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Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
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1

Determining the environmental and thermal characteristics of coke oven batteries  

Science Journals Connector (OSTI)

A method is proposed for assessing the environmental and thermal characteristics of coke oven batteries and is tested for coke oven batteries 1 and 5 at OAO Zaporozhkoks. On ... the basis of data for the environm...

E. I. Toryanik; A. L. Borisenko; A. S. Malysh; A. A. Lobov…

2009-12-01T23:59:59.000Z

2

Desulfurization of coke oven gas from the coking of coking coal blended with a sorbent and waste plastic  

Science Journals Connector (OSTI)

A new way to implement the simultaneous reutilization of solid waste, the desulfurization of coke oven gas (COG), and even the desulfurization of coke by the co-coking of coking coal (CC) and waste plastic (WP).....

Zhao Rongfang; Ye Shufeng; Xie Yusheng…

2007-03-01T23:59:59.000Z

3

New packing in absorption systems for trapping benzene from coke-oven gas  

SciTech Connect (OSTI)

The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

4

SOURCE ACTIVITY TITLE: SOLID FUEL TRANSFORMATION PLANTS Coke Oven Furnaces Coke Oven (Door Leakage and Extinction) NOSE CODE: 104.12 NFR CODE:  

E-Print Network [OSTI]

1 ACTIVITIES INCLUDED Coke-production in general can be divided into the following steps: Coal handling and storage, coke oven charging, coal coking, extinction of coke, and coke oven gas purification. Combustion in coke oven furnaces (SNAP 010406) is treated in this chapter as well as door leakage and extinction (SNAP 040201). Figure 1-1 gives a key plan of a coke plant with emission relevant process steps and the byproduct recovery section. Figure 1-1: Key plan of a coke plant (Rentz et al. 1995) C o a l S lu d g e B l a s t F u r n a c e G a s f r o m S t e e l M il l A i r E m is s io n s G a s H o ld e r

Ic Activities; So Nox Nmv

5

Effect of Indian Medium Coking Coal on Coke Quality in Non-recovery Stamp Charged Coke Oven  

Science Journals Connector (OSTI)

Abstract The maximum possibility of utilizing the Indian coking coals and inferior grade coking coal for producing metallurgical coke through non-recovery stamp charging technology was investigated. Indian indigenous coals contained low percent of vitrinite ( 15%) compared to imported coking coal. Therefore, the selection of appropriate proportion of different types of coals was a major challenge for coke makers. Coal blend selection criterion based on a single coefficient, named as composite coking potential (CCP), was developed. The use of increased proportion of semi-soft coal (crucible swelling number of 2.5) and high ash (? 15%) indigenous coal in the range of 20%–35% and 20%–65% respectively in the blends resulted in good quality of coke. Plant data of a non-recovery coke oven were used for developing and validating the model. The results showed that the coke strength after reaction (CSR) varied in the range of 63. 7%–67.7% and the M40 value was between 81.8 and 89.3 in both the cases.

H.P. Tiwari; P.K. Banerjee; V.K. Saxena; S.K. Haldar

2014-01-01T23:59:59.000Z

6

Innovative coke oven gas cleaning system for retrofit applications  

SciTech Connect (OSTI)

Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

Not Available

1992-10-16T23:59:59.000Z

7

Developing indicators for the assessment and proper management of the different levels of exposure to polycyclic aromatic hydrocarbons (PAH)s generally associated with coke-oven workers.  

E-Print Network [OSTI]

??Coke ovens may occur in the aluminium, steel, graphite, electrical, and construction industries. In the work area coke-oven workers may be exposed to various chemical… (more)

Wang, Tianyuan

2011-01-01T23:59:59.000Z

8

Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau (CPM)  

E-Print Network [OSTI]

- 1 - Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau with thermomechanical modelling of a coke oven heating wall. The objective is to define the safe limits of coke oven of walls, roof and larry car, pre-stresses (anchoring system), lateral pressure due to coal pushing A 3D

Boyer, Edmond

9

Hydrogen production from steam reforming of coke oven gas and its utility for indirect reduction of iron oxides in blast  

E-Print Network [OSTI]

of coal and coke are consumed for heating and reducing iron oxides [2,3]. As a result, BFs have becomeHydrogen production from steam reforming of coke oven gas and its utility for indirect reduction 2012 Available online 18 June 2012 Keywords: Steam reforming Hydrogen and syngas production Coke oven

Leu, Tzong-Shyng "Jeremy"

10

Spatial variation of coke quality in the non-recovery beehive coke ovens.  

E-Print Network [OSTI]

??More than 50% of hot metal production worldwide takes place in blast furnaces. Coke is the most expensive raw material in the blast furnace. It… (more)

Segers, Magrieta

2006-01-01T23:59:59.000Z

11

Production of Syngas via Partial Oxidation and CO2 Reforming of Coke Oven Gas over a Ni Catalyst  

Science Journals Connector (OSTI)

Production of Syngas via Partial Oxidation and CO2 Reforming of Coke Oven Gas over a Ni Catalyst ... The yield of produced syngas increases with an increase in temperature. ...

Jianzhong Guo; Zhaoyin Hou; Jing Gao; Xiaoming Zheng

2008-04-05T23:59:59.000Z

12

Air pollution from a large steel factory: polycyclic aromatic hydrocarbon emissions from coke-oven batteries  

SciTech Connect (OSTI)

A systematic investigation of solid and gaseous atmospheric emissions from some coke-oven batteries of one of Europe's largest integrated steel factory (Taranto, Italy) has been carried out. These emissions, predominantly diffuse, originate from oven leakages, as well as from cyclic operations of coal loading and coke unloading. In air monitoring samples, polycyclic aromatic hydrocarbons (PAHs) were consistently detected at concentrations largely exceeding threshold limit values. By means of PAHs speciation profile and benzo-(a)pyrene (BaP) equivalent dispersion modeling from diffuse sources, the study indicated that serious health risks exist not only in working areas, but also in a densely populated residential district near the factory. 30 refs., 5 figs., 3 tabs.

Lorenzo Liberti; Michele Notarnicola; Roberto Primerano; Paolo Zannetti [Technical University of Bari, Bari (Italy). Department of Environmental Engineering and Sustainable Development

2006-03-15T23:59:59.000Z

13

Ovens  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

M206 Mechanical Convection Oven The M206 oven is dedicated to CAMD staff use only. M326 Mechanical Convection Oven Located next to the spinners, the M326 oven is availabe to...

14

A new technology for producing hydrogen and adjustable ratio syngas from coke oven gas  

SciTech Connect (OSTI)

About 15 billion Nm{sup 3} coke oven gas (COG) is emitted into the air in Shanxi Province in China as air pollutants. It is also a waste of precious chemical resources. In this study, COG was purified respectively by four methods including refrigeration, fiberglass, silica gel, and molecular sieve. Purified COG was separated by a prism membrane into two gas products. One consists mainly of H{sub 2} ({gt}90 vol %) and the other is rich in CH{sub 4} ({gt}60 vol %) with their exact compositions to vary with the membrane separation pressure and outlet gas flow ratio. The gas rich in CH{sub 4} was partially oxidized with oxygen in a high-temperature fixed-bed quartz reactor charged with coke particles of 10 mm size. At 1200-1300{sup o}C, a CH{sub 4} conversion of {gt}99% could be obtained. The H{sub 2}/CO ratio in the synthesis product gas can be adjusted in the range 0.3-1.4, very favorable for further C1 synthesis. 10 refs., 17 figs., 1t ab.

Jun Shen; Zhi-zhong Wang; Huai-wang Yang; Run-sheng Yao [Taiyuan University of Technology, Taiyuan (China). Department of Chemical Engineering

2007-12-15T23:59:59.000Z

15

Innovative coke oven gas cleaning system for retrofit applications. Environmental Monitoring program. Volume 1 - sampling progrom report. Baseline Sampling Program report  

SciTech Connect (OSTI)

Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This innovative coke oven gas cleaning system combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE provided cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct and Environmental Monitoring Plan for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. It also requires the preparation of a final report on the results of the Baseline Compliance and Supplemental Sampling Programs that are part of the EMP and which were conducted prior to the startup of the innovative coke oven gas cleaning system. This report is the Baseline Sampling Program report.

Stuart, L.M.

1994-05-27T23:59:59.000Z

16

The association of XRCC1 haplotypes and chromosomal damage levels in peripheral blood lymphocyte among coke-oven workers  

SciTech Connect (OSTI)

Theoretically, a haplotype has a higher level of heterozygosity than individual single nucleotide polymorphism (SNP) and the association study based on the haplotype may have an increased power for detecting disease associations compared with SNP-based analysis. In this study, we investigated the effects of four haplotype-tagging SNPs (htSNP) and the inferred haplotype pairs of the X-ray cross-complementing group 1 (XRCC1) gene on chromosome damage detected by the cytokinesis-block micronucleus assay. The study included 141 coke-oven workers with exposure to a high level of polycyclic aromatic hydrocarbons and 66 nonexposed controls. The frequencies of total MN and MNed cells were borderline associated with the Arg{sup 194}Trp polymorphism (P = 0.053 and P = 0.050, respectively) but not associated with the Arg{sup 280}His, Arg{sup 399}Gln and Gln{sup 632}Gln polymorphisms among coke-oven workers. Five haplotypes, including CGGG, TGGG, CAGG, CGAG, and CGGA, were inferred based on the four htSNPs of XRCC1 gene. The haplotype CGGG was associated with the decreased frequencies of total MN and MNed cells, and the haplotypes TGGG and CGAG were associated with the increased frequencies of total MN and MNed cells with adjustment for covariates among coke-oven workers. This study showed that the haplotypes derived from htSNPs in the XRCC1 gene were more likely than single SNPs to correlate with the polycyclic aromatic hydrocarbon-induced chromosome damage among coke-oven workers.

Shuguang Leng; Juan Cheng; Linyuan Zhang; Yong Niu; Yufei Dai; Zufei Pan; Bin Li; Fengsheng He; Yuxin Zheng [Chinese Center for Disease Control and Prevention, Beijing (China). National Institute of Occupational Health and Poison Control

2005-05-15T23:59:59.000Z

17

Urinary 1-hydroxypyrene concentrations in Chinese coke oven workers relative to job category, respirator usage, and cigarette smoking  

SciTech Connect (OSTI)

1-Hydroxypyrene (1-OHP) is a biomarker of recent exposure to polycyclic aromatic hydrocarbons (PAHs). We investigated whether urinary 1-OHP concentrations in Chinese coke oven workers (COWs) are modulated by job category, respirator usage, and cigarette smoking. The present cross-sectional study measured urinary 1-OHP concentrations in 197 COWs from Coking plant I and 250 COWs from Coking plant II, as well as 220 unexposed referents from Control plant I and 56 referents from Control plant II. Urinary 1-OHP concentrations (geometric mean, {mu}mol/mol creatinine) were 5.18 and 4.21 in workers from Coking plants I and II, respectively. The highest 1-OHP levels in urine were found among topside workers including lidmen, tar chasers, and whistlers. Benchmen had higher 1-OHP levels than other workers at the sideoven. Above 75% of the COWs exceeded the recommended occupational exposure limit of 2.3 {mu}mol/mol creatinine. Respirator usage and increased body mass index (BMI) slightly reduced 1-OHP levels in COWs. Cigarette smoking significantly increased urinary 1-OHP levels in unexposed referents but had no effect in COWs. Chinese COWs, especially topside workers and benchmen, are exposed to high levels of PAHs. Urinary 1-OHP concentrations appear to be modulated by respirator usage and BMI in COWs, as well as by smoking in unexposed referents.

Bo Chen; Yunping Hu; Lixing Zheng; Qiangyi Wang; Yuanfen Zhou; Taiyi Jin [Fudan University, Shanghai (China). School of Public Health

2007-09-15T23:59:59.000Z

18

Effects of genetic polymorphisms of metabolic enzymes on cytokinesis-block micronucleus in peripheral blood lymphocyte among coke-oven workers  

SciTech Connect (OSTI)

Exploring the associations between genetic polymorphisms of metabolic enzymes and susceptibility to polycyclic aromatic hydrocarbon (PAH)-induced chromosomal damage is of great significance for understanding PAH carcinogenesis. Cytochrome P450, glutathione S-transferase, microsomal epoxide hydrolase, NAD(P)H:quinone oxidoreductase, and N-acetyltransferase are PAH-metabolizing enzymes. In this study, we genotyped for the polymorphisms of these genes and assessed their effects on cytokinesis-block micronucleus (CBMN) frequencies in peripheral blood lymphocytes among 141 coke-oven workers and 66 non-coke-oven worker controls. The geometric means of urinary 1-hydroxypyrene levels in coke-oven workers and the controls were 12.0 and 0.7 {mu}mol/mol creatinine, respectively. The CBMN frequency (number of micronuclei per 1,000 binucleated lymphocytes) was significantly higher in coke-oven workers (9.5 {+-} 6.6) than in the controls. Among the coke-oven workers, age was positively associated with CBMN frequency; the mEH His{sup 113} variant genotype exhibited significantly lower CBMN frequency than did the Tyr{sup 113}/Tyr{sup 113} genotype; the low mEH activity phenotype exhibited a lower CBMN frequency than did the high mEH activity phenotype; the GSTP1 Val{sup 105}/Val{sup 105} genotype exhibited a higher CBMN frequency than did the GSTP1 Ile{sup 105}/Ile{sup 105} or Ile{sup 105}/Val{sup 105} genotypes; the joint effect of high mEH activity phenotype and GSTM1 null genotype on CBMN frequencies was also found. Gene-environment interactions between occupational PAH exposure and polymorphisms of mEH and/or GSTM1 were also evident. These results indicate that the mEH, GSTP1, and GSTM1 polymorphisms may play a role in sensitivity or genetic susceptibility to the genotoxic effects of PAH exposure in the coke-oven workers.

Shuguang Leng; Yufei Dai; Yong Niu; Zufei Pan; Xiaohua Li; Juan Cheng; Fengsheng He; Yuxin Zheng [Chinese Center for Disease Control and Prevention, Beijing (China). National Institute for Occupational Health and Poison Control

2004-10-15T23:59:59.000Z

19

Production of syngas via partial oxidation and CO{sub 2} reforming of coke oven gas over a Ni catalyst  

SciTech Connect (OSTI)

The partial oxidation and CO{sub 2} reforming of coke oven gas (COG) to syngas was investigated on differently sized Ni catalysts in a fluidized-bed reactor. It was found that the catalytic performance of Ni depends strongly on its particle size. The small-sized Ni catalyst exhibited higher activity and higher selectivity in the partial oxidation of COG. The conversion of CH{sub 4} was kept at 80.7% at a lower temperature (750{sup o}C) and a wide space velocity (from 8000 to 80 000 h{sup -1}). CO{sub 2} reforming of COG is also an efficient route for syngas production. The H{sub 2}/CO ratio in the COG-derived syngas could be controlled by manipulating the concentration of O{sub 2} or CO{sub 2} added in the feed. The yield of produced syngas increases with an increase in temperature. 19 refs., 10 figs., 2 tabs.

Jianzhong Guo; Zhaoyin Hou; Jing Gao; Xiaoming Zheng [Zhejiang University, Hangzhou (China). Institute of Catalysis, Department of Chemistry

2008-05-15T23:59:59.000Z

20

Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 3, January 1, 1991--December 31, 1991  

SciTech Connect (OSTI)

Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

Not Available

1992-10-16T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Hydrogen production by reforming of simulated hot coke oven gas over nickel catalysts promoted with lanthanum and cerium in a membrane reactor  

SciTech Connect (OSTI)

Catalysts of Ni/Mg(Al)O promoted with lanthanum and cerium were tested in a BaCo{sub 0.7}Fe{sub 0.2}Nb{sub 0.1}O{sub 3{delta}} (BCFNO) membrane reactor by catalytic partial oxidation of simulated hot coke oven gas (COG) with toluene as a model tar compound under atmospheric pressure. Analysis of the catalysts suggested that the hydrotalcite precursor after thermal treatment lead to a good dispersion of nickel forming the solid solution NiO-MgO and spinel (Ni,Mg)Al{sub 2}O{sub 4}. The promoted catalysts had higher oxygen permeation flux, better catalytic activity, and better resistance to carbon formation, which will be promising catalysts in the catalytic partial oxidation reforming of hot COG. 29 refs., 11 figs., 2 tabs.

Hongwei Cheng; Xionggang Lu; Yuwen Zhang; Weizhong Ding [Shanghai University, Shanghai (China). Shanghai Key Laboratory of Modern Metallurgy and Materials Processing

2009-05-15T23:59:59.000Z

22

Syngas production by CO2 reforming of coke oven gas over Ni/La2O3–ZrO2 catalysts  

Science Journals Connector (OSTI)

Abstract Syngas production by CO2 reforming of coke oven gas (COG) was studied in a fixed-bed reactor over Ni/La2O3–ZrO2 catalysts. The catalysts were prepared by sol–gel technique and tested by XRF, BET, XRD, H2-TPR, TEM and TG–DSC. The influence of nickel loadings and calcination temperature of the catalysts on reforming reaction was measured. The characterization results revealed that all of the catalysts present excellent resistance to coking. The catalyst with appropriate nickel content and calcination temperature has better dispersion of active metal and higher conversion. It is found that the Ni/La2O3–ZrO2 catalyst with 10 wt% nickel loading provides the best catalytic activity with the conversions of CH4 and CO2 both more than 95% at 800 °C under the atmospheric pressure. The Ni/La2O3–ZrO2 catalysts show excellent catalytic performance and anti-carbon property, which will be of great prospects for catalytic CO2 reforming of COG in the future.

Wei Tao; Hongwei Cheng; Weilin Yao; Xionggang Lu; Qiuhua Zhu; Guangshi Li; Zhongfu Zhou

2014-01-01T23:59:59.000Z

23

Dale Coke: Coke Farm  

E-Print Network [OSTI]

Dale Coke Photo by Benjamin J. Myers.2009. Coke FarmDale Coke grew up on an apricot orchard in California’s

Farmer, Ellen

2010-01-01T23:59:59.000Z

24

Association of polymorphisms in AhR, CYP1A1, GSTM1, and GSTT1 genes with levels of DNA damage in peripheral blood lymphocytes among coke-oven workers  

SciTech Connect (OSTI)

Accumulating evidence has shown that both DNA damage caused by the metabolites of polycyclic aromatic hydrocarbons (PAH) and genetic polymorphisms in PAH-metabolic genes contribute to individual susceptibility to PAH-induced carcinogenesis. However, the functional relevance of genetic polymorphisms in PAH-metabolic genes in exposed individuals is still unclear. In this study of 240 coke-oven workers (the exposed group) and 123 non-coke-oven workers (the control group), we genotyped for polymorphisms in the AhR, CYP1A1, GSTM1, and GSTT1 genes by PCR methods, and determined the levels of DNA damage in peripheral blood lymphocytes using the alkaline comet assay. It was found that the ln-transformed Olive tail moment (Olive TM) values in the exposed group were significantly higher than those in the control group. Furthermore, in the exposed group, the Olive TM values in subjects with the AhR Lys{sup 554} variant genotype were higher than those with the AhR Arg{sup 554}/Arg{sup 554} genotype. Similarly, the Olive TM values in the non-coke-oven workers with the CYP1A1 MspI CC + CT genotype were lower than the values of those with the CYP1A1 MspI TT genotype. However, these differences were not evident for GSTM1 and GSTT1. These results suggested that the polymorphism of AhR might modulate the effects of PAHs in the exposed group; however, the underlying molecular mechanisms by which this polymorphism may have affected the levels of PAH-induced DNA damage warrant further investigation.

Yongwen Chen; Yun Bai; Jing Yuan; Weihong Chen; Jianya Sun; Hong Wang; Huashan Liang; Liang Guo; Xiaobo Yang; Hao Tan; Yougong Su; Qingyi Wei; Tangchun Wu [Huazhong University of Science and Technology, Wuhan (China). Institute of Occupational Medicine and Ministry of Education Key Lab of Environment and Health

2006-09-15T23:59:59.000Z

25

Selecting the optimum coke pushing sequence  

SciTech Connect (OSTI)

The sequence of pushing coke ovens is one of the most important aspects of battery operation. The sequence must satisfy a number of technical and process conditions: (1) achieve maximum heating-wall life by avoiding destructive expansion pressure in freshly charged ovens and during pushing of the finished coke; (2) ensure uniform brickwork temperature and prevent overheating by compensating for the high thermal flux in freshly charged ovens due to accumulated heat in adjacent ovens that are in the second half of the coking cycle; (3) ensure the most favorable working conditions and safety for operating personnel; (4) provide additional opportunities for repair personnel to perform various types of work, such as replacing coke-machine rails, without interrupting coal production; (5) perform the maximum number of coke-machine operations simultaneously: pushing, charging, and cleaning doors, frames, and standpipe elbows; and (6) reduce electricity consumption by minimizing idle travel of coke machines.

V.T. Krivoshein; A.V. Makarov [ZAO Trest Koksokhimmontazh (Russian Federation)

2007-01-15T23:59:59.000Z

26

Modélisation thermomécanique d'un piédroit de four à coke.  

E-Print Network [OSTI]

??Inscrite dans le cadre du projet européen Coke Oven Operating Limits, cette thèse porte sur la modélisation thermomécanique d'un piédroit de cokerie. Le piédroit est… (more)

Landreau, Matthieu

2009-01-01T23:59:59.000Z

27

coking coal  

Science Journals Connector (OSTI)

coking coal [A caking coal suitable for the production of coke for metallurgical use] ? Kokskohle f, verkokbare Kohle

2014-08-01T23:59:59.000Z

28

Effects of preheating and highly heat-conductive brick on coke quality  

SciTech Connect (OSTI)

In replacing the coke ovens available currently, the introduction of a combined technique of a preheated coal charging method (preheating temperature:175 C) and the use of highly heat-conductive brick is under examination for raising the productivity of coke ovens. With such background, a study of the effects of this combined technique on the coke quality, especially the coke size was conducted. The experimental results revealed that the primary size of coke produced by the combined technique is noticeably larger than that of the coke made from wet coal and after five revolutions of drum (equivalent to mechanical impact given at a time of dropping from coke oven chamber to wharf), the coke size reduces even compared with an ordinary coke. This may be due to the fact that the coke produced by the combined technique includes a lot of fissures inside the coke lump.

Fukuda, K.; Arima, T. [Nippon Steel Corp., Chiba (Japan). Process Technology, Research Labs.

1995-12-31T23:59:59.000Z

29

About Beryllium  

Broader source: Energy.gov [DOE]

Information on what is Beryllium, the symptoms and health hazards associated with Beryllium contamination.

30

The mechanism of coking pressure generation II: Effect of high volatile matter coking coal, semi-anthracite and coke breeze on coking pressure and contraction  

Science Journals Connector (OSTI)

One of the most important aspects of the cokemaking process is to control and limit the coking pressure since excessive coking pressure can lead to operational problems and oven wall damage. Following on from a previous paper on plastic layer permeability we have studied the effect of contraction of semi-coke on coking pressure and the effect of organic additives on contraction. A link between contraction (or simulated contraction) outside the plastic layer and coking pressure was demonstrated. The interaction between this contraction, local bulk density around the plastic layer and the dependence of the permeability of the plastic layer on bulk density was discussed as possible mechanisms for the generation of coking pressure. The effect of blending either a high volatile matter coal or one of two semi-anthracites with low volatile matter, high coking pressure coals on the coking pressure of the binary blends has been explained using this mechanism.

Merrick Mahoney; Seiji Nomura; Koichi Fukuda; Kenji Kato; Anthony Le Bas; David R. Jenkins; Sid McGuire

2010-01-01T23:59:59.000Z

31

12.2 Coke Production 12.2.1 General  

E-Print Network [OSTI]

Metallurgical coke is produced by the destructive distillation of coal in coke ovens. Prepared coal is heated in an oxygen-free atmosphere (–coked–) until most volatile components in the coal are removed. The material remaining is a carbon mass called coke. Metallurgical coke is used in iron and steel industry processes (primarily in blast furnaces) to reduce iron ore to iron. Over 90 percent of the total coke production is dedicated to blast furnace operations. Foundry coke comprises most of the balance and is used by foundries in furnaces for melting metal and in the preparation of molds. Foundry coke production uses a different blend of coking coals, longer coking times, and lower coking temperatures relative to those used for metallurgical coke. Most coke plants are collocated with iron and steel production facilities, and the demand for coke generally corresponds with the production of iron and steel. There has been a steady decline in the number of coke plants over the past several years for many reasons, including a decline in the demand for iron/steel, increased production of steel by mini-mills (electric arc furnaces that do not use coke), and the lowering of the coke:iron ratio used in the blast furnace (e. g., increased use of pulverized coal injection). There were 18 coke plants operating in the U. S. in 2007.

unknown authors

32

Clean Production of Coke from Carbonaceous Fines  

SciTech Connect (OSTI)

In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

Craig N. Eatough

2004-11-16T23:59:59.000Z

33

Coke | OpenEI  

Open Energy Info (EERE)

18 18 Varnish cache server Browse Upload data GDR 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 2142278418 Varnish cache server Coke Dataset Summary Description UK National coal (and solid fuels and gases derived from processing coal) are published in Chapter 2 (Solid Fuels and Derived Gases) of the Digest of UK Energy Statistics (DUKES). Included here are the datasets for commodity balances (1998 - 2009); supply and consumption (2005 - 2009) of coal and other fuels (e.g. coke oven gas, blast furnace gas, benzole and tars, etc). Chapter 2 of the report is available: http://www.decc.gov.uk/assets/decc/Statistics/publications/dukes/308-dukes-2010-ch2.pdf Source UK Department of Energy and Climate Change (DECC)

34

Beryllium Testing  

Broader source: Energy.gov [DOE]

Beryllium is a naturally occurring metal and is not radioactive. Because of its properties, beryllium has been part of the atomic energy and nuclear weapons industries since the 1940s.

35

Priorities in the design of chemical shops at coke plants  

SciTech Connect (OSTI)

Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

36

Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas  

SciTech Connect (OSTI)

The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

37

Making a Solar Oven  

Broader source: Energy.gov [DOE]

Students make solar ovens. Student background information is provided. The expected outcome is that students will learn about solar energy transfer.

38

A novel technique for assessing the coking potential of coals/coal blends for non-recovery coke making process  

Science Journals Connector (OSTI)

Abstract In an effort to broaden the scope of coal selection, the authors have developed a novel procedure based on a coefficient, named as Composite Coking Potential (CCP). CCP value assesses the suitability of a coal/coal blend for producing coke of desired quality; measured by the parameter coke strength after reaction (CSR). The coking potential takes into account of various properties of the coals and their proportions in a given coal blend and convert them into a single value. This technique is having advantage since each of these parameters represents different aspects of the coking phenomena along with inter dependence of some of these parameters also exists. This makes the coal selection process extremely difficult and in majority of the cases, decision is taken based on experience. In this investigation, CCP model has been used for selecting the least expensive coal blends which will comply with the minimum coke quality requirements of blast furnace. The study confirms the inter relations between the CCP and the hot strength of coke i.e. CSR. Actual plant data of a non-recovery coke oven have been used for developing and validation of the model. The technique was successfully used in identifying cheaper coals for producing coke with desired quality.

H.P. Tiwari; P.K. Banerjee; V.K. Saxena

2013-01-01T23:59:59.000Z

39

Portable oven air circulator  

DOE Patents [OSTI]

A portable air circulating apparatus for use in cooking ovens which is used to create air currents in the oven which transfer heat to cooking foodstuffs to promote more rapid and more uniform cooking or baking, the apparatus including a motor, fan blade and housing of metallic materials selected from a class of heat resistant materials.

Jorgensen, Jorgen A. (Bloomington, MN); Nygren, Donald W. (Minneapolis, MN)

1983-01-01T23:59:59.000Z

40

Gas treatment and by-products recovery of Thailand`s first coke plant  

SciTech Connect (OSTI)

Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

Diemer, P.E.; Seyfferth, W. [Krupp Uhde GmbH, Dortmund (Germany)

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Method for welding beryllium  

DOE Patents [OSTI]

A method is provided for joining beryllium pieces which comprises: depositing aluminum alloy on at least one beryllium surface; contacting that beryllium surface with at least one other beryllium surface; and welding the aluminum alloy coated beryllium surfaces together. The aluminum alloy may be deposited on the beryllium using gas metal arc welding. The aluminum alloy coated beryllium surfaces may be subjected to elevated temperatures and pressures to reduce porosity before welding the pieces together. The aluminum alloy coated beryllium surfaces may be machined into a desired welding joint configuration before welding. The beryllium may be an alloy of beryllium or a beryllium compound. The aluminum alloy may comprise aluminum and silicon.

Dixon, Raymond D. (Los Alamos, NM); Smith, Frank M. (Espanola, NM); O'Leary, Richard F. (Los Alamos, NM)

1997-01-01T23:59:59.000Z

42

Chemicals from Coal Coking  

Science Journals Connector (OSTI)

Chemicals from Coal Coking ... Since 2009, she has been at INCAR-CSIC, researching the preparation and characterization of carbon materials (cokes and fibers) and nanomaterials (nanotubes and graphenes) and their catalytic, environmental, and energy applications. ... He then joined the Fundamental Studies Section of the British Coke (later Carbonization) Research Association, eventually becoming Head of Fundamental Studies. ...

Marcos Granda; Clara Blanco; Patricia Alvarez; John W. Patrick; Rosa Menéndez

2013-09-30T23:59:59.000Z

43

Innovative coke oven gas cleaning system for retrofit applications  

SciTech Connect (OSTI)

The EMP consists of a Compliance Monitoring Sampling Program and a Supplemental monitoring Sampling Program. The Compliance Monitoring Sampling Program will be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Project and during a summer and a winter period following the successful Startup and Operational phase of the completed Project. compliance monitoring consist of conducting all the sampling and observation programs associated with existing required Federal, State, and Local Regulations, Permits and Orders. These include air, water, and waste monitoring and OSHA and NESHAP monitoring. The Supplemental Monitoring Program will also be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Demonstration Facility and during a summer and a winter period following the successful startup and Operational phase of the completed Facility. Supplemental Monitoring includes sampling of 27 additional streams that are important to measure operational or environmental performance and impacts of the installation of the new COG treatment facilities.

Not Available

1992-09-21T23:59:59.000Z

44

Influence of the permeability of the coal plastic layer on coking pressure  

Science Journals Connector (OSTI)

Ten coals of different rank and coking pressure characteristics were chosen in order to study the time of occurrence of the phenomena that take place during the coking of a coal and the way they affect the generation of dangerous coking pressures. Parameters derived from thermoplastic, thermogravimetric and permeability tests were studied together with semicoke contraction and the coking pressure generated by the coals in a movable wall oven. It was found that for safe coals, the maximum evolution of volatile matter occurs near the temperature of maximum fluidity. The position of the maximum rate of volatile matter evolution with respect to the zone of low permeability varies depending on the coking pressure characteristics of the coals. In addition, the relationship between the period of low permeability to the resolidification temperature may serve to indicate the degree of dangerousness of a coal. The fissure pattern of the semicoke was found to be related to the coking pressure and semicoke contraction.

M.D. Casal; E. Díaz-Faes; R. Alvarez; M.A. Díez; C. Barriocanal

2006-01-01T23:59:59.000Z

45

Interim Chronic Beryllium Disease  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

Establishes Departmental expectations for addressing chronic beryllium disease throughout the Department until a Departmental rule on beryllium is promulgated. This Notice was replaced by final rule 10 CFR Part 850, Chronic Beryllium Disease Prevention Program, published December 8, 1999.

1999-12-08T23:59:59.000Z

46

Relationship between coking pressure generated by coal blends and the composition of their primary tars  

Science Journals Connector (OSTI)

Four coals that develop different pressures during the coking process were selected together with 10 blends (7 binary and 3 ternary) prepared with the same coals. Their semicoke contraction/expansion was measured by means of two tests (the Koppers-INCAR and the sole heated oven) and the variation in coking pressure during coking was determined in a movable wall oven. The coals and blends were then pyrolysed and the tars were analysed by gas chromatography (GC-FID–MS). The additivity law was applied to the properties used to evaluate the dangerousness of the blends and to the composition of the tar produced from the blends. Afterwards, the composition of the tar was studied in relation to contraction/expansion and the coking pressure generated by the coals and blends.

C. Barriocanal; M.A. Díez; R. Alvarez; M.D. Casal

2009-01-01T23:59:59.000Z

47

Blast furnace coke quality in relation to petroleum coke addition  

SciTech Connect (OSTI)

The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Sirgado, M. [ENSIDESA, Aviles (Spain)

1995-12-01T23:59:59.000Z

48

Improved cost calculations of coke-oven gas at coke plants  

Science Journals Connector (OSTI)

It is important to develop new methods of determining the costs of individual products within a complex process, ... to determine, with maximum precision, the direct costs of each stage of the production process ...

S. V. Vashchilin; T. V. Osipovich; T. A. Ermolenko; E. I. Kotlyarov…

2009-04-01T23:59:59.000Z

49

100% Pet coke or pet coke blends combustion  

SciTech Connect (OSTI)

Information is outlined on the combustion of 100 percent petroleum coke or petroleum coke blends. Data are presented on NISCO overviews; fuel (coke) characteristics; delayed coke analysis (1995-96); limestone characteristics/effects; limestone preparation; ash characteristics; vortex finders; agglomerization; and NISCO performance results.

Swindle, D.L.

1996-12-31T23:59:59.000Z

50

Scanned Beryllium.pub  

Broader source: Energy.gov (indexed) [DOE]

Beryllium Oxide Operations at the Beryllium Oxide Operations at the Y-12 National Security Complex DOE/IG-0595 April 2003 Beryllium Oxide Operations Details of Finding ........................................................................1 Recommendations and Comments .............................................3 Appendices 1. Objective, Scope, and Methodology ......................................4 2. Management Comments ........................................................5 BERYLLIUM OXIDE OPERATIONS AT THE Y-12 NATIONAL SECURITY COMPLEX TABLE OF CONTENTS Page 1 Status of Beryllium Oxide Operations Much of the manufacturing equipment and facilities used for beryllium oxide operations were spread across the Y-12 site and, in some cases,

51

Covered Product Category: Commercial Ovens  

Broader source: Energy.gov [DOE]

The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial ovens, which is a product category covered by the ENERGY STAR program.

52

Beryllium Testing | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Beryllium Testing Beryllium Testing Beryllium Testing Beryllium is a naturally occurring metal and is not radioactive. Because of its properties, beryllium has been part of the atomic energy and nuclear weapons industries since the 1940s. Exposure to beryllium and certain beryllium compounds can result in beryllium sensitization, which may develop into a disease of the lungs called chronic beryllium disease (CBD). Beryllium sensitization is an "allergic" condition to beryllium that can develop primarily after a person breathes air containing beryllium mists, dusts, and fumes. Even brief or small exposures to beryllium can lead to sensitization and/or CBD. However, most people exposed to beryllium will NOT get the disease. Other beryllium-related disorders can affect the skin,

53

Influence of coal preparation and coking conditions on coke reactivity  

Science Journals Connector (OSTI)

The influence of various technological factors on the high-temperature properties of coke is investigated. It is found that factors facilitating an orderly organic structure of the coke (fine grinding and comp...

D. V. Miroshnichenko

2009-02-01T23:59:59.000Z

54

Oven wall panel construction  

DOE Patents [OSTI]

An oven roof or wall is formed from modular panels, each of which comprises an inner fabric and an outer fabric. Each such fabric is formed with an angle iron framework and somewhat resilient tie-bars or welded at their ends to flanges of the angle irons to maintain the inner and outer frameworks in spaced disposition while minimizing heat transfer by conduction and permitting some degree of relative movement on expansion and contraction of the module components. Suitable thermal insulation is provided within the module. Panels or skins are secured to the fabric frameworks and each such skin is secured to a framework and projects laterally so as slidingly to overlie the adjacent frame member of an adjacent panel in turn to permit relative movement during expansion and contraction.

Ellison, Kenneth (20 Avondale Cres., Markham, CA); Whike, Alan S. (R.R. #1, Caledon East, both of Ontario, CA)

1980-04-22T23:59:59.000Z

55

Modified coal batch in coking  

Science Journals Connector (OSTI)

The influence of volatile products from low-metamorphic poorly clinkering G coal on plasticmass formation in rammed batch during coking is considered. An experimental batch of modified coke has been produced at P...

A. G. Starovoit; E. I. Malyi; M. S. Chemerinskii; M. A. Starovoit…

2013-05-01T23:59:59.000Z

56

Met coke world summit 2005  

SciTech Connect (OSTI)

Papers are presented under the following session headings: industry overview and market outlook; coke in the Americas; the global coke industry; and new developments. All the papers (except one) only consist of a copy of the overheads/viewgraphs.

NONE

2005-07-01T23:59:59.000Z

57

Former Worker Program - Beryllium Testing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Beryllium Testing Beryllium Testing Former Worker Medical Screening Program (FWP) Beryllium is a naturally occurring metal and is not radioactive. Because of its properties, beryllium has been part of the atomic energy and nuclear weapons industries since the 1940s. Exposure to beryllium and certain beryllium compounds can result in beryllium sensitization, which may develop into a disease of the lungs called chronic beryllium disease (CBD). Beryllium sensitization is an "allergic" condition to beryllium that can develop primarily after a person breathes air containing beryllium mists, dusts, and fumes. Even brief or small exposures to beryllium can lead to sensitization and/or CBD. However, most people exposed to beryllium will NOT get the disease. Other beryllium-related disorders can affect the skin, liver, spleen, heart, eye, or kidney. These disorders often occur in the presence of CBD.

58

Coking and gasification process  

DOE Patents [OSTI]

An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

1986-01-01T23:59:59.000Z

59

Coke and Coal Research  

Science Journals Connector (OSTI)

... A. Mott at the University of Sheffield, are concerned with problems affecting the hard coke industry, which enjoys facilities for large-scale experimentation through its member firms such as ... of the body organizing this work visited the Kingston and Fulham Laboratories of the British Coal Utilisation Research Association on September 9. Mr. J. G. Bennett, director of ...

1943-09-18T23:59:59.000Z

60

High coking value pitch  

SciTech Connect (OSTI)

A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

2014-06-10T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Investigation of Bonding Mechanism of Coking on Semi-coke from Lignite with Pitch and Tar  

Science Journals Connector (OSTI)

Investigation of Bonding Mechanism of Coking on Semi-coke from Lignite with Pitch and Tar ... Study on the coking mechanism of coal and coal tar pitches. ...

Vedat Arslan

2006-08-16T23:59:59.000Z

62

Ovenized microelectromechanical system (MEMS) resonator  

DOE Patents [OSTI]

An ovenized micro-electro-mechanical system (MEMS) resonator including: a substantially thermally isolated mechanical resonator cavity; a mechanical oscillator coupled to the mechanical resonator cavity; and a heating element formed on the mechanical resonator cavity.

Olsson, Roy H; Wojciechowski, Kenneth; Kim, Bongsang

2014-03-11T23:59:59.000Z

63

Convection automated logic oven control  

SciTech Connect (OSTI)

For the past few years, there has been a greater push to bring more automation to the cooling process. There have been attempts at automated cooking using a wide range of sensors and procedures, but with limited success. The authors have the answer to the automated cooking process; this patented technology is called Convection AutoLogic (CAL). The beauty of the technology is that it requires no extra hardware for the existing oven system. They use the existing temperature probe, whether it is an RTD, thermocouple, or thermistor. This means that the manufacturer does not have to be burdened with extra costs associated with automated cooking in comparison to standard ovens. The only change to the oven is the program in the central processing unit (CPU) on the board. As for its operation, when the user places the food into the oven, he or she is required to select a category (e.g., beef, poultry, or casseroles) and then simply press the start button. The CAL program then begins its cooking program. It first looks at the ambient oven temperature to see if it is a cold, warm, or hot start. CAL stores this data and then begins to look at the food`s thermal footprint. After CAL has properly detected this thermal footprint, it can calculate the time and temperature at which the food needs to be cooked. CAL then sets up these factors for the cooking stage of the program and, when the food has finished cooking, the oven is turned off automatically. The total time for this entire process is the same as the standard cooking time the user would normally set. The CAL program can also compensate for varying line voltages and detect when the oven door is opened. With all of these varying factors being monitored, CAL can produce a perfectly cooked item with minimal user input.

Boyer, M.A.; Eke, K.I. [Apollo U.S.A. Inc., Orlando, FL (United States)] [Apollo U.S.A. Inc., Orlando, FL (United States)

1998-03-01T23:59:59.000Z

64

Design and construction of coke battery 1A at Radlin coke plant, Poland  

SciTech Connect (OSTI)

In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos'kova; N.I. Shkol'naya; V.V. Derevich; A.S. Grankin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

65

Factors influencing coke gasification with carbon dioxide.  

E-Print Network [OSTI]

??Of all coke properties the influence of the catalytic mineral matter on reactivity of metallurgical cokes is least understood. There is limited information about the… (more)

Grigore, Mihaela

2007-01-01T23:59:59.000Z

66

Coke from coal and petroleum  

DOE Patents [OSTI]

A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

1981-01-01T23:59:59.000Z

67

Definition: Petroleum coke | Open Energy Information  

Open Energy Info (EERE)

coke coke Jump to: navigation, search Dictionary.png Petroleum coke A residue high in carbon content and low in hydrogen that is the final product of thermal decomposition in the condensation process in cracking (breaking of carbon-carbon bonds). This product is reported as marketable coke or catalyst coke.Coke from petroleum has a heating value of 6.024 million Btu per barrel.[1] View on Wikipedia Wikipedia Definition Petroleum coke (often abbreviated Pet coke or petcoke) is a carbonaceous solid derived from oil refinery coker units or other cracking processes. Other coke has traditionally been derived from coal. This coke can either be fuel grade (high in sulphur and metals) or anode grade (low in sulphur and metals). The raw coke directly out of the coker is often

68

Build a Pizza Box Solar Oven  

K-12 Energy Lesson Plans and Activities Web site (EERE)

Check out this staightforward lesson, that can be adapted for all grade levels, on how to build a solar oven.

69

Beryllium Manufacturing Processes  

SciTech Connect (OSTI)

This report is one of a number of reports that will be combined into a handbook on beryllium. Each report covers a specific topic. To-date, the following reports have been published: (1) Consolidation and Grades of Beryllium; (2) Mechanical Properties of Beryllium and the Factors Affecting these Properties; (3) Corrosion and Corrosion Protection of Beryllium; (4) Joining of Beryllium; (5) Atomic, Crystal, Elastic, Thermal, Nuclear, and other Properties of Beryllium; and (6) Beryllium Coating (Deposition) Processes and the Influence of Processing Parameters on Properties and Microstructure. The conventional method of using ingot-cast material is unsuitable for manufacturing a beryllium product. Beryllium is a highly reactive metal with a high melting point, making it susceptible to react with mold-wall materials forming beryllium compounds (BeO, etc.) that become entrapped in the solidified metal. In addition, the grain size is excessively large, being 50 to 100 {micro}m in diameter, while grain sizes of 15 {micro}m or less are required to meet acceptable strength and ductility requirements. Attempts at refining the as-cast-grain size have been unsuccessful. Because of the large grain size and limited slip systems, the casting will invariably crack during a hot-working step, which is an important step in the microstructural-refining process. The high reactivity of beryllium together with its high viscosity (even with substantial superheat) also makes it an unsuitable candidate for precision casting. In order to overcome these problems, alternative methods have been developed for the manufacturing of beryllium. The vast majority of these methods involve the use of beryllium powders. The powders are consolidated under pressure in vacuum at an elevated temperature to produce vacuum hot-pressed (VHP) blocks and vacuum hot-isostatic-pressed (HIP) forms and billets. The blocks (typically cylindrical), which are produced over a wide range of sizes (up to 183 cm dia. by 61 cm high), may be cut or machined into parts or be thermomechanically processed to develop the desired microstructure, properties, and shapes. Vacuum hot-isostatic pressing and cold-isostatic pressing (CIP) followed by sintering and possibly by a final HIP'ing (CIP/Sinter/HIP) are important in their use for the production of near net-shaped parts. For the same starting powder, a HIP'ed product will have less anisotropy than that obtained for a VHP'ed product. A schematic presentation illustrating the difference between VHP'ing and HIP'ing is shown in Figure I-1. The types of powders and the various beryllium grades produced from the consolidated powders and their ambient-temperature mechanical properties were presented in the consolidation report referred to above. Elevated-temperature properties and the effect of processing variables on mechanical properties are described in the mechanical properties report. Beryllium can also be deposited as coatings as well as freestanding forms. The microstructure, properties, and various methods used that are related to the deposition of beryllium are discussed in the report on beryllium coatings.

Goldberg, A

2006-06-30T23:59:59.000Z

70

Thermodynamics of water superheated in the microwave oven  

Science Journals Connector (OSTI)

Water is conveniently heated above its normal boiling point in a microwave oven in a glass microwave oven teapot. ...

B. H. Erné; Penny Snetsinger

2000-10-01T23:59:59.000Z

71

Research on Coal and Coke  

Science Journals Connector (OSTI)

... THE third annual report of the Northern Coke Research Committee records the many-sided activities of its staff working in the Armstrong College ... activities of its staff working in the Armstrong College, Newcastle, on problems of the coals and ...

1932-10-22T23:59:59.000Z

72

Characteristics of coking coal burnout  

SciTech Connect (OSTI)

An attempt was made to clarify the characteristics of coking coal burnout by the morphological analysis of char and fly ash samples. Laboratory-scale combustion testing, simulating an ignition process, was carried out for three kinds of coal (two coking coals and one non-coking coal for reference), and sampled chars were analyzed for size, shape and type by image analysis. The full combustion process was examined in industrial-scale combustion testing for the same kinds of coal. Char sampled at the burner outlet and fly ash at the furnace exit were also analyzed. The difference between the char type, swelling properties, agglomeration, anisotropy and carbon burnout were compared at laboratory scale and at industrial scale. As a result, it was found that coking coals produced chars with relatively thicker walls, which mainly impeded char burnout, especially for low volatile coals.

Nakamura, M. [Ishikawajima-Harima Heavy Industries Co., Ltd., Tokyo (Japan); Bailey, J.G. [Univ. of Newcastle, New South Wales (Australia)

1996-12-31T23:59:59.000Z

73

Influence of petroleum coking additive on the quality of coal batch, coke, and tar  

Science Journals Connector (OSTI)

Given the shortage of coal with good coking properties, a petroleum coking additive is introduced in coal batch so as to expand the range of plasticity. This additive improves coke quality in every respect, excep...

I. I. Mel’nikov; V. M. Kryachuk; D. A. Mezin; A. A. Gorbunov…

2011-12-01T23:59:59.000Z

74

Evaluation of coal and its influence on coke quality and the coking process  

Science Journals Connector (OSTI)

The evaluation of coal batch is considered, along with its influence on coke quality and the coking properties. The quality of the coal available for coking at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat is ...

G. R. Gainieva; V. I. Byzova; N. N. Nazarov; L. D. Nikitin…

2008-10-01T23:59:59.000Z

75

Estimating Coke and Pepsi's Price and Advertising Strategies  

E-Print Network [OSTI]

Strategy Distributions for Coke (First Quarter 1977) a)Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE ADVERTISINGEconomics July, 1998 Estimating Coke and Pepsi’s Price and

Golan, Amos; Karp, Larry S.; Perloff, Jeffrey M.

1998-01-01T23:59:59.000Z

76

Experimental study of elastoplastic mechanical properties of coke drum materials.  

E-Print Network [OSTI]

??Coke drums are vertical pressure vessels used in the delayed coking process in petroleum refineries. Significant temperature variation during the delayed coking process causes the… (more)

Chen, Jie

2010-01-01T23:59:59.000Z

77

New coke-sorting system at OAO Koks  

SciTech Connect (OSTI)

A new coke-sorting system has been introduced at OAO Koks. It differs from the existing system in that it has no bunkers for all-purpose coke but only bunkers for commercial coke. In using this system with coke from battery 4, the crushing of the coke on conveyer belts, at roller screens, and in the commercial-coke bunkers is studied. After installing braking elements in the coke path, their effectiveness in reducing coke disintegration and improving coke screening is investigated. The granulometric composition and strength of the commercial coke from coke battery 3, with the new coke-sorting system, is evaluated.

B.Kh. Bulaevskii; V.S. Shved; Yu.V. Kalimin; S.D. Filippov [OAO Koks, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

78

Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001  

SciTech Connect (OSTI)

This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

Jin, H.G.; Sun, S.; Han, W.; Gao, L. [Chinese Academy of Sciences, Beijing (China)

2009-09-15T23:59:59.000Z

79

Utilization of coke and functionalized coke-based composite for uptake of heavy metals from wastewater .  

E-Print Network [OSTI]

??This study investigated the functionalization of coke particles and their utilization for the preparation of coke-polymer composite. Looking at the possibility of using it for… (more)

Mdlalose, Lindani Mbalenhle

2014-01-01T23:59:59.000Z

80

Beryllium-Associated Worker Registry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Beryllium-Associated Worker Registry Beryllium-Associated Worker Registry The Office of Domestic and International Health Studies supports the operation of a surveillance registry of current workers who are exposed to beryllium in their current job, or may have been exposed to beryllium in the past from work conducted at a DOE site. The goal of the registry is to determine the incidence and prevalence of beryllium sensitization and chronic beryllium disease (CBD). The data will be analyzed to better understand CBD and to identify those at risk. Another goal is to monitor and evaluate the effectiveness of DOE's Chronic Beryllium Disease Prevention Program. Current Worker Medical Surveillance Program Screening Results (Data Cumulative through September 2011) Related Documents and Links

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Russian coking coal in 2008 and 2009  

Science Journals Connector (OSTI)

Coal resources and coke production in the second half of 2009 ... are considered. The unsuitability of the available coal for the production of high-strength coke is analyzed.

B. P. Kiselev

2010-10-01T23:59:59.000Z

82

Technological value of coal used for coking  

Science Journals Connector (OSTI)

The technological value of coal used for coking is analyzed, with particular attention to clinkering coal, the coke group, and lean additives, as well as G and GZhO coal. A relation is established between the tec...

A. S. Stankevich; V. S. Stankevich

2013-09-01T23:59:59.000Z

83

Oxidized coal in coking: A review  

Science Journals Connector (OSTI)

A literature review shows that the oxidation of coal changes its granulometric composition, packing density, ... clinkering properties, the quality of the resulting coke, and the yield of coking byproducts. On ac...

N. A. Desna; D. V. Miroshnichenko

2011-05-01T23:59:59.000Z

84

Russian coking coal in 2008 and 2009  

Science Journals Connector (OSTI)

The distribution and quality of Russian coal and coke resources are compared for periods before (the ... definition and determination of the technological value of coal. Analysis of coke strength suggests that, i...

B. P. Kiselev

2009-12-01T23:59:59.000Z

85

Coal fractionation by density for coking purposes  

Science Journals Connector (OSTI)

Scarce coal with good coking properties may be obtained by separating less valuable coal into different density fractions. The use of valuable fractions released in enrichment ensures optimal coking-batch composi...

S. G. Gagarin

2010-09-01T23:59:59.000Z

86

Trends in the automation of coke production  

SciTech Connect (OSTI)

Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

87

New Energy Efficiency Standards for Microwave Ovens to Save Consumers...  

Energy Savers [EERE]

New Energy Efficiency Standards for Microwave Ovens to Save Consumers on Energy Bills New Energy Efficiency Standards for Microwave Ovens to Save Consumers on Energy Bills May 31,...

88

Energy Efficiency Standards for Microwave Ovens Saves Consumers...  

Energy Savers [EERE]

Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and Updates the Social Cost of Carbon Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy...

89

Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine  

SciTech Connect (OSTI)

The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

2007-03-15T23:59:59.000Z

90

Coke–pitch interactions during anode preparation  

Science Journals Connector (OSTI)

Abstract The information on the interactions between coke and pitch is of great value for the aluminum industry. This information can help choose the suitable coke and pitch pairs as well as the appropriate mixing parameters to be used during the production of anodes. In this study, the interaction mechanisms of pitch and coke at the mixing stage were studied by a sessile-drop test using two coal-tar pitches as the liquid and three petroleum cokes as the substrate. The results showed that the coke–pitch interactions are related to both pitch and coke chemical compositions. The contact angle of different coke–pitch systems decreased with increasing time and temperature. At high temperatures, decreasing the pitch viscosity facilitated the spreading of pitch and its penetration into the coke bed. The chemical behavior of petroleum cokes and coal tar pitches were studied using the FT-IR spectroscopy and XPS. The results showed that the wettability behavior of cokes by pitches depends on their physical properties as well as the presence of surface functional groups of coke and pitch which can form chemical bonds.

Arunima Sarkar; Duygu Kocaefe; Yasar Kocaefe; Dilip Sarkar; Dipankar Bhattacharyay; Brigitte Morais; Jérôme Chabot

2014-01-01T23:59:59.000Z

91

China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and in Selected Provinces  

E-Print Network [OSTI]

Coal Washed Coal Coke Coke Oven Gas Other Gas Other CokingTJ) Coal Coke Coke Oven Gas Other Gas Other Coking Products

Lu, Hongyou

2013-01-01T23:59:59.000Z

92

Blast-furnace smelting with the injection of natural gas and coke-oven gas  

Science Journals Connector (OSTI)

A multizone mathematical model developed at Nekrasov Institute of Ferrous Metallurgy reveals the internal relations between the processes in a blast furnace. Using this model, the smelting processes and parameter...

I. G. Tovarovskii; A. E. Merkulov

2011-06-01T23:59:59.000Z

93

Technical Basis for PNNL Beryllium Inventory  

SciTech Connect (OSTI)

The Department of Energy (DOE) issued Title 10 of the Code of Federal Regulations Part 850, “Chronic Beryllium Disease Prevention Program” (the Beryllium Rule) in 1999 and required full compliance by no later than January 7, 2002. The Beryllium Rule requires the development of a baseline beryllium inventory of the locations of beryllium operations and other locations of potential beryllium contamination at DOE facilities. The baseline beryllium inventory is also required to identify workers exposed or potentially exposed to beryllium at those locations. Prior to DOE issuing 10 CFR 850, Pacific Northwest Nuclear Laboratory (PNNL) had documented the beryllium characterization and worker exposure potential for multiple facilities in compliance with DOE’s 1997 Notice 440.1, “Interim Chronic Beryllium Disease.” After DOE’s issuance of 10 CFR 850, PNNL developed an implementation plan to be compliant by 2002. In 2014, an internal self-assessment (ITS #E-00748) of PNNL’s Chronic Beryllium Disease Prevention Program (CBDPP) identified several deficiencies. One deficiency is that the technical basis for establishing the baseline beryllium inventory when the Beryllium Rule was implemented was either not documented or not retrievable. In addition, the beryllium inventory itself had not been adequately documented and maintained since PNNL established its own CBDPP, separate from Hanford Site’s program. This document reconstructs PNNL’s baseline beryllium inventory as it would have existed when it achieved compliance with the Beryllium Rule in 2001 and provides the technical basis for the baseline beryllium inventory.

Johnson, Michelle Lynn

2014-07-09T23:59:59.000Z

94

Using coke-battery flue gas to dry coal batch before coking  

Science Journals Connector (OSTI)

The utilization of heat from coke-battery flue gases and other potential secondary energy resources in drying coal batch prior to coking is considered. The main factors that influence ... . The reduction in moist...

A. Ya. Eremin; V. G. Mishchikhin; S. G. Stakheev; R. R. Gilyazetdinov…

2011-03-01T23:59:59.000Z

95

Technological value of coal concentrates for coking  

Science Journals Connector (OSTI)

Options are outlined for calculating the technological value of coal and coal concentrates in the context of contractual obligations and the quality of the coke produced.

E. N. Stepanov; G. V. Larin; A. E. Stepanova; I. V. Semiokhina

2010-02-01T23:59:59.000Z

96

Estimating Coke and Pepsi's price and advertising strategies  

E-Print Network [OSTI]

Working Paper No. 789 ESTIMATING COKE AND PEPSI’ PRICE S ANDand Advertising Strategies: Coke and Pepsi) by Amos Golan,Revised, March 1999 Estimating Coke and Pepsi’s Price and

Golan, Amos; Karp, Larry; Perloff, Jeffrey M.

1999-01-01T23:59:59.000Z

97

Communicating Health Risks Working Safely With Beryllium | Department...  

Broader source: Energy.gov (indexed) [DOE]

Communicating Health Risks Working Safely With Beryllium Communicating Health Risks Working Safely With Beryllium April 2002 Training Reference for Beryllium Workers and Managers...

98

The INEL beryllium multiplication experiment  

SciTech Connect (OSTI)

The experiment to measure the multiplication of 14-MeV neutrons in bulk beryllium has been completed. The experiment consists of determining the ratio of {sup 56}Mn activities induced in a large manganese bath by a central 14-MeV neutron source, with and without a beryllium sample surrounding the source. In the manganese bath method a neutron source is placed at the center of a totally-absorbing aqueous solution of MnSo{sub 4}. The capture of neutrons by Mn produces a {sup 56}Mn activity proportional to the emission rate of the source. As applied to the measurement of the multiplication of 14- MeV neutrons in bulk beryllium, the neutron source is a tritium target placed at the end of the drift tube of a small deuteron accelerator. Surrounding the source is a sample chamber. When the sample chamber is empty, the neutrons go directly to the surrounding MnSO{sub 4} solution, and produce a {sup 56}Mn activity proportional to the neutron emission rate. When the chamber contains a beryllium sample, the neutrons first enter the beryllium and multiply through the (n,2n) process. Neutrons escaping from the beryllium enter the bath and produce a {sup 56}Mn activity proportional to the neutron emission rate multiplied by the effective value of the multiplication in bulk beryllium. The ratio of the activities with and without the sample present is proportional to the multiplication value. Detailed calculations of the multiplication and all the systematic effects were made with the Monte Carlo program MCNP, utilizing both the Young and Stewart and the ENDF/B-VI evaluations for beryllium. Both data sets produce multiplication values that are in excellent agreement with the measurements for both raw and corrected values of the multiplication. We conclude that there is not real discrepancy between experimental and calculated values for the multiplication of neutrons in bulk beryllium. 12 figs., 11 tabs., 18 refs.

Smith, J.R.; King, J.J.

1991-03-01T23:59:59.000Z

99

Interaction of low-metamorphic coal components in coking batch  

Science Journals Connector (OSTI)

The interaction of low-metamorphic coal components in coking batch during pyrolysis is studied. The characteristics of the resulting coke are presented, and the partial hydrogenation is...

E. I. Malyi; A. S. Koverya; M. A. Starovoit

2010-08-01T23:59:59.000Z

100

Clinkering properties of rammed coking coal and coal batches  

Science Journals Connector (OSTI)

The clinkering properties of rammed coking coal and coal batches are investigated. There is a close relation between the clinkering properties and coke quality.

V. M. Shmal’ko; M. A. Solov’ev

2009-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Strength of the coke fillers of carbon materials  

SciTech Connect (OSTI)

Relationships between the ultimate compression strengths of coke fillers for carbon materials determined by various techniques and structures, final coke treatment temperatures, etc., are considered.

V.S. Ostrovskii [Research Institute of Structural Graphite Materials, Moscow (Russian Federation)

2008-12-15T23:59:59.000Z

102

New designs in the reconstruction of coke-sorting systems  

SciTech Connect (OSTI)

In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

A.S. Larin; V.V. Demenko; V.L. Voitanik [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

103

Beryllium Vender Screening Program | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Worker » Former Worker Program » Beryllium Worker » Former Worker Program » Beryllium Vender Screening Program Beryllium Vender Screening Program In February 2005, DOE expanded the beryllium screening program to include former employees of defunct DOE beryllium vendors who were employed with these companies while they performed work for DOE. This change was made to ensure that workers who no longer have an employer to turn to for beryllium disease testing could receive this important screening. DOE will offer these individuals a blood test at no cost to check for beryllium sensitization. DOE will pay for both the costs of drawing the blood and the analysis of the blood. If a screened individual receives an abnormal test for beryllium sensitization, they can receive medical monitoring for beryllium disease

104

Oven Baked Sweet Potato Fries Ingredients  

E-Print Network [OSTI]

Oven Baked Sweet Potato Fries Ingredients: Vegetable cooking spray 1 1/2 pounds sweet potato (about spray a 10 x 14 cookie sheet with non-stick cooking spray. 2. Scrub potatoes under tap water with a vegetable brush. With a knife remove any bad spots or defects on the potato. Do not peel. 3. On a cutting

Liskiewicz, Maciej

105

Determination of electrical resistivity of dry coke beds  

SciTech Connect (OSTI)

The electrical resistivity of the coke bed is of great importance when producing FeMn, SiMn, and FeCr in a submerged arc furnace. In these processes, a coke bed is situated below and around the electrode tip and consists of metallurgical coke, slag, gas, and metal droplets. Since the basic mechanisms determining the electrical resistivity of a coke bed is not yet fully understood, this investigation is focused on the resistivity of dry coke beds consisting of different carbonaceous materials, i.e., coke beds containing no slag or metal. A method that reliably compares the electrical bulk resistivity of different metallurgical cokes at 1500{sup o} C to 1600{sup o}C is developed. The apparatus is dimensioned for industrial sized materials, and the electrical resistivity of anthracite, charcoal, petroleum coke, and metallurgical coke has been measured. The resistivity at high temperatures of the Magnitogorsk coke, which has the highest resistivity of the metallurgical cokes investigated, is twice the resistivity of the Corus coke, which has the lowest electrical resistivity. Zdzieszowice and SSAB coke sort in between with decreasing resistivities in the respective order. The electrical resistivity of anthracite, charcoal, and petroleum coke is generally higher than the resistivity of the metallurgical cokes, ranging from about two to about eight times the resistivity of the Corus coke at 1450{sup o}C. The general trend is that the bulk resistivity of carbon materials decreases with increasing temperature and increasing particle size.

Eidem, P.A.; Tangstad, M.; Bakken, J.A. [NTNU, Trondheim (Norway)

2008-02-15T23:59:59.000Z

106

ORISE: Worker Health Studies - Beryllium Testing Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

BeLPT Process Diagram BeLPT Process Diagram Click image for larger view Oak Ridge Institute for Science Education Beryllium Testing Laboratory Beryllium is a metal that is...

107

Carol G. Cokely's recent Presentations Cokely, C. (2007). Incorporating Service Learing in to the AuD Curriculum. Invited  

E-Print Network [OSTI]

Carol G. Cokely's recent Presentations Cokely, C. (2007). Incorporating Service Learing in to the AuD Curriculum. Invited speaker, Teaching the Management of Hearing Loss, Pittsburgh, PA. Cokely, C, Pittsburgh, PA. Kricos, P.B., Weinstein, B., Lesner, S., Cokely, C., Milstein, D., & Chisolm, T. (2006) How

O'Toole, Alice J.

108

Delayed Coking of Decant Oil and Coal in a Laboratory-Scale Coking Unit  

Science Journals Connector (OSTI)

The fact that coke quality varies with the chemical composition of the precursor feedstock creates a significant incentive to examine the process of coking and how it relates to the composition of the feedstock. ... (7)?Derbyshire, F. J.; Odoerfer, G. A.; Rudnick, L. R.; Varghese, P.; Whitehurst, D. D. Fundamental studies in the conversion of coals to fuels of increased hydrogen content. ... Bituminous coal/petroleum co-cokes were produced by coking 4:1 blends of vacuum resid (VR)/coal and decant oil (DO)/coal at temperatures of 465 and 500 °C for reaction times of 12 and 18 h, under autogenous pressure in microautoclave reactors. ...

Ömer Gül; Leslie R. Rudnick; Harold H. Schobert

2006-05-18T23:59:59.000Z

109

Delayed coking of decant oil and coal in a laboratory-scale coking unit  

SciTech Connect (OSTI)

In this paper, we describe the development of a laboratory-scale delayed coker and present results of an investigation on the recovered liquid from the coking of decant oil and decant oil/coal mixtures. Using quantitative gas chromatography/mass spectroscopy (GC/MS) and {sup 1}H and {sup 13}C NMR, a study was made of the chemical composition of the distillate liquids isolated from the overheads collected during the coking and co-coking process. {sup 1}H and {sup 13}C NMR analyses of combined liquids from coking and co-coking did not show any substantial differences. These NMR results of coking and co-coking liquids agree with those of GC/MS. In these studies, it was observed that co-coking with coal resulted in a decrease in the paraffins contents of the liquid. The percentage of cycloparaffins, indenes, naphthalenes, and tetralins did not change significantly. In contrast, alkyl benzenes and polycyclic aromatic hydrocarbons in the distillate were higher in the co-coking experiments which may have resulted from the distillation of thermally cracked coal macromolecules and the contribution of these molecules to the overall liquid composition. 40 refs., 3 figs., 13 tabs.

Oemer Guel; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University Park, PA (United States). Energy Institute, C205 Coal Utilization Laboratory

2006-08-15T23:59:59.000Z

110

Market boundaries for coking-coal concentrates  

Science Journals Connector (OSTI)

The construction of geographic and commodity boundaries is considered in relation to the Russian market for coking-coal concentrates. In this market, uniform commodities ... construction of the market boundaries....

V. A. Brodskii

2011-05-01T23:59:59.000Z

111

Fundamentals of Delayed Coking Joint Industry Project  

SciTech Connect (OSTI)

Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

Michael Volk; Keith Wisecarver

2004-09-26T23:59:59.000Z

112

Fundamentals of Delayed Coking Joint Industry Project  

SciTech Connect (OSTI)

Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

Michael Volk; Keith Wisecarver

2003-09-26T23:59:59.000Z

113

Mozambique becomes a major coking coal exporter?  

SciTech Connect (OSTI)

In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

Ruffini, A.

2008-06-15T23:59:59.000Z

114

New and revised standards for coke production  

SciTech Connect (OSTI)

The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

115

Possibilities of coke manufacture in nonpollutant conditions  

SciTech Connect (OSTI)

The paper presents some possibilities to obtain coke briquettes from anthracite, using as binders petroleum pitch, wheat flour, cement, plaster, ashes from power-plants dried from the electrofilters. Specific thermal post-treatment were proposed for each case, such as: oxidation or heating at low temperatures (under 300 C). As a result the authors obtained coke briquettes to be used in small equipment, with no pollutant pyrogenetic treatment.

Barca, F.; Panaitescu, C.; Vidrighin, C.; Peleanu, I. [Politehnica Univ. Bucharest (Romania); Albastroiu, P. [S.C. ICEM S.A., Bucharest (Romania)

1994-12-31T23:59:59.000Z

116

Réactivité de l'anode et désulfuration : effet du niveau de calcination du coke.  

E-Print Network [OSTI]

??Les propriétés du coke et la performance des anodes sont affectées par le niveau de calcination du coke. Une densité de coke (VBD) élevée implique… (more)

Bergeron-Lagacé, Charles-Luc

2012-01-01T23:59:59.000Z

117

Physical, chemical and thermal changes of coals and coal maceral concentrates during coke formation.  

E-Print Network [OSTI]

??Research Doctorate - Doctor of Philosophy (PhD) The measured coke reactivity index (CRI) and coke strength after reaction (CSR) determined in experiments based on coke… (more)

Xie, Wei

2013-01-01T23:59:59.000Z

118

LLNS Beryllium Consent Order Fact Sheet  

Broader source: Energy.gov (indexed) [DOE]

- LLNS Beryllium Consent Order - LLNS Beryllium Consent Order SUMMARY OF CONSENT ORDER In November 2010, the U.S. Department of Energy (DOE) and the National Nuclear Security Administration (NNSA) issued a consent order to Lawrence Livermore National Security, LLC (LLNS) for deficiencies related to LLNS's implementation of DOE's Chronic Beryllium Disease Prevention Program (CBDPP) regulation at Lawrence Livermore National Laboratory. The consent order requires LLNS to implement corrective actions that will ensure LLNS meets DOE requirements for assessing and controlling beryllium hazards and minimizes potential worker exposures to legacy beryllium hazards in Laboratory buildings. Under the terms of the consent order, LLNS agrees to implement corrective actions that address the

119

Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant  

SciTech Connect (OSTI)

Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

120

Beryllium Technology Research in the United States  

SciTech Connect (OSTI)

While most active research involving beryllium in the United States remains tied strongly to biological effects, there are several areas of technology development in the last two years that should be mentioned. (1) Beryllium disposed of in soil vaults at the Idaho National Laboratory (INL) Radioactive Waste Management Complex (RWMC) has been encapsulated in-situ by high-temperature and pressure injection of a proprietary wax based material to inhibit corrosion. (2) A research program to develop a process for removing heavy metals and cobalt from irradiated beryllium using solvent extraction techniques has been initiated to remove components that prevent the beryllium from being disposed of as ordinary radioactive waste. (3) The JUPITER-II program at the INL Safety and Tritium Applied Research (STAR) facility has addressed the REDOX reaction of beryllium in molten Flibe (a mixture of LiF and BeF2) to control tritium, particularly in the form of HF, bred in the Flibe by reactions involving both beryllium and lithium. (4) Work has been performed at Los Alamos National Laboratory to produce beryllium high heat flux components by plasma spray deposition on macro-roughened substrates. Finally, (5) corrosion studies on buried beryllium samples at the RWMC have shown that the physical form of some of the corroded beryllium is very filamentary and asbestos-like. This form of beryllium may exacerbate the contraction of chronic beryllium disease.

Glen R. Longhurst; Robert A. Anderl; M. Kay Adleer-Flitton; Gretchen E. Matthern; Troy J. Tranter; Kendall J. Hollis

2005-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar  

SciTech Connect (OSTI)

In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

2006-10-15T23:59:59.000Z

122

Worker Environment Beryllium Characterization Study  

SciTech Connect (OSTI)

This report summarizes the conclusion of regular monitoring of occupied buildings at the Nevada Test Site and North Las Vegas facility to determine the extent of beryllium (Be) contamination in accordance with Judgment of Needs 6 of the August 14, 2003, “Minnema Report.”

NSTec Environment, Safety, Health & Quality

2009-12-28T23:59:59.000Z

123

Relationship between the technical parameters of cokes produced from blends of three Polish coals of different coking ability  

Science Journals Connector (OSTI)

The demand for metallurgical coke for blast furnaces is forcing the coking industry to look for new sources of coking coals. The physical and chemical parameters of coals used in coking blends determine the quality (reactivity and strength) of the finished cokes. This study examines the technical properties of the cokes produced from various blends of three Polish coals with different coking. These coals were collected from three mines: Zofiówka, Szczyg?owice, and Krupi?ski (Upper Silesian Coal Basin, Poland). The coal charges were coked in the laboratory scale, at temperatures of up to 1000 °C, in an inert atmosphere. The coke reactivity (index CRI) and the coke strength after reaction (CSR) were measured and correlated to the properties of parent coals using statistical analysis. The result of this study shows strong relationships between the concentration of the best coking coal (Zofiówka) in the blend and the CRI and CSR of the resulting coke. The CRI and CSR parameters for cokes obtained from single coals and from their blends show the additive character. This study also confirms the linear relationship between CRI and CSR parameters of the cokes.

A. Koszorek; M. Krzesi?ska; S. Pusz; B. Pilawa; B. Kwieci?ska

2009-01-01T23:59:59.000Z

124

Interactions among Different Fractions in the Thermoplastic State of Goonyella Coking Coal  

Science Journals Connector (OSTI)

An understanding of thermoplastic behavior in coking coal is essential in ascertaining appropriate procedures for the efficient conversion of slightly coking coals into good quality cokes. ... The conversion of coal into coke is detd. ...

Takahiro Yoshida; Toshimasa Takanohashi; Masashi Iino; Haruo Kumagai; Kenji Kato

2004-01-09T23:59:59.000Z

125

Hydrothermal Treatment of a Sub-bituminous Coal and Its Use in Coking Blends  

Science Journals Connector (OSTI)

Crucible coking determinations suggest that hydrothermal treatment can greatly increase the coke strength and the particle coke strength after reaction toward CO2 and decrease the coke reactivity when the hydrothermally treated coals were used in the coal blends instead of the raw coal. ... While the cokes from the crucible coking experiments were subjected to 800 rotations at a speed of 25 rpm, the weight percent of coke particles (>0.2 ... The coal charges were coked in the lab. ...

Hengfu Shui; Ye Wu; Zhicai Wang; Zhiping Lei; Changhui Lin; Shibiao Ren; Chunxiu Pan; Shigang Kang

2012-11-26T23:59:59.000Z

126

OVERVIEW OF BERYLLIUM SAMPLING AND ANALYSIS  

SciTech Connect (OSTI)

Because of its unique properties as a lightweight metal with high tensile strength, beryllium is widely used in applications including cell phones, golf clubs, aerospace, and nuclear weapons. Beryllium is also encountered in industries such as aluminium manufacturing, and in environmental remediation projects. Workplace exposure to beryllium particulates is a growing concern, as exposure to minute quantities of anthropogenic forms of beryllium may lead to sensitization and to chronic beryllium disease, which can be fatal and for which no cure is currently known. Furthermore, there is no known exposure-response relationship with which to establish a 'safe' maximum level of beryllium exposure. As a result, the current trend is toward ever lower occupational exposure limits, which in turn make exposure assessment, both in terms of sampling and analysis, more challenging. The problems are exacerbated by difficulties in sample preparation for refractory forms of beryllium, such as beryllium oxide, and by indications that some beryllium forms may be more toxic than others. This chapter provides an overview of sources and uses of beryllium, health risks, and occupational exposure limits. It also provides a general overview of sampling, analysis, and data evaluation issues that will be explored in greater depth in the remaining chapters. The goal of this book is to provide a comprehensive resource to aid personnel in a wide variety of disciplines in selecting sampling and analysis methods that will facilitate informed decision-making in workplace and environmental settings.

Brisson, M

2009-04-01T23:59:59.000Z

127

Elegest coal in coking batch at OAO EVRAZ ZSMK  

Science Journals Connector (OSTI)

The coking of batch with different proportions of Elegest coal from the Ulug-Khemsk Basin is investigated ... production conditions. The mechanical strength of the coke is improved when such coal is used in the b...

V. L. Osetkovskii; M. M. Naimark; V. G. Lupenko; A. E. Bazegskiy…

2013-03-01T23:59:59.000Z

128

Modification of poorly clinkering coal for use in coking  

Science Journals Connector (OSTI)

If coal is modified by the volatile products formed in pyrolysis, high-quality blast-furnace coke may be produced from batch with a smaller proportion of expensive clinkering coal. In such coking, the batch is mo...

E. I. Malyi

2014-03-01T23:59:59.000Z

129

Improving the preparation of coal batch for coking  

Science Journals Connector (OSTI)

Various methods of preparing coal for coking are analyzed. Laboratory experiments are conducted with a view to obtaining higher-quality coke from batch with a high content of poorly clinkering coal.

M. S. Chemerinskii; A. G. Starovoit; E. I. Malyi

2012-07-01T23:59:59.000Z

130

Coking of coal batch with different content of oxidized coal  

Science Journals Connector (OSTI)

The use of oxidized coal in coking batch increases the analytical moisture content and ... increases the oxygen content; reduces the gross coke yield and the yield of tar, benzene ... of carbon dioxide, pyrogenet...

D. V. Miroshnichenko; I. D. Drozdnik; Yu. S. Kaftan; N. B. Bidolenko…

2012-05-01T23:59:59.000Z

131

Kuznetsk Basin coking coal: Reserves and technological value  

Science Journals Connector (OSTI)

Reserves of Kuznetsk Basin coking coal are analyzed, in terms of rank composition and scope for coke production. The technological value of the coal is evaluated by the OOO VNITs Ugol...

V. P. Ivanov; V. Yu. Sushkov; A. A. Torgunakov; S. A. Pantykin

2008-09-01T23:59:59.000Z

132

Development of coke strength after reaction (CSR) at Dofasco  

SciTech Connect (OSTI)

In order to prevent coke degradation without detrimentally affecting blast furnace service life, Dofasco initiated a project to improve coke strength after reaction. The results of the program and Dofasco's prediction model are presented. 9 refs., 12 figs., 9 tabs.

T.W. Todoschuk; J.P. Price; J.F. Gransden

2004-03-01T23:59:59.000Z

133

Fundamentals of Delayed Coking Joint Industry Project  

SciTech Connect (OSTI)

The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

2003-02-07T23:59:59.000Z

134

Accepted Manuscript Title: Fuel Pyrolysis through Porous Media: Coke Formation  

E-Print Network [OSTI]

Accepted Manuscript Title: Fuel Pyrolysis through Porous Media: Coke Formation and Coupled effect. Gascoin, P. Gillard, M. Bouchez, J. Steelant, Fuel Pyrolysis through Porous Media: Coke Formation Coke Formation and Coupled effect on Permeability2 G. Fau1* , N. Gascoin1 , P. Gillard1 , M. Bouchez2

Paris-Sud XI, Université de

135

Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE  

E-Print Network [OSTI]

Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE AND ADVERTISING STRATEGIES (formerly Estimating Firms'Mixed Price and Advertising Strategies: Coke and Pepsi) by Amos Golan, Larry S. Karp. #12;Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M

Karp, Larry S.

136

2011 Beryllium-Associated Worker Registry Summary  

Broader source: Energy.gov [DOE]

The DOE Beryllium-Associated Worker Registry (BAWR) is a collection of health and exposure information of individuals potentially at risk for chronic beryllium disease (CBD) due to their work at DOE-owned or leased facilities. The BAWR is a risk management tool for sites to use in managing their CBD prevention programs and other risk management operations. Sites are encouraged to use their Registry data to evaluate beryllium exposure risks. (Reported data are cumulative through September 2011.)

137

2012 Beryllium-Associated Worker Registry Summary  

Broader source: Energy.gov [DOE]

The DOE Beryllium-Associated Worker Registry (BAWR) is a collection of health and exposure information of individuals potentially at risk for chronic beryllium disease (CBD) due to their work at DOE-owned or leased facilities. The BAWR is a risk management tool for sites to use in managing their CBD prevention programs and other risk management operations. Sites are encouraged to use their Registry data to evaluate beryllium exposure risks. (Reported data are cumulative through calendar year 2012.)

138

MANAGING BERYLLIUM IN NUCLEAR FACILITY APPLICATIONS  

SciTech Connect (OSTI)

Beryllium plays important roles in nuclear facilities. Its neutron multiplication capability and low atomic weight make it very useful as a reflector in fission reactors. Its low atomic number and high chemical affinity for oxygen have led to its consideration as a plasma-facing material in fusion reactors. In both applications, the beryllium and the impurities in it become activated by neutrons, transmuting them to radionuclides, some of which are long-lived and difficult to dispose of. Also, gas production, notably helium and tritium, results in swelling, embrittlement, and cracking, which means that the beryllium must be replaced periodically, especially in fission reactors where dimensional tolerances must be maintained. It has long been known that neutron activation of inherent iron and cobalt in the beryllium results in significant {sup 60}Co activity. In 2001, it was discovered that activation of naturally occurring contaminants in the beryllium creates sufficient {sup 14}C and {sup 94}Nb to render the irradiated beryllium 'Greater-Than-Class-C' for disposal in U.S. radioactive waste facilities. It was further found that there was sufficient uranium impurity in beryllium that had been used in fission reactors up to that time that the irradiated beryllium had become transuranic in character, making it even more difficult to dispose of. In this paper we review the extent of the disposal issue, processes that have been investigated or considered for improving the disposability of irradiated beryllium, and approaches for recycling.

R. Rohe; T. N. Tranter

2011-12-01T23:59:59.000Z

139

Beryllium Screening - Informed Choice Document | Department of...  

Office of Environmental Management (EM)

chronic beryllium disease (CBD), a legacy of the Department of Energy's (DOE) role in weapons production, have been increasing across the DOE complex. This trend has sparked...

140

Beryllium Vender Screening Program | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

through DOL's EEOICP. Former workers interested in medical screening can contact the Oak Ridge Institute of Science and Education at 1-866-219-3442. DOE beryllium vendor...

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Influence of the coking properties of coal batch on coke properties  

Science Journals Connector (OSTI)

At OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK), research is undertaken to improve the optimization of coking batch. The basic approach, proposed by...K opt..., which characterizes the ...

D. A. Zavalishin; L. S. Belaya; G. R. Gainieva; V. G. Lupenko

2009-10-01T23:59:59.000Z

142

Microsoft Word - Blue Cover Report - Beryllium Controls at LLNL  

Broader source: Energy.gov (indexed) [DOE]

Implementation of Beryllium Controls Implementation of Beryllium Controls at Lawrence Livermore National Laboratory DOE/IG-0851 June 2011 Department of Energy Washington, DC 20585 June 17, 2011 MEMORANDUM FOR THE SECRETARY FROM: Gregory H. Friedman Inspector General SUBJECT: INFORMATION: Audit Report on the "Implementation of Beryllium Controls at Lawrence Livermore National Laboratory" BACKGROUND The Department of Energy has a long history of using beryllium - a metal essential for nuclear operations and other processes. Exposure to beryllium can cause beryllium sensitization or even Chronic Beryllium Disease, an often debilitating, and sometimes fatal, lung condition. In December 1999, the Department established a Chronic Beryllium Disease Prevention Program

143

Hanford Facility Beryllium Fact Sheet Building Number/Name:  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Operations: NONE Basis for above information: Beryllium Characterization Report ADS Unit Building 2736ZB 512011 and reference information from the Beryllium Facility Assessment...

144

Improvements to the Oak Ridge National Laboratory Beryllium Program...  

Broader source: Energy.gov (indexed) [DOE]

Improvements to the Oak Ridge National Laboratory Beryllium Program Improvements to the Oak Ridge National Laboratory Beryllium Program August 2009 Presenter: Kevin Petherick,...

145

ORISE: Worker Health Studies - Beryllium Associated Worker Registry...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oak Ridge Institute for Science Education Beryllium Associated Worker Registry (BAWR) The Oak Ridge Institute for Science and Education (ORISE) maintains the Beryllium Associated...

146

Review of Beryllium Management Practices at Rocky Flats During...  

Broader source: Energy.gov (indexed) [DOE]

Beryllium Management Practices at Rocky Flats During Closure Operations Review of Beryllium Management Practices at Rocky Flats During Closure Operations Administrative and...

147

Los Alamos notifies employees, visitors of possible beryllium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

work, beryllium also is used in consumer items like golf clubs and recreational bicycle frames. Beryllium is a hazardous material in a particulate or finely powdered form....

148

Water protection in coke-plant design  

SciTech Connect (OSTI)

Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

G.I. Alekseev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

149

Reducing dust emissions at OAO Alchevskkoks coke battery 10A  

SciTech Connect (OSTI)

Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

T.F. Trembach; E.N. Lanina [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

150

Solar Oven, Take One: FAIL | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Solar Oven, Take One: FAIL Solar Oven, Take One: FAIL Solar Oven, Take One: FAIL June 15, 2011 - 11:56am Addthis Our homemade solar oven. | Courtesy of Moon Choe Our homemade solar oven. | Courtesy of Moon Choe Moon Choe EERE Summer Intern The first time I ever saw solar cookers was on the news in the summer of 2009 (though that would make it their winter, as I was living in Chile at the time), as part of a development project in the north, which is mostly desert. I had no idea solar cookers were so markedly simple in all various facets, such as appearance, use, and construction, and ever since then, it always remained on my to-do list to make one of my own. Another added benefit that I was unaware of is that a solar cooker works at any time of year, so long as it's receiving direct sunlight (i.e. not

151

Solar Oven, Take One: FAIL | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Solar Oven, Take One: FAIL Solar Oven, Take One: FAIL Solar Oven, Take One: FAIL June 15, 2011 - 11:56am Addthis Our homemade solar oven. | Courtesy of Moon Choe Our homemade solar oven. | Courtesy of Moon Choe Moon Choe EERE Summer Intern The first time I ever saw solar cookers was on the news in the summer of 2009 (though that would make it their winter, as I was living in Chile at the time), as part of a development project in the north, which is mostly desert. I had no idea solar cookers were so markedly simple in all various facets, such as appearance, use, and construction, and ever since then, it always remained on my to-do list to make one of my own. Another added benefit that I was unaware of is that a solar cooker works at any time of year, so long as it's receiving direct sunlight (i.e. not

152

RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS  

SciTech Connect (OSTI)

The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

2002-05-01T23:59:59.000Z

153

Relation between the coking-chamber height, the coking pressure, and the packing density of regular or partially briquetted coal batch  

Science Journals Connector (OSTI)

Since coking coal is characterized by both elasticity and ductility in the plastic state, the coal charge of coke furnaces that contains a plastic layer exerts pressure (coking pressure) on the chamber walls. The...

L. V. Kopeliovich; V. I. Sukhorukov; V. I. Shvetsov

2012-07-01T23:59:59.000Z

154

REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE  

SciTech Connect (OSTI)

Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effects of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and electrostatic precipitator (ESP) fly ash collection efficiency.

Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

1999-09-01T23:59:59.000Z

155

Process for synthesis of beryllium chloride dietherate  

DOE Patents [OSTI]

A low temperature method of producing beryllium chloride dietherate through the addition of hydrogen chloride gas to a mixture of beryllium metal in ether in a reaction vessel is described. A reflux condenser provides an exit for hydrogen produced form the reaction. A distillation condenser later replaces the reflux condenser for purifying the resultant product.

Bergeron, Charles (Baton Rouge, LA); Bullard, John E. (Kendall Park, NJ); Morgan, Evan (Lynchburg, VA)

1991-01-01T23:59:59.000Z

156

Guidance for Informed Choice on Beryllium Testing  

Broader source: Energy.gov (indexed) [DOE]

Beryllium Testing for Research and Beyond: The ABCs of the LPT Beryllium Testing for Research and Beyond: The ABCs of the LPT January 2007 Cases of chronic beryllium disease (CBD), a legacy of the Department of Energy's (DOE) role in weapons production, have been increasing across the DOE complex. This trend has sparked increased concern about this serious occupational illness. In a national effort to identify current and former workers who have CBD or are sensitized to beryllium and to better understand the illness, DOE has set up a number of medical surveillance and research programs for both current and former workers. The way that workers enroll in the programs and the information that they are given prior to participating in the beryllium lymphocyte proliferation testing (Be-LPT) vary depending on where and

157

BERYLLIUM MEASUREMENT IN COMMERCIALLY AVAILABLE WET WIPES  

SciTech Connect (OSTI)

Analysis for beryllium by fluorescence is now an established method which is used in many government-run laboratories and commercial facilities. This study investigates the use of this technique using commercially available wet wipes. The fluorescence method is widely documented and has been approved as a standard test method by ASTM International and the National Institute for Occupational Safety and Health (NIOSH). The procedure involves dissolution of samples in aqueous ammonium bifluoride solution and then adding a small aliquot to a basic hydroxybenzoquinoline sulfonate fluorescent dye (Berylliant{trademark} Inc. Detection Solution Part No. CH-2) , and measuring the fluorescence. This method is specific to beryllium. This work explores the use of three different commercial wipes spiked with beryllium, as beryllium acetate or as beryllium oxide and subsequent analysis by optical fluorescence. The effect of possible interfering metals such as Fe, Ti and Pu in the wipe medium is also examined.

Youmans-Mcdonald, L.

2011-02-18T23:59:59.000Z

158

Path Analysis of Biomarkers of Exposure and Early Biological Effects among Coke-Oven Workers Exposed to Polycyclic Aromatic Hydrocarbons  

Science Journals Connector (OSTI)

...8-diol of benzo(a)pyrene to more water-soluble trans-dihydrodiols, which...workers exposed to polycyclic aromatic hydrocarbons in engine repair workshops. Mutat Res...determination of exposure to polycyclic aromatic hydrocarbons. Int Arch Occup Environ Health 2002...

Li Qiu; Shuguang Leng; Zhongxu Wang; Yufei Dai; Yuxin Zheng; and Zengzhen Wang

2007-06-01T23:59:59.000Z

159

REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE  

SciTech Connect (OSTI)

A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

NONE

1998-09-01T23:59:59.000Z

160

Table 16. U.S. Coke Exports  

U.S. Energy Information Administration (EIA) Indexed Site

U.S. Coke Exports U.S. Coke Exports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 16. U.S. Coke Exports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Destination April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 162,796 79,217 201,795 242,013 340,944 -29.0 Canada* 73,859 17,837 112,348 91,696 161,596 -43.3 Mexico 88,535 60,517 86,721 149,052 176,163 -15.4 Other** 402 863 2,726 1,265 3,185 -60.3 South America Total 223 217 591 440 1,158 -62.0 Other** 223 217 591 440 1,158 -62.0 Europe Total 48,972 59,197 - 108,169 6 NM Other** 347 11,743 - 12,090 - - United Kingdom 48,625 47,454 - 96,079 6 NM Asia Total 317 553 633 870 4,778

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Table 21. U.S. Coke Imports  

U.S. Energy Information Administration (EIA) Indexed Site

U.S. Coke Imports U.S. Coke Imports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 21. U.S. Coke Imports (short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Origin April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 10,284 2,293 159,462 12,577 183,712 -93.2 Canada 3,009 2,293 159,462 5,302 183,712 -97.1 Panama 7,275 - - 7,275 - - South America Total 25,267 13,030 88,424 38,297 106,612 -64.1 Brazil - - 78,595 - 78,595 - Colombia 25,267 13,030 9,829 38,297 28,017 36.7 Europe Total 6,044 40,281 165,027 46,325 485,791 -90.5 Czech Republic - 170 - 170 - - Spain 363 - - 363 - - Ukraine 5,681 40,111 5,047 45,792 53,543 -14.5 United Kingdom

162

Coking properties of perhydrous low-rank vitrains. Influence of pyrolysis conditions  

E-Print Network [OSTI]

generally lead to increased coking potential of coals characterised in the resulting cokes by large sizes equivalent to natural coking coals, since the cokes from these residues are always made of smaller MOD than those obtained for coking coals. For comparison, a similar characterisation, carried out

Paris-Sud XI, Université de

163

Reducing Energy Consumption on Process Ovens & Oxidation Systems  

E-Print Network [OSTI]

. The products manufactured include baked goods, cereals, pet food, tobacco, and many other products. Ovens are used to bake and cure surface coated materials. Such as building siding, window frames, window blinds, automotive parts, wood products...

Worachek, C.

164

Effect of bulk density of coking coal on swelling pressure  

Science Journals Connector (OSTI)

Abstract Coking coals are the important raw materials for the iron and steel industries and play an important role on its sustainable development, especially on the stamp-charging coke making with the characteristics of increasing the bulk density. There is a significance on the reasonable usage of the coking coal resource with the reduced production cost, improved efficiency of the economy to develop the stamp-charging coke making technology. Important effects of the density of coking coal on the coking and caking properties were investigated. In the article, the maximum values of swelling pressure and variation of Laowan gas coal and Xinjian 1/3 coking coal, Longhu fat coal and Didao coking coal, which were mined at Shenyang and Qitaihe respectively, were investigated under different bulk densities during the coking. The results showed that when the values of density increased from 0.85 ton/m3 to 1.05 ton/m3, for the Laowan gas coal, swelling pressure variation and even the maximum value changed slightly. The swelling pressure was 3.63 \\{KPa\\} when the density was improved to 1.05 ton/m3; for the Xinjian 1/3 coking coal, the values of swelling pressure changed significantly and the maximum values was 82.88 \\{KPa\\} with the density improved to 1.05 when the coal was heated to 600°C. The coke porosity, which was investigated by automatic microphotometer, decreased from 47.4% to 33.1% with the increasing of the density from 0.85 ton/m3 to 1.05 ton/m3, and the decreased value was 14.3%. Meanwhile, the pore structures of four cokes were characterized by an optical microscope.

Jinfeng Bai; Chunwang Yang; Zhenning Zhao; Xiangyun Zhong; Yaru Zhang; Jun Xu; Bai Xi; Hongchun Liu

2013-01-01T23:59:59.000Z

165

PITTSBURGH REGIONAL ENVIRONMENTAL THREATS ANALYSIS  

E-Print Network [OSTI]

.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 Coke Oven Emissions.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 Carbon Tetrachloride.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 Acetaldehyde

Jiang, Huiqiang

166

Coke profile and effect on methane/ethylene conversion process.  

E-Print Network [OSTI]

??The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to… (more)

Al-Solami, Bandar

2012-01-01T23:59:59.000Z

167

The methods of steam coals usage for coke production  

SciTech Connect (OSTI)

Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

1998-07-01T23:59:59.000Z

168

Reducing power production costs by utilizing petroleum coke. Annual report  

SciTech Connect (OSTI)

A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

Galbreath, K.C.

1998-07-01T23:59:59.000Z

169

Nippon Coke and Engineering Sumitomo Corp JV | Open Energy Information  

Open Energy Info (EERE)

navigation, search Name: Nippon Coke and Engineering & Sumitomo Corp JV Place: Tokyo, Japan Zip: 135-6007 Product: Japan-based natural graphite base anode materials joint...

170

Systematic approach to industrial oven optimisation for energy saving  

Science Journals Connector (OSTI)

Abstract Industrial ovens consume a sizable proportion of energy within the manufacturing sector. Although there has been considerable research into energy reduction of industrial processes throughout literature, there is not yet a generalised tool to reduce energy within industrial ovens. The systematic approach presented aims to guide an engineer through five stages of oven optimisation. These involve defining the scope of the optimisation project, measuring and analysing process variables in order to develop fundamental understanding of the system so that an optimisation plan can be established and then implemented. The paper gives an application example of the methodology to a curing oven within a masking tape manufacturing facility. This approach showed an estimated annual saving of 1,658,000 kWh (29% reduction of the oven's energy consumption and a 4.7% reduction of the whole plant's energy consumption) with very little capital expenditure. As the methodology can be tailored to accommodate individual optimisation options for each oven scenario, while still providing a clear pathway, it has potential applications within the wider manufacturing industry.

F. Pask; J. Sadhukhan; P. Lake; S. McKenna; E.B. Perez; A. Yang

2014-01-01T23:59:59.000Z

171

Impact of Coal-Coking Effluent on Sediment Microbial Communities: a Multivariate Approach  

Science Journals Connector (OSTI)

...General Microbial Ecology Impact of Coal-Coking Effluent on Sediment Microbial...response to and recovery from coal-coking waste effluent was evaluated for...community response. Impact of coal-coking effluent on sediment microbial...

Gary S. Sayler; Timothy W. Sherrill; Richard E. Perkins; Lawrence M. Mallory; Michael P. Shiaris; Deana Pedersen

1982-11-01T23:59:59.000Z

172

Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination  

Broader source: Energy.gov [DOE]

Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

173

Chronic Beryllium Disease Prevention Program Report  

SciTech Connect (OSTI)

This document describes how Lawrence Livermore National Laboratory (LLNL) meets the requirements and management practices of federal regulation 10 CFR 850, 'Chronic Beryllium Disease Prevention Program (CBDPP).' This revision of the LLNL CBDPP incorporates clarification and editorial changes based on lessons learned from employee discussions, observations and reviews of Department of Energy (DOE) Complex and commercial industry beryllium (Be) safety programs. The information is used to strengthen beryllium safety practices at LLNL, particularly in the areas of: (1) Management of small parts and components; and (2) Communication of program status to employees. Future changes to LLNL beryllium activities and on-going operating experience will be incorporated into the program as described in Section S, 'Performance Feedback.'

Lee, S

2012-03-29T23:59:59.000Z

174

LLNS Beryllium Consent Order Fact Sheet  

Broader source: Energy.gov [DOE]

The DOE Office of Enforcement investigation determined that several incidents between November 2007 and February 2010 demonstrated deficiencies in LLNS’s implementation of the Laboratory’s CBDPP and LLNS measures to protect workers from legacy beryllium contamination hazards.

175

DELAYED COKING OF SOLVENT EXTRACTED COAL FOR PRODUCTION OF ANODE GRADE COKE: CHARACTERIZATION OF SOLID AND LIQUID PRODUCTS.  

E-Print Network [OSTI]

??This study investigates the feasibility of using high temperature solvent extraction of coal to produce feedstock for the production of anode grade coke through delayed… (more)

Karri, Vamsi

2011-01-01T23:59:59.000Z

176

RELATION BETWEEN TEXTURE AND REACTIVITY IN METALLURGICAL COKES OBTAINED FROM COAL USING PETROLEUM COKE AS ADDITIVE  

E-Print Network [OSTI]

Reactivity to C O2 is, perhaps, the most importam quality parameter used to evaluate the performance of a metallurgical coke in the blast furnace [ 1]. A lot of effort has been made to study how it is influenced by the

J. J. Pis; J. A. Men~ndez; R. Alvarez; M. A. Diez; J. B. Parra

177

Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs  

E-Print Network [OSTI]

effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

Patel, S. S.

1982-01-01T23:59:59.000Z

178

Dry purification of aspirational air in coke-sorting systems with wet slaking of coke  

SciTech Connect (OSTI)

Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

179

Adsorptive removal of nitrogen from coal-based needle coke feedstocks using activated carbon.  

E-Print Network [OSTI]

??A low percentage of nitrogen in needle coke feedstocks is desired for the reduction of puffing during the process of graphitization of needle coke. The… (more)

Madala, Sreeja.

2009-01-01T23:59:59.000Z

180

Prediction of Coke Quality in Ironmaking Process: A Data Mining Approach.  

E-Print Network [OSTI]

??Coke is an indispensable material in Ironmaking process by blast furnace. To provide good and constant quality coke for stable and efficient blast furance operation… (more)

Hsieh, Hsu-huang

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Physicochemical characterization of coke-plant soil for the assessment of polycyclic aromatic hydrocarbon availability and the feasibility of phytoremediation  

SciTech Connect (OSTI)

Coke oven site soil was characterized to assess the particle association and availability of polycyclic aromatic hydrocarbons (PAHs). We identified various carbonaceous materials including coal, coke, pitch, and tar decanter sludge. Most of the PAHs were associated with the polymeric matrix of tar sludge or hard pitch as discrete particles, coatings on soil mineral particles, or complex aggregates. The PAH availability from these particles was very low due to hindered diffusive release from solid tar or pitch with apparent diffusivities of 6 x 10{sup -15} for phenanthrene, 3 x 10{sup -15} for pyrene, and 1 x 10{sup -15} cm{sup 2}/s for benzo(a)pyrene. Significant concentrations of PAHs were observed in the interior of solid tar aggregates with up to 40,000 mg/kg total PAHs. The release of PAHs from the interior of such particles requires diffusion over a substantial distance, and semipermeable membrane device tests confirmed a very limited availability of PAHs. These findings explain the results from three years of phytoremediation of the site soil, for which no significant changes in the total PAH concentrations were observed in the test plot samples. The observed low bioavailability of PAHs probably inhibited PAH phytoremediation, as diffusion-limited mass transfer would limit the release of PAHs to the aqueous phase.

Ahn, S.; Werner, D.; Luthy, R.G. [Stanford University, Stanford, CA (United States). Dept. of Civil & Environmental Engineering

2005-09-01T23:59:59.000Z

182

Former Worker Program - Defunct Beryllium Vendor Screening Program  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Defunct Beryllium Vendor Screening Program Defunct Beryllium Vendor Screening Program Former Worker Medical Screening Program (FWP) In February 2005, DOE expanded the beryllium screening program to include former employees of defunct DOE beryllium vendors who were employed with these companies while they performed work for DOE. This change was made to ensure that workers who no longer have an employer to turn to for beryllium disease testing could receive this important screening. DOE will offer these individuals a blood test at no cost to check for beryllium sensitization. DOE will pay for both the costs of drawing the blood and the analysis of the blood. If a screened individual receives an abnormal test for beryllium sensitization, they can receive medical monitoring for beryllium disease through DOL's EEOICP.

183

A container for heat treating materials in microwave ovens  

DOE Patents [OSTI]

The efficiency of a microwave oven of a conventional two-source configuration and energy level is increased by providing the oven with a container for housing a refractory material to be treated. The container is formed to top and bottom walls transparent to microwaves while the sidewalls, in a circular configuration, are formed of a nonmetallic material opaque to microwave radiation for reflecting the radiation penetrating the top and bottom walls radially inwardly into the center of the container wherein a casket of heat-insulating material is provided for housing the material to be heat treated. The reflection of the microwave radiation from the sidewalls increases the concentration of the microwaves upon the material being heat treated while the concentration of the microwaves upon the material being heat treated while the casket retains the heat to permit the heating of the material to a substantially higher temperature than achievable in the oven without the container.

Holcombe, C.E.; Dykes, N.L.; Kimrey, H.D. Jr.; Mills, J.E.

1988-01-26T23:59:59.000Z

184

Container for heat treating materials in microwave ovens  

DOE Patents [OSTI]

The efficiency of a microwave oven of a conventional two-source configuration and energy level is increased by providing the oven with a container for housing a refractory material to be treated. The container is formed of top and bottom walls transparent to microwaves while the sidewalls, in a circular configuration, are formed of a nonmetallic material opaque to microwave radiation reflecting the radiation penetrating the top and bottom walls radially inwardly into the center of the container wherein a casket of heat-insulating material is provided for housing the material to be heat treated. The reflection of the microwave radiation from the sidewalls increases the concentration of the microwaves upon the material being heat treated while the casket retains the heat to permit the heating of the material to a substantially higher temperature than achieveable in the oven without the container.

Holcombe, Cressie E. (Farragut, TN); Dykes, Norman L. (Oak Ridge, TN); Kimrey, Jr., Harold D. (Knoxville, TN); Mills, James E. (Knoxville, TN)

1989-01-01T23:59:59.000Z

185

Former Workers Medical Facilities with Experience Evaluating Chronic Beryllium Disease  

Broader source: Energy.gov [DOE]

This document provides a listing of medical facilities within the United States with experience in evaluating Chronic Beryllium Disease.

186

Testing of the Burns-Milwaukee`s Sun Oven  

SciTech Connect (OSTI)

A Burns-Milwaukee Sun Oven was tested at Sandia`s Solar Thermal Test Facility. It was instrumented with five type K thermocouples to determine warm-up rates when empty and when a pot containing two liters of water was placed inside. It reached inside air temperatures above 160{degrees}C (320{degrees}F). It heated two liters of water from room temperatures to 80{degrees}C, (175{degrees}F), in 75 minutes. Observations were also made on the cooling and reheating rates during a cloud passage. The adverse effects of wind on operation of the solar oven was also noted.

Moss, T.A.

1997-03-01T23:59:59.000Z

187

Research on the evolvement of morphology of coking coal during the coking process  

Science Journals Connector (OSTI)

Abstract The evolvement of morphology and structure of the coal with different metamorphic degrees during coking process in the vertical furnace was investigated by infrared Image detector. Moreover, the temperature distribution in the radial direction and the crack formation were also studied in heating process. The results show that the amount of crack and the shrinkage level of char decrease with the coal rank rising. In addition, the initial temperature of crack formation for char increases with the coal rank rising.

Xiangyun Zhong; Shiyong Wu; Yang Liu; Zhenning Zhao; Yaru Zhang; Jinfeng Bai; Jun Xu; Bai Xi

2013-01-01T23:59:59.000Z

188

Coke formation during pyrolysis of 1,2-dichloroethane  

SciTech Connect (OSTI)

Most processes involving hydrocarbons or carbon oxides at high temperatures suffer from the disadvantage of coke formation. The formation of coke deposits during pyrolysis of hydrocarbons or chlorinated hydrocarbons is of significant practical importance. Examples of such processes are the steam cracking of alkanes to produce olefins and the thermal decomposition of 1,2-dichloroethane (EDC) for the production of vinyl chloride monomer (VCM). Even id the rate of coke production is low, the cumulative nature of the solid product will result in reactor fouling. The present work deals with the thermal decomposition of EDC. Coke formation has been studied on metal surfaces in a quartz tubular reactor. The rate of coke deposition was measures on metal foils hanging from one arm of a microbalance. A complete analysis of the product gas was accomplished using on-line gas chromatography. The results show that coke deposition during thermal decomposition of EDC depends on the composition of the feed as well as on the nature of the surface of the metal foil. Small amounts of other components (contamination with other chlorinated hydrocarbons as an example) may have a large influence on the rate of coke formation. The results are discussed in terms of surface composition/morphology of the metal foil and the free radical mechanism for thermal decomposition of FDC.

Holmen, A. [Norwegian Institute of Technology, Trondheim (Norway); Lindvag, O.A. [SINTEF Applied Chemistry, Trondheim (Norway)

1995-12-31T23:59:59.000Z

189

Coke mineral transformations in the experimental blast furnace  

SciTech Connect (OSTI)

Blast furnace efficiency may be improved by optimizing coke reactivity. Some but not all forms of mineral matter in the coke modify its reactivity, but changes in mineral matter that occur within coke while in the blast furnace have not been fully quantified. To determine changes in mineral matter forms in the blast furnace, coke samples from a dissection study in the LKAB experimental blast furnace (EBF) were characterized using SEM/EDS analysis, EPMA (microprobe), and low-temperature ashing/quantitative XRD analysis. Variations in alkali concentration, particularly potassium, dominated the compositional changes. At high concentrations of potassium, the mineral matter was largely potassium-bearing but even more potassium was diffused throughout the coke and not associated with mineral matter. There was little difference in potassium concentration between the core and surface of the coke pieces, suggesting that potassium diffused rapidly through the whole coke. Iron, calcium, silicon, and aluminum concentrations were relatively constant in comparison, although the mineralogy of all elements changed significantly with changing temperature. 23 refs., 20 figs., 9 tabs.

Kelli Kazuberns; Sushil Gupta; Mihaela Grigore; David French; Richard Sakurovs; Mats Hallin; Bo Lindblom; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Cooperative Research Centre for Coal in Sustainable Development (CCSD)

2008-09-15T23:59:59.000Z

190

Chronic Beryllium Disease Prevention Program (10 CFR 850)  

Broader source: Energy.gov [DOE]

The DOE established a chronic beryllium disease prevention program (CBDPP) to reduce the number of workers currently exposed to beryllium in the course of their work at DOE facilities managed by DOE or its contractors, minimize the levels of, and potential for, exposure to beryllium, and establish medical surveillance requirements to ensure early detection of the disease.

191

Surveyor: A System for Generating Coherent Survey Articles for Scientific Topics Rahul Jha and Reed Coke  

E-Print Network [OSTI]

Coke Department of EECS University of Michigan Ann Arbor, MI, 48109 Dragomir Radev Department of EECS

Radev, Dragomir R.

192

Variation in coke properties within the blast-furnace shop  

SciTech Connect (OSTI)

In active production at OAO Magnitogorskii Metallurgicheskii Kombinat (MMK), samples of melt materials were taken during shutdown and during planned repairs at furnaces 1 and 8. In particular, coke was taken from the tuyere zone at different distances from the tuyere tip. The mass of the point samples was 2-15 kg, depending on the sampling zone. The material extracted from each zone underwent magnetic separation and screening by size class. The resulting coke sample was averaged out and divided into parts: one for determining the granulometric composition and mechanical strength; and the other for technical analysis and determination of the physicochemical properties of the coke.

E.N. Stepanov; I.I. Mel'nikov; V.P. Gridasov; A.A. Stepanova [OAO Magnitogorskii Metallurgicheskii Kombinat (MMK), Magnitogorsk, (Russian Federation)

2009-04-15T23:59:59.000Z

193

Thermal analyses of LiCoO2 lithium-ion battery during oven tests  

Science Journals Connector (OSTI)

A three dimensional thermal abuse model for graphite/LiPF6/LiCoO2 batteries is established particularly for oven tests. To ... of heat release condition and oven temperature on battery thermal behaviors, we perfo...

Peng Peng; Yiqiong Sun; Fangming Jiang

2014-10-01T23:59:59.000Z

194

Process analysis of syngas production by non-catalytic POX of oven gas  

Science Journals Connector (OSTI)

A non-catalytic POX of oven gas is proposed to solve the problem of secondary pollution due to solid wastes produced from the great amount of organic sulfur contained in oven gas in the traditional catalytic p...

Fuchen Wang; Xinwen Zhou; Wenyuan Guo…

2009-03-01T23:59:59.000Z

195

Process Parameters and Energy Use of Gas and Electric Ovens in Industrial Applications  

E-Print Network [OSTI]

for industrial applications where electric ovens have predominant use. Tests were performed to obtain the process efficiency and examine cost savings potential in converting electric ovens to natural gas. Preliminary results show that, for the plat studied, cost...

Kosanovic, D.; Ambs, L.

196

Graphitized needle cokes and natural graphites for lithium intercalation  

SciTech Connect (OSTI)

This paper examined effects of heat treatment and milling (before or after heat treatment) on the (electrochemical) intercalating ability of needle petroleum coke; natural graphite particles are included for comparison. 1 tab, 4 figs, 7 refs.

Tran, T.D.; Spellman, L.M.; Pekala, R.W. [Lawrence Livermore National Lab., CA (United States); Goldberger, W.M. [Superior Graphite Co., Chicago, IL (United States); Kinoshita, K. [Lawrence Berkeley National Lab., CA (United States)

1996-05-10T23:59:59.000Z

197

Co-gasification of petroleum coke and biomass  

Science Journals Connector (OSTI)

Abstract Gasification may be an attractive alternative for converting heavy oil residue – petroleum coke into valuable synthetic gas. Due to the low reactivity of petroleum coke, it is maybe preferable to convert it in combination with other fuels such as biomass. Co-gasification of petroleum coke and biomass was studied in an atmospheric bubbling fluidised bed reactor and a thermogravimetric analyser (TGA) at KTH Royal University of Technology. Biomass ash in the blends was found to have a catalytic effect on the reactivity of petroleum coke during co-gasification. Furthermore, this synergetic effect between biomass and petcoke was observed in the kinetics data. The activation energy Ea determined from the Arrhenius law for pure petcoke steam gasification in the TGA was 121.5 kJ/mol, whereas for the 50/50 mixture it was 96.3, and for the 20/80 blend – 83.5 kJ/mol.

Vera Nemanova; Araz Abedini; Truls Liliedahl; Klas Engvall

2014-01-01T23:59:59.000Z

198

Variation in mineral composition of coal during enrichment and coking  

Science Journals Connector (OSTI)

The parameters I b and B b used in developing an optimal coking-batch composition are determined from data on ... of the ash in Donetsk Basin and other coal. It is found that, when...

M. L. Ulanovskii; A. N. Likhenko

2009-06-01T23:59:59.000Z

199

Coking properties of coal pitch in coal batch  

Science Journals Connector (OSTI)

The coking properties of coal pitch depend significantly on its fractional composition, ... : 2: 2. This is typical of coal pitch with a softening temperature of 75– ... Such pitch is the best clinkering additive...

S. G. Gagarin; Yu. I. Neshin

2011-09-01T23:59:59.000Z

200

Coal preparation, coking, and slaking in China and Japan  

Science Journals Connector (OSTI)

In China and Japan, measures have been developed to maintain constant coke quality and hence permit economical and stable blast-furnace operation with the injection of coal-dust fuel; and to reduce the cost of th...

I. F. Kurunov; P. V. Lizogub; O. V. Golubev

2010-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Coking theory: Internal stress in the coal batch  

Science Journals Connector (OSTI)

The development of local internal stress in the coal batch is analyzed on the basis of ... theoretical and experimental data. Its influence on coke quality is demonstrated. The influence of mineralized ... large ...

V. I. Sukhorukov

2011-09-01T23:59:59.000Z

202

Share a Coke - An Investigation of Social Media Marketing.  

E-Print Network [OSTI]

??This investigation examines the underlying factors behind audience participation in Coca-Cola’s ‘Share a Coke’ campaign, which became a trend on social media in Denmark in… (more)

Trougaard, Victor Frederic Wagn

2014-01-01T23:59:59.000Z

203

RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES  

SciTech Connect (OSTI)

Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

2003-06-01T23:59:59.000Z

204

Table 38. Coal Stocks at Coke Plants by Census Division  

U.S. Energy Information Administration (EIA) Indexed Site

Coal Stocks at Coke Plants by Census Division Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 38. Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Census Division June 30, 2013 March 31, 2013 June 30, 2012 Percent Change (June 30) 2013 versus 2012 Middle Atlantic w w w w East North Central 1,313 1,177 1,326 -1.0 South Atlantic w w w w East South Central w w w w U.S. Total 2,500 2,207 2,295 8.9 w = Data withheld to avoid disclosure. Note: Total may not equal sum of components because of independent rounding. Source: U.S. Energy Information Administration (EIA), Form EIA-5, 'Quarterly Coal Consumption and Quality Report - Coke Plants.'

205

DOE - Office of Legacy Management -- Beryllium Corp - PA 39  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Beryllium Corp - PA 39 Beryllium Corp - PA 39 FUSRAP Considered Sites Site: BERYLLIUM CORP. (PA.39 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Brush Beryllium PA.39-1 Location: Reading , Pennsylvania PA.39-1 Evaluation Year: 1987 PA.39-1 Site Operations: Production of Beryllium circa late 1940s - 50s. PA.39-1 Site Disposition: Eliminated - No radioactive material handled at this site, only Beryllium PA.39-1 Radioactive Materials Handled: No PA.39-1 Primary Radioactive Materials Handled: None Indicated Radiological Survey(s): None Indicated Site Status: Eliminated from further consideration under FUSRAP Also see Documents Related to BERYLLIUM CORP. PA.39-1 - Memorandum/Checklist; D. Levine to the File; Subject:

206

Beryllium contamination inside vehicles of machine shop workers  

SciTech Connect (OSTI)

Inhalation of beryllium particles causes a chronic, debilitating lung disease--chronic beryllium disease (CBD)--in immunologically sensitized workers. Evidence that very low concentrations of beryllium may initiate this chronic disease is provided by incidences of the illness in family members exposed to beryllium dust from workers` clothes and residents in neighborhoods surrounding beryllium refineries. This article describes the results of a cross-sectional survey to evaluate potential take-home beryllium exposures by measuring surface concentrations on the hands and in vehicles of workers at a precision machine shop where cases of CBD had recently been diagnosed. Many workers did not change out of their work clothes and shoes at the end of their shift, increasing the risk of taking beryllium home to their families. Wipe samples collected from workers` hands and vehicle surfaces were analyzed for beryllium content by inductively coupled argon plasma-atomic emission spectroscopy (ICP-AES). The results ranged widely, from nondetectable to 40 {micro}g/ft{sup 2} on workers` hands and up to 714 {micro}g/fg{sup 2} inside their vehicles, demonstrating that many workers carried residual beryllium on their hands and contaminated the inside of their vehicles when leaving work. The highest beryllium concentrations inside the workers` vehicles were found on the drivers` floor (GM = 19 {micro}g/ft{sup 2}, GSD = 4.9), indicating that workers were carrying beryllium on their shoes into their vehicles. A safe level of beryllium contamination on surfaces is not known, but it is prudent to reduce the potential for workers to carry beryllium away from the work site.

Sanderson, W.T. [National Inst. for Occupational Safety and Health, Cincinnati, OH (United States). Div. of Surveillance, Hazard Evaluations, and Field Studies] [National Inst. for Occupational Safety and Health, Cincinnati, OH (United States). Div. of Surveillance, Hazard Evaluations, and Field Studies; Henneberger, P.K. [National Inst. for Occupational Safety and Health, Morgantown, WV (United States). Div. of Respiratory Disease Studies] [National Inst. for Occupational Safety and Health, Morgantown, WV (United States). Div. of Respiratory Disease Studies; Martyny, J. [Tri-County Health Dept., Commerce, CO (United States)] [Tri-County Health Dept., Commerce, CO (United States); Ellis, K. [Colorado State Univ., Fort Collins, CO (United States). Dept. of Environmental Health] [Colorado State Univ., Fort Collins, CO (United States). Dept. of Environmental Health; Mroz, M.M. [National Jewish Medical and Research Center, Denver, CO (United States)] [National Jewish Medical and Research Center, Denver, CO (United States); Newman, L.S. [National jewish Medical and Research Center, Denver, CO (United States)] [National jewish Medical and Research Center, Denver, CO (United States); [Univ. of Colorado School of Medicine, Denver, CO (United States)

1999-04-01T23:59:59.000Z

207

Laboratory-Scale Coking of Coal?Petroleum Mixtures in Sealed Reactors  

Science Journals Connector (OSTI)

Further evidence for coal?petroleum interactions in this system is exhibited by the fact that (i) the product slates from the co-coking reactions are not linear combinations of the products from the feedstocks reacted individually and (ii) the fluidity profiles of the Powellton?resid mixtures are similar to those for two interacting coking coals. ... The boiling distribution of the oils from co-coking resembles that observed when the Powellton coal was coked in the absence of resid. ... In addition, the co-coking reactions show a “coke jump” that occurs at ?465 °C; this jump is not observed when the coal or petroleum feedstocks are reacted individually. ...

Anne E. Fickinger; Mark W. Badger; Gareth D. Mitchell; Harold H. Schobert

2004-05-19T23:59:59.000Z

208

Prediction of metallurgical coke strength from the petrographic composition of coal blends  

SciTech Connect (OSTI)

Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

2009-07-01T23:59:59.000Z

209

Bush Administration to Expand Beryllium Disease Screening Program |  

Broader source: Energy.gov (indexed) [DOE]

Bush Administration to Expand Beryllium Disease Screening Program Bush Administration to Expand Beryllium Disease Screening Program Bush Administration to Expand Beryllium Disease Screening Program February 23, 2005 - 10:27am Addthis Former employees of DOE vendors eligible for free screening WASHINGTON, DC - U.S. Secretary of Energy Samuel W. Bodman today announced the Department of Energy (DOE) will expand a beryllium screening program to include former employees of now-defunct DOE beryllium vendor companies across the country. Beryllium is a component used in nuclear weapons built by the Department of Energy. "Through no fault of their own, these Cold Warriors were left out in the cold when their former employers went out of business. By expanding this screening program, President Bush and the Department of Energy honor these

210

Beryllium Screening - Informed Choice Document | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Beryllium Screening - Informed Choice Document Beryllium Screening - Informed Choice Document Beryllium Screening - Informed Choice Document January 2007 Cases of chronic beryllium disease (CBD), a legacy of the Department of Energy's (DOE) role in weapons production, have been increasing across the DOE complex. This trend has sparked increased concern about this serious occupational illness. In a national effort to identify current and former workers who have CBD or are sensitized to beryllium and to better understand the illness, DOE has set up a number of medical surveillance and research programs for both current and former workers. The way that workers enroll in the programs and the information that they are given prior to participating in the beryllium lymphocyte proliferation testing (Be-LPT) vary depending on where and when the worker was employed in a DOE

211

Beryllium-7 labeled carbon particles and method of making  

DOE Patents [OSTI]

Beryllium-7 labeled carbon particles made from the proton irradiation of carbon materials, preferably from dry carbon black are disclosed. Such particles are useful as gamma emitting radiotracers.

Richards, P.; Mausner, L.F.; Prach, T.F.

1987-11-17T23:59:59.000Z

212

Beryllium-7 labeled carbon particles and method of making  

DOE Patents [OSTI]

Beryllium-7 labeled carbon particles made from the proton irradiation of carbon materials, preferably from dry carbon black are disclosed. Such particles are useful as gamma emitting radiotracers.

Richards, P.; Mausner, L.F.; Prach, T.F.

1985-04-29T23:59:59.000Z

213

Hanford Facility Beryllium Fact Sheet Building Number/Name:  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

still present: NO Beryllium present: NO Current building occupancyactivity: Completed building demolition on 9302009. Maximum Estimated Current Be Exposure from Routine...

214

The Rocky Flats Environmental Technology Site beryllium characterization project  

SciTech Connect (OSTI)

A site beryllium characterization project was completed at the Rocky Flats Environmental Technology Site (RFETS) in 1997. Information from historical reviews, previous sampling surveys, and a new sampling survey were used to establish a more comprehensive understanding of the locations and levels of beryllium contamination in 35 buildings. A feature of the sampling strategy was to test if process knowledge was a good predictor of where beryllium contamination could be found. Results revealed that this technique was effective at identifying where surface contamination levels might exceed the RFETS smear control level but that it was not effective in identifying where low concentrations of beryllium might be found.

Morrell, D.M. [Kaiser-Hill Co. LLC, Golden, CO (United States); Miller, J.R. [Radian International LLC, Los Alamos, NM (United States); Allen, D.F. [Radian International LLC, Oak Ridge, TN (United States)

1999-06-01T23:59:59.000Z

215

Hanford Facility Beryllium Fact Sheet Building Number/Name:  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

beryllium- contaminated plutonium residues. These waste residues may have included Rocky Flats Environmental Technical Site (RFETS) incinerator fly ash known to contain...

216

Hydrodesulfurization of Fluid Catalytic Cracking Decant Oils for the Production of Low-sulfur Needle Coke Feedstocks.  

E-Print Network [OSTI]

??Needle coke, produced by the delayed coking of fluid catalytic cracking decant oils, is the primary filler used in the production of graphite electrodes. The… (more)

Wincek, Ronald

2013-01-01T23:59:59.000Z

217

E-Print Network 3.0 - actively cooled beryllium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

namely carbon, tungsten and beryllium. Knowledge concerning... is discussed. PACS: 52.40.Hf JNM Keywords: Plasma Material Interactions, Surface Effects, Beryllium, Carbon Source:...

218

Preparation and coking properties of coal maceral concentrates  

Science Journals Connector (OSTI)

Abstract The concentrates with different maceral contents were obtained from Kailuan coking coals with different coal ranks ( R o,ran ? varying from 0.88% to 1.73%) by float–sink separation in lab. Then these concentrates were characterized by proximate analysis, ultimate analysis, petrography analysis and coking index determination. The results show that the vitrinite is characterized as nature of lower carbon content, higher hydrogen content, higher volatile matter and stronger caking property compared to inertinite. The relationships between variation rate of volatile matter and maximum volatile matter and coal ranks are identified, and a linear model is developed for fast determination of the maceral contents. Compared to inertinite-rich concentrate, the blending ratio of vitrinite-rich concentrate is increased by 13%, which is considered to be a potential technique based on maceral separation for expanding the coking coal resources.

Lei Zhang; Wenli Liu; Dongpo Men

2014-01-01T23:59:59.000Z

219

Coking Plants, Coal-to-gas Plants, Gas Production and Distribution  

Science Journals Connector (OSTI)

This environmental brief covers various coal upgrading technologies, incl. coking and low-temperature carbonization as processes yielding the target products coke and gas plus tar products and diverse...

1995-01-01T23:59:59.000Z

220

Determining the coking properties and technological value of coal and coal mixtures  

Science Journals Connector (OSTI)

A method is developed for determining the coking properties and technological value of coal from newly identified beds or new sections of existing mines. The coking properties are assessed on the basis of predict...

A. S. Stankevich; V. S. Stankevich

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Influence of frothing-agent oxidation on coking-coal flotation  

Science Journals Connector (OSTI)

The oxidation of frothing agents (KOBS, OPPG-3, and the tar fraction of peat bitumen) affects coking-coal flotation. The tar fraction of Krapivinsk-peat ... provides the basis for a frothing agent in coking-coal ...

M. Yu. Klimovich; S. I. Zherebtsov; Yu. V. Musin; A. I. Moiseev…

2008-12-01T23:59:59.000Z

222

Calculating the relative value of coal in Russian coking-coal markets  

Science Journals Connector (OSTI)

In order to improve the pricing of Russian coking coal, a method is proposed for calculating the relative technological value of purchased coking-coal batches. The basic idea is to compare the parameters of optim...

V. A. Brodskii; E. V. Brodskaya

2009-03-01T23:59:59.000Z

223

Coal resources at OOO Metinvest Holding and their optimal coking at PAO AKKhZ  

Science Journals Connector (OSTI)

The coal resources at OOO Metinvest Holding are considered, in a climate of increase requirements on coke quality and self-reliance. The parameters of high-quality coke are outlined, and the corresponding require...

V. G. Gusak; V. I. Gavrilyuk; M. S. Magomedov; A. A. Pasternak…

2013-11-01T23:59:59.000Z

224

Role of coke characteristics in the regeneration of a catalyst for the MTG process  

SciTech Connect (OSTI)

The effect on combustion in air of the nature of the coke deposited in HZSM5 zeolites used in the MTG process has been studied. This coke is highly hydrogenated and unstable, and its H/C ratio decreases during combustion or when a previous thermal treatment is carried out. Coke H/C ratio greatly affects its reactivity during combustion; consequently, a severe thermal equilibration treatment is recommended for reproducibility of results. Combustion kinetics of equilibrated coke, when it is released from the catalyst, has been proven to be similar to that of the coke deposited on other catalysts for several processes. Lower coke reactivity for aging and combustion, on being deposited within the HZSM5 zeolite, must be attributed to air-coke contact restrictions due to the location of the coke, which partially impedes the flow of air into the crystals.

Ortega, J.M.; Gayubo, A.G.; Aguayo, A.T.; Benito, P.L.; Bilbao, J. [Univ. del Pais Vasco, Bilbao (Spain). Dept. de Ingenieria Quimica] [Univ. del Pais Vasco, Bilbao (Spain). Dept. de Ingenieria Quimica

1997-01-01T23:59:59.000Z

225

Coke in the Cross Hairs: Water, India, and the University of Michigan  

E-Print Network [OSTI]

Coke in the Cross Hairs: Water, India, and the University of Michigan case 1-429-098 July 25, 2010, where "Killer Coke" banners had hung days before. Students were holed away studying for finals, the demonstrations were over and Coke was once again flowing from machines at the Michigan Union. That morning

Edwards, Paul N.

226

Testing of the Sunstove Organization`s Sunstove Solar Oven  

SciTech Connect (OSTI)

A Sunstove Organization`s Sunstove was tested at Sandia`s Solar Thermal Test Facility. It was instrumented with five type K thermocouples to determine warm-up rates when empty and when a pot containing two liters of water was placed inside. It reached inside air temperatures above 115{degrees}C (240{degrees}F). It heated two liters of water from room temperature to 80{degrees}C (175{degrees}F) in about two hours. Observations were made on the cooling and reheating rates during a cloud passage. The adverse effects of wind on the operation of the solar oven were also noted.

Moss, T.A.

1997-03-01T23:59:59.000Z

227

Chronic Beryllium Disease Prevention Environment, Safety, Health, and Quality Division  

E-Print Network [OSTI]

of Energy EDM electrical discharge machine ESHQ Environment, Safety, Health, and Quality Division FSD Field This program covers the handling, machining, and use of beryllium and medical monitoring and surveillance, machining, and using beryllium and their supervisors; the Industrial Hygiene Group, Field Services

Wechsler, Risa H.

228

Table 33. Coal Carbonized at Coke Plants by Census Division  

U.S. Energy Information Administration (EIA) Indexed Site

Coal Carbonized at Coke Plants by Census Division Coal Carbonized at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 33. Coal Carbonized at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Census Division April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change Middle Atlantic w w w w w w East North Central 3,051 2,997 3,092 6,048 6,156 -1.8 South Atlantic w w w w w w East South Central w w w w w w U.S. Total 5,471 5,280 5,296 10,751 10,579 1.6 w = Data withheld to avoid disclosure. Note: Total may not equal sum of components because of independent rounding. Source: U.S. Energy Information Administration (EIA), Form EIA-5, 'Quarterly Coal Consumption and Quality Report - Coke Plants

229

Process for converting coal into liquid fuel and metallurgical coke  

DOE Patents [OSTI]

A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

1994-01-01T23:59:59.000Z

230

Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan*  

E-Print Network [OSTI]

Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M strategies in prices and advertising for Coca-Cola and Pepsi-Cola. Separate strategies for each firm variables are prices and advertising. We divide each firm's continuous price-advertising action space

Lansky, Joshua

231

Lummus process turns coal tar pitch to coke  

Science Journals Connector (OSTI)

Lummus Co. has developed a process for converting coal tar pitch to coke and now has a full-scale commercial plant in operation in Japan. The plant, which is owned by Nittetsu Chemical Industrial Co., a subsidiary of Yawata Iron and Steel, is producing ...

1968-12-09T23:59:59.000Z

232

The development of coke smelting and the industrial revolution  

E-Print Network [OSTI]

Abraham Darby and the origins of the industrial revolution in Britain. Alan Macfarlane talks to John about the reasons for the area near Birmingham becoming the epi-centre of the industrial development, and the development of coke furnaces and iron...

Macfarlane, Alan

2004-08-05T23:59:59.000Z

233

Coke quality for blast furnaces with coal-dust fuel  

SciTech Connect (OSTI)

Recently, plans have been developed for the introduction of pulverized coal injection (PCI) at various Russian metallurgical enterprises. The main incentive for switching to PCI is the recent price rises for Russian natural gas. The paper discusses the quality of coke for PCI into blast furnaces.

Y.A. Zolotukhin; N.S. Andreichikov [Eastern Coal-Chemistry Institute, Yekaterinburg (Russian Federation)

2009-07-01T23:59:59.000Z

234

Table 23. Coal Receipts at Coke Plants by Census Division  

U.S. Energy Information Administration (EIA) Indexed Site

Receipts at Coke Plants by Census Division Receipts at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 23. Coal Receipts at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Census Division April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change Middle Atlantic w w w w w w East North Central 3,189 2,679 3,225 5,867 5,993 -2.1 South Atlantic w w w w w w East South Central w w w w w w U.S. Total 5,770 4,962 5,370 10,732 10,440 2.8 w = Data withheld to avoid disclosure. Note: Total may not equal sum of components because of independent rounding. Source: U.S. Energy Information Administration (EIA), Form EIA-5, 'Quarterly Coal Consumption and Quality Report - Coke Plants

235

Status Report, Department of Energy's Chronic Beryllium Disease Prevention  

Broader source: Energy.gov (indexed) [DOE]

Status Report, Department of Energy's Chronic Beryllium Disease Status Report, Department of Energy's Chronic Beryllium Disease Prevention Program - February 2006 Status Report, Department of Energy's Chronic Beryllium Disease Prevention Program - February 2006 February 2006 Report on Implementation of 10 CFR Part 850, Chronic Beryllium Disease Prevention Program During calendar year 2005, the Office of Independent Oversight, within the Office of Security and Safety Performance Assurance, evaluated the effectiveness of U.S. Department of Energy (DOE) chronic beryllium disease protection programs (CBDPPs) at five sites as part of regularly scheduled inspections. These reviews focused on site programs for ensuring that workers are protected in accordance with the requirements of 10 CFR 850. This report summarizes the observations, insights, and lessons learned from

236

Status Report, Department of Energy's Chronic Beryllium Disease Prevention  

Broader source: Energy.gov (indexed) [DOE]

Status Report, Department of Energy's Chronic Beryllium Disease Status Report, Department of Energy's Chronic Beryllium Disease Prevention Program - February 2006 Status Report, Department of Energy's Chronic Beryllium Disease Prevention Program - February 2006 February 2006 Report on Implementation of 10 CFR Part 850, Chronic Beryllium Disease Prevention Program During calendar year 2005, the Office of Independent Oversight, within the Office of Security and Safety Performance Assurance, evaluated the effectiveness of U.S. Department of Energy (DOE) chronic beryllium disease protection programs (CBDPPs) at five sites as part of regularly scheduled inspections. These reviews focused on site programs for ensuring that workers are protected in accordance with the requirements of 10 CFR 850. This report summarizes the observations, insights, and lessons learned from

237

ORISE: Worker Health Studies - Testing Beryllium Vendor Populations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oak Ridge Institute for Science Education Oak Ridge Institute for Science Education Beryllium Testing Vendor Populations When former employees at 25 closed U.S. Department of Energy (DOE) beryllium vendor companies needed an entity to provide medical screening and tests related to their beryllium exposure, the agency chose the Oak Ridge Institute for Science and Education (ORISE) to manage the program. ORISE administers a brief health questionnaire and a blood test known as the beryllium lymphocyte proliferation test (BeLPT) to determine if a worker has been sensitized to the light metal or if he or she needs to be evaluated further for chronic beryllium disease (CBD). If a worker has at least one abnormal BeLPT, he or she is referred for further evaluation through the Energy Employees Occupational Illness

238

Hydrodynamic instabilities in beryllium targets for the National Ignition Facility  

SciTech Connect (OSTI)

Beryllium ablators offer higher ablation velocity, rate, and pressure than their carbon-based counterparts, with the potential to increase the probability of achieving ignition at the National Ignition Facility (NIF) [E. I. Moses et al., Phys. Plasmas 16, 041006 (2009)]. We present here a detailed hydrodynamic stability analysis of low (NIF Revision 6.1) and high adiabat NIF beryllium target designs. Our targets are optimized to fully utilize the advantages of beryllium in order to suppress the growth of hydrodynamic instabilities. This results in an implosion that resists breakup of the capsule, and simultaneously minimizes the amount of ablator material mixed into the fuel. We quantify the improvement in stability of beryllium targets relative to plastic ones, and show that a low adiabat beryllium capsule can be at least as stable at the ablation front as a high adiabat plastic target.

Yi, S. A., E-mail: austinyi@lanl.gov; Simakov, A. N.; Wilson, D. C.; Olson, R. E.; Kline, J. L.; Batha, S. H. [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico 87545 (United States); Clark, D. S.; Hammel, B. A.; Milovich, J. L.; Salmonson, J. D.; Kozioziemski, B. J. [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States)

2014-09-15T23:59:59.000Z

239

The Role of Semifusinite in Plasticity Development for a Coking Coal  

Science Journals Connector (OSTI)

Coal rank is a factor of great importance in plasticity development during carbonization, since only some bituminous coals swell in a satisfactory manner and then resolidify to produce good commercial cokes. ... Diessel studied the carbonization behavior of the inertinite macerals in Australian coals by carrying out tests up to 1000 °C where the optical characteristics of the coked entities were correlated with their noncoked counterparts. ... For instance, large-scale coking experiments of some Australian coals containing more than 45% inertinite produced good quality coke, while a Carboniferous coal with that high of an inertinite content gave only a very poor coke. ...

M. Mercedes Maroto-Valer; Darrell N. Taulbee; John M. Andrésen; James C. Hower; Colin E. Snape

1998-08-27T23:59:59.000Z

240

Theoretical and experimental foundations for preparing coke for blast-furnace smelting  

SciTech Connect (OSTI)

This article examines the preparation of coke for blast-furnace smelting by a method that most fully meets the requirements of blast-furnace technology: screening of the -36 mm fraction, the separation of nut coke of the 15-36 mm fraction, and its charging into the furnace in a mixture with the iron-ore-bearing charge components. An analysis is made of trial use of coke of the Premium class on blast furnace No. 5 at the Enakievo Metallurgical Plant. Use of this coke makes it possible to reduce the consumption of skip coke by 3.2-4.1%.

A.L. Podkorytov; A.M. Kuznetsov; E.N. Dymchenko; V.P. Padalka; S.L. Yaroshevskii; A.V. Kuzin [Enakievo Metallurgical Plant, Enakievo (Ukraine)

2009-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Characterization of Liquids Derived From Laboratory Coking of Decant Oil and Co-Coking of Pittsburgh Seam Bituminous Coal with Decant Oil  

Science Journals Connector (OSTI)

(41-43) Co-coking of decant oil/coal blend produced higher coke and gas yields but less liquid product than those of coking. ... When the same decant oil was blended with the Pittsburgh Seam coal and then delayed co-coked, the overhead liquid contained 2.1% gasoline, 3.6% jet fuel, 4.6% diesel, and 88.8% fuel oil on average. ... It is also possible that catalytic cracking reactions may occur via the coal mineral matter (e.g., clays, which are abundant minerals in coals, can serve as cracking catalysts) (Table 1). ...

Ömer Gül; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert

2009-04-21T23:59:59.000Z

242

A compact and efficient strontium oven for laser-cooling experiments  

E-Print Network [OSTI]

Here we describe a compact and efficient strontium oven well suited for laser-cooling experiments. Novel design solutions allowed us to produce a collimated strontium atomic beam with a flux of 1.0\\times10^13 s^-1 cm^-2 at the oven temperature of 450 {\\deg}C, reached with an electrical power consumption of 36 W. The oven is based on a stainless-steel reservoir, filled with 6 g of metallic strontium, electrically heated in a vacuum environment by a tantalum wire threaded through an alumina multi-bore tube. The oven can be hosted in a standard DN40CF cube and has an estimated continuous operation lifetime of 10 years. This oven can be used for other alkali and alkaline earth metals with essentially no modifications.

Marco Schioppo; Nicola Poli; Marco Prevedelli; Stephan Falke; Christian Lisdat; Uwe Sterr; Guglielmo Maria Tino

2012-09-25T23:59:59.000Z

243

A compact and efficient strontium oven for laser-cooling experiments  

E-Print Network [OSTI]

Here we describe a compact and efficient strontium oven well suited for laser-cooling experiments. Novel design solutions allowed us to produce a collimated strontium atomic beam with a flux of 1.0\\times10^13 s^-1 cm^-2 at the oven temperature of 450 {\\deg}C, reached with an electrical power consumption of 36 W. The oven is based on a stainless-steel reservoir, filled with 6 g of metallic strontium, electrically heated in a vacuum environment by a tantalum wire threaded through an alumina multi-bore tube. The oven can be hosted in a standard DN40CF cube and has an estimated continuous operation lifetime of 10 years. This oven can be used for other alkali and alkaline earth metals with essentially no modifications.

Schioppo, Marco; Prevedelli, Marco; Falke, Stephan; Lisdat, Christian; Sterr, Uwe; Tino, Guglielmo Maria

2012-01-01T23:59:59.000Z

244

Coke County, Texas: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Coke County, Texas: Energy Resources Coke County, Texas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 31.8277663°, -100.5296115° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":31.8277663,"lon":-100.5296115,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

245

Integrated coke, asphalt and jet fuel production process and apparatus  

DOE Patents [OSTI]

A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

Shang, Jer Y. (McLean, VA)

1991-01-01T23:59:59.000Z

246

Pricing of Australia's coking coal exports: A regional hedonic analysis  

Science Journals Connector (OSTI)

Black coal is Australia's most important export commodity, but the profitability of the domestic coal industry has been low relative to the mining sector average. As a consequence, a key policy issue in Australia has been the extent to which Japan's coal pricing and investment policies have influenced coal market outcomes. In this paper, a regional hedonic pricing model of Australia's coking coal exports is estimated for the period JFY1989 to 1996. Non-Japan regional intercept dummy variables were found to be significantly different from zero, although these varied across coal categories and years. However, the empirical evidence indicates that Japan does not pay significantly lower prices relative to other major export markets for coking coal of a given quality.

Lindsay Hogan; Sally Thorpe; Anthony Swan; Simon Middleton

1999-01-01T23:59:59.000Z

247

Coke profile and effect on methane/ethylene conversion process  

E-Print Network [OSTI]

balance in catalytic cracking. It is also extremely important in the dehydrogenation of butane to butadiene, because coke formation limits the cycle time before regeneration of the catalyst is needed. There are many add that equally important examples..., methane, ethane, ethylene, propane, iso-butane, butane, iso-pentane, pentane and hexanes. Also, the flow rate of the effluent stream is measured using the bubble meter. The mole percentages of methane and ethylene are subtracted of the effluent stream...

Al-Solami, Bandar

2002-01-01T23:59:59.000Z

248

New environmental concepts in the chemical and coke industries  

SciTech Connect (OSTI)

We know that environmentally pure technologies do not exist. Coke production is no exception to the rule. The article considers the logic of environmental decision making. Attention focuses on a new bank of ecologically appropriate materials whose release to the biosphere must be considered solely in quantititative terms. Qualitativily all these materials are familiar; they are assimilated by populations of microorganisms and tar thus compatible with the biosphere.

A.Yu. Naletov; V.A. Naletov [Mendeleev Russian Chemical-Engineering University (Russian Federation)

2007-05-15T23:59:59.000Z

249

Table 17. Average Price of U.S. Coke Exports  

U.S. Energy Information Administration (EIA) Indexed Site

Average Price of U.S. Coke Exports Average Price of U.S. Coke Exports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 17. Average Price of U.S. Coke Exports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Destination April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 240.59 241.38 218.40 240.85 225.80 6.7 Canada* 147.49 330.47 243.04 183.08 286.56 -36.1 Mexico 316.57 211.63 189.12 273.97 171.71 59.6 Other** 612.42 485.63 134.48 525.92 135.04 289.5 South America Total 140.65 156.15 322.70 148.29 250.36 -40.8 Other** 140.65 156.15 322.70 148.29 250.36 -40.8 Europe Total 259.26 255.24 - 257.06 427.83 -39.9 Other**

250

Table 22. Average Price of U.S. Coke Imports  

U.S. Energy Information Administration (EIA) Indexed Site

Average Price of U.S. Coke Imports Average Price of U.S. Coke Imports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Table 22. Average Price of U.S. Coke Imports (dollars per short ton) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2013 Year to Date Continent and Country of Origin April - June 2013 January - March 2013 April - June 2012 2013 2012 Percent Change North America Total 263.21 252.66 353.05 261.29 356.01 -26.6 Canada 263.51 252.66 353.05 258.82 356.01 -27.3 Panama 263.09 - - 263.09 - - South America Total 196.86 194.14 175.88 195.94 181.01 8.2 Brazil - - 157.60 - 157.60 - Colombia 196.86 194.14 322.06 195.94 246.68 -20.6 Europe Total 181.55 232.13 385.65 225.53 384.96 -41.4 Czech Republic - 475.91 - 475.91 - - Spain 360.51

251

Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 2, July 1, 1991--September 30, 1991  

SciTech Connect (OSTI)

The EMP consists of a Compliance Monitoring Sampling Program and a Supplemental monitoring Sampling Program. The Compliance Monitoring Sampling Program will be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Project and during a summer and a winter period following the successful Startup and Operational phase of the completed Project. compliance monitoring consist of conducting all the sampling and observation programs associated with existing required Federal, State, and Local Regulations, Permits and Orders. These include air, water, and waste monitoring and OSHA and NESHAP monitoring. The Supplemental Monitoring Program will also be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Demonstration Facility and during a summer and a winter period following the successful startup and Operational phase of the completed Facility. Supplemental Monitoring includes sampling of 27 additional streams that are important to measure operational or environmental performance and impacts of the installation of the new COG treatment facilities.

Not Available

1992-09-21T23:59:59.000Z

252

Innovative coke oven gas cleaning system for retrofit applications: Environmental Monitoring Program. Baseline sampling program report: Volume 2, Appendix sections 1--7  

SciTech Connect (OSTI)

This report contains no text. It consist entirely of results monitoring stack opacity, benzene surveys, chemical effluent in wastewater, etc.

Stuart, L.M.

1994-05-27T23:59:59.000Z

253

Stellar abundances of beryllium and CUBES  

E-Print Network [OSTI]

Stellar abundances of beryllium are useful in different areas of astrophysics, including studies of the Galactic chemical evolution, of stellar evolution, and of the formation of globular clusters. Determining Be abundances in stars is, however, a challenging endeavor. The two Be II resonance lines useful for abundance analyses are in the near UV, a region strongly affected by atmospheric extinction. CUBES is a new spectrograph planned for the VLT that will be more sensitive than current instruments in the near UV spectral region. It will allow the observation of fainter stars, expanding the number of targets where Be abundances can be determined. Here, a brief review of stellar abundances of Be is presented together with a discussion of science cases for CUBES. In particular, preliminary simulations of CUBES spectra are presented, highlighting its possible impact in investigations of Be abundances of extremely metal-poor stars and of stars in globular clusters.

Smiljanic, R

2014-01-01T23:59:59.000Z

254

Beryllium Lymphocyte Proliferation Testing (BeLPT)  

Broader source: Energy.gov (indexed) [DOE]

METRIC METRIC DOE-SPEC-1142-2001 April 2001 DOE SPECIFICATION BERYLLIUM LYMPHOCYTE PROLIFERATION TESTING (BeLPT) U.S. Department of Energy AREA SDMP Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. TS This document has been reproduced from the best available copy. Available to DOE and DOE contractors from ES&H Technical Information Services, U.S. Department of Energy, (800) 473-4375, fax: (301) 903-9823. Available to the public from the U.S. Department of Commerce, Technology Administration, National Technical Information Service, Springfield, VA 22161; (703) 605-6000. DOE-SPEC-1142-2001 iii CONTENTS PARAGRAPH PAGE FOREWORD..........................................................................................v

255

Title 10 CFR Part 850, Chronic Beryllium Disease Prevention Program  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Wednesday Wednesday December 8, 1999 Part III Department of Energy 10 CFR Part 850 Chronic Beryllium Disease Prevention Program; Final Rule VerDate 29-OCT-99 10:58 Dec 07, 1999 Jkt 190000 PO 00000 Frm 00001 Fmt 4717 Sfmt 4717 E:\FR\FM\A08DE0.189 pfrm04 PsN: 08DER3 68854 Federal Register / Vol. 64, No. 235 / Wednesday, December 8, 1999 / Rules and Regulations DEPARTMENT OF ENERGY 10 CFR Part 850 [Docket No. EH-RM-98-BRYLM] RIN 1901-AA75 Chronic Beryllium Disease Prevention Program AGENCY: Office of Environment, Safety and Health, Department of Energy. ACTION: Final rule. SUMMARY: The Department of Energy (DOE) is today publishing a final rule to establish a chronic beryllium disease prevention program (CBDPP) to reduce the number of workers currently exposed to beryllium in the course of their work at DOE facilities managed by

256

Status Report, Department of Energy's Chronic Beryllium Disease...  

Broader source: Energy.gov (indexed) [DOE]

of 10 C.F.R. Part 850, Chronic Beryllium Disease Prevention Program, at the Department of Energy (DOE). The report is based on the results of evaluations of the effectiveness of...

257

Development of pressurized tube specimen for creep testing of beryllium  

SciTech Connect (OSTI)

The purpose of this work was to demonstrate that creep tests could be performed on beryllium in the same pressurized tube geometry as is commonly used in the FFTF/MOTA.

Neef, W.S.; Moir, R.W. (Lawrence Livermore National Lab., CA (USA)); Opperman, E.K. (Westinghouse Hanford Co., Richland, WA (USA)); Hamilton, M.L. (Pacific Northwest Lab., Richland, WA (USA))

1990-12-01T23:59:59.000Z

258

An Integrated Model of Coal/Coke Combustion in a Blast Furnace  

Science Journals Connector (OSTI)

A three?dimensional integrated mathematical model of the combustion of pulverized coal and coke is developed. The model is applied to the region of lance?blowpipe?tuyere?raceway?coke bed to simulate the operation of pulverized coal injection in an ironmaking blast furnace. The model integrates two parts: pulverized coal combustion model in the blowpipe?tuyere?raceway?coke bed and the coke combustion model in the coke bed. The model is validated against the measurements in terms of coal burnout and gas composition respectively. The comprehensive in?furnace phenomena are simulated in the raceway and coke bed in terms of flow temperature gas composition and coal burning characteristics. In addition underlying mechanisms for the in?furnace phenomena are analyzed. The model provides a cost?effective tool for understanding and optimizing the in?furnace flow?thermo?chemical characteristics of the PCI process in full?scale blast furnaces.

Y. S. Shen; B. Y. Guo; A. B. Yu; P. Austin; P. Zulli

2010-01-01T23:59:59.000Z

259

Beryllium pressure vessels for creep tests in magnetic fusion energy  

SciTech Connect (OSTI)

Beryllium has interesting applications in magnetic fusion experimental machines and future power-producing fusion reactors. Chief among the properties of beryllium that make these applications possible is its ability to act as a neutron multiplier, thereby increasing the tritium breeding ability of energy conversion blankets. Another property, the behavior of beryllium in a 14-MeV neutron environment, has not been fully investigated, nor has the creep behavior of beryllium been studied in an energetic neutron flux at thermodynamically interesting temperatures. This small beryllium pressure vessel could be charged with gas to test pressures around 3, 000 psi to produce stress in the metal of 15,000 to 20,000 psi. Such stress levels are typical of those that might be reached in fusion blanket applications of beryllium. After contacting R. Powell at HEDL about including some of the pressure vessels in future test programs, we sent one sample pressure vessel with a pressurizing tube attached (Fig. 1) for burst tests so the quality of the diffusion bond joints could be evaluated. The gas used was helium. Unfortunately, budget restrictions did not permit us to proceed in the creep test program. The purpose of this engineering note is to document the lessons learned to date, including photographs of the test pressure vessel that show the tooling necessary to satisfactorily produce the diffusion bonds. This document can serve as a starting point for those engineers who resume this task when funds become available.

Neef, W.S.

1990-07-20T23:59:59.000Z

260

Assessing the utility of coal’s elementary composition in predicting the yield of coking products  

Science Journals Connector (OSTI)

Elementary analysis of the organic mass of coal does not provide sufficient information to predict the yield of coking products, since it does not reflect the...

M. L. Ulanovskii

2012-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Lignin as Both Fuel and Fusing Binder in Briquetted Anthracite Fines for Foundry Coke Substitute.  

E-Print Network [OSTI]

??Lignin that had been extracted from Kraft black liquor was investigated as a fusing binder in briquetted anthracite fines for a foundry coke substitute. Cupola… (more)

Lumadue, Matthew

2012-01-01T23:59:59.000Z

262

Prediction of demand trends of coking coal in China based on grey linear regression composition model  

Science Journals Connector (OSTI)

The scarce of coking coal resources in China results in its short supply. By establishing a grey linear regression composition model, this paper has greatly improved the inadequacy of grey system prediction model and regression analysis method in trend prediction and finished the prediction of demand trends of coking coal in China with this model. As result of the prediction, it is estimated that in the next decade, the demand for coking coal in China will experience a growth trend; China's demand for coking coal will reach more than 1.535 billion tons by 2015, reach the maximum of 1.639 billion tons by 2020 and drop in 2025.

Hai-Dong Zhou; Qiang Wu; Min Fang; Zhong-Bao Ren; Li-Fei Jin

2013-01-01T23:59:59.000Z

263

Balance of supply and demand in the Russian market for coking-coal concentrates  

Science Journals Connector (OSTI)

Various methods are considered for calculating the balance of supply and demand in the Russian market for coking-coal concentrates within the planning (prediction) period....

V. A. Brodskii

2010-11-01T23:59:59.000Z

264

Co-gasification of biomass with coal and oil sands coke in a drop tube furnace.  

E-Print Network [OSTI]

??Chars were obtained from individual fuels and blends with different blend ratios of coal, coke and biomass in Drop Tube Furnace at different temperatures. Based… (more)

Gao, Chen

2010-01-01T23:59:59.000Z

265

MOLECULAR COMPOSITION OF NEEDLE COKE FEEDSTOCKS AND MESOPHASE DEVELOPMENT DURING CARBONIZATION.  

E-Print Network [OSTI]

??This study investigates the molecular composition of fluid catalytic cracking (FCC) decant oil and its derivatives that are used as feedstocks for delayed coking to… (more)

Wang, Guohua

2005-01-01T23:59:59.000Z

266

Pyrolysis behavior of coal and petroleum coke at high temperature and high pressure.  

E-Print Network [OSTI]

??While pyrolysis of coal is a well-studied thermal process, little is known about pressurized pyrolysis of coal and petroleum coke. This study aims to interpret… (more)

Wagner, David Ray

2011-01-01T23:59:59.000Z

267

Development Of Reclamation Substrates For Alberta Oil Sands Using Mature Fine Tailings And Coke.  

E-Print Network [OSTI]

??Mature fine tailings and coke are waste products of the oil sands industry with potential for reclamation. A greenhouse study assessed whether substrates of various… (more)

Luna-Wolter, Gabriela L.

2012-01-01T23:59:59.000Z

268

Investigating factors that influence carbon dissolution from Coke into Molten iron.  

E-Print Network [OSTI]

??The need for more efficient blast furnaces is even greater now that there are stricter environmental regulations on greenhouse gas (GHG) emissions. Coke within the… (more)

Cham, S. Tsuey

2007-01-01T23:59:59.000Z

269

Simulation of Combustion and Thermal-flow Inside a Petroleum Coke Rotary Calcining Kiln.  

E-Print Network [OSTI]

??Calcined coke is the best material for making carbon anodes for smelting of alumina to aluminum. Calcining is an energy intensive industry and a significant… (more)

Zhang, Zexuan

2007-01-01T23:59:59.000Z

270

Coke yield and transport processes in agglomerates of bitumen and solids.  

E-Print Network [OSTI]

??Agglomerate formation is a common phenomenon that can cause operating problems in the fluid coking reactor. When agglomerates form they provide longer diffusion paths of… (more)

Ali, Mohamed Ali Hassan

2010-01-01T23:59:59.000Z

271

Characterization of Coke Properties at Tuyere Level of an Operating Blast Furnace.  

E-Print Network [OSTI]

??Coke performance in an operating blast furnace is often empirically related to popular bench-scale tests, which are performed at relative much lower temperatures. Due to… (more)

Ye, Zhuozhu

2014-01-01T23:59:59.000Z

272

Preparation of Activated Carbon from Oil Sands Coke by Chemical and Physical Activation Techniques.  

E-Print Network [OSTI]

??Oil sands coke is a by-product resulting from the upgrading of heavy crude bitumen to light synthetic oil. This research investigates the preparation of activated… (more)

Morshed, Golam

2012-01-01T23:59:59.000Z

273

The effect of diabietic acid on the coking of oxidised solvent-extracted coal.  

E-Print Network [OSTI]

??Refcoal is a refined carbon source obtained by extraction of coal with dimethylformamide (DMF). During the coking process, Refcoal goes through a mesophase (fluid) stage… (more)

Ludere, Margaret Tshimangadzo

2008-01-01T23:59:59.000Z

274

Integration of stripping of fines slurry in a coking and gasification process  

DOE Patents [OSTI]

In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

DeGeorge, Charles W. (Chester, NJ)

1980-01-01T23:59:59.000Z

275

The effects of ash and maceral composition of Azdavay and Kurucasile (Turkey) coals on coking properties  

SciTech Connect (OSTI)

In this study, investigations were made as to the effect of the maceral compositions and mineral matter content of Azdavay and Kurucasile coals on the coking property. Chemical and maceral analyses and coking properties were determined for the products of the float-sink procedure. The coking properties were established on the basis of free swelling index and Ruhr dilatometer tests. Maceral analyses showed that as the ash content of a coal containing both high and medium volatile matter increases, its effective maceral proportion decreases, and the coking property is affected in an unfavorable way.

Toroglu, I. [Zonguldak Karaelmas University, Zonguldak (Turkey). Faculty of Engineering

2006-07-01T23:59:59.000Z

276

New Energy Efficiency Standards for Microwave Ovens to Save Consumers on  

Broader source: Energy.gov (indexed) [DOE]

Energy Efficiency Standards for Microwave Ovens to Save Energy Efficiency Standards for Microwave Ovens to Save Consumers on Energy Bills New Energy Efficiency Standards for Microwave Ovens to Save Consumers on Energy Bills May 31, 2013 - 3:26pm Addthis NEWS MEDIA CONTACT (202) 586-4940 WASHINGTON - U.S. Energy Secretary Ernest Moniz announced today that the Energy Department has finalized new energy efficiency standards for microwave ovens that will save consumers nearly $3 billion on their energy bills through 2030. Over the next 30 years, it will dramatically reduce harmful carbon pollution, equivalent to taking over 12 million new cars off the road for one year. "Appliance efficiency standards represent a huge opportunity to help families save money by saving energy, while still delivering high quality

277

CHARACTERIZATION OF COAL- AND PETROLEUM-DERIVED BINDER PITCHES AND THE INTERACTION OF PITCH/COKE MIXTURES IN PRE-BAKED CARBON ANODES.  

E-Print Network [OSTI]

??Carbon anodes are manufactured from calcined petroleum coke (i.e. sponge coke) and recycled anode butts as fillers, and coal tar pitch (SCTP) as the binder.… (more)

Suriyapraphadilok, Uthaiporn

2008-01-01T23:59:59.000Z

278

Sectoral trends in global energy use and greenhouse gas emissions  

E-Print Network [OSTI]

factors for production of coal products -- patent fuel, cokeoven coke,coke oven gas, blast furnace gas and briquettes (BKB) --

2006-01-01T23:59:59.000Z

279

Controlling Beryllium Contaminated Material And Equipment For The Building 9201-5 Legacy Material Disposition Project  

SciTech Connect (OSTI)

This position paper addresses the management of beryllium contamination on legacy waste. The goal of the beryllium management program is to protect human health and the environment by preventing the release of beryllium through controlling surface contamination. Studies have shown by controlling beryllium surface contamination, potential airborne contamination is reduced or eliminated. Although there are areas in Building 9201-5 that are contaminated with radioactive materials and mercury, only beryllium contamination is addressed in this management plan. The overall goal of this initiative is the compliant packaging and disposal of beryllium waste from the 9201-5 Legacy Material Removal (LMR) Project to ensure that beryllium surface contamination and any potential airborne release of beryllium is controlled to levels as low as practicable in accordance with 10 CFR 850.25.

Reynolds, T. D.; Easterling, S. D.

2010-10-01T23:59:59.000Z

280

The effects of petroleum coke amendments on macrophytes and aquatic invertebrates in northern Alberta, Canada constructed wetlands.  

E-Print Network [OSTI]

??Oil-sands operators of Fort McMurray, Alberta produce six million t/y of petroleum coke. The use of coke to stabilize clay-dominated mine tailings in constructed wetlands… (more)

Baker, Leanne F.

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Predicting CSR and CRI of coke on the basis of the chemical and petrographic parameters of the coal batch and the coking conditions  

Science Journals Connector (OSTI)

A model is developed for predicting the postreactive strength CSR and reactivity CRI of coke. The model adequately reflects the dependence of ... on the chemical and petrographic parameters of the coal batch, tak...

A. S. Stankevich; R. R. Gilyazetdinov; N. K. Popova; D. A. Koshkarov

2008-09-01T23:59:59.000Z

282

Modification of sub-bituminous coal by steam treatment: Caking and coking properties  

Science Journals Connector (OSTI)

A Chinese sub-bituminous Shenfu (SF) coal was steam treated under atmospheric pressure and the caking and coking properties of the treated coals were evaluated by caking indexes (GRI) and crucible coking characterizations. The results show that steam treatment can obviously increase the GRI of SF coal. When the steam treated coals were used in the coal blends instead of SF raw coal, the micro-strength index (MSI) and particle coke strength after reaction (PSR) of the coke increased, and particle coke reactivity index (PRI) decreased, which are beneficial for metallurgical coke to increase the gas permeability in blast furnace. The quality of the coke obtained from 8% of 200 °C steam treated SF coal in coal blends gets to that of the coke obtained from the standard coal blends, in which there was no SF coal addition in the coal blends. The removal of oxygen groups, especially hydroxyl group thus favoring the breakage of the coal macromolecules and allowing the treated coal formation of much more amount of hydrocarbons, may be responsible for the modified results. The mechanism of the steam treatment was proposed based on the elemental analysis, thermo gravimetric (TG) and FTIR spectrometer characterizations of the steam treated coal.

Hengfu Shui; Haiping Li; Hongtao Chang; Zhicai Wang; Zhi Gao; Zhiping Lei; Shibiao Ren

2011-01-01T23:59:59.000Z

283

Study on Further Treatment of Coal Coking Wastewater by Ultrasound Wave, Fenton's Reagent and Coagulation  

Science Journals Connector (OSTI)

The study on further treatment of coal coking wastewater by ultrasound wave, Fenton's reagent and coagulation was carried out in this paper at the first time, Furthermore, this paper discussed the optimum cooperative reaction condition of their combined ... Keywords: ultrasound wave, coke plant wastewater, Fenton reagent, coagulation

Jun Shi; Liangbo Zhang

2009-10-01T23:59:59.000Z

284

Analytical input-output and supply chain study of China's coke and steel sectors  

E-Print Network [OSTI]

I design an input-output model to investigate the energy supply chain of coal-coke-steel in China. To study the demand, supply, and energy-intensity issues for coal and coke from a macroeconomic perspective, I apply the ...

Li, Yu, 1976-

2004-01-01T23:59:59.000Z

285

Cyanide Leaching from Soil Developed from Coking Plant Purifier Waste as Influenced by Citrate  

Science Journals Connector (OSTI)

...Coking Plant Purifier Waste as Influenced by Citrate...developed from gas purifier waste was investigated. Without...developed from gas purifier waste near a former coking...for the iron and steel industries. Their gas was a by-product...2003). During coal gasification, hydrogen cyanide...

Tim Mansfeldt; Heike Leyer; Kurt Barmettler; Ruben Kretzschmar

286

Influence of coal on coke properties and blast-furnace operation  

SciTech Connect (OSTI)

With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

2007-07-01T23:59:59.000Z

287

Carbonization of Coal Effects of Variation of Rate of Heating during the Carbonization of a Typical Coking Coal  

Science Journals Connector (OSTI)

Carbonization of Coal Effects of Variation of Rate of Heating during the Carbonization of a Typical Coking Coal ...

William B. Warren

1935-01-01T23:59:59.000Z

288

Carbonization of Coal Evaluation of Effects of Rate of Heating and of Maximum Temperature on Pyrolysis of a Coking Coal  

Science Journals Connector (OSTI)

Carbonization of Coal Evaluation of Effects of Rate of Heating and of Maximum Temperature on Pyrolysis of a Coking Coal ...

William B. Warren

1935-01-01T23:59:59.000Z

289

Atmospheric Oxidation of Coal at Moderate Temperatures. Effect of Oxidation on the Carbonizing Properties of Representative Coking Coals.  

Science Journals Connector (OSTI)

Atmospheric Oxidation of Coal at Moderate Temperatures. ... Effect of Oxidation on the Carbonizing Properties of Representative Coking Coals. ...

L Schmidt; J Elder; J Davis

1940-01-01T23:59:59.000Z

290

Acidity deterioration and coke deposition in a HZSM5 zeolite in the MTG process  

Science Journals Connector (OSTI)

Summary The total acidity deterioration and the acidity strength distribution of a catalyst prepared from a H-ZSM-5 zeolite has been studied in the MTG process carried out in catalytic chamber and in an isothermal fixed bed integral reactor. The acidity deterioration has been related to coke deposition. The evolution of the acidic structure and of coke deposition has been analysed in situ by diffuse reflectance FTIR in a catalytic chamber. The effect of operating conditions (time on stream and temperature) on acidity deterioration, coke deposition and coke nature has been studied from experiments in a fixed integral reactor. The technique for studying acidity yields a reproducible measurement of total acidity and acidity strength distribution of the catalyst deactivated by coke. The NH3 adsorption-desorption is measured by combination of scanning differential calorimetry and the FTIR analysis of the products desorbed.

A.T. Aguayo; P.L. Benito; A.G. Gayubo; M. Olazar; J. Bilbao

1994-01-01T23:59:59.000Z

291

BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS  

Office of Legacy Management (LM)

BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS IN LUCKEY, OHIO October 27, 1989 Prepared for: U.S. Department of Energy Formerly Utilized Sites Remedial Action Program Prepared by: R.F. Weston/Office of Technical Services BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS IN LUCKEY, OHIO INTRODUCTION The Department of Energy (DOE) is conducting a program to identify and examine the radiological conditions at sites used in the early years of nuclear energy development by the U.S. Army Corps of Engineer's Manhattan Engineer District (MED) and the Atomic Energy Commission (AEC). This program, the Formerly Utilized Sites Remedial Action Program (FUSRAP), is administered by the Assistant Secretary for Nuclear Energy through the

292

LLNL Chronic Beryllium Disease Protection Program Effectiveness Review, March 2011  

Broader source: Energy.gov (indexed) [DOE]

LLNL-2011-03-25 LLNL-2011-03-25 Site: Lawrence Livermore National Laboratory Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the Lawrence Livermore National Laboratory Chronic Beryllium Disease Prevention Program Effectiveness Review Dates of Activity : 03/14/2011 - 03/25/2011 Report Preparer: Marvin Mielke Activity Description/Purpose: The Lawrence Livermore National Laboratory (LLNL) and the Livermore Site Office (LSO) chartered a team to conduct an effectiveness review of the issues identified with the LLNL Chronic Beryllium Disease Prevention Program (CBDPP). The team included members and observers from LLNL, LSO, the National Nuclear Security Administration (NNSA), and the

293

Elemental composition in sealed plutonium–beryllium neutron sources  

Science Journals Connector (OSTI)

Abstract Five sealed plutonium–beryllium (PuBe) neutron sources from various manufacturers were disassembled. Destructive chemical analyses for recovered PuBe materials were conducted for disposition purposes. A dissolution method for PuBe alloys was developed for quantitative plutonium (Pu) and beryllium (Be) assay. Quantitation of Be and trace elements was performed using plasma based spectroscopic instruments, namely inductively coupled plasma mass spectrometry (ICP-MS) and atomic emission spectrometry (ICP-AES). Pu assay was accomplished by an electrochemical method. Variations in trace elemental contents among the five PuBe sources are discussed.

N. Xu; K. Kuhn; D. Gallimore; A. Martinez; M. Schappert; D. Montoya; E. Lujan; K. Garduno; L. Tandon

2015-01-01T23:59:59.000Z

294

Method for removal of beryllium contamination from an article  

DOE Patents [OSTI]

A method of removal of beryllium contamination from an article is disclosed. The method typically involves dissolving polyisobutylene in a solvent such as hexane to form a tackifier solution, soaking the substrate in the tackifier to produce a preform, and then drying the preform to produce the cleaning medium. The cleaning media are typically used dry, without any liquid cleaning agent to rub the surface of the article and remove the beryllium contamination below a non-detect level. In some embodiments no detectible residue is transferred from the cleaning wipe to the article as a result of the cleaning process.

Simandl, Ronald F.; Hollenbeck, Scott M.

2012-12-25T23:59:59.000Z

295

LLNL Chronic Beryllium Disease Protection Program Effectiveness Review, March 2011  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LLNL-2011-03-25 LLNL-2011-03-25 Site: Lawrence Livermore National Laboratory Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the Lawrence Livermore National Laboratory Chronic Beryllium Disease Prevention Program Effectiveness Review Dates of Activity : 03/14/2011 - 03/25/2011 Report Preparer: Marvin Mielke Activity Description/Purpose: The Lawrence Livermore National Laboratory (LLNL) and the Livermore Site Office (LSO) chartered a team to conduct an effectiveness review of the issues identified with the LLNL Chronic Beryllium Disease Prevention Program (CBDPP). The team included members and observers from LLNL, LSO, the National Nuclear Security Administration (NNSA), and the

296

Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil  

SciTech Connect (OSTI)

In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

2009-05-15T23:59:59.000Z

297

Integrated two stage coking and steam cracking process and apparatus therefor  

SciTech Connect (OSTI)

The invention relates to an improvement in an integrated, two stage coking and steam cracking process for the production of unsaturated light hydrocarbons. A heavy hydrocarbonaceous oil is first coked in a fluidized bed coking zone. The vaporous conversion product is passed to a dilute phase. High temperature cracking in the presence of steam is carried out on the vaporous coker conversion product by injecting into the vapors a stream of hot coke particles at a sufficient temperature and in sufficient amount to raise the coker vapors to steam cracking temperature and supply the endothermic heat of reaction. Solids are separated from product gas in a gas-solids separation zone such as one or more cyclones and sent to the fluid coking zone and the gas is quenched to stop olefin degradation reactions. According to the improvement, relatively low temperature steam is introduced into contact with the separated solids to superheat the steam and cool the solids. Suitably this is effected in a riser on the cyclone dipleg. The solids, after having given up heat to the steam, pass into the coking zone and the superheated steam passes into the dilute phase and serves as part of the dilution steam therefor. Conservation of fuel and mitigation of coke on reactor walls and equipment are advantages of the process.

Oldweiler, M.E.

1983-10-25T23:59:59.000Z

298

ORISE: Beryllium Testing and Surveillance for the U.S. Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Beryllium Testing and Surveillance Beryllium Testing and Surveillance Beryllium Testing Laboratory worker Beryllium, a metal used in many industries, including aerospace, defense and nuclear weapons production, can have harmful health effects when inhaled as dust or fumes from machining or manufacturing activities. The Oak Ridge Institute for Science and Education (ORISE) manages one of only four laboratories in the country that perform the beryllium lymphocyte proliferation test (LPT), which detects the worker's sensitization to beryllium and helps identify workers who have or are at risk of developing chronic beryllium disease (CBD). The laboratory is certified under the Clinical Laboratory Improvement Act (CLIA) guidelines and has been awarded the prestigious College of American Pathologists (CAP) certification.

299

Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report No. 1, May 1--August 1, 1998  

SciTech Connect (OSTI)

The overall aim of the project is to demonstrate the performance and practical use of a laser ultrasonic probe for measuring the thickness of coke deposits located within the high temperature tubes of a thermal cracking furnace. This aim will be met by constructing an optical probe that will be tested using simulated coke deposits that are positioned inside of a bench-scale furnace. Successful development of the optical coke detector will provide industry with the only available method for on-line measurement of coke deposits. The optical coke detector will have numerous uses in the refining and petrochemical sectors including monitoring of visbreakers, hydrotreaters, delayed coking units, vacuum tower heaters, and various other heavy oil heating applications where coke formation is a problem. The coke detector will particularly benefit the olefins industry where high temperature thermal crackers are used to produce ethylene, propylene, butylene and other important olefin intermediates. The ethylene industry requires development of an on-line method for gauging the thickness of coke deposits in cracking furnaces because the current lack of detailed knowledge of coke deposition profiles introduces the single greatest uncertainty in the simulation and control of modern cracking furnaces. The laser ultrasonic coke detector will provide operators with valuable new information allowing them to better optimize the decoking turnaround schedule and therefore maximize production capacity.

NONE

1998-08-15T23:59:59.000Z

300

Nuclear Magnetic Resonance and Ruthenium Ion Catalyzed Oxidation Reaction Analysis for Further Development of Aromatic Ring Size through the Heat Treatment of Coking Coals at >500 °C  

Science Journals Connector (OSTI)

The strategy for coal blending is based on many empirical viewpoints, while scientific findings are believed to develop new criteria for obtaining high-quality coke from not only coking coals but also coking coals coupled with noncoking coals. ... by TEM and by comparing the microtextures of their cokes. ...

Koh Kidena; Koji Matsumoto; Satoru Murata; Masakatsu Nomura

2004-10-23T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Annual book of ASTM Standards 2008. Section Five. Petroleum products, lubricants, and fossil fuels. Volume 05.06. Gaseous fuels; coal and coke  

SciTech Connect (OSTI)

The first part covers standards for gaseous fuels. The second part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrogrpahic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

NONE

2008-09-15T23:59:59.000Z

302

Annual book of ASTM Standards 2005. Section Five. Petroleum products, lubricants, and fossil fuels. Volume 05.06. Gaseous fuels; coal and coke  

SciTech Connect (OSTI)

The first part covers standards for gaseous fuels. The standard part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrographic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

NONE

2005-09-15T23:59:59.000Z

303

Investigation of the effects of heating rate on coking of shale during retorting  

SciTech Connect (OSTI)

The retorting of oil shale distributes organic carbon among three possible products: the liquid product, the noncondensible product, and the residual carbon (coke). The production of coke is detrimental because of the economic effects caused by the loss of organic carbon to this relatively intractable carbon form. Two reference oil shales, a Mahogany zone, Parachute Creek Member, Green River Formation oil shale from Colorado and a Clegg Creek Member, New Albany oil shale from Kentucky, were studied to evaluate the conditions that affect coke production during retorting. The variable that was studied in these experiments was the heating rate during retorting because heating rate has been indicated to have a direct effect on coke production (Burnham and Clarkson 1980). The six heating rates investigated covered the range from 1 to 650/degree/C/h (1.8 to 1169/degree/F/h). The data collected during these experiments were evaluated statistically in order to identify trends. The data for the eastern reference oil shale indicated a decrease in coke formation with increases in the heating rate. The liquid and noncondensible product yields both increased with increasing heating rate. The distribution of products in relation to retort heating rate follows the model suggested by Burnham and Clarkson (1980). Coke production during the retorting of western reference oil shale was found to be constant in relation to heating rate. The liquid product yield increased with increasing heating rate but the trend could not be verified at the 95% confidence level. The coke production observed in these experiments does not follow the prediction of the model. This may indicate that coke formation occurs early in the retorting process and may be limited by the availability of organic materials that form coke. 6 refs., 10 tabs.

Guffey, F.D.; Hunter, D.E.

1988-02-01T23:59:59.000Z

304

Caking and coking properties of the thermal dissolution soluble fraction of a fat coal  

Science Journals Connector (OSTI)

Abstract In the coal blending for coke-making, fat coal has a very important role for the caking and coking properties of the coal blends. In this study, a fat coal was thermally dissolved, and the caking and coking properties of the thermal dissolution soluble factions (TDSFs) from different solvents and temperatures were characterized. It was found that the caking properties of \\{TDSFs\\} were better than that of fat raw coal. The \\{TDSFs\\} obtained from non-polar solvents have a higher caking property than those obtained from polar solvents at the same thermal dissolution (TD) temperature. During TD process, polar solvents can thermally dissolve more polyaromatic compounds into TDSF, thus increasing the softening temperature and decreasing the caking property of the TDSF. For the same TD solvent, the \\{TDSFs\\} obtained from higher temperatures have a lower caking property compared to those obtained from lower temperatures because of more aromatic components and oxygen functional groups entering them. Crucible coking determinations were carried out to evaluate the coking property of the TDSFs. The result suggests that when 5% of TDSF and 5% of non-caking sub-bituminous coal were used instead of the same amount of fat coal and gas coal, respectively in the coal blends, the quality of the coke obtained could get to the level of the coke obtained from the standard coal blends (i.e. without TDSF and sub-bituminous coal). Therefore, the use of TDSF in coal blending for coke-making is one of the effective methods for opening the coking coal resources.

Hengfu Shui; Wenjuan Zhao; Chuanjun Shan; Tao Shui; Chunxiu Pan; Zhicai Wang; Zhiping Lei; Shibiao Ren; Shigang Kang

2014-01-01T23:59:59.000Z

305

Characterization of the origin and distribution of the minerals and phases in metallurgical cokes  

SciTech Connect (OSTI)

Three industrial metallurgical cokes were examined using X-ray diffraction (XRD) and scanning electron microscopy combined with energy dispersive X-ray analysis (SEM/EDS). The study highlighted the difficulties and implications of identifying the inherent crystalline mineral phases in cokes using XRD such that increasing the ashing temperature led to the formation of anhydrite and destruction of metallic iron: microwave plasma ashing resulted in minimal alteration of the original coke mineralogy apart from the formation of bassanite and possibly jarosite. A preliminary scheme to characterize coke minerals is presented such that, physically, minerals can be classified as fine ({lt}50 {mu}m), coarse (50-100 {mu}m), and agglomerate ({gt}1000 {mu}m); chemically, minerals can be grouped as refractory, semirefractory, and reactive, while on the basis of distribution they can be described as discrete, disseminated, or pore inclusions. Quartz, cristobalite, mullite, and high melting point Al-silicates were found to be the predominant refractory phases while low melting point Al-silicates, e.g., containing high fluxing elements such as K, and Fe were the main semirefractory phases present in all cokes. A variety of iron containing phases including pyrrhotite, troilite, iron oxides, metallic iron, and iron silicates were also invariably present in all cokes while calcium phases were found to occur as sulfide, silicates, and phosphates. In general, iron and calcium phases can be categorized as reactive phases with few exceptions such as oldhamite (CaS). The study highlighted that most of the cokes possess a similar mineralogy, with the main distinction being in their relative abundance, particle size, and nature of distribution in the coke matrix. The study provides a basis to develop a mechanistic understanding of the influence of minerals on coke reactivity and strength at high temperatures. 41 refs., 13 figs., 4 tabs.

Sushil Gupta; Maria Dubikova; David French; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). School of Materials Science and Engineering

2007-01-15T23:59:59.000Z

306

Energy efficiency of alternative coke-free metallurgical technologies  

SciTech Connect (OSTI)

Energy analysis is undertaken for the blast-furnace process, for liquid-phase processes (Corex, Hismelt, Romelt), for solid-phase pellet reduction (Midrex, HYL III, LP-V in a shaft furnace), for steel production in systems consisting of a blast furnace and a converter, a Midrex unit and an arc furnace, or a Romelt unit and an arc furnace, and for scrap processing in an arc furnace or in an LP-V shaft furnace. Three blast-furnace processes with sinter and coke are adopted as the basis of comparison, as in: the standard blast-furnace process used in Russia; the improved blast-furnace process with coal-dust injection; and the production of vanadium hot metal from vanadium-bearing titanomagnetite ore (with a subsequent duplex process, ferrovanadium production, and its use in the arc furnace).

V.G. Lisienko; A.V. Lapteva; A.E. Paren'kov [Ural State Technical University - Ural Polytechnic Institute, Yekaterinburg (Russian Federation)

2009-02-15T23:59:59.000Z

307

Beryllium Wipe Sampling (differing methods - differing exposure potentials)  

SciTech Connect (OSTI)

This research compared three wipe sampling techniques currently used to test for beryllium contamination on room and equipment surfaces in Department of Energy facilities. Efficiencies of removal of beryllium contamination from typical painted surfaces were tested by wipe sampling without a wetting agent, with water-moistened wipe materials, and by methanol-moistened wipes. Analysis indicated that methanol-moistened wipe sampling removed about twice as much beryllium/oil-film surface contamination as water-moistened wipes, which removed about twice as much residue as dry wipes. Criteria at 10 CFR 850.30 and .31 were established on unspecified wipe sampling method(s). The results of this study reveal a need to identify criteria-setting method and equivalency factors. As facilities change wipe sampling methods among the three compared in this study, these results may be useful for approximate correlations. Accurate decontamination decision-making depends on the selection of appropriate wetting agents for the types of residues and surfaces. Evidence for beryllium sensitization via skin exposure argues in favor of wipe sampling with wetting agents that provide enhanced removal efficiency such as methanol when surface contamination includes oil mist residue.

Kerr, Kent

2005-03-09T23:59:59.000Z

308

Identification of an abnormal beryllium lymphocyte proliferation test  

Science Journals Connector (OSTI)

The potential hazards from exposure to beryllium or beryllium compounds in the workplace were first reported in the 1930s. The tritiated thymidine beryllium lymphocyte proliferation test (BeLPT) is an in vitro blood test that is widely used to screen beryllium exposed workers in the nuclear industry for sensitivity to beryllium. The clinical significance of the BeLPT was described and a standard protocol was developed in the late 1980s. Cell proliferation is measured by the incorporation of tritiated thymidine into dividing cells on two culture dates and using three concentrations of beryllium sulfate. Results are expressed as a ‘stimulation index’ (SI) which is the ratio of the amount of tritiated thymidine (measured by beta counts) in the simulated cells divided by the counts for the unstimulated cells on the same culture day. Several statistical methods for use in the routine analysis of the BeLPT were proposed in the early 1990s. The least absolute values (LAV) method was recommended for routine analysis of the BeLPT. This report further evaluates the LAV method using new data, and proposes a new method for identification of an abnormal or borderline test. This new statistical–biological positive (SBP) method reflects the clinical judgment that: (i) at least two \\{SIs\\} show a ‘positive’ response to beryllium; and (ii) that the maximum of the six \\{SIs\\} must exceed a cut-point that is determined from a reference data set of normal individuals whose blood has been tested by the same method in the same serum. The new data is from the Y-12 National Security Complex in Oak Ridge (Y-12) and consists of 1080 workers and 33 non-exposed control BeLPTs (all tested in the same serum). Graphical results are presented to explain the statistical method, and the new SBP method is applied to the Y-12 group. The true positive rate and specificity of the new method were estimated to be 86% and 97%, respectively. An electronic notebook that is accessible via the Internet was used in this work and contains background information and details not included in the paper.

Edward L Frome; Lee S Newman; Donna L Cragle; Shirley P Colyer; Paul F Wambach

2003-01-01T23:59:59.000Z

309

A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.  

E-Print Network [OSTI]

other bituminous coal and coking coal. Small differences incoal (used as fuel) Coking coal Coke oven coke Natural gasrange for typical NCVs of coking coal of 26.6 to 29.8Mj/kg.

Hasanbeigi, Ali

2012-01-01T23:59:59.000Z

310

Researches on the Chemistry of Coal. Part II. The Resinic Constituents and Coking Propensitie of Coals  

Science Journals Connector (OSTI)

1 March 1922 research-article Researches on the Chemistry of Coal. Part II. The Resinic Constituents and Coking Propensitie of Coals William A. Bone A. R. Pearson E. Sinkinson W. E. Stockings The Royal Society is...

1922-01-01T23:59:59.000Z

311

A relationship for the evaluation o coking values of coal tar pitches from their physical characteristics  

Science Journals Connector (OSTI)

A relationship has been proposed to evaluate the coking values of coal tar pitches from the knowledge of their ... It has been tried on 44 self-prepared coal tar pitches and 18 others obtained from ... -ranging c...

G. Bhatia; R. K. Aggarwal; O. P. Bahl

1987-11-01T23:59:59.000Z

312

THE PREDICTED COKE STRENGTH AFTER REACTION VALl JES OF BRITISH COLUMBIA COALS, WITH COMPARISONS TCOALS  

E-Print Network [OSTI]

This paper provides background to the coke strength after reaction (CSR) test and gives perspective regarding changes in the cokinp coal market. It provides it sumtnary of some of the predicted relationships hctween the ash chemistry of

D. Ryan; B. C. Geological; Survey Branch; John T. Price; Canada Centre For Mineral; Energy Technology

313

Kinetics of catalyst regeneration by coke combustion. II. Influence of temperature rise in the catalyst particles  

Science Journals Connector (OSTI)

A grain-pellet model has been used to study the effect of high reaction rates upon the temperature profiles developed during regeneration of coked catalyst particles. The possibility of falsification of kinetic.....

D. Lafarga; C. Royo; A. Monzón; M. Menéndez…

1991-08-01T23:59:59.000Z

314

Experimental Study on Co-gasification of Coal Liquefaction Residue and Petroleum Coke  

Science Journals Connector (OSTI)

An experimental study on co-gasification of coal liquefaction residue and petroleum coke in carbon dioxide was investigated by thermogravimetric analysis. The temperature of the experiment was 1173–1323 K, and the isothermal (1273 K) kinetics were ...

Xin Liu; Zhi-jie Zhou; Qi-jing Hu; Zheng-hua Dai; Fu-chen Wang

2011-06-20T23:59:59.000Z

315

Industrial experience with the thermal preparation of coal batch before coking  

Science Journals Connector (OSTI)

The basic industrial results obtained with thermal preparation of batch, followed by bed coking in horizontal furnaces, are briefly reviewed. Precarbon technology, which, in various forms, has been successfull...

Yu. S. Vasil’ev; A. I. Gordienko; G. V. Dolgarev

2008-07-01T23:59:59.000Z

316

Pyrolysis kinetics of coking coal mixed with biomass under non-isothermal and isothermal conditions  

Science Journals Connector (OSTI)

Abstract To investigate the kinetic characteristics of coking coal mixed with biomass during pyrolysis, thermogravimetric (TG) and thermo-balance reactor (TBR) analyses were conducted under non-isothermal and isothermal condition. Yellow poplar as a biomass (B) was mixed with weak coking coal (WC) and hard coking coal (HC), respectively. The calculated activation energies of WC/B blends were higher than those of HC/B blends under non-isothermal and isothermal conditions. The coal/biomass blends show increased reactivity and decreased activation energy with increasing biomass blend ratio, regardless of the coking properties of the coal. The different char structures of the WC/B and HC/B blends were analyzed by BET and SEM.

Ha Myung Jeong; Myung Won Seo; Sang Mun Jeong; Byung Ki Na; Sang Jun Yoon; Jae Goo Lee; Woon Jae Lee

2014-01-01T23:59:59.000Z

317

Synthesis of super plasticizer NF-30 from coal coking by product washing oil and performance analysis  

Science Journals Connector (OSTI)

Super plasticizer was synthesized by using coal coking by product washing oil and industrial naphthalene....2 in exhaust (20%). Compared with NF, NF-30 have some advantages in lower cost, high water reducing rate...

Zifang Xu ???; Mingxu Zhang; Wenpei Hu

2013-10-01T23:59:59.000Z

318

Effect of Adsorption Contact Time on Coking Coal Particle Desorption Characteristics  

Science Journals Connector (OSTI)

Effect of Adsorption Contact Time on Coking Coal Particle Desorption Characteristics ... Esp. in the last decade a large amt. of data has been published characterizing coals from various coal basins world-wide for their gas sorption capacity. ...

Wei Zhao; Yuanping Cheng; Meng Yuan; Fenghua An

2014-03-20T23:59:59.000Z

319

High-Temperature Stress Relaxation Cracking and Stress Rupture Observed in a Coke Gasifier Failure  

Science Journals Connector (OSTI)

This article discusses the high-temperature metal degradation mechanisms that occurred in the failure of a nine-story tall coke gasifier, located in a refinery power plant. Cracking of gasifier internals, bulging...

Daniel J. Benac; Douglas B. Olson…

2011-06-01T23:59:59.000Z

320

Guide to ASTM test methods for the analysis of coal and coke  

SciTech Connect (OSTI)

The guide includes brief descriptions of all 56 ASTM test methods that cover the physical, chemical, and spectroscopic analytical techniques to qualitatively and quantitatively identify over 40 chemical and physical properties of coal, coke, their products, and by-products.

R.A. Kishore Nadkarni (ed.)

2008-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

The development of Coke Carried-Heat Gasification Coal-Fired Combined Cycle  

Science Journals Connector (OSTI)

Carried-Heat Partial Gasification Combined cycle is a novel combined cycle which was proposed by Thermal Engineering Department ... technology, Coke Carried-Heat Gasification Coal-Fired Combined Cycle, as the imp...

Li Zhao; Xiangdong Xu

1999-12-01T23:59:59.000Z

322

Hydrogen Generation and Coke Formation over a Diesel Oxidation Catalyst under Fuel Rich Conditions  

Science Journals Connector (OSTI)

Hydrogen Generation and Coke Formation over a Diesel Oxidation Catalyst under Fuel Rich Conditions† ... Hydrogen production via hydrocarbon steam reforming and water gas shift reactions was investigated over a monolith-supported Pt-based diesel oxidation catalyst. ...

Meshari AL-Harbi; Jin-Yong Luo; Robert Hayes; Martin Votsmeier; William S. Epling

2010-12-08T23:59:59.000Z

323

Current developments at Giprokoks for coke-battery construction and reconstruction  

SciTech Connect (OSTI)

Approaches developed at Giprokoks for coke-battery construction and reconstruction are considered. Recommendations regarding furnace construction and reconstruction are made on the basis of Ukrainian and world experience.

V.I. Rudyka; Y.E. Zingerman; V.B. Kamenyuka; O.N. Surenskii; G.E. Kos'kova; V.V. Derevich; V.A. Gushchin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

324

Producing and controlling of the pollutant in the coal`s coking process  

SciTech Connect (OSTI)

In the process of heating and coke shaping, different pollutants and polluting factors will be produced and lost to the environment due to the different coking methods. The paper analyzes the production mechanism, type, emission, average quantity, and damage to the environment of the major pollutants and polluting factors produced in several kinds of coking processes in China at the present. Then, the paper concludes that an assessment for any coking method should include a comprehensive beneficial assessment of economical benefit, environmental benefit and social benefit. The items in the evaluation should consist of infrastructure investment, which includes production equipment and pollution control equipment, production cost, benefit and profit produced by one ton coal, whether the pollution complies with the environmental requirement, extent of the damage, influence to the social development, and etc.

Li, S. [Shanxi Environmental Protection Bureau (China); Fan, Z. [Shanxi Central Environmental Monitoring Station (China)

1997-12-31T23:59:59.000Z

325

Three-dimensional simulation of combustion processes in coke-battery furnace chambers  

Science Journals Connector (OSTI)

A three-dimensional model of the heating wall in a coke battery is developed by means of the Fluent CFD program. The results of simulation are in satisfactory agreement with experimental data. The mathematical...

M. V. Isaev; I. A. Sultanguzin

2010-08-01T23:59:59.000Z

326

Experimental study on the effects of blast-cap configurations and charge patterns on coke descending in CDQ cooling shaft  

SciTech Connect (OSTI)

The coke descending behavior in a CDQ cooling shaft is studied experimentally by means of a tracing method with a digital camera. For three different blast-caps, the law of coke flow is studied under five conditions of coke charge. The experimental results show that, for the sake of the uniformity of the coke burden descending, a blast-cap with elliptical cross-section is a better choice than that with circular cross-section regardless of high or low placement. A coke charge pattern with a flat top burden surface is preferable to that with peak-valley surface, a double-peak superior to a one-peak. Trajectory and average velocity distribution of coke behavior depend weakly on whether the coke is continuously fed or not as the discharging began. The blast-caps have local effects on the descending coke and hardly affect whether the cokes flow smoothly or not in the case of coke burden with enough depth.

Y.H. Feng; X.X. Zhang; M.L. Wu [University of Science & Technology, Beijing (China). School of Mechanical Engineering

2008-08-15T23:59:59.000Z

327

Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process  

DOE Patents [OSTI]

In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

DeGeorge, Charles W. (Chester, NJ)

1981-01-01T23:59:59.000Z

328

Effect of thermal treatment on coke reactivity and catalytic iron mineralogy  

SciTech Connect (OSTI)

Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

2009-07-15T23:59:59.000Z

329

Coke gasification: the influence and behavior of inherent catalytic mineral matter  

SciTech Connect (OSTI)

Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

2009-04-15T23:59:59.000Z

330

PROCESS PARAMETERS AND ENERGY USE OF GAS AND ELECTRIC OVENS IN INDUSTRIAL APPLICATIONS  

E-Print Network [OSTI]

PROCESS PARAMETERS AND ENERGY USE OF GAS AND ELECTRIC OVENS IN INDUSTRIAL APPLICATIONS Dr for Energy Efficiency and Renewable Energy Department of Mechanical and Industrial Engineering University of Massachusetts, Amherst, Massachusetts ABSTRACT The study was conducted to evaluate the energy use of natural gas

Massachusetts at Amherst, University of

331

Review of Beryllium Management Practices at Rocky Flats During Closure Operations  

Broader source: Energy.gov (indexed) [DOE]

DOE-Environmental Management DOE - Complex Wide Review of Beryllium Management Practices at Rocky Flats During Closure Operations Challenge Beryllium (Be) metal is used by DOE in weapons production, as a reactor moderator or reflector, and as a fuel element cladding. Workers who are exposed to high concentrations of beryllium often develop acute beryllium disease caused by the inhalation of beryllium dust or particles which can cause Be sensitivity or chronic Be disease (CBD), a disabling and often fatal lung disease. A review of Rocky Flats Environmental Technology Site (RFETS) Be practices put in place by Kaiser-Hill, the cleanup contractor, was initiated to determine the effectiveness of RFETS beryllium characterization and prevention programs and to determine what, if any, suggestions could be

332

Evaluation of fly ash from co-combustion of coal and petroleum coke for use in concrete  

SciTech Connect (OSTI)

An investigation of fly ash (FA) produced from various blends of coal and petroleum coke (pet coke) fired at Belledune Generating Station, New Brunswick, Canada, was conducted to establish its performance relative to FA derived from coal-only combustion and its compliance with CSA A3000. The FA samples were beneficiated by an electrostatic separation process to produce samples for testing with a range of loss-on-ignition (LOI) values. The results of these studies indicate that the combustion of pet coke results in very little inorganic residue (for example, typically less than 0.5% ash) and the main impact on FA resulting from the co-combustion of coal and up to 25% pet coke is an increase in the unburned carbon content and LOI values. The testing of FA after beneficiation indicates that FA produced from fuels with up to 25% pet coke performs as good as FA produced from the same coal without pet coke.

Scott, A.N.; Thomas, M.D.A.

2007-01-15T23:59:59.000Z

333

Photo-Neutron Thresholds of Beryllium and Deuterium  

Science Journals Connector (OSTI)

The photo-neutron thresholds of beryllium and deuterium have been measured by comparison with the Li7(p,n) threshold. For this purpose an electrostatic generator was used in which an electron beam and a positive ion beam were established simultaneously. Accurate control and measurement of the generator voltage was obtained by using an electrostatic analyzer on the H2+ component of the ion beam. Because the Li7(p,n) threshold lies between the Be9(?,n) and D(?,n) thresholds, errors in extrapolation should be small. The electron beam was accelerated from ground to the accurately known potential of the high voltage electrode where x-rays were produced for the photo-disintegration process. From the photo-neutron thresholds the neutron binding energies of beryllium and deuterium were found to be 1.666±0.002 and 2.226±0.003 Mev, respectively.

R. C. Mobley and R. A. Laubenstein

1950-11-01T23:59:59.000Z

334

Ultrasonic evaluation of beryllium-copper diffusion bonds  

SciTech Connect (OSTI)

A study was performed to compare the effectiveness of several advanced ultrasonic techniques when used to determine the strength of diffusion bonded beryllium-copper, which heretofore have each been applied to only a few material systems. The use of integrated backscatter calculations, frequency domain reflection coefficients, and time-of-flight variance was compared in their ability to characterize the bond strength in a series of beryllium-copper diffusion bond samples having a wide variation in bond quality. Correlation of integrated backscatter calculations and time-of-flight variance with bond strength was good. Some correlation of the slope of the frequency based reflection coefficient was shown for medium and high strength bonds, while its Y-intercept showed moderate correlation for all bond strengths.

Jamieson, E.E.

2000-06-08T23:59:59.000Z

335

Dose Rates from Plutonium Metal and Beryllium Metal in a 9975 Shipping Container  

SciTech Connect (OSTI)

A parametric study was performed of the radiation dose rates that might be produced if plutonium metal and beryllium metal were shipped in the 9975 shipping package. These materials consist of heterogeneous combinations plutonium metal and beryllium. The plutonium metal content varies up to 4.4 kilograms while the beryllium metal varies up to 4 kilograms. This paper presents the results of that study.

Nathan, S.J.

2002-02-04T23:59:59.000Z

336

Impact of HFIR LEU Conversion on Beryllium Reflector Degradation Factors  

SciTech Connect (OSTI)

An assessment of the impact of low enriched uranium (LEU) conversion on the factors that may cause the degradation of the beryllium reflector is performed for the High Flux Isotope Reactor (HFIR). The computational methods, models, and tools, comparisons with previous work, along with the results obtained are documented and discussed in this report. The report documents the results for the gas and neutronic poison production, and the heating in the beryllium reflector for both the highly enriched uranium (HEU) and LEU HFIR configurations, and discusses the impact that the conversion to LEU may have on these quantities. A time-averaging procedure was developed to calculate the isotopic (gas and poisons) production in reflector. The sensitivity of this approach to different approximations is gauged and documented. The results show that the gas is produced in the beryllium reflector at a total rate of 0.304 g/cycle for the HEU configuration; this rate increases by ~12% for the LEU case. The total tritium production rate in reflector is 0.098 g/cycle for the HEU core and approximately 11% higher for the LEU core. A significant increase (up to ~25%) in the neutronic poisons production in the reflector during the operation cycles is observed for the LEU core, compared to the HEU case, for regions close to the core s horizontal midplane. The poisoning level of the reflector may increase by more than two orders of magnitude during long periods of downtime. The heating rate in the reflector is estimated to be approximately 20% lower for the LEU core than for the HEU core. The decrease is due to a significantly lower contribution of the heating produced by the gamma radiation for the LEU core. Both the isotopic (gas and neutronic poisons) production and the heating rates are spatially non-uniform throughout the beryllium reflector volume. The maximum values typically occur in the removable reflector and close to the midplane.

Ilas, Dan [ORNL] ORNL

2013-10-01T23:59:59.000Z

337

E-Print Network 3.0 - arsenic beryllium cadmium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SLAC-I-760-2A08Z-001-R002 HAZARDOUS WASTE DETERMINATION FORM Summary: : PCB Content: Metal Content: Antimony* Arsenic Barium Beryllium* Cadmium Source:...

338

Progress on a Cavity with Beryllium Walls for Muon Ionization Cooling Channel R&D.  

E-Print Network [OSTI]

WITH BERYLLIUM WALLS FOR MUON IONIZATION COOLING CHANNELNY 11973, USA Abstract The Muon Accelerator Program (MAP)an ionization cooling channel for muon beams. An ionization

Bowring, D.L.

2014-01-01T23:59:59.000Z

339

Characterization of tuyere-level core-drill coke samples from blast furnace operation  

SciTech Connect (OSTI)

A suite of tuyere-level coke samples have been withdrawn from a working blast furnace during coal injection, using the core-drilling technique. The samples have been characterized by size exclusion chromatography (SEC), Fourier transform Raman spectroscopy (FT-RS), and X-ray powder diffraction (XRD) spectroscopy. The 1-methyl-2-pyrrolidinone (NMP) extracts of the cokes sampled from the 'bosh', the rear of the 'bird's nest', and the 'dead man' zones were found by SEC to contain heavy soot-like materials (ca. 10{sup 7}-10{sup 8} apparent mass units). In contrast, NMP extracts of cokes taken from the raceway and the front of the 'bird's nest' only contained a small amount of material of relatively lower apparent molecular mass (up to ca. 10{sup 5} u). Since the feed coke contained no materials extractable by the present method, the soot-like materials are thought to have formed during the reactions of volatile matter released from the injectant coal, probably via dehydrogenation and repolymerization of the tars. The Raman spectra of the NMP-extracted core-drilled coke samples showed variations reflecting their temperature histories. Area ratios of D-band to G-band decreased as the exposure temperature increased, while intensity ratios of D to G band and those of 2D to G bands increased with temperature. The graphitic (G), defect (D), and random (R) fractions of the carbon structure of the cokes were also derived from the Raman spectra. The R fractions decreased with increasing temperature, whereas G fractions increased, while the D fractions showed a more complex variation with temperature. These data appear to give clues regarding the graphitization mechanism of tuyere-level cokes in the blast furnace. 41 refs., 9 figs., 6 tabs.

S. Dong; N. Paterson; S.G. Kazarian; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

2007-12-15T23:59:59.000Z

340

Predicting the yield of coking byproducts on the basis of elementary and petrographic analysis of the coal batch  

Science Journals Connector (OSTI)

Mathematical models are developed for predicting the yield of coking byproducts on the basis of elementary and petrographic analysis of the coal batch.

M. B. Golovko; I. D. Drozdnik; D. V. Miroshnichenko; Yu. S. Kaftan

2012-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Study of the sulphur in coal and its distribution between the gases and the residue in coking.  

E-Print Network [OSTI]

??Sulphur exists in metallurgical coke as a source of annoyance and difficulties in the economic progress of the metal industries. It ie present in coal… (more)

Wenger, Arthur W.

1923-01-01T23:59:59.000Z

342

Strategies for Low Carbon Growth In India: Industry and Non Residential Sectors  

E-Print Network [OSTI]

in the India Iron and Steel ISF Coke- Making a. b. c. d.and Stamp Charging). Maximum Recovery of Coke OvenGas Using Coke Oven Gas for achieving higher blast

Sathaye, Jayant

2011-01-01T23:59:59.000Z

343

Australia–Japan coking coal trade: A hedonic analysis under benchmark and fair treatment pricing  

Science Journals Connector (OSTI)

Given Japan's dominant position in the Asia–Pacific regional coal market and the continuing relatively low profitability of Australia's coal industry, the influence of the Japanese steel mills on coal pricing arrangements between Australia and Japan remains an issue in Australia. In Japanese fiscal year (JFY) 1996, the Japanese steel mills replaced benchmark pricing with the “fair treatment” pricing system whereby coal contract information is kept confidential. In this paper, Quandt's switching regime model is used to test for structural change in hedonic pricing relationships in the important Australia–Japan coking coal trade between JFY 1992 and 1997. There is statistical evidence of significant structural change in JFY 1996 for hard coking coal and in JFY 1995 for semisoft coking coal (when soft coking coal was merged with the semisoft category). The goodness of fit of the regressions is lower in each recent period. It is concluded that price discovery in the annual coal negotiations, particularly for hard coking coal, is relatively more difficult under fair treatment pricing.

Anthony Swan; Sally Thorpe; Lindsay Hogan

1999-01-01T23:59:59.000Z

344

Relationship between coking coal quality and its micro-Raman spectral characteristics  

Science Journals Connector (OSTI)

Abstract Micro-Raman spectroscopy examination of 20 samples of coking coals (Rr = 0.84–1.43%) was performed. Spectral parameters were correlated with the basic rank and technological properties of coals. The G band FWHM and the AG/AALL ratio decrease with the volatile matter content (Vdaf) decrease and the all maceral reflectance scan (Rscan) value increase. The correlations between these parameters are stronger than those, between the G band FWHM and the AG/AALL ratio, and the mean random vitrinite reflectance (Rr). Coking properties are weakly related to the Raman spectral characteristics of coal. Based on the Raman parameters G band FWHM and the AG/AALL ratio, it may be possible to evaluate the volatile matter content (Vdaf) and the all maceral reflectance scan (Rscan) value for coking coals.

Rafa? Morga; Iwona Jelonek; Krystyna Kruszewska

2014-01-01T23:59:59.000Z

345

Coking phenomena in the pyrolysis of ethylene dichloride into vinyl chloride  

SciTech Connect (OSTI)

Pyrolysis of ethylene dichloride (EDC) into vinyl chloride (VCM) which is the monomer for polyvinyl chloride, one of the most popular polymers, has been established commercially for quite a time. The process around 500{degrees}C has been proved to give VCM of high purity at very high selectivity about 99% and a reasonable conversion about 50%. However, the coking is a major problem in the long run, requiring decoking treatment every two months. The present paper describes features of carbons produced in the pyrolysis process. Coke of respective features was found in the reactor, the transfer line, the heat exchanger and the rapid quencher. Typical pyrolytic carbon, anisotropic coke produced in the liquid phase, isotropic carbon was produced on the reactor wall as low as 500{degrees}C. The mechanisms for their formation are discussed.

Sotowa, Chiaki; Korai, Yozo; Mochida, Isao [Kyushu Univ., Kasuga, Fukuoka (Japan)] [and others

1995-12-31T23:59:59.000Z

346

Catalyst deactivation by coking in the MTG process in fixed and fluidized bed reactors  

Science Journals Connector (OSTI)

The validity of a kinetic model for describing the deactivation of a catalyst based on a HZSM5 zeolite has been studied by carrying out reaction in fixed and fluidized bed reactors. The kinetic model takes into account that activity is dependent on the concentration of the lumps of oxygenates, of light olefins and of the remaining products and shows that coke formation capability follows this order. The difference between the deactivation kinetic constants calculated for the fixed and fluidized bed reactors is explained by the effect of the steam produced in the reaction, where coke stripping attenuates deactivation. Future improvements in the deactivation kinetic model must take into account coke stripping by the steam produced in the reaction.

Andrés T. Aguayo; Ana G. Gayubo; JoséM. Ortega; Martin Olazar; Javier Bilbao

1997-01-01T23:59:59.000Z

347

Study on the Respirable Particulate Matter Generated from the Petroleum Coke and Coal Mixed-Fired CFB Boiler  

Science Journals Connector (OSTI)

The dust generated from the fuel combustion is one of the important sources for air pollution. This paper has made a comprehensive research on the particulate matter generated from the petroleum coke and coal mixed-fired circulating fluidized bed (CFB) ... Keywords: petroleum coke, respirable particulate matter, air pollution, circulating fluidized bed boiler

Yan Ma; Hao Bai; Lihua Zhao; Yang Ma; Daqiang Cang

2010-12-01T23:59:59.000Z

348

DOE - Office of Legacy Management -- Brush Beryllium Co - Lorain - OH 47  

Office of Legacy Management (LM)

Brush Beryllium Co - Lorain - OH 47 Brush Beryllium Co - Lorain - OH 47 FUSRAP Considered Sites Site: Brush Beryllium Co. - Lorain (OH.47 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 1st Street and Hamilton Avenue , Lorain , Ohio OH.47-1 Evaluation Year: 1987 OH.47-1 Site Operations: Production of beryllium metal and compounds, such as beryllium fluoride; used isotopes in the separation of zirconium and hafnium. OH.47-1 OH.47-2 OH.47-3 Site Disposition: Eliminated - Potential for contamination considered remote based on limited operations and quantities of material handled OH.47-1 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Zirconium OH.47-1 Radiological Survey(s): No Site Status: Eliminated from consideration under FUSRAP

349

DOE - Office of Legacy Management -- Brush Beryllium Co - Elmore - OH 09  

Office of Legacy Management (LM)

Elmore - OH 09 Elmore - OH 09 FUSRAP Considered Sites Site: Brush Beryllium Co - Elmore (OH.09 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Elmore , Ohio OH.09-1 Evaluation Year: 1987 OH.09-1 Site Operations: Beryllium Research, Development and Fabrication. OH.09-1 Site Disposition: Eliminated - Operations were moved to the Luckey Plant - Beryllium work only OH.09-1 Radioactive Materials Handled: No OH.09-1 Primary Radioactive Materials Handled: None Radiological Survey(s): None Indicated Site Status: Eliminated from further consideration under FUSRAP Also see Documents Related to Brush Beryllium Co - Elmore OH.09-1 - Memorandum/Checklist; S. Jones to the File; Subject: Elimination Recommendation of Brush Beryllium; April 30, 1987

350

Preparation and evaluation of hydrotreating catalysts based on activated carbon derived from oil sand petroleum coke  

Science Journals Connector (OSTI)

Novel Ni–Mo/activated carbon (AC) hydrotreating catalysts were prepared and evaluated for upgrading heavy vacuum gas oil (HVGO). The AC supports were derived from Alberta oil sand petroleum coke, i.e. fluid coke and/or delayed coke, hereafter referred to as OSP coke, through a chemical process. The BET surface area was as high as 2194 m2/g for the fluid coke derived AC and 2357 m2/g for the delayed coke derived AC. Both \\{ACs\\} contained a large number of micropores with pore volume as high as 1.2 cm3/g. Ni and Mo based active component precursors could be easily loaded on the activated carbon supports by chemical impregnation of nickel nitrate and ammonium molybdate followed by calcination in nitrogen at 773 K without further modification or oxidation treatment to the activated carbons. Scanning electron microscopy (SEM) observation showed highly porous surface structure of the bare activated carbon supports and well dispersed metal (oxide) precursor nanoparticles of 30–50 nm loaded on the AC supports. For comparison, two reference catalysts were also prepared by the same procedure but using commercial activated carbon and porous alumina as supports. After catalyst activation by sulfiding, the hydrotreating performance of the prepared catalysts was evaluated in a magnetically stirred autoclave with a HVGO feedstock to examine their hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) activities. Two commercial hydrotreating catalysts were also tested and compared under similar conditions with the same feed. The results showed that the catalysts based on the activated carbon supports prepared from OSP coke had better hydrotreating performance than the other catalysts. Scanning transmission electron microscopy (STEM) characterization of the catalysts after activation showed that small particles of nanostructure (2–5 nm in size) were evenly embedded in the carbon matrix except for some bigger particles that were located on the catalyst surface. Energy dispersive X-ray (EDX) spectroscopy revealed that these particles were composed of Ni, Mo and S elements. The dispersed nanoparticles formed the active sites and were responsible for the observed high HDS and HDN activity. Elemental analysis and surface characterization of the spent catalysts showed that the formation of coke precursors was favored on the alumina supported catalyst, which resulted in catalyst deactivation.

Yu Shi; Jinwen Chen; Jian Chen; Robb A. Macleod; Marek Malac

2012-01-01T23:59:59.000Z

351

An active carbon catalyst prevents coke formation from asphaltenes during the hydrocracking of vacuum residue  

SciTech Connect (OSTI)

Active carbons were prepared by the steam activation of a brown coal char. The active carbon with mesopores showed greater adsorption selectivity for asphaltenes. The active carbon was effective at suppressing coke formation, even with the high hydrocracking conversion of vacuum residue. The analysis of the change in the composition of saturates, aromatics, resins, and asphaltenes in the cracked residue with conversion demonstrated the ability of active carbon to restrict the transformation of asphaltenes to coke. The active carbon that was richer in mesopores was presumably more effective at providing adsorption sites for the hydrocarbon free-radicals generated initially during thermal cracking to prevent them from coupling and polycondensing.

Fukuyama, H.; Terai, S. [Toyo Engineering Corp., Chiba (Japan). Technological Research Center

2007-07-01T23:59:59.000Z

352

Contribution to kinetic modeling of catalyst deactivation by coke in the MTG process  

SciTech Connect (OSTI)

The adequacy of a kinetic model for deactivation of a catalyst based on a H-ZSM5 used in the transformation of methanol into hydrocarbons has been proven. The model takes into account the pronounced effect on coke deposition of the concentration of reaction lumps and coke preferable deposition at the reactor inlet by degradation of oxygenates (methanol and dimethylether) on the catalyst acid sites. The kinetic model is in agreement with the experimental results of fixed and fluidized bed reactors within the 300-400 {degrees}C range. The deactivation is slightly smaller in fluidized bed but contribution of catalyst attrition to deactivation must be considered. 14 refs., 3 figs.

Gayubo, A.G.; Ortega, J.M.; Benito, P.L.; Aguayo, A.T.; Bilbao, J. [Universidad del Pais Vasco, Bilbao (Spain)

1996-12-31T23:59:59.000Z

353

Mechanism of physical transformations of mineral matter in the blast furnace coke with reference to its reactivity and strength  

SciTech Connect (OSTI)

Examinations of polished and dry cut sections of feed and tuyere coke revealed some possible mechanisms for the physical influence of mineral compounds on the reactivity and strength of coke. It was observed that rounded particles of mineral phases that are exposed to the pore walls and surface of coke at high temperature create an inorganic cover, thus reducing the surface available for gas-solid reactions. The particles of mineral matter that have a low melting point and viscosity can affect the coke at earlier stages in the blast furnace process, acting in the upper parts of the blast furnace (BF). The temperature-driven redistribution of mineral phases within the coke matrix probably leads to the creation of weak spots and in general to anisotropy in its properties, thus reducing its strength. 9 refs., 2 figs., 1 tab.

Stanislav S. Gornostayev; Jouko J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

2006-12-15T23:59:59.000Z

354

Rates of Microbial Transformation of Polycyclic Aromatic Hydrocarbons in Water and Sediments in the Vicinity of a Coal-Coking Wastewater Discharge  

Science Journals Connector (OSTI)

...Sediments in the Vicinity of a Coal-Coking Wastewater Discharge Stephen E...collected in the vicinity of a coal-coking treated wastewater discharge from...sediments in the vicinity of a coal-coking wastewater discharge. | To facilitate...

Stephen E. Herbes

1981-01-01T23:59:59.000Z

355

SOURCE AND PATHWAY DETERMINATION FOR BERYLLIUM FOUND IN BECHTEL NEVADA NORTH LAS VEGAS FACILITIES  

SciTech Connect (OSTI)

In response to the report ''Investigation of Beryllium Exposure Cases Discovered at the North Las Vegas Facility of the National Nuclear Security Administration'', published by the U.S. Department of Energy (DOE), National Nuclear Security Administration (NNSA) in August 2003, Bechtel Nevada (BN) President and General Manager Dr. F. A. Tarantino appointed the Beryllium Investigation & Assessment Team (BIAT) to identify both the source and pathway for the beryllium found in the North Las Vegas (NLV) B-Complex. From September 8 to December 18, 2003, the BIAT investigated the pathway for beryllium and determined that a number of locations existed at the Nevada Test Site (NTS) which could have contained sufficient quantities of beryllium to result in contamination if transported. Operations performed in the B-1 Building as a result of characterization activities at the Engine Maintenance, Assembly, and Disassembly (EMAD); Reactor Maintenance, Assembly, and Disassembly (RMAD); Test Cells A and C; and the Central Support Facility in Area 25 had the greatest opportunity for transport of beryllium. Investigative monitoring and sampling was performed at these sites with subsequent transport of sample materials, equipment, and personnel from the NTS to the B-1 Building. The timeline established by the BIAT for potential transport of the beryllium contamination into the B-1 Building was from September 1997 through November 2002. Based on results of recently completed swipe sampling, no evidence of transport of beryllium from test areas has been confirmed. Results less than the DOE beryllium action level of 0.2 ???g/100 cm2 were noted for work support facilities located in Area 25. All of the identified sites in Area 25 worked within the B-1 tenant's residency timeline have been remediated. Legacy contaminants have either been disposed of or capped with clean borrow material. As such, no current opportunity exists for release or spread of beryllium contamination. Historical records indicate that there are locations at the NTS which contain hazardous quantities of beryllium; however, because beryllium was not always considered a contaminant of concern, complete characterization was not performed prior to remediation efforts. Today, it is not practical to characterize Area 25 for beryllium due to the successful remediation. Analysis of sample data collected in B-1 for the BIAT was performed for the purpose of confirming past results and identifying a source of beryllium through the use of markers. The results confirmed the presence of man-made beryllium contamination in the B-1 High Bay at levels consistent with the NNSA Report. No source markers were found that would be associated with NTS historical nuclear rocket or weapons-related operations. Beryllium contamination was identified in the southwest area of the B-1 High Bay in characteristic association with materials handled during historic metal-working operations. Use of source marker analysis suggests a contributor of beryllium found in carpeted areas of the B-Complex may be naturally occurring. Naturally occurring beryllium is not regulated by Title 10 Code of Federal Regulations Part 850 (10 CFR 850) (see Appendix A). No current uncontrolled beryllium source or transport pathways have been identified as available for spread of contamination to uncontrolled areas from the NTS.

BECHTEL NEVADA

2004-07-01T23:59:59.000Z

356

Dissolution of refractories for gasification process of petroleum coke for the steel industry  

Science Journals Connector (OSTI)

The production of energizing gases such as H2 and CO by gasification process of solid fuels is a technology that has increased in recent years since it is an efficient and clean process. To enable the production of gases, it is necessary to use refractory materials capable of withstanding high temperatures, thermal shock and contact with aggressive media. Nowadays, there is not published literature on refractory materials used for furnaces lining for petroleum coke gasification at high temperatures (?1900 °C). Therefore, this paper deals with the study of alumina and magnesium aluminate/alumina-based refractories as candidates for the furnace lining used in the petroleum coke gasification for steel production. Refractory samples were made with some designed formulations which were subjected to chemical interactions with pellets made of petroleum coke and petroleum coke ash at 1650 °C for 4 h. After completing the tests, the formulations were cut transversely and were characterized by SEM-EDS and XRD to evaluate the resistance to slag penetration and formation of low melting point phases. The results show that slag penetration and corrosion in the refractory formulations occur due to the formation of hibonite, spinels (Ni2+, Fe2+, Mg2+)(Al, Fe)2O4 and gehlenite phases. However, these phases together stop the molten slag penetration.

R. Puente-Ornelas; C.J. Lizcano-Zulaica; A.M. Guzmán; P.C. Zambrano; T.K. Das-Roy

2012-01-01T23:59:59.000Z

357

Effect of Iron Species and Calcium Hydroxide on High-Sulfur Petroleum Coke CO2 Gasification  

Science Journals Connector (OSTI)

The effect of iron species on petroleum coke CO2 gasification was studied in the present work. The effects of the temperature (1173–1673 K), the catalyst types, catalyst loading (ranging from 0 to 5 wt %), and composition during the gasification of ...

Zhi-jie Zhou; Qi-jing Hu; Xin Liu; Guang-suo Yu; Fu-chen Wang

2012-01-24T23:59:59.000Z

358

The behaviors and fate of polycyclic aromatic hydrocarbons (PAHs) in a coking wastewater treatment plant  

Science Journals Connector (OSTI)

The occurrence, behaviors and fate of 18 \\{PAHs\\} were investigated in a coking wastewater treatment plant in Songshan coking plant, located in Shaoguan, Guangdong Province of China. It was found that the target compounds occurred widely in raw coking wastewater, treated effluent, sludge and gas samples. In raw coking wastewater, high molecular weight (MW) \\{PAHs\\} were the dominant compounds, while 3–6 ring \\{PAHs\\} predominated in the final effluent. The dominant compounds in gas samples were phenathrene, fluoranthene and pyrene, while they were fluoranthene, pyrene, chrysene and benzo[k]fluoranthene for sludge. The process achieved over 97% removal for all the PAHs, 47–92% of eliminations of these target compounds in liquid phase were achieved in biological stage. Different behaviors of \\{PAHs\\} were observed in the primary tank, anaerobic tank, aerobic tank, hydrolytic tank and coagulation tank units, while heavier and lower ones were mainly removed in anaerobic tank and aerobic tanks, respectively. Regarding the fate of PAHs, calculated fractions of mass losses for low MW \\{PAHs\\} due to transformation and adsorption to sludge accounted for 15–50% and 24–49%, respectively, while the rest was less than 1%. For high MW PAHs, the mass losses were mainly due to adsorption to sludge and separation with tar (contributing 56–76% and 22–39%, respectively), and the removal through transformation was less.

Wanhui Zhang; Chaohai Wei; Xinsheng Chai; Jingying He; Ying Cai; Man Ren; Bo Yan; Pingan Peng; Jiamo Fu

2012-01-01T23:59:59.000Z

359

Coke deposits formation and products selectivities for the MTG process in a fluidized bed reactor  

Science Journals Connector (OSTI)

Experiments were carried out in a demonstrative scale fluidized bed reactor for methanol conversion to gasoline (MTG). We investigated the kinetics of the coke deposits formation and their influence on the products selectivities. New reaction indexes were advanced for on line monitoring of the catalyst activity.

Grigore Pop; Gavril Musca; Eleonora Chirila; Rodica Boeru; Gheorghe Niculae; Natalia Natu; Gheorghe Ignatescu; Sorin Straja

1989-01-01T23:59:59.000Z

360

Investigation of Vanadium Compounds in Ashes from a CFBC Firing 100 Petroleum Coke  

Science Journals Connector (OSTI)

Investigation of Vanadium Compounds in Ashes from a CFBC Firing 100 Petroleum Coke ... The ash pits have since gone through an extensive remedial process. ... The other metals investigated (i.e., Fe, Cu, Zn, and Pb) also were present predominantly as sulfates. ...

L. Jia; E. J. Anthony; J. P. Charland

2002-02-27T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Coal flow aids reduce coke plant operating costs and improve production rates  

SciTech Connect (OSTI)

Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

2005-06-01T23:59:59.000Z

362

Optimization of experimental conditions for recovery of coking coal fines by oil agglomeration technique  

Science Journals Connector (OSTI)

The significance of coking coal in the metallurgical sector as well as the meager coking coal reserves across the globe increase the necessity to recover coking coal fines from the fine coking coal slurries generated from coal preparation and utilization activities. Oil agglomeration studies were carried out by varying the experimental conditions for maximum recovery of coking coal fines i.e., yield of the agglomerates. The various operational parameters studied were oil dosage, agitation speed, agglomeration time and pulp density. By using Taguchi experimental design, oil dosage (20%), agitation speed (1100 rpm), agglomeration time (3 min) and pulp density (4.5%) were identified as the optimized conditions. A confirmation experiment has also been carried out at the optimized conditions. The percentage contribution of each parameter on agglomerate yield was analyzed by adopting analysis of variance (ANOVA) statistical method as well as multiple linear regression analysis. The order of influence of the parameters on the agglomerate yield is of the following order: pulp density > oil dosage > agitation speed > agglomeration time. A mathematical model was developed to fit the set of experimental conditions with the yield obtained at each test run and also at the optimized conditions. The experimentally obtained yield was compared with the predicted yield of the model and the results indicate a maximum error of 5% between the two. A maximum yield of 90.42% predicted at the optimized conditions appeared to be in close agreement with the experimental yield thus indicating the accuracy of the model in predicting the results.

G.H.V.C. Chary; M.G. Dastidar

2010-01-01T23:59:59.000Z

363

China Energy Databook -- User Guide and Documentation, Version 7.0  

E-Print Network [OSTI]

Mining Accidents Table 2B.6. Coke Production, 1949-20062B.7. Coking Coal Used in Coke Production, 1980-2006 TableConversion (Mtce) Table 4A.19.1. Coke Oven Gas End Use and

Fridley, Ed., David

2008-01-01T23:59:59.000Z

364

China Energy Primer  

E-Print Network [OSTI]

37 Figure 2-8 Coke Production (1980-2006) 99 Figure 3-28 Coke Oven Gas End-use and Inputs35 Table 2-17 Coking Coal Used in Coke Production (1980-

Ni, Chun Chun

2010-01-01T23:59:59.000Z

365

Productivity benefits of industrial energy efficiency measures  

E-Print Network [OSTI]

the blast furnace means less coke is needed, so maintenancecontrol Foamy slag practices Coke making Oxy-fuel burners/Variable speed drive on coke oven gas compressors Coke dry

Worrell, Ernst

2011-01-01T23:59:59.000Z

366

Independent Oversight Inspection of the Hanford Site Chronic Beryllium Disease Prevention Program  

Broader source: Energy.gov (indexed) [DOE]

the the Hanford Site Chronic Beryllium Disease Prevention Program June 2010 Office of Independent Oversight Office of Health, Safety and Security Office of Health, Safety and Security HSS x Hanford Site Chronic Beryllium Disease Prevention Program | i Abbreviations iii Executive Summary v 1 Introduction 1 2 Management and Oversight 3 3 Findings Requiring Corrective Action 14 4 Conclusions and Cross-Cutting Opportunities for Improvement 17 Appendix A - Supplemental Information 23 Appendix B - Background Information 26 Appendix C - AdvanceMed Hanford Beryllium Medical Support Program 32 Appendix D - CH2M-Hill Plateau Remediation Company 48 Appendix E - Mission Support Alliance 57 Appendix F - Washington Closure Hanford 71

367

Beryllium-Associated Worker Registry Data Collection and Management Guidance  

Broader source: Energy.gov (indexed) [DOE]

7 7 June 2007 DOE TECHNICAL STANDARD Beryllium-Associated Worker Registry Data Collection and Management Guidance U.S. Department of Energy AREA SAFT Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited NOT MEASUREMENT SENSITIVE DOE-STD-1187-2007 ii Available on the Department of Energy Technical Standards Program Web site at http://www.hss.energy.gov/NuclearSafety/techstds/ DOE-STD-1187-2007 iii FOREWORD 1. This standard provides acceptable methods for compliance with the requirements of paragraph 10 CFR 850.39 "Recordkeeping and Use of Information." Use of this standard is not mandatory. Users should review the document and determine if it meets their purpose. 2. Comments (recommendations, additions, and deletions) that may be of use in

368

Quantum Modeling of Hydrogen Retention in Beryllium Bulk and Vacancies  

Science Journals Connector (OSTI)

In the nuclear fusion domain, bubble formation is well-known for tungsten,(2) but the question of bubble formation is still open in the specific case of beryllium. ... Tritium is the fuel needed for energy production using nuclear fusion: In a tokamak fusion reactor,(5) the deuterium (D)?T plasma is magnetically confined in order to reach a temperature and density high enough to induce the thermonuclear fusion of the two nuclei, producing a large quantity of energy at very high temperatures. ... Although the inner wall of the International Thermonuclear Experimental Reactor (ITER) will be isolated from the hot plasma by confinement in magnetic fields, the wall will still be subjected to damaging atom and ion fluxes originating from the boundary plasma. ...

A. Allouche; M. Oberkofler; M. Reinelt; Ch. Linsmeier

2010-02-09T23:59:59.000Z

369

Demonstration of a fuel-saving system for paint-curing ovens  

SciTech Connect (OSTI)

Two curing ovens at Roll Coater, Inc. (the Greenfield, Indiana plant) were retrofitted to save fuel and cost. Included in the fuel conserving retrofit was the design, fabrication, and installation of an afterburner for each of the two ovens, piping their combustion products to each of two commonly housed waste heat boilers before discharge from those units to the atmosphere at about 450 F. Depending on the product being run and the coating applied, natural gas requirements have been reduced by 45 to 65% with operation of the zone incinerators only and by as much as 65 to 85% including the effects of both the zone incineration and heat recovery by means of the afterburners and waste heat boilers. A demonstration program on conversion work at the No. 3 line at Greenfield and results are described in Section 2. Section 3 describes the retrofit design and the system construction. System performance (tests and measurements, qualitative performance, maintenance factors, and economic performance) is described in Section 4. Conclusions and recommendations are summarized.

Jensen, W P [comp.

1980-12-01T23:59:59.000Z

370

Potential of a beryllium x-ray lens  

SciTech Connect (OSTI)

The use of refractive lenses for focusing x-ray beams has been the subject of publications since the early 1980s. Detailed calculations have been made for different shapes for the refractive lens: cylindrical, spherical, parabolic, and for a Fresnel-type refractive lens. The main drawback to the use of a single refractive lens to focus x-rays is that the index of refraction (n = 1 {minus} {delta}) is very close to 1, which results in a lens with a very long focal length. Recently Snigerov and others have suggested and experimentally demonstrated, using cylindrical-shaped lenses, that this problem of long focal lengths can be overcome by using many lenses in series. Each lens refracts the photon through a small angle, but the sum of these sequential changes in direction can be moderately larger. This increase in effective refraction angle reduces the focal length of the lens to a few meters or less and makes the multi-element lens a much more useful instrument for focusing x-rays. This paper, annualizes the expected performance of a lens consisting of a series of aligned hollow spheres in a beryllium substrate. The use of hollow spheres rather than hollow cylinders produces focusing of the x rays into a small focal spot in contrast to the single-directional focusing of the hollow cylinders, which produces a line focus. Two multi-element lenses have been constructed: one with 20 1-mm-diameter hollow spheres in an aluminum substrate, and one with 50 hollow spheres, 1 mm in diameter, in a beryllium substrate. Some construction details and calculations of the expected performance, are given for these two multi-element lenses.

Smither, R.K.; Khounsary, A.M.; Xu, S. [Argonne National Lab., IL (United States). Advanced Photon Source

1997-09-01T23:59:59.000Z

371

Retrospective beryllium exposure assessment at the Rocky Flats Environmental Technology site  

SciTech Connect (OSTI)

Since the 1960`s, beryllium machining was performed to make nuclear weapon components at the Department of Energy (DOE) Rocky Flats Plant. Beryllium exposure was assessed via fixed airhead (FAH) sampling in which the filter cassette was affixed to the machine, generally within a few feet of the worker`s breathing zone. Approximately 500,000 FAH samples were collected for beryllium over three decades. From 1984 to 1987, personal breathing zone (PBZ) samples were also collected as part of the evaluation of a new high velocity/low volume local exhaust ventilation (HV/LV LEV) system. The purpose of this study was to determine how the two types of sampling data could be used for an exposure assessment in the beryllium shop.

Barnard, A.E.; Torma-Krajewski, J. [Department of Energy, Rocky Flats Field Office, Golden, CO (United States); Viet, S.M. [M.H. Chew & Associates, Inc., Golden, CO (United States)

1997-05-01T23:59:59.000Z

372

Plasma-Sprayed Beryllium on Macro-Roughened Substrates for Fusion Reactor High Heat Flux Applications  

Science Journals Connector (OSTI)

The development of beryllium first wall (FW) plasma facing components for future magnetic confinement fusion experiments, such as the International Thermonuclear Experimental Reactor (ITER), is a topic of great.....

Kendall J. Hollis; Brian D. Bartram; Manfred Roedig…

2007-03-01T23:59:59.000Z

373

Failure prediction of cross-rolled beryllium sheets subjected to transverse point loads  

E-Print Network [OSTI]

(1968), but nonlinear materials and large deflections are not taken into account. 1. 2. 5 Existing Policy at Johnson Space Center For a cross-rolled beryllium structure to be certified as a payload on the space shuttle, the following requirements... (1968), but nonlinear materials and large deflections are not taken into account. 1. 2. 5 Existing Policy at Johnson Space Center For a cross-rolled beryllium structure to be certified as a payload on the space shuttle, the following requirements...

Mascorro, Edward

2012-06-07T23:59:59.000Z

374

Spectroscopic studies on the formation of coke on individual Fluid Catalytic Cracking particles: the effect of poisoning metal compounds.  

E-Print Network [OSTI]

??The formation of coke on individual Fluid Catalytic Cracking (FCC) catalyst particles was studied using UV/Vis microspectroscopy and confocal fluorescence microscopy, with n-hexane cracking as… (more)

Goetze, J.G.

2013-01-01T23:59:59.000Z

375

Influence of the batch's coke-ore ratio and distribution on the porosity of the melting zone  

SciTech Connect (OSTI)

The variation in gas permeability in the melting zone is considered as a function of the height and configuration of the coke packing and the ore component of the batch.

V.P. Tarasov; L.V. Bykov; P.V. Tarasov [Priazovsk State Technical University, Mariupol (Ukraine)

2008-09-15T23:59:59.000Z

376

Deposition and characteristics of coke over a H-ZSM5 zeolite-based catalyst in the MTG process  

SciTech Connect (OSTI)

The influence of reaction conditions in the transformation of methanol into gasoline (temperature, time on stream, and contact time) on the deposition and nature of coke (composition, H/C ratio) and on its location in the porous structure of a H-ZSM5 zeolite-based catalyst has been studied in an isothermal fixed-bed integral reactor. The distribution of the coke within the porous structure of the catalyst is similar to that proposed for other reactions on H-ZSM5 zeolites, and the highly hydrogenated character of coke and its instability is noteworthy. Coke deposition has been related to catalyst acidic site deterioration and to a kinetic model for catalyst deactivation in an integral reactor.

Benito, P.L.; Gayubo, A.G.; Aguayo, A.T.; Olazar, M.; Bilbao, J. [Univ. del Pais Vasco, Bilbao (Spain). Dept. de Ingenieria Quimica] [Univ. del Pais Vasco, Bilbao (Spain). Dept. de Ingenieria Quimica

1996-11-01T23:59:59.000Z

377

Reducing the sulfur content of coke by increasing the content of thermally conditioned g coal in the batch  

Science Journals Connector (OSTI)

In periods of economic growth, Ukrainian coke plants face a shortage of Zh and K coal, because of the high demand. In periods of economic stagnation, conversely, there is an excess of Zh coal, on account of the d...

E. I. Malyi

2014-05-01T23:59:59.000Z

378

3D Computational Fluid Dynamics Simulation of Natural Coke Steam Gasification in General and Improved Fluidized Beds  

Science Journals Connector (OSTI)

The thermal characteristics of natural coke steam gasification in a fluidized bed were three-dimensionally (3D) simulated based on the computational fluid dynamics (CFD) method using Fluent code. ... However, this technology seems difficult to carry out due to its abradability, hard ignition, hot burst, and so on. ... In short, all the results in this work have a significance to provide the theoretical basis for the design, operational optimization, and scale-up of the natural coke steam gasification process. ...

Ya-li Tang; Dai-jun Liu; Yu-hong Liu; Qian Luo

2010-09-30T23:59:59.000Z

379

Linings with optimum heat-emission surfaces for cars receiving and transporting incandescent coke  

SciTech Connect (OSTI)

The least reliable components of the cars which receive and transport incandescent coke are the lining plates. This applies to both the quenching cars used for wet quenching and the hot-coke cars used in the dry cooling process. Technical advances have been described whereby the life of car linings is prolonged by increasing heat emission from the lining plate surfaces. As the heat emission level is enhanced the mean plate temperature is lowered and the lining life thereby prolonged; moreover, the between-servicings period is prolonged. This involves providing fins on the non-working (outer) plate surfaces. The problem of optimizing the size and shape of the fins with reference to heat emission remains unsolved: the requirement is maximum heat emission from plates of a given weight, or conversely minimum plate weight for a given heat emission level. 6 refs., 3 figs.

Kotlyar, B.D.; Pleshkov, P.I.; Gadyatskii, V.G. [and others

1992-12-31T23:59:59.000Z

380

Unsteady-state kinetic simulation of naphtha reforming and coke combustion processes in the fixed and moving catalyst beds  

Science Journals Connector (OSTI)

Abstract The work is dedicated to the construction of kinetics models for the naphtha reforming process and the adjacent process of catalyst regeneration by coke combustion. The proposed kinetic model for the reforming process is based on the use of common rate equations for the groups of similar reactions with account of difference in reaction rates for individual homologs within these groups by simple correlations with thermodynamic properties (first of all – with the values of Gibbs free energy) of individual reactions and by other simplification methods. Such approach gives the way to construct the kinetics models optimal from the point of view of compromise between accuracy and simplicity. The proposed naphtha reforming model is characterized with the high level of kinetic scheme detailization (62 individual and group reactants and 146 individual reactions), at the same it is rather simple and provides the accurate description of the experimental data using only 22 kinetic parameters. This model is thermodynamically consistent and provides accurate description of experimental data in a wide range of process parameters. Account of catalyst deactivation by coke deposition in the model gives the way to simulate transient reforming process performance both in fixed and moving catalyst beds. Kinetics of coke combustion for catalysts with moderate coke content (up to 3% mass) may described by simple kinetic equation with apparent reaction rate orders closed to unit for relative coke content and to 1/2 for oxygen. Demonstration simulations of naphtha reforming and coke combustion processes are presented.

Andrey N. Zagoruiko; Alexander S. Belyi; Mikhail D. Smolikov; Alexander S. Noskov

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Operating temperature effects on nozzle coking in a cottonseed oil fueled diesel engine  

E-Print Network [OSTI]

OPERATING TEMPERATURE EFFECTS ON NOZZLE COKING IN A COTTONSEED OIL FUELED DIESEL ENGINE A Thesis CHARLES MICHAEL YARBROUGH Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree cf... MASTER OF SCIENCE December 1984 Major Subject: Agricultural Engineering OPERATING TEMPERATURE EFFECTS ON NOZZLE CORING IN A COTTONSEED OIL FUELED DIESEL ENGINE A Thesis by CHARLES MICHAEL YARBROUGH Approved as to style and content by: ayne A. Le...

Yarbrough, Charles Michael

2012-06-07T23:59:59.000Z

382

Profitability analysis of non-coking coal preparation for power plants in India  

SciTech Connect (OSTI)

Currently coal-based power plants produce about 70% of the total electricity generated in India, where non-coking (steam) coals are utilized mostly without any preparation. A massive capacity addition of at least 140,000 MWe is required (over the 81,000 MWe of current installed capacity) during the next 15 years to meet growing energy demand. Such a rapid expansion of power generation capacity poses a serious challenge to the environment (at emission controls) and transportation infrastructure in India. Furthermore, the high ash content of indigenous coals and concentration of coal mines in central and northeastern India away from urban centers exacerbate the problem. Thus, coal preparation is envisioned to play a major role in shaping the energy future of India. Under the Indo-US Coal Preparation Program, the US Department of Energy`s Pittsburgh Energy Technology Center (PETC) is coordinating coal preparation activities for the US Agency for International Development. In this context, a detailed analysis of the washability characteristics of non-coking coals was performed using the PETC Coal Preparation Plant Simulator (CPPS) to identify coal preparation strategies for India. Based on these strategies, a profitability analysis of non-coking coal preparation has been conducted considering coal preparation and transportation costs, and coal quality impacts on power plant operations. This paper summarizes the results of this analysis and quantifies the significance of coal preparation for the Indian power sector.

Gollakota, S.V.; Rao, S.N. [Burns and Roe Services Corp., Pittsburgh, PA (United States). Pittsburgh Energy Technology Center; Staats, G.E. [Dept. of Energy, Pittsburgh, PA (United States). Pittsburgh Energy Technology Center

1996-12-31T23:59:59.000Z

383

General Counsel Legal Interpretation Regarding Medical Removal Protection Benefits Pursuant to 10 CFR Part 850, Chronic Beryllium Disease Prevention Program  

Broader source: Energy.gov [DOE]

The following document is the Office of the General Counsel (GC) interpretation regarding Medical Removal Protection Benefits Pursuant to 10 CFR Part 850, Chronic Beryllium Disease Prevention Program.

384

An example of alkalization of SiO{sub 2} in a blast furnace coke  

SciTech Connect (OSTI)

Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

2007-09-15T23:59:59.000Z

385

GREET Development and Applications for Life-Cycle Analysis of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Gas Animal Waste Waste water treatment 6 Coke Oven Gas Petroleum Coke Nuclear Energy Hydrogen GREET Examines More Than 85 VehicleFuel Systems Conventional Spark-Ignition...

386

Application of RIMS to the Study of Beryllium ChronologyApplication of RIMS to the Study of Beryllium Chronology in Early Solar System Condensatesin Early Solar System Condensates  

E-Print Network [OSTI]

, Beryllium and Boron in the Early Solar System Many unanswered questions remain concerning the timing in addressing early solar system events, but only after establishing an initial period of isotopic homogeneity for each isotopic system, as well as convincing evidence of closed system behavior, thereafter. Be has

Grossman, Lawrence

387

Co-coking of Hydrotreated Decant Oil/Coal Blends: Effect of Hydrotreatment Severity on the Yield Distribution and Quality of Distillate Fuels  

Science Journals Connector (OSTI)

The coke yield from delayed co-coking of hydrotreated DOs and coal blends was observed to be in the range of 15.9–24.4%. ... The coal used in this study (EI-106) was a 50:50 blend of the Powellton and Eagle seams, both very similar coals of high-volatile A bituminous rank from West Virginia. ... One of the hydrotreated DOs (EI-133) was coked alone. ...

Ömer Gül; Leslie R. Rudnick; Harold H. Schobert

2013-05-19T23:59:59.000Z

388

Usiing NovoCOS cleaning equipment in repairing the furnace-chamber lining in coke batteries 4 & 5 at OAO Koks  

SciTech Connect (OSTI)

Experience with a new surface-preparation technology for the ceramic resurfacing of the refractory furnace-chamber lining in coke batteries is described.

S.G. Protasov; R. Linden; A. Gross [OAO Koks, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

389

Beryllium fabrication/cost assessment for ITER (International Thermonuclear Experimental Reactor)  

SciTech Connect (OSTI)

A fabrication and cost estimate of three possible beryllium shapes for the International Thermonuclear Experimental Reactor (ITER) blanket is presented. The fabrication method by hot pressing (HP), cold isostatic pressing plus sintering (CIP+S), cold isostatic pressing plus sintering plus hot isostatic pressing (CIP+S+HIP), and sphere production by atomization or rotary electrode will be discussed. Conventional hot pressing blocks of beryllium with subsequent machining to finished shapes can be more expensive than production of a net shape by cold isostatic pressing and sintering. The three beryllium shapes to be considered here and proposed for ITER are: (1) cubic blocks (3 to 17 cm on an edge), (2) tubular cylinders (33 to 50 mm i.d. by 62 mm o.d. by 8 m long), and (3) spheres (1--5 mm dia.). A rough cost estimate of the basic shape is presented which would need to be refined if the surface finish and tolerances required are better than the sintering process produces. The final cost of the beryllium in the blanket will depend largely on the machining and recycling of beryllium required to produce the finished product. The powder preparation will be discussed before shape fabrication. 10 refs., 6 figs.

Beeston, J.M. (Beeston (J.M.), Garrison, UT (USA)); Longhurst, G.R. (EG and G Idaho, Inc., Idaho Falls, ID (USA)); Parsonage, T. (Brush Wellman, Inc., Elmore, OH (USA))

1990-06-01T23:59:59.000Z

390

Separation of Transmutation - and Fission-Produced Radioisotopes from Irradiated Beryllium  

SciTech Connect (OSTI)

The primary objective of this study was to test the effectiveness of a two-step solvent extraction-precipitation process for separating transmutation and fission products from irradiated beryllium. Beryllium metal was dissolved in nitric and fluoroboric acids. Isotopes of 241Am, 239Pu, 85Sr, 60Co, and 137Cs were then added to make a surrogate beryllium waste solution. A series of batch contacts was performed with the spiked simulant using chlorinated cobalt dicarbollide and polyethylene glycol diluted with sulfone to extract the isotopes of Cs and Sr. Another series of batch contacts was performed using a combination of octyl (phenyl)-N,Ndiisobutylcarbamoylmethylphosphine oxide in tributyl phosphate diluted with dodecane for extracting the isotopes of Pu and Am. The 60Co was separated by first forming a cobalt complex and then selectively precipitating the beryllium as a hydroxide. The results indicate that greater than 99.9% removal can be achieved for each radionuclide. Transuranic isotope contamination levels are reduced to less than 100 nCi/g, and sources of high beta-gamma radiation (60Co, 137Cs, and 90Sr) are reduced to levels that will allow the beryllium to be contact handled. The separation process may be applicable to a recycle or waste disposition scenario.

Troy J. Tranter; RIchard D. Tillotson; Nick R. Mann; Glen R. Longhurst

2011-11-01T23:59:59.000Z

391

Summary of Surface Swipe Sampling for Beryllium on Lead Bricks and Shielding  

SciTech Connect (OSTI)

Approximately 25,000 lbs of lead bricks at Site 300 were assessed by the Site 300 Industrial Hygienis tand Health Physicist for potential contamination of beryllium and radiation for reuse. These lead bricks and shielding had been used as shielding material during explosives tests that included beryllium and depleted uranium. Based on surface swipe sampling that was performed between July 26 and October 11, 2010, specifically for beryllium, the use of a spray encapsulant was found to be an effective means to limit removable surface contamination to levels below the DOE release limit for beryllium, which is 0.2 mcg/100 cm{sup 2}. All the surface swipe sampling data for beryllium and a timeline of when the samples were collected (and a brief description) are presented in this report. On December 15, 2010, the lead bricks and shielding were surveyed with an ion chamber and indicated dose rates less than 0.05 mrem per hour on contact. This represents a dose rate consistent with natural background. An additional suevey was performed on February 8, 2011, using a GM survey instrument to estimate total activity on the lead bricks and shielding, confirming safe levels of radioactivity. The vendor is licensed to possess and work with radioactive material.

Paik, S Y; Barron, D A

2011-08-03T23:59:59.000Z

392

A Comparison of Magnesium and Beryllium Acceptors in GaN Grown by rf-Plasma Assisted Molecular Beam Epitaxy  

E-Print Network [OSTI]

A Comparison of Magnesium and Beryllium Acceptors in GaN Grown by rf-Plasma Assisted Molecular Beam Evans and Associates, Sunnyvale, CA 94086 ABSTRACT Step-doped structures of both magnesium and beryllium activation energy of approximately 100 meV. INTRODUCTION While magnesium is currently the most

Myers, Tom

393

Application of artificial neural network to study the performance of jig for beneficiation of non-coking coal  

Science Journals Connector (OSTI)

Non-coking coal is the major resource of energy in India. Apart from its utilization in energy sector, the other major application of this coal is in metallurgical sector. The resource of high quality of non-coking coal is not available as per demand; as a result beneficiation of non-coking coal is now becoming essential. Jigging is one of the economical physical beneficiation processes for Indian high ash non-coking coal. At present scenario in coal washery in India, below 3 mm size is not being processed. Attempt has been taken to beneficiate the fine size non-coking coal fractions generated at different sizes of bed materials, feed rates and water rates using laboratory Denver mineral jig. The performance of jig was evaluated in term of Ep and imperfection value. Furthermore artificial neural network (ANN) model has been developed for determining combustible recovery and ash percent of the concentrate. The ANN architecture is made up of three layers (input – hidden – output). A back propagation algorithm was used for training of the ANN model. It has been observed that the predicted values by ANN model are in good agreement with the experimental results.

Lopamudra Panda; A.K. Sahoo; A. Tripathy; S.K. Biswal; A.K. Sahu

2012-01-01T23:59:59.000Z

394

Beryllium-7 Implantation in Plastics for Prosthesis Wear Studies | U.S. DOE  

Office of Science (SC) Website

Beryllium-7 Implantation in Plastics Beryllium-7 Implantation in Plastics for Prosthesis Wear Studies Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Spinoff Applications Spinoff Archives SBIR/STTR Applications of Nuclear Science and Technology Funding Opportunities Nuclear Science Advisory Committee (NSAC) News & Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: sc.np@science.doe.gov More Information » Spinoff Archives Beryllium-7 Implantation in Plastics for Prosthesis Wear Studies Print Text Size: A A A RSS Feeds FeedbackShare Page Application/instrumentation: 7Be Implantation in Plastics for Prosthesis Wear Studies Developed at: Oak Ridge National Laboratory, Holifield Radioactive Ion Beam Facility (HRIBF)

395

The use of a beryllium Hopkinson bar to characterize a piezoresistive accelerometer in shock environments  

SciTech Connect (OSTI)

The characteristics of a piezoresistive accelerometer in shock environments are being studied at Sandia National Laboratories in the Mechanical Shock Testing Laboratory. A Hopkinson bar capability has been developed to extend our understanding of the piezoresistive accelerometer, in two mechanical configurations, in the high frequency, high shock environments where measurements are being made. In this paper, the beryllium Hopkinson bar configuration with a laser doppler vibrometer as the reference measurement is described. The in-axis performance of the piezoresistive accelerometer for frequencies of dc-50 kHz and shock magnitudes of up to 70,000 g as determined from measurements with a beryllium Hopkinson bar are presented. Preliminary results of characterizations of the accelerometers subjected to cross-axis shocks in a split beryllium Hopkinson bar configuration are presented.

Bateman, V.I.; Brown, F.A.; Davie, N.T.

1996-03-01T23:59:59.000Z

396

Selective effect of the metallocarcinogen beryllium on hormonal regulation of gene expression in cultured cells  

SciTech Connect (OSTI)

Effects of the metallocarcinogen beryllium on regulation of gene expression were assessed by analysis of hormonal regulation of synthesis of tyrosine aminotransferase in beryllium-treated hepatoma cell cultures. Cell growth was not affected by exposure of the cells to 1 ..mu..M BeSO/sub 4/ throughout their 4- to 5-day growth cycle. In cells pretreated in this way, the induction by glucocorticoids was specifically impaired, the extent of induced enzyme synthesis being reduced about 50%. Inductions by insulin or cyclic adenosine 3':5'-monophosphate were not influenced by the metal. The results suggest that low concentrations of beryllium selectively interfere with regulatory mechanisms controlling transcriptional events in gene expression.

Perry, S.T.; Kulkarni, S.B.; Lee, K.L.; Kenney, F.T.

1982-02-01T23:59:59.000Z

397

Split and collectorless flotation to medium coking coal fines for multi-product zero waste concept  

Science Journals Connector (OSTI)

The medium coking coal fines of ? 0.5 mm from Jharia coal field were taken for this investigation. The release analysis of the composite coal reveals that yield is very low at 10.0% ash, about 25% at 14% ash and 50% at 17% ash level. The low yield is caused by the presence of high ash finer fraction. The size-wise ash analysis of ? 0.5 mm coal indicated that ? 0.5 + 0.15 mm fraction contains less ash than ? 0.15 mm fraction. Thus, the composite feed was split into ? 0.5 + 0.15 mm and ? 0.15 mm fractions and subjected to flotation separately. The low ash bearing fraction (? 0.5 + 0.15 mm) was subjected to two stages collectorless flotation to achieve the concentrate with 10% ash. The cleaner concentrate (18.9%) with 10% ash was recovered which has an application in metallurgical industries. The concentrate of 30.2% yield with 12.5% ash could be achieved in one stage collectorless flotation which is suitable for use in coke making as sweetener. As the ? 0.15 mm fraction contains relatively high ash, collector aided flotation using sodium silicate was performed to get a concentrate of 23.6% yield with about 17% ash. The blending of this product with cleaner tail obtained from ? 0.5 + 0.15 mm produces about 35.0% yield with 17% ash and that can be utilized for coke making. The reject from the two fractions can be used for conventional thermal power plant or cement industries using a 23.5% ash after one stage collector aided flotation and the final tailings produced content ash of 61.6% can be used for fluidization combustion bed (FBC). This eventually leads to complete utilization of coal.

Shobhana Dey; K.K. Bhattacharyya

2007-01-01T23:59:59.000Z

398

Fundamental hydrogen interactions with beryllium : a magnetic fusion perspective.  

SciTech Connect (OSTI)

Increasingly, basic models such as density functional theory and molecular dynamics are being used to simulate different aspects of hydrogen recycling from plasma facing materials. These models provide valuable insight into hydrogen diffusion, trapping, and recombination from surfaces, but their validation relies on knowledge of the detailed behavior of hydrogen at an atomic scale. Despite being the first wall material for ITER, basic single crystal beryllium surfaces have been studied only sparsely from an experimental standpoint. In prior cases researchers used electron spectroscopy to examine surface reconstruction or adsorption kinetics during exposure to a hydrogen atmosphere. While valuable, these approaches lack the ability to directly detect the positioning of hydrogen on the surface. Ion beam techniques, such as low energy ion scattering (LEIS) and direct recoil spectroscopy (DRS), are two of the only experimental approaches capable of providing this information. In this study, we applied both LEIS and DRS to examine how hydrogen binds to the Be(0001) surface. Our measurements were performed using an angle-resolved ion energy spectrometer (ARIES) to probe the surface with low energy ions (500 eV - 3 keV He{sup +} and Ne{sup +}). We were able to obtain a 'scattering maps' of the crystal surface, providing insight on how low energy ions are focused along open surface channels. Once we completed a characterization of the clean surface, we dosed the sample with atomic hydrogen using a heated tungsten capillary. A distinct signal associated with adsorbed hydrogen emerged that was consistent with hydrogen residing between atom rows. To aid in the interpretation of the experimental results, we developed a computational model to simulate ion scattering at grazing incidence. For this purpose, we incorporated a simplified surface model into the Kalypso molecular dynamics code. This approach allowed us to understand how the incident ions interacted with the surface hydrogen, providing confirmation of the preferred binding site.

Wampler, William R. (Sandia National Laboratories, Albuquerque, NM); Felter, Thomas E.; Whaley, Josh A.; Kolasinski, Robert D.; Bartelt, Norman Charles

2012-03-01T23:59:59.000Z

399

Co-gasification of Biomass with Coal and Oil Sand Coke in a Drop Tube Furnace  

Science Journals Connector (OSTI)

From this work, a synergistic effect was observed for blends of coal with petcoke and an increase in the production of H2 and CO was obtained. ... Finally, blending biomass with coal?petcoke blends did not produce any significant change in H2 production, although slight variations were observed in the production of CO and CO2. ... In addn., co-gasification tests of binary blends of a bituminous coal with different types of biomass (up to 10%) and petroleum coke (up to 60%), as well as ternary blends of coal-petcoke-biomass (45-45-10%) were conducted to study the effect of blending on gas prodn. ...

Chen Gao; Farshid Vejahati; Hasan Katalambula; Rajender Gupta

2009-10-13T23:59:59.000Z

400

Matrix endor studies of the carbonization of West Canadian coking coals  

Science Journals Connector (OSTI)

Cretaceous bituminous coals of known rank R?0 max vitrinite reflectance) have been examined by ESR (electron spin resonance) and ENDOR (electron nuclear double resonance) techniques. Both highly oxidised (outcrop) and unoxidised mine?run Balmer coal from the Crowsnest field have been subjected to heat treatment (200?900°C) and the matrix proton ENDOR signal studied as a function of applied microwave and rf power. Changes in ENDOR line shape and intensity are described with particular emphasis on the presoftening region of the unoxidised coal. A comparative study of the carbonization of hvb and 1vb coking coal from the Crowsnest is reported.

P. R. West; S. E. Cannon

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Form EIA-5 Users Manual Quarterly Coal Consumption and Quality - Coke Plants  

U.S. Energy Information Administration (EIA) Indexed Site

5 5 Users Manual Quarterly Coal Consumption and Quality - Coke Plants Document Number: 001 Version: 2.0 June 2011 i June 2011 Document History Number Date Section Description 1 2 June 2011 June 2011 Document initiation Revised screen shots and remove external user references. Primary POC: Tejasvi Raghuveer Phone: (202) 586-8926 Email: Tejasvi.Raghuveer@eia.gov Document Changes/Maintenance POC: Primary POC: Tejasvi Raghuveer Phone: (202) 586-8926 Email: Tejasvi.Raghuveer@eia.gov Project References: Coal Internet Data Collection (CIDC) User's Manual, September 2007 ii June 2011 Content 1. General System Overview ................................................................................. 1

402

Theoretical and experimental investigations into the particular features of the process of converting coal gas hydrocarbons on incandescent coke  

SciTech Connect (OSTI)

The prospects of the use of reducing gases in ferrous metallurgy and the possibilities for using them as a basis for coke production have been presented by the authors of the present article in the past. In the present report, the authors present certain results of theoretical and experimental investigations into the process of converting coal gas hydrocarbons on incandescent coke. The modification of the present-day method of thermodynamically calculating stable compositions of coking products, which was developed by the authors, has made it possible to apply it to specific chemical systems and process conditions not met with before, such as the conversion of hydrocarbons in mixtures of actual industrial gases (coal gas and blast furnace gas) in the presence of carbon and considerable amounts of hydrogen.

Zubilin, I.G.; Umanskii, V.E.

1984-01-01T23:59:59.000Z

403

A NEAR REAL-TIME BERYLLIUM MONITOR WITH CAM AND WIPE ANALYSIS CAPABILITIES  

SciTech Connect (OSTI)

Science & Engineering Associates, Inc. (SEA), under contract No. DE-AC26-00NT40768, was tasked by the US Department of Energy--National Energy Technology Laboratory to develop and test a near real-time beryllium monitor for airborne and surface measurements. Recent public awareness of the health risks associated with exposure to beryllium has underscored the need for better, faster beryllium monitoring capabilities within the DOE. A near real-time beryllium monitor will offer significant improvements over the baseline monitoring technology currently in use. Whereas the baseline technology relies upon collecting an air sample on a filter and the subsequent analysis of the filter by an analytical laboratory, this effort developed a monitor that offers near real-time measurement results while work is in progress. Since the baseline typically only offers after-the-fact documentation of exposure levels, the near real-time capability provides a significant increase in worker protection. The beryllium monitor developed utilizes laser induced breakdown spectroscopy, or LIBS as the fundamental measurement technology. LIBS has been used in a variety of laboratory and field based instrumentation to provide real-time, and near-real-time elemental analysis capabilities. LIBS is an analytical technique where a pulsed high energy laser beam is focused to a point on the sample to be interrogated. The high energy density produces a small high temperature plasma plume, sometimes called a spark. The conditions within this plasma plume result in the constituent atoms becoming excited and emitting their characteristic optical emissions. The emission light is collected and routed to an optical spectrometer for quantitative spectral analysis. Each element has optical emissions, or lines, of a specific wavelength that can be used to uniquely identify that element. In this application, the intensity of the beryllium emission is used to provide a quantitative measure of the abundance of the element in the sample. The monitor can be operated in one of two modes, as a continuous air monitor (CAM), or as a wipe monitor. In its CAM mode, the monitor collects an air sample for a user programmable sampling time on a conventional mixed cellulose ester (MCE) filter. The monitor can also be used in a wipe analysis mode, where the user can load up to 60 previously collected wipe samples, typically obtained on 47 mm filter media, into disposable filter cassettes. Under this effort, a beryllium monitor was designed, fabricated and tested. During laboratory testing, the monitor's measurement performance met the stated measurement objectives at the outset of the project. A typical minimum detectable beryllium mass for the monitor is below the 0.2 mg/m{sup 3} goal of the project. Field-testing of the monitor show it to exhibit extremely good sensitivity to very low levels of beryllium. On a per spark basis, the monitor has been shown to be capable of detecting a few tens of picograms of beryllium. At the culmination of the project, the beryllium CAM unit was delivered to the U.S. DOE-Rocky Flats Environmental Management Site where it is undergoing additional on-site evaluations.

D.T. Kendrick; Steven Saggese

2002-12-01T23:59:59.000Z

404

Paired Straight Hearth Furnace  

Broader source: Energy.gov [DOE]

A coal based dri and molten metal process for long range replacement of blast furnaces and coke ovens

405

Methane steam reforming at low temperature: Effect of light alkanes’ presence on coke formation  

Science Journals Connector (OSTI)

Abstract Steam reforming of natural gas for the production of hydrogen at low operation temperature offers significant financial and environmental advantages. However, the presence of higher hydrocarbons as minor components of natural gas can significantly affect the formation of coke and thus the effectiveness of the catalyst. In this study, the effect of the presence of C2–C3 alkanes in the feedstock on the carbon accumulation during low temperature steam reforming of methane is investigated over Ni and Rh catalysts supported on lanthanum doped ceria–zirconia mixed oxide. Both catalysts showed high resistance to coke formation and especially in the case of Rh/La/CeO2–ZrO2, the carbon accumulation detected was low even after 10 h on stream in steam reforming of all mixtures of hydrocarbons tested. The presence of higher alkanes in methane increased the amount of carbon on Ni(10)CeZrLa compared to pure methane as well as the nature of the carbonaceous species. Increase in the C-number of the additive alkane had almost no influence on the total amount of carbon formed (C/H feed ratio = constant) but favored the formation of filamentous carbon.

Sofia D. Angeli; Fotis G. Pilitsis; Angeliki A. Lemonidou

2015-01-01T23:59:59.000Z

406

Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz  

SciTech Connect (OSTI)

The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

2008-03-15T23:59:59.000Z

407

Features of hydrotreating catalytic cracking feed and heavy slow coking gas oils  

SciTech Connect (OSTI)

A possible means of more extensive processing of crude oil is the use, in catalytic cracking, of heavy coking gas oils (HCGOs), a feature of which is a higher content of polycyclic aromatic compounds and resins by comparison with straight-run vacuum distillates. The presence of these compounds in catalytic cracking feed causes a reduction in the product yield and increased coke formation. Therefore, one of the problems of hydrotreating feedstock of this kind is the hydrogenation of polycyclic arenes. Processes of extensive desulphurization and denitration occur in parallel, since the sulphur and nitrogen compounds of HCGO are chiefly condensed benzoderivatives of thiophene, pyridine and carbazole, and largely concentrated in heavy aromatic and resinous fractions. The composition of the saturated part of the cracking feed plays a large role in achieving the optimum yields of gaseous and gasoline fractions. Thus an increase in the proportion of cyclanes in the feed raises the gasoline yield. In this way, an investigation of the hydrocarbon conversions during the hydrotreatment of cracking feed is of great importance. The present paper sets out the results for studying the change in the group-structural characteristics of the hydrogenation products of a mixture containing 30% HCGOs according to data of {sup 1}H and {sup 13}C NMR spectroscopy. 7 refs., 7 figs., 1 tab.

Yefremov, N.I.; Kushnarev, D.F.; Frolov, P.A.; Chagovets, A.N.; Kalabin, G.A.

1993-12-31T23:59:59.000Z

408

Petroleum Coke  

U.S. Energy Information Administration (EIA) Indexed Site

81,811 82,516 82,971 84,053 85,190 84,889 1986-2013 East Coast (PADD 1) 12,198 10,887 9,316 9,766 9,003 7,430 1986-2013 Midwest (PADD 2) 15,005 15,507 16,480 16,834 17,611 17,597...

409

Progress on a Cavity with Beryllium Walls for Muon Ionization Cooling Channel R&D.  

SciTech Connect (OSTI)

The Muon Accelerator Program (MAP) collaboration is working to develop an ionization cooling channel for muon beams. An ionization cooling channel requires the operation of high-gradient, normal-conducting RF cavities in multi-Tesla solenoidal magnetic fields. However, experiments conducted at Fermilab?s MuCool Test Area (MTA) show that increasing the solenoidal field strength reduces the maximum achievable cavity gradient. This gradient limit is characterized by an RF breakdown process that has caused significant damage to copper cavity interiors. The damage may be caused by field-emitted electrons, focused by the solenoidal magnetic field onto small areas of the inner cavity surface. Local heating may then induce material fatigue and surface damage. Fabricating a cavity with beryllium walls would mitigate this damage due to beryllium?s low density, low thermal expansion, and high electrical and thermal conductivity. We address the design and fabrication of a pillbox RF cavity with beryllium walls, in order to evaluate the performance of high-gradient cavities in strong magnetic fields.

Bowring, D.L.; DeMello, A.J.; Lambert, A.R.; Li, D.; Virostek,, S.; Zisman, M.; Kaplan, D.; Palmer, R.B.

2012-05-20T23:59:59.000Z

410

Characterization of celotex and thermodynamic calculations of the formation of corrosion precursors on beryllium  

SciTech Connect (OSTI)

The importance of safe and long-term storage of nuclear weapons components has drawn attention towards the characterization and understanding of the corrosion precursors formed on beryllium. A complete compositional and thermal characterization of celotex was carried out using energy dispersive spectroscopy, inductively coupled plasma-mass spectroscopic analysis, ion chromatography, and thermogravimetric analysis. Both fluoride and sulfate anions in addition to chloride as well as several metal ions are found to be present. The chloride present in celotex is lost at moderate temperatures 200 < T < 400 C, which may have important consequences on the formation of corrosion precursors. Equilibrium thermodynamic calculations on the stability of beryllium oxide in chlorinated environments were performed for a model system composed by beryllium, carbon, chlorine, hydrogen and oxygen. The calculations were aimed at describing the equilibrium, long-term behavior of a beryllium surface and its interaction with chlorine in a closed environment. The authors found that (i) carbon is essential for the formation of BeCl{sub 2}, and (ii) the chlorine-to-hydrogen ratio in chlorinated solvents is an important quantity since for solvents with chlorine-to-hydrogen ratio higher than 1, BeCl{sub 2} is not formed independently of the amount of solvent.

Diaz-Ortiz, A.; Stolk, J.; Kim, J.; Sanchez, J.M.; Manthiram, A. [Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program

1999-04-01T23:59:59.000Z

411

Aerosol resuspension from fabric: implications for personal monitoring in the beryllium industry  

SciTech Connect (OSTI)

The fabric used for work clothing at an industrial site can significantly influence personal monitor (PM) exposure estimates because dust resuspension from clothing can increase the concentration at the sampler inlet. The magnitude of the effect depends on removal forces and on the interaction of the contaminant particles with work garments. Aerosol deposition and resuspension on cotton and Nomex aramid fabrics was evaluated at a beryllium refinery. Electrostatically charged cotton backdrops collected more beryllium than neutral controls, but electronegative Nomex backdrops did not. Moving fabrics collected more beryllium than did stationary controls. When contaminated fabrics were agitated, PMs mounted 2.5 cm in front of the fabric collected more beryllium than monitors above the fabric, positioned to simulate the nose or mouth. The difference between the air concentrations measured by these PMs increased with Be loading and tended to level off for highly contaminated fabric. Cotton resuspended a larger fraction of its contaminant load than Nomex. These results are consistent with current knowledge of the behavior of particles on fabric fibers. Aerosol resuspension from garments is an important consideration in assessing inhalation exposure to toxic dusts. A garment may attract and retain toxic particles. This contamination is then available for later resuspension.

Bohne, J.E. Jr.; Cohen, B.S.

1985-02-01T23:59:59.000Z

412

ITER-like wall sliced beryllium tiles The JET Enhanced Performance 2 (EP2) shutdown  

E-Print Network [OSTI]

ITER-like wall sliced beryllium tiles Background The JET Enhanced Performance 2 (EP2) shutdown and remote handling equipment. JET remote handling systems #12;Outcome The EP2 shutdown was successful of the remote handling system are compatible with the required component manipulation. Pre EP2 shutdown Mid

413

Evaluation of HEU-Beryllium Benchmark Experiments to Improve Computational Analysis of Space Reactors  

SciTech Connect (OSTI)

An assessment was previously performed to evaluate modeling capabilities and quantify preliminary biases and uncertainties associated with the modeling methods and data utilized in designing a nuclear reactor such as a beryllium-reflected, highly-enriched-uranium (HEU)-O2 fission surface power (FSP) system for space nuclear power. The conclusion of the previous study was that current capabilities could preclude the necessity of a cold critical test of the FSP; however, additional testing would reduce uncertainties in the beryllium and uranium cross-section data and the overall uncertainty in the computational models. A series of critical experiments using HEU metal were performed in the 1960s and 1970s in support of criticality safety operations at the Y-12 Plant. Of the hundreds of experiments, three were identified as fast-fission configurations reflected by beryllium metal. These experiments have been evaluated as benchmarks for inclusion in the International Handbook of Evaluated Criticality Safety Benchmark Experiments (IHECSBE). Further evaluation of the benchmark experiments was performed using the sensitivity and uncertainty analysis capabilities of SCALE 6. The data adjustment methods of SCALE 6 have been employed in the validation of an example FSP design model to reduce the uncertainty due to the beryllium cross section data.

John D. Bess; Keith C. Bledsoe; Bradley T. Rearden

2011-02-01T23:59:59.000Z

414

Evaluation of HEU-Beryllium Benchmark Experiments to Improve Computational Analysis of Space Reactors  

SciTech Connect (OSTI)

An assessment was previously performed to evaluate modeling capabilities and quantify preliminary biases and uncertainties associated with the modeling methods and data utilized in designing a nuclear reactor such as a beryllium-reflected, highly-enriched-uranium (HEU)-O2 fission surface power (FSP) system for space nuclear power. The conclusion of the previous study was that current capabilities could preclude the necessity of a cold critical test of the FSP; however, additional testing would reduce uncertainties in the beryllium and uranium cross-section data and the overall uncertainty in the computational models. A series of critical experiments using HEU metal were performed in the 1960s and 1970s in support of criticality safety operations at the Y-12 Plant. Of the hundreds of experiments, three were identified as fast-fission configurations reflected by beryllium metal. These experiments have been evaluated as benchmarks for inclusion in the International Handbook of Evaluated Criticality Safety Benchmark Experiments (IHECSBE). Further evaluation of the benchmark experiments was performed using the sensitivity and uncertainty analysis capabilities of SCALE 6. The data adjustment methods of SCALE 6 have been employed in the validation of an example FSP design model to reduce the uncertainty due to the beryllium cross section data.

Bess, John [Idaho National Laboratory (INL); Bledsoe, Keith C [ORNL; Rearden, Bradley T [ORNL

2011-01-01T23:59:59.000Z

415

Implementation Guide for use with 10 CFR Part 850, Chronic Beryllium Disease Prevention Program  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

The Department of Energy (DOE) has established regulatory requirements for the Chronic Beryllium Disease Prevention Program (CBDPP) in Title 10 of the Code of Federal Regulations (CFR), Part 850 (10 CFR 850) [64 Federal Register (FR) 68854]. Cancels DOE G 440.1-7. Certified 9-23-10.

2001-01-04T23:59:59.000Z

416

Irradiated Beryllium Disposal Workshop, Idaho Falls, ID, May 29-30, 2002  

SciTech Connect (OSTI)

In 2001, while performing routine radioactive decay heat rate calculations for beryllium reflector blocks for the Advanced Test Reactor (ATR), it became evident that there may be sufficient concentrations of transuranic isotopes to require classification of this irradiated beryllium as transuranic waste. Measurements on samples from ATR reflector blocks and further calculations confirmed that for reflector blocks and outer shim control cylinders now in the ATR canal, transuranic activities are about five times the threshold for classification. That situation implies that there is no apparent disposal pathway for this material. The problem is not unique to the ATR. The High Flux Isotope Reactor at Oak Ridge National Laboratory, the Missouri University Research Reactor at Columbia, Missouri and other reactors abroad must also deal with this issue. A workshop was held in Idaho Falls Idaho on May 29-30, 2002 to acquaint stakeholders with these findings and consider a path forward in resolving the issues attendant to disposition of irradiated material. Among the findings from this workshop were (1) there is a real potential for the US to be dependent on foreign sources for metallic beryllium within about a decade; (2) there is a need for a national policy on beryllium utilization and disposition and for a beryllium coordinating committee to be assembled to provide guidance on that policy; (3) it appears it will be difficult to dispose of this material at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico due to issues of Defense classification, facility radioactivity inventory limits, and transportation to WIPP; (4) there is a need for a funded DOE program to seek resolution of these issues including research on processing techniques that may make this waste acceptable in an existing disposal pathway or allow for its recycle.

Longhurst, Glen Reed; Anderson, Gail; Mullen, Carlan K; West, William Howard

2002-07-01T23:59:59.000Z

417

Beryllium-10 in the Taylor Dome ice core: Applications to Antarctic glaciology and paleoclimatology  

SciTech Connect (OSTI)

An ice core was drilled at Taylor dome, East Antarctica, reaching to bedrock at 554 meters. Oxygen-isotope measurements reveal climatic fluctuations through the last interglacial period. To facilitate comparison of the Taylor Dome paleoclimate record with geologic data and results from other deep ice cores, several glaciological issues need to be addressed. In particular, accumulation data are necessary as input for numerical ice-flow-models, for determining the flux of chemical constituents from measured concentrations, and for calculation of the offset in age between ice and trapped air in the core. The analysis of cosmogenic beryllium-10 provides a geochemical method for constraining the accumulation-rate history at Taylor Dome. High-resolution measurements were made in shallow firn cores and snow pits to determine the relationship among beryllium-10 concentrations, wet and dry deposition mechanisms, and snow-accumulation rates. Comparison between theoretical and measured variations in deposition over the last 75 years constrains the relationship between beryllium-10 deposition and global average production rates. The results indicate that variations in geomagnetically-modulated production-rate do not strongly influence beryllium-10 deposition at Taylor Dome. Although solar modulation of production rate is important for time scales of years to centuries, snow-accumulation rate is the dominant control on ice-core beryllium-10 concentrations for longer periods. Results show that the Taylor Dome core can be used to provide new constraints on regional climate over the last 130,000 years, complementing the terrestrial and marine geological record from the Dry Valley, Transantarctic Mountains and western Ross Sea.

Steig, E.J.

1996-12-31T23:59:59.000Z

418

Co-Gasification of Biomass Wastes and Coal?Coke Blends in an Entrained Flow Gasifier: An Experimental Study  

Science Journals Connector (OSTI)

An experimental study of entrained flow, air-blown cogasification of biomass and a coal?coke mixture has been performed in order to evaluate the effect of the relative fuel/air ratio (ranging between 2.5 and 7.5), the reaction temperature (ranging between ...

Juan J. Hernández; Guadalupe Aranda-Almansa; Clara Serrano

2010-03-29T23:59:59.000Z

419

Industry  

E-Print Network [OSTI]

combined heat and power and coke ovens, and waste managementto ban the use of small-scale coke-producing facilities forcasting, Scrap preheating, Dry coke quenching Inert anodes,

Bernstein, Lenny

2008-01-01T23:59:59.000Z

420

Evaluation of pitches and cokes from solvent-extracted coal materials  

SciTech Connect (OSTI)

Three initial coal-extracted (C-E) samples were received from the West Virginia University (WVU) Chemical Engineering Department. Two samples had been hydrogenated to obtain pitches that satisfy Theological requirements. One of the hydrogenated (HC-E) samples had been extracted by toluene to remove ash and higher molecular weight aromatic compounds. We were unable to measure the softening point and viscosity of the non-hydro treated solid extract sample, Positive characteristics in the HC-E materials were softening points of 113-119{degrees}C, low sulfur and ash. The oxygen and nitrogen content of the HC-E samples may limit future usage in premium carbon and graphite products. Coking values were similar to petroleum pitches. Laboratory anode testing indicates that in combination with standard coal-tar pitch, the HC-E material can be used as a binder pitch.

McHenry, E.R.

1996-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Comparative study of the performance of conventional and column flotation when treating coking coal fines  

Science Journals Connector (OSTI)

Investigations were carried out on coking coal fines by conventional cell and column flotation techniques. The effects of different operating parameters were evaluated for both conventional and column flotation. The coal fines were collected from Bhojudih washery, India. These coal fines averaged 24.4% ash, 19.8% volatile matter and 53.8% fixed carbon on a dry basis. A commercial grade sodium silicate, light diesel oil and pine oil were used as depressant, collector and frother respectively. The flotation performance was compared with release analysis. The conventional flotation results indicated that a clean coal with 14.4% ash could be obtained at 78.0% yield with 88.4% combustible recovery. The ash of the clean coal could be further reduced to 10.1% at 72.0% yield with 85.6% combustible recovery by using column flotation. The column flotation results were close to those obtained by release analysis.

M.S. Jena; S.K. Biswal; S.P. Das; P.S.R. Reddy

2008-01-01T23:59:59.000Z

422

Fouling in a 160 MWe FBC boiler firing coal and petroleum coke  

Science Journals Connector (OSTI)

The 160 MWe fluidized bed combustor (FBC) boiler owned and operated by the Tennessee Valley Authority (TVA) has recently been co-fired with coal and petroleum coke (up to 50%). However, it has suffered some fouling problems. On examination of the deposits it became clear that, in only a few cases could the fouling be partially attributed to alkali metals, and even in those cases the primarily limestone-derived materials were almost quantitatively sulphated to a level which was sufficient to cause strength development by itself. In other cases, it appeared that the fouling mechanism was carbonation of the free lime component of the deposit followed by sulphation. Finally, in a few deposits which were less sulphated than bed materials and fly ash, strength development appeared to have occurred by conversion of the free lime in the deposits to Ca(OH)2, followed by carbonation. This type of agglomeration has not been reported previously in a FBC.

E.J. Anthony; A.P. Iribarne; J.V. Iribarne; R. Talbot; L. Jia; D.L. Granatstein

2001-01-01T23:59:59.000Z

423

Cyanide leaching from soil developed from coking plant purifier waste as influenced by citrate  

SciTech Connect (OSTI)

Soils in the vicinity of manufactured gas plants and coal coking plants are often highly contaminated with cyanides in the form of the compound Prussian blue. The objective of this study was to investigate the influence of citrate on the leaching of iron-cyanide complexes from an extremely acidic soil (pH 2.3) developed from gas purifier waste near a former coking plant. The soil contained 63 g kg{sup -1} CN, 148 g kg{sup -1} Fe, 123 g kg{sup -1} S, and 222 g kg{sup -1} total C. Analysis of the soil by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy revealed the presence of Prussian blue, gypsum, elemental sulfur, jarosite, and hematite. For column leaching experiments, air-dried soil was mixed with purified cristabolite sand at a ratio of 1:3 and packed into chromatography columns. The soil was leached with dilute (0.1 or 1 mM) CaCl{sub 2} solutions and the effluent was collected and analyzed for total and dissolved CN, Ca, Fe, SO{sub 4}, pH, and pe. In the absence of citrate, the total dissolved CN concentration in the effluent was always below current drinking water limits (< 1.92 {mu}M), indicating low leaching potential. Adding citrate at a concentration of 1 mM had little effect on the CN concentrations in the column effluent. Addition of 10 or 100 mM citrate to the influent solution resulted in strong increases in dissolved and colloidal CN concentrations in the effluent.

Tim Mansfeldt; Heike Leyer; Kurt Barmettler; Ruben Kretzschmar [Ruhr-University Bochum, Bochum (Germany). Soil Science and Soil Ecology Group, Faculty of Geosciences

2004-07-01T23:59:59.000Z

424

Influence of coal thermoplastic properties on coking pressure generation: Part 2 – A study of binary coal blends and specific additives  

Science Journals Connector (OSTI)

A number of coal blends and pitch/coal blends were evaluated using rheometry, thermogravimetric analysis and microscopy to confirm and further elucidate the coking pressure mechanism previously proposed by Duffy et al. (2007) [1]. We confirm that blending a low rank, high fluidity, low coking pressure coal, with a high rank, low fluidity, high coking pressure coal can significantly reduce the coking pressure associated with the latter. Interestingly, blending does not necessarily result in a fluidity that is midway between that of the two coals; sometimes the fluidity of the blend is less than that of the low fluidity coal, especially when the coals are significantly different in rank. This occurs because the increase in complex viscosity (?*) through resolidification of the low rank, high fluidity coal counteracts the reduction in ?* resulting from softening of the high rank, low fluidity coal. It has also been confirmed that the ?* of the resultant blend can be estimated from the ?* of each component coal using a logarithmic additivity rule commonly employed for polymer blends. Polarised light microscopy has indicated that the degree of mixing between coals of different rank is minimal, with fusion restricted to the particle surface. It is therefore inappropriate to think of such a coal blend in the same way as a single coal, since each component coal behaves relatively independently. This limited fusion is important for understanding the coking pressure mechanism for blends. It is proposed here that the lower rank coal, which softens at lower temperature, is able to expand into the interparticle voids between the high rank coal that is yet to soften, and these voids can create channels for volatiles to traverse. Then, and importantly, when the high rank coal begins to expand, the pore structure developed in the resolidified structures of the low rank coal can facilitate removal of volatiles, while the resolidified material may also act as a suitable sorbent for volatile matter. This is considered to be the primary mechanism by which coal blending is able to alleviate coking pressure, and applies to addition of inert material also. Addition of a coal tar pitch was found to increase fluidity but also to extend the thermoplastic range to lower temperatures. This caused an increase in the swelling range, which was accompanied by a long plateau in ?*, a feature which has previously been observed for certain high fluidity, high pressure coals. Elasticity and ?* at the onset of expansion were also higher for both the pitch impregnated coals and the high pressure blends, which supports previous findings for singly charged high pressure coals, and confirms the potential use of such criteria for identifying potentially dangerous coals/blends.

John J. Duffy; Merrick R. Mahoney; Karen M. Steel

2010-01-01T23:59:59.000Z

425

Roughening and removal of surface contamination from beryllium using negative transferred-arc cleaning  

SciTech Connect (OSTI)

Negative transferred-arc (TA) cleaning has been used extensively in the aerospace industry to clean and prepare surfaces prior to plasma spraying of thermal barrier coatings. This non-line of sight process can improve the bond strength of plasma sprayed coatings to the substrate material by cleaning and macroscopically roughening the surface. A variation of this cleaning methodology is also used in gas tungsten arc (GTA) welding to cathodically clean the surfaces of aluminum and magnesium prior to welding. Investigations are currently being performed to quantify the degree in which the negative transferred-arc process can clean and roughen metal surfaces. Preliminary information will be reported on the influence of processing conditions on roughening and the removal of carbon and other contaminates from the surface of beryllium. Optical, spectral and electrical methods to quantify cleaning of the surface will also be discussed. Applications for this technology include chemical-free precision cleaning of beryllium components.

Castro, R.G.; Hollis, K.J.; Elliott, K.E. [Los Alamos National Lab., NM (United States). Materials Science and Technology Div.

1997-12-01T23:59:59.000Z

426

Low Prevalence of Chronic Beryllium Disease among Workers at a Nuclear Weapons Research and Development Facility  

SciTech Connect (OSTI)

To study the prevalence of beryllium sensitization (BeS) and chronic beryllium disease (CBD) in a cohort of workers from a nuclear weapons research and development facility. We evaluated 50 workers with BeS with medical and occupational histories, physical examination, chest imaging with HRCT (N=49), and pulmonary function testing. Forty of these workers also underwent bronchoscopy for bronchoalveolar lavage (BAL) and transbronchial biopsies. The mean duration of employment at the facility was 18 yrs and the mean latency (from first possible exposure) to time of evaluation was 32 yrs. Five of the workers had CBD at the time of evaluation (based on histology or HRCT); three others had evidence of probable CBD. These workers with BeS, characterized by a long duration of potential Be exposure and a long latency, had a low prevalence of CBD.

Arjomandi, M; Seward, J P; Gotway, M B; Nishimura, S; Fulton, G P; Thundiyil, J; King, T E; Harber, P; Balmes, J R

2010-01-11T23:59:59.000Z

427

Evaluating coking resources. 2. State standard GOST 25543-88 as a coding system for coal and coal mixtures in evaluating their technological properties  

Science Journals Connector (OSTI)

The codification of coal in State Standard 25543-88 is compared with the international codification of coal of medium and high rank. The ranking of coking coal on the basis of State Standard GOST...

Yu. A. Zolotukhin

2008-08-01T23:59:59.000Z

428

Follow-up Review of the Hanford Site Chronic Beryllium Disease Prevention Program, February 2013  

Broader source: Energy.gov (indexed) [DOE]

Independent Oversight Independent Oversight Follow-up Review of the Hanford Site Chronic Beryllium Disease Prevention Program February 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose................................................................................................................................... 1 2.0 Background ............................................................................................................................ 1 3.0 Scope...................................................................................................................................... 1 4.0 Results.................................................................................................................................... 2

429

Beryllium abundances in parent stars of extrasolar planets: 16 Cyg A & B and rho 1 Cnc  

E-Print Network [OSTI]

The Be II 3131 A doublet has been observed in the solar-type stars 16 Cyg A & B and in the late G-type star rho 1 Cnc, to derive their beryllium abundances. 16 Cyg A & B show similar (solar) beryllium abundances while 16 Cyg B, which has been proposed to have a planetary companion of ~2 M_Jup, is known to be depleted in lithium by a factor larger than 6 with respect to 16 Cyg A. Differences in their rotational histories which could induce different rates of internal mixing of material, and the ingestion of a similar planet by 16 Cyg A are discussed as potential explanations. The existence of two other solar-type stars which are candidates to harbour planetary-mass companions and which show lithium and beryllium abundances close to those of 16 Cyg A, requires a more detailed inspection of the peculiarities of the 16 Cyg system. For rho 1 Cnc, which is the coolest known object candidate to harbour a planetary-mass companion (M > 0.85 M_Jup), we establish a precise upper limit for its beryllium abundance, showing a strong Be depletion which constrains the available mixing mechanisms. Observations of similar stars without companions are required to asses the potential effects of the planetary companion on the observed depletion. It has been recently claimed that rho 1 Cnc appears to be a subgiant. If this were the case, the observed strong Li and Be depletions could be explained by a dilution process taking place during its post-main sequence evolution.

R. J. Garcia Lopez; M. R. Perez de Taoro

1998-03-03T23:59:59.000Z

430

Sampling for Beryllium Surface Contamination using Wet, Dry and Alcohol Wipe Sampling  

SciTech Connect (OSTI)

This research project was conducted at the National Nuclear Security Administration's Kansas City Plant, operated by Honeywell Federal Manufacturing and Technologies, in conjunction with the Safety Sciences Department of Central Missouri State University, to compare relative removal efficiencies of three wipe sampling techniques currently used at Department of Energy facilities. Efficiencies of removal of beryllium contamination from typical painted surfaces were tested by wipe sampling with dry Whatman 42 filter paper, with water-moistened (Ghost Wipe) materials, and by methanol-moistened wipes. Test plates were prepared using 100 mm X 15 mm Pyrex Petri dishes with interior surfaces spray painted with a bond coat primer. To achieve uniform deposition over the test plate surface, 10 ml aliquots of solution containing 1 beryllium and 0.1 ml of metal working fluid were transferred to the test plates and subsequently evaporated. Metal working fluid was added to simulate the slight oiliness common on surfaces in metal working shops where fugitive oil mist accumulates over time. Sixteen test plates for each wipe method (dry, water, and methanol) were processed and sampled using a modification of wiping patterns recommended by OSHA Method 125G. Laboratory and statistical analysis showed that methanol-moistened wipe sampling removed significantly more (about twice as much) beryllium/oil-film surface contamination as water-moistened wipes (p< 0.001), which removed significantly more (about twice as much) residue as dry wipes (p <0.001). Evidence for beryllium sensitization via skin exposure argues in favor of wipe sampling with wetting agents that provide enhanced residue removal efficiency.

Kerr, Kent

2004-12-17T23:59:59.000Z

431

Comparative Study of Gasification Performance between Bituminous Coal and Petroleum Coke in the Industrial Opposed Multiburner Entrained Flow Gasifier  

Science Journals Connector (OSTI)

SUMMARY : Co-gasification performance of coal and petroleum coke (petcoke) blends in a pilot-scale pressurized entrained-flow gasifier was studied exptl. ... Two different coals, including a subbituminous coal (Coal A) and a bituminous coal (Coal B), individually blended with a petcoke in the gasifier were considered. ... results suggested that, when the petcoke was mixed with Coal A over 70%, the slagging problem, which could shorten the operational period due to high ash content in the coal, was improved. ...

Zhonghua Sun; Zhenghua Dai; Zhijie Zhou; Jianliang Xu; Guangsuo Yu

2012-09-27T23:59:59.000Z

432

Characterization of fly ashes from circulating fluidized bed combustion (CFBC) boilers cofiring coal and petroleum coke  

SciTech Connect (OSTI)

The chemistry, mineralogy, morphology, and particle size distribution were investigated in fly ashes from the burning of Datong (ShanXi, China) bituminous coal and the cofiring of Mideast high-sulfur petroleum coke (PC) with 30:70 (cal %) and 50:50 (cal %) blends of Datong bituminous coal in two commercial CFBC boilers. With the exception of CaO, the amounts of major oxides in the fly ashes from cofiring PC and coal were close to those of the common coal fly ashes. The PC-coal fly ashes were enriched in Ni, V, and Mo, implying these trace elements were mainly derived from PC. Ni and V, along with several other elements, such as Cr, Cu, Se, Pb, U, Th, and possibly As and Cd, increased in content with a decrease in temperature of the electrostatic precipitator (ESP). The results of chemistry, mineralogy, and morphology studies suggested that the desulfurization rate of the CFBC boilers at current conditions was low, and the PC tends to coarsen the fly ash particles and increase the loss on ignition (LOI) values, making these fly ashes unsuitable for use as a cement additive or a mineral admixture in concrete. Further studies on the combustion status of the CFBC boilers are needed if we want to be able to increase the desulfurization rate and produce high-quality fly ashes for broader and full utilization. 22 refs., 4 figs., 4 tabs.

Feihu Li; Jianping Zhai; Xiaoru Fu; Guanghong Sheng [Nanjing University, Nanjing (China). State Key Laboratory of Pollution Control & Resource Reuse, School of the Environment

2006-08-15T23:59:59.000Z

433

“Coking” of zeolites during methanol conversion: Basic reactions of the MTO-, MTP- and MTG processes  

Science Journals Connector (OSTI)

Deactivation of acidic zeolite catalysts during methanol conversion is investigated for elucidating how spatial constraints interfere mechanistically. Detailed product composition – including retained organic matter – is determined in a time resolved mode. At 270–300 °C with H-ZSM-5, first unsaturated hydrocarbons are formed—methane being the indicative co-product. Then the reaction rate increases auto-catalytically, but soon declines because of exhaustive pore filling. The retained organic matter consists mainly of ethyl-trimethyl-benzene- and isopropyl-dimethyl-benzene molecules. Alkylation of benzene rings with ethene and propene produces the deactivating molecules. At 475 °C, alkylation of benzene rings with olefins has shifted to the reverse, reactivating the H-ZSM-5 catalyst. Coke forms slowly on the surface of H-ZSM-5 crystallites. Spatial constraints suppress the formation of 2-ring aromatics. With the wide pore zeolite H-Y, fast deactivation is noticed—bigger aromatic molecules can be formed and are retained. Methanol reactions on the protonic catalyst sites are visualized as CH3+ attack for methylation and dehydrogenation, methane being the hydrogen-rich co-product. Methanol conversion on zeolites H-ZSM-58, H-EU-1 and H-Beta is comparatively investigated. Zone ageing is discussed for favorable reactor design. It is shown, how a multi-compound product composition is the source of information for elucidating complex reaction mechanisms.

Hans Schulz

2010-01-01T23:59:59.000Z

434

Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends  

SciTech Connect (OSTI)

Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Energy Technology Research Institute

2008-05-15T23:59:59.000Z

435

Removal of ash from Indian Assam coking coal using sodium hydroxide and acid solutions  

SciTech Connect (OSTI)

Mineral matter (ash) removal from Assam coking coal by leaching with different concentrations of sodium hydroxide and acid (HCl, H{sub 2}SO{sub 4}, HNO{sub 3}, and HF) solutions has been investigated at a temperature of 75 C. The parameters tested were concentration of NaOH, type of acid, concentration of acids, and number of acid leaching steps. Total ash removed increased with increase of NaOH and acid concentrations up to the range studied. For the same experimental conditions, treatment of caustic leached coal in HCl acid resulted in better demineralization than in H{sub 2}SO{sub 4} or HNO{sub 3} acid. In the NaOH-HNO{sub 3} leaching method, a higher concentration (>20%) of HNO{sub 3} acid had an adverse effect on the de-ashing of coal. The NaOH-HF leaching process has been found to be the most effective method of coal de-ashing. The two acid treatment steps (HCl-H{sub 2}SO{sub 4}/HCl-HNO{sub 3}) after caustic leaching are the next most effective methods of coal de-ashing. The removal of mineral matter (including S) from coal is expected to decrease the graphite reactivity and thus the atmospheric pollution (due to the generation of smaller quantities of CO and SO{sub 2} gases).

Kumar, M.; Shankar, R.H.

2000-03-01T23:59:59.000Z

436

"Diffusion of Innovation: Solar Oven Use in Lesotho (Africa)." Grundy, William and Roy Grundy. Advances in Solar Cooking: Proceedings of the 2nd International Conference on Solar Cooker Use and Technology. Shyam S. Nandwani, ed. July 12-15, 1994.  

E-Print Network [OSTI]

"Diffusion of Innovation: Solar Oven Use in Lesotho (Africa)." Grundy, William and Roy Grundy. Advances in Solar Cooking: Proceedings of the 2nd International Conference on Solar Cooker Use and Technology. Shyam S. Nandwani, ed. July 12-15, 1994. pp. 240-247. 1 DIFFUSION OF INNOVATION: SOLAR OVEN USE

Noble, William Stafford

437

Results of the radiological and beryllium verification survey at the Peek Street Site, Schenectady, New York (SY001V)  

SciTech Connect (OSTI)

At the request of the U.S. Department of Energy (DOE), a team from Oak Ridge National Laboratory conducted an independent verification radiological and non-radioactive beryllium survey at the Peek Street site, located at 425 Peek Street, Schenectady, New York. The purpose of the survey, conducted during 1993 and continuing through January 1994, was to confirm the success of the remedial actions performed to remove any beryllium concentrations or radioactive materials in excess of the identified guidelines. The verification survey included surface gamma scans and gamma readings at one meter indoors and outdoors, alpha and beta scans inside the structure, and the collection of soil, dust and debris samples and smears for radionuclide and beryllium analyses. Results of the survey demonstrated that all radiological and beryllium measurements on the property were within applicable DOE guidelines. Based on all data collected, the industrial property at 425 Peek Street and the adjacent state-owned bike path in Schenectady, New York, conforms to all applicable radiological and non-radioactive beryllium guidelines established for this site by DOE and approved by the State of New York.

Foley, R.D.; Johnson, C.A.; Carrier, R.F.; Allred, J.F.

1994-10-01T23:59:59.000Z

438

Beryllium Health and Safety Committee Data Reporting Task Force White Paper #2 -- Uses of Uncensored Data  

SciTech Connect (OSTI)

On December 8, 1999, the Department of Energy (DOE) published Title 10 CFR 850 (hereafter referred to as the Rule) to establish a chronic beryllium disease prevention program (CBDPP) to: (1) reduce the number of workers currently exposed to beryllium in the course of their work at DOE facilities managed by DOE or its contractors; (2) minimize the levels of, and potential for, exposure to beryllium; and (3) establish medical surveillance requirements to ensure early detection of the disease. On January 4, 2001, DOE issued DOE G 440.1-7A, Implementation Guide for use with 10 CFR 850, Chronic Beryllium Disease Prevention Program, to assist line managers in meeting their responsibilities for implementing the CBDPP. That guide describes methods and techniques that DOE considers acceptable in complying with the Rule. In 2005 a draft DOE Technical Standard ''Management of Items and Areas Containing Low Levels of Beryllium'' (SAFT 0103; hereafter referred to as the ''TS'') was circulated for comment (http://www.hss.energy.gov/NuclearSafety/techstds/tsdrafts/saft-0103.pdf). DOE technical standards are voluntary consensus standards developed when industry standards do not exist (see http://www.hss.energy.gov/NuclearSafety/techstds/index.html for more information). DOE does not require its field elements to implement DOE technical standards, but field elements may choose to adopt these standards to meet specific needs. This beryllium TS is intended to provide best practices and lessons learned for manageing items and areas that contain low levels of beryllium, which has been a costly and technically challenging component of CBDPPs. The TS is also intended to provide guidance for determining if the Rule's housekeeping and release criteria are met. On challenge the TS addressed was the statistical interpretation of data sets with non-detected results, a topic for which no strong consensus exists. Among the many comments on the draft TS was a suggestion that certain of the statistical comparisons described in the TS could be better implemented if analytical results, even when below a reporting limit, were to be reported by analytical laboratories. See Appendix 1 for a review of terminology related to reporting limits. The Beryllium Health and Safety Committee (BHSC) formed a Sampling and Analysis Subcommittee (SAS) in 2003. The SAS established a working group on accreditation and reporting limits. By 2006 it had become evident that the issues extended to data reporting as a whole. The SAS proposed to the BHSC the formation of a Data Reporting Task Force (DRTF) to consider issues related to data reporting. The BHSC Board agreed, and requested that the DRTF generate a white paper, to be offered by the BHSC to potential interested parties such as the DOE policy office that is responsible for beryllium health and safety policy. It was noted that additional products could include detailed guidance and potentially a journal article in the future. The SAS proposed that DRTF membership represent the affected disciplines (chemists, industrial hygiene professionals and statisticians, and the DOE office that is responsible for beryllium health and safety policy). The BHSC Board decided that DRTF membership should come from DOE sites, since the focus would be on reporting in the context of the TS and the Rule. The DRTF came into existence in late 2006. The DRTF membership includes industrial hygienists, analytical chemists and laboratory managers, members of the regulatory and oversight community, and environmental statisticians. A first White Paper, ''Summary of Issues and Path Forward'', was reviewed by the BHSC in March 2007 and issued by the DRTF in June 2007. It describes the charter of the DRTF, introduces some basic terminology (reproduced here in Appendix 1), lays out the issues the DRTF is expected to address, and describes a path forward for the DRTF's work. This first White Paper is available through the BHSC web site. This White Paper presents recommendations developed by the DRTF following the process laid out in that first White Pap

MacQueen, D H

2007-10-10T23:59:59.000Z

439

Beryllium and Graphite High-Accuracy Total Cross-Section Measurements in the Energy Range from 24 to 900 keV  

E-Print Network [OSTI]

Beryllium and Graphite High-Accuracy Total Cross-Section Measurements in the Energy Range from 24 new measurements of the carbon and beryllium neutron total cross section in the energy range of 24 the measurement of the energy-dependent total cross section st ~Ei ! by applying Eq. ~1! for every TOF channel i

Danon, Yaron

440

Sensitive Analysis of Alkyl Alcohols as Decomposition Products of Alkyl Nitrites in Human Whole Blood and Urine by Headspace Capillary GC with Cryogenic Oven Trapping  

Science Journals Connector (OSTI)

......470-1192, Japan The abuse of alkyl nitrites is...oven trapping. | The abuse of alkyl nitrites is...Sensitivity and Specificity The abuse of alkyl nitrites is...abused by inhalation among young people for their aphrodisiac...common markets or by internet sales. The most popular......

Kanako Watanabe-Suzuki; Robert R. Lemmer; Hideki Nozawa; Osamu Suzuki; Akira Ishii

2003-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Sensitive Analysis of Alkyl Alcohols as Decomposition Products of Alkyl Nitrites in Human Whole Blood and Urine by Headspace Capillary GC with Cryogenic Oven Trapping  

Science Journals Connector (OSTI)

......cryogenic oven trapping. | The abuse of alkyl nitrites is becoming...Sensitivity and Specificity The abuse of alkyl nitrites is becoming...them at common markets or by internet sales. The most popular alkyl...the detection of alkyl nitrite abuse in forensic science practice......

Kanako Watanabe-Suzuki; Robert R. Lemmer; Hideki Nozawa; Osamu Suzuki; Akira Ishii

2003-02-01T23:59:59.000Z

442

Beryllium Impregnation of Uranium Fuel: Thermal Modeling of Cylindrical Objects for Efficiency Evaluation  

E-Print Network [OSTI]

, the graphs created need to be compared as shown below in figure 3.2. The goal of the new additive is to have a better heat conductivity throughout the fuel pellet in a reactor core leading to more power output from the fuel and better burnup. To see... conductivity. This leads to the temperature of the fuel to increase in order to produce the same power output as a higher thermal conductivity material. The Beryllium Oxide(BeO) that is to be used in this experiment is such a material that can raise...

Lynn, Nicholas

2011-08-04T23:59:59.000Z

443

Observation and Interpretation of the Auger Electron Spectrum from Clean Beryllium  

Science Journals Connector (OSTI)

Auger electron peaks at 92 and 104 eV have been observed in the derivative dN(E)dE of the secondary-electron energy distribution N(E) from clean polycrystalline beryllium. Existence of these two Auger transitions can be explained in terms of conduction-band electrons with s character and p character and is consistent with theoretical calculations. The observed Auger transitions can be expressed as 1s2s2s (92 eV) and 1s2p2p (104 eV).

Ronald G. Musket and R. J. Fortner

1971-01-11T23:59:59.000Z

444

Constraining Low-Energy Proton Capture on Beryllium-7 through Charge Radius Measurements  

E-Print Network [OSTI]

In this paper, we point out that a measurement of the charge radius of Boron-8 provides indirect access to the S-factor for radiative proton capture on Beryllium-7 at low energies. We use leading-order halo effective field theory to explore this correlation and we give a relation between the charge radius and the S-factor. Furthermore, we present important technical aspects relevant to the renormalization of pointlike P-wave interactions in the presence of a repulsive Coulomb interaction.

Emil Ryberg; Christian Forssén; H. -W. Hammer; Lucas Platter

2014-06-26T23:59:59.000Z

445

Broadly tunable chromium-doped beryllium aluminate lasers and operation thereof  

SciTech Connect (OSTI)

A high power, broadly wavelength-tunable laser is provided which comprises as the laser medium particular single crystals of chromium-doped beryllium aluminate (BeAl/sub 2/O/sub 4/:Cr/sup 3 +/) having the chrysoberyl structure, means for exciting the laser medium and tuning means. The laser may be operated over a broad temperature range from cryogenic temperatures to elevated temperatures. Elevated temperatures are preferred, however, since they result in higher laser gain. Emission is in a spectral range from red to infrared, and the laser is useful in the fields of defense, communications, isotope separation, photochemistry, etc.

Jenssen, H.P.; Morris, R.C.; Peterson, O.G.; Walling, J.C.

1981-06-09T23:59:59.000Z

446

Comparison of 3 MeV C{sup +} Ion-Irradiation Effects between The Nuclear Graphites made of Pitch and Petroleum Cokes  

SciTech Connect (OSTI)

Currently, all the commercially available nuclear graphite grades are being made from two different cokes, i.e., petroleum coke or coal-tar pitch coke, and a coal-tar pitch binder. Of these, since the coke composes most of the graphite volume, i.e., > 70 %, it is understood that a physical, chemical, thermal, and mechanical property as well as an irradiation-induced property change will be strongly dependent on the type of coke. To obtain first-hand information on the effects of the coke type, i.e., petroleum or pitch, on the irradiation sensitivity of graphite, specimens made of IG-110 of petroleum coke and IG-430 of pitch coke were irradiated up to {approx} 19 dpa by 3 MeV C{sup +} at room temperature, and the irradiation-induced changes in the hardness, Young's modulus, Raman spectrum, and oxidation properties were characterized. Results of the TEM show that the size and density of the Mrozowski cracks appeared to be far larger and higher in the IG-110 than the IG-430. Results of the hardness test revealed a slightly higher increase in the IG-430 than the IG-110 by around 10 dpa, and the Raman spectrum measurement showed a higher (FWHM){sub D}/(FWHM){sub G} value for IG-430 for 0.02 {approx} 0.25 dpa. Both the hardness and Raman measurement may imply a higher irradiation sensitivity of the IG-430 than the IG-110. Results of the Young's modulus measurements showed a large data scattering, which prevented us from estimating the differences between the grades. Oxidation experiments using a TG-DTA under a flow of dry air/He = 2.5 % (flow rate: 40 CC/min) at 750 and 1000 deg C show that the IG-110 of the petroleum coke exhibits a far higher oxidation rate than the IG-430. The discrepancy between the oxidation rate of the two grades increased with an increase in the oxidation temperature and the dose. Oxidized surface pore area was larger for IG-110. Judging from the results obtained from the present experimental conditions, the irradiation sensitivity appeared to be dependent on the degree of graphitization (thus, the perfection of graphite structure), and the differences in the oxidation property of the grades appeared to be largely affected by the structure of the Mrozowski cracks. Differences in the size and density of the Mrozowski cracks between the grades were attributed to the differences in the thermal conductivity of the grades. (authors)

Se-Hwan, Chi; Gen-Chan, Kim; Jong-Hwa, Chang [Nuclear Hydrogen Development and Demonstration Project, Korea Atomic Energy Research Institute, P.O. Box 105, Yuseong, Daejeon (Korea, Republic of)

2006-07-01T23:59:59.000Z

447

Detection of natural oxidation of coking coal by TG-FTIR—mechanistic implications  

Science Journals Connector (OSTI)

The natural oxidation/weathering of coal continues to be a subject of interest both scientifically and industrially, in part due to the complexity of the molecular processes at hand as well as to the commercial implications involved. It is widely recognized that coking can be adversely affected by weathering whereas, combustion processes appear to be enhanced as result of oxidation. Combustion techniques are commonly used in the analysis of coal, and organic compounds in general, for the determination of elemental hydrogen, carbon and nitrogen. For oxygen, the method in common practice involves the determination by difference from directly determined values for moisture, ash, sulphur, hydrogen, carbon and nitrogen. This has led us to consider the use of thermogravimetry coupled to gas analysis by infrared spectroscopy (TG-FTIR) to measure organic oxygen in coal directly. Although this technique, developed by Solomon and coworkers, has been extensively used by our group and others, it appears not to have been considered for this particular purpose. Recently, we have shown that TG-FTIR is capable of measuring all the organic oxygen in both fresh and oxidized coal by simultaneous measurement of the three main oxygen-containing gases H2O, CO and CO2 evolved during rapid pyrolysis. This gives us a way of measuring quantitatively the oxygen introduced into the coal matrix during oxidation and at least a partial capability of establishing oxygen speciation. We have found, using TG-FTIR, that the early stages of coal oxidation results in the appearance of O-containing functional groups not present in the original coal. The nature of these functional groups is directly related to the oxidation reaction mechanism. These results will be presented and discussed in detail.

J.A. MacPhee; L. Giroux; J.-P. Charland; J.F. Gransden; J.T. Price

2004-01-01T23:59:59.000Z

448

A scanning electron microscope study on agglomeration in petroleum coke-fired FBC boilers  

Science Journals Connector (OSTI)

Ten samples originating from different boiler FBC systems burning petroleum coke and one laboratory sample were chosen to perform a study on the development, structure, and composition of deposits formed by agglomeration in various locations. The work focused on examination by scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis. The possibility of a contribution of liquid phases in the adherence to solid surfaces and in agglomeration was discussed and checks by SEM, EDX, and analysis by neutron activation were performed; no evidence could be found either for liquid phases or for any role of vanadium or alkaline element compounds. The agglomerations result from the continued sintering of CaSO4 particles until they build up a strong framework that is indefinitely extended, into which particles of different and complex compositions are bound, without contributing to the cohesion. Chemical sintering occurring by the sulphation of CaO into CaSO4 appears to be an important contribution while CaO is still available, but sintering also occurs by mass transfer mechanisms and continues after the depletion of CaO. Deposits formed in regions only reached by fly ash (convection section), and also in in-bed deposits, grow from particles <50 ?m, mostly in the range of 10 ?m or less. In regions collecting bed ash (e.g., J-valves), the deposit grows from the sintering together of particles on the order of 100–300 ?m (originally bed ash particles), which themselves appear as conglomerates of extensively sintered smaller particles.

J.V Iribarne; E.J Anthony; A Iribarne

2003-01-01T23:59:59.000Z

449

A new mechanism for FBC agglomeration and fouling when firing 100% petroleum coke  

SciTech Connect (OSTI)

In a preliminary study of the problem of agglomeration development in the petroleum coke combustion ashes, samples from different locations in a combustor from an industrial CFBC boiler were analyzed. Various oxides and calcium compounds of vanadium were found, in all cases, amounting to a total of 0.1--0.2% of V. These compounds do not accumulate (i.e. their concentration in the deposit does not increase) in the course of the FBC operation. The deposits show abnormally high conversion to CaSO{sub 4}, in some cases with very little content of free CaO, and a new mechanism of agglomeration similar to chemical reaction sintering is proposed. Different possible mechanisms leading to the formation of agglomerates were examined and the hypothesis that currently seems to best fit with the data is that the agglomeration phenomenon is due to a ``molecular cramming`` effect caused by the nearly quantitative conversion of the CaO to CaSO{sub 4}. While the absence of fuel derived ash, which would normally provide discontinuities in the deposits allowing them to break up, instead permits the buildup of massive monolithic deposits in various parts of the CFBC primary reactor loop. This explanation is also consistent with the ability of Mg compounds to mitigate the problem, but it suggests that the effect of these compounds is to prevent the buildup of the deposits by providing ``inert material`` rather than by capturing vanadium oxides as has heretofore been supposed. Further systematic investigations are planned to definitively rule out a vanadate capture mechanisms and to explore whether sulfidization as opposed to sulfation plays any part in the buildup of these deposits.

Anthony, E.J. [CANMET, Ottawa, Ontario (Canada). Natural Resources Canada; Iribarne, A.P.; Iribarne, J.V. [Univ. of Toronto, Ontario (Canada)

1995-12-31T23:59:59.000Z

450

Proposed beryllium metal bounding airborne release fractions (ARFs)/rates (ARRs) and respirable fractions (RFs) for DOE facility accidents analyses  

Science Journals Connector (OSTI)

Beryllium metal has special properties for nuclear applications and is used widely within the Department of Energy (DOE) complex. Beryllium is toxic and has the potential to cause health effects (sensitization and chronic beryllium disease) to workers. Due to the type of processing involving large quantities of beryllium metal and powders and potential for significant airborne release under accident conditions, a comprehensive hazard analysis is required by DOE in a safety analysis document that evaluates potential accidents that can cause beryllium releases to the workplace and public or to the environment. The goal of the safety analysis is to identify and evaluate hazards so that appropriate controls or safeguards can be specified to protect the workers and public from potential accidents. A hazard assessment is also required to comply with 10 CFR Part 850, Chronic Beryllium Disease Prevention Program (1999) to protect the workers. DOE safety analyses include a quantitative estimate of releases and downwind concentrations for purposes of hazard classification and determination of the need for additional hazards analysis, accident analysis, and risk assessments. There are no complex-wide accepted Airborne Release Fractions (ARFs) and Respirable Fractions (RFs) that can be used to evaluate the potential downwind consequences of releases of beryllium under various accident conditions (e.g., spill, fire, stress, explosion, etc.). The purpose is to recommend DOE complex-wide \\{ARFs\\} and \\{RFs\\} that can be used to evaluate the potential downwind consequences of accidents. This paper proposes various values for \\{ARFs\\} and \\{RFs\\} that are based on review of the published information and data on the oxidation and ignition behavior of beryllium metal encased in a thin coat of non-porous, adherent oxide (“blue oxide”); the typical form of this material found in DOE facilities. Information is also presented as a function of the morphology of the metal (i.e., large, coherent, pieces; turnings/swarfs; chips/powder; and dust) because the surface to volume ratio is an important factor in evaluating both the amount of beryllium released and the potential for ignition of the metal that may increase the amount of release significantly. Guidance is also provided for the use of the DOE-HDBK-3010-94, Airborne Release Fractions/Rates and Respirable Fraction for Nonreactor Nuclear Facilities, values for oxide releases that result in a more liberal, allowable limiting airborne concentration for determining consequences and hazard classification of the facility. Detailed explanations of the proposed ARF/RF values for the various beryllium metal forms (large coherent pieces, chips/powder, turning/swarfs from processing, and dust) and other aspects of beryllium are provided in a report by Mishima et al. (April 2005). A short version of this report and a summary of the ARF/RF values are presented here.

Jofu Mishima; Terry L. Foppe; J.C. Laul

2008-01-01T23:59:59.000Z

451

Effect of Pyrolysis and CO2 Gasification Pressure on the Surface Area and Pore Size Distribution of Petroleum Coke  

Science Journals Connector (OSTI)

Normalization of the reaction rate by the surface area indicated that the effect of the pressure on the physical characteristics of the petcoke was the main but not sole factor in the change of the reaction rate with the gasification pressure. ... As refiners are pushed toward producing cleaner transportation fuels from poorer quality crudes, the production of petroleum coke (petcoke) is increasing as a byproduct of heavy oil upgrading units. ... (1, 2) The majority of petcoke produced in Canada is currently stockpiled on the site of the plant. ...

Maryam Malekshahian; Josephine M. Hill

2011-10-03T23:59:59.000Z

452

Characteristics of a commercially aged Ni-Mo/Al2O3 hydrotreating catalyst: component distribution, nature of coke and effects of regeneration  

SciTech Connect (OSTI)

Information concerning the morphology and behavior of active components on commercially aged catalyst, the effects of regeneration conditions on activity, and insights into the nature of coke and contaminant metal deposits could lead to improved catalysts and operating conditions , yielding significant economic returns. Spent Ni-Mo/Al2O3 hydrotreating catalyst from a commercial hydrotreater was examined using TGA, SEM, STEM, XPS, and a microreactor. Information concerning intraparticle distributions of active components, characteristics of the coke and metal deposits, and catalytic activity for fresh, spent and regenerated catalyst was used to draw general conclusions concerning hydrotreating catalyst deactivation. It was found that catalytic activity was reduced and the nature of the hydrogenation function was altered due to bulk migration and agglomeration of molybdenum. This process was found to be accelerated by high-temperature regeneration. Results also indicated that iron deposits might catalyze formation of coke. Tentative generalizations and suggestions on improved reactor operation are presented.

Bogdanor, J.M.

1984-01-01T23:59:59.000Z

453

Procedure for calibration of a portable, real-time beryllium aerosol monitor based on laser-induced breakdown spectroscopy  

E-Print Network [OSTI]

Spectroscopy (LIPS), is an analytical method whereby atmospheric components and contaminants may be analyzed in real-time or near real-time directly in the workplace. A transportable beryllium air monitor system based on LIBS has been developed at the Los...

Killough, David Thomas

2012-06-07T23:59:59.000Z

454

AN INTERSTELLAR ORIGIN FOR THE BERYLLIUM 10 IN CALCIUM-RICH, ALUMINUM-RICH INCLUSIONS S. J. Desch1  

E-Print Network [OSTI]

, Brooklyn, NY 11235; and American Museum of Natural History, Department of Earth and Planetary Sciences, Central Park West at 79th Street, New York, NY 10024; and Rutgers University, Department of Geological into calcium-rich, aluminum-rich inclusions (CAIs) at the birth of our solar system. Beryllium 10 is unique

Connolly Jr, Harold C.

455

Experimental Investigation of Natural Coke Steam Gasification in a Bench-Scale Fluidized Bed: Influences of Temperature and Oxygen Flow Rate  

Science Journals Connector (OSTI)

However, natural coke was restricted in application and research due to its hot burst, difficult ignition, and abradability. ... disordering as a cause is now a real possibility on the basis of correlated optical and x-ray diffraction data from samples analyzed from within a thermal aureole of a Tertiary dyke emplaced in Permian coal-bearing strata. ... The thermal characteristics of natural coke steam gasification in a fluidized bed were three-dimensionally (3D) simulated based on the computational fluid dynamics (CFD) method using Fluent code. ...

Wen-guo Xiang; Chang-sui Zhao; Ke-liang Pang

2009-01-05T23:59:59.000Z

456

Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China  

SciTech Connect (OSTI)

A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

2006-08-01T23:59:59.000Z

457

In{sub 2}O{sub 3} microcrystals obtained from rapid calcination in domestic microwave oven  

SciTech Connect (OSTI)

The simple way to prepare In{sub 2}O{sub 3} microcrystals is reported in this paper. The precursor, In(OH){sub 3} microstructures, were obtained using the Microwave-Assisted Hydrothermal (MAH) Method. By annealing as-prepared In(OH){sub 3} precursor at 500 {sup o}C for 5 min in a domestic microwave oven (MO), In{sub 2}O{sub 3} microcrystals were prepared, inheriting the morphology of their precursor while still slightly distorted and collapsed due to the In(OH){sub 3} dehydration process which was studied by thermal analysis. The In(OH){sub 3} and In{sub 2}O{sub 3} were characterized using powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and Raman spectroscopy. These techniques confirm the chemical dehydration of In(OH){sub 3} and the formation of In{sub 2}O{sub 3} powders. The domestic MO promotes a rapid structural organization as compared with a CF (conventional furnace). The MAH method and the subsequent annealing in a domestic MO were shown to be a low cost route for the production of In{sub 2}O{sub 3}, with the advantages of lower temperature and smaller time.

Motta, F.V., E-mail: fabiana@liec.ufscar.br [LIEC, IQ, UNESP, Rua Francisco Degni s/n, CEP 14801-907 Araraquara, SP (Brazil); Lima, R.C. [IQ, UFU, Av. Joao Naves de Avila, 2121, CEP 38400-902 Uberlandia, MG (Brazil)] [IQ, UFU, Av. Joao Naves de Avila, 2121, CEP 38400-902 Uberlandia, MG (Brazil); Marques, A.P.A.; Leite, E.R. [LIEC, DQ, UFSCar, Via Washington Luiz, km 235, CEP 13565-905 Sao Carlos, SP (Brazil)] [LIEC, DQ, UFSCar, Via Washington Luiz, km 235, CEP 13565-905 Sao Carlos, SP (Brazil); Varela, J.A.; Longo, E. [LIEC, IQ, UNESP, Rua Francisco Degni s/n, CEP 14801-907 Araraquara, SP (Brazil)] [LIEC, IQ, UNESP, Rua Francisco Degni s/n, CEP 14801-907 Araraquara, SP (Brazil)

2010-11-15T23:59:59.000Z

458

The effect of varying oven temperatures and residence times on thermal desorption of n-hexane and 1-hexene from diffusive organic vapor dosimeters  

E-Print Network [OSTI]

of suitable adsorbent medium, such as activated charcoal or silica gel. This method proved highly reliable, in that a relatively constant sampling flowrate could be held for as long as eight hours. However, the method also presented The citations used... referred to as thermal desorption has gained in- creased attention. This method consists of heating the ad- sorbent medium in an oven to release the adsorbed com- pounds from the collection medium. A carrier gas is passed through the heated tube...

Steele, Kenneth Garnett

2012-06-07T23:59:59.000Z

459

DOE-STD-1187-2005; Beryllium-Associated Worker Registry Data Collection and Management Guidance  

Broader source: Energy.gov (indexed) [DOE]

5 5 May 2005 DOE TECHNICAL STANDARD Beryllium-Associated Worker Registry Data Collection and Management Guidance U.S. Department of Energy AREA SAFT Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited NOT MEASUREMENT SENSITIVE DOE-STD-1187-2005 ii FOREWORD 1. Use of this standard is not mandatory. Users should review the document and determine if it meets their purpose. 2. Comments (recommendations, additions, and deletions) that may be of use in improving this document should be addressed to: U.S. Department of Energy, Office of Health, c/o Paul Wambach, EH-53/270 Corporate Square Building, 1000 Independence Avenue, SW, Washington, DC 20585-0270. 3. This standard was developed through a consensus process by staff operating the DOE

460

Scattering of X-Rays by Cold-Worked and by Annealed Beryllium  

Science Journals Connector (OSTI)

The intensities of reflection of Mo K?-radiation by important crystallographic planes in powdered beryllium have been measured by an ionization method under the following conditions: (I) cold-worked particles of average diameter about 3×(10)-3 cm; (II) the same after ½ hr. at 800°C; (III) cold-worked particles of average diameter about (10)-2 cm; (IV) the same after 1 hr. at 950°C. In (II) and especially in (IV) cold-working strains should have been relieved. The atomic structure factors derived from these data show no appreciable change with annealing and further show that Be crystals are rather imperfect. The mass absorption coefficient is found to be 0.26 in good agreement with a value computed according to Compton's empirical formula.

James E. Boyd

1934-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"  

U.S. Energy Information Administration (EIA) Indexed Site

2 Relative Standard Errors for Table 7.2;" 2 Relative Standard Errors for Table 7.2;" " Unit: Percents." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components" " "," ",,,,,,,,,,,,,"Total",,,,,,,,,,,,,,,,,,,,,,,"Wood Residues",,,," " " "," "," ",,,,,"Bituminous",,,,,,"Electricity","Diesel Fuel",,,,,,"Motor",,,,,,,"Natural Gas",,,"Steam",,,," ",,,"and","Wood-Related","All"

462

,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"  

U.S. Energy Information Administration (EIA) Indexed Site

Relative Standard Errors for Table 7.1;" Relative Standard Errors for Table 7.1;" " Unit: Percents." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components" " "," ",,,,,,,,,,,,,"Total",,,,,,,,,,,,,,,,,,,,,,,"Wood Residues",,,," " " "," "," ",,,,,"Bituminous",,,,,,"Electricity","Diesel Fuel",,,,,,"Motor",,,,,,,"Natural Gas",,,"Steam",,,," ",,,"and","Wood-Related","All"

463

Supplementary radiological and beryllium characterization of the facility at 425 Peek Street, Schenectady, New York  

SciTech Connect (OSTI)

At the request of the Office of Naval Reactors through the Office of Remedial Action and Waste Technology, a radiological survey of the Peek Street industrial facility, the adjacent state-owned bike path, and two nearby residential properties was conducted by Oak Ridge National Laboratory (ORNL) in November 1989. The results indicated small isolated areas that exceeded DOE guidelines. These areas totaled approximately 0.2 m{sup 2} of floor area and approximately 3 m{sup 2} of wall area inside the building, and two small areas totaling approximately 5 m{sup 2} outside the building. A small section of one of these areas extended beyond the fence on the east side of the industrial property onto the state-owned property. No residual radioactive material or elevated radiation levels were detected on any portion of the paved section of the bike path or the residential properties adjacent to the site. Because the elevated radiation levels were localized and limited in extent, any credible use scenario, including current use conditions, indicated that no significant radiation exposures would accrue to individuals frequenting the area. Samples were also analyzed for elemental beryllium since that material had formerly been used at the site. In conjunction with the planned remediation at the facility, a supplementary characterization survey was performed to further define the areas containing beryllium in excess of the identified guidelines. Additional radiological characterization of Ra-226, Th-232, and U-238 was also performed in areas that were largely inaccessible prior to the remediation efforts.

Foley, R.D.; Allred, J.F.; Carrier, R.F.

1994-10-01T23:59:59.000Z

464

Neutron flux and energy characterization of a plutonium-beryllium isotopic neutron source by Monte Carlo simulation with verification by neutron activation analysis.  

E-Print Network [OSTI]

??The purpose of this research was to characterize the neutron energy distribution and flux emitted from the UNLV plutonium-beryllium source, serial number MRC-N-W PuBe 453.… (more)

Harvey, Zachary R

2010-01-01T23:59:59.000Z

465

Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy  

SciTech Connect (OSTI)

Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

2009-03-15T23:59:59.000Z

466

Worker Safety and Health Enforcement Letter issued to Los Alamos National Security, LLC, related to Worker Beryllium Exposure during Machining at the Los Alamos National Laboratorys Beryllium Technology Facility, May 29, 2013 (WEL-2013-01)  

Broader source: Energy.gov (indexed) [DOE]

29, 2013 29, 2013 Dr. Charles F. McMillan, President Los Alamos National Security, LLC Los Alamos National Laboratory Mailstop A 100, Drop Point 03140071S Bikini Atoll Road, TA-3 Los Alamos, New Mexico 87454 WEL-2013-01 Dear Dr. McMillan: The Office of Health, Safety and Security's Office of Enforcement and Oversight evaluated the circumstances surrounding a work evolution performed at Los Alamos National Laboratory (LANL) Technical Area 3, Building 141, Beryllium Technology Facility (BTF), on July 11, 2012. The work evolution resulted in a worker exposure to beryllium in excess of the Department of Energy (DOE) action level of 0.2 micrograms per cubic meter for an 8-hour, time-weighted average. Los Alamos National Security, LLC (LANS), which manages and

467

Calculated and measured gas formation in beryllium samples irradiated in the high flux materials testing reactor BR2  

SciTech Connect (OSTI)

Beryllium samples have been irradiated in BR2, the materials testing reactor of the Nuclear Research Centre SCK/CEN at Mol, Belgium, up to fission fluence values of 5.2 10{sup 22} n/cm{sup 2} at low temperature. The gas formation (helium, tritium), as measured by SCK/CEN, as well as the induced swelling of the beryllium samples and the enhancement of the swelling due to annealing have been presented at the 17th SOFT Conference (Rome, 14--18 Sept., 1992). Since this conference, helium measurements on the same samples have been carried out at RI and calculations of the gas production have been performed, taking into account the various formation schemes. The experimental results from SCK/CEN and from RI are compared with the calculated gas formations.

De Raedt, C.M.; Sannen, L.F.; Vanmechelen, P.J. [SCK/CEN, Mol (Belgium); Oliver, B.M. [Rockwell International Corp., Canoga Park, CA (United States). Rocketdyne Div.

1994-12-31T23:59:59.000Z

468

Office of Health, Safety and Security Follow-up Review of the Hanford Site Chronic Beryllium Disease Prevention Program  

Broader source: Energy.gov (indexed) [DOE]

Follow-up Review of the Follow-up Review of the Hanford Site Chronic Beryllium Disease Prevention Program May 2011 June 2011 Office of Safety and Emergency Management Evaluations Office of Health, Safety and Security U.S. Department of Energy TABLE OF CONTENTS 1.0 Purpose ................................................................................................................................... 1 2.0 Background ............................................................................................................................ 1 3.0 Scope ...................................................................................................................................... 1 4.0 Results .................................................................................................................................... 1

469

Supplement of Atmos. Chem. Phys., 14, 65716603, 2014 http://www.atmos-chem-phys.net/14/6571/2014/  

E-Print Network [OSTI]

for coal-charging process 0 0 0 0 10 10 0 FGD for coke oven gas 0 0 0 0 10 10 0 Combination[1] BAU[2]/PC[2] 2005 2010 2020 2030 2020 2030 2030 Sintering FGD 0 10 20 40 95 100 100 Coke oven FGD 100 Hot rolling ESP 0 0 0 0 70 95 100 Cold rolling HED 0 0 0 0 70 95 100 Coke oven WET 100 100 100 100

Pierce, Jeffrey

470

Massachusetts Beryllium Screening Program for Former Workers of Wyman-Gordon, Norton Abrasives, and MIT/Nuclear Metals  

SciTech Connect (OSTI)

The overall objective of this project was to provide medical screening to former workers of Wyman-Gordon Company, Norton Abrasives, and MIT/Nuclear Metals (NMI) in order to prevent and minimize the health impact of diseases caused by site related workplace exposures to beryllium. The program was developed in response to a request by the U.S. Department of Energy (DOE) that had been authorized by Congress in Section 3162 of the 1993 Defense Authorization Act, urging the DOE to â??carry out a program for the identification and ongoing evaluation of current and former DOE employees who are subjected to significant health risks during such employment." This program, funded by the DOE, was an amendment to the medical surveillance program for former DOE workers at the Nevada Test Site (NTS). This programâ??s scope included workers who had worked for organizations that provided beryllium products or materials to the DOE as part of their nuclear weapons program. These organizations have been identified as Beryllium Vendors.

Pepper, L.D.

2008-05-21T23:59:59.000Z

471

7, 14791506, 2007 apportionment of the  

E-Print Network [OSTI]

, coal residential, coke oven, coal power plant, biomass burning, natural gas (NG) combustion. The major showed distinct seasonal variations. High contributions of biomass burning and coal (residential and coke is the world's largest coal consumption region (IEA, 2006). Thu

Paris-Sud XI, Université de

472

Lesson 9 - Solar Ovens  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3: Earth Systems Science Kindergarten: Concepts and skills students master: 1. The Sun provides heat and light to Earth 1 st grade: Concepts and skills students master: 1....

473

Selection of Russian Plutonium Beryllium Sources for Inclusion in the Nuclear Mateirals Information Program Archive  

SciTech Connect (OSTI)

Throughout the 1960s and 1970s, the former Soviet Union produced and exported Plutonium-Beryllium (PuBe) neutron sources to various Eastern European countries. The Russian sources consist of an intermetallic compound of plutonium and beryllium encapsulated in an inner welded, sealed capsule and consisting of a body and one or more covers. The amount of plutonium in the sources ranges from 0.002 g up to 15 g. A portion of the sources was originally exported to East Germany. A portion of these sources were acquired by Los Alamos National Laboratory (LANL) in the late 1990s for destruction in the Offsite Source Recovery Program. When the OSRP was canceled, the remaining 88 PuBe neutron sources were packaged and stored in a 55-gal drum at T A-55. This storage configuration is no longer acceptable for PuBe sources, and the sources must either be repackaged or disposed of. Repackaging would place the sources into Hagan container, and depending on the dose rates, some sources may be packaged individually increasing the footprint and cost of storage. In addition, each source will be subject to leak-checking every six months. Leaks have already been detected in some of the sources, and due to the age of these sources, it is likely that additional leaks may be detected over time, which will increase the overall complexity of handling and storage. Therefore, it was decided that the sources would be disposed of at the Waste Isolation Pilot Plant (WIPP) due to the cost and labor associated with continued storage at TA-55. However, the plutonium in the sources is of Russian origin and needs to be preserved for research purposes. Therefore, it is important that a representative sample of the sources retained and archived for future studies. This report describes the criteria used to obtain a representative sample of the sources. Nine Russian PuBe neutron sources have been selected out of a collection of 77 sources for inclusion in the NMIP archive. Selection criteria were developed so that the largest sources that are representative of the collection are included. One representative source was chosen for every 20 sources in the collection, and effort was made to preserve sources unique to the collection. In total, four representative sources and five unique sources were selected for the archive. The archive samples contain 40 grams of plutonium with an isotopic composition similar to that of weapon grade material and three grams of plutonium with an isotopic composition similar to that of reactor grade plutonium.

Narlesky, Joshua E [Los Alamos National Laboratory; Padilla, Dennis D [Los Alamos National Laboratory; Watts, Joe [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

474

Co-gasification of Biomass and Non-biomass Feedstocks: Synergistic and Inhibition Effects of Switchgrass Mixed with Sub-bituminous Coal and Fluid Coke During CO2 Gasification  

Science Journals Connector (OSTI)

Co-gasification of biomass, namely, switchgrass, with coal and fluid coke was performed to investigate the availability of the gasification catalysts to the mixed feedstock, especially alkali and alkaline earth elements, naturally present on switchgrass. ...

Rozita Habibi; Jan Kopyscinski; Mohammad S. Masnadi; Jill Lam; John R. Grace; Charles A. Mims; Josephine M. Hill

2012-11-21T23:59:59.000Z

475

brwtp-icoke | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 Industrial Carbon Capture and Storage Clean Coal Power Initiative Power Plant Improvement Initiative Clean Coal Technology Demonstration Program FutureGen Innovative Coke Oven...

476

Further investigation of the impact of the co-combustion of tire-derived fuel and petroleum coke on the petrology and chemistry of coal combustion products  

SciTech Connect (OSTI)

A Kentucky cyclone-fired unit burns coal and tire-derived fuel, sometimes in combination with petroleum coke. A parallel pulverized combustion (pc) unit at the same plant burns the same coal, without the added fuels. The petrology, chemistry, and sulfur isotope distribution in the fuel and resulting combustion products was investigated for several configurations of the fuel blend. Zinc and Cd in the combustion products are primarily contributed from the tire-derived fuel, the V and Ni are primarily from the petroleum coke, and the As and Hg are probably largely from the coal. The sulfur isotope distribution in the cyclone unit is complicated due to the varying fuel sources. The electrostatic precipitator (ESP) array in the pc unit shows a subtle trend towards heavier S isotopic ratios in the cooler end of the ESP.

Hower, J.C.; Robertson, J.D.; Elswick, E.R.; Roberts, J.M.; Brandsteder, K.; Trimble, A.S.; Mardon, S.M. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

2007-07-01T23:59:59.000Z

477

Optimized beryllium target design for indirectly driven inertial confinement fusion experiments on the National Ignition Facility  

SciTech Connect (OSTI)

For indirect drive inertial confinement fusion, Beryllium (Be) ablators offer a number of important advantages as compared with other ablator materials, e.g., plastic and high density carbon. In particular, the low opacity and relatively high density of Be lead to higher rocket efficiencies giving a higher fuel implosion velocity for a given X-ray drive; and to higher ablation velocities providing more ablative stabilization and reducing the effect of hydrodynamic instabilities on the implosion performance. Be ablator advantages provide a larger target design optimization space and can significantly improve the National Ignition Facility (NIF) [J. D. Lindl et al., Phys. Plasmas 11, 339 (2004)] ignition margin. Herein, we summarize the Be advantages, briefly review NIF Be target history, and present a modern, optimized, low adiabat, Revision 6 NIF Be target design. This design takes advantage of knowledge gained from recent NIF experiments, including more realistic levels of laser-plasma energy backscatter, degraded hohlraum-capsule coupling, and the presence of cross-beam energy transfer.

Simakov, Andrei N., E-mail: simakov@lanl.gov; Wilson, Douglas C.; Yi, Sunghwan A.; Kline, John L.; Batha, Steven H. [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico 87545 (United States); Clark, Daniel S.; Milovich, Jose L.; Salmonson, Jay D. [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States)] [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States)

2014-02-15T23:59:59.000Z

478

Packaging and Disposal of a Radium-beryllium Source using Depleted Uranium Polyethylene Composite Shielding  

SciTech Connect (OSTI)

Two, 111-GBq (3 Curie) radium-beryllium (RaBe) sources were in underground storage at the Brookhaven National Laboratory (BNL) since 1988. These sources originated from the Princeton Plasma Physics Laboratory (PPPL) where they were used to calibrate neutron detection diagnostics. In 1999, PPPL and BNL began a collaborative effort to expand the use of an innovative pilot-scale technology and bring it to full-scale deployment to shield these sources for eventual transport and burial at the Hanford Burial site. The transport/disposal container was constructed of depleted uranium oxide encapsulated in polyethylene to provide suitable shielding for both gamma and neutron radiation. This new material can be produced from recycled waste products (depleted uranium and polyethylene), is inexpensive, and can be disposed with the waste, unlike conventional lead containers, thus reducing exposure time for workers. This paper will provide calculations and information that led to the initial design of the shielding. We will also describe the production-scale processing of the container, cost, schedule, logistics, and many unforeseen challenges that eventually resulted in the successful fabrication and deployment of this shield. We will conclude with a description of the final configuration of the shielding container and shipping package along with recommendations for future shielding designs.

Keith Rule; Paul Kalb; Pete Kwaschyn

2003-02-11T23:59:59.000Z

479

Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry  

SciTech Connect (OSTI)

High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

2005-12-01T23:59:59.000Z

480

Effects of polymerization and briquetting parameters on the tensile strength of briquettes formed from coal coke and aniline-formaldehyde resin  

SciTech Connect (OSTI)

In this work, the utilization of aniline (C{sub 6}H{sub 7}N) formaldehyde (HCHO) resins as a binding agent of coke briquetting was investigated. Aniline (AN) formaldehyde (F) resins are a family of thermoplastics synthesized by condensing AN and F in an acid solution exhibiting high dielectric strength. The tensile strength sharply increases as the ratio of F to AN from 0.5 to 1.6, and it reaches the highest values between 1.6 and 2.2 F/AN ratio; it then slightly decreases. The highest tensile strength of F-AN resin-coke briquette (23.66 MN/m{sup 2}) was obtained from the run with 1.5 of F/AN ratio by using (NH4){sub 2}S{sub 2}O{sub 8} catalyst at 310 K briquetting temperature. The tensile strength of F-AN resin-coke briquette slightly decreased with increasing the catalyst percent to 0.10%, and then it sharply decreased to zero with increasing the catalyst percent to 0.2%. The effect of pH on the tensile strength is irregular. As the pH of the mixture increases from 9.0 to 9.2, the tensile strength shows a sharp increase, and the curve reaches a plateau value between pH 9.3 and 9.9; then the tensile strength shows a slight increase after pH = 9.9.

Demirbas, A.; Simsek, T. [Selcuk University, Konya (Turkey)

2006-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "beryllium coke oven" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Study on one-dimensional steady combustion of highly densified biomass briquette (bio-coke) in air flow  

Science Journals Connector (OSTI)

Abstract Combustion experiments on cylindrical bio-coke (BIC), a highly densified biomass briquette, have been conducted to observe whether quasi-one-dimensional steady combustion can be attained in room temperature air flow. In the experiments, the air flow velocity was the main test condition and the fuel consumption rate when the bottom surface of the BIC sample burned was evaluated as the regression rate of the combustion zone at the bottom surface. In addition, one-dimensional calculations based on an energy equation at the combustion zone were conducted to understand the mechanism that results in steady combustion and predict the effect of water and volatile matter content in BIC on the extinction limit. The results showed that steady combustion of the BIC sample could be attained in 4.67 m/s or more, and, in contrast, extinction was observed in 3.82 m/s or less. The critical regression rate explained by the combustion zone temperature was shown, and the reason combustion becomes unsteady could be explained by the energy balance at the combustion zone. Though the main reason for extinction was radiation heat loss, the heat loss by water and volatile matter was not negligible. Therefore, the effect of water and volatile matter content on steady combustion must be considered.

Takero Nakahara; Hui Yan; Hiroyuki Ito; Osamu Fujita

2014-01-01T23:59:59.000Z

482

VALIDATION OF ANALYTICAL METHODS AND INSTRUMENTATION FOR BERYLLIUM MEASUREMENT: REVIEW AND SUMMARY OF AVAILABLE GUIDES, PROCEDURES, AND PROTOCOLS  

SciTech Connect (OSTI)

Method validation is the process of evaluating whether an analytical method is acceptable for its intended purpose. For pharmaceutical methods, guidelines from the United States Pharmacopeia (USP), International Conference on Harmonisation (ICH), and the United States Food and Drug Administration (USFDA) provide a framework for performing such valications. In general, methods for regulatory compliance must include studies on specificity, linearity, accuracy, precision, range, detection limit, quantitation limit, and robustness. Elements of these guidelines are readily adapted to the issue of validation for beryllium sampling and analysis. This document provides a listing of available sources which can be used to validate analytical methods and/or instrumentation for beryllium determination. A literature review was conducted of available standard methods and publications used for method validation and/or quality control. A comprehensive listing of the articles, papers and books reviewed is given in the Appendix. Available validation documents and guides are listed therein; each has a brief description of application and use. In the referenced sources, there are varying approches to validation and varying descriptions of the valication process at different stages in method development. This discussion focuses on valication and verification of fully developed methods and instrumentation that have been offered up for use or approval by other laboratories or official consensus bodies such as ASTM International, the International Standards Organization (ISO) and the Association of Official Analytical Chemists (AOAC). This review was conducted as part of a collaborative effort to investigate and improve the state of validation for measuring beryllium in the workplace and the environment. Documents and publications from the United States and Europe are included. Unless otherwise specified, all referenced documents were published in English.

Ekechukwu, A

2009-05-27T23:59:59.000Z

483

Dynamic response of materials on subnanosecond time scales, and beryllium properties for inertial confinement fusion  

SciTech Connect (OSTI)

During the past few years, substantial progress has been made in developing experimental techniques capable of investigating the response of materials to dynamic loading on nanosecond time scales and shorter, with multiple diagnostics probing different aspects of the behavior. These relatively short time scales are scientifically interesting because plastic flow and phase changes in common materials with simple crystal structures--such as iron--may be suppressed, allowing unusual states to be induced and the dynamics of plasticity and polymorphism to be explored. Loading by laser-induced ablation can be particularly convenient: this technique has been used to impart shocks and isentropic compression waves from {approx}1 to 200 GPa in a range of elements and alloys, with diagnostics including line imaging surface velocimetry, surface displacement (framed area imaging), x-ray diffraction (single crystal and polycrystal), ellipsometry, and Raman spectroscopy. A major motivation has been the study of the properties of beryllium under conditions relevant to the fuel capsule in inertial confinement fusion: magnetically driven shock and isentropic compression shots at Z were used to investigate the equation of state and shock melting characteristics, complemented by laser ablation experiments to investigate plasticity and heterogeneous response from the polycrystalline microstructure. These results will help to constrain acceptable tolerances on manufacturing, and possible loading paths, for inertial fusion ignition experiments at the National Ignition Facility. Laser-based techniques are being developed further for future material dynamics experiments, where it should be possible to obtain high quality data on strength and phase changes up to at least 1 TPa.

Swift, Damian C.; Tierney, Thomas E.; Luo Shengnian; Paisley, Dennis L.; Kyrala, George A.; Hauer, Allan; Greenfield, Scott R.; Koskelo, Aaron C.; McClellan, Kenneth J.; Lorenzana, Hector E.; Kalantar, Daniel; Remington, Bruce A.; Peralta, Pedro; Loomis, Eric [Los Alamos National Laboratory, MS E526, Los Alamos, New Mexico 87545 (United States); Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550 (United States); Arizona State University, Tempe, Arizona 85287 (United States)

2005-05-15T23:59:59.000Z

484

Environmental radiation monitoring plan for depleted uranium and beryllium areas, Yuma Proving Ground  

SciTech Connect (OSTI)

This Environmental Radiation Monitoring Plan (ERM) discusses sampling soils, vegetation, and biota for depleted uranium (DU) and beryllium (Be) at Yuma Proving Ground (YPG). The existing ERM plan was used and modified to more adequately assess the potential of DU and Be migration through the YPG ecosystem. The potential pathways for DU and Be migration are discussed and include soil to vegetation, soil to animals, vegetation to animals, animals to animals, and animals to man. Sample collection will show DU deposition and will be used to estimate DU migration. The number of samples from each area varies and depends on if the firing range of interest is currently used for DU testing (GP 17A) or if the range is not used currently for DU testing (GP 20). Twenty to thirty-five individual mammals or lizards will be sampled from each transect. Air samples and samples of dust in the air fall will be collected in three locations in the active ranges. Thirty to forty-five sediment samples will be collected from different locations in the arroys near the impact areas. DU and Be sampling in the Hard Impact and Soft Impact areas changed only slightly from the existing ERM. The modifications are changes in sample locations, addition of two sediment transport locations, addition of vegetation samples, mammal samples, and air sampling from three to five positions on the impact areas. Analysis of samples for DU or total U by inductively-coupled mass spectroscopy (ICP/MS), cc spectroscopy, neutron activation analysis (NAA), and kinetic phosphorimetric analysis (KPA) are discussed, and analysis for Be by ICP/MS are recommended. Acquiring total U (no isotope data) from a large number of samples and analysis of those samples with relatively high total U concentrations results in fewer isotopic identifications but more information on U distribution. From previous studies, total U concentrations greater than about 3 times natural background are usually DU by isotopic confirmation.

Ebinger, M.H.; Hansen, W.R.

1994-05-11T23:59:59.000Z