National Library of Energy BETA

Sample records for bed steam reformer

  1. Durability Testing of Fluidized Bed Steam Reforming Products

    SciTech Connect (OSTI)

    JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

    2005-07-01

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

  2. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    SciTech Connect (OSTI)

    Kevin Whitty

    2007-06-30

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  3. FLUIDIZED BED STEAM REFORMING ENABLING ORGANIC HIGH LEVEL WASTE DISPOSAL

    SciTech Connect (OSTI)

    Williams, M

    2008-05-09

    Waste streams planned for generation by the Global Nuclear Energy Partnership (GNEP) and existing radioactive High Level Waste (HLW) streams containing organic compounds such as the Tank 48H waste stream at Savannah River Site have completed simulant and radioactive testing, respectfully, by Savannah River National Laboratory (SRNL). GNEP waste streams will include up to 53 wt% organic compounds and nitrates up to 56 wt%. Decomposition of high nitrate streams requires reducing conditions, e.g. provided by organic additives such as sugar or coal, to reduce NOX in the off-gas to N2 to meet Clean Air Act (CAA) standards during processing. Thus, organics will be present during the waste form stabilization process regardless of the GNEP processes utilized and exists in some of the high level radioactive waste tanks at Savannah River Site and Hanford Tank Farms, e.g. organics in the feed or organics used for nitrate destruction. Waste streams containing high organic concentrations cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by pretreatment. The alternative waste stabilization pretreatment process of Fluidized Bed Steam Reforming (FBSR) operates at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). The FBSR process has been demonstrated on GNEP simulated waste and radioactive waste containing high organics from Tank 48H to convert organics to CAA compliant gases, create no secondary liquid waste streams and create a stable mineral waste form.

  4. FLUIDIZED BED STEAM REFORMING FOR TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE

    SciTech Connect (OSTI)

    HEWITT WM

    2011-04-08

    This report is one of four reports written to provide background information regarding immobilization technologies remaining under consideration for supplemental immobilization of Hanford's low-activity waste. This paper provides the reader a general understanding of fluidized bed steam reforming and its possible application to treat and immobilize Hanford low-activity waste.

  5. Fluidized bed steam reformed mineral waste form performance testing to support Hanford Supplemental Low Activity Waste Immobilization Technology Selection

    SciTech Connect (OSTI)

    Jantzen, C. M.; Pierce, E. M.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Crawford, C. L.; Daniel, W. E.; Fox, K. M.; Herman, C. C.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.; Brown, C. F.; Qafoku, N. P.; Neeway, J. J.; Valenta, M. M.; Gill, G. A.; Swanberg, D. J.; Robbins, R. A.; Thompson, L. E.

    2015-10-01

    This report describes the benchscale testing with simulant and radioactive Hanford Tank Blends, mineral product characterization and testing, and monolith testing and characterization. These projects were funded by DOE EM-31 Technology Development & Deployment (TDD) Program Technical Task Plan WP-5.2.1-2010-001 and are entitled “Fluidized Bed Steam Reformer Low-Level Waste Form Qualification”, Inter-Entity Work Order (IEWO) M0SRV00054 with Washington River Protection Solutions (WRPS) entitled “Fluidized Bed Steam Reforming Treatability Studies Using Savannah River Site (SRS) Low Activity Waste and Hanford Low Activity Waste Tank Samples”, and IEWO M0SRV00080, “Fluidized Bed Steam Reforming Waste Form Qualification Testing Using SRS Low Activity Waste and Hanford Low Activity Waste Tank Samples”. This was a multi-organizational program that included Savannah River National Laboratory (SRNL), THOR® Treatment Technologies (TTT), Pacific Northwest National Laboratory (PNNL), Oak Ridge National Laboratory (ORNL), Office of River Protection (ORP), and Washington River Protection Solutions (WRPS). The SRNL testing of the non-radioactive pilot-scale Fluidized Bed Steam Reformer (FBSR) products made by TTT, subsequent SRNL monolith formulation and testing and studies of these products, and SRNL Waste Treatment Plant Secondary Waste (WTP-SW) radioactive campaign were funded by DOE Advanced Remediation Technologies (ART) Phase 2 Project in connection with a Work-For-Others (WFO) between SRNL and TTT.

  6. Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Burket, P. R.; Bannochie, C. J.; Daniel, W. G.; Nash, C. A.; Cozzi, A. D.; Herman, C. C.

    2012-10-22

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.

  7. Fluidized Bed Steam Reforming of Hanford LAW Using THORsm Mineralizing Technology

    SciTech Connect (OSTI)

    Olson, Arlin L.; Nicholas R Soelberg; Douglas W. Marshall; Gary L. Anderson

    2004-11-01

    The U.S. Department of Energy (DOE) documented, in 2002, a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified steam reforming technology as a candidate for supplemental treatment of as much as 70% of the low-activity waste (LAW). Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was completed in a 15-cm-diameter reactor vessel. The pilot scale facility was equipped with a highly efficient cyclone separator and heated sintered metal filters for particulate removal, a thermal oxidizer for reduced gas species and NOx destruction, and a packed activated carbon bed for residual volatile species capture. The pilot scale equipment is owned by the DOE, but located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Pilot scale testing was performed August 2–5, 2004. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Science Application International Corporation, owners of the STAR Center, personnel performed actual pilot scale operation. The pilot scale test achieved a total of 68.7 hrs of cumulative/continuous processing operation before termination in response to a bed de-fluidization condition. 178 kg of LAW surrogate were processed that resulted in 148 kg of solid product, a mass reduction of about 17%. The process achieved essentially complete bed turnover within approximately 40 hours. Samples of mineralized solid product materials were analyzed for chemical/physical properties. SRNL will report separately the results of product performance testing that were accomplished.

  8. Characterization and Leaching Tests of the Fluidized Bed Steam Reforming (FBSR) Waste Form for LAW Immobilization

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Brown, Christopher F.; Peterson, Reid A.

    2013-10-01

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) have been evaluated. One such immobilization technology is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Pacific Northwest National Laboratory (PNNL) was involved in an extensive characterization campaign. This goal of this campaign was study the durability of the FBSR mineral product and the mineral product encapsulated in a monolith to meet compressive strength requirements. This paper gives an overview of results obtained using the ASTM C 1285 Product Consistency Test (PCT), the EPA Test Method 1311 Toxicity Characteristic Leaching Procedure (TCLP), and the ASTMC 1662 Single-Pass Flow-Through (SPFT) test. Along with these durability tests an overview of the characteristics of the waste form has been collected using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), microwave digestions for chemical composition, and surface area from Brunauer, Emmett, and Teller (BET) theory.

  9. Performance of the Fluidized Bed Steam Reforming Product Under Hydraulically Unsaturated Conditions

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Williams, Benjamin D.; Rod, Kenton A.; Bowden, Mark E.; Brown, Christopher F.; Pierce, Eric M.

    2014-05-01

    Currently, several candidates for secondary waste immobilization at the Hanford site in the State of Washington, USA are being considered. To demonstrate the durability of the product in the unsaturated Integrated Disposal Facility (IDF) at the site, a series of tests have been performed one of the candidate materials using the Pressurized Unsaturated Flow (PUF) system. The material that was tested was the Fluidized Bed Steam Reformer (FBSR) granular product and the granular product encapsulated in a geopolymer matrix. The FBSR product is composed primarily of an insoluble sodium aluminosilicate matrix with the dominant phases being feldspathoid minerals mostly nepheline, sodalite, and nosean. The PUF test method allows for the accelerated weathering of materials, including radioactive waste forms, under hydraulically unsaturated conditions, thus mimicking the open-flow and transport properties that most likely will be present at the IDF. The experiments show a trend of decreasing tracer release as a function of time for several of the elements released from the material including Na, Si, Al, and Cs. However, some of the elements, notably I and Re, show a steady release throughout the yearlong test. This result suggests that the release of these minerals from the sodalite cage occurs at a different rate compared with the dissolution of the predominant nepheline phase.

  10. Radionuclide and contaminant immobilization in the fluidized bed steam reforming waste products

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Westsik, Joseph H.; Brown, Christopher F.; Jantzen, Carol; Pierce, Eric M.

    2012-05-01

    The goal of this chapter is to introduce the reader to the Fluidized Bed Steam Reforming (FBSR) process and resulting waste form. The first section of the chapter gives an overview of the potential need for FBSR processing in nuclear waste remediation followed by an overview of the engineering involved in the process itself. This is followed by a description of waste form production at a chemical level followed by a section describing different process streams that have undergone the FBSR process. The third section describes the resulting mineral product in terms of phases that are present and the ability of the waste form to encapsulate hazardous and radioactive wastes from several sources. Following this description is a presentation of the physical properties of the granular and monolith waste form product including and contaminant release mechanisms. The last section gives a brief summary of this chapter and includes a section on the strengths associated with this waste form and the needs for additional data and remaining questions yet to be answered. The reader is directed elsewhere for more information on other waste forms such as Cast Stone (Lockrem, 2005), Ceramicrete (Singh et al., 1997, Wagh et al., 1999) and geopolymers (Kyritsis et al., 2009; Russell et al., 2006).

  11. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2006-12-06

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  12. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2007-03-31

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  13. Method of steam reforming methanol to hydrogen

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA)

    1990-01-01

    The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

  14. Secondary Waste Form Screening Test Results—THOR® Fluidized Bed Steam Reforming Product in a Geopolymer Matrix

    SciTech Connect (OSTI)

    Pires, Richard P.; Westsik, Joseph H.; Serne, R. Jeffrey; Mattigod, Shas V.; Golovich, Elizabeth C.; Valenta, Michelle M.; Parker, Kent E.

    2011-07-14

    Screening tests are being conducted to evaluate waste forms for immobilizing secondary liquid wastes from the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Plans are underway to add a stabilization treatment unit to the Effluent Treatment Facility to provide the needed capacity for treating these wastes from WTP. The current baseline is to use a Cast Stone cementitious waste form to solidify the wastes. Through a literature survey, DuraLith alkali-aluminosilicate geopolymer, fluidized-bed steam reformation (FBSR) granular product encapsulated in a geopolymer matrix, and a Ceramicrete phosphate-bonded ceramic were identified both as candidate waste forms and alternatives to the baseline. These waste forms have been shown to meet waste disposal acceptance criteria, including compressive strength and universal treatment standards for Resource Conservation and Recovery Act (RCRA) metals (as measured by the toxicity characteristic leaching procedure [TCLP]). Thus, these non-cementitious waste forms should also be acceptable for land disposal. Information is needed on all four waste forms with respect to their capability to minimize the release of technetium. Technetium is a radionuclide predicted to be in the secondary liquid wastes in small quantities, but the Integrated Disposal Facility (IDF) risk assessment analyses show that technetium, even at low mass, produces the largest contribution to the estimated IDF disposal impacts to groundwater.

  15. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING WITH ACUTAL HANFORD LOW ACTIVITY WASTES VERIFYING FBSR AS A SUPPLEMENTARY TREATMENT

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Burket, P.; Bannochie, C.; Daniel, G.; Nash, C.; Cozzi, A.; Herman, C.

    2012-01-12

    The U.S. Department of Energy's Office of River Protection is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level waste (HLW) and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the cleanup mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA). Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. Fluidized Bed Steam Reforming (FBSR) is one of the supplementary treatments being considered. FBSR offers a moderate temperature (700-750 C) continuous method by which LAW and other secondary wastes can be processed irrespective of whether they contain organics, nitrates/nitrites, sulfates/sulfides, chlorides, fluorides, and/or radio-nuclides like I-129 and Tc-99. Radioactive testing of Savannah River LAW (Tank 50) shimmed to resemble Hanford LAW and actual Hanford LAW (SX-105 and AN-103) have produced a ceramic (mineral) waste form which is the same as the non-radioactive waste simulants tested at the engineering scale. The radioactive testing demonstrated that the FBSR process can retain the volatile radioactive components that cannot be contained at vitrification temperatures. The radioactive and nonradioactive mineral waste forms that were produced by co-processing waste with kaolin clay in an FBSR process are shown to be as durable as LAW glass.

  16. Fluidized Bed Steam Reforming (FBSR) Mineralization for High Organic and Nitrate Waste Streams for the Global Nuclear Energy Partnership (GNEP)

    SciTech Connect (OSTI)

    Jantzen, C.M.; Williams, M.R. [Savannah River National Laboratory, Aiken, SC (United States)

    2008-07-01

    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NOx in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 deg. C) compared to vitrification (1150-1300 deg. C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {>=}1000 deg. C. Pollucite mineralization creates secondary aqueous waste streams and NOx. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O. (authors)

  17. FLUIDIZED BED STEAM REFORMING MINERALIZATION FOR HIGH ORGANIC AND NITRATE WASTE STREAMS FOR THE GLOBAL NUCLEAR ENERGY PARTNERSHIP

    SciTech Connect (OSTI)

    Jantzen, C; Michael Williams, M

    2008-01-11

    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NO{sub x} in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {ge} 1000 C. Pollucite mineralization creates secondary aqueous waste streams and NO{sub x}. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O.

  18. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

    2011-02-24

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the Savannah River National Laboratory (SRNL) to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of I-125/129 and Tc-99 to chemically resemble WTP-SW. Ninety six grams of radioactive product were made for testing. The second campaign commenced using SRS LAW chemically trimmed to look like Hanford's LAW. Six hundred grams of radioactive product were made for extensive testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  19. Status of pulse combustion applications in (1) steam reforming of coal, (2) fluid bed combustion of coal, and (3) direct coal fired gas turbine

    SciTech Connect (OSTI)

    Durai-Swamy, K. [ThermoChem, Inc., Santa Fe Springs, CA (United States); Chandran, R.; Said, H.; Steedman, W.

    1994-12-31

    ThermoChem, Inc. has designed a 450 T/D wet coal gasification by indirect, pulse-combustor-heated, steam reforming process. The plant site is Gillette, Wyoming. Products from the demo project are: (1) High pressure steam for a K-Fuel coal upgrading plant and (2) Medium Btu syngas, which could be used for power generation or methanol production. The indirect heated steam reformer could also produce a char by-product (if desired) that could be used as a reductant in direct iron making (DRI) process. There has been interest for char production as well. ThermoChem is constructing a pulse assisted, atmospheric pressure fluid bed combustor unit (PAFBC) to produce 50,000 lb/hr of steam, at Clemson University in South Carolina. MTCI`s developing a pressurized pulse coal combustor coupled with bimodal ash agglomeration, sulfur capture and solids removal features, such that the hot flue gas can be directly expanded in a gas turbine to generate power. The status of these Clean Coal Technologies is presented in this paper.

  20. MINERALIZATION OF RADIOACTIVE WASTES BY FLUIDIZED BED STEAM REFORMING (FBSR): COMPARISONS TO VITREOUS WASTE FORMS, AND PERTINENT DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C

    2008-12-26

    The Savannah River National Laboratory (SRNL) was requested to generate a document for the Washington State Department of Ecology and the U.S. Environmental Protection Agency that would cover the following topics: (1) A description of the mineral structures produced by Fluidized Bed Steam Reforming (FBSR) of Hanford type Low Activity Waste (LAW including LAWR which is LAW melter recycle waste) waste, especially the cage structured minerals and how they are formed. (2) How the cage structured minerals contain some contaminants, while others become part of the mineral structure (Note that all contaminants become part of the mineral structure and this will be described in the subsequent sections of this report). (3) Possible contaminant release mechanisms from the mineral structures. (4) Appropriate analyses to evaluate these release mechanisms. (5) Why the appropriate analyses are comparable to the existing Hanford glass dataset. In order to discuss the mineral structures and how they bond contaminants a brief description of the structures of both mineral (ceramic) and vitreous waste forms will be given to show their similarities. By demonstrating the similarities of mineral and vitreous waste forms on atomic level, the contaminant release mechanisms of the crystalline (mineral) and amorphous (glass) waste forms can be compared. This will then logically lead to the discussion of why many of the analyses used to evaluate vitreous waste forms and glass-ceramics (also known as glass composite materials) are appropriate for determining the release mechanisms of LAW/LAWR mineral waste forms and how the durability data on LAW/LAWR mineral waste forms relate to the durability data for LAW/LAWR glasses. The text will discuss the LAW mineral waste form made by FBSR. The nanoscale mechanism by which the minerals form will be also be described in the text. The appropriate analyses to evaluate contaminant release mechanisms will be discussed, as will the FBSR test results to date and how they compare to testing performed on LAW glasses. Other details about vitreous waste form durability and impacts of REDuction/OXidation (REDOX) on durability are given in Appendix A. Details about the FBSR process, various pilot scale demonstrations, and applications are given in Appendix B. Details describing all the different leach tests that need to be used jointly to determine the leaching mechanisms of a waste form are given in Appendix C. Cautions regarding the way in which the waste form surface area is measured and in the choice of leachant buffers (if used) are given in Appendix D.

  1. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

    2012-02-02

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  2. 2009 PILOT SCALE FLUIDIZED BED STEAM REFORMING TESTING USING THE THOR (THERMAL ORGANIC REDUCTION) PROCESS: ANALYTICAL RESULTS FOR TANK 48H ORGANIC DESTRUCTION - 10408

    SciTech Connect (OSTI)

    Williams, M.; Jantzen, C.; Burket, P.; Crawford, C.; Daniel, G.; Aponte, C.; Johnson, C.

    2009-12-28

    The Savannah River Site (SRS) must empty the contents of Tank 48H, a 1.3 million gallon Type IIIA HLW storage tank, to return this tank to service. The tank contains organic compounds, mainly potassium tetraphenylborate that cannot be processed downstream until the organic components are destroyed. The THOR{reg_sign} Treatment Technologies (TTT) Fluidized Bed Steam Reforming (FBSR) technology, herein after referred to as steam reforming, has been demonstrated to be a viable process to remove greater than 99.9% of the organics from Tank 48H during various bench scale and pilot scale tests. These demonstrations were supported by Savannah River Remediation (SRR) and the Department of Energy (DOE) has concurred with the SRR recommendation to proceed with the deployment of the FBSR technology to treat the contents of Tank 48H. The Savannah River National Laboratory (SRNL) developed and proved the concept with non-radioactive simulants for SRR beginning in 2003. By 2008, several pilot scale campaigns had been completed and extensive crucible testing and bench scale testing were performed in the SRNL Shielded Cells using Tank 48H radioactive sample. SRNL developed a Tank 48H non-radioactive simulant complete with organic compounds, salt, and metals characteristic of those measured in a sample of the radioactive contents of Tank 48H. FBSR Pilot Scaled Testing with the Tank 48H simulant has demonstrated the ability to remove greater than 98% of the nitrites and greater than 99.5% of the nitrates from the Tank 48H simulant, and to form a solid product that is primarily alkali carbonate. The alkali carbonate is soluble and, thus, amenable to pumping as a liquid to downstream facilities for processing. The FBSR technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration (ESTD) pilot scale steam reformer at the Hazen Research Inc. (HRI) facility in Golden, CO. Additional ESTD tests were completed in 2008 and in 2009 that further demonstrated the TTT steam reforming process ability to destroy organics in the Tank 48 simulant and produce a soluble carbonate waste form. The ESTD was operated at varying feed rates and Denitration and Mineralization Reformer (DMR) temperatures, and at a constant Carbon Reduction Reformer (CRR) temperature of 950 C. The process produced a dissolvable carbonate product suitable for processing downstream. ESTD testing was performed in 2009 at the Hazen facility to demonstrate the long term operability of an integrated FBSR processing system with carbonate product and carbonate slurry handling capability. The final testing demonstrated the integrated TTT FBSR capability to process the Tank 48 simulant from a slurry feed into a greater than 99.9% organic free and primarily dissolved carbonate FBSR product slurry. This paper will discuss the SRNL analytical results of samples analyzed from the 2008 and 2009 THOR{reg_sign} steam reforming ESTD performed with Tank 48H simulant at HRI in Golden, Colorado. The final analytical results will be compared to prior analytical results from samples in terms of organic, nitrite, and nitrate destruction.

  3. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105 And AN-103) By Fluidized Bed Steam Reformation

    SciTech Connect (OSTI)

    Jantzen, Carol; Herman, Connie; Crawford, Charles; Bannochie, Christopher; Burket, Paul; Daniel, Gene; Cozzi, Alex; Nash, Charles; Miller, Donald; Missimer, David

    2014-01-10

    One of the immobilization technologies under consideration as a Supplemental Treatment for Hanford’s Low Activity Waste (LAW) is Fluidized Bed Steam Reforming (FBSR). The FBSR technology forms a mineral waste form at moderate processing temperatures thus retaining and atomically bonding the halides, sulfates, and technetium in the mineral phases (nepheline, sodalite, nosean, carnegieite). Additions of kaolin clay are used instead of glass formers and the minerals formed by the FBSR technology offers (1) atomic bonding of the radionuclides and constituents of concern (COC) comparable to glass, (2) short and long term durability comparable to glass, (3) disposal volumes comparable to glass, and (4) higher Na2O and SO{sub 4} waste loadings than glass. The higher FBSR Na{sub 2}O and SO{sub 4} waste loadings contribute to the low disposal volumes but also provide for more rapid processing of the LAW. Recent FBSR processing and testing of Hanford radioactive LAW (Tank SX-105 and AN-103) waste is reported and compared to previous radioactive and non-radioactive LAW processing and testing.

  4. Steam reforming catalyst

    DOE Patents [OSTI]

    Kramarz, Kurt W. (Murrysville, PA); Bloom, Ira D. (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Wilkenhoener, Rolf (Oakbrook Terrace, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01

    A method of forming a hydrogen rich gas from a source of hydrocarbon fuel. A vapor of the hydrocarbon fuel and steam is brought in contact with a two-part catalyst having a dehydrogenation powder portion and an oxide-ion conducting powder portion at a temperature not less than about 770.degree.C. for a time sufficient to generate the hydrogen rich. The H.sub.2 content of the hydrogen gas is greater than about 70 percent by volume. The dehydrogenation portion of the catalyst includes a group VIII metal, and the oxide-ion conducting portion is selected from a ceramic oxide from the group crystallizing in the fluorite or perovskite structure and mixtures thereof. The oxide-ion conducting portion of the catalyst is a ceramic powder of one or more of ZrO.sub.2, CeO.sub.2, Bi.sub.2 O.sub.3, (BiVO).sub.4, and LaGaO.sub.3.

  5. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) Presented at the 2007...

  6. Fuel cell integrated with steam reformer

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA); Whelan, James A. (Bricktown, NJ)

    1987-01-01

    A H.sub.2 -air fuel cell integrated with a steam reformer is disclosed wherein a superheated water/methanol mixture is fed to a catalytic reformer to provide a continuous supply of hydrogen to the fuel cell, the gases exhausted from the anode of the fuel cell providing the thermal energy, via combustion, for superheating the water/methanol mixture.

  7. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank Farm Blend) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-08-21

    The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Supplemental Treatment is likely to be required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP’s LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750°C) continuous method by which LAW can be processed irrespective of whether the waste contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be comparable to LAW glass, i.e. leaches Tc-99, Re and Na at <2g/m2 during ASTM C1285 (Product Consistency) durability testing. Monolithing of the granular FBSR product was investigated to prevent dispersion during transport or burial/storage. Monolithing in an inorganic geopolymer binder, which is amorphous, macro-encapsulates the granules, and the monoliths pass ANSI/ANS 16.1 and ASTM C1308 durability testing with Re achieving a Leach Index (LI) of 9 (the Hanford Integrated Disposal Facility, IDF, criteria for Tc-99) after a few days and Na achieving an LI of >6 (the Hanford IDF criteria for Na) in the first few hours. The granular and monolithic waste forms also pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) for all Resource Conservation and Recovery Act (RCRA) components at the Universal Treatment Standards (UTS). Two identical Benchscale Steam Reformers (BSR) were designed and constructed at SRNL, one to treat non-radioactive simulants and the other to treat actual radioactive wastes. The results from the non-radioactive BSR were used to determine the parameters needed to operate the radioactive BSR in order to confirm the findings of non-radioactive FBSR pilot scale and engineering scale tests and to qualify an FBSR LAW waste form for applications at Hanford. Radioactive testing commenced using SRS LAW from Tank 50 chemically trimmed to look like Hanford’s blended LAW known as the Rassat simulant as this simulant composition had been tested in the non-radioactive BSR, the non-radioactive pilot scale FBSR at the Science Applications International Corporation-Science and Technology Applications Research (SAIC-STAR) facility in Idaho Falls, ID and in the TTT Engineering Scale Technology Demonstration (ESTD) at Hazen Research Inc. (HRI) in Denver, CO. This provided a “tie back” between radioactive BSR testing and non-radioactive BSR, pilot scale, and engineering scale testing. Approximately six hundred grams of non-radioactive and radioactive BSR product were made for extensive testing and comparison to the non-radioactive pilot scale tests performed in 2004 at SAIC-STAR and the engineering scale test performed in 2008 at HRI with the Rassat simulant. The same mineral phases and off-gas species were found in the radioactive and non-radioactive testing. The granular ESTD and BSR products (radioactive and non-radioactive) were analyzed for to

  8. Supported metal catalysts for alcohol/sugar alcohol steam reforming

    SciTech Connect (OSTI)

    Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

    2014-08-21

    Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

  9. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE (WTP-SW) BY FLUIDIZED BED STEAM REFORMING (FBSR) USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, G.; Jantzen, C.; Missimer, D.

    2014-08-21

    The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150°C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750°C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford’s WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing. The granular products (both simulant and radioactive) were tested and a subset of the granular material (both simulant and radioactive) were stabilized in a geopolymer matrix. Extensive testing and characterization of the granular and monolith material were made including the following: ? ASTM C1285 (Product Consistency Test) testing of granular and monolith; ? ASTM C1308 accelerated leach testing of the radioactive monolith; ? ASTM C192 compression testing of monoliths; and ? EPA Method 1311 Toxicity Characteristic Leaching Procedure (TCLP) testing. The significant findings of the testing completed on simulant and radioactive WTP-SW are given below: ? Data indicates {sup 99}Tc, Re, Cs, and I

  10. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105, Tank AN-103, And AZ-101/102) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-09-18

    Fluidized Bed Steam Reforming (FBSR) is a robust technology for the immobilization of a wide variety of radioactive wastes. Applications have been tested at the pilot scale for the high sodium, sulfate, halide, organic and nitrate wastes at the Hanford site, the Idaho National Laboratory (INL), and the Savannah River Site (SRS). Due to the moderate processing temperatures, halides, sulfates, and technetium are retained in mineral phases of the feldspathoid family (nepheline, sodalite, nosean, carnegieite, etc). The feldspathoid minerals bind the contaminants such as Tc-99 in cage (sodalite, nosean) or ring (nepheline) structures to surrounding aluminosilicate tetrahedra in the feldspathoid structures. The granular FBSR mineral waste form that is produced has a comparable durability to LAW glass based on the short term PCT testing in this study, the INL studies, SPFT and PUF testing from previous studies as given in the columns in Table 1-3 that represent the various durability tests. Monolithing of the granular product was shown to be feasible in a separate study. Macro-encapsulating the granular product provides a decrease in leaching compared to the FBSR granular product when the geopolymer is correctly formulated.

  11. Hydrogen generation utilizing integrated CO2 removal with steam reforming

    DOE Patents [OSTI]

    Duraiswamy, Kandaswamy; Chellappa, Anand S

    2013-07-23

    A steam reformer may comprise fluid inlet and outlet connections and have a substantially cylindrical geometry divided into reforming segments and reforming compartments extending longitudinally within the reformer, each being in fluid communication. With the fluid inlets and outlets. Further, methods for generating hydrogen may comprise steam reformation and material adsorption in one operation followed by regeneration of adsorbers in another operation. Cathode off-gas from a fuel cell may be used to regenerate and sweep the adsorbers, and the operations may cycle among a plurality of adsorption enhanced reformers to provide a continuous flow of hydrogen.

  12. Investigation of Bio-Ethanol Steam Reforming over Cobalt-based...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation) Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation) Presented at the 2007...

  13. Methanol Steam Reformer on a Silicon Wafer

    SciTech Connect (OSTI)

    Park, H; Malen, J; Piggott, T; Morse, J; Sopchak, D; Greif, R; Grigoropoulos, C; Havstad, M; Upadhye, R

    2004-04-15

    A study of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabricated on a silicon wafer are presented. Comparison of computed and measured conversion efficiencies are shown to be favorable. Concepts for insulating the reactor while maintaining small overall size and starting operation from ambient temperature are analyzed.

  14. Steam Reforming of Low-Level Mixed Waste

    SciTech Connect (OSTI)

    1998-01-01

    Under DOE Contract No. DE-AR21-95MC32091, Steam Reforming of Low-Level Mixed Waste, ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design construction, and testing of the PDU as well as performance and economic projections for a 500- lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area published April 1997.1 The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfidly tested including a 750-hour test on material simulating a PCB- and Uranium- contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (>99.9999oA) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radlonuclides in the volume-reduced solids. Cost studies have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

  15. STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138

    SciTech Connect (OSTI)

    Burket, P

    2009-02-24

    This paper describes the design of the Bench-scale Steam Reformer (BSR); a processing unit for demonstrating steam reforming technology on actual radioactive waste [1]. It describes the operating conditions of the unit used for processing a sample of Savannah River Site (SRS) Tank 48H waste. Finally, it compares the results from processing the actual waste in the BSR to processing simulant waste in the BSR to processing simulant waste in a large pilot scale unit, the Fluidized Bed Steam Reformer (FBSR), operated at Hazen Research Inc. in Golden, CO. The purpose of this work was to prove that the actual waste reacted in the same manner as the simulant waste in order to validate the work performed in the pilot scale unit which could only use simulant waste.

  16. BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE

    SciTech Connect (OSTI)

    Burket, P; Gene Daniel, G; Charles Nash, C; Carol Jantzen, C; Michael Williams, M

    2008-09-25

    Fluidized Bed Steam Reforming (FBSR) has been demonstrated to be a viable technology to remove >99% of the organics from Tank 48H simulant, to remove >99% of the nitrate/nitrite from Tank 48H simulant, and to form a solid product that is primarily carbonate based. The technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration Fluidized Bed Steam Reformer1 (ESTD FBSR) at the Hazen Research Inc. (HRI) facility in Golden, CO. The purpose of the Bench-scale Steam Reformer (BSR) testing was to demonstrate that the same reactions occur and the same product is formed when steam reforming actual radioactive Tank 48H waste. The approach used in the current study was to test the BSR with the same Tank 48H simulant and same Erwin coal as was used at the ESTD FBSR under the same operating conditions. This comparison would allow verification that the same chemical reactions occur in both the BSR and ESTD FBSR. Then, actual radioactive Tank 48H material would be steam reformed in the BSR to verify that the actual tank 48H sample reacts the same way chemically as the simulant Tank 48H material. The conclusions from the BSR study and comparison to the ESTD FBSR are the following: (1) A Bench-scale Steam Reforming (BSR) unit was successfully designed and built that: (a) Emulated the chemistry of the ESTD FBSR Denitration Mineralization Reformer (DMR) and Carbon Reduction Reformer (CRR) known collectively as the dual reformer flowsheet. (b) Measured and controlled the off-gas stream. (c) Processed real (radioactive) Tank 48H waste. (d) Met the standards and specifications for radiological testing in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF). (2) Three runs with radioactive Tank 48H material were performed. (3) The Tetraphenylborate (TPB) was destroyed to > 99% for all radioactive Bench-scale tests. (4) The feed nitrate/nitrite was destroyed to >99% for all radioactive BSR tests the same as the ESTD FBSR. (5) The radioactive Tank 48H DMR product was primarily made up of soluble carbonates. The three most abundant species were thermonatrite, [Na{sub 2}CO{sub 3} {center_dot} H{sub 2}O], sodium carbonate, [Na{sub 2}CO{sub 3}], and trona, [Na{sub 3}H(CO{sub 3}){sub 2} {center_dot} 2H{sub 2}O] the same as the ESTD FBSR. (6) Insoluble solids analyzed by X-Ray Diffraction (XRD) did not detect insoluble carbonate species. However, they still may be present at levels below 2 wt%, the sensitivity of the XRD methodology. Insoluble solids XRD characterization indicated that various Fe/Ni/Cr/Mn phases are present. These crystalline phases are associated with the insoluble sludge components of Tank 48H slurry and impurities in the Erwin coal ash. The percent insoluble solids, which mainly consist of un-burnt coal and coal ash, in the products were 4 to 11 wt% for the radioactive runs. (7) The Fe{sup +2}/Fe{sub total} REDOX measurements ranged from 0.58 to 1 for the three radioactive Bench-scale tests. REDOX measurements > 0.5 showed a reducing atmosphere was maintained in the DMR indicating that pyrolysis was occurring. (8) Greater than 90% of the radioactivity was captured in the product for all three runs. (9) The collective results from the FBSR simulant tests and the BSR simulant tests indicate that the same chemistry occurs in the two reactors. (10) The collective results from the BSR simulant runs and the BSR radioactive waste runs indicates that the same chemistry occurs in the simulant as in the real waste. The FBSR technology has been proven to destroy the organics and nitrates in the Tank 48H waste and form the anticipated solid carbonate phases as expected.

  17. Steam reforming of low-level mixed waste. Final report

    SciTech Connect (OSTI)

    1998-06-01

    ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design, construction, and testing of the PDU as well as performance and economic projections for a 300-lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area and published in April 1997. The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfully tested including a 750-hour test on material simulating a PCB- and Uranium-contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (> 99.9999%) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radionuclides in the volume-reduced solids. Economic evaluations have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

  18. Modified Ni-Cu catalysts for ethanol steam reforming

    SciTech Connect (OSTI)

    Dan, M.; Mihet, M.; Almasan, V.; Borodi, G.; Katona, G.; Muresan, L.; Lazar, M. D.

    2013-11-13

    Three Ni-Cu catalysts, having different Cu content, supported on ?-alumina were synthesized by wet co-impregnation method, characterized and tested in the ethanol steam reforming (ESR) reaction. The catalysts were characterized for determination of: total surface area and porosity (N{sub 2} adsorption - desorption using BET and Dollimer Heal methods), Ni surface area (hydrogen chemisorption), crystallinity and Ni crystallites size (X-Ray Diffraction), type of catalytic active centers (Hydrogen Temperature Programmed Reduction). Total surface area and Ni crystallites size are not significantly influenced by the addition of Cu, while Ni surface area is drastically diminished by increasing of Cu concentration. Steam reforming experiments were performed at atmospheric pressure, temperature range 150-350°C, and ethanol - water molar ration of 1 at 30, using Ar as carrier gas. Ethanol conversion and hydrogen production increase by the addition of Cu. At 350°C there is a direct connection between hydrogen production and Cu concentration. Catalysts deactivation in 24h time on stream was studied by Transmission Electron Microscopy (TEM) and temperature-programmed reduction (TPR) on used catalysts. Coke deposition was observed at all studied temperatures; at 150°C amorphous carbon was evidenced, while at 350°C crystalline, filamentous carbon is formed.

  19. 976 JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 15, NO. 4, AUGUST 2006 Methanol Steam Reformer on a Silicon Wafer

    E-Print Network [OSTI]

    Malen, Jonathan A.

    of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabri- cated976 JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 15, NO. 4, AUGUST 2006 Methanol Steam Reformer is achieved through on-chip resis- tive heaters, whereby methanol steam reforming reactions were studied over

  20. Steam Reforming, 6-in. Bench-Scale Design and Testing Project -- Technical and Functional Requirements Description

    SciTech Connect (OSTI)

    Losinski, Sylvester John; Marshall, Douglas William

    2002-08-01

    Feasibility studies and technology development work are currently being performed on several processes to treat radioactive liquids and solids currently stored at the Idaho Nuclear Technology and Engineering Center (INTEC), located within the Idaho National Engineering and Environmental Laboratory (INEEL). These studies and development work will be used to select a treatment process for treatment of the radioactive liquids and solids to meet treatment milestones of the Settlement Agreement between the Department of Energy and the State of Idaho. One process under consideration for treating the radioactive liquids and solids, specifically Sodium-Bearing Waste (SBW) and tank heel solids, is fluid bed steam reforming (FBSR). To support both feasibility and development studies a bench-scale FBSR is being designed and constructed. This report presents the technical and functional requirements, experimental objectives, process flow sheets, and equipment specifications for the bench-scale FBSR.

  1. Integrated solar thermochemical reaction system for steam methane reforming

    SciTech Connect (OSTI)

    Zheng, Feng; Diver, Rich; Caldwell, Dustin D.; Fritz, Brad G.; Cameron, Richard J.; Humble, Paul H.; TeGrotenhuis, Ward E.; Dagle, Robert A.; Wegeng, Robert S.

    2015-06-05

    Solar-aided upgrade of the energy content of fossil fuels, such as natural gas, can provide a near-term transition path towards a future solar-fuel economy and reduce carbon dioxide emission from fossil fuel consumption. Both steam and dry reforming a methane-containing fuel stream have been studied with concentrated solar power as the energy input to drive the highly endothermic reactions but the concept has not been demonstrated at a commercial scale. Under a current project with the U.S. Department of Energy, PNNL is developing an integrated solar thermochemical reaction system that combines solar concentrators with micro- and meso-channel reactors and heat exchangers to accomplish more than 20% solar augment of methane higher heating value. The objective of our three-year project is to develop and prepare for commercialization such solar reforming system with a high enough efficiency to serve as the frontend of a conventional natural gas (or biogas) combined cycle power plant, producing power with a levelized cost of electricity less than 6¢/kWh, without subsidies, by the year 2020. In this paper, we present results from the first year of our project that demonstrated a solar-to-chemical energy conversion efficiency as high as 69% with a prototype reaction system.

  2. Integrated solar thermochemical reaction system for steam methane reforming

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Feng; Diver, Rich; Caldwell, Dustin D.; Fritz, Brad G.; Cameron, Richard J.; Humble, Paul H.; TeGrotenhuis, Ward E.; Dagle, Robert A.; Wegeng, Robert S.

    2015-06-05

    Solar-aided upgrade of the energy content of fossil fuels, such as natural gas, can provide a near-term transition path towards a future solar-fuel economy and reduce carbon dioxide emission from fossil fuel consumption. Both steam and dry reforming a methane-containing fuel stream have been studied with concentrated solar power as the energy input to drive the highly endothermic reactions but the concept has not been demonstrated at a commercial scale. Under a current project with the U.S. Department of Energy, PNNL is developing an integrated solar thermochemical reaction system that combines solar concentrators with micro- and meso-channel reactors and heatmore »exchangers to accomplish more than 20% solar augment of methane higher heating value. The objective of our three-year project is to develop and prepare for commercialization such solar reforming system with a high enough efficiency to serve as the frontend of a conventional natural gas (or biogas) combined cycle power plant, producing power with a levelized cost of electricity less than 6¢/kWh, without subsidies, by the year 2020. In this paper, we present results from the first year of our project that demonstrated a solar-to-chemical energy conversion efficiency as high as 69% with a prototype reaction system.« less

  3. Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts

    E-Print Network [OSTI]

    Blaylock, Donnie Wayne

    2011-01-01

    The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications including petrochemical processing and ammonia synthesis. ...

  4. Heat Transfer Limitations in Hydrogen Production Via Steam Reformation: The Effect of Reactor Geometry

    E-Print Network [OSTI]

    Vernon, David R.; Davieau, David D.; Dudgeon, Bryce A.; Erickson, Paul A.

    2006-01-01

    for on- board hydrogen production for fuel-cell poweredSteam-Reforming Hydrogen production Reactors, M.S. Thesis,at the UC Davis Hydrogen Production and Utilization

  5. Steam Reforming on Transition-metal Carbides from Density-functional Theory

    SciTech Connect (OSTI)

    Vojvodic, Aleksandra

    2012-05-11

    A screening study of the steam reforming reaction on clean and oxygen covered early transition-metal carbides surfaces is performed by means of density-functional theory calculations. It is found that carbides provide a wide spectrum of reactivities, from too reactive via suitable to too inert. Several molybdenum-based systems are identified as possible steam reforming catalysts. The findings suggest that carbides provide a playground for reactivity tuning, comparable to the one for pure metals.

  6. Solid oxide fuel cell steam reforming power system

    DOE Patents [OSTI]

    Chick, Lawrence A.; Sprenkle, Vincent L.; Powell, Michael R.; Meinhardt, Kerry D.; Whyatt, Greg A.

    2013-03-12

    The present invention is a Solid Oxide Fuel Cell Reforming Power System that utilizes adiabatic reforming of reformate within this system. By utilizing adiabatic reforming of reformate within the system the system operates at a significantly higher efficiency than other Solid Oxide Reforming Power Systems that exist in the prior art. This is because energy is not lost while materials are cooled and reheated, instead the device operates at a higher temperature. This allows efficiencies higher than 65%.

  7. New Insights into Reaction Mechanisms of Ethanol Steam Reforming on Co-ZrO2

    SciTech Connect (OSTI)

    Sun, Junming; Karim, Ayman M.; Mei, Donghai; Engelhard, Mark H.; Bao, Xinhe; Wang, Yong

    2015-01-01

    The reaction pathway of ethanol steam reforming on Co-ZrO2 has been identified and the active sites associated with each step are proposed. Ethanol is converted to acetaldehyde and then to acetone, followed by acetone steam reforming. More than 90% carbon was found to follow this reaction pathway. N2-Sorption, X-ray Diffraction (XRD), Temperature Programmed Reduction (TPR), in situ X-ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy, as well as theoretical Density Functional Theory (DFT) calculations have been employed to identify the structure and functionality of the catalysts, which was further used to correlate their performance in ESR. It was found that metallic cobalt is mainly responsible for the acetone steam reforming reactions; while, CoO and basic sites on the support play a key role in converting ethanol to acetone via dehydrogenation and condensation/ketonization reaction pathways. The current work provides fundamental understanding of the ethanol steam reforming reaction mechanisms on Co-ZrO2 catalysts and sheds light on the rational design of selective and durable ethanol steam reforming catalysts.

  8. Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer...

    Office of Environmental Management (EM)

    Hanford Envelope A composite (68 tank) simulant tested Redesigned for Shielded Cell Facility (SCF) in 2006 7 INEEL SAIC STAR FACILITY 6" TTT HAZEN FACILITY 6" TTT HAZEN FACILITY...

  9. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming...

    Office of Environmental Management (EM)

    River Company (WSRC) for the United States Department of Energy under Contract No. DEA-AC09-96SR18500 and is an account of work performed under that contract. Neither the...

  10. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaics »Tankless WaterEnergyJanuary28-982 DOE Hydrogen

  11. Steam Reforming Technology for Denitration and Immobilization of DOE Tank Wastes

    SciTech Connect (OSTI)

    Mason, J. B.; McKibbin, J.; Ryan, K.; Schmoker, D.

    2003-02-26

    THOR Treatment Technologies, LLC (THOR) is a joint venture formed in June 2002 by Studsvik, Inc. (Studsvik) and Westinghouse Government Environmental Services Company LLC to further develop, market, and deploy Studsvik's patented THORSM non-incineration, steam reforming waste treatment technology. This paper provides an overview of the THORSM steam reforming process as applied to the denitration and conversion of Department of Energy (DOE) tank wastes to an immobilized mineral form. Using the THORSM steam reforming technology to treat nitrate containing tank wastes could significantly benefit the DOE by reducing capital and life-cycle costs, reducing processing and programmatic risks, and positioning the DOE to meet or exceed its stakeholder commitments for tank closure. Specifically, use of the THORSM technology can facilitate processing of up to 75% of tank wastes without the use of vitrification, yielding substantial life-cycle cost savings.

  12. Promotion effect of cobalt-based catalyst with rare earth for the ethanol steam reforming

    SciTech Connect (OSTI)

    Chiou, Josh Y. Z.; Chen, Ya-Ping; Yu, Shen-Wei; Wang, Chen-Bin

    2013-12-16

    Catalytic performance of ethanol steam reforming (ESR) was investigated on praseodymium (Pr) modified ceria-supported cobalt oxide catalyst. The ceria-supported cobalt oxide (Ce-Co) catalyst was prepared by co-precipitation-oxidation (CPO) method, and the doped Pr (5 and 10 wt% loading) catalysts (Pr{sub 5}?Ce?Co and Pr{sub 10}?Ce?Co) were prepared by incipient wetness impregnation method. The reduction pretreatment under 250 and 400 °C (H250 and H400) was also studied. All samples were characterized by XRD, TPR and TEM. Catalytic performance of ESR was tested from 250 to 500 °C in a fixed-bed reactor. The doping of Pr into the ceria lattice has significantly promoted the activity and reduced the coke formation. The products distribution also can be influenced by the different reduction pretreatment. The Pr{sub 10}?Ce?Co?H400 sample is a preferential ESR catalyst, where the hydrogen distribution approaches 73% at 475 °C with less amounts (< 2%) of CO and CH{sub 4}.

  13. Hydrogen production from the steam reforming of Dinethyl Ether and Methanol

    SciTech Connect (OSTI)

    Semelsberger, T. A.; Borup, R. L.

    2004-01-01

    This study investigates dimethyl ether (DME) steam reforming for the generation of hydrogen rich fuel cell feeds for fuel cell applications. Methanol has long been considered as a fuel for the generation of hydrogen rich fuel cell feeds due to its high energy density, low reforming temperature, and zero impurity content. However, it has not been accepted as the fuel of choice due its current limited availability, toxicity and corrosiveness. While methanol steam reforming for the generation of hydrogen rich fuel cell feeds has been extensively studied, the steam reforming of DME, CH{sub 3}OCH{sub 3} + 3H{sub 2}O = 2CO{sub 2} + 6H{sub 2}, has had limited research effort. DME is the simplest ether (CH{sub 3}OCH{sub 3}) and is a gas at ambient conditions. DME has physical properties similar to those of LPG fuels (i.e. propane and butane), resulting in similar storage and handling considerations. DME is currently used as an aerosol propellant and has been considercd as a diesel substitute due to the reduced NOx, SOx and particulate emissions. DME is also being considered as a substitute for LPG fuels, which is used extensively in Asia as a fuel for heating and cooking, and naptha, which is used for power generation. The potential advantages of both methanol and DME include low reforming temperature, decreased fuel proccssor startup energy, environmentally benign, visible flame, high heating value, and ease of storage and transportation. In addition, DME has the added advantages of low toxicity and being non-corrosive. Consequently, DME may be an ideal candidate for the generation of hydrogen rich fuel cell feeds for both automotive and portable power applications. The steam reforming of DME has been demonstrated to occur through a pair of reactions in series, where the first reaction is DME hydration followed by MeOH steam reforming to produce a hydrogen rich stream.

  14. Feasibility Analysis of Steam Reforming of Biodiesel by-product Glycerol to Make Hydrogen 

    E-Print Network [OSTI]

    Joshi, Manoj

    2009-06-09

    ) reaction where it reacts with excess steam in presence of catalyst to form hydrogen and carbon dioxide. In general, 8 Co/MgO, Co/Al2O3, Ni/MgO is used as catalyst for steam reforming because they are cheaper and easily available. During... hydrogen. This process consists of 850oC reformer, 350oC and 210oC shift reactors for water gas shift reaction, flash tanks, and a separator. It is considered to be the least expensive method. iv At 850oC and 1 atm pressure, glycerol reacts...

  15. Steam reforming of fuel to hydrogen in fuel cells

    DOE Patents [OSTI]

    Fraioli, Anthony V. (Hawthorne Woods, IL); Young, John E. (Woodridge, IL)

    1984-01-01

    A fuel cell capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

  16. Steam reforming of fuel to hydrogen in fuel cell

    DOE Patents [OSTI]

    Young, J.E.; Fraioli, A.V.

    1983-07-13

    A fuel cell is described capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

  17. CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101/102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER

    SciTech Connect (OSTI)

    DUNCAN JB; HUBER HJ

    2011-06-08

    This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-10-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FB SR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-S.2.1-20 1 0-00 1, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, 'Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.'

  18. CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER

    SciTech Connect (OSTI)

    DUNCAN JB; HUBER HJ

    2011-04-21

    This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-l0-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FBSR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-5.2.1-2010-001, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.

  19. First-Principles Study on the Origin of the Different Selectivities for Methanol Steam Reforming on Cu(111) and Pd(111)

    E-Print Network [OSTI]

    Li, Weixue

    different catalytic processes, including methanol decomposition (eq 1), methanol steam reforming (eq 2First-Principles Study on the Origin of the Different Selectivities for Methanol Steam Reforming steam reforming (MSR) is an important industrial process for hydrogen production, and fundamental

  20. Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical Discharge

    E-Print Network [OSTI]

    Mallinson, Richard

    and carbon monoxide, is an important raw material in chemical manufacture such as, Fischer-Tropsch synthesis and Materials Science, University of Oklahoma, Norman, Oklahoma 73019 An experimental study of synthesis gas production has been steam reforming, shown in reaction 4. It is very useful to use low-cost materials

  1. Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon

    DOE Patents [OSTI]

    Sircar, Shivaji (Wescosville, PA); Hufton, Jeffrey Raymond (Fogelsville, PA); Nataraj, Shankar (Allentown, PA)

    2000-01-01

    In the steam reforming of hydrocarbon, particularly methane, under elevated temperature and pressure to produce hydrogen, a feed of steam and hydrocarbon is fed into a first reaction volume containing essentially only reforming catalyst to partially reform the feed. The balance of the feed and the reaction products of carbon dioxide and hydrogen are then fed into a second reaction volume containing a mixture of catalyst and adsorbent which removes the carbon dioxide from the reaction zone as it is formed. The process is conducted in a cycle which includes these reactions followed by countercurrent depressurization and purge of the adsorbent to regenerate it and repressurization of the reaction volumes preparatory to repeating the reaction-sorption phase of the cycle.

  2. Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis

    SciTech Connect (OSTI)

    T.A. Semelsberger

    2004-10-01

    The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

  3. Pebble Bed Boiling Water Reactor Concept With Superheated Steam

    SciTech Connect (OSTI)

    Tsiklauri, G.; Newman, D.; Meriwether, G.; Korolev, V. [Pacific Northwest National Laboratory, P.O. Box 999 Richland, WA 99352 (United States)

    2002-07-01

    An Advanced Nuclear Reactor concept is presented which extends Boiling Water Reactor technology with micro-fuel elements (MFE) and produces superheated steam. A nuclear plant with MFE is highly efficient and safe, due to ceramic-clad nuclear fuel. Water is used as both moderator and coolant. The fuel consists of spheres of about 1.5 mm diameter of UO{sub 2} with several external coatings of different carbonaceous materials. The outer coating of the particles is SiC, manufactured with chemical vapor disposition (CVD) technology. Endurance of the integrity of the SiC coating in water, air and steam has been demonstrated experimentally in Germany, Russia and Japan. This paper describes a result of a preliminary design and analysis of 3750 MWt (1500 MWe) plant with standard pressure of 16 MPa, which is widely achieved in the vessel of pressurized-water type reactors. The superheated steam outlet temperature of 550 deg. C elevates the steam cycle to high thermal efficiency of 42%. (authors)

  4. Investigation of Reaction Networks and Active Sites In Bio-Ethanol Steam Reforming Over Co-Based Catalysts

    Broader source: Energy.gov [DOE]

    Paper by Umit S. Ozkan, Hua Song, and Lingzhi Zhang (Ohio State University) on the fundamental understanding of reaction networks, active sites of deactivation mechanisms of potential bio-ethanol steam reforming catalysts.

  5. Process Options Description for Steam Reforming Flowsheet Model of INEEL Tank Farm Waste

    SciTech Connect (OSTI)

    Taylor, D.D.; Barnes, C.M.; Nichols, T.T.

    2002-05-21

    Technical information is provided herein that is required for development of a steady-state process simulation of a baseline steam reforming treatment train for Tank Farm waste at the Idaho National Engineering and Environmental Laboratory (INEEL). This document supercedes INEEL/EXT-2001-173, produced in FY2001 to support simulation of the direct vitrification treatment train which was the previous process baseline. A process block flow diagram for steam reforming is provided, together with a list of unit operations which constitute the process. A detailed description of each unit operation is given which includes its purpose, principal phenomena present, expected pressure and temperature ranges, key chemical species in the inlet steam, and the proposed manner in which the unit operation is to be modeled in the steady state process simulation. Models for the unit operations may be mechanistic (based on first principles), empirical (based solely on pilot test data without extrapolation) , or by correlations (based on extrapolative or statistical schemes applied to pilot test data). Composition data for the expected process feed streams is provided.

  6. Ethanol Steam Reforming on Co/CeO2: The Effect of ZnO Promoter

    SciTech Connect (OSTI)

    Davidson, Stephen; Sun, Junming; Wang, Yong

    2013-12-02

    A series of ZnO promoted Co/CeO2 catalysts were synthesized and characterized using XRD, TEM, H2-TPR, CO chemisorption, O2-TPO, IR-Py, and CO2-TPD. The effects of ZnO on the catalytic performances of Co/CeO2 were studied in ethanol steam reforming. It was found that the addition of ZnO facilitated the oxidation of Co0 via enhanced oxygen mobility of the CeO2 support which decreased the activity of Co/CeO2 in C–C bond cleavage of ethanol. 3 wt% ZnO promoted Co/CeO2 exhibited minimum CO and CH4 selectivity and maximum CO2 selectivity. This resulted from the combined effects of the following factors with increasing ZnO loading: (1) enhanced oxygen mobility of CeO2 facilitated the oxidation of CHx and CO to form CO2; (2) increased ZnO coverage on CeO2 surface reduced the interaction between CHx/CO and Co/CeO2; and (3) suppressed CO adsorption on Co0 reduced CO oxidation rate to form CO2. In addition, the addition of ZnO also modified the surface acidity and basicity of CeO2, which consequently affected the C2–C4 product distributions.

  7. Reforming of Diesel Fuel for Transportation Applications J. P. Kopasz, S. Lottes, D-J. Liu, R. Ahluwalia, V. Novick and S. Ahmed

    E-Print Network [OSTI]

    , steam and water prior to catalyst bed 3-fluid nozzle delivers a fine mist of fuel #12;ReformingReforming of Diesel Fuel for Transportation Applications J. P. Kopasz, S. Lottes, D-J. Liu, R. Ahluwalia, V. Novick and S. Ahmed Argonne National Laboratory Applications of diesel fuel reforming

  8. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts

    SciTech Connect (OSTI)

    Mei, Donghai; Lebarbier, Vanessa MC; Rousseau, Roger J.; Glezakou, Vassiliki Alexandra; Albrecht, Karl O.; Kovarik, Libor; Flake, Matthew D.; Dagle, Robert A.

    2013-06-01

    In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl2O4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl2O4 spinel support are stable during the BSR in the temperature range of 700-850?C. Compared to the Ir/MgAl2O4 catalyst, the Rh/MgAl2O4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function of the H2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR activity on the supported highly dispersed Rh catalyst can be rationalized by the thermodynamic limitation for the very first C-C bond scission of benzene on the small Ir50 catalyst. The C-C bond scission of benzene on the small Ir50 catalyst is highly endothermic although the barrier is competitive with the barriers of both the C-C and the C-H bond-breakings on the small Rh50 catalyst. The calculations also imply that, for the supported Rh catalysts the C-C and C-H bond scissions are competitive, independently of the Rh cluster sizes. After the initial dissociation step via either the C-C or the C-H bond scission, the C-H bond breaking seems to be more favorable rather than the C-C bond breaking on the larger Rh terrace surface. This work was financially supported by the United States Department of Energy’s Office of Biomass Program’s. Computing time was granted by a user project at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  9. NiW and NiRu Bimetallic Catalysts for Ethylene Steam Reforming: Alternative Mechanisms for Sulfur Resistance

    SciTech Connect (OSTI)

    Rangan, M.; Yung, M. M.; Medlin, J. W.

    2012-06-01

    Previous investigations of Ni-based catalysts for the steam reforming of hydrocarbons have indicated that the addition of a second metal can reduce the effects of sulfur poisoning. Two systems that have previously shown promise for such applications, NiW and NiRu, are considered here for the steam reforming of ethylene, a key component of biomass derived tars. Monometallic and bimetallic Al{sub 2}O{sub 3}-supported Ni and W catalysts were employed for ethylene steam reforming in the presence and absence of sulfur. The NiW catalysts were less active than Ni in the absence of sulfur, but were more active in the presence of 50 ppm H{sub 2}S. The mechanism for the W-induced improvements in sulfur resistance appears to be different from that for Ru in NiRu. To probe reasons for the sulfur resistance of NiRu, the adsorption of S and C{sub 2}H{sub 4} on several bimetallic NiRu alloy surfaces ranging from 11 to 33 % Ru was studied using density functional theory (DFT). The DFT studies reveal that sulfur adsorption is generally favored on hollow sites containing Ru. Ethylene preferentially adsorbs atop the Ru atom in all the NiRu (111) alloys investigated. By comparing trends across the various bimetallic models considered, sulfur adsorption was observed to be correlated with the density of occupied states near the Fermi level while C{sub 2}H{sub 4} adsorption was correlated with the number of unoccupied states in the d-band. The diverging mechanisms for S and C{sub 2}H{sub 4} adsorption allow for bimetallic surfaces such as NiRu that enhance ethylene binding without accompanying increases in sulfur binding energy. In contrast, bimetallics such as NiSn and NiW appear to decrease the affinity of the surface for both the reagent and the poison.

  10. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    Using Self-Sustained Hydro- Gasification." [0011] In aprocess, using a steam hydro-gasification reactor (SHR) thepyrolysis and hydro-gasification in a single step. This

  11. Hydrogen generation having CO.sub.2 removal with steam reforming

    SciTech Connect (OSTI)

    Kandaswamy, Duraiswamy; Chellappa, Anand S.; Knobbe, Mack

    2015-07-28

    A method for producing hydrogen using fuel cell off gases, the method feeding hydrocarbon fuel to a sulfur adsorbent to produce a desulfurized fuel and a spent sulfur adsorbent; feeding said desulfurized fuel and water to an adsorption enhanced reformer that comprises of a plurality of reforming chambers or compartments; reforming said desulfurized fuel in the presence of a one or more of a reforming catalyst and one or more of a CO.sub.2 adsorbent to produce hydrogen and a spent CO.sub.2 adsorbent; feeding said hydrogen to the anode side of the fuel cell; regenerating said spent CO.sub.2 adsorbents using the fuel cell cathode off-gases, producing a flow of hydrogen by cycling between said plurality of reforming chambers or compartments in a predetermined timing sequence; and, replacing the spent sulfur adsorbent with a fresh sulfur adsorbent at a predetermined time.

  12. Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.; Valenta, Michelle M.; Pires, Richard P.

    2011-09-12

    The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sent to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.

  13. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    OF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BED REACTOROF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BED REACTOR F Iis fed into a hydro-gasifier reactor. One such process was

  14. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    OPERATION OF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BEDMaterial Using Self-Sustained Hydro- Gasification." [0011]the process, using a steam hydro-gasification reactor (SHR)

  15. Catalytic roles of Co0 and Co2+ during steam reforming of ethanol on Co/MgO catalysts

    SciTech Connect (OSTI)

    Karim, Ayman M.; Su, Yu; Engelhard, Mark H.; King, David L.; Wang, Yong

    2011-02-25

    Abstract: The catalytic roles of Co0 and Co2+ during steam reforming of ethanol were investigated over Co/MgO catalysts. Catalysts with different Co0/(Co0+Co2+) fraction were prepared through calcination and/or reduction at different temperatures, and the Co0 fraction was quantified by TPR and in-situ XPS. High temperature calcination of Co/MgO allowed us to prepare catalysts with more non-reducible Co2+ incorporated in the MgO lattice, while lower calcination temperatures allowed for the preparation of catalysts with higher Co0/(Co0+Co2+) fractions. The catalytic tests on Co0, non-reducible Co2+, and reducible Co2+ indicated that Co0 is much more active than either reducible or non-reducible Co2+ for C-C cleavage and water gas shift reaction. In addition, catalysts with a higher Co0 surface fraction exhibited a lower selectivity to CH4.

  16. Attrition resistant fluidizable reforming catalyst

    DOE Patents [OSTI]

    Parent, Yves O. (Golden, CO); Magrini, Kim (Golden, CO); Landin, Steven M. (Conifer, CO); Ritland, Marcus A. (Palm Beach Shores, FL)

    2011-03-29

    A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

  17. Demonstration of a Highly Efficient Solid Oxide Fuel Cell Power System Using Adiabatic Steam Reforming and Anode Gas Recirculation

    SciTech Connect (OSTI)

    Powell, Michael R.; Meinhardt, Kerry D.; Sprenkle, Vincent L.; Chick, Lawrence A.; Mcvay, Gary L.

    2012-05-01

    Solid oxide fuel cells (SOFC) are currently being developed for a wide variety of applications because of their high efficiency at multiple power levels. Applications for SOFCs encompass a large range of power levels including 1-2 kW residential combined heat and power applications, 100-250 kW sized systems for distributed generation and grid extension, and MW-scale power plants utilizing coal. This paper reports on the development of a highly efficient, small-scale SOFC power system operating on methane. The system uses adiabatic steam reforming of methane and anode gas recirculation to achieve high net electrical efficiency. The anode exit gas is recirculated and all of the heat and water required for the endothermic reforming reaction are provided by the anode gas emerging from the SOFC stack. Although the single-pass fuel utilization is only about 55%, because of the anode gas recirculation the overall fuel utilization is up to 93%. The demonstrated system achieved gross power output of 1650 to 2150 watts with a maximum net LHV efficiency of 56.7% at 1720 watts. Overall system efficiency could be further improved to over 60% with use of properly sized blowers.

  18. Fixed Bed Countercurrent Low Temperature Gasification of Dairy Biomass and Coal-Dairy Biomass Blends Using Air-Steam as Oxidizer 

    E-Print Network [OSTI]

    Gordillo Ariza, Gerardo

    2010-10-12

    W) countercurrent fixed bed gasifier was rebuilt to perform gasification studies under quasisteady state conditions using dairy biomass (DB) as feedstock and various air-steam mixtures as oxidizing sources. A DB-ash (from DB) blend and a DB-Wyoming coal blend were...

  19. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernandez-Garica, Marcos; et al

    2014-11-26

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (more »The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.« less

  20. High Activity of Ce1-xNixO2-y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions

    SciTech Connect (OSTI)

    G Zhou; L Barrio; S Agnoli; S Senanayake; J Evans; A Kubacka; M Estrella; J Hanson; A Martinez-Arias; et al.

    2011-12-31

    The importance of the oxide: Ce{sub 0.8}Ni{sub 0.2}O{sub 2-y} is an excellent catalyst for ethanol steam reforming. Metal-oxide interactions perturb the electronic properties of the small particles of metallic nickel present in the catalyst under the reaction conditions and thus suppress any methanation activity. The nickel embedded in ceria induces the formation of O vacancies, which facilitate cleavage of the OH bonds in ethanol and water.

  1. Fixed Bed Counter Current Gasification of Mesquite and Juniper Biomass Using Air-steam as Oxidizer 

    E-Print Network [OSTI]

    Chen, Wei 1981-

    2012-11-27

    with them, and it gave me so much energy. I wish to acknowledge the financial support from Texas AgriLife Research State Bioenergy Initiative Funding and U.S. Department of Energy-NREL, Golden, Colorado. vi NOMENCLATURE Symbol Definition... rate of shift reaction Xi Moles fraction of each fuel product Yi Mass fraction of oxidizer ?HR Enthalpy of reaction ?Gas,E Energy conversion efficiency ? Air density (kg/m3) ? Latent heat of the water (kj/Kg) ? Bed porosity or void...

  2. Fluidized-bed technology enabling the integration of high temperature solar receiver CSP systems with steam and advanced power cycles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sakadjian, B.; Hu, S.; Maryamchik, M.; Flynn, T.; Santelmann, K.; Ma, Z.

    2015-05-01

    Solar Particle Receivers (SPR) are under development to drive concentrating solar plants (CSP) towards higher operating temperatures to support higher efficiency power conversion cycles. The novel high temperature SPR-based CSP system uses solid particles as the heat transfer medium (HTM) in place of the more conventional fluids such as molten salt or steam used in current state-of-the-art CSP plants. The solar particle receiver (SPR) is designed to heat the HTM to temperatures of 800 °C or higher which is well above the operating temperatures of nitrate-based molten salt thermal energy storage (TES) systems. The solid particles also help overcome somemore »of the other challenges associated with molten salt-based systems such as freezing, instability and degradation. The higher operating temperatures and use of low cost HTM and higher efficiency power cycles are geared towards reducing costs associated with CSP systems. This paper describes the SPR-based CSP system with a focus on the fluidized-bed (FB) heat exchanger and its integration with various power cycles. The SPR technology provides a potential pathway to achieving the levelized cost of electricity (LCOE) target of $0.06/kWh that has been set by the U.S. Department of Energy's SunShot initiative.« less

  3. Modeling the Effects of Steam-Fuel Reforming Products on Low Temperature Combustion of n-Heptane

    Broader source: Energy.gov [DOE]

    The effects of blends of base fuel (n-heptane) and fuel-reformed products on the low-temperature combustion process were investigated.

  4. Integrated reformer and shift reactor

    DOE Patents [OSTI]

    Bentley, Jeffrey M.; Clawson, Lawrence G.; Mitchell, William L.; Dorson, Matthew H.

    2006-06-27

    A hydrocarbon fuel reformer for producing diatomic hydrogen gas is disclosed. The reformer includes a first reaction vessel, a shift reactor vessel annularly disposed about the first reaction vessel, including a first shift reactor zone, and a first helical tube disposed within the first shift reactor zone having an inlet end communicating with a water supply source. The water supply source is preferably adapted to supply liquid-phase water to the first helical tube at flow conditions sufficient to ensure discharge of liquid-phase and steam-phase water from an outlet end of the first helical tube. The reformer may further include a first catalyst bed disposed in the first shift reactor zone, having a low-temperature shift catalyst in contact with the first helical tube. The catalyst bed includes a plurality of coil sections disposed in coaxial relation to other coil sections and to the central longitudinal axis of the reformer, each coil section extending between the first and second ends, and each coil section being in direct fluid communication with at least one other coil section.

  5. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    SciTech Connect (OSTI)

    Rodriguez, Jose A.; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernandez-Garica, Marcos; Senanayake, Sanjaya D.

    2014-11-26

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (< 2 nm) outside the Ni-W-Ce oxide structure. The nano NiO was reduced to Ni under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.

  6. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York Stony Brook, Stony Brook, NY (United States); Liu, Zongyuan [Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York Stony Brook, Stony Brook, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Yao, Siyu [Brookhaven National Lab. (BNL), Upton, NY (United States); Johnson-Peck, Aaron C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhao, Fuzhen [Brookhaven National Lab. (BNL), Upton, NY (United States); Michorczyk, Piotr [Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Kubacka, Anna [Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Stach, Eric A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Fernandez-Garica, Marcos [State Univ. of New York Stony Brook, Stony Brook, NY (United States); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (< 2 nm) outside the Ni-W-Ce oxide structure. The nano NiO was reduced to Ni under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.

  7. Superior performance of Ni–W–Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernández-García, Marcos; Senanayake, Sanjaya D.; et al

    2014-11-26

    In this study, the ethanol steam reforming (ESR) reaction was examined over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (more »under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.« less

  8. Bimetallic Ni-Rh catalysts with low amounts of Rh for the steam and autothermal reforming of n-butane for fuel-cell applications.

    SciTech Connect (OSTI)

    Ferrandon, M.; Kropf, A. J.; Krause, T.; Chemical Sciences and Engineering Division

    2010-05-15

    Mono-metallic nickel and rhodium catalysts and bimetallic Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}, CeZrO{sub 2} and CeMgOx were prepared and evaluated for catalyzing the steam and autothermal reforming of n-butane. The binary Ni-Rh supported on La-Al{sub 2}O{sub 3} catalysts with low weight loading of rhodium exhibited higher H{sub 2} yields than Ni or Rh alone. The Ni-Rh/CeZrO{sub 2} catalyst exhibited higher performance and no coke formation, compared to the same metals on other supports. A NiAl{sub 2}O{sub 4} spinel phase was obtained on all Ni and Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}. The presence of rhodium stabilized the spinel phase as well as NiOx species upon reforming while Ni alone was mostly reduced into metallic species. Extended X-ray absorption fine-structure analysis showed evidence of Ni-Rh alloy during preparation and even further after an accelerated aging at 900C in a H{sub 2}/H{sub 2}O atmosphere.

  9. Comparative Study on the Sulfur Tolerance and Carbon Resistance of Supported Noble Metal Catalysts in Steam Reforming of Liquid Hydrocarbon Fuel

    SciTech Connect (OSTI)

    Xie, Chao; Chen, Yongsheng; Engelhard, Mark H.; Song, Chunshan

    2012-04-18

    This work was conducted to clarify the influence of the type of metal and support on the sulfur tolerance and carbon resistance of supported noble metal catalysts in steam reforming of liquid hydrocarbons. Al2O3-supported noble metal catalysts (Rh, Ru, Pt, and Pd), Rh catalysts on different supports (Al2O3, CeO2, SiO2, and MgO), and Pt catalyst supported on CeO2 and Al2O3, were examined for steam reforming of a liquid hydrocarbon fuel (Norpar13 from Exxon Mobil) at 800 C for 55 h. The results indicate that (1) Rh/Al2O3 shows higher sulfur tolerance than the Ru, Pt, and Pd catalysts on the same support; (2) both Al2O3 and CeO2 are promising supports for Rh catalyst to process sulfur-containing hydrocarbons; and (3) Pt/CeO2 exhibits better catalytic performance than Pt/Al2O3 in the reaction with sulfur. TEM results demonstrate that the metal particles in Rh/Al2O3 were better dispersed (mostly in 1-3 nm) compared with the other catalysts after reforming the sulfur-containing feed. As revealed by XPS, the binding energy of Rh 3d for Rh/Al2O3 is notably higher than that for Rh/CeO2, implying the formation of electron-deficient Rh particles in the former. The strong sulfur tolerance of Rh/Al2O3 may be related to the formation of well-dispersed electron-deficient Rh particles on the Al2O3 support. Sulfur K-edge XANES illustrates the preferential formation of sulfonate and sulfate on Rh/Al2O3, which is believed to be beneficial for improving its sulfur tolerance as their oxygen-shielded sulfur structure may hinder direct Rh-S interaction. Due to its strong sulfur tolerance, the carbon deposition on Rh/Al2O3 was significantly lower than that on the Al2O3-supported Ru, Pt, and Pd catalysts after the reaction with sulfur. The superior catalytic performance of CeO2-supported Rh and Pt catalysts in the presence of sulfur can be ascribed mainly to the promotion effect of CeO2 on carbon gasification, leading to much lower carbon deposition compared with the Rh/Al2O3, Rh/MgO, Rh/SiO2 and Pt/Al2O3 catalysts.

  10. Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study

    SciTech Connect (OSTI)

    Mei, Donghai; Glezakou, Vassiliki Alexandra; Lebarbier, Vanessa MC; Kovarik, Libor; Wan, Haiying; Albrecht, Karl O.; Gerber, Mark A.; Rousseau, Roger J.; Dagle, Robert A.

    2014-07-01

    In this work we present a combined experimental and theoretical investigation of stable MgAl2O4 spinel-supported Rh and Ir catalysts for the steam methane reforming (SMR) reaction. Firstly, catalytic performance for a series of noble metal catalysts supported on MgAl2O4 spinel was evaluated for SMR at 600-850°C. Turnover rate at 850°C follows the order: Pd > Pt > Ir > Rh > Ru > Ni. However, Rh and Ir were found to have the best combination of activity and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed ~2 nm Rh and ~1 nm Ir clusters were formed on the MgAl2O4 spinel support. Scanning Transition Electron Microscopy (STEM) images show that excellent dispersion was maintained even under challenging high temperature conditions (e.g. at 850°C in the presence of steam) while Ir and Rh catalysts supported on Al2O3 were observed to sinter at increased rates under the same conditions. These observations were further confirmed by ab initio molecular dynamics (AIMD) simulations which find that ~1 nm Rh and Ir particles (50-atom cluster) bind strongly to the MgAl2O4 surfaces via a redox process leading to a strong metal-support interaction, thus helping anchor the metal clusters and reduce the tendency to sinter. Density functional theory (DFT) calculations suggest that these supported smaller Rh and Ir particles have a lower work function than larger more bulk-like ones, which enables them to activate both water and methane more effectively than larger particles, yet have a minimal influence on the relative stability of coke precursors. In addition, theoretical mechanistic studies were used to probe the relationship between structure and reactivity. Consistent with the experimental observations, our theoretical modeling results also suggest that the small spinel-supported Ir particle catalyst is more active than the counterpart of Rh catalyst for SMR. This work was financially supported by the United States Department of Energy (DOE)’s Bioenergy Technologies Office (BETO) and performed at the Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated for DOE by Battelle Memorial Institute. Computing time was granted by a user proposal at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) located at PNNL. Part of the computational time was provided by the National Energy Research Scientific Computing Center (NERSC).

  11. Mechanistic insights of ethanol steam reforming over Ni-CeOx(111): The importance of hydroxyl groups for suppressing coke formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Senanayake, Sanjaya D.; Duchon, Tomas; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolin, Vladimir; Stacchiola, Dario J.; et al

    2015-07-10

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³? concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themore »active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.« less

  12. The influence of nano-architectured CeOx supports in RhPd/CeO? for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO? cubes and CeO? rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO?-cubes > RhPd/CeO? -rods > RhPd/CeO?- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO?-cubes and RhPd/CeO? -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more »oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  13. Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Ducho?, Tomáš; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolín, Vladimir; Stacchiola, Dario J.; Rodriguez, José A.; et al

    2015-07-30

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³? concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themore »active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.« less

  14. Slab reformer

    DOE Patents [OSTI]

    Spurrier, F.R.; DeZubay, E.A.; Murray, A.P.; Vidt, E.J.

    1984-02-07

    Slab-shaped high efficiency catalytic reformer configurations are disclosed particularly useful for generation of fuels to be used in fuel cell based generation systems. A plurality of structures forming a generally rectangular peripheral envelope are spaced about one another to form annular regions, an interior annular region containing a catalytic bed and being regeneratively heated on one side by a hot combustion gas and on the other side by the gaseous products of the reformation. An integrally mounted combustor is cooled by impingement of incoming oxidant. 14 figs.

  15. Slab reformer

    DOE Patents [OSTI]

    Spurrier, Francis R. (Whitehall, PA); DeZubay, Egon A. (Mt. Lebanon, PA); Murray, Alexander P. (Murrysville, PA); Vidt, Edward J. (Churchill, PA)

    1985-03-12

    Slab-shaped high efficiency catalytic reformer configurations particularly useful for generation of fuels to be used in fuel cell based generation systems. A plurality of structures forming a generally rectangular peripheral envelope are spaced about one another to form annular regions, an interior annular region containing a catalytic bed and being regeneratively heated on one side by a hot combustion gas and on the other side by the gaseous products of the reformation. An integrally mounted combustor is cooled by impingement of incoming oxidant.

  16. Slab reformer

    DOE Patents [OSTI]

    Spurrier, Francis R. (Whitehall, PA); DeZubay, Egon A. (Mt. Lebanon, PA); Murray, Alexander P. (Murrysville, PA); Vidt, Edward J. (Churchill, PA)

    1984-02-07

    Slab-shaped high efficiency catalytic reformer configurations particularly useful for generation of fuels to be used in fuel cell based generation systems. A plurality of structures forming a generally rectangular peripheral envelope are spaced about one another to form annular regions, an interior annular region containing a catalytic bed and being regeneratively heated on one side by a hot comubstion gas and on the other side by the gaseous products of the reformation. An integrally mounted combustor is cooled by impingement of incoming oxidant.

  17. Steam gasification of coal at low-medium (600-800{sup o}C) temperature with simultaneous CO{sub 2} capture in a bubbling fluidized bed at atmospheric pressure. 2. Results and recommendations for scaling up

    SciTech Connect (OSTI)

    Corella, J.; Toledo, J.M.; Molina, G. [Universidad Complutense de Madrid, Madrid (Spain). Dept. of Chemical Engineering

    2008-03-19

    A gasification gas with an H{sub 2} content as high as 80 vol %, dry basis has been obtained by gasification of coal with pure steam at 600-800{sup o}C. The gasifier used was an atmospheric and bubbling fluidized bed operating with CaO in the bed as the CO{sub 2} sorbent. The research was carried out at a small pilot plant scale with continuous feeding of coal and batch mode introduction of the CaO. The gas composition and gas quality (tar content) is given for the following variables of operation: (a) type of in-bed sorbent used, (b) the amount of CaO in the bed related to the amount of coal fed, (c) temperature in the gasifier bed, (d) weight hourly space velocity (h{sup -1}) of the coal in the gasifier, and (e) time(-on-stream). To capture CaO at atmospheric pressure, the gasification with in-bed CaO had to be carried out at low-medium (600-800{sup o}C) gasification temperatures. For this reason, the tar content in the gasification gas was high (up to 52 g/Nm{sup 3}), which lowered the value of the H{sub 2}-rich gasification raw gas. It is demonstrated that a gas rich in H{sub 2} (80 vol % H{sub 2}, dry basis), and with very low CO{sub 2} and tar contents, can be obtained only if the coal gasification, at atmospheric pressure and with pure steam, is carried out at (CaO/coal) ratios above 10-15.

  18. Modeling of Pressurized Electrochemistry and Steam-Methane Reforming in Solid Oxide Fuel Cells and the Effects on Thermal and Electrical Stack Performance

    SciTech Connect (OSTI)

    Recknagle, Kurtis P.; Khaleel, Mohammad A.

    2009-03-01

    Summarizes work done to extend the electrochemical performance and methane reforming submodels to include the effects of pressurization and to demonstrate this new modeling capability by simulating large stacks operating on methane-rich fuel under pressurized and non-pressurized conditions. Pressurized operation boosts electrochemical performance, alters the kinetics of methane reforming, and effects the equilibrium composition of methane fuels. This work developed constitutive submodels that couple the electrochemistry, reforming, and pressurization to yield an increased capability of the modeling tool for prediction of SOFC stack performance.

  19. Process for purifying geothermal steam

    DOE Patents [OSTI]

    Li, Charles T. (Richland, WA)

    1980-01-01

    Steam containing hydrogen sulfide is purified and sulfur recovered by passing the steam through a reactor packed with activated carbon in the presence of a stoichiometric amount of oxygen which oxidizes the hydrogen sulfide to elemental sulfur which is adsorbed on the bed. The carbon can be recycled after the sulfur has been recovered by vacuum distillation, inert gas entrainment or solvent extraction. The process is suitable for the purification of steam from geothermal sources which may also contain other noncondensable gases.

  20. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Short Contact Time Hydrogen Generator, Wei Wei, GE Global Research Distributed Bio-Oil Reforming, Darlene Steward, National Renewable Energy Laboratory High-Pressure Steam...

  1. Performance of Ni-Fe/gadolinium-doped CeO{sub2} anode supported tubular solid oxide fuel cells using steam reforming of methane

    SciTech Connect (OSTI)

    Liang, B.; Suzuki, T.; Hamamoto, K.; Yamaguchi, T.; Sumi, H.; Fujishiro, Y.; Ingram, B. J.; Carter, J. D.

    2012-03-15

    Iron nanoparticles (Fe{sub 2}O{sub 3}) were added to NiO/gadolinium-doped CeO{sub 2} (GDC) anode supported solid oxide fuel cell (SOFC) for the direct methane-water fuel operation. The cell was co-sintered at 1400 C, and the anode porosity is 31.8%. The main size corresponding to peak volume is around 1.5 {mu}m. When steam and methane directly fed to the cell, the power density is about 0.57 W cm{sup -2} at 650 C. It is the familiar performance for H{sub 2} operation (4 times of flow rate) with same fuel utilization. Compare with the testing temperature of 600 and 650 C, there is almost no carbon fiber deposition at 700 C with steam/methane (S/C) of 5. At the same time, fuel operation of high value of S/C (=3.3) resulted in fiber-like deposition and degradation of power performance based on loading test results.

  2. Thermochemically recuperated and steam cooled gas turbine system

    DOE Patents [OSTI]

    Viscovich, P.W.; Bannister, R.L.

    1995-07-11

    A gas turbine system is described in which the expanded gas from the turbine section is used to generate the steam in a heat recovery steam generator and to heat a mixture of gaseous hydrocarbon fuel and the steam in a reformer. The reformer converts the hydrocarbon gas to hydrogen and carbon monoxide for combustion in a combustor. A portion of the steam from the heat recovery steam generator is used to cool components, such as the stationary vanes, in the turbine section, thereby superheating the steam. The superheated steam is mixed into the hydrocarbon gas upstream of the reformer, thereby eliminating the need to raise the temperature of the expanded gas discharged from the turbine section in order to achieve effective conversion of the hydrocarbon gas. 4 figs.

  3. Thermochemically recuperated and steam cooled gas turbine system

    DOE Patents [OSTI]

    Viscovich, Paul W. (Longwood, FL); Bannister, Ronald L. (Winter Springs, FL)

    1995-01-01

    A gas turbine system in which the expanded gas from the turbine section is used to generate the steam in a heat recovery steam generator and to heat a mixture of gaseous hydrocarbon fuel and the steam in a reformer. The reformer converts the hydrocarbon gas to hydrogen and carbon monoxide for combustion in a combustor. A portion of the steam from the heat recovery steam generator is used to cool components, such as the stationary vanes, in the turbine section, thereby superheating the steam. The superheated steam is mixed into the hydrocarbon gas upstream of the reformer, thereby eliminating the need to raise the temperature of the expanded gas discharged from the turbine section in order to achieve effective conversion of the hydrocarbon gas.

  4. Integrated hydrocarbon reforming system and controls

    DOE Patents [OSTI]

    Clawson, Lawrence G.; Dorson, Matthew H.; Mitchell, William L.; Nowicki, Brian J.; Thijssen, Johannes; Davis, Robert; Papile, Christopher; Rumsey, Jennifer W.; Longo, Nathan; Cross, III, James C.; Rizzo, Vincent; Kleeburg, Gunther; Rindone, Michael; Block, Stephen G.; Sun, Maria; Morriseau, Brian D.; Hagan, Mark R.; Bowers, Brian

    2003-11-04

    A hydrocarbon reformer system including a first reactor configured to generate hydrogen-rich reformate by carrying out at least one of a non-catalytic thermal partial oxidation, a catalytic partial oxidation, a steam reforming, and any combinations thereof, a second reactor in fluid communication with the first reactor to receive the hydrogen-rich reformate, and having a catalyst for promoting a water gas shift reaction in the hydrogen-rich reformate, and a heat exchanger having a first mass of two-phase water therein and configured to exchange heat between the two-phase water and the hydrogen-rich reformate in the second reactor, the heat exchanger being in fluid communication with the first reactor so as to supply steam to the first reactor as a reactant is disclosed. The disclosed reformer includes an auxiliary reactor configured to generate heated water/steam and being in fluid communication with the heat exchanger of the second reactor to supply the heated water/steam to the heat exchanger.

  5. Steam Quality 

    E-Print Network [OSTI]

    Johnston, W.

    1989-01-01

    "STEAM QUALITY has been generally defined as the amount of moisture/vapor (or lack thereof) contained within steam produced from some form of boiler. It has long been used as the standard term for the measurement of ""wet or dry"" steam and as a...

  6. Ritterschaft & Reformation

    E-Print Network [OSTI]

    Kallenrode, May-Britt

    Ritterschaft & Reformation Renaissancesaal im Ledenhof 23. und 24. Oktober 2014 Osnabrückgefördert deutsche Reformation in Böhmen und Mähren (1520-1620) Dr. Josef Hrdlicka, Ceské Budjovice 10:30 Kaffeepause. Olga Weckenbrock, Osnabrück 11:45 Die Bedeutung der Reichsritterschaft für Reformation und

  7. Applications of solar reforming technology

    SciTech Connect (OSTI)

    Spiewak, I.; Tyner, C.E.; Langnickel, U.

    1993-11-01

    Research in recent years has demonstrated the efficient use of solar thermal energy for driving endothermic chemical reforming reactions in which hydrocarbons are reacted to form synthesis gas (syngas). Closed-loop reforming/methanation systems can be used for storage and transport of process heat and for short-term storage for peaking power generation. Open-loop systems can be used for direct fuel production; for production of syngas feedstock for further processing to specialty chemicals and plastics and bulk ammonia, hydrogen, and liquid fuels; and directly for industrial processes such as iron ore reduction. In addition, reforming of organic chemical wastes and hazardous materials can be accomplished using the high-efficiency destruction capabilities of steam reforming. To help identify the most promising areas for future development of this technology, we discuss in this paper the economics and market potential of these applications.

  8. Superheated steam power plant with steam to steam reheater. [LMFBR

    SciTech Connect (OSTI)

    Silvestri, G.J.

    1981-06-23

    A desuperheater is disposed in a steam supply line supplying superheated steam to a shell and tube reheater.

  9. Pulse enhanced fluidized bed combustion

    SciTech Connect (OSTI)

    Mueller, B.; Golan, L. [South Carolina Energy Research and Development Center, Clemson, SC (United States); Toma, M.; Mansour, M. [Manufacturing and Technology Conversion International, Inc., Columbia, MD (United States)

    1996-12-31

    Various technologies are available for the combustion of high-sulfur, high-ash fuels, particularly coal. From performance, economic and environmental standpoints, fluidized bed combustion (FBC) is the leading candidate for utilization of high sulfur coals. ThermoChem, Inc., and the South Carolina Energy Research and Development Center (SCERDC) are installing a hybrid fluidized bed combustion system at Clemson University. This hybrid system, known as the Pulsed Atmospheric Fluidized Bed Combustor (PAFBC), will augment the University`s steam system by providing 50--60,000 lbs/hr of saturated process steam. The PAFBC, developed by Manufacturing and Technology Conversion International, Inc., (MTCI), integrates a pulse combustor with a bubbling-bed-type atmospheric fluidized bed coal combustor. The pulse combustion system imparts an acoustic effect that enhances combustion efficiency, SO{sub 2} capture, low NO{sub x} emissions, and heat transfer efficiency in the fluidized bed. These benefits of pulse combustion result in modestly sized PAFBC units with high throughput rates and lower costs when compared to conventional fluidized bed units.

  10. Advanced Fluidized Bed Waste Heat Recovery Systems 

    E-Print Network [OSTI]

    Peterson, G. R.

    1988-01-01

    BED WASTE HEAT RECOVERY SYSTEMS G. R. PETERSON Project Manager U.S. Department of Energy, Idaho Operations Office Idaho Falls, Idaho ABSTRACT The U.S. Department of Energy, Office of Industri al Programs, has sponsored the development of a... Fluidized Bed Waste Heat Recovery System (FBWHRS) and a higher temperature variant, the Ceramic Tubular Distributor Plate (CTOP) Fluidized Bed Heat Exchanger (FBHX) system. Both systems recover energy from high-temperature flue gases and produce steam...

  11. Aalborg Universitet Control and experimental characterization of a methanol reformer for a 350W high

    E-Print Network [OSTI]

    Berning, Torsten

    , Pontoppidanstræde 101, 9220 Aalborg East, Denmarkp gy gy g y pp g Introd ction Steam reforming of methanol for a HTPEM f el cell stack ConclusionsIntroduction Steam reforming of methanol for a HTPEM fuel cell stack where heating, conduct detailed measurements of the fuel cells offer many evaporation and superheating

  12. Method for improving catalyst function in auto-thermal and partial oxidation reformer-based processors

    DOE Patents [OSTI]

    Ahmed, Shabbir; Papadias, Dionissios D.; Lee, Sheldon H.D.; Ahluwalia, Rajesh K.

    2014-08-26

    The invention provides a method for reforming fuel, the method comprising contacting the fuel to an oxidation catalyst so as to partially oxidize the fuel and generate heat; warming incoming fuel with the heat while simultaneously warming a reforming catalyst with the heat; and reacting the partially oxidized fuel with steam using the reforming catalyst.

  13. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    The design of the Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) as described in the Quarterly Report for the period April--June, 1992 was reviewed and minor modifications were included. The most important change made was in the coal/limestone preparation and feed system. Instead of procuring pre-sized coal for testing of the PAFBC, it was decided that the installation of a milling system would permit greater flexibility in the testing with respect to size distributions and combustion characteristics in the pulse combustor and the fluid bed. Particle size separation for pulse combustor and fluid bed will be performed by an air classifier. The modified process flow diagram for the coal/limestone handling system is presented in Figure 1. The modified process flow diagrams of the fluidized bed/steam cycle and ash handling systems are presented in Figures 2 and 3, respectively.

  14. Inspect and Repair Steam Traps, Energy Tips: STEAM, Steam Tip...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    installed steam traps may have failed-thus allowing live steam to escape into the condensate return system. In systems with a regularly scheduled maintenance program, leaking...

  15. Deaerators in Industrial Steam Systems, Energy Tips: STEAM, Steam...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Systems Deaerators are mechanical devices that remove dissolved gases from boiler feedwater. Deaeration protects the steam system from the effects of corrosive gases....

  16. Heat exchanger for fuel cell power plant reformer

    DOE Patents [OSTI]

    Misage, Robert (Manchester, CT); Scheffler, Glenn W. (Tolland, CT); Setzer, Herbert J. (Ellington, CT); Margiott, Paul R. (Manchester, CT); Parenti, Jr., Edmund K. (Manchester, CT)

    1988-01-01

    A heat exchanger uses the heat from processed fuel gas from a reformer for a fuel cell to superheat steam, to preheat raw fuel prior to entering the reformer and to heat a water-steam coolant mixture from the fuel cells. The processed fuel gas temperature is thus lowered to a level useful in the fuel cell reaction. The four temperature adjustments are accomplished in a single heat exchanger with only three heat transfer cores. The heat exchanger is preheated by circulating coolant and purge steam from the power section during startup of the latter.

  17. Acquisition Reform

    E-Print Network [OSTI]

    Sapolsky, Harvey

    This report reviews the six most recent major acquisition reform reports, starting in 1949 with the Hoover Commissions and including McNamara's Total Package Procurement, Fitzhugh Commission, the Commission on Government ...

  18. Steam Turbine Cogeneration 

    E-Print Network [OSTI]

    Quach, K.; Robb, A. G.

    2008-01-01

    Steam turbines are widely used in most industrial facilities because steam is readily available and steam turbine is easy to operate and maintain. If designed properly, a steam turbine co-generation (producing heat and power simultaneously) system...

  19. Thomas Reddinger Director, Steam

    E-Print Network [OSTI]

    McConnell, Terry

    Thomas Reddinger Director, Steam Operations Steven Richards Assistant Manager of Maintenance & Operations Tim Winterfield Operations Supervisor (Distribution) Deborah Moorhead Office Coordinator III Jacob Donovan- ColinSteam Plant Operator Vincent Massara Steam Plant Operator SU Steam Station/Chilled Water

  20. Steam Pricing 

    E-Print Network [OSTI]

    Jones, K. C.

    1986-01-01

    stream_source_info ESL-IE-86-06-19.pdf.txt stream_content_type text/plain stream_size 30463 Content-Encoding ISO-8859-1 stream_name ESL-IE-86-06-19.pdf.txt Content-Type text/plain; charset=ISO-8859-1 STEAM PRICING... Kenneth C. Jones Shell Oil Company Houston, Texas ABSTRACT Steam is used in many plants to furnish both heat and mechanical energy. It is typically produced in several fired boilers which may operate at different pressures and with different...

  1. Steam in Distribution and Use: Steam Quality Redefined 

    E-Print Network [OSTI]

    Deacon, W.

    1989-01-01

    "Steam quality is an important measurement in steam generation. It's a measurement of steam to moisture ratio. In use, steam quality takes on a different meaning - steam which maximizes energy transfer. To do this, the steam must be clean, dry...

  2. Steam in Distribution and Use: Steam Quality Redefined 

    E-Print Network [OSTI]

    Deacon, W. T.

    1989-01-01

    Steam quality is an important measurement in steam generation. It's a measurement of steam to moisture ratio. In use, steam quality takes on a different meaning- steam which maximizes energy transfer. To do this, the steam must be clean, dry...

  3. Coal-Fired Fluidized Bed Combustion Cogeneration 

    E-Print Network [OSTI]

    Thunem, C.; Smith, N.

    1985-01-01

    BED COMBUSTION COGENERATION Cabot Thunem, P.E Norm Smith, P.E. Stanley Consultants, Inc. Muscatine, Iowa ABSTRACT The availability of an environmentally accep table multifuel technology, such as fluidized bed combustion, has encouraged many... steam producers/ users to investigate switching from oil or gas to coal. Changes in federal regulations encouraging cogeneration have further enhanced the economic incentives for primary fuel switching. However, this addition of cogeneration...

  4. Method of removing cesium from steam

    DOE Patents [OSTI]

    Carson, Jr., Neill J. (Clarendon Hills, IL); Noland, Robert A. (Oak Park, IL); Ruther, Westly E. (Skokie, IL)

    1991-01-01

    Method for removal of radioactive cesium from a hot vapor, such as high temperature steam, including the steps of passing input hot vapor containing radioactive cesium into a bed of silicate glass particles and chemically incorporating radioactive cesium in the silicate glass particles at a temperature of at least about 700.degree. F.

  5. Steam System Optimization 

    E-Print Network [OSTI]

    Aegerter, R.

    2004-01-01

    and Cost The ultimate goal in optimizing the steam system is to minimize the steam generation costs. Most projects are dependent on the steam balance and can only be justified if low-pressure steam is being vented or if steam is being let down. Some... savings can be quantified. Steam Venting or Letting Down? Typically a plant will be either venting excess low-pressure steam or letting down steam to meet the low-pressure steam demand. If a plant has multiple operating units, it is possible...

  6. Managing steam: An engineering guide to industrial, commercial, and utility systems

    SciTech Connect (OSTI)

    Makansi, J.

    1985-01-01

    This book is a guide to steam production, utilization, handling, transport, system optimization, and condensation and recovery. This book incudes a description of how steam, condensate, and hot water are used in various industrial, commercial, institutional, and utility sectors and explains how steam is generated and distributed. Waste-heat recovery, fluidized-bed boilers, and cogeneration systems and boiler control theory are discussed. The book also describes different types of valves, valve components, regulators, steam traps, and metering devices available for managing steam and condensate and discusses maintaining steam systems for optimum service and longer life.

  7. Steam System Optimization 

    E-Print Network [OSTI]

    Aegerter, R. A.

    1998-01-01

    Most plant steam systems are complex systems. Usually the fuel required to produce the steam represents a major expense for manufacturing facilities. By properly operating and maintaining the steam system and making minor improvements, significant...

  8. Steam Digest Volume IV

    SciTech Connect (OSTI)

    2004-07-01

    This edition of the Steam Digest is a compendium of 2003 articles on the technical and financial benefits of steam efficiency, presented by the stakeholders of the U.S. Department of Energy's BestPractices Steam effort.

  9. Steam Trap Application 

    E-Print Network [OSTI]

    Murphy, J. J.

    1982-01-01

    The effective application of steam traps encompasses three primary areas which are the selection and sizing, the installation, and the monitoring of the steam trapping system. Proper application of steam traps will improve production rates, product...

  10. ORIGINAL RESEARCH PAPER Gas phase H2S product recovery in a packed bed bioreactor

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    of sulfate-laden wastewaters and bioremediation of acid mine drainage (Colleran et al. 1995; Hulshoff et al to the conversion of CH4 to H2 by steam reforming. In the treatment of acid mine drainage, dissolved heavy metals

  11. Development of a Sorption Enhanced Steam Hydrogasification Process for In-situ Carbon Dioxide (CO2) Removal and Enhanced Synthetic Fuel Production

    E-Print Network [OSTI]

    Liu, Zhongzhe

    2013-01-01

    J. Different types of gasifiers and their integration withCO 2 in a pressurized-gasifier-based process. Energ Fuel.fluidized bed biomass steam gasifier-bed material and fuel

  12. Steam Path Audits on Industrial Steam Turbines 

    E-Print Network [OSTI]

    Mitchell, D. R.

    1992-01-01

    on Industrial steam Turbines DOUGLAS R. MITCHELL. ENGINEER. ENCOTECH, INC., SCHENECTADY, NEW YORK ABSTRACT The electric utility industry has benefitted from steam path audits on steam turbines for several years. Benefits include the ability to identify... areas of performance degradation during a turbine outage. Repair priorities can then be set in accordance with quantitative results from the steam path audit. As a result of optimized repair decisions, turbine efficiency increases, emissions...

  13. Bed Bugs 

    E-Print Network [OSTI]

    Gold, Roger E.; Howell Jr., Harry N.

    2001-11-15

    stream_source_info pdf_1512.pdf.txt stream_content_type text/plain stream_size 5811 Content-Encoding ISO-8859-1 stream_name pdf_1512.pdf.txt Content-Type text/plain; charset=ISO-8859-1 Bed Bugs L-1742 9-01 Roger Gold...

  14. Immigration Reform: 1986 & Today

    E-Print Network [OSTI]

    Woods, Gregory

    2013-01-01

    voice has  forced immigration reform back to the  political known as the Immigration Reform and Control Act of 1986 (

  15. Investigation of the Effect of In-Situ Catalyst on the Steam Hydrogasification of Biomass

    E-Print Network [OSTI]

    FAN, XIN

    2012-01-01

    feasibility of biomass gasification for power generation,Li, X.T. , et al. , Biomass gasification in a circulatingP.U. , Steam-gasification of biomass in a fluidized-bed of

  16. Steam Oxidation of Advanced Steam Turbine Alloys

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2008-01-01

    Power generation from coal using ultra supercritical steam results in improved fuel efficiency and decreased greenhouse gas emissions. Results of ongoing research into the oxidation of candidate nickel-base alloys for ultra supercritical steam turbines are presented. Exposure conditions range from moist air at atmospheric pressure (650°C to 800°C) to steam at 34.5 MPa (650°C to 760°C). Parabolic scale growth coupled with internal oxidation and reactive evaporation of chromia are the primary corrosion mechanisms.

  17. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, F.E.; Smolensky, L.A.; Doyle, E.F.; DiBella, F.A.

    1994-03-08

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculates through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried. The dryer comprises a vessel which enables the feedstock and steam to enter and recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard. 17 figures.

  18. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Doyle, Edward F. (Dedham, MA); DiBella, Francis A. (Roslindale, MA)

    1994-01-01

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculated through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried The dryer comprises a vessel which enables the feedstock and steam to enter recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard.

  19. Preliminary Thoughts on Copyright Reform

    E-Print Network [OSTI]

    Samuelson, Pamela

    2007-01-01

    Thoughts on Copyright Reform by Pamela Samuelson * Myriadfor undertaking a copyright reform project. For one thing,product of a copyright reform process that was initiated in

  20. Hydrogen production with a solar steammethanol reformer and colloid nanocatalyst

    E-Print Network [OSTI]

    Daraio, Chiara

    and Process Engineering, Laboratory of Thermodynamics in Emerging Technologies, CH-8092 Zurich, Switzerland carried out [7,8] to improve the reforming system efficiency. Energy for the endothermic steam rights reserved. doi:10.1016/j.ijhydene.2009.10.083 #12;Using concentrated solar energy to provide energy

  1. Steam Technical Brief: Steam Pressure Reduction: Opportunities and Issues

    SciTech Connect (OSTI)

    2010-06-25

    A BestPractices Technical Brief describing industrial steam generation systems and opportunities for reducing steam system operating pressure.

  2. Operating Experience of a Coal Fired Fluidized Bed at Georgetown University 

    E-Print Network [OSTI]

    Lutes, I. G.; Gamble, R. L.

    1980-01-01

    Operation of the 100,000 lb/hr capacity, coal fired fluidized bed steam generator at Georgetown University began in July 1979. This project, which was co-funded by Georgetown University and the U. S. Department of Energy, ...

  3. Waste Steam Recovery 

    E-Print Network [OSTI]

    Kleinfeld, J. M.

    1979-01-01

    An examination has been made of the recovery of waste steam by three techniques: direct heat exchange to process, mechanical compression, and thermocompression. Near atmospheric steam sources were considered, but the techniques developed are equally...

  4. Steam Digest 2001

    SciTech Connect (OSTI)

    Not Available

    2002-01-01

    Steam Digest 2001 chronicles BestPractices Program's contributions to the industrial trade press for 2001, and presents articles that cover technical, financial and managerial aspects of steam optimization.

  5. Downhole steam quality measurement

    DOE Patents [OSTI]

    Lee, D.O.; Montoya, P.C.; Muir, J.F.; Wayland, J.R. Jr.

    1985-06-19

    The present invention relates to an empirical electrical method for remote sensing of steam quality utilizing flow-through grids which allow measurement of the electrical properties of a flowing two-phase mixture. The measurement of steam quality in the oil field is important to the efficient application of steam assisted recovery of oil. Because of the increased energy content in higher quality steam it is important to maintain the highest possible steam quality at the injection sandface. The effectiveness of a steaming operation without a measure of steam quality downhole close to the point of injection would be difficult to determine. Therefore, a need exists for the remote sensing of steam quality.

  6. Downhole steam quality measurement

    DOE Patents [OSTI]

    Lee, David O. (Albuquerque, NM); Montoya, Paul C. (Albuquerque, NM); Muir, James F. (Albuquerque, NM); Wayland, Jr., J. Robert (Albuquerque, NM)

    1987-01-01

    An empirical method for the remote sensing of steam quality that can be easily adapted to downhole steam quality measurements by measuring the electrical properties of two-phase flow across electrode grids at low frequencies.

  7. 4. Heat exchangers; Steam, steam processes

    E-Print Network [OSTI]

    Zevenhoven, Ron

    to transfer a certain heat rate Q (J/s = W) For a small section dx of the tube (with diameter D), the heat With average temperature difference = for the heat exchanger length, the heat rate can1/74 4. Heat exchangers; Steam, steam processes Ron Zevenhoven Åbo Akademi University Thermal

  8. Circulating Fluid Bed Combustor 

    E-Print Network [OSTI]

    Fraley, L. D.; Do, L. N.; Hsiao, K. H.

    1982-01-01

    The circulating bed combustor represents an alternative concept of burning coal in fluid bed technology, which offers distinct advantages over both the current conventional fluidized bed combustion system and the pulverized coal boilers equipped...

  9. Steam trap monitor

    DOE Patents [OSTI]

    Ryan, M.J.

    1987-05-04

    A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (a hot finger) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellow in providing an indication of total energy (steam + condensate) of the system. Processing means coupled to and responsive to outputs from the hot and cold fingers subtracts the former from the latter to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning. 2 figs.

  10. Steam System Survey Guide | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a steam system, (2) identifying steam properties for the steam system, (3) improving boiler operations, (4) improving resource utilization in the steam system, and (5)...

  11. Steam generator support system

    DOE Patents [OSTI]

    Moldenhauer, James E. (Simi Valley, CA)

    1987-01-01

    A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances.

  12. Steam generator support system

    DOE Patents [OSTI]

    Moldenhauer, J.E.

    1987-08-25

    A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source is disclosed. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances. 4 figs.

  13. HP Steam Trap Monitoring 

    E-Print Network [OSTI]

    Pascone, S.

    2011-01-01

    stream_source_info ESL-IC-11-10-61.pdf.txt stream_content_type text/plain stream_size 2024 Content-Encoding ISO-8859-1 stream_name ESL-IC-11-10-61.pdf.txt Content-Type text/plain; charset=ISO-8859-1 STEAM MONITORING HP... Steam Trap Monitoring HP Steam Trap Monitoring ? 12-18 months payback! ? 3-5% permanent reduction in consumption ? LEED Pt.? Innovation in Operations EB O&M ? Saved clients over $1,000,000 Annual consumption Steam Trap Monitoring ? Real...

  14. Steam System Survey Guide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TO ACTION-IDENTIFYING STEAM SYSTEM PROPERTIES... 3-1 4. OPPORTUNITIES FOR BOILER EFFICIENCY IMPROVEMENT... 4-1 4.1 OVERVIEW AND GENERAL...

  15. Steam Champions in Manufacturing 

    E-Print Network [OSTI]

    Russell, C.

    2001-01-01

    Traditionally, industrial steam system management has focused on operations and maintenance. Competitive pressures, technology evolution, and increasingly complex regulations provide additional management challenges. The practice of operating a...

  16. Benchmark the Fuel Cost of Steam Generation, Energy Tips: STEAM...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of your steam system. This cost is dependent upon fuel type, unit fuel cost, boiler efficiency, feedwater temperature, and steam pressure. This calculation provides a...

  17. Options for Generating Steam Efficiently 

    E-Print Network [OSTI]

    Ganapathy, V.

    1996-01-01

    This paper describes how plant engineers can efficiently generate steam when there are steam generators and Heat Recovery Steam Generators in their plant. The process consists of understanding the performance characteristics of the various equipment...

  18. Hybrid fluidized bed combuster

    DOE Patents [OSTI]

    Kantesaria, Prabhudas P. (Windsor, CT); Matthews, Francis T. (Poquonock, CT)

    1982-01-01

    A first atmospheric bubbling fluidized bed furnace is combined with a second turbulent, circulating fluidized bed furnace to produce heat efficiently from crushed solid fuel. The bed of the second furnace receives the smaller sizes of crushed solid fuel, unreacted limestone from the first bed, and elutriated solids extracted from the flu gases of the first bed. The two-stage combustion of crushed solid fuel provides a system with an efficiency greater than available with use of a single furnace of a fluidized bed.

  19. A modeling software linking approach for the analysis of an integrated reforming combined cycle with hot potassium carbonate CO[subscript 2] capture

    E-Print Network [OSTI]

    Nord, Lars Olof

    The focus of this study is the analysis of an integrated reforming combined cycle (IRCC) with natural gas as fuel input. This IRCC consisted of a hydrogen-fired gas turbine (GT) with a single-pressure steam bottoming cycle ...

  20. Steam Trap Management 

    E-Print Network [OSTI]

    Murphy, J. J.; Hirtner, H. H.

    1985-01-01

    A medium-sized plant of a high technology company is reaping the benefits of a Pro-active Steam Trap Program provided by Yarway's TECH/SERV Division. Initial work began March '84 and the most recent steam trap feasibility study conducted in March...

  1. Steam and Condensate Systems 

    E-Print Network [OSTI]

    Yates, W.

    1980-01-01

    In the late 60's and early 70's oil was plentiful and steam was relatively inexpensive. The switch to low sulphur fuel oil and the oil embargo suddenly changed the picture. The cost of steam rose from $0.50 per 1,000# to today's cost of $4...

  2. Steam and Condensate Systems 

    E-Print Network [OSTI]

    Yates, W.

    1979-01-01

    In the late 60's and early 70's oil was plentiful and steam was relatively inexpensive. The switch to low sulphur fuel oil and the oil embargo suddenly changed the picture. The cost of steam rose from about $0.50 per 1,000# to $3.00 or more. Many...

  3. Autothermal and partial oxidation reformer-based fuel processor, method for improving catalyst function in autothermal and partial oxidation reformer-based processors

    DOE Patents [OSTI]

    Ahmed, Shabbir; Papadias, Dionissios D.; Lee, Sheldon H. D.; Ahluwalia, Rajesh K.

    2013-01-08

    The invention provides a fuel processor comprising a linear flow structure having an upstream portion and a downstream portion; a first catalyst supported at the upstream portion; and a second catalyst supported at the downstream portion, wherein the first catalyst is in fluid communication with the second catalyst. Also provided is a method for reforming fuel, the method comprising contacting the fuel to an oxidation catalyst so as to partially oxidize the fuel and generate heat; warming incoming fuel with the heat while simultaneously warming a reforming catalyst with the heat; and reacting the partially oxidized fuel with steam using the reforming catalyst.

  4. Tax Reform and Real Estate

    E-Print Network [OSTI]

    Maisel, Sherman J.; Quigley, John M.

    1985-01-01

    WORKING PAPER 85-100 TAX REFORM AND REAL ESTATE BY SHERMANof wider import. TAX REFORM AND REAL ESTATE by Sherman J.B. The Initial Impact of Tax Reform IV. RESULTS: RESTORING

  5. Streams of Steam The Steam Boiler Specification Case Study

    E-Print Network [OSTI]

    Streams of Steam ­ The Steam Boiler Specification Case Study Manfred Broy, Franz Regensburger-tuned con- cepts of FOCUS by its application of the requirements specification of a steam boiler, see [Abr96-studies. In this context, applying FOCUS to the steam boiler case study ([Abr96]) led us to a couple of questions re- #12

  6. Nanocomposite catalysts for soot combustion and propane steam reforming

    E-Print Network [OSTI]

    He, Hong, Ph. D. Massachusetts Institute of Technology

    2007-01-01

    A nanocomposite system, CuO-Ag/CeO 2, has been successfully developed to complete carbon black combustion by 400*C. This novel catalyst has excellent potential for application in the emission control of soot particulates ...

  7. Steam trap monitor

    DOE Patents [OSTI]

    Ryan, Michael J. (Plainfield, IL)

    1988-01-01

    A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (the combination of a hot finger and thermocouple well) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellows in providing an indication of total energy (steam+condensate) of the system. Processing means coupled to and responsive to outputs from the thermocouple well hot and cold fingers subtracts the condensate energy as measured by the hot finger and thermocouple well from the total energy as measured by the cold finger to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning.

  8. Steam Condensation Induced Waterhammer 

    E-Print Network [OSTI]

    Kirsner, W.

    2000-01-01

    mer-- i.e. fast moving steam picking up a slug of condensate and hurling it downstream against an elbow or a valve. Condensation Induced Waterham mer can be 100 times more powerful than this type of waterhammer. Because it does not require flowing... to seek relief from the Owner. A compromise was negotiated after the first week- steam would be de-energized at midnight before each workday, asbestos abators would start work at 4:00 a.m. and finish by noontime at which time steam would be restored...

  9. Steam System Data Management 

    E-Print Network [OSTI]

    Roberts, D.

    2013-01-01

    stream_source_info ESL-IE-13-05-35.pdf.txt stream_content_type text/plain stream_size 5953 Content-Encoding ISO-8859-1 stream_name ESL-IE-13-05-35.pdf.txt Content-Type text/plain; charset=ISO-8859-1 Steam System Data... Certifications ?Retired From Chevron After 25 Years ? Established A Steam System Program ? Planner For Routine Maintenance Work ? Planner For Steam System Improvements ? Wal-Tech Valve, Inc. ? Purchased Wal-Tech Valve, Inc. In 2007 ? Implemented Safety...

  10. Fluidized bed pyrolysis to gases containing olefins

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-01-01

    Recent gasification data are presented for a system designed to produce liquid hydrocarbon fuel from various biomass feedstocks. The factors under investigation were feedstock type, fluidizing gas type, residence time, temperature and catalyst usage. The response was gas phase composition. A fluidized bed system was utilized with a separate regenerator-combustor. An olefin content as high as 39 mole % was achieved. Hydrogen/carbon monoxide ratios were easily manipulated via steam addition over a broad range with an autocatalytic effect apparent for most feedstocks.

  11. Producing Clean Syngas via Catalytic Reforming for Fuels Production

    SciTech Connect (OSTI)

    Magrini, K. A.; Parent, Y.; Jablonski, W.; Yung, M.

    2012-01-01

    Thermochemical biomass conversion to fuels and chemicals can be achieved through gasification to syngas. The biomass derived raw syngas contains the building blocks of carbon monoxide and hydrogen as well as impurities such as tars, light hydrocarbons, and hydrogen sulfide. These impurities must be removed prior to fuel synthesis. We used catalytic reforming to convert tars and hydrocarbons to additional syngas, which increases biomass carbon utilization. In this work, nickel based, fluidizable tar reforming catalysts were synthesized and evaluated for tar and methane reforming performance with oak and model syngas in two types of pilot scale fluidized reactors (recirculating and recirculating regenerating). Because hydrogen sulfide (present in raw syngas and added to model syngas) reacts with the active nickel surface, regeneration with steam and hydrogen was required. Pre and post catalyst characterization showed changes specific to the syngas type used. Results of this work will be discussed in the context of selecting the best process for pilot scale demonstration.

  12. Modeling of On-Cell Reforming Reaction for Planar SOFC Stacks

    SciTech Connect (OSTI)

    Yang, Choongmo; Lim, Hyung-Tae; Hwang, Soon Cheol; Kim, Dohyung; Lai, Canhai; Koeppel, Brian J.; Recknagle, Kurtis P.; Khaleel, Mohammad A.

    2011-05-30

    Planar Solid Oxide Fuel Cell (SOFC) stack is known to suffer thermal problem from high stack temperature during operation to generate high current. On-Cell Reforming (OCR) phenomenon is often used to reduce stack temperature by an endothermic reaction of steam-methane reforming process. RIST conducted single-cell experiment to validate modeling tool to simulate OCR performance including temperature measurement. 2D modeling is used to check reforming rate during OCR using temperature measurement data, and 3D modeling is used to check overall thermal performance including furnace boundary conditions.

  13. Email To Friend Steam Electricity Generator

    E-Print Network [OSTI]

    . keymanengravables.com Steam Turbine Generator Info, Pictures And Deals For Steam turbine generator ediscountshoppingBack One Email To Friend Steam Electricity Generator Need Steam Electricity Generator? See Steam Electricity Generator. greenshieldsindustrial.com Steam Generators Deals on Steam Generators Find what you

  14. Catalytic reforming methods

    SciTech Connect (OSTI)

    Tadd, Andrew R; Schwank, Johannes

    2013-05-14

    A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

  15. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-04-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

  16. Non-catalytic recuperative reformer

    DOE Patents [OSTI]

    Khinkis, Mark J.; Kozlov, Aleksandr P.; Kurek, Harry

    2015-12-22

    A non-catalytic recuperative reformer has a flue gas flow path for conducting hot flue gas from a thermal process and a reforming mixture flow path for conducting a reforming mixture. At least a portion of the reforming mixture flow path is embedded in the flue gas flow path to permit heat transfer from the hot flue gas to the reforming mixture. The reforming mixture flow path contains substantially no material commonly used as a catalyst for reforming hydrocarbon fuel (e.g., nickel oxide, platinum group elements or rhenium), but instead the reforming mixture is reformed into a higher calorific fuel via reactions due to the heat transfer and residence time. In a preferred embodiment, extended surfaces of metal material such as stainless steel or metal alloy that are high in nickel content are included within at least a portion of the reforming mixture flow path.

  17. Fluidized bed combustion

    SciTech Connect (OSTI)

    Sowards, N.K.; Murphy, M.L.

    1991-10-29

    This patent describes a vessel. It comprises a fluid bed for continuously incinerating fuel comprising tire segments and the like which comprise metallic wire tramp and for concurrently removing tramp and bed materials at a bottom effluent exit means of the vessel, the vessel further comprising static air distributor means at the periphery of the bed comprising a substantially centrally unobstructed relatively large central region in which the fluid bed and fuel only are disposed and through which bed material and tramp migrate without obstruction to and through the effluent exit means, downwardly and inwardly stepped lower vessel wall means and a plurality of peripherally located centrally directed vertically and horizontally offset spaced air influent means surrounding the central region and associated with the stepped lower vessel wall means by which the bed is supported and fluidized.

  18. Steam Pressure Reduction: Opportunities and Issues | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Pressure Reduction: Opportunities and Issues Steam Pressure Reduction: Opportunities and Issues This brief details industrial steam generation systems best practices and...

  19. Technical and economic assessment of producing hydrogen by reforming syngas from the Battelle indirectly heated biomass gasifier

    SciTech Connect (OSTI)

    Mann, M.K. [National Renewable Energy Lab., Golden, CO (United States). Industrial Technologies Div.

    1995-08-01

    The technical and economic feasibility of producing hydrogen from biomass by means of indirectly heated gasification and steam reforming was studied. A detailed process model was developed in ASPEN Plus{trademark} to perform material and energy balances. The results of this simulation were used to size and cost major pieces of equipment from which the determination of the necessary selling price of hydrogen was made. A sensitivity analysis was conducted on the process to study hydrogen price as a function of biomass feedstock cost and hydrogen production efficiency. The gasification system used for this study was the Battelle Columbus Laboratory (BCL) indirectly heated gasifier. The heat necessary for the endothermic gasification reactions is supplied by circulating sand from a char combustor to the gasification vessel. Hydrogen production was accomplished by steam reforming the product synthesis gas (syngas) in a process based on that used for natural gas reforming. Three process configurations were studied. Scheme 1 is the full reforming process, with a primary reformer similar to a process furnace, followed by a high temperature shift reactor and a low temperature shift reactor. Scheme 2 uses only the primary reformer, and Scheme 3 uses the primary reformer and the high temperature shift reactor. A pressure swing adsorption (PSA) system is used in all three schemes to produce a hydrogen product pure enough to be used in fuel cells. Steam is produced through detailed heat integration and is intended to be sold as a by-product.

  20. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End User Training Steam End User Training Steam Distribution Losses Module 1 June 29, 2010 Steam EndUser Training Steam Distribution System Losses Module Slide 1 pressure. #12;DOE's BestPractices Steam End User Training Steam End User Training Steam Distribution

  1. The development of a 20-inch indirect fired fluidized bed gasifier

    SciTech Connect (OSTI)

    Flanigan, V.J.; Sitton, O.C.; Huang, W.E

    1988-03-01

    This report discusses the design, fabrication and operation of a 20'' I.D. fluidized bed gasifier producing medium Btu gas. The reactor is indirectly heated using 30 x 1-inch U-tubes inserted in the inert bed. The U-tubes are heated using flue gases produced from a propane burner system located at the bottom of the reactor. The feed material was dry wood chips fed into the bed with a 6in. auger. The reactor was fed both into the bed and at the top of the bed. The fluidizing medium was superheated steam which was superheated to 1000/degree/F. The gas produced from the reactor was passed through a cyclone for char removal and routed to the flare for combustion and disposal. The parameters measured during the experimental runs were wood feed rate, steam flow rate, steam temperatures, bed temperatures, free board temperatures, product gas temperatures, bed differential pressures, char production, gas production, gas analyses, and tar production. The parameters measured in the laboratory were moisture contents (wood and char), ash contents (wood and char), and tar content. 9 refs., 19 figs., 11 tabs.

  2. Steam Generator Group Project. Task 6. Channel head decontamination

    SciTech Connect (OSTI)

    Allen, R.P.; Clark, R.L.; Reece, W.D.

    1984-08-01

    The Steam Generator Group Project utilizes a retired-from-service pressurized-water-reactor steam generator as a test bed and source of specimens for research. An important preparatory step to primary side research activities was reduction of the radiation field in the steam generator channel head. This task report describes the channel head decontamination activities. Though not a programmatic research objective it was judged beneficial to explore the use of dilute reagent chemical decontamination techniques. These techniques presented potential for reduced personnel exposure and reduced secondary radwaste generation, over currently used abrasive blasting techniques. Two techniques with extensive laboratory research and vendors prepared to offer commercial application were tested, one on either side of the channel head. As indicated in the report, both techniques accomplished similar decontamination objectives. Neither technique damaged the generator channel head or tubing materials, as applied. This report provides details of the decontamination operations. Application system and operating conditions are described.

  3. Pressurized fluidized-bed combustion technology exchange workshop

    SciTech Connect (OSTI)

    ,

    1980-04-01

    The pressurized fluidized-bed combustion technology exchange workshop was held June 5 and 6, 1979, at The Meadowlands Hilton Hotel, Secaucus, New Jersey. Eleven papers have been entered individually into EDB and ERA. The papers include reviews of the US DOE and EPRI programs in this area and papers by Swedish, West German, British and American organizations. The British papers concern the joint program of the USA, UK and FRG at Leatherhead. The key factor in several papers is the use of fluidized bed combustors, gas turbines, and steam turbines in combined-cycle power plants. One paper examines several combined-cycle alternatives. (LTN)

  4. NETL - Fuel Reforming Facilities

    ScienceCinema (OSTI)

    None

    2014-06-27

    Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

  5. The Aftermath of Redistricting Reform in California

    E-Print Network [OSTI]

    Buchler, Justin

    2011-01-01

    2009. “Redistricting Reform Will Not Solve California’sMatthew. 2009. “Redistricting Reform Could Save California2. ———. 2011. “Redistricting Reform Revisited. ” California

  6. Bank Regulation and Mortgage Market Reform

    E-Print Network [OSTI]

    Jaffee, Dwight M.

    2011-01-01

    Regulation and Mortgage Market Reform Dwight M. Jaffee Boothfinancial sector regulatory reform initiatives are currentlyset concerns bank regulatory reform as embedded in the 2010

  7. Mapping the Consequences of Electoral Reform

    E-Print Network [OSTI]

    Latner, Michael S; Roach, Kyle

    2011-01-01

    Consequences of Electoral Reform Table A2. Unrotated Matrixthe Consequences of Electoral Reform California Journal ofConsequences of Electoral Reform Michael S. Latner and Kyle

  8. Politics and Policy in State Health Reform

    E-Print Network [OSTI]

    Zelman, Walter; Melamed, Alex

    2009-01-01

    Reform . . . . . . . . . . . . . . . . . . . . . . . . . . . .and Policy in State Health Reform by Walter Zelman, Ph.D.c Greenberge, S.S. , “Healthcare reform efforts win praise

  9. Patent Reform: Aligning Reward and Contribution

    E-Print Network [OSTI]

    Shapiro, Carl

    2007-01-01

    Patent Reform: Aligning Reward and Contribution † CarlThis paper analyzes two major reforms to the patent systemthey are issued. Three additional reforms relating to patent

  10. Constitutional Reform in California: The Surprising Divides

    E-Print Network [OSTI]

    Binder, Mike; Frisby, Tammy; Kousser, Thad B

    2010-01-01

    Issue 2 Constitutional Reform in California: The Surprisingviews on constitutional reform than whites and African-and opposition to proposed reforms, such as the elimination

  11. Working Group Meeting Presentation Guidance at a Glance Distributed Reforming of Biomass Pyrolysis Oils

    E-Print Network [OSTI]

    and Performance Carbon Deposit Removal and Catalyst Regeneration Management Process Energy Integration Integrated and 7 2007 R. J. Evans, NREL D. M. Steward, NREL #12;Innovation / Overview Biomass pyrolysis produces.31 O2 + 0.26 H2O 0.71 CO2 + 0.96 H2 #12;Key Performance Metrics Catalytic Steam Reforming of Bio

  12. Economic Evaluation of By-Product Power/Co-Generation Systems for Industrial Plants with Fluidized-Bed Coal Burning Facilities 

    E-Print Network [OSTI]

    Mesko, J. E.

    1980-01-01

    . The plants analyzed employ fluidized bed boilers for generation of steam for process and building/heating/cooling demands, in conjunction with electric power co-generation. Results of the analysis are presented, using life cycle costs and investment payback...

  13. Fluidized bed calciner apparatus

    DOE Patents [OSTI]

    Owen, Thomas J. (West Richland, WA); Klem, Jr., Michael J. (Richland, WA); Cash, Robert J. (Richland, WA)

    1988-01-01

    An apparatus for remotely calcining a slurry or solution feed stream of toxic or hazardous material, such as ammonium diurante slurry or uranyl nitrate solution, is disclosed. The calcining apparatus includes a vertical substantially cylindrical inner shell disposed in a vertical substantially cylindrical outer shell, in which inner shell is disposed a fluidized bed comprising the feed stream material to be calcined and spherical beads to aid in heat transfer. Extending through the outer and inner shells is a feed nozzle for delivering feed material or a cleaning chemical to the beads. Disposed in and extending across the lower portion of the inner shell and upstream of the fluidized bed is a support member for supporting the fluidized bed, the support member having uniform slots for directing uniform gas flow to the fluidized bed from a fluidizing gas orifice disposed upstream of the support member. Disposed in the lower portion of the inner shell are a plurality of internal electric resistance heaters for heating the fluidized bed. Disposed circumferentially about the outside length of the inner shell are a plurality of external heaters for heating the inner shell thereby heating the fluidized bed. Further, connected to the internal and external heaters is a means for maintaining the fluidized bed temperature to within plus or minus approximately 25.degree. C. of a predetermined bed temperature. Disposed about the external heaters is the outer shell for providing radiative heat reflection back to the inner shell.

  14. Fixed bed hydrocracking process

    SciTech Connect (OSTI)

    MacLean, A.J.; Holloway, R.L.; Lawson, V.A.; Cronen, J.W.

    1990-02-20

    This patent describes a process for converting a gas oil range petroleum feedstock into lighter petroleum products. It comprises: charging the gas oil range petroleum feedstock and hydrogen to a first fixed bed hydrocracking zone containing a hydrocracking catalyst at hydrocracking conditions to produce a first hydrocracking zone product stream; separating the first fixed bed hydrocracking zone product stream in a fractionation zone into a petroleum products stream and a bottoms stream; charging the bottoms stream and hydrogen to a second fixed bed hydrocracking zone containing a hydrocracking catalyst at hydrocracking conditions to produce a second fixed bed hydrocracking zone product stream; cooling the second fixed bed hydrocracking zone product stream to a temperature below about 250{degrees}F; recycling a first portion of the cooled second fixed bed hydrocracking zone product stream to the fractionation zone; removing materials having a boiling range from about 500{degrees} to about 650{degrees}F and a heavy bottoms stream having a boiling point above about 1050{degrees}F from a second portion of the cooled second fixed bed hydrocracking zone product stream to product a treated second portion; and recycling the treated second portion to the first fixed bed hydrocracking zone.

  15. Optical wet steam monitor

    DOE Patents [OSTI]

    Maxey, Lonnie C. (Powell, TN); Simpson, Marc L. (Knoxville, TN)

    1995-01-01

    A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically.

  16. Optical wet steam monitor

    DOE Patents [OSTI]

    Maxey, L.C.; Simpson, M.L.

    1995-01-17

    A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically. 4 figures.

  17. Evaluating Steam Trap Performance 

    E-Print Network [OSTI]

    Fuller, N. Y.

    1986-01-01

    stream_source_info ESL-IE-86-06-126.pdf.txt stream_content_type text/plain stream_size 11555 Content-Encoding ISO-8859-1 stream_name ESL-IE-86-06-126.pdf.txt Content-Type text/plain; charset=ISO-8859-1 EVALUATING STEAM... TRAP PERFORMANCE Noel Y Fuller, P.E. Holston Defense Corporation Kingsport, Tennessee ABSTRACT Laboratory tests were conducted on several types of steam traps at Holston Defense Corporation in Kingsport, Tennessee. Data from these tests...

  18. Pulse enhanced fluidized bed combustion

    SciTech Connect (OSTI)

    Mueller, B.

    1996-12-31

    Information is outlined on pulse enhanced fluidized bed combustion. The following topics are discussed: what is pulse enhanced fluidized bed combustion?; pulse combustors; pulsed atmospheric fluidized bed combustor (PAFBC); advantages of PAFBC; performance advantages; PAFBC facts; and PAFBC contact points.

  19. Reduction in Unit Steam Production 

    E-Print Network [OSTI]

    Gombos, R.

    2004-01-01

    In 2001 the company's Arch-Brandenburg facility faced increased steam costs due to high natural gas prices and decreased production due to shutdown of a process. The facility was challenged to reduce unit steam consumption to minimize the effects...

  20. Steam generator tube rupture study

    E-Print Network [OSTI]

    Free, Scott Thomas

    1986-01-01

    This report describes our investigation of steam generator behavior during a postulated tube rupture accident. Our study was performed using the steam generator, thermal-hydraulic analysis code THERMIT-UTSG. The purpose ...

  1. Steam System Forecasting and Management 

    E-Print Network [OSTI]

    Mongrue, D. M.; Wittke, D. O.

    1982-01-01

    Union Carbide's Taft Plant is a typical petrochemical complex with several processes that use and produce various fuel and steam resources. The plant steam and fuel system balances vary extensively since several process units 'block operate...

  2. Heat Recovery Steam Generator Simulation 

    E-Print Network [OSTI]

    Ganapathy, V.

    1993-01-01

    The paper discusses the applications of Heat Recovery Steam Generator Simulation. Consultants, plant engineers and plant developers can evaluate the steam side performance of HRSGs and arrive at the optimum system which matches the needs...

  3. Economics of Steam Pressure Reduction 

    E-Print Network [OSTI]

    Sylva, D. M.

    1985-01-01

    Economics of Steam Pressure Reduction is a technical paper that addresses the operating and economic advantages associated with the program to lower the steam operating pressure. Evaluation of a testing program will be discussed. The paper...

  4. Campus Energy Infrastructure Steam Turbine

    E-Print Network [OSTI]

    Rose, Michael R.

    Campus Energy Infrastructure Steam Turbine Gas Turbine University Substation High Pressure Natural,000 lbs/hr (with duct fire) Steam Turbine Chiller 2,000 tons Campus Heat Load 60 MMBtu/hr (average) Campus-hours) Generator Generator Heat Recovery Alternative Uses: 1. Campus heating load 2. Steam turbine chiller

  5. CGIAR Reform - Why So Difficult? Review, Reform, Renewal, Restructuring, Reform Again and then "The New CGIAR" - So Much Talk and So Little Basic Structural Change - Why?

    E-Print Network [OSTI]

    McCalla, Alex F

    2014-01-01

    Secretariat, FAO CGIAR Reform-Why So Difficult? 2013 TAC/of California, Davis CGIAR Reform — Why So Difficult?Review, Reform, Renewal, Restructuring, Reform Again and

  6. Method for using fast fluidized bed dry bottom coal gasification

    DOE Patents [OSTI]

    Snell, George J. (Fords, NJ); Kydd, Paul H. (Lawrenceville, NJ)

    1983-01-01

    Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature. This gasification arrangement provides for increased utilization of the secondary char material to produce higher overall carbon conversion and product yields in the process.

  7. Control of bed height in a fluidized bed gasification system

    DOE Patents [OSTI]

    Mehta, Gautam I. (Greensburg, PA); Rogers, Lynn M. (Export, PA)

    1983-12-20

    In a fluidized bed apparatus a method for controlling the height of the fdized bed, taking into account variations in the density of the bed. The method comprises taking simultaneous differential pressure measurements at different vertical elevations within the vessel, averaging the differential pressures, determining an average fluidized bed density, then periodically calculating a weighting factor. The weighting factor is used in the determination of the actual bed height which is used in controlling the fluidizing means.

  8. Hybrid Power Test Bed

    SciTech Connect (OSTI)

    NONE

    1996-06-01

    This document describes efforts by the National Renewable Energy Laboratory to simulate hybrid power systems. Hybrid power systems combine multiple power sources such as wind turbines, photovoltaic (PV) arrays, diesel generators, and battery storage systems. They typically are used in remote areas, away from major electric grids. The Hybrid Power Test Bed is designed to assist the U.S. wind industry in developing and testing hybrid power generation systems. Test bed capabilities, features, and equipment are described.

  9. Sea bed mechanics

    SciTech Connect (OSTI)

    Sleath, J.F.A.

    1984-01-01

    This book provides a discussion on sea bed processes with engineering applications. It brings together the material currently available only in technical reports of research papers. It provides formulae and background references necessary for design calculation of problems such as sea bed or coastal erosion, and sub-marine pipeline stability. It also covers dissipation of wave energy, formation of ripples and dunes, and the transportation of sediments.

  10. Steam Pressure Reduction Opportunities and Issues 

    E-Print Network [OSTI]

    Berry, J.; Griffin, B.; Wright, A. L.

    2006-01-01

    of changes in the high-pressure side of the steam system from the boiler through the condensate return system. In the boiler plant, losses from combustion, boiler blowdown, radiation, and steam venting from condensate receivers would be reduced... by reducing steam pressure. Similarly, in the steam distribution system, losses from radiation, flash steam vented from condensate receivers, and component and steam trap leakage would also be reduced. There are potential problems associated with steam...

  11. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, E.P. Jr.

    1999-01-12

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed there between. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock. 2 figs.

  12. Steam separator latch assembly

    DOE Patents [OSTI]

    Challberg, R.C.; Kobsa, I.R.

    1994-02-01

    A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof. 12 figures.

  13. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, Jr., Edward P. (Idaho Falls, ID)

    1999-01-01

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed therebetween. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock.

  14. Reforming using erionite catalysts

    SciTech Connect (OSTI)

    Liers, J.; Meusinger, J.; Moesch, A. (Univ. of Leipzig (Germany)); Reschetilowski, W. (Karl Winnacker Inst. of DECHEMA, Frankfurt (Germany))

    1993-08-01

    The advantage of reforming on erionite catalysts is a product with high octane numbers and low amounts of aromatics. This advantage seems to be slight at reaction pressures lower than 25 bar. But it is possible to compensate for the influence of pressure by varying the erionite content within the catalyst and the reaction temperature. When reforming on Pt/Al[sub 2]O[sub 3] catalysts, the following reactions take place: dehydrocyclization of paraffins to naphthenes, dehydrogenation of naphthenes to aromatics, isomerication of normal paraffins remains in the product, lowering its octane number. By using a Ni/H-erionite catalyst, the octane rating can be increased by 3 to 7 numbers through selective hydrocracking of n-alkanes in the reformate. Erionite catalysts favor shape-selective hydrocracking of normal paraffins and the formation of cyclopentane derivatives lowering the content of aromatics during reforming reactions. Reducing the reaction pressure decreases hydrocracking activity and cyclopentane formation. These results can be interpreted in terms of thermodynamic restrictions and deactivation.

  15. Fluidized bed heat exchanger with water cooled air distributor and dust hopper

    DOE Patents [OSTI]

    Jukkola, Walfred W. (Westport, CT); Leon, Albert M. (Mamaroneck, NY); Van Dyk, Jr., Garritt C. (Bethel, CT); McCoy, Daniel E. (Williamsport, PA); Fisher, Barry L. (Montgomery, PA); Saiers, Timothy L. (Williamsport, PA); Karstetter, Marlin E. (Loganton, PA)

    1981-11-24

    A fluidized bed heat exchanger is provided in which air is passed through a bed of particulate material containing fuel. A steam-water natural circulation system is provided for heat exchange and the housing of the heat exchanger has a water-wall type construction. Vertical in-bed heat exchange tubes are provided and the air distributor is water-cooled. A water-cooled dust hopper is provided in the housing to collect particulates from the combustion gases and separate the combustion zone from a volume within said housing in which convection heat exchange tubes are provided to extract heat from the exiting combustion gases.

  16. Production of activated carbon from coconut shell char in a fluidized bed reactor

    SciTech Connect (OSTI)

    Sai, P.M.S.; Ahmed, J. [Bhabha Atomic Research Centre, Kalpakkam (India). Centralised Waste Management Facility; Krishnaiah, K. [Indian Inst. of Tech., Madras (India). Dept. of Chemical Engineering

    1997-09-01

    Activated carbon is produced from coconut shell char using steam or carbon dioxide as the reacting gas in a 100 mm diameter fluidized bed reactor. The effect of process parameters such as reaction time, fluidizing velocity, particle size, static bed height, temperature of activation, fluidizing medium, and solid raw material on activation is studied. The product is characterized by determination of iodine number and BET surface area. The product obtained in the fluidized bed reactor is much superior in quality to the activated carbons produced by conventional processes. Based on the experimental observations, the optimum values of process parameters are identified.

  17. Pulsed atmospheric fluidized bed combustion. Final report

    SciTech Connect (OSTI)

    NONE

    1998-03-01

    ThermoChem, under contract to the Department of Energy, conducted extensive research, development and demonstration work on a Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) to confirm that advanced technology can meet these performance objectives. The ThermoChem/MTCI PAFBC system integrates a pulse combustor with an atmospheric bubbling-bed type fluidized bed combustor (BFBC) In this modular configuration, the pulse combustor burns the fuel fines (typically less than 30 sieve or 600 microns) and the fluidized bed combusts the coarse fuel particles. Since the ThermoChem/MTCI PAFBC employs both the pulse combustor and the AFBC technologies, it can handle the full-size range of coarse and fines. The oscillating flow field in the pulse combustor provides for high interphase and intraparticle mass transfer rates. Therefore, the fuel fines essentially burn under kinetic control. Due to the reasonably high temperature (>1093 C but less than the temperature for ash fusion to prevent slagging), combustion of fuel fines is substantially complete at the exit of the pulse combustor. The additional residence time of 1 to 2 seconds in the freeboard of the PAFBC unit then ensures high carbon conversion and, in turn, high combustion efficiency. A laboratory unit was successfully designed, constructed and tested for over 600 hours to confirm that the PAFBC technology could meet the performance objectives. Subsequently, a 50,000 lb/hr PAFBC demonstration steam boiler was designed, constructed and tested at Clemson University in Clemson, South Carolina. This Final Report presents the detailed results of this extensive and successful PAFBC research, development and demonstration project.

  18. Water-Efficient Technology Opportunity: Steam Sterilizer Condensate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Sterilizer Condensate Retrofit Kit Water-Efficient Technology Opportunity: Steam Sterilizer Condensate Retrofit Kit Steam sterilizers are heated by steam that condenses and...

  19. Dry reforming of hydrocarbon feedstocks

    SciTech Connect (OSTI)

    Shah, Yatish T.; Gardner, Todd H.

    2014-09-25

    Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

  20. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine induustrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100[degrees]F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600[degrees]F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  1. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine industrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100{degrees}F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600{degrees}F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  2. Steam Technical Brief: Industrial Steam System Heat-Transfer Solutions

    SciTech Connect (OSTI)

    None

    2010-06-25

    This BestPractices Steam Technical Brief provides an overview of considerations for selecting the best heat-transfer solution for various applications.

  3. Steam Pressure Reduction: Opportunities and Issues; A BestPractices Steam Technical Brief

    SciTech Connect (OSTI)

    Not Available

    2005-11-01

    A BestPractices Technical Brief describing industrial steam generation systems and opportunities for reducing steam system operating pressure.

  4. The Elimination of Steam Traps 

    E-Print Network [OSTI]

    Dickman, F.

    1985-01-01

    compile published data by three leading steam trap facturers. ANNUAL COST OF STEAM LOSS FOR 100 PSIG STEAM AT $5/1000 LBS. TgpOrlflce l18nul8ctuNf M.,utectu,., DI.mNr A' 84 1/." . $ 3,150 $ 2,313 e to from nu ufKluNf co 3,1711 1/4" $12,eoo $ 9...

  5. FEEDSTOCK-FLEXIBLE REFORMER SYSTEM (FFRS) FOR SOLID OXIDE FUEL CELL (SOFC)- QUALITY SYNGAS

    SciTech Connect (OSTI)

    Kelly Jezierski; Andrew Tadd; Johannes Schwank; Roland Kibler; David McLean; Mahesh Samineni; Ryan Smith; Sameer Parvathikar; Joe Mayne; Tom Westrich; Jerry Mader; F. Michael Faubert

    2010-07-30

    The U.S. Department of Energy National Energy Technology Laboratory funded this research collaboration effort between NextEnergy and the University of Michigan, who successfully designed, built, and tested a reformer system, which produced highquality syngas for use in SOFC and other applications, and a novel reactor system, which allowed for facile illumination of photocatalysts. Carbon and raw biomass gasification, sulfur tolerance of non-Platinum Group Metals (PGM) based (Ni/CeZrO2) reforming catalysts, photocatalysis reactions based on TiO2, and mild pyrolysis of biomass in ionic liquids (ILs) were investigated at low and medium temperatures (primarily 450 to 850 C) in an attempt to retain some structural value of the starting biomass. Despite a wide range of processes and feedstock composition, a literature survey showed that, gasifier products had narrow variation in composition, a restriction used to develop operating schemes for syngas cleanup. Three distinct reaction conditions were investigated: equilibrium, autothermal reforming of hydrocarbons, and the addition of O2 and steam to match the final (C/H/O) composition. Initial results showed rapid and significant deactivation of Ni/CeZrO2 catalysts upon introduction of thiophene, but both stable and unstable performance in the presence of sulfur were obtained. The key linkage appeared to be the hydrodesulfurization activity of the Ni reforming catalysts. For feed stoichiometries where high H2 production was thermodynamically favored, stable, albeit lower, H2 and CO production were obtained; but lower thermodynamic H2 concentrations resulted in continued catalyst deactivation and eventual poisoning. High H2 levels resulted in thiophene converting to H2S and S surface desorption, leading to stable performance; low H2 levels resulted in unconverted S and loss in H2 and CO production, as well as loss in thiophene conversion. Bimetallic catalysts did not outperform Ni-only catalysts, and small Ni particles were found to have lower activities under S-free conditions, but did show less effect of S on performance, in this study. Imidazolium-based ILs, choline chloride compounds and low-melting eutectics of metal nitrates were evaluated, and it was found that, ILs have some capacity to dissolve cellulose and show thermal stability to temperatures where pyrolysis begins, have no vapor pressure, (simplifying product recoveries), and can dissolve ionic metal salts, allowing for the potential of catalytic reactions on breakdown intermediates. Clear evidence of photoactive commercial TiO2 was obtained, but in-house synthesis of photoactive TiO2 proved difficult, as did fixed-bed gasification, primarily due to the challenge of removing the condensable products from the reaction zone quickly enough to prevent additional reaction. Further investigation into additional non-PGM catalysts and ILs is recommended as a follow-up to this work.

  6. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    1999-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  7. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  8. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  9. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  10. Apparatus for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, A.G.; Patel, J.G.

    1987-05-12

    An apparatus and process are disclosed for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance. 2 figs.

  11. Apparatus for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, Amirali G. (Westmont, IL); Patel, Jitendra G. (Bolingbrook, IL)

    1987-05-12

    An apparatus and process for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance.

  12. Staged fluidized bed

    DOE Patents [OSTI]

    Mallon, R.G.

    1983-05-13

    The invention relates to oil shale retorting and more particularly to staged fluidized bed oil shale retorting. Method and apparatus are disclosed for narrowing the distribution of residence times of any size particle and equalizing the residence times of large and small particles in fluidized beds. Particles are moved up one fluidized column and down a second fluidized column with the relative heights selected to equalize residence times of large and small particles. Additional pairs of columns are staged to narrow the distribution of residence times and provide complete processing of the material.

  13. Transportation Safeguards & Security Test Bed (TSSTB) | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Safeguards and Security Test Bed May 30, 2013 The Transportation Safeguards and Security Test Bed consists of a test-bed vehicle and a monitoringlaboratorytraining...

  14. Stability of Gas-Fluidized Beds

    E-Print Network [OSTI]

    Mandich, Kevin Matthew

    Temperature in a Bubbling Fluidized Bed, To Be Submitted tomechanisms of bubbling in fluidized beds. A simpler analysiswith the nature of bubbling in fluidized beds. When bubbles

  15. Distributed Bio-Oil Reforming

    Broader source: Energy.gov [DOE]

    Presentation by NREL's Robert Evans at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  16. Tax Reform and Real Estate

    E-Print Network [OSTI]

    Maisel, Sherman J.; Quigley, John M.

    1985-01-01

    Berkeley CENTER Eon REAL ESTATE ANDURBAN ECONOMICS WORKING85-100 TAX REFORM AND REAL ESTATE BY SHERMAN J. MAISEL JOHNADMINISTRATION CENTER FOR REAL ESTATE AND URBAN ECONOMICS

  17. Review of Orifice Plate Steam Traps

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... 25 iv v LIST OF FIGURES Figure Page 1 Steam supply and condensate drainage piping for a common space heater ... 1 2 Typical orifice plate steam...

  18. Steam Digest 2001: Office of Industrial Technologies

    SciTech Connect (OSTI)

    None, None

    2002-01-01

    Steam Digest 2001 chronicles Best Practices Program's contributions to the industrial trade press for 2001, and presents articles that cover technical, financial and managerial aspects of steam optimization.

  19. Development of the first demonstration CFB boiler for gas and steam cogeneration

    SciTech Connect (OSTI)

    Fang, M; Luo, Z.; Li, X.; Wang, Q.; Shi, Z.; Ni, M.; Cen, K.

    1997-12-31

    To solve the shortage of gas and steam supply in the small towns of the country, a new gas steam cogeneration system has been developed. On the basis of the fundamental research on the system, a demonstration gas steam cogeneration system has been designed. As the phase 1 of the project, a 75t/h demonstration CFB boiler for gas steam cogeneration has been erected and operated at Yangzhong Thermal Power Plant of China. This paper introduces the first 75t/h demonstration CFB boiler for gas steam cogeneration. Due to the need of gas steam cogeneration process, the boiler has the features of high temperature cyclone separation, high solid recycle ratio, staged combustion and an external heat exchanger adjusting bed temperature and heat load. The operation results show that the boiler has wide fuel adaptability and the heating value of the coal changes from 14MJ/Kg to 25MJ/Kg. The heat load changes from 85t/h to 28t/h while steam parameter is maintained at the normal conditions. The combustion efficiency of the boiler attain 98%. The boiler design and operation experiences may be a guide to the design and operation of larger CFB units in the future.

  20. Steam boosted internal combustion engine

    SciTech Connect (OSTI)

    Green, M.A.

    1987-01-20

    A device is described to supplement the power produced by burning fuel in an internal combustion engine with steam, the device comprising: a means for producing a constant flow of water past a boiler means; a means for allowing the water to flow in the direction of the boiler; a boiler means external to the internal combustion engine to convert the water into superheated steam; a means for controlling the pressure of the water such that the water pressure is greater than the pressure of the steam produced by the boiler; and a means for injection of the superheated steam directly into a cylinder of the internal combustion engine, a means for producing a constant flow of water at a pressure greater than the pressure of the superheated steam, wherein the constant flow means at greater pressure comprises a chamber with a gaseous component, with the gaseous component being of constant volume and exerting constant pressure upon water within the chamber.

  1. AEDP & Healthcare Reform Dipti Patel, FSA, MAAA

    E-Print Network [OSTI]

    Hong, Don

    Cigna AEDP & Healthcare Reform Dipti Patel, FSA, MAAA March 19, 2012 #12; Introductions Introducing... Cigna An overview of the AEDP Healthcare Reform Questions and Answers Overview #12 Branding ­ "GO YOU" · Things are changing ­ Health Care Reform · Young, energetic, executive leadership

  2. Packed Bed Combustion: An Overview

    E-Print Network [OSTI]

    Hallett, William L.H.

    Packed Bed Combustion: An Overview William Hallett Dept. of Mechanical Engineering Université d'Ottawa - University of Ottawa #12;Packed Bed Combustion - University of Ottawa - CICS 2005 Introduction air fuel feedproducts xbed grate Packed Bed Combustion: fairly large particles of solid fuel on a grate, air supplied

  3. Federal Information Technology Acquisition Reform Act (FITARA...

    Energy Savers [EERE]

    Information Technology Acquisition Reform Act (FITARA) Data Resources Federal Information Technology Acquisition Reform Act (FITARA) Data Resources FITARA Resources Available for...

  4. Synthesis and characterization of catalysts containing nickel for reforming methane with carbon dioxide 

    E-Print Network [OSTI]

    Sommer, Michael Edward

    1988-01-01

    may have reacted with oxygen. This was confirmed by a thermal analysis which revealed an endothermic peak corresponding to a 15% weight loss on ignition at 600'C. Nitrogen was passed through the reactor during the warm up period. Manual adjustment... to form and to be distributed on the atomic scale, thus yielding active catalysts. CHAPTER II LITERATURE REVIEW Traditional reforming of hydrocarbons has been performed using steam. New processes are in need of a syngas with lower hydrogen content...

  5. Steam Power Partnership: Improving Steam System Efficiency Through Marketplace Partnerships 

    E-Print Network [OSTI]

    Jones, T.

    1997-01-01

    The Alliance to Save Energy, a national nonprofit organization based in Washington DC, and the U.S. Department of Energy are working with energy efficiency suppliers to promote the comprehensive upgrade of industrial steam systems. Like EPA's Green...

  6. ProSteam- A Structured Approach to Steam System Improvement 

    E-Print Network [OSTI]

    Eastwood, A.

    2002-01-01

    improved insulation, better condensate return, increased process integration, new steam turbines or even the installation of gas-turbine based cogeneration. This approach allows sites to develop a staged implementation plan for both operational and capital...

  7. Trends in packaged steam generators

    SciTech Connect (OSTI)

    Ganapathy, V. [ABCO Industries, Abilene, TX (United States)

    1996-09-01

    Oil and gas-fired packaged steam generators are used in many industrial plants. They generate saturated or superheated steam up to 250,000 lb/hr, 1000 psig, and 950 F. They may be used for continuous steam generation or as standby boilers in cogeneration systems. Numerous variables affect the design of this equipment. A few important considerations should be addressed at an early point by the plant engineer specifying or evaluating equipment options. These considerations include trends such as customized designs that minimize operating costs and ensure emissions regulations are met. The paper discusses efficiency considerations first.

  8. Wet-steam erosion of steam turbine disks and shafts

    SciTech Connect (OSTI)

    Averkina, N. V.; Zheleznyak, I. V.; Kachuriner, Yu. Ya.; Nosovitskii, I. A.; Orlik, V. G.; Shishkin, V. I.

    2011-01-15

    A study of wet-steam erosion of the disks and the rotor bosses or housings of turbines in thermal and nuclear power plants shows that the rate of wear does not depend on the diagrammed degree of moisture, but is determined by moisture condensing on the surfaces of the diaphragms and steam inlet components. Renovating the diaphragm seals as an assembly with condensate removal provides a manifold reduction in the erosion.

  9. Non-Isothermal Steam Mixing Motivation & Objectives

    E-Print Network [OSTI]

    Psaltis, Demetri

    gas turbine is connected to a heat recovery steam generator (HRSG), which together feed a single steam turbine. When running multiple gas turbines at different loads, the HRSGs will produce steam streams into the intermediate pressure (IP) steam turbine (figure 1). The goal of this thesis is to determine a compact yet

  10. Combined Heat and Power Plant Steam Turbine

    E-Print Network [OSTI]

    Rose, Michael R.

    waste heat) Gas Turbine University Substation High Pressure Natural Gas Campus Electric Load SouthernCombined Heat and Power Plant Steam Turbine Steam Turbine Chiller Campus Heat Load Steam (recovered Generator Heat Recovery Alternative Uses: 1. Campus heating load 2. Steam turbine chiller to campus cooling

  11. Steam Plant Conversion Eliminating Campus Coal Use

    E-Print Network [OSTI]

    Dai, Pengcheng

    Steam Plant Conversion Eliminating Campus Coal Use at the Steam Plant #12;· Flagship campus region produce 14% of US coal (TN only 0.2%) Knoxville and the TN Valley #12;· UT is one of about 70 U.S. colleges and universities w/ steam plant that burns coal · Constructed in 1964, provides steam for

  12. The Steam System Scoping Tool: Benchmarking Your Steam Operations Through Best Practices 

    E-Print Network [OSTI]

    Wright, A.; Hahn, G.

    2001-01-01

    system efficiency. The BestPractices Steam effort, a part of the DOE-OIT effort, has developed a new tool that steam energy managers and operations personnel can use to assess their steam operations and improve their steam energy usage -the Steam System...

  13. Steam System Improvement: A Case Study 

    E-Print Network [OSTI]

    Venkatesan, V. V.; Leigh, N.

    1998-01-01

    , steam requirements for bo process heating and power service do not alwa s coincide. This may leads to an excess of 10 pressure steam that needs to be vented, or a de d for low-pressure steam that has to be supplied from a PRY. Condensing low... condensate. Other direct steam users like oil burners soot blowers and desalters are not in service. Condensate from the steam distribution system is returned to the boiler house in two ways. For large steam users with modulating pressure, steam drums...

  14. Pulsed atmospheric fluidized bed combustion. Quarterly technical progress report, July 1992--September 1992

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    The design of the Pulsed Atmospheric Fluidized Bed Combustor (PAFBC) as described in the Quarterly Report for the period April--June, 1992 was reviewed and minor modifications were included. The most important change made was in the coal/limestone preparation and feed system. Instead of procuring pre-sized coal for testing of the PAFBC, it was decided that the installation of a milling system would permit greater flexibility in the testing with respect to size distributions and combustion characteristics in the pulse combustor and the fluid bed. Particle size separation for pulse combustor and fluid bed will be performed by an air classifier. The modified process flow diagram for the coal/limestone handling system is presented in Figure 1. The modified process flow diagrams of the fluidized bed/steam cycle and ash handling systems are presented in Figures 2 and 3, respectively.

  15. Design and performance of a high-pressure Fischer-Tropsch fluidized bed reactor

    SciTech Connect (OSTI)

    Weimer, A.W.; Quarderer, G.J.; Cochran, G.A.; Conway, M.M. )

    1988-01-01

    A 900 kg/day, CO/H/sub 2/, high-pressure, fluidized bed, pilot reactor was designed from first principles to achieve high reactant conversions and heat removal rates for the Fischer-Tropsch (F-T) synthesis of liquefied petroleum gases (LPG's). Suppressed bubble growth at high pressure allowed high reactant conversions which nearly matched those obtained at identical conditions in a lab scale fixed bed reactor. For GHSV approximately 1400 hr/sup -1/ and T = 658 {Kappa} at P approximately 7000 {kappa}Pa, reactant conversion exceeded 75%. The reactor heat removal capability exceeded twice design performance with the fluidized bed easily operating under thermally stable conditions. The fluidized catalyst was a potassium promoted, molybdenum on carbon (Mo/{Kappa}/C) catalyst which did not produce any detrimental waxy products. Long catalyst lifetimes of 1000 hrs on steam between regenerations allowed the fluidized bed to be operated in a batch mode.

  16. Foam Cleaning of Steam Turbines 

    E-Print Network [OSTI]

    Foster, C.; Curtis, G.; Horvath, J. W.

    2000-01-01

    The efficiency and power output of a steam turbine can be dramatically reduced when deposits form on the turbine blades. Disassembly and mechanical cleaning of the turbine is very time consuming and costly. Deposits can be removed from the turbine...

  17. CIRCULATING MOVING BED COMBUSTION PROOF OF CONCEPT

    SciTech Connect (OSTI)

    Jukkola, Glen

    2010-06-30

    Circulating Moving Bed (CMB) combustion technology has its roots in traditional circulating fluidized bed technology and involves a novel method of solid fuel combustion and heat transfer. CMB technology represents a step change in improved performance and cost relative to conventional PC and FBC boilers. The CMB heat exchanger preheats the energy cycle working fluid, steam or air, to the high temperature levels required in systems for advanced power generation. Unique features of the CMB are the reduction of the heat transfer surfaces by about 60% as a result of the enhanced heat transfer rates, flexibility of operation, and about 30% lower cost over existing technology. The CMB Phase I project ran from July 2001 through March 2003. Its objective was to continue development of the CMB technology with a series of proof of concept tests. The tests were conducted at a scale that provided design data for scale up to a demonstration plant. These objectives were met by conducting a series of experiments in ALSTOM Power’s Multi-use Test Facility (MTF). The MTF was modified to operate under CMB conditions of commercial interest. The objective of the tests were to evaluate gas-to-solids heat transfer in the upper furnace, assess agglomeration in the high temperature CMB bubbling bed, and evaluate solids-to-tube heat transfer in the moving bed heat exchanger. The Phase I program results showed that there are still some significant technical uncertainties that needed to be resolved before the technology can be confidently scaled up for a successful demonstration plant design. Work remained in three primary areas: • scale up of gas to solid heat transfer • high temperature finned surface design • the overall requirements of mechanical and process design. The CMB Phase II workscope built upon the results of Phase I and specifically addressed the remaining technical uncertainties. It included a scaled MTF heat transfer test to provide the necessary data to scale up gas-to-solids heat transfer. A stress test rig was built and tested to provide validation data for a stress model needed to support high temperature finned surface design. Additional cold flow model tests and MTF tests were conducted to address mechanical and process design issues. This information was then used to design and cost a commercial CMB design concept. Finally, the MBHE was reconfigured into a slice arrangement and tested for an extended duration at a commercial CFB plant.

  18. Concept for a super-clean super-efficient pressurized fluidized-bed combustion system

    SciTech Connect (OSTI)

    Mollott, D.J.; Reed, M.

    1994-12-31

    A paper study for a highly efficient, environmentally benign, coal-fired electric power generation system, is presented. This system falls in the category of pressurized fluidized-bed combustion (PFBC) systems which has been dubbed super-clean super-efficient PFBC`s. The system presented starts with the second-generation PFBC concept and adds on advanced gas turbine, a solid oxide fuel cell, a supercritical steam cycle, a second low-temperature rankine cycle which pulls energy from the steam condenser, and inlet air cooling. The thermodynamic efficiency of the system is calculated to be 61.8 percent based on higher heating value (HHV).

  19. Hot waste-to-energy flue gas treatment using an integrated fluidised bed reactor

    SciTech Connect (OSTI)

    Bianchini, A.; Pellegrini, M. [DIEM, Department of Mechanical Engineering, Faculty of Engineering, University of Bologna, Viale Risorgimento 2, 40136 Bologna (Italy); Saccani, C. [DIEM, Department of Mechanical Engineering, Faculty of Engineering, University of Bologna, Viale Risorgimento 2, 40136 Bologna (Italy)], E-mail: cesare.saccani@unibo.it

    2009-04-15

    This paper describes an innovative process to increase superheated steam temperatures in waste-to-energy (WTE) plants. This solution is mainly characterised by a fluidised bed reactor in which hot flue gas is treated both chemically and mechanically. This approach, together with gas recirculation, increases the energy conversion efficiency, and raises the superheated steam temperature without decreasing the useful life of the superheater. This paper presents new experimental data obtained from the test facility installed at the Hera S.p.A. WTE plant in Forli, Italy; discusses changes that can be implemented to increase the duration of experimental testing; offers suggestions for the design of an industrial solution.

  20. Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation

    E-Print Network [OSTI]

    Lu, Xiaoming

    2012-01-01

    to make additional steam for the steam turbine cycle. Thein multi-pressure-level steam turbines to produce additionalthe superheated steam to the steam turbine cycle. The most

  1. A Novel Slurry-Based Biomass Reforming Process Final Technical Report

    SciTech Connect (OSTI)

    Sean C. Emerson; Timothy D. Davis; A. Peles; Ying She; Joshua Sheffel; Rhonda R. Willigan; Thomas H. Vanderspurt; Tianli Zhu

    2011-09-30

    This project was focused on developing a catalytic means of producing H2 from raw, ground biomass, such as fast growing poplar trees, willow trees, or switch grass. The use of a renewable, biomass feedstock with minimal processing can enable a carbon neutral means of producing H2 in that the carbon dioxide produced from the process can be used in the environment to produce additional biomass. For economically viable production of H2, the biomass is hydrolyzed and then reformed without any additional purification steps. Any unreacted biomass and other byproduct streams are burned to provide process energy. Thus, the development of a catalyst that can operate in the demanding corrosive environment and presence of potential poisons is vital to this approach. The concept for this project is shown in Figure 1. The initial feed is assumed to be a >5 wt% slurry of ground wood in dilute base, such as potassium carbonate (K2CO3). Base hydrolysis and reforming of the wood is carried out at high but sub-critical pressures and temperatures in the presence of a solid catalyst. A Pd alloy membrane allows the continuous removal of pure , while the retentate, including methane is used as fuel in the plant. The project showed that it is possible to economically produce H2 from woody biomass in a carbon neutral manner. Technoeconomic analyses using HYSYS and the DOE's H2A tool [1] were used to design a 2000 ton day-1 (dry basis) biomass to hydrogen plant with an efficiency of 46% to 56%, depending on the mode of operation and economic assumptions, exceeding the DOE 2012 target of 43%. The cost of producing the hydrogen from such a plant would be in the range of $1/kg H2 to $2/kg H2. By using raw biomass as a feedstock, the cost of producing hydrogen at large biomass consumption rates is more cost effective than steam reforming of hydrocarbons or biomass gasification and can achieve the overall cost goals of the DOE Fuel Cell Technologies Program. The complete conversion of wood to hydrogen, methane, and carbon dioxide was repeatedly demonstrated in batch reactors varying in size from 50 mL to 7.6 L. The different wood sources (e.g., swamp maple, poplar, and commercial wood flour) were converted in the presence of a heterogeneous catalyst and base at relatively low temperatures (e.g., 310 �������°C) at sub-critical pressures sufficient to maintain the liquid phase. Both precious metal and base metal catalysts were found to be active for the liquid phase hydrolysis and reforming of wood. Pt-based catalysts, particularly Pt-Re, were shown to be more selective toward breaking C-C bonds, resulting in a higher selectivity to hydrogen versus methane. Ni-based catalysts were found to prefer breaking C-O bonds, favoring the production of methane. The project showed that increasing the concentration of base (base to wood ratio) in the presence of Raney Ni catalysts resulted in greater selectivity toward hydrogen but at the expense of increasing the production of undesirable organic acids from the wood, lowering the amount of wood converted to gas. It was shown that by modifying Ni-based catalysts with dopants, it was possible to reduce the base concentration while maintaining the selectivity toward hydrogen and increasing wood conversion to gas versus organic acids. The final stage of the project was the construction and testing of a demonstration unit for H2 production. This continuous flow demonstration unit consisted of wood slurry and potassium carbonate feed pump systems, two reactors for hydrolysis and reforming, and a gas-liquid separation system. The technical challenges associated with unreacted wood fines and Raney Ni catalyst retention limited the demonstration unit to using a fixed bed Raney Ni catalyst form. The lower activity of the larger particle Raney Ni in turn limited the residence time and thus the wood mass flow feed rate to 50 g min-1 for a 1 wt% wood slurry. The project demonstrated continuous H2 yields with unmodified, fixed bed Raney Ni, from 63% to 100% with correspond

  2. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  3. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

    1995-01-01

    A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves.

  4. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN)

    1993-01-01

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves.

  5. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

    1996-01-01

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves.

  6. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.; Marasco, J.A.

    1995-04-25

    A fluidized bed reactor system utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figs.

  7. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.

    1993-12-14

    A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase is described. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary particulate phase, continuously introduced and removed in either cocurrent or countercurrent mode, acts in a secondary role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Introduction and removal of the sorbent phase is accomplished through the use of feed screw mechanisms and multivane slurry valves. 3 figures.

  8. Biparticle fluidized bed reactor

    DOE Patents [OSTI]

    Scott, C.D.; Marasco, J.A.

    1996-02-27

    A fluidized bed reactor system is described which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves. 3 figs.

  9. Fluidized bed boiler feed system

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1981-01-01

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  10. Method for packing chromatographic beds

    DOE Patents [OSTI]

    Freeman, David H. (Potomac, MD); Angeles, Rosalie M. (Germantown, MD); Keller, Suzanne (Rockville, MD)

    1991-01-01

    Column chromatography beds are packed through the application of static force. A slurry of the chromatography bed material and a non-viscous liquid is filled into the column plugged at one end, and allowed to settle. The column is transferred to a centrifuge, and centrifuged for a brief period of time to achieve a predetermined packing level, at a range generally of 100-5,000 gravities. Thereafter, the plug is removed, other fixtures may be secured, and the liquid is allowed to flow out through the bed. This results in an evenly packed bed, with no channeling or preferential flow characteristics.

  11. Consider Steam Turbine Drives for Rotating Equipment | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Turbine Drives for Rotating Equipment Consider Steam Turbine Drives for Rotating Equipment This tip sheet outlines the benefits of steam turbine drives for rotating equipment...

  12. Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam

    SciTech Connect (OSTI)

    Not Available

    2005-09-01

    Industrial Technologies Program's BestPractices tip sheet on improving efficiency of industrial steam systems by recovery latent heat from low-pressure steam.

  13. Steam Pressure Reduction, Opportunities, and Issues

    SciTech Connect (OSTI)

    Berry, Jan [ORNL; Griffin, Mr. Bob [Enbridge Gas Distribution, Inc.; Wright, Anthony L [ORNL

    2006-01-01

    Steam pressure reduction has the potential to reduce fuel consumption for a minimum capital investment. When the pressure at the boiler is reduced, fuel and steam are saved as a result of changes in the high-pressure side of the steam system from the boiler through the condensate return system. In the boiler plant, losses from combustion, boiler blowdown, radiation, and steam venting from condensate receivers would be reduced by reducing steam pressure. Similarly, in the steam distribution system, losses from radiation, flash steam vented from condensate receivers, and component and steam trap leakage would also be reduced. There are potential problems associated with steam pressure reduction, however. These may include increased boiler carryover, boiler water circulation problems in watertube boilers, increased steam velocity in piping, loss of power in steam turbines, and issues with pressure reducing valves. This paper is based a Steam Technical Brief sponsored by the U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy and Enbridge Gas Distribution, Inc. (5). An example illustrates the use of DOE BestPractices Steam System Assessment Tool to model changes in steam, fuel, electricity generation, and makeup water and to estimate resulting economic benefits.

  14. Distributed Bio-Oil Reforming

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mines Bio-Derived Liquids Distributed Reforming Working Group Meeting HFC&IT Program Baltimore, MD October 24, 2006 1 Gasification Partial oxidation CH 1.46 O .67 + 0.16 O 2 ...

  15. Tax Reform and Real Estate

    E-Print Network [OSTI]

    Rosen, Kenneth T.; Lepcio, Andrea

    1986-01-01

    investment opportunities in real estate. -13- Appentlix CashBerkeley CENTER FOR REAL ESTATE S AND URBAN ECONOMICSPAPER 86-117 TAX REFORM AND REAL ESTATE_ BY KENNETH T. ROSEN

  16. Pressurized fluidized bed reactor

    DOE Patents [OSTI]

    Isaksson, J.

    1996-03-19

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine. 1 fig.

  17. Pressurized fluidized bed reactor

    DOE Patents [OSTI]

    Isaksson, Juhani (Karhula, FI)

    1996-01-01

    A pressurized fluid bed reactor power plant includes a fluidized bed reactor contained within a pressure vessel with a pressurized gas volume between the reactor and the vessel. A first conduit supplies primary gas from the gas volume to the reactor, passing outside the pressure vessel and then returning through the pressure vessel to the reactor, and pressurized gas is supplied from a compressor through a second conduit to the gas volume. A third conduit, comprising a hot gas discharge, carries gases from the reactor, through a filter, and ultimately to a turbine. During normal operation of the plant, pressurized gas is withdrawn from the gas volume through the first conduit and introduced into the reactor at a substantially continuously controlled rate as the primary gas to the reactor. In response to an operational disturbance of the plant, the flow of gas in the first, second, and third conduits is terminated, and thereafter the pressure in the gas volume and in the reactor is substantially simultaneously reduced by opening pressure relief valves in the first and third conduits, and optionally by passing air directly from the second conduit to the turbine.

  18. Bed topography and the development of forced bed surface patches

    E-Print Network [OSTI]

    Venditti, Jeremy G.

    stress field, calculated from velocity measurements and with a quasithreedimensional hydraulic model (Fa which we made measurements of local nearbed velocity and sediment transport. The bed developedSTMECH), displayed substantial variability across the bar unit. Bed surface grain size did not correlate with local

  19. The Dynamics of Reform of India’s Federal System

    E-Print Network [OSTI]

    Singh, Nirvikar

    2007-01-01

    Conflict and Economic Reform in the Developing World, Newconstraints to economic reforms that provide aggregateExpenditures and Economic Reform in India,” Journal of

  20. Essays on India’s Economy: Perspectives on Policy Reform

    E-Print Network [OSTI]

    Singh, Nirvikar

    2014-01-01

    Perspectives on Policy Reform Nirvikar Singh Professor ofwith economic policy reform. The essays are organized intofinancial inclusion and tax reform. This is followed by a

  1. Changing Tracks? The Prospect for California Pension Reform

    E-Print Network [OSTI]

    Kogan, Vladimir; McCubbins, Mathew D

    2010-01-01

    for California Pension Reform Notes We focus on the combinedfor California Pension Reform Vladimir Kogan University ofCalifornia budget, pension reform, fiscal oversight

  2. Administering Democracy: Public Opinion on Election Reform in California

    E-Print Network [OSTI]

    Bergman, Elizabeth

    2012-01-01

    Consequences of Electoral Reform in the United States. ”Turnout and Institutional Reform in Oregon. ” Social SciencePublic Opinion on Election Reform in California Elizabeth

  3. The role of the district office in instructional practice reform

    E-Print Network [OSTI]

    Rizzi, Karen Schultz

    2008-01-01

    reality: Standards-based reform in urban districts. MenloW. A. (1989). Using reform: Conceptualizing districtHow districts support school reform. Seattle: University of

  4. Use Steam Jet Ejectors or Thermoscompressors to Reduce Venting of Low-Pressure Steam - Steam Tip Sheet #29

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO tip sheet on steam jet ejectors and thermocompressors provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  5. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    The general specifications for a Pulsed Atmospheric Fluidized Bed Combustor Design Report (PAFBC) plant are presented. The design tasks for the PAFBC are described in the following areas: Coal/Limestone preparation and feed system; pulse combustor; fluidized bed; boiler parts; and ash handling system.

  6. Solar Reforming of Carbon Dioxide to Produce Diesel Fuel

    SciTech Connect (OSTI)

    Dennis Schuetzle; Robert Schuetzle

    2010-12-31

    This project focused on the demonstration of an innovative technology, referred to as the Sunexus CO2 Solar Reformer, which utilizes waste CO2 as a feedstock for the efficient and economical production of synthetic diesel fuel using solar thermal energy as the primary energy input. The Sunexus technology employs a two stage process for the conversion of CO2 to diesel fuel. A solar reforming system, including a specially designed reactor and proprietary CO2 reforming catalyst, was developed and used to convert captured CO2 rich gas streams into syngas (primarily hydrogen and carbon monoxide) using concentrated solar energy at high conversion efficiencies. The second stage of the system (which has been demonstrated under other funding) involves the direct conversion of the syngas into synthetic diesel fuel using a proprietary catalyst (Terra) previously developed and validated by Pacific Renewable Fuels and Chemicals (PRFC). The overall system energy efficiency for conversion of CO2 to diesel fuel is 74%, due to the use of solar energy. The results herein describe modeling, design, construction, and testing of the Sunexus CO2 Solar Reformer. Extensive parametric testing of the solar reformer and candidate catalysts was conducted and chemical kinetic models were developed. Laboratory testing of the Solar Reformer was successfully completed using various gas mixtures, temperatures, and gas flow rates/space velocities to establish performance metrics which can be employed for the design of commercial plants. A variety of laboratory tests were conducted including dry reforming (CO2 and CH{sub 4}), combination dry/steam reforming (CO2, CH{sub 4} & H{sub 2}O), and tri-reforming (CO2, CH{sub 4}, H{sub 2}O & O{sub 2}). CH{sub 4} and CO2 conversions averaged 95-100% and 50-90% per reformer cycle, respectively, depending upon the temperatures and gas space velocities. No formation of carbon deposits (coking) on the catalyst was observed in any of these tests. A 16 ft. diameter, concentrating solar dish was modified to accommodate the Sunexus CO2 Solar Reformer and the integrated system was installed at the Pacific Renewable Fuels and Chemicals test site at McClellan, CA. Several test runs were conducted without catalyst during which the ceramic heat exchanger in the Sunexus Solar Reformer reached temperatures between 1,050 F (566 C) and 2,200 F (1,204 C) during the test period. A dry reforming mixture of CO2/CH{sub 4} (2.0/1.0 molar ratio) was chosen for all of the tests on the integrated solar dish/catalytic reformer during December 2010. Initial tests were carried out to determine heat transfer from the collimated solar beam to the catalytic reactor. The catalyst was operated successfully at a steady-state temperature of 1,125 F (607 C), which was sufficient to convert 35% of the 2/1 CO2/CH{sub 4} mixture to syngas. This conversion efficiency confirmed the results from laboratory testing of this catalyst which provided comparable syngas production efficiencies (40% at 1,200 F [650 C]) with a resulting syngas composition of 20% CO, 16% H{sub 2}, 39% CO2 and 25% CH{sub 4}. As based upon the laboratory results, it is predicted that 90% of the CO2 will be converted to syngas in the solar reformer at 1,440 F (782 C) resulting in a syngas composition of 50% CO: 43% H{sub 2}: 7% CO2: 0% CH{sub 4}. Laboratory tests show that the higher catalyst operating temperature of 1,440 F (782 C) for efficient conversion of CO2 can certainly be achieved by optimizing solar reactor heat transfer, which would result in the projected 90% CO2-to-syngas conversion efficiencies. Further testing will be carried out during 2011, through other funding support, to further optimize the solar dish CO2 reformer. Additional studies carried out in support of this project and described in this report include: (1) An Assessment of Potential Contaminants in Captured CO2 from Various Industrial Processes and Their Possible Effect on Sunexus CO2 Reforming Catalysts; (2) Recommended Measurement Methods for Assessing Contaminant Levels in Captured CO2 Streams; (3) An Asse

  7. Dynamic bed reactor

    DOE Patents [OSTI]

    Stormo, Keith E. (Moscow, ID)

    1996-07-02

    A dynamic bed reactor is disclosed in which a compressible open cell foam matrix is periodically compressed and expanded to move a liquid or fluid through the matrix. In preferred embodiments, the matrix contains an active material such as an enzyme, biological cell, chelating agent, oligonucleotide, adsorbent or other material that acts upon the liquid or fluid passing through the matrix. The active material may be physically immobilized in the matrix, or attached by covalent or ionic bonds. Microbeads, substantially all of which have diameters less than 50 microns, can be used to immobilize the active material in the matrix and further improve reactor efficiency. A particularly preferred matrix is made of open cell polyurethane foam, which adsorbs pollutants such as polychlorophenol or o-nitrophenol. The reactors of the present invention allow unidirectional non-laminar flow through the matrix, and promote intimate exposure of liquid reactants to active agents such as microorganisms immobilized in the matrix.

  8. National SCADA Test Bed | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cybersecurity Energy Delivery Systems Cybersecurity National SCADA Test Bed National SCADA Test Bed Created in 2003, the National SCADA Test Bed (NSTB) is a one-of-a-kind...

  9. Experimental and computational investigations of sulfur-resistant bimetallic catalysts for reforming of biomass gasification products

    SciTech Connect (OSTI)

    Rangan, Meghana; Yung, Matthew M.; Medlin, J. William (NREL); (Colorado)

    2011-11-17

    A combination of density functional theory (DFT) calculations and experimental studies of supported catalysts was used to identify H{sub 2}S-resistant biomass gasification product reforming catalysts. DFT calculations were used to search for bimetallic, nickel-based (1 1 1) surfaces with lower sulfur adsorption energies and enhanced ethylene adsorption energies. These metrics were used as predictors for H{sub 2}S resistance and activity toward steam reforming of ethylene, respectively. Relative to Ni, DFT studies found that the Ni/Sn surface alloy exhibited enhanced sulfur resistance and the Ni/Ru system exhibited an improved ethylene binding energy with a small increase in sulfur binding energy. A series of supported bimetallic nickel catalysts was prepared and screened under model ethylene reforming conditions and simulated biomass tar reforming conditions. The observed experimental trends in activity were consistent with theoretical predictions, with observed reforming activities in the order Ni/Ru > Ni > Ni/Sn. Interestingly, Ni/Ru showed a high level of resistance to sulfur poisoning compared with Ni. This sulfur resistance can be partly explained by trends in sulfur versus ethylene binding energy at different types of sites across the bimetallic surface.

  10. STeam Injected Piston Engine Troels Hrding Pedersen Bjrn Kjellstrm

    E-Print Network [OSTI]

    .............................................................19 Reduction of NOx-formation by steam injection

  11. Steam Cracker Furnace Energy Improvements 

    E-Print Network [OSTI]

    Gandler, T.

    2010-01-01

    ? Energy efficiency improvements Overview Baytown Olefins Plant Page 3 Baytown Complex ?One of world?s largest integrated, most technologically advanced petroleum/petrochemical complexes ?~3,400 acres along Houston Ship Channel, ~ 25 mi. east... Furnace tube hydrocarbon + steam 0 0.2 0.4 0.6 0.8 1 1.2 1 2 time C o k e l a y e r Page 8 Steam Cracker Furnace Energy Efficiency ? Overall energy efficiency of furnace depends on ? Run length or % of time furnace is online (more...

  12. Steam Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergyPlan | Department of Energy 1 DOE| Department ofSteam SystemSteam Systems

  13. Energy Savings Through Steam Trap Management 

    E-Print Network [OSTI]

    Gibbs, C.

    2008-01-01

    of continuous monitoring. In addition to energy loss failed open steam traps that go undetected can cause steam system issues. Over pressure on deairator tanks and return lines, electric condensate pump cavitation, and back pressure from undersized vent...

  14. Steam Conservation and Boiler Plant Efficiency Advancements 

    E-Print Network [OSTI]

    Fiorino, D. P.

    2000-01-01

    This paper examines several cost-effective steam conservation and boiler plant efficiency advancements that were implemented during a recently completed central steam boiler plant replacement project at a very large semiconductor manufacturing...

  15. Steam-sieve method and apparatus

    SciTech Connect (OSTI)

    Newby, G. R.

    1984-05-21

    Steam is compressed and heated to make a churn gas that is rife in synthetic fuel, and hydrogen and oxygen are sifted from the churn gas before the steam is recycled.

  16. The Future of Steam: A Preliminary Discussion 

    E-Print Network [OSTI]

    Russell, C.; Harrell, G.; Moore, J.; French, S.

    2001-01-01

    Steam production represents a significant proportion of today's industrial energy demand. But the evolution of process technologies, as well as turbulence in energy markets, suggests that steam's role may be subject to change in the next decade...

  17. "Greening" Industrial Steam Generation via On-demand Steam Systems 

    E-Print Network [OSTI]

    Smith, J. P.

    2010-01-01

    boiler technology currently in service in the U.S., it is critical to raise awareness and examine the role of emerging new technologies to address the energy and environmental challenges inherent with steam generation. In the same way that tank-less...

  18. Optimisation of Fuel Usage and Steam Availability in the Power and Steam

    E-Print Network [OSTI]

    Cambridge, University of

    the medium pressure manifold (nominally operated at 14 bar), through a steam turbine that can be usedOptimisation of Fuel Usage and Steam Availability in the Power and Steam Plant of a Paper Mill KEYWORDS: Model Predictive Control, Improved Efficiency, Optimisation, Power and Steam Supply System

  19. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End User Training Steam End User Training Navigational Tutorial - 1 8/27/2010 Steam End User Training Navigational Tutorial Module Slide 1 ­ Introduction Hello, and welcome to the Steam End User Training. I would like to take a few minutes to show you how to navigate through

  20. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End User Training Steam End User Training Introduction Module - 1 8/27/2010 Steam End User Training Introduction Module Slide 1 - Introduction Title Page Hello, and welcome to the Steam System End User training. In this training, we will investigate how to assess, evaluate

  1. Identifying Steam Opportunity "Impact" Inputs for the Steam System Assessment Tool (SSAT) 

    E-Print Network [OSTI]

    Harrell, G.; Jendrucko, R.; Wright, A.

    2004-01-01

    The U.S. DOE BestPractices Steam "Steam System Assessment Tool" (SSAT) is a powerful tool for quantifying potential steam improvement opportunities in steam systems. However, all assessment tools are only as good as the validity of the modeling...

  2. Apparatus for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01

    An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  3. STEAM-WATER RELATIVE PERMEABILITY A DISSERTATION

    E-Print Network [OSTI]

    Stanford University

    STEAM-WATER RELATIVE PERMEABILITY A DISSERTATION SUBMITTED TO THE DEPARTMENT OF PETROLEUM Laboratory. iv #12;ABSTRACT Steam-water relative permeability curves are required for mathematical models of two-phase geothermal reservoirs. In this study, drainage steam- water relative permeabilities were

  4. Steam System Improvement: A Case Study 

    E-Print Network [OSTI]

    Leigh, N.; Venkatesan, V. V.

    1999-01-01

    usage) where steam generation accounts for 85% of the total energy used. Therefore, optimization of the steam system has the biggest energy saving potential. This paper mill produces 40,000 pounds of steam at 600 psig and distributes it to the paper...

  5. Best Management Practice #8: Steam Boiler Systems

    Broader source: Energy.gov [DOE]

    Boilers and steam generators are commonly used in large heating systems, institutional kitchens, or in facilities where large amounts of process steam are used. This equipment consumes varying amounts of water depending on system size, the amount of steam used, and the amount of condensate returned.

  6. World launch! Hot-Steam Aerostat

    E-Print Network [OSTI]

    Berlin,Technische Universität

    to the first operable balloon ever that became buoyant by means of superheated steam. The performance of Hei-light and flocked insulation material superheated steam could be maintained also close to the envelopeInfo HeiDAS UH World launch! Hot-Steam Aerostat #12;"If you intend to view the land, if you plan

  7. Before the House Oversight and Government Reform Subcommittee...

    Broader source: Energy.gov (indexed) [DOE]

    on Technology, Information Policy, Intergovernmental Relations and Procurement Reform, Committee on Oversight and Government Reform, United States House of Representatives...

  8. Materials Performance in USC Steam

    SciTech Connect (OSTI)

    G. R. Holcomb, P. Wang, P. D. Jablonski, and J. A. Hawk

    2010-05-01

    The proposed steam inlet temperature in the Advanced Ultra Supercritical (A-USC) steam turbine is high enough (760 °C) that traditional turbine casing and valve body materials such as ferritic/martensitic steels will not suffice due to temperature limitations of this class of materials. Cast versions of several traditionally wrought Ni-based superalloys were evaluated for use as casing or valve components for the next generation of industrial steam turbines. The full size castings are substantial: 2-5,000 kg each half and on the order of 100 cm thick. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled to produce equivalent microstructures. A multi-step homogenization heat treatment was developed to better deploy the alloy constituents. The most successful of these cast alloys in terms of creep strength (Haynes 263, Haynes 282, and Nimonic 105) were subsequently evaluated by characterizing their microstructure as well as their steam oxidation resistance (at 760 and 800 °C).

  9. Generating Steam by Waste Incineration 

    E-Print Network [OSTI]

    Williams, D. R.; Darrow, L. A.

    1981-01-01

    Combustible waste is a significant source of steam at the new John Deere Tractor Works assembly plant in Waterloo, Iowa. The incinerators, each rated to consume two tons of solid waste per hour, are expected to provide up to 100 percent of the full...

  10. Bringing electricity reform to the Philippines

    SciTech Connect (OSTI)

    Fe Villamejor-Mendoza, Maria

    2008-12-15

    Electricity reforms will not translate to competition overnight. But reforms are inching their way forward in institutions and stakeholders of the Philippine electricity industry, through regulatory and competition frameworks, processes, and systems promulgated and implemented. (author)

  11. Evaluate reformer performance at a glance

    SciTech Connect (OSTI)

    Nag, A. [Indian Oil Corporation Ltd., Gujarat (India)

    1996-02-01

    Catalytic reforming is becoming increasingly important in replacing octane lost as the removal of lead from worldwide gasoline pools continues. A method has been developed that can quickly evaluate the performance of any catalytic reformer. The catalytic naphtha reforming process primarily involves three well-known reactions. These are aromatization of naphthenes, cyclization of paraffins and hydrocracking of paraffins. Hydrogen is produced in the process of aromatization and dehydrocyclization of paraffins. Reformer performance is normally evaluated with a reformate analysis (PONA) and yield of C{sub 5{sup +}} reformate. This method of quick evaluation of reformer performance is based upon the main assumption that the increase in hydrocarbon moles in the process is equal to the number of C{single_bond}C bond ruptures and one mole of hydrogen is absorbed to saturate the same. This new method calculates aromatization efficiency, paraffin conversion, aromatic selectivity and finally the paraffin, naphthene and aromatic content of C{sub 5{sup +}} reformate.

  12. ALBERTA LAW REFORM INSTITUTE EDMONTON, ALBERTA

    E-Print Network [OSTI]

    MacMillan, Andrew

    ALBERTA LAW REFORM INSTITUTE EDMONTON, ALBERTA CONTRACTS FOR THE SALE AND PURCHASE OF LAND;#12;Table of Contents ALBERTA LAW REFORM INSTITUTE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 CHAPTER 2. COMPARISON OF THE PRESENT AND PREVIOUS LAW OF ALBERTA

  13. Informationsveranstaltung zur Reform des gymnasialen Lehramtes

    E-Print Network [OSTI]

    Informationsveranstaltung zur Reform des gymnasialen Lehramtes W¨urzburg, 3. Mai 2013 ... was lange montags 16-17 Uhr und freitags 10-11 Uhr Euch und allen an der Reform Beteiligten ein herzliches Danke

  14. Hydrogen From MillHydrogen From Mill--Scale Waste Via MetalScale Waste Via Metal--Steam ReformingSteam Reforming INTRODUCTIONINTRODUCTION

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    temperature electrolyzers or photovoltaic devices, these methods are not currently practical due to the higher

  15. Plasmatron Fuel Reformer Development and Internal Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Applications Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications 2004 Diesel Engine Emissions Reduction (DEER) Conference...

  16. PER-Based Reform at a Multicultural

    E-Print Network [OSTI]

    Steinberg, Richard N.

    PER-Based Reform at a Multicultural Institution Some Lessons from Physics Education Research that the most suc- cessful reform strategies require significant interactions among students, and between students and instructor. It is therefore reasonable to wonder about the extent to which PER-based reform

  17. Continuous Bed Ion Exchange Column

    E-Print Network [OSTI]

    Lebendiker, Mario

    UNOTM Q&S Continuous Bed Ion Exchange Column Instruction Manual Catalog Numbers 720-0001, 720 with 5 column volumes of water. Elevated backpressures may occur when wash- ing with deionized water. Do

  18. The Effect Of ZnO Addition On Co/C Catalyst For Vapor And Aqueous Phase Reforming Of Ethanol

    SciTech Connect (OSTI)

    Davidson, Stephen; Sun, Junming; Hong, Yongchun; Karim, Ayman M.; Datye, Abhaya K.; Wang, Yong

    2014-02-05

    The effect of ZnO addition on the oxidation behavior of Co along with catalytic performance in vapor and aqueous phase reforming of ethanol were investigated on Co supported on carbon black (XC-72R). Carbon was selected to minimize the support interactions. Effect of ZnO addition during both vapor and aqueous phase reforming were compared at 250 °C. ZnO addition inhibited the reduction of cobalt oxides by H2 and created surface sites for H2O activation. During vapor phase reforming at 450 °C the redox of cobalt, driven by steam oxidation and H2 reduction, trended to an equilibrium of Co0/Co2+. ZnO showed no significant effect on cobalt oxidation, inferred from the minor changes of C1 product yield. Surface sites created by ZnO addition enhanced water activation and oxidation of surface carbon species, increasing CO2 selectivity. At 250 °C cobalt reduction was minimal, in situ XANES demonstrated that ZnO addition significantly facilitated oxidation of Co0 under vapor phase reforming conditions, demonstrated by lower C1 product yield. Sites introduced by ZnO addition improved the COx selectivity at 250 °C. Both Co/C and Co-ZnO/C rapidly oxidized under aqueous phase reaction conditions at 250 °C, showing negligible activity in aqueous phase reforming. This work suggests that ZnO affects the activation of H2O for Co catalysts in ethanol reforming.

  19. Steam cooling system for a gas turbine

    DOE Patents [OSTI]

    Wilson, Ian David (Mauldin, SC); Barb, Kevin Joseph (Halfmoon, NY); Li, Ming Cheng (Cincinnati, OH); Hyde, Susan Marie (Schenectady, NY); Mashey, Thomas Charles (Coxsackie, NY); Wesorick, Ronald Richard (Albany, NY); Glynn, Christopher Charles (Hamilton, OH); Hemsworth, Martin C. (Cincinnati, OH)

    2002-01-01

    The steam cooling circuit for a gas turbine includes a bore tube assembly supplying steam to circumferentially spaced radial tubes coupled to supply elbows for transitioning the radial steam flow in an axial direction along steam supply tubes adjacent the rim of the rotor. The supply tubes supply steam to circumferentially spaced manifold segments located on the aft side of the 1-2 spacer for supplying steam to the buckets of the first and second stages. Spent return steam from these buckets flows to a plurality of circumferentially spaced return manifold segments disposed on the forward face of the 1-2 spacer. Crossover tubes couple the steam supply from the steam supply manifold segments through the 1-2 spacer to the buckets of the first stage. Crossover tubes through the 1-2 spacer also return steam from the buckets of the second stage to the return manifold segments. Axially extending return tubes convey spent cooling steam from the return manifold segments to radial tubes via return elbows.

  20. SUMMARY PLAN FOR BENCH-SCALE REFORMER AND PRODUCT TESTING TREATABILITY STUDIES USING HANFORD TANK WASTE

    SciTech Connect (OSTI)

    DUNCAN JB

    2010-08-19

    This paper describes the sample selection, sample preparation, environmental, and regulatory considerations for shipment of Hanford radioactive waste samples for treatability studies of the FBSR process at the Savannah River National Laboratory and the Pacific Northwest National Laboratory. The U.S. Department of Energy (DOE) Hanford tank farms contain approximately 57 million gallons of wastes, most of which originated during the reprocessing of spent nuclear fuel to produce plutonium for defense purposes. DOE intends to pre-treat the tank waste to separate the waste into a high level fraction, that will be vitrified and disposed of in a national repository as high-level waste (HLW), and a low-activity waste (LAW) fraction that will be immobilized for on-site disposal at Hanford. The Hanford Waste Treatment and Immobilization Plant (WTP) is the focal point for the treatment of Hanford tank waste. However, the WTP lacks the capacity to process all of the LAW within the regulatory required timeframe. Consequently, a supplemental LAW immobilization process will be required to immobilize the remainder of the LAW. One promising supplemental technology is Fluidized Bed Steam Reforming (FBSR) to produce a sodium-alumino-silicate (NAS) waste form. The NAS waste form is primarily composed of nepheline (NaAlSiO{sub 4}), sodalite (Nas[AlSiO{sub 4}]{sub 6}Cl{sub 2}), and nosean (Na{sub 8}[AlSiO{sub 4}]{sub 6}SO{sub 4}). Semivolatile anions such as pertechnetate (TcO{sub 4}{sup -}) and volatiles such as iodine as iodide (I{sup -}) are expected to be entrapped within the mineral structures, thereby immobilizing them (Janzen 2008). Results from preliminary performance tests using surrogates, suggests that the release of semivolatile radionuclides {sup 99}Tc and volatile {sup 129}I from granular NAS waste form is limited by Nosean solubility. The predicted release of {sup 99}Tc from the NAS waste form at a 100 meters down gradient well from the Integrated Disposal Facility (IDF) was found to be comparable to immobilized low-activity waste glass waste form in the initial supplemental LAW treatment technology risk assessment (Mann 2003). To confirm this hypothesis, DOE is funding a treatability study where three actual Hanford tank waste samples (containing both {sup 99}Tc and {sup 125}I) will be processed in Savannah River National Laboratory's (SRNL) Bench-Scale Reformer (BSR) to form the mineral product, similar to the granular NAS waste form, that will then be subject to a number of waste form qualification tests. In previous tests, SRNL have demonstrated that the BSR product is chemically and physically equivalent to the FBSR product (Janzen 2005). The objective of this paper is to describe the sample selection, sample preparation, and environmental and regulatory considerations for treatability studies of the FBSR process using Hanford tank waste samples at the SNRL. The SNRL will process samples in its BSR. These samples will be decontaminated in the 222-S Laboratory to remove undissolved solids and selected radioisotopes to comply with Department of Transportation (DOT) shipping regulations and to ensure worker safety by limiting radiation exposure to As Low As Reasonably Achievable (ALARA). These decontamination levels will also meet the Nuclear Regulatory Commission's (NRC's) definition of low activity waste (LAW). After the SNRL has processed the tank samples to a granular mineral form, SRNL and Pacific Northwest National Laboratory (PNNL) will conduct waste form testing on both the granular material and monoliths prepared from the granular material. The tests being performed are outlined in Appendix A.

  1. A study of cellulose gasification in a fluidized bed using a high-temperature solar furnace

    SciTech Connect (OSTI)

    Murray, J.P.

    1989-01-01

    A 4.2-meter solar furnace was used to study the gasification of cellulose with steam in a fluidized bed. The heating value of the high-temperature equilibrium products is about twenty percent higher than that of the reactants. The increase represents stored solar energy; and the product, synthesis gas, is valuable as a chemical feedstock or pipeline gas. All experiments were performed at atmospheric pressure. Pure tabular alumina as well as crushed automotive exhaust was used as a bed material. Microcrystalline {alpha}-cellulose, entrained in argon, entered the fluidized bed just above the distributor. Steam heated to the operating temperature in a 10 cm packed bed section below the fluidized bed. In all cases, the process ran with more steam than required to produce an equimolar mixture of carbon monoxide and hydrogen. We used a quartz reactor between 1100 and 1430 K; a steel reactor at 1500 K and an Inconel reactor at 1600 K. Reactor inside diameter, nominally 5 cm, varied slightly; the bed height was adjusted to keep the gas residence time constant. Hydrogen production rate was measured before and after experiments with steam alone, with this amount subtracted. Equilibrium mixtures were not achieved. Catalysts improved hydrogen yields with higher than expected concentrations of carbon monoxide, methane and lighter hydrocarbons such as ethylene and acetylene. Experiments performed without catalyst at 1300 K, achieved a mixture (dry, argon-free) of 46 mole% CO, 30% H{sub 2} 14% CH{sub 4} 5% CO{sub 2} and 5% C{sub 2}H{sub 4}. An equilibrium mixture at this temperature would have contained 39% CO, 30% H{sub 2} 7% CO{sub 2} and no CH{sub 4} or C{sub 2}H{sub 4}. With the catalyst, the CO and CH{sub 4} decreased to 40% and 2% respectively, the H{sub 2} increased to 47%, and CO{sub 2} remained the same. No ethylene was formed. The hydrocarbon-rich mixtures achieved are typical of rapid-pyrolysis processes.

  2. EVALUATION OF A SULFUR OXIDE CHEMICAL HEAT STORAGE PROCESS FOR A STEAM SOLAR ELECTRIC PLANT

    E-Print Network [OSTI]

    Dayan, J.

    2011-01-01

    I Saturated Steam L ___ _ Superheated Steam XBL793-949 Fig.water and generate superheated steam at 144 atmospheres (

  3. Closed loop steam cooled airfoil

    DOE Patents [OSTI]

    Widrig, Scott M.; Rudolph, Ronald J.; Wagner, Gregg P.

    2006-04-18

    An airfoil, a method of manufacturing an airfoil, and a system for cooling an airfoil is provided. The cooling system can be used with an airfoil located in the first stages of a combustion turbine within a combined cycle power generation plant and involves flowing closed loop steam through a pin array set within an airfoil. The airfoil can comprise a cavity having a cooling chamber bounded by an interior wall and an exterior wall so that steam can enter the cavity, pass through the pin array, and then return to the cavity to thereby cool the airfoil. The method of manufacturing an airfoil can include a type of lost wax investment casting process in which a pin array is cast into an airfoil to form a cooling chamber.

  4. Steam Turbine Materials and Corrosion

    SciTech Connect (OSTI)

    Holcomb, G.H.; Hsu, D.H.

    2008-07-01

    Ultra-supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760 °C. In prior years this project examined the steamside oxidation of alloys for use in high- and intermediate-pressure USC turbines. This steamside oxidation research is continuing and progress is presented, with emphasis on chromia evaporation.

  5. Optical steam quality measurement system and method

    DOE Patents [OSTI]

    Davidson, James R.; Partin, Judy K.

    2006-04-25

    An optical measurement system is presented that offers precision on-line monitoring of the quality of steam. Multiple wavelengths of radiant energy are passed through the steam from an emitter to a detector. By comparing the amount of radiant energy absorbed by the flow of steam for each wavelength, a highly accurate measurement of the steam quality can be determined on a continuous basis in real-time. In an embodiment of the present invention, the emitter, comprises three separate radiant energy sources for transmitting specific wavelengths of radiant energy through the steam. In a further embodiment, the wavelengths of radiant energy are combined into a single beam of radiant energy for transmission through the steam using time or wavelength division multiplexing. In yet a further embodiment, the single beam of radiant energy is transmitted using specialized optical elements.

  6. Benchmark the Fuel Cost of Steam Generation - Steam Tip Sheet #15

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO tip sheet on benchmarking the fuel cost of steam provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  7. Steam Technical Brief: How to Calculate the True Cost of Steam

    SciTech Connect (OSTI)

    2010-06-25

    This BestPractice Steam Technical Brief helps you calculate the true cost of steam. Knowing the correct cost is important for many reasons and all of them have to do with improving the company's bottom line.

  8. Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on steam jet ejectors and thermocompressors provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  9. The Steam System Assessment Tool (SSAT): Estimating Steam System Energy, Cost, and Emission Savings 

    E-Print Network [OSTI]

    Wright, A.; Bealing, C.; Eastwood, A.; Tainsh, R.; Hahn, G.; Harrell, G.

    2003-01-01

    The U. S. Department of Energy's (DOE) Industrial Technology Program BestPractices Steam effort is developing a number of software tools to assist industrial energy users to improve the efficiency of their steam system. A major new Best...

  10. Steam Management- The 3M Approach 

    E-Print Network [OSTI]

    Renz, R. L.

    2000-01-01

    by utilizing air vents. ? Steam traps on siphon-drained revolving drying drums frequently operate incorrectly in this application. Automatic differential condensate controllers are being installed on these drums. ? Automatic air vents are also being... and overcooling the drum, which required irJcreased steam for reheat downstream as a consequence. Improved temperature control was added to the cooling portion of the process. ? Flash steam from condensate receivers is reused for low temperature applications...

  11. Cyclohexanone 1 Steam Optimization, Freeport Texas 

    E-Print Network [OSTI]

    Morales, J. R.

    2010-01-01

    Findings in a Mature Manufacturing Process 2010 ACC Energy Efficiency Award Exceptional Merit Cyclohexanone 1 Steam Optimization, Freeport Texas 3 Energy Survey Concept ? 80% of the savings come from 20% of the recommendations: ?What are the critical... Steam Optimization ? The challenge: ? How to optimize steam usage in a mature plant (greater than 25 years) for a commodity product with increased energy costs? ? The answer: ? The activities included a pinch analysis as well as a design...

  12. Loss of feed flow, steam generator tube rupture and steam line break thermohydraulic experiments

    SciTech Connect (OSTI)

    Mendler, O J; Takeuchi, K; Young, M Y

    1986-10-01

    The Westinghouse Model Boiler No. 2 (MB-2) steam generator test model at the Engineering Test Facility in Tampa, Florida, was reinstrumented and modified for performing a series of tests simulating steam generator accident transients. The transients simulated were: loss of feed flow, steam generator tube rupture, and steam line break events. This document presents a description of (1) the model boiler and the associated test facility, (2) the tests performed, and (3) the analyses of the test results.

  13. Steam Technical Brief: Industrial Heat Pumps for Steam and Fuel Savings

    SciTech Connect (OSTI)

    2010-06-25

    The purpose of this Steam Techcial Brief is to introduce heat-pump technology and its applicaiton in industrial processes.

  14. Industrial Heat Pumps for Steam and Fuel Savings: A BestPractices Steam Technical Brief

    SciTech Connect (OSTI)

    Not Available

    2003-06-01

    The purpose of this Steam Techcial Brief is to introduce heat-pump technology and its applicaiton in industrial processes.

  15. Covered Product Category: Commercial Steam Cookers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial steam cookers, which are covered by the ENERGY STAR program.

  16. Minimize Boiler Blowdown - Steam Tip Sheet #9

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on minimizing boiler blowdown provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  17. Achieve Steam System Excellence: Industrial Technologies Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in plant improvement projects. * Steam System Opportunity Assessment for the Pulp and Paper, Chemical Manufacturing, and Petroleum Refining Industries (1) defines the volume and...

  18. Capturing Energy Savings with Steam Traps 

    E-Print Network [OSTI]

    Bockwinkel, R. G.; French, S. A.

    1997-01-01

    , flanges and other connections. The economic loss can be significant. To appre ciate the massive economic impact of wasting steam, let's again look at the very small trap leak on 30 pound pressure typical for many process applications. Chart 1 shows... how much steam will be lost each hour from various size orifices and pressure ranges and the example calcula tions show how much steam is lost per year. Chart 1. Steam Loss Comparison For Various Pressures and Orifice Sizes Drip &Tracer Traps "1...

  19. Pre-In-Plant Training Webinar (Steam)

    Broader source: Energy.gov [DOE]

    This pre-In-Plant training webinar for the Better Plants Program covers how to find energy savings in steam systems.

  20. Apparatus and process for controlling fluidized beds

    DOE Patents [OSTI]

    Rehmat, Amirali G. (Westmont, IL); Patel, Jitendra G. (Bolingbrook, IL)

    1985-10-01

    An apparatus and process for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance.

  1. Plasma-catalyzed fuel reformer

    DOE Patents [OSTI]

    Hartvigsen, Joseph J.; Elangovan, S.; Czernichowski, Piotr; Hollist, Michele

    2013-06-11

    A reformer is disclosed that includes a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto. A first thermally conductive surface surrounds the plasma zone and is configured to transfer heat from an external heat source into the plasma zone. The reformer further includes a reaction zone to chemically transform the ionized reactants into synthesis gas comprising hydrogen and carbon monoxide. A second thermally conductive surface surrounds the reaction zone and is configured to transfer heat from the external heat source into the reaction zone. The first thermally conductive surface and second thermally conductive surface are both directly exposed to the external heat source. A corresponding method and system are also disclosed and claimed herein.

  2. Designing an ultrasupercritical steam turbine

    SciTech Connect (OSTI)

    Klotz, H.; Davis, K.; Pickering, E.

    2009-07-15

    Carbon emissions produced by the combustion of coal may be collected and stored in the future, but a better approach is to reduce the carbon produced through efficient combustion technologies. Increasing the efficiency of new plants using ultrasupercritical (USC) technology will net less carbon released per megawatt-hour using the world's abundant coal reserves while producing electricity at the lowest possible cost. The article shows how increasing the steam turbine operating conditions for a new USC project in the USA and quantify the potential CO{sub 2} reduction this advanced design makes possible. 7 figs., 3 tabs.

  3. Preliminary Results from the Industrial Steam System Market Assessment 

    E-Print Network [OSTI]

    McGrath, G. P.; Wright, A. L.

    2002-01-01

    This paper discusses fuel use and potential energy savings in the steam systems of three steam intensive industries: pulp and paper, chemical manufacturing, and petroleum refining. To determine the energy consumption to generate steam...

  4. Benchmark the Fuel Cost of Steam Generation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Benchmark the Fuel Cost of Steam Generation Benchmark the Fuel Cost of Steam Generation This tip sheet on benchmarking the fuel cost of steam provides how-to advice for improving...

  5. Energy Savings with Computerized Steam Trap Maintenance Program 

    E-Print Network [OSTI]

    Klidzejs, A. M.

    1994-01-01

    This paper describes the efforts made at 3M Company plants to save energy in the steam distribution system by improving the maintenance of steam traps. The results from steam trap surveys for 17 facilities with over 6,400 ...

  6. Effective Steam Trap Selection/Maintenance - Its Payback 

    E-Print Network [OSTI]

    Garcia, E.

    1984-01-01

    In oil refineries and petrochemical plants large number of steam traps are used to discharge condensate from steam mains, tracers and process equipment. Early efforts on steam traps focused almost exclusively on their selection and sizing...

  7. Investigation of Gas Solid Fluidized Bed Dynamics with Non-Spherical Particles

    SciTech Connect (OSTI)

    Choudhuri, Ahsan

    2013-06-30

    One of the largest challenges for 21st century is to fulfill global energy demand while also reducing detrimental impacts of energy generation and use on the environment. Gasification is a promising technology to meet the requirement of reduced emissions without compromising performance. Coal gasification is not an incinerating process; rather than burning coal completely a partial combustion takes place in the presence of steam and limited amounts of oxygen. In this controlled environment, a chemical reaction takes place to produce a mixture of clean synthetic gas. Gas-solid fluidized bed is one such type of gasification technology. During gasification, the mixing behavior of solid (coal) and gas and their flow patterns can be very complicated to understand. Many attempts have taken place in laboratory scale to understand bed hydrodynamics with spherical particles though in actual applications with coal, the particles are non-spherical. This issue drove the documented attempt presented here to investigate fluidized bed behavior using different ranges of non-spherical particles, as well as spherical. For this investigation, various parameters are controlled that included particle size, bed height, bed diameter and particle shape. Particles ranged from 355 µm to 1180 µm, bed diameter varied from 2 cm to 7 cm, two fluidized beds with diameters of 3.4 cm and 12.4 cm, for the spherical and non-spherical shaped particles that were taken into consideration. Pressure drop was measured with increasing superficial gas velocity. The velocity required in order to start to fluidize the particle is called the minimum fluidization velocity, which is one of the most important parameters to design and optimize within a gas-solid fluidized bed. This minimum fluidization velocity was monitored during investigation while observing variables factors and their effect on this velocity. From our investigation, it has been found that minimum fluidization velocity is independent of bed height for both spherical and non-spherical particles. Further, it decrease with decreasing particle size and decreases with decreasing bed diameter. Shadow sizing, a non-intrusive imaging and diagnostic technology, was also used to visualize flow fields inside fluidized beds for both spherical and non- spherical particles and to detect the particle sizes.

  8. PFBC (pressurized fluidized bed combustion) turbocharged boiler design and economic study: Volume 1, Executive summary: Final report

    SciTech Connect (OSTI)

    Not Available

    1987-11-01

    A coal combustion technology that promises to reduce the cost of electrical power is pressurized fluidized bed combustion (PFBC). Since a PFBC boiler is physically smaller than a conventional pulverized coal fired boiler with a flue gas desulfurization system (PC/FGD) and the same power rating shop assembly and modularized shipment to the power plant site can be considered. Modular construction can substantially reduce the overall design/construction time. Emission controls are equivalent to, or better than, conventional PC/FGD units, and the PFBC combustor can tolerate coals with a wider range of characteristics. Two PFBC plants and the reference PC/FGD plant were each to have four nominal 250 MW(e) units to be completed for start-up at one year intervals. To establish a well defined consistent design basis for all units, the turbine-generator and steam cycle of a recently constructed 250 MW(e) unit (designed by Fluor and built under Fluor construction management) was selected and made the common element in both of the PFBC plants and the reference PC/FGD plant. Steam conditions of 2400 psia, 1000/sup 0/F were to be identical for all units as were the steam flows for the design load range of 50% to steam turbine valves-wide-open with inlet steam pressure 5% over design pressure (VWO 5% OP). The study produced three plant designs - a 4-unit turbocharged PFBC using bubbling bed technology, a 4-unit turbocharged PFBC using circulating bed technology, and a 4-unit PC/FGD reference plant using conventional pulverized coal technology coupled with wet limestone scrubber technology. The hot gas clean-up system, operating at these more modest temperatures, is capable of reducing the particulate in the gas to a level which meets EPA/NSPS standards without further cleanup. With this level of cleanup, service conditions for the turbocharger turbine are tolerable in commercially available designs and materials. 48 figs., 14 tabs.

  9. High Efficiency Solar-based Catalytic Structure for CO{sub 2} Reforming

    SciTech Connect (OSTI)

    Menkara, Hisham

    2013-09-30

    Throughout this project, we developed and optimized various photocatalyst structures for CO{sub 2} reforming into hydrocarbon fuels and various commodity chemical products. We also built several closed-loop and continuous fixed-bed photocatalytic reactor system prototypes for a larger-scale demonstration of CO{sub 2} reforming into hydrocarbons, mainly methane and formic acid. The results achieved have indicated that with each type of reactor and structure, high reforming yields can be obtained by refining the structural and operational conditions of the reactor, as well as by using various sacrificial agents (hole scavengers). We have also demonstrated, for the first time, that an aqueous solution containing acid whey (a common bio waste) is a highly effective hole scavenger for a solar-based photocatalytic reactor system and can help reform CO{sub 2} into several products at once. The optimization tasks performed throughout the project have resulted in efficiency increase in our conventional reactors from an initial 0.02% to about 0.25%, which is 10X higher than our original project goal. When acid whey was used as a sacrificial agent, the achieved energy efficiency for formic acid alone was ~0.4%, which is 16X that of our original project goal and higher than anything ever reported for a solar-based photocatalytic reactor. Therefore, by carefully selecting sacrificial agents, it should be possible to reach energy efficiency in the range of the photosynthetic efficiency of typical crop and biofuel plants (1-3%).

  10. Hydrogen from Biomass by Autothermal Reforming

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation by Lanny D. Schmidt at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  11. Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization of Syngas in a Fixed-Bed Reactor

    SciTech Connect (OSTI)

    Siriwardane, Ranjani V.; Cicero, Daniel C. (U.S. Department of Energy, National Energy Technology Laboratory, Morgantown); Stiegel, Gary J.; Gupta, Raghubir P. (U.S. Department of Energy, National Energy Technology Laboratory, Pittsburgh); Turk, Brian S. (Research Triangle Institute)

    2001-11-06

    A fixed-bed regenerable desulfurization sorbent, identified as RVS-land developed by researchers at the U.S. Department of Energy's National Energy Technology Laboratory, was awarded the R&D 100 award in 2000 and is currently offered as a commercial product by Sued-Chemie Inc. An extensive testing program for this sorbent was undertaken which included tests at a wide range of temperatures, pressures and gas compositions both simulated and generated in an actual gasifier for sulfidation and regeneration. This testing has demonstrated that during these desulfurization tests, the RVS-1 sorbent maintained an effluent H2S concentration of <5 ppmv at temperatures from 260 to 600 C (500-1100 F) and pressures of 203-2026 kPa(2 to 20 atm) with a feed containing 1.2 vol% H{sub 2}S. The types of syngas tested ranged from an oxygen-blown Texaco gasifier to biomass-generated syngas. The RVS-1 sorbent has high crush strength and attrition resistance, which, unlike past sorbent formulations, does not decrease with extended testing at actual at operating conditions. The sulfur capacity of the sorbent is roughly 17 to 20 wt.% and also remains constant during extended testing (>25 cycles). In addition to H{sub 2}S, the RVS-1 sorbent has also demonstrated the ability to remove dimethyl sulfide and carbonyl sulfide from syngas. During regeneration, the RVS-1 sorbent has been regenerated with dilute oxygen streams (1 to 7 vol% O{sub 2}) at temperatures as low as 370 C (700 F) and pressures of 304-709 kPa(3 to 7 atm). Although regeneration can be initiated at 370 C (700 F), regeneration temperatures in excess of 538 C (1000 F) were found to be optimal. The presence of steam, carbon dioxide or sulfur dioxide (up to 6 vol%) did not have any visible effect on regeneration or sorbent performance during either sulfidation or regeneration. A number of commercial tests involving RVS-1 have been either conducted or are planned in the near future. The RVS-1 sorbent has been tested by Epyx, Aspen Systems and McDermott Technology (MTI), Inc for desulfurization of syngas produced by reforming of hydrocarbon liquid feedstocks for fuel cell applications. The RVS-1 sorbent was selected by MTI over other candidate sorbents for demonstration testing in their 500-kW ship service fuel cell program. It was also possible to obtain sulfur levels in the ppbv range with the modified RVS-1 sorbent.

  12. Design and Performance Aspects of Steam Generators 

    E-Print Network [OSTI]

    Ganapathy, V.

    1994-01-01

    generators are "standard" or "off-the-shelf items", that there exists a model number for a given steam capacity and one has to live with whatever performance is offered by the boiler vendor. Unfortunately, boiler suppliers also encourage specifying of steam...

  13. Energy Management - Using Steam Pressure Efficiently 

    E-Print Network [OSTI]

    Jiandani, N.

    1983-01-01

    Saturated steam contains heat in two different forms. Sensible heat and latent heat. Due to the nature of this vapor, the relative proportion of latent heat is higher at lower pressures compared to higher pressures. When steam is used for heating...

  14. Welfare reform and liberal governance: disciplining Cambodian-American bodies

    E-Print Network [OSTI]

    Truong, Michael H.

    2007-01-01

    Should Know About Welfare Reform (Series A, No. A- 52).2001). The Impact of Welfare Reform on Asians and PacificPunishment: How Welfare Reform Punishes the Poor. Oakland,

  15. State Finances in India: A Case for Systemic Reform

    E-Print Network [OSTI]

    Singh, Nirvikar

    2006-01-01

    M. Govinda (2000), “Tax Reform in India: Achievements andState Level Fiscal Reforms in India”, paper presented aton Indian Economic Reform, April 19-20. M. Govinda Rao and

  16. Inquiry-Based Learning: An Educational Reform Based

    E-Print Network [OSTI]

    McLoughlin, Padraig

    -Based Learning: An Educational Reform Based Upon Content-Centred Teaching. 1046-Centred Educational Reform 3 III Inquiry-Based Learning Pedagogy is Content 27 #12; ii Abstract Inquiry-Based Learning: An Educational Reform

  17. A second opinion on U.S. health care reform

    E-Print Network [OSTI]

    Chaufan, Claudia MD, PhD

    2010-01-01

    Cost Implications of Health Care Reform. N Engl J Med: p.opinion on U.S. health care reform Posted by PNHP on Friday,Obama argued that a model of reform as that implemented by

  18. Swimming Upstream: The Hard Politics of Health Reform in California

    E-Print Network [OSTI]

    Zelman, Walter

    2009-01-01

    The Hard Politics of Health Reform in California June 2009Report on State Health Access Reform,” Health Affairs, WebPolicy in State Health Reform,” Zelman, W. A. , and Melamed,

  19. Analysis of Senate Bill 92: Health Care Reform

    E-Print Network [OSTI]

    2009-01-01

    CJ. Effects of State Reforms on Health Insurance Coverage ofMorrisey MA. Small Group Reform and Insurance Provision byInterest Groups and Health Reform: Lessons from California.

  20. What is "Comprehensive Immigration Reform"? Taking the Long View

    E-Print Network [OSTI]

    Motomura, Hiroshi

    2010-01-01

    Stumpf. 1. Immigration Reform and Control Act of 1986, Pub.8 U.S.C. ). 35. Immigration Reform and Control Act of 1986,about “comprehensive immigration reform”—in the way the next

  1. Dow Chemical Company: Assessment Leads to Steam System Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a Petrochemical Plant Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a...

  2. Steam System Opportunity Assessment for the Pulp and Paper, Chemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam System Opportunity Assessment for the Pulp and Paper, Chemical Manufacturing, and Petroleum Refining Industries Steam System Opportunity Assessment for the Pulp and Paper,...

  3. Steam System Opportunity Assessment for the Pulp and Paper, Chemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy U.S. Department of Energy Steam System Opportunity Assessment for the Pulp and Paper, Chemical Manufacturing, and Petroleum Refining Industries Steam System Opportunity...

  4. Appendices: Steam System Opportunity Assessment for the Pulp...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy U.S. Department of Energy Steam System Opportunity Assessment for the Pulp and Paper, Chemical Manufacturing, and Petroleum Refining Industries Steam System Opportunity...

  5. Improving Steam System Performance: A Sourcebook for Industry...

    Office of Environmental Management (EM)

    Second Edition (October 2012) More Documents & Publications Flash High-Pressure Condensate to Regenerate Low-Pressure Steam Deaerators in Industrial Steam Systems Insulate...

  6. Insulate Steam Distribution and Condensate Return Lines, Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Insulate Steam Distribution and Condensate Return Lines Uninsulated steam distribution and condensate return lines are a constant source of wasted energy. The table shows typical...

  7. An Object-Oriented Algebraic Steam-Boiler Control Specification

    E-Print Network [OSTI]

    Ã?lveczky, Peter Csaba

    An Object-Oriented Algebraic Steam-Boiler Control Specification computations cannot happen. 1 Introduction The steam-boiler control specification problem has been

  8. Steam Pressure Reduction: Opportunities and Issues; A BestPractices...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    domestic hot water, sterilization autoclaves, and air makeup coils. Oversized boiler plants and steam distribution systems utilizing saturated steam are potential...

  9. Improving Steam System Performance: A Sourcebook for Industry...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improving Steam System Performance: A Sourcebook for Industry, Second Edition Improving Steam System Performance: A Sourcebook for Industry, Second Edition This sourcebook is...

  10. Deaerators in Industrial Steam Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Industrial Steam Systems (January 2012) More Documents & Publications Improving Steam System Performance: A Sourcebook for Industry, Second Edition Consider Installing a...

  11. Industrial Steam System Heat-Transfer Solutions | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrial Steam System Heat-Transfer Solutions Industrial Steam System Heat-Transfer Solutions This brief provides an overview of considerations for selecting the best...

  12. Fluidization quality analyzer for fluidized beds

    DOE Patents [OSTI]

    Daw, C. Stuart (Knoxville, TN); Hawk, James A. (Oak Ridge, TN)

    1995-01-01

    A control loop and fluidization quality analyzer for a fluidized bed utilizes time varying pressure drop measurements. A fast-response pressure transducer measures the overall bed pressure drop, or over some segment of the bed, and the pressure drop signal is processed to produce an output voltage which changes with the degree of fluidization turbulence.

  13. Fluidization quality analyzer for fluidized beds

    DOE Patents [OSTI]

    Daw, C.S.; Hawk, J.A.

    1995-07-25

    A control loop and fluidization quality analyzer for a fluidized bed utilizes time varying pressure drop measurements. A fast-response pressure transducer measures the overall bed pressure drop, or over some segment of the bed, and the pressure drop signal is processed to produce an output voltage which changes with the degree of fluidization turbulence. 9 figs.

  14. Initial Design of a Dual Fluidized Bed Reactor

    E-Print Network [OSTI]

    Yun, Minyoung

    2014-01-01

    fast bed and (b) the bubbling fluidized bed on gas mixingflow regimes. (A) A bubbling fluidized bed, (B) turbulent1.5, 1.6. 1. Bubbling fluidized bed gasifiers (BFB) (Figure

  15. Circumferential cracking of steam generator tubes

    SciTech Connect (OSTI)

    Karwoski, K.J.

    1997-04-01

    On April 28, 1995, the U.S. Nuclear Regulatory Commission (NRC) issued Generic Letter (GL) 95-03, {open_quote}Circumferential Cracking of Steam Generator Tubes.{close_quote} GL 95-03 was issued to obtain information needed to verify licensee compliance with existing regulatory requirements regarding the integrity of steam generator tubes in domestic pressurized-water reactors (PWRs). This report briefly describes the design and function of domestic steam generators and summarizes the staff`s assessment of the responses to GL 95-03. The report concludes with several observations related to steam generator operating experience. This report is intended to be representative of significant operating experience pertaining to circumferential cracking of steam generator tubes from April 1995 through December 1996. Operating experience prior to April 1995 is discussed throughout the report, as necessary, for completeness.

  16. Steam drying of products containing solvent mixtures

    SciTech Connect (OSTI)

    Pothmann, E.; Schluender, E.U. [Univ. Karlsruhe (Germany). Inst. fuer Thermische Verfahrenstechnik

    1995-12-31

    Drying experiments with single, porous spheres wetted with mixtures of 2-propanol and water were performed using superheated steam, air, or steam-air mixtures as drying agent. Both the drying rate and the moisture composition were determined experimentally for different temperatures and compositions of the drying agent and for different initial compositions of the moisture. It is shown that evaporation of 2-propanol is enhanced by using superheated steam as drying agent instead of air due to steam condensing on the sample. While the overall drying rate increases with rising steam temperature, the evaporation rate of 2-propanol is hardly affected. When drying samples containing mixtures of 2-propanol and water, internal boiling can occur depending on the vapor-liquid equilibrium. Vapor generated inside the sample may cause mechanical dewatering of the sample which greatly increases the drying rate.

  17. Bed BugsBed Bugs Bed bugs are small, wingless insects that

    E-Print Network [OSTI]

    Ishida, Yuko

    insecticide treatments. If you are a renter, contact your landlord or property owner to help manage't control bed bugs. Remove or heat-treat infested materials, and seal hiding spots to prevent future infestations. Inspect after treatments to be sure bugs are gone. May 2015 Minimize the use of pesticides

  18. Making Sense of Reform in Mathematics Education : : The Impact on Practice by Interactions Between Teachers' Beliefs, Reform Policy and Collaboration

    E-Print Network [OSTI]

    Javier, Laura R.

    2014-01-01

    L. , & Cohen, D. K. (1996). Reform by the book: What is: Orlearning and instructional reform? Educational Researcher,school mathematics: The anti-reform of 1997-99. Phi Delta

  19. The Definitive Reform. How the 1996 Electoral Reform Triggered the Demise of the PRI's Dominant-Party Regime

    E-Print Network [OSTI]

    Garrido de Sierra, Sebastián

    2014-01-01

    the PRI Approve the Reform? . . . . . . . . . . . . . . .vi 4 How the 1996 Reform Triggered the End of the PRI’seffect of the 1996 electoral reform on the PRI’s unity . The

  20. Method and apparatus for a combination moving bed thermal treatment reactor and moving bed filter

    DOE Patents [OSTI]

    Badger, Phillip C.; Dunn, Jr., Kenneth J.

    2015-09-01

    A moving bed gasification/thermal treatment reactor includes a geometry in which moving bed reactor particles serve as both a moving bed filter and a heat carrier to provide thermal energy for thermal treatment reactions, such that the moving bed filter and the heat carrier are one and the same to remove solid particulates or droplets generated by thermal treatment processes or injected into the moving bed filter from other sources.

  1. Diesel Reformers for On-board Hydrogen Applications | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reformers for On-board Hydrogen Applications Diesel Reformers for On-board Hydrogen Applications 2003 DEER Conference Presentation: Hydrogen Source 2003deermauss.pdf More...

  2. Agenda for the Derived Liquids to Hydrogen Distributed Reforming...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reforming Targets Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Kick-Off Meeting Proceedings Hilton Garden Inn-BWI,Baltimore, MD October 24, 2006...

  3. Hydrogen generation from plasmatron reformers and use for diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    generation from plasmatron reformers and use for diesel exhaust aftertreatment Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment 2003 DEER...

  4. Secretary Moniz to Present Project Management Reforms to the...

    Office of Environmental Management (EM)

    Moniz to Present Project Management Reforms to the National Academy of Public Administration Secretary Moniz to Present Project Management Reforms to the National Academy of Public...

  5. Improved System Performance and Reduced Cost of a Fuel Reformer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduced Cost of a Fuel Reformer, LNT, and SCR Aftertreatment System Meeting Emissions Useful Life Requirement Improved System Performance and Reduced Cost of a Fuel Reformer, LNT,...

  6. Fuel Reformer, LNT and SCR Aftertreatment System Meeting Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reformer, LNT and SCR Aftertreatment System Meeting Emissions Useful Life Requirements Fuel Reformer, LNT and SCR Aftertreatment System Meeting Emissions Useful Life Requirements...

  7. Secretary Moniz's Remarks on Project Management Reform at the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Project Management Reform at the National Academy of Public Administration -- As Delivered Secretary Moniz's Remarks on Project Management Reform at the National Academy of Public...

  8. Design, Modeling, and Validation of a Flame Reformer for LNT...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration...

  9. Before the House Oversight and Government Reform Subcommittee...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oversight and Government Reform Subcommittee on Government Management, Organization, and Procurement Before the House Oversight and Government Reform Subcommittee on Government...

  10. Regulatory and Financial Reform of Federal Research Policy: Recommenda...

    Energy Savers [EERE]

    Regulatory and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities Regulatory and Financial Reform of Federal Research...

  11. STEM education reform A public research university imperative!

    E-Print Network [OSTI]

    Sin, Peter

    STEM education reform A public research university imperative! University of Florida A significant education reform initiative for introductory courses. Will these -- and a growing number of other national

  12. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Targets (Presentation) Bio-Derived Liquids to Hydrogen Distributed Reforming Targets (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming...

  13. Heat Transfer Limitations in Hydrogen Production Via Steam Reformation: The Effect of Reactor Geometry

    E-Print Network [OSTI]

    Vernon, David R.; Davieau, David D.; Dudgeon, Bryce A.; Erickson, Paul A.

    2006-01-01

    Process for Fuel Cell Applications, Ph.D. Dissertation,An Investigation for Fuel Cell Vehicle Applications, Ph.D.

  14. Ceramic microreactors for on-site hydrogen production from high temperature steam reforming of propane{

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    of propane{ Christian, Michael Mitchell and Paul J. A. Kenis* Received 31st May 2006, Accepted 10th August of propane into hydrogen at temperatures between 800 and 1000 uC. We characterized these microreactors. Kinetic analysis using a power law model showed reaction orders of 0.50 and 20.23 with respect to propane

  15. Supported Single Pt1/Au1 Atoms for Methanol Steam Reforming Xiang-Kui Gu,,

    E-Print Network [OSTI]

    Li, Weixue

    Laboratory of Catalysis, Dalian Institute of Chemical Physics, Dalian National Laboratory for Clean Energy, Chinese Academic of Sciences, Dalian 116023, China § Department of of Physics, Arizona State University

  16. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels Research atDepartmentAuditsDepartmentj.BETO

  17. Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICE INDUSTRIALU.S. Department of(Presentation) | Department of Energy

  18. Desulfurization of lignite using steam and air 

    E-Print Network [OSTI]

    Carter, Glenn Allen

    1982-01-01

    in a setting that would be similar to a full scale plan+. Results from +he batch sys+ m were excellent, with as much as 98. 6% of the sulfur removed at 1089 K. The product recovery was abou+ 68%; the remainder of the coal had been gasified... OF CONTENTS PAGE INTRODUCTION LITERATURE REVIEW Sulfur Removal Using a Fixed Bed Reactor Sulfur Removal Using a Batch Fluidized Bed Reactor . . 9 Continuous Fluidized Bed Reactor Systems for Desulfurization of Coal Clean Coke Process IGT Process...

  19. Enabling Informed Adaptation of Reformed Instructional Materials

    E-Print Network [OSTI]

    Elby, Andy

    Enabling Informed Adaptation of Reformed Instructional Materials Rachel E. Scherr and Andrew Elby 20742 USA Abstract. Instructors inevitably need to adapt even the best reform materials to suit instructors, and video clips of students working on the materials. Our materials thus facilitate their own

  20. Olefins from High Yield Autothermal Reforming Process

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2012-03-06

    The autothermal reforming method employs an improved dehydrogenation process for olefin production, utilizing platinum based dehydrogenation catalysts in the presence of oxygen. The autothermal process requires no external energy input following ignition and produces high conversions and yields from the gaseous hydrocarbon feeds. Autothermal reforming is an effective solution that meets the high demands of the chemical market industry by producing high yields...

  1. In Njeri Wamukonya, ed., Electricity Reform

    E-Print Network [OSTI]

    Delaware, University of

    electricity consumption in industrial countries has caused major air pollution problems. In fact, power plantsIn Njeri Wamukonya, ed., Electricity Reform: Social and Environmental Challenges Roskilde, Denmark: UNEP-RISÃ? Centre. Rethinking reform in the electricity sector: Power liberalisation or energy

  2. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    applications including coal gasification, fer- tilizers fromin hydro-gasification reactions, such as coal and biomass,

  3. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    combustion of petroleum-based fuels in conventional engines can cause serious environmental pollution

  4. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    During this first quarter, a lab-scale water-cooled pulse combustor was designed, fabricated, and integrated with old pilot-scale PAFBC test systems. Characterization tests on this pulse combustor firing different kinds of fuel -- natural gas, pulverized coal and fine coal -- were conducted (without fluidized bed operation) for the purpose of finalizing PAFBC full-scale design. Steady-state tests were performed. Heat transfer performance and combustion efficiency of a coal-fired pulse combustor were evaluated.

  5. "Reform" or "Opening"? Reform of China's State-Owned Enterprises and WTO Accession - The Dilemma of Applying GATT to Marketing Economies

    E-Print Network [OSTI]

    Blumental, David

    1998-01-01

    China's Assurances on Reform Please U.S. , AsIAN WALL ST.REFORM" OR "OPENING"?REFORM OF CHINA'S STATE-OWNED ENTERPRISES AND WTO

  6. Customizing pays off in steam generators

    SciTech Connect (OSTI)

    Ganapathy, V. (ABCO Industries, Inc., Abilene, TX (United States))

    1995-01-01

    Packaged steam generators are the workhorses of chemical process plants, power plants and cogeneration systems. They are available as oil- or gas-fired models, and are used to generate either high-pressure superheated steam (400 to 1,200 psig, at 500 to 900 F) or saturated steam at low pressures (100 to 300 psig). In today's emission- and efficiency- conscious environment, steam generators have to be custom designed. Gone are the days when a boiler supplier--or for that matter an end user--could look up a model number from a list of standard sizes and select one for a particular need. Thus, before selecting a system, it is desirable to know the features of oil- and gas-fired steam generators, and the important variables that influence their selection, design and performance. It is imperative that all of these data are supplied to the boiler supplier so that the engineers may come up with the right design. Some of the parameters which are discussed in this paper are: duty, steam temperature, steam purity, emissions, and furnace design. Superheaters, economizers, and overall performance are also discussed.

  7. Rivesville multicell fluidized bed boiler

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    One objective of the experimental MFB at Rivesville, WV, was the evaluation of alternate feed systems for injecting coal and limestone into a fluidized bed. A continuous, uniform feed flow to the fluid bed is essential in order to maintain stable operations. The feed system originally installed on the MFB was a gravity feed system with an air assist to help overcome the back pressure created by the fluid bed. The system contained belt, vibrating, and rotary feeders which have been proven adequate in other material handling applications. This system, while usable, had several operational and feeding problems during the MFB testing. A major portion of these problems occurred because the coal and limestone feed control points - a belt feeder and rotary feeder, respectively - were pressurized in the air assist system. These control points were not designed for pressurized service. An alternate feed system which could accept feed from the two control points, split the feed into six equal parts and eliminate the problems of the pressurized system was sought. An alternate feed system designed and built by the Fuller Company was installed and tested at the Rivesville facility. Fuller feed systems were installed on the north and south side of C cell at the Rivesville facility. The systems were designed to handle 10,000 lb/hr of coal and limestone apiece. The systems were installed in late 1979 and evaluated from December 1979 to December 1980. During this time period, nearly 1000 h of operating time was accumulated on each system.

  8. Light-gas effect on steam condensation

    SciTech Connect (OSTI)

    Anderson, M.H.; Corradini, M.L. [Univ. of Wisconsin, Madison, WI (United States); Herranz, L.E. [Centro de Investigcaiones Energeticas Medioambientales y Tecnologicas, Madrid (Spain)

    1997-12-01

    In a postulated reactor accident, the loss of coolant results in a release of high-temperature steam into the containment. Under these circumstances steam condensation onto containment walls provides an effective mechanism of energy removal. However, the presence of noncondensable gas is known to degrade the heat transfer. It has also been found that the introduction of a light noncondensable gas has little effect until sufficient quantities are present to disrupt the buoyancy forces. Our investigation shows the dramatic effect of high concentrations of light gas decreasing steam condensation rates under anticipated accident conditions for AP600, with helium as the simulant for hydrogen.

  9. Energy Conservation Through Effective Steam Trapping 

    E-Print Network [OSTI]

    Diamante, L.; Nagengast, C.

    1979-01-01

    the bottom edge and out, the bucket becomes bouyant, floats up, closes the valve and the flow stops. The slight static pressure the water around the bucket exerts on the steam inside will begin to drive it out through the small hole in the top we spoke... at which condensate is forming, thus steam will eventually flow into the trap. Steam unlike condensate, or air in a relative sense, is highly compressible and will undergo a substantial volume change in expanding from the inlet to outlet pressure...

  10. Electrical Cost Reduction Via Steam Turbine Cogeneration 

    E-Print Network [OSTI]

    Ewing, T. S.; Di Tullio, L. B.

    1991-01-01

    REDUCTION VIA STEAM TURBINE COGENERATION LYNN B. DI TULLIO, P.E. Project Engineer Ewing Power Systems, Inc. South Deerfield, Mass. ABSTRACT Steam turbine cogeneration is a well established technology which is widely used in industry. However... reducing valves with turbine generator sets in applications with flows as low as 4000 pounds of steam per hour. These systems produce electricity for $0.01 to $.02 per kWh (based on current costs of gas and oil); system cost is between $200 and $800 per...

  11. Internal combustion engine injection superheated steam

    SciTech Connect (OSTI)

    Mahoney, F.G.

    1991-01-22

    This patent describes a method for introducing water vapor to the combustion chambers of an internal combustion engine. It comprises: introducing a metered amount of liquid water into a heat exchanger; contacting the heat exchanger directly with hot exhaust gases emanating from the exhaust manifold; maintaining the water in the heat exchanger for a period sufficient to vaporize the water into steam and superheat same; reducing pressure and increasing temperature to create superheated steam; introducing the superheated steam into the air supply proximate to the air induction system, upstream of any carburetion, of the internal combustion engine.

  12. The Enbridge "Steam Saver" Program: Steam Boiler Plant Efficiency-Update to Year End 2005 

    E-Print Network [OSTI]

    Griffin, B.; Johnson, D.

    2006-01-01

    ” PROGRAM STEAM BOILER PLANT EFFICIENCY-UPDATE TO YEAR END, 2005 March 1, 2006 Bob Griffin, P.Eng., Energy Solutions Manager, Enbridge Gas Distribution Inc., Toronto, Ontario Daniel Johnson, B.A.Sc., Industrial Energy Engineer, Enbridge Gas Distribution... of Enbridge’s “Steam Saver” program first introduced in 1997. The goal of this program is to reduce fuel consumption in industrial steam plants and distribution systems. We have now completed 92 detailed boiler plant performance tests and audits...

  13. Reservoir performance characterized in mature steam pattern

    SciTech Connect (OSTI)

    Miller, D.D.; McPherson, J.G.; Covington, T.E.

    1989-04-01

    A detailed reservoir description provided new insight in an investigation of a ten-year-old steam flood. Mobil Oil Corporation conducted this study of the Pleistocene upper Tulare sands in South Belridge field, located in the San Joaquin basin, Kern County, California. The study area is on the gently dipping (6/degrees/) southwestern flank of the South Belridge anticline. Wireline logs from 19 wells in a 10-ac (660 ft x 660 ft) pattern were correlated in detail. Seven post-steam conventional cores (1523 ft) aided (1) the evaluation of vertical and lateral steam-sweep efficiency, (2) evaluation of reservoir and fluid changes due to steam, (3) influence of lithofacies in reservoir quality, and (4) provided insight to the three-dimensional reservoir flow-unit geometries.

  14. Optimized Control Of Steam Heating Coils 

    E-Print Network [OSTI]

    Ali, Mir Muddassir

    2012-02-14

    Steam has been widely used as the source of heating in commercial buildings and industries throughout the twentieth century. Even though contemporary designers have moved to hot water as the primary choice for heating, a large number of facilities...

  15. Steam turbine upgrading: low-hanging fruit

    SciTech Connect (OSTI)

    Peltier, R.

    2006-04-15

    The thermodynamic performance of the steam turbine, more than any other plant component, determines overall plant efficiency. Upgrading steam path components and using computerized design tools and manufacturing techniques to minimise internal leaks are two ways to give tired steam turbines a new lease on life. The article presents three case studies that illustrate how to do that. These are at Unit 1 of Dairyland's J.P. Madgett Station in Alma, WI, a coal-fired subcritical steam plant; the four units at AmerenUE's 600 MW coal-fired Labadie plant west of St. Louis; and Unit 3 of KeyPlan Corp's Northport Power Station on Long Island. 8 figs.

  16. Consider Steam Turbine Drives for Rotating Equipment

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on steam turbine drives for rotating equipment provides how-to advice for improving the system using low-cost, proven practices and technologies.

  17. Compressor & Steam Turbine Efficiency Improvements & Revamping Opportunities 

    E-Print Network [OSTI]

    Hata, S.; Horiba, J.; Sicker, M.

    2011-01-01

    in which they operate. This energy growth requires high efficiency improvements for machine design and operation to minimize life cycle cost. This paper will focus on the mechanical drive steam turbines which power the main process equipment in the heart...

  18. Optimizing Steam & Condensate System: A Case Study 

    E-Print Network [OSTI]

    Venkatesan, V. V.; Norris, C.

    2011-01-01

    Optimization of Steam & Condensate systems in any process plant results in substantial reduction of purchased energy cost. During periods of natural gas price hikes, this would benefit the plant in controlling their fuel budget significantly...

  19. Solar steam generation by heat localization

    E-Print Network [OSTI]

    Ghasemi, Hadi

    Currently, steam generation using solar energy is based on heating bulk liquid to high temperatures. This approach requires either costly high optical concentrations leading to heat loss by the hot bulk liquid and heated ...

  20. Extraction Steam Controls at EPLA-W 

    E-Print Network [OSTI]

    Brinker, J. L.

    2004-01-01

    ExxonMobil's Baton Rouge site encompasses a world-scale refinery, chemical plant and third party power station. Historically, inflexible and unreliable control systems on two high-pressure, extracting/condensing steam turbines prevented the site...

  1. Steam System Optimization : A Case Study 

    E-Print Network [OSTI]

    Iordanova, N.; Venkatesan, V. V.; Calogero, M.

    2002-01-01

    The steam system optimization (generation, distribution, use and condensate return) offers a large opportunity for action to comply with the new levels of energy efficiency standards. Superior design and improved maintenance practices are the two...

  2. Apparatus and methods of reheating gas turbine cooling steam and high pressure steam turbine exhaust in a combined cycle power generating system

    DOE Patents [OSTI]

    Tomlinson, Leroy Omar (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01

    In a combined cycle system having a multi-pressure heat recovery steam generator, a gas turbine and steam turbine, steam for cooling gas turbine components is supplied from the intermediate pressure section of the heat recovery steam generator supplemented by a portion of the steam exhausting from the HP section of the steam turbine, steam from the gas turbine cooling cycle and the exhaust from the HP section of the steam turbine are combined for flow through a reheat section of the HRSG. The reheated steam is supplied to the IP section inlet of the steam turbine. Thus, where gas turbine cooling steam temperature is lower than optimum, a net improvement in performance is achieved by flowing the cooling steam exhausting from the gas turbine and the exhaust steam from the high pressure section of the steam turbine in series through the reheater of the HRSG for applying steam at optimum temperature to the IP section of the steam turbine.

  3. Optimization of Steam Network in Tehran Oil Refinery 

    E-Print Network [OSTI]

    Khodaie, H.; Nasr, M. R. J.

    2008-01-01

    involved super heater, preheater, water drum, economizer and radiant chamber. In this case study boilers do not have any economizer so no heat exchanger between the incoming boilers feed water and the hot flue gases before they are vented to atmosphere... boiler feed water treatment, steam boilers, steam turbines, steam distribution, steam users and producer. row water needs to be treated before it can be used for steam generation it need to be first filtered to remove suspend solids then need...

  4. September 25, 2013 AFSCME Continues to Object to Pension Reform;

    E-Print Network [OSTI]

    Leistikow, Bruce N.

    September 25, 2013 AFSCME Continues to Object to Pension Reform; UC Implements Latest Bargaining working conditions and reasonable pension reform. However, AFSCME has rejected UC's proposals. From the start, AFSCME leadership has objected to UC's responsible pension reform -- the kind of reform that

  5. Control system for fluid heated steam generator

    DOE Patents [OSTI]

    Boland, J.F.; Koenig, J.F.

    1984-05-29

    A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

  6. Oxidation of advanced steam turbine alloys

    SciTech Connect (OSTI)

    Holcomb, G.R.; Covino, B.S., Jr.; Bullard, S.J.; Ziomek-Moroz, M.

    2006-03-01

    Advanced or ultra supercritical (USC) steam power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760°C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections.

  7. Control system for fluid heated steam generator

    DOE Patents [OSTI]

    Boland, James F. (Bonneville County, ID); Koenig, John F. (Idaho Falls, ID)

    1985-01-01

    A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

  8. Internal reforming fuel cell assembly with simplified fuel feed

    DOE Patents [OSTI]

    Farooque, Mohammad (Huntington, CT); Novacco, Lawrence J. (Brookfield, CT); Allen, Jeffrey P. (Naugatuck, CT)

    2001-01-01

    A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

  9. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Design and Engineering of most components in the Pulsed Atmospheric Fluidized Bed System was completed prior to September 1992. The components remaining to be designed at that time were: Aerovalves for the Pulse Combustor; Gas and coal injectors for the Pulse Combustor; Lines for PC tailpipes; Air plenum and inlet silencer; Refractory lined hot gas duct connecting outlet hot cyclone to boiler; Structure and platforms, and ladders around PAFBC vessel access and major equipment. Design work is currently in progress on all of the above components. Items 1, 2, 3 and 4 are 50% completed, and items 5 6 are 75% complete.

  10. Battery using a metal particle bed electrode

    DOE Patents [OSTI]

    Evans, James V. (Piedmont, CA); Savaskan, Gultekin (Albany, CA)

    1991-01-01

    A zinc-air battery in a case including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit.

  11. Battery using a metal particle bed electrode

    DOE Patents [OSTI]

    Evans, J.V.; Savaskan, G.

    1991-04-09

    A zinc-air battery in a case is described including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit. 7 figures.

  12. Gas distributor for fluidized bed coal gasifier

    DOE Patents [OSTI]

    Worley, Arthur C. (Mt. Tabor, NJ); Zboray, James A. (Irvine, CA)

    1980-01-01

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  13. Nicholas Barr: USS reform directions Ver. 2 1 26 March 2015 What reform directions for USS?1

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Nicholas Barr: USS reform directions Ver. 2 1 26 March 2015 What reform directions for USS?1 Nicholas Barr2 Summary This note discusses reform of USS as simply as possible (see glossary at end why and how a wider view of de-risking is both feasible and desirable. Some of the reforms of USS

  14. A new bed elevation dataset for Greenland

    E-Print Network [OSTI]

    2013-01-01

    S. : A new ice thick- ness and bed data set for theto measure ice thick- ness in areas of warm and fractured

  15. Combined fluidized bed retort and combustor

    DOE Patents [OSTI]

    Shang, Jer-Yu (Fairfax, VA); Notestein, John E. (Morgantown, WV); Mei, Joseph S. (Morgantown, WV); Zeng, Li-Wen (Morgantown, WV)

    1984-01-01

    The present invention is directed to a combined fluidized bed retorting and combustion system particularly useful for extracting energy values from oil shale. The oil-shale retort and combustor are disposed side-by-side and in registry with one another through passageways in a partition therebetween. The passageways in the partition are submerged below the top of the respective fluid beds to preclude admixing or the product gases from the two chambers. The solid oil shale or bed material is transported through the chambers by inclining or slanting the fluidizing medium distributor so that the solid bed material, when fluidized, moves in the direction of the downward slope of the distributor.

  16. Packed fluidized bed blanket for fusion reactor

    DOE Patents [OSTI]

    Chi, John W. H. (Mt. Lebanon, PA)

    1984-01-01

    A packed fluidized bed blanket for a fusion reactor providing for efficient radiation absorption for energy recovery, efficient neutron absorption for nuclear transformations, ease of blanket removal, processing and replacement, and on-line fueling/refueling. The blanket of the reactor contains a bed of stationary particles during reactor operation, cooled by a radial flow of coolant. During fueling/refueling, an axial flow is introduced into the bed in stages at various axial locations to fluidize the bed. When desired, the fluidization flow can be used to remove particles from the blanket.

  17. Device for cooling and humidifying reformate

    DOE Patents [OSTI]

    Zhao, Jian Lian (Belmont, MA); Northrop, William F. (Ann Arbor, MI)

    2008-04-08

    Devices for cooling and humidifying a reformate stream from a reforming reactor as well as related methods, modules and systems includes a heat exchanger and a sprayer. The heat exchanger has an inlet, an outlet, and a conduit between the inlet and the outlet. The heat exchanger is adapted to allow a flow of a first fluid (e.g. water) inside the conduit and to establish a heat exchange relationship between the first fluid and a second fluid (e.g. reformate from a reforming reactor) flowing outside the conduit. The sprayer is coupled to the outlet of the heat exchanger for spraying the first fluid exiting the heat exchanger into the second fluid.

  18. Bank Regulation and Mortgage Market Reform

    E-Print Network [OSTI]

    Jaffee, Dwight M.

    2011-01-01

    July 2008. U.S. Treasury/HUD (2011), “Reforming America’sthe recent U.S. Treasury/HUD (2011) White Paper. The Whitepresented in the Treasury/HUD (2011) White paper. I then

  19. Electricity reform abroad and US investment

    SciTech Connect (OSTI)

    1997-10-01

    This report reviews and analyzes the recent electricity reforms in Argentina, Australia, and the United Kingdom (UK) to illustrate how different models of privatization and reform have worked in practice. This report also analyzes the motivations of the U.S. companies who have invested in the electricity industries in these countries, which have become the largest targets of U.S. foreign investment in electricity. Two calculations of foreign investment are used. One is the foreign direct investment series produced by the U.S. Department of Commerce. The other is based on transactions in electric utilities of the three countries. The electricity reform and privatization experiences reviewed may offer some insight as to how the U.S. electricity industry might develop as a result of recent domestic reform efforts and deregulation at the state and national levels. 126 refs., 23 figs., 27 tabs.

  20. Copyright Law Reform: Some Achievable Goals 

    E-Print Network [OSTI]

    MacQueen, Hector L

    2007-01-01

    Copyright law reform in the European Union. The chapter discusses possible actions in light of new and amended EU Directives and whether these balances rights' holders and users' interests....

  1. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    , SSAT, and the 3E-Plus Insulation Tool. The Steam Generation Efficiency module focuses on boiler efficiency. In this section the definition of boiler efficiency will be discussed and the various avenues of boiler losses will be explored. Resource Utilization Effectiveness will discuss fuel selection, steam

  2. Boiler Efficiency vs. Steam Quality- The Challenge of Creating Quality Steam Using Existing Boiler Efficiencies 

    E-Print Network [OSTI]

    Hahn, G.

    1998-01-01

    A boiler works under pressure and it is not possible to see what is happening inside of it. The terms "wet steam" and "carry over" are every day idioms in the steam industry, yet very few people have ever seen these phenomena and the actual water...

  3. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    steam systems - Measure boiler efficiency - Estimate the magnitude of specific boiler losses - Identify and prioritize areas of boiler efficiency improvement - Recognize the impacts of fuel selection Measurements] Boiler o Flue gas temperature o Flue gas oxygen content o Boiler fuel flow o Boiler steam

  4. Precious Corals in Hawaii: Discovery of a New Bed and Revised Management Measures for Existing Beds

    E-Print Network [OSTI]

    Precious Corals in Hawaii: Discovery of a New Bed and Revised Management Measures for Existing Beds Introduction and History of Hawaii's Precious Coral Fishery Precious corals, Corallium spp., wereTheodore Chamberlain,oftheUniversityofHawaii, discovered a small bed of Corallium Richard W. Grigg (rgrigg@soest.hawaii

  5. The Ambiguous Transition: Building State Capacity and Expanding Popular Participation in Venezuela's Agrarian Reform

    E-Print Network [OSTI]

    Page, Tiffany Linton

    2011-01-01

    the Democracy? Crisis and Reform in Venezuela. ” Journal ofLaura. 1997. Agrarian Reform and Class Consciousness inCristóbal. 1978. “Agrarian Reform and the Class Struggle in

  6. The politics of criminal law reform : a comparative analysis of lower court decision-making

    E-Print Network [OSTI]

    Tiede, Lydia Brashear

    2008-01-01

    the Goals of Sentencing Reform. Washington, DC: USSC.1991. “The Sentencing Reform Act of 1984: A Bold Approach to2008. “The Constitutional Reform Act 2005. ” Available at

  7. What Charter Reform Commissions Can Teach Us About a Proposed Constitutional Convention in California

    E-Print Network [OSTI]

    Sonenshein, Raphael

    2010-01-01

    eds. 1995. Constitutional Reform in California. Berkeley:The Reemergence of Municipal Reform. New York: Academy ofin the Los Angeles Charter Reform of 1996-1999. ” In David

  8. Excellence through General Education: The Status of General Education Reform in Chinese Universities

    E-Print Network [OSTI]

    Liao, Xuehong

    2012-01-01

    of General Education Reform in Two Chinese Universities”.of general education reform. Change, 29(4), 18- AssociationGlobalization and educational reforms in Anglo-American

  9. The Political Economy of India’s Fiscal Federal System and its Reform

    E-Print Network [OSTI]

    Rao, M. Govinda; Singh, Nirvikar

    2006-01-01

    Political Economy and Issues for Reform, eds. , SatuIncentives, and Economic Reforms in India, New Delhi: Sageon Indian Economic Reform, June. Musgrave, Richard A. (

  10. The Resurgence of Land Reform Policy and Agrarian Movements in Indonesia

    E-Print Network [OSTI]

    Rachman, Noer Fauzi

    2011-01-01

    2006. Tafsir(an) Land Reform dalam Alur Sejarah Indonesia:Bibingka Strategy in Land Reform Implementation: Autonomous2006a. “Redistributive Land Reform in ‘Public (Forest) Land?

  11. You Must Learn! Hip-Hop Steps Into the Educational Reform Discourse

    E-Print Network [OSTI]

    Allahjah, Yusuf

    2012-01-01

    in School: Afrocentric reform, urban youth & the promise of2005). Standards-Based Reform and Low Performing Schools: AIn F. Hess, Urban School Reform: Lessons From San Diego,

  12. School Reform for Students of Color and English Learners: Leaving Pedagogy Behind

    E-Print Network [OSTI]

    Trujillo, Tina

    2011-01-01

    School Reform for Students of Color and English Learners:non-profit school reform organizations, universities, for-non- profit school reform organizations have proliferated in

  13. The Politics of Revenue-Raising Tax Reform in Latin America

    E-Print Network [OSTI]

    Fairfield, Tasha

    2010-01-01

    George, ed. 1998. “Fiscal Reforms in Low-Income Countries:Markets, and Structural Reform in Latin America. Miami:Imperatives and Tax Reform: Lessons from Postcommunist

  14. Is California Different? State-Specific Risk Adjustment Needs under Health Reform

    E-Print Network [OSTI]

    Fulton, Brent D.; Dow, William H.

    2011-01-01

    Adjustment Needs under Health Reform Brent D. Fulton andinsurance market under reform is the use of risk adjustmentplans. Keywords: health care reform, The Affordable Health

  15. Mayors, Markets and Municipal Reform: The Politics of Water Delivery in Mexico

    E-Print Network [OSTI]

    Herrera, Veronica Maria Sol

    2011-01-01

    Economy of Water Pricing Reforms. Washington, DC: WorldEconomy of Policy Reform. Washington, DC: Institute for2001. “Constructing Reform Coalitions: The Politics of

  16. Reform or Radicalism: Left Social Movements from the Battle of Seattle to Occupy Wall Street

    E-Print Network [OSTI]

    Rowe, James K; Carroll, Myles

    2014-01-01

    abstract antipathy towards ‘tepid reform’ and ‘unrealisticReform or Radicalism: Left Social Movements from the Battledynamism between radical and reform wings drove gains. This

  17. Prospects for Comprehensive Immigration Reform in 2012-2013: Accounting for Trends in Immigration Public Opinion

    E-Print Network [OSTI]

    Abrejano, Marisa

    2013-01-01

    Comprehensive Immigration Reform in 2012-2013: Accountingpromised to make immigration reform a priority in his firstComprehensive Immigration Reform in 2012-2013 Accounting for

  18. Reforming of fuel inside fuel cell generator

    DOE Patents [OSTI]

    Grimble, Ralph E. (Finleyville, PA)

    1988-01-01

    Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

  19. Particle pressures in fluidized beds. Final report

    SciTech Connect (OSTI)

    Campbell, C.S.; Rahman, K.; Jin, C.

    1996-09-01

    This project studies the particle pressure, which may be thought of as the force exerted by the particulate phase of a multiphase mixture, independently of that exerted by other phases. The project is divided into two parts, one concerning gas and the other liquid fluidized beds. Previous work on gas fluidized beds had suggested that the particle pressures are generated by bubbling action. Thus, for these gas fluidized bed studies, the particle pressure is measured around single bubbles generated in 2-D fluidized beds, using special probes developed especially for this purpose. Liquid beds are immune from bubbling and the particle pressures proved too small to measure directly. However, the major interest in particle pressures in liquid beds lies in their stabilizing effect that arises from the effective elasticity (the derivative of the particle pressure with respect to the void fraction), they impart to the bed. So rather than directly measure the particle pressure, the authors inferred the values of the elasticity from measurements of instability growth in liquid beds; the inference was made by first developing a generic stability model (one with all the normally modeled coefficients left undetermined) and then working backwards to determine the unknown coefficients, including the elasticity.

  20. Particle Pressures in Fluidized Beds. Final report

    SciTech Connect (OSTI)

    Campbell, C.S.; Rahman, K.; Jin, C.

    1996-09-01

    This project studies the particle pressure, which may be thought of as the force exerted by the particulate phase of a multiphase mixture, independently of that exerted by other phases. The project is divided into two parts, one concerning gas and the other liquid fluidized beds. Previous work on gas fluidized beds had suggested that the particle pressures are generated by bubbling action. Thus, for these gas fluidized bed studies, the particle pressure is measured around single bubbles generated in 2-D fluidized beds, using special probes developed especially for this purpose. Liquid beds are immune from bubbling and the particle pressures proved too small to measure directly. However, the major interest in particle pressures in liquid beds lies in their stabilizing effect that arises from the effective elasticity (the derivative of the particle pressure with respect to the void fraction): they impart to the bed. So rather than directly measure the particle pressure, we inferred the values of the elasticity from measurements of instability growth in liquid beds the inference was made by first developing a generic stability model (one with all the normally modeled coefficients left undetermined)and then working backwards to determine the unknown coefficients, including the elasticity.

  1. Pressure Drop in a Pebble Bed Reactor 

    E-Print Network [OSTI]

    Kang, Changwoo

    2011-10-21

    of the wall effects and porosity can be explained by using different bed-to-particle diameter ratios. Four different bed-to-particle ratios were used in these experiments (D/dp = 19, 9.5, 6.33 and 3.65). A comparison is made between the predictions by a number...

  2. Best Management Practices for Bedding and

    E-Print Network [OSTI]

    Ishida, Yuko

    1 Best Management Practices for Bedding and Container Color Plant Production in California #12;2 Table of Contents Acknowledgements 3 Introduction 4 Current Integrated Pest Management Practices in California Bedding and Container Color Plant Production 5 Best Management Practices for Disease Prevention 16

  3. Fluidized-bed copper oxide process

    SciTech Connect (OSTI)

    Shah, P.P.; Takahashi, G.S.; Leshock, D.G.

    1991-10-14

    The fluidized-bed copper oxide process was developed to simultaneously remove sulfur dioxide and nitrogen oxide contaminants from the flue gas of coal-fired utility boilers. This dry and regenerable process uses a copper oxide sorbent in a fluidized-bed reactor. Contaminants are removed without generating waste material. (VC)

  4. Fluidized-bed combustion fuel

    SciTech Connect (OSTI)

    Rich, J.W. Jr.

    1990-10-09

    This patent describes a process for producing from a solid carbonaceous refuse a high ash fuel for use in a circulating fluidized-bed combustion chamber. It comprises separating from the refuse a carbonaceous portion having an ash content in a selected range percent by weight; separating the carbonaceous portion into first and second fractions, the first fraction being at or above a selected size; crushing the first fraction; and combining the crushed first fraction with the second fraction. Also described is a process wherein the selected ash content range is between about 30 percent and about 50 percent, by weight. Also described is a process wherein the selected size is above about 1/4 inch.

  5. Fluidized bed heat treating system

    DOE Patents [OSTI]

    Ripley, Edward B; Pfennigwerth, Glenn L

    2014-05-06

    Systems for heat treating materials are presented. The systems typically involve a fluidized bed that contains granulated heat treating material. In some embodiments a fluid, such as an inert gas, is flowed through the granulated heat treating medium, which homogenizes the temperature of the heat treating medium. In some embodiments the fluid may be heated in a heating vessel and flowed into the process chamber where the fluid is then flowed through the granulated heat treating medium. In some embodiments the heat treating material may be liquid or granulated heat treating material and the heat treating material may be circulated through a heating vessel into a process chamber where the heat treating material contacts the material to be heat treated. Microwave energy may be used to provide the source of heat for heat treating systems.

  6. Z-Bed Recovery Water Disposal | Department of Energy

    Office of Environmental Management (EM)

    Z-Bed Recovery Water Disposal Z-Bed Recovery Water Disposal Presentation from the 33rd Tritium Focus Group Meeting held in Aiken, South Carolina on April 22-24, 2014. Z-Bed...

  7. MEDICAL ENTOMOLOGY Repellency of Selected Chemicals Against the Bed Bug

    E-Print Network [OSTI]

    Wang, Changlu

    MEDICAL ENTOMOLOGY Repellency of Selected Chemicals Against the Bed Bug (Hemiptera: Cimicidae and bed bug bites. KEY WORDS bed bug, repellent, DEET, natural product, essential oil Since the late 1990s

  8. Subsurface steam sampling in Geysers wells

    SciTech Connect (OSTI)

    Lysne, P. [Lysne (Peter), Albuquerque, NM (United States); Koenig, B. [Unocal Geothermal and Power Operations Group, Santa Rose, CA (United States); Hirtz, P. [Thermochem, Inc., Santa Rosa, CA (United States); Normann, R.; Henfling, J. [Sandia National Labs., Albuquerque, NM (United States)

    1997-01-01

    A new downhole sampling tool has been built for use in steam wells at The Geysers geothermal reservoir. The tool condenses specimens into an initially evacuated vessel that is opened down hole at the direction of an on-board computer. The tool makes a temperature log of the well as it is deployed, and the pressure and temperature of collected specimens are monitored for diagnostic purposes. Initial tests were encouraging, and the Department of Energy has funded an expanded effort that includes data gathering needed to develop a three-dimensional model of The Geysers geochemical environment. Collected data will be useful for understanding the origins of hydrogen chloride and non-condensable gases in the steam, as well as tracking the effect of injection on the composition of produced steam. Interested parties are invited to observe the work and to join the program.

  9. Ultra supercritical turbines--steam oxidation

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Ziomek-Moroz, Margaret; Alman, David E.

    2004-01-01

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy?s Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538?C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620?C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which would require steam temperatures of up to 760?C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

  10. Integrated vacuum absorption steam cycle gas separation

    DOE Patents [OSTI]

    Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

    2011-11-22

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  11. Experimental studies of steam-propane injection to enhance recovery of an intermediate crude oil 

    E-Print Network [OSTI]

    Tinss, Judicael Christopher

    2001-01-01

    in accelerating oil production and to compare the performance of steam-propane injection versus steam injection alone on an intermediate crude oil of 21 ?API gravity. Eight experimental runs were performed: three pure steam injection runs, three steam...

  12. Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation

    E-Print Network [OSTI]

    Lu, Xiaoming

    2012-01-01

    and adding the superheated steam to the steam turbine cycle.into gasifier as superheated steam in order to reach a highsignificant amount of superheated steam has to be generated

  13. National SCADA Test Bed - Enhancing control systems security...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National SCADA Test Bed - Enhancing control systems security in the energy sector (September 2009) National SCADA Test Bed - Enhancing control systems security in the energy sector...

  14. Circulating fluidized-bed boiler makes inroads for waste recycling

    SciTech Connect (OSTI)

    1995-09-01

    Circulating fluidized-bed (CFB) boilers have ben used for years in Scandinavia to burn refuse-derived fuel (RDF). Now, Foster Wheeler Power Systems, Inc., (Clinton, N.J.) is bringing the technology to the US. Touted as the world`s largest waste-to-energy plant to use CFB technology, the Robbins (III.) Resource Recovery Facility will have the capacity to process 1,600 tons/d of municipal solid waste (MSW) when it begins operation in early 1997. The facility will have two materials-separation and RDF-processing trains, each with dual trommel screens, magnetic and eddy current separators, and shredders. About 25% of the incoming MSW will be sorted and removed for recycling, while 75% of it will be turned into fuel, with a heat value of roughly 6,170 btu/lb. Once burned in the twin CFB boilers the resulting steam will be routed through a single turbine generator to produce 50,000 mW of electric power.

  15. Energy & Environmental Benefits from Steam & Electricity Cogeneration 

    E-Print Network [OSTI]

    Ratheal, R.

    2004-01-01

    -site powerhouses (one coal-fired and one natural gas-fired) and from gas-fired and waste heat boilers in its four hydrocarbon cracking plants. The challenge was to find a way to reduce costs and improve reliability of procuring and/or producing electricity... and steam while maintaining or reducing TEX air emissions. TEX entered into an agreement with Eastex Cogeneration to build, own and operate a 440 MW gas-fired steam and electric cogeneration facility on site. Implementation of the project was complex...

  16. Savings in Steam Systems (A Case Study) 

    E-Print Network [OSTI]

    DeBat, R.

    2001-01-01

    stream_source_info ESL-IE-01-05-37.pdf.txt stream_content_type text/plain stream_size 35654 Content-Encoding ISO-8859-1 stream_name ESL-IE-01-05-37.pdf.txt Content-Type text/plain; charset=ISO-8859-1 Savings in Steam... Systems (A Case Study) Rich DeBat Steam Systems Engineer Armstrong Service, Inc. Three Rivers, MI ABSTRACT Armstrong Service Inc. (ASI) conducted an engineered evaluation at an Ammonium Nitrate Manufacturing facility during the Fall of 1999...

  17. Cover Heated, Open Vessels - Steam Tip Sheet #19

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO steam tip sheet on covering heated, open vessels provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  18. Finding Benefits by Modeling and Optimizing Steam and Power Systems 

    E-Print Network [OSTI]

    Jones, B.; Nelson, D.

    2007-01-01

    A site-wide steam modeling and optimization program (Visual MESA) was implemented at the INEOS Chocolate Bayou site. This program optimizes steam production, compressor turbine extraction, pump operation (turbine/motor) operation, as well...

  19. The Analysis and Development of Large Industrial Steam Systems 

    E-Print Network [OSTI]

    Waterland, A. F.

    1980-01-01

    Chemicals, petroleum, pulp and paper, and many other industries depend heavily on extensive complex steam systems for thermal and mechanical energy delivery. Steam's versatility and desirable characteristics as both a heat transfer medium and a...

  20. Case Study- Steam System Improvements at Dupont Automotive Marshall Laboratory 

    E-Print Network [OSTI]

    Larkin, A.

    2002-01-01

    and implement small scale cogeneration. These recommendations included reducing the medium pressure steam distribution to low pressure, eliminating the medium pressure to low pressure reducing stations, installing a back pressure steam turbine generator...

  1. Steam Tracing...New Technologies for the 21st Century 

    E-Print Network [OSTI]

    Pitzer, R. K.; Barth, R. E.; Bonorden, C.

    1999-01-01

    For decades, steam tracing has been an accepted practice in the heating of piping, vessels, and equipment. This paper presents recent product innovations such as "burn-safe" and "energy efficient" steam tracing products. For the many applications...

  2. Use Steam Jet Ejectors or Thermocompressors to Reduce Venting...

    Broader source: Energy.gov (indexed) [DOE]

    to Recover Low-Pressure Waste Steam Flash High-Pressure Condensate to Regenerate Low-Pressure Steam Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators...

  3. Install and Automatic Blowdown Control System - Steam Tip Sheet #23

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO steam tip sheet on installing automatic blowdown controls provide how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  4. Reliability Improvement Programs in Steam Distribution and Power Generation Systems 

    E-Print Network [OSTI]

    Petto, S.

    1987-01-01

    can be found in power generation. steam distribution, and in all types of durable and non-durable Industrial productions. I 300 " 0 " 200 C " ? ? ~ 'DO ?~ 50 ' .. '7. '70 '75 '50 '.2 The cost to maintain steam systems. namely...

  5. CIBO's Energy Efficiency Handbook for Steam Power Systems 

    E-Print Network [OSTI]

    Bessette, R. D.

    1997-01-01

    The Council of Industrial Boiler Owners (CIBO) has developed a handbook to help boiler operators get the best performance from their industrial steam systems. This energy efficiency handbook takes a comprehensive look at the boiler and steam system...

  6. Review of Orifice Plate Steam Traps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review of Orifice Plate Steam Traps Review of Orifice Plate Steam Traps This guide was prepared to serve as a foundation for making informed decisions about when orifice plate...

  7. Use Vapor Recompression to Recover Low-Pressure Waste Steam,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    that it can be reused. Vapor recompression relies upon a mechanical compressor or steam jet ejector to increase the temperature of the latent heat in steam to render it usable for...

  8. Following Where the Steam Goes: Industry's Business Opportunity 

    E-Print Network [OSTI]

    Jaber, D.; Jones, T.

    1999-01-01

    Many associated benefits accrue from plant projects which comprehensively address steam systems. The DOE-Alliance to Save Energy Steam Challenge program was initiated shortly after last year's IETC on April 30, 1998 to promote awareness...

  9. Standleg Moving Granular Bed Filter development program

    SciTech Connect (OSTI)

    Newby, R.A.; Yang, W.C.; Smeltzer, E.E.

    1992-11-01

    The design, fabrication, and installation of the cold flow test facility has been completed. The SMGBF test facility shown in Figure 2 consists of a solids feed hopper, a transparent test vessel, a screw conveyor, a 55-gal drum for solids storage, a dust feeder, a baghouse filter, and the associated instrumentation for flow and pressure control and measurement. The standleg is 11-in ID by 3-ft long, and also transparent to facilitate observation. The crushed acrylic particles of characteristics shown in Table 1 are used as the bed media. The bed particles were selected, by maintaining the particle size while reducing the particle density, to simulate the minimum fluidization velocity expected under high-temperature, high-pressure conditions. By maintaining the particle size, the bed effectively simulates the bed packing and voidage in the moving bed which is directly related to the efficiency of particulate removal and pressure drop characteristics. The test facility performed as designed and no particular difficulties were encountered. The baseline data on pressure profiles across the stationary and the moving granular beds were obtained for gas face velocities up to 6 ft/s, higher than the minimum fluidization velocity of the bed material (5 ft/s), and no visible fluidization was observed at the base of the standleg. This confirms the operational feasibility of the compact SMGBF design.

  10. Standleg Moving Granular Bed Filter development program

    SciTech Connect (OSTI)

    Newby, R.A.; Yang, W.C.; Smeltzer, E.E.

    1992-01-01

    The design, fabrication, and installation of the cold flow test facility has been completed. The SMGBF test facility shown in Figure 2 consists of a solids feed hopper, a transparent test vessel, a screw conveyor, a 55-gal drum for solids storage, a dust feeder, a baghouse filter, and the associated instrumentation for flow and pressure control and measurement. The standleg is 11-in ID by 3-ft long, and also transparent to facilitate observation. The crushed acrylic particles of characteristics shown in Table 1 are used as the bed media. The bed particles were selected, by maintaining the particle size while reducing the particle density, to simulate the minimum fluidization velocity expected under high-temperature, high-pressure conditions. By maintaining the particle size, the bed effectively simulates the bed packing and voidage in the moving bed which is directly related to the efficiency of particulate removal and pressure drop characteristics. The test facility performed as designed and no particular difficulties were encountered. The baseline data on pressure profiles across the stationary and the moving granular beds were obtained for gas face velocities up to 6 ft/s, higher than the minimum fluidization velocity of the bed material (5 ft/s), and no visible fluidization was observed at the base of the standleg. This confirms the operational feasibility of the compact SMGBF design.

  11. A PROTOTYPE FOUR INCH SHORT HYDRIDE (FISH) BED AS A REPLACEMENT TRITIUM STORAGE BED

    SciTech Connect (OSTI)

    Klein, J.; Estochen, E.; Shanahan, K.; Heung, L.

    2011-02-23

    The Savannah River Site (SRS) tritium facilities have used 1st generation (Gen1) metal hydride storage bed assemblies with process vessels (PVs) fabricated from 3 inch nominal pipe size (NPS) pipe to hold up to 12.6 kg of LaNi{sub 4.25}Al{sub 0.75} metal hydride for tritium gas absorption, storage, and desorption for over 15 years. The 2nd generation (Gen2) of the bed design used the same NPS for the PV, but the added internal components produced a bed nominally 1.2 m long, and presented a significant challenge for heater cartridge replacement in a footprint limited glove-box. A prototype 3rd generation (Gen3) metal hydride storage bed has been designed and fabricated as a replacement candidate for the Gen2 storage bed. The prototype Gen3 bed uses a PV pipe diameter of 4 inch NPS so the bed length can be reduced below 0.7 m to facilitate heater cartridge replacement. For the Gen3 prototype bed, modeling results show increased absorption rates when using hydrides with lower absorption pressures. To improve absorption performance compared to the Gen2 beds, a LaNi{sub 4.15}Al{sub 0.85} material was procured and processed to obtain the desired pressure-composition-temperature (PCT) properties. Other bed design improvements are also presented.

  12. Improving Steam System Performance: A Sourcebook for Industry, Second Edition

    SciTech Connect (OSTI)

    2012-02-23

    This sourcebook is designed to provide steam system users with a reference that describes the basic steam system components, outlines opportunities for energy and performance improvements, and discusses the benefits of a systems approach in identifying and implementing these improvement opportunities. The sourcebook is divided into three main sections: steam system basics, performance improvement opportunities, and where to find help.

  13. Industrial Steam Power Cycles Final End-Use Classification 

    E-Print Network [OSTI]

    Waterland, A. F.

    1983-01-01

    Final end uses of steam include two major classifications: those uses that condense the steam against heat transfer surfaces to provide heat to an item of process or service equipment; and those that require a mass flow of steam for stripping...

  14. Steam boiler control specification problem: A TLA solution

    E-Print Network [OSTI]

    Merz, Stephan

    Steam boiler control specification problem: A TLA solution Frank Le�ke and Stephan Merz Institut f of the state of the steam boiler, detect failures, and model message transmission. We give a more detailed between the physi­ cal state of the steam boiler and the model maintained by the controller and discuss

  15. An Object-Oriented Algebraic Steam-Boiler Control Specification

    E-Print Network [OSTI]

    Ã?lveczky, Peter Csaba

    An Object-Oriented Algebraic Steam-Boiler Control Specification Peter Csaba ()lveczky, Poland Abstract. In this paper an object-oriented algebraic solution of the steam-boiler specification Introduction The steam-boiler control specification problem has been proposed as a challenge for different

  16. An Object-Oriented Algebraic Steam-Boiler Control Specification

    E-Print Network [OSTI]

    Ã?lveczky, Peter Csaba

    An Object-Oriented Algebraic Steam-Boiler Control Specification.In this paper an object-oriented algebraic solution of the steam-boiler specification problem is presented computations cannot happen. 1 Introduction The steam-boiler control specification problem has been

  17. Steam boiler control speci cation problem: A TLA solution

    E-Print Network [OSTI]

    Cengarle, María Victoria

    Steam boiler control speci cation problem: A TLA solution Frank Le ke and Stephan Merz Institut fur of the state of the steam boiler, detect failures, and model message transmission. We give a more detailed between the physi- cal state of the steam boiler and the model maintained by the controller and discuss

  18. An ObjectOriented Algebraic SteamBoiler Control Specification

    E-Print Network [OSTI]

    Ã?lveczky, Peter Csaba

    An Object­Oriented Algebraic Steam­Boiler Control Specification Peter Csaba Ë? Olveczky 1# , Piotr, Poland Abstract. In this paper an object­oriented algebraic solution of the steam­boiler specification Introduction The steam­boiler control specification problem has been proposed as a challenge for di

  19. STEAM RECEIVER MODELS FOR SOLAR DISH CONCENTRATORS: TWO MODELS COMPARED

    E-Print Network [OSTI]

    that commercial steam turbines operate at. It is envisaged that plants based on large arrays of dishes wouldSTEAM RECEIVER MODELS FOR SOLAR DISH CONCENTRATORS: TWO MODELS COMPARED José Zapata, Keith response of a parabolic dish steam cavity receiver. Both approaches are based on a heat transfer model

  20. Lowest Pressure Steam Saves More BTU's Than You Think 

    E-Print Network [OSTI]

    Vallery, S. J.

    1985-01-01

    the high and low steam pressures. The discussion below shows how the savings in using low pressure steam can be above 25%! The key to the savings is not in the heat exchanger equipment or the steam trap, but is back at the powerhouse - the sensible heat...