Sample records for biomass co-firing coal-fired

  1. A supply chain network design model for biomass co-firing in coal-fired power plants

    SciTech Connect (OSTI)

    Md. S. Roni; Sandra D. Eksioglu; Erin Searcy; Krishna Jha

    2014-01-01T23:59:59.000Z

    We propose a framework for designing the supply chain network for biomass co-firing in coal-fired power plants. This framework is inspired by existing practices with products with similar physical characteristics to biomass. We present a hub-and-spoke supply chain network design model for long-haul delivery of biomass. This model is a mixed integer linear program solved using benders decomposition algorithm. Numerical analysis indicates that 100 million tons of biomass are located within 75 miles from a coal plant and could be delivered at $8.53/dry-ton; 60 million tons of biomass are located beyond 75 miles and could be delivered at $36/dry-ton.

  2. Co-firing biomass

    SciTech Connect (OSTI)

    Hunt, T.; Tennant, D. [Hunt, Guillot & Associates LLC (United States)

    2009-11-15T23:59:59.000Z

    Concern about global warming has altered the landscape for fossil-fuel combustion. The advantages and challenges of co-firing biomass and coal are discussed. 2 photos.

  3. GASIFICATION BASED BIOMASS CO-FIRING

    SciTech Connect (OSTI)

    Babul Patel; Kevin McQuigg; Robert Toerne; John Bick

    2003-01-01T23:59:59.000Z

    Biomass gasification offers a practical way to use this widespread fuel source for co-firing traditional large utility boilers. The gasification process converts biomass into a low Btu producer gas that can be used as a supplemental fuel in an existing utility boiler. This strategy of co-firing is compatible with a variety of conventional boilers including natural gas and oil fired boilers, pulverized coal fired conventional and cyclone boilers. Gasification has the potential to address all problems associated with the other types of co-firing with minimum modifications to the existing boiler systems. Gasification can also utilize biomass sources that have been previously unsuitable due to size or processing requirements, facilitating a wider selection of biomass as fuel and providing opportunity in reduction of carbon dioxide emissions to the atmosphere through the commercialization of this technology. This study evaluated two plants: Wester Kentucky Energy Corporation's (WKE's) Reid Plant and TXU Energy's Monticello Plant for technical and economical feasibility. These plants were selected for their proximity to large supply of poultry litter in the area. The Reid plant is located in Henderson County in southwest Kentucky, with a large poultry processing facility nearby. Within a fifty-mile radius of the Reid plant, there are large-scale poultry farms that generate over 75,000 tons/year of poultry litter. The local poultry farmers are actively seeking environmentally more benign alternatives to the current use of the litter as landfill or as a farm spread as fertilizer. The Monticello plant is located in Titus County, TX near the town of Pittsburgh, TX, where again a large poultry processor and poultry farmers in the area generate over 110,000 tons/year of poultry litter. Disposal of this litter in the area is also a concern. This project offers a model opportunity to demonstrate the feasibility of biomass co-firing and at the same time eliminate poultry litter disposal problems for the area's poultry farmers.

  4. GASIFICATION BASED BIOMASS CO-FIRING - PHASE I

    SciTech Connect (OSTI)

    Babul Patel; Kevin McQuigg; Robert F. Toerne

    2001-12-01T23:59:59.000Z

    Biomass gasification offers a practical way to use this locally available fuel source for co-firing traditional large utility boilers. The gasification process converts biomass into a low Btu producer gas that can be fed directly into the boiler. This strategy of co-firing is compatible with variety of conventional boilers including natural gas fired boilers as well as pulverized coal fired and cyclone boilers. Gasification has the potential to address all problems associated with the other types of co-firing with minimum modifications to the existing boiler systems. Gasification can also utilize biomass sources that have been previously unsuitable due to size or processing requirements, facilitating a reduction in the primary fossil fuel consumption in the boiler and thereby reducing the greenhouse gas emissions to the atmosphere.

  5. Nitrogen oxides emission control through reburning with biomass in coal-fired power plants

    E-Print Network [OSTI]

    Arumugam, Senthilvasan

    2005-02-17T23:59:59.000Z

    be applied to farmland in accordance with nutrient management plans and stockpiled waste poses economic and environmental liabilities. In the present study, the feasibility of using biomass as a reburn fuel in existing coal-fired power plants is considered...

  6. Co-firing of coal and biomass fuel blends M. Sami, K. Annamalai*, M. Wooldridge1

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    Co-firing of coal and biomass fuel blends M. Sami, K. Annamalai*, M. Wooldridge1 Department; accepted 6 June 2000 Abstract This paper reviews literature on co-firing of coal with biomass fuels. Here of coal and biomass fuels are presented. Different classes of co-firing methods are identified

  7. The effects of moisture and particle size of feedlot biomass on co-firing burner performance

    E-Print Network [OSTI]

    Chen, Chen-Jung

    2001-01-01T23:59:59.000Z

    Biomass (conventional and non-conventional) fuels co-fired with coal for power and steam generation are being tested and evaluated at several generation stations in the United States. The co-firing technology is expected to reduce landfill...

  8. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS (CFB AND CLB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS

    SciTech Connect (OSTI)

    Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thein; Gengsheng Wei; Soyuz Priyadarsan; Senthil Arumugam; Kevin Heflin

    2003-08-28T23:59:59.000Z

    Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain-diet diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. The manure could be used as a fuel by mixing it with coal in a 90:10 blend and firing it in an existing coal suspension fired combustion systems. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Reburn is a process where a small percentage of fuel called reburn fuel is injected above the NO{sub x} producing, conventional coal fired burners in order to reduce NO{sub x}. The manure could also be used as reburn fuel for reducing NO{sub x} in coal fired plants. An alternate approach of using animal waste is to adopt the gasification process using a fixed bed gasifier and then use the gases for firing in gas turbine combustors. In this report, the cattle manure is referred to as feedlot biomass (FB) and chicken manure as litter biomass (LB). The report generates data on FB and LB fuel characteristics. Co-firing, reburn, and gasification tests of coal, FB, LB, coal: FB blends, and coal: LB blends and modeling on cofiring, reburn systems and economics of use of FB and LB have also been conducted. The biomass fuels are higher in ash, lower in heat content, higher in moisture, and higher in nitrogen and sulfur (which can cause air pollution) compared to coal. Small-scale cofiring experiments revealed that the biomass blends can be successfully fired, and NO{sub x} emissions will be similar to or lower than pollutant emissions when firing coal. Further experiments showed that biomass is twice or more effective than coal when used in a reburning process. Computer simulations for coal: LB blends were performed by modifying an existing computer code to include the drying and phosphorus (P) oxidation models. The gasification studies revealed that there is bed agglomeration in the case of chicken litter biomass due to its higher alkaline oxide content in the ash. Finally, the results of the economic analysis show that considerable fuel cost savings can be achieved with the use of biomass. In the case of higher ash and moisture biomass, the fuel cost savings is reduced.

  9. Nitrogen oxides emission control through reburning with biomass in coal-fired power plants 

    E-Print Network [OSTI]

    Arumugam, Senthilvasan

    2005-02-17T23:59:59.000Z

    Oxides of nitrogen from coal-fired power stations are considered to be major pollutants, and there is increasing concern for regulating air quality and offsetting the emissions generated from the use of energy. Reburning ...

  10. Mercury emission control for coal fired power plants using coal and biomass

    E-Print Network [OSTI]

    Arcot Vijayasarathy, Udayasarathy

    2009-05-15T23:59:59.000Z

    . The Environmental Protection Agency (EPA) reports for 2001 shows that total mercury emissions from all sources in USA is about 145 tons per annum, of which coal fired power plants contribute around 33% of it, about 48 tons per annum. Unlike other trace metals...

  11. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS

    SciTech Connect (OSTI)

    Dr. Kalyan Annamalai; Dr. John Sweeten; Dr. Sayeed Mukhtar

    2001-05-10T23:59:59.000Z

    The following are proposed activities for quarter 3 (12/15/00-3/14/01): (1) Conduct TGA and fuel characterization studies - Task 1; (2) Continue to perform re-burn experiments. - Task 2; (3) Design fixed bed combustor. - Task 3; and (4) Modify the PCGC2 code to include moisture evaporation model - Task 4. The following were achieved During Quarter 3 (12/15/0-3/14/01): (1) Conducted TGA and Fuel Characterization studies (Appendix I). A comparison of -fuel properties, TGA traces etc is given in Appendix I. Litter has 3 and 6 times more N compared to coal on mass and heat basis. The P of litter is almost 2 % (Task 1). Both litter biomass (LB) and feedlot biomass (FB) have been pulverized. The size distributions are similar for both litter and FB in that 75 % pass through 150 {micro}m sieve while for coal 75 % pass through 60 {micro}m sieve. Rosin Rammler curve parameters are given. The TGA characteristics of FB and LB are similar and pyrolysis starts at 100 C below that of coal; (2) Reburn experiments with litter and with FB have been performed (Appendix II) -Task 2. Litter is almost twice effective (almost 70--90 % reduction) compared to coal in reducing the NOx possibly due to presence of N in the form of NH{sub 3}; (3) Designed fixed bed gasifier/combustor (Appendix III) - Task 3; and (4) Modified PCGC2 to include moisture evaporation model in coal and biomass particles. (Appendix IV) - Task 4.

  12. Formulation, Pretreatment, and Densification Options to Improve Biomass Specifications for Co-Firing High Percentages with Coal

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru; J Richard Hess; Richard D. Boardman; Shahab Sokhansanj; Christopher T. Wright; Tyler L. Westover

    2012-06-01T23:59:59.000Z

    There is a growing interest internationally to use more biomass for power generation, given the potential for significant environmental benefits and long-term fuel sustainability. However, the use of biomass alone for power generation is subject to serious challenges, such as feedstock supply reliability, quality, and stability, as well as comparative cost, except in situations in which biomass is locally sourced. In most countries, only a limited biomass supply infrastructure exists. Alternatively, co-firing biomass alongwith coal offers several advantages; these include reducing challenges related to biomass quality, buffering the system against insufficient feedstock quantity, and mitigating the costs of adapting existing coal power plants to feed biomass exclusively. There are some technical constraints, such as low heating values, low bulk density, and grindability or size-reduction challenges, as well as higher moisture, volatiles, and ash content, which limit the co-firing ratios in direct and indirect co-firing. To achieve successful co-firing of biomass with coal, biomass feedstock specifications must be established to direct pretreatment options in order to modify biomass materials into a format that is more compatible with coal co-firing. The impacts on particle transport systems, flame stability, pollutant formation, and boiler-tube fouling/corrosion must also be minimized by setting feedstock specifications, which may include developing new feedstock composition by formulation or blending. Some of the issues, like feeding, co-milling, and fouling, can be overcome by pretreatment methods including washing/leaching, steam explosion, hydrothermal carbonization, and torrefaction, and densification methods such as pelletizing and briquetting. Integrating formulation, pretreatment, and densification will help to overcome issues related to physical and chemical composition, storage, and logistics to successfully co-fire higher percentages of biomass ( > 40%) with coal.

  13. Reburning renewable biomass for emissions control and ash deposition effects in power generation

    E-Print Network [OSTI]

    Oh, Hyuk Jin

    2009-05-15T23:59:59.000Z

    Cattle biomass (CB) has been proposed as a renewable, supplementary fuel for co-firing and reburning. Reburning coal with CB has the potential to reduce NOx and Hg emissions from coal fired systems. The present research focuses on three areas...

  14. Full-Scale Boiler Measurements Demonstrating Striated Flows during Biomass Co-Firing

    E-Print Network [OSTI]

    based measurements methods #12;Objective Minor impact of biomass cofiring with coal on boiler operation and performance at biomass shares below 20% on an energy basis. Dilution of biomass ash stream reduce potential;06-02-2008 Coal burner side: 1.5 m inside boiler thermal load 433 MW boiler thermal load 440-471 MW #12

  15. Development of a Low NOx Burner System for Coal Fired Power Plants Using Coal and Biomass Blends 

    E-Print Network [OSTI]

    Gomez, Patsky O.

    2010-01-16T23:59:59.000Z

    &M University (TAMU) demonstrated that cofiring coal with feedlot biomass (FB) in conventional burners produced lower or similar levels of NOx but increased CO. The present research deals with i) construction of a small scale 29.31 kW (100,000 BTU/hr) LNB...

  16. Development of a Low NOx Burner System for Coal Fired Power Plants Using Coal and Biomass Blends

    E-Print Network [OSTI]

    Gomez, Patsky O.

    2010-01-16T23:59:59.000Z

    composted, dairy biomass (LA-PC-DB-SepS) had the following heat values and empirical formulas: CH0.6992N0.0122O0.1822S0.00217 and CH_1.2554N_0.0470O_0.3965S_0.00457. The WYO contained 3.10 kg of Ash/GJ, 15.66 kg of VM/GJ, 0.36 kg of N/GJ, and 6.21 kg of O...

  17. Effect of Co-Firing Torrefied Woody Biomass with Coal in a 30 kWt Downfired Burner 

    E-Print Network [OSTI]

    Thanapal, Siva S

    2014-04-25T23:59:59.000Z

    .g. grindability) properties of raw biomass. A simple three component parallel reaction model (TCM) was formulated to study the effect of heating rate, temperature, residence time and type of biomass on torrefaction process. Typically inert environment (e.g. N_(2...

  18. Carbon Dioxide Capture from Coal-Fired

    E-Print Network [OSTI]

    Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis May 2005 MIT LFEE 2005. LFEE 2005-002 Report #12;#12;i ABSTRACT Investments in three coal-fired power generation technologies environment. The technologies evaluated are pulverized coal (PC), integrated coal gasification combined cycle

  19. DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN CO-FIRING BIOMASS WITH COAL

    SciTech Connect (OSTI)

    Larry G. Felix; P. Vann Bush

    2002-07-01T23:59:59.000Z

    This is the seventh Quarterly Technical Report for DOE Cooperative Agreement No. DE-FC26-00NT40895. A statement of the project objectives is included in the Introduction of this report. Two additional biomass co-firing test burns were conducted during this quarter. In the first test (Test 12), up to 20% by weight dry hardwood sawdust and switchgrass was comilled with Galatia coal and injected through the single-register burner. Liquid ammonia was intermittently added to the primary air stream to increase fuel-bound nitrogen and simulate cofiring with chicken litter. Galatia coal is a medium-sulfur ({approx} 1.2% S), high chlorine ({approx}0.5%) Illinois Basin coal. In the second test (Test 13), up to 20% by weight dry hardwood sawdust and switchgrass was comilled with Jim Walters No.7 mine coal and injected through the single-register burner. Jim Walters No.7 coal is a low-volatility, low-sulfur ({approx} 0.7% S) Eastern bituminous coal. The results of these tests are presented in this quarterly report. Progress has continued to be made in implementing a modeling approach to combine reaction times and temperature distributions from computational fluid dynamic models of the pilot-scale combustion furnace with char burnout and chemical reaction kinetics to predict NO{sub x} emissions and unburned carbon levels in the furnace exhaust. The Configurable Fireside Simulator has been delivered from REI, Inc. and is being tested with exiting CFD solutions. Preparations are under way for a final pilot-scale combustion experiment using the single-register burner fired with comilled mixtures of Jim Walters No.7 low-volatility bituminous coal and switchgrass. Because of the delayed delivery of the Configurable Fireside Simulator, it is planned to ask for a no-cost time extension for the project until the end of this calendar year. Finally, a paper describing this project that included preliminary results from the first four cofiring tests was presented at the 12th European Conference and Technology Exhibition on Biomass for Energy, Industry and Climate Protection in Amsterdam, The Netherlands, in June, 2002.

  20. Coal-fired diesel generator

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    The objective of the proposed project is to test the technical, environmental, and economic viability of a coal-fired diesel generator for producing electric power in small power generating markets. Coal for the diesel generator would be provided from existing supplies transported for use in the University`s power plant. A cleanup system would be installed for limiting gaseous and particulate emissions. Electricity and steam produced by the diesel generator would be used to supply the needs of the University. The proposed diesel generator and supporting facilities would occupy approximately 2 acres of land adjacent to existing coal- and oil-fired power plant and research laboratory buildings at the University of Alaska, Fairbanks. The environmental analysis identified that the most notable changes to result from the proposed project would occur in the following areas: power plant configuration at the University of Alaska, Fairbanks; air emissions, water use and discharge, and the quantity of solid waste for disposal; noise levels at the power plant site; and transportation of coal to the power plant. No substantive adverse impacts or environmental concerns were identified in analyzing the effects of these changes.

  1. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01T23:59:59.000Z

    Coal-fired power generating plants contribute approximatelynumber of coal-fired generating plants (1-3). The mercury is

  2. Coal-fired generation staging a comeback. 2nd ed.

    SciTech Connect (OSTI)

    NONE

    2007-07-01T23:59:59.000Z

    The report is an overview of the renewed U.S. market interest in coal-fired power generation. It provides a concise look at what is driving interest in coal-fired generation, the challenges faced in implementing coal-fired generation projects, and the current and future state of coal-fired generation. Topics covered in the report include: An overview of coal-fired generation including its history, the current market environment, and its future prospects; An analysis of the key business factors that are driving renewed interest in coal-fired generation; An analysis of the challenges that are hindering the implementation of coal-fired generation projects; A description of coal-fired generation technologies; A review of the economic drivers of coal-fired generation project success; An evaluation of coal-fired generation versus other generation technologies; A discussion of the key government initiatives supporting new coal-fired generation; and A listing of planned coal-fired generation projects. 13 figs., 12 tabs., 1 app.

  3. Coal-Fired Fluidized Bed Combustion Cogeneration

    E-Print Network [OSTI]

    Thunem, C.; Smith, N.

    COAL-FIRED FLUIDIZED BED COMBUSTION COGENERATION Cabot Thunem, P.E Norm Smith, P.E. Stanley Consultants, Inc. Muscatine, Iowa ABSTRACT The availability of an environmentally accep table multifuel technology, such as fluidized bed... combustion, has encouraged many steam producers/ users to investigate switching from oil or gas to coal. Changes in federal regulations encouraging cogeneration have further enhanced the economic incentives for primary fuel switching. However...

  4. advanced coal-fired gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    coal-fired unit at Hawthorn Station. Ultimately, KCPL decided to replace the destroyed steam generator with another coal-fired unit, and repower the existing turbinegenerator...

  5. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, Charles L. (Tullahoma, TN); Foote, John P. (Tullahoma, TN)

    1995-01-01T23:59:59.000Z

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler, the converted boiler including a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones.

  6. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, C.L.; Foote, J.P.

    1995-07-04T23:59:59.000Z

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler are disclosed. The converted boiler includes a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones. 19 figs.

  7. Development of a Software System to Facilitate Implementation of Coal and Wood Co-Fired Bilers

    E-Print Network [OSTI]

    Gopalakrishnan, B.; Gump, C. D.; Gupta, D. P.; Chaudhari, S.

    2013-01-01T23:59:59.000Z

    Coal and wood co-fired boiler technology has improved significantly over the years. The term "co-firing", when used by members of the biomass or utility communities, has come to mean mixing a modest amount of clean, dry sawdust with coal and burning...

  8. Development of a Software System to Facilitate Implementation of Coal and Wood Co-Fired Bilers 

    E-Print Network [OSTI]

    Gopalakrishnan, B.; Gump, C. D.; Gupta, D. P.; Chaudhari, S.

    2013-01-01T23:59:59.000Z

    Coal and wood co-fired boiler technology has improved significantly over the years. The term "co-firing", when used by members of the biomass or utility communities, has come to mean mixing a modest amount of clean, dry sawdust with coal and burning...

  9. DEVELOPMENT OF A VALIDATED MODEL FOR USE IN MINIMIZING NOx EMISSIONS AND MAXIMIZING CARBON UTILIZATION WHEN CO-FIRING BIOMASS WITH COAL

    SciTech Connect (OSTI)

    Larry G. Felix; P. Vann Bush; Stephen Niksa

    2003-04-30T23:59:59.000Z

    In full-scale boilers, the effect of biomass cofiring on NO{sub x} and unburned carbon (UBC) emissions has been found to be site-specific. Few sets of field data are comparable and no consistent database of information exists upon which cofiring fuel choice or injection system design can be based to assure that NOX emissions will be minimized and UBC be reduced. This report presents the results of a comprehensive project that generated an extensive set of pilot-scale test data that were used to validate a new predictive model for the cofiring of biomass and coal. All testing was performed at the 3.6 MMBtu/hr (1.75 MW{sub t}) Southern Company Services/Southern Research Institute Combustion Research Facility where a variety of burner configurations, coals, biomasses, and biomass injection schemes were utilized to generate a database of consistent, scalable, experimental results (422 separate test conditions). This database was then used to validate a new model for predicting NO{sub x} and UBC emissions from the cofiring of biomass and coal. This model is based on an Advanced Post-Processing (APP) technique that generates an equivalent network of idealized reactor elements from a conventional CFD simulation. The APP reactor network is a computational environment that allows for the incorporation of all relevant chemical reaction mechanisms and provides a new tool to quantify NOx and UBC emissions for any cofired combination of coal and biomass.

  10. Biomass torrefaction and CO2 capture using mining wastes A new approach for reducing greenhouse gas emissions of co-firing plants

    E-Print Network [OSTI]

    Devernal, Anne

    substitution of coal with biomass as a renewable energy source, i.e., normally viewed as CO2 neutral in energy a , Faďçal Larachi b, a Department of Chemical Engineering, Université Laval, Québec G1V 0A6, Canada b Department of Geology and Geological Engineering, Université Laval, Québec, QC G1V 0A6, Canada h i g h l i g

  11. Application of Multivariable Control to Oil and Coal Fired Boilers

    E-Print Network [OSTI]

    Swanson, K.

    1981-01-01T23:59:59.000Z

    Increased visibility provided by advanced measurement and control techniques has shown that control of oil and coal fired boilers is a complex problem involving simultaneous determination of flue gas carbon monoxide, hydrocarbon, opacity...

  12. Global Installed Capacity of Coal Fired Power Generation to Reach...

    Open Energy Info (EERE)

    Global Installed Capacity of Coal Fired Power Generation to Reach 2,057.6 GW by 2019 Home > Groups > Increase Natural Gas Energy Efficiency John55364's picture Submitted by...

  13. Exxon Chemical's Coal-Fired Combined Cycle Power Technology

    E-Print Network [OSTI]

    Guide, J. J.

    EXXON CHEMICAL'S COAL-FIRED COMBINED CYCLE POWER TECHNOLOGY John J. Guide, P.E. Exxon Chemical Company Florham Park, New Jersey ABSTRACT Exxon Chemical's Central Engineering Divi sion has recently developed and patented CAT...-PAC for Industrial Cogeneration and Utility Power Plants. It involves the marriage of a conven tional direct pulverized coal-fired boiler radiant section with a convection section adapted ~rom our furnace experience. In particular, it 1S an open-cycle, hot air...

  14. advanced coal fired: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a possible co-firing fuel with coal. Cofiring of DB offers a technique of utilizing dairy manure for powersteam generation, reducing greenhouse gas concerns, and increasing...

  15. Geology of coal fires: case studies from around the world

    SciTech Connect (OSTI)

    Glenn B. Stracher (ed.)

    2008-01-15T23:59:59.000Z

    Coal fires are preserved globally in the rock record as burnt and volume-reduced coal seams and by pyrometamorphic rocks, explosion breccias, clinker, gas-vent-mineral assemblages, fire-induced faulting, ground fissures, slump blocks, and sinkholes. Coal fires are responsible for coronary and respiratory diseases and fatalities in humans, as well as arsenic and fluorine poisoning. Their heat energy, toxic fumes, and solid by-products of combustion destroy floral and faunal habitats while polluting the air, water, and soil. This volume includes chapters devoted to spontaneous combustion and greenhouse gases, gas-vent mineralogy and petrology, paralavas and combustion metamorphic rocks, geochronology and landforms, magnetic signatures and geophysical modeling, remote-sensing detection and fire-depth estimation of concealed fires, and coal fires and public policy.

  16. Advanced Development Of The Coal Fired Oxyfuel Process With CO2...

    Open Energy Info (EERE)

    Coal Fired Oxyfuel Process With CO2 Separation ADECOS Jump to: navigation, search Name: Advanced Development Of The Coal-Fired Oxyfuel Process With CO2 Separation (ADECOS) Place:...

  17. Efficiency and Environmental Impacts of Electricity Restructuring on Coal-fired Power Plants

    E-Print Network [OSTI]

    Efficiency and Environmental Impacts of Electricity Restructuring on Coal-fired Power Plants Hei efficiency, cost of coal purchases, and utilization among coal-fired power plants using a panel data set from recent years allows us to examine longer term impacts of restructuring; (2) the focus on coal-fired power

  18. Quantification of Variability and Uncertainty in Hourly NOx Emissions from Coal-Fired Power Plants

    E-Print Network [OSTI]

    Frey, H. Christopher

    to quantify variability and uncertainty for NOx emissions from coal-fired power plants. Data for hourly NOx Uncertainty, Variability, Emission Factors, Coal-Fired Power Plants, NOx emissions, Regression Models for different source categories, NOx emissions from coal-fired power plants are analyzed in this #12;2 paper

  19. Modification of boiler operating conditions for mercury emissions reductions in coal-fired utility boilers

    E-Print Network [OSTI]

    Li, Ying

    's studies have determined that mercury emissions from coal-fired power plants pose significant hazards to public health and must be reduced. Coal-fired power plants represent a significant fraction and reduce Hg emissions from coal-fired power plants. EPA is proposing two alternatives that include

  20. Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis Ram Chandra Sekar

    E-Print Network [OSTI]

    Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis by Ram Chandra Sekar;2 #12;3 Carbon Dioxide Capture in Coal-Fired Power Plants: A Real Options Analysis by Ram Chandra Sekar less expensive (pre-investment IGCC). All coal-fired power plants can be retrofitted to capture CO2

  1. Exxon Chemical's Coal-Fired Combined Cycle Power Technology 

    E-Print Network [OSTI]

    Guide, J. J.

    1985-01-01T23:59:59.000Z

    for the boiler. The air coil heats the 150 psig air from the standard gas turbine axial compressor to approximately, 1750°F. Today, CAT-PAC would require about 10% less fuel (or 1000 Btu/kwh) than the best coal-fired Utility Plant for the same net power output...

  2. BioCoComb -- Gasification of biomass and co-combustion of the gas in a pulverized-coal-boiler

    SciTech Connect (OSTI)

    Anderl, H.; Zotter, T.; Mory, A.

    1999-07-01T23:59:59.000Z

    In a demonstration project supported by an European Community Thermie Fund a biomass gasifier for bark, wood chips, saw dust, etc. has been installed by Austrian Energy and Environment at the 137 MW{sub el} pulverized-coal fired power station in Zeltweg, Austria. The project title BioCoComb is an abbreviation for Preparation of Biofuel for Co-Combustion, where co-combustion means combustion together with coal in existing power plants. According to the thermal capacity of 10 MW the produced gas substitutes approx. 3% of the coal fired in the boiler. Only the coarse fraction of the biomass has to pass a shredder and is then fed together with the fine fraction without any further pretreatment into the gasifier. In the gasification process the biomass will combust in a substoichiometric atmosphere, create the necessary temperature of 820 C and partly gasify due to the lack of oxygen in the combustion chamber (autothermal operation). The gasifier uses circulating fluidized bed technology, which guarantees even relatively low temperatures in all parts of the gasifier to prevent slagging. The intense motion of the bed material also favors attrition of the biomass particles. Via a hot gas duct the produced low calorific value (LCV) gas is directly led into the furnace of the existing pulverized coal fired boiler for combustion. The gas also contains fine wood char particles, that can pass the retention cyclone and burn out in the furnace of the coal boiler. The main advantages of the BioCoComb concept are: low gas quality sufficient for co-firing; no gas cleaning or cooling; no predrying of the biomass; relatively low temperatures in the gasifier to prevent slagging; favorable effects on power plant emissions (CO{sub 2}, NO{sub x}); no severe modifications of the existing coal fired boiler; and high flexibility in arranging and integrating the main components into existing plants. The plant started its trial run in November 1997 and has been in successful commercial operation since January 1998.

  3. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Martin Denison; Adel Sarofim; Connie Senior; Hong-Shig Shim; Dave Swenson; Bob Hurt; Eric Suuberg; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker

    2006-06-30T23:59:59.000Z

    This is the Final Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project was to develop cost-effective analysis tools and techniques for demonstrating and evaluating low-NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) provided co-funding for this program. This project included research on: (1) In furnace NOx control; (2) Impacts of combustion modifications on boiler operation; (3) Selective Catalytic Reduction (SCR) catalyst testing and (4) Ammonia adsorption/removal on fly ash. Important accomplishments were achieved in all aspects of the project. Rich Reagent Injection (RRI), an in-furnace NOx reduction strategy based on injecting urea or anhydrous ammonia into fuel rich regions in the lower furnace, was evaluated for cyclone-barrel and PC fired utility boilers. Field tests successfully demonstrated the ability of the RRI process to significantly reduce NOx emissions from a staged cyclone-fired furnace operating with overfire air. The field tests also verified the accuracy of the Computational Fluid Dynamic (CFD) modeling used to develop the RRI design and highlighted the importance of using CFD modeling to properly locate and configure the reagent injectors within the furnace. Low NOx firing conditions can adversely impact boiler operation due to increased waterwall wastage (corrosion) and increased soot production. A corrosion monitoring system that uses electrochemical noise (ECN) corrosion probes to monitor, on a real-time basis, high temperature corrosion events within the boiler was evaluated. Field tests were successfully conducted at two plants. The Ohio Coal Development Office provided financial assistance to perform the field tests. To investigate soot behavior, an advanced model to predict soot production and destruction was implemented into an existing reacting CFD modeling tool. Comparisons between experimental data collected in a pilot scale furnace and soot behavior predicted by the CFD model showed good agreement. Field and laboratory tests were performed for SCR catalysts used for coal and biomass co-firing applications. Fundamental laboratory studies were performed to better understand mechanisms involved with catalyst deactivation. Field tests with a slip stream reactor were used to create catalyst exposed to boiler flue gas for firing coal and for co-firing coal and biomass. The field data suggests the mechanisms leading to catalyst deactivation are, in order of importance, channel plugging, surface fouling, pore plugging and poisoning. Investigations were performed to better understand the mechanisms involved with catalyst regeneration through mechanical or chemical methods. A computer model was developed to predict NOx reduction across the catalyst in a SCR. Experiments were performed to investigate the fundamentals of ammonia/fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. Measurements were performed for ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes. This work resulted in the first fundamental ammonia isotherms on carbon-containing fly ash samples. This work confirms industrial reports that aqueous solution chemistry takes place upon the introduction of even very small amounts of water, while the ash remains in a semi-dry state.

  4. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Temi Linjewile; Connie Senior; Eric Eddings; Kevin Whitty; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding; Robert Hurt

    2003-12-31T23:59:59.000Z

    This is the fourteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Using the initial CFD baseline modeling of the Gavin Station and the plant corrosion maps, six boiler locations for the corrosion probes were identified and access ports have been installed. Preliminary corrosion data obtained appear consistent and believable. In situ, spectroscopic experiments at BYU reported in part last quarter were completed. New reactor tubes have been made for BYU's CCR that allow for testing smaller amounts of catalyst and thus increasing space velocity; monolith catalysts have been cut and a small reactor that can accommodate these pieces for testing is in its final stages of construction. A poisoning study on Ca-poisoned catalysts was begun this quarter. A possible site for a biomass co-firing test of the slipstream reactor was visited this quarter. The slipstream reactor at Rockport required repair and refurbishment, and will be re-started in the next quarter. This report describes the final results of an experimental project at Brown University on the fundamentals of ammonia / fly ash interactions with relevance to the operation of advanced NOx control technologies such as selective catalytic reduction. The Brown task focused on the measurement of ammonia adsorption isotherms on commercial fly ash samples subjected to a variety of treatments and on the chemistry of dry and semi-dry ammonia removal processes.

  5. Coal-fired open cycle magnetohydrodynamic power plant emissions and energy efficiences

    E-Print Network [OSTI]

    Gruhl, Jim

    This study is a review of projected emissions and energy efficiencies of coal-fired open cycle MHD power plants. Ideally one

  6. LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; MILIAN, L.; LIPFERT, F.; SUBRAMANIAM, S.; BLAKE, R.

    2005-09-21T23:59:59.000Z

    Mercury is a neurotoxin that accumulates in the food chain and is therefore a health concern. The primary human exposure pathway is through fish consumption. Coal-fired power plants emit mercury and there is uncertainty over whether this creates localized hot spots of mercury leading to substantially higher levels of mercury in water bodies and therefore higher exposure. To obtain direct evidence of local deposition patterns, soil and vegetations samples from around three U.S. coal-fired power plants were collected and analyzed for evidence of hot spots and for correlation with model predictions of deposition. At all three sites, there was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. It was estimated that less than 2% of the total mercury emissions from these plants deposited within 15 km of these plants. These small percentages of deposition are consistent with the literature review findings of only minor perturbations in environmental levels, as opposed to hot spots, near the plants. The major objective of the sampling studies was to determine if there was evidence for hot spots of mercury deposition around coal-fired power plants. From a public health perspective, such a hot spot must be large enough to insure that it did not occur by chance, and it must increase mercury concentrations to a level in which health effects are a concern in a water body large enough to support a population of subsistence fishers. The results of this study suggest that neither of these conditions has been met.

  7. Coal-fired high performance power generating system. Final report

    SciTech Connect (OSTI)

    NONE

    1995-08-31T23:59:59.000Z

    As a result of the investigations carried out during Phase 1 of the Engineering Development of Coal-Fired High-Performance Power Generation Systems (Combustion 2000), the UTRC-led Combustion 2000 Team is recommending the development of an advanced high performance power generation system (HIPPS) whose high efficiency and minimal pollutant emissions will enable the US to use its abundant coal resources to satisfy current and future demand for electric power. The high efficiency of the power plant, which is the key to minimizing the environmental impact of coal, can only be achieved using a modern gas turbine system. Minimization of emissions can be achieved by combustor design, and advanced air pollution control devices. The commercial plant design described herein is a combined cycle using either a frame-type gas turbine or an intercooled aeroderivative with clean air as the working fluid. The air is heated by a coal-fired high temperature advanced furnace (HITAF). The best performance from the cycle is achieved by using a modern aeroderivative gas turbine, such as the intercooled FT4000. A simplified schematic is shown. In the UTRC HIPPS, the conversion efficiency for the heavy frame gas turbine version will be 47.4% (HHV) compared to the approximately 35% that is achieved in conventional coal-fired plants. This cycle is based on a gas turbine operating at turbine inlet temperatures approaching 2,500 F. Using an aeroderivative type gas turbine, efficiencies of over 49% could be realized in advanced cycle configuration (Humid Air Turbine, or HAT). Performance of these power plants is given in a table.

  8. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W. (Winter Springs, FL)

    1990-01-01T23:59:59.000Z

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The systems include a primary combustion compartment coupled to an impact separator for removing molten slag from hot combustion gases. Quenching means are provided for solidifying the molten slag removed by the impact separator, and processing means are provided forming a slurry from the solidified slag for facilitating removal of the solidified slag from the system. The released hot combustion gases, substantially free of molten slag, are then ducted to a lean combustion compartment and then to an expander section of a gas turbine.

  9. Coal Fired Power Generation Market Forecast | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCityFundCo-benefits EvaluationCoal Fired

  10. Does proximity to coal-fired power plants influence fish tissue mercury?

    E-Print Network [OSTI]

    Does proximity to coal-fired power plants influence fish tissue mercury? Dana K. Sackett · D. Derek+Business Media, LLC 2010 Abstract Much of the mercury contamination in aquatic biota originates from coal of contaminated fish. In this study, we quantified the relative importance of proximity to coal-fired power plants

  11. Dating of coal fires in Xinjiang, north-west China Xiangmin Zhang,1

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Dating of coal fires in Xinjiang, north-west China Xiangmin Zhang,1 Salomon B. Kroonenberg2 and Cor, the Netherlands Introduction Coal fires are one of the most serious problems for the Chinese coal indus- try. The estimated annual loss of coal by fires in China ranges from about 10­20 million tonnes (Guan et al., 1998

  12. Operating Experience of a Coal Fired Fluidized Bed at Georgetown University 

    E-Print Network [OSTI]

    Lutes, I. G.; Gamble, R. L.

    1980-01-01T23:59:59.000Z

    of the heating and cooling plant with this new coal fired facility. Previously existing units at the University heating and cooling plant normally fire natural gas. The fluidized bed steam generating facility at Georgetown University is the only new coal fired...

  13. Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options

    E-Print Network [OSTI]

    Aickelin, Uwe

    Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options Xi Liang, Jia supercritical pulverized coal power plant in China, using a cash flow model with Monte-Carlo simulations Defense Council) O&M (Operating & Maintenance) PC Power Plant (Pulverized Coal Fired Power Plant) ROA

  14. Energy 42 (2012) 486-496 Thermoeconomic operation optimization of a coal-fired power plant

    E-Print Network [OSTI]

    Luh, Peter

    2012-01-01T23:59:59.000Z

    optimization of a coal-fired power plant Jie Xiong a, Haibo Zhao a.*, Chao Zhang a, Chuguang Zheng a, Peter B optimization on a 300 MW coal-fired power plant located in Yiyang (Hunan Province, China) is accomplished based, are succes- sively realized on the power plant. Both strategies aim to minimize the total annual cost ofthe

  15. Incorporating Undesirable Outputs into Malmquist TFP Index: Environmental Performance Growth of Chinese Coal-Fired Power Plants

    E-Print Network [OSTI]

    Yang, Hongliang; Pollitt, Michael G.

    potential remains with regards to the efficiency improvement and emissions control in Chinese coal-fired power plants....

  16. Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission

    E-Print Network [OSTI]

    Elliott, Emily M.

    Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls from coal-fired power plants in the U.S. at typical operating conditions with and without the presence this, a novel method for collection and isotopic analysis of coal-fired stack NOx emission samples

  17. Accumulation of trace elements and growth responses in Corbicula fluminea downstream of a coal-fired power plant

    E-Print Network [OSTI]

    Hopkins, William A.

    2009 Keywords: Corbicula fluminea Coal-fired power plant Selenium Mercury Glutathione Condition index Bioaccumulation a b s t r a c t Lentic organisms exposed to coal-fired power plant (CFPP) discharges can have, 1993, 1997, 2002; Rowe et al., 2002). For example, coal-fired power plant (CFPP) discharges have been

  18. Size distribution of fine Particles in Stack emissions of a 600-MWe coal-fired Power Plant

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Size distribution of fine Particles in Stack emissions of a 600-MWe coal-fired Power Plant I coal-fired power plant. Aknowledgements: French environment agency ADEME (Contract number 04-74-C0018 that was carried out in March 2006 at a 600-MWe coal-fired power plant. 51 ineris-00973267,version1-4Apr2014 Author

  19. LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; LIPFERT, D.D.; MORRIS, S.M.; BANDO, A.; ET AL.

    2004-03-30T23:59:59.000Z

    A thorough quantitative understanding of the processes of mercury emissions, deposition, and translocation through the food chain is currently not available. Complex atmospheric chemistry and dispersion models are required to predict concentration and deposition contributions, and aquatic process models are required to predict effects on fish. There are uncertainties in all of these predictions. Therefore, the most reliable method of understanding impacts of coal-fired power plants on Hg deposition is from empirical data. A review of the literature on mercury deposition around sources including coal-fired power plants found studies covering local mercury concentrations in soil, vegetation, and animals (fish and cows (Lopez et al. 2003)). There is strong evidence of enhanced local deposition within 3 km of the chlor-alkali plants, with elevated soil concentrations and estimated deposition rates of 10 times background. For coal-fired power plants, the data show that atmospheric deposition of Hg may be slightly enhanced. On the scale of a few km, modeling suggests that wet deposition may be increased by a factor of two or three over background. The measured data suggest lower increases of 15% or less. The effects of coal-fired plants seem to be less than 10% of total deposition on a national scale, based on emissions and global modeling. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (1) local soil concentration Hg increments of 30%-60%, (2) sediment increments of 18-30%, (3) wet deposition increments of 11-12%, and (4) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg(0) in power plant plumes and the role of water chemistry in the relationship between Hg deposition and fish content. Soil and vegetation sampling programs were performed around two mid-size coal fired power plants. The objectives were to determine if local mercury hot spots exist, to determine if they could be attributed to deposition of coal-fired power plant emissions, and to determine if they correlated with model predictions. These programs found the following: (1) At both sites, there was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. At the Kincaid plant, there was excess soil Hg along heavily traveled roads. The spatial pattern of soil mercury concentrations did not match the pattern of vegetation Hg concentrations at either plant. (2) At both sites, the subsurface (5-10 cm) samples the Hg concentration correlated strongly with the surface samples (0-5 cm). Average subsurface sample concentrations were slightly less than the surface samples, however, the difference was not statistically significant. (3) An unequivocal definition of background Hg was not possible at either site. Using various assumed background soil mercury concentrations, the percentage of mercury deposited within 10 km of the plant ranged between 1.4 and 8.5% of the RGM emissions. Based on computer modeling, Hg deposition was primarily RGM with much lower deposition from elemental mercury. Estimates of the percentage of total Hg deposition ranged between 0.3 and 1.7%. These small percentages of deposition are consistent with the empirical findings of only minor perturbations in environmental levels, as opposed to ''hot spots'', near the plants. The major objective of this study was to determine if there was evidence for ''hot spots'' of mercury deposition around coal-fired power plants. Although the term has been used extensively, it has never been defined. From a public health perspective, such a ''hot spot'' must be large enough to insure that it did not occur by chance, and it must affect water bodies large enough to support a population of subsistence fishers. The results of this study support the hypothesis

  20. Repowering a small coal-fired power plant

    SciTech Connect (OSTI)

    Miell, R.

    2007-11-15T23:59:59.000Z

    The Arkansas River Power Authority (ARPA) Lamar Repowering Project is moving forward. The new generator, capable of producing 18 MW of electricity, is scheduled to be online in June 2008 bringing the total generation to 43 MW. New coal handling equipment, with infrared fire detectors, is almost complete. The new 18 MW steam turbine will be cooled by an air-cooled condenser. Coal will be delivered in a railroad spur to an unloading site then be unloaded onto a conveyor under the tracks and conveyed to two storage domes each holding 6000 tons of coal. It will be drawn out of these through an underground conveyor system, brought into a crusher, conveyed through overhead conveyors and fed into the new coal- fired fluidized bed boilers. 1 photo.

  1. Mercury control for coal-fired power plants

    SciTech Connect (OSTI)

    Haase, P.

    2005-06-30T23:59:59.000Z

    On 15 March 2005 the US Environmental Protection Agency issued its Clean Air Mercury Rule (CAMP) to regulate mercury emissions from coal-fired power plants. EPRI is working with the US Department of Energy and the power industry to develop mercury control technologies needed to meet the final 2018 emission limits. Some improvements can be made by modifying existing SO{sub 2} or NOx control devices. Precombustion cleaning reduces mercury content of eastern coals by about one third. Adding a little halogen is another technology being researched - this promotes oxidation improving short-term mercury capture. EPRI is developing the TOXECON{trademark} technology to address a major problem of using sorbents to control mercury emissions: contamination of fly ash. 5 figs.

  2. Impacts of TMDLs on coal-fired power plants.

    SciTech Connect (OSTI)

    Veil, J. A.; Environmental Science Division

    2010-04-30T23:59:59.000Z

    The Clean Water Act (CWA) includes as one of its goals restoration and maintenance of the chemical, physical, and biological integrity of the Nation's waters. The CWA established various programs to accomplish that goal. Among the programs is a requirement for states to establish water quality standards that will allow protection of the designated uses assigned to each water body. Once those standards are set, state agencies must sample the water bodies to determine if water quality requirements are being met. For those water bodies that are not achieving the desired water quality, the state agencies are expected to develop total maximum daily loads (TMDLs) that outline the maximum amount of each pollutant that can be discharged to the water body and still maintain acceptable water quality. The total load is then allocated to the existing point and nonpoint sources, with some allocation held in reserve as a margin of safety. Many states have already developed and implemented TMDLs for individual water bodies or regional areas. New and revised TMDLs are anticipated, however, as federal and state regulators continue their examination of water quality across the United States and the need for new or revised standards. This report was funded by the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) Existing Plants Research Program, which has an energy-water research effort that focuses on water use at power plants. This study complements its overall research effort by evaluating water issues that could impact power plants. One of the program missions of the DOE's NETL is to develop innovative environmental control technologies that will enable full use of the Nation's vast coal reserves, while at the same time allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. Some of the parameters for which TMDLs are being developed are components in discharges from coal-fired power plants. If a state establishes a new or revised TMDL for one of these pollutants in a water body where a power plant is located, the next renewal of the power plant's National Pollution Discharge Elimination System (NPDES) permit is likely to include more restrictive limits. Power generators may need to modify existing operational and wastewater treatment technologies or employ new ones as TMDLs are revised or new ones are established. The extent to which coal-fired power plants may be impacted by revised and new TMDL development has not been well established. NETL asked Argonne to evaluate how current and potential future TMDLs might influence coal-fired power plant operations and discharges. This information can be used to inform future technology research funded by NETL. The scope of investigation was limited to several eastern U.S. river basins rather than providing a detailed national perspective.

  3. Coal-fired boiler costs for industrial applications

    SciTech Connect (OSTI)

    Kurzius, S.C.; Barnes, R.W.

    1982-04-01T23:59:59.000Z

    Several of the current sources of information provide data on coal-fired steam boiler costs. As published, these data give widely varying and possibly inconsistent conclusions. This study was undertaken to determine the extent to which the differences in the various sets of published data bases could be resolved and, if possible, to arrive at more reliable cost correlations to be used in Oak Ridge Energy Demand Models. Our principal finding is that it is indeed possible to restate the costs within each data base on a more consistent basis. When this is done, reasonable engineering correlations of all the cost data versus steam plant capacity can be made over the 10,000 to 5000,000 lb/hr range.

  4. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W. (Winter Springs, FL)

    1990-01-01T23:59:59.000Z

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The gas turbine system includes a primary zone for burning coal in the presence of compressed air to produce hot combustion gases and debris, such as molten slag. The turbine system further includes a secondary combustion zone for the lean combustion of the hot combustion gases. The operation of the system is improved by the addition of a cyclone separator for removing debris from the hot combustion gases. The cyclone separator is disposed between the primary and secondary combustion zones and is in pressurized communication with these zones. In a novel aspect of the invention, the cyclone separator includes an integrally disposed impact separator for at least separating a portion of the molten slag from the hot combustion gases.

  5. COAL-FIRED UTILITY BOILERS: SOLVING ASH DEPOSITION PROBLEMS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Steven A. Benson; Jay R. Gunderson

    2001-04-01T23:59:59.000Z

    The accumulation of slagging and fouling ash deposits in utility boilers has been a source of aggravation for coal-fired boiler operators for over a century. Many new developments in analytical, modeling, and combustion testing methods in the past 20 years have made it possible to identify root causes of ash deposition. A concise and comprehensive guidelines document has been assembled for solving ash deposition as related to coal-fired utility boilers. While this report accurately captures the current state of knowledge in ash deposition, note that substantial research and development is under way to more completely understand and mitigate slagging and fouling. Thus, while comprehensive, this document carries the title ''interim,'' with the idea that future work will provide additional insight. Primary target audiences include utility operators and engineers who face plant inefficiencies and significant operational and maintenance costs that are associated with ash deposition problems. Pulverized and cyclone-fired coal boilers are addressed specifically, although many of the diagnostics and solutions apply to other boiler types. Logic diagrams, ash deposit types, and boiler symptoms of ash deposition are used to aid the user in identifying an ash deposition problem, diagnosing and verifying root causes, determining remedial measures to alleviate or eliminate the problem, and then monitoring the situation to verify that the problem has been solved. In addition to a step-by-step method for identifying and remediating ash deposition problems, this guideline document (Appendix A) provides descriptions of analytical techniques for diagnostic testing and gives extensive fundamental and practical literature references and addresses of organizations that can provide help in alleviating ash deposition problems.

  6. Corrosion probes for fireside monitoring in coal-fired boilers

    SciTech Connect (OSTI)

    Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, M.; Holcomb, Gordon R.

    2005-01-01T23:59:59.000Z

    Corrosion probes are being developed and combined with an existing measurement technology to provide a tool for assessing the extent of corrosion of metallic materials on the fireside in coal-fired boilers. The successful development of this technology will provide power plant operators the ability to (1) accurately monitor metal loss in critical regions of the boiler, such as waterwalls, superheaters, and reheaters; and (2) use corrosion rates as process variables. In the former, corrosion data could be used to schedule maintenance periods and in the later, processes can be altered to decrease corrosion rates. The research approach involves laboratory research in simulated environments that will lead to field tests of corrosion probes in coal-fired boilers. Laboratory research has already shown that electrochemically-measured corrosion rates for ash-covered metals are similar to actual mass loss corrosion rates. Electrochemical tests conducted using a potentiostat show the corrosion reaction of ash-covered probes at 500?C to be electrochemical in nature. Corrosion rates measured are similar to those from an automated corrosion monitoring system. Tests of corrosion probes made with mild steel, 304L stainless steel (SS), and 316L SS sensors showed that corrosion of the sensors in a very aggressive incinerator ash was controlled by the ash and not by the alloy content. Corrosion rates in nitrogen atmospheres tended to decrease slowly with time. The addition of oxygen-containing gases, oxygen and carbon dioxide to nitrogen caused a more rapid decrease in corrosion rate, while the addition of water vapor increased the corrosion rate.

  7. Coal-fired furnace for testing of thermionic converters. Topical report

    SciTech Connect (OSTI)

    Not Available

    1980-10-01T23:59:59.000Z

    The development of thermionic converter technology has progressed to make near-term applications interesting. One of these applications is the thermionic topping of a pulverized coal-fired central station powerplant. Up to now, thermionic converters have been flame tested using natural gas as fuel. A new test furnace is required for evaluation of thermionic converters in a coal-fired environment. The design and costs of a facility which adapts a coal-fired furnace built by Foster Wheeler Development Corporation (FWDC) for thermionic converter testing are discussed. Such a facility would be exempt from air pollution regulations because of its low firing rate.

  8. MHD coal-fired flow facility. Annual technical progress report, October 1979-September 1980

    SciTech Connect (OSTI)

    Alstatt, M.C.; Attig, R.C.; Brosnan, D.A.

    1981-03-01T23:59:59.000Z

    The University of Tennessee Space Institute (UTSI) reports on significant activity, task status, planned research, testing, development, and conclusions for the Magnetohydrodynamics (MHD) Coal-Fired Flow Faclity (CFFF) and the Energy Conversion Facility (ECF).

  9. Carbon dioxide capture from coal-fired power plants : a real potions analysis

    E-Print Network [OSTI]

    Sekar, Ram Chandra

    2005-01-01T23:59:59.000Z

    Investments in three coal-fired power generation technologies are valued using the "real options" valuation methodology in an uncertain carbon dioxide (CO2) price environment. The technologies evaluated are pulverized coal ...

  10. EA-1183: Coal-fired Diesel Generator University of Alaska, Fairbanks, Alaska

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to provide funds to support the construction and operation of a coal-fired diesel generator at the University of Alaska, Fairbanks.

  11. Large Field Erected and Packaged High Temperature Water (HTW) Generators for Coal Firing

    E-Print Network [OSTI]

    Boushell, C. C.

    1980-01-01T23:59:59.000Z

    The purpose of the paper is to disseminate information on the energy savings possible with High Temperature Water (HTW) for heating and industrial process application and to provide information on coal fired HTW generator design and availability....

  12. Water vulnerabilities for existing coal-fired power plants.

    SciTech Connect (OSTI)

    Elcock, D.; Kuiper, J.; Environmental Science Division

    2010-08-19T23:59:59.000Z

    This report was funded by the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) Existing Plants Research Program, which has an energy-water research effort that focuses on water use at power plants. This study complements the Existing Plants Research Program's overall research effort by evaluating water issues that could impact power plants. Water consumption by all users in the United States over the 2005-2030 time period is projected to increase by about 7% (from about 108 billion gallons per day [bgd] to about 115 bgd) (Elcock 2010). By contrast, water consumption by coal-fired power plants over this period is projected to increase by about 21% (from about 2.4 to about 2.9 bgd) (NETL 2009b). The high projected demand for water by power plants, which is expected to increase even further as carbon-capture equipment is installed, combined with decreasing freshwater supplies in many areas, suggests that certain coal-fired plants may be particularly vulnerable to potential water demand-supply conflicts. If not addressed, these conflicts could limit power generation and lead to power disruptions or increased consumer costs. The identification of existing coal-fired plants that are vulnerable to water demand and supply concerns, along with an analysis of information about their cooling systems and related characteristics, provides information to help focus future research and development (R&D) efforts to help ensure that coal-fired generation demands are met in a cost-effective manner that supports sustainable water use. This study identified coal-fired power plants that are considered vulnerable to water demand and supply issues by using a geographical information system (GIS) that facilitated the analysis of plant-specific data for more than 500 plants in the NETL's Coal Power Plant Database (CPPDB) (NETL 2007a) simultaneously with 18 indicators of water demand and supply. Two types of demand indicators were evaluated. The first type consisted of geographical areas where specific conditions can generate demand vulnerabilities. These conditions include high projected future water consumption by thermoelectric power plants, high projected future water consumption by all users, high rates of water withdrawal per square mile (mi{sup 2}), high projected population increases, and areas projected to be in a water crisis or conflict by 2025. The second type of demand indicator was plant specific. These indicators were developed for each plant and include annual water consumption and withdrawal rates and intensities, net annual power generation, and carbon dioxide (CO{sub 2}) emissions. The supply indictors, which are also area based, include areas with low precipitation, high temperatures, low streamflow, and drought. The indicator data, which were in various formats (e.g., maps, tables, raw numbers) were converted to a GIS format and stored, along with the individual plant data from the CPPDB, in a single GIS database. The GIS database allowed the indicator data and plant data to be analyzed and visualized in any combination. To determine the extent to which a plant would be considered 'vulnerable' to a given demand or supply concern (i.e., that the plant's operations could be affected by water shortages represented by a potential demand or supply indicator), criteria were developed to categorize vulnerability according to one of three types: major, moderate, or not vulnerable. Plants with at least two major demand indicator values and/or at least four moderate demand indicator values were considered vulnerable to demand concerns. By using this approach, 144 plants were identified as being subject to demand concerns only. Plants with at least one major supply indicator value and/or at least two moderate supply indicator values were considered vulnerable to supply concerns. By using this approach, 64 plants were identified as being subject to supply concerns only. In addition, 139 plants were identified as subject to both demand and supply concerns. Therefore, a total of 347 plants were considere

  13. Water Extraction from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

    2006-06-30T23:59:59.000Z

    The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

  14. Advanced Systems for Preprocessing and Characterizing Coal-Biomass Mixtures as Next-Generation Fuels and Feedstocks

    SciTech Connect (OSTI)

    Karmis, Michael; Luttrell, Gerald; Ripepi, Nino; Bratton, Robert; Dohm, Erich

    2014-06-30T23:59:59.000Z

    The research activities presented in this report are intended to address the most critical technical challenges pertaining to coal-biomass briquette feedstocks. Several detailed investigations were conducted using a variety of coal and biomass feedstocks on the topics of (1) coal-biomass briquette production and characterization, (2) gasification of coal-biomass mixtures and briquettes, (3) combustion of coal-biomass mixtures and briquettes, and (4) conceptual engineering design and economic feasibility of briquette production. The briquette production studies indicate that strong and durable co-firing feedstocks can be produced by co-briquetting coal and biomass resources commonly available in the United States. It is demonstrated that binderless coal-biomass briquettes produced at optimized conditions exhibit very high strength and durability, which indicates that such briquettes would remain competent in the presence of forces encountered in handling, storage and transportation. The gasification studies conducted demonstrate that coal-biomass mixtures and briquettes are exceptional gasification feedstocks, particularly with regard to the synergistic effects realized during devolatilization of the blended materials. The mixture combustion studies indicate that coal-biomass mixtures are exceptional combustion feedstocks, while the briquette combustion study indicates that the use of blended briquettes reduces NO{sub x}, CO{sub 2}, and CO emissions, and requires the least amount of changes in the operating conditions of an existing coal-fired power plant. Similar results were obtained for the physical durability of the pilot-scale briquettes compared to the bench-scale tests. Finally, the conceptual engineering and feasibility analysis study for a commercial-scale briquetting production facility provides preliminary flowsheet and cost simulations to evaluate the various feedstocks, equipment selection and operating parameters.

  15. Cornell's conversion of a coal fired heating plant to natural Gas -BACKGROUND: In December 2009, the Combined Heat and Power Plant

    E-Print Network [OSTI]

    Keinan, Alon

    Cornell's conversion of a coal fired heating plant to natural Gas University began operating with natural gas, instead of the coal-fired generators of the coal that had been stockpiled, the Plant is running completely on natural gas

  16. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    of Toxic Emissions from Coal-Fired Power Plants: Phase Ito restrict SO 2 emissions from coal-burning power plants (Coal-fired Power Plant (after Weber et al. , 1996) .42 Hazardous Organic Compounds in Combined Stack Emissions

  17. Historical Costs of Coal-Fired Electricity and Implications for the Future James McNerney,a,b

    E-Print Network [OSTI]

    Historical Costs of Coal-Fired Electricity and Implications for the Future James Mc, Cambridge, MA 02139-4307, USA Abstract We study the costs of coal-fired electricity in the United States between 1882 and 2006 by decomposing it in terms of the price of coal, transportation costs, energy

  18. PRODUCTION OF NEW BIOMASS/WASTE-CONTAINING SOLID FUELS

    SciTech Connect (OSTI)

    David J. Akers; Glenn A. Shirey; Zalman Zitron; Charles Q. Maney

    2001-04-20T23:59:59.000Z

    CQ Inc. and its team members (ALSTOM Power Inc., Bliss Industries, McFadden Machine Company, and industry advisors from coal-burning utilities, equipment manufacturers, and the pellet fuels industry) addressed the objectives of the Department of Energy and industry to produce economical, new solid fuels from coal, biomass, and waste materials that reduce emissions from coal-fired boilers. This project builds on the team's commercial experience in composite fuels for energy production. The electric utility industry is interested in the use of biomass and wastes as fuel to reduce both emissions and fuel costs. In addition to these benefits, utilities also recognize the business advantage of consuming the waste byproducts of customers both to retain customers and to improve the public image of the industry. Unfortunately, biomass and waste byproducts can be troublesome fuels because of low bulk density, high moisture content, variable composition, handling and feeding problems, and inadequate information about combustion and emissions characteristics. Current methods of co-firing biomass and wastes either use a separate fuel receiving, storage, and boiler feed system, or mass burn the biomass by simply mixing it with coal on the storage pile. For biomass or biomass-containing composite fuels to be extensively used in the U.S., especially in the steam market, a lower cost method of producing these fuels must be developed that includes both moisture reduction and pelletization or agglomeration for necessary fuel density and ease of handling. Further, this method of fuel production must be applicable to a variety of combinations of biomass, wastes, and coal; economically competitive with current fuels; and provide environmental benefits compared with coal. Notable accomplishments from the work performed in Phase I of this project include the development of three standard fuel formulations from mixtures of coal fines, biomass, and waste materials that can be used in existing boilers, evaluation of these composite fuels to determine their applicability to the major combustor types, development of preliminary designs and economic projections for commercial facilities producing up to 200,000 tons per year of biomass/waste-containing fuels, and the development of dewatering technologies to reduce the moisture content of high-moisture biomass and waste materials during the pelletization process.

  19. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Suuberg; Eric Eddings; Larry Baxter

    2002-01-31T23:59:59.000Z

    This is the sixth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. This program contains multiple tasks and good progress is being made on all fronts. Preliminary results from laboratory and field tests of a corrosion probe to predict waterwall wastage indicate good agreement between the electrochemical noise corrosion rates predicted by the probe and corrosion rates measured by a surface profilometer. Four commercial manufacturers agreed to provide catalyst samples to the program. BYU has prepared two V/Ti oxide catalysts (custom, powder form) containing commercially relevant concentrations of V oxide and one containing a W oxide promoter. Two pieces of experimental apparatus being built at BYU to carry out laboratory-scale investigations of SCR catalyst deactivation are nearly completed. A decision was made to carry out the testing at full-scale power plants using a slipstream of gas instead of at the University of Utah pilot-scale coal combustor as originally planned. Design of the multi-catalyst slipstream reactor was completed during this quarter. One utility has expressed interest in hosting a long-term test at one of their plants that co-fire wood with coal. Tests to study ammonia adsorption onto fly ash have clearly established that the only routes that can play a role in binding significant amounts of ammonia to the ash surface, under practical ammonia slip conditions, are those that must involve co-adsorbates.

  20. Evaluation of air toxic emissions from advanced and conventional coal-fired power plants

    SciTech Connect (OSTI)

    Chu, P.; Epstein, M. [Electric Power Research Institute, Palo Alto, CA (United States); Gould, L. [Department of Energy, Pittsburgh, PA (United States); Botros, P. [Department of Energy, Morgantown, WV (United States)

    1995-12-31T23:59:59.000Z

    This paper evaluates the air toxics measurements at three advanced power systems and a base case conventional fossil fuel power plant. The four plants tested include a pressurized fluidized bed combustor, integrated gasification combined cycle, circulating fluidized bed combustor, and a conventional coal-fired plant.

  1. DETECTION OF EVENTS CAUSING PLUGGAGE OF A COAL-FIRED BOILER: A DATA MINING

    E-Print Network [OSTI]

    Kusiak, Andrew

    DETECTION OF EVENTS CAUSING PLUGGAGE OF A COAL-FIRED BOILER: A DATA MINING APPROACH ANDREW KUSIAK partitioning, parameter reduction, and data mining. Two inde- pendent data mining algorithms have been applied to detect both static and dynamic relationships among the process parameters. The multi-angle data mining

  2. Operating Experience of a Coal Fired Fluidized Bed at Georgetown University

    E-Print Network [OSTI]

    Lutes, I. G.; Gamble, R. L.

    1980-01-01T23:59:59.000Z

    Operation of the 100,000 lb/hr capacity, coal fired fluidized bed steam generator at Georgetown University began in July 1979. This project, which was co-funded by Georgetown University and the U. S. Department of Energy, involved expansion...

  3. Biomass energy with carbon capture and storage (BECCS): a review

    E-Print Network [OSTI]

    Matthews, Adrian

    can be reconciled with competing uses of land (and water) are both uncertain. While biomass co-firing with coal offers an early route to BECCS, a quite substantial (>20%) biomass component may be necessary to achieve negative emissions in a co-fired BECCS system (a percentage that is dependent, of course

  4. Experimental and numerical analysis of isothermal turbulent flows in interacting low NOx burners in coal-fired furnaces 

    E-Print Network [OSTI]

    Cvoro, Valentina

    Coal firing power stations represent the second largest source of global NOx emissions. The current practice of predicting likely exit NOx levels from multi-burner furnaces on the basis of single burner test rig data has been proven inadequate...

  5. Integration and operation of post-combustion capture system on coal-fired power generation: load following and peak power

    E-Print Network [OSTI]

    Brasington, Robert David, S.M. Massachusetts Institute of Technology

    2012-01-01T23:59:59.000Z

    Coal-fired power plants with post combustion capture and sequestration (CCS) systems have a variety of challenges to integrate the steam generation, air quality control, cooling water systems and steam turbine with the ...

  6. Coal-Fired Power Plants, Greenhouse Gases, and State Statutory Substantial Endangerment Provisions: Climate Change Comes to Kansas

    E-Print Network [OSTI]

    Glicksman, Robert L.

    2008-04-01T23:59:59.000Z

    economy standards on motor vehicles by states such as California. But the states have also targeted stationary sources of greenhouse gases. In particular, they have sought to minimize carbon dioxide emissions from coal-fired power plants. States have used...

  7. New 90,000 PPH Coal Fired Boiler Plant at Liggett & Myers Tobacco Company, Durham North Carolina

    E-Print Network [OSTI]

    Kaskey, G. T.

    1984-01-01T23:59:59.000Z

    Liggett & Myers Tobacco Company in Durham, North Carolina is installing a future cogeneration, coal fired boiler system designed and built by Energy Systems (ESI) of Chattanooga, Tennessee. The complete boiler plant is comprised of a 90,000 pph Dorr...

  8. Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants 

    E-Print Network [OSTI]

    Schwartz, M. H.

    1979-01-01T23:59:59.000Z

    pulverized coal-fired boiler equipment. These are: (1) coal cleaning to remove pyritic sulfur, (2) conventional wet, nonregenerable scrubbing with alkaline slurry and solution processes, and (3) dry processes which involve direct introduction of lime...

  9. European legislation in the United Kingdom: a threat to coal-fired power station product utilization?

    SciTech Connect (OSTI)

    Sear, K.A. [Quality Ash Association (United Kingdom)

    2006-07-01T23:59:59.000Z

    The author considers that the European Union has not taken the approach adopted in the USA where environmental regulators are keen to promote the use of coal-fired power station ash by-product and recycled materials. The United Kingdom has seen, with some dismay, the effects EU legislation is having on the ash industry. This article outlines only some of the problems being tackled. The Waste Framework Directive is difficult to interpret and fails to define critical aspects of the problem. This directive is discussed at some length in the article. A total of nine directives effect the operation of coal-fired power plant. Many are imprecise and open to interpretation and cause a deal of frustration, delays and confusion to the ash supplier and contractor. This is causing markets to suffer.

  10. Potential of hybrid geothermal/coal fired power plants in Arizona

    SciTech Connect (OSTI)

    White, D.H.; Goldstone, L.A.

    1982-08-01T23:59:59.000Z

    The City of Burbank and the Ralph M. Parsons Company studies showed several advantages for hybrid geothermal/coal fired power plants, as follows: (1) the estimated cost of producing electricity in hybrid plant is about 18.3 mills/kWh, compared to 19.3 mills/kWh in an all-coal fired power plant; (2) the coal requirements for a given plant can be reduced about 12 to 17%; and (3) the geothermal brines can be used for power plant cooling water, and in some cases, as boiler feedwater. The pertinent results of the City of Burbank studies are summarized and applied to the geothermal and coal resources of Arizona for possible future utilization.

  11. Aerosol dispersion and coagulation from a coal-fired power plant: a three dimensional numerical model

    SciTech Connect (OSTI)

    Buckholtz, H.T.; Biermann, A.H.

    1980-01-01T23:59:59.000Z

    A computational model to simulate the dispersion and coagulation of aerosols emitted from coal-fired power plants was constructed. In modeling the dispersion of the aerosol, turbulent diffusion and wind-driven advection are treated by a finite-difference method. Molecular coagulation is incorporated in the model to follow shifts in the particle-size distribution. Particulate coagulation is mathematically described by Timiskii's equation. The relevent semi-empirical work of Smirnov is incorporated in the model to provide for the coagultion constant. Input for the model is a bimodal, particle-size distribution measured at an operating coal-fired power plant. Simulations indicate that dispersion competes against coagulation mechanisms to maintain the bimodal shaped distribution for 32 km. Turbulence and particle settling tend to enchance coagulation effects. The size-dependent spatial segregation of particles within the plume is predicted.

  12. Summary report: Trace substance emissions from a coal-fired gasification plant

    SciTech Connect (OSTI)

    Williams, A.; Wetherold, B.; Maxwell, D.

    1996-10-16T23:59:59.000Z

    The U.S. Department of Energy (DOE), the Electric Power Research Institute (EPRI), and Louisiana Gasification Technology Inc. (LGTI) sponsored field sampling and analyses to characterize emissions of trace substances from LGTI`s integrated gasification combined cycle (IGCC) power plant at Plaquemine, Louisiana. The results indicate that emissions from the LGTI facility were quite low, often in the ppb levels, and comparable to a well-controlled pulverized coal-fired power plant.

  13. Flue Gas Conditioning to Reduce Particulate Emissions in Industrial Coal-Fired Boilers

    E-Print Network [OSTI]

    Miller, B.; Keon, E.

    1980-01-01T23:59:59.000Z

    FLUE GAS CONDITIONING TO REDUCE PARTICULATE EMISSIONS IN INDUSTRIAL COAL-FIRED BOILERS Barry Miller and Ed Keon Apollo Technologies, Inc. Whippany, New Jersey ABSTRACT Chemical technology has been used successfully to solve many... inspection of the ESP, careful observation of ESP controls to determine spark rate and voltage drop during sparking, in-situ resistivity mea surements, rapper on-off observations, and a re view of records to investigate the relationship of boiler...

  14. Measurements of POM emissions from coal-fired utility boilers. Final report

    SciTech Connect (OSTI)

    Sonnichsen, T.W.

    1983-02-01T23:59:59.000Z

    Emissions of polycyclic organic matter (POM) from fossil-fuel combustion systems are of concern due to the potential carcinogenic activity of specific POM species. The initial objectives of this research program were to (1) conduct a limited laboratory verification of state-of-the-art POM sampling and analysis techniques for pulverized coal-fired combustion exhausts and (2) measure the POM emissions of up to four coal-fired utility boilers. Initial laboratory tests, involving the injection of synthetic POM tracers into the sampling and analytical procedures were capable of accurate POM measurements. However, subsequent tracer recovery results and measurements of combustion generated POM from a coal-fired laboratory test furnace and a utility boiler were highly erratic. The program was consequently redirected to include a comprehensive evaluation of the analytical techniques and interfering factors in the flue gas or sampling train that may have impacted the POM measurements. State-of-the-art GC/MS analytical technical techniques were shown to be generally adequate, but some questions remain concerning sample preparation and adaptability for routine measurements. Review of the literature identified the potential for interaction of POM with the fly ash in either the flue-gas stream or the sampling system. The results of these evaluations were incorporated into a final field-test program on a coal-fired utility boiler. While some improvement in tracer recoveries and combustion-generated POM were obtained, several inconsistencies in the data were still apparent. Recommendations for future POM-measurement programs on utility boilers are presented.

  15. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    favors IGCC technology over existing power plant designs (technologies either retrofitted to existing power plants, ortechnologies that could either be retrofitted to existing coal-fired power plants,

  16. A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

    E-Print Network [OSTI]

    Pei, Y J; Dong, X; Feng, G Y; Fu, S; Gao, H; Hong, Y; Li, G; Li, Y X; Shang, L; Sheng, L S; Tian, Y C; Wang, X Q; Wang, Y; Wei, W; Zhang, Y W; Zhou, H J

    2001-01-01T23:59:59.000Z

    A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

  17. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    from combustion and gasification of coal – an equilibriumHolysh, M. 2005. Coke Gasification: Advanced technology forfrom a Coal-Fired Gasification Plant. Final Report, December

  18. LOCAL IMPACTS OF MERCURY EMISSIONS FROM THE MONTICELLO COAL FIRED POWER PLANT.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; ADAMS, J.; MILIAN, L.; SUBRAMANIAN, S.; FEAGIN, L.; WILLIAMS, J.; BOYD, A.

    2006-10-31T23:59:59.000Z

    The Clean Air Interstate Rule (CAIR) and the Clean Air Mercury Rule (CAMR) as currently proposed by the U.S. Environmental Protection Agency (EPA) when fully implemented will lead to reduction in mercury emissions from coal-fired power plants by 70 percent to fifteen tons per year by 2018. The EPA estimates that mercury deposition would be reduced 8 percent on average in the Eastern United States. The CAMR permits cap-and-trade approach that requires the nationwide emissions to meet the prescribed level, but do not require controls on each individual power plant. This has led to concerns that there may be hot-spots of mercury contamination near power plants. Partially because of this concern, many states including Pennsylvania have implemented, or are considering, state regulations that are stricter on mercury emissions than those in the CAMR. This study examined the possibility that coal-fired power plants act as local sources leading to mercury ''hot spots'', using two types of evidence. First, the world-wide literature was searched for reports of deposition around mercury sources, including coal-fired power plants. Second, soil samples from around two mid-sized U.S. coal-fired power plants were collected and analyzed for evidence of ''hot spots'' and for correlation with model predictions of deposition. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (A) local soil concentration Hg increments of 30%-60%, (B) sediment increments of 18-30%, (C) wet deposition increments of 11-12%, and (D) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg(0) in power plant plumes and the role of water chemistry in the relationship between Hg deposition and fish content. Soil and vegetation sampling programs were performed around the Monticello coal fired power plant. The objectives were to determine if local mercury hot spots exist, to determine if they could be attributed to deposition of coal-fired power plant emissions, and to determine if they correlated with model predictions. The study found the following: (1) There was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. At the Monticello plant, excess soil Hg was associated with soil characteristics with higher values near the lake. Vegetation concentration showed some correlation with soil concentrations having higher mercury in vegetation when the soil mercury. (2) Based on computer modeling, Hg deposition was primarily RGM with much lower deposition from elemental mercury. The total deposition within 50 Km of the plant was predicted to be 4.2% of the total emitted. In the deposition, RGM is responsible for 98.7% of the total deposition, elemental mercury accounts for 1.1% and particulate mercury accounts for 0.2%. Less than 1% of the elemental mercury emitted was predicted to deposit within 50 km.

  19. Reducing water freshwater consumption at coal-fired power plants : approaches used outside the United States.

    SciTech Connect (OSTI)

    Elcock, D. (Environmental Science Division)

    2011-05-09T23:59:59.000Z

    Coal-fired power plants consume huge quantities of water, and in some water-stressed areas, power plants compete with other users for limited supplies. Extensive use of coal to generate electricity is projected to continue for many years. Faced with increasing power demands and questionable future supplies, industries and governments are seeking ways to reduce freshwater consumption at coal-fired power plants. As the United States investigates various freshwater savings approaches (e.g., the use of alternative water sources), other countries are also researching and implementing approaches to address similar - and in many cases, more challenging - water supply and demand issues. Information about these non-U.S. approaches can be used to help direct near- and mid-term water-consumption research and development (R&D) activities in the United States. This report summarizes the research, development, and deployment (RD&D) status of several approaches used for reducing freshwater consumption by coal-fired power plants in other countries, many of which could be applied, or applied more aggressively, at coal-fired power plants in the United States. Information contained in this report is derived from literature and Internet searches, in some cases supplemented by communication with the researchers, authors, or equipment providers. Because there are few technical, peer-reviewed articles on this topic, much of the information in this report comes from the trade press and other non-peer-reviewed references. Reducing freshwater consumption at coal-fired power plants can occur directly or indirectly. Direct approaches are aimed specifically at reducing water consumption, and they include dry cooling, dry bottom ash handling, low-water-consuming emissions-control technologies, water metering and monitoring, reclaiming water from in-plant operations (e.g., recovery of cooling tower water for boiler makeup water, reclaiming water from flue gas desulfurization [FGD] systems), and desalination. Some of the direct approaches, such as dry air cooling, desalination, and recovery of cooling tower water for boiler makeup water, are costly and are deployed primarily in countries with severe water shortages, such as China, Australia, and South Africa. Table 1 shows drivers and approaches for reducing freshwater consumption in several countries outside the United States. Indirect approaches reduce water consumption while meeting other objectives, such as improving plant efficiency. Plants with higher efficiencies use less energy to produce electricity, and because the greater the energy production, the greater the cooling water needs, increased efficiency will help reduce water consumption. Approaches for improving efficiency (and for indirectly reducing water consumption) include increasing the operating steam parameters (temperature and pressure); using more efficient coal-fired technologies such as cogeneration, IGCC, and direct firing of gas turbines with coal; replacing or retrofitting existing inefficient plants to make them more efficient; installing high-performance monitoring and process controls; and coal drying. The motivations for increasing power plant efficiency outside the United States (and indirectly reducing water consumption) include the following: (1) countries that agreed to reduce carbon emissions (by ratifying the Kyoto protocol) find that one of the most effective ways to do so is to improve plant efficiency; (2) countries that import fuel (e.g., Japan) need highly efficient plants to compensate for higher coal costs; (3) countries with particularly large and growing energy demands, such as China and India, need large, efficient plants; (4) countries with large supplies of low-rank coals, such as Germany, need efficient processes to use such low-energy coals. Some countries have policies that encourage or mandate reduced water consumption - either directly or indirectly. For example, the European Union encourages increased efficiency through its cogeneration directive, which requires member states to assess their

  20. Dose assessment for various coals in the coal-fired power plant

    SciTech Connect (OSTI)

    Antic, D.; Sokcic-Kostic, M. (Institute of Nuclear Sciences Vinca, Belgrade (Yugoslavia))

    1993-01-01T23:59:59.000Z

    The radiation exposure of the public in the vicinity of a coal-fired power plant has been studied. The experimental data on uranium, thorium, and potassium content in selected coals from Serbia and Bosnia have been used to calculate the release rates of natural radionuclides from the power plant. A generalized model for analysis of radiological impact of an energy source that includes the two-dimensional version of the cloud model simulates the transport of radionuclides released to the atmosphere. The inhalation dose rates are assessed for various meteorological conditions.

  1. Fuel supply system and method for coal-fired prime mover

    DOE Patents [OSTI]

    Smith, William C. (Morgantown, WV); Paulson, Leland E. (Morgantown, WV)

    1995-01-01T23:59:59.000Z

    A coal-fired gas turbine engine is provided with an on-site coal preparation and engine feeding arrangement. With this arrangement, relatively large dry particles of coal from an on-site coal supply are micro-pulverized and the resulting dry, micron-sized, coal particulates are conveyed by steam or air into the combustion chamber of the engine. Thermal energy introduced into the coal particulates during the micro-pulverizing step is substantially recovered since the so-heated coal particulates are fed directly from the micro-pulverizer into the combustion chamber.

  2. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Browers, Bruce; Srinivasachar, Srivats; Laudal, Daniel

    2014-12-31T23:59:59.000Z

    Under contract DE-FE0007603, the University of North Dakota conducted the project Evaluation of Carbon Dioxide Capture from Existing Coal Fired Plants by Hybrid Sorption Using Solid Sorbents. As an important element of this effort, a Technical and Economic Feasibility Study was conducted by Barr Engineering Co. (Barr) in association with the University of North Dakota. The assessment developed a process flow diagram, major equipment list, heat balances for the SCPC power plant, capital cost estimate, operating cost estimate, levelized cost of electricity, cost of CO2 capture ($/ton) and three sensitivity cases for the CACHYS™ process.

  3. Coal-fired power generation: Proven technologies and pollution control systems

    SciTech Connect (OSTI)

    Balat, M. [University of Mah, Trabzon (Turkey)

    2008-07-01T23:59:59.000Z

    During the last two decades, significant advances have been made in the reduction of emissions from coal-fired power generating plants. New technologies include better understanding of the fundamentals of the formation and destruction of criteria pollutants in combustion processes (low nitrogen oxides burners) and improved methods for separating criteria pollutants from stack gases (FGD technology), as well as efficiency improvements in power plants (clean coal technologies). Future demand for more environmentally benign electric power, however, will lead to even more stringent controls of pollutants (sulphur dioxide and nitrogen oxides) and greenhouse gases such as carbon dioxide.

  4. Research on fundamental aspects of inorganic vapor and particle deposition in coal-fired systems

    SciTech Connect (OSTI)

    Rosner, D.E.

    1992-03-01T23:59:59.000Z

    In September 1990 DOE-PETC initiated at the Yale HTCRE Laboratory a systematic three-year research program directed toward providing engineers with the fundamentally-based design/optimization tools'' foreconomically predicting the dynamics of net deposit growth, and thermophysical properties of the resulting microparticulate deposits in coal-fired systems. The goal of our research in the area of mineral mattertransport is to advance the capability of making reliable engineering predictions of the dynamics of net deposit growth for surfaces exposed to the particle-laden products of coal combustion. To accomplish thisfor a wide variety of combustor types, coal types, and operating conditions, this capability must be based on a quantitative understanding of each of the important mechanisms of mineral matter transport, as well as the nature of the interactions between these substances and the prevailing fireside'' surface of deposits. This level of understanding and predictive capability could be translated into very significant cost reductions for coal-fired equipment design, development and operation. It is also expected that this research activity will not only directly benefit the ash deposition R D community -- but also generically closely related technologies of importance to DOE (e.g. hot-gas clean-up, particulate solids handling,...).

  5. PFB coal fired combined cycle development program: commercial plant economic analysis (Task 1. 6)

    SciTech Connect (OSTI)

    Not Available

    1980-11-01T23:59:59.000Z

    The objectives of this program are to evaluate the Coal Fired Combined Cycle (CFCC) power plant conceptual design and to conduct supporting development programs for pressurized fluidized bed technology advancement in combustion/steam generator, gas turbine and hot gas cleanup technologies. The Coal-Fired Combined Cycle is the unique power plant concept developed under the leadership of the General Electric Company to provide a direct coal-burning gas turbine and steam turbine combined-cycle power plant. The advantages of the combined cycle for higher efficiency and the potential of the pressurized fluidized bed combustor improvements in emissions could offer a new and attractive option to the electric utility industry. The CFCC approach provides for cooling the fluid bed combustor through the use of steam tubes in the bed which supply a steam turbine generator. The partially cooled combustion gases drive a gas turbine generator after passing through a hot gas cleanup train. The Conceptual CFCC Commercial Plant has been defined in Report No. Fe-2357-28. This design, being conceptual in nature, has not been improved through the formal cost reduction iteration/design program. An economic analysis of this baseline plant is provided in this report. The General Electric Company believes that the combustion of coal by the pressurized fluidized bed process is one of the most effective and efficient means for the utilization of coal with respect to both environmental considerations and the cost of electricity.

  6. Coal-fired high performance power generating system. Quarterly progress report, January 1--March 31, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    This report covers work carried out under Task 2, Concept Definition and Analysis, and Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, ``Engineering Development of a Coal Fired High Performance Power Generation System`` between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of: > 47% thermal efficiency; NO{sub x}, SO{sub x} and Particulates {le} 25% NSPS; cost {ge} 65% of heat input; and all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW{sub e} combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (FHTAF) which integrates several combustor and air heater designs with appropriate ash management procedures. The cycle optimization effort has brought about several revisions to the system configuration resulting from: (1) the use of Illinois No. 6 coal instead of Utah Blind Canyon; (2) the use of coal rather than methane as a reburn fuel; (3) reducing radiant section outlet temperatures to 1700F (down from 1800F); and (4) the need to use higher performance (higher cost) steam cycles to offset losses introduced as more realistic operating and construction constraints are identified.

  7. Coal-fired high performance power generating system. Quarterly progress report, April 1--June 30, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-01T23:59:59.000Z

    This report covers work carried out under Task 2, Concept Definition and Analysis, Task 3, Preliminary R&D and Task 4, Commercial Generating Plant Design, under Contract AC22-92PC91155, ``Engineering Development of a Coal Fired High Performance Power Generation System`` between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of: >47% thermal efficiency; NO{sub x}, SO{sub x} and Particulates {le}25% NSPS; cost {ge}65% of heat input; all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW{sub e} combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (HITAF) which integrates several combustor and air heater designs with appropriate ash management procedures. A survey of currently available high temperature alloys has been completed and some of their high temperature properties are shown for comparison. Several of the most promising candidates will be selected for testing to determine corrosion resistance and high temperature strength. The corrosion resistance testing of candidate refractory coatings is continuing and some of the recent results are presented. This effort will provide important design information that will ultimately establish the operating ranges of the HITAF.

  8. ENGINEERING DEVELOPMENT OF COAL-FIRED HIGH PERFORMANCE POWER SYSTEMS PHASE II AND III

    SciTech Connect (OSTI)

    NONE

    1998-09-30T23:59:59.000Z

    This report presents work carried out under contract DE-AC22-95PC95144 "Engineering Development of Coal-Fired High Performance Systems Phase II and III." The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: ŕ thermal efficiency (HHV) >47%; ŕ NOx, SOx, and particulates <10% NSPS (New Source Performance Standard); ŕ coal providing >65% of heat input; ŕ all solid wastes benign; ŕ cost of electricity <90% of present plants. Phase I, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase I also included preliminary R&D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This phase, Phase II, involves the development and testing of plant subsystems, refinement and updating of the HIPPS commercial plant design, and the site selection and engineering design of a HIPPS prototype plant. Work reported herein is from: ŕ Task 2.2 HITAF Air Heaters; ŕ Task 6 HIPPS Commercial Plant Design Update.

  9. Life assessment and emissions monitoring of Indian coal-fired power plants. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-07-01T23:59:59.000Z

    At the request of the Pittsburgh Energy Technology Center (PETC) of the United States Department of Energy (USDOE), the traveler, along with Dr. R. P. Krishnan, Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee spent three weeks in India planning and performing emissions monitoring at the coal-fired Vijayawada Thermal Power Station (VTPS). The coordination for the Indian participants was provided by BHEL, Trichy and CPRI, Bangalore. The trip was sponsored by the PETC under the United States Agency for International Development (USAID)/Government of India (GOI)P Alternate Energy Resources Development (AERD) Project. The AERD Project is managed by PETC, and ORNL is providing the technical coordination and support for four coal projects that are being implemented with BHEL, Trichy. The traveler, after briefing the USAID mission in New Delhi visited BHEL, Trichy and CPRI, Bangalore to coordinate and plan the emissions test program. The site selection was made by BHEL, CPRI, TVA, and PETC. Monitoring was performed for 4 days on one of the 4 existing 210 MW coal-fired boilers at the VTPS, 400 km north of Madras, India.

  10. Life assessment and emissions monitoring of Indian coal-fired power plants

    SciTech Connect (OSTI)

    Not Available

    1992-07-01T23:59:59.000Z

    At the request of the Pittsburgh Energy Technology Center (PETC) of the United States Department of Energy (USDOE), the traveler, along with Dr. R. P. Krishnan, Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee spent three weeks in India planning and performing emissions monitoring at the coal-fired Vijayawada Thermal Power Station (VTPS). The coordination for the Indian participants was provided by BHEL, Trichy and CPRI, Bangalore. The trip was sponsored by the PETC under the United States Agency for International Development (USAID)/Government of India (GOI)P Alternate Energy Resources Development (AERD) Project. The AERD Project is managed by PETC, and ORNL is providing the technical coordination and support for four coal projects that are being implemented with BHEL, Trichy. The traveler, after briefing the USAID mission in New Delhi visited BHEL, Trichy and CPRI, Bangalore to coordinate and plan the emissions test program. The site selection was made by BHEL, CPRI, TVA, and PETC. Monitoring was performed for 4 days on one of the 4 existing 210 MW coal-fired boilers at the VTPS, 400 km north of Madras, India.

  11. Emissions, Monitoring and Control of Mercury from Subbituminous Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Alan Bland; Kumar Sellakumar; Craig Cormylo

    2007-08-01T23:59:59.000Z

    The Subbituminous Energy Coalition (SEC) identified a need to re-test stack gas emissions from power plants that burn subbituminous coal relative to compliance with the EPA mercury control regulations for coal-fired plants. In addition, the SEC has also identified the specialized monitoring needs associated with mercury continuous emissions monitors (CEM). The overall objectives of the program were to develop and demonstrate solutions for the unique emission characteristics found when burning subbituminous coals. The program was executed in two phases; Phase I of the project covered mercury emission testing programs at ten subbituminous coal-fired plants. Phase II compared the performance of continuous emission monitors for mercury at subbituminous coal-fired power plants and is reported separately. Western Research Institute and a number of SEC members have partnered with Eta Energy and Air Pollution Testing to assess the Phase I objective. Results of the mercury (Hg) source sampling at ten power plants burning subbituminous coal concluded Hg emissions measurements from Powder River Basin (PBR) coal-fired units showed large variations during both ICR and SEC testing. Mercury captures across the Air Pollution Control Devices (APCDs) present much more reliable numbers (i.e., the mercury captures across the APCDs are positive numbers as one would expect compared to negative removal across the APCDs for the ICR data). Three of the seven units tested in the SEC study had previously shown negative removals in the ICR testing. The average emission rate is 6.08 lb/TBtu for seven ICR units compared to 5.18 lb/TBtu for ten units in the SEC testing. Out of the ten (10) SEC units, Nelson Dewey Unit 1, burned a subbituminous coal and petcoke blend thus lowering the total emission rate by generating less elemental mercury. The major difference between the ICR and SEC data is in the APCD performance and the mercury closure around the APCD. The average mercury removal values across the APCDs are 2.1% and 39.4% with standard deviations (STDs) of 1990 and 75%, respectively for the ICR and SEC tests. This clearly demonstrates that variability is an issue irrespective of using 'similar' fuels at the plants and the same source sampling team measuring the species. The study also concluded that elemental mercury is the main Hg specie that needs to be controlled. 2004 technologies such as activated carbon injection (ACI) may capture up to 60% with double digit lb/MMacf addition of sorbent. PRB coal-fired units have an Hg input of 7-15 lb/TBtu; hence, these units must operate at over 60% mercury efficiency in order to bring the emission level below 5.8 lb/TBtu. This was non-achievable with the best technology available as of 2004. Other key findings include: (1) Conventional particulate collectors, such as Cold-side Electro-Static Precipitators (CESPs), Hot-side Electro-Static Precipitator (HESP), and Fabric Filter (FF) remove nearly all of the particulate bound mercury; (2) CESPs perform better highlighting the flue gas temperature effect on the mercury removal. Impact of speciation with flue gas cooling is apparent; (3) SDA's do not help in enhancing adsorption of mercury vapor species; and (4) Due to consistently low chlorine values in fuels, it was not possible to analyze the impact of chlorine. In summary, it is difficult to predict the speciation at two plants that burn the same fuel. Non-fuel issues, such as flue gas cooling, impact the speciation and consequently mercury capture potential.

  12. Potential nanotechnology applications for reducing freshwater consumption at coal fired power plants : an early view.

    SciTech Connect (OSTI)

    Elcock, D. (Environmental Science Division)

    2010-09-17T23:59:59.000Z

    This report was funded by the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) Existing Plants Research Program, which has an energy-water research effort that focuses on water use at power plants. This study complements the overall research effort of the Existing Plants Research Program by evaluating water issues that could impact power plants. A growing challenge to the economic production of electricity from coal-fired power plants is the demand for freshwater, particularly in light of the projected trends for increasing demands and decreasing supplies of freshwater. Nanotechnology uses the unique chemical, physical, and biological properties that are associated with materials at the nanoscale to create and use materials, devices, and systems with new functions and properties. It is possible that nanotechnology may open the door to a variety of potentially interesting ways to reduce freshwater consumption at power plants. This report provides an overview of how applications of nanotechnology could potentially help reduce freshwater use at coal-fired power plants. It was developed by (1) identifying areas within a coal-fired power plant's operations where freshwater use occurs and could possibly be reduced, (2) conducting a literature review to identify potential applications of nanotechnology for facilitating such reductions, and (3) collecting additional information on potential applications from researchers and companies to clarify or expand on information obtained from the literature. Opportunities, areas, and processes for reducing freshwater use in coal-fired power plants considered in this report include the use of nontraditional waters in process and cooling water systems, carbon capture alternatives, more efficient processes for removing sulfur dioxide and nitrogen oxides, coolants that have higher thermal conductivities than water alone, energy storage options, and a variety of plant inefficiencies, which, if improved, would reduce energy use and concomitant water consumption. These inefficiencies include air heater inefficiencies, boiler corrosion, low operating temperatures, fuel inefficiencies, and older components that are subject to strain and failure. A variety of nanotechnology applications that could potentially be used to reduce the amount of freshwater consumed - either directly or indirectly - by these areas and activities was identified. These applications include membranes that use nanotechnology or contain nanomaterials for improved water purification and carbon capture; nano-based coatings and lubricants to insulate and reduce heat loss, inhibit corrosion, and improve fuel efficiency; nano-based catalysts and enzymes that improve fuel efficiency and improve sulfur removal efficiency; nanomaterials that can withstand high temperatures; nanofluids that have better heat transfer characteristics than water; nanosensors that can help identify strain and impact damage, detect and monitor water quality parameters, and measure mercury in flue gas; and batteries and capacitors that use nanotechnology to enable utility-scale storage. Most of these potential applications are in the research stage, and few have been deployed at coal-fired power plants. Moving from research to deployment in today's economic environment will be facilitated with federal support. Additional support for research development and deployment (RD&D) for some subset of these applications could lead to reductions in water consumption and could provide lessons learned that could be applied to future efforts. To take advantage of this situation, it is recommended that NETL pursue funding for further research, development, or deployment for one or more of the potential applications identified in this report.

  13. ECONOMICS AND FEASIBILITY OF RANKINE CYCLE IMPROVEMENTS FOR COAL FIRED POWER PLANTS

    SciTech Connect (OSTI)

    Richard E. Waryasz; Gregory N. Liljedahl

    2004-09-08T23:59:59.000Z

    ALSTOM Power Inc.'s Power Plant Laboratories (ALSTOM) has teamed with the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL), American Electric Company (AEP) and Parsons Energy and Chemical Group to conduct a comprehensive study evaluating coal fired steam power plants, known as Rankine Cycles, equipped with three different combustion systems: Pulverized Coal (PC), Circulating Fluidized Bed (CFB), and Circulating Moving Bed (CMB{trademark}). Five steam cycles utilizing a wide range of steam conditions were used with these combustion systems. The motivation for this study was to establish through engineering analysis, the most cost-effective performance potential available through improvement in the Rankine Cycle steam conditions and combustion systems while at the same time ensuring that the most stringent emission performance based on CURC (Coal Utilization Research Council) 2010 targets are met: > 98% sulfur removal; < 0.05 lbm/MM-Btu NO{sub x}; < 0.01 lbm/MM-Btu Particulate Matter; and > 90% Hg removal. The final report discusses the results of a coal fired steam power plant project, which is comprised of two parts. The main part of the study is the analysis of ten (10) Greenfield steam power plants employing three different coal combustion technologies: Pulverized Coal (PC), Circulating Fluidized Bed (CFB), and Circulating Moving Bed (CMB{trademark}) integrated with five different steam cycles. The study explores the technical feasibility, thermal performance, environmental performance, and economic viability of ten power plants that could be deployed currently, in the near, intermediate, and long-term time frame. For the five steam cycles, main steam temperatures vary from 1,000 F to 1,292 F and pressures from 2,400 psi to 5,075 psi. Reheat steam temperatures vary from 1,000 F to 1,328 F. The number of feedwater heaters varies from 7 to 9 and the associated feedwater temperature varies from 500 F to 626 F. The main part of the study therefore determines the steam cycle parameters and combustion technology that would yield the lowest cost of electricity (COE) for the next generation of coal-fired steam power plants. The second part of the study (Repowering) explores the means of upgrading the efficiency and output of an older existing coal fired steam power plant. There are currently more than 1,400 coal-fired units in operation in the United States generating about 54 percent of the electricity consumed. Many of these are modern units are clean and efficient. Additionally, there are many older units in excellent condition and still in service that could benefit from this repowering technology. The study evaluates the technical feasibility, thermal performance, and economic viability of this repowering concept.

  14. Abdel-Aziz, A. and H.C. Frey, "Quantification of Hourly Variability in Hourly Activity and NOx Emissions for Baseload Coal-Fired Power Plants," Proceedings, Annual Meeting of the Air & Waste Management Association, Pittsburgh, PA, June 2003

    E-Print Network [OSTI]

    Frey, H. Christopher

    Emissions for Baseload Coal- Fired Power Plants," Proceedings, Annual Meeting of the Air & Waste Management for Baseload Coal Fired Power Plants Paper No. 69572 Amr Abdel-Aziz and H. Christopher Frey Department of Civil emission factors from coal-fired power plants vary over time due to variation in coal composition fed

  15. MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS LOCAL IMPACTS ON HUMAN HEALTH RISK.

    SciTech Connect (OSTI)

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; LIPFERT, F.; MORRIS, S.M.; BANDO, A.; PENA, R.; BLAKE, R.

    2005-12-01T23:59:59.000Z

    A thorough quantitative understanding of the processes of mercury emissions, deposition, and translocation through the food chain is currently not available. Complex atmospheric chemistry and dispersion models are required to predict concentration and deposition contributions, and aquatic process models are required to predict effects on fish. However, there are uncertainties in all of these predictions. Therefore, the most reliable method of understanding impacts of coal-fired power plants on Hg deposition is from empirical data. A review of the literature on mercury deposition around sources including coal-fired power plants found studies covering local mercury concentrations in soil, vegetation, and animals (fish and cows). There is strong evidence of enhanced local deposition within 3 km of the chlor-alkali plants, with elevated soil concentrations and estimated deposition rates of 10 times background. For coal-fired power plants, the data show that atmospheric deposition of Hg may be slightly enhanced. On the scale of a few km, modeling suggests that wet deposition may be increased by a factor of two or three over background. The measured data suggest lower increases of 15% or less. The effects of coal-fired plants seem to be less than 10% of total deposition on a national scale, based on emissions and global modeling. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (1) local soil concentration Hg increments of 30%-60%, (2) sediment increments of 18-30%, (3) wet deposition increments of 11-12%, and (4) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg{sub 0} in power plant plumes and the role of water chemistry in the relationship between Hg deposition and fish content. Soil and vegetation sampling programs were performed around two mid-size coal fired power plants. The objectives were to determine if local mercury hot-spots exist, to determine if they could be attributed to deposition of coal-fired power plant emissions, and to determine if they correlated with model predictions. These programs found the following: (1) At both sites, there was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. At the Kincaid plant, there was excess soil Hg along heavily traveled roads. The spatial pattern of soil mercury concentrations did not match the pattern of vegetation Hg concentrations at either plant. (2) At both sites, the subsurface (5-10 cm) samples the Hg concentration correlated strongly with the surface samples (0-5 cm). Average subsurface sample concentrations were slightly less than the surface samples; however, the difference was not statistically significant. (3) An unequivocal definition of background Hg was not possible at either site. Using various assumed background soil mercury concentrations, the percentage of mercury deposited within 10 km of the plant ranged between 1.4 and 8.5% of the RGM emissions. Based on computer modeling, Hg deposition was primarily RGM with much lower deposition from elemental mercury. Estimates of the percentage of total Hg deposition ranged between 0.3 and 1.7%. These small percentages of deposition are consistent with the empirical findings of only minor perturbations in environmental levels, as opposed to ''hot spots'', near the plants. The major objective of this study was to determine if there was evidence for ''hot-spots'' of mercury deposition around coal-fired power plants. Although the term has been used extensively, it has never been defined. From a public health perspective, such a ''hot spot'' must be large enough to insure that it did not occur by chance, and it must affect water bodies large enough to support a population of subsistence fishers. The results of this study support the hypothesis that n

  16. New 90,000 PPH Coal Fired Boiler Plant at Liggett & Myers Tobacco Company, Durham North Carolina 

    E-Print Network [OSTI]

    Kaskey, G. T.

    1984-01-01T23:59:59.000Z

    Liggett & Myers Tobacco Company in Durham, North Carolina is installing a future cogeneration, coal fired boiler system designed and built by Energy Systems (ESI) of Chattanooga, Tennessee. The complete boiler plant is comprised of a 90,000 pph Dorr-Oliver/E.Keeler...

  17. assumed, with no inter-district transport.) If the conventional technology coal-fired power plant is used

    E-Print Network [OSTI]

    assumed, with no inter-district transport.) If the conventional technology coal-fired power plant-fired power plant is used for comparison, then lower SO2, NOx or particulate emissions can be expected in 9. A final option considered was to retrofit emission controls for captive power plants at an additional cost

  18. ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

    SciTech Connect (OSTI)

    Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

    2002-12-30T23:59:59.000Z

    ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and related combustion performance. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive Powder River Basin coal (PRB) to a moderately reactive Midwestern bituminous coal (HVB) to a less reactive medium volatile Eastern bituminous coal (MVB). Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis.

  19. Modeling of integrated environmental control systems for coal-fired power plants

    SciTech Connect (OSTI)

    Rubin, E.S.

    1988-06-01T23:59:59.000Z

    This is the third quarterly report of DOE Contract No. DE-AC22- 87PC79864, entitled Modeling of Integrated Environmental Control Systems for Coal-Fired Power Plants.'' This report summarizes accomplishments during the period April 1, 1988 to June 30, 1988. Our efforts during the last quarter focused on, (1) completion of a sulfuric acid plant model (used in conjunction with by-product recovery processes for SO{sub 2}/NO{sub x} removal) and, (2) an update the NOXSO process model. Other accomplishments involved revision and expansion of the enthalpy data algorithms used for process energy balances. The sections below present the details of these developments. References are included at the end of each section.

  20. Proposed finding of no significant impact for the Sakakawea Medical Center coal-fired heating plant

    SciTech Connect (OSTI)

    Not Available

    1994-07-01T23:59:59.000Z

    The Department of Energy (the Department) has prepared an environmental assessment (Assessment) (DOE/EA-0949) to identify and evaluate the potential environmental impacts of a proposed action at the Sakakawea Medical Center (the Center) in Hazen, North Dakota. The proposed action would replace the existing No. 2 fuel oil-fired boilers supplemented by electric reheat with a new coal-fired hot water heating plant, using funds provided from a grant under the Institutional Conservation Program. Based on the analysis in DOE/EA-0949, the Department has determined that the proposed action is not a major federal action significantly affecting the quality of the human environment, within the meaning of the National Environmental Policy Act (NEPA) of 1969, as amended. Therefore, preparation of an Environmental Impact Statement is not required, and the Department is issuing this Finding of No Significant Impact (Finding).

  1. Comprehensive assessment of toxic emissions from coal-fired power plants

    SciTech Connect (OSTI)

    NONE

    1996-09-01T23:59:59.000Z

    The 1990 Clean Air Act Amendments (CAAA) have two primary goals: pollution prevention and a market-based least-cost approach to emission control. To address air quality issues as well as permitting and enforcement, the 1990 CAAA contain 11 sections or titles. The individual amendment titles are as follows: Title I - National Ambient Air Quality Standards Title II - Mobile Sources Title III - Hazardous Air Pollutants Title IV - Acid Deposition Control Title V - Permits Title VI - Stratospheric Ozone Protection Chemicals Title VII - Enforcement Title VIII - Miscellaneous Provisions Title IX - Clean Air Research Title X - Disadvantaged Business Concerns Title XI - Clean Air Employment Transition Assistance Titles I, III, IV, and V will change or have the potential to change how operators of coal-fired utility boilers control, monitor, and report emissions. For the purpose of this discussion, Title III is the primary focus.

  2. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Palo, Daniel; Srinivasachar, Srivats; Laudal, Daniel

    2014-12-01T23:59:59.000Z

    Under contract DE-FE0007603, the University of North Dakota conducted the project Evaluation of Carbon Dioxide Capture from Existing Coal Fired Plants by Hybrid Sorption Using Solid Sorbents. As an important element of this effort, an Environmental Health and Safety (EH&S) Assessment was conducted by Barr Engineering Co. (Barr) in association with the University of North Dakota. The assessment addressed air and particulate emissions as well as solid and liquid waste streams. The magnitude of the emissions and waste streams was estimated for evaluation purposes. EH&S characteristics of materials used in the system are also described. This document contains data based on the mass balances from both the 40 kJ/mol CO2 and 80 kJ/mol CO2 desorption energy cases evaluated in the Final Technical and Economic Feasibility study also conducted by Barr Engineering.

  3. PFB coal fired combined cycle development program. Annual report, July 1978-June 1979

    SciTech Connect (OSTI)

    Not Available

    1980-05-01T23:59:59.000Z

    The Coal Fired Combined Cycle (CFCC) is the unique powerplant concept developed under the leadership of the General Electric Company to provide a direct coal-burning gas turbine and steam turbine combined cycle powerplant. On the basis of previous studies and confirming work under this contract, General Electric continues to believe that the CFCC approach offers important advantages over alternate approaches: higher powerplant efficiency in the combustor temperature range of interest; reduced combustor/steam generator corrosion potential, due to low fluid-bed tube temperature (as contrasted to the air in tube cycle); and increased gas turbine bucket life from improved material protection systems. The objective of this program is to evaluate the coal fired combined cycle powerplant conceptual design, and to conduct a supporting development program. The supporting development is required for evaluating the pressurized fluidized bed combustion concept, for developing engineering correlations to be used in optimizing the commercial plant concept, and for evaluating the combustor/steam generator, the hot-gas cleanup, and the advanced gas turbine materials approach for this application. Work to date has identified the need to protect the gas turbine from corrosion caused by substantial amounts of alkali in the submicron aerosol and vapor phase and to protect the turbine from erosion caused by multi-micron-sized particulates. We believe that a solution to the corrosion protection challenge can more confidently and quickly be found by extending turbine materials work in dirty liquid fuels to the PFB environmental levels. Particulate removal for erosion protection has as its objective a better quantification of the erosion tolerance level coupled with work to improve the performance of inertial separators, including electrostatic augmentation, in the less-than-10-..mu..m-particle-size region. A few other testing programs are described briefly.

  4. The development of a coal-fired combustion system for industrial process heating applications

    SciTech Connect (OSTI)

    Not Available

    1992-07-16T23:59:59.000Z

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation's Coal-Fired Combustion System for Industrial Process Heating Applications has been selected for Phase III development under contract DE-AC22-91PC91161. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting, recycling, and refining processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase HI research effort is being focused on the development of a process heater system to be used for producing glass frits and wool fiber from boiler and incinerator ashes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The economic evaluation of commercial scale CMS processes has begun. In order to accurately estimate the cost of the primary process vessels, preliminary designs for 25, 50, and 100 ton/day systems have been started under Task 1. This data will serve as input data for life cycle cost analysis performed as part of techno-economic evaluations. The economic evaluations of commercial CMS systems will be an integral part of the commercialization plan.

  5. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01T23:59:59.000Z

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  6. Development of advanced NO[sub x] control concepts for coal-fired utility boiler

    SciTech Connect (OSTI)

    Evans, A.; Pont, J.N.; England, G.; Seeker, W.R.

    1993-02-11T23:59:59.000Z

    Hybrid technologies for the reduction of NO[sub x] emissions from coal-fired utility boilers have shown the potential to offer greater levels of NO[sub x] control than the sum of the individual technologies, leading to more cost effective emissions control strategies. Energy and Environmental Research Corporation (EER) has developed a hybrid NO[sub x] control strategy involving two proprietary concepts which has the potential to meet the US Department of Energy's NO[sub x] reduction goal at a significant reduction in cost compared to existing technology. The process has been named CombiNO[sub x]. CombiNO[sub x] is an integration of three technologies: modified reburning, promoted selective noncatalytic reduction (SNCR) and methanol injection. These technologies are combined to achieve high levels of NO[sub x] emission reduction from coal-fired power plants equipped with S0[sub x] scrubbers. The first two steps, modified reburning and promoted SNCR are linked. It has been shown that performance of the SNCR agent is dependent upon local oxidation of CO. Reburning is used to generate the optimum amount of CO to promote the SNCR agent. Approximately 10 percent reburning is required, this represents half of that required for conventional reburning. If the reburn fuel is natural gas, the combination of reburning and SNCR may result in a significant cost savings over conventional reburning. The third step, injection of methanol into the flue gas, is used to oxidize NO to N0[sub 2] which may subsequently be removed in a wet scrubber. Pilot-scale tests performed at EER's 1 MMBtu/hr Boiler Simulation Facility (BSF) have demonstrated NO[sub x] reductions up to 92%. The program's next phase entails process scale-up to a 10 MMBtu/hr furnace also located at EER's Santa Anna test site.

  7. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31T23:59:59.000Z

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and l

  8. Development and Testing of Industrial Scale Coal Fired Combustion System, Phase 3

    SciTech Connect (OSTI)

    Bert Zauderer

    1998-09-30T23:59:59.000Z

    Coal Tech Corp's mission is to develop, license & sell innovative, lowest cost, solid fuel fired power systems & total emission control processes using proprietary and patented technology for domestic and international markets. The present project 'DEVELOPMENT & TESTING OF INDUSTRIAL SCALE, COAL FIRED COMBUSTION SYSTEM, PHASE 3' on DOE Contract DE-AC22-91PC91162 was a key element in achieving this objective. The project consisted of five tasks that were divided into three phases. The first phase, 'Optimization of First Generation 20 MMBtu/hr Air-Cooled Slagging Coal Tech Combustor', consisted of three tasks, which are detailed in Appendix 'A' of this report. They were implemented in 1992 and 1993 at the first generation, 20 MMBtu/hour, combustor-boiler test site in Williamsport, PA. It consisted of substantial combustor modifications and coal-fired tests designed to improve the combustor's wall cooling, slag and ash management, automating of its operation, and correcting severe deficiencies in the coal feeding to the combustor. The need for these changes was indicated during the prior 900-hour test effort on this combustor that was conducted as part of the DOE Clean Coal Program. A combination of combustor changes, auxiliary equipment changes, sophisticated multi-dimensional combustion analysis, computer controlled automation, and series of single and double day shift tests totaling about 300 hours, either resolved these operational issues or indicated that further corrective changes were needed in the combustor design. The key result from both analyses and tests was that the combustor must be substantially lengthened to maximize combustion efficiency and sharply increase slag retention in the combustor. A measure of the success of these modifications was realized in the third phase of this project, consisting of task 5 entitled: 'Site Demonstration with the Second Generation 20 MMBtu/hr Air-Cooled Slagging Coal Tech Combustor'. The details of the task 5 effort are contained in Appendix 'C'. It was implemented between 1994 and 1998 after the entire 20 MMBtu/hr combustor-boiler facility was relocated to Philadelphia, PA in 1994. A new test facility was designed and installed. A substantially longer combustor was fabricated. Although not in the project plan or cost plan, an entire steam turbine-electric power generating plant was designed and the appropriate new and used equipment for continuous operation was specified. Insufficient funds and the lack of a customer for any electric power that the test facility could have generated prevented the installation of the power generating equipment needed for continuous operation. All other task 5 project measures were met and exceeded. 107 days of testing in task 5, which exceeded the 63 days (about 500 hours) in the test plan, were implemented. Compared to the first generation 20 MMBtu/hr combustor in Williamsport, the 2nd generation combustor has a much higher combustion efficiency, the retention of slag inside the combustor doubled to about 75% of the coal ash, and the ash carryover into the boiler, a major problem in the Williamsport combustor was essentially eliminated. In addition, the project goals for coal-fired emissions were exceeded in task 5. SO{sub 2} was reduced by 80% to 0.2 lb/MMBtu in a combination of reagent injection in the combustion and post-combustion zones. NO{sub x} was reduced by 93% to 0.07 lb/MMBtu in a combination of staged combustion in the combustor and post-combustion reagent injection. A baghouse was installed that was rated to 0.03 lb/MMBtu stack particle emissions. The initial particle emission test by EPA Method 5 indicated substantially higher emissions far beyond that indicated by the clear emission plume. These emissions were attributed to steel particles released by wall corrosion in the baghouse, correction of which had no effect of emissions.

  9. Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

    SciTech Connect (OSTI)

    Bradley Adams; Andrew Fry; Constance Senior; Hong Shim; Huafeng Wang; Jost Wendt; Christopher Shaddix

    2009-06-30T23:59:59.000Z

    This report summarizes Year 1 results of a research program designed to use multi-scale experimental studies and fundamental theoretical models to characterize and predict the impacts of retrofit of existing coal-fired utility boilers for oxy-combustion. Through the course of Year 1 activities, great progress was made toward understanding the issues associated with oxy-combustion retrofit of coal-fired boilers. All four Year 1 milestones and objectives have been, or will be, completed on schedule and within budget. Progress in the four milestone areas may be summarized as follows: • University of Utah has performed size segregated ash composition measurements in the Oxy-Fuel Combustor (OFC). These experiments indicate that oxy-combustion retrofit may impact ash aerosol mineral matter composition. Both flame temperature and flue gas composition have been observed to influence the concentration of calcium, magnesium and iron in the fine particulate. This could in turn impact boiler fouling and slagging. • Sandia National Labs has shown that char oxidation rate is dependent on particle size (for sizes between 60 and 100 microns) by performing fundamental simulations of reacting char particles. These predictions will be verified by making time-resolved optical measurements of char particle temperature, velocity and size in bench-scale experiments before the end of Year 1. • REI and Siemens have completed the design of an oxy-research burner that will be mounted on University of Utah’s pilot-scale furnace, the L1500. This burner will accommodate a wide range of O2, FGR and mixing strategies under conditions relevant for utility boiler operation. Through CFD modeling of the different burner designs, it was determined that the key factor influencing flame stabilization location is particle heat-up rate. The new oxy-research burner and associated equipment is scheduled for delivery before the end of Year 1. • REI has completed a literature survey of slagging and fouling mechanisms in coal-fired power plants to understand key issues influencing these deposition regimes and infer their behavior under oxy-fired conditions. Based on the results of this survey, an algorithm for integrating slagging predictions into CFD models was outlined. This method accounts for ash formation, particle impaction and sticking, deposit growth and physical properties and impact of the deposit on system flow and heat transfer. A model for fouling in the back pass has also been identified which includes vaporization of sodium, deposition of sodium sulfate on fly ash particles and tube surfaces, and deposit growth rate on tubes. In Year 1, REI has also performed a review of the literature describing corrosion in order to understand the behavior of oxidation, sulfidation, chloridation, and carburization mechanisms in air-fired and oxy-combustion systems. REI and Vattenfall have met and exchanged information concerning oxy-coal combustion mechanisms for CFD simulations currently used by Vattenfall. In preparation for Year 2 of this program, two coals (North Antelope PRB, Western bituminous) have been ordered, pulverized and delivered to the University of Utah and Sandia National Labs. Materials for the corrosion experiments have been identified, suppliers located, and a schedule for equipment fabrication and shakedown has been established. Finally, a flue gas recycle system has been designed and is being constructed for the OFC.

  10. Coal-fired high performance power generating system. Draft quarterly progress report, January 1--March 31, 1995

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This report covers work carried out under Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, ``Engineering Development of a Coal-Fired High Performance Power Generation System`` between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of >47% thermal efficiency; NO{sub x}, SO{sub x} and particulates {le} 25% NSPS; cost {ge}65% of heat input; all solid wastes benign. A crucial aspect of the authors design is the integration of the gas turbine requirements with the HITAF output and steam cycle requirements. In order to take full advantage of modern highly efficient aeroderivative gas turbines they have carried out a large number of cycle calculations to optimize their commercial plant designs for both greenfield and repowering applications.

  11. COMPACTING BIOMASS AND MUNICIPAL SOLID WASTES TO FORM AND UPGRADED FUEL

    SciTech Connect (OSTI)

    Henry Liu; Yadong Li

    2000-11-01T23:59:59.000Z

    Biomass waste materials exist in large quantity in every city and in numerous industrial plants such as wood processing plants and waste paper collection centers. Through minimum processing, such waste materials can be turned into a solid fuel for combustion at existing coal-fired power plants. Use of such biomass fuel reduces the amount of coal used, and hence reduces the greenhouse effect and global warming, while at the same time it reduces the use of land for landfill and the associated problems. The carbon-dioxide resulting from burning biomass fuel is recycled through plant growth and hence does not contribute to global warming. Biomass fuel also contains little sulfur and hence does not contribute to acid rain problems. Notwithstanding the environmental desirability of using biomass waste materials, not much of them are used currently due to the need to densify the waste materials and the high cost of conventional methods of densification such as pelletizing and briquetting. The purpose of this project was to test a unique new method of biomass densification developed from recent research in coal log pipeline (CLP). The new method can produce large agglomerates of biomass materials called ''biomass logs'' which are more than 100 times larger and 30% denser than conventional ''pellets'' or ''briquettes''. The Phase I project was to perform extensive laboratory tests and an economic analysis to determine the technical and economic feasibility of the biomass log fuel (BLF). A variety of biomass waste materials, including wood processing residues such as sawdust, mulch and chips of various types of wood, combustibles that are found in municipal solid waste stream such as paper, plastics and textiles, energy crops including willows and switch grass, and yard waste including tree trimmings, fallen leaves, and lawn grass, were tested by using this new compaction technology developed at Capsule Pipeline Research Center (CPRC), University of Missouri-Columbia (MU). The compaction conditions, including compaction pressure, pressure holding time, back pressure, moisture content, particle size and shape, piston and mold geometry and roughness, and binder for the materials were studied and optimized. The properties of the compacted products--biomass logs--were evaluated in terms of physical, mechanical, and combustion characteristics. An economic analysis of this technology for anticipated future commercial operations was performed. It was found that the compaction pressure and the moisture content of the biomass materials are critical for producing high-quality biomass logs. For most biomass materials, dense and strong logs can be produced under room temperature without binder and at a pressure of 70 MPa (10,000 psi), approximately. A few types of the materials tested such as sawdust and grass need a minimum pressure of 100 MPa (15,000 psi) in order to produce good logs. The appropriate moisture range for compacting waste paper into good logs is 5-20%, and the optimum moisture is in the neighborhood of 13%. For the woody materials and yard waste, the appropriate moisture range is narrower: 5-13%, and the optimum is 8-9%. The compacted logs have a dry density of 0.8 to 1.0 g/cm{sup 3}, corresponding to a wet density of 0.9 to 1.1 g/cm{sup 3}, approximately. The logs have high strength and high resistance to impact and abrasion, but are feeble to water and hence need to be protected from water or rain. They also have good long-term performance under normal environmental conditions, and can be stored for a long time without significant deterioration. Such high-density and high-strength logs not only facilitate handling, transportation, and storage, but also increase the energy content of biomass per unit volume. After being transported to power plants and crushed, the biomass logs can be co-fired with coal to generate electricity.

  12. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 2

    SciTech Connect (OSTI)

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K. [eds.

    1994-06-01T23:59:59.000Z

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume II contains papers presented at the following sessions: filter technology issues; hazardous air pollutants; sorbents and solid wastes; and membranes. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  13. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 1

    SciTech Connect (OSTI)

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K. [eds.

    1994-06-01T23:59:59.000Z

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume I contains papers presented at the following sessions: opening commentaries; changes in the market and technology drivers; advanced IGCC systems; advanced PFBC systems; advanced filter systems; desulfurization system; turbine systems; and poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  14. Clean coal technology: selective catalytic reduction (SCR) technology for the control of nitrogen oxide emissions from coal-fired boilers

    SciTech Connect (OSTI)

    NONE

    2005-05-01T23:59:59.000Z

    The report discusses a project carried out under the US Clean Coal Technology (CCT) Demonstration Program which demonstrated selective catalytic reduction (SCR) technology for the control of NOx emissions from high-sulphur coal-fired boilers under typical boilers conditions in the United States. The project was conducted by Southern Company Services, Inc., who served as a co-funder and as the host at Gulf Power Company's Plant Crist. The SCR process consists of injecting ammonia (NH{sub 3}) into boiler flue gas and passing the flue gas through a catalyst bed where the Nox and NH{sub 3} react to form nitrogen and water vapor. The results of the CCTDP project confirmed the applicability of SCR for US coal-fired power plants. In part as a result of the success of this project, a significant number of commercial SCR units have been installed and are operating successfully in the United States. By 2007, the total installed SCR capacity on US coal-fired units will number about 200, representing about 100,000 MWe of electric generating capacity. This report summarizes the status of SCR technology. 21 refs., 3 figs., 2 tabs., 10 photos.

  15. Conference on alternatives for pollution control from coal-fired low emission sources, Plzen, Czech Republic. Plzen Proceedings

    SciTech Connect (OSTI)

    Not Available

    1994-07-01T23:59:59.000Z

    The Conference on Alternatives for Pollution Control from Coal-Fired Emission Sources presented cost-effective approaches for pollution control of low emission sources (LES). It also identified policies and strategies for implementation of pollution control measures at the local level. Plzen, Czech Republic, was chosen as the conference site to show participants first hand the LES problems facing Eastern Europe today. Collectively, these Proceedings contain clear reports on: (a) methods for evaluating the cost effectiveness of alternative approaches to control pollution from small coal-fired boilers and furnaces; (b) cost-effective technologies for controlling pollution from coal-fired boilers and furnaces; (c) case studies of assessment of cost effective pollution control measures for selected cities in eastern Europe; and (d) approaches for actually implementing pollution control measures in cities in Eastern Europe. It is intended that the eastern/central European reader will find in these Proceedings useful measures that can be applied to control emissions and clean the air in his city or region. The conference was sponsored by the United States Agency for International Development (AID), the United States Department of Energy (DOE), and the Czech Ministry of Industry and Trade. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

  16. Engineering development of coal-fired high performance power systems, Phase II and III

    SciTech Connect (OSTI)

    None

    1999-01-01T23:59:59.000Z

    The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: thermal efficiency (HHV) {ge} 47%; NOx, SOx, and particulates {le} 10% NSPS (New Source Performance Standard) coal providing {ge} 65% of heat input; all solid wastes benign; cost of electricity {le} 90% of present plants. Phase 1, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase 1 also included preliminary R and D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This phase, Phase 2, involves the development and testing of plant subsystems, refinement and updating of the HIPPS commercial plant design, and the site selection and engineering design of a HIPPS prototype plant. Work reported herein is from: Task 2.1 HITAC Combustors; Task 2.2 HITAF Air Heaters; Task 6 HIPPS Commercial Plant Design Update.

  17. Historical Costs of Coal-Fired Electricity and Implications for the Future

    E-Print Network [OSTI]

    McNerney, James; Farmer, J Doyne

    2010-01-01T23:59:59.000Z

    We study the costs of coal-fired electricity in the United States between 1882 and 2006 by decomposing it in terms of the price of coal, transportation costs, energy density, thermal efficiency, plant construction cost, interest rate, and capacity factor. The dominant determinants of costs at present are the price of coal and plant construction cost. The price of coal appears to fluctuate more or less randomly while the construction cost follows long-term trends, decreasing from 1902 - 1970, increasing from 1970 - 1990, and leveling off or decreasing a little since then. This leads us to forecast that even without carbon capture and storage, and even under an optimistic scenario in which construction costs resume their previously decreasing trending behavior, the cost of coal-based electricity will drop for a while but eventually be determined by the price of coal, which varies stochastically but shows no long term decreasing trends. Our analysis emphasizes the importance of using long time series and compari...

  18. Development and testing of a commercial-scale coal-fired combustion system, Phase 3

    SciTech Connect (OSTI)

    Litka, A.F.; Breault, R.W.

    1991-10-01T23:59:59.000Z

    Within the commercial sector, oil and natural gas are the predominant fuels used to meet the space-heating needs of schools, office buildings, apartment complexes, and other similar structures. In general, these buildings require firing rates of 1 to 10 million Btu/hr. The objective of this program is to demonstrate the technical and economic viability of a coal-fired combustion system for this sector. The commercial-scale coal-water slurry (CWS)-fired space heating system will be a scale-up of a CWS-fired residential warm-air heating system developed by Tecogen under contract to the Department of Energy, Pittsburgh Energy Technology Center. This system included a patented nonslagging combustor known as IRIS, for Inertial Reactor with Internal Separation. This combustion technology, which has demonstrated high combustion efficiency using CWS fuels at input rates of 100,000 Btu/hr, will be scaled to operate at 2 to 5 millon Btu/hr. Along with the necessary fuel storage and delivery, heat recovery, and control equipment, the system will include pollution control devices to meet targeted values of NO{sub x}, S0{sub 2}, and particulate emissions. In general, the system will be designed to match the reliability, safety, turndown, and ignition performance of gas or oil-fired systems.

  19. Research on fundamental aspects of inorganic vapor and particle deposition in coal-fired systems

    SciTech Connect (OSTI)

    Rosner, D.E.

    1992-09-01T23:59:59.000Z

    In September 1990 DOE-PETC initiated at the Yale HTCRE Laboratory a systematic three-year research program directed toward providing engineers with the fundamentally-based design/optimization 'tools' for economically predicting the dynamics of net deposit growth*, and thermophysical properties of the resulting microparticulate deposits in coal-fired systems. In light of the theoretical 'program' based on the notion of self-regulation'' set forth in Rosner and Nagarajan (1987), this Task includes investigation of the effects of particle material properties and possible liquid phases on the capture properties of particulate deposits. For this purpose we exploit dynamical 'many-body' computer simulation techniques. This approach will provide the required parametric dependencies (on such quantities as incident kinetic energy and angle, mechanical and thermophysical properties of the particles,[hor ellipsis]) of a dimensionless ensemble-averaged particle capture fraction, relegating the role of direct laboratory experiment to verifying (or rejecting) some crucial features/consequences of the simulation route followed. Our ultimate goal is recommend 'sticking' and 'erosion' laws of mechanistic origin. The availability of such laws could dramatically increase the reliability of predicted deposition rates of inertially delivered particles, in the simultaneous presence of a condensed liquid phase within the growing particulate, deposit. Equally important, one could also rationally select conditions to avoid. troublesome deposition subject to other operational requirements.

  20. Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development

    SciTech Connect (OSTI)

    Radisav Vidic; Joseph Flora; Eric Borguet

    2008-12-31T23:59:59.000Z

    The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

  1. An assessment of mercury emissions and health risks from a coal-fired power plant

    SciTech Connect (OSTI)

    Fthenakis, V.M.; Lipfert, F.; Moskowitz, P. [Brookhaven National Lab., Upton, NY (United States). Analytical Sciences Div.

    1994-12-01T23:59:59.000Z

    Title 3 of the 1990 Clean Air Act Amendments (CAAA) mandated that the US Environmental Protection Agency (EPA) evaluate the need to regulate mercury emissions from electric utilities. In support of this forthcoming regulatory analysis the U.S. DOE, sponsored a risk assessment project at Brookhaven (BNL) to evaluate methylmercury (MeHg) hazards independently. In the US MeHg is the predominant way of exposure to mercury originated in the atmosphere. In the BNL study, health risks to adults resulting from Hg emissions from a hypothetical 1,000 MW coal-fired power plant were estimated using probabilistic risk assessment techniques. This study showed that the effects of emissions of a single power plant may double the background exposures to MeHg resulting from consuming fish obtained from a localized area near the power plant. Even at these more elevated exposure levels, the attributable incidence in mild neurological symptoms was estimated to be quite small, especially when compared with the estimated background incidence in the population. The current paper summarizes the basic conclusions of this assessment and highlights issues dealing with emissions control and environmental transport.

  2. Multiplexed Optical Fiber Sensors for Coal Fired Advanced Fossil Energy Systems

    SciTech Connect (OSTI)

    Anbo Wang; Gary Pickrell

    2011-12-31T23:59:59.000Z

    This report summarizes technical progress on the program â??Multiplexed Optical Fiber Sensors for Coal Fired Advanced Fossil Energy Systemsâ?ť funded by the National Energy Technology Laboratory of the U.S. Department of Energy, and performed jointly by the Center for Photonics Technology of the Bradley Department of Electrical and Computer Engineering and the Department of Materials Science and Engineering at Virginia Tech. This three-year project started on October 1, 2008. In the project, a fiber optical sensing system based on intrinsic Fabry-Perot Interferometer (IFPI) was developed for strain and temperature measurements for Ultra Supercritical boiler condition assessment. Investigations were focused on sensor design, fabrication, attachment techniques and novel materials for high temperature and strain measurements. At the start of the project, the technical requirements for the sensing technology were determined together with our industrial partner Alstom Power. As is demonstrated in Chapter 4, all the technical requirements are successfully met. The success of the technology extended beyond laboratory test; its capability was further validated through the field test at DOE NETL, in which the sensors yielded distributed temperature mapping of a testing coupon installed in the turbine test rig. The measurement results agreed well with prior results generated with thermocouples. In this project, significant improvements were made to the IFPI sensor technology by splicing condition optimization, transmission loss reduction, sensor signal demodulation and sensor system design.

  3. A study of toxic emissions from a coal-fired gasification plant. Final report

    SciTech Connect (OSTI)

    NONE

    1995-12-01T23:59:59.000Z

    Under the Fine Particulate Control/Air Toxics Program, the US Department of Energy (DOE) has been performing comprehensive assessments of toxic substance emissions from coal-fired electric utility units. An objective of this program is to provide information to the US Environmental Protection Agency (EPA) for use in evaluating hazardous air pollutant emissions as required by the Clean Air Act Amendments (CAAA) of 1990. The Electric Power Research Institute (EPRI) has also performed comprehensive assessments of emissions from many power plants and provided the information to the EPA. The DOE program was implemented in two. Phase 1 involved the characterization of eight utility units, with options to sample additional units in Phase 2. Radian was one of five contractors selected to perform these toxic emission assessments.Radian`s Phase 1 test site was at southern Company Service`s Plant Yates, Unit 1, which, as part of the DOE`s Clean Coal Technology Program, was demonstrating the CT-121 flue gas desulfurization technology. A commercial-scale prototype integrated gasification-combined cycle (IGCC) power plant was selected by DOE for Phase 2 testing. Funding for the Phase 2 effort was provided by DOE, with assistance from EPRI and the host site, the Louisiana Gasification Technology, Inc. (LGTI) project This document presents the results of that effort.

  4. Engineering development of coal-fired high performance power systems, Phase II and III

    SciTech Connect (OSTI)

    None

    1998-07-01T23:59:59.000Z

    The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: thermal efficiency (HHV) {ge} 47%, NOx, SOx, and particulates {le} 10% NSPS (New Source Performance Standard), coal providing {ge} 65% of heat input, all solid wastes benign cost of electricity {le} 90% of present plants. Phase 1, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase 1 also included preliminary R and D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This phase, Phase 2, involves the development and testing of plant subsystems, refinement and updating of the HIPPS commercial plant design, and the site selection and engineering design of a HIPPS prototype plant. Work reported herein is from: Task 2.1 HITAF Combustor; Task 2.2 HITAF Air Heaters; Task 6 HIPPS Commercial Plant Design Update.

  5. MHD Coal Fired Flow Facility. Quarterly technical progress report, July-September 1980

    SciTech Connect (OSTI)

    Altstatt, M. C.; Attig, R. C.; Brosnan, D. A.

    1980-11-01T23:59:59.000Z

    Significant activity, task status, planned research, testing, development, and conclusions for the Magnetohydrodynamics (MHD) Coal-Fired Flow Facility (CFFF) and the Energy Conversion Facility (ECF) are described. On Task 1, the first phase of the downstream quench system was completed. On Task 2, all three combustor sections were completed, hydrotested, ASME code stamped, and delivered to UTSI. The nozzle was also delivered. Fabrication of support stands and cooling water manifolds for the combustor and vitiation heater were completed, heat transfer and thermal stress analysis, along with design development, were conducted on the generator and radiant furnace and secondary combustor installation progressed as planned. Under Task 3 an Elemental Analyzer and Atomic Absorption Spectrophotometer/Graphite Furnace were received and installed, sites were prepared for two air monitoring stations, phytoplankton analysis began, and foliage and soil sampling was conducted using all study plots. Some 288 soil samples were combined to make 72 samples which were analyzed. Also, approval was granted to dispose of MHD flyash and slag at the Franklin County landfill. Task 4 effort consisted of completing all component test plans, and establishing the capability of displaying experimental data in graphical format. Under Task 7, a preliminary testing program for critical monitoring of the local current and voltage non-uniformities in the generator electrodes was outlined, electrode metal wear characteristics were documented, boron nitride/refrasil composite interelectrode sealing was improved, and several refractories for downstream MHD applications were evaluated with promising results.

  6. Health and environmental effects of coal-fired electric power plants

    SciTech Connect (OSTI)

    Morris, S.C.; Hamilton, L.D.

    1984-05-01T23:59:59.000Z

    This paper describes health and environmental impacts of coal-fired electric power plants. Effects on man, agriculture, and natural ecosystems are considered. These effects may result from direct impacts or exposures via air, water, and food chains. The paper is organized by geographical extent of effect. Occupational health impacts and local environmental effects such as noise and solid waste leachate are treated first. Then, regional effects of air pollution, including acid rain, are analyzed. Finally, potential global impacts are examined. Occupational health concerns considered include exposure to noise, dust, asbestos, mercury, and combustion products, and resulting injury and disease. Local effects considered include noise; air and water emissions of coal storage piles, solid waste operations, and cooling systems. Air pollution, once an acute local problem, is now a regional concern. Acute and chronic direct health effects are considered. Special attention is given to potential effects of radionuclides in coal and of acid rain. Finally, potential global impacts associated with carbon dioxide emissions are considered. 88 references, 9 tables.

  7. Production of New Biomass/Waste-Containing Solid Fuels

    SciTech Connect (OSTI)

    Glenn A. Shirey; David J. Akers

    2005-09-23T23:59:59.000Z

    CQ Inc. and its industry partners--PBS Coals, Inc. (Friedens, Pennsylvania), American Fiber Resources (Fairmont, West Virginia), Allegheny Energy Supply (Williamsport, Maryland), and the Heritage Research Group (Indianapolis, Indiana)--addressed the objectives of the Department of Energy and industry to produce economical, new solid fuels from coal, biomass, and waste materials that reduce emissions from coal-fired boilers. This project builds on the team's commercial experience in composite fuels for energy production. The electric utility industry is interested in the use of biomass and wastes as fuel to reduce both emissions and fuel costs. In addition to these benefits, utilities also recognize the business advantage of consuming the waste byproducts of customers both to retain customers and to improve the public image of the industry. Unfortunately, biomass and waste byproducts can be troublesome fuels because of low bulk density, high moisture content, variable composition, handling and feeding problems, and inadequate information about combustion and emissions characteristics. Current methods of co-firing biomass and wastes either use a separate fuel receiving, storage, and boiler feed system, or mass burn the biomass by simply mixing it with coal on the storage pile. For biomass or biomass-containing composite fuels to be extensively used in the U.S., especially in the steam market, a lower cost method of producing these fuels must be developed that is applicable to a variety of combinations of biomass, wastes, and coal; economically competitive with current fuels; and provides environmental benefits compared with coal. During Phase I of this project (January 1999 to July 2000), several biomass/waste materials were evaluated for potential use in a composite fuel. As a result of that work and the team's commercial experience in composite fuels for energy production, paper mill sludge and coal were selected for further evaluation and demonstration in Phase II. In Phase II (June 2001 to December 2004), the project team demonstrated the GranuFlow technology as part of a process to combine paper sludge and coal to produce a composite fuel with combustion and handling characteristics acceptable to existing boilers and fuel handling systems. Bench-scale studies were performed at DOE-NETL, followed by full-scale commercial demonstrations to produce the composite fuel in a 400-tph coal cleaning plant and combustion tests at a 90-MW power plant boiler to evaluate impacts on fuel handling, boiler operations and performance, and emissions. A circuit was successfully installed to re-pulp and inject paper sludge into the fine coal dewatering circuit of a commercial coal-cleaning plant to produce 5,000 tons of a ''composite'' fuel containing about 5% paper sludge. Subsequent combustion tests showed that boiler efficiency and stability were not compromised when the composite fuel was blended with the boiler's normal coal supply. Firing of the composite fuel blend did not have any significant impact on emissions as compared to the normal coal supply, and it did not cause any excursions beyond Title V regulatory limits; all emissions were well within regulatory limits. SO{sub 2} emissions decreased during the composite fuel blend tests as a result of its higher heat content and slightly lower sulfur content as compared to the normal coal supply. The composite fuel contained an extremely high proportion of fines because the parent coal (feedstock to the coal-cleaning plant) is a ''soft'' coal (HGI > 90) and contained a high proportion of fines. The composite fuel was produced and combustion-tested under record wet conditions for the local area. In spite of these conditions, full load was obtained by the boiler when firing the composite fuel blend, and testing was completed without any handling or combustion problems beyond those typically associated with wet coal. Fuel handling and pulverizer performance (mill capacity and outlet temperatures) could become greater concerns when firing composite fuels which contain higher percent

  8. Optimum usage and economic feasibility of animal manure-based biomass in combustion systems 

    E-Print Network [OSTI]

    Carlin, Nicholas T.

    2010-07-14T23:59:59.000Z

    Manure-based biomass (MBB) has the potential to be a source of green energy at large coal-fired power plants and on smaller-scale combustion systems at or near confined animal feeding operations. Although MBB is a low quality fuel with an inferior...

  9. Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

    SciTech Connect (OSTI)

    Adams, Bradley; Davis, Kevin; Senior, Constance; Shim, Hong Shim; Otten, Brydger; Fry, Andrew; Wendt, Jost; Eddings, Eric; Paschedag, Alan; Shaddix, Christopher; Cox, William; Tree, Dale

    2013-09-30T23:59:59.000Z

    Reaction Engineering International (REI) managed a team of experts from University of Utah, Siemens Energy, Praxair, Vattenfall AB, Sandia National Laboratories, Brigham Young University (BYU) and Corrosion Management Ltd. to perform multi-scale experiments, coupled with mechanism development, process modeling and CFD modeling, for both applied and fundamental investigations. The primary objective of this program was to acquire data and develop tools to characterize and predict impacts of CO{sub 2} flue gas recycle and burner feed design on flame characteristics (burnout, NO{sub x}, SO{sub x}, mercury and fine particle emissions, heat transfer) and operational concerns (fouling, slagging and corrosion) inherent in the retrofit of existing coal-fired boilers for oxy-coal combustion. Experimental work was conducted at Sandia National Laboratories’ Entrained Flow Reactor, the University of Utah Industrial Combustion Research Facility, and Brigham Young University. Process modeling and computational fluid dynamics (CFD) modeling was performed at REI. Successful completion of the project objectives resulted in the following key deliverables: 1) Multi-scale test data from 0.1 kW bench-scale, 100 kW and 200 kW laboratory-scale, and 1 MW semi-industrial scale combustors that describe differences in flame characteristics, fouling, slagging and corrosion for coal combustion under air-firing and oxygen-firing conditions, including sensitivity to oxy-burner design and flue gas recycle composition. 2) Validated mechanisms developed from test data that describe fouling, slagging, waterwall corrosion, heat transfer, char burnout and sooting under coal oxy-combustion conditions. The mechanisms were presented in a form suitable for inclusion in CFD models or process models. 3) Principles to guide design of pilot-scale and full-scale coal oxy-firing systems and flue gas recycle configurations, such that boiler operational impacts from oxy-combustion retrofits are minimized. 4) Assessment of oxy-combustion impacts in two full-scale coal-fired utility boiler retrofits based on computational fluid dynamics (CFD) modeling of air-fired and oxygen-fired operation. This research determined that it is technically feasible to retrofit the combustion system in an air-fired boiler for oxy-fired operation. The impacts of CO{sub 2} flue gas recycle and burner design on flame characteristics (burnout, NO{sub x}, SO{sub x}, mercury and fine particle emissions, heat transfer) and operational concerns (fouling, slagging and corrosion) were minimal, with the exception of high sulfur levels resulting from untreated flue gas recycle with medium and high-sulfur coals. This work focused on combustion in the radiant and convective sections of the boiler and did not address boiler system integration issues, plant efficiencies, impacts on downstream air pollution control devices, or CO{sub 2} capture and compression. The experimental data, oxy-firing system principles and oxy-combustion process mechanisms provided by this work can be used by electric utilities, boiler OEMs, equipment suppliers, design firms, software vendors, consultants and government agencies to assess retrofit applications of oxy-combustion technologies to existing boilers and to guide development of new designs.

  10. PFB coal fired combined cycle development program. Commercial plant requirements definition update (Task 1. 1)

    SciTech Connect (OSTI)

    Not Available

    1980-05-01T23:59:59.000Z

    The Coal Fired Combined Cycle (CFCC) power system thermodynamic cycle is illustrated schematically. Pressurized air supplied at the discharge of gas turbine compressors is ducted to the pressure vessel of pressurized, fluidized-bed, combustor-steam generator modules. The air is introduced in parallel to the beds, entering through distribution grids beneath each bed. Steam generation tubes are buried within the beds and are also arranged as membrane tube walls enclosing the four sides. Crushed coal (1/4 inch x 0) is pneumatically fed at locations just above the air inlet grids at the bottom of each bed. Dolomite is similarly fed to the individual beds. The coal is burned at a temperature below the ash fusion point. Sulfur is removed in the fluid beds through reaction of the SO/sub 2/ with CaCO/sub 3/ and O/sub 2/ to form solid CaSO/sub 4/ and CO/sub 2/ gas. The combustion gases leave the beds at a temperature in the range of 1400/sup 0/F to 1750/sup 0/F, depending upon the plant load fraction, and combustion heat is also transferred from the bed to the steam generation tubes. For the PFB combustor at full load, approximately 39% of the heating value of the coal appears i the exhaust gas, 57% appears in the steam, and 4% is apportioned among various losses. The steam circuitry is the supercritical once-through type. Steam is generated at 3500 psi and 1000/sup 0/F and is reheated to 1000/sup 0/F after expansion through the high pressure section of the steam turbine. The exhaust gases from the fluidized beds, which entrain a high percentage of the coal ash as well as dolomite fines, are ducted to conventional cyclones and then to electrocyclones before being admitted to the gas turbine.

  11. Optimization of Trona/Limestone Injection for SO2 Control in Coal-Fired Boilers

    SciTech Connect (OSTI)

    None

    2005-09-01T23:59:59.000Z

    Mobotec USA develops and markets air pollution control systems for utility boilers and other combustion systems. They have a particular interest in technologies that can reduce NOx, SOx, and mercury emissions from coal-fired boilers, and have been investigating the injection of sorbents such as limestone and trona into a boiler to reduce SOx and Hg emissions. WRI proposed to use the Combustion Test Facility (CTF) to enable Mobotec to conduct a thorough evaluation of limestone and trona injection for SO{sub 2} control. The overall goal of the project was to characterize the SO{sub 2} reductions resulting from the injection of limestone and trona into the CTF when fired with a high-sulfur eastern bituminous coal used in one of Mobotec's Midwest installations. Results revealed that when limestone was injected at Ca:S molar ratios of 1.5 to 3.0, the resulting SO{sub 2} reductions were 35-55%. It is believed that further reductions can be attained with improved mixing of the sorbent with the combustion gases. When limestone was added to the coal, at Ca:S molar ratios of 0.5 to 1.5, the SO{sub 2} reductions were 13-21%. The lower reductions were attributed to dead-burning of the sorbent in the high temperature flame zone. In cases where limestone was both injected into the furnace and added to the coal, the total SO{sub 2} reductions for a given Ca:S molar ratio were similar to the reductions for furnace injection only. The injection of trona into the mid-furnace zone, for Na:S molar ratios of 1.4 to 2.4, resulted in SO{sub 2} reductions of 29-43%. Limestone injection did not produce any slag deposits on an ash deposition probe while trona injection resulted in noticeable slag deposition.

  12. Engineering Development of Coal-Fired High-Performance Power Systems

    SciTech Connect (OSTI)

    York Tsuo

    2000-12-31T23:59:59.000Z

    A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolysis process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately. This report addresses the areas of technical progress for this quarter. The detail of syngas cooler design is given in this report. The final construction work of the CFB pyrolyzer pilot plant has started during this quarter. No experimental testing was performed during this quarter. The proposed test matrix for the future CFB pyrolyzer tests is given in this report. Besides testing various fuels, bed temperature will be the primary test parameter.

  13. Evolution of particulate emissions from a coal-fired power plant. [Ph. D. Thesis

    SciTech Connect (OSTI)

    Buckholtz, H.T.Y.

    1980-08-15T23:59:59.000Z

    A numerical model has been developed for the dispersal of aerosols downwind from a coal-fired power plant. The main goals were to evaluate with a mathematical simulation the evolution of the spatial extent and particle size distribution of the aerosol material and to predict settling rates affecting the surface environment in the downwind path. The hot air plume coming out of the power plant stack includes a large quantity of aerosol particles. The plume rises with initial upward emission speed until it reaches thermal and kinetic equilibria with the ambient air, then it is transported by the wind current. The plume disperses vertically and horizontally by wind turbulence. In the model particulate coagulation is mathematically described by Timiskii's equation. The relevant semi-empirical work of Smirnov is incorporated to provide the coagulation constant. Because of coagulation, the concentrations of different sizes of aerosol particles in the plume are changed. The numerical simulation studies the importance of particulate coagulation and turbulent dispersion on the downwind plume profile. The downwind transport of the aerosol particles is described by Fick's diffusion equation with the Brownian diffusion coefficient replaced by the turbulent diffusion coefficient. Particle sedimentation is incorporated into the diffusion equation as a first-order differential term. The transport equation is solved by an unconditionally stable finite difference method. At 20 miles downwind, most of the particles with diameter larger than 10 ..mu..m have settled to the ground. The size distribution is still bimodal. The distribution of larger particles remains almost unchanged, except for the departure of the super-micronic particles, because coagulation losses are approximately balanced by coagulation gains.

  14. The best use of biomass? Greenhouse gas lifecycle analysis of predicted pyrolysis biochar systems 

    E-Print Network [OSTI]

    Hammond, James A R

    2009-01-01T23:59:59.000Z

    to pessimistic scenarios are used for system operation. Slow pyrolysis is compared to fast pyrolysis and biomass co-firing for GHG abatement and electricity production, using various scenarios for availability of indigenous Scottish feedstocks....

  15. Cofiring of coal and dairy biomass in a 100,000 btu/hr furnace

    E-Print Network [OSTI]

    Lawrence, Benjamin Daniel

    2009-05-15T23:59:59.000Z

    Dairy biomass (DB) is evaluated as a possible co-firing fuel with coal. Cofiring of DB offers a technique of utilizing dairy manure for power/steam generation, reducing greenhouse gas concerns, and increasing financial returns to dairy operators...

  16. Sintering and joining of low temperature co-fired tungsten and aluminum oxide

    E-Print Network [OSTI]

    Boonyongmaneerat, Yuttanant

    2006-01-01T23:59:59.000Z

    Conventional methods used to fabricate co-fired tungsten/alumina composites usually rely on high temperature processing (>1500C). As it would be beneficial or even necessary for some applications to produce such composites ...

  17. Optimum usage and economic feasibility of animal manure-based biomass in combustion systems

    E-Print Network [OSTI]

    Carlin, Nicholas T.

    2010-07-14T23:59:59.000Z

    value of cattle biomass vs. moisture and ash percentage (assuming a dry, ash free HHV of 19,770 kJ/kg)........................................32 Figure 2.5 Nitrogen, sulfur, and chlorine contents of DB, FB, Texas lignite, and Wyoming sub... 6.27 Ash emission vs. co-fire rate when replacing Wyoming sub-bituminous coal with low-ash dairy biomass ...............................................................269 Figure 6.28 Ash emission vs. co-fire rate when replacing Texas lignite...

  18. Superheater Corrosion In Biomass Boilers: Today's Science and Technology

    SciTech Connect (OSTI)

    Sharp, William (Sandy) [SharpConsultant

    2011-12-01T23:59:59.000Z

    This report broadens a previous review of published literature on corrosion of recovery boiler superheater tube materials to consider the performance of candidate materials at temperatures near the deposit melting temperature in advanced boilers firing coal, wood-based fuels, and waste materials as well as in gas turbine environments. Discussions of corrosion mechanisms focus on the reactions in fly ash deposits and combustion gases that can give corrosive materials access to the surface of a superheater tube. Setting the steam temperature of a biomass boiler is a compromise between wasting fuel energy, risking pluggage that will shut the unit down, and creating conditions that will cause rapid corrosion on the superheater tubes and replacement expenses. The most important corrosive species in biomass superheater corrosion are chlorine compounds and the most corrosion resistant alloys are typically FeCrNi alloys containing 20-28% Cr. Although most of these materials contain many other additional additions, there is no coherent theory of the alloying required to resist the combination of high temperature salt deposits and flue gases that are found in biomass boiler superheaters that may cause degradation of superheater tubes. After depletion of chromium by chromate formation or chromic acid volatilization exceeds a critical amount, the protective scale gives way to a thick layer of Fe{sub 2}O{sub 3} over an unprotective (FeCrNi){sub 3}O{sub 4} spinel. This oxide is not protective and can be penetrated by chlorine species that cause further acceleration of the corrosion rate by a mechanism called active oxidation. Active oxidation, cited as the cause of most biomass superheater corrosion under chloride ash deposits, does not occur in the absence of these alkali salts when the chloride is present as HCl gas. Although a deposit is more corrosive at temperatures where it is molten than at temperatures where it is frozen, increasing superheater tube temperatures through the measured first melting point of fly ash deposits does not necessarily produce a step increase in corrosion rate. Corrosion rate typically accelerates at temperatures below the first melting temperature and mixed deposits may have a broad melting temperature range. Although the environment at a superheater tube surface is initially that of the ash deposits, this chemistry typically changes as the deposits mature. The corrosion rate is controlled by the environment and temperature at the tube surface, which can only be measured indirectly. Some results are counter-intuitive. Two boiler manufacturers and a consortium have developed models to predict fouling and corrosion in biomass boilers in order to specify tube materials for particular operating conditions. It would be very useful to compare the predictions of these models regarding corrosion rates and recommended alloys in the boiler environments where field tests will be performed in the current program. Manufacturers of biomass boilers have concluded that it is more cost-effective to restrict steam temperatures, to co-fire biofuels with high sulfur fuels and/or to use fuel additives rather than try to increase fuel efficiency by operating with superheater tube temperatures above melting temperature of fly ash deposits. Similar strategies have been developed for coal fired and waste-fired boilers. Additives are primarily used to replace alkali metal chloride deposits with higher melting temperature and less corrosive alkali metal sulfate or alkali aluminum silicate deposits. Design modifications that have been shown to control superheater corrosion include adding a radiant pass (empty chamber) between the furnace and the superheater, installing cool tubes immediately upstream of the superheater to trap high chloride deposits, designing superheater banks for quick replacement, using an external superheater that burns a less corrosive biomass fuel, moving circulating fluidized bed (CFB) superheaters from the convective pass into the hot recirculated fluidizing medium and adding an insulating layer to superh

  19. OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS

    SciTech Connect (OSTI)

    Constance Senior

    2004-12-31T23:59:59.000Z

    The objectives of this program were to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel and to develop a greater understanding of mercury oxidation across SCR catalysts in the form of a simple model. The Electric Power Research Institute (EPRI) and Argillon GmbH provided co-funding for this program. REI used a multicatalyst slipstream reactor to determine oxidation of mercury across five commercial SCR catalysts at a power plant that burned a blend of 87% subbituminous coal and 13% bituminous coal. The chlorine content of the blend was 100 to 240 {micro}g/g on a dry basis. Mercury measurements were carried out when the catalysts were relatively new, corresponding to about 300 hours of operation and again after 2,200 hours of operation. NO{sub x}, O{sub 2} and gaseous mercury speciation at the inlet and at the outlet of each catalyst chamber were measured. In general, the catalysts all appeared capable of achieving about 90% NO{sub x} reduction at a space velocity of 3,000 hr{sup -1} when new, which is typical of full-scale installations; after 2,200 hours exposure to flue gas, some of the catalysts appeared to lose NO{sub x} activity. For the fresh commercial catalysts, oxidation of mercury was in the range of 25% to 65% at typical full-scale space velocities. A blank monolith showed no oxidation of mercury under any conditions. All catalysts showed higher mercury oxidation without ammonia, consistent with full-scale measurements. After exposure to flue gas for 2,200 hours, some of the catalysts showed reduced levels of mercury oxidation relative to the initial levels of oxidation. A model of Hg oxidation across SCRs was formulated based on full-scale data. The model took into account the effects of temperature, space velocity, catalyst type and HCl concentration in the flue gas.

  20. ENGINEERING DEVELOPMENT OF COAL-FIRED HIGH-PERFORMANCE POWER SYSTEMS

    SciTech Connect (OSTI)

    Unknown

    1999-02-01T23:59:59.000Z

    A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolysis process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately, and after each experimental program has been completed, a larger scale pyrolyzer will be tested at the Power Systems Development Facility (PSDF) in Wilsonville, AL. The facility is equipped with a gas turbine and a topping combustor, and as such, will provide an opportunity to evaluate integrated pyrolyzer and turbine operation. This report addresses the areas of technical progress for this quarter. A general arrangement drawing of the char transfer system was forwarded to SCS for their review. Structural steel drawings were used to generate a three-dimensional model of the char transfer system including all pressure vessels and major piping components. Experimental testing at the Combustion and Environmental Test Facility continued during this quarter. Performance of the char burner, as benchmarked by flame stability and low NOx, has been exceptional. The burner was operated successfully both without natural gas and supplemental pulverized coal.

  1. The ADESORB Process for Economical Production of Sorbents for Mercury Removal from Coal Fired Power Plants

    SciTech Connect (OSTI)

    Robin Stewart

    2008-03-12T23:59:59.000Z

    The DOE's National Energy Technology Laboratory (NETL) currently manages the largest research program in the country for controlling coal-based mercury emissions. NETL has shown through various field test programs that the determination of cost-effective mercury control strategies is complex and highly coal- and plant-specific. However, one particular technology has the potential for widespread application: the injection of activated carbon upstream of either an electrostatic precipitator (ESP) or a fabric filter baghouse. This technology has potential application to the control of mercury emissions on all coal-fired power plants, even those with wet and dry scrubbers. This is a low capital cost technology in which the largest cost element is the cost of sorbents. Therefore, the obvious solutions for reducing the costs of mercury control must focus on either reducing the amount of sorbent needed or decreasing the cost of sorbent production. NETL has researched the economics and performance of novel sorbents and determined that there are alternatives to the commercial standard (NORIT DARCO{reg_sign} Hg) and that this is an area where significant technical improvements can still be made. In addition, a key barrier to the application of sorbent injection technology to the power industry is the availability of activated carbon production. Currently, about 450 million pounds ($250 million per year) of activated carbon is produced and used in the U.S. each year - primarily for purification of drinking water, food, and beverages. If activated carbon technology were to be applied to all 1,100 power plants, EPA and DOE estimate that it would require an additional $1-$2 billion per year, which would require increasing current capacity by a factor of two to eight. A new facility to produce activated carbon would cost approximately $250 million, would increase current U.S. production by nearly 25%, and could take four to five years to build. This means that there could be significant shortages in supply if response to new demand is not well-timed.

  2. Characterization of open-cycle coal-fired MHD generators. 16th quarterly technical progress report, December 16, 1980-March 31, 1981

    SciTech Connect (OSTI)

    Wormhoudt, J.; Yousefian, V.; Weinberg, M.; Kolb, C.; Martinez-Sanchez, M.; Cheng, W.; Dvore, D.; Freedman, A.; Stanton, A.; Stewart, G.

    1981-05-01T23:59:59.000Z

    The successful design of full-scale, open-cycle, coal-fired MHD generators for baseload electrical production requires a detailed understanding of the plasma chemical and plasma dynamic characteristics of anticipated combustor and channel fluids. Progress in efforts to model the efficiency of an open-cycle, coal-fired MHD channel based on the characterization of the channel flow as well as laboratory experiments to validate the modeling effort is reported. In addition, studies related to understanding arcing and corrosion phenomena in the vicinity of an anode are reported.

  3. Near-term implications of a ban on new coal-fired power plants in the United States

    SciTech Connect (OSTI)

    Adam Newcomer; Jay Apt [Carnegie Mellon University, Pittsburgh, PA (United States). Carnegie Mellon Electricity Industry Center

    2009-06-15T23:59:59.000Z

    Large numbers of proposed new coal power generators in the United States have been cancelled, and some states have prohibited new coal power generators. We examine the effects on the U.S. electric power system of banning the construction of coal-fired electricity generators, which has been proposed as a means to reduce U.S. CO{sub 2} emissions. The model simulates load growth, resource planning, and economic dispatch of the Midwest Independent Transmission System Operator (ISO), Inc., Electric Reliability Council of Texas (ERCOT), and PJM under a ban on new coal generation and uses an economic dispatch model to calculate the resulting changes in dispatch order, CO{sub 2} emissions, and fuel use under three near-term (until 2030) future electric power sector scenarios. A national ban on new coal-fired power plants does not lead to CO{sub 2} reductions of the scale required under proposed federal legislation such as Lieberman-Warner but would greatly increase the fraction of time when natural gas sets the price of electricity, even with aggressive wind and demand response policies. 50 refs., 5 figs., 4 tabs.

  4. Sustainability Assessment of Coal-Fired Power Plants with Carbon Capture and Storage

    SciTech Connect (OSTI)

    Widder, Sarah H.; Butner, R. Scott; Elliott, Michael L.; Freeman, Charles J.

    2011-11-30T23:59:59.000Z

    Carbon capture and sequestration (CCS) has the ability to dramatically reduce carbon dioxide (CO2) emissions from power production. Most studies find the potential for 70 to 80 percent reductions in CO2 emissions on a life-cycle basis, depending on the technology. Because of this potential, utilities and policymakers are considering the wide-spread implementation of CCS technology on new and existing coal plants to dramatically curb greenhouse gas (GHG) emissions from the power generation sector. However, the implementation of CCS systems will have many other social, economic, and environmental impacts beyond curbing GHG emissions that must be considered to achieve sustainable energy generation. For example, emissions of nitrogen oxides (NOx), sulfur oxides (SOx), and particulate matter (PM) are also important environmental concerns for coal-fired power plants. For example, several studies have shown that eutrophication is expected to double and acidification would increase due to increases in NOx emissions for a coal plant with CCS provided by monoethanolamine (MEA) scrubbing. Potential for human health risks is also expected to increase due to increased heavy metals in water from increased coal mining and MEA hazardous waste, although there is currently not enough information to relate this potential to actual realized health impacts. In addition to environmental and human health impacts, supply chain impacts and other social, economic, or strategic impacts will be important to consider. A thorough review of the literature for life-cycle analyses of power generation processes using CCS technology via the MEA absorption process, and other energy generation technologies as applicable, yielded large variability in methods and core metrics. Nonetheless, a few key areas of impact for CCS were developed from the studies that we reviewed. These are: the impact of MEA generation on increased eutrophication and acidification from ammonia emissions and increased toxicity from MEA production and the impact of increased coal use including the increased generation of NOx from combustion and transportation, impacts of increased mining of coal and limestone, and the disposal of toxic fly ash and boiler ash waste streams. Overall, the implementing CCS technology could contribute to a dramatic decrease in global GHG emissions, while most other environmental and human health impact categories increase only slightly on a global scale. However, the impacts on human toxicity and ecotoxicity have not been studied as extensively and could have more severe impacts on a regional or local scale. More research is needed to draw strong conclusions with respect to the specific relative impact of different CCS technologies. Specifically, a more robust data set that disaggregates data in terms of component processes and treats a more comprehensive set of environmental impacts categories from a life-cycle perspective is needed. In addition, the current LCA framework lacks the required temporal and spatial scales to determine the risk of environmental impact from carbon sequestration. Appropriate factors to use when assessing the risk of water acidification (groundwater/oceans/aquifers depending on sequestration site), risk of increased human toxicity impact from large accidental releases from pipeline or wells, and the legal and public policy risk associated with licensing CO2 sequestration sites are also not currently addressed. In addition to identifying potential environmental, social, or risk-related issues that could impede the large-scale deployment of CCS, performing LCA-based studies on energy generation technologies can suggest places to focus our efforts to achieve technically feasible, economically viable, and environmentally conscious energy generation technologies for maximum impact.

  5. MINIMIZATION OF NO EMISSIONS FROM MULTI-BURNER COAL-FIRED BOILERS

    SciTech Connect (OSTI)

    E.G. Eddings; A. Molina; D.W. Pershing; A.F. Sarofim; T.H. Fletcher; H. Zhang; K.A. Davis; M. Denison; H. Shim

    2002-01-01T23:59:59.000Z

    The focus of this program is to provide insight into the formation and minimization of NO{sub x} in multi-burner arrays, such as those that would be found in a typical utility boiler. Most detailed studies are performed in single-burner test facilities, and may not capture significant burner-to-burner interactions that could influence NO{sub x} emissions. Thus, investigations of such interactions were made by performing a combination of single and multiple burner experiments in a pilot-scale coal-fired test facility at the University of Utah, and by the use of computational combustion simulations to evaluate full-scale utility boilers. In addition, fundamental studies on nitrogen release from coal were performed to develop greater understanding of the physical processes that control NO formation in pulverized coal flames--particularly under low NO{sub x} conditions. A CO/H{sub 2}/O{sub 2}/N{sub 2} flame was operated under fuel-rich conditions in a flat flame reactor to provide a high temperature, oxygen-free post-flame environment to study secondary reactions of coal volatiles. Effects of temperature, residence time and coal rank on nitrogen evolution and soot formation were examined. Elemental compositions of the char, tar and soot were determined by elemental analysis, gas species distributions were determined using FTIR, and the chemical structure of the tar and soot was analyzed by solid-state {sup 13}C NMR spectroscopy. A laminar flow drop tube furnace was used to study char nitrogen conversion to NO. The experimental evidence and simulation results indicated that some of the nitrogen present in the char is converted to nitric oxide after direct attack of oxygen on the particle, while another portion of the nitrogen, present in more labile functionalities, is released as HCN and further reacts in the bulk gas. The reaction of HCN with NO in the bulk gas has a strong influence on the overall conversion of char-nitrogen to nitric oxide; therefore, any model that aims to predict the conversion of char-nitrogen to nitric oxide should allow for the conversion of char-nitrogen to HCN. The extent of the HCN conversion to NO or N{sub 2} will depend on the composition of the atmosphere surrounding the particle. A pilot-scale testing campaign was carried out to evaluate the impact of multiburner firing on NO{sub x} emissions using a three-burner vertical array. In general, the results indicated that multiburner firing yielded higher NO{sub x} emissions than single burner firing at the same fuel rate and excess air. Mismatched burner operation, due to increases in the firing rate of the middle burner, generally demonstrated an increase in NO{sub x} over uniform firing. Biased firing, operating the middle burner fuel rich with the upper and lower burners fuel lean, demonstrated an overall reduction in NO{sub x} emissions; particularly when the middle burner was operated highly fuel rich. Computational modeling indicated that operating the three burner array with the center burner swirl in a direction opposite to the other two resulted in a slight reduction in NO{sub x}.

  6. Proceedings of the joint contractors meeting: FE/EE Advanced Turbine Systems conference FE fuel cells and coal-fired heat engines conference

    SciTech Connect (OSTI)

    Geiling, D.W. [ed.

    1993-08-01T23:59:59.000Z

    The joint contractors meeting: FE/EE Advanced Turbine Systems conference FEE fuel cells and coal-fired heat engines conference; was sponsored by the US Department of Energy Office of Fossil Energy and held at the Morgantown Energy Technology Center, P.O. Box 880, Morgantown, West Virginia 26507-0880, August 3--5, 1993. Individual papers have been entered separately.

  7. Engineering development of coal-fired high performance power systems, Phase II and Phase III. Quarter progress report, April 1, 1996--June 30, 1996

    SciTech Connect (OSTI)

    NONE

    1996-11-01T23:59:59.000Z

    Work is presented on the development of a coal-fired high performance power generation system by the year 2000. This report describes the design of the air heater, duct heater, system controls, slag viscosity, and design of a quench zone.

  8. Design study of a coal-fired thermionic (THX) topped power plant. Volume IV. Thermionic heat exchanger design and costing

    SciTech Connect (OSTI)

    Dick, R.S.; Britt, E.J.

    1980-10-15T23:59:59.000Z

    This volume deals with the details of how thermionic conversion works, and how it is used in a coal-fired furnace to achieve power plant efficiencies of 45%, and overall costs of 36.3 mills/kWh. A review of the fundamental technical aspects of thermionic conversion is given. The overall Thermionic Heat Exchanger (THX) design, the heat pipe design, and the interaction of the heat pipes with the furnace are presented. Also, the operational characteristics of thermionic converters are described. Details on the computer program used to perform the parametric study are given. The overall program flow is reviewed along with the specifics of how the THX subroutine designed the converter to match the conditions imposed. Also, input costs and variables effecting the THX's performance are detailed. The efficiencies of the various power plants studied are given as a function of the air preheat temperature, size of the power plant, and thermionic level of performance.

  9. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment

    SciTech Connect (OSTI)

    Rosner, D.E.

    1990-05-01T23:59:59.000Z

    The overall goal of this research in the area of ash transport was to advance the capability of making reliable engineering predictions of the dynamics and consequences of net deposit growth for surfaces exposed to the products of coal combustion. To accomplish this for a wide variety of combustor types, coal types, and operating conditions, this capability must be based on a quantitative understanding of each of the important mechanisms of mineral matter transport, as well as the nature of the interactions between these substances and the prevailing fireside'' surface of the deposit. This level of understanding and predictive capability could ultimately be translated into very significant cost reductions for coal-fired equipment design, development and operation.

  10. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01T23:59:59.000Z

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  11. [Engineering development of advanced coal-fired low-emission boiler systems]. Technical progress report, October--December 1995

    SciTech Connect (OSTI)

    Wesnor, J.D.; Bakke, E. [ABB Environmental Systems, Birmingham, AL (United States); Bender, D.J.; Kaminski, R.S. [Raytheon Engineers and Constructors, Inc., Philadelphia, PA (United States)

    1995-12-31T23:59:59.000Z

    The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emisssion boiler systems. The primary objectives are: NO{sub x} emissions, lb/million Btu; SO{sub 2} emissions, lb/million Btu; particulate emissions, lb/million Btu; and net plant efficiency, not less than 42%. The secondary objectives are: improved ash disposability; reduced waste generation; and reduced air toxics emissions. Accomplishments to date are summarized for the following tasks: task 1, project planning and management; task 7, component development and optimization; task 8, preliminary POC test facility design; task 9, subsystem test design and plan; task 10, subsystem test unit construction; and task 11, subsystem test operation and evaluation.

  12. Radiological Impact Associated to Technologically Enhanced Naturally Occurring Radioactive Materials (TENORM) from Coal-Fired Power Plants Emissions - 13436

    SciTech Connect (OSTI)

    Dinis, Maria de Lurdes; Fiuza, Antonio; Soeiro de Carvalho, Jose; Gois, Joaquim [Geo-Environment and Resources Research Centre (CIGAR), Porto University, Faculty of Engineering - FEUP, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal)] [Geo-Environment and Resources Research Centre (CIGAR), Porto University, Faculty of Engineering - FEUP, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); Meira Castro, Ana Cristina [School of Engineering Polytechnic of Porto - ISEP, Rua Dr. Antonio Bernardino de Almeida, 431, 4200-072, Porto (Portugal)] [School of Engineering Polytechnic of Porto - ISEP, Rua Dr. Antonio Bernardino de Almeida, 431, 4200-072, Porto (Portugal)

    2013-07-01T23:59:59.000Z

    Certain materials used and produced in a wide range of non-nuclear industries contain enhanced activity concentrations of natural radionuclides. In particular, electricity production from coal is one of the major sources of increased human exposure to naturally occurring radioactive materials. A methodology was developed to assess the radiological impact due to natural radiation background. The developed research was applied to a specific case study, the Sines coal-fired power plant, located in the southwest coastline of Portugal. Gamma radiation measurements were carried out with two different instruments: a sodium iodide scintillation detector counter (SPP2 NF, Saphymo) and a gamma ray spectrometer with energy discrimination (Falcon 5000, Canberra). Two circular survey areas were defined within 20 km of the power plant. Forty relevant measurements points were established within the sampling area: 15 urban and 25 suburban locations. Additionally, ten more measurements points were defined, mostly at the 20-km area. The registered gamma radiation varies from 20 to 98.33 counts per seconds (c.p.s.) corresponding to an external gamma exposure rate variable between 87.70 and 431.19 nGy/h. The highest values were measured at locations near the power plant and those located in an area within the 6 and 20 km from the stacks. In situ gamma radiation measurements with energy discrimination identified natural emitting nuclides as well as their decay products (Pb-212, Pb-2142, Ra-226, Th-232, Ac-228, Th-234, Pa-234, U- 235, etc.). According to the results, an influence from the stacks emissions has been identified both qualitatively and quantitatively. The developed methodology accomplished the lack of data in what concerns to radiation rate in the vicinity of Sines coal-fired power plant and consequently the resulting exposure to the nearby population. (authors)

  13. Coal-fired high performance power generating system. Quarterly progress report, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    NONE

    1995-08-01T23:59:59.000Z

    This report covers work carried out under Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, {open_quotes}Engineering Development of a Coal-Fired High Performance Power Generation System{close_quotes} between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of (1) > 47% thermal efficiency; (2) NO{sub x}, SO{sub x} and particulates {<=}25% NSPS; (3) cost {>=}65% of heat input; (4) all solid wastes benign. In our design consideration, we have tried to render all waste streams benign and if possible convert them to a commercial product. It appears that vitrified slag has commercial values. If the flyash is reinjected through the furnace, along with the dry bottom ash, then the amount of the less valuable solid waste stream (ash) can be minimized. A limitation on this procedure arises if it results in the buildup of toxic metal concentrations in either the slag, the flyash or other APCD components. We have assembled analytical tools to describe the progress of specific toxic metals in our system. The outline of the analytical procedure is presented in the first section of this report. The strengths and corrosion resistance of five candidate refractories have been studied in this quarter. Some of the results are presented and compared for selected preparation conditions (mixing, drying time and drying temperatures). A 100 hour pilot-scale stagging combustor test of the prototype radiant panel is being planned. Several potential refractory brick materials are under review and five will be selected for the first 100 hour test. The design of the prototype panel is presented along with some of the test requirements.

  14. The effects of moisture and particle size of feedlot biomass on co-firing burner performance 

    E-Print Network [OSTI]

    Chen, Chen-Jung

    2001-01-01T23:59:59.000Z

    increased from 350 ppm to 650 ppm while CO decreased from 46,000 ppm to 18,000 ppm (data measured at the first probe, 6" from the burner). The external water injection used to simulate high moisture FB decreased the pollutant emissions (NO[]) from 570 ppm...

  15. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Srinivasachar, Srivats; Laudal, Daniel; Browers, Bruce

    2014-12-31T23:59:59.000Z

    A novel hybrid solid sorbent technology for CO2 capture and separation from coal combustion-derived flue gas was evaluated. The technology – Capture of CO2 by Hybrid Sorption (CACHYS™) – is a solid sorbent technology based on the following ideas: 1) reduction of energy for sorbent regeneration, 2) utilization of novel process chemistry, 3) contactor conditions that minimize sorbent-CO2 heat of reaction and promote fast CO2 capture, and 4) low-cost method of heat management. This report provides key information developed during the course of the project that includes sorbent performance, energy for sorbent regeneration, physical properties of the sorbent, the integration of process components, sizing of equipment, and overall capital and operational cost of the integrated CACHYS™ system. Seven sorbent formulations were prepared and evaluated at the lab-scale for energy requirements and CO2 capture performance. Sorbent heat of regeneration ranged from 30-80 kJ/mol CO2 and was found to be dependent on process conditions. Two sorbent formulations (designated HCK-4 & HCK-7) were down-selected for additional fixed-bed testing. Additional testing involved subjecting the sorbents to 100 continuous cycles in the fixed-bed reactor to determine performance as a function of time. The working capacity achieved for HCK-4 sorbent ranged from 5.5-8.0 g CO2/100 g sorbent, while the HCK-7 typically ranged from 8.0-10.0 g CO2/100 g sorbent. Overall, there was no deterioration in capacity with continuous cycling for either sorbent. The CACHYS™ bench-scale testing system designed and fabricated under this award consists of a dual circulating fluidized-bed adsorber and a moving-bed regenerator. The system takes a flue gas slipstream from the University of North Dakota’s coal-fired steam plant. Prior to being sent to the adsorber, the flue gas is scrubbed to remove SO2 and particulate. During parametric testing of the adsorber, CO2 capture achieved using the 2-bed configuration with recirculation in both beds was 65-70% with a high flue gas CO2 loading (~7%) and up to 85% with a low flue gas CO2 loading (~4%). A sorbent regenerator system consisting of a pre-heater, desorber, and cooler is used to heat the CO2-rich sorbent with direct and indirect steam producing a nearly 100% pure stream of CO2. Parametric testing of the regenerator system demonstrated the impact of process conditions on both desorption rate and the heat of regeneration. Clear evidence of the use of specific process conditions that lower the overall energy of desorption was identified. This observation validates measurements made at the laboratory-scale. Several longer-term continuous tests were conducted to evaluate the performance of the sorbent/process as a function of time. Using a 2-bed configuration, sustained capture efficiency of 40-60% with a high flue gas CO2 loading (~8%) and 70-80% with a low flue gas CO2 loading (~4%) were achieved. However, sorbent working capacity was found to be considerably lower than laboratory-scale measurements. The low working capacity is attributed to insufficient sorbent/gas contact time in the adsorber. Sorbent properties that had a significant impact on CO2 capture performance were identified. The results show that controlling these sorbent properties substantially improves CO2 capture performance, with preliminary estimates indicating that relative improvement of ~30% is possible. Testing culminated with an operationally trouble-free test of 15 hours with sustainable performance. Overall, several practical strategies to increase performance of the sorbent and process were identified. The initial technical and economic assessment of the CACHYS™ process estimated the cost of CO2 capture was $36.19/ton with a 48.6% increase in levelized cost of electricity (LCOE) for the 550 MWe net plant. Using additional data gathered over the course of the project, and with revised technical and economic assumptions, the estimated cost of CO2 capture with the CACHYS™ process is $39/ton (only includes the cost of the CO2 capture system

  16. Coal-firing sulfur coal with refuse derived fuels. Technical progress report {number_sign}7, [April--June 1996

    SciTech Connect (OSTI)

    Pan, Wei-Ping, Riley, J.T.; Lloyd, W.G.

    1996-05-31T23:59:59.000Z

    The objectives for this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the organic compounds tentatively identified as combustion products in the previous report were confirmed by comparing retention times with pure samples. Secondly, a reduced amount of unburned carbon in the fly ash and an oxygen concentration at about 3--6% in the flue gases were achieved by the addition of removable heat exchange tubes in the AFBC system.

  17. Evaluation of BOC'S Lotox Process for the Oxidation of Elemental Mercury in Flue Gas from a Coal-Fired Boiler

    SciTech Connect (OSTI)

    Khalid Omar

    2008-04-30T23:59:59.000Z

    Linde's Low Temperature Oxidation (LoTOx{trademark}) process has been demonstrated successfully to remove more than 90% of the NOx emitted from coal-fired boilers. Preliminary findings have shown that the LoTOx{trademark} process can be as effective for mercury emissions control as well. In the LoTOx{trademark} system, ozone is injected into a reaction duct, where NO and NO{sub 2} in the flue gas are selectively oxidized at relatively low temperatures and converted to higher nitrogen oxides, which are highly water soluble. Elemental mercury in the flue gas also reacts with ozone to form oxidized mercury, which unlike elemental mercury is water-soluble. Nitrogen oxides and oxidized mercury in the reaction duct and residual ozone, if any, are effectively removed in a wet scrubber. Thus, LoTOx{trademark} appears to be a viable technology for multi-pollutant emission control. To prove the feasibility of mercury oxidation with ozone in support of marketing LoTOx{trademark} for multi-pollutant emission control, Linde has performed a series of bench-scale tests with simulated flue gas streams. However, in order to enable Linde to evaluate the performance of the process with a flue gas stream that is more representative of a coal-fired boiler; one of Linde's bench-scale LoTOx{trademark} units was installed at WRI's combustion test facility (CTF), where a slipstream of flue gas from the CTF was treated. The degree of mercury and NOx oxidation taking place in the LoTOx{trademark} unit was quantified as a function of ozone injection rates, reactor temperatures, residence time, and ranks of coals. The overall conclusions from these tests are: (1) over 80% reduction in elemental mercury and over 90% reduction of NOx can be achieved with an O{sub 3}/NO{sub X} molar ratio of less than two, (2) in most of the cases, a lower reactor temperature is preferred over a higher temperature due to ozone dissociation, however, the combination of both low residence time and high temperature proved to be effective in the oxidation of both NOx and elemental mercury, and (3) higher residence time, lower temperature, and higher molar ratio of O{sub 3}/NOx contributed to the highest elemental mercury and NOx reductions.

  18. Thermal Integration of CO{sub 2} Compression Processes with Coal-Fired Power Plants Equipped with Carbon Capture

    SciTech Connect (OSTI)

    Edward Levy

    2012-06-29T23:59:59.000Z

    Coal-fired power plants, equipped either with oxycombustion or post-combustion CO{sub 2} capture, will require a CO{sub 2} compression system to increase the pressure of the CO{sub 2} to the level needed for sequestration. Most analyses show that CO{sub 2} compression will have a significant effect on parasitic load, will be a major capital cost, and will contribute significantly to reduced unit efficiency. This project used first principle engineering analyses and computer simulations to determine the effects of utilizing compressor waste heat to improve power plant efficiency and increase net power output of coal-fired power plants with carbon capture. This was done for units with post combustion solvent-based CO{sub 2} capture systems and for oxyfired power plants, firing bituminous, PRB and lignite coals. The thermal integration opportunities analyzed for oxycombustion capture are use of compressor waste heat to reheat recirculated flue gas, preheat boiler feedwater and predry high-moisture coals prior to pulverizing the coal. Among the thermal integration opportunities analyzed for post combustion capture systems are use of compressor waste heat and heat recovered from the stripper condenser to regenerate post-combustion CO{sub 2} capture solvent, preheat boiler feedwater and predry high-moisture coals. The overall conclusion from the oxyfuel simulations is that thermal integration of compressor heat has the potential to improve net unit heat rate by up to 8.4 percent, but the actual magnitude of the improvement will depend on the type of heat sink used and to a lesser extent, compressor design and coal rank. The simulations of a unit with a MEA post combustion capture system showed that thermal integration of either compressor heat or stripper condenser heat to preheat boiler feedwater would result in heat rate improvements from 1.20 percent to 4.19 percent. The MEA capture simulations further showed that partial drying of low rank coals, done in combination with feedwater heating, would result in heat rate reductions of 7.43 percent for PRB coal and 10.45 percent for lignite.

  19. Engineering development of advanced coal-fired low-emission boiler systems. Quarterly technical progress report, January 1--March 31, 1994

    SciTech Connect (OSTI)

    Not Available

    1994-04-28T23:59:59.000Z

    This project is concerned with the development of an a coal-fired low-emission boiler system. During march, separate kick-off meetings were held with PSI Powerserve, Raytheon and B&W`s Environmental Equipment Division to begin work on Phase I Task 5, the Commercial Plant Design. In addition, a meeting was held with MIT to discuss and review work completed and schedule work remaining on the project.

  20. JV 58-Effects of Biomass Combustion on SCR Catalyst

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Christopher J. Zygarlicke; Joshua R. Strege; Donald P. McCollor; Jason D. Laumb; Lingbu Kong

    2006-08-31T23:59:59.000Z

    A portable slipstream selective catalytic reduction (SCR) reactor was installed at a biomass cofired utility boiler to examine the rates and mechanisms of catalyst deactivation when exposed to biomass combustion products. The catalyst was found to deactivate at a much faster rate than typically found in a coal-fired boiler, although this may have been the result of high ash loading rather than a general property of biomass combustion. Deactivation was mainly the result of alkali and alkaline-earth sulfate formation and growth in catalyst pores, apparently caused by alkaline-earth ash deposition on or near the pore sites. The high proportion of biomass in the fuel contributed to elevated levels of alkali and alkaline-earth material in the ash when compared to coal ash, and these higher levels provided more opportunity for sulfate formation. Based on laboratory tests, neither catalyst material nor ammonia contributed measurably to ash mass gains via sulfation. A model constructed using both field and laboratory data was able to predict catalyst deactivation of catalysts under subbituminous coal firing but performed poorly at predicting catalyst deactivation under cofiring conditions. Because of the typically higher-than coal levels of alkali and alkaline-earth elements present in biomass fuels that are available for sulfation at typical SCR temperatures, the use of SCR technology and biomass cofiring needs to be carefully evaluated prior to implementation.

  1. Engineering development of advanced coal-fired low-emissions boiler system. Phase II subsystem test design and plan - an addendum to the Phase II RD & T Plan

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    Shortly after the year 2000 it is expected that new generating plants will be needed to meet the growing demand for electricity and to replace the aging plants that are nearing the end of their useful service life. The plants of the future will need to be extremely clean, highly efficient and economical. Continuing concerns over acid rain, air toxics, global climate changes, ozone depletion and solid waste disposal are expected to further then regulations. In the late 1980`s it was commonly believed that coal-fired power plants of the future would incorporate either some form of Integrated Gasification Combined Cycle (IGCC) or first generation Pressurized Fluidized Bed Combustion (PFBS) technologies. However, recent advances In emission control techniques at reduced costs and auxiliary power requirements coupled with significant improvements In steam turbine and cycle design have clearly indicated that pulverized coal technology can continue to be competitive In both cost and performance. In recognition of the competitive potential for advanced pulverized coal-fired systems with other emerging advanced coal-fired technologies, DOE`s Pittsburgh Energy Technology Center (PETC) began a research and development initiative In late 1990 named, Combustion 2000, with the intention of preserving and expanding coal as a principal fuel In the Generation of electrical power. The project was designed for two stages of commercialization, the nearer-term Low Emission Boiler System (LEBS) program, and for the future, the High Performance Power System (HIPPS) program. B&W is participating In the LEBS program.

  2. Eliminating air heater plugging and corrosion caused by SCR/SNCR systems for NOx control on coal-fired boilers

    SciTech Connect (OSTI)

    Guffre, J. [Paragon Airheater Technologies (United States)

    2007-10-15T23:59:59.000Z

    In a typical coal-fired power plant the rotary regenerative air heater is responsible for 5-10% of the boiler's total efficiency. The three biggest threats to air heater performance deterioration are corrosion of the heat exchange surfaces, plugging, and air heater leakage through the seals. The article concentrates on the vastly increased level of corrosion and plugging issues associated with installing selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR) systems for controlling nitrogen oxide emissions. Some injected ammonia in the SCR process reacts with SO{sub 2} to form ammonium sulphate and bisulphate (ABS) which is deposited on the air heater element surfaces. This can be overcome by applying coatings, using corrosion-resistant steels, reconfiguring the air heaters to a two layer design, improving air heater blowers, improving technologies for removing ammonia 'slip' before it enters the air heater, and using new catalysts that reduce the oxidation of SO{sub 2} to SO{sub 3}. 4 figs.

  3. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    Kenneth E. Baldrey

    2001-09-01T23:59:59.000Z

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

  4. Development of a coal fired pulse combustor for residential space heating. Technical progress report, July--September 1987

    SciTech Connect (OSTI)

    NONE

    1987-12-31T23:59:59.000Z

    The systematic development of the residential combustion system is divided into three phases. Only Phase I is detailed here. Phase I constitutes the design, fabrication, testing, and evaluation of a pulse combustor sized for residential space heating. Phase II is an optional phase to develop an integrated system including a heat exchanger. Phase III is projected as a field test of the integrated coal-fired residential space heater. The Phase I effort was nearing completion during this reporting period and a final report is in preparation. The configuration testing was completed early in the period and based upon results of the configuration tests, an optimized configuration for the experimental development testing was chosen. The refractory-lined chambers were fabricated and tested from mid-September through early October. The tandem unit was operated on dry micromized coal without support gas or excitation air for periods lasting from one to three hours. Performance was stable and turndown ratios of 3:1 were achieved during the first three-hour test. A early commercial residential heating system configuration has been identified on the basis of the development testing conducted throughout the first phase of this effort. The development effort indicates that the residential unit goals are achievable with some additional product improvement effort to increase carbon burn-out efficiency, reduce CO emissions and develop a reliable and compact dry, ultrafine coal feed system (not included in the present effort).

  5. Low Cost Sorbent for Capturing CO{sub 2} Emissions Generated by Existing Coal-fired Power Plants

    SciTech Connect (OSTI)

    Elliott, Jeannine

    2013-08-31T23:59:59.000Z

    TDA Research, Inc. has developed a novel sorbent based post-combustion CO{sub 2} removal technology. This low cost sorbent can be regenerated with low-pressure (ca. 1 atm) superheated steam without temperature swing or pressure-swing. The isothermal and isobaric operation is a unique and advantageous feature of this process. The objective of this project was to demonstrate the technical and economic merit of this sorbent based CO{sub 2} capture approach. Through laboratory, bench-scale and field testing we demonstrated that this technology can effectively and efficiently capture CO{sub 2} produced at an existing pulverized coal power plants. TDA Research, Inc is developing both the solid sorbent and the process designed around that material. This project addresses the DOE Program Goal to develop a capture technology that can be added to an existing or new coal fired power plant, and can capture 90% of the CO{sub 2} produced with the lowest possible increase in the cost of energy. .

  6. Full operating range robust hybrid control of a coal-fired boiler/turbine unit - article no. 041011

    SciTech Connect (OSTI)

    Zheng, K.; Bentsman, J.; Taft, C.W. [University of Illinois, Urbana, IL (United States). Dept. for Engineering Science & Mechanics

    2008-07-15T23:59:59.000Z

    Multi-input-multi-output robust controllers recently designed for the megawatt output/throttle pressure control in a coal-fired power plant boiler/turbine unit have demonstrated performance robustness noticeably superior to that of the currently employed nonlinear PID-based controller. These controllers, however, have been designed only for the range of 150-185 MW around the 185 MW nominal operating point, exhibiting a significant loss of performance in the lower range of 120-150 MW. Through system identification, the reason for this performance loss is demonstrated in the current work to be a pronounced dependence of the boiler/turbine unit steady state gains on the operating point. This problem is addressed via a hybrid control law consisting of two robust controllers and a robust switch between them activated by the set point change. The controllers are designed to cover the corresponding half-ranges of the full operating range. This permits attainment of the desired overall performance as well as reduction of modeling uncertainty induced by the operating point change to approximately 25% of that associated with the previous designs. Robust switching is accomplished through a novel hybrid mode of behavior-robustly controlled discrete transition.

  7. Advanced intelligent coordinated control of coal fired power plant based on fuzzy reasoning and auto-tuning

    SciTech Connect (OSTI)

    Li, S.Y.; Liu, H.B.; Cai, W.J.; Soh, Y.C.; Xie, L.H. [Shanghai Jiao Tong University, Shanghai (China)

    2004-07-01T23:59:59.000Z

    The load following operation of coal-fired boiler-turbine unit in power plants can lead to changes in operating points, and it results in nonlinear variations of the plant variables and parameters. As there exist strong couplings between the main steam pressure control loop and the power output control loop in the boiler-turbine unit with large time-delay and uncertainties, automatic coordinated control of the two loops is a very challenging problem. This paper presents a new coordinated control strategy (CCS) which is organized into two levels: a basic control level and a high supervision level. PID-type controllers are used in the basic level to perform basic control functions while the decoupling between two control loops can be realized in the high level. Moreover, PID-type controllers can be auto-tuned to achieve a better control performance in the whole operating range and to reject the unmeasurable disturbances. A special subclass of fuzzy inference systems, namely the Gaussian partition system with evenly spaced midpoints, is also proposed to auto-tune the PID controller in the main steam pressure loop based on the error signal and its first difference to overcome uncertainties caused by changing fuel calorific value, machine wear, contamination of the boiler heating surfaces and plant modeling errors, etc. The developed CCS has been implemented in a power plant in China, and satisfactory industrial operation results demonstrate that the proposed control strategy has enhanced the adaptability and robustness of the process.

  8. Assessment of energy and economic impacts of particulate-control technologies in coal-fired power generation

    SciTech Connect (OSTI)

    Not Available

    1980-04-01T23:59:59.000Z

    Under contract to Argonne National Laboratory, Midwest Research Institute has derived models to assess the economic and energy impacts of particulate-control systems for coal-fired power plants. The models take into account the major functional variables, including plant size and location, coal type, and applicable particulate-emission standards. The algorithms obtained predict equipment and installation costs, as well as operating costs (including energy usage), for five control devices: (1) cold-side electrostatic precipitators, (2) hot-side electrostatic precipitators, (3) reverse-flow baghouses, (4) shake baghouses, and (5) wet scrubbers. A steam-generator performance model has been developed, and the output from this model has been used as input for the control-device performance models that specify required design and operating parameters for the control systems under study. These parameters then have been used as inputs to the cost models. Suitable guideline values have been provided for independent variables wherever necessary, and three case studies are presented to demonstrate application of the subject models. The control-equipment models aggregate the following cost items: (1) first costs (capital investment), (2) total, first-year annualized costs, and (3) integrated cost of ownership and operation over any selected plant lifetime. Although the models have been programmed for rapid computation, the algorithms can be solved with a hand calculator.

  9. Alstom's Chemical Looping Combustion Prototype for CO{sub 2} Capture from Existing Pulverized Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Andrus, Herbert; Chiu, John; Edberg, Carl; Thibeault, Paul; Turek, David

    2012-09-30T23:59:59.000Z

    Alstom’s Limestone Chemical Looping (LCL™) process has the potential to capture CO{sub 2} from new and existing coal-fired power plants while maintaining high plant power generation efficiency. This new power plant concept is based on a hybrid combustion- gasification process utilizing high temperature chemical and thermal looping technology. This process could also be potentially configured as a hybrid combustion-gasification process producing a syngas or hydrogen for various applications while also producing a separate stream of CO{sub 2} for use or sequestration. The targets set for this technology is to capture over 90% of the total carbon in the coal at cost of electricity which is less than 20% greater than Conventional PC or CFB units. Previous work with bench scale test and a 65 kWt Process Development Unit Development (PDU) has validated the chemistry required for the chemical looping process and provided for the investigation of the solids transport mechanisms and design requirements. The objective of this project is to continue development of the combustion option of chemical looping (LCL-C™) by designing, building and testing a 3 MWt prototype facility. The prototype includes all of the equipment that is required to operate the chemical looping plant in a fully integrated manner with all major systems in service. Data from the design, construction, and testing will be used to characterize environmental performance, identify and address technical risks, reassess commercial plant economics, and develop design information for a demonstration plant planned to follow the proposed Prototype. A cold flow model of the prototype will be used to predict operating conditions for the prototype and help in operator training. Operation of the prototype will provide operator experience with this new technology and performance data of the LCL-C™ process, which will be applied to the commercial design and economics and plan for a future demonstration plant.

  10. Mercury speciation in coal-fired power plant plumes observed at three surface sites in the southeastern U.S.

    SciTech Connect (OSTI)

    Eric S. Edgerton; Benjamin E. Hartsell; John J. Jansen [Atmospheric Research & Analysis, Inc., Cary, NC (United States)

    2006-08-01T23:59:59.000Z

    Elemental Hg (Hg{sup 0}), reactive gaseous Hg (RGM) and fine particulate Hg (Hg{sub P}) were measured intermittently at three sites in the southeastern U.S. from June 2001 through November 2004. Simultaneous measurements of SO{sub 2} and NOy were used to identify plumes from coal fired power plants (CFPPs). Emission signatures and back trajectories were used to identity specific CFPPs, and to compare observed (i.e., at the site) versus expected (i.e., at the stack) Hg speciation. Results for 41 precipitation-free plume events show that observed RGM:SO{sub 2} is substantially lower (by a factor of 2-4) than expected RGM:SO{sub 2}. Hg{sub P} represented 2%, or less, of total-Hg in CFPP plumes, in general agreement with emission estimates. Results for 21 events, where both RGM and Hg{sup 0} could be estimated, show that total-Hg (i.e., RGM + Hg{sup 0}) was essentially conserved from the point of emission to the site, and that Hg{sup 0} was the dominant form (average 84%). Emission estimates, based on coal analyses and the EPRI-ICR Hg speciation model, indicate that Hg{sup 0} should represent about 42% of Hg in the observed plumes. Possible explanations for these differences include, but are not limited to, in-plume reduction of RGM to Hg{sub 0}, measurement error, errors in emission estimates, and depositional losses. Further work is needed to confirm these results and to determine if they apply to CFPPs in general, or the limited set of observed CFPPs. 27 refs., 4 figs., 2 tabs.

  11. Performance analysis of co-firing waste materials in an advanced pressurized fluidized-bed combustor

    SciTech Connect (OSTI)

    Bonk, D.L.; McDaniel, H.M. [USDOE Morgantown Energy Technology Center, WV (United States); DeLallo, M.R. Jr.; Zaharchuk, R. [Gilbert/Commonwealth, Inc., Reading, PA (United States)

    1995-07-01T23:59:59.000Z

    The co-firing of waste materials with coal in utility scale power plants has emerged as an effective approach to produce energy and manage municipal wastes. Leading this approach is the atmospheric fluidized-bed combustor (AFBC). It has demonstrated its commercial acceptance in the utility market as a reliable source of power by burning a variety of waste and alternative fuels. The application of pressurized fluidized-bed combustor (PFBC) technology, although relatively new, can provide significant enhancements to the efficient production of electricity while maintaining the waste management benefits of AFBC. A study was undertaken to investigate the technical and economical feasibility of co-firing a PFBC with coal and municipal and industrial wastes. Focus was placed on the production of electricity and the efficient disposal of wastes for application in central power station and distributed locations. Issues concerning waste material preparation and feed, PFBC operation, plant emissions, and regulations are addressed. The results and conclusions developed are generally applicable to current and advanced PFBC design concepts. Wastes considered for co-firing include municipal solid waste (MSW), sewage sludge, and industrial de-inking sludge. Conceptual designs of two power plants rated at 250 MWe and 150 MWe were developed. Heat and material balances were completed for each plant along with environmental issues. With the PFBC`s operation at high temperature and pressure, efforts were centered on defining feeding systems capable of operating at these conditions. Air emissions and solid wastes were characterized to assess the environmental performance comparing them to state and Federal regulations. This paper describes the results of this investigation, presents conclusions on the key issues, and provides recommendations for further evaluation.

  12. Engineering development of advanced coal-fired low-emission boiler systems. Technical progress report No. 11, April 1995--June 1995

    SciTech Connect (OSTI)

    NONE

    1995-08-30T23:59:59.000Z

    The Pittsburgh Energy Technology Center of the U.S. Department of Energy (DOE) has contracted with Combustion Engineering, Inc. (ABB CE) to perform work on the {open_quotes}Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems{close_quotes} Project and has authorized ABB CE to complete Phase I on a cost-reimbursable basis and Phases II and III on a cost-share basis. The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The specified primary objectives are: (1) NO{sub x} emissions not greater than one-third NSPS. (2) SO{sub x} emissions not greater than one-third NSPS. (3) Particulate emissions not greater than one-half NSPS. The specific secondary objectives are: (1) Improved ash disposability and reduced waste generation. (2) Reduced air toxics emissions. (3) Increased generating efficiency. The final deliverables are a design data base that will allow future coal-fired power plants to meet the stated objectives and a preliminary design of a Commercial Generation Unit. The work in Phase I covered a 24-month period and included system analysis, RD&T Plan formulation, component definition, and preliminary Commercial Generating Unit (CGU) design. Phase II will cover a 15-month period and will include preliminary Proof-of-Concept Test Facility (POCTF) design and subsystem testing. Phase III will cover a 9-month period and will produce a revised CGU design and a revised POCTF design, cost estimate and a test plan. Phase IV, the final Phase, will cover a 36-month period and will include POCTF detailed design, construction, testing, and evaluation.

  13. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Volume 1, Final report

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    A major objective of the coal-fired high performance power systems (HIPPS) program is to achieve significant increases in the thermodynamic efficiency of coal use for electric power generation. Through increased efficiency, all airborne emissions can be decreased, including emissions of carbon dioxide. High Performance power systems as defined for this program are coal-fired, high efficiency systems where the combustion products from coal do not contact the gas turbine. Typically, this type of a system will involve some indirect heating of gas turbine inlet air and then topping combustion with a cleaner fuel. The topping combustion fuel can be natural gas or another relatively clean fuel. Fuel gas derived from coal is an acceptable fuel for the topping combustion. The ultimate goal for HIPPS is to, have a system that has 95 percent of its heat input from coal. Interim systems that have at least 65 percent heat input from coal are acceptable, but these systems are required to have a clear development path to a system that is 95 percent coal-fired. A three phase program has been planned for the development of HIPPS. Phase 1, reported herein, includes the development of a conceptual design for a commercial plant. Technical and economic feasibility have been analysed for this plant. Preliminary R&D on some aspects of the system were also done in Phase 1, and a Research, Development and Test plan was developed for Phase 2. Work in Phase 2 include s the testing and analysis that is required to develop the technology base for a prototype plant. This work includes pilot plant testing at a scale of around 50 MMBtu/hr heat input. The culmination of the Phase 2 effort will be a site-specific design and test plan for a prototype plant. Phase 3 is the construction and testing of this plant.

  14. Evaluation of technical feasibility of closed-cycle non-equilibrium MHD power generation with direct coal firing. Final report, Task I

    SciTech Connect (OSTI)

    Not Available

    1981-11-01T23:59:59.000Z

    Program accomplishments in a continuing effort to demonstrate the feasibility of direct coal-fired, closed-cycle MHD power generation are reported. This volume contains the following appendices: (A) user's manual for 2-dimensional MHD generator code (2DEM); (B) performance estimates for a nominal 30 MW argon segmented heater; (C) the feedwater cooled Brayton cycle; (D) application of CCMHD in an industrial cogeneration environment; (E) preliminary design for shell and tube primary heat exchanger; and (F) plant efficiency as a function of output power for open and closed cycle MHD power plants. (WHK)

  15. Economics of co-firing waste materials in an advanced pressurized fluidized-bed combustor

    SciTech Connect (OSTI)

    Bonk, D.L.; McDaniel, H.M. [Dept. of Energy, Morgantown, WV (United States). Morgantown Energy Technology Center; DeLallo, M.R. Jr.; Zaharchuk, R. [Gilbert/Commonwealth, Inc., Reading, PA (United States)

    1995-04-01T23:59:59.000Z

    The co-firing of waste materials with coal in utility scale power plants has emerged as an effective approach to produce energy and manage municipal waste. Leading this approach is the atmospheric fluidized bed combustor (AFBC). It has demonstrated its commercial acceptance in the utility market as a reliable source of power by burning a variety of waste and alternative fuels. The fluidized bed, with its stability of combustion, reduces the amount of thermochemical transients and provides for easier process control. The application of pressurized fluidized-bed combustor (PFBC) technology, although relatively new, can provide significant enhancements to the efficient production of electricity while maintaining the waste management benefits of AFBC. A study was undertaken to investigate the technical and economic feasibility of co-firing a PFBC with coal and municipal and industrial wastes. Focus was placed on the production of electricity and the efficient disposal of wastes for application in central power station and distributed locations. Issues concerning waste material preparation and feed, PFBC operation, plant emissions, and regulations are addressed. The results and conclusions developed are generally applicable to current and advanced PFBC design concepts.

  16. Engineering development of coal-fired high performance power systems, Phase 2 and 3. Quarterly progress report, October 1--December 31, 1995

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of: >47% thermal efficiency (HHV); NO{sub x}, SO{sub x} and particulates {ge} 10% NSPS; coal {ge} 65% of heat input; all solid wastes benign; and cost of electricity 90% of present plant. The HIPPS generating plant integrates a combustion gas turbine/HRSG combined cycle arrangement with an advanced coal-fired boiler. The unique feature of the HIPPS plant is the partial heating of gas turbine (GT) compressor outlet air using energy released by firing coal in the high temperature advanced furnace (HITAF). The compressed air is additionally heated prior to entering the GT expander section by burning natural gas. Energy available, in the gas turbine exhaust and in the HITAF flue gas are used in a steam cycle to maximize energy production. The HIPPS plant arrangement is thus a combination of existing technologies (gas turbine, heat recovery boilers, conventional steam cycle) and new technologies (the HITAF design especially the heater located in the radiant section). Work reported herein is from Task 1.3, HIPPS Commercial Design and Task 2.2, HITAF Air Heaters.

  17. Research on fundamental aspects of inorganic vapor and particle deposition in coal-fired systems. Quarterly technical report, December 6, 1991--March 5, 1992

    SciTech Connect (OSTI)

    Rosner, D.E.

    1992-03-01T23:59:59.000Z

    In September 1990 DOE-PETC initiated at the Yale HTCRE Laboratory a systematic three-year research program directed toward providing engineers with the fundamentally-based design/optimization ``tools`` foreconomically predicting the dynamics of net deposit growth, and thermophysical properties of the resulting microparticulate deposits in coal-fired systems. The goal of our research in the area of mineral mattertransport is to advance the capability of making reliable engineering predictions of the dynamics of net deposit growth for surfaces exposed to the particle-laden products of coal combustion. To accomplish thisfor a wide variety of combustor types, coal types, and operating conditions, this capability must be based on a quantitative understanding of each of the important mechanisms of mineral matter transport, as well as the nature of the interactions between these substances and the prevailing ``fireside`` surface of deposits. This level of understanding and predictive capability could be translated into very significant cost reductions for coal-fired equipment design, development and operation. It is also expected that this research activity will not only directly benefit the ash deposition R&D community -- but also generically closely related technologies of importance to DOE (e.g. hot-gas clean-up, particulate solids handling,...).

  18. Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1991-08-01T23:59:59.000Z

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor, Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuel performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal.

  19. Internet Based, GIS Catalog of Non-Traditional Sources of Cooling Water for Use at America's Coal-Fired Power Plants

    SciTech Connect (OSTI)

    J. Daniel Arthur

    2011-09-30T23:59:59.000Z

    In recent years, rising populations and regional droughts have caused coal-fired power plants to temporarily curtail or cease production due to a lack of available water for cooling. In addition, concerns about the availability of adequate supplies of cooling water have resulted in cancellation of plans to build much-needed new power plants. These issues, coupled with concern over the possible impacts of global climate change, have caused industry and community planners to seek alternate sources of water to supplement or replace existing supplies. The Department of Energy, through the National Energy Technology Laboratory (NETL) is researching ways to reduce the water demands of coal-fired power plants. As part of the NETL Program, ALL Consulting developed an internet-based Catalog of potential alternative sources of cooling water. The Catalog identifies alternative sources of water, such as mine discharge water, oil and gas produced water, saline aquifers, and publicly owned treatment works (POTWs), which could be used to supplement or replace existing surface water sources. This report provides an overview of the Catalog, and examines the benefits and challenges of using these alternative water sources for cooling water.

  20. Evaluation of AFBC co-firing of coal and hospital wastes

    SciTech Connect (OSTI)

    Not Available

    1991-02-01T23:59:59.000Z

    The purpose of this program is to expand the use of coal by utilizing CFB (circulating fluidized bed) technology to provide an environmentally safe method for disposing of waste materials. Hospitals are currently experiencing a waste management crisis. In many instances, they are no longer permitted to burn pathological and infectious wastes in incinerators. Older hospital incinerators are not capable of maintaining the stable temperatures and residence times necessary in order to completely destroy toxic substances before release into the atmosphere. In addition, the number of available landfills which can safely handle these substances is decreasing each year. The purpose of this project is to conduct necessary research investigating whether the combustion of the hospital wastes in a coal-fired circulating fluidized bed boiler will effectively destroy dioxins and other hazardous substances before release into the atmosphere. If this is proven feasible, in light of the quantity of hospital wastes generated each year, it would create a new market for coal -- possibly 50 million tons/year.

  1. Co-firing high sulfur coal with refuse derived fuels. Quarterly report, October - December 1996

    SciTech Connect (OSTI)

    Pan, W.-P.; Riley, J.T.; Lloyd, W.G.

    1996-12-01T23:59:59.000Z

    The objectives of this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the effect of S0{sub 2} on the formation of chlorine during combustion processes was examined. To simulate the conditions used in the AFBC system, experiments were conducted in a quartz tube in an electrically heated furnace. The principle analytical technique used for identification of the products from this study was GC/MS. The evolved gas was trapped by an absorbent and analyzed with a GC/MS system. The preliminary results indicate an inhibiting effect of S0{sub 2} on the Deacon Reaction. Secondly, information on the evolution of chlorine, sulfur and organic compounds from coals 95031 and 95011 were studied with the AFBC system. 2 figs., 1 tab.

  2. AFBC co-firing of coal and hospital waste. Quarterly report, February - April, 1996

    SciTech Connect (OSTI)

    Stuart, J.M.

    1996-12-31T23:59:59.000Z

    The project objective is to design, construct, install provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation while providing efficient destruction of both general and infectious hospital waste. The steam generated is as follows: steam = 20,000 lb/hr; temperature = 353 F (saturated); pressure = 125 psig; and steam quality = {approximately}98.5%. During this reporting period: structural corrections have been made to make the facility meet the required building costs; and refractory bakeout was successfully completed during April 23-25, 1996 over a 54 -hour period. Operating permits will be obtained after construction has been completed.

  3. Novel polymer membrane process for pre-combustion CO{sub 2} capture from coal-fired syngas

    SciTech Connect (OSTI)

    Merkel, Tim [MTR Inc., Menlo Park, CA (United States)

    2011-09-14T23:59:59.000Z

    This final report describes work conducted for the Department of Energy (DOE NETL) on development of a novel polymer membrane process for pre-combustion CO{sub 2} capture from coalfired syngas (award number DE-FE0001124). The work was conducted by Membrane Technology and Research, Inc. (MTR) from September 15, 2009, through December 14, 2011. Tetramer Technologies, LLC (Tetramer) was our subcontract partner on this project. The National Carbon Capture Center (NCCC) at Wilsonville, AL, provided access to syngas gasifier test facilities. The main objective of this project was to develop a cost-effective membrane process that could be used in the relatively near-term to capture CO{sub 2} from shifted syngas generated by a coal-fired Integrated Gasification Combined Cycle (IGCC) power plant. In this project, novel polymeric membranes (designated as Proteus™ membranes) with separation properties superior to conventional polymeric membranes were developed. Hydrogen permeance of up to 800 gpu and H{sub 2}/CO{sub 2} selectivity of >12 was achieved using a simulated syngas mixture at 150°C and 50 psig, which exceeds the original project targets of 200 gpu for hydrogen permeance and 10 for H{sub 2}/CO{sub 2} selectivity. Lab-scale Proteus membrane modules (with a membrane area of 0.13 m{sup 2}) were also developed using scaled-up Proteus membranes and high temperature stable module components identified during this project. A mixed-gas hydrogen permeance of about 160 gpu and H{sub 2}/CO{sub 2} selectivity of >12 was achieved using a simulated syngas mixture at 150°C and 100 psig. We believe that a significant improvement in the membrane and module performance is likely with additional development work. Both Proteus membranes and lab-scale Proteus membrane modules were further evaluated using coal-derived syngas streams at the National Carbon Capture Center (NCCC). The results indicate that all module components, including the Proteus membrane, were stable under the field conditions (feed pressures: 150-175 psig and feed temperatures: 120-135°C) for over 600 hours. The field performance of both Proteus membrane stamps and Proteus membrane modules is consistent with the results obtained in the lab, suggesting that the presence of sulfur-containing compounds (up to 780 ppm hydrogen sulfide), saturated water vapor, carbon monoxide and heavy hydrocarbons in the syngas feed stream has no adverse effect on the Proteus membrane or module performance. We also performed an economic analysis for a number of membrane process designs developed in this project (using hydrogen-selective membranes, alone or in the combination with CO{sub 2}- selective membranes). The current field performance for Proteus membranes was used in the design analysis. The study showed the current best design has the potential to reduce the increase in Levelized Cost of Electricity (LCOE) caused by 90% CO{sub 2} capture to about 15% if co-sequestration of H{sub 2}S is viable. This value is still higher than the DOE target for increase in LCOE (10%); however, compared to the base-case Selexol process that gives a 30% increase in LCOE at 90% CO2 capture, the membrane-based process appears promising. We believe future improvements in membrane performance have the potential to reach the DOE target.

  4. Engineering development of advanced coal-fired low-emissions boiler systems. Quarterly report, October 1994--December 1994; January 1995--March 1995; April 1995--June 1995; July 1995--September 1995; October 1995--December 1995

    SciTech Connect (OSTI)

    NONE

    1996-04-01T23:59:59.000Z

    This report covers five quarters of work on the engineering development of a coal-fired low -emissions boiler systems. Contents include summaries of activities and key accomplishments for the following: project management; NO{sub x} subsystem; SO{sub 2}/particulate/air toxics/solid by-product subsystems; controls and sensors subsystems; boiler subsystem; and balance of plant subsystem.

  5. Performance and economics of co-firing a coal/waste slurry in advanced fluidized-bed combustion

    SciTech Connect (OSTI)

    DeLallo, M.R.; Zaharchuk, R. [Parsons Power Group, Inc., Reading, PA (United States); Reuther, R.B.; Bonk, D.L. [USDOE Morgantown Energy Technology Center, WV (United States)

    1996-09-01T23:59:59.000Z

    This study`s objective was to investigate co-firing a pressurized fluidized-bed combustor with coal and refuse-derived fuel for the production of electricity and the efficient disposal of waste. Performance evaluation of the pressurized fluidized-bed combustor (PFBC) power plant co-fired with refuse-derived fuel showed only slightly lower overall thermal efficiency than similar sized plants without waste co-firing. Capital costs and costs of electricity are within 4.2 percent and 3.2 percent, respectively, of waste-free operation. The results also indicate that there are no technology barriers to the co-firing of waste materials with coal in a PFBC power plant. The potential to produce cost-competitive electrical power and support environmentally acceptable waste disposal exists with this approach. However, as part of technology development, there remain several design and operational areas requiring data and verification before this concept can realize commercial acceptance. 3 refs., 3 figs., 4 tabs.

  6. Modeling of integrated environmental control systems for coal-fired power plants. Quarterly progress report, [April 1, 1988--June 30, 1988

    SciTech Connect (OSTI)

    Rubin, E.S.

    1988-06-01T23:59:59.000Z

    This is the third quarterly report of DOE Contract No. DE-AC22- 87PC79864, entitled ``Modeling of Integrated Environmental Control Systems for Coal-Fired Power Plants.`` This report summarizes accomplishments during the period April 1, 1988 to June 30, 1988. Our efforts during the last quarter focused on, (1) completion of a sulfuric acid plant model (used in conjunction with by-product recovery processes for SO{sub 2}/NO{sub x} removal) and, (2) an update the NOXSO process model. Other accomplishments involved revision and expansion of the enthalpy data algorithms used for process energy balances. The sections below present the details of these developments. References are included at the end of each section.

  7. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment. Final technical report, September 1, 1986--April 30, 1990

    SciTech Connect (OSTI)

    Rosner, D.E.

    1990-05-01T23:59:59.000Z

    The overall goal of this research in the area of ash transport was to advance the capability of making reliable engineering predictions of the dynamics and consequences of net deposit growth for surfaces exposed to the products of coal combustion. To accomplish this for a wide variety of combustor types, coal types, and operating conditions, this capability must be based on a quantitative understanding of each of the important mechanisms of mineral matter transport, as well as the nature of the interactions between these substances and the prevailing ``fireside`` surface of the deposit. This level of understanding and predictive capability could ultimately be translated into very significant cost reductions for coal-fired equipment design, development and operation.

  8. Hybrid Solvent-Membrane CO2 Capture: A Solvent/Membrane Hybrid Post-combustion CO2 Capture Process for Existing Coal-Fired Power Plants

    SciTech Connect (OSTI)

    None

    2010-07-01T23:59:59.000Z

    IMPACCT Project: The University of Kentucky is developing a hybrid approach to capturing CO2 from the exhaust gas of coal-fired power plants. In the first, CO2 is removed as flue gas is passed through an aqueous ammonium-based solvent. In the second, carbon-rich solution from the CO2 absorber is passed through a membrane that is designed to selectively transport the bound carbon, enhancing its concentration on the permeate side. The team’s approach would combine the best of both membrane- and solventbased carbon capture technologies. Under the ARPA-E award, the team is enabling the membrane operation to be a drop-in solution.

  9. Upgraded Coal Interest Group

    SciTech Connect (OSTI)

    Evan Hughes

    2009-01-08T23:59:59.000Z

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  10. The development of a coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, January 1992--March 1992

    SciTech Connect (OSTI)

    Not Available

    1992-07-16T23:59:59.000Z

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Coal-Fired Combustion System for Industrial Process Heating Applications has been selected for Phase III development under contract DE-AC22-91PC91161. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting, recycling, and refining processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase HI research effort is being focused on the development of a process heater system to be used for producing glass frits and wool fiber from boiler and incinerator ashes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The economic evaluation of commercial scale CMS processes has begun. In order to accurately estimate the cost of the primary process vessels, preliminary designs for 25, 50, and 100 ton/day systems have been started under Task 1. This data will serve as input data for life cycle cost analysis performed as part of techno-economic evaluations. The economic evaluations of commercial CMS systems will be an integral part of the commercialization plan.

  11. EVALUATION OF SOLID SORBENTS AS A RETROFIT TECHNOLOGY FOR CO2 CAPTURE FROM COAL-FIRED POWER PLANTS

    SciTech Connect (OSTI)

    Holly Krutka; Sharon Sjostrom

    2011-07-31T23:59:59.000Z

    Through a U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) funded cooperative agreement DE-NT0005649, ADA Environmental Solutions (ADA) has begun evaluating the use of solid sorbents for CO{sub 2} capture. The project objective was to address the viability and accelerate development of a solid-based CO{sub 2} capture technology. To meet this objective, initial evaluations of sorbents and the process/equipment were completed. First the sorbents were evaluated using a temperature swing adsorption process at the laboratory scale in a fixed-bed apparatus. A slipstream reactor designed to treat flue gas produced by coal-fired generation of nominally 1 kWe was designed and constructed, which was used to evaluate the most promising materials on a more meaningful scale using actual flue gas. In a concurrent effort, commercial-scale processes and equipment options were also evaluated for their applicability to sorbent-based CO{sub 2} capture. A cost analysis was completed that can be used to direct future technology development efforts. ADA completed an extensive sorbent screening program funded primarily through this project, DOE NETL cooperative agreement DE-NT0005649, with support from the Electric Power Research Institute (EPRI) and other industry participants. Laboratory screening tests were completed on simulated and actual flue gas using simulated flue gas and an automated fixed bed system. The following types and quantities of sorbents were evaluated: 87 supported amines; 31 carbon based materials; 6 zeolites; 7 supported carbonates (evaluated under separate funding); and 10 hydrotalcites. Sorbent evaluations were conducted to characterize materials and down-select promising candidates for further testing at the slipstream scale. More than half of the materials evaluated during this program were supported amines. Based on the laboratory screening four supported amine sorbents were selected for evaluation at the 1 kW scale at two different field sites. ADA designed and fabricated a slipstream pilot to allow an evaluation of the kinetic behavior of sorbents and provide some flexibility for the physical characteristics of the materials. The design incorporated a transport reactor for the adsorber (co-current reactor) and a fluidized-bed in the regenerator. This combination achieved the sorbent characterization goals and provided an opportunity to evaluate whether the potential cost savings associated with a relatively simple process design could overcome the sacrifices inherent in a co-current separation process. The system was installed at two field sites during the project, Luminant's Martin Lake Steam Electric Station and Xcel Energy's Sherburne County Generating Station (Sherco). Although the system could not maintain continuous 90% CO{sub 2} removal with the sorbents evaluated under this program, it was useful to compare the CO{sub 2} removal properties of several different sorbents on actual flue gas. One of the supported amine materials, sorbent R, was evaluated at both Martin Lake and Sherco. The 1 kWe pilot was operated in continuous mode as well as batch mode. In continuous mode, the sorbent performance could not overcome the limitations of the cocurrent adsorbent design. In batch mode, sorbent R was able to remove up to 90% CO{sub 2} for several cycles. Approximately 50% of the total removal occurred in the first three feet of the adsorption reactor, which was a transport reactor. During continuous testing at Sherco, CO{sub 2} removal decreased to approximately 20% at steady state. The lack of continuous removal was due primarily to the combination of a co-current adsorption system with a fluidized bed for regeneration, a combination which did not provide an adequate driving force to maintain an acceptable working CO{sub 2} capacity. In addition, because sorbent R consisted of a polymeric amine coated on a silica substrate, it was believed that the 50% amine loaded resulted in mass diffusion limitations related to the CO{sub 2} uptake rate. Three additional supported amine materials, so

  12. Evaluation of Solid Sorbents As A Retrofit Technology for CO{sub 2} Capture from Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Krutka, Holly; Sjostrom, Sharon

    2011-07-31T23:59:59.000Z

    Through a U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) funded cooperative agreement DE-NT0005649, ADA Environmental Solutions (ADA) has begun evaluating the use of solid sorbents for CO{sub 2} capture. The project objective was to address the viability and accelerate development of a solid-based CO{sub 2} capture technology. To meet this objective, initial evaluations of sorbents and the process / equipment were completed. First the sorbents were evaluated using a temperature swing adsorption process at the laboratory scale in a fixed-bed apparatus. A slipstream reactor designed to treat flue gas produced by coal-fired generation of nominally 1 kWe was designed and constructed, which was used to evaluate the most promising materials on a more meaningful scale using actual flue gas. In a concurrent effort, commercial-scale processes and equipment options were also evaluated for their applicability to sorbent-based CO{sub 2} capture. A cost analysis was completed that can be used to direct future technology development efforts. ADA completed an extensive sorbent screening program funded primarily through this project, DOE NETL cooperative agreement DE-NT0005649, with support from the Electric Power Research Institute (EPRI) and other industry participants. Laboratory screening tests were completed on simulated and actual flue gas using simulated flue gas and an automated fixed bed system. The following types and quantities of sorbents were evaluated: 87 supported amines, 31 carbon based materials, 6 zeolites, 7 supported carbonates (evaluated under separate funding), 10 hydrotalcites. Sorbent evaluations were conducted to characterize materials and down-select promising candidates for further testing at the slipstream scale. More than half of the materials evaluated during this program were supported amines. Based on the laboratory screening four supported amine sorbents were selected for evaluation at the 1 kW scale at two different field sites. ADA designed and fabricated a slipstream pilot to allow an evaluation of the kinetic behavior of sorbents and provide some flexibility for the physical characteristics of the materials. The design incorporated a transport reactor for the adsorber (co-current reactor) and a fluidized-bed in the regenerator. This combination achieved the sorbent characterization goals and provided an opportunity to evaluate whether the potential cost savings associated with a relatively simple process design could overcome the sacrifices inherent in a co-current separation process. The system was installed at two field sites during the project, Luminant’s Martin Lake Steam Electric Station and Xcel Energy’s Sherburne County Generating Station (Sherco). Although the system could not maintain continuous 90% CO{sub 2} removal with the sorbents evaluated under this program, it was useful to compare the CO{sub 2} removal properties of several different sorbents on actual flue gas. One of the supported amine materials, sorbent R, was evaluated at both Martin Lake and Sherco. The 1 kWe pilot was operated in continuous mode as well as batch mode. In continuous mode, the sorbent performance could not overcome the limitations of the co-current adsorbent design. In batch mode, sorbent R was able to remove up to 90% CO{sub 2} for several cycles. Approximately 50% of the total removal occurred in the first three feet of the adsorption reactor, which was a transport reactor. During continuous testing at Sherco, CO{sub 2} removal decreased to approximately 20% at steady state. The lack of continuous removal was due primarily to the combination of a co-current adsorption system with a fluidized bed for regeneration, a combination which did not provide an adequate driving force to maintain an acceptable working CO{sub 2} capacity. In addition, because sorbent R consisted of a polymeric amine coated on a silica substrate, it was believed that the 50% amine loaded resulted in mass diffusion limitations related to the CO{sub 2} uptake rate. Three additional supported amine materials,

  13. Biomass Reburning: Modeling/Engineering Studies

    SciTech Connect (OSTI)

    Vladimir M. Zamansky

    1998-01-20T23:59:59.000Z

    Reburning is a mature fuel staging NO{sub x} control technology which has been successfully demonstrated at full scale by Energy and Environmental Research Corporation (EER) and others on numerous occasions. Based on chemical kinetic modeling and experimental combustion studies, EER is currently developing novel concepts to improve the efficiency of the basic gas reburning process and to utilize various renewable and waste fuels for NO{sub x} control. This project is designed to develop engineering and modeling tools for a family of NO{sub x} control technologies utilizing biomass as a reburning fuel. Basic and advanced biomass reburning have the potential to achieve 60-90+% NO{sub x} control in coal fired boilers at a significantly lower cost than SCR. The scope of work includes modeling studies (kinetic, CFD, and physical modeling), experimental evaluation of slagging and fouling associated with biomass reburning, and economic study of biomass handling requirements. Project participants include: EER, FETC R and D group, Niagara Mohawk Power Corporation and Antares, Inc. Most of the combustion experiments on development of biomass reburning technologies are being conducted in the scope of coordinated SBIR program funded by USDA. The first reporting period (October 1--December 31, 1997) included preparation of project management plan and organization of project kick-off meeting at DOE FETC. The quarterly report briefly describes the management plan and presents basic information about the kick-off meeting.

  14. Atmospheric fluidized-bed combustion (AFBC) co-firing of coal and hospital waste. Environmental Assessment

    SciTech Connect (OSTI)

    Not Available

    1993-02-01T23:59:59.000Z

    The proposed project involves co-firing of coal and medical waste (including infectious medical waste) in an atmospheric fluidized-bed combustor (AFBC) to safely dispose of medical waste and produce steam for hospital needs. Combustion at the design temperature and residence time (duration) in the AFBC has been proven to render infectious medical waste free of disease producing organisms. The project would be located at the Veterans Affairs (VA) Medical Center in Lebanon, Pennsylvania. The estimated cost of the proposed AFBC facility is nearly $4 million. It would be jointly funded by DOE, Veterans Affairs, and Donlee Technologies, Inc., of York, Pennsylvania, under a cooperative agreement between DOE and Donlee. Under the terms of this agreement, $3.708 million in cost-shared financial assistance would be jointly provided by DOE and the Veterans Affairs (50/50), with $278,000 provided by Donlee. The purposes of the proposed project are to: (1) provide the VA Medical Center and the Good Samaritan Hospital (GSH), also of Lebanon, Pennsylvania, with a solution for disposal of their medical waste; and (2) demonstrate that a new coal-burning technology can safely incinerate infectious medical waste, produce steam to meet hospital needs, and comply with environmental regulations.

  15. AFBC co-firing of coal and hospital waste. Quarterly report, August--October 1995

    SciTech Connect (OSTI)

    Stuart, J.M.

    1996-03-01T23:59:59.000Z

    The project objective is to design, construct, install provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation. This would permit full capacity operation of the FBC year round in spite of the VA laundry that was shut down as well as efficient destruction of both general and infectious hospital waste and steam generation. The State permitting process required for construction will be completed in early November to allow installation and construction to be completed. Operating permits will be obtained after construction has been completed. A request for proposal for stack sampling and biospore tests was released to four (4) vendors in mid-October. The proposals shall be reviewed during November and the stack sampler will be selected. Funding was approved as of August 1, 1995. Construction and installation resumed on August 21, 1995 at the LVAMC. Construction and installation continues and will be completed by late December 1995.

  16. AFBC co-firing of coal and hospital waste. Quarterly report, November 1995--January 1996

    SciTech Connect (OSTI)

    Stuart, J.M.

    1996-03-01T23:59:59.000Z

    The project objective is to design, construct, install provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation while providing efficient destruction of both general and infectious hospital waste. Operating permits will be obtained after construction has been completed. The stack sampler has been selected. This vendor is currently developing the testing protocol. Severe weather in December and January caused work delays to the project, especially to outside work The fabrication and installation of the stack are complete. Only the insulation of the stack remains to be done. Budget problems began to occur in late January. Correction of this situation should occur shortly in February or March. A current schedule for the project is included with this report.

  17. Effect of Co-Firing Torrefied Woody Biomass with Coal in a 30 kWt Downfired Burner

    E-Print Network [OSTI]

    Thanapal, Siva S

    2014-04-25T23:59:59.000Z

    emission by 10% when compared to base case NOx emission from combustion of pure PRB coal. NOx emission decreased with increase in equivalence ratio. In addition, a term used in the biological literature, respiratory quotient (RQ), is applied to fossil...

  18. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 6, January--March 1996

    SciTech Connect (OSTI)

    Pan, W.P.; Riley, J.T.; Lloyd, W.G.

    1996-02-29T23:59:59.000Z

    The objectives for this quarter of study on the co-firing of high sulfur coals with refuse derived fuels were two-fold. First, the effects of different experimental parameters such as temperature, flow rates and reaction times on the formation of chlorinated organic compounds were studied using the tubular furnace as a reactor followed by GC/MS analysis. Secondly, the effect of fuel/air ratio on the flue gas composition and combustion efficiency were studied with the AFBC system.

  19. FIELD TEST PROGRAM FOR LONG-TERM OPERATION OF A COHPAC SYSTEM FOR REMOVING MERCURY FROM COAL-FIRED FLUE GAS

    SciTech Connect (OSTI)

    Jean Bustard; Charles Lindsey; Paul Brignac; Travis Starns; Sharon Sjostrom; Trent Taylor; Cindy Larson

    2004-01-29T23:59:59.000Z

    With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Sorbent injection technology represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. It involves injecting a solid material such as powdered activated carbon into the flue gas. The gas-phase mercury in the flue gas contacts the sorbent and attaches to its surface. The sorbent with the mercury attached is then collected by the existing particle control device along with the other solid material, primarily fly ash. During 2001, ADA Environmental Solutions (ADA-ES) conducted a full-scale demonstration of sorbent-based mercury control technology at the Alabama Power E.C. Gaston Station (Wilsonville, AL). This unit burns a low-sulfur bituminous coal and uses a hot-side electrostatic precipitator (ESP) in combination with a Compact Hybrid Particulate Collector (COHPAC{trademark}) baghouse to collect fly ash. The majority of the fly ash is collected in the ESP with the residual being collected in the COHPAC{trademark} baghouse. Activated carbon was injected between the ESP and COHPAC{trademark} units to collect the mercury. Short-term mercury removal levels in excess of 90% were achieved using the COHPAC{trademark} unit. The test also showed that activated carbon was effective in removing both forms of mercury--elemental and oxidized. However, a great deal of additional testing is required to further characterize the capabilities and limitations of this technology relative to use with baghouse systems such as COHPAC{trademark}. It is important to determine performance over an extended period of time to fully assess all operational parameters. The project described in this report focuses on fully demonstrating sorbent injection technology at a coal-fired power generating plant that is equipped with a COHPAC{trademark} system. The overall objective is to evaluate the long-term effects of sorbent injection on mercury capture and COHPAC{trademark} performance. The work is being done on one-half of the gas stream at Alabama Power Company's Plant Gaston Unit 3 (nominally 135 MW). Data from the testing will be used to determine: (1) If sorbent injection into a high air-to-cloth ratio baghouse is a viable, long-term approach for mercury control; and (2) Design criteria and costs for new baghouse/sorbent injection systems that will use a similar, polishing baghouse (TOXECON{trademark}) approach.

  20. Site Characterization for CO{sub 2} Storage from Coal-fired Power Facilities in the Black Warrior Basin of Alabama

    SciTech Connect (OSTI)

    Clark, Peter; Pashin, Jack; Carlson, Eric; Goodliffe, Andrew; McIntyre-Redden, Marcella; Mann, Steven; Thompson, Mason

    2012-08-31T23:59:59.000Z

    Coal-fired power plants produce large quantities of carbon dioxide. In order to mitigate the greenhouse gas emissions from these power plants, it is necessary to separate and store the carbon dioxide. Saline formations provide a potential sink for carbon dioxide and delineating the capacity of the various known saline formations is a key part of building a storage inventory. As part of this effort, a project was undertaken to access the storage capacity of saline reservoirs in the Black Warrior Basin of Alabama. This basin has been a productive oil and gas reservoir that is well characterized to the west of the two major coal-fired power plants that are north of Birmingham. The saline zones were thought to extend as far east as the Sequatchie Anticline which is just east of the power plants. There is no oil or gas production in the area surrounding the power plants so little is known about the formations in that area. A geologic characterization well was drilled on the Gorgas Power Plant site, which is the farthest west of two power plants in the area. The well was planned to be drilled to approximately 8,000 feet, but drilling was halted at approximately 5,000 feet when a prolific freshwater zone was penetrated. During drilling, a complete set of cores through all of the potential injection zones and the seals above these zones were acquired. A complete set of openhole logs were run along with a vertical seismic profile (VSP). Before drilling started two approximately perpendicular seismic lines were run and later correlated with the VSP. While the zones that were expected were found at approximately the predicted depths, the zones that are typically saline through the reservoir were found to be saturated with a light crude oil. Unfortunately, both the porosity and permeability of these zones were small enough that no meaningful hydrocarbon production would be expected even with carbon dioxide flooding. iv While this part of the basin was found to be unsuitable for carbon dioxide injection, there is still a large storage capacity in the basin to the west of the power plants. It will, however, require pipeline construction to transport the carbon dioxide to the injection sites.

  1. Optimized Solvent for Energy-Efficient, Environmentally-Friendly Capture of CO{sub 2} at Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Farthing, G. A.; Rimpf, L. M.

    2014-04-30T23:59:59.000Z

    The overall goal of this project, as originally proposed, was to optimize the formulation of a novel solvent as a critical enabler for the cost-effective, energy-efficient, environmentally-friendly capture of CO{sub 2} at coal-fired utility plants. Aqueous blends of concentrated piperazine (PZ) with other compounds had been shown to exhibit high rates of CO{sub 2} absorption, low regeneration energy, and other desirable performance characteristics during an earlier 5-year development program conducted by B&W. The specific objective of this project was to identify PZ-based solvent formulations that globally optimize the performance of coal-fired power plants equipped with CO{sub 2} scrubbing systems. While previous solvent development studies have tended to focus on energy consumption and absorber size, important issues to be sure, the current work seeks to explore, understand, and optimize solvent formulation across the full gamut of issues related to commercial application of the technology: capital and operating costs, operability, reliability, environmental, health and safety (EH&S), etc. Work on the project was intended to be performed under four budget periods. The objective of the work in the first budget period has been to identify several candidate formulations of a concentrated PZ-based solvent for detailed characterization and evaluation. Work in the second budget period would generate reliable and comprehensive property and performance data for the identified formulations. Work in the third budget period would quantify the expected performance of the selected formulations in a commercial CO{sub 2} scrubbing process. Finally, work in the fourth budget period would provide a final technology feasibility study and a preliminary technology EH&S assessment. Due to other business priorities, however, B&W has requested that this project be terminated at the end of the first budget period. This document therefore serves as the final report for this project. It is the first volume of the two-volume final report and summarizes Budget Period 1 accomplishments under Tasks 1-5 of the project, including the selection of four solvent formulations for further study.

  2. Oxy-fuel combustion of coal and biomass, the effect on radiative and convective heat transfer and burnout

    SciTech Connect (OSTI)

    Smart, John P.; Patel, Rajeshriben; Riley, Gerry S. [RWEnpower, Windmill Hill Business Park, Whitehill Way, Swindon, Wiltshire SN5 6PB, England (United Kingdom)

    2010-12-15T23:59:59.000Z

    This paper focuses on results of co-firing coal and biomass under oxy-fuel combustion conditions on the RWEn 0.5 MWt Combustion Test Facility (CTF). Results are presented of radiative and convective heat transfer and burnout measurements. Two coals were fired: a South African coal and a Russian Coal under air and oxy-fuel firing conditions. The two coals were also co-fired with Shea Meal at a co-firing mass fraction of 20%. Shea Meal was also co-fired at a mass fraction of 40% and sawdust at 20% with the Russian Coal. An IFRF Aerodynamically Air Staged Burner (AASB) was used. The thermal input was maintained at 0.5 MWt for all conditions studied. The test matrix comprised of varying the Recycle Ratio (RR) between 65% and 75% and furnace exit O{sub 2} was maintained at 3%. Carbon-in-ash samples for burnout determination were also taken. Results show that the highest peak radiative heat flux and highest flame luminosity corresponded to the lowest recycle ratio. The effect of co-firing of biomass resulted in lower radiative heat fluxes for corresponding recycle ratios. Furthermore, the highest levels of radiative heat flux corresponded to the lowest convective heat flux. Results are compared to air firing and the air equivalent radiative and convective heat fluxes are fuel type dependent. Reasons for these differences are discussed in the main text. Burnout improves with biomass co-firing under both air and oxy-fuel firing conditions and burnout is also seen to improve under oxy-fuel firing conditions compared to air. (author)

  3. Development and testing of a commercial-scale coal-fired combustion system, Phase 3. Quarterly technical progress report No. 3, April 1, 1991--June 30, 1991

    SciTech Connect (OSTI)

    Litka, A.F.; Breault, R.W.

    1991-10-01T23:59:59.000Z

    Within the commercial sector, oil and natural gas are the predominant fuels used to meet the space-heating needs of schools, office buildings, apartment complexes, and other similar structures. In general, these buildings require firing rates of 1 to 10 million Btu/hr. The objective of this program is to demonstrate the technical and economic viability of a coal-fired combustion system for this sector. The commercial-scale coal-water slurry (CWS)-fired space heating system will be a scale-up of a CWS-fired residential warm-air heating system developed by Tecogen under contract to the Department of Energy, Pittsburgh Energy Technology Center. This system included a patented nonslagging combustor known as IRIS, for Inertial Reactor with Internal Separation. This combustion technology, which has demonstrated high combustion efficiency using CWS fuels at input rates of 100,000 Btu/hr, will be scaled to operate at 2 to 5 millon Btu/hr. Along with the necessary fuel storage and delivery, heat recovery, and control equipment, the system will include pollution control devices to meet targeted values of NO{sub x}, S0{sub 2}, and particulate emissions. In general, the system will be designed to match the reliability, safety, turndown, and ignition performance of gas or oil-fired systems.

  4. Research on fundamental aspects of inorganic vapor and particle deposition in coal-fired systems. Eighth quarterly technical progress report, June 6, 1992--September 5, 1992

    SciTech Connect (OSTI)

    Rosner, D.E.

    1992-09-01T23:59:59.000Z

    In September 1990 DOE-PETC initiated at the Yale HTCRE Laboratory a systematic three-year research program directed toward providing engineers with the fundamentally-based design/optimization `tools` for economically predicting the dynamics of net deposit growth*, and thermophysical properties of the resulting microparticulate deposits in coal-fired systems. In light of the theoretical `program` based on the notion of ``self-regulation`` set forth in Rosner and Nagarajan (1987), this Task includes investigation of the effects of particle material properties and possible liquid phases on the capture properties of particulate deposits. For this purpose we exploit dynamical `many-body` computer simulation techniques. This approach will provide the required parametric dependencies (on such quantities as incident kinetic energy and angle, mechanical and thermophysical properties of the particles,{hor_ellipsis}) of a dimensionless ensemble-averaged particle capture fraction, relegating the role of direct laboratory experiment to verifying (or rejecting) some crucial features/consequences of the simulation route followed. Our ultimate goal is recommend `sticking` and `erosion` laws of mechanistic origin. The availability of such laws could dramatically increase the reliability of predicted deposition rates of inertially delivered particles, in the simultaneous presence of a condensed liquid phase within the growing particulate, deposit. Equally important, one could also rationally select conditions to avoid. troublesome deposition subject to other operational requirements.

  5. Exergy method of power plant systems analysis and its application to a pressurized fluidized bed coal-fired combined-cycle power plant

    SciTech Connect (OSTI)

    Ghamarian, A.

    1981-01-01T23:59:59.000Z

    This thesis surveys the concepts of exergy and extends the exergy method of analysis from the standpoint of its applications to the power plant systems. After a brief historical review of exergy concepts, the general exergy equation is derived from the combined equation of First and Second Law, and it is shown that any special case of exergy equation is a simplified form of the general exergy equation. The mathematical method for the exergy analysis of a steady-state, steady-flow system, analogous to that of the First Law, is given. The exergy losses in a power plant are discussed. Then in order to examine these losses, the Second Law performance of major processes of combustion, compression, heat transfer, mixing and throttling have been analyzed analytically, and the exergy efficiencies are defined that accurately assess the thermodynamic performance of the corresponding processes. The methods for computation of exergy loss and exergy efficiency are given and simplified for practical cases of the corresponding processes. Analytical methods for evaluating the exergy of coal, pure substances (air and water), and combustion gases are presented and the energy-exergy tables for corresponding working substances are constructed. Finally, a comprehensive thermodynamic analysis, with emphasis on the Second Law (exergy) consideration, of an actual coal-fired, combined-cycle (CFCC) power plant, being designed by the General Electric Company, is carried out and suggestions are made as to what (and where), if any, improvement might be made in the design.

  6. Oxygen-Fired CO{sub 2} Recycle for Application to Direct CO{sub 2} Capture form Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Thomas Gale

    2010-09-26T23:59:59.000Z

    The Southern Research/Southern Company 1 MWth Pilot-Scale Coal-Fired Test Facility was successfully retrofit to fire in either the traditional air-fired mode or with 100% oxygen and recycled flue gas, with a fully integrated feedback and control system, including oxygen and recycled flue gas modulation during startup, transfer, and shutdown, safety and operational interlocks, and data acquisition. A MAXON Staged Oxygen Burner for Oxy-Coal Applications produced a stable flame over a significant range of firing turn-down, staging, and while firing five different U.S. coal types. The MAXON burner design produces lower flame temperatures than for air firing, which will enable (A) Safe operation, (B) Reduction of recycle flow without concern about furnace flame temperatures, and (C) May likely be affective at reducing slagging and fouling in the boiler and super heater at full-scale Power Plants. A CFD model of the Oxy-fired Combustion Research Facility (OCRF) was used to predict the flame geometry and temperatures in the OCRF and make a comparison with the air-fired case. The model predictions were consistent with the experimental data in showing that the MAXON burner fired with oxygen produced lower flame temperatures than the air-fired burner while firing with air.

  7. A study of toxic emissions from a coal-fired power plant utilizing an ESP/Wet FGD system. Volume 1, Sampling, results, and special topics: Final report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01T23:59:59.000Z

    This was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE-PETC in 1993 as mandated by the 1990 Clean Air Act. It is organized into 2 volumes; Volume 1 describes the sampling effort, presents the concentration data on toxic chemicals in several power plant streams, and reports the results of evaluations and calculations. The study involved solid, liquid, and gaseous samples from input, output, and process streams at Coal Creek Station Unit No. 1, Underwood, North Dakota (1100 MW mine-mouth plant burning lignite from the Falkirk mine located adjacent to the plant). This plant had an electrostatic precipitator and a wet scrubber flue gas desulfurization unit. Measurements were conducted on June 21--24, 26, and 27, 1993; chemicals measured were 6 major and 16 trace elements (including Hg, Cr, Cd, Pb, Se, As, Be, Ni), acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate), ammonia and cyanide, elemental C, radionuclides, VOCs, semivolatiles (incl. PAH, polychlorinated dioxins, furans), and aldehydes. Volume 2: Appendices includes process data log sheets, field sampling data sheets, uncertainty calculations, and quality assurance results.

  8. Development of a coal-fired combustion system for industrial process heating applications. Phase 3 final report, November 1992--December 1994

    SciTech Connect (OSTI)

    NONE

    1995-09-26T23:59:59.000Z

    A three phase research and development program has resulted in the development and commercialization of a Cyclone Melting System (CMS{trademark}), capable of being fueled by pulverized coal, natural gas, and other solid, gaseous, or liquid fuels, for the vitrification of industrial wastes. The Phase 3 research effort focused on the development of a process heater system to be used for producing value added glass products from the vitrification of boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project was to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential for successful commercialization. The demonstration test consisted of one test run with a duration of 105 hours, approximately one-half (46 hours) performed with coal as the primary fuel source (70% to 100%), the other half with natural gas. Approximately 50 hours of melting operation were performed vitrifying approximately 50,000 lbs of coal-fired utility boiler flyash/dolomite mixture, producing a fully-reacted vitrified product.

  9. PRELIMINARY CARBON DIOXIDE CAPTURE TECHNICAL AND ECONOMIC FEASIBILITY STUDY EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Envergex, Srivats; Browers, Bruce; Thumbi, Charles

    2013-01-01T23:59:59.000Z

    Barr Engineering Co. was retained by the Institute for Energy Studies (IES) at University of North Dakota (UND) to conduct a technical and economic feasibility analysis of an innovative hybrid sorbent technology (CACHYS™) for carbon dioxide (CO2) capture and separation from coal combustion–derived flue gas. The project team for this effort consists of the University of North Dakota, Envergex LLC, Barr Engineering Co., and Solex Thermal Science, along with industrial support from Allete, BNI Coal, SaskPower, and the North Dakota Lignite Energy Council. An initial economic and feasibility study of the CACHYS™ concept, including definition of the process, development of process flow diagrams (PFDs), material and energy balances, equipment selection, sizing and costing, and estimation of overall capital and operating costs, is performed by Barr with information provided by UND and Envergex. The technology—Capture from Existing Coal-Fired Plants by Hybrid Sorption Using Solid Sorbents Capture (CACHYS™)—is a novel solid sorbent technology based on the following ideas: reduction of energy for sorbent regeneration, utilization of novel process chemistry, contactor conditions that minimize sorbent-CO2 heat of reaction and promote fast CO2 capture, and a low-cost method of heat management. The technology’s other key component is the use of a low-cost sorbent.

  10. Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semiannual technical report, January 14, 1997--August 14, 1997

    SciTech Connect (OSTI)

    Schorr, B.S.; Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1997-08-31T23:59:59.000Z

    Research is presently being conducted to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The research will be accomplished by producing model cermet composites using powder metallurgy and electrodeposition methods in which the effect of ceramic/metal combination for the erosion and corrosion resistance will be determined. These results will provide the basis for determining the optimum hard phase constituent size and volume percent in thermal spray coatings. Thermal spray coatings will be applied by our industrial sponsor and tested in our erosion and corrosion laboratories. Bulk powder processed Ni-Al{sub 2}O{sub 3} composites were produced at Idaho National Engineering Laboratory. The composite samples contained 0, 21, 27, 37, and 45 volume percent Al{sub 2}O{sub 3} with an average particle size of 12 um. Also, to deposit model Ni-Al{sub 2}O{sub 3} coatings, an electrodeposition technique was developed and coatings with various volume fractions (0-35%) of Al{sub 2}O{sub 3} were produced. The powder and electrodeposition processing of Ni-Al{sub 2}O{sub 3} Composites provide the ability to produce two phase microstructure without changing the microstructure of the matrix material. Therefore, the effect of hard second phase particles size and volume fraction on erosion resistance could be analyzed.

  11. A study of toxic emissions from a coal-fired power plant: Niles Station Boiler No. 2. Volume 1, Sampling/results/special topics: Final report

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    This study was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for US Department of Energy, Pittsburgh Energy Technology Center (DOE-PETC) during 1993. The motivation for those assessments was the mandate in the 1990 Clean Air Act Amendments that a study be made of emissions of hazardous air pollutants (HAPs) from electrical utilities. The results of this study will be used by the US Environmental Protection Agency to evaluate whether regulation of HAPs emissions from utilities is warranted. This report is organized in two volumes. Volume 1: Sampling/Results/Special Topics describes the sampling effort conducted as the basis for this study, presents the concentration data on toxic chemicals in the several power plant streams, and reports the results of evaluations and calculations conducted with those data. The Special Topics section of Volume 1 reports on issues such as comparison of sampling methods and vapor/particle distributions of toxic chemicals. Volume 2: Appendices include field sampling data sheets, quality assurance results, and uncertainty calculations. The chemicals measured at Niles Boiler No. 2 were the following: five major and 16 trace elements, including mercury, chromium, cadmium, lead, selenium, arsenic, beryllium, and nickel; acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate); ammonia and cyanide; elemental carbon; radionuclides; volatile organic compounds (VOC); semivolatile compounds (SVOC) including polynuclear aromatic hydrocarbons (PAH), and polychlorinated dioxins and furans; and aldehydes.

  12. A study of toxic emissions from a coal-fired power plant utilizing an ESP while demonstrating the ICCT CT-121 FGD Project. Final report

    SciTech Connect (OSTI)

    Not Available

    1994-06-16T23:59:59.000Z

    The US Department of Energy is performing comprehensive assessments of toxic emissions from eight selected coal-fired electric utility units. This program responds to the Clean Air Act Amendments of 1990, which require the US Environmental Protection Agency (EPA) to evaluate emissions of hazardous air pollutants (HAPs) from electric utility power plants for Potential health risks. The resulting data will be furnished to EPA utility power plants and health risk determinations. The assessment of emissions involves the collection and analysis of samples from the major input, process, and output streams of each of the eight power plants for selected hazardous Pollutants identified in Title III of the Clean Air Act. Additional goals are to determine the removal efficiencies of pollution control subsystems for these selected pollutants and the Concentrations associated with the particulate fraction of the flue gas stream as a function of particle size. Material balances are being performed for selected pollutants around the entire power plant and several subsystems to identify the fate of hazardous substances in each utility system. Radian Corporation was selected to perform a toxics assessment at a plant demonstrating an Innovative Clean Coal Technology (ICCT) Project. The site selected is Plant Yates Unit No. 1 of Georgia Power Company, which includes a Chiyoda Thoroughbred-121 demonstration project.

  13. AFBC co-firing of coal and hospital waste: Quarterly report, 1 May 1996-31 July, 1996

    SciTech Connect (OSTI)

    Stuart, J.M.

    1996-12-31T23:59:59.000Z

    The project objective is to design, construct, install, provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation while providing efficient destruction of both general and infectious hospital waste. This quarterly report describes activities completed in the design, procure, install and start-up phase.

  14. AFBC co-firing of coal and hospital waste. Quarterly progress report, August 1--October 31, 1996

    SciTech Connect (OSTI)

    NONE

    1997-06-01T23:59:59.000Z

    The project objective is to design, construct, install, provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation while providing efficient destruction of both general and infectious hospital waste. The steam generated as follows: (1) Steam = 20,000 lb/hr, (2) Temperature = 353 F (saturated), (3) Pressure = 125 psig, and (4) Steam quality = {approximately}98.5%.

  15. INSTRUMENTATION DEVELOPMENT, MEASUREMENT AND PERFORMANCE EVALUATION OF ENVIRONMENTAL TECHNOLOGIES

    SciTech Connect (OSTI)

    Unknown

    2001-07-01T23:59:59.000Z

    Biomass gasification offers a practical way to use this locally available fuel source for co-firing traditional large utility boilers. The gasification process converts biomass into a low Btu producer gas that can be fed directly into the boiler. This strategy of co-firing is compatible with a variety of conventional boilers including natural gas fired boilers as well as pulverized coal fired and cyclone boilers. Gasification has the potential to address all problems associated with the other types of co-firing with minimum modifications to the existing boiler systems. Gasification can also utilize biomass sources that have been previously unsuitable due to size or processing requirements, facilitating a reduction in the primary fossil fuel consumption in the boiler and thereby reducing the greenhouse gas emissions to the atmosphere.

  16. Effect of Using Inert and Non-Inert Gases on the Thermal Degradation and Fuel Properties of Biomass in the Torrefaction and Pyrolysis Region 

    E-Print Network [OSTI]

    Eseltine, Dustin E.

    2012-02-14T23:59:59.000Z

    to N? and Ar (which are entirely inert), making it better suited for use as a fuel for co-firing with coal or gasification. Three different biomasses were investigated: Juniper wood chips, Mesquite wood chips, and forage Sorghum. Experiments were...

  17. Effect of Using Inert and Non-Inert Gases on the Thermal Degradation and Fuel Properties of Biomass in the Torrefaction and Pyrolysis Region

    E-Print Network [OSTI]

    Eseltine, Dustin E.

    2012-02-14T23:59:59.000Z

    to N? and Ar (which are entirely inert), making it better suited for use as a fuel for co-firing with coal or gasification. Three different biomasses were investigated: Juniper wood chips, Mesquite wood chips, and forage Sorghum. Experiments were...

  18. THE LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS ON HUMAN HEALTH RISK. PROGRESS REPORT FOR THE PERIOD OF MARCH 2003 - MARCH 2003.

    SciTech Connect (OSTI)

    SULLIVAN,T.M.LIPFERT,F.D.MORRIS,S.M.

    2003-05-01T23:59:59.000Z

    This report presents a follow-up to previous assessments of the health risks of mercury that BNL performed for the Department of Energy. Methylmercury is an organic form of mercury that has been implicated as the form of mercury that impacts human health. A comprehensive risk assessment report was prepared (Lipfert et al., 1994) that led to several journal articles and conference presentations (Lipfert et al. 1994, 1995, 1996). In 2001, a risk assessment of mercury exposure from fish consumption was performed for 3 regions of the U.S (Northeast, Southeast, and Midwest) identified by the EPA as regions of higher impact from coal emissions (Sullivan, 2001). The risk assessment addressed the effects of in utero exposure to children through consumption of fish by their mothers. Two population groups (general population and subsistence fishers) were considered. Three mercury levels were considered in the analysis, current conditions based on measured data, and hypothetical reductions in Hg levels due to a 50% and 90% reduction in mercury emissions from coal fired power plants. The findings of the analysis suggested that a 90% reduction in coal-fired emissions would lead to a small reduction in risk to the general population (population risk reduction on the order of 10{sup -5}) and that the population risk is born by less than 1% of the population (i.e. high end fish consumers). The study conducted in 2001 focused on the health impacts arising from regional deposition patterns as determined by measured data and modeling. Health impacts were assessed on a regional scale accounting for potential percent reductions in mercury emissions from coal. However, quantitative assessment of local deposition near actual power plants has not been attempted. Generic assessments have been performed, but these are not representative of any single power plant. In this study, general background information on the mercury cycle, mercury emissions from coal plants, and risk assessment are provided to provide the basis for examining the impacts of local deposition. A section that covers modeling of local deposition of mercury emitted from coal power plants follows. The code ISCST3 was used with mercury emissions data from two power plants and local meteorological conditions to assess local deposition. The deposition modeling results were used to estimate the potential increase in mercury deposition that could occur in the vicinity of the plant. Increased deposition was assumed to lead to a linearly proportional increase in mercury concentrations in fish in local water bodies. Fish are the major pathway for human health impacts and the potential for increased mercury exposure was evaluated and the risks of such exposure estimated. Based on the findings recommendations for future work and conclusions are provided. Mercury is receiving substantial attention in a number of areas including: understanding of mercury deposition, bioaccumulation, and transport through the atmosphere, and improvements to the understanding of health impacts created by exposure to mercury. A literature review of key articles is presented as Appendix A.

  19. Design and Feasibility Assessment of a Retrospective Epidemiological Study of Coal-Fired Power Plant Emissions in the Pittsburgh Pennsylvania Region

    SciTech Connect (OSTI)

    Richard A. Bilonick; Daniel Connell; Evelyn Talbott; Jeanne Zborowski; Myoung Kim

    2006-12-20T23:59:59.000Z

    Eighty-nine (89) percent of the electricity supplied in the 35-county Pittsburgh region (comprising parts of the states of Pennsylvania, Ohio, West Virginia, and Maryland) is generated by coal-fired power plants making this an ideal region in which to study the effects of the fine airborne particulates designated as PM{sub 2.5} emitted by the combustion of coal. This report demonstrates that during the period from 1999-2006 (1) sufficient and extensive exposure data, in particular samples of speciated PM{sub 2.5} components from 1999 to 2003, and including gaseous co-pollutants and weather have been collected, (2) sufficient and extensive mortality, morbidity, and related health outcomes data are readily available, and (3) the relationship between health effects and fine particulates can most likely be satisfactorily characterized using a combination of sophisticated statistical methodologies including latent variable modeling (LVM) and generalized linear autoregressive moving average (GLARMA) time series analysis. This report provides detailed information on the available exposure data and the available health outcomes data for the construction of a comprehensive database suitable for analysis, illustrates the application of various statistical methods to characterize the relationship between health effects and exposure, and provides a road map for conducting the proposed study. In addition, a detailed work plan for conducting the study is provided and includes a list of tasks and an estimated budget. A substantial portion of the total study cost is attributed to the cost of analyzing a large number of archived PM{sub 2.5} filters. Analysis of a representative sample of the filters supports the reliability of this invaluable but as-yet untapped resource. These filters hold the key to having sufficient data on the components of PM{sub 2.5} but have a limited shelf life. If the archived filters are not analyzed promptly the important and costly information they contain will be lost.

  20. ENGINEERING FEASIBILITY AND ECONOMICS OF CO2 SEQUESTRATION/USE ON AN EXISTING COAL-FIRED POWER PLANT: A LITERATURE REVIEW

    SciTech Connect (OSTI)

    Carl R. Bozzuto; Nsakala ya Nsakala

    2000-01-31T23:59:59.000Z

    The overall objective of this study is to evaluate the technical feasibility and the economics of alternate CO{sub 2} capture and sequestration/use technologies for retrofitting an existing pulverized coal-fired power plant. To accomplish this objective three alternative CO{sub 2} capture and sequestration systems will be evaluated to identify their impact on an existing boiler, associated boiler auxiliary components, overall plant operation and performance and power plant cost, including the cost of electricity. The three retrofit technologies that will be evaluated are as follows: (1) Coal combustion in air, followed by CO{sub 2} separation from flue gas with Kerr-McGee/ABB Lummus Global's commercial MEA-based absorption/stripping process. (2) Coal combustion in an O{sub 2}/CO{sub 2} environment with CO{sub 2} recycle. (3) Coal combustion in air with oxygen removal and CO{sub 2} captured by tertiary amines In support of this objective and execution of the evaluation of the three retrofit technologies a literature survey was conducted. It is presented in an ''annotated'' form, consistent with the following five sections: (1) Coal Combustion in O{sub 2}/CO{sub 2} Media; (2) Oxygen Separation Technologies; (3) Post Combustion CO{sub 2} Separation Technologies; (4) Potential Utilization of CO{sub 2}; and (5) CO{sub 2} Sequestration. The objective of the literature search was to determine if the three retrofit technologies proposed for this project continue to be sound choices. Additionally, a review of the literature would afford the opportunity to determine if other researchers have made significant progress in developing similar process technologies and, in that context, to revisit the current state-of-the-art. Results from this literature survey are summarized in the report.

  1. SAMPLING, ANALYSIS, AND PROPERTIES OF PRIMARY PM-2.5: APPLICATION TO COAL-FIRED UTILITY BOILERS

    SciTech Connect (OSTI)

    Allen L. Robinson; Spyros N. Pandis; Eric Lipsky; Charles Stainer; Natalie Anderson; Satoshi Takahama; Sarah Rees

    2003-02-01T23:59:59.000Z

    A dilution sampler was used to examine the effects of dilution ratio and residence time on the particulate emissions from a pilot-scale pulverized coal combustor. Measurements include the particle size distribution from 0.003 to 2.5 {micro}m, PM{sub 2.5} mass emission rate and PM2.5 composition (OC/EC, major ions, and elemental). Hot filter samples were also collected simultaneously in order to compare the dilution sampler measurement with standard stack sampling methodologies such as EPA Method 5. Measurements were made both before and after the bag-house, the particle control device used on the coal combustor. Measurements were made with three different coal types and a coal-biomass blend. The residence time and dilution ratio do not influence the PM{sub 2.5} mass emission rate, but have a significant effect on the size distribution and total number emissions. Measurements made before the bag-house showed increasing the residence time dramatically decreases the total particle number concentration, and shifts the particle mass to larger sizes. The effects of residence time can be explained quantitatively by the coagulation of the emitted particles. Measurements made after the bag-house were not affected by coagulation due to the lower concentration of particles. Nucleation of sulfuric acid vapor within the dilution was an important source of ultrafine particles. This nucleation is strongly a function of dilution ratio because of the competition between condensation and nucleation. At low dilution ratios condensation dominates and little nucleation is observed; increasing the dilution ratio promotes nucleation because of the corresponding decrease in available surface area per unit volume for condensation. No nucleation was observed after the bag house where conditions greatly favor nucleation over condensation; we suspect that the bag house removed the SO{sub 3} in the flue gas. Exhaust SO{sub 3} levels were not measured during these experiments. Dilution caused the enrichment of selenium, ammonium and sulfate in the PM{sub 2.5} emissions compared to the hot filter samples. The enrichment of selenium was independent of dilution ratio or residence time. The enrichment of ammonium and sulfate increased with increasing dilution ratio. PM{sub 2.5} emission profiles for four different fuels (two eastern bituminous coals, a western sub-bituminous coal, and coal-wood blend) were developed. These profiles compared well with profiles from similar coal sources, while showing unique characteristics due to differences in fuel composition.

  2. Evaluation of AFBC co-firing of coal and hospital wastes. Technical report, January 1989--August 1990

    SciTech Connect (OSTI)

    Not Available

    1991-02-01T23:59:59.000Z

    The purpose of this program is to expand the use of coal by utilizing CFB (circulating fluidized bed) technology to provide an environmentally safe method for disposing of waste materials. Hospitals are currently experiencing a waste management crisis. In many instances, they are no longer permitted to burn pathological and infectious wastes in incinerators. Older hospital incinerators are not capable of maintaining the stable temperatures and residence times necessary in order to completely destroy toxic substances before release into the atmosphere. In addition, the number of available landfills which can safely handle these substances is decreasing each year. The purpose of this project is to conduct necessary research investigating whether the combustion of the hospital wastes in a coal-fired circulating fluidized bed boiler will effectively destroy dioxins and other hazardous substances before release into the atmosphere. If this is proven feasible, in light of the quantity of hospital wastes generated each year, it would create a new market for coal -- possibly 50 million tons/year.

  3. Innovative Clean Coal Technology (ICCT): Demonstration of selective catalytic reduction technology for the control of nitrogen oxide emissions from high-sulfur coal-fired boilers. First and second quarterly technical progress reports, [January--June 1995]. Final report

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia (NH{sub 3}) into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor containing a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. (3) performance of a wide variety of SCR catalyst compositions, geometries, and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal. The demonstration is being performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW nameplate capacity) near Pensacola, Florida. The project is funded by the US Department of Energy (DOE), Southern Company Services, Inc. (SCS on behalf of the entire Southern electric system), the Electric Power Research Institute (EPRI), and Ontario Hydro. SCS is the participant responsible for managing all aspects of this project.

  4. Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Third quarterly technical progress report 1992

    SciTech Connect (OSTI)

    Not Available

    1992-11-01T23:59:59.000Z

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur, coal-fired boilers, there are several technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3} and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small- scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high-sulfur US coal. The demonstration will be performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW capacity) near Pensacola, Florida.

  5. Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO[sub x]) emissions from high-sulfur coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1992-11-01T23:59:59.000Z

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO[sub x]) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO[sub x] to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur, coal-fired boilers, there are several technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO[sub 2] and SO[sub 3] and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small- scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high-sulfur US coal. The demonstration will be performed at Gulf Power Company's Plant Crist Unit No. 5 (75 MW capacity) near Pensacola, Florida.

  6. Innovative Clean Coal Technology (ICCT). Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers: Volume 1. Final report

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO.) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO. to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal- fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: 1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels. 2) performance of the technology and effects on the balance-of- plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. 3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacturer under typical high-sulfur coal-fired utility operating conditions. These uncertainties were explored by operating nine small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. In addition, the test facility operating experience provided a basis for an economic study investigating the implementation of SCR technology.

  7. Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, first and second quarters 1994

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involve injecting ammonia into the flue gas generated from coal combustion in a boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The project is being conducted in the following three phases: permitting, environmental monitoring plan and preliminary engineering; detailed design engineering and construction; and operation, testing, disposition and final report. The project was in the operation and testing phase during this reporting period. Accomplishments for this period are described.

  8. Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semi-annual technical progress report, February 1996--July 1996

    SciTech Connect (OSTI)

    Banovic, S.W.; Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1996-08-01T23:59:59.000Z

    Present coal-fired boiler environments remain hostile to the materials of choice since corrosion and erosion can be a serious problem in certain regions of the boiler. Recently, the Clean Air Act Amendment is requiring electric power plants to reduce NO{sub x}, emissions to the environment. To reduce NO{sub x}, emissions, new low NO{sub x}, combustors are utilized which burn fuel with a substoichiometric amount of oxygen (i.e., low oxygen partial pressure). In these low NO{sub x} environments, H{sub 2}S gas is a major source of sulfur. Due to the sulfidation process, corrosion rates in reducing parts of boilers have increased significantly and existing boiler tube materials do not always provide adequate corrosion resistance. Combined attack due to corrosion and erosion is a concern because of the significantly increased operating costs which result in material failures. One method to combat corrosion and erosion in coal-fired boilers is to apply coatings to the components subjected to aggressive environments. Thermal spray coatings, a cermet composite comprised of hard ceramic phases of oxide and/or carbide in a metal binder, have been used with some success as a solution to the corrosion and erosion problems in boilers. However, little is known on the effect of the volume fraction, size, and shape of the hard ceramic phase on the erosion and corrosion resistance of the thermally sprayed coatings. It is the objective of this research to investigate metal matrix composite (cermet) coatings in order to determine the optimum ceramic/metal combination that will give the best erosion and corrosion resistance in new advanced coal-fired boilers.

  9. Biopower Report Presents Methodology for Assessing the Value of Co-Firing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platform isEnergyMeeting |Resources » Energy Resource Library »Biomass in

  10. BPACK -- A computer model package for boiler reburning/co-firing performance evaluations. User`s manual, Volume 1

    SciTech Connect (OSTI)

    Wu, K.T.; Li, B.; Payne, R.

    1992-06-01T23:59:59.000Z

    This manual presents and describes a package of computer models uniquely developed for boiler thermal performance and emissions evaluations by the Energy and Environmental Research Corporation. The model package permits boiler heat transfer, fuels combustion, and pollutant emissions predictions related to a number of practical boiler operations such as fuel-switching, fuels co-firing, and reburning NO{sub x} reductions. The models are adaptable to most boiler/combustor designs and can handle burner fuels in solid, liquid, gaseous, and slurried forms. The models are also capable of performing predictions for combustion applications involving gaseous-fuel reburning, and co-firing of solid/gas, liquid/gas, gas/gas, slurry/gas fuels. The model package is conveniently named as BPACK (Boiler Package) and consists of six computer codes, of which three of them are main computational codes and the other three are input codes. The three main codes are: (a) a two-dimensional furnace heat-transfer and combustion code: (b) a detailed chemical-kinetics code; and (c) a boiler convective passage code. This user`s manual presents the computer model package in two volumes. Volume 1 describes in detail a number of topics which are of general users` interest, including the physical and chemical basis of the models, a complete description of the model applicability, options, input/output, and the default inputs. Volume 2 contains a detailed record of the worked examples to assist users in applying the models, and to illustrate the versatility of the codes.

  11. Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Fourth quarterly progress report

    SciTech Connect (OSTI)

    NONE

    1992-12-31T23:59:59.000Z

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal.

  12. Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 4, April--June 1991

    SciTech Connect (OSTI)

    Not Available

    1991-08-01T23:59:59.000Z

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor, Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuel performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal.

  13. PARTICULATE CHARACTERIZATION AND ULTRA LOW-NOx BURNER FOR THE CONTROL OF NO{sub x} AND PM{sub 2.5} FOR COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Ralph Bailey; Hamid Sarv; Jim Warchol; Debi Yurchison

    2001-09-30T23:59:59.000Z

    In response to the serious challenge facing coal-fired electric utilities with regards to curbing their NO{sub x} and fine particulate emissions, Babcock and Wilcox and McDermott Technology, Inc. conducted a project entitled, ''Particulate Characterization and Ultra Low-NO{sub x} Burner for the Control of NO{sub x} and PM{sub 2.5} for Coal Fired Boilers.'' The project included pilot-scale demonstration and characterization of technologies for removal of NO{sub x} and primary PM{sub 2.5} emissions. Burner development and PM{sub 2.5} characterization efforts were based on utilizing innovative concepts in combination with sound scientific and fundamental engineering principles and a state-of-the-art test facility. Approximately 1540 metric tonnes (1700 tons) of high-volatile Ohio bituminous coal were fired. Particulate sampling for PM{sub 2.5} emissions characterization was conducted in conjunction with burner testing. Based on modeling recommendations, a prototype ultra low-NO{sub x} burner was fabricated and tested at 100 million Btu/hr in the Babcock and Wilcox Clean Environment Development Facility. Firing the unstaged burner with a high-volatile bituminous Pittsburgh 8 coal at 100 million Btu/hr and 17% excess air achieved a NO{sub x} goal of 0.20 lb NO{sub 2}/million Btu with a fly ash loss on ignition (LOI) of 3.19% and burner pressure drop of 4.7 in H{sub 2}O for staged combustion. With the burner stoichiometry set at 0.88 and the overall combustion stoichiometry at 1.17, average NO{sub x} and LOI values were 0.14 lb NO{sub 2}/million Btu and 4.64% respectively. The burner was also tested with a high-volatile Mahoning 7 coal. Based on the results of this work, commercial demonstration is being pursued. Size classified fly ash samples representative of commercial low-NO{sub x} and ultra low-NO{sub x} combustion of Pittsburgh 8 coal were collected at the inlet and outlet of an ESP. The mass of size classified fly ash at the ESP outlet was sufficient to evaluate the particle size distribution, but was of insufficient size to permit reliable chemical analysis. The size classified fly ash from the inlet of the ESP was used for detailed chemical analyses. Chemical analyses of the fly ash samples from the ESP outlet using a high volume sampler were performed for comparison to the size classified results at the inlet. For all test conditions the particulate removal efficiency of the ESP exceeded 99.3% and emissions were less than the NSPS limits of {approx}48 mg/dscm. With constant combustion conditions, the removal efficiency of the ESP increased as the ESP voltage and Specific Collection Area (SCA) increased. The associated decrease in particle emissions occurred in size fractions both larger and smaller than 2.5 microns. For constant ESP voltage and SCA, the removal efficiency for the ultra low-NO{sub x} combustion ash (99.4-99.6%) was only slightly less than for the low-NO{sub x} combustion ash (99.7%). The decrease in removal efficiency was accompanied by a decrease in ESP current. The emission of PM{sub 2.5} from the ESP did not change significantly as a result of the change in combustion conditions. Most of the increase in emissions was in the size fraction greater than 2.5 microns, indicating particle re-entrainment. These results may be specific to the coal tested in this program. In general, the concentration of inorganic elements and trace species in the fly ash at the ESP inlet was dependent on the particle size fraction. The smallest particles tended to have higher concentrations of inorganic elements/trace species than larger particles. The concentration of most elements by particle size range was independent of combustion condition and the concentration of soluble ions in the fly ash showed little change with combustion condition when evaluated on a carbon free basis.

  14. Field Test Program for Long-Term Operation of a COHPAC System for Removing Mercury from Coal-Fired Flue Gas

    SciTech Connect (OSTI)

    C. Jean Bustard; Charles Lindsey; Paul Brignac

    2006-05-01T23:59:59.000Z

    This document provides a summary of the full-scale demonstration efforts involved in the project ''Field Test Program for Long-Term Operation of a COHPAC{reg_sign} System for Removing Mercury from Coal-Fired Flue Gas''. The project took place at Alabama Power's Plant Gaston Unit 3 and involved the injection of sorbent between an existing particulate collector (hot-side electrostatic precipitators) and a COHPAC{reg_sign} fabric filter (baghouse) downstream. Although the COHPAC{reg_sign} baghouse was designed originally for polishing the flue gas, when activated carbon injection was added, the test was actually evaluating the EPRI TOXECON{reg_sign} configuration. The results from the baseline tests with no carbon injection showed that the cleaning frequency in the COHPAC{reg_sign} unit was much higher than expected, and was above the target maximum cleaning frequency of 1.5 pulses/bag/hour (p/b/h), which was used during the Phase I test in 2001. There were times when the baghouse was cleaning continuously at 4.4 p/b/h. In the 2001 tests, there was virtually no mercury removal at baseline conditions. In this second round of tests, mercury removal varied between 0 and 90%, and was dependent on inlet mass loading. There was a much higher amount of ash exiting the electrostatic precipitators (ESP), creating an inlet loading greater than the design conditions for the COHPAC{reg_sign} baghouse. Tests were performed to try to determine the cause of the high ash loading. The LOI of the ash in the 2001 baseline tests was 11%, while the second baseline tests showed an LOI of 17.4%. The LOI is an indication of the carbon content in the ash, which can affect the native mercury uptake, and can also adversely affect the performance of ESPs, allowing more ash particles to escape the unit. To overcome this, an injection scheme was implemented that balanced the need to decrease carbon injection during times when inlet loading to the baghouse was high and increase carbon injection when inlet loading and mercury removal were low. The resulting mercury removal varied between 50 and 98%, with an overall average of 85.6%, showing that the process was successful at removing high percentages of vapor-phase mercury even with a widely varying mass loading. In an effort to improve baghouse performance, high-permeability bags were tested. The new bags made a significant difference in the cleaning frequency of the baghouse. Before changing the bags, the baghouse was often in a continuous clean of 4.4 p/b/h, but with the new bags the cleaning frequency was very low, at less than 1 p/b/h. Alternative sorbent tests were also performed using these high-permeability bags. The results of these tests showed that most standard, high-quality activated carbon performed similarly at this site; low-cost sorbent and ash-based sorbents were not very effective at removing mercury; and chemically enhanced sorbents did not appear to offer any benefits over standard activated carbons at this site.

  15. Biomass power for rural development. Quarterly report, July 3--December 4, 1997

    SciTech Connect (OSTI)

    Cooper, J.T.

    1998-03-01T23:59:59.000Z

    This paper describes progress in several projects related to biomass power. These include switchgrass conversion development; switchgrass gasification development; production activities including soil studies, carbon studies, switchgrass production economics, watershed impacts, and prairie lands bio-products; information and education; and geographical information system. Attachments describe switchgrass co-firing test; switchgrass production in Iowa; cooperative agreements with ISU; Rathbun Lake watershed project; newspaper articles and information publications; Secretary of Agriculture Glickman`s visit; integration of technical aspects of switchgrass production in Iowa; and evaluation of an integrated biomass gasification/fuel cell power plant.

  16. A survey of state clean energy fund support for biomass

    SciTech Connect (OSTI)

    Fitzgerald, Garrett; Bolinger, Mark; Wiser, Ryan

    2004-08-20T23:59:59.000Z

    This survey reviews efforts by CESA member clean energy funds to promote the use of biomass as a renewable energy source. For each fund, details are provided regarding biomass eligibility for support, specific programs offering support to biomass projects, and examples of supported biomass projects (if available). For the purposes of this survey, biomass is defined to include bio-product gasification, combustion, co-firing, biofuel production, and the combustion of landfill gas, though not all of the programs reviewed here take so wide a definition. Programs offered by non-CESA member funds fall outside the scope of this survey. To date, three funds--the California Energy Commission, Wisconsin Focus on Energy, and the New York State Energy Research and Development Authority--have offered programs targeted specifically at the use of biomass as a renewable energy source. We begin by reviewing efforts in these three funds, and then proceed to cover programs in other funds that have provided support to biomass projects when the opportunity has arisen, but otherwise do not differentially target biomass relative to other renewable technologies.

  17. Co-firing High Sulfur Coal with Refuse Derived Fuels. Technical Progress Report {number_sign}11

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, John T.; Lloyd, William G.

    1997-05-31T23:59:59.000Z

    The objective of this quarter of study was to prepare fuel pellets containing PVC, newspaper and plastics to be co-fired with coal in the AFBC combustor. The Western Kentucky University atmospheric fluidized bed combustion system requires the fuel to fall from a bunker into a lock-hopper, and from there into a mixing box where the fuel is auger-fed under pressure into the bottom of the fluidized bed. The fuel must flow freely out of the bunker and through the lock- hopper for proper feeding into the combustor. In order for the fuel to continuously fall through these units and into the mixing box during combustion, the density of the fuel and the size of the particles must meet certain requirements. The particles must be no larger than 3/8 inches in diameter and must have a density approaching that of coal. Loose materials such as sawdust, shredded paper products and most shredded plastics do not feed properly in the WKU AFBC system. Bridging and blockage of feed chutes result, even with constant vibration of parts of the feed mechanism. It is not possible to run the AFBC system powered solely by these loose materials.

  18. AFBC co-firing of coal and hospital waste. Quarterly progress report, February 1, 1995--April 30, 1995

    SciTech Connect (OSTI)

    Stuart, J.M.

    1996-01-01T23:59:59.000Z

    The project objective is to design, construct, install, provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing inexpensive and efficient destruction of both general and infectious hospital waste and steam generation. The steam generated is as follows: (1) Steam = 20,000 lb/hr, (2) Temperature = 353 F (saturated), (3) Pressure = 125 psig, and (4) Steam quality ={approximately}98.5%. On February 3, 1995 DONLEE notified Lebanon VA and DOE-METC that additional funding would be required to complete the project. This funding, in the amount of $1,140,127, is needed to complete the facility, start-up and shakedown the facility, perform the test program and write the final report. On March 7, 1995 the vendors were notified that the Lebanon VA Steam Plant Project was shut down and that all work outside DONLEE was stopped pending obtaining additional funding.

  19. AFBC co-firing of coal and hospital waste. Quarterly progress report, May 1--July 31, 1995

    SciTech Connect (OSTI)

    Stuart, J.M.

    1995-12-31T23:59:59.000Z

    The project objective is to design, construct, install, provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon, Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation. This would permit full capacity operation of the FBC year round in spite of the VA laundry that was shut down as well as efficient destruction of both general and infectious hospital waste and steam generation. On February 3, 1995 Donlee notified Lebanon VA and DOE-METC that additional funding would be required to complete the project. This funding, in the amount of $1,140,127, is needed to complete the facility, start-up and shakedown the facility, perform the test program and write the final report. After review DOE-METC approved funding in the amount of $1,246,019 to be available August 1, 1995. This report describes each task of the project and its status.

  20. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Public design report (preliminary and final)

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    This Public Design Report presents the design criteria of a DOE Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of NO{sub x} emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 (500 MW) near Rome, Georgia. The technologies being demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NO{sub x} burner. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NO{sub x} burners, advanced overfire systems, and digital control system.

  1. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Quarterly progress report No. 7, July--September 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-01T23:59:59.000Z

    A concept for an advanced coal-fired combined-cycle power generating system is currently being developed. The first phase of this three-phase program consists of conducting the necessary research and development to define the system, evaluating the economic and technical feasibility of the concept, and preparing an R&D plan to develop the concept further. Foster Wheeler Development Corporation (FWDC) is leading a team of companies involved in this effort. The power generating system being developed in this project will be an improvement over current coal-fired systems. Goals have been specified that relate to the efficiency, emissions, costs, and general operation of the system. The system proposed to meet these goals is a combined-cycle system where air for a gas turbine is indirectly heated to approximately 1800{degrees}F in furnaces fired with coal-derived fuels and then directly heated in a natural-gas-fired combustor to about 2400{degrees}F. The system is based on a pyrolyzing process that converts the coal into a low-Btu fuel gas and char. The fuel gas is relatively clean, and it is fired to heat tube surfaces that are susceptible to corrosion and problems from ash deposition. In particular, the high-temperature air heater tubes, which will need to be a ceramic material, will be located in a separate furnace or region of a furnace that is exposed to combustion products from the low-Btu fuel gas only. A simplified process flow diagram is shown in Figure 1.

  2. Co-firing a pressurized fluidized-bed combustion system with coal and refuse derived fuels and/or sludges. Task 16

    SciTech Connect (OSTI)

    DeLallo, M.; Zaharchuk, R.

    1994-01-01T23:59:59.000Z

    The co-firing of waste materials with coal in utility scale power plants has emerged as an effective approach to produce energy and manage municipal waste. Leading this approach, the atmospheric fluidized-bed combustor (AFBC) has demonstrated its commercial acceptance in the utility market as a reliable source of power burning a variety of waste and alternative fuels. The fluidized bed, with its stability of combustion, reduces the amount of thermochemical transients and provides for easier process control. The application of pressurized fluidized-bed combustor (PFBC) technology, although relatively new, can provide significant enhancements to the efficient production of electricity while maintaining the waste management benefits of AFBC. A study was undertaken to investigate the technical and economic feasibility of co-firing a PFBC with coal and municipal and industrial wastes. Focus was placed on the production of electricity and the efficient disposal of wastes for application in central power station and distributed locations. Wastes considered for co-firing include municipal solid waste (MSW), tire-derived fuel (TDF), sewage sludge, and industrial de-inking sludge. Issues concerning waste material preparation and feed, PFBC operation, plant emissions, and regulations are addressed. This paper describes the results of this investigation, presents conclusions on the key issues, and provides recommendations for further evaluation.

  3. EA-1850: Flambeau River BioFuels, Inc. Proposed Wood Biomass-to-Liquid Fuel Biorefinery, Park Falls, Wisconsin

    Broader source: Energy.gov [DOE]

    NOTE: This EA has been cancelled. This EA will evaluate the environmental impacts of a proposal to provide federal funding to Flambeau River Biofuels (FRB) to construct and operate a biomass-to-liquid biorefinery in Park Falls, Wisconsin, on property currently used by Flambeau Rivers Paper, LLC (FRP) for a pulp and paper mill and Johnson Timber Corporation's (JTC) Summit Lake Yard for timber storage. This project would design a biorefinery which would produce up to 1,150 barrels per day (bpd) of clean syncrude. The biorefinery would also supply steam to the FRP mill, meeting the majority of the mill's steam demand and reducing or eliminating the need for the existing biomass/coal-fired boiler. The biorefinery would also include a steam turbine generator that will produce "green" electrical power for use by the biorefinery or for sale to the electric utility.

  4. Biomass pretreatment

    DOE Patents [OSTI]

    Hennessey, Susan Marie; Friend, Julie; Elander, Richard T; Tucker, III, Melvin P

    2013-05-21T23:59:59.000Z

    A method is provided for producing an improved pretreated biomass product for use in saccharification followed by fermentation to produce a target chemical that includes removal of saccharification and or fermentation inhibitors from the pretreated biomass product. Specifically, the pretreated biomass product derived from using the present method has fewer inhibitors of saccharification and/or fermentation without a loss in sugar content.

  5. PROSPECTS FOR CO-FIRING OF CLEAN COAL AND CREOSOTE-TREATED WASTE WOOD AT SMALL-SCALE POWER STATIONS

    E-Print Network [OSTI]

    Janis Zandersons; Aivars Zhurinsh; Edward Someus

    If a small-scale clean coal fu eled power plant is co-fu eled with 5 % of cre o-sote-treated used-up sleeper wood, the de con tam i na tion by carbonisation at 500 °C in an in di rectly heated ro tary kiln with the di am e ter 1.7 m and ef fec-tive length 10 m can be real ised. It should be in cluded in the “3R Clean Coal Carbonisation Plant ” sys tem, which pro cesses coal. It will im prove the heat bal ance of the sys tem, since the carbonisation of wood will de liver a lot of high caloricity pyroligneous vapour to the joint fur nace of the “3R Clean Coal Carbonisation Plant”. Pine wood sleeper sap wood con tains 0.25 % of sul phur, but the av er age pine sleeper wood (sap wood and heart wood) 0.05% of sul phur. Most of the sul phur is lost with the pyroligneous vapour and burned in the fur nace. Since the “3R Clean Coal Carbonisation Plant ” is equipped with a flue gases clean ing sys tem, the SO2 emis sion level will not ex-ceed 5 mg/m 3. The char coal of the sap wood por tion of sleep ers and that of the av er age sleeper wood will con tain 0.22 % and 0.035 % of sul phur, re spec-tively. The in crease of the carbonisation tem per a ture does not sub stan tially de crease the sul phur con tent in char coal, al though it is suf fi ciently low, and the char coal can be co-fired with clean coal. The con sid ered pro cess is suit-able for small power plants, if the bio mass in put in the com mon en ergy bal-ance is 5 to 10%. If the mean dis tance of sleep ers trans por ta tion for Cen tral and East ern Eu-rope is es ti mated not to ex ceed 200 km, the co-com bus tion of clean coal and carbonised sleep ers would be an ac cept able op tion from the en vi ron men tal and eco nomic points of view.

  6. CATALYTIC BIOMASS LIQUEFACTION

    E-Print Network [OSTI]

    Ergun, Sabri

    2013-01-01T23:59:59.000Z

    Solvent Systems Catalystic Biomass Liquefaction Investigatereactor Product collection Biomass liquefaction process12-13, 1980 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,

  7. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1992-11-25T23:59:59.000Z

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

  8. Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semiannual technical progress report, August 14, 1996--January 14, 1997

    SciTech Connect (OSTI)

    Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1997-02-01T23:59:59.000Z

    Research is presently being conducted to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The research will be accomplished by producing model cermet composites using powder metallurgy and electrodeposition methods in which the effect of ceramic/metal combination for the erosion and corrosion resistance will be determined. These results will provide the basis for determining the optimum hard phase constituent size and volume percent in thermal spray coatings. Thermal spray coatings will be applied by our industrial sponsor and tested in our erosion and corrosion laboratories. In the first six months of this project, bulk powder processed Ni-Al{sub 2}O{sub 3} composites were produced at Idaho National Engineering Laboratory. The results of microstructural characterization of these alloys were presented in the first semiannual report. The composite samples contained 0, 21, 27, 37, and 45 volume percent Al{sub 2}O{sub 3} with an average particle size of 12 um. An increase in the volume fraction of alumina in the nickel matrix from 0 to 45% led to a significant increase in hardness of these composites.

  9. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1992-02-03T23:59:59.000Z

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company's Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an Advanced Overfire Air (AOFA) system followed by Low NO{sub x} Burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

  10. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, third quarter 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-03T23:59:59.000Z

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an Advanced Overfire Air (AOFA) system followed by Low NO{sub x} Burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

  11. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Fourth quarterly technical progress report, [October--December, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    This quarterly report discusses the technical progress of a U. S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. During this quarter, tests of the LNCFS Level III system were conducted to determine the effect that fuel fineness has on NOx emissions and unburned carbon levels. Results showed that changing the fineness of the fuel has almost no effect on NOx emissions; however, unburned carbon levels can be reduced significantly by increasing fuel fineness.

  12. AGCO Biomass Solutions: Biomass 2014 Presentation

    Broader source: Energy.gov [DOE]

    Plenary IV: Advances in Bioenergy Feedstocks—From Field to Fuel AGCO Biomass Solutions: Biomass 2014 Presentation Glenn Farris, Marketing Manager Biomass, AGCO Corporation

  13. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Topical report, LNCFS Levels 1 and 3 test results

    SciTech Connect (OSTI)

    Not Available

    1993-08-17T23:59:59.000Z

    This report presents results from the third phase of an Innovative Clean Coal Technology (ICC-1) project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The purpose of this project was to study the NO{sub x} emissions characteristics of ABB Combustion Engineering`s (ABB CE) Low NO{sub x} Concentric Firing System (LNCFS) Levels I, II, and III. These technologies were installed and tested in a stepwise fashion at Gulf Power Company`s Plant Lansing Smith Unit 2. The objective of this report is to provide the results from Phase III. During that phase, Levels I and III of the ABB C-E Services Low NO{sub x} Concentric Firing System were tested. The LNCFS Level III technology includes separated overfire air, close coupled overfire air, clustered coal nozzles, flame attachment coal nozzle tips, and concentric firing. The LNCFS Level I was simulated by closing the separated overfire air nozzles of the LNCFS Level III system. Based upon long-term data, LNCFS Level HI reduced NO{sub x} emissions by 45 percent at full load. LOI levels with LNCFS Level III increased slightly, however, tests showed that LOI levels with LNCFS Level III were highly dependent upon coal fineness. After correcting for leakage air through the separated overfire air system, the simulated LNCFS Level I reduced NO{sub x} emissions by 37 percent. There was no increase in LOI with LNCFS Level I.

  14. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, second quarter 1992

    SciTech Connect (OSTI)

    Not Available

    1992-11-25T23:59:59.000Z

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

  15. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, first quarter 1992

    SciTech Connect (OSTI)

    Not Available

    1992-05-20T23:59:59.000Z

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progess report presents the LNCFS Level III long-term data collected during this quarter. NO{sub x} emissions for each day of long-term testing are presented. The average NO{sub x} emission during long-term testing was 0.39 lb/MBtu at an average load of 155 MW. The effect of the low NO{sub x} combustion system on other combustion parameters such as carbon monoxide, excess oxygen level, and carbon carryover are also included.

  16. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1992-05-20T23:59:59.000Z

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progess report presents the LNCFS Level III long-term data collected during this quarter. NO[sub x] emissions for each day of long-term testing are presented. The average NO[sub x] emission during long-term testing was 0.39 lb/MBtu at an average load of 155 MW. The effect of the low NO[sub x] combustion system on other combustion parameters such as carbon monoxide, excess oxygen level, and carbon carryover are also included.

  17. Measurement of vapor phase mercury emissions at coal-fired power plants using regular and speciating sorbent traps with in-stack and out-of-stack sampling methods

    SciTech Connect (OSTI)

    Chin-Min Cheng; Chien-Wei Chen; Jiashun Zhu; Chin-Wei Chen; Yao-Wen Kuo; Tung-Han Lin; Shu-Hsien Wen; Yong-Siang Zeng; Juei-Chun Liu; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

    2009-09-15T23:59:59.000Z

    A systematic investigation of sorbent-trap sampling, which is a method that uses paired sorbent traps to measure total vapor phase mercury (Hg), was carried out at two coal-fired power plants. The objective of the study was to evaluate the effects (if any) on data quality when the following aspects of the sorbent trap method are varied: (a) sorbent trap configuration; (b) sampling time; and (c) analytical technique. Also, the performance of a speciating sorbent trap (i.e., a trap capable of separating elemental Hg from oxidized Hg), was evaluated by direct comparison against the Ontario Hydro (OH) reference method. Flue gas samples were taken using both 'regular' and modified sorbent trap measurement systems. Both short-term (1.5 h) and long-term (18 h to 10 days) samples were collected. The in-stack and out-of-stack sampling methods produced satisfactory relative accuracy results for both the short-term and long-term testing. For the short-term tests, the in-stack sampling results compared more favorably to the OH method than did the out-of-stack results. The relative deviation between the paired traps was considerably higher for the short-term out-of-stack tests than for the long-term tests. A one-way analysis of variance (ANOVA), showed a statistically significant difference (p < 0.1) between the direct combustion and wet-chemistry analytical methods used in the study; the results from the direct combustion method were consistently higher than the wet-chemistry results. The evaluation of the speciating mercury sorbent trap demonstrated that the trap is capable of providing reasonably accurate total mercury concentrations and speciation data that are somewhat comparable to data obtained with the OH method. 5 refs., 4 figs., 8 tabs.

  18. Innovative clean coal technology: 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Final report, Phases 1 - 3B

    SciTech Connect (OSTI)

    NONE

    1998-01-01T23:59:59.000Z

    This report presents the results of a U.S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project was conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The technologies demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NOx burner. The primary objective of the demonstration at Hammond Unit 4 was to determine the long-term effects of commercially available wall-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology were also performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications was established for the project. Short-term and long-term baseline testing was conducted in an {open_quotes}as-found{close_quotes} condition from November 1989 through March 1990. Following retrofit of the AOFA system during a four-week outage in spring 1990, the AOFA configuration was tested from August 1990 through March 1991. The FWEC CF/SF low NOx burners were then installed during a seven-week outage starting on March 8, 1991 and continuing to May 5, 1991. Following optimization of the LNBs and ancillary combustion equipment by FWEC personnel, LNB testing commenced during July 1991 and continued until January 1992. Testing in the LNB+AOFA configuration was completed during August 1993. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NOx burners and advanced overfire systems.

  19. A study of toxic emissions from a coal-fired power plant utilizing the SNOX innovative clean coal technology demonstration. Volume 1, Sampling/results/special topics: Final report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01T23:59:59.000Z

    This study was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE during 1993. The motivation for those assessments was the mandate in the 1990 Clean Air Act Amendments that a study be made of emissions of hazardous air pollutants (HAPs) from electric utilities. The report is organized in two volumes. Volume 1: Sampling describes the sampling effort conducted as the basis for this study; Results presents the concentration data on HAPs in the several power plant streams, and reports the results of evaluations and calculations conducted with those data; and Special Topics report on issues such as comparison of sampling methods and vapor/solid distributions of HAPs. Volume 2: Appendices include quality assurance/quality control results, uncertainty analysis for emission factors, and data sheets. This study involved measurements of a variety of substances in solid, liquid, and gaseous samples from input, output, and process streams at the Innovative Clean Coal Technology Demonstration (ICCT) of the Wet Sulfuric Acid-Selective Catalytic Reduction (SNOX) process. The SNOX demonstration is being conducted at Ohio Edison`s Niles Boiler No. 2 which uses cyclone burners to burn bituminous coal. A 35 megawatt slipstream of flue gas from the boiler is used to demonstrate SNOX. The substances measured at the SNOX process were the following: 1. Five major and 16 trace elements, including mercury, chromium, cadmium, lead, selenium, arsenic, beryllium, and nickel; 2. Acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate); 3. Ammonia and cyanide; 4. Elemental carbon; 5. Radionuclides; 6. Volatile organic compounds (VOC); 7. Semi-volatile compounds (SVOC) including polynuclear aromatic hydrocarbons (PAH); and 8. Aldehydes.

  20. Biomass Feedstocks

    Broader source: Energy.gov [DOE]

    A feedstock is defined as any renewable, biological material that can be used directly as a fuel, or converted to another form of fuel or energy product. Biomass feedstocks are the plant and algal materials used to derive fuels like ethanol, butanol, biodiesel, and other hydrocarbon fuels. Examples of biomass feedstocks include corn starch, sugarcane juice, crop residues such as corn stover and sugarcane bagasse, purpose-grown grass crops, and woody plants. The Bioenergy Technologies Office works in partnership with the U.S. Department of Agriculture (USDA), national laboratories, universities, industry, and other key stakeholders to identify and develop economically, environmentally, and socially sustainable feedstocks for the production of energy, including transportation fuels, electrical power and heat, and other bioproducts. Efforts in this area will ultimately support the development of technologies that can provide a large and sustainable cellulosic biomass feedstock supply of acceptable quality and at a reasonable cost for use by the developing U.S. advanced biofuel industry.

  1. Biomass Surface Characterization Laboratory

    E-Print Network [OSTI]

    the recalcitrant nature of biomass feedstocks and the performance of techniques to deconstruct biomass NREL of biomass feedstocks. BSCL imaging capabilities include: · Confocal microscopy and Raman microscopy

  2. Co-Firing Oil Shale with Coal and Other Fuels for Improved Efficiency and Multi-Pollutant Control

    SciTech Connect (OSTI)

    Robert A. Carrington; William C. Hecker; Reed Clayson

    2008-06-01T23:59:59.000Z

    Oil shale is an abundant, undeveloped natural resource which has natural sorbent properties, and its ash has natural cementitious properties. Oil shale may be blended with coal, biomass, municipal wastes, waste tires, or other waste feedstock materials to provide the joint benefit of adding energy content while adsorbing and removing sulfur, halides, and volatile metal pollutants, and while also reducing nitrogen oxide pollutants. Oil shale depolymerization-pyrolysis-devolatilization and sorption scoping studies indicate oil shale particle sorption rates and sorption capacity can be comparable to limestone sorbents for capture of SO2 and SO3. Additionally, kerogen released from the shale was shown to have the potential to reduce NOx emissions through the well established “reburning” chemistry similar to natural gas, fuel oil, and micronized coal. Productive mercury adsorption is also possible by the oil shale particles as a result of residual fixed-carbon and other observed mercury capture sorbent properties. Sorption properties were found to be a function particle heating rate, peak particle temperature, residence time, and gas-phase stoichmetry. High surface area sorbents with high calcium reactivity and with some adsorbent fixed/activated carbon can be produced in the corresponding reaction zones that exist in a standard pulverized-coal or in a fluidized-bed combustor.

  3. NREL: Biomass Research - Biomass Characterization Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    before and after pretreatment and during processing. The characterization of biomass feedstocks, intermediates, and products is a critical step in optimizing biomass conversion...

  4. Biomass shock pretreatment

    DOE Patents [OSTI]

    Holtzapple, Mark T.; Madison, Maxine Jones; Ramirez, Rocio Sierra; Deimund, Mark A.; Falls, Matthew; Dunkelman, John J.

    2014-07-01T23:59:59.000Z

    Methods and apparatus for treating biomass that may include introducing a biomass to a chamber; exposing the biomass in the chamber to a shock event to produce a shocked biomass; and transferring the shocked biomass from the chamber. In some aspects, the method may include pretreating the biomass with a chemical before introducing the biomass to the chamber and/or after transferring shocked biomass from the chamber.

  5. Corrosion in coal-fired boilers

    SciTech Connect (OSTI)

    Vausher, A.L.

    1982-01-01T23:59:59.000Z

    The corrosive effect of the flue gas and the fly ash from burning coal on combustion and pollution control equipment has led to extensive research efforts aimed at solving this problem. A wide variety of chemical additives are offered by suppliers to perform corrosion reduction functions when added to the solid or liquid fuel. Protection of equipment by the use of corrosion resistant coatings and improved designs to prevent or reduce slag formation are also well known corrosion reduction techniques. However, the problem facing management is to evaluate the many different alternatives and to define the most effective one for their particular facility. Information gained from previous corrosion reduction attempts, and knowledge of factors which increase the SO/sub 3//SO/sub 2/ ratio in the flue gas have resulted in the investigation of methods of controlling the dew point and therefore, reducing the condensation of sulfuric acid. Various methods of avoiding the formation of acid are being evaluated.

  6. Tracking New Coal-Fired Power Plants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2, 2003Tool ofTopo II:7.1Tracking Living Cells as(data

  7. Tracking New Coal-Fired Power Plants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2, 2003Tool ofTopo II:7.1Tracking Living Cells as(data

  8. Biomass power for rural development. Technical progress report, April 1, 1997--June 30, 1997

    SciTech Connect (OSTI)

    Neuhauser, E.

    1997-08-01T23:59:59.000Z

    Detailed task progress reports and schedules are provided for the DOE/USDA sponsored Biomass Power for Rural Development project. The focus of the project is on developing commercial energy crops for power generation by the year 2000. The New York based Salix Consortium project is a multi-partner endeavor, implemented in three stages. Phase-I, Final Design and Project Development, will conclude with the preparation of construction and/or operating permits, feedstock production plans, and contracts ready for signature. Field trials of willow (Salix) have been initiated at several locations in New York (Tully, Lockport, King Ferry, La Fayette, Massena, and Himrod) and co-firing tests are underway at Greenidge Station (NYSEG) and Dunkirk Station (NMPC). Phase-H of the project will focus on scale-up of willow crop acreage, construction of co-firing facilities at Dunkirk Station (NMPC), and final modifications for Greenidge Station. Cofiring willow is also under consideration for GPU`s Seward Station where testing is under way. There will be an evaluation of the energy crop as part of the gasification trials occurring at BED`s McNeill power station. Phase-III will represent fullscale commercialization of the energy crop and power generation on a sustainable basis.

  9. Thermal Pretreatment of Wood for Cogasification/cofiring of Biomass and Coal

    SciTech Connect (OSTI)

    Wang, Ping; Howard, Bret; Hedges, Sheila; Morreale, Bryan; Van Essendelft, Dirk; Berry, David

    2013-10-29T23:59:59.000Z

    Utilization of biomass as a co-feed in coal and biomass co-firing and co-gasification requires size reduction of the biomass. Reducing biomass to below 0.2 mm without pretreatment is difficult and costly because biomass is fibrous and compressible. Torrefaction is a promising thermal pretreatment process and has the advantages of increasing energy density, improving grindability, producing fuels with more homogenous compositions and hydrophobic behavior. Temperature is the most important factor for the torrefaction process. Biomass grindability is related to cell wall structure, thickness and composition. Thermal treatment such as torrefaction can cause chemical changes that significantly affect the strength of biomass. The objectives of this study are to understand the mechanism by which torrefaction improves the grindability of biomass and discuss suitable temperatures for thermal pretreatment for co-gasification/cofiring of biomass and coal. Wild cherry wood was selected as the model for this study. Samples were prepared by sawing a single tangential section from the heartwood and cutting it into eleven pieces. The samples were consecutively heated at 220, 260, 300, 350, 450 and 550oC for 0.5 hr under flowing nitrogen in a tube furnace. Untreated and treated samples were characterized for physical properties (color, dimensions and weight), microstructural changes by SEM, and cell wall composition changes and thermal behaviors by TGA and DSC. The morphology of the wood remained intact through the treatment range but the cell walls were thinner. Thermal treatments were observed to decompose the cell wall components. Hemicellulose decomposed over the range of ~200 to 300oC and resulted in weakening of the cell walls and subsequently improved grindability. Furthermore, wood samples treated above 300oC lost more than 39% in mass. Therefore, thermal pretreatment above the hemicelluloses decomposition temperature but below 300oC is probably sufficient to improve grindability and retain energy value.

  10. Alternative Energy Development and China's Energy Future

    E-Print Network [OSTI]

    Zheng, Nina

    2012-01-01T23:59:59.000Z

    An evaluation of biomass co-firing in Europe. ” Biomass andprimarily in Europe. China have also developed small biomass

  11. E-Print Network 3.0 - animal disseminated plants Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DHP") n Implementation (,,Utilization of biomass from... municipal coal-fired district heating plants to combined heat and power with utilisation of biomass Source: Louisiana...

  12. CATALYTIC LIQUEFACTION OF BIOMASS

    E-Print Network [OSTI]

    Seth, Manu

    2012-01-01T23:59:59.000Z

    liquid Fuels from Biomass: "Catalyst Screening and KineticUC-61 (l, RCO osn CDL or BIOMASS CATALYTIC LIQUEFACTION ManuCATALYTIC LIQUEFACTION OF BIOMASS Manu Seth, Roger Djafar,

  13. CATALYTIC BIOMASS LIQUEFACTION

    E-Print Network [OSTI]

    Ergun, Sabri

    2013-01-01T23:59:59.000Z

    LBL-11 019 UC-61 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,Catalytic Liquefaction of Biomass,n M, Seth, R. Djafar, G.of California. CATALYTIC BIOMASS LIQUEFACTION QUARTERLY

  14. Sandia National Laboratories: Biomass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass "Bionic" Liquids from Lignin: Joint BioEnergy Institute Results Pave the Way for Closed-Loop Biofuel Refineries On December 11, 2014, in Biofuels, Biomass, Capabilities,...

  15. Sandia National Laboratories: Biomass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass Assessing the Economic Potential of Advanced Biofuels On September 10, 2013, in Biofuels, Biomass, Energy, Facilities, JBEI, News, News & Events, Partnership, Renewable...

  16. Biomass Analytical Library

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    diversity and performance, The chemical and physical properties of biomass and biomass feedstocks are characterized as they move through the supply chain to various conversion...

  17. Biomass Densification Workshop Overview

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    supply systems that ensure high- volume, reliable, and on-spec availability of biomass feedstocks. The United States has a diverse and abundant potential of biomass resources...

  18. Biomass treatment method

    DOE Patents [OSTI]

    Friend, Julie (Claymont, DE); Elander, Richard T. (Evergreen, CO); Tucker, III; Melvin P. (Lakewood, CO); Lyons, Robert C. (Arvada, CO)

    2010-10-26T23:59:59.000Z

    A method for treating biomass was developed that uses an apparatus which moves a biomass and dilute aqueous ammonia mixture through reaction chambers without compaction. The apparatus moves the biomass using a non-compressing piston. The resulting treated biomass is saccharified to produce fermentable sugars.

  19. Mapping Biomass Distribution Potential

    E-Print Network [OSTI]

    Schaetzel, Michael

    2010-11-18T23:59:59.000Z

    Mapping Biomass Distribution Potential Michael Schaetzel Undergraduate ? Environmental Studies ? University of Kansas L O C A T S I O N BIOMASS ENERGY POTENTIAL o According to DOE, Biomass has the potential to provide 14% of... the nation’s power o Currently 1% of national power supply o Carbon neutral? combustion of biomass is part of the natural carbon cycle o Improved crop residue management has potential to benefit environment, producers, and economy Biomass Btu...

  20. RESEARCH & DEVELOPMENT TO PREPARE AND CHARACTERIZE ROBUST COAL/BIOMASS MIXTURES FOR DIRECT CO-FEEDING INTO GASIFICATION SYSTEMS

    SciTech Connect (OSTI)

    Felix, Larry; Farthing, William; Hoekman, S. Kent

    2014-12-31T23:59:59.000Z

    This project was initiated on October 1, 2010 and utilizes equipment and research supported by the Department of Energy, National Energy Technology Laboratory, under Award Number DE- FE0005349. It is also based upon previous work supported by the Department of Energy, National Energy Technology Laboratory, under Award Numbers DOE-DE-FG36-01GOl1082, DE-FG36-02G012011 or DE-EE0000272. The overall goal of the work performed was to demonstrate and assess the economic viability of fast hydrothermal carbonization (HTC) for transforming lignocellulosic biomass into a densified, friable fuel to gasify like coal that can be easily blended with ground coal and coal fines and then be formed into robust, weather-resistant pellets and briquettes. The specific objectives of the project include: • Demonstration of the continuous production of a uniform densified and formed feedstock from loblolly pine (a lignocellulosic, short rotation woody crop) in a hydrothermal carbonization (HTC) process development unit (PDU). • Demonstration that finely divided bituminous coal and HTC loblolly pine can be blended to form 90/10 and 70/30 weight-percent mixtures of coal and HTC biomass for further processing by pelletization and briquetting equipment to form robust weather resistant pellets and/or briquettes suitable for transportation and long term storage. • Characterization of the coal-biomass pellets and briquettes to quantify their physical properties (e.g. flow properties, homogeneity, moisture content, particle size and shape), bulk physical properties (e.g. compressibility, heat transfer and friability) and assess their suitability for use as fuels for commercially-available coal gasifiers. • Perform economic analyses using Aspen-based process simulations to determine the costs for deploying and operating HTC processing facilities for the production of robust coal/biomass fuels suitable for fueling commercially-available coal-fired gasifiers. This Final Project Scientific/Technical Report discusses and documents the project work required to meet each of these objectives.

  1. Boiler Corrosion and Monitoring

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    G. R. Holcomb; B. F. McGhee; A. T. Fry; N. J. Simms; K. Davis; Shim, H S; S. J. Bullard

    2013-11-19T23:59:59.000Z

    Results of a collaborative effort to investigate and develop solutions for key material issues affecting the performance of large-scale coal-fired boilers operating at advanced conditions is presented. Advanced conditions include advanced steam temperatures, oxyfuel firing, and co-firing biomass materials. A series of laboratory experimental results are presented on fireside corrosion in environments representing air-, and oxy-fired conditions, and with coal and/or biomass as the fuel. The effects of fluctuating reducing atmospheres and heat flux effects were examined. A variety of boiler corrosion probes and sensors were developed and tested. The probes measured corrosion by section loss and the sensors by electrochemical techniques including electrochemical noise. The probes were tested in coal and waste-to-energy boilers. Correlations between section loss probes and electrochemical noise sensors allow for real-time corrosion rate measurements to be made that allow for changes in boiler operations to be tracked in terms of corrosion effects.

  2. BIOMASS ENERGY CONVERSION IN HAWAII

    E-Print Network [OSTI]

    Ritschard, Ronald L.

    2013-01-01T23:59:59.000Z

    Report, (unpublished, 1979). Biomass Project Progress 31.Operations, vol. 2 of Biomass Energy (Stanford: StanfordPhotosynthethic Pathway Biomass Energy Production," ~c:_! _

  3. Pretreated densified biomass products

    DOE Patents [OSTI]

    Dale, Bruce E; Ritchie, Bryan; Marshall, Derek

    2014-03-18T23:59:59.000Z

    A product comprising at least one densified biomass particulate of a given mass having no added binder and comprised of a plurality of lignin-coated plant biomass fibers is provided, wherein the at least one densified biomass particulate has an intrinsic density substantially equivalent to a binder-containing densified biomass particulate of the same given mass and h a substantially smooth, non-flakey outer surface. Methods for using and making the product are also described.

  4. Original article Root biomass and biomass increment in a beech

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Root biomass and biomass increment in a beech (Fagus sylvatica L.) stand in North ­ This study is part of a larger project aimed at quantifying the biomass and biomass increment been developed to estimate the biomass and biomass increment of coarse, small and fine roots of trees

  5. AVAILABLE NOW! Biomass Funding

    E-Print Network [OSTI]

    AVAILABLE NOW! Biomass Funding Guide 2010 The Forestry Commission and the Humber Rural Partnership (co-ordinated by East Riding of Yorkshire Council) have jointly produced a biomass funding guide fuel prices continue to rise, and the emerging biomass sector is well-placed to make a significant

  6. TASK 3.4--IMPACTS OF COFIRING BIOMASS WITH FOSSIL FUELS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Kurt E. Eylands; Melanie D. Hetland; Mark A. Musich; Charlene R. Crocker; Jonas Dahl; Stacie Laducer

    2001-08-01T23:59:59.000Z

    With a major worldwide effort now ongoing to reduce greenhouse gas emissions, cofiring of renewable biomass fuels at conventional coal-fired utilities is seen as one of the lower-cost options to achieve such reductions. The Energy & Environmental Research Center has undertaken a fundamental study to address the viability of cofiring biomass with coal in a pulverized coal (pc)-fired boiler for power production. Wheat straw, alfalfa stems, and hybrid poplar were selected as candidate biomass materials for blending at a 20 wt% level with an Illinois bituminous coal and an Absaloka subbituminous coal. The biomass materials were found to be easily processed by shredding and pulverizing to a size suitable for cofiring with pc in a bench-scale downfired furnace. A literature investigation was undertaken on mineral uptake and storage by plants considered for biomass cofiring in order to understand the modes of occurrence of inorganic elements in plant matter. Sixteen essential elements, C, H, O, N, P, K, Ca, Mg, S, Zn, Cu, Fe, Mn, B, Mo, and Cl, are found throughout plants. The predominant inorganic elements are K and Ca, which are essential to the function of all plant cells and will, therefore, be evenly distributed throughout the nonreproductive, aerial portions of herbaceous biomass. Some inorganic constituents, e.g., N, P, Ca, and Cl, are organically associated and incorporated into the structure of the plant. Cell vacuoles are the repository for excess ions in the plant. Minerals deposited in these ubiquitous organelles are expected to be most easily leached from dry material. Other elements may not have specific functions within the plant, but are nevertheless absorbed and fill a need, such as silica. Other elements, such as Na, are nonessential, but are deposited throughout the plant. Their concentration will depend entirely on extrinsic factors regulating their availability in the soil solution, i.e., moisture and soil content. Similarly, Cl content is determined less by the needs of the plant than by the availability in the soil solution; in addition to occurring naturally, Cl is present in excess as the anion complement in K fertilizer applications. An analysis was performed on existing data for switchgrass samples from ten different farms in the south-central portion of Iowa, with the goal of determining correlations between switchgrass elemental composition and geographical and seasonal changes so as to identify factors that influence the elemental composition of biomass. The most important factors in determining levels of various chemical compounds were found to be seasonal and geographical differences related to soil conditions. Combustion testing was performed to obtain deposits typical of boiler fouling and slagging conditions as well as fly ash. Analysis methods using computer-controlled scanning electron microscopy and chemical fractionation were applied to determine the composition and association of inorganic materials in the biomass samples. Modified sample preparation techniques and mineral quantification procedures using cluster analysis were developed to characterize the inorganic material in these samples. Each of the biomass types exhibited different inorganic associations in the fuel as well as in the deposits and fly ash. Morphological analyses of the wheat straw show elongated 10-30-{micro}m amorphous silica particles or phytoliths in the wheat straw structure. Alkali such as potassium, calcium, and sodium is organically bound and dispersed in the organic structure of the biomass materials. Combustion test results showed that the blends fed quite evenly, with good burnout. Significant slag deposit formation was observed for the 100% wheat straw, compared to bituminous and subbituminous coals burned under similar conditions. Although growing rapidly, the fouling deposits of the biomass and coal-biomass blends were significantly weaker than those of the coals. Fouling was only slightly worse for the 100% wheat straw fuel compared to the coals. The wheat straw ash was found to show the greatest similar

  7. Is it Worth it? A Comparative Analysis of Cost-Benefit Projections for State Renewables Portfolio Standards

    E-Print Network [OSTI]

    Chen, Cliff; Wiser, Ryan; Bolinger, Mark

    2006-01-01T23:59:59.000Z

    generation, while hydro, landfill gas, and solar eachGeothermal Solar Hydro Landfill Gas Biomass Co-Fire Biomass

  8. Weighing the Costs and Benefits of State Renewables Portfolio Standards in the United States: A Comparative Analysis of State-Level Policy Impact Projections

    E-Print Network [OSTI]

    Chen, Cliff

    2009-01-01T23:59:59.000Z

    RPS generation, while hydro, landfill gas, and solar eachGeothermal Solar Hydro Landfill Gas Biomass Co-Fire Biomass

  9. Understanding Biomass Feedstock Variability

    SciTech Connect (OSTI)

    Kevin L. Kenney; William A. Smith; Garold L. Gresham; Tyler L. Westover

    2013-01-01T23:59:59.000Z

    If the singular goal of biomass logistics and the design of biomass feedstock supply systems is to reduce the per ton supply cost of biomass, these systems may very well develop with ultimate unintended consequences of highly variable and reduced quality biomass feedstocks. This paper demonstrates that due to inherent species variabilities, production conditions, and differing harvest, collection, and storage practices, this is a very real scenario that biomass producers and suppliers as well as conversion developers should be aware of. Biomass feedstock attributes of ash, carbohydrates, moisture, and particle morphology will be discussed. We will also discuss specifications for these attributes, inherent variability of these attributes in biomass feedstocks, and approaches and solutions for reducing variability for improving feedstock quality.

  10. Understanding Biomass Feedstock Variability

    SciTech Connect (OSTI)

    Kevin L. Kenney; Garold L. Gresham; William A. Smith; Tyler L. Westover

    2013-01-01T23:59:59.000Z

    If the singular goal of biomass logistics and the design of biomass feedstock supply systems is to reduce the per-ton supply cost of biomass, these systems may very well develop with ultimate unintended consequences of highly variable and reduced quality biomass feedstocks. This paper demonstrates that, due to inherent species variabilities, production conditions and differing harvest, collection and storage practices, this is a very real scenario that biomass producers and suppliers as well as conversion developers should be aware of. Biomass feedstock attributes of ash, carbohydrates, moisture and particle morphology will be discussed. We will also discuss specifications for these attributes, inherent variability of these attributes in biomass feedstocks, and approaches and solutions for reducing variability for improving feedstock quality.

  11. Biomass power for rural development. Technical progress report, May 1, 1996--December 31, 1996

    SciTech Connect (OSTI)

    Neuhauser, E.

    1996-02-01T23:59:59.000Z

    Developing commercial energy crops for power generation by the year 2000 is the focus of the DOE/USDA sponsored Biomass Power for Rural Development project. The New York based Salix Consortium project is a multi-partner endeavor, implemented in three stages. Phase-I, Final Design and Project Development, will conclude with the preparation of construction and/or operating permits, feedstock production plans, and contracts ready for signature. Field trials of willow (Salix) have been initiated at several locations in New York (Tully, Lockport, King Ferry, La Facette, Massena, and Himrod) and co-firing tests are underway at Greenidge Station (NYSEG). Phase-II of the project will focus on scale-up of willow crop acreage, construction of co-firing facilities at Dunkirk Station (NMPC), and final modifications for Greenidge Station. There will be testing of the energy crop as part of the gasification trials expected to occur at BED`s McNeill power station and potentially at one of GPU`s facilities. Phase-III will represent full-scale commercialization of the energy crop and power generation on a sustainable basis. Willow has been selected as the energy crop of choice for many reasons. Willow is well suited to the climate of the Northeastern United States, and initial field trials have demonstrated that the yields required for the success of the project are obtainable. Like other energy crops, willow has rural development benefits and could serve to diversify local crop production, provide new sources of income for participating growers, and create new jobs. Willow could be used to put a large base of idle acreage back into crop production. Additionally, the willow coppicing system integrates well with current farm operations and utilizes agricultural practices that are already familiar to farmers.

  12. Complex pendulum biomass sensor

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Perrenoud, Ben C. (Rigby, ID)

    2007-12-25T23:59:59.000Z

    A complex pendulum system biomass sensor having a plurality of pendulums. The plurality of pendulums allow the system to detect a biomass height and density. Each pendulum has an angular deflection sensor and a deflector at a unique height. The pendulums are passed through the biomass and readings from the angular deflection sensors are fed into a control system. The control system determines whether adjustment of machine settings is appropriate and either displays an output to the operator, or adjusts automatically adjusts the machine settings, such as the speed, at which the pendulums are passed through the biomass. In an alternate embodiment, an entanglement sensor is also passed through the biomass to determine the amount of biomass entanglement. This measure of entanglement is also fed into the control system.

  13. Sandia National Laboratories: Biomass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass Renewable Systems On November 4, 2010, in Renewable Systems Renewable Energy Transportation Nuclear Fossil Energy Efficiency Publications Events News Renewable Systems The...

  14. Biomass Processing Photolibrary

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Research related to bioenergy is a major focus in the U.S. as science agencies, universities, and commercial labs seek to create new energy-efficient fuels. The Biomass Processing Project is one of the funded projects of the joint USDA-DOE Biomass Research and Development Initiative. The Biomass Processing Photolibrary has numerous images, but there are no accompanying abstracts to explain what you are seeing. The project website, however, makes available the full text of presentations and publications and also includes an exhaustive biomass glossary that is being developed into an ASAE Standard.

  15. Sandia National Laboratories: Biomass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biofuels Biofuels Publications Biochemical Conversion Program Lignocellulosic Biomass Microalgae Thermochemical Conversion Sign up for our E-Newsletter Required.gif?3.21 Email...

  16. Biomass 2013 Attendee List | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Attendee List Biomass 2013 Attendee List This is a list of attendees for the Biomass 2013 conference. biomass2013attendeelist.pdf More Documents & Publications Biomass 2013...

  17. An integrated appraisal of energy recovery options in the United Kingdom using solid recovered fuel derived from municipal solid waste

    SciTech Connect (OSTI)

    Garg, A.; Smith, R. [Sustainable Systems Department, School of Applied Sciences, Cranfield University, Cranfield, Bedfordshire, MK43 0AL (United Kingdom); Hill, D. [DPH Environment and Energy Ltd., c/o Sustainable Systems Department, School of Applied Sciences, Cranfield University, Cranfield, Bedfordshire, MK43 0AL (United Kingdom); Longhurst, P.J.; Pollard, S.J.T. [Sustainable Systems Department, School of Applied Sciences, Cranfield University, Cranfield, Bedfordshire, MK43 0AL (United Kingdom); Simms, N.J. [Sustainable Systems Department, School of Applied Sciences, Cranfield University, Cranfield, Bedfordshire, MK43 0AL (United Kingdom)], E-mail: n.j.simms@cranfield.ac.uk

    2009-08-15T23:59:59.000Z

    This paper reports an integrated appraisal of options for utilising solid recovered fuels (SRF) (derived from municipal solid waste, MSW) in energy intensive industries within the United Kingdom (UK). Four potential co-combustion scenarios have been identified following discussions with industry stakeholders. These scenarios have been evaluated using (a) an existing energy and mass flow framework model, (b) a semi-quantitative risk analysis, (c) an environmental assessment and (d) a financial assessment. A summary of results from these evaluations for the four different scenarios is presented. For the given ranges of assumptions; SRF co-combustion with coal in cement kilns was found to be the optimal scenario followed by co-combustion of SRF in coal-fired power plants. The biogenic fraction in SRF (ca. 70%) reduces greenhouse gas (GHG) emissions significantly ({approx}2500 g CO{sub 2} eqvt./kg DS SRF in co-fired cement kilns and {approx}1500 g CO{sub 2} eqvt./kg DS SRF in co-fired power plants). Potential reductions in electricity or heat production occurred through using a lower calorific value (CV) fuel. This could be compensated for by savings in fuel costs (from SRF having a gate fee) and grants aimed at reducing GHG emission to encourage the use of fuels with high biomass fractions. Total revenues generated from coal-fired power plants appear to be the highest ( Pounds 95/t SRF) from the four scenarios. However overall, cement kilns appear to be the best option due to the low technological risks, environmental emissions and fuel cost. Additionally, cement kiln operators have good experience of handling waste derived fuels. The scenarios involving co-combustion of SRF with MSW and biomass were less favourable due to higher environmental risks and technical issues.

  18. Biomass One Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: EnergyAvignon,Belcher HomesLyons BiomassBiofuels)Biomass Facility Jump

  19. Biomass Research Program

    SciTech Connect (OSTI)

    Kenney, Kevin; Wright, Christopher; Shelton-Davis, Colleen

    2011-01-01T23:59:59.000Z

    INL's mission is to achieve DOE's vision of supplying high-quality raw biomass; preprocessing biomass into advanced bioenergy feedstocks; and delivering bioenergy commodities to biorefineries. You can learn more about research like this at the lab's facebook site http://www.facebook.com/idahonationallaboratory.

  20. Biomass Research Program

    ScienceCinema (OSTI)

    Kenney, Kevin; Wright, Christopher; Shelton-Davis, Colleen

    2013-05-28T23:59:59.000Z

    INL's mission is to achieve DOE's vision of supplying high-quality raw biomass; preprocessing biomass into advanced bioenergy feedstocks; and delivering bioenergy commodities to biorefineries. You can learn more about research like this at the lab's facebook site http://www.facebook.com/idahonationallaboratory.

  1. NREL: Biomass Research - Projects in Biomass Process and Sustainabilit...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Projects in Biomass Process and Sustainability Analyses Researchers at NREL use biomass process and sustainability analyses to understand the economic, technical, and global...

  2. Module Handbook Specialisation Biomass Energy

    E-Print Network [OSTI]

    Damm, Werner

    Module Handbook Specialisation Biomass Energy 2nd Semester for the Master Programme REMA/EUREC Course 2008/2009 University of Zaragoza Specialisation Provider: Biomass Energy #12;Specialisation Biomass Energy, University of Zaragoza Modul: Introduction and Basic Concepts

  3. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY to treatment prescriptions and anticipated outputs of sawlogs and biomass fuel? How many individual operations biomass fuel removed. Typically in plantations. 50% No harvest treatment

  4. NREL: Biomass Research - Video Text

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    common corn grain ethanol. Cellulosic ethanol is made from organic plant matter called biomass. The video shows different forms of biomass such as switchgrass, corn stalks, and...

  5. BIOMASS ENERGY CONVERSION IN HAWAII

    E-Print Network [OSTI]

    Ritschard, Ronald L.

    2013-01-01T23:59:59.000Z

    biomass resources will have to be reassessed periodically in the light of priceEthanol Price. Effect of Sugar on Ethanol Cost • vii BIOMASS

  6. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY .................................................................................... 33 3.3 BIOMASS POWER PLANT OPERATION MODELS AND DATA

  7. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY and continuously between the earth's biomass and atmosphere. From a greenhouse gas perspective, forest treatments

  8. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY study. The Biomass to Energy (B2E) Project is exploring the ecological and economic consequences

  9. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY Citation: USDA Forest Service, Pacific Southwest Research Station. 2009. Biomass to Energy: Forest

  10. Developing better biomass feedstock | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Developing better biomass feedstock Developing better biomass feedstock Released: September 04, 2014 Multi-omics unlocking the workings of plants Kim Hixson, an EMSL research...

  11. Sandia National Laboratories: biomass conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    biomass conversion Sandia Video Featured by DOE Bioenergy Technologies Office On December 10, 2014, in Biofuels, Biomass, Capabilities, Energy, Facilities, JBEI, News, News &...

  12. NREL: Biomass Research - Amie Sluiter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Biomass Analysis Technologies team to provide compositional analysis data on biomass feedstocks and process intermediates for use in pretreatment models and techno-economic...

  13. Gasification Characteristics of Coal/Biomass Mixed Fuels

    SciTech Connect (OSTI)

    Mitchell, Reginald

    2013-09-30T23:59:59.000Z

    A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co- produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle pores and energy exchange between the particle and its environment. This char-particle gasification model is capable of predicting the average mass loss rates, sizes, apparent densities, specific surface areas, and temperatures of the char particles produced when co-firing coal and biomass to the type environments established in entrained flow gasifiers operating at high temperatures and elevated pressures. A key result of this work is the finding that the reactivities of the mixed chars were not always in between the reactivities of the pure component chars at comparable gasification conditions. Mixed char reactivity to CO{sub 2} was lower than the reactivities of both the pure Wyodak coal and pure corn stover chars to CO{sub 2}. In contrast, mixed char reactivity to H{sub 2}O was higher than the reactivities of both the pure Wyodak coal and pure corn stover chars to H{sub 2}O. This was found to be in part, a consequence of the reduced mass specific surface areas of the coal char particles formed during devolatilization when the coal and biomass particles are co-fired. The biomass particles devolatilize prior to the coal particles, impacting the temperature and the composition of the environment in which the coal particles devolatilize. This situation results in coal char particles within the mixed char that differ in specific surface area and reactivity from the coal char particles produced in the absence of the devolatilizing biomass particles. Due to presence of this “affected” coal char, it was not possible to develop a mixed char reactivity model that uses linear mixing rules to determine the reactivity of a mixed char from only the reactivities of the pure mixture components. However, it was possible to predict both mixed char specific surface area and reactivity for a wide range of fuel mixture rat os provided the specific surface area and reactivity of the affected coal char particles are known. Using the kinetic parameters determined for the Wyodak coal and corn stover chars, the model was found to adequately predict the observed conversion times a

  14. FETC/EPRI Biomass Cofiring Cooperative Agreement. Quarterly technical report, September 26-December 31, 1996

    SciTech Connect (OSTI)

    Hughes, E. Tillman, D.

    1997-12-01T23:59:59.000Z

    Biomass utilization to reduce fossil C0{sub 2} emissions is being supported by sixteen (16) EPRI research projects, each contributing to the commercialization of systems to address greenhouse gas emissions. These projects include: (1) cofiring combustion testing at the Seward Generating Station of GPU Genco; (2) fuel preparation testing at the Greenidge Generating Station of NYSEG; (3) precommercial testing of cofiring at the Allen and Colbert Fossil Plants of TVA; (4) testing of switchgrass cofiring at the Blount St. Station of Madison Gas & Electric; (5) high percentage biomass cofiring with Southern Company; (6) urban wood waste cofiring at the supercritical cyclone boiler at Michigan City Generating Station of Northern Indiana Public Service Co. (NIPSCO); (7) evaluation of switchgrass cofiring with Nebraska Public Power District at Sandia National Laboratories in Livermore, CA; (8) waste plastics cofiring with Duke Power in a tangentially-fired pulverized coal (PC) boiler; (9) cofiring a mixture of plastics, fiber, and pulp industry wastes with South Carolina Electric and Gas; (10) urban wood waste cofiring evaluation and testing by the University of Pittsburgh in stoker boilers; (11) assessment of toxic emissions from cofiring of wood and coal; (12) development of fuel and power plant models for analysis and interpretation of cofiring results; (13) analysis of C0{sub 2} utilization in algal systems for wastewater treatment; (14) combustion testing and combustor development focusing on high percentage cofiring; (15) analysis of problems and potential solutions to the sale of flyash from coal- fired boilers practicing cofiring; and (16) analysis of C0{sub 2} capture and disposal systems. EPRI is supported in these efforts by numerous contractors including: Foster Wheeler Environmental Corporation, Battelle Columbus Laboratories, New York State Electric and Gas Co., Tennessee Valley Authority (TVA), NIPSCO, the University of Pittsburgh, John Benneman, and others. These projects address various aspects of cofiring for C0{sub 2} mitigation including testing of cofiring with various fuels, and in all types of boilers; development of analytical tools to support the cofiring assessment; addressing specific barriers to cofiring such as the sale of flyash; longer term technology development; and evaluating alternative methods for C0{sub 2} mitigation. Taken together, they address the critical concerns associated with this approach to biofuel utilization. As such, they support implementation of the most promising near-term approach to biomass usage for greenhouse gas mitigation. This report contains a brief description of each project. It then reports the progress made during the first quarter of the contract, focusing upon test results from the Allen Fossil Plant, where precommercial testing at a cyclone boiler was used to evaluate particle size and NO{sub x} emissions from cofiring.

  15. WP 3 Report: Biomass Potentials Biomass production potentials

    E-Print Network [OSTI]

    WP 3 Report: Biomass Potentials 1 Biomass production potentials in Central and Eastern Europe under different scenarios Final report of WP3 of the VIEWLS project, funded by DG-Tren #12;WP 3 Report: Biomass Potentials 2 Report Biomass production potentials in central and Eastern Europe under different scenarios

  16. A LOW COST AND HIGH QUALITY SOLID FUEL FROM BIOMASS AND COAL FINES

    SciTech Connect (OSTI)

    John T. Kelly; George Miller; Mehdi Namazian

    2001-07-01T23:59:59.000Z

    Use of biomass wastes as fuels in existing boilers would reduce greenhouse gas emissions, SO2 and NOx emissions, while beneficially utilizing wastes. However, the use of biomass has been limited by its low energy content and density, high moisture content, inconsistent configuration and decay characteristics. If biomass is upgraded by conventional methods, the cost of the fuel becomes prohibitive. Altex has identified a process, called the Altex Fuel Pellet (AFP) process, that utilizes a mixture of biomass wastes, including municipal biosolids, and some coal fines, to produce a strong, high energy content, good burning and weather resistant fuel pellet, that is lower in cost than coal. This cost benefit is primarily derived from fees that are collected for accepting municipal biosolids. Besides low cost, the process is also flexible and can incorporate several biomass materials of interest The work reported on herein showed the technical and economic feasibility of the AFP process. Low-cost sawdust wood waste and light fractions of municipal wastes were selected as key biomass wastes to be combined with biosolids and coal fines to produce AFP pellets. The process combines steps of dewatering, pellet extrusion, drying and weatherizing. Prior to pilot-scale tests, bench-scale test equipment was used to produce limited quantities of pellets for characterization. These tests showed which pellet formulations had a high potential. Pilot-scale tests then showed that extremely robust pellets could be produced that have high energy content, good density and adequate weatherability. It was concluded that these pellets could be handled, stored and transported using equipment similar to that used for coal. Tests showed that AFP pellets have a high combustion rate when burned in a stoker type systems. While NOx emissions under stoker type firing conditions was high, a simple air staging approach reduced emissions to below that for coal. In pulverized-fuel-fired tests it was found that the ground pellets could be used as an effective NOx control agent for pulverized-coal-fired systems. NOx emissions reductions up to 63% were recorded, when using AFP as a NOx control agent. In addition to performance benefits, economic analyses showed the good economic benefits of AFP fuel. Using equipment manufacturer inputs, and reasonable values for biomass, biosolids and coal fines costs, it was determined that an AFP plant would have good profitability. For cases where biosolids contents were in the range of 50%, the after tax Internal Rates of Return were in the range of 40% to 50%. These are very attractive returns. Besides the baseline analysis for the various AFP formulations tested at pilot scale, sensitivity analysis showed the impact of important parameters on return. From results, it was clear that returns are excellent for a range of parameters that could be expected in practice. Importantly, these good returns are achieved even without incentives related to the emissions control benefits of biomass.

  17. DOE 2014 Biomass Conference

    Broader source: Energy.gov [DOE]

    Breakout Session 1C—Fostering Technology Adoption I: Building the Market for Renewables with High Octane Fuels DOE 2014 Biomass Conference Jim Williams, Senior Manager, American Petroleum Institute

  18. Countercurrent Saccharification of Biomass 

    E-Print Network [OSTI]

    Derner, John David

    2015-04-21T23:59:59.000Z

    Our goal was to research and implement a countercurrent system to run enzymatic saccharification of biomass. The project provided clear results to show that this method is more efficient than the batch process that companies currently employ. Excess...

  19. Biomass Energy Production Incentive

    Broader source: Energy.gov [DOE]

    In 2007 South Carolina enacted the ''Energy Freedom and Rural Development Act'', which provides production incentives for certain biomass-energy facilities. Eligible systems earn $0.01 per kilowatt...

  20. Strategic Biomass Solutions (Mississippi)

    Broader source: Energy.gov [DOE]

    The Strategic Biomass Solutions (SBS) was formed by the Mississippi Technology Alliance in June 2009. The purpose of the SBS is to provide assistance to existing and potential companies, investors...

  1. Converting Biomass to Products

    SciTech Connect (OSTI)

    Graybeal, Judith W.

    2006-06-01T23:59:59.000Z

    For nearly 30 years, PNNL has been developing and applying novel thermal, chemical and biological processes to convert biomass to industrial and consumer products, fuels and energy. Honors for technologies resulting from this research include the Presidential Green Chemistry Award and several Federal Laboratory Consortium and R&D 100 Awards. PNNL’s research and development activities address the complete processing scheme, from feedstock pretreatment to purified product recovery. The laboratory applies fundamental science and advanced engineering capabilities to biomass conversion and processing to ensure effective recovery of optimal value from biomass; carbohydrate polymer systems to maximize energy efficiencies; and micro-technology systems for separation and conversion processes. For example, bioproducts researchers in the laboratory’s Institute for Interfacial Catalysis develop and demonstrate the utility of new catalyst formulations for production of bio-based chemicals. This article describes a sampling of current and recent catalysis projects for biomass conversion.

  2. Biomass 2014 Poster Session

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy’s Bioenergy Technologies Office (BETO) invites students, researchers, public and private organizations, and members of the general public to submit poster abstracts for consideration for the annual Biomass Conference Poster Session. The Biomass 2014 conference theme focuses on topics that are advancing the growth of the bioeconomy, such as improvements in feedstock logistics; promising, innovative pathways for advanced biofuels; and market-enabling co-products.

  3. BIOMASS ACTION PLAN FOR SCOTLAND

    E-Print Network [OSTI]

    BIOMASS ACTION PLAN FOR SCOTLAND #12; #12;© Crown copyright 2007 ISBN: 978 0 7559 6506 9 Scottish% recyclable. #12;A BIOMASS ACTION PLAN FOR SCOTLAND #12;#12;1 CONTENTS FOREWORD 3 1. EXECUTIVE SUMMARY 5 2. INTRODUCTION 9 3. WIDER CONTEXT 13 4. SCOTLAND'S ROLE IN THE UK BIOMASS STRATEGY 17 5. BIOMASS HEATING 23 6

  4. Northeast Regional Biomass Program

    SciTech Connect (OSTI)

    Lusk, P.D.

    1992-12-01T23:59:59.000Z

    The Northeast Regional Biomass Program has been in operation for a period of nine years. During this time, state managed programs and technical programs have been conducted covering a wide range of activities primarily aim at the use and applications of wood as a fuel. These activities include: assessments of available biomass resources; surveys to determine what industries, businesses, institutions, and utility companies use wood and wood waste for fuel; and workshops, seminars, and demonstrations to provide technical assistance. In the Northeast, an estimated 6.2 million tons of wood are used in the commercial and industrial sector, where 12.5 million cords are used for residential heating annually. Of this useage, 1504.7 mw of power has been generated from biomass. The use of wood energy products has had substantial employment and income benefits in the region. Although wood and woodwaste have received primary emphasis in the regional program, the use of municipal solid waste has received increased emphasis as an energy source. The energy contribution of biomass will increase as potentia users become more familiar with existing feedstocks, technologies, and applications. The Northeast Regional Biomass Program is designed to support region-specific to overcome near-term barriers to biomass energy use.

  5. Biomass cogeneration. A business assessment

    SciTech Connect (OSTI)

    Skelton, J.C.

    1981-11-01T23:59:59.000Z

    This guide serves as an overview of the biomass cogeneration area and provides direction for more detailed analysis. The business assessment is based in part on discussions with key officials from firms that have adopted biomass cogeneration systems and from organizations such as utilities, state and federal agencies, and banks that would be directly involved in a biomass cogeneration project. The guide is organized into five chapters: biomass cogeneration systems, biomass cogeneration business considerations, biomass cogeneration economics, biomass cogeneration project planning, and case studies.

  6. Biomass Boiler and Furnace Emissions and Safety Regulations in...

    Open Energy Info (EERE)

    Air Use Management (NESCAUM) Sector: Energy Focus Area: Biomass, - Biomass Combustion, - Biomass Gasification, - Biomass Pyrolysis, - Biofuels, Economic Development...

  7. A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis

    E-Print Network [OSTI]

    Farrell, Alexander; Sperling, Daniel

    2007-01-01T23:59:59.000Z

    that, nationally, a price of $40/ton biomass is necessary toof farm gate prices needed to increase biomass production inprice volatility has engendered a resurgence in coal-fired facilities, though more creative solutions such as the use of biomass

  8. A Low-Carbon Fuel Standard for California Part 1: Technical Analysis

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    that, nationally, a price of $40/ton biomass is necessary toof farm gate prices needed to increase biomass production inprice volatility has engendered a resurgence in coal-fired facilities, though more creative solutions such as the use of biomass

  9. Estimating the variable cost for high-volume and long-haul transportation of densified biomass and biofuel

    SciTech Connect (OSTI)

    Jacob J. Jacobson; Erin Searcy; Md. S. Roni; Sandra D. Eksioglu

    2014-06-01T23:59:59.000Z

    This article analyzes rail transportation costs of products that have similar physical properties as densified biomass and biofuel. The results of this cost analysis are useful to understand the relationship and quantify the impact of a number of factors on rail transportation costs of denisfied biomass and biofuel. These results will be beneficial and help evaluate the economic feasibility of high-volume and long-haul transportation of biomass and biofuel. High-volume and long-haul rail transportation of biomass is a viable transportation option for biofuel plants, and for coal plants which consider biomass co-firing. Using rail optimizes costs, and optimizes greenhouse gas (GHG) emissions due to transportation. Increasing bioenergy production would consequently result in lower GHG emissions due to displacing fossil fuels. To estimate rail transportation costs we use the carload waybill data, provided by Department of Transportation’s Surface Transportation Board for products such as grain and liquid type commodities for 2009 and 2011. We used regression analysis to quantify the relationship between variable transportation unit cost ($/ton) and car type, shipment size, rail movement type, commodity type, etc. The results indicate that: (a) transportation costs for liquid is $2.26/ton–$5.45/ton higher than grain type commodity; (b) transportation costs in 2011 were $1.68/ton–$5.59/ton higher than 2009; (c) transportation costs for single car shipments are $3.6/ton–$6.68/ton higher than transportation costs for multiple car shipments of grains; (d) transportation costs for multiple car shipments are $8.9/ton and $17.15/ton higher than transportation costs for unit train shipments of grains.

  10. NREL: Biomass Research - Biomass Characterization Capabilities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Saleshttp://www.fnal.gov/directorate/nalcal/nalcal02_07_05_files/nalcal.gifNREL NREL RefinesAnalysisBiochemical ConversionBiomass

  11. Biomass power for rural development. Quarterly report, January 1--April 2, 1998

    SciTech Connect (OSTI)

    Cooper, J.T.

    1998-07-01T23:59:59.000Z

    During the period of January 2 to April 2, 1998, efforts revolved around the design of the switchgrass materials handling/feeding system for the co-fire test and permanent system, the development of a revised statement of work and budget for fiscal years 1998--1999 and, the continuation of farmer/land conversion, and public relations efforts. The weather continues to be a major problem with an unprecedented warm winter. Much of Iowa has had little or no frost in the ground. This lack of frost has prevented farmers from getting into their fields and harvesting switchgrass. Farmers are hesitant to drive processing equipment into unfrozen fields due to the large ruts left by the wheels. The producers group has continued to gather information and develop resources necessary to supply the switchgrass to the facility in a competitive manner. Information and contacts are starting to be gathered which will help establish a market for the dedicated biomass generated electricity. The report describes the progress in the following tasks: Switchgrass conversion development including fuel analysis and engineering; Production activities which include: soil studies, carbon studies, switchgrass production economics, and switchgrass yield improvements; Information and education; and Miscellaneous which includes legislation and regulatory activities. Appendices contain the following: Switchgrass sample analysis; Chariton Valley biomass project cooperator agreement; Soil and landscape characterization status report for switchgrass project; Agreement with Center for Global and Regional Environmental Research; A literature review of reed canarygrass utility for biomass; Prairie Lands Bio-Products, Inc. agenda; Feasibility analysis and cooperative structure for value-added switchgrass products; and Information and education efforts.

  12. YEAR 2 BIOMASS UTILIZATION

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke

    2004-11-01T23:59:59.000Z

    This Energy & Environmental Research Center (EERC) Year 2 Biomass Utilization Final Technical Report summarizes multiple projects in biopower or bioenergy, transportation biofuels, and bioproducts. A prototype of a novel advanced power system, termed the high-temperature air furnace (HITAF), was tested for performance while converting biomass and coal blends to energy. Three biomass fuels--wood residue or hog fuel, corn stover, and switchgrass--and Wyoming subbituminous coal were acquired for combustion tests in the 3-million-Btu/hr system. Blend levels were 20% biomass--80% coal on a heat basis. Hog fuel was prepared for the upcoming combustion test by air-drying and processing through a hammer mill and screen. A K-Tron biomass feeder capable of operating in both gravimetric and volumetric modes was selected as the HITAF feed system. Two oxide dispersion-strengthened (ODS) alloys that would be used in the HITAF high-temperature heat exchanger were tested for slag corrosion rates. An alumina layer formed on one particular alloy, which was more corrosion-resistant than a chromia layer that formed on the other alloy. Research activities were completed in the development of an atmospheric pressure, fluidized-bed pyrolysis-type system called the controlled spontaneous reactor (CSR), which is used to process and condition biomass. Tree trimmings were physically and chemically altered by the CSR process, resulting in a fuel that was very suitable for feeding into a coal combustion or gasification system with little or no feed system modifications required. Experimental procedures were successful for producing hydrogen from biomass using the bacteria Thermotoga, a deep-ocean thermal vent organism. Analytical procedures for hydrogen were evaluated, a gas chromatography (GC) method was derived for measuring hydrogen yields, and adaptation culturing and protocols for mutagenesis were initiated to better develop strains that can use biomass cellulose. Fly ash derived from cofiring coal with waste paper, sunflower hulls, and wood waste showed a broad spectrum of chemical and physical characteristics, according to American Society for Testing and Materials (ASTM) C618 procedures. Higher-than-normal levels of magnesium, sodium, and potassium oxide were observed for the biomass-coal fly ash, which may impact utilization in cement replacement in concrete under ASTM requirements. Other niche markets for biomass-derived fly ash were explored. Research was conducted to develop/optimize a catalytic partial oxidation-based concept for a simple, low-cost fuel processor (reformer). Work progressed to evaluate the effects of temperature and denaturant on ethanol catalytic partial oxidation. A catalyst was isolated that had a yield of 24 mole percent, with catalyst coking limited to less than 15% over a period of 2 hours. In biodiesel research, conversion of vegetable oils to biodiesel using an alternative alkaline catalyst was demonstrated without the need for subsequent water washing. In work related to biorefinery technologies, a continuous-flow reactor was used to react ethanol with lactic acid prepared from an ammonium lactate concentrate produced in fermentations conducted at the EERC. Good yields of ester were obtained even though the concentration of lactic acid in the feed was low with respect to the amount of water present. Esterification gave lower yields of ester, owing to the lowered lactic acid content of the feed. All lactic acid fermentation from amylose hydrolysate test trials was completed. Management activities included a decision to extend several projects to December 31, 2003, because of delays in receiving biomass feedstocks for testing and acquisition of commercial matching funds. In strategic studies, methods for producing acetate esters for high-value fibers, fuel additives, solvents, and chemical intermediates were discussed with several commercial entities. Commercial industries have an interest in efficient biomass gasification designs but are waiting for economic incentives. Utility, biorefinery, pulp and paper, or o

  13. Sustainable Biomass Supply Systems

    SciTech Connect (OSTI)

    Erin Searcy; Dave Muth; Erin Wilkerson; Shahab Sokansanj; Bryan Jenkins; Peter Titman; Nathan Parker; Quinn Hart; Richard Nelson

    2009-04-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) aims to displace 30% of the 2004 gasoline use (60 billion gal/yr) with biofuels by 2030 as outlined in the Energy Independence and Security Act of 2007, which will require 700 million tons of biomass to be sustainably delivered to biorefineries annually. Lignocellulosic biomass will make an important contribution towards meeting DOE’s ethanol production goals. For the biofuels industry to be an economically viable enterprise, the feedstock supply system (i.e., moving the biomass from the field to the refinery) cannot contribute more that 30% of the total cost of the biofuel production. The Idaho National Laboratory in collaboration with Oak Ridge National Laboratory, University of California, Davis and Kansas State University are developing a set of tools for identifying economical, sustainable feedstocks on a regional basis based on biorefinery siting.

  14. NREL: Biomass Research - David W. Templeton

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    W. Templeton Photo of David Templeton David Templeton is the senior biomass analyst on the Biomass Analysis team (Biomass Compositional Analysis Laboratory) within the National...

  15. NREL: International Activities - Biomass Resource Assessment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass Resource Assessment Map showing annual productivity of marginal lands in APEC economies. Biomass resource assessments quantify the existing or potential biomass material in...

  16. UCSD Biomass to Power Economic Feasibility Study

    E-Print Network [OSTI]

    Cattolica, Robert

    2009-01-01T23:59:59.000Z

    Teotl Energy Partners LLC, West Biofuels Biomass?to?Fuels Teotl Energy Partners LLC, West Biofuels Biomass-to-Fuelssolid?fuel biomass, solar thermal electric, or wind energy 

  17. November 2011 Model documentation for biomass,

    E-Print Network [OSTI]

    Noble, James S.

    1 November 2011 Model documentation for biomass, cellulosic biofuels, renewable of Education, Office of Civil Rights. #12;3 Contents Biomass.....................................................................................................................................................4 Variables in the biomass module

  18. UCSD Biomass to Power Economic Feasibility Study

    E-Print Network [OSTI]

    Cattolica, Robert

    2009-01-01T23:59:59.000Z

    Biofuels, LLC  UCSD Biomass to Power  Economic Feasibility Figure 1: West Biofuels Biomass Gasification to Power rates..……………………. ……31  UCSD Biomass to Power ? Feasibility 

  19. UCSD Biomass to Power Economic Feasibility Study

    E-Print Network [OSTI]

    Cattolica, Robert

    2009-01-01T23:59:59.000Z

    facilities that use biomass, waste, or renewable resources (Eligible renewable energy resources include biomass, solar renewable  power  than  there  is  in  the  market  for  biomass 

  20. Minimally refined biomass fuel

    DOE Patents [OSTI]

    Pearson, Richard K. (Pleasanton, CA); Hirschfeld, Tomas B. (Livermore, CA)

    1984-01-01T23:59:59.000Z

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water solubilizes the carbohydrates; and the alcohol aids in the combustion of the carbohydrate and reduces the vicosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  1. Biomass | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: EnergyAvignon,Belcher HomesLyons BiomassBiofuels)BiomassThermal

  2. High-biomass sorghums for biomass biofuel production

    E-Print Network [OSTI]

    Packer, Daniel

    2011-05-09T23:59:59.000Z

    for breeding evaluations. Seventeen hundred ninety two exotic sorghum accessions from 7 different geographic origins were evaluated for high-biomass desirability in 3 environments. Significant relationships between passport data and high-biomass desirability...

  3. Biomass Anaerobic Digestion Facilities and Biomass Gasification Facilities (Indiana)

    Broader source: Energy.gov [DOE]

    The Indiana Department of Environmental Management requires permits before the construction or expansion of biomass anaerobic digestion or gasification facilities.

  4. Alternative Energy Development and China's Energy Future

    E-Print Network [OSTI]

    Zheng, Nina

    2012-01-01T23:59:59.000Z

    curtail-chinas-coal- gasification-for-fuel-yet-conversion-Biogas and Biomass Gasification Liquid Biofuels Bioethanolcombustion, biomass gasification and biomass co-fired coal

  5. N.J. Themelis Trip to China, October 2007 Trip of Nickolas Themelis, WTERT Chair, to China, October 18-

    E-Print Network [OSTI]

    Columbia University

    greatly by the Renewable Energy policy of the country: Coal-fired power plants receive 4-6 cents/kWh. WTE and Circulating Fluid Bed. The latter are much smaller and they need coal co-firing, up to 20% of the feed

  6. Burgeoning Biomass: Creating Efficient and Sustainable Forest Biomass Supply Chains in the Rockies

    E-Print Network [OSTI]

    1 Burgeoning Biomass: Creating Efficient and Sustainable Forest Biomass Supply Chains and removing beetle- killed trees, produce a byproduct called woody biomass. Also known as "slash, woody biomass can be collected, processed and transported SUMMARY Woody biomass could be used

  7. biomass | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    or products. More detailed information on the subject of biomassMSW gasification and co-gasification of coal and biomass is available. Challenges A few obstacles exist before...

  8. Biomass Feedstock National User Facility

    Broader source: Energy.gov [DOE]

    Breakout Session 1B—Integration of Supply Chains I: Breaking Down Barriers Biomass Feedstock National User Facility Kevin L. Kenney, Director, Biomass Feedstock National User Facility, Idaho National Laboratory

  9. ENERGY FROM BIOMASS AND

    E-Print Network [OSTI]

    in aeroderivative gas turbines has beencommerciallyestablished for natural gas-fired cogeneration since 1980. Steam!l!ledin a companionpaperprepared for this conference. 781 #12;BIOMASS-GASIFIER ~.INJECTED GAS TURBINE COGENERA110N FOR THE CANE of the gas turbine for cogeneration.applications(27) and the low unit capital cost of gas turbines comparedto

  10. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY as a result of emerging biomass opportunities on private industrial and public multiple-use lands (tracked in the vegetation domain) and the quantity of biomass consumed by the wildfire (tracked

  11. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY;12-2 #12;Appendix 12: Biomass to Energy Project Team, Committee Members and Project Advisors Research Team. Nechodom's background is in biomass energy policy development and public policy research. Peter Stine

  12. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY or recommendations of the study. 1. INTRODUCTION 1.1 Domain Description The study area for the Biomass to Energy (B2 and environmental costs and benefits of using forest biomass to generate electrical power while changing fire

  13. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY;10-2 #12;Appendix 10: Power Plant Analysis for Conversion of Forest Remediation Biomass to Renewable Fuels and Electricity 1. Report to the Biomass to Energy Project (B2E) Principal Authors: Dennis Schuetzle, TSS

  14. 7, 1733917366, 2007 Biomass burning

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 7, 17339­17366, 2007 Biomass burning plumes during the AMMA wet season experiment C. H. Mari a Creative Commons License. Atmospheric Chemistry and Physics Discussions Tracing biomass burning plumes from. Mari (marc@aero.obs-mip.fr) 17339 #12;ACPD 7, 17339­17366, 2007 Biomass burning plumes during the AMMA

  15. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY not substantively affect the findings or recommendations of the study. 2. Introduction The Biomass to Energy (B2E) Project is developing a comprehensive forest biomass-to- electricity model to identify and analyze

  16. Arnold Schwarzenegger BIOMASS TO ENERGY

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor BIOMASS TO ENERGY: FOREST MANAGEMENT FOR WILDFIRE REDUCTION, ENERGY;6-2 #12;APPENDIX 6: Cumulative Watershed Effects Analysis for the Biomass to Energy Project 1. Principal the findings or recommendations of the study. Cumulative watershed effects (CWE) of the Biomass to Energy (B2E

  17. Reburn system with feedlot biomass

    DOE Patents [OSTI]

    Annamalai, Kalyan; Sweeten, John M.

    2005-12-13T23:59:59.000Z

    The present invention pertains to the use of feedlot biomass as reburn fuel matter to reduce NO.sub.x emissions. According to one embodiment of the invention, feedlot biomass is used as the reburn fuel to reduce NO.sub.x. The invention also includes burners and boiler in which feedlot biomass serves a reburn fuel.

  18. 13, 3226932289, 2013 Biomass burning

    E-Print Network [OSTI]

    Dong, Xiquan

    ACPD 13, 32269­32289, 2013 Biomass burning aerosol properties over the Northern Great Plains T (ACP). Please refer to the corresponding final paper in ACP if available. Biomass burning aerosol Geosciences Union. 32269 #12;ACPD 13, 32269­32289, 2013 Biomass burning aerosol properties over the Northern

  19. Biomass Energy Crops: Massachusetts' Potential

    E-Print Network [OSTI]

    Schweik, Charles M.

    Biomass Energy Crops: Massachusetts' Potential Prepared for: Massachusetts Division of Energy;#12;Executive Summary In Massachusetts, biomass energy has typically meant wood chips derived from the region's extensive forest cover. Yet nationally, biomass energy from dedicated energy crops and from crop residues

  20. Condensing economizers for small coal-fired boilers and furnaces

    SciTech Connect (OSTI)

    Butcher, T.A.; Litzke, W.

    1994-01-01T23:59:59.000Z

    Condensing economizers increase the thermal efficiency of boilers by recovering sensible and latent heat from exhaust gas. These economizers are currently being used commercially for this purpose in a wide range of applications. Performance is dependent upon application-specific factors affecting the utility of recovered heat. With the addition of a condensing economizer boiler efficiency improvements up to 10% are possible. Condensing economizers can also capture flue gas particulates. In this work, the potential use of condensing economizers for both efficiency improvement and control of particulate emissions from small, coal water slurry-fired boilers was evaluated. Analysis was done to predict heat transfer and particulate capture by mechanisms including: inertial impaction, interception, diffusion, thermophoretic forces, and condensation growth. Shell-and-tube geometries were considered with flue gas on the outside of Teflon-covered tubes. Experimental studies were done with both air- and water-cooled economizers refit to a small boiler. Two experimental arrangements were used including oil-firing with injection of flyash upstream of the economizer and direct coal water slurry firing. Firing rates ranged from 27 to 82 kW (92,000 to 280,000 Btu/hr). Inertial impaction was found to be the most important particulate capture mechanism and removal efficiencies to 95% were achieved. With the addition of water sprays directly on the first row of tubes, removal efficiencies increased to 98%. Use of these sprays adversely affects heat recovery. Primary benefits of the sprays are seen to be the addition of small impaction sites and future design improvements are suggested in which such small impactors are permanently added to the highest velocity regions of the economizer. Predicted effects of these added impactors on particulate removal and pressure drop are presented.

  1. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Temi Linjewile; Connie Senior; Hong-Shig Shim; Bob Hurt; Eric Eddings; Larry Baxter

    2003-01-30T23:59:59.000Z

    This is the tenth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NO{sub x} control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. During this quarter, progress was made on the computational simulation of a full-scale boiler with the purpose of understanding the potential impacts of burner operating conditions on soot and NO{sub x} generation. Sulfation tests on both the titania support and vanadia/titania catalysts were completed using BYU's in situ spectroscopy reactor this quarter. These experiments focus on the extent to which vanadia and titania sulfate in an SO{sub 2}-laden, moist environment. Construction of the CCS reactor system is essentially complete and the control hardware and software are largely in place. A large batch of vanadia/titania catalyst in powder form has been prepared for use in poisoning tests. During this quarter, minor modifications were made to the multi-catalyst slipstream reactor and to the control system. The slipstream reactor was installed at AEP's Rockport plant at the end of November 2002. In this report, we describe the reactor system, particularly the control system, which was created by REI specifically for the reactor, as well as the installation at Rockport.

  2. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-09-30T23:59:59.000Z

    This is the seventeenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. The SCR slipstream reactor was assembled and installed at Plant Gadsden this quarter. Safety equipment for ammonia had not been installed at the end of the quarter, but will be installed at the beginning of next quarter. The reactor will be started up next quarter. Four ECN corrosion probes were reinstalled at Gavin and collected corrosion data for approximately one month. Two additional probes were installed and removed after about 30 hours for future profilometry analysis. Preliminary analysis of the ECN probes, the KEMA coupons and the CFD modeling results all agree with the ultrasonic tube test measurements gathered by AEP personnel.

  3. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Mike Bockelie; Marc Cremer; Kevin Davis; Connie Senior; Bob Hurt; Eric Eddings; Larry Baxter

    2001-10-10T23:59:59.000Z

    This is the fifth Quarterly Technical Report for DOE Cooperative Agreement No: DE-FC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The Electric Power Research Institute (EPRI) is providing cofunding for this program. This program contains multiple tasks and good progress is being made on all fronts. Field tests for NOx reduction in a cyclone fired utility boiler due to using Rich Reagent Injection (RRI) have been started. CFD modeling studies have been started to evaluate the use of RRI for NOx reduction in a corner fired utility boiler using pulverized coal. Field tests of a corrosion monitor to measure waterwall wastage in a utility boiler have been completed. Computational studies to evaluate a soot model within a boiler simulation program are continuing. Research to evaluate SCR catalyst performance has started. A literature survey was completed. Experiments have been outlined and two flow reactor systems have been designed and are under construction. Commercial catalyst vendors have been contacted about supplying catalyst samples. Several sets of new experiments have been performed to investigate ammonia removal processes and mechanisms for fly ash. Work has focused on a promising class of processes in which ammonia is destroyed by strong oxidizing agents at ambient temperature during semi-dry processing (the use of moisture amounts less than 5 wt-%). Both ozone and an ozone/peroxide combination have been used to treat both basic and acidic ammonia-laden ashes.

  4. NOx Control Options and Integration for US Coal Fired Boilers

    SciTech Connect (OSTI)

    Mike Bockelie; Kevin Davis; Connie Senior; Darren Shino; Dave Swenson; Larry Baxter; Calvin Bartholomew; William Hecker; Stan Harding

    2004-12-31T23:59:59.000Z

    This is the eighteenth Quarterly Technical Report for DOE Cooperative Agreement No: DEFC26-00NT40753. The goal of the project is to develop cost effective analysis tools and techniques for demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for boilers firing US coals. The Electric Power Research Institute (EPRI) is providing co-funding for this program. Safety equipment for ammonia for the SCR slipstream reactor at Plant Gadsden was installed. The slipstream reactor was started and operated for about 1400 hours during the last performance period. Laboratory analysis of exposed catalyst and investigations of the sulfation of fresh catalyst continued at BYU. Thicker end-caps for the ECN probes were designed and fabricated to prevent the warpage and failure that occurred at Gavin with the previous design. A refurbished ECN probe was successfully tested at the University of Utah combustion laboratory. Improvements were implemented to the software that controls the flow of cooling air to the ECN probes.

  5. DOEEA-1183 ENVIRONMENTAL ASSESSMENT COAL-FIRED DIESEL GENERATOR

    Broader source: Energy.gov (indexed) [DOE]

    (EA) (DOEEA-1183) for a project proposed by Arthur D. Little, Inc., to demonstrate a clean coal technology. Under this proposal, DOE would provide partial funding under a...

  6. Emissions of airborne toxics from coal-fired boilers: Mercury

    SciTech Connect (OSTI)

    Huang, H.S.; Livengood, C.D.; Zaromb, S.

    1991-09-01T23:59:59.000Z

    Concerns over emissions of hazardous air Pollutants (air toxics) have emerged as a major environmental issue, and the authority of the US Environmental Protection Agency to regulate such pollutants was greatly expanded through the Clean Air Act Amendments of 1990. Mercury has been singled out for particular attention because of concerns over possible effects of emissions on human health. This report evaluates available published information on the mercury content of coals mined in the United States, on mercury emitted in coal combustion, and on the efficacy of various environmental control technologies for controlling airborne emissions. Anthracite and bituminous coals have the highest mean-mercury concentrations, with subbituminous coals having the lowest. However, all coal types show very significant variations in mercury concentrations. Mercury emissions from coal combustion are not well-characterized, particularly with regard to determination of specific mercury compounds. Variations in emission rates of more than an order of magnitude have been reported for some boiler types. Data on the capture of mercury by environmental control technologies are available primarily for systems with electrostatic precipitators, where removals of approximately 20% to over 50% have been reported. Reported removals for wet flue-gas-desulfurization systems range between 35 and 95%, while spray-dryer/fabric-filter systems have given removals of 75 to 99% on municipal incinerators. In all cases, better data are needed before any definitive judgments can be made. This report briefly reviews several areas of research that may lead to improvements in mercury control for existing flue-gas-clean-up technologies and summarizes the status of techniques for measuring mercury emissions from combustion sources.

  7. Application of Multivariable Control to Oil and Coal Fired Boilers 

    E-Print Network [OSTI]

    Swanson, K.

    1981-01-01T23:59:59.000Z

    of the boiler, flue gas transport delay, existing boiler control system and analyzer dynamics. The algorithm com ponents are illustrated schematically in Figures 2 and 3. The strategy is designed to optimize com bustion efficiency under current combustion... appropriate action to avoid exceeding those limits. It then calculates the control output required to correct Ea/f without overshooting the Control target value. The entire control strategy is easily tuned in the field. Even though many boiler control...

  8. Water recovery using waste heat from coal fired power plants.

    SciTech Connect (OSTI)

    Webb, Stephen W.; Morrow, Charles W.; Altman, Susan Jeanne; Dwyer, Brian P.

    2011-01-01T23:59:59.000Z

    The potential to treat non-traditional water sources using power plant waste heat in conjunction with membrane distillation is assessed. Researchers and power plant designers continue to search for ways to use that waste heat from Rankine cycle power plants to recover water thereby reducing water net water consumption. Unfortunately, waste heat from a power plant is of poor quality. Membrane distillation (MD) systems may be a technology that can use the low temperature waste heat (<100 F) to treat water. By their nature, they operate at low temperature and usually low pressure. This study investigates the use of MD to recover water from typical power plants. It looks at recovery from three heat producing locations (boiler blow down, steam diverted from bleed streams, and the cooling water system) within a power plant, providing process sketches, heat and material balances and equipment sizing for recovery schemes using MD for each of these locations. It also provides insight into life cycle cost tradeoffs between power production and incremental capital costs.

  9. Coal-fired gas turbine for locomotive propulsion

    SciTech Connect (OSTI)

    Green, L. Jr.

    1987-01-01T23:59:59.000Z

    Substitution of a deeply-cleaned coal-water slurry fuel for bulk solid coal in an atmospheric fluidized-bed combustor permits a sequence of evolutionary steps which can convert the conventional AFBC into a pressurized, combustion-stirred, fluidized-bed heat exchanger compact enough to propel a standard locomotive by use of a closed Brayton power cycle.

  10. Advanced coal-fired glass melting development program

    SciTech Connect (OSTI)

    Not Available

    1991-05-01T23:59:59.000Z

    The objective of Phase 1 of the current contract was to verify the technical feasibility and economic benefits of Vortec's advanced combustion/melting technology using coal as the fuel of choice. The objective of the Phase 2 effort was to improve the performance of the primary components and demonstrate the effective operation of a subscale process heater system integrated with a glass separator/reservoir. (VC)

  11. Wood-Coal Fired "Small" Boiler Case Study

    E-Print Network [OSTI]

    Pincelli, R. D.

    1980-01-01T23:59:59.000Z

    Galaxy Carpet Corporation installed a coal and wood waste fired boiler approximately twelve months ago. Its first year net savings were $195,000.00 Total capital investment was paid off in 1.9 years. 20% investment tax credits were granted...

  12. Global Coal Fired Power Generation Market | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEI Reference LibraryAdd toWell2008) |GigaCrete IncIGlenrockGCEH

  13. NOx CONTROL OPTIONS AND INTEGRATION FOR US COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Michael J. Bockelie

    2000-10-31T23:59:59.000Z

    This report summarizes the research that has been performed by Reaction Engineering International (REI) during the last three months on demonstrating and evaluating low NOx control strategies and their possible impact on boiler performance for firing US coals. The focus of our efforts during the last six months have been on: (1) Field Tests for RRI at the Conectiv BL England Station Unit No.1, a 130 MW cyclone fired boiler; (2) Extending our Computational Fluid Dynamics (CFD) based NOx model to accommodate the chemistry for Rich Reagent Injection (RRI) in cyclone fired boilers; (3) Applying the NOx model to evaluate RRI systems integrated into a boiler with Over Fired Air (OFA) and Selective Non-Catalytic Reduction (SNCR); (4) Field Tests of the REI Corrosion Probe at the Conectiv BL England Station Unit No.1; (5) Commence engineering study of ammonia adsorption mechanisms for Fly Ash; (6) Presentation of current program accomplishments and plans for future work to DoE staff members at NETL-FE (Pittsburgh); and (7) Presentation of preliminary field test results for RRI to EPRI CNCIG.

  14. Life Cycle Assessment of Coal-fired Power Production

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found TheHot electron dynamics in807 DE89 002669Life Cycle

  15. OpenEI Community - Coal Fired Power Generation Market

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri: EnergyExcellenceOfficeOhio: Energy Resourcesen)

  16. OpenEI Community - Coal Fired Power Generation Market Analysis

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri: EnergyExcellenceOfficeOhio: Energy Resourcesen)

  17. OpenEI Community - Coal Fired Power Generation Market Forecast

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri: EnergyExcellenceOfficeOhio: Energy Resourcesen)

  18. OpenEI Community - Coal Fired Power Generation Market Size

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri: EnergyExcellenceOfficeOhio: Energy Resourcesen)

  19. OpenEI Community - Coal Fired Power Generation Market Trends

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri: EnergyExcellenceOfficeOhio: Energy Resourcesen)

  20. OpenEI Community - Global Coal Fired Power Generation Market

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri: EnergyExcellenceOfficeOhio: Energy Resourcesen)

  1. Coal Fired Power Generation Market Analysis | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCityFundCo-benefits Evaluation

  2. Coal Fired Power Generation Market Size | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCityFundCo-benefits EvaluationCoal

  3. Coal Fired Power Generation Market Trends | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCityFundCo-benefits EvaluationCoal

  4. Coal Fired Power Generation Market | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCityFundCo-benefits EvaluationCoalCoal

  5. Biomass Supply and Carbon Accounting for

    E-Print Network [OSTI]

    Biomass Supply and Carbon Accounting for Southeastern Forests February 2012 #12;This Biomass Supply and Carbon Accounting for Southeastern Forests study was conducted by the Biomass Energy Resource Center Biomass Energy Resource Center Kamalesh Doshi Biomass Energy Resource Center Hillary Emick Biomass Energy

  6. Science Activities in Biomass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiationImplementingnpitcheResearch BriefsTenney, Office of ScienceActivities in Biomass

  7. Hydrolysis of biomass material

    DOE Patents [OSTI]

    Schmidt, Andrew J.; Orth, Rick J.; Franz, James A.; Alnajjar, Mikhail

    2004-02-17T23:59:59.000Z

    A method for selective hydrolysis of the hemicellulose component of a biomass material. The selective hydrolysis produces water-soluble small molecules, particularly monosaccharides. One embodiment includes solubilizing at least a portion of the hemicellulose and subsequently hydrolyzing the solubilized hemicellulose to produce at least one monosaccharide. A second embodiment includes solubilizing at least a portion of the hemicellulose and subsequently enzymatically hydrolyzing the solubilized hemicellulose to produce at least one monosaccharide. A third embodiment includes solubilizing at least a portion of the hemicellulose by heating the biomass material to greater than 110.degree. C. resulting in an aqueous portion that includes the solubilized hemicellulose and a water insoluble solids portion and subsequently separating the aqueous portion from the water insoluble solids portion. A fourth embodiment is a method for making a composition that includes cellulose, at least one protein and less than about 30 weight % hemicellulose, the method including solubilizing at least a portion of hemicellulose present in a biomass material that also includes cellulose and at least one protein and subsequently separating the solubilized hemicellulose from the cellulose and at least one protein.

  8. Pull strength evaluation of Sn-Pb solder joints made to Au-Pt-Pd and Au thick film structures on low-temperature co-fired ceramic -final report for the MC4652 crypto-coded switch (W80).

    SciTech Connect (OSTI)

    Uribe, Fernando; Vianco, Paul Thomas; Zender, Gary L.

    2006-06-01T23:59:59.000Z

    A study was performed that examined the microstructure and mechanical properties of 63Sn-37Pb (wt.%, Sn-Pb) solder joints made to thick film layers on low-temperature co-fired (LTCC) substrates. The thick film layers were combinations of the Dupont{trademark} 4596 (Au-Pt-Pd) conductor and Dupont{trademark} 5742 (Au) conductor, the latter having been deposited between the 4596 layer and LTCC substrate. Single (1x) and triple (3x) thicknesses of the 4596 layer were evaluated. Three footprint sizes were evaluated of the 5742 thick film. The solder joints exhibited excellent solderability of both the copper (Cu) lead and thick film surface. In all test sample configurations, the 5742 thick film prevented side wall cracking of the vias. The pull strengths were in the range of 3.4-4.0 lbs, which were only slightly lower than historical values for alumina (Al{sub 2}O{sub 3}) substrates. General (qualitative) observations: (a) The pull strength was maximized when the total number of thick film layers was between two and three. Fewer that two layers did not develop as strong of a bond at the thick film/LTCC interface; more than three layers and of increased footprint area, developed higher residual stresses at the thick film/LTCC interface and in the underlying LTCC material that weakened the joint. (b) Minimizing the area of the weaker 4596/LTCC interface (e.g., larger 5742 area) improved pull strength. Specific observations: (a) In the presence of vias and the need for the 3x 4596 thick film, the preferred 4596:5742 ratio was 1.0:0.5. (b) For those LTCC components that require the 3x 4596 layer, but do not have vias, it is preferred to refrain from using the 5742 layer. (c) In the absence of vias, the highest strength was realized with a 1x thick 5742 layer, a 1x thick 4596 layer, and a footprint ratio of 1.0:1.0.

  9. An analysis of the pull strength behaviors of fine-pitch, flip chip solder interconnections using a Au-Pt-Pd thick film conductor on Low-Temperature, Co-fired Ceramic (LTCC) substrates.

    SciTech Connect (OSTI)

    Uribe, Fernando R.; Kilgo, Alice C.; Grazier, John Mark; Vianco, Paul Thomas; Zender, Gary L.; Hlava, Paul Frank; Rejent, Jerome Andrew

    2008-09-01T23:59:59.000Z

    The assembly of the BDYE detector requires the attachment of sixteen silicon (Si) processor dice (eight on the top side; eight on the bottom side) onto a low-temperature, co-fired ceramic (LTCC) substrate using 63Sn-37Pb (wt.%, Sn-Pb) in a double-reflow soldering process (nitrogen). There are 132 solder joints per die. The bond pads were gold-platinum-palladium (71Au-26Pt-3Pd, wt.%) thick film layers fired onto the LTCC in a post-process sequence. The pull strength and failure modes provided the quality metrics for the Sn-Pb solder joints. Pull strengths were measured in both the as-fabricated condition and after exposure to thermal cycling (-55/125 C; 15 min hold times; 20 cycles). Extremely low pull strengths--referred to as the low pull strength phenomenon--were observed intermittently throughout the product build, resulting in added program costs, schedule delays, and a long-term reliability concern for the detector. There was no statistically significant correlation between the low pull strength phenomenon and (1) the LTCC 'sub-floor' lot; (2) grit blasting the LTCC surfaces prior to the post-process steps; (3) the post-process parameters; (4) the conductor pad height (thickness); (5) the dice soldering assembly sequence; or (5) the dice pull test sequence. Formation of an intermetallic compound (IMC)/LTCC interface caused by thick film consumption during either the soldering process or by solid-state IMC formation was not directly responsible for the low-strength phenomenon. Metallographic cross sections of solder joints from dice that exhibited the low pull strength behavior, revealed the presence of a reaction layer resulting from an interaction between Sn from the molten Sn-Pb and the glassy phase at the TKN/LTCC interface. The thick film porosity did not contribute, explicitly, to the occurrence of reaction layer. Rather, the process of printing the very thin conductor pads was too sensitive to minor thixotropic changes to ink, which resulted in inconsistent proportions of metal and glassy phase particles present during the subsequent firing process. The consequences were subtle, intermittent changes to the thick film microstructure that gave rise to the reaction layer and, thus, the low pull strength phenomenon. A mitigation strategy would be the use of physical vapor deposition (PVD) techniques to create thin film bond pads; this is multi-chip module, deposited (MCM-D) technology.

  10. Biomass -Feedstock User Facility

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureCommentsEnergyandapproximately 10 wt%inandWBS 1.2.3.3 Biomass -

  11. Biomass 2013: Welcome

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureCommentsEnergyandapproximately 10 wt%inandWBS 1.2.3.31Biomass 2013

  12. Biomass Scenario Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureCommentsEnergyandapproximately 10 wt%inandWBSBiomassAct ofBiomass

  13. Hydrothermal Liquefaction of Biomass

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2010-12-10T23:59:59.000Z

    Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international collaboration with Canada to investigate kelp (seaweed) as a biomass feedstock. The collaborative project includes process testing of the kelp in HydroThermal Liquefaction in the bench-scale unit at PNNL. HydroThermal Liquefaction at PNNL is performed in the hydrothermal processing bench-scale reactor system. Slurries of biomass are prepared in the laboratory from whole ground biomass materials. Both wet processing and dry processing mills can be used, but the wet milling to final slurry is accomplished in a stirred ball mill filled with angle-cut stainless steel shot. The PNNL HTL system, as shown in the figure, is a continuous-flow system including a 1-litre stirred tank preheater/reactor, which can be connected to a 1-litre tubular reactor. The product is filtered at high-pressure to remove mineral precipitate before it is collected in the two high-pressure collectors, which allow the liquid products to be collected batchwise and recovered alternately from the process flow. The filter can be intermittently back-flushed as needed during the run to maintain operation. By-product gas is vented out the wet test meter for volume measurement and samples are collected for gas chromatography compositional analysis. The bio-oil product is analyzed for elemental content in order to calculate mass and elemental balances around the experiments. Detailed chemical analysis is performed by gas chromatography-mass spectrometry and 13-C nuclear magnetic resonance is used to evaluate functional group types in the bio-oil. Sufficient product is produced to allow subsequent catalytic hydroprocessing to produce liquid hydrocarbon fuels. The product bio-oil from hydrothermal liquefaction is typically a more viscous product compared to fast pyrolysis bio-oil. There are several reasons for this difference. The HTL bio-oil contains a lower level of oxygen because of more extensive secondary reaction of the pyrolysis products. There are less amounts of the many light oxygenates derived from the carbohydrate structures as they have been further reacted to phenolic Aldol condensation products. The bio-oil

  14. Biomass: Biogas Generator

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find Find MoreTechnical Report: BiomassInnovationBIOGAS

  15. Remotely sensed heat anomalies linked with Amazonian forest biomass declines

    E-Print Network [OSTI]

    Toomey, M.; Roberts, D. A.; Still, C.; Goulden, M. L.; McFadden, J. P.

    2011-01-01T23:59:59.000Z

    with Amazonian forest biomass declines Michael Toomey, 1 Darof aboveground living biomass (p biomass declines, Geophys. Res.

  16. Interactions of Lignin and Hemicellulose and Effects on Biomass Deconstruction

    E-Print Network [OSTI]

    Li, Hongjia

    2012-01-01T23:59:59.000Z

    such lignocellulosic biomass feedstocks into ethanol via atools. Different biomass feedstocks have different cell wallmajor lignocellulosic biomass feedstocks, except softwoods,

  17. NREL: Biomass Research - Joseph Shekiro

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deacetylation and Mechanical (Disc) Refining Process for the Conversion of Renewable Biomass to Lower Cost Sugars." Biotechnology for Biofuels (7:7). Shekiro, J. ; Kuhn, E.M.;...

  18. NREL: Biomass Research - Josh Schaidle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of pyrolysis products to produce fungible transportation fuels. Research Interests Biomass conversion to fuels and chemicals Environmentally-sustainable engineering practices...

  19. NREL: Biomass Research - Michael Resch

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    improve the hydrolysis efficiency of cellulase and hemicellulase enzyme digestion of biomass. This work will help NREL lower the industrial cost of lignocellulosic enzyme...

  20. Sandia National Laboratories: Lignocellulosic Biomass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    industrial process environments, (3) development of high-throughput assays using microfluidics, and (4) understanding how microbial communities degrade biomass and the...

  1. Biomass Gasification | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    gasification involve reducing costs associated with capital equipment and biomass feedstocks. Research to lower capital costs: If oxygen is used in the gasifier, capital...

  2. Biomass Rapid Analysis Network (BRAN)

    SciTech Connect (OSTI)

    Not Available

    2003-10-01T23:59:59.000Z

    Helping the emerging biotechnology industry develop new tools and methods for real-time analysis of biomass feedstocks, process intermediates and The Biomass Rapid Analysis Network is designed to fast track the development of modern tools and methods for biomass analysis to accelerate the development of the emerging industry. The network will be led by industry and organized and coordinated through the National Renewable Energy Lab. The network will provide training and other activities of interest to BRAN members. BRAN members will share the cost and work of rapid analysis method development, validate the new methods, and work together to develop the training for the future biomass conversion workforce.

  3. System and process for biomass treatment

    DOE Patents [OSTI]

    Dunson, Jr., James B; Tucker, III, Melvin P; Elander, Richard T; Lyons, Robert C

    2013-08-20T23:59:59.000Z

    A system including an apparatus is presented for treatment of biomass that allows successful biomass treatment at a high solids dry weight of biomass in the biomass mixture. The design of the system provides extensive distribution of a reactant by spreading the reactant over the biomass as the reactant is introduced through an injection lance, while the biomass is rotated using baffles. The apparatus system to provide extensive assimilation of the reactant into biomass using baffles to lift and drop the biomass, as well as attrition media which fall onto the biomass, to enhance the treatment process.

  4. Biomass in the Deregulated Marketplace: Current Issues for Biomass Power

    SciTech Connect (OSTI)

    Not Available

    1998-12-01T23:59:59.000Z

    This issue brief provides readers with a monthly review and analysis of electric utility deregulation as it impacts biomass power production and distribution. The topical areas to be routinely covered will include Federal activities, State activities, Current challenges, and Current opportunities. Additionally, a monthly highlighted topic will provide more in-depth analysis of current issue impacting biomass power.

  5. Process for concentrated biomass saccharification

    DOE Patents [OSTI]

    Hennessey, Susan M. (Avondale, PA); Seapan, Mayis (Landenberg, PA); Elander, Richard T. (Evergreen, CO); Tucker, Melvin P. (Lakewood, CO)

    2010-10-05T23:59:59.000Z

    Processes for saccharification of pretreated biomass to obtain high concentrations of fermentable sugars are provided. Specifically, a process was developed that uses a fed batch approach with particle size reduction to provide a high dry weight of biomass content enzymatic saccharification reaction, which produces a high sugars concentration hydrolysate, using a low cost reactor system.

  6. Biomass 2014 Attendee List | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    is the attendee list for Biomass 2014, held July 29-July 30 in Washington, D.C. biomass2014attendeelist.pdf More Documents & Publications Biomass 2013 Attendee List Bioproducts:...

  7. BIOMASS LIQUEFACTION EFFORTS IN THE UNITED STATES

    E-Print Network [OSTI]

    Ergun, Sabri

    2012-01-01T23:59:59.000Z

    icat ion Preheat zone Biomass liquefaction Tubular reactor (design is shown in Figure 7, C I Biomass ua efaction Fic LBL Process BiOMASS t NON-REVERS lNG CYCLONE CONDENSER (

  8. Treatment of biomass to obtain fermentable sugars

    DOE Patents [OSTI]

    Dunson, Jr., James B. (Newark, DE); Tucker, Melvin (Lakewood, CO); Elander, Richard (Evergreen, CO); Hennessey, Susan M. (Avondale, PA)

    2011-04-26T23:59:59.000Z

    Biomass is pretreated using a low concentration of aqueous ammonia at high biomass concentration. Pretreated biomass is further hydrolyzed with a saccharification enzyme consortium. Fermentable sugars released by saccharification may be utilized for the production of target chemicals by fermentation.

  9. Biomass Producer or Collector Tax Credit (Oregon)

    Broader source: Energy.gov [DOE]

     The Oregon Department of Energy provides a tax credit for agricultural producers or collectors of biomass.  The credit can be used for eligible biomass used to produce biofuel; biomass used in...

  10. Mobile Biomass Pelletizing System

    SciTech Connect (OSTI)

    Thomas Mason

    2009-04-16T23:59:59.000Z

    This grant project examines multiple aspects of the pelletizing process to determine the feasibility of pelletizing biomass using a mobile form factor system. These aspects are: the automatic adjustment of the die height in a rotary-style pellet mill, the construction of the die head to allow the use of ceramic materials for extreme wear, integrating a heat exchanger network into the entire process from drying to cooling, the use of superheated steam for adjusting the moisture content to optimum, the economics of using diesel power to operate the system; a break-even analysis of estimated fixed operating costs vs. tons per hour capacity. Initial development work has created a viable mechanical model. The overall analysis of this model suggests that pelletizing can be economically done using a mobile platform.

  11. Investigation of an integrated switchgrass gasification/fuel cell power plant. Final report for Phase 1 of the Chariton Valley Biomass Power Project

    SciTech Connect (OSTI)

    Brown, R.C.; Smeenk, J. [Iowa State Univ., Ames, IA (United States); Steinfeld, G. [Energy Research Corp., Danbury, CT (United States)

    1998-09-30T23:59:59.000Z

    The Chariton Valley Biomass Power Project, sponsored by the US Department of Energy Biomass Power Program, has the goal of converting switchgrass grown on marginal farmland in southern Iowa into electric power. Two energy conversion options are under evaluation: co-firing switchgrass with coal in an existing utility boiler and gasification of switchgrass for use in a carbonate fuel cell. This paper describes the second option under investigation. The gasification study includes both experimental testing in a pilot-scale gasifier and computer simulation of carbonate fuel cell performance when operated on gas derived from switchgrass. Options for comprehensive system integration between a carbonate fuel cell and the gasification system are being evaluated. Use of waste heat from the carbonate fuel cell to maximize overall integrated plant efficiency is being examined. Existing fuel cell power plant design elements will be used, as appropriate, in the integration of the gasifier and fuel cell power plant to minimize cost complexity and risk. The gasification experiments are being performed by Iowa State University and the fuel cell evaluations are being performed by Energy Research Corporation.

  12. NREL: Biomass Research - Robert M. Baldwin

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MI. Dr. Baldwin has extensive experience and expertise in thermochemical conversion of biomass to gaseous and liquid fuels, including catalysis and reaction engineering of biomass...

  13. NREL: Biomass Research - Daniel J. Schell

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    more than 30 years of research experience in bio-based conversion of lignocellulosic biomass and has extensive expertise in integrated biomass conversion operations at the bench...

  14. NREL: Biomass Research - News Release Archives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Facility (IBRF). June 2, 2011 Science & Industry Peers Turn to NREL for Biomass Solutions The biomass industry looks to the U.S. Department of Energy's National...

  15. Supplying High-Quality, Raw Biomass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supplying High-Quality, Raw Biomass The building blocks to supply high-quality raw biomass start with harvesting and collection practices, product storage and recommendations of...

  16. Molecular Characterization of Biomass Burning Aerosols Using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass Burning Aerosols Using High Resolution Mass Spectrometry. Molecular Characterization of Biomass Burning Aerosols Using High Resolution Mass Spectrometry. Abstract: Chemical...

  17. Converting Biomass to High-Value Feedstocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Converting Biomass to High-Value Feedstocks Advanced feedstocks play an important role in economically and efficiently converting biomass into bioenergy products. Advanced...

  18. BSCL Use Plan: Solving Biomass Recalcitrance

    SciTech Connect (OSTI)

    Himmel, M.; Vinzant, T.; Bower, S.; Jechura, J.

    2005-08-01T23:59:59.000Z

    Technical report describing NREL's new Biomass Surface Characterization Laboratory (BSCL). The BSCL was constructed to provide the most modern commercial surface characterization equipment for studying biomass surfaces.

  19. Hydrogen Production Cost Estimate Using Biomass Gasification...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost Estimate Using Biomass Gasification: Independent Review Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review This independent review is the...

  20. Symbiosis: Addressing Biomass Production Challenges and Climate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Symbiosis: Addressing Biomass Production Challenges and Climate Change Symbiosis: Addressing Biomass Production Challenges and Climate Change This presentation was the opening...

  1. Coal-Biomass Feed and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal-Biomass Feed and Gasification The Coal-Biomass Feed and Gasification Key Technology is advancing scientific knowledge of the production of liquid hydrocarbon fuels from coal...

  2. Biomass Guidelines (Prince Edward Island, Canada)

    Broader source: Energy.gov [DOE]

    PEI Biomass Guidelines identify two major pathways that biomass projects may follow: No Public Investment, and Public Investment. Projects with Public Investment include any project that has:

  3. Hydrogen Production Cost Estimate Using Biomass Gasification

    E-Print Network [OSTI]

    Hydrogen Production Cost Estimate Using Biomass Gasification National Renewable Energy Laboratory Panel, Hydrogen Production Cost Estimate Using Biomass Gasification To: Mr. Mark Ruth, NREL, DOE

  4. NREL: Biomass Research - Ryan M. Ness

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    involve bench-scale wet chemical and instrumental analysis of lignocellulosic biomass feedstocks for the purpose of providing baseline, solids-intermediate, and biomass...

  5. NREL: Biomass Research - Biochemical Conversion Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL's projects in biochemical conversion involve three basic steps to convert biomass feedstocks to fuels: Converting biomass to sugar or other fermentation feedstock Fermenting...

  6. Renewable Energy and Efficiency Modeling Analysis Partnership: An Analysis of How Different Energy Models Addressed a Common High Renewable Energy Penetration Scenario in 2025

    E-Print Network [OSTI]

    Blair, N.

    2010-01-01T23:59:59.000Z

    eligible hydropower, landfill gas, and municipal solidgeothermal, biomass, landfill gas, solar, ocean, and theCo-Fired Biomass Landfill Gas Solar Ocean Existing (2004) Y

  7. Renewable Energy and Efficiency Modeling Analysis Partnership: An Analysis of How Different Energy Models Addressed a Common High Renewable Energy Penetration Scenario in 2025

    E-Print Network [OSTI]

    Blair, N.

    2010-01-01T23:59:59.000Z

    eligible hydropower, landfill gas, and municipal solidwind, geothermal, biomass, landfill gas, solar, ocean, andCo-Fired Biomass Landfill Gas Solar Ocean Existing (2004) Y

  8. Biothermal gasification of biomass

    SciTech Connect (OSTI)

    Chynoweth, D.P.; Srivastava, V.J.; Henry, M.P.; Tarman, P.B.

    1980-01-01T23:59:59.000Z

    The BIOTHERMGAS Process is described for conversion of biomass, organic residues, and peat to substitute natural gas (SNG). This new process, under development at IGT, combines biological and thermal processes for total conversion of a broad variety of organic feeds (regardless of water or nutrient content). The process employs thermal gasification for conversion of refractory digester residues. Ammonia and other inorganic nutrients are recycled from the thermal process effluent to the bioconversion unit. Biomethanation and catalytic methanation are presented as alternative processes for methanation of thermal conversion product gases. Waste heat from the thermal component is used to supply the digester heat requirements of the bioconversion component. The results of a preliminary systems analysis of three possible applications of this process are presented: (1) 10,000 ton/day Bermuda grass plant with catalytic methanation; (2) 10,000 ton/day Bermuda grass plant with biomethanation; and (3) 1000 ton/day municipal solid waste (MSW) sewage sludge plant with biomethanation. The results indicate that for these examples, performance is superior to that expected for biological or thermal processes used separately. The results of laboratory studies presented suggest that effective conversion of thermal product gases can be accomplished by biomethanation.

  9. RENEWABLE ENERGY AND ENVIRONMENTAL SUSTAINABILITY USING BIOMASS FROM DAIRY AND BEEF ANIMAL PRODUCTION

    SciTech Connect (OSTI)

    John M. Sweeten, Kalyan Annamalai

    2012-05-03T23:59:59.000Z

    ABSTRACT The Texas Panhandle is regarded as the â??Cattle Feeding Capital of the Worldâ?ť, producing 42% of the fed beef cattle in the United States within a 200-mile radius of Amarillo generating more than 5 million tons of feedlot manure /year. Apart from feedlots, the Bosque River Region in Erath County, just north of Waco, Texas with about 110,000 dairy cattle in over 250 dairies, produces 1.8 million tons of manure biomass (excreted plus bedding) per year. While the feedlot manure has been used extensively for irrigated and dry land crop production, most dairies, as well as other concentrated animal feeding operations (CAFOâ??s), the dairy farms utilize large lagoon areas to store wet animal biomass. Water runoff from these lagoons has been held responsible for the increased concentration of phosphorus and other contaminates in the Bosque River which drains into Lake Wacoâ??the primary source of potable water for Wacoâ??s 108,500 people. The concentrated animal feeding operations may lead to land, water, and air pollution if waste handling systems and storage and treatment structures are not properly managed. Manure-based biomass (MBB) has the potential to be a source of green energy at large coal-fired power plants and on smaller-scale combustion systems at or near confined animal feeding operations. Although MBB particularly cattle biomass (CB) is a low quality fuel with an inferior heat value compared to coal and other fossil fuels, the concentration of it at large animal feeding operations can make it a viable source of fuel. The overall objective of this interdisciplinary proposal is to develop environmentally benign technologies to convert low-value inventories of dairy and beef cattle biomass into renewable energy. Current research expands the suite of technologies by which cattle biomass (CB: manure, and premature mortalities) could serve as a renewable alternative to fossil fuel. The work falls into two broad categories of research and development. Category 1 â?? Renewable Energy Conversion. This category addressed mostly in volume I involves developing. Thermo-chemical conversion technologies including cofiring with coal, reburn to reduce nitrogen oxide (NO, N2O, NOx, etc.) and Hg emissions and gasification to produce low-BTU gas for on-site power production in order to extract energy from waste streams or renewable resources. Category 2 â?? Biomass Resource Technology. This category, addressed mostly in Volume II, deals with the efficient and cost-effective use of CB as a renewable energy source (e.g. through and via aqueous-phase, anaerobic digestion or biological gasification). The investigators formed an industrial advisory panel consisting fuel producers (feedlots and dairy farms) and fuel users (utilities), periodically met with them, and presented the research results; apart from serving as dissemination forum, the PIs used their critique to red-direct the research within the scope of the tasks. The final report for the 5 to 7 year project performed by an interdisciplinary team of 9 professors is arranged in three volumes: Vol. I (edited by Kalyan Annamalai) addressing thermo-chemical conversion and direct combustion under Category 1 and Vol. II and Vol. III ( edited by J M Sweeten) addressing biomass resource Technology under Category 2. Various tasks and sub-tasks addressed in Volume I were performed by the Department of Mechanical Engineering (a part of TEES; see Volume I), while other tasks and sub-tasks addressed in Volume II and IIII were conducted by Texas AgriLife Research at Amarillo; the TAMU Biological & Agricultural Engineering Department (BAEN) College Station; and West Texas A&M University (WTAMU) (Volumes II and III). The three volume report covers the following results: fuel properties of low ash and high ash CB (particularly DB) and MB (mortality biomass and coals, non-intrusive visible infrared (NVIR) spectroscopy techniques for ash determination, dairy energy use surveys at 14 dairies in Texas and Califor

  10. RENEWABLE ENERGY AND ENVIRONMENTAL SUSTAINABILITY USING BIOMASS FROM DAIRY AND BEEF ANIMAL PRODUCTION

    SciTech Connect (OSTI)

    Kalyan Annamalai, John M. Sweeten,

    2012-05-03T23:59:59.000Z

    The Texas Panhandle is regarded as the 'Cattle Feeding Capital of the World', producing 42% of the fed beef cattle in the United States within a 200-mile radius of Amarillo generating more than 5 million tons of feedlot manure/year. Apart from feedlots, the Bosque River Region in Erath County, just north of Waco, Texas with about 110,000 dairy cattle in over 250 dairies, produces 1.8 million tons of manure biomass (excreted plus bedding) per year. While the feedlot manure has been used extensively for irrigated and dry land crop production, most dairies, as well as other concentrated animal feeding operations (CAFO's), the dairy farms utilize large lagoon areas to store wet animal biomass. Water runoff from these lagoons has been held responsible for the increased concentration of phosphorus and other contaminates in the Bosque River which drains into Lake Waco - the primary source of potable water for Waco's 108,500 people. The concentrated animal feeding operations may lead to land, water, and air pollution if waste handling systems and storage and treatment structures are not properly managed. Manure-based biomass (MBB) has the potential to be a source of green energy at large coal-fired power plants and on smaller-scale combustion systems at or near confined animal feeding operations. Although MBB particularly cattle biomass (CB) is a low quality fuel with an inferior heat value compared to coal and other fossil fuels, the concentration of it at large animal feeding operations can make it a viable source of fuel. The overall objective of this interdisciplinary proposal is to develop environmentally benign technologies to convert low-value inventories of dairy and beef cattle biomass into renewable energy. Current research expands the suite of technologies by which cattle biomass (CB: manure, and premature mortalities) could serve as a renewable alternative to fossil fuel. The work falls into two broad categories of research and development. Category 1 - Renewable Energy Conversion. This category addressed mostly in volume I involves developing. Thermo-chemical conversion technologies including cofiring with coal, reburn to reduce nitrogen oxide (NO, N2O, NOx, etc.) and Hg emissions and gasification to produce low-BTU gas for on-site power production in order to extract energy from waste streams or renewable resources. Category 2 - Biomass Resource Technology. This category, addressed mostly in Volume II, deals with the efficient and cost-effective use of CB as a renewable energy source (e.g. through and via aqueous-phase, anaerobic digestion or biological gasification). The investigators formed an industrial advisory panel consisting fuel producers (feedlots and dairy farms) and fuel users (utilities), periodically met with them, and presented the research results; apart from serving as dissemination forum, the PIs used their critique to red-direct the research within the scope of the tasks. The final report for the 5 to 7 year project performed by an interdisciplinary team of 9 professors is arranged in three volumes: Vol. I (edited by Kalyan Annamalai) addressing thermo-chemical conversion and direct combustion under Category 1 and Vol. II and Vol. III ( edited by J M Sweeten) addressing biomass resource Technology under Category 2. Various tasks and sub-tasks addressed in Volume I were performed by the Department of Mechanical Engineering (a part of TEES; see Volume I), while other tasks and sub-tasks addressed in Volume II and IIII were conducted by Texas AgriLife Research at Amarillo; the TAMU Biological and Agricultural Engineering Department (BAEN) College Station; and West Texas A and M University (WTAMU) (Volumes II and III). The three volume report covers the following results: fuel properties of low ash and high ash CB (particularly DB) and MB (mortality biomass) and coals, non-intrusive visible infrared (NVIR) spectroscopy techniques for ash determination, dairy energy use surveys at 14 dairies in Texas and California, cofiring of low quality CB with high quality coal, emission results and ash fouling beh

  11. RENEWABLE ENERGY AND ENVIRONMENTAL SUSTAINABILITY USING BIOMASS FROM DAIRY AND BEEF ANIMAL PRODUCTION

    SciTech Connect (OSTI)

    John M. Sweeten, Kalyan Annamalai

    2012-05-02T23:59:59.000Z

    The Texas Panhandle is regarded as the �Cattle Feeding Capital of the World�, producing 42% of the fed beef cattle in the United States within a 200-mile radius of Amarillo generating more than 5 million tons of feedlot manure /year. Apart from feedlots, the Bosque River Region in Erath County, just north of Waco, Texas with about 110,000 dairy cattle in over 250 dairies, produces 1.8 million tons of manure biomass (excreted plus bedding) per year. While the feedlot manure has been used extensively for irrigated and dry land crop production, most dairies, as well as other concentrated animal feeding operations (CAFO�s), the dairy farms utilize large lagoon areas to store wet animal biomass. Water runoff from these lagoons has been held responsible for the increased concentration of phosphorus and other contaminates in the Bosque River which drains into Lake Waco�the primary source of potable water for Waco�s 108,500 people. The concentrated animal feeding operations may lead to land, water, and air pollution if waste handling systems and storage and treatment structures are not properly managed. Manure-based biomass (MBB) has the potential to be a source of green energy at large coal-fired power plants and on smaller-scale combustion systems at or near confined animal feeding operations. Although MBB particularly cattle biomass (CB) is a low quality fuel with an inferior heat value compared to coal and other fossil fuels, the concentration of it at large animal feeding operations can make it a viable source of fuel. The overall objective of this interdisciplinary proposal is to develop environmentally benign technologies to convert low-value inventories of dairy and beef cattle biomass into renewable energy. Current research expands the suite of technologies by which cattle biomass (CB: manure, and premature mortalities) could serve as a renewable alternative to fossil fuel. The work falls into two broad categories of research and development. Category 1 � Renewable Energy Conversion. This category addressed mostly in volume I involves developing. Thermo-chemical conversion technologies including cofiring with coal, reburn to reduce nitrogen oxide (NO, N2O, NOx, etc.) and Hg emissions and gasification to produce low-BTU gas for on-site power production in order to extract energy from waste streams or renewable resources. Category 2 � Biomass Resource Technology. This category, addressed mostly in Volume II, deals with the efficient and cost-effective use of CB as a renewable energy source (e.g. through and via aqueous-phase, anaerobic digestion or biological gasification). The investigators formed an industrial advisory panel consisting fuel producers (feedlots and dairy farms) and fuel users (utilities), periodically met with them, and presented the research results; apart from serving as dissemination forum, the PIs used their critique to red-direct the research within the scope of the tasks. The final report for the 5 to 7 year project performed by an interdisciplinary team of 9 professors is arranged in three volumes: Vol. I (edited by Kalyan Annamalai) addressing thermo-chemical conversion and direct combustion under Category 1 and Vol. II and Vol. III ( edited by J M Sweeten) addressing biomass resource Technology under Category 2. Various tasks and sub-tasks addressed in Volume I were performed by the Department of Mechanical Engineering (a part of TEES; see Volume I), while other tasks and sub-tasks addressed in Volume II and IIII were conducted by Texas AgriLife Research at Amarillo; the TAMU Biological & Agricultural Engineering Department (BAEN) College Station; and West Texas A&M University (WTAMU) (Volumes II and III). The three volume report covers the following results: fuel properties of low ash and high ash CB (particularly DB) and MB (mortality biomass and coals, non-intrusive visible infrared (NVIR) spectroscopy techniques for ash determination, dairy energy use surveys a

  12. Ohio Biomass Energy Program (Ohio)

    Broader source: Energy.gov [DOE]

    Ohio is one of seven states participating in the Great Lakes Regional Biomass Energy Program which was established in 1983. The Regional Program is administered by the Council of Great Lakes...

  13. Biomass Supply for a Bioenergy

    E-Print Network [OSTI]

    Hydrocarbon-based Biofuels; Zia Haq

    2012-01-01T23:59:59.000Z

    Resource assessment – do we have enough biomass? Techno-economic analysis – can biofuels be produced at competitive prices? • Integrated biorefineries – what is being funded at DOE and what are future plans?

  14. Cadmium Biosorption Rate in Protonated Sargassum Biomass

    E-Print Network [OSTI]

    Volesky, Bohumil

    Cadmium Biosorption Rate in Protonated Sargassum Biomass J I N B A I Y A N G A N D B O H U M I L V Sargassum fluitans biomass was accompanied by the release of hydrogen protons from the biomass. The uptake the overall biosorption rate of cadmium ions in flat seaweed biomass particles. The overall biosorption

  15. Global (International) Energy Policy and Biomass

    SciTech Connect (OSTI)

    Overend, R. P.

    2004-01-01T23:59:59.000Z

    Presentation to the California Biomass Collaboration--First Annual Forum, January 8th 2004, Sacramento, California

  16. Biomass Surface Characterization Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-04-01T23:59:59.000Z

    This fact sheet provides information about Biomass Surface Characterization Laboratory capabilities and applications at NREL.

  17. November 2011 Competition for biomass among

    E-Print Network [OSTI]

    Noble, James S.

    remain high, limiting the development of national or even regional markets for biomass feedstocks. We

  18. Enzymatic Hydrolysis of Cellulosic Biomass

    SciTech Connect (OSTI)

    Yang, Bin; Dai, Ziyu; Ding, Shi-You; Wyman, Charles E.

    2011-08-22T23:59:59.000Z

    Biological conversion of cellulosic biomass to fuels and chemicals offers the high yields to products vital to economic success and the potential for very low costs. Enzymatic hydrolysis that converts lignocellulosic biomass to fermentable sugars may be the most complex step in this process due to substrate-related and enzyme-related effects and their interactions. Although enzymatic hydrolysis offers the potential for higher yields, higher selectivity, lower energy costs, and milder operating conditions than chemical processes, the mechanism of enzymatic hydrolysis and the relationship between the substrate structure and function of various glycosyl hydrolase components are not well understood. Consequently, limited success has been realized in maximizing sugar yields at very low cost. This review highlights literature on the impact of key substrate and enzyme features that influence performance to better understand fundamental strategies to advance enzymatic hydrolysis of cellulosic biomass for biological conversion to fuels and chemicals. Topics are summarized from a practical point of view including characteristics of cellulose (e.g., crystallinity, degree of polymerization, and accessible surface area) and soluble and insoluble biomass components (e.g., oligomeric xylan, lignin, etc.) released in pretreatment, and their effects on the effectiveness of enzymatic hydrolysis. We further discuss the diversity, stability, and activity of individual enzymes and their synergistic effects in deconstructing complex lignocellulosic biomass. Advanced technologies to discover and characterize novel enzymes and to improve enzyme characteristics by mutagenesis, post-translational modification, and over-expression of selected enzymes and modifications in lignocellulosic biomass are also discussed.

  19. Instructions for CEC-1250E-4 Biomass and Fossil Fuel Usage Report for Biomass Facilities

    E-Print Network [OSTI]

    Instructions for CEC-1250E-4 Biomass and Fossil Fuel Usage Report for Biomass Facilities Biomass energy input basis in the upcoming calendar year? - Please check "yes" or "no." 12. Types of Biomass Fuel Used - Please report the quantity and supplier of the following types of biomass fuel used

  20. Biomass and Bioenergy 31 (2007) 646655 Estimating biomass of individual pine trees using airborne lidar

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    Biomass and Bioenergy 31 (2007) 646­655 Estimating biomass of individual pine trees using airborne biomass and bio-energy feedstocks. The overall goal of this study was to develop a method for assessing aboveground biomass and component biomass for individual trees using airborne lidar data in forest settings

  1. Fiscalini Farms Biomass Energy Project

    SciTech Connect (OSTI)

    William Stringfellow; Mary Kay Camarillo; Jeremy Hanlon; Michael Jue; Chelsea Spier

    2011-09-30T23:59:59.000Z

    In this final report describes and documents research that was conducted by the Ecological Engineering Research Program (EERP) at the University of the Pacific (Stockton, CA) under subcontract to Fiscalini Farms LP for work under the Assistance Agreement DE-EE0001895 'Measurement and Evaluation of a Dairy Anaerobic Digestion/Power Generation System' from the United States Department of Energy, National Energy Technology Laboratory. Fiscalini Farms is operating a 710 kW biomass-energy power plant that uses bio-methane, generated from plant biomass, cheese whey, and cattle manure via mesophilic anaerobic digestion, to produce electricity using an internal combustion engine. The primary objectives of the project were to document baseline conditions for the anaerobic digester and the combined heat and power (CHP) system used for the dairy-based biomass-energy production. The baseline condition of the plant was evaluated in the context of regulatory and economic constraints. In this final report, the operation of the plant between start-up in 2009 and operation in 2010 are documented and an interpretation of the technical data is provided. An economic analysis of the biomass energy system was previously completed (Appendix A) and the results from that study are discussed briefly in this report. Results from the start-up and first year of operation indicate that mesophilic anaerobic digestion of agricultural biomass, combined with an internal combustion engine, is a reliable source of alternative electrical production. A major advantage of biomass energy facilities located on dairy farms appears to be their inherent stability and ability to produce a consistent, 24 hour supply of electricity. However, technical analysis indicated that the Fiscalini Farms system was operating below capacity and that economic sustainability would be improved by increasing loading of feedstocks to the digester. Additional operational modifications, such as increased utilization of waste heat and better documentation of potential of carbon credits, would also improve the economic outlook. Analysis of baseline operational conditions indicated that a reduction in methane emissions and other greenhouse gas savings resulted from implementation of the project. The project results indicate that using anaerobic digestion to produce bio-methane from agricultural biomass is a promising source of electricity, but that significant challenges need to be addressed before dairy-based biomass energy production can be fully integrated into an alternative energy economy. The biomass energy facility was found to be operating undercapacity. Economic analysis indicated a positive economic sustainability, even at the reduced power production levels demonstrated during the baseline period. However, increasing methane generation capacity (via the importation of biomass codigestate) will be critical for increasing electricity output and improving the long-term economic sustainability of the operation. Dairy-based biomass energy plants are operating under strict environmental regulations applicable to both power-production and confined animal facilities and novel approached are being applied to maintain minimal environmental impacts. The use of selective catalytic reduction (SCR) for nitrous oxide control and a biological hydrogen sulfide control system were tested at this facility. Results from this study suggest that biomass energy systems can be compliant with reasonable scientifically based air and water pollution control regulations. The most significant challenge for the development of biomass energy as a viable component of power production on a regional scale is likely to be the availability of energy-rich organic feedstocks. Additionally, there needs to be further development of regional expertise in digester and power plant operations. At the Fiscalini facility, power production was limited by the availability of biomass for methane generation, not the designed system capacity. During the baseline study period, feedstocks included manure, sudan grass silage, and

  2. COFIRING BIOMASS WITH LIGNITE COAL

    SciTech Connect (OSTI)

    Darren D. Schmidt

    2002-01-01T23:59:59.000Z

    The University of North Dakota Energy & Environmental Research Center, in support of the U.S. Department of Energy's (DOE) biomass cofiring program, completed a Phase 1 feasibility study investigating aspects of cofiring lignite coal with biomass relative to utility-scale systems, specifically focusing on a small stoker system located at the North Dakota State Penitentiary (NDSP) in Bismarck, North Dakota. A complete biomass resource assessment was completed, the stoker was redesigned to accept biomass, fuel characterization and fireside modeling tests were performed, and an engineering economic analysis was completed. In general, municipal wood residue was found to be the most viable fuel choice, and the modeling showed that fireside problems would be minimal. Experimental ash deposits from firing 50% biomass were found to be weaker and more friable compared to baseline lignite coal. Experimental sulfur and NO{sub x} emissions were reduced by up to 46%. The direct costs savings to NDSP, from cogeneration and fuel saving, results in a 15- to 20-year payback on a $1,680,000 investment, while the total benefits to the greater community would include reduced landfill burden, alleviation of fees for disposal by local businesses, and additional jobs created both for the stoker system as well as from the savings spread throughout the community.

  3. Biomass One LP Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: EnergyAvignon,Belcher HomesLyons BiomassBiofuels)Biomass Facility

  4. The role of biomass in California's hydrogen economy

    E-Print Network [OSTI]

    Parker, Nathan C; Ogden, Joan; Fan, Yueyue

    2009-01-01T23:59:59.000Z

    the biomass resources, hydrogen demands and prices to ?ndhydrogen. The price premium for biomass hydrogen comparedfrom biomass varies with hydrogen selling price. The curves

  5. The role of biomass in California's hydrogen economy

    E-Print Network [OSTI]

    Parker, Nathan C; Ogden, Joan; Fan, Yueyue

    2009-01-01T23:59:59.000Z

    Making a Business from Biomass in Energy, Environment,2004. An assessment of biomass resources in California.methanol and hydrogen from biomass. Journal of Power Sources

  6. Abengoa Bioenergy Biomass of Kansas LLC | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Abengoa Bioenergy Biomass of Kansas LLC Abengoa Bioenergy Biomass of Kansas LLC Abengoa Bioenergy Biomass of Kansas LLC Location: Hugoton, KS Eligibility: 1705 Snapshot In...

  7. New process speeds conversion of biomass to fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion of Biomass to Fuels New process speeds conversion of biomass to fuels Scientists made a major step forward recently towards transforming biomass-derived molecules into...

  8. Biomass Resources Overview and Perspectives on Best Fits for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Resources Overview and Perspectives on Best Fits for Fuel Cells Biomass Resources Overview and Perspectives on Best Fits for Fuel Cells Biomass resources overview and...

  9. LBL CONTINUOUS BIOMASS LIQUEFACTION PROCESS ENGINEERING UNIT (PEU)

    E-Print Network [OSTI]

    Figueroa, Carlos

    2012-01-01T23:59:59.000Z

    0092 UC-61 ORNIA LBL CONTINUOUS BIOMASS LIQUEFACTION PROCESSLBL~l0092 LBL CONTINUOUS BIOMASS LIQUEFACTION PROCESSof Energy LBL CONTINUOUS BIOMASS LIQUEFACTION PROCESS

  10. MARINE BIOMASS SYSTEM: ANAEROBIC DIGESTION AND PRODUCTION OF METHANE

    E-Print Network [OSTI]

    Haven, Kendall F.

    2011-01-01T23:59:59.000Z

    Design Parameters Marine Biomass Production Sea Farmof Various Types of Biomass . Biomethanation Parameters.Proceedings, Fuels from Biomass Symposium. University of

  11. The role of biomass in California's hydrogen economy

    E-Print Network [OSTI]

    Parker, Nathan C; Ogden, Joan; Fan, Yueyue

    2009-01-01T23:59:59.000Z

    promising than renewable sources, including biomass, for aof biomass. US Department of Energy, National RenewableRenewable Energy Laboratory projects the current technology production cost of biomass

  12. Interactions of Lignin and Hemicellulose and Effects on Biomass Deconstruction

    E-Print Network [OSTI]

    Li, Hongjia

    2012-01-01T23:59:59.000Z

    lignocellulosic biomass a promising renewable feedstock forNational Renewable Energy Laboratory (NREL) standard biomassLignocellulosic biomass is the only promising renewable

  13. ITP Energy Intensive Processes: Improved Heat Recovery in Biomass...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improved Heat Recovery in Biomass-Fired Boilers ITP Energy Intensive Processes: Improved Heat Recovery in Biomass-Fired Boilers biomass-firedboilers.pdf More Documents &...

  14. The role of biomass in California's hydrogen economy

    E-Print Network [OSTI]

    Parker, Nathan C; Ogden, Joan; Fan, Yueyue

    2009-01-01T23:59:59.000Z

    for the same quantity of biomass. Finally, the distanceto ?nd the quantity of hydrogen from biomass that is likelyhow the quantity of hydrogen available from biomass varies

  15. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01T23:59:59.000Z

    less recalcitrant biomass feedstocks and improved enzymes.of less recalcitrant biomass feedstocks and improvedpotential of improved biomass feedstocks and enzymes for the

  16. High-biomass sorghums for biomass biofuel production 

    E-Print Network [OSTI]

    Packer, Daniel

    2011-05-09T23:59:59.000Z

    photoperiod-sensitive (PS) hybrids within the Ma1/Ma5/Ma6 hybrid production system. High-biomass sorghums are PS and the Ma1/Ma5/Ma6 hybrid production system produces PS hybrids with PI parents by manipulating alleles at the Ma1, Ma5 and Ma6 sorghum maturity...

  17. Treatment of biomass to obtain ethanol

    DOE Patents [OSTI]

    Dunson, Jr., James B. (Newark, DE); Elander, Richard T. (Evergreen, CO); Tucker, III, Melvin P. (Lakewood, CO); Hennessey, Susan Marie (Avondale, PA)

    2011-08-16T23:59:59.000Z

    Ethanol was produced using biocatalysts that are able to ferment sugars derived from treated biomass. Sugars were obtained by pretreating biomass under conditions of high solids and low ammonia concentration, followed by saccharification.

  18. Biomass Resources for the Federal Sector

    SciTech Connect (OSTI)

    Not Available

    2005-08-01T23:59:59.000Z

    Biomass Resources for the Federal Sector is a fact sheet that explains how biomass resources can be incorporated into the federal sector, and also how they can provide opportunities to meet federal renewable energy goals.

  19. Biomass Sales and Use Tax Exemption

    Broader source: Energy.gov [DOE]

    Georgia enacted legislation in April 2006 (HB 1018) creating an exemption for biomass materials from the state's sales and use taxes. The term "biomass material" is defined as "organic matter,...

  20. Biomass Webinar Text Version | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Dowload the text version of the audio from the DOE Office of Indian Energy webinar on biomass. DOE Office of Indian Energy Foundational Course Webinar on Biomass: Text Version More...

  1. Biomass Equipment & Materials Compensating Tax Deduction

    Broader source: Energy.gov [DOE]

    In 2005, New Mexico adopted a policy to allow businesses to deduct the value of biomass equipment and biomass materials used for the processing of biopower, biofuels, or biobased products in...

  2. Conversion of Waste Biomass into Useful Products 

    E-Print Network [OSTI]

    Holtzapple, M.

    1998-01-01T23:59:59.000Z

    Waste biomass includes municipal solid waste (MSW), municipal sewage sludge (SS), industrial biosludge, manure, and agricultural residues. When treated with lime, biomass is highly digestible by a mixed culture of acid-forming microorganisms. Lime...

  3. Biomass Equipment and Materials Compensating Tax Deduction

    Broader source: Energy.gov [DOE]

    In 2005 New Mexico adopted a policy to allow businesses to deduct the value of biomass equipment and biomass materials used for the processing of biopower, biofuels or biobased products in...

  4. Biomass Feedstock Composition and Property Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Office of Energy Efficiency and Renewable Energy's Biomass Program works with industry, academia and national laboratory partners on a balanced portfolio of research in biomass feedstocks and conversion technologies. Through research, development, and demonstration efforts geared at the development of integrated biorefineries, the Biomass Program is helping transform the nation's renewable and abundant biomass resources into cost competitive, high performance biofuels, bioproducts, and biopower.(From the Biomass Program's home page at http://www1.eere.energy.gov/biomass/) The Biomass Feedstock Composition and Property Database allows the user to choose from more than 150 types of biomass samples. The specialized interface then guides the user through choices within the sample (such as "Ash" as a choice in the "Hardwood" sample and displays tables based on choice of composition properties, structure properties, elemental properties, extractive properties, etc.

  5. CALLA ENERGY BIOMASS COFIRING PROJECT

    SciTech Connect (OSTI)

    Unknown

    2001-10-01T23:59:59.000Z

    The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications.

  6. Biomass from Combined Backseatter Modeling

    E-Print Network [OSTI]

    Weishampel, John F.

    and SAR back- scatter. In this article we discuss' the use of models to help develop a relationship to an airbomw SAR (AIB- SAB) image over a fi?rested area in Maine. A relationship derived totall!l from model results was fi?und to undervs- timate biomass. Calibrating the modeled backscatter with limited AIRSAB

  7. Biomass Catalyst Characterization Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-07-01T23:59:59.000Z

    This fact sheet provides information about Biomass Catalyst Characterization Laboratory (BCCL) capabilities and applications at NREL's National Bioenergy Center.

  8. Dairy Biomass as a Renewable Fuel Source

    E-Print Network [OSTI]

    Mukhtar, Saqib; Goodrich, Barry; Engler, Cady; Capareda, Sergio

    2008-03-19T23:59:59.000Z

    biomass. This publication explains the properties of dairy manure that could make it an excellent source of fuel....

  9. Dairy Biomass as a Renewable Fuel Source 

    E-Print Network [OSTI]

    Mukhtar, Saqib; Goodrich, Barry; Engler, Cady; Capareda, Sergio

    2008-03-19T23:59:59.000Z

    biomass. This publication explains the properties of dairy manure that could make it an excellent source of fuel....

  10. Biomass Compositional Analysis Laboratory (Fact Sheet), National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Providing detailed and accurate characterization of the chemical composition of biomass feedstocks, intermediates, and products Compositional Analysis Service Capabilities...

  11. Biomass Compositional Analysis Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-07-01T23:59:59.000Z

    This fact sheet provides information about Biomass Compositional Analysis Laboratory (BCAL) capabilities and applications at NREL's National Bioenergy Center.

  12. CALLA ENERGY BIOMASS COFIRING PROJECT

    SciTech Connect (OSTI)

    Unknown

    2001-07-01T23:59:59.000Z

    The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Waste coal fines are to be evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. Define a combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. During this Performance Period work efforts proceeded, and Carbona completed the gasifier island design package. Nexant has completed the balance of plant support systems design and the design for the biomass feed system. Work on the Technoeconomic Study is proceeding. Approximately 75% of the specified hardware quotations have been received at the end of the reporting period. A meeting is scheduled for July 23 rd and 24 th to review the preliminary cost estimates. GTI presented a status review update of the project at the DOE/NETL contractor's review meeting in Pittsburgh on June 21st.

  13. CALLA ENERGY BIOMASS COFIRING PROJECT

    SciTech Connect (OSTI)

    Francis S. Lau

    2003-09-01T23:59:59.000Z

    The Calla Energy Biomass Project, to be located in Estill County, Kentucky is to be conducted in two phases. The objective of Phase I is to evaluate the technical and economic feasibility of cofiring biomass-based gasification fuel-gas in a power generation boiler. Natural gas and waste coal fines were evaluated as the cofired fuel. The project is based on the use of commercially available technology for feeding and gas cleanup that would be suitable for deployment in municipal, large industrial and utility applications. A design was developed for a cofiring combustion system for the biomass gasification-based fuel-gas capable of stable, low-NOx combustion over the full range of gaseous fuel mixtures in a power generation boiler, with low carbon monoxide emissions and turndown capabilities suitable for large-scale power generation applications. Following the preliminary design, GTI evaluated the gasification characteristics of selected feedstocks for the project. To conduct this work, GTI assembled an existing ''mini-bench'' unit to perform the gasification tests. The results of the test were used to confirm the process design completed in Phase Task 1. As a result of the testing and modeling effort, the selected biomass feedstocks gasified very well, with a carbon conversion of over 98% and individual gas component yields that matched the RENUGAS{reg_sign} model. As a result of this work, the facility appears very attractive from a commercial standpoint. Similar facilities can be profitable if they have access to low cost fuels and have attractive wholesale or retail electrical rates for electricity sales. The objective for Phase II is to design, install and demonstrate the combined gasification and combustion system in a large-scale, long-term cofiring operation to promote acceptance and utilization of indirect biomass cofiring technology for large-scale power generation applications. Phase II has not been approved for construction at this time.

  14. Determination of Protein Content in Biomass: Laboratory Analytical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Biomass") and biomass before extraction. 2.2 This procedure is suitable for biomass feedstocks, process solids, and process liquids. 2.3 Some types of biomass feedstocks, such...

  15. Original article Micronutrients in biomass fractions

    E-Print Network [OSTI]

    Boyer, Edmond

    Original article Micronutrients in biomass fractions of holm oak, beech and fir forests biomass fractions in individual monospecific stands of holm oak (Quercus ilex L), beech (Fagus sylvatica L in different biomass fractions of the holm oak forest studied. This can be related to the low soil pH values

  16. UCSD Biomass to Power Economic Feasibility Study

    E-Print Network [OSTI]

    Cattolica, Robert

    2009-01-01T23:59:59.000Z

    and  the  high  price  of  the  biomass  from  the  Miramar biomass to be secured under long?term contracts at better prices.   biomass and any dual fuel)  • Moisture, ash, and carbon concentrations (for weight calculations of input fuel and facility waste)  • Sale price 

  17. Also inside this issue: Bioengineering Better Biomass

    E-Print Network [OSTI]

    Also inside this issue: Bioengineering Better Biomass DOE JGI/EMSL Collaborative Science Projects and degrade carbon. This is an image of the Mn(II)-oxidizing fungus Stilbella aciculosa ­ the fungal biomass Better Biomass Feedstock Science Highlights 15 Clouds up Close Improving Catalysts Pore Challenge

  18. 4, 707745, 2007 Proxies of biomass

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 4, 707­745, 2007 Proxies of biomass for primary production Y. Huot et al. Title Page Abstract the best index of phytoplankton biomass for primary productivity studies? Y. Huot 1,2 , M. Babin 1,2 , F of biomass for primary production Y. Huot et al. Title Page Abstract Introduction Conclusions References

  19. Thermodynamics of Energy Production from Biomass

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    Thermodynamics of Energy Production from Biomass Tad W. Patzek 1 and David Pimentel 2 1 Department #12;3 Biomass from Tropical Tree Plantations 14 3.1 Scope of the Problem . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 3.2 Environmental Impacts of Industrial Biomass Production . . . . . . . . . . . . . . . 16 3

  20. 4, 51355200, 2004 A review of biomass

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 5135­5200, 2004 A review of biomass burning emissions, part II J. S. Reid et al. Title Page and Physics Discussions A review of biomass burning emissions, part II: Intensive physical properties of biomass burning particles J. S. Reid 1 , R. Koppmann 2 , T. F. Eck 3 , and D. P. Eleuterio 4 1 Marine