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  1. Suntechnics Belgium | Open Energy Information

    Open Energy Info (EERE)

    Belgium Place: Belgium Sector: Solar Product: Belgian manufacturer and installer of solar thermal heating systems. Also sells and installs PV panels and heat pumps....

  2. CS Chang

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CS Chang CS Chang FES Requirements Worksheet 1.1. Project Information - Center for Plasma Edge Simulation Document Prepared By CS Chang Project Title Center for Plasma Edge...

  3. Belgium | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    are pleased to announce that they have jointly completed the removal of a significant amount of excess highly enriched uranium (HEU) and separated plutonium from Belgium. At

  4. CS Chang

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CS Chang CS Chang FES Requirements Worksheet 1.1. Project Information - Center for Plasma Edge Simulation Document Prepared By CS Chang Project Title Center for Plasma Edge Simulation Principal Investigator CS Chang Participating Organizations New York University, ORNL, PPPL, LBNL, MIT, Columbia U., Rutgers U. Lehigh U., Georgia Tech, Auburn U., U. Colorado, U. California at Irvine, Caltech, Hinton Associates Funding Agencies DOE SC DOE NSA NSF NOAA NIH Other: 2. Project Summary & Scientific

  5. CS Frontend

    Energy Science and Technology Software Center (OSTI)

    2013-01-07

    CS Frontend is a data acquisition frontend software that interfaces to the open source software MIDAS, to read information from VME modules and transfer it to the MIDAS logger.

  6. Brussels, Belgium: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Sustainable Energy Ventures References http:www.geonames.org2800866brussels.html Retrieved from "http:en.openei.orgwindex.php?titleBrussels,Belgium&oldid266529...

  7. Belgium

    National Nuclear Security Administration (NNSA)

    that required the joint team to develop a new glovebox facility for plutonium packaging, to train and certify personnel in specialized packaging operations, to validate...

  8. Belgium's Red Electrical Devils Win $1 Million for Innovative...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Belgium's Red Electrical Devils Win 1 Million for Innovative Inverter Design NREL ... Google and IEEE announced today that Belgium's Red Electrical Devils, a team from CE+T ...

  9. Belgium: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    the existing buildings in Belgium, the potential roof surface that can be used to install solar panel equals around 250 km.Wind EnergyOver the last decade, onshore wind capacity...

  10. CS267: NERSC Discussion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computers Discussion CS267: NERSC Discussion This area is intended for NERSC users and staff to help each other with questions about CS267. Last edited: 2011-05-19 11:55:08...

  11. SF6432-CS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with the Directorate of Defense Trade Control : SF 6432-CS Title: Standard Terms and Conditions for Commercial Services Owner: Procurement Policy Department Release Date: 04...

  12. SF6432-CS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... prior to any attempts to enter a government site as shown ... premises are subject to search. (e) Contractor shall ... SF 6432-CS Title: Standard Terms and Conditions for ...

  13. SF6432-CS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... SF 6432-CS Title: Standard Terms and Conditions for ... Any Contractor personnel who will enter a government site to ... premises are subject to search. (e) Contractor shall ...

  14. Belgium Highly Enriched Uranium and Plutonium Removals | National...

    National Nuclear Security Administration (NNSA)

    Uranium and Plutonium Removals March 24, 2014 Belgium has been a global leader in nonproliferation, working with the United States since 2006 to minimize highly enriched uranium ...

  15. Costa Rica: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Country Profile Name Costa Rica Population 4,586,353 GDP 52,968,000,000 Energy Consumption 0.20 Quadrillion Btu 2-letter ISO code CR 3-letter ISO code CRI Numeric ISO...

  16. Port Costa, California: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Port Costa is a census-designated place in Contra Costa County, California.1 References...

  17. SF6432-CS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11/17/15 Page 1 of 20 Printed copies of this document are uncontrolled. Retrieve latest version electronically. SANDIA CORPORATION SF 6432-CS (11/2015) SECTION II STANDARD TERMS AND CONDITIONS FOR COMMERCIAL SERVICES THE FOLLOWING CLAUSES APPLY TO THIS CONTRACT AS INDICATED UNLESS SPECIFICALLY DELETED, OR EXCEPT TO THE EXTENT THEY ARE SPECIFICALLY SUPPLEMENTED OR AMENDED IN WRITING IN THE COVER PAGE OR SECTION I. (CTRL+CLICK ON A LINK BELOW TO ADVANCE DIRECTLY TO THAT SECTION) ACCEPTANCE OF

  18. Belgium Nuclear Security Summit: Fact Sheet | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration | (NNSA) Nuclear Security Summit: Fact Sheet March 27, 2012 As one of the leaders in nuclear technology development, Belgium's nuclear program has covered all aspects of nuclear fuel cycle including reprocessing and operated a reprocessing plant between 1966 and 1974. Belgium signed the NPT in 1975 as a non-weapons state, but has retained a leading nuclear technology research center and derives over 50% of its energy from nuclear power using 7 power reactors. SCK-CEN is one of

  19. SF6432-CS Commercial Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with the Directorate of Defense Trade Control : SF 6432-CS Title: Standard Terms and Conditions for Commercial Services Owner: Procurement Policy & Quality Dept Release Date:...

  20. CAES MaCS Home

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cross-cutting capabilities that support the Center for Advanced Energy Studies' (CAES) mission in multiple initiative areas. MaCS is largely made possible through its...

  1. SF6432-CS Commercial Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... SF 6432-CS Title: Standard Terms and Conditions for ... Any Contractor personnel who will enter a government site to ... premises are subject to search. (e) Contractor will ...

  2. Holographic Embedding de Teramond, Guy F.; /Costa Rica U.; Dosch...

    Office of Scientific and Technical Information (OSTI)

    Baryon Spectrum from Superconformal Quantum Mechanics and its Light-Front Holographic Embedding de Teramond, Guy F.; Costa Rica U.; Dosch, Hans Gunter; U. Heidelberg, ITP;...

  3. Costa Rica-Mitigation of Greenhouse Gas Emissions through Avoided...

    Open Energy Info (EERE)

    Value Areas AgencyCompany Organization Government of Costa Rica, Peace with Nature Sector Land Focus Area Forestry Topics Co-benefits assessment, Implementation,...

  4. Costa Rica-UNEP Risoe Technology Needs Assessment Program | Open...

    Open Energy Info (EERE)

    UNEP Risoe Technology Needs Assessment Program Jump to: navigation, search Name Costa Rica-UNEP Risoe-Technology Needs Assessment Program AgencyCompany Organization UNEP-Risoe...

  5. Costa Rica-EU-UNDP Climate Change Capacity Building Program ...

    Open Energy Info (EERE)

    EU-UNDP Climate Change Capacity Building Program Jump to: navigation, search Name Costa Rica-EU-UNDP Climate Change Capacity Building Program AgencyCompany Organization The...

  6. Contra Costa County, California: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    Energy Companies in Contra Costa County, California BEW Engineering Banyan Energy Bay Biodiesel LLC Bio Friendly Fuel Partners LLC Cogent Energy EcoNexus Synergy Conscious...

  7. Costa Mesa, California: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    district.12 Registered Energy Companies in Costa Mesa, California Ceradyne Inc EPS Corp Energy and Power Solutions MGE UPS SYSTEMS Inc Registered Financial Organizations...

  8. Fuel Tax Incidence in Developing Countries: The Case of Costa...

    Open Energy Info (EERE)

    Conventional Energy Topics Finance, Market analysis, Background analysis Resource Type Lessons learnedbest practices Website http:www.rff.orgRFFDocumen Country Costa Rica...

  9. Costa Rica-NREL Energy Activities | Open Energy Information

    Open Energy Info (EERE)

    Costa-Rica NREL Cooperation AgencyCompany Organization National Renewable Energy Laboratory Sector Energy Focus Area Energy Efficiency Topics Background analysis Website http:...

  10. CRAD, NNSA- Criticality Safety (CS)

    Broader source: Energy.gov [DOE]

    CRAD for Criticality Safety (CS). Criteria Review and Approach Documents (CRADs) that can be used to conduct a well-organized and thorough assessment of elements of safety and health programs.

  11. CS2SAT Desktop Tool

    Energy Science and Technology Software Center (OSTI)

    2006-03-15

    The Idaho National Laboratory (INL) has developed a Control System Cyber Security Self-Assessment Tool (CS2SAT) desktop tool that provides a repeatable and systematic approach for control system users to assess the cyber security posture of their control system networks. The tool assists users in identifying the cyber security parameters of their systems and then offers security objectives, in the form of requirements, for improving the security of their specific network. Each requirement is linked tomore » a series of associated recommendations for compliance dependent upon the desired level of security protection. Each requirement is supported by links to the original standards document and recommendations are supported by links to whitepapers and other help documents. Package also includes two back-end supporting codes: CS2SAT Requirements Matrix and Control System Security Information System.« less

  12. Potential value of Cs-137 capsules

    SciTech Connect (OSTI)

    Bloomster, C.H.; Brown, D.R.; Bruno, G.A.; Hazelton, R.F.; Hendrickson, P.L.; Lezberg, A.J.; Tingey, G.L.; Wilfert, G.L.

    1985-04-01

    We determined the value of Cs-137 compared to Co-60 as a source for the irradiation of fruit (apples and cherries), pork and medical supplies. Cs-137, in the WESF capsule form, had a value of approximately $0.40/Ci as a substitute for Co-60 priced at approximately $1.00/Ci. The comparison was based on the available curies emitted from the surface of each capsule. We developed preliminary designs for fourteen irradiation facilities; seven were based on Co-60 and seven were based on Cs-137. These designs provided the basis for estimating capital and operating costs which, in turn, provided the basis for determining the value of Cs-137 relative to Co-60 in these applications. We evaluated the effect of the size of the irradiation facility on the value of Cs-137. The cost of irradiation is low compared to the value of the product. Irradiation of apples for disinfestation costs $.01 to .02 per pound. Irradiation for trichina-safe pork costs $.02 per pound. Irradiation of medical supplies for sterilization costs $.07 to .12 per pound. The cost of the irradiation source, either Co-60 or Cs-137, contributed only a minor amount to the total cost of irradiation, about 5% for the fruit and hog cases and about 20% for the medical supply cases. We analyzed the sensitivity of the irradiation costs and Cs-137 value to several key assumptions.

  13. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Workforce Development Record of Categorical Exclusion (CS) Determination, Office of ... Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and ...

  14. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): American ... Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and ...

  15. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and ... Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and ...

  16. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Interoperability Standards and Framework (EISA 1305) Record of Categorical Exclusion (CS) ... PDF icon Record of Categorical Exclusion (CS) Determination, Office of Electricity ...

  17. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Smart Grid Investment Grant Program (EISA 1306) Record of Categorical Exclusion (CS) ... PDF icon Record of Categorical Exclusion (CS) Determination, Office of Electricity ...

  18. Fast CsI-phoswich detector

    DOE Patents [OSTI]

    Langenbrunner, James R.

    1996-01-01

    An improved phoswich radiation detector used pure CsI crystal and a fast plastic scintillator and a single photomultiplier tube. The plastic is arranged to receive incident radiation, and that which passed through then strikes the CsI crystal. Scintillation light from both the plastic and CsI crystal are applied to the photomultiplier tube, with the light from the plastic passing through the crystal without absorption therein. Electronics are provided for analyzing the output of the photomultiplier tube to discriminate responses due to the plastic and the CsI crystal, through short gate and long gate integration, to produce results which are indicative of the characteristics of the different types of incident radiation, even in the presence of large amounts of radiation. The phoswich detector has excellent timing resolution. The scintillators of the CsI- phoswich were chosen for their fast risetimes, of about 3 ns for NE102A, and 30 ns for the pure CsI.

  19. Fast CsI-phoswich detector

    DOE Patents [OSTI]

    Langenbrunner, J.R.

    1996-05-07

    An improved phoswich radiation detector used pure CsI crystal and a fast plastic scintillator and a single photomultiplier tube. The plastic is arranged to receive incident radiation, and that which passed through then strikes the CsI crystal. Scintillation light from both the plastic and CsI crystal are applied to the photomultiplier tube, with the light from the plastic passing through the crystal without absorption therein. Electronics are provided for analyzing the output of the photomultiplier tube to discriminate responses due to the plastic and the CsI crystal, through short gate and long gate integration, to produce results which are indicative of the characteristics of the different types of incident radiation, even in the presence of large amounts of radiation. The phoswich detector has excellent timing resolution. The scintillators of the CsI- phoswich were chosen for their fast risetimes, of about 3 ns for NE102A, and 30 ns for the pure CsI. 5 figs.

  20. Low level detection of Cs-135 and Cs-137 in environmental samples...

    Office of Scientific and Technical Information (OSTI)

    The measurement of the fission product cesium isotopes 135Cs and ... by high sensitivity ICP-MS analysis. A high efficiency desolvating nebulizer system was employed to maximize ...

  1. 4 Questions for a Better Buildings Case Competition Judge: Marc Costa of the Energy Coalition

    Broader source: Energy.gov [DOE]

    Meet Marc Costa of The Energy Coalition and find out how the Better Buildings Case Competition can serve as a recruiting tool for energy organizations.

  2. Alameda-Contra Costa Transit District (AC Transit) Fuel Cell Transit Buses: Third Evaluation Report

    Broader source: Energy.gov [DOE]

    This report describes operations at Alameda-Contra Costa Transit district for three protoype fuel cell buses and six diesel buses operating from the same location.

  3. Alameda-Contra Costa Transit District (AC Transit) Fuel Cell Transit Buses: Third Evaluation Report- Appendices

    Broader source: Energy.gov [DOE]

    This report describes operations at Alameda-Contra Costa Transit district for three protoype fuel cell buses and six diesel buses operating from the same location.

  4. Alameda-Contra Costa Transit District Fuel Cell Transit Buses: Evalluation Results Update

    Broader source: Energy.gov [DOE]

    This report is an update to the 2007 preliminary results report on hydrogen fuel cell and diesel buses operating at Alameda-Contra Costa Transit District.

  5. (Findings of the Costa Rica power sector efficiency study)

    SciTech Connect (OSTI)

    Waddle, D.B.

    1990-10-08

    To present findings of the Costa Rica Power Sector Efficiency Study to the Instituto Costarricense de Electridad, and to the Ministry of Energy, Natural Resources and Mining. To discuss the progress and plans for the Central American Rural Electrification Project with US Agency for International Development (USAID)/Regional Office Central American Program (ROCAP). I traveled to San Jose, Costa Rica to present the findings of the Costa Rica Power Sector Efficiency Study to our counterparts in the utility and the Ministry of Energy. Discussions were held with line level managers at Instituto Costarricensede Electricidad (ICE) and Ministry of Energy Mines and Natural Resources (MIRENEM), as well as a plan of action set for the final stage of the project. Discussions were held for a one day period with both the bilateral Agency for International Development (AID) and the regional AID mission regarding the need for a similar study in Guatemala and matters directly pertaining to the Central American Rural Electrification Study (CARES) project.

  6. 135Cs/137Cs isotopic composition of environmental samples across Europe: Environmental transport and source term emission applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Snow, Mathew S.; Snyder, Darin C.

    2015-11-02

    135Cs/137Cs isotopic analyses represent an important tool for studying the fate and transport of radiocesium in the environment; in this work the 135Cs/137Cs isotopic composition in environmental samples taken from across Europe is reported. Surface soil and vegetation samples from western Russia, Ukraine, Austria, and Hungary show consistent aged thermal fission product 135Cs/137Cs isotope ratios of 0.58 ± 0.01 (age corrected to 1/1/15), with the exception of one sample of soil-moss from Hungary which shows an elevated 135Cs/137Cs ratio of 1.78 ± 0.12. With the exception of the outlier sample from Hungary, surface soil/vegetation data are in quantitative agreement withmore » values previously reported for soils within the Chernobyl exclusion zone, suggesting that radiocesium at these locations is primarily composed of homogenous airborne deposition from Chernobyl. Seawater samples taken from the Irish Sea show 135Cs/137Cs isotope ratios of 1.22 ± 0.11 (age corrected to 1/1/15), suggesting aged thermal fission product Cs discharged from Sellafield. Furthermore, the differences in 135Cs/137Cs isotope ratios between Sellafield, Chernobyl, and global nuclear weapons testing fallout indicate that 135Cs/137Cs isotope ratios can be utilized to discriminate between and track radiocesium transport from different nuclear production source terms, including major emission sources in Europe.« less

  7. Properties of CsI and CsI-TMAE photocathodes

    SciTech Connect (OSTI)

    Anderson, D.F.; Kwan, S.; Peskov, V.; Hoeneisen, B.

    1992-06-01

    The importance of heating the CsI or CsI-TMAE photocathodes during preparation, as well as the importance of the gas environment on the quantum efficiency is presented. The dependence of the aging characteristics of these photocathodes on the operating temperature, on the presence of gas, and on the charge amplification of the chamber is also discussed. For CsI photocathodes charges in excess of 2{times}10{sup 14} e{sup {minus}}/mm{sup 2} can be collected with little degradation of performance. A timing resolution of 0.55 ns is also achieved for single photoelectrons suggesting a possible time-of-flight detector.

  8. In situ 7Li and 133Cs NMR Investigations of the Role of Cs+ Additive in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium-Metal Deposition Processes - Joint Center for Energy Storage Research February 1, 2016, Research Highlights In situ 7Li and 133Cs NMR Investigations of the Role of Cs+ Additive in Lithium-Metal Deposition Processes In situ 7Li NMR spectra from live Li-metal batteries with and without Cs+ additives. At discharge voltage point "C," more microstructured lithium (260 ppm) is recharged back onto the opposite Li electrode to form smoothly deposited Li-metal structures (248 ppm)

  9. IR-Improved DGLAP-CS Theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ward, B. F. L.

    2008-01-01

    We show that it is possible to improve the infrared aspects of the standard treatment of the DGLAP-CS evolution theory to take into account a large class of higher-order corrections that significantly improve the precision of the theory for any given level of fixed-order calculation of its respective kernels. We illustrate the size of the effects we resum using the moments of the parton distributions.

  10. The radiation chemistry of Cs-7SB, a solvent modifier used in Cs and Sr extraction

    SciTech Connect (OSTI)

    Mincher, B.J.; Martin, L.R.; Elias, G.; Mezyk, S.P.

    2008-07-01

    The solvent modifier 1-(2,2,3,3-tetrafluoro-propoxy)-3-(4-sec-butylphenoxy)-2-propanol, (Cs- 7SB) is used in conjunction with calixarenes and crown ethers dissolved in alkane diluents for the extraction of Cs and Sr from highly radioactive solutions. Its purpose is to solvate the ligands and the resulting ligand-metal complexes in the organic phase. Given this role, and its relatively high concentration in the formulations used for solvent extraction, radiolytic degradation of Cs-7SB might decrease the extraction efficiency of these elements as the solvent accumulates absorbed radiation dose. This work presents the results of studies of Cs-7SB using post-radiolysis gas chromatography with electron-capture detection and solvent-extraction distribution-ratio measurements. Also presented is the kinetic analysis of the bimolecular rate constant for the modifier's reaction with nitrogen trioxide and nitrogen dioxide radicals, major radiolytically-produced radical species in irradiated aqueous nitric acid. Although Cs-7SB was found to undergo reactions with nitrogen-centered radicals, little decrease in extraction efficiency was found. It is concluded the modifier, always present at concentrations much higher than the ligands, acts as a radical scavenger, protecting ligands from radiolytic attack. (authors)

  11. Alameda-Contra Costa Transit District (AC Transit) Fuel Cell Transit Buses: Third Evaluation Report and Appendices

    SciTech Connect (OSTI)

    Chandler, K.; Eudy, L.

    2008-07-01

    This report describes operations at Alameda-Contra Costa Transit district for three protoype fuel cell buses and six diesel buses operating from the same location.

  12. Microbial Electrochemical Technology (MxCs): Challenges and Opportunities |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Electrochemical Technology (MxCs): Challenges and Opportunities Microbial Electrochemical Technology (MxCs): Challenges and Opportunities Presentation by Jason Ren, University of Colorado Boulder, during the "Technological State of the Art" panel at the Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop held March 18-19, 2015. Microbial Electrochemical Technology (MxCs): Challenges and Opportunities (2.69 MB) More Documents &

  13. Microbial Fuel Cell Technologies--MxCs: Can They Scale?

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Technol. 29 30 Conclusions * Microbial Fuel Cell Technologies-- MxCs: Can they scale? Yes 30 MET Companies * Emefcy (Israel) , www.emefcy.com * Cambrian Innovations (Boston, ...

  14. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-363 Noble Americas Gas & Power Corporation Record of Categorical Exclusion (CS) Determination, ...

  15. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PP-366 Twin Rivers Paper Company, Inc. Record of Categorical Exclusion (CS) Determination, ... Record of Categorical Exclusion PDF icon PP-366 Twin Rivers Paper Company, Inc. More ...

  16. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    StateRegionalLocal Assistance for Interconnection Transmission Planning and Ana Record ... PDF icon Record of Categorical Exclusion (CS) Determination, Office of Electricity ...

  17. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Marketing LP Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-368 Brookfield Energy Marketing LP Record of ...

  18. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Noble Americas Gas & Power Corporation Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-365 Centre Land Trading

  19. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EDF Trading North America, LLC (EDF) Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-365 Centre Land Trading

  20. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EA-365 Centre Land Trading Limited Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-365 Centre Land Trading ...

  1. SF6432-CS (02-01-12) Commercial Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... prior to any attempts to enter a government site as shown ... premises are subject to search. (e) Contractor will ... SF 6432-CS Title: Standard Terms and Conditions for ...

  2. Record of Categorical Exclusion (CS) Determination, Office of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    North America, LLC (EDF) Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-367 EDF Trading North America, LLC (EDF) ...

  3. Microbial Electrochemical Technology (MxCs): Challenges and Opportunit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Microbial Electrolysis Cells (MECs) for High Yield Hydrogen (H2) Production from Biodegradable Materials Microbial Fuel Cell Technologies-MxCs: Can ...

  4. Possibility of transmutation of {sup 135}Cs by ultraintense laser

    SciTech Connect (OSTI)

    Takashima, R.; Hasegawa, S.; Nemoto, K.; Kato, K.

    2005-01-03

    The possibility of photo-transmutation of long-lived nuclide {sup 135}Cs by ultrashort ultraintense laser was analytically evaluated. The yield of {sup 135}Cs({gamma},n) {sup 134}Cs was strongly dependent on the laser intensity at around 10{sup 20} W/cm{sup 2}. If {sup 135}Cs were irradiated by such a laser with the intensity of 10{sup 21} W/cm{sup 2} and 10 Hz for 30 min, characteristic {gamma}-ray counting rate was estimated to be 3 Bq.

  5. CS-Studio Scan System Parallelization

    SciTech Connect (OSTI)

    Kasemir, Kay; Pearson, Matthew R

    2015-01-01

    For several years, the Control System Studio (CS-Studio) Scan System has successfully automated the operation of beam lines at the Oak Ridge National Laboratory (ORNL) High Flux Isotope Reactor (HFIR) and Spallation Neutron Source (SNS). As it is applied to additional beam lines, we need to support simultaneous adjustments of temperatures or motor positions. While this can be implemented via virtual motors or similar logic inside the Experimental Physics and Industrial Control System (EPICS) Input/Output Controllers (IOCs), doing so requires a priori knowledge of experimenters requirements. By adding support for the parallel control of multiple process variables (PVs) to the Scan System, we can better support ad hoc automation of experiments that benefit from such simultaneous PV adjustments.

  6. Hydro and geothermal electricity as an alternative for industrial petroleum consumption in Costa Rica

    SciTech Connect (OSTI)

    Mendis, M.; Park, W.; Sabadell, A.; Talib, A.

    1982-04-01

    This report assesses the potential for substitution of electricity for petroleum in the industrial/agro-industrial sector of Costa Rica. The study includes a preliminary estimate of the process energy needs in this sector, a survey of the principal petroleum consuming industries in Costa Rica, an assessment of the electrical technologies appropriate for substitution, and an analysis of the cost trade offs of alternative fuels and technologies. The report summarizes the total substitution potential both by technical feasibility and by cost effectiveness under varying fuel price scenarios and identifies major institutional constraints to the introduction of electric based technologies. Recommendations to the Government of Costa Rica are presented. The key to the success of a Costa Rican program for substitution of electricity for petroleum in industry rests in energy pricing policy. The report shows that if Costa Rica Bunker C prices are increased to compare equitably with Caribbean Bunker C prices, and increase at 3 percent per annum relative to a special industrial electricity rate structure, the entire substitution program, including both industrial and national electric investment, would be cost effective. The definition of these pricing structures and their potential impacts need to be assessed in depth.

  7. Synthesis of economic criteria in the design of electric utility industrial conservation programs in Costa Rica

    SciTech Connect (OSTI)

    Fisher, S.C.

    1995-12-31

    This paper lays out a set of economic criteria to guide the development of electricity conservation programs for industrial customers of the Costa Rican utilities. It puts the problem of utility and other public policy formulation in the industrial conservation field into the context of ongoing economic and trade liberalization in Costa Rica, as well as the financial and political pressures with which the country`s utilities must contend. The need to bolster utility financial performance and the perennial political difficulty of adjusting power rates for inflation and devaluation, not to mention maintaining efficient real levels, puts a premium on controlling the costs of utility conservation programs and increasing the degree of cost recovery over time. Industrial conservation programs in Costa Rica must adopt a certain degree of activation to help overcome serious market failures and imperfections while at the same time avoiding significant distortion of the price signals guiding the ongoing industrial rationalization process and the reactivation of growth.

  8. EnergyCS Inc Energy Control Systems Engineering Inc | Open Energy...

    Open Energy Info (EERE)

    EnergyCS Inc Energy Control Systems Engineering Inc Jump to: navigation, search Name: EnergyCS Inc (Energy Control Systems Engineering, Inc) Sector: Services Product: String...

  9. ESI_CS_Zirkle 1.6.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    more information about BPA ESI: Visit www.energysmartindustrial.com or contact your local utility provider. LIT ESI-CS-006-1 REV DATE 2012-11-14 ZIRKLE FRUIT energy efficiency...

  10. Solvent Extraction of Tc and Cs from Alkaline Nitrate Wastes

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Bonnesen, Peter V.; Delmau, Laetitia H.; Haverlock, T J.; Sachleben, R A.; Leonard, R A.; Conner, C; Lumetta, Gregg J. ); M. Cox, M. Hidalgo, and M. Valiente

    2001-01-01

    This paper summarizes progress at three collaborating U.S. national laboratories on the extraction of the fission products 99Tc and 137Cs from alkaline high-level wastes. Efficient economical processes for Tc and Cs extraction (SRTALK and alkaline-side CSEX, respectively) have been developed, and testing has progressed through batch tests on actual wastes and continuous counter-current centrifugal-contactor tests on simulants.

  11. Solvent Extraction of Tc and Cs from Alkaline Nitrate Wastes

    SciTech Connect (OSTI)

    Bonnesen, P.V.; Conner, C.; Delmau, L.H.; Haverlock, T.J.; Leonard, R.A.; Lumetta, G.J.; Moyer, B.A.; Sachleben, R.A.

    1999-07-11

    This paper summarizes progress at three collaborating US national laboratories on the extraction of the fission products {sup 99}Tc and {sup 137}Cs from alkaline high-level wastes (HLW). Efficient, economical processes for Tc and Cs extraction (SRTALK and alkaline-side CSEX, respectively) have been developed, and testing has progressed through batch tests on actual wastes and continuous countercurrent centrifugal-contactor tests on simulants.

  12. Record of Categorical Exclusion (CS) Determination, Office of Electricity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Smart Grid Investment Grant Program (EISA 1306) | Department of Energy CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Smart Grid Investment Grant Program (EISA 1306) Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): American Recovery and

  13. Microbial cleavage of organic C-S bonds

    DOE Patents [OSTI]

    Kilbane, II, John J.

    1994-01-01

    A microbial process for selective cleavage of organic C--S bonds which may be used for reducing the sulfur content of sulfur-containing organic carbonaceous materials, Microorganisms of Rhodococcus rhodochrous and Bacillus sphaericus have been found which have the ability of selective cleavage of organic C--S bonds. Particularly preferred microorganisms are Rhodococcus rhodochrous strain ATCC 53968 and Bacillus sphaericus strain ATCC 53969 and their derivatives.

  14. Microbial cleavage of organic C-S bonds

    DOE Patents [OSTI]

    Kilbane, J.J. II.

    1994-10-25

    A microbial process is described for selective cleavage of organic C-S bonds which may be used for reducing the sulfur content of sulfur-containing organic carbonaceous materials. Microorganisms of Rhodococcus rhodochrous and Bacillus sphaericus have been found which have the ability of selective cleavage of organic C-S bonds. Particularly preferred microorganisms are Rhodococcus rhodochrous strain ATCC 53968 and Bacillus sphaericus strain ATCC 53969 and their derivatives.

  15. The third-generation turbocharged engine for the Audi 5000 CS and 5000 CS Quattro

    SciTech Connect (OSTI)

    Stock, D.

    1986-01-01

    In September 1985 the new Audi 5000 CS Quattro was introduced to the American market. This luxurious high performance touring sedan has been equipped with a more advanced turbocharged engine with intercooler and electronic engine management giving improved performance, excellent torque, faster response and better fuel economy. The basic engine is the tried-and-tested Audi 5-cylinder unit. The turbocharged engine's ancillary systems, the electronic ignition control and fuel injection have all been newly developed, carefully optimized and well matched in the special demands of a turbocharged engine. The ignition system controls the engine and fuel injection and delivers analog and digital signals to the car's instrument panel display. The system also has an integrated self-diagnostic function.

  16. Role of excited state photoionization in the 852.1 nm Cs laser pumped by Cs-Ar photoassociation

    SciTech Connect (OSTI)

    Hewitt, J. D.; Houlahan, T. J. Jr.; Eden, J. G.; Gallagher, J. E.; Perram, G. P.; Carroll, D. L.; Palla, A. D.; Verdeyen, J. T.

    2013-03-18

    Photoionization of Cs (6p {sup 2}P{sub 3/2}) atoms during the operation of a Cs D{sub 2} line (852.1 nm: 6p {sup 2}P{sub 3/2}{yields}6s {sup 2}S{sub 1/2}) laser, pumped by free{yields}free transitions of thermal Cs-Ar ground state pairs, has been investigated experimentally and computationally. Photoexcitation of Cs vapor/Ar mixtures through the blue satellite of the D{sub 2} transition (peaking at 836.7 nm) selectively populates the {sup 2}P{sub 3/2} upper laser level by the dissociation of the CsAr excited complex. Comparison of laser output energy data, for instantaneous pump powers up to 3 MW, with the predictions of a numerical model sets an upper bound of 8 Multiplication-Sign 10{sup -26} cm{sup 4} W{sup -1} on the Cs (6p {sup 2}P{sub 3/2}) two photon ionization cross-section at 836.7 nm which corresponds to a single photon cross-section of 2.4 Multiplication-Sign 10{sup -19} cm{sup 2} for a peak pump intensity of 3 MW cm{sup -2}.

  17. Photoelectron Emission Studies in CsBr at 257 nm

    SciTech Connect (OSTI)

    Maldonado, Juan R.; Liu, Zhi; Sun, Yun; Pianetta, Piero A.; Pease, Fabian W.; /Stanford U., Elect. Eng. Dept. /SLAC, SSRL

    2006-09-28

    CsBr/Cr photocathodes were found [1,2] to meet the requirements of a multi-electron beam lithography system operating with a light energy of 4.8 eV (257nm). The fact that photoemission was observed with a light energy below the reported 7.3 eV band gap for CsBr was not understood. This paper presents experimental results on the presence of intra-band gap absorption sites (IBAS) in CsBr thin film photo electron emitters, and presents a model based on IBAS to explain the observed photoelectron emission behavior at energies below band gap. A fluorescence band centered at 330 nm with a FWHM of about 0.34 eV was observed in CsBr/Cr samples under 257 nm laser illumination which can be attributed to IBAS and agrees well with previously obtained synchrotron photoelectron spectra[1] from the valence band of CsBr films.

  18. Estimation of average burnup of damaged fuels loaded in Fukushima Dai-ichi reactors by using the {sup 134}Cs/{sup 137}Cs ratio method

    SciTech Connect (OSTI)

    Endo, T.; Sato, S.; Yamamoto, A.

    2012-07-01

    Average burnup of damaged fuels loaded in Fukushima Dai-ichi reactors is estimated, using the {sup 134}Cs/{sup 137}Cs ratio method for measured radioactivities of {sup 134}Cs and {sup 137}Cs in contaminated soils within the range of 100 km from the Fukushima Dai-ichi nuclear power plants. As a result, the measured {sup 134}Cs/{sup 137}Cs ratio from the contaminated soil is 0.996{+-}0.07 as of March 11, 2011. Based on the {sup 134}Cs/{sup 137}Cs ratio method, the estimated burnup of damaged fuels is approximately 17.2{+-}1.5 [GWd/tHM]. It is noted that the numerical results of various calculation codes (SRAC2006/PIJ, SCALE6.0/TRITON, and MVP-BURN) are almost the same evaluation values of {sup 134}Cs/ {sup 137}Cs ratio with same evaluated nuclear data library (ENDF-B/VII.0). The void fraction effect in depletion calculation has a major impact on {sup 134}Cs/{sup 137}Cs ratio compared with the differences between JENDL-4.0 and ENDF-B/VII.0. (authors)

  19. Additional requirements for leak-before-break application to primary coolant piping in Belgium

    SciTech Connect (OSTI)

    Roussel, G.

    1997-04-01

    Leak-Before-Break (LBB) technology has not been applied in the first design of the seven Pressurized Water Reactors the Belgian utility is currently operating. The design basis of these plants required to consider the dynamic effects associated with the ruptures to be postulated in the high energy piping. The application of the LBB technology to the existing plants has been recently approved by the Belgian Safety Authorities but with a limitation to the primary coolant loop. LBB analysis has been initiated for the Doel 3 and Tihange 2 plants to allow the withdrawal of some of the reactor coolant pump snubbers at both plants and not reinstall some of the restraints after steam generator replacement at Doel 3. LBB analysis was also found beneficial to demonstrate the acceptability of the primary components and piping to the new conditions resulting from power uprating and stretch-out operation. LBB analysis has been subsequently performed on the primary coolant loop of the Tihange I plant and is currently being performed for the Doel 4 plant. Application of the LBB to the primary coolant loop is based in Belgium on the U.S. Nuclear Regulatory Commission requirements. However the Belgian Safety Authorities required some additional analyses and put some restrictions on the benefits of the LBB analysis to maintain the global safety of the plant at a sufficient level. This paper develops the main steps of the safety evaluation performed by the Belgian Safety Authorities for accepting the application of the LBB technology to existing plants and summarizes the requirements asked for in addition to the U.S. Nuclear Regulatory Commission rules.

  20. 135Cs/137Cs isotopic composition of environmental samples across Europe: Environmental transport and source term emission applications

    SciTech Connect (OSTI)

    Snow, Mathew S.; Snyder, Darin C.

    2015-11-02

    135Cs/137Cs isotopic analyses represent an important tool for studying the fate and transport of radiocesium in the environment; in this work the 135Cs/137Cs isotopic composition in environmental samples taken from across Europe is reported. Surface soil and vegetation samples from western Russia, Ukraine, Austria, and Hungary show consistent aged thermal fission product 135Cs/137Cs isotope ratios of 0.58 ± 0.01 (age corrected to 1/1/15), with the exception of one sample of soil-moss from Hungary which shows an elevated 135Cs/137Cs ratio of 1.78 ± 0.12. With the exception of the outlier sample from Hungary, surface soil/vegetation data are in quantitative agreement with values previously reported for soils within the Chernobyl exclusion zone, suggesting that radiocesium at these locations is primarily composed of homogenous airborne deposition from Chernobyl. Seawater samples taken from the Irish Sea show 135Cs/137Cs isotope ratios of 1.22 ± 0.11 (age corrected to 1/1/15), suggesting aged thermal fission product Cs discharged from Sellafield. Furthermore, the differences in 135Cs/137Cs isotope ratios between Sellafield, Chernobyl, and global nuclear weapons testing fallout indicate that 135Cs/137Cs isotope ratios can be utilized to discriminate between and track radiocesium transport from different nuclear production source terms, including major emission sources in Europe.

  1. 137 Cs Activities and 135 Cs/ 137 Cs Isotopic Ratios from Soils at Idaho National Laboratory: A Case Study for Contaminant Source Attribution in the Vicinity of Nuclear Facilities

    SciTech Connect (OSTI)

    Snow, Mathew S.; Snyder, Darin C.; Clark, Sue B.; Kelley, Morgan; Delmore, James E.

    2015-03-03

    Radiometric and mass spectrometric analyses of Cs contamination in the environment can reveal the location of Cs emission sources, release mechanisms, modes of transport, prediction of future contamination migration, and attribution of contamination to specific generator(s) and/or process(es). The Subsurface Disposal Area (SDA) at Idaho National Laboratory (INL) represents a complicated case study for demonstrating the current capabilities and limitations to environmental Cs analyses. 137Cs distribution patterns, 135Cs/137Cs isotope ratios, known Cs chemistry at this site, and historical records enable narrowing the list of possible emission sources and release events to a single source and event, with the SDA identified as the emission source and flood transport of material from within Pit 9 and Trench 48 as the primary release event. These data combined allow refining the possible number of waste generators from dozens to a single generator, with INL on-site research and reactor programs identified as the most likely waste generator. A discussion on the ultimate limitations to the information that 135Cs/137Cs ratios alone can provide is presented and includes (1) uncertainties in the exact date of the fission event and (2) possibility of mixing between different Cs source terms (including nuclear weapons fallout and a source of interest).

  2. Characterization of Interlayer Cs+ in Clay Samples Using Secondary Ion Mass Spectrometry with Laser Sample Modification

    SciTech Connect (OSTI)

    G. S. Groenewold; R. Avci; C. Karahan; K. Lefebre; R. V. Fox; M. M. Cortez; A. K. Gianotto; J. Sunner; W. L. Manner

    2004-04-01

    Ultraviolet laser irradiation was used to greatly enhance the secondary ion mass spectrometry (SIMS) detection of Cs+ adsorbed to soil consisting of clay and quartz. Imaging SIMS showed that the enhancement of the Cs+ signal was spatially heterogeneous: the intensity of the Cs+ peak was increased by factors up to 100 for some particles but not at all for others. Analysis of standard clay samples exposed to Cs+ showed a variable response to laser irradiation depending on the type of clay analyzed. The Cs+ abundance was significantly enhanced when Cs+-exposed montmorillonite was irradiated and then analyzed using SIMS, which contrasted with the behavior of Cs+-exposed kaolinite, which displayed no Cs+ enhancement. Exposed illitic clays displayed modest enhancement of Cs+ upon laser irradiation, intermediate between that of kaolinite and montmorillonite. The results for Cs+ were rationalized in terms of adsorption to interlayer sites within the montmorillonite, which is an expandable phyllosilicate. In these locations, Cs+ was not initially detectable using SIMS. Upon irradiation, Cs+ was thermally redistributed, which enabled detection using SIMS. Since neither the illite nor the kaolinite is an expandable clay, adsorption to inner-layer sites does not occur, and either modest or no laser enhancement of the Cs+ signal is observed. Laser irradiation also produced unexpected enhancement of Ti+ from illite and kaolinite clays that contained small quantities of Ti, which indicates the presence of microscopic titanium oxide phases in the clay materials.

  3. Structure and Interactions of the CS Domain of Human H/ACA RNP...

    Office of Scientific and Technical Information (OSTI)

    Structure and Interactions of the CS Domain of Human HACA RNP Assembly Protein Shq1 Citation Details In-Document Search Title: Structure and Interactions of the CS Domain of Human...

  4. Lattice dynamics in perovskite halides CsSn X 3 with X = I ,...

    Office of Scientific and Technical Information (OSTI)

    Lattice dynamics in perovskite halides CsSn X 3 with X I , Br , Cl Prev Next Title: Lattice dynamics in perovskite halides CsSn X 3 with X I , Br , Cl Authors: Huang, ...

  5. Lattice dynamics in perovskite halides CsSn X 3 with X = I ,...

    Office of Scientific and Technical Information (OSTI)

    Lattice dynamics in perovskite halides CsSn X 3 with X I , Br , Cl Citation Details In-Document Search Title: Lattice dynamics in perovskite halides CsSn X 3 with X I , Br , Cl ...

  6. Economic characteristics of the peat deposits of Costa Rica: preliminary study

    SciTech Connect (OSTI)

    Cohen, A.D. Malavassi, L.; Raymond, R. Jr.; Mora, S.; Alverado, A.

    1985-01-01

    Recent field and laboratory studies have established the presence of numerous extensive peat deposits in Costa Rica. Three of these were selected for initial investigation: (1) the cloud-forest histosols of the Talamanca Mountain Range; (2) the Rio Medio Queso flood plain deposits near the northern Costa Rican border; and (3) a tropical jungle swamp deposit on the northeastern coastal plain. In the Talamanca area, 29 samples were collected from eight sites. Due to the high moisture and cool temperatures of the cloud forest, the peats in this area form blanket-like deposits (generally <1 meter thick) over a wide area (>150 km/sup 2/). These peats are all highly decomposed (avg. 28% fiber), high in ash (avg. 21%), and extensively bioturbated. Relative to all other sites visited, these peats are lowest in moisture (avg. 84%), pH (avg. 4.4), fixed carbon (avg. 23%), and sulfur (avg. 0.2%). However, they have the highest bulk densities (avg. 0.22 g/cc), volatile matter contents (avg. 55%), and nitrogen. Their heating value averaged 7700 BTUs/lb., dry. In the Rio Medio Queso area, 28 samples were collected, representing one transect of the 70 km/sup 2/ flood plain. The peats here occurred in several layers (each <1-1/2 meters thick), interfingering with river flood plain sediments. These peats have the highest calorific values (avg. 8000 BTUs/lb., dry), fixed carbon (avg. 30%), and ash (avg. 22%) and have an average pH of 5.4 and a bulk density of 0.20 g/cc. These results represent only the first part of a long-term, extensive survey of Costa Rica's peat resources. However, they suggest that large, economically-significant peat deposits may be present in this country. 5 refs., 8 figs., 4 tabs.

  7. Record of Categorical Exclusion (CS) Determination, Office of Electricity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Interoperability Standards and Framework (EISA 1305) | Department of Energy Interoperability Standards and Framework (EISA 1305) Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Interoperability Standards and Framework (EISA 1305) Based on OE's review of the information

  8. Record of Categorical Exclusion (CS) Determination, Office of Electricity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Program Direction | Department of Energy Program Direction Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Program Direction Based on OE's review of the information concerning the proposal action, the NEPA compliance Officer has determined that the proposed action fits

  9. Record of Categorical Exclusion (CS) Determination, Office of Electricity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Smart Grid Investment Grant Program (EISA 1306) | Department of Energy Smart Grid Investment Grant Program (EISA 1306) Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Smart Grid Investment Grant Program (EISA 1306) Based on OE's review of the information concerning the

  10. Record of Categorical Exclusion (CS) Determination, Office of Electricity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Smart Grid Investment Grant Program (EISA 1306) | Department of Energy Smart Grid Investment Grant Program (EISA 1306) Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Smart Grid Investment Grant Program (EISA 1306) Based on OE's review of the information concerning the

  11. Record of Categorical Exclusion (CS) Determination, Office of Electricity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) State/Regional/Local Assistance for Interconnection Transmission Planning and Ana | Department of Energy State/Regional/Local Assistance for Interconnection Transmission Planning and Ana Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) State/Regional/Local Assistance for

  12. Record of Categorical Exclusion (CS) Determination, Office of Electricity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Workforce Development | Department of Energy Workforce Development Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): American Recovery and Reinvestment Act of 2009 (Recovery Act) Workforce Development Based on OE's review of the information concerning the proposal action, the NEPA compliance Officer has determined that the proposed

  13. Duration Test Report for the Viryd CS8 Wind Turbine

    SciTech Connect (OSTI)

    Roadman, J.; Murphy, M.; van Dam, J.

    2013-06-01

    This report summarizes the results of a duration noise test that the National Renewable Energy Laboratory (NREL) conducted on the Viryd CS8 wind turbine. This test was conducted in accordance with Clause 9.4 of the International Electrotechnical Commission's (IEC) standard, Wind turbines - Part 2: Design requirements for small wind turbines, IEC 61400-2 Ed. 2.0:2006-03. NREL researchers evaluated the turbine based on structural integrity and material degradation, quality of environmental protection, and dynamic behavior.

  14. HPC_AppPerf_2013_CS267.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Performance Debugging Techniques For HPC Applications David Skinner deskinner@lbl.gov CS267 Feb 19 2013 Today's Topics * Principles - Topics in performance scalability - Examples of areas where tools can help * Practice - Where to find tools - Specifics to NERSC and Hopper/Franklin * Scope & Audience - Budding simulation scientist app dev - Compiler/middleware dev, YMMV 2 Overview * Serving all of DOE Office of Science domain breadth range of scales * Lots of users ~4.5K active ~500 logged

  15. High gradient rf gun studies of CsBr photocathodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vecchione, Theodore; Maldonado, Juan R.; Gierman, Stephen; Corbett, Jeff; Hartmann, Nick; Pianetta, Piero A.; Hesselink, Lambertus; Schmerge, John F.

    2015-04-03

    CsBr photocathodes have 10 times higher quantum efficiency with only 3 times larger intrinsic transverse emittance than copper. They are robust and can withstand 80 MV/m fields without breaking down or emitting dark current. They can operate in 2×10⁻⁹ torr vacuum and survive exposure to air. They are well suited for generating high pulse charge in rf guns without a photocathode transfer system.

  16. High gradient rf gun studies of CsBr photocathodes

    SciTech Connect (OSTI)

    Vecchione, Theodore; Maldonado, Juan R.; Gierman, Stephen; Corbett, Jeff; Hartmann, Nick; Pianetta, Piero A.; Hesselink, Lambertus; Schmerge, John F.

    2015-04-03

    CsBr photocathodes have 10 times higher quantum efficiency with only 3 times larger intrinsic transverse emittance than copper. They are robust and can withstand 80 MV/m fields without breaking down or emitting dark current. They can operate in 210?? torr vacuum and survive exposure to air. They are well suited for generating high pulse charge in rf guns without a photocathode transfer system.

  17. Quantum spin transport through magnetic superatom dimer (Cs{sub 8}V-Cs{sub 8}V)

    SciTech Connect (OSTI)

    Zhu Lin; Khanna, Shiv N.

    2012-10-28

    Theoretical studies of the spin transport through a magnetic superatom dimer (Cs{sub 8}V)-(Cs{sub 8}V) have been carried out within a density functional theory combined with nonequilibrium Green's-function formalism. It is shown that the electronic transport is sensitive to the binding site as well as the contact distance between the dimer and the electrode, and that the conductance at zero bias exhibits an oscillatory behavior as a function of the contact distance. The conductance in ferromagnetic state shows an unusually high spin polarization that exceeds 80% at large separations. The I-V curve shows negative differential resistance for specific contact distances, whose origin lies in the shift of frontier energy levels as well as the charged state of the superatom, under external bias.

  18. Estimating the greenhouse gas benefits of forestry projects: A Costa Rican Case Study

    SciTech Connect (OSTI)

    Busch, Christopher; Sathaye, Jayant; Sanchez Azofeifa, G. Arturo

    2000-09-01

    If the Clean Development Mechanism proposed under the Kyoto Protocol is to serve as an effective means for combating global climate change, it will depend upon reliable estimates of greenhouse gas benefits. This paper sketches the theoretical basis for estimating the greenhouse gas benefits of forestry projects and suggests lessons learned based on a case study of Costa Rica's Protected Areas Project, which is a 500,000 hectare effort to reduce deforestation and enhance reforestation. The Protected Areas Project in many senses advances the state of the art for Clean Development Mechanism-type forestry projects, as does the third-party verification work of SGS International Certification Services on the project. Nonetheless, sensitivity analysis shows that carbon benefit estimates for the project vary widely based on the imputed deforestation rate in the baseline scenario, e.g. the deforestation rate expected if the project were not implemented. This, along with a newly available national dataset that confirms other research showing a slower rate of deforestation in Costa Rica, suggests that the use of the 1979--1992 forest cover data originally as the basis for estimating carbon savings should be reconsidered. When the newly available data is substituted, carbon savings amount to 8.9 Mt (million tones) of carbon, down from the original estimate of 15.7 Mt. The primary general conclusion is that project developers should give more attention to the forecasting land use and land cover change scenarios underlying estimates of greenhouse gas benefits.

  19. Continuous Nondemolition Measurement of the Cs Clock Transition Pseudospin

    SciTech Connect (OSTI)

    Chaudhury, Souma; Smith, Greg A.; Schulz, Kevin; Jessen, Poul S.

    2006-02-03

    We demonstrate a weak continuous measurement of the pseudospin associated with the clock transition in a sample of Cs atoms. Our scheme uses an optical probe tuned near the D{sub 1} transition to measure the sample birefringence, which depends on the z component of the collective pseudospin. At certain probe frequencies the differential light shift of the clock states vanishes, and the measurement is nonperturbing. In dense samples the measurement can be used to squeeze the collective clock pseudospin and has the potential to improve the performance of atomic clocks and interferometers.

  20. Chemical information on tank supernatants, Cs adsorption from tank liquids onto Hanford sediments, and field observations of Cs migration from past tank leaks

    SciTech Connect (OSTI)

    Serne, R.J.; Zachara, J.M.; Burke, D.S.

    1998-01-01

    Borehole gamma-logging profiles beneath the SX-Tank Farm suggest that contamination from Cs-137 extends to at least a depth of 40 m (130 ft), and may extend even deeper. What is presently not known is the pathway that Cs-137 has taken to reach these depths. In this report we provide an analysis of the chemistry of tank supernates with emphasis on the REDOX waste stream disposed in SX tanks, Cs chemistry in aqueous solutions and adsorption properties onto minerals, available data on Cs adsorption onto Hanford sediments, and information on Cs migration from other Hanford tank leaks that have been studied. The data in this report was used to help guide the vadose zone transport analysis of the SX Tank Farm presented in a companion report. The goal of the vadose zone transport modelling is to attempt to explain the depth and extent of the Cs-137 plume under the SX Tank farm, specifically in the vicinity of the greatest leak, near the SX-109 Tank as inferred from the gamma logs (DOE 1996). In solution Cs is present as the monovalent cation and shows very little tendency to form aqueous complexes with inorganic or organic ligands. Cs is expected to adsorb primarily onto selective minerals that have unique adsorption sites. The small Cs{sup +} ion is accommodated on these frayed edge and interlayer sites. Adsorption within the interlayers often leads to collapse of the layers such that the Cs{sup +} ion is effectively trapped and not readily exchangeable by all other common cations. The degree of adsorption is thus only moderately dependent on the types and high concentrations of other cations in leaking tank liquors.

  1. Build an oven, cook a meal: How solar energy empowered women in Costa Rica

    SciTech Connect (OSTI)

    Blankenship, J. )

    1990-12-01

    A pilot solar cooking project in the hot, northern province of Guanacaste promises to serve as a model for community groups wanting to build their own solar ovens. An $8,000 (US) grant has been awarded by the Canadian Embassy in Costa Rica to take the Guanacaste project into a second stage in 1990-91. Two construction workshops, with twelve participants in each, are planned in communities near Oriente. Three women from the Oriente group will have paid jobs as organizational facilitators and workshop supervisors. In popular education this is called the multiplier effect - the users of solar cookers construct the ovens themselves, and then instruct others to do the same. 3 refs.

  2. Photoinduced Br Desorption from CsBr Thin Films Grown on Cu(100)

    SciTech Connect (OSTI)

    Halliday, Matthew T.; Joly, Alan G.; Hess, Wayne P.; Shluger, AL

    2015-10-22

    Thin films of CsBr deposited onto metals such as copper are potential photocathode materials for light sources and other applications. We investigate desorption dynamics of Br atoms from CsBr films grown on insulator (KBr, LiF) and metal (Cu) substrates induced by sub-bandgap 6.4 eV laser pulses. The experimental results demonstrate that the peak kinetic energy of Br atoms desorbed from CsBr/Cu films is much lower than that for the hyperthermal desorption from CsBr/LiF films. Kelvin probe measurements indicate negative charge at the surface following Br desorption from CsBr/Cu films. Our ab initio calculations of excitons at CsBr surfaces demonstrate that this behavior can be explained by an exciton model of desorption including electron trapping at the CsBr surface. Trapped negative charges reduce the energy of surface excitons available for Br desorption. We examine the electron-trapping characteristics of low-coordinated sites at the surface, in particular, divacancies and kink sites. We also provide a model of cation desorption caused by Franck-Hertz excitation of F centers at the surface in the course of irradiation of CsBr/Cu films. These results provide new insights into the mechanisms of photoinduced structural evolution of alkali halide films on metal substrates and activation of metal photocathodes coated with CsBr.

  3. Half metallic ferromagnetism in alkali metal nitrides MN (M = Rb, Cs): A first principles study

    SciTech Connect (OSTI)

    Murugan, A. Rajeswarapalanichamy, R. Santhosh, M. Sudhapriyanga, G.; Kanagaprabha, S.

    2014-04-24

    The structural, electronic and elastic properties of two alkali metal nitrides (MN: M= Rb, Cs) are investigated by the first principles calculations based on density functional theory using the Vienna ab-initio simulation package. At ambient pressure the two nitrides are stable in ferromagnetic state with CsCl structure. The calculated lattice parameters are in good agreement with the available results. The electronic structure reveals that these materials are half metallic in nature. A pressure-induced structural phase transition from CsCl to ZB phase is observed in RbN and CsN.

  4. The Dependence of the Oxidation Enhancement of InP(100) Surface on the Coverage of the Adsorbed Cs

    SciTech Connect (OSTI)

    Sun, Yun

    2010-06-07

    We report the oxidation of the InP(100) surface promoted by adsorbed Cs by synchrotron radiation photoemission. Oxygen exposure causes reduction of the charge transferred to the InP substrate from Cs and the growth of indium oxide and phosphorous oxide. The oxide growth displays a clear dependence on the Cs coverage. The oxidation of phosphorous is negligible up to 1000 L of O{sub 2} exposure when the Cs coverage is less than half a monolayer (ML), but the formation of the second half monolayer of Cs greatly accelerates the oxidation. This different enhancement of the InP oxidation by the first and the second half monolayer of Cs is due to the double layer structure of the adsorbed Cs atoms, and consequently the higher 6s electron density in the Cs atoms when Cs coverage is larger than 0.5 ML.

  5. Technical memo on new results on CsI photocathodes: Enhancement and aging

    SciTech Connect (OSTI)

    Anderson, D.F.; Kwan, S. ); Hoeneisen, B. ); Peskov, V. . World Lab.)

    1991-09-01

    It appears that there are 4 processes involved in the enhancement and aging of a CsI or CsI-TMAE photocathode: water absorption, charging up of the photocathode, a self annealing aging, and a permanent aging. The evidence for these processes are presented. 9 refs., 6 figs.

  6. Temporal resolution limit estimation of x-ray streak cameras using a CsI photocathode

    SciTech Connect (OSTI)

    Li, Xiang; Gu, Li; Zong, Fangke; Zhang, Jingjin; Yang, Qinlao

    2015-08-28

    A Monte Carlo model is developed and implemented to calculate the characteristics of x-ray induced secondary electron (SE) emission from a CsI photocathode used in an x-ray streak camera. Time distributions of emitted SEs are investigated with an incident x-ray energy range from 1 to 30 keV and a CsI thickness range from 100 to 1000 nm. Simulation results indicate that SE time distribution curves have little dependence on the incident x-ray energy and CsI thickness. The calculated time dispersion within the CsI photocathode is about 70 fs, which should be the temporal resolution limit of x-ray streak cameras that use CsI as the photocathode material.

  7. Hanford Isotope Project strategic business analysis Cesium-137 (Cs-137)

    SciTech Connect (OSTI)

    1995-10-01

    The purpose of this business analysis is to address the beneficial reuse of Cesium 137 (Cs-137) in order to utilize a valuable national asset and possibly save millions of tax dollars. Food irradiation is the front runner application along with other uses. This business analysis supports the objectives of the Department of Energy National Isotope Strategy distributed in August 1994 which describes the DOE plans for the production and distribution of isotope products and services. As part of the Department`s mission as stated in that document. ``The Department of Energy will also continue to produce and distribute other radioisotopes and enriched stable isotopes for medical diagnostics and therapeutics, industrial, agricultural, and other useful applications on a businesslike basis. This is consistent with the goals and objectives of the National Performance Review. The Department will endeavor to look at opportunities for private sector to co-fund or invest in new ventures. Also, the Department will seek to divest from ventures that can more profitably or reliably be operated by the private sector.``

  8. Cost comparison between private and public collection of residual household waste: Multiple case studies in the Flemish region of Belgium

    SciTech Connect (OSTI)

    Jacobsen, R.; Buysse, J.; Gellynck, X.

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer The goal is to compare collection costs for residual household waste. Black-Right-Pointing-Pointer We have clustered all municipalities in order to find mutual comparable pairs. Black-Right-Pointing-Pointer Each pair consists of one private and one public operating waste collection program. Black-Right-Pointing-Pointer All cases show that private service has lower costs than public service. Black-Right-Pointing-Pointer Municipalities were contacted to identify the deeper causes for the waste management program. - Abstract: The rising pressure in terms of cost efficiency on public services pushes governments to transfer part of those services to the private sector. A trend towards more privatizing can be noticed in the collection of municipal household waste. This paper reports the findings of a research project aiming to compare the cost between the service of private and public collection of residual household waste. Multiple case studies of municipalities about the Flemish region of Belgium were conducted. Data concerning the year 2009 were gathered through in-depth interviews in 2010. In total 12 municipalities were investigated, divided into three mutual comparable pairs with a weekly and three mutual comparable pairs with a fortnightly residual waste collection. The results give a rough indication that in all cases the cost of private service is lower than public service in the collection of household waste. Albeit that there is an interest in establishing whether there are differences in the costs and service levels between public and private waste collection services, there are clear difficulties in establishing comparisons that can be made without having to rely on a large number of assumptions and corrections. However, given the cost difference, it remains the responsibility of the municipalities to decide upon the service they offer their citizens, regardless the cost efficiency: public or private.

  9. Preliminary reservoir engineering studies of the Miravalles geothermal field, Costa Rica

    SciTech Connect (OSTI)

    Haukwa, C.; Bodvarsson, G.S.; Lippmann, M.J.; Mainieri, A.

    1992-01-01

    The Earth Sciences Division of Lawrence Berkeley Laboratory in cooperation with the Instituto Costarricense de Electricidad is conducting a reservoir engineering study of the Miravalles geothermal field, Costa Rica. Using data from eight exploration wells, a two-dimensional areal, natural-state model of Miravalles has been developed. The model was calibrated by fitting the observed temperature and pressure distributions and requires a geothermal upflow zone in the northern part of the field, associated with the Miravalles volcano and an outflow towards the south. The total hot (about 260 C) water recharge is 130 kg/s, corresponding to a thermal input of about 150 MWt. On the basis of the natural-state model a two-dimensional exploitation model was developed. The field has a production area of about 10 km{sup 2}, with temperatures exceeding 220 C. The model indicated that power generation of 55 MWe can be maintained for 30 years, with or without injection of the separated geothermal brine. Generation of 110 MWe could be problematic. Until more information becomes available on the areal extent of the field and the properties of the reservoir rocks, especially their relative permeability characteristics, it is difficult to ascertain if 110 MWe can be sustained during a 30-year period.

  10. Separation of CsCl from a Ternary CsCl-LiCl-KCl Salt via a Melt Crystallization Technique for Pyroprocessing Waste Minimization

    SciTech Connect (OSTI)

    Ammon Williams; Supathorn Phongikaroon; Michael Simpson

    2013-02-01

    A parametric study has been conducted to identify the effects of several parameters on the separation of CsCl from molten LiCl-KCl salt via a melt crystallization process. A reverse vertical Bridgman technique was used to grow the salt crystals. The investigated parameters were: (1) the advancement rate, (2) the crucible lid configuration, (3) the amount of salt mixture, (4) the initial composition of CsCl, and (5) the temperature difference between the high and low furnace zones. From each grown crystal, samples were taken axially and analyzed using inductively coupled plasma mass spectrometry (ICP-MS). Results show that CsCl concentrations at the top of the crystals were low and increased to a maximum at the bottom of the salt. Salt (LiCl-KCl) recycle percentages for the experiments ranged from 50% to 75% and the CsCl composition in the waste salt was low. To increase the recycle percentage and the concentration of CsCl in the waste form, the possibility of using multiple crystallization stages was explored to further optimize the process. Results show that multiple crystallization stages are practical and the optimal experimental conditions should be operated at 5.0 mm/hr rate with a lid configuration and temperature difference of 200 C for a total of five crystallization stages. Under these conditions, up to 88% of the salt can be recycled.

  11. Management options for implementing a basic and applied research program responsive to CS technology base needs. Task VIII. Review existing CS materials R and D programs

    SciTech Connect (OSTI)

    Not Available

    1980-02-28

    Possibilities for setting up a basic and applied research program that would be responsive to the Conservation and Solar energy base needs are considered with emphasis on the area of materials research. Several organizational arrangements for the implementation of this basic and applied research program are described and analyzed. The key functions of the system such as resources allocation, and program coordination and management follow from two fundamental characteristics: assignment of lead responsibility (CS and the Office of Energy Research, ER); and nature of the organizational chain-of-command. Three options are categorized in terms of these two characteristics and discussed in detail. The first option retains lead responsibility in ER, with CS personnel exercising sign-off authority and filling the coordination role. Option 2 places lead responsibility with CS program office management, and utilizes the existing chain-of-command, but adds a Basic and Applied Research Division to each program office. Option 3 also places lead responsibility with CS, but within a new Office of Basic and Applied Research, which would include a Research Coordinator to manage interactions with ER, and Research Managers for each CS program area. (MCW)

  12. Microstructure and Cs Behavior of Ba-Doped Aluminosilicate Pollucite Irradiated with F+ Ions

    SciTech Connect (OSTI)

    Jiang, Weilin; Kovarik, Libor; Zhu, Zihua; Varga, Tamas; Engelhard, Mark H.; Bowden, Mark E.; Nenoff, Tina M.; Garino, Terry

    2014-08-07

    Radionuclide 137Cs is one of the major fission products that dominate heat generation in spent fuels over the first 300 hundred years. A durable waste form for 137Cs that decays to 137Ba is needed to minimize its environmental impact. Aluminosilicate pollucite CsAlSi2O6 is selected as a model waste form to study the decay-induced structural effects. While Ba-containing precipitates are not present in charge-balanced Cs0.9Ba0.05AlSi2O6, they are found in Cs0.9Ba0.1AlSi2O6 and identified as monoclinic Ba2Si3O8. Pollucite is susceptible to electron irradiation induced amorphization. The threshold density of the electronic energy deposition for amorphization is determined to be ~235 keV/nm3. Pollucite can be readily amorphized under F+ ion irradiation at 673 K. A significant amount of Cs diffusion and release from the amorphized pollucite is observed during the irradiation. However, cesium is immobile in the crystalline structure under He+ ion irradiation at room temperature. The critical temperature for amorphization is not higher than 873 K under F+ ion irradiation. If kept at or above 873 K all the time, the pollucite structure is unlikely to be amorphized; Cs diffusion and release are improbable. A general discussion regarding pollucite as a potential waste form is provided in this report.

  13. Performance Study of K2CsSb Photocathode inside a DC High Voltage Gun

    SciTech Connect (OSTI)

    T. Rao, J. Smedley, J.M. Grames, R. Mammei, J.L. McCarter, M. Poelker, R. Suleiman

    2011-03-01

    In the past decade, there has been considerable interest in the generation of tens of mA average current in a photoinjector. Until recently, GaAs:Cs cathodes and K2CsSb cathodes have been tested successfully in DC and RF injectors respectively for this application. Our goal is to test the GaAs:Cs in RF injector and the K2CsSb cathode in the DC gun in order to widen our choices. Since the multialkali cathode is a compound with uniform stochiometry over its entire thickness, we anticipate that the life time issues seen in GaAs:Cs due surface damage by ion bombardment would be minimized with this material. Hence successful operation of the K2CsSb cathode in DC gun could lead to a relatively robust electron source capable of delivering ampere level currents. In order to test the performance of K2CsSb cathode in a DC gun, we have designed and built a load lock system that would allow the fabrication of the cathode at BNL and its testing at JLab. In this paper, we will present the design of the load-lock system, cathode fabrication, and the cathode performance in the preparation chamber and in the DC gun.

  14. Performance Study of K2CsSb Photocathode Inside a DC High Voltage Gun

    SciTech Connect (OSTI)

    McCarter J. L.; Rao T.; Smedley, J.; Grames, J.; Mammei, R.; Poelker, M.; Suleiman, R.

    2011-09-01

    In the past decade, there has been considerable interest in the generation of tens of mA average current in a photoinjector. Until recently, GaAs:Cs cathodes and K{sub 2}CsSb cathodes have been tested successfully in DC and RF injectors respectively for this application. Our goal is to test the K{sub 2}CsSb photocathode inside a DC gun. Since the multialkali cathode is a compound with constant characteristics over its entire thickness, we anticipate that the lifetime issues seen in GaAs:Cs due to surface damage by ion bombardment would be minimized. Hence successful operation of the K{sub 2}CsSb cathode in a DC gun could lead to a relatively robust electron source capable of delivering ampere level currents. In order to test the performance of a K{sub 2}CsSb cathode in a DC gun, we have designed and built a load lock system that allows the fabrication of the cathode at Brookhaven National Lab (BNL) and its testing at Jefferson Lab (JLab). In this paper, we will present the performance of the K{sub 2}CsSb photocathode in the preparation chamber and in the DC gun.

  15. Crystal chemistry peculiarities of Cs{sub 2}Te{sub 4}O{sub 12}

    SciTech Connect (OSTI)

    Hamani, David; Mirgorodsky, Andrei; Masson, Olivier; Merle-Mejean, Therese; Colas, Maggy; Smirnov, Mikhael; Thomas, Philippe

    2011-03-15

    The Raman and IR-absorption spectra of the Cs{sub 2}Te{sub 4}O{sub 12} lattice are first recorded and interpreted. Extraordinary features observed in the structure and Raman spectra of Cs{sub 2}Te{sub 4}O{sub 12} are analyzed by using ab initio and lattice-dynamical model calculations. This compound is specified as a caesium-tellurium tellurate Cs{sub 2}Te{sup IV}(Te{sup VI}O{sub 4}){sub 3} in which Te{sup IV} atoms transfer their 5p electrons to [Te{sup VI}O{sub 4}]{sub 3}{sup 6-} tellurate anions, thus fulfilling (jointly with Cs atoms) the role of cations. The Te{sup VI}-O-Te{sup VI} bridge vibration Raman intensity is found abnormally weak, which is reproduced by model treatment including the Cs{sup +} ion polarizability properties in consideration. -- Graphical abstract: Two versions of the BPM estimations of the Raman intensity for the Cs{sub 2}Te{sub 4}O{sub 12} lattice vibrations: (a) without including effects of the Cs-O bonds and (b) including the above mentioned effects. Experimentally observed peaks are characterized by their frequency positions. Display Omitted Research highlights: > Extraordinary features observed in the structure and Raman spectra of Cs{sub 2}Te{sub 4}O{sub 12}. > Ab initio and lattice-dynamical model calculations. > Abnormally weak Raman intensities of the symmetric Te{sup VI}-O-Te{sup VI} bridge. > The monovalent Cs{sup +} cations profoundly influence the polarizability properties.

  16. CsBi4Te6: A High-Performance Thermoelectric Material for Low...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    thermoelectric properties of CsBi(4)Te(6) appear to match or exceed those of Bi(2-x)Sb(x)Te(3-y)Se(y) alloys. URL: Link to article - National Center for Biotechnology Information

  17. A comparison of {sup 137}Cs radioactivity in localized evergreen and deciduous plant species

    SciTech Connect (OSTI)

    Rangel, R.C.

    1996-05-01

    A vegetation study at the Comanche Peak Steam Electric Station (CPSES) near Glen Rose, Texas was conducted in 1991 and 1992. The CPSES is a commercial nuclear power plant owned and operated by Texas Utilities Electric of Dallas, Texas. The US Nuclear Regulatory Commission (USNRC) requires the CPSES to routinely sample broadleaf vegetation in place of milk samples. Few commercial dairies exist in the vicinity. Broadleaf tree species are scarce because the climate and local limestone geology have produced a dry rolling hill topography. An evergreen juniper is the dominant tree species. Few broadleaves during the winter season have hindered year-round sampling. This study compares the environmental {sup 137}Cs concentrations between broadleaf and evergreen foliage at CPSES. Soil {sup 137}Cs concentrations from each vegetation location were also compared to the foliage {sup 137}Cs concentrations. The study`s objective was to determine if the deciduous and evergreen vegetation {sup 137}Cs concentrations are statistically the same.

  18. Variations in the Retention and Excretion of {sup 137}Cs with Age and Sex

    SciTech Connect (OSTI)

    Boni, A.L.

    2001-08-29

    This report discusses the effects of age and sex on the retention and excretion of {sup 137}Cs in the body in a cross section of the general population over a four-year period.

  19. Useful for cleavage of organic C-S bonds Bacillus sphaericus microorganism

    DOE Patents [OSTI]

    Kilbane II, John J.

    1993-01-01

    A mutant Bacillus sphaericus strain ATCC No. 53969 which has the property of sulfur removal and sulfur metabolism by selective cleavage of C-S bonds in organic carbonaceous materials.

  20. Useful for cleavage of organic C-S bonds Bacillus sphaericus microorganism

    DOE Patents [OSTI]

    Kilbane, J.J. II.

    1993-03-30

    A mutant Bacillus sphaericus strain ATCC No. 53969 which has the property of sulfur removal and sulfur metabolism by selective cleavage of C-S bonds in organic carbonaceous materials.

  1. Mutant microorganisms useful for cleavage of organic C-S bonds

    DOE Patents [OSTI]

    Kilbane, II, John J.

    1991-01-01

    A mutant Bacillus sphaericus strain ATC No. 53969 which has the property of sulfur removal and sulfur metabolism by selective cleavage of C-S bonds in organic carbonaceous materials.

  2. Mutant microorganisms useful for cleavage of organic C-S bonds

    DOE Patents [OSTI]

    Kilbane, II, John J.

    1992-01-01

    A mutant Rhodococcus rhodochrous strain ATCC No. 53968 which has the property of sulfur removal and sulfur metabolism by selective cleavage of C-S bonds in organic carbonaceous materials.

  3. Fragmentation dynamics of CS22+ on collision with a self assembled...

    Office of Scientific and Technical Information (OSTI)

    Surface-induced dissociation of doubly charged CS22+ ions in collision with a self assembled monolayer surface of fluorinated alkyl thiol on gold 111 crystal has been studied on a ...

  4. Characterization of Cs vapor cell coated with octadecyltrichlorosilane using coherent population trapping spectroscopy

    SciTech Connect (OSTI)

    Hafiz, Moustafa Abdel; Maurice, Vincent; Chutani, Ravinder; Passilly, Nicolas; Gorecki, Christophe; Boudot, Rodolphe; Guérandel, Stéphane; Clercq, Emeric de

    2015-05-14

    We report the realization and characterization using coherent population trapping (CPT) spectroscopy of an octadecyltrichlorosilane (OTS)-coated centimeter-scale Cs vapor cell. The dual-structure of the resonance lineshape, with presence of a narrow structure line at the top of a Doppler-broadened structure, is clearly observed. The linewidth of the narrow resonance is compared to the linewidth of an evacuated Cs cell and of a buffer gas Cs cell of similar size. The Cs-OTS adsorption energy is measured to be (0.42 ± 0.03) eV, leading to a clock frequency shift rate of 2.7 × 10{sup −9}/K in fractional unit. A hyperfine population lifetime, T{sub 1}, and a microwave coherence lifetime, T{sub 2}, of 1.6 and 0.5 ms are reported, corresponding to about 37 and 12 useful bounces, respectively. Atomic-motion induced Ramsey narrowing of dark resonances is observed in Cs-OTS cells by reducing the optical beam diameter. Ramsey CPT fringes are detected using a pulsed CPT interrogation scheme. Potential applications of the Cs-OTS cell to the development of a vapor cell atomic clock are discussed.

  5. Conclusions and recommendations of the Latin America and Caribbean Regional Energy Conservation Seminar, Alajuela, Costa Rica, January 14-17, 1985

    SciTech Connect (OSTI)

    Not Available

    1985-03-29

    Reports were given on active energy-conservation projects in the region (Barbados, Jamaica, Central American region and Panama, Peru, Ecuador, the Dominican Republic, and Costa Rica). In addition, there were presentations on energy auditing, fuel substitution, and financing energy conservation. Although the seminar concentrated on the industrial sector, it also explored opportunities for energy-efficiency improvements in the building and transportation sectors.

  6. Bioaccumulation factor of {sup 137}Cs in some marine biotas from West Bangka Indonesia

    SciTech Connect (OSTI)

    Suseno, Heny

    2014-03-24

    Radionuclides may be released from nuclear facilities to the marine environment. Concentrations of radionuclides within marine biotic systems can be influenced by a number of factors, including the type of biota, its source, the radionuclide, and specific characteristics of the sampled specimens and the marine environment (salinity, etc.). The bioconcentration factor for a marine organism is the ratio of the concentration of a radionuclide in that organism to the concentration found in its marine water environment - under conditions of equilibrium. Information on the bioaccumulation of Cs-137 in marine organisms is required to risk assessment evaluates the potential risks to human health. Bioaccumulation of Cs was investigated in marine biota from west Bangka such as Marine cat fish (Arius thalassinus), Baramundi (Lates calcarifer), Mackerel (Scomberomorus commerson), Striped eel catfish (Plotosus lineatus), eel tailed fish (Euristhmus microceps), Yellowtail fusilier (Caesio erythrogaster), Coastal crab (Scylla sp), White shrimp (Penaeus merguiensis) and marine bivalve mollusk (Anadara granosa). Muscle of these marine biota, sediments and water were assayed for Cs-137 by HPGe gamma spectrometer. The bioaccumulation factor for fishes were calculated by ratio of concentration Cs-137 in muscle biota to the its concentration in water. The bioaccumulation factor for mollusks were calculates by ratio of concentration Cs-137 in muscle biota to the its concentration in sediments. The bioaccumulation factor were range 4.99 to 136.34.

  7. Statistical analysis of content of Cs-137 in soils in Bansko-Razlog region

    SciTech Connect (OSTI)

    Kobilarov, R. G.

    2014-11-18

    Statistical analysis of the data set consisting of the activity concentrations of {sup 137}Cs in soils in Bansko–Razlog region is carried out in order to establish the dependence of the deposition and the migration of {sup 137}Cs on the soil type. The descriptive statistics and the test of normality show that the data set have not normal distribution. Positively skewed distribution and possible outlying values of the activity of {sup 137}Cs in soils were observed. After reduction of the effects of outliers, the data set is divided into two parts, depending on the soil type. Test of normality of the two new data sets shows that they have a normal distribution. Ordinary kriging technique is used to characterize the spatial distribution of the activity of {sup 137}Cs over an area covering 40 km{sup 2} (whole Razlog valley). The result (a map of the spatial distribution of the activity concentration of {sup 137}Cs) can be used as a reference point for future studies on the assessment of radiological risk to the population and the erosion of soils in the study area.

  8. Porous Alumina Silicate Matrix Gubka for Solidification of {sup 137}Cs Strip Product

    SciTech Connect (OSTI)

    Aloy, Albert; Strelnikov, Alexander; Essimantovskiy, Vyacheslav

    2007-07-01

    Separated liquid high-level radioactive waste (HLW) fractions, in particular, about 100 liters of a {sup 137}Cs strip product with activity up to {approx} 100 Ci/l (3.7 TBq/l) have been produced during the development and testing of partitioning technology and temporarily stored at V.G. Khlopin Radium Institute (KRI) (Saint-Petersburg, Russia). The bench-scale experimental unit designed for operation in the hot cell was developed for {sup 137}Cs strip product solidification using an alumina silicate porous inorganic material (PIM) called Gubka. Conditions of saturation, drying, and calcinations of the salts into Gubka pores were optimized, and the operations under a remote control regime were executed during tests using a simulated strip product doped with {sup 137}Cs. The volume reduction coefficients were equal by a factor of 3.2-3.9 and a {sup 137}Cs discharge into an off-gas system was not detected. {sup 137}Cs leach rates from Gubka blocks after calcination at 800 deg. C were 1.0-1.5.10{sup -3} g/m{sup 2}.per day. (authors)

  9. Coupled Neutronics Thermal-Hydraulic Solution of a Full-Core PWR Using VERA-CS

    SciTech Connect (OSTI)

    Clarno, Kevin T; Palmtag, Scott; Davidson, Gregory G; Salko, Robert K; Evans, Thomas M; Turner, John A; Belcourt, Kenneth; Hooper, Russell; Schmidt, Rodney

    2014-01-01

    The Consortium for Advanced Simulation of Light Water Reactors (CASL) is developing a core simulator called VERA-CS to model operating PWR reactors with high resolution. This paper describes how the development of VERA-CS is being driven by a set of progression benchmark problems that specify the delivery of useful capability in discrete steps. As part of this development, this paper will describe the current capability of VERA-CS to perform a multiphysics simulation of an operating PWR at Hot Full Power (HFP) conditions using a set of existing computer codes coupled together in a novel method. Results for several single-assembly cases are shown that demonstrate coupling for different boron concentrations and power levels. Finally, high-resolution results are shown for a full-core PWR reactor modeled in quarter-symmetry.

  10. Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-361 Aquilon Power Limited

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE) for Aquilon Power Limited to export electric energy to Canada

  11. Hydrolysis of COS and CS{sub 2} over alumina catalysts at lower temperature

    SciTech Connect (OSTI)

    Shangguan Ju; Li Chunhu; Guo Hanxian [Taiyuan Univ. of Technology, Shanxi (China). Research Inst. of Chemical Engineering for Coal

    1997-12-31

    Carbonyl sulfide (COS) and carbon disulfide (CS{sub 2}) widely exist in chemical processing gases from natural gas, coal, Claus tail gas, and petroleum. Those sulfur compound are a major factor of deactivation of synthesis catalysts. Since it is difficult to remove COS and CS{sub 2} completely by the conventional desulfurization, a hydrolysis process has been developed in recent years. The activity of COS and CS{sub 2} hydrolysis was measured in a fixed bed reactor and the surface basicity was studied by CO{sub 2}-TPD. The results showed that the apparent reaction activation energies of COS over three catalysts are 57.80, 52.50 and 44.71 kJ/mol at lower temperature, and those of CS{sub 2}, 55.53, 38.70 and 35.30 kJ/mol, respectively. The apparent activation energies of desorption for weak type basic center over three catalysts were 25.97, 27.92 and 29.77kJ/mol respectively. The surface basicity on catalysts played an important role in the hydrolysis of COS and CS{sub 2}.The weak basic center was the catalytic active center of COS hydrolysis, while the weak and the weaker basic centers took part in catalytic reaction of CS{sub 2} hydrolysis. The K{sub 2}O and Pt loaded on active {gamma}-Al{sub 2}O{sub 3} could greatly change the distribution of surface basicity over catalysts and increase organic sulfide catalytic hydrolysis.

  12. Acoustic Noise Test Report for the Viryd CS8 Wind Turbine

    SciTech Connect (OSTI)

    Roadman, J.; Huskey, A.

    2013-07-01

    This report summarizes the results of an acoustic noise test that the National Renewable Energy Laboratory (NREL) conducted on the Viryd CS8 wind turbine. This test was conducted in accordance with the International Electrotechnical Commission's (IEC) standard, Wind Turbine Generator Systems Part 11: Acoustic Noise Measurement Techniques, IEC 61400-11 Ed.2.1, 2006-11. However, because the Viryd CS8 is a small turbine, as defined by IEC, NREL used 10-second averages instead of 60-second averages and binning by wind speed instead of regression analysis.

  13. {sup 137}Cs sorption into bentonite from Cidadap-Tasikmalaya as buffer material for disposal demonstration plant facility at Serpong

    SciTech Connect (OSTI)

    Setiawan, B. Sriwahyuni, H. Ekaningrum, NE. Sumantry, T.

    2014-03-24

    According to co-location principle, near surface disposal type the disposal demonstration plant facility will be build at Serpong nuclear area. The facility also for anticipation of future needs to provide national facility for the servicing of radwaste management of non-nuclear power plant activity in Serpong Nuclear Area. It is needs to study the material of buffer and backfill for the safety of demonstration plant facility. A local bentonite rock from Cidadap-Tasikmalaya was used as the buffer materials. Objective of experiment is to find out the specific data of sorption characteristic of Cidadap bentonite as buffer material in a radwaste disposal system. Experiments were performed in batch method, where bentonite samples were contacted with CsCl solution labeled with Cs-137 in 100 ml/g liquid:solid ratio. Initial Cs concentration was 10{sup −8} M and to study the effects of ionic strength and Cs concentration in solution, 0.1 and 1.0 M NaCl also CsCl concentration ranging 10{sup −8} - 10{sup −4} M were added in solution. As the indicator of Cs saturated in bentonite samples, Kd value was applied. Affected parameters in the experiment were contact time, effects of ionic strength and concentration of CsCl. Results showed that sorption of Cs by bentonite reached constantly after 16 days contacted, and Kd value was 10.600 ml/g. Effect of CsCl concentration on Kd value may decreased in increased in CsCl concentration. Effect of ionic strength increased according to increased in concentration of background and would effect to Kd value due to competition of Na ions and Cs in solution interacts with bentonite. By obtaining the bentonite character data as buffer material, the results could be used as the basis for making of design and the basic of performance assessment the near surface disposal facility in terms of isolation capacity of radwaste later.

  14. Photon-enhanced thermionic emission from p-GaAs with nonequilibrium Cs overlayers

    SciTech Connect (OSTI)

    Zhuravlev, A. G.; Romanov, A. S.; Alperovich, V. L.

    2014-12-22

    Photon-enhanced thermionic emission (PETE), which is promising for increasing the efficiency of solar energy conversion, is studied during cesium deposition on the As- and Ga-rich p-GaAs(001) surfaces and subsequent relaxation in the nonequilibrium Cs overlayer by means of photoemission quantum yield spectroscopy adapted for systems with time-variable parameters. Along with direct photoemission of hot electrons excited by light above the vacuum level, the spectra contain PETE contribution of thermalized electrons, which are excited below the vacuum level and emit in vacuum due to thermalization up in energy by phonon absorption. Comparing the measured and calculated spectra, the effective electron affinity and escape probabilities of hot and thermalized electrons are obtained as functions of submonolayer Cs coverage. The minima in the affinity and pronounced peaks in the escape probabilities are observed for Cs deposition on both the As- and Ga-rich surfaces. Possible reasons for the low mean values of the electron escape probabilities and for the observed enhancement of the probabilities at certain Cs coverages are discussed, along with the implications for the PETE device realization.

  15. Power Performance Test Report for the Viryd CS8 Wind Turbine

    SciTech Connect (OSTI)

    Roadman, J.; Murphy, M.; van Dam, J.

    2012-12-01

    This report contains the results of the power performance test that was performed on a Viryd CS8 wind turbine as part of the DOE Independent Testing project. The test is an accredited test to the IEC 61400-12-1 power performance standard.

  16. Estimation of SX Farm Vadose Zone CS-137 Inventories from Geostatistical Analysis of Drywell and Soil Core Data

    SciTech Connect (OSTI)

    KNEPP, A.J.

    2000-06-02

    This report provides an estimation of the Cs-137 inventories in the soil under the SX Tank Farm based on measurements obtained from drywell and soil cores. The Cs-137 inventories are estimated separately for distinct volumes of soil associated etc.

  17. Enviromental influences on the {sup 137}Cs kinetics of the yellow-bellied turtle (Trachemys Scripta)

    SciTech Connect (OSTI)

    Peters, E.L.; Brisbin, L.I. Jr.

    1996-02-01

    Assessments of ecological risk require accurate predictions of contaminant dynamics in natural populations. However, simple deterministic models that assume constant uptake rates and elimination fractions may compromise both their ecological realism and their general application to animals with variable metabolism or diets. In particular, the temperature-dependent model of metabolic rates characteristic of ectotherms may lead to significant differences between observed and predicted contaminant kinetics. We examined the influence of a seasonally variable thermal environment on predicting the uptake and annual cycling of contaminants by ectotherms, using a temperature-dependent model of {sup 137}Cs kinetics in free-living yellow-bellied turtles, Trachemys scripta. We compared predictions from this model with those of deterministics negative exponential and flexibly shaped Richards sigmoidal models. Concentrations of {sup 137}Cs in a population if this species in Pond B, a radionuclide-contaminated nuclear reactor cooling reservoir, and {sup 137}Cs uptake by the uncontaminated turtles held captive in Pond B for 4 yr confirmed both the pattern of uptake and the equilibrium concentrations predicted by the temperature-dependent model. Almost 90% of the variance on the predicted time-integrated {sup 137}Cs concentration was explainable by linear relationships with model paramaters. The model was also relatively insensitive to uncertainties in the estimates of ambient temperature, suggesting that adequate estimates of temperature-dependent ingestion and elimination may require relatively few measurements of ambient conditions at sites of interest. Analyses of Richards sigmoidal models of {sup 137}Cs uptake indicated significant differences from a negative exponential trajectory in the 1st yr after the turtles` release into Pond B. 76 refs., 7 figs., 5 tabs.

  18. International Symposium on Remote Sensing of Environment, 14th, San Jose, Costa Rica, April 23-30, 1980, Proceedings. Volumes 1, 2 and 3

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Papers are presented on remote sensing applications in resource monitoring and management, data classification and modeling procedures, and the use of remote sensing techniques in developing nations. The subjects of land use/land cover, soil mapping, crop identification, mapping of geological resources, renewable resource analysis, and oceanographic applications are discussed. Papers from Argentina, Bolivia, Brazil, Costa Rica, the Syrian Arab Republic, the People's Republic of China, the Phillipines, Italy, Upper Volta and the United States are included.

  19. Cs/sup +/ + Cs/sup +/ charge-transfer and ionization cross-section measurements by a plasma-target technique

    SciTech Connect (OSTI)

    Stalder, K.R.

    1982-05-01

    A Q machine plasma target using cesium was constructed to serve as a target for a beam of Cs/sup +/ ions. The sum of charge transfer and ionization cross sections was determined by measuring the growth of the Cs/sup + +/ component of the beam as a function of the plasma radial line density. The measured cross section varies approximately linearly with energy between 50 and 110 keV. This loss cross section is 0.47 +- .11 x 10/sup -16/ cm/sup 2/ at 110 keV. These results have been compared to the cross section determined by a crossed-beam technique. The agreement between the results of the experiments is good at energies above 75 keV. A discrepancy between the results at lower energies indicated a systematic error in one of the techniques. Theoretical estimates of the cross section recently have begun to agree with the magnitude of the cross section but have not fully explained the energy dependence.

  20. Determination of prescription dose for Cs-131 permanent implants using the BED formalism including resensitization correction

    SciTech Connect (OSTI)

    Luo, Wei Molloy, Janelle; Aryal, Prakash; Feddock, Jonathan; Randall, Marcus

    2014-02-15

    Purpose: The current widely used biological equivalent dose (BED) formalism for permanent implants is based on the linear-quadratic model that includes cell repair and repopulation but not resensitization (redistribution and reoxygenation). The authors propose a BED formalism that includes all the four biological effects (4Rs), and the authors propose how it can be used to calculate appropriate prescription doses for permanent implants with Cs-131. Methods: A resensitization correction was added to the BED calculation for permanent implants to account for 4Rs. Using the same BED, the prescription doses with Au-198, I-125, and Pd-103 were converted to the isoeffective Cs-131 prescription doses. The conversion factor F, ratio of the Cs-131 dose to the equivalent dose with the other reference isotope (F{sub r}: with resensitization, F{sub n}: without resensitization), was thus derived and used for actual prescription. Different values of biological parameters such as α, β, and relative biological effectiveness for different types of tumors were used for the calculation. Results: Prescription doses with I-125, Pd-103, and Au-198 ranging from 10 to 160 Gy were converted into prescription doses with Cs-131. The difference in dose conversion factors with (F{sub r}) and without (F{sub n}) resensitization was significant but varied with different isotopes and different types of tumors. The conversion factors also varied with different doses. For I-125, the average values of F{sub r}/F{sub n} were 0.51/0.46, for fast growing tumors, and 0.88/0.77 for slow growing tumors. For Pd-103, the average values of F{sub r}/F{sub n} were 1.25/1.15 for fast growing tumors, and 1.28/1.22 for slow growing tumors. For Au-198, the average values of F{sub r}/F{sub n} were 1.08/1.25 for fast growing tumors, and 1.00/1.06 for slow growing tumors. Using the biological parameters for the HeLa/C4-I cells, the averaged value of F{sub r} was 1.07/1.11 (rounded to 1.1), and the averaged value of F

  1. Magnetic measurements on ??CS{sub 2}U{sub 4}O{sub 12}

    SciTech Connect (OSTI)

    Kanrar, Buddhadev Misra, N. L.; Sastry, P. U.; Dube, V.; Ravikumar, G.

    2014-04-24

    Magnetic and XRD measurements on ??CS{sub 2}U{sub 4}O{sub 12} having uranium in mixed valent states of U (V) and U (VI) have been made. The study reveals that the compound undergoes an antiferromagnetic transition below 25K and an anomalous magnetic behavior was seen around 75K. This anomalous behavior indicates towards a structural phase transition. However, the low temperature XRD could not confirm this observation.

  2. Potentiometric Response Characteristics of Membrane-BasedCs+-Selective Electrodes Containing Ionophore-Functionalized Polymeric Microspheres

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peper, Shane; Gonczy, Chad

    2011-01-01

    Cs+-selective solvent polymeric membrane-based ion-selective electrodes (ISEs) were developed by doping ethylene glycol-functionalized cross-linked polystyrene microspheres (P-EG) into a plasticized poly(vinyl chloride) (PVC) matrix containing sodium tetrakis-(3,5-bis(trifluoromethyl)phenyl) borate (TFPB) as the ion exchanger. A systematic study examining the effects of the membrane plasticizers bis(2-ethylhexyl) sebacate (DOS), 2-nitrophenyl octyl ether (NPOE), and 2-fluorophenyl nitrophenyl ether (FPNPE) on the potentiometric response and selectivity of the corresponding electrodes was performed. Under certain conditions, P-EG-based ion-selective electrodes (ISEs) containing TFPB and plasticized with NPOE exhibited a super-Nernstian response between110?3and110?4?M Cs+, a response characteristic not observed in analogous membranes plasticized with either DOS or FPNPE.moreAdditionally, the performance of P-EG-based ISEs was compared to electrodes based on two mobile ionophores, a neutral lipophilic ethylene glycol derivative (ethylene glycol monooctadecyl ether (U-EG)) and a charged metallacarborane ionophore, sodium bis(dicarbollyl)cobaltate(III) (CC). In general, P-EG-based electrodes plasticized with FPNPE yielded the best performance, with a linear range from 10-110-5?M Cs+, a conventional lower detection limit of8.110?6?M Cs+, and a response slope of 57.7?mV/decade. The pH response of P-EG ISEs containing TFPB was evaluated for membranes plasticized with either NPOE or FPNPE. In both cases, the electrodes remained stable throughout the pH range 312, with only slight proton interference observed below pH 3.less

  3. COMMISSIONING AND START-UP TESTS OF ALPHA-CONTAMINATED SOLID WASTE SORTING, CEMENTING, AND INTERIM STORAGE FACILITIES AT BELGOPROCESS (BELGIUM)

    SciTech Connect (OSTI)

    GLIBERT, R.C.; NUYT, G.; LAMOTTE, G.; RENARD, CL.; DE GOEYSE, A.; GOETSCHALCKX, R.; GHYS, B.

    2003-02-27

    The alpha-contaminated solid waste generated in Belgium results from past activities in the fuel cycle (R & D +Reprocessing and MOX fabrication pilot plants) and present operation of BELGONUCLEAIRE's MOX fuel fabrication plant. After the main steps in the management of alpha-contaminated solid waste were established, BELGONUCLEAIRE, with the backing of BELGOPROCESS and ONDRAF/NIRAS, started the design and construction of the T & C and interim-storage facilities for this alpha waste. The accumulated solid alpha radwaste containing a mixture of combustible and non-combustible material will be sorted. After sorting, both the accumulated and recently-generated non-combustible alpha waste will be embedded in a cement matrix. The erection of the sorting and cementing units which include glove-boxes and the interim storage building for conditioned packages was completed at BELGOPROCESS, at the beginning of year 2002. Start-up operations for both facilities have been performed. Operating tests of the sorting and cementing units were completed in July 2002 and inactive operation campaigns were started in August 2002. The results of the tests and inactive campaigns are given. Overall testing of the storage building supervised by the Safety Authorities was successfully performed at the end of 202 after completion of the operating tests on the equipment. The present paper summarizes the main information collected during the tests and campaigns, some of which has led to modifications of the equipment originally installed.

  4. Inline Monitors for Measuring Cs-137 in the SRS Caustic Side Solvent Extraction Process

    SciTech Connect (OSTI)

    Casella, V

    2006-04-24

    The Department of Energy (DOE) selected Caustic-Side Solvent Extraction (CSSX) as the preferred technology for the removal of radioactive cesium from High-Level Waste (HLW) at the Savannah River Site (SRS). Before the full-scale Salt Waste Processing Facility (SWPF) becomes operational, a portion of dissolved saltcake waste will be processed through a Modular CSSX Unit (MCU). The MCU employs the CSSX process, a continuous process that uses a novel solvent to extract cesium from waste and concentrate it in dilute nitric acid. Of primary concern is Cs-137 which makes the solution highly radioactive. Since the MCU does not have the capacity to wait for sample results while continuing to operate, the Waste Acceptance Strategy is to perform inline analyses. Gamma-ray monitors are used to: measure the Cs-137 concentration in the decontaminated salt solution (DSS) before entering the DSS Hold Tank; measure the Cs-137 concentration in the strip effluent (SE) before entering the SE Hold Tank; and verify proper operation of the solvent extraction system by verifying material balance within the process. Since this gamma ray monitoring system application is unique, specially designed shielding was developed and software was written and acceptance tested by Savannah River National Laboratory (SRNL) personnel. The software is a LabView-based application that serves as a unified interface for controlling the monitor hardware and communicating with the host Distributed Control System. This paper presents the design, fabrication and implementation of this monitoring system.

  5. Evaluation of aqueous Na{sup +}/Cs{sup +} separation by electrodialysis

    SciTech Connect (OSTI)

    Buehler, M.F.; Lawrence, W.E.; Norton, J.D.

    1993-12-01

    In support of the Hanford Site cleanup, electrodialysis is being investigated as a method to separate aqueous sodium (Na{sup +}) and cesium (Cs{sup +}) ions. The approach has many advantages over existing separation technologies; in particular, electrodialysis creates little secondary waste while producing usable acid and base streams. The fundamentals of electrodialysis are presented in this report to provide a foundation for interpreting experimental data. A flat-plate laboratory-scale apparatus was used to determine the feasibility of separating Na{sup +}/Cs{sup +} mixtures by electrodialysis. The results showed that Cs{sup +} is preferentially separated over Na{sup +} by a factor of 2 to 3 using a Nafion{reg_sign} 417 cationic membrane. The separation is relatively insensitive to solution ionic strength and flow-rate variations. The current efficiency of the separation ranges from 0.60 to 0.65 depending on the applied voltage. The laboratory-scale system was characterized by dimensional analysis, which demonstrated that the process could be scaled up to a size attractive for the volume of waste at the Hanford Site. Preliminary experiments on a bench-scale system were also conducted. The initial results showed that the current-voltage response of the laboratory- and the bench-scale unit is identical.

  6. Crystal Structure and Thermodynamic Stability of Ba/Ti-Substituted Pollucites for Radioactive Cs/Ba Immobilization

    SciTech Connect (OSTI)

    Xu, Hongwu; Chavez, Manuel E.; Mitchell, Jeremy N.; Garino, Terry J.; Schwarz, Haiqing L.; Rodriguez, Mark A.; Rademacher, David X.; Nenoff, Tina Maria

    2015-04-23

    An analogue of the mineral pollucite (CsAlSi2O6), CsTiSi2O6.5 has a potential host phase for radioactive Cs. However, as 137Cs and 135Cs transmute to 137Ba and 135Ba, respectively, through the beta decay, it is essential to study the structure and stability of this phase upon Cs → Ba substitution. In this work, two series of Ba/Ti-substituted samples, CsxBa(1-x)/2TiSi2O6.5 and CsxBa1-xTiSi2O7-0.5x, (x = 0.9 and 0.7), were synthesized by high-temperature crystallization from their respective precursors. Synchrotron X-ray diffraction and Rietveld analysis reveal that while CsxBa(1-x)/2TiSi2O6.5 samples are phase-pure, CsxBa1-xTiSi2O7-0.5x samples contain Cs3x/(2+x)Ba(1-x)/(2+x)TiSi2O6.5 pollucites (i.e., also two-Cs-to-one-Ba substitution) and a secondary phase, fresnoite (Ba2TiSi2O8). Thus, the CsxBa1-xTiSi2O7-0.5x series is energetically less favorable than CsxBa(1-x)/2TiSi2O6.5. To study the stability systematics of CsxBa(1-x)/2TiSi2O6.5 pollucites, high-temperature calorimetric experiments were performed at 973 K with or without the lead borate solvent. Enthalpies of formation from the constituent oxides (and elements) have thus been derived. Our results show that with increasing Ba/(Cs + Ba) ratio, the thermodynamic stability of these phases decreases with respect to their component oxides. Hence, from the energetic viewpoint, continued Cs → Ba transmutation tends to destabilize the parent silicotitanate pollucite structure. However, the Ba-substituted pollucite co-forms with fresnoite (which incorporates the excess Ba

  7. Diffusion of Ag, Au and Cs implants in MAX phase Ti3SiC2 (Journal...

    Office of Scientific and Technical Information (OSTI)

    Title: Diffusion of Ag, Au and Cs implants in MAX phase Ti3SiC2 MAX phases (M: early transition metal; A: elements in group 13 or 14; X: C or N), such as titanium silicon carbide ...

  8. Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-368 Brookfield Energy Marketing LP

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE):  Application from Brookfield Energy Marketing LP to export electric energy to CanadaA

  9. Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-365 Centre Land Trading Limited

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE):  Application from Centre Land Trading Limited to export electric energy to Canada

  10. Decomposition of tetraphenylborate precipitates used to isolate Cs-137 from Savannah River Site high-level waste

    SciTech Connect (OSTI)

    Ferrara, D.M.; Bibler, N.E.; Ha, B.C.

    1993-03-01

    This paper presents results of the radioactive demonstration of the Precipitate Hydrolysis Process (PHP) that will be performed in the Defense Waste Processing Facility (DWPF) at the Savannah River Site. The PHP destroys the tetraphenylborate precipitate that is used at SRS to isolate Cs-137 from caustic High-Level Waste (HLW) supernates. This process is necessary to decrease the amount of organic compounds going to the melter in the DWPF. Actual radioactive precipitate containing Cs-137 was used for this demonstration.

  11. Evaluation and comparison of SuperLig{reg_sign} 644, resorcinol-formaldehyde and CS-100 ion exchange materials for the removal of cesium from simulated alkaline supernate

    SciTech Connect (OSTI)

    Brown, G.N.; Bray, L.A.; Eloviche, R.J.; Bruening, R.L.; Decker, R.M.; Kafka, T.M.; White, L.R.

    1995-03-01

    PNL evaluated three polymeric materials for Cs removal efficiency from a simulated Hanford Neutralized Current Acid Waste (NCAW) supernatant liquid using 200 mL ion exchange columns. Cs loadings (mmole Cs/g resin) were 0.20, 0.18, and 0.039 for Super Lig 644, R-F, and CS-100 (0.045, 0.070, 0.011 mmole Cs/mL resin). Elution of each resin material with 0.5 M HNO{sub 3} required 3.5, 7.0, and 3.2 cv to reach 0.1 C/C{sub 0} for the respective materials, resulting in volume compressions of 27, 20, and 6.9. Peak Cs concentrations during elution was 185, 38.5, and 27.8 C/C{sub 0}. SuperLig 644 had the highest Cs loading per gram in NCAW and the greatest volume compression on aci elution. Because of high density and poor elution, R-F had the highest Cs loading per unit volume and lower volume compression. CS-100, the baseline material for Cs removal at Hanford, was inferior to both SuperLig 644 and R-F in terms of Cs loading and selectivity over sodium.

  12. APPLICATION OF BAYESIAN AND GEOSTATISTICAL MODELING TO THE ENVIRONMENTAL MONITORING OF CS-137 AT THE IDAHO NATIONAL LABORATORY

    SciTech Connect (OSTI)

    Kara G. Eby

    2010-08-01

    At the Idaho National Laboratory (INL) Cs-137 concentrations above the U.S. Environmental Protection Agency risk-based threshold of 0.23 pCi/g may increase the risk of human mortality due to cancer. As a leader in nuclear research, the INL has been conducting nuclear activities for decades. Elevated anthropogenic radionuclide levels including Cs-137 are a result of atmospheric weapons testing, the Chernobyl accident, and nuclear activities occurring at the INL site. Therefore environmental monitoring and long-term surveillance of Cs-137 is required to evaluate risk. However, due to the large land area involved, frequent and comprehensive monitoring is limited. Developing a spatial model that predicts Cs-137 concentrations at unsampled locations will enhance the spatial characterization of Cs-137 in surface soils, provide guidance for an efficient monitoring program, and pinpoint areas requiring mitigation strategies. The predictive model presented herein is based on applied geostatistics using a Bayesian analysis of environmental characteristics across the INL site, which provides kriging spatial maps of both Cs-137 estimates and prediction errors. Comparisons are presented of two different kriging methods, showing that the use of secondary information (i.e., environmental characteristics) can provide improved prediction performance in some areas of the INL site.

  13. Effects of Compaction and Temperature on Sorption and Diffusion of Cs and HTO in Compacted Bentonite Saturated with Saline Water

    SciTech Connect (OSTI)

    Satoru Suzuki; Masashi Haginuma; Kazunori Suzuki

    2007-07-01

    The sorption and diffusion of Cs and tritiated water (HTO) in compacted bentonite was investigated at temperatures from 30 to 60 deg. C. The apparent (D{sub a}) and effective (D{sub e}) diffusion coefficients were determined by in-diffusion and through-diffusion experiments with a constant boundary concentration maintained. The temperature dependence of De and Da obeyed an Arrhenius-type equation, allowing determination of the activation energy for diffusion of Cs and HTO. The D{sub e} value of Cs was three times the D{sub e} of HTO, which is considered to be a result of surface-excess diffusion. Cs may be concentrated near the surface of the negatively charged clay, thus giving a large diffusive flux. The activation energies for Cs diffusion were 21.4{+-}2.8 kJ/mol and 37.3{+-}1.5 kJ/mol as determined based on D{sub e} and D{sub a}, respectively. This difference was due to the temperature dependence of the distribution coefficient K{sub d} of Cs. (authors)

  14. Comparison of the post-Chernobyl [sup 137]Cs contamination of mushrooms from eastern Europe, Sweden, and North America

    SciTech Connect (OSTI)

    Smith, M.L.; Taylor, H.W.; Sharma, H.D. )

    1993-01-01

    A comparison was made of 134Cs and 137Cs contamination in fungi from eastern Europe and eastern North America. Mean activities of 25 Ukrainian, 6 Swedish, and 10 North American collections were 4,660, 9,750, and 205 Bq/kg (dry weight), respectively. Additional measurements were made on samples from the Moscow, southern Belarus, and Yugoslavia/Bulgaria regions. Activity values were found to vary by several orders of magnitude within all geographic areas, even for the same mushroom species. Significantly higher specific activities were observed in mycorrhizal species than in saprophytic and parasitic fungi. Unfortunately, many of the European mycorrhizal species considered as prized edibles contained unacceptably high levels of 137Cs (> 1,000 Bq/kg [dry weight]) and should be used sparingly as food. By contrast, no mushrooms collected in Ontario or northern Michigan exceeded 1,000 Bq of 137Cs per kg (dry weight). The excessive 137Cs contamination was evident in mushrooms from areas that had substantial fallout from the 1986 accident in reactor 4 at the Chernobyl nuclear power station. However, observations suggest that about 20% of the 137Cs in eastern Europe (Moscow area, Belarus, and Ukraine) is of non-Chernobyl origin.

  15. Crystal Structure and Thermodynamic Stability of Ba/Ti-Substituted Pollucites for Radioactive Cs/Ba Immobilization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Hongwu; Chavez, Manuel E.; Mitchell, Jeremy N.; Garino, Terry J.; Schwarz, Haiqing L.; Rodriguez, Mark A.; Rademacher, David X.; Nenoff, Tina Maria

    2015-04-23

    An analogue of the mineral pollucite (CsAlSi2O6), CsTiSi2O6.5 has a potential host phase for radioactive Cs. However, as 137Cs and 135Cs transmute to 137Ba and 135Ba, respectively, through the beta decay, it is essential to study the structure and stability of this phase upon Cs → Ba substitution. In this work, two series of Ba/Ti-substituted samples, CsxBa(1-x)/2TiSi2O6.5 and CsxBa1-xTiSi2O7-0.5x, (x = 0.9 and 0.7), were synthesized by high-temperature crystallization from their respective precursors. Synchrotron X-ray diffraction and Rietveld analysis reveal that while CsxBa(1-x)/2TiSi2O6.5 samples are phase-pure, CsxBa1-xTiSi2O7-0.5x samples contain Cs3x/(2+x)Ba(1-x)/(2+x)TiSi2O6.5 pollucites (i.e., also two-Cs-to-one-Ba substitution) and a secondary phase, fresnoitemore » (Ba2TiSi2O8). Thus, the CsxBa1-xTiSi2O7-0.5x series is energetically less favorable than CsxBa(1-x)/2TiSi2O6.5. To study the stability systematics of CsxBa(1-x)/2TiSi2O6.5 pollucites, high-temperature calorimetric experiments were performed at 973 K with or without the lead borate solvent. Enthalpies of formation from the constituent oxides (and elements) have thus been derived. Our results show that with increasing Ba/(Cs + Ba) ratio, the thermodynamic stability of these phases decreases with respect to their component oxides. Hence, from the energetic viewpoint, continued Cs → Ba transmutation tends to destabilize the parent silicotitanate pollucite structure. However, the Ba-substituted pollucite co-forms with fresnoite (which incorporates the excess Ba), thereby providing viable ceramic waste forms for all the Ba decay products.« less

  16. Complete genome sequence of the phenanthrene-degrading soil bacterium Delftia acidovorans Cs1-4

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shetty, Ameesha R.; de Gannes, Vidya; Obi, Chioma C.; Lucas, Susan; Lapidus, Alla; Cheng, Jan-Fang; Goodwin, Lynne A.; Pitluck, Samuel; Peters, Linda; Mikhailova, Natalia; et al

    2015-08-15

    Polycyclic aromatic hydrocarbons (PAH) are ubiquitous environmental pollutants and microbial biodegradation is an important means of remediation of PAH-contaminated soil. Delftia acidovorans Cs1-4 (formerly Delftia sp. Cs1-4) was isolated by using phenanthrene as the sole carbon source from PAH contaminated soil in Wisconsin. Its full genome sequence was determined to gain insights into a mechanisms underlying biodegradation of PAH. Three genomic libraries were constructed and sequenced: an Illumina GAii shotgun library (916,416,493 reads), a 454 Titanium standard library (770,171 reads) and one paired-end 454 library (average insert size of 8 kb, 508,092 reads). The initial assembly contained 40 contigs inmore » two scaffolds. The 454 Titanium standard data and the 454 paired end data were assembled together and the consensus sequences were computationally shredded into 2 kb overlapping shreds. Illumina sequencing data was assembled, and the consensus sequence was computationally shredded into 1.5 kb overlapping shreds. Gaps between contigs were closed by editing in Consed, by PCR and by Bubble PCR primer walks. A total of 182 additional reactions were needed to close gaps and to raise the quality of the finished sequence. The final assembly is based on 253.3 Mb of 454 draft data (averaging 38.4 X coverage) and 590.2 Mb of Illumina draft data (averaging 89.4 X coverage). The genome of strain Cs1-4 consists of a single circular chromosome of 6,685,842 bp (66.7 %G+C) containing 6,028 predicted genes; 5,931 of these genes were protein-encoding and 4,425 gene products were assigned to a putative function. Genes encoding phenanthrene degradation were localized to a 232 kb genomic island (termed the phn island), which contained near its 3’ end a bacteriophage P4-like integrase, an enzyme often associated with chromosomal integration of mobile genetic elements. Other biodegradation pathways reconstructed from the genome sequence included: benzoate (by the acetyl

  17. Complete genome sequence of the phenanthrene-degrading soil bacterium Delftia acidovorans Cs1-4

    SciTech Connect (OSTI)

    Shetty, Ameesha R.; de Gannes, Vidya; Obi, Chioma C.; Lucas, Susan; Lapidus, Alla; Cheng, Jan-Fang; Goodwin, Lynne A.; Pitluck, Samuel; Peters, Linda; Mikhailova, Natalia; Teshima, Hazuki; Han, Cliff; Tapia, Roxanne; Land, Miriam; Hauser, Loren J.; Kyrpides, Nikos; Ivanova, Natalia; Pagani, Ioanna; Chain, Patrick S. G.; Denef, Vincent J.; Woyke, Tanya; Hickey, William J.

    2015-08-15

    Polycyclic aromatic hydrocarbons (PAH) are ubiquitous environmental pollutants and microbial biodegradation is an important means of remediation of PAH-contaminated soil. Delftia acidovorans Cs1-4 (formerly Delftia sp. Cs1-4) was isolated by using phenanthrene as the sole carbon source from PAH contaminated soil in Wisconsin. Its full genome sequence was determined to gain insights into a mechanisms underlying biodegradation of PAH. Three genomic libraries were constructed and sequenced: an Illumina GAii shotgun library (916,416,493 reads), a 454 Titanium standard library (770,171 reads) and one paired-end 454 library (average insert size of 8 kb, 508,092 reads). The initial assembly contained 40 contigs in two scaffolds. The 454 Titanium standard data and the 454 paired end data were assembled together and the consensus sequences were computationally shredded into 2 kb overlapping shreds. Illumina sequencing data was assembled, and the consensus sequence was computationally shredded into 1.5 kb overlapping shreds. Gaps between contigs were closed by editing in Consed, by PCR and by Bubble PCR primer walks. A total of 182 additional reactions were needed to close gaps and to raise the quality of the finished sequence. The final assembly is based on 253.3 Mb of 454 draft data (averaging 38.4 X coverage) and 590.2 Mb of Illumina draft data (averaging 89.4 X coverage). The genome of strain Cs1-4 consists of a single circular chromosome of 6,685,842 bp (66.7 %G+C) containing 6,028 predicted genes; 5,931 of these genes were protein-encoding and 4,425 gene products were assigned to a putative function. Genes encoding phenanthrene degradation were localized to a 232 kb genomic island (termed the phn island), which contained near its 3’ end a bacteriophage P4-like integrase, an enzyme often associated with chromosomal integration of mobile genetic elements. Other biodegradation pathways reconstructed from the genome sequence included: benzoate (by the acetyl-CoA pathway

  18. Structure and properties of electronic and hole centers in CsBr from theoretical calculations

    SciTech Connect (OSTI)

    Halliday, Matthew T.; Hess, Wayne P.; Shluger, Alexander L.

    2015-06-24

    The electronic structure, geometry, diffusion barriers and optical properties of fundamental defects of CsBr are calculated using hybrid functional DFT and TD- DFT methods. The B3LYP functional with a modified exchange contribution has been used in an embedded cluster scheme to model the structure and spectroscopic properties of self-trapped triplet exciton, interstitial Br atoms and ions, self-trapped holes and Br vacancies. The calculated migration barriers and positions of maxima of optical absorption bands are in good agreement with experiment, justifying the obtained defect geometries. The o*-center triplet exciton luminescence energy is also accurately calculated.

  19. Crystal structure and phase transition mechanisms in CsFe{sub 2}F{sub 6}

    SciTech Connect (OSTI)

    Molokeev, M.S.; Bogdanov, E.V.; Misyul, S.V.; Tressaud, A.; Flerov, I.N.

    2013-04-15

    For the first time, structural phase transitions induced by the temperature were found in A{sub x}M{sub x}{sup II}M{sub (1?x)}{sup III}F{sub 3} fluorides with the defect pyrochlore structure (Fd3{sup }m, Z=8). The room temperature structure of CsFe{sub 2}F{sub 6} was determined using X-ray powder diffraction technique. This phase was found to be ordered with the Pnma space group. The study of the temperature stability of orthorhombic structure by differential scanning calorimeter between 100 K and 700 K has shown a succession of phase transitions. The Pnma (Z=4)?Imma (Z=4)?I4{sub 1}/amd (Z=4)?Fd3{sup }m (Z=8) structural sequence was proposed to occur within a rather narrow temperature range 500560 K. The mechanism of structural transition has been mainly associated with the rotation of (MF{sub 6}) octahedra and small displacements of some Fe atoms. This assumption is in good agreement with the low experimental entropy value, which is characteristic for displacive transformations. - Graphical abstract: Mechanism of phase transition between the HT cubic form of CsFe{sub 2}F{sub 6} at 573 K (left) and the room temperature orthorhombic form at 298 K (right). The grey rectangles are clusters of five FeF{sub 6} octahedra. Highlights: ? Structural transition found for the first time in CsFe{sub 2}F{sub 6} with defect pyrochlore type. ? Fe{sup II} and Fe{sup III} atoms are ordered in room temperature Pnma form of CsFe{sub 2}F{sub 6}. ? Pnma(Z=4)?Imma(Z=4)?I4{sub 1}/amd(Z=4)?Fd-3m(Z=8) transition sequence is proposed. ? Structural transition due to rotation of MF{sub 6} groups+small displacements of Fe atoms. ? The low value of the entropy is in agreement with a displacive-type transition.

  20. Correlation of CsK2Sb photocathode lifetime with antimony thickness

    SciTech Connect (OSTI)

    Mamun, M. A.; Hernandez-Garcia, C.; Poelker, M.; Elmustafa, A. A.

    2015-06-01

    CsK2Sb photocathodes with quantum efficiency on the order of 10% at 532 nm, and lifetime greater than 90 days at low voltage, were successfully manufactured via co-deposition of alkali species emanating from an effusion source. Photocathodes were characterized as a function of antimony layer thickness and alkali consumption, inside a vacuum chamber that was initially baked, but frequently vented without re-baking. Photocathode lifetime measured at low voltage is correlated with the antimony layer thickness. Photocathodes manufactured with comparatively thick antimony layers exhibited the best lifetime. We speculate that the antimony layer serves as a reservoir, or sponge, for the alkali.

  1. In Situ Remediation of {sup 137}Cs Contaminated Wetlands Using Naturally Occurring Minerals

    SciTech Connect (OSTI)

    Kaplan, D.I.

    1999-08-11

    Cesium-137 has contaminated a large area of the wetlands on the Savannah River Site. Remediation of the contaminated wetlands is problematic because current techniques destroy the sensitive ecosystem and generate a higher dose to workers. To address this problem, we proposed a non-trusive, in situ technology to sequester 137Cs in sediments. One intention of this study was to provide information regarding a go/no go decision for future work. Since the proof-of-concept was successful and several minerals were identified as potential candidates for this technology, a go decision was made.

  2. Environmental and economic development consequences of forest and agricultural sector policies in Latin America (a synthesis of case studies of Costa Rica, Ecuador, and Bolivia)

    SciTech Connect (OSTI)

    Stewart, R.; Gibson, D.

    1994-04-15

    This paper draws heavily on the results of case studies in Bolivia, Costa Rica, and Ecuador to explain how sectoral policies have tilted land use decisions against forestry and in favor of agriculture, and to present estimates of the economic development effects of those decisions. The paper summarizes information on forests and forest industries of the three countries, and it describes the framework within which policies are designed. It presents the effects of sectoral policies on land use and forest management, and then quantifies and discusses economic costs of relevant sectoral policies. Conclusions and recommendations for policy reform are offered.

  3. Signal and noise transfer properties of CMOS based active pixel flat panel imager coupled to structured CsI:Tl

    SciTech Connect (OSTI)

    Arvanitis, C. D.; Bohndiek, S. E.; Blakesley, J.; Olivo, A.; Speller, R. D.

    2009-01-15

    Complementary metal-oxide-semiconductors (CMOS) active pixel sensors can be optically coupled to CsI:Tl phosphors forming a indirect active pixel flat panel imager (APFPI) for high performance medical imaging. The aim of this work is to determine the x-ray imaging capabilities of CMOS-based APFPI and study the signal and noise transfer properties of CsI:Tl phosphors. Three different CsI:Tl phosphors from two different vendors have been used to produce three system configurations. The performance of each system configuration has been studied in terms of the modulation transfer function (MTF), noise power spectra, and detective quantum efficiency (DQE) in the mammographic energy range. A simple method to determine quantum limited systems in this energy range is also presented. In addition, with aid of monochromatic synchrotron radiation, the effect of iodine characteristic x-rays of the CsI:Tl on the MTF has been determined. A Monte Carlo simulation of the signal transfer properties of the imager is also presented in order to study the stages that degrade the spatial resolution of our current system. The effect of using substrate patterning during the growth of CsI:Tl columnar structure was also studied, along with the effect of CsI:Tl fixed pattern noise due to local variations in the scintillation light. CsI:Tl fixed pattern noise appears to limit the performance of our current system configurations. All the system configurations are quantum limited at 0.23 {mu}C/kg with two of them having DQE (0) equal to 0.57. Active pixel flat panel imagers are shown to be digital x-ray imagers with almost constant DQE throughout a significant part of their dynamic range and in particular at very low exposures.

  4. Watts Bar Unit 1 Cycle Zero Power Physics Tests Analysis with VERA-CS

    SciTech Connect (OSTI)

    Gehin, Jess C; Godfrey, Andrew T; Evans, Thomas M; Hamilton, Steven P; Francheschini, F.

    2014-01-01

    The Consortium for Advanced Simulation of Light Water Reactors (CASL) is developing a collection of methods and software products known as VERA, the Virtual Environment for Reactor Applications, including a core simulation capability called VERA-CS. A key milestone for this endeavor is to validate VERA against measurements from operating nuclear power reactors. The first step in validation against plant data is to determine the ability of VERA to accurately simulate the initial startup physics tests for Watts Bar Nuclear Power Station, Unit 1 (WBN1) cycle 1. VERA-CS calculations were performed with the Insilico code developed at ORNL using cross section processing from the SCALE system and the transport capabilities within the Denovo transport code using the SPN method. The calculations were performed with ENDF/B-VII.0 cross sections in 252 groups (collapsed to 23 groups for the 3D transport solution). The key results of the comparison of calculations with measurements include initial criticality, control rod worth critical configurations, control rod worth, differential boron worth, and isothermal temperature reactivity coefficient (ITC). The VERA results for these parameters show good agreement with measurements, with the exception of the ITC, which requires additional investigation. Results are also compared to those obtained with Monte Carlo methods and a current industry core simulator.

  5. Glass Ceramic Waste Forms for Combined CS+LN+TM Fission Products Waste Streams

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Turo, Laura A.; Riley, Brian J.; Tang, Ming; Kossoy, Anna; Sickafus, Kurt E.

    2010-09-23

    In this study, glass ceramics were explored as an alternative waste form for glass, the current baseline, to be used for immobilizing alkaline/alkaline earth + lanthanide (CS+LN) or CS+LN+transition metal (TM) fission-product waste streams generated by a uranium extraction (UREX+) aqueous separations type process. Results from past work on a glass waste form for the combined CS+LN waste streams showed that as waste loading increased, large fractions of crystalline phases precipitated upon slow cooling.[1] The crystalline phases had no noticeable impact on the waste form performance by the 7-day product consistency test (PCT). These results point towards the development of a glass ceramic waste form for treating CS+LN or CS+LN+TM combined waste streams. Three main benefits for exploring glass ceramics are: (1) Glass ceramics offer increased solubility of troublesome components in crystalline phases as compared to glass, leading to increased waste loading; (2) The crystalline network formed in the glass ceramic results in higher heat tolerance than glass; and (3) These glass ceramics are designed to be processed by the same melter technology as the current baseline glass waste form. It will only require adding controlled canister cooling for crystallization into a glass ceramic waste form. Highly annealed waste form (essentially crack free) with up to 50X lower surface area than a typical High-Level Waste (HLW) glass canister. Lower surface area translates directly into increased durability. This was the first full year of exploring glass ceramics for the Option 1 and 2 combined waste stream options. This work has shown that dramatic increases in waste loading are achievable by designing a glass ceramic waste form as an alternative to glass. Table S1 shows the upper limits for heat, waste loading (based on solubility), and the decay time needed before treatment can occur for glass and glass ceramic waste forms. The improvements are significant for both combined waste

  6. Task 2 - Limits for High-Frequency Conducted Susceptibility Testing - CS114 (NRC-HQ-60-14-D-0015)

    SciTech Connect (OSTI)

    Wood, Richard Thomas; Ewing, Paul D.; Moses, Rebecca J.

    2015-09-01

    A principal focus of Task 2 under this project was for ORNL to evaluate the basis for susceptibility testing against high-frequency conducted interference and to establish recommendations to resolve concerns about the severity of test limits for the conducted susceptibility (CS) test, CS114, from MIL-STD-461. The primary concern about the test limit has been characterized by the EPRI EMI Working Group in the following terms: Demonstrating compliance with the CS114 test limits recommended in TR-102323 has proven to be problematic, even for components that have been tested to commercial standards and demonstrated proper operation in industrial applications [6]. Specifically, EPRI notes that the CS114 limits approved in regulatory documents are significantly higher than those invoked by the US military and similar commercial standards in the frequency range below 200 kHz. For this task, ORNL evaluated the original approach to establishing the test limit, EPRI technical findings from a review of the limit, and the regulatory basis through which the currently approved limits were accepted. Based on this analysis, strategies have been developed regarding changes to the CS114 limit that can resolve the technical concerns raised by the industry. Guided by the principles that reasonable assurance of safety must not be compromised but excessive conservatism should be reduced, recommendations on a suitable basis for a revised limit have been developed and can be incorporated into the planned Revision 2 of RG 1.180.

  7. A novel cold-regulated gene from Camellia sinensis, CsCOR1, enhances salt- and dehydration-tolerance in tobacco

    SciTech Connect (OSTI)

    Li, Xian-Wen; College of Life Science, Xinyang Normal University, Xinyang 464000; Key Laboratory of Horticultural Plant Biology of the Ministry of Education, Huazhong Agricultural University, Wuhan 430070 ; Feng, Zhi-Guo; Yang, Hui-Min; Zhu, Xiao-Pei; Liu, Jun; Key Laboratory of Horticultural Plant Biology of the Ministry of Education, Huazhong Agricultural University, Wuhan 430070 ; Yuan, Hong-Yu

    2010-04-02

    In present research, the full-length cDNA and the genomic sequence of a novel cold-regulated gene, CsCOR1, were isolated from Camellia sinensis L. The deduced protein CsCOR1 contains a hydrophobic N-terminus as a signal peptide and a hydrophilic C-terminal domain that is rich in glycine, arginine and proline. Two internal repetitive tridecapeptide fragments (HSVTAGRGGYNRG) exist in the middle of the C-terminal domain and the two nucleotide sequences encoding them are identical. CsCOR1 was localized in the cell walls of transgenic-tobaccos via CsCOR1::GFP fusion approach. The expression of CsCOR1 in tea leaves was enhanced dramatically by both cold- and dehydration-stress. And overexpression of CsCOR1 in transgenic-tobaccos improved obviously the tolerance to salinity and dehydration.

  8. Nanocrystalline Cs{sub x}WO{sub 3} particles: Effects of N{sub 2} annealing on microstructure and near-infrared shielding characteristics

    SciTech Connect (OSTI)

    Liu, Jing-Xiao, E-mail: drliu-shi@dlpu.edu.cn [School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034 (China); Institute of Multidisciplinary Research for Advanced Material, Tohoku University, Sendai, 980-8577,Japan (Japan); Shi, Fei; Dong, Xiao-Li; Xu, Qiang [School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034 (China); Yin, Shu; Sato, Tsugio [Institute of Multidisciplinary Research for Advanced Material, Tohoku University, Sendai, 980-8577,Japan (Japan)

    2013-10-15

    In order to further improve the near-infrared shielding properties of cesium tungsten bronze (Cs{sub x}WO{sub 3}) for solar filter applications, Cs{sub x}WO{sub 3} particles were prepared by solvothermal reaction method and the effects of nitrogen annealing on the microstructure and near-infrared shielding properties of Cs{sub x}WO{sub 3} were investigated. The obtained Cs{sub x}WO{sub 3} samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and spectrophotometer. The results indicate that nanosheet-like Cs{sub x}WO{sub 3} particles with hexagonal structure began to transform into nanorods after annealed at temperature higher than 600 C. The near-infrared shielding properties of Cs{sub x}WO{sub 3} particles could be further improved by N{sub 2} annealing at 500700 C. Particularly, the 500 C-annealed Cs{sub x}WO{sub 3} samples in the N{sub 2} atmosphere showed best near-infrared shielding properties. It was suggested that the excellent near-infrared shielding ability of the 500 C-annealed Cs{sub x}WO{sub 3} samples is correlated with its minimum O/W atomic ratio and most oxygen vacancies. Highlights: N{sub 2} annealing could further improve the near-infrared (NIR) shielding of Cs{sub x}WO{sub 3}. Effects of N{sub 2} annealing on microstructure and NIR shielding of Cs{sub x}WO{sub 3} were studied. The 500 C-N{sub 2}-annealed Cs{sub x}WO{sub 3} exhibited minimum O/W ratio and most oxygen vacancies. The 500 C-N{sub 2}-annealed Cs{sub x}WO{sub 3} particles exhibited best NIR shielding properties.

  9. Selective Separation of Cs and Sr from LiCl-Based Salt for Electrochemical Processing of Oxide Spent Nuclear Fuel

    SciTech Connect (OSTI)

    P Sachdev

    2008-07-01

    Electrochemical processing technology is currently being used for the treatment of metallic spent fuel from the Experimental Breeder Reactor-II at Idaho National Laboratory. The treatment of oxide-based spent nuclear fuel via electrochemical processing is possible provided there is a front-end oxide reduction step. During this reduction process, certain fission products, including Cs and Sr, partition into the salt phase and form chlorides. Both solid state and molten LiCl-zeolite-A ion exchange tests were conducted for selectively removing Cs and Sr from LiCl-based salt. The solid-state tests produced in excess of 99% removal of Cs and Sr. The molten state tests failed due to phase transformation of the zeolite structure when in contact with the molten LiCl salt.

  10. Fourier-transform microwave spectroscopy and determination of the three dimensional potential energy surface for ArCS

    SciTech Connect (OSTI)

    Niida, Chisato; Nakajima, Masakazu; Endo, Yasuki; Sumiyoshi, Yoshihiro; Ohshima, Yasuhiro; Kohguchi, Hiroshi

    2014-03-14

    Pure rotational transitions of the ArCS van der Waals complex have been observed by Fourier Transform Microwave (FTMW) and FTMW-millimeter wave double resonance spectroscopy. Rotational transitions of v{sub s} = 0, 1, and 2 were able to be observed for normal CS, together with those of C{sup 34}S in v{sub s} = 0, where v{sub s} stands for the quantum number of the CS stretching vibration. The observed transition frequencies were analyzed by a free rotor model Hamiltonian, where rovibrational energies were calculated as dynamical motions of the three nuclei on a three-dimensional potential energy surface, expressed by analytical functions with 57 parameters. Initial values for the potential parameters were obtained by high-level ab initio calculations. Fifteen parameters were adjusted among the 57 parameters to reproduce all the observed transition frequencies with the standard deviation of the fit to be 0.028 MHz.

  11. Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-363 Noble Americas Gas & Power Corporation

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE):  Noble Americas Gas & Power Corporation to export electric energy to Mexico

  12. Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): OE Docket EA-364 Noble Americas Gas & Power Corporation

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE):  Application from Noble Americas Gas & Power Corporation to export electric...

  13. 137Cs Inter-Plant Concentration Ratios Provide a Predictive Tool for Coral Atolls with Distinct Benefits Over Transfer Factors

    SciTech Connect (OSTI)

    Robison, W L; Hamilton, T F; Bogen, K; Corado, C L; Kehl, S R

    2007-07-17

    Inter-plant concentration ratios (IPCR), [Bq g{sup -1} {sup 137}Cs in coral atoll tree food-crops/Bq g{sup -1} {sup 137}Cs in leaves of native plant species whose roots share a common soil volume], can replace transfer factors (TF) to predict {sup 137}Cs concentration in tree food-crops in a contaminated area with an aged source term. The IPCR strategy has significant benefits relative to TF strategy for such purposes in the atoll ecosystem. IPCR strategy applied to specific assessments takes advantage of the fact tree roots naturally integrate 137Cs over large volumes of soil. Root absorption of {sup 137}Cs replaces large-scale, expensive soil sampling schemes to reduce variability in {sup 137}Cs concentration due to inhomogeneous radionuclide distribution. IPCR [drinking-coconut meat (DCM)/Scaevola (SCA) and Tournefortia (TOU) leaves (native trees growing on all atoll islands)] are log normally distributed (LND) with geometric standard deviation (GSD) = 1.85. TF for DCM from Enewetak, Eneu, Rongelap and Bikini Atolls are LND with GSD's of 3.5, 3.0, 2.7, and 2.1, respectively. TF GSD for Rongelap copra coconut meat is 2.5. IPCR of Pandanus fruit to SCA and TOU leaves are LND with GSD = 1.7 while TF GSD is 2.1. Because IPCR variability is much lower than TF variability, relative sampling error of an IPCR field sample mean is up 6- to 10-fold lower than that of a TF sample mean if sample sizes are small (10 to 20). Other IPCR advantages are that plant leaf samples are collected and processed in far less time with much less effort and cost than soil samples.

  14. Belgium | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure...

  15. Bose-Einstein Condensation of Magnons in Cs{sub 2}CuCl{sub 4}

    SciTech Connect (OSTI)

    Radu, T.; Wilhelm, H.; Luehmann, T.; Steglich, F.; Yushankhai, V.; Kovrizhin, D.; Coldea, R.; Tylczynski, Z.

    2005-09-16

    We report on results of specific heat measurements on single crystals of the frustrated quasi-2D spin-1/2 antiferromagnet Cs{sub 2}CuCl{sub 4} (T{sub N}=0.595 K) in external magnetic fields B<12 T and for temperatures T>30 mK. Decreasing B from high fields leads to the closure of the field-induced gap in the magnon spectrum at a critical field B{sub c}{approx_equal}8.51 T and a magnetic phase transition is clearly seen below B{sub c}. In the vicinity of B{sub c}, the phase transition boundary is well described by the power law T{sub c}(B){proportional_to}(B{sub c}-B){sup 1/{phi}}, with the measured critical exponent {phi}{approx_equal}1.5. These findings are interpreted as a Bose-Einstein condensation of magnons.

  16. DEVELOPMENT OF DEPOSIT DETECTION SYSTEM IN PIPELINES OF THE STEELWORKS USING CS-137 GAMMA-RAY

    SciTech Connect (OSTI)

    Song, Won-Joon; Lee, Seung-Hee; Jeong, Hee-Dong

    2008-02-28

    The deposit is built up in the pipeline of the steelworks by the chemical reaction among COG (coke oven gas), BFG (blast furnace gas), moisture, and steel in the high temperature environment and obstructs the smooth gas flow. In this study a gamma-ray system is developed to detect the deposit accumulated in pipelines and calculate the accumulation rate with respect to the cross section area of pipes. Cs-137 is used as the gamma-ray source and the system is designed to apply to pipes of various diameters. This system also includes the DB for storage and display of the measurement results so that it can be used for the efficient management of the pipelines.

  17. EVALUATION OF THE MIGRATION POTENTIAL FOR 60Co AND 137Cs AT THE MAINE YANKEE SITE.

    SciTech Connect (OSTI)

    FUHRMANN,M.SULLIVAN,T.

    2002-08-08

    The objective of this report is to discuss the degree of sorption and desorption of {sup 137}Cs and {sup 60}Co that may be associated with the granite bedrock and the ''popcorn'' cement drain system that underlie the Maine Yankee Containment Foundation. The purpose is to estimate how much retardation of these two radionuclides takes place in groundwater that flows in the near-field of the Containment Foundation, specifically with respect to contamination originating at the PAB Test Pit. Specific concerns revolve around the potential for the contamination originating near the PAB to create a radioactive dose to a hypothetical ''resident farmer'' using a well intercepting this water to exceed 4 millirems/yr.

  18. Sulfurization behavior of cerium doped uranium oxides by CS{sub 2}

    SciTech Connect (OSTI)

    Sato, Nobuaki; Kato, Shintaro; Kirishima, Akira; Tochiyama, Osamu

    2007-07-01

    For the recovery of nuclear materials from the spent nuclear fuel, the sulfide process has been proposed and the voloxidation of spent fuel and selective sulfurization rare-earth elements has been proposed. In this paper, cerium was used as a stand-in of plutonium and sulfurization behavior of cerium doped uranium dioxide by CS{sub 2} was studied. UO{sub 2} was oxidized to U{sub 3}O{sub 8} in air, while the Ce doped UO{sub 2} solid solution was formed in the presence of CeO{sub 2} by the heat treatment in air. The effect of heating time, temperature and the ratio of uranium to cerium on the formation of solid solution was analyzed. The results were also compared with those of thermodynamic consideration. (authors)

  19. TUNGSTEN SHIELDS FOR CS-137 INLINE MONITORS IN THE CAUSTIC SIDE SOLVENT EXTRACTION PROCESS

    SciTech Connect (OSTI)

    Casella, V; Mark Hogue, M; Javier Reyes-Jimenez, J; Paul Filpus-Luyckx, P; Timothy Riley, T; Fred Ogden, F; Donald Pak, D

    2007-05-10

    The Department of Energy (DOE) selected Caustic-Side Solvent Extraction (CSSX) as the preferred technology for the removal of radioactive cesium from High-Level Waste (HLW) at the Savannah River Site (SRS). The CSSX process is a continuous process that uses a novel solvent to extract cesium from highly radioactive waste and concentrate it in dilute nitric acid. In-line analyses are performed with gamma-ray monitors to measure the C-137 concentration in the decontaminated salt solution (DSS) and in the strip effluent (SE). Sodium iodide (NaI) monitors are used to measure the Cs-137 concentration before the DSS Hold Tank, while Geiger-Mueller (GM) monitors are used for Cs-137 measurements before the SE hold tank. Tungsten shields were designed using Monte Carlo calculations and fabricated to provide the needed reduction of the process background radiation at the detector positions. A one-inch tungsten cylindrical shield reduced the background radiation by a factor of fifty that was adequate for the GM detectors, while a three-and-one-half-inch tungsten cylindrical shield was required for the NaI detectors. Testing of the NaI shield was performed at the SRS Instrument Calibration Facility. Based on this testing, the as-built shield is predicted to be able to detect the MCU DSS stream at concentrations above 0.003 Ci/gal under the ''worst case'' field conditions with a MCU feed solution of 1.1 Ci/gal and all of the process tanks completely full. This paper discusses the design, fabrication, testing and implementation of the tungsten shields in the MCU facility.

  20. A magnesium-carboxylate framework showing luminescent sensing for CS{sub 2} and nitroaromatic compounds

    SciTech Connect (OSTI)

    Wu, Zhao-Feng; Tan, Bin; Feng, Mei-Ling; Du, Cheng-Feng; Huang, Xiao-Ying

    2015-03-15

    A magnesium metal-organic framework compound, namely [NH{sub 2}(CH{sub 3}){sub 2}][Mg{sub 3}(NDC){sub 2.5}(HCO{sub 2}){sub 2}(DMF){sub 0.75}(H{sub 2}O){sub 0.25}]·1.25DMF·0.75H{sub 2}O (1) (H{sub 2}NDC=1,4-naphthalene dicarboxylic acid, DMF=N,N′-dimethylformamide), has been synthesized in solvothermal conditions and structurally characterized. It features a three-dimensionally anionic framework with aligned channels parallel to the b-axis. Luminescent studies indicated that it showed significant luminescence quenching for carbon disulfide (CS{sub 2}) and nitrobenzene after being activated, at a content of only 3.0 and 0.1 vol% in DMF, respectively. In addition, the activated sample showed sensitive luminescence quenching for 1,3,5-trinitrophenol with a low concentration of 5×10{sup −5} mol/L. - Graphical abstract: Presented is a microporous 3D Mg-MOF, namely, [NH{sub 2}(CH{sub 3}){sub 2}][Mg{sub 3}(NDC){sub 2.5}(HCO{sub 2}){sub 2}(DMF){sub 0.75}(H{sub 2}O){sub 0.25}]·1.25DMF·0.75H{sub 2}O (1) (H{sub 2}NDC=1,4-naphthalene dicarboxylic acid) showing significant luminescence quenching for carbon disulfide and nitrobenzene. - Highlights: • A microporous 3D metal-organic framework based on Mg. • The compound shows significant luminescence quenching for CS{sub 2} and nitrobenzene after activated. • The compound shows sensitive luminescence quenching for 1,3,5-trinitrophenol with a low concentration of 5×10{sup −5} mol/L.

  1. High-temperature behavior of dicesium molybdate Cs{sub 2}MoO{sub 4}: Implications for fast neutron reactors

    SciTech Connect (OSTI)

    Wallez, Gilles; Raison, Philippe E.; Smith, Anna L.; Clavier, Nicolas

    2014-07-01

    Dicesium molybdate (Cs{sub 2}MoO{sub 4})'s thermal expansion and crystal structure have been investigated herein by high temperature X ray diffraction in conjunction with Raman spectroscopy. This first crystal-chemical insight at high temperature is aimed at predicting the thermostructural and thermomechanical behavior of this oxide formed by the accumulation of Cs and Mo fission products at the periphery of nuclear fuel rods in sodium-cooled fast reactors. Within the temperature range of the fuel's rim, Cs{sub 2}MoO{sub 4} becomes hexagonal P6{sub 3}/mmc, with disordered MoO{sub 4} tetrahedra and 2D distribution of CsO bonds that makes thermal axial expansion both large (50??{sub l}?70 10{sup ?6} C{sup ?1}, 500800 C) and highly anisotropic (?{sub c}??{sub a}=6710{sup ?6} C{sup ?1}, hexagonal form). The difference with the fuel's expansion coefficient is of potential concern with respect to the cohesion of the Cs{sub 2}MoO{sub 4} surface film and the possible release of cesium radionuclides in accidental situations. - Graphical abstract: The weakness of the CsO bonds and the disordering of the MoO{sub 4} tetrahedra array in the high-temperature form are responsible for the huge thermal expansion of Cs{sub 2}MoO{sub 4} along the c-axis. - Highlights: Thermomechanical behavior of Cs{sub 2}MoO{sub 4} fission products compound is studied. High-temperature form of Cs{sub 2}MoO{sub 4} is characterized by XRD and Raman. Thermal expansion appears very high and anisotropic. Cohesion between Cs{sub 2}MoO{sub 4} and nuclear fuel seems questionable, and Cs release is expected.

  2. Evaluation of polymer-coated CsI:Tl as an alpha/beta pulse shape discriminating flow cell

    SciTech Connect (OSTI)

    Chotoo, S.D.; DeVol, T.A.; Fjeld, R.A.

    1997-08-01

    A pulse shape discriminating flow-cell radiation detection system constructed with polymer-coated CsI:Tl was evaluated for simultaneous gross alpha/gross beta quantification. The CsI:Tl scintillator was crushed and sieved to 63--90-{micro}m particle size and encapsulated with Parylene C to slow its dissolution rate. Averaged over the first hour of use, the pulse shape discrimination figure of merit was 1.4, and the detection efficiencies ({+-}1{sigma}) were 64.9 {+-} 5.7%, 52.5 {+-} 4.5%, and 4.5 {+-} 0.2% for {sup 233}U, {sup 90}Sr/{sup 90}Y, and {sup 14}C, respectively. The typical background count rates in the alpha and beta pulse shape window were 0.004 and 0.17 cps, respectively. The resultant minimum detectable activities ({+-}1{sigma}) for a 30-s count time were calculated to be 0.19 {+-} 0.01 Bq, 0.9 {+-} 0.1 Bq, and 11.4 {+-} 0.6 Bq for {sup 233}U, {sup 90}Sr/{sup 90}Y, and {sup 14}C, respectively. Although the 3-{micro}m-thick encapsulation slowed CsI:Tl dissolution, the detection efficiency declined by a factor of two after 4.8 h, while the pulse shape resolution degraded slightly. With an appropriate coating, CsI:Tl is a good candidate for a heterogeneous pulse shape discriminating flow-cell.

  3. Production of monoclonal antibody (MoAB) CS-1 against platelet glycoprotein IIb-IIIa (GP IIb-IIIa)

    SciTech Connect (OSTI)

    Ramsamooj, P.; Morris, M.; Doellgast, G.; Hantgan, R.

    1987-05-01

    Platelet aggregation is mediated by the binding of fibrinogen (FGN) to the platelet GP IIb-IIIa complex. Receptor complex was purified from a solubilized platelet membrane fraction followed by lentil-lectin affinity chromatography and gel filtration. SDS-PAGE showed the product to be the complex, GP IIb-IIIa; light scattering intensity measurements indicated a Ca/sup 2 +/-dependent complex of the appropriate MW. Purified complex was then used to raise antibodies in Balb-c mice by standard hybridoma technology; positive cells were found by ELISA enabling the detection of antibody concentrations as low as 3 ng/ml. The MoABs were purified from both culture supernatant and ascites fluid by ion exchange and protein-A affinity chromatography. Western blotting determined that CS-1 is specific for nonreduced GP IIIa but not reduced GP IIIa or any form of GP IIb. CS-1 inhibited binding of radiolabeled FGN to ADP-stimulated platelets by 40-50% over a concentration range of 5-70 ..mu..g/ml. Flow cytometric analysis confirmed that CS-1 recognized a protein on the surface of both resting and stimulated platelets. The determined specificity of CS-1 and its limited ability to inhibit FGN binding to platelets make this MoAB useful for analysis of the structural and functional relationships between fibrin(ogen) and GP IIb-IIIa.

  4. Design, Development and Operational Experience of Demonstration Facility for Cs-137 Source Pencil Production at Trombay - 13283

    SciTech Connect (OSTI)

    Patil, S.B.; Srivastava, P.; Mishra, S.K.; Khan, S.S.; Nair, K.N.S.

    2013-07-01

    Radioactive waste management is a vital aspect of any nuclear program. The commercial feasibility of the nuclear program largely depends on the efficiency of the waste management techniques. One of such techniques is the separation of high yield radio-nuclides from the waste and making it suitable for medical and industrial applications. This will give societal benefit in addition to revenue generation. Co-60, the isotope presently being used for medical applications, needs frequent replacement because of its short half life. Cs-137, the major constituent of the nuclear waste, is a suitable substitute for Co-60 as a radioactive source because of its longer half life (28 years). Indian nuclear waste management program has given special emphasis on utilization of Cs-137 for such applications. In view of this a demonstration facility has been designed for vitrification of Cs-137 in borosilicate glass, cast in stainless steel pencils, to be used as source pencils of 300 Ci strength for blood irradiation. An induction heated metallic melter of suitable capacity has been custom designed for the application and employed for the Cs-137 pencil fabrication facility. This article describes various systems, design features, experiments and resulting modifications, observations and remote handling features necessary for the actual operation of such facility. The layout of the facility has been planned in such a way that the same can be adopted in a hot cell for commercial production of source pencils. (authors)

  5. Environmental effects of fog oil and CS usage at the Combat Maneuver Training Center, Hohenfels, Germany. [2-chlorophenylmethylene

    SciTech Connect (OSTI)

    Brubaker, K.L.; Rosenblatt, D.H.; Snyder, C.T.

    1992-03-01

    In response to environmental concerns at the Combat Maneuver Training Center (CMTC), Hohenfels, Germany, the US Army 7th Army Training Command commissioned a scientific study by Argonne National Laboratory to investigate specific issues. The study involved three parts: (1) a field study to determine if fog oil and CS (a compound named after its discoverers, B.B. Carson and R.W. Stoughton) were accumulating in the CMTC environment, (2) a screening of selected soil samples for the presence of US Environmental Protection Agency priority pollutants, and (3) a literature review of the health effects of fog oil and CS, as well as a review of training practices at CMTC. No fog oil or fog oil degradation products were detected in any soil, sediment, or vegetation sample collected at CMTC. Trace quantities of one or more priority pollutants were tentatively detected in three of eight soil and sediment samples. However, the priority pollutant concentrations are so low that they pose no environmental or health hazards. No evidence of widespread or significant contamination in the training areas was found. Crucial data needed to fully evaluate both acute and chronic health effects of civilian exposures to CS at CMTC are not available. On the basis of the available literature, long-ten-n health effects in the civilian population near CMTC that could result from the use of fog oil and CS during training activities are believed to be negligible.

  6. Cation ordering and effect of biaxial strain in double perovskite CsRbCaZnCl6

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pilania, G.; Uberuaga, B. P.

    2015-03-19

    Here, we investigate the electronic structure, energetics of cation ordering, and effect of biaxial strain on double perovskite CsRbCaZnCl6 using first-principles calculations based on density functional theory. The two constituents (i.e., CsCaCl3 and RbZnCl3) forming the double perovskite exhibit a stark contrast. While CsCaCl3 is known to exist in a cubic perovskite structure and does not show any epitaxial strain induced phase transitions within an experimentally accessible range of compressive strains, RbZnCl3 is thermodynamically unstable in the perovskite phase and exhibits ultra-sensitive response at small epitaxial strains if constrained in the perovskite phase. We show that combining the two compositionsmore » in a double perovskite structure not only improves overall stability but also the strain-polarization coupling of the material. Our calculations predict a ground state with P4/nmm space group for the double perovskite, where A-site cations (i.e., Cs and Rb) are layer-ordered and B-site cations (i.e., Ca and Zn) prefer a rocksalt type ordering. The electronic structure and bandgap in this system are shown to be quite sensitive to the B-site cation ordering and is minimally affected by the ordering of A-site cations. We find that at experimentally accessible compressive strains CsRbCaZnCl6 can be phase transformed from its paraelectric ground state to an antiferroelectric state, where Zn atoms contribute predominantly to the polarization. Furthermore, both energy difference and activation barrier for a transformation between this antiferroelectric state and the corresponding ferroelectric configuration are predicted to be small. As a result, the computational approach presented here opens a new pathway towards a rational design of novel double perovskites with improved strain response and functionalities.« less

  7. Temperature and composition phase diagram in the iron-based ladder compounds Ba 1 - x Cs x Fe 2 Se 3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hawai, Takafumi; Nambu, Yusuke; Ohgushi, Kenya; Du, Fei; Hirata, Yasuyuki; Avdeev, Maxim; Uwatoko, Yoshiya; Sekine, Yurina; Fukazawa, Hiroshi; Ma, Jie; et al

    2015-05-28

    We investigated the iron-based ladder compounds (Ba,Cs)Fe₂Se₃. Their parent compounds BaFe₂Se₃ and CsFe₂Se₃ have different space groups, formal valences of Fe, and magnetic structures. Electrical resistivity, specific heat, magnetic susceptibility, x-ray diffraction, and powder neutron diffraction measurements were conducted to obtain a temperature and composition phase diagram of this system. Block magnetism observed in BaFe₂Se₃ is drastically suppressed with Cs doping. In contrast, stripe magnetism observed in CsFe₂Se₃ is not so fragile against Ba doping. A new type of magnetic structure appears in intermediate compositions, which is similar to stripe magnetism of CsFe₂Se₃, but interladder spin configuration is different. Intermediatemore » compounds show insulating behavior, nevertheless a finite T-linear contribution in specific heat was obtained at low temperatures.« less

  8. Fiscal year 1995 laboratory scale studies of Cs elution in Tank 8D-1 and sludge dissolution in tank 8D-2

    SciTech Connect (OSTI)

    Sills, J.A.; Patello, G.K.; Roberts, J.S.; Wiemers, K.D.; Elmore, M.R.; Richmond, W.G.; Russell, R.L.

    1996-04-01

    During Phase I of West Valley Demonstration project waste remediation, an estimated 95% of the zeolite currently in tank 8D-1 will be transferred to tank 8D-2, leaving behind residual Cs-loaded zeolite which will require treatment to remove the Cs. After phase I vitrification, tank 8D-2 will contain residual waste from PUREX and THOREX and spent Cs-loaded zeolite. The residual waste will require treatment. Oxalic acid has been proposed for eluting Cs from zeolite in tank 8D-1 and dissolving radionuclides in tank 8D-2. Laboratory tests were performed to determine optimum Cs elution and sludge dissolution conditions and to evaluate effects of multiple contacts, long-term contacts, presence of corrosion products, lack of agitation, temperature of tank contents, and oxalic acid concentration. Mild steel corrosion tests were also conducted.

  9. Cancer incidence and community exposure to air emissions from petroleum and chemical plants in Contra Costa County, California: A critical epidemiological assessment

    SciTech Connect (OSTI)

    Otto Wong ); Bailey, W.J.

    1993-12-01

    The northern part of Contra Costa County, California is heavily industrialized with a number of petroleum refineries, chemical facilities and other small industrial plants. Several epidemiological studies have been conducted in the country to assess cancer risk in relation to estimated air pollution levels. In this paper, the air monitoring data, air pollution modeling and the epidemiologic studies are critically reviewed. The association between cancer risk and estimated emissions is critically evaluated. The role of occupational and lifestyle (such as cigarette smoking and diet) confounding exposures is also assessed. The importance of validating exposure data generated by air pollution models in epidemiologic studies is emphasized. Pollutants of major concern are sulfur dioxide, nitrogen oxides, and hydrocarbons.

  10. High-quality permanent draft genome sequence of Bradyrhizobium sp. Ai1a-2; a microsymbiont of Andira inermis discovered in Costa Rica

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tian, Rui; Parker, Matthew; Seshadri, Rekha; Reddy, T. B. K.; Markowitz, Victor; Ivanova, Natalia; Pati, Amrita; Woyke, Tanja; Baeshen, Mohammed; Baeshen, Nabih; et al

    2015-06-14

    Bradyrhizobium sp. Ai1a-2 is is an aerobic, motile, Gram-negative, non-spore-forming rod that was isolated from an effective nitrogen fixing root nodule of Andira inermis collected from Tres Piedras in Costa Rica. In this report we describe, for the first time, the genome sequence information and annotation of this legume microsymbiont. The 9,029,266 bp genome has a GC content of 62.56% with 247 contigs arranged into 246 scaffolds. The assembled genome contains 8,482 protein-coding genes and 102 RNA-only encoding genes. Lastly, this rhizobial genome was sequenced as part of the DOE Joint Genome Institute 2010 Genomic Encyclopedia for Bacteria and Archaea-Rootmore » Nodule Bacteria (GEBA-RNB) project proposal.« less

  11. Progress report for FACETS (Framework Application for Core-Edge Transport Simulations): C.S. SAP

    SciTech Connect (OSTI)

    Epperly, T W

    2008-10-01

    The mission of the Computer Science Scientific Application Partnership (C.S. SAP) at LLNL is to develop and apply leading-edge scientific component technology to FACETS software. Contributions from LLNL's fusion energy program staff towards the underlying physics modules are described in a separate report. FACETS uses component technology to combine selectively multiple physics and solver software modules written in different languages by different institutions together in an tightly-integrated, parallel computing framework for Tokamak reactor modeling. In the past fiscal year, the C.S. SAP has focused on two primary tasks: applying Babel to connect UEDGE into the FACETS framework through UEDGE's existing Python interface and developing a next generation componentization strategy for UEDGE which avoids the use of Python. The FACETS project uses Babel to solve its language interoperability challenges. Specific accomplishments for the year include: (1) Refined SIDL interfaces for UEDGE to meet satisfy the standard interfaces required by FACETS for all physics modules. This required consensus building between framework and UEDGE developers. (2) Wrote prototype C++ driver for UEDGE to demonstrate how UEDGE can be called from C++ using Babel. (3) Supported the FACETS project by adding new features to Babel such as release number tagging, porting to new machines, and adding new configuration options. Babel modifications were delivered to FACETS by testing and publishing development snapshots in the projects software repository. (4) Assisted Tech-X Corporation in testing and debugging of a high level build system for the complete FACETS tool chain--the complete list of third-party software libraries that FACETS depends on directly or indirectly (e.g., MPI, HDF5, PACT, etc.). (5) Designed and implemented a new approach to wrapping UEDGE as a FACETS component without requiring Python. To get simulation results as soon as possible, our initial connection from the FACETS

  12. Structure of a highly acidic β-lactamase from the moderate halophile Chromohalobacter sp. 560 and the discovery of a Cs{sup +}-selective binding site

    SciTech Connect (OSTI)

    Arai, Shigeki; Yonezawa, Yasushi; Okazaki, Nobuo; Matsumoto, Fumiko; Shibazaki, Chie; Shimizu, Rumi; Yamada, Mitsugu; Adachi, Motoyasu; Tamada, Taro; Kawamoto, Masahide; Tokunaga, Hiroko; Ishibashi, Matsujiro; Blaber, Michael; Tokunaga, Masao; Kuroki, Ryota

    2015-03-01

    The tertiary structure of a β-lactamase derived from the halobacterium Chromohalobacter sp. 560 (HaBLA) was determined by X-ray crystallography. Three unique Sr{sup 2+}-binding sites and one Cs{sup +}-binding site were discovered in the HaBLA molecule. Environmentally friendly absorbents are needed for Sr{sup 2+} and Cs{sup +}, as the removal of the radioactive Sr{sup 2+} and Cs{sup +} that has leaked from the Fukushima Nuclear Power Plant is one of the most important problems in Japan. Halophilic proteins are known to have many acidic residues on their surface that can provide specific binding sites for metal ions such as Cs{sup +} or Sr{sup 2+}. The crystal structure of a halophilic β-lactamase from Chromohalobacter sp. 560 (HaBLA) was determined to resolutions of between 1.8 and 2.9 Å in space group P3{sub 1} using X-ray crystallography. Moreover, the locations of bound Sr{sup 2+} and Cs{sup +} ions were identified by anomalous X-ray diffraction. The location of one Cs{sup +}-specific binding site was identified in HaBLA even in the presence of a ninefold molar excess of Na{sup +} (90 mM Na{sup +}/10 mM Cs{sup +}). From an activity assay using isothermal titration calorimetry, the bound Sr{sup 2+} and Cs{sup +} ions do not significantly affect the enzymatic function of HaBLA. The observation of a selective and high-affinity Cs{sup +}-binding site provides important information that is useful for the design of artificial Cs{sup +}-binding sites that may be useful in the bioremediation of radioactive isotopes.

  13. Spectroscopy identification performance enhancement of a novel CZT/CsI hybrid system

    SciTech Connect (OSTI)

    Russ, W.; Nakazawa, D.; Hau, I.; Morichi, M.

    2011-07-01

    New hybrid spectroscopic systems directly combine spectra from detectors with very different energy resolutions, accommodating standard analyses of the output hybrid spectrum. Simulations of a hybrid system consisting of a 2 or 4 cm{sup 3} cadmium zinc telluride detector combined with a 32.8 cm{sup 3} CsI(Tl) were evaluated for identification performance. 29 nuclides of interest for security applications were simulated as singles and unique pairs, producing 435 spectral simulations at live times of 3, 10, 30, 100 and 300 seconds. The nuclides were modeled as point sources at 25 cm with activities that provide an interesting range of statistical significance for the range of counting times. Standard nuclide identification analyses were applied to the component detectors as well as the hybrid combination. Tallies of the results were used to calculate true and false identification rates. The hybrid system was shown to provide an identification performance benefit, consistently achieving performances closest to ideal relative to the separate component detectors. The hybrid approach enables the consideration of a greater variety of measurement system solutions in terms of cost and performance. (authors)

  14. Heavy ion beam induced charge transfer in Ar-Cs mixtures

    SciTech Connect (OSTI)

    Murnick, D.E.; Gernhauser, R.; Ulrich, A.; Krotz, W.; Wieser, J.

    1993-12-01

    In situ production of target ions in cold, dense matter by heavy ion collisions and subsequent selective charge transfer may provide an effective pumping scheme for heavy ion beam pumped lasers. Charge transfer from cesium atoms to doubly charged argon ions was used for selective population of 4d-levels in Ar II. The argon ions were produced in an argon-cesium gas target by a pulsed beam of 100 MeV {sup 32}S{sup 8+} ions from the Munich Tandem van de Graaff accelerator. The ion beam of 12 {times} 10{sup 6} ions/pulse had a pulse width of 2 ns and a repetition rate of 32 kHz. The argon pressure was typically 250 mbar. The cesium partial pressure was adjusted by heating the gas target, including a cesium reservoir, to temperatures between 250 and 500{degrees}C. Time resolved wavelength spectra showed large intensity increases corresponding to 4d {sup 4}D and 4d {sup 4}F to 4p transitions in Ar II in the ultraviolet wavelength region between 300 and 400 nm. This is interpreted as a resonant charge transfer of outer electrons of cesium to 4d levels in Ar II in Cs{sup 0} + Ar{sup 2+} collisions.

  15. Radiocesium ([sup 137]Cs) from the Chernobyl reactor in Eurasian woodcock and earthworms in Norway

    SciTech Connect (OSTI)

    Kalas, J.A. ); Bretten, S.; Njastad, O. ); Byrkjedal, I. )

    1994-01-01

    To understand the ecological effects of the Chernobyl reactor accident, we investigated radiocesium ([sup 137]Cs) levels in Eurasian woodcock (Scolopax rusticola), earthworms (Lambricidae), litter (dead organic materials lying on the ground), humus (beneath litter 2 cm deep), and mineral soil samples (3-6 cm deep) from a heavily effected (20-60 kBq/m[sup 2][1 Bq = 1 nuclear fission/sec]) area in Norway. The highest concentrations measured in earthworms (1988 median = 142 Bq/Kg) and woodcock (1986 median = 730 Bq/kg) for human food (600 Bq/kg fresh mass) only were found in woodcock during 1986. Radiocesium concentrations decreased (P < 0.001) in earthworms (40%) and woodcock (95%) from 1986 to 1990. There was no reduction in total radiocesium in soil over the same period. The relatively high radiocesium concentrations in woodcock during 1986 and the decreasing radiocesium ratio in woodcock to earthworms during the first years following fallout could have been caused by woodcock ingesting abiotic radiocesium with earthworms. The decrease in radiocesium in woodcock and earthworms during the study (1986-90) probably resulted from decreasing bioavailability of radiocesium during the first years after fallout rather than by radiocesium disappearing from the ecosystem. 38 refs., 3 figs., 2 tabs.

  16. Characterization of high-voltage cathodes in CsBr-LiBr-KBr eutectic electrolyte

    SciTech Connect (OSTI)

    GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.

    2000-04-20

    The transition-metal oxides LiMn{sub 2}O{sub 4}, MnO{sub 2}, CrO{sub 2}, and LiCoO{sub 2} were evaluated for possible use as high-voltage cathodes for potential geothermal power applications. These were coupled with Li(Si) anodes and a low-melting CsBr-LiBr-KBr eutectic electrolyte that melts at 228.5 C. Single-cell tests at 250 C and 300 C at 15.8 and 31.6 mA/cm{sup 2} showed that MnO{sub 2} performed the best overall and had the lowest polarization. A 5-cell battery test using LiMn{sub 2}O{sub 4} cathodes was only modestly successful due to possible parasitic chemical reactions between the cathode and electrolyte at the much higher temperature (500 C) during discharge. The overall energy densities for these cathode were still less than for FeS{sub 2}.

  17. Conditioning and Repackaging of Spent Radioactive Cs-137 and Co-60 Sealed Sources in Egypt - 13490

    SciTech Connect (OSTI)

    Hasan, M.A.; Selim, Y.T.; El-Zakla, T.

    2013-07-01

    Radioactive Sealed sources (RSSs) are widely use all over the world in medicine, agriculture, industry, research, etc. The accidental misuse and exposure to RSSs has caused significant environmental contamination, serious injuries and many deaths. The high specific activity of the materials in many RSSs means that the spread of as little as microgram quantities can generate significant risk to human health and inhibit the use of buildings and land. Conditioning of such sources is a must to protect humans and environment from the hazard of ionizing radiation and contamination. Conditioning is also increase the security of these sources by decreasing the probability of stolen and/or use in terrorist attacks. According to the law No.7/2010, Egyptian atomic energy authority represented in the hot laboratories and waste management center (centralized waste facility, HLWMC) has the responsibility of collecting, conditioning, storing and management of all types of radioactive waste from all Egyptian territory including spent radioactive sealed sources (SRSSs). This paper explains the conditioning procedures for two of the most common SRSSs, Cs{sup 137} and Co{sup 60} sources which make up more than 90% of the total spent radioactive sealed sources stored in our centralized waste facility as one of the major activities of hot laboratories and waste management center. Conditioning has to meet three main objectives, be acceptable for storage, enable their safe transport, and comply with disposal requirements. (authors)

  18. Intrinsic quantum anomalous Hall effect in the kagome lattice Cs2LiMn3F12

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Gang; Lian, Biao; Zhang, Shou -Cheng

    2015-10-27

    In a kagome lattice, the time reversal symmetry can be broken by a staggered magnetic flux emerging from ferromagnetic ordering and intrinsic spin-orbit coupling, leading to several well-separated nontrivial Chern bands and intrinsic quantum anomalous Hall effect. Based on this idea and ab initio calculations, we propose the realization of the intrinsic quantum anomalous Hall effect in the single layer Cs2Mn3F12 kagome lattice and on the (001) surface of a Cs2LiMn3F12 single crystal by modifying the carrier coverage on it, where the band gap is around 20 meV. Furthermore, a simplified tight binding model based on the in-plane ddσ antibondingmore » states is constructed to understand the topological band structures of the system.« less

  19. Comparison of CsBr and KBr coated Cu photocathodes: Effects of laser irradiation and work function changes

    SciTech Connect (OSTI)

    He, Weidong; VilayurGanapathy, Subramanian; Joly, Alan G.; Droubay, Timothy C.; Chambers, Scott A.; Maldonado, Juan R.; Hess, Wayne P.

    2013-02-20

    Thin films (7 nm layers) of CsBr and KBr were deposited on Cu(100) to investigate photoemission properties of these potential photocathode materials. After thin film deposition and prolonged laser ultraviolet (UV) irradiation (266 nm picosecond laser) photoemission quantum efficiency increases by factors of 26 and 77 for KBr/Cu(100) and CsBr/Cu(100) photocathodes, respectively. Immediately following thin film deposition, a decrease in work function is observed, compared to bare Cu, in both cases. Quantum efficiency enhancements are attributed to the decrease in photocathode work function, due to the deposition of alkali halide thin films, and photo-induced processes, that introduce defect states into the alkali halide bandgap, induced by UV laser irradiation. It is possible that alkali metal formation occurs during UV irradiation and that this further contributes to photoemission enhancement. Our results suggest that KBr, a relatively stable alkali-halide, has potential for photocathode applications.

  20. Comparison of {sup 241}Am, {sup 239,240}Pu, and {sup 137}Cs concentrations in soil around Rocky Flats

    SciTech Connect (OSTI)

    Hulse, S.E.; Ibrahim, S.A.; Whicker, F.W.; Chapman, P.L.

    1999-03-01

    Gamma spectroscopy measurements were used to estimate concentrations of {sup 241}Am and {sup 137}Cs in soil profiles to depths of 21 cm at on-site and off-site locations around the Rocky Flats Environmental Technology Site and at regional background locations east of the Front Range between Colorado`s borders with New Mexico and Wyoming. Concentrations of these radionuclides were compared with concentrations of {sup 239,240}Pu in the same samples. Concentrations of {sup 241}Am in soil from depths of 0 to 3 cm decreased in an easterly direction from more than 5.3 kBq kg{sup {minus}1} 5 to 7 km away at a rate that was nearly proportional to the inverse square of distance. Deposits of {sup 137}Cs were ubiquitous, averaging 0.12 kBq kg{sup {minus}1} in soil from depths of 0 to 3 cm, but were unevenly distributed around Rocky Flats and the regional background locations. Deviations from the uniform exponential rate at which soil concentrations of {sup 137}Cs typically decreased with depth, {minus}0.25 cm{sup {minus}1} at undisturbed sites, enabled the authors to determine that about 10% of their sampling sites had been disturbed by erosion, tillage, or other factors. The mean rate at which {sup 239,240}Pu decreased with depth was about the same, {minus}0.23 cm{sup {minus}1}, throughout the study area. Soil concentrations of {sup 241}Am decreased with depth at a similar mean rate of {minus}0.22 cm{sup {minus}1} at locations close to the 903 pad where measurements were robust. Ratios between {sup 241}Am or {sup 239,240}Pu and {sup 137}Cs proved more useful for delineating the extent and pattern of contamination from Rocky Flats than did activity concentrations in soil.

  1. ASSESSMENT OF 90SR AND 137CS PENETRATION INTO REINFORCED CONCRETE (EXTENT OF 'DEEPENING') UNDER NATURAL ATMOSPHERIC CONDITIONS

    SciTech Connect (OSTI)

    Farfan, E.; Jannik, T.

    2011-10-01

    When assessing the feasibility of remediation following the detonation of a radiological dispersion device or improvised nuclear device in a large city, several issues should be considered including the levels and characteristics of the radioactive contamination, the availability of resources required for decontamination, and the planned future use of the city's structures and buildings. Currently, little is known about radionuclide penetration into construction materials in an urban environment. Knowledge in this area would be useful when considering costs of a thorough decontamination of buildings, artificial structures, and roads in an affected urban environment. Pripyat, a city substantially contaminated by the Chernobyl Nuclear Power Plant accident in April 1986, may provide some answers. The main objective of this study was to assess the depth of {sup 90}Sr and {sup 137}Cs penetration into reinforced concrete structures in a highly contaminated urban environment under natural weather conditions. Thirteen reinforced concrete core samples were obtained from external surfaces of a contaminated building in Pripyat. The concrete cores were drilled to obtain sample layers of 0-5, 5-10, 10-15, 15-20, 20-30, 30-40, and 40-50 mm. Both {sup 90}Sr and {sup 137}Cs were detected in the entire 0-50 mm profile of the reinforced cores sampled. In most of the cores, over 90% of the total {sup 137}Cs inventory and 70% of the total {sup 90}Sr inventory was found in the first 0-5 mm layer of the reinforced concrete. {sup 90}Sr had penetrated markedly deeper into the reinforced concrete structures than {sup 137}Cs.

  2. Evaluation of polymer-coated CsI:Tl as an alpha/beta pulse shape discriminating flow-cell

    SciTech Connect (OSTI)

    Branton, S.D.; Fjeld, R.A.; DeVol, T.A.

    1996-12-31

    A pulse shape discriminating flow-cell radiation detection system constructed with polymer coated CsI:Tl was evaluated for simultaneous gross alpha/gross beta quantification. The CsI:TI scintillator was crushed and sieved to 63-90 {mu}m particle size and microencapsulated with Parylene C to reduce its rate of dissolution. Averaged over the first hour of use, the pulse shape discrimination figure-of-merit was 1.4 and the detection efficiencies were 64.9 {+-} 5.7 %, 52.5 {+-} 4.5 % and 4.5 {+-} 0.2 % for {sup 233}U, {sup 90}Sr/{sup 90}Y and {sup 14}C , respectively. The typical background count rate in the alpha and beta pulse shape window was 0.17 and 0.004 cps, respectively. The resultant minimum detectable activity for a 30 second count time was calculated to be 0.19 {+-} 0.01 Bq, 0.9 {+-} 0.1 Bq and 11.4 {+-} 0.6 Bq for {sup 233}U, {sup 90}Sr/{sup 90}Y and {sup 14}C, respectively. Although the 3 {mu}m thick microencapsulation reduced CsI:Tl dissolution, the detection efficiency declined by a factor of two after 4.8 hours while the pulse shape resolution degraded slightly.

  3. Colloid-Facilitated Transport of 137Cs in Fracture-Fill Material. Experiments and Modeling

    SciTech Connect (OSTI)

    Dittrich, Timothy M.; Reimus, Paul William

    2015-10-29

    In this study, we demonstrate how a combination of batch sorption/desorption experiments and column transport experiments were used to effectively parameterize a model describing the colloid-facilitated transport of Cs in the Grimsel granodiorite/FFM system. Cs partition coefficient estimates onto both the colloids and the stationary media obtained from the batch experiments were used as initial estimates of partition coefficients in the column experiments, and then the column experiment results were used to obtain refined estimates of the number of different sorption sites and the adsorption and desorption rate constants of the sites. The desorption portion of the column breakthrough curves highlighted the importance of accounting for adsorption-desorption hysteresis (or a very nonlinear adsorption isotherm) of the Cs on the FFM in the model, and this portion of the breakthrough curves also dictated that there be at least two different types of sorption sites on the FFM. In the end, the two-site model parameters estimated from the column experiments provided excellent matches to the batch adsorption/desorption data, which provided a measure of assurance in the validity of the model.

  4. A new ab initio potential energy surface and infrared spectra for the Ar–CS{sub 2} complex

    SciTech Connect (OSTI)

    Yuan, Ting; Sun, Xueli; Hu, Yi; Zhu, Hua

    2014-09-14

    We report a new three-dimensional potential energy surface for Ar–CS{sub 2} involving the Q{sub 3} normal mode for the υ{sub 3} antisymmetric stretching vibration of the CS{sub 2} molecule. The potential energies were calculated using the supermolecular method at the coupled-cluster singles and doubles level with noniterative inclusion of connected triples, using augmented correlation-consistent quadruple-zeta basis set plus midpoint bond functions. Two vibrationally averaged potentials with CS{sub 2} at both the ground (υ = 0) and the first excited (υ = 1)υ{sub 3} vibrational states were generated from the integration of the three-dimensional potential over the Q{sub 3} coordinate. Each potential was found to have a T-shaped global minimum and two equivalent linear local minima. The radial discrete variable representation /angular finite basis representation method and the Lanczos algorithm were applied to calculate the rovibrational energy levels. The calculated band origin shift of the complex (0.0622 cm{sup −1}) is very close to the observed one (0.0671 cm{sup −1}). The predicted infrared spectra and spectroscopic parameters based on the two averaged potentials are in excellent agreement with the available experimental data.

  5. Magnetic excitations in the spin-1/2 triangular-lattice antiferromagnet Cs2CuBr4

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zvyagin, S. A.; Ozerov, M.; Kamenskyi, D.; Wosnitza, J.; Krzystek, J.; Yoshizawa, D.; Hagiwara, M.; Hu, Rongwei; Ryu, Hyejin; Petrovic, C.; et al

    2015-11-27

    We present on high- field electron spin resonance (ESR) studies of magnetic excitations in the spin- 1/2 triangular-lattice antiferromagnet Cs2CuBr4. Frequency- field diagrams of ESR excitations are measured for different orientations of magnetic fields up to 25 T. We show that the substantial zero- field energy gap, Δ ≈ 9.5 K, observed in the low-temperature excitation spectrum of Cs2CuBr4 [Zvyagin et al:, Phys. Rev. Lett. 112, 077206 (2014)], is present well above TN. Noticeably, the transition into the long-range magnetically ordered phase does not significantly affect the size of the gap, suggesting that even below TN the high-energy spin dynamicsmore » in Cs2CuBr4 is determined by short-range-order spin correlations. The experimental data are compared with results of model spin-wave-theory calculations for spin-1/2 triangle-lattice antiferromagnet.« less

  6. Crystal structure and thermal expansion of a CsCe2Cl7 scintillator

    SciTech Connect (OSTI)

    Zhuravleva, M.; Lindsey, A.; Chakoumakos, B. C.; Custelcean, R.; Meilleur, F.; Hughes, R. W.; Kriven, W. M.; Melcher, C. L.

    2015-04-06

    Here we used single-crystal X-ray diffraction data to determine crystal structure of CsCe2Cl7. It crystallizes in a P1121/b space group with a = 19.352(1) Å, b = 19.352(1) Å, c = 14.838(1) Å, γ = 119.87(2) ° , and V = 4818.6(5) Å3. Differential scanning calorimetry measurements combined with the structural evolution of CsCe2Cl7 via X-ray diffractometry over a temperature range from room temperature to the melting point indicates no obvious intermediate solid-solid phase transitions. The anisotropy in the average linear coefficient of thermal expansion of the a axis (21.3 10-6/ °C) with respect to the b and c axes (27.0 10-6/ °C) was determined through lattice parameter refinement of the temperature dependent diffraction patterns. Lastly, these findings suggest that the reported cracking behavior during melt growth of CsCe2Cl7 bulk crystals using conventional Bridgman and Czochralski techniques may be largely attributed to the anisotropy in thermal expansion.

  7. Cs-doped Mo as surface converter for H{sup −}/D{sup −} generation in negative ion sources: First steps and proof of principle

    SciTech Connect (OSTI)

    Schiesko, L. Hopf, C.; Höschen, T.; Meisl, G.; Encke, O.; Franzen, P.; Heinemann, B.; Hopf, C.; Fantz, U.; Cartry, G.; Achkasov, K.

    2015-04-08

    In a proof-of-principle study, molybdenum samples were implanted with a very small dose of Cs in order to test the properties of the compound as a surface converter for negative hydrogen ion production. First results on the properties of Cs doped Mo compounds show a reduction of the work function and a stable H{sup −} yield up to four hours in low density hydrogen plasma. The implanted Cs atoms were stable in the Mo lattice over one year for samples stored in vacuum and not exposed to the plasma. The surface H{sup −} generation mechanisms were identified and a comparison of the negative ion yield with pure Mo showed that the Cs doped Mo sample’s yield was much larger.

  8. A full dimensional investigation of infrared spectroscopy of the RbCs dimer using the multi-configuration time-dependent Hartree method

    SciTech Connect (OSTI)

    Wang, Huihui; Yang, Yonggang Xiao, Liantuan; Jia, Suotang

    2013-12-28

    The geometry and infrared absorption spectrum of (RbCs){sub 2} have been studied by full dimensional quantum dynamics simulations. For this purpose, the potential energy and dipole moment surfaces are generated by means of a cluster expansion with all two and three mode correlations, and fitted to analytical expressions with negligible deviations. Accordingly, the ground state (RbCs){sub 2} has a diamond geometry with D{sub 2h} symmetry. The infrared spectrum with frequencies up to 120 cm{sup −1}, exhibits rich details of the fundamentals, overtones, and combination bands; the highest fundamental frequency of (RbCs){sub 2} is only 40.26 cm{sup −1}. The present study unravels important details of the interactions between the widely investigated ultracold RbCs molecules.

  9. Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-367 EDF Trading North America, LLC (EDF)

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE):  Application of EDF Trading North America, LLC (EDF) to export electric energy to Canada

  10. Novel defect pyrochlores ABi/sub 2/B/sub 5/O/sub 16/ (A = Cs, Rb; B = Ta, Nb)

    SciTech Connect (OSTI)

    Ehlert, M.K., Greedan, J.E.; Subramanian, M.A.

    1988-07-01

    The crystal structures of three oxides with compositions CsBi/sub 2/Nb/sub 5/O/sub 16/, CsBi/sub 2/Ta/sub 5/O/sub 16/, and RbBi/sub 2/Ta/sub 5/O/sub 16/ have been determined from powder neutron diffraction data. A common structure of the defect pyrochlore types has been found. Atomic positions in space group Fd3m are 3.2 O and 3.2 Cs(Rb) in 8b, 6.4 Bi in 16d, 16 Ta(Nb) in 16c, and 48 O in 48f. There is some evidence that the Rb atoms actually occupy 32e sites. On electrostatic grounds it is highly unlikely that the Cs(Rb) and O atoms are randomly distributed in 8b. Evidence for short-range order is apparent in the X-ray powder diffraction data. Cell constants are 10.528(1) A (Cs, Nb), 10.504(1) A (Cs, Ta), and 10.510(2) A (Rb, Ta), respectively, with 48f x parameters 0.3139(2) (Cs, Nb), 0.3152(2) (Cs, Ta), and 0.3153(2) (Rb, Ta). Isotropic temperature factors for the 8b and 16d site atoms ranged from 3 to 6 (A)/sup 2/. These large values suggest anharmonic behavior or high mobility for some of the ions. Evidence for this is found in the presence of significant dielectric loss effects in all of the compounds studied.

  11. Distribution and Ratios of 137Cs and K in Control and K-treated Coconut Trees at Bikini Island where Nuclear Test Fallout Occurred: Effects and Implications

    SciTech Connect (OSTI)

    Robison, W L; Brown, P H; Stone, E L; Hamilton, T F; Conrado, C L; Kehl, S R

    2008-05-19

    Coconut trees growing on atolls of the Bikini Islands are on the margin of K deficiency because the concentration of exchangeable K in coral soil is very low ranging from only 20 to 80 mg kg{sup -1}. When provided with additional K, coconut trees absorb large quantities of K and this uptake of K significantly alters the patterns of distribution of {sup 137}Cs within the plant. Following a single K fertilization event, mean total K in trunks of K-treated trees is 5.6 times greater than in trunks of control trees. In contrast, {sup 137}Cs concentration in trunks of K-treated and control trees is statistically the same while {sup 137}Cs is significantly lower in edible fruits of K treated trees. Within one year after fertilization (one rainy season), K concentration in soil is back to naturally, low concentrations, however, the tissue concentrations of K in treated trees stays very high internally in the trees for years while {sup 137}Cs concentration in treated trees remains very low in all tree compartments except for the trunk. Potassium fertilization did not change soil Cs availability. Mass balance calculations suggest that the fertilization event increased above ground plant K content by at least a factor of 5 or 2.2 kg. Potassium concentrations and content were higher in all organs of K fertilized trees with the greatest increases seen in organs that receive a portion of tissue K through xylem transport (trunk, fronds and fruit husks) and lowest in organs supplied predominantly with K via the phloem (palm heart, spathe, coco meat and fluid). {sup 137}Cesium concentrations and contents were dramatically lower in all organs of K treated trees with greatest proportional reductions observed in organs supplied predominantly with K via the phloem (palm heart, spathe, coco meat and fluid). All trees remobilize both K and {sup 137}Cs from fronds as they proceed toward senescence. In control trees the reduction in concentration of K and {sup 137}Cs in fronds as they age

  12. Temperature-dependent structural study of microporous CsAlSi{sub 5}O{sub 12}

    SciTech Connect (OSTI)

    Fisch, Martin; Armbruster, Thomas Kolesov, Boris

    2008-03-15

    CsAlSi{sub 5}O{sub 12} crystals were synthesized at high temperature by slow cooling of a vanadium oxide flux. Single-crystal X-ray diffraction structure analysis and electron microprobe analyses yielded the microporous CAS zeolite framework structure of Cs{sub 0.85}Al{sub 0.85}Si{sub 5.15}O{sub 12} composition. High-temperature single-crystal and powder X-ray diffraction studies were utilized to analyze anisotropic thermal expansion. Rietveld refined cell constants from powder diffraction data, measured in steps of 25 deg. C up to 700 deg. C, show a significant decrease in expansion above 500 deg. C. At 500 deg. C, a displacive, static disorder-dynamic disorder-type phase transition from the acentric low-temperature space group Ama2 to centrosymmetric Amam (Cmcm in standard setting) was found. Thermal expansion below the phase transition is governed by rigid-body TO{sub 4} rotations accompanied by stretching of T-O-T angles. Above the phase transition at 500 deg. C all atoms, except one oxygen (O6), are fixed on mirror planes. Temperature-dependent polarized Raman single-crystal spectra between -270 and 300 deg. C and unpolarized spectra between room temperature and 1000 deg. C become increasingly less resolved with rising temperature confirming the disordered static-disordered dynamic type of the phase transition. - Graphical abstract: Temperature-dependent structural evolution of microporous CsAlSi{sub 5}O{sub 12} has been investigated by single-crystal and powder X-ray diffraction, as well as Raman spectroscopy. Results yielded a phase transition of order-disorder type.

  13. Light output measurements and computational models of microcolumnar CsI scintillators for x-ray imaging

    SciTech Connect (OSTI)

    Nillius, Peter Klamra, Wlodek; Danielsson, Mats; Sibczynski, Pawel; Sharma, Diksha; Badano, Aldo

    2015-02-15

    Purpose: The authors report on measurements of light output and spatial resolution of microcolumnar CsI:Tl scintillator detectors for x-ray imaging. In addition, the authors discuss the results of simulations aimed at analyzing the results of synchrotron and sealed-source exposures with respect to the contributions of light transport to the total light output. Methods: The authors measured light output from a 490-?m CsI:Tl scintillator screen using two setups. First, the authors used a photomultiplier tube (PMT) to measure the response of the scintillator to sealed-source exposures. Second, the authors performed imaging experiments with a 27-keV monoenergetic synchrotron beam and a slit to calculate the total signal generated in terms of optical photons per keV. The results of both methods are compared to simulations obtained with hybridMANTIS, a coupled x-ray, electron, and optical photon Monte Carlo transport package. The authors report line response (LR) and light output for a range of linear absorption coefficients and describe a model that fits at the same time the light output and the blur measurements. Comparing the experimental results with the simulations, the authors obtained an estimate of the absorption coefficient for the model that provides good agreement with the experimentally measured LR. Finally, the authors report light output simulation results and their dependence on scintillator thickness and reflectivity of the backing surface. Results: The slit images from the synchrotron were analyzed to obtain a total light output of 48 keV{sup ?1} while measurements using the fast PMT instrument setup and sealed-sources reported a light output of 28 keV{sup ?1}. The authors attribute the difference in light output estimates between the two methods to the difference in time constants between the camera and PMT measurements. Simulation structures were designed to match the light output measured with the camera while providing good agreement with the

  14. Diminished cage effect in solid p-H{sub 2}: Infrared spectra of ClSCS, ClCS, and ClSC in an irradiated p-H{sub 2} matrix containing Cl{sub 2} and CS{sub 2}

    SciTech Connect (OSTI)

    Huang, Chiung-Wei; Lee, Yaw-Chang; Lee, Yuan-Pern

    2010-04-28

    Irradiation of a p-H{sub 2} matrix containing Cl{sub 2} and CS{sub 2} at 3.3 K with laser emission at 340 nm followed by annealing of the matrix produced main features at 1479.5 and 1480.8 cm{sup -1}. These lines are attributed to {nu}{sub 1} (SCS antisymmetric stretching) mode of ClSCS. Irradiation of the matrix at 355 nm decomposes ClSCS. Products CS (1272.2 and 1271.1 cm{sup -1}), ClCS (1193.9/1191.9 and 637.5 cm{sup -1}), and ClSC (1137.0 cm{sup -1}) were observed upon annealing. The assignments were based on comparison of observed vibrational wavenumbers and {sup 13}C- and {sup 34}S-isotopic ratios with those predicted with density-functional theories (B3LYP and BPW91/aug-cc-pVTZ). These results demonstrate that the cage effect of solid p-H{sub 2} is diminished so that isolated Cl was produced via photodissociation of Cl{sub 2} in situ and subsequently reacted with CS{sub 2} to form ClSCS, but not ClC(=S)SCl, upon annealing; typically ClC(=S)SCl was produced as the major product on irradiation of noble-gas matrices containing Cl{sub 2} and CS{sub 2}. Observation of ClSCS but not ClCS{sub 2} is consistent with the theoretical prediction that only formation of the former proceeds via a barrierless path. Similarly, upon irradiation of ClSCS at 355 nm, Cl, CS, and CS{sub 2} were produced; subsequent annealing of the irradiated matrix produced ClSC and ClCS via barrierless paths.

  15. CHANGES IN 137 CS CONCENTRATIONS IN SOIL AND VEGETATION ON THE FLOODPLAIN OF THE SAVANNAH RIVER OVER A 30 YEAR PERIOD

    SciTech Connect (OSTI)

    Paller, M.; Jannik, T.; Fledderman, P.

    2007-12-12

    {sup 137}Cs released during 1954-1974 from nuclear production reactors on the Savannah River Site, a US Department of Energy nuclear materials production site in South Carolina, contaminated a portion of the Savannah River floodplain known as Creek Plantation. {sup 137}Cs activity concentrations have been measured in Creek Plantation since 1974 making it possible to calculate effective half-lives for {sup 137}Cs in soil and vegetation and assess the spatial distribution of contaminants on the floodplain. Activity concentrations in soil and vegetation were higher near the center of the floodplain than near the edges as a result of frequent inundation coupled with the presence of low areas that trapped contaminated sediments. {sup 137}Cs activity was highest near the soil surface, but depth related differences diminished with time as a likely result of downward diffusion or leaching. Activity concentrations in vegetation were significantly related to concentrations in soil. The plant to soil concentration ratio (dry weight) averaged 0.49 and exhibited a slight but significant tendency to decrease with time. The effective half-lives for {sup 137}Cs in shallow (0-7.6 cm) soil and in vegetation were 14.9 (95% CI = 12.5-17.3) years and 11.6 (95% CI = 9.1-14.1) years, respectively, and rates of {sup 137}Cs removal from shallow soil and vegetation did not differ significantly among sampling locations. Potential health risks on the Creek Plantation floodplain have declined more rapidly than expected on the basis of radioactive decay alone because of the relatively short effective half-life of {sup 137}Cs.

  16. The impact of size distribution assumptions in a bulk one-moment microphysics scheme on simulated surface precipitation and storm dynamics during a low-topped supercell case in Belgium

    SciTech Connect (OSTI)

    Van Weverberg, K.; VanLipzig, N. P. M.; Delobbe, L.

    2011-04-01

    In this research the impact of modifying the size distribution assumptions of the precipitating hydrometeors in a bulk one-moment microphysics scheme on simulated surface precipitation and storm dynamics has been explored for long-lived low-topped supercells in Belgium. It was shown that weighting the largest precipitating ice species of the microphysics scheme to small graupel results in an increase of surface precipitation because of counteracting effects. On the one hand, the precipitation formation process slowed down, resulting in lower precipitation efficiency. On the other hand, latent heat release associated with freezing favored more intense storms. In contrast to previous studies finding decreased surface precipitation when graupel was present in the microphysics parameterization, storms were rather shallow in the authors simulations. This left little time for graupel sublimation. The impact of size distribution assumptions of snow was found to be small, but more realistic size distribution assumptions of rain led to the strongest effect on surface precipitation. Cold pools shrunk because of weaker rain evaporation at the cold pool boundaries, leading to a decreased surface rain area.

  17. Inclusion property of Cs, Sr, and Ba impurities in LiCl crystal formed by layer-melt crystallization

    SciTech Connect (OSTI)

    Choi, Jung-Hoon; Cho, Yung-Zun; Lee, Tae-Kyo; Eun, Hee-Chul; Kim, Jun-Hong; Park, Hwan-Seo; Kim, In-Tae; Park, Geun-Il

    2013-07-01

    Pyroprocessing is one of the promising technologies enabling the recycling of spent nuclear fuels from a commercial light water reactor (LWR). In general, pyroprocessing uses dry molten salts as electrolytes. In particular, LiCl waste salt after pyroprocessing contains highly radioactive I/II group fission products mainly composed of Cs, Sr, and Ba impurities. Therefore, it is beneficial to reuse LiCl salt in the pyroprocessing as an electrolyte for economic and environmental issues. Herein, to understand the inclusion property of impurities within LiCl crystal, the physical properties such as lattice parameter change, bulk modulus, and substitution enthalpy of a LiCl crystal having 0-6 at% Cs{sup +} or Ba{sup 2+} impurities under existence of 1 at% Sr{sup 2+} impurity were calculated via the first-principles density functional theory. The substitution enthalpy of LiCl crystals having 1 at% Sr{sup 2+} showed slightly decreased value than those without Sr{sup 2+} impurity. Therefore, through the substitution enthalpy calculation, it is expected that impurities will be incorporated within LiCl crystal as co-existed form rather than as a single component form. (authors)

  18. The Ground State of (CS)4 Is Different from that of (CO)4: An Experimental Test of a Computational Prediction by Negative Ion Photoelectron Spectroscopy

    SciTech Connect (OSTI)

    Zhang, Jian; Hrovat, David; Sun, Zhenrong; Bao, Xiaoguang; Borden, Weston; Wang, Xue B.

    2013-08-22

    Cyclobutane-1,2,3,4-tetrathione, (CS)4, has recently been calculated to have a singlet ground state, 1A1g, in which the highest b2g  MO is doubly occupied and the lowest a2u  MO is empty. Thus, (CS)4 is predicted to have a different ground state than its lighter congener, (CO)4, which has a triplet ground state, 3B1u, in which these two MOs are each singly occupied. Here we report the results of a negative ion photoelectron spectroscopy (NIPES) study of the radical anion (CS)4●-, designed to test the prediction that (CS)4 has a singlet ground state. The NIPE spectrum reveals that (CS)4 does, indeed, have a singlet ground state with electron affinity (EA) = 3.75 eV. The lowest triplet state is found to lie 0.31 eV higher in energy than the ground state, and the open-shell singlet is 0.14 eV higher in energy than the triplet state. Calculations at the (U)CCSD(T)/aug-cc-pVTZ//(U)B3LYP/6-311+G(2df) level support the spectral assignments, giving EA = 3.71 eV, EST = 0.44 eV. These calculated values are, respectively, 0.04 eV (0.9 kcal/mol) smaller, and 0.13 eV (3.0 kcal/mol) larger than the corresponding experimental values. In addition, RASPT2 calculations with various active spaces converge on a 1B1u-3B1u energy gap of 0.137 eV, in excellent agreement with the 0.14 eV energy difference obtained from the NIPE spectrum. Finally, calculations of the Franck-Condon factors for transitions from the ground state of (CS)4●- to the ground (1A1g) and two excited states (3B1u, 1B1u) of (CS)4 account for all of the major spectral peaks, and nicely reproduce vibrational structure observed in each electronic transition. The close correspondence between the calculated and the observed features in the NIPE spectrum of (CS)4●- provides unequivocal proof that (CS)4, unlike (CO)4, has a singlet ground state.

  19. Novel apo E-derived ABCA1 agonist peptide (CS-6253) promotes reverse cholesterol transport and induces formation of preβ-1 HDL in vitro

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hafiane, Anouar; Bielicki, John K.; Johansson, Jan O.; Genest, Jacques; Zhu, Xuewei

    2015-07-24

    Apolipoprotein (apo) mimetic peptides replicate some aspects of HDL function. We have previously reported the effects of compound ATI-5261 on its ability to replicate many functions of native apo A-I in the process of HDL biogenesis. ATI-5261 induced muscle toxicity in wild type C57Bl/6 mice, increased CPK, ALT and AST and increase in triglyceride (Tg) levels. Aromatic phenylalanine residues on the non-polar face of ATI-5261, together with positively charged arginine residues at the lipid-water interface were responsible for these effects. This information was used to create a novel analog (CS-6253) that was non-toxic. We evaluated this peptide designed from themore » carboxyl terminus of apo E, in its ability to mimic apo A-I functionality. Our data shows that the lipidated particles generated by incubating cells overexpressing ABCA1 with lipid free CS-6253 enhances the rate of ABCA1 lipid efflux with high affinity interactions with native ABCA1 oligomeric forms and plasma membrane micro-domains. Interaction between ABCA1 and lipid free CS-6253 resulted in formation of nascent HDL-CS-6253 particles that are actively remodeled in plasma. Mature HDL-CS-6253 particles deliver cholesterol to liver cells via SR-BI in-vitro. CS-6253 significantly increases cholesterol efflux in murine macrophages and in human THP-1 macrophage-derived foam cells expressing ABCA1. Addition of CS-6253 to plasma dose-dependently displaced apo A-I from α-HDL particles and led to de novo formation of preβ-1 HDL that stimulates ABCA1 dependent cholesterol efflux efficiently. When incubated with human plasma CS-6253 was also found to bind with HDL and LDL and promoted the transfer of cholesterol from HDL to LDL predominantly. Our data shows that CS-6253 mimics apo A-I in its ability to promote ABCA1-mediated formation of nascent HDL particles, and enhances formation of preβ-1 HDL with increase in the cycling of apo A-I between the preβ and α-HDL particles in-vitro. These mechanisms are

  20. SU-E-I-11: Cascaded Linear System Model for Columnar CsI Flat Panel Imagers with Depth Dependent Gain and Blur

    SciTech Connect (OSTI)

    Peng, B; Lubinsky, A; Zheng, H; Zhao, W; Teymurazyan, A

    2014-06-01

    Purpose: To implement a depth dependent gain and blur cascaded linear system model (CLSM) for optimizing columnar structured CsI indirect conversion flat panel imager (FPI) for advanced imaging applications. Methods: For experimental validation, depth dependent escape efficiency, e(z), was extracted from PHS measurement of different CsI scintillators (thickness, substrate and light output). The inherent MTF and DQE of CsI was measured using high resolution CMOS sensor. For CLSM, e(z) and the depth dependent MTF(f,z), were estimated using Monte Carlo simulation (Geant4) of optical photon transport through columnar CsI. Previous work showed that Monte Carlo simulation for CsI was hindered by the non-ideality of its columnar structure. In the present work we allowed variation in columnar width with depth, and assumed diffusive reflective backing and columns. Monte Carlo simulation was performed using an optical point source placed at different depth of the CsI layer, from which MTF(z,f) and e(z) were computed. The resulting e(z) with excellent matching with experimental measurements were then applied to the CLSM, Monte Carlo simulation was repeated until the modeled MTF, DQE(f) also match experimental measurement. Results: For a 150 micron FOS HL type CsI, e(z) varies between 0.56 to 0.45, and the MTF at 14 cycles/mm varies between 62.1% to 3.9%, from the front to the back of the scintillator. The overall MTF and DQE(f) at all frequencies are in excellent agreement with experimental measurements at all frequencies. Conclusion: We have developed a CLSM for columnar CsI scintillators with depth dependent gain and MTF, which were estimated from Monte Carlo simulation with novel optical simulation settings. Preliminary results showed excellent agreement between simulation results and experimental measurements. Future work is aimed at extending this approach to optimize CsI screen optic design and sensor structure for achieving higher DQE(f) in cone-beam CT, which uses

  1. Cs{sub 3}Zr{sub 6}Br{sub 15}Z (Z = C, B): A stuffed rhombohedral perovskite structure of linked clusters

    SciTech Connect (OSTI)

    Qi, Ru-Yi; Corbett, J.D.

    1995-03-29

    The isostructural title compounds are synthesized in good yields form reactions of Zr, ZrBr{sub 4}, CsBr, and Z in sealed Ta tubing for {approximately}3 weeks at 850 {degrees}C. Their single-crystal data refinements established the products as Cs{sub 3.02(7)-}Zr{sub 6}Br{sub 14}C and Cs{sub 3.39(5)}Zr{sub 6}br{sub 15}B (R3c, Z = 6, a = 13.1031 (6), 13.116(1) {angstrom}, c = 35.800(3), 35.980(6) {angstrom}, R(F)/R{sub w} = 5.4/5.9, 5.4/4.4%, respectively). The structure is derived form a three-dimensional [Zr{sub 6}(Z)Br{sub 12}]Br{sub 6/2} network of four-rings (as in ReO{sub 6/2}) twisted into a rhombohedral perovskite analogous to VF{sub 3}. The three necessary Cs{sup +} cations are fractionally distributed over five sites that are far from optimal or common, with either eight asymmetric or only three close bromide neighbors. Refinement of a third Cs{sub 3.18(5)}Zr{sub 6}Br{sub 15}C structure at {minus}50 {degrees}C gave the same result with somewhat smaller positional distributions of the atoms.

  2. Burnup estimation of fuel sourcing radioactive material based on monitored Cs and Pu isotopic activity ratios in Fukushima N. P. S. accident

    SciTech Connect (OSTI)

    Yamamoto, T.; Suzuki, M.; Ando, Y.

    2012-07-01

    After the severe core damage of Fukushima Dai-Ichi Nuclear Power Station, radioactive material leaked from the reactor buildings. As part of monitoring of radioactivity in the site, measurements of radioactivity in soils at three fixed points have been performed for {sup 134}Cs and {sup 137}Cs with gamma-ray spectrometry and for Pu, Pu, and {sup 240}Pu with {alpha}-ray spectrometry. Correlations of radioactivity ratios of {sup 134}Cs to {sup 137}Cs, and {sup 238}Pu to the sum of {sup 239}Pu and {sup 240}Pu with fuel burnup were studied by using theoretical burnup calculations and measurements on isotopic inventories, and compared with the Cs and Pu radioactivity rations in the soils. The comparison indicated that the burnup of the fuel sourcing the radioactivity was from 18 to 38 GWd/t, which corresponded to that of the fuel in the highest power and, therefore, the highest decay heat in operating high-burnup fueled BWR cores. (authors)

  3. The radiation chemistry of CCD-PEG, a solvent-extraction process for Cs and Sr from dissolved nuclear fuel

    SciTech Connect (OSTI)

    Mincher, B.J.; Herbst, R.S.; Tillotson, R.D.; Mezyk, S.P.

    2008-07-01

    Cobalt dicarbollide and polyethylene glycol in phenyl-trifluoromethyl sulfone (HCCD/PEG in FS- 13) is currently under consideration for use in the process-scale selective extraction of fission- product cesium and strontium from dissolved nuclear fuel. This solvent will be exposed to high radiation doses during use and has not been adequately investigated for radiation stability. Here, HCCD/PEG was y-irradiated to various absorbed doses, to a maximum of 432 kGy, using {sup 60}Co. Irradiations were performed for the neat organic phase and also for the organic phase in contact with 1 M-nitric acid mixed by air sparging. Post-irradiation solvent-extraction measurements showed that Cs distribution ratios were unaffected; however, Sr extraction efficiency decreased with absorbed dose under both conditions and was greater when in contact with the aqueous phase. Stripping performance was not affected. A mechanism, initiated by direct radiolysis of the sulfone diluent, is proposed. (authors)

  4. Response of Cs2LiYCl6:Ce (CLYC) to High Energy Protons

    SciTech Connect (OSTI)

    Coupland, Daniel David Schechtman; Stonehill, Laura Catherine; Goett, John Jerome III

    2015-11-23

    Cs2LiYCl6:Ce (CLYC) is a promising new inorganic scintillator for gamma and neutron detection. As a gamma-ray detector, it exhibits bright light output and better resolution and proportionality of response than traditional gamma-ray scintillators such as NaI. It is also highly sensitive to thermal neutrons through capture on 6Li, and recent experiments have demonstrated sensitivity to fast neutrons through interactions with 35Cl. The response of CLYC to other forms of radiation has not been reported. We have performed the first measurements of the response of CLYC to several-hundred MeV protons. We have collected digitized waveforms from proton events, and compare to those produced by gammas and thermal neutrons. Finally, we discuss the potential for pulse shape discrimination between them.

  5. Radiochemical procedures for analysis of Pu, Am, Cs and Sr in water, soil, sediments and biota samples

    SciTech Connect (OSTI)

    Wong, K.M.; Jokela, T.A.; Noshkin, V.E.

    1994-02-01

    The Environmental Radioactivity Analysis Laboratory (ERAL) was established as an analytical facility. The primary function of ERAL is to provide fast and accurate radiological data of environmental samples. Over the years, many radiochemical procedures have been developed by the staffs of ERAL. As result, we have found that our procedures exist in many different formats and in many different notebooks, documents and files. Therefore, in order to provide for more complete and orderly documentation of the radiochemical procedures that are being used by ERAL, we have decided to standardize the format and compile them into a series of reports. This first report covers procedures we have developed and are using for the radiochemical analysis of Pu, Am, Cs, and Sr in various matrices. Additional analytical procedures and/or revisions for other elements will be reported as they become available through continuation of these compilation efforts.

  6. Comparison of the spectral response of a thinned, backside illuminated CCD with a CsI coated MCP system and Kodak 101 film

    SciTech Connect (OSTI)

    Li Yuelin; Crespo Lopex-Urrutia, J. R.; Tsakiris, G. D.; Sigel, R.; Volk, R.; Pina, L.

    1995-05-01

    A thinned backside illuminated CCD chip was calibrated by self consistently determining the thickness of its dead layer. Its spectral response and sensitivity were then compared with those of the calibrated Kodak 101 photographic plates and of a CsI coated microchannel plate detection system.

  7. A compact, discrete CsI(Tl) scintillator/Si photodiode gamma camera for breast cancer imaging

    SciTech Connect (OSTI)

    Gruber, Gregory J.

    2000-12-01

    Recent clinical evaluations of scintimammography (radionuclide breast imaging) are promising and suggest that this modality may prove a valuable complement to X-ray mammography and traditional breast cancer detection and diagnosis techniques. Scintimammography, however, typically has difficulty revealing tumors that are less than 1 cm in diameter, are located in the medial part of the breast, or are located in the axillary nodes. These shortcomings may in part be due to the use of large, conventional Anger cameras not optimized for breast imaging. In this thesis I present compact single photon camera technology designed specifically for scintimammography which strives to alleviate some of these limitations by allowing better and closer access to sites of possible breast tumors. Specific applications are outlined. The design is modular, thus a camera of the desired size and geometry can be constructed from an array (or arrays) of individual modules and a parallel hole lead collimator for directional information. Each module consists of: (1) an array of 64 discrete, optically-isolated CsI(Tl) scintillator crystals 3 x 3 x 5 mm{sup 3} in size, (2) an array of 64 low-noise Si PIN photodiodes matched 1-to-1 to the scintillator crystals, (3) an application-specific integrated circuit (ASIC) that amplifies the 64 photodiode signals and selects the signal with the largest amplitude, and (4) connectors and hardware for interfacing the module with a motherboard, thereby allowing straightforward computer control of all individual modules within a camera.

  8. Shape resonances in ground-state diatomic molecules: General trends and the example of RbCs

    SciTech Connect (OSTI)

    Londono, B. E.; Mahecha, J. E.; Luc-Koenig, E.; Crubellier, A.

    2010-07-15

    The presence of shape resonances due to tunneling through the centrifugal barrier modifies strongly the dynamics of cold atom scattering. As shown on the example of the ground and lowest triplet electronic states of the {sup 85}Rb{sup 133}Cs molecule, the crucial parameter is, as usual for cold collisions, the scattering length. A general description of shape resonances of diatomic molecules is given from three simple single channel asymptotic models, whose respective performances are discussed. The first model, which consists of a R{sup -6} potential limited at short range by a repulsive wall, positioned to reproduce the s-wave scattering length, accounts satisfactorily for the main system-independent properties of shape resonances. Introduction in the model of energy- and angular-momentum-dependent nodal lines specific to the inner part of the potential greatly improves its efficiency. When the energy and angular momentum dependence of the nodal lines cannot be deduced from full potential calculations or from experiment, a rough, but universal, estimate of these properties is obtained by extending the R{sup -6} behavior of the potential up to the origin.

  9. Quantum-noise-limited interferometric measurement of atomic noise: Towards spin squeezing on the Cs clock transition

    SciTech Connect (OSTI)

    Oblak, Daniel; Tittel, Wolfgang; Vershovski, Anton K.; Mikkelsen, Jens K.; Soerensen, Jens L.; Petrov, Plamen G.; Garrido Alzar, Carlos L.; Polzik, Eugene S.

    2005-04-01

    We investigate theoretically and experimentally a nondestructive interferometric measurement of the state population of an ensemble of laser-cooled and trapped atoms. This study is a step toward generation of (pseudo)spin squeezing of cold atoms targeted at the improvement of the cesium clock performance beyond the limit set by the quantum projection noise of atoms. We calculate the phase shift and the quantum noise of a near-resonant optical probe pulse propagating through a cloud of cold {sup 133}Cs atoms. We analyze the figure of merit for a quantum nondemolition (QND) measurement of the collective pseudospin and show that it can be expressed simply as a product of the ensemble optical density and the pulse-integrated rate of the spontaneous emission caused by the off-resonant probe light. Based on this, we propose a protocol for the sequence of operations required to generate and utilize spin squeezing for the improved atomic clock performance via a QND measurement on the probe light. In the experimental part we demonstrate that the interferometric measurement of the atomic population can reach a sensitivity of the order of {radical}(N{sub at}) in a cloud of N{sub at} cold atoms, which is an important benchmark toward the experimental realization of the theoretically analyzed protocol.

  10. Individual Radiological Protection Monitoring of Utrok Atoll Residents Based on Whole Body Counting of Cesium-137 (137Cs) and Plutonium Bioassay

    SciTech Connect (OSTI)

    Hamilton, T; Kehl, S; Brown, T; Martinelli, R; Hickman, D; Jue, T; Tumey, S; Langston, R

    2007-06-08

    This report contains individual radiological protection surveillance data developed during 2006 for adult members of a select group of families living on Utrok Atoll. These Group I volunteers all underwent a whole-body count to determine levels of internally deposited cesium-137 ({sup 137}Cs) and supplied a bioassay sample for analysis of plutonium isotopes. Measurement data were obtained and the results compared with an equivalent set of measurement data for {sup 137}Cs and plutonium isotopes from a second group of adult volunteers (Group II) who were long-term residents of Utrok Atoll. For the purposes of this comparison, Group II volunteers were considered representative of the general population on Utrok Atoll. The general aim of the study was to determine residual systemic burdens of fallout radionuclides in each volunteer group, develop data in response to addressing some specific concerns about the preferential uptake and potential health consequences of residual fallout radionuclides in Group I volunteers, and generally provide some perspective on the significance of radiation doses delivered to volunteers (and the general Utrok Atoll resident population) in terms of radiological protection standards and health risks. Based on dose estimates from measurements of internally deposited {sup 137}Cs and plutonium isotopes, the data and information developed in this report clearly show that neither volunteer group has acquired levels of internally deposited fallout radionuclides specific to nuclear weapons testing in the Marshall Islands that are likely to have any consequence on human health. Moreover, the dose estimates are well below radiological protection standards as prescribed by U.S. regulators and international agencies, and are very small when compared to doses from natural sources of radiation in the Marshall Islands and the threshold where radiation health effects could be either medically diagnosed in an individual or epidemiologically discerned in a

  11. Synthesis and structural characterization of the new clathrates K8Cd4Ge42, Rb8Cd4Ge42, and Cs8Cd4Ge42

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schafer, Marion; Bobev, Svilen

    2016-03-25

    This paper presents results from our exploratory work in the systems K-Cd-Ge, Rb-Cd-Ge, and Cs-Cd-Ge, which yielded the novel type-I clathrates with refined compositions K8Cd3.77(7)Ge42.23, Rb8Cd3.65(7)Ge42.35, and Cs7.80(1)Cd3.65(6)Ge42.35. The three compounds represent rare examples of clathrates of germanium with the alkali metals, where a d10 element substitutes a group 14 element. The three structures, established by single-crystal X-ray diffraction, indicate that the framework-building Ge atoms are randomly substituted by Cd atoms on only one of the three possible crystallographic sites. Furthermore, this and several other details of the crystal chemistry are elaborated.

  12. Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process

    SciTech Connect (OSTI)

    McCarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-06-01

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.

  13. Intrinsic quantum anomalous Hall effect in the kagome lattice Cs2LiMn3F12

    SciTech Connect (OSTI)

    Xu, Gang; Lian, Biao; Zhang, Shou -Cheng

    2015-10-27

    In a kagome lattice, the time reversal symmetry can be broken by a staggered magnetic flux emerging from ferromagnetic ordering and intrinsic spin-orbit coupling, leading to several well-separated nontrivial Chern bands and intrinsic quantum anomalous Hall effect. Based on this idea and ab initio calculations, we propose the realization of the intrinsic quantum anomalous Hall effect in the single layer Cs2Mn3F12 kagome lattice and on the (001) surface of a Cs2LiMn3F12 single crystal by modifying the carrier coverage on it, where the band gap is around 20 meV. Furthermore, a simplified tight binding model based on the in-plane ddσ antibonding states is constructed to understand the topological band structures of the system.

  14. Soil concentration, vertical distribution and inventory of plutonium, [sup 241]Am, [sup 90]Sr and [sup 137]Cs in the Marche Region of Central Italy

    SciTech Connect (OSTI)

    Jia, G.; Testa, C.; Desideri, D.; Guerra, F.; Meli, M.A.; Roselli, C. . Inst. of General Chemistry); Belli, M.E. )

    1999-07-01

    Soil concentrations of [sup 239+240]Pu, [sup 238]Pu, [sup 241]Am, [sup 90]Sr, and [sup 137]Cs are investigated in the Marche Region of Central Italy. Mean values in uncultivated soils are 3.5--8 times higher than the corresponding values in cultivated soils. Radionuclide inventories and ratios are consistent with values reported by the United nations Scientific Committee on the Effect of Atomic Radiation for this latitude. This suggests that radiocontamination in this region is mainly due to atmospheric deposition of nuclear weapon test fallout. The vertical distribution of these radionuclides is also studied. The results show that, with the exception of [sup 90]Sr, more than 90% of these radionuclides are contained in the first 20 cm of soil and that mobility follows the order [sup 90]Sr > [sup 241]Am > [sup 239+240]Pu, [sup 238]Pu > [sup 137]Cs.

  15. Performance of LiAlloy/Ag(2)CrO(4) Couples in Molten CsBr-LiBr-KBr Eutectic

    SciTech Connect (OSTI)

    GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.

    1999-10-18

    The performance of Li-alloy/CsBr-LiBr-KBr/Ag{sub 2}CrO{sub 4} systems was studied over a temperature range of 250 C to 300 C, for possible use as a power source for geothermal borehole applications. Single cells were discharged at current densities of 15.8 and 32.6 mA/cm{sup 2} using Li-Si and Li-Al anodes. When tested in 5-cell batteries, the Li-Si/CsBr-LiBr-KBr/Ag{sub 2}CrO{sub 4} system exhibited thermal runaway. Thermal analytical tests showed that the Ag{sub 2}CrO{sub 4} cathode reacted exothermically with the electrolyte on activation. Consequently, this system would not be practical for the envisioned geothermal borehole applications.

  16. Preliminary flowsheet: Ion exchange process for the separation of cesium from Hanford tank waste using Duolite{trademark} CS-100 resin

    SciTech Connect (OSTI)

    Eager, K.M.; Penwell, D.L.; Knutson, B.J.

    1994-12-01

    This preliminary flowsheet document describes an ion exchange process which uses Duolite{trademark} CS-100 resin to remove cesium from Hanford Tank waste. The flowsheet describes one possible equipment configuration, and contains mass balances based on that configuration with feeds of Neutralized Current Acid Waste, and Double Shell Slurry Feed. Process alternatives, unresolved issues, and development needs are discussed which relate to the process.

  17. Reversible uptake of COS, CS2 and SO2; Ionic liquids with O-alkylxanthate, O-alkylthiocarbonate, and O-alkylsulfite anions

    SciTech Connect (OSTI)

    Heldebrant, David J.; Yonker, Clement R.; Jessop, Philip G.; Phan, Lam

    2009-08-14

    Further development of CO2 binding organic liquids to capture and release carbonyl sulfide, carbon disulfide and sulfur dioxide. This paper investigates a brand new class of ionic liquids which have potential as chemical sensors for acid gas capture. Applications to flue gas scrubbing are discussed with an emphasis on capture and release of COS, CS2 and SO2 with amidine and guanidine bases with alcohols. Formal spectroscopic characterization is presented.

  18. Scintillation properties and electronic structure of the intrinsic and extrinsic mixed elpasolites Cs2 Na REBr3I3 (R = La, Y)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, Hua; Du, Mao -Hua; Stand, Luis; Zhao, Zhao; Zhuravleva, Mariya; Melcher, Charles L.; Shi, Hongliang

    2016-02-19

    Scintillators attract wide research interest for their distinct applications in radiation detection. Elpasolite halides are among the most promising scintillators due to their high structural symmetry and good scintillation performance. A better understanding of their underlying scintillation mechanism opens up possibilities in scintillator development. In this work, we employ a variety of experimental techniques to study the two mixed-anion elpasolites Cs2 Na REBr3I3 (R = La, Y). The emission of intrinsic Cs2Na RBr3I3 with a light yield ranging from 20 000 to 40 000 ph / MeV is dominant by self-trapped exciton emission. Partial substitution of R with Ce introducesmore » a competing emission, the Ce3+ 5d-to-4f radiative transition. Ab initio calculations are performed to investigate the electronic structures as well as the binding energies of polarons in Cs2 Na RBr6. The calculated large self-trapped exciton binding energies are consistent with the observed high light yield due to self-trapped exciton (STE) emission. The unique electronic structure of halide elpasolites as calculated enhances the STE stability and the STE emission. The highly tunable scintillation properties of mixed-anion elpasolites underscore the role of their complex scintillation mechanism. Furthermore, our study provides guidance for the design of elpasolite scintillators with exceptional energy resolution and light yield desirable for applications.« less

  19. I/S and C/S mixed layers, some indicators of recent physical-chemical changes in active geothermal systems: The case study of Chipilapa (El Salvador)

    SciTech Connect (OSTI)

    Beaufort, D.; Papapanagiotou, P.; patrier, P.; Fouillac, A.M.; Traineau, H.

    1996-01-24

    I/S and C/S mixed layers from the geothermal field of Chipilapa (El Salvador) have been studied in details in order to reevaluate their potential use as indicator of the thermodynamic conditions in which they were formed. It is funded that overprinting of clay bearing alteration stages is common. For a given alteration stage, the spatial variation of I/S and C/S mixed layer ininerals is controlled by kinetics of mixed layer transformation and not only by temperature. Clay geo-thermometers cannot give reliable results because the present crystal-chemical states of the I/S and C/S mixed layers is not their initial state, it was aquired during the overall hydrothermal history which post dated the nucleation of smectitic clay material at high temperature. Occurrences of smectites or smectite-rich mixed layers at high temperature in reservoirs is a promising guide for reconstruct the zones in which boiling or mixing of non isotherinal fluids occurred very recently or still presently.

  20. Scintillation properties and electronic structure of the intrinsic and extrinsic mixed elpasolites Cs2 Na RBr3I3 (R = La, Y)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, Hua; Du, Mao -Hua; Stand, Luis; Zhao, Zhao; Zhuravleva, Mariya; Melcher, Charles L.; Shi, Hongliang

    2016-02-19

    Scintillators attract wide research interest for their distinct applications in radiation detection. Elpasolite halides are among the most promising scintillators due to their high structural symmetry and good scintillation performance. A better understanding of their underlying scintillation mechanism opens up possibilities in scintillator development. In this work, we employ a variety of experimental techniques to study the two mixed-anion elpasolites Cs2NaRBr3I3 (R = La, Y). The emission of intrinsic Cs2NaRBr3I3 with a light yield ranging from 20 000 to 40 000 ph / MeV is dominant by self-trapped exciton emission. Partial substitution of R with Ce introduces a competing emission,more » the Ce3+ 5d-to-4f radiative transition. Ab initio calculations are performed to investigate the electronic structures as well as the binding energies of polarons in Cs2NaRBr6. The calculated large self-trapped exciton binding energies are consistent with the observed high light yield due to self-trapped exciton (STE) emission. The unique electronic structure of halide elpasolites as calculated enhances the STE stability and the STE emission. The highly tunable scintillation properties of mixed-anion elpasolites underscore the role of their complex scintillation mechanism. Furthermore, our study provides guidance for the design of elpasolite scintillators with exceptional energy resolution and light yield desirable for applications.« less

  1. Magnetic excitations in the spin-1/2 triangular-lattice antiferromagnet Cs2CuBr4

    SciTech Connect (OSTI)

    Zvyagin, S. A.; Ozerov, M.; Kamenskyi, D.; Wosnitza, J.; Krzystek, J.; Yoshizawa, D.; Hagiwara, M.; Hu, Rongwei; Ryu, Hyejin; Petrovic, C.; Zhitomirsky, M. E.

    2015-11-27

    We present on high- field electron spin resonance (ESR) studies of magnetic excitations in the spin- 1/2 triangular-lattice antiferromagnet Cs2CuBr4. Frequency- field diagrams of ESR excitations are measured for different orientations of magnetic fields up to 25 T. We show that the substantial zero- field energy gap, Δ ≈ 9.5 K, observed in the low-temperature excitation spectrum of Cs2CuBr4 [Zvyagin et al:, Phys. Rev. Lett. 112, 077206 (2014)], is present well above TN. Noticeably, the transition into the long-range magnetically ordered phase does not significantly affect the size of the gap, suggesting that even below TN the high-energy spin dynamics in Cs2CuBr4 is determined by short-range-order spin correlations. The experimental data are compared with results of model spin-wave-theory calculations for spin-1/2 triangle-lattice antiferromagnet.

  2. Temperature and pressure shift of the Cs clock transition in the presence of buffer gases: Ne, N{sub 2}, Ar

    SciTech Connect (OSTI)

    Kozlova, Olga; Guerandel, Stephane; Clercq, Emeric de

    2011-06-15

    The ground-state hyperfine resonance line of alkali-metal atoms is frequency shifted in the presence of noble or molecular gases. The buffer gases used in vapor-cell atomic clocks thus induce a temperature-dependent shift of the clock transition frequency. We report on measurements of the pressure and temperature dependence of the Cs clock transition frequency in the presence of Ne, Ar, and N{sub 2} buffer gases. The pressure in the sealed glass vapor cells is measured by means of the shift of the Cs D{sub 1} line. We have also investigated the temperature dependence of the optical shift. From these measurements, we infer the pressure and temperature coefficients of the hyperfine frequency shift. It is then possible to predetermine gas mixture ratios that cancel the temperature sensitivity at a given temperature. This prediction is confirmed experimentally for Ar-N{sub 2} mixtures. These results can be useful for improving the long-term frequency stability of Cs vapor-cell clocks.

  3. Cationic coordination compound Cs{sub 2}Hg{sub 3}I{sub 8} for IR NLO material: Synthesis, crystal growth and characterizations

    SciTech Connect (OSTI)

    Sathiskumar, S.; Kathiravan, P.; Balakrishnan, T.

    2015-06-24

    Single crystals Cs{sub 2}Hg{sub 3}I{sub 8} of dimensions 5 × 3 × 4   mm{sup 3} were grown by solution growth method at room temperature and structurally characterized by single crystal X – ray diffraction. Cs{sub 2}Hg{sub 3}I{sub 8} compound crystallizes in a noncentrosymmetric space group Cm with the crystal data of a = 7.4415 Å, b = 21.6629 Å, c = 7.6726 Å, α, β = 90°, γ = 108.05° and Z = 2. The grown crystals were characterized by powder X – ray diffraction analysis and the various diffraction planes are indexed. The presence of functional groups was identified qualitatively by Fourier transform infrared and FT – Raman spectral analyses. Ultraviolet – visible spectral analyses shows that the crystal has low UV cut off at 388 nm combined with very good transparency of 98 % in a wide range. The optical band gap was estimated to be 3 eV. Mechanical hardness of the grown crystal Cs{sub 2}Hg{sub 3}I{sub 8} was determined. The dielectric response of the crystal with varying frequencies was studied. Differential scanning calorimetry (DSC) analysis shows that the grown crystal has very good thermal stability up to 97.5°C.

  4. Mechanical environmental transport of actinides and ¹³⁷Cs from an arid radioactive waste disposal site

    SciTech Connect (OSTI)

    Snow, Mathew S.; Clark, Sue B.; Morrison, Samuel S.; Watrous, Matthew G.; Olson, John E.; Snyder, Darin C.

    2015-10-01

    Particulate transport represents an important mechanism for actinides and fission products at the Earth's surface; soil samples taken in the early 1970's near the Subsurface Disposal Area (SDA) at Idaho National Laboratory (INL) provide a case study for examining the mechanisms and characteristics of actinide transport under arid conditions. Transuranic waste was disposed via shallow land burial at the SDA until shortly after a flooding event that occurred in 1969. In this study we analyze soils collected in the early 1970's for ¹³⁷Cs, ²⁴¹Am, and Pu using a combination of radiometric and mass spectrometric techniques. Two distinct ²⁴⁰Pu/²³⁹Pu isotopic ratios are observed for contamination from the SDA, with values ranging from at least 0.059 to 0.069. ²⁴¹Am concentrations are observed to increase only slightly in 0-4 cm soils over the ~40 year period since soil sampling, contrary to Markham's previous hypothesis that ²⁴¹Pu is principally associated with the 0-4 cm soil fractions (Markham 1978). The lack of statistical difference in ²⁴¹Am/²³⁹⁺²⁴⁰Pu ratios with depth suggests mechanical transport and mixing discrete contaminated particles under arid conditions. Occasional samples beyond the northeastern corner are observed to contain anomalously high Pu concentrations with corresponding low ²⁴⁰Pu/²³⁹Pu atoms ratios, suggesting the occurrence of "hot particles;" application of a background Pu subtraction results in calculated Pu atom ratios for the "hot particles" which are statistically similar to those observed in the northeastern corner. Taken together, our data suggests that flooding resulted in mechanical transport of contaminated particles into the area between the SDA and the flood containment dike in the northeastern corner, following which subsequent contamination spreading resulted from wind transport of discrete particles.

  5. MEASURING THE ULTIMATE HALO MASS OF GALAXY CLUSTERS: REDSHIFTS AND MASS PROFILES FROM THE HECTOSPEC CLUSTER SURVEY (HeCS)

    SciTech Connect (OSTI)

    Rines, Kenneth; Geller, Margaret J.; Kurtz, Michael J.; Diaferio, Antonaldo E-mail: diaferio@ph.unito.it

    2013-04-10

    The infall regions of galaxy clusters represent the largest gravitationally bound structures in a {Lambda}CDM universe. Measuring cluster mass profiles into the infall regions provides an estimate of the ultimate mass of these halos. We use the caustic technique to measure cluster mass profiles from galaxy redshifts obtained with the Hectospec Cluster Survey (HeCS), an extensive spectroscopic survey of galaxy clusters with MMT/Hectospec. We survey 58 clusters selected by X-ray flux at 0.1 < z < 0.3. The survey includes 22,680 unique MMT/Hectospec redshifts for individual galaxies; 10,145 of these galaxies are cluster members. For each cluster, we acquired high signal-to-noise spectra for {approx}200 cluster members and a comparable number of foreground/background galaxies. The cluster members trace out infall patterns around the clusters. The members define a very narrow red sequence. We demonstrate that the determination of velocity dispersion is insensitive to the inclusion of bluer members (a small fraction of the cluster population). We apply the caustic technique to define membership and estimate the mass profiles to large radii. The ultimate halo mass of clusters (the mass that remains bound in the far future of a {Lambda}CDM universe) is on average (1.99 {+-} 0.11)M{sub 200}, a new observational cosmological test in essential agreement with simulations. Summed profiles binned in M{sub 200} and in L{sub X} demonstrate that the predicted Navarro-Frenk-White form of the density profile is a remarkably good representation of the data in agreement with weak lensing results extending to large radius. The concentration of these summed profiles is also consistent with theoretical predictions.

  6. Mechanical environmental transport of actinides and ¹³⁷Cs from an arid radioactive waste disposal site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Snow, Mathew S.; Clark, Sue B.; Morrison, Samuel S.; Watrous, Matthew G.; Olson, John E.; Snyder, Darin C.

    2015-10-01

    Particulate transport represents an important mechanism for actinides and fission products at the Earth's surface; soil samples taken in the early 1970's near the Subsurface Disposal Area (SDA) at Idaho National Laboratory (INL) provide a case study for examining the mechanisms and characteristics of actinide transport under arid conditions. Transuranic waste was disposed via shallow land burial at the SDA until shortly after a flooding event that occurred in 1969. In this study we analyze soils collected in the early 1970's for ¹³⁷Cs, ²⁴¹Am, and Pu using a combination of radiometric and mass spectrometric techniques. Two distinct ²⁴⁰Pu/²³⁹Pu isotopic ratiosmore » are observed for contamination from the SDA, with values ranging from at least 0.059 to 0.069. ²⁴¹Am concentrations are observed to increase only slightly in 0-4 cm soils over the ~40 year period since soil sampling, contrary to Markham's previous hypothesis that ²⁴¹Pu is principally associated with the 0-4 cm soil fractions (Markham 1978). The lack of statistical difference in ²⁴¹Am/²³⁹⁺²⁴⁰Pu ratios with depth suggests mechanical transport and mixing discrete contaminated particles under arid conditions. Occasional samples beyond the northeastern corner are observed to contain anomalously high Pu concentrations with corresponding low ²⁴⁰Pu/²³⁹Pu atoms ratios, suggesting the occurrence of "hot particles;" application of a background Pu subtraction results in calculated Pu atom ratios for the "hot particles" which are statistically similar to those observed in the northeastern corner. Taken together, our data suggests that flooding resulted in mechanical transport of contaminated particles into the area between the SDA and the flood containment dike in the northeastern corner, following which subsequent contamination spreading resulted from wind transport of discrete particles.« less

  7. Assessing the use of reflectance spectroscopy in determining CsCl stress in the model species Arabidopsis thaliana

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martinez, N. E.; Sharp, J. L.; Kuhne, W. W.; Johnson, T. E.; Stafford, C. T.; Duff, M. C.

    2015-11-23

    Here, reflectance spectroscopy is a rapid and non-destructive analytical technique that may be used for assessing plant stress, and has potential applications for use in remediation. Changes in reflectance such as that due to metal stress may occur before damage is visible, and existing studies have shown that metal stress does cause changes in plant reflectance. To further investigate the potential use of reflectance spectroscopy as a method for assessing metal stress in plants, an exploratory study was conducted in which Arabidopsis thaliana plants were treated twice weekly in a laboratory setting with varying levels (0, 0.5, or 5 mMmore » (millimolar)) of caesium chloride (CsCl) solution, and reflectance spectra were collected every week for three weeks using an Analytical Spectral Devices FieldSpec Pro spectroradiometer with both a contact probe (CP) and a field of view (FOV) probe at 36.8 and 66.7 cm, respectively, above the plant. Plants were harvested each week after spectra collection for determination of relative water content and chlorophyll content. A visual assessment of the plants was also conducted using point observations on a uniform grid of 81 points. A mixed-effects model analysis was conducted for each vegetation index (VI) considered to determine the effects of length of treatment, treatment level, view with which spectra were acquired, and the interactions of these terms. Two-way analyses of variance (ANOVAs) were performed on the aforementioned endpoints (e.g. chlorophyll content) to determine the significance of the effects of treatment level and length of treatment. Multiple linear regression (MLR) was used to develop a predictive model for each endpoint, considering VI acquired at each view (CP, high FOV, and low FOV). Of the 14 VI considered, 8 were included in the MLR models. Contact probe readings and FOV readings differed significantly, but FOV measurements were generally consistent at each height.« less

  8. Ts&Cs FP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the electronic document to ensure you are using the correct version. FP15 - PERFORMANCE EVALUATION PROGRAM In keeping with Sandia's goals of continuous improvement, and promoting...

  9. Ts&Cs FP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    furnished to the SDR or to the Requester if no Control : SF 6432-FP Title: Standard Terms and Conditions for Firm-Fixed Price Contracts Owner: Procurement Policy & Quality Dept...

  10. Ts&Cs FP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and vehicles entering or leaving Sandia's KAFB or Government's premises are subject to search. (e) Contractor will promptly notify Sandia and provide a report of any accidents or...