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1

Structure and properties of bimetallic Ru-Fe/Al/sub 2/O/sub 3/ catalysts  

SciTech Connect (OSTI)

The authors studied the influence of the composition of Ru-Fe-/Al/sub 2/O/sub 3/-catalysts on adsorption and interaction of carbon monoxide and hydrogen. Moessbauer investigations were conducted. According to x-ray photoelectron spectra (XPS) bimetallic Ru-Fe/Al/sub 2/O/sub 3/ catalysts contain ruthenium mainly in the form of Ru/sup 0/ (E/sub b/ = 280.8 eV). Adsorption of carbon monoxide, hydrogen, and CO + H/sub 2/ mixture was studied by microcalorimetric and thermal-desorption methods.

Zakumbaeva, G.D.; Shapovalova, L.B.; Omarov, Zh.T.; Kuanyshev, A.Sh.; Yaskevich, V.I.

1988-08-20T23:59:59.000Z

2

Electronic structure of Fe-vs. Ru-based dye molecules Phillip S. Johnson, Peter L. Cook, Ioannis Zegkinoglou, J. M. Garca-Lastra, Angel Rubio et al.  

E-Print Network [OSTI]

Electronic structure of Fe- vs. Ru-based dye molecules Phillip S. Johnson, Peter L. Cook, Ioannis molecules Phillip S. Johnson,1 Peter L. Cook,2 Ioannis Zegkinoglou,1,3 J. M. García-Lastra,4,5 Angel Rubio,4 molecules for solar cells, the differences in the electronic structure of Fe- and Ru-based dyes

Himpsel, Franz J.

3

Microsoft Word - BH-OM-1089 NEPA.docx  

Broader source: Energy.gov (indexed) [DOE]

all labor, materials, equipment, tools, fabrication, transportation, supervision, mobile lifting equipment, and rigging required to install BH fence modifications. Regulatory...

4

Dpon ru Paean 3  

E-Print Network [OSTI]

??????????? Tape No. / Track / Item No. Dpon ru Paean 3.WAV Length of track 00:03:15 Related tracks (include description/relationship if appropriate) Title of track The Sun Rises From Up There ???????? ?????????????????????????? Translation of title... Description (to be used in archive entry) The lyrics say, "The sun rising above the mountaintop is not the sun, it is the lama. The moon rising over the mid-slopes of the mountain is not the moon, it is the leader. The stars sparkling at the foot...

Gcod pa don 'grub

5

Microsoft Word - BH-09-038 NEPA.docx  

Broader source: Energy.gov (indexed) [DOE]

Title: Lower BH 36" Crude Oil Pipeline at the Needmore Diversion Channel Description: Subcontractor shall shall provide all labor, tools, materials (except GFE), equipment, and...

6

Microsoft Word - BH-09-038A NEPA.docx  

Broader source: Energy.gov (indexed) [DOE]

A Title: Lower BH 36" Crude Oil Pipeline at the Needmore Diversion Channel GFE Description: Manufacturersupplier shall provide 36" diameter pipe with fusion bonded epoxy coating,...

7

The structure of energy levels in ¹?²RU  

E-Print Network [OSTI]

. Experimental and calculated routhian (e') as a function of (hen) for Ru. 30 96 9a Ru Ru LOO Ru f 02 R 104 u Ru Fig. 10. Systematic representation of the negative-parity states in even-even Rn iso- topes. 31 deformation is angular momentum dependent... 4 0 00 4 3 . '2 + t02 Ru (0) 0 2 4 6 8 10 12 14 J (rt) Fig. 11. Positive and negative parity band as a function of J(h) in even-even Ru iso- topes. 33 CHAPTER IV CONCLUSION We have presented theoretical analysis of experimental...

Bouttchenko, Sviatoslav Olegovich

1998-01-01T23:59:59.000Z

8

Bulk modulus and specific heat of B-site doped (La{sub 0.3}Pr{sub 0.7}){sub 0.65}Ca{sub 0.35}Mn{sub 1?x}B{sub x}O{sub 3} (B=Fe, Cr, Ru, Al, Ga)  

SciTech Connect (OSTI)

Specific heat (C{sub p}) thermal expansion (?) and Bulk modulus (B{sub T}) of lightly doped Rare Earth manganites (La{sub 0.3}Pr{sub 0.7}){sub 0.65}Ca{sub 0.35}Mn{sub 1?x}B{sub x}O{sub 3} (B{sup 3+}?=?Fe{sup 3+},Cr{sup 3+},Ga{sup 3+},Al{sup 3+},Ru4+); (0.3Fe{sub 0.03}O{sub 3} as a function of temperature (10K?T? 200K) is found to be in agreement with the published data. The trend of variation of Debye temperature with B-site cationic radius is predicted probably for the first time for the B-site doped rare earth manganites.

Srivastava, Archana, E-mail: archanasaran01@gmail.com [Department of Physics, Sri Sathya Sai College for Women, Bhopal-462024 (India); Thakur, Rasna; Gaur, N. K. [Department of Physics, Barkatullah University, Bhopal-462026 (India)

2014-04-24T23:59:59.000Z

9

Quasielastic neutron scattering of -NH3 and -BH3 rotational dynamics...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Quasielastic neutron scattering of -NH3 and -BH3 rotational dynamics in orthorhombic ammonia borane. Quasielastic neutron scattering of -NH3 and -BH3 rotational dynamics in...

10

Glycerol Hydrogenolysis on Carbon-Supported PtRu and AuRu Bimetallic Catalysts  

SciTech Connect (OSTI)

Bimetallic PtRu and AuRu catalysts were prepared by a surface redox method in which Pt or Au was deposited onto the surface of carbon-supported Ru nanoparticles with an average diameter of 2-3 nm. Characterization by H2 chemisorption, analytical TEM, and X-ray absorption spectroscopy at the Ru K-edge, Pt LIII-edge, and Au LIII-edge confirmed that Pt and Au were successfully deposited onto Ru without disrupting the Ru particles. Depression of the ethane hydrogenolysis rate over Ru after addition of Au provided further evidence of successful deposition. The bimetallic particles were subsequently evaluated in the aqueous-phase hydrogenolysis of glycerol at 473 K and 40 bar H2 at neutral and elevated pH. Although monometallic Pt and Ru exhibited different activities and selectivities to products, the bimetallic PtRu catalyst functioned more like Ru. A similar result was obtained for the AuRu bimetallic catalyst. The PtRu catalyst appeared to be stable under the aqueous-phase reaction conditions, whereas the AuRu catalyst was altered by the harsh conditions. Gold appeared to migrate off the Ru and agglomerate on the carbon during the reaction in liquid water.

Maris,E.; Ketchie, W.; Murayama, M.; Davis, R.

2007-01-01T23:59:59.000Z

11

Search for the decay modes B±?h±??  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

We present a search for the lepton flavor violating decay modes B±?h±?? (h=K, ?; ?=e, ?) using the BABAR data sample, which corresponds to 472×10? BB¯¯¯ pairs. The search uses events where one B meson is fully reconstructed in one of several hadronic final states. Using the momenta of the reconstructed B, h, and ? candidates, we are able to fully determine the ? four-momentum. The resulting ? candidate mass is our main discriminant against combinatorial background. We see no evidence for B±?h±?? decays and set a 90% confidence level upper limit on each branching fraction at the level of a few times 10??.

Lees, J. P.; Poireau, V.; Tisserand, V.; Garra Tico, J.; Grauges, E.; Milanes, D. A.; Palano, A.; Pappagallo, M.; Eigen, G.; Stugu, B.; Brown, D. N.; Kerth, L. T.; Kolomensky, Yu. G.; Lynch, G.; Koch, H.; Schroeder, T.; Asgeirsson, D. J.; Hearty, C.; Mattison, T. S.; McKenna, J. A.; Khan, A.; Blinov, V. E.; Buzykaev, A. R.; Druzhinin, V. P.; Golubev, V. B.; Kravchenko, E. A.; Onuchin, A. P.; Serednyakov, S. I.; Skovpen, Yu. I.; Solodov, E. P.; Todyshev, K. Yu.; Yushkov, A. N.; Bondioli, M.; Kirkby, D.; Lankford, A. J.; Mandelkern, M.; Stoker, D. P.; Atmacan, H.; Gary, J. W.; Liu, F.; Long, O.; Vitug, G. M.; Campagnari, C.; Hong, T. M.; Kovalskyi, D.; Richman, J. D.; West, C. A.; Eisner, A. M.; Kroseberg, J.; Lockman, W. S.; Martinez, A. J.; Schalk, T.; Schumm, B. A.; Seiden, A.; Cheng, C. H.; Doll, D. A.; Echenard, B.; Flood, K. T.; Hitlin, D. G.; Ongmongkolkul, P.; Porter, F. C.; Rakitin, A. Y.; Andreassen, R.; Huard, Z.; Meadows, B. T.; Sokoloff, M. D.; Sun, L.; Bloom, P. C.; Ford, W. T.; Gaz, A.; Nagel, M.; Nauenberg, U.; Smith, J. G.; Wagner, S. R.; Ayad, R.; Toki, W. H.; Spaan, B.; Kobel, M. J.; Schubert, K. R.; Schwierz, R.; Bernard, D.; Verderi, M.; Clark, P. J.; Playfer, S.; Bettoni, D.; Bozzi, C.; Calabrese, R.; Cibinetto, G.; Fioravanti, E.; Garzia, I.; Luppi, E.; Munerato, M.; Negrini, M.; Piemontese, L.; Santoro, V.; Baldini-Ferroli, R.; Calcaterra, A.; de Sangro, R.; Finocchiaro, G.; Patteri, P.; Peruzzi, I. M.; Piccolo, M.; Rama, M.; Zallo, A.; Contri, R.; Guido, E.; Lo Vetere, M.; Monge, M. R.; Passaggio, S.; Patrignani, C.; Robutti, E.; Bhuyan, B.; Prasad, V.; Lee, C. L.; Morii, M.; Edwards, A. J.; Adametz, A.; Marks, J.; Uwer, U.; Lacker, H. M.; Lueck, T.; Dauncey, P. D.; Behera, P. K.; Mallik, U.; Chen, C.; Cochran, J.; Meyer, W. T.; Prell, S.; Rubin, A. E.; Gritsan, A. V.; Guo, Z. J.; Arnaud, N.; Davier, M.; Derkach, D.; Grosdidier, G.; Le Diberder, F.; Lutz, A. M.; Malaescu, B.; Roudeau, P.; Schune, M. H.; Stocchi, A.; Wormser, G.; Lange, D. J.; Wright, D. M.; Bingham, I.; Chavez, C. A.; Coleman, J. P.; Fry, J. R.; Gabathuler, E.; Hutchcroft, D. E.; Payne, D. J.; Touramanis, C.; Bevan, A. J.; Di Lodovico, F.; Sacco, R.; Sigamani, M.; Cowan, G.; Brown, D. N.; Davis, C. L.; Denig, A. G.; Fritsch, M.; Gradl, W.; Hafner, A.; Prencipe, E.; Alwyn, K. E.; Bailey, D.; Barlow, R. J.; Jackson, G.; Lafferty, G. D.; Behn, E.; Cenci, R.; Hamilton, B.; Jawahery, A.; Roberts, D. A.; Simi, G.; Dallapiccola, C.; Cowan, R.; Dujmic, D.; Sciolla, G.; Lindemann, D.; Patel, P. M.; Robertson, S. H.; Schram, M.; Biassoni, P.; Neri, N.; Palombo, F.; Stracka, S.; Cremaldi, L.; Godang, R.; Kroeger, R.; Sonnek, P.; Summers, D. J.; Nguyen, X.; Simard, M.; Taras, P.; De Nardo, G.; Monorchio, D.; Onorato, G.; Sciacca, C.; Martinelli, M.; Raven, G.; Jessop, C. P.; Knoepfel, K. J.; LoSecco, J. M.; Wang, W. F.; Honscheid, K.; Kass, R.; Brau, J.; Frey, R.; Sinev, N. B.; Strom, D.; Torrence, E.; Feltresi, E.; Gagliardi, N.; Margoni, M.; Morandin, M.; Posocco, M.; Rotondo, M.; Simonetto, F.; Stroili, R.; Akar, S.; Ben-Haim, E.; Bomben, M.; Bonneaud, G. R.; Briand, H.; Calderini, G.; Chauveau, J.; Hamon, O.; Leruste, Ph.; Marchiori, G.; Ocariz, J.; Sitt, S.; Biasini, M.; Manoni, E.; Pacetti, S.; Rossi, A.; Angelini, C.; Batignani, G.; Bettarini, S.; Carpinelli, M.; Casarosa, G.; Cervelli, A.; Forti, F.; Giorgi, M. A.; Lusiani, A.; Oberhof, B.; Paoloni, E.; Perez, A.; Rizzo, G.; Walsh, J. J.; Lopes Pegna, D.; Lu, C.; Olsen, J.; Smith, A. J. S.; Telnov, A. V.; Anulli, F.; Cavoto, G.; Faccini, R.; Ferrarotto, F.; Ferroni, F.; Gaspero, M.; Li Gioi, L.; Mazzoni, M. A.; Piredda, G.; Bünger, C.; Grünberg, O.; Hartmann, T.; Leddig, T.; Schröder, H.; Voss, C.; Waldi, R.; Adye, T.; Olaiya, E. O.; Wilson, F. F.; Emery, S.; Hamel de Monchenault, G.; Vasseur, G.; Yèche, Ch.; Aston, D.; Bard, D. J.; Bartoldus, R.; Cartaro, C.; Convery, M. R.; Dorfan, J.; Dubois-Felsmann, G. P.; Dunwoodie, W.; Ebert, M.; Field, R. C.; Franco Sevilla, M.; Fulsom, B. G.; Gabareen, A. M.; Graham, M. T.; Grenier, P.; Hast, C.; Innes, W. R.; Kelsey, M. H.; Kim, P.; Kocian, M. L.; Leith, D. W. G. S.; Lewis, P.; Lindquist, B.; Luitz, S.; Luth, V.; Lynch, H. L.; MacFarlane, D. B.; Muller, D. R.; Neal, H.; Nelson, S.; Perl, M.; Pulliam, T.; Ratcliff, B. N.; Roodman, A.; Salnikov, A. A.; Schindler, R. H.; Snyder, A.; Su, D.; Sullivan, M. K.; Va’vra, J.; Wagner, A. P.; Weaver, M.; Wisniewski, W. J.; Wittgen, M.; Wright, D. H.; Wulsin, H. W.; Young, C. C.; Ziegler, V.; Park, W.; Purohit, M. V.; White, R. M.; Wilson, J. R.; Randle-Conde, A.; Sekula, S. J.; Bellis, M.; Benitez, J. F.; Burchat, P. R.; Miyashita, T. S.; Alam, M. S.; Ernst, J. A.; Gorodeisky, R.; Guttman, N.; Peimer, D. R.; Soffer, A.; Lund, P.; Spanier, S. M.; Eckmann, R.; Ritchie, J. L.

2012-07-01T23:59:59.000Z

12

Lightest Isotope of Bh Produced Via the 209Bi(52Cr,n)260BhReaction  

SciTech Connect (OSTI)

The lightest isotope of Bh known was produced in the new {sup 209}Bi({sup 52}Cr,n){sup 260}Bh reaction at the Lawrence Berkeley National Laboratory's 88-Inch Cyclotron. Positive identification was made by observation of eight correlated alpha particle decay chains in the focal plane detector of the Berkeley Gas-Filled Separator. {sup 260}Bh decays with a 35{sub -9}{sup +19} ms half-life by alpha particle emission mainly by a group at 10.16 MeV. The measured cross section of 59{sub -20}{sup +29} pb is approximately a factor of four larger than compared to recent model predictions. The influences of the N = 152 and Z = 108 shells on alpha decay properties are discussed.

Nelson, Sarah L.; Gregorich, Kenneth E.; Dragojevic, Irena; Garcia, Mitch A.; Gates, Jacklyn M.; Sudowe, Ralf; Nitsche, Heino

2007-05-07T23:59:59.000Z

13

AL 3 (BH 261): a new globular cluster in the Galaxy  

E-Print Network [OSTI]

AL~3 (BH 261), previously classified as a faint open cluster candidate, is shown to be a new globular cluster in the Milky Way, by means of B, V and I Color-Magnitude Diagrams. The main feature of AL~3 is a prominent blue extended Horizontal Branch. Its Color-Magnitude Diagrams match those of the intermediate metallicity cluster M~5. The cluster is projected in a rich bulge field, also contaminated by the disk main sequence. The globular cluster is located in the Galactic bulge at a distance from the Sun d$_{\\odot}$ = 6.0$\\pm$0.5 kpc. The reddening is E(B-V)=0.36$\\pm$0.03 and the metallicity is estimated to be [Fe/H] $\\approx$ -1.3$\\pm$0.25. AL~3 is probably one of the least massive globular clusters of the Galaxy.

S. Ortolani; E. Bica; B. Barbuy

2006-06-29T23:59:59.000Z

14

In-silico and in-vitro elucidation of BH3 binding specificity towards Bcl-2  

E-Print Network [OSTI]

Interactions between Bcl-2-like proteins and BH3 domains play a key role in the regulation of apoptosis. Despite the overall structural similarity of their interaction with helical BH3 domains, Bcl-2-like proteins exhibit ...

London, Nir

15

Atomistic modeling of Ru nanocluster formation on graphene/Ru(0001): Thermodynamically versus kinetically directed-assembly  

E-Print Network [OSTI]

Atomistic modeling of Ru nanocluster formation on graphene/Ru(0001): Thermodynamically versus nanocluster formation on a monolayer of graphene supported on Ru(0001) at 309 K. Nanocluster density, mean

Ulm, Universität

16

Non-Born-Oppenheimer calculations of the BH molecule  

SciTech Connect (OSTI)

Variational calculations employing explicitly correlated Gaussian basis functions have been performed for the ground state of the boron monohydride molecule (BH) and for the boron atom (B). Up to 2000 Gaussians were used for each system. The calculations did not assume the Born-Oppenheimer (BO) approximation. In the optimization of the wave function, we employed the analytical energy gradient with respect to the Gaussian exponential parameters. In addition to the total nonrelativistic energies, we computed scalar relativistic corrections (mass-velocity and Darwin). With those added to the total energies, we estimated the dissociation energy of BH. The non-BO wave functions were also used to compute some expectation values involving operators dependent on the interparticle distances.

Bubin, Sergiy; Stanke, Monika; Adamowicz, Ludwik

2009-07-30T23:59:59.000Z

17

Ionic conductivity and the formation of cubic CaH{sub 2} in the LiBH{sub 4}–Ca(BH{sub 4}){sub 2} composite  

SciTech Connect (OSTI)

LiBH{sub 4}–Ca(BH{sub 4}){sub 2} composites were prepared by ball milling. Their crystal structures and phase composition were investigated using synchrotron X-ray diffraction and Rietveld refinement, and their ionic conductivity was measured using impedance spectroscopy. The materials were found to form a physical mixture. The composites were composed of ?-Ca(BH{sub 4}){sub 2}, ?-Ca(BH{sub 4}){sub 2} and orthorhombic LiBH{sub 4}, and the relative phase quantities of the Ca(BH{sub 4}){sub 2} polymorphs varied significantly with LiBH{sub 4} content. The formation of small amounts of orthorhombic CaH{sub 2} and cubic CaH{sub 2} in a CaF{sub 2}-like structure was observed upon heat treatment. Concurrent formation of elemental boron may also occur. The ionic conductivity of the composites was measured using impedance spectroscopy, and was found to be lower than that of ball milled LiBH{sub 4}. Electronic band structure calculations indicate that cubic CaH{sub 2} with hydrogen defects is electronically conducting. Its formation along with the possible precipitation of boron therefore has an effect on the measured conductivity of the LiBH{sub 4}–Ca(BH{sub 4}){sub 2} composites and may increase the risk of an internal short-circuit in the cells. -- Graphical abstract: An Arrhenius plot of the ionic conductivity of the LiBH{sub 4}–Ca(BH{sub 4}){sub 2} composites (red, blue, green). The ionic conductivity of ball milled (gray) and non-milled (black) LiBH{sub 4} is shown for comparison. The filled symbols are measured during heating runs and the empty symbols are measured during subsequent cooling runs. The conductivity of the composites is in all cases higher during cooling, most probably due to the formation of an electronically conducting layer containing defect-rich cubic CaH{sub 2}. Such layer formation could eventually lead to a short circuit in the cell and reveals a general issue of chemical stability that should be attended to in the development of solid electrolyte materials. Highlights: • The LiBH{sub 4}–Ca(BH{sub 4}){sub 2} composite forms a physical mixture rather than a solid solution. • The formation of defect-rich, cubic CaH{sub 2} in a CaF{sub 2}-like structure is observed. • A new layer containing cubic CaH{sub 2} is conducting and may lead to a short-circuit.

Sveinbjörnsson, Dadi; Blanchard, Didier [Department of Energy Conversion and Storage, Technical University of Denmark, Frederiksborgvej 399, P.O. Box 49, DK-4000 Roskilde (Denmark); Myrdal, Jon Steinar Gardarsson [Department of Energy Conversion and Storage, Technical University of Denmark, Frederiksborgvej 399, P.O. Box 49, DK-4000 Roskilde (Denmark); Center for Atomic-Scale Materials Design, Department of Physics, Technical University of Denmark, Anker Engelunds Vej 1, DK-2800 Lyngby (Denmark); Younesi, Reza; Viskinde, Rasmus [Department of Energy Conversion and Storage, Technical University of Denmark, Frederiksborgvej 399, P.O. Box 49, DK-4000 Roskilde (Denmark); Riktor, Marit Dalseth [Physics Department, Institute for Energy Technology, Instituttveien 18, P.O. Box 40, NO-2027 Kjeller (Norway); Norby, Poul [Department of Energy Conversion and Storage, Technical University of Denmark, Frederiksborgvej 399, P.O. Box 49, DK-4000 Roskilde (Denmark); Vegge, Tejs, E-mail: teve@dtu.dk [Department of Energy Conversion and Storage, Technical University of Denmark, Frederiksborgvej 399, P.O. Box 49, DK-4000 Roskilde (Denmark)

2014-03-15T23:59:59.000Z

18

Kinetic Characterization of PtRu Fuel Cell Anode Catalysts Made by Spontaneous Pt Deposition on Ru Nanoparticles  

E-Print Network [OSTI]

rotating disk electrode without using Nafion film to stabilize them. Nonlinear fittings of the entire for a polycrystalline Pt electrode. For the PtRu20 , PtRu10 , and PtRu5 samples prepared by spontaneous deposition of 1 spontaneous deposition of Pt4 and Pd5 on Ru-single crystals, which facilitates a new method

Brankovic, Stanko R.

19

Graphene on Ru(0001) Moire Corrugation Studied by Scanning Tunneling Microscopy on Au/Graphene/Ru(0001) Heterostructures  

E-Print Network [OSTI]

Graphene on Ru(0001) Moire Corrugation Studied by Scanning Tunneling Microscopy on Au/Graphene on graphene/Ru(0001) were used to study the corrugation of the moire structure of graphene/Ru(0001 for the graphene/Ru(0001) moire is of structural nature rather than electronic. STM showed a large value

Ciobanu, Cristian

20

FutureCamp GmBH | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, search Equivalent URIFrontier,Jump to:Wilmette, IL Website:FutureCamp GmBH

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Graphene Growth by Metal Etching on Ru (0001)  

E-Print Network [OSTI]

of step etching during graphene growth, such as in Fig. 3,adsorption of water on graphene structures will be describedRu(0001) Figure 5. a b c graphene Ru d Figure 6. Figure 7. a

Loginova, Elena

2010-01-01T23:59:59.000Z

22

Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Storage Properties of New Hydrogen-Rich BH3NH3-Metal Hydride (TiH2, ZrH2, MgH2, andor CaH2) Composite Systems. Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal...

23

CO oxidation over Ru(0001) at near-atmospheric pressures: From chemisorbed oxygen to RuO2  

E-Print Network [OSTI]

modulation Infrared reflection absorption spectroscopy Reaction kinetics a b s t r a c t RuO2(110) was formed polarization modulation infrared reflection absorption spectroscopy (PM-IRAS) and post-reaction Auger electronCO oxidation over Ru(0001) at near-atmospheric pressures: From chemisorbed oxygen to RuO2 Feng Gao

Goodman, Wayne

24

Level structure of /sup 101/Ru from the /sup 100/Ru(d,p) reaction  

SciTech Connect (OSTI)

Energy levels of /sup 101/Ru have been studied by the /sup 100/Ru(d,p)/sup 101/Ru reaction at an incident deuteron energy of 12 MeV. Outgoing particles were momentum analyzed by a magnetic spectrograph and detected in nuclear emulsion plates, with an energy resolution of 7.5 keV. A total of 68 levels up to 3.2 MeV excitation energy was identified, about two-thirds of them reported for the first time. Experimental angular distributions were compared to distorted-wave Born approximation predictions and reduced spectroscopic factors obtained. The total l = 2 and 75% of l = 0, 4, and 5 spectroscopic strengths were located. Attention is drawn to transitions to low-lying states in /sup 101/Ru (below E/sub exc/ = 0.75 MeV) with l = 3 and l = 1 character.

Duarte, J.L.M.; Horodynski-Matsushigue, L.B.; Borello-Lewin, T.; Dietzsch, O.

1988-08-01T23:59:59.000Z

25

Hexadecapolar excitation in sup 100 Ru  

SciTech Connect (OSTI)

Attention is drawn to the strong collective {ital L}=4 direct excitation of the state at 2.367 MeV in {sup 100}Ru by inelastic scattering of 16 MeV protons characterized by a deformation parameter {beta}{sub 4}=0.10, one of the highest reported for any region of the mass table.

Sirota, S.; Duarte, J.L.M.; Horodynski-Matsushigue, L.B.; Borello-Lewin, T. (Instituto de Fisica da Universidade de Sa Paulo, 01498 Sao Paulo, Brasil (BR))

1989-09-01T23:59:59.000Z

26

Lab Safety: RuO4Lab Safety: RuO4 Ruthenium tetroxide is a strong oxidizing agent and must be stored in the  

E-Print Network [OSTI]

Lab Safety: RuO4Lab Safety: RuO4 RuO4 Note: Ruthenium tetroxide is a strong oxidizing agent with sodium bisulfite solution to decompose RuO4 and then flush with plenty of water. #12;Lab Safety:Lab Safety: Reaction used to create RuO4 for staining: RuCl3 #12;Sodium hypochlorite: HARMFUL IF SWALLOWED

Cohen, Robert E.

27

Microsoft Word - BH-OM-1074 and BC-OM-1240 NEPA.docx  

Broader source: Energy.gov (indexed) [DOE]

74 and BC-OM-1240 Title: Replacement of Deep-Anode Ground Bed Sites for BH Cavern 104 and Site Unit 1 "A", and BC Cavern 18 Description: Subcontractor shall provide all materials,...

28

DO QUIESCENT AND ACTIVE GALAXIES HAVE DIFFERENT M{sub BH}-{sigma}{sub *} RELATIONS?  

SciTech Connect (OSTI)

To investigate the validity of the assumption that quiescent galaxies and active galaxies follow the same black hole mass (M{sub BH})-stellar velocity dispersion ({sigma}{sub *}) relation, as required for the calibration of M{sub BH} estimators for broad line active galactic nuclei (AGNs), we determine and compare the M{sub BH}-{sigma}{sub *} relations, respectively, for quiescent and active galaxies. For the quiescent galaxy sample, composed of 72 dynamical M{sub BH} measurements, we update {sigma}{sub *} for 28 galaxies using homogeneous H-band measurements that are corrected for galaxy rotation. For active galaxies, we collect 25 reverberation-mapped AGNs and improve {sigma}{sub *} measurement for two objects. Combining the two samples, we determine the virial factor f, first by scaling the active galaxy sample to the M{sub BH}-{sigma}{sub *} relation of quiescent galaxies, and second by simultaneously fitting the quiescent and active galaxy samples, as f=5.1{sub -1.1}{sup +1.5} and f=5.9{sub -1.5}{sup +2.1}, respectively. The M{sub BH}-{sigma}{sub *} relation of active galaxies appears to be shallower than that of quiescent galaxies. However, the discrepancy is caused by a difference in the accessible M{sub BH} distribution at given {sigma}{sub *}, primarily due to the difficulty of measuring reliable stellar velocity dispersion for the host galaxies of luminous AGNs. Accounting for the selection effects, we find that active and quiescent galaxies are consistent with following intrinsically the same M{sub BH}-{sigma}{sub *} relation.

Woo, Jong-Hak; Park, Daeseong; Kang, Wol-Rang [Astronomy Program, Department of Physics and Astronomy, Seoul National University, 1 Gwanak-ro Gwanak-gu, Seoul, 151-742 (Korea, Republic of); Schulze, Andreas [Kavli Institute for Astronomy and Astrophysics, Peking University, 100871 Beijing (China); Kim, Sang Chul [Korea Astronomy and Space Science Institute, Daejeon 305-348 (Korea, Republic of); Riechers, Dominik A., E-mail: woo@astro.snu.ac.kr [Astronomy Department, Cornell University, 220 Space Science Building, Ithaca, NY 14853 (United States)

2013-07-20T23:59:59.000Z

29

PtRu/Carbon Nanotube Nanocomposite Synthesized in Supercritical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Synthesized in Supercritical Fluid: A Novel Electrocatalyst for Direct Methanol Fuel Cell. PtRuCarbon Nanotube Nanocomposite Synthesized in Supercritical Fluid: A Novel...

30

Multiple Pathways for Benzyl Alcohol Oxidation by Ru(V)?O3+ and Ru(IV)?O2+  

SciTech Connect (OSTI)

Significant rate enhancements are found for benzyl alcohol oxidation by the Ru{sup V}?O{sup 3+} form of the water oxidation catalyst [Ru(Mebimpy)(bpy)(OH{sub 2})]{sup 2+} [Mebimpy = 2,6-bis(1-methylbenzimidazol-2-yl)pyridine; bpy = 2,2?-bipyridine] compared to Ru{sup IV}?O{sup 2+} and for the Ru{sup IV}?O{sup 2+} form with added bases due to a new pathway involving concerted hydride proton transfer (HPT).

Paul, Amit; Hull, Jonathan F; Norris, Michael R; Chen, Zuofeng; Ess, Daniel H.; Concepcion, Javier J; Meyer, Thomas J.

2011-01-01T23:59:59.000Z

31

Multiple Pathways for Benzyl Alcohol Oxidation by RuV=O3+ and RuIV=O2+  

SciTech Connect (OSTI)

Significant rate enhancements are found for benzyl alcohol oxidation by the Ru{sup V}?O{sup 3+} form of the water oxidation catalyst [Ru(Mebimpy)(bpy)(OH{sub 2})]{sup 2+} [Mebimpy = 2,6-bis(1-methylbenzimidazol-2-yl)pyridine; bpy = 2,2?-bipyridine] compared to Ru{sup IV}?O{sup 2+} and for the Ru{sup IV}?O{sup 2+} form with added bases due to a new pathway, concerted hydride proton transfer (HPT).

Paul, Amit; Hull, Jonathan F; Norris, Michael R; Chen, Zuofeng; Ess, Daniel H; Concepcion, Javier J; Meyer, Thomas J

2011-01-01T23:59:59.000Z

32

EPR and IR studies of [Ru(NH?)?]³+-Y and [Ru(NH?)?N?]²+-Y type zeolites  

E-Print Network [OSTI]

EPR AND IR STUDIES OF [Ru(NH ) ] -Y 3 6 AND [Ru(NE ) N ] -Y TYPE ZEOLITES 2+ A Thesis by RAYMOND LEON LEUBNER Submitted to the Graduate College of Texas A&M University in partia1 fulfillment of the requirement for the degree of MASTER... OF SCIENCE December 1973 Major Subject: Chemistry EPR AND IR STUDIES OF [Ru(NH3) ] -Y 3+ AND [Ru(NH3) N ) -Y TYPE ZEOLITES 2+ 3&2 A Thesis by RAYMOND LEON LEUBNER Approved as to style and content by: (Chairman of Committ (Head of Department) (Memb...

Leubner, Raymond Leon

1973-01-01T23:59:59.000Z

33

Diruthenium Tetracarbonate Trianion, [RuII/III(O2 CO)4 3- Based Molecule Based Magnets: Three-Dmensional Network Structure and Two Dimensional Magnetic Ordering  

SciTech Connect (OSTI)

HxK1-xMII[Ru2(CO3)4](H2O)y(MeOH)z (M = Mn, Fe, Co, Ni, Mg) were synthesized from the reaction of MII and K3[Ru2(CO3)4] in water and are isomorphous with an orthorhombic three-dimensional network structures based on e3-CO32- linkages to Ru2 moieties forming layers and also to trans-MII(OH2)4 sites forming linked chains that connect the layers. They, as well as non-isomorphous M = Cu, magnetically order as canted ferrimagnets with Tc = 4.4 {+-} 1.0 K. The presence of S = 0 MII = Mg(II) has essentially no effect on Tc suggesting that the main magnetic pathway does not occur the through MII-based chains, but only via Ru2{center_dot}...Ru2 linkages that reside in layers. This is a rare example of a magnet based upon a second row transition metal.

Kennon, B.; Her, J; Stephens, P; Miller, J

2009-01-01T23:59:59.000Z

34

Atomistic modeling of the directed-assembly of bimetallic Pt-Ru nanoclusters on Ru(0001)-supported monolayer graphene  

E-Print Network [OSTI]

)-supported monolayer graphene Yong Han,1 Albert K. Engstfeld,2 R. Juergen Behm,2 and James W. Evans1,3,* 1 of Pt-Ru nanoclusters (NC's) by sequential deposition of Pt and Ru on a periodically rumpled graphene. The periodic variation of the adsorption energy across the graphene sheet directs the assembly of NC

Ulm, Universität

35

OBSERVATIONS IN REACTIVITY BETWEEN BH CONTAINING COMPOUNDS AND ORGANOMETALLIC REAGENTS: SYNTHESIS OF BORONIC ACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES  

E-Print Network [OSTI]

aryl bromides and H 2 BN(iPr) 2 Scheme 2.7. Hydroboration oftransfer hydride to BH 2 -N(iPr) 2 Scheme 2.10. Conversionchloride with BH 2 -N(iPr) 2 Scheme 3; Aqueous quench of p-

Clary, Jacob William

2012-01-01T23:59:59.000Z

36

MoRu/Be multilayers for extreme ultraviolet applications  

DOE Patents [OSTI]

High reflectance, low intrinsic roughness and low stress multilayer systems for extreme ultraviolet (EUV) lithography comprise amorphous layers MoRu and crystalline Be layers. Reflectance greater than 70% has been demonstrated for MoRu/Be multilayers with 50 bilayer pairs. Optical throughput of MoRu/Be multilayers can be 30-40% higher than that of Mo/Be multilayer coatings. The throughput can be improved using a diffusion barrier to make sharper interfaces. A capping layer on the top surface of the multilayer improves the long-term reflectance and EUV radiation stability of the multilayer by forming a very thin native oxide that is water resistant.

Bajt, Sasa C. (Livermore, CA); Wall, Mark A. (Stockton, CA)

2001-01-01T23:59:59.000Z

37

Parameter Estimation of Gravitational Waves from Precessing BH-NS Inspirals with higher harmonics  

E-Print Network [OSTI]

Precessing black hole-neutron star (BH-NS) binaries produce a rich gravitational wave signal, encoding the binary's nature and inspiral kinematics. Using the lalinference\\_mcmc Markov-chain Monte Carlo parameter estimation code, we use two fiducial examples to illustrate how the geometry and kinematics are encoded into the modulated gravitational wave signal, using coordinates well-adapted to precession. Even for precessing binaries, we show the performance of detailed parameter estimation can be estimated by "effective" estimates: comparisons of a prototype signal with its nearest neighbors, adopting a fixed sky location and idealized two-detector network. We use detailed and effective approaches to show higher harmonics provide nonzero but small local improvement when estimating the parameters of precessing BH-NS binaries. That said, we show higher harmonics can improve parameter estimation accuracy for precessing binaries ruling out approximately-degenerate source orientations. Our work illustrates quantities gravitational wave measurements can provide, such as reliable component masses and the precise orientation of a precessing short gamma ray burst progenitor relative to the line of sight. "Effective" estimates may provide a simple way to estimate trends in the performance of parameter estimation for generic precessing BH-NS binaries in next-generation detectors. For example, our results suggest that the orbital chirp rate, precession rate, and precession geometry are roughly-independent observables, defining natural variables to organize correlations in the high-dimensional BH-NS binary parameter space.

R. O'Shaughnessy; B. Farr; E. Ochsner; H. S. Cho; V. Raymond; C. Kim; C. H. Lee

2014-04-11T23:59:59.000Z

38

XRF 100316D / SN 2010bh and the Nature of Gamma Ray Burst Supernovae  

E-Print Network [OSTI]

We present ground-based and HST optical and infrared observations of XRF 100316D / SN 2010bh. It is seen that the optical light curves of SN 2010bh evolve at a faster rate than the archetype GRB-SN 1998bw, but at a similar rate to SN 2006aj, a supernova that was spectroscopically linked with XRF 060218, and at a similar rate to non-GRB associated type Ic SN 1994I. We estimate the rest-frame extinction of this event from our optical data to be E(B-V)=0.18 +/- 0.08 mag. We find the V-band absolute magnitude of SN 2010bh to be M_{V}=-18.62 +/- 0.08, which is the faintest peak V-band magnitude observed to-date for a spectroscopically-confirmed GRB-SNe. When we investigate the origin of the flux at t-t_{o}=0.598 days, it is shown that the light is not synchrotron in origin, but is likely coming from the supernova shock break-out. We then use our optical and infrared data to create a quasi-bolometric light curve of SN 2010bh which we model with a simple analytical formula. The results of our modeling imply that SN ...

Cano, Z; Guidorzi, C; Kobayashi, S; Levan, A J; Tanvir, N R; Wiersema, K; D'Avanzo, P; Fruchter, A S; Garnavich, P; Gomboc, A; Gorosabel, J; Kasen, D; Kopac, D; Margutti, R; Mazzali, P A; Melandri, A; Mundell, C G; Nugent, P E; Pian, E; Smith, R J; Steele, I; Wijers, R A M J; Woosley, S E

2011-01-01T23:59:59.000Z

39

BH-2 Mainframe Chassis 65-0200 IP-2 Iontophoresis Pump Module 65-0203  

E-Print Network [OSTI]

BH-2 Mainframe Chassis 65-0200 IP-2 Iontophoresis Pump Module 65-0203 PPM-2 Pneumatic Pump Module Module ..............6 MS-2 Power Supply ..........................................6 IP-2 Pump Module ..............................................7-8 PPM-2 Pneumatic Pump Module ..........................9 Recommended Setup Procedure

40

REVERSIBLE HYDROGEN STORAGE IN A LiBH{sub 4}-C{sub 60} NANOCOMPOSITE  

SciTech Connect (OSTI)

Reversible hydrogen storage in a LiBH{sub 4}:C{sub 60} nanocomposite (70:30 wt. %) synthesized by solvent-assisted mixing has been demonstrated. During the solvent-assisted mixing and nanocomposite formation, a chemical reaction occurs in which the C{sub 60} cages are significantly modified by polymerization as well as by hydrogenation (fullerane formation) in the presence of LiBH{sub 4}. We have determined that two distinct hydrogen desorption events are observed upon rehydrogenation of the material, which are attributed to the reversible formation of a fullerane (C{sub 60}H{sub x}) as well as a LiBH4 species. This system is unique in that the carbon species (C{sub 60}) actively participates in the hydrogen storage process which differs from the common practice of melt infiltration of high surface area carbon materials with LiBH{sub 4} (nanoconfinment effect). This nanocomposite demonstrated good reversible hydrogen storage properties as well as the ability to absorb hydrogen under mild conditions (pressures as low as 10 bar H{sub 2} or temperatures as low as 150?C). The nanocomposite was characterized by TGA-RGA, DSC, XRD, LDI-TOF-MS, FTIR, 1H NMR, and APPI MS.

Teprovich, J.; Zidan, R.; Peters, B.; Wheeler, J.

2013-08-06T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

High density Ru nanocrystal deposition for nonvolatile memory applications  

E-Print Network [OSTI]

High density Ru nanocrystal deposition for nonvolatile memory applications Damon B. Farmer School density optimizes the charge storing capability of the floating layer, while a high degree of size

42

Low energy electron bombardment induced surface contamination of Ru mirrors  

E-Print Network [OSTI]

of electrons irradiation along with slight oxidation of pure Ru surface. All chemical changes were discussed for EUVL vacuum chamber to avoid heat induced degradation of the EUV optics6 . Heating of MLM scan initiate

Harilal, S. S.

43

EXPLORING THE LOW-MASS END OF THE M{sub BH}-{sigma}{sub *} RELATION WITH ACTIVE GALAXIES  

SciTech Connect (OSTI)

We present new measurements of stellar velocity dispersions, using spectra obtained with the Keck Echellette Spectrograph and Imager (ESI) and the Magellan Echellette (MagE), for 76 Seyfert 1 galaxies from the recent catalog of Greene and Ho. These objects were selected from the Sloan Digital Sky Survey (SDSS) to have estimated black hole (BH) masses below 2 x 10{sup 6} M{sub sun}. Combining our results with previous ESI observations of similar objects, we obtain an expanded sample of 93 galaxies and examine the relation between BH mass and velocity dispersion (the M{sub BH}-{sigma}{sub *} relation) for active galaxies with low BH masses. The low-mass active galaxies tend to follow the extrapolation of the M{sub BH}-{sigma}{sub *} relation of inactive galaxies. Including results for active galaxies of higher BH mass from the literature, we find a zero point {alpha} = 7.68 {+-} 0.08 and slope of {beta} = 3.32 {+-} 0.22 for the M{sub BH}-{sigma}{sub *} relation (in the form log M{sub BH} = {alpha} + {beta}log ({sigma}{sub *}/200 km s{sup -1})), with intrinsic scatter of 0.46 {+-} 0.03 dex. This result is consistent, within the uncertainties, with the slope of the M{sub BH}-{sigma}{sub *} relation for reverberation-mapped active galaxies with BH masses from 10{sup 6} to 10{sup 9} M{sub sun}. For the subset of our sample having morphological information from Hubble Space Telescope images, we examine the slope of the M{sub BH}-{sigma}{sub *} relation separately for subsamples of barred and unbarred host galaxies, and find no significant evidence for a difference in slope. We do find a mild offset between low-inclination and high-inclination disk galaxies, such that more highly inclined galaxies tend to have larger {sigma}{sub *} at a given value of BH mass, presumably due to the contribution of disk rotation within the spectroscopic aperture. We also find that the velocity dispersion of the ionized gas, measured from narrow emission lines including [N II] {lambda}6583, [S II] {lambda}{lambda}6716, 6731, and the core of [O III] {lambda}5007 (with the blueshifted wing removed), trace the stellar velocity dispersion well for this large sample of low-mass Seyfert 1 galaxies.

Xiao Ting [Key Laboratory for Research in Galaxies and Cosmology, Department of Astronomy, University of Science and Technology of China, Chinese Academy of Sciences, Hefei, Anhui 230026 (China); Barth, Aaron J. [Department of Physics and Astronomy, University of California at Irvine, 4129 Frederick Reines Hall, Irvine, CA 92697-4575 (United States); Greene, Jenny E.; Ludwig, Randi R. [University of Texas at Austin, Department of Astronomy, 1 University Station, C1400, Austin, TX 78712-0259 (United States); Ho, Luis C. [The Observatories of the Carnegie Institution for Science, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Bentz, Misty C. [Department of Physics and Astronomy, Georgia State University, Astronomy Offices, One Park Place South SE, Suite 700, Atlanta, GA 30303 (United States); Jiang Yanfei, E-mail: xiaoting@mail.ustc.edu.cn, E-mail: barth@uci.edu, E-mail: jgreene@astro.as.utexas.edu, E-mail: lho@obs.carnegiescience.edu, E-mail: bentz@chara.gsu.edu, E-mail: yanfei@astro.princeton.edu [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States)

2011-09-20T23:59:59.000Z

44

Termination of star formation by BH feedback in equal- and unequal-mass mergers of disk and elliptical galaxies  

E-Print Network [OSTI]

We present binary galaxy merger simulations of gas-rich disks (Sp-Sp), of early-type galaxies and disks (E-Sp, mixed mergers), and mergers of early-type galaxies (E-E, dry mergers) with varying mass ratios and different progenitor morphologies. The simulations include radiative cooling, star formation and black hole (BH) accretion and the associated feedback processes. We find for Sp-Sp mergers, that the peak star formation rate and BH accretion rate decrease and the growth timescales of the central black holes and newly formed stars increase with higher progenitor mass ratios. The termination of star formation by BH feedback in disk mergers is significantly less important for higher progenitor mass ratios (e.g. 3:1 and higher). In addition, the inclusion of BH feedback suppresses efficiently star formation in dry E-E mergers and mixed E-Sp mergers.

Peter H. Johansson; Thorsten Naab; Andreas Burkert

2008-09-19T23:59:59.000Z

45

Development of bulk-type all-solid-state lithium-sulfur battery using LiBH{sub 4} electrolyte  

SciTech Connect (OSTI)

Stable battery operation of a bulk-type all-solid-state lithium-sulfur battery was demonstrated by using a LiBH{sub 4} electrolyte. The electrochemical activity of insulating elemental sulfur as the positive electrode was enhanced by the mutual dispersion of elemental sulfur and carbon in the composite powders. Subsequently, a tight interface between the sulfur-carbon composite and the LiBH{sub 4} powders was manifested only by cold-pressing owing to the highly deformable nature of the LiBH{sub 4} electrolyte. The high reducing ability of LiBH{sub 4} allows using the use of a Li negative electrode that enhances the energy density. The results demonstrate the interface modification of insulating sulfur and the architecture of an all-solid-state Li-S battery configuration with high energy density.

Unemoto, Atsushi, E-mail: unemoto@imr.tohoku.ac.jp; Ikeshoji, Tamio [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yasaku, Syun; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Nogami, Genki; Tazawa, Masaru; Taniguchi, Mitsugu [Mitsubishi Gas Chemicals Co., Ltd., 182 Tayuhama Shinwari, Kita-ku, Niigata 950-3112 (Japan); Orimo, Shin-ichi [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

2014-08-25T23:59:59.000Z

46

OBSERVATIONS IN REACTIVITY BETWEEN BH CONTAINING COMPOUNDS AND ORGANOMETALLIC REAGENTS: SYNTHESIS OF BORONIC ACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES  

E-Print Network [OSTI]

Reaction of BH 3 :THF with magnesium hydride byproduct. A.It was also observed that magnesium hydride can partiallyACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES A dissertation

Clary, Jacob William

2012-01-01T23:59:59.000Z

47

CO2 Reduction on Supported Ru/Al2O3 Catalysts: Cluster Size Dependence...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CO2 Reduction on Supported RuAl2O3 Catalysts: Cluster Size Dependence of Product Selectivity. CO2 Reduction on Supported RuAl2O3 Catalysts: Cluster Size Dependence of Product...

48

Enhanced Magnetism in Epitaxial SrRuO3 Thin Films  

E-Print Network [OSTI]

Enhanced Magnetism in Epitaxial SrRuO 3 A. J. Grutter, 1, 2and their e?ects on magnetism. In this paper we demonstrateXMCD con?rmed that the magnetism originates from the Ru 4+

Grutter, A.J.

2010-01-01T23:59:59.000Z

49

Complex of transferrin with ruthenium for medical applications. [Ru 97, Ru 103  

DOE Patents [OSTI]

A novel Ruthenium-transferrin complex, prepared by reacting iron-free human transferrin dissolved in a sodium acetate solution at pH 7 with ruthenium by heating at about 40/sup 0/C for about 2 hours, and purifying said complex by means of gel chromatography with pH 7 sodium acetate as eluent. The mono- or di-metal complex produced can be used in nuclear medicine in the diagnosis and/or treatment of tumors and abscesses. Comparitive results with Ga-67-citrate, which is the most widely used tumor-localizing agent in nuclear medicine, indicate increased sensitivity of detection and greater tumor uptake with the Ru-transferrin complex.

Richards, P.; Srivastava, S.C.; Meinken, G.E.

1980-11-03T23:59:59.000Z

51

Adsorption study of carbon oxides on reticulated vitreous carbon/RVC/plated with Ru electrode  

SciTech Connect (OSTI)

The adsorption of CO and CO2 on Ru/RVC and Ru/Pt electrodes has been studied by a potentiodynamic technique. It was shown that there are some differences between CO adsorption products on these two kinds of electrodes.CO2 adsorption on Ru electrode was not observed.

Czerwinski, A.

1987-04-01T23:59:59.000Z

52

PHYSICAL REVIEW B 85, 195405 (2012) Graphene on Ru(0001): Evidence for two graphene band structures  

E-Print Network [OSTI]

PHYSICAL REVIEW B 85, 195405 (2012) Graphene on Ru(0001): Evidence for two graphene band structures) High-resolution photoemission illustrates that the band structure of graphene on Ru(0001) exhibits a well- defined splitting. This splitting is largest with the graphene directly on the Ru(0001) substrate

Goodman, Wayne

53

Diruthenium Tetracarbonate Trianion, [RuII/III2(O2CO)4]3?, Based Molecule-Based Magnets: Three-Dimensional Network Structure and Two-Dimensional Magnetic Ordering  

SciTech Connect (OSTI)

HxK1-xMII[Ru2(CO3)4](H2O)y(MeOH)z (M = Mn, Fe, Co, Ni, Mg) were synthesized from the reaction of MII and K3[Ru2(CO3)4] in water and are isomorphous with an orthorhombic three-dimensional network structures based on e3-CO32- linkages to Ru2 moieties forming layers and also to trans-MII(OH2)4 sites forming linked chains that connect the layers. They, as well as non-isomorphous M = Cu, magnetically order as canted ferrimagnets with Tc = 4.4 {+-} 1.0 K. The presence of S = 0 MII = Mg(II) has essentially no effect on Tc suggesting that the main magnetic pathway does not occur the through MII-based chains, but only via Ru2{center_dot}...Ru2 linkages that reside in layers. This is a rare example of a magnet based upon a second row transition metal.

Novoa, J.; Stephens, P; Weerasekare, M; Shum, W; Miller, J

2009-01-01T23:59:59.000Z

54

Effect of MoS{sub 2} on hydrogenation storage properties of LiBH{sub 4}  

SciTech Connect (OSTI)

The hydrogen storage properties of LiBH{sub 4} ball milled with 20 wt% MoS{sub 2} have been investigated. It shows that the LiBH{sub 4} doped with MoS{sub 2} exhibits favorable hydrogenation and dehydrogenation properties in terms of decomposition temperature and hydriding/dehydriding reversibility. The sample with MoS{sub 2} starts to release hydrogen at 230 °C and has a decrease of 80 °C in contrast with pristine LiBH{sub 4}. Furthermore, for the second cycle, the LiBH{sub 4} with MoS{sub 2} maintains a reversible hydrogen storage capacity of about 8.0 wt% which is almost identical with the first cycle under 5 MPa at 550 °C. Analyzed by the XRD and the FTIR results, LiBH{sub 4} can be regenerated after re-hydrogenation under a relatively mild condition by adding MoS{sub 2}. The improvement of the hydrogenation and dehydrogenation properties mainly results from the formation of Li{sub 2}S and MoB{sub 2} during ball milling. -- Graphical abstract: Hydrogen absorption curves of LiBH{sub 4} doped with MoS{sub 2} for five cycles at 400 °C. Highlights: • The hydrogen absorption capacity is nearly the same for 5 cycles at 400 °C. • The sample with MoS{sub 2} starts to release hydrogen at 230 °C. • The coexistence of MoB{sub 2} and Li{sub 2}S catalyzes the decomposition of LiBH{sub 4}.

Liang, Dan [College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China); Han, Shumin, E-mail: hanshm@ysu.edu.cn [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China); Wang, Jiasheng [College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China); Zhang, Wei [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China); Zhao, Xin; Zhao, Ziyang [College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China)

2014-03-15T23:59:59.000Z

55

(Bh 1 2s) 1 / 58 http://ist.ksc.kwansei.ac.jp/tutimura/  

E-Print Network [OSTI]

&R (1978 G/) 7?%A%'%C%/$J$7 q ANSI C (C89, 1989 G/) 4X?t%W%m%H%?%$%W, void 7?, enum 7? q C99 (1999 G/) JC ANSI 5,3J=`5r!JBh 2 HG!K!W B.W. Kernighan, D.M. Ritchie Cx, @PED @25W K]Lu, 6&N)=PHG, 1989 G/. !J (Bh 1FALSE $OC $G$OD>@\\$OMQ0U$5$l$F$$$J$$ 3 ANSI C89 $J$i int 7?$rMQ$$$F #define FALSE 0 $J$I$H

Murota, Kazuo

56

CO adsorption on ion-exchanged Ru zeolite catalysts  

SciTech Connect (OSTI)

CO adsorption on ion-exchanged Ru zeolite catalysts, studied by IR spectroscopy, revealed the existence of three types of ruthenium which adsorbed the carbon monoxide into three different states. The ruthenium types were atomically or highly dispersed ruthenium, ruthenium clusters which formed ruthenium carbonyl, and larger (> 1 nm) particles, probably on the outer zeolite surfaces.

Goodwin, J.G. (Univ. of Pittsburgh); Naccache, G.

1980-08-01T23:59:59.000Z

57

Adsorption of intact methanol on Ru,,0001... Pawel Gazdzicki,1  

E-Print Network [OSTI]

in applications such as the direct methanol fuel cell, where Ru/Pt alloys are used as catalysts for dehydration and hydrogen/ deuterium as suggested in the literature is therefore discarded. At very low coverages or by annealing a low coverage methanol layer, hydrogen bonding leads to cluster formation, as evidenced

58

The interactions of water and perfluorodiethyl ether on Ru(100)  

SciTech Connect (OSTI)

We have studied the interactions of water and perfluorodiethyl ether on Ru(100) in order to model the effects of surface structure and humidity on the bonding and decomposition of perfluoroalkyl ether lubricants with metal surfaces. In order to understand the interactions on Ru(100), we have first investigated the interactions of each of these adsorbates alone on the clean surface. The interactions of water with Ru(100) have been studied using both thermal desorption spectroscopy (TDS) and electron energy loss spectroscopy (EELS). From these studies we conclude that a small amount of water dissociates on this surface (5--10% of a monolayer), but water is adsorbed in a predominantly molecular form on this surface with an increasing degree of hydrogen-bonding with increasing coverage. The effects of hydrogen and oxygen coadsorption on the interactions of water with this surface have also been studied using TDS. Finally, the interactions of coadsorbed water and perfluorodiethyl ether on Ru(100) have been investigated using TDS.

Leavitt, P.

1990-09-21T23:59:59.000Z

59

Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol  

SciTech Connect (OSTI)

Abstract Carbon supported metal catalysts (Cu/C, Fe/C, Pd/C, Pt/C, PdFe/C and Ru/C) have been prepared, characterized and tested for vapor-phase hydrodeoxygenation (HDO) of guaiacol (GUA) at atmospheric pressure. Phenol was the major intermediate on all catalysts. Over the noble metal catalysts saturation of the aromatic ring was the major pathway observed at low temperature (250 °C), forming predominantly cyclohexanone and cyclohexanol. Substantial ring opening reaction was observed on Pt/C and Ru/C at higher reaction temperatures (e.g., 350 °C). Base metal catalysts, especially Fe/C, were found to exhibit high HDO activity without ring-saturation or ring-opening with the main products being benzene, phenol along with small amounts of cresol, toluene and trimethylbenzene (TMB). A substantial enhancement in HDO activity was observed on the PdFe/C catalysts. Compared with Fe/C, the yield to oxygen-free aromatic products (i.e., benzene/toluene/TMB) on PdFe/C increased by a factor of four at 350 °C, and by approximately a factor of two (83.2% versus 43.3%) at 450 °C. The enhanced activity of PdFe/C is attributed to the formation of PdFe alloy as evidenced by STEM, EDS and TPR.

Sun, Junming; Karim, Ayman M.; Zhang, He; Kovarik, Libor; Li, Xiaohong S.; Hensley, Alyssa; McEwen, Jean-Sabin; Wang, Yong

2013-10-01T23:59:59.000Z

60

The Fast Evolution of SN 2010bh associated with XRF 100316D  

E-Print Network [OSTI]

About a decade ago the first observational evidence of the connection between supernovae and gamma-ray bursts was found. Since then, only half a dozen spectroscopically confirmed associations have been discovered and XRF 100316D/SN 2010bh lies among the latest. Starting observations at 12 hr and continuing until 80 days after the burst, GROND provided excellent photometric data of XRF 100316D/SN 2010bh in six filter bands from the optical to the near-infrared, significantly expanding the existing data set for this event. Combining GROND and Swift/UVOT+XRT data, the early SED is modelled with a blackbody and afterglow component attenuated by dust and gas absorption. The best-fit models imply a moderate host-galaxy extinction (A_V=1.2\\pm0.1 mag). Furthermore, temperature and radius evolution of the thermal component are combined with earlier measurements available from the literature. The analysis reveals a cooling envelope at an apparent initial radius of 7\\times10^11 cm, compatible with a dense wind surroundi...

E., Felipe Olivares; Schady, Patricia; Rau, Arne; Klose, Sylvio; Krühler, Thomas; Afonso, Paulo M J; Updike, Adria C; Nardini, Marco; Filgas, Robert; Guelbenzu, Ana Nicuesa; Clemens, Christian; Elliott, Jonny; Kann, D Alexander; Rossi, Andrea; Sudilovsky, Vladimir

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The Chemistry of Trimethylamine on Ru(001) and O/Ru(001) B. F. Hallac and M. Asscher*  

E-Print Network [OSTI]

of Physical Chemistry and the Farkas Center for Light Induced Processes, The Hebrew UniVersity of Jerusalem of trimethylamine (TMA) has been studied over clean and oxygen-covered Ru(001) under UHV conditions, as a model dissociates upon surface heating, with hydrogen as the only evolving molecule following temperature

Asscher, Micha

62

Biased interface between solid ion conductor LiBH{sub 4} and lithium metal: A first principles molecular dynamics study  

SciTech Connect (OSTI)

We use first-principles molecular dynamics to study the electrochemical solid-solid interface between lithium metal and lithium electrolyte LiBH{sub 4}. An external bias is applied by using an effective screening medium. We observe large polarization in the LiBH{sub 4}, because the lithium cations in LiBH{sub 4} are shifted more on one side of the double-well potential of Li{sup +}. This results in a large potential drop in the interface region and a large double-layer capacity corresponding to ca. 70 ?F/cm{sup 2}. H-coordination to the Li atoms plays an important role in the charge-transfer reaction and ion transfer.

Ikeshoji, Tamio [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan) [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan); Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 2, 1-1-1 Umezono, Tsukuba 305-8568 (Japan); Ando, Yasunobu; Otani, Minoru; Tsuchida, Eiji [Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 2, 1-1-1 Umezono, Tsukuba 305-8568 (Japan)] [Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 2, 1-1-1 Umezono, Tsukuba 305-8568 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan)] [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan) [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan)

2013-09-23T23:59:59.000Z

63

Odd-Z Transactinide Compound Nucleus Reactions Including the Discovery of 260Bh  

SciTech Connect (OSTI)

Several reactions producing odd-Z transactinide compound nuclei were studiedwith the 88-Inch Cyclotron and the Berkeley Gas-Filled Separator at the LawrenceBerkeley National Laboratory. The goal was to produce the same compound nucleus ator near the same excitation energy with similar values of angular momentum via differentnuclear reactions. In doing so, it can be determined if there is a preference in entrancechannel, because under these experimental conditions the survival portion of Swiatecki, Siwek-Wilcznska, and Wilczynski's"Fusion By Diffusion" model is nearly identical forthe two reactions. Additionally, because the same compound nucleus is produced, theexit channel is the same. Four compound nuclei were examined in this study: 258Db, 262Bh, 266Mt, and 272Rg. These nuclei were produced by using very similar heavy-ion induced-fusion reactions which differ only by one proton in the projectile or target nucleus (e.g.: 50Ti + 209Bi vs. 51V + 208Pb). Peak 1n exit channel cross sections were determined for each reaction in each pair, and three of the four pairs' cross sections were identical within statistical uncertainties. This indicates there is not an obvious preference of entrancechannel in these paired reactions. Charge equilibration immediately prior to fusionleading to a decreased fusion barrier is the likely cause of this phenomenon. In addition to this systematic study, the lightest isotope of element 107, bohrium, was discovered in the 209Bi(52Cr,n) reaction. 260Bh was found to decay by emission of a 10.16 MeV alpha particle with a half-life of 35 ms. The cross section is 59 pb at an excitation energy of 15.0 MeV. The effect of the N = 152 shell is also seen in this isotope's alpha particle energy, the first evidence of such an effect in Bh. All reactions studied are also compared to model predictions by Swiatecki, Siwek-Wilcznska, and Wilczynski's"Fusion By Diffusion" theory.

Nelson, Sarah L; Nelson, Sarah L

2008-05-14T23:59:59.000Z

64

The alpha-cluster model applied to {sup 96}Ru  

SciTech Connect (OSTI)

The states of {sup 96}Ru are investigated in terms of the a alpha+ core structure. The ground state band of the alpha+{sup 92}Mo system is obtained through a local cluster-core potential which includes a fixed set of parameters employed in other mass regions. The calculated spectrum gives a good general description of the experimental {sup 96}Ru levels. The reduced alpha-widths, B(E2) transition rates and rms intercluster separations are determined for the members of the ground state band. The results show that the model can reproduce the order of magnitude of the experimental B(E2) values without the use of effective charges and indicate that the first members of the ground state band present a stronger alpha-cluster character. Predictions concerning a negative parity band of the alpha+{sup 92}Mo system are also shown.

Souza, M. A.; Miyake, H. [Institute of Physics, Universidade de Sao Paulo, Sao Paulo-SP (Brazil)

2010-05-21T23:59:59.000Z

65

Masses of Fe-61 and Fe-62  

E-Print Network [OSTI]

PHYSICAL RKVIK% C VO LUMK 15, N UMBKB, 5 Masses of 'Fe and Fef MA Y 1977 J. D. Cossairt, R. E. Tribble, * and R. A. Kenefick Cyclotron Institute, Texas A AM University, College Station, Texas 77843 (Received 4 October 1976) The mass excesses... of 'Fe and Fe have been measured using the Ni(a, Be) 'Fe and Ni("B,"N) Fe reactions. The mass excesses obtained are M( 'Fe) = ?58.92 ~ 0.02 MeV and M("Fe) = ?58.85 + 0.07 MeV. The results are consistent with recent predictions from two different mass...

Cossairt, J. D.; Tribble, Robert E.; Kenefick, R. A.

1977-01-01T23:59:59.000Z

66

Synthesis and characterization of phosphine adducts of thorium borohydride, Crystal structures of Th(BH4)4(PEt3)2 and Th(BH4)4(Me2PCH2CH2PMe2)2  

E-Print Network [OSTI]

Synthesis and characterization of phosphine adducts of thorium borohydride, Th(BH4)4 Crystal: Thorium Phosphine Trialkylphosphine Borohydride Tetrahydroborate Crystal structures a b s t r a c NMR spectroscopy. The results show that thorium complexes of unidentate phosphines can be made

Girolami, Gregory S.

67

Dimerization Induced Deprotonation of Water on RuO2(110)  

SciTech Connect (OSTI)

RuO2 has proven to be indispensable as a co-catalyst in numerous systems designed for photocatalytic water splitting. In this study we have carried out a detailed mechanistic study of water behavior on the most stable RuO2 face, RuO2(110), by employing variable temperature scanning tunneling microscopy and density functional theory calculations. We show that water monomers adsorb molecularly on Ru sites, become mobile above 238 K, diffuse along the Ru rows and form water dimers. The onset for dimer diffusion is observed at ~277 K indicating significantly higher diffusion barrier than that for monomers. More importantly, we find that water dimers deprotonate readily to form Ru-bound H3O2 and bridging OH species. The observed behavior is compared and contrasted with that observed for water on isostructural rutile TiO2(110).

Mu, Rentao; Cantu Cantu, David; Lin, Xiao; Glezakou, Vassiliki Alexandra; Wang, Zhitao; Lyubinetsky, Igor; Rousseau, Roger J.; Dohnalek, Zdenek

2014-10-02T23:59:59.000Z

68

Investigation of high temperature gaseous species by Knudsen cell mass spectrometry above the condensed systems Cu-Y-Ru-C, Ag-Y-Ru-C, and Au-Y- Ru-C  

E-Print Network [OSTI]

of the total ion intensities listed in Tables 2 through 5, + + except those for RuC and YC2, were calculated by dividing the individual isotopic species by the isotopic abundance of that species according to Equation 1, where I is the total intensity of all... not be used because their mass to charge ratios overlap. For these iona, an + algebraic equation was used which compared the ratios of YC (Mass 113), YC2 (Mass 114), RuC (Mass 113), and RuC (Mass 114). The + + + calculated isotopic abundances...

Wilhite, Dale Wayne

1988-01-01T23:59:59.000Z

69

A candidate LiBH4 for hydrogen storage: Crystal structures and reaction mechanisms of intermediate phases  

E-Print Network [OSTI]

combustion engine for transporta- tion. A hydrogen fuel cell car needs to store at least 4 kg hydrogenA candidate LiBH4 for hydrogen storage: Crystal structures and reaction mechanisms of intermediate phases Jeung Ku Kanga and Se Yun Kim Department of Materials Science and Engineering, KAIST, Daejeon 305

Goddard III, William A.

70

Journal of Power Sources 165 (2007) 509516 Direct NaBH4/H2O2 fuel cells  

E-Print Network [OSTI]

Published by Elsevier B.V. Keywords: Fuel cell; Hydrogen peroxide; Regenerative fuel cell; Sodium) /hydrogen per- oxide (H2O2) fuel cell (FC) is under development jointly by the University of IllinoisJournal of Power Sources 165 (2007) 509­516 Direct NaBH4/H2O2 fuel cells George H. Mileya,e,, Nie

Carroll, David L.

71

Hydriding and dehydriding characteristics of LiBH{sub 4} and transition metals-added magnesium hydride  

SciTech Connect (OSTI)

Graphical abstract: Hydriding reaction curves under 12 bar H{sub 2}, and dehydriding reaction curves under 1.0 bar H{sub 2}, at 593 K at the 1st cycle for MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti and MgH{sub 2}. Highlights: ? Addition of Ni, LiBH{sub 4}, and Ti to MgH{sub 2} to increase reaction rates. ? Sample preparation by reactive mechanical grinding. ? At n = 2, the sample absorbed 4.05 wt% H for 60 min at 593 K under 12 bar H{sub 2}. ? Analysis of rate-controlling step for dehydriding of the sample at n = 3. - Abstract: In this study, MgH{sub 2} was used as a starting material instead of Mg. Ni, Ti, and LiBH{sub 4} with a high hydrogen-storage capacity of 18.4 wt% were added. A sample with a composition of MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti was prepared by reactive mechanical grinding. The activation of MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti was completed after the first hydriding–dehydrding cycle. The hydriding rate decreases as the temperature increases due to the decrease in the driving force for the hydriding reaction. At the 1st cycle, the sample desorbs 1.45 wt% H for 10 min, 2.54 wt% H for 20 min, 3.13 wt% H for 30 min, and 3.40 wt% H for 60 min at 593 K under 1.0 bar H{sub 2}. At the 2nd cycle, the sample absorbs 3.84 wt% H for 5 min, 3.96 wt% H for 10 min, and 4.05 wt% H for 60 min at 593 K under 12 bar H{sub 2}. MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti after reactive mechanical grinding contained MgH{sub 2}, Mg, Ni, TiH{sub 1.924}, and MgO phases. The reactive mechanical grinding of Mg with Ni, LiBH{sub 4}, and Ti is considered to create defects on the surface and in the interior of Mg (to facilitate nucleation), and to reduce the particle size of Mg (to shorten diffusion distances of hydrogen atoms). The formation of Mg{sub 2}Ni during hydriding–dehydriding cycling increases the hydriding and dehydriding rates of the sample.

Song, Myoung Youp, E-mail: songmy@jbnu.ac.kr [Division of Advanced Materials Engineering, Hydrogen and Fuel Cell Research Center, Engineering Research Institute, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju, 561-756 (Korea, Republic of); Kwak, Young Jun; Lee, Seong Ho [Department of Materials Engineering, Graduate School, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju, 561-756 (Korea, Republic of); Park, Hye Ryoung [Faculty of Applied Chemical Engineering, Chonnam National University, 300 Yongbongdong, Bukgu, Gwangju, 500-757 (Korea, Republic of)

2013-07-15T23:59:59.000Z

72

Synthesis of Ru/multiwalled carbon nanotubes by microemulsion for electrochemical supercapacitor  

SciTech Connect (OSTI)

An efficient way to decorate multiwalled carbon nanotubes with Ru had been developed. In this method, Ru nanoparticles were prepared by water-in-oil reverse microemulsion, and the produced Ru anchored on MWCNTs. Transmission electron microscopy (TEM) result showed that RuO{sub 2} nanoparticles had the uniform size distribution after electrochemical oxidation. Energy dispersive X-rays (EDX) spectra elucidated the presence of ruthenium oxide in the as-prepared composites after electrochemical oxidation. Cyclic voltammetry result demonstrated that a specific capacitance of deposited ruthenium oxide electrode was significantly greater than that of the pristine MWCNTs electrode in the same medium.

Yan Shancheng; Qu Peng; Wang Haitao; Tian Tian [State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Si Pai Lou 2, Nanjing 210096 (China); Xiao Zhongdang [State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Si Pai Lou 2, Nanjing 210096 (China)], E-mail: zdxiao@seu.edu.cn

2008-10-02T23:59:59.000Z

73

The kinetics of CO poisoning in simulated reformate and effect of Ru island morphology on PtRu fuel cell catalysts as determined by operando XANES  

SciTech Connect (OSTI)

In situ X-ray absorption spectroscopy (XAS) measurements, including both X-ray absorption near edge spectroscopy (XANES) and extended X-ray absorption fine structure (EXAFS), were carried out on commercially produced Pt and PtRu bimetallic electrocatalysts as well as on a mechanically mixed PtRu bimetallic electrocatalyst in an operating fuel cell in H{sub 2} doped with 150 ppm CO. By use of the novel {Delta}XANES technique, the coverages of CO and ontop and n-fold H (overpotential deposited and underpotential deposited hydrogen) are obtained and compared for the three catalysts, and the results are correlated with PtRu cluster morphology. The mechanical mixing process used to create the bimetallic PtRu catalyst is found to maximize CO tolerance, although the PtRu commercial electrocatalyst exhibits an increased electronic effect, most probably due to the presence of Ru(O){sub x} islands at the catalyst surface. The mobility of the CO on both Ru and Pt is found to be sharply dependent on the CO coverage, decreasing dramatically beyond 0.4 fractional coverage.

Scott, F.; Roth, C; Ramaker, D

2007-01-01T23:59:59.000Z

74

MAGIC observations of MWC 656, the only known Be/BH system  

E-Print Network [OSTI]

Context: MWC 656 has recently been established as the first observationally detected high-mass X-ray binary system containing a Be star and a black hole (BH). The system has been associated with a gamma-ray flaring event detected by the AGILE satellite in July 2010. Aims: Our aim is to evaluate if the MWC 656 gamma-ray emission extends to very high energy (VHE > 100 GeV) gamma rays. Methods. We have observed MWC 656 with the MAGIC telescopes for $\\sim$23 hours during two observation periods: between May and June 2012 and June 2013. During the last period, observations were performed contemporaneously with X-ray (XMM-Newton) and optical (STELLA) instruments. Results: We have not detected the MWC 656 binary system at TeV energies with the MAGIC Telescopes in either of the two campaigns carried out. Upper limits (ULs) to the integral flux above 300 GeV have been set, as well as differential ULs at a level of $\\sim$5\\% of the Crab Nebula flux. The results obtained from the MAGIC observations do not support persis...

,

2015-01-01T23:59:59.000Z

75

Low leakage Ru-strontium titanate-Ru metal-insulator-metal capacitors for sub-20?nm technology node in dynamic random access memory  

SciTech Connect (OSTI)

Improved metal-insulator-metal capacitor (MIMCAP) stacks with strontium titanate (STO) as dielectric sandwiched between Ru as top and bottom electrode are shown. The Ru/STO/Ru stack demonstrates clearly its potential to reach sub-20?nm technology nodes for dynamic random access memory. Downscaling of the equivalent oxide thickness, leakage current density (J{sub g}) of the MIMCAPs, and physical thickness of the STO have been realized by control of the Sr/Ti ratio and grain size using a heterogeneous TiO{sub 2}/STO based nanolaminate stack deposition and a two-step crystallization anneal. Replacement of TiN with Ru as both top and bottom electrodes reduces the amount of electrically active defects and is essential to achieve a low leakage current in the MIM capacitor.

Popovici, M., E-mail: Mihaela.Ioana.Popovici@imec.be; Swerts, J.; Redolfi, A.; Kaczer, B.; Aoulaiche, M.; Radu, I.; Clima, S.; Everaert, J.-L.; Van Elshocht, S.; Jurczak, M. [Imec, Leuven 3001 (Belgium)

2014-02-24T23:59:59.000Z

76

Dynamic Characterization of Graphene Growth and Etching by Oxygen on Ru(0001) by Photoemission Electron Microscopy  

E-Print Network [OSTI]

Dynamic Characterization of Graphene Growth and Etching by Oxygen on Ru(0001) by Photoemission of graphene on Ru(0001) was investigated by photoemission electron microscopy (PEEM) and scanning tunneling, we show that graphene overlayers with sizes ranging from nanometers to sub-millimeters have been

Bao, Xinhe

77

Surface Science Letters Spontaneous deposition of Pd on a Ru(0 0 0 1) surface  

E-Print Network [OSTI]

deposition of Pd on a Pt(1 1 1) electrode, monolayer [3], or submonolayer [4,7] coverages were reportedSurface Science Letters Spontaneous deposition of Pd on a Ru(0 0 0 1) surface S.R. Brankovic, J. Mc March 2001 Abstract Spontaneous deposition of Pd on a Ru(0 0 0 1) single crystal surface has been

Brankovic, Stanko R.

78

Enhanced Thermoelectric Power and Electronic Correlations in RuSe2  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

We report the electronic structure, electric and thermal transport properties of Ru1-xIrxSe2 (x ? 0:2). RuSe2 is a semiconductor that crystallizes in a cubic pyrite unit cell. The Seebeck coefficient of RuSe2 exceeds -200 ?#22;V/K around 730 K. Ir substitution results in the suppression of the resistivity and the Seebeck coefficient, suggesting the removal of the peaks in density of states near the Fermi level. Ru0.8Ir0.2Se2 shows a semiconductor-metal crossover at about 30 K. The magnetic field restores the semiconducting behavior. Our results indicate the importance of the electronic correlations in enhanced thermoelectricity of RuSb2.

Wang, Kefeng [Brookhaven National Laboratory (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.; Wang, Aifeng [Brookhaven National Laboratory (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.; Tomic, A. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.; Wang, Limin [Brookhaven National Laboratory (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.; Abeykoon, A.M. Milinda [Brookhaven National Laboratory (BNL), Upton, NY (United States). Photon Sciences Directorate; Dooryhee, E. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Photon Sciences Directorate; Billinge, S. J.L. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.; Columbia Univ., New York, NY (United States); Petrovic, C. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.

2015-04-01T23:59:59.000Z

79

Syntrophic Effects in a Subsurface Clostridial Consortium on Fe(III)-(Oxyhydr)oxide Reduction and Secondary Mineralization  

SciTech Connect (OSTI)

In this study, we cultivated from subsurface sediments an anaerobic Clostridia 25 consortium that was composed of a fermentative Fe-reducer Clostridium species (designated as 26 strain FGH) and a novel sulfate-reducing bacterium belonging to the Clostridia family 27 Vellionellaceae (designated as strain RU4). In pure culture, Clostridium sp. strain FGH mediated 28 the reductive dissolution/transformation of iron oxides during growth on peptone. When 29 Clostridium sp. FGH was grown with strain RU4 on peptone, the rates of iron oxide reduction 30 were significantly higher. Iron reduction by the consortium was mediated by multiple 31 mechanisms, including biotic reduction by Clostridium sp. FGH and biotic/abiotic reactions 32 involving biogenic sulfide by strain RU4. The Clostridium sp. FGH produced hydrogen during 33 fermentation, and the presence of hydrogen inhibited growth and iron reduction activity. The 34 sulfate-reducing partner strain RU4 was stimulated by the presence of H2 gas and generated 35 reactive sulfide which promoted the chemical reduction of the iron oxides. Characterization of 36 Fe(II) mineral products showed the formation of magnetite during ferrihydrite reduction, and 37 the precipitation of iron sulfides during goethite and hematite reduction. The results suggest an 38 important pathway for iron reduction and secondary mineralization by fermentative sulfate-39 reducing microbial consortia is through syntrophy-driven biotic/abiotic reactions with biogenic 40 sulfide.

Shah, Madhavi; Lin, Chu-Ching; Kukkadapu, Ravi K.; Engelhard, Mark H.; Zhao, Xiuhong; Wang, Yangping; Barkay, Tamar; Yee, Nathan

2013-12-02T23:59:59.000Z

80

The Evolution of the M_BH-sigma relation Inferred from the Age Distribution of Local Early-Type Galaxies and AGN Evolution  

E-Print Network [OSTI]

We utilize the local velocity dispersion function (VDF) of spheroids, together with their inferred age--distributions, to predict the VDF at higher redshifts (01.3 excluded at the 99% confidence level. A direct match between the characteristic BH mass in the VDF--based and quasar LF--based BH mass functions also yields a mean Eddington ratio of lambda ~ 0.5-1 that is roughly constant within 00.23 for alpha>1.5. abridged

Shankar, Francesco; Haiman, Zoltan

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

THE M {sub BH}-L {sub SPHEROID} RELATION AT HIGH AND LOW MASSES, THE QUADRATIC GROWTH OF BLACK HOLES, AND INTERMEDIATE-MASS BLACK HOLE CANDIDATES  

SciTech Connect (OSTI)

From a sample of 72 galaxies with reliable supermassive black hole masses M {sub bh}, we derive the M {sub bh}-(host spheroid luminosity, L) relation for (1) the subsample of 24 core-Sersic galaxies with partially depleted cores, and (2) the remaining subsample of 48 Sersic galaxies. Using K{sub s} -band Two Micron All Sky Survey data, we find the near-linear relation M {sub bh}{proportional_to}L {sup 1.10{+-}0.20} {sub K{sub s}} for the core-Sersic spheroids thought to be built in additive dry merger events, while we find the relation M {sub bh}{proportional_to}L {sup 2.73{+-}0.55}{sub K{sub s}} for the Sersic spheroids built from gas-rich processes. After converting literature B-band disk galaxy magnitudes into inclination- and dust-corrected bulge magnitudes, via a useful new equation presented herein, we obtain a similar result. Unlike with the M {sub bh}-(velocity dispersion) diagram, which is also updated here using the same galaxy sample, it remains unknown whether barred and non-barred Sersic galaxies are offset from each other in the M {sub bh}-L diagram. While black hole feedback has typically been invoked to explain what was previously thought to be a nearly constant M {sub bh}/M {sub Spheroid} mass ratio of {approx}0.2%, we advocate that the near-linear M {sub bh}-L and M {sub bh}-M {sub Spheroid} relations observed at high masses may have instead arisen largely from the additive dry merging of galaxies. We argue that feedback results in a dramatically different scaling relation, such that black hole mass scales roughly quadratically with the spheroid mass in Sersic galaxies. We therefore introduce a revised cold-gas 'quasar' mode feeding equation for semi-analytical models to reflect what we dub the quadratic growth of black holes in Sersic galaxies built amidst gas-rich processes. Finally, we use our new Sersic M {sub bh}-L equations to predict the masses of candidate intermediate mass black holes in almost 50 low-luminosity spheroids containing active galactic nuclei, finding many masses between that of stellar mass black holes and supermassive black holes.

Graham, Alister W.; Scott, Nicholas, E-mail: AGraham@swin.edu.au [Centre for Astrophysics and Supercomputing, Swinburne University of Technology, Hawthorn, Victoria 3122 (Australia)] [Centre for Astrophysics and Supercomputing, Swinburne University of Technology, Hawthorn, Victoria 3122 (Australia)

2013-02-20T23:59:59.000Z

82

Search for 2\\beta\\ decays of 96Ru and 104Ru by ultra-low background HPGe gamma spectrometry at LNGS: final results  

E-Print Network [OSTI]

An experiment to search for double beta decay processes in 96Ru and 104Ru, which are accompanied by gamma rays, has been realized in the underground Gran Sasso National Laboratories of the I.N.F.N. (Italy). Ruthenium samples with masses of about (0.5-0.7) kg were measured with the help of ultra-low background high purity Ge gamma ray spectrometry. After 2162 h of data taking the samples were deeply purified to reduce the internal contamination of 40K. The last part of the data has been accumulated over 5479 h. New improved half life limits on 2\\beta+/\\epsilon \\beta+/2\\epsilon\\ processes in 96Ru have been established on the level of 10^{20} yr, in particular for decays to the ground state of 96Mo: T1/2(2\

Belli, P; Cappella, F; Cerulli, R; Danevich, F A; d'Angelo, S; Incicchitti, A; Kovtun, G P; Kovtun, N G; Laubenstein, M; Poda, D V; Polischuk, O G; Shcherban, A P; Solopikhin, D A; Suhonen, J; Tretyak, V I

2013-01-01T23:59:59.000Z

83

Search for 2? decays of 96Ru and 104Ru by ultra-low background HPGe gamma spectrometry at LNGS: final results  

E-Print Network [OSTI]

An experiment to search for double beta decay processes in 96Ru and 104Ru, which are accompanied by gamma rays, has been realized in the underground Gran Sasso National Laboratories of the I.N.F.N. (Italy). Ruthenium samples with masses of about (0.5-0.7) kg were measured with the help of ultra-low background high purity Ge gamma ray spectrometry. After 2162 h of data taking the samples were deeply purified to reduce the internal contamination of 40K. The last part of the data has been accumulated over 5479 h. New improved half life limits on 2\\beta+/\\epsilon \\beta+/2\\epsilon\\ processes in 96Ru have been established on the level of 10^{20} yr, in particular for decays to the ground state of 96Mo: T1/2(2\

P. Belli; R. Bernabei; F. Cappella; R. Cerulli; F. A. Danevich; S. d'Angelo; A. Incicchitti; G. P. Kovtun; N. G. Kovtun; M. Laubenstein; D. V. Poda; O. G. Polischuk; A. P. Shcherban; D. A. Solopikhin; J. Suhonen; V. I. Tretyak

2013-02-28T23:59:59.000Z

84

In situ Ru K-edge x-ray absorption fine structure studies of electroprecipitated ruthenium dioxide films with relevance to supercapacitor applications.  

SciTech Connect (OSTI)

Modifications in electronic and structural aspects of RuO{sub 2} films electroprecipitated onto Au electrodes induced by changes in the applied potential have been examined in situ in aqueous 0.50 M H{sub 2}SO{sub 4} by Ru K-edge X-ray absorption spectroscopy (XAS). The Fourier transform of the k{sup 3}-weighted extended X-ray absorption fine structure (EXAFS), k{sup 3}x(k), for the film polarized at +1.20V vs RHE is characterized by two shells attributed to Ru-O and Ru-Ru interactions with average distances of 1.94(1) and 3.12(2) {angstrom}, respectively, in agreement with results obtained ex situ for Ru{sup 4+} in hydrous RuO{sub 2} by other groups. In contrast, films in the reduced state, i.e., +0.40 V vs RHE, yielded only a single shell ascribed to a Ru-O interaction at 2.02(1) {angstrom} with no evidence for a distant Ru-Ru shell. The long Ru-O distance is in agreement with that reported earlier for the hydrous Ru{sup 3+} ion [Ru-(OH{sub 2}){sub 6}]{sup 3+} in the solid state. Moreover, the difference between the average Ru-O bond lengths for the reduced and oxidized films is consistent with the difference in the ionic radii of Ru{sup 3+} and Ru{sup 4+}. On this basis it has been suggested that films in the reduced state contain Ru{sup 3+} sites, consistent with the electrochemical results, in a phase with apparently less order beyond the Ru-O coordination sphere than for hydrous RuO{sub 2}.

Mo, Y.; Antonio, M. R.; Stefan, I. C.; Scherson, D. A.; Chemistry; Case Western Reserve Univ.

2000-10-26T23:59:59.000Z

85

Interfacial electron transfer dynamics of ru(II)-polypy6ridine sensitized TiO2  

SciTech Connect (OSTI)

Quantum dynamics simulations combined with density functional theory calculations are applied to study interfacial electron transfer (IET) from pyridine-4-phosphonic acid, [Ru(tpy)(tpy(PO{sub 3}H{sub 2}))]{sup 2+} and [Ru(tpy)(bpy)(H{sub 2}O)-Ru(tpy)(tpy(PO{sub 3}H{sub 2}))]{sup 4+} into the (101) surface of anatase TiO{sub 2}. IET rate from pyridine-4-phosphonic acid attached to the nanoparticle in bidentate mode ({tau} {approx} 100 fs) is an order of magnitude faster than the IET rate of the adsorbate attached in the monodentate mode ({tau} {approx} 1 ps). Upon excitation with visible light, [Ru(tpy)(tpy(PO{sub 3}H{sub 2}))]{sup 2+} attached to TiO{sub 2} in bidentate binding mode will undergo IET with the rate of {approx} 1-10 ps, which is competitive with the excited state decay into the ground state. The probability of electron injection from [Ru(tpy)(bpy)(H{sub 2}O)-Ru(tpy)(tpy(PO{sub 3}H{sub 2}))]{sup 4+} is rather low, as the excitation with visible light localizes the excited electron in the tpy-tpy bridge, which does not have favorable coupling with the TiO{sub 2} nanoparticle. The results are relevant to better understanding of the adsorbate features important for promoting efficient interfacial electron transfer into the semiconductor.

Jakubikova, Elena [Los Alamos National Laboratory; Martin, Richard L [Los Alamos National Laboratory; Batista, Enrique R [Los Alamos National Laboratory; Snoeberger, Robert C [YALE UNIV.; Batista, Victor S [YALE UNIV.

2009-01-01T23:59:59.000Z

86

XRF 100316D/SN 2010bh: clue to the diverse origin of nearby supernova-associated GRBs  

E-Print Network [OSTI]

X-ray Flash (XRF) 100316D, a nearby super-long under-luminous burst with a peak energy E_p \\sim 20 keV, was detected by Swift and was found to be associated with an energetic supernova SN 2010bh. Both the spectral and the temporal behavior of this burst are rather similar to that of XRF 060218, except that the latter was associated with a "less energetic" SN 2006aj and had a prominent soft thermal emission component in the spectrum. We analyze the spectral and temporal properties of this burst, and interpret the prompt gamma-ray emission and the early X-ray plateau emission as synchrotron emission from a dissipating Poynting-flux-dominated outflow, probably powered by a magnetar with a spin period of $P \\sim 10$ ms and the polar cap magnetic field $B_{\\rm p} \\sim 3\\times 10^{15}$ G. The energetic supernova SN 2010bh associated with this burst is, however, difficult to interpret within the slow magnetar model, which implies that the nascent magnetar may spin much faster with an initial rotation period $\\sim 1$...

Fan, Yi-Zhong; Xu, Dong; Liang, En-Wei; Zhang, Bing

2010-01-01T23:59:59.000Z

87

Quantum effects in the diffusion of hydrogen on Ru(0001)  

E-Print Network [OSTI]

An understanding of hydrogen diffusion on metal surfaces is important, not just for its role in heterogeneous catalysis and hydrogen fuel cell technology, but also because it provides model systems where tunneling can be studied under well-defined conditions. Here we report helium spin-echo measurements of the atomic-scale motion of hydrogen on the Ru(0001) surface between 75 and 250 K. Quantum effects are evident at temperatures as high as 200 K, while below 120 K we observe a tunneling-dominated temperature independent jump rate of 1.9$\\times$10$^9$ s$^{-1}$, many orders of magnitude faster than previously seen. Quantum transition state theory calculations based on ab initio path-integral simulations reproduce the temperature dependence of the rate at higher temperatures and predict a crossover to tunneling-dominated diffusion at low temperatures, although the tunneling rate is under-estimated, highlighting the need for future experimental and theoretical studies of hydrogen diffusion on well-defined surfac...

McIntosh, Eliza M; Ellis, John; Michaelides, Angelos; Allison, William

2014-01-01T23:59:59.000Z

88

Studies on the sulfur poisoning of Ru-RuO{sub x}/TiO{sub 2} catalyst for the adsorption and methanation of carbon monoxide  

SciTech Connect (OSTI)

The effects of sulfur poisoning on the chemisorption and on the methanation of carbon monoxide over Ru/TiO{sub 2} catalyst were investigated by FTIR spectroscopy and volumetric gas adsorption measurements. The CS{sub 2} molecules are {eta}` bonded to Ru sites through one of the sulfur atoms and decompose to the constituent elements on thermal activation. Each S atom may deactivate 3 to 10 metal sites even at low coverages, the effect being more pronounced on the chemisorption of hydrogen. The deposited sulfur (and possibly carbon also) sterically hinders the formation of certain multicarbonyl and monocarbonyl species (vCO in 2055-2140 cm{sup -1} region), which otherwise transform to methane via surface methylene groups in the presence of chemisorbed hydrogen and are found to play an important role in the low-temperature methanation activity of the studied catalyst. The Ru-CO species giving rise to lower frequency vibrational bands are affected to a lesser extent. The presence of sulfur also results in the development of some new CO binding states which are weak and are identified with the CO and S coadsorbed at Ru sites of different oxidation states or of varying crystallographic nature. The CO adsorbed in these states is not reactive to hydrogen. 45 refs., 9 figs., 1 tab.

Kamble, V.S.; Londhe, V.P.; Gupta, N.M. [Bhambha Atomic Research centre, Bombay (India)] [and others] [Bhambha Atomic Research centre, Bombay (India); and others

1996-02-01T23:59:59.000Z

89

Getting to Santa Fe  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Capital City Cab (Santa Fe taxi company) - 50 each way. Reservation not required Hertz car rental (LANL discount code 72120) National car rental (in town location) - (LANL...

90

Charge transfer switching in photoexcited Ru(II) porphyrins: A time-resolved resonance Raman and spectroelectrochemical study  

SciTech Connect (OSTI)

The charge transfer (CT) excited states of Ru(II)OEP(Py){sub 2} and Ru(II)TPP(Py){sub 2} (TPP=tetraphenylporphyrin, OEP=octaethylporphyrin, and Py=pyridine) have been investigated by nanosecond time-resolved resonance Raman(TR{sup 3}) spectroscopy. The spectra reveal unexpected differences between the two species. The TR{sup 3} spectrum of [Ru(II)TPP(Py){sub 2}]{sup *} resembles the resonance Raman (RR) spectrum of the RuTPP(Py){sub 2} radical anion. Both spectra show strong enhancement of nontotally symmetric modes, resulting from a Jahn-Teller distortion due to the e{sub g}{sup *} orbital degeneracy. The band frequencies are slightly higher in the CT state than in the radical anion, reflecting the effect of the Ru(II) oxidation. Thus, the TR{sup 3} spectral features support a {sup 3}(d{pi},{pi}{sup *}) excited state assignment, with an electron transferred from Ru(II) to the porphyrin. In contrast, the TR3 spectrum [Ru(II)OEP(Py){sub 2}]{sup *} does not resemble the RR spectra of the Ru(II)OEP radical anion. Rather, it contains totally symmetric modes, at frequencies close to those of Ru(II)OEP(Py){sub 2}. In addition, bound pyridine modes appear at 1208 and 1603 cm{sup -1} in the TR{sup 3} spectrum and they shift upon pyridine perdeuteration. These characteristics imply electron transfer from Ru(II) to bound pyridine, instead of porphyrin, for the CT state of Ru(II)OEP(Py){sub 2}. 38 refs., 11 figs., 4 tabs.

Vitols, S.E.; Kumble, R.; Blackwood, M.E. Jr.; Roman, J.S.; Spiro, T.G. [Princeton Univ., NJ (United States)] [Princeton Univ., NJ (United States)

1996-03-07T23:59:59.000Z

91

The Effects of Oxygen Plasma on the Chemical Composition and Morphology of the Ru Capping Layer of the Extreme Ultraviolet (EUV) Mask Blanks  

E-Print Network [OSTI]

P-5B-03 The effects of oxygen plasma on the chemicalRu) mask surface after oxygen plasma treatment using surfacein the subsurface oxygen concentration, Ru oxidation and

Belau, Leonid

2009-01-01T23:59:59.000Z

92

The influence of microstructure on magnetic properties of nanocrystalline Fe-Pt-Nb-B permanent magnet ribbons  

SciTech Connect (OSTI)

A FePt-based hard-magnetic nanocomposite of exchange spring type was prepared by isothermal annealing of melt-spun Fe{sub 52}Pt{sub 28}Nb{sub 2}B{sub 18} (atomic percent) ribbons. The relationship between microstructure and magnetic properties was investigated by qualitative and quantitative structural analysis based on the x-ray diffraction, transmission electron microscopy, and {sup 57}Fe Moessbauer spectrometry on one hand and the superconducting quantum interference device magnetometry on the other hand. The microstructure consists of L1{sub 0}-FePt hard-magnetic grains (15-45 nm in diameter) dispersed in a soft magnetic medium composed by A1 FePt, Fe{sub 2}B, and boron-rich (FeB)PtNb remainder phase. The ribbons annealed at 700 deg. C for 1 h exhibit promising hard-magnetic properties at room temperature: M{sub r}/M{sub s}=0.69; H{sub c}=820 kA/m and (BH){sub max}=70 kJ/m{sup 3}. Strong exchange coupling between hard and soft magnetic phases was demonstrated by a smooth demagnetizing curve and positive {delta}M-peak in the Henkel plot. The magnetic properties measured from 5 to 750 K reveals that the hard characteristics remains rather stable up to 550 K, indicating a good prospect for the use of these permanent magnets in a wide temperature range.

Randrianantoandro, N.; Greneche, J. M. [Laboratoire de Physique de l'Etat Condense, UMR CNRS 6087, Universite du Maine, 72085 Le Mans cedex 9 (France); Crisan, A. D. [Laboratoire de Physique de l'Etat Condense, UMR CNRS 6087, Universite du Maine, 72085 Le Mans cedex 9 (France); National Institute for Materials Physics, P.O. Box MG-7, 76900 Bucharest (Romania); Crisan, O. [National Institute for Materials Physics, P.O. Box MG-7, 76900 Bucharest (Romania); Marcin, J.; Kovac, J.; Hanko, J.; Skorvanek, I. [Institute of Experimental Physics, Slovak Academy of Sciences, 043 53 Kosice (Slovakia); Svec, P. [Institute of Physics, SAS, Dubravska cesta 9, 84228 Bratislava (Slovakia); Chrobak, A. [August Chelkowski Institute of Physics, University of Silesia, 40-007 Katowice (Poland)

2010-11-15T23:59:59.000Z

93

Control of silicidation in HfO2/Si,,100... interfaces Deok-Yong Cho, Kee-Shik Park, B.-H. Choi,a  

E-Print Network [OSTI]

like nitrogen.6,7 Among these, Hf-silicide is probably most detrimental since it is metallic and degrades the capacitor performance. Metal- lic Hf-silicide formation has been reported in the interfaceControl of silicidation in HfO2/Si,,100... interfaces Deok-Yong Cho, Kee-Shik Park, B.-H. Choi

Oh, Se-Jung

94

Exploring the structure and chemical activity of 2-D gold islands on graphene moire/Ru(0001)  

E-Print Network [OSTI]

Exploring the structure and chemical activity of 2-D gold islands on graphene moire/Ru(0001) Ye Xu May 2011 DOI: 10.1039/c1fd00030f Au deposited on Ru(0001)-supported extended, continuous graphene. These Au islands conform to the corrugation of the underlying graphene and display commensurate moire

Goodman, Wayne

95

Electronic and optical response of functionalized Ru(II) complexes: joint theoretical and experimental study  

SciTech Connect (OSTI)

New photovoltaic and photocatalysis applications have been recently proposed based on the hybrid Ru(II)-bipyridine-complex/semiconductor quantum dot systems. In order to attach the Ru(II) complex to the surface of a semiconductor, a linking bridge -- a carboxyl group -- needs to be added to one or two of the 2,2'-bipyridine (bpy) ligands. Such changes in the ligand structure affect electronic and optical properties and, consequently, the charge transfer reactivity of Ru(II)-systems. In this study, we analyze the effects brought by functionalization of bipyridine ligands with the methyl, carboxyl, and carboxilate groups on the electronic structure and optical response of the [Ru(bpy){sub 3}]{sup 2+} complex. First principle calculations based on density functional theory (DFT) and time dependent DFT (TDDFT) are used to simulate the ground and excited-state properties, respectively, of functionalized Ru-complexes in the gas phase and acetonitrile solution. In addition, an effective Frenkel exciton model is used to explain the optical activity and splitting patterns of the low-energy excited states in all molecules. All theoretical results nicely complement and allow for detailed interpretation of experimental absorption spectra of Ru-complexes that have been done in parallel with our theoretical investigations. We found that the carboxyl group breaks the degeneracy of two low-energy optically bright excited states and red-shifts the absorption spectrum, while leaves ionization and affinity energies of complexes almost unchanged. Experimental studies show that deprotonation of the carboxyl group in the Ru-complexes results in a slight blue shift and decrease of oscillator strengths of the low energy absorption peaks. Comparison of experimental and theoretical linear response spectra of deprotonated complexes demonstrate strong agreement if the theoretical calculations are performed with the addition of a dielectric continuum model. A polar solvent is found to play an important role in calculations of optical spectra: it stabilizes the energy of states localized on the carboxyl or carboxylate groups. Thus, the excited-state structure of the functionalized Ru-complexes, specifically in the case of the deprotonated functions, can be accurately modeled by TDDFT with the addition of a dielectric continuum in simulations.

Kilina, Svetlana [Los Alamos National Laboratory; Tretiak, Sergei [Los Alamos National Laboratory; Sykora, Milan [Los Alamos National Laboratory; Albert, Victor [UNIV OF FLORIDA; Badaeva, Ekaterina [UNIV OF WASHINGTON; Koposov, Alexey [UNIV OF WASHINGTON

2008-01-01T23:59:59.000Z

96

Nitroxide-Labeled Ru(II) Polypyridyl Complexes as EPR Probes of Organized Systems. 3. Characterization of Starburst Dendrimers and Comparison to Photophysical Measurements  

E-Print Network [OSTI]

Nitroxide-Labeled Ru(II) Polypyridyl Complexes as EPR Probes of Organized Systems. 3- links, RuPT and RuPC8T, respectively, have been utilized as EPR probes to monitor the binding). Analysis of the EPR signals by spectral computation provided structural and dynamic parameters

Turro, Claudia

97

BWR - Spent Fuel Transport and Storage with the TN{sup TM}9/4 and TN{sup TM}24BH Casks  

SciTech Connect (OSTI)

The Swiss Nuclear Utilities have started in 2001 to store spent fuel in dry metallic dual-purpose casks at ZWILAG, the Swiss interim storage facility. BKW FMB Energy Ltd., the Muehleberg Nuclear Power Plant owner, is involved in this process and has elected to store its BWR spent fuel in a new high capacity dual-purpose cask, the TNeTeM24BH from the COGEMA Logistics/TRANSNUCLEAR TN{sup TM}24 family. The Muehleberg BWR spent fuels are transported by road in a medium size shuttle transport cask and then transferred to a heavy transport/storage cask (dry transfer) in the hot cell of ZWILAG site. For that purpose, COGEMA Logistics designed and supplied: - Two shuttle casks, TN{sup TM}9/4, mainly devoted to transport of spent fuel from Muehleberg NPP to ZWILAG. Licensed according to IAEA 1996, the TN{sup TM}9/4 is a 40 ton transport cask, for 7 BWR high bum-up spent fuel assemblies. - A series of new high capacity dual-purpose casks, TN{sup TM}24BH, holding 69 BWR spent fuels. Two transport campaigns took place in 2003 and 2004. For each campaign, ten TN{sup TM}9/4 round trips are performed, and one TN{sup TM}24BH is loaded. 5 additional TN{sup TM}24BH are being manufactured for BKW, and the next transport campaigns are scheduled from 2006. The TN{sup TM}24BH high capacity dual purpose cask and the TN{sup TM}9/4 transport cask characteristics and capabilities will then be detailed. (authors)

Wattez, L. [COGEMA LOGISTICS - AREVA Group (France); Marguerat, Y. [BKW FMB Energy Ltd (Switzerland); Hoesli, C. [ZWILAG Zwischenlager Wuerenlingen AG (Switzerland)

2006-07-01T23:59:59.000Z

98

NiW and NiRu Bimetallic Catalysts for Ethylene Steam Reforming: Alternative Mechanisms for Sulfur Resistance  

SciTech Connect (OSTI)

Previous investigations of Ni-based catalysts for the steam reforming of hydrocarbons have indicated that the addition of a second metal can reduce the effects of sulfur poisoning. Two systems that have previously shown promise for such applications, NiW and NiRu, are considered here for the steam reforming of ethylene, a key component of biomass derived tars. Monometallic and bimetallic Al{sub 2}O{sub 3}-supported Ni and W catalysts were employed for ethylene steam reforming in the presence and absence of sulfur. The NiW catalysts were less active than Ni in the absence of sulfur, but were more active in the presence of 50 ppm H{sub 2}S. The mechanism for the W-induced improvements in sulfur resistance appears to be different from that for Ru in NiRu. To probe reasons for the sulfur resistance of NiRu, the adsorption of S and C{sub 2}H{sub 4} on several bimetallic NiRu alloy surfaces ranging from 11 to 33 % Ru was studied using density functional theory (DFT). The DFT studies reveal that sulfur adsorption is generally favored on hollow sites containing Ru. Ethylene preferentially adsorbs atop the Ru atom in all the NiRu (111) alloys investigated. By comparing trends across the various bimetallic models considered, sulfur adsorption was observed to be correlated with the density of occupied states near the Fermi level while C{sub 2}H{sub 4} adsorption was correlated with the number of unoccupied states in the d-band. The diverging mechanisms for S and C{sub 2}H{sub 4} adsorption allow for bimetallic surfaces such as NiRu that enhance ethylene binding without accompanying increases in sulfur binding energy. In contrast, bimetallics such as NiSn and NiW appear to decrease the affinity of the surface for both the reagent and the poison.

Rangan, M.; Yung, M. M.; Medlin, J. W.

2012-06-01T23:59:59.000Z

99

Magnetic properties of RT2Zn20; R = rare earth, T = Fe, Co, Ru, Os and Ir  

SciTech Connect (OSTI)

It is well known that rare earth intermetallic compounds have versatile, magnetic properties associated with the 4f electrons: a local moment associated with the Hund's rule ground state is formed in general, but a strongly correlated, hybridized state may also appear for specific 4f electronic configuration (eg. for rare earth elements such as Ce or Yb). On the other hand, the conduction electrons in rare earth intermetallic compounds, certainly ones associated with non hybridizing rare earths, usually manifest non-magnetic behavior and can be treated as a normal, non-interacted Fermi liquid, except for some 3d-transition metal rich binary or ternary systems which often manifest strong, itinerant, d electron dominant magnetic behavior. Of particular interest are examples in which the band filling of the conduction electrons puts the system in the vicinity of a Stoner transition: such systems, characterized as nearly or weakly ferromagnet, manifest strongly correlated electronic properties [Moriya, 1985]. For rare earth intermetallic compounds, such systems provide an additional versatility and allow for the study of the behaviors of local moments and hybridized moments which are associated with 4f electron in a correlated conduction electron background.

Jia, Shuang

2008-12-15T23:59:59.000Z

100

Missing Data Handling for Meter Data Management System Ru-Sen Jeng1  

E-Print Network [OSTI]

Missing Data Handling for Meter Data Management System Ru-Sen Jeng1 , Chien-Yu Kuo1 , Yao-hua Ho1, Academia Sinica ABSTRACT We study the meter data management systems (MDMS) with a fo- cus on missing data meter data manage- ment systems. Categories and Subject Descriptors H.4.2 [Information Systems

Chen, Ling-Jyh

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101

cis,cis-[(bpy)2RuV Catalyzes Water Oxidation Formally  

E-Print Network [OSTI]

at room temperature (eq 1). In green plants, a tetramanganese cluster found in the Oxygen Evolving Complex at each of the Ru(V)-d3 centers were explored and we found that the high-spin states play an important opportunity for understanding how two transition metal centers work in concert to oxidize water. Such atomic

Baik, Mu-Hyun

102

Core-Shell Assisted Bimetallic Assembly of Pt and Ru Nanoparticles by DNA Hybridization  

E-Print Network [OSTI]

We have discovered that the current protocols to assemble Au nanoparticles based on DNA hybridization do not work well with the small metal nanoparticles (e.g. 5 nm Au, 3.6 nm Pt and 3.2 nm Ru particles). Further investigations ...

Lee, Jim Yang

103

Learning outcomes MSc in Civil Engineering (Concrete Technology) RU-School of Science and Engineering 1  

E-Print Network [OSTI]

including fracture mechanics, high performance concrete including self-compacting concrete and durabilityLearning outcomes MSc in Civil Engineering (Concrete Technology) RU-School of Science and Engineering 1 MSc in Civil Engineering (Cycle 2, level 4) Specialisation: Concrete Technology MSc in Civil

Karlsson, Brynjar

104

Organometallic Complexes that Model the Active Sites of the [FeFe]- and [Fe]-Hydrogenases  

E-Print Network [OSTI]

My research primarily focuses on biomimetics of the active sites of the [FeFe]- and [Fe]-hydrogenases (H2ase) and is classified into three parts. Part A: The one-electron oxidation of asymmetrically disubstituted FeIFeI models of the active site...

Liu, Tianbiao

2011-02-22T23:59:59.000Z

105

Synthesis and Characterization of RuO2/poly (3,4-ethylenedioxythiophene) (PEDOT) Composite Nanotubes for Supercapacitors  

SciTech Connect (OSTI)

We report the synthesis of composite RuO{sub 2}/poly(3,4-ethylenedioxythiophene) (PEDOT) nanotubes with high specific capacitance and fast charging/discharging capability as well as their potential application as electrode materials for a high-energy and high-power supercapacitor. RuO{sub 2}/PEDOT nanotubes were synthesized in a porous alumina membrane by a step-wise electrochemical deposition method, and their structures were characterized using electron microscopy. Cyclic voltammetry was used to qualitatively characterize the capacitive properties of the composite RuO{sub 2}/PEDOT nanotubes. Their specific capacitance, energy density and power density were evaluated by galvanostatic charge/discharge cycles at various current densities. The pseudocapacitance behavior of these composite nanotubes originates from ion diffusion during the simultaneous and parallel redox processes of RuO{sub 2} and PEDOT. We show that the energy density (specific capacitance) of PEDOT nanotubes can be remarkably enhanced by electrodepositing RuO{sub 2} into their porous walls and onto their rough internal surfaces. The flexible PEDOT prevents the RuO{sub 2} from breaking and detaching from the current collector while the rigid RuO{sub 2} keeps the PEDOT nanotubes from collapsing and aggregating. The composite RuO{sub 2}/PEDOT nanotube can reach a high power density of 20 kW kg{sup ?1} while maintaining 80% energy density (28 Wh kg{sup ?1}) of its maximum value. This high power capability is attributed to the fast charge/discharge of nanotubular structures: hollow nanotubes allow counter-ions to readily penetrate into the composite material and access their internal surfaces, while a thin wall provides a short diffusion distance to facilitate ion transport. The high energy density originates from the RuO{sub 2}, which can store high electrical/electrochemical energy intrinsically. The high specific capacitance (1217 F g{sup ?1}) which is contributed by the RuO{sub 2} in the composite RuO{sub 2}/PEDOT nanotube is realized because of the high specific surface area of the nanotubular structures. Such PEDOT/RuO{sub 2} composite nanotube materials are an ideal candidate for the development of high-energy and high-power supercapacitors.

Liu, Ran; Duay, Jonathon; Lane, Timothy; Lee, Sang Bok

2010-01-01T23:59:59.000Z

106

Decay Properties of {sup 266}Bh and {sup 262}Db Produced in the {sup 248}Cm+{sup 23}Na Reaction - Further Confirmation of the {sup 278}113 Decay Chain  

SciTech Connect (OSTI)

Decay properties of an isotope {sup 266}Bh and its daughter nucleus {sup 262}Db produced by the {sup 248}Cm({sup 23}Na,5n) reaction were studied by using a gas-filled recoil separator coupled with a position-sensitive semiconductor detector. {sup 266}Bh was clearly identified from the correlation of the known nuclide, {sup 262}Db. The obtained decay properties of {sup 266}Bh and {sup 262}Db are consistent with those observed in the {sup 278}113 chain by RIKEN collaboration, which provided further confirmation of the discovery of {sup 278}113.

Morita, K.; Morimoto, K.; Kaji, D.; Haba, H.; Ozeki, K.; Kudou, Y.; Yoneda, A.; Ichikawa, T.; Katori, K.; Yoshida, A. [RIKEN Nishina Center, RIKEN, Wako, Saitama 351-0198 (Japan); Sato, N. [RIKEN Nishina Center, RIKEN, Wako, Saitama 351-0198 (Japan); Department of Physics, Tohoku University, Aoba-ku, Sendai 980-8578 (Japan); Sumita, T. [RIKEN Nishina Center, RIKEN, Wako, Saitama 351-0198 (Japan); Faculty of Science and Technology, Tokyo University of Science, Noda, Chiba 278-8510 (Japan); Fujimori, Y.; Tokanai, F. [Department of Physics, Yamagata University, Yamagata 990-8560 (Japan); Goto, S. [Center for Instrumental Analysis, Niigata University, Ikarashi, Nishi-ku, Niigata 950-2181 (Japan); Ideguchi, E. [Center for Nuclear Study, University of Tokyo, Wako, Saitama 351-0198 (Japan); Kasamatsu, Y.; Koura, H.; Tsukada, K. [Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Komori, Y. [Department of Chemistry, Osaka University, Toyonaka, Osaka 560-0043 (Japan)

2010-06-01T23:59:59.000Z

107

Structural and magnetic properties and superconductivity in Ba(Fe{sub 1-x}TM{sub x}){sub 2}As{sub 2}  

SciTech Connect (OSTI)

We studied the effects on structural and magnetic phase transitions and the emergence of superconductivity in transition metal substituted BaFe{sub 2}As{sub 2}. We grew four series of Ba(Fe{sub 1-x}TM{sub x}){sub 2}As{sub 2} (TM=Ru, Mn, Co+Cr and Co+Mn) and characterized them by crystallographic, magnetic and transport measurements. We also subjected Ba(Fe{sub 1-x}Cr{sub x}){sub 2}As{sub 2} and Ba(Fe{sub 1-x}Co{sub x}){sub 2}As{sub 2} to heat treatment to explore what changes might be induced.

Thaler, Alexander

2012-07-23T23:59:59.000Z

108

CALIBRATING STELLAR VELOCITY DISPERSIONS BASED ON SPATIALLY RESOLVED H-BAND SPECTRA FOR IMPROVING THE M{sub BH}-{sigma}{sub *} RELATION  

SciTech Connect (OSTI)

To calibrate stellar velocity dispersion measurements from optical and near-IR stellar lines, and to improve the black hole mass (M{sub BH})-stellar velocity dispersion ({sigma}{sub *}) relation, we measure {sigma}{sub *} based on high-quality H-band spectra for a sample of 31 nearby galaxies, for which dynamical M{sub BH} is available in the literature. By comparing velocity dispersions measured from stellar lines in the H-band with those measured from optical stellar lines, we find no significant difference, suggesting that optical and near-IR stellar lines represent the same kinematics and that dust effect is negligible for early-type galaxies. Based on the spatially resolved rotation and velocity dispersion measurements along the major axis of each galaxy, we find that a rotating stellar disk is present for 80% of galaxies in the sample. For galaxies with a rotation component, {sigma}{sub *} measured from a single aperture spectrum can vary by up to {approx}20%, depending on the size of the adopted extraction aperture. To correct for the rotational broadening, we derive luminosity-weighted {sigma}{sub *} within the effective radius of each galaxy, providing uniformly measured velocity dispersions to improve the M{sub BH}-{sigma}{sub *} relation.

Kang, Wol-Rang; Woo, Jong-Hak; Park, Daeseong [Astronomy Program, Department of Physics and Astronomy, Seoul National University, 1 Gwanak-ro Gwanak-gu, Seoul, 151-742 (Korea, Republic of)] [Astronomy Program, Department of Physics and Astronomy, Seoul National University, 1 Gwanak-ro Gwanak-gu, Seoul, 151-742 (Korea, Republic of); Schulze, Andreas [Kavli Institute for Astronomy and Astrophysics, Peking University, 100871 Beijing (China)] [Kavli Institute for Astronomy and Astrophysics, Peking University, 100871 Beijing (China); Riechers, Dominik A. [Astronomy Department, Cornell University, 220 Space Science Building, Ithaca, NY 14853 (United States)] [Astronomy Department, Cornell University, 220 Space Science Building, Ithaca, NY 14853 (United States); Kim, Sang Chul [Korea Astronomy and Space Science Institute, Daejeon 305-348 (Korea, Republic of)] [Korea Astronomy and Space Science Institute, Daejeon 305-348 (Korea, Republic of); Smolcic, Vernesa, E-mail: woo@astro.snu.ac.kr [Physics Department, University of Zagreb, Bijenicka cesta 32, 10002 Zagreb (Croatia)] [Physics Department, University of Zagreb, Bijenicka cesta 32, 10002 Zagreb (Croatia)

2013-04-10T23:59:59.000Z

109

Photoemission study of energy-band alignment for RuO{sub x}/HfO{sub 2}/Si system  

SciTech Connect (OSTI)

Conductive oxides RuO{sub x} as alternative electrode on high-{kappa} HfO{sub 2} gate dielectric have been fabricated by ultrahigh-vacuum sputtering and subsequently oxidized using oxygen plasma. The energy-band alignment for the RuO{sub x}/HfO{sub 2}/Si system and the oxidation-state dependence of barrier height for RuO{sub x} contacting to HfO{sub 2} dielectrics has been analyzed by x-ray photoemission spectroscopy. The valence- and conduction-band offsets of HfO{sub 2}/Si are determined to be 3.05{+-}0.1 and 1.48{+-}0.1 eV, respectively. The barrier heights for the RuO{sub x} contacting to HfO{sub 2} are oxidation-state dependent, in the range of 1.95-2.73 eV.

Li, Q.; Wang, S.J.; Li, K.B.; Huan, A.C.H.; Chai, J.W.; Pan, J.S.; Ong, C.K. [Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Institute of Materials Research and Engineering, 3 Research Link, Singapore 117602 (Singapore); Data Storage Institute, DSI Building, 5 Engineering Drive 1, Singapore 117608 (Singapore); Institute of Materials Research and Engineering, 3 Research Link, Singapore 117602, Singapore and Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Institute of Materials Research and Engineering, 3 Research Link, Singapore 117602 (Singapore); Department of Physics, National University of Singapore, Singapore 117542 (Singapore)

2004-12-20T23:59:59.000Z

110

The nature and role of bridged carbonyl intermediates in theultrafast photo-induced rearrangement of Ru3(CO)12.  

SciTech Connect (OSTI)

The photochemistry of the trimetal cluster,Ru(3)(CO)12, was investigated on the ultrafast timescale using UV-vis pump, infrared probe spectroscopy in order to study the transient intermediates formed upon photoexcitation.

Glascoe, Elizabeth A.; Kling, Matthias F.; Shanoski, Jennifer E.; Harris, Charles B.

2005-09-18T23:59:59.000Z

111

Further Theoretical Evidence for Hydrogen-Assisted CO Dissociation on Ru(0001)  

SciTech Connect (OSTI)

Extensive calculations based on spin-polarized density functional theory were carried out to examine how CH{sub x} are formed from the dissociation of CO on Ru(0001) in the presence of hydrogen. Common pathways, such as the direct CO dissociation and H-assisted route leading to HCO or COH, including alternative routes that involve the formation of HCOH and CH{sub 2}O, were examined. The reaction energy and barrier for each elementary step were calculated. The calculations show that the carbide mechanism is not the main reaction pathway for the conversion of CO on Ru(0001). Complementary microkinetic simulations utilizing results from first-principles quantum mechanical calculations indicate that a branch starting from the hydrogenation of CO to HCOH (via COH intermediate) and subsequent C–O bond cleavage is more plausible.

Alfonso, Dominic R.

2013-10-10T23:59:59.000Z

112

Enhanced oxygen evolution activity of IrO2 and RuO2 (100) surfaces  

SciTech Connect (OSTI)

The activities of the oxygen evolution reaction (OER) on IrO2 and RuO2 catalysts are among the highest known to date. However, the intrinsic OER activities of surfaces with defined crystallographic orientations are not well established experimentally. Here we report that the (100) surface of IrO2 and RuO2 is more active than the (110) surface that has been traditionally explored by density functional theory studies. The relation between the OER activity and density of coordinatively undersaturated metal sites exposed on each rutile crystallographic facet is discussed. The surface-orientation dependent activities can guide the design of high-surface-area catalysts with increased activity for electrolyzers, metal-air batteries, and photoelectrochemical water splitting applications.

Stoerzinger, Kelsey [Massachusetts Institute of Technology (MIT)] [Massachusetts Institute of Technology (MIT); Qiao, Liang [ORNL] [ORNL; Biegalski, Michael D [ORNL] [ORNL; Christen, Hans M [ORNL] [ORNL; Shao-Horn, Yang [Massachusetts Institute of Technology (MIT)] [Massachusetts Institute of Technology (MIT)

2014-01-01T23:59:59.000Z

113

Water adsorption on O(2x2)/Ru(0001) from STM experiments andfirst-principles calculations  

SciTech Connect (OSTI)

We present a combined theoretical and experimental study of water adsorption on Ru(0001) pre-covered with 0.25 monolayers (ML) of oxygen forming a (2 x 2) structure. Several structures were analyzed by means of Density Functional Theory calculations for which STM simulations were performed and compared with experimental data. Up to 0.25 monolayers the molecules bind to the exposed Ru atoms of the 2 x 2 unit cell via the lone pair orbitals. The molecular plane is almost parallel to the surface with its H atoms pointing towards the chemisorbed O atoms of the 2 x 2 unit cell forming hydrogen bonds. The existence of these additional hydrogen bonds increases the adsorption energy of the water molecule to approximately 616 meV, which is {approx}220 meV more stable than on the clean Ru(0001) surface with a similar configuration. The binding energy shows only a weak dependence on water coverage, with a shallow minimum for a row structure at 0.125 ML. This is consistent with the STM experiments that show a tendency of the molecules to form linear rows at intermediate coverage. Our calculations also suggest the possible formation of water dimers near 0.25 ML.

Cabrera-Sanfelix, P.; Sanchez-Portal, D.; Mugarza, A.; Shimizu,T.K.; Salmeron, M.; Arnau, A.

2007-10-15T23:59:59.000Z

114

Water Induced Surface Reconstruction of the Oxygen (2x1) covered Ru(0001)  

SciTech Connect (OSTI)

Low temperature scanning tunneling microscopy (STM) and density functional theory (DFT) were used to study the adsorption of water on a Ru(0001) surface covered with half monolayer of oxygen. The oxygen atoms occupy hcp sites in an ordered structure with (2x1) periodicity. DFT predicts that water is weakly bound to the unmodified surface, 86 meV compared to the ~;;200 meV water-water H-bond. Instead, we found that water adsorption causes a shift of half of the oxygen atoms from hcp sites to fcc sites, creating a honeycomb structure where water molecules bind strongly to the exposed Ru atoms. The energy cost of reconstructing the oxygen overlayer, around 230 meV per displaced oxygen atom, is more than compensated by the larger adsorption energy of water on the newly exposed Ru atoms. Water forms hydrogen bonds with the fcc O atoms in a (4x2) superstructure due to alternating orientations of the molecules. Heating to 185 K results in the complete desorption of the water layer, leaving behind the oxygen honeycomb structure, which is metastable relative to the original (2x1). This stable structure is not recovered until after heating to temperatures close to 260K.

Maier, Sabine; Cabrera-Sanfelix, Pepa; Stass, Ingeborg; Sanchez-Portal, Daniel; Arnau, Andres; Salmeron, Miquel

2010-08-06T23:59:59.000Z

115

High-spin structure and multiphonon {gamma} vibrations in very neutron-rich {sup 114}Ru  

SciTech Connect (OSTI)

High-spin levels of the neutron-rich {sup 114}Ru have been investigated by measuring the prompt {gamma} rays in the spontaneous fission of {sup 252}Cf. The ground-state band and one-phonon {gamma}-vibrational band have been extended up to 14{sup +} and 9{sup +}, respectively. Two levels are proposed as the members of a two-phonon {gamma}-vibrational band. A back bending (band crossing) has been observed in the ground-state band at ({h_bar}/2{pi}){omega}{approx_equal} 0.40 MeV. Using the triaxial deformation parameters, the cranked shell model calculations indicate that this back bending in {sup 114}Ru should originate from the alignment of a pair of h{sub 11/2} neutrons. Triaxial projected shell model calculations for the {gamma}-vibrational band structures of {sup 114}Ru are in good agreement with the experimental data. However, when using the oblate deformation parameters, both of the above-calculated results are not in agreement with the experimental data.

Yeoh, E. Y.; Wang, J. G.; Ding, H. B.; Gu, L.; Xu, Q.; Xiao, Z. G. [Department of Physics, Tsinghua University, Beijing 100084 (China); Zhu, S. J. [Department of Physics, Tsinghua University, Beijing 100084 (China); Department of Physics, Vanderbilt University, Nashville, Tennessee 37235 (United States); Hamilton, J. H.; Li, K.; Ramayya, A. V.; Hwang, J. K. [Department of Physics, Vanderbilt University, Nashville, Tennessee 37235 (United States); Liu, Y. X. [School of Science, Huzhou Teachers College, Huzhou 313000 (China); Liu, S. H. [Department of Physics, Vanderbilt University, Nashville, Tennessee 37235 (United States); UNIRIB/Oak Ridge Associated Universities, Oak Ridge, Tennessee 37831 (United States); Sun, Y. [Department of Physics, Shanghai Jiao Tong University, Shanghai 200240 (China); Sheikh, J. A.; Bhat, G. H. [Department of Physics, University of Kashmir, Srinagar 190 006 (India); Luo, Y. X. [Department of Physics, Vanderbilt University, Nashville, Tennessee 37235 (United States); Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Rasmussen, J. O.; Lee, I. Y. [Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Ma, W. C. [Department of Physics, Mississippi State University, Mississippi State, Mississippi 39762 (United States)

2011-05-15T23:59:59.000Z

116

Manipulating Magnetism: Ru-2(5+) Paddlewheels Devoid of Axial Interactions  

SciTech Connect (OSTI)

Variable-temperature magnetic and structural data of two pairs of diruthenium isomers, one pair having an axial ligand and the formula Ru-2(DArF)(4)Cl (where DArF is the anion of a diarylformamidine isomer and Ar = p-anisyl or m-anisyl) and the other one being essentially identical but devoid of axial ligands and having the formula [Ru-2(DArF)(4)]BF4, show that the axial ligand has a significant effect on the electronic structure of the diruthenium unit. Variable temperature crystallographic and magnetic data as well as density functional theory calculations unequivocally demonstrate the occurrence of pi interactions between the p orbitals of the chlorine ligand and the pi* orbitals in the Ru-2(5+) units. The magnetic and structural data are consistent with the existence of combined ligand sigma/metal sigma and ligand p pi/metal-d pi interactions. Electron paramagnetic resonance data show unambiguously that the unpaired electrons are in metal-based molecular orbitals.

Chiarella, Gina M [Texas A& M University; Cotton, F. A. [Texas A& M University; Murillo, Carlos A [Texas A& M University; Ventura, Karen [University of Texas at El Paso; Vilagran, Dino [University of Texas at El Paso; Wang, Xiaoping [ORNL

2014-01-01T23:59:59.000Z

117

Microsoft Word - Sarangi bh  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reactivity of oxygen-containing metal complexes and metalloenzymes such as the oxygen-evolving complex (OEC) in photosystem II (PSII) and its small-molecule mimics. In PSII, a Ca...

118

Microsoft Word - Chacon bh  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science Highlight - October 2014 Figure 1. Cartoon overview of the CusCBFA efflux pump in the periplasm. New Method Tracks Metal-ion Movement in Periplasmic Proteins Copper is an...

119

Microsoft Word - Squid bh  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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120

Theoretical study of the interaction of Fe, Fe/sup +/, and FeCO with Ar  

SciTech Connect (OSTI)

Ab initio Hartree--Fock calculations were performed on FeAr and FeAr/sup +/ in order to determine the interaction of both neutral and singly-ionized Fe atoms trapped in Ar, and on ArFeCO and FeCOAr in order to ascertain the effect of an Ar matrix on the FeCO molecule. Quadrupole splittings and isomer shifts are computed using ab initio orbital populations and charge densities scaled by a relativistic factor. Good agreement between calculated and experimental hyperfine parameters is found in each case. The interaction energy for Fe/sup +/--Ar has been computed by ab initio Hartree--Fock and effective-core potential (ECP) methods. Both approaches yield a minimum between Fe/sup +/ and Ar at approximately 7.6 bohr.

Braga, M.; Almeida, A.L.; Taft, C.A.; Hammond, B.L.; Lester W.A. Jr.

1988-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
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121

Thermal response of Ru electrodes in contact with SiO{sub 2} and Hf-based high-k gate dielectrics  

SciTech Connect (OSTI)

A systematic experimental evaluation of the thermal stability of Ru metal gate electrodes in direct contact with SiO{sub 2} and Hf-based dielectric layers was performed and correlated with electrical device measurements. The distinctly different interfacial reactions in the Ru/SiO{sub 2}, Ru/HfO{sub 2}, and Ru/HfSiO{sub x} film systems were observed through cross-sectional high-resolution transmission electron microscopy, high angle annular dark field scanning transmission electron microscopy with electron-energy-loss spectra, and energy dispersive x-ray spectra analysis. Ru interacted with SiO{sub 2}, but remained stable on HfO{sub 2} at 1000 deg. C. The onset of Ru/SiO{sub 2} interfacial interactions is identified via silicon substrate pitting possibly from Ru diffusion into the dielectric in samples exposed to a 900 deg. C/10-s anneal. The dependence of capacitor device degradation with decreasing SiO{sub 2} thickness suggests Ru diffuses through SiO{sub 2}, followed by an abrupt, rapid, nonuniform interaction of ruthenium silicide as Ru contacts the Si substrate. Local interdiffusion detected on Ru/HfSiO{sub x} samples may be due to phase separation of HfSiO{sub x} into HfO{sub 2} grains within a SiO{sub 2} matrix, suggesting that SiO{sub 2} provides a diffusion pathway for Ru. Detailed evidence consistent with a dual reaction mechanism for the Ru/SiO{sub 2} system at 1000 deg. C is presented.

Wen, H.-C.; Lysaght, P.; Alshareef, H.N.; Huffman, C.; Harris, H.R.; Choi, K.; Senzaki, Y.; Luan, H.; Majhi, P.; Lee, B.H.; Campin, M. J.; Foran, B.; Lian, G.D.; Kwong, D.-L. [SEMATECH, 2706 Montopolis Drive, Austin, Texas 78741(United States); University of Texas at Austin, Pickle Research Campus-Microelectronics and Engineering Research (PRC-MER) Building 2.606A/R9950, Austin, Texas 78712 (United States); SEMATECH, 2706 Montopolis Drive, Austin, Texas 78741 (United States); Advanced Technology Development Facility (ATDF) Inc., 2706 Montopolis Drive, Austin, Texas 78741 (United States); University of Texas at Austin, Pickle Research Campus-Microelectronics and Engineering Research (PRC-MER) Building 2.606A/R9950, Austin, Texas 78712 (United States)

2005-08-15T23:59:59.000Z

122

Measurements and calculations of metastable level lifetimes in Fe X, Fe XI, Fe XII, Fe XIII, and Fe XIV  

E-Print Network [OSTI]

Lifetimes of metastable levels in the ground term of Fe ions within the 3s(2)3p(k), k=1-5, isoelectronic sequences have been measured. These measurements were performed utilizing ions that were selected by mass to charge ratio while transported from...

Moehs, D. P.; Bhatti, M. I.; Church, David A.

2001-01-01T23:59:59.000Z

123

Relative g-factor measurements in {sup 54}Fe, {sup 56}Fe, and {sup 58}Fe  

SciTech Connect (OSTI)

The g factors of the 2{sub 1}{sup +} states in {sup 54}Fe and {sup 58}Fe have been measured relative to the 2{sub 1}{sup +} state g factor of {sup 56}Fe using the transient-field technique in inverse kinematics. The results are in satisfactory agreement with recent shell model calculations in the fp model space. For {sup 56}Fe and {sup 58}Fe the g factors approach Z/A and are therefore also consistent with collective interpretations of these 2{sup +} states.

East, M. C.; Stuchbery, A. E.; Chamoli, S. K.; Kibedi, T. [Department of Nuclear Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Pinter, J. S.; Crawford, H. L.; Mantica, P. F. [NSCL and Department of Chemistry, Michigan State University, Michigan 48824 (United States); Wilson, A. N. [Department of Nuclear Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Department of Physics, Australian National University, Canberra, ACT 0200 (Australia)

2009-02-15T23:59:59.000Z

124

Time-Resolved XAFS Spectroscopic Studies of B-H and N-H Oxidative Addition to Transition Metal Catalysts Relevant to Hydrogen Storage  

SciTech Connect (OSTI)

Successful catalytic dehydrogenation of aminoborane, H3NBH3, prompted questions as to the potential role of N-H oxidative addition in the mechanisms of these processes. N-H oxidative addition reactions are rare, and in all cases appear to involve initial dative bonding to the metal by the amine lone pairs followed by transfer of a proton to the basic metal. Aminoborane and its trimethylborane derivative block this mechanism and, in principle, should permit authentic N-H oxidative attrition to occur. Extensive experimental work failed to confirm this hypothesis. In all cases either B-H complexation or oxidative addition of solvent C-H bonds dominate the chemistry.

Bitterwolf, Thomas E. [University of Idaho

2014-12-09T23:59:59.000Z

125

Features of the band structure and conduction mechanisms in the n-HfNiSn semiconductor heavily doped with Ru  

SciTech Connect (OSTI)

The crystal and electronic structure and energy and kinetic properties of the n-HfNiSn semiconductor heavily doped with a Ru acceptor impurity are investigated in the temperature and Ru concentration ranges T = 80–400 K and N{sub A}{sup Ru} ? 9.5 × 10{sup 19}?5.7 × 10{sup 20} cm{sup ?3} (x = 0–0.03), respectively. The mechanism of structural-defect generation is established, which changes the band gap and degree of compensation of the semiconductor and consists in the simultaneous concentration reduction and elimination of donor structural defects by means of the displacement of ?1% of Ni atoms from the Hf (4a) positions, the generation of acceptor structural defects upon the substitution of Ru atoms for Ni atoms in the 4c positions, and the generation of donor defects in the form of vacancies in the Sn (4b) positions. The calculated electronic structure of HfNi{sub 1?x}Ru{sub x}Sn is consistent with the experiment. The results obtained are discussed within the Shklovsky-Efros model for a heavily doped and compensated semiconductor.

Romaka, V. A., E-mail: vromaka@polynet.lviv.ua [National Academy of Sciences of Ukraine, Pidstrygach Institute for Applied Problems in Mechanics and Mathematics (Ukraine); Rogl, P. [Universität Wien, Institut für Physikalische Chemie (Austria); Romaka, V. V. [National University Lvivska Politekhnika (Ukraine); Stadnyk, Yu. V. [Ivan Franko National University of Lviv (Ukraine); Korzh, R. O.; Krayovskyy, V. Ya. [National University Lvivska Politekhnika (Ukraine); Horyn, A. M. [Ivan Franko National University of Lviv (Ukraine)

2014-12-15T23:59:59.000Z

126

Ultrafast Magnetization Dynamics of SrRuO3 Thin Films  

SciTech Connect (OSTI)

Itinerant ferromagnet SrRuO3 has drawn interest from physicists due to its unusual transport and magnetic properties as well as from engineers due to its low resistivity and good lattice-matching to other oxide materials. The exact electronic structure remains a mystery, as well as details of the interactions between magnetic and electron transport properties. This thesis describes the use of time-resolved magneto-optical Kerr spectroscopy to study the ferromagnetic resonance of SrRuO3 thin films, where the ferromagnetic resonance is initiated by a sudden change in the easy axis direction in response to a pump pulse. The rotation of the easy axis is induced by laser heating, taking advantage of a temperature-dependent easy axis direction in SrRuO3 thin films. By measuring the change in temperature of the magnetic system in response to the laser pulse, we find that the specific heat is dominated by magnons up to unusually high temperature, ~;;100 K, and thermal diffusion is limited by a boundary resistance between the film and the substrate that is not consistent with standard phonon reflection and scattering models. We observe a high FMR frequency, 250 GHz, and large Gilbert damping parameter, alpha ~;; 1, consistent with strong spin-orbit coupling. We observe a time-dependent change in the easy axis direction on a ps time-scale, and we find that parameters associated with the change in easy axis, as well as the damping parameter, have a non-monotonic temperature dependence similar to that observed in anomalous Hall measurements.

Langner, Matthew C

2009-05-19T23:59:59.000Z

127

Metastable phase boundaries of quasicrystalline phases. [Al-Mn; Al-Ru  

SciTech Connect (OSTI)

The melting curve (T/sub 0/) of the metastable icosahedral phase and the liquidus of the decagonal phase of Al-Mn have been obtained for 14 to 22 at. % Mn. Icosahedral Al-Mn has a congruent melting point of 910 +- 20/sup 0/C at 20 at. % Mn, and melts approx.30/sup 0/C lower than crystalline compounds with the same composition. Icosahedral Al/sub 82/Ru/sub 18/ was determined to melt at 1260 +- 30/sup 0/C. These results were obtained by forming single-phase icosahedral alloys with ion beam mixing, and by rapid heating to accurately known temperatures with electron beams.

Follstaedt, D.M.; Knapp, J.A.

1987-01-01T23:59:59.000Z

128

BIG RU N INDIANA LAKESHORE RUN E LUMBER CIT Y WARSAW JOHNST  

Gasoline and Diesel Fuel Update (EIA)

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129

FE Transition Deliverables  

Broader source: Energy.gov (indexed) [DOE]

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130

miniFE Benchmark  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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131

Fe(A)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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132

DE-FE0005958  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases onOrganization FY 2012JDA 1/31/136P2DOE/NETL MethaneFE0005958

133

Studies on catalytic and structural properties of BaRuO3 type perovskite1 material for diesel soot oxidation2  

E-Print Network [OSTI]

1 Studies on catalytic and structural properties of BaRuO3 type perovskite1 material for diesel by co-precipitation24 method and its catalytic activity has been tested for diesel soot oxidation processes and vehicle exhaust.33 Key words: BaRuO3, perovskite, diesel soot oxidation, vehicular exhaust

Paris-Sud XI, Université de

134

Ion irradiation of Fe-Fe oxide core-shell nanocluster films:...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

irradiation of Fe-Fe oxide core-shell nanocluster films: Effect of interface on stability of magnetic properties. Ion irradiation of Fe-Fe oxide core-shell nanocluster films:...

135

Strain relaxation in epitaxial SrRuO{sub 3} thin films on LaAlO{sub 3} substrates  

SciTech Connect (OSTI)

Strain relaxation behavior of epitaxial SrRuO{sub 3} thin films on (001) LaAlO{sub 3} substrates was investigated using high resolution X-ray diffraction. Lattice distortion and dislocation densities were systematically studied with samples under different growth conditions. Reciprocal space maps reveal different strain relaxation behavior in SrRuO{sub 3} thin films grown at different temperatures. Two kinds of strain relaxation mechanisms were proposed to understand the growth dynamics, including the evolution of threading dislocations and the tilt of crystalline planes.

Gao, M.; Du, H.; Dai, C.; Lin, Y. [State Key Laboratory of Electronic Thin films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, Sichuan 610054 (China)] [State Key Laboratory of Electronic Thin films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, Sichuan 610054 (China); Ma, C. R.; Liu, M.; Collins, G.; Zhang, Y. M.; Chen, C. L. [Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, Texas 78249, USA and Department of Physics and The Texas Center for Superconductivity, University of Houston, Houston, Texas 77204 (United States)] [Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, Texas 78249, USA and Department of Physics and The Texas Center for Superconductivity, University of Houston, Houston, Texas 77204 (United States)

2013-09-30T23:59:59.000Z

136

Coadsorption of hydrogen and ethylene, and carbon monoxide and ethylene on the Ru(001) surface  

SciTech Connect (OSTI)

A detailed investigation of the coadsorption of ethylene with both preadsorbed hydrogen and preadsorbed carbon monoxide on the Ru(001) surface is reported here. Both preadsorbed hydrogen and carbon monoxide reduce the saturation coverage of subsequently chemisorbed ethylene. The coadsorption of hydrogen with ethylene results in detectable hydrogenation of ethylene to ethane below 250 K, whereas no self-hydrogenation of ethylene to ethane is observed. High-resolution electron energy loss spectra show that ethylene coadsorbed with either hydrogen or carbon monoxide decomposes to ethylidyne (CCH/sub 3/) and acetylide (CCH), as it does on the clean surface. Carbon monoxide preadsorption enhances the stability of the ethylidyne such that it decomposes at approximately 420 K, rather than 355 K as on the initially clean Ru(001) surface. Preadsorbed carbon monoxide also reduces the ratio of ethylidyne to acetylide that is formed from ethylene, compared to the ratio observed from an equivalent coverage of ethylene on the clean surface; hydrogen preadsorption, on the other hand, increases this ratio.

Hills, M.M.; Parmeter, J.E.; Weinberg, W.H.

1986-11-12T23:59:59.000Z

137

Spin-lozenge thermodynamics and magnetic excitations in Na3RuO4  

SciTech Connect (OSTI)

We report inelastic and elastic neutron scattering, magnetic susceptibility, and heat capacity measurements of polycrystalline sodium ruthenate (Na3RuO4). Previous work suggests this material consists of isolated tetramers of S = 3/2 Ru5+ ions in a so-called lozenge configuration. Using a Heisenberg antiferromagnet Hamiltonian, we analytically determine the energy eigenstates for general spin S. From this model, the neutron scattering cross-sections for excitations associated with spin-3/2 tetramer configurations is determined. Comparison of magnetic susceptibility and inelastic neutron scattering results shows that the proposed lozenge model is not distinctly supported, but provides evidence that the system may be better described as a pair of non-interacting inequivalent dimers, i.e double dimers. However, the existence of long-range magnetic order below Tc ? 28 K immediately questions such a description. Although no evidence of the lozenge model is observed, future studies on single crystals may further clarify the appropriate magnetic Hamiltonian.

Haraldsen, Jason T [ORNL; Stone, Matthew B [ORNL; Lumsden, Mark D [ORNL; Barnes, Ted {F E } [ORNL; Jin, Rongying [ORNL; Taylor, J. W. [ISIS Facility, Rutherford Appleton Laboratory; Fernandez-Alonso, F [ISIS Facility, Rutherford Appleton Laboratory

2009-01-01T23:59:59.000Z

138

The pure rotational spectrum of ruthenium monocarbide, RuC, and relativistic ab initio predictions  

SciTech Connect (OSTI)

The J = 1 ? J = 0 and J = 2 ? J = 1 rotational transitions of ruthenium monocarbide, RuC, have been recorded using the separated field pump/probe microwave optical double resonance technique and analyzed to determine the fine and hyperfine parameters for the X{sup 1}?{sup +} state. The {sup 101}Ru(I = 5/2) electric quadrupole parameter, eq{sub 0}Q, and nuclear spin-rotation interaction parameter, C{sub I}{sup eff}, were determined to be 433.19(8) MHz and ?0.049(6) MHz, respectively. The equilibrium bond distance, r{sub e}, was determined to be 1.605485(2) Å. Hartree-Fock and coupled-cluster calculations were carried out for the properties of the X{sup 1}?{sup +} state. Electron-correlation effects are pronounced for all properties studied. It is shown that (a) the moderate scalar-relativistic contribution to eq{sub 0}Q is entirely due to the coupling between scalar-relativistic and electron-correlation effects, (b) the spin-free exact two-component theory in its one-electron variant offers a reliable and efficient treatment of scalar-relativistic effects, and (c) non-relativistic theory performs quite well for the prediction of C{sub I}{sup elec}, provided that electron correlation is treated accurately.

Wang, Fang; Steimle, Timothy C.; Adam, Allan G. [Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287-1604 (United States)] [Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona 85287-1604 (United States); Cheng, Lan; Stanton, John F. [Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas 78712 (United States)] [Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas 78712 (United States)

2013-11-07T23:59:59.000Z

139

Investigation of Double Beta Decay of 100Mo to Excited States of 100Ru  

SciTech Connect (OSTI)

Double beta decay of 100Mo to the excited states of daughter nuclei has been studied using a 600 cm3 low-background HPGe detector and an external source consisting of 2588 g of 97.5% enriched metallic 100Mo, which was formerly inside the NEMO-3 detector and used for the NEMO-3 measurements of 100Mo. The half-life for the two-neutrino double beta decay of 100Mo to the excited View the MathML source state in 100Ru is measured to be T1/2=[7.5±0.6(stat)±0.6(syst)]·1020 yr. For other (0?+2?) transitions to the View the MathML source, View the MathML source, View the MathML source, View the MathML source and View the MathML source levels in 100Ru, limits are obtained at the level of ~(0.25–1.1)·1022 yr.

A. J. Caffrey; The NEMO-3 Collaboration

2014-05-01T23:59:59.000Z

140

SCHOOL INFORMATION Santa Fe Indian School  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SCHOOL INFORMATION Santa Fe Indian School 1501 Cerrillos Road Santa Fe, NM 87505 P.O. Box 5340 Santa Fe, NM 87502 Main: (505) 989-6300 www.sfindianschool.org Main and only Entrance...

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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141

Electronic structure of the Nowotny chimney-ladder silicide Ru{sub 2}Si{sub 3}  

SciTech Connect (OSTI)

We report {ital ab initio} calculations for the electronic structure of the Nowotny chimney-ladder silicide Ru{sub 2}Si{sub 3} in the orthorhombic low-temperature phase. We find Ru{sub 2}Si{sub 3} to be a semiconductor with a direct band gap of about 0.45 eV. Since this gap is a p-d gap, the oscillator strength for a direct transition is expected to be of sizable magnitude. Also, the calculated effective masses of hole and electron states suggest that Ru{sub 2}Si{sub 3} is a very promising material for various applications in semiconductor technology. The electronic structure is controlled by the hybridization of Si p states with Ru d states and shows similarities to the group-IV transition-metal disilicides (CrSi{sub 2}, MoSi{sub 2}, WSi{sub 2}) and to transition-metal-rich silicides. The calculations are based on the density-functional theory in local-density approximation and are performed by means of the full-potential linearized-augmented-plane-wave method. {copyright} {ital 1997} {ital The American Physical Society}

Wolf, W. [Institut fuer Physikalische Chemie der Universitaet Wien, Liechtensteinstrae 22a, A-1090 Wien (Austria)] [Institut fuer Physikalische Chemie der Universitaet Wien, Liechtensteinstrae 22a, A-1090 Wien (Austria); Bihlmayer, G.; Bluegel, S. [Institut fuer Festkoerperforschung, Forschungszentrum Juelich, D-52425 Juelich (Germany)] [Institut fuer Festkoerperforschung, Forschungszentrum Juelich, D-52425 Juelich (Germany)

1997-03-01T23:59:59.000Z

142

Chemical Effect of Dry and Wet Cleaning of the Ru Protective Layer of the Extreme ultraviolet (EUV) Lithography Reflector  

SciTech Connect (OSTI)

The authors report the chemical influence of cleaning of the Ru capping layer on the extreme ultraviolet (EUV) reflector surface. The cleaning of EUV reflector to remove the contamination particles has two requirements: to prevent corrosion and etching of the reflector surface and to maintain the reflectivity functionality of the reflector after the corrosive cleaning processes. Two main approaches for EUV reflector cleaning, wet chemical treatments [sulfuric acid and hydrogen peroxide mixture (SPM), ozonated water, and ozonated hydrogen peroxide] and dry cleaning (oxygen plasma and UV/ozone treatment), were tested. The changes in surface morphology and roughness were characterized using scanning electron microscopy and atomic force microscopy, while the surface etching and change of oxidation states were probed with x-ray photoelectron spectroscopy. Significant surface oxidation of the Ru capping layer was observed after oxygen plasma and UV/ozone treatment, while the oxidation is unnoticeable after SPM treatment. Based on these surface studies, the authors found that SPM treatment exhibits the minimal corrosive interactions with Ru capping layer. They address the molecular mechanism of corrosive gas and liquid-phase chemical interaction with the surface of Ru capping layer on the EUV reflector.

Belau, Leonid; Park, Jeong Y.; Liang, Ted; Seo, Hyungtak; Somorjai, Gabor A.

2009-04-10T23:59:59.000Z

143

WORLDVIEW THEORY AND THE CONCEPTUALISATION OF SPACE Marc Schfer, Rhodes University, Grahamstown, South Africa, M.Schafer@ru.ac.za  

E-Print Network [OSTI]

, Grahamstown, South Africa, M.Schafer@ru.ac.za Introduction The aim of this paper and presentation is to shareMathematicsin South Africa for example, sees space and shape within a context of social experiences. One and representexperienceswithshape,space,timeand motion, using all available senses" (Republic of South Africa, 1997). This apparent

Spagnolo, Filippo

144

Density functional theory study of the mechanism of Li diffusion in rutile RuO{sub 2}  

SciTech Connect (OSTI)

First-principle calculations are carried out to study the diffusion of Li ions in rutile structure RuO{sub 2}, a material for positive electrodes in rechargeable Li ion batteries. The calculations focus on migration pathways and energy barriers for diffusion in Li-poor and Li-rich phases using the Nudged Elastic Band Method. Diffusion coefficients estimated based on calculated energy barriers are in good agreement with experimental values reported in the literature. The results confirm the anisotropic nature of diffusion of Li ions in one-dimensional c channels along the [001] crystalline direction of rutile RuO{sub 2} and show that Li diffusion in the Li-poor phase is faster than in the Li-rich phase. The findings of fast Li diffusion and feasible Li insertion at low temperatures in the host rutile RuO{sub 2} suggest this material is a good ionic conductor for Li transport. The finding also suggests possible means for enhancing the performance of RuO{sub 2}-based electrode materials.

Jung, Jongboo; Cho, Maenghyo [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of)] [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of); Zhou, Min, E-mail: min.zhou@gatech.edu [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of) [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of); George W. Woodruff School of Mechanical Engineering, School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0405 (United States)

2014-01-15T23:59:59.000Z

145

Half-life of the electron-capture decay of (97)Ru: Precision measurement shows no temperature dependence  

E-Print Network [OSTI]

.8382(14) d at 19K, are consistent with, but much more precise than, previous room-temperature measurements. In addition, we have also measured the half-lives of the beta(-)-emitters (103)Ru and (105)Rh at both temperatures, and found them also to be unchanged....

Goodwin, J. R.; Golovko, V. V.; Iacob, V. E.; Hardy, John C.

2009-01-01T23:59:59.000Z

146

Dependence of Electronic Structure of SrRuO3 and the Degree of Correlation on Cation Off-Stoichiometry  

SciTech Connect (OSTI)

We have grown and studied high quality SrRuO{sub 3} films grown by MBE as well as PLD. By changing the oxygen activity during deposition we were able to make SrRuO{sub 3} samples that were stoichiometric (low oxygen activity) or with ruthenium vacancies (high oxygen activity). Samples with strontium vacancies were found impossible to produce since the ruthenium would precipitate out as RuO{sub 2}. The volume of the unit cell of SrRuO{sub 3} becomes larger as more ruthenium vacancies are introduced. The residual resistivity ratio (RRR) and room temperature resistivity were found to systematically depend on the volume of the unit cell and therefore on the amount of ruthenium vacancies. The RRR varied from {approx}30 for stoichiometric samples to less than two for samples that were very ruthenium poor. The room temperature resistivity varied from 190 {micro}{Omega} cm for stoichoimetric samples to over 300 {micro}{Omega} cm for very ruthenium poor samples. UPS spectra show a shift of weight from the coherent peak to the incoherent peak around the Fermi level when samples have more ruthenium vacancies. Core level XPS spectra of the ruthenium 3d lines show a strong screened part in the case of stoichiometric samples. This screened part disappears when ruthenium vacancies are introduced. Both the UPS and the XPS results are consistent with the view that correlation increases as the amount of ruthenium vacancies increase.

Siemons, W.

2011-08-19T23:59:59.000Z

147

Electronic and optical response of Ru(II) complexes functionalized by methyl, carboxylate groups: joint theoretical and experimental study  

SciTech Connect (OSTI)

New photovoltaic and photocatalysis applications have been recently proposed based on the hybrid Ru(II)-bipyridine-complex/semiconductor quantum dot systems. In order to attach the complex to the surface of a semiconductor, a linking bridge - a carboxyl group - is added to one or two of the 2,2{prime}-bipyridine ligands. Such changes in the ligand structure, indeed, affect electronic and optical properties and consequently, the charge transfer reactivity of Ru-systems. In this study, we apply both theoretical and experimental approaches to analyze the effects brought by functionalization of bipyridine ligands with the methyl, carboxyl, and carboxilate groups on the electronic structure and optical response of the Ru(II) bipyridine complex. First principle calculations based on density functional theory (DFT) and linear response time dependent density functional theory (TDDFT) are used to simulate the ground and excited-state structures of functionalized Ru-complexes in the gas phase, as well as in acetonitrile solution. In addition, an inelaborate Frenkel exciton model is used to explain the optical activity and splitting patterns of the low-energy excited states. All theoretical results nicely complement experimental absorption spectra of Ru-complexes and contribute to their interpretation. We found that the carboxyl group breaks the degeneracy of two low-energy optically bright excited states and red-shifts the absorption spectrum, while leaves ionization and affinity energies of complexes almost unchanged. Experimental studies show a high probability of deprotonation of the carbboxyl group in the Ru-complexes resulted in a slight blue shift and decrease of intensities of the low energy absorption peaks. Comparison of experimental and theoretical linear response spectra of deprotanated complexes demonstrate strong agreement when acetonitrile solvent is used in simulations. A polar solvent is found to play an important role in calculations of optical spectra: it stabilizes the energy of states localized on the carboxyl or carboxylate groups eliminating artificial charge transport states, which typically appear in TDDFT calculations. Thus, it is validated that the excited-state structure of the functionalized Ru-complexes, specifically in the case of the deprotonated functions, can be accurately modeled by TDDFT with the addition of a dielectric continuum in simulations.

Tretiak, Sergei [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

148

JOURNAL OF MAGNETIC RESONANCE 28,383-390 (1977) High-Resolution `H and llB NMR Studiesof 1,2-and 1,7-B&H,,  

E-Print Network [OSTI]

,7-B&H,, A. R. GARBER,G. M. BODNER,AND L. J. TODD Department of Chemistry,' Indiana University, Bloomington, Indiana 47401 AND A. R. SIEDLE~ Inorganic Chemistry Section, National Bureau of Standards by butyllithium and quenching by slow addition of D,O. The deuterated carboranes were purified by sublimation

Bodner, George M.

149

Tracing the origins of permitted emission lines in RU Lupi down to AU scales  

E-Print Network [OSTI]

Most of the observed emission lines and continuum excess from young accreting low mass stars (Classical T Tauri stars -- CTTSs) take place in the star-disk or inner disk region. These regions have a complex emission topology still largely unknown. In this paper the magnetospheric accretion and inner wind contributions to the observed permitted He and H near infrared (NIR) lines of the bright southern CTTS RU Lupi are investigated for the first time. Previous optical observations of RU Lupi showed a large H-alpha profile, due to the emission from a wind in the line wings, and a micro-jet detected in forbidden lines. We extend this analysis to NIR lines through seeing-limited high spectral resolution spectra taken with VLT/ISAAC, and adaptive optics (AO) aided narrow-band imaging and low spectral resolution spectroscopy with VLT/NACO. Using spectro-astrometric analysis we investigate the presence of extended emission down to very low spatial scales (a few AU). The HeI 10830 line presents a P Cygni profile whose absorption feature indicates the presence of an inner stellar wind. Moreover the spectro-astrometric analysis evidences the presence of an extended emission superimposed to the absorption feature and likely coming from the micro-jet detected in the optical. On the contrary, the origin of the Hydrogen Paschen and Brackett lines is difficult to address. We tried tentatively to explain the observed line profiles and flux ratios with both accretion and wind models showing the limits of both approaches. The lack of spectro-astrometric signal indicates that the HI emission is either compact or symmetric. Our analysis confirms the sensitivity of the HeI line to the presence of faint extended emission regions in the close proximity of the star.

L. Podio; P. J. V. Garcia; F. Bacciotti; S. Antoniucci; B. Nisini; C. Dougados; M. Takami

2007-11-16T23:59:59.000Z

150

Roles of Fe2+, Fe3+, and Cr3+ Surface Sites in the Oxidation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fe3+, and Cr3+ Surface Sites in the Oxidation of NO on the (Fe,Cr)3O4(1 1 1) Surface Termination of an -(Fe,Cr Roles of Fe2+, Fe3+, and Cr3+ Surface Sites in the Oxidation of NO...

151

The Effects of Oxygen Plasma on the Chemical Composition and Morphology of the Ru Capping Layer of the Extreme Ultraviolet (EUV) Mask Blanks  

SciTech Connect (OSTI)

Contamination removal from extreme ultraviolet (EUV) mask surfaces is one of the most important aspects to improve reliability for the next generation of EUV lithography. We report chemical and morphological changes of the ruthenium (Ru) mask surface after oxygen plasma treatment using surface sensitive analytical methods: X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and transmission electron microscopy (TEM). Chemical analysis of the EUV masks shows an increase in the subsurface oxygen concentration, Ru oxidation and surface roughness. XPS spectra at various photoelectron takeoff angles suggest that the EUV mask surface was covered with chemisorbed oxygen after oxygen plasma treatment. It is proposed that the Kirkendall effect is the most plausible mechanism that explains the Ru surface oxidation. The etching rate of the Ru capping layer by oxygen plasma was estimated to be 1.5 {+-} 0.2 {angstrom}/min, based on TEM cross sectional analysis.

Belau, Leonid; Park, Jeong Y.; Liang, Ted; Somorjai, Gabor A.

2008-06-07T23:59:59.000Z

152

CO Coverage/Oxidation Correlated with PtRu Electroscatalyst Particle Morphology in 0.3 M Methanol by In Situ XAS  

SciTech Connect (OSTI)

In situ X-ray absorption spectroscopy (XAS) measurements, including both X-ray absorption near edge spectroscopy (XANES) and extended X-ray absorption fine structure (EXAFS) at the Pt L{sub 3} and Ru K edges, were carried out on three different carbon-supported PtRu electrocatalysts in an electrochemical cell in 1 M HClO{sub 4} with 0.3 M methanol. The CO and OH adsorbate coverage on Pt and Ru were determined as a function of the applied potential via the novel delta XANES technique, and the particle morphology was determined from the EXAFS and a modeling technique. Both the bifunctional and direct CO oxidation mechanisms, the latter enhanced by electronic ligand effects, were evident for all three electrocatalysts; however, the dominant mechanism depended critically on the particle size and morphology. Both the Ru island size and overall cluster size had a very large effect on the CO oxidation mechanism and activation of water, with the bifunctional mechanism dominating for more monodispersed Ru islands, and the direct surface ligand effect dominating in the presence of larger Ru islands.

Scott,F.; Mukerjee, S.; Ramaker, D.

2007-01-01T23:59:59.000Z

153

CO Coverage/Oxidation Correlated with PtRu Electrocatalyst Particle Morphology in 0.3 M Methanol by in situ XAS  

SciTech Connect (OSTI)

In situ X-ray absorption spectroscopy (XAS) measurements, including both X-ray absorption near edge spectroscopy (XANES) and extended X-ray absorption fine structure (EXAFS) at the Pt L{sub 3} and Ru K edges, were carried out on three different carbon-supported PtRu electrocatalysts in an electrochemical cell in 1 M HClO{sub 4} with 0.3 M methanol. The CO and OH adsorbate coverage on Pt and Ru were determined as a function of the applied potential via the novel delta XANES technique, and the particle morphology was determined from the EXAFS and a modeling technique. Both the bifunctional and direct CO oxidation mechanisms, the latter enhanced by electronic ligand effects, were evident for all three electrocatalysts; however, the dominant mechanism depended critically on the particle size and morphology. Both the Ru island size and overall cluster size had a very large effect on the CO oxidation mechanism and activation of water, with the bifunctional mechanism dominating for more monodispersed Ru islands, and the direct surface ligand effect dominating in the presence of larger Ru islands.

Scott, F.; Mukerjee, S; Ramaker, D

2007-01-01T23:59:59.000Z

154

/sup 13/C magic angle spinning NMR study of CO adsorption on Ru-exchanged zeolite Y  

SciTech Connect (OSTI)

Three types of adsorbed carbon monoxide are observed on Ru-Y zeolite by /sup 13/C magic angle spinning NMR: linear, bridged, and dicarbonyl CO. Samples exposed to CO at room temperature exhibit only linear and dicarbonyl species. At higher adsorption temperature bridged species are formed and a relative increase in dicarbonyl adsorption is observed. A smaller percentage of linear species is produced at high temperature. The electronic environments of linearly bonded CO are more diverse than those of bridging and dicarbonyl moieties. CO/sub 2/ is formed over Ru-Y zeolite upon initial exposure of the catalyst to CO at room temperature, apparently through reaction with unreduced metal oxide. 20 references, 2 figures, 1 table.

Shoemaker, R.K.; Apple, T.M.

1985-07-18T23:59:59.000Z

155

Q values for neutrinoless double-electron capture in {sup 96}Ru, {sup 162}Er, and {sup 168}Yb  

SciTech Connect (OSTI)

The Q values of the neutrinoless double-electron capture transitions in {sup 96}Ru, {sup 162}Er, and {sup 168}Yb have been determined by Penning-trap mass-ratio measurements. Based on our new high-precision results for the Q values, neither of these transitions shows a resonant enhancement of the capture rate. At present, this excludes these nuclides from the list of suitable candidates in the search for neutrinoless double-electron capture.

Eliseev, S.; Blaum, K. [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany); Nesterenko, D. [Department of Physics, St. Petersburg State University, RU-198504 St. Petersburg (Russian Federation); Block, M.; Herfurth, F.; Minaya Ramirez, E. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, Planckstrasse 1, D-64291 Darmstadt (Germany); Droese, C.; Schweikhard, L. [Institut fuer Physik, Ernst-Moritz-Arndt-Universitaet, D-17487 Greifswald (Germany); Novikov, Yu. N. [Petersburg Nuclear Physics Institute, Gatchina, RU-188300 St. Petersburg (Russian Federation); Zuber, K. [Institut fuer Kern- und Teilchenphysik, Technische Universitaet, D-01069 Dresden (Germany)

2011-03-15T23:59:59.000Z

156

EXAFS study on the morphology change of Ru catalyst by CO adsorption  

SciTech Connect (OSTI)

Great attention has recently been paid to the reconstruction of clean metal surface upon adsorption. Then a question naturally arise what happens to the small metal clusters in supported catalyst upon adsorption, which is the first step of catalytic reaction. Surface spectroscopic techniques like LEED are not available for small particles on the surface of supports, and mainly infrared absorption spectroscopy has provided information, rather indirectly, through the number of observed vibrations and the frequency shifts of adsorbed species such as CO. Recently Van't Blik et al. reported in a series of papers direct evidence of a structural change of Rh clusters supported in Al/sub 2/O/sub 3/ upon CO adsorption. They observed a drastic change in EXAFS (extended X-ray absorption fine structure) by the admission of CO. It was concluded that this change was caused by the disruption of the metal-metal bond, resulting in formation of Rh(CO)/sub 2/ species. As far as the authors know, this is the only example of straightforward evidence of morphology changes caused by adsorption, and it is not certain whether or not this phenomenon is general. In this communication they present another example of the morphology change upon adsorption for Ru supported on ..gamma..-Al/sub 2/O/sub 3/ and show this phenomenon is not limited to Rh.

Mizushima, T.; Tohji, K.; Udagawa, Y.

1988-06-22T23:59:59.000Z

157

Second Harmonic Generation Studies of Fe(II) Interactions with...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Second Harmonic Generation Studies of Fe(II) Interactions with Hematite (?-Fe2O3). Second Harmonic Generation Studies of Fe(II) Interactions with Hematite (?-Fe2O3)....

158

Process and genes for expression and overexpression of active [FeFe] hydrogenases  

DOE Patents [OSTI]

A process for expression of active [FeFe]-hydrogenase in a host organism that does not contain either the structural gene(s) for [FeFe]-hydrogenases and/or homologues for the maturation genes HydE, HydF and HyG, comprising: cloning the structural hydrogenase gene(s) and/or the maturation genes HydE, HydF and HydG from an organisms that contains these genes into expression plasmids; transferring the plasmids into an organism that lacks a native [FeFe]-hydrogenase or that has a disrupted [FeFe]-hydrogenase and culturing it aerobically; and inducing anaerobiosis to provide [FeFe] hydrogenase biosynthesis and H?2#191 production.

Seibert, Michael; King, Paul W; Ghirardi, Maria Lucia; Posewitz, Matthew C; Smolinski, Sharon L

2014-09-16T23:59:59.000Z

159

Radiation effects on interface reactions of U/Fe, U/(Fe + Cr), and U/(Fe + Cr + Ni)  

SciTech Connect (OSTI)

We study the effects of radiation damage on interdiffusion and intermetallic phase formation at the interfaces of U/Fe, U/(Fe + Cr), and U/(Fe + Cr + Ni) diffusion couples. Magnetron sputtering is used to deposit thin films of Fe, Fe + Cr, or Fe + Cr + Ni on U substrates to form the diffusion couples. One set of samples are thermally annealed under high vacuum at 450 C or 550 C for one hour. A second set of samples are annealed identically but with concurrent 3.5 MeV Fe++ ion irradiation. The Fe++ ion penetration depth is sufficient to reach the original interfaces. Rutherford backscattering spectrometry analysis with high fidelity spectral simulations is used to obtain interdiffusion profiles, which are used to examine differences in U diffusion and intermetallic phase formation at the buried interfaces. For all three diffusion systems, Fe++ ion irradiations enhance U diffusion. Furthermore, the irradiations accelerate the formation of intermetallic phases. In U/Fe couples, for example, the unirradiated samples show typical interdiffusion governed by Fick’s laws, while the irradiated ones show step-like profiles influenced by Gibbs phase rules.

KUn Shao; Di Chen; Chaochen Wei; Michael S. Martin; Xuemei Wang; Youngjoo Park; Ed Dein; Kevin R. Coffey; b , Yongho Sohn; Bulent H. Sencer; J. Rory Kennedy

2014-09-01T23:59:59.000Z

160

Microsoft Word - Nitrogenase2015 bh  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fundProject8 -3 Subject: TankINL busing now becomingLana Cox

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Project RU LlSON COPY ON-SITE RADIOLOGICAL PROGRAMS DURING REENTRY DISILLING THROUGH PRODUCTION TESTING  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*.MSE Cores" _August..Land UseRU

162

Exotic magnetism on the quasi-FCC lattices of the d3 double perovskites La2NaB'O6 (B' = Ru, Os)  

SciTech Connect (OSTI)

We find evidence for long-range and short-range ($\\zeta$~$=$~70~\\AA~at 4~K) incommensurate magnetic order on the quasi-face-centered-cubic (FCC) lattices of the monoclinic double perovskites La$_2$NaRuO$_6$ and La$_2$NaOsO$_6$ respectively. Incommensurate magnetic order on the FCC lattice has not been predicted by mean field theory, but may arise via a delicate balance of inequivalent nearest neighbour and next nearest neighbour exchange interactions. In the Ru system with long-range order, inelastic neutron scattering also reveals a spin gap $\\Delta$~$\\sim$~2.75~meV. Magnetic anisotropy is generally minimized in the more familiar octahedrally-coordinated $3d^3$ systems, so the large gap observed for La$_2$NaRuO$_6$ may result from the significantly enhanced value of spin-orbit coupling in this $4d^3$ material.

Aczel, Adam A [ORNL] [ORNL; Baker, Peter J. [ISIS Facility, Rutherford Appleton Laboratory (ISIS)] [ISIS Facility, Rutherford Appleton Laboratory (ISIS); Bugaris, Dan [University of South Carolina] [University of South Carolina; Yeon, Jeongho [University of South Carolina, Columbia] [University of South Carolina, Columbia; Zur Loye, Hans-Conrad [University of South Carolina] [University of South Carolina; Guidi, T. [ISIS Facility, Rutherford Appleton Laboratory (ISIS)] [ISIS Facility, Rutherford Appleton Laboratory (ISIS); Adroja, D. T. [ISIS Facility, Rutherford Appleton Laboratory (ISIS)] [ISIS Facility, Rutherford Appleton Laboratory (ISIS)

2014-01-01T23:59:59.000Z

163

Low-temperature transport properties of the mixed-valence semiconductor Ru{sub 0.5}Pd{sub 0.5}Sb{sub 3}  

SciTech Connect (OSTI)

We have measured the transport properties of Ru{sub 0.5}Pd{sub 0.5}Sb{sub 3} from 300 down to 4 K and compared them to those of the binary-skutterudite antimonides. In particular, the lattice thermal conductivity of this compound is substantially lower than that of CoSb{sub 3} and IrSb{sub 3}. This is attributed to the mixed-valency of ruthenium in this compound. Using near-edge extended absorption fine structure analysis, it is observed that ruthenium in this compound is in the Ru{sup 4+}- and Ru{sup 2+}-valence states in approximately equal proportions. The potential for thermoelectric applications of this material is also discussed. {copyright} {ital 1996 American Institute of Physics.}

Nolas, G.S. [Research and Development Division, Marlow Industries, Dallas, Texas 75238 (United States)] [Research and Development Division, Marlow Industries, Dallas, Texas 75238 (United States); Harris, V.G.; Tritt, T.M. [Materials Physics Branch, Naval Research Laboratory, Washington, DC 20375 (United States)] [Materials Physics Branch, Naval Research Laboratory, Washington, DC 20375 (United States); Slack, G.A. [Department of Physics, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States)] [Department of Physics, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States)

1996-12-01T23:59:59.000Z

164

Interstitial Fe in MgO  

SciTech Connect (OSTI)

Isolated {sup 57}Fe atoms were studied in MgO single-crystals by emission Mössbauer spectroscopy following implantation of {sup 57}Mn decaying to {sup 57}Fe. Four Mössbauer spectral components were found corresponding to different Fe lattice positions and/or charge states. Two components represent Fe atoms substituting Mg as Fe{sup 2+} and Fe{sup 3+}, respectively; a third component is due to Fe in a strongly implantation-induced disturbed region. The fourth component, which is the focus of this paper, can be assigned to Fe at an interstitial site. Comparison of its measured isomer shift with ab initio calculations suggests that the interstitial Fe is located on, or close to, the face of the rock-salt MgO structure. To harmonize such an assignment with the measured near-zero quadrupole interaction a local motion process (cage motion) of the Fe has to be stipulated. The relation of such a local motion as a starting point for long range diffusion is discussed.

Mølholt, T. E., E-mail: tem4@hi.is; Gislason, H. P.; Ólafsson, S. [Science Institute, University of Iceland, Dunhaga 3, IS-107 Reykjavík (Iceland); Mantovan, R. [Laboratorio MDM, IMM-CNR, Via Olivetti 2, 20846 Agrate Brianza (MB) (Italy); Gunnlaugsson, H. P.; Svane, A.; Weyer, G. [Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C (Denmark); Masenda, H.; Naidoo, D. [School of Physics, University of the Witwatersrand, WITS 2050 (South Africa); Bharuth-Ram, K. [Durban University of Technology, Durban 4001 (South Africa); Fanciulli, M. [Laboratorio MDM, IMM-CNR, Via Olivetti 2, 20846 Agrate Brianza (MB) (Italy); Dipartimento di Scienza dei Materiali, Università di Milano Bicocca, Milano (Italy); Johnston, K. [PH Department, ISOLDE/CERN, 1211 Geneva 23 (Switzerland); Langouche, G. [Instituut voor Kern-en Stralings fysika, University of Leuven, B-3001 Leuven (Belgium); Sielemann, R. [Helmholtz-Zentrum-Berlin für Materialien und Energie, D-14109 Berlin (Germany)

2014-01-14T23:59:59.000Z

165

Fe-containing phases in hydrated cements  

SciTech Connect (OSTI)

In this study synchrotron X-ray absorption spectroscopy (XAS) has been applied, an element specific technique which allows Fe-containing phases to be identified in the complex mineral mixture of hydrated cements. Several Fe species contributed to the overall Fe K-edge spectra recorded on the cement samples. In the early stage of cement hydration ferrite was the dominant Fe-containing mineral. Ferrihydrite was detected during the first hours of the hydration process. After 1 day the formation of Al- and Fe-siliceous hydrogarnet was observed, while the amount of ferrihydrite decreased. The latter finding agrees with thermodynamic modeling, which predicts the formation of Fe-siliceous hydrogarnet in Portland cement systems. The presence of Al- and Fe-containing siliceous hydrogarnet was further substantiated in the residue of hydrated cement by performing a selective dissolution procedure. - Highlights: • Fe bound to ferrihydrite at early age hydration • Fe found to be stable in siliceous hydrogarnet at longer term age hydration • Fe-containing AFt and AFm phases are less stable than siliceous hydrogarnet. • The study demonstrates EXAFS used to identify amorphous or poorly crystalline phases.

Dilnesa, B.Z., E-mail: belay.dilnesa@gmail.com [Empa, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Wieland, E. [Paul Scherrer Institute, Laboratory for Waste Management, 5232 Villigen PSI (Switzerland); Lothenbach, B. [Empa, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Dähn, R. [Paul Scherrer Institute, Laboratory for Waste Management, 5232 Villigen PSI (Switzerland); Scrivener, K.L. [Ecole Polytechnique Federal de Lausanne (EPFL), Laboratory for Construction Materials, 1015 Lausanne (Switzerland)

2014-04-01T23:59:59.000Z

166

Adsorption of water on O(2x2)/Ru(0001): thermal stability and inhibition of dissociation by H2O-O bonding  

SciTech Connect (OSTI)

The effect of preadsorbed oxygen on the subsequent adsorption and reactions of water on Ru(0001) has been studied using low temperature scanning tunneling microscopy and DFT calculations. Experiments were carried out for O coverages close to 0.25 ML. It was found that no dissociation of water takes place up to the desorption temperature of {approx}180-230 K. DFT calculations show that intact water on O(2x2)/Ru(0001) is {approx} 0.49 eV more stable than the dissociation products, H and OH, at their preferred fcc and top adsorption sites.

Mugarza, Aitor; Shimizu, Tomoko; Cabrera-Sanfelix, Pepa; Sanchez-Portal, Daniel; Arnau, Andres; Salmeron, Miquel

2008-08-01T23:59:59.000Z

167

Interactions of hydrogen with alkali promoted Ru/SiO{sub 2} catalysts: A proton NMR study  

SciTech Connect (OSTI)

Role of H spillover to the silica support was studied using chemisorption; a strongly bound component of spilled over H was found in the silica support which interfered with accurate measurements of active metal sites via volumetric strong H chemisorption. The volumetric chemisorption technique was modified so that measurement times were reduced from 12--36 h to 1 h. The active Ru surface was characterized means of changes in proton spin counts and NMR Knight shifts vs alkali loading. Na, K blocked the active surface of Ru metal, but Cs was pushed off by H chemisorption. The alkali promoters restricted H mobility on both metal surface and at the metal support interfaces; this is consistent with effects on Fischer-Tropsch synthesis. {sup 1}H NMR was used to study the effect of the active metal and promoter on support hydroxyl groups. The OH group density in the silica support decreased with metal and/or promoter loading, but not on a one-to-one basis; the exchange efficiency of the hydroxyls decreased with atomic size of the alkali metal. An additional downfield proton resonance was detected which was assigned to the alkali hydroxide species in the support.

Ozbay, U.D.

1994-05-10T23:59:59.000Z

168

Fe/Au Multilayers: Structure and Magnetoresistance  

SciTech Connect (OSTI)

We have measured the magnetoresistance (MR) in two sets of Fe/Au multilayers, with varying (1) Fe layer thickness, t{sub Fe} = 3-10 nm, and (2) Au layer thickness t{sub Au} = 5-15 nm, grown on Si substrates by sputtering. The multilayer interface structure and magnetic properties were studied by polarized neutron reflectometry (PNR). The study was undertaken to understand the correlation between structure of these multilayers and their magneto-transport properties.

Singh, Surendra; Basu, Saibal; Bhattacharya, D. [Solid State Physics Division, Bhabha Atomic Research Center, Mumbai 400085 (India); Prajapat, C. L. [Technical Physics Division, Bhabha Atomic Research Center, Mumbai 400085 (India); Gupta, M. [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452 017 (India)

2011-07-15T23:59:59.000Z

169

FE Blog | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProvedDecember 2005DepartmentDecember U.S. Department of9ofDepartment ofatBlog FE Blog RSS

170

Electronic behavior of three oxygen non-stoichiometric Fe4+/Fe3...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

r(T), thermoelectric power a(T), and magnetic susceptibility w(T). Oxidation of Ca 2 Fe 2 O 5 by annealing in ozone progresses by oxygen insertion to give conductive CaFeO...

171

fe0013723-UTA | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Development of Nanoparticle-Stabilized Foams To Improve Performance of Water-less Hydraulic Fracturing Last Reviewed 1292014 DE-FE0013723 Goal The overall objective of this...

172

fe0024314-swri | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Novel Natural Gas Surface Process Equipment for Replacement of Water as Primary Hydraulic Fracturing Fluid Last Reviewed 1272015 DE-FE0024314 Goal The goal is to develop...

173

Fe-V redox flow batteries  

DOE Patents [OSTI]

A redox flow battery having a supporting solution that includes Cl.sup.- anions is characterized by an anolyte having V.sup.2+ and V.sup.3+ in the supporting solution, a catholyte having Fe.sup.2+ and Fe.sup.3+ in the supporting solution, and a membrane separating the anolyte and the catholyte. The anolyte and catholyte can have V cations and Fe cations, respectively, or the anolyte and catholyte can each contain both V and Fe cations in a mixture. Furthermore, the supporting solution can contain a mixture of SO.sub.4.sup.2- and Cl.sup.- anions.

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

2014-07-08T23:59:59.000Z

174

fe0024293-geglobal | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Unconventional Resources Enhanced Oil Recovery Deepwater Tech Methane Hydrate nXis Well Integrity Inspection in Unconventional Wells Last Reviewed January 2015 DE-FE0024293...

175

fe0024271-utaustin | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fracture Diagnostics Using Low Frequency Electromagnetic Induction and Electrically Conductive Proppants Last Reviewed January 2015 DE-FE0024271 Goal The goal of this project is to...

176

Reductive Biotransformation of Fe in Shale-Limestone Saprolite Containing Fe(III) Oxides and Fe(II)/Fe(III) Phyllosilicates  

SciTech Connect (OSTI)

A <2.0-mm fraction of a mineralogically complex subsurface sediment containing goethite and Fe(II)/Fe(III) phyllosilicates was incubated with Shewanella putrefaciens (strain CN32) and lactate at circumneutral pH under anoxic conditions to investigate electron acceptor preference and the nature of the resulting biogenic Fe(II) fraction. Anthraquinone-2,6-disulfonate (AQDS), an electron shuttle, was included in select treatments to enhance bioreduction and subsequent biomineralization. The sediment was highly aggregated and contained two distinct clast populations: i) a highly weathered one with “sponge-like” internal porosity, large mineral crystallites, and Fe-containing micas, and ii) a dense, compact one with fine-textured Fe-containing illite and nano-sized goethite, as revealed by various forms of electron microscopic analyses. Approximately 10 to 15% of the Fe(III)TOT was bioreduced by CN32 over 60 d in media without AQDS, whereas 24% and 35% of the Fe(III)TOT was bioreduced by CN32 after 40 and 95 d in media with AQDS. Little or no Fe2+, Mn, Si, Al, and Mg were evident in aqueous filtrates after reductive incubation. Mössbauer measurements on the bioreduced sediments indicated that both goethite and phyllosilicate Fe(III) were partly reduced without bacterial preference. Goethite was more extensively reduced in the presence of AQDS whereas phyllosilicate Fe(III) reduction was not influenced by AQDS. Biogenic Fe(II) resulting from phyllosilicate Fe(III) reduction remained in a layer-silicate environment that displayed enhanced solubility in weak acid. The mineralogic nature of the goethite biotransformation product was not determined. Chemical and cryogenic Mössbauer measurements, however, indicated that the transformation product was not siderite, green rust, magnetite, Fe(OH)2, or Fe(II) adsorbed on phyllosilicate or bacterial surfaces. Several lines of evidence suggested that biogenic Fe(II) existed as surface associated phase on the residual goethite, and/or as a Fe(II)-Al coprecipitate. Sediment aggregation and mineral physical and/or chemical factors were demonstrated to play a major role on the nature and location of the biotransformation reaction and its products.

Kukkadapu, Ravi K.; Zachara, John M.; Fredrickson, Jim K.; McKinley, James P.; Kennedy, David W.; Smith, Steven C.; Dong, Hailiang

2006-07-15T23:59:59.000Z

177

FE Petroleum Reserves News | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Petroleum Reserves News FE Petroleum Reserves News RSS June 30, 2011 Department of Energy Update on Strategic Petroleum Reserve Sale On June 23, 2011, the International Energy...

178

Structural and magnetic properties of the ordered FePt{sub 3}, FePt and Fe{sub 3}Pt nanoparticles  

SciTech Connect (OSTI)

The Fe{sub x}Pt{sub 100?x} nanoparticles (NPs) with different nominal atomic rations (30?x?80) were synthesized at 700 °C by the sol–gel method. The structure, morphology and magnetic properties of the samples were investigated. When the Fe content in the Fe–Pt alloy NPs was 30 at%, FePt{sub 3} NPs were successfully synthesized. With the increase in Fe content up to 50 at%, it was found that the superlattice reflections (0 0 1) and (1 1 0) appeared, which indicated the formation of the L1{sub 0}-FePt phase. Meanwhile, the FePt{sub 3} fraction was reduced. When the Fe content increased to 60 at%, single-phase L1{sub 0}-FePt NPs were synthesized. The coercivity (Hc), saturation magnetization (Ms) and chemical order parameter S for Fe{sub 60}Pt{sub 40} NPs were as high as 10,200 Oe, 17.567 emu/g and 0.928, respectively. With the further increase of the Fe content to 80 at%, only Fe{sub 3}Pt phase existed and the Hc of the Fe{sub 3}Pt NPs decreased drastically to 360 Oe. - Graphical abstract: Fe{sub 3}Pt, FePt and FePt{sub 3} nanoparticles was obtained by sol–gel method. The effect of iron and platinum content on structural and magnetic properties of the FePt nanoparticles was investigated. Display Omitted - Highlights: • L1{sub 2}-FePt{sub 3}, L1{sub 0}-FePt and L1{sub 2}-Fe{sub 3}Pt NPs were synthesized by sol–gel method. • The chemical order parameter S affects the magnetic properties of the Fe–Pt alloy. • Structural and magnetic properties of the Fe–Pt alloy NPs were studied. • The synthetic route in this study will open up the possibilities of practical use.

Liu, Yang [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry (Jilin Normal University), Ministry of Education, Siping 136000 (China); Institute of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Jiang, Yuhong; Zhang, Xiaolong; Wang, Yaxin; Zhang, Yongjun; Liu, Huilian; Zhai, Hongju; Liu, Yanqing [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry (Jilin Normal University), Ministry of Education, Siping 136000 (China); Yang, Jinghai, E-mail: jhyang1@jlnu.edu.cn [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry (Jilin Normal University), Ministry of Education, Siping 136000 (China); Yan, Yongsheng, E-mail: yanyongsheng215@126.com [Institute of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China)

2014-01-15T23:59:59.000Z

179

Address: 125252, Russia, Moscow, Zorge Street, 9, www.farmina.ru The status and development trends of the Russian HP market  

E-Print Network [OSTI]

#12;2 Address: 125252, Russia, Moscow, Zorge Street, 9, www.farmina.ru The status and development Shishov, Farmina, Russia E-mail:vv@shishov.net . ., , 10.2013 #12;3 Address: 125252, Russia . « » 2020 . 45 , (), [1]. #12;4 Address: 125252, Russia, Moscow, Zorge Street, 9, www

Oak Ridge National Laboratory

180

Giant magnetoresistive structures based on CrO{sub 2} with epitaxial RuO{sub 2} as the spacer layer  

SciTech Connect (OSTI)

Epitaxial ruthenium dioxide (RuO{sub 2})/chromium dioxide(CrO{sub 2}) thin film heterostructures have been grown on (100)-TiO{sub 2} substrates by chemical vapor deposition. Both current-in-plane (CIP) and current-perpendicular-to-plane (CPP) giant magnetoresistive stacks were fabricated with either Co or another epitaxial CrO{sub 2} layer as the top electrode. The Cr{sub 2}O{sub 3} barrier, which forms naturally on CrO{sub 2} surfaces, is no longer present after the RuO{sub 2} deposition, resulting in a highly conductive interface that has a resistance at least four orders of magnitude lower. However, only very limited magnetoresistance (MR) was observed. Such low MR is due to the appearance of a chemically and magnetically disordered layer at the CrO{sub 2} and RuO{sub 2} interfaces when Cr{sub 2}O{sub 3} is transformed into rutile structures during its intermixing with RuO{sub 2}.

Miao, G.X.; Gupta, A.; Sims, H.; Butler, W.H.; Ghosh, S.; Xiao Gang [Physics Department, Brown University, Providence, Rhode Island 02912 (United States); Center for Materials for Information Technology, University of Alabama, Tuscaloosa, Alabama 35487 (United States); Department of Electrical and Computer Engineering, University of Illinois, Chicago, Illinois 60607 (United States); Physics Department, Brown University, Providence, Rhode Island 02912 (United States)

2005-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Microstructures and electrical resistivities of the RuO{sub 2} electrode on SiO{sub 2}/Si annealed in the oxygen ambient  

SciTech Connect (OSTI)

The electrical resistivity property of RuO{sub 2} thin films grown on the SiO{sub 2}/Si substrate by reactive dc sputtering was examined in terms of microstructure using x-ray diffraction and cross-sectional transmission electron microscopy. As the samples were annealed in the oxygen ambient over the temperature range 300{endash}700{degree}C, the resistivity decreased from 270 to 90 {mu}{Omega}cm with increasing annealing temperature. When heat treatment was performed below 500{degree}C, the strain which accumulated in the RuO{sub 2} layer during deposition was released without significant increase in grain size. It is thought that below 500{degree}C the improvement in the crystallinity plays an important role in the variation of the resistivity. Although a considerable amount of growth of RuO{sub 2} grains was achieved, the columnar structure of the RuO{sub 2} layer in the as-deposited sample remained unchanged even after annealing at 700{degree}C. The resistivity improvement above 500{degree}C was driven mainly by the grain boundary annihilation. {copyright} {ital 1996 Materials Research Society.}

Lee, J.S.; Kwon, H.J.; Jeong, Y.W.; Kim, H.H.; Kim, C.Y. [LG Electronics Research Center, 16, Woomyeon-dong, Seocho-gu, Seoul 137-140 (Korea)

1996-11-01T23:59:59.000Z

182

Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439  

E-Print Network [OSTI]

Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Y. Choia Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 Y. Z. Yoo, O. Chmaissem, A. Ullah, S. Kolesnik, and C. W University, DeKalb, Illinois 60115 D. Haskel Advanced Photon Source, Argonne National Laboratory, Argonne

Haskel, Daniel

183

Electron Microscopy Study of Novel Ru Doped La0.8Sr0.2CrO3 as Anode Materials for Solid Oxide Fuel Cells (SOFCs)  

E-Print Network [OSTI]

Cells (SOFCs) Y. Wang,* B. D. Madsen,* W. Kobsiriphat,* S.A. Barnett* and L.D. Marks* * Department of electrocatalyst nanoparticles have been introduced into ceramic anodes to improve the electrochemical of Ru nanoparticles could then be directly linked to the electrochemical performance of LSCR anode. Our

Marks, Laurence D.

184

Giant dielectric response in Pb,,Zr,Ti...O3Pb2Ru2O6.5 all-ceramic percolative composite  

E-Print Network [OSTI]

Giant dielectric response in Pb,,Zr,Ti...O3­Pb2Ru2O6.5 all-ceramic percolative composite Vid Bobnar response of a composite comprising a conductive filler embedded in a dielectric matrix--the effective­9 and inorganic composites comprising metal particles dis- persed in a dielectric matrix10­14 have been developed

Bobnar, Vid

185

Excited State Dynamics of Two New Ru(II) Cyclometallated Dyes: Relation to Cells for Solar Energy Conversion and Comparison to  

E-Print Network [OSTI]

Excited State Dynamics of Two New Ru(II) Cyclometallated Dyes: Relation to Cells for Solar Energy, are reported. Related complexes have been used as efficient dyes in dye- sensitized solar cells (DSSCs of ruthenium dyes used in DSSCs to lower energies, it is evident from this work, that for cyclometallated phpy

Turro, Claudia

186

Mid-Infrared Spectrum of [Ru(phen)3]2+* Kristin M. Omberg, Jon R. Schoonover,*, Stefan Bernhard, John A. Moss,  

E-Print Network [OSTI]

(diphenylarsino)ethane) in acetonitrile-d3 at 298 K. The spectra are assigned by comparison to electrochemically generated [RuIII(phen)3 Materials. Acetonitrile-d3 was obtained from Cambridge Isotope Labs and used without further purification

Bernhard, Stefan

187

Theoretical Electron Density Distributions for Fe- and Cu-Sulfide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electron Density Distributions for Fe- and Cu-Sulfide Earth Materials: A Connection between Bond Length, Bond Theoretical Electron Density Distributions for Fe- and Cu-Sulfide...

188

Purification and Characterization of [NiFe]-Hydrogenase of Shewanella...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Purification and Characterization of NiFe-Hydrogenase of Shewanella oneidensis MR-1. Purification and Characterization of NiFe-Hydrogenase of Shewanella oneidensis MR-1....

189

Study of Fe-Co Nanocomposite Films  

SciTech Connect (OSTI)

Moessbauer study of nanogranular ferromagnetic FeCo films is presented. Two ways of production of nanocomposite systems were employed: (i) hollow cathode plasma jet deposition process, and (ii) laser ablation from Fe-Co metallic targets by means of a KrF excimer laser and r.f. magnetron sputtering. Complementary information on the composition of the samples were obtained by nuclear magnetic resonance of {sup 57}Fe and {sup 59}Co nuclei, conversion electron Moessbauer spectroscopy, and high resolution transmission electron microscopy. The films contain crystalline nanoparticles, 5-20 nm in size, embedded in an amorphous matrix.

Lancok, A.; Klementova, M. [Institute of Inorganic Chemistry of the AS CR, v. v. i., 250 68 Husinec-Rez 1001 (Czech Republic); Kohout, J. [Faculty of Mathematics and Physics. Charles University, V Holesovickach 2, 180 00 Prague (Czech Republic); Miglierini, M. [Institute of Inorganic Chemistry of the AS CR, v. v. i., 250 68 Husinec-Rez 1001 (Czech Republic); Department of Nuclear Physics and Technology, Slovak University of Technology, Ilkovicova 3, 812 19 Bratislava (Slovakia); Fendrych, F.; Lancok, J. [Institute of Physics AS CR, v. v. i., Na Slovance 2, 182 21 Prague (Czech Republic)

2010-07-13T23:59:59.000Z

190

FE0005889_UTPermian | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Case Studies of the ROZ CO2 Flood and the Combined ROZMPZ CO2 Flood at the Goldsmith Landreth Unit, Ector County, Texas Last Reviewed 12162014 DE-FE0005889 Goal The goal of this...

191

fe0024311-ttu | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Maximize Liquid Oil Production from Shale Oil and Gas Condensate Reservoirs by Cyclic Gas Injection Last Reviewed 12102014 DE-FE0024311 Goal The goal is to evaluate the oil...

192

The transport coefficients in (R1.5Ce0.5)RuSr2Cu2O10-5 (R=Gd,Eu) rutheno-cuprates  

E-Print Network [OSTI]

Page Table 1. The onset of superconductivity and the values for first and second superconducting temperatures, Tc and Tcg superconducting temperatures for Ru-1222(Eu) with different oxygen content..............................................61... Table 2. The onset of superconductivity, the values for first and second superconducting temperatures, Tc and Tcg determined from resistivity data and the superconducting temperatures TcS determined from thermopower data for Ru-1222(Gd) with different...

Anatska, Maryna Petrovna

2007-04-25T23:59:59.000Z

193

Thermodynamics of the Magnetite-Ulvöspinel (Fe3O4-Fe2TiO4) Solid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Magnetite-Ulvspinel (Fe3O4-Fe2TiO4) Solid Solution. Thermodynamics of the Magnetite-Ulvspinel (Fe3O4-Fe2TiO4) Solid Solution. Abstract: The thermodynamics of mixing and its...

194

High-Quality Epitaxy of Ruthenium Dioxide, RuO2, on Rutile Titanium Dioxide, TiO2, by Pulsed Chemical Vapor Deposition  

E-Print Network [OSTI]

of rutile TiO2, a material with a high dielectric constant. Therefore, capacitors with high capacitance per these capacitors have low leakage current. Due to its good redox properties, RuO2 has been made into electrodes films have been made by CVD, such as wide-gap semiconductors ZnO23,25 and SnO2,26,27 super- conducting

195

Underwater Explosive Shock Consolidation of Nanocomposite Pr2Fe14B/-Fe Magnetic Powders  

E-Print Network [OSTI]

performance permanent magnets has focused attention on exchange-coupled nanocomposites because of their low to fabricate exchange-coupled Pr2Fe14B/-Fe nanocomposite bulk magnets, using explosively generated shock waves, ensured exchange coupling between the hard and soft phases, resulting in magnetic properties better than

Liu, J. Ping

196

Explosive shock processing of Pr2Fe14B/ Fe exchange-coupled nanocomposite bulk magnets  

E-Print Network [OSTI]

Explosive shock processing of Pr2Fe14B/ ­Fe exchange-coupled nanocomposite bulk magnets Z.Q. Jin between neigh- boring magnetic phases.1,2 The prerequisite for effective exchange coupling is a small are usually used to produce single-phase microcrystalline permanent magnets, are not favored in making bulk

Liu, J. Ping

197

Characterization of new Co and Ru on -WC catalysts for Fischer-Tropsch reaction. Influence of the carbide surface state.  

E-Print Network [OSTI]

[8]. Among the group VI transition metal carbides, the hexagonal tungsten carbide WC is a remarkable proceeds on supported transition metal catalysts, Co or Fe on oxide supports generally Al2O3 or SiO2 [1 of the carbide surface state. A. Griboval-Constant(1) *, J.-M. Giraudon(1) , I. Twagishema(1) , G. Leclercq(1

Paris-Sud XI, Université de

198

Characterization of new Co and Ru on -WC catalysts for Fischer-Tropsch reaction. Influence of the carbide surface state.  

E-Print Network [OSTI]

of the metallic particles [8]. Among the group VI transition metal carbides, the hexagonal tungsten carbide WC monoxide and hydrogen. FT synthesis proceeds on supported transition metal catalysts, Co or Fe on oxide of the carbide surface state. A. Griboval-Constant(1) *, J.-M. Giraudon(1) , I. Twagishema(1) , G. Leclercq(1

Paris-Sud XI, Université de

199

Heavy d-electron Quasiparticle Interference and Real-space Electronic Structure of Sr3Ru2O7  

SciTech Connect (OSTI)

The intriguing idea that strongly interacting electrons can generate spatially inhomogeneous electronic liquid-crystalline phases is over a decade old, but these systems still represent an unexplored frontier of condensed-matter physics. One reason is that visualization of the many-body quantum states generated by the strong interactions, and of the resulting electronic phases, has not been achieved. Soft condensed-matter physics was transformed by microscopies that enabled imaging of real-space structures and patterns. A candidate technique for obtaining equivalent data in the purely electronic systems is spectroscopic imaging scanning tunnelling microscopy (SI-STM). The core challenge is to detect the tenuous but 'heavy' momentum (k)-space components of the many-body electronic state simultaneously with its real-space constituents. Sr{sub 3}Ru{sub 2}O{sub 7} provides a particularly exciting opportunity to address these issues. It possesses a very strongly renormalized 'heavy' d-electron Fermi liquid and exhibits a field-induced transition to an electronic liquid-crystalline phase. Finally, as a layered compound, it can be cleaved to present an excellent surface for SI-STM.

Lee, J.; Allan, M.P.; Wang, M.A.; Farrell, J.; Grigera, S.A.; Baumberger, F.; Davis, J.C.; Mackenzie, A.P.

2009-09-13T23:59:59.000Z

200

The mechanical properties of FeAl  

SciTech Connect (OSTI)

Only in the last few years has progress been made in obtaining reproducible mechanical properties data for FeAl. Two sets of observations are the foundation of this progress. The first is that the large vacancy concentrations that exist in FeAl at high temperature are easily retained at low temperature and that these strongly affect the low-temperature mechanical properties. The second is that RT ductility is adversely affected by water vapor. Purpose of this paper is not to present a comprehensive overview of the mechanical properties of FeAl but rather to highlight our understanding of key phenomena and to show how an understanding of the factors which control the yield strength and fracture behavior has followed the discovery of the above two effects. 87 refs, 9 figs.

Baker, I. [Dartmouth Coll., Hanover, NH (United States); George, E.P. [Oak Ridge National Lab., TN (United States)

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Evidence for weak electronic correlations in Fe-pnictides  

SciTech Connect (OSTI)

Using x-ray absorption and resonant inelastic x-ray scattering, charge dynamics at and near the Fe L edges is investigated in Fe pnictide materials, and contrasted to that measured in other Fe compounds. It is shown that the XAS and RIXS spectra for 122 and 1111 Fe pnictides are each qualitatively similar to Fe metal. Cluster diagonalization, multiplet, and density-functional calculations show that Coulomb correlations are much smaller than in the cuprates, highlighting the role of Fe metallicity and strong covalency in these materials. Best agreement with experiment is obtained using Hubbard parameters U {approx}< 2eV and J {approx} 0.8eV.

Yang, W.L.

2010-04-29T23:59:59.000Z

202

Evidence for weak electronic correlations in Fe-Pnictides  

SciTech Connect (OSTI)

Using x-ray absorption and resonant inelastic x-ray scattering, charge dynamics at and near the Fe L edges is investigated in Fe pnictide materials, and contrasted tothat measured in other Fe compounds. It is shown that the XAS and RIXS spectra for 122 and 1111 Fe pnictides are each qualitatively similar to Fe metal. Cluster diagonalization, multiplet, and density-functional calculations show that Coulomb correlations are much smaller than in the cuprates, highlighting the role of Fe metallicity and strong covalency in these materials. Best agreement with experiment is obtained using Hubbard parameters U<~;; 2eV and J ~;; 0.8eV.

Yang, W. L.; Sorini, A. P.; Chen, C-C.; Moritz, B.; Lee, W.-S.; Vernay, F.; Olalde-Velasco, P.; Denlinger, J. D.; Delley, B.; Chu, J.-H.; Analytis, J.G.; Fisher, I. R.; Ren, Z. A.; Yang, J.; Lu, W.; Zhao, Z. X.; van den Brink, J.; Hussain, Z.; Shen, Z.-X.; Devereaux, T. P.

2009-06-11T23:59:59.000Z

203

Magnetic interaction in oxygenated alpha Fe-phthalocyanines  

SciTech Connect (OSTI)

Alpha iron phthalocyanines (?-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mössbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mössbauer spectroscopy revealed that upon oxygenation of ?-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated ?-FePc was observed below 20 K. In-field Mössbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated ?-FePc.

Kuzmann, Ern?, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltán; Horváth, Attila [Institute of Chemistry, Eötvös Loránd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsár, Zoltán [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

2014-10-27T23:59:59.000Z

204

Membrane separation advances in FE hydrogen program  

SciTech Connect (OSTI)

Since its inception in Fiscal Year 2003 the US Office of Fossil Energy (FE) Hydrogen from Coal Program has sponsored more than 60 projects and made advances in the science of separating out pure hydrogen from syngas produced through coal gasification. The Program is focusing on advanced hydrogen separation technologies, which include membranes, and combining the WGS reaction and hydrogen separation in a single operation known as process intensification. The article explains the technologies and describes some key FE membrane projects. More details are available from http://www.fossil.energy.gov. 1 fig.

NONE

2007-12-31T23:59:59.000Z

205

Regulation of brain copper homeostasis by the brain barrier systems: Effects of Fe-overload and Fe-deficiency  

SciTech Connect (OSTI)

Maintaining brain Cu homeostasis is vital for normal brain function. The role of systemic Fe deficiency (FeD) or overload (FeO) due to metabolic diseases or environmental insults in Cu homeostasis in the cerebrospinal fluid (CSF) and brain tissues remains unknown. This study was designed to investigate how blood-brain barrier (BBB) and blood-SCF barrier (BCB) regulated Cu transport and how FeO or FeD altered brain Cu homeostasis. Rats received an Fe-enriched or Fe-depleted diet for 4 weeks. FeD and FeO treatment resulted in a significant increase (+ 55%) and decrease (- 56%) in CSF Cu levels (p < 0.05), respectively; however, neither treatment had any effect on CSF Fe levels. The FeD, but not FeO, led to significant increases in Cu levels in brain parenchyma and the choroid plexus. In situ brain perfusion studies demonstrated that the rate of Cu transport into the brain parenchyma was significantly faster in FeD rats (+ 92%) and significantly slower (- 53%) in FeO rats than in controls. In vitro two chamber Transwell transepithelial transport studies using primary choroidal epithelial cells revealed a predominant efflux of Cu from the CSF to blood compartment by the BCB. Further ventriculo-cisternal perfusion studies showed that Cu clearance by the choroid plexus in FeD animals was significantly greater than control (p < 0.05). Taken together, our results demonstrate that both the BBB and BCB contribute to maintain a stable Cu homeostasis in the brain and CSF. Cu appears to enter the brain primarily via the BBB and is subsequently removed from the CSF by the BCB. FeD has a more profound effect on brain Cu levels than FeO. FeD increases Cu transport at the brain barriers and prompts Cu overload in the CNS. The BCB plays a key role in removing the excess Cu from the CSF.

Monnot, Andrew D.; Behl, Mamta; Ho, Sanna; Zheng, Wei, E-mail: wzheng@purdue.edu

2011-11-15T23:59:59.000Z

206

Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Inhibition and HC Storage Modeling in Fe-Zeolite Catalysts for HD Diesel Engines Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite Catalysts for HD Diesel Engines...

207

Reductive Biotransformation of Fe in Shale-Limestone Saprolite...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AQDS, whereas 24% and 35% of the Fe(III)TOT was bioreduced by CN32 after 40 and 95 d in media with AQDS. Little or no Fe2+, Mn, Si, Al, and Mg were evident in aqueous filtrates...

208

The effect of the exchange-correlation functional on H{sub 2} dissociation on Ru(0001)  

SciTech Connect (OSTI)

The specific reaction parameter (SRP) approach to density functional theory (DFT) has enabled a chemically accurate description of reactive scattering experiments for activated H{sub 2}–metal systems (H{sub 2} + Cu(111) and Cu(100)), but its application has not yet resulted in a similarly accurate description of non-activated or weakly activated H{sub 2}-metal systems. In this study, the effect of the choice of the exchange-correlation functional in DFT on the potential energy surface and dynamics of H{sub 2} dissociation on Ru(0001), a weakly activated system, is investigated. In total, full potential energy surfaces were calculated for over 20 different functionals. The functionals investigated include functionals incorporating an approximate description of the van der Waals dispersion in the correlation functional (vdW-DF and vdW-DF2 functionals), as well as the revTPSS meta-GGA. With two of the functionals investigated here, which include vdW-DF and vdW-DF2 correlation, it has been possible to accurately reproduce molecular beam experiments on sticking of H{sub 2} and D{sub 2}, as these functionals yield a reaction probability curve with an appropriate energy width. Diffraction probabilities computed with these two functionals are however too high compared to experimental diffraction probabilities, which are extrapolated from surface temperatures (T{sub s}) ? 500 K to 0 K using a Debye–Waller model. Further research is needed to establish whether this constitutes a failure of the two candidate SRP functionals or a failure of the Debye–Waller model, the use of which can perhaps in future be avoided by performing calculations that include the effect of surface atom displacement or motion, and thereby of the experimental T{sub s}.

Wijzenbroek, M.; Kroes, G. J. [Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, 2300 RA, Leiden (Netherlands)] [Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, 2300 RA, Leiden (Netherlands)

2014-02-28T23:59:59.000Z

209

Solution-phase photochemistry of a [FeFe]hydrogenase model compound: Evidence of photoinduced isomerisation  

SciTech Connect (OSTI)

The solution-phase photochemistry of the [FeFe] hydrogenase subsite model ({mu}-S(CH{sub 2}){sub 3}S)Fe{sub 2}(CO){sub 4}(PMe{sub 3}){sub 2} has been studied using ultrafast time-resolved infrared spectroscopy supported by density functional theory calculations. In three different solvents, n-heptane, methanol, and acetonitrile, relaxation of the tricarbonyl intermediate formed by UV photolysis of a carbonyl ligand leads to geminate recombination with a bias towards a thermodynamically less stable isomeric form, suggesting that facile interconversion of the ligand groups at the Fe center is possible in the unsaturated species. In a polar or hydrogen bonding solvent, this process competes with solvent substitution leading to the formation of stable solvent adduct species. The data provide further insight into the effect of incorporating non-carbonyl ligands on the dynamics and photochemistry of hydrogenase-derived biomimetic compounds.

Kania, Rafal; Hunt, Neil T. [Department of Physics, University of Strathclyde, SUPA, Glasgow G4 0NG (United Kingdom); Frederix, Pim W. J. M. [Department of Physics, University of Strathclyde, SUPA, Glasgow G4 0NG (United Kingdom); WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL (United Kingdom); Wright, Joseph A.; Pickett, Christopher J. [Energy Materials Laboratory, School of Chemistry, University of East Anglia, Norwich Research Park, Norwich NR4 7TJ (United Kingdom); Ulijn, Rein V. [WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL (United Kingdom)

2012-01-28T23:59:59.000Z

210

Design of FePd spring actuators Taishi Wada*  

E-Print Network [OSTI]

. The coil spring made by a FSMA is activated by the attractive magnetic force produced by electromagnets on the above principle by using polycrystalline FePd alloy. Since the stiffness of the FePd coil spring become actuation. Keywords: actuator, coil spring, FePd, wire, ferromagnetic shape memory alloy, superelasticity

Taya, Minoru

211

Low 60Fe abundance in Semarkona and Sahara 99555  

E-Print Network [OSTI]

Iron-60 (t1/2=2.62 Myr) is a short-lived nuclide that can help constrain the astrophysical context of solar system formation and date early solar system events. A high abundance of 60Fe (60Fe/56Fe= 4x10-7) was reported by in situ techniques in some chondrules from the LL3.00 Semarkona meteorite, which was taken as evidence that a supernova exploded in the vicinity of the birthplace of the Sun. However, our previous MC-ICPMS measurements of a wide range of meteoritic materials, including chondrules, showed that 60Fe was present in the early solar system at a much lower level (60Fe/56Fe=10-8). The reason for the discrepancy is unknown but only two Semarkona chondrules were measured by MC-ICPMS and these had Fe/Ni ratios below ~2x chondritic. Here, we show that the initial 60Fe/56Fe ratio in Semarkona chondrules with Fe/Ni ratios up to ~24x chondritic is 5.4x10-9. We also establish the initial 60Fe/56Fe ratio at the time of crystallization of the Sahara 99555 angrite, a chronological anchor, to be 1.97x10-9. The...

Tang, Haolan

2015-01-01T23:59:59.000Z

212

Multiferroicity and spiral magnetism in FeVO{sub 4} with quenched Fe orbital moments  

SciTech Connect (OSTI)

FeVO{sub 4} has been studied by heat capacity, magnetic susceptibility, electric polarization and single-crystal neutron-diffraction experiments. The triclinic crystal structure is made of S-shaped clusters of six Fe{sup 3+} ions, linked by VO{sub 4}{sup 3-} groups. Two long-range magnetic ordering transitions occur at T{sub N1}=22 K and T{sub N2}=15 K. Both magnetic structures are incommensurate and below T{sub N2}, FeVO{sub 4} becomes weakly ferroelectric coincidentally with the loss of the collinearity of the magnetic structure in a very similar fashion than in the classical TbMnO{sub 3} multiferroic material. However we argue that the symmetry considerations and the mechanisms invoked to explain these properties in TbMnO{sub 3} do not straightforwardly apply to FeVO{sub 4}. First, the magnetic structures, even the collinear structure, are all acentric so that ferroelectricity in FeVO{sub 4} is not correlated with the fact magnetic ordering is breaking inversion symmetry. Regarding the mechanism, FeVO{sub 4} has quenched orbital moments that questions the exact role of the spin-orbit interactions.

Daoud-Aladine, A.; Chapon, L. C. [ISIS facility, Rutherford Appleton Laboratory, STFC, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Kundys, B.; Martin, C.; Simon, C. [Laboratoire CRISMAT-UMR, 6508 ENSI CAEN, 6, Marechal Juin, 14050 Caen (France); Radaelli, P. G. [ISIS facility, Rutherford Appleton Laboratory, STFC, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Brown, P. J. [Institut Laue-Langevin, 6 rue Jules Horowitz, BP 156, 38042 Grenoble Cedex 9 (France)

2009-12-01T23:59:59.000Z

213

Corrosion performance of Fe-Cr-Al and Fe aluminide alloys in complex gas environments  

SciTech Connect (OSTI)

Alumina-forming structural alloys can offer superior resistance to corrosion in the presence of sulfur-containing environments, which are prevalent in coal-fired fossil energy systems. Further, Fe aluminides are being developed for use as structural materials and/or cladding alloys in these systems. Extensive development has been in progress on Fe{sub 3}Al-based alloys to improve their engineering ductility. In addition, surface coatings of Fe aluminide are being developed to impart corrosion resistance to structural alloys. This paper describes results from an ongoing program that is evaluating the corrosion performance of alumina-forming structural alloys, Fe-Al and Fe aluminide bulk alloys, and Fe aluminide coatings in environments typical of coal-gasification and combustion atmospheres. Experiments were conducted at 650-1000{degrees}C in simulated oxygen/sulfur gas mixtures. Other aspects of the program are corrosion evaluation of the aluminides in the presence of HCl-containing gases. Results are used to establish threshold Al levels in the alloys for development of protective alumina scales and to determine the modes of corrosion degradation that occur in the materials when they are exposed to S/Cl-containing gaseous environments.

Natesan, K. [Argonne National Lab., IL (United States); Johnson, R.N. [Pacific Northwest Lab., Richland, WA (United States)

1995-05-01T23:59:59.000Z

214

In-field {sup 57}Fe Mössbauer spectroscopy below spin-flop transition in powdered troilite (FeS) mineral  

SciTech Connect (OSTI)

Powdered troilite (FeS), extracted from the Cape York IIIA octahedrite meteorite, was investigated employing in-field {sup 57}Fe Mössbauer spectroscopy. The study identified a typical behavior of polycrystalline antiferromagnetic material under external magnetic fields. The in-field evolution of the {sup 57}Fe Mössbauer spectra showed that the spin-flop transition in the FeS system occurs at a field higher than 5 T.

Cuda, Jan, E-mail: jan.cuda@upol.cz; Tucek, Jiri; Filip, Jan; Malina, Ondrej; Krizek, Michal; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science, Palacký University in Olomouc, 17. listopadu 1192/12, 771 46 Olomouc (Czech Republic); Kohout, Tomas [Department of Physics, University of Helsinki, P.O. Box 64, 00014 Helsinki University, Finland and Institute of Geology, Academy of Sciences of the Czech Republic v.v.i., Rozvojová 269, 165 00 Prague (Czech Republic)

2014-10-27T23:59:59.000Z

215

“Covalent Hydration” Reactions in Model Monomeric Ru 2,2'-Bipyridine Complexes: Thermodynamic Favorability as a Function of Metal Oxidation and Overall Spin States  

SciTech Connect (OSTI)

Density functional theory (DFT) has been used to investigate the plausibility of water addition to the simple mononuclear ruthenium complexes, [(NH{sub 3}){sub 3}(bpy)Ru=O]{sup 2+}/{sup 3+} and [(NH{sub 3}){sub 3}(bpy)RuOH]{sup 3+}, in which the OH fragment adds to the 2,2{prime}-bipyridine (bpy) ligand. Activation of bpy toward water addition has frequently been postulated within the literature, although there exists little definitive experimental evidence for this type of 'covalent hydration'. In this study, we examine the energetic dependence of the reaction upon metal oxidation state, overall spin state of the complex, as well as selectivity for various positions on the bipyridine ring. The thermodynamic favorability is found to be highly dependent upon all three parameters, with free energies of reaction that span favorable and unfavorable regimes. Aqueous addition to [(NH{sub 3}){sub 3}(bpy)Ru=O]{sup 3+} was found to be highly favorable for the S = 1/2 state, while reduction of the formal oxidation state on the metal center makes the reaction highly unfavorable. Examination of both facial and meridional isomers reveals that when bipyridine occupies the position trans to the ruthenyl oxo atom, reactivity toward OH addition decreases and the site preferences are altered. The electronic structure and spectroscopic signatures (EPR parameters and simulated spectra) have been determined to aid in recognition of 'covalent hydration' in experimental systems. EPR parameters are found to uniquely characterize the position of the OH addition to the bpy as well as the overall spin state of the system.

Ozkanlar, Abdullah; Cape, Jonathan L.; Hurst, James K.; Clark, Aurora E.

2011-09-05T23:59:59.000Z

216

Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal Hydride (TiH2, ZrH2, MgH2, and/or CaH2) Composite Systems  

SciTech Connect (OSTI)

Ammonia borane (AB = NH3BH3) is one of the most attractive materials for chemical hydrogen storage due to its high hydrogen contents of 19.6 wt.%, however, impurity levels of borazine, ammonia and diborane in conjunction with foaming and exothermic hydrogen release calls for finding ways to mitigate the decomposition reactions. In this paper we present a solution by mixing AB with metal hydrides (TiH2, ZrH2, MgH2 and CaH2) which have endothermic hydrogen release in order to control the heat release and impurity levels from AB upon decomposition. The composite materials were prepared by mechanical ball milling, and their H2 release properties were characterized by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The formation of volatile products from decomposition side reactions, such as borazine (N3B3H6) was determined by mass spectrometry (MS). Sieverts type pressure-composition-temperature (PCT) gas-solid reaction instrument was adopted to observe the kinetics of the H2 release reactions of the combined systems and neat AB. In situ 11B MAS-NMR revealed a destabilized decomposition pathway. We found that by adding specific metal hydrides to AB we can eliminate the impurities and mitigate the heat release.

Choi, Young Joon; Xu, Yimin; Shaw, Wendy J.; Ronnebro, Ewa

2012-04-19T23:59:59.000Z

217

Controlled oxidation of FeCo magnetic nanoparticles to produce faceted FeCo/ferrite nanocomposites for rf heating applications  

E-Print Network [OSTI]

Controlled oxidation of FeCo magnetic nanoparticles to produce faceted FeCo/ferrite nanocomposites XRD and TEM showed MNPs to have a thin ferrite shell. Nanopowders were isochronally annealed and oxidation products in FeCo/ferrite nanocomposite materials and their influence on applications.4 We report

Laughlin, David E.

218

Speciation of Fe in ambient aerosol and cloudwater  

SciTech Connect (OSTI)

Atmospheric iron (Fe) is thought to play an important role in cloudwater chemistry (e.g., S(IV) oxidation, oxidant production, etc.), and is also an important source of Fe to certain regions of the worlds oceans where Fe is believed to be a rate-limiting nutrient for primary productivity. This thesis focuses on understanding the chemistry, speciation and abundance of Fe in cloudwater and aerosol in the troposphere, through observations of Fe speciation in the cloudwater and aerosol samples collected over the continental United States and the Arabian Sea. Different chemical species of atmospheric Fe were measured in aerosol and cloudwater samples to help assess the role of Fe in cloudwater chemistry.

Siefert, L. [California Institute of Technology, Pasadena, CA (United States)

1996-08-15T23:59:59.000Z

219

Effect of nitrogen upon structural and magnetic properties of FePt in FePt/AlN multilayer structures  

SciTech Connect (OSTI)

This paper investigates the effect of the addition of nitrogen in FePt layers for ultrathin FePt/AlN multilayer structures. X-ray diffraction results reveal that a compressive stress relaxation occurs after annealing owing to the release of interstitial nitrogen atoms in the FePt layers. The introduction of nitrogen also induces a large in-plane compressive strain during grain growth not seen in FePt deposited without nitrogen. This strain is considered to decrease the driving force for (111) grain growth and FePt ordering.

Gao, Tenghua, E-mail: gao.t.ab@m.titech.ac.jp; Zhang, Cong; Sannomiya, Takumi; Muraishi, Shinji; Nakamura, Yoshio; Shi, Ji [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2-12-1 Oh-okayama, Meguro-ku, Tokyo 152-8552 (Japan)

2014-09-01T23:59:59.000Z

220

Structural characterisation of BaTiO{sub 3} thin films deposited on SrRuO{sub 3}/YSZ buffered silicon substrates and silicon microcantilevers  

SciTech Connect (OSTI)

We report on the progress towards an all epitaxial oxide layer technology on silicon substrates for epitaxial piezoelectric microelectromechanical systems. (101)-oriented epitaxial tetragonal BaTiO{sub 3} (BTO) thin films were deposited at two different oxygen pressures, 5.10{sup ?2} mbar and 5.10{sup ?3} mbar, on SrRuO{sub 3}/Yttria-stabilized zirconia (YSZ) buffered silicon substrates by pulsed laser deposition. The YSZ layer full (001) orientation allowed the further growth of a fully (110)-oriented conductive SrRuO{sub 3} electrode as shown by X-ray diffraction. The tetragonal structure of the BTO films, which is a prerequisite for the piezoelectric effect, was identified by Raman spectroscopy. In the BTO film deposited at 5.10{sup ?2} mbar strain was mostly localized inside the BTO grains whereas at 5.10{sup ?3} mbar, it was localized at the grain boundaries. The BTO/SRO/YSZ layers were finally deposited on Si microcantilevers at an O{sub 2} pressure of 5.10{sup ?3} mbar. The strain level was low enough to evaluate the BTO Young modulus. Transmission electron microscopy (TEM) was used to investigate the epitaxial quality of the layers and their epitaxial relationship on plain silicon wafers as well as on released microcantilevers, thanks to Focused-Ion-Beam TEM lamella preparation.

Colder, H.; Jorel, C., E-mail: corentin.jorel@unicaen.fr; Méchin, L. [GREYC, UMR 6072, CNRS, ENSICAEN, UCBN, 6 bd du Maréchal Juin, 14050 Caen Cedex (France); Domengès, B. [LAMIPS, CRISMAT-NXP Semiconductors-Presto Engineering laboratory, CNRS-UMR 6508, ENSICAEN, UCBN, 2 rue de la Girafe, 14 000 Caen (France); Marie, P.; Boisserie, M. [CIMAP, UMR 6252, CNRS, ENSICAEN, UCBN, CEA, 6 bd du Maréchal Juin, 14050 Caen Cedex (France); Guillon, S.; Nicu, L. [LAAS, CNRS, Univ de Toulouse, 7 avenue du Colonel Roche, 31400 Toulouse (France); Galdi, A. [GREYC, UMR 6072, CNRS, ENSICAEN, UCBN, 6 bd du Maréchal Juin, 14050 Caen Cedex (France); Department of Industrial Engineering, CNR-SPIN Salerno, Università di Salerno, 84084 Fisciano, Salerno (Italy)

2014-02-07T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
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221

SiO MASERS IN ASYMMETRIC MIRAS. IV. {chi} CYGNI, R AQUILAE, R LEO MINORIS, RU HERCULIS, U HERCULIS, AND U ORIONIS  

SciTech Connect (OSTI)

This is the fourth paper in a series of multi-epoch observations at 7 mm wavelength of the SiO masers in several asymptotic giant branch stars from a sample of Mira variable stars showing evidence of asymmetric structure in the infrared. These stars have been observed interferometrically in the infrared by IOTA and with VLBA measurements of the SiO masers. In this paper, we present the observations of {chi} Cygni ({chi} Cyg), R Aquilae (R Aql), R Leo Minoris (R LMi), RU Herculis (RU Her), U Herculis (U Her), and U Orionis (U Ori). Several radial features with velocity gradients were observed, all with velocities close to systemic furthest from the star and redshifted closer to the stellar surface. Systemic velocities are estimated for several of the stars. No compelling evidence of asymmetry is seen in the maser distributions. All maser rings are approximately twice the near-IR uniform disk diameter and are comparable in size to the extended molecular envelope when such measurements are available.

Cotton, W. D. [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22903-2475 (United States); Ragland, S. [W. M. Keck Observatory, 65-1120 Mamalahoa Hwy, Kamuela, HI 96743 (United States); Pluzhnik, E. A. [NASA-Ames Research Center, Moffett Field, CA 94035 (United States); Danchi, W. C. [NASA Goddard Space Flight Center, Exoplanets and Stellar Astrophysics, Code 667, Greenbelt, MD 20771 (United States); Traub, W. A. [Jet Propulsion Laboratory, California Institute of Technology, M/S 301-451, 4800 Oak Grove Dr., Pasadena, CA 91109 (United States); Willson, L. A. [Department of Physics and Astronomy, Iowa State University, Ames, IA 50014 (United States); Lacasse, M. G., E-mail: bcotton@nrao.ed [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

2010-06-15T23:59:59.000Z

222

Proteome of Geobacter sulfurreducens grown with Fe(III) oxide or Fe(III) citrate as the electron acceptor.  

SciTech Connect (OSTI)

e(III) oxides are the most abundant source of reducible Fe(III) by microorganisms in most soils and sediments, yet few studies on the physiology of Fe(III)-reducing microorganisms during growth on Fe(III) oxide have been conducted because of the technical difficulties in working with cell growth and harvest in the presence of Fe(III) oxides. Geobacter sulfurreducens is a representative of the Geobacter species that predominate in a variety of subsurface environments in which Fe(III) oxide is important. In order to better understand the physiology of Geobacter species during growth on Fe(III) oxide, the proteome of G. sulfurreducens grown on Fe(III) oxide was compared with the proteome of cells grown with soluble Fe(III) citrate. Two-dimensional polyacrylamide gel electrophoresis (2-D PAGE) revealed 19 proteins that were more abundant during growth on Fe(III) oxide than on soluble Fe(III). These included proteins related to protein synthesis, electron transfer and energy production, oxidative stress, protein folding, outer membrane proteins, nitrogen metabolism and hypothetical proteins. Further analysis of the proteome with the accurate mass and time (AMT) tag method revealed additional proteins associated with growth on Fe(III) oxide. These included the outer-membrane c-type cytochrome, OmcS and OmcG, which genetic studies have suggested are required for Fe(III) oxide reduction. Furthermore, several other cytochromes, as yet unstudied, were detected to be significantly up regulated during growth on Fe(III) oxide and other proteins of unknown function were more abundant during growth on Fe(III) oxide than on soluble Fe(III). PilA, the structural protein for pili, which is required for Fe(III) oxide reduction, and other pilin-associated proteins were also more abundant during growth on Fe(III) oxide. Confirmation of the differential expression of proteins known to be important in Fe(III) oxide reduction was observed, and an additional number of previously unidentified proteins were found with significant abundance in the cells grown under conditions of Fe(III) oxide reduction.

Ding, Y-H R.; Hixson, Kim K.; Aklujkar, Ma; Lipton, Mary S.; Smith, Richard D.; Lovley, Derek R.; Mester, Tunde

2008-12-01T23:59:59.000Z

223

Activation of the S-H Group in Fe(µ2-SH)Fe Clusters: S-H Bond Strengths and Free Radical Reactivity of the Fe(µ2-SH)Fe Cluster  

SciTech Connect (OSTI)

Absolute rate constants were determined for the abstraction of hydrogen atom from (OC)3Fe(?-SH)2Fe(CO)3 (Fe2S2H2) and (OC)3Fe(?-SCH3)(?-SH)Fe(CO)3 (Fe2S2MeH) by benzyl radical in benzene. From the temperature dependent rate data for Fe2S2H2, ?H‡ and ?S‡ were determined to be 2.03 ? 0.56 kcal/mol and 19.3 ? 1.7 cal/mol K, respectively, giving kabs = 1.2 ? 107 M 1 s 1 at 25?C. For Fe2S2MeH, ?H‡ and ?S‡ were determined to be 1.97 ? 0.46 kcal/mol and 18.1 ? 1.5 cal/mol K, respectively, giving kabs = 2.3 ? 107 M 1 s 1 at 25?C. Temperature dependent rate data are also reported for hydrogen atom abstraction by benzyl radical from thiophenol (?H‡ = 3.62 ? 0.43 kcal/mol, ?S‡ = 21.7 ? 1.3 cal/mol K) and H2S (?H‡ = 5.13 ? 0.99 kcal/mol, ?S‡ = 24.8 ? 3.2 cal/mol K), giving kabs at 25?C of 2.5 ? 105 and 4.2 ? 103 M 1 s 1, respectively. DFT calculations predict S-H bond strengths of 73.1 and 73.2 kcal/mol for Fe2S2H2 and Fe2S2MeH, respectively. Free energy and NMR chemical shift calculations confirm the NMR assignments and populations of Fe2S2H2 and Fe2S2MeH isomers. Derived radicals Fe2S2H• and Fe2S2Me• exhibit singly occupied HOMOs with unpaired spin density distributed between the two Fe atoms, a bridging sulfur, and d?-bonding between Fe centers. The S-H solution bond dissociation free energy (SBDFE) of Fe2S2MeH was found to be 69.4 ± 1.7 kcal/mol by determination of its pKa (16.0 ± 0.4) and the potential for the oxidation of the anion, Fe2S2Me- of 0.26 ± 0.05 V vs. ferrocene in acetonitrile (corrected for dimerization of Fe2S2Me•). This SBDFE for Fe2S2MeH corresponds to a gas phase bond dissociation enthalpy (BDE) of 74.2 kcal/mol, in satisfactory agreement with the DFT value of 73.2 kcal/mol. Replacement of the Fe-Fe bond in Fe2S2MeH with bridging ?-S (Fe2S3MeH) or ?-CO (Fe2S2(CO)MeH) groups leads to (DFT) BDEs of 72.8 and 66.2 kcal/mol, the latter indicating dramatic effects of choice of bridge structure on S-H bond strengths. These results provide a model for the reactivity of hydrosulfido sites of low-valent heterogeneous FeS catalysts. This work was supported by the US Department of Energy's Office of Basic Energy Sciences, Chemical Sciences program. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

Franz, James A.; Lee, Suh-Jane; Bowden, Thomas A.; Alnajjar, Mikhail S.; Appel, Aaron M.; Birnbaum, Jerome C.; Bitterwolf, Thomas E.; Dupuis, Michel

2009-10-28T23:59:59.000Z

224

MAS NMR Study of the Metastable Solid Solutions Found in the LiFePO4/FePO4 System  

E-Print Network [OSTI]

compared to the lithium-electron interaction in x Li FeP04 (by Fermi contact interactions between the lithium ions andlithium ions in LiFePC^ suggests a modification of the Fe -O-P interaction.

Cabana, Jordi

2010-01-01T23:59:59.000Z

225

Interfacial electronic transport phenomena in single crystalline Fe-MgO-Fe thin barrier junctions  

SciTech Connect (OSTI)

Spin filtering effects in nano-pillars of Fe-MgO-Fe single crystalline magnetic tunnel junctions are explored with two different sample architectures and thin MgO barriers (thickness: 3–8 monolayers). The two architectures, with different growth and annealing conditions of the bottom electrode, allow tuning the quality of the bottom Fe/MgO interface. As a result, an interfacial resonance states (IRS) is observed or not depending on this interface quality. The IRS contribution, observed by spin polarized tunnel spectroscopy, is analyzed as a function of the MgO barrier thickness. Our experimental findings agree with theoretical predictions concerning the symmetry of the low energy (0.2?eV) interfacial resonance states: a mixture of ?{sub 1}-like and ?{sub 5}-like symmetries.

Gangineni, R. B., E-mail: rameshg.phy@pondiuni.edu.in [Department of Physics, School of Physical, Chemical and Applied Sciences, Pondicherry University, R. V. Nagar, Kalapet, Pondicherry 605 014 (India); SPINTEC, UMR 8191 CEA/CNRS/UJF-Grenoble 1/Grenoble INP, INAC, 17 rue des Martyrs, F-38054 Grenoble Cedex (France); Bellouard, C., E-mail: christine.bellouard@ijl.nancy-universite.fr; Duluard, A. [Institut Jean Lamour, UMR 7198, CNRS-Université de Lorraine, BP 239, 54506 Vandoeuvre (France); Negulescu, B. [Institut Jean Lamour, UMR 7198, CNRS-Université de Lorraine, BP 239, 54506 Vandoeuvre (France); UFR de Sciences et Techniques, Matériaux, microélectronique, acoustique, nanotechnologies (GREMAN), University François Rabelais, Parc de Grandmont, 37200 Tours (France); Baraduc, C.; Gaudin, G. [SPINTEC, UMR 8191 CEA/CNRS/UJF-Grenoble 1/Grenoble INP, INAC, 17 rue des Martyrs, F-38054 Grenoble Cedex (France); Tiusan, C., E-mail: coriolan.tiusan@phys.utcluj.ro [Institut Jean Lamour, UMR 7198, CNRS-Université de Lorraine, BP 239, 54506 Vandoeuvre (France); Department of Physics and Chemistry, Center of Superconductivity, Spintronics and Surface Science, Technical University of Cluj Napoca, Str. Memorandumului No. 28, RO-400114 Cluj-Napoca (Romania)

2014-05-05T23:59:59.000Z

226

Photo- and thermal-induced antiferromagnetic interlayer coupling in Fe/(Fe-Si) superlattices  

SciTech Connect (OSTI)

We have grown via sputtering, Fe - iron silicide superlattices that exhibit novel thermal and photomagnetic effects. For {approximately}15 {Angstrom} nominal thickness of the silicide layer the superlattices are antiferromagnetically (AF) coupled at room temperature. Upon cooling below 100K, they gradually revert to ferromagnetic alignment, but the AF coupling is restored at low temperature by exposure to visible light off sufficient intensity (> 10 mW/mm{sup 2}). These effects are due to charge carriers in the silicide spacer layer which, when thermally or photo-generated, are capable of communicating spin information between the Fe layers.

Mattson, J.E.; Fullerton, E.E.; Kumar, S.; Lee, S.R.; Sowers, C.H.; Grimsditch, M.; Bader, S.D. [Argonne National Lab., IL (United States); Parker, F.T. [California Univ., San Diego, La Jolla, CA (United States). Center for Magnetic Recording Research

1993-08-01T23:59:59.000Z

227

Ru!fsa!!  

Office of Legacy Management (LM)

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228

Doc.~:Ru.  

Office of Legacy Management (LM)

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229

Overview of the development of FeAl intermetallic alloys  

SciTech Connect (OSTI)

B2-phase FeAl ordered intermetallic alloys based on an Fe-36 at.% Al composition are being developed to optimize a combination of properties that includes high-temperature strength, room-temperature ductility, and weldability. Microalloying with boron and proper processing are very important for FeAl properties optimization. These alloys also have the good to outstanding resistance to oxidation, sulfidation, and corrosion in molten salts or chlorides at elevated temperatures, characteristic of FeAl with 30--40 at.% Al. Ingot- and powder-metallurgy (IM and PM, respectively) processing both produce good properties, including strength above 400 MPa up to about 750 C. Technology development to produce FeAl components for industry testing is in progress. In parallel, weld-overlay cladding and powder coating technologies are also being developed to take immediate advantage of the high-temperature corrosion/oxidation and erosion/wear resistance of FeAl.

Maziasz, P.J.; Liu, C.T.; Goodwin, G.M.

1995-09-01T23:59:59.000Z

230

XANES study of Fe-implanted strontium titanate  

SciTech Connect (OSTI)

Properties of strontium titanate SrTiO{sub 3} (STO) depend to a great extent on the substitutional dopants and defects of crystal structure. The ion beam implantation method was used for doping STO (001) crystals with Fe at different doses. Implanted samples were then annealed at 350°C in oxygen to induce recrystallization and remove oxygen vacancies produced during ion implantation process. The effect of Fe doping and post-implantation annealing was studied by X-ray Absorption Near Edge Spectroscopy (XANES) method and Superconducting Quantum Interference Device (SQUID). XANES allowed to monitor the change in structure of STO crystals and in the local environment of Fe following the implantation and annealing steps. SQUID measurements revealed correlation between magnetic moment and Fe implantation dose. Ferromagnetic hysteresis was observed on selected Fe-implanted STO at 5 K. The observed magnetic properties can be correlated with the several Fe oxide phases in addition to the presence of O/Ti vacancies.

Lobacheva, O.; Goncharova, L. V.; Chavarha, M.; Sham, T. K. [Department of Physics and Astronomy, and Department of Chemistry, University of Western Ontario, London, ON N6A 5B7 (Canada)

2014-03-31T23:59:59.000Z

231

FE Speeches and Testimony | Department of Energy  

Office of Environmental Management (EM)

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232

FE Petroleum Reserves News | Department of Energy  

Office of Environmental Management (EM)

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233

Microsoft Word - FeV.doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMappingENVIRONMENTALHYDROPOWER MEETING Tulsa16, 20138,AprilF F Fig. 1.Fe

234

Microsoft Word - FeVI.doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMappingENVIRONMENTALHYDROPOWER MEETING Tulsa16, 20138,AprilF F Fig. 1.Fe6

235

FE Clean Energy Group | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump37. It isInformationexplains a4Evendale,OpenFAOSTAT Jump to:FE Clean

236

Isolation and microbial reduction of Fe(III) phyllosilicates...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

phases, and if possible, Fe(III) oxide phases, from a weathered shale saprolite sediment in order to permit experimentation with each phase in isolation. Physical...

237

Spin glass behavior in FeAl2  

E-Print Network [OSTI]

temperature.10 For higher Al concen- trations, Fe12xAlx alloys form a series of complex ordered crystal structures, generally with weak magnetic behavior. While no magnetic or spin-glass transitions have been iden- tified in these alloys, a recent site...-diluted Ising model has suggested the existence of a spin-glass phase in disordered alloys of this type.11 In the dilute Fe limit, Fe-Al alloys are nonmagnetic, and there is some uncertainty as to whether the Fe ions lose their moment through spin...

Lue, CS; Oner, Y.; Naugle, Donald G.; Ross, JH.

2001-01-01T23:59:59.000Z

238

Structure and Properties of Magnetic (Co, Fe, Fe{sub 3}C and Ni) Carbon Beads  

SciTech Connect (OSTI)

Nanoparticles exhibit unique physical properties due to the surface or quantum-size effects. Particular attention has been focused on magnetic nanoparticles and substantial progress has been done in this field. In this work magnetic composites, consisting of elementary metals or carbides nanocrystallites, stabilized in carbon matrix, were prepared by the procedure comprising formation of appropriate metal acrylamide complexes, followed by frontal polymerization and pyrolysis of the polymer at various temperatures. Application of frontal polymerization and further pyrolysis enables formation of composite beads consisting of Co, Fe, Fe{sub 3}C or Ni nanocrystallites stabilized in carbon matrix. It was found that the lowest pyrolysis temperature, which enables the production of metallic nanocrystallites, was 673 K for Co and Ni, and 773 K for Fe. The magnetic properties of the beads, percentage of the metallic component, their composition and shape depended on the pyrolysis temperature. Extracts on the basis of composites containing Fe{sub 3}C showed no cytotoxicity, whereas those containing Co and Ni exhibited negligible cytotoxicity up to concentrations of 6.25 mg/ml.

Leonowicz, Marcin; Izydorzak, Marta [Faculty of Materials Science and Engineering, Warsaw University of Technology, Woloska 141, 02-507 Warsaw (Poland); Pomogailo, Anatolii D.; Dzhardimalieva, Gulzhian I. [Institute of Chemical Physics RAS, Chernogolovka (Russian Federation)

2010-12-02T23:59:59.000Z

239

Microsoft Word - MappingMetals bh  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

andor heavy molecules of oil feedstock into smaller and lighter hydrocarbons, such as gasoline. The workhorse of the FCC process is a tiny catalyst particle of 50-150 m...

240

Microsoft Word - PtxY bh  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

July 2014 Mass-selected Nanoparticles of Pt x Y as Model Catalysts for Oxygen Electroreduction A team of researchers from the Technical University of Denmark and the SUNCAT...

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Microsoft Word - InterfacialElectron bh  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fundProject8 -3 Subject: Tank Waste System Plan4 CX

242

Microsoft Word - MappingMetals bh  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fundProject8 -3 Subject: Tank Waste4.1 OctoberManaging

243

Local magnetism in the molecule-based metamagnet [Ru2(O2CMe)4]3[Cr(CN)6] probed with implanted muons  

SciTech Connect (OSTI)

We present a muon-spin relaxation study of local magnetism in the molecule-based metamagnet [Ru2(O2CMe)4]3[Cr(CN)6]. We observe magnetic order with TN = 33 K, although above 25 K the sublattice spins become less rigid and a degree of static magnetic disorder is observed. The comparison of measurements in applied magnetic field with simulations allows us to understand the origin of the muon response across the metamagnetic transition and to map out the phase diagram of the material. Applied hydrostatic pressures of up to 6 kbar lead to an increase in the local magnetic field along with a complex change in the internal magnetic field distribution.

Lancaster, T. [University of Oxford; Pratt, F. L. [ISIS Facility, Rutherford Appleton Laboratory; Blundell, S. J. [University of Oxford; Steele, Andrew J. [University of Oxford; Baker, Peter J. [ISIS Facility, Rutherford Appleton Laboratory; Wright, Jack D. [University of Oxford; Fishman, Randy Scott [ORNL; Miller, Joel S. [University of Utah

2011-01-01T23:59:59.000Z

244

Synthesis and characterization of redox polymers of (M(4-vinyl-4 prime -methyl-2,2 prime -bipyridine) sub 3 )(PF sub 6 ) sub 2 (M = Ru, Os)  

SciTech Connect (OSTI)

The authors have prepared polymers of (M(vbpy){sub 3}(PF{sub 6}){sub 2}) (M = Ru, Os) (vbpy = 4-vinyl-4{prime}-methyl-2,2{prime}-bipyridine) in solution via free-radical polymerization and fractionated them according to molecular weight using size exclusion chromatography. Different fractions have been characterized by electrochemical and spectroscopic means. The authors find that whereas for the osmium containing polymers the relative polymer size varies in proportion to the number of vinyl groups consumed during the polymerization reaction, the same is not true for the analogous ruthenium polymers. In addition, the emission energy of both the ruthenium and osmium polymers is also related to the concentration of residual vinyl groups in the polymer. Upon polymerization, there is a shift in the emission toward higher energies. Electrochemically determined diffusion coefficients are consistent with the relative size of the various fractions.

Bommarito, S.L.; Lowery-Bretz, S.P.; Abruna, H.D. (Cornell Univ., Ithaca, NY (United States))

1992-02-05T23:59:59.000Z

245

Solution medium control of the photoredox yield in the Ru(bpy)/sub 3//sup 2 +//methyl viologen/EDTA system  

SciTech Connect (OSTI)

The observed quantum yield of formation of the methyl viologen radical cation, phi(MV/sup +/-), upon 450-nm irradiation of the Ru(bpy)/sub 3//sup 2 +//methyl viologen dication/EDTA system at pH 11.0 is dependent on the concentrations of all three components. Under the conditions of the experiments, phi(MV/sup +/-)approx. =2eta/sub cr/ where eta/sub cr/ is the efficiency of release of redox products from the solvent cage. The maximum value of eta/sub cr/ is approx. =0.17 at high concentrations of all components where the photosensitizer, electron relay, and sacrificial electron donor exist as ion-paired aggregates within a single solvent-caged unit. 3 figures.

Mandal, K.; Hoffman, M.Z.

1984-01-19T23:59:59.000Z

246

Ru-induced loss of long-range magnetic order in a-Fe90 xRuxZr10 Physics Department, McGill University, 3600 University Street, Montreal, Quebec H3A 2T8, Canada  

E-Print Network [OSTI]

, The University of New South Wales, Sydney, NSW 2052, Australia Zin Tun AECL, Chalk River Laboratories, Chalk the DUALSPEC triple-axis spectrometer at AECL, Chalk River. Initial polarizations of 95% at 0.237 nm were

Ryan, Dominic

247

RDX degradation using an integrated Fe(0)-microbial treatment approach  

E-Print Network [OSTI]

remediation challenge at numerous munitions manufacturing and load-assemblage-package facilities. This work was enhanced by anaerobic bacteria that feed on cathodic hydrogen (i.e., H2 produced during anaerobic Fe(0) corrosion by water). Apparently, the hydrogenotrophic consortium that exploits Fe(0) corrosion

Alvarez, Pedro J.

248

Hydrogen decrepitation of sintered NdFeB magnets  

SciTech Connect (OSTI)

The kinetics of the hydrogen absorption and desorption behavior of a NdFeB sintered magnet is studied. Hydrogenation at temperatures above 200 C is used to crumble the Nd-enriched phase. The grains of Nd{sub 2}Fe{sub 14}B phase remain undamaged. Hydrogen desorption occurs in several stages and is complete at approximately 400 C.

Stiller, C.; Roth, S.; Binner, A. [Inst. fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany)] [Inst. fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany)

1994-03-01T23:59:59.000Z

249

Synthesis and Characterization of Ferroferriborate (Fe3BO5) Nanorods  

E-Print Network [OSTI]

a number of interesting properties, including its catalytic oxidation of ethyl acetate and methanol[5] and Fe3BO5 and GdBO3 particles produced from interface diffusion between Fe­Gd particle cores and B2O3/H3) could be used as a weak reducing agent for producing Au and Pd nanoparticles in the presence of oleyl

Wang, Zhong L.

250

Fundamentals of Engineering (FE) Exam Fluid Mechanics Review  

E-Print Network [OSTI]

Fundamentals of Engineering (FE) Exam Fluid Mechanics Review Steven Burian Civil & Environmental Engineering March 22, 2013 #12;Morning (Fluid Mechanics) A. Flow measurement B. Fluid properties C. Fluid, and compressors K. Non-Newtonian flow L. Flow through packed beds Fluids and FE #12;#12;#12;Fluids § Fluids

Provancher, William

251

Synthesis and properties of titanomagnetite (Fe3-xTixO4) nanoparticles...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

properties of titanomagnetite (Fe3-xTixO4) nanoparticles: A tunable solid-state Fe(IIIII) redox system. Synthesis and properties of titanomagnetite (Fe3-xTixO4) nanoparticles: A...

252

Synthesis and Photoexcited Charge Carrier Dynamics of beta-FeOOH...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Photoexcited Charge Carrier Dynamics of beta-FeOOH Nanorods. Synthesis and Photoexcited Charge Carrier Dynamics of beta-FeOOH Nanorods. Abstract: Akaganeite(B-FeOOH) nanorods of...

253

Anharmonic phonons and magnons in BiFeO3  

SciTech Connect (OSTI)

The phonon density of states (DOS) and magnetic excitation spectrum of polycrystalline BiFeO3 were measured for temperatures 200 < T < 750K , using inelastic neutron scattering (INS). Our results indicate that the magnetic spectrum of BiFeO3 closely resembles that of similar Fe perovskites, such as LaFeO3, despite the cycloid modulation in BiFeO3. We do not find any evidence for a spin gap. A strong T-dependence of the phonon DOS was found, with a marked broadening of the whole spectrum, providing evidence of strong anharmonicity. This anharmonicity is corroborated by large amplitude motions of Bi and O ions observed with neutron diffraction. These results highlight the importance of spin-phonon coupling in this material.

Delaire, Olivier A [ORNL; Ma, Jie [ORNL; Stone, Matthew B [ORNL; Huq, Ashfia [ORNL; Gout, Delphine J [ORNL; Brown, Craig [National Institute of Standards and Technology (NIST); Wang, Kefeng [Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing; Ren, Zhifeng [Boston College, Chestnut Hill

2012-01-01T23:59:59.000Z

254

Physica B 322 (2002) 236247 The electronic properties of FeCo, Ni3Mn and Ni3Fe  

E-Print Network [OSTI]

1. Introduction The Fe- and Mn-based transition metal (TM) alloys possess a number of unusual with the local-density functional method. It is shown that the value of the magnetic moment is insensitive- stant and magnetization of Fe­Co alloys depend non-monotonically on Co concentration, and change

Kim, Jai Sam

255

Interface structures in FePtFe3Pt hard-soft exchange-coupled magnetic nanocomposites  

E-Print Network [OSTI]

Interface structures in FePtÃ?Fe3Pt hard-soft exchange-coupled magnetic nanocomposites Jing Li with sizes 10 nm. This ensures the effective exchange coupling of magnetically hard and soft phases. High magnetic materials, the performance of conventional bulk permanent magnetic ma- terials is limited by its

Liu, J. Ping

256

Enhanced coercivity in thermally processed ,,Nd,Dy...,,Fe,Co,Nb,B...5.5/ -Fe nanoscale multilayer magnets  

E-Print Network [OSTI]

and theoretical research has been done on exchange-coupled hard-soft1­14 permanent magnets. However, up to now, ex, the addition of the soft phase to the hard phase enhances the remanence but deteriorates the permanent-magnet,10 exchange-coupled -Fe/Nd­Fe­B multilayer magnets as investigated by Shindo et al.11 the Nd

Liu, J. Ping

257

Rauchfuss Group Prep of Fe2S2(CO)6 Large Scale Synthesis of Fe2S2(CO)6.  

E-Print Network [OSTI]

Rauchfuss Group Prep of Fe2S2(CO)6 Large Scale Synthesis of Fe2S2(CO)6. A three neck, 5-liter round was filtered though a small plug of Celite to remove elemental sulfur. Solvent was removed, and the solid and reduced pressure. We do not recommend sublimation as a method of purification. IR (pentanes): 2084 (s

Rauchfuss, Thomas B.

258

Biostimulation of Iron Reduction and Subsequent Oxidation of Sediment Containing Fe-silicates and Fe-oxides: Effect of Redox Cycling on Fe(III) Bioreduction  

SciTech Connect (OSTI)

Microbial reduction of iron has been shown to be important in the transformation and remediation of contaminated sediments. Re-oxidation of microbially reduced iron may occur in sediments that experience oxidation-reduction cycling and can thus impact the extent of contaminant remediation. The purpose of this research was to quantify iron oxidation in a flow-through column filled with biologically-reduced sediment and to compare the iron phases in the re-oxidized sediment to both the pristine and biologically-reduced sediment. The sediment contained both Fe(III)-oxides (primarily goethite) and silicate Fe (illite/vermiculite) and was biologically reduced in phosphate buffered (PB) medium during a 497 day column experiment with acetate supplied as the electron donor. Long-term iron reduction resulted in partial reduction of silicate Fe(III) without any goethite reduction, based on Mössbauer spectroscopy measurements. This reduced sediment was treated with an oxygenated PB solution in a flow-through column resulting in the oxidation of 38% of the biogenic Fe(II). Additional batch experiments showed that the Fe(III) in the oxidized sediment was more quickly reduced compared to the pristine sediment, indicating that oxidation of the sediment not only regenerated Fe(III) but also enhanced iron reduction compared to the pristine sediment. Oxidation-reduction cycling may be a viable method to extend iron-reducing conditions during in-situ bioremediation.

Komlos, John; Kukkadapu, Ravi K.; Zachara, John M.; Jaffe, Peter R.

2007-07-01T23:59:59.000Z

259

Microbial Reduction of Fe(III) in the Fithian and Muloorina Illites...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fe(III) in the Fithian and Muloorina Illites : Contrasting Extents and Rates of Bioreduction. Microbial Reduction of Fe(III) in the Fithian and Muloorina Illites : Contrasting...

260

Effect of Extent of Natural Subsurface Bioreduction on Fe-mineralogy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extent of Natural Subsurface Bioreduction on Fe-mineralogy of Subsurface Sediments. Effect of Extent of Natural Subsurface Bioreduction on Fe-mineralogy of Subsurface Sediments....

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Physical Properties of Intermetallic FE2VA1  

SciTech Connect (OSTI)

Fe{sub 2}VAl has recently been discovered to have a negative temperature coefficient of resistivity, moderately enhanced specific heat coefficient, and a large DOS at the Fermi level by photoemission. This triggered a round of heated research to understand the ground state of this material, both theoretically and experimentally. here they report a comprehensive characterization of Fe{sub 2}VAl. X-ray diffraction exhibited appreciable antisite disorder in all of our samples. FTIR spectroscopy measurements showed that the carrier density and scattering time had little sample-to-sample variation or temperature dependence for near-stoichiometric samples. FTIR and DC resistivity suggest that the transport properties of Fe{sub 2}VAl are influenced by both localized and delocalized carriers, with the former primarily responsible for the negative temperature coefficient of resistivity. Magnetization measurements reveal that near-stoichiometric samples have superparamagnetic clusters with at least two sizes of moments. X-ray photoemission from Fe core level showed localized magnetic moments on site-exchanged Fe. They conclude that in Fe{sub 2}VAl, antisite disorder causes significant modification to the semi-metallic band structure proposed by LDA calculations. With antisite disorder considered, they are now able to explain most of the physical properties of Fe{sub 2}VAl.

Ye Feng

2002-05-30T23:59:59.000Z

262

Accelerated decarburization of Fe-C metal alloys  

DOE Patents [OSTI]

A process is described for improving the rate of metal production and FeO utilization in a steelmaking process or a process combining iron-making and steelmaking in a single reactor that uses or generates Fe-C metal alloy droplets submerged in an FeO-containing slag. The process involves discharging a charge build-up (electron accumulation) in the slag at the slag-metal alloy interface by means of an electron conductor connected between the metal alloy droplets and a gas at a gas-slag interface, said gas having an oxygen partial pressure of at least about 0.01 atmosphere. 2 figs.

Pal, U.B.; Sadoway, D.R.

1997-05-27T23:59:59.000Z

263

Accelerated decarburization of Fe-C metal alloys  

DOE Patents [OSTI]

A process for improving the rate of metal production and FeO utilization in a steelmaking process or a process combining iron-making and steelmaking in a single reactor that uses or generates Fe-C metal alloy droplets submerged in an FeO-containing slag. The process involves discharging a charge build-up (electron accumulation) in the slag at the slag-metal alloy interface by means of an electron conductor connected between the metal alloy droplets and a gas at a gas-slag interface, said gas having an oxygen partial pressure of at least about 0.01 atmosphere.

Pal, Uday B. (Needham, MA); Sadoway, Donald R. (Belmont, MA)

1997-01-01T23:59:59.000Z

264

Fluorescence of [Fe II] in H II regions  

E-Print Network [OSTI]

A study of [Fe II] lines at various positions within the H II regions M42 and M43 is presented. The relative intensities of selected optical [Fe II] lines are shown to be correlated with the intensity of the apparent nebular continuous spectrum. Since the continuum of H II regions is known to be mostly stellar radiation scattered by dust intermixed with the emitting gas, these correlations provide direct evidence for the existence of fluorescent excitation in the formation process of the [Fe II] lines, irrespective of the prevailing physical state.

M. Rodriguez

1999-06-17T23:59:59.000Z

265

Pulsed-electron-beam melting of Fe  

SciTech Connect (OSTI)

Pulsed (50 nsec) electron beams with deposited energies of 1.1 to 2.3 J/cm/sup 2/ have been used to rapidly melt a surface layer of Fe. Calculations show that this range of energies produces melt depths from 0.4 to 1.2 ..mu..m and melt times of 100 to 500 nsec. Optical microscopy and SEM of pulse treated polycrystalline foils show slip traces, as well as a general smoothing of surface features which shows that melting has occurred. TEM shows that the resolidified material is bcc, and that the material within a grain is epitaxial with the substrate. TEM also shows slip traces along (110) planes, as well as a high density of dislocations, both extended and loop. At the highest energy, subgrain boundaries are observed. Some samples were implanted with 1 x 10/sup 16/ Sn/cm/sup 2/ at 150 keV. After pulse treatment, the Sn depth profile was observed to have broadened, consistent with liquid phase diffusion. The Sn had the unexpected effect of suppressing slip at the sample surface.

Knapp, J.A.; Follstaedt, D.M.

1981-01-01T23:59:59.000Z

266

Clean Energy- FE Dkt No. 14-54-LNG (FTA)  

Broader source: Energy.gov [DOE]

The Office of Fossil Energy (FE) of the Department of Energy (DOE) gives notice of receipt of an application filed on March 18, 2014, by Clean Energy, requesting blanket authorization to engage in...

267

fe0013531-Oregon-State | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Assessing the Response of Methane Hydrates to Environmental Change at the Svalbad Continental Margin Last Reviewed 152015 DE-FE0013531 Goal The goal of this project is to study...

268

Hydrogen-Vacancy Interactions in Fe-C Alloys  

E-Print Network [OSTI]

Energetics and concentrations of hydrogen-containing point defect clusters (PDCs) in Fe-C alloys are calculated and cast into a PDC dominance diagram. Because of the strong binding effects of iron vacancies on the stability ...

Yip, Sidney

269

A nuclear magnetic resonance probe of Fe-Al and Al20V2Eu intermetallics  

E-Print Network [OSTI]

Al-rich Fe-Al systems (FeAl2, Fe2 Al5 and Fe4Al13) and Al20V2Eu have complicated structures with quasicrystal-like features making these materials potentially of interest for magnetic behavior. However, there is not much work on these materials...

Chi, Ji

2009-05-15T23:59:59.000Z

270

Determination of the stellar (n,$\\gamma$) cross section of $^{54}Fe$ with accelerator mass spectrometry  

E-Print Network [OSTI]

Determination of the stellar (n,$\\gamma$) cross section of $^{54}Fe$ with accelerator mass spectrometry

Coquard, L; Dillmann, I; Wallner, A; Knie, K; Kutschera, W

2006-01-01T23:59:59.000Z

271

Demonstration of Security Benefits of Renewable Generation at FE Warren Air Force Base  

SciTech Connect (OSTI)

Report detailing field demonstration of security benefits of renewable generation at FE Warren Air Force Base.

Warwick, William M.; Myers, Kurt; Seifert, Gary

2010-12-31T23:59:59.000Z

272

Mössbauer investigations of hyperfine interactions features of {sup 57}Fe nuclei in BiFeO{sub 3} ferrite  

SciTech Connect (OSTI)

New results of {sup 57}Fe Mössbauer studies on BiFeO{sub 3} powder sample performed at various temperatures above and below magnetic phase transitions point T{sub N} ? 640K are reported. We have performed self-consistent calculations of the lattice contributions to the EFG tensor, taking into account dipole moments of the O{sup 2?} and Bi{sup 3+} ions. Low-temperature {sup 57}Fe Mössbauer spectra recorded at T < T{sub N} were analyzed assuming an anharmonic cycloidal modulation of the Fe{sup 3+} magnetic moments. The cycloidal modulation of the iron spin was described with the elliptic Jacobi function sn[(±4K(m)/?)x,m]. The good fit of the experimental spectra was obtained for the anharmonicity m = 0.44 ± 0.04 (T = 4.9K) resulting from the easy-axis magnetic anisotropy.

Sobolev, Alexey, E-mail: salex12@rambler.ru; Presniakov, Igor, E-mail: salex12@rambler.ru; Rusakov, Vyacheslav, E-mail: salex12@rambler.ru; Matsnev, Mikhail; Gorchakov, Dmitry; Glazkova, Iana [Lomonosov Moscow State University, 119991, Moscow (Russian Federation); Belik, Alexey [International Center for Materials Nanoarchitectonics (MANA), National Institute for Material Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044 (Japan)

2014-10-27T23:59:59.000Z

273

Atom probe: a direct technique for kinetic measurements. [Fe-24Cr; Fe-32Cr; Fe-28. 5Cr-10. 6Co  

SciTech Connect (OSTI)

The atom probe has been used to study the phase transformations occurring within the low-temperature miscibility gaps in Fe-Cr and Fe-Cr-Co alloys. The morphology of the two-phase microstructure resulting from phase separation deep within the miscibility gaps was found to be highly interconnected and charactristic of an isotropic spinodal reaction. The characteristic dimensions of the microstructure and the changes in composition were measured as a function of aging. The coarsening of the network structures could be fitted with a power law with time exponents that were significantly less than the classical Lifshitz-Slyozov-Wagner value of one-third.

Miller, M.K.; Brenner, S.S.; Camus, P.P.; Soffa, W.A.

1984-04-04T23:59:59.000Z

274

Lightest Isotope of Bh Produced Via the 209Bi(52Cr,n)260Bh Reaction  

E-Print Network [OSTI]

models. For many years, “cold fusion” reactions utilizingproduced via the new “cold fusion” reaction 209 Bi( 52 Cr,

2007-01-01T23:59:59.000Z

275

Crystal structure, magnetism and transport properties of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10}  

SciTech Connect (OSTI)

Single crystals of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10} were obtained from a process in which a polycrystalline sample of CeRu{sub 2}Al{sub 2}B was annealed in an excess of a Ni–In flux. The initial phase, CeRu{sub 2}Al{sub 2}B, does not recrystallize, instead, crystals of a new phase, Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10}, could be isolated once the flux was removed. The title compound crystallizes in the tetragonal space group P4/nmm (No. 129) with a=1139.02(8), c=801.68(6) pm (c/a=0.70) in the Nd{sub 3}Ni{sub 29}Si{sub 4}B{sub 10} structure type. Electrical resistivity measurements reveal metallic behavior with a minimum of 700 µ? cm and a small residual resistivity ratio of RRR=1.4 indicating a large amount of disorder scattering. The cerium atoms are either in the 4+ or an intermediate valence state with a valence fluctuation temperature far above room temperature. - Graphical abstract: Single crystals of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}A{sub l4.1}B{sub 10} were obtained using a process in which a polycrystalline sample of CeRu{sub 2}Al{sub 2}B was annealed in an excess of a Ni–In flux. Electrical resistivity measurements reveal metallic behavior with a minimum of 700 ?? cm and a small residual resistivity ratio of RRR=1.4 indicating a large amount of disorder scattering. The cerium atoms are either in the 4+ or an intermediate valence state with a valence fluctuation temperature far above room temperature. Display Omitted - Highlights: • Flux synthesis of high quality single crystals of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10} is presented along with the crystal structure, magnetic and transport properties. • The compound is isostructural to Nd{sub 3}Ni{sub 29}Si{sub 4}B{sub 10} but is first of this structure type showing mixed occupancies of d-elements. • This is an intermetallic phase with Ce in either the 4+ or an intermediate valence state. • The fact that this structure with mixed occupied transition metal sites exists suggests that more compounds of this type should be accessible and the physical properties tuned.

Janka, Oliver [Department of Chemistry, University of California, One Shields Ave, Davis, CA 95616 (United States); Baumbach, Ryan E.; Thompson, Joe D. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Bauer, Eric D., E-mail: edbauer@lanl.gov [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Kauzlarich, Susan M., E-mail: smkauzlarich@ucdavis.edu [Department of Chemistry, University of California, One Shields Ave, Davis, CA 95616 (United States)

2013-09-15T23:59:59.000Z

276

Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative dehydrogenation with N2O and N2O decomposition  

E-Print Network [OSTI]

Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative species Steamed Fe-zeolites Mössbauer spectroscopy UV­Vis FTIR H2-TPR N2O decomposition Propane oxidative of propane to propene with N2O. The evacuated non-steamed FeH-ZSM-5 contained high concentration of Brønsted

Sklenak, Stepan

277

PHYSICAL REVIEW B 83, 104526 (2011) Fe Mossbauer study of magnetic ordering in superconducting K0.80Fe1.76Se2.00 single crystals  

E-Print Network [OSTI]

PHYSICAL REVIEW B 83, 104526 (2011) 57 Fe M¨ossbauer study of magnetic ordering in superconducting 31 March 2011) The magnetic ordering of superconducting single crystals of K0.80Fe1.76Se2.00 has been studied between 10 and 550 K using 57 Fe M¨ossbauer spectroscopy. Despite being superconducting below Tsc

Ryan, Dominic

2011-01-01T23:59:59.000Z

278

N2s2 chelating agents as cys-x-cys biomimics for fe(no) and fe(no)2 complexes  

E-Print Network [OSTI]

model complexes I have examined the fundamental properties of a dithiolato-Fe(NO)2 complex, bismercaptoethandiazacyclooctane iron dinitrosyl or (H+bme-daco)Fe(NO)2 as a biomimic of dicysteinate coordination of [Fe(NO)2]. This complex was prepared...

Chiang, Chao-Yi

2006-08-16T23:59:59.000Z

279

Abiotic U(VI) Reduction by Sorbed Fe(II) on Natural Sediments  

SciTech Connect (OSTI)

Laboratory experiments were performed as a function of aqueous Fe(II) concentration to determine the uptake and oxidation of Fe(II), and Fe(II)-mediated abiotic reduction of U(VI) by aquifer sediments from the Rifle IFRC field site in Colorado, USA. Mössbauer analysis of the sediments spiked with aqueous 57Fe(II) showed that 57Fe(II) was oxidized on the mineral surfaces to 57Fe(III) and most likely formed a nano-particulate Fe(III)-oxide or ferrihydrite-like phase. The extent of 57Fe oxidation decreased with increasing 57Fe(II) uptake, such that 100 % was oxidized at 7.3 ?mol/g Fe and 52 % at 39.6 ?mol/g Fe, indicating that the sediments had a finite capacity for oxidation of Fe(II). Abiotic U(VI) reduction was observed by XANES spectroscopy only when the Fe(II) uptake was greater than approximately 20 ?mol/g and surface-bound Fe(II) was present. The level of U(VI) reduction increased with increasing Fe(II)- loading above this level to a maximum of 18 and 36 % U(IV) at pH 7.2 (40.7 ?mol/g Fe) and 8.3 (56.1 ?mol/g Fe), respectively in the presence of 400 ppm CO2. Greater U(VI) reduction was observed in CO2 free systems [up to 44 and 54 % at pH 7.2 (17.3 ?mol/g Fe) and 8.3 (54.8 ?mol/g Fe), respectively] compared to 400 ppm CO2 systems, presumably due to differences in aqueous U(VI) speciation. While pH affects the amount of Fe(II) uptake onto the solid phase, with greater Fe(II) uptake at higher pH, similar amounts of U(VI) reduction were observed at pH 7.2 and 8.3 for a similar Fe(II) uptake. Thus, it appears that abiotic U(VI) reduction is controlled primarily by Fe(II) concentration and aqueous U(VI) speciation. The range of Fe(II) loadings tested in this study are within the range observed in bioreduced sediments, suggesting that Fe(II)-mediated abiotic U(VI) reduction may indeed play a role in field settings.

Fox, Patricia M.; Davis, James A.; Kukkadapu, Ravi K.; Singer, David M.; Bargar, John R.; Williams, Kenneth H.

2013-09-15T23:59:59.000Z

280

Anomalous codeposition of Fe-Ni alloys and Fe-Ni-SiO{sub 2} composites under potentiostatic conditions: Experimental study and mathematical model  

SciTech Connect (OSTI)

A mathematical model has been developed to describe the electrodeposition of Fe-Ni alloys and Fe-Ni-SiO{sub 2} composites under potentiostatic conditions. This model can be used to predict the polarization behavior, partial current densities, and alloy composition of each of the components as a function of the applied potential. Fe-Ni-SiO{sub 2} samples were deposited on platinum rotating disk electrodes from sulfate electrolytes under potentiostatic conditions, and the results obtained were compared to the model. The model predictions were found to agree well with the experimental observations for the Fe-Ni and Fe-Ni-SiO{sub 2} systems.

Ramasubramanian, M.; Popova, S.N.; Popov, B.N.; White, R.E. [Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemical Engineering; Yin, K.M. [Yuan-Ze Inst. of Tech., Taoyuan (Taiwan, Province of China)

1996-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Single-crystal epitaxial thin films of SrFeO{sub 2} with FeO{sub 2} 'infinite layers'  

SciTech Connect (OSTI)

Single-crystal thin films of SrFeO{sub 2}, which is an oxygen-deficient perovskite with ''infinite layers'' of Fe{sup 2+}O{sub 2}, were prepared by using CaH{sub 2} for low-temperature reduction of epitaxial SrFeO{sub 2.5} single-crystal films deposited on KTaO{sub 3} substrates. This reduction process, removing oxygen ions from the perovskite structure framework and causing rearrangements of oxygen ions, topotactically transforms the brownmillerite SrFeO{sub 2.5} to the c-axis oriented SrFeO{sub 2}.

Inoue, Satoru; Kawai, Masanori; Shimakawa, Yuichi [Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan); Mizumaki, Masaichiro; Kawamura, Naomi [Japan Synchrotron Radiation Research Institute/SPring-8, Sayo, Hyogo 679-5198 (Japan); Watanabe, Takashi; Tsujimoto, Yoshihiro; Kageyama, Hiroshi; Yoshimura, Kazuyoshi [Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502 (Japan)

2008-04-21T23:59:59.000Z

282

Synthesis and characterization of Fe(III)-silicate precipitation tubes  

SciTech Connect (OSTI)

Fe(III)-silicate precipitation tubes synthesized through 'silica garden' route have been characterized using a number of analytical techniques including X-ray diffraction, infrared spectroscopy, atomic force microscopy, scanning and transmission electron microscopy. These tubes are brittle and amorphous and are hierarchically built from smaller tubes of 5-10 nm diameters. They remain amorphous at least up to 650 {sup o}C. Crystobalite and hematite are the major phases present in Fe(III)-silicate tubes heated at 850 {sup o}C. Morphology and chemical compositions at the external and internal walls of these tubes are remarkably different. These tubes are porous with high BET surface area of 291.2 m{sup 2}/g. Fe(III)-silicate tubes contain significant amount of physically and chemically bound moisture. They show promise as an adsorbent for Pb(II), Zn(II), and Cr(III) in aqueous medium.

Parmar, K.; Pramanik, A.K. [National Metallurgical Laboratory, Council of Scientific and Industrial Research, Burmamines, Jamshedpur 831007 (India)] [National Metallurgical Laboratory, Council of Scientific and Industrial Research, Burmamines, Jamshedpur 831007 (India); Bandyopadhya, N.R. [Bengal Engineering and Science University, Shibpur, Howrah 711103 (India)] [Bengal Engineering and Science University, Shibpur, Howrah 711103 (India); Bhattacharjee, S., E-mail: santanu@nmlindia.org [National Metallurgical Laboratory, Council of Scientific and Industrial Research, Burmamines, Jamshedpur 831007 (India)

2010-09-15T23:59:59.000Z

283

Bimetallic Fe-Ni Oxygen Carriers for Chemical Looping Combustion  

SciTech Connect (OSTI)

The relative abundance, low cost, and low toxicity of iron make Fe-based oxygen carriers of great interest for chemical looping combustion (CLC), an emerging technology for clean and efficient combustion of fossil and renewable fuels. However, Fe also shows much lower reactivity than other metals (such as Ni and Cu). Here, we demonstrate strong improvement of Fe-based carriers by alloying the metal phase with Ni. Through a combination of carrier synthesis and characterization with thermogravimetric and fixed-bed reactor studies, we demonstrate that the addition of Ni results in a significant enhancement in activity as well as an increase in selectivity for total oxidation. Furthermore, comparing alumina and ceria as support materials highlights the fact that reducible supports can result in a strong increase in oxygen carrier utilization.

Bhavsar, Saurabh; Veser, Goetz

2013-11-06T23:59:59.000Z

284

Fe/Al2O3 C2H4 Hata mm/10 min  

E-Print Network [OSTI]

Fe/Al2O3 C2H4 () () () () () () () * () 1. (SWNT) SWNT (CVD) (CNT)[1] Hata mm/10 min SWNT (Super Growth)[2]Al2O3 Fe C2H4 SWNT Fe/Al2O3 C2H4 CVD SWNT CNT CNT 2 SiO2 Al2O3 20 (RBM) 1350 cm-1 (D-Band)Fe G/D RBM Fe SWNT Al 15 nm Fe 0.6 nm CVD TEM Fig. 3 3 nm SWNT

Maruyama, Shigeo

285

Iron-phosphorus relationships in Fe chlorisis of sorghum  

E-Print Network [OSTI]

IRON-PHOSPHORUS RELATIONSHIPS IN FE CHLOROSIS OF SORGHUM A Thesis by DENNIS A. MORALES-VARGAS Submitted to the Graduate College of Texas A8M University in partial fulfillment of the requirement for the degree of MASl'ER OF SCIENCE December... 1979 Major Subject: Soil Science IRON-PHOSPHORUS RELATIONSHIPS IN FE CHLOROSI OF SORGHUM A Thesis by DENNIS A. MORALES-VARGAS Approved as to style and content by: \\ J(c'w"H~. v& 4 Cc ~. r&'4 wc' c "&"~ / ~Chairman of Committee ! ~Co-' hai...

Morales-Vargas, Dennis A

1979-01-01T23:59:59.000Z

286

First analysis of eight Algol-type systems: V537 And, GS Boo, AM CrB, V1298 Her, EL Lyn, FW Per, RU Tri, and WW Tri  

E-Print Network [OSTI]

Analyzing available photometry from the Super WASP and other databases, we performed the very first light curve analysis of eight eclipsing binary systems V537 And, GS Boo, AM CrB, V1298 Her, EL Lyn, FW Per, RU Tri, and WW Tri. All of these systems were found to be detached ones of Algol-type, having the orbital periods of the order of days. 722 new times of minima for these binaries were derived and presented, trying to identify the period variations caused by the third bodies in these systems.

Zasche, P

2014-01-01T23:59:59.000Z

287

Magnetism of NiMn2O4-Fe3O4 spinel interfaces  

E-Print Network [OSTI]

Magnetism of NiMn 2 O 4 –Fe 3 O 4 spinel interfaces B. B.2. Element-specific magnetism of Fe 3 O 4 /NMO interface inin these structures, 6 the magnetism near the isostructural

Nelson-Cheeseman, B. B.

2007-01-01T23:59:59.000Z

288

UV spectra of iron-doped carbon clusters FeC_n n = 3-6  

E-Print Network [OSTI]

Electronic transitions of jet-cooled FeC$_n$ clusters ($n = 3 - 6$) were measured between 230 and 300 nm by a mass-resolved 1+1 resonant two-photon ionization technique. Rotational profiles were simulated based on previous calculations of ground state geometries and compared to experimental observations. Reasonable agreement is found for the planar fan-like structure of FeC$_3$. The FeC$_4$ data indicate a shorter distance between the Fe atom and the bent C$_4$ unit of the fan. The transitions are suggested to be $^{3}$A$_{2} \\leftarrow ^{3}$B$_{1}$ for FeC$_3$ and $^{5}$A$_{1} \\leftarrow ^{5}$A$_{1}$ for FeC$_4$. In contrast to the predicted C$_{\\infty \\text{v}}$ geometry, non-linear FeC$_5$ is apparently observed. Line width broadening prevents analysis of the FeC$_6$ spectrum.

Steglich, Mathias; Johnson, Anatoly; Maier, John P

2015-01-01T23:59:59.000Z

289

The Utility of FeVO4 in Combination with Stabilized Titanias...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR Application The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR Application...

290

Analysis of Fe Nanoparticles Using XPS Measurements Under D.C...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fe Nanoparticles Using XPS Measurements Under D.C. or Pulsed-Voltage Bias. Analysis of Fe Nanoparticles Using XPS Measurements Under D.C. or Pulsed-Voltage Bias. Abstract: The...

291

Kinetics of Reduction of Fe(III) Complexes by Outer Membrane...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fe(III) Complexes by Outer Membrane Cytochromes MtrC and OmcA of Shewanella oneidensis MR-1. Kinetics of Reduction of Fe(III) Complexes by Outer Membrane Cytochromes MtrC and OmcA...

292

A MOSSBAUER STUDY OF AUSTENITE STABILITY AND IMPACT FRACTURE IN Fe - 6 Ni STEEL  

E-Print Network [OSTI]

IMPACT FRACTURE IN Fe-6Ni STEEL Brent Thomas Fultz Materialscommercial cryogenic alloy steel was studied with regard toThe Experiments Fe-6Ni-lMn steel plate was received from the

Fultz, Brent

2011-01-01T23:59:59.000Z

293

WELDABILITY OF GRAIN-REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS  

E-Print Network [OSTI]

of the Cryogenic Nickel Steels, WRC Bull, 205, May, 1975.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.E.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.

Morris Jr., J.W.

2013-01-01T23:59:59.000Z

294

Co-synthesis of LiFePO4 and Carbon Nanotubes  

E-Print Network [OSTI]

of LiFePO 4 and carbon nanotubes potentially bypassessynthesis of LiFePO 4 and Carbon Nanotubes James Wilcox* ,†that multi-walled carbon nanotubes (MWCNTs, Figure 1) and

Wilcox, James; Doeff, Marca M.

2006-01-01T23:59:59.000Z

295

Charge transport in micas: The kinetics of FeII/III electron...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

transport in micas: The kinetics of FeIIIII electron transfer in the octahedral sheet. Charge transport in micas: The kinetics of FeIIIII electron transfer in the octahedral...

296

An Ab Initio Model of Electron Transport in Hematite (a-Fe2O3...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

An Ab Initio Model of Electron Transport in Hematite (a-Fe2O3) Basal Planes. An Ab Initio Model of Electron Transport in Hematite (a-Fe2O3) Basal Planes. Abstract: Transport of...

297

Accelerated Thermal Aging of Fe-Zeolite SCR Catalysts Using an...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermal Aging of Fe-Zeolite SCR Catalysts Using an Engine-Based Systems Approach Accelerated Thermal Aging of Fe-Zeolite SCR Catalysts Using an Engine-Based Systems Approach This...

298

Heterogeneous Reduction of U6+ by Structural Fe2+ From Theory...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

single crystals of magnetite with different initial Fe2+Fe3+ ratios were exposed to uranyl-nitrate solution (pH 4) for 90 hours. X ray photoelectron spectroscopy and...

299

SEMI-ANNUAL REPORTS FOR LAKE CHARLES EXPORTS, LLC - FE DKT. NO...  

Broader source: Energy.gov (indexed) [DOE]

LAKE CHARLES EXPORTS, LLC - FE DKT. NO. 11-59-LNG - ORDER 3324 SEMI-ANNUAL REPORTS FOR LAKE CHARLES EXPORTS, LLC - FE DKT. NO. 11-59-LNG - ORDER 3324 October 2013 April 2014...

300

Bear Head LNG Corporation and Bear Head LNG (USA), LLC - FE Dkt...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Bear Head LNG Corporation and Bear Head LNG (USA), LLC - FE Dkt. No. - 15-33-LNG Bear Head LNG Corporation and Bear Head LNG (USA), LLC - FE Dkt. No. - 15-33-LNG The Office of...

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 | Department...  

Broader source: Energy.gov (indexed) [DOE]

CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 No reports submitted for this docket. More Documents & Publications...

302

Optical absorption and band gap reduction in (Fe1-xCrx)2O3 solid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optical absorption and band gap reduction in (Fe1-xCrx)2O3 solid solutions: A first-principles study. Optical absorption and band gap reduction in (Fe1-xCrx)2O3 solid solutions: A...

303

Excited Carrier Dynamics of ?-Cr2O3/?-Fe2O3 Core...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Excited Carrier Dynamics of ?-Cr2O3?-Fe2O3 Core-Shell Nanostructures. Abstract: In this work ?-Cr2O3?-Fe2O3 core-shell polycrystalline...

304

Electronic Structure and Fragmentation Properties of[Fe4S4(SEt...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abstract: A limited exposure of (n-Bu4N)2Fe4S4(SEt)4 solutions in acetonitrile to air was found to produce a new series of 4Fe-4S cluster complexes,...

305

Carrier Dynamics in a-Fe2O3 (0001) Thin Films and Single Crystals...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carrier Dynamics in a-Fe2O3 (0001) Thin Films and Single Crystals Probed by Femtosecond Transient Absorption and Reflectivity. Carrier Dynamics in a-Fe2O3 (0001) Thin Films and...

306

Effects of Laser Energy and Wavelength on the Analysis of LiFePO4...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Laser Energy and Wavelength on the Analysis of LiFePO4 Using Laser Assisted Atom Probe Tomography. Effects of Laser Energy and Wavelength on the Analysis of LiFePO4 Using Laser...

307

Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phasehydrodeoxy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol. Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of...

308

Important role of the non-uniform Fe distribution for the ferromagnetism in group-IV-based ferromagnetic semiconductor GeFe  

SciTech Connect (OSTI)

We investigate the growth-temperature dependence of the properties of the group-IV-based ferromagnetic semiconductor Ge{sub 1?x}Fe{sub x} films (x?=?6.5% and 10.5%), and reveal the correlation of the magnetic properties with the lattice constant, Curie temperature (T{sub C}), non-uniformity of Fe atoms, stacking-fault defects, and Fe-atom locations. While T{sub C} strongly depends on the growth temperature, we find a universal relationship between T{sub C} and the lattice constant, which does not depend on the Fe content x. By using the spatially resolved transmission-electron diffractions combined with the energy-dispersive X-ray spectroscopy, we find that the density of the stacking-fault defects and the non-uniformity of the Fe concentration are correlated with T{sub C}. Meanwhile, by using the channeling Rutherford backscattering and particle-induced X-ray emission measurements, we clarify that about 15% of the Fe atoms exist on the tetrahedral interstitial sites in the Ge{sub 0.935}Fe{sub 0.065} lattice and that the substitutional Fe concentration is not correlated with T{sub C}. Considering these results, we conclude that the non-uniformity of the Fe concentration plays an important role in determining the ferromagnetic properties of GeFe.

Wakabayashi, Yuki K.; Ohya, Shinobu; Ban, Yoshisuke; Tanaka, Masaaki [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

2014-11-07T23:59:59.000Z

309

ELECTRON-CAPTURE SUPERNOVAE AS SOURCES OF {sup 60}Fe  

SciTech Connect (OSTI)

We investigate the nucleosynthesis of the radionuclide {sup 60}Fe in electron-capture supernovae (ECSNe). The nucleosynthetic results are based on a self-consistent, two-dimensional simulation of an ECSN as well as models in which the densities are systematically increased by some factors (low-entropy models). {sup 60}Fe is found to be appreciably made in neutron-rich ejecta during the nuclear quasi-equilibrium phase with greater amounts being produced in the lower-entropy models. Our results, combining them with the yields of core-collapse supernovae in the literature, suggest that ECSNe account for at least 4%-30% of live {sup 60}Fe in the Milky Way. ECSNe co-produce neutron-rich isotopes, {sup 48}Ca, {sup 50}Ti, {sup 54}Cr, some light trans-iron elements, and possibly weak r-process elements including some radionuclides such as {sup 93}Zr, {sup 99}Tc, and {sup 107}Pd, whose association with {sup 60}Fe might have been imprinted in primitive meteorites or in the deep ocean crust on the Earth.

Wanajo, Shinya [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Janka, Hans-Thomas; Mueller, Bernhard, E-mail: shinya.wanajo@nao.ac.jp [Max-Planck-Institut fuer Astrophysik, Karl-Schwarzschild-Str. 1, D-85748 Garching (Germany)

2013-09-01T23:59:59.000Z

310

The Effects of Fe3+ Aluminum Silicate Phase Relations in  

E-Print Network [OSTI]

The Effects of Fe3+ and Mn3+ on Aluminum Silicate Phase Relations in North-Central New Mexico, U, New Mexico 87131 (Received 28 November 1983; in revised form 2 October 1984) ABSTRACT Aluminum, then their equilibrium coexistence is invariant. However, the aluminum silicate minerals are not pure in highly oxidized

Lee, Cin-Ty Aeolus

311

Equation of state and phase diagram of FeO  

SciTech Connect (OSTI)

Wuestite, Fe{sub 1-x}O, is an important component in the mineralogy of Earth's lower mantle and may also be a component in the core. Therefore the high pressure, high temperature behavior of FeO, including its phase diagram and equation of state, is essential knowledge for understanding the properties and evolution of Earth's deep interior. We performed X-ray diffraction measurements using a laser-heated diamond anvil cell to achieve simultaneous high pressures and temperatures. Wuestite was mixed with iron metal, which served as our pressure standard, under the assumption that negligible oxygen dissolved into the iron. Our data show a positive slope for the subsolidus phase boundary between the B1 and B8 structures, indicating that the B1 phase is stable at the P-T conditions of the lower mantle and core. We have determined the thermal equation of state of B1 FeO to 156 GPa and 3100 K, finding an isothermal bulk modulus K{sub 0} = 149.4 {+-} 1.0 GPa and its pressure derivative K'{sub 0} = 3.60 {+-} 0.4. This implies that 7.7 {+-} 1.1 wt.% oxygen is required in the outer core to match the seismologically-determined density, under the simplifying assumption of a purely Fe-O outer core.

Fischer, Rebecca A.; Campbell, Andrew J.; Shofner, Gregory A.; Lord, Oliver T.; Dera, Przemyslaw; Prakapenka, Vitali B. (Bristol); (Maryland); (UC)

2012-04-11T23:59:59.000Z

312

Structural and Mössbauer spectroscopic study of Fe-Ni alloy nanoparticles  

SciTech Connect (OSTI)

Nano-crystalline Fe-Ni alloys have been synthesized in ethylene glycol medium. Based on XRD studies it is confirmed that, in these alloys Fe atoms are incorporated at Ni site to form Ni-Fe solid solutions. Mössbauer studies have established that for alloy particles having smaller size there is significant concentration of two different types of paramagnetic Fe species and their relative concentration decreased with increase in particle size.

Kumar, Asheesh; Banerjee, S., E-mail: vsudar@barc.gov.in; Sudarsan, V., E-mail: vsudar@barc.gov.in [Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085 (India); Meena, S. S. [Solid State Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085 (India)

2014-04-24T23:59:59.000Z

313

High strength-high conductivity Cu--Fe composites produced by powder compaction/mechanical reduction  

DOE Patents [OSTI]

A particulate mixture of Cu and Fe is compacted and mechanically reduced to form an "in-situ" Cu-Fe composite having high strength and high conductivity. Compaction and mechanical reduction of the particulate mixture are carried out at a temperature and time at temperature selected to avoid dissolution of Fe into the Cu matrix particulates to a harmful extent that substantially degrades the conductivity of the Cu-Fe composite.

Verhoeven, John D. (Ames, IA); Spitzig, William A. (Ames, IA); Gibson, Edwin D. (Ames, IA); Anderson, Iver E. (Ames, IA)

1991-08-27T23:59:59.000Z

314

High-pressure phases of FeTiO3 from first principles N. C. Wilson  

E-Print Network [OSTI]

2005; published 19 July 2005 The structural, elastic, and electronic properties of the high-pressure Fe and their interaction with the structural degrees of freedom. Ilmenite, the mineral form of FeTiO3, is commonly found of diamond deposits.2 In addition to ilmenite, two other polymorphs of FeTiO3 are known,3 namely, the lithium

315

Highpressure behavior of iron carbide (Fe7C3) at inner core conditions  

E-Print Network [OSTI]

Highpressure behavior of iron carbide (Fe7C3) at inner core conditions Mainak Mookherjee,1 Yoichi at high pressures have demonstrated that Fe7C3 iron carbide is a likely candidate for the Earth's inner behavior of iron carbide (Fe7C3) at inner core conditions, J. Geophys. Res., 116, B04201, doi:10

Steinle-Neumann, Gerd

316

Hydrothermal synthesis, off-axis electron holography and magnetic properties of Fe3O4 nanoparticles  

E-Print Network [OSTI]

-sized Fe3O4 have been prepared by various methods such as sol­ gel processing, hydrothermal synthesisHydrothermal synthesis, off-axis electron holography and magnetic properties of Fe3O4 nanoparticles Jülich, Germany. Abstract. The hydrothermal synthesis of Fe3O4 nanoparticles (NPs) (

Dunin-Borkowski, Rafal E.

317

Characterization of Zr-Fe-Cu Alloys for an Inert Matrix Fuel for Nuclear Energy Applications  

E-Print Network [OSTI]

Cu had the largest melting temperature (886.3°C) while Zr-12Fe-10Cu had the smallest melting temperature (870°C). The third alloy, Zr-12Fe-15Cu, had a melting point just below that of Zr-12Fe-5Cu at 882.7°C. Light Flash Analysis (LFA...

Barnhart, Brian A.

2013-08-09T23:59:59.000Z

318

A synthesis of LiFePO{sub 4} starting from FePO{sub 4} under reducing atmosphere  

SciTech Connect (OSTI)

A fast and easy way to produce LiFePO{sub 4} starting from FePO{sub 4}, used as iron and phosphorus source, is proposed. 5% hydrogen is employed as a reducing agent and various compounds containing lithium as lithiation agents. The selected lithiation agents included: LiCl, CH{sub 3}COOLi, LiOH, Li{sub 2}S, LiH, and Li{sub 2}CO{sub 3}. Solid state synthesis is used for the LiFePO{sub 4} preparation and the so obtained materials are structurally characterized by XRD. The materials are used to fabricate composite electrode and their specific capacity is evaluated by low rate galvanostatic charge/discharge cycles (C/10 rate). Among the various lithium salts, the acetate give rise to the LiFePO{sub 4} with the best electrochemical performance. The morphology of this material is further investigated by SEM microscopy and the specific capacity is evaluated as a function of the discharge rate and the cycle number.

Prosini, Pier Paolo [ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria di Galeria, Rome, Italy and DInESto, Drive the Innovation in Energy Storage, Via Provin (Italy); Cento, Cinzia; Masci, Amedeo; Carewska, Maria; Gislon, Paola [ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria di Galeria, Rome (Italy)

2014-06-19T23:59:59.000Z

319

The importance of holes in aluminium tris-8-hydroxyquinoline (Alq{sub 3}) devices with Fe and NiFe contacts  

SciTech Connect (OSTI)

To study the dominant charge carrier polarity in aluminium tris-8-hydroxyquinoline (Alq{sub 3}) based spin valves, single Alq{sub 3} layer devices with NiFe, ITO, Fe, and aluminium electrodes were fabricated and characterised by Time of Flight (ToF) and Dark Injection (DI) techniques, yielding a lower hole mobility compared to electron mobility. We compare the mobility measured by DI for the dominant carrier injected from NiFe and Fe electrodes into Alq{sub 3}, to that of holes measured by ToF. This comparison leads us to conclude that the dominant charge carriers in Alq{sub 3} based spin valves with NiFe or Fe electrodes are holes.

Zhang, Hongtao; Desai, P.; Kreouzis, T. [Materials Research Institute, School of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom)] [Materials Research Institute, School of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom); Zhan, Y. Q. [Materials Research Institute, School of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom) [Materials Research Institute, School of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom); State Key Laboratory of ASIC and System, Department of Microelectronics, SIST, Fudan University, Shanghai 200433 (China); Drew, A. J. [Materials Research Institute, School of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom) [Materials Research Institute, School of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom); College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China); Gillin, W. P. [Materials Research Institute, School of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom) [Materials Research Institute, School of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E1 4NS (United Kingdom); State Key Laboratory of ASIC and System, Department of Microelectronics, SIST, Fudan University, Shanghai 200433 (China); College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China)

2014-01-06T23:59:59.000Z

320

Identification of an incommensurate FeAl{sub 2} overlayer on FeAl(110) using x-ray diffraction and reflectivity  

SciTech Connect (OSTI)

FeAl, like NiAl, crystallizes in the CsCl structure. Consequently the (110) planes contain equal amounts of Fe and Al distributed as interlocking rectangles. Unlike the NiAI(110) surface, which retains the (1{times}l) in-plane symmetry of the bulk, FeAl(l10) reconstructs to form an ordered, incommensurate overlayer. The reconstructed layer introduces x-ray diffraction rods at half-order positions along the [1{bar 1}0] direction, and displaced {plus_minus}0.2905 from integer positions along the [001] direction. Peak widths reveal excellent long range order. Specular reflectivity measurements above and below the Fe K{alpha} edge can be reproduced using a model containing a single reconstructed overlayer with an Fe:Al ratio of 1:2, consistent with FeA{sub I}2.

Baddorf, A.P. [Oak Ridge National Lab., TN (United States); Chandavarkar, S.S. [Tennessee Univ., Knoxville, TN (United States). Dept. of Physics and Astronomy

1995-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Structurally-driven metal-insulator transition in Ca{sub 2}Ru{sub 1-x}Cr{sub x}O{sub 4} (0{<=}x<0.14): A single crystal X-ray diffraction study  

SciTech Connect (OSTI)

Correlation between structure and transport properties are investigated in high-quality single-crystals of Ca{sub 2}Ru{sub 1-x}Cr{sub x}O{sub 4} with 013.5% and the system behaves as an insulator. Such a large, sharp metal-insulator transition and tuneable transition temperature may have potential applications in electronic devices. -- Graphical abstract: The metal-insulator transition temperature (T{sub MI}) was drastically reduced by Cr doping, and is closely related to the distortion of structure. Display Omitted Research highlights: {yields} The metal-insulator transition temperature (T{sub MI}) was drastically reduced by doping Cr into Ca{sub 2}RuO{sub 4} single crystal. {yields} Detailed single crystal structural analysis provided important insight into this structurally-driven metal-insulator transition. {yields} Negative Volume Thermal Expansion (NVTE) was observed with increasing temperature.

Qi, T.F., E-mail: tqi2@uky.ed [Center for Advanced Materials, University of Kentucky, Lexington, KY 40506 (United States); Department of Physics and Astronomy, University of Kentucky, Lexington, KY 40506 (United States); Ge, M. [Center for Advanced Materials, University of Kentucky, Lexington, KY 40506 (United States); High Magnetic Field Laboratory, University of Science and Technology of China, Hefei, Anhui 230026 (China); Korneta, O.B. [Center for Advanced Materials, University of Kentucky, Lexington, KY 40506 (United States); Department of Physics and Astronomy, University of Kentucky, Lexington, KY 40506 (United States); Parkin, S. [Center for Advanced Materials, University of Kentucky, Lexington, KY 40506 (United States); Department of Chemistry, University of Kentucky, Lexington, KY 40506 (United States); De Long, L.E.; Cao, G. [Center for Advanced Materials, University of Kentucky, Lexington, KY 40506 (United States); Department of Physics and Astronomy, University of Kentucky, Lexington, KY 40506 (United States)

2011-04-15T23:59:59.000Z

322

0 1 2 3 4 5 Fig. S1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core  

E-Print Network [OSTI]

1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core scanning determined by XRF core scanning on core ZH10-19 from Lake Zurich recovered in 135 m water depth (2 m above counts and Mn/Fe ratio determined by XRF core scanning on core ZH10-21 from Lake Zurich recovered in 123

Gilli, Adrian

323

g factor of the first excited state in {sup 56}Fe and implications for transient-field calibration in the Fe region  

SciTech Connect (OSTI)

The transient-field technique has been used to measure the g factor of the 2{sub 1}{sup +} state in {sup 56}Fe relative to the independently determined g factor of the first 5/2{sup -} state in {sup 57}Fe. The new result for {sup 56}Fe agrees with previous measurements but is more precise. Implications for calibrating the transient field and g-factor measurements in the fp region are discussed.

East, M. C.; Stuchbery, A. E.; Chamoli, S. K.; Kibedi, T. [Department of Nuclear Physics, Research School of Physics and Engineering, Australian National University Canberra, ACT 0200 (Australia); Wilson, A. N. [Department of Nuclear Physics, Research School of Physics and Engineering, Australian National University Canberra, ACT 0200 (Australia); Department of Physics, Australian National University, Canberra, ACT 0200 (Australia); Crawford, H. L.; Pinter, J. S.; Mantica, P. F. [NSCL and Department of Chemistry, Michigan State University, Michigan 48824 (United States)

2009-02-15T23:59:59.000Z

324

XAS Characterization of a Nitridoiron(IV) Complex with a Very Short Fe-N Bond  

SciTech Connect (OSTI)

X-ray absorption spectroscopy has been used to characterize the novel nitridoiron(IV) units in two [PhBP{sup R}{sub 3}]Fe(N) complexes (R = iPr and CyCH{sub 2}) and obtain direct spectroscopic evidence for a very short Fe-N distance. The distance of 1.51-1.55 {angstrom} reflects the presence of an Fe{triple_bond}N triple bond in accord with the observed Fe{triple_bond}N vibration observed for one of these species ({nu}{sub FeN} = 1034 cm{sup -1}). This highly covalent bonding interaction results in the appearance of an unusually intense pre-edge peak, whose estimated area of 100(20) units is much larger than those of the related tetrahedral complexes with Fe{sup I}-N{sub 2}-Fe{sup I}, Fe{sup II}-NPh{sub 2}, and Fe{sup III}NAd motifs, and those of recently described six-coordinate Fe{sup V}{triple_bond}N and Fe{sup VI}{triple_bond}N complexes. The observation that the Fe{sup IV}-N distances of two [PhBP{sup R}{sub 3}]Fe(N) complexes are shorter than the Fe{sup IV}-O bond lengths of oxoiron(IV) complexes may be rationalized on the basis of the greater {pi} basicity of the nitrido ligand than the oxo ligand and a lower metal coordination number for the Fe(N) complex.

Rohde,J.; Betley, T.; Jackson, T.; Saouma, C.; Peters, J.; Que, Jr., L.

2007-01-01T23:59:59.000Z

325

XAS Characterization of a Nitridoiron(IV) Complex With a Very Short Fe-N Bond  

SciTech Connect (OSTI)

X-ray absorption spectroscopy has been used to characterize the novel nitridoiron(IV) units in two [PhBP{sup R}{sub 3}]Fe(N) complexes (R = iPr and CyCH{sub 2}) and obtain direct spectroscopic evidence for a very short Fe-N distance. The distance of 1.51--1.55 {angstrom} reflects the presence of an Fe{triple_bond}N triple bond in accord with the observed Fe{triple_bond}N vibration observed for one of these species (v{sub FeN}=1034 cm{sup -1}). This highly covalent bonding interaction results in the appearance of an unusually intense pre-edge peak, whose estimated area of 100(20) units is much larger than those of the related tetrahedral complexes with Fe{sup I}-N{sub 2}-Fe{sup I}, Fe{sup II}-NPh{sub 2}, and Fe{sup III}{triple_bond}NAd motifs, and those of recently described six-coordinate Fe{sup V}{triple_bond}N and Fe{sup VI}{triple_bond}N complexes. The observation that the Fe{sup IV}-N distances of two [PhBP{sup R}{sub 3}]Fe(N) complexes are shorter than the Fe{sup IV}-O bond lengths of oxoiron(IV) complexes may be rationalized on the basis of the greater ? basicity of the nitrido ligand than the oxo ligand and a lower metal coordination number for the Fe(N) complex.

Rohde, J.-U.; Betley, T.A.; Jackson, T.A.; Saouma, C.T.; Peters, J.C.; Que, L.; Jr.

2009-06-04T23:59:59.000Z

326

Interface magnetism of Co{sub 2}FeGe Heusler alloy layers and magnetoresistance of Co{sub 2}FeGe/MgO/Fe magnetic tunnel junctions  

SciTech Connect (OSTI)

The interface magnetism between Co{sub 2}FeGe Heusler alloy layers and MgO layers was investigated using {sup 57}Fe Mössbauer spectroscopy. Interface-sensitive samples, where the {sup 57}Fe isotope was used only for the interfacial atomic layer of the Co{sub 2}FeGe layer on the MgO layer, were prepared using atomically controlled alternate deposition. The {sup 57}Fe Mössbauer spectra of the interface-sensitive samples at room temperature were found similar to those of the bulk-sensitive Co{sub 2}FeGe films in which the {sup 57}Fe isotope was distributed throughout the films. On the other hand, the tunnel magnetoresistance effect of magnetic tunnel junctions with Co{sub 2}FeGe layers as the ferromagnetic electrodes showed strong reduction at room temperature. These results indicate that the strong temperature dependence of the tunneling magnetoresistance of magnetic tunnel junctions using Heusler alloy electrodes cannot be attributed simply to the reduction of the magnetization at the interfaces between the Heusler alloy and insulator layers.

Tanaka, M. A., E-mail: mtanaka@nitech.ac.jp; Maezaki, D.; Ishii, T.; Okubo, A.; Mibu, K. [Department of Engineering Physics, Electronics and Mechanics, Nagoya Institute of Technology, Nagoya, Aichi 466-8555 (Japan); Hiramatsu, R.; Ono, T. [Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan)

2014-10-28T23:59:59.000Z

327

Morphology and crystallographic orientation relationship in isothermally transformed Fe–N austenite  

SciTech Connect (OSTI)

The 225 °C isothermal transformation of a high-nitrogen austenite with Fe–2.71 wt.% N was investigated by means of electron microscopy. It was found that the transformation products were composed of ultrafine ?-Fe and ??-Fe{sub 4}N plus retained austenite ?, which were in two types of morphologies, namely, (i) with the retained austenite patches dispersed among the (?-Fe + ??-Fe{sub 4}N) packets and (ii) with the ultrafine ?-Fe and ?/??-Fe{sub 4}N laths interwoven with each other within a single bainitic packet. A cube–cube orientation relationship between the ? (austenite) and ??-Fe{sub 4}N, and a near Greninger–Troiano (G–T) one between the ? (austenite) and the bainitic ?-ferrite were detected. The morphology, orientation relationship and high hardness (> 1000 HV) of the transformation products indicated that the isothermal transformation of the high nitrogen austenite was analogous to a bainitic one. - Highlights: • Isothermal transformation products consisted of nano-sized ?-Fe + ?? + ? (retained). • The hardness of transformation product exceeded 1000 HV. • The ?-Fe and ?/??-Fe{sub 4}N kept a near G-T OR in the grain interior.

Jiao, Dongling, E-mail: dljiao@scut.edu.cn [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Luo, Chengping; Liu, Jiangwen [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Zhang, Guoqing [Science and Technology on Advanced High Temperature Structural Materials Laboratory, Beijing Institute of Aeronautical Materials, Beijing 100095 (China)

2014-02-15T23:59:59.000Z

328

Oxide shell reduction and magnetic property changes in core-shell Fe nanoclusters under ion irradiation  

SciTech Connect (OSTI)

Ion irradiation effects are studied on the Fe-based core-shell nanocluster (NC) films with core as Fe and shell as Fe{sub 3}O{sub 4}/Fe{sub 3}N. These NC films were deposited on Si substrates to thickness of ?0.5 ?m using a NC deposition system. The films were irradiated at room temperature with 5.5?MeV Si{sup 2+} ions to ion fluences of 10{sup 15} and 10{sup 16} ions/cm{sup 2}. It is found that the irradiation induces grain growth, Fe valence reduction in the shell, and crystallization or growth of Fe{sub 3}N. The film retained its Fe-core and its ferromagnetic properties after irradiation. The nature and mechanism of oxide shell reduction and composition dependence after irradiation were studied by synthesizing additional NC films of Fe{sub 3}O{sub 4} and FeO?+?Fe{sub 3}N and irradiating them under the same conditions. The presence of nanocrystalline Fe is found to be a major factor for the oxide shell reduction. The surface morphologies of these films show dramatic changes in the microstructures due to cluster growth and agglomeration as a result of ion irradiation.

Sundararajan, Jennifer A.; Kaur, Maninder; Qiang, You, E-mail: youqiang@uidaho.edu [Department of Physics, University of Idaho, Moscow, Idaho 83844 (United States); Jiang, Weilin [Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352 (United States); McCloy, John S. [School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 99164 (United States)

2014-05-07T23:59:59.000Z

329

Phase formation in Zr/Fe multilayers during Kr ion irradiation.  

SciTech Connect (OSTI)

A detailed study has been conducted of the effect of Kr ion irradiation on phase formation in Zr-Fe metallic multilayers, using the Intermediate Voltage Electron Microscopy (IVEM) at Argonne National Laboratory. Metallic multilayers were prepared with different overall compositions (near 50-50 and Fe-rich), and with different wavelengths (repetition thicknesses). These samples were irradiated with 300 keV Kr ions at various temperatures to investigate the final products, as well as the kinetics of phase formation. For the shorter wavelength samples, the final product was in all cases an amorphous Zr-Fe phase, in combination with Fe, while specially for the larger wavelength samples, in the Fe-rich samples the intermetallic compounds ZrFe{sub 2} and Zr{sub 3}Fe were formed in addition to the amorphous phase. The dose to full reaction decreases with temperature, and with wavelength in a manner consistent with a diffusion-controlled reaction.

Motta, A. T.

1998-01-29T23:59:59.000Z

330

Effect of tungsten addition on the toughness and hardness of Fe{sub 2}B in wear-resistant Fe-B-C cast alloy  

SciTech Connect (OSTI)

The effects of tungsten additions of 0%, 1.12%, 2.04%, and 3.17% (in wt.%) on the morphology, fracture toughness and micro-hardness of Fe{sub 2}B in Fe-B-C cast alloy were investigated. The results indicate that, with the increase of tungsten addition, the morphology and distribution of Fe{sub 2}B have no change and a new W-containing phase, except the (Fe, W){sub 2}B with a certain tungsten solution, does not form, and that the fracture toughness of Fe{sub 2}B increases first and then decreases, while the hardness increases first and then has a little change. Compared with the fracture toughness (3.8 MPa{center_dot}m{sup 1/2}) of Fe{sub 2}B without tungsten addition, the toughness at 2.04 wt.% tungsten can be improved by about above 80% and achieves about 6.9 MPa{center_dot}m{sup 1/2}, and variation characteristics of hardness and toughness of Fe{sub 2}B were also testified by viewing the indentation marks and cracks on the Fe{sub 2}B, respectively. - Highlights: Black-Right-Pointing-Pointer Poor toughness of Fe2B decreases obviously the wear resistance of the alloy. Black-Right-Pointing-Pointer As W content increases, Fe2B's toughness increases first and then decreases. Black-Right-Pointing-Pointer As W content increases, Fe2B's hardness first increases and then has little change. Black-Right-Pointing-Pointer The toughness at 2.04 % W can be improved by above 80% more than that at 0% W.

Huang, Zhifu, E-mail: hzf@mail.xjtu.edu.cn; Xing, Jiandong; Lv, Liangliang

2013-01-15T23:59:59.000Z

331

Tensile properties of Fe-16 at. % Al alloys  

SciTech Connect (OSTI)

A newly developed melting method for Fe-16 at. % Al alloy (FAPY) is described. Tensile data on the air-induction-melted (AIM) and vacuum-induction-melted (VIM) heats of FAPY after identical processing are presented. Optical, scanning electron micrographs (SEM), and microprobe analysis were carried out to explain the lower room-temperature ductility and more scatter in the data for the AIM material as opposed to the VIM material.

Sikka, V.K.

1995-02-01T23:59:59.000Z

332

Average Fe K-alpha emission from distant AGN  

E-Print Network [OSTI]

One of the most important parameters in the XRB (X-ray background) synthesis models is the average efficiency of accretion onto SMBH (super-massive black holes). This can be inferred from the shape of broad relativistic Fe lines seen in X-ray spectra of AGN (active galactic nuclei). Several studies have tried to measure the mean Fe emission properties of AGN at different depths with very different results. We compute the mean Fe emission from a large and representative sample of AGN X-ray spectra up to redshift ~ 3.5. We developed a method of computing the rest-frame X-ray average spectrum and applied it to a large sample (more than 600 objects) of type 1 AGN from two complementary medium sensitivity surveys based on XMM-Newton data, the AXIS and XWAS samples. This method makes use of medium-to-low quality spectra without needing to fit complex models to the individual spectra but with computing a mean spectrum for the whole sample. Extensive quality tests were performed by comparing real to simulated data, and a significance for the detection of any feature over an underlying continuum was derived. We detect with a 99.9% significance an unresolved Fe K-alpha emission line around 6.4 keV with an EW ~ 90 eV, but we find no compelling evidence of any significant broad relativistic emission line in the final average spectrum. Deviations from a power law around the narrow line are best represented by a reflection component arising from cold or low-ionization material. We estimate an upper limit for the EW of any relativistic line of 400 eV at a 3 sigma confidence level. We also marginally detect the so-called Iwasawa-Taniguchi effect on the EW for the unresolved emission line, which appears weaker for higher luminosity AGN.

A. Corral; M. J. Page; F. J. Carrera; X. Barcons; S. Mateos; J. Ebrero; M. Krumpe; A. Schwope; J. A. Tedds; M. G. Watson

2008-10-02T23:59:59.000Z

333

Santa Fe Springs, California: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to: navigation, searchVirginiaRooseveltVI SolarisSanduskyClarita,Fe Springs, California:

334

Santa Fe, Texas: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to: navigation, searchVirginiaRooseveltVI SolarisSanduskyClarita,Fe Springs,

335

Rancho Santa Fe, California: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to: navigation, search RAPIDColoradosource HistoryRaftRamsey, NewRancho Santa Fe, California:

336

Average Fe K-alpha emission from distant AGN  

E-Print Network [OSTI]

One of the most important parameters in the XRB (X-ray background) synthesis models is the average efficiency of accretion onto SMBH (super-massive black holes). This can be inferred from the shape of broad relativistic Fe lines seen in X-ray spectra of AGN (active galactic nuclei). Several studies have tried to measure the mean Fe emission properties of AGN at different depths with very different results. We compute the mean Fe emission from a large and representative sample of AGN X-ray spectra up to redshift ~ 3.5. We developed a method of computing the rest-frame X-ray average spectrum and applied it to a large sample (more than 600 objects) of type 1 AGN from two complementary medium sensitivity surveys based on XMM-Newton data, the AXIS and XWAS samples. This method makes use of medium-to-low quality spectra without needing to fit complex models to the individual spectra but with computing a mean spectrum for the whole sample. Extensive quality tests were performed by comparing real to simulated data, a...

Corral, A; Carrera, F J; Barcons, X; Mateos, S; Ebrero, J; Krumpe, M; Schwope, A; Tedds, J A; Watson, M G

2008-01-01T23:59:59.000Z

337

AlN/Fe/AlN nanostructures for magnetooptic magnetometry  

SciTech Connect (OSTI)

AlN/Fe/AlN/Cu nanostructures with ultrathin Fe grown by sputtering on Si substrates are evaluated as probes for magnetooptical (MO) mapping of weak currents. They are considered for a laser wavelength of ??=?410?nm (3.02?eV) and operate at oblique light incidence angles, ?{sup (0)}, to enable detection of both in-plane and out-of-plane magnetization. Their performance is evaluated in terms of MO reflected wave electric field amplitudes. The maximal MO amplitudes in AlN/Fe/AlN/Cu are achieved by a proper choice of layer thicknesses. The nanostructures were characterized by MO polar Kerr effect at ?{sup (0)}???5° and longitudinal Kerr effect spectra (?{sup (0)}?=?45°) at photon energies between 1 and 5?eV. The nominal profiles were refined using a model-based analysis of the spectra. Closed form analytical expressions are provided, which are useful in the search for maximal MO amplitudes.

Lišková-Jakubisová, E., E-mail: liskova@karlov.mff.cuni.cz; Viš?ovský, Š. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 5, 12116 Prague 2 (Czech Republic); Široký, P.; Hrabovský, D.; Pištora, J. [Nanotechnology Center, Technical University of Ostrava, 17. listopadu 15/2172, 70833 Ostrava Poruba (Czech Republic); Harward, I.; Celinski, Z. [Center for Magnetism and Magnetic Nanostructures, University of Colorado at Colorado Springs, 1420 Austin Bluffs Pkwy., Colorado Springs, Colorado 80918 (United States)

2014-05-07T23:59:59.000Z

338

134 Inorg. Chem. 1995, 34, 134-139 Structural and Spectroscopic Properties of Antiferromagnetically Coupled FeUIMnUand  

E-Print Network [OSTI]

homodinuclear active sites involving first row transition metals like Fe (hemerythrin,2ribonucleotide redu

Hendrich, Mike

339

Tunneling conductance studies in the ion-beam sputtered CoFe/Mg/MgO/NiFe magnetic tunnel junctions  

SciTech Connect (OSTI)

Magnetic tunnel junctions consisting of CoFe(10 nm)/Mg(1 nm)/MgO(3.5 nm)/NiFe(10 nm) are grown at room temperature using dual ion beam sputtering via in-situ shadow masking. The effective barrier thickness and average barrier height are estimated to be 3.5 nm (2.9 nm) and 0.69 eV (1.09 eV) at 290 K (70 K), respectively. The tunnel magnetoresistance value of 0.2 % and 2.3 % was observed at 290 K and 60 K, respectively. The temperature dependence of tunneling conductance revealed the presence of localized states present within the forbidden gap of the MgO barrier leading to finite inelastic spin independent tunneling contributions, which degrade the TMR value.

Singh, Braj Bhusan; Chaudhary, Sujeet [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India)

2013-06-03T23:59:59.000Z

340

Magnetoelectric nano-Fe3O4?CoFe2O4?PbZr0.53Ti0.47O3 composite  

E-Print Network [OSTI]

A new magnetoelectric hybrid device composed of a nanoparticulate magnetostrictive iron oxide-cobalt ferritefilm on a piezoelectric lead zirconic titanate crystal serving as both substrate and straining medium is described. Nano-Fe3O4?CoFe2O4...

Ren, Shenqiang; Wuttig, Manfred

2008-02-26T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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341

Focus on superconductivity in Fe-based systems  

SciTech Connect (OSTI)

The past four years of incredibly intense research into Fe-based superconductors have brought about many unexpected surprises. Our understanding of their behavior and physical properties is constantly evolving. Unlike any other superconductors, those containing iron span diverse groups of materials: pnictides, chalcogenides, intermetallics and oxides. Some major properties of the materials are quite similar, yet each group has its own distinct features. Significant effort has been put into identifying new superconducting compositions, modifying the existing ones with new dopants and treatments, and producing single crystals, thin films, wires and polycrystalline bulk material. A wide array of experimental techniques was applied to study Fe-based superconductors and the result is a tremendous amount of data collected over a period of less than four years. Theoretical debates are still lively, and there is an ongoing search for possible universalities and commonalities with other unconventional superconductors, like high-Tc cuprates or heavy fermion materials. The three-dimensional electronic structures of Fe-based superconductors, as well as their extreme sensitivity to disorder, present serious challenges for both theoretical analysis and the interpretation of experiments. However, some key properties emerge from multiple studies. Unconventional, multiband superconductivity originating from an electronic mechanism has found both experimental and theoretical support. There has been great progress in the understanding of various anisotropies of superconducting gap structures, including the possibility of gap nodes even if the gap symmetry is s-wave. Similar to high-Tc cuprates, the superconducting phase has a dome-like shape on T-doping or T-pressure phase diagrams. The anisotropy of the superconducting gap evolves with doping and is likely to become stronger at the dome's edge. In many Fe-based superconductors there is a range where superconductivity coexists and competes with long-range magnetic order, and magnetic fluctuations are considered by some to be of the utmost importance for the pairing mechanism. Others argue that orbital fluctuations, possibly in combination with phonons, are crucial for the pairing. Fe-based superconductors show extremely large upper critical fields and relatively low electronic anisotropy, which are crucial aspects for power applications. The expectations are high, though it remains unclear what maximal current densities can be supported by a properly designed bulk material with optimal pinning centers. This focus issue of Superconductor Science and Technology is a snapshot of some of the recent progress in materials preparation, experiments and theory. It includes articles on the search for new Fe-based superconductors and on the search for superconductivity at extreme conditions. Particular attention is devoted to: the effects of chemical substitutions; the development of thin films; the introduction of artificial defects to increase critical current density; and a general analysis of vortex physics. The articles on fundamental aspects of superconductivity include: the discussion of various experimental problems; an in-depth analysis of the nodal and nodeless pairing states; the discussion of the pairing mechanism; and the effects of pair-breaking due to disorder. Also discussed are nematic correlations and the coexistence of magnetism and superconductivity. The papers collected in this issue present a detailed review of the accomplishments of the last four years of research into Fe-based superconductors, up to and including last-minute developments. We hope that this combination will make this special section of Superconductor Science and Technology both interesting and useful to a broad spectrum of physicists and materials scientists.

Prozorov, Ruslan; Chubukov, Andrey; Meingast, Christoph; Putti, Marina

2012-08-03T23:59:59.000Z

342

Isolation and microbial reduction of Fe(III) phyllosilicates from subsurface sediments  

SciTech Connect (OSTI)

Fe(III)-bearing phyllosilicates can be important sources of Fe(III) for dissimilatory microbial iron reduction in clay-rich anoxic soils and sediments. The goal of this research was to isolate Fe(III) phyllosilicate phases, and if possible, Fe(III) oxide phases, from a weathered shale saprolite sediment in order to permit experimentation with each phase in isolation. Physical partitioning by density gradient centrifugation did not adequately separate phyllosilicate and Fe(III) oxide phases (primarily nanoparticulate goethite). Hence we examined the ability of chemical extraction methods to remove Fe(III) oxides without significantly altering the properties of the phyllosilicates. XRD analysis showed that extraction with oxalate alone or oxalate in the presence of added Fe(II) altered the structure of Fe-bearing phyllosilicates in the saprolite. In contrast, citrate-bicarbonate-dithionite (CBD) extraction at room temperature and 80C led to minimal alteration of phyllosilicate structures. Reoxidation of CDB-extracted sediment with H2O2 restored phyllosilicate structure (i.e. d-spacing) and redox speciation to conditions similar to that in the pristine sediment. The extent of microbial (Geobacter sulfurreducens) reduction of Fe(III) phyllosilicates isolated by CDB extraction (ca. 16 %) was comparable to what took place in pristine sediments as determined by Mossbauer spectroscopy (ca. 18 % reduction). These results suggest that materials isolated by CDB extraction and H2O2 reoxidation are appropriate targets for detailed studies of natural soil/sediment Fe(III) phyllosilicate reduction.

Wu, Tao; Shelobolina, Evgenya S.; Xu, Huifang; Konishi, Hiromi; Kukkadapu, Ravi K.; Roden, Eric E.

2012-10-12T23:59:59.000Z

343

First principles study of Fe in diamond: A diamond-based half metallic dilute magnetic semiconductor  

SciTech Connect (OSTI)

Half-metallic ferromagnetic ordering in semiconductors, essential in the emerging field of spintronics for injection and transport of highly spin polarised currents, has up to now been considered mainly in III–V and II–VI materials. However, low Curie temperatures have limited implementation in room temperature device applications. We report ab initio Density Functional Theory calculations on the properties of Fe in diamond, considering the effects of lattice site, charge state, and Fermi level position. We show that the lattice sites and induced magnetic moments of Fe in diamond depend strongly on the Fermi level position and type of diamond co-doping, with Fe being energetically most favorable at the substitutional site in p-type and intrinsic diamond, while it is most stable at a divacancy site in n-type diamond. Fe induces spin polarized bands in the band gap, with strong hybridization between Fe-3d and C-2s,2p bands. We further consider Fe-Fe spin interactions in diamond and show that substitutional Fe{sup +1} in p-type diamond exhibits a half-metallic character, with a magnetic moment of 1.0??{sub B} per Fe atom and a large ferromagnetic stabilization energy of 33?meV, an order of magnitude larger than in other semiconductors, with correspondingly high Curie temperatures. These results, combined with diamond's unique properties, demonstrate that Fe doped p-type diamond is likely to be a highly suitable candidate material for spintronics applications.

Benecha, E. M. [Department of Physics, University of South Africa, P.O. Box 392, UNISA 0003 Pretoria (South Africa); Lombardi, E. B., E-mail: lombaeb@unisa.ac.za [College of Graduate Studies, University of South Africa, P.O. Box 392, UNISA 0003 Pretoria (South Africa)

2013-12-14T23:59:59.000Z

344

STORAGE RING CROSS SECTION MEASUREMENTS FOR ELECTRON IMPACT SINGLE AND DOUBLE IONIZATION OF Fe{sup 13+} AND SINGLE IONIZATION OF Fe{sup 16+} AND Fe{sup 17+}  

SciTech Connect (OSTI)

We report measurements of electron impact ionization for Fe{sup 13+}, Fe{sup 16+}, and Fe{sup 17+} over collision energies from below threshold to above 3000 eV. The ions were recirculated using an ion storage ring. Data were collected after a sufficiently long time that essentially all the ions had relaxed radiatively to their ground state. For single ionization of Fe{sup 13+}, we find that previous single pass experiments are more than 40% larger than our results. Compared to our work, the theoretical cross section recommended by Arnaud and Raymond is more than 30% larger, while that of Dere is about 20% greater. Much of the discrepancy with Dere is due to the theory overestimating the contribution of excitation-autoionization via n = 2 excitations. Double ionization of Fe{sup 13+} is dominated by direct ionization of an inner shell electron accompanied by autoionization of a second electron. Our results for single ionization of Fe{sup 16+} and Fe{sup 17+} agree with theoretical calculations to within the experimental uncertainties.

Hahn, M.; Novotny, O.; Savin, D. W. [Columbia Astrophysics Laboratory, Columbia University, 550 West 120th Street, New York, NY 10027 (United States)] [Columbia Astrophysics Laboratory, Columbia University, 550 West 120th Street, New York, NY 10027 (United States); Becker, A.; Grieser, M.; Krantz, C.; Repnow, R.; Wolf, A. [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany)] [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany); Bernhardt, D.; Mueller, A.; Schippers, S.; Spruck, K. [Institut fuer Atom- und Molekuelphysik, Justus-Liebig-Universitaet Giessen, Leihgesterner Weg 217, D-35392 Giessen (Germany)] [Institut fuer Atom- und Molekuelphysik, Justus-Liebig-Universitaet Giessen, Leihgesterner Weg 217, D-35392 Giessen (Germany); Lestinsky, M. [GSI Helmholtzzentrum fuer Schwerionenforschung, Planckstr. 1, D-64291 Darmstadt (Germany)] [GSI Helmholtzzentrum fuer Schwerionenforschung, Planckstr. 1, D-64291 Darmstadt (Germany)

2013-04-10T23:59:59.000Z

345

Search for supernova-produced 60Fe in a marine sediment  

E-Print Network [OSTI]

An 60Fe peak in a deep-sea FeMn crust has been interpreted as due to the signature left by the ejecta of a supernova explosion close to the solar system 2.8 +/- 0.4 Myr ago [Knie et al., Phys. Rev. Lett. 93, 171103 (2004)]. To confirm this interpretation with better time resolution and obtain a more direct flux estimate, we measured 60Fe concentrations along a dated marine sediment. We find no 60Fe peak at the expected level from 1.7 to 3.2 Myr ago. However, applying the same chemistry used for the sediment, we confirm the 60Fe signal in the FeMn crust. The cause of the discrepancy is discussed.

C. Fitoussi; G. M. Raisbeck; K. Knie; G. Korschinek; T. Faestermann; S. Goriely; D. Lunney; M. Poutivtsev; G. Rugel; C. Waelbroeck; A. Wallner

2007-09-26T23:59:59.000Z

346

Cation self-diffusion in Fe/sub 2/O/sub 3/  

SciTech Connect (OSTI)

Self-diffusion of /sup 59/Fe in single crystals of Fe/sub 2/O/sub 3/ parallel to the c-axis has been measured as a function of temperature (1150 to 1340/sup 0/C) and oxygen partial pressure (2 x 10/sup -3/) less than or equal to Po/sub 2/ less than or equal to 1 atm). The oxygen partial pressure dependence of the diffusivity indicates that cation self-diffusion occurs by an interstitial-type mechanism. The simultaneous diffusion of /sup 52/Fe and /sup 59/Fe has been measured in Fe/sub 2/O/sub 3/ at 1251/sup 0/C and Po/sub 2/ = 1.91 x 10/sup -2/ atm. The small value of the isotope effect (f..delta..K = 0.067 +- 0.016) is consistent with diffusion of Fe ions by an interstitially mechanism.

Hoshino, K.; Peterson, N.L.

1984-01-01T23:59:59.000Z

347

Magnetism of NiMn2O4-Fe3O4 spinel interfaces  

SciTech Connect (OSTI)

We investigate the magnetic properties of the isostructural spinel-spinel interface of NiMn{sub 2}O{sub 4}(NMO)-Fe{sub 3}O{sub 4}. Although the magnetic transition temperature of the NMO film is preserved, both bulk and interface sensitive measurements demonstrate that the interface exhibits strong interfacial magnetic coupling up to room temperature. While NMO thin films have a ferrimagnetic transition temperature of 60 K, both NiFe{sub 2}O{sub 4} and MnFe{sub 2}O{sub 4} are ferrimagnetic at room temperature. Our experimental results suggest that these magnetic properties arise from a thin interdiffused region of (Fe,Mn,Ni){sub 3}O{sub 4} at the interface, leading to Mn and Ni magnetic properties similar to those of MnFe{sub 2}O{sub 4} and NiFe{sub 2}O{sub 4}.

Arenholz, Elke; Nelson-Cheeseman, B. B.; Chopdekar, R. V.; Bettinger, J. S.; Arenholz, E.; Suzuki, Y.

2007-09-13T23:59:59.000Z

348

Refined model of the {Fe9} magnetic molecule from low-temperature inelastic neutron scattering studies  

SciTech Connect (OSTI)

We present a refined model of the {Fe9} tridiminished icosahedron magnetic molecule system. This molecule was originally modeled as being composed of two ({Fe3} and {Fe6}) clusters, with the Fe3+ ions within each cluster being coupled via exchange interactions, but with no coupling between the clusters. The present inelastic neutron scattering (INS) measurements were used to probe the low-lying energy spectrum of {Fe9}, and these results demonstrate that the previously published model of two uncoupled clusters is incomplete. To achieve agreement between the experiment and theory, we have augmented the model with relatively small exchange coupling between the clusters. A combination of Lanczos matrix diagonalization and quantum Monte Carlo simulations have been used to achieve good agreement between the experimental data and the improved model of the full {Fe9} system despite the complexity of this model (with Hilbert space dimension >107).

Engelhardt, Larry [Francis Marion University; Demmel, Franz [Rutherford Appleton Laboratory; Luban, Marshall [Ames Laboratory; Timco, Grigore A [The University of Manchester; Tuna, Floriana [The University of Manchester; Winpenny, Richard E [The University of Manchester

2014-06-01T23:59:59.000Z

349

Corrosion behavior of newly developed TiAgFe dental alloys in neutral saline solution  

E-Print Network [OSTI]

Corrosion behavior of newly developed Ti­Ag­Fe dental alloys in neutral saline solution B. B. Zhang, B. L. Wang, L. Li and Y. F. Zheng* The corrosion behavior of Ti­5Ag­xFe alloys (x ¼ 1, 2.5, 5 wt) Ti,Ti­ 5Ag­xFe alloys exhibited higher corrosion potentials, lower current densities, and larger

Zheng, Yufeng

350

Solubility and freezing effects of Fe2+ solutions representative of upper tropospheric and lower  

E-Print Network [OSTI]

determined the total equilibrium metal solubility ([Fe2+ ]T and [Mg2+ ]T) in 20­90 wt % sulfuric acidSolubility and freezing effects of Fe2+ and Mg2+ in H2SO4 solutions representative of upper solutions over the temperature range 200­300 K. We have measured solubilities using samples of MgSO4, FeSO4Á

351

The impact of alpha/Fe enhanced stellar evolutionary tracks on the ages of elliptical galaxies  

E-Print Network [OSTI]

We complement our study of alpha/Fe enhanced stellar population models of Lick absorption indices (Thomas et al. 2003) by comparing two sets of alpha/Fe enhanced models. In both models the impact on Lick indices due to alpha/Fe enhancement is accounted for through a modification of the stellar absorption line-strengths using the response functions of Tripicco & Bell (1995). One set of models, however, uses solar-scaled, the other alpha/Fe enhanced stellar evolutionary tracks. Since the alpha/Fe enhanced tracks are hotter than the solar-scaled ones (Salasnich et al. 2000), the correspondent stellar population models have slightly weaker metallic indices (i.e. Mgb, etc.) and stronger Balmer line indices (Hbeta) (Maraston et al 2003). Here we explore quantitatively the impact of this effect on the alpha/Fe ratios, metallicities and ages that are derived for elliptical galaxies. We find that the modest decrease of the metallic indices Mgb and balance each other, such that fully consistent alpha/Fe ratios are derived for stellar systems using alpha/Fe enhanced models with either solar-scaled or alpha/Fe enhanced stellar tracks. The decrease of the metallic indices and the increase of Hbeta conspire in a way that also consistent metallicities are obtained. The derived ages, instead, are significantly different. The inclusion of alpha/Fe enhanced stellar tracks leads to the derivation of ages as high as 30 Gyr for elliptical galaxies. For the same objects, ages not older than 15 Gyr are obtained, if alpha/Fe enhanced models using solar-scaled tracks are adopted. This may indicate that current stellar evolutionary models overestimate the bluing of stellar evolutionary tracks due to alpha/Fe enhanced chemical mixtures at super-solar metallicities.

Daniel Thomas; Claudia Maraston

2003-02-04T23:59:59.000Z

352

Controlling ferromagnetism of (In,Fe)As semiconductors by electron doping  

SciTech Connect (OSTI)

Based on experimental results, using the Korringa-Kohn-Rostoker coherent potential approximation (KKR-CPA) method and Monte Carlo simulation, we study the mechanism of ferromagnetic behavior of (In,Fe)As. We show that with doped Be atoms occupying in interstitial sites, chemical pair interactions between atoms and magnetic exchange interactions between Fe atoms change due to electron concentration. Therefore, by controlling the doping process, magnetic behavior of (In,Fe)As is controlled and ferromagnetism is observed in this semiconductor.

Dang Vu, Nguyen; Fukushima, Tetsuya; Katayama-Yoshida, Hiroshi [Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan); Sato, Kazunori [Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)

2014-02-21T23:59:59.000Z

353

Nonlinear FE analysis of cracks in tension and shear  

E-Print Network [OSTI]

Carbon FRP Shear Reinforcement. PhD thesis, University of Cambridge, UK, 2003. 3. Bazant Z. P. and Planas J. Fracture and Size Effect in Con- crete and Other Quasibrittle Materials. CRC Press, Boca Raton, Florida, 1998. Nonlinear FE analysis of cracks... of plain concrete to cyclic tension. ACI Materials Journal, 1987, 84, No. 5, 365–373. 9. Paulay T. and Loeber P. J. Shear transfer by aggregate inter- lock. ACI Special Publication, SP-42, 1974, 1, 1–14. 10. Houde J. and Mirza M. S. A finite element...

Kesse, G.; Lees, Janet M.

2007-05-01T23:59:59.000Z

354

Inelastic scattering of fast neutrons from $^{56}$Fe  

E-Print Network [OSTI]

Inelastic scattering of fast neutrons from $^{56}$Fe was studied at the photoneutron source nELBE. The neutron energies were determined on the basis of a timeof- flight measurement. Gamma-ray spectra were measured with a high-purity germanium detector. The total scattering cross sections deduced from the present experiment in an energy range from 0.8 to 9.6 MeV agree within 15% with earlier data and with predictions of the statistical-reaction code Talys.

Beyer, R; Hannaske, R; Junghans, A R; Massarczyk, R; Anders, M; Bemmerer, D; Ferrari, A; Kögler, T; Röder, M; Schmidt, K; Wagner, A

2014-01-01T23:59:59.000Z

355

Improved oxidation sulfidation resistance of Fe-Cr-Ni alloys  

DOE Patents [OSTI]

High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1 to 8 wt % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500 to 1000/sup 0/C.

Natesan, K.; Baxter, D.J.

1983-07-26T23:59:59.000Z

356

Oxidation sulfidation resistance of Fe-Cr-Ni alloys  

DOE Patents [OSTI]

High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1-8 wt. % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500.degree.-1000.degree. C.

Natesan, Ken (Naperville, IL); Baxter, David J. (Woodridge, IL)

1984-01-01T23:59:59.000Z

357

FE Press Releases and Techlines | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProvedDecember 2005DepartmentDecember U.S. Department of9ofDepartment ofatBlog FE Blog

358

SF 6432-FE Fixed Price Contracts Outside the US  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromisingStoriesSANDIA REPORT SANDSDN forAA7/31/13 Page 1 of 16FE

359

Santa Fe, New Mexico: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to: navigation, searchVirginiaRooseveltVI SolarisSanduskyClarita,Fe Springs, California:NM)

360

Los Alamos National Security invests in Santa Fe Community College  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and Interfaces Sample6,LocalNuclearandplants willows forinvests in Santa Fe

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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361

Santa Fe Community College offers new welding program  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systems controller systemsis aSecurity AdministrationSanketSanta Fe

362

AgFe Management Ltd | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300 SouthWaterBrasil JumpAerowatt Energies Jump to:Africa-EconomicAfricanLtdAgFe

363

DE-FE0009897 | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases onOrganization FY 2012JDA 1/31/136P2DOE/NETL MethaneFE0005958

364

DE-FE0009904 | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases onOrganization FY 2012JDA 1/31/136P2DOE/NETL MethaneFE0005958

365

Structural Insights into FeMo Cofactor Biosynthesis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSiteNeutronStrategic PlanStructuralMethodologyInsights into FeMo

366

Balmer Absorption Lines in FeLoBALs  

E-Print Network [OSTI]

We discovered non-stellar Balmer absorption lines in two many-narrow-trough FeLoBALs (mntBALs) by the near-infrared spectroscopy with Subaru/CISCO. Presence of the non-stellar Balmer absorption lines is known to date only in the Seyfert galaxy NGC 4151, thus our discovery is the first cases for quasars. Since all known active galactic nuclei with Balmer absorption lines share characteristics, it is suggested that there is a population of BAL quasars which have unique structures at their nuclei or unique evolutionary phase.

K. Aoki; I. Iwata; K. Ohta; N. Tamura; M. Ando; M. Akiyama; G. Kiuchi; K. Nakanishi

2006-12-14T23:59:59.000Z

367

Magnetic structures and interplay between rare-earth Ce and Fe magnetism in single-crystal CeFeAsO  

SciTech Connect (OSTI)

Neutron and synchrotron resonant x-ray magnetic scattering (RXMS) complemented by heat capacity and resistivity measurements reveal the evolution of the magnetic structures of Fe and Ce sublattices in a CeFeAsO single crystal. The RXMS of magnetic reflections at the Ce LII edge shows a magnetic transition that is specific to the Ce antiferromagnetic long-range ordering at TCe? 4 K with short-range Ce ordering above TCe, whereas neutron diffraction measurements of a few magnetic reflections indicate a transition at T?? 12 K with an unusual order parameter. Detailed order-parameter measurements on several magnetic reflections by neutrons show a weak anomaly at 4 K that we associate with the Ce ordering. The successive transitions at TCe and T? can also be clearly identified by two anomalies in heat capacity and resistivity measurements. The higher transition temperature at T?? 12 K is mainly ascribed to Fe spin reorientation transition, below which Fe spins rotate uniformly and gradually in the ab plane. The Fe spin reorientation transition and short-range Ce ordering above TCe reflect the strong Fe-Ce couplings prior to long-range ordering of the Ce. The evolution of the intricate magnetic structures in CeFeAsO going through T? and TCe is proposed.

Zhang, Qiang [Ames Laboratory; Tian, Wei [Ames Laboratory; Li, Haifeng [Ames Laboratory; Kim, Jong-Woo [Argonne Naitonal Laboratory; Yan, Jiaqiang [Ames Laboratory; McCallum, Robert William [Ames Laboratory; Lograsso, Thomas A. [Ames Laboratory; Zarestky, Jerel L. [Ames Laboratory; Budko, Sergey L. [Ames Laboratory; McQueeney, Robert J. [Ames Laboratory; Vaknin, David [Ames Laboratory

2013-11-27T23:59:59.000Z

368

Improvement of SOFC Electrodes through Catalyst Infiltration & Control of Cr Volatilization from FeCr Components  

SciTech Connect (OSTI)

This presentation discusses the improvement of SOFC electrodes through catalyst infiltration and control of Cr volatilization from FeCr components.

Visco, S.J.; Jacobson, C.; Kurokawa, H.; Sholklapper, T.; Lu, C.; De Jonghe, L.

2005-01-28T23:59:59.000Z

369

Phonon densities of states of face-centered-cubic Ni-Fe alloys  

SciTech Connect (OSTI)

Inelastic neutron scattering and nuclear resonant inelastic x-ray scattering were used to determine the phonon densities of states of face-centered-cubic Ni-Fe alloys. Increasing Fe concentration results in an average softening of the phonon modes. Chemical ordering of the Ni0.72Fe0.28 alloy results in a reduction of the partial vibrational entropy of the Fe atoms but does not significantly change the partial vibrational entropy of the Ni atoms. Changes in the phonon densities of states with composition and chemical ordering are discussed and analyzed with a cluster expansion method.

Lucas, Matthew [United States Air Force Research Laboratory, Wright-Patterson Air Force Base] [United States Air Force Research Laboratory, Wright-Patterson Air Force Base; Mauger, L [California Institute of Technology, W. M. Keck Laboratory, Pasadena] [California Institute of Technology, W. M. Keck Laboratory, Pasadena; Munoz, Jorge A. [California Institute of Technology, Pasadena] [California Institute of Technology, Pasadena; Halevy, I [California Institute of Technology, Pasadena] [California Institute of Technology, Pasadena; Horwath, J [United States Air Force Research Laboratory, Wright-Patterson Air Force Base] [United States Air Force Research Laboratory, Wright-Patterson Air Force Base; Semiatin, S L [United States Air Force Research Laboratory, Wright-Patterson Air Force Base] [United States Air Force Research Laboratory, Wright-Patterson Air Force Base; Leontsev, S. O. [University of Kentucky, Lexington] [University of Kentucky, Lexington; Stone, Matthew B [ORNL] [ORNL; Abernathy, Douglas L [ORNL] [ORNL; Xiao, Yuming [Carnegie Institution of Washington] [Carnegie Institution of Washington; Chow, P [HPCAT Geophysical Lab, Argonne, IL] [HPCAT Geophysical Lab, Argonne, IL; Fultz, B. [California Institute of Technology, Pasadena] [California Institute of Technology, Pasadena

2013-01-01T23:59:59.000Z

370

E-Print Network 3.0 - al si fe Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

morphology... -section of a strut showing the microstructure. Dendrites of -Al and eutectic structure of Al-Si with needles of - AlFeSi... . ... Source: Groningen,...

371

Structural, thermodynamic, mechanical, and magnetic properties of FeW system  

SciTech Connect (OSTI)

The Fe-W system is systematically investigated through a combined use of first-principles calculation, cluster expansion, special quasirandom structures, and experiments. It is revealed that the ferromagnetic state of BCC Fe-W solid solution has lower heat of formation than its nonmagnetic state within the entire composition range, and intermetallic ?-Fe{sub 2}W and ?-Fe{sub 7}W{sub 6} phases are energetically favorable with negative heats of formation. Calculations also show that the Fe-W solid solution has much lower coefficient of thermal expansion than its mechanical mixture, and that the descending sequence of temperature-dependent elastic moduli of each Fe-W solid solution is E?>?G?>?B. Moreover, magnetic state should have an important effect on mechanical properties of Fe-W phases, and electronic structures can provide a deeper understanding of various properties of Fe-W. The derived results agree well with experimental observations, and can clarify two experimental controversies regarding structural stability and magnetic property of Fe-W phases in the literature.

Ren, Q. Q.; Fan, J. L.; Han, Y.; Gong, H. R., E-mail: gonghr@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)

2014-09-07T23:59:59.000Z

372

Microsoft Word - santa-fe-county-fact-sheet-2013-2014.docx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Santa Fe County participated in one or more of LANL's regional education programs. * Academy for Technology and the Classics * Acequia Madre Elementary * Capital High School *...

373

validation_inv_qs55_fe_and_analytical_dry.eps  

E-Print Network [OSTI]

Page 1. 0. 50. 100. 150. 2. Frequency (Hz). 0. 50. 100. 150. 200. 1000/Q. FE values. analytical values. 55.

santos

374

E-Print Network 3.0 - applied zn fe Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

on bulk samples indicated that ZnS and Zn-Fe (oxyhydr) oxides amounted... in the sediment, and from their further oxidative dissolution and ... Source: Lawrence Berkeley...

375

Nanostructure evolution in joining of Al and Fe nanoparticles with femtosecond laser irradiation  

SciTech Connect (OSTI)

The joining of Al-Fe nanoparticles (NPs) by femtosecond (fs) laser irradiation is reported in this paper. Fe and Al NPs were deposited on a carbon film in vacuum via fs laser ablation. Particles were then exposed to multiple fs laser pulses at fluences between 0.5 and 1.3?mJ/cm{sup 2}. Transmission Electron Microscopy (TEM) and Electron Diffraction X-ray observations indicate that Al and Fe NPs bond to each other under these conditions. For comparison, bonding of Al to Al and Fe to Fe NPs was also investigated. The nanostructure, as observed using TEM, showed that individual Al NPs were monocrystalline while individual Fe NPs were polycrystalline prior to joining and that these structures are retained after the formation of Al-Al and Fe-Fe NPs. Al-Fe NPs produced by fs laser joining exhibited a mixed amorphous and crystalline phase at the interface. Bonding is suggested to originate from intermixing within a region of high field intensity between particles.

Jiao, Z. [State Key Laboratory of Advanced Welding Production Technology, Harbin Institute of Technology, Harbin 150001 (China); Centre for Advanced Materials Joining, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Huang, H.; Zhou, Y., E-mail: hepeng@hit.edu.cn, E-mail: nzhou@uwaterloo.ca [Centre for Advanced Materials Joining, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Department of Mechanical and Mechatronics Engineering, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Liu, L. [Department of Mechanical and Mechatronics Engineering, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Department of Mechanical Engineering, Tsinghua University, Beijing 100084 (China); Hu, A. [Department of Mechanical and Mechatronics Engineering, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Department of Mechanical, Aerospace, and Biomedical Engineering, University of Tennessee, Knoxville, Tennessee 37916 (United States); Duley, W. [Centre for Advanced Materials Joining, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Department of Physics and Astronomy, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); He, P., E-mail: hepeng@hit.edu.cn, E-mail: nzhou@uwaterloo.ca [State Key Laboratory of Advanced Welding Production Technology, Harbin Institute of Technology, Harbin 150001 (China)

2014-04-07T23:59:59.000Z

376

SciTech Connect: A Solution for Solution-Produced [beta]-FeSe...  

Office of Scientific and Technical Information (OSTI)

A Solution for Solution-Produced beta-FeSe: Elucidating and Overcoming Factors that Prevent Superconductivity Citation Details In-Document Search Title: A Solution for...

377

Origin of room temperature ferromagnetic moment in Rh-rich Rh/Fe multilayer thin films  

E-Print Network [OSTI]

films of FeRh was done by electron beam melting on amorphous substrates3 but the low extent of ordering

Laughlin, David E.

378

Fe and Al Abundances for 180 Red Giants in the Globular Cluster Omega Centauri (NGC 5139)  

E-Print Network [OSTI]

We present radial velocities, Fe, and Al abundances for 180 red giant branch (RGB) stars in the Galactic globular cluster Omega Centauri ($\\omega$ Cen). The majority of our data lie in the range 11.0$Al/Fe] ratios exhibit large star--to--star scatter for all populations, with the more than 1.0 dex range of [Al/Fe] decreasing for stars more metal--rich than [Fe/H]$\\sim$--1.4. The minimum [Al/Fe] abundance observed for all metallicity populations is [Al/Fe]$\\sim$+0.15. The maximum abundance of log $\\epsilon$(Al) is reached for stars with [Fe/H]$\\sim$--1.4 and does not increase further with stellar metallicity. We interpret these results as evidence for type II SNe providing the minimum [Al/Fe] ratio and a mass spectrum of intermediate mass asymptotic giant branch stars causing the majority of the [Al/Fe] scatter. These results seem to fit in the adopted scheme that star formation occurred in $\\omega$ Cen over $>$1 Gyr.

Christian I. Johnson; Catherine A. Pilachowski; Jennifer Simmerer; Dustin Schwenk

2008-04-16T23:59:59.000Z

379

E-Print Network 3.0 - accelerated 56fe particles Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: accelerated 56fe particles Page: << < 1 2 3 4 5 > >> 1 RADIATION RESEARCH 162, 655659 (2004)...

380

Structure of epitaxial (Fe,N) codoped rutile TiO2 thin films...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

No evidence of structural disorder associated with a high concentration of oxygen vacancies is observed. Substitution of Fe for Ti could not be confirmed, although secondary...

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

CORROSION OF Fe-10Al-Cr ALLOYS BY COAL CHAR  

E-Print Network [OSTI]

off-gas from a typical gasifier contains large percentagesIOAl-Cr alloys at coal-gasifier This FeS and CaS0 operating

Gordon, B.A.

2011-01-01T23:59:59.000Z

382

Search for Resonant Absorption of Solar Axions Emitted in M1 Transition in $^{57}$Fe Nuclei  

E-Print Network [OSTI]

A search for resonant absorbtion of 14.4 keV solar axions by $^{57}$Fe target was performed. The Si(Li) detector placed inside the low-background setup was used to detect the $\\gamma$-quanta appearing in the deexcitation of 14.4 keV nuclear level: $A+\\rm{^{57}Fe} \\to \\rm{^{57}Fe^{*}} \\to \\rm{^{57}Fe} + \\gamma$. The new upper limit for the hadronic axion mass have been obtained: $m_{A} \\leq 151$ eV (90% C.L.) ($S$=0.5, $z$=0.56).

A. V. Derbin; A. I. Egorov; I. A. Mitropol'sky; V. N. Muratova; D. A. Semenov; E. V. Unzhakov

2009-06-01T23:59:59.000Z

383

CONTROL OF FE(III) SITE OCCUPANCY ON THE RATE AND EXTENT OF MICROBIAL REDUCTION OF FE(III) IN NONTRONITE  

SciTech Connect (OSTI)

A quantitative study was performed to understand how Fe(III) site occupancy controls Fe(III) bioreduction in nontronite by Shewanella putrefaciens CN32. NAu-1 and NAu-2 were nontronites and contained Fe(III) in different structure sites with 16% and 23% total iron (w/w), respectively, with almost all iron as Fe(III). Moessbauer spectroscopy showed that Fe(III) was present in the octahedral site in NAu-1 (with a small amount of goethite), but in both the tetrahedral and the octahedral sites in NAu-2. Moessbauer data further showed that the octahedral Fe(III) in NAu-2 existed in at least two environments- trans (M1) and cis (M2) sites. The microbial Fe(III) reduction in NAu-1 and NAu-2 was studied in batch cultures at a nontronite concentration of 5mg/mL in bicarbonate buffer with lactate as the electron donor. Fe(II) production in inoculated treatments was determined by extraction with 0.5 N HCl and compared to uninoculated controls to establish the extent of biological reduction. The resulting solids were characterized by X-ray diffraction (XRD), Moessbauer spectroscopy, and transmission electron microscopy (TEM). In the presence of an electron shuttle, anthraquinone-2,6-disulfonate (AQDS), the extent of bioreduction was 11-16% for NAu-1 but 28-32% for NAu-2. The extent of reduction in the absence of AQDS was only 5-7% in NAu-1 but 14-18% in NAu-2. The reduction rate was also faster in NAu-2 than that in NAu-1. Moessbauer data of the bioreduced nontronite materials indicated that the Fe(III) reduction in NAu-1 was mostly from the presence of goethite, whereas the reduction in NAu-2 was due to the presence of the tetrahedral and trans-octahedral Fe(III) in the structure. The measured aqueous Fe(II) was negligible [< 2.5% of the total biogenic Fe(II)]. As a result of bioreduction, the average nontronite particle thickness remained nearly the same (from 2.1 to 2.5 nm) for NAu-1, but decreased significantly from 6 to 3.5 nm for NAu-2 with a concomitant change in crystal size distribution. The decrease in crystal size suggests reductive dissolution of nontronite NAu-2, which was supported by aqueous solution chemistry (i.e., aqueous Si). These data suggest that the more extensive Fe(III) bioreduction in NAu-2 was due to the presence of the tetrahedral and the trans-octahedral Fe(III), which was presumed to be more reducible. The biogenic Fe(II) was not associated with biogenic solids such as siderite or green rust or in the aqueous solution. We infer that it may be either adsorbed onto surfaces of nontronite particles/bacteria and in the structure of nontronite. Furthermore, we have demonstrated that natural nontronite clays were capable of supporting cell growth even in non-growth medium, possibly due to presence of naturally existing nutrients in the nontronite clays. These results suggest that crystal chemical environment of Fe(III) is an important determinant in controlling the rate and extent of microbial reduction of Fe(III) in nontronite.

Jaisi, Deb P.; Kukkadapu, Ravi K.; Eberl, Dennis D.; Dong, Hailiang

2005-12-01T23:59:59.000Z

384

Proton spectroscopy of 48Ni, 46Fe, and 44Cr  

E-Print Network [OSTI]

Results of decay spectroscopy on nuclei in vicinity of the doubly magic 48Ni are presented. The measurements were performed with a Time Projection Chamber with optical readout which records tracks of ions and protons in the gaseous volume. Six decays of 48Ni including four events of two-proton ground-state radioactivity were recorded. An advanced reconstruction procedure yielded the 2p decay energy for 48Ni of Q2p = 1.29(4) MeV. In addition, the energy spectra of \\b{eta}-delayed protons emitted in the decays of 44Cr and 46Fe, as well as half-lives and branching ratios were determined. The results were found to be consistent with the previous measurements made with Si detectors. A new proton line in the decay of 44Cr corresponding to the decay energy of 760 keV is reported. The first evidence for the \\b{eta}2p decay of 46 Fe, based on one clear event, is shown.

M. Pomorski; M. Pfützner; W. Dominik; R. Grzywacz; A. Stolz; T. Baumann; J. S. Berryman; H. Czyrkowski; R. D?browski; A. Fija?kowska; T. Ginter; J. Johnson; G. Kami?ski; N. Larson; S. N. Liddick; M. Madurga; C. Mazzocchi; S. Mianowski; K. Miernik; D. Miller; S. Paulauskas; J. Pereira; K. P. Rykaczewski; S. Suchyta

2014-07-06T23:59:59.000Z

385

Postirradiation deformation of ferritic Fe-Cr binary alloys  

SciTech Connect (OSTI)

Six binary Fe-Cr alloys ranging from 3 to 18% chromium were irradiated in the form of miniature tensile specimens in the Fast Flux Test Facility and tested at room temperature. The irradiation conditions produced 7 to 30 dpa at 365 to 574{degrees}C. The major purpose of the experiment was to compare the behavior of these simple alloys with that of more complex commercial alloys, The tensile data obtained on these specimens at room temperature are discussed with appropriate fractographic and microstructural support. Previous studies on similar materials had revealed the presence of a feature typically exhibited in channel fractures: elongated voids were evident in shear bands of an irradiated and deformed TEM disk of a binary Fe-6Cr alloy. An additional purpose of the experiment was therefore to provide a better understanding of the potential contribution of channel fracture to deformation in ferritic alloys. No evidence for channel fracture was found, however. 14 refs., 6 figs., 2 tabs.

Hamilton, M.L.; Gelles, D.S.

1991-06-01T23:59:59.000Z

386

Interdiffusion Behavior of Aluminide Coatings on Fe-Base Alloys  

SciTech Connect (OSTI)

One of the potential degradation modes of oxidation-resistant iron aluminide coatings is the loss of Al from the coatings into Fe-base substrate alloys that typically contain no Al. To address this issue, interdiffusion between aluminide coatings and steel substrates was studied for times up to 10,000 h in the temperature range of 500-800 C. Coatings were synthesized in a laboratory chemical vapor deposition (CVD) reactor on representative commercial ferritic alloy Fe-9Cr-1Mo and type 304L austenitic stainless steel. The microstructural and compositional changes after diffusion anneals were examined in detail. An initial attempt to model the interdiffusion behavior was carried out by applying an existing software program COSIM (coating oxidation and substrate interdiffusion model). Complementary work was conducted using a simple mathematic model developed by Heckel et al. Reasonable agreement was observed between the simulated and experimental composition profiles for the aluminide coatings on ferritic alloys. Model results were then applied to predict coating lifetime.

Zhang, Ying [Tennessee Technological University; Liu, A. P. [Tennessee Technological University; Pint, Bruce A [ORNL

2007-01-01T23:59:59.000Z

387

Magnetization dynamics and interface studies in ion-beam sputtered Si/CoFeB(8)/MgO(4)/CoFeB(8)/Ta(5) structures  

SciTech Connect (OSTI)

The interface roughness, Boron distribution in bulk CoFeB and at interface, Gilbert damping constant (?), and inhomogeneous broadening in ion-beam sputtered Si/CoFeB(8)/MgO(4)/CoFeB(8)/Ta(5) structures are found to be sensitive to the MgO growth process. The ion-assist and reactive growth processes that result in sharper interfaces of width ?0.5?nm lead to smaller ? of 0.0050?±?0.0003 and 0.0060?±?0.0002 and inhomogeneous broadening ?H{sub 0} of 3?±?0.3 and 1?±?0.3?Oe, respectively. On the other hand, the post-oxidation method results in rough interface and higher retention of Boron in CoFeB leading to higher values for ? and ?H{sub 0} as 0.0080?±?0.0006 and 5?±?0.3?Oe, respectively.

Raju, M.; Behera, Nilamani; Pandya, Dinesh K., E-mail: dkpandya@physics.iitd.ac.in; Chaudhary, Sujeet [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India)

2014-05-07T23:59:59.000Z

388

Role of cross-shell excitations in the reaction 54Fe(d_pol,p)55Fe  

E-Print Network [OSTI]

The reaction 54Fe(d_pol,p)55Fe was studied at the Munich Q3D spectrograph with a 14 MeV polarized deuteron beam. Excitation energies, angular distributions and analyzing powers were measured for 39 states up to 4.5 MeV excitation energy. Spin and parity assignments were made and spectroscopic factors deduced by comparison to DWBA calculations. The results were compared to predictions by large scale shell model calculations in the full pf-shell and it was found that reasonable agreement for energies and spectroscopic factors below 2.5 MeV could only be obtained if up to 6 particles were allowed to be excited from the f_7/2 orbital into p_3/2, f_5/2, and p_1/2 orbitals across the N=28 gap. For levels above 2.5 MeV the experimental strength distribution was found to be significantly more fragmented than predicted by the shell model calculations.

M. Mahgoub; R. Kruecken; Th. Faestermann; A. Bergmaier; D. Bucurescu; R. Hertenberger; Th. Kroell; H. -F. Wirth; A. F. Lisetskiy

2009-01-13T23:59:59.000Z

389

A Twisted Ladder: Relating the Fe Superconductors to the High Tc Cuprates  

SciTech Connect (OSTI)

We construct a 2-leg ladder model of an Fe-pnictide superconductor and discuss its properties and relationship with the familiar 2-leg cuprate model. Our results suggest that the underlying pairing mechanism for the Fe-pnictide superconductors is similar to that for the cuprates.

Berg, E.

2010-05-26T23:59:59.000Z

390

Mapping magnetic fields of Fe3O4 nanosphere assemblies by electron holography  

E-Print Network [OSTI]

Magnetite (Fe3O4) nanocrystals have attracted much attention due to their unique magnetic properties, and bio-separation.1­3 Fe3O4 has also been demonstrated as an excellent storage material for lithium and mesocrystals, where magnetic interactions deter- mine the morphology.3 It is of great importance to identify

Rubloff, Gary W.

391

Large pyramid shaped single crystals of BiFeO{sub 3} by solvothermal synthesis method  

SciTech Connect (OSTI)

Synthesis parameters are optimized in order to grow single crystals of multiferroic BiFeO{sub 3}. 2 to 3 mm size pyramid (tetrahedron) shaped single crystals were successfully obtained by solvothermal method. Scanning electron microscopy with EDAX confirmed the phase formation. Raman scattering spectra of bulk BiFeO3 single crystals have been measured which match well with reported spectra.

Sornadurai, D.; Ravindran, T. R.; Paul, V. Thomas; Sastry, V. Sankara [Condensed Matter Physics Division, Materials Science Group, Physical Metallurgy Division, Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamil Nadu (India); Condensed Matter Physics Division, Materials Science Group (India)

2012-06-05T23:59:59.000Z

392

INVESTIGATION OF THE ELECTRICAL PROPERTIES OF METAL/PYRITE (FeS2) JUNCTIONS  

E-Print Network [OSTI]

cost was a factor and the unconventional solar cell candidates included: FeS2, CuO, and Zn3P2 (Wadia et al 2009:2702). For high volume production of solar panels, cheaper material for commercial use The nontoxic semiconductor pyrite FeS2 appeals to us as a good candidate for solar cells because it has a small

Hall, Sharon J.

393

High temperature magnetic properties of SmCo5/-Fe(Co) bulk nanocomposite magnets  

E-Print Network [OSTI]

-compaction route. Up to 30% of the Fe soft magnetic phase has been added to the composites with grain size (!150 C) are needed for applica- tions in advanced power systems, including electric vehicles and wind mill turbines.1,2 Nd2Fe14B-based magnets are the material of choice in systems where weight or size

Liu, J. Ping

394

FE Electrical Report 2005-2006 By: Chris Dudasik, Tianyi Li, and Jeff Schvey  

E-Print Network [OSTI]

, batteries, or general electrical theory, please see the Fe Electrical Team Report ­ Spring 2005 or the Fe the ground, the metal strip connected to the lever of the limit switch presses up against the case; this causes the signal wire to read +0v. When the foot is in the air, the strip is depressed and the signal

Ruina, Andy L.

395

NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS  

E-Print Network [OSTI]

Parr, J. Gordon, J. Iron and Steel Inst. B, vol. 283,137 (Properties of Fe-12Mn-0.2Ti Steel at -196°C Yield Stress (FREE Fe-12Mn-O. 2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

Hwang, S.

2010-01-01T23:59:59.000Z

396

Exchange bias and blocking temperature distribution of Fe-film/CoO-nanoparticle hybrid bilayers  

E-Print Network [OSTI]

relaxation in a Fe-film/CoO-nanoparticle hybrid system Appl. Phys. Lett. 101, 132401 (2012); 10 anisotropy energy per unit volume and V is the grain volume. Therefore, hybrid EB bilayers with the AF layer beExchange bias and blocking temperature distribution of Fe-film/CoO-nanoparticle hybrid bilayers Wei

Krishnan, Kannan M.

397

SCT&E LNG, LLC - FE Dkt. No. 14-98-LNG | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

FE Dkt. No. 14-98-LNG SCT&E LNG, LLC - FE Dkt. No. 14-98-LNG The Office of Fossil Energy gives notice of receipt of an Application filed July 24, 2014, by SCT&E LNG, LLC (SCT&E),...

398

Building the Santa Fe Artificial Stock Market Blake LeBaron  

E-Print Network [OSTI]

Building the Santa Fe Artificial Stock Market Blake LeBaron Brandeis University June 2002 Abstract This short summary presents an insider's look at the construction of the Santa Fe artificial stock of the directions that researchers have been taking is the use of agent-based financial markets. These "bottom- up

Tesfatsion, Leigh

399

Controllable synthesis, magnetic and biocompatible properties of Fe{sub 3}O{sub 4} and {alpha}-Fe{sub 2}O{sub 3} nanocrystals  

SciTech Connect (OSTI)

Iron oxide nanocrystals (NCs) with a series of well-controlled morphologies (octahedron, rod, wire, cube and plate) and compositions (Fe{sub 3}O{sub 4} and {alpha}-Fe{sub 2}O{sub 3}) were synthesized via a facile hydrothermal process. The morphological and compositional control of various iron oxide NCs was based on the regulations of precursor thermolysis kinetics and surfactants. The obtained samples were characterized by XRD, SEM, TEM, SQUID and cytotoxicity test. These as-prepared iron oxide NCs showed excellent magnetic properties and good biocompatibility, paving the way for their high-efficiency bio-separation and bio-detection applications. - Graphical Abstract: Schematic illustration for the formation of iron oxide NCs (Fe{sub 3}O{sub 4} and {alpha}-Fe{sub 2}O{sub 3}) with different controlled morphologies and compositions. Highlights: Black-Right-Pointing-Pointer Iron oxide NCs with a series of well-controlled morphologies (octahedron, rod, wire, cube, and plate) and compositions (Fe{sub 3}O{sub 4} and {alpha}-Fe{sub 2}O{sub 3}) were synthesized via a facile hydrothermal method. Black-Right-Pointing-Pointer The mechanism of the morphological and compositional control process is directly related to precursor thermolysis kinetics and surfactants. Black-Right-Pointing-Pointer These iron oxide NCs exhibited excellent magnetic response and good biocompatibility, which should have great applications in the cell separation and biodetection.

Zhou, Xi, E-mail: xizhou@xmu.edu.cn [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China)] [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China); Shi, Yanfeng; Ren, Lei [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China)] [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China); Bao, Shixiong [State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)] [State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China); Han, Yu; Wu, Shichao; Zhang, Honggang; Zhong, Lubin [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China)] [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China); Zhang, Qiqing, E-mail: zhangqiq@xmu.edu.cn [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China)] [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China)

2012-12-15T23:59:59.000Z

400

Tuning exchange bias in Fe/?-Fe{sub 2}O{sub 3} core-shell nanoparticles: Impacts of interface and surface spins  

SciTech Connect (OSTI)

A comparative study has been performed of the exchange bias (EB) effect in Fe/?-Fe{sub 2}O{sub 3} core-shell nanoparticles with the same thickness of the ?-Fe{sub 2}O{sub 3} shell (?2?nm) and the diameter of the Fe core varying from 4?nm to 11?nm. Transmission electron microscopy (TEM) and high-resolution TEM confirmed the high quality of the core-shell nanostructures. A systematic analysis of magnetization versus magnetic field measurements under zero-field-cooled and field-cooled regimes using the Meiklejohn-Bean model and deconvoluting superparamagnetic and paramagnetic contribution to the total magnetic moment Langevin function shows that there exists a critical particle size (?10?nm), above which the spins at the interface between Fe and ?-Fe{sub 2}O{sub 3} contribute primarily to the EB, but below which the surface spin effect is dominant. Our finding yields deeper insight into the collective contributions of interface and surface spins to the EB in core-shell nanoparticle systems, knowledge of which is the key to manipulating EB in magnetic nanostructures for spintronics applications.

Khurshid, Hafsa, E-mail: hkhurshi@usf.edu, E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu; Phan, Manh-Huong, E-mail: hkhurshi@usf.edu, E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu; Mukherjee, Pritish; Srikanth, Hariharan, E-mail: hkhurshi@usf.edu, E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu [Department of Physics, University of South Florida, Tampa, Florida 33620 (United States)

2014-02-17T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Nebular spectra and abundance tomography of the type Ia supernova SN 2011fe: a normal SN Ia with a stable Fe core  

E-Print Network [OSTI]

A series of optical and one near-infrared nebular spectra covering the first year of the Type Ia supernova SN 2011fe are presented and modelled. The density profile that proved best for the early optical/ultraviolet spectra, "rho-11fe", was extended to lower velocities to include the regions that emit at nebular epochs. Model rho-11fe is intermediate between the fast deflagration model W7 and a low-energy delayed-detonation. Good fits to the nebular spectra are obtained if the innermost ejecta are dominated by neutron-rich, stable Fe-group species, which contribute to cooling but not to heating. The correct thermal balance can thus be reached for the strongest [FeII] and [FeIII] lines to be reproduced with the observed ratio. The 56Ni mass thus obtained is 0.47 +/- 0.05 Mo. The bulk of 56Ni has an outermost velocity of ~8500 km/s. The mass of stable iron is 0.23 +/- 0.03 Mo. Stable Ni has low abundance, ~10^{-2} Mo. This is sufficient to reproduce an observed emission line near 7400 A. A sub-Chandrasekhar exp...

Mazzali, P A; Filippenko, A V; Garnavich, P M; Clubb, K I; Maguire, K; Pan, Y -C; Shappee, R; Silverman, J M; Benetti, S; Hachinger, S; Nomoto, K; Pian, E

2015-01-01T23:59:59.000Z

402

STORAGE RING CROSS-SECTION MEASUREMENTS FOR ELECTRON IMPACT SINGLE AND DOUBLE IONIZATION OF Fe{sup 9+} AND SINGLE IONIZATION OF Fe{sup 10+}  

SciTech Connect (OSTI)

We have measured electron impact ionization from the ground state of Fe{sup 9+} and Fe{sup 10+} over the relative electron-ion collision energy ranges 200-1900 eV and 250-1800 eV, respectively. The ions were confined in an ion storage ring long enough for essentially all metastable levels to radiatively relax to the ground state. For single ionization, we find a number of discrepancies between the existing theoretical cross sections and our results. The calculations appear to neglect some excitation-autoionization (EA) channels, particularly from n = 3 to n' excitations, which are important near threshold, and those from n = 2 {yields} 3 excitations, which contribute at about 650 eV. Conversely, at higher energies the calculations appear to overestimate the importance of EA channels due to excitation into levels where n {>=} 4. The resulting experimental rate coefficients agree with the most recent theory for Fe{sup 9+} to within 16% and for Fe{sup 10+} to within 19% at temperatures where these ions are predicted to form in collisional ionization equilibrium. We have also measured double ionization of Fe{sup 9+} forming Fe{sup 11+} in the energy range 450-3000 eV and found that although there is an appreciable cross section for direct double ionization, the dominant mechanism appears to be through direct ionization of an inner shell electron producing an excited state that subsequently stabilizes through autoionization.

Hahn, M.; Novotny, O.; Savin, D. W. [Columbia Astrophysics Laboratory, Columbia University, 550 West 120th Street, New York, NY 10027 (United States); Becker, A.; Grieser, M.; Krantz, C.; Wolf, A. [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany); Lestinsky, M.; Repnow, R. [GSI Helmholtzzentrum fuer Schwerionenforschung, Planckstr. 1, D-64291 Darmstadt (Germany); Mueller, A.; Schippers, S.; Spruck, K. [Institut fuer Atom- und Molekuelphysik, Justus-Liebig-Universitaet Giessen, Leihgesterner Weg 217, D-35392 Giessen (Germany)

2012-11-20T23:59:59.000Z

403

Intrinsic magnetic properties of hexagonal LuFeO{sub 3} and the effects of nonstoichiometry  

SciTech Connect (OSTI)

We used oxide molecular-beam epitaxy in a composition-spread geometry to deposit hexagonal LuFeO{sub 3} (h-LuFeO{sub 3}) thin films with a monotonic variation in the Lu/Fe cation ratio, creating a mosaic of samples that ranged from iron rich to lutetium rich. We characterized the effects of composition variation with x-ray diffraction, atomic force microscopy, scanning transmission electron microscopy, and superconducting quantum interference device magnetometry. After identifying growth conditions leading to stoichiometric film growth, an additional sample was grown with a rotating sample stage. From this stoichiometric sample, we determined stoichiometric h-LuFeO{sub 3} to have a T{sub N} = 147 K and M{sub s} = 0.018 ?{sub B}/Fe.

Moyer, Jarrett A., E-mail: moyerja@illinois.edu, E-mail: schlom@cornell.edu; Schiffer, Peter [Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Misra, Rajiv [Department of Physics, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Mundy, Julia A. [School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853 (United States); Brooks, Charles M.; Heron, John T. [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Muller, David A. [School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States); Schlom, Darrell G., E-mail: moyerja@illinois.edu, E-mail: schlom@cornell.edu [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States)

2014-01-01T23:59:59.000Z

404

Spreading of Sn-Ag solders on FeNi alloys  

SciTech Connect (OSTI)

The spreading of Sn-3Ag-xBi solders on Fe-42Ni has been studied using a drop transfer setup. Initial spreading velocities as fast as {approx}0.5 m/s have been recorded. The results are consistent with a liquid front moving on a metastable, flat, unreacted substrate and can be described by using a modified molecular-kinetic model for which the rate controlling step is the movement of one atom from the liquid to the surface of the solid substrate. Although the phase diagram predicts the formation of two Fe-Sn intermetallics at the solder/substrate interface in samples heated at temperatures lower than 513 C, after spreading at 250 C only a thin FeSn reaction layer could be observed. Two interfacial layers (FeSn and FeSn2) were found after spreading at 450 C.

Saiz, Eduardo; Hwang, C-W.; Suganuma, Katsuaki; Tomsia, Antoni P.

2003-02-28T23:59:59.000Z

405

FePt-based exchange-coupled composite perpendicular recording media.  

SciTech Connect (OSTI)

In order to demonstrate the strong and proper exchange coupling between bottom magnetic layer and capping magnetic layer in FePt-based exchange-coupled composite (ECC) perpendicular recording media, we have investigated the thermal stability, writability, degree of exchange coupling, and ECC gain factor of FePt-based ECC media as a function of the thickness of the capping FePt layer. With increasing the thickness of capping FePt layer, both thermal stability and media writability increase simultaneously as a result of the change from strong exchange coupling to proper exchange coupling. The proper exchange-coupled FePt ECC is a promising candidate for future high-density perpendicular recording.

Sun, C.; Stafford, D.; Acharya, R.; X-Ray Science Division; Western Digital Media

2010-06-01T23:59:59.000Z

406

Postirradiation deformation behavior in ferritic Fe-Cr alloys  

SciTech Connect (OSTI)

It has been demonstrated that fast neutron irradiation produces significant hardening in simple Fe(3-18)Cr binary alloys irradiated to about 35 dpa in the temperature range 365 to 420{degrees}C, whereas irradiation at 574{degrees}C produces hardening only for 15% or more chromium. The irradiation-induced changes in tensile properties are discussed in terms of changes in the power law work hardening exponent. The work hardening exponent of the lower chromium alloys decreased significantly after low temperature irradiation ({le}420{degrees}C) but increased after irradiation at 574{degrees}C. The higher chromium alloys failed either in cleavage or in a mixed ductile/brittle fashion. Deformation microstructures are presented to support the tensile behavior.

Hamilton, M.L.; Gelles, D.S. [Pacific Northwest Lab., Richland, VA (United States); Gardner, P.L. [Univ. of Missouri, Rolla (United States)

1992-12-31T23:59:59.000Z

407

Postirradiation deformation behavior in ferritic Fe-Cr alloys  

SciTech Connect (OSTI)

It has been demonstrated that fast-neutron irradiation produces significant hardening in simple Fe-(3-18)Cr binary alloys irradiated to about 35 dpa in the temperature range 365 to 420{degrees}C, whereas irradiation at 574{degrees}C produces hardening only for 15% or more chromium. The irradiation-induced changes in tensile properties are discussed in terms of changes in the power law work-hardening exponent. The work-hardening exponent of the lower chromium alloys decreased significantly after low-temperature irradiation ({le} 420{degrees}C) but increased after irradiation at 574{degrees}C. The higher chromium alloys failed either in cleavage or in a mixed ductile/brittle fashion. Deformation microstructures are presented to support the tensile behavior.

Hamilton, M.L.; Gelles, D.S. [Pacific Northwest Lab., Richland, WA (United States); Gardner, P.L. [Missouri Univ., Rolla, MO (United States)

1992-06-01T23:59:59.000Z

408

Postirradiation deformation behavior in ferritic Fe-Cr alloys  

SciTech Connect (OSTI)

It has been demonstrated that fast-neutron irradiation produces significant hardening in simple Fe-(3-18)Cr binary alloys irradiated to about 35 dpa in the temperature range 365 to 420[degrees]C, whereas irradiation at 574[degrees]C produces hardening only for 15% or more chromium. The irradiation-induced changes in tensile properties are discussed in terms of changes in the power law work-hardening exponent. The work-hardening exponent of the lower chromium alloys decreased significantly after low-temperature irradiation ([le] 420[degrees]C) but increased after irradiation at 574[degrees]C. The higher chromium alloys failed either in cleavage or in a mixed ductile/brittle fashion. Deformation microstructures are presented to support the tensile behavior.

Hamilton, M.L.; Gelles, D.S. (Pacific Northwest Lab., Richland, WA (United States)); Gardner, P.L. (Missouri Univ., Rolla, MO (United States))

1992-06-01T23:59:59.000Z

409

Development of FeNiMoB thin film materials for microfabricated magnetoelastic sensors  

SciTech Connect (OSTI)

Metglas{sup TM} 2826MB foils of 25-30 {mu}m thickness with the composition of Fe{sub 40}Ni{sub 38}Mo{sub 4}B{sub 18} have been used for magnetoelastic sensors in various applications over many years. This work is directed at the investigation of {approx}3 {mu}m thick iron-nickel-molybdenum-boron (FeNiMoB) thin films that are intended for integrated microsystems. The films are deposited on Si substrate by co-sputtering of iron-nickel (FeNi), molybdenum (Mo), and boron (B) targets. The results show that dopants of Mo and B can significantly change the microstructure and magnetic properties of FeNi materials. When FeNi is doped with only Mo its crystal structure changes from polycrystalline to amorphous with the increase of dopant concentration; the transition point is found at about 10 at. % of Mo content. A significant change in anisotropic magnetic properties of FeNi is also observed as the Mo dopant level increases. The coercivity of FeNi films doped with Mo decreases to a value less than one third of the value without dopant. Doping the FeNi with B together with Mo considerably decreases the value of coercivity and the out-of-plane magnetic anisotropy properties, and it also greatly changes the microstructure of the material. In addition, doping B to FeNiMo remarkably reduces the remanence of the material. The film material that is fabricated using an optimized process is magnetically as soft as amorphous Metglas{sup TM} 2826MB with a coercivity of less than 40 Am{sup -1}. The findings of this study provide us a better understanding of the effects of the compositions and microstructure of FeNiMoB thin film materials on their magnetic properties.

Liang Cai; Gooneratne, Chinthaka; Cha, Dongkyu; Chen Long; Kosel, Jurgen [Computer Electrical and Mathematical Sciences and Engineering, King Abdullah University of Science and Technology, 4700 KAUST, Thuwal 23955 (Saudi Arabia); Gianchandani, Yogesh [Department of Electrical Engineering and Computer Science, 1301 Beal Ave., University of Michigan, Ann Arbor, Michigan 48109 (United States)

2012-12-01T23:59:59.000Z

410

The Wide Field Spectrograph (WiFeS)  

E-Print Network [OSTI]

This paper describes the Wide Field Spectrograph (WiFeS) under construction at the Research School of Astronomy and Astrophysics (RSAA) of the Australian National University (ANU) for the ANU 2.3m telescope at the Siding Spring Observatory. WiFeS is a powerful integral field, double-beam, concentric, image-slicing spectrograph designed to deliver excellent thoughput, wavelength stability, spectrophotometric performance and superb image quality along with wide spectral coverage throughout the 320-950 nm wavelength region. It provides a 25x38 arcsec. field with 0.5 arcsec. sampling along each of twenty five 38X1 arcsec slitlets. The output format is optimized to match the 4096x4096 pixel CCD detectors in each of two cameras individually optimized for the blue and the red ends of the spectrum, respectively. A process of "interleaved nod-and-shuffle" will be applied to permit quantum noise-limited sky subtraction. Using VPH gratings, spectral resolutions of 3000 and 7000 are provided. The full spectral range is covered in a single exposure at R=3000, and in two exposures in the R=7000 mode. The use of transmissive coated optics, VPH gratings and optimized mirror coatings ensures a throughput (including telescope atmosphere and detector) > 30% over a wide spectral range. The concentric image-slicer design ensures an excellent and uniform image quality across the full field. To maximize scientific return, the whole instrument is configured for remote observing, pipeline data reduction, and the accumulation of calibration image libraries.

Michael Dopita; John Hart; Peter McGregor; Patrick Oates; Gabe Bloxham; Damien Jones

2007-05-02T23:59:59.000Z

411

Microsoft Word - BH-MM-746B NEPA.docx  

Broader source: Energy.gov (indexed) [DOE]

of water, soil, rock, or contaminants; and sampling and characterization of water effluents, air emissions, or solid waste streams. Electronic approval via NEPA Workflow 92313 ....

412

_PART I - THE SCHEDULE SECTION B-H  

National Nuclear Security Administration (NNSA)

the Performance Evaluation Plan (PEP) and its supporting documentation; and (iii) The balance, if any, upon issuance of the Contracting Officer's notification in accordance with...

413

_PART I - THE SCHEDULE SECTION B-H  

National Nuclear Security Administration (NNSA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartmentNationalRestart of the Review of theOFFICE OF CIVIL toRockyDECEMBER|About03/31/15

414

Microsoft Word - Dynamic Chemical Imaging at Nanoscale bh  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fundProject8 - Outline andPROPOSAL68R18Requiringof4 2.1Draft)

415

Microsoft Word - BH-MM-1038 NEPA.docx  

Broader source: Energy.gov (indexed) [DOE]

38 Title: Recondition and Repair BHTX-14 Transformer Description: Subcontractor shall provide all labor, supervision, tools, equipment, and transportation required to remanufacture...

416

Synthesis and magnetic properties of the double layer perovskite CeBaFe2O5+w  

E-Print Network [OSTI]

Synthesis and magnetic properties of the double layer perovskite CeBaFe2O5+w R. L. de Almeida,1 O The synthesis, crystallographic structure, and magnetic properties of polycrystalline single-phase samples of CeBaFe results on the successful prepara- tion and characterization of polycrystalline CeBaFe2O5+w samples. Ideal

de Lima, Oscar Ferreira

417

Removal of arsenic from effluents - a comparison between the FeSO{sub 4}/Air and FeSO{sub 4}/H{sub 2}O{sub 2} systems  

SciTech Connect (OSTI)

This paper reports the results of kinetic studies involving the precipitation of arsenic from aqueous solutions as FeAsO{sub 4} / Fe(OH){sub 3}, using FeSO{sub 4} as source of Fe ions, and Air or H{sub 2}O{sub 2} as oxidizing agents. Both systems lead to an efficient removal of arsenic. The differences in oxidants performances are in the precipitation reaction rate - much faster using hydrogen peroxide. Mechanisms of reactions were suggested based on the following main steps: Fe(II) oxidation: 2 Fe{sup 2+} + 1/2 O{sub 2} + 2 H{sup +} 2 Fe{sup 3+} + H{sub 2}O 2 Fe{sup 2+} + H{sub 2}O{sub 2} + 2 H{sup +}= 2 Fe{sup 3+} + 2 H{sub 2}O As(III) oxidation: HAsO{sub 2} + 2 Fe {sup 3+} + 2 H{sub 2}O = 2 Fe{sup 2+} + H{sub 3}AsO{sub 4} + 2H{sup +} HAsO{sub 2} + H{sub 2}O{sub 2} = H{sub 3}ASO{sub 4} Precipitation: Fe{sup 3+} + H{sub 3}AsO{sub 4} = FeASO{sub 4} (s) + 3 H{sup +} H{sub 3}AsO{sub 4} + n Fe(OH){sub 3} (s) = H{sub 3}ASO{sub 4} (ads) [Fe(OH){sub 3}]{sub n} (s). 15 refs., 7 figs.

Teixeira, L.A.; Kohler, H.M. [Catholic Univ. of Rio de Janeiro (Brazil); [Peroxidos do Brasil Ltda, S. Paulo (Brazil); Kohler, H.M. [Catholic Univ. of Rio de Janeiro (Brazil); Monteiro, A.G. [BHP Minerals, Reno, NV (United States)

1996-12-31T23:59:59.000Z

418

Approved Module Information for BH3328, 2014/5 Module Title/Name: Psychology and Work Module Code: BH3328  

E-Print Network [OSTI]

* Organizational culture, climate, and change * Applying the Psychology of Work and Organizations The learning communication Planning and organizing Interpersonal discussion and communication Indicative Module Content

Neirotti, Juan Pablo

419

Approved Module Information for BH2239, 2014/5 Module Title/Name: Psychology and Work Module Code: BH2239  

E-Print Network [OSTI]

culture, climate, and change * Applying the Psychology of Work and Organizations The learning outcomes * Academic writing skills * Critical reasoning * Written and oral communication * Planning and organizing * Interpersonal discussion and communication Indicative Module Content: * Introduction to Work and Organizational

Neirotti, Juan Pablo

420

Platinum Monolayer on IrFe Core–Shell Nanoparticle Electrocatalysts for the Oxygen Reduction Reaction  

SciTech Connect (OSTI)

We synthesized high activity and stability platinum monolayer on IrFe core-shell nanoparticle electrocatalysts. Carbon-supported IrFe core-shell nanoparticles were synthesized by chemical reduction and subsequent thermal annealing. The formation of Ir shells on IrFe solid-solution alloy cores has been verified by scanning transmission electron microscopy coupled with energy-loss spectroscopy (EELS) and in situ X-ray absorption spectroscopy. The Pt monolayers were deposited on IrFe core-shell nanoparticles by galvanic replacement of underpotentially deposited Cu adatoms on the Ir shell surfaces. The specific and Pt mass activities for the ORR on the Pt monolayer on IrFe core-shell nanoparticle electrocatalyst are 0.46 mA/cm{sup 2} and 1.1 A/mg{sub Pt}, which are much higher than those on a commercial Pt/C electrocatalyst. High durability of Pt{sub ML}/IrFe/C has also been demonstrated by potential cycling tests. These high activity and durability observed can be ascribed to the structural and electronic interaction between the Pt monolayer and the IrFe core-shell nanoparticles.

Sasaki K.; Kuttiyiel, K.A.; Su, D.; Adzic, R.R.

2012-04-19T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Hardness of FeB{sub 4}: Density functional theory investigation  

SciTech Connect (OSTI)

A recent experimental study reported the successful synthesis of an orthorhombic FeB{sub 4} with a high hardness of 62(5) GPa [H. Gou et al., Phys. Rev. Lett. 111, 157002 (2013)], which has reignited extensive interests on whether transition-metal borides compounds will become superhard materials. However, it is contradicted with some theoretical studies suggesting transition-metal boron compounds are unlikely to become superhard materials. Here, we examined structural and electronic properties of FeB{sub 4} using density functional theory. The electronic calculations show the good metallicity and covalent Fe–B bonding. Meanwhile, we extensively investigated stress-strain relations of FeB{sub 4} under various tensile and shear loading directions. The calculated weakest tensile and shear stresses are 40 GPa and 25 GPa, respectively. Further simulations (e.g., electron localization function and bond length along the weakest loading direction) on FeB{sub 4} show the weak Fe–B bonding is responsible for this low hardness. Moreover, these results are consistent with the value of Vickers hardness (11.7–32.3 GPa) by employing different empirical hardness models and below the superhardness threshold of 40 GPa. Our current results suggest FeB{sub 4} is a hard material and unlikely to become superhard (>40 GPa)

Zhang, Miao; Du, Yonghui; Gao, Lili [Department of Physics, Beihua University, Jilin 132013 (China)] [Department of Physics, Beihua University, Jilin 132013 (China); Lu, Mingchun [Department of Aeronautical Engineering Professional Technology, Jilin Institute of Chemical Technology, Jilin 132102 (China)] [Department of Aeronautical Engineering Professional Technology, Jilin Institute of Chemical Technology, Jilin 132102 (China); Lu, Cheng [Department of Physics, Nanyang Normal University, Nanyang 473061 (China)] [Department of Physics, Nanyang Normal University, Nanyang 473061 (China); Liu, Hanyu, E-mail: hal420@mail.usask.ca [Department of Physics and Engineering Physics, University of Saskatchewan, Saskatoon, Saskatchewan S7N 5E2 (Canada)] [Department of Physics and Engineering Physics, University of Saskatchewan, Saskatoon, Saskatchewan S7N 5E2 (Canada)

2014-05-07T23:59:59.000Z

422

NdBaFe{sub 2}O{sub 5+w} and steric effect of Nd on valence mixing and ordering of Fe  

SciTech Connect (OSTI)

NdBaFe{sub 2}O{sub 5} above and below Verwey transition is studied by synchrotron X-ray powder diffraction and Moessbauer spectroscopy and compared with GdBaFe{sub 2}O{sub 5} that adopts a higher-symmetry charge-ordered structure typical of the Sm-Ho variants of the title phase. Differences are investigated by Moessbauer spectroscopy accounting for iron valence states at their local magnetic and ionic environments. In the charge-ordered state, the orientation of the electric-field gradient (EFG) versus the internal magnetic field (B) agrees with experiment only when contribution from charges of the ordered d{sub xz} orbitals of Fe{sup 2+} is included, proving thus the orbital ordering. The EFG magnitude indicates that only some 60% of the orbital order occurring in the Sm-Ho variants is achieved in NdBaFe{sub 2}O{sub 5}. The consequent diminishing of the orbit contribution (of opposite sign) to the field B at the Fe{sup 2+} nucleus explains why B is larger than for the Sm-Ho variants. The decreased orbital ordering in NdBaFe{sub 2}O{sub 5} causes a corresponding decrease in charge ordering, which is achieved by decreasing both the amount of the charge-ordered iron states in the sample and their fractional valence separation as seen by the Moessbauer isomer shift. The charge ordering in NdBaFe{sub 2}O{sub 5+w} is more easily suppressed by the oxygen nonstoichiometry (w) than in the Sm-Ho variants. Also the valence mixing into Fe{sup 2.5+} is destabilized by the large size of Nd. The orientation of the EFG around this valence-mixed iron can only be accounted for when the valence-mixing electron is included in the electrostatic ligand field. This proves that the valence mixing occurs between the two iron atoms facing each other across the structural plane of the rare-earth atoms. -- Graphical Abstract: Moessbauer spectrum detects ordering of d{sub xz} orbitals of Fe{sup II}O{sub 5} via the electric-field gradient (EFG) of the orbital, which makes the main component of the total EFG parallel with the magnetic moment B. Display Omitted

Linden, J. [Department of Physics, AAbo Akademi, FI-20500 Turku (Finland); Karen, P., E-mail: pavel.karen@kjemi.uio.n [Department of Chemistry, University of Oslo, P.O.Box 1033, Blindern, N-0315 Oslo (Norway)

2010-11-15T23:59:59.000Z

423

Size dependent structural, vibrational and magnetic properties of BiFeO{sub 3} and core-shell structured BiFeO{sub 3}@SiO{sub 2} nanoparticles  

SciTech Connect (OSTI)

Bulk BiFeO{sub 3}, BiFeO{sub 3} nanoparticles and core-shell structured BiFeO{sub 3}@SiO{sub 2} nanoparticles were synthesized by solid state reaction method, sol-gel and Stöber process (SiO{sub 2} shell) respectively. Transmission electron microscopy image confirmed the core-shell structure of BiFeO{sub 3}@SiO{sub 2} nanoparticles with BiFeO3 core ?50-90 nm and SiO{sub 2} shell ?16 nm. X-ray diffraction and FTIR spectroscopy results showed the presence of distorted rhombohedral structure with R3c space group in all three samples. The magnetic measurement indicated the existence of room-temperature weak ferromagnetism in core-shell BiFeO{sub 3}@SiO{sub 2} nanoparticles and BiFeO3 nanoparticles, whereas bulk BiFeO{sub 3} showed antiferromagnteic nature. Electron Spin Resonance results confirmed the enhancement in magnetic properties of coreshell structured BiFeO{sub 3}@SiO{sub 2} nanoparticles in comparison with BiFeO{sub 3} nanoparticles and bulk BiFeO{sub 3}.

Chauhan, Sunil, E-mail: sunilchauhanjiit@gmail.com; Kumar, Manoj, E-mail: sunilchauhanjiit@gmail.com; Chhoker, Sandeep, E-mail: sunilchauhanjiit@gmail.com; Katyal, S. C., E-mail: sunilchauhanjiit@gmail.com [Department of Physics and Materials Science and Engineering, Jaypee Institute of Information Technology, Noida- 201307 (India)

2014-04-24T23:59:59.000Z

424

Enhancement of exchange bias and training effect in ion-beam sputtered Fe{sub 46}Mn{sub 54}/Ni{sub 81}Fe{sub 19} bilayers  

SciTech Connect (OSTI)

We present a remarkable enhancement by 300% of the exchange-bias field at room temperature, without affecting the coercivity value, via optimum magnetic annealing (250?°C/3 kOe) in ion-beam sputtered FeMn(30?nm)/NiFe(10?nm) bilayers. This specific behavior has been attributed to a higher degree of ?-FeMn(111) orientation that offers more interfacial FeMn moments to get pinned with the moments of the adjacent NiFe layer. Unlike the absence of training effect at room temperature, a pronounced training effect and an accompanying magnetization reversal asymmetry are evidenced upon field cooling below 50?K due to the presence of biaxial exchange induced anisotropy across the interdiffused FeMn/NiFe interface. The present findings not only have technological significance but also are of relevance to the understanding of interfacial spin disorder and frustration in these exchange-biased systems.

Fulara, Himanshu; Chaudhary, Sujeet, E-mail: sujeetc@physics.iitd.ac.in; Kashyap, Subhash C. [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India); Granville, Simon [Callaghan Innovation, PO Box 31310, Lower Hutt 5040 (New Zealand); The MacDiarmid Institute for Advanced Materials and Nanotechnology, Lower Hutt (New Zealand)

2014-01-28T23:59:59.000Z

425

A Minimal Two-band Model for the Superconducting Fe-pnictides  

SciTech Connect (OSTI)

Following the discovery of the Fe-pnictide superconductors, LDA band structure calculations showed that the dominant contributions to the spectral weight near the Fermi energy came from the Fe 3d orbitals. The Fermi surface is characterized by two hole surfaces around the {Lambda} point and two electron surfaces around the M point of the 2 Fe/cell Brillouin zone. Here, we describe a 2-band model that reproduces the topology of the LDA Fermi surface and exhibits both ferromagnetic and q = ({pi}, 0) spin density wave (SDW) fluctuations. We argue that this minimal model contains the essential low energy physics of these materials.

Raghu, S.

2010-03-25T23:59:59.000Z

426

A theoretical study of the electronic structure of Invar Fe*3Pt and related materials  

SciTech Connect (OSTI)

The Full Potential Linear Augmented Plane Wave (FPLAPW or FLAPW) method is used for a spin-polarized band calculation for ordered Fe{sub 3}Pt. As major purpose, the momentum distributions of the spin-polarized electrons are calculated and compared with results from a magnetic Compton scattering measurement. To get related information, the electronic behavior is also analyzed by examining the partial densities of states and the spatial electron distributions; the role of alloying effects is then explored by studying the electrons in some related alloys: Fe{sub 3}Ni, Fe{sub 3}Pd, Ni{sub 3}Pt and Co{sub 3}Pt.

Zuo, Zhiqi

1997-01-10T23:59:59.000Z

427

Cyclic voltammetric study of Co-Ni-Fe alloys electrodeposition in sulfate medium  

SciTech Connect (OSTI)

Electrochemical technique has been used to study the electrodeposition of cobalt, nickel, iron and Co-Ni-Fe alloy on indium tin oxide (ITO) coated glass substrate. To obtain the nucleation mechanism, cyclic voltammetry is used to characterize the Co-Ni-Fe system. The scanning rate effect on the deposition process was investigated. Deposition of single metal occurs at potential values more positive than that estimated stability potential. Based on the cyclic voltammetry results, the electrodeposition of cobalt, nickel, iron and Co-Ni-Fe alloy clearly show that the process of diffusion occurs is controlled by the typical nucleation mechanism.

Hanafi, I.; Daud, A. R.; Radiman, S. [Material Science Program, School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia)

2013-11-27T23:59:59.000Z

428

Influence of surface segregation on magnetic properties of FePt nanoparticles  

SciTech Connect (OSTI)

Surface segregation leads to chemical disordering in magnetic alloy nanostructures and thus could have profound impact upon the magnetic properties of these nanostructures. In this study, we used the first-principles density functional theory calculation method to determine how Pt surface segregation (exchanging interior Pt with surface Fe atoms) would affect the magnetic properties of L1{sub 0} ordered FePt nanoparticles. For both cuboid and cuboctahedral FePt nanoparticles, we predicted that the Pt surface segregation process could cause a decrease in total magnetic moments, a change in (easy and/or hard) magnetization axes, and a reduction in magnetic anisotropy.

Lv, Hongyan [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States) [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States); Key Laboratory of Artificial Micro- and Nano-Structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Lei, Yinkai; Datta, Aditi; Wang, Guofeng [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States)] [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States)

2013-09-23T23:59:59.000Z

429

Nickel recovery from electronic waste II Electrodeposition of Ni and Ni–Fe alloys from diluted sulfate solutions  

SciTech Connect (OSTI)

Highlights: • Ni can be recovered from EG wastes as pure Ni or as Ni–Fe alloys. • The control of the experimental conditions gives a certain alloy composition. • Unusual deposits morphology shows different nucleation mechanisms for Ni vs Fe. • The nucleation mechanism was progressive for Ni and instantaneous for Fe and Ni–Fe. - Abstract: This study focuses on the electrodeposition of Ni and Ni–Fe alloys from synthetic solutions similar to those obtained by the dissolution of electron gun (an electrical component of cathode ray tubes) waste. The influence of various parameters (pH, electrolyte composition, Ni{sup 2+}/Fe{sup 2+} ratio, current density) on the electrodeposition process was investigated. Scanning electron microscopy (SEM) and X-ray fluorescence analysis (XRFA) were used to provide information about the obtained deposits’ thickness, morphology, and elemental composition. By controlling the experimental parameters, the composition of the Ni–Fe alloys can be tailored towards specific applications. Complementarily, the differences in the nucleation mechanisms for Ni, Fe and Ni–Fe deposition from sulfate solutions have been evaluated and discussed using cyclic voltammetry and potential step chronoamperometry. The obtained results suggest a progressive nucleation mechanism for Ni, while for Fe and Ni–Fe, the obtained data points are best fitted to an instantaneous nucleation model.

Robotin, B. [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, RO-400028 Cluj-Napoca (Romania); Ispas, A. [Fachgebiet Elektrochemie und Galvanotechnik II, Technische Universität Ilmenau, D-98693 Ilmenau (Germany); Coman, V. [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, RO-400028 Cluj-Napoca (Romania); Bund, A. [Fachgebiet Elektrochemie und Galvanotechnik II, Technische Universität Ilmenau, D-98693 Ilmenau (Germany); Ilea, P., E-mail: pilea@chem.ubbcluj.ro [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, RO-400028 Cluj-Napoca (Romania)

2013-11-15T23:59:59.000Z

430

High temperature oxidation behavior of Fe-Cr-Al foils  

SciTech Connect (OSTI)

Metallic catalytic converters for automotive emission control is becoming an important application for heat resistant alloys as more design opportunities are realized. The service conditions and design of metallic catalytic converters require the alloy to be highly oxidation resistant at gauges typically at 50 microns or less. For conventional heat resistant alloy design the goal is to form a well adherent scale on the alloy surface to protect the alloy matrix from being oxidized. However, the thin gauge results in a limited supply of alloying elements that can form the protective scale on the surface. The alloy chemistry has to be optimized to have the minimum oxidation while maintaining processing characteristics. Furthermore, the ratio of scale thickness to foil gauge is significant and the stress state between them introduces measurable permanent distortion of the foil. In this study, the effect of alloying elements on the oxidation behavior of commonly used Fe-Cr-Al alloys was quantified by the oxidation weight gain and length change measurements.

Chang, C.S.; Jha, B. [Texas Instruments, Inc., Attleboro, MA (United States)

1998-12-31T23:59:59.000Z

431

Air Flow North America Corp. – FE Dkt. No. 14-53-LNG (Re-export)  

Broader source: Energy.gov [DOE]

The Office of Fossil Energy (FE) of the Department of Energy (DOE) gives notice of receipt of an application filed on March 25, 2014, by Air Flow North America Corp. (AIR FLOW) requesting short...

432

E-Print Network 3.0 - automatic 3d fe Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

under FT3 4 conditions... and is rapidly converted to -Fe C. Activation with carbon monoxide or syngas2.2 with low ... Source: Kentucky, University of - Center for Applied Energy...

433

CORROSION OF Fe-10Al-Cr ALLOYS BY COAL CHAR  

E-Print Network [OSTI]

owned rights. LBL-6946 Corrosion of Fe-lOAl-Cr Alloys byOctober, 1977 Abstract Corrosion of iron-base alloys at 982°high-temperature induced corrosion are probably sulfides and

Gordon, B.A.

2011-01-01T23:59:59.000Z

434

FE's Advanced Combustion R&D Seeks Innovative Ways to Lower Cost...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

capture is a key to the commercial deployment of CCS. Housed under the multi-pronged Carbon Capture and Storage and Power Systems program, the Office of Fossil Energy (FE) has...

435

E-Print Network 3.0 - austenitic fe-cr-ni alloys Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

than at 650C. Therefore, for these Fe-Cr-Ni model alloys, increasing... Figure 5 shows LM of the samples after 100x1h cycles at 650C for representative ... Source: Pint, Bruce...

436

Evaluation of Quasicrystal Al-Cu-Fe Alloys for Tribological Applications  

E-Print Network [OSTI]

This research investigated the tribological performance of a composite material, formed from an ultra high molecular weight polyethylene (UHMWPE) matrix and quasicrystalline Al-Cu-Fe alloy powders. An evaluation was conducted for the microstructure...

Nabelsi, Nezar

2013-07-22T23:59:59.000Z

437

Co-synthesis of LiFePO4 and Carbon Nanotubes  

E-Print Network [OSTI]

as low as 0.1% have been reported for nanotubes in epoxy. 8of LiFePO 4 and carbon nanotubes potentially bypassesthat multi-walled carbon nanotubes (MWCNTs, Figure 1) and

Wilcox, James; Doeff, Marca M.

2006-01-01T23:59:59.000Z

438

Pressure tuning of competing magnetic interactions in intermetallic CeFe2  

SciTech Connect (OSTI)

We use high-pressure magnetic x-ray diffraction and numerical simulation to determine the low-temperature magnetic phase diagram of stoichiometric CeFe2. Near 1.5 GPa we find a transition from ferromagnetism to antiferromagnetism, accompanied by a rhombohedral distortion of the cubic Laves crystal lattice. By comparing pressure and chemical substitution we find that the phase transition is controlled by a shift of magnetic frustration from the Ce-Ce to the Fe-Fe sublattice. Notably the dominant Ce-Fe magnetic interaction, which sets the temperature scale for the onset of long-range order, remains satisfied throughout the phase diagram but does not determine the magnetic ground state. Our results illustrate the complexity of a system with multiple competing magnetic energy scales and lead to a general model for magnetism in cubic Laves phase intermetallic compounds.

Wang, Jiyang; Feng, Yejun; Jaramillo, R.; van Wezel, Jasper; Canfield, Paul C.; Rosenbaum, T.F.

2012-07-20T23:59:59.000Z

439

Reactivity of nanocolloidal particles -Fe2O3 at charged interfaces: 2-Electrochemical conversion.  

E-Print Network [OSTI]

, convection, migration, and the charge transfer depending on the redox potential of the species by methyl viologen), nanoparticles of hematite and goethite (-FeOOH: d = 50 nm) are invo

Boyer, Edmond

440

Mass Measurements of Proton-Rich Nuclei Fe-50 and Ni-54  

E-Print Network [OSTI]

, and target thicknesses determined the Q-value scales shown in Fig. 2. The resulting Q values and mass excesses (all in MeV) are Q("Fe) =-50..95+0.06, M(SOFe) =-34.48+0.06 and Q("Ni) = -50.19+0.05, M("Ni) =-39.21 +0.05, with the mass results based on a... Station, Texas 77843 {Received 6 December 1976) The reactions "Fe{'He,'He)' Fe and "Ni{'He,'He)"Ni have been observed at an incident a energy of 110 MeV. The reaction Q values are found to be Q{ Fe) = ?50.95 + 0.06 MeV and Q{' Ni) = ?50.19 + 0.05 Me...

Tribble, Robert E.; Cossairt, J. D.; May, D. P.; Kenefick, R. A.

1977-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

E-Print Network 3.0 - atlas fe-i4 pixel Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

pixel Search Powered by Explorit Topic List Advanced Search Sample search results for: atlas fe-i4 pixel Page: << < 1 2 3 4 5 > >> 1 Joint ATLASCMS SLHC Opto WG 1 March 5, 2010...

442

Cheniere Marketing, LLC – FE Dkt. No. 14-31-LNG (Re-export)  

Broader source: Energy.gov [DOE]

The Office of Fossil Energy (FE) of the Department of Energy (DOE) gives notice of receipt of an Application filed on March 7, 2014, by Cheniere Marketing, LLC (CMI), requesting blanket...

443

A Biophysical Approach to Investigate the Human Fe-S Cluster Assembly Pathway  

E-Print Network [OSTI]

Iron sulfur (Fe-S) clusters are essential cofactors that function in electron transport, catalyzing substrate turnover, environmental sensing, and initiating radical chemistry. Elaborate multi-component systems have evolved to protect organisms from...

Fox, Nicholas G

2014-06-02T23:59:59.000Z

444

Impact of Fe (III) on the Performance of Viscoelastic Surfactant-Based Acids  

E-Print Network [OSTI]

Viscoelastic surfactant (VES)-based acid systems have been used successfully in matrix and acid fracturing treatments. However, the existence of Fe (III) as a contaminant in such systems may lead to many problems, due to interactions between VES...

Shu, Yi

2013-08-02T23:59:59.000Z

445

E-Print Network 3.0 - al mg fe Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mg2+ . Experiments on phyllosilicates have... -rich specimens. Muller et al. (1997) observed that Mg and Fe form clusters that segregate fromAl in the Camp... that ... Source:...

446

Accelerated Thermal Aging of Fe-Zeolite SCR Catalysts Using an...  

Broader source: Energy.gov (indexed) [DOE]

Thermal Aging of Fe-Zeolite SCR Catalysts Using an Engine-based Systems Approach Poster P Poster P - - 2 2, Wednesday Bruce Bunting and Todd Toops Oak Ridge National Laboratory...

447

Charge transfer in Fe-doped GaN: The role of the donor  

SciTech Connect (OSTI)

Several nitride-based device structures would benefit from the availability of high quality, large-area, freestanding semi-insulating GaN substrates. Due to the intrinsic n-type nature of GaN, however, the incorporation of compensating centers such as Fe is necessary to achieve the high resistivity required. We are using electron paramagnetic resonance (EPR) to explore charge transfer in 450 um thick GaN:Fe plates to understand the basic mechanisms related to compensation so that the material may be optimized for device applications. The results suggest that the simple model based on one shallow donor and a single Fe level is insufficient to describe compensation. Rather, the observation of the neutral donor and Fe3+ indicates that either the two species are spatially segregated or additional compensating and donor defects must be present.

Sunay, Ustun; Dashdorj, J.; Zvanut, M. E.; Harrison, J. G. [Department of Physics, University of Alabama at Birmingham, 1300 University Blvd., CH 310, Birmingham, Alabama 35294-1170 (United States); Leach, J. H.; Udwary, K. [Kyma Technologies, 8829 Midway West Rd., Raleigh, North Carolina 27617 (United States)

2014-02-21T23:59:59.000Z

448

SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT...  

Broader source: Energy.gov (indexed) [DOE]

111-LNG - ORDER 2961 & 2961-A SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 10-111-LNG - ORDER 2961 & 2961-A April 2011 October 2011 April 2012 October 2012...

449

Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

1-161-LNG Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE Dkt. No. 11-161-LNG On November 15, 2013, the Office of Fossil Energy of the Department of Energy (DOEFE)...

450

SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT...  

Broader source: Energy.gov (indexed) [DOE]

85-LNG - ORDER 2833 SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 10-85-LNG - ORDER 2833 April 2011 October 2011 April 2012 October 2012 April 2013 October...

451

Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

0-161-LNG Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE Dkt. No. 10-161-LNG On May 17, 2013, the Office of Fossil Energy of the Department of Energy (DOEFE) issued...

452

Bioavailability of Fe(III) in Loess Sediments: An Important Source...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fe(III) in loess as the sole electron acceptor in the presence and absence of anthraquinone-2, 6-disulfonate (AQDS) as an electron shuttle. Experiments were performed in...

453

Absence of long-range chemical ordering in equimolar FeCoCrNi  

SciTech Connect (OSTI)

Equimolar FeCoCrNi alloys have been the topic of recent research as 'high-entropy alloys,' where the name is derived from the high configurational entropy of mixing for a random solid solution. Despite their name, no systematic study of ordering in this alloy system has been performed to date. Here, we present results from anomalous x-ray scattering and neutron scattering on quenched and annealed samples. An alloy of FeNi{sub 3} was prepared in the same manner to act as a control. Evidence of long-range chemical ordering is clearly observed in the annealed FeNi{sub 3} sample from both experimental techniques. The FeCoCrNi sample given the same heat treatment lacks long-range chemical order.

Lucas, M. S. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); UTC Inc., 1270 North Fairfield Road, Dayton, Ohio 45432 (United States); Wilks, G. B.; Senkov, O. N. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); UES, Inc., 4401 Dayton-Xenia Rd., Dayton, Ohio 45432 (United States); Mauger, L.; Munoz, J. A. [California Institute of Technology, W. M. Keck Laboratory 138-78, Pasadena, California 91125 (United States); Michel, E. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); Wright State University, Dayton, Ohio 45435 (United States); Horwath, J.; Semiatin, S. L. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); Stone, M. B.; Abernathy, D. L. [Oak Ridge National Laboratory, 1, Bethel Valley Road, Oak Ridge, Tennessee 37831 (United States); Karapetrova, E. [Argonne National Laboratory, Argonne, Illinois 60439 (United States)

2012-06-18T23:59:59.000Z

454

Absence of long-range chemical ordering in equimolar FeCoCrNi  

SciTech Connect (OSTI)

Equimolar FeCoCrNi alloys have been the topic of recent research as high-entropy alloys, where the name is derived from the high configurational entropy of mixing for a random solid solution. Despite their name, no systematic study of ordering in this alloy system has been performed to date. Here we present results from anomalous x-ray scattering and neutron scattering on quenched and annealed samples. An alloy of FeNi3 was prepared in the same manner to act as a control. Evidence of longrange chemical ordering is clearly observed in the annealed FeNi3 sample from both experimental techniques. The FeCoCrNi sample given the same heat treatment lacks long-range chemical order.

Lucas, Matthew [Air Force Research Laboratory, Wright-Patterson AFB, OH; Wilks, G B [Air Force Research Laboratory, Wright-Patterson AFB, OH; Mauger, L [W. M. Keck Laboratory, Pasadena, CA; Munoz, Jorge A. [California Institute of Technology, Pasadena; Senkov, Oleg [ORNL; Michel, E [Air Force Research Laboratory, Wright-Patterson AFB, OH; Horwath, J [Air Force Research Laboratory, Wright-Patterson AFB, OH; Semiatin, S L [Air Force Research Laboratory, Wright-Patterson AFB, OH; Stone, Matthew B [ORNL; Abernathy, Douglas L [ORNL; Karapetrova, Evgenia [University of Illinois, Urbana-Champaign

2012-01-01T23:59:59.000Z

455

SPECTROPHOTOMETRIC DETERMINATION OF Fe IN DRINKING WATER Background Reading: Harris, 7th  

E-Print Network [OSTI]

SPECTROPHOTOMETRIC DETERMINATION OF Fe IN DRINKING WATER Background Reading: Harris, 7th ed., Chap contaminants in drinking water can be determined spectrophotometrically, including iron. Although iron the iron content of drinking water to

Weston, Ken

456

E-Print Network 3.0 - al cr fe Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IEEE TRANSACTIONS ON MAGNETICS, VOL. 43, NO. 6, JUNE 2007 Valence States of Transition-Metal Ions and Electronic Summary: -Metal Ions and Electronic Structures of Spinel Fe1 Cu...

457

Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geochemical Behaviour of S, Cl and Fe in Silicate MeltsGlasses Simulating Natural Magmas Monday, March 26, 2012 - 11:00am SSRL Conference Room 137-322 G. Giuli, R. Alonso-Mori, E....

458

2002 Blackwell Science Ltd Reduction of Fe(III) oxide by methanogens in the  

E-Print Network [OSTI]

electrons to extracellular quinones such as humic acids and the humic acid analogue anthraquinone- 2 anthraquinone-2,6-disulphonate (AQDS). Two species (M. barkeri and M. voltaei) reduced significant amounts of Fe

Lovley, Derek

459

Bioreduction of Fe-bearing clay minerals and their reactivity toward pertechnetate (Tc-99)  

SciTech Connect (OSTI)

99Technetium (99Tc) is a fission product of uranium-235 and plutonium-239 and poses a high environmental hazard due to its long half-life (t1/2 = 2.13 x 105 y), abundance in nuclear wastes, and environmental mobility under oxidizing conditions [i.e., Tc(VII)]. Under reducing conditions, Tc(VII) can be reduced to insoluble Tc(IV). Ferrous iron [Fe(II)], either in aqueous form or in mineral form, has been used to reduce Tc(VII) to Tc(IV). However, the reactivity of Fe(II) from clay minerals, other than nontronite, toward immobilization of Tc(VII) and its role in retention of reduced Tc(IV) have not been investigated. In this study the reactivity of a suite of clay minerals toward Tc(VII) reduction and immobilization was evaluated. The clay minerals chosen for this study included five members in the smectite-illite (S-I) series, (montmorillonite, nontronite, rectorite, mixed layered I-S, and illite), chlorite, and palygorskite. Fe-oxides were removed from these minerals with a modified dithionite-citrate-bicarbonate (DCB) procedure. The total Fe content of these clay minerals, after Fe-oxide removal, ranged from 0.7 to 30.4% by weight, and the Fe(III)/Fe(total) ratio ranged from 44.9 to 98.5%. X-ray diffraction (XRD) and Mössbauer spectroscopy results showed that after Fe oxide removal the clay minerals were free of Fe-oxides. Scanning electron microscopy (SEM) revealed that little dissolution occurred during the DCB treatment. Bioreduction experiments were performed in bicarbonate buffer (pH-7) with Fe(III) in the clay minerals as the sole electron acceptor, lactate as the sole electron donor, and Shewanella Putrifaciens CN32 cells as mediators. In select tubes, anthraquinone-2,6-disulfate (AQDS) was added as electron shuttle to facilitate electron transfer. The extent of Fe(III) bioreduction was the highest for chlorite (~43 wt%) and the lowest for palygorskite (~4.17 wt%). In the S-I series, NAu-2 was the most reducible (~31 %) and illite the least (~0.4 %). The extent and initial rate of bioreduction were positively correlated with the percent smectite in the S-I series (i.e., layer expandability). Fe(II) in the bioreduced clay minerals subsequently was used to reduce Tc(VII) to Tc(IV) in PIPES buffer. Similar to the trend of bioreduction, in the S-I series, reduced smectite showed the highest reactivity toward Tc(VII), and reduced illite exhibited the least. The initial rate of Tc(VII) reduction, after normalization to clay and Fe(II) concentrations, was positively correlated with the percent smectite in the S-I series. Fe(II) in chlorite and palygorskite was also reactive toward Tc(VII) reduction. These data demonstrate that crystal chemical parameters (layer expandability, Fe and Fe(II) contents, and surface area etc.) play important roles in controlling the extent and rate of bioreduction and the reactivity toward Tc(VII) reduction. Reduced Tc(IV) resides within clay mineral matrix, and this association could minimize any potential of reoxidation over long term.

Bishop, Michael E.; Dong, Hailiang; Kukkadapu, Ravi K.; Liu, Chongxuan; Edelmann, Richard E.

2011-07-01T23:59:59.000Z

460

CORROSION OF Fe-10Al-Cr ALLOYS BY COAL CHAR  

E-Print Network [OSTI]

Potent.ials Encountered in Coal Conversion Systems", NASA TNof Illinois #6 ash and coal char. Figure 1. Cross sectionsof Fe-lOAl-Cr Alloys by Coal Char B. A. Gordon and V.

Gordon, B.A.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bh fe ru" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Strain relaxation and enhanced perpendicular magnetic anisotropy in BiFeO{sub 3}:CoFe{sub 2}O{sub 4} vertically aligned nanocomposite thin films  

SciTech Connect (OSTI)

Self-assembled BiFeO{sub 3}:CoFe{sub 2}O{sub 4} (BFO:CFO) vertically aligned nanocomposite thin films have been fabricated on SrTiO{sub 3} (001) substrates using pulsed laser deposition. The strain relaxation mechanism between BFO and CFO with a large lattice mismatch has been studied by X-ray diffraction and transmission electron microscopy. The as-prepared nanocomposite films exhibit enhanced perpendicular magnetic anisotropy as the BFO composition increases. Different anisotropy sources have been investigated, suggesting that spin-flop coupling between antiferromagnetic BFO and ferrimagnetic CFO plays a dominant role in enhancing the uniaxial magnetic anisotropy.

Zhang, Wenrui; Jiao, Liang; Li, Leigang [Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States); Jian, Jie; Khatkhatay, Fauzia; Chu, Frank [Department of Electrical and Computer Engineering, Texas A and M University, College Station, Texas 77843 (United States); Chen, Aiping [Department of Electrical and Computer Engineering, Texas A and M University, College Station, Texas 77843 (United States); Center for Integrated Nanotechnologies (CINT), Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Jia, Quanxi [Center for Integrated Nanotechnologies (CINT), Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); MacManus-Driscoll, Judith L. [Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge CB2 3QZ (United Kingdom); Wang, Haiyan, E-mail: wangh@ece.tamu.edu [Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States); Department of Electrical and Computer Engineering, Texas A and M University, College Station, Texas 77843 (United States)

2014-02-10T23:59:59.000Z

462

ANALYSIS OF OPTICAL Fe II EMISSION IN A SAMPLE OF ACTIVE GALACTIC NUCLEUS SPECTRA  

SciTech Connect (OSTI)

We present a study of optical Fe II emission in 302 active galactic nuclei (AGNs) selected from the Sloan Digital Sky Survey. We group the strongest Fe II multiplets into three groups according to the lower term of the transition (b{sup 4} F, a{sup 6} S, and a{sup 4} G terms). These approximately correspond to the blue, central, and red parts, respectively, of the 'iron shelf' around H{beta}. We calculate an Fe II template that takes into account transitions into these three terms and an additional group of lines, based on a reconstruction of the spectrum of I Zw 1. This Fe II template gives a more precise fit of the Fe II lines in broad-line AGNs than other templates. We extract Fe II, H{alpha}, H{beta}, [O III], and [N II] emission parameters and investigate correlations between them. We find that Fe II lines probably originate in an intermediate line region. We note that the blue, red, and central parts of the iron shelf have different relative intensities in different objects. Their ratios depend on continuum luminosity, FWHM H{beta}, the velocity shift of Fe II, and the H{alpha}/H{beta} flux ratio. We examine the dependence of the well-known anti-correlation between the equivalent widths of Fe II and [O III] on continuum luminosity. We find that there is a Baldwin effect for [O III] but an inverse Baldwin effect for the Fe II emission. The [O III]/Fe II ratio thus decreases with L {sub {lambda}5100}. Since the ratio is a major component of the Boroson and Green Eigenvector 1 (EV1), this implies a connection between the Baldwin effect and EV1 and could be connected with AGN evolution. We find that spectra are different for H{beta} FWHMs greater and less than {approx}3000 km s{sup -1}, and that there are different correlation coefficients between the parameters.

Kovacevic, Jelena; Popovic, Luka C.; Dimitrijevic, Milan S., E-mail: jkovacevic@aob.bg.ac.r [Astronomical Observatory, Volgina 7, 11060 Belgrade (Serbia)

2010-07-15T23:59:59.000Z

463

Single crystal growth and superconductivity of Ca(Fe1-xCox)2As2  

SciTech Connect (OSTI)

We report the single crystal growth of Ca(Fe1-xCox)2As2 (0 <= x <= 0.082) from Sn flux. The temperature-composition phase diagram is mapped out based on the magnetic susceptibility and electrical transport measurements. Phase diagram of Ca(Fe1-xCox)2As2 is qualitatively different from those of Sr and Ba, it could be due to both the charge doping and structural tuning effects associated with Co substitution.

Hu, Rongwei; Ran, Sheng; Budko, Serguei; Straszheim, Warren E.; Canfield, Paul C.

2012-05-18T23:59:59.000Z

464

Surface modification to improve fireside corrosion resistance of Fe-Cr ferritic steels  

DOE Patents [OSTI]

An article of manufacture and a method for providing an Fe--Cr ferritic steel article of manufacture having a surface layer modification for corrosion resistance. Fe--Cr ferritic steels can be modified to enhance their corrosion resistance to liquid coal ash and other chemical environments, which have chlorides or sulfates containing active species. The steel is modified to form an aluminide/silicide passivating layer to reduce such corrosion.

Park, Jong-Hee (Clarendon Hills, IL); Natesan, Krishnamurti (Naperville, IL); Rink, David L. (Mokena, IL)

2010-03-16T23:59:59.000Z

465

Heat treatment of NiCrFe alloy to optimize resistance to intergrannular stress corrosion  

DOE Patents [OSTI]

A process of producing a NiCrFe alloy having a high resistance to stress corrosion cracking comprising heating a NiCrFe alloy to a temperature sufficient to enable the carbon present in the alloy body in the form of carbide deposits to enter into solution, rapidly cool the alloy body, and heat the cooled body to a temperature between 1100.degree. to 1500.degree. F. for about 1 to 30 hours.

Steeves, Arthur F. (Schenectady, NY); Bibb, Albert E. (Clifton Park, NY)

1984-01-01T23:59:59.000Z

466

Lifshitz Transition and Chemical Instabilities in Ba1 xKxFe2As2 Superconductors  

SciTech Connect (OSTI)

Forsolid-solutionBa1 xKxFe2As2FermisurfaceevolutionismappedviaBlochspectralfunctionscalculatedusingdensityfunctionaltheoryimplementedinKorringa-Kohn-Rostokermultiplescatteringtheorywiththecoherent-potentialapproximation.Spectralfunctionsrevealelectronicdispersion,topology,orbitalcharacter,andbroadening(electron-lifetimeeffects)duetochemicaldisorder.Dissolutionofelectroncylindersoccursnearx 0.9withanonuniform,topological(Lifshitz)transition,reducingtheinterbandinteractions;yetthedispersionmaintainsitsdxzordyzcharacter.Formationenergiesindicatealloyingatx 0.35,asobserved,andatendencyforsegregationontheK-rich(x>0.6)side,explainingthedifficultyofcontrollingsamplequalityandtheconflictingresultsbetweencharacterizedelectronicstructures.OurresultsrevealFermisurfacetransitionsinalloyedsamplesthatinfluencestonodalsuperconductivityandsuggesttheoriginfordeviationsofcommontrendsinFe-basedsuperconductors,suchasBud ko-Ni-Canfieldscaling.

Khan, Suffian N. [University of Illinois, Urbana-Champaign] [University of Illinois, Urbana-Champaign; Johnson, Duane D. [University of Illinois, Urbana-Champaign] [University of Illinois, Urbana-Champaign

2014-01-01T23:59:59.000Z

467

Development of an Fe efficiency screening procedure for sorghum based on realistic soil parameters  

E-Print Network [OSTI]

DEVELOPMENT OF AN FE EFFICIENCY SCREENING PROCEDURE FOR SORGHUH BASED ON REAl ISTIC SOIL PARAHETERS A Thesis by FRANCISCO HERNANDEZ Submitted to the Graduate College of Texas ASH University in partial fulfillment of the requirements... for the degree of HASTER OF SCIENCE August 1987 Hajor Subject: Agronomy DEVELOPMENT OF AN FE EFFICIENCY SCREENING PROCEDURE FOR SORGHUM BASED ON REALISTIC SOIL PARAMETERS A Thesis by Francisco Hernandez Approved as to style and content by: (Chairman...

Hernandez, Francisco

1987-01-01T23:59:59.000Z

468

Screening peach rootstocks for tolerance to iron deficiency stress: mechanisms of Fe?p3+ ?sreduction  

E-Print Network [OSTI]

SCREENING PEACH ROOTSTOCKS FOR TOLERANCE TO IRON DEFICIENCY STRESS: MECHANISMS OF FE REDUCTION A Thesis by JONATHAN NDA A. EGILLA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1989 Major Subject: Horticulture SCREENING PEACH ROOTSTOCKS FOR TOLERANCE TO IRON DEFICIENCY STRESS: MECHANISMS OF FE REDUCTION A Thesis by JONATHAN NDA A. EGILLA Approved as to style and content by: . H...

Egilla, Jonathan Nda

1989-01-01T23:59:59.000Z

469

Single crystal growth and characterization of ilmenite, FeTiO?, for electronic applications  

E-Print Network [OSTI]

SINGLE CRYSTAL GROWTH AND CHARACTERIZATION OF ILMENITE, FeTi03, FOR ELECTRONIC APPUCATIONS A Thesis by BRIAN LEONARD GRIES Submitted to the Office of Graduate Studies Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE December 1988 Major Subject: Electrical Engineering SINGLE CRYSTAL GROWTH AND CHARACTERIZATION OF ILMENITE, FeT)Oq, FOR ELECTRONIC APPLICATIONS A Thesis by BRIAN LEONARD GRIES Approved as to style and content by...

Gries, Brian Leonard

2012-06-07T23:59:59.000Z

470

Magnetic Properties of Fe Ions in a Silicate Glass and Ceramic  

E-Print Network [OSTI]

Magnetic Properties of Fe Ions in a Silicate Glass and Ceramic A. Mekki1 ) Department of Physics of sodium iron silicate glasses, namely (0.70­­x)SiO2­0.30Na2O­xFe2O3, where x ¼ 0, 0.05, 0.10, 0.15, and 0 of the present study is to compare the magnetic properties of the so- dium silicate glass and the crystallized

Mekki, Abdelkarim

471

Microstructure and Mechanical Property Studies on Neutron-Irradiated Ferritic Fe-Cr Model Alloys  

SciTech Connect (OSTI)

Model Fe, Fe-10Cr and Fe-14Cr alloys were irradiated in Advanced Test Reactor at 300°C and 450°C to target doses of 0.01, 0.1 and 1 dpa. The microstructure and the mechanical property of irradiated specimens were investigated using TEM, APT and hardness measurements. The irradiation-induced hardening was consistent with the observed microstructures. For lower doses of 0.01 and 0.1 dpa, the formation of dislocation loops was the primarily contributor to the hardening; no a’ precipitates of resolvable sizes were observed. By 1 dpa, additional increase in hardening were attributed to the formation of a high density of 1-2 nm a' precipitates. In Fe, the hardness increased less as a function of irradiation dose compared to Fe-Cr alloys because of the lack of a' precipitation and differences in loop structures. Three single-parameter effects have been studied: the Cr content, the irradiation temperature and the grain size. The addition of Cr reduced the mobility of both ½<111> and <100> dislocation loops, leading to a smaller loop size and higher loop density. Also, the Cr contents were positively correlated to the density of a' precipitates, but were less relevant to the precipitate size. Higher irradiation temperature of 450°C resulted in a preferential production of the immobile <100> loops over the mobile ½<111> loops (ex. a ratio of 8:1 in Fe-10Cr irradiated 450°C to 0.01 dpa). At lower temperature of 300°C, heterogeneous formation of dislocation loops at the vicinity of line dislocations frequently. In Fe, the development of dislocation loops was suppressed (compared to Fe-Cr alloys) due to a combination of smaller grain size, high initial dislocation density and high defect mobility.

Jian Gan; Maria Okuniewski; Wei-Ying Chen; Yinbin Miao; Carolyn A. Tomchik; James F. Stubbins; Y. Q. Wu; Stu A. Maloy

2014-06-01T23:59:59.000Z

472

Magnetron-sputter epitaxy of {beta}-FeSi{sub 2}(220)/Si(111) and {beta}-FeSi{sub 2}(431)/Si(001) thin films at elevated temperatures  

SciTech Connect (OSTI)

{beta}-FeSi{sub 2} thin films have been grown on Si(111) and Si(001) substrates by magnetron-sputter epitaxy at 700 Degree-Sign C. On Si(111), the growth is consistent with the commonly observed orientation of [001]{beta}-FeSi{sub 2}(220)//[1-10]Si(111) having three variants, in-plane rotated 120 Degree-Sign with respect to one another. However, on Si(001), under the same growth conditions, the growth is dominated by [-111]{beta}-FeSi{sub 2}(431)//[110]Si(001) with four variants, which is hitherto unknown for growing {beta}-FeSi{sub 2}. Photoelectron spectra reveal negligible differences in the valance-band and Fe2p core-level between {beta}-FeSi{sub 2} grown on Si(111) and Si(001) but an apparent increased Si-oxidization on the surface of {beta}-FeSi{sub 2}/Si(001). This phenomenon is discussed and attributed to the Si-surface termination effect, which also suggests that the Si/Fe ratio on the surface of {beta}-FeSi{sub 2}(431)/Si(001) is larger than that on the surface of {beta}-FeSi{sub 2}(220)/Si(111).

Liu Hongfei; Tan Chengcheh; Chi Dongzhi [Institute of Materials Research and Engineering (IMRE), A-STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)

2012-07-15T23:59:59.000Z

473

Transmission electron microscopy investigation of acicular ferrite precipitation in {gamma}'-Fe{sub 4}N nitride  

SciTech Connect (OSTI)

Acicular-shaped crystals precipitate from {gamma}'-Fe{sub 4}N nitride in an iron-nitrogen alloy and were identified by electron microdiffraction as {alpha}-ferrite. Acicular ferrite develops both the Nishiyama-Wassermann and the Kurdjumov-Sachs orientation relationships with {gamma}'-Fe{sub 4}N nitride. These orientation relationships were discussed in terms of the symmetry theory. The driving force for acicular ferrite formation was related to the increasing nitrogen content of {gamma}'-Fe{sub 4}N, in equilibrium with {alpha}-ferrite, with decreasing temperature. The passage from lamellar to acicular structure in Fe-N system was proposed. - Research Highlights: {yields} Acicular crystals precipitate from pearlitic{gamma}'-Fe{sub 4}N nitride in an iron-nitrogen alloy and were identified by electron microdiffraction as acicular ferrite. {yields} The crystal structure, orientation relationships with the matrix and morphologies of acicular ferrite, were studied by transmission electron microscopy. {yields} The driving force for the formation of acicular ferrite is related to the temperature dependence of nitrogen content of {gamma}'-Fe{sub 4}N, in equilibrium with ferrite. {yields} The passage from the pearlitic structure to the acicular structure in the present iron-nitrogen alloy was proposed.

Xiong, X.C., E-mail: xiaochuan.xiong@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Institut Jean Lamour, UMR 7198 CNRS, Nancy-Universite, UPV-Metz, Ecole des Mines de Nancy, Parc de Saurupt CS 14234, F-54042 Nancy Cedex (France); Redjaimia, A. [Institut Jean Lamour, UMR 7198 CNRS, Nancy-Universite, UPV-Metz, Ecole des Mines de Nancy, Parc de Saurupt CS 14234, F-54042 Nancy Cedex (France); Goune, M. [Institut Jean Lamour, UMR 7198 CNRS, Nancy-Universite, UPV-Metz, Ecole des Mines de Nancy, Parc de Saurupt CS 14234, F-54042 Nancy Cedex (France); ArcelorMittal SA, Voie Romaine, BP 30320, F-57283 Maizieres-les-Metz (France)

2010-11-15T23:59:59.000Z

474

Magnetic excitations and anomalous spin-wave broadening in multiferroic FeV2O4  

SciTech Connect (OSTI)

We report on the different roles of two orbital-active Fe2+ at the A site and V3+ at the B site in the magnetic excitations and on the anomalous spin-wave broadening in FeV2O4. FeV2O4 exhibits three structural transitions and successive paramagnetic (PM)–collinear ferrimagnetic (CFI)–noncollinear ferrimagnetic (NCFI)/ferroelectric transitions. The high-temperature tetragonal/PM–orthorhombic/CFI transition is accompanied by the appearance of a large energy gap in the magnetic excitations due to strong spin-orbit-coupling-induced anisotropy at the Fe2+ site. While there is no measurable increase in the energy gap from the orbital ordering of V3+ at the orthorhombic/CFI–tetragonal/NCFI transition, anomalous spin-wave broadening is observed in the orthorhombic/CFI state due to V3+ spin fluctuations at the B site. The spin-wave broadening is also observed at the zone boundary without softening in the NCFI/ferroelectric phase, which is discussed in terms of magnon-phonon coupling. Our study also indicates that the Fe2+ spins without the frustration at the A site may not play an important role in inducing ferroelectricity in the tetragonal/NCFI phase of FeV2O4.

Zhang, Qiang [Ames Laboratory; Ramazanoglu, Mehmet [Ames Laboratory; Chi, Songxue [Oak Ridge National Laboratory; Liu, Yong [Ames Laboratory; Lograsso, Thomas A. [Ames Laboratory; Vaknin, David [Ames Laboratory

2014-06-01T23:59:59.000Z

475

Microbial Reductive Transformation of Phyllosilicate Fe(III) and U(VI) in Fluvial Subsurface Sediments  

SciTech Connect (OSTI)

The microbial reduction of Fe(III) and U(VI) were investigated in shallow aquifer sediments collected from subsurface Pleistocene flood deposits near the Hanford Reach of the Columbia River in Washington State. Increases in 0.5 N HCl-extractable Fe(II) were observed in incubated sediments and 57Fe Mössbauer spectroscopy revealed that Fe(III) associated with phyllosilicates and pyroxene was reduced to Fe(II). Aqueous uranium(VI) concentrations decreased in incubated Hanford sediments with the rate and extent being greater in sediment amended with organic carbon. X-ray absorption spectroscopy of bioreduced sediments indicated that 67-77% of the U signal was U(VI), probably as an adsorbed species associated with a new or modified reactive mineral phase. Phylotypes within the Deltaproteobacteria were more common in Hanford sediments incubated with U(VI) than without and in U(VI)-free incubations, members of the Clostridiales were dominant with sulfate-reducing phylotypes more common in the sulfate-amended sediments. These results demonstrate the potential for anaerobic reduction phyllosilicate Fe(III) and sulfate in Hanford unconfined aquifer sediments and biotransformations involving reduction and adsorption leading to decreased aqueous U concentrations.

Lee, Ji-Hoon; Fredrickson, Jim K.; Kukkadapu, Ravi K.; Boyanov, Maxim I.; Kemner, Kenneth M.; Lin, Xueju; Kennedy, David W.; Bjornstad, Bruce N.; Konopka, Allan; Moore, Dean A.; Resch, Charles T.; Phillips, Jerry L.

2012-04-14T23:59:59.000Z

476

Precessional magnetization induced spin current from CoFeB into Ta  

SciTech Connect (OSTI)

The spin dynamics at the interface between the CoFeB and Ta layer has been studied using spin pumping and spin wave characterizations. The spin pumping driven by the ferromagnetic resonance in the CoFeB layer injects a spin current into Ta layer which results in an electromotive force across the Ta layer due to the inverse spin Hall effect. Upon changing the polarity of the bias magnetic field, the polarity of the output voltage inverts and the output voltage increases linearly in respect to the microwave signal power which are consistent with the spin pumping characteristics. The effect of the in-plane magnetization angle on the output voltage has been studied. Furthermore, it is found that the frequency spectrum of the spin Hall voltage is modified by the annealing temperature and the full width at half maximum of the spin pumping increases by more than 40% with the increase of the annealing temperature from 200?°C to 300?°C. The spin Hall angle at the Ta-CoFeB interface is determined to be 0.014, and the damping constant of the CoFeB increases from 0.006 in pure CoFeB to 0.015 in Ta/CoFeB film.

Jamali, Mahdi; Klemm, Angeline; Wang, Jian-Ping, E-mail: jpwang@umn.edu [Department of Electrical and Computer Engineering, University of Minnesota, 4-174 200 Union Street SE, Minneapolis, Minnesota 55455 (United States)] [Department of Electrical and Computer Engineering, University of Minnesota, 4-174 200 Union Street SE, Minneapolis, Minnesota 55455 (United States)

2013-12-16T23:59:59.000Z

477

Electronic structure and vibrational entropies of fcc Au-Fe alloys  

SciTech Connect (OSTI)

Phonon density of states (DOS) curves were measured on alloys of face-centered-cubic (fcc) Au-Fe using nuclear resonant inelastic x-ray scattering (NRIXS) and inelastic neutron scattering (INS). The NRIXS and INS results were combined to obtain the total phonon DOS and the partial phonon DOS curves of Au and Fe atoms. The 57Fe partial phonon DOS of the dilute alloy Au0.97 57