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Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bioactive Glass Scaffolds for Bone Regeneration Bioactive Glass Scaffolds for Bone Regeneration Print Wednesday, 28 September 2011 00:00 Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

2

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

3

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

4

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

5

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

6

In-Vivo Evaluation of 13-93 Bioactive Glass Scaffolds Made by ...  

Science Conference Proceedings (OSTI)

In-vitro, the compressive strength of the SLS scaffolds was measured as a function of time for up to three months when immersed in Dubelcos Modified Eagles ...

7

Graded Bioactive Glass and Glass/Ceramic Coatings for ...  

For Industry; For Researchers; Success Stories; About Us; Available Technologies. ... Graded Bioactive Glass and Glass/Ceramic Coatings for Metal Bone ...

8

JOINT SESSION: Bioactive Glasses: Structure and Bioactivity  

Science Conference Proceedings (OSTI)

Oct 10, 2012 ... Solid state NMR investigating 29Si, 31P and 19F nucleii has been used to characterize both the structure of the glasses and follow the ...

9

Alkali-free bioactive glasses for bone tissue engineering: A preliminary investigation  

SciTech Connect

An alkali-free series of bioactive glasses has been designed and developed in the glass system CaO-MgO-SiO2-P2O5-CaF2 along diopside (CaMgSi2O6) – fluorapatite [Ca5(PO4)3F] – tricalcium phosphate (3CaO•P2O5) join. The silicate network in all the investigated glasses is predominantly coordinated in Q2 (Si) units while phosphorus tends to remain in orthophosphate (Q0) environment. The in vitro bioactivity analysis of glasses has been made by immersion of glass powders in simulated body fluid (SBF) while chemical degradation has been studied in Tris-HCl in accordance with ISO-10993-14. Some of the investigated glasses exhibit hydroxyapatite (HA) formation on their surface with in 1-12 h of their immersion in SBF solution. The sintering and crystallization kinetics of glasses has been investigated by differential thermal analysis (DTA) and hot-stage microscopy (HSM), respectively while the crystalline phase evolution in resultant glass-ceramics (GCs) has been studied in the temperature range of 800-900 oC using powder X-ray diffraction (XRD) and scanning electron microscope (SEM). The cell growth and osteogenic differentiation for glasses has been studied in vitro on sintered glass powder compacts using rat bone marrow mesenchymal stem cells. The as designed glasses are ideal candidates for their potential applications in bone tissue engineering in the form of bioactive glasses as well as glass/GC scaffolds.

Goel, Ashutosh; Kapoor, Saurabh; Rajagopal, Raghu R.; Pascual, Maria J.; Kim, Hae-Won; Ferreira, Jose M.

2011-08-25T23:59:59.000Z

10

Thermal analysis and in vitro bioactivity of bioactive glass-alumina composites  

Science Conference Proceedings (OSTI)

Bioactive glass-alumina composite (BA) pellets were fabricated in the range 95/5-60/40 wt.% respectively and were heat-treated under a specific thermal treatment up to 950 {sup o}C. Control (unheated) and heat-treated pellets were immersed in Simulated Body Fluid (SBF) for bioactivity testing. All pellets before and after immersion in SBF were studied by Fourier Transform Infrared spectroscopy (FTIR), Scanning Electron Microscopy (SEM-EDS) and X-ray Diffraction (XRD) analysis. All composite pellets presented bioactive response. On the surface of the heat-treated pellets the development of a rich biological hydroxyapatite (HAp) layer was delayed for one day, compared to the respective control pellets. Independent of the proportion of the two components, all composites of each group (control and heat-treated) presented the same bioactive response as a function of immersion time in SBF. It was found that by the applied methodology, Al{sub 2}O{sub 3} can be successfully applied in bioactive glass composites without obstructing their bioactive response. - Research Highlights: {yields} Isostatically pressed glass-alumina composites presented apatite-forming ability. {yields} The interaction with SBF resulted in an aluminium phosphate phase formation. {yields} The formation of an aluminium phosphate phase enhanced the in vitro apatite growth.

Chatzistavrou, Xanthippi, E-mail: x.chatzistavrou@imperial.ac.uk [Solid State Physics Section, Physics Department, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece); Kantiranis, Nikolaos, E-mail: kantira@geo.auth.gr [School of Geology, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece); Kontonasaki, Eleana, E-mail: kont@dent.auth.gr [School of Dentistry, Department of Fixed Prosthesis and Implant Prosthodontics, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece); Chrissafis, Konstantinos, E-mail: hrisafis@physics.auth.gr [Solid State Physics Section, Physics Department, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece); Papadopoulou, Labrini, E-mail: lambrini@geo.auth.gr [School of Geology, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece); Koidis, Petros, E-mail: pkoidis@dent.auth.gr [School of Dentistry, Department of Fixed Prosthesis and Implant Prosthodontics, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece); Boccaccini, Aldo R., E-mail: a.boccaccini@imperial.ac.uk [Department of Materials, Faculty of Engineering, Imperial College, SW7 2AZ London (United Kingdom); Paraskevopoulos, Konstantinos M., E-mail: kpar@auth.gr [Solid State Physics Section, Physics Department, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece)

2011-01-15T23:59:59.000Z

11

Bioactive glass coatings with hydroxyapatite and Bioglass ...  

Table 1 Composition and main properties of glasses and HA Composition (wt%) a „ 4 E (10~63C~1)(3C) (GPa) SiO 2 Na 2 OK 2 O CaO MgO P 2 O 5 6P57 56.5 11.0 3.0 15.0 8 ...

12

Nano-Hydroxyapatite/Fluoridated and Unfluoridated Bioactive Glass Composites: Structural Analysis and Bioactivity Evaluation  

Science Conference Proceedings (OSTI)

Biphasic bioceramic composites containing nano-hydroxyapatite (HAP) and nanosized bioactive glasses have been prepared in the form of pellets and have been examined for the effects of bioglass concentrations and sintering temperature on the structural transformations and bioactivity behavior. Pure stoichiometric nano-HAP was synthesized using sol-gel technique. Two bioglasses synthesized in this work--fluoridated bioglass (Cao-P{sub 2}O{sub 5}-Na{sub 2}O{sub 3}-CaF{sub 2}) and unfluoridated bioglass (Cao-P{sub 2}O{sub 5}-Na{sub 2}O{sub 3}) designated as FBG and UFBG respectively, were added to nano-HAP with concentrations of 5, 10, 12 and 15%. The average particle sizes of synthesized HAP and bioglasses were 23 nm and 35 nm, respectively. The pellets were sintered at four different temperatures i.e. 1000 deg. C, 1150 deg. C, 1250 deg. C and 1350 deg. C. The investigations involved study of structural and bioactivity behavior of green and sintered pellets and their deviations from original materials i.e. HAP, FBG and UFBG, using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The phase composition of the sintered pellets was found to be non-stoichiometric HAP with {alpha}-TCP (tricalcium phosphate) and {beta}-TCP. It was revealed from SEM images that bonding mechanism was mainly solid state sintering for all pellets sintered at 1000 deg. C and 1150 deg. C and also for pellets with lower concentrations of bioglass i.e. 5% and 10% sintered at 1250 deg. C. Partly liquid phase sintering was observed for pellets with higher bioglass concentrations of 12% and 15% sintered at 1250 deg. C and same behaviour was noted for pellets at all concentrations of bioglasses at 1350 deg. C. The sintered density, hardness and compression strength of pellets have been influenced both by the concentration of the bioglasses and sintering temperature. It was observed that the biological HAP layer formation was faster on the green pellets surface than on pure HAP and sintered pellets, showing higher bioactivity in the green pellets.

Batra, Uma [Department of Materials and Metallurgical Engineering, PEC University of Technology, Chandigarh-160012 (India); Kapoor, Seema [University Institute of Chemical Engineering and Technology, Panjab University, Chandigarh-160014 (India); Sharma, J. D. [Department of Materials and Metallurgical Engineering, PEC University of Technology, Chandigarh (India)

2011-12-12T23:59:59.000Z

13

Factors Affecting the Dissolution of Resorbable Bioactive Glasses  

Science Conference Proceedings (OSTI)

Factors affecting dissolution are numerous: residual stress, composition, ... and manufacturing method on the dissolution behaviour of glasses with fixed overall ...

14

Mechanical behavior of nanostructured hybrids based on poly(vinyl alcohol)/bioactive glass reinforced with functionalized carbon nanotubes  

Science Conference Proceedings (OSTI)

This study reports the synthesis and characterization of novel tridimensional porous hybrids based on PVA combined with bioactive glass and reinforced by chemically functionalized carbon nanotubes (CNT) for potential use in bone tissue engineering. The ...

H. S. Mansur, M. M. Pereira, H. S. Costa, A. A. P. Mansur

2012-01-01T23:59:59.000Z

15

Effect of Surface Roughness of 45S Bioactive Glass on the ...  

Science Conference Proceedings (OSTI)

Their adhesion and proliferation are determined by fluorescent microscopy. ... Improving the Resistance of Ceramic Surfaces to Biofilm Formation ... Sol-Gel Synthesis of Bio-Active Nanoporous Sodium Zirconate Coated on 316L Stainless

16

Glass and Optical Materials  

Science Conference Proceedings (OSTI)

NMR Insight into Glass Formers and Modifiers · NMR Studies on Biomaterials and Bioactive Glasses · Non-Linear Optical Properties in Glasses.

17

B43: Surface Tension of B2O3 with High Wetting Glass Systems  

Science Conference Proceedings (OSTI)

A12: In Vitro Evaluation of Three-Dimensional PCL-Bioactive Glass Scaffolds Prepared by .... D22: Phase Field Model of Li Dendrite Formation in Lithium Ion Batteries ... D6: Viscosity of Ethylene Glycol+Water Based Al2O3 Nanofluids with

18

The investigation of bioactivity and mechanical properties of glass ionomer cements prepared from Al2O3-SiO2 glass and poly(?-glutamic acid)  

Science Conference Proceedings (OSTI)

Theglass ionomer cement as one of the dental cements has been subjected to be widespread application in restoring tooth structure. Most of glass ionomer cements employ the poly(acrylic acid) (PAA) as the liquid phase, but the presence of PAA inhibits ...

Jinkun Liu, Yoshimitsu Kuwahara, Yuki Shirosaki, Toshiki Miyazaki

2013-01-01T23:59:59.000Z

19

Selective Laser Sintering Fabrication of Bioglass Bone Scaffolds  

Science Conference Proceedings (OSTI)

On-Site Speaker (Planned), Mariano Velez. Abstract Scope, Bioactive glasses implanted in vivo convert to hydroxyapatite and form a strong bond with ...

20

Bioactive Glasses and Glass-Ceramics  

Science Conference Proceedings (OSTI)

...addition of as little as 3 wt% Al2 or 12.5 wt% calcium fluoride (CaF2) for SiO3O2 do not bond to bone. However,

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Osteoconductivity and biodegradability of collagen scaffold coated with nano-?-TCP and fibroblast growth factor 2  

Science Conference Proceedings (OSTI)

Nanoparticle bioceramics have become anticipated for biomedical applications.Highly bioactive and biodegradable scaffoldswould be developed using nanoparticles of ?-tricalcium phosphate (?-TCP).We prepared collagen scaffolds coated by nano-?-TCP ...

Asako Ibara, Hirofumi Miyaji, Bunshi Fugetsu, Erika Nishida, Hiroko Takita, Saori Tanaka, Tsutomu Sugaya, Masamitsu Kawanami

2013-01-01T23:59:59.000Z

22

3D Tissue Scaffolds  

Science Conference Proceedings (OSTI)

... Left: Reference material scaffolds RM8394 are deployed. One unit is a 96-well plate with 24 scaffolds. ... End Date: ongoing. Lead Organizational Unit: ...

2013-09-30T23:59:59.000Z

23

Glass Production  

E-Print Network (OSTI)

40, pp. 162 - 186. Glass Production, Shortland, UEE 2009AINES Short Citation: Shortland 2009, Glass Production. UEE.Andrew, 2009, Glass Production. In Willeke Wendrich (ed. ),

Shortland, Andrew

2009-01-01T23:59:59.000Z

24

Scaffold Gradients: Finding the Right Environment for ...  

Science Conference Proceedings (OSTI)

Scaffold Gradients: Finding the Right Environment for Developing Cells. For Immediate Release: May 25, 2010. ...

2013-05-14T23:59:59.000Z

25

A preliminary study of acoustic propagation in thick foam tissue scaffolds composed of poly(lactic-co-glycolic acid)  

E-Print Network (OSTI)

The exclusive ability of acoustic waves to probe the structural, mechanical and fluidic properties of foams may offer novel approaches to characterise the porous scaffolds employed in tissue engineering. Motivated by this we conduct a preliminary investigation into the acoustic properties of a typical biopolymer and the feasibility of acoustic propagation within a foam scaffold thereof. Focussing on poly(lactic-co-glycolic acid), we use a pulse-echo method to determine the longitudinal speed of sound, whose temperature-dependence reveals the glass transition of the polymer. Finally, we demonstrate the first topographic and tomographic acoustic images of polymer foam tissue scaffolds.

N. G. Parker; M. L. Mather; S. P. Morgan; M. J. W. Povey

2010-02-26T23:59:59.000Z

26

007 Direct Cytotoxicity Evaluation of 63s Bioactive Glass ...  

Science Conference Proceedings (OSTI)

005 Calcium Phosphates for Drug Carrier: Adsorption and Release Kinetics of Drugs ... 058 Properties Optimization of Refractory Mineral Resources in China.

27

Bioactive Glasses and their Biological Impact on Osteogenesis  

Science Conference Proceedings (OSTI)

Microstructural Characteristics of Nano Calcium Phosphates Doped with Fluoride and Titanium Ions · Microwave Assisted Synthesis of Nano Hydroxyapatite ...

28

FABRICATION AND CHARACTERIZATION OF A BIOACTIVE GLASS COATING ...  

and the specimens were lowered from the furnace to cool to room temperature. The stress corrosion crack growth (SCCG) prop-erties of the 6P57 ...

29

Dissolution of Bioactive Glasses: The Effects of Crystallinity Coupled ...  

Science Conference Proceedings (OSTI)

signed to bond and repair human con- nective tissues such as ligaments and bone. .... that trial and error optimization led to the compositions of most biomateri -.

30

Traditional Glasses  

Science Conference Proceedings (OSTI)

Table 1   Glass product types and applications...plates, cups, bowls, serving dishes Fiberglass Wool: insulation, filters Textile: plastic or rubber tire reinforcements, fabrics,

31

Glass Fibers  

Science Conference Proceedings (OSTI)

Table 14   Compositional ranges for insulation-type glasses...from materials melted in a cupola with coke as fuel, all iron oxide

32

Novel Bioceramic Scaffolds for Regenerative Medicine  

Science Conference Proceedings (OSTI)

Presentation Title, Novel Bioceramic Scaffolds for Regenerative Medicine ... Composite Powder from Zro2-B2O3/B System by High-Energy Ball-Milling and ...

33

Glass Surfaces and Water in Glasses  

Science Conference Proceedings (OSTI)

Oct 9, 2012 ... Glass and Optical Materials: Glass Surfaces and Water in Glasses Program Organizers: Jincheng Du, University of North Texas; John Kieffer, ...

34

Amorphous Calcium Phosphate-Based Bioactive Polymeric ...  

Science Conference Proceedings (OSTI)

... Glass ionomers/resin modified Release of fluoride ions from ionomers/ compomers fluoride-containing filler Amorphous calcium phosphate Release ...

2003-07-02T23:59:59.000Z

35

Indirect Tissue Scaffold Fabrication via Additive Manufacturing and Biomimetic Mineralization.  

E-Print Network (OSTI)

??Unlike traditional stochastic scaffold fabrication techniques, additive manufacturing (AM) can be used to create tissue-specific three-dimensional scaffolds with controlled porosity and pore geometry (meso-structure). However,… (more)

Bernardo, Jesse Raymond

2011-01-01T23:59:59.000Z

36

Hydroxyls and Glass Surface Reactivity  

Science Conference Proceedings (OSTI)

Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass · Glass Ceramics ... Terahertz Properties of Lithium Iron Phosphate Glasses.

37

Metallic Glass II  

Science Conference Proceedings (OSTI)

Aug 8, 2013 ... Application of Metallic Glass for High Performance Si Solar Cell: ... of the metallic glasses during heating is dependent on the thermal stability of ...

38

Bulk Metallic Glasses IX  

Science Conference Proceedings (OSTI)

... of elements to form metallic-glass alloys] have resulted in the required cooling rate ... Bauschinger Effect in Metallic Glass Nanowires under Cyclic Loading.

39

DOE Glass Publications Portal  

Office of Scientific and Technical Information (OSTI)

coated glass products. The Glass IOF is sponsored by the Department of Energy (DOE) Energy Efficiency & Renewable Energy (EERE) Industrial Technologies Program (ITP) which...

40

Bulk Metallic Glasses XI  

Science Conference Proceedings (OSTI)

Jul 15, 2013 ... A Bulk Metallic Glass with Record-breaking Damage Tolerance ... Oxidation on the Surface Characteristics of Zr-based Bulk Metallic Glasses.

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Glass Cookware Safety  

NLE Websites -- All DOE Office Websites (Extended Search)

Glass Cookware Safety Glass Cookware Safety Under the wrong conditions, glass cookware can crack, break or shatter. Glass cookware is tempered (heat resistant). However, there are many steps to follow to ensure safe use of glass cookware. Glass Cookware Steps: If the steps are not followed, glass cookware can shatter unexpectedly. shatters, (it looks as if it has exploded) If glass bakeware is chipped, cracked, or scratched, it's time for it to be retired from service. It is more likely to shatter! Don't take glass bakeware directly from the freezer to the oven, or vice versa. Allow the oven to fully preheat before putting glassware inside. Don't add liquid to glassware that is already hot. Cover the bottom of glass bakeware with liquid before cooking meat or vegetables.

42

D6: Viscosity of Ethylene Glycol+Water Based Al2O3 Nanofluids ...  

Science Conference Proceedings (OSTI)

However, few studies are available on viscosity of nanofluids especially in presence of ... A12: In Vitro Evaluation of Three-Dimensional PCL-Bioactive Glass Scaffolds .... D22: Phase Field Model of Li Dendrite Formation in Lithium Ion Batteries.

43

Scaffolding Program Management for Dose Reduction  

Science Conference Proceedings (OSTI)

The nuclear industry has reduced collective radiation exposure annually since 1990, with the exception of 2003. (Large component replacement in several plants caused most of the increase in 2003.) In order for the industry to meet and maintain their continuous improvement goals, it is necessary to carefully review the activities in which workers acquire dose. Research has shown that one of the primary contributors is the erection and disassembly of scaffolding.

2004-11-17T23:59:59.000Z

44

Mineralization of Synthetic Polymer Scaffolds: A Bottom-Up ...  

Mineralization of Synthetic Polymer Scaffolds: A Bottom-Up Approach for the Development of Artificial Bone Jie Song,*,†,‡ Viengkham Malathong,† and Carolyn R ...

45

Glass Working, Use and Discard  

E-Print Network (OSTI)

of the glass object, be it glass block or glass vessel. Thisglass would have been reheated and cast, probably into blocks

Nicholson, Paul

2011-01-01T23:59:59.000Z

46

DRAFT Glass.indd  

NLE Websites -- All DOE Office Websites (Extended Search)

FAST FACTS FAST FACTS Glass technology provides a versatile method for safely managing a variety of wastes SRNL has studied the behavior in glass of nearly every element in the Periodic Table Overview Converting waste materials into a stable glass form is a highly effective way of treating and disposing of many types of waste, including some hazardous and radioactive wastes. Vitrifi cation - the immobilization of a material in glass - is

47

Analysis of Glass Breakage  

Science Conference Proceedings (OSTI)

Analysis of a Bucketwheel Stacker Reclaimer Structural Failure · Analysis of Glass Breakage · Analysis of Sealed, Integrated, Automotive Wheel Bearings.

48

Method for making a bio-compatible scaffold  

DOE Patents (OSTI)

A method for forming a three-dimensional, biocompatible, porous scaffold structure using a solid freeform fabrication technique (referred to herein as robocasting) that can be used as a medical implant into a living organism, such as a human or other mammal. Imaging technology and analysis is first used to determine the three-dimensional design required for the medical implant, such as a bone implant or graft, fashioned as a three-dimensional, biocompatible scaffold structure. The robocasting technique is used to either directly produce the three-dimensional, porous scaffold structure or to produce an over-sized three-dimensional, porous scaffold lattice which can be machined to produce the designed three-dimensional, porous scaffold structure for implantation.

Cesarano, III, Joseph (Albuquerque, NM); Stuecker, John N. (Albuquerque, NM); Dellinger, Jennifer G. (Champaigne, IL); Jamison, Russell D. (Urbana, IL)

2006-01-31T23:59:59.000Z

49

Radiation coloration resistant glass  

SciTech Connect

A radiation coloration resistant glass is disclosed which is used in a radiation environment sufficient to cause coloration in most forms of glass. The coloration resistant glass includes higher proportions by weight of water and has been found to be extremely resistant to color change when exposed to such radiation levels. The coloration resistant glass is free of cerium oxide and has more than about 0.5% by weight water content. Even when exposed to gamma radiation of more than 10.sup.7 rad, the coloration resistant glass does not lose transparency.

Tomozawa, Minoru (Troy, NY); Watson, E. Bruce (Troy, NY); Acocella, John (Troy, NY)

1986-01-01T23:59:59.000Z

50

Cold Spray Process as an Alternative for Bioactive Coatings for ...  

Science Conference Proceedings (OSTI)

... Templates Facilitates Neural Stem Cell Adhesion, Proliferation and Differentiation ... Improving the Resistance of Ceramic Surfaces to Biofilm Formation ... Sol-Gel Synthesis of Bio-Active Nanoporous Sodium Zirconate Coated on 316L ...

51

Bioactivation of myelotoxic xenobiotics by human neutrophil myeloperoxidase  

Science Conference Proceedings (OSTI)

Many environmental pollutants and drugs are toxic to the bone marrow. Some of these xenobiotics may initiate toxicity after undergoing bioactivation to free radicals and/or other reactive electrophiles. Peroxidases are a group of enzymes that catalyze the one-electron oxidative bioactivation of a variety of xenobiotics in vitro. Myeloperoxidase (MPO) is a peroxidative enzyme found in very high concentration in the neutrophils of human bone marrow. In this study, human MPO was evaluated to determine its ability to catalyze the in vitro bioactivation of known bone marrow toxicants that contain the aromatic hydroxyl (Ar-OH), aromatic amine (Ar-N-R{sub 2}), or heterocyclic tertiary amine ({double bond}N-R) moieties. The formation of free radical metabolites during the MPO-catalyzed bioactivation of hydroquinone and catechol (benzene metabolites), mitoxantrone and ametantrone (antitumor drugs), and chlorpromazine and promazine (antipsychotic drugs) was demonstrated by EPR spectroscopy. The reactivity of the products formed during the MPO catalyzed bioactivation of ({sup 14}C)hydroquinone and ({sup 14}C)catechol was shown by their covalent binding to protein and DNA in vitro. The covalently binding metabolite in each case is postulated to be the quinone form of the xenobiotic. In addition, both GSH and NADH were oxidized by the reactive intermediate(s) formed during the MPO-catalyzed bioactivation of many of the bone marrow toxicants tested. It was also shown that p,p-biphenol stimulated the MPO catalyzed bioactivation of both hydroquinone and catechol, while p-cresol stimulated the MPO-catalyzed bioactivation of catechol.

Roy, R.R.

1989-01-01T23:59:59.000Z

52

Collagen-Hyaluronic Acid Scaffolds for Adipose Tissue Engineering  

E-Print Network (OSTI)

- ___________________________________________________________________________ 7 drying cycle. Disc samples of diameter 10 mm were then cut from sheets of scaffolds using a punch. 2.3. Scaffold morphology X-ray microtomography ( Skyscan 1072 Micro-CT (µCT) system), with a 28 kV/ 164 ?A X-ray source (using 0-360o range... days incubation in DMEM, 10% FCS and insulin. Adipogenic control specimens were incubated for 8 days in DMEM + FCS. 2.10. Oil-Red O and Immunohistochemical staining Following 8 days adipogenic induction, cell-seeded scaffolds were fixed in 4...

Davidenko, Natalia; Campbell, J. J.; Thian, E. S.; Watson, C. J,; Cameron, Ruth Elizabeth

2010-01-01T23:59:59.000Z

53

Deformation and Void Structure in Glass  

Science Conference Proceedings (OSTI)

Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass · Glass Ceramics ... Terahertz Properties of Lithium Iron Phosphate Glasses.

54

Method for making glass  

DOE Patents (OSTI)

A method is discussed for making better quality molten borosilicate glass in a glass melter, the glass having the desired viscosity and, preferably, also the desired resistivity so that the glass melt can be established effectively and the product of the glass melter will have the desired level of quality. The method includes the adjustment of the composition of the glass constituents that are fed into the melter in accordance with certain correlations that reliably predict the viscosity and resistivity from the melter temperature and the melt composition, then heating the ingredients to the melter's operating temperature until they melt and homogenize. The equations include the calculation of a non-bridging oxygen'' term from the numbers of moles of the various ingredients, and then the determination of the viscosity and resistivity from the operating temperature of the melter and the non-bridging oxygen term.

Jantzen, C.M.

1991-01-01T23:59:59.000Z

55

GlassMelt&Sealing  

NLE Websites -- All DOE Office Websites (Extended Search)

Glass Melting and Sealing Glass Melting and Sealing Manufacturing Technologies The Manufacturing Science & Technology Center performs process development of glass and glass-ceramic-to-metal seals. Small batches of specialty glass can be melted from reagent grade oxide powders. Glass and glass-ceramic-to-metal seals are made in microprocessor controlled inert atmospheres and are checked for her- meticity after sealing. Sandia's extensive properties database of low melting solder glasses is used to aid in material and processing decisions when making glass-to-glass, ceramic-to-ceramic, and glass-to-ceramic seals. These seals are typically done in air at much lower tem- peratures than glass and glass-to-ceramic seals. Capabilities * Interface with designers and vendors to assure that the most appropriate materi-

56

Mechanical Properties of Glass  

Science Conference Proceedings (OSTI)

... moduli and Vicker's hardness, as well as high transparency in the UV/visible region, ... Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and  ...

57

About - Glass Publications Portal  

Office of Scientific and Technical Information (OSTI)

from the repository at OSTI. The Glass Publications Portal is sponsored by the DOE Energy Efficiency and Renewable Energy (EERE) Industrial Technologies Program. In...

58

Synthetic scaffolds and protein assemblies for engineering applications  

E-Print Network (OSTI)

S-layer proteins, which naturally self-assemble on the exterior of cells, provide an interesting basis for the creation of synthetic scaffolds. In this thesis, I created a plasmid which produces a recombinant form of a ...

Norville, Julie Erin, 1980-

2004-01-01T23:59:59.000Z

59

Collagen scaffolds and injectable biopolymer gels for cardiac tissue engineering  

E-Print Network (OSTI)

Three-dimensional biomaterial scaffolds have begun to shown promise for cell delivery for cardiac tissue engineering. Although various polymers and material forms have been explored, there is a need for: injectable gels ...

Ng, Karen Kailin

2012-01-01T23:59:59.000Z

60

Porous anodic aluminum oxide scaffolds; formation mechanisms and applications  

E-Print Network (OSTI)

Nanoporous anodic aluminium oxide (AAO) can be created with pores that self-assemble into ordered configurations. Nanostructured metal oxides have proven to be very useful as scaffolds for growth of nanowires and nanotubes ...

Oh, Jihun

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Control of Nano/Micro Structure of Bioactive Glass and Its Influence ...  

Science Conference Proceedings (OSTI)

Microstructural Characteristics of Nano Calcium Phosphates Doped with Fluoride and Titanium Ions · Microwave Assisted Synthesis of Nano Hydroxyapatite ...

62

A12: In Vitro Evaluation of Three-Dimensional PCL-Bioactive Glass ...  

Science Conference Proceedings (OSTI)

A18: Effect of Local Alendronate Delivery on In Vivo Osteogenesis From PCL ... A7: On-the-fly System Design for High Precision/Ultra Fast/Wide Area Fabrication .... C19: Dissolution Behavior of Cu Under Bump Metallization in Ball Grid Array ... High Volume and Fast Turnaround Automated Inline TEM Sample Preparation.

63

Importance of glass and brass  

E-Print Network (OSTI)

The importance of scientific instruments in the scientific revolution, especially brass and glass. Precise lenses and lens grinding, glass vessels for chemical experiments, the advances in astronomy, microscopy and many other areas due to glass...

Dugan, David

2004-08-17T23:59:59.000Z

64

Sol-GelGlasses  

NLE Websites -- All DOE Office Websites (Extended Search)

Sol-Gel Glasses Sol-Gel Glasses Manufacturing Technologies The Manufacturing Science & Technology Center conducts process development and scale-up of ceramic and glass materials prepared by the sol- gel process. Sol-gel processing uses solutions prepared at low temperature rather than high temperature powder processing to make materi- als with controlled properties. A precursor sol-gel solution (sol) is either poured into a mold and allowed to gel or is diluted and applied to a sub- strate by spinning, dipping, spraying, elec- trophoresis, inkjet printing or roll coating. Controlled drying of the wet gel results in either a ceramic or glass bulk part or a thin film on a glass, plastic, ceramic or metal substrate. Sol-gel derived materials have diverse applications in optics, electronics, energy, space, sensors and

65

MST: Organizations: Ceramic and Glass  

NLE Websites -- All DOE Office Websites (Extended Search)

formation and machining, to complete component fabrication and testing. Our Mission Our ceramic, glass, and glass-ceramic products meet customer needs in defense, energy,...

66

Teaching an Old Scaffold New Tricks: Monobodies Constructed Using Alternative Surfaces of the FN3 Scaffold  

Science Conference Proceedings (OSTI)

The fibronectin type III domain (FN3) has become one of the most widely used non-antibody scaffolds for generating new binding proteins. Because of its structural homology to the immunoglobulin domain, combinatorial libraries of FN3 designed to date have primarily focused on introducing amino acid diversity into three loops that are equivalent to antibody complementarity-determining regions. Here, we report an FN3 library that utilizes alternative positions for presenting amino acid diversity. We diversified positions on a {beta}-sheet and surface loops that together form a concave surface. The new library produced binding proteins (termed 'monobodies') to multiple target proteins, generally with similar efficacy as the original, loop-focused library. The crystal structure of a monobody generated from the new library in complex with its target, the Abl SH2 domain, revealed that a concave surface of the monobody, as intended in our design, bound to a convex surface of the target with the interface area being among the largest of published structures of monobody-target complexes. This mode of interaction differs from a common binding mode for single-domain antibodies and antibody mimics in which recognition loops recognize clefts in targets. Together, this work illustrates the utilization of different surfaces of a single immunoglobulin-like scaffold to generate binding proteins with distinct characteristics.

Koide, Akiko; Wojcik, John; Gilbreth, Ryan N.; Hoey, Robert J.; Koide, Shohei (UC)

2012-06-28T23:59:59.000Z

67

Glass electrolyte composition  

DOE Patents (OSTI)

An ionically conductive glass is disclosed for use as electrolyte in a high temperature electrochemical cell, particularly a cell with sodium anode and sulfur cathode. The glass includes the constituents Na/sub 2/O, ZrO/sub 2/, Al/sub 2/O/sub 3/ and SiO/sub 2/ in selected proportions to be a single phase solid solution substantially free of crystalline regions and undissolved constituents. Other advantageous properties are an ionic conductivity in excess of 2 x 10/sup -3/ (ohm-cm)/sup -1/ at 300/sup 0/C and a glass transition temperature in excess of 500/sup 0/C.

Kucera, G.H.; Roche, M.F.

1985-01-08T23:59:59.000Z

68

Waste glass weathering  

Science Conference Proceedings (OSTI)

The weathering of glass is reviewed by examining processes that affect the reaction of commercial, historical, natural, and nuclear waste glass under conditions of contact with humid air and slowly dripping water, which may lead to immersion in nearly static solution. Radionuclide release data from weathered glass under conditions that may exist in an unsaturated environment are presented and compared to release under standard leaching conditions. While the comparison between the release under weathering and leaching conditions is not exact, due to variability of reaction in humid air, evidence is presented of radionuclide release under a variety of conditions. These results suggest that both the amount and form of radionuclide release can be affected by the weathering of glass.

Bates, J.K.; Buck, E.C.

1993-12-31T23:59:59.000Z

69

Terahertz Properties of Glasses  

Science Conference Proceedings (OSTI)

A review of advances in THz-TDS spectroscopy of selected glass families ... Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate ... Molecular Mechanisms of the Conversion Reaction in FeF2 Cathodes Exposed to Li in ...

70

Bulk Metallic Glasses X  

Science Conference Proceedings (OSTI)

Jul 31, 2012 ... Aerospace and Spacecraft Applications for Bulk Metallic Glasses and Matrix Composites · Air Oxidation of a Binary Cu64.5Zr35.5 Bulk Metallic ...

71

Bulk Metallic Glasses VII  

Science Conference Proceedings (OSTI)

Sponsorship, The Minerals, Metals and Materials Society ... Air-Oxidation of a ( Zr55Cu30Al10Ni5)98Er2 Bulk Metallic Glass at 350-500oc · Anelastic ...

72

Baseline LAW Glass Formulation Testing  

Science Conference Proceedings (OSTI)

The major objective of the baseline glass formulation work was to develop and select glass formulations that are compliant with contractual and processing requirements for each of the LAW waste streams. Other objectives of the work included preparation and characterization of glasses with respect to the properties of interest, optimization of sulfate loading in the glasses, evaluation of ability to achieve waste loading limits, testing to demonstrate compatibility of glass melts with melter materials of construction, development of glass formulations to support ILAW qualification activities, and identification of glass formulation issues with respect to contract specifications and processing requirements.

Kruger, Albert A. [USDOE Office of River Protection, Richland, WA (United States); Mooers, Cavin [The Catholic University of America, Washington, DC (United States). Vitreous State Lab.; Bazemore, Gina [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Pegg, Ian L. [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Hight, Kenneth [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Lai, Shan Tao [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Buechele, Andrew [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Rielley, Elizabeth [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Gan, Hao [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Muller, Isabelle S. [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Cecil, Richard [The Catholic University of America, Washington, DC (United States). Vitreous State Lab

2013-06-13T23:59:59.000Z

73

Advancement into the Arctic Region for Bioactive Sponge Secondary Metabolites  

E-Print Network (OSTI)

Abstract: Porifera have long been a reservoir for the discovery of bioactive compounds and drug discovery. Most research in the area has focused on sponges from tropical and temperate waters, but more recently the focus has shifted to the less accessible colder waters of the Antarctic and, to a lesser extent, the Arctic. The Antarctic region in particular has been a more popular location for natural products discovery and has provided promising candidates for drug development. This article reviews groups of bioactive compounds that have been isolated and reported from the southern reaches of the Arctic Circle, surveys the known sponge diversity present in the Arctic waters, and details a recent sponge collection by our group in the Aleutian Islands, Alaska. The collection has yielded previously undescribed sponge species along with primary activity against opportunistic infectious diseases, malaria, and HCV. The discovery of new sponge species and bioactive crude extracts gives optimism for the isolation of new bioactive compounds from a relatively unexplored source.

Samuel Abbas; Michelle Kelly; John Bowling; James Sims; A Waters; Mark Hamann

2011-01-01T23:59:59.000Z

74

DWPF GLASS BEADS AND GLASS FRIT TRANSPORT DEMONSTRATION  

SciTech Connect

DWPF is considering replacing irregularly shaped glass frit with spherical glass beads in the Slurry Mix Evaporator (SME) process to decrease the yield stress of the melter feed (a non-Newtonian Bingham Plastic). Pilot-scale testing was conducted on spherical glass beads and glass frit to determine how well the glass beads would transfer when compared to the glass frit. Process Engineering Development designed and constructed the test apparatus to aid in the understanding and impacts that spherical glass beads may have on the existing DWPF Frit Transfer System. Testing was conducted to determine if the lines would plug with the glass beads and the glass frit slurry and what is required to unplug the lines. The flow loop consisted of vertical and horizontal runs of clear PVC piping, similar in geometry to the existing system. Two different batches of glass slurry were tested: a batch of 50 wt% spherical glass beads and a batch of 50 wt% glass frit in process water. No chemicals such as formic acid was used in slurry, only water and glass formers. The glass beads used for this testing were commercially available borosilicate glass of mesh size -100+200. The glass frit was Frit 418 obtained from DWPF and is nominally -45+200 mesh. The spherical glass beads did not have a negative impact on the frit transfer system. The transferring of the spherical glass beads was much easier than the glass frit. It was difficult to create a plug with glass bead slurry in the pilot transfer system. When a small plug occurred from setting overnight with the spherical glass beads, the plug was easy to displace using only the pump. In the case of creating a man made plug in a vertical line, by filling the line with spherical glass beads and allowing the slurry to settle for days, the plug was easy to remove by using flush water. The glass frit proved to be much more difficult to transfer when compared to the spherical glass beads. The glass frit impacted the transfer system to the point that the test apparatus had to be disassembled to dislodge the plugs created in the system.

Adamson, D; Bradley Pickenheim, B

2008-11-24T23:59:59.000Z

75

Argonne Software Licensing: Glass Furnace Model (GFM)  

The Glass Furnace Model (GFM) The Glass Furnace Model (GFM) Version 4.0, a computational fluid dynamic (CFD) glass furnace simulation code was developed at Argonne ...

76

Glass-water Interactions - Programmaster.org  

Science Conference Proceedings (OSTI)

Glass and Optical Materials: Glass-water Interactions ... Corrosion of Photomultiplier Tube Glasses in High Purity Water : Ruhil Dongol1; S. K. Sundaram1; Milind ...

77

HLW Glass Waste Loadings  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

HLW HLW Glass Waste Loadings Ian L. Pegg Vitreous State Laboratory The Catholic University of America Washington, DC Overview Overview  Vitrification - general background  Joule heated ceramic melter (JHCM) technology  Factors affecting waste loadings  Waste loading requirements and projections  WTP DWPF  DWPF  Yucca Mountain License Application requirements on waste loading  Summary Vitrification  Immobilization of waste by conversion into a glass  Internationally accepted treatment for HLW  Why glass?  Amorphous material - able to incorporate a wide spectrum of elements over wide ranges of composition; resistant to radiation damage  Long-term durability - natural analogs Relatively simple process - amenable to nuclearization at large  Relatively simple process - amenable to nuclearization at large scale  There

78

Versa Glass | Open Energy Information  

Open Energy Info (EERE)

Zip 43220 Product Versa is manufacturing a new technology privacy glass in Ohio that is LEED and has cleantech properties References Versa Glass1 LinkedIn Connections CrunchBase...

79

Superhydrophobic Transparent Glass Thin Films  

Glass used in building materials (curtain walls), windshields, goggles, glasses,optical lenses, and similar applications must be durable and transparent. To meetthis challenge, ORNL researchers have invented a method to produce ...

80

Terahertz Properties of Lithium Iron Phosphate Glasses  

Science Conference Proceedings (OSTI)

Presentation Title, Terahertz Properties of Lithium Iron Phosphate Glasses ... Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass.

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Breeding for Bioactive Compounds in Vigna Unguiculata L. (WALP.)  

E-Print Network (OSTI)

One of the many ways to address health, obesity and hunger issues is genetic bio-fortification, a strategy of breeding or transforming staple crops with micronutrients and vitamins. This dissertation details efforts to bio-fortify bioactive compounds (phenols, antioxidants, condensed tannins, flavonoids and anthocyanins) in Vigna unguiculata, a staple legume grain crop. Approaches included screening of genetic variation in polyphenolic compositions to identify potential varieties and phenotypes, evaluating the impact of environment (drought stress) on these compositions and elucidating the underlying genetics of their inheritance. Our screening showed significant diversity among genotypes for phenols (2.05 –15.48 mg GAE/g), condensed tannin (0.05 -15.29 mg CE/g) and antioxidant activity (4.0 -201.8 µM TE/g). The highest levels of phenols and antioxidant activity were observed in genotypes with light brown, black and red seed coat color, and those with smooth texture and medium maturity (70-90 days). Red and black phenotypes showed the highest content of flavan-3-ols, flavonols and phenolic acids among all color groups, with values of 169 µg CE/g, 26.17 µg QHE/g, 27.14 µg GAE/g for red and 281 µg CE/g, 23 µg QHE/g and 25 GAE/g for black phenotypes. When studying the impact of drought stress, genotypeXtreatment and treatmentXyear interactions for bioactive compounds were significant when tested under irrigated and drought stress conditions. Anthocyanins showed a 14 % decrease under drought stress. The genotypes that were stable to drought stress are favorable for breeding programs in preparation towards climate change. An FTNIR method was established for high-throughput, non-destructive quantification of bioactive compounds. This was used in inheritance studies of bioactive compounds. Phenols, condensed tannins and flavonoids showed heterosis in F1 and exhibit transgressive segregation in F2 populations. The information presented in this manuscript will be useful for nutritional improvement of cowpeas, where potential genotypes and phenotypes with health benefits offered by enhanced contents of bioactive compounds can be improved further upon.

Gawde, Archana Jairam

2013-05-01T23:59:59.000Z

82

Structural and thermal characterization of CaO-MgO-SiO2-P2O5-CaF2 glasses  

SciTech Connect

The paper presents the influence of varying CaO/MgO ratio on the structure and thermal properties of CaO-MgO-SiO2-P2O5-CaF2 glasses. A series of eight glass compositions in the glass forming region of diopside (CaMgSi2O6) - fluorapatite [Ca5(PO4)3F] - wollastonite (CaSiO3) ternary system have been designed and synthesized by varying diopside/wollastonite ratio in glasses. The as prepared melt-quenched glasses have been characterized for their structure by infrared spectroscopy (FTIR) and magic angle spinning (MAS)-nuclear magnetic resonance (NMR) spectroscopy. Silicon is predominantly present as Q2 (Si) species, while phosphorus tends to coordinate in orthophosphate environment in all the investigated glasses. The change in CaO/MgO ratio had an insignificant affect on the structure of glasses. The thermal sintering and crystallization parameters for the studied glasses have been obtained from differential thermal analysis (DTA) while crystalline phase fractions in the sintered glass-ceramics have been analyzed by X-ray diffraction adjoined with Rietveld refinement. Diopside, fluorapatite, wollastonite and pseudowollastonite have crystallized as the main crystalline phases in all the glass-ceramics with their content varying with respect to variation in CaO/MgO ratio in glasses. Scanning electron microscopy (SEM) has been used to shed light on the microstructure of glass-ceramics. The possible implications of structure and sintering behaviour of glasses on their bioactivity have been discussed.

Kansal, Ishu; Goel, Ashutosh; Tulyaganov, Dilshat U.; Rajagopal, Raghu R.; Ferreira, Jose M.

2012-08-01T23:59:59.000Z

83

Glass Plates under Micro-indentation” Incorporation in Glass Ionomer  

Science Conference Proceedings (OSTI)

Effects of nanocrystalline calcium de?cient hydroxyapatite gnCDHAl incorporation in glass ..... K., Nishino, M., 2003. Toughness, bonding and ?uoride release.

84

WINDOW 5 Glass Library Update  

NLE Websites -- All DOE Office Websites (Extended Search)

WINDOW 6 or 7 Glass Library Update WINDOW 6 or 7 Glass Library Update Last update:12/09/13 07:26 PM Automatic IGDB Update Feature in WINDOW 6 and 7 The latest versions of WINDOW 6 and 7 have an automatic IGDB database update function in the Glass Library. When you first open the program, it checks to see if there is an IGDB version later than what you already have installed, and will notify you if there is an update. Then you can download and install the IGDB database, and click on the Update IGDB button in the Glass Library in order to start the automatic update. For older versions of WINDOW 6 and 7 without the automatic IGDB update function bullet How to Check the Current WINDOW5 IGDB Version bullet Updating the Glass Library bullet Problem Updating the Glass Library bullet Discontinued Records or Reused NFRC IDs

85

Glass rupture disk  

DOE Patents (OSTI)

A frangible rupture disk and mounting apparatus for use in blocking fluid flow, generally in a fluid conducting conduit such as a well casing, a well tubing string or other conduits within subterranean boreholes. The disk can also be utilized in above-surface pipes or tanks where temporary and controllable fluid blockage is required. The frangible rupture disk is made from a pre-stressed glass with controllable rupture properties wherein the strength distribution has a standard deviation less than approximately 5% from the mean strength. The frangible rupture disk has controllable operating pressures and rupture pressures.

Glass, S. Jill (Albuquerque, NM); Nicolaysen, Scott D. (Albuquerque, NM); Beauchamp, Edwin K. (Albuquerque, NM)

2002-01-01T23:59:59.000Z

86

Method for heating a glass sheet  

DOE Patents (OSTI)

A method for heating a glass sheet includes the steps of heating a glass sheet to a first predetermined temperature and applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature to allow the glass sheet to be formed.

Boaz, Premakaran Tucker (Livonia, MI)

1998-01-01T23:59:59.000Z

87

Method for heating a glass sheet  

DOE Patents (OSTI)

A method for heating a glass sheet includes the steps of heating a glass sheet to a first predetermined temperature and applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature to allow the glass sheet to be formed. 5 figs.

Boaz, P.T.

1998-07-21T23:59:59.000Z

88

Compositional threshold for Nuclear Waste Glass Durability  

Science Conference Proceedings (OSTI)

Within the composition space of glasses, a distinct threshold appears to exist that separates "good" glasses, i.e., those which are sufficiently durable, from "bad" glasses of a low durability. The objective of our research is to clarify the origin of this threshold by exploring the relationship between glass composition, glass structure and chemical durability around the threshold region.

Kruger, Albert A. [Pacific Northwest National Lab., Richland, WA (United States); Farooqi, Rahmatullah [Pohang Univ. of Science and Technology, (Korea, Republic of); Hrma, Pavel R. [Pacific Northwest National Lab., Richland, WA (United States), Pohang Univ. of Science and Technology, (Korea, Republic of)

2013-04-24T23:59:59.000Z

89

POROUS WALL, HOLLOW GLASS MICROSPHERES  

DOE Green Energy (OSTI)

Hollow Glass Microspheres (HGM) is not a new technology. All one has to do is go to the internet and Google{trademark} HGM. Anyone can buy HGM and they have a wide variety of uses. HGM are usually between 1 to 100 microns in diameter, although their size can range from 100 nanometers to 5 millimeters in diameter. HGM are used as lightweight filler in composite materials such as syntactic foam and lightweight concrete. In 1968 a patent was issued to W. Beck of the 3M{trademark} Company for 'Glass Bubbles Prepared by Reheating Solid Glass Particles'. In 1983 P. Howell was issued a patent for 'Glass Bubbles of Increased Collapse Strength' and in 1988 H. Marshall was issued a patent for 'Glass Microbubbles'. Now Google{trademark}, Porous Wall, Hollow Glass Microspheres (PW-HGMs), the key words here are Porous Wall. Almost every article has its beginning with the research done at the Savannah River National Laboratory (SRNL). The Savannah River Site (SRS) where SRNL is located has a long and successful history of working with hydrogen and its isotopes for national security, energy, waste management and environmental remediation applications. This includes more than 30 years of experience developing, processing, and implementing special ceramics, including glasses for a variety of Department of Energy (DOE) missions. In the case of glasses, SRS and SRNL have been involved in both the science and engineering of vitreous or glass based systems. As a part of this glass experience and expertise, SRNL has developed a number of niches in the glass arena, one of which is the development of porous glass systems for a variety of applications. These porous glass systems include sol gel glasses, which include both xerogels and aerogels, as well as phase separated glass compositions, that can be subsequently treated to produce another unique type of porosity within the glass forms. The porous glasses can increase the surface area compared to 'normal glasses of a 1 to 2 order of magnitude, which can result in unique properties in areas such as hydrogen storage, gas transport, gas separations and purifications, sensors, global warming applications, new drug delivery systems and so on. One of the most interesting porous glass products that SRNL has developed and patented is Porous Wall, Hollow Glass Microspheres (PW-HGMs) that are being studied for many different applications. The European Patent Office (EPO) just recently notified SRS that the continuation-in-part patent application for the PW-HGMs has been accepted. The original patent, which was granted by the EPO on June 2, 2010, was validated in France, Germany and the United Kingdom. The microspheres produced are generally in the range of 2 to 100 microns, with a 1 to 2 micron wall. What makes the SRNL microspheres unique from all others is that the team in Figure 1 has found a way to induce and control porosity through the thin walls on a scale of 100 to 3000 {angstrom}. This is what makes the SRNL HW-HGMs one-of-a-kind, and is responsible for many of their unique properties and potential for various applications, including those in tritium storage, gas separations, H-storage for vehicles, and even a variety of new medical applications in the areas of drug delivery and MRI contrast agents. SRNL Hollow Glass Microspheres, and subsequent, Porous Wall, Hollow Glass Microspheres are fabricated using a flame former apparatus. Figure 2 is a schematic of the apparatus.

Sexton, W.

2012-06-30T23:59:59.000Z

90

Quinary metallic glass alloys  

DOE Patents (OSTI)

At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d.multidot.y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

Lin, Xianghong (Pasadena, CA); Johnson, William L. (Pasadena, CA)

1998-01-01T23:59:59.000Z

91

Quinary metallic glass alloys  

DOE Patents (OSTI)

At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3}K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf){sub a}(Al,Zn){sub b}(Ti,Nb){sub c}(Cu{sub x}Fe{sub y}(Ni,Co){sub z}){sub d} wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d{hor_ellipsis}y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

Lin, X.; Johnson, W.L.

1998-04-07T23:59:59.000Z

92

Investigation of electrospun fibrous scaffolds, locally delivered anti-inflammatory drugs, and neural stem cells for promoting nerve regeneration  

E-Print Network (OSTI)

The organization and intricacy of the central and peripheral nervous systems pose special criteria for the selection of a suitable scaffold to aid in regeneration. The scaffold must have sufficient mechanical strength while ...

Vacanti, Nathaniel (Nathaniel Martin)

2010-01-01T23:59:59.000Z

93

Method of determining glass durability  

DOE Patents (OSTI)

A process is described for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, {Delta}G{sub p}, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, {Delta}G{sub a}, based upon the free energy associated with weak acid dissociation, {Delta}G{sub a}{sup WA}, and accelerated matrix dissolution at high pH, {Delta}G{sub a}{sup SB} associated with solution strong base formation, and determining a final hydration free energy, {Delta}G{sub f}. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log{sub 10}(N C{sub i}(g/L))=a{sub i} + b{sub i}{Delta}G{sub f}. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained. 4 figs.

Jantzen, C.M.; Pickett, J.B.; Brown, K.G.; Edwards, T.B.

1998-12-08T23:59:59.000Z

94

Holder for rotating glass body  

DOE Patents (OSTI)

A device is provided for holding and centering a rotating glass body such as a rod or tube. The device includes a tubular tip holder which may be held in a lathe chuck. The device can utilize a variety of centering tips each adapted for a particular configuration, such as a glass O-ring joint or semi-ball joint.

Kolleck, Floyd W. (Clarendon Hills, IL)

1978-04-04T23:59:59.000Z

95

Method of determining glass durability  

DOE Patents (OSTI)

A process for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, .DELTA.G.sub.p, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, .DELTA.G.sub.a, based upon the free energy associated with weak acid dissociation, .DELTA.G.sub.a.sup.WA, and accelerated matrix dissolution at high pH, .DELTA.G.sub.a.sup.SB associated with solution strong base formation, and determining a final hydration free energy, .DELTA.G.sub.f. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log.sub.10 (N C.sub.i (g/L))=a.sub.i +b.sub.i .DELTA.G.sub.f. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained.

Jantzen, Carol Maryanne (Aiken, SC); Pickett, John Butler (Aiken, SC); Brown, Kevin George (Augusta, GA); Edwards, Thomas Barry (Aiken, SC)

1998-01-01T23:59:59.000Z

96

Refractory Glass Seals for SOFC  

DOE Green Energy (OSTI)

One of the critical challenges facing planar solid oxide fuel cell (SOFC) technology is the need for reliable sealing technology. Seals must exhibit long-term stability and mechanical integrity in the high temperature SOFC environment during normal and transient operation. Several different approaches for sealing SOFC stacks are under development, including glass or glass-ceramic seals, metallic brazes, and compressive seals. Among glass seals, rigid glass-ceramics, self-healing glass, and composite glass approaches have been investigated under the SECA Core Technology Program. The U.S. Department of Energy's Pacific Northwest National Laboratory (PNNL) has developed the refractory glass approach in light of the fact that higher sealing temperatures (e.g., 930-1000 degrees C) may enhance the ultimate in-service bulk strength and electrical conductivity of contact materials, as well as the bonding strength between contact materials and adjacent SOFC components, such as interconnect coatings and electrodes. This report summarizes the thermal, chemical, mechanical, and electrical properties of the refractory sealing glass.

Chou, Y. S.; Stevenson, Jeffry W.

2011-07-01T23:59:59.000Z

97

Database and Interim Glass Property Models for Hanford HLW Glasses  

SciTech Connect

The purpose of this report is to provide a methodology for an increase in the efficiency and a decrease in the cost of vitrifying high-level waste (HLW) by optimizing HLW glass formulation. This methodology consists in collecting and generating a database of glass properties that determine HLW glass processability and acceptability and relating these properties to glass composition. The report explains how the property-composition models are developed, fitted to data, used for glass formulation optimization, and continuously updated in response to changes in HLW composition estimates and changes in glass processing technology. Further, the report reviews the glass property-composition literature data and presents their preliminary critical evaluation and screening. Finally the report provides interim property-composition models for melt viscosity, for liquidus temperature (with spinel and zircon primary crystalline phases), and for the product consistency test normalized releases of B, Na, and Li. Models were fitted to a subset of the screened database deemed most relevant for the current HLW composition region.

Hrma, Pavel R.; Piepel, Gregory F.; Vienna, John D.; Cooley, Scott K.; Kim, Dong-Sang; Russell, Renee L.

2001-07-24T23:59:59.000Z

98

Glass and Optical Materials - Programmaster.org  

Science Conference Proceedings (OSTI)

Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and Natural Gas Bearing Shales · Modeling the Electrical Conductivity in Glass Melts.

99

Lead phosphate glass compositions for optical components  

DOE Patents (OSTI)

A lead phosphate glass to which has been added indium oxide or scandium oe to improve chemical durability and provide a lead phosphate glass with good optical properties.

Sales, Brian C. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN)

1987-01-01T23:59:59.000Z

100

Compositional Study of Neutron Detecting Glasses  

Science Conference Proceedings (OSTI)

The current study involves the production and characterization of glass with high concentrations of Gd2O3 in various oxide glass formers, and containing one of ...

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Laboratory Equipment - Ace Glass UV Photochemistry Safety ...  

Science Conference Proceedings (OSTI)

... Specifications / Capabilities: UV Photchemistry Safety Cabinet Ace Glass Cat. Number 7836-20. ... Power Supply Ace Glass Cat. Number 7830-60. ...

2013-02-27T23:59:59.000Z

102

Unusually Stable Glasses May Benefit Drugs, Coatings  

Science Conference Proceedings (OSTI)

... glass is more apt to convert to a low-energy crystalline order ... to study how molecules diffuse during subsequent annealing of the two types of glass ...

2012-11-01T23:59:59.000Z

103

Chemical Strengthening of Soda Lime Silicate Glass  

Science Conference Proceedings (OSTI)

Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and Natural Gas Bearing Shales · Modeling the Electrical Conductivity in Glass Melts.

104

Glass science tutorial: Lecture No. 7, Waste glass technology for Hanford  

SciTech Connect

This paper presents the details of the waste glass tutorial session that was held to promote knowledge of waste glass technology and how this can be used at the Hanford Reservation. Topics discussed include: glass properties; statistical approach to glass development; processing properties of nuclear waste glass; glass composition and the effects of composition on durability; model comparisons of free energy of hydration; LLW glass structure; glass crystallization; amorphous phase separation; corrosion of refractories and electrodes in waste glass melters; and glass formulation for maximum waste loading.

Kruger, A.A.

1995-07-01T23:59:59.000Z

105

Engineered plant biomass particles coated with bioactive agents  

DOE Patents (OSTI)

Plant biomass particles coated with a bioactive agent such as a fertilizer or pesticide, characterized by a length dimension (L) aligned substantially parallel to a grain direction and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. In particular, the L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers, the W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers, and the L.times.W dimensions define a pair of substantially parallel top and bottom surfaces.

Dooley, James H; Lanning, David N

2013-07-30T23:59:59.000Z

106

GLASS COMPOSITION-TCLP RESPONSE MODEL FOR WASTE GLASSES  

Science Conference Proceedings (OSTI)

A first-order property model for normalized Toxicity Characteristic Leaching Procedure (TCLP) release as a function of glass composition was developed using data collected from various studies. The normalized boron release is used to estimate the release of toxic elements based on the observation that the boron release represents the conservative release for those constituents of interest. The current TCLP model has two targeted application areas: (1) delisting of waste-glass product as radioactive (not mixed) waste and (2) designating the glass wastes generated from waste-glass research activities as hazardous or non-hazardous. This paper describes the data collection and model development for TCLP releases and discusses the issues related to the application of the model.

Kim, Dong-Sang; Vienna, John D.

2004-01-01T23:59:59.000Z

107

Method for manufacturing glass frit  

SciTech Connect

A method of manufacturing a glass frit for use in the manufacture of uniform glass microspheres to serve as containers for laser fusion fuel to be exposed to laser energy which includes the formation of a glass gel which is then dried, pulverized, and very accurately sized to particles in a range of, for example, 125 to 149 micrometers. The particles contain an occluded material such as urea which expands when heated. The sized particles are washed, dried, and subjected to heat to control the moisture content prior to being introduced into a system to form microspheres.

Budrick, Ronald G. (Ann Arbor, MI); King, Frank T. (Hillsboro, OR); Nolen, Jr., Robert L. (Ann Arbor, MI); Solomon, David E. (Ann Arbor, MI)

1977-01-01T23:59:59.000Z

108

Glass in 21st Century  

Science Conference Proceedings (OSTI)

Oct 19, 2011 ... This presentation is an overview of the findings from the June 21-22, 2010 American Ceramic Society Leadership Summit ... Borosilicate Glasses: Steve W. Martin1; Randi Christensen1; Garrett Olson1; 1Iowa State University

109

Fast Crystals and Strong Glasses  

SciTech Connect

This talk describes new results on model colloid systems that provide insight into the behavior of fundamental problems in colloid physics, and more generally, for other materials as well. By visualizing the nucleation and growth of colloid crystals, we find that the incipient crystallites are much more disordered than expected, leading to a larger diversity of crystal morphologies. When the entropic contribution of these diverse morphologies is included in the free energy, we are able to describe the behavior very well, and can predict the nucleation rate surprisingly accurately. The talk also describes the glass transition in deformable colloidal particles, and will show that when the internal elasticity of the particles is included, the colloidal glass transition mimics that of molecular glass formers much more completely. These results also suggest that the elasticity at the scale of the fundamental unit, either colloid particle or molecule, determines the nature of the glass transition, as described by the "fragility."

Weitz, David [Harvard

2009-11-04T23:59:59.000Z

110

Thermal insulation of window glass  

SciTech Connect

The thermal insulation of window glass can be increased by a factor of two using spray-on semiconductive SnO/sub 2/: Sb or IN/sub 2/O/sub 3/: Sn coatings. (auth)

Sievers, A.J.

1973-11-01T23:59:59.000Z

111

Sol-Gel Synthesis of Bio-Active Nanoporous Sodium Zirconate ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Bio-active sodium substituted zirconium was coated by sol-gel method ... Templates Facilitates Neural Stem Cell Adhesion, Proliferation and Differentiation ... Improving the Resistance of Ceramic Surfaces to Biofilm Formation.

112

Lipids in NanotechnologyChapter 3 Milk Phospholipids: A Nanocarrier System for Delivery of Bioactive Compounds  

Science Conference Proceedings (OSTI)

Lipids in Nanotechnology Chapter 3 Milk Phospholipids: A Nanocarrier System for Delivery of Bioactive Compounds Food Science Health Nutrition Biochemistry Processing eChapters Food Science & Technology Health - Nutrition - Biochemistr

113

Computation-Guided Backbone Grafting of a Discontinuous Motif onto a Protein Scaffold  

SciTech Connect

The manipulation of protein backbone structure to control interaction and function is a challenge for protein engineering. We integrated computational design with experimental selection for grafting the backbone and side chains of a two-segment HIV gp120 epitope, targeted by the cross-neutralizing antibody b12, onto an unrelated scaffold protein. The final scaffolds bound b12 with high specificity and with affinity similar to that of gp120, and crystallographic analysis of a scaffold bound to b12 revealed high structural mimicry of the gp120-b12 complex structure. The method can be generalized to design other functional proteins through backbone grafting.

Azoitei, Mihai L.; Correia, Bruno E.; Ban, Yih-En Andrew; Carrico, Chris; Kalyuzhniy, Oleksandr; Chen, Lei; Schroeter, Alexandria; Huang, Po-Ssu; McLellan, Jason S.; Kwong, Peter D.; Baker, David; Strong, Roland K.; Schief, William R. (UWASH); (FHCRC); (NIAID)

2012-02-07T23:59:59.000Z

114

BNFL Report Glass Formers Characterization  

Science Conference Proceedings (OSTI)

The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten glass formers, (kyanite, iron oxide, titania, zircon, and zinc oxide) have the potential to cause some level of solids f low problems. In addition, all of the blends may require consideration for their handling. A number of engineering considerations and recommendations were prepared based on the experimental findings, experience, and other process considerations. Recommendations for future testing are included. In conjunction with future work, it is recommended that a professional consultant be engaged to guide and assist with testing and design input.

Schumacher, R.F.

2000-07-27T23:59:59.000Z

115

BNFL Report Glass Formers Characterization  

Science Conference Proceedings (OSTI)

The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten glass formers, (kyanite, iron oxide, titania, zircon, and zinc oxide) have the potential to cause some level of solids f low problems. The problems might include arching or ratholing in the silo/hopper. In addition, all of the blends may require consideration for their handling.

Schumacher, R.F.

2000-07-27T23:59:59.000Z

116

Influence of strontium on structure, sintering and biodegradation behaviour of CaO-MgO-SrO-SiO2-P2O5-CaF2 glasses  

SciTech Connect

The present study investigates the influence of SrO on structure, apatite forming ability, physico-chemical degradation and sintering behaviour of melt-quenched bioactive glasses with composition: mol.% (36.07 – x) CaO – x SrO - 19.24 MgO – 5.61 P2O5 – 38.49 SiO2 – 0.59 CaF2, where x varies between 0 – 10. The detailed structural analysis of glasses has been made by infra red spectroscopy (FTIR) and magic angle spinning-nuclear magnetic resonance spectroscopy (MAS-NMR). Silicon was predominantly present as Q2 (Si) species while phosphorus was found in orthophosphate type environment in all the investigated glasses. The apatite forming ability of glasses was investigated by immersion of glass powders in simulated body fluid (SBF) for time durations varying between 1 h – 7 days. While increasing Sr2+/Ca2+ ratio in glasses did not affect the structure of glasses significantly, their apatite forming ability was decreased considerably. Further, physico-chemical degradation of glasses has been studied in accordance with ISO 10993-14 “Biological evaluation of medical devices – Part 14: Identification and quantification of degradation products from ceramics” in Tris HCl and citric acid buffer and the possible implications of ion release profile from glasses in different solutions has been discussed. The addition of strontium in glasses led to a 7-fold decrease in chemical degradation of glasses in Tris-HCl. The sintering of glass powders rendered glass-ceramics (GCs) with varying degree of crystallinity and good flexural strength (98-131 MPa) where the mechanical properties depend on the nature and amount of crystalline phases present in GCs.

Goel, Ashutosh; Rajagopal, Raghu R.; Ferreira, Jose M.

2011-11-01T23:59:59.000Z

117

Natural analogues of nuclear waste glass corrosion.  

SciTech Connect

This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses.

Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

1999-01-06T23:59:59.000Z

118

Phenomenological study of Au and Pt nanowires grown in porous alumina scaffolds  

E-Print Network (OSTI)

Porous anodic aluminum oxide, commonly known as AAO, has been widely used as a scaffold to synthesize nanowires and nanotubes. The porous alumina structure can be obtained from a simple electrochemical oxidation process, ...

Shin, Yong Cheol, S.M. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

119

Potential commercialization of a collagen-GAG scaffold for liver regeneration  

E-Print Network (OSTI)

The potential for commercializing a scaffold made of collagen and glycosaminoglycan to help regenerate cirrhotic liver was analyzed and a business plan and model were created. Using a lypholization technique, a bulk-sized ...

Southworth, Adam R

2008-01-01T23:59:59.000Z

120

Cell-seeded type II collagen scaffolds for articular cartilage tissue engineering  

E-Print Network (OSTI)

Defects in articular cartilage exhibit little spontaneous healing response, in part due to the limited number of chondrocytes available to infiltrate the defect and the absence of a provisional fibrin scaffold to accommodate ...

Vickers, Scott M. (Scott Mitchell), 1978-

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Physical analysis of collagen-GAG composite scaffolds for nucleus pulposus tissue regeneration  

E-Print Network (OSTI)

In this study biomaterial scaffolds for regeneration of nucleus pulposus were developed by freeze drying slurries with different proportions of collagen II (CII), chondroitin-6-sulfate (CS), and hyaluronic acid (HA). The ...

Simson, Jacob A

2008-01-01T23:59:59.000Z

122

HLW Glass Studies: Development of Crystal-Tolerant HLW Glasses  

Science Conference Proceedings (OSTI)

In our study, a series of lab-scale crucible tests were performed on designed glasses of different compositions to further investigate and simulate the effect of Cr, Ni, Fe, Al, Li, and RuO2 on the accumulation rate of spinel crystals in the glass discharge riser of the HLW melter. The experimental data were used to expand the compositional region covered by an empirical model developed previously (Matyᚠet al. 2010b), improving its predictive performance. We also investigated the mechanism for agglomeration of particles and impact of agglomerates on accumulation rate. In addition, the TL was measured as a function of temperature and composition.

Matyas, Josef; Huckleberry, Adam R.; Rodriguez, Carmen P.; Lang, Jesse B.; Owen, Antionette T.; Kruger, Albert A.

2012-04-02T23:59:59.000Z

123

Structure glass technology : systems and applications  

E-Print Network (OSTI)

Glass cannot compete with steel in terms of strength or durability, but it is the only structural material that offers the highly sought after qualities of translucency and transparency. The use of glass has evolved from ...

Leitch, Katherine K. (Katherine Kristen)

2005-01-01T23:59:59.000Z

124

Graphene Reinforced Glass and Ceramic Matrix Composites  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2013. Symposium, Ceramic Matrix Composites. Presentation Title, Graphene Reinforced Glass ...

125

PHYSICAL AGING OF PLASTICIZED POLYMER GLASS. WH ...  

Science Conference Proceedings (OSTI)

PHYSICAL AGING OF PLASTICIZED POLYMER GLASS. WH Han and GB McKenna, Polymers Division, Building 224, Room ...

126

Laboratory Waste Disposal HAZARDOUS GLASS  

E-Print Network (OSTI)

Laboratory Waste Disposal HAZARDOUS GLASS Items that could cut or puncture skin or trash- can liners. This waste stream must be boxed to protect custodial staff. It goes directly to the landfill lined cardboard box. Tape seams with heavy duty tape to contain waste. Limit weight to 20 lbs. Or

Sheridan, Jennifer

127

High-Temperature Viscosity of Commercial Glasses  

SciTech Connect

Arrhenius models were developed for glass viscosity within the processing temperature of six types of commercial glasses: low-expansion-borosilicate glasses, E glasses, fiberglass wool glasses, TV panel glasses, container glasses, and float glasses. Both local models (for each of the six glass types) and a global model (for the composition region of commercial glasses, i.e., the six glass types taken together) are presented. The models are based on viscosity data previously obtained with rotating spindle viscometers within the temperature range between 900 C and 1550 C; the viscosity varied from 1 Pa?s to 750 Pa?s. First-order models were applied to relate Arrhenius coefficients to the mass fractions of 15 components: SiO2, TiO2, ZrO2, Al2O3, Fe2O3, B2O3, MgO, CaO, SrO, BaO, PbO, ZnO, Li2O, Na2O, K2O. The R2 is 0.98 for the global model and ranges from .097 to 0.99 for the six local models. The models are recommended for glasses containing 42 to 84 mass% SiO2 to estimate viscosities or temperatures at a constant viscosity for melts within both the temperature range from 1100 C to 1550 C and viscosity range from 5 to 400 Pa?s.

Hrma, Pavel R.

2006-08-31T23:59:59.000Z

128

DURABLE GLASS FOR THOUSANDS OF YEARS  

SciTech Connect

The durability of natural glasses on geological time scales and ancient glasses for thousands of years is well documented. The necessity to predict the durability of high level nuclear waste (HLW) glasses on extended time scales has led to various thermodynamic and kinetic approaches. Advances in the measurement of medium range order (MRO) in glasses has led to the understanding that the molecular structure of a glass, and thus the glass composition, controls the glass durability by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. During the early stages of glass dissolution, a 'gel' layer resembling a membrane forms through which ions exchange between the glass and the leachant. The hydrated gel layer exhibits acid/base properties which are manifested as the pH dependence of the thickness and nature of the gel layer. The gel layer ages into clay or zeolite minerals by Ostwald ripening. Zeolite mineral assemblages (higher pH and Al{sup 3+} rich glasses) may cause the dissolution rate to increase which is undesirable for long-term performance of glass in the environment. Thermodynamic and structural approaches to the prediction of glass durability are compared versus Ostwald ripening.

Jantzen, C.

2009-12-04T23:59:59.000Z

129

Standard Guide for Dry Lead Glass and Oil-Filled Lead Glass Radiation Shielding Window Components for Remotely Operated Facilities  

E-Print Network (OSTI)

Standard Guide for Dry Lead Glass and Oil-Filled Lead Glass Radiation Shielding Window Components for Remotely Operated Facilities

American Society for Testing and Materials. Philadelphia

2010-01-01T23:59:59.000Z

130

Cell-matrix interactions : collagen-GAG scaffold fabrication, characterization, and measurement of cell migratory and contractile behavior via confocal microscopy  

E-Print Network (OSTI)

Three-dimensional, collagen scaffolds are an analog of the extracellular matrix and are used for many tissue engineering applications. While material and microstructural properties significantly affect overall scaffold ...

Harley, Brendan A. (Brendan Andrew), 1978-

2006-01-01T23:59:59.000Z

131

Recirculation bubbler for glass melter apparatus  

DOE Patents (OSTI)

A gas bubbler device provides enhanced recirculation of molten glass within a glass melter apparatus. The bubbler device includes a tube member disposed within a pool of molten glass contained in the melter. The tube member includes a lower opening through which the molten glass enters and upper slots disposed close to (above or below) the upper surface of the pool of molten glass and from which the glass exits. A gas (air) line is disposed within the tube member and extends longitudinally thereof. A gas bubble distribution device, which is located adjacent to the lower end of the tube member and is connected to the lower end of the gas line, releases gas through openings therein so as to produce gas bubbles of a desired size in the molten glass and in a distributed pattern across the tube member.

Guerrero, Hector (Evans, GA); Bickford, Dennis (Folly Beach, SC)

2007-06-05T23:59:59.000Z

132

Lid heater for glass melter  

DOE Patents (OSTI)

A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes. 3 figures.

Phillips, T.D.

1993-12-14T23:59:59.000Z

133

Lid heater for glass melter  

DOE Patents (OSTI)

This invention is comprised of a glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes.

Phillips, T.D.

1992-12-31T23:59:59.000Z

134

"S" Glass Manufacturing Technology Transfer  

SciTech Connect

A glass-ceramic-to metal sealing technology patented by Sandia National Laboratories, Albuquerque (SNLA) was developed by MRC-Mound for use in the manufacture of weapon components. Successful implementation attracted increasingly widespread weapon use of this technology. "S-glass" manufacturing technology was transferred to commercial vendors to ensure that weapons production schedules would be met in the coming years. Such transfer also provided sources of this fledgling technology for the Department of Defense (DOD), aerospace and other commercial uses. The steps involved in the technology transfer are described, from the initial cooperative development work of Sandia and Mound scientists and technologists to the final phase of qualifying commercial vendors for component manufacture.

Buckner, Dean, A.; McCollister, Howard, L.

1988-06-01T23:59:59.000Z

135

Melter Glass Removal and Dismantlement  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy (DOE) has been using vitrification processes to convert high-level radioactive waste forms into a stable glass for disposal in waste repositories. Vitrification facilities at the Savannah River Site (SRS) and at the West Valley Demonstration Project (WVDP) are converting liquid high-level waste (HLW) by combining it with a glass-forming media to form a borosilicate glass, which will ensure safe long-term storage. Large, slurry fed melters, which are used for this process, were anticipated to have a finite life (on the order of two to three years) at which time they would have to be replaced using remote methods because of the high radiation fields. In actuality the melters useable life spans have, to date, exceeded original life-span estimates. Initial plans called for the removal of failed melters by placing the melter assembly into a container and storing the assembly in a concrete vault on the vitrification plant site pending size-reduction, segregation, containerization, and shipment to appropriate storage facilities. Separate facilities for the processing of the failed melters currently do not exist. Options for handling these melters include (1) locating a facility to conduct the size-reduction, characterization, and containerization as originally planned; (2) long-term storing or disposing of the complete melter assembly; and (3) attempting to refurbish the melter and to reuse the melter assembly. The focus of this report is to look at methods and issues pertinent to size-reduction and/or melter refurbishment in particular, removing the glass as a part of a refurbishment or to reduce contamination levels (thus allowing for disposal of a greater proportion of the melter as low level waste).

Richardson, BS

2000-10-31T23:59:59.000Z

136

Oil palm vegetation liquor: a new source of phenolic bioactives Ravigadevi Sambanthamurthi1  

E-Print Network (OSTI)

Oil palm vegetation liquor: a new source of phenolic bioactives Ravigadevi Sambanthamurthi1 *, Yew , Krishnan Subramaniam5 , Soon-Sen Leow1 , Kenneth C. Hayes6 and Mohd Basri Wahid1 1 Malaysian Palm Oil Board, 6, Persiaran Institusi, Bandar Baru Bangi, 43000 Kajang Selangor, Malaysia 2 Malaysian Palm Oil

Sinskey, Anthony J.

137

Effects of Bioactive Compounds from Different Potato Genotypes on Prostate Cancer Development in Athymic Nude Mice  

E-Print Network (OSTI)

Phytochemicals are widely noted for their role in chemoprevention. Potato (Solanum tuberosum L.) is the third most important food crop worldwide and is considered a significant source of antioxidants, providing an ideal delivery system for beneficial compounds. The anti-proliferative and pro-apoptotic properties of potato bioactive compounds have been reported in vitro on human prostate cancer cell lines. However, in vivo studies are limited, and more information is needed to determine the chemopreventive properties of potato in the diet. The objective of this study was to evaluate the effects of potato bioactives on prostate cancer in vivo using a mouse model. Athymic nude mice received xenografts of human prostate cancer cells (PC-3) and were administered extracts of potato bioactives from either the white flesh Solanum bulbocastanum (PI243510) or CO112F2-2P/P (purple-flesh Colorado selection), while control mice received water. Neither potato extract provided a significant reduction in tumor growth nor reduced levels of the pro-angiogenic protein VEGF, but the S. bulbocastanum extract reduced expression of metastasis associated protein 1 (MTA1) in tumors, and both potato extracts reduced MTA1 expression in lungs, suggesting the need for further research on the potential chemopreventive or chemotherapeutic properties of potato bioactives.

Turner, Sarah

2012-05-01T23:59:59.000Z

138

Method for heating, forming and tempering a glass sheet  

DOE Patents (OSTI)

A method for heating, forming and tempering a glass sheet is disclosed including the steps of heating at least one glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, forming the glass sheet to a predetermined configuration, and cooling an outer surface of the glass sheet to at least a third predetermined temperature to temper the glass sheet. 2 figs.

Boaz, P.T.; Sitzman, G.W.

1998-10-27T23:59:59.000Z

139

A History of the Theories of Glass Structure: Can We Really Believe ...  

Science Conference Proceedings (OSTI)

Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass · Glass Ceramics ... Terahertz Properties of Lithium Iron Phosphate Glasses.

140

Process for preparing improved silvered glass mirrors  

DOE Patents (OSTI)

Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

Buckwalter, C.Q. Jr.

1980-01-28T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Glass Property Data and Models for Estimating High-Level Waste Glass Volume  

SciTech Connect

This report describes recent efforts to develop glass property models that can be used to help estimate the volume of high-level waste (HLW) glass that will result from vitrification of Hanford tank waste. The compositions of acceptable and processable HLW glasses need to be optimized to minimize the waste-form volume and, hence, to save cost. A database of properties and associated compositions for simulated waste glasses was collected for developing property-composition models. This database, although not comprehensive, represents a large fraction of data on waste-glass compositions and properties that were available at the time of this report. Glass property-composition models were fit to subsets of the database for several key glass properties. These models apply to a significantly broader composition space than those previously publised. These models should be considered for interim use in calculating properties of Hanford waste glasses.

Vienna, John D.; Fluegel, Alexander; Kim, Dong-Sang; Hrma, Pavel R.

2009-10-05T23:59:59.000Z

142

Prestressed glass, aezoelectric electrical power source  

DOE Patents (OSTI)

An electrical power source which comprises a body of prestressed glass having a piezoelectric transducer supported on the body in direct mechanical coupling therewith.

Newson, Melvin M. (Albuquerque, NM)

1976-01-01T23:59:59.000Z

143

Fractography of Thermally Shocked Glass Cookware  

Science Conference Proceedings (OSTI)

Fractography of fractured glass cookware can be a time consuming process of putting ... to Conduct Thermal Shock Test on Refractories Using Steel Blocks.

144

Electrochemical cell with high conductivity glass electrolyte  

DOE Patents (OSTI)

A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with a ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material. 6 figs.

Nelson, P.A.; Bloom, I.D.; Roche, M.F.

1987-04-21T23:59:59.000Z

145

Electrochemical cell with high conductivity glass electrolyte  

DOE Patents (OSTI)

A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with an ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material.

Nelson, P.A.; Bloom, I.D.; Roche, M.F.

1986-04-17T23:59:59.000Z

146

Carbon Emissions: Stone, Clay, and Glass Industry  

U.S. Energy Information Administration (EIA)

Energy-Related Carbon Emissions for Selected Stone, Clay, and Glass Industries, 1994. The cement and lime manufacturing industries emit almost half of ...

147

Carbon Emissions: Stone, Clay, and Glass Industry  

Gasoline and Diesel Fuel Update (EIA)

Stone et al. Industries Energy-Related Carbon Emissions for the Stone, Clay, and Glass Industry by Source, 1994. Three sources, coal, natural gas, and electricity, account for...

148

Nanocrystal Formation in Glasses - Programmaster.org  

Science Conference Proceedings (OSTI)

Presentation Title, Nanocrystal Formation in Glasses ... copper have been treated in hydrogen atmospheres to form nanocrystals imbedded in a glassy matrix.

149

Mechanical Properties of Thin Film Metallic Glass  

Science Conference Proceedings (OSTI)

Because of these and other properties, thin film metallic-glasses (TFMGs) are a promising structural material for fabricating the next generation of micro- and ...

150

Nepheline Crystallization in Nuclear Waste Glasses: Progress ...  

Science Conference Proceedings (OSTI)

Abstract Scope, One significant limitation to waste loading in glass for Hanford defense wastes is the commonly high Al concentrations. The primary concern is ...

151

Lithiated Glass Scintillating-Particle Neutron Detector  

developed from glass that has been loaded with a high concentration of lithium-6, a neutron-absorbing material. A scintillating material in the form ...

152

Lithiated Glass Scintillating-Particle Neutron Detector ...  

... ORNL invention uses a matrix material developed from glass that has been loaded with a high concentration of lithium-6, a neutron-absorbing ...

153

Advanced Characterization Techniques of Glasses - Programmaster ...  

Science Conference Proceedings (OSTI)

Oct 8, 2012 ... Many researchers rely on NMR of glass-forming cations to understand network structure, often in combination with other experimental and ...

154

Modeling the Electrical Conductivity in Glass Melts  

Science Conference Proceedings (OSTI)

Abstract Scope, The electrical resistivity of oxide melts is important for the design and operation of electric furnaces. The electrical properties of glass and slag ...

155

Bulk Metallic Glasses VIII - Programmaster.org  

Science Conference Proceedings (OSTI)

Aug 2, 2010 ... Sponsorship, The Minerals, Metals and Materials Society .... The Oxidation Behavior of an FeCo-Based Bulk Metallic Glass at 600 - 700C.

156

Properties of Glass-Ceramics  

Science Conference Proceedings (OSTI)

Table 21   Maximum use temperatures of selected glass-ceramics...9608 Corning 1000 1830 â?¦ LAS I â?¦ 1000 1830 46% SiC fiber-reinforced composite LAS II (Nb) â?¦ 1100 2010 46% SiC fiber-reinforced composite LAS III (Nb,Zr) â?¦ 1200 2190 46% SiC fiber-reinforced composite LAS-type â?¦ 1200â??1300 2190â??2370 â?¦ Cordierite 9606 Corning 1100 2010 Creep over 900 °C (1650 °F)...

157

Solar Glass Fact Sheet Harvard Green Campus Initiative  

E-Print Network (OSTI)

Solar Glass Fact Sheet Harvard Green Campus Initiative What is Solar Glass? Solar glass is a type electricity and the rest to let in light. Solar glass is not fully transparent, so it should not be used or patterned to minimize heat gain and control glare are ideal candidates. Solar glass can be made in different

Paulsson, Johan

158

Storage and disposal of radioactive waste as glass in canisters  

SciTech Connect

A review of the use of waste glass for the immobilization of high-level radioactive waste glass is presented. Typical properties of the canisters used to contain the glass, and the waste glass, are described. Those properties are used to project the stability of canisterized waste glass through interim storage, transportation, and geologic disposal.

Mendel, J.E.

1978-12-01T23:59:59.000Z

159

Post-processing of polymer foam tissue scaffolds with high power ultrasound: a route to increased pore interconnectivity, pore size and fluid transport  

E-Print Network (OSTI)

We expose thick polymer foam tissue scaffolds to high power ultrasound and study its effect on the openness of the pore architecture and fluid transport through the scaffold. Our analysis is supported by measurements of fluid uptake during insonification and imaging of the scaffold microstructure via x-ray computed tomography, scanning electron microscopy and acoustic microscopy. The ultrasonic treatment is found to increase the mean pore size by over 10%. More striking is the improvement in fluid uptake: for scaffolds with only 40% water uptake via standard immersion techniques, we can routinely achieve full saturation of the scaffold over approximately one hour of exposure. These desirable modifications occur with no loss of scaffold integrity and negligible mass loss, and are optimized when the ultrasound treatment is coupled to a pre-wetting stage with ethanol. Our findings suggest that high power ultrasound is a highly targetted and efficient means to promote pore interconnectivity and fluid transport in thick foam tissue scaffolds.

N J Watson; R K Johal; Y Reinwald; L J White; A M Ghaemmaghami; S P Morgan; F R A J Rose; M J W Povey; N G Parker

2013-02-18T23:59:59.000Z

160

The Effectiveness of Scaffolding Treatment on College Students' Epistemological Reasoning about how Data are Used as Evidence  

E-Print Network (OSTI)

College students rarely engage model-based epistemological reasoning about scientific data and evidence. The purpose of this study was to (1) investigate how scaffolding treatments influenced college students' epistemological reasoning about how data are used as evidence, (2) describe students' epistemological reasoning practice over the course of the study, (3) learn more about relationships among students' domain knowledge, epistemological beliefs about scientific knowledge, and epistemological reasoning, and (4) investigate how scaffolding for epistemological reasoning influences knowledge gain. Participants in this study consisted of three-hundred fifteen undergraduate students; all were juniors and seniors and all students were enrolled in one of two introductory genetics laboratory courses. Study participants included non-majors (Experiment 1, N =143) and majors (Experiment 2, N = 172). A partially mixed-methods sequential research design was used in this study; qualitative and quantitative phases were mixed during data analysis. A distributed scaffolding system was used in this study. All participants from each laboratory section were randomly assigned to one of three treatments; no scaffolds, domain-general scaffolds, or domain specific scaffolds. Study variables included domain knowledge, epistemological beliefs about the nature of scientific knowledge, and epistemological reasoning, scaffolding treatment was the manipulated variable. Findings were: (1) Chi square analysis indicated no statistically significant differences in epistemological reasoning by scaffolding treatment; model-based reasoning was not observed in students' explanations; (2) Spearman rho indicated no change in epistemological reasoning over the course of the study, however, statistical significance was not reached, however, a repeated measures ANOVA with Greenhouse-Geisser correction indicated a statistically significant within subjects change in epistemological reasoning, implications are discussed; (3) statistically significant bivariate correlations were found and (4) ANCOVA indicated pretest domain knowledge was a statistically significant covariate for posttest domain knowledge and a statistically significant main effect for scaffolding treatment was reached by Experiment 1 participants but not by Experiment 2 participants. Implications for instructional design and future research are discussed.

Shimek, Christina

2012-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

SRNL POROUS WALL GLASS MICROSPHERES  

DOE Green Energy (OSTI)

The Savannah River National Laboratory (SRNL) has developed a new medium for storage of hydrogen and other gases. This involves fabrication of thin, Porous Walled, Hollow Glass Microspheres (PW-HGMs), with diameters generally in the range of 1 to several hundred microns. What is unique about the glass microballons is that porosity has been induced and controlled within the thin, one micron thick walls, on the scale of 10 to several thousand Angstroms. This porosity results in interesting properties including the ability to use these channels to fill the microballons with special absorbents and other materials, thus providing a contained environment even for reactive species. Gases can now enter the microspheres and be retained on the absorbents, resulting in solid-state and contained storage of even reactive species. Also, the porosity can be altered and controlled in various ways, and even used to filter mixed gas streams within a system. SRNL is involved in about a half dozen different programs involving these PW-HGMs and an overview of some of these activities and results emerging are presented.

Wicks, G; Leung Heung, L; Ray Schumacher, R

2008-04-15T23:59:59.000Z

162

Nutritionally Enhanced Edible Oil and Oilseed ProcessingChapter 2 Effects of Processing on Nutritional and Bioactive Components of Oil  

Science Conference Proceedings (OSTI)

Nutritionally Enhanced Edible Oil and Oilseed Processing Chapter 2 Effects of Processing on Nutritional and Bioactive Components of Oil Processing eChapters Processing Press Downloadable pdf of Chapter 2 Effects o

163

Development of Bulk Metallic Glasses with High Plasticity Using the ...  

Science Conference Proceedings (OSTI)

Air-Oxidation of a (Zr55Cu30Al10Ni5)98Er2 Bulk Metallic Glass at 350-500oc · Anelastic Deformation of a Metallic Glass · Anisotropy in Metallic Glasses.

164

Load relaxation studies of a metallic glass  

SciTech Connect

Experimental results of load relaxation studies of a commercial metallic glass as a function of temperature are reported. The data suggest that metallic glasses exhibit deformation behavior with flow laws similar to those governing plastic deformation in crystalline solids. The lack of appreciable work hardening in annealed material and the identification of an anelastic component are also indicated by the experimental observations. (GHT)

Hadnagy, T.D.; Krenisky, D.J.; Ast, D.G.; Li, C.Y.

1977-01-01T23:59:59.000Z

165

Monitoring and analyzing waste glass compositions  

DOE Patents (OSTI)

A device and method are described for determining the viscosity of a fluid, preferably molten glass. The apparatus and method use the velocity of rising bubbles, preferably helium bubbles, within the molten glass to determine the viscosity of the molten glass. The bubbles are released from a tube positioned below the surface of the molten glass so that the bubbles pass successively between two sets of electrodes, one above the other, that are continuously monitoring the conductivity of the molten glass. The measured conductivity will change as a bubble passes between the electrodes enabling an accurate determination of when a bubble has passed between the electrodes. The velocity of rising bubbles can be determined from the time interval between a change in conductivity of the first electrode pair and the second, upper electrode pair. The velocity of the rise of the bubbles in the glass melt is used in conjunction with other physical characteristics, obtained by known methods, to determine the viscosity of the glass melt fluid and, hence, glass quality. 2 figures.

Schumacher, R.F.

1994-03-01T23:59:59.000Z

166

Viscous Glass Sealants for SOFC Applications  

DOE Green Energy (OSTI)

Two series of silicate glasses that contain gallium as the primary critical component have been identified and optimized for viscous sealing of solid oxide fuel cells operating from 650 to 850°C. Both series of glass sealants crystallize partially upon heat treatment and yield multiphase microstructures that allow viscous flow at temperatures as low as 650°C. A fully amorphous sealant was also developed by isolating, synthesizing and testing a silicate glass of the same composition as the remnant glassy phase in one of the two glass series. Of ~40 glasses tested for longer than 500 hours, a set of 5 glasses has been further tested for up to 1000h in air, wet hydrogen, and against both yttria-stabilized zirconia and aluminized stainless steel. In some cases the testing times reached 2000h. The reactivity testing has provided new insight into the effects of Y, Zr, and Al on bulk and surface crystallization in boro-gallio-silicate glasses, and demonstrated that at least 5 of the newly-developed glasses are viable viscous sealants.

Scott Misture

2012-09-30T23:59:59.000Z

167

Monitoring and analyzing waste glass compositions  

DOE Patents (OSTI)

A device and method for determining the viscosity of a fluid, preferably molten glass. The apparatus and method uses the velocity of rising bubbles, preferably helium bubbles, within the molten glass to determine the viscosity of the molten glass. The bubbles are released from a tube positioned below the surface of the molten glass so that the bubbles pass successively between two sets of electrodes, one above the other, that are continuously monitoring the conductivity of the molten glass. The measured conductivity will change as a bubble passes between the electrodes enabling an accurate determination of when a bubble has passed between the electrodes. The velocity of rising bubbles can be determined from the time interval between a change in conductivity of the first electrode pair and the second, upper electrode pair. The velocity of the rise of the bubbles in the glass melt is used in conjunction with other physical characteristics, obtained by known methods, to determine the viscosity of the glass melt fluid and, hence, glass quality.

Schumacher, Ray F. (Aiken, SC)

1994-01-01T23:59:59.000Z

168

Decontamination processes for waste glass canisters  

SciTech Connect

The process which will be used to decontaminate waste glass canisters at the Savannah River Plant consists of: decontamination (slurry blasting); rinse (high-pressure water); and spot decontamination (high-pressure water plus slurry). No additional waste will be produced by this process because glass frit used in decontamination will be mixed with the radioactive waste and fed into the glass melter. Decontamination of waste glass canisters with chemical and abrasive blasting techniques was investigated. The ability of a chemical technique with HNO/sub 3/-HF and H/sub 2/C/sub 2/O/sub 4/ to remove baked-on contamination was demonstrated. A correlation between oxide removal and decontamination was observed. Oxide removal and, thus, decontamination by abrasive blasting techniques with glass frit as the abrasive was proposed and demonstrated.

Rankin, W.N.

1981-06-01T23:59:59.000Z

169

Titanium sealing glasses and seals formed therefrom  

DOE Patents (OSTI)

Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La.sub.2 O.sub.3, B.sub.2 O.sub.3, TiO.sub.2 and Al.sub.2 O.sub.3 in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

1997-01-01T23:59:59.000Z

170

Glass heat pipe evacuated tube solar collector  

DOE Patents (OSTI)

A glass heat pipe is adapted for use as a solar energy absorber in an evacuated tube solar collector and for transferring the absorbed solar energy to a working fluid medium or heat sink for storage or practical use. A capillary wick is formed of granular glass particles fused together by heat on the inside surface of the heat pipe with a water glass binder solution to enhance capillary drive distribution of the thermal transfer fluid in the heat pipe throughout the entire inside surface of the evaporator portion of the heat pipe. Selective coatings are used on the heat pipe surface to maximize solar absorption and minimize energy radiation, and the glass wick can alternatively be fabricated with granular particles of black glass or obsidian.

McConnell, Robert D. (Lakewood, CO); Vansant, James H. (Tracy, CA)

1984-01-01T23:59:59.000Z

171

Gaseous Sulfate Solubility in Glass: Experimental Method  

SciTech Connect

Sulfate solubility in glass is a key parameter in many commercial glasses and nuclear waste glasses. This report summarizes key publications specific to sulfate solubility experimental methods and the underlying physical chemistry calculations. The published methods and experimental data are used to verify the calculations in this report and are expanded to a range of current technical interest. The calculations and experimental methods described in this report will guide several experiments on sulfate solubility and saturation for the Hanford Waste Treatment Plant Enhanced Waste Glass Models effort. There are several tables of sulfate gas equilibrium values at high temperature to guide experimental gas mixing and to achieve desired SO3 levels. This report also describes the necessary equipment and best practices to perform sulfate saturation experiments for molten glasses. Results and findings will be published when experimental work is finished and this report is validated from the data obtained.

Bliss, Mary

2013-11-30T23:59:59.000Z

172

Heat capacity at the glass transition  

E-Print Network (OSTI)

A fundamental problem of glass transition is to explain the jump of heat capacity at the glass transition temperature $T_g$ without asserting the existence of a distinct solid glass phase. This problem is also common to other disordered systems, including spin glasses. We propose that if $T_g$ is defined as the temperature at which the liquid stops relaxing at the experimental time scale, the jump of heat capacity at $T_g$ follows as a necessary consequence due to the change of system's elastic, vibrational and thermal properties. In this picture, we discuss time-dependent effects of glass transition, and identify three distinct regimes of relaxation. Our approach explains widely observed logarithmic increase of $T_g$ with the quench rate and the correlation of heat capacity jump with liquid fragility.

Kostya Trachenko; Vadim Brazhkin

2010-02-10T23:59:59.000Z

173

Method for heating and forming a glass sheet  

DOE Patents (OSTI)

A method for heating and forming a glass sheet includes the steps of heating a glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, cooling an outer surface of the glass sheet to at least a third predetermined temperature and forming the glass sheet using forming rollers to a predetermined configuration.

Boaz, Premakaran Tucker (Livonia, MI)

1997-01-01T23:59:59.000Z

174

Direct conversion of halogen-containing wastes to borosilicate glass  

SciTech Connect

Glass has become a preferred waste form worldwide for radioactive wastes: however, there are limitations. Halogen-containing wastes can not be converted to glass because halogens form poor-quality waste glasses. Furthermore, halides in glass melters often form second phases that create operating problems. A new waste vitrification process, the Glass Material Oxidation and dissolution System (GMODS), removes these limitations by converting halogen-containing wastes into borosilicate glass and a secondary, clean, sodium-halide stream.

Forsberg, C.W.; Beahm, E.C.; Rudolph, J.C.

1996-12-09T23:59:59.000Z

175

Chalcogenide Glasses Developed for Optical Micro-sensor Devices  

Science Conference Proceedings (OSTI)

... In the sensor field, chalcogenide glasses are well established membranes or thin ... Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and ...

176

Anomalous Adsorption of Ultrafast Laser Irradiation in Glass ...  

Science Conference Proceedings (OSTI)

Presentation Title, Anomalous Adsorption of Ultrafast Laser Irradiation in Glass ... and is driven by the stress induced by absorption of ultrafast light in glass.

177

Cost model for a small glass manufacturing enterprise.  

E-Print Network (OSTI)

??The cost model developed is for small, glass-manufacturing enterprises to help themdetermine their product costs. It estimates the direct cost in glass manufacturing such as… (more)

Gopisetti, Swetha.

2008-01-01T23:59:59.000Z

178

Ion-Exchanged Glass with High Damage Resistance  

Science Conference Proceedings (OSTI)

Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and Natural Gas Bearing Shales · Modeling the Electrical Conductivity in Glass Melts.

179

Research Needs: Glass Solar Reflectance and Vinyl Siding  

NLE Websites -- All DOE Office Websites (Extended Search)

Research Needs: Glass Solar Reflectance and Vinyl Siding Title Research Needs: Glass Solar Reflectance and Vinyl Siding Publication Type Report LBNL Report Number LBNL-5022E Year...

180

Thermal Performance Impacts of Center-of-Glass Deflections in...  

NLE Websites -- All DOE Office Websites (Extended Search)

Impacts of Center-of-Glass Deflections in Installed Insulating Glazing Units Title Thermal Performance Impacts of Center-of-Glass Deflections in Installed Insulating Glazing...

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Understanding Structure of Glass from Its Response to External Stimuli  

Science Conference Proceedings (OSTI)

Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and Natural Gas Bearing Shales · Modeling the Electrical Conductivity in Glass Melts.

182

Corrosion of Photomultiplier Tube Glasses in High Purity Water  

Science Conference Proceedings (OSTI)

Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and Natural Gas Bearing Shales · Modeling the Electrical Conductivity in Glass Melts.

183

Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil ...  

Science Conference Proceedings (OSTI)

Symposium, Glass and Optical Materials. Presentation Title, Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and Natural Gas Bearing Shales.

184

M. Bulk Metallic Glasses, Nanocrystalline Materials, and Ultrafine ...  

Science Conference Proceedings (OSTI)

Age Hardening of 7075 Alloy Processed by High-pressure Sliding (HPS) ... Atomic Structure and its Change during Glass Transition of Metallic Glasses.

185

Infra-red transparent glass as per ancient Indian text ...  

Science Conference Proceedings (OSTI)

The test results revealed that new glass could be compared with Calcium Fluoride Glass. ... Optical Response of Laser Materials in High Radiation Environments.

186

209- Development of Borosilicate Glasses for the Immobilization of ...  

Science Conference Proceedings (OSTI)

027- Search for the Rigidity Transition and Intermediate Phase in Lithium Oxide Silicate Glass Systems Using .... 101- Viscous Silicate SOFC Glass Sealants.

187

Fogged Glass by Biofilm Formation and Its Evaluation  

Science Conference Proceedings (OSTI)

Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and Natural Gas Bearing Shales · Modeling the Electrical Conductivity in Glass Melts.

188

Refractive index of glass and its dipersion for visible light.  

Science Conference Proceedings (OSTI)

The classification of optical glass and empirical relations between the refractive index and its dispersion are discussed in terms of moments of the glass's IR and UV absorption spectra. The observed linear dependence of index on dispersion within glass families is shown to arise primarily from the approximately linear superposition of the electronic absorptions of glass former and glass modifiers. The binary classification into crown and flint glasses is also based primarily on electronic spectra: Crown glasses are 'wide-gap' materials with excitation energies greater than {approx}12.4 eV, while flint glasses are their 'narrow-gap' counterpart.

Smith, D. Y.; Karstens, W. (Physics); (Univ. of Vermont); (Saint Michael's Coll.)

2010-01-01T23:59:59.000Z

189

China Glass Solar aka CG Solar formerly Weihai Bluestar Terra...  

Open Energy Info (EERE)

Glass Solar aka CG Solar formerly Weihai Bluestar Terra Photovoltaic Co Ltd Jump to: navigation, search Name China Glass Solar (aka CG Solar, formerly Weihai Bluestar Terra...

190

Cuttings Analysis At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Cuttings Analysis At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Cuttings Analysis At Glass Buttes Area (DOE GTP)...

191

Multispectral Imaging At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Glass Buttes Area (DOE GTP) Exploration Activity Details Location Glass Buttes Area Exploration Technique Multispectral Imaging Activity Date Usefulness not indicated DOE-funding...

192

Aeromagnetic Survey At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Glass Buttes Area (DOE GTP) Exploration Activity Details Location Glass Buttes Area Exploration Technique Aeromagnetic Survey Activity Date Usefulness not indicated DOE-funding...

193

Development Wells At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Development Wells At Glass Buttes Area (DOE GTP) Exploration Activity...

194

Oxidation Behavior of Metallic Glass - Programmaster.org  

Science Conference Proceedings (OSTI)

Symposium, M. Bulk Metallic Glasses, Nanocrystalline Materials, and ... Application of Metallic Glass for High Performance Si Solar Cell: Oxidation Behavior of ...

195

Fabrication of Bulk Metallic Glass Foams via Severe Plastic ...  

Science Conference Proceedings (OSTI)

Symposium, M. Bulk Metallic Glasses, Nanocrystalline Materials, and ... Application of Metallic Glass for High Performance Si Solar Cell: Oxidation Behavior of ...

196

Bulk Metallic Glass Composites Fabricated within the Supercooled ...  

Science Conference Proceedings (OSTI)

In the present work, lightweight magnesium base Bulk Metallic Glass Composites ... Application of Metallic Glass for High Performance Si Solar Cell: Oxidation ...

197

Conductive porous scaffolds as potential neural interface materials.  

SciTech Connect

Our overall intent is to develop improved prosthetic devices with the use of nerve interfaces through which transected nerves may grow, such that small groups of nerve fibers come into close contact with electrode sites, each of which is connected to electronics external to the interface. These interfaces must be physically structured to allow nerve fibers to grow through them, either by being porous or by including specific channels for the axons. They must be mechanically compatible with nerves such that they promote growth and do not harm the nervous system, and biocompatible to promote nerve fiber growth and to allow close integration with biological tissue. They must exhibit selective and structured conductivity to allow the connection of electrode sites with external circuitry, and electrical properties must be tuned to enable the transmission of neural signals. Finally, the interfaces must be capable of being physically connected to external circuitry, e.g. through attached wires. We have utilized electrospinning as a tool to create conductive, porous networks of non-woven biocompatible fibers in order to meet the materials requirements for the neural interface. The biocompatible fibers were based on the known biocompatible material poly(dimethyl siloxane) (PDMS) as well as a newer biomaterial developed in our laboratories, poly(butylene fumarate) (PBF). Both of the polymers cannot be electrospun using conventional electrospinning techniques due to their low glass transition temperatures, so in situ crosslinking methodologies were developed to facilitate micro- and nano-fiber formation during electrospinning. The conductivity of the electrospun fiber mats was controlled by controlling the loading with multi-walled carbon nanotubes (MWNTs). Fabrication, electrical and materials characterization will be discussed along with initial in vivo experimental results.

Hedberg-Dirk, Elizabeth L.; Cicotte, Kirsten N.; Buerger, Stephen P.; Reece, Gregory; Dirk, Shawn M.; Lin, Patrick P.

2011-11-01T23:59:59.000Z

198

Gas separation with glass membranes  

DOE Green Energy (OSTI)

The Department of Energy (DOE) is seeking to develop high temperature, high pressure inorganic membrane technology to perform a variety of gas separation processes to improve the efficiency and economics of advanced power generation systems such as direct coal-fueled turbines (DCFT) and the integrated gasification combined cycle process (IGCC). The temperatures encountered in these power generation systems are far above the temperature range for organic membrane materials. Inorganic materials such as ceramics are therefore the most likely membrane materials for use at high temperatures. This project focussed on silica glass fiber membranes made by PPG Industries (Pittsburgh, PA). The goals were both experimental and theoretical. The first objective was to develop a rational theory for the performance of these membranes. With existing theories as a starting point, a new theory was devised to explain the unusual molecular sieving'' behavior exhibited by these glass membranes. An apparatus was then devised for making permeation performance measurements at conditions of interest to DOE (temperatures to 2000[degrees]F; pressures to 1000 psia). With this apparatus, gas mixtures could be made typical of coal combustion or coal gasification processes, these gases could be passed into a membrane test cell, and the separation performance determined. Data were obtained for H[sub 2]/CO,N[sub 2]/CO[sub 2], 0[sub 2]/N[sub 2], and NH[sub 3]/N[sub 2] mixtures and for a variety of pure component gases (He, H[sub 2], CO[sub 2], N[sub 2], CO, NH[sub 3]). The most challenging part of the project turned out to be the sealing of the membrane at high temperatures and pressures. The report concludes with an overview of the practical potential of these membranes and of inorganic membranes in general of DOE and other applications.

Roberts, D.L.; Abraham, L.C.; Blum, Y.; Way, J.D.

1992-05-01T23:59:59.000Z

199

Potential commercial application of a bi-layer bone-ligament regeneration scaffold to anterior cruciate ligament replacement  

E-Print Network (OSTI)

A business model was created in order to explore the commercial application of a bi-layer bone-ligament scaffold to the treatment of torn anterior cruciate ligaments (ACL) requiring replacement. The two main keys in producing ...

Li, Jessica C. (Jessica Ching-Yi)

2006-01-01T23:59:59.000Z

200

Energy implications of glass-container recycling  

SciTech Connect

This report addresses the question of whether glass-container recycling actually saves energy. Glass-container production in 1991 was 10{sup 7} tons, with cullet making up about 30% of the input to manufacture. Two-thirds of the cullet is postconsumer waste; the remainder is in-house scrap (rejects). Most of the glass recycled is made into new containers. Total primary energy consumption includes direct process-energy use by the industry (adjusted to account for the efficiency of fuel production) plus fuel and raw-material transportation and production energies; the grand total for 1991 is estimated to be about 168 {times} 10{sup 12} Btu. The total primary energy use decreases as the percent of glass recycled rises, but the maximum energy saved is only about 13%. If distance to the landfill is kept fixed and that to the recovery facility multiplied by about eight, to 100 mi, a break-even point is reached, and recycling saves no energy. Previous work has shown that to save energy when using glass bottles, reuse is the clear choice. Recycling of glass does not save much energy or valuable raw material and does not reduce air or water pollution significantly. The most important impacts are the small reduction of waste sent to the landfill and increased production rates at glass plants.

Gaines, L.L.; Mintz, M.M. [Argonne National Lab., IL (United States)

1994-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Critical review of glass performance modeling  

Science Conference Proceedings (OSTI)

Borosilicate glass is to be used for permanent disposal of high-level nuclear waste in a geologic repository. Mechanistic chemical models are used to predict the rate at which radionuclides will be released from the glass under repository conditions. The most successful and useful of these models link reaction path geochemical modeling programs with a glass dissolution rate law that is consistent with transition state theory. These models have been used to simulate several types of short-term laboratory tests of glass dissolution and to predict the long-term performance of the glass in a repository. Although mechanistically based, the current models are limited by a lack of unambiguous experimental support for some of their assumptions. The most severe problem of this type is the lack of an existing validated mechanism that controls long-term glass dissolution rates. Current models can be improved by performing carefully designed experiments and using the experimental results to validate the rate-controlling mechanisms implicit in the models. These models should be supported with long-term experiments to be used for model validation. The mechanistic basis of the models should be explored by using modern molecular simulations such as molecular orbital and molecular dynamics to investigate both the glass structure and its dissolution process.

Bourcier, W.L. [Lawrence Livermore National Lab., CA (United States)

1994-07-01T23:59:59.000Z

202

Melting of foaming batches: Nuclear waste glass  

Science Conference Proceedings (OSTI)

A simple model is presented for the rate of melting of a batch blanket in an electric glassmelting furnace. The melting process is assumed to be jointly controlled by the heat transfer from the pool of molten glass and the batch-to-glass conversion kinetics. Factors affecting the melting rate in the conversion-controlled regime are discussed. Attention is paid to gas evolution from redox reactions in waste glass batches and component accumulation within the blanket. It is suggested that the high rate of the blanket-free melting in a mechanically agitated furnace is made possible by increasing the rate of melt surface renewal. 27 refs.

Hrma, P.

1990-10-01T23:59:59.000Z

203

The Color Glass Condensate at RHIC  

E-Print Network (OSTI)

The Color Glass Condensate formalism and its application to high energy heavy ion collisions at RHIC are discussed. We argue that the RHIC data supports the view that the Color Glass Condensate provides the initial conditions for gold-gold collisions at RHIC while final state (Quark Gluon Plasma) effects are responsible for the high $p_t$ suppression in mid rapidity. At forward rapidities in deuteron-gold collisions, however, Color Glass Condensate is the underlying physics of the observed suppression of the particle spectra and their centrality dependence.

Jamal Jalilian-Marian

2004-03-26T23:59:59.000Z

204

Glass melter off-gas system  

DOE Patents (OSTI)

This invention is comprised of an apparatus and method for melting glass in a glass melter in such a way as to reduce deposition of particulates in the off-gas duct. Deposit accumulation is reduced by achieving an off-gas velocity above approximately 15 meters/second and an off-gas temperature as close as possible to, but not higher than, the glass softening point. Because the deposits are largely water-soluble, those that do form on the interior surface of the duct can be readily removed by injecting water or steam directly into the off-gas duct from its entrance or exit.

Jantzen, C.M.

1992-12-31T23:59:59.000Z

205

GLASS COMPOSITION AND PROCESS OF MAKING  

DOE Patents (OSTI)

Glass compositions are described which are suitable for scintillators of thermal-neutron counters. The glass consists of from 70 to 75 mole% of B/sub 2/O/ sub 3/, from 7 to 9 mole% of Ce/sub 2/O/sub 3/, and from 23 to 16 mole% of Al/sub 2/O/sub 3/ plus Na/sub 2 /O in a mole ratio of 1 to 1.5. The process of making the glass from cerous oxalate, ammonium pentaborate, sodium carbonate, and hydrated alumina in a nonoxidizing atmosphere at 1400-1500 deg C is given. (AEC)

Bishay, A.M.

1962-09-01T23:59:59.000Z

206

LingLunch Abstract Adult-Child Discourse in Quest Atlantis: Scaffolding Complexity  

E-Print Network (OSTI)

Multimodal computer gaming environments have the potential to enhance learner motivation and make 3:00- 4:30PM discourse more egalitarian. This study investigates what role adult presence plays in such environments, specifically with regard to the proposition that adults Ballantine 148 scaffold language acquisition in older children (cf. Vygotsky, 1978). We analyzed adult-child interactions in a graphical multi-user virtual environment, Quest Atlantis, designed to teach science content and social responsiveness to children 9-14 years o l d. Extended exchanges of messages from chat, bulletin boards, and weblogs in Quest Atlantis were analyzed for structural complexity using quantitative discourse analysis methods. Results reveal that the adults provided discourse models that effectively scaffolded more complex and standard child language use than when the children interacted only among themselves.

Susan C. Herring; Anupam Das; Shashikant Penumarthy

2005-01-01T23:59:59.000Z

207

SLUDGE BATCH 7B GLASS VARIABILITY STUDY  

SciTech Connect

The Defense Waste Processing Facility (DWPF) is preparing to initiate processing Sludge Batch 7b (SB7b). In support of the upcoming processing, the Savannah River National Laboratory (SRNL) provided a recommendation to utilize Frits 418 with a 6% Na{sub 2}O addition (26 wt% Na{sub 2}O in sludge) and 702 with a 4% Na{sub 2}O addition (24 wt% Na{sub 2}O in sludge) to process SB7b. This recommendation was based on assessments of the compositional projections for SB7b available at the time from the Savannah River Remediation (SRR). To support qualification of SB7b, SRNL executed a variability study to assess the applicability of the current durability models for SB7b. The durability models were assessed over the expected composition range of SB7b, including potential caustic additions, combined with Frits 702 and 418 over a 32-40% waste loading (WL) range. Thirty four glasses were selected based on Frits 418 and 702 coupled with the sludge projections with an additional 4-6% Na{sub 2}O to reflect the potential caustic addition. Six of these glasses, based on average nominal sludge compositions including the appropriate caustic addition, were developed for both Frit 418 and Frit 702 at 32, 36 and 40% WL to provide coverage in the center of the anticipated SB7b glass region. All glasses were fabricated and characterized using chemical composition analysis, X-ray diffraction (XRD) and the Product Consistency Test (PCT). To comply with the DWPF Glass Product Control Program, a total of thirty four glasses were fabricated to assess the applicability of the current DWPF PCCS durability models. Based on the measured PCT response, all of the glasses were acceptable with respect to the Environmental Assessment (EA) benchmark glass regardless of thermal history. The NL[B] values of the SB7b variability study glasses were less than 1.99 g/L as compared to 16.695 g/L for EA. A small number of the D-optimally selected 'outer layer' extreme vertices (EV) glasses were not predictable using the current Product Composition Control System (PCCS) models for durability, but were acceptable compared to the EA glass when tested. These glasses fell outside of the lower 95% confidence band, which demonstrates conservatism in the model. A few of the glasses fell outside of the upper 95% confidence band; however, these particular glasses have normalized release values that were much lower than the values of EA and should be of no practical concern. Per the requirements of the DWPF Glass Product Control Program, the PCCS durability models have been shown to be applicable to the SB7b sludge system with a range of Na{sub 2}O concentrations blended with Frits 418 or 702. PCT results from the glasses fabricated as part of the variability study were shown to be predictable by the current DWPF PCCS models and/or acceptable with respect to the EA benchmark glass regardless of thermal history or compositional view.

Johnson, F.; Edwards, T.

2011-10-25T23:59:59.000Z

208

Post-processing of polymer foam tissue scaffolds with high power ultrasound: a route to increased pore interconnectivity, pore size and fluid transport  

E-Print Network (OSTI)

We expose thick polymer foam tissue scaffolds to high power ultrasound and study its effect on the openness of the pore architecture and fluid transport through the scaffold. Our analysis is supported by measurements of fluid uptake during insonification and imaging of the scaffold microstructure via x-ray computed tomography, scanning electron microscopy and acoustic microscopy. The ultrasonic treatment is found to increase the mean pore size by over 10%. More striking is the improvement in fluid uptake: for scaffolds with only 40% water uptake via standard immersion techniques, we can routinely achieve full saturation of the scaffold over approximately one hour of exposure. These desirable modifications occur with no loss of scaffold integrity and negligible mass loss, and are optimized when the ultrasound treatment is coupled to a pre-wetting stage with ethanol. Our findings suggest that high power ultrasound is a highly targetted and efficient means to promote pore interconnectivity and fluid transport in...

Watson, N J; Reinwald, Y; White, L J; Ghaemmaghami, A M; Morgan, S P; Rose, F R A J; Povey, M J W; Parker, N G

2013-01-01T23:59:59.000Z

209

Community Geothermal Technology Program: Hawaii glass project. Final report  

DOE Green Energy (OSTI)

Objective was to develop a glass utilizing the silica waste material from geothermal energy production, and to supply local artists with this glass to make artistic objects. A glass composed of 93% indigenous Hawaiian materials was developed; 24 artists made 110 objects from this glass. A market was found for art objects made from this material.

Miller, N. [comp.; Irwin, B.

1988-01-20T23:59:59.000Z

210

Glass/polymer composites and methods of making  

DOE Patents (OSTI)

The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.

Samuels, W. D. (Richland, WA); Exarhos, Gregory J. (Richland, WA)

1995-01-01T23:59:59.000Z

211

Glass Buttes Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Glass Buttes Geothermal Area Glass Buttes Geothermal Area (Redirected from Glass Buttes Area) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Glass Buttes Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (1) 9 Exploration Activities (14) 10 References Area Overview Geothermal Area Profile Location: Oregon Exploration Region: Cascades GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure Operating Power Plants: 0 No geothermal plants listed. Add a new Operating Power Plant

212

Cooperative motions in supercooled liquids and glasses  

E-Print Network (OSTI)

Far ir-spectra and heat-capacities for propylene carbonateO. & Suga, H. Heat-capacities and glass transitions of 1-1999). [70] Johari, G. P. Heat capacity and entropy of an

Stevenson, Jacob D.

2009-01-01T23:59:59.000Z

213

Bipolaron Model of Superconductivity in Chalcogenide Glasses  

E-Print Network (OSTI)

In this paper we propose a small bipolaron model for the superconductivity in the Chalcogenide glasses (c-As2Te3 and c-GeTe). The results are agree with the experiments.

Liang-You Zheng; Bo-Cheng Wang; Shan T. Lai

2010-10-25T23:59:59.000Z

214

Measurement of DWPF glass viscosity - Final Report  

SciTech Connect

This report details the results of a scoping study funded by the Defense Waste Processing Facility (DWPF) for the measurement of melt viscosities for simulated glasses representative of Macrobatch 2 (Tank 42/51 feed).

Harbour, J.R.

2000-02-17T23:59:59.000Z

215

Preparation of fullerene/glass composites  

DOE Patents (OSTI)

Synthesis of fullerene/glass composites. A direct method for preparing solid solutions of C.sub.60 in silicon dioxide (SiO.sub.2) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these "guests" in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C.sub.60. Depending upon the preparative procedure, C.sub.60 dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C.sub.60 in a solid glass matrix, is generated by the present method.

Mattes, Benjamin R. (Santa Fe, NM); McBranch, Duncan W. (Santa Fe, NM); Robinson, Jeanne M. (Los Alamos, NM); Koskelo, Aaron C. (Los Alamos, NM); Love, Steven P. (Los Alamos, NM)

1995-01-01T23:59:59.000Z

216

ELECTRICAL PROPERTIES OF GLASS. A BIBLIOGRAPHY  

SciTech Connect

A bibliography on the electrical properties of glass is presented. The 267 references covering the period from 1930 through 1960 are arranged according to subject. An author index is included. (M.C.G.)

Kepple, R.

1961-07-01T23:59:59.000Z

217

Glassy and Glass Composite Nuclear Wasteforms  

Science Conference Proceedings (OSTI)

Presentation Title, Glassy and Glass Composite Nuclear Wasteforms ... for aqueous wastes which should be solidified for safe storage and disposal. ... Creep Behavior of High Temperature Alloys for Generation IV Nuclear Energy Applications.

218

Model for TCLP Releases from Waste Glasses  

Science Conference Proceedings (OSTI)

A first-order property model for normalized Toxicity Characteristic Leaching Procedure (TCLP) release as a function of glass composition was developed using data collected from various studies. The normalized boron release is used to estimate the release of toxic elements based on the observation that the boron release represents the conservative release for those constituents of interest. The current TCLP model has two targeted application areas: (1) delisting of waste-glass product as radioactive (not mixed) waste and (2) designating the glass wastes generated from waste-glass research activities as hazardous or non-hazardous. This report describes the data collection and model development for TCLP releases and discusses the issues related to the application of the model.

Kim, Dong-Sang; Vienna, John D.

2003-05-01T23:59:59.000Z

219

Model for TCLP Releases from Waste Glasses  

Science Conference Proceedings (OSTI)

A first-order property model for normalized Toxicity Characteristic Leaching Procedure (TCLP) release as a function of glass composition was developed using collected data from various studies. The normalized boron release is used to estimate the release of toxic elements based on the observation that the boron release represents the conservative release for those constituents of interest. The current TCLP model has two targeted application areas: (1) delisting of waste-glass product as radioactive (not mixed) waste and (2) designating the glass wastes generated from waste-glass research activities as hazardous or non-hazardous. This report describes the data collection and model development for TCLP releases and discusses the issues related to the application of the model.

Kim, Dong-Sang; Vienna, John D.

2002-09-01T23:59:59.000Z

220

High expansion, lithium corrosion resistant sealing glasses  

DOE Patents (OSTI)

Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO in various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with pin materials of 446 Stainless Steel and Alloy-52 rather than molybdenum, for use in harsh chemical environments, specifically in lithium batteries.

Brow, Richard K. (Albuquerque, NM); Watkins, Randall D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

THE COLOUR GLASS CONDENSATE: AN INTRODUCTION  

Science Conference Proceedings (OSTI)

In these lectures, the authors develop the theory of the Colour Glass Condensate. This is the matter made of gluons in the high density environment characteristic of deep inelastic scattering or hadron-hadron collisions at very high energy. The lectures are self contained and comprehensive. They start with a phenomenological introduction, develop the theory of classical gluon fields appropriate for the Colour Glass, and end with a derivation and discussion of the renormalization group equations which determine this effective theory.

IANCU,E.; LEONIDOV,A.; MCLERRAN,L.

2001-08-06T23:59:59.000Z

222

Cordierite Glass-Ceramics for Dielectric Materials  

Science Conference Proceedings (OSTI)

The objective of this project is to examine the potential of using Malaysian silica sand deposit as SiO2 raw material in producing cordierite glass-ceramics (2MgO-2Al2O3-5SiO2) for dielectric materials. Upgraded silica sands from Terengganu and ex-mining land in Perak were used in the test-works. The glass batch of the present work has a composition of 45.00% SiO2, 24.00% Al2O3, 15.00% MgO and 8.50% TiO2 as nucleation agent. From the differential thermal analysis results, the crystallization temperature was found to start around 900 deg. C. The glass samples were heat-treated at 900 deg. C and 1000 deg. C. The X-ray diffraction analysis (XRD) results showed glass-ceramics from Terengganu samples containing mainly cordierite and minor {beta}-quartz crystals. However, glass-ceramics from ex-mining land samples contained mainly {alpha}-quartz and minor cordierite crystals. Glass-ceramics with different crystal phases exhibit different mechanical, dielectric and thermal properties. Based on the test works, both silica sand deposits, can be potentially used to produce dielectric material component.

Siti Mazatul Azwa Saiyed Mohd Nurddin; Selamat, Malek; Ismail, Abdullah [Minerals Research Centre, Department of Minerals and Geoscience Malaysia, Jalan Sultan Azlan Shah, 31400 Ipoh (Malaysia)

2007-05-09T23:59:59.000Z

223

A molecular view of vapor deposited glasses  

SciTech Connect

Recently, novel organic glassy materials that exhibit remarkable stability have been prepared by vapor deposition. The thermophysical properties of these new ''stable'' glasses are equivalent to those that common glasses would exhibit after aging over periods lasting thousands of years. The origin of such enhanced stability has been elusive; in the absence of detailed models, past studies have discussed the formation of new polyamorphs or that of nanocrystals to explain the observed behavior. In this work, an atomistic molecular model of trehalose, a disaccharide of glucose, is used to examine the properties of vapor-deposited stable glasses. Consistent with experiment, the model predicts the formation of stable glasses having a higher density, a lower enthalpy, and higher onset temperatures than those of the corresponding ''ordinary'' glass formed by quenching the bulk liquid. Simulations reveal that newly formed layers of the growing vapor-deposited film exhibit greater mobility than the remainder of the material, thereby enabling a reorganization of the film as it is grown. They also reveal that ''stable'' glasses exhibit a distinct layered structure in the direction normal to the substrate that is responsible for their unusual properties.

Singh, Sadanand; Pablo, Juan J. de [Department of Chemical and Biological Engineering, University of Wisconsin, Madison Wisconsin 53706 (United States)

2011-05-21T23:59:59.000Z

224

Collagen Scaffolds Incorporating Select Therapeutic Agents to Facilitate a Reparative Response in a Standardized Hemiresection Defect in the Rat Spinal Cord  

E-Print Network (OSTI)

A multifaceted therapeutic approach involving biomaterial scaffolds, neurotrophic factors, exogenous cells, and antagonists to axon growth inhibitors may ultimately prove necessary for the treatment of defects resulting ...

Cholas, Rahmatullah

225

Sealed glass coating of high temperature ceramic superconductors  

DOE Patents (OSTI)

A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

Wu, Weite (Tainan, TW); Chu, Cha Y. (Garnerville, NY); Goretta, Kenneth C. (Downers Grove, IL); Routbort, Jules L. (Darien, IL)

1995-01-01T23:59:59.000Z

226

Engineering Glass Passivation Layers -Model Results  

SciTech Connect

The immobilization of radioactive waste into glass waste forms is a baseline process of nuclear waste management not only in the United States, but worldwide. The rate of radionuclide release from these glasses is a critical measure of the quality of the waste form. Over long-term tests and using extrapolations of ancient analogues, it has been shown that well designed glasses exhibit a dissolution rate that quickly decreases to a slow residual rate for the lifetime of the glass. The mechanistic cause of this decreased corrosion rate is a subject of debate, with one of the major theories suggesting that the decrease is caused by the formation of corrosion products in such a manner as to present a diffusion barrier on the surface of the glass. Although there is much evidence of this type of mechanism, there has been no attempt to engineer the effect to maximize the passivating qualities of the corrosion products. This study represents the first attempt to engineer the creation of passivating phases on the surface of glasses. Our approach utilizes interactions between the dissolving glass and elements from the disposal environment to create impermeable capping layers. By drawing from other corrosion studies in areas where passivation layers have been successfully engineered to protect the bulk material, we present here a report on mineral phases that are likely have a morphological tendency to encrust the surface of the glass. Our modeling has focused on using the AFCI glass system in a carbonate, sulfate, and phosphate rich environment. We evaluate the minerals predicted to form to determine the likelihood of the formation of a protective layer on the surface of the glass. We have also modeled individual ions in solutions vs. pH and the addition of aluminum and silicon. These results allow us to understand the pH and ion concentration dependence of mineral formation. We have determined that iron minerals are likely to form a complete incrustation layer and we plan to look more closely at Vivianite [Fe3(PO4)2-8(H2O)] and Siderite [FeCO3] in the next stage of the project.

Skorski, Daniel C.; Ryan, Joseph V.; Strachan, Denis M.; Lepry, William C.

2011-08-08T23:59:59.000Z

227

An Insulating Glass Knowledge Base  

SciTech Connect

This report will discuss issues relevant to Insulating Glass (IG) durability performance by presenting the observations and developed conclusions in a logical sequential format. This concluding effort discusses Phase II activities and focuses on beginning to quantifying IG durability issues while continuing the approach presented in the Phase I activities (Appendix 1) which discuss a qualitative assessment of durability issues. Phase II developed a focus around two specific IG design classes previously presented in Phase I of this project. The typical box spacer and thermoplastic spacer design including their Failure Modes and Effect Analysis (FMEA) and Fault Tree diagrams were chosen to address two currently used IG design options with varying components and failure modes. The system failures occur due to failures of components or their interfaces. Efforts to begin quantifying the durability issues focused on the development and delivery of an included computer based IG durability simulation program. The focus/effort to deliver the foundation for a comprehensive IG durability simulation tool is necessary to address advancements needed to meet current and future building envelope energy performance goals. This need is based upon the current lack of IG field failure data and the lengthy field observation time necessary for this data collection. Ultimately, the simulation program is intended to be used by designers throughout the current and future industry supply chain. Its use is intended to advance IG durability as expectations grow around energy conservation and with the growth of embedded technologies as required to meet energy needs. In addition the tool has the immediate benefit of providing insight for research and improvement prioritization. Included in the simulation model presentation are elements and/or methods to address IG materials, design, process, quality, induced stress (environmental and other factors), validation, etc. In addition, acquired data is presented in support of project and model assumptions. Finally, current and suggested testing protocol and procedure for future model validation and IG physical testing are discussed.

Michael L. Doll; Gerald Hendrickson; Gerard Lagos; Russell Pylkki; Chris Christensen; Charlie Cureija

2005-08-01T23:59:59.000Z

228

IMPACT OF COMPOSITION AND HEAT TREATMENT ON PORE SIZE IN POROUS WALLED HOLLOW GLASS MICROSPHERES  

DOE Green Energy (OSTI)

The Savannah River National Laboratory (SRNL) developed a new geometric form: hollow glass microspheres (HGMs), with unique porous walls. The new geometric form combines the existing technology of HGMs with basic glass science knowledge in the realm of glass-in-glass phase separation. Conceptually, the development of a HGM with porous walls (referred to as a PWHGM) provides a unique system in which various media or filling agents can be incorporated into the PWHGM (via transport through the porous walls) and ultimately has the capacity to serve as a functional delivery system in various industrial applications. Applications of these types of systems could range from hydrogen storage, molecular sieves, drug and bioactive delivery systems, to environmental, chemical and biological indicators, relevant to Energy, Environmental Processing and Homeland Security fields. As a specific example, previous studies at SRNL have introduced materials capable of hydrogen storage (as well as other materials) into the interior of the PWHGMs. The goal of this project was to determine if the microstructure (i.e., pore size and pore size distribution) of a PWHGM could be altered or tailored by varying composition and/or heat treatment (time and/or temperature) conditions. The ability to tailor the microstructure through composition or heat treatments could provide the opportunity to design the PWHGM system to accommodate different additives or fill agents. To meet this objective, HGMs of various alkali borosilicate compositions were fabricated using a flame forming apparatus installed at the Aiken County Technical Laboratory (ACTL). HGMs were treated under various heat treatment conditions to induce and/or enhance glass in glass phase separation. Heat treatment temperatures ranged from 580 C to 620 C, while heat treatment times were either 8 or 24 hours. Of the two primary variables assessed in this study, heat treatment temperature was determined to be most effective in changing the porosity of PWHGMs. Pore diameter in a non-heat treated baseline sample is approximately 100 {angstrom} and with heat treatment at 600 C for 8 hours, the diameter is approximately 1000 {angstrom}; an increase of a factor of 10. The results of this study also indicate significant microstructural differences with only a 20 C difference in heat treatment temperature (580 C and 600 C) for constant times. The microstructural changes observed via electron microscopy as a function of heat treatment temperature were confirmed by mercury porosimetry measurements, where considerable increases in pore volume were measured. Under constant heat treatment conditions, composition may impose a secondary effect on the resulting microstructure as micrographs indicate variations in the degree of porosity. Although microstructural differences were observed among the compositions assessed, the magnitude of the impact (i.e., difference in pore size or pore volume) appears to be smaller than that associated with heat treatment temperature. With respect to heat treatment time, the results suggest that the change in the degree of porosity is minimal for samples heat treated between 8 and 24 hours (it should be noted that the assessment of the impact of time on the resulting microstructure was limited to two compositions). The minimal impact of heat treatment time (on the two glasses evaluated) was confirmed by mercury porosimetry measurements indicating that there was a very slight shift in pore diameter and very little increase in pore volume in the baseline sample. Another important parameter, which will need to be considered under manufacturing or operational conditions, is the yield of the HGM and/or PWHGM and the characteristics of the final product (i.e., not only microstructure characteristics, but perhaps strength of the PWHGM for use under certain applications). In this report, yield is defined as the percentage of feed material converted to HGMs or the percentage of HGMs converted to PWHGMs. The yield of HGM formation was found to be a strong function of composition. As the S

Raszewski, F; Erich Hansen, E; Ray Schumacher, R; David Peeler, D

2007-12-04T23:59:59.000Z

229

Glass science tutorial: Lecture No. 4, commercial glass melting and associated air emission issues  

SciTech Connect

This document serves as a manual for a workshop on commercial glass melting and associated air emission issues. Areas covered include: An overview of the glass industry; Furnace design and construction practices; Melting furnace operation; Energy input methods and controls; Air legislation and regulations; Soda lime emission mechanisms; and, Post furnace emission controls. Supporting papers are also included.

Kruger, A.A.

1995-01-01T23:59:59.000Z

230

Computational studies of the glass-forming ability of model bulk metallic glasses  

E-Print Network (OSTI)

Bulk metallic glasses (BMGs) are produced by rapidly thermally quenching supercooled liquid metal alloys below the glass transition temperature at rates much faster than the critical cooling rate R_c below which crystallization occurs. The glass-forming ability of BMGs increases with decreasing R_c, and thus good glass-formers possess small values of R_c. We perform molecular dynamics simulations of binary Lennard-Jones (LJ) mixtures to quantify how key parameters, such as the stoichiometry, particle size difference, attraction strength, and heat of mixing, influence the glass-formability of model BMGs. For binary LJ mixtures, we find that the best glass-forming mixtures possess atomic size ratios (small to large) less than 0.92 and stoichiometries near 50:50 by number. In addition, weaker attractive interactions between the smaller atoms facilitate glass formation, whereas negative heats of mixing (in the experimentally relevant regime) do not change R_c significantly. These studies represent a first step in the development of computational methods for quantitatively predicting glass-formability.

Kai Zhang; Minglei Wang; Stefanos Papanikolaou; Yanhui Liu; Jan Schroers; Mark D. Shattuck; Corey S. O'Hern

2013-05-05T23:59:59.000Z

231

Glass and glass-derivative seals for use in energy-efficient fuel cells and lamps  

DOE Green Energy (OSTI)

For solid oxide fuel cells (SOFC), a series of 18 sealing glasses have been prepared and characterized. From the whole design space, several glasses were ''downselected'' and studied in detail to describe their behaviors in simulated fuel cell environments. One of the glasses was found to outperform all others, including the well-known G18 sealant developed at Pacific Northwest National Laboratory. The new glass composition showed lower bulk electrical conductivity, excellent sealing and wetting behavior when sealing under applied load, and qualitatively superior performance when exposed to wet hydrogen for 800 hours. Traditional melting was used to prepare all of the glasses that were studied in detail. The sol-gel approach was used to synthesize several compositions, but it was found that the glasses crystallized very rapidly during heating, precluding sealing. The glass characterization included measurements of the viscosity and thermal expansion of the glasses, as well as the thermal expansion of the partly crystalline glass ceramics. In addition, the wetting and sintering behavior of all glasses has been measured, as well as the crystallization behavior. The time and temperature at which crystalline phases form from the glasses has been determined for all of the glasses. Each glass ceramic contains at least two crystalline phases, and most of the crystalline phases have been positively identified. The body of fundamental data provides a platform for future developments for high temperature sealants, and the newly-developed glass compositions appear promising for large-scale testing. The second component of the work, focused on seals for higher-temperature discharge lighting, has focused on determining the phase relations in the yttria-alumina-silica system at various silica levels. Functional testing of one of the candidate sealants demonstrated that it performs well in current HID lighting applications. Further testing is required to evaluate its performance in next-generation lamps that operate at higher temperatures, but the baseline phase equilibria and crystallization behavior has been established for additional development. Again, traditional melting and sol-gel synthesis have been employed, and the sol-gel method was successful for preparing new phases that were discovered during the work. Four new phases have been identified and synthesized in pure form, from which full structure solutions were obtained as well as the anisotropic thermal expansion for each phase.

Scott Misture; Arun Varshineya; Matthew Hall; Sylvia DeCarr; Steve Bancheri

2005-07-28T23:59:59.000Z

232

ALSNews Vol. 324  

NLE Websites -- All DOE Office Websites (Extended Search)

4 Print 4 Print Bioactive Glass Scaffolds for Bone Regeneration Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. Researchers at Beamline 8.3.2 have created bioactive glass scaffolds that mirror nature's efficient materials and may provide a means for previously problematic bone regeneration in large, load-bearing limbs. Read more... Contact: Q. Fu Direct Imaging of Antiferromagnetic Vortex States Despite intensive activity in the study of ferromagnetic (FM) vortex states, there has been no direct observation of such states in antiferromagnetic (AFM) microstructures. Researchers have now taken the first direct images of two types of AFM vortex states, one of which has no FM analogue. Read more...

233

ALSNews Vol. 324  

NLE Websites -- All DOE Office Websites (Extended Search)

4 Print 4 Print Bioactive Glass Scaffolds for Bone Regeneration Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. Researchers at Beamline 8.3.2 have created bioactive glass scaffolds that mirror nature's efficient materials and may provide a means for previously problematic bone regeneration in large, load-bearing limbs. Read more... Contact: Q. Fu Direct Imaging of Antiferromagnetic Vortex States Despite intensive activity in the study of ferromagnetic (FM) vortex states, there has been no direct observation of such states in antiferromagnetic (AFM) microstructures. Researchers have now taken the first direct images of two types of AFM vortex states, one of which has no FM analogue. Read more...

234

ALSNews Vol. 324  

NLE Websites -- All DOE Office Websites (Extended Search)

4 Print 4 Print Bioactive Glass Scaffolds for Bone Regeneration Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. Researchers at Beamline 8.3.2 have created bioactive glass scaffolds that mirror nature's efficient materials and may provide a means for previously problematic bone regeneration in large, load-bearing limbs. Read more... Contact: Q. Fu Direct Imaging of Antiferromagnetic Vortex States Despite intensive activity in the study of ferromagnetic (FM) vortex states, there has been no direct observation of such states in antiferromagnetic (AFM) microstructures. Researchers have now taken the first direct images of two types of AFM vortex states, one of which has no FM analogue. Read more...

235

ALSNews Vol. 324  

NLE Websites -- All DOE Office Websites (Extended Search)

4 Print 4 Print Bioactive Glass Scaffolds for Bone Regeneration Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. Researchers at Beamline 8.3.2 have created bioactive glass scaffolds that mirror nature's efficient materials and may provide a means for previously problematic bone regeneration in large, load-bearing limbs. Read more... Contact: Q. Fu Direct Imaging of Antiferromagnetic Vortex States Despite intensive activity in the study of ferromagnetic (FM) vortex states, there has been no direct observation of such states in antiferromagnetic (AFM) microstructures. Researchers have now taken the first direct images of two types of AFM vortex states, one of which has no FM analogue. Read more...

236

ALSNews Vol. 324  

NLE Websites -- All DOE Office Websites (Extended Search)

4 Print 4 Print Bioactive Glass Scaffolds for Bone Regeneration Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. Researchers at Beamline 8.3.2 have created bioactive glass scaffolds that mirror nature's efficient materials and may provide a means for previously problematic bone regeneration in large, load-bearing limbs. Read more... Contact: Q. Fu Direct Imaging of Antiferromagnetic Vortex States Despite intensive activity in the study of ferromagnetic (FM) vortex states, there has been no direct observation of such states in antiferromagnetic (AFM) microstructures. Researchers have now taken the first direct images of two types of AFM vortex states, one of which has no FM analogue. Read more...

237

GLASS AND GLASS-DERIVATIVE SEALS FOR USE IN ENERGY-EFFICIENT FUEL CELLS AND LAMPS  

DOE Green Energy (OSTI)

As the project approaches the end of the first year, the materials screening components of the work are ahead of schedule, while all other tasks are on schedule. For solid oxide fuel cells (SOFC), a series of 16 sealing glasses have been prepared and characterized. Traditional melting was used to prepare all of the glasses, and the sol-gel approach has been used to prepare some of the glasses as well as other compositions that might be viable because of the low processing temperatures afforded by the sol-gel method. The glass characterization included measurements of the viscosity and thermal expansion of the glasses, as well as the thermal expansion of the partly crystalline glass ceramics. In addition, the wetting and sintering behavior of all glasses has been measured, as well as the crystallization behavior. The time and temperature at which crystalline phases form from the glasses has been determined for all of the glasses. Each glass ceramic contains at least two crystalline phases, and most of the crystalline phases have been positively identified. Room temperature leak testing has been completed for all sealants, and experiments are in progress to determine the DC electrochemical degradation and degradation in wet hydrogen. The second component of the work, focused on seals for higher-temperature discharge lighting, has focused on determining the phase relations in the yttria--alumina--silica system at various silica levels. Again, traditional melting and sol-gel synthesis have been employed, and the sol-gel method was successful for preparing new phases that were discovered during the work. High temperature diffraction and annealing studies have clarified the phase relations for the samples studies, although additional work remains. Four new phases have been identified and synthesized in pure form, from which full structure solutions were obtained as well as the anisotropic thermal expansion for each phase. Functional testing of lamps are on on-going and will be analyzed during year 2 of the contract.

Scott Misture; Arun Varshneya; Matthew Hall; Sylvia DeCarr; Steve Bancheri

2004-08-15T23:59:59.000Z

238

Glass viscosity calculation based on a global statistical modelling approach  

SciTech Connect

A global statistical glass viscosity model was developed for predicting the complete viscosity curve, based on more than 2200 composition-property data of silicate glasses from the scientific literature, including soda-lime-silica container and float glasses, TV panel glasses, borosilicate fiber wool and E type glasses, low expansion borosilicate glasses, glasses for nuclear waste vitrification, lead crystal glasses, binary alkali silicates, and various further compositions from over half a century. It is shown that within a measurement series from a specific laboratory the reported viscosity values are often over-estimated at higher temperatures due to alkali and boron oxide evaporation during the measurement and glass preparation, including data by Lakatos et al. (1972) and the recently published High temperature glass melt property database for process modeling by Seward et al. (2005). Similarly, in the glass transition range many experimental data of borosilicate glasses are reported too high due to phase separation effects. The developed global model corrects those errors. The model standard error was 9-17°C, with R^2 = 0.985-0.989. The prediction 95% confidence interval for glass in mass production largely depends on the glass composition of interest, the composition uncertainty, and the viscosity level. New insights in the mixed-alkali effect are provided.

Fluegel, Alex

2007-02-01T23:59:59.000Z

239

Vacuum fusion bonding of glass plates  

DOE Patents (OSTI)

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2001-01-01T23:59:59.000Z

240

Vacuum fusion bonding of glass plates  

DOE Patents (OSTI)

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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241

Dynamics of window glass fracture in explosions  

SciTech Connect

An exploratory study was conducted under the Architectural Surety Program to examine the possibility of modifying fracture of glass in the shock-wave environment associated with terrorist bombings. The intent was to explore strategies to reduce the number and severity of injuries resulting from those attacks. The study consisted of a series of three experiments at the Energetic Materials Research and Testing Center (EMRTC) of the New Mexico Institute of Mining and Technology at Socorro, NM, in which annealed and tempered glass sheets were exposed to blast waves at several different levels of overpressure and specific impulse. A preliminary assessment of the response of tempered glass to the blast environment suggested that inducing early failure would result in lowering fragment velocity as well as reducing the loading from the window to the structure. To test that possibility, two different and novel procedures (indentation flaws and spot annealing) were used to reduce the failure strength of the tempered glass while maintaining its ability to fracture into small cube-shaped fragments. Each experiment involved a comparison of the performance of four sheets of glass with different treatments.

Beauchamp, E.K.; Matalucci, R.V.

1998-05-01T23:59:59.000Z

242

Sealing glasses for titanium and titanium alloys  

DOE Patents (OSTI)

Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B.sub.2 O.sub.3), barium oxide (BaO), lanthanum oxide (La.sub.2 O.sub.3), and at least one other oxide selected from the group consisting of aluminum oxide (Al.sub.2 O.sub.3), calcium oxide (CaO), lithium oxide (Li.sub.2 O), sodium oxide (Na.sub.2 O), silicon dioxide (SiO.sub.2), or titanium dioxide (TiO.sub.2). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900.degree. C., and generally about 700.degree.-800.degree. C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

1997-01-01T23:59:59.000Z

243

Sealing glasses for titanium and titanium alloys  

DOE Patents (OSTI)

Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B{sub 2}O{sub 3}), barium oxide (BaO), lanthanum oxide (La{sub 2}O{sub 3}), and at least one other oxide selected from the group consisting of aluminum oxide (Al{sub 2}O{sub 3}), calcium oxide (CaO), lithium oxide (Li{sub 2}O), sodium oxide (Na{sub 2}O), silicon dioxide (SiO{sub 2}), or titanium dioxide (TiO{sub 2}). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900 C, and generally about 700--800 C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 1 fig.

Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

1997-07-15T23:59:59.000Z

244

Properties of glass-bonded zeolite monoliths  

Science Conference Proceedings (OSTI)

It has been shown that mineral waste forms can be used to immobilize waste salt generated during the pyrochemical processing of spent fuel from the Integral Fast Reactor (IFR). Solid, leach resistant monoliths were formed by hot-pressing mixtures of salt-occluded zeolite A powders and glass frit at 990 K and 28 MPa. Additional samples have now been fabricated and tested. Normalized release rates for all elements, including iodide and chloride, were less than 1 g/m{sup 2}d in 28-day tests in deionized water and in brine at 363 K (90{degrees}C). Preliminary results indicate that these rates fall with time with both leachants and that the zeolite phase in the glass-bonded zeolite does not function as an ion exchanger. Some material properties were measured. The Poisson ratio and Young`s modulus were slightly smaller in glass-bonded zeolite than in borosilicate glass. Density depended on zeolite fraction. The glass-bonded zeolite represents a promising mineral waste form for IFR salt.

Lewis, M.A.; Fischer, D.F. [Argonne National Lab., IL (United States); Murphy, C.D. [Univ. of Cincinnati, OH (United States)

1994-05-01T23:59:59.000Z

245

Bioactive Coatings  

Science Conference Proceedings (OSTI)

Oct 10, 2012 ... Tailoring the Surface Properties of Parylene Biocompatible Coating: Martina Cihova1; Quoc Nguyen2; Varshni Singh2; 1Karlsruhe Institute of ...

246

The fabrication and characterization of linearly oriented nerve guidance scaffolds for spinal cord injury  

E-Print Network (OSTI)

of glass tubes containing polymerized agarose to a block ofglass tube in Styrofoam was then placed onto the surface of a 15 Â 15 Â 3 cm 3 block

Stokols, S; Tuszynski, M H

2004-01-01T23:59:59.000Z

247

Glass Buttes Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Glass Buttes Geothermal Area Glass Buttes Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Glass Buttes Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (1) 9 Exploration Activities (14) 10 References Area Overview Geothermal Area Profile Location: Oregon Exploration Region: Cascades GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure Operating Power Plants: 0 No geothermal plants listed. Add a new Operating Power Plant Developing Power Projects: 0

248

Irradiation effects on borosilicate waste glasses  

SciTech Connect

The effects of alpha decay on five borosilicate glasses containing simulated nuclear high-level waste oxides were studied. Irradiations carried out at room temperature were achieved by incorporating 1 to 8 wt % /sup 244/Cm/sub 2/O/sub 3/ in the glasses. Density changes and stored-energy build-up saturated at doses less than 2 x 10/sup 21/ alpha decays/kg. Damage manifested by stored energy was completely annealed at 633/sup 0/K. Positive and negative density changes were observed which never exceeded 1%. Irradiation had very little effect on mechanical strength or on chemical durability as measured by aqueous leach rates. Also, no effects were observed on the microstructure for vitreous waste glasses, although radiation-induced microcracking could be achieved on specimens that had been devitrified prior to irradiation.

Roberts, F.P.

1980-06-01T23:59:59.000Z

249

Glass material oxidation and dissolution system: Converting miscellaneous fissile materials to glass  

SciTech Connect

The cold war and the development of nuclear energy have resulted in significant inventories of miscellaneous fissile materials (MFMs). MFMs include (1) plutonium scrap and residue, (2) miscellaneous spent nuclear fuel (SNF), (3) certain hot cell wastes, and (4) many one-of-a-kind materials. Major concerns associated with the long-term management of these materials include: safeguards and nonproliferation issues; health, environment, and safety concerns. waste management requirements; and high storage costs. These issues can be addressed by converting the MFMs to glass for secure, long-term storage or repository disposal; however, conventional glass-making processes require oxide-like feed materials. Converting MFMs to oxide-like materials with subsequent vitrification is a complex and expensive process. A new vitrification process has been invented, the Glass Material Oxidation and Dissolution System (GMODS), which directly converts metals, ceramics, and amorphous solids to glass; oxidizes organics with the residue converted to glass; and converts chlorides to borosilicate glass and a secondary sodium chloride (NaCl) stream. Laboratory work has demonstrated the conversion of cerium (a plutonium surrogate), uranium, Zircaloy, stainless steel, multiple oxides, and other materials to glass. However, significant work is required to develop GMODS further for applications at an industrial scale. If implemented, GMODS will provide a new approach to manage these materials.

Forsberg, C.W.; Ferrada, J.J.

1996-03-19T23:59:59.000Z

250

Properties of low cost, high volume glasses  

DOE Green Energy (OSTI)

The properties of new and weathered samples of low cost, high volume glasses have been studied to determine their usefulness for solar energy applications. Glasses of varying compositions produced by float, drawn, rolled fusion, and twin ground techniques were examined. Spectral transmittance and reflectance were measured and solar weighted values calculated. Laser raytrace techniques were used to evaluate surface parallelism and bulk homogeneity. Compositional changes were examined with scanning electron microscopy, x-ray fluorescence, and Auger electron spectroscopy. These techniques were used in conjunction with ellipsometry to study the surface effects associated with weathering.

Lind, M. A.; Hartman, J. S.; Buckwalter, C. Q.

1979-01-01T23:59:59.000Z

251

Nonlinear mechanics of thermoreversibly associating dendrimer glasses  

E-Print Network (OSTI)

We model the mechanics of associating trivalent dendrimer network glasses with a focus on their energy dissipation properties. Various combinations of sticky bond (SB) strength and kinetics are employed. The toughness (work-to-fracture) of these systems displays a surprising deformation-protocol dependence; different association parameters optimize different properties. In particular, "strong, slow" SBs optimize strength, while "weak, fast" SBs optimize ductility via self-healing during deformation. We relate these observations to breaking, reformation, and partner-switching of SBs during deformation. These studies point the way to creating associating-polymer network glasses with tailorable mechanical properties.

Arvind Srikanth; Robert S. Hoy; Berend C. Rinderspacher; Jan W. Andzelm

2013-08-06T23:59:59.000Z

252

Direction of CRT waste glass processing: Electronics recycling industry communication  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Given a large flow rate of CRT glass {approx}10% of the panel glass stream will be leaded. Black-Right-Pointing-Pointer The supply of CRT waste glass exceeded demand in 2009. Black-Right-Pointing-Pointer Recyclers should use UV-light to detect lead oxide during the separation process. Black-Right-Pointing-Pointer Recycling market analysis techniques and results are given for CRT glass. Black-Right-Pointing-Pointer Academic initiatives and the necessary expansion of novel product markets are discussed. - Abstract: Cathode Ray Tube, CRT, waste glass recycling has plagued glass manufacturers, electronics recyclers and electronics waste policy makers for decades because the total supply of waste glass exceeds demand, and the formulations of CRT glass are ill suited for most reuse options. The solutions are to separate the undesirable components (e.g. lead oxide) in the waste and create demand for new products. Achieving this is no simple feat, however, as there are many obstacles: limited knowledge of waste glass composition; limited automation in the recycling process; transportation of recycled material; and a weak and underdeveloped market. Thus one of the main goals of this paper is to advise electronic glass recyclers on how to best manage a diverse supply of glass waste and successfully market to end users. Further, this paper offers future directions for academic and industry research. To develop the recommendations offered here, a combination of approaches were used: (1) a thorough study of historic trends in CRT glass chemistry; (2) bulk glass collection and analysis of cullet from a large-scale glass recycler; (3) conversations with industry members and a review of potential applications; and (4) evaluation of the economic viability of specific uses for recycled CRT glass. If academia and industry can solve these problems (for example by creating a database of composition organized by manufacturer and glass source) then the reuse of CRT glass can be increased.

Mueller, Julia R., E-mail: mueller.143@osu.edu [Ohio State University, William G. Lowrie Department of Chemical and Biomolecular Engineering, OH (United States) and University of Queensland, School of Chemical Engineering (Australia) and Ohio State University, Materials Science and Engineering, OH (United States); Boehm, Michael W. [University of Queensland, School of Chemical Engineering (Australia); Drummond, Charles [Ohio State University, Materials Science and Engineering, OH (United States)

2012-08-15T23:59:59.000Z

253

PLUTONIUM SOLUBILITY IN HIGH-LEVEL WASTE ALKALI BOROSILICATE GLASS  

SciTech Connect

The solubility of plutonium in a Sludge Batch 6 (SB6) reference glass and the effect of incorporation of Pu in the glass on specific glass properties were evaluated. A Pu loading of 1 wt % in glass was studied. Prior to actual plutonium glass testing, surrogate testing (using Hf as a surrogate for Pu) was conducted to evaluate the homogeneity of significant quantities of Hf (Pu) in the glass, determine the most appropriate methods to evaluate homogeneity for Pu glass testing, and to evaluate the impact of Hf loading in the glass on select glass properties. Surrogate testing was conducted using Hf to represent between 0 and 1 wt % Pu in glass on an equivalent molar basis. A Pu loading of 1 wt % in glass translated to {approx}18 kg Pu per Defense Waste Processing Facility (DWPF) canister, or about 10X the current allowed limit per the Waste Acceptance Product Specifications (2500 g/m{sup 3} of glass or about 1700 g/canister) and about 30X the current allowable concentration based on the fissile material concentration limit referenced in the Yucca Mountain Project License Application (897 g/m{sup 3}3 of glass or about 600 g Pu/canister). Based on historical process throughput data, this level was considered to represent a reasonable upper bound for Pu loading based on the ability to provide Pu containing feed to the DWPF. The task elements included evaluating the distribution of Pu in the glass (e.g. homogeneity), evaluating crystallization within the glass, evaluating select glass properties (with surrogates), and evaluating durability using the Product Consistency Test -- Method A (PCT-A). The behavior of Pu in the melter was evaluated using paper studies and corresponding analyses of DWPF melter pour samples.The results of the testing indicated that at 1 wt % Pu in the glass, the Pu was homogeneously distributed and did not result in any formation of plutonium-containing crystalline phases as long as the glass was prepared under 'well-mixed' conditions. The incorporation of 1 wt % Pu in the glass did not adversely impact glass viscosity (as assessed using Hf surrogate) or glass durability. Finally, evaluation of DWPF glass pour samples that had Pu concentrations below the 897 g/m{sup 3} limit showed that Pu concentrations in the glass pour stream were close to targeted compositions in the melter feed indicating that Pu neither volatilized from the melt nor stratified in the melter when processed in the DWPF melter.

Marra, J.; Crawford, C.; Fox, K.; Bibler, N.

2011-01-04T23:59:59.000Z

254

Biological Materials Science  

Science Conference Proceedings (OSTI)

Factors Affecting the Dissolution of Resorbable Bioactive Glasses · Fatigue Behavior ... Manufacturing Bioactive Glass 45S5 by the Sol-Gel Method · Mechanical ...

255

IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION KT07-SERIES GLASS COMPOSITIONS  

Science Conference Proceedings (OSTI)

This report is the third in a series of studies of the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility is also considered in the study. The KT07-series glasses were selected to evaluate any potential impacts of noble metals on their properties and performance. The glasses characterized thus far for the SCIX study have not included noble metals since they are not typically tracked in sludge batch composition projections. However, noble metals can act as nucleation sites in glass melts, leading to enhanced crystallization. This crystallization can potentially influence the properties and performance of the glass, such as chemical durability, viscosity, and liquidus temperature. The noble metals Ag, Pd, Rh, and Ru were added to the KT07-series glasses in concentrations based on recent measurements of Sludge Batch 6, which was considered to contain a high concentration of noble metals. The KT04-series glasses were used as the baseline compositions. After fabrication, the glasses were characterized to determine their homogeneity, chemical composition, durability, and viscosity. Liquidus temperature measurements are also underway but were not complete at the time of this report. The liquidus temperature results for the KT07-series glasses, along with several of the earlier glasses in the SCIX study, will be documented separately. All of the KT07-series glasses, both quenched and slowly cooled, were found to be amorphous by X-ray diffraction. Chemical composition measurements showed that all of the glasses met their targeted compositions. The Product Consistency Test (PCT) results showed that all of the glasses had chemical durabilities that were far better than that of the Environmental Assessment benchmark glass. The measured PCT responses were well predicted by the current DWPF Product Composition Control System (PCCS) durability models. The measured viscosity values for each KT07-series glass were acceptable for DWPF processing and were well predicted by the current PCCS model. Overall, the results show that the inclusion of relatively high concentrations of noble metals (in terms of expected values for a DWPF sludge batch) had no significant impact on the properties and performance of these glass compositions. There were no significant differences in the measured properties when compared to those of the KT04-series glasses, which did not contain noble metals. Liquidus temperature measurements are still underway and there may be an impact of the noble metals on those measurements. However, no adverse effects were noted in terms of crystallization after slow cooling. At the completion of these studies, all of the data generated will be reviewed with regard to the applicability of the DWPF PCCS models and recommendations will be made as to whether the validation ranges of the current models can be extended, or whether some or all of the models need to be refit to allow for the incorporation of the SCIX streams. As changes are made to the projected sludge compositions and the volume of the SCIX material, additional evaluations should be performed.

Fox, K.; Edwards, T.

2011-01-12T23:59:59.000Z

256

Glass Transition by Gelation in a Phase Separating Binary Alloy  

E-Print Network (OSTI)

We use molecular dynamics simulations to show that glass transition in a model phase separating amorphous alloy, Cu50Nb50, occurs by gelation. At the glass transition, a mechanically stiff, percolating network of atoms ...

Baumer, Richard E.

257

Nano-structured self-cleaning superhydrophobic glass  

E-Print Network (OSTI)

glass have been fabricated by Teflon coating, polystyrene-block-blocks, and RIE processes. Teflon nanopillars- decorated glassblock-poly (4-vinylpyridine) (PS-b- P4VP) coatings on a glass

Kim, Jin Yeol

2010-01-01T23:59:59.000Z

258

EA-0821: Operation of the Glass Melter Thermal Treatment Unit...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1: Operation of the Glass Melter Thermal Treatment Unit at the U.S. Department of Energy's Mound Plant, Miamisburg, Ohio EA-0821: Operation of the Glass Melter Thermal Treatment...

259

Weathering and leaching of glass for solar heliostats  

DOE Green Energy (OSTI)

In order to assess the effects of weathering on the transmittance of glass, several old samples were collected from two desert environments for evaluation. The glass obtained by PNL at the Hanford reservation in Washington came from south-facing, vertical windows which were known to be over forty years old. The glass obtained by Sandia from Barstow, California, is estimated to be over twenty years old. To determine the durability of glasses proposed for heliostat mirrors, selected samples were leached in a Soxhlet apparatus and pH 4 and pH 9 buffer solutions. The glass samples produced by the float process are soda-lime-silica glasses, whereas the glass samples produced by the fusion process are aluminosilicate glasses. Results are presented and discussed. (WHK)

Rusin, J. M.

1979-03-01T23:59:59.000Z

260

The Development of Glass Compositions for the Vitrification of Ion ...  

Science Conference Proceedings (OSTI)

This presentation explores the development of a glass system intended for the ... The Effects of Lithium Nitrate on Highly Active Liquor in the Calcination Process ... Viscosity of Multicomponent Glasses as a Function of Temperature and ...

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Science and Technology of Chemical Strengthening of Glass  

Science Conference Proceedings (OSTI)

One of Cooper's contributions to glass was the scientific understanding of the ... Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass ... Mechanisms of the Conversion Reaction in FeF2 Cathodes Exposed to Li in ...

262

Conversion of Rare Earth Doped Borate Glass to Rare Earth ...  

Science Conference Proceedings (OSTI)

A History of the Theories of Glass Structure: Can We Really Believe What is ... Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass ... Mechanisms of the Conversion Reaction in FeF2 Cathodes Exposed to Li in ...

263

Advanced Characterization as Applied to the Corrosion of Glass  

Science Conference Proceedings (OSTI)

A History of the Theories of Glass Structure: Can We Really Believe What is ... Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass ... Mechanisms of the Conversion Reaction in FeF2 Cathodes Exposed to Li in ...

264

SLAC National Accelerator Laboratory - Metallic Glass: A Crystal...  

NLE Websites -- All DOE Office Websites (Extended Search)

Metallic Glass: A Crystal at Heart June 16, 2011 Menlo Park, Calif.-Glass, by definition, is amorphous; its atoms lack order and are arranged every which way. But when scientists...

265

Space-time thermodynamics of the glass transition  

E-Print Network (OSTI)

Space-time Thermodynamics of the Glass Transition Maurobehavior in terms of a thermodynamics of trajectory space.

Merolle, Mauro; Garrahan, Juan P.; Chandler, David

2005-01-01T23:59:59.000Z

266

Glass Ion Exchange: One Century of "Tough" Applications  

Science Conference Proceedings (OSTI)

... ion-exchange to glass components such as pharmaceutical packaging, transparent lightweight armor, transparencies for private vehicles, trains and aircrafts, ...

267

Ceramic and Glass Composite Interconnects for Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2011. Symposium, Energy Conversion/Fuel Cells. Presentation Title, Ceramic and Glass ...

268

Glass manufacturing is an energy-intensive industry mainly ...  

U.S. Energy Information Administration (EIA)

Energy Information Administration ... There is substantial potential for energy efficiency improvements in glass manufacturing. Estimates range from ...

269

Glass-Ceramic Seal for Solid Oxide Fuel Cells - Available ...  

Computers & Electronics; Consumer Products; Energy & Utilities; Manufacturing & Warehousing; Video(s) Glass frit is dispersed in a ...

270

Glass molding process with mold lubrication  

DOE Patents (OSTI)

Improvements are provided in glass forming processes of the type wherein hot metal blank molds are employed by using the complementary action of a solid film lubricant layer, of graphite dispersed in a cured thermoset organopolysiloxane, along with an overspray of a lubricating oil.

Davey, Richard G. (Toledo, OH)

1978-06-27T23:59:59.000Z

271

DWPF Glass Melter Technology Manual: Volume 4  

Science Conference Proceedings (OSTI)

This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Plant. Information contained in this document consists solely of a machine drawing and parts list and purchase orders with specifications of equipment used in the development of the melter.

Iverson, D.C.

1993-12-31T23:59:59.000Z

272

Window selection: problems and promise of glass  

SciTech Connect

In the past few years, technical innovations in glass and window design have made windows more energy efficient, reducing energy costs and increasing the comfort levels in buildings. These innovations make it possible for occupants to enjoy the benefits of real windows while enabling owners and managers to lower overall operating costs. 1 figure, 1 table.

1986-04-01T23:59:59.000Z

273

Polymers replace glass in Nova fuel capsules  

SciTech Connect

The glass fuel-capsule designs used in previous laser-fusion research are not adaptable to the implosion-physics requirements of Nova and other more powerful laser facilities that may be available in the future. As one tries to learn more about the physics of high-density compression, it becomes increasingly important to replace the glass with lower-Z material. Accordingly, the authors have shut down the high-temperature drop-tower furnaces they used to make glass capsules, and they are focusing all their efforts on developing new techniques for making polymer capsules. These capsules are ten times larger in diameter than the glass capsules used in the early days of laser-fusion research, but they are still only one-tenth as large as a high-gain capsule must be. The polymer capsules will be used in classified indirect-drive targets. This article describes how the decisions were made on which polymers to use in the NOVA fuel capsules, the techniques explored, and the properties of the prototype capsules.

Burnham, A.K.

1986-01-01T23:59:59.000Z

274

DWPF Glass Melter Technology Manual: Volume 3  

Science Conference Proceedings (OSTI)

This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Site. Topics discussed include: Information collected during testing, equipment, materials, design basis, feed tubes, and an evaluation of the performance of various components. Information is conveyed using many diagrams and photographs.

Iverson, D.C.

1993-12-31T23:59:59.000Z

275

The Conservation of Seventeenth Century Archaeological Glass  

E-Print Network (OSTI)

The primary goal of the conservator is to stabilize and conserve artifacts with the best possible treatment available. Ideally, these treatments are noninvasive and reversible, and maintain the integrity of the object as a top priority. In this respect, it is the responsibility of the conservator to research other possible treatments when traditional methods prove to be insufficient to properly stabilize and conserve an object. Sometimes choosing to treat with a seemingly unorthodox method is the only chance for the objects survival. Though glass is considered one of the most stable archaeological materials, noninvasive, reversible treatments are not always possible given the level of deterioration glass objects undergo within the archaeological setting, specifically the underwater or waterlogged archaeological setting. This research is a consideration and investigation of the use of silicone polymers and silanes as consolidation materials for 17th-century glass recovered from aqueous environments. Working within the Conservation Research Laboratory and the Archaeological Preservation Research Laboratory at Texas A and M University, a newly developed polymer passivation technique utilizing materials acquired from the Dow Corning Corporation was applied to archaeological glass recovered from the 1686 shipwreck La Belle, excavated in Matagorda Bay off the coast of Texas by the Texas Historical Commission from 1996 to 1997. The successful application of a hydroxyl ended silicone polymer Q-1 3563, combined with a methyltrimethoxysilane intermediate crosslinker, Q-9 1315, at a 15% solution by weight and catalyzed with dibutyltin diacetate (DBTDA Fascat 4200) occurred in 1999. This project was the first large scale application of silicone polymers and silanes to 17th-century archaeological glass recovered from a marine site. Through this investigation we answered a number of questions regarding the use and application of the silicone technologies and confirmed that these materials are a viable resource for glass consolidation and conservation in terms of the suggested conservation guidelines of the IIC. The silicone technology was successfully applied to numerous types, forms, colors and degradation levels of glass. This included successful application to composite artifacts and the retreatment of objects unsuccessfully treated with a "traditional" method.

Arcak, Cory

2009-08-01T23:59:59.000Z

276

HIGH ALUMINUM HLW GLASSES FOR HANFORDS WTP  

Science Conference Proceedings (OSTI)

The world's largest radioactive waste vitrification facility is now under construction at the United State Department of Energy's (DOE's) Hanford site. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is designed to treat nearly 53 million gallons of mixed hazardous and radioactive waste now residing in 177 underground storage tanks. This multi-decade processing campaign will be one of the most complex ever undertaken because of the wide chemical and physical variability of the waste compositions generated during the cold war era that are stored at Hanford. The DOE Office of River Protection (ORP) has initiated a program to improve the long-term operating efficiency of the WTP vitrification plants with the objective of reducing the overall cost of tank waste treatment and disposal and shortening the duration of plant operations. Due to the size, complexity and duration of the WTP mission, the lifecycle operating and waste disposal costs are substantial. As a result, gains in High Level Waste (HLW) and Low Activity Waste (LAW) waste loadings, as well as increases in glass production rate, which can reduce mission duration and glass volumes for disposal, can yield substantial overall cost savings. EnergySolutions and its long-term research partner, the Vitreous State Laboratory (VSL) of the Catholic University of America, have been involved in a multi-year ORP program directed at optimizing various aspects of the HLW and LAW vitrification flow sheets. A number of Hanford HLW streams contain high concentrations of aluminum, which is challenging with respect to both waste loading and processing rate. Therefore, a key focus area of the ORP vitrification process optimization program at EnergySolutions and VSL has been development of HLW glass compositions that can accommodate high Al{sub 2}O{sub 3} concentrations while maintaining high processing rates in the Joule Heated Ceramic Melters (JHCMs) used for waste vitrification at the WTP. This paper, reviews the achievements of this program with emphasis on the recent enhancements in Al{sub 2}O{sub 3} loadings in HLW glass and its processing characteristics. Glass formulation development included crucible-scale preparation and characterization of glass samples to assess compliance with all melt processing and product quality requirements, followed by small-scale screening tests to estimate processing rates. These results were used to down-select formulations for subsequent engineering-scale melter testing. Finally, further testing was performed on the DM1200 vitrification system installed at VSL, which is a one-third scale (1.20 m{sup 2}) pilot melter for the WTP HLW melters and which is fitted with a fully prototypical off-gas treatment system. These tests employed glass formulations with high waste loadings and Al{sub 2}O{sub 3} contents of {approx}25 wt%, which represents a near-doubling of the present WTP baseline maximum Al{sub 2}O{sub 3} loading. In addition, these formulations were processed successfully at glass production rates that exceeded the present requirements for WTP HLW vitrification by up to 88%. The higher aluminum loading in the HLW glass has an added benefit in that the aluminum leaching requirements in pretreatment are reduced, thus allowing less sodium addition in pretreatment, which in turn reduces the amount of LAW glass to be produced at the WTP. The impact of the results from this ORP program in reducing the overall cost and schedule for the Hanford waste treatment mission will be discussed.

KRUGER AA; JOSEPH I; BOWMAN BW; GAN H; KOT W; MATLACK KS; PEGG IL

2009-08-19T23:59:59.000Z

277

CADMIUM-RARE EARTH BORATE GLASS AS REACTOR CONTROL MATERIAL  

DOE Patents (OSTI)

A reactor control rod fabricated from a cadmiumrare earth-borate glass is presented. The rare earth component of this glass is selected from among those rare earths having large neutron capture cross sections, such as samarium, gadolinium or europium. Partlcles of this glass are then dispersed in a metal matrix by standard powder metallurgy techniques.

Ploetz, G.L.; Ray, W.E.

1958-11-01T23:59:59.000Z

278

Energy efficient residential new construction: market transformation. Spectral selective glass. Final project report  

Science Conference Proceedings (OSTI)

This final report describes the following tasks associated with this project: cost and availability of spectrally selective glass (SSG); window labeling problem and field verification of glass; availability of SSG replacement glass and tempered glass; HVAC load reduction due to spectrally selective glass; and comsumer appreciation of spectrally selective glass. Also included in the report are four attachments: builder and HVAC subcontractor presentation, sample advertisements, spectrally selective glass demonstration model, and invitation to SCE Glass mini trade-show.

Hammon, Robert

2000-12-18T23:59:59.000Z

279

Relationship between the shear viscosity and heating rate in metallic glasses below the glass transition  

Science Conference Proceedings (OSTI)

It has been shown that first-order irreversible structural relaxation with distributed activation energies must lead to a linear decrease of the logarithm of Newtonian shear viscosity with the logarithm of heating rate upon linear heating of glass. Such a behavior is indeed observed in the experiments on metallic glasses. Structural relaxation-induced viscous flow leads to infra-low-frequency Maxwell viscoelastic internal friction, which is predicted to increase with the heating rate.

Khonik, Vitaly A.; Kobelev, N. P. [Department of General Physics, State Pedagogical University, Lenin Street 86, 394043 Voronezh (Russian Federation); Institute for Solid State Physics, Chernogolovka, 142432 Moscow District (Russian Federation)

2008-04-01T23:59:59.000Z

280

Aging in attraction-driven colloidal glasses  

E-Print Network (OSTI)

Aging in an attraction-driven colloidal glass is studied by computer simulations. The system is equilibrated without attraction and instantaneously ``quenched'', at constant colloid volume fraction, to one of two states beyond the glass transition; one is close to the transition, and the other one deep in the glass. The evolution of structural properties shows that bonds form in the system, increasing the local density, creating density deficits (holes) elsewhere. This process slows down with the time elapsed since the quench. As a consequence of bond formation, there is a slowing down of the dynamics, as measured by the mean squared displacement and the density, bond, and environment correlation functions. The density correlations can be time-rescaled to collapse their long time (structural) decay. The time scale for structural relaxation shows for both quenches a super-linear dependence on waiting time; it grows faster than the bond lifetime, showing the collective origin of the transition. At long waiting times and high attraction strength, we observe {\\rem completely} arrested dynamics for more than three decades in time, although individual bonds are not permanent on this time scale. The localization length decreases as the state moves deeper in the glass; the non-ergodicity parameter oscillates in phase with the structure factor. Our main results are obtained for systems with a barrier in the pair potential that inhibits phase separation. However, when this barrier is removed for the case of a deep quench, we find changes in the static structure but almost none in the dynamics. Hence our results for the aging behavior remain relevant to experiments in which the glass transition competes with phase separation.

Antonio M. Puertas; Matthias Fuchs; Michael E. Cates

2006-03-24T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Promotion of EFL Student Motivation, Confidence, and Satisfaction Via a Learning Spiral, Peer-Scaffolding, and CMC  

Science Conference Proceedings (OSTI)

This study presents an EFL English as a Foreign Language instructional model in which peer interaction improves motivation, confidence, satisfaction, and actual performance of students. Researchers used peer interaction for repeated assignments via Computer-Mediated ... Keywords: Actual Performance, Computer Mediated Communication, Confidence, Constructivism, EFL, Instrumental Motivation, Integrative Motivation, Learning Spiral, Peer Interaction, Satisfaction, Scaffolding

Wen-Chi Vivian Wu; Michael Marek; Ling Ling Yen

2012-07-01T23:59:59.000Z

282

Fabrication and characterization of collagen-immobilized porous PHBV/HA nanocomposite scaffolds for bone tissue engineering  

Science Conference Proceedings (OSTI)

The porous composite scaffolds (PHBV/HA) consisting of poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and hydroxyapatite (HA) were fabricated using a hot-press machine and salt-leaching. Collagen (type I) was then immobilized on the surface of ...

Jin-Young Baek; Zhi-Cai Xing; Giseop Kwak; Keun-Byoung Yoon; Soo-Young Park; Lee Soon Park; Inn-Kyu Kang

2012-01-01T23:59:59.000Z

283

The Assembly of Nano-materials Using Bio-Scaffolding C. Steven Yun, Jody L. Major, Geoffrey F. Strouse*  

E-Print Network (OSTI)

The Assembly of Nano-materials Using Bio-Scaffolding C. Steven Yun, Jody L. Major, Geoffrey F for electronics and sensing applications. Bio-engineered architectures arising from the fusion of nano of biological materials and the intrinsic optical and electronic properties of nano-materials. The criteria

Strouse, Geoffrey F.

284

Sealed glass coating of high temperature ceramic superconductors  

DOE Patents (OSTI)

A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor is disclosed. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor. 8 figs.

Wu, W.; Chu, C.Y.; Goretta, K.C.; Routbort, J.L.

1995-05-02T23:59:59.000Z

285

Glass Mica Composite Seals for Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

A novel glass-mica composite seal was developed based on the previous concept of ''infiltrated'' mica seals for solid oxide fuel cells. A Ba-Al-Ca silicate sealing glass was mixed with mica flakes to form the glass-mica composite seals. The glass-mica composite seals were tested thermal cycle stability in terms of the high temperature leakage and compressive stresses. Post mortem analyses were used to characterize the fracture and leak path of the glass-mica composite seals.

Chou, Y S.; Stevenson, Jeffry W.; Singh, Prabhakar

2005-07-20T23:59:59.000Z

286

Energy Efficient Glass Melting - The Next Generation Melter  

Science Conference Proceedings (OSTI)

The objective of this project is to demonstrate a high intensity glass melter, based on the submerged combustion melting technology. This melter will serve as the melting and homogenization section of a segmented, lower-capital cost, energy-efficient Next Generation Glass Melting System (NGMS). After this project, the melter will be ready to move toward commercial trials for some glasses needing little refining (fiberglass, etc.). For other glasses, a second project Phase or glass industry research is anticipated to develop the fining stage of the NGMS process.

David Rue

2008-03-01T23:59:59.000Z

287

DEVELOPMENT OF GLASS MATRICES FOR HLW RADIOACTIVE WASTES  

Science Conference Proceedings (OSTI)

Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either borosilicate glass or phosphate glass. One of the primary reasons that glass has become the most widely used immobilization media is the relative simplicity of the vitrification process, e.g. melt waste plus glass forming frit additives and cast. A second reason that glass has become widely used for HLW is that the short range order (SRO) and medium range order (MRO) found in glass atomistically bonds the radionuclides and governs the melt properties such as viscosity, resistivity, sulphate solubility. The molecular structure of glass controls contaminant/radionuclide release by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. The molecular structure is flexible and hence accounts for the flexibility of glass formulations to waste variability. Nuclear waste glasses melt between 1050-1150 C which minimizes the volatility of radioactive components such as Tc{sup 99}, Cs{sup 137}, and I{sup 129}. Nuclear waste glasses have good long term stability including irradiation resistance. Process control models based on the molecular structure of glass have been mechanistically derived and have been demonstrated to be accurate enough to control the world's largest HLW Joule heated ceramic melter in the US since 1996 at 95% confidence.

Jantzen, C.

2010-03-18T23:59:59.000Z

288

GlassPoint Solar Inc | Open Energy Information  

Open Energy Info (EERE)

GlassPoint Solar Inc GlassPoint Solar Inc Jump to: navigation, search Name GlassPoint Solar Inc. Place San Francisco, California Zip 94105 Sector Solar Product San Francisco-based developer and marketer of solar industrial process heat generating equipment for a wide range of industries including enhanced oil recovery, municipal waste water treatment and electrical power generation. References GlassPoint Solar Inc.[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. GlassPoint Solar Inc. is a company located in San Francisco, California . References ↑ "GlassPoint Solar Inc." Retrieved from "http://en.openei.org/w/index.php?title=GlassPoint_Solar_Inc&oldid=345889

289

Ammonia-treated phosphate glasses useful for sealing to metals  

DOE Patents (OSTI)

A method of improving surface-dependent properties of phosphate glass such as durability and wear resistance without significantly affecting its thermal expansion coefficient is provided which comprises annealing the glass in a dry ammonia atmosphere at temperatures approximating the transition temperature of the glass. The ammonia annealing treatment of the present invention is carried out for a time sufficient to allow incorporation of a thin layer of nitrogen into the surface of the phosphate glass, and the treatment improves the durability of the glass without the reduction in the thermal expansion coefficient that has restricted the effectiveness of prior ammonia treatments. The improved phosphate glass resulting from this method is superior in wear resistance, yet maintains suitable thermal expansion properties so that it may be used effectively in a variety of applications requiring hermetic glass-metal seals.

Brow, R.K.; Day, D.E.

1990-12-31T23:59:59.000Z

290

Control of Nepheline Crystallization in Nuclear Waste Glass  

SciTech Connect

Glass frits with a high B{sub 2}O{sub 3} concentration have been designed which, when combined with high-alumina concentration nuclear waste streams, will form glasses with durabilities that are acceptable for repository disposal and predictable using a free energy of hydration model. Two glasses with nepheline discriminator values closest to 0.62 showed significant differences in normalized boron release between the quenched and heat treated versions of each glass. X-ray diffraction confirmed that nepheline crystallized in the glass with the lowest nepheline discriminator value, and nepheline may also exist in the second glass as small nanocrystals. The high-B{sub 2}O{sub 3} frit was successful in producing simulated waste glasses with no detectable nepheline crystallization at waste loadings of up to 45 wt%. The melt rate of this frit was also considerably better than other frits with increased concentrations of Na{sub 2}O.

Fox, Kevin

2008-07-01T23:59:59.000Z

291

Bulk Metallic Glasses Deform via Slip Avalanches  

E-Print Network (OSTI)

Inelastic deformation of metallic glasses occurs via slip events with avalanche dynamics similar to those of earthquakes. For the first time in these materials, measurements have been obtained with sufficiently high temporal resolution to extract both the exponents and the scaling functions that describe the nature, statistics and dynamics of the slips according to a simple mean-field model. These slips originate from localized deformation in shear bands. The mean-field model describes the slip process as an avalanche of rearrangements of atoms in shear transformation zones (STZs). Small slips show the predicted power-law scaling and correspond to limited propagation of a shear front, while large slips are associated with uniform shear on unconstrained shear bands. The agreement between the model and data across multiple independent measures of slip statistics and dynamics provides compelling evidence for slip avalanches of STZs as the elementary mechanism of inhomogeneous deformation in metallic glasses.

James Antonaglia; Wendelin J. Wright; Xiaojun Gu; Rachel R. Byer; Todd C. Hufnagel; Michael LeBlanc; Jonathan T. Uhl; Karin A. Dahmen

2013-12-21T23:59:59.000Z

292

Water dynamics in controlled pore silica glasses  

DOE Green Energy (OSTI)

Water in porous silica glass is a suitable system for investigating the effect of confinement on translational diffusion. These systems are important because of their relevance in catalytic and separation processes. Two factors are to be considered in the case of confined water: (1) the effects of hydrophilic and hydrophobic surfaces on interfacial water and (2) how the dynamics of the hydrogen bond network changes due to the volume of confinement. Here quasi-elastic neutron scattering experiments at room temperature on water filled controlled pore glasses with radius of 15, 24 and 32 {angstrom}, are presented and analyzed using the random-jump diffusion model. Both the average residence time and the mean jump distance increase with decreasing pore radius.

Bordallo, H. N.; Herwig, K. W.; Dozier, W. D.; Drake, F.

1999-12-09T23:59:59.000Z

293

Cocoa Butter and Related CompoundsChapter 17 Methods and Technologies Related to Shea Butter Chemophysical Properties and to the Delivery of Bioactives in Chocolate and Related Products  

Science Conference Proceedings (OSTI)

Cocoa Butter and Related Compounds Chapter 17 Methods and Technologies Related to Shea Butter Chemophysical Properties and to the Delivery of Bioactives in Chocolate and Related Products Food Science Health Nutrition eChapters Food Science

294

Nutritionally Enhanced Edible Oil and Oilseed ProcessingChapter 1 Oil and Oilseed-Based Bioactive Compounds and Their Health Effects  

Science Conference Proceedings (OSTI)

Nutritionally Enhanced Edible Oil and Oilseed Processing Chapter 1 Oil and Oilseed-Based Bioactive Compounds and Their Health Effects Processing eChapters Processing Press Downloadable pdf of Chapter 1 Oil and Oil

295

Omega-3 Oils: Applications in Functional FoodsChapter 8 Synergistic/Additive Health Effects of Fish Oil and Bio-Active Agents  

Science Conference Proceedings (OSTI)

Omega-3 Oils: Applications in Functional Foods Chapter 8 Synergistic/Additive Health Effects of Fish Oil and Bio-Active Agents Health Nutrition Biochemistry eChapters Health - Nutrition - Biochemistry Downloadable pdf...

296

DWPF Glass Melter Technology Manual: Volume 1  

Science Conference Proceedings (OSTI)

This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Site. Topics include: melter overview, design basis, materials, vessel configuration, insulation, refractory configuration, electrical isolation, electrodes, riser and pour spout heater design, dome heaters, feed tubes, drain valves, differential pressure pouring, and melter test results. Information is conveyed using many diagrams and photographs.

Iverson, D.C.

1993-12-31T23:59:59.000Z

297

Tandem SAM Domain Structure of Human Caskin1: A Presynaptic, Self-Assembling Scaffold for CASK  

Science Conference Proceedings (OSTI)

The synaptic scaffolding proteins CASK and Caskin1 are part of the fibrous mesh of proteins that organize the active zones of neural synapses. CASK binds to a region of Caskin1 called the CASK interaction domain (CID). Adjacent to the CID, Caskin1 contains two tandem sterile a motif (SAM) domains. Many SAM domains form polymers so they are good candidates for forming the fibrous structures seen in the active zone. We show here that the SAM domains of Caskin1 form a new type of SAM helical polymer. The Caskin1 polymer interface exhibits a remarkable segregation of charged residues, resulting in a high sensitivity to ionic strength in vitro. The Caskin1 polymers can be decorated with CASK proteins, illustrating how these proteins may work together to organize the cytomatrix in active zones.

Stafford, Ryan L.; Hinde, Elizabeth; Knight, Mary Jane; Pennella, Mario A.; Ear, Jason; Digman, Michelle A.; Gratton, Enrico; Bowie, James U. (UCI); (UCLA)

2012-02-07T23:59:59.000Z

298

Analysis and Research on the Thermal Properties of Energy-efficient Building Glass: A Case Study in PVB Laminated Glass  

E-Print Network (OSTI)

A new kind of PVB-laminated glass is introduced as an energy-efficient building glass. Based on tests and calculations of the shading coefficients of flat glass, LOW-E coated glass and PVB-laminated glass with different thickness, their effects on room base temperature and cooling load of the residential buildings in the hot-summer-warm-winter zone are simulated and analyzed. Compared with flat glass, the PVB laminated glass shields 44 percent of the solar radiation from entering the room and reduces 40 percent of the shading coefficient. At the same time, 28 percent of the cooling load, 21 percent of installed capacity and 8.6 percent of full-load operation time can be saved.

Chen, Z.; Meng, Q.

2006-01-01T23:59:59.000Z

299

Methods of making glass wool blowing insulation  

SciTech Connect

A process is described of making pieces of glass wool, suitable to be blown into attics as thermal insulation, from an elongated generally laminar resiliently compressible glass wool blanket having an original thickness in an unrestrained condition and made of glass fibers bonded with thermoset resin. The process comprises feeding the blanket longitudinally through a compressing station where it is resiliently compressed from its original thickness to a smaller thickness, and feeding the compressed blanket longitudinally between a rotating backup roll and a cooperative rotating cutting roll from one side of the rolls, the cutting roll including a supporting cylinder. A plywood blade-mounting cylinder is mounted on the supporting cylinder, circular cutting blades each have shank portions spaced from each other and disposed substantially completely around an inner periphery of the blade. Straight cutting blades have shank portions spaced from each other and disposed substantially completely along a length of the blade. Resiliently compressible plugs, the circular cutting blades respectively are separately mounted on the plywood cylinder circumferentially distributed substantially throughout the length spaced equally from each other axially by a distance smaller than the original thickness of the blanket, and having their shank portions mounted respectively in slits extending substantially all the way through a wall thickness of the plywood cylinder. The straight cutting blades respectively are separatedly mounted on the plywood cylinder axially distributed throughout the circumference.

Johnson, A.R.; Yawberg, R.C.

1987-07-28T23:59:59.000Z

300

Electrostatic transfer of epitaxial graphene to glass.  

SciTech Connect

We report on a scalable electrostatic process to transfer epitaxial graphene to arbitrary glass substrates, including Pyrex and Zerodur. This transfer process could enable wafer-level integration of graphene with structured and electronically-active substrates such as MEMS and CMOS. We will describe the electrostatic transfer method and will compare the properties of the transferred graphene with nominally-equivalent 'as-grown' epitaxial graphene on SiC. The electronic properties of the graphene will be measured using magnetoresistive, four-probe, and graphene field effect transistor geometries [1]. To begin, high-quality epitaxial graphene (mobility 14,000 cm2/Vs and domains >100 {micro}m2) is grown on SiC in an argon-mediated environment [2,3]. The electrostatic transfer then takes place through the application of a large electric field between the donor graphene sample (anode) and the heated acceptor glass substrate (cathode). Using this electrostatic technique, both patterned few-layer graphene from SiC(000-1) and chip-scale monolayer graphene from SiC(0001) are transferred to Pyrex and Zerodur substrates. Subsequent examination of the transferred graphene by Raman spectroscopy confirms that the graphene can be transferred without inducing defects. Furthermore, the strain inherent in epitaxial graphene on SiC(0001) is found to be partially relaxed after the transfer to the glass substrates.

Ohta, Taisuke; Pan, Wei; Howell, Stephen Wayne; Biedermann, Laura Butler; Beechem Iii, Thomas Edwin; Ross, Anthony Joseph, III

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Standard test method for determining liquidus temperature of immobilized waste glasses and simulated waste glasses  

E-Print Network (OSTI)

1.1 These practices cover procedures for determining the liquidus temperature (TL) of nuclear waste, mixed nuclear waste, simulated nuclear waste, or hazardous waste glass in the temperature range from 600°C to 1600°C. This method differs from Practice C829 in that it employs additional methods to determine TL. TL is useful in waste glass plant operation, glass formulation, and melter design to determine the minimum temperature that must be maintained in a waste glass melt to make sure that crystallization does not occur or is below a particular constraint, for example, 1 volume % crystallinity or T1%. As of now, many institutions studying waste and simulated waste vitrification are not in agreement regarding this constraint (1). 1.2 Three methods are included, differing in (1) the type of equipment available to the analyst (that is, type of furnace and characterization equipment), (2) the quantity of glass available to the analyst, (3) the precision and accuracy desired for the measurement, and (4) candi...

American Society for Testing and Materials. Philadelphia

2011-01-01T23:59:59.000Z

302

High-Intensity Plasma Glass Melter Final Technical Report  

Science Conference Proceedings (OSTI)

The purpose of this project was to demonstrate the energy efficiency and reduced emissions that can be obtained with a dual torch DC plasma transferred arc-melting system. Plasmelt Glass Technologies, LLC was formed to solicit and execute the project, which utilize a full-scale test melter system. The system is similar to the one that was originally constructed by Johns Manville, but Plasmelt has added significant improvements to the torch design and melter system that has extended the original JM short torch lives. The original JM design has been shown to achieve melt rates 5 to 10 times faster than conventional gas or electric melting, with improved energy efficiency and reduced emissions. This project began on 7/28/2003 and ended 7/27/06. A laboratory scale melter was designed, constructed, and operated to conduct multiple experimental melting trials on various glass compositions. Glass quality was assessed. Although the melter design is generic and equally applicable to all sectors within the glass industry, the development of this melter has focused primarily on fiberglass with additional exploratory melting trials of frits, specialty, and minerals-melting applications. Throughput, energy efficiency, and glass quality have been shown to be heavily dependent on the selected glass composition. During this project, Plasmelt completed the proof-of-concept work in our Boulder, CO Lab to show the technical feasibility of this transferred-arc plasma melter. Late in the project, the work was focused on developing the processes and evaluating the economic viability of plasma melting aimed at the specific glasses of interest to specific client companies. Post project work is on going with client companies to address broader non-glass materials such as refractories and industrial minerals. Exploratory melting trials have been conducted on several glasses of commercial interest including: C-glass, E-glass, S-Glass, AR-Glass, B-glass, Lighting Glass, NE-Glass, and various frits. Exploratory melts of non-glassy materials, such as wollastonite, zirconium silicate, and alumino-silicate melts were successfully done indicating that plasma melting has potential application beyond glass. Experimental results were generated that show the high quality of plasma-melted fiberglass compositions, such as E-glass, can result in good fiberizing performance. Fiberizing performance and tensile strength data were achieved during the project to support this conclusion. High seed counts are a feature of the current lab scale melter and must be dealt with via other means, since fining work was outside the scope of this project.

Gonterman, J. Ronald; Weinstein, Michael A.

2006-10-27T23:59:59.000Z

303

Correlation of Atomic Cluster Symmetry and Glass-Forming Ability of Metallic Glass  

SciTech Connect

Local structures play a crucial role in glass formation and properties. In addition to topological short-range order, the geometric property of site symmetry is another important but less known characteristic of local structures. It is shown that the observed sharp increase of glass forming ability of Ce{sub 70-x}Al{sub 10}Cu{sub 20}Co{sub x} upon Co addition is correlated with a dramatic increase of Al site symmetry, as reflected by decreasing quadrupole frequency measured by {sup 27}Al NMR. The result is consistent with the structure model of Al-centered icosahedral clusters as the predominant structural building blocks.

Xi Xuekui; Li Lilong; Wu Yue [Department of Physics and Astronomy and Curriculum in Applied and Materials Sciences, University of North Carolina, Chapel Hill, North Carolina 27599-3255 (United States); Zhang Bo; Wang Weihua [Institute of Physics, Chinese Academy of Sciences, Beijing 100080 (China)

2007-08-31T23:59:59.000Z

304

Tiny Glass Bubbles With Big Potential | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Tiny Glass Bubbles With Big Potential Tiny Glass Bubbles With Big Potential Tiny Glass Bubbles With Big Potential August 19, 2011 - 12:32pm Addthis SRNL's Porous Walled Hollow Glass Microspheres (which are about half the width of a human hair in diameter) have a network of interconnected pores that enable them to be filled with, hold and release gases and other materials. | Image courtesy of SRNL SRNL's Porous Walled Hollow Glass Microspheres (which are about half the width of a human hair in diameter) have a network of interconnected pores that enable them to be filled with, hold and release gases and other materials. | Image courtesy of SRNL Liisa O'Neill Liisa O'Neill Former New Media Specialist, Office of Public Affairs What are the key facts? SRNL's porous walled glass microspheres allow the potential for

305

Decontamination of DWPF canisters by glass frit blasting  

SciTech Connect

High-level radioactive waste at the Savannah River Plant will be incorporated in borosilicate glass for permanent disposal. The waste glass will be encapsulated in a 304L stainless steel canister. During the filling operation the outside of the canister will become contaminated. This contamination must be reduced to an accepable level before the canister leaves the Defense Waste Processing Facility (DWPF). Tests with contaminated coupons have demonstrated that this decontamination can be accomplished by blasting the surface with glass frit. The contaminated glass frit byproduct of this operation is used as a feedstock for the waste glass process, so no secondary waste is created. Three blasting techniques, using glass frit as the blasting medium, were evaluated. Air-injected slurry blasting was the most promising and was chosen for further development. The optimum parametric values for this process were determined in tests using coupon weight loss as the output parameter. 1 reference, 13 figures, 3 tables.

Ward, C.R.; Rankin, W.N.

1984-01-01T23:59:59.000Z

306

Improving Glass Walls Thermal Resistance In Air-Conditioned Buildings  

E-Print Network (OSTI)

The solar radiation through an air conditioned building depends on what is called the building envelope. Building envelope consists of the surfaces that separate the inside from the building outdoors. Area, direction, and specifications of glass walls; as one of envelope surfaces; has an important impact on solar radiation. Design and construction of glass walls have significant effects on building comfort and energy consumption. This paper describes methods of improving glass walls thermal resistance in air conditioned buildings. Effect of glass wall radiation temperature on the indoor temperature distribution of building rooms is also investigated. Heat gain through various types of glass is discussed. Optimization and testing of these types are carried out theoretically and experimentally as well. A series of experiments on different types of glass with special strips is performed.

Galal, T.; Kulaib, A. M.; Alajmi, R.; Al-Ansary. A; Abuzaid, M.

2010-01-01T23:59:59.000Z

307

EMPIRICAL MODEL FOR FORMULATION OF CRYSTAL-TOLERANT HLW GLASSES  

Science Conference Proceedings (OSTI)

Historically, high-level waste (HLW) glasses have been formulated with a low liquideus temperature (T{sub L}), or temperature at which the equilibrium fraction of spinel crystals in the melt is below 1 vol % (T{sub 0.01}), nominally below 1050 C. These constraints cannot prevent the accumulation of large spinel crystals in considerably cooler regions ({approx} 850 C) of the glass discharge riser during melter idling and significantly limit the waste loading, which is reflected in a high volume of waste glass, and would result in high capital, production, and disposal costs. A developed empirical model predicts crystal accumulation in the riser of the melter as a function of concentration of spinel-forming components in glass, and thereby provides guidance in formulating crystal-tolerant glasses that would allow high waste loadings by keeping the spinel crystals small and therefore suspended in the glass.

KRUGER AA; MATYAS J; HUCKLEBERRY AR; VIENNA JD; RODRIGUEZ CA

2012-03-07T23:59:59.000Z

308

Method for forming glass-to-metal seals  

SciTech Connect

A method for forming a glass-to-metal seal in which the glass has a higher melting point than the metal. The molten glass is vacuum injection molded onto the metal, thus melting a very thin layer of the surface of the metal long enough to form a seal, but not long enough to cause a distortion in the shape of the metal component.

Kramer, Daniel P. (Dayton, OH); Massey, Richard T. (Hamilton, OH)

1986-01-01T23:59:59.000Z

309

Using sputter coated glass to stabilize microstrip gas chambers  

DOE Patents (OSTI)

By sputter coating a thin-layer of low-resistive, electronically-conductive glass on various substrates (including quartz and ceramics, thin-film Pestov glass), microstrip gas chambers (MSGC) of high gain stability, low leakage current, and a high rate capability can be fabricated. This design can make the choice of substrate less important, save the cost of ion-implantation, and use less glass material.

Gong, Wen G. (Albany, CA)

1997-01-01T23:59:59.000Z

310

Graded index antireflective coatings for glass. Second annual report  

SciTech Connect

M.I.T. is conducting research which will lead to a process for forming broad band antireflective (AR) coatings on glass. Use of these coatings increases the extractable heat from flat-plate solar collectors by 30 to 50% compared with their performance under equivalent solar flux, surface temperature and ambient conditions without broad band AR coatings. Graded index surface films can virtually eliminate reflection losses if controlled properly. Graded index films on a borosilicate glass (Corning Glass Works No. 7740, Pyrex) has been demonstrated. While glass treated this way exhibited adequate optical properties, the glass itself, cannot be fabricated by the float glass process because of excessive working temperatures, and consequently is too expensive for solar applications. The objective of this work is to define glass compositions and processing steps which will result in graded index surface films (which exhibit broad band AR characteristics) on glasses which can be fabricated by the float glass process. The mechanism by which these graded index surface films are produced on glass surfaces consists of preferentially etching one phase from a phase separated glass. The film which remains consists of a porous structure in which the fraction of solid phase increases continuously from the free surface toward the bulk glass. Scattering effects are eliminated by limiting the size of the pore structure to dimensions which are substantially less than the wavelength of light. With this structure, the local index of refraction is proportional to the fraction of solid phase which is present. Characterizations are intended to define the microstructural and chemical nature of the surface film throughout its thickness. Progress is reported. (WHK)

Haggerty, J.S.

1980-05-01T23:59:59.000Z

311

Formulation and Characterization of Waste Glasses with Varying Processing Temperature  

Science Conference Proceedings (OSTI)

This report documents the preliminary results of glass formulation and characterization accomplished within the finished scope of the EM-31 technology development tasks for WP-4 and WP-5, including WP-4.1.2: Glass Formulation for Next Generation Melter, WP-5.1.2.3: Systematic Glass Studies, and WP-5.1.2.4: Glass Formulation for Specific Wastes. This report also presents the suggested studies for eventual restart of these tasks. The initial glass formulation efforts for the cold crucible induction melter (CCIM), operating at {approx}1200 C, with selected HLW (AZ-101) and LAW (AN-105) successfully developed glasses with significant increase of waste loading compared to that is likely to be achieved based on expected reference WTP formulations. Three glasses formulated for AZ-101HLW and one glass for AN-105 LAW were selected for the initial CCIM demonstration melter tests. Melter tests were not performed within the finished scope of the WP-4.1.2 task. Glass formulations for CCIM were expanded to cover additional HLWs that have high potential to successfully demonstrate the unique advantages of the CCIM technologies based on projected composition of Hanford wastes. However, only the preliminary scoping tests were completed with selected wastes within the finished scope. Advanced glass formulations for the reference WTP melter, operating at {approx}1200 C, were initiated with selected specific wastes to determine the estimated maximum waste loading. The incomplete results from these initial formulation efforts are summarized. For systematic glass studies, a test matrix of 32 high-aluminum glasses was completed based on a new method developed in this study.

Kim, Dong-Sang; Schweiger, M. J.; Rodriguez, Carmen P.; Lepry, William C.; Lang, Jesse B.; Crum, Jarrod V.; Vienna, John D.; Johnson, Fabienne; Marra, James C.; Peeler, David K.

2011-10-17T23:59:59.000Z

312

Low temperature process for obtaining thin glass films  

DOE Patents (OSTI)

A method for coating a substrate with a glass-like film comprises, applying to the substrate an aqueous alcoholic solution containing a polymeric network of partially hydrolyzed metal alkoxide into which network there is incorporated finely powdered glass, whereby there is achieved on the substrate a coherent and adherent initial film; and heating said film to a temperature sufficient to melt said powdered glass component, thereby converting said initial film to a final densified film.

Brinker, C. Jeffrey (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM)

1984-01-01T23:59:59.000Z

313

Aging, Fragility and Reversibility Window in Bulk Alloy Glasses  

E-Print Network (OSTI)

Non-reversing relaxation enthalpies (DHnr) at glass transitions Tg(x) in the PxGexSe1-2x ternary display wide, sharp and deep global minima (~ 0) in the 0.09 age, in contrast to aging observed for fragile glass compositions outside the window. Thermal reversibility and lack of aging seem to be paradigms of self-organization which molecular glasses share with protein structures which repetitively and reversibly change conformation near Tg and the folding temperature respectively.

S. Chakravarty; D. G. Georgiev; P. Boolchand; M. Micoulaut

2007-09-27T23:59:59.000Z

314

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Materials Advanced Materials Adjustably Inducing Biaxial Strain in Thin Films Bone Replacement and Dental Materials Flexibone: Osteo-mimetic Composites Graded Bioactive Glass and Glass/Ceramic Coatings for Metal Bone Implants Injectable Hydrogel-Based Biodegradable Bone Replacement Materials Mineralization of Biocompatible Scaffolds Peptides for the Controllable Promotion or Inhibition of Bone Growth Remineralization and Repair of Calcified Tissues Using Biomimetic Polymer Boron Nitride Converted Carbon Fibers Catalysts for Reduction of SO2 to Elemental Sulfur Catalyst Exchanges Deuterium or Tritium into Organic and Organometallic Compounds Direct Thin Film Path to Low Cost, Large Area III-V Photovoltaics Easily Assembled Porous Thin Films Full Spectrum Semiconducting Material for Affordable, Highly

315

Optical Spectroscopy of Borate Glasses Doped with Trivalent Rare ...  

Science Conference Proceedings (OSTI)

Luminescence properties of rare-earth ions are well-known, but quantum efficiencies ... Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and ...

316

Glass Ceramic Waste Form Development for Fission Products from ...  

Science Conference Proceedings (OSTI)

Symposium, Materials Issues in Nuclear Waste Management in the 21st Century. Presentation Title, Glass Ceramic Waste Form Development for Fission ...

317

Glass Does a Double-Take | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Highlights rss feed Glass Does a Double-Take APRIL 4, 2008 Bookmark and Share Predicted phase diagram as a function of reduced temperature () and volume fraction (). Inset...

318

Metallic Glasses for Electro-Catalytic Applications - Programmaster.org  

Science Conference Proceedings (OSTI)

Motivated by these characteristics, we have explored the use of a number of metallic glasses as electro-catalysts in direct alcohol fuel cells. We demonstrate that ...

319

LBNL-5022E Research Needs: Glass Solar Reflectance and Vinyl...  

NLE Websites -- All DOE Office Websites (Extended Search)

022E Research Needs: Glass Solar Reflectance and Vinyl Siding Authors: R. Hart*, C. Curcija, D. Arasteh, H. Goudey, C. Kohler, S. Selkowitz Environmental Energy Technologies...

320

Characterization of Fluorescent Lamp Glass Waste Powders for ...  

Science Conference Proceedings (OSTI)

The glass waste presents favorable characteristics for incorporation into clayey ceramic ... Codin, Located in Campos (RJ), to Produce Soil-Cement Blocks.

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Welding/sealing glass-enclosed space in a vacuum  

DOE Patents (OSTI)

A method of welding and sealing the edges of two juxtaposed glass sheets together to seal a vacuum space between the sheets comprises the steps of positioning a radiation absorbent material, such as FeO, VO{sub 2}, or NiO, between the radiation transmissive glass sheets adjacent the edges and then irradiating the absorbent material, preferably with a laser beam, through at least one of the glass sheets. Heat produced by the absorbed radiation in the absorbent material melts glass in the portions of both glass sheets that are adjacent the absorbent material, and the melted glass from both sheets flows together to create the weld when the melted glass cools and hardens. The absorbent material can be dissolved and diffused into the melted glass to the extent that it no longer absorbs enough energy to keep the glass melted, thus, with appropriate proportioning of absorbent material to source energy power and welding heat needed, the process can be made self-stopping. 8 figs.

Tracy, C.E.; Benson, D.K.

1996-02-06T23:59:59.000Z

322

047 Glass-Ceramic Composites for High Energy Density Capacitors  

Science Conference Proceedings (OSTI)

047 Glass-Ceramic Composites for High Energy Density Capacitors .... 150 Analysis of Hf-Ta Alloys for Oxidation Protection in Ultra High Temperature ...

323

Research Needs: Glass Solar Reflectance and Vinyl Siding  

E-Print Network (OSTI)

properties of reflected solar radiation from glass surfaces,transfer at the siding surface. Direct solar radiation tosiding, reflected solar radiation from nearby surfaces,

Hart, Robert

2012-01-01T23:59:59.000Z

324

Atomic Structure and its Change during Glass Transition of Metallic ...  

Science Conference Proceedings (OSTI)

In addition, we will discuss how the atomic structure evolves during glass transition ... Age Hardening of 7075 Alloy Processed by High-pressure Sliding ( HPS).

325

Welding/sealing glass-enclosed space in a vacuum  

SciTech Connect

A method of welding and sealing the edges of two juxtaposed glass sheets together to seal a vacuum space between the sheets comprises the steps of positioning a radiation absorbant material, such as FeO, VO.sub.2, or NiO, between the radiation transmissive glass sheets adjacent the edges and then irradiating the absorbant material, preferably with a laser beam, through at least one of the glass sheets. Heat produced by the absorbed radiation in the absorbant material melts glass in the portions of both glass sheets that are adjacent the absorbant material, and the melted glass from both sheets flows together to create the weld when the melted glass cools and hardens. The absorbant material can be dissolved and diffused into the melted glass to the extent that it no longer absorbs enough energy to keep the glass melted, thus, with appropriate proportioning of absorbant material to source energy power and welding heat needed, the process can be made self-stopping.

Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO)

1996-01-01T23:59:59.000Z

326

Edge-Strength of Thin Chemically Strengthened Glass  

Science Conference Proceedings (OSTI)

Structure and Transport Properties of Nanoconfined Water in Porous Silica and Water-Glass ... on the Mechanical and Optical Properties of Multiphase Ceramics.

327

Nano/Micro Vacuum Triodes Using Glass Fiber Drawing Methods  

Nano/Micro Vacuum Triodes Using Glass Fiber Drawing Methods Note: The technology described above is an early stage opportunity. Licensing rights to this intellectual ...

328

Electrical Properties and Glasses for Energy and Memory Applications  

Science Conference Proceedings (OSTI)

Oct 9, 2012 ... Terahertz Properties of Lithium Iron Phosphate Glasses: Robert ... to form a viscous, gas-tight, and stress-free sealing layer during the cell ...

329

Potential for energy conservation in the glass industry  

SciTech Connect

While the glass industry (flat glass, container glass, pressed and blown glass, and insulation fiber glass) has reduced its specific energy use (Btu/ton) by almost 30% since 1972, significant potential for further reduction still remains. State-of-the-art technologies are available which could lead to incremental improvements in glass industry energy productivity; however, these technologies must compete for capital with projects undertaken for other reasons (e.g., capacity expansion, equipment rebuild, labor cost reduction, product quality improvement, or compliance with environmental, health or safety regulations). Narrowing profit margins in the large tonnage segments of the glass industry in recent years and the fact that energy costs represent less than 25% of the value added in glass manufacture have combined to impede the widespread adoption of many state-of-the-art conservation technologies. Savings in energy costs alone have not provided the incentive to justify the capital expenditures required to realize the energy savings. Beyond implementation of state-of-the-art technologies, significant potential energy savings could accrue from advanced technologies which represent a radical departure from current glass making technology. Long-term research and development (R and D) programs, which address the technical and economic barriers associated with advanced, energy-conserving technologies, offer the opportunity to realize this energy-saving potential.

Garrett-Price, B.A.; Fassbender, A.G.; Bruno, G.A.

1986-06-01T23:59:59.000Z

330

Molecular Dynamics Simulation of Cavitation in Metallic Glass  

Science Conference Proceedings (OSTI)

We have undertaken a series of molecular dynamics simulations of cavitation under hydrostatic tension in a binary metallic glass analog using pair-wise ...

331

High-Speed Fracture Phenomena of Glass Bottle by Underwater ...  

Science Conference Proceedings (OSTI)

Presentation Title, High-Speed Fracture Phenomena of Glass Bottle by Underwater Shock Wave. Author(s), Hidetoshi Sakamoto, Shinjirou Kawabe, Yoshifumi ...

332

Vitrification of DOE Problematic Wastes Using Iron Phosphate Glasses  

Science Conference Proceedings (OSTI)

Abstract Scope, This work is to formulate and optimize iron phosphate glass compositions which are suitable for vitrifying several specified Hanford HLW and  ...

333

Borosilicate Glass Formulations for Advanced Joule Heated Melters  

Summary – Hanford High Cr/S HLW • Selected formulations have waste loadings of 40 and 45 wt% • ~23 – 38% increase over previous glass formulations

334

Glass fiber composition. [for use as thermal insulation  

DOE Patents (OSTI)

The invention relates to a glass fiber composition useful for thermal insulation having a low melting temperature and high chemical durability.

Wolf, G.A.; Kupfer, M.J.

1980-12-19T23:59:59.000Z

335

In Situ Structural Characterization for Metallic Glasses and Nano ...  

Science Conference Proceedings (OSTI)

Presentation Title, In Situ Structural Characterization for Metallic Glasses and Nano-materials under High Pressure via Synchrotron Techniques. Author(s) ...

336

Vitrification and Glass Characterization for Nuclear Materials Disposal  

Science Conference Proceedings (OSTI)

Oct 20, 2011 ... One significant limitation to waste loading in glass for Hanford .... to the high level sludge vitrified at the Defense Waste Processing Facility.

337

Interaction-Flip Identities in Spin Glasses  

E-Print Network (OSTI)

We study the properties of fluctuation for the free energies and internal energies of two spin glass systems that differ for having some set of interactions flipped. We show that their difference has a variance that grows like the volume of the flipped region. Using a new interpolation method, which extends to the entire circle the standard interpolation technique, we show by integration by parts that the bound imply new overlap identities for the equilibrium state. As a side result the case of the non-interacting random field is analyzed and the triviality of its overlap distribution proved.

Pierluigi Contucci; Cristian Giardina; Claudio Giberti

2008-11-15T23:59:59.000Z

338

Molten Glass for Thermal Storage: Advanced Molten Glass for Heat Transfer and Thermal Energy Storage  

Science Conference Proceedings (OSTI)

HEATS Project: Halotechnics is developing a high-temperature thermal energy storage system using a new thermal-storage and heat-transfer material: earth-abundant and low-melting-point molten glass. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night—when the sun is not out—to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. Halotechnics new thermal storage material targets a price that is potentially cheaper than the molten salt used in most commercial solar thermal storage systems today. It is also extremely stable at temperatures up to 1200°C—hundreds of degrees hotter than the highest temperature molten salt can handle. Being able to function at high temperatures will significantly increase the efficiency of turning heat into electricity. Halotechnics is developing a scalable system to pump, heat, store, and discharge the molten glass. The company is leveraging technology used in the modern glass industry, which has decades of experience handling molten glass.

None

2012-01-01T23:59:59.000Z

339

A comparison of glass reaction at high and low glass surface/solution volume  

SciTech Connect

Static leach tests have been performed at glass surface area/leachant volume (SA/V) ratios of 10, 340, 2,000, and 20,000 m[sup [minus]1] to assess the effects of the SA/V on the mechanism and rate of the glass reaction. Tests were performed using actinide-doped borosilicate waste glasses [Savannah River Laboratory (SRL) 131 and SRL 202] to monitor the distribution of released radionuclides in tests at different SA/V. Solution results show the major effect of the SA/V to be dilution of reaction of products. Differences in the pH and silicic acid concentrations attained in tests at different SA/V then affect the reaction rate. Tests at low SA/V maintain leachate pH values similar to the initial leachant, while tests at higher SA/V result in higher leachate pH values being attained due to ion-exchange reactions. Transuranics released as the glass corrodes may exist in the leachate in concentrations far above their solubility limits by sorbing onto colloids, although the colloids may eventually settle out of solution. Transuranics also sorb onto the steel reaction vessel. The glass reaction progress can be characterized by three stages: (a) an initial stage where the reaction rate depends on the leachant pH, (b) an intermediate stage where the reaction slows toward a minimum rate as the leachate solution approaches saturation,'' and (c) a long-term stage where the reaction rate may be affected by the formation of secondary phases that control the solution chemistry. Tests at different SA/V cannot always be compared directly because the dominant reaction step and the observed reaction stage (initial, intermediate, or long-term) may not be the same.

Ebert, W.L.; Bates, J.K. (Argonne National Lab., IL (United States))

1993-12-01T23:59:59.000Z

340

Direct observation of a magnetic Bose glass  

Science Conference Proceedings (OSTI)

A Bose glass is a novel state of matter that emerges in systems of interacting bosons in the presence of quenched disorder. At sufficiently low temperatures, disorder-free bosons are subject to so-called Bose-Einstein condensation (BEC). BEC can involve atoms in liquid 4He, laser-cooled ions in magnetic traps,2 Cooper pairs in superconductors, or magnons in magnetic systems. Due to peculiarities of Bose statistics, particles lose their individuality and occupy a unique quantum-mechanical state. The wave function of this condensate establishes long-range quantum phase coherence across a macroscopic sample. This, in turn, spawns unique quantum phenomena such as superfluity,5 Josephson effect6 and vortex matter. For repulsive bosons, quenched disorder disrupts the condensate and interferes with phase coherence. The result is a peculiar glassy state with only short-range phase correlations. While some experimental evidence of this was found in ultracold atoms,9 novel high-temperature superconductors,10 and quantum magnets,11, 12 none of the studies were direct. The key characteristic, namely the wave function of the condensate disrupted by disorder on the microscopic scale, remained inaccessible. Hereby we report a direct neutron diffraction observation of short range correlations of the BEC order parameter in a magnetic Bose glass. This phase is realized in the quantum spin ladder compound IPA-Cu(Cl0.96Br0.04)3, where disorder is induced by random chemical substitution.

Hong, Tao [ORNL; Zheludev, Andrey I [ORNL; Manaka, H. [Kagoshima University, Kagoshima JAPAN; Regnault, L.-P. [CEA, Grenoble, France

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Glass Mountain Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Glass Mountain Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Glass Mountain Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (2) 9 Exploration Activities (3) 10 References Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"TERRAIN","zoom":6,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"500px","height":"300px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.7,"lon":-121.45,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

342

Reduction of Glass Surface Reflectance by Ion Beam Surface Modification  

DOE Green Energy (OSTI)

This is the final report for DOE contract DE-EE0000590. The purpose of this work was to determine the feasibility of the reduction of the reflection from the front of solar photovoltaic modules. Reflection accounts for a power loss of approximately 4%. A solar module having an area of one square meter with an energy conversion efficiency of 18% generates approximately 180 watts. If reflection loss can be eliminated, the power output can be increased to 187 watts. Since conventional thin-film anti-reflection coatings do not have sufficient environmental stability, we investigated the feasibility of ion beam modification of the glass surface to obtain reduction of reflectance. Our findings are generally applicable to all solar modules that use glass encapsulation, as well as commercial float glass used in windows and other applications. Ion implantation of argon, fluorine, and xenon into commercial low-iron soda lime float glass, standard float glass, and borosilicate glass was studied by implantation, annealing, and measurement of reflectance. The three ions all affected reflectance. The most significant change was obtained by argon implantation into both low-iron and standard soda-lime glass. In this way samples were formed with reflectance lower than can be obtained with a single-layer coatings of magnesium fluoride. Integrated reflectance was reduced from 4% to 1% in low-iron soda lime glass typical of the glass used in solar modules. The reduction of reflectance of borosilicate glass was not as large; however borosilicate glass is not typically used in flat plate solar modules. Unlike conventional semiconductor ion implantation doping, glass reflectance reduction was found to be tolerant to large variations in implant dose, meaning that the process does not require high dopant uniformity. Additionally, glass implantation does not require mass analysis. Simple, high current ion implantation equipment can be developed for this process; however, before the process can be employed on full scale solar modules, equipment must be developed for ion implanting large sheets of glass. A cost analysis shows that the process can be economical. Our finding is that the reduction of reflectance by ion beam surface modification is technically and economically feasible. The public will benefit directly from this work by the improvement of photovoltaic module efficiency, and indirectly by the greater understanding of the modification of glass surfaces by ion beams.

Mark Spitzer

2011-03-11T23:59:59.000Z

343

Initial Examination of Low Velocity Sphere Impact of Glass Ceramics  

Science Conference Proceedings (OSTI)

This report summarizes US Army TARDEC sponsored work at Oak Ridge National Laboratory (ORNL) involving low velocity (energy of impact and the elastic property mismatch between sphere and target material. Quasistatic spherical indentation was also performed on both glass ceramics and their contact damage responses were compared to those of soda-lime silicate and borosilicate glasses. Lastly, variability of contact damage response was assessed by performing spherical indentation testing across the area of an entire glass ceramic tile. The primary observations from this low velocity (< 30 m/s or < 65 mph) testing were: (1) Resistan{trademark}-L glass ceramic required the highest velocity of sphere impact for damage to initiate. Starphire{reg_sign} soda-lime silicate glass was second best, then Resistan{trademark}-G1 glass ceramic, and then BOROFLOAT{reg_sign} borosilicate glass. (2) Glass-ceramic Resistan{trademark}-L also required the largest force to initiate ring crack from quasi-static indentation. That ranking was followed, in descending order, by Starphire{reg_sign} soda-lime silicate glass, Resistan{trademark}-G1 glass ceramic, and BOROFLOAT{reg_sign} borosilicate glass. (3) Spheres with a lower elastic modulus require less force to initiate fracture in Resistan{trademark}-G1 from quasi-static spherical indentation. This indicates that friction is affecting ring crack initiation in Resistan{trademark}-G1. Friction also affected ring crack initiation in Starphire{reg_sign} soda-lime silicate and BOROFLOAT{reg_sign} borosilicate glasses. Among these three materials, friction was the most pronounced (largest slope in the RCIF-elastic modulus graph) in the Starphire{reg_sign} and least pronounced in the BOROFLOAT{reg_sign}. The reason for this is not understood, but differences in deformation behavior under high contact stresses could be a cause or contributor to this. (4) The force necessary to initiate contact-induced fracture is higher under dynamic conditions than it is under quasi-static conditions in Resistan{trademark}-L and Resistan{trademark}-G1 glass ceramics. This is a trend observed too in Starphire{reg_sign} and BOROFLOAT{reg_sign}. (5) There is a subtle indication there was intra-tile differences in spherical indentation-induced ring crack initiation forces. This is not a material property nor is it exclusive to glass-ceramic Resistan{trademark}-G1 glass ceramic, rather, it is a statistical mechanical response to an accumulated history of processing and handling of that specific tile.

Morrissey, Timothy G [ORNL; Fox, Ethan E [ORNL; Wereszczak, Andrew A [ORNL; Ferber, Mattison K [ORNL

2012-06-01T23:59:59.000Z

344

Optical Basicity and Nepheline Crystallization in High Alumina Glasses  

SciTech Connect

The purpose of this study was to find compositions that increase waste loading of high-alumina wastes beyond what is currently acceptable while avoiding crystallization of nepheline (NaAlSiO4) on slow cooling. Nepheline crystallization has been shown to have a large impact on the chemical durability of high-level waste glasses. It was hypothesized that there would be some composition regions where high-alumina would not result in nepheline crystal production, compositions not currently allowed by the nepheline discriminator. Optical basicity (OB) and the nepheline discriminator (ND) are two ways of describing a given complex glass composition. This report presents the theoretical and experimental basis for these models. They are being studied together in a quadrant system as metrics to explore nepheline crystallization and chemical durability as a function of waste glass composition. These metrics were calculated for glasses with existing data and also for theoretical glasses to explore nepheline formation in Quadrant IV (passes OB metric but fails ND metric), where glasses are presumed to have good chemical durability. Several of these compositions were chosen, and glasses were made to fill poorly represented regions in Quadrant IV. To evaluate nepheline formation and chemical durability of these glasses, quantitative X-ray diffraction (XRD) analysis and the Product Consistency Test were conducted. A large amount of quantitative XRD data is collected here, both from new glasses and from glasses of previous studies that had not previously performed quantitative XRD on the phase assemblage. Appendix A critically discusses a large dataset to be considered for future quantitative studies on nepheline formation in glass. Appendix B provides a theoretical justification for choice of the oxide coefficients used to compute the OB criterion for nepheline formation.

Rodriguez, Carmen P.; McCloy, John S.; Schweiger, M. J.; Crum, Jarrod V.; Winschell, Abigail E.

2011-02-25T23:59:59.000Z

345

Initial Examination of Low Velocity Sphere Impact of Glass Ceramics  

SciTech Connect

This report summarizes US Army TARDEC sponsored work at Oak Ridge National Laboratory (ORNL) involving low velocity (< 30 m/s or < 65 mph) sphere impact testing of two materials from the lithium aluminosilicate family reinforced with different amounts of ceramic particulate, i.e., glass-ceramic materials, SCHOTT Resistan{trademark}-G1 and SCHOTT Resistan{trademark}-L. Both materials are provided by SCHOTT Glass (Duryea, PA). This work is a follow-up to similar sphere impact studies completed by the authors on PPG's Starphire{reg_sign} soda-lime silicate glass and SCHOTT BOROFLOAT{reg_sign} borosilicate glass. A gas gun or a sphere-drop test setup was used to produce controlled velocity delivery of silicon nitride (Si{sub 3}N{sub 4}) spheres against the glass ceramic tile targets. Minimum impact velocities to initiate fracture in the glass-ceramics were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between sphere and target material. Quasistatic spherical indentation was also performed on both glass ceramics and their contact damage responses were compared to those of soda-lime silicate and borosilicate glasses. Lastly, variability of contact damage response was assessed by performing spherical indentation testing across the area of an entire glass ceramic tile. The primary observations from this low velocity (< 30 m/s or < 65 mph) testing were: (1) Resistan{trademark}-L glass ceramic required the highest velocity of sphere impact for damage to initiate. Starphire{reg_sign} soda-lime silicate glass was second best, then Resistan{trademark}-G1 glass ceramic, and then BOROFLOAT{reg_sign} borosilicate glass. (2) Glass-ceramic Resistan{trademark}-L also required the largest force to initiate ring crack from quasi-static indentation. That ranking was followed, in descending order, by Starphire{reg_sign} soda-lime silicate glass, Resistan{trademark}-G1 glass ceramic, and BOROFLOAT{reg_sign} borosilicate glass. (3) Spheres with a lower elastic modulus require less force to initiate fracture in Resistan{trademark}-G1 from quasi-static spherical indentation. This indicates that friction is affecting ring crack initiation in Resistan{trademark}-G1. Friction also affected ring crack initiation in Starphire{reg_sign} soda-lime silicate and BOROFLOAT{reg_sign} borosilicate glasses. Among these three materials, friction was the most pronounced (largest slope in the RCIF-elastic modulus graph) in the Starphire{reg_sign} and least pronounced in the BOROFLOAT{reg_sign}. The reason for this is not understood, but differences in deformation behavior under high contact stresses could be a cause or contributor to this. (4) The force necessary to initiate contact-induced fracture is higher under dynamic conditions than it is under quasi-static conditions in Resistan{trademark}-L and Resistan{trademark}-G1 glass ceramics. This is a trend observed too in Starphire{reg_sign} and BOROFLOAT{reg_sign}. (5) There is a subtle indication there was intra-tile differences in spherical indentation-induced ring crack initiation forces. This is not a material property nor is it exclusive to glass-ceramic Resistan{trademark}-G1 glass ceramic, rather, it is a statistical mechanical response to an accumulated history of processing and handling of that specific tile.

Morrissey, Timothy G [ORNL; Fox, Ethan E [ORNL; Wereszczak, Andrew A [ORNL; Ferber, Mattison K [ORNL

2012-06-01T23:59:59.000Z

346

ANOMALOUS ELECTRON PRODUCTION IN THE LEAD-GLASS WALL EXPERIMENT AT SPEAR  

E-Print Network (OSTI)

x 19 array of lea,J-glass "back-block counters" (BB), 10.Sdeposited in the lead-glass back blocks (ESS) is (Thisactive converter (baelblock) lead-glass counter was viewed

Madaras, R.J.

2010-01-01T23:59:59.000Z

347

Glass Formation and Phase Equilibria Studies in the TeO 2 -ZnO ...  

Science Conference Proceedings (OSTI)

Meeting, Materials Science & Technology 2013. Symposium, Glass and ... Glass Formation of LaTiZrO System by Containerless Processing ... Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and Natural Gas Bearing Shales.

348

Assessment, development, and testing of glass for blast environments.  

SciTech Connect

Glass can have lethal effects including fatalities and injuries when it breaks and then flies through the air under blast loading (''the glass problem''). One goal of this program was to assess the glass problem and solutions being pursued to mitigate it. One solution to the problem is the development of new glass technology that allows the strength and fragmentation to be controlled or selected depending on the blast performance specifications. For example the glass could be weak and fail, or it could be strong and survive, but it must perform reliably. Also, once it fails it should produce fragments of a controlled size. Under certain circumstances it may be beneficial to have very small fragments, in others it may be beneficial to have large fragments that stay together. The second goal of this program was to evaluate the performance (strength, reliability, and fragmentation) of Engineered Stress Profile (ESP) glass under different loading conditions. These included pseudo-static strength and pressure tests and free-field blast tests. The ultimate goal was to provide engineers and architects with a glass whose behavior under blast loading is less lethal. A near-term benefit is a new approach for improving the reliability of glass and modifying its fracture behavior.

Glass, Sarah Jill

2003-06-01T23:59:59.000Z

349

Thermodynamics and Universality for Mean Field Quantum Spin Glasses  

E-Print Network (OSTI)

We study aspects of the thermodynamics of quantum versions of spin glasses. By means of the Lie-Trotter formula for exponential sums of operators, we adapt methods used to analyze classical spin glass models to answer analogous questions about quantum models.

Nick Crawford

2006-10-13T23:59:59.000Z

350

Solubility effects in waste-glass/demineralized-water systems  

SciTech Connect

Aqueous systems involving demineralized water and four glass compositions (including standins for actinides and fission products) at temperatures of up to 150/sup 0/C were studied. Two methods were used to measure the solubility of glass components in demineralized water. One method involved approaching equilibrium from subsaturation, while the second method involved approaching equilibrium from supersaturation. The aqueous solutions were analyzed by induction-coupled plasma spectrometry (ICP). Uranium was determined using a Scintrex U-A3 uranium analyzer and zinc and cesium were determined by atomic absorption. The system that results when a waste glass is contacted with demineralized water is a complex one. The two methods used to determine the solubility limits gave very different results, with the supersaturation method yielding much higher solution concentrations than the subsaturation method for most of the elements present in the waste glasses. The results show that it is impossible to assign solubility limits to the various glass components without thoroughly describing the glass-water systems. This includes not only defining the glass type and solution temperature, but also the glass surface area-to-water volume ratio (S/V) of the system and the complete thermal history of the system. 21 figures, 22 tables. (DLC)

Fullam, H.T.

1981-06-01T23:59:59.000Z

351

Disposition of actinides released from high-level waste glass  

SciTech Connect

A series of static leach tests was conducted using glasses developed for vitrifying tank wastes at the Savannah River Site to monitor the disposition of actinide elements upon corrosion of the glasses. In these tests, glasses produced from SRL 131 and SRL 202 frits were corroded at 90{degrees}C in a tuff groundwater. Tests were conducted using crushed glass at different glass surface area-to-solution volume (S/V) ratios to assess the effect of the S/V on the solution chemistry, the corrosion of the glass, and the disposition of actinide elements. Observations regarding the effects of the S/V on the solution chemistry and the corrosion of the glass matrix have been reported previously. This paper highlights the solution analyses performed to assess how the S/V used in a static leach test affects the disposition of actinide elements between fractions that are suspended or dissolved in the solution, and retained by the altered glass or other materials.

Ebert, W.L.; Bates, J.K.; Buck, E.C.; Gong, M.; Wolf, S.F.

1994-05-01T23:59:59.000Z

352

Glass for low-cost photovoltaic solar arrays  

DOE Green Energy (OSTI)

In photovoltaic systems, the encapsulant material that protects the solar cells should be highly transparent and very durable. Glass satisfies these two criteria and is considered a primary candidate for low-cost, photovoltaic encapsulation systems. In this report, various aspects of glass encapsulation are treated that are important for the designer of photovoltaic systems. Candidate glasses and available information defining the state of the art of glass encapsulation materials and processes for automated, high volume production of terrestrial photovoltaic devices and related applications are presented. The criteria for consideration of the glass encapsulation systems were based on the LSA (Low-cost Solar Array) Project goals for arrays: (a) a low degradation rate, (b) high reliability, (c) an efficiency greater than 10 percent, (d) a total array price less than $500/kW, and (e) a production capacity of 5 x 10/sup 5/ kW/yr. The glass design areas treated herein include the types of glass, sources and costs, physical properties and glass modifications, such as antireflection coatings. 78 references.

Bouquet, F.L.

1980-02-01T23:59:59.000Z

353

DWPF Melter Glass Pump Implementation and Design Improvement  

SciTech Connect

In order to improve the melt rate of high level waste slurry feed being vitrified in the Savannah River Sites (SRS) Defense Waste Processing Facility (DWPF) Melter, a melter glass pump (pump 1) was installed in the DWPF Melter on February 10, 2004. The glass pump increased melt rate by generating a forced convection within the molten glass pool, thereby increasing the heat transfer from the molten glass to the unmolten feed cold cap that is on top of the glass pool. After operating for over four months, the pump was removed on June 22, 2004 due to indications that it had failed. The removed pump exhibited obvious signs of corrosion, had collapsed inward at the glass exit slots at the melt line, and was dog-legged in the same area. This lead to the pump being redesigned to improve its mechanical integrity (increased wall thickness and strength) while maintaining its hydraulic diameter as large as possible. The improved DWPF glass pump (pump 2) was installed on September 15, 2004. The impact of the new design on pump life, along with analysis of the glass pumps impact on melt rate in the DWPF Melter is discussed in this paper.

MICHAEL, SMITH

2005-04-01T23:59:59.000Z

354

The recycling of the coal fly ash in glass production  

Science Conference Proceedings (OSTI)

The recycling of fly ash obtained from the combustion of coal in thermal power plant has been studied. Coal fly ash was vitrified by melting at 1773 K for 5 hours without any additives. The properties of glasses produced from coal fly ash were investigated by means of Differential Thermal Analysis (DTA), X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) techniques. DTA study indicated that there was only one endothermic peak at 1003 K corresponding to the glass transition temperature. XRD analysis showed the amorphous state of the glass sample produced from coal fly ash. SEM investigations revealed that the coal fly ash based glass sample had smooth surface. The mechanical, physical and chemical properties of the glass sample were also determined. Recycling of coal fly ash by using vitrification technique resulted to a glass material that had good mechanical, physical and chemical properties. Toxicity characteristic leaching procedure (TCLP) results showed that the heavy metals of Pb, Cr, Zn and Mn were successfully immobilized into the glass. It can be said that glass sample obtained by the recycling of coal fly ash can be taken as a non-hazardous material. Overall, results indicated that the vitrification technique is an effective way for the stabilization and recycling of coal fly ash.

Erol, M.M.; Kucukbayrak, S.; Ersoy-Mericboyu, A. [Istanbul Technical University, Istanbul (Turkey). Dept. of Chemical Engineering

2006-09-15T23:59:59.000Z

355

Crystallizing hard-sphere glasses by doping with active particles  

E-Print Network (OSTI)

Crystallization and vitrification are two different routes to form a solid. Normally these two processes suppress each other, with the glass transition preventing crystallization at high density (or low temperature). This is even true for systems of colloidal hard spheres, which are commonly used as building blocks for fabricating photonic crystals [1-3]. Here, by performing Brownian dynamics simulations of glass systems consisting of mixtures of active and passive hard spheres, we show that the crystallization of such hard-sphere glasses can be dramatically promoted by doping the system with small amounts of active particles. Surprisingly, even hard-sphere glasses of packing fraction up to $\\phi = 0.635$ crystallize, which is around 0.5% below the random close packing ~ 0.64. Our results suggest a novel way of fabricating crystalline materials from (colloidal) glasses. This is particularly important for materials that get easily kinetically trapped in glassy states, and crystal nucleation hardly occurs.

Ran Ni; Martien A. Cohen Stuart; Marjolein Dijkstra; Peter G. Bolhuis

2013-10-28T23:59:59.000Z

356

Glass-heat-pipe evacuated-tube solar collector  

DOE Patents (OSTI)

A glass heat pipe is adapted for use as a solar energy absorber in an evacuated tube solar collector and for transferring the absorbed solar energy to a working fluid medium or heat sink for storage or practical use. A capillary wick is formed of granular glass particles fused together by heat on the inside surface of the heat pipe with a water glass binder solution to enhance capillary drive distribution of the thermal transfer fluid in the heat pipe throughout the entire inside surface of the evaporator portion of the heat pipe. Selective coatings are used on the heat pipe surface to maximize solar absorption and minimize energy radiation, and the glass wick can alternatively be fabricated with granular particles of black glass or obsidian.

McConnell, R.D.; VanSant, J.H.

1981-08-06T23:59:59.000Z

357

IRON-PHOSPHATE GLASS FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM  

Science Conference Proceedings (OSTI)

Technetium-99 (Tc-99) can bring a serious environmental threat because of its high fission yield, long half-life, and high solubility and mobility in the ground water. The present work investigated the immobilization of Tc-99 (surrogated by Re) by heat-treating mixtures of an iron-phosphate glass with 1.5 to 6 wt.% KReO{sub 4} at {approx}1000 C. The Re retention in the glass was as high as {approx}1.2 wt. % while the loss of Re by evaporation during melting was {approx}50%. Re was uniformly distributed within the glass. The normalized Re release by the 7-day Product Consistency Test was {approx}0.39 g/m{sup 2}, comparable with that in phosphate-bonded ceramics and borosilicate glasses. These results suggest that iron-phosphate glass can provide a good matrix for immobilizing Tc-99.

KRUGER AA; HRMA PR; XU K; CHOI J; UM W; HEO J

2012-03-19T23:59:59.000Z

358

Hydrogen speciation in hydrated layers on nuclear waste glass  

DOE Green Energy (OSTI)

The hydration of an outer layer on nuclear waste glasses is known to occur during leaching, but the actual speciation of hydrogen (as water or hydroxyl groups) in these layers has not been determined. As part of the Nevada Nuclear Waste Storage Investigations Project, we have used infrared spectroscopy to determine hydrogen speciations in three nuclear waste glass compositions (SRL-131 & 165, and PNL 76-68), which were leached at 90{sup 0}C (all glasses) or hydrated in a vapor-saturated atmosphere at 202{sup 0}C (SRL-131 only). Hydroxyl groups were found in the surface layers of all the glasses. Molecular water was found in the surface of SRL-131 and PNL 76-68 glasses that had been leached for several months in deionized water, and in the vapor-hydrated sample. The water/hydroxyl ratio increases with increasing reaction time; molecular water makes up most of the hydrogen in the thick reaction layers on vapor-phase hydrated glass while only hydroxyl occurs in the least reacted samples. Using the known molar absorptivities of water and hydroxyl in silica-rich glass the vapor-phase layer contained 4.8 moles/liter of molecular water, and 0.6 moles water in the form hydroxyl. A 15 {mu}m layer on SRL-131 glass formed by leaching at 90{sup 0}C contained a total of 4.9 moles/liter of water, 2/3 of which was as hydroxyl. The unreacted bulk glass contains about 0.018 moles/liter water, all as hydroxyl. The amount of hydrogen added to the SRL-131 glass was about 70% of the original Na + Li content, not the 300% that would result from alkali=hydronium ion interdiffusion. If all the hydrogen is then assumed to be added as the result of alkali-H{sup +} interdiffusion, the molecular water observed may have formed from condensation of the original hydroxyl groups.

Aines, R.D.; Weed, H.C.; Bates, J.K.

1987-01-15T23:59:59.000Z

359

Modeling of Glass Making Processes for Improved Efficiency  

SciTech Connect

The overall goal of this project was to develop a high-temperature melt properties database with sufficient reliability to allow mathematical modeling of glass melting and forming processes for improved product quality, improved efficiency and lessened environmental impact. It was initiated by the United States glass industry through the NSF Industry/University Center for Glass Research (CGR) at Alfred University [1]. Because of their important commercial value, six different types/families of glass were studied: container, float, fiberglass (E- and wool-types), low-expansion borosilicate, and color TV panel glasses. CGR member companies supplied production-quality glass from all six families upon which we measured, as a function of temperature in the molten state, density, surface tension, viscosity, electrical resistivity, infrared transmittance (to determine high temperature radiative conductivity), non-Newtonian flow behavior, and oxygen partial pres sure. With CGR cost sharing, we also studied gas solubility and diffusivity in each of these glasses. Because knowledge of the compositional dependencies of melt viscosity and electrical resistivity are extremely important for glass melting furnace design and operation, these properties were studied more fully. Composition variations were statistically designed for all six types/families of glass. About 140 different glasses were then melted on a laboratory scale and their viscosity and electrical resistivity measured as a function of temperature. The measurements were completed in February 2003 and are reported on here. The next steps will be (1) to statistically analyze the compositional dependencies of viscosity and electrical resistivity and develop composition-property response surfaces, (2) submit all the data to CGR member companies to evaluate the usefulness in their models, and (3) publish the results in technical journals and most likely in book form.

Thomas P. Seward III

2003-03-31T23:59:59.000Z

360

Synthetic Strategies Toward Tetrahydrofurans Involving Double Diastereoselective Nucleophile-Promoted Aldol-Lactonizations and Subsequent Applications to Bioactive Natural Products  

E-Print Network (OSTI)

Novel synthetic strategies towards the formation of tetrahydrofurans and their subsequent application to bioactive natural products have been explored. More specifically, a method for invoking double-diastereoselectivity in the formation of tetrahydrofuran-fused ?-lactones through nucleophile-catalyzed aldol-lactonization (NCAL) has been developed. By employing a chiral catalyst, such as OTMS-quinidine or OTMS-quinine, coupled with a chiral aldehyde acid substrate, we have been able to successfully override the inherent substrate stereochemical bias to access either diastereomeric product as the major adduct. This new methodology is being applied to construction of the tetrahydrofuran fragment of the cytotoxic agent, haterumalide NA.

Arendt, Kevin M.

2009-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Conversion of plutonium-containing materials into borosilicate glass using the glass material oxidation and dissolution system  

SciTech Connect

The end of the cold war has resulted in excess plutonium-containing materials (PCMs) in multiple chemical forms. Major problems are associated with the long-term management of these materials: safeguards and nonproliferation issues; health, environment, and safety concerns; waste management requirements; and high storage costs. These issues can be addressed by conversion of the PCMs to glass: however, conventional glass processes require oxide-like feed materials. Conversion of PCMs to oxide-like materials followed by vitrification is a complex and expensive process. A new vitrification process has been invented, the Glass Material Oxidation and Dissolution System (GMODS) to allow direct conversion of PCMs to glass. GMODS directly converts metals, ceramics, and amorphous solids to glass; oxidizes organics with the residue converted to glass; and converts chlorides to borosilicate glass and a secondary sodium chloride stream. Laboratory work has demonstrated the conversion of cerium (a plutonium surrogate), uranium (a plutonium surrogate), Zircaloy, stainless steel, multiple oxides, and other materials to glass. Equipment options have been identified for processing rates between 1 and 100,000 t/y. Significant work, including a pilot plant, is required to develop GMODS for applications at an industrial scale.

Forsberg, C.W.; Beahm, E.C.; Parker, G.W. [and others

1996-01-27T23:59:59.000Z

362

Gadolinium Borosilicate Glass-Bonded Gd-Silicate Apatite: A Glass-Ceramic Nuclear Waste Form for Actinides  

SciTech Connect

A Gd-rich crystalline phase precipitated in a sodium gadolinium alumino-borosilicate glass during synthesis. The glass has a chemical composition of 45.39-31.13 wt% Gd2O3, 28.80-34.04 wt% SiO2, 10.75-14.02 wt% Na2O, 4.30-5.89 wt% Al2O3, and 10.75-14.91 wt% B2O3. Backscattered electron images revealed that the crystals are hexagonal, elongated, acicular, prismatic, skeletal or dendritic, tens of mm in size, some reaching 200 mm in length. Electron microprobe analysis confirmed that the crystals are chemically homogeneous and have a formula of NaGd9(SiO4)6O2 with minor B substitution for Si. The X-ray diffraction pattern of this phase is similar to that of lithium gadolinium silicate apatite. Thus, this hexagonal phase is a rare earth silicate with the apatite structure. We suggest that this Gd-silicate apatite in a Gd-borosilicate glass is a potential glass-ceramic nuclear waste form for actinide disposition. Am, Cm and other actinides can easily occupy the Gd-sites. The potential advantages of this glass-ceramic waste form include: (1) both the glass and apatite can be used to immobilize actinides, (2) silicate apatite is thermodynamically more stable than the glass, (3) borosilicate glass-bonded Gd-silicate apatite is easily fabricated, and (4) the Gd is an effective neutron absorber.

Zhao, Donggao (Michigan, Univ Of - Ann Arbor); Li, Liyu (BATTELLE (PACIFIC NW LAB)); Davis, Linda L. (ASSOC WESTERN UNIVERSITY); Weber, William J. (BATTELLE (PACIFIC NW LAB)); Ewing, Rodney C. (Michigan, Univ Of - Ann Arbor); KP Hart and GR Lumpkin

2001-01-01T23:59:59.000Z

363

Flow Test At Glass Buttes Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

Flow Test At Glass Buttes Area (DOE GTP) Exploration Activity Details Location Glass Buttes Area Exploration Technique Flow Test Activity Date Usefulness not indicated DOE-funding...

364

A Model of the Effect of Particle Shape on Observed Glass ...  

Science Conference Proceedings (OSTI)

Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and Natural Gas Bearing Shales · Modeling the Electrical Conductivity in Glass Melts.

365

Corrosion Behavior of SnO2-Based Ceramics in Soda-Lime Glass ...  

Science Conference Proceedings (OSTI)

027- Search for the Rigidity Transition and Intermediate Phase in Lithium Oxide Silicate Glass Systems Using .... 101- Viscous Silicate SOFC Glass Sealants.

366

Ground Gravity Survey At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At Glass Buttes Area (DOE GTP) Exploration...

367

Field Mapping At Glass Buttes Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Field Mapping At Glass Buttes Area (DOE GTP) Exploration Activity...

368

What's the Matter? Q-Glasses Could Be a New Class of Solids  

Science Conference Proceedings (OSTI)

Q-Glasses Could Be a New Class of Solids. ... The round nodules are the q-glass, not crystalline but with a well-defined chemical composition. ...

2013-08-07T23:59:59.000Z

369

Water-Gas Samples At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water-Gas Samples At Glass Buttes Area (DOE GTP) Exploration Activity Details Location Glass...

370

“Work-Hardenable” Ductile Ti-based Bulk Metallic Glass Matrix ...  

Science Conference Proceedings (OSTI)

Highly processable bulk metallic glasses (BMGs) with unique supercooled liquid ... Application of Metallic Glass for High Performance Si Solar Cell: Oxidation ...

371

Mechanical Properties of Al-Ni-Zr Bulk Metallic Glasses Interpreted ...  

Science Conference Proceedings (OSTI)

Symposium, M. Bulk Metallic Glasses, Nanocrystalline Materials, and ... Application of Metallic Glass for High Performance Si Solar Cell: Oxidation Behavior of ...

372

Fabrication of Cu-Zr-based Bulk Metallic Glasses by Vertical Twin ...  

Science Conference Proceedings (OSTI)

Symposium, M. Bulk Metallic Glasses, Nanocrystalline Materials, and ... Application of Metallic Glass for High Performance Si Solar Cell: Oxidation Behavior of ...

373

Investigation of Torsion Fracture on Zr-based Bulk Metallic Glass  

Science Conference Proceedings (OSTI)

Symposium, M. Bulk Metallic Glasses, Nanocrystalline Materials, and ... Application of Metallic Glass for High Performance Si Solar Cell: Oxidation Behavior of ...

374

Crack-resistance Curve of a Zr-Ti-Cu-Al Bulk Metallic Glass with ...  

Science Conference Proceedings (OSTI)

Symposium, M. Bulk Metallic Glasses, Nanocrystalline Materials, and ... Application of Metallic Glass for High Performance Si Solar Cell: Oxidation Behavior of ...

375

Indentation behavior of ion-exchanged glasses  

SciTech Connect

This paper reports indentation fracture mechanics extended to include the effect of a thin layer of residual stress on the indentation strength of brittle materials. The proposed theory was used to predict the residual stress values for an ion-exchanged glass. For flaws placed before the exchange, considerable strengthening was observed, but the value of the surface stress predicted was considerable underestimated. For flaws placed after the exchange, there was no strengthening and the value of the surface stress was predicted to be zero. The failure of the indentation analysis indicates that it has to be modified for accurate stress determination. Thin layers of residual stress were found to retard the initiation of surface damage, but their influence on the strength after damage initiation was minimal.

Tandon, R.; Green, D.J. (Dept. of Materials Science and Engineering, Pennsylvania State Univ., University Park, PA (US))

1990-04-01T23:59:59.000Z

376

Gas separation with glass membranes. Final report  

DOE Green Energy (OSTI)

The Department of Energy (DOE) is seeking to develop high temperature, high pressure inorganic membrane technology to perform a variety of gas separation processes to improve the efficiency and economics of advanced power generation systems such as direct coal-fueled turbines (DCFT) and the integrated gasification combined cycle process (IGCC). The temperatures encountered in these power generation systems are far above the temperature range for organic membrane materials. Inorganic materials such as ceramics are therefore the most likely membrane materials for use at high temperatures. This project focussed on silica glass fiber membranes made by PPG Industries (Pittsburgh, PA). The goals were both experimental and theoretical. The first objective was to develop a rational theory for the performance of these membranes. With existing theories as a starting point, a new theory was devised to explain the unusual ``molecular sieving`` behavior exhibited by these glass membranes. An apparatus was then devised for making permeation performance measurements at conditions of interest to DOE (temperatures to 2000{degrees}F; pressures to 1000 psia). With this apparatus, gas mixtures could be made typical of coal combustion or coal gasification processes, these gases could be passed into a membrane test cell, and the separation performance determined. Data were obtained for H{sub 2}/CO,N{sub 2}/CO{sub 2}, 0{sub 2}/N{sub 2}, and NH{sub 3}/N{sub 2} mixtures and for a variety of pure component gases (He, H{sub 2}, CO{sub 2}, N{sub 2}, CO, NH{sub 3}). The most challenging part of the project turned out to be the sealing of the membrane at high temperatures and pressures. The report concludes with an overview of the practical potential of these membranes and of inorganic membranes in general of DOE and other applications.

Roberts, D.L.; Abraham, L.C.; Blum, Y.; Way, J.D.

1992-05-01T23:59:59.000Z

377

Low Velocity Sphere Impact of a Borosilicate Glass  

SciTech Connect

This report summarizes US Army TARDEC sponsored work at Oak Ridge National Laboratory (ORNL) involving low velocity (< 30 m/s or < 65 mph) ball impact testing of Borofloat borosilicate glass, and is a follow-up to a similar study completed by the authors on Starphire soda-lime silicate glass last year. The response of the borosilicate glass to impact testing at different angles was also studied. The Borofloat glass was supplied by the US Army Research Laboratory and its tin-side was impacted or indented. The intent was to better understand low velocity impact response in the Borofloat. Seven sphere materials were used whose densities bracket that of rock: borosilicate glass, soda-lime silicate glass, silicon nitride, aluminum oxide, zirconium oxide, carbon steel, and a chrome steel. A gas gun or a ball-drop test setup was used to produce controlled velocity delivery of the spheres against the glass tile targets. Minimum impact velocities to initiate fracture in the Borofloat were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between the seven sphere-Borofloat-target combinations. The primary observations from this low velocity (< 30 m/s or < 65 mph) testing were: (1) BS glass responded similarly to soda-lime silicate glass when spherically indented but quite differently under sphere impact conditions; (2) Frictional effects contributed to fracture initiation in BS glass when it spherically indented. This effect was also observed with soda-lime silicate glass; (3) The force necessary to initiate fracture in BS glass under spherical impact decreases with increasing elastic modulus of the sphere material. This trend is opposite to what was observed with soda-lime silicate glass. Friction cannot explain this trend and the authors do not have a legitimate explanation for it yet; (4) The force necessary to initiate contact-induced fracture is higher under dynamic conditions than under quasi-static conditions. That difference decreases with increasing elastic modulus mismatch between the sphere material and borosilicate This trend was opposite in soda-lime silicate glass; (5) Fracture in borosilicate glass occurs at lower velocities (i.e., easier) at 24{sup o} than at 0{sup o} (orthogonal) and 46{sup o} of impact for the same probability of failure. Though not analyzed yet, this suggests that a convolution of kinetic energy and friction is contributing to that trend; (6) There is a subtle indication there was intra-tile differences in spherical indentation RCIF. This likely is not a material property nor exclusive to borosilicate glass, rather, it is a statistical response of a combination of local, surface-located flaw and imposed tensile stress. Understanding of the surface flaw population and flaw positioning can likely enable prediction of spherical indentation RCIF; and (7) Contact-induced fracture did not initiate in the Borofloat BS for impact kinetic energies up to {approx} 20 mJ. For kinetic energies between {approx} 20-150 mJ, fracture sometimes initiated. Contact-induced fracture would always occur for impact energies > 150 mJ. The energy values, and their boundaries, were much lower for BS glass than they were for soda-lime silicate glass.

Morrissey, Timothy G [ORNL; Ferber, Mattison K [ORNL; Wereszczak, Andrew A [ORNL; Fox, Ethan E [ORNL

2012-05-01T23:59:59.000Z

378

Radionuclide decay effects on waste glass corrosion and weathering  

Science Conference Proceedings (OSTI)

The release of glass components into solution, including radionuclides, may be influenced by the presence of radiolytically produced nitric acid, carboxylic acid, and transient water dissociation products such as {center_dot}OH and O{sub 2}{sup {minus}}. Under batch test conditions, glass corrosion has been shown to increase up to a maximum of three-to five-fold in irradiated tests relative to nonirradiated tests, while in other studies the presence of radiolytic products has actually decreased glass corrosion rates. Bicarbonate groundwaters will buffer against pH decreases and changes in corrosion rates. Under high surface area-to-solution volume (S/V) conditions, the bicarbonate buffering reservoir may be quickly overwhelmed by radiolytic acids that are concentrated in the thin films of water contacting the samples. Glass reaction rates have been shown to increase up to 10-to-15-fold due to radiation exposure under high S/V conditions. Radiation damage to solid glass materials results in bond damage and atomic displacements. This type of damage has been shown to increase the release rates of glass components up to four-fold during subsequent corrosion tests, although under actual disposal conditions, glass annealing processes may negate the solid radiation damage effects.

Wronkiewicz, D.J.

1993-12-31T23:59:59.000Z

379

Infrared spectroscopy and hydrogen isotope geochemistry of hydrous silicate glasses  

DOE Green Energy (OSTI)

The focus of this project is the combined appication of infrared spectroscopy and stable isotope geochemistry to the study of hydrogen-bearing species dissolved in silicate melts and glasses. We are conducting laboratory experiments aimed at determining the fractionation of D and H between melt species (OH and H{sub 2}O) and hydrous vapor and the diffusivities of these species in glasses and melts. Knowledge of these parameters is critical to understanding the behavior of hydrogen isotopes during igneous processes and hydrothermal processes. These results also could be valuable in application of glass technology to development of nuclear waste disposal strategies.

Epstein, S.; Stolper, E.

1992-01-01T23:59:59.000Z

380

Ultrafast pulsed laser utilizing broad bandwidth laser glass  

DOE Patents (OSTI)

An ultrafast laser uses a Nd-doped phosphate laser glass characterized by a particularly broad emission bandwidth to generate the shortest possible output pulses. The laser glass is composed primarily of P{sub 2}O{sub 5}, Al{sub 2}O{sub 3} and MgO, and possesses physical and thermal properties that are compatible with standard melting and manufacturing methods. The broad bandwidth laser glass can be used in modelocked oscillators as well as in amplifier modules. 7 figs.

Payne, S.A.; Hayden, J.S.

1997-09-02T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Ultrafast pulsed laser utilizing broad bandwidth laser glass  

DOE Patents (OSTI)

An ultrafast laser uses a Nd-doped phosphate laser glass characterized by a particularly broad emission bandwidth to generate the shortest possible output pulses. The laser glass is composed primarily of P.sub.2 O.sub.5, Al.sub.2 O.sub.3 and MgO, and possesses physical and thermal properties that are compatible with standard melting and manufacturing methods. The broad bandwidth laser glass can be used in modelocked oscillators as well as in amplifier modules.

Payne, Stephen A. (Castro Valley, CA); Hayden, Joseph S. (Clarks Summit, PA)

1997-01-01T23:59:59.000Z

382

Application of Argonne's Glass Furnace Model to longhorn glass corporation oxy-fuel furnace for the production of amber glass.  

SciTech Connect

The objective of this project is to apply the Argonne National Laboratory's Glass Furnace Model (GFM) to the Longhorn oxy-fuel furnace to improve energy efficiency and to investigate the transport of gases released from the batch/melt into the exhaust. The model will make preliminary estimates of the local concentrations of water, carbon dioxide, elemental oxygen, and other subspecies in the entire combustion space as well as the concentration of these species in the furnace exhaust gas. This information, along with the computed temperature distribution in the combustion space may give indications on possible locations of crown corrosion. An investigation into the optimization of the furnace will be performed by varying several key parameters such as the burner firing pattern, exhaust number/size, and the boost usage (amount and distribution). Results from these parametric studies will be analyzed to determine more efficient methods of operating the furnace that reduce crown corrosion. Finally, computed results from the GFM will be qualitatively correlated to measured values, thus augmenting the validation of the GFM.

Golchert, B.; Shell, J.; Jones, S.; Energy Systems; Shell Glass Consulting; Anheuser-Busch Packaging Group

2006-09-06T23:59:59.000Z

383

Alkaline resistant phosphate glasses and method of preparation and use thereof  

Science Conference Proceedings (OSTI)

A substantially alkaline resistant calcium-iron-phosphate (CFP) glass and methods of making and using thereof. In one application, the CFP glass is drawn into a fiber and dispersed in cement to produce glass fiber reinforced concrete (GFRC) articles having the high compressive strength of concrete with the high impact, flexural and tensile strength associated with glass fibers.

Brow, Richard K. (Rolla, MO); Reis, Signo T. (Rolla, MO); Velez, Mariano (Rolla, MO); Day, Delbert E. (Rolla, MO)

2010-01-26T23:59:59.000Z

384

Preparation of Bi-Sr-Ca-Cu-O superconductors from oxide-glass precursors  

DOE Patents (OSTI)

A superconductor and precursor therefor from oxide mixtures of Ca, Sr, Bi and Cu. Glass precursors quenched to elevated temperatures result in glass free of crystalline precipitates having enhanced mechanical properties. Superconductors are formed from the glass precursors by heating in the presence of oxygen to a temperature below the melting point of the glass.

Hinks, David G. (Lemont, IL); Capone, II, Donald W. (Northbridge, MA)

1992-01-01T23:59:59.000Z

385

IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION: KT05- AND KT06-SERIES GLASS COMPOSITIONS  

SciTech Connect

This report is the second in a series of studies of the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. The KT05-series glasses were selected, fabricated, and characterized to further study glass compositions where iron titanate crystals had been previously found to form. The intent was to better understand the mechanisms and compositions that favored the formation of crystals containing titanium. Formation of these crystalline phases was confirmed. Increased Na{sub 2}O concentrations had little if any impact on reducing the propensity for the formation of the iron titanate crystalline phases. Other physical properties of these glasses were not measured since the intent was to focus on crystallization. Additional studies are suggested to investigate the potential impacts of Al{sub 2}O{sub 3} and K{sub 2}O on crystallization in glasses with high TiO{sub 2} concentrations. The KT06-series glasses were selected, fabricated, and characterized to further study glass compositions that, while broader than the current projections for DWPF feeds with SCIX material, are potential candidates for future processing (i.e., the compositions are acceptable for processing by the Product Composition Control System (PCCS) with the exception of the current TiO{sub 2} concentration constraint). The chemical compositions of these glasses matched well with the target values. The chemical durabilities of all the glasses were acceptable relative to the Environmental Assessment (EA) benchmark. Minor crystallization was identified in some of the slowly cooled glasses, although this crystallization did not impact chemical durability. Several of the KT06-series compositions had durability values that, while acceptable, were not accurately predicted by the current durability models. It was shown that for these high TiO{sub 2} concentration glasses, relatively high Fe{sub 2}O{sub 3} concentrations combined with relatively high Al{sub 2}O{sub 3} concentrations led to durabilities that were unpredictable. Several of the KT06-series glasses also had measured viscosity values that were not well predicted by the current model. A statistical partitioning routine showed that the measured viscosities became unpredictable by the current model when the Fe{sub 2}O{sub 3} concentration in the glasses was less than about 8.2 wt % at the elevated TiO{sub 2} concentrations. The current durability and viscosity models will have to be further evaluated should compositions in these regions become necessary for DWPF processing. Overall, the results presented for the KT06-series glasses show that TiO{sub 2} from the SCIX streams can be incorporated into DWPF-type glasses at concentrations of 6 wt % (in glass) without any detrimental impacts on crystallization or chemical durability that are of practical importance. The measured values for chemical durability and viscosity were acceptable for processing; however, not all of the values were predictable by the current PCCS models. Since the compositions selected for the KT06-series glasses were outside the current projections for DWPF processing with the SCIX streams (in terms of waste components other than TiO{sub 2}), these results help identify compositional regions that, if necessary for processing, would require modifications to the current models. Additional experiments are currently underway. Once completed, all of the measured data will be reviewed and compared to model predictions to better determine whether the validation range of the DWPF process control models can be confidently extended, or whether refitting of the models will be necessary.

Fox, K.; Edwards, T.

2011-01-03T23:59:59.000Z

386

Smart Glass Based on Micro-Blinds (MEMS)  

NLE Websites -- All DOE Office Websites (Extended Search)

Smart Glass Based on Micro-Blinds (MEMS) Smart Glass Based on Micro-Blinds (MEMS) Speaker(s): Boris Lamontagne Date: June 22, 2012 - 2:00pm Location: 90-3122 Seminar Host/Point of Contact: Stephen Selkowitz At the National Research Council, Canada we are developing a new type of smart glass based on micro-blinds (MEMS). The micro-blinds are tiny stressed metallic foils curling up once released or rolling down once actuated using electrostatic forces. Such smart glass is characterized by fast switching speed, UV-temperature insensitive and neutral appearance. Recent results will be presented as a well as our demo. Transmittance and thermal characteristics will also be addressed. There are various possible applications in building, automotive, aerospace as well as in display sectors. A video briefly describing the technology is

387

Research Needs: Glass Solar Reflectance and Vinyl Siding  

DOE Green Energy (OSTI)

The subject of glass solar reflectance and its contribution to permanent vinyl siding distortion has not been extensively studied, and some phenomena are not yet well understood. This white paper presents what is known regarding the issue and identifies where more research is needed. Three primary topics are discussed: environmental factors that control the transfer of heat to and from the siding surface; vinyl siding properties that may affect heat build-up and permanent distortion; and factors that determine the properties of reflected solar radiation from glass surfaces, including insulating window glass. Further research is needed to fully characterize the conditions associated with siding distortion, the scope of the problem, physical properties of vinyl siding, insulating window glass reflection characteristics, and possible mitigation or prevention strategies.

Hart, Robert; Curcija, Charlie; Arasteh, Dariush; Goudey, Howdy; Kohler, Christian; Selkowitz, Stephen

2011-07-07T23:59:59.000Z

388

Towards on-Chip, Integrated Chalcogenide Glass Based Biochemical Sensors  

E-Print Network (OSTI)

This paper reviews ongoing progress in the development of novel on-chip planar molecular sensors in infrared-transparent chalcogenide glasses. We demonstrate on-chip cavity-enhanced refractometry and infrared absorption ...

Hu, Juejun

389

Optical and structural analysis of lead bismuth silicate glasses  

SciTech Connect

Glasses having compositions 20PbO(79.5-x)Bi{sub 2}O{sub 3}xSiO{sub 2} (x = 10,30,50) doped with 0.5 mole% of Nd{sup 3+} ions were prepared by melt quench technique. The spectroscopic properties of the glasses were investigated using optical absorption and fluorescence spectra. The structural investigations of these glasses were carried out by recording the IR spectra. The variation of {Omega}{sub 2} with Bi{sub 2}O{sub 3} content has been attributed to changes in the asymmetry of the ligand field at the rare earth ion site and to the changes in the rare earth oxygen covalency. Heavy metal oxide glasses have been used as potential candidate in solid state laser, solar concentrators, optical detector, optical fiber and fluorescent display devices.

Bhardwaj, S.; Shukla, R. [Department of physics, Deenbandhu Chhotu Ram University of Science and Technology Murthal, Sonipat, Haryana (India); Sanghi, S.; Agarwal, A.; Pal, I. [Department of Applied Physics, Guru Jambheshwar University of Science and Technology, Hisar, Haryana (India)

2011-12-12T23:59:59.000Z

390

Ecology of microbe/basaltic glass interactions : mechanisms and diversity  

E-Print Network (OSTI)

basaltic glass dissolution. Materials and Methods 1. Growthmethod has likely resulted in the digestion and dissolutionmethod is commonly used in the chemical digestion of minerals, but additional dissolution and

Sudek, Lisa A.

2011-01-01T23:59:59.000Z

391

Colloid formation during the corrosion of SRL 200 glass  

SciTech Connect

Nonradioactive SRL 200S glass and fully radioactive SRL 200R glass were reacted at glass surface areas to leachant volume (SA/V) ratios of 20,000, 2,000, and 340 m{sup {minus}1} for times varying from several days to a few years. The particles present in the leachates of these tests have been examined by analytical electron microscopy (AEM). The major colloidal clay phase was identified as a smectite clay from its characteristic electron diffraction pattern. The clay colloids eventually disappear from the solution and return to the glass; the time at which this occurs depends on the SA/V. Uranium silicate particles and calcium-bearing phases were also sometimes found in the leachates.

Buck, E.C.; Bates, J.K.; Feng, X.

1994-05-01T23:59:59.000Z

392

Microsoft Word - Nanocrystal-in-glass-composites bh  

NLE Websites -- All DOE Office Websites (Extended Search)

(ICMAB, Spain) have demonstrated the power of this approach by introducing tin-doped indium oxide nanocrystals (ITO NCs) into niobium oxide glass (NbO x ) and showing that a...

393

RETENTION OF SULFATE IN HIGH LEVEL RADIOACTIVE WASTE GLASS  

SciTech Connect

High level radioactive wastes are being vitrified at the Savannah River Site for long term disposal. Many of the wastes contain sulfate at concentrations that can be difficult to retain in borosilicate glass. This study involves efforts to optimize the composition of a glass frit for combination with the waste to improve sulfate retention while meeting other process and product performance constraints. The fabrication and characterization of several series of simulated waste glasses are described. The experiments are detailed chronologically, to provide insight into part of the engineering studies used in developing frit compositions for an operating high level waste vitrification facility. The results lead to the recommendation of a specific frit composition and a concentration limit for sulfate in the glass for the next batch of sludge to be processed at Savannah River.

Fox, K.

2010-09-07T23:59:59.000Z

394

Preliminary Investigation of Sulfur Loading in Hanford LAW Glass  

SciTech Connect

A preliminary estimate was developed for loading limits for high-sulfur low-activity waste (LAW) feeds that will be vitrified into borosilicate glass at the Hanford Site in the waste-cleanup effort. Previous studies reported in the literature were consulted to provide a basis for the estimate. The examination of previous studies led to questions about sulfur loading in Hanford LAW glass, and scoping tests were performed to help answer these questions. These results of these tests indicated that a formulation approach developed by Vienna and colleagues shows promise for maximizing LAW loading in glass. However, there is a clear need for follow-on work. The potential for significantly lowering the amount of LAW glass produced at Hanford (after the initial phase of processing) because of higher sulfur tolerances may outweigh the cost and effort required to perform the necessary testing.

Vienna, John D.; Hrma, Pavel R.; Buchmiller, William C.; Ricklefs, Joel S.

2004-04-01T23:59:59.000Z

395

Nanomechanical studies of metallic glasses at ambient and elevated temperatures  

E-Print Network (OSTI)

Bulk metallic glasses, though attractive for use in structural applications for their high strength and elastic limit, display several unacceptable features upon deformation, including quasi-brittle failure along shear ...

Packard, Corinne E

2009-01-01T23:59:59.000Z

396

Q-Glasses Could Be a New Class of Solids  

Science Conference Proceedings (OSTI)

Aug 6, 2013 ... Seen under a microscope, it's clear that, like a crystal, the spherical q-glass ... so small they don't show up individually under the X-ray probes.

397

Property Models for High Waste Loaded Hanford HLW Glasses  

High Waste Loading Was Shown for Selected Wastes Examples of the high loaded glasses Al 2O 3 loadings in the 24-26 wt% range compared to <15% for a

398

Composite polymer: Glass edge cladding for laser disks  

DOE Patents (OSTI)

Large neodymium glass laser disks for disk amplifiers such as those used in the Nova laser require an edge cladding which absorbs at 1 micrometer. This cladding prevents edge reflections from causing parasitic oscillations which would otherwise deplete the gain. Nova now utilizes volume-absorbing monolithic-glass claddings which are fused at high temperature to the disks. These perform quite well but are expensive to produce. Absorbing glass strips are adhesively bonded to the edges of polygonal disks using a bonding agent whose index of refraction matches that of both the laser and absorbing glass. Optical finishing occurs after the strips are attached. Laser disks constructed with such claddings have shown identical gain performance to the previous Nova disks and have been tested for hundreds of shots without significant degradation. 18 figs.

Powell, H.T.; Wolfe, C.A.; Campbell, J.H.; Murray, J.E.; Riley, M.O.; Lyon, R.E.; Jessop, E.S.

1987-11-02T23:59:59.000Z

399

ALICE provides looking glass to birth of cosmos  

NLE Websites -- All DOE Office Websites (Extended Search)

10082010 ALICE provides looking glass to birth of cosmos Donald B Johnston, LLNL, (925) 423-4902, johnston19@llnl.gov Printer-friendly From left: Teresa Kamakea, Jeff...

400

Mapping the Strain Distributions in Deformed Bulk Metallic Glasses ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Bulk metallic glasses (BMGs) represent relatively new class of ... Evolution of Internal Strain with Temperature in Depleted Uranium in the ... Structural Effects upon Macroscopic Phenomena in Strained Ordered Oxide Films.

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Controlled Shear Band and Fracture in Bulk Metallic Glasses  

Science Conference Proceedings (OSTI)

Aerospace and Spacecraft Applications for Bulk Metallic Glasses and Matrix Composites · Air Oxidation of a Binary Cu64.5Zr35.5 Bulk Metallic Alloy at 573 ...

402

Horizontal non-contact slumping of flat glass  

E-Print Network (OSTI)

This paper continues the work of M. Akilian and A. Husseini on developing a noncontact glass slumping/shaping process. The shift from vertical slumping to horizontal slumping is implemented and various technologies required ...

Sung, Edward, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

403

Research Needs: Glass Solar Reflectance and Vinyl Siding  

E-Print Network (OSTI)

of the University of California, nor any of their employees,of the University of California. The views and opinions ofof the University of California. Research Needs: Glass Solar

Hart, Robert

2012-01-01T23:59:59.000Z

404

Open-cell glass crystalline porous material  

DOE Patents (OSTI)

An open-cell glass crystalline porous material made from hollow microspheres which are cenospheres obtained from fly ash, having an open-cell porosity of up to 90 vol. % is produced. The cenospheres are separated into fractions based on one or more of grain size, density, magnetic or non-magnetic, and perforated or non-perforated. Selected fractions are molded and agglomerated by sintering with a binder at a temperature below the softening temperature, or without a binder at a temperature about, or above, the softening temperature but below the temperature of liquidity. The porous material produced has an apparent density of 0.3-0.6 g/cm.sup.3, a compressive strength in the range of 1.2-3.5 MPa, and two types of openings: through-flow wall pores in the cenospheres of 0.1-30 micrometers, and interglobular voids between the cenospheres of 20-100 micrometers. The porous material of the invention has properties useful as porous matrices for immobilization of liquid radioactive waste, heat-resistant traps and filters, supports for catalysts, adsorbents and ion-exchangers.

Anshits, Alexander G. (Krasnoyarsk, RU); Sharonova, Olga M. (Krasnoyarsk, RU); Vereshchagina, Tatiana A. (Krasnoyarsk, RU); Zykova, Irina D. (Krasnoyarsk, RU); Revenko, Yurii A. (Zheleznogorsk, RU); Tretyakov, Alexander A. (Zheleznogorsk, RU); Aloy, Albert S. (Saint-Petersburg, RU); Lubtsev, Rem I. (Saint-Petersburg, RU); Knecht, Dieter A. (Idaho Falls, ID); Tranter, Troy J. (Idaho Falls, ID); Macheret, Yevgeny (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

405

Specialty Cellular Glass Products and Their Applications  

E-Print Network (OSTI)

Cellular glass products are composed of hermetically-sealed cells containing gases which exhibit no extracellular diffusion. As such, these products are impermeable to liquids and gases. FOAMGLAS® blocks have long been used as fireproof thermal insulation, especially in low temperature applications where condensation and subsequent ice formation in insulation can cause significant reduction in insulating value. Recently, specialty compositions have been developed in the borosilicate and boroaluminosilicate fields which exhibit a high degree of resistance to corrosion by aggressive chemicals as well. One product, sold as PENNGUARDTM block by Pennwalt Corporation, is used as a liner for chimneys where acid corrosion had previously caused substantial maintenance problems. The product is also used as an insulative, acid-resistant liner in numerous chemical processes. A more refractory foam called FOAMSID®12 insulation has been developed for use in extremely corrosive environments at elevated temperatures. One such field of application, the Alcoa Smelting Process, involves the use of molten salts which tend to impregnate materials which are porous to either salt vapors or to the liquid phase. Such impregnation of ordinary insulating materials causes a significant increase in heat transfer rates. FOAMSID®-12 blocks, with their unique properties of light weight, high strength, impermeability, and low thermal conductivity offer an opportunity for industrial energy conservation which did not previously exist.

Rostoker, D.

1979-01-01T23:59:59.000Z

406

Lithium Loaded Glass Fiber Neutron Detector Tests  

Science Conference Proceedings (OSTI)

Radiation portal monitors used for interdiction of illicit materials at borders include highly sensitive neutron detection systems. The main reason for having neutron detection capability is to detect fission neutrons from plutonium. The currently deployed radiation portal monitors (RPMs) from Ludlum and Science Applications International Corporation (SAIC) use neutron detectors based upon 3He-filled gas proportional counters, which are the most common large neutron detector. There is a declining supply of 3He in the world and, thus, methods to reduce the use of this gas in RPMs with minimal changes to the current system designs and sensitivity to cargo-borne neutrons are being investigated. Four technologies have been identified as being currently commercially available, potential alternative neutron detectors to replace the use of 3He in RPMs. Reported here are the results of tests of the lithium-loaded glass fibers option. This testing measured the neutron detection efficiency and gamma ray rejection capabilities of a small system manufactured by Nucsafe (Oak Ridge, TN).

Ely, James H.; Erikson, Luke E.; Kouzes, Richard T.; Lintereur, Azaree T.; Stromswold, David C.

2009-11-12T23:59:59.000Z

407

Fracturing of simulated high-level waste glass in canisters  

SciTech Connect

Waste-glass castings generated from engineering-scale developmental processes at the Pacific Northwest Laboratory are generally found to have significant levels of cracks. The causes and extent of fracturing in full-scale canisters of waste glass as a result of cooling and accidental impact are discussed. Although the effects of cracking on waste-form performance in a repository are not well understood, cracks in waste forms can potentially increase leaching surface area. If cracks are minimized or absent in the waste-glass canisters, the potential for radionuclide release from the canister package can be reduced. Additional work on the effects of cracks on leaching of glass is needed. In addition to investigating the extent of fracturing of glass in waste-glass canisters, methods to reduce cracking by controlling cooling conditions were explored. Overall, the study shows that the extent of glass cracking in full-scale, passively-cooled, continuous melting-produced canisters is strongly dependent on the cooling rate. This observation agrees with results of previously reported Pacific Northwest Laboratory experiments on bench-scale annealed canisters. Thus, the cause of cracking is principally bulk thermal stresses. Fracture damage resulting from shearing at the glass/metal interface also contributes to cracking, more so in stainless steel canisters than in carbon steel canisters. This effect can be reduced or eliminated with a graphite coating applied to the inside of the canister. Thermal fracturing can be controlled by using a fixed amount of insulation for filling and cooling of canisters. In order to maintain production rates, a small amount of additional facility space is needed to accomodate slow-cooling canisters. Alternatively, faster cooling can be achieved using the multi-staged approach. Additional development is needed before this approach can be used on full-scale (60-cm) canisters.

Peters, R.D.; Slate, S.C.

1981-09-01T23:59:59.000Z

408

Structure of Glass-Forming Melts - Lanthanide in Borosilicates  

Science Conference Proceedings (OSTI)

Over the past few years, we studied several complex Na2O-Al2O3-B2O3-SiO2 glass systems to answer key questions: effects of melt chemistry on solubility of lanthanide oxides; lanthanide solution behavior, and intermediate-range ordering in the melts. This paper summarizes our currently understanding on rare earth elements in borosilicate glasses, covering solution behavior, solubility limits, crystalization and phase separation.

Li, Hong; Li, Liyu; Qian, Morris; Strachan, Denis M.; Wang, Zheming

2004-05-17T23:59:59.000Z

409

Metallic glass composition. [That does not embrittle upon annealing  

DOE Patents (OSTI)

This patent pertains to a metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon, carbon and phosphorous to which is added an amount of a ductility-enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

Kroeger, D.M.; Koch, C.C.

1984-09-14T23:59:59.000Z

410

GRADIENT INDEX SPHERES BY THE SEQUENTIAL ACCRETION OF GLASS POWDERS  

Science Conference Proceedings (OSTI)

The Department of Energy is seeking a method for fabricating mm-scale spheres having a refractive index that varies smoothly and continuously from the center to its surface [1]. The fabrication procedure must allow the creation of a range of index profiles. The spheres are to be optically transparent and have a refractive index differential greater than 0.2. The sphere materials can be either organic or inorganic and the fabrication technique must be capable of scaling to low cost production. Mo-Sci Corporation proposed to develop optical quality gradient refractive index (GRIN) glass spheres of millimeter scale (1 to 2 mm diameter) by the sequential accretion and consolidation of glass powders. Other techniques were also tested to make GRIN spheres as the powder-accretion method produced non-concentric layers and poor optical quality glass spheres. Potential ways to make the GRIN spheres were (1) by "coating" glass spheres (1 to 2 mm diameter) with molten glass in a two step process; and (2) by coating glass spheres with polymer layers.

MARIANO VELEZ

2008-06-15T23:59:59.000Z

411

Development of a process control sensor for the glass industry  

SciTech Connect

This project was initiated to fill a need in the glass industry for a non-contact temperature sensor for glass melts. At present, the glass forming industry (e.g., bottle manufacture) consumes significant amounts of energy. Careful control of temperature at the point the bottle is molded is necessary to prevent the bottle from being rejected as out-of-specification. In general, the entire glass melting and conditioning process is designed to minimize this rejection rate, maximize throughput and thus control energy and production costs. This program focuses on the design, development and testing of an advanced optically based pyrometer for glass melts. The pyrometer operates simultaneously at four wavelengths; through analytical treatment of the signals, internal temperature profiles within the glass melt can be resolved. A novel multiplexer alloys optical signals from a large number of fiber-optic sensors to be collected and resolved by a single detector at a location remote from the process. This results in a significant cost savings on a per measurement point basis. The development program is divided into two phases. Phase 1 involves the construction of a breadboard version on the instrument and its testing on a pilot-scale furnace. In Phase 2, a prototype analyzer will be constructed and tested on a commercial forehearth. This report covers the Phase 1 activities.

Gardner, M.; Candee, A.; Kramlich, J.; Koppang, R.

1991-05-01T23:59:59.000Z

412

Phosphate glasses for radioactive, hazardous and mixed waste immobilization  

DOE Patents (OSTI)

Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole %.iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.5 mole % to about 2 mole % iron (III) oxide and from about 3 mole % to about 6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided.

Cao, Hui (Middle Island, NY); Adams, Jay W. (Stony Brook, NY); Kalb, Paul D. (Wading River, NY)

1999-03-09T23:59:59.000Z

413

Phosphate glasses for radioactive, hazardous and mixed waste immobilization  

DOE Patents (OSTI)

Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole % iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.5 mole % to about 2 mole % iron (III) oxide and from about 3 mole % to about 6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided.

Cao, Hui (Middle Island, NY); Adams, Jay W. (Stony Brook, NY); Kalb, Paul D. (Wading River, NY)

1998-11-24T23:59:59.000Z

414

Glass Formulation Development for INEEL Sodium-Bearing Waste  

SciTech Connect

For about four decades, radioactive wastes have been collected and calcined from nuclear fuels reprocessing at the Idaho Nuclear Technology and Engineering Center (INTEC), formerly Idaho Chemical Processing Plant (ICPP). Over this time span, secondary radioactive wastes have also been collected and stored as liquid from decontamination, laboratory activities, and fuel-storage activities. These liquid wastes are collectively called sodium-bearing wastes (SBW). About 5.7 million liters of these wastes are temporarily stored in stainless steel tanks at the Idaho National Engineering and Environmental Laboratory (INEEL). Vitrification is being considered as an immobilization step for SBW with a number of treatment and disposal options. A systematic study was undertaken to develop a glass composition to demonstrate direct vitrification of INEEL's SBW. The objectives of this study were to show the feasibility of SBW vitrification, not a development of an optimum formulation. The waste composition is relatively high in sodium, aluminum, and sulfur. A specific composition and glass property restrictions, discussed in Section 2, were used as a basis for the development. Calculations based on first-order expansions of selected glass properties in composition and some general tenets of glass chemistry led to an additive (fit) composition (68.69 mass % SiO{sub 2}, 14.26 mass% B{sub 2}O{sub 3}, 11.31 mass% Fe{sub 2}O{sub 3}, 3.08 mass% TiO{sub 2}, and 2.67 mass % Li{sub 2}O) that meets all property restrictions when melted with 35 mass % of SBW on an oxide basis, The glass was prepared using oxides, carbonates, and boric acid and tested to confirm the acceptability of its properties. Glass was then made using waste simulant at three facilities, and limited testing was performed to test and optimize processing-related properties and confirm results of glass property testing. The measured glass properties are given in Section 4. The viscosity at 1150 C, 5 Pa{center_dot}s, is nearly ideal for waste-glass processing in a standard liquid-fed joule-heated melter. The normalized elemental releases by 7-day PCT are all well below 1 g/m{sup 2}, which is a very conservative set point used in this study. The T{sub L}, ignoring sulfate formation, is less than the 1050 C limit. Based on these observations and the reasonable waste loading of 35 mass 0/0, the SBW glass was a prime candidate for further testing. Sulfate salt segregation was observed in all test melts formed from oxidized carbonate precursors. Melts fabricated using SBW simulants suggest that the sulfate-salt segregation seen in oxide and carbonate melts was much less of a problem. The cause for the difference is likely H{sub 2}SO{sub 4} fuming during the boil-down stage of wet-slurry processing. Additionally, some crucible tests with SBW simulant were conducted at higher temperatures (1250 C), which could increase the volatility of sulfate salts. The fate of sulfate during the melting process is still uncertain and should be the topic of future studies. The properties of the simulant glass confirmed those of the oxide and carbonate glass. Corrosion tests on Inconel 690 electrodes and K-3 refractory blocks conducted at INEEL suggest that the glass is not excessively corrosive. Based on the results of this study, the authors recommend that a glass made of 35% SBW simulant (on a mass oxide and halide basis) and 65% of the additive mix (either filled or raw chemical) be used in demonstrating the direct vitrification of INEEL SBW. It is further recommended that a study be conducted to determine the fate of sulfate during glass processing and the tolerance of the chosen melter technology to sulfate salt segregation and corrosivity of the melt.

J.D. Vienna; M.J. Schweiger; D.E. Smith; H.D. Smith; J.V. Crum; D.K. Peeler; I.A. Reamer; C.A. Musick; R.D. Tillotson

1999-08-03T23:59:59.000Z

415

Glass Formulation Development for INEEL Sodium-Bearing Waste  

SciTech Connect

For about four decades, radioactive wastes have been collected and calcined from nuclear fuels reprocessing at the Idaho Nuclear Technology and Engineering Center (INTEC), formerly Idaho Chemical Processing Plant (ICPP). Over this time span, secondary radioactive wastes have also been collected and stored as liquid from decontamination, laboratory activities, and fuel-storage activities. These liquid wastes are collectively called sodium-bearing wastes (SBW). About 5.7 million liters of these wastes are temporarily stored in stainless steel tanks at the Idaho National Engineering and Environmental Laboratory (INEEL). Vitrification is being considered as an immobilization step for SBW with a number of treatment and disposal options. A systematic study was undertaken to develop a glass composition to demonstrate direct vitrification of INEEL's SBW. The objectives of this study were to show the feasibility of SBW vitrification, not a development of an optimum formulation. The waste composition is relatively high in sodium, aluminum, and sulfur. A specific composition and glass property restrictions, discussed in Section 2, were used as a basis for the development. Calculations based on first-order expansions of selected glass properties in composition and some general tenets of glass chemistry led to an additive (fit) composition (68.69 mass % SiO{sub 2}, 14.26 mass% B{sub 2}O{sub 3}, 11.31 mass% Fe{sub 2}O{sub 3}, 3.08 mass% TiO{sub 2}, and 2.67 mass % Li{sub 2}O) that meets all property restrictions when melted with 35 mass % of SBW on an oxide basis, The glass was prepared using oxides, carbonates, and boric acid and tested to confirm the acceptability of its properties. Glass was then made using waste simulant at three facilities, and limited testing was performed to test and optimize processing-related properties and confirm results of glass property testing. The measured glass properties are given in Section 4. The viscosity at 1150 C, 5 Pa{center_dot}s, is nearly ideal for waste-glass processing in a standard liquid-fed joule-heated melter. The normalized elemental releases by 7-day PCT are all well below 1 g/m{sup 2}, which is a very conservative set point used in this study. The T{sub L}, ignoring sulfate formation, is less than the 1050 C limit. Based on these observations and the reasonable waste loading of 35 mass 0/0, the SBW glass was a prime candidate for further testing. Sulfate salt segregation was observed in all test melts formed from oxidized carbonate precursors. Melts fabricated using SBW simulants suggest that the sulfate-salt segregation seen in oxide and carbonate melts was much less of a problem. The cause for the difference is likely H{sub 2}SO{sub 4} fuming during the boil-down stage of wet-slurry processing. Additionally, some crucible tests with SBW simulant were conducted at higher temperatures (1250 C), which could increase the volatility of sulfate salts. The fate of sulfate during the melting process is still uncertain and should be the topic of future studies. The properties of the simulant glass confirmed those of the oxide and carbonate glass. Corrosion tests on Inconel 690 electrodes and K-3 refractory blocks conducted at INEEL suggest that the glass is not excessively corrosive. Based on the results of this study, the authors recommend that a glass made of 35% SBW simulant (on a mass oxide and halide basis) and 65% of the additive mix (either filled or raw chemical) be used in demonstrating the direct vitrification of INEEL SBW. It is further recommended that a study be conducted to determine the fate of sulfate during glass processing and the tolerance of the chosen melter technology to sulfate salt segregation and corrosivity of the melt.

J.D. Vienna; M.J. Schweiger; D.E. Smith; H.D. Smith; J.V. Crum; D.K. Peeler; I.A. Reamer; C.A. Musick; R.D. Tillotson

1999-08-03T23:59:59.000Z

416

Energy transfer kinetics in oxy-fluoride glass and glass-ceramics doped with rare-earth ions  

SciTech Connect

An investigation of donor-acceptor energy transfer kinetics in dual rare earths doped precursor oxy-fluoride glass and its glass-ceramics containing NaYF{sub 4} nano-crystals is reported here, using three different donor-acceptor ion combinations such as Nd-Yb, Yb-Dy, and Nd-Dy. The precipitation of NaYF{sub 4} nano-crystals in host glass matrix under controlled post heat treatment of precursor oxy-fluoride glasses has been confirmed from XRD, FESEM, and transmission electron microscope (TEM) analysis. Further, the incorporation of dopant ions inside fluoride nano-crystals has been established through optical absorption and TEM-EDX analysis. The noticed decreasing trend in donor to acceptor energy transfer efficiency from precursor glass to glass-ceramics in all three combinations have been explained based on the structural rearrangements that occurred during the heat treatment process. The reduced coupling phonon energy for the dopant ions due to fluoride environment and its influence on the overall phonon assisted contribution in energy transfer process has been illustrated. Additionally, realization of a correlated distribution of dopant ions causing clustering inside nano-crystals has also been reported.

Sontakke, Atul D.; Annapurna, K. [Glass Science and Technology Section, CSIR-Central Glass and Ceramic Research Institute, 196, Raja S. C. Mullick Road, Kolkata - 700 032 (India)

2012-07-01T23:59:59.000Z

417

Final Report on Actinide Glass Scintillators for Fast Neutron Detection  

Science Conference Proceedings (OSTI)

This is the final report of an experimental investigation of actinide glass scintillators for fast-neutron detection. It covers work performed during FY2012. This supplements a previous report, PNNL-20854 “Initial Characterization of Thorium-loaded Glasses for Fast Neutron Detection” (October 2011). The work in FY2012 was done with funding remaining from FY2011. As noted in PNNL-20854, the glasses tested prior to July 2011 were erroneously identified as scintillators. The decision was then made to start from “scratch” with a literature survey and some test melts with a non-radioactive glass composition that could later be fabricated with select actinides, most likely thorium. The normal stand-in for thorium in radioactive waste glasses is cerium in the same oxidation state. Since cerium in the 3+ state is used as the light emitter in many scintillating glasses, the next most common substitute was used: hafnium. Three hafnium glasses were melted. Two melts were colored amber and a third was clear. It barely scintillated when exposed to alpha particles. The uses and applications for a scintillating fast neutron detector are important enough that the search for such a material should not be totally abandoned. This current effort focused on actinides that have very high neutron capture energy releases but low neutron capture cross sections. This results in very long counting times and poor signal to noise when working with sealed sources. These materials are best for high flux applications and access to neutron generators or reactors would enable better test scenarios. The total energy of the neutron capture reaction is not the only factor to focus on in isotope selection. Many neutron capture reactions result in energetic gamma rays that require large volumes or high densities to detect. If the scintillator is to separate neutrons from gamma rays, the capture reactions should produce heavy particles and few gamma rays. This would improve the detection of a signal for fast neutron capture.

Bliss, Mary; Stave, Jean A.

2012-10-01T23:59:59.000Z

418

Ancient Glass in the Nuclear Age - Denis Strachan and Joseph Ryan |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ancient Glass in the Nuclear Age - Denis Strachan and Joseph Ryan Ancient Glass in the Nuclear Age - Denis Strachan and Joseph Ryan Ancient Glass in the Nuclear Age - Denis Strachan and Joseph Ryan August 12, 2011 - 12:00pm Addthis Ancient Glass in the Nuclear Age - Denis Strachan and Joseph Ryan PNNL scientists are studying pieces of ancient Roman glass from 1,800-year-old shipwrecks and ruins to assist today's efforts to safely store nuclear waste. One way to store nuclear waste safely is to turn it into durable glass through a process called vitrification. At PNNL, Denis Strachan, Joseph Ryan and others are helping explore how such a glass can withstand the test of time if stored in repositories deep underground. Glass dissolves so slowly that it's difficult to understand changes that might happen over thousands or a million years. Researchers want samples of old glass against

419

Glass Stronger than Steel | U.S. DOE Office of Science (SC)  

NLE Websites -- All DOE Office Websites (Extended Search)

Glass Stronger than Steel Glass Stronger than Steel Stories of Discovery & Innovation Glass Stronger than Steel Enlarge Photo Image courtesy of R. Ritchie and M. Demetriou Highly magnified image shows a sharp crack introduced into palladium-based metallic glass and the extensive plastic shielding, marked by the white shear lines extending out from the crack, prevent the crack from opening the glass any further. Inset is a magnified view of the shear lines (arrow) developed during plastic sliding. 03.28.11 Glass Stronger than Steel A new type of damage-tolerant metallic glass, demonstrating a strength and toughness beyond that of steel or any other known material, has been developed and tested by a collaboration of researchers from Berkeley Lab and Caltech. Drop a glass and it breaks, right? But there's a kind of glass that while

420

Development of Crystal-Tolerant High-Level Waste Glasses  

SciTech Connect

Twenty five glasses were formulated. They were batched from HLW AZ-101 simulant or raw chemicals and melted and tested with a series of tests to elucidate the effect of spinel-forming components (Ni, Fe, Cr, Mn, and Zn), Al, and noble metals (Rh2O3 and RuO2) on the accumulation rate of spinel crystals in the glass discharge riser of the high-level waste (HLW) melter. In addition, the processing properties of glasses, such as the viscosity and TL, were measured as a function of temperature and composition. Furthermore, the settling of spinel crystals in transparent low-viscosity fluids was studied at room temperature to access the shape factor and hindered settling coefficient of spinel crystals in the Stokes equation. The experimental results suggest that Ni is the most troublesome component of all the studied spinel-forming components producing settling layers of up to 10.5 mm in just 20 days in Ni-rich glasses if noble metals or a higher concentration of Fe was not introduced in the glass. The layer of this thickness can potentially plug the bottom of the riser, preventing glass from being discharged from the melter. The noble metals, Fe, and Al were the components that significantly slowed down or stopped the accumulation of spinel at the bottom. Particles of Rh2O3 and RuO2, hematite and nepheline, acted as nucleation sites significantly increasing the number of crystals and therefore decreasing the average crystal size. The settling rate of ?10-?m crystal size around the settling velocity of crystals was too low to produce thick layers. The experimental data for the thickness of settled layers in the glasses prepared from AZ-101 simulant were used to build a linear empirical model that can predict crystal accumulation in the riser of the melter as a function of concentration of spinel-forming components in glass. The developed model predicts the thicknesses of accumulated layers quite well, R2 = 0.985, and can be become an efficient tool for the formulation of the crystal-tolerant HLW glasses for higher waste loading. A physical modeling effort revealed that the Stokes and Richardson-Zaki equations can be used to adequately predict the accumulation rate of spinel crystals of different sizes and concentrations in the glass discharge riser of HLW melters. The determined shape factor for the glass beads was only 0.73% lower than the theoretical shape factor for a perfect sphere. The shape factor for the spinel crystals matched the theoretically predicted value to within 10% and was smaller than that of the beads, given the larger drag force caused by the larger surface area-to-volume ratio of the octahedral crystals. In the hindered settling experiments, both the glass bead and spinel suspensions were found to follow the predictions of the Richardson-Zaki equation with the exponent n = 3.6 and 2.9 for glass beads and spinel crystals, respectively.

Matyas, Josef; Vienna, John D.; Schaible, Micah J.; Rodriguez, Carmen P.; Crum, Jarrod V.; Arrigoni, Alyssa L.; Tate, Rachel M.

2010-12-17T23:59:59.000Z

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421

Energy Saving Glass Lamination via Selective Radio Frequency Heating  

SciTech Connect

This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North America. The second task dealt with a study of current lamination processes in the various laminate industries, and development of concepts for integrating RF lamination into new or existing processes. The third task explored the use of a non-destructive technique for analyzing laminate adhesion with the University of Illinois at Urbana-Champaign. The fourth task focused on developing concepts for curved glass lamination using RF lamination. The fifth and sixth tasks together comprised an analysis of laminate product markets, ranking for applicability and commercialization potential, and the development of commercialization strategies for those products. In addition, throughout the project as new experimental data and conventional process data were obtained, the benefits analysis of RF lamination was refined. The goals of the project described above were achieved, positioning RF lamination for the next stage growth envisioned in the original Industrial Grand Challenge proposal. Working with Pilkington North America, lamination of flat autoglass with PVB was achieved, meeting all 16 stringent industry tests. In particular, PVB laminates made with RF lamination passed environmental tests including the high temperature, 120 C bake test, without significant formation of bubbles (defects). The adhesion of PVB to glass was measured using the pummel method. Adhesion values ranging from 1 to 7 out of 10 were obtained. The significant process parameters affecting the environmental and adhesion performance were identified through a designed experiment. Pre-lamination process variables including PVB storage humidity and the de-airing process (vacuum or nip rolling) were significant, as well as the level of pressure applied to the laminate during the RF process. Analysis of manufacturing with RF lamination equipment, based on the processes developed indicated that 3 RF presses could replace a typical auto-industry autoclave to achieve equal or greater throughput with possibly less capital cost and smaller footprint. Concepts for curved lamination identifying castable molds for

Allan, Shawn M.

2012-02-27T23:59:59.000Z

422

Energy Saving Glass Lamination via Selective Radio Frequency Heating  

SciTech Connect

This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North America. The second task dealt with a study of current lamination processes in the various laminate industries, and development of concepts for integrating RF lamination into new or existing processes. The third task explored the use of a non-destructive technique for analyzing laminate adhesion with the University of Illinois at Urbana-Champaign. The fourth task focused on developing concepts for curved glass lamination using RF lamination. The fifth and sixth tasks together comprised an analysis of laminate product markets, ranking for applicability and commercialization potential, and the development of commercialization strategies for those products. In addition, throughout the project as new experimental data and conventional process data were obtained, the benefits analysis of RF lamination was refined. The goals of the project described above were achieved, positioning RF lamination for the next stage growth envisioned in the original Industrial Grand Challenge proposal. Working with Pilkington North America, lamination of flat autoglass with PVB was achieved, meeting all 16 stringent industry tests. In particular, PVB laminates made with RF lamination passed environmental tests including the high temperature, 120 ���°C bake test, without significant formation of bubbles (defects). The adhesion of PVB to glass was measured using the pummel method. Adhesion values ranging from 1 to 7 out of 10 were obtained. The significant process parameters affecting the environmental and adhesion performance were identified through a designed experiment. Pre-lamination process variables including PVB storage humidity and the de-airing process (vacuum or nip rolling) were significant, as well as the level of pressure applied to the laminate during the RF process. Analysis of manufacturing with RF lamination equipment, based on the processes developed indicated that 3 RF presses could replace a typical auto-industry autoclave to achieve equal or greater throughput with possibly less capital cost and smaller footprint. Concepts for curved lamination id

Allan, Shawn M.; Baranova, Inessa; Poley, Joseph; Reis, Henrique

2012-02-27T23:59:59.000Z

423

Integrated Disposal Facility FY2010 Glass Testing Summary Report  

SciTech Connect

Pacific Northwest National Laboratory was contracted by Washington River Protection Solutions, LLC to provide the technical basis for estimating radionuclide release from the engineered portion of the disposal facility (e.g., source term). Vitrifying the low-activity waste at Hanford is expected to generate over 1.6 × 105 m3 of glass (Puigh 1999). The volume of immobilized low-activity waste (ILAW) at Hanford is the largest in the DOE complex and is one of the largest inventories (approximately 0.89 × 1018 Bq total activity) of long-lived radionuclides, principally 99Tc (t1/2 = 2.1 × 105), planned for disposal in a low-level waste (LLW) facility. Before the ILAW can be disposed, DOE must conduct a performance assessement (PA) for the Integrated Disposal Facility (IDF) that describes the long-term impacts of the disposal facility on public health and environmental resources. As part of the ILAW glass testing program PNNL is implementing a strategy, consisting of experimentation and modeling, in order to provide the technical basis for estimating radionuclide release from the glass waste form in support of future IDF PAs. The purpose of this report is to summarize the progress made in fiscal year (FY) 2010 toward implementing the strategy with the goal of developing an understanding of the long-term corrosion behavior of low-activity waste glasses. The emphasis in FY2010 was the completing an evaluation of the most sensitive kinetic rate law parameters used to predict glass weathering, documented in Bacon and Pierce (2010), and transitioning from the use of the Subsurface Transport Over Reactive Multi-phases to Subsurface Transport Over Multiple Phases computer code for near-field calculations. The FY2010 activities also consisted of developing a Monte Carlo and Geochemical Modeling framework that links glass composition to alteration phase formation by 1) determining the structure of unreacted and reacted glasses for use as input information into Monte Carlo calculations, 2) compiling the solution data and alteration phases identified from accelerated weathering tests conducted with ILAW glass by PNNL and Viteous State Laboratory/Catholic University of America as well as other literature sources for use in geochemical modeling calculations, and 3) conducting several initial calculations on glasses that contain the four major components of ILAW-Al2O3, B2O3, Na2O, and SiO2.

Pierce, Eric M.; Bacon, Diana H.; Kerisit, Sebastien N.; Windisch, Charles F.; Cantrell, Kirk J.; Valenta, Michelle M.; Burton, Sarah D.; Serne, R Jeffrey; Mattigod, Shas V.

2010-09-30T23:59:59.000Z

424

Vacuum fusion bonded glass plates having microstructures thereon  

DOE Patents (OSTI)

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2001-01-01T23:59:59.000Z

425

Radiation Effects on Transport and Bubble Formation in Silicate Glasses  

DOE Green Energy (OSTI)

Using advanced magnetic resonance spectroscopies and small-cluster modeling, atomic structure of radiation-induced point defects in alkali borate, silicate, and borosilicate glasses is fully characterized. It is shown that in boron-containing glasses, most of these point defects are electrons/holes trapped by cation/anion vacancies, such as O1 - - O3 + valence-alternation pairs. In microscopically phase-separated borosilicate glasses, radiation-induced defects are found to cluster at the interface between the borate and silicate phases. Reaction and diffusion dynamics of defect-annealing interstitial hydrogen atoms in boron and silica oxide glasses are studied. The yield of radiolytic O2 is estimated. This oxygen is shown to be the final product of triplet exciton decay. Plausible mechanisms for the oxygen bubble formation are put forward. Two practical conclusions relevant for the EMSP mission are made: First, the yield of radiolytic oxygen is shown to be too low to interfere with the storage of vitrified radioactive waste in the first 10 Kyr. Second, microscopic phase separation is demonstrated to increase both the chemical and radiation stability of borosilicate glass.

Trifunac, A.D.; Shkrob, I.A.; Werst, D.W.

2001-12-31T23:59:59.000Z

426

Evaluation of cellular glasses for solar mirror panel applications  

DOE Green Energy (OSTI)

An analytic technique is developed to compare the structural and environmental performance of various materials considered for backing of second surface glass solar mirrors. Metals, ceramics, dense molded plastics, foamed plastics, forest products and plastic laminates are surveyed. Cellular glass is determined to be a prime candidate due to its low cost, high stiffness-to-weight ratio, thermal expansion match to mirror glass, evident minimal environmental impact and chemical and dimensional stability under conditions of use. While applications could employ this material as a foam core or compressive member of a composite material system, the present analysis addresses the bulk material only, allowing a basis for simple extrapolations. The current state of the art and anticipated developments in cellular glass technology are discussed. Material properties are correlated to design requirements using a Weibull weakest link statistical method appropriate for describing the behavior of such brittle materials. A mathematical model is presented which suggests a design approach which allows minimization of life cycle cost; given adequate information for a specific aplication, this would permit high confidence estimates of the cost/performance factor. A mechanical and environmental testing program is outlined, designed to providea material property basis for development of cellular glass hardware, together with methodology for collecting lifetime predictive data required by the mathematical treatment provided herein. Preliminary material property data from measurements is given.

Giovan, M.; Adams, M.

1979-06-15T23:59:59.000Z

427

Final Report - Glass Formulation Development and DM10 Melter Testing with ORP LAW Glasses, VSL-09R1510-2, Rev. 0, dated 6/12/09  

SciTech Connect

The principal objective of the work described in this Final Report is to extend the glass formulation methodology developed in the earlier work by development of acceptable glass compositions for four LAW compositions specified by ORP that cover the range of sulfate to sodium and potassium to sodium ratios expected in Hanford LAW. The glass formulations were designed to exclude titanium and iron as glass former additives, while tin and vanadium as glass former additives were evaluated for beneficial effects in increasing waste loading in the glasses. This was accomplished through a combination of crucible-scale tests and tests on the DM10 melter system. This melter is the most efficient melter platform for screening glass compositions over a wide range of sulfate concentrations and therefore was selected for the present tests. The current tests provide information on melter processing characteristics and off-gas data, including sulfur incorporation and partitioning.

Kruger, Albert A.; Pegg, I. L.; Matlack, K. S.; Joseph, I.; Muller, I. S.; Gong, W.

2013-11-13T23:59:59.000Z

428

Metallic Glass Yields Secrets under Pressure | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Structure of the "Swine Flu" Virus Structure of the "Swine Flu" Virus The Package Matters Disarming Deadly South American Hemorrhagic Fever Viruses Pull-Chain "Polymer" Solves Puzzle of Complex Molecular Packing Discovering New Talents for Diamond Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Metallic Glass Yields Secrets under Pressure MARCH 29, 2010 Bookmark and Share Diamond anvil cell used for high-pressure experiments Metallic glasses are emerging as potentially useful materials at the frontier of materials science research. They combine the advantages-and avoid many of the problems of-normal metals and glasses, two classes of materials with a very wide range of applications. For example, metallic

429

Observations of Nuclear Explosive Melt Glass Textures and Surface Areas  

Science Conference Proceedings (OSTI)

This memo report summarizes our current knowledge of the appearance of melt glass formed and subsequently deposited in the subsurface after an underground nuclear test. We have collected archived pictures and melt glass samples from a variety of underground nuclear tests that were conducted at the Nevada Test Site (NTS) during the U.S. nuclear testing program. The purpose of our work is to better determine the actual variation in texture and surface area of the melt glass material. This study is motivated by our need to better determine the rate at which the radionuclides incorporated in the melt glass are released into the subsurface under saturated and partially saturated conditions. The rate at which radionuclides are released from the glass is controlled by the dissolution rate of the glass. Glass dissolution, in turn, is a strong function of surface area, glass composition, water temperature and water chemistry (Bourcier, 1994). This work feeds into an ongoing experimental effort to measure the change in surface area of analog glasses as a function of dissolution rate. The conclusions drawn from this study help bound the variation in the textures of analog glass samples needed for the experimental studies. The experimental work is a collaboration between Desert Research Institute (DRI) and Earth and Environmental Sciences-Lawrence Livermore National Laboratory (EES-LLNL). On March 4, 1999 we hosted a meeting at LLNL to present and discuss our findings. The names of the attendees appear at the end of this memo. This memo report further serves to outline and summarize the conclusions drawn from our meeting. The United States detonated over 800 underground nuclear tests at the NTS between 1951 and 1992. In an effort to evaluate the performance of the nuclear tests, drill-back operations were carried out to retrieve samples of rock in the vicinity of the nuclear test. Drill-back samples were sent to Los Alamos National Laboratory (LANL) and Lawrence Livermore National Laboratory (LLNL) and analyzed for diagnostic purposes. As a result of these activities, a body of knowledge consisting of personal accounts, photos, reports and archived solid samples was gained regarding the physical nature of the melt glass that formed during an underground nuclear test. In this memo report, we summarize previously published reports, compile archived photos, document and describe melt glass samples and summarized discussions from former field engineers and radiochemists who had direct knowledge of drill-back samples. All the information presented in the report was gathered from unclassified sources. We have included as wide a variation of samples as we could document. Unfortunately, as part of the drill-back and diagnostic efforts, it was not common practice to photograph or physically describe the material returned to the surface.

Kersting, A B; Smith, D K

2006-01-17T23:59:59.000Z

430

Method of forming crystalline silicon devices on glass  

DOE Patents (OSTI)

A method for fabricating single-crystal silicon microelectronic components on a silicon substrate and transferring same to a glass substrate. This is achieved by utilizing conventional silicon processing techniques for fabricating components of electronic circuits and devices on bulk silicon, wherein a bulk silicon surface is prepared with epitaxial layers prior to the conventional processing. The silicon substrate is bonded to a glass substrate and the bulk silicon is removed leaving the components intact on the glass substrate surface. Subsequent standard processing completes the device and circuit manufacturing. This invention is useful in applications requiring a transparent or insulating substrate, particularly for display manufacturing. Other applications include sensors, actuators, optoelectronics, radiation hard electronics, and high temperature electronics.

McCarthy, Anthony M. (Menlo Park, CA)

1995-01-01T23:59:59.000Z

431

LOW VELOCITY SHPERE IMPACT OF SODA LIME SILICATE GLASS  

Science Conference Proceedings (OSTI)

This report summarizes TARDEC-sponsored work at Oak Ridge National Laboratory (ORNL) during the FY11 involving low velocity ( 30 m/s or 65 mph) ball impact testing of Starphire soda lime silicate glass. The intent was to better understand low velocity impact response in the Starphire for sphere densities that bracketed that of rock. Five sphere materials were used: borosilicate glass, soda-lime silicate glass, steel, silicon nitride, and alumina. A gas gun was fabricated to produce controlled velocity delivery of the spheres against Starphire tile targets. Minimum impact velocities to initiate fracture in the Starphire were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between the any of the five sphere-Starphire-target combinations.

Morrissey, Timothy G [ORNL; Fox, Ethan E [ORNL; Wereszczak, Andrew A [ORNL; Vuono, Daniel J [ORNL

2012-01-01T23:59:59.000Z

432

A modeling study on the thermomechanical behavior of glass-ceramic and self-healing glass seals at elevated temperatures  

Science Conference Proceedings (OSTI)

Hermetic gas seals are critical components for planar solid oxide fuel cells. This article focuses on comparative evaluation of a glass-ceramic developed by the Pacific Northwest National Laboratory (PNNL) and a self-healing glass seal developed by the University of Cincinnati. The stress and strain levels in the Positive electrode-Electrolyte-Negative electrode (PEN) seal in one cell stack are evaluated using a multi-physics simulation package developed at PNNL. Simulations were carried out with and without consideration of clamping force and stack body force, respectively. The results indicate that the overall stress and strain levels are dominated by the thermal expansion mismatches between the different cell components. Further, compared with glass-ceramic seal, the self-healing glass seal results in much lower steady state stress due to its much lower stiffness at the operating temperature of SOFC, and also exhibits much shorter relaxation times due to high creep rate. It is also noted that the self-healing glass seal will experience continuing creep deformation under the operating temperature of SOFC therefore resulting in possible overflow of the sealing materials. Further stopper material may need to be added to maintain its geometric stability during operation.

Govindaraju, Nirmal; Liu, Wenning N.; Sun, Xin; Singh, Prabhakar; Singh, R.

2009-05-15T23:59:59.000Z

433

Hydrogen transport and storage in engineered glass microspheres  

DOE Green Energy (OSTI)

New, high-strength, hollow, glass microspheres filled with pressurized hydrogen exhibit storage densities which make them attractive for bulk hydrogen storage and transport. The hoop stress at failure of our engineered glass microspheres is about 150,000 psi, permitting a three-fold increase in pressure limit and storage capacity above commercial microspheres, which fail at wall stresses of 50,000 psi. For this project, microsphere material and structure will be optimized for storage capacity and charge/discharge kinetics to improve their commercial practicality. Microsphere production scale up will be performed, directed towards large-scale commercial use. Our analysis relating glass microspheres for hydrogen transport with infrastructure and economics` indicate that pressurized microspheres can be economically competitive with other forms of bulk rail and truck transport such as hydride beds, cryocarbons and pressurized tube transports. For microspheres made from advanced materials and processes, analysis will also be performed to identify the appropriate applications of the microspheres considering property variables, and different hydrogen infrastructure, end use, production and market scenarios. This report presents some of the recent modelling results for large beds of glass microspheres in hydrogen storage applications. It includes plans for experiments to identify the properties relevant to large-bed hydrogen transport and storage applications, of the best, currently producible, glass microspheres. This work began in March, 1994. Project successes will be manifest in the matching of cur-rent glass microspheres with a useful application in hydrogen bulk transport and storage, and in developing microsphere materials and processes that increase the storage density and reduce the storage energy requirement.

Rambach, G.D.

1994-04-20T23:59:59.000Z

434

Adhesion Strength Study of EVA Encapsulants on Glass Substrates  

DOE Green Energy (OSTI)

An extensive peel-test study was conducted to investigate the various factors that may affect the adhesion strength of photovoltaic module encapsulants, primarily ethylene-vinyl acetate (EVA), on glass substrates of various laminates based on a common configuration of glass/encapsulant/backfoil. The results show that"pure" or"absolute" adhesion strength of EVA-to-glass was very difficult to obtain because of tensile deformation of the soft, semi-elastic EVA layer upon pulling. A mechanically"strong enough" backing foil on the EVA was critical to achieving the"apparent" adhesion strength. Peel test method with a 90-degree-pull yielded similar results to a 180-degree-pull. The 90-degree-pull method better revealed the four stages of delamination failure of the EVA/backfoil layers. The adhesion strength is affected by a number of factors, which include EVA type, formulation, backfoil type and manufacturing source, glass type, and surface priming treatment on the glass surface or on the backfoil. Effects of the glass-cleaning method and surface texture are not obvious. Direct priming treatments used in the work did not improve, or even worsened, the adhesion. Aging of EVA by storage over~5 years reduced notably the adhesion strength. Lower adhesion strengths were observed for the blank (unformulated) EVA and non-EVA copolymers, such as poly(ethylene-co-methacrylate) (PEMA) or poly(ethylene-co-butylacrylate) (PEBA). Their adhesion strengths increased if the copolymers were cross-linked. Transparent fluoropolymer superstrates such as TefzelTM and DureflexTM films used for thin-film PV modules showed low adhesion strengths to the EVA at a level of~2 N/mm.

Pern, F. J.; Glick, S. H.

2003-05-01T23:59:59.000Z

435

Flat Glass Manufacturing Plant EPI | ENERGY STAR Buildings & Plants  

NLE Websites -- All DOE Office Websites (Extended Search)

Flat Glass Manufacturing Plant EPI Flat Glass Manufacturing Plant EPI Secondary menu About us Press room Contact Us Portfolio Manager Login Facility owners and managers Existing buildings Commercial new construction Industrial energy management Small business Service providers Service and product providers Verify applications for ENERGY STAR certification Design commercial buildings Energy efficiency program administrators Commercial and industrial program sponsors Associations State and local governments Federal agencies Tools and resources Training In This Section Campaigns Commercial building design Communications resources Energy management guidance Financial resources Portfolio Manager Products and purchasing Recognition Research and reports Service and product provider (SPP) resources Success stories Target Finder

436

Ion-Exchange Processes and Mechanisms in Glasses  

DOE Green Energy (OSTI)

Leaching of alkalis from glass is widely recognized as an important mechanism in the initial stages of glass-water interactions. Pioneering experimental studies [1-3] nearly thirty-five years ago established that alkali (designated as M{sup +}) are lost to solution more rapidly than network-forming cations. The overall chemical reaction describing the process can be written as: {triple_bond}Si-O-M + H{sup +} {yields} {triple_bond}Si-OH + M{sup +} (1) or {triple_bond}Si-O-M + H{sub 3}O{sup +} {yields} {triple_bond}Si-OH + M{sup +} + H{sub 2}O. (2) Doremus and coworkers [4-7] fashioned a quantitative model where M{sup +} ions in the glass are exchanged for counter-diffusing H{sub 3}O{sup +} or H{sup +}. Subsequent investigations [8], which have relied heavily on reaction layer analysis, recognized the role of H{sub 2}O molecules in the alkali-exchange process, without minimizing the importance of charged hydrogen species. Beginning in the 1980s, however, interest in M{sup +}-H{sup +} exchange reactions in silicate glasses diminished considerably because important experimental observations showed that network hydrolysis and dissolution rates were principally controlled by the chemical potential difference between the glass and solution (chemical affinity) [9]. For nuclear waste glasses, formation of alteration products or secondary phases that remove important elements from solution, particularly Si, was found to have very large impacts on glass dissolution rates [10,11]. Consequently, recent work on glass/water interactions has focused on understanding this process and incorporating it into models [12]. The ion-exchange process has been largely ignored because it has been thought to be a short duration, secondary or tertiary process that had little or no bearing on long-term corrosion or radionuclide release rates from glasses [13]. The only significant effect identified in the literature that is attributed to alkali ion exchange is an increase in solution pH in static laboratory tests conducted at high surface area-to-volume ratios [14,15]. Renewed interest in alkali ion exchange reactions has come about because of interest in development of durable Na-rich silicate glasses for immobilization of low-activity waste (LAW) at Hanford, Washington [16] and high-level wastes in China [17]. In reactive transport simulations of a LAW glass disposed in a shallow subsurface facility, Chen, McGrail, and Engel [18] showed that ion-exchange reactions increased the radionuclide release rate by over two orders of magnitude when compared with simulations where ion exchange was excluded. Sheng, Luo, and Tang [17] conducted static tests in a simulated groundwater and showed that alkali ion exchange was the dominant release mechanism over a large temperature range. Although the significance of alkali ion exchange reactions in long-term disposal system performance has now been recognized, the fundamental processes and mechanisms controlling the exchange reactions are still remarkably poorly understood, especially with regard to how glass structure affects alkali ion exchange kinetics. Experimental studies of Na release from various simple silicate glasses are numerous [19-23]. However, in all previous studies of which we are aware, no attempt was made to distinguish between M{sup +} release through alkali exchange versus matrix dissolution. The release rate of alkali in all of the early work was convoluted by contributions from matrix dissolution, which dominates in dilute solutions. Also, none of the previous studies attempted to define the relationship, if any, between glass structure (composition) and the kinetics of the ion exchange reaction. The motivation behind this Environmental Management Science Project (EMSP) is to develop a better understanding of how glass structure impacts sodium ion exchange so that improved glasses can be developed. Development of low ion-exchange rate glasses may also permit engineers to use higher loadings in nuclear waste glasses, which would result in substantial savings in production and disposal costs.

McGrail, B.P.; Icenhower, J.P.; Darab, J.G.; Shuh, D.k.; Baer, D.R.; Shutthanandan, V.; Thevuthasan, S.; Engelhard, M.H.; Steele, J.L.; Rodriguez, E.A.; Liu, P.; Ivanov, K.E.; Booth, C.H.; Nachimuthu, P.

2001-12-31T23:59:59.000Z

437

Thermally efficient melting and fuel reforming for glass making  

DOE Patents (OSTI)

An integrated process is described for utilizing waste heat from a glass making furnace. The hot off-gas from the furnace is initially partially cooled, then fed to a reformer. In the reformer, the partially cooled off-gas is further cooled against a hydrocarbon which is thus reformed into a synthesis gas, which is then fed into the glass making furnace as a fuel. The further cooled off-gas is then recycled back to absorb the heat from the hot off-gas to perform the initial cooling. 2 figures.

Chen, M.S.; Painter, C.F.; Pastore, S.P.; Roth, G.S.; Winchester, D.C.

1991-10-15T23:59:59.000Z

438

A simple monatomic ideal glass former: the glass transition by a first-order phase transition above the melting point  

E-Print Network (OSTI)

A liquid can form under cooling a glassy state either as a result of a continuous slowing down or by a first order polyamorphous phase transition. The second scenario has so far always been observed below the melting point where it interfered with crystalline nucleation. We report the first observation of the liquid-glass transition by a first order phase transition above the melting point. The observation was made in a molecular dynamics simulation of a one-component system with a model metallic pair potential. This is also the first observation of a simple monatomic ideal glass former -- a liquid that avoids crystallization at any cooling rate. Besides its conceptual importance, this result indicates a possibility of existence of metallic ideal glass formers.

Måns Elenius; Tomas Oppelstrup; Mikhail Dzugutov

2010-04-15T23:59:59.000Z

439

Comparison of glass surfaces as a countertop material to existing surfaces  

SciTech Connect

Gleen Glass, a small production glass company that creates countertops, was selected for the Technology Assistance Program through Pacific Northwest National Laboratory. Gleen Glass was seeking material property analysis comparing glass as a countertop material to current surfaces (i.e. marble, granite and engineered stone). With samples provided from Gleen Glass, testing was done on granite, marble, and 3 different glass surfaces ('Journey,' 'Pebble,' and 'Gleen'). Results showed the glass surfaces have a lower density, lower water absorption, and are stronger in compressive and flexural tests as compared to granite and marble. Thermal shock tests showed the glass failed when objects with a high thermal mass are placed directly on them, whereas marble and granite did not fracture under these conditions.

Turo, Laura A.; Winschell, Abigail E.

2011-09-01T23:59:59.000Z

440

Amorphous Metallic Glass as New High Power and Energy Density Anodes For Lithium Ion Rechargeable Batteries  

E-Print Network (OSTI)

We have investigated the use of aluminum based amorphous metallic glass as the anode in lithium ion rechargeable batteries. Amorphous metallic glasses have no long-range ordered microstructure; the atoms are less closely ...

Meng, Shirley Y.

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
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441

High-Power Solid-State Lasers from a Laser Glass Perspective  

Science Conference Proceedings (OSTI)

Advances in laser glass compositions and manufacturing have enabled a new class of high-energy/high-power (HEHP), petawatt (PW) and high-average-power (HAP) laser systems that are being used for fusion energy ignition demonstration, fundamental physics research and materials processing, respectively. The requirements for these three laser systems are different necessitating different glasses or groups of glasses. The manufacturing technology is now mature for melting, annealing, fabricating and finishing of laser glasses for all three applications. The laser glass properties of major importance for HEHP, PW and HAP applications are briefly reviewed and the compositions and properties of the most widely used commercial laser glasses summarized. Proposed advances in these three laser systems will require new glasses and new melting methods which are briefly discussed. The challenges presented by these laser systems will likely dominate the field of laser glass development over the next several decades.

Campbell, J H; Hayden, J S; Marker, A J

2010-12-17T23:59:59.000Z

442

Phase Equilibria and Glass Formation Studies in the TeO 2  

Science Conference Proceedings (OSTI)

Abstract Scope, Sodium-tellurite glasses are of great interest due to their ... Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass ... Mechanisms of the Conversion Reaction in FeF2 Cathodes Exposed to Li in High

443

SP-29: Oxidation Behavior of Zr56Al16Co28 Metallic Glasses  

Science Conference Proceedings (OSTI)

Abstract Scope, The oxidation behavior of Zr56A16Co28 bulk metallic glass was ... A high resistance against oxidation in Zr56Al16Co28 bulk metallic glasses ...

444

LiDAR At Glass Buttes Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

LiDAR At Glass Buttes Area (DOE GTP) Exploration Activity Details Location Glass Buttes Area Exploration Technique LiDAR Activity Date Usefulness not indicated DOE-funding Unknown...

445

Expanded High-Level Waste Glass Property Data Development: Phase I  

Science Conference Proceedings (OSTI)

Two separate test matrices were developed as part if the EM-21 Glass Matrix Crucible Testing. The first matrix, developed using a single component-at-a-time design method and covering glasses of interest primarily to Hanford, is addressed in this data package. This data package includes methods and results from glass fabrication, chemical analysis of glass compositions, viscosity, electrical conductivity, liquidus temperature, canister centerline cooling, product consistency testing, and the toxicity characteristic leach procedure.

Schweiger, Michael J.; Riley, Brian J.; Crum, Jarrod V.; Hrma, Pavel R.; Rodriguez, Carmen P.; Arrigoni, Benjamin M.; Lang, Jesse B.; Kim, Dong-Sang; Vienna, John D.; Raszewski, F. C.; Peeler, David K.; Edwards, Tommy B.; Best, D. R.; Reamer, Irene A.; Riley, W. T.; Simmons, P. T.; Workman, R. J.

2011-01-21T23:59:59.000Z

446

GLASS FABRICATION AND ANALYSIS LITERATURE REVIEW AND METHOD SELECTION FOR WTP WASTE FEED QUALIFICATION  

SciTech Connect

Scope of the Report The objective of this literature review is to identify and review documents to address scaling, design, operations, and experimental setup, including configuration, data collection, and remote handling that would be used during waste feed qualification in support of the glass fabrication unit operation. Items addressed include: ? LAW and HLW glass formulation algorithms; ? Mixing and sampling; ? Rheological measurements; ? Heat of hydration; ? Glass fabrication techniques; ? Glass inspection; ? Composition analysis; ? Use of cooling curves; ? Hydrogen generation rate measurement.

Peeler, D.

2013-06-27T23:59:59.000Z

447

A Brief Introduction to the Color Glass Condensate and the Glasma  

E-Print Network (OSTI)

I provide a brief introduction to the theoretical ideas and phenomenological motivation for the Color Glass Condensate and the Glasma

Larry McLerran

2008-12-29T23:59:59.000Z

448

Energy Efficiency Improvement and Cost Saving Opportunities for the Glass Industry. An ENERGY STAR Guide for Energy and Plant Managers  

E-Print Network (OSTI)

training. Target Group: Industries in Wisconsin Format: OpenU.S. Glass Container Industry. International Glass Review,Study on Energy Efficiency in Industry, Rye Brook, New York.

Worrell, Ernst

2008-01-01T23:59:59.000Z

449

Thermo-mechanical Properties of Na2O-TiO2-SiO2 Glasses  

Science Conference Proceedings (OSTI)

Ion Exchanged Mixed Glass Cullet Proppants for Stimulation of Oil and Natural Gas Bearing Shales · Modeling the Electrical Conductivity in Glass Melts.

450

Application of glass technology to novel solar energy collectors  

DOE Green Energy (OSTI)

Various compound parabolic concentrator (CPC) configurations are discussed, and the application of glass technology to CPC designs is discussed. CPC designs with flat absorbers, cylindrical absorbers, evacuated receivers, and evacuated tube receivers are considered. Also a floodlamp collector concept and a fluorescent tube collector concept are discussed. (WHK)

Reed, K A

1979-01-01T23:59:59.000Z

451

Fractal nature of medium-range order in metallic glasses  

Science Conference Proceedings (OSTI)

The atomic structure of metallic glasses has been a long-standing scientific mystery. Unlike crystalline metals, where long-range ordering is established by periodic stacking of fundamental building blocks known as unit cells, a metallic glass has no long-range translational order, although some degrees of short- and medium-range order do exist.1,2,3 Previous studies1,2,3,4 have identified solute-centered clusters, characterized by short-range order (SRO) in favor of unlike bonds, as the fundamental building blocks of metallic glasses. However, how these building blocks are connected or packed to form the medium range order (MRO) remains an open question.1,2,3 Here, based on neutron and x-ray diffraction experiments, we propose a new packing scheme - the self-similar packing of atomic clusters. We show that MRO has the characteristics of a fractal network with a dimension of 2.38, and is described by a power-law correlation function over the medium-range length scale. Our finding provides a new prospective of order in disordered materials and has broad implications for understanding the structure-property relationship in metallic glasses, particularly those involving change in length scales due to phase transformation and mechanical deformation.

Ma, Dong [ORNL; Stoica, Alexandru Dan [ORNL; Wang, Xun-Li [ORNL

2009-01-01T23:59:59.000Z

452

Efficient wide-aperture neodymium glass rod amplifiers  

SciTech Connect

Amplifiers based on neodymium phosphate glass rods 60 - 100 mm in diameter are experimentally studied. The amplifiers are pumped by INP-16/250 tubular flash lamps placed in a universal pump cavity with a two-section mirror reflector. A compact high-voltage capacitive energy storage with a preionisation circuit was developed to supply the lamps. (lasers)

Potemkin, A K; Zhurin, K A; Kirsanov, A V; Kopelovich, E A; Kuznetsov, M V; Kuz'min, A A; Flat, F A; Khazanov, Efim A; Shaikin, A A [Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod (Russian Federation)

2011-06-30T23:59:59.000Z

453

FABRICATION OF GAS-FILLED TUNGSTEN-COATED GLASS SHELLS  

SciTech Connect

OAK-B135 Deuterium (D{sub 2}) filled glass shells coated with a high Z element are needed for high energy density (HED) experiments by researchers at Los Alamos National Laboratory. They report here on our initial attempt to produce such shells. Glass shells made using the drop tower technique were coated with gold, palladium or tungsten, or a mixture of two of these elements. It was found that gold and palladium coatings did not stick well to the glass and resulted in poor or delaminated films. Tungsten coatings resulted in films suitable for these targets. Bouncing of shells during coating resulted in uniform tungsten coatings, but the surface of such coatings were filled with small nodules. Proper agitation of shells using a tapping technique resulted in smooth films with minimal particulate contamination. For coating rates of {approx} 0.15 {micro}m/hr coatings with {approx} 2 nm RMS surface finish could be deposited. The surface roughness of coatings at higher rates, 0.7 {micro}m/hr, was considerably worse ({approx} 100 nm RMS). The columnar structure of the coatings allowed permeation filling of the tungsten coated glass shells with deuterium at 300 C.

NIKROO,A; BAUGH,W; STEINMAN,D.A

2003-06-01T23:59:59.000Z

454

Iron Phosphate Glass-Containing Hanford Waste Simulant  

SciTech Connect

Resolution of the nation’s high level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron phosphate-based glass with a selected waste composition that is high in sulfates (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis as related to the implementation of phosphate-based glasses for Hanford low activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, and Mo-Sci Corporation.

Sevigny, Gary J.; Kimura, Marcia L.; Fischer, Christopher M.; Schweiger, Michael J.; Kim, Dong-Sang

2011-08-01T23:59:59.000Z

455

Mechanical and Acoustic Studies of Deep Ocean Glass Sphere Implosions  

E-Print Network (OSTI)

Mechanical and Acoustic Studies of Deep Ocean Glass Sphere Implosions P. W. Gorham, M. Rosen, J. W of the instrument package and therefore no knowledge of the cause of the loss. Because the failure rate mooring and the electro-optical power and teleme- try riser cables for survival in the event of implosion

Learned, John

456

Interaction Flip Identities for non Centered Spin Glasses  

E-Print Network (OSTI)

We consider spin glass models with non-centered interactions and investigate the effect, on the random free energies, of flipping the interaction in a subregion of the entire volume. A fluctuation bound obtained by martingale methods produces, with the help of integration by parts technique, a family of polynomial identities involving overlaps and magnetizations.

Pierluigi Contucci; Cristian Giardina'; Claudio Giberti

2012-12-07T23:59:59.000Z

457

Iron Phosphate Glass-Containing Hanford Waste Simulant  

SciTech Connect

Resolution of the nation's high-level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research-scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron-phosphate-based glass with a selected waste composition that is high in sulfate (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis related to the implementation of phosphate-based glasses for Hanford low-activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, Missouri University of Science and Technology, and Mo-Sci Corporation.

Sevigny, Gary J.; Kimura, Marcia L.; Fischer, Christopher M.; Schweiger, M. J.; Rodriguez, Carmen P.; Kim, Dong-Sang; Riley, Brian J.

2012-01-18T23:59:59.000Z

458

Baseline Glass Development for Combined Fission Products Waste Streams  

SciTech Connect

Borosilicate glass was selected as the baseline technology for immobilization of the Cs/Sr/Ba/Rb (Cs), lanthanide (Ln) and transition metal fission product (TM) waste steams as part of a cost benefit analysis study.[1] Vitrification of the combined waste streams have several advantages, minimization of the number of waste forms, a proven technology, and similarity to waste forms currently accepted for repository disposal. A joint study was undertaken by Pacific Northwest National Laboratory (PNNL) and Savannah River National Laboratory (SRNL) to develop acceptable glasses for the combined Cs + Ln + TM waste streams (Option 1) and Cs + Ln combined waste streams (Option 2) generated by the AFCI UREX+ set of processes. This study is aimed to develop baseline glasses for both combined waste stream options and identify key waste components and their impact on waste loading. The elemental compositions of the four-corners study were used along with the available separations data to determine the effect of burnup, decay, and separations variability on estimated waste stream compositions.[2-5] Two different components/scenarios were identified that could limit waste loading of the combined Cs + LN + TM waste streams, where as the combined Cs + LN waste stream has no single component that is perceived to limit waste loading. Combined Cs + LN waste stream in a glass waste form will most likely be limited by heat due to the high activity of Cs and Sr isotopes.

Crum, Jarrod V.; Billings, Amanda Y.; Lang, Jesse B.; Marra, James C.; Rodriguez, Carmen P.; Ryan, Joseph V.; Vienna, John D.

2009-06-29T23:59:59.000Z

459

Iron Phosphate Glass-Containing Hanford Waste Simulant  

SciTech Connect

Resolution of the nation's high-level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research-scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron-phosphate-based glass with a selected waste composition that is high in sulfate (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis related to the implementation of phosphate-based glasses for Hanford low-activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, Missouri University of Science and Technology, and Mo-Sci Corporation.

Sevigny, Gary J.; Kimura, Marcia L.; Fischer, Christopher M.; Schweiger, M. J.; Rodriguez, Carmen P.; Kim, Dong-Sang; Riley, Brian J.

2012-01-18T23:59:59.000Z

460

Barium oxide, calcium oxide, magnesia, and alkali oxide free glass  

DOE Patents (OSTI)

A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

2013-09-24T23:59:59.000Z

Note: This page contains sample records for the topic "bioactive glass scaffolds" from the National Library of EnergyBeta (NLEBeta).
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461

High strength glass-ceramic to metal seals  

SciTech Connect

In many applications, ceramics are joined to other materials, especially metals. In such cases, interfacial strength is as important as the strength of each constituent material. Examples are presented for tailoring materials and processes to optimize the glass-ceramic-to-metal seal. Means for detecting defects, nondestructively, are also identified.

Haws, L D; Kramer, D P; Moddeman, W E; Wooten, G W

1986-12-01T23:59:59.000Z

462

Measurement of Solute Diffusion Behavior in Fractured Waste Glass Media  

SciTech Connect

Determination of aqueous phase diffusion coefficients of solutes through fractured media is essential for understanding and modeling contaminants transport at many hazardous waste disposal sites. No methods for earlier measurements are available for the characterization of diffusion in fractured glass blocks. We report here the use of time-lag diffusion experimental method to assess the diffusion behavior of three different solutes (Cs, Sr and Pentafluoro Benzoic Acid or PFBA) in fractured, immobilized low activity waste (ILAW) glass forms. A fractured media time-lag diffusion experimental apparatus that allows the measurement of diffusion coefficients has been designed and built for this purpose. Use of time-lag diffusion method, a considerably easier experimental method than the other available methods, was not previously demonstrated for measuring diffusion in any fractured media. Hydraulic conductivity, porosity and diffusion coefficients of a solute were experimentally measured in fractured glass blocks using this method for the first time. Results agree with the range of properties reported for similar rock media earlier, indicating that the time-lag experimental method can effectively characterize the diffusion coefficients of fractured ILAW glass media.

Saripalli, Kanaka P.; Lindberg, Michael J.; Meyer, Philip D.

2008-10-01T23:59:59.000Z

463

Integrated Disposal Facility FY2011 Glass Testing Summary Report  

SciTech Connect

Pacific Northwest National Laboratory was contracted by Washington River Protection Solutions, LLC to provide the technical basis for estimating radionuclide release from the engineered portion of the disposal facility (e.g., source term). Vitrifying the low-activity waste at Hanford is expected to generate over 1.6 x 10{sup 5} m{sup 3} of glass (Certa and Wells 2010). The volume of immobilized low-activity waste (ILAW) at Hanford is the largest in the DOE complex and is one of the largest inventories (approximately 8.9 x 10{sup 14} Bq total activity) of long-lived radionuclides, principally {sup 99}Tc (t{sub 1/2} = 2.1 x 10{sup 5}), planned for disposal in a low-level waste (LLW) facility. Before the ILAW can be disposed, DOE must conduct a performance assessment (PA) for the Integrated Disposal Facility (IDF) that describes the long-term impacts of the disposal facility on public health and environmental resources. As part of the ILAW glass testing program PNNL is implementing a strategy, consisting of experimentation and modeling, in order to provide the technical basis for estimating radionuclide release from the glass waste form in support of future IDF PAs. The purpose of this report is to summarize the progress made in fiscal year (FY) 2011 toward implementing the strategy with the goal of developing an understanding of the long-term corrosion behavior of low-activity waste glasses.

Pierce, Eric M.; Bacon, Diana H.; Kerisit, Sebastien N.; Windisch, Charles F.; Cantrell, Kirk J.; Valenta, Michelle M.; Burton, Sarah D.; Westsik, Joseph H.

2011-09-29T23:59:59.000Z

464

Measuring residual stress in glasses and ceramics using instrumented indentation.  

Science Conference Proceedings (OSTI)

Instrumented indentation has yielded mixed results when used to measure surface residual stresses in metal films. Relative to metals, many glasses and ceramics have a low modulus-to-yield strength (E/sy) ratio. The advantage of this characteristic for measuring residual stress using instrumented indentation is demonstrated by a series of comparative spherical and conical tip finite element simulations. Two cases are considered: (i) a material with E/s{sub y} = 24-similar to glass and (ii) a material with E/s{sub y} = 120-similar to metal films. In both cases, compressive residual stress shifts the simulated load-displacement response toward increasing hardness, irrespective of tip geometry. This shift is shown to be entirely due to pile up for the ''metal'' case, but primarily due to the direct influence of the residual stress for the ''glass'' case. Hardness changes and load-displacement curve shifts are explained by using the spherical cavity model. Supporting experimental results on stressed glasses are provided.

Tandon, Rajan; Buchheit, Thomas E.

2007-03-01T23:59:59.000Z