Sample records for beryllium coke oven

  1. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

    1995-12-01T23:59:59.000Z

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  2. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany). Inst. for Cokemaking and Fuel Technology; Hofherr, K. [Thyssen Stahl AG, Duisburg (Germany)

    1995-12-01T23:59:59.000Z

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  3. Factors affecting coking pressures in tall coke ovens

    SciTech Connect (OSTI)

    Grimley, J.J.; Radley, C.E. [British Steel plc, Scunthorpe (United Kingdom). Scunthorpe Works

    1995-12-01T23:59:59.000Z

    The detrimental effects of excessive coking pressures, resulting in the permanent deformation of coke oven walls, have been recognized for many years. Considerable research has been undertaken worldwide in attempts to define the limits within which a plant may safely operate and to quantify the factors which influence these pressures. Few full scale techniques are available for assessing the potential of a coal blend for causing wall damage. Inference of dangerous swelling pressures may be made however by the measurement of the peak gas pressure which is generated as the plastic layers meet and coalesce at the center of the oven. This pressure is referred to in this report as the carbonizing pressure. At the Dawes Lane cokemaking plant of British Steel`s Scunthorpe Works, a large database has been compiled over several years from the regulator measurement of this pressure. This data has been statistically analyzed to provide a mathematical model for predicting the carbonizing pressure from the properties of the component coals, the results of this analysis are presented in this report.

  4. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect (OSTI)

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01T23:59:59.000Z

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  5. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  6. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio [Mitsubishi Chemical Corp., Yokohama (Japan); Tanioka, Seiichi [Mitsubishi Chemical Corp., Sakaide (Japan)

    1997-12-31T23:59:59.000Z

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  7. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31T23:59:59.000Z

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  8. Heating control methodology in coke oven battery at Rourkela Steel Plant

    SciTech Connect (OSTI)

    Bandyopadhyay, S.S.; Parthasarathy, L.; Gupta, A.; Bose, P.R.; Mishra, U.

    1996-12-31T23:59:59.000Z

    A methodology of heating control was evolved incorporating temperature data generated through infra-red sensor at quenching station and thermocouples specially installed in the gooseneck of coke oven battery No. 3 of RSP. Average temperature of the red-hot coke as pushed helps in diagnosis of the abnormal ovens and in setting the targeted battery temperature. A concept of coke readiness factor (Q) was introduced which on optimization resulted in lowering the specific heat consumption by 30 KCal/Kg.

  9. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D. [Centre de Pyrolyse de Marienau, Forbach (France)

    1997-12-31T23:59:59.000Z

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  10. Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau (CPM)

    E-Print Network [OSTI]

    Boyer, Edmond

    - 1 - Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau with thermomechanical modelling of a coke oven heating wall. The objective is to define the safe limits of coke oven of walls, roof and larry car, pre-stresses (anchoring system), lateral pressure due to coal pushing A 3D

  11. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect (OSTI)

    Battle, E.T.; Chen, K.L. [Bethlehem Steel Corp., Burns Harbor, IN (United States); [Bethlehem Steel Corp., PA (United States)

    1997-12-31T23:59:59.000Z

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  12. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect (OSTI)

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01T23:59:59.000Z

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  13. Hydrogen production from steam reforming of coke oven gas and its utility for indirect reduction of iron oxides in blast

    E-Print Network [OSTI]

    Leu, Tzong-Shyng "Jeremy"

    of coal and coke are consumed for heating and reducing iron oxides [2,3]. As a result, BFs have becomeHydrogen production from steam reforming of coke oven gas and its utility for indirect reduction 2012 Available online 18 June 2012 Keywords: Steam reforming Hydrogen and syngas production Coke oven

  14. Operational improvements at Jewell Coal and Coke Company`s non-recovery ovens

    SciTech Connect (OSTI)

    Ellis, C.E.; Pruitt, C.W.

    1995-12-01T23:59:59.000Z

    Operational improvements at Jewell Coal and Coke Company over the past five years includes safety and environmental concerns, product quality, equipment availability, manpower utilization, and productivity. These improvements with Jewell`s unique process has allowed Jewell Coal and Coke Company to be a consistent, high quality coke producer. The paper briefly explains Jewell`s unique ovens, their operating mode, improved process control, their maintenance management program, and their increase in productivity.

  15. Coke oven doors: Historical methods of emission control and evaluation of current designs

    SciTech Connect (OSTI)

    Pettrey, J.O.; Greene, D.E. (Armco Steel Co., Middletown, OH (United States))

    1993-01-01T23:59:59.000Z

    The containment of oven door leakage has presented challenges to coke producers for many years as the requirements of environmental regulatory agencies have become increasingly stringent. A description and evaluation of past door modifications, leakage control methodologies and luting practices on Armco Steel Company, L.P.'s Ashland No. 4 Battery is detailed to provide a background for recent work, and to expand the industry's technology base. The strict door leakage standards of the 1990 amendments to the USA Clean Air Act has prompted additional technical studies. Both a joint Armco committee's evaluation of successful systems world wide and test door installations at Ashland were incorporated to determine compliance strategy. The eventual installation of Ikio Model II coke oven doors, along with modifications to ancillary equipment, has resulted in door leakage rates approaching zero. Associated methods, problems, results and evaluations are discussed.

  16. Health-hazard evaluation report No. HETA-88-377-2120, Armco Coke Oven, Ashland Kentucky

    SciTech Connect (OSTI)

    Kinnes, G.M.; Fleeger, A.K.; Baron, S.L.

    1991-06-01T23:59:59.000Z

    In response to a request from the Oil, Chemical and Atomic Workers International Union, a study was made of possible hazardous working conditions at ARMCO Coke Oven (SIC-3312), Ashland, Kentucky. The facility produces about 1,000,000 tons of coke annually. Of the approximately 400 total employees at the coke oven site, 55 work in the by products area. Air quality sampling results indicated overexposure to both benzene (71432) and coal tar pitch volatiles (CTPVs). Airborne levels of benzene ranged as high as 117 parts per million (ppm) with three of 17 samples being above the OSHA limit of 1ppm. Airborne concentrations of CTPVs ranged as high as 0.38mg/cu m with two of six readings being above OSHA limit of 0.2mg/cu m. Several polynuclear aromatic hydrocarbons were also detected. The authors conclude that by products area workers are potentially overexposed to carcinogens, including benzene, CTPVs, and polynuclear aromatic hydrocarbons. An epidemiologic study is considered unlikely to yield meaningful information at this time, due to the small number of workers and the short follow up period. The authors recommend specific measures for reducing potential employee exposures, including an environmental sampling program, a preventive maintenance program, improved housekeeping procedures, and reducing exposure in operators' booths.

  17. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31T23:59:59.000Z

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  18. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J. [Magnitogorsk Integrated Iron and Steel Works, (Russian Federation); Gross, M. [Krupp Koppers GmbH, Essen (Germany)

    1995-12-01T23:59:59.000Z

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  19. Experience and results of new heating control system of coke oven batteries at Rautaruukki Oy Raahe Steel

    SciTech Connect (OSTI)

    Swanljung, J.; Palmu, P. [Rautaruukki Oy Raahe Steel (Finland)

    1997-12-31T23:59:59.000Z

    The latest development and results of the heating control system at Raahe Steel are presented in this paper. From the beginning of coke production in Rautaruukki Oy Raahe Steel (October 1987) the heating control systems have been developed. During the first stage of development work at the coking plant (from year 1987 to 1992), when only the first coke oven battery consisting of 35 ovens was in production, the main progress was in the field of process monitoring. After commissioning of the second stage of the coking plant (November 1992), the development of the new heating control model was started. Target of the project was to develop a dynamic control system which guides the heating of batteries through the various process conditions. Development work took three years and the heating control system was commissioned in the year 1995. Principle of the second generation system is an energy balance calculation, coke end temperature determination and dynamic oven scheduling system. The control is based on simultaneous feedforward and feedback control. The fuzzy logic components were added after about one year experience.

  20. Innovative coke oven gas cleaning system for retrofit applications. Environmental Monitoring program. Volume 1 - sampling progrom report. Baseline Sampling Program report

    SciTech Connect (OSTI)

    Stuart, L.M.

    1994-05-27T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This innovative coke oven gas cleaning system combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE provided cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct and Environmental Monitoring Plan for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. It also requires the preparation of a final report on the results of the Baseline Compliance and Supplemental Sampling Programs that are part of the EMP and which were conducted prior to the startup of the innovative coke oven gas cleaning system. This report is the Baseline Sampling Program report.

  1. Urinary 1-hydroxypyrene concentrations in Chinese coke oven workers relative to job category, respirator usage, and cigarette smoking

    SciTech Connect (OSTI)

    Bo Chen; Yunping Hu; Lixing Zheng; Qiangyi Wang; Yuanfen Zhou; Taiyi Jin [Fudan University, Shanghai (China). School of Public Health

    2007-09-15T23:59:59.000Z

    1-Hydroxypyrene (1-OHP) is a biomarker of recent exposure to polycyclic aromatic hydrocarbons (PAHs). We investigated whether urinary 1-OHP concentrations in Chinese coke oven workers (COWs) are modulated by job category, respirator usage, and cigarette smoking. The present cross-sectional study measured urinary 1-OHP concentrations in 197 COWs from Coking plant I and 250 COWs from Coking plant II, as well as 220 unexposed referents from Control plant I and 56 referents from Control plant II. Urinary 1-OHP concentrations (geometric mean, {mu}mol/mol creatinine) were 5.18 and 4.21 in workers from Coking plants I and II, respectively. The highest 1-OHP levels in urine were found among topside workers including lidmen, tar chasers, and whistlers. Benchmen had higher 1-OHP levels than other workers at the sideoven. Above 75% of the COWs exceeded the recommended occupational exposure limit of 2.3 {mu}mol/mol creatinine. Respirator usage and increased body mass index (BMI) slightly reduced 1-OHP levels in COWs. Cigarette smoking significantly increased urinary 1-OHP levels in unexposed referents but had no effect in COWs. Chinese COWs, especially topside workers and benchmen, are exposed to high levels of PAHs. Urinary 1-OHP concentrations appear to be modulated by respirator usage and BMI in COWs, as well as by smoking in unexposed referents.

  2. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka [Kawasaki Steel Corp., Mizushima, Kurashiki (Japan). Mizushima Works

    1997-12-31T23:59:59.000Z

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  3. Prolongation technologies for campaign life of tall oven

    SciTech Connect (OSTI)

    Doko, Yoshiji; Saji, Takafumi; Kitayama, Yoshiteru; Yoshida, Shuhei [Sumitomo Metal Industries, Ltd., Kashima, Ibaraki (Japan). Kashima Steel Works

    1997-12-31T23:59:59.000Z

    In Kashima Steel Works, 25-year-old 7-meter-high coke ovens have damage on their walls. However, by using new methods of internal in-situ investigation, ceramic welding for the extended central and upper portions of coke ovens has prolonged the campaign life for over 40 years without large-scale hot repair. In this paper, introduction of these new methods, its application in Kashima and the policy of repairing the tall coke oven are reported.

  4. Simulation of industrial coking -- Phase 1

    SciTech Connect (OSTI)

    Todoschuk, T.W.; Price, J.T.; Gransden, J.F.

    1997-12-31T23:59:59.000Z

    Two statistically designed experimental programs using an Appalachian and a Western Canadian coal blend were run in CANMET`s 460mm (18 inch) movable wall oven. Factors included coal grind, moisture, oil addition, carbonization rate and final coke temperature. Coke quality parameters including CSR, coal charge characteristics and pressure generation were analyzed.

  5. About Beryllium

    Broader source: Energy.gov [DOE]

    Information on what is Beryllium, the symptoms and health hazards associated with Beryllium contamination.

  6. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16T23:59:59.000Z

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

  7. Collector main replacement at Indianapolis Coke

    SciTech Connect (OSTI)

    Sickle, R.R. Van

    1997-12-31T23:59:59.000Z

    Indianapolis Coke is a merchant coke producer, supplying both foundry and blast furnace coke to the industry. The facility has three coke batteries: two 3 meter batteries, one Wilputte four divided and one Koppers Becker. Both batteries are underjet batteries and are producing 100% foundry coke at a net coking time of 30.6 hours. This paper deals with the No. 1 coke battery, which is a 72 oven, gun fired, 5 meter Still battery. No. 1 battery produces both foundry and blast furnace coke at a net coking rate of 25.4 hours. No. 1 battery was commissioned in 1979. The battery is equipped with a double collector main. Although many renovations have been completed to the battery, oven machinery and heating system, to date no major construction projects have taken place. Deterioration of the collector main was caused in part from elevated levels of chlorides in the flushing liquor, and temperature fluctuations within the collector main. The repair procedures are discussed.

  8. Unmanned operation of the coke guides at Hoogovens IJmuiden Coke Plant 1

    SciTech Connect (OSTI)

    Vos, D.; Mannes, N.; Poppema, B. [Hoogovens IJmuiden B.V. (Netherlands)

    1995-12-01T23:59:59.000Z

    Due to the bad condition of batteries and many ovens under repair, Hoogovens was forced to partially repair and rebuild the Coke plant No. 1. The production of coke at Coke plant No. 1 is realized in 3 production blocks subdivided in 6 batteries. Besides a renovated installation, all coke oven machines were renewed. A total of five identical machine sets are available. Each consists of a pusher machine, larry car, coke guide and quench car with diesel locomotive. A complete automated control system was implemented. The main objectives were a highly regular coking and pushing process, automated traveling and positioning and a centrally coordinated interlocking of machine functions. On each operational machine however an operator performed the supervisory control of the automated machine functions. After years of good experience with the automated system, economical reasons urged further personnel reduction from 1994 on. Totally 375 people were involved, including the maintenance department. To reduce the occupation at coke plant No. 1, the coke guide was the first machine to be fully automated because of the isolated and uncomfortable working place.

  9. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-12-01T23:59:59.000Z

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  10. The waste water free coke plant

    SciTech Connect (OSTI)

    Schuepphaus, K.; Brink, N. [Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany)

    1995-12-01T23:59:59.000Z

    Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

  11. Priorities in the design of chemical shops at coke plants

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

  12. Beryllium Testing

    Broader source: Energy.gov [DOE]

    Beryllium is a naturally occurring metal and is not radioactive. Because of its properties, beryllium has been part of the atomic energy and nuclear weapons industries since the 1940s.

  13. Cyanide treatment options in coke plants

    SciTech Connect (OSTI)

    Minak, H.P.; Lepke, P. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    The paper discusses the formation of cyanides in coke oven gas and describes and compares waste processing options. These include desulfurization by aqueous ammonia solution, desulfurization using potash solution, desulfurization in oxide boxes, decomposition of NH{sub 3} and HCN for gas scrubbing. Waste water treatment methods include chemical oxidation, precipitation, ion exchange, reverse osmosis, and biological treatment. It is concluded that biological treatment is the most economical process, safe in operation and requires a minimum of manpower.

  14. Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas

    SciTech Connect (OSTI)

    V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

  15. The new Kaiserstuhl coking plant: The heating system -- Design, construction and initial operating experience

    SciTech Connect (OSTI)

    Strunk, J.

    1996-12-31T23:59:59.000Z

    At the end of 1992 the new coke plant Kaiserstuhl in Dortmund/Germany with presently the largest coke ovens world-wide started its production operation in close linkage to the Krupp-Hoesch Metallurgical Works after about 35 months construction time. This plant incorporating comprehensive equipment geared to improve environmental protection is also considered as the most modern coke plant of the world. The heating-system and first results of operation will be presented.

  16. Portable oven air circulator

    DOE Patents [OSTI]

    Jorgensen, Jorgen A. (Bloomington, MN); Nygren, Donald W. (Minneapolis, MN)

    1983-01-01T23:59:59.000Z

    A portable air circulating apparatus for use in cooking ovens which is used to create air currents in the oven which transfer heat to cooking foodstuffs to promote more rapid and more uniform cooking or baking, the apparatus including a motor, fan blade and housing of metallic materials selected from a class of heat resistant materials.

  17. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect (OSTI)

    Diemer, P.E.; Seyfferth, W. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  18. Operating and maintenance benefits of automated oven wall temperature measurement

    SciTech Connect (OSTI)

    Leuchtmann, K.P. [Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany); Hinz, D.; Bergbau, D. [Ruhrkohle Bergbau AG, Bottrop (Germany). Prosper Coking Plant; Platts, M. [Thyssen Still Otto Technical Services, Pittsburgh, PA (United States)

    1997-12-31T23:59:59.000Z

    For a very long time and regardless of all shortcomings associated with it, the manual measurement of the heating flue temperature has been the only method of monitoring the temperature prevailing in a coke oven battery and discovering weak points in the heating system. In the course of the last few years a number of automated temperature measuring systems have been developed that are intended to replace or supplement the manual heating flue measurement system. These measuring systems and their advantages/disadvantages are briefly described in this paper. Additionally, operational experience gathered with the oven chamber wall temperature measuring system is discussed in detail.

  19. Beryllium disease

    SciTech Connect (OSTI)

    Not Available

    1991-12-20T23:59:59.000Z

    After two workers at the nuclear weapons plant at Oak Ridge National Laboratory in Tennessee were diagnosed earlier this year with chronic beryllium disease (CBD), a rare and sometimes fatal scarring of the lungs, the Department of Energy ordered up a 4-year probe. Now, part of that probe has begun - tests conducted by the Oak Ridge Associated Universities' Center for Epidemiological Research measuring beryllium sensitivity in 3,000 people who've been exposed to the metal's dust since Manhattan Project managers opened the Y-12 plant at Oak Ridge in 1943. Currently, 119 Y-12 employees process beryllium, which has a number of industrial uses, including rocket heat shields and nuclear weapon and electrical components. The disease often takes 20 to 25 years to develop, and the stricken employees haven't worked with beryllium for years. There is no cure for CBD, estimated to strike 2% of people exposed to the metal. Anti-inflammatory steroids alleviate such symptoms as a dry cough, weight loss, and fatigue. Like other lung-fibrosis diseases that are linked to lung cancer, some people suspect CBD might cause some lung cancer. While difficult to diagnose, about 900 cases of CBD have been reported since a Beryllium Case Registry was established in 1952. The Department of Energy (DOE) estimates that about 10,000 DOE employees and 800,000 people in private industry have worked with beryllium.

  20. Method for welding beryllium

    DOE Patents [OSTI]

    Dixon, Raymond D. (Los Alamos, NM); Smith, Frank M. (Espanola, NM); O'Leary, Richard F. (Los Alamos, NM)

    1997-01-01T23:59:59.000Z

    A method is provided for joining beryllium pieces which comprises: depositing aluminum alloy on at least one beryllium surface; contacting that beryllium surface with at least one other beryllium surface; and welding the aluminum alloy coated beryllium surfaces together. The aluminum alloy may be deposited on the beryllium using gas metal arc welding. The aluminum alloy coated beryllium surfaces may be subjected to elevated temperatures and pressures to reduce porosity before welding the pieces together. The aluminum alloy coated beryllium surfaces may be machined into a desired welding joint configuration before welding. The beryllium may be an alloy of beryllium or a beryllium compound. The aluminum alloy may comprise aluminum and silicon.

  1. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Sirgado, M. [ENSIDESA, Aviles (Spain)

    1995-12-01T23:59:59.000Z

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  2. Beryllium weldability

    SciTech Connect (OSTI)

    Hill, M.A.; Damkroger, B.K.; Dixon, R.D. (Los Alamos National Lab., NM (USA)); Robertson, E. (Air Force Office of Scientific Research, Washington, DC (USA))

    1990-01-01T23:59:59.000Z

    Welding processes and metallurgical considerations for beryllium welding are discussed in this review. The primary difficulties of welding beryllium are hot cracking, cracking at defects, and ductility limitation or thermally induced cracking. Solutions to these welding problems include control of the Fe/Al ratio in the base metal to reduce hot cracking, minimization of the BeO content and starting grain size to limit cracking at defects and ductility limitation cracking, and optimization of the welding process and process variables. 25 refs., 9 figs., 2 tabs.

  3. Western Canadian coking coals -- Thermal rheology and coking quality

    SciTech Connect (OSTI)

    Leeder, W.R. [Teck Corp. (Canada); Price, J.T.; Gransden, J.F. [CANMET Energy Technology Centre, Ottawa, Ontario (Canada)

    1997-12-31T23:59:59.000Z

    Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

  4. Interim Chronic Beryllium Disease

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-12-08T23:59:59.000Z

    Establishes Departmental expectations for addressing chronic beryllium disease throughout the Department until a Departmental rule on beryllium is promulgated. This Notice was replaced by final rule 10 CFR Part 850, Chronic Beryllium Disease Prevention Program, published December 8, 1999.

  5. Method for welding beryllium

    DOE Patents [OSTI]

    Dixon, R.D.; Smith, F.M.; O`Leary, R.F.

    1997-04-01T23:59:59.000Z

    A method is provided for joining beryllium pieces which comprises: depositing aluminum alloy on at least one beryllium surface; contacting that beryllium surface with at least one other beryllium surface; and welding the aluminum alloy coated beryllium surfaces together. The aluminum alloy may be deposited on the beryllium using gas metal arc welding. The aluminum alloy coated beryllium surfaces may be subjected to elevated temperatures and pressures to reduce porosity before welding the pieces together. The aluminum alloy coated beryllium surfaces may be machined into a desired welding joint configuration before welding. The beryllium may be an alloy of beryllium or a beryllium compound. The aluminum alloy may comprise aluminum and silicon. 9 figs.

  6. Met coke world summit 2005

    SciTech Connect (OSTI)

    NONE

    2005-07-01T23:59:59.000Z

    Papers are presented under the following session headings: industry overview and market outlook; coke in the Americas; the global coke industry; and new developments. All the papers (except one) only consist of a copy of the overheads/viewgraphs.

  7. Oven wall panel construction

    DOE Patents [OSTI]

    Ellison, Kenneth (20 Avondale Cres., Markham, CA); Whike, Alan S. (R.R. #1, Caledon East, both of Ontario, CA)

    1980-04-22T23:59:59.000Z

    An oven roof or wall is formed from modular panels, each of which comprises an inner fabric and an outer fabric. Each such fabric is formed with an angle iron framework and somewhat resilient tie-bars or welded at their ends to flanges of the angle irons to maintain the inner and outer frameworks in spaced disposition while minimizing heat transfer by conduction and permitting some degree of relative movement on expansion and contraction of the module components. Suitable thermal insulation is provided within the module. Panels or skins are secured to the fabric frameworks and each such skin is secured to a framework and projects laterally so as slidingly to overlie the adjacent frame member of an adjacent panel in turn to permit relative movement during expansion and contraction.

  8. Coking and gasification process

    DOE Patents [OSTI]

    Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

    1986-01-01T23:59:59.000Z

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  9. High coking value pitch

    SciTech Connect (OSTI)

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10T23:59:59.000Z

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  10. Ovenized microelectromechanical system (MEMS) resonator

    DOE Patents [OSTI]

    Olsson, Roy H; Wojciechowski, Kenneth; Kim, Bongsang

    2014-03-11T23:59:59.000Z

    An ovenized micro-electro-mechanical system (MEMS) resonator including: a substantially thermally isolated mechanical resonator cavity; a mechanical oscillator coupled to the mechanical resonator cavity; and a heating element formed on the mechanical resonator cavity.

  11. Design and construction of coke battery 1A at Radlin coke plant, Poland

    SciTech Connect (OSTI)

    A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos'kova; N.I. Shkol'naya; V.V. Derevich; A.S. Grankin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

  12. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M. [Krupp Koppers GmbH, Essen (Germany)

    1996-12-31T23:59:59.000Z

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  13. Light oil yield improvement project at Granite City Division Coke/By-Product Plant

    SciTech Connect (OSTI)

    Holloran, R.A. [National Steel Corp., Granite City, IL (United States). Granite City Div.

    1995-12-01T23:59:59.000Z

    Light oil removal from coke oven gas is a process that has long been proven and utilized throughout many North American Coke/By-Products Plants. The procedures, processes, and equipment requirements to maximize light oil recovery at the Granite City By-Products Plant will be discussed. The Light Oil Yield Improvement Project initially began in July, 1993 and was well into the final phase by February, 1994. Problem solving techniques, along with utilizing proven theoretical recovery standards were applied in this project. Process equipment improvements and implementation of Operator/Maintenance Standard Practices resulted in an average yield increase of 0.4 Gals./NTDC by the end of 1993.

  14. Coke from coal and petroleum

    DOE Patents [OSTI]

    Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

    1981-01-01T23:59:59.000Z

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  15. Rapid baking characteristics and energy efficiency of an impingement air oven compared to a reel oven

    E-Print Network [OSTI]

    Smith, Lloyd Hobart

    1983-01-01T23:59:59.000Z

    had e i ght set s o f bo t t om j et modul es while oven number 1 had six top jets and oven number 2 had seven. The Conventional Reel Oven A M idd1 eby Marshal 1 Model H-725 gas f ired 36 pan reel oven [Ill ustrat ion 3 ) was used as the control o... heating to 400 'P. Data represents gas consmsptinn for "Jet Sweep" oven heating to a baking temperature of 320/300'P. and control oven to a baking temperature of 400'P. Equal quantities of hamburger buna were baked in both ovens and the gas...

  16. Converting Petroleum Coke to Electricity

    E-Print Network [OSTI]

    Pavone, A.

    contributes 80% of this total. As crude oil coke is a cement kiln, where the alkaline quality deteriorates, and the market for residual components in cement will absorb the sulfur oil. becomes less profitable due to increasingly released by the coke during.... The higher value has been amply demonstrated by the Combustion Power Units, and by commercial gasification systems producing syngas for chemicals We do not anticipate a major system availability debit for adding an industrial-scale, base loaded...

  17. New coke-sorting system at OAO Koks

    SciTech Connect (OSTI)

    B.Kh. Bulaevskii; V.S. Shved; Yu.V. Kalimin; S.D. Filippov [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    A new coke-sorting system has been introduced at OAO Koks. It differs from the existing system in that it has no bunkers for all-purpose coke but only bunkers for commercial coke. In using this system with coke from battery 4, the crushing of the coke on conveyer belts, at roller screens, and in the commercial-coke bunkers is studied. After installing braking elements in the coke path, their effectiveness in reducing coke disintegration and improving coke screening is investigated. The granulometric composition and strength of the commercial coke from coke battery 3, with the new coke-sorting system, is evaluated.

  18. Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001

    SciTech Connect (OSTI)

    Jin, H.G.; Sun, S.; Han, W.; Gao, L. [Chinese Academy of Sciences, Beijing (China)

    2009-09-15T23:59:59.000Z

    This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

  19. Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002Optics Group (X-rayLSDPreciousM206 Mechanical Convection

  20. Beryllium Manufacturing Processes

    SciTech Connect (OSTI)

    Goldberg, A

    2006-06-30T23:59:59.000Z

    This report is one of a number of reports that will be combined into a handbook on beryllium. Each report covers a specific topic. To-date, the following reports have been published: (1) Consolidation and Grades of Beryllium; (2) Mechanical Properties of Beryllium and the Factors Affecting these Properties; (3) Corrosion and Corrosion Protection of Beryllium; (4) Joining of Beryllium; (5) Atomic, Crystal, Elastic, Thermal, Nuclear, and other Properties of Beryllium; and (6) Beryllium Coating (Deposition) Processes and the Influence of Processing Parameters on Properties and Microstructure. The conventional method of using ingot-cast material is unsuitable for manufacturing a beryllium product. Beryllium is a highly reactive metal with a high melting point, making it susceptible to react with mold-wall materials forming beryllium compounds (BeO, etc.) that become entrapped in the solidified metal. In addition, the grain size is excessively large, being 50 to 100 {micro}m in diameter, while grain sizes of 15 {micro}m or less are required to meet acceptable strength and ductility requirements. Attempts at refining the as-cast-grain size have been unsuccessful. Because of the large grain size and limited slip systems, the casting will invariably crack during a hot-working step, which is an important step in the microstructural-refining process. The high reactivity of beryllium together with its high viscosity (even with substantial superheat) also makes it an unsuitable candidate for precision casting. In order to overcome these problems, alternative methods have been developed for the manufacturing of beryllium. The vast majority of these methods involve the use of beryllium powders. The powders are consolidated under pressure in vacuum at an elevated temperature to produce vacuum hot-pressed (VHP) blocks and vacuum hot-isostatic-pressed (HIP) forms and billets. The blocks (typically cylindrical), which are produced over a wide range of sizes (up to 183 cm dia. by 61 cm high), may be cut or machined into parts or be thermomechanically processed to develop the desired microstructure, properties, and shapes. Vacuum hot-isostatic pressing and cold-isostatic pressing (CIP) followed by sintering and possibly by a final HIP'ing (CIP/Sinter/HIP) are important in their use for the production of near net-shaped parts. For the same starting powder, a HIP'ed product will have less anisotropy than that obtained for a VHP'ed product. A schematic presentation illustrating the difference between VHP'ing and HIP'ing is shown in Figure I-1. The types of powders and the various beryllium grades produced from the consolidated powders and their ambient-temperature mechanical properties were presented in the consolidation report referred to above. Elevated-temperature properties and the effect of processing variables on mechanical properties are described in the mechanical properties report. Beryllium can also be deposited as coatings as well as freestanding forms. The microstructure, properties, and various methods used that are related to the deposition of beryllium are discussed in the report on beryllium coatings.

  1. Trends in the automation of coke production

    SciTech Connect (OSTI)

    R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

  2. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L. [Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant

    1995-12-01T23:59:59.000Z

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  3. Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine

    SciTech Connect (OSTI)

    Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

    2007-03-15T23:59:59.000Z

    The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

  4. China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and in Selected Provinces

    E-Print Network [OSTI]

    Lu, Hongyou

    2013-01-01T23:59:59.000Z

    Coal Washed Coal Coke Coke Oven Gas Other Gas Other CokingTJ) Coal Coke Coke Oven Gas Other Gas Other Coking Products

  5. Coke cake behavior under compressive forces

    SciTech Connect (OSTI)

    Watakabe, S.; Takeda, T.; Itaya, H.; Suginobe, H.

    1997-12-31T23:59:59.000Z

    The deformation of the coke cake and load on the side wall during pushing were studied using an electric furnace equipped with a movable wall. Coke cake was found to deform in three stages under compressive forces. The coke cake was shortened in the pushing direction in the cake deformation stage, and load was generated on the side walls in the high wall load stage. Secondary cracks in the coke cake were found to prevent load transmission on the wall. The maximum load transmission rate was controlled by adjusting the maximum fluidity and mean reflectance of the blended coal.

  6. New designs in the reconstruction of coke-sorting systems

    SciTech Connect (OSTI)

    A.S. Larin; V.V. Demenko; V.L. Voitanik [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

  7. ORISE: Worker Health Studies - Beryllium Testing Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    procedures are performed according to the protocol specified by the U.S. Department of Energy. Featured Video Beryllium Awareness Video WATCH: Beryllium Awareness Video (15:10)...

  8. Technical Basis for PNNL Beryllium Inventory

    SciTech Connect (OSTI)

    Johnson, Michelle Lynn

    2014-07-09T23:59:59.000Z

    The Department of Energy (DOE) issued Title 10 of the Code of Federal Regulations Part 850, “Chronic Beryllium Disease Prevention Program” (the Beryllium Rule) in 1999 and required full compliance by no later than January 7, 2002. The Beryllium Rule requires the development of a baseline beryllium inventory of the locations of beryllium operations and other locations of potential beryllium contamination at DOE facilities. The baseline beryllium inventory is also required to identify workers exposed or potentially exposed to beryllium at those locations. Prior to DOE issuing 10 CFR 850, Pacific Northwest Nuclear Laboratory (PNNL) had documented the beryllium characterization and worker exposure potential for multiple facilities in compliance with DOE’s 1997 Notice 440.1, “Interim Chronic Beryllium Disease.” After DOE’s issuance of 10 CFR 850, PNNL developed an implementation plan to be compliant by 2002. In 2014, an internal self-assessment (ITS #E-00748) of PNNL’s Chronic Beryllium Disease Prevention Program (CBDPP) identified several deficiencies. One deficiency is that the technical basis for establishing the baseline beryllium inventory when the Beryllium Rule was implemented was either not documented or not retrievable. In addition, the beryllium inventory itself had not been adequately documented and maintained since PNNL established its own CBDPP, separate from Hanford Site’s program. This document reconstructs PNNL’s baseline beryllium inventory as it would have existed when it achieved compliance with the Beryllium Rule in 2001 and provides the technical basis for the baseline beryllium inventory.

  9. Oven Baked Sweet Potato Fries Ingredients

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    Oven Baked Sweet Potato Fries Ingredients: Vegetable cooking spray 1 1/2 pounds sweet potato (about spray a 10 x 14 cookie sheet with non-stick cooking spray. 2. Scrub potatoes under tap water with a vegetable brush. With a knife remove any bad spots or defects on the potato. Do not peel. 3. On a cutting

  10. Heat treatment of exchangers to remove coke

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-20T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating the furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas containing molecular oxygen at a sufficient temperature below 800{degrees}F (427{degrees}C) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of five thousand pounds per square inch.

  11. Delayed coking of decant oil and coal in a laboratory-scale coking unit

    SciTech Connect (OSTI)

    Oemer Guel; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University Park, PA (United States). Energy Institute, C205 Coal Utilization Laboratory

    2006-08-15T23:59:59.000Z

    In this paper, we describe the development of a laboratory-scale delayed coker and present results of an investigation on the recovered liquid from the coking of decant oil and decant oil/coal mixtures. Using quantitative gas chromatography/mass spectroscopy (GC/MS) and {sup 1}H and {sup 13}C NMR, a study was made of the chemical composition of the distillate liquids isolated from the overheads collected during the coking and co-coking process. {sup 1}H and {sup 13}C NMR analyses of combined liquids from coking and co-coking did not show any substantial differences. These NMR results of coking and co-coking liquids agree with those of GC/MS. In these studies, it was observed that co-coking with coal resulted in a decrease in the paraffins contents of the liquid. The percentage of cycloparaffins, indenes, naphthalenes, and tetralins did not change significantly. In contrast, alkyl benzenes and polycyclic aromatic hydrocarbons in the distillate were higher in the co-coking experiments which may have resulted from the distillation of thermally cracked coal macromolecules and the contribution of these molecules to the overall liquid composition. 40 refs., 3 figs., 13 tabs.

  12. New and revised standards for coke production

    SciTech Connect (OSTI)

    G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

  13. Mozambique becomes a major coking coal exporter?

    SciTech Connect (OSTI)

    Ruffini, A.

    2008-06-15T23:59:59.000Z

    In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

  14. The INEL beryllium multiplication experiment

    SciTech Connect (OSTI)

    Smith, J.R.; King, J.J.

    1991-03-01T23:59:59.000Z

    The experiment to measure the multiplication of 14-MeV neutrons in bulk beryllium has been completed. The experiment consists of determining the ratio of {sup 56}Mn activities induced in a large manganese bath by a central 14-MeV neutron source, with and without a beryllium sample surrounding the source. In the manganese bath method a neutron source is placed at the center of a totally-absorbing aqueous solution of MnSo{sub 4}. The capture of neutrons by Mn produces a {sup 56}Mn activity proportional to the emission rate of the source. As applied to the measurement of the multiplication of 14- MeV neutrons in bulk beryllium, the neutron source is a tritium target placed at the end of the drift tube of a small deuteron accelerator. Surrounding the source is a sample chamber. When the sample chamber is empty, the neutrons go directly to the surrounding MnSO{sub 4} solution, and produce a {sup 56}Mn activity proportional to the neutron emission rate. When the chamber contains a beryllium sample, the neutrons first enter the beryllium and multiply through the (n,2n) process. Neutrons escaping from the beryllium enter the bath and produce a {sup 56}Mn activity proportional to the neutron emission rate multiplied by the effective value of the multiplication in bulk beryllium. The ratio of the activities with and without the sample present is proportional to the multiplication value. Detailed calculations of the multiplication and all the systematic effects were made with the Monte Carlo program MCNP, utilizing both the Young and Stewart and the ENDF/B-VI evaluations for beryllium. Both data sets produce multiplication values that are in excellent agreement with the measurements for both raw and corrected values of the multiplication. We conclude that there is not real discrepancy between experimental and calculated values for the multiplication of neutrons in bulk beryllium. 12 figs., 11 tabs., 18 refs.

  15. Possibilities of coke manufacture in nonpollutant conditions

    SciTech Connect (OSTI)

    Barca, F.; Panaitescu, C.; Vidrighin, C.; Peleanu, I. [Politehnica Univ. Bucharest (Romania); Albastroiu, P. [S.C. ICEM S.A., Bucharest (Romania)

    1994-12-31T23:59:59.000Z

    The paper presents some possibilities to obtain coke briquettes from anthracite, using as binders petroleum pitch, wheat flour, cement, plaster, ashes from power-plants dried from the electrofilters. Specific thermal post-treatment were proposed for each case, such as: oxidation or heating at low temperatures (under 300 C). As a result the authors obtained coke briquettes to be used in small equipment, with no pollutant pyrogenetic treatment.

  16. Physical, chemical and thermal changes of coals and coal maceral concentrates during coke formation.

    E-Print Network [OSTI]

    Xie, Wei

    2013-01-01T23:59:59.000Z

    ??Research Doctorate - Doctor of Philosophy (PhD) The measured coke reactivity index (CRI) and coke strength after reaction (CSR) determined in experiments based on coke… (more)

  17. Beryllium usage in fusion blankets and beryllium data needs. [None

    SciTech Connect (OSTI)

    Moir, R.W.

    1988-04-06T23:59:59.000Z

    Increasing numbers of designers are choosing beryllium for fusion reactor blankets because it, among all nonfissile materials, produces the highest number (2.5 neutron in an infinite media) of neutrons per 14-MeV incident neutron. In amounts of about 20 cm of equivalent solid density, it can be used to produce fissile material, to breed all the tritium consumed in ITER from outboard blankets only, and in designs to produce Co-60. The problem is that predictions of neutron multiplication in beryllium are off by some 10 to 20% and appear to be on the high side, which means that better multiplication measurements and numerical methods are needed. The n,2n reactions result in two helium atoms, which cause radiation damage in the form of hardening at low temperatures (<300/degree/C) and swelling at high temperatures (>300/degree/C). The usual way beryllium parts are made is by hot pressing the powder. A lower cost method is to cold press and then sinter. There is no radiation damage data on this form of beryllium. The issues of corrosion, safety relative to the release of the tritium built-up inside beryllium, and recycle of used beryllium are also discussed. 10 figs.

  18. Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

  19. Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar

    SciTech Connect (OSTI)

    Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

    2006-10-15T23:59:59.000Z

    In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

  20. Multiple delivery cesium oven system for negative ion sources

    SciTech Connect (OSTI)

    Bansal, G.; Bhartiya, S.; Pandya, K.; Bandyopadhyay, M.; Singh, M. J.; Soni, J.; Gahlaut, A.; Parmar, K. G.; Chakraborty, A. [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat 382428 (India)

    2012-02-15T23:59:59.000Z

    Distribution of cesium in large negative ion beam sources to be operational in ITER, is presently based on the use of three or more cesium ovens, which operate simultaneously and are controlled remotely. However, use of multiple Cs ovens simultaneously is likely to pose difficulties in operation and maintenance of the ovens. An alternate method of Cs delivery, based on a single oven distribution system is proposed as one which could reduce the need of simultaneous operation of many ovens. A proof of principle experiment verifying the concept of a multinozzle distributor based Cs oven has been carried out at Institute for Plasma Research. It is also observed that the Cs flux is not controlled by Cs reservoir temperature after few hours of operation but by the temperature of the distributor which starts behaving as a Cs reservoir.

  1. Beryllium Related Matter

    SciTech Connect (OSTI)

    Gaylord, R F

    2008-12-23T23:59:59.000Z

    In recent months, LLNL has identified, commenced, and implemented a series of interim controls, compensatory measures, and initiatives to ensure worker safety, and improve safety processes with regards to potential worker exposure to beryllium. Many of these actions have been undertaken in response to the NNSA Independent Review (COR-TS-5/15/2008-8550) received by LLNL in November of 2008. Others are the result of recent discoveries, events or incidents, and lessons learned, or were scheduled corrective actions from earlier commitments. Many of these actions are very recent in nature, or are still in progress, and vary in the formality of implementation. Actions are being reviewed for effectiveness as they progress. The documentation of implementation, and review of effectiveness, when appropriate, of these actions will be addressed as part of the formal Corrective Action Plan addressing the Independent Review. The mitigating actions taken fall into the following categories: (1) Responses to specific events/concerns; (2) Development of interim controls; (3) Review of ongoing activities; and (4) Performance improvement measures.

  2. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

    2003-02-07T23:59:59.000Z

    The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

  3. Processing Irradiated Beryllium For Disposal

    SciTech Connect (OSTI)

    T. J. Tranter; R. D. Tillotson; N. R. Mann; G. R. Longhurst

    2005-11-01T23:59:59.000Z

    The purpose of this research was to develop a process for decontaminating irradiated beryllium that will allow it to be disposed of through normal radwaste channels. Thus, the primary objectives of this ongoing study are to remove the transuranic (TRU) isotopes to less than 100 nCi/g and remove {sup 60}Co, and {sup 137}Cs, to levels that will allow the beryllium to be contact handled. One possible approach that appears to have the most promise is aqueous dissolution and separation of the isotopes by selected solvent extraction followed by precipitation, resulting in a granular form for the beryllium that may be fixed to prevent it from becoming respirable and therefore hazardous. Beryllium metal was dissolved in nitric and fluorboric acids. Isotopes of {sup 241}Am, {sup 239}Pu, {sup 85}Sr, and {sup 137}Cs were then added to make a surrogate beryllium waste solution. A series of batch contacts was performed with the spiked simulant using chlorinated cobalt dicarbollide (CCD) and polyethylene glycol diluted with sulfone to extract the isotopes of Cs and Sr. Another series of batch contacts was performed using a combination of octyl (phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) in tributyl phosphate (TBP) diluted with dodecane for extracting the isotopes of Pu and Am. The results indicate that greater than 99.9% removal can be achieved for each isotope with only three contact stages.

  4. Neutron irradiation of beryllium pebbles

    SciTech Connect (OSTI)

    Gelles, D.S.; Ermi, R.M. [Pacific Northwest National Lab., Richland, WA (United States); Tsai, H. [Argonne National Lab., IL (United States)

    1998-03-01T23:59:59.000Z

    Seven subcapsules from the FFTF/MOTA 2B irradiation experiment containing 97 or 100% dense sintered beryllium cylindrical specimens in depleted lithium have been opened and the specimens retrieved for postirradiation examination. Irradiation conditions included 370 C to 1.6 {times} 10{sup 22} n/cm{sup 2}, 425 C to 4.8 {times} 10{sup 22} n/cm{sup 2}, and 550 C to 5.0 {times} 10{sup 22} n/cm{sup 2}. TEM specimens contained in these capsules were also retrieved, but many were broken. Density measurements of the cylindrical specimens showed as much as 1.59% swelling following irradiation at 500 C in 100% dense beryllium. Beryllium at 97% density generally gave slightly lower swelling values.

  5. Water protection in coke-plant design

    SciTech Connect (OSTI)

    G.I. Alekseev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

  6. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature to remove hydrogen sulfide from furnace gases. (2) An understanding of what causes foaming in c

  7. Reducing dust emissions at OAO Alchevskkoks coke battery 10A

    SciTech Connect (OSTI)

    T.F. Trembach; E.N. Lanina [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

  8. Beryllium Technology Research in the United States

    SciTech Connect (OSTI)

    Glen R. Longhurst; Robert A. Anderl; M. Kay Adleer-Flitton; Gretchen E. Matthern; Troy J. Tranter; Kendall J. Hollis

    2005-02-01T23:59:59.000Z

    While most active research involving beryllium in the United States remains tied strongly to biological effects, there are several areas of technology development in the last two years that should be mentioned. (1) Beryllium disposed of in soil vaults at the Idaho National Laboratory (INL) Radioactive Waste Management Complex (RWMC) has been encapsulated in-situ by high-temperature and pressure injection of a proprietary wax based material to inhibit corrosion. (2) A research program to develop a process for removing heavy metals and cobalt from irradiated beryllium using solvent extraction techniques has been initiated to remove components that prevent the beryllium from being disposed of as ordinary radioactive waste. (3) The JUPITER-II program at the INL Safety and Tritium Applied Research (STAR) facility has addressed the REDOX reaction of beryllium in molten Flibe (a mixture of LiF and BeF2) to control tritium, particularly in the form of HF, bred in the Flibe by reactions involving both beryllium and lithium. (4) Work has been performed at Los Alamos National Laboratory to produce beryllium high heat flux components by plasma spray deposition on macro-roughened substrates. Finally, (5) corrosion studies on buried beryllium samples at the RWMC have shown that the physical form of some of the corroded beryllium is very filamentary and asbestos-like. This form of beryllium may exacerbate the contraction of chronic beryllium disease.

  9. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS

    SciTech Connect (OSTI)

    John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

    2002-05-01T23:59:59.000Z

    The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

  10. Worker Environment Beryllium Characterization Study

    SciTech Connect (OSTI)

    NSTec Environment, Safety, Health & Quality

    2009-12-28T23:59:59.000Z

    This report summarizes the conclusion of regular monitoring of occupied buildings at the Nevada Test Site and North Las Vegas facility to determine the extent of beryllium (Be) contamination in accordance with Judgment of Needs 6 of the August 14, 2003, “Minnema Report.”

  11. Beryllium - A Unique Material in Nuclear Applications

    SciTech Connect (OSTI)

    T., A. Tomberlin

    2004-11-01T23:59:59.000Z

    Beryllium, due to its unique combination of structural, chemical, atomic number, and neutron absorption cross section characteristics, has been used successfully as a neutron reflector for three generations of nuclear test reactors at the Idaho National Engineering and Environmental Laboratory (INEEL). The Advanced Test Reactor (ATR), the largest test reactor in the world, has utilized five successive beryllium neutron reflectors and is scheduled for continued operation with a sixth beryllium reflector. A high radiation environment in a test reactor produces radiation damage and other changes in beryllium. These changes necessitate safety analysis of the beryllium, methods to predict performance, and appropriate surveillances. Other nuclear applications also utilize beryllium. Beryllium, given its unique atomic, physical, and chemical characteristics, is widely used as a “window” for x-rays and gamma rays. Beryllium, intimately mixed with high-energy alpha radiation emitters has been successfully used to produce neutron sources. This paper addresses operational experience and methodologies associated with the use of beryllium in nuclear test reactors and in “windows” for x-rays and gamma rays. Other nuclear applications utilizing beryllium are also discussed.

  12. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  13. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P. [BHP Research, Mulgrave (Australia). Melbourne Labs.; Cunningham, R.; Hockings, K. [BHP Steel, Pt Kembla, New South Wales (Australia). Coal and Coke Technical Development Group

    1997-12-31T23:59:59.000Z

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  14. Defense programs beryllium good practice guide

    SciTech Connect (OSTI)

    Herr, M.

    1997-07-01T23:59:59.000Z

    Within the DOE, it has recently become apparent that some contractor employees who have worked (or are currently working) with and around beryllium have developed chronic beryllium disease (CBD), an occupational granulomatous lung disorder. Respiratory exposure to aerosolized beryllium, in susceptible individuals, causes an immunological reaction that can result in granulomatous scarring of the lung parenchyma, shortness of breath, cough, fatigue, weight loss, and, ultimately, respiratory failure. Beryllium disease was originally identified in the 1940s, largely in the fluorescent light industry. In 1950, the Atomic Energy Commission (AEC) introduced strict exposure standards that generally curtailed both the acute and chronic forms of the disease. Beginning in 1984, with the identification of a CBD case in a DOE contractor worker, there was increased scrutiny of both industrial hygiene practices and individuals in this workforce. To date, over 100 additional cases of beryllium-specific sensitization and/or CBD have been identified. Thus, a disease previously thought to be largely eliminated by the adoption of permissible exposure standards 45 years ago is still a health risk in certain workforces. This good practice guide forms the basis of an acceptable program for controlling workplace exposure to beryllium. It provides (1) Guidance for minimizing worker exposure to beryllium in Defense Programs facilities during all phases of beryllium-related work, including the decontamination and decommissioning (D&D) of facilities. (2) Recommended controls to be applied to the handling of metallic beryllium and beryllium alloys, beryllium oxide, and other beryllium compounds. (3) Recommendations for medical monitoring and surveillance of workers exposed (or potentially exposed) to beryllium, based on the best current understanding of beryllium disease and medical diagnostic tests available. (4) Site-specific safety procedures for all processes of beryllium that is likely to generate dusts, mists, fumes, or small particulates. A beryllium exposure control program should minimize airborne concentrations, the potential for and spread of contamination, the number of times individuals are exposed to beryllium, and the number of employees who may be potentially exposed.

  15. Coking properties of perhydrous low-rank vitrains. Influence of pyrolysis conditions

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    generally lead to increased coking potential of coals characterised in the resulting cokes by large sizes equivalent to natural coking coals, since the cokes from these residues are always made of smaller MOD than those obtained for coking coals. For comparison, a similar characterisation, carried out

  16. The Corrosion / Electrochemistry of Beryllium and Beryllium Weldments in Aqueous Chloride Environments

    E-Print Network [OSTI]

    The Corrosion / Electrochemistry of Beryllium and Beryllium Weldments in Aqueous Chloride Environments submitted by: Mary Ann Hill, Darryl P. Butt, R. Scott Lillard Materials Corrosion year. Our goals for FY '96 were two-fold: 1) develop a sensor for monitoring the corrosion of beryllium

  17. Beryllium Use in the Advanced Test Reactor

    SciTech Connect (OSTI)

    Glen R. Longhurst

    2007-12-01T23:59:59.000Z

    The Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL) began operation in 1967. It makes use of a unique serpentine fuel core design and a beryllium reflector. Reactor control is achieved with rotating beryllium cylinders to which have been fastened plates of hafnium. Over time, the beryllium develops rather high helium content because of nuclear transmutations and begins to swell. The beryllium must be replaced at nominally 10-year intervals. Determination of when the replacement is made is by visual observation using a periscope to examine the beryllium surface for cracking and swelling. Disposition of the irradiated beryllium was once accomplished in the INL’s Radioactive Waste Management Complex, but that is no longer possible. Among contributing reasons are high levels of specific radioactive contaminants including transuranics. The INL is presently considering disposition pathways for this irradiated beryllium, but presently is storing it in the canal adjacent to the reactor. Numerous issues are associated with this situation including (1) Is there a need for ultra-low uranium material? (2) Is there a need to recover tritium from irradiated beryllium either because this is a strategic material resource or in preparation for disposal? (3) Is there a need to remove activation and fission products from irradiated beryllium? (4) Will there be enough material available to meet requirements for research reactors (fission and fusion)? In this paper will be discussed the present status of considerations on these issues.

  18. MANAGING BERYLLIUM IN NUCLEAR FACILITY APPLICATIONS

    SciTech Connect (OSTI)

    R. Rohe; T. N. Tranter

    2011-12-01T23:59:59.000Z

    Beryllium plays important roles in nuclear facilities. Its neutron multiplication capability and low atomic weight make it very useful as a reflector in fission reactors. Its low atomic number and high chemical affinity for oxygen have led to its consideration as a plasma-facing material in fusion reactors. In both applications, the beryllium and the impurities in it become activated by neutrons, transmuting them to radionuclides, some of which are long-lived and difficult to dispose of. Also, gas production, notably helium and tritium, results in swelling, embrittlement, and cracking, which means that the beryllium must be replaced periodically, especially in fission reactors where dimensional tolerances must be maintained. It has long been known that neutron activation of inherent iron and cobalt in the beryllium results in significant {sup 60}Co activity. In 2001, it was discovered that activation of naturally occurring contaminants in the beryllium creates sufficient {sup 14}C and {sup 94}Nb to render the irradiated beryllium 'Greater-Than-Class-C' for disposal in U.S. radioactive waste facilities. It was further found that there was sufficient uranium impurity in beryllium that had been used in fission reactors up to that time that the irradiated beryllium had become transuranic in character, making it even more difficult to dispose of. In this paper we review the extent of the disposal issue, processes that have been investigated or considered for improving the disposability of irradiated beryllium, and approaches for recycling.

  19. Table 23. Coal Receipts at Coke Plants by Census Division

    U.S. Energy Information Administration (EIA) Indexed Site

    Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2014 Table 23. Coal Receipts at Coke Plants by Census Division...

  20. Reducing power production costs by utilizing petroleum coke. Annual report

    SciTech Connect (OSTI)

    Galbreath, K.C.

    1998-07-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  1. The methods of steam coals usage for coke production

    SciTech Connect (OSTI)

    Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

    1998-07-01T23:59:59.000Z

    Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

  2. ORISE: Worker Health Studies - Testing Beryllium Vendor Populations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oak Ridge Institute for Science Education Beryllium Testing Vendor Populations When former employees at 25 closed U.S. Department of Energy (DOE) beryllium vendor companies needed...

  3. Sandia National Laboratories: Beryllium High Heat Flux Testing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    system, controls, and blast gun) is now used for electron beam test system vacuum vessel beryllium decontamination and has shortened the beryllium clean-up procedure from...

  4. Reducing Energy Consumption on Process Ovens & Oxidation Systems

    E-Print Network [OSTI]

    Worachek, C.

    recovery systems are capable of metals in the heat exchangers along with stresses recovering up to 97% of the energy used in the induced by changing process conditions can oxidation process. Most units on the market severely reduce the life...REDUCING ENERGY CONSUMPTION ON PROCESS OVENS & OXIDATION SYSTEMS Chris Worachek Design Engineer MEGTEC Systems De Pere, WI ABSTRACT With the uncertain cost of energy, optimizing the use of air in process dryers, ovens and air pollution...

  5. DELAYED COKING OF SOLVENT EXTRACTED COAL FOR PRODUCTION OF ANODE GRADE COKE: CHARACTERIZATION OF SOLID AND LIQUID PRODUCTS.

    E-Print Network [OSTI]

    Karri, Vamsi

    2011-01-01T23:59:59.000Z

    ??This study investigates the feasibility of using high temperature solvent extraction of coal to produce feedstock for the production of anode grade coke through delayed… (more)

  6. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    Broader source: Energy.gov [DOE]

    Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

  7. PITTSBURGH REGIONAL ENVIRONMENTAL THREATS ANALYSIS

    E-Print Network [OSTI]

    Jiang, Huiqiang

    .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 Coke Oven Emissions.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 Carbon Tetrachloride.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 Acetaldehyde

  8. Dry purification of aspirational air in coke-sorting systems with wet slaking of coke

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

  9. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs

    E-Print Network [OSTI]

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  10. Process for synthesis of beryllium chloride dietherate

    DOE Patents [OSTI]

    Bergeron, Charles (Baton Rouge, LA); Bullard, John E. (Kendall Park, NJ); Morgan, Evan (Lynchburg, VA)

    1991-01-01T23:59:59.000Z

    A low temperature method of producing beryllium chloride dietherate through the addition of hydrogen chloride gas to a mixture of beryllium metal in ether in a reaction vessel is described. A reflux condenser provides an exit for hydrogen produced form the reaction. A distillation condenser later replaces the reflux condenser for purifying the resultant product.

  11. BERYLLIUM MEASUREMENT IN COMMERCIALLY AVAILABLE WET WIPES

    SciTech Connect (OSTI)

    Youmans-Mcdonald, L.

    2011-02-18T23:59:59.000Z

    Analysis for beryllium by fluorescence is now an established method which is used in many government-run laboratories and commercial facilities. This study investigates the use of this technique using commercially available wet wipes. The fluorescence method is widely documented and has been approved as a standard test method by ASTM International and the National Institute for Occupational Safety and Health (NIOSH). The procedure involves dissolution of samples in aqueous ammonium bifluoride solution and then adding a small aliquot to a basic hydroxybenzoquinoline sulfonate fluorescent dye (Berylliant{trademark} Inc. Detection Solution Part No. CH-2) , and measuring the fluorescence. This method is specific to beryllium. This work explores the use of three different commercial wipes spiked with beryllium, as beryllium acetate or as beryllium oxide and subsequent analysis by optical fluorescence. The effect of possible interfering metals such as Fe, Ti and Pu in the wipe medium is also examined.

  12. Postirradiation examination of beryllium pebbles

    SciTech Connect (OSTI)

    Gelles, D.S. [Pacific Northwest National Lab., Richland, WA (United States)

    1998-03-01T23:59:59.000Z

    Postirradiation examinations of COBRA-1A beryllium pebbles irradiated in the EBR-II fast reactor at neutron fluences which generated 2700--3700 appm helium have been performed. Measurements included density change, optical microscopy, scanning electron microscopy, and transmission electron microscopy. The major change in microstructure is development of unusually shaped helium bubbles forming as highly non-equiaxed thin platelet-like cavities on the basal plane. Measurement of the swelling due to cavity formation was in good agreement with density change measurements.

  13. Beryllium Program Information - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I.Program Information About Us Beryllium Program

  14. THE IDAHO NATIONAL LABORATORY BERYLLIUM TECHNOLOGY UPDATE

    SciTech Connect (OSTI)

    Glen R. Longhurst

    2007-12-01T23:59:59.000Z

    A Beryllium Technology Update meeting was held at the Idaho National Laboratory on July 18, 2007. Participants came from the U.S., Japan, and Russia. There were two main objectives of this meeting. One was a discussion of current technologies for beryllium in fission reactors, particularly the Advanced Test Reactor and the Japan Materials Test Reactor, and prospects for material availability in the coming years. The second objective of the meeting was a discussion of a project of the International Science and Technology Center regarding treatment of irradiated beryllium for disposal. This paper highlights discussions held during that meeting and major conclusions reached

  15. Coke formation during pyrolysis of 1,2-dichloroethane

    SciTech Connect (OSTI)

    Holmen, A. [Norwegian Institute of Technology, Trondheim (Norway); Lindvag, O.A. [SINTEF Applied Chemistry, Trondheim (Norway)

    1995-12-31T23:59:59.000Z

    Most processes involving hydrocarbons or carbon oxides at high temperatures suffer from the disadvantage of coke formation. The formation of coke deposits during pyrolysis of hydrocarbons or chlorinated hydrocarbons is of significant practical importance. Examples of such processes are the steam cracking of alkanes to produce olefins and the thermal decomposition of 1,2-dichloroethane (EDC) for the production of vinyl chloride monomer (VCM). Even id the rate of coke production is low, the cumulative nature of the solid product will result in reactor fouling. The present work deals with the thermal decomposition of EDC. Coke formation has been studied on metal surfaces in a quartz tubular reactor. The rate of coke deposition was measures on metal foils hanging from one arm of a microbalance. A complete analysis of the product gas was accomplished using on-line gas chromatography. The results show that coke deposition during thermal decomposition of EDC depends on the composition of the feed as well as on the nature of the surface of the metal foil. Small amounts of other components (contamination with other chlorinated hydrocarbons as an example) may have a large influence on the rate of coke formation. The results are discussed in terms of surface composition/morphology of the metal foil and the free radical mechanism for thermal decomposition of FDC.

  16. Testing of the Burns-Milwaukee`s Sun Oven

    SciTech Connect (OSTI)

    Moss, T.A.

    1997-03-01T23:59:59.000Z

    A Burns-Milwaukee Sun Oven was tested at Sandia`s Solar Thermal Test Facility. It was instrumented with five type K thermocouples to determine warm-up rates when empty and when a pot containing two liters of water was placed inside. It reached inside air temperatures above 160{degrees}C (320{degrees}F). It heated two liters of water from room temperatures to 80{degrees}C, (175{degrees}F), in 75 minutes. Observations were also made on the cooling and reheating rates during a cloud passage. The adverse effects of wind on operation of the solar oven was also noted.

  17. Method for removal of furfural coke from metal surfaces

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-27T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating ship furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas with a total pressure of less than 100 psig containing molecular oxygen. The gas being at a sufficient temperature below 800{degrees}F. (427{degrees}C.) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of about 5000 psi.

  18. Chronic Beryllium Disease Prevention Program Report

    SciTech Connect (OSTI)

    Lee, S

    2012-03-29T23:59:59.000Z

    This document describes how Lawrence Livermore National Laboratory (LLNL) meets the requirements and management practices of federal regulation 10 CFR 850, 'Chronic Beryllium Disease Prevention Program (CBDPP).' This revision of the LLNL CBDPP incorporates clarification and editorial changes based on lessons learned from employee discussions, observations and reviews of Department of Energy (DOE) Complex and commercial industry beryllium (Be) safety programs. The information is used to strengthen beryllium safety practices at LLNL, particularly in the areas of: (1) Management of small parts and components; and (2) Communication of program status to employees. Future changes to LLNL beryllium activities and on-going operating experience will be incorporated into the program as described in Section S, 'Performance Feedback.'

  19. Polymer Surface Modification Using Microwave-Oven-Generated Plasma

    E-Print Network [OSTI]

    Steinbock, Oliver

    , diameter 160 mm) are from Fisher Scientific. Compressed oxygen and ethanol (100%) are from Air Products with plasma is a frequently used technique to accomplish surface modifi- cations that affect chemical products. Our approach relies on an unmodified "kitchen microwave oven" and standard laboratory glassware

  20. Process Parameters and Energy Use of Gas and Electric Ovens in Industrial Applications

    E-Print Network [OSTI]

    Kosanovic, D.; Ambs, L.

    for industrial applications where electric ovens have predominant use. Tests were performed to obtain the process efficiency and examine cost savings potential in converting electric ovens to natural gas. Preliminary results show that, for the plat studied, cost...

  1. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

    2003-06-01T23:59:59.000Z

    Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

  2. Chronic beryllium disease: Diagnosis and management

    SciTech Connect (OSTI)

    Rossman, M.D. [Hospital of the Univ. of Pennsylvania, Philadelphia, PA (United States)

    1996-10-01T23:59:59.000Z

    Chronic beryllium disease is predominantly a pulmonary granulomatosis that was originally described in 1946. Symptoms usually include dyspnea and cough. Fever, anorexia, and weight loss are common. Skin lesions are the most common extrathoracic manifestation. Granulomatous hepatitis, hypercalcemia, and kidney stones can also occur. Radiographic and physiologic abnormalities are similar to those in sarcoidosis. While traditionally the pathologic changes included granulomas and cellular interstitial changes, the hallmark of the disease today is the well-formed granuloma. Immunologic studies have demonstrated a cell-mediated response to beryllium that is due to an accumulation of CD4{sup +} T cells at the site of disease activity. Diagnosis depends on the demonstration of pathologic changes (i.e., granuloma) and evidence that the granuloma was caused by a hypersensitivity to beryllium (i.e., positive lung proliferative response to beryllium). Using these criteria, the diagnosis of chronic beryllium disease can now be made before the onset of clinical symptoms. Whether, with early diagnosis, the natural course of this condition will be the same as when it was traditionally diagnosed is not known. Currently, corticosteroids are used to treat patients with significant symptoms or evidence of progressive disease. 21 refs.

  3. Analysis of tritium transport in irradiated beryllium

    SciTech Connect (OSTI)

    Cho, S.; Abdou, M.A. [Univ. of California, Los Angeles, CA (United States)

    1994-12-31T23:59:59.000Z

    Analysis of the beryllium tritium release results with simple analytical models indicated that tritium behavior in Be is not dominated by one simple mechanism, but by a combination of several mechanisms including surface processes and helium bubbles. A model was developed and the initial version of the model included tritium diffusion in the beryllium and the beryllium oxide, second order desorption at the solid/gas interface and diffusion through interconnected porosity. Fundamental data, tritium diffusion and desorption coefficients for Be and BeO, were derived from experimental data using the model. Beryllium is a metal to which one can generally apply the concepts of diffusion, solubility, surface processes and traps. Tritium transport in the irradiated beryllium is affected by processes occurring in the bulk, He bubbles, the bulk/surface and surface/gas interfaces. There are two types of solid/gas surfaces in the irradiated Be. One is the surface at the pure Be/He bubble interface where no oxide layer exists and the other is the surface at the BeO layer/purge gas interface. Although the material characteristics of the Be and BeO layer are different and have different activation barriers, the surface processes can be applied to both interfaces.

  4. Prediction of metallurgical coke strength from the petrographic composition of coal blends

    SciTech Connect (OSTI)

    Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

    2009-07-01T23:59:59.000Z

    Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

  5. Summary of beryllium specifications, current and historical

    SciTech Connect (OSTI)

    Abeln, S.P.; Kyed, P.

    1990-12-28T23:59:59.000Z

    This report summarizes beryllium properties included in producer, Department of Energy, and government specifications. The specifications are divided into two major categories: current and historical. Within each category the data are arranged primarily according to increasing purity and secondarily by increasing tensile properties. Qualitative comments on formability and weldability are included. Also, short summaries of powder production and consolidation techniques are provided.

  6. Testing of the Sunstove Organization`s Sunstove Solar Oven

    SciTech Connect (OSTI)

    Moss, T.A.

    1997-03-01T23:59:59.000Z

    A Sunstove Organization`s Sunstove was tested at Sandia`s Solar Thermal Test Facility. It was instrumented with five type K thermocouples to determine warm-up rates when empty and when a pot containing two liters of water was placed inside. It reached inside air temperatures above 115{degrees}C (240{degrees}F). It heated two liters of water from room temperature to 80{degrees}C (175{degrees}F) in about two hours. Observations were made on the cooling and reheating rates during a cloud passage. The adverse effects of wind on the operation of the solar oven were also noted.

  7. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

    1994-01-01T23:59:59.000Z

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  8. Coke profile and effect on methane/ethylene conversion process

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to catalyst deactivation. A fixed bed reactor was used to conduct this investigation. A series of runs were...

  9. Neutron irradiation of beryllium: Recent Russian results

    SciTech Connect (OSTI)

    Gelles, D.S. [Pacific Northwest Lab., Richland, VA (United States)

    1992-12-31T23:59:59.000Z

    Results on postirradiation tensile and compression testing, swelling and bubble growth during annealing for various grades of beryllium are presented. It is shown that swelling at temperatures above 550{degrees}C is sensitive to material condition and response is correlated with oxygen content. Swelling on the order of 15% can be expected at 700{degrees}C for doses on the order of 10{sup 22} n/cm{sup 2}. Bubble growth response depends on irradiation fluence.

  10. Neutron counter based on beryllium activation

    SciTech Connect (OSTI)

    Bienkowska, B.; Prokopowicz, R.; Kaczmarczyk, J.; Paducha, M. [Institute of Plasma Physics and Laser Microfusion (IPPLM), Hery 23, 01-497 Warsaw (Poland); Scholz, M.; Igielski, A. [Institute of Nuclear Physics PAS (IFJPAN), Radzikowskiego 152, 31-342 Krakow (Poland); Karpinski, L. [Faculty of Electrical Engineering, Rzeszow University of Technology, Pola 2, 35-959 Rzeszow (Poland); Pytel, K. [National Centre for Nuclear Research (NCBJ), Soltana 7, 05-400 Otwock - Swierk (Poland)

    2014-08-21T23:59:59.000Z

    The fusion reaction occurring in DD plasma is followed by emission of 2.45 MeV neutrons, which carry out information about fusion reaction rate and plasma parameters and properties as well. Neutron activation of beryllium has been chosen for detection of DD fusion neutrons. The cross-section for reaction {sup 9}Be(n, ?){sup 6}He has a useful threshold near 1 MeV, which means that undesirable multiple-scattered neutrons do not undergo that reaction and therefore are not recorded. The product of the reaction, {sup 6}He, decays with half-life T{sub 1/2} = 0.807 s emitting ?{sup ?} particles which are easy to detect. Large area gas sealed proportional detector has been chosen as a counter of ?–particles leaving activated beryllium plate. The plate with optimized dimensions adjoins the proportional counter entrance window. Such set-up is also equipped with appropriate electronic components and forms beryllium neutron activation counter. The neutron flux density on beryllium plate can be determined from the number of counts. The proper calibration procedure needs to be performed, therefore, to establish such relation. The measurements with the use of known ?–source have been done. In order to determine the detector response function such experiment have been modeled by means of MCNP5–the Monte Carlo transport code. It allowed proper application of the results of transport calculations of ?{sup ?} particles emitted from radioactive {sup 6}He and reaching proportional detector active volume. In order to test the counter system and measuring procedure a number of experiments have been performed on PF devices. The experimental conditions have been simulated by means of MCNP5. The correctness of simulation outcome have been proved by measurements with known radioactive neutron source. The results of the DD fusion neutron measurements have been compared with other neutron diagnostics.

  11. Beryllium-7 labeled carbon particles and method of making

    DOE Patents [OSTI]

    Richards, P.; Mausner, L.F.; Prach, T.F.

    1987-11-17T23:59:59.000Z

    Beryllium-7 labeled carbon particles made from the proton irradiation of carbon materials, preferably from dry carbon black are disclosed. Such particles are useful as gamma emitting radiotracers.

  12. Beryllium-7 labeled carbon particles and method of making

    DOE Patents [OSTI]

    Richards, P.; Mausner, L.F.; Prach, T.F.

    1985-04-29T23:59:59.000Z

    Beryllium-7 labeled carbon particles made from the proton irradiation of carbon materials, preferably from dry carbon black are disclosed. Such particles are useful as gamma emitting radiotracers.

  13. Beryllium-7 labeled carbon particles and method of making

    DOE Patents [OSTI]

    Richards, Powell (New Bern, NC); Mausner, Leonard F. (Stony Brook, NY); Prach, Thomas F. (Port Jefferson, NY)

    1987-01-01T23:59:59.000Z

    Beryllium-7 labeled carbon particles made from the proton irradiation of carbon materials, preferably from dry carbon black are disclosed. Such particles are useful as gamma emitting radiotracers.

  14. A compact and efficient strontium oven for laser-cooling experiments

    E-Print Network [OSTI]

    Marco Schioppo; Nicola Poli; Marco Prevedelli; Stephan Falke; Christian Lisdat; Uwe Sterr; Guglielmo Maria Tino

    2012-09-25T23:59:59.000Z

    Here we describe a compact and efficient strontium oven well suited for laser-cooling experiments. Novel design solutions allowed us to produce a collimated strontium atomic beam with a flux of 1.0\\times10^13 s^-1 cm^-2 at the oven temperature of 450 {\\deg}C, reached with an electrical power consumption of 36 W. The oven is based on a stainless-steel reservoir, filled with 6 g of metallic strontium, electrically heated in a vacuum environment by a tantalum wire threaded through an alumina multi-bore tube. The oven can be hosted in a standard DN40CF cube and has an estimated continuous operation lifetime of 10 years. This oven can be used for other alkali and alkaline earth metals with essentially no modifications.

  15. A compact and efficient strontium oven for laser-cooling experiments

    E-Print Network [OSTI]

    Schioppo, Marco; Prevedelli, Marco; Falke, Stephan; Lisdat, Christian; Sterr, Uwe; Tino, Guglielmo Maria

    2012-01-01T23:59:59.000Z

    Here we describe a compact and efficient strontium oven well suited for laser-cooling experiments. Novel design solutions allowed us to produce a collimated strontium atomic beam with a flux of 1.0\\times10^13 s^-1 cm^-2 at the oven temperature of 450 {\\deg}C, reached with an electrical power consumption of 36 W. The oven is based on a stainless-steel reservoir, filled with 6 g of metallic strontium, electrically heated in a vacuum environment by a tantalum wire threaded through an alumina multi-bore tube. The oven can be hosted in a standard DN40CF cube and has an estimated continuous operation lifetime of 10 years. This oven can be used for other alkali and alkaline earth metals with essentially no modifications.

  16. An overview of crisis management in the coke industry

    SciTech Connect (OSTI)

    Saunders, D.A.

    1995-12-01T23:59:59.000Z

    Members of the American Coke and Coal Chemicals Institute (ACCCI), as responsible corporate citizens, have embraced the concepts of crisis management and progress down the various paths of planning and preparation, monitoring, media communications, community outreach, emergency response, and recovery. Many of the concepts outlined here reflect elements of crisis management guidelines developed by the Chemical Manufacturers Association (CMA). At a coke plant, crises can take the form of fires, chemical releases, labor strikes, feedstock supply disruptions, and excessive snowfall, just to name a few. The CMA defines a crisis as: ``an unplanned event that has the potential to significantly impact a company`s operability or credibility, or to pose a significant environment, economic or legal liability``; and crisis management as: ``those activities undertaken to anticipate or prevent, prepare for, respond to and recover from any incident that has the potential to greatly affect the way a company conducts its business.

  17. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA)

    1991-01-01T23:59:59.000Z

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  18. New environmental concepts in the chemical and coke industries

    SciTech Connect (OSTI)

    A.Yu. Naletov; V.A. Naletov [Mendeleev Russian Chemical-Engineering University (Russian Federation)

    2007-05-15T23:59:59.000Z

    We know that environmentally pure technologies do not exist. Coke production is no exception to the rule. The article considers the logic of environmental decision making. Attention focuses on a new bank of ecologically appropriate materials whose release to the biosphere must be considered solely in quantititative terms. Qualitativily all these materials are familiar; they are assimilated by populations of microorganisms and tar thus compatible with the biosphere.

  19. Innovative coke oven gas cleaning system for retrofit applications: Environmental Monitoring Program. Baseline sampling program report: Volume 2, Appendix sections 1--7

    SciTech Connect (OSTI)

    Stuart, L.M.

    1994-05-27T23:59:59.000Z

    This report contains no text. It consist entirely of results monitoring stack opacity, benzene surveys, chemical effluent in wastewater, etc.

  20. How to implement a quality program in a coking plant. The AHMSA experience

    SciTech Connect (OSTI)

    Reyes M, M.A.; Perez, J.L.; Garza, C. de la; Morales, M.

    1995-12-01T23:59:59.000Z

    AHMSA (Altos Hornos de Mexico) is the largest integrated Steel Plant in Mexico, with its 3.1 MMMT of Liquid Steel production program for 1995. AHMSA operates two coke plants which began operations in 1955 and 1976. Total coke monthly production capacity amounts to as much as 106,000 Metric Tons (MT). The coke plants working philosophy was discussed and established in 1986 as part of the Quality Improvement Program, where its ultimate goal is to give the best possible coke quality to its main client--the blast furnaces. With this goal in mind, a planned joint effort with their own coal mines was initiated. This paper deals with the implementation process of the Quality Program, and the results of this commitment at the coal mines, coke plants and blast furnaces. The coke quality improvement is shown since 1985 to 1994, as well as the impact on the blast furnace operation.

  1. Low-coke rate operation under high PCI at Kobe No. 3 BF

    SciTech Connect (OSTI)

    Matsuo, Tadasu; Kanazuka, Yasuo; Hoshino, Koichi; Yoshida, Yasuo; Kitayama, Syuji; Ishiwaki, Shiro [Kobe Steel Ltd. (Japan). Kobe Works

    1997-12-31T23:59:59.000Z

    Kobe No. 3 blast furnace (BF) suffered tremendous damage when the Great Hanshin-Awaji Earthquake rocked the area on January 17, 1995. However, working as quickly as possible to dig out of the burden and rehabilitate various facilities, the company managed to restart the No. 3 BF on April 2. After the restart, which went smoothly, production was shifted into the low coke rate operation which was being promoted before the disaster. In October, 1995, only seven months after the restart, the nation record of 296 kg/t low coke rate could be achieved. Subsequently, in January, 1996, coke rate reached 290 kg/t and the low coke rate operation was renewed. Since that time the same level of coke rate has been maintained. The paper discusses how low coke rate operation was achieved.

  2. Hydrodynamic instabilities in beryllium targets for the National Ignition Facility

    SciTech Connect (OSTI)

    Yi, S. A., E-mail: austinyi@lanl.gov; Simakov, A. N.; Wilson, D. C.; Olson, R. E.; Kline, J. L.; Batha, S. H. [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico 87545 (United States); Clark, D. S.; Hammel, B. A.; Milovich, J. L.; Salmonson, J. D.; Kozioziemski, B. J. [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States)

    2014-09-15T23:59:59.000Z

    Beryllium ablators offer higher ablation velocity, rate, and pressure than their carbon-based counterparts, with the potential to increase the probability of achieving ignition at the National Ignition Facility (NIF) [E. I. Moses et al., Phys. Plasmas 16, 041006 (2009)]. We present here a detailed hydrodynamic stability analysis of low (NIF Revision 6.1) and high adiabat NIF beryllium target designs. Our targets are optimized to fully utilize the advantages of beryllium in order to suppress the growth of hydrodynamic instabilities. This results in an implosion that resists breakup of the capsule, and simultaneously minimizes the amount of ablator material mixed into the fuel. We quantify the improvement in stability of beryllium targets relative to plastic ones, and show that a low adiabat beryllium capsule can be at least as stable at the ablation front as a high adiabat plastic target.

  3. Beryllium Program Performance Assessments - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I.Program Information About Us Beryllium

  4. Beryllium Program Points of Contact - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I.Program Information About Us BerylliumProgram

  5. The effects of ash and maceral composition of Azdavay and Kurucasile (Turkey) coals on coking properties

    SciTech Connect (OSTI)

    Toroglu, I. [Zonguldak Karaelmas University, Zonguldak (Turkey). Faculty of Engineering

    2006-07-01T23:59:59.000Z

    In this study, investigations were made as to the effect of the maceral compositions and mineral matter content of Azdavay and Kurucasile coals on the coking property. Chemical and maceral analyses and coking properties were determined for the products of the float-sink procedure. The coking properties were established on the basis of free swelling index and Ruhr dilatometer tests. Maceral analyses showed that as the ash content of a coal containing both high and medium volatile matter increases, its effective maceral proportion decreases, and the coking property is affected in an unfavorable way.

  6. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1980-01-01T23:59:59.000Z

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  7. The effect of diabietic acid on the coking of oxidised solvent-extracted coal.

    E-Print Network [OSTI]

    Ludere, Margaret Tshimangadzo

    2008-01-01T23:59:59.000Z

    ??Refcoal is a refined carbon source obtained by extraction of coal with dimethylformamide (DMF). During the coking process, Refcoal goes through a mesophase (fluid) stage… (more)

  8. Lignin as Both Fuel and Fusing Binder in Briquetted Anthracite Fines for Foundry Coke Substitute.

    E-Print Network [OSTI]

    Lumadue, Matthew

    2012-01-01T23:59:59.000Z

    ??Lignin that had been extracted from Kraft black liquor was investigated as a fusing binder in briquetted anthracite fines for a foundry coke substitute. Cupola… (more)

  9. Acoustic emission feedback control for control of boiling in a microwave oven

    DOE Patents [OSTI]

    White, Terry L. (Oak Ridge, TN)

    1991-01-01T23:59:59.000Z

    An acoustic emission based feedback system for controlling the boiling level of a liquid medium in a microwave oven is provided. The acoustic emissions from the medium correlated with surface boiling is used to generate a feedback control signal proportional to the level of boiling of the medium. This signal is applied to a power controller to automatically and continuoulsly vary the power applied to the oven to control the boiling at a selected level.

  10. CHARACTERIZATION OF COAL- AND PETROLEUM-DERIVED BINDER PITCHES AND THE INTERACTION OF PITCH/COKE MIXTURES IN PRE-BAKED CARBON ANODES.

    E-Print Network [OSTI]

    Suriyapraphadilok, Uthaiporn

    2008-01-01T23:59:59.000Z

    ??Carbon anodes are manufactured from calcined petroleum coke (i.e. sponge coke) and recycled anode butts as fillers, and coal tar pitch (SCTP) as the binder.… (more)

  11. Radiation effects in beryllium used for plasma protection

    SciTech Connect (OSTI)

    Gelles, D.S. [Pacific Northwest Lab., Richland, WA (United States); Dalle Donne, M. [Kernforschungszentrum Karlsruhe (Germany); Sernyaev, G.A. [SF NIKIET, Zarechnyi (Russian Federation); Kawamura, H. [Japan Atomic Energy Research Inst., Oarai, Ibaraki (Japan). Blanket Irradiation and Analysis Lab.

    1993-09-01T23:59:59.000Z

    Beryllium is presently a leading candidate material for fusion reactor first wall coating and divertor applications. This paper reviews the literature on beryllium, emphasizing the effects of irradiation on essential properties. Swelling and embrittlement experiments as a function of irradiation temperature and dose, and as a function of neutron spectrum are described, and the results are quantified, where possible. Effects of impurity content are also reported, from which optimum composition specifications can be defined. Microstructural information has also been obtained to elucidate the processes controlling the property changes. The available information indicates that beryllium divertors can be expected to embrittle quickly and may need frequent replacement.

  12. Teamwork in planning and carrying out the first inspection of the coke dry quenching (CDQ) plant of the Kaiserstuhl Coking Facility

    SciTech Connect (OSTI)

    Burchardt, G.

    1996-12-31T23:59:59.000Z

    The coke plant Kaiserstuhl operates a coke dry quenching (CDQ) plant with a downstream installed waste heat boiler to satisfy statutory pollution control rules and requirements. This CDQ which went on stream in March 1993 cools the whole coke production output from the Kaiserstuhl coke plant in counterflow to an inert cooling gas. This brief overview on the whole CDQ plant should elucidate the complex of problems posed when trying to make an exact plant revision plan. After all it was impossible to evaluate or to assess all the interior process technology relevant components during the planning stage as the plant was in operation. The revision data for the first interior check was determined and fixed by the statutory rule for steam boilers and pressure vessels. The relevant terms for this check are mandatorily prescribed. In liaison with the testing agency (RW TUEV) the date for the first revision was fixed for April 1995, that means two years after the first commissioning.

  13. Influence of coal on coke properties and blast-furnace operation

    SciTech Connect (OSTI)

    G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

    2007-07-01T23:59:59.000Z

    With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

  14. Analytical input-output and supply chain study of China's coke and steel sectors

    E-Print Network [OSTI]

    Li, Yu, 1976-

    2004-01-01T23:59:59.000Z

    I design an input-output model to investigate the energy supply chain of coal-coke-steel in China. To study the demand, supply, and energy-intensity issues for coal and coke from a macroeconomic perspective, I apply the ...

  15. Status Report, Department of Energy's Chronic Beryllium Disease...

    Broader source: Energy.gov (indexed) [DOE]

    of 10 C.F.R. Part 850, Chronic Beryllium Disease Prevention Program, at the Department of Energy (DOE). The report is based on the results of evaluations of the effectiveness of...

  16. Development of pressurized tube specimen for creep testing of beryllium

    SciTech Connect (OSTI)

    Neef, W.S.; Moir, R.W. (Lawrence Livermore National Lab., CA (USA)); Opperman, E.K. (Westinghouse Hanford Co., Richland, WA (USA)); Hamilton, M.L. (Pacific Northwest Lab., Richland, WA (USA))

    1990-12-01T23:59:59.000Z

    The purpose of this work was to demonstrate that creep tests could be performed on beryllium in the same pressurized tube geometry as is commonly used in the FFTF/MOTA.

  17. Development of Biomarkers for Chronic Beryllium Disease in Mice

    SciTech Connect (OSTI)

    Gordon, Terry

    2013-01-25T23:59:59.000Z

    Beryllium is a strategic metal, indispensable for national defense programs in aerospace, telecommunications, electronics, and weaponry. Exposure to beryllium is an extensively documented occupational hazard that causes irreversible, debilitating granulomatous lung disease in as much as 3 - 5% of exposed workers. Mechanistic research on beryllium exposure-disease relationships has been severely limited by a general lack of a sufficient CBD animal model. We have now developed and tested an animal model which can be used for dissecting dose-response relationships and pathogenic mechanisms and for testing new diagnostic and treatment paradigms. We have created 3 strains of transgenic mice in which the human antigen-presenting moiety, HLA-DP, was inserted into the mouse genome. Each mouse strain contains HLA-DPB1 alleles that confer different magnitude of risk for chronic beryllium disease (CBD): HLA-DPB1*0401 (odds ratio = 0.2), HLA-DPB1*0201 (odds ratio = 15), HLA-DPB1*1701 (odds ratio = 240). Our preliminary work has demonstrated that the *1701 allele, as predicted by human studies, results in the greatest degree of sensitization in a mouse ear swelling test. We have also completed dose-response experiments examining beryllium-induced lung granulomas and identified susceptible and resistant inbred strains of mice (without the human transgenes) as well as quantitative trait loci that may contain gene(s) that modify the immune response to beryllium. In this grant application, we propose to use the transgenic and Â?normal inbred strains of mice to identify biomarkers for the progression of beryllium sensitization and CBD. To achieve this goal, we propose to compare the sensitivity and accuracy of the lymphocyte proliferation test (blood and bronchoalveolar lavage fluid) with the ELISPOT test in the three HLA-DP transgenic mice strains throughout a 6 month treatment with beryllium particles. Because of the availability of high-throughput proteomics, we will also identify changes in potential protein biomarkers in beryllium-treated mice. We will correlate these findings with the ability of the transgenic mice to develop a beryllium-specific adaptive immune response in blood and bronchoalveolar lavage (BAL) fluid. We will also determine whether beryllium-responsive CD4+ T cells in blood and BAL correlate with the onset of granuloma formation. Thus, we will provide the scientific community with biomarkers of sensitization and disease progression for CBD. These biomarkers will serve as critical tools for development of improved industrial hygiene and therapeutic interventions.

  18. 2013 Beryllium-Associated Worker Registry Summary | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustionImprovement3 Beryllium-Associated Worker Registry Summary 2013 Beryllium-Associated Worker

  19. Beryllium pressure vessels for creep tests in magnetic fusion energy

    SciTech Connect (OSTI)

    Neef, W.S.

    1990-07-20T23:59:59.000Z

    Beryllium has interesting applications in magnetic fusion experimental machines and future power-producing fusion reactors. Chief among the properties of beryllium that make these applications possible is its ability to act as a neutron multiplier, thereby increasing the tritium breeding ability of energy conversion blankets. Another property, the behavior of beryllium in a 14-MeV neutron environment, has not been fully investigated, nor has the creep behavior of beryllium been studied in an energetic neutron flux at thermodynamically interesting temperatures. This small beryllium pressure vessel could be charged with gas to test pressures around 3, 000 psi to produce stress in the metal of 15,000 to 20,000 psi. Such stress levels are typical of those that might be reached in fusion blanket applications of beryllium. After contacting R. Powell at HEDL about including some of the pressure vessels in future test programs, we sent one sample pressure vessel with a pressurizing tube attached (Fig. 1) for burst tests so the quality of the diffusion bond joints could be evaluated. The gas used was helium. Unfortunately, budget restrictions did not permit us to proceed in the creep test program. The purpose of this engineering note is to document the lessons learned to date, including photographs of the test pressure vessel that show the tooling necessary to satisfactorily produce the diffusion bonds. This document can serve as a starting point for those engineers who resume this task when funds become available.

  20. Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil

    SciTech Connect (OSTI)

    Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

    2009-05-15T23:59:59.000Z

    In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

  1. Development of a high-temperature oven for the 28 GHz electron cyclotron resonance ion source

    SciTech Connect (OSTI)

    Ohnishi, J., E-mail: ohnishi@riken.jp; Higurashi, Y.; Kidera, M.; Ozeki, K.; Nakagawa, T. [RIKEN Nishina Center, Wako, Saitama 351-0198 (Japan)] [RIKEN Nishina Center, Wako, Saitama 351-0198 (Japan)

    2014-02-15T23:59:59.000Z

    We have been developing the 28 GHz ECR ion source in order to accelerate high-intensity uranium beams at the RIKEN RI-beam Factory. Although we have generated U{sup 35+} beams by the sputtering method thus far, we began developing a high-temperature oven with the aim of increasing and stabilizing the beams. Because the oven method uses UO{sub 2}, a crucible must be heated to a temperature higher than 2000?°C to supply an appropriate amount of UO{sub 2} vapor to the ECR plasma. Our high-temperature oven uses a tungsten crucible joule-heated with DC current of approximately 450 A. Its inside dimensions are ?11 mm × 13.5 mm. Since the crucible is placed in a magnetic field of approximately 3 T, it is subject to a magnetic force of approximately 40 N. Therefore, we used ANSYS to carefully design the crucible, which was manufactured by machining a tungsten rod. We could raise the oven up to 1900?°C in the first off-line test. Subsequently, UO{sub 2} was loaded into the crucible, and the oven was installed in the 28 GHz ECR ion source and was tested. As a result, a U{sup 35+} beam current of 150 ?A was extracted successfully at a RF power of approximately 3 kW.

  2. Investigation of the effects of heating rate on coking of shale during retorting

    SciTech Connect (OSTI)

    Guffey, F.D.; Hunter, D.E.

    1988-02-01T23:59:59.000Z

    The retorting of oil shale distributes organic carbon among three possible products: the liquid product, the noncondensible product, and the residual carbon (coke). The production of coke is detrimental because of the economic effects caused by the loss of organic carbon to this relatively intractable carbon form. Two reference oil shales, a Mahogany zone, Parachute Creek Member, Green River Formation oil shale from Colorado and a Clegg Creek Member, New Albany oil shale from Kentucky, were studied to evaluate the conditions that affect coke production during retorting. The variable that was studied in these experiments was the heating rate during retorting because heating rate has been indicated to have a direct effect on coke production (Burnham and Clarkson 1980). The six heating rates investigated covered the range from 1 to 650/degree/C/h (1.8 to 1169/degree/F/h). The data collected during these experiments were evaluated statistically in order to identify trends. The data for the eastern reference oil shale indicated a decrease in coke formation with increases in the heating rate. The liquid and noncondensible product yields both increased with increasing heating rate. The distribution of products in relation to retort heating rate follows the model suggested by Burnham and Clarkson (1980). Coke production during the retorting of western reference oil shale was found to be constant in relation to heating rate. The liquid product yield increased with increasing heating rate but the trend could not be verified at the 95% confidence level. The coke production observed in these experiments does not follow the prediction of the model. This may indicate that coke formation occurs early in the retorting process and may be limited by the availability of organic materials that form coke. 6 refs., 10 tabs.

  3. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A. (National Research Council of Canada, Ottawa, ON (Canada). Div. of Chemistry)

    1989-01-01T23:59:59.000Z

    Ash reduction of the cokes and fly ash samples derived from the Athabasca oil sands bitumen was attempted by dissolving the mineral matter in acids. The samples used for this investigation included Syncrude fluid coking coke, Suncor delayed coking coke and the two fly ash samples obtained from the combustion of these cokes. All samples were analyzed for C,H,N,O, and S before and after acid demineralization and the analyses results compared. Further, the ash from the samples before and after acid demineralization was analyzed for silica, alumina, iron titanium, nickel and vanadium to assess the acid leaching of these elements. CP/MAS, /sup 13/C NMR spectroscopic study of the demineralized coke and fly ash samples was also attempted.

  4. Controlling Beryllium Contaminated Material And Equipment For The Building 9201-5 Legacy Material Disposition Project

    SciTech Connect (OSTI)

    Reynolds, T. D.; Easterling, S. D.

    2010-10-01T23:59:59.000Z

    This position paper addresses the management of beryllium contamination on legacy waste. The goal of the beryllium management program is to protect human health and the environment by preventing the release of beryllium through controlling surface contamination. Studies have shown by controlling beryllium surface contamination, potential airborne contamination is reduced or eliminated. Although there are areas in Building 9201-5 that are contaminated with radioactive materials and mercury, only beryllium contamination is addressed in this management plan. The overall goal of this initiative is the compliant packaging and disposal of beryllium waste from the 9201-5 Legacy Material Removal (LMR) Project to ensure that beryllium surface contamination and any potential airborne release of beryllium is controlled to levels as low as practicable in accordance with 10 CFR 850.25.

  5. Report of a technical evaluation panel on the use of beryllium for ITER plasma facing material and blanket breeder material

    SciTech Connect (OSTI)

    Ulrickson, M.A. [ed.] [Sandia National Labs., Albuquerque, NM (United States); Manly, W.D. [Oak Ridge National Lab., TN (United States); Dombrowski, D.E. [Brush Wellman, Inc., Cleveland, OH (United States)] [and others

    1995-08-01T23:59:59.000Z

    Beryllium because of its low atomic number and high thermal conductivity, is a candidate for both ITER first wall and divertor surfaces. This study addresses the following: why beryllium; design requirements for the ITER divertor; beryllium supply and unirradiated physical/mechanical property database; effects of irradiation on beryllium properties; tritium issues; beryllium health and safety; beryllium-coolant interactions and safety; thermal and mechanical tests; plasma erosion of beryllium; recommended beryllium grades for ITER plasma facing components; proposed manufacturing methods to produce beryllium parts for ITER; emerging beryllium materials; proposed inspection and maintenance techniques for beryllium components and coatings; time table and costs; and the importance of integrating materials and manufacturing personnel with designers.

  6. Producing and controlling of the pollutant in the coal`s coking process

    SciTech Connect (OSTI)

    Li, S. [Shanxi Environmental Protection Bureau (China); Fan, Z. [Shanxi Central Environmental Monitoring Station (China)

    1997-12-31T23:59:59.000Z

    In the process of heating and coke shaping, different pollutants and polluting factors will be produced and lost to the environment due to the different coking methods. The paper analyzes the production mechanism, type, emission, average quantity, and damage to the environment of the major pollutants and polluting factors produced in several kinds of coking processes in China at the present. Then, the paper concludes that an assessment for any coking method should include a comprehensive beneficial assessment of economical benefit, environmental benefit and social benefit. The items in the evaluation should consist of infrastructure investment, which includes production equipment and pollution control equipment, production cost, benefit and profit produced by one ton coal, whether the pollution complies with the environmental requirement, extent of the damage, influence to the social development, and etc.

  7. Current developments at Giprokoks for coke-battery construction and reconstruction

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.B. Kamenyuka; O.N. Surenskii; G.E. Kos'kova; V.V. Derevich; V.A. Gushchin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Approaches developed at Giprokoks for coke-battery construction and reconstruction are considered. Recommendations regarding furnace construction and reconstruction are made on the basis of Ukrainian and world experience.

  8. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1981-01-01T23:59:59.000Z

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  9. Effect of thermal treatment on coke reactivity and catalytic iron mineralogy

    SciTech Connect (OSTI)

    Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

    2009-07-15T23:59:59.000Z

    Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

  10. A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2012-01-01T23:59:59.000Z

    other bituminous coal and coking coal. Small differences incoal (used as fuel) Coking coal Coke oven coke Natural gasrange for typical NCVs of coking coal of 26.6 to 29.8Mj/kg.

  11. Risk-based approach for controlling beryllium exposure in a manufacturing environment

    SciTech Connect (OSTI)

    Gilmore, W. E. (Walter E.); Clawson, C. D. (Chris D.); Ellis, K. K. (Kimberly K.)

    2003-01-01T23:59:59.000Z

    There are many diverse uses for beryllium in both military and industrial applications. Unfortunately, there are certain worker health risks associated with the manufacture and production of beryllium products. Respiratory illnesses due to prolonged contact with beryllium particulate are of paramount concern. However, these health risks can be controlled provided that the appropriate protective measures to prevent worker exposure from beryllium are in place. But it is no1 always a straightforward process to identify exactly what the beryllium protective measures should be in order to realize a true risk savings. Without prudent attention to a systematic inquiry and suitable evaluative criteria, a program for controlling beryllium health risks can be lacking in completeness and overall effectiveness. One approach that took into account the necessary ingredients for risk-based determination of beryllium protective measures was developed for a beryllium operation at a Department of Energy (DOE) facility. The methodological framework that was applied at this facility, as well as a discussion of the final beryllium protective measures that were determined by this approach will be presented. Regulatory aspects for working with beryllium, as well as a risk-assessment strategy for ranking beryllium-handling activities with respect to exposure potential will also be discussed. The presentation will conclude with a synopsis of lessons-learned as gleaned from this case study, as well as providing the participants with a constructive blueprint that can be adapted to other processes involving beryllium.

  12. Coke gasification: the influence and behavior of inherent catalytic mineral matter

    SciTech Connect (OSTI)

    Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

    2009-04-15T23:59:59.000Z

    Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

  13. Extra Crispy OvenFried Drumsticks 3 cups cornflake cereal, crushed

    E-Print Network [OSTI]

    Jawitz, James W.

    Extra Crispy OvenFried Drumsticks 3 cups cornflake cereal, crushed 1/3 cup grated Parmesan pepper sauce 8 chicken drumsticks, skinned Vegetable cooking spray 1. Combine buttermilk and hot pepper sauce in an extralarge ziptop freezer bag. Add chicken drumsticks, turning to coat. Place bag

  14. PROCESS PARAMETERS AND ENERGY USE OF GAS AND ELECTRIC OVENS IN INDUSTRIAL APPLICATIONS

    E-Print Network [OSTI]

    Massachusetts at Amherst, University of

    PROCESS PARAMETERS AND ENERGY USE OF GAS AND ELECTRIC OVENS IN INDUSTRIAL APPLICATIONS Dr for Energy Efficiency and Renewable Energy Department of Mechanical and Industrial Engineering University of Massachusetts, Amherst, Massachusetts ABSTRACT The study was conducted to evaluate the energy use of natural gas

  15. CHAPTER 7. BERYLLIUM ANALYSIS BY NON-PLASMA BASED METHODS

    SciTech Connect (OSTI)

    Ekechukwu, A

    2009-04-20T23:59:59.000Z

    The most common method of analysis for beryllium is inductively coupled plasma atomic emission spectrometry (ICP-AES). This method, along with inductively coupled plasma mass spectrometry (ICP-MS), is discussed in Chapter 6. However, other methods exist and have been used for different applications. These methods include spectroscopic, chromatographic, colorimetric, and electrochemical. This chapter provides an overview of beryllium analysis methods other than plasma spectrometry (inductively coupled plasma atomic emission spectrometry or mass spectrometry). The basic methods, detection limits and interferences are described. Specific applications from the literature are also presented.

  16. Method for removal of beryllium contamination from an article

    DOE Patents [OSTI]

    Simandl, Ronald F.; Hollenbeck, Scott M.

    2012-12-25T23:59:59.000Z

    A method of removal of beryllium contamination from an article is disclosed. The method typically involves dissolving polyisobutylene in a solvent such as hexane to form a tackifier solution, soaking the substrate in the tackifier to produce a preform, and then drying the preform to produce the cleaning medium. The cleaning media are typically used dry, without any liquid cleaning agent to rub the surface of the article and remove the beryllium contamination below a non-detect level. In some embodiments no detectible residue is transferred from the cleaning wipe to the article as a result of the cleaning process.

  17. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M. [ILVA, Taranto (Italy); Eichinger, F.; Rafi, M.

    1995-12-01T23:59:59.000Z

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  18. Coking phenomena in the pyrolysis of ethylene dichloride into vinyl chloride

    SciTech Connect (OSTI)

    Sotowa, Chiaki; Korai, Yozo; Mochida, Isao [Kyushu Univ., Kasuga, Fukuoka (Japan)] [and others

    1995-12-31T23:59:59.000Z

    Pyrolysis of ethylene dichloride (EDC) into vinyl chloride (VCM) which is the monomer for polyvinyl chloride, one of the most popular polymers, has been established commercially for quite a time. The process around 500{degrees}C has been proved to give VCM of high purity at very high selectivity about 99% and a reasonable conversion about 50%. However, the coking is a major problem in the long run, requiring decoking treatment every two months. The present paper describes features of carbons produced in the pyrolysis process. Coke of respective features was found in the reactor, the transfer line, the heat exchanger and the rapid quencher. Typical pyrolytic carbon, anisotropic coke produced in the liquid phase, isotropic carbon was produced on the reactor wall as low as 500{degrees}C. The mechanisms for their formation are discussed.

  19. Ultrasonic evaluation of beryllium-copper diffusion bonds

    SciTech Connect (OSTI)

    Jamieson, E.E.

    2000-06-08T23:59:59.000Z

    A study was performed to compare the effectiveness of several advanced ultrasonic techniques when used to determine the strength of diffusion bonded beryllium-copper, which heretofore have each been applied to only a few material systems. The use of integrated backscatter calculations, frequency domain reflection coefficients, and time-of-flight variance was compared in their ability to characterize the bond strength in a series of beryllium-copper diffusion bond samples having a wide variation in bond quality. Correlation of integrated backscatter calculations and time-of-flight variance with bond strength was good. Some correlation of the slope of the frequency based reflection coefficient was shown for medium and high strength bonds, while its Y-intercept showed moderate correlation for all bond strengths.

  20. Impact of HFIR LEU Conversion on Beryllium Reflector Degradation Factors

    SciTech Connect (OSTI)

    Ilas, Dan [ORNL

    2013-10-01T23:59:59.000Z

    An assessment of the impact of low enriched uranium (LEU) conversion on the factors that may cause the degradation of the beryllium reflector is performed for the High Flux Isotope Reactor (HFIR). The computational methods, models, and tools, comparisons with previous work, along with the results obtained are documented and discussed in this report. The report documents the results for the gas and neutronic poison production, and the heating in the beryllium reflector for both the highly enriched uranium (HEU) and LEU HFIR configurations, and discusses the impact that the conversion to LEU may have on these quantities. A time-averaging procedure was developed to calculate the isotopic (gas and poisons) production in reflector. The sensitivity of this approach to different approximations is gauged and documented. The results show that the gas is produced in the beryllium reflector at a total rate of 0.304 g/cycle for the HEU configuration; this rate increases by ~12% for the LEU case. The total tritium production rate in reflector is 0.098 g/cycle for the HEU core and approximately 11% higher for the LEU core. A significant increase (up to ~25%) in the neutronic poisons production in the reflector during the operation cycles is observed for the LEU core, compared to the HEU case, for regions close to the core s horizontal midplane. The poisoning level of the reflector may increase by more than two orders of magnitude during long periods of downtime. The heating rate in the reflector is estimated to be approximately 20% lower for the LEU core than for the HEU core. The decrease is due to a significantly lower contribution of the heating produced by the gamma radiation for the LEU core. Both the isotopic (gas and neutronic poisons) production and the heating rates are spatially non-uniform throughout the beryllium reflector volume. The maximum values typically occur in the removable reflector and close to the midplane.

  1. Shockless compression and release behavior of beryllium to 110?GPa

    SciTech Connect (OSTI)

    Brown, J. L.; Knudson, M. D.; Alexander, C. S.; Asay, J. R. [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)

    2014-07-21T23:59:59.000Z

    A magnetohydrodynamic loading technique was used to shocklessly compress beryllium to peak longitudinal stresses of 19–110?GPa and, subsequently, unload in order to determine both the compressive response and also the shear stress supported upon release. Loading strain rates were on the order of 10{sup 6?}s{sup ?1}, while the unloading rates were nearly constant at 3?×?10{sup 5?}s{sup ?1}. Velocimetry was used to monitor the ramp and release behavior of a beryllium/lithium fluoride window interface. After applying window corrections to infer in situ beryllium velocities, a Lagrangian analysis was employed to determine the material response. The Lagrangian wavespeed-particle velocity response is integrated to generate the stress-strain path, average change in shear stress over the elastic unloading, and estimates of the shear modulus at peak compression. These data are used to infer the pressure dependence of the flow strength at the unloading rate. Comparisons to several strength models reveal good agreement to 45?GPa, but the data indicate 20%–30% higher strength near 100?GPa.

  2. Boron nitride protective coating of beryllium window surfaces

    SciTech Connect (OSTI)

    Gmuer, N.F.

    1991-12-01T23:59:59.000Z

    The use of beryllium windows on white synchrotron radiation beamlines is constrained by the fact that the downstream surfaces of these windows should not be exposed to ambient atmosphere. They should, rather, be protected by a tail-piece under vacuum or containing helium atmosphere. This tailpiece is typically capped by Kapton (3M Corporation, St. Paul, MN) or aluminum foil. The reason for such an arrangement is due to the health risk associated with contaminants (BeO) which from on the exposed beryllium window surfaces and due to possible loss of integrity of the windows. Such a tail-piece may, however, add unwanted complications to the beamline in the form of vacuum pumps or helium supplies and their related monitoring systems. The Kapton windows may burn through in the case of high intensity beams and lower energy radiation may be absorbed in the case of aluminum foil windows. A more ideal situation would be to provide a coating for the exposed beryllium window surface, sealing it off from the atmosphere, thus preventing contamination and/or degradation of the window, and eliminating the need for helium or vacuum equipment.

  3. The beryllium quandary: will the lower exposure limits spur new developments in sampling and analysis?

    SciTech Connect (OSTI)

    Brisson, Michael

    2013-06-03T23:59:59.000Z

    At the time this article was written, new rulemakings were under consideration at OSHA and the U.S. Department of Energy (DOE) that would propose changes to occupational exposure limits for beryllium. Given these developments, it’s a good time to review the tools and methods available to IHs for assessing beryllium air and surface contamination in the workplace—what’s new and different, and what’s tried and true. The article discusses limit values and action levels for beryllium, problematic aspects of beryllium air sampling, sample preparation, sample analysis, and data evaluation.

  4. E-Print Network 3.0 - americium-beryllium ambe source Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for: americium-beryllium ambe source Page: << < 1 2 3 4 5 > >> 1 FINAL REPORT Task Order 1345 Summary: density and water content are typically measured with an...

  5. Beryllium Science: US-UK agreement on the use of Atomic Energy for mutual defense

    SciTech Connect (OSTI)

    Hanafee, J.E. (ed.)

    1988-02-19T23:59:59.000Z

    Twenty-seven papers are presented on beryllium supply, production, fabrication, safe handling, analysis, powder technology, and coatings. Separate abstracts have been prepared for the individual papers. (DLC)

  6. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01T23:59:59.000Z

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  7. Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore Torquatob)

    E-Print Network [OSTI]

    Torquato, Salvatore

    Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore of a Brownian particle diffusing among a, digitized lattice-based domain of traps. Following the first, the inverse of the trapping rate, is obtained for a variety of configurations involving digitized spheres

  8. Demonstration of a fuel-saving system for paint-curing ovens

    SciTech Connect (OSTI)

    Jensen, W P [comp.

    1980-12-01T23:59:59.000Z

    Two curing ovens at Roll Coater, Inc. (the Greenfield, Indiana plant) were retrofitted to save fuel and cost. Included in the fuel conserving retrofit was the design, fabrication, and installation of an afterburner for each of the two ovens, piping their combustion products to each of two commonly housed waste heat boilers before discharge from those units to the atmosphere at about 450 F. Depending on the product being run and the coating applied, natural gas requirements have been reduced by 45 to 65% with operation of the zone incinerators only and by as much as 65 to 85% including the effects of both the zone incineration and heat recovery by means of the afterburners and waste heat boilers. A demonstration program on conversion work at the No. 3 line at Greenfield and results are described in Section 2. Section 3 describes the retrofit design and the system construction. System performance (tests and measurements, qualitative performance, maintenance factors, and economic performance) is described in Section 4. Conclusions and recommendations are summarized.

  9. DOE - Office of Legacy Management -- Beryllium Corp - PA 39

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou are here Home »Hill - NJ 0-04 BellCityBeryllium

  10. Linings with optimum heat-emission surfaces for cars receiving and transporting incandescent coke

    SciTech Connect (OSTI)

    Kotlyar, B.D.; Pleshkov, P.I.; Gadyatskii, V.G. [and others

    1992-12-31T23:59:59.000Z

    The least reliable components of the cars which receive and transport incandescent coke are the lining plates. This applies to both the quenching cars used for wet quenching and the hot-coke cars used in the dry cooling process. Technical advances have been described whereby the life of car linings is prolonged by increasing heat emission from the lining plate surfaces. As the heat emission level is enhanced the mean plate temperature is lowered and the lining life thereby prolonged; moreover, the between-servicings period is prolonged. This involves providing fins on the non-working (outer) plate surfaces. The problem of optimizing the size and shape of the fins with reference to heat emission remains unsolved: the requirement is maximum heat emission from plates of a given weight, or conversely minimum plate weight for a given heat emission level. 6 refs., 3 figs.

  11. Operating temperature effects on nozzle coking in a cottonseed oil fueled diesel engine

    E-Print Network [OSTI]

    Yarbrough, Charles Michael

    1984-01-01T23:59:59.000Z

    OPERATING TEMPERATURE EFFECTS ON NOZZLE COKING IN A COTTONSEED OIL FUELED DIESEL ENGINE A Thesis CHARLES MICHAEL YARBROUGH Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree cf... MASTER OF SCIENCE December 1984 Major Subject: Agricultural Engineering OPERATING TEMPERATURE EFFECTS ON NOZZLE CORING IN A COTTONSEED OIL FUELED DIESEL ENGINE A Thesis by CHARLES MICHAEL YARBROUGH Approved as to style and content by: ayne A. Le...

  12. March 1980 / Vol. 5, No. 3 / OPTICS LETTERS 117 Disk-shaped heat-pipe oven used for lithium excited-state

    E-Print Network [OSTI]

    Stroud, Carlos R.

    March 1980 / Vol. 5, No. 3 / OPTICS LETTERS 117 Disk-shaped heat-pipe oven used for lithium excited-vapor spectroscopic oven based on the heat-pipe principle has been constructed in which the heated stain- less steel and Cooperl from an evaporative conductive device known as a heat pipe, described first by Grover et al. 2

  13. An example of alkalization of SiO{sub 2} in a blast furnace coke

    SciTech Connect (OSTI)

    S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

    2007-09-15T23:59:59.000Z

    Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

  14. Grass roots technology and energy policy: Solar ovens and wind turbines in Kenya

    SciTech Connect (OSTI)

    Kammen, D.M. [Harvard Univ., Cambridge, MA (United States). Dept. of Physics

    1992-12-31T23:59:59.000Z

    Kenya is said to be an ideal site for projects that promote renewable energy sources since it devotes over forty percent of its GNP to the purchase of imported coal and oil. The author presents a chronology of solar oven projects in Kenya and suggests that success of the program will be measured by the number of people who move on to wind turbine use. He discusses the role of renewable energy technology in reducing greenhouse gases and closes by recommending that industrialized nations that produce large amounts of carbon dioxide provide aid to develop projects that reduce carbon dioxide elsewhere in the world. At the same time they would receive credit towards their carbon dioxide quotas.

  15. Initial coke deposition on a NiMo/{gamma}-Al{sub 2}O{sub 3} bitumen hydroprocessing catalyst

    SciTech Connect (OSTI)

    Richardson, S.M.; Nagaishi, Hiroshi; Gray, M.R. [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering] [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering

    1996-11-01T23:59:59.000Z

    Athabasca bitumen was hydrocracked over a commercial NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst in two reactors, a microbatch reactor and a 1-L continuous stirred tank reactor (CSTR). Coke deposition on catalyst was measured as a function of hydrogen pressure, time on stream, and liquid composition by measuring the carbon content of the cleaned spent catalyst. The carbon content ranged from 11.3% to 17.6% over the pressure range 6.9--15.2 MPa in CSTR experiments. Batch and CSTR experiments showed a rapid approach to a constant coke content with increasing oil/catalyst ratio. Coke deposition was independent of product composition for residue concentrations ranging from 8% to 32% by weight. Removal of the coke by tetralin at reaction conditions suggested reversible adsorption of residue components on the catalyst surface. A physical model based on clearance of coke by hydrogen in the vicinity of metal crystallites is presented for the coke deposition behavior during the first several hours of hydrocracking use. This model gives good agreement with experimental data, including the effect of reaction time, the ratio of total feed weight to catalyst weight, hydrogen pressure, and feed composition, and it agrees with general observations from industrial usage. The model implies that except at the highest coke levels, the active surfaces of the metal crystallites remain exposed. Severe mass-transfer limitations are caused by the overall narrowing of the pore structure, which in {gamma}-Al{sub 2}O{sub 3} would give very low effective diffusivity for residuum molecules in micropores.

  16. Usiing NovoCOS cleaning equipment in repairing the furnace-chamber lining in coke batteries 4 & 5 at OAO Koks

    SciTech Connect (OSTI)

    S.G. Protasov; R. Linden; A. Gross [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    Experience with a new surface-preparation technology for the ceramic resurfacing of the refractory furnace-chamber lining in coke batteries is described.

  17. Fracture testing and performance of beryllium copper alloy C 17510

    SciTech Connect (OSTI)

    Murray, H.A.; Zatz, I.J. (Princeton Univ., NJ (United States). Plasma Physics Lab.); Ratka, J.O. (Brush Wellman, Inc., Cleveland, OH (United States))

    1992-01-01T23:59:59.000Z

    A series of test programs was undertaken on copper beryllium alloy C 17510 for several variations in material process and chemistry. These variations in C 17510 were primarily optimized for combinations of strength and conductivity. While originally intended for use as cyclically loaded high-field, high-strength conductors in fusion energy research, material testing of C 17510 has indicated that it is an attractive and economical alternative for a host of other structural, mechanical and electrical applications. ASTM tests performed on three variations of C 17510 alloys included both J-integral and plane strain fracture toughness testing (E813, E399) and fatigue crack growth rate tests (E647), as well as verifying tensile, hardness, Charpy, and other well defined mechanical properties. Fracture testing was performed at both room and liquid nitrogen temperatures, which bound the thermal environment anticipated for the fusion components being designed. Fatigue crack propagation stress ratios ranged from nominal zero to minus one at each temperature.

  18. Fracture testing and performance of beryllium copper alloy C 17510

    SciTech Connect (OSTI)

    Murray, H.A.; Zatz, I.J. [Princeton Univ., NJ (United States). Plasma Physics Lab.; Ratka, J.O. [Brush Wellman, Inc., Cleveland, OH (United States)

    1992-12-01T23:59:59.000Z

    A series of test programs was undertaken on copper beryllium alloy C 17510 for several variations in material process and chemistry. These variations in C 17510 were primarily optimized for combinations of strength and conductivity. While originally intended for use as cyclically loaded high-field, high-strength conductors in fusion energy research, material testing of C 17510 has indicated that it is an attractive and economical alternative for a host of other structural, mechanical and electrical applications. ASTM tests performed on three variations of C 17510 alloys included both J-integral and plane strain fracture toughness testing (E813, E399) and fatigue crack growth rate tests (E647), as well as verifying tensile, hardness, Charpy, and other well defined mechanical properties. Fracture testing was performed at both room and liquid nitrogen temperatures, which bound the thermal environment anticipated for the fusion components being designed. Fatigue crack propagation stress ratios ranged from nominal zero to minus one at each temperature.

  19. Validation of NCSSHP for highly enriched uranium systems containing beryllium

    SciTech Connect (OSTI)

    Krass, A.W.; Elliott, E.P.; Tollefson, D.A.

    1994-09-29T23:59:59.000Z

    This document describes the validation of KENO V.a using the 27-group ENDF/B-IV cross section library for highly enriched uranium and beryllium neutronic systems, and is in accordance with ANSI/ANS-8.1-1983(R1988) requirements for calculational methods. The validation has been performed on a Hewlett Packard 9000/Series 700 Workstation at the Oak Ridge Y-12 Plant Nuclear Criticality Safety Department using the Oak Ridge Y-12 Plant Nuclear Criticality Safety Software code package. Critical experiments from LA-2203, UCRL-4975, ORNL-2201, and ORNL/ENG-2 have been identified as having the constituents desired for this validation as well as sufficient experimental detail to allow accurate construction of KENO V.a calculational models. The results of these calculations establish the safety criteria to be employed in future calculational studies of these types of systems.

  20. Optical properties and structure of beryllium lead silicate glasses

    SciTech Connect (OSTI)

    Zhidkov, I. S., E-mail: i.s.zhidkov@urfu.ru [Ural Federal University, Mira Str. 19, Yekaterinburg, 620002, Russia and Institute of Metal Physics, Russian Academy of Sciences-Ural Division, S. Kovalevskoi Str. 18, 620990 Yekaterinburg (Russian Federation); Zatsepin, A. F.; Cholakh, S. O.; Kuznetsova, Yu. A. [Ural Federal University, Mira Str. 19, Yekaterinburg, 620002 (Russian Federation)

    2014-10-21T23:59:59.000Z

    Luminescence and optical properties and structural features of (BeO){sub x}(PbO?SiO{sub 2}){sub 1?x} glasses (x = 0 ÷ 0.3) are investigated by means of optical absorption and photoluminescence spectroscopy and X-ray diffraction. The regularities of the formation of the optical absorption edge and static disorder are studied. It is shown that the optical absorption and luminescence are determined by transitions between localized states of lead ions. The impact of beryllium oxide on optical and luminescence properties and electronic structure of bands tails is discussed. The presence of two different concentration ranges with various short-range order structure and band tails nature has been established.

  1. E-Print Network 3.0 - aluminium chloride beryllium Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    49 Chemicals Requiring Designated Areas The OSHA Laboratory Standard 29 CFR 1910.1450 mandates that an employer's Summary: -52-9 Beryl Ore 7440-41-7 Beryllium...

  2. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A.

    1988-06-01T23:59:59.000Z

    Today's commercially proved technology to recover oil from the Athabasca oil sands, as practiced by Suncor and Syncrude, involves two major operations, namely: separation of the bitumen from the sand and upgrading of the bitumen to refinery oil. Significant amounts of petroleum coke are produced during the bitumen upgrading process. Suncor burns the bulk of its petroleum coke in boilers to fulfill the energy requirements of the entire operation, still meeting government regulations restricting the amount of sulfur dioxide that can be released to the environment. In contrast, Syncrude is able to burn only 20% of its coke production because of high sulphur dioxide emissions from elsewhere in its operations. The boiler ash (Fly ash) which contains appreciable amounts of metals, such as vanadium, nickel, titianium, iron, aluminum and other elements, is collected in the boiler hoppers and cyclones of the petroleum coke fired steam generation plants. There has been relatively little effort made towards the understanding of the chemical or physical nature of these materials. Knowledge of the physico-chemical properties of these materials will be helpful in assessing their beneficiation and potential use as fuel or metallurigcal coke and the feasibility of extracting some metals, especially Ni and V. In this communication the authors report studies of acid demineralization as a means of reducing ash content of these materials for /sup 13/C NMR spectroscopic investigations.

  3. Dynamic failure prediction of cross-rolled beryllium sheets subjected to vibration loads

    E-Print Network [OSTI]

    Serna, Oscar R.

    1996-01-01T23:59:59.000Z

    DYNAMIC FAILURE PREDICTION OF CROSS-ROLLED BERYLLIUM SHEETS SUBJECTED TO VIBRATION LOADS A Thesis OSCAR R. SERNA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 1996 Major Subject; Civil Engineering DYNAMIC FAILURE PREDICTION OF CROSS-ROLLED BERYLLIUM SHEETS SUBJECTED TO VIBRATION LOADS A Thesis by OSCAR R. SERNA Submitted to Texas ARM University in partial fulfillment...

  4. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J. [Wheeling-Pittsburgh Steel Corp., Follansbee, WV (United States)

    1995-12-01T23:59:59.000Z

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  5. Theoretical and experimental investigations into the particular features of the process of converting coal gas hydrocarbons on incandescent coke

    SciTech Connect (OSTI)

    Zubilin, I.G.; Umanskii, V.E.

    1984-01-01T23:59:59.000Z

    The prospects of the use of reducing gases in ferrous metallurgy and the possibilities for using them as a basis for coke production have been presented by the authors of the present article in the past. In the present report, the authors present certain results of theoretical and experimental investigations into the process of converting coal gas hydrocarbons on incandescent coke. The modification of the present-day method of thermodynamically calculating stable compositions of coking products, which was developed by the authors, has made it possible to apply it to specific chemical systems and process conditions not met with before, such as the conversion of hydrocarbons in mixtures of actual industrial gases (coal gas and blast furnace gas) in the presence of carbon and considerable amounts of hydrogen.

  6. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-03-15T23:59:59.000Z

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  7. Petroleum Coke

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing ReservoirsYear-MonthCoalbedPricethe PricetheCity Gate Price81,811

  8. Petroleum Coke

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30 2013 Macroeconomicper8,170 8,310 8,304PricePriceby81,811 82,516 82,971

  9. Application of RIMS to the Study of Beryllium ChronologyApplication of RIMS to the Study of Beryllium Chronology in Early Solar System Condensatesin Early Solar System Condensates

    E-Print Network [OSTI]

    Grossman, Lawrence

    - tion events from the first days of the early solar system. SIMS analyses use large analytical spot of Beryllium Chronology in Early Solar System Condensatesin Early Solar System Condensates K. B. Knight1 of Be decay products shows potential for addressing early solar system events.Resonant Ionization (RIMS

  10. Beryllium fabrication/cost assessment for ITER (International Thermonuclear Experimental Reactor)

    SciTech Connect (OSTI)

    Beeston, J.M. (Beeston (J.M.), Garrison, UT (USA)); Longhurst, G.R. (EG and G Idaho, Inc., Idaho Falls, ID (USA)); Parsonage, T. (Brush Wellman, Inc., Elmore, OH (USA))

    1990-06-01T23:59:59.000Z

    A fabrication and cost estimate of three possible beryllium shapes for the International Thermonuclear Experimental Reactor (ITER) blanket is presented. The fabrication method by hot pressing (HP), cold isostatic pressing plus sintering (CIP+S), cold isostatic pressing plus sintering plus hot isostatic pressing (CIP+S+HIP), and sphere production by atomization or rotary electrode will be discussed. Conventional hot pressing blocks of beryllium with subsequent machining to finished shapes can be more expensive than production of a net shape by cold isostatic pressing and sintering. The three beryllium shapes to be considered here and proposed for ITER are: (1) cubic blocks (3 to 17 cm on an edge), (2) tubular cylinders (33 to 50 mm i.d. by 62 mm o.d. by 8 m long), and (3) spheres (1--5 mm dia.). A rough cost estimate of the basic shape is presented which would need to be refined if the surface finish and tolerances required are better than the sintering process produces. The final cost of the beryllium in the blanket will depend largely on the machining and recycling of beryllium required to produce the finished product. The powder preparation will be discussed before shape fabrication. 10 refs., 6 figs.

  11. Separation of Transmutation - and Fission-Produced Radioisotopes from Irradiated Beryllium

    SciTech Connect (OSTI)

    Troy J. Tranter; RIchard D. Tillotson; Nick R. Mann; Glen R. Longhurst

    2011-11-01T23:59:59.000Z

    The primary objective of this study was to test the effectiveness of a two-step solvent extraction-precipitation process for separating transmutation and fission products from irradiated beryllium. Beryllium metal was dissolved in nitric and fluoroboric acids. Isotopes of 241Am, 239Pu, 85Sr, 60Co, and 137Cs were then added to make a surrogate beryllium waste solution. A series of batch contacts was performed with the spiked simulant using chlorinated cobalt dicarbollide and polyethylene glycol diluted with sulfone to extract the isotopes of Cs and Sr. Another series of batch contacts was performed using a combination of octyl (phenyl)-N,Ndiisobutylcarbamoylmethylphosphine oxide in tributyl phosphate diluted with dodecane for extracting the isotopes of Pu and Am. The 60Co was separated by first forming a cobalt complex and then selectively precipitating the beryllium as a hydroxide. The results indicate that greater than 99.9% removal can be achieved for each radionuclide. Transuranic isotope contamination levels are reduced to less than 100 nCi/g, and sources of high beta-gamma radiation (60Co, 137Cs, and 90Sr) are reduced to levels that will allow the beryllium to be contact handled. The separation process may be applicable to a recycle or waste disposition scenario.

  12. A Comparison of Magnesium and Beryllium Acceptors in GaN Grown by rf-Plasma Assisted Molecular Beam Epitaxy

    E-Print Network [OSTI]

    Myers, Tom

    A Comparison of Magnesium and Beryllium Acceptors in GaN Grown by rf-Plasma Assisted Molecular Beam Evans and Associates, Sunnyvale, CA 94086 ABSTRACT Step-doped structures of both magnesium and beryllium activation energy of approximately 100 meV. INTRODUCTION While magnesium is currently the most

  13. Evaluation of pitches and cokes from solvent-extracted coal materials

    SciTech Connect (OSTI)

    McHenry, E.R.

    1996-12-01T23:59:59.000Z

    Three initial coal-extracted (C-E) samples were received from the West Virginia University (WVU) Chemical Engineering Department. Two samples had been hydrogenated to obtain pitches that satisfy Theological requirements. One of the hydrogenated (HC-E) samples had been extracted by toluene to remove ash and higher molecular weight aromatic compounds. We were unable to measure the softening point and viscosity of the non-hydro treated solid extract sample, Positive characteristics in the HC-E materials were softening points of 113-119{degrees}C, low sulfur and ash. The oxygen and nitrogen content of the HC-E samples may limit future usage in premium carbon and graphite products. Coking values were similar to petroleum pitches. Laboratory anode testing indicates that in combination with standard coal-tar pitch, the HC-E material can be used as a binder pitch.

  14. Selective effect of the metallocarcinogen beryllium on hormonal regulation of gene expression in cultured cells

    SciTech Connect (OSTI)

    Perry, S.T.; Kulkarni, S.B.; Lee, K.L.; Kenney, F.T.

    1982-02-01T23:59:59.000Z

    Effects of the metallocarcinogen beryllium on regulation of gene expression were assessed by analysis of hormonal regulation of synthesis of tyrosine aminotransferase in beryllium-treated hepatoma cell cultures. Cell growth was not affected by exposure of the cells to 1 ..mu..M BeSO/sub 4/ throughout their 4- to 5-day growth cycle. In cells pretreated in this way, the induction by glucocorticoids was specifically impaired, the extent of induced enzyme synthesis being reduced about 50%. Inductions by insulin or cyclic adenosine 3':5'-monophosphate were not influenced by the metal. The results suggest that low concentrations of beryllium selectively interfere with regulatory mechanisms controlling transcriptional events in gene expression.

  15. Cyanide leaching from soil developed from coking plant purifier waste as influenced by citrate

    SciTech Connect (OSTI)

    Tim Mansfeldt; Heike Leyer; Kurt Barmettler; Ruben Kretzschmar [Ruhr-University Bochum, Bochum (Germany). Soil Science and Soil Ecology Group, Faculty of Geosciences

    2004-07-01T23:59:59.000Z

    Soils in the vicinity of manufactured gas plants and coal coking plants are often highly contaminated with cyanides in the form of the compound Prussian blue. The objective of this study was to investigate the influence of citrate on the leaching of iron-cyanide complexes from an extremely acidic soil (pH 2.3) developed from gas purifier waste near a former coking plant. The soil contained 63 g kg{sup -1} CN, 148 g kg{sup -1} Fe, 123 g kg{sup -1} S, and 222 g kg{sup -1} total C. Analysis of the soil by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy revealed the presence of Prussian blue, gypsum, elemental sulfur, jarosite, and hematite. For column leaching experiments, air-dried soil was mixed with purified cristabolite sand at a ratio of 1:3 and packed into chromatography columns. The soil was leached with dilute (0.1 or 1 mM) CaCl{sub 2} solutions and the effluent was collected and analyzed for total and dissolved CN, Ca, Fe, SO{sub 4}, pH, and pe. In the absence of citrate, the total dissolved CN concentration in the effluent was always below current drinking water limits (< 1.92 {mu}M), indicating low leaching potential. Adding citrate at a concentration of 1 mM had little effect on the CN concentrations in the column effluent. Addition of 10 or 100 mM citrate to the influent solution resulted in strong increases in dissolved and colloidal CN concentrations in the effluent.

  16. Fundamental hydrogen interactions with beryllium : a magnetic fusion perspective.

    SciTech Connect (OSTI)

    Wampler, William R. (Sandia National Laboratories, Albuquerque, NM); Felter, Thomas E.; Whaley, Josh A.; Kolasinski, Robert D.; Bartelt, Norman Charles

    2012-03-01T23:59:59.000Z

    Increasingly, basic models such as density functional theory and molecular dynamics are being used to simulate different aspects of hydrogen recycling from plasma facing materials. These models provide valuable insight into hydrogen diffusion, trapping, and recombination from surfaces, but their validation relies on knowledge of the detailed behavior of hydrogen at an atomic scale. Despite being the first wall material for ITER, basic single crystal beryllium surfaces have been studied only sparsely from an experimental standpoint. In prior cases researchers used electron spectroscopy to examine surface reconstruction or adsorption kinetics during exposure to a hydrogen atmosphere. While valuable, these approaches lack the ability to directly detect the positioning of hydrogen on the surface. Ion beam techniques, such as low energy ion scattering (LEIS) and direct recoil spectroscopy (DRS), are two of the only experimental approaches capable of providing this information. In this study, we applied both LEIS and DRS to examine how hydrogen binds to the Be(0001) surface. Our measurements were performed using an angle-resolved ion energy spectrometer (ARIES) to probe the surface with low energy ions (500 eV - 3 keV He{sup +} and Ne{sup +}). We were able to obtain a 'scattering maps' of the crystal surface, providing insight on how low energy ions are focused along open surface channels. Once we completed a characterization of the clean surface, we dosed the sample with atomic hydrogen using a heated tungsten capillary. A distinct signal associated with adsorbed hydrogen emerged that was consistent with hydrogen residing between atom rows. To aid in the interpretation of the experimental results, we developed a computational model to simulate ion scattering at grazing incidence. For this purpose, we incorporated a simplified surface model into the Kalypso molecular dynamics code. This approach allowed us to understand how the incident ions interacted with the surface hydrogen, providing confirmation of the preferred binding site.

  17. Fracture testing and performance of beryllium copper alloy C17510

    SciTech Connect (OSTI)

    Murray, H.A.; Zatz, I.J.

    1994-05-01T23:59:59.000Z

    When a literature search and discussion with manufacturers revealed that there was virtually no existing data related to the fracture properties and behavior of copper beryllium alloy C17510, a series of test programs was undertaken to ascertain this information for several variations in material processing and chemistry. These variations in C17510 were primarily optimized for combinations of strength and conductivity. While originally intended for use as cyclically loaded high-field, high-strength conductors in fusion energy research, material testing of C17510 has indicated that it is an attractive and economical alternative for a host of other structural, mechanical and electrical applications. ASTM tests performed on three variations of C17510 alloys included both J-integral and plane strain fracture toughness testing and fatigue crack growth rate tests, as well as verifying tensile, hardness, Charpy, and other well defined mechanical properties. Fracture testing was performed at both room and liquid nitrogen temperatures, which bound the thermal environment anticipated for the fusion components being designed. Fatigue crack propagation stress ratios ranged from nominal zero to minus one at each temperature. In order to confirm the test results, duplicate and independent test programs were awarded to separate facilities with appropriate test experience, whenever possible. The primary goal of the test program, to determine and bound the fracture toughness and Paris constants for C17510,was accomplished. In addition, a wealth of information was accumulated pertaining to crack growth characteristics, effects of directionality and potential testing pitfalls. The paper discusses the test program and its findings in detail.

  18. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15T23:59:59.000Z

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an “opportunity fuel” for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administration’s “National Goal to Reduce Emissions Intensity.” 8

  19. Calculation and Experiment of Adding Top Beryllium Shims for Iran MNSR

    SciTech Connect (OSTI)

    Ebadati, Javad; Rezvanifard, Mehdi; Shahabi, Iraj [Esfahan Nuclear Technology Center - ENTC (Iran, Islamic Republic of)

    2006-07-01T23:59:59.000Z

    Miniature Neutron Source Reactor which is called MNSR were put into operation on June 1994 in Esfahan Nuclear Technology Center (ENTC). At that time the excess reactivity at the cold condition was 3.85 mk. After 7 years of operation and fuel consumption the reactivity was reduced to 2.90 mk. To compensate this reduction and upgrade the reactor, Beryllium Shim were used at the top of the core. This paper discusses the steps for this accurate and sensitive task. Finally a layer of 1.5 mm Beryllium were added to restore the reactor life. (authors)

  20. Evaluation of HEU-Beryllium Benchmark Experiments to Improve Computational Analysis of Space Reactors

    SciTech Connect (OSTI)

    John D. Bess; Keith C. Bledsoe; Bradley T. Rearden

    2011-02-01T23:59:59.000Z

    An assessment was previously performed to evaluate modeling capabilities and quantify preliminary biases and uncertainties associated with the modeling methods and data utilized in designing a nuclear reactor such as a beryllium-reflected, highly-enriched-uranium (HEU)-O2 fission surface power (FSP) system for space nuclear power. The conclusion of the previous study was that current capabilities could preclude the necessity of a cold critical test of the FSP; however, additional testing would reduce uncertainties in the beryllium and uranium cross-section data and the overall uncertainty in the computational models. A series of critical experiments using HEU metal were performed in the 1960s and 1970s in support of criticality safety operations at the Y-12 Plant. Of the hundreds of experiments, three were identified as fast-fission configurations reflected by beryllium metal. These experiments have been evaluated as benchmarks for inclusion in the International Handbook of Evaluated Criticality Safety Benchmark Experiments (IHECSBE). Further evaluation of the benchmark experiments was performed using the sensitivity and uncertainty analysis capabilities of SCALE 6. The data adjustment methods of SCALE 6 have been employed in the validation of an example FSP design model to reduce the uncertainty due to the beryllium cross section data.

  1. ITER-like wall sliced beryllium tiles The JET Enhanced Performance 2 (EP2) shutdown

    E-Print Network [OSTI]

    ITER-like wall sliced beryllium tiles Background The JET Enhanced Performance 2 (EP2) shutdown and remote handling equipment. JET remote handling systems #12;Outcome The EP2 shutdown was successful of the remote handling system are compatible with the required component manipulation. Pre EP2 shutdown Mid

  2. Implementation Guide for use with 10 CFR Part 850, Chronic Beryllium Disease Prevention Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2001-01-04T23:59:59.000Z

    The Department of Energy (DOE) has established regulatory requirements for the Chronic Beryllium Disease Prevention Program (CBDPP) in Title 10 of the Code of Federal Regulations (CFR), Part 850 (10 CFR 850) [64 Federal Register (FR) 68854]. Cancels DOE G 440.1-7. Certified 9-23-10.

  3. Progress on a Cavity with Beryllium Walls for Muon Ionization Cooling Channel R&D.

    SciTech Connect (OSTI)

    Bowring, D.L.; DeMello, A.J.; Lambert, A.R.; Li, D.; Virostek,, S.; Zisman, M.; Kaplan, D.; Palmer, R.B.

    2012-05-20T23:59:59.000Z

    The Muon Accelerator Program (MAP) collaboration is working to develop an ionization cooling channel for muon beams. An ionization cooling channel requires the operation of high-gradient, normal-conducting RF cavities in multi-Tesla solenoidal magnetic fields. However, experiments conducted at Fermilab?s MuCool Test Area (MTA) show that increasing the solenoidal field strength reduces the maximum achievable cavity gradient. This gradient limit is characterized by an RF breakdown process that has caused significant damage to copper cavity interiors. The damage may be caused by field-emitted electrons, focused by the solenoidal magnetic field onto small areas of the inner cavity surface. Local heating may then induce material fatigue and surface damage. Fabricating a cavity with beryllium walls would mitigate this damage due to beryllium?s low density, low thermal expansion, and high electrical and thermal conductivity. We address the design and fabrication of a pillbox RF cavity with beryllium walls, in order to evaluate the performance of high-gradient cavities in strong magnetic fields.

  4. Irradiated Beryllium Disposal Workshop, Idaho Falls, ID, May 29-30, 2002

    SciTech Connect (OSTI)

    Longhurst, Glen Reed; Anderson, Gail; Mullen, Carlan K; West, William Howard

    2002-07-01T23:59:59.000Z

    In 2001, while performing routine radioactive decay heat rate calculations for beryllium reflector blocks for the Advanced Test Reactor (ATR), it became evident that there may be sufficient concentrations of transuranic isotopes to require classification of this irradiated beryllium as transuranic waste. Measurements on samples from ATR reflector blocks and further calculations confirmed that for reflector blocks and outer shim control cylinders now in the ATR canal, transuranic activities are about five times the threshold for classification. That situation implies that there is no apparent disposal pathway for this material. The problem is not unique to the ATR. The High Flux Isotope Reactor at Oak Ridge National Laboratory, the Missouri University Research Reactor at Columbia, Missouri and other reactors abroad must also deal with this issue. A workshop was held in Idaho Falls Idaho on May 29-30, 2002 to acquaint stakeholders with these findings and consider a path forward in resolving the issues attendant to disposition of irradiated material. Among the findings from this workshop were (1) there is a real potential for the US to be dependent on foreign sources for metallic beryllium within about a decade; (2) there is a need for a national policy on beryllium utilization and disposition and for a beryllium coordinating committee to be assembled to provide guidance on that policy; (3) it appears it will be difficult to dispose of this material at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico due to issues of Defense classification, facility radioactivity inventory limits, and transportation to WIPP; (4) there is a need for a funded DOE program to seek resolution of these issues including research on processing techniques that may make this waste acceptable in an existing disposal pathway or allow for its recycle.

  5. Validation of FSP Reactor Design with Sensitivity Studies of Beryllium-Reflected Critical Assemblies

    SciTech Connect (OSTI)

    John D. Bess; Margaret A. Marshall

    2013-02-01T23:59:59.000Z

    The baseline design for space nuclear power is a fission surface power (FSP) system: sodium-potassium (NaK) cooled, fast spectrum reactor with highly-enriched-uranium (HEU)-O2 fuel, stainless steel (SS) cladding, and beryllium reflectors with B4C control drums. Previous studies were performed to evaluate modeling capabilities and quantify uncertainties and biases associated with analysis methods and nuclear data. Comparison of Zero Power Plutonium Reactor (ZPPR)-20 benchmark experiments with the FSP design indicated that further reduction of the total design model uncertainty requires the reduction in uncertainties pertaining to beryllium and uranium cross-section data. Further comparison with three beryllium-reflected HEU-metal benchmark experiments performed at the Oak Ridge Critical Experiments Facility (ORCEF) concluded the requirement that experimental validation data have similar cross section sensitivities to those found in the FSP design. A series of critical experiments was performed at ORCEF in the 1960s to support the Medium Power Reactor Experiment (MPRE) space reactor design. The small, compact critical assembly (SCCA) experiments were graphite- or beryllium-reflected assemblies of SS-clad, HEU-O2 fuel on a vertical lift machine. All five configurations were evaluated as benchmarks. Two of the five configurations were beryllium reflected, and further evaluated using the sensitivity and uncertainty analysis capabilities of SCALE 6.1. Validation of the example FSP design model was successful in reducing the primary uncertainty constituent, the Be(n,n) reaction, from 0.28 %dk/k to 0.0004 %dk/k. Further assessment of additional reactor physics measurements performed on the SCCA experiments may serve to further validate FSP design and operation.

  6. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Energy Technology Research Institute

    2008-05-15T23:59:59.000Z

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  7. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01T23:59:59.000Z

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  8. "Diffusion of Innovation: Solar Oven Use in Lesotho (Africa)." Grundy, William and Roy Grundy. Advances in Solar Cooking: Proceedings of the 2nd International Conference on Solar Cooker Use and Technology. Shyam S. Nandwani, ed. July 12-15, 1994.

    E-Print Network [OSTI]

    Noble, William Stafford

    "Diffusion of Innovation: Solar Oven Use in Lesotho (Africa)." Grundy, William and Roy Grundy. Advances in Solar Cooking: Proceedings of the 2nd International Conference on Solar Cooker Use and Technology. Shyam S. Nandwani, ed. July 12-15, 1994. pp. 240-247. 1 DIFFUSION OF INNOVATION: SOLAR OVEN USE

  9. Sampling for Beryllium Surface Contamination using Wet, Dry and Alcohol Wipe Sampling

    SciTech Connect (OSTI)

    Kerr, Kent

    2004-12-17T23:59:59.000Z

    This research project was conducted at the National Nuclear Security Administration's Kansas City Plant, operated by Honeywell Federal Manufacturing and Technologies, in conjunction with the Safety Sciences Department of Central Missouri State University, to compare relative removal efficiencies of three wipe sampling techniques currently used at Department of Energy facilities. Efficiencies of removal of beryllium contamination from typical painted surfaces were tested by wipe sampling with dry Whatman 42 filter paper, with water-moistened (Ghost Wipe) materials, and by methanol-moistened wipes. Test plates were prepared using 100 mm X 15 mm Pyrex Petri dishes with interior surfaces spray painted with a bond coat primer. To achieve uniform deposition over the test plate surface, 10 ml aliquots of solution containing 1 beryllium and 0.1 ml of metal working fluid were transferred to the test plates and subsequently evaporated. Metal working fluid was added to simulate the slight oiliness common on surfaces in metal working shops where fugitive oil mist accumulates over time. Sixteen test plates for each wipe method (dry, water, and methanol) were processed and sampled using a modification of wiping patterns recommended by OSHA Method 125G. Laboratory and statistical analysis showed that methanol-moistened wipe sampling removed significantly more (about twice as much) beryllium/oil-film surface contamination as water-moistened wipes (p< 0.001), which removed significantly more (about twice as much) residue as dry wipes (p <0.001). Evidence for beryllium sensitization via skin exposure argues in favor of wipe sampling with wetting agents that provide enhanced residue removal efficiency.

  10. Nuclear Transmutations in HFIR's Beryllium Reflector and Their Impact on Reactor Operation and Reflector Disposal

    SciTech Connect (OSTI)

    Chandler, David [ORNL; Maldonado, G Ivan [ORNL; Primm, Trent [ORNL; Proctor, Larry Duane [ORNL

    2012-01-01T23:59:59.000Z

    The High Flux Isotope Reactor located at the Oak Ridge National Laboratory utilizes a large cylindrical beryllium reflector that is subdivided into three concentric regions and encompasses the compact reactor core. Nuclear transmutations caused by neutron activation occur in the beryllium reflector regions, which leads to unwanted neutron absorbing and radiation emitting isotopes. During the past year, two topics related to the HFIR beryllium reflector were reviewed. The first topic included studying the neutron poison (helium-3 and lithium-6) buildup in the reflector regions and its affect on beginning-of-cycle reactivity. A new methodology was developed to predict the reactivity impact and estimated symmetrical critical control element positions as a function of outage time between cycles due to helium-3 buildup and was shown to be in better agreement with actual symmetrical critical control element position data than the current methodology. The second topic included studying the composition of the beryllium reflector regions at discharge as well as during decay to assess the viability of transporting, storing, and ultimately disposing the reflector regions currently stored in the spent fuel pool. The post-irradiation curie inventories were used to determine whether the reflector regions are discharged as transuranic waste or become transuranic waste during the decay period for disposal purposes and to determine the nuclear hazard category, which may affect the controls invoked for transportation and temporary storage. Two of the reflector regions were determined to be transuranic waste at discharge and the other region was determined to become transuranic waste in less than 2 years after being discharged due to the initial uranium content (0.0044 weight percent uranium). It was also concluded that all three of the reflector regions could be classified as nuclear hazard category 3 (potential for localized consequences only).

  11. ORISE: Beryllium Testing and Surveillance for the U.S. Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory | NationalJohnSecurityControlsOMBRadiationHowdesignedBeryllium

  12. Beryllium Sampling and Analysis Within the DOE Complex and Opportunities for Standardization

    SciTech Connect (OSTI)

    BRISSON, MICHAEL

    2005-01-25T23:59:59.000Z

    Since the U. S. Department of Energy (DOE) published the DOE Beryllium Rule (10 CFR 850) in 1999, DOE sites have been required to measure beryllium on air filters and wipes for worker protection and for release of materials from beryllium-controlled areas. Measurements in the nanogram range on a filter or wipe are typically required. Industrial hygiene laboratories have applied methods from various analytical compendia, and a number of issues have emerged with sampling and analysis practices. As a result, a committee of analytical chemists, industrial hygienists, and laboratory managers was formed in November 2003 to address the issues. The committee developed a baseline questionnaire and distributed it to DOE sites and other agencies in the U.S. and U.K. The results of the questionnaire are presented in this paper. These results confirmed that a wide variety of practices were in use in the areas of sampling, sample preparation, and analysis. Additionally, although these laboratories are generally accredited by the American Industrial Hygiene Association (AIHA), there are inconsistencies in performance among accredited labs. As a result, there are significant opportunities for development of standard methods that could improve consistency. The current availabilities and needs for standard methods are further discussed in a companion paper.

  13. Influence of Atomic Physics on EDGE2D-EIRENE Simulations of JET Divertor Detachment with Carbon and Beryllium/Tungsten Plasma-Facing Components

    E-Print Network [OSTI]

    Influence of Atomic Physics on EDGE2D-EIRENE Simulations of JET Divertor Detachment with Carbon and Beryllium/Tungsten Plasma-Facing Components

  14. Target Particle and Heat Loads in Low-Triangularity L-mode Plasmas in JET with Carbon and Beryllium/Tungsten Walls

    E-Print Network [OSTI]

    Target Particle and Heat Loads in Low-Triangularity L-mode Plasmas in JET with Carbon and Beryllium/Tungsten Walls

  15. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

    2006-08-01T23:59:59.000Z

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  16. Results of the radiological and beryllium verification survey at the Sacandaga Site, Glenville, New York (SY002V)

    SciTech Connect (OSTI)

    Foley, R.D.; Cottrell, W.D.; Johnson, C.A.

    1994-09-01T23:59:59.000Z

    At the request of the US Department of Energy (DOE), a team from Oak Ridge National Laboratory conducted an independent verification radiological and non-radioactive beryllium survey at the Sacandaga Site, located on Sacandaga Road, Glenville, New York following limited remediation of the site by Allwash of Syracuse, Inc. At the time of this survey, only building P was still standing. A small concrete structure at the east of the property had been demolished and the debris hauled away, leaving only a pit. The purpose of the survey, conducted between April and August 1993, was to confirm the success of the remedial actions performed to remove any beryllium concentrations or radioactive materials in excess of the identified guidelines. The verification survey included surface gamma scans and gamma readings at 1 meter indoors and outdoors, alpha and beta scans inside building P, and the collection of soil, dust and debris samples and smears for radionuclide and beryllium analyses. Results of the survey demonstrated that all radiological and beryllium measurements on the property were within applicable DOE guidelines. Based on all data collected. the Sacandaga Site, Glenville, New York, conforms to all applicable radiological and non-radioactive beryllium guidelines established for this site by DOE and approved by the State of New York.

  17. Results of the radiological and beryllium verification survey at the Peek Street Site, Schenectady, New York (SY001V)

    SciTech Connect (OSTI)

    Foley, R.D.; Johnson, C.A.; Carrier, R.F.; Allred, J.F.

    1994-10-01T23:59:59.000Z

    At the request of the U.S. Department of Energy (DOE), a team from Oak Ridge National Laboratory conducted an independent verification radiological and non-radioactive beryllium survey at the Peek Street site, located at 425 Peek Street, Schenectady, New York. The purpose of the survey, conducted during 1993 and continuing through January 1994, was to confirm the success of the remedial actions performed to remove any beryllium concentrations or radioactive materials in excess of the identified guidelines. The verification survey included surface gamma scans and gamma readings at one meter indoors and outdoors, alpha and beta scans inside the structure, and the collection of soil, dust and debris samples and smears for radionuclide and beryllium analyses. Results of the survey demonstrated that all radiological and beryllium measurements on the property were within applicable DOE guidelines. Based on all data collected, the industrial property at 425 Peek Street and the adjacent state-owned bike path in Schenectady, New York, conforms to all applicable radiological and non-radioactive beryllium guidelines established for this site by DOE and approved by the State of New York.

  18. Beryllium Health and Safety Committee Data Reporting Task Force White Paper #2 -- Uses of Uncensored Data

    SciTech Connect (OSTI)

    MacQueen, D H

    2007-10-10T23:59:59.000Z

    On December 8, 1999, the Department of Energy (DOE) published Title 10 CFR 850 (hereafter referred to as the Rule) to establish a chronic beryllium disease prevention program (CBDPP) to: (1) reduce the number of workers currently exposed to beryllium in the course of their work at DOE facilities managed by DOE or its contractors; (2) minimize the levels of, and potential for, exposure to beryllium; and (3) establish medical surveillance requirements to ensure early detection of the disease. On January 4, 2001, DOE issued DOE G 440.1-7A, Implementation Guide for use with 10 CFR 850, Chronic Beryllium Disease Prevention Program, to assist line managers in meeting their responsibilities for implementing the CBDPP. That guide describes methods and techniques that DOE considers acceptable in complying with the Rule. In 2005 a draft DOE Technical Standard ''Management of Items and Areas Containing Low Levels of Beryllium'' (SAFT 0103; hereafter referred to as the ''TS'') was circulated for comment (http://www.hss.energy.gov/NuclearSafety/techstds/tsdrafts/saft-0103.pdf). DOE technical standards are voluntary consensus standards developed when industry standards do not exist (see http://www.hss.energy.gov/NuclearSafety/techstds/index.html for more information). DOE does not require its field elements to implement DOE technical standards, but field elements may choose to adopt these standards to meet specific needs. This beryllium TS is intended to provide best practices and lessons learned for manageing items and areas that contain low levels of beryllium, which has been a costly and technically challenging component of CBDPPs. The TS is also intended to provide guidance for determining if the Rule's housekeeping and release criteria are met. On challenge the TS addressed was the statistical interpretation of data sets with non-detected results, a topic for which no strong consensus exists. Among the many comments on the draft TS was a suggestion that certain of the statistical comparisons described in the TS could be better implemented if analytical results, even when below a reporting limit, were to be reported by analytical laboratories. See Appendix 1 for a review of terminology related to reporting limits. The Beryllium Health and Safety Committee (BHSC) formed a Sampling and Analysis Subcommittee (SAS) in 2003. The SAS established a working group on accreditation and reporting limits. By 2006 it had become evident that the issues extended to data reporting as a whole. The SAS proposed to the BHSC the formation of a Data Reporting Task Force (DRTF) to consider issues related to data reporting. The BHSC Board agreed, and requested that the DRTF generate a white paper, to be offered by the BHSC to potential interested parties such as the DOE policy office that is responsible for beryllium health and safety policy. It was noted that additional products could include detailed guidance and potentially a journal article in the future. The SAS proposed that DRTF membership represent the affected disciplines (chemists, industrial hygiene professionals and statisticians, and the DOE office that is responsible for beryllium health and safety policy). The BHSC Board decided that DRTF membership should come from DOE sites, since the focus would be on reporting in the context of the TS and the Rule. The DRTF came into existence in late 2006. The DRTF membership includes industrial hygienists, analytical chemists and laboratory managers, members of the regulatory and oversight community, and environmental statisticians. A first White Paper, ''Summary of Issues and Path Forward'', was reviewed by the BHSC in March 2007 and issued by the DRTF in June 2007. It describes the charter of the DRTF, introduces some basic terminology (reproduced here in Appendix 1), lays out the issues the DRTF is expected to address, and describes a path forward for the DRTF's work. This first White Paper is available through the BHSC web site. This White Paper presents recommendations developed by the DRTF following the process laid out in that first White Pap

  19. Trace-level beryllium analysis in the laboratory and in the field: State of the art, challenges, and opportunities

    SciTech Connect (OSTI)

    BRISSON, MICHAEL

    2006-03-30T23:59:59.000Z

    Control of workplace exposure to beryllium is a growing issue in the United States and other nations. As the health risks associated with low-level exposure to beryllium are better understood, the need increases for improved analytical techniques both in the laboratory and in the field. These techniques also require a greater degree of standardization to permit reliable comparison of data obtained from different locations and at different times. Analysis of low-level beryllium samples, in the form of air filters or surface wipes, is frequently required for workplace monitoring or to provide data to support decision-making on implementation of exposure controls. In the United States and the United Kingdom, the current permissible exposure level is 2 {micro}g/m{sup 3} (air), and the United States Department of Energy has implemented an action level of 0.2 {micro}g/m{sup 3} (air) and 0.2 {micro}g/100 cm{sup 2} (surface). These low-level samples present a number of analytical challenges, including (1) a lack of suitable standard reference materials, (2) unknown robustness of sample preparation techniques, (3) interferences during analysis, (4) sensitivity (sufficiently low detection limits), (5) specificity (beryllium speciation), and (6) data comparability among laboratories. Additionally, there is a need for portable, real-time (or near real-time) equipment for beryllium air monitoring and surface wipe analysis that is both laboratory-validated and field-validated in a manner that would be accepted by national and/or international standards organizations. This paper provides a review of the current analytical requirements for trace-level beryllium analysis for worker protection, and also addresses issues that may change those requirements. The current analytical state of the art and relevant challenges facing the analytical community will be presented, followed by suggested criteria for real-time monitoring equipment. Recognizing and addressing these challenges will present opportunities for laboratories, research and development organizations, instrument manufacturers, and others.

  20. Single and double photoionization of beryllium below 40 eV

    SciTech Connect (OSTI)

    Wehlitz, R.; Bluett, J.B. [Synchrotron Radiation Center, UW-Madison, Stoughton, Wisconsin 53589 (United States); Lukic, D. [Institute of Physics, 11001 Belgrade (Serbia and Montenegro)

    2005-01-01T23:59:59.000Z

    We have measured the double-to-single photoionization ratio of beryllium (1s{sup 2}2s{sup 2}) between 28 and 40 eV and determined the relative single- and double-photoionization cross sections. In this energy region only simultaneous but not sequential emission of both 2s electrons can take place. We also compare our data with recent theoretical calculations and find good agreement with our data. The previously found scaling law for the double-to-single photoionization ratio is confirmed with high accuracy.

  1. A Lithium-Beryllium Method for the Detection of Solar Neutrinos

    E-Print Network [OSTI]

    A. V. Kopylov; I. V. Orekhov; V. V. Petukhov; A. E. Solomatin

    2009-10-20T23:59:59.000Z

    A method for the detection of solar neutrino has been developed using the laboratory bench installations. The efficiency of the extraction of beryllium from lithium as high as 96.4{%} has been achieved, and it was shown that lithium losses during the extraction were less than 1{%}. The prospects of a full-scale experiment with a 10-t lithium detector consisting of twenty 500-kg lithium modules are discussed. The technical solutions formulated on the basis of this study enable to make design of a pilot lithium installation containing 500 kg of metallic lithium

  2. Broadly tunable chromium-doped beryllium aluminate lasers and operation thereof

    SciTech Connect (OSTI)

    Jenssen, H.P.; Morris, R.C.; Peterson, O.G.; Walling, J.C.

    1981-06-09T23:59:59.000Z

    A high power, broadly wavelength-tunable laser is provided which comprises as the laser medium particular single crystals of chromium-doped beryllium aluminate (BeAl/sub 2/O/sub 4/:Cr/sup 3 +/) having the chrysoberyl structure, means for exciting the laser medium and tuning means. The laser may be operated over a broad temperature range from cryogenic temperatures to elevated temperatures. Elevated temperatures are preferred, however, since they result in higher laser gain. Emission is in a spectral range from red to infrared, and the laser is useful in the fields of defense, communications, isotope separation, photochemistry, etc.

  3. Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy

    SciTech Connect (OSTI)

    S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

    2009-03-15T23:59:59.000Z

    Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

  4. Graphite and Beryllium Reflector Critical Assemblies of UO2 (Benchmark Experiments 2 and 3)

    SciTech Connect (OSTI)

    Margaret A. Marshall; John D. Bess

    2012-11-01T23:59:59.000Z

    INTRODUCTION A series of experiments was carried out in 1962-65 at the Oak Ridge National Laboratory Critical Experiments Facility (ORCEF) for use in space reactor research programs. A core containing 93.2 wt% enriched UO2 fuel rods was used in these experiments. The first part of the experimental series consisted of 252 tightly-packed fuel rods (1.27-cm triangular pitch) with graphite reflectors [1], the second part used 252 graphite-reflected fuel rods organized in a 1.506-cm triangular-pitch array [2], and the final part of the experimental series consisted of 253 beryllium-reflected fuel rods in a 1.506-cm-triangular-pitch configuration and in a 7-tube-cluster configuration [3]. Fission rate distribution and cadmium ratio measurements were taken for all three parts of the experimental series. Reactivity coefficient measurements were taken for various materials placed in the beryllium reflected core. All three experiments in the series have been evaluated for inclusion in the International Reactor Physics Experiment Evaluation Project (IRPhEP) [4] and the International Criticality Safety Benchmark Evaluation Project (ICSBEP) Handbooks, [5]. The evaluation of the first experiment in the series was discussed at the 2011 ANS Winter meeting [6]. The evaluations of the second and third experiments are discussed below. These experiments are of interest as benchmarks because they support the validation of compact reactor designs with similar characteristics to the design parameters for a space nuclear fission surface power systems [7].

  5. Procedure for calibration of a portable, real-time beryllium aerosol monitor based on laser-induced breakdown spectroscopy

    E-Print Network [OSTI]

    Killough, David Thomas

    2012-06-07T23:59:59.000Z

    Spectroscopy (LIPS), is an analytical method whereby atmospheric components and contaminants may be analyzed in real-time or near real-time directly in the workplace. A transportable beryllium air monitor system based on LIBS has been developed at the Los...

  6. AN INTERSTELLAR ORIGIN FOR THE BERYLLIUM 10 IN CALCIUM-RICH, ALUMINUM-RICH INCLUSIONS S. J. Desch1

    E-Print Network [OSTI]

    Connolly Jr, Harold C.

    , Brooklyn, NY 11235; and American Museum of Natural History, Department of Earth and Planetary Sciences, Central Park West at 79th Street, New York, NY 10024; and Rutgers University, Department of Geological into calcium-rich, aluminum-rich inclusions (CAIs) at the birth of our solar system. Beryllium 10 is unique

  7. Lesson 9 - Solar Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and Interfaces Sample6, 2011 LawrenceE C H NLensless Lesson 16 - Pinwheel

  8. Supplement of Atmos. Chem. Phys., 14, 65716603, 2014 http://www.atmos-chem-phys.net/14/6571/2014/

    E-Print Network [OSTI]

    Pierce, Jeffrey

    for coal-charging process 0 0 0 0 10 10 0 FGD for coke oven gas 0 0 0 0 10 10 0 Combination[1] BAU[2]/PC[2] 2005 2010 2020 2030 2020 2030 2030 Sintering FGD 0 10 20 40 95 100 100 Coke oven FGD 100 Hot rolling ESP 0 0 0 0 70 95 100 Cold rolling HED 0 0 0 0 70 95 100 Coke oven WET 100 100 100 100

  9. The effect of varying oven temperatures and residence times on thermal desorption of n-hexane and 1-hexene from diffusive organic vapor dosimeters

    E-Print Network [OSTI]

    Steele, Kenneth Garnett

    1981-01-01T23:59:59.000Z

    , which caused a pis- ton situated on top of the thermal desorber to be pneuma- tically pulled up, causing nitrogen purge gas from the connected cylinder to be drawn up through the desorbing oven containing an empty flare tube and then into the de...M Monitor into Foil Pouch 5. Sealed Foil Pouch, Ready for Storage 6. Filter Paper in place on Draft Shield 7. Injecting 10pL Liquid Sample onto Filter Paper 8. Rolling Charcoal Wafer into a Cylinder 9, Inserting Charcoal Wafer into Flare Tube...

  10. 7, 14791506, 2007 apportionment of the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , coal residential, coke oven, coal power plant, biomass burning, natural gas (NG) combustion. The major showed distinct seasonal variations. High contributions of biomass burning and coal (residential and coke is the world's largest coal consumption region (IEA, 2006). Thu

  11. Further investigation of the impact of the co-combustion of tire-derived fuel and petroleum coke on the petrology and chemistry of coal combustion products

    SciTech Connect (OSTI)

    Hower, J.C.; Robertson, J.D.; Elswick, E.R.; Roberts, J.M.; Brandsteder, K.; Trimble, A.S.; Mardon, S.M. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    2007-07-01T23:59:59.000Z

    A Kentucky cyclone-fired unit burns coal and tire-derived fuel, sometimes in combination with petroleum coke. A parallel pulverized combustion (pc) unit at the same plant burns the same coal, without the added fuels. The petrology, chemistry, and sulfur isotope distribution in the fuel and resulting combustion products was investigated for several configurations of the fuel blend. Zinc and Cd in the combustion products are primarily contributed from the tire-derived fuel, the V and Ni are primarily from the petroleum coke, and the As and Hg are probably largely from the coal. The sulfur isotope distribution in the cyclone unit is complicated due to the varying fuel sources. The electrostatic precipitator (ESP) array in the pc unit shows a subtle trend towards heavier S isotopic ratios in the cooler end of the ESP.

  12. Supplementary radiological and beryllium characterization of the facility at 425 Peek Street, Schenectady, New York

    SciTech Connect (OSTI)

    Foley, R.D.; Allred, J.F.; Carrier, R.F.

    1994-10-01T23:59:59.000Z

    At the request of the Office of Naval Reactors through the Office of Remedial Action and Waste Technology, a radiological survey of the Peek Street industrial facility, the adjacent state-owned bike path, and two nearby residential properties was conducted by Oak Ridge National Laboratory (ORNL) in November 1989. The results indicated small isolated areas that exceeded DOE guidelines. These areas totaled approximately 0.2 m{sup 2} of floor area and approximately 3 m{sup 2} of wall area inside the building, and two small areas totaling approximately 5 m{sup 2} outside the building. A small section of one of these areas extended beyond the fence on the east side of the industrial property onto the state-owned property. No residual radioactive material or elevated radiation levels were detected on any portion of the paved section of the bike path or the residential properties adjacent to the site. Because the elevated radiation levels were localized and limited in extent, any credible use scenario, including current use conditions, indicated that no significant radiation exposures would accrue to individuals frequenting the area. Samples were also analyzed for elemental beryllium since that material had formerly been used at the site. In conjunction with the planned remediation at the facility, a supplementary characterization survey was performed to further define the areas containing beryllium in excess of the identified guidelines. Additional radiological characterization of Ra-226, Th-232, and U-238 was also performed in areas that were largely inaccessible prior to the remediation efforts.

  13. Neutron flux and energy characterization of a plutonium-beryllium isotopic neutron source by Monte Carlo simulation with verification by neutron activation analysis.

    E-Print Network [OSTI]

    Harvey, Zachary R

    2010-01-01T23:59:59.000Z

    ??The purpose of this research was to characterize the neutron energy distribution and flux emitted from the UNLV plutonium-beryllium source, serial number MRC-N-W PuBe 453.… (more)

  14. Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

    2005-12-01T23:59:59.000Z

    High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

  15. EA-0404: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Innovative Clean Coal Technology Program - Coke Oven Gas Cleaning Demonstration Project at the Bethlehem Steel Corp. Sparrows Point Plant, Baltimore County, Maryland

  16. brwtp-icoke | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Dec 1989) Comprehensive Report to Congress Comprehensive Report to Congress on the Clean Coal Technology Program: Innovative Coke Oven Gas Cleaning System for Retrofit...

  17. Effects of polymerization and briquetting parameters on the tensile strength of briquettes formed from coal coke and aniline-formaldehyde resin

    SciTech Connect (OSTI)

    Demirbas, A.; Simsek, T. [Selcuk University, Konya (Turkey)

    2006-10-15T23:59:59.000Z

    In this work, the utilization of aniline (C{sub 6}H{sub 7}N) formaldehyde (HCHO) resins as a binding agent of coke briquetting was investigated. Aniline (AN) formaldehyde (F) resins are a family of thermoplastics synthesized by condensing AN and F in an acid solution exhibiting high dielectric strength. The tensile strength sharply increases as the ratio of F to AN from 0.5 to 1.6, and it reaches the highest values between 1.6 and 2.2 F/AN ratio; it then slightly decreases. The highest tensile strength of F-AN resin-coke briquette (23.66 MN/m{sup 2}) was obtained from the run with 1.5 of F/AN ratio by using (NH4){sub 2}S{sub 2}O{sub 8} catalyst at 310 K briquetting temperature. The tensile strength of F-AN resin-coke briquette slightly decreased with increasing the catalyst percent to 0.10%, and then it sharply decreased to zero with increasing the catalyst percent to 0.2%. The effect of pH on the tensile strength is irregular. As the pH of the mixture increases from 9.0 to 9.2, the tensile strength shows a sharp increase, and the curve reaches a plateau value between pH 9.3 and 9.9; then the tensile strength shows a slight increase after pH = 9.9.

  18. Reduction of COD in leachate from a hazardous waste landfill adjacent to a coke-making facility

    SciTech Connect (OSTI)

    Banerjee, K.; O`Toole, T.J. [Chester Environmental, Moon Township, PA (United States)

    1995-12-01T23:59:59.000Z

    A hazardous waste landfill adjacent to a coke manufacturing facility was in operation between July 1990 and December 1991. A system was constructed to collect and treat the leachate from the landfill prior to discharge to the river. Occasionally, the discharge from the treatment facility exceeded the permit limitations for Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), and Total Organic Carbon (TOC). The objectives of this study were to determine treatment methods which would enable compliance with the applicable discharge limits; to establish the desired operating conditions of the process; and to investigate the effect of various parameters such as pH, catalyst dosage, and reaction time on the COD destruction efficiency. The characteristics of the landfill leachate in question were significantly variable in terms of chemical composition. A review of the influent quality data suggests that the COD concentration ranges between 80 and 390 mg/l. The oxidation processes using Fenton`s reagent or a combination of UV/hydrogen peroxide/catalyst are capable of reducing the COD concentration of the leachate below the discharge limitation of 35 mg/l. The estimated capital cost associated with the Fenton`s reagent process is approximately $525,000, and the annual operating and maintenance cost is $560,000. The estimated capital cost for the UV/hydrogen peroxide/catalyst treatment system is $565,000. The annual operating and maintenance cost of this process would be approximately $430,000.

  19. Massachusetts Beryllium Screening Program for Former Workers of Wyman-Gordon, Norton Abrasives, and MIT/Nuclear Metals

    SciTech Connect (OSTI)

    Pepper, L.D.

    2008-05-21T23:59:59.000Z

    The overall objective of this project was to provide medical screening to former workers of Wyman-Gordon Company, Norton Abrasives, and MIT/Nuclear Metals (NMI) in order to prevent and minimize the health impact of diseases caused by site related workplace exposures to beryllium. The program was developed in response to a request by the U.S. Department of Energy (DOE) that had been authorized by Congress in Section 3162 of the 1993 Defense Authorization Act, urging the DOE to â??carry out a program for the identification and ongoing evaluation of current and former DOE employees who are subjected to significant health risks during such employment." This program, funded by the DOE, was an amendment to the medical surveillance program for former DOE workers at the Nevada Test Site (NTS). This programâ??s scope included workers who had worked for organizations that provided beryllium products or materials to the DOE as part of their nuclear weapons program. These organizations have been identified as Beryllium Vendors.

  20. ORALLOY (93.15 235U) METAL ANNULI WITH BERYLLIUM CORE

    SciTech Connect (OSTI)

    John D. Bess; Leland M. Montierth; Raymond L. Reed; John T. Mihalczo

    2010-09-01T23:59:59.000Z

    A variety of critical experiments were constructed of enriched uranium metal during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, two were performed that consisted of uranium metal annuli with a solid beryllium metal core. The outer diameter of the annuli was approximately 13 or 15 inches with an inner diameter of 7 inches. The diameter of the core was approximately 7 inches. The critical height of the configurations was approximately 5 and 4 inches, respectively. The uranium annuli consisted of multiple stacked rings with diametral thicknesses of approximately 2 inches apiece and varying heights. The 15-inch experiment was performed on June 4, 1963, and the 13-inch experiment on July 12, 1963 by J. T. Mihalczo and R. G. Taylor (Ref. 1) with accompanying logbook. Both detailed and simplified model specifications are provided in this evaluation. Both of these fast-spectra experiments were determined to represent acceptable benchmarks. The calculated eigenvalues for both the detailed and simple models are within approximately 0.6% of the benchmark values, but significantly greater than 3s from the benchmark value because the uncertainty in the benchmark is very small: <±0.0004 (1s). There is significant variability between results using different neutron cross section libraries, the greatest being a ?keff of ~0.67%. Unreflected and unmoderated experiments with the same highly enriched uranium metal parts were performed at the Oak Ridge Critical Experiments Facility in the 1960s and are evaluated in HEU MET FAST 051. Thin graphite reflected (2 inches or less) experiments also using the same highly enriched uranium metal parts are evaluated in HEU MET FAST 071. Polyethylene-reflected configurations are evaluated in HEU-MET-FAST-076. A stack of highly enriched metal discs with a thick beryllium reflector is evaluated in HEU-MET-FAST-069.

  1. ORALLOY (93.2 235U) METAL CYLINDER WITH BERYLLIUM TOP REFLECTOR

    SciTech Connect (OSTI)

    John D. Bess; Leland M. Montierth; Raymond Reed; John T. Mihalczo

    2010-09-01T23:59:59.000Z

    A variety of critical experiments were constructed of enriched uranium metal during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, one experiment was comprised of a stack of approximately 7-inch-diameter metal discs. The bottom of the stack consisted of uranium with an approximate height of 4-1/8 inches. The top of the stack consisted of beryllium with an approximate height of 5-9/16 inches. This experiment was performed on August 20, 1963 by J. T. Mihalczo and R. G. Taylor (Ref. 1) with accompanying logbook. Both detailed and simplified model specifications are provided in this evaluation. This fast-spectra experiment was determined to represent an acceptable benchmark. The calculated eigenvalues for both the detailed and simple models are within approximately 0.5% of the benchmark values, but significantly greater than 3s from the benchmark value because the uncertainty in the benchmark is very small: ±0.0002 (1s). There is significant variability between results using different neutron cross section libraries, the greatest being a ?keff of ~0.65% . Unreflected and unmoderated experiments with the same highly enriched uranium metal parts were performed at the Oak Ridge Critical Experiments Facility in the 1960s and are evaluated in HEU MET FAST 051. Thin graphite reflected (2 inches or less) experiments also using the same highly enriched uranium metal parts are evaluated in HEU MET FAST 071. Polyethylene-reflected configurations are evaluated in HEU-MET-FAST-076. Highly enriched metal annuli with beryllium cores are evaluated in HEU-MET-FAST-059.

  2. Selection of Russian Plutonium Beryllium Sources for Inclusion in the Nuclear Mateirals Information Program Archive

    SciTech Connect (OSTI)

    Narlesky, Joshua E [Los Alamos National Laboratory; Padilla, Dennis D [Los Alamos National Laboratory; Watts, Joe [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    Throughout the 1960s and 1970s, the former Soviet Union produced and exported Plutonium-Beryllium (PuBe) neutron sources to various Eastern European countries. The Russian sources consist of an intermetallic compound of plutonium and beryllium encapsulated in an inner welded, sealed capsule and consisting of a body and one or more covers. The amount of plutonium in the sources ranges from 0.002 g up to 15 g. A portion of the sources was originally exported to East Germany. A portion of these sources were acquired by Los Alamos National Laboratory (LANL) in the late 1990s for destruction in the Offsite Source Recovery Program. When the OSRP was canceled, the remaining 88 PuBe neutron sources were packaged and stored in a 55-gal drum at T A-55. This storage configuration is no longer acceptable for PuBe sources, and the sources must either be repackaged or disposed of. Repackaging would place the sources into Hagan container, and depending on the dose rates, some sources may be packaged individually increasing the footprint and cost of storage. In addition, each source will be subject to leak-checking every six months. Leaks have already been detected in some of the sources, and due to the age of these sources, it is likely that additional leaks may be detected over time, which will increase the overall complexity of handling and storage. Therefore, it was decided that the sources would be disposed of at the Waste Isolation Pilot Plant (WIPP) due to the cost and labor associated with continued storage at TA-55. However, the plutonium in the sources is of Russian origin and needs to be preserved for research purposes. Therefore, it is important that a representative sample of the sources retained and archived for future studies. This report describes the criteria used to obtain a representative sample of the sources. Nine Russian PuBe neutron sources have been selected out of a collection of 77 sources for inclusion in the NMIP archive. Selection criteria were developed so that the largest sources that are representative of the collection are included. One representative source was chosen for every 20 sources in the collection, and effort was made to preserve sources unique to the collection. In total, four representative sources and five unique sources were selected for the archive. The archive samples contain 40 grams of plutonium with an isotopic composition similar to that of weapon grade material and three grams of plutonium with an isotopic composition similar to that of reactor grade plutonium.

  3. A Comparison of "Total Dust" and Inhalable Personal Sampling for Beryllium Exposure.

    SciTech Connect (OSTI)

    Carter, C M

    2012-04-25T23:59:59.000Z

    In 2009, the American Conference of Governmental Industrial Hygienists (ACGIH) reduced the Beryllium (Be) 8-hr Time Weighted Average Threshold Limit Value (TLV-TWA) from 2.0 {micro}g/m{sup 3} to 0.05 {micro}g/m{sup 3} with an inhalable 'I' designation in accordance with ACGIH's particle size-selective criterion for inhalable mass. Currently, per the Department of Energy (DOE) requirements, the Lawrence Livermore National Laboratory (LLNL) is following the Occupational Health and Safety Administration (OSHA) Permissible Exposure Limit (PEL) of 2.0 {micro}g/m{sup 3} as an 8-hr TWA, which is also the 2005 ACGIH TLV-TWA, and an Action Level (AL) of 0.2 {micro}g/m{sup 3} and sampling is performed using the 37mm (total dust) sampling method. Since DOE is considering adopting the newer 2009 TLV guidelines, the goal of this study was to determine if the current method of sampling using the 37mm (total dust) sampler would produce results that are comparable to what would be measured using the IOM (inhalable) sampler specific to the application of high energy explosive work at LLNL's remote experimental test facility at Site 300. Side-by-side personal sampling using the two samplers was performed over an approximately two-week period during chamber re-entry and cleanup procedures following detonation of an explosive assembly containing Beryllium (Be). The average ratio of personal sampling results for the IOM (inhalable) vs. 37-mm (total dust) sampler was 1.1:1 with a P-value of 0.62, indicating that there was no statistically significant difference in the performance of the two samplers. Therefore, for the type of activity monitored during this study, the 37-mm sampling cassette would be considered a suitable alternative to the IOM sampler for collecting inhalable particulate matter, which is important given the many practical and economic advantages that it presents. However, similar comparison studies would be necessary for this conclusion to be applied to other types of activities, where earlier studies have shown that the IOM sampler tends to collect higher concentrations of Be compared to the 37-mm cassette, which could complicate compliance with what is already an extremely low exposure limit.

  4. Electron transport properties of bis[2-(2-hydroxyphenyl)-pyridine]beryllium investigated by impedance spectroscopy

    SciTech Connect (OSTI)

    Wang, Yanping; Chen, Jiangshan; Huang, Jinying; Ma, Dongge, E-mail: mdg1014@ciac.jl.cn, E-mail: dongls@ciac.jl.cn [State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, Changchun 130022 (China); Dong, Lisong, E-mail: mdg1014@ciac.jl.cn, E-mail: dongls@ciac.jl.cn [Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, Changchun 130022 (China); Chen, Hui [Department of Science, Shenyang University of Chemical Technology, Shenyang 110142 (China)

    2014-06-14T23:59:59.000Z

    The electron transport properties of bis[2-(2-hydroxyphenyl)-pyridine] beryllium (Bepp{sub 2}) are investigated by impedance spectroscopy over a frequency range of 10?Hz to 13?MHz. The Cole-Cole plots demonstrate that the Bepp{sub 2}-based device can be represented by a single parallel resistance R{sub p} and capacitance C{sub p} network with a series resistance R{sub s}. The current-voltage characteristics and the variation of R{sub p} with applied bias voltage indicate the electron conduction of space-charge-limited current with exponential trap distributions in Bepp{sub 2}. It can be seen that the electron mobility exhibits strong field-dependence in low electric field region and almost saturate in high electric field region. It is experimentally found that Bepp{sub 2} shows dispersion transport and becomes weak as the electric field increases. The activation energy is determined to be 0.043?eV by temperature-dependent conductivity, which is consistent with the result obtained from the temperature-dependent current density characteristics. The electron mobility reaches the orders of 10{sup ?6}–10{sup ?5} cm{sup 2} V{sup ?1} s{sup ?1}, depending on the electric field.

  5. Packaging and Disposal of a Radium-beryllium Source using Depleted Uranium Polyethylene Composite Shielding

    SciTech Connect (OSTI)

    Keith Rule; Paul Kalb; Pete Kwaschyn

    2003-02-11T23:59:59.000Z

    Two, 111-GBq (3 Curie) radium-beryllium (RaBe) sources were in underground storage at the Brookhaven National Laboratory (BNL) since 1988. These sources originated from the Princeton Plasma Physics Laboratory (PPPL) where they were used to calibrate neutron detection diagnostics. In 1999, PPPL and BNL began a collaborative effort to expand the use of an innovative pilot-scale technology and bring it to full-scale deployment to shield these sources for eventual transport and burial at the Hanford Burial site. The transport/disposal container was constructed of depleted uranium oxide encapsulated in polyethylene to provide suitable shielding for both gamma and neutron radiation. This new material can be produced from recycled waste products (depleted uranium and polyethylene), is inexpensive, and can be disposed with the waste, unlike conventional lead containers, thus reducing exposure time for workers. This paper will provide calculations and information that led to the initial design of the shielding. We will also describe the production-scale processing of the container, cost, schedule, logistics, and many unforeseen challenges that eventually resulted in the successful fabrication and deployment of this shield. We will conclude with a description of the final configuration of the shielding container and shipping package along with recommendations for future shielding designs.

  6. PACKAGING AND DISPOSAL OF A RADIUM BERYLLIUM SOURCE USING DEPLETED URANIUM POLYETHYLENE COMPOSITE SHIELDING.

    SciTech Connect (OSTI)

    RULE,K.; KALB,P.; KWASCHYN,P.

    2003-02-23T23:59:59.000Z

    Two, 111 GBq (3 Curie) radium-beryllium (RaBe) sources were in underground storage at the Brookhaven National Laboratory (BNL) since 1988. These sources originated from Princeton Plasma Physics Laboratory (PPPL) where they were used to calibrate neutron detection diagnostics. In 1999, PPPL and BNL began a collaborative effort to expand the use of an innovative pilot-scale technology and bring it to full-scale deployment to shield these sources for eventual transport and burial at the Hanford Burial site. The transport/disposal container was constructed of depleted uranium oxide encapsulated in polyethylene to provide suitable shielding for both gamma and neutron radiation. This new material can be produced from recycled waste products (DU and polyethylene), is inexpensive, and can be disposed with the waste, unlike conventional lead containers, thus reducing exposure time for workers. This paper will provide calculations and information that led to the initial design of the shielding. We will also describe the production-scale processing of the container, cost, schedule, logistics, and many unforeseen challenges that eventually resulted in the successful fabrication and deployment of this shield. We will conclude with a description of the final configuration of the shielding container and shipping package along with recommendations for future shielding designs.

  7. Optimized beryllium target design for indirectly driven inertial confinement fusion experiments on the National Ignition Facility

    SciTech Connect (OSTI)

    Simakov, Andrei N., E-mail: simakov@lanl.gov; Wilson, Douglas C.; Yi, Sunghwan A.; Kline, John L.; Batha, Steven H. [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico 87545 (United States); Clark, Daniel S.; Milovich, Jose L.; Salmonson, Jay D. [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States)] [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States)

    2014-02-15T23:59:59.000Z

    For indirect drive inertial confinement fusion, Beryllium (Be) ablators offer a number of important advantages as compared with other ablator materials, e.g., plastic and high density carbon. In particular, the low opacity and relatively high density of Be lead to higher rocket efficiencies giving a higher fuel implosion velocity for a given X-ray drive; and to higher ablation velocities providing more ablative stabilization and reducing the effect of hydrodynamic instabilities on the implosion performance. Be ablator advantages provide a larger target design optimization space and can significantly improve the National Ignition Facility (NIF) [J. D. Lindl et al., Phys. Plasmas 11, 339 (2004)] ignition margin. Herein, we summarize the Be advantages, briefly review NIF Be target history, and present a modern, optimized, low adiabat, Revision 6 NIF Be target design. This design takes advantage of knowledge gained from recent NIF experiments, including more realistic levels of laser-plasma energy backscatter, degraded hohlraum-capsule coupling, and the presence of cross-beam energy transfer.

  8. Measurement of the Melting Point Temperature of Several Lithium-Sodium-Beryllium Fluoride Salt (Flinabe) Mixtures

    SciTech Connect (OSTI)

    McDonald, J.M; Nygren, R.E.; Lutz, T.J.; Tanaka, T.J; Ulrickson, M.A.; Boyle, T.J.; Troncosa, K.P. [Sandia National Laboratories (United States)

    2005-04-15T23:59:59.000Z

    The molten salt Flibe, a combination of lithium and beryllium fluorides studied for molten salt fission reactors, has been proposed as a breeder and coolant for fusion applications. The melting points of 2LiF-BeF{sub 2} and LiF-BeF{sub 2} are 460 deg. C and 363 deg. C, but LiF-BeF{sub 2} is rather viscous and has less lithium for breeding. In the Advanced Power Extraction (APEX) Program, concepts with a free flowing liquid for the first wall and blanket were investigated. Flinabe (a mixture of LiF, BeF{sub 2} and NaF) was selected for a molten salt design because a melting temperature below 350 deg. C appeared possible and this provided an attractive operating temperature window for a reactor. To confirm that a ternary salt with a low melting temperature existed, several combinations of the fluoride salts, LiF, NaF and BeF{sub 2}, were melted in a stainless steel crucible under vacuum. One had an apparent melting temperature of 305 deg. C. The test system, preparation of the mixtures, melting procedures and temperature curves for the melting and cooling are presented along with the apparent melting points. Thermal modeling of the salt pool and crucible is reported in an accompanying paper.

  9. Helium-cooled, FLiBe-breeder, beryllium-multiplier blanket for MINIMARS

    SciTech Connect (OSTI)

    Moir, R.W.; Lee, J.D.

    1986-06-01T23:59:59.000Z

    We adapted the helium-cooled, FLiBe-breeder blanket to the commercial tandem-mirror fusion-reactor design, MINIMARS. Vanadium was used to achieve high performance from the high-energy-release neutron-capture reactions and from the high-temperature operation permitted by the refractory property of the material, which increases the conversion efficiency and decreases the helium-pumping power. Although this blanket had the highest performance among the MINIMARS blankets designs, measured by Mn/sub th/ (blanket energy multiplication times thermal conversion efficiency), it had a cost of electricity (COE) 18% higher than the University of Wisconsin (UW) blanket design (42.5 vs 35.9 mills/kW.h). This increased cost was due to using higher-cost blanket materials (beryllium and vanadium) and a thicker blanket, which resulted in higher-cost central-cell magnets and the need for more blanket materials. Apparently, the high efficiency does not substantially affect the COE. Therefore, in the future, we recommend lowering the helium temperature so that ferritic steel can be used. This will result in a lower-cost blanket, which may compensate for the lower performance resulting from lower efficiency.

  10. Experimental Investigation and Analysis of the Effective Thermal Properties of Beryllium Packed Beds

    SciTech Connect (OSTI)

    Abou-Sena, A.; Ying, A.; Abdou, M. [University of California at Los Angeles (United States)

    2003-07-15T23:59:59.000Z

    Beryllium, in its pebble form, has been proposed in various blanket concepts to serve different purposes. Thermal property data for such a heterogeneous packed bed is needed, particularly data on the impact of compression forces on its magnitude and consequent temperature profile. The objectives of this work are to obtain and quantify experimental data on the effective thermal conductivity of a Be-He packed bed, on the interface heat conductance between Be and SiC, and on the effects of externally applied pressure on these effective thermal properties. The effective thermal conductivity of a Be-He pebble bed increases as the bed mean temperature increases. The values of effective thermal conductivity vary from 2.15 to 3.00 W/m.K for bed mean temperature ranges from 90 to 420 deg C. Similar temperature effects are seen in the Be/SiC interface heat conductance, as the values of interface heat conductance range from 1140 to 2200 W/m{sup 2}.K. In addition, effective thermal conductivity increases remarkably with the increase of applied pressure (by a factor of 2.53 at 2 MPa), while it remains higher than the initial value by {approx}0.3 W/m.K when external pressure is released (hysteresis effect)

  11. VALIDATION OF ANALYTICAL METHODS AND INSTRUMENTATION FOR BERYLLIUM MEASUREMENT: REVIEW AND SUMMARY OF AVAILABLE GUIDES, PROCEDURES, AND PROTOCOLS

    SciTech Connect (OSTI)

    Ekechukwu, A

    2009-05-27T23:59:59.000Z

    Method validation is the process of evaluating whether an analytical method is acceptable for its intended purpose. For pharmaceutical methods, guidelines from the United States Pharmacopeia (USP), International Conference on Harmonisation (ICH), and the United States Food and Drug Administration (USFDA) provide a framework for performing such valications. In general, methods for regulatory compliance must include studies on specificity, linearity, accuracy, precision, range, detection limit, quantitation limit, and robustness. Elements of these guidelines are readily adapted to the issue of validation for beryllium sampling and analysis. This document provides a listing of available sources which can be used to validate analytical methods and/or instrumentation for beryllium determination. A literature review was conducted of available standard methods and publications used for method validation and/or quality control. A comprehensive listing of the articles, papers and books reviewed is given in the Appendix. Available validation documents and guides are listed therein; each has a brief description of application and use. In the referenced sources, there are varying approches to validation and varying descriptions of the valication process at different stages in method development. This discussion focuses on valication and verification of fully developed methods and instrumentation that have been offered up for use or approval by other laboratories or official consensus bodies such as ASTM International, the International Standards Organization (ISO) and the Association of Official Analytical Chemists (AOAC). This review was conducted as part of a collaborative effort to investigate and improve the state of validation for measuring beryllium in the workplace and the environment. Documents and publications from the United States and Europe are included. Unless otherwise specified, all referenced documents were published in English.

  12. Dynamic response of materials on subnanosecond time scales, and beryllium properties for inertial confinement fusion

    SciTech Connect (OSTI)

    Swift, Damian C.; Tierney, Thomas E.; Luo Shengnian; Paisley, Dennis L.; Kyrala, George A.; Hauer, Allan; Greenfield, Scott R.; Koskelo, Aaron C.; McClellan, Kenneth J.; Lorenzana, Hector E.; Kalantar, Daniel; Remington, Bruce A.; Peralta, Pedro; Loomis, Eric [Los Alamos National Laboratory, MS E526, Los Alamos, New Mexico 87545 (United States); Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550 (United States); Arizona State University, Tempe, Arizona 85287 (United States)

    2005-05-15T23:59:59.000Z

    During the past few years, substantial progress has been made in developing experimental techniques capable of investigating the response of materials to dynamic loading on nanosecond time scales and shorter, with multiple diagnostics probing different aspects of the behavior. These relatively short time scales are scientifically interesting because plastic flow and phase changes in common materials with simple crystal structures--such as iron--may be suppressed, allowing unusual states to be induced and the dynamics of plasticity and polymorphism to be explored. Loading by laser-induced ablation can be particularly convenient: this technique has been used to impart shocks and isentropic compression waves from {approx}1 to 200 GPa in a range of elements and alloys, with diagnostics including line imaging surface velocimetry, surface displacement (framed area imaging), x-ray diffraction (single crystal and polycrystal), ellipsometry, and Raman spectroscopy. A major motivation has been the study of the properties of beryllium under conditions relevant to the fuel capsule in inertial confinement fusion: magnetically driven shock and isentropic compression shots at Z were used to investigate the equation of state and shock melting characteristics, complemented by laser ablation experiments to investigate plasticity and heterogeneous response from the polycrystalline microstructure. These results will help to constrain acceptable tolerances on manufacturing, and possible loading paths, for inertial fusion ignition experiments at the National Ignition Facility. Laser-based techniques are being developed further for future material dynamics experiments, where it should be possible to obtain high quality data on strength and phase changes up to at least 1 TPa.

  13. Predicting the sensitivity of the beryllium/scintillator layer neutron detector using Monte Carlo and experimental response functions

    SciTech Connect (OSTI)

    Styron, J. D., E-mail: jdstyro@sandia.gov; Cooper, G. W.; Carpenter, Ken; Bonura, M. A. [Department of Nuclear Engineering, University of New Mexico, Albuquerque, New Mexico 87131 (United States); Ruiz, C. L.; Hahn, K. D.; Chandler, G. A.; Nelson, A. J.; Torres, J. A.; McWatters, B. R. [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)

    2014-11-15T23:59:59.000Z

    A methodology for obtaining empirical curves relating absolute measured scintillation light output to beta energy deposited is presented. Output signals were measured from thin plastic scintillator using NIST traceable beta and gamma sources and MCNP5 was used to model the energy deposition from each source. Combining the experimental and calculated results gives the desired empirical relationships. To validate, the sensitivity of a beryllium/scintillator-layer neutron activation detector was predicted and then exposed to a known neutron fluence from a Deuterium-Deuterium fusion plasma (DD). The predicted and the measured sensitivity were in statistical agreement.

  14. Atmos. Chem. Phys., 7, 35873596, 2007 www.atmos-chem-phys.net/7/3587/2007/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    on the emis- sion data in Seoul and Northeast Asia: Gasoline and diesel vehicles, residential coal use, coke daily and seasonal variations. High contributions of biomass burning and coal (residential and coke oven ovens, coal power plants, biomass burning, and natural gas (NG) combustion. The ma- jor sources

  15. Fracture toughness of CIP-HIP (cold isostatic pressed - hot isostatic pressed) beryllium at elevated temperatures. Final report, 13 May 1980-13 February 1981

    SciTech Connect (OSTI)

    Barker, L.M.; Jones, A.H.

    1986-04-01T23:59:59.000Z

    The fracture toughness of CIP-HIP (cold isostatic pressed-hot isostatic pressed) beryllium was determined using the short-bar fracture-toughness (K/sub IcSB/) method. The K/sub IcSB/ value measured was 10.96 MPa x the square root of m at room temperature. This falls well within the expected range of 9 to 12 MPa x the square root of m as observed from previous fracture toughness measurements of beryllium. Toughness increased rapidly between 400 F and 500 F reaching a value of 16.7 MPa x the square root of m at 500 F.

  16. VALIDATION OF ANALYTICAL METHODS AND INSTRUMENTATION FOR BERYLLIUM MEASUREMENT: REVIEW AND SUMMARY OF AVAILABLE GUIDES, PROCEDURES, AND PROTOCOLS

    SciTech Connect (OSTI)

    Ekechukwu, A.

    2008-12-17T23:59:59.000Z

    This document proposes to provide a listing of available sources which can be used to validate analytical methods and/or instrumentation for beryllium determination. A literature review was conducted of available standard methods and publications used for method validation and/or quality control. A comprehensive listing of the articles, papers, and books reviewed is given in Appendix 1. Available validation documents and guides are listed in the appendix; each has a brief description of application and use. In the referenced sources, there are varying approaches to validation and varying descriptions of validation at different stages in method development. This discussion focuses on validation and verification of fully developed methods and instrumentation that have been offered up for use or approval by other laboratories or official consensus bodies such as ASTM International, the International Standards Organization (ISO) and the Association of Official Analytical Chemists (AOAC). This review was conducted as part of a collaborative effort to investigate and improve the state of validation for measuring beryllium in the workplace and the environment. Documents and publications from the United States and Europe are included. Unless otherwise specified, all documents were published in English.

  17. Measurement of the melting point temperature of several lithium-sodium-beryllium fluoride salt (FLINABE) mixtures.

    SciTech Connect (OSTI)

    Boyle, Timothy J.; Troncosa, Kenneth P.; Nygren, Richard Einar; Lutz, Thomas Joseph; McDonald, Jimmie M.; Tanaka, Tina Joan; Ulrickson, Michael Andrew

    2004-09-01T23:59:59.000Z

    The molten salt Flibe, a combination of lithium and beryllium flourides, was studied for molten salt fission reactors and has been proposed as a breeder and coolant for the fusion applications. 2LiF-BeF{sub 2} melts at 460 C. LiF-BeF{sub 2} melts at a lower temperature, 363 C, but is rather viscous and has less lithium breeder. In the Advanced Power Extraction (APEX) Program, concepts with a free flowing ternary molten salt for the first wall surface and blanket were investigated. The molten salt (FLiNaBe, a ternary mixture of LiF, BeF2 and NaF) salt was selected because a melting temperature below 350 C that would provide an attractive operating temperature window for a reactor application appeared possible. This information came from a Russian binary phase diagram and a US ternary phase diagram in the 1960's that were not wholly consistent. To confirm that a ternary salt with a low melting temperature existed, several combinations of the fluoride salts, LiF, NaF and, BeF{sub 2}, were melted in a small stainless steel crucible under vacuum. The proportions of the three salts were selected to yield conglomerate salts with as low a melting temperature as possible. The temperature of the salts and the crucible were recorded during the melting and subsequent re-solidification using a thermocouple directly in the salt pool and two thermocouples embedded in the crucible. One mixture had an apparent melting temperature of 305 C. Particular attention was paid to the cooling curve of the salt temperature to observe evidence of any mixed intermediate phases between the fully liquid and fully solid states. The clarity, texture, and thickness were observed and noted as well. The test system, preparation of the mixtures, and the melting procedure are described. The temperature curves for the melting and cooling of each of the mixtures are presented along with the apparent melting points. Thermal modeling of the salt pool and crucible was also done and is reported in a separate paper.

  18. Technical support document: Energy efficiency standards for consumer products: Room air conditioners, water heaters, direct heating equipment, mobile home furnaces, kitchen ranges and ovens, pool heaters, fluorescent lamp ballasts and television sets. Volume 1, Methodology

    SciTech Connect (OSTI)

    Not Available

    1993-11-01T23:59:59.000Z

    The Energy Policy and Conservation Act (P.L. 94-163), as amended, establishes energy conservation standards for 12 of the 13 types of consumer products specifically covered by the Act. The legislation requires the Department of Energy (DOE) to consider new or amended standards for these and other types of products at specified times. DOE is currently considering amending standards for seven types of products: water heaters, direct heating equipment, mobile home furnaces, pool heaters, room air conditioners, kitchen ranges and ovens (including microwave ovens), and fluorescent light ballasts and is considering establishing standards for television sets. This Technical Support Document presents the methodology, data, and results from the analysis of the energy and economic impacts of the proposed standards. This volume presents a general description of the analytic approach, including the structure of the major models.

  19. The Passivity and Breakdown of Beryllium in Aqueous Solutions M.A. Hill, D.P. Butt, and R.S. Lillard

    E-Print Network [OSTI]

    .S. Lillard Materials Corrosion and Environmental Effects Laboratory Materials Science and Technology Division, the presence of the fluoride increased the passive current density of beryllium, but had no effect. It is an attractive engineering material for nuclear applications due to its low neutron cross section

  20. Pushing schedule derivation method

    SciTech Connect (OSTI)

    Henriquez, B. [Compania Siderurgica Huachipato S.A., Talcahuano (Chile)

    1996-12-31T23:59:59.000Z

    The development of a Pushing Schedule Derivation Method has allowed the company to sustain the maximum production rate at CSH`s Coke Oven Battery, in spite of having single set oven machinery with a high failure index as well as a heat top tendency. The stated method provides for scheduled downtime of up to two hours for machinery maintenance purposes, periods of empty ovens for decarbonization and production loss recovery capability, while observing lower limits and uniformity of coking time.

  1. Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report. Report No. 5 for reporting period May 1, 1999 through August 1, 1999

    SciTech Connect (OSTI)

    NONE

    1999-08-15T23:59:59.000Z

    The overall aim of the project is to demonstrate the performance and practical use of a probe for measuring the thickness of coke deposits located within the high-temperature tubes of a thermal cracking furnace. The objective of work during this period was to enhance the sensitivity and signal-to-noise ratio of the probe measurement. Testing identified that the primary source of signal noise was traced to imperfections in the sacrificial stand-off, which was formed using a casting procedure. Laminations, voids, and impurities contained in the casting result in attenuation and dispersion of the ultrasonic signal. This report describes the work performed to optimize the signal conductance of the sacrificial stand-off.

  2. Beyond chemical accuracy: The pseudopotential approximation in diffusion Monte Carlo calculations of the HCP to BCC phase transition in beryllium

    E-Print Network [OSTI]

    Shulenburger, Luke; Desjarlais, M P

    2015-01-01T23:59:59.000Z

    Motivated by the disagreement between recent diffusion Monte Carlo calculations and experiments on the phase transition pressure between the ambient and beta-Sn phases of silicon, we present a study of the HCP to BCC phase transition in beryllium. This lighter element provides an oppor- tunity for directly testing many of the approximations required for calculations on silicon and may suggest a path towards increasing the practical accuracy of diffusion Monte Carlo calculations of solids in general. We demonstrate that the single largest approximation in these calculations is the pseudopotential approximation. After removing this we find excellent agreement with experiment for the ambient HCP phase and results similar to careful calculations using density functional theory for the phase transition pressure.

  3. Analyses of engineering-oriented neutronics integral experiments utilizing beryllium in various configurations with 14 MeV point source

    SciTech Connect (OSTI)

    Youssef, M.; Abdou, M.; Kumar, A. [Univ. of California, Los Angeles, CA (United States)] [and others

    1994-12-31T23:59:59.000Z

    The analysis of integral experiments on tritium breeding rate (TPR), in-system spectrum, and several reaction rates inside a Li{sub 2}O test assembly were performed in a closed geometry with a 14 MeV point source in which beryllium has been extensively utilized as a neutron multiplier. This activity was part of the USDOE/JAERI Collaborative Program on Fusion Blanket Neutronics with the objective of verifying the present neutron transport codes and databases in predicting key design parameters such as TPR. The test assembly itself (with dimension of {approximately}87 cm x {approximately}87 cm x 60 cm) is located at one end of a Li{sub 2}CO{sub 3} enclosure and the neutron point source is located at a distance of {approximately}78 cm from the assembly. The enclosure is surrounded from the outside by polyethylene layer (5 cm-thick) to minimize the neutron wall-room effect.

  4. Prospects for the development of femtosecond laser systems based on beryllium aluminate crystals doped with chromium and titanium ions

    SciTech Connect (OSTI)

    Pestryakov, Efim V [Institute of Laser Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk (Russian Federation); Alimpiev, A I [Design Technological Institute of Monocrystals, Siberian Branch of the Russian Academy of Sciences, Novosibirsk (Russian Federation); Matrosov, V N [Belorussian State Polytechnical Academy, Minsk-107 (Belarus)

    2001-08-31T23:59:59.000Z

    The physical and laser properties of beryllium-containing BeAl{sub 2}O{sub 4}, BeAl{sub 6}O{sub 10}, Be{sub 3}Al{sub 2}Si{sub 6}O{sub 18}, and BeLaAl{sub 11}O{sub 19} oxide crystals doped with chromium and titanium ions are studied. The Cr{sup 3+}:BeAl{sub 2}O{sub 4}, Cr{sup 3+}:BeAl{sub 6}O{sub 10}, and Ti{sup 3+}:BeAl{sub 2}O{sub 4} crystals were shown to compare favourably in physical and laser properties with the well-known laser media and to be candidates for femtosecond laser systems. (lasers and amplifiers)

  5. STARTUP REACTIVITY ACCOUNTABILITY ATTRIBUTED TO ISOTOPIC TRANSMUTATIONS IN THE IRRADIATED BERYLLIUM REFLECTOR OF THE HIGH FLUX ISTOTOPE REACTOR

    SciTech Connect (OSTI)

    Chandler, David [ORNL] [ORNL; Maldonado, G Ivan [ORNL] [ORNL; Primm, Trent [ORNL] [ORNL

    2010-01-01T23:59:59.000Z

    The objective of this study is to develop a methodology to predict the reactivity impact as a function of outage time between cycles of 3He, 6Li, and other poisons in the High Flux Isotope Reactor s (HFIR) beryllium reflector. The reactivity worth at startup of the HFIR has been incorrectly predicted in the past after the reactor has been shut-down for long periods of time. The incorrect prediction was postulated to be due to the erroneous calculation of 3He buildup in the beryllium reflector. It is necessary to develop a better estimate of the start-of-cycle symmetric critical control element positions since if the estimated and actual symmetrical critical control element positions differ by more than $1.55 in reactivity (approximately one-half inch in control element startup position), HFIR is to be shutdown and a technical evaluation is performed to resolve the discrepancy prior to restart. 3He is generated and depleted during operation, but during an outage, the depletion of 3He ceases because it is a stable isotope. 3He is born from the radioactive decay of tritium, and thus the concentration of 3He increases during shutdown. The computer program SCALE, specifically the TRITON and CSAS5 control modules including the KENO V.A, COUPLE, and ORIGEN functional modules were utilized in this study. An equation relating the down time (td) to the change in symmetric control element position was generated and validated against measurements for approximately 40 HFIR operating cycles. The newly-derived correlation was shown to improve accuracy of predictions for long periods of down time.

  6. Calculation of two-centre two-electron integrals over Slater-type orbitals revisited. III. Case study of the beryllium dimer

    E-Print Network [OSTI]

    Micha? Lesiuk; Micha? Przybytek; Monika Musia?; Bogumi? Jeziorski; Robert Moszynski

    2015-01-20T23:59:59.000Z

    In this paper we present results of ab-initio calculations for the beryllium dimer with basis set of Slater-type orbitals (STOs). Nonrelativistic interaction energy of the system is determined using the frozen-core full configuration interaction calculations combined with high-level coupled cluster correction for inner-shell effects. Newly developed STOs basis sets, ranging in quality from double to sextuple zeta, are used in these computations. Principles of their construction are discussed and several atomic benchmarks are presented. Relativistic effects of order ${\\alpha}^2$ are calculated perturbatively by using the Breit-Pauli Hamiltonian and are found to be significant. We also estimate the leading-order QED effects. Influence of the adiabatic correction is found to be negligible. Finally, the interaction energy of the beryllium dimer is determined to be 929.0$\\,\\pm\\,$1.9 $cm^{-1}$, in a very good agreement with the recent experimental value. The results presented here appear to be the most accurate ab-initio calculations for the beryllium dimer available in the literature up to date and probably also one of the most accurate calculations for molecular systems containing more than four electrons.

  7. Characterization of a Sealed Americium-Beryllium (AmBe) Source by Inductively Coupled Plasma Mass Spectrometry

    SciTech Connect (OSTI)

    James Sommers; Marcos Jimenez; Mary Adamic; Jeffrey Giglio; Kevin Carney

    2009-12-01T23:59:59.000Z

    Two Americium-Beryllium neutron sources were dismantled, sampled (sub-sampled) and analyzed via inductively coupled plasma mass spectrometry (ICP-MS). Characteristics such as “age” since purification, actinide content, trace metal content and inter and intra source composition were determined. The “age” since purification of the two sources was determined to be 25.0 and 25.4 years, respectively. The systematic errors in the “age” determination were ± 4 % 2s. The amount and isotopic composition of U and Pu varied substantially between the sub-samples of Source 2 (n=8). This may be due to the physical means of sub-sampling or the way the source was manufactured. Source 1 was much more consistent in terms of content and isotopic composition (n=3 sub-samples). The Be-Am ratio varied greatly between the two sources. Source 1 had an Am-Be ratio of 6.3 ± 52 % (1s). Source 2 had an Am-Be ratio of 9.81 ± 3.5 % (1s). In addition, the trace element content between the samples varied greatly. Significant differences were determined between Source 1 and 2 for Sc, Sr, Y, Zr, Mo, Ba and W.

  8. Experimental Investigations on Pulsed Nd:YAG Laser Welding of C17300 Copper-Beryllium and 49Ni-Fe Soft Magnetic Alloys

    SciTech Connect (OSTI)

    Mousavi, S. A. A. Akbari [School of Metallurgy and Materials Engineering, School of Engineering University of Tehran, Tehran (Iran, Islamic Republic of); School of Metallurgy and Materials Engineering, School of Engineering University of Tehran, Tehran (Iran, Islamic Republic of); Ebrahimzadeh, H. [School of Metallurgy and Materials Engineering, School of Engineering University of Tehran, Tehran (Iran, Islamic Republic of)

    2011-01-17T23:59:59.000Z

    Copper-beryllium and soft magnetic alloys must be joined in electrical and electro-mechanical applications. There is a high difference in melting temperatures of these alloys which cause to make the joining process very difficult. In addition, copper-beryllium alloys are of age hardenable alloys and precipitations can brittle the weld. 49Ni-Fe alloy is very hot crack sensitive. Moreover, these alloys have different heat transfer coefficients and reflection of laser beam in laser welding process. Therefore, the control of welding parameters on the formation of adequate weld puddle composition is very difficult. Laser welding is an advanced technique for joining of dissimilar materials since it can precisely control and adjust the welding parameters. In this study, a 100W Nd:YAG pulsed laser machine was used for joining 49Ni-Fe soft magnetic to C17300 copper-beryllium alloys. Welding of samples was carried out autogenously by changing the pulse duration, diameter of beam, welding speed, voltage and frequency. The spacing between samples was set to almost zero. The ample were butt welded. It was required to apply high voltage in this study due to high reflection coefficient of copper alloys. Metallography, SEM analysis, XRD and microhardness measurement was used for survey of results. The results show that the weld strength depends upon the chemical composition of the joints. To change the wells composition and heat input of the welds, it was attempted to deviate the laser focus away from the weld centerline. The best strength was achieved by deviation of the laser beam away about 0.1mm from the weld centerline. The result shows no intermetallic compounds if the laser beam is deviated away from the joint.

  9. Experimental Measurement of the Interface Heat Conductance Between Nonconforming Beryllium and Type 316 Stainless Steel Surfaces Subjected to Nonuniform Thermal Deformations

    SciTech Connect (OSTI)

    Abelson, Robert Dean; Abdou, Mohamed A. [University of California, Los Angeles (United States)

    2001-03-15T23:59:59.000Z

    In fusion blanket designs that employ beryllium as a neutron multiplier, the interface conductance h plays a key role in evaluating the blanket's thermal profile. Therefore, an extensive experimental program was conducted to measure the magnitude of h between nonconforming beryllium and Type 316 stainless steel surfaces subjected to nonuniform thermal deformations. The magnitude of h was measured as a function of relevant environmental, surface, and geometric parameters, including surface roughness, contact pressure, gas pressure, gas type, and magnitude and direction of heat flow. The results indicate the following: (a) Decreasing the interfacial surface roughness from 6.28 to 0.28 {mu}m, in 760 Torr of helium, increased the magnitude of h by up to 100%; however, increasing the surface roughness reduced the dependence of h on the magnitude of the contact pressure. (b) The interface conductance was significantly higher for measurements made in helium gas as opposed to air. Additionally, the sensitivity of h to the gas pressure was significantly greater for runs conducted in helium and/or with smoother surfaces. This sensitivity was reduced in air and/or with roughened surfaces, and it was essentially nonexistent for the 6.25-{mu}m specimen for air pressures exceeding 76 Torr. (c) For runs conducted in vacuum, the interface conductance was more sensitive to heat flux than when runs were conducted in 760 Torr of helium. (d) The interface conductance was found to be dependent on the direction of heat flux. When the specimens were arranged so that heat flowed from the steel to the beryllium disk, the magnitude of h was generally greater than in the opposite direction.

  10. Adsorption of Hydrogen Sulfide onto Activated Carbon Fibers: Effect of

    E-Print Network [OSTI]

    Borguet, Eric

    . These processes include natural gas processing, petroleum refining, petrochemical plants, Kraft mills, coke ovens, and coal gasifiers. H2S concentrations in these processes vary from 0 to 60 vol % (6). The Claus process

  11. HOW TO LIVE (almost) FOREVER Justyna Derkach, UG Lab/Research

    E-Print Network [OSTI]

    Thompson, Michael

    before you work with these. acrylonitrile arsenic asbestos benzene coke oven emissions ethylene from ABB Scientific Stores or Justyna ­ JHE-A106) #12;NASTIES (designated substances) More paperwork

  12. 1 novembre 8, 2011 Title: The Employment Potential of Site Remediation Policies: a Micro-

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , the first gathering gasworks and coke ovens and the other dealing with petrol filling stations. As regards are only beginning to design a policy. It is very likely that this will become a major policy issue

  13. EAST CAROLINA UNIVERSITY HAZARDOUS CHEMICAL USE GRANT REVIEW FORM ECU policy requires that all grant proposals involving the use of hazardous chemicals be reviewed by an institutional review committee or

    E-Print Network [OSTI]

    -benezene 4-Aminodiphenyl Asbestos Coal tar pitch volatiles Methyl chloromethyl ether Formaldehyde Vinyl chloride Coke oven emissions 1,2-dibromo-3-chloropropane Lead Cadmium Benzene Cotton dust Chromium VI

  14. A new approach and computational algorithm for sensitivity/uncertainty analysis for SED and SAD with applications to beryllium integral experiments

    SciTech Connect (OSTI)

    Song, P.M.; Youssef, M.Z.; Abdou, M.A. (Univ. of California, Los Angeles (United States))

    1993-04-01T23:59:59.000Z

    A new approach for treating the sensitivity and uncertainty in the secondary energy distribution (SED) and the secondary angular distribution (SAD) has been developed, and the existing two-dimensional sensitivity/uncertainty analysis code, FORSS, was expanded to incorporate the new approach. The calculational algorithm was applied to the [sup 9]Be(n,2n) cross section to study the effect of the current uncertainties in the SED and SAD of neutrons emitted from this reaction on the prediction accuracy of the tritium production rate from [sup 6]Li(T[sub 6]) and [sup 7]Li(T[sub 7]) in an engineering-oriented fusion integral experiment of the US Department of Energy/Japan Atomic Energy Research Institute Collaborative Program on Fusion Neutronics in which beryllium was used as a neutron multiplier. In addition, the analysis was extended to include the uncertainties in the integrated smooth cross sections of beryllium and other materials that constituted the test assembly used in the experiment. This comprehensive two-dimensional cross-section sensitivity/uncertainty analysis aimed at identifying the sources of discrepancies between calculated and measured values for T[sub 6] and T[sub 7].

  15. Coking Coal Import Costs - EIA

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOil andMCKEESPORTfor the

  16. HANFORD SITE BERYLLIUM QUESTIONNAIRE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky LearningGetGraphene'sEMSLonly)EnergyP.Oc tBD-8800-804(10/12)

  17. Beryllium FAQs - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I. Ben-Zvi,BenefitsBerkeleyGWDiagnosticFAQs About

  18. Beryllium Program - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformationCenterResearch HighlightsToolsBESEnergy Department to Provide $75 Million

  19. Energy conservation and efficiency in Giprokoks designs at Ukrainian ferrous-metallurgical enterprises

    SciTech Connect (OSTI)

    M.I. Fal'kov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Energy conditions at Ukrainian ferrous-metallurgical enterprises are analyzed. Measures to boost energy conservation and energy efficiency are proposed: specifically, the introduction of systems for dry slaking of coke; and steam-gas turbines that employ coke-oven gas or a mixture of gases produced at metallurgical enterprises. Such turbines may be built from Ukrainian components.

  20. Characteristics of the WWR-K test core and the LEU LTAS to be placed in the central experimental beryllium device.

    SciTech Connect (OSTI)

    Arinkin, F.; Chakrov, P.; Chekushina, L.; Gizatulin,, Sh.; Koltochnik, S.; Hanan, N.; Garner, P.; Nuclear Engineering Division; Kazakhstan Ministry of Energy and Mineral Resources

    2010-03-01T23:59:59.000Z

    In 2010 life test of three LEU (19.7%) lead test assemblies (LTA) is expected in the existing WWR-K reactor core with regular WWR-C-type fuel assemblies and a smaller core with a beryllium insert. Preliminary analysis of test safety is to be carried out. It implies reconstruction of the reactor core history for last three years, including burnup calculation for each regular fuel assembly (FA), as well as calculation of characteristics of the test core. For the planned configuration of the test core a number of characteristics have been calculated. The obtained data will be used as input for calculations on LTA test core steady-state thermal hydraulics and on transient analysis.

  1. Modification of environmental control of cokemaking plant

    SciTech Connect (OSTI)

    Katoh, H.; Yasuno, M.; Gotch, T.; Yoshida, F.

    1993-01-01T23:59:59.000Z

    Recently, global environmental protection has been a great concern in the world. In the United States of America, the Clean Air Act (CAA) has been revised to control emissions strictly. Especially in the field of cokemaking, the restriction of fume emission from a coke oven is so severe that old coke ovens will stop operation with the application of CAA. In Japan, it is expected that more severe protection measures are going to be requested for keeping environmental quality. In this situation, it is indispensable to strengthen environmental protection measures for cokemaking plants to continue coke production in the 21st century. In Chiba Works, Kawasaki Steep Corp., the Ironmaking Department has been struggling for the improvement of environmental measures for. These activities for coke ovens are described in this report. The paper describes fume emission control from the coke oven door and dust emission control measures, including the dust monitoring system, prevention of secondary dust scattering from coke ovens, replacement of dedusters, and fume and dust control of stack emission.

  2. CRITICAL CONFIGURATION FOR BERYLLIUM REFLECTED ASSEMBLIES OF U(93.15)O2 FUEL RODS (1.506-CM PITCH AND 7-TUBE CLUSTERS)

    SciTech Connect (OSTI)

    Margaret A. Marshall

    2012-05-01T23:59:59.000Z

    A series of critical experiments were completed in 1962-1965 at Oak Ridge National Laboratory’s Critical Experiments Facility in support of the Medium-Power Reactor Experiments (MPRE) program. In the late 1950’s efforts were made to study “power plants for the production of electrical power in space vehicles”. The MPRE program was a part of those efforts and studied the feasibility of a stainless steel system, boiling potassium 1 MW(t), or about 140 kW(e), reactor. The program was carried out in [fiscal years] 1964, 1965, and 1966. A summary of the program’s effort was compiled in 1967. The delayed critical experiments were a mockup of a small, potassium-cooled space power reactor for validation of reactor calculations and reactor physics methods. Initial experiments, performed in November and December of 1962, consisted of a core of 253 unmoderated stainless steel tubes, each containing 26 UO2 fuel pellets, surrounded by a graphite reflector. Measurements were made to determine critical reflector arrangements, fission-rate distributions, and cadmium ratio distributions. “The [assemblies were built] on [a] vertical assembly machine so that the movable part was the core and bottom reflector.” The first two experiments in the series were evaluated in HEU-COMP-FAST-001 (SCCA-FUND-EXP-001) and HEU-COMP-FAST-002 (SCCA-FUND-EXP-002). The first experiment had the 253 fuel tubes packed tightly into a 22.87 cm outside diameter (OD) core tank (References 1 and 2). The second experiment in the series, performed in early 1963, had the 253 fuel tubes at a 1.506-cm triangular lattice in a 25.96 cm OD core tank and graphite reflectors on all sides. The third set of experiments in the series, performed in mid-1963, which is studied in this evaluation, used beryllium reflectors. The beryllium reflected system was the preferred reactor configuration for this application because of the small thickness of the reflector. The two core configurations had the 253 fuel tubes at a 1.506-cm triangular lattice and arranged in 7-tube clusters. The experiments have been determined to represent acceptable benchmark experiments. Information for this evaluation was compiled from published reports on all three parts of the experimental series (Reference 1-5) and the experimental logbook as well as from communication with the experimenter, John T. Mihalczo.

  3. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    1999-09-22T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (4) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (5) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: Detailed workings of the team; Proposal to FETC for Phase II; Permitting and Environmental Work; and Engineering Progress.

  4. Calderon cokemaking process/demonstration project

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    The Clean Air Act Amendments of 1990 set new emission standards for hazardous air pollutants from coke ovens. Congress, recognizing that the coke industry faces technological and financial difficulties in meeting these new, stringent emission standards, required the U.S. Environmental Protection Agency and DOE to conduct a joint six-year research and development program to assist the industry in developing and commercializing new technologies and work practices that would significantly reduce hazardous coke oven emissions. DOE`s purpose for sponsoring the proposed demonstration project is to provide the coke industry with a new option for the economical production of high quality coke that significantly reduces the quantity of pollutants entering the environment.

  5. Supercomputers Take a Cue From Microwave Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    many different licenses for different applications," says Shalf. "Just as the consumer electronics chip designers choose a set of processor characteristics appropriate to the...

  6. Solar Pizza Oven Box k - 6

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: AlternativeEnvironment,Institutes and ResponseStaffServicesFutureU.S.Solar Cell | Department

  7. Making a Solar Oven | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of Energy Low-TemperatureEnergy Maine State

  8. Supercomputers Take a Cue From Microwave Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystalline Gallium OxideSumin Kim Sumin KimSunilSupercomputers Take a Cue

  9. Battery operation experience at SSAB, Luleaa six years after rehabilitation

    SciTech Connect (OSTI)

    Petrini, H.; Sundgren, M. [SSAB Tunnplaat, Luleaa (Sweden); Meyer, G. [Krupp Koppers GmbH, Essen (Germany)

    1995-12-01T23:59:59.000Z

    SSAB operates a coke oven plant in Luleaa, Sweden, consisting of one 7 m battery. Pushing the first coke in 1975, the battery encountered over the years more and more difficulties in keeping coking time and operation level at the design rate. In order to improve the coke supply a major repair of the battery was made. In 1989 the battery was fully rehabilitated by Krupp Koppers. The experience made during the years before and during repair contributed to a new policy for the operation of the plant. The policy has led to considerable improvements. It is clear that it is possible to successfully operate a rehabilitated battery.

  10. Shock wave compression of hexagonal-close-packed metal single crystals: Time-dependent, anisotropic elastic-plastic response of beryllium

    SciTech Connect (OSTI)

    Winey, J. M.; Gupta, Y. M. [Institute for Shock Physics and Department of Physics, Washington State University, Pullman, Washington 99164 (United States)

    2014-07-21T23:59:59.000Z

    Understanding and modeling the response of hcp metals to high stress impulsive loading is challenging because the lower crystal symmetry, compared to cubic metals, results in a significantly more complex material response. To gain insight into the inelastic deformation of hcp metals subjected to high dynamic stresses, shock wave compression of single crystals provides a useful approach because different inelastic deformation mechanisms can be examined selectively by shock compression along different crystal orientations. As a representative example, we report, here, on wave propagation simulations for beryllium (Be) single crystals shocked along the c-axis, a-axis, and several low-symmetry directions to peak stresses reaching 7?GPa. The simulations utilized a time-dependent, anisotropic material model that incorporated dislocation dynamics, deformation twinning, and shear cracking based descriptions of inelastic deformation. The simulation results showed good overall agreement with measured wave profiles for all the different crystal orientations examined [Pope and Johnson, J. Appl. Phys. 46, 720 (1975)], including features arising from wave mode coupling due to the highly anisotropic inelastic response of Be. This good agreement demonstrates that the measured profiles can be understood in terms of dislocation slip along basal, prismatic, and pyramidal planes, together with deformation twinning along (101{sup Ż}2) planes. Our results show that the response of shocked Be single crystals involves the simultaneous operation of multiple, distinct inelastic deformation mechanisms for all orientations except the c-axis. For shocked c-axis Be, the measured wave profiles do not provide good discrimination between pyramidal slip and other inelastic deformation mechanisms, such as shear cracking. The findings presented here provide insight into the complex inelastic deformation response of shocked Be single crystals and are expected to be useful for other hcp crystals. More broadly, the present work demonstrates the potential of shock wave propagation along low-symmetry directions to examine, and discriminate between, different inelastic deformation mechanisms in crystalline solids.

  11. Evaluation of Cadmium Ratio and Foil Activation Measurements For Beryllium Reflected Assemblies of U(93.15)O2 Fuel Rods (1.506-cm pitch and 7-tube clusters)

    SciTech Connect (OSTI)

    Margaret A. Marshall

    2014-12-01T23:59:59.000Z

    A series of small, compact critical assembly (SCCA) experiments were completed from 1962 to 1965 at Oak Ridge National Laboratory’s Critical Experiments Facility (ORCEF) in support of the Medium-Power Reactor Experiments (MPRE) program. Initial experiments, performed in November and December of 1962, consisted of a core of un-moderated stainless-steel tubes, each containing 26 UO2 fuel pellets, surrounded by a graphite reflector. Measurements were performed to determine critical reflector arrangements, fission-rate distributions, and cadmium ratio distributions. The graphite reflectors were then changed to beryllium reflectors. For the beryllium reflected assemblies, the fuel was in 1.506-cm-triangular and 7-tube clusters leading to two critical configurations. Once the critical configurations had been achieved, various measurements of reactivity, relative axial and radial activation rates of 235U, and cadmium ratios were performed. The cadmium ratio, reactivity, and activation rate measurements, performed on the 1.506-cm-array critical configuration, have been evaluated and are described in this paper.

  12. What is a Beryllium Measurement? A Critical Look at Beryllium

    SciTech Connect (OSTI)

    Charles Davis; Dan Field; John Hess; Dan Jensen

    2006-03-01T23:59:59.000Z

    DOE workplaces strive to comply with the 10 CFR 850.31(b)(1) surface concentration release criterion. The usual planning considerations for demonstrating compliance are these: how many swipes, and where; which sample preparation and analytical methods; what reporting limits; and what sample statistic to compare with the criterion. We have reviewed swipe samples from hundreds of Nevada Test Site workplaces: office buildings; experimental facilities; forward area field units; shops; and tunnels. Our experiences have led us to a critical examination of the inner workings of the measurement process itself, involving details generally taken for granted when those usual questions are asked. In this presentation we dissect the ICP-AES Be measurement process. We discuss calibration options and how they impact the distributions of analytical results. We look at distributions of blank results obtained from different labs, and discuss their relevance to determining reporting limits. We examine the way measurements are made from spectra, how that process impacts our understanding of the actual statistical distributions of Be measurements, and how interferences can affect Be measurements. Our objective is to gain sufficient confidence in the measurement process so that the usual questions will make sense and the survey results will be credible. Based on our observations, we offer these recommendations: prepare calibration samples in digested blank swipes; force the calibration line through (0,0); base reporting limits on field blank measurement distributions rather than 40 CFR 236 calculations; use, but do not believe, the usual lognormal distribution assumption; and avoid the 234.861 nm emission line.

  13. An investigation of three problems concerning the analysis of airborne asphalt fumes

    E-Print Network [OSTI]

    Laird, Larry Teal

    1981-01-01T23:59:59.000Z

    and well documented carcinogens; however, the BaP content of asphalt fumes is only about 0. 03 percent of the BaP content of coal fed coke oven emissions. 4 This strongly illustrates the need to avoid confusion between asphalts and tars or pitches from... in the composition of asphalt and tar or pitch . The principal significant difference lies in the fact that there are much smaller amounts of PNA's in asphalt fumes than are found in tar or pitch fumes. Coke ovens and coal gasification plants also produce a fume...

  14. Beryllium - HPMC Occupational Health Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I. Ben-Zvi,BenefitsBerkeleyGWDiagnostic

  15. Beryllium Health Advocates - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I. Ben-Zvi,BenefitsBerkeleyGWDiagnosticFAQsHealth

  16. Beryllium Program Feedback - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I.

  17. Beryllium Related Links - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I.Program Information About Us

  18. Beryllium Information | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAboutScienceCareers Apply for a JobBernard Matthew Poelker, 2011 The

  19. MATERIALS ENGINEERING KEYWORDS: beryllium, stainless

    E-Print Network [OSTI]

    Abdou, Mohamed

    SURFACES SUBJECTED TO NONUNIFORM THERMAL DEFORMATIONS ROBERT DEAN ABELSON and MOHAMED A. ABDOU* University.*E-mail: abdou@fusion.ucla.edu FUSION TECHNOLOGY VOL. 39 MAR. 2001 157 #12;To understand the interface

  20. Supplementary Information for Refined Estimate of China's CO2 Emissions in

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    .95-0.98); Weibull Other washed coal 0.96 (0.92-1); Triangular Briquettes 0.90 (0.89-0.98); Weibull IPCC( 2006); Coke coal 0.93 (0.89-0.98); Gamma IPCC( 2006); Cai et al. (2009); Zhao et al (2012) Cleaned coal 0.96 (0 0.93 (0.89-1); Triangular Coke Oven Gas 0.99 (0.98-1); Triangular Other Gas 0.99 (0

  1. Supplement of Atmos. Chem. Phys., 14, 56175638, 2014 http://www.atmos-chem-phys.net/acp-14-5617-2014/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    .2 Industry Combustion Coal/Boiler, Kilns Liu et al. (2008), 1185 1185 1701.2 Coke Oven Blast Furnace Gas in the original INTEX-B NMVOC Emissions /Gg Power Coal 1178 1178 1130.7 Biofuel Tsai et al. (2003), Liu et al, 4421, 5561 (Andreae and Merlet, 2001) Tsai et al.(2003) 16.8 Industry Non-combustion Coke 11, 217 11

  2. Petroleum Coke: A Viable Fuel for Cogeneration

    E-Print Network [OSTI]

    Dymond, R. E.

    ; buy sulfur dioxide credits on the open market; install FGD; or switch to clean coal technology such as circulating fluidized bed combustion and gasification. Current trends in utility modernization are to utilize new clean coal technologies...

  3. Coking Coal Prices for Industry - EIA

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOil andMCKEESPORTfor thePrices for Industry

  4. Table 16. U.S. Coke Exports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328AdministrationReleaseMetallurgical Coal Exports by

  5. Table 21. U.S. Coke Imports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328AdministrationReleaseMetallurgical Coal ExportsPrice

  6. Operational experience using the novel FixCup collecting main valve

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany). Inst. for Cokemaking and Fuel Technology; Spitz, J. [Thyssen Stahl AG, Duisburg (Germany)

    1996-12-31T23:59:59.000Z

    On the occasion of the 1995 AIME conference the new PROven (Pressure Regulated Oven) process to control the pressure in coke ovens individually was introduced. This process was made feasible with a new collecting main valve, termed FixCup, with the aid of this valve a variable flow resistance to the raw gas discharge can be realized using a water immersion system. However, just the application of the FixCup system alone--without any pressure regulation--is very advantageous and cost saving. Thyssen has equipped 30 ovens with the new valve. The special constructive features as well as the operational experience using the FixCup valve are treated.

  7. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    ALBERT CALDERON

    1998-09-22T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (i) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; and (iv) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: ? Consolidation of the project team-players; ? Recruiting Koppers Industries as an additional stakeholder; ? Developing a closed system for the production of binder pitch from tar in the Calderon coking process as the incentive for Koppers to join the team; ? Gathering appropriate equipment for conducting a set of experiments at bench scale to simulate tar quality produced from the Calderon coking process for the production of binder pitch; and ? Further progress made in the design of the commercial coking reactor.

  8. Master Thesis: Collaboration between Utility Systems and Production

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    ) Electricity Natural GasElectricity Generation (Power Plant) 1. Abbreviations: CO (coke oven), SP (sinter plant and LF) Casting (CC) Storage (SY) Reheating (RF) Rolling (HSM) Meltshop Hot Rolling Mill Coal Iron Ore) Meltshop Hot Rolling Mill Coal Iron Ore Slabs CO and BF Gas BOF Gas Given: Hot rolling mill produces set

  9. 1 GENERAL DESCRIPTION OF BAOTOU EARTHQUAKE DAMAGES

    E-Print Network [OSTI]

    Spencer Jr., B.F.

    frame gallery (west) of No. 5 coke oven system of BISC. It acted in the violation of the national of the ore dressing system. The original design did not consider earthquake resistance, so the stressed standard "Aseismic Design Code of Structures", as a result, shear failures and dislocation occurred

  10. ME 6222: Manufacturing Processes and Systems Prof. J.S. Colton GIT 2011

    E-Print Network [OSTI]

    Colton, Jonathan S.

    solubility and porosity · Defects · Design rules · Economics #12;ME 6222: Manufacturing Processes and Systems with charge · steel making in blast furnace -mix coke with steel · Furnace material - refractory ­ high;Melting Time · Estimate by · Take into account oven efficiency ME 6222: Manufacturing Processes

  11. SOLAR SEMINAR SERIESS P R I N G 2 0 1 3 P H O T O V O L T A I C S E M I N A R S E R I E S SURESH V. GARIMELLA

    E-Print Network [OSTI]

    Ginzel, Matthew

    . 0928 088 Consumption by thermal power plants & auxiliaries Consumption by other energy producers Conversion in thermal power plants F30 Fossil fuel use: Other transformation sector (refineries, coke ovens how the usage types of the two datasets were merged. - Figure S1, referring to the model simulations

  12. Energy Flow Models for the Steel Industry

    E-Print Network [OSTI]

    Hyman, B.; Andersen, J. P.

    each step is calibrated against Commerce Dept. data. Third, a detailed energy flow model is presented for coke ovens and blast furnaces, two very energy-intensive steps in our seven step model of steelmaking. This process-step model is calibrated...

  13. L{sub g}?=?100?nm In{sub 0.7}Ga{sub 0.3}As quantum well metal-oxide semiconductor field-effect transistors with atomic layer deposited beryllium oxide as interfacial layer

    SciTech Connect (OSTI)

    Koh, D., E-mail: dh.koh@utexas.edu, E-mail: Taewoo.Kim@sematech.org [Department of Electrical and Computer Engineering, Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States); SEMATECH, Inc., Albany, New York 12203 (United States); Kwon, H. M. [Department of Electronics Engineering, Chungnam National University, Daejeon 305-764 (Korea, Republic of); Kim, T.-W., E-mail: dh.koh@utexas.edu, E-mail: Taewoo.Kim@sematech.org; Veksler, D.; Gilmer, D.; Kirsch, P. D. [SEMATECH, Inc., Albany, New York 12203 (United States); Kim, D.-H. [SEMATECH, Inc., Albany, New York 12203 (United States); GLOBALFOUNDRIES, Malta, New York 12020 (United States); Hudnall, Todd W. [Department of Chemistry and Biochemistry, Texas State University, San Marcos, Texas, 78666 (United States); Bielawski, Christopher W. [Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas 78712 (United States); Maszara, W. [GLOBALFOUNDRIES, Santa Clara, California 95054 (United States); Banerjee, S. K. [Department of Electrical and Computer Engineering, Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)

    2014-04-21T23:59:59.000Z

    In this study, we have fabricated nanometer-scale channel length quantum-well (QW) metal-oxide-semiconductor field effect transistors (MOSFETs) incorporating beryllium oxide (BeO) as an interfacial layer. BeO has high thermal stability, excellent electrical insulating characteristics, and a large band-gap, which make it an attractive candidate for use as a gate dielectric in making MOSFETs. BeO can also act as a good diffusion barrier to oxygen owing to its small atomic bonding length. In this work, we have fabricated In{sub 0.53}Ga{sub 0.47}As MOS capacitors with BeO and Al{sub 2}O{sub 3} and compared their electrical characteristics. As interface passivation layer, BeO/HfO{sub 2} bilayer gate stack presented effective oxide thickness less 1 nm. Furthermore, we have demonstrated In{sub 0.7}Ga{sub 0.3}As QW MOSFETs with a BeO/HfO{sub 2} dielectric, showing a sub-threshold slope of 100?mV/dec, and a transconductance (g{sub m,max}) of 1.1 mS/?m, while displaying low values of gate leakage current. These results highlight the potential of atomic layer deposited BeO for use as a gate dielectric or interface passivation layer for III–V MOSFETs at the 7?nm technology node and/or beyond.

  14. Energy Efficiency Standards for Microwave Ovens Saves Consumers...

    Broader source: Energy.gov (indexed) [DOE]

    Positive Impact Significant savings to consumer energy bills and reductions in carbon pollution. Locations Nationwide Partners Lawrence Berkeley National Laboratory, Navigant EERE...

  15. New Energy Efficiency Standards for Microwave Ovens to Save Consumers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    through 2030. Over the next 30 years, it will dramatically reduce harmful carbon pollution, equivalent to taking over 12 million new cars off the road for one year. "Appliance...

  16. Oven rack having integral lubricious, dry porcelain surface

    SciTech Connect (OSTI)

    Ambrose, Jeffrey A; Mackiewicz-Ludtka, Gail; Sikka, Vinod K; Qu, Jun

    2014-06-03T23:59:59.000Z

    A lubricious glass-coated metal cooking article capable of withstanding repeated heating and cooling between room temperature and at least 500.degree. F. without chipping or cracking the glass coating, wherein the glass coating includes about 0.1 to about 20% by weight of a homogeneously distributed dry refractory lubricant material having a particle size less than about 200 .mu.m. The lubricant material is selected from the group consisting of carbon; graphite; boron nitride; cubic boron nitride; molybdenum (FV) sulfide; molybdenum sulfide; molybdenum (IV) selenide; molybdenum selenide, tungsten (IV) sulfide; tungsten disulfide; tungsten sulfide; silicon nitride (Si.sub.3N.sub.4); TiN; TiC; TiCN; TiO.sub.2; TiAlN; CrN; SiC; diamond-like carbon; tungsten carbide (WC); zirconium oxide (ZrO.sub.2); zirconium oxide and 0.1 to 40 weight % aluminum oxide; alumina-zirconia; antimony; antimony oxide; antimony trioxide; and mixtures thereof.

  17. Solar Oven, Take One: FAIL | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    (e.g. newspaper) Black construction paper (black non-toxic paint can also be used) Plastic wrap Aluminum foil Tape Our delicious test product. More detailed instructions can be...

  18. Surveys of Microwave Ovens in U.S. Homes

    E-Print Network [OSTI]

    Williams, Alison

    2014-01-01T23:59:59.000Z

    AHAM ..Home Appliance Manufacturers (AHAM), and Appliance Magazine.and (3) refrigerator. 1.1.3 AHAM AHAM collected information

  19. Build a Pizza Box Solar Oven | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top Five EEREDepartmentFebruary 4,Brent Nelson About UsDepartment ofBudgetBuild

  20. Covered Product Category: Commercial Ovens | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top FiveDepartmentfor EngineeringDepartment ofBoilers Covered

  1. Energy Efficiency Standards for Microwave Ovens Saves Consumers Energy and

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomentheATLANTA, GA5 & 6,Department of EnergyAn agreementUpdates the Social

  2. Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up from theDepartment of Dept. ofUSA RSDepartment of EnergyEfficiency | Department of

  3. Calderon Cokemaking Process/Demonstration Project

    SciTech Connect (OSTI)

    None

    1998-04-08T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon with the following objectives in order to enable its commercialization: (i) making coke of such quality as to be suitable for use in high driving (highly productive) blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; and (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process. The activities of the past quarter were entirely focused on operating the Calderon Process Development Unit (PDU-I) in Alliance, Ohio conducting a series of tests under steady state using coal from Bethlehem Steel and U.S. Steel in order to demonstrate the above. The objectives mentioned above were successfully demonstrated.

  4. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    ALBERT CALDERON

    1998-06-22T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitating commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; and (4) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on three main activities: Continuation of design of the coking reactor; Raising funds from the private sector; and Detailed analysis of the tests conducted in Alliance, Ohio. The design of the reactor work centered on the provision for the capability to inspect and maintain the internals of the reactor. The activities relating to raising funds from the steel industry have been fruitful. Bethlehem Steel has agreed to contribute funds. The collected data from the tests at Alliance were analyzed and a detailed report was completed and presented to the International Iron & Steel Institute by invitation.

  5. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2000-03-22T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (i) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (iv) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (v) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter continued to be focused on the following: Concluding the Negotiation and completing Contracts among Stakeholders of the Team; Revision of Final Report for Phase I; Engineering Design Progress; Selection of Systems Associates, Inc. for design of Control System; Conclusion of Secrecy Agreement with Carborundum (St. Gobain); and Permitting Work and Revisions.

  6. Calderon cokemaking process/demonstration project

    SciTech Connect (OSTI)

    Albert Calderon

    1999-12-21T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such a process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (4) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (5) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter continued to be focused on the following: Drafting of Contracts among the Stakeholders of the Team, Completion and Delivery of Proposal for Phase 2 Permitting and Environmental Work Engineering Progress Preparation of Final Report for Phase 1 DCAA Audit Funding for Phase 2.

  7. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2000-06-21T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (i) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (iv) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (v) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter continued to be focused on the following: Concluding the Negotiation and completing Contracts among Stakeholders of the Team; Revision of Final Report for Phase I; Engineering Design Progress; Selection of Systems Associates, Inc. for design of Control System; Conclusion of Secrecy Agreement with Carborundum (St. Gobain); and Permitting Work and Revisions.

  8. Chronic Beryllium Disease Prevention Program What's New

    Broader source: Energy.gov [DOE]

    For additional information Contact: David Weitzman, Office of Worker Safety and Health Policy at (301) 903-5401 or: David.Weitzman@hq.doe.gov.

  9. Guidance for Informed Choice on Beryllium Testing

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAX POLICIES7.pdfFuel Cell VehicleEnergyGreensburgUMTRCA Title I and Titleand

  10. Hanford Beryllium Awareness Group (BAG) - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr FlickrGuided Self-Assembly ofSeptember 4-5, 2014February 7-8,About

  11. ORISE: Worker Health Studies - Beryllium Testing Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory |CHEMPACKRadiologicalEric Dulmes Student'sDuringandOakBeLPT

  12. LLNS Beryllium Consent Order Fact Sheet

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe10 DOEWashington, DCKickoffLDV5-CE-14022) LG: Proposed- LLNS

  13. Beryllium Lymphocyte Proliferation Testing (BeLPT)

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists' ResearchTheMarketing,Energy and Natural Resourcespatterson.pdf MoreCombinedBeport

  14. Beryllium Vender Screening Program | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists' ResearchTheMarketing,Energy and Natural Resourcespatterson.pdf MoreCombinedBeportIn

  15. 2013 Beryllium-Associated Worker Registry Summary

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy Cooperation |South Valley Responsible DOEQA:Program PeerDepartment ofDepartmentProtection |

  16. Beryllium Facilities & Areas - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I. Ben-Zvi,BenefitsBerkeleyGWDiagnosticFAQs

  17. Beryllium Associated Worker Registry Summary 2012

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd: ScopeDepartment ofEnergyBeowawe Binary Table of Contents

  18. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    factor of bituminous coal, coking coal, and coke consumed inprice of Bituminous coal, coking coal, and coke consumed in

  19. The operation results with the modified charging equipment and ignition furnace at Kwangyang No. 2 sinter plant

    SciTech Connect (OSTI)

    Lee, K.J.; Pi, Y.J.; Kim, J.R.; Lee, J.N. [POSCO, Kwangyang, Cheonnam (Korea, Republic of)

    1996-12-31T23:59:59.000Z

    There will be another blast furnace, the production capacity of which is 3.0 million tonnes per year in 1999 and mini mill plant, the production capacity of which is 1.8 million tonnes per year in 1996 at Kwangyang Works. Therefore, the coke oven gas and burnt lime will be deficient and more sinter will be needed. To meet with these situations, the authors modified the charging equipment and ignition furnace at Kwangyang No. 2 sinter plant in April 1995. After the modification of the charging equipment and ignition furnace, the consumption of burnt lime and coke oven gas could be decreased and the sinter productivity increased in spite of the reduction of burnt lime consumption. This report describes the operation results with the modification of the charging equipment and ignition furnace in No. 2 sinter plant Kwangyang works.

  20. Characterisation of coking activity during supercritical hydrocarbon Nicolas Gascoina*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    (SCRamjet) beyond [3] [4], because of its high specific impulse and its capability to be reusable [5] [6-France company and its partners with calculations [8] and material tests [9]-[11]. The principle of SCRAMJET

  1. Hydroprocessing Bio-oil and Products Separation for Coke Production

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2013-04-01T23:59:59.000Z

    Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

  2. Table 33. Coal Carbonized at Coke Plants by Census Division

    U.S. Energy Information Administration (EIA) Indexed Site

    2014 Year to Date Census Division April - June 2014 January - March 2014 April - June 2013 2014 2013 Percent Change Middle Atlantic 1,599 1,503 1,622 3,102 3,178 -2.4 East North...

  3. Cogeneration Waste Heat Recovery at a Coke Calcining Facility

    E-Print Network [OSTI]

    Coles, R. L.

    hard surface overlays on their impellers and scrolls to prevent erosion. The use of linings was selected after a comprehensive study was performed investi gating the expected wear on unlined equipment, additional cost of linings, frequency of main... is provided fr the pump discharge head r for of the bypass steam e tering carbon steel steam sal s line line of the refine is feet long. The st am is metered by a primary venturi flow nozzle, essure transmitters, and temperature elements ne r...

  4. Table 38. Coal Stocks at Coke Plants by Census Division

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystallineForeign ObjectOUR Table 1. Summary: ReportedEnergyChanges

  5. Coke County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:EnergyWisconsin: Energy, -105.3774934°Coda BatteryCohoe, Alaska:

  6. Nippon Coke and Engineering Sumitomo Corp JV | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's HeatMexico: EnergyMithunCenterInformationNexxus(CTI PFAN)Corp JV Jump to:

  7. Table 17. Average Price of U.S. Coke Exports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328AdministrationReleaseMetallurgical Coal Exports byAverage

  8. Table 22. Average Price of U.S. Coke Imports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328AdministrationReleaseMetallurgical Coal ExportsPriceAverage

  9. Energy Consumption and Potential for Energy Conservation in the Steel Industry

    E-Print Network [OSTI]

    Hughes, M. L.

    1979-01-01T23:59:59.000Z

    , April 22-25, 1979 IRON ORE REDUCTION STEELMAKING PRIMARY CONVERSION HOT ROLLING FINISHING SIMPLIFIED FLOW SHEET STEEL PRODUCTION PROCESSES Iron Ore & Wastes , Agg lomerating Pellets Ore & Flux Coal ~ " Sinter - Blast ~ Coke Furnaces... - Ovens '( BF Iron Outside ,~., Scrap Open Hearth Furnaces , Ingot Casting Basic Oxygen Furnaces Raw Steel Electric Arc Furnaces Scrap , Primary Rolling Mills Continuous Casting Slabs, Blooms, Billets r Secondary Hot Rolling Bars...

  10. Energy Efficiency Business in China: A Roadmap For American Companies

    E-Print Network [OSTI]

    Hamburger, J.; Sinton, J.

    the Eighteenth Industrial Energy Technology Conference, Houston, TX, April 17-18, 1996 FIGURE 1. Energy Use by Equipment Type in China, 1990 (l) Coal Electricity ~ Industrial Boilers o Pumps II Power Plant Boilers III Fans D Coke Ovens and Smelting Furnaces o... currency (16). As part of the economic reform program, the Chinese goverrunent stopped paying the coal industry its annual subsidy of $230 million. Coal prices began rising sharply in many areas in 1993 and continued to increase after being...

  11. Operation of dry-cleaned and agglomerated precompaction system (DAPS)

    SciTech Connect (OSTI)

    Tanaka, Shigemi; Okanishi, Kazuya; Kikuchi, Akio; Yamamura, Yuichi

    1997-12-31T23:59:59.000Z

    In order to reduce the manufacturing cost of coke, it is necessary to reduce mainly (1) the material cost and (2) operating cost. Both of these costs can be reduced by lowering the moisture of charging coal. Because dust generation increases with decreasing moisture of charging coal, however, the lower limit of charging coal moisture in the existing coke-oven equipment was about 5%, which yielded good results in coal moisture control (CMC) equipment. Nippon Steel has furthered the development of techniques for lowering the moisture of charging coal as far as possible in the existing coke ovens and has recently succeeded in developing a dry-cleaned and agglomerated precompaction system (DAPS) and incorporating this system in commercial production equipment. In this system, a coal preparation process is undertaken that involves separating coal fines, which cause dust generation, from dried charging coal and agglomerating them. The equipment incorporating this system was installed in the No. 3 and No. 4 coke batteries at Oita Works and brought into full-scale operation in September 1992. The equipment has since been operating smoothly.

  12. Methods for reduction of charging emissions

    SciTech Connect (OSTI)

    Schuecker, F.J.; Schulte, H. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    One of the most critical subjects in coking plants are charging emissions. The paper reviews the systems that have been used over the years to reduce charging emissions. The advantages and disadvantages are summarized for the following systems: Double collecting main with aspiration on both oven sides; Single collecting main with/without aspiration via standpipe, and extraction and cleaning of charging gas on charging car; Single collecting main with aspiration via standpipe and pretreatment of charging gas on the charging car as well as additional stationary exhaust and cleaning of charging gas; Single collecting main with aspiration via single standpipe; and Single collecting main with simultaneous aspiration via two standpipes and a U-tube connecting the oven chamber with the neighboring oven. The paper then briefly discusses prerequisites for reduction of charging emissions.

  13. Trials with a 100% pellet burden in blast furnace No. 6 at Hoogovens IJmuiden

    SciTech Connect (OSTI)

    Schoone, E.; Toxopeus, H.; Vos, D. [Hoogovens IJmuiden (Netherlands). Ironmaking and Raw Materials Div.

    1995-12-01T23:59:59.000Z

    The burden consists of 50% high basicity sinter and 50% home made olivine pellets. Two coke oven plants produce the required coke, about 340 kg/t (680 lb/NT). The average pulverized coal injection rate is 150 kg/t (300 lb/NT). To anticipate the aging coke oven plant No. 2 the coal injection capacity will e increased by 50% in 1996, by the installation of a third coal grinding line. In the Netherlands environmental issues have a high impact on further developments. In particular the environmental regulations require a significant decrease of dust, SO{sub 2} and dioxins emitted by the sinter plant. The appropriate measures must be concluded in the second part of this decade. To avoid costly conventional solutions Hoogovens has been testing since April, 1994 the Emission Optimized Sintering (EOS). In case of failure of EOS, the situation of a (partially) closed sinter plant was tested. Purchased pellets replaced sinter, leading to a 100% pellet and an 80% pellet/20% sinter trial. The trials were executed in the first half of 1994 at blast furnace No. 6, equipped with a PW-bell less top. Results are described.

  14. Created March 2009 Microwave ovens are located throughout Swinburne University campuses in both staff & students

    E-Print Network [OSTI]

    Liley, David

    burns. · Never use plastic grocery bags, newspaper or plastic containers for frozen foods (such as ice-cream containers) in the microwave. · Avoid using plastic containers or film unless the manufacturer explicitly not touch food to avoid migration of chemicals from the plastic. · Open or pierce sealed food containers

  15. New Energy Efficiency Standards for Microwave Ovens to Save Consumers on

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy HealthCommentsAugustNationalMarkets with Wind PowerProcesses |FYEnergy Bills

  16. Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01T23:59:59.000Z

    In addition, the coking coal market began to deteriorateits permeability. Bituminous, or coking coal, is blended andmerchant coke plants, coking coal is heated in a low-oxygen,

  17. ORISE: Ann Gehl named new manager of Beryllium Lymphocyte Proliferatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of laboratory experience to role at ORISE FOR IMMEDIATE RELEASE Sept. 2, 2014 FY14-61 Ann Gehl Ann Gehl (Click for high resolution version) OAK RIDGE, Tenn.-ORAU has announced...

  18. Beryllium-7 Implantation in Plastics for Prosthesis Wear Studies...

    Office of Science (SC) Website

    instrumentation: 7Be Implantation in Plastics for Prosthesis Wear Studies Developed at: Oak Ridge National Laboratory, Holifield Radioactive Ion Beam Facility (HRIBF) Developed...

  19. acute beryllium disease: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that was originally described in 1946. Symptoms usually include dyspnea and cough. Fever, anorexia, and weight loss are common. Skin lesions are the most common...

  20. ORISE: Worker Health Studies - Beryllium Exposure Studies and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    which reduce the ability of the lungs to process gases and cause the patient to cough and experience shortness of breath. Other symptoms of CBD are chest pain, joint aches,...

  1. Hanford Site Beryllium Posting and Labeling Requirements Procedure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr FlickrGuidedCH2M HILL Secretary MonizSite Public Tours Hanford-003

  2. Hanford Site Beryllium Work Permit (BWP) and Hazard Assessment Procedure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr FlickrGuidedCH2M HILL Secretary MonizSite Public Tours

  3. Hanford Site Evaluation of Electrical Equipment for Beryllium Procedure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr FlickrGuidedCH2M HILL Secretary MonizSite Public ToursOfficial5

  4. Chronic Beryllium Disease Prevention Program (10 CFR 850) | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth DayFuels ChemicalChris Galm About

  5. Communicating Health Risks Working Safely With Beryllium | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth Codestheat Two Aluminum Sheet Production

  6. Improvements to the Oak Ridge National Laboratory Beryllium Program |

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietipDepartment of EnergyDepartment ofPhoto of anDepartment of

  7. Beryllium Screening - Informed Choice Document | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top Five EEREDepartment ofEnergy StevenHouseFieldBeowawe Binary

  8. Beryllium-Associated Worker Registry | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top Five EEREDepartment ofEnergy StevenHouseFieldBeowawe

  9. NIOSH Alert-Preventing Sentization and Disease from Beryllium | Department

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2 to:Diesel Engines|Foreign Travel RequestNEXT STEPS

  10. ORISE: Beryllium Awareness for Employees and Families (Video)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory | NationalJohnSecurityControlsOMBRadiationHowdesigned toMaking

  11. ORISE: Beryllium Laboratory Accredited by College of American Pathologists

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory | NationalJohnSecurityControlsOMBRadiationHowdesigned

  12. ORISE: Worker Health Studies - Beryllium Associated Worker Registry (BAWR)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory |CHEMPACKRadiologicalEric Dulmes Student'sDuringandOak

  13. ORISE: Worker Health Studies - Testing Beryllium Vendor Populations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory |CHEMPACKRadiologicalEric DulmesHow ORISE is Making a

  14. 2011 Beryllium-Associated Worker Registry Summary | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustionImprovement Awardflash2007-42attachment1.pdfmodule(EE) | Department ofofofJunctionScience20111

  15. 2012 Beryllium-Associated Worker Registry Summary | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustionImprovement Awardflash2007-42attachment1.pdfmodule(EE) |theDepartment2 Annual Site2

  16. Microsoft Word - Blue Cover Report - Beryllium Controls at LLNL

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office0-72.pdfGeorgeDoesn't32 Master EMAZ AUTOMOTIVE Submitted by:Microsoftof

  17. LLNS Beryllium Consent Order Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe10 DOEWashington, DCKickoffLDV5-CE-14022) LG: Proposed-

  18. ORISE: Ann Gehl named new manager of Beryllium Lymphocyte Proliferation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the ContributionsArms Control R&DNuclear fuelOPTICS FORJoethe U.S. at

  19. Bush Administration to Expand Beryllium Disease Screening Program |

    Office of Environmental Management (EM)

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  20. BACKGROUND REVIEW OF THE BRUSH BERYLLIUM AND DIAMOND MAGNESIUM PLANTS

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou areDowntown Site -MiamiYVE r. aw wL2--\ AP_I lo

  1. Beryllium-Associated Worker Registry Data Collection and Management Guidance

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists' ResearchTheMarketing,Energy and Natural Resourcespatterson.pdf

  2. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE Rad Con

  3. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE Rad

  4. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE Rad2S REDOX

  5. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE Rad2S

  6. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE Rad2S22T

  7. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE Rad2S22T1Z

  8. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE

  9. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE36Z

  10. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE36Z

  11. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE36Z71B B

  12. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE36Z71B B

  13. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE36Z71B BZB

  14. Hanford Facility Beryllium Fact Sheet Building Number/Name:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meetingand Eric EdlundWaste Treatment06KE36Z71B

  15. Los Alamos notifies employees, visitors of possible beryllium exposure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and Interfaces Sample6,LocalNuclearandplantsLos Alamos laser

  16. ORISE: Worker Health Studies - Beryllium Exposure Studies and Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat CornellInternships, Scholarships andUNIRIB Research Radiation

  17. Bush Administration to Expand Beryllium Disease Screening Program |

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustionImprovement3--Logistical5/08February 29 - March 2,Building

  18. Beryllium-Associated Worker Registry - HPMC Occupational Health Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAboutScienceCareers Apply for a JobBernard Matthew Poelker, 2011

  19. Beryllium-Associated Worker Registry Data Collection and Management Guidance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAboutScienceCareers Apply for a JobBernard Matthew Poelker,

  20. Microsoft Word - Beryllium Report Released NR - FINAL.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMappingENVIRONMENTAL IMPACTApproved: 5-16-14 FEDERAL5, 201015,THERELEASE:

  1. Title 10 CFR Part 850, Chronic Beryllium Disease Prevention Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe1A:decisional. 1 B O N NUnlocking Office of

  2. Sandia National Laboratories: Beryllium High Heat Flux Testing at PMTF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0Energy Advanced NuclearBASF latent curing epoxyBPU

  3. Thermal conductivity of beryllium-gas packed bed

    SciTech Connect (OSTI)

    Xu, M.; Abdou, M.A.; Raffray, A.R. [Univ. of California, Los Angeles, CA (United States)

    1994-12-31T23:59:59.000Z

    Unsintered packed bed has been suggested as a material form for solid breeder and multiplier in the ITER and fusion power reactor blankets. Study of the effective bed thermal conductivity can provide tools for analysis of the blanket performance under different operating conditions, and of how to actively control the thermal behavior of the blanket. Issues of particular interest are the ability to predict and to control the thermal conductivity. The 2-D model developed at UCLA is used to study the effect of particle diameter, solid-to-gas conductivity ratio, bed porosity, contact area, and surface roughness characteristics on bed thermal conductivity. The study shows that all parameters except bed porosity play important roles in determining the bed thermal controllability.

  4. Hot metal Si control at Kwangyang blast furnaces

    SciTech Connect (OSTI)

    Hur, N.S.; Cho, B.R.; Kim, G.Y.; Choi, J.S.; Kim, B.H. [POSCO, Cheollanamdo (Korea, Republic of). Kwangyang Works

    1995-12-01T23:59:59.000Z

    Studies of Si transfer in blast furnaces have shown that the Si level in pig iron is influenced more by the reaction of silicon oxide gas generation in the raceway than the chemical reaction between hot metal and slag at the drop zone. Specifications require a Si content of pig iron below 0.15% at the Kwangyang Works, but the use of soft coking coal in the blend for coke ovens, high pulverized coal injection rate into the blast furnace, and the application of lower grade iron ore has resulted in the need to develop methods to control Si in hot metal. In this paper, the results of in furnace Si control and the desiliconization skills at the casthouse floor are described.

  5. Building Energy Supply Infrastructures and Urban Sustained Development of Shenyang

    E-Print Network [OSTI]

    Feng, G.; Wang, Y.; Gao, Y.

    2006-01-01T23:59:59.000Z

    store 300-thousand-cubemeter gases. The compressor is designed to distribute 63? 000m3/h gas. At present, in Shenyang there are oil gases, coal seam gases, mine gases, coke oven gases, liquefied petroleum gases with air, liquefied petroleum gases...-generation power, immaculate energy and coal boiler. The heating area of combination between heat and electricity is 18 million square meters. The heating area of immaculate energy is 1.4 million square meters, in which that of electric, oil and gas heating...

  6. The interrelationship between environmental goals, productivity improvement, and increased energy efficiency in integrated paper and steel plants

    SciTech Connect (OSTI)

    NONE

    1997-06-01T23:59:59.000Z

    This report presents the results of an investigation into the interrelationships between plant-level productivity, energy efficiency, and environmental improvements for integrated pulp and paper mills and integrated steel mills in the US. Integrated paper and steel plants are defined as those facilities that use some form of onsite raw material to produce final products (for example, paper and paperboard or finished steel). Fully integrated pulp and paper mills produce onsite the pulp used to manufacture paper from virgin wood fiber, secondary fiber, or nonwood fiber. Fully integrated steel mills process steel from coal, iron ore, and scrap inputs and have onsite coke oven facilities.

  7. Industrial Plate Exchangers Heat Recovery and Fouling

    E-Print Network [OSTI]

    Cross, P. H.

    1981-01-01T23:59:59.000Z

    (still)for separation of light oil from the wash oil,which is then returned to absorber tower.The debenzolised wash 0 0 oil is cooled indirectly to 20 C/30 C before returning to the absorber tower. This is toprevent condensation of water from the gas... Industrial Energy Technology Conference Houston, TX, April 26-29, 1981 -- c.O.G. LIGHT OIL SCRUBBER COKE OVEN GAS(C.O.G,J BENZINE COOLING WATER BENZOLISED ~WASH OILSTRIPPER CONVENTIONAL LIGHT OIL RECOVERY PLANT DEBENZOLISED WASH OIL / COOLING WATER...

  8. China Energy Primer

    E-Print Network [OSTI]

    Ni, Chun Chun

    2010-01-01T23:59:59.000Z

    35 Table 2-17 Coking Coal Used in Coke Production (1980-Figure 2-5, Figure 2-6). Coking coal accounts for about 45%although less than 40% of coking coal is used for coking (

  9. Technology for processing ammonium rhodanide of coking plants into high-purity ammonium thiocyanate and thiourea

    SciTech Connect (OSTI)

    Urakaev, F.K. [Institute of Geology & Mineral SB RAS, Novosibirsk (Russian Federation)

    2009-04-15T23:59:59.000Z

    The regularities of the reversible reaction of isomerization of ammonium thiocyanate (NH{sub 4}NCS) into thiourea (NH{sub 2}){sub 2}CS, and the reverse reaction, were analyzed. An ecologically clean and highly efficient method for the extraction, purification, separation, and production of isomers from the coal byproduct ammonium thiocyanate was developed based on the measured volatilities of NH{sub 4}NCS and (NH{sub 2}){sub 2}CS.

  10. Sawdust Pyrolysis and Petroleum Coke CO2 Gasification at High Heating Rates.

    E-Print Network [OSTI]

    Lewis, Aaron D.

    2011-01-01T23:59:59.000Z

    ??Clean and efficient electricity can be generated using an Integrated Gasification Combined Cycle (IGCC). Although IGCC is typically used with coal, it can also be… (more)

  11. Thermal and hydraulic effects of coke deposit in hydrocarbon pyrolysis process.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    are of interest, notably in case of regenerative methods to be applied on the SCRamjet engine [1],[2]. Some

  12. Reconstruction of the paleoenvironments of Jameson (Strawn) Reef field, Coke County, Texas

    E-Print Network [OSTI]

    Hopkins, Kenneth Warren

    1983-01-01T23:59:59.000Z

    strata filled depressions on the deeply eroded Ellenburger pro- viding a flat surface on which the Strawn could be deposited. Cheney and Goss (1952) classified Bendian rocks as normal marine blanket deposits. They are mainly shale and argillaceous... phreatic from the marine phreatic and is marked by brackish waters. The marine phreatic environment is characterized by rocks that have all pore space filled with normal marine water. As burial of the sediments continues, other forms of diagenesis occur...

  13. Process safety management (OSHA) and process risk management (CAA) application. Application to a coke plant

    SciTech Connect (OSTI)

    Graeser, W.C.; Mentzer, W.P.

    1995-12-01T23:59:59.000Z

    Risk Management Programs for Chemical Accidental Release Prevention is the name of the proposed rule for the RMP Risk Management Program. The RMP was written in response to several catastrophic releases of hazardous substances. The rule is applicable to facilities that store, process or use greater than threshold quantities of 62 listed flammable chemicals and another 100 listed toxic substances. Additionally, a Risk Management Plan is registered with the EPA, Chemical Safety and Hazardous Investigation Board, state governments and the local emergency planning commission. The Clean Air Act Amendments of 1990 (specifically Section 112r) required the EPA to develop a three phase Risk Management Plan for industry: prevention program; hazard assessment; and emergency response program. The Prevention Program closely follows the OSHA`s Process Safety Management Standard. The Hazard Assessment section requires facilities to develop plans for a worst case scenario. The Emergency Response section defines the steps the facility and each employee will take if a release occurs. This section also needs to be coordinated with the Local Emergency Planning Commission. These regulations are described using Clairton Works as an example of compliance.

  14. The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite

    E-Print Network [OSTI]

    McLaughlin, Kenneth Woot

    1983-01-01T23:59:59.000Z

    ). Reactant: methanol t-butanol 1-heotanol Reaction conditions Temp. (K) LHSV (hr ) 644 1. 0 644 1. 0 644 0. 7 Conversion (g) 1 00 100 99. 9 Hydrocarbon distribution (wt g) methane ethane ethylene propane propylene i-butane n-butane bu...

  15. Solidification/stabilization of toxic metal wastes using coke and coal combustion by-products

    SciTech Connect (OSTI)

    Vempati, R.K.; Mollah, M.Y.A.; Chinthala, A.K.; Cocke, D.L. [Lamar Univ., Beaumont, TX (United States)] [Lamar Univ., Beaumont, TX (United States); Beeghly, J.H. [Dravo Lime, Pittsburgh, PA (United States)] [Dravo Lime, Pittsburgh, PA (United States)

    1995-12-31T23:59:59.000Z

    A study has been conducted to evaluate the potential of a special rubber waste, NISCO Cyclone Ash (NCA), which contains substantial calcium oxide and calcium sulfites/sulfates for solidification/stabilization (S/S) of toxic metal wastes. The mineralogical compositions of the NCA and a class ``C`` fly ash have been characterized by X-ray diffraction (XRD). Hydrated mixtures of these wastes have been examined by XRD and found to form ettringite. Low concentrations of As (15 {micro}g ml{sup {minus}1}), Ba (500 {micro}g ml{sup {minus}1}), Pb (15 {micro}g ml{sup {minus}1}), and Zn (1,000 {micro}g ml{sup {minus}1}) were added to these hydrated mixtures and found to be successfully immobilized and solidified, as determined by the Toxicity Characteristic Leaching Procedure (TCLP). In addition, the mineralogy, chemistry and leaching characteristics of these combined waste products and their interactions with toxic metals are discussed.

  16. High temperature properties and reactivity of coal and coke for ironmaking.

    E-Print Network [OSTI]

    Kim, Byong-Chul

    2012-01-01T23:59:59.000Z

    ??Rapid growth of the steel industry in coming years will be strongly dependent upon coal. Understanding of coal behavior in current or emerging ironmaking processes… (more)

  17. High ash non-coking coal preparation by tribo-electrostatic dry process.

    E-Print Network [OSTI]

    Ranjan Dwari

    2008-01-01T23:59:59.000Z

    ??Coal is the single largest fossil fuel used world-wide and accounts for more than 60% of the total commercial energy consumed. Between 60 to 80%… (more)

  18. Effects of hydrogen donor additives on the coking properties of high-temperature coal extracts.

    E-Print Network [OSTI]

    Makgato, Matlou Hector

    2009-01-01T23:59:59.000Z

    ?? Refcoal is a carbon precursor obtained by alkali-mediated extraction of coal with aprotic solvents such as DMF. Refcoal can be converted into a graphitic… (more)

  19. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot Kennel; Chong Chen; Dady Dadyburjor; Mark Heavner; Manoj Katakdaunde; Liviu Magean; James Mayberry; Alfred Stiller; Joseph Stoffa; Christopher Yurchick; John Zondlo

    2009-12-31T23:59:59.000Z

    This NETL sponsored effort seeks to develop continuous technologies for the production of carbon products, which may be thought of as the heavier products currently produced from refining of crude petroleum and coal tars obtained from metallurgical grade coke ovens. This effort took binder grade pitch, produced from liquefaction of West Virginia bituminous grade coal, all the way to commercial demonstration in a state of the art arc furnace. Other products, such as crude oil, anode grade coke and metallurgical grade coke were demonstrated successfully at the bench scale. The technology developed herein diverged from the previous state of the art in direct liquefaction (also referred to as the Bergius process), in two major respects. First, direct liquefaction was accomplished with less than a percent of hydrogen per unit mass of product, or about 3 pound per barrel or less. By contrast, other variants of the Bergius process require the use of 15 pounds or more of hydrogen per barrel, resulting in an inherent materials cost. Second, the conventional Bergius process requires high pressure, in the range of 1500 psig to 3000 psig. The WVU process variant has been carried out at pressures below 400 psig, a significant difference. Thanks mainly to DOE sponsorship, the WVU process has been licensed to a Canadian Company, Quantex Energy Inc, with a commercial demonstration unit plant scheduled to be erected in 2011.

  20. Energy and materials savings from gases and solid waste recovery in the iron and steel industry in Brazil: An industrial ecology approach

    SciTech Connect (OSTI)

    Costa, M.M.; Schaeffer, R.

    1997-07-01T23:59:59.000Z

    This paper attempts to investigate, from an entropic point of view, the role of selected technologies in the production, transformation, consumption and release of energy and materials in the Iron and Steel Industry in Brazil. In a quantitative analysis, the potential for energy and materials savings with recovery of heat, gases and tar are evaluated for the Iron and Steel Industry in Brazil. The technologies for heat recovery of gases include Coke Dry Quenching (CDQ), applied only in one of the five Brazilian coke integrated steel plants, Top Gas Pressure Recovery Turbines (TPRT), recovery of Coke Oven Gas (COG), recovery of Blast Furnace Gas (BFG), recovery of BOF gas, recovery of tar, and thermal plant. Results indicate that, in a technical scenario, some 5.1 TWh of electricity can be generated if these technologies are applied to recover these remaining secondary fuels in the Iron and Steel Industry in Brazil, which is equivalent to some 45% of current total electricity consumption in the integrated plants in the country. Finally, solid waste control technologies, including options available for collection and treatment, are discussed. Estimates using the best practice methodology show that solid waste generation in the Iron and Steel Industry in Brazil reached approximately 18 million metric tons in 1994, of which 28% can be recirculated if the best practice available in the country is applied thoroughly.

  1. Usnesen ze 4. zasedn Vdeck rady AV CR konanho dne 10. z 1. Oven a kontrola zpisu z 3. zasedn

    E-Print Network [OSTI]

    Tebbens, Jurjen Duintjer

    reform terciárního vzdlávání. Vdecká rada AV CR bere se souhlasem na vdomí stanovisko AR AV CR k reform

  2. J. Am. Chem. SOC 1982, 104, 313-315 313 the vapor to 670 K oven temperature.

    E-Print Network [OSTI]

    Dervan, Peter B.

    with the is0 (valence) electronic acrolein, the PE spectrum8 of which (Figure 1) displays a similar ionization

  3. Correlation between self-ignition of a dust layer on a hot surface and in baskets in an oven

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    such as heat of combustion, heat capacity, density) [dimensionless] P: lumped parameter [K] r: critical

  4. Abstract--The paper reviews solutions being explored to face the supply problems faced in the Chilean electricity market oven

    E-Print Network [OSTI]

    Catholic University of Chile (Universidad CatĂłlica de Chile)

    coal has to be used for electric generation. Hydroelectric generation has developed using most Argentina. Investment in generation came to a stall, given uncertainties in natural gas supply and the risk only provides less than 10% of the country's needs, while its coal is of poor quality, so that imported

  5. Inventory of China's Energy-Related CO2 Emissions in 2008

    E-Print Network [OSTI]

    Fridley, David

    2011-01-01T23:59:59.000Z

    from Agriculture Energy Consumption Coal Coke and Otherfrom Industry Energy Consumption Coal Coke and Otherfrom Construction Energy Consumption Coal Coke and Other

  6. China Energy and Emissions Paths to 2030

    E-Print Network [OSTI]

    Fridley, David

    2012-01-01T23:59:59.000Z

    refining, oil extraction, coking, coal mining, natural gasthe use of expensive heavy coking coal and increase theof inexpensive semi-coking coal. The ability to substitute

  7. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    19 3.4. Coking coal for iron & steels FOB export value for coking coal was relatively stables FOB export value for coking coal significantly increased

  8. China Energy Databook - Rev. 4

    E-Print Network [OSTI]

    Sinton Editor, J.E.

    2010-01-01T23:59:59.000Z

    generation, heating, coking and coal gas production, andgeneration, heating, coking and coal gas production, andgeneration, heating, coking and coal gas production, and

  9. Inventory of China's Energy-Related CO2 Emissions in 2008

    E-Print Network [OSTI]

    Fridley, David

    2011-01-01T23:59:59.000Z

    gas petroleum waxes coking coal t C/TJ other bituminous coalprocesses of coal washing, coking, petroleum refineries, gaslosses include coal washing, coking, petroleum refining, gas

  10. Key China Energy Statistics 2011

    E-Print Network [OSTI]

    Levine, Mark

    2013-01-01T23:59:59.000Z

    Heating Supply Coal Washing Coking Petroleum Refineries GasPower Heating Supply Coal Washing Coking Total ConsumptionHeating Supply Coal Washing Coking Petroleum Refineries Gas

  11. Key China Energy Statistics 2012

    E-Print Network [OSTI]

    Levine, Mark

    2013-01-01T23:59:59.000Z

    Heating Supply Coal Washing Coking Petroleum Refineries GasHeating Supply Coal Washing Coking Petroleum Refineries GasRefueling in China Coal Washing Coking Petroleum Refineries

  12. China Energy Databook -- User Guide and Documentation, Version 7.0

    E-Print Network [OSTI]

    Fridley, Ed., David

    2008-01-01T23:59:59.000Z

    years report coking and oil refining investment in a singleyears report coking and oil refining investment in a singleyears report coking and oil refining investment in a single

  13. Development of an advanced, continuous mild gasification process for the production of co-products

    SciTech Connect (OSTI)

    Cohen, L.R. (Xytel-Bechtel, Inc. (United States)); Hogsett, R.F. (AMAX Research and Development Center, Golden, CO (United States)); Sinor, J.E. (Sinor (J.E.) Consultants, Inc., Niwot, CO (United States)); Ness, R.O. Jr.; Runge, B.D. (North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center)

    1992-10-01T23:59:59.000Z

    The principal finding of this study was the high capital cost and poor financial performance predicted for the size and configuration of the plant design presented. The XBi financial assessment gave a disappointingly low base-case discounted cash flow rate of return (DCFRR) of only 8.1% based on a unit capital cost of $900 per ton year (tpy) for their 129,000 tpy design. This plant cost is in reasonable agreement with the preliminary estimates developed by J.E. Sinor Associates for a 117,000 tpy plant based on the FMC process with similar auxiliaries (Sinor, 1989), for which a unit capital costs of $938 tpy was predicted for a design that included char beneficiation and coal liquids upgrading--or about $779 tpy without the liquid upgrading facilities. The XBi assessment points out that a unit plant cost of $900 tpy is about three times the cost for a conventional coke oven, and therefore, outside the competitive range for commercialization. Modifications to improve process economics could involve increasing plant size, expanding the product slate that XBi has restricted to form coke and electricity, and simplifying the plant flow sheet by eliminating marginally effective cleaning steps and changing other key design parameters. Improving the financial performance of the proposed formed coke design to the level of a 20% DCFRR based on increased plant size alone would require a twenty-fold increase to a coal input of 20,000 tpd and a coke production of about 2.6 minion tpy--a scaling exponent of 0.70 to correct plant cost in relation to plant size.

  14. Development of an advanced, continuous mild gasification process for the production of co-products. Task 4.6, Economic evaluation

    SciTech Connect (OSTI)

    Cohen, L.R. [Xytel-Bechtel, Inc. (United States); Hogsett, R.F. [AMAX Research and Development Center, Golden, CO (United States); Sinor, J.E. [Sinor (J.E.) Consultants, Inc., Niwot, CO (United States); Ness, R.O. Jr.; Runge, B.D. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

    1992-10-01T23:59:59.000Z

    The principal finding of this study was the high capital cost and poor financial performance predicted for the size and configuration of the plant design presented. The XBi financial assessment gave a disappointingly low base-case discounted cash flow rate of return (DCFRR) of only 8.1% based on a unit capital cost of $900 per ton year (tpy) for their 129,000 tpy design. This plant cost is in reasonable agreement with the preliminary estimates developed by J.E. Sinor Associates for a 117,000 tpy plant based on the FMC process with similar auxiliaries (Sinor, 1989), for which a unit capital costs of $938 tpy was predicted for a design that included char beneficiation and coal liquids upgrading--or about $779 tpy without the liquid upgrading facilities. The XBi assessment points out that a unit plant cost of $900 tpy is about three times the cost for a conventional coke oven, and therefore, outside the competitive range for commercialization. Modifications to improve process economics could involve increasing plant size, expanding the product slate that XBi has restricted to form coke and electricity, and simplifying the plant flow sheet by eliminating marginally effective cleaning steps and changing other key design parameters. Improving the financial performance of the proposed formed coke design to the level of a 20% DCFRR based on increased plant size alone would require a twenty-fold increase to a coal input of 20,000 tpd and a coke production of about 2.6 minion tpy--a scaling exponent of 0.70 to correct plant cost in relation to plant size.

  15. Major prime contractors have developed a plan to address Hanford Beryllium exposure and are continuing to improve the Chronic Beryllium Disease Prevention Plan (CBDPP)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and InterfacesAdministration -Lowellfor 2013 |Spherical

  16. China Energy Databook -- User Guide and Documentation, Version 7.0

    E-Print Network [OSTI]

    Fridley, Ed., David

    2008-01-01T23:59:59.000Z

    2] In 1996, 1997, 1998, coking and coal numbers are combined2] In 1996, 1997, 1998, coking and coal numbers are combined1949-2006 Table 2B.7. Coking Coal Used in Coke Production,

  17. A Long, Contingent Path to Comparative Advantage: Industrial Policy and the Japanese Iron and Steel Industry, 1900-1973

    E-Print Network [OSTI]

    ELBAUM, BERNARD

    2006-01-01T23:59:59.000Z

    Overseas Procurement of Coking Coal By the Japanese Steelendowed as Japan in coking coal and iron ore (Yonekura,

  18. Japan's Long-term Energy Demand and Supply Scenario to 2050 - Estimation for the Potential of Massive CO2 Mitigation

    E-Print Network [OSTI]

    Komiyama, Ryoichi

    2010-01-01T23:59:59.000Z

    Consumption of coking coal mainly for steelmaking will dropelectricity and town gas. Coking coal consumption mainly for

  19. The Cylinder: Kinematics of the Nineteenth Century

    E-Print Network [OSTI]

    Müller-Sievers, Helmut

    2012-01-01T23:59:59.000Z

    distillation. The coking of coal as well as the productionin coal mines, in steel and paper mills, in coking plants,

  20. Adding coal dust to coal batch

    SciTech Connect (OSTI)

    V.S. Shved; A.V.Berezin [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    The granulometric composition of coke dust from the dry-slaking machine is determined. The influence of additions of 3-7% coke dust on the quality of industrial coking batch and the coke obtained by box coking is estimated. Adding 1% coke dust to coking batch does not markedly change the coke quality. Industrial equipment for the supply of dry-slaking dust to the batch is described.

  1. Assessment of China's Energy-Saving and Emission-Reduction Accomplishments and Opportunities During the 11th Five Year Plan

    E-Print Network [OSTI]

    Levine, Mark D.

    2010-01-01T23:59:59.000Z

    calcium carbide, coking, cement, coal, plate glass, pulp andcarbide 2 Mt Coking 80 Mt Cement 250 Mt Coal mining (

  2. Vol. 60364 P. L. WALKER,JR.,AND EMILERAATS whether the swelling is of the predicted order of

    E-Print Network [OSTI]

    ofpetro- leum coke bound together by a thin shell of coal tar pitch coke, which essentially consists

  3. AISI Direct Steelmaking Program. Final technical report

    SciTech Connect (OSTI)

    Aukrust, E.

    1994-08-01T23:59:59.000Z

    This final report deals with the results of a 5-yr project for developing a more energy-efficient, environmentally friendly, less costly process for producing hot metal than current coke ovens and blast furnaces. In the process, iron ore pellets are smelted in a foamy slag created by reaction of coal char with molten slag to produce CO. The CO further reacts with oxygen, which also reacts with coal volatile matter, to produce the heat necessary to sustain the endothermic reduction reaction. The uncombusted CO and H{sub 2} from the coal are used to preheat and prereduce hematite pellets for the most efficient use of the energy in the coal. Laboratory programs confirmed that the process steps worked. Pilot plant studies were successful. Economic analysis for a 1 million tpy plant is promising.

  4. Analysis of ammonium sulfate circulation tank failure -- Possible causes and their remediation

    SciTech Connect (OSTI)

    O`Hearn, R.J. [Acme Steel, Chicago, IL (United States)

    1997-12-31T23:59:59.000Z

    Acme steel manufactures a liquid solution of ammonium sulphate by scrubbing the coke oven gas with a dilute solution of sulphuric acid. When the bath reaches a predetermined specific gravity, it is isolated from the system, neutralized with aqua ammonia, pumped to the shipping tanks, re-charged with water and acid, then placed back in service. To improve the ammonia removal efficiency, three circulation tanks are used in this system. In June 1996, the volume of two of the sulfate solution tanks in the ammonia removal plant were increased by two different pressure events. The first tank was damaged by pressure that was not relieved due to a plugged vent line. The second tank was damaged by a pressure event generated during the process of making ammonium sulfate. This paper will discuss the cause of the second tank`s failure, and the design solution to restart the operation of the plant.

  5. Operating experience with 100% pellet burden on Amanda blast furnace

    SciTech Connect (OSTI)

    Keaton, D.E.; Minakawa, T. (Armco Steel Co., Middletown, OH (United States). Ironmaking Dept.)

    1993-01-01T23:59:59.000Z

    A number of significant changes in operations at the Ashland Works of the Armco Steel Company occurred in 1992 which directly impacted the Amanda Blast Furnace operation. These changes included the shutdown of the hot strip mill which resulted in coke oven gas enrichment of the Amanda stoves and an increase of 75 C in hot blast temperature, transition to 100% continuous cast operation which resulted in increased variation of the hot metal demand, and the July idling of the sinter plant. Historically, the Amanda Blast Furnace burden was 30% fluxed sinter and 70% acid pellet. It was anticipated that the change to 100% pellet burden would require changes in charging practice and alter furnace performance. The paper gives a general furnace description and then describes the burden characteristics, operating practice with 30% sinter/70% acid pellet burden, preparations for the 100% acid pellet burden operation, the 100% acid pellet operation, and the 100% fluxed pellet burden operation.

  6. The Search for Dark Matter in XENON100 using a Two-Dimensional Profile Likelihood Analysis

    E-Print Network [OSTI]

    Lung, Kevin J.

    2013-01-01T23:59:59.000Z

    for the simulated Americium Beryllium neutron source fromwere performed using an Americium-Beryllium (AmBe) source.input energy spectrum from Americium Beryllium decays (ISO

  7. A novel technique for on-line coke gasification during propane steam reforming using forced CO2 cycling.

    E-Print Network [OSTI]

    Alenazey, Feraih Sheradh

    2011-01-01T23:59:59.000Z

    ??Steam reforming is an important source of synthesis gas production that is used by major petrochemical processes such as ammonia, methanol and the Fisher-Tropsch process.… (more)

  8. Enhancing P-xylene selectivity during m-xylene transformation using mildly pre-coked ZSM-5 catalyst

    E-Print Network [OSTI]

    Al-Khattaf, Sulaiman

    catalyst S. Al-Khattaf* Department of Chemical Engineering, King Fahd University of Petroleum & Minerals for various processes, like the production of synthetic fibres and plasticizers, efforts are continually been been investigated in detail by several workers [1-12]. Modifications of ZSM-5 by various compounds have

  9. Minimizing the formation of coke and methane on Co nanoparticles in steam reforming of biomass-derived oxygenates

    SciTech Connect (OSTI)

    Sun, Junming; Mei, Donghai; Karim, Ayman M.; Datye, Abhaya K.; Wang, Yong

    2013-06-01T23:59:59.000Z

    Fundamental understanding and control of chemical transformations are essential to the development of technically feasible and economically viable catalytic processes for efficient conversion of biomass to fuels and chemicals. Using an integrated experimental and theoretical approach, we report high hydrogen selectivity and catalyst durability of acetone steam reforming (ASR) on inert carbon supported Co nanoparticles. The observed catalytic performance is further elucidated on the basis of comprehensive first-principles calculations. Instead of being considered as an undesired intermediate prone for catalyst deactivation during bioethanol steam reforming (ESR), acetone is suggested as a key and desired intermediate in proposed two-stage ESR process that leads to high hydrogen selectivity and low methane formation on Co-based catalysts. The significance of the present work also sheds a light on controlling the chemical transformations of key intermediates in biomass conversion such as ketones. We gratefully acknowledge the financial support from U. S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences, and the Laboratory directed research and development (LDRD) project of Pacific Northwest National Laboratory (PNNL). Computing time was granted by the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL). The EMSL is a U.S. DOE national scientific user facility located at PNNL, and sponsored by the U.S. DOE’s Office of Biological and Environmental Research.

  10. E-Print Network 3.0 - antimony barium beryllium Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cadmium, lead, and zinc), only two individual QC results fell outside Source: Fleskes, Joe - Dixon Field Station, Western Ecological Research Center, USGS Collection:...

  11. On the possibility of using uranium-beryllium oxide fuel in a VVER reactor

    SciTech Connect (OSTI)

    Kovalishin, A. A.; Prosyolkov, V. N.; Sidorenko, V. D. [National Research Center Kurchatov Institute (Russian Federation); Stogov, Yu. V., E-mail: YVStogov@mephi.ru [National Research Nuclear University MEPhI (Russian Federation)

    2014-12-15T23:59:59.000Z

    The possibility of using UO{sub 2}-BeO fuel in a VVER reactor is considered with allowance for the thermophysical properties of this fuel. Neutron characteristics of VVER fuel assemblies with UO{sub 2}-BeO fuel pellets are estimated.

  12. Periodic striations on beryllium and tungsten surfaces by indirect femtosecond laser irradiation

    SciTech Connect (OSTI)

    Lungu, C. P.; Tico?, C. M., E-mail: catalin.ticos@inflpr.ro; Poro?nicu, C.; Jepu, I.; Lungu, M.; Marcu, A.; Luculescu, C.; Cojocaru, G.; Ursescu, D.; B?nici, R.; Ungureanu, G. R. [National Institute for Laser, Plasma and Radiation Physics, 077125 Bucharest (Romania)] [National Institute for Laser, Plasma and Radiation Physics, 077125 Bucharest (Romania)

    2014-03-10T23:59:59.000Z

    Femtosecond laser pulses with ??=?800?nm were focused in air at one atmosphere and in deuterium (D) at low pressure. Submicron periodic structures were observed on surfaces made of Be, W and a mixture of Be-W immersed in these gases and placed nearly parallel with the laser beam, at 300??m from the focal spot. In air, no structures were observed on Be. For the Be-W mixture, the periodic structures were uniform and parallel when formed in D but irregular in air. In this last case the striations were organized into small patches of 1 to 2 ?m in size.

  13. Review of Beryllium Management Practices at Rocky Flats During Closure Operations

    Broader source: Energy.gov [DOE]

    Administrative and engineering controls, along with detailed medical and training programs and strict adherence to all characterization, sampling, and work procedures ensured that exposure to...

  14. Greek research reactor performance characteristics after addition of beryllium reflector and LEU fuel

    SciTech Connect (OSTI)

    Deen, J.R.; Snelgrove, J.L. [Argonne National Lab., IL (United States); Papastergiou, C. [National Center for Scientific Research, Athens (Greece)

    1992-12-31T23:59:59.000Z

    The GRR-1 is a 5-MW pool-type, light-water-moderated and-cooled reactor fueled with MTR-type fuel elements. Recently received Be reflector blocks will soon be added to the core to add additional reactivity until fresh LEU fuel arrives. REBUS-3 xy fuel cycle analyses, using burnup dependent cross sections, were performed to assist in fuel management decisions for the water- and Be-reflected HEU nonequilibrium cores. Cross sections generated by EPRI-CELL have been benchmarked to identical VIM Monte Carlo models. The size of the Be-reflected LEU core has been reduced to 30 elements compared to 35 for the HEU water-reflected core, and an equilibrium cycle calculation has been performed.

  15. Greek research reactor performance characteristics after addition of beryllium reflector and LEU fuel

    SciTech Connect (OSTI)

    Deen, J.R.; Snelgrove, J.L. (Argonne National Lab., IL (United States)); Papastergiou, C. (National Center for Scientific Research, Athens (Greece))

    1992-01-01T23:59:59.000Z

    The GRR-1 is a 5-MW pool-type, light-water-moderated and-cooled reactor fueled with MTR-type fuel elements. Recently received Be reflector blocks will soon be added to the core to add additional reactivity until fresh LEU fuel arrives. REBUS-3 xy fuel cycle analyses, using burnup dependent cross sections, were performed to assist in fuel management decisions for the water- and Be-reflected HEU nonequilibrium cores. Cross sections generated by EPRI-CELL have been benchmarked to identical VIM Monte Carlo models. The size of the Be-reflected LEU core has been reduced to 30 elements compared to 35 for the HEU water-reflected core, and an equilibrium cycle calculation has been performed.

  16. Beryllium Impregnation of Uranium Fuel: Thermal Modeling of Cylindrical Objects for Efficiency Evaluation

    E-Print Network [OSTI]

    Lynn, Nicholas

    2011-08-04T23:59:59.000Z

    With active research projects related to nuclear waste immobilization and high conductivity nuclear fuels, a thermal model has been developed to simulate the temperature profile within a heat generating cylinder in order to imitate the behavior...

  17. E-Print Network 3.0 - actively cooled beryllium Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    flux-trap type swimming pool reactor that uses highly... of the reactor is its neutron scattering capabilities. This activity has grown in both scientific and economic......

  18. Investigation of the Dashigil mud volcano (Azerbaijan) using beryllium-10 K.J. Kim a,

    E-Print Network [OSTI]

    Geological Research Division, Korea Institute of Geoscience and Mineral Resources, Daejeon 305-350, Republic of Korea b Department of Geology, Wayne State University, Detroit, MI 48202, USA c Geology Institute volcanoes, sedimentary volca- noes, gas­oil volcanoes etc. Mud volcanoes resemble magmatic volcanoes

  19. Monte-Carlo Analysis of Big Bang Production of Beryllium and Boron

    E-Print Network [OSTI]

    David Thomas

    1994-12-11T23:59:59.000Z

    There is continued interest in the possibility that big bang nucleosynthesis may produce significant quantities of Be and B. In this paper we reevaluate the primordial abundances taking into account uncertainties in reactions rates. We discuss the implications for primordial nucleosynthesis, and for galactic cosmic ray spallation.

  20. E-Print Network 3.0 - arsenic beryllium cadmium Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with much stronger emission lines from ... Source: Buckley, Steven G. - Department of Mechanical and Aerospace Engineering, University of California at San Diego; Hahn, David...

  1. Update on the Hanford Site Chronic Beryllium Disease Prevention Program (CBDPP)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II Field Emission SEM with EDAX (For3WebinarUpdateUpdate

  2. Update on the Hanford Site Chronic Beryllium Disease Prevention Program (CBDPP)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II Field Emission SEM with EDAX (For3WebinarUpdateUpdateMay 9,

  3. ORISE: ORAU-managed beryllium lab marks outstanding year in 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the ContributionsArms Control R&DNuclearNuclear engineering degreesORAUORAU-managed

  4. DOE - Office of Legacy Management -- Brush Beryllium Co - Clevland - OH 02

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou are here Home »Hill -

  5. DOE - Office of Legacy Management -- Brush Beryllium Co - Elmore - OH 09

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou are here Home »Hill -Elmore - OH 09 FUSRAP

  6. DOE - Office of Legacy Management -- Brush Beryllium Co - Lorain - OH 47

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou are here Home »Hill -Elmore - OH 09 FUSRAPBrush

  7. Independent Oversight Inspection of the Hanford Site Chronic Beryllium Disease Prevention Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinementEtching.348 270Energy Innovation Portal

  8. Microsoft Word - 2010O-01_DOE Response to Beryllium.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fundProject QuarterlyDepartmentConducting1,Response to DOE's

  9. Microsoft Word - HABAdv#228_Independent Review of BerylliumProgram.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fundProject8 -3 Subject: Tank Waste System Plan Rev 420345 HAB

  10. Beryllium-7 Implantation in Plastics for Prosthesis Wear Studies | U.S. DOE

    Office of Science (SC) Website

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 IndustrialIsadore Perlman,BiosScience(SC) AprilScienceReports »

  11. ATTACHMENT 1: HANFORD SITE CHRONIC BERYLLIUM DISEASE PREVENTION PROGRAM (CBDPP) COMMITTEE CHARTER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)Productssondeadjustsondeadjust DocumentationARMStreamsUSBudget AdvancedASSESSING AND9NOV98: HANFORD SITE

  12. Fusion Engineering and Design 5152 (2000) 8591 Analysis of tritium kinetics of SIBELIUS beryllium

    E-Print Network [OSTI]

    Abdou, Mohamed

    S. Cho a, *, M.A. Abdou b a Korea Basic Science Institute, 52 Yeoeun-dong, Yusung-ku, Taejeon, 305 © 2000 Elsevier Science B.V. All rights reserved. PII: S0920-3796(00)00378-1 #12;S. Cho, M.A. Abdou

  13. The effects of beryllium additions on the oxidation of nickel aluminide and titanium aluminide based intermetallics

    SciTech Connect (OSTI)

    Hanrahan, R.J. Jr.; Chen, K.C. [Los Alamos National Lab., NM (United States). Materials Science and Technology Div.; Brady, M.P. [Oak Ridge National Lab., NM (United States). Metals and Ceramics Div.

    1998-12-31T23:59:59.000Z

    The effects of Be additions on the oxidation behavior of {beta}-NiAl in moist air at 1,000 C and borderline alumina-forming {gamma} (TiAl) + Laves Ti-Al-Cr based alloys at 800 C and 1,000 C in dry and moist air were investigated. The addition of Be to {beta}-NiAl suppressed the formation of transient alumina, and resulted in the formation of a protective BeAl{sub 2}O{sub 4} spinel phase. In dry air, the addition of Be to the Ti-Al-Cr alloys also resulted in the formation of a protective BeAl{sub 2}O{sub 4} spinel phase. In moist air, only Ti-Al-Cr-Be alloys with a high Cr content (10 to 15 a/o) formed the protective BeAl{sub 2}O{sub 4} scale.

  14. The effects of beryllium additions on the oxidation of nickel aluminide and titanium aluminide based intermetallics

    SciTech Connect (OSTI)

    Hanrahan, R.J. Jr.; Chen, K.C. [Los Alamos National Lab., NM (United States). Materials Science and Technology Div.; Brady, M.P. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1998-11-01T23:59:59.000Z

    The effects of Be additions on the oxidation behavior of {beta}-NiAl in moist air at 1,000 C as well as on the borderline alumina-forming {gamma} + Laves Ti-Al-Cr based alloys at 800 C and 1,000 C in dry and moist air were investigated. The addition of Be to {beta}-NiAl suppressed the formation of transient alumina and resulted in the formation of a protective BeAl{sub 2}O{sub 4} spinel phase. In dry air, the addition of Be to the Ti-Al-Cr alloys also resulted in the formation of a protective BeAl{sub 2}O{sub 4} spinel phase. In moist air, only Ti-Al-Cr-Be alloys with a high Cr content (10 to 15 a/o) formed the protective BeAl{sub 2}O{sub 4} scale.

  15. Planning for the 400,000 tons/year AISI ironmaking demonstration plant

    SciTech Connect (OSTI)

    Aukrust, E. (LTV Steel Corp., Cleveland, OH (United States). AISI Direct Steelmaking Program)

    1993-01-01T23:59:59.000Z

    The American Iron and Steel Institute (AISI) has formulated a four-year program to design, construct, and operate a 400,000 net ton per year ironmaking demonstration plant. The plant will employ the coal-based ironmaking process developed under a 1989 cooperative agreement with DOE. AISI will manage the design and construction to be completed in the first two years and operate the plant for the second two years with a variety or ores, coals, and fluxes. Campaigns of increasing length are planned to optimize operations. After successful operation, the plant will be taken over by the host company. Results of studies to date indicate that, on a commercial scale, the AISI process will use 27% less energy and have variable operating costs $10 per ton lower and capital costs of $160 per annual ton, compared to the $250 per annual ton rebuild cost for the coke oven-blast furnace process it will replace. The process will enable the domestic steel industry to become more competitive by reducing its capital and operating cost. Furthermore, by eliminating the pollution problems associated with coke production and by completely enclosing the smelting reactions, this process represents a major step towards an environmentally friendly steel industry.

  16. Coals and coal requirements for the COREX process

    SciTech Connect (OSTI)

    Heckmann, H. [Deutsche Voest-Alpine Industrieanlagenbau GmbH, Duesseldorf (Germany)

    1996-12-31T23:59:59.000Z

    The utilization of non met coals for production of liquid hot metal was the motivation for the development of the COREX Process by VAI/DVAI during the 70`s. Like the conventional ironmaking route (coke oven/blast furnace) it is based on coal as source of energy and reduction medium. However, in difference to blast furnace, coal can be used directly without the necessary prestep of cokemaking. Coking ability of coals therefore is no prerequisite of suitability. Meanwhile the COREX Process is on its way to become established in ironmaking industry. COREX Plants at ISCOR, Pretoria/South Africa and POSCO Pohang/Korea, being in operation and those which will be started up during the next years comprise already an annual coal consumption capacity of approx. 5 Mio. tonnes mtr., which is a magnitude attracting the interest of industrial coal suppliers. The increasing importance of COREX as a comparable new technology forms also a demand for information regarding process requirements for raw material, especially coal, which is intended to be met here.

  17. Co-production of electricity and alternate fuels from coal. Final report, August 1995

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The Calderon process and its process development unit, PDU, were originally conceived to produce two useful products from a bituminous coal: a desulfurized medium BTU gas containing primarily CO, H{sub 2}, CH{sub 4}, CO{sub 2}, and H{sub 2}O; and a desulfurized low BTU gas containing these same constituents plus N{sub 2} from the air used to provide heat for the process through the combustion of a portion of the fuel. The process was viewed as a means for providing both a synthesis gas for liquid fuel production (perhaps CH{sub 3}OH, alternatively CH{sub 4} or NH{sub 3}) and a pressurized, low BTU fuel gas, for gas turbine based power generation. The Calderon coal process comprises three principle sections which perform the following functions: coal pyrolysis in a continuous, steady flow unit based on coke oven technology; air blown, slagging, coke gasification in a moving bed unit based on a blast furnace technology; and a novel, lime pebble based, product gas processing in which a variety of functions are accomplished including the cracking of hydrocarbons and the removal of sulfur, H{sub 2}S, and of particulates from both the medium and low BTU gases. The product gas processing unit, based on multiple moving beds, has also been conceived to regenerate the lime pebbles and recover sulfur as elemental S.

  18. Benefits of solvent extracted pitch in the densification of carbon-carbon composites

    SciTech Connect (OSTI)

    Baker, C.F. [Fiber Materials, Inc., Biddeford, ME (United States); Stiller, A.

    1994-12-31T23:59:59.000Z

    As new commercial/industrial applications for carbon-carbon develop, it is necessary to adjust the matrix to the needs of the application, and reduce the cost of carbon-carbon. In addition, the environmental impact of current pitch production has resulted in the closing of coke ovens, and the loss of sources of raw material. To over come these problems, a new source of pitch is being developed utilizing a unique process involving the solvent extraction of coal. This process, developed at West Virginia University, has resulted in a number of pitch materials which are currently undergoing studies to determine the feasibility of their use in carbon-carbon composites. Work to date has centered on comparison of the microstructure of coked samples of the new pitches with those of currently used coal tar and petroleum pitches. Because of the ability to vary process parameters, it is possible to very closely replicate the microstructure of a typical carbon-carbon composites using solvent extracted pitch. Additional work will completely characterize the new materials to ensure they have similar properties as currently used pitches. Future work will alter and improve the properties of solvent extracted pitch to produce composites with special properties and at lower cost.

  19. Addendum to industrial market assessment of the products of mild gasification

    SciTech Connect (OSTI)

    Not Available

    1992-05-01T23:59:59.000Z

    The objective of this report is to review and update the 1988 report by J. E. Sinor Consultants Inc., Industrial Market Assessment of the Products of Mild Gasification, and to more fully present market opportunities for two char-based products from the mild gasification process (MGP): Formcoke for the iron and steel industry, and activated carbon for wastewater cleanup and flue gas scrubbing. Please refer to the original report for additional details. In the past, coal conversion projects have and liquids produced, and the value of the residual char was limited to its fuel value. Some projects had limited success until gas and oil competition overwhelmed them. The strategy adopted for this assessment is to seek first a premium value for the char in a market that has advantages over gas and oil, and then to find the highest values possible for gases, liquids, and tars, either on-site or sold into existing markets. During the intervening years since the 1988 report, there have been many changes in the national economy, industrial production, international competition, and environmental regulations. The Clean Air Act Amendments of 1990 (CAAA) will have a large impact on industry. There is considerable uncertainty about how the Act will be implemented, but it specifically addresses coke-oven batteries. This may encourage industry to consider formcoke produced via mild gasification as a low-pollution substitute for conventional coke. The chemistry and technology of coke making steel were reviewed in the 1988 market assessment and will not be repeated here. The CAAA require additional pollution control measures for most industrial facilities, but this creates new opportunities for the mild gasification process.

  20. Addendum to industrial market assessment of the products of mild gasification

    SciTech Connect (OSTI)

    Not Available

    1992-05-01T23:59:59.000Z

    The objective of this report is to review and update the 1988 report by J. E. Sinor Consultants Inc., ``Industrial Market Assessment of the Products of Mild Gasification, and to more fully present market opportunities for two char-based products from the mild gasification process (MGP): Formcoke for the iron and steel industry, and activated carbon for wastewater cleanup and flue gas scrubbing. Please refer to the original report for additional details. In the past, coal conversion projects have and liquids produced, and the value of the residual char was limited to its fuel value. Some projects had limited success until gas and oil competition overwhelmed them. The strategy adopted for this assessment is to seek first a premium value for the char in a market that has advantages over gas and oil, and then to find the highest values possible for gases, liquids, and tars, either on-site or sold into existing markets. During the intervening years since the 1988 report, there have been many changes in the national economy, industrial production, international competition, and environmental regulations. The Clean Air Act Amendments of 1990 (CAAA) will have a large impact on industry. There is considerable uncertainty about how the Act will be implemented, but it specifically addresses coke-oven batteries. This may encourage industry to consider formcoke produced via mild gasification as a low-pollution substitute for conventional coke. The chemistry and technology of coke making steel were reviewed in the 1988 market assessment and will not be repeated here. The CAAA require additional pollution control measures for most industrial facilities, but this creates new opportunities for the mild gasification process.