires permits before the construction or expansion of biomass anaerobic digestion or gasification facilities.

316

General equations for Biomass Properties Nadge Richard1,2  

E-Print Network [OSTI]

of reaction, flash pyrolysis. This type of reaction yields higher amount of tar than slow pyrolysis. In [2 and the temperature of the particle during pyrolysis. These empirical correlations are found by curve fitting (see of 573 K -1173 K. Pyrolysis is a thermal decomposition of a product without any oxygen at high

317

Thermal Decomposition of Dichlorosilane Investigated by Pulsed Laser Powered Homogeneous Pyrolysis  

E-Print Network [OSTI]

of vacuum flash pyrolysis of SiH 2Cl2. Ban and Gilbert6 observed SiCl2 by mass spectrometry under sili- conThermal Decomposition of Dichlorosilane Investigated by Pulsed Laser Powered Homogeneous Pyrolysis powered homogeneous pyrolysis of dichlorosilane are reported. Pyrolyses at temperatures of 1350 to 1700 K

Swihart, Mark T.

318

Biomass Feedstock National User Facility  

Broader source: Energy.gov [DOE]

Breakout Session 1B—Integration of Supply Chains I: Breaking Down Barriers Biomass Feedstock National User Facility Kevin L. Kenney, Director, Biomass Feedstock National User Facility, Idaho National Laboratory

319

ENERGY FROM BIOMASS AND  

E-Print Network [OSTI]

in aeroderivative gas turbines has beencommerciallyestablished for natural gas-fired cogeneration since 1980. Steam!l!ledin a companionpaperprepared for this conference. 781 #12;BIOMASS-GASIFIER ~.INJECTED GAS TURBINE COGENERA110N FOR THE CANE of the gas turbine for cogeneration.applications(27) and the low unit capital cost of gas turbines comparedto

320

Biomass 2014 Attendee List | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biomass 2014 Attendee List Biomass 2014 Attendee List This document is the attendee list for Biomass 2014, held July 29-July 30 in Washington, D.C. biomass2014attendeelist.pdf...

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Production of low BTU gas from biomass  

E-Print Network [OSTI]

J. To utilize this untapped resource, several tech- nologies were proposed. Among them were pyrolysis, gasification and combustion. As the study group ' s objective was focused on actual farm usage, pyrolysis This thesis follows the style and format... for combustion is simple relative to the gasification or pyrolysis and construc- tion and operation of the necessary equipment should also be easier. However, the final product of com- bustion, steam energy, cannot be stored for long periods of time...

Lee, Yung N.

1981-01-01T23:59:59.000Z

322

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY;5-2 #12;APPENDIX 5: BIOMASS TO ENERGY PROJECT:WILDLIFE HABITAT EVALUATION 1. Authors: Patricia Manley Ross management scenarios. We evaluated the potential effects of biomass removal scenarios on biological diversity

323

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY as a result of emerging biomass opportunities on private industrial and public multiple-use lands (tracked in the vegetation domain) and the quantity of biomass consumed by the wildfire (tracked

324

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY;12-2 #12;Appendix 12: Biomass to Energy Project Team, Committee Members and Project Advisors Research Team. Nechodom's background is in biomass energy policy development and public policy research. Peter Stine

325

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY or recommendations of the study. 1. INTRODUCTION 1.1 Domain Description The study area for the Biomass to Energy (B2 and environmental costs and benefits of using forest biomass to generate electrical power while changing fire

326

Biomass Energy Crops: Massachusetts' Potential  

E-Print Network [OSTI]

Biomass Energy Crops: Massachusetts' Potential Prepared for: Massachusetts Division of Energy;#12;Executive Summary In Massachusetts, biomass energy has typically meant wood chips derived from the region's extensive forest cover. Yet nationally, biomass energy from dedicated energy crops and from crop residues

Schweik, Charles M.

327

13, 3226932289, 2013 Biomass burning  

E-Print Network [OSTI]

ACPD 13, 32269­32289, 2013 Biomass burning aerosol properties over the Northern Great Plains T (ACP). Please refer to the corresponding final paper in ACP if available. Biomass burning aerosol Geosciences Union. 32269 #12;ACPD 13, 32269­32289, 2013 Biomass burning aerosol properties over the Northern

Dong, Xiquan

328

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY;10-2 #12;Appendix 10: Power Plant Analysis for Conversion of Forest Remediation Biomass to Renewable Fuels and Electricity 1. Report to the Biomass to Energy Project (B2E) Principal Authors: Dennis Schuetzle, TSS

329

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY;6-2 #12;APPENDIX 6: Cumulative Watershed Effects Analysis for the Biomass to Energy Project 1. Principal the findings or recommendations of the study. Cumulative watershed effects (CWE) of the Biomass to Energy (B2E

330

7, 1733917366, 2007 Biomass burning  

E-Print Network [OSTI]

ACPD 7, 17339­17366, 2007 Biomass burning plumes during the AMMA wet season experiment C. H. Mari a Creative Commons License. Atmospheric Chemistry and Physics Discussions Tracing biomass burning plumes from. Mari (marc@aero.obs-mip.fr) 17339 #12;ACPD 7, 17339­17366, 2007 Biomass burning plumes during the AMMA

Paris-Sud XI, Université de

331

Reburn system with feedlot biomass  

DOE Patents [OSTI]

The present invention pertains to the use of feedlot biomass as reburn fuel matter to reduce NO.sub.x emissions. According to one embodiment of the invention, feedlot biomass is used as the reburn fuel to reduce NO.sub.x. The invention also includes burners and boiler in which feedlot biomass serves a reburn fuel.

Annamalai, Kalyan; Sweeten, John M.

2005-12-13T23:59:59.000Z

332

Integration of waste pyrolysis with coal/oil coprocessing  

SciTech Connect (OSTI)

HTI has developed a novel process, HTI CoPro Plus{trademark}, to produce alternative fuels and chemicals from the combined liquefaction of waste materials, coal, and heavy petroleum residues. Promising results have been obtained from a series of bench tests (PB-01 through PB-06) under the DOE Proof of Concept Program. Recently, HTI acquired a proven technology for the mild co-pyrolysis of used rubber tires and waste refinery or lube oils, developed by the University of Wyoming and Amoco. The feasibility of integration of pyrolysis with coal-oil coprocessing was studied in the eighth bench run (PB-08) of the program. The objective of Run PB-08 was to study the coprocessing of coal with oils derived from mild pyrolysis of scrap tires, waste plastics, and waste lube oils to obtain data required for economic comparisons with the DOE data base. A specific objective was also to study the performance of HTI`s newly improved GelCat{trademark} catalyst in coal-waste coprocessing under low-high (Reactor 1-Reactor 2 temperatures) operating mode. This paper presents the results obtained from Run PB-08, a 17-day continuous operation conducted in August 1997. A total of 5 conditions were tested, including a baseline coal-only condition. During the coprocessing conditions, 343{degrees}C+ pyrolysis oils derived from co-pyrolysis of rubber tires or a mixture of rubber tires and plastics with waste lube oil, were coprocessed with Black Thunder coal using HTI GelCat{trademark} catalyst. In the last condition, rubber tires were pyrolyzed with 524{degrees}C- coal liquid to study the possible elimination of lube oil used as pyrolysis processing oil. Overall coal conversion above 90 W% was achieved.

Hu, J.; Zhou, P.; Lee, T.L.K.; Comolli, A. [Hydrocarbon Technologies, Inc., Lawrenceville, NJ (United States)

1998-04-01T23:59:59.000Z

333

NREL: Biomass Research - Microalgal Biofuels Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

synthesis. Learn about microalgal biofuels capabilities. Printable Version Biomass Research Home Capabilities Projects Biomass Characterization Biochemical Conversion...

334

Federal Biomass Activities | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Federal Biomass Activities Federal Biomass Activities Statutory and executive order requirements for Bioproducts and Biofuels federalbiomassactivities.pdf More Documents &...

335

Pyrolysis of shale oil residual fractions  

SciTech Connect (OSTI)

The freezing point of JP-5, the Navy jet fuel, has been related to the n-alkane content, specifically n-hexadecane. In general, jet fuels from shale oil have the highest n-alkanes. The formation of n-alkanes in the jet fuel distillation range can be explained if large n-alkanes are present in the crude oil source. Quantities of large n-alkanes are insufficient, however, to explain the amounts found - up to 37% n-alkanes in the jet fuel range. Other possible precursors to small straight chain molecules are substituted cyclic compounds. Attack in the side chain obviously afford a path to an n-alkane. Aromatic hydrocarbons, esters, acids, amines, and ethers also have the potential to form n-alkanes if an unbranched alkyl chain is present in the molecule. Investigations showed that the best yield of the JP-5 cut comes at different times for the various fractions, but a time in the 60 to 120 min range would appear to be the optimum time for good yield at 450/sup 0/C. The longer time would be preferred with respect to lower potential n-alkane yield. None of the fractions gave n-alkane yields approaching the 37% amount found in the Shale-I JP-5. A temperature different than the 450/sup 0/C used here might affect the conversion percentage. Further the combined saturate, aromatic, and polar fractions may interact under pyrolysis conditions to give higher potential n-alkane yields than the fractions stressed independently.

Hazlett, R.N.; Beal, E.; Vetter, T.; Sonntag, R.; Moniz, W.

1980-01-01T23:59:59.000Z

336

Pyrolysis and Combustion of Acetonitrile (CH{sub 3}CN)  

SciTech Connect (OSTI)

Acetonitrile (CH{sub 3}CN) is formed from the thermal decomposition of a variety of cyclic, noncyclic, and polymeric nitrogen-containing compounds such as pyrrole and polyacrylonitrile. The pyrolysis and combustion of acetonitrile have been studied over the past 30 years to gain a more detailed understanding of the complex mechanisms involved in the release of nitrogen-containing compounds such as hydrogen cyanide (HCN) in fires and nitrogen oxides (NOx) in coal combustion. This report reviews the literature on the formation of HCN and NOx from the pyrolysis and combustion of acetonitrile and discusses the possible products found in an acetonitrile fire.

Britt, P.F.

2002-05-22T23:59:59.000Z

337

Biomass Supply and Carbon Accounting for  

E-Print Network [OSTI]

Biomass Supply and Carbon Accounting for Southeastern Forests February 2012 #12;This Biomass Supply and Carbon Accounting for Southeastern Forests study was conducted by the Biomass Energy Resource Center Biomass Energy Resource Center Kamalesh Doshi Biomass Energy Resource Center Hillary Emick Biomass Energy

338

Pyrolysis kinetics of scrap tire rubbers. 1: Using DTG and TGA  

SciTech Connect (OSTI)

Tire pyrolysis kinetics was investigated to explore an economically viable design for the pyrolysis process. Derivative thermogravimetry (DTG) and thermogravimetric analysis (TGA) were found to provide valuable information on pyrolysis kinetics and mechanisms of a heterogeneous compound like scrap tire rubbers. Kinetic parameters of each compositional compound were obtained by analyzing DTG and TGA results with a series of mathematical methods proposed in this study. The pyrolysis kinetics of the scrap tire rubbers tested was well accounted for by the first-order irreversible independent reactions of three compositional compounds. The sidewall and tread rubber exhibited different thermal degradation patterns, suggesting a compositional difference between them. Isothermal pyrolysis results showed that the sidewall rubber would hardly be degraded at low temperature regions (<600 K), whereas it would be more rapidly degraded than the tread rubber at higher temperatures ({>=}746 K). Because of the shorter pyrolysis time, the higher isothermal pyrolysis temperature appeared to be more economically favorable.

Kim, S.; Park, J.K. [Univ. of Wisconsin, Madison, WI (United States); Chun, H.D. [Research Inst. of Industrial Science and Technology, Pohang (Korea, Republic of)

1995-07-01T23:59:59.000Z

339

The Development of a Hydrothermal Method for Slurry Feedstock Preparation for Gasification Technology  

E-Print Network [OSTI]

Reactor for the Study of Biomass Pyrolysis Chemistry at Highmineral matter on biomass pyrolysis characteristics. Fuel,Puigjaner, Kinetics of Biomass Pyrolysis: ? a Reformulated

He, Wei

2011-01-01T23:59:59.000Z

340

Synthetic and Jet Fuels Pyrolysis for Cooling and Combustion Applications.  

E-Print Network [OSTI]

phenomenon (heat and mass transfers, pyrolysis, combustion) in a cooling channel surrounding a SCRamjet regeneratively cooled SCRamjet is provided to get a large vision of the fuel nature impact on the system of supersonic combustion ramjet (SCRamjet) [1]. For such high velocity, the total temperature of external air

Boyer, Edmond

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management  

E-Print Network [OSTI]

1 Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management : United States (2008)" #12;2 I. Introduction One of the main issues of the development of scramjet, an air to the endothermicity of its thermal decomposition. Because of the large heat load found in a scramjet, engine

Paris-Sud XI, Université de

342

European Market Study for BioOil (Pyrolysis Oil)  

E-Print Network [OSTI]

European Market Study for BioOil (Pyrolysis Oil) Dec 15, 2006 Doug Bradley President Climate Change Solutions National Team Leader- IEA Bioenergy Task 40- Bio-trade 402 Third Avenue ·Ottawa, Ontario ·Canada K. Market Determining Factors 5. EU Country Perspectives 6. Potential European Markets 6.1. Pulp Mill Lime

343

Pyrolysis of polyolefins for increasing the yield of monomers' recovery  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Thermal and catalytic pyrolysis of mixed polyolefins in fluidized bed has been studied. Black-Right-Pointing-Pointer We tested applicability of a commercial Ziegler-Natta catalyst (Z-N: TiCl{sub 4}/MgCl{sub 2}). Black-Right-Pointing-Pointer The catalyst has a strong influence on product distribution, increasing gas fraction. Black-Right-Pointing-Pointer At 650 Degree-Sign C the monomer generation increased by 55% when the catalyst was used. Black-Right-Pointing-Pointer We showed the concept of treatment of mixed polyolefins without a need of separation. - Abstract: Pyrolysis of plastic waste is an alternative way of plastic recovery and could be a potential solution for the increasing stream of solid waste. The objective of this work was to increase the yield the gaseous olefins (monomers) as feedstock for polymerization process and to test the applicability of a commercial Ziegler-Natta (Z-N): TiCl{sub 4}/MgCl{sub 2} for cracking a mixture of polyolefins consisted of 46% wt. of low density polyethylene (LDPE), 30% wt. of high density polyethylene (HDPE) and 24% wt. of polypropylene (PP). Two sets of experiments have been carried out at 500 and 650 Degree-Sign C via catalytic pyrolysis (1% of Z-N catalyst) and at 650 and 730 Degree-Sign C via only-thermal pyrolysis. These experiments have been conducted in a lab-scale, fluidized quartz-bed reactor of a capacity of 1-3 kg/h at Hamburg University. The results revealed a strong influence of temperature and presence of catalyst on the product distribution. The ratios of gas/liquid/solid mass fractions via thermal pyrolysis were: 36.9/48.4/15.7% wt. and 42.4/44.7/13.9% wt. at 650 and 730 Degree-Sign C while via catalytic pyrolysis were: 6.5/89.0/4.5% wt. and 54.3/41.9/3.8% wt. at 500 and 650 Degree-Sign C, respectively. At 650 Degree-Sign C the monomer generation increased by 55% up to 23.6% wt. of total pyrolysis products distribution while the catalyst was added. Obtained yields of olefins were compared with the naphtha steam cracking process and other potentially attractive processes for feedstock generation. The concept of closed cycle material flow for polyolefins has been discussed, showing the potential benefits of feedstock recycling in a plastic waste management.

Donaj, Pawel J., E-mail: pawel@mse.kth.se [Royal Institute of Technology, School of Industrial Engineering and Management, Division of Energy and Furnace Technology, Brinellvagen 23, 100-44 Stockholm (Sweden); Kaminsky, W. [University of Hamburg, Institute of Technical and Macromolecular Chemistry, Martin-Luther-King Platz 6, 20146 Hamburg (Germany); Buzeto, F. [State University of Campinas - UNICAMP, College of Chemical Engineering, Department of Polymer Science - Av. Albert Einstein 13083-852 Campinas (Brazil); Yang, W. [Royal Institute of Technology, School of Industrial Engineering and Management, Division of Energy and Furnace Technology, Brinellvagen 23, 100-44 Stockholm (Sweden)

2012-05-15T23:59:59.000Z

344

High-biomass sorghums for biomass biofuel production  

E-Print Network [OSTI]

University; M.S., Texas A&M University Chair of Advisory Committee: Dr. William Rooney High-biomass sorghums provide structural carbohydrates for bioenergy production. Sorghum improvement is well established, but development of high- biomass sorghums... these goals and be economically viable, abundant and low-cost 3 biomass sources are needed. To provide this, dedicated bioenergy crops are necessary (Epplin et al., 2007). For a variety of reasons, the C4 grass sorghum (Sorghum bicolor L...

Packer, Daniel

2011-05-09T23:59:59.000Z

345

Remotely sensed heat anomalies linked with Amazonian forest biomass declines  

E-Print Network [OSTI]

with Amazonian forest biomass declines Michael Toomey, 1 Darof aboveground living biomass (p biomass declines, Geophys. Res.

Toomey, M.; Roberts, D. A.; Still, C.; Goulden, M. L.; McFadden, J. P.

2011-01-01T23:59:59.000Z

346

Interactions of Lignin and Hemicellulose and Effects on Biomass Deconstruction  

E-Print Network [OSTI]

such lignocellulosic biomass feedstocks into ethanol via atools. Different biomass feedstocks have different cell wallmajor lignocellulosic biomass feedstocks, except softwoods,

Li, Hongjia

2012-01-01T23:59:59.000Z

347

A Review on Biomass Torrefaction Process and Product Properties for Energy Applications  

SciTech Connect (OSTI)

Torrefaction of biomass can be described as a mild form of pyrolysis at temperatures typically ranging between 200 and 300 C in an inert and reduced environment. Common biomass reactions during torrefaction include devolatilization, depolymerization, and carbonization of hemicellulose, lignin and cellulose. Torrefaction process produces a brown to black solid uniform product and also condensable (water, organics, and lipids) and non condensable gases (CO2, CO, and CH4). Typically during torrefaction, 70% of the mass is retained as a solid product, containing 90% of the initial energy content, and 30% of the lost mass is converted into condensable and non-condensable products. The system's energy efficiency can be improved by reintroducing the material lost during torrefaction as a source of heat. Torrefaction of biomass improves its physical properties like grindability; particle shape, size, and distribution; pelletability; and proximate and ultimate composition like moisture, carbon and hydrogen content, and calorific value. Carbon and calorific value of torrefied biomass increases by 15-25%, and moisture content reduces to <3% (w.b.). Torrefaction reduces grinding energy by about 70%, and the ground torrefied biomass has improved sphericity, particle surface area, and particle size distribution. Pelletization of torrefied biomass at temperatures of 225 C reduces specific energy consumption by two times and increases the capacity of the mill by two times. The loss of the OH group during torrefaction makes the material hydrophobic (loses the ability to attract water molecules) and more stable against chemical oxidation and microbial degradation. These improved properties make torrefied biomass particularly suitable for cofiring in power plants and as an upgraded feedstock for gasification.

Jaya Shankar Tumuluru; Shahab Sokhansanj; J. Richard Hess; Christopher T. Wright; Richard D. Boardman

2011-10-01T23:59:59.000Z

348

Science Activities in Biomass  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2) CawithMicrofluidicJournalWhatActivities in Biomass

349

Biomass 2013: Welcome  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd: ScopeDepartment1, 2011 (BETO)and Fuel09 ConferenceBiomass 2013

350

Sandia National Laboratories: Biomass  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0Energy Advanced NuclearBASF latentBiofuelsBiomass Renewable

351

NREL: Biomass Research - Joseph Shekiro  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Deacetylation and Mechanical (Disc) Refining Process for the Conversion of Renewable Biomass to Lower Cost Sugars." Biotechnology for Biofuels (7:7). Shekiro, J. ; Kuhn, E.M.;...

352

Biomass IBR Fact Sheet: POET  

Broader source: Energy.gov (indexed) [DOE]

in the project, including POET Design and Construction, POET Research, POET Biomass, and POET Biorefining - Emmetsburg. LIBERTY is partnering with Novozymes to optimize...

353

NREL: Biomass Research - Michael Resch  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

improve the hydrolysis efficiency of cellulase and hemicellulase enzyme digestion of biomass. This work will help NREL lower the industrial cost of lignocellulosic enzyme...

354

Biomass power for rural development  

SciTech Connect (OSTI)

Biomass is a proven option for electricity generation. A diverse range of biopower producers includes electric utilities, independent power producers, and the pulp and paper industry. To help expand opportunities for biomass power production, the U.S. Department of Energy established the Biopower Program and is sponsoring efforts to increase the productivity of dedicated energy crops. The Program aims to double biomass conversion efficiencies, thus reducing biomass power generation costs. These efforts will promote industrial and agricultural growth, improve the environment, create jobs, increase U.S. energy security, and provide new export markets.

Shepherd, P.

2000-06-02T23:59:59.000Z

355

System and process for biomass treatment  

SciTech Connect (OSTI)

A system including an apparatus is presented for treatment of biomass that allows successful biomass treatment at a high solids dry weight of biomass in the biomass mixture. The design of the system provides extensive distribution of a reactant by spreading the reactant over the biomass as the reactant is introduced through an injection lance, while the biomass is rotated using baffles. The apparatus system to provide extensive assimilation of the reactant into biomass using baffles to lift and drop the biomass, as well as attrition media which fall onto the biomass, to enhance the treatment process.

Dunson, Jr., James B; Tucker, III, Melvin P; Elander, Richard T; Lyons, Robert C

2013-08-20T23:59:59.000Z

356

Biomass in the Deregulated Marketplace: Current Issues for Biomass Power  

SciTech Connect (OSTI)

This issue brief provides readers with a monthly review and analysis of electric utility deregulation as it impacts biomass power production and distribution. The topical areas to be routinely covered will include Federal activities, State activities, Current challenges, and Current opportunities. Additionally, a monthly highlighted topic will provide more in-depth analysis of current issue impacting biomass power.

Not Available

1998-12-01T23:59:59.000Z

357

CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS  

SciTech Connect (OSTI)

The following are proposed activities for quarter 3 (12/15/00-3/14/01): (1) Conduct TGA and fuel characterization studies - Task 1; (2) Continue to perform re-burn experiments. - Task 2; (3) Design fixed bed combustor. - Task 3; and (4) Modify the PCGC2 code to include moisture evaporation model - Task 4. The following were achieved During Quarter 3 (12/15/0-3/14/01): (1) Conducted TGA and Fuel Characterization studies (Appendix I). A comparison of -fuel properties, TGA traces etc is given in Appendix I. Litter has 3 and 6 times more N compared to coal on mass and heat basis. The P of litter is almost 2 % (Task 1). Both litter biomass (LB) and feedlot biomass (FB) have been pulverized. The size distributions are similar for both litter and FB in that 75 % pass through 150 {micro}m sieve while for coal 75 % pass through 60 {micro}m sieve. Rosin Rammler curve parameters are given. The TGA characteristics of FB and LB are similar and pyrolysis starts at 100 C below that of coal; (2) Reburn experiments with litter and with FB have been performed (Appendix II) -Task 2. Litter is almost twice effective (almost 70--90 % reduction) compared to coal in reducing the NOx possibly due to presence of N in the form of NH{sub 3}; (3) Designed fixed bed gasifier/combustor (Appendix III) - Task 3; and (4) Modified PCGC2 to include moisture evaporation model in coal and biomass particles. (Appendix IV) - Task 4.

Dr. Kalyan Annamalai; Dr. John Sweeten; Dr. Sayeed Mukhtar

2001-05-10T23:59:59.000Z

358

Process for concentrated biomass saccharification  

DOE Patents [OSTI]

Processes for saccharification of pretreated biomass to obtain high concentrations of fermentable sugars are provided. Specifically, a process was developed that uses a fed batch approach with particle size reduction to provide a high dry weight of biomass content enzymatic saccharification reaction, which produces a high sugars concentration hydrolysate, using a low cost reactor system.

Hennessey, Susan M. (Avondale, PA); Seapan, Mayis (Landenberg, PA); Elander, Richard T. (Evergreen, CO); Tucker, Melvin P. (Lakewood, CO)

2010-10-05T23:59:59.000Z

359

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

and impact of Industrial Private Forestry (IPF) has been eliminated from most of the analyses that make up) Project is developing a comprehensive forest biomass-to- electricity model to identify and analyze the economic and environmental costs and benefits of using forest biomass to generate electricity while

360

Method of producing pyrolysis gases from carbon-containing materials  

DOE Patents [OSTI]

A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

Mudge, Lyle K. (Richland, WA); Brown, Michael D. (West Richland, WA); Wilcox, Wayne A. (Kennewick, WA); Baker, Eddie G. (Richland, WA)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Biomass Producer or Collector Tax Credit (Oregon)  

Broader source: Energy.gov [DOE]

 The Oregon Department of Energy provides a tax credit for agricultural producers or collectors of biomass.  The credit can be used for eligible biomass used to produce biofuel; biomass used in...

362

Treatment of biomass to obtain fermentable sugars  

DOE Patents [OSTI]

Biomass is pretreated using a low concentration of aqueous ammonia at high biomass concentration. Pretreated biomass is further hydrolyzed with a saccharification enzyme consortium. Fermentable sugars released by saccharification may be utilized for the production of target chemicals by fermentation.

Dunson, Jr., James B. (Newark, DE); Tucker, Melvin (Lakewood, CO); Elander, Richard (Evergreen, CO); Hennessey, Susan M. (Avondale, PA)

2011-04-26T23:59:59.000Z

363

BIOMASS LIQUEFACTION EFFORTS IN THE UNITED STATES  

E-Print Network [OSTI]

icat ion Preheat zone Biomass liquefaction Tubular reactor (design is shown in Figure 7, C I Biomass ua efaction Fic LBL Process BiOMASS t NON-REVERS lNG CYCLONE CONDENSER (

Ergun, Sabri

2012-01-01T23:59:59.000Z

364

Mineral Transformation and Biomass Accumulation Associated With  

E-Print Network [OSTI]

Mineral Transformation and Biomass Accumulation Associated With Uranium Bioremediation at Rifle transformation and biomass accumulation, both of which can alter the flow field and potentially bioremediation to understand the biogeochemical processes and to quantify the biomass and mineral transformation/ accumulation

Hubbard, Susan

365

Experimental Flash Pyrolysis of High Density1 PolyEthylene under Hybrid Propulsion Conditions2  

E-Print Network [OSTI]

1/25 Experimental Flash Pyrolysis of High Density1 PolyEthylene under Hybrid Propulsion Conditions2 Poly-Ethylene (HDPE) is studied6 up to 20 000 K.s-1 , under pressure up to 3.0 MPa and at temperature Pyrolysis (2013) 1-11" DOI : 10.1016/j.jaap.2013.02.014 #12;2/25 Keywords: Polyethylene; flash pyrolysis

Boyer, Edmond

366

Catalytic Hydrothermal Gasification of Biomass  

SciTech Connect (OSTI)

A recent development in biomass gasification is the use of a pressurized water processing environment in order that drying of the biomass can be avoided. This paper reviews the research undertaken developing this new option for biomass gasification. This review does not cover wet oxidation or near-atmospheric-pressure steam-gasification of biomass. Laboratory research on hydrothermal gasification of biomass focusing on the use of catalysts is reviewed here, and a companion review focuses on non-catalytic processing. Research includes liquid-phase, sub-critical processing as well as super-critical water processing. The use of heterogeneous catalysts in such a system allows effective operation at lower temperatures, and the issues around the use of catalysts are presented. This review attempts to show the potential of this new processing concept by comparing the various options under development and the results of the research.

Elliott, Douglas C.

2008-05-06T23:59:59.000Z

367

Pyrolysis Kinetics and Chemical Structure Considerations of a Green River Oil Shale and Its Derivatives.  

E-Print Network [OSTI]

??This work had the objective of determining both the kinetic parameters for the pyrolysis of oil shale and kerogen as well as using analytical techniques… (more)

Hillier, James L

2011-01-01T23:59:59.000Z

368

Reactive gases evolved during pyrolysis of Devonian oil shale  

SciTech Connect (OSTI)

Computer modeling of oil shale pyrolysis is an important part of the Lawrence Livermore National Laboratory (LLNL) Oil Shale Program. Models containing detailed chemistry have been derived from an investigation of Colorado oil shale. We are currently attempting to use models to treat more completely reactions of nitrogen and sulfur compounds in the retort to better understand emissions. Batch retorting work on Devonian oil shale is proving particularly useful for this study of nitrogen/sulfur chemistry. Improved analytical methods have been developed to quantitatively determine reactive volatiles at the parts-per-million level. For example, the triple quadrupole mass spectrometer (TQMS) is used in the chemical ionization (CI) mode to provide real-time analytical data on ammonia evolution as the shale is pyrolyzed. A heated transfer line and inlet ensure rapid and complete introduction of ammonia to the instrument by preventing water condensation. Ammonia and water release data suitable for calculating kinetic parameters have been obtained from a New Albany Shale sample. An MS/MS technique with the TQMS in the electron ionization (EI) mode allows hydrogen sulfide, carbonyl sulfide, and certain trace organic sulfur compounds to be monitored during oil shale pyrolysis. Sensitivity and selectivity for these compounds have been increased by applying artificial intelligence techniques to tuning of the spectrometer. Gas evolution profiles (100 to 900/sup 0/C) are reported for hydrogen sulfide, water, ammonia, and trace sulfur species formed during pyrolysis of Devonian oil shale. Implications for retorting chemistry are discussed. 18 refs., 11 figs., 3 tabs.

Coburn, T.T.; Crawford, R.W.; Gregg, H.R.; Oh, M.S.

1986-11-01T23:59:59.000Z

369

Pore Scale Analysis of Oil Shale/Sands Pyrolysis  

SciTech Connect (OSTI)

There are important questions concerning the quality and volume of pore space that is created when oil shale is pyrolyzed for the purpose of producing shale oil. In this report, 1.9 cm diameter cores of Mahogany oil shale were pyrolyzed at different temperatures and heating rates. Detailed 3D imaging of core samples was done using multiscale X-ray computed tomography (CT) before and after pyrolysis to establish the pore structure. The pore structure of the unreacted material was not clear. Selected images of a core pyrolyzed at 400oC were obtained at voxel resolutions from 39 microns (?m) to 60 nanometers (nm). Some of the pore space created during pyrolysis was clearly visible at these resolutions and it was possible to distinguish between the reaction products and the host shale rock. The pore structure deduced from the images was used in Lattice Boltzmann simulations to calculate the permeability in the pore space. The permeabilities of the pyrolyzed samples of the silicate-rich zone were on the order of millidarcies, while the permeabilities of the kerogen-rich zone after pyrolysis were very anisotropic and about four orders of magnitude higher.

Lin, Chen-Luh; Miller, Jan

2011-03-01T23:59:59.000Z

370

Mobile Biomass Pelletizing System  

SciTech Connect (OSTI)

This grant project examines multiple aspects of the pelletizing process to determine the feasibility of pelletizing biomass using a mobile form factor system. These aspects are: the automatic adjustment of the die height in a rotary-style pellet mill, the construction of the die head to allow the use of ceramic materials for extreme wear, integrating a heat exchanger network into the entire process from drying to cooling, the use of superheated steam for adjusting the moisture content to optimum, the economics of using diesel power to operate the system; a break-even analysis of estimated fixed operating costs vs. tons per hour capacity. Initial development work has created a viable mechanical model. The overall analysis of this model suggests that pelletizing can be economically done using a mobile platform.

Thomas Mason

2009-04-16T23:59:59.000Z

371

NREL: Biomass Research - Biochemical Conversion Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NREL's projects in biochemical conversion involve three basic steps to convert biomass feedstocks to fuels: Converting biomass to sugar or other fermentation feedstock...

372

Symbiosis: Addressing Biomass Production Challenges and Climate...  

Broader source: Energy.gov (indexed) [DOE]

Symbiosis: Addressing Biomass Production Challenges and Climate Change Symbiosis: Addressing Biomass Production Challenges and Climate Change This presentation was the opening...

373

NREL: Biomass Research - Robert M. Baldwin  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MI. Dr. Baldwin has extensive experience and expertise in thermochemical conversion of biomass to gaseous and liquid fuels, including catalysis and reaction engineering of biomass...

374

Tribal Renewable Energy Curriculum Foundational Course: Biomass...  

Broader source: Energy.gov (indexed) [DOE]

Renewable Energy Curriculum Foundational Course: Biomass Tribal Renewable Energy Curriculum Foundational Course: Biomass Watch the U.S. Department of Energy Office of Indian Energy...

375

Molecular Characterization of Biomass Burning Aerosols Using...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biomass Burning Aerosols Using High Resolution Mass Spectrometry. Molecular Characterization of Biomass Burning Aerosols Using High Resolution Mass Spectrometry. Abstract: Chemical...

376

NREL: Biomass Research - Daniel J. Schell  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

more than 30 years of research experience in bio-based conversion of lignocellulosic biomass and has extensive expertise in integrated biomass conversion operations at the bench...

377

Biomass Compositional Analysis Laboratory (Fact Sheet), National...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

At the Biomass Compositional Analysis Laboratory, NREL scientists have more than 20 years of experience supporting the biomass conversion industry. They develop, refine, and...

378

NREL: Biomass Research - News Release Archives  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Research Facility (IBRF). June 2, 2011 Science & Industry Peers Turn to NREL for Biomass Solutions The biomass industry looks to the U.S. Department of Energy's National...

379

Transcript: Biomass Clean Cities Webinar ? Workforce Development  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Transcript: Biomass Clean Cities Webinar - Workforce Development Page 1 of 12 Alicia Lindauer: My name is Alicia Lindauer. I work for the Department of Energy's Biomass Program....

380

High temperature, optically transparent plastics from biomass  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

temperature, optically transparent plastics from biomass At a Glance Rapid, selective catalytic system to produce vinyl plastics from renewable biomass Stereoregular...

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Supplying High-Quality, Raw Biomass  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Supplying High-Quality, Raw Biomass The building blocks to supply high-quality raw biomass start with harvesting and collection practices, product storage and recommendations of...

382

Converting Biomass to High-Value Feedstocks  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Converting Biomass to High-Value Feedstocks Advanced feedstocks play an important role in economically and efficiently converting biomass into bioenergy products. Advanced...

383

Biomass Guidelines (Prince Edward Island, Canada)  

Broader source: Energy.gov [DOE]

PEI Biomass Guidelines identify two major pathways that biomass projects may follow: No Public Investment, and Public Investment. Projects with Public Investment include any project that has:

384

Hydrogen Production Cost Estimate Using Biomass Gasification...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Production Cost Estimate Using Biomass Gasification: Independent Review Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review This independent review is...

385

Fast Ignition  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Region service area. TheEPSCI Home It isGasERPSpun Off From A GovernmentFast

386

General equations for Biomass Properties Nadge Richard1,2  

E-Print Network [OSTI]

measured after the same type of reaction, flash pyrolysis. This type of reaction yields higher amount and the temperature of the particle during pyrolysis. These empirical correlations are found by curve fitting (see is supposed to be pyrolysed in a temperature range of 573 K -1173 K. Pyrolysis is a thermal decomposition

387

Development of a Computational Fluid Dynamics Model for Combustion of Fast Pyrolysis Liquid (Bio-oil).  

E-Print Network [OSTI]

??A study was carried out into the computational fluid dynamic simulation of bio-oil combustion. Measurements were taken in an empirical burner to obtain information regarding… (more)

McGrath, Arran Thomas

2011-01-01T23:59:59.000Z

388

Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top Five EEREDepartmentFebruary 4, 2014 BioenergyDepartment of

389

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review:Department of Energy EnvironmentalJuly 2015communication

390

Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd: ScopeDepartment1, 2011 (BETO) Project

391

Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and Hydroprocessing  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd: ScopeDepartment1, 2011 (BETO) Projectdried to about 10 wt%

392

Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd: ScopeDepartment1, 2011 (BETO) Projectdried to about 10 wt%about

393

Development of integrated assessment platform for biofuels production via fast pyrolysis and upgrading pathway.  

E-Print Network [OSTI]

??Growing concern over Greenhouse Gas (GHG) emissions from petroleum-based fuel consumption have prompted interest in the production of alternative transportation fuels from biorenewable sources. As… (more)

Zhang, Yanan

2014-01-01T23:59:59.000Z

394

Review and analysis of the 1980-1989 biomass thermochemical conversion program  

SciTech Connect (OSTI)

In the period between 1980 and 1989, the U.S. Department of Energy (DOE) sponsored research and development projects through its Biomass Thermochemical Conversion (BTC) Program. Thermochemical conversion technologies use elevated temperatures to convert biomass into more useful forms of energy such as fuel gases or transportation fuels. The BTC Program included a wide range of biomass conversion projects in the areas of gasification, pyrolysis, liquefaction, and combustion. This work formed the basis of the present DOE research and development efforts on advanced liquid fuel and power generation systems. At the beginning of Fiscal Year 1989, the management of the BTC Program was transferred from Pacific Northwest Laboratory (PNL) to National Renewable Energy Laboratory (NREL, formerly Solar Energy Research Institute). This document presents a summary of the research which was performed under the BTC Program during the 1981-1989 time frame. The document consists of an analysis of the research projects which were funded by the BTC Program and a bibliography of published documents. This work will help ensure that information from PNL`s BTC Program is available to those interested in biomass conversion technologies. The background of the BTC Program is discussed in the first chapter of this report. In addition, a brief summary of other related biomass research and development programs funded by the U.S. Department of Energy and others is presented with references where additional information can be found. The remaining chapters of the report present a detailed summary of the research projects which were funded by the BTC Program. The progress which was made on each project is summarized, the overall impact on biomass conversion is discussed, and selected references are provided.

Stevens, D.J.

1994-09-01T23:59:59.000Z

395

BIOMASS LIQUEFACTION EFFORTS IN THE UNITED STATES  

E-Print Network [OSTI]

coil) Pyrolysis zone j Gasification zone j · Combustion zoneis a reactor for both gasification and liquefaction. The$0 lb = 17~6 lb 13.5 lb Gasification stoichiometry (at 1290°

Ergun, Sabri

2012-01-01T23:59:59.000Z

396

Biothermal gasification of biomass  

SciTech Connect (OSTI)

The BIOTHERMGAS Process is described for conversion of biomass, organic residues, and peat to substitute natural gas (SNG). This new process, under development at IGT, combines biological and thermal processes for total conversion of a broad variety of organic feeds (regardless of water or nutrient content). The process employs thermal gasification for conversion of refractory digester residues. Ammonia and other inorganic nutrients are recycled from the thermal process effluent to the bioconversion unit. Biomethanation and catalytic methanation are presented as alternative processes for methanation of thermal conversion product gases. Waste heat from the thermal component is used to supply the digester heat requirements of the bioconversion component. The results of a preliminary systems analysis of three possible applications of this process are presented: (1) 10,000 ton/day Bermuda grass plant with catalytic methanation; (2) 10,000 ton/day Bermuda grass plant with biomethanation; and (3) 1000 ton/day municipal solid waste (MSW) sewage sludge plant with biomethanation. The results indicate that for these examples, performance is superior to that expected for biological or thermal processes used separately. The results of laboratory studies presented suggest that effective conversion of thermal product gases can be accomplished by biomethanation.

Chynoweth, D.P.; Srivastava, V.J.; Henry, M.P.; Tarman, P.B.

1980-01-01T23:59:59.000Z

397

Ohio Biomass Energy Program (Ohio)  

Broader source: Energy.gov [DOE]

Ohio is one of seven states participating in the Great Lakes Regional Biomass Energy Program which was established in 1983. The Regional Program is administered by the Council of Great Lakes...

398

Arnold Schwarzenegger BIOMASS TO ENERGY  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY Public Interest Energy Research Program Prepared By: USDA Forest Service Pacific Southwest Research PRODUCTION, AND OTHER BENEFITS PIERFINALPROJECTREPORT APPENDICES Prepared For: California Energy Commission

399

Biomass Supply for a Bioenergy  

E-Print Network [OSTI]

Resource assessment – do we have enough biomass? Techno-economic analysis – can biofuels be produced at competitive prices? • Integrated biorefineries – what is being funded at DOE and what are future plans?

Hydrocarbon-based Biofuels; Zia Haq

2012-01-01T23:59:59.000Z

400

Washington State biomass data book  

SciTech Connect (OSTI)

This is the first edition of the Washington State Biomass Databook. It assess sources and approximate costs of biomass fuels, presents a view of current users, identifies potential users in the public and private sectors, and lists prices of competing energy resources. The summary describes key from data from the categories listed above. Part 1, Biomass Supply, presents data increasing levels of detail on agricultural residues, biogas, municipal solid waste, and wood waste. Part 2, Current Industrial and Commercial Use, demonstrates how biomass is successfully being used in existing facilities as an alternative fuel source. Part 3, Potential Demand, describes potential energy-intensive public and private sector facilities. Part 4, Prices of Competing Energy Resources, shows current suppliers of electricity and natural gas and compares utility company rates. 49 refs., 43 figs., 72 tabs.

Deshaye, J.A.; Kerstetter, J.D.

1991-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Cadmium Biosorption Rate in Protonated Sargassum Biomass  

E-Print Network [OSTI]

Cadmium Biosorption Rate in Protonated Sargassum Biomass J I N B A I Y A N G A N D B O H U M I L V Sargassum fluitans biomass was accompanied by the release of hydrogen protons from the biomass. The uptake the overall biosorption rate of cadmium ions in flat seaweed biomass particles. The overall biosorption

Volesky, Bohumil

402

Vanadium catalysts break down biomass for fuels  

E-Print Network [OSTI]

- 1 - Vanadium catalysts break down biomass for fuels March 26, 2012 Vanadium catalysts break down biomass into useful components Due to diminishing petroleum reserves, non-food biomass (lignocellulose biomass into high-value commodity chemicals. The journal Angewandte Chemie International Edition published

403

Biomass Surface Characterization Laboratory (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet provides information about Biomass Surface Characterization Laboratory capabilities and applications at NREL.

Not Available

2012-04-01T23:59:59.000Z

404

November 2011 Competition for biomass among  

E-Print Network [OSTI]

remain high, limiting the development of national or even regional markets for biomass feedstocks. We

Noble, James S.

405

Global (International) Energy Policy and Biomass  

SciTech Connect (OSTI)

Presentation to the California Biomass Collaboration--First Annual Forum, January 8th 2004, Sacramento, California

Overend, R. P.

2004-01-01T23:59:59.000Z

406

Cell Wall Chemotyping for Functional Applications of PyrolysisGas Chromatography / Mass  

E-Print Network [OSTI]

Cell Wall Chemotyping for Functional Genomics Applications of Pyrolysis­Gas Chromatography / Mass, Umeå 2012 #12;Cell Wall Chemotyping for Functional Genomics Applications of Pyrolysis.4.1 The Basic Tool-set 27 1.5 Wood Formation and Functional Genomics 31 2 Objectives 33 3 Methodological

407

Dynamic molecular structure of plant biomass-derived black carbon (biochar)  

E-Print Network [OSTI]

Mechanism study of wood lignin pyrolysis  by using TG?FTIR hemicellulose,  cellulose and lignin pyrolysis.  Fuel 2007, bark,  cellulose,  and  lignin:  Implications for the 

Keiluweit, M.

2010-01-01T23:59:59.000Z

408

Modeling of the reburn process with the use of feedlot biomass as a reburn fuel  

E-Print Network [OSTI]

...................................................................................... 43 Chemical reactions .............................................................................. 46 Pyrolysis .............................................................................................. 52 viii CHAPTER Page Fuel... nitrogen pyrolysis........................................................................ 54 Gas stream mass conservation equations ............................................ 56 Particle geometry...

Colmegna, Giacomo

2009-05-15T23:59:59.000Z

409

Biomass and Bioenergy 31 (2007) 646655 Estimating biomass of individual pine trees using airborne lidar  

E-Print Network [OSTI]

Biomass and Bioenergy 31 (2007) 646­655 Estimating biomass of individual pine trees using airborne biomass and bio-energy feedstocks. The overall goal of this study was to develop a method for assessing aboveground biomass and component biomass for individual trees using airborne lidar data in forest settings

410

Instructions for CEC-1250E-4 Biomass and Fossil Fuel Usage Report for Biomass Facilities  

E-Print Network [OSTI]

Instructions for CEC-1250E-4 Biomass and Fossil Fuel Usage Report for Biomass Facilities Biomass energy input basis in the upcoming calendar year? - Please check "yes" or "no." 12. Types of Biomass Fuel Used - Please report the quantity and supplier of the following types of biomass fuel used

411

Enzymatic Hydrolysis of Cellulosic Biomass  

SciTech Connect (OSTI)

Biological conversion of cellulosic biomass to fuels and chemicals offers the high yields to products vital to economic success and the potential for very low costs. Enzymatic hydrolysis that converts lignocellulosic biomass to fermentable sugars may be the most complex step in this process due to substrate-related and enzyme-related effects and their interactions. Although enzymatic hydrolysis offers the potential for higher yields, higher selectivity, lower energy costs, and milder operating conditions than chemical processes, the mechanism of enzymatic hydrolysis and the relationship between the substrate structure and function of various glycosyl hydrolase components are not well understood. Consequently, limited success has been realized in maximizing sugar yields at very low cost. This review highlights literature on the impact of key substrate and enzyme features that influence performance to better understand fundamental strategies to advance enzymatic hydrolysis of cellulosic biomass for biological conversion to fuels and chemicals. Topics are summarized from a practical point of view including characteristics of cellulose (e.g., crystallinity, degree of polymerization, and accessible surface area) and soluble and insoluble biomass components (e.g., oligomeric xylan, lignin, etc.) released in pretreatment, and their effects on the effectiveness of enzymatic hydrolysis. We further discuss the diversity, stability, and activity of individual enzymes and their synergistic effects in deconstructing complex lignocellulosic biomass. Advanced technologies to discover and characterize novel enzymes and to improve enzyme characteristics by mutagenesis, post-translational modification, and over-expression of selected enzymes and modifications in lignocellulosic biomass are also discussed.

Yang, Bin; Dai, Ziyu; Ding, Shi-You; Wyman, Charles E.

2011-08-22T23:59:59.000Z

412

Mineral Nutrient Recovery from Pyrolysis Co-Products  

E-Print Network [OSTI]

. 2 For highly cellulosic biomass feedstocks (i.e. sorghum, switchgrass, ect.), the pyrolyzed liquid fraction usually contains acids, alcohols, aldehydes, ketones, esters, heterocyclic derivatives and phenolic compounds (Yaman, 2004). Bio... has revealed that most of these inorganic compounds, especially K, Ca, Na, Si, P, and Cl, are constituents of the ash in biomass feedstocks (Agblevor and Besler, 1996). High recoveries P and K were reported for bio-char derived from fluidized...

Wise, Jatara Rob

2012-07-16T23:59:59.000Z

413

University of Delaware | Catalysis Center for Energy Innovation | Pyrolysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest RegionatSearchScheduledProductionCCEIResearch Thrust Pyrolysis

414

D/H isotope ratios of kerogen, bitumen, oil, and water in hydrous pyrolysis of source rocks containing kerogen types I, II, IIS, and III  

SciTech Connect (OSTI)

Immature source rock chips containing different types of kerogen (I,II,IIS,III) were artificially matured in isotopically distinct waters by hydrous pyrolysis and by pyrolysis in supercritical water. Converging isotopic trends of inorganic (water) and organic (kerogen, bitumen, oil) hydrogen with increasing time and temperature document that water-derived hydrogen is added to or exchanged with organic hydrogen, or both, during chemical reactions that take place during thermal maturation. Isotopic mass-balance calculations show that, depending on temperature (310--381 C), time (12--144h), and source rock type, between ca. 45 and 79% of carbon-bound hydrogen in kerogen is derived from water. Estimates for bitumen and oil range slightly lower, with oil-hydrogen being least affected by water-derived hydrogen. Comparative hydrous pyrolyses of immature source rocks at 330 C for 72h show that hydrogen in kerogen, bitumen, and expelled oil/wax ranks from most to least isotopically influenced by water-derived hydrogen in the order IIS {gt} II {approximately} III {gt} I. Pyrolysis of source rock containing type II kerogen in supercritical water at 381 C for 12 h yields isotopic results that are similar to those from hydrous pyrolysis at 250 C for 72 h or 330 C for 133 h. Bulk hydrogen in kerogen contains several percent of isotopically labile hydrogen that exchanges fast and reversibly with hydrogen in water vapor at 115 C. The isotopic equilibration of labile hydrogen in kerogen with isotopic standard water vapors significantly reduces the analytical uncertainty of D/H ratios when compared with simple D/H determination of bulk hydrogen in kerogen. If extrapolation of their results from hydrous pyrolysis is permitted to natural thermal maturation at lower temperatures, the authors suggest that organic D/H ratios of fossil fuels in contact with formation water are typically altered during chemical reactions, but that D/H ratios of generated hydrocarbons are subsequently little or not affected by exchange with water hydrogen at typical reservoir conditions over geologic time. It will be difficult to utilize D/H ratios of thermally mature bulk or fractions or organic matter to quantitatively reconstruct isotopic aspects of paleoclimate and paleoenvironment. Hope resides in compound-specific D/H ratio of thermally stable, extractable biomarkers (molecular fossils) that are less susceptible to hydrogen exchange with water-derived hydrogen.

Schimmelmann, A.; Lewan, M.D.; Wintsch, R.P.

1999-11-01T23:59:59.000Z

415

Fiscalini Farms Biomass Energy Project  

SciTech Connect (OSTI)

In this final report describes and documents research that was conducted by the Ecological Engineering Research Program (EERP) at the University of the Pacific (Stockton, CA) under subcontract to Fiscalini Farms LP for work under the Assistance Agreement DE-EE0001895 'Measurement and Evaluation of a Dairy Anaerobic Digestion/Power Generation System' from the United States Department of Energy, National Energy Technology Laboratory. Fiscalini Farms is operating a 710 kW biomass-energy power plant that uses bio-methane, generated from plant biomass, cheese whey, and cattle manure via mesophilic anaerobic digestion, to produce electricity using an internal combustion engine. The primary objectives of the project were to document baseline conditions for the anaerobic digester and the combined heat and power (CHP) system used for the dairy-based biomass-energy production. The baseline condition of the plant was evaluated in the context of regulatory and economic constraints. In this final report, the operation of the plant between start-up in 2009 and operation in 2010 are documented and an interpretation of the technical data is provided. An economic analysis of the biomass energy system was previously completed (Appendix A) and the results from that study are discussed briefly in this report. Results from the start-up and first year of operation indicate that mesophilic anaerobic digestion of agricultural biomass, combined with an internal combustion engine, is a reliable source of alternative electrical production. A major advantage of biomass energy facilities located on dairy farms appears to be their inherent stability and ability to produce a consistent, 24 hour supply of electricity. However, technical analysis indicated that the Fiscalini Farms system was operating below capacity and that economic sustainability would be improved by increasing loading of feedstocks to the digester. Additional operational modifications, such as increased utilization of waste heat and better documentation of potential of carbon credits, would also improve the economic outlook. Analysis of baseline operational conditions indicated that a reduction in methane emissions and other greenhouse gas savings resulted from implementation of the project. The project results indicate that using anaerobic digestion to produce bio-methane from agricultural biomass is a promising source of electricity, but that significant challenges need to be addressed before dairy-based biomass energy production can be fully integrated into an alternative energy economy. The biomass energy facility was found to be operating undercapacity. Economic analysis indicated a positive economic sustainability, even at the reduced power production levels demonstrated during the baseline period. However, increasing methane generation capacity (via the importation of biomass codigestate) will be critical for increasing electricity output and improving the long-term economic sustainability of the operation. Dairy-based biomass energy plants are operating under strict environmental regulations applicable to both power-production and confined animal facilities and novel approached are being applied to maintain minimal environmental impacts. The use of selective catalytic reduction (SCR) for nitrous oxide control and a biological hydrogen sulfide control system were tested at this facility. Results from this study suggest that biomass energy systems can be compliant with reasonable scientifically based air and water pollution control regulations. The most significant challenge for the development of biomass energy as a viable component of power production on a regional scale is likely to be the availability of energy-rich organic feedstocks. Additionally, there needs to be further development of regional expertise in digester and power plant operations. At the Fiscalini facility, power production was limited by the availability of biomass for methane generation, not the designed system capacity. During the baseline study period, feedstocks included manure, sudan grass silage, and

William Stringfellow; Mary Kay Camarillo; Jeremy Hanlon; Michael Jue; Chelsea Spier

2011-09-30T23:59:59.000Z

416

E-Print Network 3.0 - anti-cysticercus cellulosae antibodies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy 16 General equations for Biomass Properties Nadge Richard1,2 Summary: shell (biomass) cellulosa type of reaction flash pyrolysis pyrolysis flash pyrolysis slow...

417

Development of a Sorption Enhanced Steam Hydrogasification Process for In-situ Carbon Dioxide (CO2) Removal and Enhanced Synthetic Fuel Production  

E-Print Network [OSTI]

synthesis from biomass pyrolysis with in situ carbon dioxideof pyrolysis, combustion and gasification of three biomassand biomass, undergoes several different processes and/or reactions: dehydration, pyrolysis,

Liu, Zhongzhe

2013-01-01T23:59:59.000Z

418

Pyrolysis of scrap tires: Can it be profitable?  

SciTech Connect (OSTI)

Pyrolysis--the thermal degradation in the absence of oxygen--is one way to reprocess scrap tires. The products are fuel gas, oils, and a solid residue (char), which contains appreciable quantities of mineral matter and low-grade carbon black. The three products have comparable yields by weight. The two most important factors affecting process economics are the tipping fees charged for tire disposal and the selling prices of the products. Selling prices of the products yield low returns because of the low market value of the fuels and the low quality of the recovered char or carbon black. Therefore, to obtain a positive cash flow, it would be desirable to develop a process based on the recovery of value-added products such as high-grade carbon black, activated carbon, or valuable chemicals (e.g., benzene, toluene, and xylene). The authors believe that significant improvement in the economics can be accomplished by upgrading the primary pyrolysis products to secondary products of higher value.

Wojtowicz, M.A.; Serio, M.A.

1996-10-01T23:59:59.000Z

419

Isolation of levoglucosan from pyrolysis oil derived from cellulose  

DOE Patents [OSTI]

High purity levoglucosan is obtained from pyrolysis oil derived from cellulose by: mixing pyrolysis oil with water and a basic metal hydroxide, oxide, or salt in amount sufficient to elevate pH values to a range of from about 12 to about 12.5, and adding an amount of the hydroxide, oxide, or salt in excess of the amount needed to obtain the pH range until colored materials of impurities from the oil are removed and a slurry is formed; drying the slurry azeotropically with methyl isobutyl ketone solvent to form a residue, and further drying the residue by evaporation; reducing the residue into a powder; continuously extracting the powder residue with ethyl acetate to provide a levoglucosan-rich extract; and concentrating the extract by removing ethyl acetate to provide crystalline levoglucosan. Preferably, Ca(OH)[sub 2] is added to adjust the pH to the elevated values, and then Ca(OH)[sub 2] is added in an excess amount needed. 3 figures.

Moens, L.

1994-12-06T23:59:59.000Z

420

COFIRING BIOMASS WITH LIGNITE COAL  

SciTech Connect (OSTI)

The University of North Dakota Energy & Environmental Research Center, in support of the U.S. Department of Energy's (DOE) biomass cofiring program, completed a Phase 1 feasibility study investigating aspects of cofiring lignite coal with biomass relative to utility-scale systems, specifically focusing on a small stoker system located at the North Dakota State Penitentiary (NDSP) in Bismarck, North Dakota. A complete biomass resource assessment was completed, the stoker was redesigned to accept biomass, fuel characterization and fireside modeling tests were performed, and an engineering economic analysis was completed. In general, municipal wood residue was found to be the most viable fuel choice, and the modeling showed that fireside problems would be minimal. Experimental ash deposits from firing 50% biomass were found to be weaker and more friable compared to baseline lignite coal. Experimental sulfur and NO{sub x} emissions were reduced by up to 46%. The direct costs savings to NDSP, from cogeneration and fuel saving, results in a 15- to 20-year payback on a $1,680,000 investment, while the total benefits to the greater community would include reduced landfill burden, alleviation of fees for disposal by local businesses, and additional jobs created both for the stoker system as well as from the savings spread throughout the community.

Darren D. Schmidt

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

ITP Energy Intensive Processes: Improved Heat Recovery in Biomass...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Improved Heat Recovery in Biomass-Fired Boilers ITP Energy Intensive Processes: Improved Heat Recovery in Biomass-Fired Boilers biomass-firedboilers.pdf More Documents &...

422

Biomass IBR Fact Sheet: Amyris, Inc. | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biomass IBR Fact Sheet: Amyris, Inc. Biomass IBR Fact Sheet: Amyris, Inc. Demonstrating the conversion of sweet sorgum biomass to hydrocarbon fuel and chemicals....

423

The role of biomass in California's hydrogen economy  

E-Print Network [OSTI]

Making a Business from Biomass in Energy, Environment,2004. An assessment of biomass resources in California.methanol and hydrogen from biomass. Journal of Power Sources

Parker, Nathan C; Ogden, Joan; Fan, Yueyue

2009-01-01T23:59:59.000Z

424

New process speeds conversion of biomass to fuels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conversion of Biomass to Fuels New process speeds conversion of biomass to fuels Scientists made a major step forward recently towards transforming biomass-derived molecules into...

425

LBL CONTINUOUS BIOMASS LIQUEFACTION PROCESS ENGINEERING UNIT (PEU)  

E-Print Network [OSTI]

0092 UC-61 ORNIA LBL CONTINUOUS BIOMASS LIQUEFACTION PROCESSLBL~l0092 LBL CONTINUOUS BIOMASS LIQUEFACTION PROCESSof Energy LBL CONTINUOUS BIOMASS LIQUEFACTION PROCESS

Figueroa, Carlos

2012-01-01T23:59:59.000Z

426

MARINE BIOMASS SYSTEM: ANAEROBIC DIGESTION AND PRODUCTION OF METHANE  

E-Print Network [OSTI]

Design Parameters Marine Biomass Production Sea Farmof Various Types of Biomass . Biomethanation Parameters.Proceedings, Fuels from Biomass Symposium. University of

Haven, Kendall F.

2011-01-01T23:59:59.000Z

427

The role of biomass in California's hydrogen economy  

E-Print Network [OSTI]

for the same quantity of biomass. Finally, the distanceto ?nd the quantity of hydrogen from biomass that is likelyhow the quantity of hydrogen available from biomass varies

Parker, Nathan C; Ogden, Joan; Fan, Yueyue

2009-01-01T23:59:59.000Z

428

Biomass Resources Overview and Perspectives on Best Fits for...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biomass Resources Overview and Perspectives on Best Fits for Fuel Cells Biomass Resources Overview and Perspectives on Best Fits for Fuel Cells Biomass resources overview and...

429

Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass  

E-Print Network [OSTI]

less recalcitrant biomass feedstocks and improved enzymes.of less recalcitrant biomass feedstocks and improvedpotential of improved biomass feedstocks and enzymes for the

McKenzie, Heather Lorelei

2012-01-01T23:59:59.000Z

430

CX-006584: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Upgrading of Biomass Fast Pyrolysis Oil (Bio-oil)CX(s) Applied: A9, B3.6Date: 08/15/2011Location(s): Columbus, OhioOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

431

Laminar Entrained Flow Reactor (Fact Sheet), National Bioenergy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Flow Reactor Investigating the core principles of in situ and ex situ catalytic fast pyrolysis of biomass NREL is a national laboratory of the U.S. Department of Energy,...

432

NREL: News Feature - NREL Interns Look Toward the Future  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

engineering at the University of Wisconsin. At NREL, she works with a catalytic fast-pyrolysis, tandem micro-reactor to process biomass samples at NREL's Field Test Laboratory...

433

DEPARTMENT OF ENERGY EERE PROJECT MANAGEMENT CENTER NEPA DETFIU...  

Broader source: Energy.gov (indexed) [DOE]

DETFIU.llNATION RECIPIENT:Battelie Memorial Institute Corporate PROJECT TITLE: Upgrading of Biomass Fast Pyrolysis Oil (Bio-oil) Page I of2 STATE: OH Funding Opportunity...

434

Distributed Reforming of Biomass Pyrolysis Oils: Cooperative Research and Development Final Report, CRADA number CRD-06-00192  

SciTech Connect (OSTI)

The objective of this project is for Chevron and NREL to collaborate in determining the effect of bio-oil composition variability on autothermal reforming performance including bio-oil volatilization, homogeneous oxidative cracking, and catalytic reforming.

Czernik, S.

2010-07-01T23:59:59.000Z

435

Treatment of biomass to obtain ethanol  

DOE Patents [OSTI]

Ethanol was produced using biocatalysts that are able to ferment sugars derived from treated biomass. Sugars were obtained by pretreating biomass under conditions of high solids and low ammonia concentration, followed by saccharification.

Dunson, Jr., James B. (Newark, DE); Elander, Richard T. (Evergreen, CO); Tucker, III, Melvin P. (Lakewood, CO); Hennessey, Susan Marie (Avondale, PA)

2011-08-16T23:59:59.000Z

436

Biomass Sales and Use Tax Exemption  

Broader source: Energy.gov [DOE]

Georgia enacted legislation in April 2006 (HB 1018) creating an exemption for biomass materials from the state's sales and use taxes. The term "biomass material" is defined as "organic matter,...

437

Biomass Feedstock Composition and Property Database  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The Office of Energy Efficiency and Renewable Energy's Biomass Program works with industry, academia and national laboratory partners on a balanced portfolio of research in biomass feedstocks and conversion technologies. Through research, development, and demonstration efforts geared at the development of integrated biorefineries, the Biomass Program is helping transform the nation's renewable and abundant biomass resources into cost competitive, high performance biofuels, bioproducts, and biopower.(From the Biomass Program's home page at http://www1.eere.energy.gov/biomass/) The Biomass Feedstock Composition and Property Database allows the user to choose from more than 150 types of biomass samples. The specialized interface then guides the user through choices within the sample (such as "Ash" as a choice in the "Hardwood" sample and displays tables based on choice of composition properties, structure properties, elemental properties, extractive properties, etc.

438

Hydrogen Production Cost Estimate Using Biomass Gasification  

E-Print Network [OSTI]

Hydrogen Production Cost Estimate Using Biomass Gasification National Renewable Energy Laboratory% postconsumer waste #12;i Independent Review Panel Summary Report September 28, 2011 From: Independent Review Panel, Hydrogen Production Cost Estimate Using Biomass Gasification To: Mr. Mark Ruth, NREL, DOE

439

Biomass Equipment and Materials Compensating Tax Deduction  

Broader source: Energy.gov [DOE]

In 2005 New Mexico adopted a policy to allow businesses to deduct the value of biomass equipment and biomass materials used for the processing of biopower, biofuels or biobased products in...

440

Conversion of Waste Biomass into Useful Products  

E-Print Network [OSTI]

Waste biomass includes municipal solid waste (MSW), municipal sewage sludge (SS), industrial biosludge, manure, and agricultural residues. When treated with lime, biomass is highly digestible by a mixed culture of acid-forming microorganisms. Lime...

Holtzapple, M.

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Biomass energy systems program summary  

SciTech Connect (OSTI)

Research programs in biomass which were funded by the US DOE during fiscal year 1978 are listed in this program summary. The conversion technologies and their applications have been grouped into program elements according to the time frame in which they are expected to enter the commercial market. (DMC)

None

1980-07-01T23:59:59.000Z

442

CALLA ENERGY BIOMASS COFIRING PROJECT  

SciTech Connect (OSTI)

The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications.

Unknown

2001-10-01T23:59:59.000Z

443

Biomass from Combined Backseatter Modeling  

E-Print Network [OSTI]

and SAR back- scatter. In this article we discuss' the use of models to help develop a relationship to an airbomw SAR (AIB- SAB) image over a fi?rested area in Maine. A relationship derived totall!l from model results was fi?und to undervs- timate biomass. Calibrating the modeled backscatter with limited AIRSAB

Weishampel, John F.

444

Dairy Biomass as a Renewable Fuel Source  

E-Print Network [OSTI]

biomass. This publication explains the properties of dairy manure that could make it an excellent source of fuel....

Mukhtar, Saqib; Goodrich, Barry; Engler, Cady; Capareda, Sergio

2008-03-19T23:59:59.000Z

445

Biomass Compositional Analysis Laboratory (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet provides information about Biomass Compositional Analysis Laboratory (BCAL) capabilities and applications at NREL's National Bioenergy Center.

Not Available

2011-07-01T23:59:59.000Z

446

Ris Energy Report 5 Biomass biomass is one of few non-fluctuating renewable energy  

E-Print Network [OSTI]

Risø Energy Report 5 Biomass 6.2 biomass is one of few non-fluctuating renewable energy resources- tem. Alongside stored hydro and geothermal, this sets biomass apart from most other renewables such as wind power, which must be used when available. A proportion of biomass is therefore attractive

447

Forest Biomass Supply for BioForest Biomass Supply for Bio--productionproduction in the Southeastern United Statesin the Southeastern United States  

E-Print Network [OSTI]

Forest Biomass Supply for BioForest Biomass Supply for BioBio--production and biomass utilizationsproduction and biomass utilizations Industrial sector: for heat and steam Utility sector: for electricity Forest biomass: Agricultural biomass: Transportation sector: for biofuels

Gray, Matthew

448

4, 52015260, 2004 A review of biomass  

E-Print Network [OSTI]

ACPD 4, 5201­5260, 2004 A review of biomass burning emissions part III J. S. Reid et al. Title Page and Physics Discussions A review of biomass burning emissions part III: intensive optical properties of biomass burning particles J. S. Reid1 , T. F. Eck2 , S. A. Christopher3 , R. Koppmann4 , O. Dubovik3 , D

Paris-Sud XI, Université de

449

4, 707745, 2007 Proxies of biomass  

E-Print Network [OSTI]

BGD 4, 707­745, 2007 Proxies of biomass for primary production Y. Huot et al. Title Page Abstract the best index of phytoplankton biomass for primary productivity studies? Y. Huot 1,2 , M. Babin 1,2 , F of biomass for primary production Y. Huot et al. Title Page Abstract Introduction Conclusions References

Paris-Sud XI, Université de

450

Biomass Gasification at The Evergreen State College  

E-Print Network [OSTI]

Biomass Gasification at The Evergreen State College Written by Students of the Winter 2011 Program "Applied Research: Biomass, Energy, and Environmental Justice" At The Evergreen State College, Olympia://blogs.evergreen.edu/appliedresearch/ #12; i Table of Contents Chapter 1: Introduction to Biomass at the Evergreen State College by Dani

451

THE BURNING OF BIOMASS Economy, Environment, Health  

E-Print Network [OSTI]

THE BURNING OF BIOMASS Economy, Environment, Health Kees Kolff, MD, MPH April 21, 2012 #12;OUR TRUCKS OF BIOMASS/ DAY (Currently 82) #12;BAD FOR THE ECONOMY · Taxpayers will pay 50% - tax credits, etc · Not a cogen project so only 25% efficient · Biomass better for biofuels, not electricity · MILL JOBS

452

Thermodynamics of Energy Production from Biomass  

E-Print Network [OSTI]

Thermodynamics of Energy Production from Biomass Tad W. Patzek 1 and David Pimentel 2 1 Department #12;3 Biomass from Tropical Tree Plantations 14 3.1 Scope of the Problem . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 3.2 Environmental Impacts of Industrial Biomass Production . . . . . . . . . . . . . . . 16 3

Patzek, Tadeusz W.

453

SEE ALSO SIDEBARS: RECOURCES SOLARRESOURCES BIOMASS & BIOFUELS  

E-Print Network [OSTI]

373 SEE ALSO SIDEBARS: RECOURCES · SOLARRESOURCES · BIOMASS & BIOFUELS Engineered and Artificial Biomass remains a key energy source for several billion people living in developing countries, and the production of liquid biofuels for transportation is growing rapidly. However, both traditional biomass energy

Kammen, Daniel M.

454

Fermentable sugars by chemical hydrolysis of biomass  

E-Print Network [OSTI]

Fermentable sugars by chemical hydrolysis of biomass Joseph B. Binder and Ronald T. Raines1 19, 2009) Abundant plant biomass has the potential to become a sustainable source of fuels of biomass into monosaccharides. Add- ing water gradually to a chloride ionic liquid-containing catalytic

Raines, Ronald T.

455

Energie-Cits 2001 BIOMASS -WOOD  

E-Print Network [OSTI]

Energie-Cités 2001 BIOMASS - WOOD Gasification / Cogeneration ARMAGH United Kingdom Gasification is transferring the combustible matters in organic waste or biomass into gas and pure char by burning the fuel via it allows biomass in small-scaled engines and co-generation units ­ which with conventional technologies

456

Also inside this issue: Bioengineering Better Biomass  

E-Print Network [OSTI]

Also inside this issue: Bioengineering Better Biomass DOE JGI/EMSL Collaborative Science Projects and degrade carbon. This is an image of the Mn(II)-oxidizing fungus Stilbella aciculosa ­ the fungal biomass Better Biomass Feedstock Science Highlights 15 Clouds up Close Improving Catalysts Pore Challenge

457

Woody Biomass Logistics Robert Keefe1  

E-Print Network [OSTI]

14 Woody Biomass Logistics Robert Keefe1 , Nathaniel Anderson2 , John Hogland2 , and Ken Muhlenfeld The economics of using woody biomass as a fuel or feedstock for bioenergy applications is often driven by logistical considerations. Depending on the source of the woody biomass, the acquisition cost of the material

458

5, 1045510516, 2005 A review of biomass  

E-Print Network [OSTI]

ACPD 5, 10455­10516, 2005 A review of biomass burning emissions, part I R. Koppmann et al. Title and Physics Discussions A review of biomass burning emissions, part I: gaseous emissions of carbon monoxide A review of biomass burning emissions, part I R. Koppmann et al. Title Page Abstract Introduction

Paris-Sud XI, Université de

459

4, 51355200, 2004 A review of biomass  

E-Print Network [OSTI]

ACPD 4, 5135­5200, 2004 A review of biomass burning emissions, part II J. S. Reid et al. Title Page and Physics Discussions A review of biomass burning emissions, part II: Intensive physical properties of biomass burning particles J. S. Reid 1 , R. Koppmann 2 , T. F. Eck 3 , and D. P. Eleuterio 4 1 Marine

Paris-Sud XI, Université de

460

Liquid Transportation Fuels from Coal and Biomass  

E-Print Network [OSTI]

Liquid Transportation Fuels from Coal and Biomass Technological Status, Costs, and Environmental Katzer #12;CHARGE TO THE ALTF PANEL · Evaluate technologies for converting biomass and coal to liquid for liquid fuels produced from coal or biomass. · Evaluate environmental, economic, policy, and social

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Original article Micronutrients in biomass fractions  

E-Print Network [OSTI]

Original article Micronutrients in biomass fractions of holm oak, beech and fir forests biomass fractions in individual monospecific stands of holm oak (Quercus ilex L), beech (Fagus sylvatica L in different biomass fractions of the holm oak forest studied. This can be related to the low soil pH values

Boyer, Edmond

462

Gasification reactivities of solid biomass fuels  

SciTech Connect (OSTI)

The design and operation of the biomass based gasification processes require knowledge about the biomass feedstocks characteristics and their typical gasification behaviour in the process. In this study, the gasification reactivities of various biomasses were investigated in laboratory scale Pressurized Thermogravimetric apparatus (PTG) and in the PDU-scale (Process Development Unit) Pressurized Fluidized-Bed (PFB) gasification test facility of VTT.

Moilanen, A.; Kurkela, E.

1995-12-31T23:59:59.000Z

463

CALLA ENERGY BIOMASS COFIRING PROJECT  

SciTech Connect (OSTI)

The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. GTI received supplemental authorization A002 from DOE for additional work to be performed under Phase I that will further extend the performance period until the end of February 2003. The additional scope of work is for GTI to develop the gasification characteristics of selected feedstock for the project. To conduct this work, GTI assembles an existing ''mini-bench'' unit to perform the gasification tests. The results of the test will be used to confirm or if necessary update the process design completed in Phase Task 1. During this Performance Period work efforts focused on conducting tests of biomass feedstock samples on the 2 inch mini-bench gasifier.

Unknown

2002-12-31T23:59:59.000Z

464

CALLA ENERGY BIOMASS COFIRING PROJECT  

SciTech Connect (OSTI)

The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. During this Performance Period work efforts proceeded, and Carbona completed the gasifier island design package. Nexant has completed the balance of plant support systems design and the design for the biomass feed system. Work on the Technoeconomic Study is proceeding. Approximately 75% of the specified hardware quotations have been received at the end of the reporting period. A meeting is scheduled for July 23 rd and 24 th to review the preliminary cost estimates. GTI presented a status review update of the project at the DOE/NETL contractor's review meeting in Pittsburgh on June 21st.

Unknown

2001-07-01T23:59:59.000Z

465

CALLA ENERGY BIOMASS COFIRING PROJECT  

SciTech Connect (OSTI)

The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Natural gas and waste coal fines were evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. A design was developed for a cofiring combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures in a power generation boiler, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. Following the preliminary design, GTI evaluated the gasification characteristics of selected feedstocks for the project. To conduct this work, GTI assembled an existing ''mini-bench'' unit to perform the gasification tests. The results of the test were used to confirm the process design completed in Phase Task 1. As a result of the testing and modeling effort, the selected biomass feedstocks gasified very well, with a carbon conversion of over 98% and individual gas component yields that matched the RENUGAS{reg_sign} model. As a result of this work, the facility appears very attractive from a commercial standpoint. Similar facilities can be profitable if they have access to low cost fuels and have attractive wholesale or retail electrical rates for electricity sales. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. Phase II has not been approved for construction at this time.

Francis S. Lau

2003-09-01T23:59:59.000Z

466

Pyrolysis in Porous Media:1 Part 1. Numerical model and parametric study.2  

E-Print Network [OSTI]

due to the formation of light species and heavy ones (up to solid coke particles). The1 presence by the formation of3 permeable char [10,11]. The coal pyrolysi

Boyer, Edmond

467

Numerical model for the vacuum pyrolysis of scrap tires in batch reactors  

SciTech Connect (OSTI)

A quantitative model for scrap tire pyrolysis in a batch scale reactor developed comprises the following basic phenomena: conduction inside tire particles; conduction, convection, and radiation between the feedstock particles or between the fluids and the particles; tire pyrolysis reaction; exothermicity and endothermicity caused by tire decomposition and volatilization; and the variation of the composition and the thermal properties of tire particles. This model was used to predict the transient temperature and density distributions in the bed of particles, the volatile product evolution rate, the mass change, the energy consumption during the pyrolysis process, and the pressure history in a tire pyrolysis reactor with a load of 1 kg. The model predictions agree well with independent experimental data.

Yang, J.; Tanguy, P.A.; Roy, C. [Univ. Laval, Quebec, PQ (Canada). Dept. de Genie Chimique] [Univ. Laval, Quebec, PQ (Canada). Dept. de Genie Chimique

1995-06-01T23:59:59.000Z

468

Feasibility study for thermal treatment of solid tire wastes in Bangladesh by using pyrolysis technology  

SciTech Connect (OSTI)

In this study on the basis of lab data and available resources in Bangladesh, feasibility study has been carried out for pyrolysis process converting solid tire wastes into pyrolysis oils, solid char and gases. The process considered for detailed analysis was fixed-bed fire-tube heating pyrolysis reactor system. The comparative techno-economic assessment was carried out in US$ for three different sizes plants: medium commercial scale (144 tons/day), small commercial scale (36 tons/day), pilot scale (3.6 tons/day). The assessment showed that medium commercial scale plant was economically feasible, with the lowest unit production cost than small commercial and pilot scale plants for the production of crude pyrolysis oil that could be used as boiler fuel oil and for the production of upgraded liquid-products.

Islam, M.R., E-mail: mrislam1985@yahoo.com [Department of Mechanical Engineering, Rajshahi University of Engineering and Technology, Rajshahi 6204 (Bangladesh); Joardder, M.U.H.; Hasan, S.M. [Department of Mechanical Engineering, Rajshahi University of Engineering and Technology, Rajshahi 6204 (Bangladesh); Takai, K.; Haniu, H. [Department of Mechanical Engineering, National University Corporation Kitami Institute of Technology, 165 Koen-cho, Kitami City, Hokkaido 090-8507 (Japan)

2011-09-15T23:59:59.000Z

469

The role of biomass in California's hydrogen economy  

E-Print Network [OSTI]

hydrogen from dry biomass feedstocks (i.e. straws, stovers,be produced from the wet biomass feedstocks (manures, urban

Parker, Nathan C; Ogden, Joan; Fan, Yueyue

2009-01-01T23:59:59.000Z

470

Group pyrolysis, ignition, and combustion of a spherical cloud of coal particles  

E-Print Network [OSTI]

GROUP PYROLYSIS, IGNITION, AND COMBUSTION OF A SPHERICAL CLOUD OF COAL PARTICLES A Thesis by WILLIAM RICHARD RYAN, JR. Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree MASTER OF SCIENCE December 1988 Major Subject: Mechanical Engineering GROUP PYROLYSIS, IGNITION, AND COMBUSTION OF A SPHERICAL CLOUD OF COAL PARTICLES A Thesis by WIL LI AM RI C HA RD RYA N ~ JR Approved ss to style and content by...

Ryan, William Richard

1988-01-01T23:59:59.000Z

471

BIOMASS FOR HYDROGEN AND OTHER TRANSPORT FUELS -POTENTIALS, LIMITATIONS & COSTS  

E-Print Network [OSTI]

BIOMASS FOR HYDROGEN AND OTHER TRANSPORT FUELS - POTENTIALS, LIMITATIONS & COSTS Senior scientist - "Towards Hydrogen Society" ·biomass resources - potentials, limits ·biomass carbon cycle ·biomass for hydrogen - as compared to other H2- sources and to other biomass paths #12;BIOMASS - THE CARBON CYCLE

472

S-1041 Multistate Research Project The Science and Engineering for a Biobased Industry  

E-Print Network [OSTI]

, Vonore, TN 37885 (865-441-1123) kgoddar3@utk.edu DISTRIBUTED FAST PYROLYSIS FOR CONVERSION OF BIOMASS Industry 2010 Symposium Proceedings 4 THERMOCHEMICAL CONVERSION OF BIOMASS TO ADVANCED BIOFUELS, U.S. DEPARTMENT OF ENERGY, BIOMASS PROGRAM............................................41 Jonathan L. Male

473

CALLA ENERGY BIOMASS COFIRING PROJECT  

SciTech Connect (OSTI)

The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. During this Performance Period work efforts focused on completion of the Topical Report, summarizing the design and techno-economic study of the project's feasibility. GTI received supplemental authorization A002 from DOE contracts for additional work to be performed under Phase I that will further extend the performance period until the end of February 2003. The additional scope of work is for GTI to develop the gasification characteristics of selected feedstock for the project. To conduct this work, GTI will assemble an existing ''mini-bench'' unit to perform the gasification tests. The results of the test will be used to confirm or if necessary update the process design completed in Phase Task 1.

Unknown

2002-09-30T23:59:59.000Z

474

CALLA ENERGY BIOMASS COFIRING PROJECT  

SciTech Connect (OSTI)

The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. During this Performance Period work efforts focused on completion of the Topical Report, summarizing the design and techno-economic study of the project's feasibility. GTI received supplemental authorization A002 from DOE contracts for additional work to be performed under Phase I that will further extend the performance period until the end of 2002. GTI worked with DOE to develop the Statement of Work for the supplemental activities. DOE granted an interim extension of the project until the end of January 2002 to complete the contract paperwork. GTI worked with Calla Energy to develop request for continued funding to proceed with Phase II, submitted to DOE on November 1, 2001.

Unknown

2001-12-31T23:59:59.000Z

475

CALLA ENERGY BIOMASS COFIRING PROJECT  

SciTech Connect (OSTI)

The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. During this Performance Period work efforts focused on completion of the Topical Report, summarizing the design and techno-economic study of the project's feasibility. GTI received supplemental authorization A002 from DOE contracts for additional work to be performed under Phase I that will further extend the performance period until the end of February 2003. The additional scope of work is for GTI to develop the gasification characteristics of selected feedstock for the project. To conduct this work, GTI will assemble an existing ''mini-bench'' unit to perform the gasification tests. The results of the test will be used to confirm or if necessary update the process design completed in Phase Task 1.

Unknown

2002-06-30T23:59:59.000Z

476

CALLA ENERGY BIOMASS COFIRING PROJECT  

SciTech Connect (OSTI)

The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. During this Performance Period work efforts focused on completion of the Topical Report, summarizing the design and techno-economic study of the project's feasibility. GTI received supplemental authorization A002 from DOE contracts for additional work to be performed under Phase I that will further extend the performance period until the end of February 2003. The additional scope of work is for GTI to develop the gasification characteristics of selected feedstock for the project. To conduct this work, GTI will assemble an existing ''mini-bench'' unit to perform the gasification tests. The results of the test will be used to confirm or if necessary update the process design completed in Phase Task 1.

Unknown

2002-03-31T23:59:59.000Z

477

Biomass Basics | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top Five EEREDepartmentFebruary 4, 2014Biogas and Fuel Cells2008:Biomass

478

Engineered plant biomass feedstock particles  

DOE Patents [OSTI]

A new class of plant biomass feedstock particles characterized by consistent piece size and shape uniformity, high skeletal surface area, and good flow properties. The particles of plant biomass material having fibers aligned in a grain are characterized by a length dimension (L) aligned substantially parallel to the grain and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. In particular, the L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers, the W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers, and the L.times.W dimensions define a pair of substantially parallel top and bottom surfaces. The L.times.W surfaces of particles with L/H dimension ratios of 4:1 or less are further elaborated by surface checking between longitudinally arrayed fibers. The length dimension L is preferably aligned within 30.degree. parallel to the grain, and more preferably within 10.degree. parallel to the grain. The plant biomass material is preferably selected from among wood, agricultural crop residues, plantation grasses, hemp, bagasse, and bamboo.

Dooley, James H. (Federal Way, WA); Lanning, David N. (Federal Way, WA); Broderick, Thomas F. (Lake Forest Park, WA)

2012-04-17T23:59:59.000Z

479

Biomass Energy Data Book: Edition 2  

SciTech Connect (OSTI)

The Biomass Energy Data Book is a statistical compendium prepared and published by Oak Ridge National Laboratory (ORNL) under contract with the Biomass Program in the Energy Efficiency and Renewable Energy (EERE) program of the Department of Energy (DOE). Designed for use as a convenient reference, the book represents an assembly and display of statistics and information that characterize the biomass industry, from the production of biomass feedstocks to their end use, including discussions on sustainability. This is the second edition of the Biomass Energy Data Book which is only available online in electronic format. There are five main sections to this book. The first section is an introduction which provides an overview of biomass resources and consumption. Following the introduction to biomass, is a section on biofuels which covers ethanol, biodiesel and bio-oil. The biopower section focuses on the use of biomass for electrical power generation and heating. The fourth section is on the developing area of biorefineries, and the fifth section covers feedstocks that are produced and used in the biomass industry. The sources used represent the latest available data. There are also four appendices which include frequently needed conversion factors, a table of selected biomass feedstock characteristics, assumptions for selected tables and figures, and discussions on sustainability. A glossary of terms and a list of acronyms are also included for the reader's convenience.

Wright, Lynn L [ORNL; Boundy, Robert Gary [ORNL; Badger, Philip C [ORNL; Perlack, Robert D [ORNL; Davis, Stacy Cagle [ORNL

2009-12-01T23:59:59.000Z

480

Biomass Energy Data Book: Edition 4  

SciTech Connect (OSTI)

The Biomass Energy Data Book is a statistical compendium prepared and published by Oak Ridge National Laboratory (ORNL) under contract with the Biomass Program in the Energy Efficiency and Renewable Energy (EERE) program of the Department of Energy (DOE). Designed for use as a convenient reference, the book represents an assembly and display of statistics and information that characterize the biomass industry, from the production of biomass feedstocks to their end use, including discussions on sustainability. This is the fourth edition of the Biomass Energy Data Book which is only available online in electronic format. There are five main sections to this book. The first section is an introduction which provides an overview of biomass resources and consumption. Following the introduction to biomass, is a section on biofuels which covers ethanol, biodiesel and bio-oil. The biopower section focuses on the use of biomass for electrical power generation and heating. The fourth section is on the developing area of biorefineries, and the fifth section covers feedstocks that are produced and used in the biomass industry. The sources used represent the latest available data. There are also two appendices which include frequently needed conversion factors, a table of selected biomass feedstock characteristics, and discussions on sustainability. A glossary of terms and a list of acronyms are also included for the reader's convenience.

Boundy, Robert Gary [ORNL; Diegel, Susan W [ORNL; Wright, Lynn L [ORNL; Davis, Stacy Cagle [ORNL

2011-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "biomass fast pyrolysis" from the National Library of EnergyBeta (NLEBeta).
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481

Biomass Energy Data Book: Edition 3  

SciTech Connect (OSTI)

The Biomass Energy Data Book is a statistical compendium prepared and published by Oak Ridge National Laboratory (ORNL) under contract with the Biomass Program in the Energy Efficiency and Renewable Energy (EERE) program of the Department of Energy (DOE). Designed for use as a convenient reference, the book represents an assembly and display of statistics and information that characterize the biomass industry, from the production of biomass feedstocks to their end use, including discussions on sustainability. This is the third edition of the Biomass Energy Data Book which is only available online in electronic format. There are five main sections to this book. The first section is an introduction which provides an overview of biomass resources and consumption. Following the introduction to biomass, is a section on biofuels which covers ethanol, biodiesel and bio-oil. The biopower section focuses on the use of biomass for electrical power generation and heating. The fourth section is on the developing area of biorefineries, and the fifth section covers feedstocks that are produced and used in the biomass industry. The sources used represent the latest available data. There are also four appendices which include frequently needed conversion factors, a table of selected biomass feedstock characteristics, and discussions on sustainability. A glossary of terms and a list of acronyms are also included for the reader's convenience.

Boundy, Robert Gary [ORNL; Davis, Stacy Cagle [ORNL

2010-12-01T23:59:59.000Z

482

Biomass Energy Data Book: Edition 1  

SciTech Connect (OSTI)

The Biomass Energy Data Book is a statistical compendium prepared and published by Oak Ridge National Laboratory (ORNL) under contract with the Office of the Biomass Program and the Office of Planning, Budget and Analysis in the Department of Energy's Energy Efficiency and Renewable Energy (EERE) program. Designed for use as a desk-top reference, the book represents an assembly and display of statistics and information that characterize the biomass industry, from the production of biomass feedstocks to their end use. This is the first edition of the Biomass Energy Data Book and is currently only available online in electronic format. There are five main sections to this book. The first section is an introduction which provides an overview of biomass resources and consumption. Following the introduction to biomass is a section on biofuels which covers ethanol, biodiesel and BioOil. The biopower section focuses on the use of biomass for electrical power generation and heating. The fourth section is about the developing area of biorefineries, and the fifth section covers feedstocks that are produced and used in the biomass industry. The sources used represent the latest available data. There are also three appendices which include measures of conversions, biomass characteristics and assumptions for selected tables and figures. A glossary of terms and a list of acronyms are also included for the reader's convenience.

Wright, Lynn L [ORNL; Boundy, Robert Gary [ORNL; Perlack, Robert D [ORNL; Davis, Stacy Cagle [ORNL; Saulsbury, Bo [ORNL

2006-09-01T23:59:59.000Z

483

Biomass Energy Data Book, 2011, Edition 4  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The Biomass Energy Data Book is a statistical compendium prepared and published by Oak Ridge National Laboratory (ORNL) under contract with the Biomass Program in the Energy Efficiency and Renewable Energy (EERE) program of the Department of Energy (DOE). Designed for use as a convenient reference, the book represents an assembly and display of statistics and information that characterize the biomass industry, from the production of biomass feedstocks to their end use, including discussions on sustainability. This is the fourth edition of the Biomass Energy Data Book which is only available online in electronic format. There are five main sections to this book. The first section is an introduction which provides an overview of biomass resources and consumption. Following the introduction to biomass, is a section on biofuels which covers ethanol, biodiesel and bio-oil. The biopower section focuses on the use of biomass for electrical power generation and heating. The fourth section is on the developing area of biorefineries, and the fifth section covers feedstocks that are produced and used in the biomass industry. The sources used represent the latest available data. There are also four appendices which include frequently needed conversion factors, a table of selected biomass feedstock characteristics, and discussions on sustainability.

Wright, L.; Boundy, B.; Diegel, S.W.; Davis, S.C.

484

Swelling of kraft black liquor: an understanding of the associated phenomena during pyrolysis  

SciTech Connect (OSTI)

The objectives of this thesis were to quantify the swelling of black liquor during pyrolysis in a nitrogen atmosphere and to determine what factors were responsible for swelling. The first part of the investigation studied the process variables: pyrolysis temperature, solid content, heating rate and particle size. A temperature of 500/sup 0/C resulted in maximum swelling for the investigated temperature range of 300-900/sup 0/C. The swelling of black liquor occurred during the evolution of pyrolysis gases; however, there was no correlation found between the amount of pyrolysis gases evolved and the change in char volume. The initial solid content of black liquor had a small influence on the swelling of black liquor. The heating rate was found to effect the rate of swelling but not the final volume. Particle size had no effect on the swollen volume per unit particle weight. The effect of black liquor composition was studied. An interaction between sugar acids and kraft lignin was responsible for swelling. The extractives interfered with the swelling mechanism of black liquor, while inorganic salts acted as a diluent. The swelling behavior of black liquor appeared to be dictated by the surface active and viscous forces present in black liquor during pyrolysis. Surface active forces were evidenced by the formation of small bubbles (50-150 microns in diameter) which appeared necessary for highly swollen chars. Low swelling chars did not exhibit this phenomenon. Bubble formation began at 250/sup 0/C, which closely corresponded to the thermal decomposition temperature of sugar acids. The sugar acids formed bubbles when pyrolyzed but did not swell significantly during pyrolysis. Kraft lignin appeared to enhance the swelling of the sugar acids by increasing the viscosity and stabilizing the bubbles during pyrolysis.

Miller, P.T.

1986-01-01T23:59:59.000Z

485

Pyrolysis behavior of different type of materials contained in the rejects of packaging waste sorting plants  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Study of the influence of materials in the pyrolysis of real plastic waste samples. Black-Right-Pointing-Pointer Inorganic compounds remain unaltered. Black-Right-Pointing-Pointer Cellulosic components give rise to an increase in char formation. Black-Right-Pointing-Pointer Cellulosic components promote the production of aqueous phase. Black-Right-Pointing-Pointer Cellulosic components increase CO and CO{sub 2} contents in the gases. - Abstract: In this paper rejected streams coming from a waste packaging material recovery facility have been characterized and separated into families of products of similar nature in order to determine the influence of different types of ingredients in the products obtained in the pyrolysis process. The pyrolysis experiments have been carried out in a non-stirred batch 3.5 dm{sup 3} reactor, swept with 1 L min{sup -1} N{sub 2}, at 500 Degree-Sign C for 30 min. Pyrolysis liquids are composed of an organic phase and an aqueous phase. The aqueous phase is greater as higher is the cellulosic material content in the sample. The organic phase contains valuable chemicals as styrene, ethylbenzene and toluene, and has high heating value (HHV) (33-40 MJ kg{sup -1}). Therefore they could be used as alternative fuels for heat and power generation and as a source of valuable chemicals. Pyrolysis gases are mainly composed of hydrocarbons but contain high amounts of CO and CO{sub 2}; their HHV is in the range of 18-46 MJ kg{sup -1}. The amount of CO-CO{sub 2} increases, and consequently HHV decreases as higher is the cellulosic content of the waste. Pyrolysis solids are mainly composed of inorganics and char formed in the process. The cellulosic materials lower the quality of the pyrolysis liquids and gases, and increase the production of char.

Adrados, A., E-mail: aitziber.adrados@ehu.es [Chemical and Environmental Engineering Department, School of Engineering of Bilbao, Alameda. Urquijo s/n, 48013 Bilbao (Spain); De Marco, I.; Lopez-Urionabarrenechea, A.; Caballero, B.M.; Laresgoiti, M.F. [Chemical and Environmental Engineering Department, School of Engineering of Bilbao, Alameda. Urquijo s/n, 48013 Bilbao (Spain)

2013-01-15T23:59:59.000Z

486

Biomass One LP Biomass Facility | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarre BiomassTHIS PAGE IS UNDER(Redirected fromOne

487

APS Biomass I Biomass Facility | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectric Coop,SaveWhiskey FlatshydroMultiple2 Jump to: navigation,APNAAPS Biomass

488

Fabrication of functional nanomaterials using flame assisted spray pyrolysis  

SciTech Connect (OSTI)

Flame assisted spray pyrolysis (FASP) is a class of synthesis method for nanomaterials fabrication. The ability to control nanomaterials characteristics and easy to be-scaled up are the main features of FASP. The crystallinity and particles size of the prepared nanomaterials can be easily controlled by variation of fuel flow rate. The precursor concentration, carrier gas flow rate, and carrier gas can be also used to control the prepared nanomaterials. Energy related nanomaterials preparation uses as the example case in FASP application. These material are yttrium aluminum garnet (YAG:Ce) and tungsten oxide (WO{sub 3}). It needs strategies to produce these materials into nano-sized order. YAG:Ce nanoparticles only can be synthesized by FASP using the urea addition. The decomposition of urea under high temperature of flame promotes the breakage of YAG:Ce particles into nanoparticles. In the preparation of WO{sub 3}, the high temperature flame can be used to gasify WO{sub 3} solid material. As a result, WO{sub 3} nanoparticles can be prepared easily. Generally, to produce nanoparticles via FASP method, the boiling point of the material is important to determine the strategy which will be used.

Purwanto, Agus, E-mail: aguspur@uns.ac.id [Chemical Engineering Department, Faculty of Engineering, Sebelas Maret University, Surakarta 632112 (Indonesia)

2014-02-24T23:59:59.000Z

489

Coke formation during pyrolysis of 1,2-dichloroethane  

SciTech Connect (OSTI)

Most processes involving hydrocarbons or carbon oxides at high temperatures suffer from the disadvantage of coke formation. The formation of coke deposits during pyrolysis of hydrocarbons or chlorinated hydrocarbons is of significant practical importance. Examples of such processes are the steam cracking of alkanes to produce olefins and the thermal decomposition of 1,2-dichloroethane (EDC) for the production of vinyl chloride monomer (VCM). Even id the rate of coke production is low, the cumulative nature of the solid product will result in reactor fouling. The present work deals with the thermal decomposition of EDC. Coke formation has been studied on metal surfaces in a quartz tubular reactor. The rate of coke deposition was measures on metal foils hanging from one arm of a microbalance. A complete analysis of the product gas was accomplished using on-line gas chromatography. The results show that coke deposition during thermal decomposition of EDC depends on the composition of the feed as well as on the nature of the surface of the metal foil. Small amounts of other components (contamination with other chlorinated hydrocarbons as an example) may have a large influence on the rate of coke formation. The results are discussed in terms of surface composition/morphology of the metal foil and the free radical mechanism for thermal decomposition of FDC.

Holmen, A. [Norwegian Institute of Technology, Trondheim (Norway); Lindvag, O.A. [SINTEF Applied Chemistry, Trondheim (Norway)

1995-12-31T23:59:59.000Z

490

Biomass Resource Allocation among Competing End Uses  

SciTech Connect (OSTI)

The Biomass Scenario Model (BSM) is a system dynamics model developed by the U.S. Department of Energy as a tool to better understand the interaction of complex policies and their potential effects on the biofuels industry in the United States. However, it does not currently have the capability to account for allocation of biomass resources among the various end uses, which limits its utilization in analysis of policies that target biomass uses outside the biofuels industry. This report provides a more holistic understanding of the dynamics surrounding the allocation of biomass among uses that include traditional use, wood pellet exports, bio-based products and bioproducts, biopower, and biofuels by (1) highlighting the methods used in existing models' treatments of competition for biomass resources; (2) identifying coverage and gaps in industry data regarding the competing end uses; and (3) exploring options for developing models of biomass allocation that could be integrated with the BSM to actively exchange and incorporate relevant information.

Newes, E.; Bush, B.; Inman, D.; Lin, Y.; Mai, T.; Martinez, A.; Mulcahy, D.; Short, W.; Simpkins, T.; Uriarte, C.; Peck, C.

2012-05-01T23:59:59.000Z

491

Understanding Substrate Features Influenced by Pretreatments that Limit Biomass Deconstruction by Enzymes  

E-Print Network [OSTI]

Biomass feedstocks .Materials and Methods Biomass feedstocks Two kinds ofthe screening of biomass feedstocks. In this study, a one-

Gao, Xiadi

2013-01-01T23:59:59.000Z

492

Biomass Compositional Analysis Laboratory (Fact Sheet)  

SciTech Connect (OSTI)

At the Biomass Compositional Analysis Laboratory, NREL scientists have more than 20 years of experience supporting the biomass conversion industry. They develop, refine, and validate analytical methods to determine the chemical composition of biomass samples before, during, and after conversion processing. These high-quality compositional analysis data are used to determine feedstock compositions as well as mass balances and product yields from conversion processes.

Not Available

2014-07-01T23:59:59.000Z

493

Estimates of US biomass energy consumption 1992  

SciTech Connect (OSTI)

This report is the seventh in a series of publications developed by the Energy Information Administration (EIA) to quantify the biomass-derived primary energy used by the US economy. It presents estimates of 1991 and 1992 consumption. The objective of this report is to provide updated estimates of biomass energy consumption for use by Congress, Federal and State agencies, biomass producers and end-use sectors, and the public at large.

Not Available

1994-05-06T23:59:59.000Z

494

Bayport Biomass Facility | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarre Biomass Facility Jump to:Sector BiomassBayport Biomass

495

Prospects for pyrolysis technologies in managing municipal, industrial, and DOE cleanup wastes  

SciTech Connect (OSTI)

Pyrolysis converts portions of municipal solid wastes, hazardous wastes, and special wastes such as tires, medical wastes, and even old landfills into solid carbon and a liquid or gaseous hydrocarbon stream. Pyrolysis heats a carbonaceous waste stream typically to 290--900 C in the absence of oxygen, and reduces the volume of waste by 90% and its weight by 75%. The solid carbon char has existing markets as an ingredient in many manufactured goods, and as an adsorbent or filter to sequester certain hazardous wastes. Pyrolytic gases may be burned as fuel by utilities, or liquefied for use as chemical feedstocks, or low-pollution motor vehicle fuels and fuel additives. This report analyzes the potential applications of pyrolysis in the Long Island region and evaluates for the four most promising pyrolytic systems their technological and commercial readiness, their applicability to regional waste management needs, and their conformity with DOE requirements for environmental restoration and waste management. This summary characterizes their engineering performance, environmental effects, costs, product applications, and markets. Because it can effectively treat those wastes that are inadequately addressed by current systems, pyrolysis can play an important complementing role in the region`s existing waste management strategy. Its role could be even more significant if the region moves away from existing commitments to incineration and MSW composting. Either way, Long Island could become the center for a pyrolysis-based recovery services industry serving global markets in municipal solid waste treatment and hazardous waste cleanup. 162 refs.

Reaven, S.J. [State Univ. of New York, Stony Brook, NY (United States)

1994-12-01T23:59:59.000Z

496

Biomass 2014 Breakout Speaker Biographies  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd: ScopeDepartment1, 2011 (BETO)and Fuel09 ConferenceBiomass

497

Determination of Extractives in Biomass: Laboratory Analytical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extractives in Biomass Laboratory Analytical Procedure (LAP) Issue Date: 7172005 A. Sluiter, R. Ruiz, C. Scarlata, J. Sluiter, and D. Templeton Technical Report NRELTP-510-42619...

498

NREL: Biomass Research - Ryan M. Ness  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ryan M. Ness Ryan Ness is a research technician with the National Bioenergy Center Biomass Analysis Group at NREL. Ryan has been with NREL since 2007. Ryan's primary...

499

SSF Experimental Protocols -- Lignocellulosic Biomass Hydrolysis...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SSF Experimental Protocols - Lignocellulosic Biomass Hydrolysis and Fermentation Laboratory Analytical Procedure (LAP) Issue Date: 10302001 N. Dowe and J. McMillan Technical...

500

Enzymatic Saccharification of Lignocellulosic Biomass: Laboratory...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enzymatic Saccharification of NRELTP-510-42629 Lignocellulosic Biomass March 2008 Laboratory Analytical Procedure (LAP) Issue Date: 3212008 M. Selig, N. Weiss, and Y. Ji NREL is...