National Library of Energy BETA

Sample records for beryllium coke oven

  1. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L.

    1995-12-01

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  2. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F.; Hofherr, K.

    1995-12-01

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  3. Factors affecting coking pressures in tall coke ovens

    SciTech Connect (OSTI)

    Grimley, J.J.; Radley, C.E.

    1995-12-01

    The detrimental effects of excessive coking pressures, resulting in the permanent deformation of coke oven walls, have been recognized for many years. Considerable research has been undertaken worldwide in attempts to define the limits within which a plant may safely operate and to quantify the factors which influence these pressures. Few full scale techniques are available for assessing the potential of a coal blend for causing wall damage. Inference of dangerous swelling pressures may be made however by the measurement of the peak gas pressure which is generated as the plastic layers meet and coalesce at the center of the oven. This pressure is referred to in this report as the carbonizing pressure. At the Dawes Lane cokemaking plant of British Steel`s Scunthorpe Works, a large database has been compiled over several years from the regulator measurement of this pressure. This data has been statistically analyzed to provide a mathematical model for predicting the carbonizing pressure from the properties of the component coals, the results of this analysis are presented in this report.

  4. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect (OSTI)

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  5. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev

    2009-07-15

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  6. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio; Tanioka, Seiichi

    1997-12-31

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  7. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  8. Heating control methodology in coke oven battery at Rourkela Steel Plant

    SciTech Connect (OSTI)

    Bandyopadhyay, S.S.; Parthasarathy, L.; Gupta, A.; Bose, P.R.; Mishra, U.

    1996-12-31

    A methodology of heating control was evolved incorporating temperature data generated through infra-red sensor at quenching station and thermocouples specially installed in the gooseneck of coke oven battery No. 3 of RSP. Average temperature of the red-hot coke as pushed helps in diagnosis of the abnormal ovens and in setting the targeted battery temperature. A concept of coke readiness factor (Q) was introduced which on optimization resulted in lowering the specific heat consumption by 30 KCal/Kg.

  9. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D.

    1997-12-31

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  10. System to acquire and monitor operating machinery positions for horizontal coke oven batteries

    SciTech Connect (OSTI)

    Bierbaum, D.; Teschner, W.

    1980-02-26

    In a horizontal coke oven battery with at least one coke receiving device movable along one longitudinal side of the battery and at least one coke driving device movable along an opposite longitudinal side of the battery, an apparatus is disclosed for determining the relative position of the coke receiving device with respect to the coke driving device and for activating the coke driving device when its position corresponds with that of the coke receiving device. A first wheel is mounted on the coke receiving device for rotation with the movement of the coke receiving device, a first angle encoder is connected to the first wheel for producing a first signal corresponding to the location of the first wheel and the position of the coke receiving device along the coke oven, and an input storage in the form of a magnetic disc is connected to the first angle encoder for recording and storing the signal. A second wheel is mounted on the coke driving device for rotation with the movement of the coke driving device and a second angle encoder is connected thereto for producing a second signal which corresponds to the rotation of the second wheel and the position of the coke driving device along the coke oven. A comparator is connected to the second signal encoder for receiving the second signal and a data link is provided between the comparator and the input storage of the coke receiving device so that the first signal from the coke receiving device can be impressed on the comparator. An activator is connected to the comparator for activating the coke driving device when the first signal corresponds to the second signal indicating a corresponding positional relationship between the coke receiving device and the coke driving device.

  11. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect (OSTI)

    Battle, E.T.; Chen, K.L.

    1997-12-31

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  12. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect (OSTI)

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  13. Using Coke Oven Gas in a Blast Furnace Saves Over $6 Million Annually at a Steel Mill (U.S. Steel Edgar Thompson Plant)

    SciTech Connect (OSTI)

    2000-12-01

    Like most steel companies, U.S. Steel (USS) had been using coke oven gas (COG), a by-product of coke manufacturing, as a fuel in their coke ovens, boilers, and reheat furnaces.

  14. Operational improvements at Jewell Coal and Coke Company`s non-recovery ovens

    SciTech Connect (OSTI)

    Ellis, C.E.; Pruitt, C.W.

    1995-12-01

    Operational improvements at Jewell Coal and Coke Company over the past five years includes safety and environmental concerns, product quality, equipment availability, manpower utilization, and productivity. These improvements with Jewell`s unique process has allowed Jewell Coal and Coke Company to be a consistent, high quality coke producer. The paper briefly explains Jewell`s unique ovens, their operating mode, improved process control, their maintenance management program, and their increase in productivity.

  15. Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    M206 Mechanical Convection Oven The M206 oven is dedicated to CAMD staff use only. M326 Mechanical Convection Oven Located next to the spinners, the M326 oven is availabe to...

  16. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  17. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J.; Gross, M.

    1995-12-01

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  18. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka

    1997-12-31

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  19. Prolongation technologies for campaign life of tall oven

    SciTech Connect (OSTI)

    Doko, Yoshiji; Saji, Takafumi; Kitayama, Yoshiteru; Yoshida, Shuhei

    1997-12-31

    In Kashima Steel Works, 25-year-old 7-meter-high coke ovens have damage on their walls. However, by using new methods of internal in-situ investigation, ceramic welding for the extended central and upper portions of coke ovens has prolonged the campaign life for over 40 years without large-scale hot repair. In this paper, introduction of these new methods, its application in Kashima and the policy of repairing the tall coke oven are reported.

  20. Simulation of industrial coking -- Phase 1

    SciTech Connect (OSTI)

    Todoschuk, T.W.; Price, J.T.; Gransden, J.F.

    1997-12-31

    Two statistically designed experimental programs using an Appalachian and a Western Canadian coal blend were run in CANMET`s 460mm (18 inch) movable wall oven. Factors included coal grind, moisture, oil addition, carbonization rate and final coke temperature. Coke quality parameters including CSR, coal charge characteristics and pressure generation were analyzed.

  1. About Beryllium

    Broader source: Energy.gov [DOE]

    Information on what is Beryllium, the symptoms and health hazards associated with Beryllium contamination.

  2. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

  3. Collector main replacement at Indianapolis Coke

    SciTech Connect (OSTI)

    Sickle, R.R. Van

    1997-12-31

    Indianapolis Coke is a merchant coke producer, supplying both foundry and blast furnace coke to the industry. The facility has three coke batteries: two 3 meter batteries, one Wilputte four divided and one Koppers Becker. Both batteries are underjet batteries and are producing 100% foundry coke at a net coking time of 30.6 hours. This paper deals with the No. 1 coke battery, which is a 72 oven, gun fired, 5 meter Still battery. No. 1 battery produces both foundry and blast furnace coke at a net coking rate of 25.4 hours. No. 1 battery was commissioned in 1979. The battery is equipped with a double collector main. Although many renovations have been completed to the battery, oven machinery and heating system, to date no major construction projects have taken place. Deterioration of the collector main was caused in part from elevated levels of chlorides in the flushing liquor, and temperature fluctuations within the collector main. The repair procedures are discussed.

  4. The correlation between reactivity and ash mineralogy of coke

    SciTech Connect (OSTI)

    Kerkkonen, O.; Mattila, E.; Heiniemi, R.

    1996-12-31

    Rautaruukki is a modern integrated Finnish steel works having a production of 2.4 mil. t/year of flat products. The total fuel consumption of the two blast furnaces in 1994 was 435 kg/t HM. Coke used was 345 kg/t HM and oil injection was 90 kg/t HM. The coking plant was taken in to operation in 1987 and is the only one in Finland, which means that the coking tradition is very short. Coke production is 0.9 mil. t/year. The coking blends include 70--80% medium volatile coals having a wide range of total dilatation. From time to time disturbances in the operation of the blast furnaces have occurred in spite of the fact that the reactivity of the coke used has remained constant or even decreased. It was thought necessary to investigate the factors affecting coke reactivity, in order to better understand the results of the reactivity test. This paper deals with carbonization tests done in a 7 kg test oven using nine individual coals having volatile-matter contents of 17--36% (dry) and seven blends made from these coals. Coke reactivity with CO{sub 2} at 1100 C (CRI) and coke strength after reaction (CSR) were determined using the test developed by the Nippon Steel Corporation. The influence of coke carbon form, porosity and especially ash mineralogy on the coke reactivity were examined. The effects of some additives; petroleum coke (pet coke), the spillage material from the coke ovens and oxidized coal, on coke quality were also studied. Typical inorganic minerals found in coals were added to one of the high volatile coals, which was then coked to determine the affect of the minerals on the properties of the coke produced.

  5. Improvement of coke quality by utilization of hydrogenation residue

    SciTech Connect (OSTI)

    Meckel, J.F. ); Wairegi, T. )

    1993-01-01

    Hydrogenation residue is the product left over when petroleum residue feedstocks (or coal) are treated by, e.g. the Veba Combi Cracking (VCC) process. Many tests in semitechnical and full-sized coke ovens were carried out with hydrogenation residue (HR) as an additive in coking coal blends for the production of blast furnace coke or foundry coke. The results of the investigations reported in this paper demonstrate that HR is a very promising alternative for enlarging the coking coal basis compared to other processes or the use of other additives. The application of HR on an industrial scale did not indicate any negative impact on the handling of the hydrogenation residue or on the operation of the coke oven battery.

  6. Beryllium Information | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beryllium Report 2001 Beryllium Report 2008 Beryllium Report 2010 Beryllium Report 2011 Beryllium News Release 6-5-09 Beryllium Fact Sheet Chronic Beryllium Disease Prevention Plan...

  7. Unmanned operation of the coke guides at Hoogovens IJmuiden Coke Plant 1

    SciTech Connect (OSTI)

    Vos, D.; Mannes, N.; Poppema, B.

    1995-12-01

    Due to the bad condition of batteries and many ovens under repair, Hoogovens was forced to partially repair and rebuild the Coke plant No. 1. The production of coke at Coke plant No. 1 is realized in 3 production blocks subdivided in 6 batteries. Besides a renovated installation, all coke oven machines were renewed. A total of five identical machine sets are available. Each consists of a pusher machine, larry car, coke guide and quench car with diesel locomotive. A complete automated control system was implemented. The main objectives were a highly regular coking and pushing process, automated traveling and positioning and a centrally coordinated interlocking of machine functions. On each operational machine however an operator performed the supervisory control of the automated machine functions. After years of good experience with the automated system, economical reasons urged further personnel reduction from 1994 on. Totally 375 people were involved, including the maintenance department. To reduce the occupation at coke plant No. 1, the coke guide was the first machine to be fully automated because of the isolated and uncomfortable working place.

  8. Beryllium FAQs - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FAQs About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources Beryllium FAQs Email Email Page | Print Print Page |Text Increase Font Size Decrease

  9. Beryllium Program - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program About Us About Hanford Cleanup Hanford History Hanford Site Wide Programs Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources Contact Us Beryllium

  10. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H.

    1995-12-01

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  11. The waste water free coke plant

    SciTech Connect (OSTI)

    Schuepphaus, K.; Brink, N.

    1995-12-01

    Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

  12. Beryllium Testing

    Broader source: Energy.gov [DOE]

    Beryllium is a naturally occurring metal and is not radioactive. Because of its properties, beryllium has been part of the atomic energy and nuclear weapons industries since the 1940s.

  13. Lesson 9 - Solar Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fridell * Place the oven on a sunny flat surface facing the sun and use masking tape to prop the aluminum flap open. Sunlight should reflect off the flap and into the solar oven...

  14. Beryllium Program Feedback - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanford Site Wide Programs Beryllium Program Beryllium Program Feedback About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources Beryllium Program

  15. Cyanide treatment options in coke plants

    SciTech Connect (OSTI)

    Minak, H.P.; Lepke, P.

    1997-12-31

    The paper discusses the formation of cyanides in coke oven gas and describes and compares waste processing options. These include desulfurization by aqueous ammonia solution, desulfurization using potash solution, desulfurization in oxide boxes, decomposition of NH{sub 3} and HCN for gas scrubbing. Waste water treatment methods include chemical oxidation, precipitation, ion exchange, reverse osmosis, and biological treatment. It is concluded that biological treatment is the most economical process, safe in operation and requires a minimum of manpower.

  16. Making a Solar Oven

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    Students make solar ovens. Student background information is provided. The expected outcome is that students will learn about solar energy transfer.

  17. The new Kaiserstuhl coking plant: The heating system -- Design, construction and initial operating experience

    SciTech Connect (OSTI)

    Strunk, J.

    1996-12-31

    At the end of 1992 the new coke plant Kaiserstuhl in Dortmund/Germany with presently the largest coke ovens world-wide started its production operation in close linkage to the Krupp-Hoesch Metallurgical Works after about 35 months construction time. This plant incorporating comprehensive equipment geared to improve environmental protection is also considered as the most modern coke plant of the world. The heating-system and first results of operation will be presented.

  18. Portable oven air circulator

    DOE Patents [OSTI]

    Jorgensen, Jorgen A. (Bloomington, MN); Nygren, Donald W. (Minneapolis, MN)

    1983-01-01

    A portable air circulating apparatus for use in cooking ovens which is used to create air currents in the oven which transfer heat to cooking foodstuffs to promote more rapid and more uniform cooking or baking, the apparatus including a motor, fan blade and housing of metallic materials selected from a class of heat resistant materials.

  19. Operating and maintenance benefits of automated oven wall temperature measurement

    SciTech Connect (OSTI)

    Leuchtmann, K.P.; Hinz, D.; Bergbau, D.; Platts, M.

    1997-12-31

    For a very long time and regardless of all shortcomings associated with it, the manual measurement of the heating flue temperature has been the only method of monitoring the temperature prevailing in a coke oven battery and discovering weak points in the heating system. In the course of the last few years a number of automated temperature measuring systems have been developed that are intended to replace or supplement the manual heating flue measurement system. These measuring systems and their advantages/disadvantages are briefly described in this paper. Additionally, operational experience gathered with the oven chamber wall temperature measuring system is discussed in detail.

  20. Beryllium Health Advocates - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Health Advocates About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources Beryllium Health Advocates Email Email Page | Print Print Page |Text

  1. Beryllium Program Information - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Information About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources Beryllium Program Information Email Email Page | Print Print Page |Text

  2. Beryllium Related Links - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Related Links About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources Beryllium Related Links Email Email Page | Print Print Page |Text Increase Font

  3. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect (OSTI)

    Diemer, P.E.; Seyfferth, W.

    1997-12-31

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  4. Beryllium disease

    SciTech Connect (OSTI)

    Not Available

    1991-12-20

    After two workers at the nuclear weapons plant at Oak Ridge National Laboratory in Tennessee were diagnosed earlier this year with chronic beryllium disease (CBD), a rare and sometimes fatal scarring of the lungs, the Department of Energy ordered up a 4-year probe. Now, part of that probe has begun - tests conducted by the Oak Ridge Associated Universities' Center for Epidemiological Research measuring beryllium sensitivity in 3,000 people who've been exposed to the metal's dust since Manhattan Project managers opened the Y-12 plant at Oak Ridge in 1943. Currently, 119 Y-12 employees process beryllium, which has a number of industrial uses, including rocket heat shields and nuclear weapon and electrical components. The disease often takes 20 to 25 years to develop, and the stricken employees haven't worked with beryllium for years. There is no cure for CBD, estimated to strike 2% of people exposed to the metal. Anti-inflammatory steroids alleviate such symptoms as a dry cough, weight loss, and fatigue. Like other lung-fibrosis diseases that are linked to lung cancer, some people suspect CBD might cause some lung cancer. While difficult to diagnose, about 900 cases of CBD have been reported since a Beryllium Case Registry was established in 1952. The Department of Energy (DOE) estimates that about 10,000 DOE employees and 800,000 people in private industry have worked with beryllium.

  5. Method for welding beryllium

    DOE Patents [OSTI]

    Dixon, Raymond D. (Los Alamos, NM); Smith, Frank M. (Espanola, NM); O'Leary, Richard F. (Los Alamos, NM)

    1997-01-01

    A method is provided for joining beryllium pieces which comprises: depositing aluminum alloy on at least one beryllium surface; contacting that beryllium surface with at least one other beryllium surface; and welding the aluminum alloy coated beryllium surfaces together. The aluminum alloy may be deposited on the beryllium using gas metal arc welding. The aluminum alloy coated beryllium surfaces may be subjected to elevated temperatures and pressures to reduce porosity before welding the pieces together. The aluminum alloy coated beryllium surfaces may be machined into a desired welding joint configuration before welding. The beryllium may be an alloy of beryllium or a beryllium compound. The aluminum alloy may comprise aluminum and silicon.

  6. Interim Chronic Beryllium Disease

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-12-08

    Establishes Departmental expectations for addressing chronic beryllium disease throughout the Department until a Departmental rule on beryllium is promulgated. This Notice was replaced by final rule 10 CFR Part 850, Chronic Beryllium Disease Prevention Program, published December 8, 1999.

  7. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J.; Sirgado, M.

    1995-12-01

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  8. Method for welding beryllium

    DOE Patents [OSTI]

    Dixon, R.D.; Smith, F.M.; O`Leary, R.F.

    1997-04-01

    A method is provided for joining beryllium pieces which comprises: depositing aluminum alloy on at least one beryllium surface; contacting that beryllium surface with at least one other beryllium surface; and welding the aluminum alloy coated beryllium surfaces together. The aluminum alloy may be deposited on the beryllium using gas metal arc welding. The aluminum alloy coated beryllium surfaces may be subjected to elevated temperatures and pressures to reduce porosity before welding the pieces together. The aluminum alloy coated beryllium surfaces may be machined into a desired welding joint configuration before welding. The beryllium may be an alloy of beryllium or a beryllium compound. The aluminum alloy may comprise aluminum and silicon. 9 figs.

  9. Hanford Beryllium Awareness Group (BAG) - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanford Site Wide Programs Beryllium Program Hanford Beryllium Awareness Group (BAG) About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources Hanford

  10. Western Canadian coking coals -- Thermal rheology and coking quality

    SciTech Connect (OSTI)

    Leeder, W.R.; Price, J.T.; Gransden, J.F.

    1997-12-31

    Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

  11. Beryllium Facilities & Areas - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facilities & Areas About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources Beryllium Facilities & Areas Email Email Page | Print Print Page

  12. Beryllium Program Performance Assessments - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Performance Assessments About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources Beryllium Program Performance Assessments Email Email Page |

  13. Oven wall panel construction

    DOE Patents [OSTI]

    Ellison, Kenneth; Whike, Alan S.

    1980-04-22

    An oven roof or wall is formed from modular panels, each of which comprises an inner fabric and an outer fabric. Each such fabric is formed with an angle iron framework and somewhat resilient tie-bars or welded at their ends to flanges of the angle irons to maintain the inner and outer frameworks in spaced disposition while minimizing heat transfer by conduction and permitting some degree of relative movement on expansion and contraction of the module components. Suitable thermal insulation is provided within the module. Panels or skins are secured to the fabric frameworks and each such skin is secured to a framework and projects laterally so as slidingly to overlie the adjacent frame member of an adjacent panel in turn to permit relative movement during expansion and contraction.

  14. Coking and gasification process

    DOE Patents [OSTI]

    Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

    1986-01-01

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  15. Ovenized microelectromechanical system (MEMS) resonator

    DOE Patents [OSTI]

    Olsson, Roy H; Wojciechowski, Kenneth; Kim, Bongsang

    2014-03-11

    An ovenized micro-electro-mechanical system (MEMS) resonator including: a substantially thermally isolated mechanical resonator cavity; a mechanical oscillator coupled to the mechanical resonator cavity; and a heating element formed on the mechanical resonator cavity.

  16. High coking value pitch

    SciTech Connect (OSTI)

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  17. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M.

    1996-12-31

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  18. Light oil yield improvement project at Granite City Division Coke/By-Product Plant

    SciTech Connect (OSTI)

    Holloran, R.A.

    1995-12-01

    Light oil removal from coke oven gas is a process that has long been proven and utilized throughout many North American Coke/By-Products Plants. The procedures, processes, and equipment requirements to maximize light oil recovery at the Granite City By-Products Plant will be discussed. The Light Oil Yield Improvement Project initially began in July, 1993 and was well into the final phase by February, 1994. Problem solving techniques, along with utilizing proven theoretical recovery standards were applied in this project. Process equipment improvements and implementation of Operator/Maintenance Standard Practices resulted in an average yield increase of 0.4 Gals./NTDC by the end of 1993.

  19. Solar Pizza Oven Box k - 6

    Office of Environmental Management (EM)

    Ready to Build? BUILD A PIZZA BOX SOLAR OVEN Background The sun is hot enough to bake food. Here's how to make a simple solar oven that gets hot enough to warm up cookies and other...

  20. Coke from coal and petroleum

    DOE Patents [OSTI]

    Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

    1981-01-01

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  1. Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001

    SciTech Connect (OSTI)

    Jin, H.G.; Sun, S.; Han, W.; Gao, L.

    2009-09-15

    This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

  2. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L.

    1995-12-01

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  3. A fully integrated oven controlled microelectromechanical oscillator --

    Office of Scientific and Technical Information (OSTI)

    Part I. Design and fabrication (Journal Article) | DOE PAGES - Part I. Design and fabrication This content will become publicly available on June 24, 2016 Title: A fully integrated oven controlled microelectromechanical oscillator -- Part I. Design and fabrication Our paper reports the design and fabrication of a fully integrated oven controlled microelectromechanical oscillator (OCMO). This paper begins by describing the limits on oscillator frequency stability imposed by the thermal drift

  4. Rocky Flats beryllium health surveillance

    SciTech Connect (OSTI)

    Stange, A.W.; Furman, F.J.; Hilmas, D.E.

    1996-10-01

    The Rocky Flats Beryllium Health Surveillance Program (BHSP), initiated in June 1991, was designed to provide medical surveillance for current and former employees exposed to beryllium. The BHSP identifies individuals who have developed beryllium sensitivity using the beryllium lymphocyte proliferation test (BeLPT). A detailed medical evaluation to determine the prevalence of chronic beryllium disease (CBD) is offered to individuals identified as beryllium sensitized or to those who have chest X-ray changes suggestive of CBD. The BHSP has identified 27 cases of CBD and another 74 cases of beryllium sensitization out of 4268 individuals tested. The distribution of BeLPT values for normal, sensitized, and CBD-identified individuals is described. Based on the information collected during the first 3 1/3 years of the BHSP, the BeLPT is the most effective means for the early identification of beryllium-sensitized individuals and to identify individuals who may have CBD. The need for BeLPT retesting is demonstrated through the identification of beryllium sensitization in individuals who previously tested normal. Posterior/anterior chest X-rays were not effective in the identification of CBD. 12 refs., 8 tabs.

  5. Beryllium Program Points of Contact - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HAMTC Representative (509-372-0626) HPMC Occupational Medical Services; Nicholas N. (Nic) Holland, MS, CIH, OHST, Beryllium Registry (509-376-1085) Dana C. Gribble, Beryllium...

  6. Characterization of Shocked Beryllium

    SciTech Connect (OSTI)

    Cady, Carl M; Adams, Chris D; Hull, Lawrence M; Gray III, George T; Prime, Michael B; Addessio, Francis L; Wynn, Thomas A; Brown, Eric N

    2012-08-24

    Beryllium metal has many excellent structural properties in addition to its unique radiation characteristics, including: high elastic modulus, low Poisson's ratio, low density, and high melting point. However, it suffers from several major mechanical drawbacks: 1) high anisotropy - due to its hexagonal lattice structure and its susceptibility to crystallographic texturing; 2) susceptibility to impurity-induced fracture - due to grain boundary segregation; and 3) low intrinsic ductility at ambient temperatures thereby limiting fabricability. While large ductility results from deformation under the conditions of compression, the material can exhibit a brittle behavior under tension. Furthermore, there is a brittle to ductile transition at approximately 200 C under tensile conditions. While numerous studies have investigated the low-strain-rate constitutive response of beryllium, the combined influence of high strain rate and temperature on the mechanical behavior and microstructure of beryllium has received limited attention over the last 40 years. Prior studies have focused on tensile loading behavior, or limited conditions of dynamic strain rate and/or temperature. The beryllium used in this study was Grade S200-F (Brush Wellman, Inc., Elmore, OH) material. The work focused on high strain rate deformation and examine the validity of constitutive models in deformation rate regimes, including shock, the experiments were modeled using a Lagrangian hydrocode. Two constitutive strength (plasticity) models, the Preston-Tonks-Wallace (PTW) and Mechanical Threshold Stress (MTS) models, were calibrated using the same set of quasi-static and Hopkinson bar data taken at temperatures from 77K to 873K and strain rates from 0.001/sec to 4300/sec. In spite of being calibrated on the same data, the two models give noticeably different results when compared with the measured wave profiles. These high strain rate tests were conducted using both explosive drive and a gas gun to accelerate the material. Preliminary analysis of the results appears to indicate that, if fractured by the initial shock loading, the S200F Be remains sufficiently intact to support a shear stress following partial release and subsequent shock re-loading of the material. Additional 'arrested' drive shots were designed and tested to minimize the reflected tensile pulse in the sample. These tests were done to both validate the model and to put large shock induced compressive loads into the beryllium sample.

  7. Inhibition of coke formation in pyrolysis furnaces

    SciTech Connect (OSTI)

    Tong, Y.; Poindexter, M.K.; Rowe, C.T.

    1995-12-31

    Coke formation in pyrolysis furnaces, which thermally convert hydrocarbons to ethylene as well as other useful products, adversely affects product yields, causes furnace down time for coke removal, and shortens furnace coil life. A phosphorus-based chemical treatment program was developed to inhibit the coke formation. The anticoking performance of the phosphorus-based treatment program was studied using a bench scale coking rate measurement apparatus. The programs`s influence on coke morphology and reactor surface was addressed using SEM/EDX surface characterization techniques. For comparison, similar studies were carried out with sulfur-containing species which are conventionally used in industrial practice as furnace additives. The present work demonstrated that the phosphorus-based treatment program provided an efficient and durable surface passivation against coke formation.

  8. Technical Basis for PNNL Beryllium Inventory

    SciTech Connect (OSTI)

    Johnson, Michelle Lynn

    2014-07-09

    The Department of Energy (DOE) issued Title 10 of the Code of Federal Regulations Part 850, “Chronic Beryllium Disease Prevention Program” (the Beryllium Rule) in 1999 and required full compliance by no later than January 7, 2002. The Beryllium Rule requires the development of a baseline beryllium inventory of the locations of beryllium operations and other locations of potential beryllium contamination at DOE facilities. The baseline beryllium inventory is also required to identify workers exposed or potentially exposed to beryllium at those locations. Prior to DOE issuing 10 CFR 850, Pacific Northwest Nuclear Laboratory (PNNL) had documented the beryllium characterization and worker exposure potential for multiple facilities in compliance with DOE’s 1997 Notice 440.1, “Interim Chronic Beryllium Disease.” After DOE’s issuance of 10 CFR 850, PNNL developed an implementation plan to be compliant by 2002. In 2014, an internal self-assessment (ITS #E-00748) of PNNL’s Chronic Beryllium Disease Prevention Program (CBDPP) identified several deficiencies. One deficiency is that the technical basis for establishing the baseline beryllium inventory when the Beryllium Rule was implemented was either not documented or not retrievable. In addition, the beryllium inventory itself had not been adequately documented and maintained since PNNL established its own CBDPP, separate from Hanford Site’s program. This document reconstructs PNNL’s baseline beryllium inventory as it would have existed when it achieved compliance with the Beryllium Rule in 2001 and provides the technical basis for the baseline beryllium inventory.

  9. Coke cake behavior under compressive forces

    SciTech Connect (OSTI)

    Watakabe, S.; Takeda, T.; Itaya, H.; Suginobe, H.

    1997-12-31

    The deformation of the coke cake and load on the side wall during pushing were studied using an electric furnace equipped with a movable wall. Coke cake was found to deform in three stages under compressive forces. The coke cake was shortened in the pushing direction in the cake deformation stage, and load was generated on the side walls in the high wall load stage. Secondary cracks in the coke cake were found to prevent load transmission on the wall. The maximum load transmission rate was controlled by adjusting the maximum fluidity and mean reflectance of the blended coal.

  10. Solar Pizza Oven Box k - 6

    Energy Savers [EERE]

    Ready to Build? BUILD A PIZZA BOX SOLAR OVEN Background The sun is hot enough to bake food. Here's how to make a simple solar oven that gets hot enough to warm up cookies and other treats, like s'mores. It won't get really hot, though, so you can't bake things in it and you won't burn yourself when playing with it. Be sure to have an adult help you with this! Materials - One pizza box from a local pizza delivery store. Here's a good excuse to ask your parents to order pizza tonight! - Newspapers

  11. Beryllium Vendor Screening Program | Department of Energy

    Office of Environmental Management (EM)

    Beryllium Vendor Screening Program Beryllium Vendor Screening Program In February 2005, DOE expanded the beryllium screening program to include former employees of defunct DOE beryllium vendors who were employed with these companies while they performed work for DOE. This change was made to ensure that workers who no longer have an employer to turn to for beryllium disease testing could receive this important screening. DOE will offer these individuals a blood test at no cost to check for

  12. Beryllium Vender Screening Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Beryllium Vender Screening Program Beryllium Vender Screening Program In February 2005, DOE expanded the beryllium screening program to include former employees of defunct DOE beryllium vendors who were employed with these companies while they performed work for DOE. This change was made to ensure that workers who no longer have an employer to turn to for beryllium disease testing could receive this important screening. DOE will offer these individuals a blood test at no cost to check for

  13. Coke County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Zone Subtype B. Places in Coke County, Texas Blackwell, Texas Bronte, Texas Robert Lee, Texas Retrieved from "http:en.openei.orgwindex.php?titleCokeCounty,Texas&oldid...

  14. Coke formation in visbreaking process

    SciTech Connect (OSTI)

    Yan, T.Y. )

    1987-04-01

    Visbreaking is a mild cracking process primarily used to reduce residual oil viscosity and thus decrease the amount of cutter stock required for blending to heavy fuels specification. It can also be used to produce incremental quantities of gasoline, middle distillates and catalytic cracker feeds. This process was widely used in the 1930s and 1940s and became obsolete until a few years ago. When the need for increased conversion of residues to light products became desirable, visbreaking offered economic advantages to many refining schemes - especially in Western Europe. Between 1978-1981, Exxon brought on stream seven visbreakers ranging from 1900 to 9100 tons/SD capacity. In January 1983, the world-wide visbreaking capacity was over 2 MM B/SD. The visbreaking process and its application in refinery operations have been well described. In general, the process economics improve as the process severity is increased but it is limited by coke formation in the process. For this reason, they have studied the kinetics of coke formation in the visbreaking process.

  15. Rheology of petroleum coke-water slurry

    SciTech Connect (OSTI)

    Prasad, M.; Mall, B.K.; Mukherjee, A.; Basu, S.K.; Verma, S.K.; Narasimhan, K.S.

    1998-07-01

    This paper reports the results of the studies carried out on the optimization of particle size distribution, the rheological characteristics and stability of highly loaded petroleum coke-water slurry using three additives. The solids loading achieved in the slurries were in the range of 65% to 75.6% depending on the additives used. Slurry viscosity varied between 267 to 424 mPas at 128 s{sup {minus}} shear rate. The petroleum coke-water slurries exhibited pseudoplastic characteristics with yield tending towards Bingham plastic as the solids loading progressively increased. The effect of addition of petroleum coke to the extent of 25% in coal-water slurry prepared from low ash Ledo coal of Makum field in Assam was also examined. The slurry containing coal-petroleum coke blend showed better stability, having shelf life of 7 days as compared to 5 days in the case of petroleum coke-water slurry.

  16. Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency | Department of Energy Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency This process heating tip sheet recommends using lower flammable limit monitoring equipment to improve oven efficiency. PROCESS HEATING TIP SHEET #11 PDF icon Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency (October 2007) More Documents & Publications Check Burner

  17. Covered Product Category: Commercial Ovens | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ovens Covered Product Category: Commercial Ovens The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial ovens, which is a product category covered by the ENERGY STAR program. Federal laws and requirements mandate that agencies purchase products that are covered by ENERGY STAR or FEMP in all acquisitions that are not specifically exempted by law. Meeting Energy Efficiency Requirements for Commercial Ovens ENERGY STAR sets efficiency requirements for commercial

  18. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, Irwin Charles (Strongsville, OH); Greinke, Ronald Alfred (Medina, OH)

    1997-01-01

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (i) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (ii) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns. (b) a binder This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode.

  19. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, I.C.; Greinke, R.A.

    1997-06-17

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (1) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (2) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns and (b) a binder. This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode. 5 figs.

  20. Demand for superpremium needle cokes on upswing

    SciTech Connect (OSTI)

    Acciarri, J.A.; Stockman, G.H. )

    1989-12-01

    The authors discuss how recent supply shortages of super-premium quality needle cokes, plus the expectation of increased shortfalls in the future, indicate that refiners should consider upgrading their operations to fill these demands. Calcined, super-premium needle cokes are currently selling for as much as $550/metric ton, fob producer, and increasing demand will continue the upward push of the past year. Needle coke, in its calcined form, is the major raw material in the manufacture of graphite electrodes. Used in steelmaking, graphite electrodes are the electrical conductors that supply the heat source, through arcing electrode column tips, to electric arc steel furnaces. Needle coke is commercially available in three grades - super premium, premium, and intermediate. Super premium is used to produce electrodes for the most severe electric arc furnace steelmaking applications, premium for electrodes destined to less severe operations, and intermediate for even less critical needs.

  1. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2003-09-26

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  2. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2004-09-26

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  3. Mozambique becomes a major coking coal exporter?

    SciTech Connect (OSTI)

    Ruffini, A.

    2008-06-15

    In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

  4. 2014 Beryllium-Associated Worker Registry Summary

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... The U.S. Code of Federal Regulations (CFR) Title 10, Part 850 Chronic Beryllium Disease Prevention Program (10 CFR 850) requires DOE sites to inventory and assess beryllium ...

  5. ORISE: Worker Health Studies - Beryllium Testing Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BeLPT Process Diagram BeLPT Process Diagram Click image for larger view Oak Ridge Institute for Science Education Beryllium Testing Laboratory Beryllium is a metal that is primarily used as a hardening agent in alloys. Its low density, heat stability and high melting point have made it of benefit to the aerospace and defense industries. However, beryllium dust or fumes produced during machining or manufacturing activities can cause sensitivity in some persons that may lead to chronic beryllium

  6. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1713F Offices For Technical Personnel And Drafting Operation March 25, 1998 February 9, 2012 N/A Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: No Form of beryllium: N/A Period of beryllium operations (dates): Start: 1973 End: 1973 Location(s) in facility that contained beryllium materials: Potential beryllium contamination in the small animal quarters was investigated in 1973. Description of beryllium activities: Rats were exposed to beryllium oxide dust in the 331 Building

  7. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1Z Materials Engineering Laboratory (Plutonium Metallurgy Lab) February 23, 2004 February 1, 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: 1967 End: 1980 Location(s) in facility that contained beryllium materials: PNNL conducted various beryllium operations in this facility from 1967 to 1980. Confirmed rooms with past beryllium activities include 23, 24, 34, 39, and 49. No beryllium

  8. Communicating Health Risks Working Safely With Beryllium | Department of

    Office of Environmental Management (EM)

    Energy Communicating Health Risks Working Safely With Beryllium Communicating Health Risks Working Safely With Beryllium April 2002 Training Reference for Beryllium Workers and Managers/Supervisors, Facilitator Manual Prepared by the Beryllium Health Risk Communication Task Force PDF icon Communicating Health Risks Working Safely With Beryllium More Documents & Publications Communicating Health Risks Working Safely With Beryllium Beryllium Screening - Informed Choice Document Federal

  9. Multiple delivery cesium oven system for negative ion sources

    SciTech Connect (OSTI)

    Bansal, G.; Bhartiya, S.; Pandya, K.; Bandyopadhyay, M.; Singh, M. J.; Soni, J.; Gahlaut, A.; Parmar, K. G.; Chakraborty, A. [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat 382428 (India)

    2012-02-15

    Distribution of cesium in large negative ion beam sources to be operational in ITER, is presently based on the use of three or more cesium ovens, which operate simultaneously and are controlled remotely. However, use of multiple Cs ovens simultaneously is likely to pose difficulties in operation and maintenance of the ovens. An alternate method of Cs delivery, based on a single oven distribution system is proposed as one which could reduce the need of simultaneous operation of many ovens. A proof of principle experiment verifying the concept of a multinozzle distributor based Cs oven has been carried out at Institute for Plasma Research. It is also observed that the Cs flux is not controlled by Cs reservoir temperature after few hours of operation but by the temperature of the distributor which starts behaving as a Cs reservoir.

  10. Solar Oven, Take One: FAIL | Department of Energy

    Energy Savers [EERE]

    Oven, Take One: FAIL Solar Oven, Take One: FAIL June 15, 2011 - 11:56am Addthis Our homemade solar oven. | Courtesy of Moon Choe Our homemade solar oven. | Courtesy of Moon Choe Moon Choe EERE Summer Intern The first time I ever saw solar cookers was on the news in the summer of 2009 (though that would make it their winter, as I was living in Chile at the time), as part of a development project in the north, which is mostly desert. I had no idea solar cookers were so markedly simple in all

  11. Worker Environment Beryllium Characterization Study

    SciTech Connect (OSTI)

    NSTec Environment, Safety, Health & Quality

    2009-12-28

    This report summarizes the conclusion of regular monitoring of occupied buildings at the Nevada Test Site and North Las Vegas facility to determine the extent of beryllium (Be) contamination in accordance with Judgment of Needs 6 of the August 14, 2003, Minnema Report.

  12. Rheology of petroleum coke-water slurry

    SciTech Connect (OSTI)

    Prasad, M.; Mall, B.K.; Mukherjee, A.

    1998-04-01

    This paper reports the results of the studies carried out on the optimization of particle size distribution, the theological characteristics and stability of highly loaded petroleum coke-water slurry using three additives. The solids loading achieved in the slurries were in the range of 65% to 75.6% depending on the additives used. Slurry viscosity varied between 267 to 424 mPas at 128 s{sup -1} shear rate. The petroleum coke-water slurries exhibited pseudoplastic characteristics with yield tending towards Bingham plastic as the solids loading progressively increased.

  13. Defense programs beryllium good practice guide

    SciTech Connect (OSTI)

    Herr, M.

    1997-07-01

    Within the DOE, it has recently become apparent that some contractor employees who have worked (or are currently working) with and around beryllium have developed chronic beryllium disease (CBD), an occupational granulomatous lung disorder. Respiratory exposure to aerosolized beryllium, in susceptible individuals, causes an immunological reaction that can result in granulomatous scarring of the lung parenchyma, shortness of breath, cough, fatigue, weight loss, and, ultimately, respiratory failure. Beryllium disease was originally identified in the 1940s, largely in the fluorescent light industry. In 1950, the Atomic Energy Commission (AEC) introduced strict exposure standards that generally curtailed both the acute and chronic forms of the disease. Beginning in 1984, with the identification of a CBD case in a DOE contractor worker, there was increased scrutiny of both industrial hygiene practices and individuals in this workforce. To date, over 100 additional cases of beryllium-specific sensitization and/or CBD have been identified. Thus, a disease previously thought to be largely eliminated by the adoption of permissible exposure standards 45 years ago is still a health risk in certain workforces. This good practice guide forms the basis of an acceptable program for controlling workplace exposure to beryllium. It provides (1) Guidance for minimizing worker exposure to beryllium in Defense Programs facilities during all phases of beryllium-related work, including the decontamination and decommissioning (D&D) of facilities. (2) Recommended controls to be applied to the handling of metallic beryllium and beryllium alloys, beryllium oxide, and other beryllium compounds. (3) Recommendations for medical monitoring and surveillance of workers exposed (or potentially exposed) to beryllium, based on the best current understanding of beryllium disease and medical diagnostic tests available. (4) Site-specific safety procedures for all processes of beryllium that is likely to generate dusts, mists, fumes, or small particulates. A beryllium exposure control program should minimize airborne concentrations, the potential for and spread of contamination, the number of times individuals are exposed to beryllium, and the number of employees who may be potentially exposed.

  14. Method for hot pressing beryllium oxide articles

    DOE Patents [OSTI]

    Ballard, Ambrose H. (Oak Ridge, TN); Godfrey, Jr., Thomas G. (Oak Ridge, TN); Mowery, Erb H. (Clinton, TN)

    1988-01-01

    The hot pressing of beryllium oxide powder into high density compacts with little or no density gradients is achieved by employing a homogeneous blend of beryllium oxide powder with a lithium oxide sintering agent. The lithium oxide sintering agent is uniformly dispersed throughout the beryllium oxide powder by mixing lithium hydroxide in an aqueous solution with beryllium oxide powder. The lithium hydroxide is converted in situ to lithium carbonate by contacting or flooding the beryllium oxide-lithium hydroxide blend with a stream of carbon dioxide. The lithium carbonate is converted to lithium oxide while remaining fixed to the beryllium oxide particles during the hot pressing step to assure uniform density throughout the compact.

  15. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature to remove hydrogen sulfide from furnace gases. (2) An understanding of what causes foaming in c

  16. Hanford Site Beryllium Questionnaire Affected Worker Questionnaire

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beryllium Questionnaire Affected Worker Questionnaire Page 1 of 15 Hanford Site Beryllium Interview Questionnaire Affected Worker Interview Date (MM/YYYY) Name (Last, First, MI) HID# DOB (MM/YYYY) Contractor/Employer Home Address City State Zip Code Home Phone Number ( ) - Alternate Phone Number ( ) - Hanford Site Beryllium Questionnaire Affected Worker Questionnaire Page 2 of 15 Hanford Work History Timeline Original Hire Date for the Hanford Site: (MM/YYYY) Contractor: Job Title: Bargaining

  17. Guidance for Informed Choice on Beryllium Testing

    Office of Environmental Management (EM)

    Beryllium Testing for Research and Beyond: The ABCs of the LPT January 2007 Cases of chronic beryllium disease (CBD), a legacy of the Department of Energy's (DOE) role in weapons production, have been increasing across the DOE complex. This trend has sparked increased concern about this serious occupational illness. In a national effort to identify current and former workers who have CBD or are sensitized to beryllium and to better understand the illness, DOE has set up a number of medical

  18. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    06KE Rad Con Count Lab Facility September 23, 1999 January 26, 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: 1960 End: 1960 Location(s) in facility that contained beryllium materials: Laboratory. No beryllium contamination areas were noted during 1999 assessment. Description of beryllium activities: The Coolant Systems Development Operation tested the effects of decontaminating agents on

  19. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Responsible Contractor: Contact: 2714W March 25, 1998 February 9, 2012 N/A Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: Potential Form of beryllium: SOLID (trace on coveralls) Period of beryllium operations (dates): Mid 1960s End: 1991 Location(s) in facility that contained beryllium materials: Laundering area and exterior settling pond. Description of beryllium activities: Potentially beryllium-contaminated laundry was laundered in the facility and wash water was

  20. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    71B B Plant Support Building March 25, 1998 February 9, 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: NO Form of beryllium: N/A Period of beryllium operations (dates): N/A End: N/A Location(s) in facility that contained beryllium materials: None that were known. Description of beryllium activities: This facility appeared on the original list of possible beryllium facilities. Reviews of documentation, facility personnel, a UW research representative, and DOE-RL

  1. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Responsible Contractor: Contact: 272W Machine Shop Building September 23, 1999 January 26, 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: 1955 End: 1980s Location(s) in facility that contained beryllium materials: Machine shop, tool and die shop Description of beryllium activities: Fabrication of electrical connectors using 0.61% beryllium alloy using a machining process and subsequent

  2. 2014 Beryllium-Associated Worker Registry Summary | Department of Energy

    Energy Savers [EERE]

    Beryllium-Associated Worker Registry Summary 2014 Beryllium-Associated Worker Registry Summary March 2016 This report summarizes data reported for beryllium workers from 27 DOE sites and contractors participating in the DOE Beryllium-Associated Worker Registry for the year 2014. Basic demographic information about these workers is included, as is a summary of workers who have become beryllium sensitized and those with chronic beryllium disease. Exposure measurements are also summarized by

  3. Beryllium-Associated Worker Registry | Department of Energy

    Energy Savers [EERE]

    Beryllium-Associated Worker Registry Beryllium-Associated Worker Registry The DOE Domestic and International Health Studies supports the operation of a surveillance registry of current workers who are exposed to beryllium in their current job, or may have been exposed to beryllium in the past from work conducted at a DOE site. The goal of the registry is to determine the incidence and prevalence of beryllium sensitization and chronic beryllium disease (CBD). The data will be analyzed to better

  4. NIOSH Alert-Preventing Sentization and Disease from Beryllium | Department

    Office of Environmental Management (EM)

    of Energy NIOSH Alert-Preventing Sentization and Disease from Beryllium NIOSH Alert-Preventing Sentization and Disease from Beryllium February 3, 2011 Preventing Sensitization and Disease from Beryllium Exposure The National Institute for Occupational Safety and Health (NIOSH) requests assistance in preventing beryllium sensitization and chronic beryllium disease. Development of these conditions requires exposure to beryllium and is affected by both job tasks and genetic factors. Some jobs

  5. 2013 Beryllium-Associated Worker Registry Summary | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Beryllium-Associated Worker Registry Summary 2013 Beryllium-Associated Worker Registry Summary April 2015 This report summarizes data reported for beryllium workers from 27 DOE sites and contractors participating in the DOE Beryllium-Associated Worker Registry for 2013. Basic demographic information about these workers is included, as is a summary of workers who have become beryllium sensitized and those with chronic beryllium disease. Exposure measurements are also summarized by various factors

  6. ORISE: Worker Health Studies - Beryllium Testing Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    or manufacturing activities can cause sensitivity in some persons that may lead to chronic beryllium disease. The Oak Ridge Institute for Science and Education (ORISE)...

  7. Characterization of NIF cryogenic beryllium capsules using x...

    Office of Scientific and Technical Information (OSTI)

    Characterization of NIF cryogenic beryllium capsules using x-ray phase contrast imaging. Citation Details In-Document Search Title: Characterization of NIF cryogenic beryllium...

  8. ORISE: Worker Health Studies - Beryllium Associated Worker Registry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oak Ridge Institute for Science Education Beryllium Associated Worker Registry (BAWR) The Oak Ridge Institute for Science and Education (ORISE) maintains the Beryllium Associated...

  9. Characterization of NIF cryogenic beryllium capsules using x...

    Office of Scientific and Technical Information (OSTI)

    Characterization of NIF cryogenic beryllium capsules using x-ray phase contrast imaging. Citation Details In-Document Search Title: Characterization of NIF cryogenic beryllium ...

  10. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS

    SciTech Connect (OSTI)

    John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

    2002-05-01

    The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

  11. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

    1999-09-01

    Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effects of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and electrostatic precipitator (ESP) fly ash collection efficiency.

  12. Build a Pizza Box Solar Oven | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Build a Pizza Box Solar Oven Build a Pizza Box Solar Oven Below is information about the student activity/lesson plan from your search. Grades K-4, 5-8, 9-12 Subject Solar Summary Check out this staightforward lesson, that can be adapted for all grade levels, on how to build a solar oven. Curriculum Science, Visual Arts, Language Arts Plan Time One class period Materials One pizza box from a local pizza delivery store, tape, scissors, black construction paper, clear plastic wrap, aluminum foil,

  13. Process for synthesis of beryllium chloride dietherate

    DOE Patents [OSTI]

    Bergeron, Charles (Baton Rouge, LA); Bullard, John E. (Kendall Park, NJ); Morgan, Evan (Lynchburg, VA)

    1991-01-01

    A low temperature method of producing beryllium chloride dietherate through the addition of hydrogen chloride gas to a mixture of beryllium metal in ether in a reaction vessel is described. A reflux condenser provides an exit for hydrogen produced form the reaction. A distillation condenser later replaces the reflux condenser for purifying the resultant product.

  14. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P.; Cunningham, R.; Hockings, K.

    1997-12-31

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  15. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    1998-09-01

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  16. ISSUANCE 2015-07-23: Energy Conservation Program: Energy Conservation Standards for Residential Conventional Ovens

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for Residential Conventional Ovens, Comment Period Extension

  17. Petroleum-derived additive reduces coke on hydrotreating catalyst

    SciTech Connect (OSTI)

    Not Available

    1993-12-27

    Upgrading heavy oils is becoming increasingly important as the world crude slate gets heavier and demand for light products increases. But most upgrading processes must contend with problems related to coke formation during hydrotreating. Three researchers have found that materials having high radical-scavenging ability can reduce coke formation when applied to hydrotreating heavy oils. And these materials can be produced from heavy petroleum fractions. The paper discusses coke formation, the research program, and the pilot plant.

  18. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9-E Tank Farm Waste Support Facility February 23, 2004 March 20, 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: Pre-1985 End: Pre-1997 Location(s) in facility that contained beryllium materials: Characterization sampling was conducted in 2010. The CAR and MIX rooms remained posted as potential beryllium contaminated systems due to the high radioactivity levels in the Gloveboxes and Hoods

  19. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    22T Office Administration Building February 23, 2004 January 31, 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: 1952 End: 1952 Location(s) in facility that contained beryllium materials: Data on the 1952 operations indicate beryllium was used inside a ventilation hood in Room 6. However, Room 6 could not be located on 8/5/99. The earlier data may refer to Room 106. No currently marked

  20. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    36Z Plutonium Storage Facility June 30, 2004 January 26, 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Built in 1971. Unknown Location(s) in facility that contained beryllium materials: Miscellaneous plutonium products potentially containing trace quantities of beryllium were stored in sealed 3013-type containers within vaults 1, 3 and 4. Plutonium products stored in sealed containers in 2736Z

  1. Chronic Beryllium Disease Prevention Program (10 CFR 850) | Department of

    Office of Environmental Management (EM)

    Energy Chronic Beryllium Disease Prevention Program (10 CFR 850) Chronic Beryllium Disease Prevention Program (10 CFR 850) The DOE established a chronic beryllium disease prevention program (CBDPP) to reduce the number of workers currently exposed to beryllium in the course of their work at DOE facilities managed by DOE or its contractors, minimize the levels of, and potential for, exposure to beryllium, and establish medical surveillance requirements to ensure early detection of the

  2. Reducing power production costs by utilizing petroleum coke. Annual report

    SciTech Connect (OSTI)

    Galbreath, K.C.

    1998-07-01

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  3. Nippon Coke and Engineering Sumitomo Corp JV | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: Nippon Coke and Engineering & Sumitomo Corp JV Place: Tokyo, Japan Zip: 135-6007 Product: Japan-based natural graphite base anode materials joint...

  4. THE IDAHO NATIONAL LABORATORY BERYLLIUM TECHNOLOGY UPDATE

    SciTech Connect (OSTI)

    Glen R. Longhurst

    2007-12-01

    A Beryllium Technology Update meeting was held at the Idaho National Laboratory on July 18, 2007. Participants came from the U.S., Japan, and Russia. There were two main objectives of this meeting. One was a discussion of current technologies for beryllium in fission reactors, particularly the Advanced Test Reactor and the Japan Materials Test Reactor, and prospects for material availability in the coming years. The second objective of the meeting was a discussion of a project of the International Science and Technology Center regarding treatment of irradiated beryllium for disposal. This paper highlights discussions held during that meeting and major conclusions reached

  5. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    Broader source: Energy.gov [DOE]

    Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

  6. 2013 Beryllium-Associated Worker Registry Summary

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Table of Contents Beryllium-Associated Worker Registry Summary............................................................................................................................... 1 Location of 27 Sites and Subcontractors Currently Submitting Data to BAWR ............................................................................. 4 27 Sites and Subcontractors Currently Submitting Data to BAWR

  7. Chronic Beryllium Disease Prevention Program Report

    SciTech Connect (OSTI)

    Lee, S

    2012-03-29

    This document describes how Lawrence Livermore National Laboratory (LLNL) meets the requirements and management practices of federal regulation 10 CFR 850, 'Chronic Beryllium Disease Prevention Program (CBDPP).' This revision of the LLNL CBDPP incorporates clarification and editorial changes based on lessons learned from employee discussions, observations and reviews of Department of Energy (DOE) Complex and commercial industry beryllium (Be) safety programs. The information is used to strengthen beryllium safety practices at LLNL, particularly in the areas of: (1) Management of small parts and components; and (2) Communication of program status to employees. Future changes to LLNL beryllium activities and on-going operating experience will be incorporated into the program as described in Section S, 'Performance Feedback.'

  8. LLNS Beryllium Consent Order Fact Sheet

    Office of Environmental Management (EM)

    - LLNS Beryllium Consent Order SUMMARY OF CONSENT ORDER In November 2010, the U.S. Department of Energy (DOE) and the National Nuclear Security Administration (NNSA) issued a consent order to Lawrence Livermore National Security, LLC (LLNS) for deficiencies related to LLNS's implementation of DOE's Chronic Beryllium Disease Prevention Program (CBDPP) regulation at Lawrence Livermore National Laboratory. The consent order requires LLNS to implement corrective actions that will ensure LLNS meets

  9. Transgenic Mouse Model of Chronic Beryllium Disease

    SciTech Connect (OSTI)

    Gordon, Terry

    2009-05-26

    Animal models provide powerful tools for dissecting dose-response relationships and pathogenic mechanisms and for testing new treatment paradigms. Mechanistic research on beryllium exposure-disease relationships is severely limited by a general inability to develop a sufficient chronic beryllium disease animal model. Discovery of the Human Leukocyte Antigen (HLA) - DPB1Glu69 genetic susceptibility component of chronic beryllium disease permitted the addition of this human beryllium antigen presentation molecule to an animal genome which may permit development of a better animal model for chronic beryllium disease. Using FVB/N inbred mice, Drs. Rubin and Zhu, successfully produced three strains of HLA-DPB1 Glu 69 transgenic mice. Each mouse strain contains a haplotype of the HLA-DPB1 Glu 69 gene that confers a different magnitude of odds ratio (OR) of risk for chronic beryllium disease: HLA-DPB1*0401 (OR = 0.2), HLA-DPB1*0201 (OR = 15), HLA-DPB1*1701 (OR = 240). In addition, Drs. Rubin and Zhu developed transgenic mice with the human CD4 gene to permit better transmission of signals between T cells and antigen presenting cells. This project has maintained the colonies of these transgenic mice and tested the functionality of the human transgenes.

  10. Container for heat treating materials in microwave ovens

    DOE Patents [OSTI]

    Holcombe, Cressie E. (Farragut, TN); Dykes, Norman L. (Oak Ridge, TN); Kimrey, Jr., Harold D. (Knoxville, TN); Mills, James E. (Knoxville, TN)

    1989-01-01

    The efficiency of a microwave oven of a conventional two-source configuration and energy level is increased by providing the oven with a container for housing a refractory material to be treated. The container is formed of top and bottom walls transparent to microwaves while the sidewalls, in a circular configuration, are formed of a nonmetallic material opaque to microwave radiation reflecting the radiation penetrating the top and bottom walls radially inwardly into the center of the container wherein a casket of heat-insulating material is provided for housing the material to be heat treated. The reflection of the microwave radiation from the sidewalls increases the concentration of the microwaves upon the material being heat treated while the casket retains the heat to permit the heating of the material to a substantially higher temperature than achieveable in the oven without the container.

  11. A container for heat treating materials in microwave ovens

    DOE Patents [OSTI]

    Holcombe, C.E.; Dykes, N.L.; Kimrey, H.D. Jr.; Mills, J.E.

    1988-01-26

    The efficiency of a microwave oven of a conventional two-source configuration and energy level is increased by providing the oven with a container for housing a refractory material to be treated. The container is formed to top and bottom walls transparent to microwaves while the sidewalls, in a circular configuration, are formed of a nonmetallic material opaque to microwave radiation for reflecting the radiation penetrating the top and bottom walls radially inwardly into the center of the container wherein a casket of heat-insulating material is provided for housing the material to be heat treated. The reflection of the microwave radiation from the sidewalls increases the concentration of the microwaves upon the material being heat treated while the concentration of the microwaves upon the material being heat treated while the casket retains the heat to permit the heating of the material to a substantially higher temperature than achievable in the oven without the container.

  12. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    45Z Plutonium Fabrication Facility June 30, 2004 February 7, 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: Yes Form of beryllium: SOLID Period of beryllium operations (dates): Start: 1961 End: 2012 Location(s) in facility that contained beryllium materials: Pure beryllium metallic powder was used in the Standards Lab Rooms 221C, 221D & 221E until mid-1980s. Approximately 25 grams of beryllium was stored in a vial in this area. Waste records document that the

  13. Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Updates the Social Cost of Carbon | Department of Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and Updates the Social Cost of Carbon Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and Updates the Social Cost of Carbon August 21, 2013 - 9:18am Addthis A typical microwave is used to heat food for about 70 hours each year, but continues to use electricity for the remaining 8,690 hours of the year to power the electronic controls and display. On

  14. Table 16. U.S. Coke Exports

    Gasoline and Diesel Fuel Update (EIA)

    6. U.S. Coke Exports (short tons) Year to Date Continent and Country of Destination July - September 2015 April - June 2015 July - September 2014 2015 2014 Percent Change North America Total 151,884 301,843 315,628 553,020 599,779 -7.8 Canada* 137,062 273,140 229,301 477,799 380,794 25.5 Mexico 14,476 28,404 85,930 74,273 217,777 -65.9 Other** 346 299 397 948 1,208 -21.5 South America Total 298 - 39 376 1,151 -67.3 Other** 298 - 39 376 1,151 -67.3 Europe Total 19 140 184 35,581 1,450 NM Other**

  15. Table 21. U.S. Coke Imports

    Gasoline and Diesel Fuel Update (EIA)

    1. U.S. Coke Imports (short tons) Year to Date Continent and Country of Origin July - September 2015 April - June 2015 July - September 2014 2015 2014 Percent Change North America Total 26,442 2,184 1,212 30,661 39,596 -22.6 Canada 26,442 2,184 1,212 30,661 39,596 -22.6 South America Total 16,976 322 10,544 17,298 10,544 64.1 Colombia 16,976 322 10,544 17,298 10,544 64.1 Europe Total 29,060 6,280 61 35,354 62 NM Czech Republic - 5,300 - 5,300 - - France - 15 - 15 - - Germany, Federal Republic of

  16. ORISE: Beryllium Laboratory Accredited by College of American...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    proliferation test FOR IMMEDIATE RELEASE: Aug. 12, 2011 FY11-41 Linda Nichols performs blood test in ORISE Beryllium Lab Linda Nichols, MS, MT(ASCP) and Beryllium Lab manager,...

  17. Chronic beryllium disease: Diagnosis and management

    SciTech Connect (OSTI)

    Rossman, M.D.

    1996-10-01

    Chronic beryllium disease is predominantly a pulmonary granulomatosis that was originally described in 1946. Symptoms usually include dyspnea and cough. Fever, anorexia, and weight loss are common. Skin lesions are the most common extrathoracic manifestation. Granulomatous hepatitis, hypercalcemia, and kidney stones can also occur. Radiographic and physiologic abnormalities are similar to those in sarcoidosis. While traditionally the pathologic changes included granulomas and cellular interstitial changes, the hallmark of the disease today is the well-formed granuloma. Immunologic studies have demonstrated a cell-mediated response to beryllium that is due to an accumulation of CD4{sup +} T cells at the site of disease activity. Diagnosis depends on the demonstration of pathologic changes (i.e., granuloma) and evidence that the granuloma was caused by a hypersensitivity to beryllium (i.e., positive lung proliferative response to beryllium). Using these criteria, the diagnosis of chronic beryllium disease can now be made before the onset of clinical symptoms. Whether, with early diagnosis, the natural course of this condition will be the same as when it was traditionally diagnosed is not known. Currently, corticosteroids are used to treat patients with significant symptoms or evidence of progressive disease. 21 refs.

  18. 2011 Beryllium-Associated Worker Registry Summary | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Beryllium-Associated Worker Registry Summary 2011 Beryllium-Associated Worker Registry Summary September 2011 The DOE Beryllium-Associated Worker Registry (BAWR) is a collection of health and exposure information of individuals potentially at risk for chronic beryllium disease (CBD) due to their work at DOE-owned or leased facilities. The BAWR is a risk management tool for sites to use in managing their CBD prevention programs and other risk management operations. Sites are encouraged to use

  19. 2012 Beryllium-Associated Worker Registry Summary | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Beryllium-Associated Worker Registry Summary 2012 Beryllium-Associated Worker Registry Summary August 2013 The DOE Beryllium-Associated Worker Registry (BAWR) is a collection of health and exposure information of individuals potentially at risk for chronic beryllium disease (CBD) due to their work at DOE-owned or leased facilities. The BAWR is a risk management tool for sites to use in managing their CBD prevention programs and other risk management operations. Sites are encouraged to use their

  20. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    36Z Plutonium Reclamation Building June 30, 2004 February 9, 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: VARIES Period of beryllium operations (dates): Start: 1973 End: 2004 Location(s) in facility that contained beryllium materials: Miscellaneous Treatment (MT) gloveboxes MT-1, MT-3, MT-4, MT-5, MT-6 and the connecting conveyor glovebox in Room 41. These enclosures and downstream ventilation systems in Room 26 are indicated with a

  1. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ZB Plutonium Storage Support Facility June 30, 2004 January 26, 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Unknown Location(s) in facility that contained beryllium materials: Gloveboxes 642A through F in Room 642 were used to stabilize plutonium-containing waste material and repackage plutonium material. Miscellaneous plutonium products were stored in sealed 3013-type containers in Room 637.

  2. ORISE: Worker Health Studies - Testing Beryllium Vendor Populations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oak Ridge Institute for Science Education Beryllium Testing Vendor Populations When former employees at 25 closed U.S. Department of Energy (DOE) beryllium vendor companies needed an entity to provide medical screening and tests related to their beryllium exposure, the agency chose the Oak Ridge Institute for Science and Education (ORISE) to manage the program. ORISE administers a brief health questionnaire and a blood test known as the beryllium lymphocyte proliferation test (BeLPT) to

  3. Former Workers Medical Facilities with Experience Evaluating Chronic Beryllium Disease

    Broader source: Energy.gov [DOE]

    This document provides a listing of medical facilities within the United States with experience in evaluating Chronic Beryllium Disease.

  4. ORISE: Worker Health Studies - Beryllium Exposure Studies and Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beryllium Testing Vendor Populations Beryllium Associated Worker Registry Beryllium Testing Laboratory Radiation Exposure Data Collection Protecting Human Subjects How ORISE is Making a Difference Overview Argonne Electronic Medical Records System Beryllium Testing and Surveillance Radiation Exposure Information and Reporting System (REIRS) U.S. Department of Energy Radiation Exposure Monitoring System (REMS) DOE IISP 10-Year Summary Report Resources Overview Reports Peer-Reviewed Journal

  5. Bush Administration to Expand Beryllium Disease Screening Program |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Bush Administration to Expand Beryllium Disease Screening Program Bush Administration to Expand Beryllium Disease Screening Program February 23, 2005 - 10:27am Addthis Former employees of DOE vendors eligible for free screening WASHINGTON, DC - U.S. Secretary of Energy Samuel W. Bodman today announced the Department of Energy (DOE) will expand a beryllium screening program to include former employees of now-defunct DOE beryllium vendor companies across the country.

  6. Review of Beryllium Management Practices at Rocky Flats During Closure

    Energy Savers [EERE]

    Operations | Department of Energy Review of Beryllium Management Practices at Rocky Flats During Closure Operations Review of Beryllium Management Practices at Rocky Flats During Closure Operations Administrative and engineering controls, along with detailed medical and training programs and strict adherence to all characterization, sampling, and work procedures ensured that exposure to beryllium by RFETS employees was minimized to the highest extent possible. PDF icon Review of Beryllium

  7. Beryllium Screening - Informed Choice Document | Department of Energy

    Energy Savers [EERE]

    Beryllium Screening - Informed Choice Document Beryllium Screening - Informed Choice Document January 2007 Cases of chronic beryllium disease (CBD), a legacy of the Department of Energy's (DOE) role in weapons production, have been increasing across the DOE complex. This trend has sparked increased concern about this serious occupational illness. In a national effort to identify current and former workers who have CBD or are sensitized to beryllium and to better understand the illness, DOE has

  8. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

    2003-06-01

    Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

  9. Methods for retarding coke formation during pyrolytic hydrocarbon processing

    SciTech Connect (OSTI)

    Not Available

    1993-06-22

    A method is described for inhibiting the formation and deposition of pyrolytic coke on the heated metal surfaces in contact with a hydrocarbon feedstock which is undergoing pyrolytic processing to produce lower hydrocarbon fractions and said metal surfaces having a temperature of about 1,400 F or higher, consisting essentially of adding to said hydrocarbon feedstock being pyrolytically processed a coke inhibiting amount of hydroquinone.

  10. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2S REDOX February 23, 2004 February 14 , 2012 CHPRC Kristy Kimmerle, CIH PAST OPERATIONS Beryllium brought in facility: None known. Form of beryllium: N/A Period of beryllium operations (dates): Start: N/A End: N/A Location(s) in facility that contained beryllium materials: Two survey units in the facility are contaminated with beryllium. They are the east end of the Upper South Pipe (Operating) Gallery and the Administration rooms on the southwest side. It is not known how these areas were

  11. DOE - Office of Legacy Management -- Beryllium Corp - PA 39

    Office of Legacy Management (LM)

    Beryllium Corp - PA 39 FUSRAP Considered Sites Site: BERYLLIUM CORP. (PA.39 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Brush Beryllium PA.39-1 Location: Reading , Pennsylvania PA.39-1 Evaluation Year: 1987 PA.39-1 Site Operations: Production of Beryllium circa late 1940s - 50s. PA.39-1 Site Disposition: Eliminated - No radioactive material handled at this site, only Beryllium PA.39-1 Radioactive Materials Handled: No PA.39-1 Primary

  12. Study on rheological characteristics of petroleum coke residual oil slurry

    SciTech Connect (OSTI)

    Shou Weiyi; Xu Xiaoming; Cao Xinyu

    1997-07-01

    We have embarked on a program to develop petroleum coke residual oil slurry (POS) as an alternative fuel for existing oil-fired boilers. The industrial application of petroleum coke residual oil slurry requires full knowledge of its flow behavior. This paper will present the results of an experimental investigation undertaken to study the Theological properties using a rotating viscometer at shear rate up to 996 s{sup -1}. The effects of temperature, concentration, particle size distribution and additives are also investigated. The experiments show that petroleum coke residual oil slurry exhibits pseudoplastic behavior, which has favorable viscosity property under a certain condition and has broad prospect to be applied on oil-fired boilers.

  13. ORISE: Beryllium laboratory achieves accreditation from College of American

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pathologists Beryllium laboratory achieves accreditation from College of American Pathologists ORISE beryllium laboratory in Oak Ridge accredited for the third time since 2009 FOR IMMEDIATE RELEASE July 14, 2015 FY15-42 OAK RIDGE, Tenn.-The College of American Pathologists, or CAP, has accredited the beryllium laboratory in Oak Ridge for the third time since the laboratory's first accreditation in 2009. The laboratory is managed by ORAU for the Department of Energy's Oak Ridge Institute for

  14. LLNS Beryllium Consent Order Fact Sheet | Department of Energy

    Office of Environmental Management (EM)

    LLNS Beryllium Consent Order Fact Sheet LLNS Beryllium Consent Order Fact Sheet In November 2010, the U.S. Department of Energy (DOE) and the National Nuclear Security Administration (NNSA) issued a consent order to Lawrence Livermore National Security, LLC (LLNS) for deficiencies related to LLNS's implementation of DOE's Chronic Beryllium Disease Prevention Program (CBDPP) regulation at Lawrence Livermore National Laboratory. The consent order requires LLNS to implement corrective actions that

  15. Microsoft Word - Blue Cover Report - Beryllium Controls at LLNL

    Office of Environmental Management (EM)

    Implementation of Beryllium Controls at Lawrence Livermore National Laboratory DOE/IG-0851 June 2011 Department of Energy Washington, DC 20585 June 17, 2011 MEMORANDUM FOR THE SECRETARY FROM: Gregory H. Friedman Inspector General SUBJECT: INFORMATION: Audit Report on the "Implementation of Beryllium Controls at Lawrence Livermore National Laboratory" BACKGROUND The Department of Energy has a long history of using beryllium - a metal essential for nuclear operations and other processes.

  16. The evaluation of the Nippon Steel Corporation reactivity and post-reaction-strength test for coke

    SciTech Connect (OSTI)

    Not Available

    1980-12-01

    A systematic investigation was made of the factors influencing the reactivity of coke, including test temperature, coke structural properties, mineral inclusions and additives, and the inert content of the charge.

  17. Quantitative method of determining beryllium or a compound thereof in a sample

    DOE Patents [OSTI]

    McCleskey, T. Mark (Los Alamos, NM); Ehler, Deborah S. (Los Alamos, NM); John, Kevin D. (Santa Fe, NM); Burrell, Anthony K. (Los Alamos, NM); Collis, Gavin E. (Los Alamos, NM); Minogue, Edel M. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM)

    2010-08-24

    A method of determining beryllium or a beryllium compound thereof in a sample, includes providing a sample suspected of comprising beryllium or a compound thereof, extracting beryllium or a compound thereof from the sample by dissolving in a solution, adding a fluorescent indicator to the solution to thereby bind any beryllium or a compound thereof to the fluorescent indicator, and determining the presence or amount of any beryllium or a compound thereof in the sample by measuring fluorescence.

  18. Quantitative method of determining beryllium or a compound thereof in a sample

    DOE Patents [OSTI]

    McCleskey, T. Mark; Ehler, Deborah S.; John, Kevin D.; Burrell, Anthony K.; Collis, Gavin E.; Minogue, Edel M.; Warner, Benjamin P.

    2006-10-31

    A method of determining beryllium or a beryllium compound thereof in a sample, includes providing a sample suspected of comprising beryllium or a compound thereof, extracting beryllium or a compound thereof from the sample by dissolving in a solution, adding a fluorescent indicator to the solution to thereby bind any beryllium or a compound thereof to the fluorescent indicator, and determining the presence or amount of any beryllium or a compound thereof in the sample by measuring fluorescence.

  19. Table 38. Coal Stocks at Coke Plants by Census Division

    Gasoline and Diesel Fuel Update (EIA)

    Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2014 Table 38. Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2014 Census Division June 30, 2014 March 31, 2014 June 30, 2013 Percent Change (June 30) 2014 versus 2013 Middle Atlantic 547 544 857 -36.2 East North Central 1,130 963 1,313 -13.9 South Atlantic

  20. Beryllium-7 labeled carbon particles and method of making

    DOE Patents [OSTI]

    Richards, P.; Mausner, L.F.; Prach, T.F.

    1987-11-17

    Beryllium-7 labeled carbon particles made from the proton irradiation of carbon materials, preferably from dry carbon black are disclosed. Such particles are useful as gamma emitting radiotracers.

  1. Beryllium-7 labeled carbon particles and method of making

    DOE Patents [OSTI]

    Richards, P.; Mausner, L.F.; Prach, T.F.

    1985-04-29

    Beryllium-7 labeled carbon particles made from the proton irradiation of carbon materials, preferably from dry carbon black are disclosed. Such particles are useful as gamma emitting radiotracers.

  2. Beryllium-7 labeled carbon particles and method of making

    DOE Patents [OSTI]

    Richards, Powell (New Bern, NC); Mausner, Leonard F. (Stony Brook, NY); Prach, Thomas F. (Port Jefferson, NY)

    1987-01-01

    Beryllium-7 labeled carbon particles made from the proton irradiation of carbon materials, preferably from dry carbon black are disclosed. Such particles are useful as gamma emitting radiotracers.

  3. Update on the Hanford Site Chronic Beryllium Disease Prevention...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chronic Beryllium Disease Prevention Program (CBDPP) Stan Branch Richland Operations Office Hanford Advisory Board Health, Safety and Environmental Protection Committee January 7,...

  4. Update on the Hanford Site Chronic Beryllium Disease Prevention...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Training Development and CBDPP Revision & Approval Beryllium Work Permit Building AssessmentCharacterizationVerification Sampling Postings Products in Contractor Training...

  5. The Rocky Flats Environmental Technology Site beryllium characterization project

    SciTech Connect (OSTI)

    Morrell, D.M.; Miller, J.R.; Allen, D.F.

    1999-06-01

    A site beryllium characterization project was completed at the Rocky Flats Environmental Technology Site (RFETS) in 1997. Information from historical reviews, previous sampling surveys, and a new sampling survey were used to establish a more comprehensive understanding of the locations and levels of beryllium contamination in 35 buildings. A feature of the sampling strategy was to test if process knowledge was a good predictor of where beryllium contamination could be found. Results revealed that this technique was effective at identifying where surface contamination levels might exceed the RFETS smear control level but that it was not effective in identifying where low concentrations of beryllium might be found.

  6. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  7. A coke/soot formation model for multiphase reacting flow simulation

    SciTech Connect (OSTI)

    Chang, S.L.; Lottes, S.A.; Petrick, M.; Zhou, C.Q. |

    1997-03-01

    Coke is a by-product in petroleum fluid catalytic cracking (FCC) processes. The concentration of coke in an FCC riser reactor is a critical parameter used to evaluate the riser performance. A coke formation and transport model was developed. It was incorporated into a computational fluid dynamic (CFD) computer code, ICRKFLO, to simulate the coke formation processes in an FCC riser reactor. Based on a similar process, a soot formation model can be derived from the coke formation model and used for diesel combustion processes, where soot is emitted as one of the primary pollutants.

  8. Method for fabricating beryllium-based multilayer structures

    DOE Patents [OSTI]

    Skulina, Kenneth M. (Livermore, CA); Bionta, Richard M. (Livermore, CA); Makowiecki, Daniel M. (Livermore, CA); Alford, Craig S. (Tracy, CA)

    2003-02-18

    Beryllium-based multilayer structures and a process for fabricating beryllium-based multilayer mirrors, useful in the wavelength region greater than the beryllium K-edge (111 .ANG. or 11.1 nm). The process includes alternating sputter deposition of beryllium and a metal, typically from the fifth row of the periodic table, such as niobium (Nb), molybdenum (Mo), ruthenium (Ru), and rhodium (Rh). The process includes not only the method of sputtering the materials, but the industrial hygiene controls for safe handling of beryllium. The mirrors made in accordance with the process may be utilized in soft x-ray and extreme-ultraviolet projection lithography, which requires mirrors of high reflectivity (>60%) for x-rays in the range of 60-140 .ANG. (60-14.0 nm).

  9. Review of Beryllium Management Practices at Rocky Flats During Closure Operations

    Office of Environmental Management (EM)

    DOE-Environmental Management DOE - Complex Wide Review of Beryllium Management Practices at Rocky Flats During Closure Operations Challenge Beryllium (Be) metal is used by DOE in weapons production, as a reactor moderator or reflector, and as a fuel element cladding. Workers who are exposed to high concentrations of beryllium often develop acute beryllium disease caused by the inhalation of beryllium dust or particles which can cause Be sensitivity or chronic Be disease (CBD), a disabling and

  10. An overview of crisis management in the coke industry

    SciTech Connect (OSTI)

    Saunders, D.A.

    1995-12-01

    Members of the American Coke and Coal Chemicals Institute (ACCCI), as responsible corporate citizens, have embraced the concepts of crisis management and progress down the various paths of planning and preparation, monitoring, media communications, community outreach, emergency response, and recovery. Many of the concepts outlined here reflect elements of crisis management guidelines developed by the Chemical Manufacturers Association (CMA). At a coke plant, crises can take the form of fires, chemical releases, labor strikes, feedstock supply disruptions, and excessive snowfall, just to name a few. The CMA defines a crisis as: ``an unplanned event that has the potential to significantly impact a company`s operability or credibility, or to pose a significant environment, economic or legal liability``; and crisis management as: ``those activities undertaken to anticipate or prevent, prepare for, respond to and recover from any incident that has the potential to greatly affect the way a company conducts its business.

  11. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA)

    1991-01-01

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  12. Beryllium Health and Safety Committee Data Reporting Task Force

    SciTech Connect (OSTI)

    MacQueen, D H

    2007-02-21

    On December 8, 1999, the Department of Energy (DOE) published Title 10 CFR 850 (hereafter referred to as the Rule) to establish a chronic beryllium disease prevention program (CBDPP) to: {sm_bullet} reduce the number of workers currently exposed to beryllium in the course of their work at DOE facilities managed by DOE or its contractors, {sm_bullet} minimize the levels of, and potential for, expos exposure to beryllium, and {sm_bullet} establish medical surveillance requirements to ensure early detection of the disease.

  13. Low-coke rate operation under high PCI at Kobe No. 3 BF

    SciTech Connect (OSTI)

    Matsuo, Tadasu; Kanazuka, Yasuo; Hoshino, Koichi; Yoshida, Yasuo; Kitayama, Syuji; Ishiwaki, Shiro

    1997-12-31

    Kobe No. 3 blast furnace (BF) suffered tremendous damage when the Great Hanshin-Awaji Earthquake rocked the area on January 17, 1995. However, working as quickly as possible to dig out of the burden and rehabilitate various facilities, the company managed to restart the No. 3 BF on April 2. After the restart, which went smoothly, production was shifted into the low coke rate operation which was being promoted before the disaster. In October, 1995, only seven months after the restart, the nation record of 296 kg/t low coke rate could be achieved. Subsequently, in January, 1996, coke rate reached 290 kg/t and the low coke rate operation was renewed. Since that time the same level of coke rate has been maintained. The paper discusses how low coke rate operation was achieved.

  14. How to implement a quality program in a coking plant. The AHMSA experience

    SciTech Connect (OSTI)

    Reyes M, M.A.; Perez, J.L.; Garza, C. de la; Morales, M.

    1995-12-01

    AHMSA (Altos Hornos de Mexico) is the largest integrated Steel Plant in Mexico, with its 3.1 MMMT of Liquid Steel production program for 1995. AHMSA operates two coke plants which began operations in 1955 and 1976. Total coke monthly production capacity amounts to as much as 106,000 Metric Tons (MT). The coke plants working philosophy was discussed and established in 1986 as part of the Quality Improvement Program, where its ultimate goal is to give the best possible coke quality to its main client--the blast furnaces. With this goal in mind, a planned joint effort with their own coal mines was initiated. This paper deals with the implementation process of the Quality Program, and the results of this commitment at the coal mines, coke plants and blast furnaces. The coke quality improvement is shown since 1985 to 1994, as well as the impact on the blast furnace operation.

  15. ORISE: Ann Gehl named new manager of Beryllium Lymphocyte Proliferatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    individuals at higher risk of developing Chronic Beryllium Disease that scars the lungs. In 2013, the lab processed nearly 4,100 such tests without a single error. Located in...

  16. Examination of Beryllium Under Intense High Energy Proton Beam...

    Office of Scientific and Technical Information (OSTI)

    Examination of Beryllium Under Intense High Energy Proton Beam at CERN's HiRadMat Facility ... 6th International Particle Accelerator Conference. Richmond, Virginia, USA, 3-8 May 2015.

  17. Update on the Hanford Site Chronic Beryllium Disease Prevention...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by DOE- EM on March 13, 2013 2 Be CAP Status * Rev. 1 of the Hanford site wide Chronic Beryllium Disease Prevention Program (CBDPP) was approved by DOE March 7, 2012 * Rev....

  18. ORISE: Worker Health Studies - Testing Beryllium Vendor Populations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (ORISE) to manage the program. ORISE administers a brief health questionnaire and a blood test known as the beryllium lymphocyte proliferation test (BeLPT) to determine if a...

  19. Development of Biomarkers for Chronic Beryllium Disease in Mice

    SciTech Connect (OSTI)

    Gordon, Terry

    2013-01-25

    Beryllium is a strategic metal, indispensable for national defense programs in aerospace, telecommunications, electronics, and weaponry. Exposure to beryllium is an extensively documented occupational hazard that causes irreversible, debilitating granulomatous lung disease in as much as 3 - 5% of exposed workers. Mechanistic research on beryllium exposure-disease relationships has been severely limited by a general lack of a sufficient CBD animal model. We have now developed and tested an animal model which can be used for dissecting dose-response relationships and pathogenic mechanisms and for testing new diagnostic and treatment paradigms. We have created 3 strains of transgenic mice in which the human antigen-presenting moiety, HLA-DP, was inserted into the mouse genome. Each mouse strain contains HLA-DPB1 alleles that confer different magnitude of risk for chronic beryllium disease (CBD): HLA-DPB1*0401 (odds ratio = 0.2), HLA-DPB1*0201 (odds ratio = 15), HLA-DPB1*1701 (odds ratio = 240). Our preliminary work has demonstrated that the *1701 allele, as predicted by human studies, results in the greatest degree of sensitization in a mouse ear swelling test. We have also completed dose-response experiments examining beryllium-induced lung granulomas and identified susceptible and resistant inbred strains of mice (without the human transgenes) as well as quantitative trait loci that may contain gene(s) that modify the immune response to beryllium. In this grant application, we propose to use the transgenic and ?normal inbred strains of mice to identify biomarkers for the progression of beryllium sensitization and CBD. To achieve this goal, we propose to compare the sensitivity and accuracy of the lymphocyte proliferation test (blood and bronchoalveolar lavage fluid) with the ELISPOT test in the three HLA-DP transgenic mice strains throughout a 6 month treatment with beryllium particles. Because of the availability of high-throughput proteomics, we will also identify changes in potential protein biomarkers in beryllium-treated mice. We will correlate these findings with the ability of the transgenic mice to develop a beryllium-specific adaptive immune response in blood and bronchoalveolar lavage (BAL) fluid. We will also determine whether beryllium-responsive CD4+ T cells in blood and BAL correlate with the onset of granuloma formation. Thus, we will provide the scientific community with biomarkers of sensitization and disease progression for CBD. These biomarkers will serve as critical tools for development of improved industrial hygiene and therapeutic interventions.

  20. ORISE: Ann Gehl named new manager of Beryllium Lymphocyte Proliferation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Gehl named manager of Beryllium Laboratory New manager brings nearly 30 years of laboratory experience to role at ORISE FOR IMMEDIATE RELEASE Sept. 2, 2014 FY14-61 Ann Gehl Ann Gehl (Click for high resolution version) OAK RIDGE, Tenn.-ORAU has announced that Ann Gehl, with nearly 30 years of medical technology and laboratory experience, will become the manager of the Beryllium Lymphocyte Proliferation Laboratory. ORAU manages the lab for the Department of Energy. Gehl is replacing

  1. ORISE: Worker Health Studies - Beryllium Associated Worker Registry (BAWR)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oak Ridge Institute for Science Education Beryllium Associated Worker Registry (BAWR) The Oak Ridge Institute for Science and Education (ORISE) maintains the Beryllium Associated Worker Registry (BAWR) for the U.S. Department of Energy's (DOE) Office of Health, Safety and Security (HSS). ORISE collects data from 25 reporting DOE sites on nearly 20,000 workers, assisting DOE in the analysis of these data focusing on predictive indicators and risk management. Reports are also provided to the

  2. Los Alamos notifies employees, visitors of possible beryllium exposure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Possible beryllium exposure Los Alamos notifies employees, visitors of possible beryllium exposure Current and former Laboratory employees and contractors who either worked at or visited the facility have been-or are in the process of being-notified. January 28, 2009 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to

  3. Actinide/beryllium neutron sources with reduced dispersion characteristics

    DOE Patents [OSTI]

    Schulte, Louis D.

    2012-08-14

    Neutron source comprising a composite, said composite comprising crystals comprising BeO and AmBe.sub.13, and an excess of beryllium, wherein the crystals have an average size of less than 2 microns; the size distribution of the crystals is less than 2 microns; and the beryllium is present in a 7-fold to a 75-fold excess by weight of the amount of AmBe.sub.13; and methods of making thereof.

  4. BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS

    Office of Legacy Management (LM)

    BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS IN LUCKEY, OHIO October 27, 1989 Prepared for: U.S. Department of Energy Formerly Utilized Sites Remedial Action Program Prepared by: R.F. Weston/Office of Technical Services BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS IN LUCKEY, OHIO INTRODUCTION The Department of Energy (DOE) is conducting a program to identify and examine the radiological conditions at sites used in the early years of nuclear

  5. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1980-01-01

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  6. New Energy Efficiency Standards for Microwave Ovens to Save Consumers on Energy Bills

    Broader source: Energy.gov [DOE]

    U.S. Energy Secretary Ernest Moniz announced today that the Energy Department has finalized new energy efficiency standards for microwave ovens that will save consumers nearly $3 billion on their energy bills through 2030.

  7. ISSUANCE 2016-02-09: Energy Conservation Program: Energy Conservation Standards for Standby Mode and Off Mode for Microwave Ovens; Correction

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for Standby Mode and Off Mode for Microwave Ovens; Correction

  8. New additive retards coke formation in ethylene furnace tubes

    SciTech Connect (OSTI)

    Not Available

    1994-05-09

    Adding relatively small amounts of a new additive to the feed stream of a steam cracker can inhibit coke formation on the metal surfaces of processing equipment and increase furnace run time. The additive comprises a variable mixture of four to six inorganic salts in aqueous solution. The components of the additive mixture can be varied, as needed, for processing heavy feed materials such as heavy naphtha and gas oil. The process was first tested at a Korean petrochemical plant and is now operating successfully at a commercial facility in Russia. The results of the Korean trial are presented here.

  9. Teamwork in planning and carrying out the first inspection of the coke dry quenching (CDQ) plant of the Kaiserstuhl Coking Facility

    SciTech Connect (OSTI)

    Burchardt, G.

    1996-12-31

    The coke plant Kaiserstuhl operates a coke dry quenching (CDQ) plant with a downstream installed waste heat boiler to satisfy statutory pollution control rules and requirements. This CDQ which went on stream in March 1993 cools the whole coke production output from the Kaiserstuhl coke plant in counterflow to an inert cooling gas. This brief overview on the whole CDQ plant should elucidate the complex of problems posed when trying to make an exact plant revision plan. After all it was impossible to evaluate or to assess all the interior process technology relevant components during the planning stage as the plant was in operation. The revision data for the first interior check was determined and fixed by the statutory rule for steam boilers and pressure vessels. The relevant terms for this check are mandatorily prescribed. In liaison with the testing agency (RW TUEV) the date for the first revision was fixed for April 1995, that means two years after the first commissioning.

  10. Use of selective oxidation of petroleum residue for production of low-sulfur coke

    SciTech Connect (OSTI)

    Hairudinov, I.R.; Kul`chitskaya, O.V.; Imashev, U.B.

    1995-12-10

    The chemical nature of liquid-phase oxidation of sulfurous petroleum residues by cumene hydroperoxide was studied by a tracer technique. Sulfur compounds are selectively oxidized in the presence of catalytic additives of molybdenum salts. Desulfurization of distillate products and coke during coking of preoxidized raw materials was revealed.

  11. Controlling Beryllium Contaminated Material And Equipment For The Building 9201-5 Legacy Material Disposition Project

    SciTech Connect (OSTI)

    Reynolds, T. D.; Easterling, S. D.

    2010-10-01

    This position paper addresses the management of beryllium contamination on legacy waste. The goal of the beryllium management program is to protect human health and the environment by preventing the release of beryllium through controlling surface contamination. Studies have shown by controlling beryllium surface contamination, potential airborne contamination is reduced or eliminated. Although there are areas in Building 9201-5 that are contaminated with radioactive materials and mercury, only beryllium contamination is addressed in this management plan. The overall goal of this initiative is the compliant packaging and disposal of beryllium waste from the 9201-5 Legacy Material Removal (LMR) Project to ensure that beryllium surface contamination and any potential airborne release of beryllium is controlled to levels as low as practicable in accordance with 10 CFR 850.25.

  12. ORISE: Beryllium Testing and Surveillance for the U.S. Department...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    registry of active beryllium workers for the U.S. Department of Energy's (DOE) Office of Environmental Health. The Beryllium Associated Worker Registry is mandated by 10 CFR 850...

  13. Beryllium processing technology review for applications in plasma-facing components

    SciTech Connect (OSTI)

    Castro, R.G.; Jacobson, L.A.; Stanek, P.W.

    1993-07-01

    Materials research and development activities for the International Thermonuclear Experimental Reactor (ITER), i.e., the next generation fusion reactor, are investigating beryllium as the first-wall containment material for the reactor. Important in the selection of beryllium is the ability to process, fabricate and repair beryllium first-wall components using existing technologies. Two issues that will need to be addressed during the engineering design activity will be the bonding of beryllium tiles in high-heat-flux areas of the reactor, and the in situ repair of damaged beryllium tiles. The following review summarizes the current technology associated with welding and joining of beryllium to itself and other materials, and the state-of-the-art in plasma-spray technology as an in situ repair technique for damaged beryllium tiles. In addition, a review of the current status of beryllium technology in the former Soviet Union is also included.

  14. Validation of cleaning method for various parts fabricated at a Beryllium facility

    SciTech Connect (OSTI)

    Davis, Cynthia M.

    2015-12-15

    This study evaluated and documented a cleaning process that is used to clean parts that are fabricated at a beryllium facility at Los Alamos National Laboratory. The purpose of evaluating this cleaning process was to validate and approve it for future use to assure beryllium surface levels are below the Department of Energy’s release limits without the need to sample all parts leaving the facility. Inhaling or coming in contact with beryllium can cause an immune response that can result in an individual becoming sensitized to beryllium, which can then lead to a disease of the lungs called chronic beryllium disease, and possibly lung cancer. Thirty aluminum and thirty stainless steel parts were fabricated on a lathe in the beryllium facility, as well as thirty-two beryllium parts, for the purpose of testing a parts cleaning method that involved the use of ultrasonic cleaners. A cleaning method was created, documented, validated, and approved, to reduce beryllium contamination.

  15. Report of a technical evaluation panel on the use of beryllium for ITER plasma facing material and blanket breeder material

    SciTech Connect (OSTI)

    Ulrickson, M.A.; Manly, W.D.; Dombrowski, D.E.

    1995-08-01

    Beryllium because of its low atomic number and high thermal conductivity, is a candidate for both ITER first wall and divertor surfaces. This study addresses the following: why beryllium; design requirements for the ITER divertor; beryllium supply and unirradiated physical/mechanical property database; effects of irradiation on beryllium properties; tritium issues; beryllium health and safety; beryllium-coolant interactions and safety; thermal and mechanical tests; plasma erosion of beryllium; recommended beryllium grades for ITER plasma facing components; proposed manufacturing methods to produce beryllium parts for ITER; emerging beryllium materials; proposed inspection and maintenance techniques for beryllium components and coatings; time table and costs; and the importance of integrating materials and manufacturing personnel with designers.

  16. Validation of cleaning method for various parts fabricated at a beryllium facility

    SciTech Connect (OSTI)

    Davis, Cynthia M.

    2015-12-11

    This report describes beryllium and its effect on human health. Furthermore, it proposes strategies for safe use in the lab.

  17. Mission Support Alliance (MSA) (MSA) Beryllium Health Advocate Travel Contacts Company info

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mission Support Alliance (MSA) (MSA) Beryllium Health Advocate Travel Contacts Company info Site Beryllium Health Advocate Washington River Protection Solutions (WRPS) (WRPS) Beryllium Health Advocate Travel Contacts Company info CH2M Hill Plateau Remediation Company (CHPRC) (CHPRC) Beryllium Health Advocate Travel Contacts Company info Calin Tebay (509) 376-5602 office (509) 987-2288 cell Email: Calin_P_Tebay@rl.gov Teri Parke 376-7817 E-mail questions ^Travel Questions-MSA Contact Travel

  18. Method for removal of beryllium contamination from an article

    DOE Patents [OSTI]

    Simandl, Ronald F.; Hollenbeck, Scott M.

    2012-12-25

    A method of removal of beryllium contamination from an article is disclosed. The method typically involves dissolving polyisobutylene in a solvent such as hexane to form a tackifier solution, soaking the substrate in the tackifier to produce a preform, and then drying the preform to produce the cleaning medium. The cleaning media are typically used dry, without any liquid cleaning agent to rub the surface of the article and remove the beryllium contamination below a non-detect level. In some embodiments no detectible residue is transferred from the cleaning wipe to the article as a result of the cleaning process.

  19. Title 10 CFR Part 850, Chronic Beryllium Disease Prevention Program

    Office of Environmental Management (EM)

    federal register Wednesday December 8, 1999 Part III Department of Energy 10 CFR Part 850 Chronic Beryllium Disease Prevention Program; Final Rule VerDate 29-OCT-99 10:58 Dec 07, 1999 Jkt 190000 PO 00000 Frm 00001 Fmt 4717 Sfmt 4717 E:\FR\FM\A08DE0.189 pfrm04 PsN: 08DER3 68854 Federal Register / Vol. 64, No. 235 / Wednesday, December 8, 1999 / Rules and Regulations DEPARTMENT OF ENERGY 10 CFR Part 850 [Docket No. EH-RM-98-BRYLM] RIN 1901-AA75 Chronic Beryllium Disease Prevention Program AGENCY:

  20. CHAPTER 7. BERYLLIUM ANALYSIS BY NON-PLASMA BASED METHODS

    SciTech Connect (OSTI)

    Ekechukwu, A

    2009-04-20

    The most common method of analysis for beryllium is inductively coupled plasma atomic emission spectrometry (ICP-AES). This method, along with inductively coupled plasma mass spectrometry (ICP-MS), is discussed in Chapter 6. However, other methods exist and have been used for different applications. These methods include spectroscopic, chromatographic, colorimetric, and electrochemical. This chapter provides an overview of beryllium analysis methods other than plasma spectrometry (inductively coupled plasma atomic emission spectrometry or mass spectrometry). The basic methods, detection limits and interferences are described. Specific applications from the literature are also presented.

  1. Table 17. Average Price of U.S. Coke Exports

    Gasoline and Diesel Fuel Update (EIA)

    7. Average Price of U.S. Coke Exports (dollars per short ton) Year to Date Continent and Country of Destination July - September 2015 April - June 2015 July - September 2014 2015 2014 Percent Change North America Total 234.67 253.60 264.43 252.47 261.48 -3.4 Canada* 209.80 247.54 287.72 243.43 285.74 -14.8 Mexico 460.37 307.48 200.84 305.69 217.48 40.6 Other** 643.59 666.50 577.54 640.63 545.34 17.5 South America Total 135.27 - 465.18 252.87 154.98 63.2 Other** 135.27 - 465.18 252.87 154.98 63.2

  2. Table 22. Average Price of U.S. Coke Imports

    Gasoline and Diesel Fuel Update (EIA)

    2. Average Price of U.S. Coke Imports (dollars per short ton) Year to Date Continent and Country of Origin July - September 2015 April - June 2015 July - September 2014 2015 2014 Percent Change North America Total 120.37 192.95 189.61 131.75 96.81 36.1 Canada 120.37 192.95 189.61 131.75 96.81 36.1 South America Total 201.39 274.73 223.17 202.76 223.17 -9.1 Colombia 201.39 274.73 223.17 202.76 223.17 -9.1 Europe Total 120.34 302.86 363.18 153.02 397.65 -61.5 Czech Republic - 288.36 - 288.36 - -

  3. EERE Success Story-Energy Efficiency Standards for Microwave Ovens Saves

    Office of Environmental Management (EM)

    Consumers Energy and Updates the Social Cost of Carbon | Department of Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and Updates the Social Cost of Carbon EERE Success Story-Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and Updates the Social Cost of Carbon August 21, 2013 - 9:18am Addthis A typical microwave is used to heat food for about 70 hours each year, but continues to use electricity for the remaining 8,690 hours of the year to power

  4. Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report No. 1, May 1--August 1, 1998

    SciTech Connect (OSTI)

    1998-08-15

    The overall aim of the project is to demonstrate the performance and practical use of a laser ultrasonic probe for measuring the thickness of coke deposits located within the high temperature tubes of a thermal cracking furnace. This aim will be met by constructing an optical probe that will be tested using simulated coke deposits that are positioned inside of a bench-scale furnace. Successful development of the optical coke detector will provide industry with the only available method for on-line measurement of coke deposits. The optical coke detector will have numerous uses in the refining and petrochemical sectors including monitoring of visbreakers, hydrotreaters, delayed coking units, vacuum tower heaters, and various other heavy oil heating applications where coke formation is a problem. The coke detector will particularly benefit the olefins industry where high temperature thermal crackers are used to produce ethylene, propylene, butylene and other important olefin intermediates. The ethylene industry requires development of an on-line method for gauging the thickness of coke deposits in cracking furnaces because the current lack of detailed knowledge of coke deposition profiles introduces the single greatest uncertainty in the simulation and control of modern cracking furnaces. The laser ultrasonic coke detector will provide operators with valuable new information allowing them to better optimize the decoking turnaround schedule and therefore maximize production capacity.

  5. Organophosphorus compounds as coke inhibitors during naphtha pyrolysis. Effect of benzyl diethyl phosphite and triphenylphosphine sulfide

    SciTech Connect (OSTI)

    Das, P.; Prasad, S.; Kunztu, D.

    1992-09-01

    This paper reports that significant reduction in the rate of coke formation during naphtha pyrolysis was achieved by adding benzyl diethyl phosphite or triphenylphosphine sulfide to the feed. Although the yield of carbon oxides was reduced, there was no effect of these additives on the hydrocarbon yields. Addition of these organophosphorus compounds significantly reduced the concentration of metals, such as iron, nickel, and chromium, incorporated in the coke. A previously proposed model for coke inhibition due to the formation of a passivating metal-phosphorus complex could satisfactorily correlate the data.

  6. The effect of processing parameters on plasma sprayed beryllium for fusion applications

    SciTech Connect (OSTI)

    Castro, R.G.; Stanek, P.W.; Jacobson, L.A.; Cowgill, D.F.; Snead, L.L.

    1993-10-01

    Plasma spraying is being investigated as a potential coating technique for applying thin (0.1--5mm) layers of beryllium on plasma facing surfaces of blanket modules in ITER and also as an in-situ repair technique for repairing eroded beryllium surfaces in high heat flux divertor regions. High density spray deposits (>98% of theoretical density) of beryllium will be required in order to maximize the thermal conductivity of the beryllium coatings. A preliminary investigation was done to determine the effect of various processing parameters (particle size, particle morphology, secondary gas additions and reduced chamber pressure) on the as-deposited density of beryllium. The deposits were made using spherical beryllium feedstock powder which was produced by centrifugal atomization at Los Alamos National Laboratory (LANL). Improvements in the as-deposited densities and deposit efficiencies of the beryllium spray deposits will be discussed along with the corresponding thermal conductivity and outgassing behavior of these deposits.

  7. An investigation of the properties of pitch coke modified by chemically active additives

    SciTech Connect (OSTI)

    Kulakov, V.V.; Fedeneva, E.N.; Neproshin, E.I.

    1984-01-01

    The results of an investigation are presented of the influence of chemically active additives on the yield and properties of coke from hard-coal pitch. A comparison has been made of the efficacy of the influence of these additives.

  8. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1981-01-01

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  9. Application of process safety management to the coke industry

    SciTech Connect (OSTI)

    Mentzer, W.P. (USX Corp., Clairton, PA (United States))

    1994-09-01

    OSHA's Process Safety Management (PSM) standard went into effect on May 26, 1992. Explosions at various industrial facilities that claimed the lives of workers over the past several years were the catalyst for the new federal regulations. The new PSM standard deals with 130 specific chemicals along with flammable liquids and gases used at nearly 25,000 worksites. The performance-based PSM standard consists of 14 elements that establish goals and describe basic program elements to fulfill these goals. The PSM standard requires employers to conduct a process hazard analysis to examine potential problems and determine what preventative measures should be taken. Key elements include employee training, written operating procedures, safety reviews and maintenance requirements to insure the mechanical integrity of critical components. The presentation will cover the evolution of OSHA's PSM standard, the requirements of the 14 elements in the PSM standard and discuss the significant achievements in the development and implementation of the PSM process at US Steel's Clairton coke plant.

  10. Characterization of NIF cryogenic beryllium capsules using x-ray phase

    Office of Scientific and Technical Information (OSTI)

    contrast imaging. (Conference) | SciTech Connect Characterization of NIF cryogenic beryllium capsules using x-ray phase contrast imaging. Citation Details In-Document Search Title: Characterization of NIF cryogenic beryllium capsules using x-ray phase contrast imaging. Beryllium capsules filled with cryogenic deuterium and tritium fuel layers may provide many advantages for obtaining ignition at the National Ignition Facility (NIF). However, characterizing the uniformity and thickness of the

  11. DOE - Office of Legacy Management -- Brush Beryllium Co - Elmore - OH 09

    Office of Legacy Management (LM)

    Elmore - OH 09 FUSRAP Considered Sites Site: Brush Beryllium Co - Elmore (OH.09 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Elmore , Ohio OH.09-1 Evaluation Year: 1987 OH.09-1 Site Operations: Beryllium Research, Development and Fabrication. OH.09-1 Site Disposition: Eliminated - Operations were moved to the Luckey Plant - Beryllium work only OH.09-1 Radioactive Materials Handled: No OH.09-1 Primary Radioactive Materials

  12. DOE - Office of Legacy Management -- Brush Beryllium Co - Lorain - OH 47

    Office of Legacy Management (LM)

    Lorain - OH 47 FUSRAP Considered Sites Site: Brush Beryllium Co. - Lorain (OH.47 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 1st Street and Hamilton Avenue , Lorain , Ohio OH.47-1 Evaluation Year: 1987 OH.47-1 Site Operations: Production of beryllium metal and compounds, such as beryllium fluoride; used isotopes in the separation of zirconium and hafnium. OH.47-1 OH.47-2 OH.47-3 Site Disposition: Eliminated - Potential for

  13. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    SciTech Connect (OSTI)

    2009-02-01

    This factsheet describes a research project whose goal is to reduce the energy and carbon intensity of the calcined coke production process.

  14. Impact of HFIR LEU Conversion on Beryllium Reflector Degradation Factors

    SciTech Connect (OSTI)

    Ilas, Dan

    2013-10-01

    An assessment of the impact of low enriched uranium (LEU) conversion on the factors that may cause the degradation of the beryllium reflector is performed for the High Flux Isotope Reactor (HFIR). The computational methods, models, and tools, comparisons with previous work, along with the results obtained are documented and discussed in this report. The report documents the results for the gas and neutronic poison production, and the heating in the beryllium reflector for both the highly enriched uranium (HEU) and LEU HFIR configurations, and discusses the impact that the conversion to LEU may have on these quantities. A time-averaging procedure was developed to calculate the isotopic (gas and poisons) production in reflector. The sensitivity of this approach to different approximations is gauged and documented. The results show that the gas is produced in the beryllium reflector at a total rate of 0.304 g/cycle for the HEU configuration; this rate increases by ~12% for the LEU case. The total tritium production rate in reflector is 0.098 g/cycle for the HEU core and approximately 11% higher for the LEU core. A significant increase (up to ~25%) in the neutronic poisons production in the reflector during the operation cycles is observed for the LEU core, compared to the HEU case, for regions close to the core s horizontal midplane. The poisoning level of the reflector may increase by more than two orders of magnitude during long periods of downtime. The heating rate in the reflector is estimated to be approximately 20% lower for the LEU core than for the HEU core. The decrease is due to a significantly lower contribution of the heating produced by the gamma radiation for the LEU core. Both the isotopic (gas and neutronic poisons) production and the heating rates are spatially non-uniform throughout the beryllium reflector volume. The maximum values typically occur in the removable reflector and close to the midplane.

  15. ORISE: ORAU-managed beryllium lab marks outstanding year in 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    higher risk of developing Chronic Beryllium Disease, a chronic disease that scars the lungs making it more difficult for oxygen to transfer into the bloodstream. The test...

  16. ORISE: ORAU-managed beryllium lab marks outstanding year in 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ORAU-managed beryllium lab marks outstanding year in 2013 Lab managed for DOE achieves zero error rate in beryllium lymphocyte proliferation test FOR IMMEDIATE RELEASE April 3, 2014 FY14-16 OAK RIDGE, Tenn.-For the second time in recent years, the Beryllium Testing Laboratory, managed by ORAU for the Department of Energy, performed flawlessly by processing nearly 4,100 beryllium lymphocyte proliferation tests (BeLPTs) in 2013, without a single error. The laboratory is one of only three

  17. A fully integrated oven controlled microelectromechanical oscillator Part II. Characterization and measurement

    SciTech Connect (OSTI)

    Wojciechowski, Kenneth E.; Olsson, Roy H.

    2015-06-24

    Our paper reports the measurement and characterization of a fully integrated oven controlled microelectromechanical oscillator (OCMO). The OCMO takes advantage of high thermal isolation and monolithic integration of both aluminum nitride (AlN) micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. Operation at microscale sizes allows implementation of high thermal resistance platform supports that enable thermal stabilization at very low-power levels when compared with the state-of-the-art oven controlled crystal oscillators. A prototype OCMO has been demonstrated with a measured temperature stability of -1.2 ppb/C, over the commercial temperature range while using tens of milliwatts of supply power and with a volume of 2.3 mm3 (not including the printed circuit board-based thermal control loop). Additionally, due to its small thermal time constant, the thermal compensation loop can maintain stability during fast thermal transients (>10 C/min). This new technology has resulted in a new paradigm in terms of power, size, and warm up time for high thermal stability oscillators.

  18. A fully integrated oven controlled microelectromechanical oscillator -- Part I. Design and fabrication

    SciTech Connect (OSTI)

    Wojciechowski, Kenneth E.; Baker, Michael S.; Clews, Peggy J.; Olsson, Roy H.

    2015-06-24

    Our paper reports the design and fabrication of a fully integrated oven controlled microelectromechanical oscillator (OCMO). This paper begins by describing the limits on oscillator frequency stability imposed by the thermal drift and electronic properties (Q, resistance) of both the resonant tank circuit and feedback electronics required to form an electronic oscillator. An OCMO is presented that takes advantage of high thermal isolation and monolithic integration of both micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. This was achieved by developing a processing technique where both silicon-on-insulator complementary metal-oxide-semiconductor (CMOS) circuitry and piezoelectric aluminum nitride, AlN, micromechanical resonators are placed on a suspended platform within a standard CMOS integrated circuit. Operation at microscale sizes achieves high thermal resistances (~10 C/mW), and hence thermal stabilization of the oscillators at very low-power levels when compared with the state-of-the-art ovenized crystal oscillators, OCXO. This constant resistance feedback circuit is presented that incorporates on platform resistive heaters and temperature sensors to both measure and stabilize the platform temperature. Moreover, the limits on temperature stability of the OCMO platform and oscillator frequency imposed by the gain of the constant resistance feedback loop, placement of the heater and temperature sensing resistors, as well as platform radiative and convective heat losses are investigated.

  19. A Fully Integrated Oven Controlled Microelectromechanical OscillatorPart II. Characterization and Measurement

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wojciechowski, Kenneth E.; Olsson, Roy H.

    2015-06-24

    Our paper reports the measurement and characterization of a fully integrated oven controlled microelectromechanical oscillator (OCMO). The OCMO takes advantage of high thermal isolation and monolithic integration of both aluminum nitride (AlN) micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. Operation at microscale sizes allows implementation of high thermal resistance platform supports that enable thermal stabilization at very low-power levels when compared with the state-of-the-art oven controlled crystal oscillators. A prototype OCMO has been demonstrated with a measured temperature stability of -1.2 ppb/C, over the commercial temperature range while using tensmoreof milliwatts of supply power and with a volume of 2.3 mm3 (not including the printed circuit board-based thermal control loop). Additionally, due to its small thermal time constant, the thermal compensation loop can maintain stability during fast thermal transients (>10 C/min). This new technology has resulted in a new paradigm in terms of power, size, and warm up time for high thermal stability oscillators.less

  20. A fully integrated oven controlled microelectromechanical oscillator – Part II. Characterization and measurement

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wojciechowski, Kenneth E.; Olsson, Roy H.

    2015-06-24

    Our paper reports the measurement and characterization of a fully integrated oven controlled microelectromechanical oscillator (OCMO). The OCMO takes advantage of high thermal isolation and monolithic integration of both aluminum nitride (AlN) micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. Operation at microscale sizes allows implementation of high thermal resistance platform supports that enable thermal stabilization at very low-power levels when compared with the state-of-the-art oven controlled crystal oscillators. A prototype OCMO has been demonstrated with a measured temperature stability of -1.2 ppb/°C, over the commercial temperature range while using tensmore » of milliwatts of supply power and with a volume of 2.3 mm3 (not including the printed circuit board-based thermal control loop). Additionally, due to its small thermal time constant, the thermal compensation loop can maintain stability during fast thermal transients (>10 °C/min). This new technology has resulted in a new paradigm in terms of power, size, and warm up time for high thermal stability oscillators.« less

  1. A fully integrated oven controlled microelectromechanical oscillatorPart I. Design and fabrication

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wojciechowski, Kenneth E.; Baker, Michael S.; Clews, Peggy J.; Olsson, Roy H.

    2015-06-24

    Our paper reports the design and fabrication of a fully integrated oven controlled microelectromechanical oscillator (OCMO). This paper begins by describing the limits on oscillator frequency stability imposed by the thermal drift and electronic properties (Q, resistance) of both the resonant tank circuit and feedback electronics required to form an electronic oscillator. An OCMO is presented that takes advantage of high thermal isolation and monolithic integration of both micromechanical resonators and electronic circuitry to thermally stabilize or ovenize all the components that comprise an oscillator. This was achieved by developing a processing technique where both silicon-on-insulator complementary metal-oxide-semiconductor (CMOS) circuitrymoreand piezoelectric aluminum nitride, AlN, micromechanical resonators are placed on a suspended platform within a standard CMOS integrated circuit. Operation at microscale sizes achieves high thermal resistances (~10 C/mW), and hence thermal stabilization of the oscillators at very low-power levels when compared with the state-of-the-art ovenized crystal oscillators, OCXO. This constant resistance feedback circuit is presented that incorporates on platform resistive heaters and temperature sensors to both measure and stabilize the platform temperature. Moreover, the limits on temperature stability of the OCMO platform and oscillator frequency imposed by the gain of the constant resistance feedback loop, placement of the heater and temperature sensing resistors, as well as platform radiative and convective heat losses are investigated.less

  2. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M.; Eichinger, F.; Rafi, M.

    1995-12-01

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  3. Summary of beryllium electrorefining technology developed by KBI Division of Cabot Berylco Inc

    SciTech Connect (OSTI)

    Pistole, C.O.

    1983-05-27

    Proprietary beryllium electrorefining technology has been purchased from the KBI Division of Cabot Berylco Inc. by Rockwell International, Rocky Flats Plant, as part of a DOE beryllium option study. This technology has been reviewed and is summarized. 12 figures, 7 tables.

  4. Beryllium-Associated Worker Registry Data Collection and Management Guidance

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    87-2007 June 2007 DOE TECHNICAL STANDARD Beryllium-Associated Worker Registry Data Collection and Management Guidance U.S. Department of Energy AREA SAFT Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited NOT MEASUREMENT SENSITIVE DOE-STD-1187-2007 ii Available on the Department of Energy Technical Standards Program Web site at http://www.hss.energy.gov/NuclearSafety/techstds/ DOE-STD-1187-2007 iii FOREWORD 1. This standard provides acceptable

  5. SOURCE AND PATHWAY DETERMINATION FOR BERYLLIUM FOUND IN BECHTEL NEVADA NORTH LAS VEGAS FACILITIES

    SciTech Connect (OSTI)

    BECHTEL NEVADA

    2004-07-01

    In response to the report ''Investigation of Beryllium Exposure Cases Discovered at the North Las Vegas Facility of the National Nuclear Security Administration'', published by the U.S. Department of Energy (DOE), National Nuclear Security Administration (NNSA) in August 2003, Bechtel Nevada (BN) President and General Manager Dr. F. A. Tarantino appointed the Beryllium Investigation & Assessment Team (BIAT) to identify both the source and pathway for the beryllium found in the North Las Vegas (NLV) B-Complex. From September 8 to December 18, 2003, the BIAT investigated the pathway for beryllium and determined that a number of locations existed at the Nevada Test Site (NTS) which could have contained sufficient quantities of beryllium to result in contamination if transported. Operations performed in the B-1 Building as a result of characterization activities at the Engine Maintenance, Assembly, and Disassembly (EMAD); Reactor Maintenance, Assembly, and Disassembly (RMAD); Test Cells A and C; and the Central Support Facility in Area 25 had the greatest opportunity for transport of beryllium. Investigative monitoring and sampling was performed at these sites with subsequent transport of sample materials, equipment, and personnel from the NTS to the B-1 Building. The timeline established by the BIAT for potential transport of the beryllium contamination into the B-1 Building was from September 1997 through November 2002. Based on results of recently completed swipe sampling, no evidence of transport of beryllium from test areas has been confirmed. Results less than the DOE beryllium action level of 0.2 ???g/100 cm2 were noted for work support facilities located in Area 25. All of the identified sites in Area 25 worked within the B-1 tenant's residency timeline have been remediated. Legacy contaminants have either been disposed of or capped with clean borrow material. As such, no current opportunity exists for release or spread of beryllium contamination. Historical records indicate that there are locations at the NTS which contain hazardous quantities of beryllium; however, because beryllium was not always considered a contaminant of concern, complete characterization was not performed prior to remediation efforts. Today, it is not practical to characterize Area 25 for beryllium due to the successful remediation. Analysis of sample data collected in B-1 for the BIAT was performed for the purpose of confirming past results and identifying a source of beryllium through the use of markers. The results confirmed the presence of man-made beryllium contamination in the B-1 High Bay at levels consistent with the NNSA Report. No source markers were found that would be associated with NTS historical nuclear rocket or weapons-related operations. Beryllium contamination was identified in the southwest area of the B-1 High Bay in characteristic association with materials handled during historic metal-working operations. Use of source marker analysis suggests a contributor of beryllium found in carpeted areas of the B-Complex may be naturally occurring. Naturally occurring beryllium is not regulated by Title 10 Code of Federal Regulations Part 850 (10 CFR 850) (see Appendix A). No current uncontrolled beryllium source or transport pathways have been identified as available for spread of contamination to uncontrolled areas from the NTS.

  6. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  7. Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis

    SciTech Connect (OSTI)

    Graham, J.D.; Beaulieu, N.D.; Sussman, D.; Sadowitz, M.; Li, Y.C. )

    1999-04-01

    Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmental inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.

  8. SIMULTANEOUS VISAR AND TXD MEASUREMENTS ON SHOCKS IN BERYLLIUM CRYSTALS

    SciTech Connect (OSTI)

    Swift, D. C.; Paisley, Dennis L.; Kyrala, George A.; Hauer, Allan

    2001-01-01

    Shock waves were induced in single crystals of beryllium, by direct illumination using the TRIDENT laser at Los Alamos. The velocity history at the surface was measured using a line-imaging VISAR, and transient X-ray diffraction (TXD) records were obtained with a plasma backlighter and X-ray streak camera. At lower pressures, the VISAR records exhibited an elastic precursor followed by a plastic wave and spall. At higher pressure, the velocity records showed a two-wave structure suggesting a phase change, then at the highest pressure a single broad wave suggesting a shock directly into the high pressure phase. The rocking curves of the crystals were typically about 2 degrees wide, so analysis of the TXD records is complicated by the relatively large amount of blurring. However the Bragg record of the shocked 0002 peak clearly indicates a smaller lattice parameter at higher pressure. In the shots where polymorphism seemed to appear in the VISAR record, additional lines appeared in the bragg record, and new lines also appeared within the field of view of the Laue camera. These results are consistent with a new quantum mechanical equation of state for beryllium, which suggests that the hexagonal to body-centered cubic transition occurs at {approx}40 GPa on the principal Hugoniot.

  9. Demonstration of a fuel-saving system for paint-curing ovens

    SciTech Connect (OSTI)

    Jensen, W P

    1980-12-01

    Two curing ovens at Roll Coater, Inc. (the Greenfield, Indiana plant) were retrofitted to save fuel and cost. Included in the fuel conserving retrofit was the design, fabrication, and installation of an afterburner for each of the two ovens, piping their combustion products to each of two commonly housed waste heat boilers before discharge from those units to the atmosphere at about 450 F. Depending on the product being run and the coating applied, natural gas requirements have been reduced by 45 to 65% with operation of the zone incinerators only and by as much as 65 to 85% including the effects of both the zone incineration and heat recovery by means of the afterburners and waste heat boilers. A demonstration program on conversion work at the No. 3 line at Greenfield and results are described in Section 2. Section 3 describes the retrofit design and the system construction. System performance (tests and measurements, qualitative performance, maintenance factors, and economic performance) is described in Section 4. Conclusions and recommendations are summarized.

  10. Torrefaction reduction of coke formation on catalysts used in esterification and cracking of biofuels from pyrolysed lignocellulosic feedstocks

    DOE Patents [OSTI]

    Kastner, James R; Mani, Sudhagar; Hilten, Roger; Das, Keshav C

    2015-11-04

    A bio-oil production process involving torrefaction pretreatment, catalytic esterification, pyrolysis, and secondary catalytic processing significantly reduces yields of reactor char, catalyst coke, and catalyst tar relative to the best-case conditions using non-torrefied feedstock. The reduction in coke as a result of torrefaction was 28.5% relative to the respective control for slow pyrolysis bio-oil upgrading. In fast pyrolysis bio-oil processing, the greatest reduction in coke was 34.9%. Torrefaction at 275.degree. C. reduced levels of acid products including acetic acid and formic acid in the bio-oil, which reduced catalyst coking and increased catalyst effectiveness and aromatic hydrocarbon yields in the upgraded oils. The process of bio-oil generation further comprises a catalytic esterification of acids and aldehydes to generate such as ethyl levulinate from lignified biomass feedstock.

  11. Retrospective beryllium exposure assessment at the Rocky Flats Environmental Technology site

    SciTech Connect (OSTI)

    Barnard, A.E.; Torma-Krajewski, J.; Viet, S.M.

    1997-05-01

    Since the 1960`s, beryllium machining was performed to make nuclear weapon components at the Department of Energy (DOE) Rocky Flats Plant. Beryllium exposure was assessed via fixed airhead (FAH) sampling in which the filter cassette was affixed to the machine, generally within a few feet of the worker`s breathing zone. Approximately 500,000 FAH samples were collected for beryllium over three decades. From 1984 to 1987, personal breathing zone (PBZ) samples were also collected as part of the evaluation of a new high velocity/low volume local exhaust ventilation (HV/LV LEV) system. The purpose of this study was to determine how the two types of sampling data could be used for an exposure assessment in the beryllium shop.

  12. Independent Oversight Inspection of the Hanford Site Chronic Beryllium Disease Prevention Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Independent Oversight Inspection of the Hanford Site Chronic Beryllium Disease Prevention Program June 2010 Office of Independent Oversight Office of Health, Safety and Security Office of Health, Safety and Security HSS x Hanford Site Chronic Beryllium Disease Prevention Program | i Abbreviations iii Executive Summary v 1 Introduction 1 2 Management and Oversight 3 3 Findings Requiring Corrective Action 14 4 Conclusions and Cross-Cutting Opportunities for Improvement 17 Appendix A - Supplemental

  13. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect (OSTI)

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights

    2009-05-15

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  14. Characterization of beryllium deformation using in-situ x-ray diffraction

    SciTech Connect (OSTI)

    Magnuson, Eric Alan; Brown, Donald William; Clausen, Bjorn; Sisneros, Thomas A.; Park, Jun-Sang

    2015-08-24

    Beryllium’s unique mechanical properties are extremely important in a number of high performance applications. Consequently, accurate models for the mechanical behavior of beryllium are required. However, current models are not sufficiently microstructure aware to accurately predict the performance of beryllium under a range of processing and loading conditions. Previous experiments conducted using the SMARTS and HIPPO instruments at the Lujan Center(LANL), have studied the relationship between strain rate and texture development, but due to the limitations of neutron diffraction studies, it was not possible to measure the response of the material in real-time. In-situ diffraction experiments conducted at the Advanced Photon Source have allowed the real time measurement of the mechanical response of compressed beryllium. Samples of pre-strained beryllium were reloaded orthogonal to their original load path to show the reorientation of already twinned grains. Additionally, the in-situ experiments allowed the real time tracking of twin evolution in beryllium strained at high rates. The data gathered during these experiments will be used in the development and validation of a new, microstructure aware model of the constitutive behavior of beryllium.

  15. The Status of Beryllium Research for Fusion in the United States

    SciTech Connect (OSTI)

    Glen R. Longhurst

    2003-12-01

    Use of beryllium in fusion reactors has been considered for neutron multiplication in breeding blankets and as an oxygen getter for plasma-facing surfaces. Previous beryllium research for fusion in the United States included issues of interest to fission (swelling and changes in mechanical and thermal properties) as well as interactions with plasmas and hydrogen isotopes and methods of fabrication. When the United States formally withdrew its participation in the International Thermonuclear Experimental Reactor (ITER) program, much of this effort was terminated. The focus in the U.S. has been mainly on toxic effects of beryllium and on industrial hygiene and health-related issues. Work continued at the INEEL and elsewhere on beryllium-containing molten salts. This activity is part of the JUPITER II Agreement. Plasma spray of ITER first wall samples at Los Alamos National Laboratory has been performed under the European Fusion Development Agreement. Effects of irradiation on beryllium structure are being studied at Oak Ridge National Laboratory. Numerical and phenomenological models are being developed and applied to better understand important processes and to assist with design. Presently, studies are underway at the University of California Los Angeles to investigate thermo-mechanical characteristics of beryllium pebble beds, similar to research being carried out at Forschungszentrum Karlsruhe and elsewhere. Additional work, not funded by the fusion program, has dealt with issues of disposal, and recycling.

  16. Incorporation of deuterium in coke formed on an acetylene hydrogenation catalyst

    SciTech Connect (OSTI)

    Larsson, M.; Jansson, J.; Asplund, S.

    1996-09-01

    In selective hydrogenation of acetylene in excess ethylene, considerable amounts of coke or {open_quotes}green oils{close_quotes} are formed and accumulate on the catalyst. A fraction of the acetylene undergoes oligomerization reactions producing C{sub 4}`s and larger hydrocarbons. Compounds larger than C{sub 8} are retained on the catalysts surface or as a condensed phase in the pore system. The reaction mechanism is largely unknown but several authors have postulated that oligomerization occurs through dissociatively adsorbed acetylene (2), i.e., C{sub 2}H(ads) and C{sub 2}(ads). In this paper a novel method of studying the coke formation on a catalyst is introduced. Deuterium is incorporated in the coke during hydrogenation of acetylene, and during temperature-programmed oxidation (TPO) experiments the deuterium content is analyzed. The objective is to shed some light on the mechanism for oligomer formation in this system. The catalyst, Pd/{alpha}-Al{sub 2}O{sub 3}, was prepared by the impregnation of {alpha}-alumina (Sued-Chemie) with a solution of Pd(NO{sub 3}){sub 2} in 30% HNO{sub 3}. 8 refs., 4 figs.

  17. General Counsel Legal Interpretation Regarding Medical Removal Protection Benefits Pursuant to 10 CFR Part 850, Chronic Beryllium Disease Prevention Program

    Broader source: Energy.gov [DOE]

    The following document is the Office of the General Counsel (GC) interpretation regarding Medical Removal Protection Benefits Pursuant to 10 CFR Part 850, Chronic Beryllium Disease Prevention Program.

  18. Relational contracting and the law and economics of vertical integration: a study of the economics of petroleum coking, processing, and consumption

    SciTech Connect (OSTI)

    Erickson, J.R.

    1981-01-01

    The basis for this study was an antitrust suit brought by the Federal Trade Commission against the Great Lakes Carbon Corp., a processor and reseller of green petroleum coke, and eight petroleum refiners. The respondents in this case were accused of using long-term contracts to foreclose the markets for both green and processed petroleum coke. Chapter 1 develops a theory of exchange and the contracts governing exchange. Chapter 2 describes the petroleum-coke industry and the nature of green coke exchange. It explains the reasons for the highly concentrated structure of the green-coke market in terms of the technology of petroleum-coke production and consumption and the physical and byproduct nature of petroleum coke. Chapter 3 takes a large number of green-coke contracts and breaks them down into their various relevant provisions. These provisions are then grouped according to their purpose and the characteristics of the firms employing them and shows that differences between the contracts can be explained by differences in the risks to firms of engaging in green coke exchange. Chapter 4 discusses the implications of vertical restrictions from the point of view of relational contracting using the data adduced in Chapter 3.

  19. Design of the beryllium window for Brookhaven Linac Isotope Producer

    SciTech Connect (OSTI)

    Nayak, S.; Mapes, M.; Raparia, D.

    2015-11-01

    In the Brookhaven Linac Isotope Producer (BLIP) beam line, there were two Beryllium (Be) windows with an air gap to separate the high vacuum upstream side from low vacuum downstream side. There had been frequent window failures in the past which affected the machine productivity and increased the radiation dose received by worker due to unplanned maintenance. To improve the window life, design of Be window is reexamined. Detailed structural and thermal simulations are carried out on Be window for different design parameters and loading conditions to come up with better design to improve the window life. The new design removed the air gap and connect the both beam lines with a Be window in-between. The new design has multiple advantages such as 1) reduces the beam energy loss (because of one window with no air gap), 2) reduces air activation due to nuclear radiation and 3) increased the machine reliability as there is no direct pressure load during operation. For quick replacement of this window, an aluminum bellow coupled with load binder was designed. There hasnt been a single window failure since the new design was implemented in 2012.

  20. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J.

    1995-12-01

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  1. Memorandum, Clarification of Title 10 of the Code of Federal Regulations, Part 850 (10 CPR 850), Chronic Beryllium Disease Prevention Program, Paragraph 850.34(g)

    Broader source: Energy.gov [DOE]

    The purpose of this memorandum is to clarification regarding the reporting of beryllium sensitization (BeS) and chronic beryllium disease (CBD) as required by paragraph 850.34(g) of the Chronic Beryllium Disease Prevention Program rule (10 CFR 850).

  2. Examination of Beryllium Under Intense High Energy Proton Beam at CERN's

    Office of Scientific and Technical Information (OSTI)

    HiRadMat Facility (Conference) | SciTech Connect Examination of Beryllium Under Intense High Energy Proton Beam at CERN's HiRadMat Facility Citation Details In-Document Search Title: Examination of Beryllium Under Intense High Energy Proton Beam at CERN's HiRadMat Facility Authors: Ammigan, K. ; et al. Publication Date: 2015-05-01 OSTI Identifier: 1230046 Report Number(s): IPAC-2015-WEPTY015 DOE Contract Number: AC02-07CH11359 Resource Type: Conference Resource Relation: Conference: 6th

  3. Microsoft Word - 2010O-01_DOE Response to Beryllium.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Response to DOE's Response to Beryllium Advice 2010O-01 February 5, 2010 Page 1 February 5, 2010 David Brockman, Manager U.S. Department of Energy, Richland Operations Office P.O. Box 550 (A7-75) Richland, WA 99352 Shirley Olinger, Manager U.S. Department of Energy, Office of River Protection P.O. Box 450 (H6-60) Richland, WA 99352 Re: DOE's Response to HAB Beryllium Advice #217 and #218 Dear Mr. Brockman and Ms. Olinger, On April 3, 2009 the Hanford Advisory Board (Board) provided two pieces of

  4. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang

    2008-03-15

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  5. Petroleum Coke

    Gasoline and Diesel Fuel Update (EIA)

    82,516 82,971 84,053 85,190 84,889 85,527 1986-2014 East Coast (PADD 1) 10,887 9,316 9,766 9,003 7,430 8,048 1986-2014 Midwest (PADD 2) 15,507 16,480 16,834 17,611 17,597 16,837 1986-2014 Gulf Coast (PADD 3) 41,042 43,341 42,186 42,614 43,692 44,599 1986-2014 Rocky Mountain (PADD 4) 3,332 3,342 3,474 3,380 3,476 3,418 1986-2014 West Coast (PADD 5) 11,748 10,492 11,793 12,582 12,694 12,625

  6. Evaluation of HEU-Beryllium Benchmark Experiments to Improve Computational Analysis of Space Reactors

    SciTech Connect (OSTI)

    John D. Bess; Keith C. Bledsoe; Bradley T. Rearden

    2011-02-01

    An assessment was previously performed to evaluate modeling capabilities and quantify preliminary biases and uncertainties associated with the modeling methods and data utilized in designing a nuclear reactor such as a beryllium-reflected, highly-enriched-uranium (HEU)-O2 fission surface power (FSP) system for space nuclear power. The conclusion of the previous study was that current capabilities could preclude the necessity of a cold critical test of the FSP; however, additional testing would reduce uncertainties in the beryllium and uranium cross-section data and the overall uncertainty in the computational models. A series of critical experiments using HEU metal were performed in the 1960s and 1970s in support of criticality safety operations at the Y-12 Plant. Of the hundreds of experiments, three were identified as fast-fission configurations reflected by beryllium metal. These experiments have been evaluated as benchmarks for inclusion in the International Handbook of Evaluated Criticality Safety Benchmark Experiments (IHECSBE). Further evaluation of the benchmark experiments was performed using the sensitivity and uncertainty analysis capabilities of SCALE 6. The data adjustment methods of SCALE 6 have been employed in the validation of an example FSP design model to reduce the uncertainty due to the beryllium cross section data.

  7. Progress on a Cavity with Beryllium Walls for Muon Ionization Cooling Channel R&D.

    SciTech Connect (OSTI)

    Bowring, D.L.; DeMello, A.J.; Lambert, A.R.; Li, D.; Virostek,, S.; Zisman, M.; Kaplan, D.; Palmer, R.B.

    2012-05-20

    The Muon Accelerator Program (MAP) collaboration is working to develop an ionization cooling channel for muon beams. An ionization cooling channel requires the operation of high-gradient, normal-conducting RF cavities in multi-Tesla solenoidal magnetic fields. However, experiments conducted at Fermilab?s MuCool Test Area (MTA) show that increasing the solenoidal field strength reduces the maximum achievable cavity gradient. This gradient limit is characterized by an RF breakdown process that has caused significant damage to copper cavity interiors. The damage may be caused by field-emitted electrons, focused by the solenoidal magnetic field onto small areas of the inner cavity surface. Local heating may then induce material fatigue and surface damage. Fabricating a cavity with beryllium walls would mitigate this damage due to beryllium?s low density, low thermal expansion, and high electrical and thermal conductivity. We address the design and fabrication of a pillbox RF cavity with beryllium walls, in order to evaluate the performance of high-gradient cavities in strong magnetic fields.

  8. Implementation Guide for use with 10 CFR Part 850, Chronic Beryllium Disease Prevention Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2001-01-04

    The Department of Energy (DOE) has established regulatory requirements for the Chronic Beryllium Disease Prevention Program (CBDPP) in Title 10 of the Code of Federal Regulations (CFR), Part 850 (10 CFR 850) [64 Federal Register (FR) 68854]. Supersedes DOE G 440.1-7. Certified 9-23-10.

  9. Validation of FSP Reactor Design with Sensitivity Studies of Beryllium-Reflected Critical Assemblies

    SciTech Connect (OSTI)

    John D. Bess; Margaret A. Marshall

    2013-02-01

    The baseline design for space nuclear power is a fission surface power (FSP) system: sodium-potassium (NaK) cooled, fast spectrum reactor with highly-enriched-uranium (HEU)-O2 fuel, stainless steel (SS) cladding, and beryllium reflectors with B4C control drums. Previous studies were performed to evaluate modeling capabilities and quantify uncertainties and biases associated with analysis methods and nuclear data. Comparison of Zero Power Plutonium Reactor (ZPPR)-20 benchmark experiments with the FSP design indicated that further reduction of the total design model uncertainty requires the reduction in uncertainties pertaining to beryllium and uranium cross-section data. Further comparison with three beryllium-reflected HEU-metal benchmark experiments performed at the Oak Ridge Critical Experiments Facility (ORCEF) concluded the requirement that experimental validation data have similar cross section sensitivities to those found in the FSP design. A series of critical experiments was performed at ORCEF in the 1960s to support the Medium Power Reactor Experiment (MPRE) space reactor design. The small, compact critical assembly (SCCA) experiments were graphite- or beryllium-reflected assemblies of SS-clad, HEU-O2 fuel on a vertical lift machine. All five configurations were evaluated as benchmarks. Two of the five configurations were beryllium reflected, and further evaluated using the sensitivity and uncertainty analysis capabilities of SCALE 6.1. Validation of the example FSP design model was successful in reducing the primary uncertainty constituent, the Be(n,n) reaction, from 0.28 %dk/k to 0.0004 %dk/k. Further assessment of additional reactor physics measurements performed on the SCCA experiments may serve to further validate FSP design and operation.

  10. Multiscale modeling of beryllium: quantum mechanics and laser-driven shock experiments using novel diagnostics.

    SciTech Connect (OSTI)

    Swift, D. C.; Paisley, Dennis L.; Kyrala, George A.; Hauer, Allan

    2002-01-01

    Ab initio quantum mechanics was used to construct a thermodynamically complete and rigorous equation of state for beryllium in the hexagonal and body-centred cubic structures, and to predict elastic constants as a function of compression. The equation of state agreed well with Hugoniot data and previously-published equations of state, but the temperatures were significantly different. The hexagonal/bcc phase boundary agreed reasonably well with published data, suggesting that the temperatures in our new equation of state were accurate. Shock waves were induced in single crystals and polycrystalline foils of beryllium, by direct illumination using the TRIDENT laser at Los Alamos. The velocity history at the surface of the sample was measured using a line-imaging VISAR, and transient X-ray diffraction (TXD) records were obtained with a plasma backlighter and X-ray streak cameras. The VISAR records exhibited elastic precursors, plastic waves, phase changes and spall. Dual TXD records were taken, in Bragg and Laue orientations. The Bragg lines moved in response to compression in the uniaxial direction. Because direct laser drive was used, the results had to be interpreted with the aid of radiation hydrodynamics simulations to predict the loading history for each laser pulse. In the experiments where there was evidence of polymorphism in the VISAR record, additional lines appeared in the Bragg and Laue records. The corresponding pressures were consistent with the phase boundary predicted by the quantum mechanical equation of state for beryllium. A model of the response of a single crystal of beryllium to shock loading is being developed using these new theoretical and experimental results. This model will be used in meso-scale studies of the response of the microstructure, allowing us to develop a more accurate representation of the behaviour of polycrystalline beryllium.

  11. Irradiated Beryllium Disposal Workshop, Idaho Falls, ID, May 29-30, 2002

    SciTech Connect (OSTI)

    Longhurst, Glen Reed; Anderson, Gail; Mullen, Carlan K; West, William Howard

    2002-07-01

    In 2001, while performing routine radioactive decay heat rate calculations for beryllium reflector blocks for the Advanced Test Reactor (ATR), it became evident that there may be sufficient concentrations of transuranic isotopes to require classification of this irradiated beryllium as transuranic waste. Measurements on samples from ATR reflector blocks and further calculations confirmed that for reflector blocks and outer shim control cylinders now in the ATR canal, transuranic activities are about five times the threshold for classification. That situation implies that there is no apparent disposal pathway for this material. The problem is not unique to the ATR. The High Flux Isotope Reactor at Oak Ridge National Laboratory, the Missouri University Research Reactor at Columbia, Missouri and other reactors abroad must also deal with this issue. A workshop was held in Idaho Falls Idaho on May 29-30, 2002 to acquaint stakeholders with these findings and consider a path forward in resolving the issues attendant to disposition of irradiated material. Among the findings from this workshop were (1) there is a real potential for the US to be dependent on foreign sources for metallic beryllium within about a decade; (2) there is a need for a national policy on beryllium utilization and disposition and for a beryllium coordinating committee to be assembled to provide guidance on that policy; (3) it appears it will be difficult to dispose of this material at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico due to issues of Defense classification, facility radioactivity inventory limits, and transportation to WIPP; (4) there is a need for a funded DOE program to seek resolution of these issues including research on processing techniques that may make this waste acceptable in an existing disposal pathway or allow for its recycle.

  12. Table 7.8 Coke Overview, 1949-2011 (Thousand Short Tons)

    U.S. Energy Information Administration (EIA) Indexed Site

    Coke Overview, 1949-2011 (Thousand Short Tons) Year Production Trade Stock Change 2 Consumption 3 Imports Exports Net Imports 1 1949 63,637 279 548 -269 176 63,192 1950 72,718 438 398 40 -659 73,417 1951 79,331 162 1,027 -865 372 78,094 1952 68,254 313 792 -479 419 67,356 1953 78,837 157 520 -363 778 77,696 1954 59,662 116 388 -272 269 59,121 1955 75,302 126 531 -405 -1,248 76,145 1956 74,483 131 656 -525 634 73,324 1957 75,951 118 822 -704 814 74,433 1958 53,604 122 393 -271 675 52,658 1959

  13. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an opportunity fuel for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an opportunity fuel for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administrations National Goal to Reduce Emissions Intensity. 8

  14. Roughening and removal of surface contamination from beryllium using negative transferred-arc cleaning

    SciTech Connect (OSTI)

    Castro, R.G.; Hollis, K.J.; Elliott, K.E.

    1997-12-01

    Negative transferred-arc (TA) cleaning has been used extensively in the aerospace industry to clean and prepare surfaces prior to plasma spraying of thermal barrier coatings. This non-line of sight process can improve the bond strength of plasma sprayed coatings to the substrate material by cleaning and macroscopically roughening the surface. A variation of this cleaning methodology is also used in gas tungsten arc (GTA) welding to cathodically clean the surfaces of aluminum and magnesium prior to welding. Investigations are currently being performed to quantify the degree in which the negative transferred-arc process can clean and roughen metal surfaces. Preliminary information will be reported on the influence of processing conditions on roughening and the removal of carbon and other contaminates from the surface of beryllium. Optical, spectral and electrical methods to quantify cleaning of the surface will also be discussed. Applications for this technology include chemical-free precision cleaning of beryllium components.

  15. Low Prevalence of Chronic Beryllium Disease among Workers at a Nuclear Weapons Research and Development Facility

    SciTech Connect (OSTI)

    Arjomandi, M; Seward, J P; Gotway, M B; Nishimura, S; Fulton, G P; Thundiyil, J; King, T E; Harber, P; Balmes, J R

    2010-01-11

    To study the prevalence of beryllium sensitization (BeS) and chronic beryllium disease (CBD) in a cohort of workers from a nuclear weapons research and development facility. We evaluated 50 workers with BeS with medical and occupational histories, physical examination, chest imaging with HRCT (N=49), and pulmonary function testing. Forty of these workers also underwent bronchoscopy for bronchoalveolar lavage (BAL) and transbronchial biopsies. The mean duration of employment at the facility was 18 yrs and the mean latency (from first possible exposure) to time of evaluation was 32 yrs. Five of the workers had CBD at the time of evaluation (based on histology or HRCT); three others had evidence of probable CBD. These workers with BeS, characterized by a long duration of potential Be exposure and a long latency, had a low prevalence of CBD.

  16. Sampling for Beryllium Surface Contamination using Wet, Dry and Alcohol Wipe Sampling

    SciTech Connect (OSTI)

    Kerr, Kent

    2004-12-17

    This research project was conducted at the National Nuclear Security Administration's Kansas City Plant, operated by Honeywell Federal Manufacturing and Technologies, in conjunction with the Safety Sciences Department of Central Missouri State University, to compare relative removal efficiencies of three wipe sampling techniques currently used at Department of Energy facilities. Efficiencies of removal of beryllium contamination from typical painted surfaces were tested by wipe sampling with dry Whatman 42 filter paper, with water-moistened (Ghost Wipe) materials, and by methanol-moistened wipes. Test plates were prepared using 100 mm X 15 mm Pyrex Petri dishes with interior surfaces spray painted with a bond coat primer. To achieve uniform deposition over the test plate surface, 10 ml aliquots of solution containing 1 beryllium and 0.1 ml of metal working fluid were transferred to the test plates and subsequently evaporated. Metal working fluid was added to simulate the slight oiliness common on surfaces in metal working shops where fugitive oil mist accumulates over time. Sixteen test plates for each wipe method (dry, water, and methanol) were processed and sampled using a modification of wiping patterns recommended by OSHA Method 125G. Laboratory and statistical analysis showed that methanol-moistened wipe sampling removed significantly more (about twice as much) beryllium/oil-film surface contamination as water-moistened wipes (p< 0.001), which removed significantly more (about twice as much) residue as dry wipes (p <0.001). Evidence for beryllium sensitization via skin exposure argues in favor of wipe sampling with wetting agents that provide enhanced residue removal efficiency.

  17. Nuclear Transmutations in HFIR's Beryllium Reflector and Their Impact on Reactor Operation and Reflector Disposal

    SciTech Connect (OSTI)

    Chandler, David [ORNL; Maldonado, G Ivan [ORNL; Primm, Trent [ORNL; Proctor, Larry Duane [ORNL

    2012-01-01

    The High Flux Isotope Reactor located at the Oak Ridge National Laboratory utilizes a large cylindrical beryllium reflector that is subdivided into three concentric regions and encompasses the compact reactor core. Nuclear transmutations caused by neutron activation occur in the beryllium reflector regions, which leads to unwanted neutron absorbing and radiation emitting isotopes. During the past year, two topics related to the HFIR beryllium reflector were reviewed. The first topic included studying the neutron poison (helium-3 and lithium-6) buildup in the reflector regions and its affect on beginning-of-cycle reactivity. A new methodology was developed to predict the reactivity impact and estimated symmetrical critical control element positions as a function of outage time between cycles due to helium-3 buildup and was shown to be in better agreement with actual symmetrical critical control element position data than the current methodology. The second topic included studying the composition of the beryllium reflector regions at discharge as well as during decay to assess the viability of transporting, storing, and ultimately disposing the reflector regions currently stored in the spent fuel pool. The post-irradiation curie inventories were used to determine whether the reflector regions are discharged as transuranic waste or become transuranic waste during the decay period for disposal purposes and to determine the nuclear hazard category, which may affect the controls invoked for transportation and temporary storage. Two of the reflector regions were determined to be transuranic waste at discharge and the other region was determined to become transuranic waste in less than 2 years after being discharged due to the initial uranium content (0.0044 weight percent uranium). It was also concluded that all three of the reflector regions could be classified as nuclear hazard category 3 (potential for localized consequences only).

  18. Beryllium-7 Implantation in Plastics for Prosthesis Wear Studies | U.S. DOE

    Office of Science (SC) Website

    Office of Science (SC) Beryllium-7 Implantation in Plastics for Prosthesis Wear Studies Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Applications of Nuclear Science Applications of Nuclear Science Archives Small Business Innovation / Technology Transfer Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW

  19. DOE - Office of Legacy Management -- Brush Beryllium Co - Clevland - OH 02

    Office of Legacy Management (LM)

    Clevland - OH 02 FUSRAP Considered Sites Site: Brush Beryllium Co. (OH.02) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 4201 Perkins Avenue and 3714 Chester Street (two locations) , Cleveland , Ohio OH.02-1 Evaluation Year: 1985 OH.02-2 Site Operations: Performed thorium rod extrusion activities in the 1950s. OH.02-3 Site Disposition: Eliminated - Radiation levels below criteria OH.02-1 OH.02-2 Radioactive Materials Handled:

  20. Use of a Paraffin Based Grout to Stabilize Buried Beryllium and Other Wastes

    SciTech Connect (OSTI)

    Gretchen Matthern; Duane Hanson; Neal Yancey; Darrell Knudson

    2005-12-01

    The long term durability of WAXFIXi, a paraffin based grout, was evaluated for in situ grouting of activated beryllium wastes in the Subsurface Disposal Area (SDA), a radioactive landfill at the Radioactive Waste Management Complex, part of the Idaho National Laboratory (INL). The evaluation considered radiological and biological mechanisms that could degrade the grout using data from an extensive literature search and previous tests of in situ grouting at the INL. Conservative radioactive doses for WAXFIX were calculated from the "hottest" (i.e., highest-activity) Advanced Test Reactor beryllium block in the SDA.. These results indicate that WAXFIX would not experience extensive radiation damage for many hundreds of years. Calculation of radiation induced hydrogen generation in WAXFIX indicated that grout physical performance should not be reduced beyond the effects of radiation dose on the molecular structure. Degradation of a paraffin-based grout by microorganisms in the SDA is possible and perhaps likely, but the rate of degradation will be at a slower rate than found in the literature reviewed. The calculations showed the outer 0.46 m (18 in.) layer of each monolith, which represents the minimum expected distance to the beryllium block, was calculated to require 1,000 to 3,600 years to be consumed. The existing data and estimations of biodegradation and radiolysis rates

  1. Benchmark Evaluation of Uranium Metal Annuli and Cylinders with Beryllium Reflectors

    SciTech Connect (OSTI)

    John D. Bess

    2010-06-01

    An extensive series of delayed critical experiments were performed at the Oak Ridge Critical Experiments Facility using enriched uranium metal during the 1960s and 1970s in support of criticality safety operations at the Y-12 Plant. These experiments were designed to evaluate the storage, casting, and handling limits of the Y-12 Plant and to provide data for the verification of cross sections and calculation methods utilized in nuclear criticality safety applications. Many of these experiments have already been evaluated and included in the International Criticality Safety Benchmark Evaluation Project (ICSBEP) Handbook: unreflected (HEU-MET-FAST-051), graphite-reflected (HEU-MET-FAST-071), and polyethylene-reflected (HEU-MET-FAST-076). Three of the experiments consisted of highly-enriched uranium (HEU, ~93.2% 235U) metal parts reflected by beryllium metal discs. The first evaluated experiment was constructed from a stack of 7-in.-diameter, 4-1/8-in.-high stack of HEU discs top-reflected by a 7-in.-diameter, 5-9/16-in.-high stack of beryllium discs. The other two experiments were formed from stacks of concentric HEU metal annular rings surrounding a 7-in.diameter beryllium core. The nominal outer diameters were 13 and 15 in. with a nominal stack height of 5 and 4 in., respectively. These experiments have been evaluated for inclusion in the ICSBEP Handbook.

  2. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  3. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito

    2008-05-15

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  4. Beryllium Health and Safety Committee Data Reporting Task Force White Paper #2 -- Uses of Uncensored Data

    SciTech Connect (OSTI)

    MacQueen, D H

    2007-10-10

    On December 8, 1999, the Department of Energy (DOE) published Title 10 CFR 850 (hereafter referred to as the Rule) to establish a chronic beryllium disease prevention program (CBDPP) to: (1) reduce the number of workers currently exposed to beryllium in the course of their work at DOE facilities managed by DOE or its contractors; (2) minimize the levels of, and potential for, exposure to beryllium; and (3) establish medical surveillance requirements to ensure early detection of the disease. On January 4, 2001, DOE issued DOE G 440.1-7A, Implementation Guide for use with 10 CFR 850, Chronic Beryllium Disease Prevention Program, to assist line managers in meeting their responsibilities for implementing the CBDPP. That guide describes methods and techniques that DOE considers acceptable in complying with the Rule. In 2005 a draft DOE Technical Standard ''Management of Items and Areas Containing Low Levels of Beryllium'' (SAFT 0103; hereafter referred to as the ''TS'') was circulated for comment (http://www.hss.energy.gov/NuclearSafety/techstds/tsdrafts/saft-0103.pdf). DOE technical standards are voluntary consensus standards developed when industry standards do not exist (see http://www.hss.energy.gov/NuclearSafety/techstds/index.html for more information). DOE does not require its field elements to implement DOE technical standards, but field elements may choose to adopt these standards to meet specific needs. This beryllium TS is intended to provide best practices and lessons learned for manageing items and areas that contain low levels of beryllium, which has been a costly and technically challenging component of CBDPPs. The TS is also intended to provide guidance for determining if the Rule's housekeeping and release criteria are met. On challenge the TS addressed was the statistical interpretation of data sets with non-detected results, a topic for which no strong consensus exists. Among the many comments on the draft TS was a suggestion that certain of the statistical comparisons described in the TS could be better implemented if analytical results, even when below a reporting limit, were to be reported by analytical laboratories. See Appendix 1 for a review of terminology related to reporting limits. The Beryllium Health and Safety Committee (BHSC) formed a Sampling and Analysis Subcommittee (SAS) in 2003. The SAS established a working group on accreditation and reporting limits. By 2006 it had become evident that the issues extended to data reporting as a whole. The SAS proposed to the BHSC the formation of a Data Reporting Task Force (DRTF) to consider issues related to data reporting. The BHSC Board agreed, and requested that the DRTF generate a white paper, to be offered by the BHSC to potential interested parties such as the DOE policy office that is responsible for beryllium health and safety policy. It was noted that additional products could include detailed guidance and potentially a journal article in the future. The SAS proposed that DRTF membership represent the affected disciplines (chemists, industrial hygiene professionals and statisticians, and the DOE office that is responsible for beryllium health and safety policy). The BHSC Board decided that DRTF membership should come from DOE sites, since the focus would be on reporting in the context of the TS and the Rule. The DRTF came into existence in late 2006. The DRTF membership includes industrial hygienists, analytical chemists and laboratory managers, members of the regulatory and oversight community, and environmental statisticians. A first White Paper, ''Summary of Issues and Path Forward'', was reviewed by the BHSC in March 2007 and issued by the DRTF in June 2007. It describes the charter of the DRTF, introduces some basic terminology (reproduced here in Appendix 1), lays out the issues the DRTF is expected to address, and describes a path forward for the DRTF's work. This first White Paper is available through the BHSC web site. This White Paper presents recommendations developed by the DRTF following the process laid out in that first White Pap

  5. Microsoft Word - HABAdv#228_Independent Review of BerylliumProgram.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HAB Consensus Advice # 228 Subject: Independent Review of Beryllium Program Adopted: February 5, 2010 Page 1 February 5, 2010 Inés Triay, Assistant Secretary for Environmental Management EM-1/Forestal Building U.S. Department of Energy 1000 Independence Avenue Washington, D.C. 20585 Steven Krahn, Deputy Assistance Secretary U.S. Department of Energy, Office of Health, Safety and Security HS-10 / GTN 1000 Independence Avenue, SW Washington, D.C. 20585 David Brockman, Manager U.S. Department of

  6. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen

    2006-08-01

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  7. SU-E-T-602: Beryllium Seeds Implant for Photo-Neutron Yield Using External Beam Therapy

    SciTech Connect (OSTI)

    Koren, S; Veltchev, I; Furhang, E

    2014-06-01

    Purpose: To evaluate the Neutron yield obtained during prostate external beam irradiation. Methods: Neutrons, that are commonly a radiation safety concern for photon beams with energy above 10 MV, are induced inside a PTV from Beryllium implemented seeds. A high megavoltage photon beam delivered to a prostate will yield neutrons via the reaction Be-9(?,n)2?. Beryllium was chosen for its low gamma,n reaction cross-section threshold (1.67 MeV) to be combined with a high feasible 25 MV photon beam. This beam spectra has a most probable photon energy of 2.5 to 3.0 MeV and an average photon energy of about 5.8 MeV. For this feasibility study we simulated a Beryllium-made common seed dimension (0.1 cm diameter and 0.5 cm height) without taking into account encapsulation. We created a 0.5 cm grid loading pattern excluding the Urethra, using Variseed (Varian inc.) A total of 156 seeds were exported to a 4cm diameter prostate sphere, created in Fluka, a particle transport Monte Carlo Code. Two opposed 25 MV beams were simulated. The evaluation of the neutron dose was done by adjusting the simulated photon dose to a common prostate delivery (e.g. 7560 cGy in 42 fractions) and finding the corresponding neutron dose yield from the simulation. A variance reduction technique was conducted for the neutrons yield and transported. Results: An effective dose of 3.65 cGy due to neutrons was found in the prostate volume. The dose to central areas of the prostate was found to be about 10 cGy. Conclusion: The neutron dose yielded does not justify a clinical implant of Beryllium seeds. Nevertheless, one should investigate the Neutron dose obtained when a larger Beryllium loading is combined with commercially available 40 MeV Linacs.

  8. Removal of CDP Mandrels from Sputter Coated Beryllium Capsules for NIF Targets

    SciTech Connect (OSTI)

    Lawrence Livermore National Laboratory

    2006-12-22

    Ablative targets for the National Ignition Campaign (NIC) have been fabricated by sputter coating spherical mandrels made of glow discharge polymer (GDP) with graded copper doped beryllium (Be) layers. The inner mandrel must be completely removed to meet specific ignition design requirements. The process of removing the mandrel requires elevated temperature in the presence of oxygen. However, elevating the temperature in air also oxidizes the Be and can cause blistering on the inner surface of the Be shell. This paper will discuss a refined technique, which removes the GDP mandrel without compromising the integrity of the inner Be surface. The oxygen gradient that develops during the mandrel removal and the impact of its presence will also be discussed.

  9. Thermal and Lorentz force analysis of beryllium windows for a rectilinear muon cooling channel

    SciTech Connect (OSTI)

    Luo, T.; Stratakis, D.; Li, D.; Virostek, S.; Palmer, R. B.; Bowring, D.

    2015-05-03

    Reduction of the 6-dimensional phase-space of a muon beam by several orders of magnitude is a key requirement for a Muon Collider. Recently, a 12-stage rectilinear ionization cooling channel has been proposed to achieve that goal. The channel consists of a series of low frequency (325 MHz-650 MHz) normal conducting pillbox cavities, which are enclosed with thin beryllium windows (foils) to increase shunt impedance and give a higher field on-axis for a given amount of power. These windows are subject to ohmic heating from RF currents and Lorentz force from the EM field in the cavity, both of which will produce out of the plane displacements that can detune the cavity frequency. In this study, using the TEM3P code, we report on a detailed thermal and mechanical analysis for the actual Be windows used on a 325 MHz cavity in a vacuum ionization cooling rectilinear channel for a Muon Collider.

  10. Solid Deuterium-Tritium Surface Roughness In A Beryllium Inertial Confinement Fusion Shell

    SciTech Connect (OSTI)

    Kozioziemski, B J; Sater, J D; Moody, J D; Montgomery, D S; Gautier, C

    2006-04-19

    Solid deuterium-tritium (D-T) fuel layers for inertial confinement fusion experiments were formed inside of a 2 mm diameter beryllium shell and were characterized using phase-contrast enhanced x-ray imaging. The solid D-T surface roughness is found to be 0.4 {micro}m for modes 7-128 at 1.5 K below the melting temperature. The layer roughness is found to increase with decreasing temperature, in agreement with previous visible light characterization studies. However, phase-contrast enhanced x-ray imaging provides a more robust surface roughness measurement than visible light methods. The new x-ray imaging results demonstrate clearly that the surface roughness decreases with time for solid D-T layers held at 1.5 K below the melting temperature.

  11. The use of a beryllium Hopkinson bar to characterize in-axis and cross-axis accelerometer response in shock environments

    SciTech Connect (OSTI)

    Bateman, V.I.; Brown, F.A.

    1997-05-01

    The characteristics of a piezoresistive accelerometer in shock environments are being studied at Sandia National Laboratories in the Mechanical Shock Testing Laboratory. A beryllium Hopkinson bar capability has been developed to extend the understanding of the piezoresistive accelerometer, in two mechanical configurations and with and without mechanical isolation, in the high frequency, high shock environments where measurements are being made. In this paper, recent measurements with beryllium single and split-Hopkinson bar configurations are described. The in axis performance of the piezoresistive accelerometer in mechanical isolation for frequencies of dc-30 kHz and shock magnitudes of up to 6,000 g as determined from measurements with a beryllium Hopkinson bar with a certified laser doppler vibrometer as the reference measurement are presented. Results of characterizations of the accelerometers subjected to cross axis shocks in a split beryllium Hopkinson bar configuration are also presented.

  12. Worker Safety and Health Enforcement Letter issued to Los Alamos National Security, LLC, related to Worker Beryllium Exposure during Machining at the Los Alamos National Laboratorys Beryllium Technology Facility, May 29, 2013 (WEL-2013-01)

    Broader source: Energy.gov (indexed) [DOE]

    29, 2013 Dr. Charles F. McMillan, President Los Alamos National Security, LLC Los Alamos National Laboratory Mailstop A 100, Drop Point 03140071S Bikini Atoll Road, TA-3 Los Alamos, New Mexico 87454 WEL-2013-01 Dear Dr. McMillan: The Office of Health, Safety and Security's Office of Enforcement and Oversight evaluated the circumstances surrounding a work evolution performed at Los Alamos National Laboratory (LANL) Technical Area 3, Building 141, Beryllium Technology Facility (BTF), on July 11,

  13. Massachusetts Beryllium Screening Program for Former Workers of Wyman-Gordon, Norton Abrasives, and MIT/Nuclear Metals

    SciTech Connect (OSTI)

    Pepper, L.D.

    2008-05-21

    The overall objective of this project was to provide medical screening to former workers of Wyman-Gordon Company, Norton Abrasives, and MIT/Nuclear Metals (NMI) in order to prevent and minimize the health impact of diseases caused by site related workplace exposures to beryllium. The program was developed in response to a request by the U.S. Department of Energy (DOE) that had been authorized by Congress in Section 3162 of the 1993 Defense Authorization Act, urging the DOE to ??carry out a program for the identification and ongoing evaluation of current and former DOE employees who are subjected to significant health risks during such employment." This program, funded by the DOE, was an amendment to the medical surveillance program for former DOE workers at the Nevada Test Site (NTS). This program??s scope included workers who had worked for organizations that provided beryllium products or materials to the DOE as part of their nuclear weapons program. These organizations have been identified as Beryllium Vendors.

  14. ORALLOY (93.2 235U) METAL CYLINDER WITH BERYLLIUM TOP REFLECTOR

    SciTech Connect (OSTI)

    John D. Bess; Leland M. Montierth; Raymond Reed; John T. Mihalczo

    2010-09-01

    A variety of critical experiments were constructed of enriched uranium metal during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, one experiment was comprised of a stack of approximately 7-inch-diameter metal discs. The bottom of the stack consisted of uranium with an approximate height of 4-1/8 inches. The top of the stack consisted of beryllium with an approximate height of 5-9/16 inches. This experiment was performed on August 20, 1963 by J. T. Mihalczo and R. G. Taylor (Ref. 1) with accompanying logbook. Both detailed and simplified model specifications are provided in this evaluation. This fast-spectra experiment was determined to represent an acceptable benchmark. The calculated eigenvalues for both the detailed and simple models are within approximately 0.5% of the benchmark values, but significantly greater than 3s from the benchmark value because the uncertainty in the benchmark is very small: 0.0002 (1s). There is significant variability between results using different neutron cross section libraries, the greatest being a ?keff of ~0.65% . Unreflected and unmoderated experiments with the same highly enriched uranium metal parts were performed at the Oak Ridge Critical Experiments Facility in the 1960s and are evaluated in HEU MET FAST 051. Thin graphite reflected (2 inches or less) experiments also using the same highly enriched uranium metal parts are evaluated in HEU MET FAST 071. Polyethylene-reflected configurations are evaluated in HEU-MET-FAST-076. Highly enriched metal annuli with beryllium cores are evaluated in HEU-MET-FAST-059.

  15. ORALLOY (93.15 235U) METAL ANNULI WITH BERYLLIUM CORE

    SciTech Connect (OSTI)

    John D. Bess; Leland M. Montierth; Raymond L. Reed; John T. Mihalczo

    2010-09-01

    A variety of critical experiments were constructed of enriched uranium metal during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, two were performed that consisted of uranium metal annuli with a solid beryllium metal core. The outer diameter of the annuli was approximately 13 or 15 inches with an inner diameter of 7 inches. The diameter of the core was approximately 7 inches. The critical height of the configurations was approximately 5 and 4 inches, respectively. The uranium annuli consisted of multiple stacked rings with diametral thicknesses of approximately 2 inches apiece and varying heights. The 15-inch experiment was performed on June 4, 1963, and the 13-inch experiment on July 12, 1963 by J. T. Mihalczo and R. G. Taylor (Ref. 1) with accompanying logbook. Both detailed and simplified model specifications are provided in this evaluation. Both of these fast-spectra experiments were determined to represent acceptable benchmarks. The calculated eigenvalues for both the detailed and simple models are within approximately 0.6% of the benchmark values, but significantly greater than 3s from the benchmark value because the uncertainty in the benchmark is very small: <0.0004 (1s). There is significant variability between results using different neutron cross section libraries, the greatest being a ?keff of ~0.67%. Unreflected and unmoderated experiments with the same highly enriched uranium metal parts were performed at the Oak Ridge Critical Experiments Facility in the 1960s and are evaluated in HEU MET FAST 051. Thin graphite reflected (2 inches or less) experiments also using the same highly enriched uranium metal parts are evaluated in HEU MET FAST 071. Polyethylene-reflected configurations are evaluated in HEU-MET-FAST-076. A stack of highly enriched metal discs with a thick beryllium reflector is evaluated in HEU-MET-FAST-069.

  16. A Comparison of "Total Dust" and Inhalable Personal Sampling for Beryllium Exposure.

    SciTech Connect (OSTI)

    Carter, C M

    2012-04-25

    In 2009, the American Conference of Governmental Industrial Hygienists (ACGIH) reduced the Beryllium (Be) 8-hr Time Weighted Average Threshold Limit Value (TLV-TWA) from 2.0 {micro}g/m{sup 3} to 0.05 {micro}g/m{sup 3} with an inhalable 'I' designation in accordance with ACGIH's particle size-selective criterion for inhalable mass. Currently, per the Department of Energy (DOE) requirements, the Lawrence Livermore National Laboratory (LLNL) is following the Occupational Health and Safety Administration (OSHA) Permissible Exposure Limit (PEL) of 2.0 {micro}g/m{sup 3} as an 8-hr TWA, which is also the 2005 ACGIH TLV-TWA, and an Action Level (AL) of 0.2 {micro}g/m{sup 3} and sampling is performed using the 37mm (total dust) sampling method. Since DOE is considering adopting the newer 2009 TLV guidelines, the goal of this study was to determine if the current method of sampling using the 37mm (total dust) sampler would produce results that are comparable to what would be measured using the IOM (inhalable) sampler specific to the application of high energy explosive work at LLNL's remote experimental test facility at Site 300. Side-by-side personal sampling using the two samplers was performed over an approximately two-week period during chamber re-entry and cleanup procedures following detonation of an explosive assembly containing Beryllium (Be). The average ratio of personal sampling results for the IOM (inhalable) vs. 37-mm (total dust) sampler was 1.1:1 with a P-value of 0.62, indicating that there was no statistically significant difference in the performance of the two samplers. Therefore, for the type of activity monitored during this study, the 37-mm sampling cassette would be considered a suitable alternative to the IOM sampler for collecting inhalable particulate matter, which is important given the many practical and economic advantages that it presents. However, similar comparison studies would be necessary for this conclusion to be applied to other types of activities, where earlier studies have shown that the IOM sampler tends to collect higher concentrations of Be compared to the 37-mm cassette, which could complicate compliance with what is already an extremely low exposure limit.

  17. file://C:\\Documents and Settings\\bh5\\My Documents\\Energy Effici

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    coke ovens), and rolling mills. 2. 1998 data unavailable due to disclosure avoidance procedures in place at the time. 3. Denominators represent the entire steel industry, not those...

  18. file://C:\\Documents and Settings\\bh5\\My Documents\\Energy Effici

    Gasoline and Diesel Fuel Update (EIA)

    coke ovens), and rolling mills. 3. 1998 data unavailable due to disclosure avoidance procedures in place at the time. 4. Denominators represent the value of production for the...

  19. brwtp-icoke | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1989) Comprehensive Report to Congress Comprehensive Report to Congress on the Clean Coal Technology Program: Innovative Coke Oven Gas Cleaning System for Retrofit Applications...

  20. file://C:\\Documents and Settings\\bh5\\My Documents\\Energy Effici

    Gasoline and Diesel Fuel Update (EIA)

    Classification System (NAICS) has replaced the Standard Industrial Classification (SIC) system. NAICS 331111 includes steel works, blast furnaces (including coke ovens), and...

  1. EA-0404: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Innovative Clean Coal Technology Program - Coke Oven Gas Cleaning Demonstration Project at the Bethlehem Steel Corp. Sparrows Point Plant, Baltimore County, Maryland

  2. Microsoft Word - table_07.doc

    U.S. Energy Information Administration (EIA) Indexed Site

    Notes: Totals may not equal sum of components due to independent rounding. Other includes coke oven gas, blast furnace gas, and air injection for Btu stabilization. Source: Energy ...

  3. file://C:\\Documents and Settings\\bh5\\My Documents\\Energy Effici

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    blast furnaces (including coke ovens), and rolling mills. Deflated by the chain-type price indices for iron and steel mills shipments. 2. Denominators represent the value of...

  4. Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape

    2005-12-01

    High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

  5. ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"

    U.S. Energy Information Administration (EIA) Indexed Site

    Relative Standard Errors for Table 7.1;" " Unit: Percents." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components" " "," ",,,,,,,,,,,,,"Total",,,,,,,,,,,,,,,,,,,,,,,"Wood Residues",,,," " " "," ","

  6. ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Relative Standard Errors for Table 7.2;" " Unit: Percents." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components" " "," ",,,,,,,,,,,,,"Total",,,,,,,,,,,,,,,,,,,,,,,"Wood Residues",,,," " " "," ","

  7. Mechanistic Insights of Ethanol Steam Reforming over NiCeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation

    SciTech Connect (OSTI)

    Liu, Zongyuan; Ducho?, Tom; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matoln, Vladimir; Stacchiola, Dario J.; Rodriguez, Jos A.; Senanayake, Sanjaya D.

    2015-07-30

    We have studied the reaction of ethanol and water over NiCeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on NiCeO2-x(111) at varying Ce? concentrations (CeO1.82.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is the active phase leading to both the CC and CH cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metalsupport interaction between nickel and ceria that facilitates oxygen transfer.

  8. Mechanistic insights of ethanol steam reforming over Ni-CeOx(111): The importance of hydroxyl groups for suppressing coke formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Senanayake, Sanjaya D.; Duchon, Tomas; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolin, Vladimir; Stacchiola, Dario J.; et al

    2015-07-10

    We have studied the reaction of ethanol and water over NiCeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on NiCeO2-x(111) at varying Ce? concentrations (CeO1.82.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themoreactive phase leading to both the CC and CH cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metalsupport interaction between nickel and ceria that facilitates oxygen transfer.less

  9. Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Duchoň, Tomáš; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolín, Vladimir; Stacchiola, Dario J.; Rodriguez, José A.; et al

    2015-07-30

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³⁺ concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni⁰ is themore » active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni₃C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.« less

  10. Reduction of COD in leachate from a hazardous waste landfill adjacent to a coke-making facility

    SciTech Connect (OSTI)

    Banerjee, K.; O`Toole, T.J.

    1995-12-01

    A hazardous waste landfill adjacent to a coke manufacturing facility was in operation between July 1990 and December 1991. A system was constructed to collect and treat the leachate from the landfill prior to discharge to the river. Occasionally, the discharge from the treatment facility exceeded the permit limitations for Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), and Total Organic Carbon (TOC). The objectives of this study were to determine treatment methods which would enable compliance with the applicable discharge limits; to establish the desired operating conditions of the process; and to investigate the effect of various parameters such as pH, catalyst dosage, and reaction time on the COD destruction efficiency. The characteristics of the landfill leachate in question were significantly variable in terms of chemical composition. A review of the influent quality data suggests that the COD concentration ranges between 80 and 390 mg/l. The oxidation processes using Fenton`s reagent or a combination of UV/hydrogen peroxide/catalyst are capable of reducing the COD concentration of the leachate below the discharge limitation of 35 mg/l. The estimated capital cost associated with the Fenton`s reagent process is approximately $525,000, and the annual operating and maintenance cost is $560,000. The estimated capital cost for the UV/hydrogen peroxide/catalyst treatment system is $565,000. The annual operating and maintenance cost of this process would be approximately $430,000.

  11. VALIDATION OF ANALYTICAL METHODS AND INSTRUMENTATION FOR BERYLLIUM MEASUREMENT: REVIEW AND SUMMARY OF AVAILABLE GUIDES, PROCEDURES, AND PROTOCOLS

    SciTech Connect (OSTI)

    Ekechukwu, A

    2009-05-27

    Method validation is the process of evaluating whether an analytical method is acceptable for its intended purpose. For pharmaceutical methods, guidelines from the United States Pharmacopeia (USP), International Conference on Harmonisation (ICH), and the United States Food and Drug Administration (USFDA) provide a framework for performing such valications. In general, methods for regulatory compliance must include studies on specificity, linearity, accuracy, precision, range, detection limit, quantitation limit, and robustness. Elements of these guidelines are readily adapted to the issue of validation for beryllium sampling and analysis. This document provides a listing of available sources which can be used to validate analytical methods and/or instrumentation for beryllium determination. A literature review was conducted of available standard methods and publications used for method validation and/or quality control. A comprehensive listing of the articles, papers and books reviewed is given in the Appendix. Available validation documents and guides are listed therein; each has a brief description of application and use. In the referenced sources, there are varying approches to validation and varying descriptions of the valication process at different stages in method development. This discussion focuses on valication and verification of fully developed methods and instrumentation that have been offered up for use or approval by other laboratories or official consensus bodies such as ASTM International, the International Standards Organization (ISO) and the Association of Official Analytical Chemists (AOAC). This review was conducted as part of a collaborative effort to investigate and improve the state of validation for measuring beryllium in the workplace and the environment. Documents and publications from the United States and Europe are included. Unless otherwise specified, all referenced documents were published in English.

  12. Dynamic response of materials on subnanosecond time scales, and beryllium properties for inertial confinement fusion

    SciTech Connect (OSTI)

    Swift, Damian C.; Tierney, Thomas E.; Luo Shengnian; Paisley, Dennis L.; Kyrala, George A.; Hauer, Allan; Greenfield, Scott R.; Koskelo, Aaron C.; McClellan, Kenneth J.; Lorenzana, Hector E.; Kalantar, Daniel; Remington, Bruce A.; Peralta, Pedro; Loomis, Eric

    2005-05-15

    During the past few years, substantial progress has been made in developing experimental techniques capable of investigating the response of materials to dynamic loading on nanosecond time scales and shorter, with multiple diagnostics probing different aspects of the behavior. These relatively short time scales are scientifically interesting because plastic flow and phase changes in common materials with simple crystal structures--such as iron--may be suppressed, allowing unusual states to be induced and the dynamics of plasticity and polymorphism to be explored. Loading by laser-induced ablation can be particularly convenient: this technique has been used to impart shocks and isentropic compression waves from {approx}1 to 200 GPa in a range of elements and alloys, with diagnostics including line imaging surface velocimetry, surface displacement (framed area imaging), x-ray diffraction (single crystal and polycrystal), ellipsometry, and Raman spectroscopy. A major motivation has been the study of the properties of beryllium under conditions relevant to the fuel capsule in inertial confinement fusion: magnetically driven shock and isentropic compression shots at Z were used to investigate the equation of state and shock melting characteristics, complemented by laser ablation experiments to investigate plasticity and heterogeneous response from the polycrystalline microstructure. These results will help to constrain acceptable tolerances on manufacturing, and possible loading paths, for inertial fusion ignition experiments at the National Ignition Facility. Laser-based techniques are being developed further for future material dynamics experiments, where it should be possible to obtain high quality data on strength and phase changes up to at least 1 TPa.

  13. VALIDATION OF ANALYTICAL METHODS AND INSTRUMENTATION FOR BERYLLIUM MEASUREMENT: REVIEW AND SUMMARY OF AVAILABLE GUIDES, PROCEDURES, AND PROTOCOLS

    SciTech Connect (OSTI)

    Ekechukwu, A.

    2008-12-17

    This document proposes to provide a listing of available sources which can be used to validate analytical methods and/or instrumentation for beryllium determination. A literature review was conducted of available standard methods and publications used for method validation and/or quality control. A comprehensive listing of the articles, papers, and books reviewed is given in Appendix 1. Available validation documents and guides are listed in the appendix; each has a brief description of application and use. In the referenced sources, there are varying approaches to validation and varying descriptions of validation at different stages in method development. This discussion focuses on validation and verification of fully developed methods and instrumentation that have been offered up for use or approval by other laboratories or official consensus bodies such as ASTM International, the International Standards Organization (ISO) and the Association of Official Analytical Chemists (AOAC). This review was conducted as part of a collaborative effort to investigate and improve the state of validation for measuring beryllium in the workplace and the environment. Documents and publications from the United States and Europe are included. Unless otherwise specified, all documents were published in English.

  14. The Use of a Beryllium Hopkinson Bar to Characterize In-Axis and Cross-Axis Accelerometer Response in Shock Environments

    SciTech Connect (OSTI)

    Bateman, V.I.; Brown, F.A.

    1999-01-01

    The characteristics of a piezoresistive accelerometer in shock environments have been studied at Sandia National Laboratories in the Mechanical Shock Laboratory. A beryllium Hopkinson bar capability with diameters of 0.75 in. and 2.0 in has been developed to extend our understanding of the piezoresistive accelerometer, in two mechanical configurations, in the high frequency, high shock environments where measurements are being made. The in-axis performance of the piezoresistive accelerometer determined from measurements with a beryllium Hopkinson bar and a certified laser doppler vibrometer as the reference measurement is presented. The cross-axis performance of the accelerometer subjected to static compression on a beryllium cylinder, static strain on a steel beam, dynamic strain on a steel beam (ISA-RP 37.2, Paragraph 6.6), and compressive shocks in a split beryllium Hopkinson bar configuration is also presented. The performance of the accelerometer in a combined in-axis and cross-axis shock environment is shown for one configuration. Finally, a failure analysis conducted in cooperation with ENDEVCO gives a cause for the occasional unexplained failures that have occurred in some applications.

  15. Technical support document: Energy efficiency standards for consumer products: Room air conditioners, water heaters, direct heating equipment, mobile home furnaces, kitchen ranges and ovens, pool heaters, fluorescent lamp ballasts and television sets. Volume 1, Methodology

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The Energy Policy and Conservation Act (P.L. 94-163), as amended, establishes energy conservation standards for 12 of the 13 types of consumer products specifically covered by the Act. The legislation requires the Department of Energy (DOE) to consider new or amended standards for these and other types of products at specified times. DOE is currently considering amending standards for seven types of products: water heaters, direct heating equipment, mobile home furnaces, pool heaters, room air conditioners, kitchen ranges and ovens (including microwave ovens), and fluorescent light ballasts and is considering establishing standards for television sets. This Technical Support Document presents the methodology, data, and results from the analysis of the energy and economic impacts of the proposed standards. This volume presents a general description of the analytic approach, including the structure of the major models.

  16. Prediction of {sup 1}P Rydberg energy levels of beryllium based on calculations with explicitly correlated Gaussians

    SciTech Connect (OSTI)

    Bubin, Sergiy; Adamowicz, Ludwik

    2014-01-14

    Benchmark variational calculations are performed for the seven lowest 1s{sup 2}2s?np?({sup 1}P), n = 28, states of the beryllium atom. The calculations explicitly include the effect of finite mass of {sup 9}Be nucleus and account perturbatively for the mass-velocity, Darwin, and spin-spin relativistic corrections. The wave functions of the states are expanded in terms of all-electron explicitly correlated Gaussian functions. Basis sets of up to 12500 optimized Gaussians are used. The maximum discrepancy between the calculated nonrelativistic and experimental energies of 1s{sup 2}2s?np?({sup 1}P) ?1s{sup 2}2s{sup 2}?({sup 1}S) transition is about 12 cm{sup ?1}. The inclusion of the relativistic corrections reduces the discrepancy to bellow 0.8 cm{sup ?1}.

  17. STARTUP REACTIVITY ACCOUNTABILITY ATTRIBUTED TO ISOTOPIC TRANSMUTATIONS IN THE IRRADIATED BERYLLIUM REFLECTOR OF THE HIGH FLUX ISTOTOPE REACTOR

    SciTech Connect (OSTI)

    Chandler, David [ORNL] [ORNL; Maldonado, G Ivan [ORNL] [ORNL; Primm, Trent [ORNL] [ORNL

    2010-01-01

    The objective of this study is to develop a methodology to predict the reactivity impact as a function of outage time between cycles of 3He, 6Li, and other poisons in the High Flux Isotope Reactor s (HFIR) beryllium reflector. The reactivity worth at startup of the HFIR has been incorrectly predicted in the past after the reactor has been shut-down for long periods of time. The incorrect prediction was postulated to be due to the erroneous calculation of 3He buildup in the beryllium reflector. It is necessary to develop a better estimate of the start-of-cycle symmetric critical control element positions since if the estimated and actual symmetrical critical control element positions differ by more than $1.55 in reactivity (approximately one-half inch in control element startup position), HFIR is to be shutdown and a technical evaluation is performed to resolve the discrepancy prior to restart. 3He is generated and depleted during operation, but during an outage, the depletion of 3He ceases because it is a stable isotope. 3He is born from the radioactive decay of tritium, and thus the concentration of 3He increases during shutdown. The computer program SCALE, specifically the TRITON and CSAS5 control modules including the KENO V.A, COUPLE, and ORIGEN functional modules were utilized in this study. An equation relating the down time (td) to the change in symmetric control element position was generated and validated against measurements for approximately 40 HFIR operating cycles. The newly-derived correlation was shown to improve accuracy of predictions for long periods of down time.

  18. Pushing schedule derivation method

    SciTech Connect (OSTI)

    Henriquez, B.

    1996-12-31

    The development of a Pushing Schedule Derivation Method has allowed the company to sustain the maximum production rate at CSH`s Coke Oven Battery, in spite of having single set oven machinery with a high failure index as well as a heat top tendency. The stated method provides for scheduled downtime of up to two hours for machinery maintenance purposes, periods of empty ovens for decarbonization and production loss recovery capability, while observing lower limits and uniformity of coking time.

  19. Evaluation of beryllium exposure assessment and control programs at AWE, Cardiff Facility, Rocky Flats Plant, Oak Ridge Y-12 Plant and Lawrence Livermore National Laboratory. Phase 1

    SciTech Connect (OSTI)

    Johnson, J.S.; Foote, K.L.; Slawski, J.W.; Cogbill, G.

    1995-04-28

    Site visits were made to DOE beryllium handling facilities at the Rocky Flats Plant; Oak Ridge Y-12 Plant, LLNL; as well as to the AWE Cardiff Facility. Available historical data from each facility describing its beryllium control program were obtained and summarized in this report. The AWE Cardiff Facility computerized Be personal and area air-sampling database was obtained and a preliminary evaluation was conducted. Further validation and documentation of this database will be very useful in estimating worker Be. exposure as well as in identifying the source potential for a variety of Be fabrication activities. Although all of the Be control programs recognized the toxicity of Be and its compounds, their established control procedures differed significantly. The Cardiff Facility, which was designed for only Be work, implemented a very strict Be control program that has essentially remained unchanged, even to today. LLNL and the Oak Ridge Y-12 Plant also implemented a strict Be control program, but personal sampling was not used until the mid 1980s to evaluate worker exposure. The Rocky Flats plant implemented significantly less controls on beryllium processing than the three previous facilities. In addition, records were less available, management and industrial hygiene staff turned over regularly, and less control was evident from a management perspective.

  20. Benchmark Evaluation of Fuel Effect and Material Worth Measurements for a Beryllium-Reflected Space Reactor Mockup

    SciTech Connect (OSTI)

    Marshall, Margaret A.; Bess, John D.

    2015-02-01

    The critical configuration of the small, compact critical assembly (SCCA) experiments performed at the Oak Ridge Critical Experiments Facility (ORCEF) in 1962-1965 have been evaluated as acceptable benchmark experiments for inclusion in the International Handbook of Evaluated Criticality Safety Benchmark Experiments. The initial intent of these experiments was to support the design of the Medium Power Reactor Experiment (MPRE) program, whose purpose was to study power plants for the production of electrical power in space vehicles. The third configuration in this series of experiments was a beryllium-reflected assembly of stainless-steel-clad, highly enriched uranium (HEU)-O2 fuel mockup of a potassium-cooled space power reactor. Reactivity measurements cadmium ratio spectral measurements and fission rate measurements were measured through the core and top reflector. Fuel effect worth measurements and neutron moderating and absorbing material worths were also measured in the assembly fuel region. The cadmium ratios, fission rate, and worth measurements were evaluated for inclusion in the International Handbook of Evaluated Criticality Safety Benchmark Experiments. The fuel tube effect and neutron moderating and absorbing material worth measurements are the focus of this paper. Additionally, a measurement of the worth of potassium filling the core region was performed but has not yet been evaluated Pellets of 93.15 wt.% enriched uranium dioxide (UO2) were stacked in 30.48 cm tall stainless steel fuel tubes (0.3 cm tall end caps). Each fuel tube had 26 pellets with a total mass of 295.8 g UO2 per tube. 253 tubes were arranged in 1.506-cm triangular lattice. An additional 7-tube cluster critical configuration was also measured but not used for any physics measurements. The core was surrounded on all side by a beryllium reflector. The fuel effect worths were measured by removing fuel tubes at various radius. An accident scenario was also simulated by moving outward twenty fuel rods from the periphery of the core so they were touching the core tank. The change in the system reactivity when the fuel tube(s) were removed/moved compared with the base configuration was the worth of the fuel tubes or accident scenario. The worth of neutron absorbing and moderating materials was measured by inserting material rods into the core at regular intervals or placing lids at the top of the core tank. Stainless steel 347, tungsten, niobium, polyethylene, graphite, boron carbide, aluminum and cadmium rods and/or lid worths were all measured. The change in the system reactivity when a material was inserted into the core is the worth of the material.

  1. Experimental Investigations on Pulsed Nd:YAG Laser Welding of C17300 Copper-Beryllium and 49Ni-Fe Soft Magnetic Alloys

    SciTech Connect (OSTI)

    Mousavi, S. A. A. Akbari [School of Metallurgy and Materials Engineering, School of Engineering University of Tehran, Tehran (Iran, Islamic Republic of); School of Metallurgy and Materials Engineering, School of Engineering University of Tehran, Tehran (Iran, Islamic Republic of); Ebrahimzadeh, H. [School of Metallurgy and Materials Engineering, School of Engineering University of Tehran, Tehran (Iran, Islamic Republic of)

    2011-01-17

    Copper-beryllium and soft magnetic alloys must be joined in electrical and electro-mechanical applications. There is a high difference in melting temperatures of these alloys which cause to make the joining process very difficult. In addition, copper-beryllium alloys are of age hardenable alloys and precipitations can brittle the weld. 49Ni-Fe alloy is very hot crack sensitive. Moreover, these alloys have different heat transfer coefficients and reflection of laser beam in laser welding process. Therefore, the control of welding parameters on the formation of adequate weld puddle composition is very difficult. Laser welding is an advanced technique for joining of dissimilar materials since it can precisely control and adjust the welding parameters. In this study, a 100W Nd:YAG pulsed laser machine was used for joining 49Ni-Fe soft magnetic to C17300 copper-beryllium alloys. Welding of samples was carried out autogenously by changing the pulse duration, diameter of beam, welding speed, voltage and frequency. The spacing between samples was set to almost zero. The ample were butt welded. It was required to apply high voltage in this study due to high reflection coefficient of copper alloys. Metallography, SEM analysis, XRD and microhardness measurement was used for survey of results. The results show that the weld strength depends upon the chemical composition of the joints. To change the wells composition and heat input of the welds, it was attempted to deviate the laser focus away from the weld centerline. The best strength was achieved by deviation of the laser beam away about 0.1mm from the weld centerline. The result shows no intermetallic compounds if the laser beam is deviated away from the joint.

  2. Dynamic response of materials on sub-nanosecond time scales, and beryllium properties for inertial confinement fusion

    SciTech Connect (OSTI)

    Swift, D C; Tierney, T E; Luo, S N; Paisley, D L; Kyrala, G A; Hauer, A; Greenfield, S R; Koskelo, A C; McClellan, K J; Lorenzana, H E; Knudson, M D; Peralta, P P; Loomis, E

    2004-12-09

    During the past few years, substantial progress has been made in developing experimental techniques capable of investigating the response of materials to dynamic loading on nanosecond time scales and shorter, with multiple diagnostics probing different aspects of the behavior. these relatively short time scales are scientifically interesting because plastic flow and phase changes in common materials with simple crystal structures--such as iron--may be suppressed, allowing unusual states to be induced and the dynamics of plasticity and polymorphism to be explored. Loading by laser ablation can be particularly convenient. The TRIDENT laser has been used to impart shocks and isentropic compression waves from {approx}1 to 200GPa in a range of elements and alloys, with diagnostics including surface velocimetry (line-imaging VISAR), surface displacement (framed area imaging), x-ray diffraction (single crystal and polycrystal), ellipsometry, and Raman spectroscopy. A major motivation has been the study of the properties of beryllium under conditions relevant to the fuel capsule in inertial confinement fusion: magnetically-driven shock and isentropic compression shots at Z were used to investigate the equation of state and shock melting characteristics, complemented by laser ablation experiments to investigate plasticity and heterogeneous response. These results will help to constrain acceptable tolerances on manufacturing, and possible loading paths, for inertial fusion ignition experiments at the National Ignition Facility. Laser-based techniques are being developed further for future material dynamics experiments, where it should be possible to obtain high quality data on strength and phase changes up to at least 1TPa.

  3. Microstructure and properties of rapidly solidified beryllium-transition metal alloys. [With small amounts of Ti, Zr and Y (1-3 wt %)

    SciTech Connect (OSTI)

    Jacobson, L.A.; Richardson, S.

    1988-01-01

    Alloys of beryllium with small amounts of Ti, Zr and Y (1-3 wt %) were rapidly solidified using an arc hammer splat technique. Each of these elements forms a dilute eutectic with beryllium, and has very low solid solubility in the alpha phase. In the case of Ti, the Be-rich compound is TiBe/sub 12/, and for Zr and Y, the compound is MBe. The objective of the work was to achieve a fine, uniform dispersion of particles of the intermetallic compound. Since these compounds have very high melting points, it was expected that rapidly solidified microstructures would be relatively stable at elevated temperatures. This microstructural stability should result in improved high temperature properties for the alloys. Microstructures have been characterized using optical, scanning and transmission electron microscopy. Microhardness measurements have been made in order to determine the effects of rapid solidification and to evaluate the effects of high temperature exposure on microstructural stability and property retention. The results will be presented in light of the potential of these alloys for intermediate temperature application. 12 refs., 8 figs.

  4. Characteristics of the WWR-K test core and the LEU LTAS to be placed in the central experimental beryllium device.

    SciTech Connect (OSTI)

    Arinkin, F.; Chakrov, P.; Chekushina, L.; Gizatulin,, Sh.; Koltochnik, S.; Hanan, N.; Garner, P.; Nuclear Engineering Division; Kazakhstan Ministry of Energy and Mineral Resources

    2010-03-01

    In 2010 life test of three LEU (19.7%) lead test assemblies (LTA) is expected in the existing WWR-K reactor core with regular WWR-C-type fuel assemblies and a smaller core with a beryllium insert. Preliminary analysis of test safety is to be carried out. It implies reconstruction of the reactor core history for last three years, including burnup calculation for each regular fuel assembly (FA), as well as calculation of characteristics of the test core. For the planned configuration of the test core a number of characteristics have been calculated. The obtained data will be used as input for calculations on LTA test core steady-state thermal hydraulics and on transient analysis.

  5. CRITICAL CONFIGURATION FOR BERYLLIUM REFLECTED ASSEMBLIES OF U(93.15)O2 FUEL RODS (1.506-CM PITCH AND 7-TUBE CLUSTERS)

    SciTech Connect (OSTI)

    Margaret A. Marshall

    2012-05-01

    A series of critical experiments were completed in 1962-1965 at Oak Ridge National Laboratorys Critical Experiments Facility in support of the Medium-Power Reactor Experiments (MPRE) program. In the late 1950s efforts were made to study power plants for the production of electrical power in space vehicles. The MPRE program was a part of those efforts and studied the feasibility of a stainless steel system, boiling potassium 1 MW(t), or about 140 kW(e), reactor. The program was carried out in [fiscal years] 1964, 1965, and 1966. A summary of the programs effort was compiled in 1967. The delayed critical experiments were a mockup of a small, potassium-cooled space power reactor for validation of reactor calculations and reactor physics methods. Initial experiments, performed in November and December of 1962, consisted of a core of 253 unmoderated stainless steel tubes, each containing 26 UO2 fuel pellets, surrounded by a graphite reflector. Measurements were made to determine critical reflector arrangements, fission-rate distributions, and cadmium ratio distributions. The [assemblies were built] on [a] vertical assembly machine so that the movable part was the core and bottom reflector. The first two experiments in the series were evaluated in HEU-COMP-FAST-001 (SCCA-FUND-EXP-001) and HEU-COMP-FAST-002 (SCCA-FUND-EXP-002). The first experiment had the 253 fuel tubes packed tightly into a 22.87 cm outside diameter (OD) core tank (References 1 and 2). The second experiment in the series, performed in early 1963, had the 253 fuel tubes at a 1.506-cm triangular lattice in a 25.96 cm OD core tank and graphite reflectors on all sides. The third set of experiments in the series, performed in mid-1963, which is studied in this evaluation, used beryllium reflectors. The beryllium reflected system was the preferred reactor configuration for this application because of the small thickness of the reflector. The two core configurations had the 253 fuel tubes at a 1.506-cm triangular lattice and arranged in 7-tube clusters. The experiments have been determined to represent acceptable benchmark experiments. Information for this evaluation was compiled from published reports on all three parts of the experimental series (Reference 1-5) and the experimental logbook as well as from communication with the experimenter, John T. Mihalczo.

  6. Modification of environmental control of cokemaking plant

    SciTech Connect (OSTI)

    Katoh, H.; Yasuno, M.; Gotch, T.; Yoshida, F.

    1993-01-01

    Recently, global environmental protection has been a great concern in the world. In the United States of America, the Clean Air Act (CAA) has been revised to control emissions strictly. Especially in the field of cokemaking, the restriction of fume emission from a coke oven is so severe that old coke ovens will stop operation with the application of CAA. In Japan, it is expected that more severe protection measures are going to be requested for keeping environmental quality. In this situation, it is indispensable to strengthen environmental protection measures for cokemaking plants to continue coke production in the 21st century. In Chiba Works, Kawasaki Steep Corp., the Ironmaking Department has been struggling for the improvement of environmental measures for. These activities for coke ovens are described in this report. The paper describes fume emission control from the coke oven door and dust emission control measures, including the dust monitoring system, prevention of secondary dust scattering from coke ovens, replacement of dedusters, and fume and dust control of stack emission.

  7. Supercomputers Take a Cue From Microwave Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for one or a few dedicated functions. "Because the ultimate goal of the embedded market is to maximize battery life, these technologies have always been driven by...

  8. A fully integrated oven controlled microelectromechanical oscillator...

    Office of Scientific and Technical Information (OSTI)

    Authors: Wojciechowski, Kenneth E. 1 ; Baker, Michael S. 1 ; Clews, Peggy J. 1 ; Olsson, Roy H. 1 + Show Author Affiliations Sandia National Lab. (SNL-NM), Albuquerque, NM ...

  9. A fully integrated oven controlled microelectromechanical oscillator...

    Office of Scientific and Technical Information (OSTI)

    Additional Journal Information: Journal Volume: 24; Journal Issue: 6; Journal ID: ISSN 1057-7157 Publisher: IEEE Research Org: Sandia National Laboratories (SNL-NM), Albuquerque, ...

  10. Shock wave compression of hexagonal-close-packed metal single crystals: Time-dependent, anisotropic elastic-plastic response of beryllium

    SciTech Connect (OSTI)

    Winey, J. M.; Gupta, Y. M.

    2014-07-21

    Understanding and modeling the response of hcp metals to high stress impulsive loading is challenging because the lower crystal symmetry, compared to cubic metals, results in a significantly more complex material response. To gain insight into the inelastic deformation of hcp metals subjected to high dynamic stresses, shock wave compression of single crystals provides a useful approach because different inelastic deformation mechanisms can be examined selectively by shock compression along different crystal orientations. As a representative example, we report, here, on wave propagation simulations for beryllium (Be) single crystals shocked along the c-axis, a-axis, and several low-symmetry directions to peak stresses reaching 7?GPa. The simulations utilized a time-dependent, anisotropic material model that incorporated dislocation dynamics, deformation twinning, and shear cracking based descriptions of inelastic deformation. The simulation results showed good overall agreement with measured wave profiles for all the different crystal orientations examined [Pope and Johnson, J. Appl. Phys. 46, 720 (1975)], including features arising from wave mode coupling due to the highly anisotropic inelastic response of Be. This good agreement demonstrates that the measured profiles can be understood in terms of dislocation slip along basal, prismatic, and pyramidal planes, together with deformation twinning along (101{sup }2) planes. Our results show that the response of shocked Be single crystals involves the simultaneous operation of multiple, distinct inelastic deformation mechanisms for all orientations except the c-axis. For shocked c-axis Be, the measured wave profiles do not provide good discrimination between pyramidal slip and other inelastic deformation mechanisms, such as shear cracking. The findings presented here provide insight into the complex inelastic deformation response of shocked Be single crystals and are expected to be useful for other hcp crystals. More broadly, the present work demonstrates the potential of shock wave propagation along low-symmetry directions to examine, and discriminate between, different inelastic deformation mechanisms in crystalline solids.

  11. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    1998-12-23

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; and (4) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: Conducting bench-scale tests to produce coke and acceptable tar from the process to satisfy Koppers, a prospective stakeholder; Consolidation of the project team players to execute the full size commercial cokemaking reactor demonstration; and Progress made in advancing the design of the full size commercial cokemaking reactor.

  12. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    1999-06-23

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (4) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (5) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: Detailed studies of LTV's site for the installation of the commercial Demonstration Unit with site specific layouts; Environmental Work; Firm commitments for funding from the private sector; and Federal funding to complement the private contribution.

  13. Battery operation experience at SSAB, Luleaa six years after rehabilitation

    SciTech Connect (OSTI)

    Petrini, H.; Sundgren, M.; Meyer, G.

    1995-12-01

    SSAB operates a coke oven plant in Luleaa, Sweden, consisting of one 7 m battery. Pushing the first coke in 1975, the battery encountered over the years more and more difficulties in keeping coking time and operation level at the design rate. In order to improve the coke supply a major repair of the battery was made. In 1989 the battery was fully rehabilitated by Krupp Koppers. The experience made during the years before and during repair contributed to a new policy for the operation of the plant. The policy has led to considerable improvements. It is clear that it is possible to successfully operate a rehabilitated battery.

  14. Evaluation of Cadmium Ratio and Foil Activation Measurements for a Beryllium-Reflected Assembly of U(93.15)O2 Fuel Rods (1.506-cm Triangular Pitch)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Marshall, Margaret A.

    2014-11-04

    A series of small, compact critical assembly (SCCA) experiments were completed from 1962 to 1965 at Oak Ridge National Laboratory’s Critical Experiments Facility (ORCEF) in support of the Medium-Power Reactor Experiments (MPRE) program. Initial experiments, performed in November and December of 1962, consisted of a core of un-moderated stainless-steel tubes, each containing 26 UOIdaho National Laboratory (INL), Idaho Falls, ID (United States) fuel pellets, surrounded by a graphite reflector. Measurements were performed to determine critical reflector arrangements, fission-rate distributions, and cadmium ratio distributions. The graphite reflectors were then changed to beryllium reflectors. For the beryllium reflected assemblies, the fuel wasmore » in 1.506-cm-triangular and 7-tube clusters leading to two critical configurations. Once the critical configurations had been achieved, various measurements of reactivity, relative axial and radial activation rates of 235U, and cadmium ratios were performed. The cadmium ratio, reactivity, and activation rate measurements, performed on the 1.506-cm-array critical configuration, have been evaluated and are described in this paper.« less

  15. THORIUM-SILICON-BERYLLIUM ALLOYS

    DOE Patents [OSTI]

    Foote, F.G.

    1959-02-10

    Th, Si, anol Bt alloys where Be and Si are each present in anmounts between 0.1 and 3.5% by weight and the total weight per cent of the minor alloying elements is between 1.5 and 4.5% are discussed. These ternary alloys show increased hardness and greater resistant to aqueous corrosion than is found in pure Th, Th-Si alloys, or Th-Be alloys.

  16. Beryllium - HPMC Occupational Health Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (HRP) Industrial Rehabilitation & Ergonomics Infection Control & Immunizations Influenza Immunization Program Medical Exam Scheduling Medical Exams Return to Work Risk...

  17. Nonrecovery cokemaking/cogeneration complex at Inland Steel scheduled to start up in mid-1998

    SciTech Connect (OSTI)

    Samways, N.L.

    1997-12-01

    A 1.33 million ton/year cokemaking/cogeneration power complex is under construction at the Indiana Harbor Works. The cokemaking plant consists of four batteries of nonrecovery type coke ovens representing a total of 268 ovens. The cogeneration energy facilities include: 16 heat recovery boilers; a steam turbine generator, and a flue gas desulfurization system. Start-up is scheduled for mid-1998. Both facilities are described.

  18. L{sub g}?=?100?nm In{sub 0.7}Ga{sub 0.3}As quantum well metal-oxide semiconductor field-effect transistors with atomic layer deposited beryllium oxide as interfacial layer

    SciTech Connect (OSTI)

    Koh, D., E-mail: dh.koh@utexas.edu, E-mail: Taewoo.Kim@sematech.org [Department of Electrical and Computer Engineering, Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States); SEMATECH, Inc., Albany, New York 12203 (United States); Kwon, H. M. [Department of Electronics Engineering, Chungnam National University, Daejeon 305-764 (Korea, Republic of); Kim, T.-W., E-mail: dh.koh@utexas.edu, E-mail: Taewoo.Kim@sematech.org; Veksler, D.; Gilmer, D.; Kirsch, P. D. [SEMATECH, Inc., Albany, New York 12203 (United States); Kim, D.-H. [SEMATECH, Inc., Albany, New York 12203 (United States); GLOBALFOUNDRIES, Malta, New York 12020 (United States); Hudnall, Todd W. [Department of Chemistry and Biochemistry, Texas State University, San Marcos, Texas, 78666 (United States); Bielawski, Christopher W. [Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas 78712 (United States); Maszara, W. [GLOBALFOUNDRIES, Santa Clara, California 95054 (United States); Banerjee, S. K. [Department of Electrical and Computer Engineering, Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)

    2014-04-21

    In this study, we have fabricated nanometer-scale channel length quantum-well (QW) metal-oxide-semiconductor field effect transistors (MOSFETs) incorporating beryllium oxide (BeO) as an interfacial layer. BeO has high thermal stability, excellent electrical insulating characteristics, and a large band-gap, which make it an attractive candidate for use as a gate dielectric in making MOSFETs. BeO can also act as a good diffusion barrier to oxygen owing to its small atomic bonding length. In this work, we have fabricated In{sub 0.53}Ga{sub 0.47}As MOS capacitors with BeO and Al{sub 2}O{sub 3} and compared their electrical characteristics. As interface passivation layer, BeO/HfO{sub 2} bilayer gate stack presented effective oxide thickness less 1 nm. Furthermore, we have demonstrated In{sub 0.7}Ga{sub 0.3}As QW MOSFETs with a BeO/HfO{sub 2} dielectric, showing a sub-threshold slope of 100?mV/dec, and a transconductance (g{sub m,max}) of 1.1 mS/?m, while displaying low values of gate leakage current. These results highlight the potential of atomic layer deposited BeO for use as a gate dielectric or interface passivation layer for IIIV MOSFETs at the 7?nm technology node and/or beyond.

  19. Operational experience using the novel FixCup collecting main valve

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F.; Spitz, J.

    1996-12-31

    On the occasion of the 1995 AIME conference the new PROven (Pressure Regulated Oven) process to control the pressure in coke ovens individually was introduced. This process was made feasible with a new collecting main valve, termed FixCup, with the aid of this valve a variable flow resistance to the raw gas discharge can be realized using a water immersion system. However, just the application of the FixCup system alone--without any pressure regulation--is very advantageous and cost saving. Thyssen has equipped 30 ovens with the new valve. The special constructive features as well as the operational experience using the FixCup valve are treated.

  20. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    ALBERT CALDERON

    1998-09-22

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (i) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; and (iv) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: ? Consolidation of the project team-players; ? Recruiting Koppers Industries as an additional stakeholder; ? Developing a closed system for the production of binder pitch from tar in the Calderon coking process as the incentive for Koppers to join the team; ? Gathering appropriate equipment for conducting a set of experiments at bench scale to simulate tar quality produced from the Calderon coking process for the production of binder pitch; and ? Further progress made in the design of the commercial coking reactor.

  1. Energy Efficiency Standards for Microwave Ovens Saves Consumers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Positive Impact Significant savings to consumer energy bills and reductions in carbon pollution. Locations Nationwide Partners Lawrence Berkeley National Laboratory, Navigant EERE ...

  2. Oven rack having integral lubricious, dry porcelain surface

    SciTech Connect (OSTI)

    Ambrose, Jeffrey A; Mackiewicz-Ludtka, Gail; Sikka, Vinod K; Qu, Jun

    2014-06-03

    A lubricious glass-coated metal cooking article capable of withstanding repeated heating and cooling between room temperature and at least 500.degree. F. without chipping or cracking the glass coating, wherein the glass coating includes about 0.1 to about 20% by weight of a homogeneously distributed dry refractory lubricant material having a particle size less than about 200 .mu.m. The lubricant material is selected from the group consisting of carbon; graphite; boron nitride; cubic boron nitride; molybdenum (FV) sulfide; molybdenum sulfide; molybdenum (IV) selenide; molybdenum selenide, tungsten (IV) sulfide; tungsten disulfide; tungsten sulfide; silicon nitride (Si.sub.3N.sub.4); TiN; TiC; TiCN; TiO.sub.2; TiAlN; CrN; SiC; diamond-like carbon; tungsten carbide (WC); zirconium oxide (ZrO.sub.2); zirconium oxide and 0.1 to 40 weight % aluminum oxide; alumina-zirconia; antimony; antimony oxide; antimony trioxide; and mixtures thereof.

  3. New Energy Efficiency Standards for Microwave Ovens to Save Consumers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    "Appliance efficiency standards represent a huge opportunity to help families save money by saving energy, while still delivering high quality appliances for consumers," said ...

  4. Covered Product Category: Commercial Ovens | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    product is available to meet the functional requirements, or that no such product is life cycle cost-effective for a specific application. Additional information on Federal...

  5. Primary Contractors/Employers - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium...

  6. ORISE: Beryllium laboratory achieves accreditation from College...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and the public by fostering and advocating excellence in the practice of pathology and laboratory medicine worldwide. The CAP's Laboratory Improvement Programs...

  7. Chronic Beryllium Disease Prevention Program What's New

    Broader source: Energy.gov [DOE]

    For additional information Contact: David Weitzman, Office of Worker Safety and Health Policy at (301) 903-5401 or: David.Weitzman@hq.doe.gov.

  8. Beryllium Lymphocyte Proliferation Testing (BeLPT)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... FOREWORD 1. Use of this purchase specification is not mandatory. User should review the ... Wash the cells three times to be certain all surfactant proteins are removed. A calcium ...

  9. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2000-06-21

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (i) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (iv) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (v) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter continued to be focused on the following: Concluding the Negotiation and completing Contracts among Stakeholders of the Team; Revision of Final Report for Phase I; Engineering Design Progress; Selection of Systems Associates, Inc. for design of Control System; Conclusion of Secrecy Agreement with Carborundum (St. Gobain); and Permitting Work and Revisions.

  10. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    ALBERT CALDERON

    1998-06-22

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitating commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; and (4) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on three main activities: Continuation of design of the coking reactor; Raising funds from the private sector; and Detailed analysis of the tests conducted in Alliance, Ohio. The design of the reactor work centered on the provision for the capability to inspect and maintain the internals of the reactor. The activities relating to raising funds from the steel industry have been fruitful. Bethlehem Steel has agreed to contribute funds. The collected data from the tests at Alliance were analyzed and a detailed report was completed and presented to the International Iron & Steel Institute by invitation.

  11. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2000-09-19

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (i) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (iv) conducting a blast furnace test to demonstrate the compatibility of the coke produced; (v) demonstrating that coke can be produced economically, at a level competitive with coke imports; and (vi) applying the Calderon technology to making additional iron units. The activities of the past quarter were focused on the following: (1) Bethlehem Steel's withdrawal and efforts expended to substitute U.S. Steel for Bethlehem; (2) Assessment work performed with U.S. Steel to show that the Calderon Technology has merit and would add to U.S. Steel's economic benefit by being involved in it, including for making additional iron units; (3) Addressing material selection and heat input capacity to increase heat input into the processing reactor by actual modeling of such approach; (4) Construction of two full size courses of heating tiles to verify the manufacturing and the fitting of the tiles with one another; (5) Making available equipment to test carbon deposition on sorbent; and (6) Permitting issues.

  12. Table 3.5 Selected Byproducts in Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Selected Byproducts in Fuel Consumption, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Trillion Btu. Blast Pulping Liquor NAICS Furnace/Coke Petroleum or Wood Chips, Code(a) Subsector and Industry Total Oven Gases Waste Gas Coke Black Liquor Bark Total United States 311 Food 11 0 7 0 0 1 3112 Grain and Oilseed Milling 5 0 2 0 0 * 311221 Wet Corn Milling * 0 * 0 0 0 31131 Sugar Manufacturing * 0 * 0 0 * 3114 Fruit and Vegetable Preserving and Specialty

  13. Originally Released: August 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    August 2009 Revised: October 2009 Next MECS will be conducted in 2010 Table 3.5 Selected Byproducts in Fuel Consumption, 2006; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Trillion Btu. Waste Blast Pulping Liquor Oils/Tars NAICS Furnace/Coke Petroleum or Wood Chips, and Waste Code(a) Subsector and Industry Total Oven Gases Waste Gas Coke Black Liquor Bark Materials Total United States 311 Food 10 0 3 0 0 7 Q 3112 Grain and Oilseed Milling 7 0 1 0 0 6 *

  14. Released: August 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Relative Standard Errors for Table 3.5;" " Unit: Percents." ,,,,,,,,"Waste",," " ,,,"Blast",,,"Pulping Liquor",,"Oils/Tars" "NAICS",,,"Furnace/Coke",,"Petroleum","or","Wood Chips,","and Waste" "Code(a)","Subsector and Industry","Total","Oven Gases","Waste Gas","Coke","Black

  15. The operation results with the modified charging equipment and ignition furnace at Kwangyang No. 2 sinter plant

    SciTech Connect (OSTI)

    Lee, K.J.; Pi, Y.J.; Kim, J.R.; Lee, J.N.

    1996-12-31

    There will be another blast furnace, the production capacity of which is 3.0 million tonnes per year in 1999 and mini mill plant, the production capacity of which is 1.8 million tonnes per year in 1996 at Kwangyang Works. Therefore, the coke oven gas and burnt lime will be deficient and more sinter will be needed. To meet with these situations, the authors modified the charging equipment and ignition furnace at Kwangyang No. 2 sinter plant in April 1995. After the modification of the charging equipment and ignition furnace, the consumption of burnt lime and coke oven gas could be decreased and the sinter productivity increased in spite of the reduction of burnt lime consumption. This report describes the operation results with the modification of the charging equipment and ignition furnace in No. 2 sinter plant Kwangyang works.

  16. The AISI (American Iron and Steel Inst. ) program for direct steelmaking

    SciTech Connect (OSTI)

    Aukrust, E. ); Downing, K.B. )

    1990-01-01

    AISI with co-funding from DOE has initiated a research and development program aimed at the development of a new process for direct steelmaking, and the program is discussed in this document. The project is expected to cost about $30 million over a three-year period, with the government providing approximately 77 percent of the funds and AISI the balance. In contrast to current steelmaking processes which are largely open and batch, the direct steelmaking process would be closed and continuous. Further, it would use coal directly, thereby avoiding the need for coke ovens. It is thought that this new process, if successful, would have significant capital and operating cost benefits. Further, there would be important energy savings and environmental benefits, primarily as a result of the elimination of coke ovens. 10 refs., 1 fig., 2 tabs.

  17. Deuterium retention and out-gassing from beryllium oxide on beryllium

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Roth, J.; Wampler, W. R.; Oberkofler, M.; van Deusen, S.; Elgeti, S.

    2014-06-27

    We studied the desorption of D implanted into Be with a superficial oxide layer. We found that the different oxide thicknesses and implantation at different energies resulted in a strong variation of the fraction stopped within the oxide layer. Thermal desorption of D was subsequently performed, intermitted by nuclear reaction analysis for assessment of the D depth distributions and total retained amounts. Moreover, for the conditions, where part of the D was deposited in the Be substrate, a sharp decrease of the retained amount of D occurs around 200 °C. This is attributed to the release from metallic Be. Correspondingly,more » the D and O depth profiles show that above 200 °C the remaining D is only retained in the BeO layer. Apparently, the superficial BeO layer does not act as a diffusion barrier for D that is released from the metallic substrate. The retained amount of D deposited within the BeO layer decreases steadily and is not completely released at 350 °C, the foreseen bake-out temperature in ITER.« less

  18. Hydroprocessing Bio-oil and Products Separation for Coke Production

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2013-04-01

    Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

  19. brwtp-icoke | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovative Coke Oven Gas Cleaning System for Retrofit Applications - There is no Project Brief for this project (Withdrawn) Bethlehem Steel Corporation, Bethlehem, PA PROGRAM PUBLICATIONS Annual/Quarterly Technical Reports Quarterly Technical Progress Reports Number 6, April - June 1991 [PDF-409KB] (Aug 1994) Number 5, January - March 1991 [PDF-326KB] (Mar 1994) Number 4, October - December 1990 [PDF-453KB] (Dec 1990) Number 2, April - June 1990 [PDF-500KB] (Sept 1990) Number 1, May 1989 - March

  20. A Novel Flash Ironmaking Process

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ironmaking Process ADVANCED MANUFACTURING OFFICE A Novel Flash Ironmaking Process Advancing a Cost-Efficient Option to Produce Iron and Eliminate Pelletizing Operations. Steel is used in a wide variety of manufactured products, such as skyscrapers, automobiles, and bridges. The coke oven/ blast furnace process that produces pig iron for steelmaking requires additional energy to prepare the raw iron ore as sinter and pellets, and consumes large amounts of carbon which is emitted as the greenhouse

  1. Paired Straight Hearth Furnace

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Paired Straight Hearth Furnace A Coal Based DRI and Molten Metal Process for Long Range Replacement of Blast Furnaces and Coke Ovens The U. S. steel industry has reduced its energy intensity per ton of steel shipped by 33% since 1990. However, further signifcant gains in energy effciency will require the development of new, transformational iron and steelmaking processes. The Paired Straight Hearth Furnace (PSH) process is an emerging alterna- tive high productivity, direct reduced iron (DRI)

  2. Methods for reduction of charging emissions

    SciTech Connect (OSTI)

    Schuecker, F.J.; Schulte, H.

    1997-12-31

    One of the most critical subjects in coking plants are charging emissions. The paper reviews the systems that have been used over the years to reduce charging emissions. The advantages and disadvantages are summarized for the following systems: Double collecting main with aspiration on both oven sides; Single collecting main with/without aspiration via standpipe, and extraction and cleaning of charging gas on charging car; Single collecting main with aspiration via standpipe and pretreatment of charging gas on the charging car as well as additional stationary exhaust and cleaning of charging gas; Single collecting main with aspiration via single standpipe; and Single collecting main with simultaneous aspiration via two standpipes and a U-tube connecting the oven chamber with the neighboring oven. The paper then briefly discusses prerequisites for reduction of charging emissions.

  3. Alkali-metal/alkaline-earth-metal fluorine beryllium borate NaSr{sub 3}Be{sub 3}B{sub 3}O{sub 9}F{sub 4} with large nonlinear optical properties in the deep-ultraviolet region

    SciTech Connect (OSTI)

    Reshak, A. H.; Huang, Hongwei; Kamarudin, H.; Auluck, S.

    2015-02-28

    The linear optical response and second harmonic generation (SHG) in alkali-metal/alkaline-earth-metal fluorine beryllium borate NaSr{sub 3}Be{sub 3}B{sub 3}O{sub 9}F{sub 4} are investigated by means of density functional theory. Calculations are performed using four types of exchange correlations: Ceperley-Alder local density approximation, Perdew Burke and Ernzerhof general gradient approximation, Engel-Vosko generalized gradient approximation, and the recently modified Becke-Johnson potential (mBJ). The mBJ approach brings the calculated band gap (7.20?eV) in excellent agreement with the experimental one (7.28?eV). The calculated values of the uniaxial anisotropy ??=?0.076 and the birefringence ?n(0)=0.052 indicate considerable anisotropy in the linear optical properties, which makes it favorable for the second harmonic generation. The dominant component of the second harmonic generation is ?{sub 111}{sup (2)}(?). The value of |?{sub 111}{sup (2)}(?)| is about 1.2?pm/V at ??=?1064?nm in agreement with previous calculations. To analyze the origin of the high SHG of NaSr{sub 3}Be{sub 3}B{sub 3}O{sub 9}F{sub 4} single crystals, we have correlated the features of |?{sub 111}{sup (2)}(?)| spectra with the features of ?{sub 2}(?) spectra as a function of ?/2 and ?. From the calculated dominant component |?{sub 111}{sup (2)}(?)|, we find that the microscopic first hyperpolarizability, ?{sub 111}, the vector components along the dipole moment direction is 0.5??10{sup ?30} esu at static limit and 0.6??10{sup ?30} esu at ??=?1064?nm.

  4. Trials with a 100% pellet burden in blast furnace No. 6 at Hoogovens IJmuiden

    SciTech Connect (OSTI)

    Schoone, E.; Toxopeus, H.; Vos, D.

    1995-12-01

    The burden consists of 50% high basicity sinter and 50% home made olivine pellets. Two coke oven plants produce the required coke, about 340 kg/t (680 lb/NT). The average pulverized coal injection rate is 150 kg/t (300 lb/NT). To anticipate the aging coke oven plant No. 2 the coal injection capacity will e increased by 50% in 1996, by the installation of a third coal grinding line. In the Netherlands environmental issues have a high impact on further developments. In particular the environmental regulations require a significant decrease of dust, SO{sub 2} and dioxins emitted by the sinter plant. The appropriate measures must be concluded in the second part of this decade. To avoid costly conventional solutions Hoogovens has been testing since April, 1994 the Emission Optimized Sintering (EOS). In case of failure of EOS, the situation of a (partially) closed sinter plant was tested. Purchased pellets replaced sinter, leading to a 100% pellet and an 80% pellet/20% sinter trial. The trials were executed in the first half of 1994 at blast furnace No. 6, equipped with a PW-bell less top. Results are described.

  5. Examination of Beryllium Under Intense High Energy Proton Beam...

    Office of Scientific and Technical Information (OSTI)

    Contract Number: AC02-07CH11359 Resource Type: Conference Resource Relation: Conference: 6th International Particle Accelerator Conference. Richmond, Virginia, USA, 3-8 May 2015....

  6. Beryllium-7 Implantation in Plastics for Prosthesis Wear Studies...

    Office of Science (SC) Website

    Here the traditional wear determination via mass loss is imprecise due to the liquid soak. Also, the long test times usually do not allow sufficient resolution to test the impact ...

  7. CX-00077_CHPRC Beryllium Site Sampling.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  8. 2012_0112_BerylliumStatistics_Attachment7.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  9. ORISE: Beryllium Awareness for Employees and Families (Video)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transcript (MS-Word)

  10. Hanford Site Chronic Beryllium Disease Prevention Program (CBDPP...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advocate Domina, Kirk 376-3723 948-9763 Stoner, Mike 373-7587 713-4513 HPMC OMS Holland, Nic 376-1085 (406) 544-4502 Cowley, Dana Phillips MD, Karen 372-0015 376-4716 (509)...

  11. ORISE: Worker Health Studies - Beryllium Exposure Studies and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CBD leads to the development of small, inflammatory nodules in the lungs called granulomas, which reduce the ability of the lungs to process gases and cause the patient to cough ...

  12. Title 10 CFR Part 850, Chronic Beryllium Disease Prevention Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Frequently reported symptoms include one or more of the following: dyspnea (shortness of breath) on exertion, cough, fever, night sweats, and chest pain and, less frequently, ...

  13. Hanford Site Beryllium Work Permit (BWP) and Hazard Assessment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Page 1 of 1 Change Summary Rev Date Changed Change Details 1A May 6, 2013 Minor editorial change: added instructions back for Step 20 of Section 5.3.2, inadvertently left out...

  14. Hanford Site Beryllium Posting and Labeling Requirements Procedure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DateSection Changed Change Details 1 31913, Misc. changes as listed Minor editorial changes throughout. 1.0, added callout to Attachment 1. 5.2, directed reader to...

  15. Beryllium-Associated Worker Registry Data Collection and Management...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... operation, maintenance, or decommissioning, and which may involve one DOE ... by site) DOE-STD-1187-2007 8 3. *Status Code N New record, D Delete record 4. ...

  16. Hanford Site Evaluation of Electrical Equipment for Beryllium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... event that requires maintenance on electrical equipment to correct a safety issue or restore power to a facility. ... the risk of catastrophic failure andor unplanned outages. ...

  17. General Resources - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beryllium Program General Resources About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources General Resources Email Email Page | Print Print Page

  18. Medical Testing and Surveillance Facilities - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanford Site Wide Programs Beryllium Program Medical Testing and Surveillance Facilities About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources

  19. Hot metal Si control at Kwangyang blast furnaces

    SciTech Connect (OSTI)

    Hur, N.S.; Cho, B.R.; Kim, G.Y.; Choi, J.S.; Kim, B.H.

    1995-12-01

    Studies of Si transfer in blast furnaces have shown that the Si level in pig iron is influenced more by the reaction of silicon oxide gas generation in the raceway than the chemical reaction between hot metal and slag at the drop zone. Specifications require a Si content of pig iron below 0.15% at the Kwangyang Works, but the use of soft coking coal in the blend for coke ovens, high pulverized coal injection rate into the blast furnace, and the application of lower grade iron ore has resulted in the need to develop methods to control Si in hot metal. In this paper, the results of in furnace Si control and the desiliconization skills at the casthouse floor are described.

  20. Hanford CBDPP Committee - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanford CBDPP Committee About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources Hanford CBDPP Committee Email Email Page | Print Print Page |Text

  1. Process safety management (OSHA) and process risk management (CAA) application. Application to a coke plant

    SciTech Connect (OSTI)

    Graeser, W.C.; Mentzer, W.P.

    1995-12-01

    Risk Management Programs for Chemical Accidental Release Prevention is the name of the proposed rule for the RMP Risk Management Program. The RMP was written in response to several catastrophic releases of hazardous substances. The rule is applicable to facilities that store, process or use greater than threshold quantities of 62 listed flammable chemicals and another 100 listed toxic substances. Additionally, a Risk Management Plan is registered with the EPA, Chemical Safety and Hazardous Investigation Board, state governments and the local emergency planning commission. The Clean Air Act Amendments of 1990 (specifically Section 112r) required the EPA to develop a three phase Risk Management Plan for industry: prevention program; hazard assessment; and emergency response program. The Prevention Program closely follows the OSHA`s Process Safety Management Standard. The Hazard Assessment section requires facilities to develop plans for a worst case scenario. The Emergency Response section defines the steps the facility and each employee will take if a release occurs. This section also needs to be coordinated with the Local Emergency Planning Commission. These regulations are described using Clairton Works as an example of compliance.

  2. AB INITIO STUDIES OF COKE FORMATION ON NI CATALYSTS DURING METHANE REFORMING

    SciTech Connect (OSTI)

    David S. Sholl

    2004-09-25

    The atomic-scale processes that control the formation of carbon deposits on Ni catalysts in reforming applications are poorly understood. Ab initio Density Functional Theory calculations have been used to examine several key elementary steps in the complex network of chemical reactions that precedes carbon formation on practical catalysts. Attention has been focused on the disproportionation of CO. A comparative study of this reaction on flat and stepped crystal planes of Ni has provided the first direct evidence that surface carbon formation is driven by elementary reactions occurring at defect sites on Ni catalysts. The adsorption and diffusion of atomic H on several flat and stepped Ni surfaces has also been characterized experimentally.

  3. Ab Initio Studies of Coke Formation on Ni Catalysts During Methane Reforming

    SciTech Connect (OSTI)

    David S. Sholl

    2006-03-05

    The atomic-scale processes that control the formation of carbon deposits on Ni catalysts in reforming applications are poorly understood. Ab initio Density Functional Theory calculations have been used to examine several key elementary steps in the complex network of chemical reactions that precedes carbon formation on practical catalysts. Attention has been focused on the disproportionation of CO. A comparative study of this reaction on flat and stepped crystal planes of Ni has provided the first direct evidence that surface carbon formation is driven by elementary reactions occurring at defect sites on Ni catalysts. The adsorption and diffusion of atomic H on several flat and stepped Ni surfaces has also been characterized experimentally.

  4. AB INITIO STUDIES OF COKE FORMATION ON NI CATALYSTS DURING METHANE REFORMING

    SciTech Connect (OSTI)

    David S. Sholl

    2003-09-25

    The atomic-scale processes that control the formation of carbon deposits on Ni catalysts in reforming applications are poorly understood. Ab initio Density Functional Theory calculations have been used to examine several key elementary steps in the complex network of chemical reactions that precedes carbon formation on practical catalysts. Attention has been focused on the disproportionation of CO. A comparative study of this reaction on flat and stepped crystal planes of Ni has provided the first direct evidence that surface carbon formation is driven by elementary reactions occurring at defect sites on Ni catalysts.

  5. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot Kennel; Chong Chen; Dady Dadyburjor; Mark Heavner; Manoj Katakdaunde; Liviu Magean; James Mayberry; Alfred Stiller; Joseph Stoffa; Christopher Yurchick; John Zondlo

    2009-12-31

    This NETL sponsored effort seeks to develop continuous technologies for the production of carbon products, which may be thought of as the heavier products currently produced from refining of crude petroleum and coal tars obtained from metallurgical grade coke ovens. This effort took binder grade pitch, produced from liquefaction of West Virginia bituminous grade coal, all the way to commercial demonstration in a state of the art arc furnace. Other products, such as crude oil, anode grade coke and metallurgical grade coke were demonstrated successfully at the bench scale. The technology developed herein diverged from the previous state of the art in direct liquefaction (also referred to as the Bergius process), in two major respects. First, direct liquefaction was accomplished with less than a percent of hydrogen per unit mass of product, or about 3 pound per barrel or less. By contrast, other variants of the Bergius process require the use of 15 pounds or more of hydrogen per barrel, resulting in an inherent materials cost. Second, the conventional Bergius process requires high pressure, in the range of 1500 psig to 3000 psig. The WVU process variant has been carried out at pressures below 400 psig, a significant difference. Thanks mainly to DOE sponsorship, the WVU process has been licensed to a Canadian Company, Quantex Energy Inc, with a commercial demonstration unit plant scheduled to be erected in 2011.

  6. Part 2: Performance of the THERMOSELECT{reg_sign} plant at Fondotoce, Italy: Product quality and distribution of chemical elements in the material flow

    SciTech Connect (OSTI)

    Stahlberg, R.

    1996-12-31

    Results of an extended and complete investigation period at the Thermoselect{reg_sign} solid waste demonstration plant in Fondotoce, Italy, will be discussed. The demonstration plant is an in-line process for commingled wastes combining a compression step, coking oven, and high temperature gasification using oxygen to achieve total decomposition of solid waste and simultaneous production of pollutant-free energy rich synthesis gas, inert and non-toxic vitrified mineral product, and the recovery of metals from the solid wastes. The process air emissions are by a significant margin below the current European and proposed USEPA, NSPS emission standards for MWCs. All processing water and that from the solid waste is recovered, cleaned in-house and reused by the process.

  7. Operating experience with 100% pellet burden on Amanda blast furnace

    SciTech Connect (OSTI)

    Keaton, D.E.; Minakawa, T. . Ironmaking Dept.)

    1993-01-01

    A number of significant changes in operations at the Ashland Works of the Armco Steel Company occurred in 1992 which directly impacted the Amanda Blast Furnace operation. These changes included the shutdown of the hot strip mill which resulted in coke oven gas enrichment of the Amanda stoves and an increase of 75 C in hot blast temperature, transition to 100% continuous cast operation which resulted in increased variation of the hot metal demand, and the July idling of the sinter plant. Historically, the Amanda Blast Furnace burden was 30% fluxed sinter and 70% acid pellet. It was anticipated that the change to 100% pellet burden would require changes in charging practice and alter furnace performance. The paper gives a general furnace description and then describes the burden characteristics, operating practice with 30% sinter/70% acid pellet burden, preparations for the 100% acid pellet burden operation, the 100% acid pellet operation, and the 100% fluxed pellet burden operation.

  8. Analysis of ammonium sulfate circulation tank failure -- Possible causes and their remediation

    SciTech Connect (OSTI)

    O`Hearn, R.J.

    1997-12-31

    Acme steel manufactures a liquid solution of ammonium sulphate by scrubbing the coke oven gas with a dilute solution of sulphuric acid. When the bath reaches a predetermined specific gravity, it is isolated from the system, neutralized with aqua ammonia, pumped to the shipping tanks, re-charged with water and acid, then placed back in service. To improve the ammonia removal efficiency, three circulation tanks are used in this system. In June 1996, the volume of two of the sulfate solution tanks in the ammonia removal plant were increased by two different pressure events. The first tank was damaged by pressure that was not relieved due to a plugged vent line. The second tank was damaged by a pressure event generated during the process of making ammonium sulfate. This paper will discuss the cause of the second tank`s failure, and the design solution to restart the operation of the plant.

  9. Wastewater treatment with biomass carriers made from steelmaking by-product

    SciTech Connect (OSTI)

    Aritome, Kiyoshi; Miki, Osamu; Okuno, Yoshio

    1995-07-01

    It is economical to use microorganisms in wastewater treatment. In steelmaking, ammonia liquor from coke-oven plant, for example, is treated using microorganisms. To treat wastewater efficiently in biological processes, the following conditions are necessary: appropriate conditions for activities of microorganisms; proper concentration of microorganisms in reactor; effective contact of wastewater and microorganisms; and reliable separation of treated wastewater and microorganisms. Three types of biomass carriers made from granulated slag to satisfy these conditions have been developed. Research efforts have been under way to apply these carriers in reduction of COD (chemical oxygen demand) in wastewater. Developed biomass carriers can reduce the volume of COD oxidation reactor and promise easy operation compared with the conventional activated sludge processes. This result has been substantialized in sewage treatment facilities, factory wastewater treatment facilities and deodorization facilities. For the future, nitrate reduction in stainless pickling wastewater with fixed-bed biomass carriers will be also investigated.

  10. AISI direct steelmaking program

    SciTech Connect (OSTI)

    Aukrust, E.

    1991-01-09

    AISI with co-funding from DOE has initiated a research and development program aimed at the development of a new process for direct steelmaking, and the program is discussed in this document. The project is expected to cost about $30 million over a three-year period, with the government providing approximately 77 percent of the funds and AISI the balance. In contrast to current steelmaking processes which are largely open and batch, the direct steelmaking process would be closed and continuous. Further, it would use coal directly, thereby avoiding the need for coke ovens. The second year of the Direct Steelmaking Program (November 29, 1989, through November 28, 1990) was a year of significant accomplishment. The various research programs proceeded essentially on schedule and the pilot plant, the centerpiece of the program, was completed about three months behind schedule but began operation in almost a picture-perfect manner. This report presents the last years accomplishments.

  11. DEVELOPMENT OF DEPOSIT DETECTION SYSTEM IN PIPELINES OF THE STEELWORKS USING CS-137 GAMMA-RAY

    SciTech Connect (OSTI)

    Song, Won-Joon; Lee, Seung-Hee; Jeong, Hee-Dong

    2008-02-28

    The deposit is built up in the pipeline of the steelworks by the chemical reaction among COG (coke oven gas), BFG (blast furnace gas), moisture, and steel in the high temperature environment and obstructs the smooth gas flow. In this study a gamma-ray system is developed to detect the deposit accumulated in pipelines and calculate the accumulation rate with respect to the cross section area of pipes. Cs-137 is used as the gamma-ray source and the system is designed to apply to pipes of various diameters. This system also includes the DB for storage and display of the measurement results so that it can be used for the efficient management of the pipelines.

  12. Chronic disease and early exposure to air-borne mixtures. 2. Exposure assessment

    SciTech Connect (OSTI)

    James Argo

    2007-10-15

    This work is part of a larger study of the impact of early exposure to releases from industry on the etiology of cancer. Releases from all kraft and sulfite mills, coke ovens, oil refineries, copper, nickel, and lead/zinc smelters operating in Canada during the exposure period of 1967-1970 have been determined. All plumes have been expressed in g BaP eq/d using the RASH methodology. The releases have been divided into process, boiler fuel, dioxin, and SO{sub 2} emissions. Combustion sources have been defined with FIREv6.23. Dioxin congenors are expected in all source types when the boiler fuel is heavy fuel oil, wood or wood bark, or coal. All about 90 communities examined have an inverted sex ratio. 53 refs., 2 figs., 4 tabs.

  13. On the possibility of using uranium-beryllium oxide fuel in a VVER reactor

    SciTech Connect (OSTI)

    Kovalishin, A. A.; Prosyolkov, V. N.; Sidorenko, V. D.; Stogov, Yu. V.

    2014-12-15

    The possibility of using UO{sub 2}-BeO fuel in a VVER reactor is considered with allowance for the thermophysical properties of this fuel. Neutron characteristics of VVER fuel assemblies with UO{sub 2}-BeO fuel pellets are estimated.

  14. Update on the Hanford Site Chronic Beryllium Disease Prevention Program (CBDPP)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 18, 2015 Be Corrective Action Plan (CAP) * Be CAP was approved by DOE-HQ in September 2010 * CAP supplement addressing new consensus process and high-priority Phase 1 products was approved by DOE Office of Environmental Management (DOE-EM) in September 2011 * CAP supplement addressing lower priority Phase 2 and Phase 3 products was approved by DOE-EM on March 13, 2012 Be CAP Status * DOE HQ Enterprise Assessment review March 2015, awaiting final report, no findings, 3 Opportunities for

  15. First principles electronic band structure and phonon dispersion curves for zinc blend beryllium chalcogenide

    SciTech Connect (OSTI)

    Dabhi, Shweta Mankad, Venu Jha, Prafulla K.

    2014-04-24

    A detailed theoretical study of structural, electronic and Vibrational properties of BeX compound is presented by performing ab-initio calculations based on density-functional theory using the Espresso package. The calculated value of lattice constant and bulk modulus are compared with the available experimental and other theoretical data and agree reasonably well. BeX (X = S,Se,Te) compounds in the ZB phase are indirect wide band gap semiconductors with an ionic contribution. The phonon dispersion curves are represented which shows that these compounds are dynamically stable in ZB phase.

  16. Final Report: No{sub x} Emissions from By Product Fuel Combustion in Steel Making, September 15, 1996 - October 15, 1999

    SciTech Connect (OSTI)

    Pershing, David W.; Lighty, JoAnn S.; Eddings, Eric G.; Cacciatore, David A.

    1999-01-28

    Exhaust gases from the primary operations in the steel making process are almost exclusively utilized as supplemental fuels within the steel plant. These by-product fuels include blast furnace gas (BFG) and coke oven gas (COG) which contain mixtures of H{sub 2}, CO, CH{sub 4} and trace amounts of some heavier hydrocarbons and the impurities NH{sub 3} and HCN. These fuels are burned alone or in combination with natural gas to fire the coke ovens, blast furnace stoves utility boilers and metal working furnaces. The utilization of these by-product fuels reduces the waste gas emissions at the steel mill and reduces the requirements for outside fuel sources. However, as with primary fuel sources, the combustion of these by-product fuel blends does produce hazardous pollutants, in particular nitrogen oxides, and because these are atypical fuel blends of varying composition, the pollutant formation is not well understood. The objective of this research was to develop an understanding of the mechanisms controlling NO{sub x} formation from the combustion of by-product fuels from the steel industry and investigate control and design options to minimize emissions. The minimization strategies investigated were constrained by limits on CO and hydrocarbon emissions, both of which increased under fuel-rich combustion scenarios that resulted in reduced NO{sub x} emissions. Also, the minimization strategies were constrained by the need for reasonable heat generation rates in the furnaces that employ these by-product fuels, so that product steel quality is not adversely affected.

  17. Coals and coal requirements for the COREX process

    SciTech Connect (OSTI)

    Heckmann, H.

    1996-12-31

    The utilization of non met coals for production of liquid hot metal was the motivation for the development of the COREX Process by VAI/DVAI during the 70`s. Like the conventional ironmaking route (coke oven/blast furnace) it is based on coal as source of energy and reduction medium. However, in difference to blast furnace, coal can be used directly without the necessary prestep of cokemaking. Coking ability of coals therefore is no prerequisite of suitability. Meanwhile the COREX Process is on its way to become established in ironmaking industry. COREX Plants at ISCOR, Pretoria/South Africa and POSCO Pohang/Korea, being in operation and those which will be started up during the next years comprise already an annual coal consumption capacity of approx. 5 Mio. tonnes mtr., which is a magnitude attracting the interest of industrial coal suppliers. The increasing importance of COREX as a comparable new technology forms also a demand for information regarding process requirements for raw material, especially coal, which is intended to be met here.

  18. Planning for the 400,000 tons/year AISI ironmaking demonstration plant

    SciTech Connect (OSTI)

    Aukrust, E. . AISI Direct Steelmaking Program)

    1993-01-01

    The American Iron and Steel Institute (AISI) has formulated a four-year program to design, construct, and operate a 400,000 net ton per year ironmaking demonstration plant. The plant will employ the coal-based ironmaking process developed under a 1989 cooperative agreement with DOE. AISI will manage the design and construction to be completed in the first two years and operate the plant for the second two years with a variety or ores, coals, and fluxes. Campaigns of increasing length are planned to optimize operations. After successful operation, the plant will be taken over by the host company. Results of studies to date indicate that, on a commercial scale, the AISI process will use 27% less energy and have variable operating costs $10 per ton lower and capital costs of $160 per annual ton, compared to the $250 per annual ton rebuild cost for the coke oven-blast furnace process it will replace. The process will enable the domestic steel industry to become more competitive by reducing its capital and operating cost. Furthermore, by eliminating the pollution problems associated with coke production and by completely enclosing the smelting reactions, this process represents a major step towards an environmentally friendly steel industry.

  19. Co-production of electricity and alternate fuels from coal. Final report, August 1995

    SciTech Connect (OSTI)

    1995-12-31

    The Calderon process and its process development unit, PDU, were originally conceived to produce two useful products from a bituminous coal: a desulfurized medium BTU gas containing primarily CO, H{sub 2}, CH{sub 4}, CO{sub 2}, and H{sub 2}O; and a desulfurized low BTU gas containing these same constituents plus N{sub 2} from the air used to provide heat for the process through the combustion of a portion of the fuel. The process was viewed as a means for providing both a synthesis gas for liquid fuel production (perhaps CH{sub 3}OH, alternatively CH{sub 4} or NH{sub 3}) and a pressurized, low BTU fuel gas, for gas turbine based power generation. The Calderon coal process comprises three principle sections which perform the following functions: coal pyrolysis in a continuous, steady flow unit based on coke oven technology; air blown, slagging, coke gasification in a moving bed unit based on a blast furnace technology; and a novel, lime pebble based, product gas processing in which a variety of functions are accomplished including the cracking of hydrocarbons and the removal of sulfur, H{sub 2}S, and of particulates from both the medium and low BTU gases. The product gas processing unit, based on multiple moving beds, has also been conceived to regenerate the lime pebbles and recover sulfur as elemental S.

  20. Addendum to industrial market assessment of the products of mild gasification

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The objective of this report is to review and update the 1988 report by J. E. Sinor Consultants Inc., ``Industrial Market Assessment of the Products of Mild Gasification, and to more fully present market opportunities for two char-based products from the mild gasification process (MGP): Formcoke for the iron and steel industry, and activated carbon for wastewater cleanup and flue gas scrubbing. Please refer to the original report for additional details. In the past, coal conversion projects have and liquids produced, and the value of the residual char was limited to its fuel value. Some projects had limited success until gas and oil competition overwhelmed them. The strategy adopted for this assessment is to seek first a premium value for the char in a market that has advantages over gas and oil, and then to find the highest values possible for gases, liquids, and tars, either on-site or sold into existing markets. During the intervening years since the 1988 report, there have been many changes in the national economy, industrial production, international competition, and environmental regulations. The Clean Air Act Amendments of 1990 (CAAA) will have a large impact on industry. There is considerable uncertainty about how the Act will be implemented, but it specifically addresses coke-oven batteries. This may encourage industry to consider formcoke produced via mild gasification as a low-pollution substitute for conventional coke. The chemistry and technology of coke making steel were reviewed in the 1988 market assessment and will not be repeated here. The CAAA require additional pollution control measures for most industrial facilities, but this creates new opportunities for the mild gasification process.

  1. Addendum to industrial market assessment of the products of mild gasification

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The objective of this report is to review and update the 1988 report by J. E. Sinor Consultants Inc., Industrial Market Assessment of the Products of Mild Gasification, and to more fully present market opportunities for two char-based products from the mild gasification process (MGP): Formcoke for the iron and steel industry, and activated carbon for wastewater cleanup and flue gas scrubbing. Please refer to the original report for additional details. In the past, coal conversion projects have and liquids produced, and the value of the residual char was limited to its fuel value. Some projects had limited success until gas and oil competition overwhelmed them. The strategy adopted for this assessment is to seek first a premium value for the char in a market that has advantages over gas and oil, and then to find the highest values possible for gases, liquids, and tars, either on-site or sold into existing markets. During the intervening years since the 1988 report, there have been many changes in the national economy, industrial production, international competition, and environmental regulations. The Clean Air Act Amendments of 1990 (CAAA) will have a large impact on industry. There is considerable uncertainty about how the Act will be implemented, but it specifically addresses coke-oven batteries. This may encourage industry to consider formcoke produced via mild gasification as a low-pollution substitute for conventional coke. The chemistry and technology of coke making steel were reviewed in the 1988 market assessment and will not be repeated here. The CAAA require additional pollution control measures for most industrial facilities, but this creates new opportunities for the mild gasification process.

  2. Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency; Industrial Technologies Program (ITP) Process Heating Tip Sheet #11 (Fact Sheet)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    heating applications involving flammable solvent removal use large amounts of energy to maintain safe lower flammable limits (LFL) in the exhaust air. National Fire Protection Association (NFPA) guidelines require the removal of significant amounts of exhaust air to maintain a safe, low-vapor solvent concentration. If LFL monitoring equipment is used to ensure proper vapor concentrations, these guidelines allow for less exhaust air removal. LFL monitoring equipment can improve the efficiency of

  3. Technical support document: Energy efficiency standards for consumer products: Room air conditioners, water heaters, direct heating equipment, mobile home furnaces, kitchen ranges and ovens, pool heaters, fluorescent lamp ballasts and television sets. Volume 2, Fluorescent lamp ballasts, television sets, room air conditioners, and kitchen ranges and ovens

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    This document is divided into ``volumes`` B through E, dealing with individual classes of consumer products. Chapters in each present engineering analysis, base case forecasts, projected national impacts of standards, life-cycle costs and payback periods, impacts on manufacturers, impacts of standards on electric utilities, and environmental effects. Supporting appendices are included.

  4. File

    U.S. Energy Information Administration (EIA) Indexed Site

    Coke Plant","Truck",87126 2013,1,"Alabama","Alabama","Industrial Plants Excluding Coke","Truck",267108 2013,1,"Alabama","Indiana","Coke Plant","Railroad",164223 ...

  5. Utilization of Process Off-Gas as a Fuel for Improved Energy Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination ADVANCED MANUFACTURING OFFICE Utilization of Process Off-Gas as a Fuel for Improved Energy Efficiency Introduction Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the aluminum industry, where it is used to produce carbon anodes for aluminum production. Calcined coke is also

  6. --No Title--

    U.S. Energy Information Administration (EIA) Indexed Site

    Consumer AG Agriculture, Mining and Construction CP Coke Plant EG Electric Generation EX Export Coal MF Manufacturing (Except Coke Plants) NC Not a Consumer RC Residential...

  7. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    Coast (PADD 3) Petroleum Coke Consumed at Refineries (Thousand Barrels)","Rocky Mountain (PADD 4) Petroleum Coke Consumed at Refineries (Thousand Barrels)","West...

  8. U.S. Energy Information Administration | Annual Coal Distribution...

    Gasoline and Diesel Fuel Update (EIA)

    short tons) Coal Origin State Transportation Mode Electric Power Sector Coke Plants Industrial Plants (excluding Coke) Commercial & Institutional Total Alabama Total 6,085 670...

  9. U.S. Energy Information Administration | Annual Coal Distribution...

    Gasoline and Diesel Fuel Update (EIA)

    tons) Coal Destination State Transportation Mode Electric Power Sector Coke Plants Industrial Plants (excluding Coke) Commercial & Institutional Total Alabama Total 6,982 679...

  10. U.S. Energy Information Administration | Annual Coal Distribution...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (thousand short tons) Coal Origin State Transportation Mode Electric Power Sector Coke Plants Industrial Plants (excluding Coke) Commercial & Institutional Total Alabama Total...

  11. U.S. Energy Information Administration | Annual Coal Distribution...

    Gasoline and Diesel Fuel Update (EIA)

    short tons) Coal Destination State Transportation Mode Electric Power Sector Coke Plants Industrial Plants (excluding Coke) Commercial & Institutional Total Alabama Total...

  12. By Coal Destination State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    California (thousand short tons) Coal Origin State Transportation Mode Electric Power Sector Coke Plants Industrial Plants (excluding Coke) Commercial & Institutional Total...

  13. File

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Plants Excluding Coke","Railroad",14493 2013,1,"Alabama","Alabama","Industrial Plants Excluding Coke","Truck",267108 2013,1,"Alabama","Colorado","Electric Power ...

  14. o_al_05.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Destination by Method of Transportation Electricity Generation Coke Plants Industrial Plants (Except Coke) Residential and Commercial Total Alabama 770 851 1,739 * 3,360 Railroad...

  15. Building Number/Name: Date prepared: Responsible Contractor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    22-S February 2, 2012 WRPS C M Smith; E A Hill PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: LIQUID matrix Period of beryllium operations (dates): (1) ...

  16. Building Number/Name: Date prepared: Responsible Contractor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WA February 7, 2012 WRPS C M Smith; E A Hill PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: Early 1980s ...

  17. Building Number/Name: Date prepared: Responsible Contractor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    07-SX Jan 29, 2012 WRPS C M Smith; E A Hill PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: Early 1980s ...

  18. Building Number/Name: Date prepared: Responsible Contractor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-AW Feb 10,2012 WRPS C M Smith; E A Hill PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: Early 1980s ...

  19. Building Number/Name: Date prepared: Responsible Contractor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    S Feb 10, 2012 WRPS C M Smith; E A Hill PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: Early 1980s End: ...

  20. Building Number/Name: Date prepared: Responsible Contractor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    101-HV Feb 8 201 WRPS C M Smith; E A Hill PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: Early 1980s ...

  1. Building Number/Name: Date prepared: Responsible Contractor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3-E Jan 28, 2012 WRPS C M Smith; E A Hill PAST OPERATIONS Beryllium brought in facility: YES Form of beryllium: SOLID Period of beryllium operations (dates): Start: Early 1980s ...

  2. Audit Report: DOE/IG-0851 | Department of Energy

    Energy Savers [EERE]

    1 Audit Report: DOE/IG-0851 June 17, 2011 Implementation of Beryllium Controls at Lawrence Livermore National Laboratory The Department of Energy has a long history of using beryllium - a metal essential for nuclear operations and other processes. Exposure to beryllium can cause beryllium sensitization or even Chronic Beryllium Disease, an often debilitating, and sometimes fatal, lung condition. In December 1999, the Department established a Chronic Beryllium Disease Prevention Program

  3. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Green Fuel This activity allows students the opportunity to explore different methods for...

  4. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    this staightforward lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0...

  5. EA-1662: Final Environmental Assessment

    Broader source: Energy.gov [DOE]

    10 CFR Part 430 Energy Conservation Program: EnergyConservation Standards for Certain Consumer Products (Dishwashers, Dehumidifiers, Microwave Ovens, and Electric and Gas Kitchen Ranges and Ovens)

  6. ISSUANCE 2015-06-18: Energy Conservation Program: Test Procedures...

    Energy Savers [EERE]

    18: Energy Conservation Program: Test Procedures for Conventional Ovens, Final Rule ISSUANCE 2015-06-18: Energy Conservation Program: Test Procedures for Conventional Ovens, Final ...

  7. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Sources Science & Innovation Search results Search results Enter terms Search Showing 31 - 40 of 36 results. Download Making a Solar Oven Students make solar ovens....

  8. Momentum-Savings-Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Residential Room Air Conditioning Residential Ceiling Fan Light Kits Electric Clothes Dryers Electric Cooktops Electric Ovens Residential Furnace Fans Microwave Ovens...

  9. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Energy From the Sun (10 activities) Hands-on explorations to teach intermediate students...

  10. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Alternative Fuels...

  11. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Geothermal Energy:...

  12. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Energy in Today's Global Society Energy is an abstract concept that is very familiar to...

  13. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Energy Production...

  14. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Check out this staightforward lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-...

  15. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Protect Your Climate Curriculum and Training Request projects here....

  16. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    this staightforward lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download...

  17. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Search results Search results Enter terms Search Showing 121 - 130 of 189 results. Download Making a Solar Oven Students make solar ovens. Student background information is...

  18. Use Lower Flammable Limit Monitoring Equipment to Improve Process...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency This process heating ...

  19. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Box Solar Oven Check out this staightforward lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloads...

  20. Former Worker Medical Screening Program Related Documents & Links...

    Office of Environmental Management (EM)

    Related Documents & Links Related Documents & Links Beryllium Information-ORISE Chronic Beryllium Disease Information-National Jewish Health Department of Energy Human...

  1. Former Workers Medical Facilities with Experience Evaluating...

    Energy Savers [EERE]

    Former Workers Medical Facilities with Experience Evaluating Chronic Beryllium Disease Former Workers Medical Facilities with Experience Evaluating Chronic Beryllium Disease April...

  2. Enforcement Letter, WEL-2013-01- May 29, 2013

    Broader source: Energy.gov [DOE]

    Issued to Los Alamos National Security, LLC, related to Worker Beryllium Exposure during Machining at the Los Alamos National Laboratory's Beryllium Technology Facility

  3. Audit Report: IG-0583 | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    7, 2003 Management of Beryllium Metal Supply The Department of Energy (Department) uses beryllium metal to fabricate weapons components and to facilitate a number of weaponsrelated...

  4. BeryllFactShts12-7-01

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... WHAT ARE THE SYMPTOMS OF CHRONIC BERYLLIUM DISEASE? * Symptoms of Chronic Beryllium Disease include: - Shortness of Breath, especially with activity - Cough - Chest Pain - Fatigue ...

  5. DOE F 440.1 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon 10 CFR PART 850 - APPENDIX A CHRONIC BERYLLIUM DISEASE PREVENTION PROGRAM INFORMED CONSENT FORM More Documents & Publications Beryllium Screening - Informed Choice ...

  6. Enterprise Assessments Follow-up Review of the Hanford Site Chronic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review of the Hanford Site Chronic Beryllium Disease Prevention Program - June 2015 Enterprise Assessments Follow-up Review of the Hanford Site Chronic Beryllium Disease Prevention...

  7. Audit Report: IG-0726 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of beryllium disease, two of the objectives of the Chronic Beryllium Disease Prevention Program (Prevention Program). PDF icon Audit Report: IG-0726 More Documents &...

  8. Vacuum Distillation

    U.S. Energy Information Administration (EIA) Indexed Site

    Day) Process: Vacuum Distillation Thermal Cracking Thermal Cracking: Coking Thermal Cracking: Delayed Coking Thermal Cracking: Fluid Coking Thermal Cracking: Visbreaking Thermal Cracking: Other/Gas Oil Thermal Cracking: Coking (Barrels/Calendar Day) Catalytic Cracking Fresh Feed Catalytic Cracking Fresh Feed (Barrels/Calendar Day) Catalytic Cracking Recycled Feed Catalytic Hydrocracking Catalytic Hydrocracking: Distillate Catalytic Hydrocracking: Gas Oil Catalytic Hydrocracking: Residual Fuel

  9. Air toxics provisions of the Clean Air Act: Potential impacts on energy

    SciTech Connect (OSTI)

    Hootman, H.A.; Vernet, J.E.

    1991-11-01

    This report provides an overview of the provisions of the Clean Air Act and its Amendments of 1990 that identify hazardous air pollutant (HAP) emissions and addresses their regulation by the US Environmental Protection Agency (EPA). It defines the major energy sector sources of these HAPs that would be affected by the regulations. Attention is focused on regulations that would cover coke oven emissions; chromium emission from industrial cooling towers and the electroplating process; HAP emissions from tank vessels, asbestos-related activities, organic solvent use, and ethylene oxide sterilization; and emissions of air toxics from municipal waste combustors. The possible implications of Title III regulations for the coal, natural gas, petroleum, uranium, and electric utility industries are examined. The report discusses five major databases of HAP emissions: (1) TRI (EPA`s Toxic Release Inventory); (2) PISCES (Power Plant Integrated Systems: Chemical Emissions Studies developed by the Electric Power Research Institute); (3) 1985 Emissions Inventory on volatile organic compounds (used for the National Acid Precipitation Assessment Program); (4) Particulate Matter Species Manual (EPA); and (5) Toxics Emission Inventory (National Aeronautics and Space Administration). It also offers information on emission control technologies for municipal waste combustors.

  10. Air toxics provisions of the Clean Air Act: Potential impacts on energy

    SciTech Connect (OSTI)

    Hootman, H.A.; Vernet, J.E.

    1991-11-01

    This report provides an overview of the provisions of the Clean Air Act and its Amendments of 1990 that identify hazardous air pollutant (HAP) emissions and addresses their regulation by the US Environmental Protection Agency (EPA). It defines the major energy sector sources of these HAPs that would be affected by the regulations. Attention is focused on regulations that would cover coke oven emissions; chromium emission from industrial cooling towers and the electroplating process; HAP emissions from tank vessels, asbestos-related activities, organic solvent use, and ethylene oxide sterilization; and emissions of air toxics from municipal waste combustors. The possible implications of Title III regulations for the coal, natural gas, petroleum, uranium, and electric utility industries are examined. The report discusses five major databases of HAP emissions: (1) TRI (EPA's Toxic Release Inventory); (2) PISCES (Power Plant Integrated Systems: Chemical Emissions Studies developed by the Electric Power Research Institute); (3) 1985 Emissions Inventory on volatile organic compounds (used for the National Acid Precipitation Assessment Program); (4) Particulate Matter Species Manual (EPA); and (5) Toxics Emission Inventory (National Aeronautics and Space Administration). It also offers information on emission control technologies for municipal waste combustors.

  11. The start-up of the DIOS pilot plant (DIOS Project)

    SciTech Connect (OSTI)

    Sawada, Terutoshi

    1995-12-01

    The DIOS process has been successfully developed as an 8-year project commenced in April 1988. Based on the results of the element studies reported at the previous conference and at other meetings, the pilot plant, with a designed capacity of 500 t/d, was constructed and started up in october 1993. After the starting operation with the single smelting reduction furnace in the beginning of the first campaign, the pilot plant has been principally operated in integration, that is, with the smelting reduction furnace connected with the preheating and prereduction furnaces. So far five campaigns have been successfully conducted on schedule. The operation has been improved gradually and the designed performance has been achieved. New processes are targeted at the direct use of coal and iron ore fines to eliminate not only the problematic coke ovens but also pellet and sinter plants. The direct smelting reduction processes currently at the most advanced stage of development are the DIOS in Japan, the AISI in the USA and the HIsmelt in Australia.

  12. AISI Direct Steelmaking Program. Annual technical report for year ending November 30, 1991

    SciTech Connect (OSTI)

    Aukrust, A.

    1992-01-01

    The Direct Steelmaking Program has completed the third year of research and development since cost-share funding was provided by the Department of Energy. The physical chemistry programs conducted by Carnegie Mellon University (CMU) and the Massachusetts Institute of Technology (MIT) have been completed. A pilot plant has been constructed and successfully operated at Universal, Pennsylvania, and construction of a new, two-zone vessel pilot plant has been completed and trial operation is underway. The success of the pilot plant operation coupled with the development of process models involving reaction rates, heat-transfer and fluid-flow rates, and mass and energy balances has led to a basic study of a 350,000 tonne per year demonstration plant that gives promise of being a low capital and operating cost alternative for ironmaking as compared to the coke oven, blast furnace process. It has the further advantages of ease of startup and shutdown, lower energy consumption, and modularity so that capacity can be adapted to need. The physical chemistry programs at CMU and MIT studied fundamental reactions among ore, coal, flux, slag, metal droplets, and the liquid metal bath. Work at CMU centered on slag foaming studies, coal devolatilization, dissolution of hematite and wustite pellets in bath smelting slags, reduction of FeO in slag by char, extent of reverse or depostcombustion reactions in postcombustion gases, and developing an overall smelting model.

  13. AISI waste oxide recycling program. Final technical report

    SciTech Connect (OSTI)

    Aukrust, E.; Downing, K.B.; Sarma, B.

    1995-08-01

    In March 1995 AISI completed a five-year, $60 million collaborative development program on Direct Steelmaking cost-shared by DOE under the Metals Initiative. This program defined an energy-efficient and environmentally-friendly technology to produce hot metal for steelmaking directly from coal and iron ore pellets without incurring the high capital costs and environmental problems associated with traditional coke oven and blast furnace technology. As it becomes necessary to replace present capacity, this new technology will be favored because of reduced capital costs, higher energy efficiency, and lower operating costs. In April 1994, having failed to move forward with a demonstration plant for direct ironmaking, despite substantial efforts by both Stelco and Geneva Steel, an alternative opportunity was sought to commercialize this new technology without waiting until existing ironmaking capacity needed to be replaced. Recycling and resource recovery of steel plant waste oxides was considered an attractive possibility. This led to approval of a ten-month, $8.3 million joint program with DOE on recycling steel plant waste oxides utilizing this new smelting technology. This highly successful trial program was completed in December 1994. The results of the pilot plant work and a feasibility study for a recycling demonstration plant are presented in this final technical report.

  14. DEVELOPMENT AND DEMONSTRATION OF NOVEL LOW-NOx BURNERS IN THE STEEL INDUSTRY

    SciTech Connect (OSTI)

    Cygan, David

    2006-12-28

    Gas Technology Institute (GTI), together with Hamworthy Peabody Combustion Incorporated (formerly Peabody Engineering Corporation), the University of Utah, and Far West Electrochemical have developed and demonstrated an innovative combustion system suitable for natural gas and coke-oven gas firing within the steel industry. The combustion system is a simple, low-cost, energy-efficient burner that can reduce NOx by more than 75%. The U.S. steel industry needs to address NOx control at its steelmaking facilities. A significant part of NOx emissions comes from gas-fired boilers. In steel plants, byproduct gases blast furnace gas (BFG) and coke-oven gas (COG) are widely used together with natural gas to fire furnaces and boilers. In steel plants, natural gas can be fired together with BFG and COG, but, typically, the addition of natural gas raises NOx emissions, which can already be high because of residual fuel-bound nitrogen in COG. The Project Team has applied its expertise in low-NOx burners to lower NOx levels for these applications by combining advanced burner geometry and combustion staging with control strategies tailored to mixtures of natural gas and byproduct fuel gases. These methods reduce all varieties of NOx thermal NOx produced by high flame temperatures, prompt NOx produced by complex chain reactions involving radical hydrocarbon species and NOx from fuel-bound nitrogen compounds such as ammonia found in COG. The Project Team has expanded GTIs highly successful low-NOx forced internal recirculation (FIR) burner, previously developed for natural gas-fired boilers, into facilities that utilize BFG and COG. For natural gas firing, these burners have been shown to reduce NOx emissions from typical uncontrolled levels of 80-100 vppm to single-digit levels (9 vppm). This is done without the energy efficiency penalties incurred by alternative NOx control methods, such as external flue gas recirculation (FGR), water injection, and selective non-catalytic reduction. The FIR burner was previously demonstrated on firetube and watertube boilers, and these units are still operating at several industrial and commercial boiler sites in sizes ranging from 2.5 to 60 million Btu/h. This report covers the development of an innovative combustion system suitable for natural gas or coke-oven gas firing within the steel industry. The prototype FIR burner was evaluated on a 20 million Btu/h watertube boiler. Acceptable burner performance was obtained when firing natural gas and simulated coke-oven gas doped with ammonia. The laboratory data reveals a direct relationship between NOx formation and the ammonia concentration in the fuel. In addition, NOx formation increases as the primary stoichiometric ratio (PSR) increases. Representative ammonia concentrations, as documented in the steel industry, ranged from 200 to 500 vppm. When the laboratory burner/boiler was operated with 500 vppm ammonia in the fuel, NOx emissions ranged from 50 to 75 vppm. This, conservatively, is 75% less than state-of-the-art burner performance. When the burner is operated with 200 vppm ammonia in the fuel, the corresponding NOx emissions would range from 30 to 45 vppm, 84% less than present burner technology. During field evaluation on a 174 million Btu/h industrial prototype burner both natural gas and actual COG from on-site generation were tested. Despite the elevated hydrogen cyanide and ammonia content in the COG throughout the test program, the FIR burner showed an improvement over baseline emissions. At full load; 167 million Btu/h, NOx emissions were relatively low at 169 vppm. This represents a 30% reduction compared to baseline emissions not accounting for the higher hydrogen cyanide content in the COG. CO emissions remained below 20 vppm and were stable across the firing range. This represents a 68% reduction compared to baseline CO emissions. When firing natural gas, emissions were stable as firing rate increased over the range. At low fire; 45 million Btu/h, NOx emissions where 33 vppm and increased at full load; 144 million Btu

  15. U.S. Energy Information Administration | State Energy Data 2013: Prices and Expenditures

    Gasoline and Diesel Fuel Update (EIA)

    3 Coal prices are developed for the following three categories: coking coal; steam coal (all noncoking coal); and coal coke imports and exports. Coking coal, used in the industrial sector only, is a high-quality bituminous coal that is used to make coal coke. Steam coal, which may be used by all sectors, includes anthracite, bituminous coal, subbituminous coal, and lignite. In the industrial sector, coal consumption is the sum of coking coal and steam coal. The industrial coal price is the

  16. Potential trace element emissions from the gasification of Illinois...

    Office of Scientific and Technical Information (OSTI)

    GASIFICATION PLANTS; ENVIRONMENTAL EFFECTS; ABSORPTION SPECTROSCOPY; ACTIVATION ANALYSIS; AIR POLLUTION; BERYLLIUM; COAL GASIFICATION; ELEMENTS; FLOWSHEETS; FLUORESCENCE...

  17. DOE-SPEC-1142-2001

    Broader source: Energy.gov [DOE]

    Beryllium Lymphocyte Proliferation Testing This specification is for beryllium lymphocyte proliferation tests (BeLPT) used for detecting an individual’s sensitivity to beryllium and for clinical evaluation and diagnosis of patients for chronic beryllium disease. This specification should be used in all contracts with laboratories for the purchase of BeLPT Services.

  18. Checklist for Individuals with an Abnormal BeLPT

    Broader source: Energy.gov [DOE]

    This checklist is to assist individuals who have received an abnormal Beryllium Lymphocyte Proliferation Test.

  19. Method of making crack-free zirconium hydride

    DOE Patents [OSTI]

    Sullivan, Richard W. (Denver, CO)

    1980-01-01

    Crack-free hydrides of zirconium and zirconium-uranium alloys are produced by alloying the zirconium or zirconium-uranium alloy with beryllium, or nickel, or beryllium and scandium, or nickel and scandium, or beryllium and nickel, or beryllium, nickel and scandium and thereafter hydriding.

  20. ISSUANCE 2015-06-18: Energy Conservation Program: Test Procedures for

    Office of Environmental Management (EM)

    Conventional Ovens, Final Rule | Department of Energy 18: Energy Conservation Program: Test Procedures for Conventional Ovens, Final Rule ISSUANCE 2015-06-18: Energy Conservation Program: Test Procedures for Conventional Ovens, Final Rule This document is the Energy Conservation Program: Test Procedures for Conventional Ovens, Final Rule. PDF icon conventional_ovens_tp_finalrule.pdf More Documents & Publications ISSUANCE 2015-05-29: Energy Conservation Program: Energy Conservation

  1. May 2002

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 A newsletter for the employees and friends of the Y-12 National Security Complex May 2002 Editor's note: This is a special edition devoted to exploring issues concerning beryllium. Questions you may have about beryllium will be answered in this publication. Current personal protection equipment and handling techniques also will be discussed, as well as technology for the future handling of beryllium at Y-12. First, some basic facts: What is beryllium? Beryllium is a silver-gray metallic

  2. CRITICAL CONFIGURATION AND PHYSICS MEASUREMENTS FOR BERYLLIUM REFLECTED ASSEMBLIES OF U(93.15)O2 FUEL RODS (1.506-CM PITCH)

    SciTech Connect (OSTI)

    Margaret A. Marshall

    2013-03-01

    Cadmium ratios were measured with enriched uranium metal foils at various locations in the assembly with the fuel tube at the 1.506-cm spacing. They are described in the following subsections. The experiment configuration was the same as the first critical configuration described in HEU-COMP-FAST-004 (Case 1). The experimenter placed 0.75-cm-diameter 0.010-cm-thick 93.15%-235U-enriched uranium metal foils with and without 0.051-cm-thick cadmium covers at various locations in the core and top reflector. One part of the cadmium cover was cupshape and contained the uranium foil. The other part was a lid that fit over the exposed side of the foil when it was in the cup shaped section of the cover. As can be seen in the logbook, two runs were required to obtain all the measurements necessary for the cadmium ratio. The bare foil measurements within the top reflector were run first as part of the axial foil activation measurements. The results of this run are used for both the axial activation results and the cadmium ratios. Cadmium covered foils were then placed at the same location through the top reflector in a different run. Three pairs of bare and cadmium covered foils were also placed through the core tank. One pair was placed at the axial center of a fuel tube 11.35 cm from the center of the core. Two pairs of foils were placed on top of fuel tubes 3.02 and 12.06 cm from the center of the core. The activation of the uranium metal foils was measured after removal from the assembly using two lead shielded NaI scintillation detectors as follows. The NaI scintillators were carefully matched and had detection efficiencies for counting delayed-fission-product gamma rays with energies above 250 KeV within 5%. In all foil activation measurements, one foil at a specific location was used as a normalizing foil to remove the effects of the decay of fission products during the counting measurements with the NaI detectors. The normalization foil was placed on one NaI scintillator and the other foil on the other NaI detector and the activities measured simultaneously. The activation of a particular foil was compared to that of the normalization foil by dividing the count rate for each foil by that of the normalization foil. To correct for the differing efficiencies of the two NaI detectors, the normalization foil was counted in Detector 1 simultaneously with the foil at position x in Detector 2, and then the normalization foil was counted simultaneously in Detector 2 with the foil from position x in Counter 1. The activity of the foil from position x was divided by the activity of the normalization foil counted simultaneously. This resulted in obtaining two values of the ratio that were then averaged. This procedure essentially removed the effect of the differing efficiencies of the two NaI detectors. Differing efficiencies of 10% resulted in errors in the ratios measured to less than 1%. The background counting rates obatined with the foils used for the measurements on the NaI detectors before their irradiation measurement were subtracted from all count rates. The results of the cadmium ratio measurements are given in Table 1.3-1 and Figure 1.3-1. No correction has been made for self shielding in the foils (Reference 3).

  3. Light-element nucleosynthesis in a molecular cloud interacting with a supernova remnant and the origin of beryllium-10 in the protosolar nebula

    SciTech Connect (OSTI)

    Tatischeff, Vincent; Duprat, Jean [Centre de Sciences Nuclaires et de Sciences de la Matire, IN2P3-CNRS and Univ Paris-Sud, F-91405 Orsay Cedex (France); De Srville, Nicolas, E-mail: Vincent.Tatischeff@csnsm.in2p3.fr [Institut de Physique Nuclaire d'Orsay, IN2P3-CNRS and Univ Paris-Sud, F-91405 Orsay Cedex (France)

    2014-12-01

    The presence of short-lived radionuclides (t {sub 1/2} < 10 Myr) in the early solar system provides important information about the astrophysical environment in which the solar system formed. The discovery of now extinct {sup 10}Be (t {sub 1/2} = 1.4 Myr) in calcium-aluminum-rich inclusions (CAIs) with Fractionation and Unidentified Nuclear isotope anomalies (FUN-CAIs) suggests that a baseline concentration of {sup 10}Be in the early solar system was inherited from the protosolar molecular cloud. In this paper, we investigate various astrophysical contexts for the nonthermal nucleosynthesis of {sup 10}Be by cosmic-ray-induced reactions. We first show that the {sup 10}Be recorded in FUN-CAIs cannot have been produced in situ by irradiation of the FUN-CAIs themselves. We then show that trapping of Galactic cosmic rays (GCRs) in the collapsing presolar cloud core induced a negligible {sup 10}Be contamination of the protosolar nebula, the inferred {sup 10}Be/{sup 9}Be ratio being at least 40 times lower than that recorded in FUN-CAIs ({sup 10}Be/{sup 9}Be ? 3 10{sup 4}). Irradiation of the presolar molecular cloud by background GCRs produced a steady-state {sup 10}Be/{sup 9}Be ratio ? 1.3 10{sup 4} at the time of the solar system formation, which suggests that the presolar cloud was irradiated by an additional source of CRs. Considering a detailed model for CR acceleration in a supernova remnant (SNR), we find that the {sup 10}Be abundance recorded in FUN-CAIs can be explained within two alternative scenarios: (1) the irradiation of a giant molecular cloud by CRs produced by ? 50 supernovae exploding in a superbubble of hot gas generated by a large star cluster of at least 20,000 members, and (2) the irradiation of the presolar molecular cloud by freshly accelerated CRs escaped from an isolated SNR at the end of the Sedov-Taylor phase. In the second picture, the SNR resulted from the explosion of a massive star that ran away from its parent OB association, expanded during most of its adiabatic phase in an intercloud medium of density of about 1 H-atom cm{sup 3}, and eventually interacted with the presolar molecular cloud only during the radiative stage. This model naturally provides an explanation for the injection of other short-lived radionuclides of stellar origin into the cold presolar molecular cloud ({sup 26}Al, {sup 41}Ca, and {sup 36}Cl) and is in agreement with the solar system originating from the collapse of a molecular cloud shocked by a supernova blast wave.

  4. CRITICAL CONFIGURATION AND PHYSICS MEASUREMENTS FOR BERYLLIUM REFLECTED ASSEMBLIES OF U(93.15)O2 FUEL RODS (1.506-CM PITCH AND 7-TUBE CLUSTERS)

    SciTech Connect (OSTI)

    Margaret A. Marshall

    2014-03-01

    Cadmium ratios were measured with enriched uranium metal foils at various locations in the assembly with the fuel tube at the 1.506-cm spacing. They are described in the following subsections. The experiment configuration was the same as the first critical configuration described in HEU-COMP-FAST-004 (Case 1). The experimenter placed 0.75-cm-diameter 0.010-cm-thick 93.15%-235U-enriched uranium metal foils with and without 0.051-cm-thick cadmium covers at various locations in the core and top reflector. One part of the cadmium cover was cupshape and contained the uranium foil. The other part was a lid that fit over the exposed side of the foil when it was in the cup shaped section of the cover. As can be seen in the logbook, two runs were required to obtain all the measurements necessary for the cadmium ratio. The bare foil measurements within the top reflector were run first as part of the axial foil activation measurements. The results of this run are used for both the axial activation results and the cadmium ratios. Cadmium covered foils were then placed at the same location through the top reflector in a different run. Three pairs of bare and cadmium covered foils were also placed through the core tank. One pair was placed at the axial center of a fuel tube 11.35 cm from the center of the core. Two pairs of foils were placed on top of fuel tubes 3.02 and 12.06 cm from the center of the core. The activation of the uranium metal foils was measured after removal from the assembly using two lead shielded NaI scintillation detectors as follows. The NaI scintillators were carefully matched and had detection efficiencies for counting delayed-fission-product gamma rays with energies above 250 KeV within 5%. In all foil activation measurements, one foil at a specific location was used as a normalizing foil to remove the effects of the decay of fission products during the counting measurements with the NaI detectors. The normalization foil was placed on one NaI scintillator and the other foil on the other NaI detector and the activities measured simultaneously. The activation of a particular foil was compared to that of the normalization foil by dividing the count rate for each foil by that of the normalization foil. To correct for the differing efficiencies of the two NaI detectors, the normalization foil was counted in Detector 1 simultaneously with the foil at position x in Detector 2, and then the normalization foil was counted simultaneously in Detector 2 with the foil from position x in Counter 1. The activity of the foil from position x was divided by the activity of the normalization foil counted simultaneously. This resulted in obtaining two values of the ratio that were then averaged. This procedure essentially removed the effect of the differing efficiencies of the two NaI detectors. Differing efficiencies of 10% resulted in errors in the ratios measured to less than 1%. The background counting rates obatined with the foils used for the measurements on the NaI detectors before their irradiation measurement were subtracted from all count rates. The results of the cadmium ratio measurements are given in Table 1.3-1 and Figure 1.3-1. No correction has been made for self shielding in the foils (Reference 3).

  5. d_al_05.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Origin by Method of Transportation Electricity Generation Coke Plants Industrial Plants (Except Coke) Residential and Commercial Total Alabama 770 851 1,739 3,360 Railroad 642 1...

  6. File

    U.S. Energy Information Administration (EIA) Indexed Site

    4,2,"Alabama","Alabama","Coke Plant","Railroad",87406 2014,2,"Alabama","Alabama","Coke Plant","Truck",97501 2014,2,"Alabama","Alabama","Electric Power Sector","Railroad",95016 ...

  7. File

    U.S. Energy Information Administration (EIA) Indexed Site

    3,"Alabama","Alabama","Coke Plant","Railroad",81151 2014,3,"Alabama","Alabama","Coke Plant","Truck",156509 2014,3,"Alabama","Alabama","Electric Power Sector","Railroad",214186 ...

  8. File

    U.S. Energy Information Administration (EIA) Indexed Site

    4,"Alabama","Alabama","Coke Plant","Railroad",65620 2014,4,"Alabama","Alabama","Coke Plant","Truck",124124 2014,4,"Alabama","Alabama","Electric Power Sector","Railroad",28514 ...

  9. File

    U.S. Energy Information Administration (EIA) Indexed Site

    Electric Power Sector","Truck",12356 2013,1,"Alabama","Alabama","Coke Plant","Truck",87126 2013,1,"Alabama","Alabama","Industrial Plants Excluding Coke","Truck",269810 ...

  10. File

    U.S. Energy Information Administration (EIA) Indexed Site

    2,4,"Alabama","Alabama","Coke Plant","Railroad",17349 2012,4,"Alabama","Alabama","Coke Plant","Truck",144411 2012,4,"Alabama","Alabama","Electric Power Sector","Railroad",802677 ...

  11. File

    U.S. Energy Information Administration (EIA) Indexed Site

    2,"Alabama","Alabama","Coke Plant","Railroad",116028 2013,2,"Alabama","Alabama","Coke Plant","Truck",94157 2013,2,"Alabama","Alabama","Electric Power Sector","Railroad",495478 ...

  12. File

    U.S. Energy Information Administration (EIA) Indexed Site

    3,"Alabama","Alabama","Coke Plant","Railroad",25825 2013,3,"Alabama","Alabama","Coke Plant","Truck",125381 2013,3,"Alabama","Alabama","Electric Power Sector","Railroad",796189 ...

  13. SAS Output

    Gasoline and Diesel Fuel Update (EIA)

    1. Stocks of Coal, Petroleum Liquids, and Petroleum Coke: Electric Power Sector, 2004 - 2014 Electric Power Sector Electric Utilities Independent Power Producers Period Coal (Thousand Tons) Petroluem Liquids (Thousand Barrels) Petroleum Coke (Thousand Tons) Coal (Thousand Tons) Petroluem Liquids (Thousand Barrels) Petroleum Coke (Thousand Tons) Coal (Thousand Tons) Petroluem Liquids (Thousand Barrels) Petroleum Coke (Thousand Tons) End of Year Stocks 2004 106,669 46,750 937 84,917 29,144 627

  14. EA-1662: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for Certain Consumer Products (Dishwashers, Dehumidifiers, Microwave Ovens, and Electric and Gas Kitchen Ranges and Ovens) and for Certain Commercial and Industrial Equipment (Commercial Clothes Washers)

  15. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Wonders of the Sun...

  16. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Green Fuel This...

  17. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Plants in Your Gas...

  18. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download An Exploration of...

  19. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Energy in Today's...

  20. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download What Makes A Home...

  1. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download The Sun and Its...

  2. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lesson, that can be adapted for all grade levels, on how to build a solar oven. http:energy.goveereeducationdownloadsbuild-pizza-box-solar-oven-0 Download Energy From the Sun...

  3. Baseline risk assessment of ground water contamination at the Uranium Mill Tailings Site near Naturita, Colorado

    SciTech Connect (OSTI)

    1995-08-01

    The Uranium Mill Tailings Remedial Action (UMTRA) Project consists of the Surface Project (phase I), and the Ground Water Project (phase II). For the UMTRA Project site located near Naturita, Colorado (the Naturita site), phase I involves the removal of radioactively contaminated soils and materials and their transportation to a disposal site at Union Carbide Corporation`s Upper Burbank Repository at Uravan, Colorado, about 13 road miles (mi) (21 kilometers [km]) to the northwest. No uranium mill tailings are involved because the tailings were removed from the Naturita site and placed at Coke Oven, Colorado, during 1977 to 1979. Phase II of the project will evaluate the nature and extent of ground water contamination resulting from uranium processing and its effect on human health or the environment; and will determine site-specific ground water compliance strategies in accordance with the US Environmental Protection Agency (EPA) ground water standards established for the UMTRA Project. Human health risks could occur from drinking water pumped from a hypothetical well drilled in the contaminated ground water area. Environmental risks may result if plants or animals are exposed to contaminated ground water, or surface water that has received contaminated ground water. Therefore, a risk assessment is conducted for the Naturita site. This risk assessment report is the first site-specific document prepared for the Ground Water Project at the Naturita site. What follows is an evaluation of current and possible future impacts to the public and the environment from exposure to contaminated ground water. The results of this evaluation and further site characterization will be used to determine whether any action is needed to protect human health or the environment.

  4. Clean Coal Technology Demonstration Program. Program update 1994

    SciTech Connect (OSTI)

    1995-04-01

    The Clean Coal Technology Demonstration Program (CCT Program) is a $7.14 billion cost-shared industry/government technology development effort. The program is to demonstrate a new generation of advanced coal-based technologies, with the most promising technologies being moved into the domestic and international marketplace. Clean coal technologies being demonstrated under the CCT program are creating the technology base that allows the nation to meet its energy and environmental goals efficiently and reliably. The fact that most of the demonstrations are being conducted at commercial scale, in actual user environments, and under conditions typical of commercial operations allows the potential of the technologies to be evaluated in their intended commercial applications. The technologies are categorized into four market sectors: advanced electric power generation systems; environmental control devices; coal processing equipment for clean fuels; and industrial technologies. Sections of this report describe the following: Role of the Program; Program implementation; Funding and costs; The road to commercial realization; Results from completed projects; Results and accomplishments from ongoing projects; and Project fact sheets. Projects include fluidized-bed combustion, integrated gasification combined-cycle power plants, advanced combustion and heat engines, nitrogen oxide control technologies, sulfur dioxide control technologies, combined SO{sub 2} and NO{sub x} technologies, coal preparation techniques, mild gasification, and indirect liquefaction. Industrial applications include injection systems for blast furnaces, coke oven gas cleaning systems, power generation from coal/ore reduction, a cyclone combustor with S, N, and ash control, cement kiln flue gas scrubber, and pulse combustion for steam coal gasification.

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (1) atom collisions (1) atomic and molecular physics (1) beryllium 10 (1) beryllium ... London WC1E 6BT ; Istituto Nazionale di Fisica Nucleare, Largo Pontecorvo 3, 56100 Pisa ...

  6. ISSUANCE 2015-05-29: Energy Conservation Program: Energy Conservation

    Office of Environmental Management (EM)

    Standards for Residential Conventional Ovens, Notice of Proposed Rulemaking | Department of Energy Energy Conservation Standards for Residential Conventional Ovens, Notice of Proposed Rulemaking ISSUANCE 2015-05-29: Energy Conservation Program: Energy Conservation Standards for Residential Conventional Ovens, Notice of Proposed Rulemaking This document is the notice of proposed rule for Energy Conservation Program: Energy Conservation Standards for Residential Conventional Ovens. PDF icon

  7. ISSUANCE 2015-07-23: Energy Conservation Program: Energy Conservation...

    Broader source: Energy.gov (indexed) [DOE]

    Conventional Ovens, Comment Period Extension. conventionalovenscommentextension.pdf More Documents & Publications ISSUANCE 2015-07-17: Energy Conservation Program: Energy...

  8. Rulemaking-Public Hearing Agenda, 2/11/99, Washington, DC

    Broader source: Energy.gov [DOE]

    Chronic Beryllium Diease Prevention Program Notice of Proposed Rulemaking (NOPR) Docket Number EH-RM-98-BRYLM

  9. Rulemaking, Public Hearing in Oak Ridge, TN (2/3/1999)

    Broader source: Energy.gov [DOE]

    Chronic Beryllium Diease Prevention Program Notice of Proposed Rulemaking (NOPR) Docket Number EH-RM-98-BRYLM

  10. Cleaning Up the Hanford River Corridor and Improving Site Operations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7.4 Hanford Beryllium Work History BeCAP Product January 2015 2 1.7.4 Hanford Beryllium Work History BeCAP Product * Completed Beryllium Affected Worker History questionnaire * Questionnaire based on timeline concept * Interviews to be conducted by HPMC OMS' Certified Industrial Hygienist * Goal: prevent future beryllium exposures to Hanford workers 3 BeLPT* Statistics * Running total as of November 2014 - Be Sensitized workers = 148 - CBD workers = 37 * Current Active Hanford workers - Be

  11. CRAD, Assessment of the Site- February 17, 2010

    Broader source: Energy.gov [DOE]

    Assessment of the Site Chronic Beryllium Disease Prevention Plan (CBDPP) Implementation (HSS CRAD 64-37, Rev 0)

  12. Independent Activity Report, Lawrence Livermore National Laboratory...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Independent Activity Report, Lawrence Livermore National Laboratory - March 2011 March 2011 Lawrence Livermore National Laboratory Chronic Beryllium Disease Prevention Program ...

  13. ORISE: How to Work With Us | Worker Health Studies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    environmental health. Services provided include illness and injury surveillance, worker health research, medical data management, beryllium exposure studies and testing,...

  14. ORISE: Iddins promoted to associate director of Radiation Emergency...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Medical Center Healthworks and Roane Industrial Medicine where she performed occupational health surveillance physicals, conducted respirator and beryllium surveillance clearances,...

  15. Audit Report: IG-0783 | Department of Energy

    Energy Savers [EERE]

    3 Audit Report: IG-0783 December 17, 2007 Beryllium Surface Contamination at the Y-12 National Security Complex BWXT Y-12, LLC's (BWXT Y-12) actions were not consistent with its Chronic Beryllium Disease Prevention Program (Prevention Program). In particular, BWXT Y-12 had not always posted locations of beryllium contamination that were outside of beryllium operational areas in the three facilities included in our review. These postings would have alerted workers to the potential risks of

  16. DOL: Role in EEOICPA - Part B and Part E | Department of Energy

    Office of Environmental Management (EM)

    Role in EEOICPA - Part B and Part E DOL: Role in EEOICPA - Part B and Part E Addthis Description DOL is tasked with administering the EEOICPA, both Parts B and E. Part B covers current and former workers who have been diagnosed with cancer, chronic beryllium disease, beryllium sensitivity, or silicosis, and whose illness was caused by exposure to radiation, beryllium or silica while working at a covered Department of Energy (DOE) facility, Atomic Weapons Employer (AWE) facility or a beryllium

  17. Raceway behaviors in blast furnace with pulverized coal injection

    SciTech Connect (OSTI)

    Chung, J.K.; Han, J.W.; Cho, B.R.

    1995-12-01

    The blast furnace raceway shows different characteristics with PCR (pulverized coal injection rate). It was found in this study that with the increase of PCR the raceway depth decreases, and the size of birds nest and sometimes with liquid holdup, increases. Oxygen enrichment with co-axial lances was known to be very effective on the extension of raceway depth and size reduction of birds nest. It was also found that there are various factors which affect the coke properties at tuyere level of the blast furnace. Coke traveling time was calculated to be extended with PCR and it had a close relationship with the coke size in bosh. Coke mean size decreased with the increase of coke traveling time, that is, with the increase of PCR. Both DI (the strength of coke in cold) and CSR (the strength of coke after reaction) were also decreased with PCR. RAFT (Raceway Adiabatic Flame Temperature) had a tendency to be decreased with the increase of PCR, which is obtained by the estimation of coke temperature via XRD analysis. From the analysis of alkali contents in coke sampled along the radius of the blast furnace, it was understood that no difference in alkali contents between fine and lump coke represents that coke fines generated from upper burden might appear at tuyere level.

  18. A study on the flow of molten iron in the hearth of blast furnace

    SciTech Connect (OSTI)

    Suh, Y.K.; Lee, Y.J.; Baik, C.Y.

    1996-12-31

    The flow of molten iron in the hearth of blast furnace was investigated by using a water model test and a numerical simulation. The water model apparatus was set up in order to evaluate the effects of coke size, coke bed structure, drain rate, and coke free space on the fluidity of molten iron through measurement of residence time and visualization of flow pattern. In addition, the flow was calculated by solving momentum equation in porous media using finite element method. The residence time increased with the coke size decrease, but decreased with the drain rate increase. If small coke was placed in the center of deadman, peripheral flow was enhanced. The flow path was changed due to the coke free space.

  19. Catalyst Assisted Manufacture of Olefins (CAMOL)

    Office of Environmental Management (EM)

    Majid Keyvani, Ph.D., Lyondell Chemical Company U.S. DOE Advanced Manufacturing Office Peer Review Meeting Washington, D.C. May 6-7, 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Background  Coke is a naturally occurring by-product of steam cracking  Coking (carbonaceous deposits) of the furnace coils increases energy requirements, requires frequent production interruptions to de-coke, and shortens coil life  Both the

  20. Crude Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    Barrels) Product: Crude Oil Liquefied Petroleum Gases Distillate Fuel Oil Residual Fuel Oil Still Gas Petroleum Coke Marketable Petroleum Coke Catalyst Petroleum Coke Other Petroleum Products Natural Gas Coal Purchased Electricity Purchased Steam Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2009 2010 2011 2012 2013 2014 View History U.S. 0 0 0 0 0 0 1986-2014 East Coast (PADD 1) 0 0 0 0

  1. Development of an Advanced Combined Heat and Power (CHP) System Utilizing

    Office of Environmental Management (EM)

    Off-Gas from Coke Calcination - Fact Sheet, 2014 | Department of Energy an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination - Fact Sheet, 2014 Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination - Fact Sheet, 2014 The Gas Technology Institute-in collaboration with Superior Graphite Company and SCHMIDTSCHE SCHACK, a division of ARVOS Group, Wexford business unit (formerly Alstom Power Energy

  2. International Agreements Comments

    Broader source: Energy.gov (indexed) [DOE]

    (especially coking and cracking; (b) mineral reactions and their relationships to air pollution issues; (c) mining studies; and (d) systems analysis. VISITS AND...

  3. Characterization of carbon dissolution from the new Auscarb clean carbon for ironmaking

    SciTech Connect (OSTI)

    Sahajwalla, V.; Farrell, K.; Gao, K.; Waugh, B.; Roberts, C.; Langley, J.M.

    1995-12-01

    In the foundry industry, the recarburizing materials used can range from high purity graphite to chars. The dissolution performance of recarburizing materials is critical to the industry, as it has a direct bearing on productivity. In this study, the dissolution performance of a variety of clean Auscarb carbon materials has been determined to assess their suitability as recarburizing material. The carbon sources investigated were graphite (synthetic), coke A (2.5 and 18 hr), coke B (2.5, 3 and 18 hr) and coke C (2.5 hr). In addition, the effect of melt sulfur content and coke supplier (ACIRL or CSIRO laboratories) on dissolution performance was examined. Dissolution performance was characterized on the basis of the measured rate constant. The experimental investigation conducted in this study has established the trend in performance of the carbons. The results show that, for a fixed melt sulfur content of 0.2%, synthetic graphite was the best, although the dissolution performance of coke B approaches half that of synthetic graphite. The performance of cokes A and C fall slightly behind that of coke B. The cokes supplied from different sources were found to have similar dissolution performance only on extended coking times. Decreased melt sulfur content was found to increase the dissolution rate, and it was found that the extent of improvement was influenced by the nature of the carbonaceous material.

  4. article_dc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Even though coal is such a small part of the total ... The substantial decrease in the generation by hydroelectric ... Coal consumption at coke plants Figure 5. Coal Consumption ...

  5. DOE/EIA-0035(93/05) Energy R*y

    Gasoline and Diesel Fuel Update (EIA)

    wind, photovoltaic, and solar b Production and consumption totals exclude wood, waste, geothermal, thermal energy; and net imports of electricity and coal coke. wind,...

  6. DOE/EIA-0035(93/07) Monthly Energy Review W S. IRA W,

    Gasoline and Diesel Fuel Update (EIA)

    wind, photovoltaic, and solar b Production and consumption totals exclude wood, waste, geothermal, thermal energy; and net imports of electricity and coal coke. wind,...

  7. DOE/EIA-003353/06)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    wind, photovoltaic, and solar b Production and consumption totals exclude wood, waste, geothermal, thermal energy; and net imports of electricity and coal coke. wind,...

  8. American Recovery & Reinvestment Act Newsletter - Issue 25

    Office of Environmental Management (EM)

    concerns," Chaloupka said. "That in turn affected our schedule and budget." Other trash found in the pit included cardboard boxes, glass Coke bottles, and a calendar from...

  9. Word Pro - S2

    Gasoline and Diesel Fuel Update (EIA)

    Btu of coal coke net imports. 4 Conventional hydroelectric power, geothermal, solarphotovoltaic, wind, and biomass. 5 Includes industrial combined-heat-and-power (CHP)...

  10. Word Pro - S2.lwp

    Gasoline and Diesel Fuel Update (EIA)

    Btu of coal coke net imports. 4 Conventional hydroelectric power, geothermal, solarphotovoltaic, wind, and biomass. 5 Includes industrial combined-heat-and-power (CHP)...

  11. Appendix A: Reference case

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    road oil, still gas, special naphthas, petroleum coke, crude oil product supplied, methanol, and miscellaneous petroleum products. 14 Includes energy for combined heat and...

  12. Fact #864: March 16, 2015 Imports of Primary Energy have Declined...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    years 1950 to 2014. Note: Primary energy includes coal, coal coke, petroleum, natural gas, biofuels and electricity. To see imports of petroleum only, see Fact 837. Fact 864...

  13. Energy Information Administration - Energy Efficiency-table 7b...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    on electric, natural gas, residual fuel oil, coal or coke. NANot available.. Sources: Energy Information Administration, Manufacturing Energy Consumption Surveys 1998, 2002, and...

  14. Energy Information Administration - Energy Efficiency-Table 6a...

    Gasoline and Diesel Fuel Update (EIA)

    on electric, natural gas, coal, residual fuel oil or coke. NANot available. Sources: Energy Information Administration, Manufacturing Energy Consumption Surveys 1998, 2002, and...

  15. U.S. Energy Information Administration | Quarterly Coal Report, April - June 2014

    Gasoline and Diesel Fuel Update (EIA)

    Coke and Breeze Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2014 Table 41. Coke and Breeze Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2014 Census Division June 30, 2014 March 31, 2014 June 30, 2013 Percent Change (June 30) 2014 versus 2013 Middle Atlantic 215 126 54 296.0 East North Central 627 635 724

  16. Refines Efficiency Improvement

    SciTech Connect (OSTI)

    WRI

    2002-05-15

    Refinery processes that convert heavy oils to lighter distillate fuels require heating for distillation, hydrogen addition or carbon rejection (coking). Efficiency is limited by the formation of insoluble carbon-rich coke deposits. Heat exchangers and other refinery units must be shut down for mechanical coke removal, resulting in a significant loss of output and revenue. When a residuum is heated above the temperature at which pyrolysis occurs (340 C, 650 F), there is typically an induction period before coke formation begins (Magaril and Aksenova 1968, Wiehe 1993). To avoid fouling, refiners often stop heating a residuum before coke formation begins, using arbitrary criteria. In many cases, this heating is stopped sooner than need be, resulting in less than maximum product yield. Western Research Institute (WRI) has developed innovative Coking Index concepts (patent pending) which can be used for process control by refiners to heat residua to the threshold, but not beyond the point at which coke formation begins when petroleum residua materials are heated at pyrolysis temperatures (Schabron et al. 2001). The development of this universal predictor solves a long standing problem in petroleum refining. These Coking Indexes have great potential value in improving the efficiency of distillation processes. The Coking Indexes were found to apply to residua in a universal manner, and the theoretical basis for the indexes has been established (Schabron et al. 2001a, 2001b, 2001c). For the first time, a few simple measurements indicates how close undesired coke formation is on the coke formation induction time line. The Coking Indexes can lead to new process controls that can improve refinery distillation efficiency by several percentage points. Petroleum residua consist of an ordered continuum of solvated polar materials usually referred to as asphaltenes dispersed in a lower polarity solvent phase held together by intermediate polarity materials usually referred to as resins. The Coking Indexes focus on the amount of these intermediate polarity species since coke formation begins when these are depleted. Currently the Coking Indexes are determined by either titration or solubility measurements which must be performed in a laboratory. In the current work, various spectral, microscopic, and thermal techniques possibly leading to on-line analysis were explored for measuring the Coking Indexes.

  17. "RSE Table N1.3. Relative Standard Errors for Table N1.3;...

    U.S. Energy Information Administration (EIA) Indexed Site

    "Coal ",3 "Natural Gas",1 "Net Electricity",1 " Purchases",1 " Transfers In",9 " Onsite Generation from Noncombustible Renewable Energy",15 " Sales and Transfers Offsite",3 "Coke ...

  18. Reforming Pyrolysis Aqueous Waste Streams to Process Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Experiment: MBMS: real-time deactivation of the catalysts GCMS: Identify and quantify products TGA analysis: coking extent XRDNMR Investigate dealumination ...

  19. Fiber Reinforced Polymer Composite Manufacturing Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... imagingspectra, dielectric loss - Ultrasonic attenuation & non-linear measurement ... in the coking process. * Bio-Compound Extraction: Torrefaction can extract high-value ...

  20. Coal Market Module

    Gasoline and Diesel Fuel Update (EIA)

    power generation, industrial steam generation, coal-to-liquids production, coal coke manufacturing, residentialcommercial consumption, and coal exports) within the CMM. By...