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1

Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer...  

Office of Environmental Management (EM)

Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification C.M. Jantzen and E.M. Pierce November 18, 2010 2 Participating Organizations 3...

2

INVESTIGATION OF FUEL CHEMISTRY AND BED PERFORMANCE IN A FLUIDIZED BED BLACK LIQUOR STEAM REFORMER  

SciTech Connect (OSTI)

The University of Utah project ''Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer'' (DOE award number DE-FC26-02NT41490) was developed in response to a solicitation for projects to provide technical support for black liquor and biomass gasification. The primary focus of the project is to provide support for a DOE-sponsored demonstration of MTCI's black liquor steam reforming technology at Georgia-Pacific's paper mill in Big Island, Virginia. A more overarching goal is to improve the understanding of phenomena that take place during low temperature black liquor gasification. This is achieved through five complementary technical tasks: (1) construction of a fluidized bed black liquor gasification test system, (2) investigation of bed performance, (3) evaluation of product gas quality, (4) black liquor conversion analysis and modeling and (5) computational modeling of the Big Island gasifier. Four experimental devices have been constructed under this project. The largest facility, which is the heart of the experimental effort, is a pressurized fluidized bed gasification test system. The system is designed to be able to reproduce conditions near the black liquor injectors in the Big Island steam reformer, so the behavior of black liquor pyrolysis and char gasification can be quantified in a representative environment. The gasification test system comprises five subsystems: steam generation and superheating, black liquor feed, fluidized bed reactor, afterburner for syngas combustion and a flue gas cooler/condenser. The three-story system is located at University of Utah's Industrial Combustion and Gasification Research Facility, and all resources there are available to support the research.

Kevin Whitty

2003-12-01T23:59:59.000Z

3

Durability Testing of Fluidized Bed Steam Reforming Products  

SciTech Connect (OSTI)

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

2005-07-01T23:59:59.000Z

4

Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer  

SciTech Connect (OSTI)

University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

Kevin Whitty

2007-06-30T23:59:59.000Z

5

FLUIDIZED BED STEAM REFORMING ENABLING ORGANIC HIGH LEVEL WASTE DISPOSAL  

SciTech Connect (OSTI)

Waste streams planned for generation by the Global Nuclear Energy Partnership (GNEP) and existing radioactive High Level Waste (HLW) streams containing organic compounds such as the Tank 48H waste stream at Savannah River Site have completed simulant and radioactive testing, respectfully, by Savannah River National Laboratory (SRNL). GNEP waste streams will include up to 53 wt% organic compounds and nitrates up to 56 wt%. Decomposition of high nitrate streams requires reducing conditions, e.g. provided by organic additives such as sugar or coal, to reduce NOX in the off-gas to N2 to meet Clean Air Act (CAA) standards during processing. Thus, organics will be present during the waste form stabilization process regardless of the GNEP processes utilized and exists in some of the high level radioactive waste tanks at Savannah River Site and Hanford Tank Farms, e.g. organics in the feed or organics used for nitrate destruction. Waste streams containing high organic concentrations cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by pretreatment. The alternative waste stabilization pretreatment process of Fluidized Bed Steam Reforming (FBSR) operates at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). The FBSR process has been demonstrated on GNEP simulated waste and radioactive waste containing high organics from Tank 48H to convert organics to CAA compliant gases, create no secondary liquid waste streams and create a stable mineral waste form.

Williams, M

2008-05-09T23:59:59.000Z

6

FLUIDIZED BED STEAM REFORMER (FBSR) PRODUCT: MONOLITH FORMATION AND CHARACTERIZATION  

SciTech Connect (OSTI)

The most important requirement for Hanford's low activity waste (LAW) form for shallow land disposal is the chemical durability of the product. A secondary, but still essential specification, is the compressive strength of the material with regards to the strength of the material under shallow land disposal conditions, e.g. the weight of soil overburden and potential intrusion by future generations, because the term ''near-surface disposal'' indicates disposal in the uppermost portion, or approximately the top 30 meters, of the earth's surface. The THOR{reg_sign} Treatment Technologies (TTT) mineral waste form for LAW is granular in nature because it is formed by Fluidized Bed Steam Reforming (FBSR). As a granular product it has been shown to be as durable as Hanford's LAW glass during testing with ASTM C-1285-02 known as the Product Consistency Test (PCT) and with the Single Pass Flow Through Test (SPFT). Hanford Envelope A and Envelope C simulants both performed well during PCT and SPFT testing and during subsequent performance assessment modeling. This is partially due to the high aluminosilicate content of the mineral product which provides a natural aluminosilicate buffering mechanism that inhibits leaching and is known to occur in naturally occurring aluminosilicate mineral analogs. In order for the TTT Na-Al-Si (NAS) granular mineral product to meet the compressive strength requirements (ASTM C39) for a Hanford waste form, the granular product needs to be made into a monolith or disposed of in High Integrity Containers (HIC's). Additionally, the Hanford intruder scenario for disposal in the Immobilized Low Activity Waste (ILAW) trench is mitigated as there is reduced intruder exposure when a waste form is in a monolithic form. During the preliminary testing of a monolith binder for TTT's FBSR mineral product, four parameters were monitored: (1) waste loading (not optimized for each waste form tested); (2) density; (3) compressive strength; and (4) durability must not be compromised--binding agent should not react with the NAS product and binding agent should not create an unfavorable pH environment that may cause accelerated leaching. It is the goal of the present study to survey cementitious waste forms based on Ordinary Portland Cement (OPC), Ceramicrete, and hydroceramic binders by correlating waste loading, density and compressive strength and then determine if these binders affect the product performance in terms of the PCT response. This will be done by making a one-to-one comparison of the PCT response measured on granular NAS mineral product (mixed bed and fines products) with the PCT response of the monolithed NAS product in the different binders. Future studies may include, refining the above binders, and examining other binders. It is likely that binders formed from kaolin would be most compatible with the chemistry of the THOR{reg_sign} mineral waste form which is made by steam reforming of kaolin and sodium rich wastes. The economics of production on a large scale have yet to be investigated for any of the binders tested.

Jantzen, C

2006-09-13T23:59:59.000Z

7

FLUIDIZED BED STEAM REFORMING FOR TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE  

SciTech Connect (OSTI)

This report is one of four reports written to provide background information regarding immobilization technologies remaining under consideration for supplemental immobilization of Hanford's low-activity waste. This paper provides the reader a general understanding of fluidized bed steam reforming and its possible application to treat and immobilize Hanford low-activity waste.

HEWITT WM

2011-04-08T23:59:59.000Z

8

Steam reformer with catalytic combustor  

DOE Patents [OSTI]

A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

Voecks, Gerald E. (La Crescenta, CA)

1990-03-20T23:59:59.000Z

9

Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes  

SciTech Connect (OSTI)

Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.

Jantzen, C. M.; Crawford, C. L.; Burket, P. R.; Bannochie, C. J.; Daniel, W. G.; Nash, C. A.; Cozzi, A. D.; Herman, C. C.

2012-10-22T23:59:59.000Z

10

Fluidized Bed Steam Reforming of INEEL SBW Using THORsm Mineralizing Technology  

SciTech Connect (OSTI)

Sodium bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Office’s (NE-ID) and State of Idaho’s top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). Many studies have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. DOE desired further experimental data, with regard to steam reforming technology, to make informed decisions concerning selection of treatment technology for SBW. Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was performed in a 15-cm-diameter reactor vessel September 27 through October 1, 2004. The pilot scale equipment is owned by the DOE, and located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Personnel from Science Applications International Corporation, owners of the STAR Center, operated the pilot plant. The pilot scale test was terminated as planned after achieving a total of 100 hrs of cumulative/continuous processing operation. About 230 kg of SBW surrogate were processed that resulted in about 88 kg of solid product, a mass reduction of about 62%. The process achieved about a 90% turnover of the starting bed. Samples of mineralized solid product materials were analyzed for chemical/physical properties. Results of product performance testing conducted by SRNL will be reported separately by SRNL.

Arlin L. Olson; Nicholas R. Soelberg; Douglas W. Marshall; Gary L. Anderson

2004-12-01T23:59:59.000Z

11

Fluidized Bed Steam Reforming of Hanford LAW Using THORsm Mineralizing Technology  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) documented, in 2002, a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified steam reforming technology as a candidate for supplemental treatment of as much as 70% of the low-activity waste (LAW). Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was completed in a 15-cm-diameter reactor vessel. The pilot scale facility was equipped with a highly efficient cyclone separator and heated sintered metal filters for particulate removal, a thermal oxidizer for reduced gas species and NOx destruction, and a packed activated carbon bed for residual volatile species capture. The pilot scale equipment is owned by the DOE, but located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Pilot scale testing was performed August 2–5, 2004. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Science Application International Corporation, owners of the STAR Center, personnel performed actual pilot scale operation. The pilot scale test achieved a total of 68.7 hrs of cumulative/continuous processing operation before termination in response to a bed de-fluidization condition. 178 kg of LAW surrogate were processed that resulted in 148 kg of solid product, a mass reduction of about 17%. The process achieved essentially complete bed turnover within approximately 40 hours. Samples of mineralized solid product materials were analyzed for chemical/physical properties. SRNL will report separately the results of product performance testing that were accomplished.

Olson, Arlin L.; Nicholas R Soelberg; Douglas W. Marshall; Gary L. Anderson

2004-11-01T23:59:59.000Z

12

Stabilization of Savannah River National Laboartory (SRNL) Aqueous Waste by Fluidized Bed Steam Reforming (FBSR)  

SciTech Connect (OSTI)

The Savannah River National Laboratory (SRNL) is a multidisciplinary laboratory operated by Westinghouse Savannah River Company (WSRC) in Aiken, South Carolina. Research and development programs have been conducted at SRNL for {approx}50 years generating non-radioactive (hazardous and non-hazardous) and radioactive aqueous wastes. Typically the aqueous effluents from the R&D activities are disposed of from each laboratory module via the High Activity Drains (HAD) or the Low Activity Drains (LAD) depending on whether they are radioactive or not. The aqueous effluents are collected in holding tanks, analyzed and shipped to either H-Area (HAD waste) or the F/H Area Effluent Treatment Facility (ETF) (LAD waste) for volume reduction. Because collection, analysis, and transport of LAD and HAD waste is cumbersome and since future treatment of this waste may be curtailed as the F/H-Area evaporators and waste tanks are decommissioned, SRNL laboratory operations requested several proof of principle demonstrations of alternate technologies that would define an alternative disposal path for the aqueous wastes. Proof of principle for the disposal of SRNL HAD waste using a technology known as Fluidized Bed Steam Reforming (FBSR) is the focus of the current study. The FBSR technology can be performed either as a batch process, e.g. in each laboratory module in small furnaces with an 8'' by 8'' footprint, or in a semi-continuous Bench Scale Reformer (BSR). The proof of principle experiments described in this study cover the use of the FBSR technology at any scale (pilot or full scale). The proof of principle experiments described in this study used a non-radioactive HAD simulant.

Jantzen, C

2004-11-01T23:59:59.000Z

13

Radionuclide and contaminant immobilization in the fluidized bed steam reforming waste products  

SciTech Connect (OSTI)

The goal of this chapter is to introduce the reader to the Fluidized Bed Steam Reforming (FBSR) process and resulting waste form. The first section of the chapter gives an overview of the potential need for FBSR processing in nuclear waste remediation followed by an overview of the engineering involved in the process itself. This is followed by a description of waste form production at a chemical level followed by a section describing different process streams that have undergone the FBSR process. The third section describes the resulting mineral product in terms of phases that are present and the ability of the waste form to encapsulate hazardous and radioactive wastes from several sources. Following this description is a presentation of the physical properties of the granular and monolith waste form product including and contaminant release mechanisms. The last section gives a brief summary of this chapter and includes a section on the strengths associated with this waste form and the needs for additional data and remaining questions yet to be answered. The reader is directed elsewhere for more information on other waste forms such as Cast Stone (Lockrem, 2005), Ceramicrete (Singh et al., 1997, Wagh et al., 1999) and geopolymers (Kyritsis et al., 2009; Russell et al., 2006).

Neeway, James J.; Qafoku, Nikolla; Westsik, Joseph H.; Brown, Christopher F.; Jantzen, Carol; Pierce, Eric M.

2012-05-01T23:59:59.000Z

14

Performance of the Fluidized Bed Steam Reforming Product Under Hydraulically Unsaturated Conditions  

SciTech Connect (OSTI)

Currently, several candidates for secondary waste immobilization at the Hanford site in the State of Washington, USA are being considered. To demonstrate the durability of the product in the unsaturated Integrated Disposal Facility (IDF) at the site, a series of tests have been performed one of the candidate materials using the Pressurized Unsaturated Flow (PUF) system. The material that was tested was the Fluidized Bed Steam Reformer (FBSR) granular product and the granular product encapsulated in a geopolymer matrix. The FBSR product is composed primarily of an insoluble sodium aluminosilicate matrix with the dominant phases being feldspathoid minerals mostly nepheline, sodalite, and nosean. The PUF test method allows for the accelerated weathering of materials, including radioactive waste forms, under hydraulically unsaturated conditions, thus mimicking the open-flow and transport properties that most likely will be present at the IDF. The experiments show a trend of decreasing tracer release as a function of time for several of the elements released from the material including Na, Si, Al, and Cs. However, some of the elements, notably I and Re, show a steady release throughout the yearlong test. This result suggests that the release of these minerals from the sodalite cage occurs at a different rate compared with the dissolution of the predominant nepheline phase.

Neeway, James J.; Qafoku, Nikolla; Williams, Benjamin D.; Rod, Kenton A.; Bowden, Mark E.; Brown, Christopher F.; Pierce, Eric M.

2014-05-01T23:59:59.000Z

15

Characterization and Leaching Tests of the Fluidized Bed Steam Reforming (FBSR) Waste Form for LAW Immobilization  

SciTech Connect (OSTI)

Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) have been evaluated. One such immobilization technology is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Pacific Northwest National Laboratory (PNNL) was involved in an extensive characterization campaign. This goal of this campaign was study the durability of the FBSR mineral product and the mineral product encapsulated in a monolith to meet compressive strength requirements. This paper gives an overview of results obtained using the ASTM C 1285 Product Consistency Test (PCT), the EPA Test Method 1311 Toxicity Characteristic Leaching Procedure (TCLP), and the ASTMC 1662 Single-Pass Flow-Through (SPFT) test. Along with these durability tests an overview of the characteristics of the waste form has been collected using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), microwave digestions for chemical composition, and surface area from Brunauer, Emmett, and Teller (BET) theory.

Neeway, James J.; Qafoku, Nikolla; Brown, Christopher F.; Peterson, Reid A.

2013-10-01T23:59:59.000Z

16

FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING  

SciTech Connect (OSTI)

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

2006-12-06T23:59:59.000Z

17

FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING  

SciTech Connect (OSTI)

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

2007-03-31T23:59:59.000Z

18

Method of steam reforming methanol to hydrogen  

DOE Patents [OSTI]

The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA)

1990-01-01T23:59:59.000Z

19

Steam reforming analyzed  

SciTech Connect (OSTI)

This paper reports that maximum steam reformer operation without excessive coking reactions requires careful control of thermodynamic and kinetic conditions. Regardless of the syngas-based feedstock composition, carbon formation problems can be avoided while increasing reformer CO or H{sub 2} production. Steam reforming technology is best understood via: Primary steam reformer developments, Kinetics of methane steam reforming, Simulation of an industrial steam/CO{sub 2} reformer, Example conditions (steam/CO{sub 2} reforming), Thermodynamic approach (minimum to steam ratio). Hydrogen and carbon monoxide are two of the most important building blocks in the chemical industry. Hydrogen is mainly used in ammonia and methanol synthesis and petroleum refining. Carbon monoxide is used to produce pains, plastics, foams, pesticides and insecticides, to name a few. Production of H{sub 2} and CO is usually carried out by the following processes: Steam reforming (primary and secondary) of hydrocarbons, Partial oxidation of hydrocarbons, Coal gasification. Coal gasification and partial oxidation do not use catalysts and depend on partial combustion of the feedstock to internally supply reaction heat. Secondary (autothermal) reforming is a type of steam reforming that also uses the heat of partial combustion but afterwards uses a catalyst of promote the production of hydrogen and CO.

Wagner, E.S. (KTI Corp., San Dimas, CA (US)); Froment, G.F. (Ghent Rijksuniversiteit (Belgium))

1992-07-01T23:59:59.000Z

20

Performance of the Fluidized Bed Steam Reforming product under hydraulically unsaturated conditions  

SciTech Connect (OSTI)

Several candidates for supplemental low-activity waste (LAW) immobilization at the Hanford site in Washington State, USA are being considered. One waste sequestering technology considered is Fluidized Bed Steam Reforming (FBSR). The granular product resulting from the FBSR process is composed primarily of an insoluble sodium aluminosilicate matrix with the dominant phases being feldspathoid minerals with a 1:1:1 molar ratio of Na, Al and Si. To demonstrate the durability of the product, which can be disposed of at the unsaturated Integrated Disposal Facility (IDF) at Hanford, a series of tests has been performed using the Pressurized Unsaturated Flow (PUF) system, which allows for the accelerated weathering of the solid materials. The system maintains hydraulically unsaturated conditions, thus mimicking the open-flow and transport properties that will be present at the IDF. Two materials were tested using the system: 1) the FBSR granular product and 2) the FBSR granular product encapsulated in a geopolymer to form a monolith. Results of the experiments show a trend of relatively constant effluent concentration of Na, Si, Al, and Cs as a function of time from both materials. The elements I and Re show a steady release throughout the yearlong test from the granular material but their concentrations seem to be increasing at one year from the monolith material. This result suggests that these two elements may be present in the sodalite cage structure rather than in the predominant nepheline phase because their release occurs at a different rate compared to nepheline phase. Also, these elements to not seem to reprecipitate when released from the starting material. Calculated one-year release rates for Si are on the order of 10 6 g/(m2 d) for the granular material and 10 5 g/(m2 d) for the monolith material while Re release is seen to be two orders of magnitude higher than Si release rates. SEM imaging and XRD analysis show how the alteration of the two materials is dependent on their depth in the column. This phenomenom is a result of depth-dependent solution concentrations giving rise chemical environments that may be supersaturated with respect to a number of mineral phases.

Neeway, James J [ORNL] [ORNL; Rod, Kenton A. [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Bowden, Mark E [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Pierce, Eric M [ORNL] [ORNL; Qafoku, Nikolla [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Williams, Benjamin D [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Brown, Christopher F [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL)

2014-01-01T23:59:59.000Z

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21

Characterization and Leaching Tests of the Fluidized Bed Steam Reforming (FBSR) Waste Form for LAW Immobilization - 13400  

SciTech Connect (OSTI)

Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) have been evaluated. One such immobilization technology is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Pacific Northwest National Laboratory (PNNL) was involved in an extensive characterization campaign. The goal of this campaign was to study the durability of the FBSR mineral product and the encapsulated FBSR product in a geo-polymer monolith. This paper gives an overview of results obtained using the ASTM C 1285 Product Consistency Test (PCT), the EPA Test Method 1311 Toxicity Characteristic Leaching Procedure (TCLP), and the ASTMC 1662 Single-Pass Flow-Through (SPFT) test. Along with these durability tests an overview of the characteristics of the waste form has been collected using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), microwave digestions for chemical composition, and surface area from Brunauer, Emmett, and Teller (BET) theory. (authors)

Neeway, James J.; Qafoku, Nikolla P.; Peterson, Reid A.; Brown, Christopher F. [Pacific Northwest National Laboratory, Richland, WA (United States)] [Pacific Northwest National Laboratory, Richland, WA (United States)

2013-07-01T23:59:59.000Z

22

Secondary Waste Form Screening Test Results—THOR® Fluidized Bed Steam Reforming Product in a Geopolymer Matrix  

SciTech Connect (OSTI)

Screening tests are being conducted to evaluate waste forms for immobilizing secondary liquid wastes from the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Plans are underway to add a stabilization treatment unit to the Effluent Treatment Facility to provide the needed capacity for treating these wastes from WTP. The current baseline is to use a Cast Stone cementitious waste form to solidify the wastes. Through a literature survey, DuraLith alkali-aluminosilicate geopolymer, fluidized-bed steam reformation (FBSR) granular product encapsulated in a geopolymer matrix, and a Ceramicrete phosphate-bonded ceramic were identified both as candidate waste forms and alternatives to the baseline. These waste forms have been shown to meet waste disposal acceptance criteria, including compressive strength and universal treatment standards for Resource Conservation and Recovery Act (RCRA) metals (as measured by the toxicity characteristic leaching procedure [TCLP]). Thus, these non-cementitious waste forms should also be acceptable for land disposal. Information is needed on all four waste forms with respect to their capability to minimize the release of technetium. Technetium is a radionuclide predicted to be in the secondary liquid wastes in small quantities, but the Integrated Disposal Facility (IDF) risk assessment analyses show that technetium, even at low mass, produces the largest contribution to the estimated IDF disposal impacts to groundwater.

Pires, Richard P.; Westsik, Joseph H.; Serne, R. Jeffrey; Mattigod, Shas V.; Golovich, Elizabeth C.; Valenta, Michelle M.; Parker, Kent E.

2011-07-14T23:59:59.000Z

23

RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING WITH ACUTAL HANFORD LOW ACTIVITY WASTES VERIFYING FBSR AS A SUPPLEMENTARY TREATMENT  

SciTech Connect (OSTI)

The U.S. Department of Energy's Office of River Protection is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level waste (HLW) and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the cleanup mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA). Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. Fluidized Bed Steam Reforming (FBSR) is one of the supplementary treatments being considered. FBSR offers a moderate temperature (700-750 C) continuous method by which LAW and other secondary wastes can be processed irrespective of whether they contain organics, nitrates/nitrites, sulfates/sulfides, chlorides, fluorides, and/or radio-nuclides like I-129 and Tc-99. Radioactive testing of Savannah River LAW (Tank 50) shimmed to resemble Hanford LAW and actual Hanford LAW (SX-105 and AN-103) have produced a ceramic (mineral) waste form which is the same as the non-radioactive waste simulants tested at the engineering scale. The radioactive testing demonstrated that the FBSR process can retain the volatile radioactive components that cannot be contained at vitrification temperatures. The radioactive and nonradioactive mineral waste forms that were produced by co-processing waste with kaolin clay in an FBSR process are shown to be as durable as LAW glass.

Jantzen, C.; Crawford, C.; Burket, P.; Bannochie, C.; Daniel, G.; Nash, C.; Cozzi, A.; Herman, C.

2012-01-12T23:59:59.000Z

24

FLUIDIZED BED STEAM REFORMING MINERALIZATION FOR HIGH ORGANIC AND NITRATE WASTE STREAMS FOR THE GLOBAL NUCLEAR ENERGY PARTNERSHIP  

SciTech Connect (OSTI)

Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NO{sub x} in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {ge} 1000 C. Pollucite mineralization creates secondary aqueous waste streams and NO{sub x}. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O.

Jantzen, C; Michael Williams, M

2008-01-11T23:59:59.000Z

25

RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES  

SciTech Connect (OSTI)

The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the Savannah River National Laboratory (SRNL) to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of I-125/129 and Tc-99 to chemically resemble WTP-SW. Ninety six grams of radioactive product were made for testing. The second campaign commenced using SRS LAW chemically trimmed to look like Hanford's LAW. Six hundred grams of radioactive product were made for extensive testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

2011-02-24T23:59:59.000Z

26

MINERALIZATION OF RADIOACTIVE WASTES BY FLUIDIZED BED STEAM REFORMING (FBSR): COMPARISONS TO VITREOUS WASTE FORMS, AND PERTINENT DURABILITY TESTING  

SciTech Connect (OSTI)

The Savannah River National Laboratory (SRNL) was requested to generate a document for the Washington State Department of Ecology and the U.S. Environmental Protection Agency that would cover the following topics: (1) A description of the mineral structures produced by Fluidized Bed Steam Reforming (FBSR) of Hanford type Low Activity Waste (LAW including LAWR which is LAW melter recycle waste) waste, especially the cage structured minerals and how they are formed. (2) How the cage structured minerals contain some contaminants, while others become part of the mineral structure (Note that all contaminants become part of the mineral structure and this will be described in the subsequent sections of this report). (3) Possible contaminant release mechanisms from the mineral structures. (4) Appropriate analyses to evaluate these release mechanisms. (5) Why the appropriate analyses are comparable to the existing Hanford glass dataset. In order to discuss the mineral structures and how they bond contaminants a brief description of the structures of both mineral (ceramic) and vitreous waste forms will be given to show their similarities. By demonstrating the similarities of mineral and vitreous waste forms on atomic level, the contaminant release mechanisms of the crystalline (mineral) and amorphous (glass) waste forms can be compared. This will then logically lead to the discussion of why many of the analyses used to evaluate vitreous waste forms and glass-ceramics (also known as glass composite materials) are appropriate for determining the release mechanisms of LAW/LAWR mineral waste forms and how the durability data on LAW/LAWR mineral waste forms relate to the durability data for LAW/LAWR glasses. The text will discuss the LAW mineral waste form made by FBSR. The nanoscale mechanism by which the minerals form will be also be described in the text. The appropriate analyses to evaluate contaminant release mechanisms will be discussed, as will the FBSR test results to date and how they compare to testing performed on LAW glasses. Other details about vitreous waste form durability and impacts of REDuction/OXidation (REDOX) on durability are given in Appendix A. Details about the FBSR process, various pilot scale demonstrations, and applications are given in Appendix B. Details describing all the different leach tests that need to be used jointly to determine the leaching mechanisms of a waste form are given in Appendix C. Cautions regarding the way in which the waste form surface area is measured and in the choice of leachant buffers (if used) are given in Appendix D.

Jantzen, C

2008-12-26T23:59:59.000Z

27

RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM  

SciTech Connect (OSTI)

The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

2012-02-02T23:59:59.000Z

28

Recover heat from steam reforming  

SciTech Connect (OSTI)

Steam reforming is one of the most important chemical processes--it is used in the manufacture of ammonia, hydrogen, methanol, and many chemicals made from hydrogen and carbon monoxide. Furthermore, many current trends will increase its importance. For example, methanol for addition to gasoline is likely to be produced by steam reforming. Because steam reforming occurs at high temperatures--typically 750 C--900 C--it generates a large amount of waste heat. Clearly, heat recovery is crucial to process economics. A typical 50,000 Nm[sup 3]/h hydrogen plant using natural gas feed has a radiant heat duty of about 50 MW. At a radiant efficiency of 50% and fuel cost of $3/GJ, this means that the reformer fires $9 million worth of fuel per year. Obviously, this amount of fuel justifies a close loot at ways to reduce costs. This article first provides a brief overview of steam reforming. It then outlines the available heat-recovery options and explains how to select the best method.

Fleshman, J.D. (Foster Wheeler USA Corp., Livingston, NJ (United States))

1993-10-01T23:59:59.000Z

29

Conversion of hydrocarbons for fuel-cell applications. Part I. Autothermal reforming of sulfur-free and sulfur-containing hydrocarbon liquids. Part II. Steam reforming of n-hexane on pellet and monolithic catalyst beds. Final report  

SciTech Connect (OSTI)

Experimental autothermal reforming (ATR) results obtained in the previous phase of this work with sulfur-free pure hydrocarbon liquids are summarized. Catalyst types and configuration used were the same as in earlier tests with No. 2 fuel oil to facilitate comparisons. Fuel oil has been found to form carbon in ATR at conditions much milder than those predicted by equilibrium. Reactive differences between paraffins and aromatics in ATR, and thus the formation of different carbon precursors, have been shown to be responsible for the observed carbon formation characteristics (fuel-specific). From tests with both light and heavy paraffins and aromatics, it is concluded that high boiling point hydrocarbons and polynuclear aromatics enhance the propensity for carbon formation in ATR. Effects of olefin (propylene) addition on the ATR performance of benzene are described. In ATR tests with mixtures of paraffins and aromatics (n-tetradecane and benzene) synergistic effects on conversion characteristics were identified. Comparisons of the No. 2 fuel oil data with the experimental results from this work with pure (and mixed) sulfur-free hydrocarbons indicate that the sulfur content of the fuel may be the limiting factor for efficient ATR operation. Steam reforming of hydrocarbons in conventional reformers is heat transfer limited. Steam reforming tasks performed have included performance comparisons between conventional pellet beds and honeycomb monolith catalysts. Metal-supported monoliths offer higher structural stability than ceramic supports, and have a higher thermal conductivity. Data from two metal monoliths of different catalyst (nickel) loading were compared to pellets under the same operating conditions.

Flytzani-Stephanopoulos, M.; Voecks, G.E.

1981-10-01T23:59:59.000Z

30

Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105 And AN-103) By Fluidized Bed Steam Reformation  

SciTech Connect (OSTI)

One of the immobilization technologies under consideration as a Supplemental Treatment for Hanford’s Low Activity Waste (LAW) is Fluidized Bed Steam Reforming (FBSR). The FBSR technology forms a mineral waste form at moderate processing temperatures thus retaining and atomically bonding the halides, sulfates, and technetium in the mineral phases (nepheline, sodalite, nosean, carnegieite). Additions of kaolin clay are used instead of glass formers and the minerals formed by the FBSR technology offers (1) atomic bonding of the radionuclides and constituents of concern (COC) comparable to glass, (2) short and long term durability comparable to glass, (3) disposal volumes comparable to glass, and (4) higher Na2O and SO{sub 4} waste loadings than glass. The higher FBSR Na{sub 2}O and SO{sub 4} waste loadings contribute to the low disposal volumes but also provide for more rapid processing of the LAW. Recent FBSR processing and testing of Hanford radioactive LAW (Tank SX-105 and AN-103) waste is reported and compared to previous radioactive and non-radioactive LAW processing and testing.

Jantzen, Carol; Herman, Connie; Crawford, Charles; Bannochie, Christopher; Burket, Paul; Daniel, Gene; Cozzi, Alex; Nash, Charles; Miller, Donald; Missimer, David

2014-01-10T23:59:59.000Z

31

Steam reforming utilizing high activity catalyst  

SciTech Connect (OSTI)

High activity, sulfur tolerant steam reforming catalysts are described comprising rhodium or nickel supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. The catalysts have improved activity over conventionally used catalysts in the presence of sulfur containing hydrocarbon fuel (such as No. 2 fuel oil) in a steam reforming environment. The material has particular utility in autothermal, tubular, cyclic and adiabatic steam reforming processes.

Setzer, H. J.

1985-03-05T23:59:59.000Z

32

Comparative Investigation of Benzene Steam Reforming over Spinel...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts....

33

Steam reforming utilizing iron oxide catalyst  

SciTech Connect (OSTI)

High activity steam reforming iron oxide catalysts are described. Such catalysts can be unsupported utilizing at least 90% by weight iron oxide and various modifiers (Ai/sub 2/O/sub 3/, K/sub 2/O, CaO, SiO/sub 2/) or unmodified and supported on such things as alumina, CaO impregnated alumina, and lanthanum stabilized alumina. When used in steam reformers such as autothermal and tubular steam reformers, these catalysts demonstrate much improved resistance to carbon plugging.

Setzer, H. T.; Bett, J. A. S.

1985-06-11T23:59:59.000Z

34

Fuel cell integrated with steam reformer  

DOE Patents [OSTI]

A H.sub.2 -air fuel cell integrated with a steam reformer is disclosed wherein a superheated water/methanol mixture is fed to a catalytic reformer to provide a continuous supply of hydrogen to the fuel cell, the gases exhausted from the anode of the fuel cell providing the thermal energy, via combustion, for superheating the water/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA); Whelan, James A. (Bricktown, NJ)

1987-01-01T23:59:59.000Z

35

Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank Farm Blend) By Fluidized Bed Steam Reformation (FBSR)  

SciTech Connect (OSTI)

The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Supplemental Treatment is likely to be required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP’s LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750°C) continuous method by which LAW can be processed irrespective of whether the waste contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be comparable to LAW glass, i.e. leaches Tc-99, Re and Na at <2g/m2 during ASTM C1285 (Product Consistency) durability testing. Monolithing of the granular FBSR product was investigated to prevent dispersion during transport or burial/storage. Monolithing in an inorganic geopolymer binder, which is amorphous, macro-encapsulates the granules, and the monoliths pass ANSI/ANS 16.1 and ASTM C1308 durability testing with Re achieving a Leach Index (LI) of 9 (the Hanford Integrated Disposal Facility, IDF, criteria for Tc-99) after a few days and Na achieving an LI of >6 (the Hanford IDF criteria for Na) in the first few hours. The granular and monolithic waste forms also pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) for all Resource Conservation and Recovery Act (RCRA) components at the Universal Treatment Standards (UTS). Two identical Benchscale Steam Reformers (BSR) were designed and constructed at SRNL, one to treat non-radioactive simulants and the other to treat actual radioactive wastes. The results from the non-radioactive BSR were used to determine the parameters needed to operate the radioactive BSR in order to confirm the findings of non-radioactive FBSR pilot scale and engineering scale tests and to qualify an FBSR LAW waste form for applications at Hanford. Radioactive testing commenced using SRS LAW from Tank 50 chemically trimmed to look like Hanford’s blended LAW known as the Rassat simulant as this simulant composition had been tested in the non-radioactive BSR, the non-radioactive pilot scale FBSR at the Science Applications International Corporation-Science and Technology Applications Research (SAIC-STAR) facility in Idaho Falls, ID and in the TTT Engineering Scale Technology Demonstration (ESTD) at Hazen Research Inc. (HRI) in Denver, CO. This provided a “tie back” between radioactive BSR testing and non-radioactive BSR, pilot scale, and engineering scale testing. Approximately six hundred grams of non-radioactive and radioactive BSR product were made for extensive testing and comparison to the non-radioactive pilot scale tests performed in 2004 at SAIC-STAR and the engineering scale test performed in 2008 at HRI with the Rassat simulant. The same mineral phases and off-gas species were found in the radioactive and non-radioactive testing. The granular ESTD and BSR products (radioactive and non-radioactive) were analyzed for to

Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

2013-08-21T23:59:59.000Z

36

Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons  

SciTech Connect (OSTI)

An apparatus is described for the essentially autothermal, integrated primary and secondary reforming of hydrocarbons comprising: (a) an internally insulated outer reactor shell adapted for the positioning of primary and secondary reforming zones therein; (b) means defining a primary reforming zone within the outer reactor shell and having catalyst-containing reformer tubes positioned therein, the primary reforming zone not requiring an external fuel fired source of heat for the endothermic primary reforming reaction occurring therein; (c) means for introducing a fluid hydrocarbon feed stream and steam to the outer reactor shell for passage through the reformer tubes in the primary reforming zone; (d) means defining a secondary reforming zone within the outer reactor shell comprising a secondary reforming catalyst bed, a catalyst-free reaction space defining a feed end adjacent to the catalyst bed and a discharge end at the opposite side of the secondary reforming catalyst bed to the feed end; and (e) conduit means positioned entirely within the outer reactor shell and extending through the secondary reforming catalyst bed for passing partly reformed product effluent from the primary reforming zone to the catalyst-free reaction space in the secondary reforming zone.

Fuderer, A.

1987-03-17T23:59:59.000Z

37

Supported metal catalysts for alcohol/sugar alcohol steam reforming  

SciTech Connect (OSTI)

Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

2014-08-21T23:59:59.000Z

38

DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR THE BENCH STEAM REFORMER TEST  

SciTech Connect (OSTI)

This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Fluid Bed Steam Reformer testing. The type, quantity and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluid bed steam reformer (FBSR). A determination of the adequacy of the FBSR process to treat Hanford tank waste is required. The initial step in determining the adequacy of the FBSR process is to select archived waste samples from the 222-S Laboratory that will be used to test the FBSR process. Analyses of the selected samples will be required to confirm the samples meet the testing criteria.

BANNING DL

2010-08-03T23:59:59.000Z

39

RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE (WTP-SW) BY FLUIDIZED BED STEAM REFORMING (FBSR) USING THE BENCH SCALE REFORMER PLATFORM  

SciTech Connect (OSTI)

The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150°C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750°C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford’s WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing. The granular products (both simulant and radioactive) were tested and a subset of the granular material (both simulant and radioactive) were stabilized in a geopolymer matrix. Extensive testing and characterization of the granular and monolith material were made including the following: ? ASTM C1285 (Product Consistency Test) testing of granular and monolith; ? ASTM C1308 accelerated leach testing of the radioactive monolith; ? ASTM C192 compression testing of monoliths; and ? EPA Method 1311 Toxicity Characteristic Leaching Procedure (TCLP) testing. The significant findings of the testing completed on simulant and radioactive WTP-SW are given below: ? Data indicates {sup 99}Tc, Re, Cs, and I

Crawford, C.; Burket, P.; Cozzi, A.; Daniel, G.; Jantzen, C.; Missimer, D.

2014-08-21T23:59:59.000Z

40

FLUIDIZED BED STEAM REFORMING (FBSR) OF HIGH LEVEL WASTE (HLW) ORGANIC AND NITRATE DESTRUCTION PRIOR TO VITRIFICATION: CRUCIBLE SCALE TO ENGINEERING SCALE DEMONSTRATIONS AND NON-RADIOACTIVE TO RADIOACTIVE DEMONSTRATIONS  

SciTech Connect (OSTI)

Over a decade ago, an in-tank precipitation process to remove Cs-137 from radioactive high level waste (HLW) supernates was demonstrated at the Savannah River Site (SRS). The full scale demonstration with actual HLW was performed in SRS Tank 48 (T48). Sodium tetraphenylborate (NaTPB) was added to enable Cs-137 extraction as CsTPB. The CsTPB, an organic, and its decomposition products proved to be problematic for subsequent processing of the Cs-137 precipitate in the SRS HLW vitrification facility for ultimate disposal in a HLW repository. Fluidized Bed Steam Reforming (FBSR) is being considered as a technology for destroying the organics and nitrates in the T48 waste to render it compatible with subsequent HLW vitrification. During FBSR processing the T48 waste is converted into organic-free and nitrate-free carbonate-based minerals which are water soluble. The soluble nature of the carbonate-based minerals allows them to be dissolved and pumped to the vitrification facility or returned to the tank farm for future vitrification. The initial use of the FBSR process for T48 waste was demonstrated with simulated waste in 2003 at the Savannah River National Laboratory (SRNL) using a specially designed sealed crucible test that reproduces the FBSR pyrolysis reactions, i.e. carbonate formation, organic and nitrate destruction. This was followed by pilot scale testing of simulants at the Science Applications International Corporation (SAIC) Science & Technology Application Research (STAR) Center in Idaho Falls, ID by Idaho National Laboratory (INL) and SRNL in 2003-4 and then engineering scale demonstrations by THOR{reg_sign} Treatment Technologies (TTT) and SRS/SRNL at the Hazen Research, Inc. (HRI) test facility in Golden, CO in 2006 and 2008. Radioactive sealed crucible testing with real T48 waste was performed at SRNL in 2008, and radioactive Benchscale Steam Reformer (BSR) testing was performed in the SRNL Shielded Cell Facility (SCF) in 2008.

Jantzen, C; Michael Williams, M; Gene Daniel, G; Paul Burket, P; Charles Crawford, C

2009-02-07T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Alternative technologies to steam-methane reforming  

SciTech Connect (OSTI)

Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

1995-11-01T23:59:59.000Z

42

Hydrogen generation utilizing integrated CO2 removal with steam reforming  

DOE Patents [OSTI]

A steam reformer may comprise fluid inlet and outlet connections and have a substantially cylindrical geometry divided into reforming segments and reforming compartments extending longitudinally within the reformer, each being in fluid communication. With the fluid inlets and outlets. Further, methods for generating hydrogen may comprise steam reformation and material adsorption in one operation followed by regeneration of adsorbers in another operation. Cathode off-gas from a fuel cell may be used to regenerate and sweep the adsorbers, and the operations may cycle among a plurality of adsorption enhanced reformers to provide a continuous flow of hydrogen.

Duraiswamy, Kandaswamy; Chellappa, Anand S

2013-07-23T23:59:59.000Z

43

Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105, Tank AN-103, And AZ-101/102) By Fluidized Bed Steam Reformation (FBSR)  

SciTech Connect (OSTI)

Fluidized Bed Steam Reforming (FBSR) is a robust technology for the immobilization of a wide variety of radioactive wastes. Applications have been tested at the pilot scale for the high sodium, sulfate, halide, organic and nitrate wastes at the Hanford site, the Idaho National Laboratory (INL), and the Savannah River Site (SRS). Due to the moderate processing temperatures, halides, sulfates, and technetium are retained in mineral phases of the feldspathoid family (nepheline, sodalite, nosean, carnegieite, etc). The feldspathoid minerals bind the contaminants such as Tc-99 in cage (sodalite, nosean) or ring (nepheline) structures to surrounding aluminosilicate tetrahedra in the feldspathoid structures. The granular FBSR mineral waste form that is produced has a comparable durability to LAW glass based on the short term PCT testing in this study, the INL studies, SPFT and PUF testing from previous studies as given in the columns in Table 1-3 that represent the various durability tests. Monolithing of the granular product was shown to be feasible in a separate study. Macro-encapsulating the granular product provides a decrease in leaching compared to the FBSR granular product when the geopolymer is correctly formulated.

Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

2013-09-18T23:59:59.000Z

44

Compatibility of selected ceramics with steam-methane reformer environments  

SciTech Connect (OSTI)

Conventional steam reforming of methane to synthesis gas (CO and H{sub 2}) hasa conversion efficiency of about 85%. Replacement of metal tubes in the reformer with ceramic tubes offers the potential for operation at temperatures high enough to increase the efficiency to 98-99%. However, the two candidate ceramic materials being given strongest consideration, sintered alpha Si carbide and Si carbide particulate-strengthened alumina, have been shown to react with components of the reformer environment. Extent of degradation as a function of steam partial pressure and exposure time has been studied, and results suggest limits under which these structural ceramics can be used in advanced steam-methane reformers.

Keiser, J.R.; Howell, M. [Oak Ridge National Lab., TN (United States); Williams, J.J.; Rosenberg, R.A. [Stone and Webster Engineering Corp., Boston, MA (United States)

1996-04-01T23:59:59.000Z

45

TWR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

Marshall, D.W.; Soelberg, N.R.

2003-05-21T23:59:59.000Z

46

TWR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

D. W. Marshall; N. R. Soelberg

2003-05-01T23:59:59.000Z

47

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS  

E-Print Network [OSTI]

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS Kimberly established that biomass pyrolysis oil could be steam-reformed to generate hydrogen using non pyrolysis oil could be almost stoichiometrically converted to hydrogen. However, process performance

48

Catalytic roles of Co0 and Co2+ during steam reforming of ethanol...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Catalytic roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Abstract:...

49

A Comparative Study between Co and Rh for Steam Reforming of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

between Co and Rh for Steam Reforming of Ethanol. A Comparative Study between Co and Rh for Steam Reforming of Ethanol. Abstract: Rh and Co-based catalyst performance was compared...

50

Methanol Steam Reformer on a Silicon Wafer  

SciTech Connect (OSTI)

A study of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabricated on a silicon wafer are presented. Comparison of computed and measured conversion efficiencies are shown to be favorable. Concepts for insulating the reactor while maintaining small overall size and starting operation from ambient temperature are analyzed.

Park, H; Malen, J; Piggott, T; Morse, J; Sopchak, D; Greif, R; Grigoropoulos, C; Havstad, M; Upadhye, R

2004-04-15T23:59:59.000Z

51

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical Discharge  

E-Print Network [OSTI]

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical production from simultaneous steam reforming and partial oxidation of methane using an ac corona discharge production has been steam reforming, shown in reaction 4. It is very useful to use low-cost materials

Mallinson, Richard

52

Steam Reforming of Low-Level Mixed Waste  

SciTech Connect (OSTI)

Under DOE Contract No. DE-AR21-95MC32091, Steam Reforming of Low-Level Mixed Waste, ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design construction, and testing of the PDU as well as performance and economic projections for a 500- lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area published April 1997.1 The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfidly tested including a 750-hour test on material simulating a PCB- and Uranium- contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (>99.9999oA) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radlonuclides in the volume-reduced solids. Cost studies have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

None

1998-01-01T23:59:59.000Z

53

The use of advanced steam reforming technology for hydrogen production  

SciTech Connect (OSTI)

The demand for supplementary hydrogen production in refineries is growing significantly world-wide as environmental legislation concerning cleaner gasoline and diesel fuels is introduced. The main manufacturing method is by steam reforming. The process has been developed both to reduce the capital cost and increase efficiency, reliability and ease of operation. ICI Katalco`s Leading Concept Hydrogen or LCH process continues this process of improvement by replacing the conventional fired steam reformer with a type of heat exchange reformer known as the Gas Heated Reformer or GHR. The GHR was first used in the Leading Concept Ammonia process, LCA at ICI`s manufacturing site at Severnside, England and commissioned in 1988 and later in the Leading Concept Methanol (LCM) process for methanol at Melbourne, Australia and commissioned in 1994. The development of the LCH process follows on from both LCA and LCM processes. This paper describes the development and use of the GHR in steam reforming, and shows how the GHR can be used in LCH. A comparison between the LCH process and a conventional hydrogen plant is given, showing the benefits of the LCH process in certain circumstances.

Abbishaw, J.B.; Cromarty, B.J. [ICI Katalco, Billingham (United Kingdom)

1996-12-01T23:59:59.000Z

54

Steam methane reforming in molten carbonate salt. Final report  

SciTech Connect (OSTI)

This report documents the work accomplished on the project {open_quotes}Steam Methane Reforming in Molten Carbonate Salt.{close_quotes}. This effort has established the conceptual basis for molten carbonate-based steam reforming of methane. It has not proceeded to prototype verification, because corrosion concerns have led to reluctance on the part of large hydrogen producers to adopt the technology. Therefore the focus was shifted to a less corrosive embodiment of the same technology. After considerable development effort it was discovered that a European company (Catalysts and Chemicals Europe) was developing a similar process ({open_quotes}Regate{close_quotes}). Accordingly the focus was shifted a second time, to develop an improvement which is generic to both types of reforming. That work is still in progress, and shows substantial promise.

Erickson, D.C.

1996-05-01T23:59:59.000Z

55

STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138  

SciTech Connect (OSTI)

This paper describes the design of the Bench-scale Steam Reformer (BSR); a processing unit for demonstrating steam reforming technology on actual radioactive waste [1]. It describes the operating conditions of the unit used for processing a sample of Savannah River Site (SRS) Tank 48H waste. Finally, it compares the results from processing the actual waste in the BSR to processing simulant waste in the BSR to processing simulant waste in a large pilot scale unit, the Fluidized Bed Steam Reformer (FBSR), operated at Hazen Research Inc. in Golden, CO. The purpose of this work was to prove that the actual waste reacted in the same manner as the simulant waste in order to validate the work performed in the pilot scale unit which could only use simulant waste.

Burket, P

2009-02-24T23:59:59.000Z

56

Phase 2 TWR Steam Reforming Test for Sodium-Bearing Waste Treatment  

SciTech Connect (OSTI)

About one million gallons of acidic, hazardous, and radioactive sodium-bearing waste (SBW) is stored in stainless steel tanks a the Idaho Nuclear Technology and Engineering Center (INTEC), which is a major operating facility of the Idaho National Engineering and Environmental Laboratory (INEEL). Steam reforming is a candidate technology being investigated for converting the SBW into a road ready waste form that can be shipped to the Waste Isolation Pilot Plant in New Mexico for interment. Fluidized bed steam reforming technology, licensed to ThermoChem Waste Remediation, LLC (TWR) by Manufacturing Technology Conversion International, was tested in two phases using an INEEL (Department of Energy) fluidized bed test system located at the Science Applications International Corporation (SAIC) Science and Technology Applications Research Center in Idaho Falls, Idaho. The Phase 1 tests were reported earlier. The Phase 2 tests are reported here. For Phase 2, the process feed rate, reductant stoichiometry, and process temperature were varied to identify and demonstrate how the process might be optimized to improve operation and product characteristics. The first week of testing was devoted primarily to process chemistry and the second week was devoted more toward bed stability and particle size control.

Nicholas R. Soelberg; Doug Marshall; Dean Taylor; Steven Bates

2004-01-01T23:59:59.000Z

57

Steam reforming of low-level mixed waste. Final report  

SciTech Connect (OSTI)

ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design, construction, and testing of the PDU as well as performance and economic projections for a 300-lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area and published in April 1997. The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfully tested including a 750-hour test on material simulating a PCB- and Uranium-contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (> 99.9999%) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radionuclides in the volume-reduced solids. Economic evaluations have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

NONE

1998-06-01T23:59:59.000Z

58

THOR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

D. W. Marshall; N. R. Soelberg; K. M. Shaber

2003-05-01T23:59:59.000Z

59

THOR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

Marshall, D.W.; Soelberg, N.R.; Shaber, K.M.

2003-05-21T23:59:59.000Z

60

Thermodynamic evaluation of hydrogen production via bioethanol steam reforming  

SciTech Connect (OSTI)

In this article, a thermodynamic analysis for bioethanol steam reforming for hydrogen production is presented. Bioethanol is a newly proposed renewable energy carrier mainly produced from biomass fermentation. Reforming of bioethanol provides a promising method for hydrogen production from renewable resources. Steam reforming of ethanol (SRE) takes place under the action of a metal catalyst capable of breaking C-C bonds into smaller molecules. A large domain for the water/bioethanol molar ratio as well as the temperature and average pressure has been used in the present work. The interval of investigated temperature was 100-800°C, the pressure was in the range of 1-10 bar and the molar ratio was between 3-25. The variations of gaseous species concentration e.g. H{sub 2}, CO, CO{sub 2}, CH{sub 4} were analyzed. The concentrations of the main products (H{sub 2} and CO) at lower temperature are smaller than the ones at higher temperature due to by-products formation (methane, carbon dioxide, acetylene etc.). The concentration of H2 obtained in the process using high molar ratio (>20) is higher than the one at small molar ratio (near stoichiometric). When the pressure is increased the hydrogen concentration decreases. The results were compared with literature data for validation purposes.

Tasnadi-Asztalos, Zsolt; Cormos, Ana-Maria; Imre-Lucaci, Árpád; Cormos, C?lin C. [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, Arany Janos 11, RO-400028, Cluj-Napoca (Romania)] [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, Arany Janos 11, RO-400028, Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT  

E-Print Network [OSTI]

ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT SHELLS, and academic organizations is developing a steam reforming process to be demonstrated on the gaseous byproducts of this engineering demonstration project. After an initial problem with the heaters that required modification

62

Modified Ni-Cu catalysts for ethanol steam reforming  

SciTech Connect (OSTI)

Three Ni-Cu catalysts, having different Cu content, supported on ?-alumina were synthesized by wet co-impregnation method, characterized and tested in the ethanol steam reforming (ESR) reaction. The catalysts were characterized for determination of: total surface area and porosity (N{sub 2} adsorption - desorption using BET and Dollimer Heal methods), Ni surface area (hydrogen chemisorption), crystallinity and Ni crystallites size (X-Ray Diffraction), type of catalytic active centers (Hydrogen Temperature Programmed Reduction). Total surface area and Ni crystallites size are not significantly influenced by the addition of Cu, while Ni surface area is drastically diminished by increasing of Cu concentration. Steam reforming experiments were performed at atmospheric pressure, temperature range 150-350°C, and ethanol - water molar ration of 1 at 30, using Ar as carrier gas. Ethanol conversion and hydrogen production increase by the addition of Cu. At 350°C there is a direct connection between hydrogen production and Cu concentration. Catalysts deactivation in 24h time on stream was studied by Transmission Electron Microscopy (TEM) and temperature-programmed reduction (TPR) on used catalysts. Coke deposition was observed at all studied temperatures; at 150°C amorphous carbon was evidenced, while at 350°C crystalline, filamentous carbon is formed.

Dan, M.; Mihet, M.; Almasan, V.; Borodi, G. [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Street, 400293, Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Street, 400293, Cluj-Napoca (Romania); Katona, G.; Muresan, L. [Univ. Babes Bolyai, Fac. Chem. and Chem. Eng.,11 Arany Janos, 400028, Cluj-Napoca (Romania)] [Univ. Babes Bolyai, Fac. Chem. and Chem. Eng.,11 Arany Janos, 400028, Cluj-Napoca (Romania); Lazar, M. D., E-mail: diana.lazar@itim-cj.ro [65-103 Donath Street (Romania)

2013-11-13T23:59:59.000Z

63

Phase 2 THOR Steam Reforming Tests for Sodium Bearing Waste Treatment  

SciTech Connect (OSTI)

About one million gallons of acidic, hazardous, and radioactive sodium-bearing waste is stored in stainless steel tanks at the Idaho Nuclear Technology and Engineering Center (INTEC), which is a major operating facility of the Idaho National Engineering and Environmental Laboratory. Steam reforming is a candidate technology being investigated for converting the waste into a road ready waste form that can be shipped to the Waste Isolation Pilot Plant in New Mexico for interment. A steam reforming technology patented by Studsvik, Inc., and licensed to THOR Treatment Technologies has been tested in two phases using a Department of Energy-owned fluidized bed test system located at the Science Applications International Corporation (SAIC) Science and Technology Applications Research Center located in Idaho Falls, Idaho. The Phase 1 tests were reported earlier in 2003. The Phase 2 tests are reported here. For Phase 2, the process feed rate, stoichiometry, and chemistry were varied to identify and demonstrate process operation and product characteristics under different operating conditions. Two test series were performed. During the first series, the process chemistry was designed to produce a sodium carbonate product. The second series was designed to produce a more leach-resistant, mineralized sodium aluminosilicate product. The tests also demonstrated the performance of a MACT-compliant off-gas system.

Nicholas R. Soelberg

2004-01-01T23:59:59.000Z

64

Steam Reforming, 6-in. Bench-Scale Design and Testing Project -- Technical and Functional Requirements Description  

SciTech Connect (OSTI)

Feasibility studies and technology development work are currently being performed on several processes to treat radioactive liquids and solids currently stored at the Idaho Nuclear Technology and Engineering Center (INTEC), located within the Idaho National Engineering and Environmental Laboratory (INEEL). These studies and development work will be used to select a treatment process for treatment of the radioactive liquids and solids to meet treatment milestones of the Settlement Agreement between the Department of Energy and the State of Idaho. One process under consideration for treating the radioactive liquids and solids, specifically Sodium-Bearing Waste (SBW) and tank heel solids, is fluid bed steam reforming (FBSR). To support both feasibility and development studies a bench-scale FBSR is being designed and constructed. This report presents the technical and functional requirements, experimental objectives, process flow sheets, and equipment specifications for the bench-scale FBSR.

Losinski, Sylvester John; Marshall, Douglas William

2002-08-01T23:59:59.000Z

65

Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts  

E-Print Network [OSTI]

The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications including petrochemical processing and ammonia synthesis. ...

Blaylock, Donnie Wayne

2011-01-01T23:59:59.000Z

66

Heat Transfer Limitations in Hydrogen Production Via Steam Reformation: The Effect of Reactor Geometry  

E-Print Network [OSTI]

for on- board hydrogen production for fuel-cell poweredSteam-Reforming Hydrogen production Reactors, M.S. Thesis,at the UC Davis Hydrogen Production and Utilization

Vernon, David R.; Davieau, David D.; Dudgeon, Bryce A.; Erickson, Paul A.

2006-01-01T23:59:59.000Z

67

Solid oxide fuel cell steam reforming power system  

DOE Patents [OSTI]

The present invention is a Solid Oxide Fuel Cell Reforming Power System that utilizes adiabatic reforming of reformate within this system. By utilizing adiabatic reforming of reformate within the system the system operates at a significantly higher efficiency than other Solid Oxide Reforming Power Systems that exist in the prior art. This is because energy is not lost while materials are cooled and reheated, instead the device operates at a higher temperature. This allows efficiencies higher than 65%.

Chick, Lawrence A.; Sprenkle, Vincent L.; Powell, Michael R.; Meinhardt, Kerry D.; Whyatt, Greg A.

2013-03-12T23:59:59.000Z

68

Steam Reforming on Transition-metal Carbides from Density-functional Theory  

SciTech Connect (OSTI)

A screening study of the steam reforming reaction on clean and oxygen covered early transition-metal carbides surfaces is performed by means of density-functional theory calculations. It is found that carbides provide a wide spectrum of reactivities, from too reactive via suitable to too inert. Several molybdenum-based systems are identified as possible steam reforming catalysts. The findings suggest that carbides provide a playground for reactivity tuning, comparable to the one for pure metals.

Vojvodic, Aleksandra

2012-05-11T23:59:59.000Z

69

Steam reforming of low-level mixed waste  

SciTech Connect (OSTI)

The U.S. department of Energy (DOE) is responsible for the treatment and disposal of an inventory of approximately 160,000 tons of Low-Level Mixed Waste (LLMW). Most of this LLMW is stored in drums, barrels and steel boxes at 20 different sites throughout the DOE complex. The basic objective of low-level mixed waste treatment systems is to completely destroy the hazardous constituents and to simultaneously isolate and capture the radionuclides in a superior final waste form such as glass. The DOE is sponsoring the development of advanced technologies that meet this objective while achieving maximum volume reduction, low-life cycle costs and maximum operational safety. ThermoChem, Inc. is in the final stages of development of a steam-reforming system capable of treating a wide variety of DOE low-level mixed waste that meets these objectives. The design, construction, and testing of a nominal 1 ton/day Process Development Unit is described.

Voelker, G.E.; Steedman, W.G. [Thermochem, Inc., Columbia, MD (United States); Chandran, R.R. [Manufacturing and Technology Conversion International, Inc., Columbia, MD (United States)

1996-12-31T23:59:59.000Z

70

Steam reforming as a method to treat Hanford underground storage tank (UST) wastes  

SciTech Connect (OSTI)

This report summarizes a Sandia program that included partnerships with Lawrence Livermore National Laboratory and Synthetica Technologies, Inc. to design and test a steam reforming system for treating Hanford underground storage tank (UST) wastes. The benefits of steam reforming the wastes include the resolution of tank safety issues and improved radionuclide separations. Steam reforming destroys organic materials by first gasifying, then reacting them with high temperature steam. Tests indicate that up to 99% of the organics could be removed from the UST wastes by steam exposure. In addition, it was shown that nitrates in the wastes could be destroyed by steam exposure if they were first distributed as a thin layer on a surface. High purity alumina and nickel alloys were shown to be good candidates for materials to be used in the severe environment associated with steam reforming the highly alkaline, high nitrate content wastes. Work was performed on designing, building, and demonstrating components of a 0.5 gallon per minute (gpm) system suitable for radioactive waste treatment. Scale-up of the unit to 20 gpm was also considered and is feasible. Finally, process demonstrations conducted on non-radioactive waste surrogates were carried out, including a successful demonstration of the technology at the 0.1 gpm scale.

Miller, J.E.; Kuehne, P.B. [eds.] [and others

1995-07-01T23:59:59.000Z

71

A novel technique for on-line coke gasification during propane steam reforming using forced CO2 cycling.  

E-Print Network [OSTI]

??Steam reforming is an important source of synthesis gas production that is used by major petrochemical processes such as ammonia, methanol and the Fisher-Tropsch process.… (more)

Alenazey, Feraih Sheradh

2011-01-01T23:59:59.000Z

72

New Insights into Reaction Mechanisms of Ethanol Steam Reforming on Co-ZrO2  

SciTech Connect (OSTI)

The reaction pathway of ethanol steam reforming on Co-ZrO2 has been identified and the active sites associated with each step are proposed. Ethanol is converted to acetaldehyde and then to acetone, followed by acetone steam reforming. More than 90% carbon was found to follow this reaction pathway. N2-Sorption, X-ray Diffraction (XRD), Temperature Programmed Reduction (TPR), in situ X-ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy, as well as theoretical Density Functional Theory (DFT) calculations have been employed to identify the structure and functionality of the catalysts, which was further used to correlate their performance in ESR. It was found that metallic cobalt is mainly responsible for the acetone steam reforming reactions; while, CoO and basic sites on the support play a key role in converting ethanol to acetone via dehydrogenation and condensation/ketonization reaction pathways. The current work provides fundamental understanding of the ethanol steam reforming reaction mechanisms on Co-ZrO2 catalysts and sheds light on the rational design of selective and durable ethanol steam reforming catalysts.

Sun, Junming; Karim, Ayman M.; Mei, Donghai; Engelhard, Mark H.; Bao, Xinhe; Wang, Yong

2015-01-01T23:59:59.000Z

73

Fixed Bed Counter Current Gasification of Mesquite and Juniper Biomass Using Air-steam as Oxidizer  

E-Print Network [OSTI]

Thermal gasification of biomass is being considered as one of the most promising technologies for converting biomass into gaseous fuel. Here we present results of gasification, using an adiabatic bed gasifier with air, steam as gasification medium...

Chen, Wei 1981-

2012-11-27T23:59:59.000Z

74

Steam reforming on transition-metal carbides from density-functional theory  

E-Print Network [OSTI]

A screening study of the steam reforming reaction (CH_4 + H_2O -> CO + 3H_2) on early transition-metal carbides (TMC's) is performed by means of density-functional theory calculations. The set of considered surfaces includes the alpha-Mo_2C(100) surfaces, the low-index (111) and (100) surfaces of TiC, VC, and delta-MoC, and the oxygenated alpha-Mo_2C(100) and TMC(111) surfaces. It is found that carbides provide a wide spectrum of reactivities towards the steam reforming reaction, from too reactive via suitable to too inert. The reactivity is discussed in terms of the electronic structure of the clean surfaces. Two surfaces, the delta-MoC(100) and the oxygen passivated alpha-Mo_2C(100) surfaces, are identified as promising steam reforming catalysts. These findings suggest that carbides provide a playground for reactivity tuning, comparable to the one for pure metals.

Vojvodic, Aleksandra

2009-01-01T23:59:59.000Z

75

Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR)  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of Energy StrainClientDesignOffice - 201420122 DOE Hydrogen andTechnology

76

Promotion effect of cobalt-based catalyst with rare earth for the ethanol steam reforming  

SciTech Connect (OSTI)

Catalytic performance of ethanol steam reforming (ESR) was investigated on praseodymium (Pr) modified ceria-supported cobalt oxide catalyst. The ceria-supported cobalt oxide (Ce-Co) catalyst was prepared by co-precipitation-oxidation (CPO) method, and the doped Pr (5 and 10 wt% loading) catalysts (Pr{sub 5}?Ce?Co and Pr{sub 10}?Ce?Co) were prepared by incipient wetness impregnation method. The reduction pretreatment under 250 and 400 °C (H250 and H400) was also studied. All samples were characterized by XRD, TPR and TEM. Catalytic performance of ESR was tested from 250 to 500 °C in a fixed-bed reactor. The doping of Pr into the ceria lattice has significantly promoted the activity and reduced the coke formation. The products distribution also can be influenced by the different reduction pretreatment. The Pr{sub 10}?Ce?Co?H400 sample is a preferential ESR catalyst, where the hydrogen distribution approaches 73% at 475 °C with less amounts (< 2%) of CO and CH{sub 4}.

Chiou, Josh Y. Z.; Chen, Ya-Ping; Yu, Shen-Wei; Wang, Chen-Bin [Department of Chemical and Materials Engineering, Chung Cheng Institute of Technology, National Defense University, Tahsi, Taoyuan 33509, Taiwan (China)

2013-12-16T23:59:59.000Z

77

Hydrogen production from steam reforming of coke oven gas and its utility for indirect reduction of iron oxides in blast  

E-Print Network [OSTI]

of coal and coke are consumed for heating and reducing iron oxides [2,3]. As a result, BFs have becomeHydrogen production from steam reforming of coke oven gas and its utility for indirect reduction 2012 Available online 18 June 2012 Keywords: Steam reforming Hydrogen and syngas production Coke oven

Leu, Tzong-Shyng "Jeremy"

78

Steam reforming of fuel to hydrogen in fuel cells  

DOE Patents [OSTI]

A fuel cell capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Fraioli, Anthony V. (Hawthorne Woods, IL); Young, John E. (Woodridge, IL)

1984-01-01T23:59:59.000Z

79

Steam reforming of fuel to hydrogen in fuel cell  

DOE Patents [OSTI]

A fuel cell is described capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Young, J.E.; Fraioli, A.V.

1983-07-13T23:59:59.000Z

80

CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER  

SciTech Connect (OSTI)

This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-l0-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FBSR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-5.2.1-2010-001, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.

DUNCAN JB; HUBER HJ

2011-04-21T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101/102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER  

SciTech Connect (OSTI)

This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-10-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FB SR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-S.2.1-20 1 0-00 1, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, 'Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.'

DUNCAN JB; HUBER HJ

2011-06-08T23:59:59.000Z

82

EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY  

E-Print Network [OSTI]

1 EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY O. Le Corre1 , C for a CHP plant based on spark ignition engine running under lean conditions. An overall auto combustion engine. The potential benefits of using H2 in spark ignition (SI) engines may be listed as follows

Paris-Sud XI, Université de

83

Life Cycle Assessment of Hydrogen Production via Natural Gas Steam Reforming  

SciTech Connect (OSTI)

A life cycle assessment of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases as well as other major environmental consequences. LCA is a systematic analytical method that helps identify and evaluate the environmental impacts of a specific process or competing processes.

Spath, P. L.; Mann, M. K.

2000-09-28T23:59:59.000Z

84

Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon  

DOE Patents [OSTI]

In the steam reforming of hydrocarbon, particularly methane, under elevated temperature and pressure to produce hydrogen, a feed of steam and hydrocarbon is fed into a first reaction volume containing essentially only reforming catalyst to partially reform the feed. The balance of the feed and the reaction products of carbon dioxide and hydrogen are then fed into a second reaction volume containing a mixture of catalyst and adsorbent which removes the carbon dioxide from the reaction zone as it is formed. The process is conducted in a cycle which includes these reactions followed by countercurrent depressurization and purge of the adsorbent to regenerate it and repressurization of the reaction volumes preparatory to repeating the reaction-sorption phase of the cycle.

Sircar, Shivaji (Wescosville, PA); Hufton, Jeffrey Raymond (Fogelsville, PA); Nataraj, Shankar (Allentown, PA)

2000-01-01T23:59:59.000Z

85

Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis  

SciTech Connect (OSTI)

The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

T.A. Semelsberger

2004-10-01T23:59:59.000Z

86

Studies of mechanisms and kinetics of methane and ethane steam reforming on nickel catalysts  

SciTech Connect (OSTI)

Methane and ethane adsorption/desorption and reaction on steam-reforming catalysts, Ni(INCO), Ni/ZrO{sub 2}, and Ni/CaAl{sub 2}O{sub 4}, were studied by temperature-programmed desorption (TPD), temperature-programmed surface reaction (TPSR), and thermogravimetric (TGA) techniques. The data show that only a fraction of the methane adsorbed (determined by TPSR with H{sub 2}) on nickel catalysts is desorbed during TPD experiments. The results of TPD indicate supports and promoters affect the adsorption of methane and ethane, and transformation of adsorbed carbon species. Several carbon types formed during methane and ethane adsorptions including {alpha}, {beta}, {gamma}, vermicular (v), and graphitic (c) carbon can be identified by TPSR. These data indicate that the distribution of these carbon forms is also strongly a function of adsorption temperature and catalyst. The results show that there are significant quantities of CH{sub 4}, CO, and CO{sub 2} desorbed during TPSR reaction of H{sub 2}O with preadsorbed CH{sub 4}, CD{sub 4} and C{sub 2}H{sub 6}. The agreement between previously reported steady-state and the unsteady-state steam reforming reforming rates of this study indicates that the steam-reforming kinetic data can be quantitatively measured by TPSR experiments.

Hsieh, H.Y.

1988-01-01T23:59:59.000Z

87

MINERALIZING, STEAM REFORMING TREATMENT OF HANFORD LOW-ACTIVITY WASTE (a.k.a. INEEL/EXT-05-02526)  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) documented, in 2002, a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified steam reforming technology as a candidate for supplemental treatment of as much as 70% of the low-activity waste (LAW). Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was completed in a 15-cm-diameter reactor vessel. The pilot scale facility was equipped with a cyclone separator and heated sintered metal filters for particulate removal, a thermal oxidizer for reduced gas species and NOx destruction, and a packed activated carbon bed for residual volatile species capture. The pilot scale equipment is owned by the DOE, but located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Pilot scale testing was performed August 2–5, 2004. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory (INEEL), Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Science Application International Corporation, owners of the STAR Center, personnel performed actual pilot scale operation. The pilot scale test achieved a total of 68.4 hours of cumulative/continuous processing operation before termination in response to a bed de-fluidization condition. 178 kg of LAW surrogate were processed that resulted in 148 kg of solid product, a mass reduction of about 17%. The process achieved essentially complete bed turnover within approximately 40 hours. Samples of mineralized solid product materials were analyzed for chemical/physical properties. SRNL will report separately the results of product performance testing that were accomplished.

A. L. Olson; N. R. Soelberg; D. W. Marshall; G. L. Anderson

2005-02-01T23:59:59.000Z

88

Investigation of Reaction Networks and Active Sites In Bio-Ethanol Steam Reforming Over Co-Based Catalysts  

Broader source: Energy.gov [DOE]

Paper by Umit S. Ozkan, Hua Song, and Lingzhi Zhang (Ohio State University) on the fundamental understanding of reaction networks, active sites of deactivation mechanisms of potential bio-ethanol steam reforming catalysts.

89

Demonstration of Energy Efficient Steam Reforming in Microchannels for Automotive Fuel Processing  

SciTech Connect (OSTI)

A compact, energy efficient microchannel steam reforming system has been demonstrated. The unit generates sufficient reformate to provide H2 to a 10 kWe PEM fuel cell (when coupled with a water-gas shift and CO cleanup reactors). The overall volume of the reactor is 4.9 liters while that of the supporting network of heat exchangers is 1.7 liters . Use of a microchannel configuration in the steam reforming reactor produces rapid heat and mass transport which enables fast kinetics for the highly endothermic reaction. Heat is provided to the reactor by a combustion gas flowing in interleaved microchannels in cross flow with the reaction channels. A network of microchannel heat exchangers allows recovery of heat in the reformate product and combustion exhaust streams for use in vaporizing water and fuel, preheating reactants to reactor temperature and preheating combustion air. The microchannel architecture enables very compact and highly effective heat exchangers to be constructed. As a result of the heat exchange network, the system exhaust temperatures are typically ~50?C for the combustion gas and ~130?C for the reformate product while the reactor is operated at 750?C. While reforming isooctane at a rate sufficient to supply a 13.7 kWe fuel cell the system achieved 98.6% conversion with an estimated overall system efficiency after integration with WGS and PEM fuel cell of 44% (electrical output / LHV fuel). The efficiency estimate assumes integration with a WGS reactor (90% conversion CO to CO2 with 100% selectivity) and a PEM fuel cell (64% power conversion effectiveness with 85% H2 utilization for an overall 54% efficiency) and does not include parasitic losses for compression of combustion air. Acknowledgement The work described here was funded by the U.S. Department of Energy, Office of Transportation Technology as part of the OTT Fuel Cells Program.

Whyatt, Greg A.; TeGrotenhuis, Ward E.; Geeting, John GH; Davis, James M.; Wegeng, Robert S.; Pederson, Larry R.

2002-01-01T23:59:59.000Z

90

Feasibility Analysis of Steam Reforming of Biodiesel by-product Glycerol to Make Hydrogen  

E-Print Network [OSTI]

, lubricants, cleaners, and semiconductor circuits. It can be used to make electricity. NASA is the primary user of hydrogen as energy fuel-called fuel cells- to power the shuttle?s electrical system (Hydrogen Energy, 2008). Hydrogen can fuel tomorrow?s fuel-cell... wide application in industries and refineries. In the United States, about 17.2 billion pounds of hydrogen are produced per year and 95% are from steam reforming of methane (Hydrogen Now). It can be used as a fuel in tomorrow?s fuel-cell vehicles...

Joshi, Manoj

2009-06-09T23:59:59.000Z

91

Engineering Study for a Full Scale Demonstration of Steam Reforming Black Liquor Gasification at Georgia-Pacific's Mill in Big Island, Virginia  

SciTech Connect (OSTI)

Georgia-Pacific Corporation performed an engineering study to determine the feasibility of installing a full-scale demonstration project of steam reforming black liquor chemical recovery at Georgia-Pacific's mill in Big Island, Virginia. The technology considered was the Pulse Enhanced Steam Reforming technology that was developed and patented by Manufacturing and Technology Conversion, International (MTCI) and is currently licensed to StoneChem, Inc., for use in North America. Pilot studies of steam reforming have been carried out on a 25-ton per day reformer at Inland Container's Ontario, California mill and on a 50-ton per day unit at Weyerhaeuser's New Bern, North Carolina mill.

Robert De Carrera; Mike Ohl

2002-03-19T23:59:59.000Z

92

Reformer-pressure swing adsorption process for the production of carbon monoxide  

SciTech Connect (OSTI)

An improved process for the production of carbon monoxide by the steam reforming of hydrocarbons is described comprising: (a) catalytically reacting a fluid hydrocarbon feed stream with steam in a steam reformer; (b) passing the reformer effluent containing hydrogen, carbon monoxide and carbon dioxide from the steam reformer, without scrubbing to remove the carbon dioxide content thereof, to a pressure swing adsorption system having at least four adsorbent beds, each bed of which, on a cyclic basis, undergoes a processing sequence; (c) recycling the carbon dioxide-rich stream to the steam reformer for reaction with additional quantities of the hydrocarbon feed stream being passed to the stream reformer to form additional quantities of carbon monoxide and hydrogen, with product recovery being enhanced and the need for employing a carbon dioxide wash system being obviated.

Fuderer, A.

1988-02-23T23:59:59.000Z

93

PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift  

SciTech Connect (OSTI)

Pd/ZnO/Al2O3 catalysts were studied for water-gas-shift (WGS), methanol steam reforming, and reverse-water-gas-shift (RWGS) reactions. WGS activity was found to be dependent on the Pd:Zn ratio with a maximum activity obtained at approximately 0.50, which was comparable to that of a commercial Pt-based catalyst. The catalyst stability was demonstrated for 100 hours time-on-stream at a temperature of 3600C without evidence of metal sintering. WGS reaction rates were approximately 1st order with respect to CO concentration, and kinetic parameters were determined to be Ea = 58.3 kJ mol-1 and k0 = 6.1x107 min-1. During methanol steam reforming, the CO selectivities were observed to be lower than the calculated equilibrium values over a range of temperatures and steam/carbon ratios studied while the reaction rate constants were approximately of the same magnitude for both WGS and methanol steam reforming. These results indicate that although Pd/ZnO/Al2O3 are active WGS catalysts, WGS is not involved in methanol steam reforming. RWGS rate constants are on the order of about 20 times lower than that of methanol steam reforming, suggesting that RWGS reaction could be one of the sources for small amount of CO formation in methanol steam reforming.

Dagle, Robert A.; Platon, Alexandru; Datye, Abhaya K.; Vohs, John M.; Wang, Yong; Palo, Daniel R.

2008-03-07T23:59:59.000Z

94

Methane steam reforming analysis in a palladium-based catalytic membrane reactor  

SciTech Connect (OSTI)

The methane steam reforming in a catalytic membrane reactor has been studied. A previous theoretical study of this reaction has been carried out. In the model a global kinetic rate as a function of three reactions over nickel catalyst as proposed by Xu and Froment has been considered. It has been shown that the counterflow configuration has, at high temperature (500 C), a marginal advantage on parallel flow and, also, that the space velocity cannot be considered a design variable for membrane reactors. A laboratory plant was realized utilizing membranes of Pd and Pd/Ag supported on Al{sub 2}O{sub 3}. The Pd membranes utilized have been prepared using the co-condensation technique and the electroless plating method. A comparison of the overall membrane performance has also been carried out. The experiments were aimed to study the effects of several parameters such as temperature, feed flow rate, and feed molar ratio on the methane conversion. The experimental results have been compared with the data predicted by the previously developed theoretical model.

Barbieri, G. [CNR, Rende (Italy). Inst. of Research on Membranes and Chemical Reactors Modeling] [CNR, Rende (Italy). Inst. of Research on Membranes and Chemical Reactors Modeling; Violante, V. [CR ENEA Frascati (Italy)] [CR ENEA Frascati (Italy); Maio, F.P. di; Criscuoli, A. [Univ. of Calabria, Rende (Italy). Dept. of Chemical Engineering and Materials] [Univ. of Calabria, Rende (Italy). Dept. of Chemical Engineering and Materials; Drioli, E. [CNR, Rende (Italy). Inst. of Research on Membranes and Chemical Reactors Modeling] [CNR, Rende (Italy). Inst. of Research on Membranes and Chemical Reactors Modeling; [Univ. of Calabria, Rende (Italy). Dept. of Chemical Engineering and Materials

1997-08-01T23:59:59.000Z

95

Steady-State Simulation of Steam Reforming of INEEL Tank Farm Waste  

SciTech Connect (OSTI)

A steady-state model of the Sodium-Bearing Waste steam reforming process at the Idaho National Engineering and Environmental Laboratory has been performed using the commercial ASPEN Plus process simulator. The preliminary process configuration and its representation in ASPEN are described. As assessment of the capability of the model to mechanistically predict product stream compositions was made, and fidelity gaps and opportunities for model enhancement were identified, resulting in the following conclusions: 1) Appreciable benefit is derived from using an activity coefficient model for electrolyte solution thermodynamics rather than assuming ideality (unity assumed for all activity coefficients). The concentrations of fifteen percent of the species present in the primary output stream were changed by more than 50%, relative to Electrolyte NRTL, when ideality was assumed; 2) The current baseline model provides a good start for estimating mass balances and performing integrated process optimization because it contains several key species, uses a mechanistic electrolyte thermodynamic model, and is based on a reasonable process configuration; and 3) Appreciable improvement to model fidelity can be realized by expanding the species list and the list of chemical and phase transformations. A path forward is proposed focusing on the use of an improved electrolyte thermodynamic property method, addition of chemical and phase transformations for key species currently absent from the model, and the combination of RGibbs and Flash blocks to simulate simultaneous phase and chemical equilibria in the off-gas treatment train.

Nichols, Todd Travis; Taylor, Dean Dalton; Wood, Richard Arthur; Barnes, Charles Marshall

2002-08-01T23:59:59.000Z

96

Steady-State Simulation of Steam Reforming of INEEL Tank Farm Waste  

SciTech Connect (OSTI)

A steady-state model of the Sodium-Bearing Waste steam reforming process at the Idaho National Engineering and Environmental Laboratory has been performed using the commercial ASPEN Plus process simulator. The preliminary process configuration and its representation in ASPEN are described. As assessment of the capability of the model to mechanistically predict product stream compositions was made, and fidelity gaps and opportunities for model enhancement were identified, resulting in the following conclusions: (1) Appreciable benefit is derived from using an activity coefficient model for electrolyte solution thermodynamics rather than assuming ideality (unity assumed for all activity coefficients). The concentrations of fifteen percent of the species present in the primary output stream were changed by more than 50%, relative to Electrolyte NRTL, when ideality was assumed; (2) The current baseline model provides a good start for estimating mass balances and performing integrated process optimization because it contains several key species, uses a mechanistic electrolyte thermodynamic model, and is based on a reasonable process configuration; and (3) Appreciable improvement to model fidelity can be realized by expanding the species list and the list of chemical and phase transformations. A path forward is proposed focusing on the use of an improved electrolyte thermodynamic property method, addition of chemical and phase transformations for key species currently absent from the model, and the combination of RGibbs and Flash blocks to simulate simultaneous phase and chemical equilibria in the off-gas treatment train.

Nichols, T.T.; Taylor, D.D.; Wood, R.A.; Barnes, C.M.

2002-08-15T23:59:59.000Z

97

Ethanol Steam Reforming on Co/CeO2: The Effect of ZnO Promoter  

SciTech Connect (OSTI)

A series of ZnO promoted Co/CeO2 catalysts were synthesized and characterized using XRD, TEM, H2-TPR, CO chemisorption, O2-TPO, IR-Py, and CO2-TPD. The effects of ZnO on the catalytic performances of Co/CeO2 were studied in ethanol steam reforming. It was found that the addition of ZnO facilitated the oxidation of Co0 via enhanced oxygen mobility of the CeO2 support which decreased the activity of Co/CeO2 in C–C bond cleavage of ethanol. 3 wt% ZnO promoted Co/CeO2 exhibited minimum CO and CH4 selectivity and maximum CO2 selectivity. This resulted from the combined effects of the following factors with increasing ZnO loading: (1) enhanced oxygen mobility of CeO2 facilitated the oxidation of CHx and CO to form CO2; (2) increased ZnO coverage on CeO2 surface reduced the interaction between CHx/CO and Co/CeO2; and (3) suppressed CO adsorption on Co0 reduced CO oxidation rate to form CO2. In addition, the addition of ZnO also modified the surface acidity and basicity of CeO2, which consequently affected the C2–C4 product distributions.

Davidson, Stephen; Sun, Junming; Wang, Yong

2013-12-02T23:59:59.000Z

98

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

SciTech Connect (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R&D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

99

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

SciTech Connect (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

100

Corrosion of SiC and oxide-composite ceramics by a simulated steam-reformer atmosphere  

SciTech Connect (OSTI)

To achieve higher process efficiency by using pressurized reactants and/or heat transfer fluids, the US DOE is promoting development of high-pressure heat exchanger systems under cost-sharing agreements with industrial contractors. The steam reformer would contain more than 600 tubes. Because the combination of high temperature and pressure differential of 12.7 kg/cm{sup 2} (180 psig) across the tube wall is too severe for metallic tubes, ceramic materials are being considered for reformer tubes. Their use is expected to increase the efficiency of steam reformers by about 19%. At ORNL, four SiC ceramics, a SiC-TiB{sub 2} composite, a Si{sub 3}N{sub 4}-bonded SiC ceramic, and two alumina-matrix composites were selected as candidate materials for heat exchanger/steam-reformer tubes. These commercially available materials were exposed to a simulated steam-reformer atmosphere for up to 2000 h at 1260{degrees}C to assess their corrosion behavior and the effect of the exposure on their flexure strength (in air) at 20 and 1260{degrees}C. The approximate partial pressures of the constituents of the gas mixture at 1 atm total pressure were 0.54 H{sub 2}, 0.13 CO, 0.03 CO{sub 2}m 0.004 CH{sub 4}, and 0.30 H{sub 2}O. All but one material had net weight gains during the exposure test. The flexure strengths of the SiC and Si{sub 3}N{sub 4} ceramics and the SiC-TiB{sub 2} composite at 20 and 1260{degrees}C were not changed significantly by corrosion. The strengths of the alumina-matrix composites were decreased by corrosion; however, the strength of one of these (reinforced with SiC whiskers) was still higher than that of any other material after 500 h. The other alumina composite (containing SiC particles) exhibited the largest strength decrease of any material. The strength retention of the SiC ceramics and the SiC-TiB{sub 2} composite and the strength loss of the composites were associated with surface layers caused by corrosion. 12 refs., 12 figs., 4 tabs.

Federer, J.I.; Kim, H.E.; Moorhead, A.J.

1991-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Pyrolysis/Steam Reforming Technology for Treatment of TRU Orphan Wastes  

SciTech Connect (OSTI)

Certain transuranic (TRU) waste streams within the Department of Energy (DOE) complex cannot be disposed of at the Waste Isolation Pilot Plant (WIPP) because they do not meet the shipping requirements of the TRUPACT-II or the disposal requirements of the Waste Analysis Plan (WAP) in the WIPP RCRA Part B Permit. These waste streams, referred to as orphan wastes, cannot be shipped or disposed of because they contain one or more prohibited items, such as liquids, volatile organic compounds (VOCs), hydrogen gas, corrosive acids or bases, reactive metals, or high concentrations of polychlorinated biphenyl (PCB), etc. The patented, non-incineration, pyrolysis and steam reforming processes marketed by THOR Treatment Technologies LLC removes all of these prohibited items from drums of TRU waste and produces a dry, inert, inorganic waste material that meets the existing TRUPACT-II requirements for shipping, as well as the existing WAP requirements for disposal of TRU waste at WIPP. THOR Treatment Technologies is a joint venture formed in June 2002 by Studsvik, Inc. (Studsvik) and Westinghouse Government Environmental Services Company LLC (WGES) to further develop and deploy Studsvik's patented THORSM technology within the DOE and Department of Defense (DoD) markets. The THORSM treatment process is a commercially proven system that has treated over 100,000 cu. ft. of nuclear waste from commercial power plants since 1999. Some of this waste has had contact dose rates of up to 400 R/hr. A distinguishing characteristic of the THORSM process for TRU waste treatment is the ability to treat drums of waste without removing the waste contents from the drum. This feature greatly minimizes criticality and contamination issues for processing of plutonium-containing wastes. The novel features described herein are protected by issued and pending patents.

Mason, J. B.; McKibbin, J.; Schmoker, D.; Bacala, P.

2003-02-27T23:59:59.000Z

102

Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts  

SciTech Connect (OSTI)

In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl2O4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl2O4 spinel support are stable during the BSR in the temperature range of 700-850?C. Compared to the Ir/MgAl2O4 catalyst, the Rh/MgAl2O4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function of the H2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR activity on the supported highly dispersed Rh catalyst can be rationalized by the thermodynamic limitation for the very first C-C bond scission of benzene on the small Ir50 catalyst. The C-C bond scission of benzene on the small Ir50 catalyst is highly endothermic although the barrier is competitive with the barriers of both the C-C and the C-H bond-breakings on the small Rh50 catalyst. The calculations also imply that, for the supported Rh catalysts the C-C and C-H bond scissions are competitive, independently of the Rh cluster sizes. After the initial dissociation step via either the C-C or the C-H bond scission, the C-H bond breaking seems to be more favorable rather than the C-C bond breaking on the larger Rh terrace surface. This work was financially supported by the United States Department of Energy’s Office of Biomass Program’s. Computing time was granted by a user project at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

Mei, Donghai; Lebarbier, Vanessa MC; Rousseau, Roger J.; Glezakou, Vassiliki Alexandra; Albrecht, Karl O.; Kovarik, Libor; Flake, Matthew D.; Dagle, Robert A.

2013-06-01T23:59:59.000Z

103

Fixed bed testing of durable, steam resistant zinc oxide containing sorbents  

SciTech Connect (OSTI)

The US Department of Energy is currently developing Integrated Gasification combined Cycle (IGCC) systems for electrical power generation. It has been predicted that IGCC plants with hot gas cleanup will be superior to conventional pulverized coal-fired power plants in overall plant efficiency and environmental performance. Development of a suitable regenerable sorbent is a major barrier issue in the hot gas cleanup program for IGCC systems. This has been a challenging problem during the last 20 years, since many of the sorbents developed in the program could not retain their reactivity and physical integrity during repeated cycles of sulfidation and regeneration reactions. Two promising sorbents and (METC6), which were capable of sustaining their reactivity and physical integrity during repeated sulfidation/regeneration cycles, have been developed at the Morgantown Energy Technology Center (METC) during the past year. These sorbents were tested (sulfided) both in low-pressure (260 kPa/37.7 psia) and high-pressure (1034 kPa/150 psia) fixed-bed reactors at 538{degrees}C (1000{degrees}F) with simulated KRW coal gas. High-pressure testing was continued for 20 cycles with steam regeneration. There were no appreciable changes in sulfidation capacity of the sorbents during the 20-cycle testing. The crush strength of the sorbent actually improved after 20 cycles and there were no indications of spalling or any other physical deterioration of the sorbents. In testing to date, these sorbents exhibit better overall sulfur capture performance than the conventional sorbents.

Siriwardane, R.V.; Grimm, U.; Poston, J. [USDOE Morgantown Energy Technology Center, WV (United States); Monaco, S.J. [EG& G dTechnical Services of West Virginia, Inc., Morgantown, WV (United States)

1994-12-31T23:59:59.000Z

104

NiW and NiRu Bimetallic Catalysts for Ethylene Steam Reforming: Alternative Mechanisms for Sulfur Resistance  

SciTech Connect (OSTI)

Previous investigations of Ni-based catalysts for the steam reforming of hydrocarbons have indicated that the addition of a second metal can reduce the effects of sulfur poisoning. Two systems that have previously shown promise for such applications, NiW and NiRu, are considered here for the steam reforming of ethylene, a key component of biomass derived tars. Monometallic and bimetallic Al{sub 2}O{sub 3}-supported Ni and W catalysts were employed for ethylene steam reforming in the presence and absence of sulfur. The NiW catalysts were less active than Ni in the absence of sulfur, but were more active in the presence of 50 ppm H{sub 2}S. The mechanism for the W-induced improvements in sulfur resistance appears to be different from that for Ru in NiRu. To probe reasons for the sulfur resistance of NiRu, the adsorption of S and C{sub 2}H{sub 4} on several bimetallic NiRu alloy surfaces ranging from 11 to 33 % Ru was studied using density functional theory (DFT). The DFT studies reveal that sulfur adsorption is generally favored on hollow sites containing Ru. Ethylene preferentially adsorbs atop the Ru atom in all the NiRu (111) alloys investigated. By comparing trends across the various bimetallic models considered, sulfur adsorption was observed to be correlated with the density of occupied states near the Fermi level while C{sub 2}H{sub 4} adsorption was correlated with the number of unoccupied states in the d-band. The diverging mechanisms for S and C{sub 2}H{sub 4} adsorption allow for bimetallic surfaces such as NiRu that enhance ethylene binding without accompanying increases in sulfur binding energy. In contrast, bimetallics such as NiSn and NiW appear to decrease the affinity of the surface for both the reagent and the poison.

Rangan, M.; Yung, M. M.; Medlin, J. W.

2012-06-01T23:59:59.000Z

105

E-Print Network 3.0 - autothermal steam reforming Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(ITM) Reactor - Air Products and Chemicals, Inc. Autothermal Reforming (ATR) - Praxair Inc. 12... sequestration. 2005 2010 2013 2015 12;Barriers to Hydrogen Production...

106

Minimizing the formation of coke and methane on Co nanoparticles in steam reforming of biomass-derived oxygenates  

SciTech Connect (OSTI)

Fundamental understanding and control of chemical transformations are essential to the development of technically feasible and economically viable catalytic processes for efficient conversion of biomass to fuels and chemicals. Using an integrated experimental and theoretical approach, we report high hydrogen selectivity and catalyst durability of acetone steam reforming (ASR) on inert carbon supported Co nanoparticles. The observed catalytic performance is further elucidated on the basis of comprehensive first-principles calculations. Instead of being considered as an undesired intermediate prone for catalyst deactivation during bioethanol steam reforming (ESR), acetone is suggested as a key and desired intermediate in proposed two-stage ESR process that leads to high hydrogen selectivity and low methane formation on Co-based catalysts. The significance of the present work also sheds a light on controlling the chemical transformations of key intermediates in biomass conversion such as ketones. We gratefully acknowledge the financial support from U. S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences, and the Laboratory directed research and development (LDRD) project of Pacific Northwest National Laboratory (PNNL). Computing time was granted by the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL). The EMSL is a U.S. DOE national scientific user facility located at PNNL, and sponsored by the U.S. DOE’s Office of Biological and Environmental Research.

Sun, Junming; Mei, Donghai; Karim, Ayman M.; Datye, Abhaya K.; Wang, Yong

2013-06-01T23:59:59.000Z

107

Operation of a steam hydro-gasifier in a fluidized bed reactor  

E-Print Network [OSTI]

Using Self-Sustained Hydro- Gasification." [0011] In aprocess, using a steam hydro-gasification reactor (SHR) thepyrolysis and hydro-gasification in a single step. This

Park, Chan Seung; Norbeck, Joseph N.

2008-01-01T23:59:59.000Z

108

Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form  

SciTech Connect (OSTI)

The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sent to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.

Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.; Valenta, Michelle M.; Pires, Richard P.

2011-09-12T23:59:59.000Z

109

Operation of a steam hydro-gasifier in a fluidized bed reactor  

E-Print Network [OSTI]

OPERATION OF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BEDMaterial Using Self-Sustained Hydro- Gasification." [0011]the process, using a steam hydro-gasification reactor (SHR)

Park, Chan Seung; Norbeck, Joseph N.

2008-01-01T23:59:59.000Z

110

Operation of a steam hydro-gasifier in a fluidized bed reactor  

E-Print Network [OSTI]

OF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BED REACTOROF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BED REACTOR F Iis fed into a hydro-gasifier reactor. One such process was

Park, Chan Seung; Norbeck, Joseph N.

2008-01-01T23:59:59.000Z

111

Demonstration of a Highly Efficient Solid Oxide Fuel Cell Power System Using Adiabatic Steam Reforming and Anode Gas Recirculation  

SciTech Connect (OSTI)

Solid oxide fuel cells (SOFC) are currently being developed for a wide variety of applications because of their high efficiency at multiple power levels. Applications for SOFCs encompass a large range of power levels including 1-2 kW residential combined heat and power applications, 100-250 kW sized systems for distributed generation and grid extension, and MW-scale power plants utilizing coal. This paper reports on the development of a highly efficient, small-scale SOFC power system operating on methane. The system uses adiabatic steam reforming of methane and anode gas recirculation to achieve high net electrical efficiency. The anode exit gas is recirculated and all of the heat and water required for the endothermic reforming reaction are provided by the anode gas emerging from the SOFC stack. Although the single-pass fuel utilization is only about 55%, because of the anode gas recirculation the overall fuel utilization is up to 93%. The demonstrated system achieved gross power output of 1650 to 2150 watts with a maximum net LHV efficiency of 56.7% at 1720 watts. Overall system efficiency could be further improved to over 60% with use of properly sized blowers.

Powell, Michael R.; Meinhardt, Kerry D.; Sprenkle, Vincent L.; Chick, Lawrence A.; Mcvay, Gary L.

2012-05-01T23:59:59.000Z

112

Attrition resistant fluidizable reforming catalyst  

DOE Patents [OSTI]

A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

Parent, Yves O. (Golden, CO); Magrini, Kim (Golden, CO); Landin, Steven M. (Conifer, CO); Ritland, Marcus A. (Palm Beach Shores, FL)

2011-03-29T23:59:59.000Z

113

Process to Accomplish Autothermal or Steam Reforming Via a Reciprocating Compression Device  

SciTech Connect (OSTI)

The invention provides a method and apparatus for producing a synthesis gas from a variety of hydrocarbons. The apparatus (device) consists of a semi-batch, non-constant volume reactor to generate a synthesis gas. While the apparatus feeds mixtures of air, steam, and hydrocarbons into a cylinder where work is performed on the fluid by a piston to adiabatically raise its temperature without heat transfer from an external source.

Lyons, David K.; James, Robert; Berry, David A.; Gardern, Todd

2004-09-21T23:59:59.000Z

114

Process And Apparatus To Accomplish Autothermal Or Steam Reforming Via A Reciprocating Compression Device  

DOE Patents [OSTI]

The invention provides a method and apparatus for producing a synthesis gas from a variety of hydrocarbons. The apparatus (device) consists of a semi-batch, non-constant volume reactor to generate a synthesis gas. While the apparatus feeds mixtures of air, steam, and hydrocarbons into a cylinder where work is performed on the fluid by a piston to adiabatically raise its temperature without heat transfer from an external source.

Lyons, K. David (Morgantown, WV); James, Robert (Fairmont, WV); Berry, David A. (Mt. Morris, PA); Gardner, Todd (Morgantown, WV)

2004-09-21T23:59:59.000Z

115

DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR BENCH-SCALE REFORMER TREATABILITY STUDIES  

SciTech Connect (OSTI)

This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Bench-Scale Reforming testing. The type, quantity, and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluidized bed steam reformer. A determination of the adequacy of the fluidized bed steam reformer process to treat Hanford tank waste is required. The initial step in determining the adequacy of the fluidized bed steam reformer process is to select archived waste samples from the 222-S Laboratory that will be used in a bench scale tests. Analyses of the selected samples will be required to confirm the samples meet the shipping requirements and for comparison to the bench scale reformer (BSR) test sample selection requirements.

BANNING DL

2011-02-11T23:59:59.000Z

116

Statistical validation and an empirical model of hydrogen production enhancement found by utilizing passive flow disturbance in the steam-reformation process  

SciTech Connect (OSTI)

A passive flow disturbance has been proven to enhance the conversion of fuel in a methanol-steam reformer. This study presents a statistical validation of the experiment based on a standard 2{sup k} factorial experiment design and the resulting empirical model of the enhanced hydrogen producing process. A factorial experiment design was used to statistically analyze the effects and interactions of various input factors in the experiment. Three input factors, including the number of flow disturbers, catalyst size, and reactant flow rate were investigated for their effects on the fuel conversion in the steam-reformation process. Based on the experimental results, an empirical model was developed and further evaluated with an uncertainty analysis and interior point data. (author)

Erickson, Paul A.; Liao, Chang-hsien [Department of Mechanical and Aeronautical Engineering, University of California, One Shields Avenue, Davis, CA 95616 (United States)

2007-11-15T23:59:59.000Z

117

High Activity of Ce1-xNixO2-y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions  

SciTech Connect (OSTI)

The importance of the oxide: Ce{sub 0.8}Ni{sub 0.2}O{sub 2-y} is an excellent catalyst for ethanol steam reforming. Metal-oxide interactions perturb the electronic properties of the small particles of metallic nickel present in the catalyst under the reaction conditions and thus suppress any methanation activity. The nickel embedded in ceria induces the formation of O vacancies, which facilitate cleavage of the OH bonds in ethanol and water.

G Zhou; L Barrio; S Agnoli; S Senanayake; J Evans; A Kubacka; M Estrella; J Hanson; A Martinez-Arias; et al.

2011-12-31T23:59:59.000Z

118

Effects of temperature and pressure on the performance of a solid oxide fuel cell running on steam reformate of kerosene  

SciTech Connect (OSTI)

A button solid oxide fuel cell with a La0.6Sr0.4Co0.2Fe0.8O3 cathode and a nickel-YSZ anode was tested over a range of temperatures from 650 to 800°C and a range of pressures from 101 to 724 kPa. The fuel was simulated steam-reformed kerosene and the oxidant was air. The observed increases in open circuit voltages (OCV) were accurately predicted by the Nernst equation. Kinetics also increased, although the power boost due to kinetics was about two thirds as large as the boost due to OCV. The total power boost in going from 101 to 724 kPa at 750°C and 0.8 volts was 66%. Impedance spectroscopy demonstrated a significant decrease in electrodic losses at elevated pressures. Complex impedance spectra were dominated by a combination of low frequency processes that decreased markedly with increasing pressure. A composite of high-frequency processes also decreased with pressure, but to a lesser extent. An empirical algorithm that accurately predicts the increased fuel cell performance at elevated pressures was developed for our results and was also suitable for some, but not all, data reported in the literature.

Chick, Lawrence A.; Marina, Olga A.; Coyle, Christopher A.; Thomsen, Edwin C.

2013-08-15T23:59:59.000Z

119

976 JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 15, NO. 4, AUGUST 2006 Methanol Steam Reformer on a Silicon Wafer  

E-Print Network [OSTI]

by wafer bonding. The reactor bed was subsequently filled with catalyst particles. Thermal control.2006.878888 Binary diffusion coefficient . Mixture diffusion coefficient . Knudsen diffusion coeffcient . Effective mixture diffusion coefficient for transport in catalyst pores . Diameter of catalyst pellet (m

Malen, Jonathan A.

120

Fluidized Bed Steam Reformer (FBSR) Na-AI-SI (NAS) Waste Form for Hanford LAW and Secondary Waste  

SciTech Connect (OSTI)

FBSR sodium-aluminosilicate (NAS) waste form has been identified as a promising supplemental treatment technology for Hanford LAW and/or Waste Treatment Plant Secondary Waste (WTP-SW). Objectives of the project: 1) Prove the robustness of FBSR as a waste form for either LAW and/or WTP-SW; 2) Reduce the risk associated with implementing the FBSR NAS waste form as a supplemental treatment technology for Hanford LAW and/or WTP-SW; 3) Conduct two treatability studies with SRS radioactive wastes that have been shimmed to look like Hanford WTP-SW and LAW; 4) Conduct three treatability studies with actual Hanford tank wastes; 5) Fill key data gaps; 6) Link previous and new results together.

Jantzen, C.; Pierce, E.

2010-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG | Department ofHTS Cable Projects HTS Cable Projects FactHandbook|AWasteLow

122

Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP)  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNGInternational EnergyCommitteeRenewable1234Department ofTechnology FactKey

123

Bimetallic Ni-Rh catalysts with low amounts of Rh for the steam and autothermal reforming of n-butane for fuel-cell applications.  

SciTech Connect (OSTI)

Mono-metallic nickel and rhodium catalysts and bimetallic Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}, CeZrO{sub 2} and CeMgOx were prepared and evaluated for catalyzing the steam and autothermal reforming of n-butane. The binary Ni-Rh supported on La-Al{sub 2}O{sub 3} catalysts with low weight loading of rhodium exhibited higher H{sub 2} yields than Ni or Rh alone. The Ni-Rh/CeZrO{sub 2} catalyst exhibited higher performance and no coke formation, compared to the same metals on other supports. A NiAl{sub 2}O{sub 4} spinel phase was obtained on all Ni and Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}. The presence of rhodium stabilized the spinel phase as well as NiOx species upon reforming while Ni alone was mostly reduced into metallic species. Extended X-ray absorption fine-structure analysis showed evidence of Ni-Rh alloy during preparation and even further after an accelerated aging at 900C in a H{sub 2}/H{sub 2}O atmosphere.

Ferrandon, M.; Kropf, A. J.; Krause, T.; Chemical Sciences and Engineering Division

2010-05-15T23:59:59.000Z

124

Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study  

SciTech Connect (OSTI)

In this work we present a combined experimental and theoretical investigation of stable MgAl2O4 spinel-supported Rh and Ir catalysts for the steam methane reforming (SMR) reaction. Firstly, catalytic performance for a series of noble metal catalysts supported on MgAl2O4 spinel was evaluated for SMR at 600-850°C. Turnover rate at 850°C follows the order: Pd > Pt > Ir > Rh > Ru > Ni. However, Rh and Ir were found to have the best combination of activity and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed ~2 nm Rh and ~1 nm Ir clusters were formed on the MgAl2O4 spinel support. Scanning Transition Electron Microscopy (STEM) images show that excellent dispersion was maintained even under challenging high temperature conditions (e.g. at 850°C in the presence of steam) while Ir and Rh catalysts supported on Al2O3 were observed to sinter at increased rates under the same conditions. These observations were further confirmed by ab initio molecular dynamics (AIMD) simulations which find that ~1 nm Rh and Ir particles (50-atom cluster) bind strongly to the MgAl2O4 surfaces via a redox process leading to a strong metal-support interaction, thus helping anchor the metal clusters and reduce the tendency to sinter. Density functional theory (DFT) calculations suggest that these supported smaller Rh and Ir particles have a lower work function than larger more bulk-like ones, which enables them to activate both water and methane more effectively than larger particles, yet have a minimal influence on the relative stability of coke precursors. In addition, theoretical mechanistic studies were used to probe the relationship between structure and reactivity. Consistent with the experimental observations, our theoretical modeling results also suggest that the small spinel-supported Ir particle catalyst is more active than the counterpart of Rh catalyst for SMR. This work was financially supported by the United States Department of Energy (DOE)’s Bioenergy Technologies Office (BETO) and performed at the Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated for DOE by Battelle Memorial Institute. Computing time was granted by a user proposal at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) located at PNNL. Part of the computational time was provided by the National Energy Research Scientific Computing Center (NERSC).

Mei, Donghai; Glezakou, Vassiliki Alexandra; Lebarbier, Vanessa MC; Kovarik, Libor; Wan, Haiying; Albrecht, Karl O.; Gerber, Mark A.; Rousseau, Roger J.; Dagle, Robert A.

2014-07-01T23:59:59.000Z

125

Diesel Reforming for Fuel Cell Auxiliary Power Units  

SciTech Connect (OSTI)

This objective of this project was to develop technology suitable for onboard reforming of diesel. The approach was to examine catalytic partial oxidation and steam reforming.

Borup, R.; Parkinson, W. J.; Inbody, M.; Brosha, E.L.; Guidry, D.R.

2005-01-27T23:59:59.000Z

126

Autothermal reforming catalyst and process  

SciTech Connect (OSTI)

High activity steam reforming catalysts are described particularly adapted for use in autothermal reforming processes. A rhodium catalyst on a calcium oxide impregnated alumina substrate allow the autothermal reforming process to take place with substantially no carbon plugging at oxygen to carbon ratios below what had been considered critical for avoiding carbon plugging of the catalyst in the past.

Setzer, H. J.; Karavolis, S.; Lesieur, R. R.; Wnuck, W. G.

1984-09-25T23:59:59.000Z

127

Apparatus for production of synthesis gas using convective reforming  

SciTech Connect (OSTI)

This patent describes a system for the steam reforming of hydrocarbons into a hydrogen-rich gas. It comprises a convective reformer device having indirect heat exchange means for partially reforming a feed mixture of hydrocarbons and steam; a steam reforming furnace having a radiant section, reforming tubes in the radiant section, and means for producing radiant heat for the further reforming of the partially reformed effluent; an auto-thermal reformer for fully reforming the effluent; conduit means for passing the partially reformed effluent; conduit means for passing the effluent; and conduit means for passing the fully reformed effluent to supply the heat of reaction for the partial reformation of the hydrocarbon-steam feed mixture.

Karafian, M.; Tsang, I.C.

1991-04-09T23:59:59.000Z

128

Modeling of Pressurized Electrochemistry and Steam-Methane Reforming in Solid Oxide Fuel Cells and the Effects on Thermal and Electrical Stack Performance  

SciTech Connect (OSTI)

Summarizes work done to extend the electrochemical performance and methane reforming submodels to include the effects of pressurization and to demonstrate this new modeling capability by simulating large stacks operating on methane-rich fuel under pressurized and non-pressurized conditions. Pressurized operation boosts electrochemical performance, alters the kinetics of methane reforming, and effects the equilibrium composition of methane fuels. This work developed constitutive submodels that couple the electrochemistry, reforming, and pressurization to yield an increased capability of the modeling tool for prediction of SOFC stack performance.

Recknagle, Kurtis P.; Khaleel, Mohammad A.

2009-03-01T23:59:59.000Z

129

Process for purifying geothermal steam  

DOE Patents [OSTI]

Steam containing hydrogen sulfide is purified and sulfur recovered by passing the steam through a reactor packed with activated carbon in the presence of a stoichiometric amount of oxygen which oxidizes the hydrogen sulfide to elemental sulfur which is adsorbed on the bed. The carbon can be recycled after the sulfur has been recovered by vacuum distillation, inert gas entrainment or solvent extraction. The process is suitable for the purification of steam from geothermal sources which may also contain other noncondensable gases.

Li, Charles T. (Richland, WA)

1980-01-01T23:59:59.000Z

130

DUNCAN PRITCHARD Reforming Reformed Epistemology*  

E-Print Network [OSTI]

DUNCAN PRITCHARD Reforming Reformed Epistemology* 0. Introduction There has been a renaissance-called "reformed" defence of the rationality of reli- gious belief. The starting-point for this reformed conception concern here. Instead, I will be outlining one way in which the reformed epistemological stance can

Edinburgh, University of

131

Thermochemically recuperated and steam cooled gas turbine system  

DOE Patents [OSTI]

A gas turbine system in which the expanded gas from the turbine section is used to generate the steam in a heat recovery steam generator and to heat a mixture of gaseous hydrocarbon fuel and the steam in a reformer. The reformer converts the hydrocarbon gas to hydrogen and carbon monoxide for combustion in a combustor. A portion of the steam from the heat recovery steam generator is used to cool components, such as the stationary vanes, in the turbine section, thereby superheating the steam. The superheated steam is mixed into the hydrocarbon gas upstream of the reformer, thereby eliminating the need to raise the temperature of the expanded gas discharged from the turbine section in order to achieve effective conversion of the hydrocarbon gas.

Viscovich, Paul W. (Longwood, FL); Bannister, Ronald L. (Winter Springs, FL)

1995-01-01T23:59:59.000Z

132

Thermochemically recuperated and steam cooled gas turbine system  

DOE Patents [OSTI]

A gas turbine system is described in which the expanded gas from the turbine section is used to generate the steam in a heat recovery steam generator and to heat a mixture of gaseous hydrocarbon fuel and the steam in a reformer. The reformer converts the hydrocarbon gas to hydrogen and carbon monoxide for combustion in a combustor. A portion of the steam from the heat recovery steam generator is used to cool components, such as the stationary vanes, in the turbine section, thereby superheating the steam. The superheated steam is mixed into the hydrocarbon gas upstream of the reformer, thereby eliminating the need to raise the temperature of the expanded gas discharged from the turbine section in order to achieve effective conversion of the hydrocarbon gas. 4 figs.

Viscovich, P.W.; Bannister, R.L.

1995-07-11T23:59:59.000Z

133

Steam Quality  

E-Print Network [OSTI]

"STEAM QUALITY has been generally defined as the amount of moisture/vapor (or lack thereof) contained within steam produced from some form of boiler. It has long been used as the standard term for the measurement of ""wet or dry"" steam and as a...

Johnston, W.

134

Superheated steam power plant with steam to steam reheater. [LMFBR  

SciTech Connect (OSTI)

A desuperheater is disposed in a steam supply line supplying superheated steam to a shell and tube reheater.

Silvestri, G.J.

1981-06-23T23:59:59.000Z

135

Applications of solar reforming technology  

SciTech Connect (OSTI)

Research in recent years has demonstrated the efficient use of solar thermal energy for driving endothermic chemical reforming reactions in which hydrocarbons are reacted to form synthesis gas (syngas). Closed-loop reforming/methanation systems can be used for storage and transport of process heat and for short-term storage for peaking power generation. Open-loop systems can be used for direct fuel production; for production of syngas feedstock for further processing to specialty chemicals and plastics and bulk ammonia, hydrogen, and liquid fuels; and directly for industrial processes such as iron ore reduction. In addition, reforming of organic chemical wastes and hazardous materials can be accomplished using the high-efficiency destruction capabilities of steam reforming. To help identify the most promising areas for future development of this technology, we discuss in this paper the economics and market potential of these applications.

Spiewak, I. [Weizmann Inst. of Science, Rehovoth (Israel); Tyner, C.E. [Sandia National Labs., Albuquerque, NM (United States); Langnickel, U. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Koeln (Germany)

1993-11-01T23:59:59.000Z

136

Thomas Reddinger Director, Steam  

E-Print Network [OSTI]

Thomas Reddinger Director, Steam Operations Steven Richards Assistant Manager of Maintenance (Distribution) Deborah Moorhead Office Coordinator III Martin Bower Steam Plant Operator Richard Redfield Steam Plant Operator Bohdan Sawa Steam Plant Operator Robert Tedesco Steam Plant Operator James Bradley

Raina, Ramesh

137

Thomas Reddinger Director, Steam  

E-Print Network [OSTI]

Thomas Reddinger Director, Steam Operations Steven Richards Assistant Manager of Maintenance Bourdon Steam Plant Operator Vincent Massara Steam Plant Operator Cliff Lescenski Steam Plant Operator Robert Tedesco Steam Plant Operator James Bradley Equipment Maintenance Robert Earle Equipment

Mather, Patrick T.

138

Improve syngas production using autothermal reforming  

SciTech Connect (OSTI)

Synthesis gas or syngas, i.e., mixtures of CO and H[sub 2], is a major route from hydrocarbons to many important bulk chemicals ranging from acetic acid to ammonia. Syngas conversion uses hydrocarbon feedstocks, steam, O[sub 2] and CO[sub 2], either separately or in combinations. Autothermal reforming (ATR) is a low-investment process using a simple reactor design. The process is soot-free due to burner design and fixed-bed catalyst. Developed in the late '50s, ATR's main application was for ammonia and methanol syntheses. In ammonia plants, hydrogen production was maximized by operating at high H[sub 2]O/C ratios ranging from 2.5 to 3.5 mole/mole. In methanol units, CO[sub 2] recycle adjusted the syngas composition. ATR is also used to co-produce CO and H[sub 2] as separate streams at H[sub 2]O/C ratios of 1.4 to 2.0 mole/mole. recent developments and optimizations allow cost-effective operation at very low H[sub 2]O/C feed ratios to produce CO-rich syngas. The paper describes the process, including feedstocks and reactor design, the chemical reactions, development and improvements to the process, test results, soot formation, burner design, burner testing, applications, thermodynamic calculations, industrial application, noncatalytic and catalytic partial oxidation, and future uses.

Christensen, T.S.; Primdahl, I.I. (Haldor Topsoe, Copenhagen (Denmark))

1994-03-01T23:59:59.000Z

139

Steam Pricing  

E-Print Network [OSTI]

as useable horsepower for pumps, compressors, etc. The turbines can be topping turbines which admit steam at a high pressure and exhaust it at a lower pressure, but a pressure which is still high enough to be used as a source of heat. Or, the turbines... can be condensing turbines which exhaust the steam at a pressure too low for the remaining heat to be useable. In this case the exhaust steam is normally condensed using cooling water, and the condensate is returned to the boiler house. Our plant...

Jones, K. C.

140

*sja@iet.aau.dkwww.iet.aau.dk Initial experiments with a Pt based heat exchanger methanol reformer for a HTPEM fuel cell system  

E-Print Network [OSTI]

of the fuel water/methanol mixture is done by electrical heaters, but could be integrated with the burner side reformed hydro- carbon as fuel for fuel cells can redu- ce fuel storage volume considerably. The PBI of evaporated water and methanol is presented and steam-reformed to a hydrogen rich gas. The steam reforming

Andreasen, Søren Juhl

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

CRUCIBLE TESTING OF TANK 48H RADIOACTIVEWASTE SAMPLE USING FLUIDIZED BED STEAMREFORMING TECHNOLOGY FOR ORGANICDESTRUCTION  

SciTech Connect (OSTI)

The purpose of crucible scale testing with actual radioactive Tank 48H material was to duplicate the test results that had been previously performed on simulant Tank 48H material. The earlier crucible scale testing using simulants was successful in demonstrating that bench scale crucible tests produce results that are indicative of actual Fluidized Bed Steam Reforming (FBSR) pilot scale tests. Thus, comparison of the results using radioactive Tank 48H feed to those reported earlier with simulants would then provide proof that the radioactive tank waste behaves in a similar manner to the simulant. Demonstration of similar behavior for the actual radioactive Tank 48H slurry to the simulant is important as a preliminary or preparation step for the more complex bench-scale steam reformer unit that is planned for radioactive application in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF) later in 2008. The goals of this crucible-scale testing were to show 99% destruction of tetraphenylborate and to demonstrate that the final solid product produced is sodium carbonate. Testing protocol was repeated using the specifications of earlier simulant crucible scale testing, that is sealed high purity alumina crucibles containing a pre-carbonated and evaporated Tank 48H material. Sealing of the crucibles was accomplished by using an inorganic 'nepheline' sealant. The sealed crucibles were heat-treated at 650 C under constant argon flow to inert the system. Final product REDOX measurements were performed to establish the REDuction/OXidation (REDOX) state of known amounts of added iron species in the final product. These REDOX measurements confirm the processing conditions (pyrolysis occurring at low oxygen fugacity) of the sealed crucible environment which is the environment actually achieved in the fluidized bed steam reformer process. Solid product dissolution in water was used to measure soluble cations and anions, and to investigate insoluble fractions of the product solids. Radioanalytical measurements were performed on the Tank 48H feed material and on the dissolved products in order to estimate retention of Cs-137 in the process. All aspects of prior crucible scale testing with simulant Tank 48H slurry were demonstrated to be repeatable with the actual radioactive feed. Tetraphenylborate destruction was shown to be >99% and the final solid product is sodium carbonate crystalline material. Less than 10 wt% of the final solid products are insoluble components comprised of Fe/Ni/Cr/Mn containing sludge components and Ti from monosodium titanate present in Tank 48H. REDOX measurements on the radioactive solid products indicate a reducing atmosphere with extremely low oxygen fugacity--evidence that the sealed crucible tests performed in the presence of a reductant (sugar) under constant argon purge were successful in duplicating the pyrolysis reactions occurring with the Tank 48H feed. Soluble anion measurements confirm that using sugar as reductant at 1X stoichiometry was successful in destroying nitrate/nitrite in the Tank 48H feed. Radioanalytical measurements indicate that {approx}75% of the starting Cs-137 is retained in the solid product. No attempts were made to analyze/measure other potential Cs-137 in the process, i.e., as possible volatile components on the inner surface of the alumina crucible/lid or as offgas escaping the sealed crucible. The collective results from these crucible scale tests on radioactive material are in good agreement with simulant testing. Crucible scale processing has been shown to duplicate the complex reactions of an actual fluidized bed steam reformer. Thus this current testing should provide a high degree of confidence that upcoming bench-scale steam reforming with radioactive Tank 48H slurry will be successful in tetraphenylborate destruction and production of sodium carbonate product.

Crawford, C

2008-07-31T23:59:59.000Z

142

Method for improving catalyst function in auto-thermal and partial oxidation reformer-based processors  

DOE Patents [OSTI]

The invention provides a method for reforming fuel, the method comprising contacting the fuel to an oxidation catalyst so as to partially oxidize the fuel and generate heat; warming incoming fuel with the heat while simultaneously warming a reforming catalyst with the heat; and reacting the partially oxidized fuel with steam using the reforming catalyst.

Ahmed, Shabbir; Papadias, Dionissios D.; Lee, Sheldon H.D.; Ahluwalia, Rajesh K.

2014-08-26T23:59:59.000Z

143

2007 DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Meeting  

E-Print Network [OSTI]

Biogas reformation Shift reactorShift reactor Selective oxidation of COSelective oxidation of CO Fuel cellFuel cell2007 DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Meeting Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts Hua Song Lingzhi Zhang Umit S

144

Steam Turbine Cogeneration  

E-Print Network [OSTI]

Steam turbines are widely used in most industrial facilities because steam is readily available and steam turbine is easy to operate and maintain. If designed properly, a steam turbine co-generation (producing heat and power simultaneously) system...

Quach, K.; Robb, A. G.

2008-01-01T23:59:59.000Z

145

Heat exchanger for fuel cell power plant reformer  

DOE Patents [OSTI]

A heat exchanger uses the heat from processed fuel gas from a reformer for a fuel cell to superheat steam, to preheat raw fuel prior to entering the reformer and to heat a water-steam coolant mixture from the fuel cells. The processed fuel gas temperature is thus lowered to a level useful in the fuel cell reaction. The four temperature adjustments are accomplished in a single heat exchanger with only three heat transfer cores. The heat exchanger is preheated by circulating coolant and purge steam from the power section during startup of the latter.

Misage, Robert (Manchester, CT); Scheffler, Glenn W. (Tolland, CT); Setzer, Herbert J. (Ellington, CT); Margiott, Paul R. (Manchester, CT); Parenti, Jr., Edmund K. (Manchester, CT)

1988-01-01T23:59:59.000Z

146

Steam in Distribution and Use: Steam Quality Redefined  

E-Print Network [OSTI]

"Steam quality is an important measurement in steam generation. It's a measurement of steam to moisture ratio. In use, steam quality takes on a different meaning - steam which maximizes energy transfer. To do this, the steam must be clean, dry...

Deacon, W.

147

Steam in Distribution and Use: Steam Quality Redefined  

E-Print Network [OSTI]

Steam quality is an important measurement in steam generation. It's a measurement of steam to moisture ratio. In use, steam quality takes on a different meaning- steam which maximizes energy transfer. To do this, the steam must be clean, dry...

Deacon, W. T.

148

Steam Path Audits on Industrial Steam Turbines  

E-Print Network [OSTI]

steam Path Audits on Industrial steam Turbines DOUGLAS R. MITCHELL. ENGINEER. ENCOTECH, INC., SCHENECTADY, NEW YORK ABSTRACT The electric utility industry has benefitted from steam path audits on steam turbines for several years. Benefits... not extend the turbine outage. To assure that all of the turbine audit data are available, the audit engineer must be at the turbine site the day the steam path is first exposed. A report of the opening audit findings is generated to describe the as...

Mitchell, D. R.

149

Method of removing cesium from steam  

DOE Patents [OSTI]

Method for removal of radioactive cesium from a hot vapor, such as high temperature steam, including the steps of passing input hot vapor containing radioactive cesium into a bed of silicate glass particles and chemically incorporating radioactive cesium in the silicate glass particles at a temperature of at least about 700.degree. F.

Carson, Jr., Neill J. (Clarendon Hills, IL); Noland, Robert A. (Oak Park, IL); Ruther, Westly E. (Skokie, IL)

1991-01-01T23:59:59.000Z

150

Advanced Fluidized Bed Waste Heat Recovery Systems  

E-Print Network [OSTI]

and produce steam. In a one-year evaluation test on an aluminum remelt furnace, the FBWHRS generated about 26 million lb of saturated steam at 150 psig. Before entering the FBWHRS, the flue gases were diluted to IIOO?F to protect the fluidized bed... an improved foulant cleaning system for the fluidized bed di~tributor plate and operating the total system on an aluminum remelt furnace which has a corrosive and fouling flue gas stream (3). Although this project focused on an aluminum remelt furnace...

Peterson, G. R.

151

Thomas Reddinger Director, Steam  

E-Print Network [OSTI]

Thomas Reddinger Director, Steam Operations Steven Richards Assistant Manager of Maintenance Supervisor (Distribution) Deborah Moorhead Office Coordinator III Martin Bower Steam Plant Operator Richard Redfield Steam Plant Operator SU Steam Station/Chilled Water Plant Bohdan Sawa Steam Plant Operator Robert

McConnell, Terry

152

Reforming of Liquid Hydrocarbons in a Novel Hydrogen-Selective Membrane-Based Fuel Processor  

SciTech Connect (OSTI)

In this work, asymmetric dense Pd/porous stainless steel composite membranes were fabricated by depositing palladium on the outer surface of the tubular support. The electroless plating method combined with an osmotic pressure field was used to deposit the palladium film. Surface morphology and microstructure of the composite membranes were characterized by SEM and EDX. The SEM and EDX analyses revealed strong adhesion of the plated pure palladium film on the substrate and dense coalescence of the Pd film. Membranes were further characterized by conducting permeability experiments with pure hydrogen, nitrogen, and helium gases at temperatures from 325 to 450 C and transmembrane pressure differences from 5 to 45 psi. The permeation results showed that the fabricated membranes have both high hydrogen permeability and selectivity. For example, the hydrogen permeability for a composite membrane with a 20 {micro}m Pd film was 3.02 x 10{sup -5} moles/m{sup 2}.s.Pa{sup 0.765} at 450 C. Hydrogen/nitrogen selectivity for this composite membrane was 1000 at 450 C with a transmembrane pressure difference of 14.7 psi. Steam reforming of methane is one of the most important chemical processes in hydrogen and syngas production. To investigate the usefulness of palladium-based composite membranes in membrane-reactor configuration for simultaneous production and separation of hydrogen, steam reforming of methane by equilibrium shift was studied. The steam reforming of methane using a packed-bed inert membrane tubular reactor (PBIMTR) was simulated. A two-dimensional pseudo-homogeneous reactor model with parallel flow configuration was developed for steam reforming of methane. The shell volume was taken as the feed and sweep gas was fed to the inside of the membrane tube. Radial diffusion was taken into account for concentration gradient in the radial direction due to hydrogen permeation through the membrane. With appropriate reaction rate expressions, a set of partial differential equations was derived using the continuity equation for the reaction system and then solved by finite difference method with appropriate boundary and initial conditions. An iterative scheme was used to obtain a converged solution. Membrane reactor performance was compared to that in a traditional non-membrane packed-bed reactor (PBR). Their performances were also compared with thermodynamic equilibrium values achievable in a conventional non-membrane reactor. Numerical results of the models show that the methane conversions in the PBIMTR are always higher than that in the PBR, as well as thermodynamic equilibrium conversions. For instance, at a reaction pressure of 6 atm, a temperature of 650 C, a space velocity of 900/16.0 SCCM/gm{sub cat}, a steam to methane molar feed ratio of 3.0, a sweep ratio of 0.15, the conversion in the membrane reactor is about 86.5%, while the conversion in the non-membrane reactor is about 50.8%. The corresponding equilibrium conversion is about 56.4%. The effects on the degree of conversion and hydrogen yield were analyzed for different parameters such as temperature, reactor pressure, feed and sweep flow rate, feed molar ratio, and space time. From the analysis of the model results, it is obvious that the membrane reactor operation can be optimized for conversion or yield through the choice of proper operating and design parameters. Comparisons with available literature data for both membrane and non-membrane reactors showed a good agreement.

Shamsuddin Ilias

2006-03-10T23:59:59.000Z

153

Fluid Bed Combustion Applied to Industrial Waste  

E-Print Network [OSTI]

of its relatively recent application to coal fired steam production, fluid beds have been uti lized in industry for over 60 years. Beginning in Germany in the twenties for coal gasification, the technology was applied to catalytic cracking of heavy... system cost), use of minimum excess air required, and maintaining the min"imum reactor temperature neces sary to sustain combustion. For superautogenous fuels, where incineration. only is desired, minimum capital cost is achieved by using direct bed...

Mullen, J. F.; Sneyd, R. J.

154

Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation  

E-Print Network [OSTI]

size gasification for syngas, substitute natural gas, andfor Biomass-Derived Syngas. NREL/ TP-510-34929. Golden, CO:either converted into syngas in the Steam Methane Reformer (

Lu, Xiaoming

2012-01-01T23:59:59.000Z

155

Steam System Optimization  

E-Print Network [OSTI]

flanges, control valves, steam turbines, manways, sections of piping, heads on vessels, etc. are uninsulated. If steam is in demand at the steam pressure level of the uninsulated piping and equipment, then the piping and equipment should be insulated... been developed, it is an excellent tool to identify the steam sources. Areas to first look for possible waste are steam turbines and steam let down stations. 161 ESL-IE-98-04-26 Proceedings from the Twentieth National Industrial Energy Technology...

Aegerter, R. A.

156

Steam and Condensate Systems  

E-Print Network [OSTI]

efficiency and profit. Some important factors to consider in steam and condensate systems are: 1) Proper steam pressure 2) Adequate sized steam lines 3) Adequate sized condensate return lines 4) Utilization of flash steam 5) Properly sized... ! can cause system inefficiency. i Adequate sized steam lines assure the process will be furnished with sufficiertt i quantities of steam at the proper pressure. Adequate sized condensate return lines are essential to overall efficiency. lhese...

Yates, W.

1979-01-01T23:59:59.000Z

157

SteamMaster: Steam System Analysis Software  

E-Print Network [OSTI]

STEAMMASTER: STEAM SYSTEM ANALYSIS SOFTW ARE Greg Wheeler Associate Professor Oregon State University Corvallis, OR 9733 I ABSTRACT As director of Oregon's ]ndustrial Assessment Center, [ have encountered many industrial steam systems during... plant visits. We analyze steam systems and make recommendations to improve system efficiency. [n nearly 400 industrial assessments, we have recommended 210 steam system improvements, excluding heat recovery, that would save $1.5 million/year with a...

Wheeler, G.

158

Verification of the Accountability Method as a Means to Classify Radioactive Wastes Processed Using THOR Fluidized Bed Steam Reforming at the Studsvik Processing Facility in Erwin, Tennessee, USA - 13087  

SciTech Connect (OSTI)

Studsviks' Processing Facility Erwin (SPFE) has been treating Low-Level Radioactive Waste using its patented THOR process for over 13 years. Studsvik has been mixing and processing wastes of the same waste classification but different chemical and isotopic characteristics for the full extent of this period as a general matter of operations. Studsvik utilizes the accountability method to track the movement of radionuclides from acceptance of waste, through processing, and finally in the classification of waste for disposal. Recently the NRC has proposed to revise the 1995 Branch Technical Position on Concentration Averaging and Encapsulation (1995 BTP on CA) with additional clarification (draft BTP on CA). The draft BTP on CA has paved the way for large scale blending of higher activity and lower activity waste to produce a single waste for the purpose of classification. With the onset of blending in the waste treatment industry, there is concern from the public and state regulators as to the robustness of the accountability method and the ability of processors to prevent the inclusion of hot spots in waste. To address these concerns and verify the accountability method as applied by the SPFE, as well as the SPFE's ability to control waste package classification, testing of actual waste packages was performed. Testing consisted of a comprehensive dose rate survey of a container of processed waste. Separately, the waste package was modeled chemically and radiologically. Comparing the observed and theoretical data demonstrated that actual dose rates were lower than, but consistent with, modeled dose rates. Moreover, the distribution of radioactivity confirms that the SPFE can produce a radiologically homogeneous waste form. The results of the study demonstrate: 1) the accountability method as applied by the SPFE is valid and produces expected results; 2) the SPFE can produce a radiologically homogeneous waste; and 3) the SPFE can effectively control the waste package classification. (authors)

Olander, Jonathan [Studsvik Processing Facility Erwin, 151 T.C. Runnion Rd., Erwin, TN 37650 (United States)] [Studsvik Processing Facility Erwin, 151 T.C. Runnion Rd., Erwin, TN 37650 (United States); Myers, Corey [Studsvik, Inc., 5605 Glenridge Drive, Suite 705, Atlanta, GA 30342 (United States)] [Studsvik, Inc., 5605 Glenridge Drive, Suite 705, Atlanta, GA 30342 (United States)

2013-07-01T23:59:59.000Z

159

Development of a Sorption Enhanced Steam Hydrogasification Process for In-situ Carbon Dioxide (CO2) Removal and Enhanced Synthetic Fuel Production  

E-Print Network [OSTI]

J. Different types of gasifiers and their integration withCO 2 in a pressurized-gasifier-based process. Energ Fuel.fluidized bed biomass steam gasifier-bed material and fuel

Liu, Zhongzhe

2013-01-01T23:59:59.000Z

160

Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery  

SciTech Connect (OSTI)

MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and agglomeration problems of the conversion of Na{sub 2}CO{sub 3} to (high sodium) titanates during gasification of black liquor in the presence of (low sodium) titanates or TiO{sub 2} (Task 2). MTCI/ThermoChem tested the performance and operability of the combined technology of steam reforming and direct causticization in their Process Development Unit (PDU) (Task 3). The specific objectives were: (1) to investigate how split sulfidity and polysulfide (+ AQ) pulping can be used to increase pulp fiber yield and properties compared to conventional kraft pulping; (2) to determine the economics of black liquor gasification combined with these pulping technologies in comparison with conventional kraft pulping and black liquor recovery; (3) to determine the effect of operating conditions on the kinetics of the titanate-based direct causticization reaction during black liquor gasification at relatively low temperatures ({le} 750 C); (4) to determine the mechanism of particle agglomeration during gasification of black liquor in the presence of titanates at relatively low temperatures ({le} 750 C); and (5) to verify performance and operability of the combined technology of steam reforming and direct causticization of black liquor in a pilot scale fluidized bed test facility.

Adriaan van Heiningen

2007-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Steam Oxidation of Advanced Steam Turbine Alloys  

SciTech Connect (OSTI)

Power generation from coal using ultra supercritical steam results in improved fuel efficiency and decreased greenhouse gas emissions. Results of ongoing research into the oxidation of candidate nickel-base alloys for ultra supercritical steam turbines are presented. Exposure conditions range from moist air at atmospheric pressure (650°C to 800°C) to steam at 34.5 MPa (650°C to 760°C). Parabolic scale growth coupled with internal oxidation and reactive evaporation of chromia are the primary corrosion mechanisms.

Holcomb, Gordon R.

2008-01-01T23:59:59.000Z

162

Bed Bugs  

E-Print Network [OSTI]

Bed Bugs L-1742 9-01 Roger Gold and Harry Howell* B ed bugs, generally called ?chinces? in Texas, feed on blood, principally that of humans, by piercing the skin with their elongated beaks. Although they inflict misery on their victims, it has never...

Gold, Roger E.; Howell Jr., Harry N.

2001-11-15T23:59:59.000Z

163

Steam atmosphere drying exhaust steam recompression system  

DOE Patents [OSTI]

This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculates through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried. The dryer comprises a vessel which enables the feedstock and steam to enter and recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard. 17 figures.

Becker, F.E.; Smolensky, L.A.; Doyle, E.F.; DiBella, F.A.

1994-03-08T23:59:59.000Z

164

Steam atmosphere drying exhaust steam recompression system  

DOE Patents [OSTI]

This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculated through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried The dryer comprises a vessel which enables the feedstock and steam to enter recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard.

Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Doyle, Edward F. (Dedham, MA); DiBella, Francis A. (Roslindale, MA)

1994-01-01T23:59:59.000Z

165

Downhole steam quality measurement  

DOE Patents [OSTI]

The present invention relates to an empirical electrical method for remote sensing of steam quality utilizing flow-through grids which allow measurement of the electrical properties of a flowing two-phase mixture. The measurement of steam quality in the oil field is important to the efficient application of steam assisted recovery of oil. Because of the increased energy content in higher quality steam it is important to maintain the highest possible steam quality at the injection sandface. The effectiveness of a steaming operation without a measure of steam quality downhole close to the point of injection would be difficult to determine. Therefore, a need exists for the remote sensing of steam quality.

Lee, D.O.; Montoya, P.C.; Muir, J.F.; Wayland, J.R. Jr.

1985-06-19T23:59:59.000Z

166

Steam Digest 2001  

SciTech Connect (OSTI)

Steam Digest 2001 chronicles BestPractices Program's contributions to the industrial trade press for 2001, and presents articles that cover technical, financial and managerial aspects of steam optimization.

Not Available

2002-01-01T23:59:59.000Z

167

Steam and Condensate Systems  

E-Print Network [OSTI]

.00 or more. Many see costs of $6.00/$7.00 in the near future. These tremendous increases have caused steam systems, steam traps and condensate systems to become a major factor in overall plant efficiency and profit....

Yates, W.

1980-01-01T23:59:59.000Z

168

Waste Steam Recovery  

E-Print Network [OSTI]

applicable to other sources of steam. The interaction of the recovery system with the plant's steam/power system has been included. Typical operating economics have been prepared. It was found that the profitability of most recovery schemes is generally...

Kleinfeld, J. M.

1979-01-01T23:59:59.000Z

169

Flash Steam Recovery Project  

E-Print Network [OSTI]

organic compounds, was targeted for improvement. This unit uses a portion of the high-pressure steam available from the plant's cogeneration facility. Continuous expansions within the unit had exceeded the optimum design capacity of the unit's steam...

Bronhold, C. J.

170

Downhole steam quality measurement  

DOE Patents [OSTI]

An empirical method for the remote sensing of steam quality that can be easily adapted to downhole steam quality measurements by measuring the electrical properties of two-phase flow across electrode grids at low frequencies.

Lee, David O. (Albuquerque, NM); Montoya, Paul C. (Albuquerque, NM); Muir, James F. (Albuquerque, NM); Wayland, Jr., J. Robert (Albuquerque, NM)

1987-01-01T23:59:59.000Z

171

HP Steam Trap Monitoring  

E-Print Network [OSTI]

STEAM MONITORING HP Steam Trap Monitoring HP Steam Trap Monitoring ? 12-18 months payback! ? 3-5% permanent reduction in consumption ? LEED Pt.? Innovation in Operations EB O&M ? Saved clients over $1,000,000 Annual consumption... Steam Trap Monitoring ? Real-time monitoring for high-pressure critical traps (>15 PSIG) ? Average total system cost $25K - $50K ? Web-Based or Modbus/BMS Integration Basic Installation Wireless Signal Transmitter Receiver Repeater...

Pascone, S.

2011-01-01T23:59:59.000Z

172

Steam trap monitor  

DOE Patents [OSTI]

A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (a hot finger) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellow in providing an indication of total energy (steam + condensate) of the system. Processing means coupled to and responsive to outputs from the hot and cold fingers subtracts the former from the latter to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning. 2 figs.

Ryan, M.J.

1987-05-04T23:59:59.000Z

173

Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air or Liquid Heat Integration  

E-Print Network [OSTI]

Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air PEM fuel cell systems fuelled by steam reformed methanol. Various fuel cell system solutions exist, they mainly differ depending on the desired fuel used. High temperature PEM (HTPEM) fuel cells offer

Berning, Torsten

174

Geothermal steam quality testing  

SciTech Connect (OSTI)

Geothermal steam quality and purity have a significant effect on the operational efficiency and life of geothermal steam turbines and accessory equipment. Poor steam processing can result in scaled nozzles/blades, erosion, corrosion, reduced utilization efficiency, and early fatigue failures accelerated by stress corrosion cracking (SCC). Upsets formed by undetected slugs of liquid entering the turbine can cause catastrophic failure. The accurate monitoring and determination of geothermal steam quality/purity is intrinsically complex which often results in substantial errors. This paper will review steam quality and purity relationships, address some of the errors, complexities, calibration and focus on: thermodynamic techniques for evaluating and monitoring steam quality by use of the modified throttling calorimeters.

Jung, D.B. [Two-Phase Engineering & Research, Inc., Santa Rosa, CA (United States)

1995-12-31T23:59:59.000Z

175

Improving steam turbine efficiency  

SciTech Connect (OSTI)

This paper describes the condition of a significant number of fossil steam turbines operating in the United States and the maintenance practices used to improve their performance. Through the use of steam path audits conducted by the authors` company and by several utilities, a large data base of information on turbine heat rate, casing efficiency, and maintenance practices is available to help the power generation industry understand how different maintenance practices and steam path damage impact turbine performance. The data base reveals that turbine cycle heat rate is typically 5.23% poorer than design just prior to major outages. The degraded condition of steam turbines presents an opportunity for utilities to improve heat rate and reduce emissions without increasing fuel costs. The paper describes what losses typically contribute to the 5.23% heat rate degradation and how utilities can recover steam turbine performance through maintenance actions aimed at improving steam path efficiency.

Cioffi, D.H.; Mitchell, D.R.; Whitecar, S.C. [Encotech, Inc., Schenectady, NY (United States)

1995-06-01T23:59:59.000Z

176

Steam generator support system  

DOE Patents [OSTI]

A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source is disclosed. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances. 4 figs.

Moldenhauer, J.E.

1987-08-25T23:59:59.000Z

177

Steam generator support system  

DOE Patents [OSTI]

A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances.

Moldenhauer, James E. (Simi Valley, CA)

1987-01-01T23:59:59.000Z

178

Circulating Fluid Bed Combustor  

E-Print Network [OSTI]

The circulating bed combustor represents an alternative concept of burning coal in fluid bed technology, which offers distinct advantages over both the current conventional fluidized bed combustion system and the pulverized coal boilers equipped...

Fraley, L. D.; Do, L. N.; Hsiao, K. H.

1982-01-01T23:59:59.000Z

179

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the eighth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2004-September 30, 2005 and includes an entire review of the progress for year 2 of the project. This year saw progress in eight areas. These areas are: (1) steam reformer transient response, (2) steam reformer catalyst degradation, (3) steam reformer degradation tests using bluff bodies, (4) optimization of bluff bodies for steam reformation, (5) heat transfer enhancement, (6) autothermal reforming of coal derived methanol, (7) autothermal catalyst degradation, and (8) autothermal reformation with bluff bodies. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

Paul A. Erickson

2005-09-30T23:59:59.000Z

180

Predicting Steam Turbine Performance  

E-Print Network [OSTI]

," PREDICTING STEAM TURBINE PERFORMANCE James T. Harriz, EIT Waterland, Viar & Associates, Inc. Wilmington, Delaware ABSTRACT Tracking the performance of extraction, back pressure and condensing steam turbines is a crucial part... energy) and test data are presented. Techniques for deriving efficiency curves from each source are described. These techniques can be applied directly to any steam turbine reliability study effort. INTRODUCTION As the cost of energy resources...

Harriz, J. T.

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Steam System Optimization  

E-Print Network [OSTI]

is being let down. Some projects are independent of the steam balance, such as eliminating high-pressure (HP) steam leaks, insulating HP steam piping, optimizing the boiler operation, and improving the performance of condensing turbines.... If dirty fuels are used, then soot blowing should be frequently performed and the economizers cleaned on a more frequent schedule. For sites with condensing turbines, the turbine blades and the surface condensers must remain clean to maintain...

Aegerter, R.

2004-01-01T23:59:59.000Z

182

Steam System Data Management  

E-Print Network [OSTI]

Steam System Data Management What Does It Include Safety In Motion Wal?Tech?Valve,?Inc. 251?438?2203 The Real Genius Behind Technology Is People ESL-IE-13-05-35 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New... ? Fabrication Training (Six Year Training) ? Welding Certifications ?Retired From Chevron After 25 Years ? Established A Steam System Program ? Planner For Routine Maintenance Work ? Planner For Steam System Improvements ? Wal-Tech Valve, Inc. ? Purchased...

Roberts, D.

2013-01-01T23:59:59.000Z

183

Downhole steam injector  

DOE Patents [OSTI]

An improved downhole steam injector has an angled water orifice to swirl the water through the device for improved heat transfer before it is converted to steam. The injector also has a sloped diameter reduction in the steam chamber to throw water that collects along the side of the chamber during slant drilling into the flame for conversion to steam. In addition, the output of the flame chamber is beveled to reduce hot spots and increase efficiency, and the fuel-oxidant inputs are arranged to minimize coking.

Donaldson, A. Burl (Albuquerque, NM); Hoke, Donald E. (Albuquerque, NM)

1983-01-01T23:59:59.000Z

184

catalyst beds | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

catalyst beds catalyst beds Leads No leads are available at this time. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. Abstract: As a candidate...

185

Reduction on synthesis gas costs by decrease of steam/carbon and oxygen/carbon ratios in the feedstock  

SciTech Connect (OSTI)

The costs for syngas production at low steam/carbon and oxygen/carbon ratios have been analyzed for simplified process schemes of the main syngas production technologies (steam-CO{sub 2} reforming, autothermal reforming, and combined reforming) and different synthesis gas compositions. The broad analysis arises from experimental indication on the possibility of preventing carbon formation at low steam/carbon and oxygen/carbon ratios in the feedstock by choosing an appropriate catalyst or by introducing small amounts of sulfur compounds in the reactant feed. The analysis is limited to the synthesis gas production step and does not include its downstream processes. The results indicate that technologies at low steam/carbon and oxygen/carbon ratios would have a significant positive impact on synthesis gas costs.

Basini, L.; Piovesan, L. [Snamprogetti S.p.A. Research Labs., Milano (Italy)] [Snamprogetti S.p.A. Research Labs., Milano (Italy)

1998-01-01T23:59:59.000Z

186

Catalytic autothermal reforming increases fuel cell flexibility  

SciTech Connect (OSTI)

To give a better understanding of autothermal reforming (ATR), a process which offers an advantageous alternative to steam reforming for H/sub 2/ production for fuel cells because of the wider range of fuels which can be converted, the conversion of individual fuel components was studied. Attempts have been made to characterize the chemical reactions of light and heavy paraffins and aromatics in ATR. Results of studies to determine the effects of operating parameters on the carbon-forming tendency of each hydrocarbon type are reported. The catalyst used for the ATR process was three-layers of supported nickel catalysts, Norton NC-100 spheres in the top zone, cylindrical G-56B tablets in the bottom one, and either ICI 46-I or ICI 46-4 Raschig rings in the middle zone. A summary of the experimental studies of the ATR of n-hexane, n-tetradecane, benzene, and benzene solutions of naphthalene is presented. (BLM)

Flytzani-Stephanopoulos, M.; Voecks, G.E.

1981-12-01T23:59:59.000Z

187

Options for Generating Steam Efficiently  

E-Print Network [OSTI]

This paper describes how plant engineers can efficiently generate steam when there are steam generators and Heat Recovery Steam Generators in their plant. The process consists of understanding the performance characteristics of the various equipment...

Ganapathy, V.

188

Cycle Configurations for a PBMR Steam and Electricity Production Plant  

SciTech Connect (OSTI)

The Pebble Bed Modular Reactor (PBMR) is an advanced helium-cooled, graphite moderated High Temperature Gas-cooled Reactor (HTGR) that is capable of multiple missions. The petrochemical industry requires the use of high temperature steam and electricity for their processes. Currently coal or natural gas is utilised for the generation of high temperature steam and electricity, which under-utilises natural resources and in the process emits CO{sub 2} into the atmosphere. This paper provides an overview of the PBMR product development path and discusses how steam production forms part of the future possibilities of the PBMR technology. Suitable cycle configurations for both process steam and electricity generation as required by petrochemical plants are discussed. (authors)

Matzner, Dieter; Kriel, Willem; Correia, Michael; Greyvenstein, Renee [PBMR - Pty - Ltd, Lake Buena Vista Building, 1267 Gordon Hood Avenue, Centurion, PO Box 9396, Centurion 0046 (South Africa)

2006-07-01T23:59:59.000Z

189

Steam Trap Management  

E-Print Network [OSTI]

A medium-sized plant of a high technology company is reaping the benefits of a Pro-active Steam Trap Program provided by Yarway's TECH/SERV Division. Initial work began March '84 and the most recent steam trap feasibility study conducted in March...

Murphy, J. J.; Hirtner, H. H.

190

A modeling software linking approach for the analysis of an integrated reforming combined cycle with hot potassium carbonate CO[subscript 2] capture  

E-Print Network [OSTI]

The focus of this study is the analysis of an integrated reforming combined cycle (IRCC) with natural gas as fuel input. This IRCC consisted of a hydrogen-fired gas turbine (GT) with a single-pressure steam bottoming cycle ...

Nord, Lars Olof

191

Description of emission control using fluidized-bed, heat-exchange technology  

SciTech Connect (OSTI)

Environmental effects of fluidized-bed, waste-heat recovery technology are identified. The report focuses on a particular configuration of fluidized-bed, heat-exchange technology for a hypothetical industrial application. The application is a lead smelter where a fluidized-bed, waste-heat boiler (FBWHB) is used to control environmental pollutants and to produce steam for process use. Basic thermodynamic and kinetic information for the major sulfur dioxide (SO/sub 2/) and NO/sub x/ removal processes is presented and their application to fluidized-bed, waste heat recovery technology is discussed. Particulate control in fluidized-bed heat exchangers is also discussed.

Vogel, G.J.; Grogan, P.J.

1980-06-01T23:59:59.000Z

192

Autothermal and partial oxidation reformer-based fuel processor, method for improving catalyst function in autothermal and partial oxidation reformer-based processors  

DOE Patents [OSTI]

The invention provides a fuel processor comprising a linear flow structure having an upstream portion and a downstream portion; a first catalyst supported at the upstream portion; and a second catalyst supported at the downstream portion, wherein the first catalyst is in fluid communication with the second catalyst. Also provided is a method for reforming fuel, the method comprising contacting the fuel to an oxidation catalyst so as to partially oxidize the fuel and generate heat; warming incoming fuel with the heat while simultaneously warming a reforming catalyst with the heat; and reacting the partially oxidized fuel with steam using the reforming catalyst.

Ahmed, Shabbir; Papadias, Dionissios D.; Lee, Sheldon H. D.; Ahluwalia, Rajesh K.

2013-01-08T23:59:59.000Z

193

Streams of Steam The Steam Boiler Specification Case Study  

E-Print Network [OSTI]

Streams of Steam ­ The Steam Boiler Specification Case Study Manfred Broy, Franz Regensburger-tuned con- cepts of FOCUS by its application of the requirements specification of a steam boiler, see [Abr96-studies. In this context, applying FOCUS to the steam boiler case study ([Abr96]) led us to a couple of questions re- #12

194

Ukraine Steam Partnership  

SciTech Connect (OSTI)

The Ukraine Steam Partnership program is designed to implement energy efficiency improvements in industrial steam systems. These improvements are to be made by the private plants and local government departments responsible for generation and delivery of energy to end-users. One of the activities planned under this program was to provide a two-day training workshop on industrial steam systems focusing on energy efficiency issues related to the generation, distribution, and consumption of steam. The workshop was geared towards plant managers, who are not only technically oriented, but are also key decision makers in their respective companies. The Agency for Rational Energy Use and Ecology (ARENA-ECO), a non-governmental, not-for-profit organization founded to promote energy efficiency and environmental protection in Ukraine, in conjunction with the Alliance staff in Kiev sent out invitations to potential participants in all the regions of Ukraine. The purpose of this report is the describe the proceedings from the workshop and provide recommendations from the workshop's roundtable discussion. The workshop was broken down into two main areas: (1) Energy efficient boiler house steam generation; and Energy efficient steam distribution and consumption. The workshop also covered the following topics: (1) Ukrainian boilers; (2) Water treatment systems; (3) A profile of UKRESCO (Ukrainian Energy Services Company); (4) Turbine expanders and electricity generation; (5) Enterprise energy audit basics; and (6) Experience of steam use in Donetsk oblast.

Gurvinder Singh

2000-02-15T23:59:59.000Z

195

Steam trap monitor  

DOE Patents [OSTI]

A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (the combination of a hot finger and thermocouple well) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellows in providing an indication of total energy (steam+condensate) of the system. Processing means coupled to and responsive to outputs from the thermocouple well hot and cold fingers subtracts the condensate energy as measured by the hot finger and thermocouple well from the total energy as measured by the cold finger to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning.

Ryan, Michael J. (Plainfield, IL)

1988-01-01T23:59:59.000Z

196

Nanocomposite catalysts for soot combustion and propane steam reforming  

E-Print Network [OSTI]

A nanocomposite system, CuO-Ag/CeO 2, has been successfully developed to complete carbon black combustion by 400*C. This novel catalyst has excellent potential for application in the emission control of soot particulates ...

He, Hong, Ph. D. Massachusetts Institute of Technology

2007-01-01T23:59:59.000Z

197

Comparative Investigation of Benzene Steam Reforming over Spinel Supported  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New SubstationCleanCommunity Involvement and Making

198

Steam generator tube failures  

SciTech Connect (OSTI)

A review and summary of the available information on steam generator tubing failures and the impact of these failures on plant safety is presented. The following topics are covered: pressurized water reactor (PWR), Canadian deuterium uranium (CANDU) reactor, and Russian water moderated, water cooled energy reactor (VVER) steam generator degradation, PWR steam generator tube ruptures, the thermal-hydraulic response of a PWR plant with a faulted steam generator, the risk significance of steam generator tube rupture accidents, tubing inspection requirements and fitness-for-service criteria in various countries, and defect detection reliability and sizing accuracy. A significant number of steam generator tubes are defective and are removed from service or repaired each year. This wide spread damage has been caused by many diverse degradation mechanisms, some of which are difficult to detect and predict. In addition, spontaneous tube ruptures have occurred at the rate of about one every 2 years over the last 20 years, and incipient tube ruptures (tube failures usually identified with leak detection monitors just before rupture) have been occurring at the rate of about one per year. These ruptures have caused complex plant transients which have not always been easy for the reactor operators to control. Our analysis shows that if more than 15 tubes rupture during a main steam line break, the system response could lead to core melting. Although spontaneous and induced steam generator tube ruptures are small contributors to the total core damage frequency calculated in probabilistic risk assessments, they are risk significant because the radionuclides are likely to bypass the reactor containment building. The frequency of steam generator tube ruptures can be significantly reduced through appropriate and timely inspections and repairs or removal from service.

MacDonald, P.E.; Shah, V.N.; Ward, L.W.; Ellison, P.G.

1996-04-01T23:59:59.000Z

199

Refurbishing steam turbines  

SciTech Connect (OSTI)

Power-plant operators are reducing maintenance costs of their aging steam turbines by using wire-arc spray coating and shot peening to prolong the service life of components, and by replacing outmoded bearings and seals with newer designs. Steam-turbine operators are pressed with the challenge of keeping their aging machines functioning in the face of wear problems that are exacerbated by the demand for higher efficiencies. These problems include intense thermal cycling during both start-up and shutdown, water particles in steam and solid particles in the air that pit smooth surfaces, and load changes that cause metal fatigue.

Valenti, M.

1997-12-01T23:59:59.000Z

200

Evaluating Steam Trap Performance  

E-Print Network [OSTI]

~LmT " TRIf' 1 TRIf' 2 Figure 2 It has become common practice for engineers to oversize steam traps and place more emphasis on first cost than on maintenance cost and operating 766 3 4 ESL-IE-86-06-126 Proceedings from the Eighth Annual Industrial...EVALUATING STEAM TRAP PERFORMANCE Noel Y Fuller, P.E. Holston Defense Corporation Kingsport, Tennessee ABSTRACT Laboratory tests were conducted on several types of steam traps at Holston Defense Corporation in Kingsport, Tennessee. Data...

Fuller, N. Y.

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Immigration reform and California agriculture  

E-Print Network [OSTI]

reform and California agriculture Philip Martin Professor,proposals for California agriculture. Immigration reformCenter. 196 CALIFORNIA AGRICULTURE • VOLUME 67 , NUMBER 4

Martin, Philip

2013-01-01T23:59:59.000Z

202

Materials Performance in USC Steam  

SciTech Connect (OSTI)

Materials Performance in USC Steam: (1) pressure effects on steam oxidation - unique capability coming on-line; (2) hydrogen evolution - hydrogen permeability apparatus to determine where hydrogen goes during steam oxidation; and (3) NETL materials development - steam oxidation resource for NETL developed materials.

G. R. Holcomb; J. Tylczak; G. H. Meier; N. M. Yanar

2011-09-07T23:59:59.000Z

203

Steam Champions in Manufacturing  

E-Print Network [OSTI]

into equivalent corporate rewards, such as increased profitability, reliability, workplace safety, and other benefits. The prerequisites for becoming a true steam champion will include engineering, business, and management skills....

Russell, C.

204

Advanced turbine systems program conceptual design and product development Task 8.3 - autothermal fuel reformer (ATR). Topical report  

SciTech Connect (OSTI)

Autothermal fuel reforming (ATR) consists of reacting a hydrocarbon fuel such as natural gas or diesel with steam to produce a hydrogen-rich {open_quotes}reformed{close_quotes} fuel. This work has been designed to investigate the fuel reformation and the product gas combustion under gas turbine conditions. The hydrogen-rich gas has a high flammability with a wide range of combustion stability. Being lighter and more reactive than methane, the hydrogen-rich gas mixes readily with air and can be burned at low fuel/air ratios producing inherently low emissions. The reformed fuel also has a low ignition temperature which makes low temperature catalytic combustion possible. ATR can be designed for use with a variety of alternative fuels including heavy crudes, biomass and coal-derived fuels. When the steam required for fuel reforming is raised by using energy from the gas turbine exhaust, cycle efficiency is improved because of the steam and fuel chemically recuperating. Reformation of natural gas or diesel fuels to a homogeneous hydrogen-rich fuel has been demonstrated. Performance tests on screening various reforming catalysts and operating conditions were conducted on a batch-tube reactor. Producing over 70 percent of hydrogen (on a dry basis) in the product stream was obtained using natural gas as a feedstock. Hydrogen concentration is seen to increase with temperature but less rapidly above 1300{degrees}F. The percent reforming increases as the steam to carbon ratio is increased. Two basic groups of reforming catalysts, nickel - and platinum-basis, have been tested for the reforming activity.

NONE

1996-11-01T23:59:59.000Z

205

Multi-fuel reformers for fuel cells used in transportation. Multi-fuel reformers: Phase 1 -- Final report  

SciTech Connect (OSTI)

DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

Not Available

1994-05-01T23:59:59.000Z

206

Producing Clean Syngas via Catalytic Reforming for Fuels Production  

SciTech Connect (OSTI)

Thermochemical biomass conversion to fuels and chemicals can be achieved through gasification to syngas. The biomass derived raw syngas contains the building blocks of carbon monoxide and hydrogen as well as impurities such as tars, light hydrocarbons, and hydrogen sulfide. These impurities must be removed prior to fuel synthesis. We used catalytic reforming to convert tars and hydrocarbons to additional syngas, which increases biomass carbon utilization. In this work, nickel based, fluidizable tar reforming catalysts were synthesized and evaluated for tar and methane reforming performance with oak and model syngas in two types of pilot scale fluidized reactors (recirculating and recirculating regenerating). Because hydrogen sulfide (present in raw syngas and added to model syngas) reacts with the active nickel surface, regeneration with steam and hydrogen was required. Pre and post catalyst characterization showed changes specific to the syngas type used. Results of this work will be discussed in the context of selecting the best process for pilot scale demonstration.

Magrini, K. A.; Parent, Y.; Jablonski, W.; Yung, M.

2012-01-01T23:59:59.000Z

207

Bed material agglomeration during fluidized bed combustion  

SciTech Connect (OSTI)

The purpose of this project is to determine the physical and chemical reactions which led to the undesired agglomeration of bed material during fluidized bed combustion and to relate these reactions to specific causes. Survey of industrial-scale fluidized bed combustors is being conducted to determine the occurrence of bed agglomeration and the circumstances under which agglomeration took place. This task should be finished by the end of February. Samples of bed material, agglomerate material, and boiler deposits are being requested from boiler operators as part of the survey. Once received, these sample will be analyzed to determine chemical and mineralogic composition. The bulk chemical determination will be performed using x-ray fluorescence and inductively coupled plasma-optical emission (ICP). Mineralogy will be detected by x-ray diffraction (XRD). Chemical and mineral reactions will be determined by scanning electron microscopy, optical microscopy, and electron microprobe.

Brown, R.C.; Dawson, M.R.; Noble, S.

1993-02-01T23:59:59.000Z

208

Steam System Tool Suite Introduction Guide  

E-Print Network [OSTI]

Steam System Tool Suite Introduction Guide Alternate Text Narratives and Graphic.............................................................................................................................6 Modules Steam System Scoping Tool (SSST)........................................................................................8 Steam System Assessment Tool (SSAT

Oak Ridge National Laboratory

209

Catalytic reforming methods  

DOE Patents [OSTI]

A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

Tadd, Andrew R; Schwank, Johannes

2013-05-14T23:59:59.000Z

210

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2006-04-01T23:59:59.000Z

211

DOE's BestPractices Steam End User Training Steam End User Training  

E-Print Network [OSTI]

DOE's BestPractices Steam End User Training Steam End User Training Steam Distribution Losses Module 1 June 29, 2010 Steam EndUser Training Steam Distribution System Losses Module Slide 1 pressure. #12;DOE's BestPractices Steam End User Training Steam End User Training Steam Distribution

Oak Ridge National Laboratory

212

Steam Basics: Use Available Data to Lower Steam System Cost  

E-Print Network [OSTI]

Industrial steam users recognize the need to reduce system cost in order to remain internationally competitive. Steam systems are a key utility that influence cost significantly, and represent a high value opportunity target. However, the quality...

Risko, J. R.

2011-01-01T23:59:59.000Z

213

NETL - Fuel Reforming Facilities  

ScienceCinema (OSTI)

Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

None

2014-06-27T23:59:59.000Z

214

NETL - Fuel Reforming Facilities  

SciTech Connect (OSTI)

Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

None

2013-06-12T23:59:59.000Z

215

Natural Gas Reforming | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Production Natural Gas Reforming Natural Gas Reforming Photo of Petroleum Refinery Natural gas reforming is an advanced and mature production process that builds upon...

216

Optical wet steam monitor  

DOE Patents [OSTI]

A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically. 4 figures.

Maxey, L.C.; Simpson, M.L.

1995-01-17T23:59:59.000Z

217

Steam Condensation Induced Waterhammer  

E-Print Network [OSTI]

,200 foot steam line to begin wanning it up. He'd been energizing the G-line for 3 weeks now at the end ofthe asbestos worker's shift and had never had the system warm up this quickly. It usually took from 30 to 45 minutes. When the handwheel spun... at Fort Wainwright, Alaska, the G and H Lines ran underground in narrow utilidors 2 filled with pipe. Originally, the contractor had tried to abate the steam main with the lines energized. This proved to be near impossible for the workers. Utilidor...

Kirsner, W.

218

Optical wet steam monitor  

DOE Patents [OSTI]

A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically.

Maxey, Lonnie C. (Powell, TN); Simpson, Marc L. (Knoxville, TN)

1995-01-01T23:59:59.000Z

219

Steam Power Partnership: Improving Steam System Efficiency Through Marketplace Partnerships  

E-Print Network [OSTI]

to support the steam efficiency program. Today, the Steam Team includes, the North American Insulation Manufacturers Association (NAIMA), the American Gas Association (AGA), the Council of Industrial Boiler Owners (ClBO), Armstrong International... pinch technology, and high performance steam. ? Armstrong International - Three worldwide factory seminar facilities, 13 North American sales representative facilities, 4 international sales representative facilities, 8 co-sponsored facilities, 2...

Jones, T.

220

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect (OSTI)

Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2004-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Liquid fuel reformer development: Autothermal reforming of Diesel fuel  

SciTech Connect (OSTI)

Argonne National Laboratory is developing a process to convert hydrocarbon fuels to clean hydrogen feeds for a polymer electrolyte fuel cell. The process incorporates an autothermal reforming catalyst that can process hydrocarbon feeds at lower temperatures than existing commercial catalysts. The authors have tested the catalyst with three diesel-type fuels: hexadecane, certified low-sulfur grade 1 diesel, and a standard grade 2 diesel. Hexadecane yielded products containing 60% hydrogen on a dry, nitrogen-free basis at 850 C, while maximum hydrogen product yields for the two diesel fuels were near 50%. Residual products in all cases included CO, CO{sub 2}, ethane, and methane. Further studies with grade 1 diesel showed improved conversion as the water:fuel ratio was increased from 1 to 2 at 850 C. Soot formation was reduced when the oxygen:carbon ratio was maintained at 1 at 850 C. There were no significant changes in hydrogen yield as the space velocity and the oxygen:fuel ratio were varied. Tests with a microchannel monolithic catalyst yielded similar or improved hydrogen levels at higher space velocities than with extruded pellets in a packed bed.

Pereira, C.; Bae, J-M.; Ahmed, S.; Krumpelt, M.

2000-07-24T23:59:59.000Z

222

Steam System Improvements at a Manufacturing Plant  

E-Print Network [OSTI]

BWX Technologies, Naval Nuclear Fuel Division (NNFD) is a manufacturing company with a steam system consisting of two Babcock & Wilcox boilers and approximately 350 steam traps. The steam system is used to produce and distribute steam for space...

Compher, J.; Morcom, B.

223

Laboratory Experiments and Hydrodynamic Modeling of a Bed Leveler Used to Level the Bottom of Ship Channels after Dredging  

E-Print Network [OSTI]

attached parallel to the trench ???? 4 5. Production cycle of a bed leveler ????????????????? 12 6. Elevation and plan view of dredge/tow tank in the Haynes Coastal Engineering Laboratory at Texas A&M University ?????????? 13 7... Page 18. Net used to prevent fine sand from leaving the tank when water is drained to reform sand bed after bed leveling ?????????????? 25 19. Dredge carriage at sediment pit in Texas A&M dredge/tow tank ??? 26 20. Control...

Paul, Ephraim Udo

2011-02-22T23:59:59.000Z

224

Steam generator tube rupture study  

E-Print Network [OSTI]

This report describes our investigation of steam generator behavior during a postulated tube rupture accident. Our study was performed using the steam generator, thermal-hydraulic analysis code THERMIT-UTSG. The purpose ...

Free, Scott Thomas

1986-01-01T23:59:59.000Z

225

Heat Recovery Steam Generator Simulation  

E-Print Network [OSTI]

The paper discusses the applications of Heat Recovery Steam Generator Simulation. Consultants, plant engineers and plant developers can evaluate the steam side performance of HRSGs and arrive at the optimum system which matches the needs...

Ganapathy, V.

226

Deaerators in Industrial Steam Systems  

SciTech Connect (OSTI)

This revised ITP tip sheet on deaerators in industrial steam systems provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-01-01T23:59:59.000Z

227

Reduction in Unit Steam Production  

E-Print Network [OSTI]

In 2001 the company's Arch-Brandenburg facility faced increased steam costs due to high natural gas prices and decreased production due to shutdown of a process. The facility was challenged to reduce unit steam consumption to minimize the effects...

Gombos, R.

2004-01-01T23:59:59.000Z

228

Belgrade Lot Steam Plant Lot  

E-Print Network [OSTI]

2 2A 2A Belgrade Lot Steam Plant Lot Alfond Lot Satellite Lot North Gym Lot Corbett Lot Dunn Lot Chadbourne Merrill Aubert Hannibal Hamlin Steam Plant Crosby Machine Tool Lab Children's Center Rogers N

Thomas, Andrew

229

Belgrade Lot Steam Plant Lot  

E-Print Network [OSTI]

2 2A 2A Belgrade Lot Steam Plant Lot Alfond Lot Satellite Lot North Gym Lot Corbett Lot Dunn Lot Hamlin Steam Plant Crosby Machine Tool Lab Children's Center Rogers N S Estabrooke Memorial Gym Stevens

Thomas, Andrew

230

Economics of Steam Pressure Reduction  

E-Print Network [OSTI]

Economics of Steam Pressure Reduction is a technical paper that addresses the operating and economic advantages associated with the program to lower the steam operating pressure. Evaluation of a testing program will be discussed. The paper...

Sylva, D. M.

231

Inspect and Repair Steam Traps  

SciTech Connect (OSTI)

This revised ITP tip sheet on inspecting and repairing steam traps provide how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-01-01T23:59:59.000Z

232

Belgrade Lot Steam Plant Lot  

E-Print Network [OSTI]

2 2A 2A Belgrade Lot Steam Plant Lot Alfond Lot Satellite Lot North Gym Lot Gym Lot Corbett Lot Greenhouse Patch Oceanographic Operations 1 2 8 5 3 4 7 6 AMC Chadbourne Merrill Aubert Hannibal Hamlin Steam

Thomas, Andrew

233

Belgrade Lot Steam Plant Lot  

E-Print Network [OSTI]

2 2A 2A Belgrade Lot Steam Plant Lot Alfond Lot Satellite Lot North Gym Lot Corbett Lot Dunn Lot Oceanographic Operations 1 2 8 5 3 4 7 6 AMC Chadbourne Merrill Aubert Hannibal Hamlin Steam Plant Crosby

Thomas, Andrew

234

Plasmatron Fuel Reformer Development and Internal Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications...

235

Pressurized fluidized-bed combustion technology exchange workshop  

SciTech Connect (OSTI)

The pressurized fluidized-bed combustion technology exchange workshop was held June 5 and 6, 1979, at The Meadowlands Hilton Hotel, Secaucus, New Jersey. Eleven papers have been entered individually into EDB and ERA. The papers include reviews of the US DOE and EPRI programs in this area and papers by Swedish, West German, British and American organizations. The British papers concern the joint program of the USA, UK and FRG at Leatherhead. The key factor in several papers is the use of fluidized bed combustors, gas turbines, and steam turbines in combined-cycle power plants. One paper examines several combined-cycle alternatives. (LTN)

,

1980-04-01T23:59:59.000Z

236

DOE's BestPractices Steam End User Training Steam End User Training  

E-Print Network [OSTI]

DOE's BestPractices Steam End User Training Steam End User Training Steam Generation Efficiency Module Efficiency Definition - 1 8/30/2010 Steam End-User Training Steam Generation Efficiency Module Efficiency Definition Section Slide 1 - Steam Generation Efficiency Module This module will discuss steam

Oak Ridge National Laboratory

237

DOE's BestPractices Steam End User Training Steam End User Training  

E-Print Network [OSTI]

DOE's BestPractices Steam End User Training Steam End User Training Steam Generation Efficiency Module Shell Losses - 1 8/27/2010 Steam End-User Training Steam Generation Efficiency Module Shell Losses-Section: Shell Losses] Banner: DOE's BestPractices Steam End User Training Steam Generation Efficiency Efficiency

Oak Ridge National Laboratory

238

EMSL - catalyst beds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

catalyst-beds en Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. http:www.emsl.pnl.govemslwebpublicationsmagnesium-behavior-and-structural-defe...

239

Compositional characteristics of the Fire Clay coal bed in a portion of eastern Kentucky  

SciTech Connect (OSTI)

The Fire Clay (Hazard No. 4) coal bed (Middle Pennsylvanian Breathitt Formation) is one of the most extensively mined coal in eastern Kentucky. The coal is used for metallurgical and steam end uses and, with its low sulfur content, should continue to be a prime steam coal. This study focuses on the petrology, mineralogy, ash geochemistry, and palynology of the coal in an eight 7.5-min quadrangle area of Leslie, Perry, Knott, and Letcher counties.

Hower, J.C.; Andrews, W.M. Jr.; Rimmer, S.M. (Univ. of Kentucky, Lexington (United States)); Eble, C.F. (Kentucky Geological Survey, Lexington (United States))

1991-08-01T23:59:59.000Z

240

Steam separator latch assembly  

DOE Patents [OSTI]

A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof. 12 figures.

Challberg, R.C.; Kobsa, I.R.

1994-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Steam separator latch assembly  

DOE Patents [OSTI]

A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof.

Challberg, Roy C. (Livermore, CA); Kobsa, Irvin R. (San Jose, CA)

1994-01-01T23:59:59.000Z

242

Water cooled steam jet  

DOE Patents [OSTI]

A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed therebetween. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock.

Wagner, Jr., Edward P. (Idaho Falls, ID)

1999-01-01T23:59:59.000Z

243

FOOD REFORM MOVEMENTS Nicolas Larchet  

E-Print Network [OSTI]

FOOD REFORM MOVEMENTS Nicolas Larchet Social historians have broadly defined two cycles of American history characterized by an efflorescence of social movements aiming to reform both the individual to the 1920s. The reform impulse thrived wherever there was a perceived vice, abuse or corruption

Boyer, Edmond

244

Reforming the Private Insurance Market  

E-Print Network [OSTI]

SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION he prospects for national health care reform are more promising than at any time since 1994. President Obama and Members of Congress have made health care reform a top priority and legislation

Kammen, Daniel M.

245

Four Rivers second generation Pressurized Circulating Fluidized Bed Combustion Project  

SciTech Connect (OSTI)

Air Products has been selected in the DOE Clean Coal Technology Round V program to build, own, and operate the first commercial power plant using second generation Pressurized Circulating Fluidized Bed (PCFB) combustion technology. The four Rivers Energy Project (Four Rivers) will produce up to 400,000 lb/hr steam, or an equivalent gross capacity of 95 MWe. The unit will be used to repower an Air Products chemicals manufacturing facility in Calvert City, Kentucky.

Holley, E.P.; Lewnard, J.J. [Air Products and Chemicals, Inc. (United States); von Wedel, G. [LLB Lurgi Lentjes Babcock Energietechnik (GmbH); Richardson, K.W. [Foster Wheeler Energy Corp. (United States); Morehead, H.T. [Westinghouse Electric Corp. (United States)

1995-04-01T23:59:59.000Z

246

Fluidized bed calciner apparatus  

DOE Patents [OSTI]

An apparatus for remotely calcining a slurry or solution feed stream of toxic or hazardous material, such as ammonium diurante slurry or uranyl nitrate solution, is disclosed. The calcining apparatus includes a vertical substantially cylindrical inner shell disposed in a vertical substantially cylindrical outer shell, in which inner shell is disposed a fluidized bed comprising the feed stream material to be calcined and spherical beads to aid in heat transfer. Extending through the outer and inner shells is a feed nozzle for delivering feed material or a cleaning chemical to the beads. Disposed in and extending across the lower portion of the inner shell and upstream of the fluidized bed is a support member for supporting the fluidized bed, the support member having uniform slots for directing uniform gas flow to the fluidized bed from a fluidizing gas orifice disposed upstream of the support member. Disposed in the lower portion of the inner shell are a plurality of internal electric resistance heaters for heating the fluidized bed. Disposed circumferentially about the outside length of the inner shell are a plurality of external heaters for heating the inner shell thereby heating the fluidized bed. Further, connected to the internal and external heaters is a means for maintaining the fluidized bed temperature to within plus or minus approximately 25.degree. C. of a predetermined bed temperature. Disposed about the external heaters is the outer shell for providing radiative heat reflection back to the inner shell.

Owen, Thomas J. (West Richland, WA); Klem, Jr., Michael J. (Richland, WA); Cash, Robert J. (Richland, WA)

1988-01-01T23:59:59.000Z

247

Saving Money with Steam Leak and Steam Trap Surveys  

E-Print Network [OSTI]

-sonic equipment. o Having uncorrected steam leaks and faulty traps cost your businesses time and money as well as being environmentally unfriendly. SERVICES ? Air Leak Surveys ? Nitrogen Leak Surveys ?Gas Leak Survey (H2, O2, Natural Gas) ? Steam Leak... productivity ? Processing efficiency ?Provide recommendations for improvement ?Stop profit loss by conserving wasted energy Undetected Steam leaks ? Rob efficiency in manufacturing and processing ? Lose millions of dollars annually ? Add up to very costly...

Woodruff, D.

2010-01-01T23:59:59.000Z

248

Steam condensate leakage  

SciTech Connect (OSTI)

Argonne National Laboratory (ANL) is a multi-program research and development center owned by the United States Department of Energy and operated by the University of Chicago. The majority of the buildings on site use steam for heating and other purposes. Steam is generated from liquid water at the site`s central boiler house and distributed around the site by means of large pipes both above and below the ground. Steam comes into each building where it is converted to liquid condensate, giving off heat which can be used by the building. The condensate is then pumped back to the boiler house where it will be reheated to steam again. The process is continual but is not perfectly efficient. A substantial amount of condensate is being lost somewhere on site. The lost condensate has both economic and environmental significance. To compensate for lost condensate, makeup water must be added to the returned condensate at the boiler house. The water cost itself will become significant in the future when ANL begins purchasing Lake Michigan water. In addition to the water cost, there is also the cost of chemically treating the water to remove impurities, and there is the cost of energy required to heat the water, as it enters the boiler house 1000 F colder than the condensate return. It has been estimated that only approximately 60% of ANL`s steam is being returned as condensate, thus 40% is being wasted. This is quite costly to ANL and will become significantly more costly in the future when ANL begins purchasing water from Lake Michigan. This study locates where condensate loss is occurring and shows how much money would be saved by repairing the areas of loss. Shortly after completion of the study, one of the major areas of loss was repaired. This paper discusses the basis for the study, the areas where losses are occurring, the potential savings of repairing the losses, and a hypothesis as to where the unaccounted for loss is occurring.

Midlock, E.B.; Thuot, J.R.

1996-07-01T23:59:59.000Z

249

Use a Vent Condenser to Recover Flash Steam Energy: Office of Industrial Technologies (OIT) Steam Energy Tips Fact Sheet  

SciTech Connect (OSTI)

BestPractices Steam tip sheet about using a vent condenser to recover flash steam energy in steam systems.

DOE Office of Industrial Technologies

2001-05-11T23:59:59.000Z

250

Dry reforming of hydrocarbon feedstocks  

SciTech Connect (OSTI)

Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

2014-01-01T23:59:59.000Z

251

Topping PCFB combustion plant with supercritical steam pressure  

SciTech Connect (OSTI)

Research is being conducted to develop a new type of coal fired plant for electric power generation. This new type of plant, called a second generation or topping pressurized circulating fluidized bed combustion (topping PCFB) plant, offers the promise of efficiencies greater than 46 percent (HHV), with both emissions and a cost of electricity that are significantly lower than conventional pulverized coal fired plants with scrubbers. The topping PCFB plant incorporates the partial gasification of coal in a carbonizer, the combustion of carbonizer char in a pressurized circulating fluidized bed combustor (PCFB), and the combustion of carbonizer fuel gas in a topping combustor to achieve gas turbine inlet temperatures of 2,300 F and higher. After completing pilot plant tests of a carbonizer, a PCFB, and a gas turbine topping combustor, all being developed for this new plant, the authors calculated a higher heating value efficiency of 46.2 percent for the plant. In that analysis, the plant operated with a conventional 2,400 psig steam cycle with 1,000 F superheat and reheat steam and a 2.5 inch mercury condenser back pressure. This paper identifies the efficiency gains that this plant will achieve by using supercritical pressure steam conditions.

Robertson, A. [Foster Wheeler Development Corp., Livingston, NJ (United States); White, J. [Parsons Power Group Inc., Reading, PA (United States)

1997-11-01T23:59:59.000Z

252

Steam Cracker Furnace Energy Improvements  

E-Print Network [OSTI]

Channel, ~ 25 mi. east of Houston ? Includes 4 manufacturing sites, 2 technology/engineering offices ?Significant community involvement Baytown Refinery Page 4 Steam Cracking to Olefins ? Process 60+ years old; ExxonMobil one of pioneers... Steam Cracker Furnace Energy Improvements Tim Gandler Energy Coordinator Baytown Olefins Plant, Baytown Tx 2010 Industrial Energy Technology Conference May, 2010 Page 2 ? Baytown Complex ? Steam Cracking to Olefins ? Furnace overview...

Gandler, T.

253

Steam System Forecasting and Management  

E-Print Network [OSTI]

by manipulation of operating schedules to avoid steam balances that result in steam venting, off gas-flaring, excessive condensing on extraction/condensing turbines, and ineffective use of extraction turbines. For example, during the fourth quarter of 1981... minimum turndown levels. Several boilers would have oeen shut down; by-product fuel gas would have been flared; and surplus low level steam would have been vented to the atmosphere. Several scenarios were studied with SFC and evaluated based...

Mongrue, D. M.; Wittke, D. O.

1982-01-01T23:59:59.000Z

254

Application of the Kellogg reforming exchanger system to large scale methanol plants  

SciTech Connect (OSTI)

In a majority of existing methanol production facilities, synthesis gas is furnished typically by a tubular fired steam reformer which uses natural gas as a feedstock. When one considers all synthesis gas produced from both ammonia and methanol plants, well over 80% is produced in a conventional reforming furnace. Steam reforming in a conventional sense, however, requires a considerable investment in both capital equipment and on-going maintenance and further, the use of such a unit operation will require heat recovery in the form of steam which forces the hand of the designer with respect to machinery driver selection. The authors have investigated alternatives to the coinventional approach with a view towards developing a process for methanol production that would be hopefully less expensive to construct, easier to operate and more reliable over the course of long term operation. In this paper, the authors present an alternative methanol plant process based on Kellogg`s proprietary reforming exchanger system (KRES). The flowsheet presented herein is for a 1500 MTPD facility that will produce US Federal Grade AA + methanol and will be compared on an economic basis to a conventional plant with respect to investment requirements and expected energy efficiency.

Joshi, G.; Schneider, R.V. III [M.W. Kellogg Co., Houston, TX (United States)

1995-12-31T23:59:59.000Z

255

Air-cooled vacuum steam condenser  

SciTech Connect (OSTI)

This patent describes a steam powered system. It comprises: a turbine for converting steam energy into mechanical energy upon expansion of steam therein, a boiler for generating steam to be fed to the turbine, and a conduit arrangement coupling the boiler to the turbine and then recoupling the turbine exhaust to the boiler through steam condensing mechanisms.

Larinoff, M.W.

1990-02-27T23:59:59.000Z

256

Constant-Pressure Measurement of Steam-  

E-Print Network [OSTI]

SGP-TR-169 Constant-Pressure Measurement of Steam- Water Relative Permeability Peter A. O by measuring in-situ steam saturation more directly. Mobile steam mass fraction was established by separate steam and water inlets or by correlating with previous results. The measured steam-water relative

Stanford University

257

Catalytic autothermal reforming increases fuel cell flexibility  

SciTech Connect (OSTI)

Experimental results are presented for the autothermal reforming (ATR) of n-hexane, n-tetradecane, benzene and benzene solutions of naphthalene. The tests were run at atmospheric pressure and at moderately high reactant preheat temperatures in the 800-900 K range. Carbon formation lines were determined for paraffinic and aromatic liquids. Profiles were determined for axial bed temperature and composition. Space velocity efforts were assessed, and the locations and types of carbon were recorded. Significant reactive differences between hydrocarbons were identified. Carbon formation characteristics were hydrocarbon specific. The differing behavior of paraffinic and aromatic fuels with respect to their carbon formation may be important in explaining the narrow range of carbon-free operating conditions found in the ATR of number two fuel oil.

Flytzani-Stephanopoulos, M.; Voecks, G.E.

1981-12-01T23:59:59.000Z

258

Steam Pressure Reduction: Opportunities and Issues; A BestPractices Steam Technical Brief  

SciTech Connect (OSTI)

A BestPractices Technical Brief describing industrial steam generation systems and opportunities for reducing steam system operating pressure.

Not Available

2005-11-01T23:59:59.000Z

259

Method for using fast fluidized bed dry bottom coal gasification  

DOE Patents [OSTI]

Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature. This gasification arrangement provides for increased utilization of the secondary char material to produce higher overall carbon conversion and product yields in the process.

Snell, George J. (Fords, NJ); Kydd, Paul H. (Lawrenceville, NJ)

1983-01-01T23:59:59.000Z

260

Steam Trap Application  

E-Print Network [OSTI]

~ ~ [EMPERATURE ~ -Surface pyrometer may indicate fluctuation due to expected in termittent discharge. -Blow down strainer, -Look for other leaks 5 ~e~7;~~rP~;i;~h~d~~:cer ~ l/month most process ~ l/week critical process ~ and air heaters in winter... valves must be -Small leaks undetected condensate & steam arf being trap line size -Electrical safety-some discharged simultaneorsly -Added cost of test tee,valves devices -Some devices need cal~bration en nipples, etc_ -Infra red devices nee~ cali- Z...

Murphy, J. J.

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

DOE's BestPractices Steam End-User Training Steam End User Training  

E-Print Network [OSTI]

DOE's BestPractices Steam End-User Training Steam End User Training Steam Generation Module Stack Losses 1 June 28, 2010 Steam EndUser Training Steam Generation Efficiency Module Stack Losses loss is almost always the largest boiler loss. [Slide Visual ­ Stack Loss Title Page] Steam

Oak Ridge National Laboratory

262

--No Title--  

Broader source: Energy.gov (indexed) [DOE]

A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on SRS Low Activity Waste (LAW) modified to simulate Hanford waste....

263

CO-PRODUCTION OF HYDROGEN AND ELECTRICITY USING PRESSURIZED CIRCULATING FLUIDIZED BED GASIFICATION TECHNOLOGY  

SciTech Connect (OSTI)

Foster Wheeler has completed work under a U.S. Department of Energy cooperative agreement to develop a gasification equipment module that can serve as a building block for a variety of advanced, coal-fueled plants. When linked with other equipment blocks also under development, studies have shown that Foster Wheeler's gasification module can enable an electric generating plant to operate with an efficiency exceeding 60 percent (coal higher heating value basis) while producing near zero emissions of traditional stack gas pollutants. The heart of the equipment module is a pressurized circulating fluidized bed (PCFB) that is used to gasify the coal; it can operate with either air or oxygen and produces a coal-derived syngas without the formation of corrosive slag or sticky ash that can reduce plant availabilities. Rather than fuel a gas turbine for combined cycle power generation, the syngas can alternatively be processed to produce clean fuels and or chemicals. As a result, the study described herein was conducted to determine the performance and economics of using the syngas to produce hydrogen for sale to a nearby refinery in a hydrogen-electricity co-production plant setting. The plant is fueled with Pittsburgh No. 8 coal, produces 99.95 percent pure hydrogen at a rate of 260 tons per day and generates 255 MWe of power for sale. Based on an electricity sell price of $45/MWhr, the hydrogen has a 10-year levelized production cost of $6.75 per million Btu; this price is competitive with hydrogen produced by steam methane reforming at a natural gas price of $4/MMBtu. Hence, coal-fueled, PCFB gasifier-based plants appear to be a viable means for either high efficiency power generation or co-production of hydrogen and electricity. This report describes the PCFB gasifier-based plant, presents its performance and economics, and compares it to other coal-based and natural gas based hydrogen production technologies.

Zhen Fan

2006-05-30T23:59:59.000Z

264

Development of Sulfur and Carbon Tolerant Reforming Alloy Catalysts Aided by Fundamental Atomistics Insights  

SciTech Connect (OSTI)

Current hydrocarbon reforming catalysts suffer from rapid carbon and sulfur poisoning. Even though there is a tremendous incentive to develop more efficient catalysts, these materials are currently formulated using inefficient trial and error experimental approaches. We have utilized a novel hybrid experimental/theoretical approach, combining quantum Density Functional Theory (DFT) calculations and various state-of-the-art experimental tools, to formulate carbon tolerant reforming catalysts. We have employed DFT calculations to develop molecular insights into the elementary chemical transformations that lead to carbon poisoning of Ni catalysts. Based on the obtained molecular insights, we have identified, using DFT quantum calculation, Sn/Ni alloy as a potential carbon tolerant reforming catalyst. Sn/Ni alloy was synthesized and tested in steam reforming of methane, propane, and isooctane. We demonstrated that the alloy catalyst is carbon-tolerant under nearly stoichiometric steam-to-carbon ratios. Under these conditions, monometallic Ni is rapidly poisoned by sp2 carbon deposits. The research approach is distinguished by a few characteristics: (a) Knowledge-based, bottom-up approach, compared to the traditional trial and error approach, allows for a more efficient and systematic discovery of improved catalysts. (b) The focus is on exploring alloy materials which have been largely unexplored as potential reforming catalysts.

Suljo Linic

2006-08-31T23:59:59.000Z

265

Development of Sulfur and Carbon Tolerant Reforming Alloy Catalysts Aided Fundamental Atomistic Insights  

SciTech Connect (OSTI)

Current hydrocarbon reforming catalysts suffer from rapid carbon and sulfur poisoning. Even though there is a tremendous incentive to develop more efficient catalysts, these materials are currently formulated using inefficient trial and error experimental approaches. We have utilized a hybrid experimental/theoretical approach, combining quantum Density Functional Theory (DFT) calculations and various state-of-the-art experimental tools, to formulate carbon tolerant reforming catalysts. We have employed DFT calculations to develop molecular insights into the elementary chemical transformations that lead to carbon poisoning of Ni catalysts. Based on the obtained molecular insights, we have identified, using DFT quantum calculation, various Ni alloy catalysts as potential carbon tolerant reforming catalysts. The alloy catalysts were synthesized and tested in steam reforming and partial oxidation of methane, propane, and isooctane. We demonstrated that the alloy catalysts are much more carbon-tolerant than monometallic Ni catalysts under nearly stoichiometric steam-to-carbon ratios. Under these conditions, monometallic Ni is rapidly poisoned by sp2 carbon deposits. The research approach is distinguished by two characteristics: (a) knowledge-based, bottomup approach, compared to the traditional trial and error approach, allows for a more efficient and systematic discovery of improved catalysts. (b) the focus is on exploring alloy materials which have been largely unexplored as potential reforming catalysts.

Suljo Linic

2008-12-31T23:59:59.000Z

266

Steam System Improvement: A Case Study  

E-Print Network [OSTI]

. For industries, this will result in the reduction of production cost. In industry where steam is utilized, the steam production and distribution system consumes a significant portion of energy. Therefore, optimization of steam system is among the biggest energy...

Venkatesan, V. V.; Leigh, N.

267

Control of bed height in a fluidized bed gasification system  

DOE Patents [OSTI]

In a fluidized bed apparatus a method for controlling the height of the fdized bed, taking into account variations in the density of the bed. The method comprises taking simultaneous differential pressure measurements at different vertical elevations within the vessel, averaging the differential pressures, determining an average fluidized bed density, then periodically calculating a weighting factor. The weighting factor is used in the determination of the actual bed height which is used in controlling the fluidizing means.

Mehta, Gautam I. (Greensburg, PA); Rogers, Lynn M. (Export, PA)

1983-12-20T23:59:59.000Z

268

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

269

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

270

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

271

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

272

Packed Bed Combustion: An Overview  

E-Print Network [OSTI]

;Packed Bed Combustion - University of Ottawa - CICS 2005 fuel fuel feed air products air fuel Retort) products Underfeed Combustion fuel feed air #12;Packed Bed Combustion - University of Ottawa - CICS 2005 required #12;Packed Bed Combustion - University of Ottawa - CICS 2005 Overfeed Bed fuel motion products air

Hallett, William L.H.

273

FEEDSTOCK-FLEXIBLE REFORMER SYSTEM (FFRS) FOR SOLID OXIDE FUEL CELL (SOFC)- QUALITY SYNGAS  

SciTech Connect (OSTI)

The U.S. Department of Energy National Energy Technology Laboratory funded this research collaboration effort between NextEnergy and the University of Michigan, who successfully designed, built, and tested a reformer system, which produced highquality syngas for use in SOFC and other applications, and a novel reactor system, which allowed for facile illumination of photocatalysts. Carbon and raw biomass gasification, sulfur tolerance of non-Platinum Group Metals (PGM) based (Ni/CeZrO2) reforming catalysts, photocatalysis reactions based on TiO2, and mild pyrolysis of biomass in ionic liquids (ILs) were investigated at low and medium temperatures (primarily 450 to 850 C) in an attempt to retain some structural value of the starting biomass. Despite a wide range of processes and feedstock composition, a literature survey showed that, gasifier products had narrow variation in composition, a restriction used to develop operating schemes for syngas cleanup. Three distinct reaction conditions were investigated: equilibrium, autothermal reforming of hydrocarbons, and the addition of O2 and steam to match the final (C/H/O) composition. Initial results showed rapid and significant deactivation of Ni/CeZrO2 catalysts upon introduction of thiophene, but both stable and unstable performance in the presence of sulfur were obtained. The key linkage appeared to be the hydrodesulfurization activity of the Ni reforming catalysts. For feed stoichiometries where high H2 production was thermodynamically favored, stable, albeit lower, H2 and CO production were obtained; but lower thermodynamic H2 concentrations resulted in continued catalyst deactivation and eventual poisoning. High H2 levels resulted in thiophene converting to H2S and S surface desorption, leading to stable performance; low H2 levels resulted in unconverted S and loss in H2 and CO production, as well as loss in thiophene conversion. Bimetallic catalysts did not outperform Ni-only catalysts, and small Ni particles were found to have lower activities under S-free conditions, but did show less effect of S on performance, in this study. Imidazolium-based ILs, choline chloride compounds and low-melting eutectics of metal nitrates were evaluated, and it was found that, ILs have some capacity to dissolve cellulose and show thermal stability to temperatures where pyrolysis begins, have no vapor pressure, (simplifying product recoveries), and can dissolve ionic metal salts, allowing for the potential of catalytic reactions on breakdown intermediates. Clear evidence of photoactive commercial TiO2 was obtained, but in-house synthesis of photoactive TiO2 proved difficult, as did fixed-bed gasification, primarily due to the challenge of removing the condensable products from the reaction zone quickly enough to prevent additional reaction. Further investigation into additional non-PGM catalysts and ILs is recommended as a follow-up to this work.

Kelly Jezierski; Andrew Tadd; Johannes Schwank; Roland Kibler; David McLean; Mahesh Samineni; Ryan Smith; Sameer Parvathikar; Joe Mayne; Tom Westrich; Jerry Mader; F. Michael Faubert

2010-07-30T23:59:59.000Z

274

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2005-04-01T23:59:59.000Z

275

Pulsed atmospheric fluidized bed combustion. Final report  

SciTech Connect (OSTI)

ThermoChem, under contract to the Department of Energy, conducted extensive research, development and demonstration work on a Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) to confirm that advanced technology can meet these performance objectives. The ThermoChem/MTCI PAFBC system integrates a pulse combustor with an atmospheric bubbling-bed type fluidized bed combustor (BFBC) In this modular configuration, the pulse combustor burns the fuel fines (typically less than 30 sieve or 600 microns) and the fluidized bed combusts the coarse fuel particles. Since the ThermoChem/MTCI PAFBC employs both the pulse combustor and the AFBC technologies, it can handle the full-size range of coarse and fines. The oscillating flow field in the pulse combustor provides for high interphase and intraparticle mass transfer rates. Therefore, the fuel fines essentially burn under kinetic control. Due to the reasonably high temperature (>1093 C but less than the temperature for ash fusion to prevent slagging), combustion of fuel fines is substantially complete at the exit of the pulse combustor. The additional residence time of 1 to 2 seconds in the freeboard of the PAFBC unit then ensures high carbon conversion and, in turn, high combustion efficiency. A laboratory unit was successfully designed, constructed and tested for over 600 hours to confirm that the PAFBC technology could meet the performance objectives. Subsequently, a 50,000 lb/hr PAFBC demonstration steam boiler was designed, constructed and tested at Clemson University in Clemson, South Carolina. This Final Report presents the detailed results of this extensive and successful PAFBC research, development and demonstration project.

NONE

1998-03-01T23:59:59.000Z

276

Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine induustrial plant study  

SciTech Connect (OSTI)

Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100[degrees]F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600[degrees]F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

1992-07-01T23:59:59.000Z

277

Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine industrial plant study  

SciTech Connect (OSTI)

Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100{degrees}F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600{degrees}F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

1992-07-01T23:59:59.000Z

278

Operating Experience of a Coal Fired Fluidized Bed at Georgetown University  

E-Print Network [OSTI]

Operation of the 100,000 lb/hr capacity, coal fired fluidized bed steam generator at Georgetown University began in July 1979. This project, which was co-funded by Georgetown University and the U. S. Department of Energy, involved expansion...

Lutes, I. G.; Gamble, R. L.

1980-01-01T23:59:59.000Z

279

What's right SHIP & Healthcare Reform Forum  

E-Print Network [OSTI]

&Health Reform What's right for you SHIP & Healthcare Reform Forum: What's Right for You This session will help you: * demystify the healthcare reform changes * explore your options * learn how

Walker, Matthew P.

280

ProSteam- A Structured Approach to Steam System Improvement  

E-Print Network [OSTI]

of the steam system could, therefore, be: ? To calculate the real cost of steam under various operational scenarios ? To identify current energy losses ? To accurately evaluate project savings ? To forecast future steam demand versus production... Energy Technology Conference, Houston, TX, April 16-19, 2002 Optimised System eff:85% 77.4MW eff:85% O.OMW 98 Uh 352'C 66 lIh eff:80% 68 lIh Max 100 Vh 18 lIh 80 lIh 50 'c 40 lIh 0.50 MW Po e Re ulrement 5 ba Ollh -0.6 barg Max 20 Vh...

Eastwood, A.

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Steam/fuel system optimization report: 6000-tpd SRC-I Demonstration Plant  

SciTech Connect (OSTI)

The design and configuration of the steam and fuel system for the 6000-ton-per-day (tpd) SRC-I Demonstration plant have been optimized, based on requirements for each area of the plant that were detailed in Area Baseline Designs of December 1982. The system was optimized primarily for the two most likely modes of plant operation, that is, when the expanded-bed hydrocracker (EBH) is operating at either high or low conversion, with all other units operating. However, the design, as such, is also operable under four other anticipated operating modes. The plant is self-sufficient in fuel except when the coker/calciner unit is not operating; then the required fuel oil import ranges from 80 to 125 MM Btu/h, lower heating value (LHV). The system affords stable operation under varying fuel gas availability and is reliable, flexible, and efficient. The optimization was based on maximizing overall efficiency of the steam system. The system was optimized to operate at five different steam-pressure levels, which are justifiable based on the plant's team requirements for process, heat duty, and power. All identified critical equipment drives will be run by steam turbines. Also part of the optimization was elimination of the steam evaporator in the wastewater treatment area. This minimized the impact on the steam system of operating in either the discharge of zero-discharge mode; the steam system remains essentially the same for either mode. Any further optimization efforts should be based on overall cost-effectiveness.

Vakil, T.D.

1983-07-01T23:59:59.000Z

282

ULTRA-SUPERCRITICAL STEAM CORROSION  

SciTech Connect (OSTI)

Efficiency increases in fossil energy boilers and steam turbines are being achieved by increasing the temperature and pressure at the turbine inlets well beyond the critical point of water. To allow these increases, advanced materials are needed that are able to withstand the higher temperatures and pressures in terms of strength, creep, and oxidation resistance. As part of a larger collaborative effort, the Albany Research Center (ARC) is examining the steam-side oxidation behavior for ultrasupercritical (USC) steam turbine applications. Initial tests are being done on six alloys identified as candidates for USC steam boiler applications: ferritic alloy SAVE12, austenitic alloy Super 304H, the high Cr-high Ni alloy HR6W, and the nickel-base superalloys Inconel 617, Haynes 230, and Inconel 740. Each of these alloys has very high strength for its alloy type. Three types of experiments are planned: cyclic oxidation in air plus steam at atmospheric pressure, thermogravimetric ana lysis (TGA) in steam at atmospheric pressure, and exposure tests in supercritical steam up to 650 C (1202 F) and 34.5 MPa (5000 psi). The atmospheric pressure tests, combined with supercritical exposures at 13.8, 20.7, 24.6, and 34.5 MPa (2000, 3000, 4000, and 5000 psi) should allow the determination of the effect of pressure on the oxidation process.

Holcomb, G.R.; Alman, D.E.; Bullard, S.B.; Covino, B.S., Jr.; Cramer, S.D.; Ziomek-Moroz, M.

2003-04-22T23:59:59.000Z

283

Renewable Liquid Fuels Reforming | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Renewable Liquid Fuels Reforming The Program anticipates that distributed reforming of biomass-derived liquid fuels could be commercial during the transition to hydrogen and used...

284

Fuel Cell 101 Don Hoffman  

E-Print Network [OSTI]

(with air) ­ Steam Reforming (with steam) ­ Autothermal Reforming (with air and steam) · Water Gas Shift

285

GCFR steam generator conceptual design  

SciTech Connect (OSTI)

The gas-cooled fast reactor (GCFR) steam generators are large once-through heat exchangers with helically coiled tube bundles. In the GCFR demonstration plant, hot helium from the reactor core is passed through these units to produce superheated steam, which is used by the turbine generators to produce electrical power. The paper describes the conceptual design of the steam generator. The major components and functions of the design are addressed. The topics discussed are the configuration, operating conditions, design criteria, and the design verification and support programs.

Holm, R.A.; Elliott, J.P.

1980-01-01T23:59:59.000Z

286

Wet-steam erosion of steam turbine disks and shafts  

SciTech Connect (OSTI)

A study of wet-steam erosion of the disks and the rotor bosses or housings of turbines in thermal and nuclear power plants shows that the rate of wear does not depend on the diagrammed degree of moisture, but is determined by moisture condensing on the surfaces of the diaphragms and steam inlet components. Renovating the diaphragm seals as an assembly with condensate removal provides a manifold reduction in the erosion.

Averkina, N. V. [JSC 'NPO TsKTI' (Russian Federation); Zheleznyak, I. V. [Leningradskaya AES branch of JSC 'Kontsern Rosenergoatom' (Russian Federation); Kachuriner, Yu. Ya.; Nosovitskii, I. A.; Orlik, V. G., E-mail: orlikvg@mail.ru [JSC 'NPO TsKTI' (Russian Federation); Shishkin, V. I. [Leningradskaya AES branch of JSC 'Kontsern Rosenergoatom' (Russian Federation)

2011-01-15T23:59:59.000Z

287

Novel Reforming Catalysts  

SciTech Connect (OSTI)

Aqueous phase reforming is useful for processing oxygenated hydrocarbons to hydrogen and other more useful products. Current processing is hampered by the fact that oxide based catalysts are not stable under high temperature hydrothermal conditions. Silica in the form of structured MCM-41 is thermally a more stable support for Co and Ni than conventional high surface area amorphous silica but hydrothermal stability is not demonstrated. Carbon nanotube supports, in contrast, are highly stable under hydrothermal reaction conditions. In this project we show that carbon nanotubes are stable high activity/selectivity supports for the conversion of ethylene glycol to hydrogen.

Pfefferle, Lisa D; Haller, Gary L

2012-10-16T23:59:59.000Z

288

Apparatus for controlling fluidized beds  

DOE Patents [OSTI]

An apparatus and process are disclosed for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance. 2 figs.

Rehmat, A.G.; Patel, J.G.

1987-05-12T23:59:59.000Z

289

Staged fluidized bed  

DOE Patents [OSTI]

The invention relates to oil shale retorting and more particularly to staged fluidized bed oil shale retorting. Method and apparatus are disclosed for narrowing the distribution of residence times of any size particle and equalizing the residence times of large and small particles in fluidized beds. Particles are moved up one fluidized column and down a second fluidized column with the relative heights selected to equalize residence times of large and small particles. Additional pairs of columns are staged to narrow the distribution of residence times and provide complete processing of the material.

Mallon, R.G.

1983-05-13T23:59:59.000Z

290

Combined Heat and Power Plant Steam Turbine  

E-Print Network [OSTI]

Combined Heat and Power Plant Steam Turbine Steam Turbine Chiller Campus Heat Load Steam (recovered waste heat) Gas Turbine University Substation High Pressure Natural Gas Campus Electric Load Southern Generator Heat Recovery Alternative Uses: 1. Campus heating load 2. Steam turbine chiller to campus cooling

Rose, Michael R.

291

Steam Load Reduction Guidance Emergency Management Program  

E-Print Network [OSTI]

Steam Load Reduction Guidance Emergency Management Program v October 2014 Steam_Load_Reduction_Guidance_DSRDSR 1.0 PurposeandScope Utilities provides steam to the campus community for space heating, hot water in the steam distribution system or the Central Energy Plant, the preservation of building infrastructure

Pawlowski, Wojtek

292

Steam-Powered Sensing Chengjie Zhang  

E-Print Network [OSTI]

Steam-Powered Sensing Chengjie Zhang 1 Affan Syed 1,2 Young Cho 1 John Heidemann 1 chengjie blockages in steam pipelines of a production oilfield. First, we eliminate the high cost of bringing power in steam pipelines and full blockages in hot water pipelines. Finally, we evaluate our "steam

Heidemann, John

293

Steam Plant Conversion Eliminating Campus Coal Use  

E-Print Network [OSTI]

Steam Plant Conversion Eliminating Campus Coal Use at the Steam Plant #12;· Flagship campus region produce 14% of US coal (TN only 0.2%) Knoxville and the TN Valley #12;· UT is one of about 70 U.S. colleges and universities w/ steam plant that burns coal · Constructed in 1964, provides steam for

Dai, Pengcheng

294

The Steam System Scoping Tool: Benchmarking Your Steam Operations Through Best Practices  

E-Print Network [OSTI]

system efficiency. The BestPractices Steam effort, a part of the DOE-OIT effort, has developed a new tool that steam energy managers and operations personnel can use to assess their steam operations and improve their steam energy usage -the Steam System...

Wright, A.; Hahn, G.

295

DOE's BestPractices Steam End User Training Steam End User Training  

E-Print Network [OSTI]

DOE's BestPractices Steam End User Training Steam End User Training Welcome Module - 1 8/27/2010 Steam End User Training Welcome Module Slide 1 ­ Steam End User Training Welcome to the Department of Energy's Industrial Technologies Program BestPractices Steam End-User Training. The Department of Energy

Oak Ridge National Laboratory

296

DOE's BestPractices Steam End User Training Steam EndUser Training  

E-Print Network [OSTI]

DOE's BestPractices Steam End User Training Steam EndUser Training Resource Utilization. These include fuel selection, steam enduse or demand management, and combined heat and power activities importance of investigating steam enduse components and reducing steam consumption or improving the energy

Oak Ridge National Laboratory

297

Hydrocarbon reforming for hydrogen fuel cells: a study of carbon formation on autothermal reforming catalysts. Final report  

SciTech Connect (OSTI)

The mechanism of carbon formation on nickel autothermal steam reforming catalysts has been studied by temperature-programming, thermogravimetric and electron microscopic techniques. Temperature-programmed surface reaction (TPSR) studies of carbon deposited on nickel reforming catalysts by the decomposition of C/sub 2/H/sub 4/ and C/sub 2/H/sub 2/ exhibit seven forms of carbon that are distinguished by their characteristic reactivity with H/sub 2/ and 3.0-vol % H/sub 2/O/He. The relative population of the different carbon states depends primarily on the temperature during deposition. C/sub 2/H/sub 2/ exposure populates the same carbon states as C/sub 2/H/sub 4/ exposure but at approximately 100/sup 0/K lower deposition temperature. Similar carbon states were found on all nickel catalysts studies including Ni/..gamma..-Al/sub 2/O/sub 3/ and Ni/MgO-Al/sub 2/O/sub 3/ leading to the conclusion that the support has little effect on carbon deposit formation and reactivity. The reactivity of the carbon states is not altered by exposure to steam in C/sub 2/H/sub 4/-H/sub 2/O mixtures, but the amount of carbon deposited decreases to zero as H/sub 2/O/C increases past a critical ratio.

McCarty, J.G.; Sheridan, D.M.; Wise, H.; Wood, B.J.

1981-12-01T23:59:59.000Z

298

The steam engine and industrialization  

E-Print Network [OSTI]

Simon Schaffer in York Rail Museum talks to the camera about the relationship between the steam engine and industrialization and whatsteam meant; a regular supply of moving power for workshops and factories....

Dugan, David

2004-08-17T23:59:59.000Z

299

Foam Cleaning of Steam Turbines  

E-Print Network [OSTI]

The efficiency and power output of a steam turbine can be dramatically reduced when deposits form on the turbine blades. Disassembly and mechanical cleaning of the turbine is very time consuming and costly. Deposits can be removed from the turbine...

Foster, C.; Curtis, G.; Horvath, J. W.

300

The Elimination of Steam Traps  

E-Print Network [OSTI]

claims and misinformation gener ated by over thirty-six steam trap manufacturers in the United States alone. A PARTIAL LIST OF STEAM TRAP MANUFACTURERS AAF GESTRA ANDERSON HIROSS ARMSTRONG HOFFMAN BARNES &JONES HONEYWELL BRAUKMANN BESTOBELL... removal had been devised and these same methods, with minor variations, are employed today. The inverted bucket trap was in vented in 1910 by Otto Arner, a friend of Adam Armstrong. Armstrong began his business career by making bicycle spokes...

Dickman, F.

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Capturing Energy Savings with Steam Traps  

E-Print Network [OSTI]

Capturing Energy Savings with Steam Traps Richard C; Bockwinkel General Manager Armstrong Service? A Division of Armstrong International, Inc. Orlando, Florida ABSTRACT This paper will discuss the energy savings potential of steam... Engineer Steam Traps Armstrong International, Inc. Three Rivers, Michigan basis. Finally, it's important to recognize that a steam trap program will reduce steam waste> which will reduce the amount of fuel burned> which will reduce pollutants...

Bockwinkel, R. G.; French, S. A.

302

Multipath Curved Planar Reformation of the Peripheral  

E-Print Network [OSTI]

Multipath Curved Planar Reformation of the Peripheral Arterial Tree in CT Angiography1 Justus that cause artifacts in multipath curved planar reformations (MPCPRs) of the peripheral arterial tree in 10-oblique multiplanar reformations perpendicular to the ves- sel centerline (10), and curved planar reformations

303

Optimization of Multiplanar Reformations from Isotropic  

E-Print Network [OSTI]

Optimization of Multiplanar Reformations from Isotropic Data Sets Acquired with 16­ Detector Row coronal reformations at vari- ous thicknesses were ranked qualitatively by three radiol- ogists. Effective reformations of data acquired in the custom phantom were compared, coronal reformations obtained with the 16

304

Toward a Reformalization of QSIM Benjamin Shults  

E-Print Network [OSTI]

Toward a Reformalization of QSIM Benjamin Shults Department of Mathematics University of Texas is to reformalize part of the framework of the Guaranteed Coverage Theorem for QSIM. The intention is not to reformalize every detail of the proof but merely to mention some areas whose reformalization lends deeper

Kuipers, Benjamin

305

Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation  

E-Print Network [OSTI]

to make additional steam for the steam turbine cycle. Thein multi-pressure-level steam turbines to produce additionalthe superheated steam to the steam turbine cycle. The most

Lu, Xiaoming

2012-01-01T23:59:59.000Z

306

Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam  

SciTech Connect (OSTI)

Industrial Technologies Program's BestPractices tip sheet on improving efficiency of industrial steam systems by recovery latent heat from low-pressure steam.

Not Available

2005-09-01T23:59:59.000Z

307

A Novel Slurry-Based Biomass Reforming Process Final Technical Report  

SciTech Connect (OSTI)

This project was focused on developing a catalytic means of producing H2 from raw, ground biomass, such as fast growing poplar trees, willow trees, or switch grass. The use of a renewable, biomass feedstock with minimal processing can enable a carbon neutral means of producing H2 in that the carbon dioxide produced from the process can be used in the environment to produce additional biomass. For economically viable production of H2, the biomass is hydrolyzed and then reformed without any additional purification steps. Any unreacted biomass and other byproduct streams are burned to provide process energy. Thus, the development of a catalyst that can operate in the demanding corrosive environment and presence of potential poisons is vital to this approach. The concept for this project is shown in Figure 1. The initial feed is assumed to be a >5 wt% slurry of ground wood in dilute base, such as potassium carbonate (K2CO3). Base hydrolysis and reforming of the wood is carried out at high but sub-critical pressures and temperatures in the presence of a solid catalyst. A Pd alloy membrane allows the continuous removal of pure , while the retentate, including methane is used as fuel in the plant. The project showed that it is possible to economically produce H2 from woody biomass in a carbon neutral manner. Technoeconomic analyses using HYSYS and the DOE's H2A tool [1] were used to design a 2000 ton day-1 (dry basis) biomass to hydrogen plant with an efficiency of 46% to 56%, depending on the mode of operation and economic assumptions, exceeding the DOE 2012 target of 43%. The cost of producing the hydrogen from such a plant would be in the range of $1/kg H2 to $2/kg H2. By using raw biomass as a feedstock, the cost of producing hydrogen at large biomass consumption rates is more cost effective than steam reforming of hydrocarbons or biomass gasification and can achieve the overall cost goals of the DOE Fuel Cell Technologies Program. The complete conversion of wood to hydrogen, methane, and carbon dioxide was repeatedly demonstrated in batch reactors varying in size from 50 mL to 7.6 L. The different wood sources (e.g., swamp maple, poplar, and commercial wood flour) were converted in the presence of a heterogeneous catalyst and base at relatively low temperatures (e.g., 310 �������°C) at sub-critical pressures sufficient to maintain the liquid phase. Both precious metal and base metal catalysts were found to be active for the liquid phase hydrolysis and reforming of wood. Pt-based catalysts, particularly Pt-Re, were shown to be more selective toward breaking C-C bonds, resulting in a higher selectivity to hydrogen versus methane. Ni-based catalysts were found to prefer breaking C-O bonds, favoring the production of methane. The project showed that increasing the concentration of base (base to wood ratio) in the presence of Raney Ni catalysts resulted in greater selectivity toward hydrogen but at the expense of increasing the production of undesirable organic acids from the wood, lowering the amount of wood converted to gas. It was shown that by modifying Ni-based catalysts with dopants, it was possible to reduce the base concentration while maintaining the selectivity toward hydrogen and increasing wood conversion to gas versus organic acids. The final stage of the project was the construction and testing of a demonstration unit for H2 production. This continuous flow demonstration unit consisted of wood slurry and potassium carbonate feed pump systems, two reactors for hydrolysis and reforming, and a gas-liquid separation system. The technical challenges associated with unreacted wood fines and Raney Ni catalyst retention limited the demonstration unit to using a fixed bed Raney Ni catalyst form. The lower activity of the larger particle Raney Ni in turn limited the residence time and thus the wood mass flow feed rate to 50 g min-1 for a 1 wt% wood slurry. The project demonstrated continuous H2 yields with unmodified, fixed bed Raney Ni, from 63% to 100% with correspond

Sean C. Emerson; Timothy D. Davis; A. Peles; Ying She; Joshua Sheffel; Rhonda R. Willigan; Thomas H. Vanderspurt; Tianli Zhu

2011-09-30T23:59:59.000Z

308

Four Rivers second generation pressurized circulating fluidized bed combustion project  

SciTech Connect (OSTI)

Air Products has been selected in the DOE Clean Coal Technology Round 5 program to build, own, and operate the first commercial power plant using second generation Pressurized Circulating Fluidized Bed (PCFB) combustion technology. The Four Rivers Energy Project (Four Rivers) will produce approximately 70 MW electricity, and will produce up to 400,000 lb/hr steam, or an equivalent gross capacity of 95 MWe. The unit will be used to repower an Air Products chemicals manufacturing facility in Calvert City, Kentucky.

Holley, E.P.; Lewnard, J.J. [Air Products and Chemicals, Inc., Allentown, PA (United States); Wedel, G. von; Richardson, K.W.; Morehead, H.T.

1995-12-31T23:59:59.000Z

309

Before the House Oversight and Government Reform Subcommittee...  

Office of Environmental Management (EM)

Oversight and Government Reform Subcommittee on Technology, Information Policy, Intergovernmental Relations, and Procurement Reform Before the House Oversight and Government Reform...

310

Evaluation of steam path audits  

SciTech Connect (OSTI)

Tri-State Generation and Transmission association is the operating agent for the 1350 megawatt Craig Generating Station, located in northwestern Colorado. Tri-State has recently incorporated turbine steam path audits into their aggressive performance improvement program. The intent of the audits are to quantify and attain the most cost effective increase in turbine performance as a result of a major outage. Valuable information about performance losses in the turbine has been obtained from steam path audits conducted on the three Craig Units. However, accurate audit results often depend on the quality of measurements and the experience of the auditor. Without a second method to verify the results of a steam path audit, repairs might be performed on a non-cost effective basis, or significant performance degradations might be overlooked. In addition, an inaccurate audit may lead to erroneous expectations for performance improvements resulting from the maintenance performed during the outage.

Caudill, M.B. [Tri-State Generation and Transmission Association, Inc., Montrose, CO (United States); Griebenow, R.D. [SAIC, Huntersville, NC (United States)

1995-06-01T23:59:59.000Z

311

CIRCULATING MOVING BED COMBUSTION PROOF OF CONCEPT  

SciTech Connect (OSTI)

Circulating Moving Bed (CMB) combustion technology has its roots in traditional circulating fluidized bed technology and involves a novel method of solid fuel combustion and heat transfer. CMB technology represents a step change in improved performance and cost relative to conventional PC and FBC boilers. The CMB heat exchanger preheats the energy cycle working fluid, steam or air, to the high temperature levels required in systems for advanced power generation. Unique features of the CMB are the reduction of the heat transfer surfaces by about 60% as a result of the enhanced heat transfer rates, flexibility of operation, and about 30% lower cost over existing technology. The CMB Phase I project ran from July 2001 through March 2003. Its objective was to continue development of the CMB technology with a series of proof of concept tests. The tests were conducted at a scale that provided design data for scale up to a demonstration plant. These objectives were met by conducting a series of experiments in ALSTOM Power’s Multi-use Test Facility (MTF). The MTF was modified to operate under CMB conditions of commercial interest. The objective of the tests were to evaluate gas-to-solids heat transfer in the upper furnace, assess agglomeration in the high temperature CMB bubbling bed, and evaluate solids-to-tube heat transfer in the moving bed heat exchanger. The Phase I program results showed that there are still some significant technical uncertainties that needed to be resolved before the technology can be confidently scaled up for a successful demonstration plant design. Work remained in three primary areas: • scale up of gas to solid heat transfer • high temperature finned surface design • the overall requirements of mechanical and process design. The CMB Phase II workscope built upon the results of Phase I and specifically addressed the remaining technical uncertainties. It included a scaled MTF heat transfer test to provide the necessary data to scale up gas-to-solids heat transfer. A stress test rig was built and tested to provide validation data for a stress model needed to support high temperature finned surface design. Additional cold flow model tests and MTF tests were conducted to address mechanical and process design issues. This information was then used to design and cost a commercial CMB design concept. Finally, the MBHE was reconfigured into a slice arrangement and tested for an extended duration at a commercial CFB plant.

Jukkola, Glen

2010-06-30T23:59:59.000Z

312

"Greening" Industrial Steam Generation via On-demand Steam Systems  

E-Print Network [OSTI]

boiler technology currently in service in the U.S., it is critical to raise awareness and examine the role of emerging new technologies to address the energy and environmental challenges inherent with steam generation. In the same way that tank...

Smith, J. P.

2010-01-01T23:59:59.000Z

313

Bed drain cover assembly for a fluidized bed  

DOE Patents [OSTI]

A loose fitting movable cover plate (36), suitable for the severe service encountered in a fluidized bed combustor (10), restricts the flow of solids into the combustor drain lines (30) during shutdown of the bed. This cover makes it possible to empty spent solids from the bed drain lines which would otherwise plug the piping between the drain and the downstream metering device. This enables use of multiple drain lines each with a separate metering device for the control of solids flow rate.

Comparato, Joseph R. (Bloomfield, CT); Jacobs, Martin (Hartford, CT)

1982-01-01T23:59:59.000Z

314

Solar Reforming of Carbon Dioxide to Produce Diesel Fuel  

SciTech Connect (OSTI)

This project focused on the demonstration of an innovative technology, referred to as the Sunexus CO2 Solar Reformer, which utilizes waste CO2 as a feedstock for the efficient and economical production of synthetic diesel fuel using solar thermal energy as the primary energy input. The Sunexus technology employs a two stage process for the conversion of CO2 to diesel fuel. A solar reforming system, including a specially designed reactor and proprietary CO2 reforming catalyst, was developed and used to convert captured CO2 rich gas streams into syngas (primarily hydrogen and carbon monoxide) using concentrated solar energy at high conversion efficiencies. The second stage of the system (which has been demonstrated under other funding) involves the direct conversion of the syngas into synthetic diesel fuel using a proprietary catalyst (Terra) previously developed and validated by Pacific Renewable Fuels and Chemicals (PRFC). The overall system energy efficiency for conversion of CO2 to diesel fuel is 74%, due to the use of solar energy. The results herein describe modeling, design, construction, and testing of the Sunexus CO2 Solar Reformer. Extensive parametric testing of the solar reformer and candidate catalysts was conducted and chemical kinetic models were developed. Laboratory testing of the Solar Reformer was successfully completed using various gas mixtures, temperatures, and gas flow rates/space velocities to establish performance metrics which can be employed for the design of commercial plants. A variety of laboratory tests were conducted including dry reforming (CO2 and CH{sub 4}), combination dry/steam reforming (CO2, CH{sub 4} & H{sub 2}O), and tri-reforming (CO2, CH{sub 4}, H{sub 2}O & O{sub 2}). CH{sub 4} and CO2 conversions averaged 95-100% and 50-90% per reformer cycle, respectively, depending upon the temperatures and gas space velocities. No formation of carbon deposits (coking) on the catalyst was observed in any of these tests. A 16 ft. diameter, concentrating solar dish was modified to accommodate the Sunexus CO2 Solar Reformer and the integrated system was installed at the Pacific Renewable Fuels and Chemicals test site at McClellan, CA. Several test runs were conducted without catalyst during which the ceramic heat exchanger in the Sunexus Solar Reformer reached temperatures between 1,050 F (566 C) and 2,200 F (1,204 C) during the test period. A dry reforming mixture of CO2/CH{sub 4} (2.0/1.0 molar ratio) was chosen for all of the tests on the integrated solar dish/catalytic reformer during December 2010. Initial tests were carried out to determine heat transfer from the collimated solar beam to the catalytic reactor. The catalyst was operated successfully at a steady-state temperature of 1,125 F (607 C), which was sufficient to convert 35% of the 2/1 CO2/CH{sub 4} mixture to syngas. This conversion efficiency confirmed the results from laboratory testing of this catalyst which provided comparable syngas production efficiencies (40% at 1,200 F [650 C]) with a resulting syngas composition of 20% CO, 16% H{sub 2}, 39% CO2 and 25% CH{sub 4}. As based upon the laboratory results, it is predicted that 90% of the CO2 will be converted to syngas in the solar reformer at 1,440 F (782 C) resulting in a syngas composition of 50% CO: 43% H{sub 2}: 7% CO2: 0% CH{sub 4}. Laboratory tests show that the higher catalyst operating temperature of 1,440 F (782 C) for efficient conversion of CO2 can certainly be achieved by optimizing solar reactor heat transfer, which would result in the projected 90% CO2-to-syngas conversion efficiencies. Further testing will be carried out during 2011, through other funding support, to further optimize the solar dish CO2 reformer. Additional studies carried out in support of this project and described in this report include: (1) An Assessment of Potential Contaminants in Captured CO2 from Various Industrial Processes and Their Possible Effect on Sunexus CO2 Reforming Catalysts; (2) Recommended Measurement Methods for Assessing Contaminant Levels in Captured CO2 Streams; (3) An Asse

Dennis Schuetzle; Robert Schuetzle

2010-12-31T23:59:59.000Z

315

Lowest Pressure Steam Saves More BTU's Than You Think  

E-Print Network [OSTI]

ABSTRACT Steam is the most transferring heat from But most steam systems LOWEST PRESSURE STEAM SAVES MORE BTU'S THAN YOU THINK Stafford J. Vallery Armstrong Machine Works Three Rivers, Michigan steam to do the process heating rather than...

Vallery, S. J.

316

Use Steam Jet Ejectors or Thermocompressors to Reduce Venting...  

Broader source: Energy.gov (indexed) [DOE]

Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam This tip sheet...

317

DOE BestPractices Steam End User Training  

E-Print Network [OSTI]

DOE BestPractices Steam End User Training Guide Alternate Text Narratives and Graphic Descriptions June 29, 2010 #12;DOE BestPractices Steam End User Training Steam End User Training Table ................................................................................................................................................................................................ 8 Technical Modules Steam Generation Efficiency Efficiency Definition

Oak Ridge National Laboratory

318

The steam engine and what it needs  

E-Print Network [OSTI]

Simon Schaffer explains that to produce an effective steam engine you do not just need specific inventions, such as the separate condenser of James Watt, but also skills from clockworking, distillation, metal working and so on. Then the steam power...

Dugan, David

2004-08-18T23:59:59.000Z

319

The Future of Steam: A Preliminary Discussion  

E-Print Network [OSTI]

Steam production represents a significant proportion of today's industrial energy demand. But the evolution of process technologies, as well as turbulence in energy markets, suggests that steam's role may be subject to change in the next decade...

Russell, C.; Harrell, G.; Moore, J.; French, S.

320

Insulate Steam Distribution and Condensate Return Lines  

SciTech Connect (OSTI)

This revised ITP tip sheet on insulating steam distribution and condensate return lines provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Steam Conservation and Boiler Plant Efficiency Advancements  

E-Print Network [OSTI]

This paper examines several cost-effective steam conservation and boiler plant efficiency advancements that were implemented during a recently completed central steam boiler plant replacement project at a very large semiconductor manufacturing...

Fiorino, D. P.

322

Training: Steam Systems | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Steam Systems Training: Steam Systems April 16, 2014 - 6:31pm Addthis Learn about the diverse training sessions offered. The courses are taught by highly qualified instructors who...

323

Experimental and computational investigations of sulfur-resistant bimetallic catalysts for reforming of biomass gasification products  

SciTech Connect (OSTI)

A combination of density functional theory (DFT) calculations and experimental studies of supported catalysts was used to identify H{sub 2}S-resistant biomass gasification product reforming catalysts. DFT calculations were used to search for bimetallic, nickel-based (1 1 1) surfaces with lower sulfur adsorption energies and enhanced ethylene adsorption energies. These metrics were used as predictors for H{sub 2}S resistance and activity toward steam reforming of ethylene, respectively. Relative to Ni, DFT studies found that the Ni/Sn surface alloy exhibited enhanced sulfur resistance and the Ni/Ru system exhibited an improved ethylene binding energy with a small increase in sulfur binding energy. A series of supported bimetallic nickel catalysts was prepared and screened under model ethylene reforming conditions and simulated biomass tar reforming conditions. The observed experimental trends in activity were consistent with theoretical predictions, with observed reforming activities in the order Ni/Ru > Ni > Ni/Sn. Interestingly, Ni/Ru showed a high level of resistance to sulfur poisoning compared with Ni. This sulfur resistance can be partly explained by trends in sulfur versus ethylene binding energy at different types of sites across the bimetallic surface.

Rangan, Meghana; Yung, Matthew M.; Medlin, J. William (NREL); (Colorado)

2011-11-17T23:59:59.000Z

324

DOE's BestPractices Steam End User Training Steam End User Training  

E-Print Network [OSTI]

DOE's BestPractices Steam End User Training Steam End User Training Navigational Tutorial - 1 8/27/2010 Steam End User Training Navigational Tutorial Module Slide 1 ­ Introduction Hello, and welcome to the Steam End User Training. I would like to take a few minutes to show you how to navigate through

Oak Ridge National Laboratory

325

DOE's BestPractices Steam End User Training Steam End User Training  

E-Print Network [OSTI]

DOE's BestPractices Steam End User Training Steam End User Training Introduction Module - 1 8/27/2010 Steam End User Training Introduction Module Slide 1 - Introduction Title Page Hello, and welcome to the Steam System End User training. In this training, we will investigate how to assess, evaluate

Oak Ridge National Laboratory

326

Optimisation of Fuel Usage and Steam Availability in the Power and Steam  

E-Print Network [OSTI]

Optimisation of Fuel Usage and Steam Availability in the Power and Steam Plant of a Paper Mill KEYWORDS: Model Predictive Control, Improved Efficiency, Optimisation, Power and Steam Supply System ABSTRACT This paper presents the results of a project aimed at minimising fuel usage while maximising steam

Cambridge, University of

327

Low pressure combustor for generating steam downhole  

SciTech Connect (OSTI)

A compact catalytic combustor for generating steam downhole in an oil reservoir has steam generating tubes that are attached to a metal catalyst support. The metal support comprises sheets of metal that are spaced apart and transverse to the tubes. Heat from combustion is generated on the metal sheets and is conducted to the steam generating tubes. The steam is injected into the oil reservoir. The combustion gas is vented to ground level.

Retallick, W.B.

1983-03-22T23:59:59.000Z

328

Coal Bed Methane Primer  

SciTech Connect (OSTI)

During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

Dan Arthur; Bruce Langhus; Jon Seekins

2005-05-25T23:59:59.000Z

329

Best Management Practice #8: Steam Boiler Systems  

Broader source: Energy.gov [DOE]

Boilers and steam generators are commonly used in large heating systems, institutional kitchens, or in facilities where large amounts of process steam are used. This equipment consumes varying amounts of water depending on system size, the amount of steam used, and the amount of condensate returned.

330

Steam System Improvement: A Case Study  

E-Print Network [OSTI]

usage) where steam generation accounts for 85% of the total energy used. Therefore, optimization of the steam system has the biggest energy saving potential. This paper mill produces 40,000 pounds of steam at 600 psig and distributes it to the paper...

Leigh, N.; Venkatesan, V. V.

331

A LABORATORY INVESTIGATION OF STEAM ADSORPTION  

E-Print Network [OSTI]

A LABORATORY INVESTIGATION OF STEAM ADSORPTION IN GEOTHERMAL RESERVOIR ROCKS OF STANFORD UNIVERSITY, if any, liquid. Yet to satisfy material bal- ance constraints, another phase besides steam must be present. If steam adsorption occurring in significant amounts is not accounted for, the reserves

Stanford University

332

STEAM-WATER RELATIVE PERMEABILITY A DISSERTATION  

E-Print Network [OSTI]

STEAM-WATER RELATIVE PERMEABILITY A DISSERTATION SUBMITTED TO THE DEPARTMENT OF PETROLEUM Laboratory. iv #12;ABSTRACT Steam-water relative permeability curves are required for mathematical models of two-phase geothermal reservoirs. In this study, drainage steam- water relative permeabilities were

Stanford University

333

Steam Sterilization Cycles for Lab Applications  

E-Print Network [OSTI]

Steam Sterilization Cycles for Lab Applications Presented by Gary Butler STERIS Life Sciences August 2009 #12;Early Steam Sterilizers Koch Upright Sterilizer · First Pressurized Sterilizer · First OPERATING END (NO PRINTER) PRIMARY OPERATING END WITH PRINTER SAFETY VALVE CHAMBER PRESSURE GAUGE Steam

Farritor, Shane

334

Biparticle fluidized bed reactor  

DOE Patents [OSTI]

A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase is described. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figures.

Scott, C.D.

1993-12-14T23:59:59.000Z

335

Biparticle fluidized bed reactor  

DOE Patents [OSTI]

A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figs.

Scott, C.D.; Marasco, J.A.

1995-04-25T23:59:59.000Z

336

Fluidized-bed sorbents  

SciTech Connect (OSTI)

The objectives of this project are to identify and demonstrate methods for enhancing long-term chemical reactivity and attrition resistance of zinc oxide-based mixed metal-oxide sorbents for desulfurization of hot coal-derived gases in a high-temperature, high-pressure (HTHP) fluidized-bed reactor. In this program, regenerable ZnO-based mixed metal-oxide sorbents are being developed and tested. These include zinc ferrite, zinc titanate, and Z-SORB sorbents. The Z-SORB sorbent is a proprietary sorbent developed by Phillips Petroleum Company (PPCo).

Gangwal, S.K.; Gupta, R.P.

1994-10-01T23:59:59.000Z

337

Generating Steam by Waste Incineration  

E-Print Network [OSTI]

Combustible waste is a significant source of steam at the new John Deere Tractor Works assembly plant in Waterloo, Iowa. The incinerators, each rated to consume two tons of solid waste per hour, are expected to provide up to 100 percent of the full...

Williams, D. R.; Darrow, L. A.

1981-01-01T23:59:59.000Z

338

Materials Performance in USC Steam  

SciTech Connect (OSTI)

The proposed steam inlet temperature in the Advanced Ultra Supercritical (A-USC) steam turbine is high enough (760 °C) that traditional turbine casing and valve body materials such as ferritic/martensitic steels will not suffice due to temperature limitations of this class of materials. Cast versions of several traditionally wrought Ni-based superalloys were evaluated for use as casing or valve components for the next generation of industrial steam turbines. The full size castings are substantial: 2-5,000 kg each half and on the order of 100 cm thick. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled to produce equivalent microstructures. A multi-step homogenization heat treatment was developed to better deploy the alloy constituents. The most successful of these cast alloys in terms of creep strength (Haynes 263, Haynes 282, and Nimonic 105) were subsequently evaluated by characterizing their microstructure as well as their steam oxidation resistance (at 760 and 800 °C).

G. R. Holcomb, P. Wang, P. D. Jablonski, and J. A. Hawk

2010-05-01T23:59:59.000Z

339

Fluidized bed boiler feed system  

DOE Patents [OSTI]

A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

Jones, Brian C. (Windsor, CT)

1981-01-01T23:59:59.000Z

340

Plant View On Reducing Steam Trap Energy Loss  

E-Print Network [OSTI]

of the steam traps are passing excess steam. This is caused by neglect of aged steam traps which have worn out and misapplication of steam traps by oversizing or using the 'wrong' type trap. Elimination of steam wastes by an effective well engineered steam trap...

Vallery, S. J.

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Comprehensive Study of the Impact of Steam on Polyethyleneimine on Silica for CO{sub 2} Capture  

SciTech Connect (OSTI)

An amine sorbent, prepared by impregnation of polyethyleneimine on silica, was tested for steam stability. The stability of the sorbent was investigated in a fixed bed reactor using multiple steam cycles of 90 vol.% H{sub 2}O/He at 105 {degrees}?C and the gas effluent was monitored with a mass spectrometer. CO{sub 2} uptake of sorbent was found to decrease with repeated exposure to steam. Characterization of the spent sorbent using N{sub 2} physisorption, SEM, and thermogravimetric analysis (TGA), showed that the decrease in CO{sub 2} loading can possibly be attributed to a reagglomeration of the amine in the pores of the silica. No support effect was found in this study. The commercial SiO{sub 2} used, Cariact G10, was found to be stable under the conditions used. While it was found that subjecting the sorbent to several steam cycles decreased its CO{sub 2} uptake, a continuous exposure of the sorbent to steam did not have a significant performance impact. A silanated sorbent, consisting of a mixture of PEI and aminopropyl-triethoxysilane on SiO{sub 2} support, was also investigated for steam stability. Similarly to the non-silanated sorbent, the CO{sub 2} loading of this sorbent decreased upon steam exposure, although a mechanism for this change has not been postulated at this time.

Hammache, Sonia; Hoffman, James S.; Gray, McMahan L.; Fauth, Daniel J; Howard, Bret H.; Pennline, Henry W.

2013-11-01T23:59:59.000Z

342

Pressurized fluidized bed reactor  

DOE Patents [OSTI]

A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine. 1 fig.

Isaksson, J.

1996-03-19T23:59:59.000Z

343

Pressurized fluidized bed reactor  

DOE Patents [OSTI]

A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine.

Isaksson, Juhani (Karhula, FI)

1996-01-01T23:59:59.000Z

344

Breakout SessionIII,Bed-Materialand Bed-TopographyMeasurement  

E-Print Network [OSTI]

as independent variables. 2. Does your organization have any accuracy standards for collecting theses types (bed topography or bed material) of sediment data? National and international mapping standards such as those of Standards and Technology, and the North Atlantic Treaty Organization's Digital Geographic Information

345

Steam Pressure Reduction Opportunities and Issues  

E-Print Network [OSTI]

Parameter Baseline System (130 psig) (klb/h) % of Steam Produced Reduced Pressure (80 psig) (klb/h) % of Steam Produced Savings (klb/h) Steam generation 40.8 40.3 0.5 High pressure steam consumption 12.5 30.64 12.2 30.27 0.3 Low... the operating pressure is reached (3). The amount of fuel consumed is reduced while still meeting the required need for thermal energy. This fuel reduction can be estimated using the U.S. Department of Energy (DOE) BestPractices Steam System Assessment Tool...

Berry, J.; Griffin, B.; Wright, A. L.

2006-01-01T23:59:59.000Z

346

Steam cooling system for a gas turbine  

DOE Patents [OSTI]

The steam cooling circuit for a gas turbine includes a bore tube assembly supplying steam to circumferentially spaced radial tubes coupled to supply elbows for transitioning the radial steam flow in an axial direction along steam supply tubes adjacent the rim of the rotor. The supply tubes supply steam to circumferentially spaced manifold segments located on the aft side of the 1-2 spacer for supplying steam to the buckets of the first and second stages. Spent return steam from these buckets flows to a plurality of circumferentially spaced return manifold segments disposed on the forward face of the 1-2 spacer. Crossover tubes couple the steam supply from the steam supply manifold segments through the 1-2 spacer to the buckets of the first stage. Crossover tubes through the 1-2 spacer also return steam from the buckets of the second stage to the return manifold segments. Axially extending return tubes convey spent cooling steam from the return manifold segments to radial tubes via return elbows.

Wilson, Ian David (Mauldin, SC); Barb, Kevin Joseph (Halfmoon, NY); Li, Ming Cheng (Cincinnati, OH); Hyde, Susan Marie (Schenectady, NY); Mashey, Thomas Charles (Coxsackie, NY); Wesorick, Ronald Richard (Albany, NY); Glynn, Christopher Charles (Hamilton, OH); Hemsworth, Martin C. (Cincinnati, OH)

2002-01-01T23:59:59.000Z

347

Air-cooled vacuum steam condenser  

SciTech Connect (OSTI)

This patent describes a steam powered system. It comprises: a turbine for converting steam energy into mechanical energy upon expansion of steam therein, a boiler for generating steam to be fed to the turbine, and a conduit arrangement coupling the boiler to the turbine and then recoupling the turbine exhaust to the boiler through steam condensing mechanisms. The condensing mechanisms including: a plurality of finned tubes through which the expanded exhaust steam flows and is condensed; a plurality of bundle from headers at the lower ends of the condensing tubes for receiving exhaust steam from the turbine; a plurality of bundle divided rear headers, one for each tube row in the bundle, at the higher ends of the condensing tubes for receiving non-condensible gases; and means in the rear and last headers to remove non-condensible gasses from the rear headers along their full length.

Larinoff, M.W.

1990-03-06T23:59:59.000Z

348

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING  

E-Print Network [OSTI]

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

349

The Effect Of ZnO Addition On Co/C Catalyst For Vapor And Aqueous Phase Reforming Of Ethanol  

SciTech Connect (OSTI)

The effect of ZnO addition on the oxidation behavior of Co along with catalytic performance in vapor and aqueous phase reforming of ethanol were investigated on Co supported on carbon black (XC-72R). Carbon was selected to minimize the support interactions. Effect of ZnO addition during both vapor and aqueous phase reforming were compared at 250 °C. ZnO addition inhibited the reduction of cobalt oxides by H2 and created surface sites for H2O activation. During vapor phase reforming at 450 °C the redox of cobalt, driven by steam oxidation and H2 reduction, trended to an equilibrium of Co0/Co2+. ZnO showed no significant effect on cobalt oxidation, inferred from the minor changes of C1 product yield. Surface sites created by ZnO addition enhanced water activation and oxidation of surface carbon species, increasing CO2 selectivity. At 250 °C cobalt reduction was minimal, in situ XANES demonstrated that ZnO addition significantly facilitated oxidation of Co0 under vapor phase reforming conditions, demonstrated by lower C1 product yield. Sites introduced by ZnO addition improved the COx selectivity at 250 °C. Both Co/C and Co-ZnO/C rapidly oxidized under aqueous phase reaction conditions at 250 °C, showing negligible activity in aqueous phase reforming. This work suggests that ZnO affects the activation of H2O for Co catalysts in ethanol reforming.

Davidson, Stephen; Sun, Junming; Hong, Yongchun; Karim, Ayman M.; Datye, Abhaya K.; Wang, Yong

2014-02-05T23:59:59.000Z

350

A new bed elevation dataset for Greenland  

E-Print Network [OSTI]

A new bed elevation dataset for Greenland J. L. Bamber 1 ,al. : A new bed elevation dataset for Greenland Howat, I. M.al. : A new bed elevation dataset for Greenland Fig. 3. (a)

2013-01-01T23:59:59.000Z

351

Coal Bed Methane Protection Act (Montana)  

Broader source: Energy.gov [DOE]

The Coal Bed Methane Protection Act establishes a long-term coal bed methane protection account and a coal bed methane protection program for the purpose of compensating private landowners and...

352

Steam Turbine Materials and Corrosion  

SciTech Connect (OSTI)

Ultra-supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760 °C. In prior years this project examined the steamside oxidation of alloys for use in high- and intermediate-pressure USC turbines. This steamside oxidation research is continuing and progress is presented, with emphasis on chromia evaporation.

Holcomb, G.H.; Hsu, D.H.

2008-07-01T23:59:59.000Z

353

Apparatus for fixed bed coal gasification  

DOE Patents [OSTI]

An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

Sadowski, Richard S. (Greenville, SC)

1992-01-01T23:59:59.000Z

354

Fluidized-bed gasification of an eastern oil shale  

SciTech Connect (OSTI)

The current conceptual HYTORT process design for the hydroretorting of oil shales employs moving-bed retorts that utilize shale particles larger than 3 mm. Work at the Institute of Gas Technology (IGT) is in progress to investigate the potential of high-temperature (1100 to 1300 K) fluidized-bed gasification of shale fines (<3 mm size) using steam and oxygen as a technique for more complete utilization of the resource. Synthesis gas produced from fines gasification can be used for making some of the hydrogen needed in the HYTORT process. After completing laboratory-scale batch and continuous gasification tests with several Eastern oil shales, two tests with Indiana New Albany shale were conducted in a 0.2 m diameter fluidized-bed gasification process development unit (PDU). A conceptual gasifier design for 95% carbon conversion was completed. Gasification of 20% of the mined shale can produce the hydrogen required by the HYTORT reactor to retort 80% of the remaining shale. 12 refs., 1 fig., 5 tabs.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1987-01-01T23:59:59.000Z

355

Hydrocarbon reforming for hydrogen fuel cells. Annual report, 1 October 1979 to 30 September 1980  

SciTech Connect (OSTI)

The mechanism of carbon formation on nickel autothermal steam reforming catalysts has been studied by temperature-programming, thermogravimetric and electron microscopic techniques. Temperature programmed surface reaction (TPSR) studies of carbon deposited on nickel reforming catalysts by the decomposition of ethylene exhibit seven forms of carbon that are distinguished by their characteristic reactivity with H/sub 2/ and 3.0 vol% H/sub 2/O/He. The relative population of the different carbon states depends primarily on the temperature during deposition. The reactivity of the carbon states are not altered by exposure to steam in C/sub 2/H/sub 4/-H/sub 2/O mixtures, but the amount of carbon deposited decreases to zero as the H/sub 2/O/C increases past a critical ratio. Critical steam-to-carbon ratios have been measured in the presence of C/sub 2/H/sub 4/-H/sub 2/O mixtures so as to establish the carbon formation boundary for several alumina-supported nickel, Ni-Rh, and Ni-Ir alloy catalysts. The critical H/sub 2/O/C ratio measured with a gravimetric balance decreased from approx. 30 at 773/sup 0/K to approx. 1 at 1073/sup 0/K for all the catalysts studied. The very rapid rate of C/sub 2/H/sub 4/ reforming over this temperature range caused mass transport gradients, which in turn lowered the apparent critical H/sub 2/O/C ratios. Carbon deposited on a 17 wt% Ni/Al/sub 2/O/sub 3/ catalyst at 875/sup 0/K and 1073/sup 0/K was examined by transmission (TEM) and scanning (SEM) electron microscopy. Results are reported and discussed.

Hart, C.; Hou, P.Y.; Laine, R.M.; McCarty, J.G.; Sheridan, D.; Wise, H.; Wood, B.J.

1981-01-30T23:59:59.000Z

356

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the seventh report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 31, 2005. This quarter saw progress in these areas. These areas are: (1) Steam reformer transient response, (2) Heat transfer enhancement, (3) Catalyst degradation, (4) Catalyst degradation with bluff bodies, and (5) Autothermal reforming of coal-derived methanol. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2005-06-30T23:59:59.000Z

357

Development of a catalytic partial oxidation ethanol reformer for fuel cell applications  

SciTech Connect (OSTI)

Arthur D. Little in conjunction with the Department of Energy and the Illinois Department of Commerce and Community Affairs are developing an ethanol fuel processor for fuel cell vehicles. Initial studies were carried out on a 25 kWe catalytic partial oxidation (POX) reformer to determine the effect of equivalence ratio, steam to carbon ratio, and residence time on ethanol conversion. Results of the POX experiments show near equilibrium yields of hydrogen and carbon monoxide for an equivalence ratio of 3.0 with a fuel processor efficiency of 80%. The size and weight of the prototype reformer yield power densities of 1.44 l/kW and 1.74 kg/kW at an estimated cost of $20/kW.

Mitchell, W.L.; Thijssen, J.H.J.; Bentley, J.M.; Marek, N.J.

1995-12-31T23:59:59.000Z

358

Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam  

SciTech Connect (OSTI)

This revised ITP tip sheet on steam jet ejectors and thermocompressors provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-01-01T23:59:59.000Z

359

Identifying Steam Opportunity "Impact" Inputs for the Steam System Assessment Tool (SSAT)  

E-Print Network [OSTI]

IDENTIFYING STEAM OPPORTUNITY "IMPACT" INPUTS FOR THE STEAM SYSTEM ASSESSMENT TOOL (SSAT) Dr. Greg Harrell, University of Tennessee/Knoxville Dr. Richard Jendrucko, University of Tennessee/Knoxville Dr. Anthony Wright, Oak Ridge National...

Harrell, G.; Jendrucko, R.; Wright, A.

2004-01-01T23:59:59.000Z

360

The Steam System Assessment Tool (SSAT): Estimating Steam System Energy, Cost, and Emission Savings  

E-Print Network [OSTI]

The U. S. Department of Energy's (DOE) Industrial Technology Program BestPractices Steam effort is developing a number of software tools to assist industrial energy users to improve the efficiency of their steam system. A major new Best...

Wright, A.; Bealing, C.; Eastwood, A.; Tainsh, R.; Hahn, G.; Harrell, G.

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Energy Savings Through Steam Trap Management  

E-Print Network [OSTI]

Energy Savings through Steam Trap Management Chris Gibbs, Account Manager, Armstrong International, Inc., Three Rivers, MI ESL-IE-08-05-08 Proceedings from theThirtieth Industrial Energy Technology Conference...-based steam trap management application developed by Armstrong International. The application calculates steam loss, fuel loss, dollar loss and CO 2 emission generation. The database allows for trend analysis, automatic energy report generation...

Gibbs, C.

2008-01-01T23:59:59.000Z

362

Electrical Cost Reduction Via Steam Turbine Cogeneration  

E-Print Network [OSTI]

ELECTRICAL COST REDUCTION VIA STEAM TURBINE COGENERATION LYNN B. DI TULLIO, P.E. Project Engineer Ewing Power Systems, Inc. South Deerfield, Mass. ABSTRACT Steam turbine cogeneration is a well established technology which is widely used... mature technology. Steam turbines and engines have been used by industry to cogen erate power since before there were electric utilities. While the technology for turbines, generators and controls has continued to develop there is very little about...

Ewing, T. S.; Di Tullio, L. B.

363

Reduce Steam Trap Failures at Chambers Works  

E-Print Network [OSTI]

Ultrasonic Inspection At least 2 times per year Steam Trap Surveyor Submit reports to area management, energy team, and reliability engineers for each area every month Steam Trap Team Leader Control Plan ? Process Owner agrees...Reduce Steam Trap Failures at Chambers Works GB/BB Name: Cyndi Kouba Mentor/MBB: Andrew Degraff Team Members Michael Crowley(Site Energy Lead), (Charlie) Flanigan (Aramids-maintenance), Ben Snyder (Aramids-ATO), Michael Scruggs (Central...

Kouba, C.

364

World launch! Hot-Steam Aerostat  

E-Print Network [OSTI]

Info HeiDAS UH World launch! Hot-Steam Aerostat #12;"If you intend to view the land, if you plan Verne: "Fife weeks on a balloon". HeiDAS stands for HeiÃ?DampfAeroStat (Hot-Steam AeroStat) and it refers to the first operable balloon ever that became buoyant by means of superheated steam. The performance of Hei

Berlin,Technische Universität

365

Proceedings of design, repair, and refurbishment of steam turbines  

SciTech Connect (OSTI)

This book reports on the proceedings of design, repair and refurbishment of steam engines. Topics covered include: Advisor/Expert Systems for Steam Turbines; Moisture Effects on the Operating and Performance of Steam Turbines; Turbine Steam Path Development; Repair and Refurbishment of the Electric Generator Components; and Advanced Steam Turbine Designs.

Warnock, A.S. (Lehigh Univ., PA (United States))

1991-01-01T23:59:59.000Z

366

Industrial Heat Pumps for Steam and Fuel Savings: A BestPractices Steam Technical Brief  

SciTech Connect (OSTI)

The purpose of this Steam Techcial Brief is to introduce heat-pump technology and its applicaiton in industrial processes.

Not Available

2003-06-01T23:59:59.000Z

367

Efficiently generate steam from cogeneration plants  

SciTech Connect (OSTI)

As cogeneration gets more popular, some plants have two choices of equipment for generating steam. Plant engineers need to have a decision chart to split the duty efficiently between (oil-fired or gas-fired) steam generators (SGs) and heat recovery steam generators (HRSGs) using the exhaust from gas turbines. Underlying the dilemma is that the load-versus-efficiency characteristics of both types of equipment are different. When the limitations of each type of equipment and its capability are considered, analysis can come up with several selection possibilities. It is almost always more efficient to generate steam in an HRSG (designed for firing) as compared with conventional steam generators. However, other aspects, such as maintenance, availability of personnel, equipment limitations and operating costs, should also be considered before making a final decision. Loading each type of equipment differently also affects the overall efficiency or the fuel consumption. This article describes the performance aspects of representative steam generators and gas turbine HRSGs and suggests how plant engineers can generate steam efficiently. It also illustrates how to construct a decision chart for a typical installation. The equipment was picked arbitrarily to show the method. The natural gas fired steam generator has a maximum capacity of 100,000 lb/h, 400-psig saturated steam, and the gas-turbine-exhaust HRSG has the same capacity. It is designed for supplementary firing with natural gas.

Ganapathy, V. [ABCO Industries, Abilene, TX (United States)

1997-05-01T23:59:59.000Z

368

Covered Product Category: Commercial Steam Cookers  

Broader source: Energy.gov [DOE]

The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial steam cookers, which are covered by the ENERGY STAR program.

369

Save Energy Now in Your Steam Systems  

SciTech Connect (OSTI)

This DOE Industrial Technologies Program fact sheet describes how manufacturing plants can save energy and money by making energy efficiency improvements to their industrial steam systems.

Not Available

2006-01-01T23:59:59.000Z

370

DOE's BestPractices Steam End User Training Steam End User Training  

E-Print Network [OSTI]

DOE's BestPractices Steam End User Training Steam End User Training Conclusion Module 1 June 28, 2010 Steam EndUser Training Conclusion Module Slide 1 Conclusions Let's briefly examine the major items we have covered in this training. [Slide Visual ­ Contents of Module Sections

Oak Ridge National Laboratory

371

Steam catalysis in CaO carbonation under low steam partial pressure  

SciTech Connect (OSTI)

CaO was widely used to capture CO{sub 2} in direct hydrogen production process, where steam always existed simultaneously. The effect of steam on CaO carbonation performance under low steam partial pressure was investigated using a pressurized thermogravimetric apparatus. The experimental results revealed that steam improved CaO carbonation performance significantly no matter whether Ca(OH){sub 2} was produced or not. At 823 K and 0.5 MPa of steam partial pressure, effect of steam on CaO carbonation performance could not be attributed mainly to production of Ca(OH){sub 2} because the hydration rate of CaO was very slow. The main reason was steam catalysis in CaO carbonation. Enhancement of steam on CaO carbonation performance without Ca(OH){sub 2} production could not be attributed to improvement of steam on the physical property, but to catalytic effect of steam. Effects of CaO precursors, CO{sub 2} partial pressure, steam partial pressure, and temperature with steam addition on CaO carbonation performance were also investigated.

Yang, S.J.; Xiao, Y.H. [Chinese Academy of Science, Beijing (China)

2008-06-15T23:59:59.000Z

372

Fluidized bed controls refinery emissions  

SciTech Connect (OSTI)

In early 1983, two fluidized bed, waste heat boilers entered into service at the Ashland Petroleum Company refinery site in Ashland, Kentucky. These fluidized bed units are coupled to the regeneration end of a newly developed reduced crude conversion (RCC) process and served the purpose of reducing CO, SO/sub 2/ and NO/sub x/ emissions while recuperating waste heat from the regenerator process off gases.

Abdulally, I.F.; Kersey, B.R.

1986-05-01T23:59:59.000Z

373

Geismar TDI Plant Steam Optimization  

E-Print Network [OSTI]

BASF North America 7 ESL-IE-13-05-19 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New Orleans, LA. May 21-24, 2013 BASF?s strategic principles A conscientious commitment to our investors, customers, employees...Geismar TDI Plant Steam Optimization May 23rd, 2013 IET Conference Meredith Bailey, PDP Engineer BASF Corporation (734) 324-5047 meredith.bailey@basf.com ESL-IE-13-05-19 Proceedings of the Thrity-Fifth Industrial Energy Technology...

Baily, M.

2013-01-01T23:59:59.000Z

374

Designing an ultrasupercritical steam turbine  

SciTech Connect (OSTI)

Carbon emissions produced by the combustion of coal may be collected and stored in the future, but a better approach is to reduce the carbon produced through efficient combustion technologies. Increasing the efficiency of new plants using ultrasupercritical (USC) technology will net less carbon released per megawatt-hour using the world's abundant coal reserves while producing electricity at the lowest possible cost. The article shows how increasing the steam turbine operating conditions for a new USC project in the USA and quantify the potential CO{sub 2} reduction this advanced design makes possible. 7 figs., 3 tabs.

Klotz, H.; Davis, K.; Pickering, E. [Alstom (Germany)

2009-07-15T23:59:59.000Z

375

Steam Systems | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: AlternativeEnvironment,Institutes and1 Special Report: OAS-RA-14-01AwardsStateStatesAboutSteam

376

Steam Coal Import Costs - EIA  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael Schaal Director, Oil and10:InformationSteam Coal Import

377

Pressure Drop in a Pebble Bed Reactor  

E-Print Network [OSTI]

Pressure drops over a packed bed of pebble bed reactor type are investigated. Measurement of porosity and pressure drop over the bed were carried out in a cylindrical packed bed facility. Air and water were used for working fluids. There are several...

Kang, Changwoo

2011-10-21T23:59:59.000Z

378

A study of cellulose gasification in a fluidized bed using a high-temperature solar furnace  

SciTech Connect (OSTI)

A 4.2-meter solar furnace was used to study the gasification of cellulose with steam in a fluidized bed. The heating value of the high-temperature equilibrium products is about twenty percent higher than that of the reactants. The increase represents stored solar energy; and the product, synthesis gas, is valuable as a chemical feedstock or pipeline gas. All experiments were performed at atmospheric pressure. Pure tabular alumina as well as crushed automotive exhaust was used as a bed material. Microcrystalline {alpha}-cellulose, entrained in argon, entered the fluidized bed just above the distributor. Steam heated to the operating temperature in a 10 cm packed bed section below the fluidized bed. In all cases, the process ran with more steam than required to produce an equimolar mixture of carbon monoxide and hydrogen. We used a quartz reactor between 1100 and 1430 K; a steel reactor at 1500 K and an Inconel reactor at 1600 K. Reactor inside diameter, nominally 5 cm, varied slightly; the bed height was adjusted to keep the gas residence time constant. Hydrogen production rate was measured before and after experiments with steam alone, with this amount subtracted. Equilibrium mixtures were not achieved. Catalysts improved hydrogen yields with higher than expected concentrations of carbon monoxide, methane and lighter hydrocarbons such as ethylene and acetylene. Experiments performed without catalyst at 1300 K, achieved a mixture (dry, argon-free) of 46 mole% CO, 30% H{sub 2} 14% CH{sub 4} 5% CO{sub 2} and 5% C{sub 2}H{sub 4}. An equilibrium mixture at this temperature would have contained 39% CO, 30% H{sub 2} 7% CO{sub 2} and no CH{sub 4} or C{sub 2}H{sub 4}. With the catalyst, the CO and CH{sub 4} decreased to 40% and 2% respectively, the H{sub 2} increased to 47%, and CO{sub 2} remained the same. No ethylene was formed. The hydrocarbon-rich mixtures achieved are typical of rapid-pyrolysis processes.

Murray, J.P.

1989-01-01T23:59:59.000Z

379

Plasma-catalyzed fuel reformer  

DOE Patents [OSTI]

A reformer is disclosed that includes a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto. A first thermally conductive surface surrounds the plasma zone and is configured to transfer heat from an external heat source into the plasma zone. The reformer further includes a reaction zone to chemically transform the ionized reactants into synthesis gas comprising hydrogen and carbon monoxide. A second thermally conductive surface surrounds the reaction zone and is configured to transfer heat from the external heat source into the reaction zone. The first thermally conductive surface and second thermally conductive surface are both directly exposed to the external heat source. A corresponding method and system are also disclosed and claimed herein.

Hartvigsen, Joseph J.; Elangovan, S.; Czernichowski, Piotr; Hollist, Michele

2013-06-11T23:59:59.000Z

380

Stream-bed scour, egg burial depths, and the influence of salmonid spawning on bed surface  

E-Print Network [OSTI]

Stream-bed scour, egg burial depths, and the influence of salmonid spawning on bed surface mobility-Hames, and Thomas P. Quinn Abstract: Bed scour, egg pocket depths, and alteration of stream-bed surfaces by spawning chum salmon (Onchorhynchus keta) were measured in two Pacific Northwest gravel-bedded streams. Close

Montgomery, David R.

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Effective Steam Trap Selection/Maintenance - Its Payback  

E-Print Network [OSTI]

In oil refineries and petrochemical plants large number of steam traps are used to discharge condensate from steam mains, tracers and process equipment. Early efforts on steam traps focused almost exclusively on their selection and sizing...

Garcia, E.

1984-01-01T23:59:59.000Z

382

Preliminary Results from the Industrial Steam System Market Assessment  

E-Print Network [OSTI]

This paper discusses fuel use and potential energy savings in the steam systems of three steam intensive industries: pulp and paper, chemical manufacturing, and petroleum refining. To determine the energy consumption to generate steam...

McGrath, G. P.; Wright, A. L.

383

Steam turbine materials and corrosion  

SciTech Connect (OSTI)

Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760°C. This research examines the steamside oxidation of alloys for use in USC systems, with emphasis placed on applications in high- and intermediate-pressure turbines. The list of alloys being examined is discussed, including the addition of new alloys to the study. These include alloy 625, selected because of its use as one of the two alloys used for turbine rotors, valves, casings, blading and bolts in the European AD700 full-scale demonstration plant (Scholven Unit F). The other alloy, alloy 617, is already one of the alloys currently being examined by this project. Other new alloys to the study are the three round robin alloys in the UK-US collaboration: alloys 740, TP347HFG, and T92. Progress on the project is presented on cyclic oxidation in 50% air – 50% water vapor, furnace exposures in moist air, and thermogravimetric analysis in argon with oxygen saturated steam. An update on the progress towards obtaining an apparatus for high pressure exposures is given.

Holcomb, G.R.; Ziomek-Moroz, M.

2007-01-01T23:59:59.000Z

384

Energy Management - Using Steam Pressure Efficiently  

E-Print Network [OSTI]

Saturated steam contains heat in two different forms. Sensible heat and latent heat. Due to the nature of this vapor, the relative proportion of latent heat is higher at lower pressures compared to higher pressures. When steam is used for heating...

Jiandani, N.

1983-01-01T23:59:59.000Z

385

Steam System Optimization: A Case Study  

E-Print Network [OSTI]

This paper highlights the study findings in a steam system in a plant from a multinational Petrochemical giant in an European country. The steam system operates with an annual budget of $8.9 million (local currency was converted to US Dollars...

Iordanova, N.; Venkatesan, V. V.

386

Optimized Control Of Steam Heating Coils  

E-Print Network [OSTI]

............................................................................................... 7 2.4 Summary of Literature Review .................................................................... 8 2.5 Significance of the Study ............................................................................. 9 2.6 Limitations... .................................................................. 25 Figure 8: Integrated Face/Bypass Damper Arrangement (Owen, 2005)..................... 26 Figure 9: Schematic of Specimen AHU and its Steam Supply, Alexandria, LA ........ 32 Figure 10: Preheat Temperature Plot for Steam Pressure...

Ali, Mir Muddassir

2012-02-14T23:59:59.000Z

387

Email To Friend Steam Electricity Generator  

E-Print Network [OSTI]

. keymanengravables.com Steam Turbine Generator Info, Pictures And Deals For Steam turbine generator ediscountshopping can make electricity directly." Logan's process uses a microbial fuel cell to convert organic material - that consume the sugars and other organic material and release electrons. These electrons travel to the anode

388

Circumferential cracking of steam generator tubes  

SciTech Connect (OSTI)

On April 28, 1995, the U.S. Nuclear Regulatory Commission (NRC) issued Generic Letter (GL) 95-03, {open_quote}Circumferential Cracking of Steam Generator Tubes.{close_quote} GL 95-03 was issued to obtain information needed to verify licensee compliance with existing regulatory requirements regarding the integrity of steam generator tubes in domestic pressurized-water reactors (PWRs). This report briefly describes the design and function of domestic steam generators and summarizes the staff`s assessment of the responses to GL 95-03. The report concludes with several observations related to steam generator operating experience. This report is intended to be representative of significant operating experience pertaining to circumferential cracking of steam generator tubes from April 1995 through December 1996. Operating experience prior to April 1995 is discussed throughout the report, as necessary, for completeness.

Karwoski, K.J.

1997-04-01T23:59:59.000Z

389

DOEEA-1178 Assessment 300 Area Steam Plant Replacement, Hanford...  

Broader source: Energy.gov (indexed) [DOE]

facilities would not be achieved. 5.3.4 Upgrade Central Steam System Impacts from upgrading the central steam system would include a reduction in the operational costs...

390

Recent Progress on Steam Hydrogasification of Carbonaceous Matter...  

Broader source: Energy.gov (indexed) [DOE]

Recent Progress on Steam Hydrogasification of Carbonaceous Matter to Clean Synthetic Diesel Fuel Recent Progress on Steam Hydrogasification of Carbonaceous Matter to Clean...

391

Improving Steam System Performance: A Sourcebook for Industry...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Improving Steam System Performance: A Sourcebook for Industry, Second Edition Improving Steam System Performance: A Sourcebook for Industry, Second Edition This sourcebook is...

392

Dow Chemical Company: Assessment Leads to Steam System Energy...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a Petrochemical Plant Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a...

393

Steam System Efficiency Optimized After J.R. Simplot Fertilizer...  

Broader source: Energy.gov (indexed) [DOE]

Steam System Efficiency Optimized After J.R. Simplot Fertilizer Plant Receives Energy Assessment Steam System Efficiency Optimized After J.R. Simplot Fertilizer Plant Receives...

394

Lessons Learned from Prior Attempts at National Security Reform The Project on National Security Reform  

E-Print Network [OSTI]

Lessons Learned from Prior Attempts at National Security Reform The Project on National Security was their solution effective? 4. What implications for present-day reformers can be drawn from this reform? Lessons learned from each chapter are summarized at the end of each section, and a synthesis of these findings

Lewis, Robert Michael

395

Hydrogen from Biomass by Autothermal Reforming  

Broader source: Energy.gov [DOE]

Presentation by Lanny D. Schmidt at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

396

Distributed Bio-Oil Reforming (Presentation)  

SciTech Connect (OSTI)

This presentation by Bob Evans at the 2007 DOE Hydrogen Program Annual Merit Review Meeting provides information about NREL's distributed bio-oil reforming efforts.

Evans, R. J.; Czernik, S.; French, R.; Ratcliff, M.; Marda, J.; Dean, A. M.

2007-05-15T23:59:59.000Z

397

High Efficiency Solar-based Catalytic Structure for CO{sub 2} Reforming  

SciTech Connect (OSTI)

Throughout this project, we developed and optimized various photocatalyst structures for CO{sub 2} reforming into hydrocarbon fuels and various commodity chemical products. We also built several closed-loop and continuous fixed-bed photocatalytic reactor system prototypes for a larger-scale demonstration of CO{sub 2} reforming into hydrocarbons, mainly methane and formic acid. The results achieved have indicated that with each type of reactor and structure, high reforming yields can be obtained by refining the structural and operational conditions of the reactor, as well as by using various sacrificial agents (hole scavengers). We have also demonstrated, for the first time, that an aqueous solution containing acid whey (a common bio waste) is a highly effective hole scavenger for a solar-based photocatalytic reactor system and can help reform CO{sub 2} into several products at once. The optimization tasks performed throughout the project have resulted in efficiency increase in our conventional reactors from an initial 0.02% to about 0.25%, which is 10X higher than our original project goal. When acid whey was used as a sacrificial agent, the achieved energy efficiency for formic acid alone was ~0.4%, which is 16X that of our original project goal and higher than anything ever reported for a solar-based photocatalytic reactor. Therefore, by carefully selecting sacrificial agents, it should be possible to reach energy efficiency in the range of the photosynthetic efficiency of typical crop and biofuel plants (1-3%).

Menkara, Hisham

2013-09-30T23:59:59.000Z

398

Comparative case studies of health reform in England  

E-Print Network [OSTI]

Comparative case studies of health reform in England Report submitted to the Department of Health........................................................................................14 1.1 Presenting the Health System Reform policy agenda...................................14 1 ..........................................................................................64 Demand Side Reform.........................................

Birmingham, University of

399

Supported Single Pt1/Au1 Atoms for Methanol Steam Reforming Xiang-Kui Gu,,  

E-Print Network [OSTI]

, responsible for the low-temperature activity of the water-gas-shift reaction10,11 and CO oxidation,12,13 can more strongly toward the inter- mediates, improve the reaction energetics and kinetics, and change

Li, Weixue

400

Artificial neural networks assisted catalyst design and optimisation of methane steam reforming.  

E-Print Network [OSTI]

??Hydrogen has diverse industrial applications namely in ammonia synthesis, petroleum refining and methanol production. The advent of fuel cell technology had prompted hydrogen as an… (more)

Arcotumapathy, Viswanathan

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

A Comparative Study between Co and Rh for Steam Reforming of Ethanol. |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011 Mon,Electrocatalysis | StanfordZeise'sEMSL

402

Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe10 DOE VehicleStationary FuelPresentation from the

403

BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd: Scope ChangeL-01-06Hot-Humid Climate:BEopt Version

404

Modeling the Effects of Steam-Fuel Reforming Products on Low Temperature  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F S i DOE TribaltheMyMinutes fromBased| DepartmentCombustion of

405

Ceramic microreactors for on-site hydrogen production from high temperature steam reforming of propane{  

E-Print Network [OSTI]

of propane{ Christian, Michael Mitchell and Paul J. A. Kenis* Received 31st May 2006, Accepted 10th August of propane into hydrogen at temperatures between 800 and 1000 uC. We characterized these microreactors. Kinetic analysis using a power law model showed reaction orders of 0.50 and 20.23 with respect to propane

Kenis, Paul J. A.

406

Design, Modeling, and Validation of a Flame Reformer for LNT...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration...

407

Regulatory and Financial Reform of Federal Research Policy: Recommenda...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities Regulatory and Financial Reform of Federal Research Policy:...

408

Secretary Moniz to Present Project Management Reforms to the...  

Energy Savers [EERE]

Moniz to Present Project Management Reforms to the National Academy of Public Administration Secretary Moniz to Present Project Management Reforms to the National Academy of Public...

409

Hydrogen generation from plasmatron reformers and use for diesel...  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment 2003...

410

Steam turbine upgrades: A utility based approach  

SciTech Connect (OSTI)

In the increasingly competitive power generation markets utilities must strive towards lower electricity generation costs, whilst relying on an aging steam turbine fleet. By the year 2000 more than 25% of the global steam turbine capacity will be older than 30 years. The heat rate of such units is generally considerably higher than that of equivalent new plant, and such equipment can be further disadvantaged by increased maintenance costs and forced outage rates. Over the past decade steam turbine conversion, modification, and upgrade packages have become an increasingly important part of the European steam turbine market. Furthermore, many utilities now realize that enhanced cost-effectiveness can often be obtained by moving away from the original equipment manufacturer (OEM), and the upgrading of other manufacturers' plant is now routine within the steam turbine industry. By working closely with customers, GE has developed a comprehensive range of steam turbine upgrade packages, including advanced design steampaths which can increase the performance of existing turbine installations to levels comparable with new plant. Such packages are tailor-made to the requirements of each customer, to ensure that the most cost-effective engineering solution is identified. This paper presents an overview of GE's state-of-the-art steam turbine technology, and continues to describe typical economic models for turbine upgrades.

Wakeley, G.R.

1998-07-01T23:59:59.000Z

411

Enabling Informed Adaptation of Reformed Instructional Materials  

E-Print Network [OSTI]

Enabling Informed Adaptation of Reformed Instructional Materials Rachel E. Scherr and Andrew Elby 20742 USA Abstract. Instructors inevitably need to adapt even the best reform materials to suit instructors, and video clips of students working on the materials. Our materials thus facilitate their own

Elby, Andy

412

Reformate Cleanup: The Case for Microchannel Architecture  

E-Print Network [OSTI]

Reformate Cleanup: The Case for Microchannel Architecture DOE Hydrogen and Fuel Cells 2003 Annual for MicrochannelMicrochannel ArchitectureArchitecture DOE Hydrogen and Fuel CellsDOE Hydrogen and Fuel Cells 2003, controls Integrated reformer/fuel cell demonstration at ~2 kWeFY 2002 WGS/PROX catalyst studies

413

Investigation of Gas Solid Fluidized Bed Dynamics with Non-Spherical Particles  

SciTech Connect (OSTI)

One of the largest challenges for 21st century is to fulfill global energy demand while also reducing detrimental impacts of energy generation and use on the environment. Gasification is a promising technology to meet the requirement of reduced emissions without compromising performance. Coal gasification is not an incinerating process; rather than burning coal completely a partial combustion takes place in the presence of steam and limited amounts of oxygen. In this controlled environment, a chemical reaction takes place to produce a mixture of clean synthetic gas. Gas-solid fluidized bed is one such type of gasification technology. During gasification, the mixing behavior of solid (coal) and gas and their flow patterns can be very complicated to understand. Many attempts have taken place in laboratory scale to understand bed hydrodynamics with spherical particles though in actual applications with coal, the particles are non-spherical. This issue drove the documented attempt presented here to investigate fluidized bed behavior using different ranges of non-spherical particles, as well as spherical. For this investigation, various parameters are controlled that included particle size, bed height, bed diameter and particle shape. Particles ranged from 355 µm to 1180 µm, bed diameter varied from 2 cm to 7 cm, two fluidized beds with diameters of 3.4 cm and 12.4 cm, for the spherical and non-spherical shaped particles that were taken into consideration. Pressure drop was measured with increasing superficial gas velocity. The velocity required in order to start to fluidize the particle is called the minimum fluidization velocity, which is one of the most important parameters to design and optimize within a gas-solid fluidized bed. This minimum fluidization velocity was monitored during investigation while observing variables factors and their effect on this velocity. From our investigation, it has been found that minimum fluidization velocity is independent of bed height for both spherical and non-spherical particles. Further, it decrease with decreasing particle size and decreases with decreasing bed diameter. Shadow sizing, a non-intrusive imaging and diagnostic technology, was also used to visualize flow fields inside fluidized beds for both spherical and non- spherical particles and to detect the particle sizes.

Choudhuri, Ahsan

2013-06-30T23:59:59.000Z

414

Economic Analysis of "Steam-Shock" and "Pasteurization"  

E-Print Network [OSTI]

Economic Analysis of "Steam-Shock" and "Pasteurization" Processes for Oyster Shucking JOHN W. BROWN Introduction "Steam-shock" is an oyster shucking process that uses steam to relax the oyster's adductor muscle of the shucking process as in integral part of the operation of an existing oyster-shucking house. The term "steam

415

A new bed elevation dataset for Greenland  

E-Print Network [OSTI]

and bed data set for the Greenland ice sheet 1. Measure-bed elevation dataset for Greenland J. L. Bamber 1 , J. A.face mass balance of the Greenland ice sheet revealed by

2013-01-01T23:59:59.000Z

416

State of Fluidized Bed Combustion Technology  

E-Print Network [OSTI]

directly in fluidized beds while taking advantage of low furnace temperatures and chemical activity within the bed to limit SO2 and NOx emissions, thereby eliminating the need for stack gas scrubbing equipment. The excellent heat transfer characteristics...

Pope, M.

1979-01-01T23:59:59.000Z

417

The Enbridge "Steam Saver" Program: Steam Boiler Plant Efficiency-Update to Year End 2005  

E-Print Network [OSTI]

industrial sectors are represented. The automotive, pulp-and -paper, petrochemical and steel industries are particularly large energy and steam users. Food and beverage processors are also heavy steam consumers. The Enbridge franchise service area... summary of the results of the boiler plant audit program. This data excludes other programs such as steam trap surveys and insulation surveys to be presented later in this paper. In summary, 13.7% of the total fuel can be saved if all identified...

Griffin, B.; Johnson, D.

2006-01-01T23:59:59.000Z

418

Fluidized bed steam reactor including two horizontal cyclone separators and an integral recycle heat exchanger  

SciTech Connect (OSTI)

A reactor is described comprising: a vessel; a first furnace section disposed in said vessel; a second furnace section disposed in said vessel; means in each of said furnace sections for receiving a combustible fuel for generating heat and combustion gases; a first heat recovery area located adjacent said furnace sections; a second heat recovery area located adjacent said furnace sections; means for passing said combustion gases from said first furnace section to said first heat recovery area; and means for passing said combustion gases from said second furnace section to said second heat recovery area.

Gorzegno, W.P.

1993-06-15T23:59:59.000Z

419

The revolutionary impact of the steam engine  

E-Print Network [OSTI]

Sitting with a model of Stephenson’s Rocket, Simon Schaffer reflects on the steam revolution and how it changed the world in the nineteenth century in so many different ways....

Dugan, David

2004-08-18T23:59:59.000Z

420

How did the Rocket steam engine work?  

E-Print Network [OSTI]

Simon Schaffer talks to a museum curator at the York railway museum about the way in which steam engines worked and the imagination and technical ability of George Stephenson....

Dugan, David

2004-08-17T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Steam Management- The 3M Approach  

E-Print Network [OSTI]

As one of the world's leading manufacturers of innovative products, 3M is continually working to improve energy efficiency in offices, research centers, and production facilities. Steam system optimization is one of the keys to this process...

Renz, R. L.

422

Optimizing Steam & Condensate System: A Case Study  

E-Print Network [OSTI]

Optimization of Steam & Condensate systems in any process plant results in substantial reduction of purchased energy cost. During periods of natural gas price hikes, this would benefit the plant in controlling their fuel budget significantly...

Venkatesan, V. V.; Norris, C.

2011-01-01T23:59:59.000Z

423

Steam System Optimization : A Case Study  

E-Print Network [OSTI]

The steam system optimization (generation, distribution, use and condensate return) offers a large opportunity for action to comply with the new levels of energy efficiency standards. Superior design and improved maintenance practices are the two...

Iordanova, N.; Venkatesan, V. V.; Calogero, M.

424

Smokeless Control of Flare Steam Flow Rate  

E-Print Network [OSTI]

measurement of mass flow rate of flare gas, in spite of the hostile environment. Its use for initiating control of flare steam flow rate and the addition of molecular weight compensation, using specific gravity (relative density) measurement to achieve...

Agar, J.; Balls, B. W.

1979-01-01T23:59:59.000Z

425

Cogeneration: An Industrial Steam and Power Option  

E-Print Network [OSTI]

Industrial facilities of all sizes have the ability to reduce and better control both power and steam costs with a cogeneration system. Unlike the larger systems that sell almost all of the cogenerated power to a regulated electric utility...

Orlando, J. A.; Stewart, M. M.; Roberts, J. R.

426

Compressor & Steam Turbine Efficiency Improvements & Revamping Opportunities  

E-Print Network [OSTI]

in which they operate. This energy growth requires high efficiency improvements for machine design and operation to minimize life cycle cost. This paper will focus on the mechanical drive steam turbines which power the main process equipment in the heart...

Hata, S.; Horiba, J.; Sicker, M.

2011-01-01T23:59:59.000Z

427

Extraction Steam Controls at EPLA-W  

E-Print Network [OSTI]

ExxonMobil's Baton Rouge site encompasses a world-scale refinery, chemical plant and third party power station. Historically, inflexible and unreliable control systems on two high-pressure, extracting/condensing steam turbines prevented the site...

Brinker, J. L.

2004-01-01T23:59:59.000Z

428

Solar steam generation by heat localization  

E-Print Network [OSTI]

Currently, steam generation using solar energy is based on heating bulk liquid to high temperatures. This approach requires either costly high optical concentrations leading to heat loss by the hot bulk liquid and heated ...

Ghasemi, Hadi

429

Steam turbine upgrading: low-hanging fruit  

SciTech Connect (OSTI)

The thermodynamic performance of the steam turbine, more than any other plant component, determines overall plant efficiency. Upgrading steam path components and using computerized design tools and manufacturing techniques to minimise internal leaks are two ways to give tired steam turbines a new lease on life. The article presents three case studies that illustrate how to do that. These are at Unit 1 of Dairyland's J.P. Madgett Station in Alma, WI, a coal-fired subcritical steam plant; the four units at AmerenUE's 600 MW coal-fired Labadie plant west of St. Louis; and Unit 3 of KeyPlan Corp's Northport Power Station on Long Island. 8 figs.

Peltier, R.

2006-04-15T23:59:59.000Z

430

Consider Steam Turbine Drives for Rotating Equipment  

SciTech Connect (OSTI)

This revised ITP tip sheet on steam turbine drives for rotating equipment provides how-to advice for improving the system using low-cost, proven practices and technologies.

Not Available

2006-01-01T23:59:59.000Z

431

Savings in Steam Systems (A Case Study)  

E-Print Network [OSTI]

Savings in Steam Systems (A Case Study) Rich DeBat Steam Systems Engineer Armstrong Service, Inc. Three Rivers, MI ABSTRACT Armstrong Service Inc. (ASI) conducted an engineered evaluation at an Ammonium Nitrate Manufacturing facility during... existing burner system after refractory repair and continue with normal operation of the existing boiler. Annstrong Service cannot guarantee any aspect of this option. Option 2. Armstrong Service, Inc. proposes to evaluate, select and install a...

DeBat, R.

432

World Class Boilers and Steam Distribution System  

E-Print Network [OSTI]

WORLD CLASS BOILERS AND STEAM DISTRIBUTION SYSTEM Vernon P. Portell, Ph.D. Manager Armstrong Service, Inc. ABSTRACT categorizing, measuring, and comparing subjects which are of interest to us is the way we identify the "World class" is a... of information can also be obtained through an independent firm that provides third-party assessment of steam systems. One of these third parties, Armstrong Energy Certification, Inc., has used data gleaned from decades of industrial experience...

Portell, V. P.

433

Cheng Cycle Brings Flexibility to Steam Plant  

E-Print Network [OSTI]

. Based upon an estimated steam load between 5,000 and 50,000 Ibjhr and an electrical load of approximately 1500 KW, the Engineering Department examined several energy optimization systems for this site. It was determined that a modified gas turbine... within the borders allows exact tracking of desired electrical and thermal outputs. The Allison engine used in the Cheng Cycle system was selected for its proved performance and its ample surge margin which permits stable steam injection...

Keller, D. C.; Bynum, D.; Kosla, L.

434

Control system for fluid heated steam generator  

DOE Patents [OSTI]

A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

Boland, J.F.; Koenig, J.F.

1984-05-29T23:59:59.000Z

435

Oxidation of advanced steam turbine alloys  

SciTech Connect (OSTI)

Advanced or ultra supercritical (USC) steam power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760°C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections.

Holcomb, G.R.; Covino, B.S., Jr.; Bullard, S.J.; Ziomek-Moroz, M.

2006-03-01T23:59:59.000Z

436

Best Management Practices for Bedding and  

E-Print Network [OSTI]

1 Best Management Practices for Bedding and Container Color Plant Production in California #12 in California Bedding and Container Color Plant Production 5 Best Management Practices for Disease Prevention 16 Best Management Practices For Insect And Mite Prevention 19 Impact of Common Bedding And Container

Ferrara, Katherine W.

437

Fluidization quality analyzer for fluidized beds  

DOE Patents [OSTI]

A control loop and fluidization quality analyzer for a fluidized bed utilizes time varying pressure drop measurements. A fast-response pressure transducer measures the overall bed pressure drop, or over some segment of the bed, and the pressure drop signal is processed to produce an output voltage which changes with the degree of fluidization turbulence.

Daw, C. Stuart (Knoxville, TN); Hawk, James A. (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

438

ExxonMobile Beaumont Chemical Plant Steam Integration Project  

E-Print Network [OSTI]

? Conventional boilers ? Gas turbine generators/ heat recovery steam generators ? Waste heat recovery boilers ? Steam is distributed and consumed at multiple locations and at various levels ? Evolution across the site can lead to isolated steam imbalances 4... the chemical plant boundaries ? The Refinery had a need for this valuable energy resource. ? A project was conceived to install piping and control systems to export the excess medium pressure steam to the adjacent Refinery where the steam could be more...

Long, T.

439

BILIWG Meeting: DOE Hydrogen Quality Working Group  

E-Print Network [OSTI]

: distributed (forecourt) production ­ reforming of natural gas (autothermal & steam reforming) ­ reforming

440

Pulsed atmospheric fluidized bed combustion. Technical progress report, April--June 1995  

SciTech Connect (OSTI)

Design activities for this report period included: (1) Mechanical. Stress analysis calculations were performed on the steam/water pressure piping. Pipe support design and drawings were completed by Duke Fluor Daniel. The fluid bed distributor bubble cap design was revisited and changes made for ease of maintenance. (2) Electrical and Instrumentation. Control and instrumentation scheme proposed earlier, was based on independent single loop controllers. After careful review, it is decided to go for state of art distributed control system (DCS) which uses programmable logic controllers (PLC). In addition, coal/limestone pickup hopper fabrication was completed during this period and shipped to the site. The coal/limestone floating caps have been made at MTCI and ready for shipping. All major equipment installation was completed. The pulse combustor steam/water jacket and air plenum were installed. Construction of control room building was just completed.

NONE

1995-07-31T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Apparatus and methods of reheating gas turbine cooling steam and high pressure steam turbine exhaust in a combined cycle power generating system  

DOE Patents [OSTI]

In a combined cycle system having a multi-pressure heat recovery steam generator, a gas turbine and steam turbine, steam for cooling gas turbine components is supplied from the intermediate pressure section of the heat recovery steam generator supplemented by a portion of the steam exhausting from the HP section of the steam turbine, steam from the gas turbine cooling cycle and the exhaust from the HP section of the steam turbine are combined for flow through a reheat section of the HRSG. The reheated steam is supplied to the IP section inlet of the steam turbine. Thus, where gas turbine cooling steam temperature is lower than optimum, a net improvement in performance is achieved by flowing the cooling steam exhausting from the gas turbine and the exhaust steam from the high pressure section of the steam turbine in series through the reheater of the HRSG for applying steam at optimum temperature to the IP section of the steam turbine.

Tomlinson, Leroy Omar (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

2002-01-01T23:59:59.000Z

442

AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA  

E-Print Network [OSTI]

AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA Jeffrey Sachs ABSTRACT: The paper reviews the experience of Poland and Russia with economic reform, with occasional comparison to China's experience. The author argues that macroeconomic chaos in Poland and Russia preceded reform and was allayed by reform

443

September 25, 2013 AFSCME Continues to Object to Pension Reform;  

E-Print Network [OSTI]

September 25, 2013 AFSCME Continues to Object to Pension Reform; UC Implements Latest Bargaining working conditions and reasonable pension reform. However, AFSCME has rejected UC's proposals. From the start, AFSCME leadership has objected to UC's responsible pension reform -- the kind of reform that

Leistikow, Bruce N.

444

REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH  

E-Print Network [OSTI]

REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH Cecilia TESTA London School of Economics are a reform and a compensating taxation. The main feature of the reform is that it creates gainers and losers on tax parameters. keywords: reform, lobbying, redistribution, economic welfare. 1 #12;Introduction

Royal Holloway, University of London

445

Diesel Reforming for Solid Oxide Fuel Cell Application  

SciTech Connect (OSTI)

This presentation discusses the development of a diesel reforming catalyst and catalytic system development.

Liu, D-J.; Sheen, S-H.; Krumpelt, M.

2005-01-27T23:59:59.000Z

446

Electricity reform in developing and transition countries: A reappraisal  

E-Print Network [OSTI]

Electricity reform in developing and transition countries: A reappraisal J.H. Williams, R. Ghanadan-oriented reforms in their electric power sectors. Despite the widespread adoption of a standard policy model features of non-OECD electricity reform and reappraises reform policies and underlying assumptions

Kammen, Daniel M.

447

Internal reforming fuel cell assembly with simplified fuel feed  

DOE Patents [OSTI]

A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

Farooque, Mohammad (Huntington, CT); Novacco, Lawrence J. (Brookfield, CT); Allen, Jeffrey P. (Naugatuck, CT)

2001-01-01T23:59:59.000Z

448

Analysis of the Pebble-Bed VHTR Spectrum Shifting Capabilities for Advanced Fuel Cycles  

E-Print Network [OSTI]

to be subcritical is indeed subcritical. KENO-VI and CENTRM have validation reports noting that the codes were validated using the 238-group ENDF/B-V library against critical experiments. A wide range of experiments were selected, which include high... fuel, the neutron steaming effects in a pebble-bed type HTR, and the effects of accidental water ingress (since HTR systems generally tend to be under moderated, an accident of this type can lead to large positive reactivity changes, in particular...

Pritchard, Megan; Tsvetkov, Pavel

2009-09-30T23:59:59.000Z

449

Analysis of Pebble-Bed VHTR Spectrum Shifting Capabilities for Advanced Fuel Cycles  

E-Print Network [OSTI]

of validation is to establish an acceptance criteria such that there is a high degree of confidence that a system is calculated to be subcritical is indeed subcritical. KENO-VI and CENTRM have validation reports noting that the codes were...-heterogeneity in LEU fuel, the neutron steaming effects in a pebble-bed type HTR, and the effects of accidental water ingress (since HTR systems generally tend to be under moderated, an accident of this type can lead to large positive reactivity changes...

Pritchard, Megan

2006-07-11T23:59:59.000Z

450

Boiler Efficiency vs. Steam Quality- The Challenge of Creating Quality Steam Using Existing Boiler Efficiencies  

E-Print Network [OSTI]

A boiler works under pressure and it is not possible to see what is happening inside of it. The terms "wet steam" and "carry over" are every day idioms in the steam industry, yet very few people have ever seen these phenomena and the actual water...

Hahn, G.

451

Solving chemical and mechanical problems of PWR steam generators  

SciTech Connect (OSTI)

Steam generators in power plants, based on pressurized water reactors (PWRs), transfer heat from a primary coolant system (pressurized water) to a secondary coolant system. Primary coolant water is heated in the core and passes through the steam generator that transfers heat to the secondary coolant water to make steam. The steam then drives a turbine that turns an electric generator. Steam is condensed and returned to the steam generator as feedwater. Two types of PWR steam generators are in use: recirculating steam generators (RSGs) and once-through steam generators (OTSGs). Since most of the units are vertical, only vertical units are discussed in this article. Some vertical units have operated with a minimum of problems, while others have experienced a variety of corrosion and mechanically-induced problems that have caused unscheduled outages and expensive repairs.

Green, S.J.

1987-07-01T23:59:59.000Z

452

Visbreaking-enhanced thermal recovery method utilizing high temperature steam  

SciTech Connect (OSTI)

The displacement efficiency of a steam drive process is improved and steam override reduced by rapidly injecting a predetermined amount of high temperature steam via an injection well into the formation to visbreak a portion of the oil in the formation prior to a steam drive wherein steam is injected into the formation via the injection well to displace oil to a spaced-apart production well through which oil is recovered. The visbroken oil provides a more favorable transition of mobility ratio between the phases in the formation thereby reducing viscous fingering and increasing the displacement efficiency of the steam drive. In addition, after a predetermined amount of high temperature steam has been injected into the formation, the formation may be allowed to undergo a soak period prior to the steam drive. The high temperature steam injection and soaking steps may be sequentially repeated for a plurality of cycles.

Shu, W.R.

1984-06-26T23:59:59.000Z

453

A Better Steam Engine: Designing a Distributed Concentrating Solar Combined Heat and Power System  

E-Print Network [OSTI]

A Better Steam Engine: Designing a Distributed Concentrating2011 Abstract A Better Steam Engine: Designing a Distributedprovided for a steam Rankine cycle heat engine achieving 50%

Norwood, Zachary Mills

2011-01-01T23:59:59.000Z

454

Development of Steam Turbine Inlet Control Valve for Supercritical Pressure at Siemens Industrial Turbomachinery AB.  

E-Print Network [OSTI]

?? The development in the steam turbine business is heading for applications with much higher steam parameters since this enables a raised efficiency. Steam parameters… (more)

Sors, Felix

2010-01-01T23:59:59.000Z

455

Electrical Generation Tax Reform Act (Montana)  

Broader source: Energy.gov [DOE]

This Act reforms taxes paid by electricity generators to reduce tax rates and imposes replacement taxes in response to the 1997 restructuring of the Montana electric utility industry that allows...

456

Electricity reform abroad and US investment  

SciTech Connect (OSTI)

This report reviews and analyzes the recent electricity reforms in Argentina, Australia, and the United Kingdom (UK) to illustrate how different models of privatization and reform have worked in practice. This report also analyzes the motivations of the U.S. companies who have invested in the electricity industries in these countries, which have become the largest targets of U.S. foreign investment in electricity. Two calculations of foreign investment are used. One is the foreign direct investment series produced by the U.S. Department of Commerce. The other is based on transactions in electric utilities of the three countries. The electricity reform and privatization experiences reviewed may offer some insight as to how the U.S. electricity industry might develop as a result of recent domestic reform efforts and deregulation at the state and national levels. 126 refs., 23 figs., 27 tabs.

NONE

1997-10-01T23:59:59.000Z

457

Device for cooling and humidifying reformate  

DOE Patents [OSTI]

Devices for cooling and humidifying a reformate stream from a reforming reactor as well as related methods, modules and systems includes a heat exchanger and a sprayer. The heat exchanger has an inlet, an outlet, and a conduit between the inlet and the outlet. The heat exchanger is adapted to allow a flow of a first fluid (e.g. water) inside the conduit and to establish a heat exchange relationship between the first fluid and a second fluid (e.g. reformate from a reforming reactor) flowing outside the conduit. The sprayer is coupled to the outlet of the heat exchanger for spraying the first fluid exiting the heat exchanger into the second fluid.

Zhao, Jian Lian (Belmont, MA); Northrop, William F. (Ann Arbor, MI)

2008-04-08T23:59:59.000Z

458

E-Print Network 3.0 - assessing welfare reform Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reventionscience.umn.edu Summary: , poverty, welfare reform, school reform, and health- care reform. An emphasis is given to large... , and dissemination of a variety of programs...

459

Energy Savings with Computerized Steam Trap Maintenance Program  

E-Print Network [OSTI]

by Armstrong International, Inc. Five other manufacturers each have about a 5% share of the tmp population, and about 5 more account for the remaining steam traps. 6,430 STEAM TRAPS COLl3Il~) FIGURE 3 - Steam trap population by application. 8,430 STEAM... standardized using the inverted bucket steam trap made by Armstrong International, Inc. "or equal", with approval, wherever applicable and sensible. I believe the inverted bucket steam trap is the best one for this. The selection of a good manufacturer...

Klidzejs, A. M.

460

CX-004445: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Waste Treatment Plant Secondary Waste Radioactive Fluidized Bed Steam Reforming (Module A)CX(s) Applied: B3.6Date: 10/25/2010Location(s): Aiken, South CarolinaOffice(s): Savannah River Operations Office

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

--No Title--  

Broader source: Energy.gov (indexed) [DOE]

This work (Module A) involves performing the fluidized bed steam reforming (FBSR) process on caustic DWPF Offgas Condensate Tank (OGCT) in SRNL HLC, A-block. The DWPF OGCT...

462

High-temperature hydrogen-air-steam detonation experiments in the BNL small-scale development apparatus  

SciTech Connect (OSTI)

The Small-Scale Development Apparatus (SSDA) was constructed to provide a preliminary set of experimental data to characterize the effect of temperature on the ability of hydrogen-air-steam mixtures to undergo detonations and, equally important, to support design of the larger scale High-Temperature Combustion Facility (HTCF) by providing a test bed for solution of a number of high-temperature design and operational problems. The SSDA, the central element of which is a 10-cm inside diameter, 6.1-m long tubular test vessel designed to permit detonation experiments at temperatures up to 700K, was employed to study self-sustained detonations in gaseous mixtures of hydrogen, air, and steam at temperatures between 300K and 650K at a fixed initial pressure of 0.1 MPa. Hydrogen-air mixtures with hydrogen composition from 9 to 60 percent by volume and steam fractions up to 35 percent by volume were studied for stoichiometric hydrogen-air-steam mixtures. Detonation cell size measurements provide clear evidence that the effect of hydrogen-air gas mixture temperature, in the range 300K-650K, is to decrease cell size and, hence, to increase the sensitivity of the mixture to undergo detonations. The effect of steam content, at any given temperature, is to increase the cell size and, thereby, to decrease the sensitivity of stoichiometric hydrogen-air mixtures. The hydrogen-air detonability limits for the 10-cm inside diameter SSDA test vessel, based upon the onset of single-head spin, decreased from 15 percent hydrogen at 300K down to between 9 and 10 percent hydrogen at 650K. The one-dimensional ZND model does a very good job at predicting the overall trends in the cell size data over the range of hydrogen-air-steam mixture compositions and temperature studied in the experiments.

Ciccarelli, G.; Ginsburg, T.; Boccio, J.; Economos, C.; Finfrock, C.; Gerlach, L. [Brookhaven National Lab., Upton, NY (United States); Sato, K.; Kinoshita, M. [Nuclear Power Engineering Corp., Tokyo (Japan)

1994-08-01T23:59:59.000Z

463

Ultra supercritical turbines--steam oxidation  

SciTech Connect (OSTI)

Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy?s Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538?C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620?C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which would require steam temperatures of up to 760?C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

Holcomb, Gordon R.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Ziomek-Moroz, Margaret; Alman, David E.

2004-01-01T23:59:59.000Z

464

Integrated vacuum absorption steam cycle gas separation  

DOE Patents [OSTI]

Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

2011-11-22T23:59:59.000Z

465

Apparatus for removing micronized coal from steam  

SciTech Connect (OSTI)

Micronized coal is removed from coal-bearing steam by spraying stabilized petroleum oil into the steam and directing the resultant stream at a separation surface on which a coal-oil slurry is deposited and collected. Apparatus includes conduits which direct the resultant stream downward into a housing and normal to a surface on which the slurry is deposited by impact forces. In additional apparatus disclosed, the resultant stream is directed from a horizontal conduit circumferentially along the interior wall of a horizontally disposed cylindrical chamber at the top of the chamber and the coal-oil slurry deposited on the wall by centrifugal force is collected in a trough situated below a longitudinal slot at the bottom of the chamber. In both types of apparatus, after separation of the slurry the velocity of the steam is reduced to settle out remaining oil droplets and is then discharged to the atmosphere.

Vlnaty, J.

1981-12-15T23:59:59.000Z

466

Improved plant performance through evaporative steam condensing  

SciTech Connect (OSTI)

Combining an open cooling tower and a steam condenser into one common unit is a proven technology with many advantages in power generation application, including reduced first cost of equipment, reduced parasitic energy consumption, simplified design, reduced maintenance, and simplified water treatment, Performance of the steam turbine benefits from the direct approach to wet bulb temperature, and operating flexibility and reliability improve compared to a system with a cooling tower and surface condenser. System comparisons and case histories will be presented to substantiate improved systems economies.

Hutton, D.

1998-07-01T23:59:59.000Z

467

Steam Trap Maintenance as a Profit Center  

E-Print Network [OSTI]

the Eighteenth Industrial Energy Technology Conference, Houston, TX, April 17-18, 1996 EXCUSES Everybody thinks his or her steam trap maintenance is good. Surveysl have shown the following are the most popular excuses encountered when managers are confronted... for steam traps. 192 ESL-IE-96-04-28 Proceedings from the Eighteenth Industrial Energy Technology Conference, Houston, TX, April 17-18, 1996 5. Set up a trap maintenance program C. Prepare and present a report to that will: management on the results...

Bouchillon, J. L.

468

Energy & Environmental Benefits from Steam & Electricity Cogeneration  

E-Print Network [OSTI]

steam from two on-site powerhouses (one coal-fired and one natural gas-fired) and from gas-fired and waste heat boilers in its four hydrocarbon cracking plants. The challenge was to find a way to reduce costs and improve reliability of procuring and... the electricity required by TEX and sells excess power to wholesale customers in the region. It provides a large portion of TEX steam requirements, with sufficient reliability such that TEX decommissioned its coal-fired powerhouse and reduced operations...

Ratheal, R.

2004-01-01T23:59:59.000Z

469

23rd steam-station cost survey  

SciTech Connect (OSTI)

The results of the 23rd Steam Station Cost Survey covering the year 1982 are summarized. The major categories of the survey are as follows: general data; output data, 1982; fuel consumption, 1982; operation 1982 (mills/net kWh); investment ($/net kWh); energy cost, 1982 (mills/net kWh); and station performance, 1982. Thirty-one fossil-fuel steam plants and four nuclear stations were included in the survey. Fuel and operating cost increases are felt to be responsible for the moderate rise in total busbar-enery costs. 11 figures, 1 table.

Friedlander, G.D.; Going, M.C.

1983-11-01T23:59:59.000Z

470

Perspective: The road to reform  

SciTech Connect (OSTI)

The rapid transformation underway in the utility industry provides ample evidence that the reality of the Energy Policy Act of 1992 is sinking in. This law reflected Congress's conclusion that competition in wholesale power generation-at the plant busbar-is a demonstrable reality. It expressed the vision of a fully competitive wholesale generation market, with suppliers linked to markets through a grid that would provide service on a nondiscriminatory basis. But will consumers reap the full benefits of effective competition at the wholesale generation level Or will more disorderly forms of competition emerge, reflecting a hybrid of deregulation and old-fashioned monopoly tactics Along the latter course we run the risk of cost shifts among customer classes, customer defections, diminished utility cooperation, and higher overall costs to society. In short, the vision of a competitive market in wholesale generation will not come about without thoughtful efforts at defining the relevant market, as well as careful attention to the management of a difficult transition away from outmodes mindsets and regulatory models. As a national trade association representing independent power producers (IPPs) and suppliers of goods and services to the competitive wholesale electric generation industry, the Electric Generation Association (EGA) believes that constructive dialogue will yield the best approach to managing this difficult process of transition. In that spirit, the EGA Emerging Operational Issues Committee recently released a while paper, [open quotes]Electrifying Change: Strategies for Structural Reform in the Electric Industry,[close quotes] which forms the basis for this article.

Howe, J.B. (J. Makowski Associates Inc., Boston, MA (United States))

1994-04-01T23:59:59.000Z

471

Building a Raised Bed Garden  

E-Print Network [OSTI]

need, and are less likely to wet foliage. However, they do have some disadvantages. Emitters are prone to clogging unless the water used is very clean, and if emitters are installed under mulch it is difficult to spot problems. Emitters are also... this flexibility as your plantings mature. If you choose drip or trickle irrigation, determine the length of the hose and the number of emitters you will need. Drip tape with 12-inch emitter spacing is best for vegetables. Beds should be divided into watering zones...

Files, Priscilla J.; Dainello, Frank J.; Arnold, Michael A.; Welsh, Douglas F.

2009-03-26T23:59:59.000Z

472

Battery using a metal particle bed electrode  

DOE Patents [OSTI]

A zinc-air battery in a case including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit.

Evans, James V. (Piedmont, CA); Savaskan, Gultekin (Albany, CA)

1991-01-01T23:59:59.000Z

473

Gas distributor for fluidized bed coal gasifier  

DOE Patents [OSTI]

A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

Worley, Arthur C. (Mt. Tabor, NJ); Zboray, James A. (Irvine, CA)

1980-01-01T23:59:59.000Z

474

Battery using a metal particle bed electrode  

DOE Patents [OSTI]

A zinc-air battery in a case is described including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit. 7 figures.

Evans, J.V.; Savaskan, G.

1991-04-09T23:59:59.000Z

475

E-Print Network 3.0 - advanced steam generators Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

THEORY AND IN PRACTICE. BY R... OF A HISTORY OF THE STEAM-EN- GINE, A MANUAL OF THE STEAM-ENGINE, A MANUAL OF STEAM-BOILERS, ETC., ETC., ETC... treatise on Steam-Boiler Explosions...

476

Energy Conservation Thru Steam Trap Surveys and Preventive Maintenance Programs  

E-Print Network [OSTI]

ENERGY CONSERVATION THRU STEAM TRAP SURVEYS AND PREVENTIVE MAINTENANCE PROGRAMS Terry Boynton, Armstrong, Three Rivers, Mich. Bob Dewhirst, Armstrong, New Braunfels, Texas. This paper will deal with steam trap surveys and preventive maintenance...

Boynton, T.; Dewhirst, B.

1980-01-01T23:59:59.000Z

477

Pafnuty Chebyshev, Steam Engines, and Polynomials by John Albert  

E-Print Network [OSTI]

Pafnuty Chebyshev, Steam Engines, and Polynomials by John Albert OU Mathfest, January 2009 1 professorship at age 61, but continued to work on mathematics right up to his death at age 73. 2. Steam Engines

Albert, John

478

Following Where the Steam Goes: Industry's Business Opportunity  

E-Print Network [OSTI]

Many associated benefits accrue from plant projects which comprehensively address steam systems. The DOE-Alliance to Save Energy Steam Challenge program was initiated shortly after last year's IETC on April 30, 1998 to promote awareness...

Jaber, D.; Jones, T.

479

Optimization of Steam Network in Tehran Oil Refinery  

E-Print Network [OSTI]

case study and its steam network is analyzed. At the first step, using STAR software, the steam network is simulated and then optimized, which determines the optimum conditions. In this regard, energy saving potential was identified and total operating...

Khodaie, H.; Nasr, M. R. J.

2008-01-01T23:59:59.000Z

480

The Analysis and Development of Large Industrial Steam Systems  

E-Print Network [OSTI]

Chemicals, petroleum, pulp and paper, and many other industries depend heavily on extensive complex steam systems for thermal and mechanical energy delivery. Steam's versatility and desirable characteristics as both a heat transfer medium and a...

Waterland, A. F.

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bed steam reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Use a Vent Condenser to Recover Flash Steam Energy (Revised)  

SciTech Connect (OSTI)

This revised ITP tip sheet on vent condenser to recover flash steam energy provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-05-01T23:59:59.000Z

482

Case Study- Steam System Improvements at Dupont Automotive Marshall Laboratory  

E-Print Network [OSTI]

and implement small scale cogeneration. These recommendations included reducing the medium pressure steam distribution to low pressure, eliminating the medium pressure to low pressure reducing stations, installing a back pressure steam turbine generator...

Larkin, A.

483

Finding Benefits by Modeling and Optimizing Steam and Power Systems  

E-Print Network [OSTI]

A site-wide steam modeling and optimization program (Visual MESA) was implemented at the INEOS Chocolate Bayou site. This program optimizes steam production, compressor turbine extraction, pump operation (turbine/motor) operation, as well...

Jones, B.; Nelson, D.

2007-01-01T23:59:59.000Z

484

Steam Tracing...New Technologies for the 21st Century  

E-Print Network [OSTI]

For decades, steam tracing has been an accepted practice in the heating of piping, vessels, and equipment. This paper presents recent product innovations such as "burn-safe" and "energy efficient" steam tracing products. For the many applications...

Pitzer, R. K.; Barth, R. E.; Bonorden, C.

485

CIBO's Energy Efficiency Handbook for Steam Power Systems  

E-Print Network [OSTI]

The Council of Industrial Boiler Owners (CIBO) has developed a handbook to help boiler operators get the best performance from their industrial steam systems. This energy efficiency handbook takes a comprehensive look at the boiler and steam system...

Bessette, R. D.

486

Packed fluidized bed blanket for fusion reactor  

DOE Patents [OSTI]

A packed fluidized bed blanket for a fusion reactor providing for efficient radiation absorption for energy recovery, efficient neutron absorption for nuclear transformations, ease of blanket removal, processing and replacement, and on-line fueling/refueling. The blanket of the reactor contains a bed of stationary particles during reactor operation, cooled by a radial flow of coolant. During fueling/refueling, an axial flow is introduced into the bed in stages at various axial locations to fluidize the bed. When desired, the fluidization flow can be used to remove particles from the blanket.

Chi, John W. H. (Mt. Lebanon, PA)

1984-01-01T23:59:59.000Z

487

Combined fluidized bed retort and combustor  

DOE Patents [OSTI]

The present invention is directed to a combined fluidized bed retorting and combustion system particularly useful for extracting energy values from oil shale. The oil-shale retort and combustor are disposed side-by-side and in registry with one another through passageways in a partition therebetween. The passageways in the partition are submerged below the top of the respective fluid beds to preclude admixing or the product gases from the two chambers. The solid oil shale or bed material is transported through the chambers by inclining or slanting the fluidizing medium distributor so that the solid bed material, when fluidized, moves in the direction of the downward slope of the distributor.

Shang, Jer-Yu (Fairfax, VA); Notestein, John E. (Morgantown, WV); Mei, Joseph S. (Morgantown, WV); Zeng, Li-Wen (Morgantown, WV)

1984-01-01T23:59:59.000Z