National Library of Energy BETA

Sample records for bc v6t 1z1

  1. Geocost-Bc

    Energy Science and Technology Software Center (OSTI)

    1981-03-24

    GEOCOST calculates the cost of generating electricity from geothermal energy. The version of GEOCOST in this release, GEOCOST-BC, simulates the production of electricity using a binary fluid cycle based upon a hydrothermal resource.

  2. A-BC Exact Coupled Channel Scattering

    Energy Science and Technology Software Center (OSTI)

    1992-03-02

    VIVAS2 computes the scattering S-matrix and transition probabilities for the collision of an S-state atom, A, with a sigma-state diatomic molecule, BC.

  3. ARM - Campaign Instrument - tc-bc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentstc-bc Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Total Carbon and Black Carbon Concentrations on Filter Samples (TC-BC) Instrument Categories Aerosols, Atmospheric Carbon Campaigns Aerosol IOP [ Download Data ] Southern Great Plains, 2003.05.01 - 2003.05.31 Primary Measurements Taken The following measurements are those considered scientifically relevant. Refer to the datastream (netcdf) file headers for

  4. Synthesis of bulk superhard semiconducting B-C material (Journal...

    Office of Scientific and Technical Information (OSTI)

    Synthesis of bulk superhard semiconducting B-C material Citation Details In-Document Search Title: Synthesis of bulk superhard semiconducting B-C material A bulk composite ...

  5. Ferro- and antiferro-magnetism in (Np, Pu)BC

    SciTech Connect (OSTI)

    Klimczuk, T.; Kozub, A. L.; Griveau, J.-C.; Colineau, E.; Wastin, F.; Falmbigl, M.; Rogl, P.

    2015-04-01

    Two new transuranium metal boron carbides, NpBC and PuBC, have been synthesized. Rietveld refinements of powder XRD patterns of (Np,Pu)BC confirmed in both cases isotypism with the structure type of UBC. Temperature dependent magnetic susceptibility data reveal antiferromagnetic ordering for PuBC below T{sub N} = 44 K, whereas ferromagnetic ordering was found for NpBC below T{sub C} = 61 K. Heat capacity measurements prove the bulk character of the observed magnetic transition for both compounds. The total energy electronic band structure calculations support formation of the ferromagnetic ground state for NpBC and the antiferromagnetic ground state for PuBC.

  6. Hanford Site - 100-BC-5 | Department of Energy

    Office of Environmental Management (EM)

    BC-5 Hanford Site - 100-BC-5 July 1, 2014 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName, State: Hanford Site Responsible DOE Office: Office of Environmental Management Plume Name: 100-BC-5 Remediation Contractor: CHPRC PBS Number: 30 Report Last Updated: July 2014 with CY2013 data Contaminants Halogenated VOCs/SVOCs Present?: Yes VOC Name Concentration (ppb) Regulatory Driver Cleanup Requirement TCE 2.8 No Metal Name Metal Concentration

  7. 100-B/C Target Analyte List Development for Soil

    SciTech Connect (OSTI)

    R.W. Ovink

    2010-03-18

    This report documents the process used to identify source area target analytes in support of the 100-B/C remedial investigation/feasibility study addendum to DOE/RL-2008-46. This report also establishes the analyte exclusion criteria applicable for 100-B/C use and the analytical methods needed to analyze the target analytes.

  8. Painted Hills B&C Wind Farm I | Open Energy Information

    Open Energy Info (EERE)

    Painted Hills B&C Wind Farm I Jump to: navigation, search Name Painted Hills B&C Wind Farm I Facility Painted Hills B&C Sector Wind energy Facility Type Commercial Scale Wind...

  9. BC Transit Fuel Cell Bus Project: Evaluation Results Report

    SciTech Connect (OSTI)

    Eudy, L.; Post, M.

    2014-02-01

    This report evaluates a fuel cell electric bus demonstration led by British Columbia Transit (BC Transit) in Whistler, Canada. BC Transit is collaborating with the California Air Resources Board and the U.S. Department of Energy's National Renewable Energy Laboratory to evaluate the buses in revenue service. This evaluation report covers two years of revenue service data on the buses from April 2011 through March 2013.

  10. CHPRC0909-33 BC Control Facts.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiological Surveys at Hanford A Department of Energy Recovery Act Project An innovative approach to radiological surveys is being used to evaluate shallow soil contamination near the center of the Hanford Site, an area known as the Central Plateau. As a result of animal intrusion and wind dispersion of contaminants originating in the BC Cribs and Trenches, shallow soil contamination across the adjacent site known as the BC Controlled Area, located south of Hanford's 200 East Area. The U.S.

  11. BC Transit Fuel Cell Bus Project Evaluation Results: Second Report

    SciTech Connect (OSTI)

    Eudy, L.; Post, M.

    2014-09-01

    Second report evaluating a fuel cell electric bus (FCEB) demonstration led by British Columbia Transit (BC Transit) in Whistler, Canada. BC Transit is collaborating with the California Air Resources Board and the U.S. Department of Energy's National Renewable Energy Laboratory to evaluate the buses in revenue service. NREL published its first report on the demonstration in February 2014. This report is an update to the previous report; it covers 3 full years of revenue service data on the buses from April 2011 through March 2014 and focuses on the final experiences and lessons learned.

  12. Synthesis of bulk superhard semiconducting B-C material

    SciTech Connect (OSTI)

    Solozhenko, Vladimir L.; Dubrovinskaia, Natalia A.; Dubrovinsky, Leonid S.

    2004-08-30

    A bulk composite superhard material was synthesized from graphitelike BC{sub 3} at 20 GPa and 2300 K using a multianvil press. The material consists of intergrown boron carbide B{sub 4}C and B-doped diamond with 1.8 at.%B. The material exhibits semiconducting behavior and extreme hardness comparable with that of single-crystal diamond.

  13. Painted Hills B&C Wind Farm II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Painted Hills B&C Wind Farm II Facility Painted Hills B&C Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  14. BC Hydro Brings Energy Savings to Low-Income Families in Canada...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BC Hydro Brings Energy Savings to Low-Income Families in Canada BC Hydro Brings Energy Savings to Low-Income Families in Canada The number of British Columbia, Canada, households ...

  15. BC Hydro Brings Energy Savings to Low-Income Families in Canada |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy BC Hydro Brings Energy Savings to Low-Income Families in Canada BC Hydro Brings Energy Savings to Low-Income Families in Canada The number of British Columbia, Canada, households eligible for Better Buildings Residential Network member BC Hydro's Energy Conservation Assistance Program (ECAP) just doubled. British Columbia Energy Minister Bill Bennett recently announced an increase in the low-income qualification cutoff for BC Hydro's free home energy-saving kits and

  16. BC Transit Fuel Cell Bus Project Evaluation Results: Second Report

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    BC Transit Fuel Cell Bus Project Evaluation Results: Second Report L. Eudy and M. Post National Renewable Energy Laboratory Technical Report NREL/TP-5400-62317 September 2014 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance for Sustainable Energy, LLC This report is available at no cost from the National Renewable Energy Laboratory (NREL) at www.nrel.gov/publications. Contract No. DE-AC36-08GO28308 National

  17. Study of the B+c ? J/?D+s and B+c ? J/?D*s+ decays with the ATLAS detector

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aad, G.; Abbott, B.; Abdallah, J.; Abdinov, O.; Aben, R.; Abolins, M.; AbouZeid, O. S.; Abramowicz, H.; Abreu, H.; Abreu, R.; et al

    2016-01-05

    The decays B+c ? J/?D+s and B+c ? J/?D*s+ are studied with the ATLAS detector at the LHC using a dataset corresponding to integrated luminosities of 4.9 and 20.6 fb1 of pp collisions collected at centre-of-mass energies ?s = 7 TeV and 8 TeV, respectively. Furthermore, signal candidates are identified through J/? ? ?+?- and D(*)+s ? ??+(?/?0) decays.

  18. Measurement of the ratio of the production cross sections times branching fractions of Bc ? J/??and B ? J/? K and B(Bc? J/? ???-/+)/B(Bc ? J/? ?) in pp collisions at ?s = 7 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, V.

    2015-01-13

    The ratio of the production cross sections times branching fractions (?(Bc) B(Bc ? J/??))/(?(B) B(B ? J/?K) is studied in proton-proton collisions at a center-of-mass energy of 7 TeV with the CMS detector at the LHC. The kinematic region investigated requires Ba,sub>c and Bmesons with transverse momentum p? > 15 GeV and rapidity |y| -1. The ratio is determined to be [0.48 0.05 (stat) 0.03(syst) 0.05 (?Bc)]% The J/????-/+ decay mode is also observed in the same data sample. Using a model-independent method developed tomoremeasure the efficiency given the presence of resonant behaviour in the three-pion system, the ratio of the branching fractions J/? ???-/+)/B(Bc is measured to be 2.55 0.80(stat) 0.33(syst) +0.04-0.01 (?Bc), consistent with the previous LHCb result.less

  19. Genome analysis and physiological comparison of Alicycliphilus denitrificans strains BC and K601T

    SciTech Connect (OSTI)

    Oosterkamp, Margreet J.; Veuskens, Teun; Saia, Flavia Talarico; Weelink, Sander A.B.; Goodwin, Lynne A.; Daligault, Hajnalka E.; Bruce, David; Detter, J. Chris; Tapia, Roxanne; Han, Cliff; Land, Miriam L; Hauser, Loren John; Langenhoff, A. M.; Gerritse, Jan; Van Berkel, Willem J. H.; Pieper, Dietmar; Junca, Howard; Smidt, Hauke; Schraa, Gosse; Davids, Mark; Schaap, Peter J; Plugge, Caroline M.; Stams, Alfons J. M.

    2013-01-01

    The genomes of the Betaproteobacteria Alicycliphilus denitrificans strains BC and K601T have been sequenced to get insight into the physiology of the two strains. Strain BC degrades benzene with chlorate as electron acceptor. The cyclohexanol-degrading denitrifying strain K601T is not able to use chlorate as electron acceptor, while strain BC cannot degrade cyclohexanol. The 16S rRNA sequences of strains BC and K601T are identical and the fatty acid methyl ester patterns of the strains are similar. Basic Local Alignment Search Tool (BLAST) analysis of predicted open reading frames of both strains showed most hits with Acidovorax sp. JS42, a bacterium that degrades nitro-aromatics. The genomes include strain-specific plasmids (pAlide201 in strain K601T and pAlide01 and pAlide02 in strain BC). Key genes of chlorate reduction in strain BC were located on a 120 kb megaplasmid (pAlide01), which was absent in strain K601T. Genes involved in cyclohexanol degradation were only found in strain K601T. Benzene and toluene are degraded via oxygenase-mediated pathways in both strains. Genes involved in the meta-cleavage pathway of catechol are present in the genomes of both strains. Strain BC also contains all genes of the ortho-cleavage pathway. The large number of mono- and dioxygenase genes in the genomes suggests that the two strains have a broader substrate range than known thus far.

  20. Synthesis of new Diamond-like B-C Phases under High Pressure and Temperatures

    SciTech Connect (OSTI)

    Ming, L. C.; Zinin, P. V.; Sharma, S. K.

    2014-04-22

    A cubic BC3 (c-BC3) phase was synthesized by direct transformation from graphitic phases at a pressure of 39 GPa and temperature of 2200 K in a laser-heated diamond anvil cell (DAC). A combination of x-ray diffraction (XRD), electron diffraction (ED), transmission electron microscopy (TEM) imaging, and electron energy loss spectroscopy (EELS) measurements lead us to conclude that the obtained phase is hetero-nano-diamond, c-BC3. The EELS measurements show that the atoms inside the cubic structure are bonded by sp3 bonds.

  1. Study of the B+c → J/ΨD+s and B+c → J/ΨD*s+ decays with the ATLAS detector

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aad, G.; Abbott, B.; Abdallah, J.; Abdinov, O.; Aben, R.; Abolins, M.; AbouZeid, O. S.; Abramowicz, H.; Abreu, H.; Abreu, R.; et al

    2016-01-05

    The decays B+c → J/ΨD+s and B+c → J/ΨD*s+ are studied with the ATLAS detector at the LHC using a dataset corresponding to integrated luminosities of 4.9 and 20.6 fb–1 of pp collisions collected at centre-of-mass energies √s = 7 TeV and 8 TeV, respectively. Furthermore, signal candidates are identified through J/ψ → μ+μ- and D(*)+s → Φπ+(γ/π0) decays.

  2. Remedial investigation/feasibility study work plan for the 100-BC-2 operable unit, Hanford Site, Richland, Washington

    SciTech Connect (OSTI)

    Not Available

    1993-05-01

    This work plan and attached supporting project plans establish the operable unit setting and the objectives, procedures, tasks, and schedule for conducting the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) remedial investigation/feasibility study (RI/FS) for the 100-BC-2 operable unit in the 100 Area of the Hanford Site. The 100 Area is one of four areas at the Hanford Site that are on the US Environmental Protection Agency`s (EPA) National Priorities List under CERCLA. The 100-BC-2 operable unit is one of two source operable units in the 100-B/C Area (Figure ES-1). Source operable units are those that contain facilities and unplanned release sites that are potential sources of hazardous substance contamination. The 100-BC-2 source operable unit contains waste sites that were formerly in the 100-BC-2, 100-BC-3, and 100-BC-4 operable units. Because of their size and geographic location, the waste sites from these two operable units were added to 100-BC-2. This allows for a more efficient and effective investigation of the remaining 100-B/C Reactor area waste sites. The investigative approach to waste sites associated with the 100-BC-2 operable unit are listed in Table ES-1. The waste sites fall into three general categories: high priority liquid waste disposal sites, low priority liquid waste disposal sites, and solid waste burial grounds. Several sites have been identified as candidates for conducting an IRM. Two sites have been identified as warranting additional limited field sampling. The two sites are the 116-C-2A pluto crib, and the 116-C-2C sand filter.

  3. BC_2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the J efferson Science A sso ciates for the U.S. Department of Energy Office of Science Thomas Jefferson National Accelerator Facility Jefferson Lab Operated by the J efferson Science A sso ciates for the U.S. Department of Energy Office of Science Thomas Jefferson National Accelerator Facility Jefferson Lab Operated by the J efferson Science A sso ciates for the U.S. Department of Energy Office of Science Thomas Jefferson National Accelerator Facility Jefferson Lab Operated by the J efferson

  4. Oh Canada! B.C. ratifies North America's first carbon tax

    SciTech Connect (OSTI)

    Peltier, R.

    2008-08-15

    British Columbia began collecting increased tax revenue on fossil fuels on July 1 with a promise to rebate those taxes through reduced income and business tax rates. This 'revenue recycling' plan makes little progress toward the province's goal to reduce CO{sub 2} emissions 33% by 2020, yet it is hailed by proponents as a legislative milestone. Others believe BC residents are victims of another governmental 'bait and switch' program. This paper examines the legislation. 2 figs.

  5. Source sector and region contributions to BC and PM2.5 in Central Asia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kulkarni, S.; Sobhani, N.; Miller-Schulze, J. P.; Shafer, M. M.; Schauer, J. J.; Solomon, P. A.; Saide, P. E.; Spak, S. N.; Cheng, Y. F.; Denier van der Gon, H. A. C.; et al

    2015-02-18

    Particulate matter (PM) mass concentrations, seasonal cycles, source sector, and source region contributions in Central Asia (CA) are analyzed for the period April 2008–July 2009 using the Sulfur Transport and dEposition Model (STEM) chemical transport model and modeled meteorology from the Weather Research and Forecasting (WRF) model. Predicted aerosol optical depth (AOD) values (annual mean value ~0.2) in CA vary seasonally, with lowest values in the winter. Surface PM2.5 concentrations (annual mean value ~10 μg m-3) also exhibit a seasonal cycle, with peak values and largest variability in the spring/summer, and lowest values and variability in the winter (hourly valuesmore » from 2 to 90 μg m-3). Surface concentrations of black carbon (BC) (mean value ~0.1 μg m-3) show peak values in the winter. The simulated values are compared to surface measurements of AOD as well as PM2.5, PM10, BC, and organic carbon (OC) mass concentrations at two regional sites in Kyrgyzstan (Lidar Station Teplokluchenka (LST) and Bishkek). The predicted values of AOD and PM mass concentrations and their seasonal cycles are fairly well captured. The carbonaceous aerosols are underpredicted in winter, and analysis suggests that the winter heating emissions are underestimated in the current inventory. Dust, from sources within and outside CA, is a significant component of the PM mass and drives the seasonal cycles of PM and AOD. On an annual basis, the power and industrial sectors are found to be the most important contributors to the anthropogenic portion of PM2.5. Residential combustion and transportation are shown to be the most important sectors for BC. Biomass burning within and outside the region also contributes to elevated PM and BC concentrations. The analysis of the transport pathways and the variations in particulate matter mass and composition in CA demonstrates that this region is strategically located to characterize regional and intercontinental transport of

  6. Novel spin-electronic properties of BC{sub 7} sheets induced by strain

    SciTech Connect (OSTI)

    Xu, Lei; Dai, ZhenHong Sui, PengFei; Sun, YuMing; Wang, WeiTian

    2014-11-01

    Based on first-principles calculations, the authors have investigated the electronic and magnetic properties of BC{sub 7} sheets with different planar strains. It is found that metal–semiconductor transition appears at the biaxial strain of 15.5%, and the sheets are characteristic of spin-polarized semiconductor with a zero band-gap. The band-gap rapidly increases with strain, and reaches a maximum value of 0.60 eV at the strain of 20%. Subsequently, the band-gap decreases until the strain reaches up to 22% and shows a semiconductor-half metal transformation. It will further present metal properties until the strain is up to the maximum value of 35%. The magnetic moments also have some changes induced by biaxial strain. The numerical analysis shows that the two-dimensional distortions have great influences on the magnetic moments. The novel spin-electronic properties make BC{sub 7} sheets have potential applications in future spintronic nanodevices.

  7. Thermal evolution of the metastable r8 and bc8 polymorphs of silicon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Haberl, Bianca; Guthrie, Malcolm; Sinogeikin, Stanislav; Shen, Guoyin; Williams, James S.; Bradby, Jodie E.

    2015-01-01

    The kinetics of two metastable polymorphs of silicon under thermal annealing was investi- gated. These phases with body-centred cubic bc8 and rhombohedral r8 structures can be formed upon pressure release from metallic silicon. In the present study, these metastable polymorphs were formed by two dierent methods, via point loading and in a diamond-anvil cell. Upon thermal annealing dierent transition pathways were detected. In the point loading case, the previously reported Si-XIII formed and was conrmed as a new phase with an as yet unidentied structure. In the diamond-anvil cell case, bc8-Si transformed to the hexagonal-diamond structure at elevated pressure, consistentmore » with previous studies at ambient pressure. In contrast, r8-Si transformed directly to diamond-cubic Si at a temperature of 255C. These data were used to construct diagrams of the metastability regimes of the polymorphs formed in a diamond anvil cell and may prove useful for potential technological applications of these metastable polymorphs.« less

  8. Thermal evolution of the metastable r8 and bc8 polymorphs of silicon

    SciTech Connect (OSTI)

    Haberl, Bianca; Guthrie, Malcolm; Sinogeikin, Stanislav; Shen, Guoyin; Williams, James S.; Bradby, Jodie E.

    2015-01-01

    The kinetics of two metastable polymorphs of silicon under thermal annealing was investi- gated. These phases with body-centred cubic bc8 and rhombohedral r8 structures can be formed upon pressure release from metallic silicon. In the present study, these metastable polymorphs were formed by two dierent methods, via point loading and in a diamond-anvil cell. Upon thermal annealing dierent transition pathways were detected. In the point loading case, the previously reported Si-XIII formed and was conrmed as a new phase with an as yet unidentied structure. In the diamond-anvil cell case, bc8-Si transformed to the hexagonal-diamond structure at elevated pressure, consistent with previous studies at ambient pressure. In contrast, r8-Si transformed directly to diamond-cubic Si at a temperature of 255C. These data were used to construct diagrams of the metastability regimes of the polymorphs formed in a diamond anvil cell and may prove useful for potential technological applications of these metastable polymorphs.

  9. Stochastic Parameterization for Light Absorption by Internally Mixed BC/dust in Snow Grains for Application to Climate Models

    SciTech Connect (OSTI)

    Liou, K. N.; Takano, Y.; He, Cenlin; Yang, P.; Leung, Lai-Yung R.; Gu, Y.; Lee, W- L.

    2014-06-27

    A stochastic approach to model the positions of BC/dust internally mixed with two snow-grain types has been developed, including hexagonal plate/column (convex) and Koch snowflake (concave). Subsequently, light absorption and scattering analysis can be followed by means of an improved geometric-optics approach coupled with Monte Carlo photon tracing to determine their single-scattering properties. For a given shape (plate, Koch snowflake, spheroid, or sphere), internal mixing absorbs more light than external mixing. The snow-grain shape effect on absorption is relatively small, but its effect on the asymmetry factor is substantial. Due to a greater probability of intercepting photons, multiple inclusions of BC/dust exhibit a larger absorption than an equal-volume single inclusion. The spectral absorption (0.2 5 um) for snow grains internally mixed with BC/dust is confined to wavelengths shorter than about 1.4 um, beyond which ice absorption predominates. Based on the single-scattering properties determined from stochastic and light absorption parameterizations and using the adding/doubling method for spectral radiative transfer, we find that internal mixing reduces snow albedo more than external mixing and that the snow-grain shape plays a critical role in snow albedo calculations through the asymmetry factor. Also, snow albedo reduces more in the case of multiple inclusion of BC/dust compared to that of an equal-volume single sphere. For application to land/snow models, we propose a two-layer spectral snow parameterization containing contaminated fresh snow on top of old snow for investigating and understanding the climatic impact of multiple BC/dust internal mixing associated with snow grain metamorphism, particularly over mountains/snow topography.

  10. Remaining Sites Verification Package for the 100-B-21:2 Subsite (100-B/C Discovery Pipeline DS-100BC-002), Waste Site Reclassification Form 2008-003

    SciTech Connect (OSTI)

    J. M. Capron

    2008-06-16

    The 100-B-21:2 waste site consists of the immediate area of the DS-100BC-02 pipeline. In accordance with this evaluation, the confirmatory and verification sampling results support a reclassification of this site to Interim Closed Out. The results of verification sampling show that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River.

  11. Microsoft Word - Electron transfer.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    correspondence: edward.solomon@stanford.edu 2 Present Address: Department of Chemistry, University of British Columbia, Vancouver, BC, Canada V6T 1Z1 Science Highlight - June 2003 A A N N e e w w L L o o o o k k a a t t B B i i o o l l o o g g i i c c a a l l E E l l e e c c t t r r o o n n T T r r a a n n s s f f e e r r : : E E l l e e c c t t r r o o n n i i c c R R e e l l a a x x a a t t i i o o n n i i n n R R u u b b r r e e d d o o x x i i n n s s 1 1, , 2 2, , 3 3 Pierre Kennepohl 1,2

  12. Data:0149f280-821d-4e6f-bc27-501c18ec12fd | Open Energy Information

    Open Energy Info (EERE)

    f-bc27-501c18ec12fd No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic...

  13. Source sector and region contributions to BC and PM2.5 in Central Asia

    SciTech Connect (OSTI)

    Kulkarni, S.; Sobhani, N.; Miller-Schulze, J. P.; Shafer, M. M.; Schauer, J. J.; Solomon, P. A.; Saide, P. E.; Spak, S. N.; Cheng, Y. F.; Denier van der Gon, H. A. C.; Lu, Z.; Streets, D. G.; Janssens-Maenhout, G.; Wiedinmyer, C.; Lantz, J.; Artamonova, M.; Chen, B.; Imashev, S.; Sverdlik, L.; Deminter, J. T.; Adhikary, B.; D'Allura, A.; Wei, C.; Carmichael, G. R.

    2015-02-18

    Particulate matter (PM) mass concentrations, seasonal cycles, source sector, and source region contributions in Central Asia (CA) are analyzed for the period April 2008–July 2009 using the Sulfur Transport and dEposition Model (STEM) chemical transport model and modeled meteorology from the Weather Research and Forecasting (WRF) model. Predicted aerosol optical depth (AOD) values (annual mean value ~0.2) in CA vary seasonally, with lowest values in the winter. Surface PM2.5 concentrations (annual mean value ~10 μg m-3) also exhibit a seasonal cycle, with peak values and largest variability in the spring/summer, and lowest values and variability in the winter (hourly values from 2 to 90 μg m-3). Surface concentrations of black carbon (BC) (mean value ~0.1 μg m-3) show peak values in the winter. The simulated values are compared to surface measurements of AOD as well as PM2.5, PM10, BC, and organic carbon (OC) mass concentrations at two regional sites in Kyrgyzstan (Lidar Station Teplokluchenka (LST) and Bishkek). The predicted values of AOD and PM mass concentrations and their seasonal cycles are fairly well captured. The carbonaceous aerosols are underpredicted in winter, and analysis suggests that the winter heating emissions are underestimated in the current inventory. Dust, from sources within and outside CA, is a significant component of the PM mass and drives the seasonal cycles of PM and AOD. On an annual basis, the power and industrial sectors are found to be the most important contributors to the anthropogenic portion of PM2.5. Residential combustion and transportation are shown to be the most important sectors for BC. Biomass burning within and outside the region also contributes to elevated PM and BC concentrations. The analysis of the transport pathways and the variations in particulate matter mass and composition in CA demonstrates that this region is strategically located

  14. Communication: Microsecond dynamics of the protein and water affect electron transfer in a bacterial bc{sub 1} complex

    SciTech Connect (OSTI)

    Martin, Daniel R.; Matyushov, Dmitry V.

    2015-04-28

    Cross-membrane electron transport between cofactors localized in proteins of mitochondrial respiration and bacterial photosynthesis is the source of all biological energy. The statistics and dynamics of nuclear fluctuations in these protein/membrane/water heterogeneous systems are critical for their energetic efficiency. The results of 13 ?s of atomistic molecular dynamics simulations of the membrane-bound bc{sub 1} bacterial complex are analyzed here. The reaction is affected by a broad spectrum of nuclear modes, with the slowest dynamics in the range of time-scales ?0.1-1.6 ?s contributing half of the reaction reorganization energy. Two reorganization energies are required to describe protein electron transfer due to dynamical arrest of protein conformations on the observation window. This mechanistic distinction allows significant lowering of activation barriers for reactions in proteins.

  15. Characterization of Sediments from the Soil Desiccation Pilot Test (SDPT) Site in the BC Cribs and Trenches Area

    SciTech Connect (OSTI)

    Um, Wooyong; Truex, Michael J.; Valenta, Michelle M.; Iovin, Cristian; Kutnyakov, Igor V.; Chang, Hyun-shik; Clayton, Ray E.; Serne, R. Jeffrey; Ward, Anderson L.; Brown, Christopher F.; Geiszler, Keith N.; Clayton, Eric T.; Baum, Steven R.; Smith, David M.

    2009-09-25

    This technical report documents the results of laboratory geochemical and hydrologic measurements of sediments collected from new borehole 299-E13-65 (C7047) and comparison of the results with those of nearby borehole 299-13E-62 (C5923) both drilled in the BC Cribs and Trenches Area. The total and water-leachable concentrations of key contaminants will be used to update contaminant-distribution conceptual models and to provide more data for improving baseline risk predictions and remedial alternative selections. Improved understanding of subsurface conditions and methods to remediate these principal contaminants can be also used to evaluate the application of specific technologies to other contaminants across the Hanford Site.

  16. Electrical Resistivity Correlation to Vadose Zone Sediment and Pore-Water Composition for the BC Cribs and Trenches Area

    SciTech Connect (OSTI)

    Serne, R. Jeffrey; Ward, Anderson L.; Um, Wooyong; Bjornstad, Bruce N.; Rucker, Dale F.; Lanigan, David C.; Benecke, Mark W.

    2009-06-01

    This technical report documents the results of geochemical and soil resistivity characterization of sediment obtained from four boreholes drilled in the BC Cribs and Trench area. Vadose zone sediment samples were obtained at a frequency of about every 2.5 ft from approximately 5 ft bgs to borehole total depth. In total, 505 grab samples and 39 six-inch long cores were obtained for characterization. The pore-water chemical composition data, laboratory-scale soil resistivity and other ancillary physical and hydrologic measurements and analyses described in this report are designed to provide a crucial link between direct measurements on sediments and the surface-based electrical-resistivity information obtained via field surveys. A second goal of the sediment characterization was to measure the total and water-leachable concentrations of key contaminants of concern as a function of depth and distance from the footprints of inactive disposal facilities. The total and water-leachable concentrations of key contaminants will be used to update contaminant distribution conceptual models and to provide more data for improving base-line risk predictions and remedial alternative selections. The ERC “ground truthing” exercise for the individual boreholes showed mixed results. In general, the high concentrations of dissolved salts in the pore waters of sediments from C5923, C5924 and C4191 produced a low resistivity “target” in the processed resistivity field surveys, and variability could be seen in the resistivity data that could relate to the variability in pore- water concentrations but the correlations (regression R2 were mediocre ranging from 0.2 to 0.7 at best; where perfect correlation is 1.0). The field-based geophysical data also seemed to suffer from a sort of vertigo, where looking down from the ground surface, the target (e.g., maximum pore-water salt concentration) depth was difficult to resolve. The best correlations between the field electrical

  17. 1992 CBECS BC

    U.S. Energy Information Administration (EIA) Indexed Site

    . Census Region, Number of Buildings and Floorspace, 1992 Building Characteristics RSE Column Factor: Number of Buildings (thousand) Total Floorspace (million square feet) RSE Row Factor All Buildings Northeast Midwest South West All Buildings Northeast Midwest South West 0.6 1.2 1.1 1.0 1.3 0.6 1.3 1.1 1.1 1.2 All Buildings ................................... 4,806 771 1,202 1,963 870 67,876 13,400 17,280 24,577 12,619 6.3 Building Floorspace (square feet) 1,001 to 5,000

  18. 1992 CBECS BC

    U.S. Energy Information Administration (EIA) Indexed Site

    A8. Building Size, Number of Buildings, 1992 (Thousand) Building Characteristics RSE Column Factor: All Buildings Buildings by Size RSE Row Factor 1,001 to 5,000 Square Feet 5,001 to 10,000 Square Feet 10,001 to 25,000 Square Feet 25,001 to 50,000 Square Feet 50,001 to 100,000 Square Feet 100,001 to 200,000 Square Feet 200,001 to 500,000 Square Feet Over 500,000 Square Feet 0.5 0.7 0.8 0.8 1.0 1.1 1.3 1.4 2.2 All Buildings ..................................... 4,806 2,681 975 647 280 116 71 26 9

  19. 1992 CBECS BC

    U.S. Energy Information Administration (EIA) Indexed Site

    7. Employment Size Category, Number of Buildings, 1992 (Thousand) Building Characteristics RSE Column Factor: All Buildings Buildings by Number of Workers RSE Row Factor Less than 5 Workers 5 to 9 Workers 10 to 19 Workers 20 to 49 Workers 50 to 99 Workers 100 to 249 Workers 250 or More Workers 0.5 0.8 0.9 1.1 1.0 1.2 1.3 1.4 All Buildings ................................... 4,806 2,718 895 561 405 130 64 31 5.9 Building Floorspace (square feet) 1,001 to 5,000 ................................

  20. 1992 CBECS BC

    U.S. Energy Information Administration (EIA) Indexed Site

    9. Energy Sources, Number of Buildings, 1992 (Thousand) Building Characteristics RSE Column Factor: All Buildings All Buildings Using Any Energy Source Energy Sources Used (more than one may apply) RSE Row Factor Electricity Natural Gas Fuel Oil District Heat District Chilled Water Propane Wood 0.5 0.5 0.5 0.6 1.1 1.6 2.2 1.6 2.0 All Buildings ..................................... 4,806 4,620 4,616 2,665 559 95 28 337 103 7.7 Building Floorspace (Square Feet) 1,001 to 5,000

  1. 1992 CBECS BC

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Percent of Floorspace Heated, Number of Buildings and Floorspace, 1992 Building Characteristics RSE Column Factor: Number of Buildings (thousand) Total Floorspace (million square feet) RSE Row Factor All Buildings Not Heated Less than 51 Percent Heated 51 to 99 Percent Heated 100 Percent Heated All Buildings Total Heated Floorspace in All Buildings Not Heated Less than 51 Percent Heated 51 to 99 Percent Heated 100 Percent Heated 0.6 1.6 1.2 1.1 0.7 0.6 0.6 2.2 1.6 1.2 0.7 All Buildings

  2. 1992 CBECS BC

    U.S. Energy Information Administration (EIA) Indexed Site

    7. Heating Equipment, Number of Buildings, 1992 (Thousand) Building Characteristics RSE Column Factor: All Buildings All Heated Buildings Heating Equipment (more than one may apply) RSE Row Factor Heat Pumps Furnaces Individual Space Heaters District Heat Boilers Packaged Heating Units Other 0.5 0.5 1.3 0.8 0.8 1.7 0.9 1.0 3.1 All Buildings ..................................... 4,806 4,178 449 1,692 1,464 93 624 870 42 6.7 Building Floorspace (square feet) 1,001 to 5,000

  3. 1992 CBECS BC

    U.S. Energy Information Administration (EIA) Indexed Site

    A57. Energy Conservation Features, Number of Buildings and Floorspace, 1992 Building Characteristics RSE Column Factor: Number of Buildings (thousand) Total Floorspace (million square feet) RSE Row Factor All Buildings Any Conser- vation Features Build- ing Shell HVAC Light- ing Other All Buildings Any Conser- vation Features Build- ing Shell HVAC Light- ing Other 0.8 0.8 0.8 0.9 1.0 1.9 0.8 0.9 0.9 0.9 1.2 1.7 All Buildings ................................... 4,806 4,357 4,223 2,604 1,178 264

  4. 1992 CBECS BC

    U.S. Energy Information Administration (EIA) Indexed Site

    A68. Principal Building Activity, Number of Buildings and Floorspace, 1992 Building Characteristics RSE Column Factor: All Buildings (thousand) Total Floorspace (million square feet) RSE Row Factor 0.9 1.1 All Buildings ........................................................ 4,806 67,876 3.7 Principal Building Activity Education ............................................................ 301 8,470 7.5 Food Sales ......................................................... 130 757 14.5 Food

  5. 1992 CBECS BC

    U.S. Energy Information Administration (EIA) Indexed Site

    . Summary Table of Square Feet, Hours of Operation and Age of Building, 1992 Building Characteristics RSE Column Factor: All Buildings (thousand) Total Floorspace (million square feet) Total Workers in All Buildings (thousand) Mean Square Feet per Building (thousand) Median Square Feet per Building (thousand) Mean Square Feet per Worker Median Square Feet per Worker Mean Hours per Week Median Hours per Week Median Age of Buildings (years) RSE Row Factor 1.1 1.2 1.5 1.0 -- 1.3 -- 0.4 -- -- All

  6. PP-22 BC Hydro

    Office of Environmental Management (EM)

  7. Bc at CDF

    SciTech Connect (OSTI)

    Wester, William; /Fermilab

    2006-04-01

    The authors report CDF results on the B{sub c}{sup -} meson in Run II. The B{sub c}{sup -} meson has been observed in semileptonic decays, B{sub c}{sup -} {yields} J/{psi} {ell}{sup -} {nu}X, where {ell} = e, {mu} at a significance greater than 5{sigma} in both channels. The B{sub c}{sup -} {yields} J/{psi} {ell}{sup -}{nu}X observations have resulted in measurements of the relative production times branching ratio with respect to B{sup -} J/{psi} K{sup -} decays and a precise determination of the lifetime of the B{sub c}{sup -}: {tau}(B{sub c}{sup -}) = 0.474{sub -0.066}{sup +0.073}(stat.) {+-} 0.033(syst.) ps. Also, an observation of B{sub c}{sup -} {yields} J/{psi} {pi}{sup -} decays at a significance exceeding 6{sigma} results in a precise determination of the mass of the B{sub c}{sup -}: M(B{sub c}{sup -}) = 6275.2 {+-} 4.3(stat.) {+-} 2.3(syst.) MeV/c{sup 2}.

  8. Binding of the Respiratory Chain Inhibitor Antimycin to theMitochondrial bc1 Complex: A New Crystal Structure Reveals an AlteredIntramolecular Hydrogen-Bonding Pattern

    SciTech Connect (OSTI)

    Huang, Li-shar; Cobessi, David; Tung, Eric Y.; Berry, Edward A.

    2005-05-10

    Antimycin A (antimycin), one of the first known and most potent inhibitors of the mitochondrial respiratory chain, binds to the quinone reduction site of the cytochrome bc1 complex.Structure-activity-relationship studies have shown that the N-formylamino-salicyl-amide group is responsible for most of the binding specificity, and suggested that a low pKa for the phenolic OH group and an intramolecular H-bond between that OH and the carbonyl O of the salicylamide linkage are important. Two previous X-ray structures of antimycin bound to vertebrate bc1 complex gave conflicting results. A new structure reported here of the bovine mitochondrial bc1 complex at 2.28Angstrom resolution with antimycin bound, allows us for the first time to reliably describe the binding of antimycin and shows that the intramolecular hydrogen bond described in solution and in the small-molecule structure is replaced by one involving the NH rather than carbonyl O of the amide linkage, with rotation of the amide group relative to the aromatic ring. The phenolic OH and formylamino N form H-bonds with conserved Asp228 of cyt b, and the formylamino O H-bonds via a water molecule to Lys227. A strong density the right size and shape for a diatomic molecule is found between the other side of the dilactone ring and the alpha-A helix.

  9. License Amendment Request for Storing Exelon Sister Nuclear Stations Class B/C LLRW in the LaSalle Station Interim Radwaste Storage Facility - 13620

    SciTech Connect (OSTI)

    Azar, Miguel; Gardner, Donald A.; Taylor, Edward R.

    2013-07-01

    Exelon Nuclear (Exelon) designed and constructed an Interim Radwaste Storage Facility (IRSF) in the mid-1980's at LaSalle County Nuclear Station (LaSalle). The facility was designed to store low-level radioactive waste (LLRW) on an interim basis, i.e., up to five years. The primary reason for the IRSF was to offset lack of disposal in case existing disposal facilities, such as the Southeast Compact's Barnwell Disposal Facility in Barnwell, South Carolina, ceased accepting radioactive waste from utilities not in the Southeast Compact. Approximately ninety percent of the Radwaste projected to be stored in the LaSalle IRSF in that period of time was Class A, with the balance being Class B/C waste. On July 1, 2008 the Barnwell Disposal Facility in the Southeast Compact closed its doors to out of- compact Radwaste, which precluded LaSalle from shipping Class B/C Radwaste to an outside disposal facility. Class A waste generated by LaSalle is still able to be disposed at the 'Envirocare of Utah LLRW Disposal Complex' in Clive, Utah. Thus the need for utilizing the LaSalle IRSF for storing Class B/C Radwaste for an extended period, perhaps life-of-plant or more became apparent. Additionally, other Exelon Midwest nuclear stations located in Illinois that did not build an IRSF heretofore also needed extended Radwaste storage. In early 2009, Exelon made a decision to forward Radwaste from the Byron Nuclear Station (Byron), Braidwood Nuclear Station (Braidwood), and Clinton Nuclear Station (Clinton) to LaSalle's IRSF. As only Class B/C Radwaste would need to be forwarded to LaSalle, the original volumetric capacity of the LaSalle IRSF was capable of handling the small number of additional expected shipments annually from the Exelon sister nuclear stations in Illinois. Forwarding Class B/C Radwaste from the Exelon sister nuclear stations in Illinois to LaSalle would require an amendment to the LaSalle Station operating license. Exelon submitted the License Amendment Request

  10. Measured thermal and fast neutron fluence rates, ATR Cycle 100-BC, April 23, 1993--May 13, 1993

    SciTech Connect (OSTI)

    Smith, L.D.; Murray, R.K.; Rogers, J.W.

    1993-07-01

    This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for ATR Cycle 100-BC which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order. This report contains fluence rate values corresponding to the particular elevations (relative to the 80 ft. core elevation) where the measurements were taken. The data in this report consists of (1) a table of the ATR power history and distribution, (2) a hard copy listing of all thermal and fast neutron fluence rates, (3) plots of both the thermal and fast neutron fluence rates, and (4) a magnetic record (3.5 inch diskette) containing a listing of only the fast neutron fluence rates, their assigned elevations and proper header identification of all monitor positions contained herein. The fluence rates reported are for the average power levels given in the table of power history and distribution. All {open_quotes}H{close_quotes} holder monitor wires for this cycle are 54 inches long. All {open_quotes}SR{close_quotes} holder monitor wires for this cycle are 55 inches long. This length allows measurement of the full core region and makes the first count elevation 24.73 inches above core midplane. Due to the safety rod problems in the west lobe, {open_quotes}BR{close_quotes} holders were used in the W-1, 2, 3, and 4 positions. All {open_quotes}BR{close_quotes} holder monitor wires for this cycle are 56.25 inches long. The distance from the end of the wires to the first count position was 4.25 inches for all wires counted from this cycle. The results from the measurements in the W-1, 2, 3, 4 monitor positions indicate that the safety rod followers were rotated to a different azimuthal orientation relative to the normal orientation. The results indicate that the rotation was counterclockwise from their normal orientation. This is the same condition observed starting with Cycle 99-B.

  11. Data:A3a8d802-1d32-4c6c-9e1f-e583306bc162 | Open Energy Information

    Open Energy Info (EERE)

    83306bc162 No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic Information 2....

  12. SREL Reprint #3298

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 Development and characterization of twenty-five microsatellite markers for the longnose dace (Cyprinidae: Rhinichthys) using paired-end Illumina shotgun sequencing Rochelle Beasley1, Stacey L. Lance1, Jennifer A. Ruskey2, and Eric B. Taylor2 1Savannah River Ecology Laboratory, University of Georgia, Aiken, SC 29802, USA 2Department of Zoology, Biodiversity Research Centre and Beaty Biodiversity Museum, University of British Columbia, 6270 University Blvd., Vancouver, BC V6T 1Z4, Canada

  13. CBECS 1992 - BC Tables and Definitions

    U.S. Energy Information Administration (EIA) Indexed Site

    of building characteristics that provide the most comprehensive breakdown of principal building activity and energy sources and end uses, respectively. Generally, there are two...

  14. PP-22_BC_Hydro.pdf

    Office of Environmental Management (EM)

  15. PP-369 BC Hydro.pdf

    Office of Environmental Management (EM)

  16. Side-on Cu-Nitrosyl Coordination by Nitrite Reductase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Elitza I. Tocheva and Michael E. P. Murphy Department of Microbiology & Immunology, The University of British Columbia, Vancouver, BC, Canada V6T 1Z3. Nitric oxide (NO) is one of the smallest and simplest biologically active molecules. In mammals, NO is produced from arginine by isoforms of nitric oxide synthase, and it functions in signal transduction and as a cytoprotective or cytotoxic agent. In bacteria, NO is produced by nitrite reductase (NiR), a copper-containing enzyme, which is

  17. MHK Projects/Ucluelet BC Canada | Open Energy Information

    Open Energy Info (EERE)

    has been granted an Investigative Use Permit for the purposes on determining the feasibility of a wave energy project off the coast of Ucluelet, British Columbia. Project...

  18. PP-22-1_BC_Hydro.pdf

    Office of Environmental Management (EM)

  19. PP-22-2_BC_Hydro.pdf

    Office of Environmental Management (EM)

  20. BC TIPS - Hot-Humid Climate: New Orleans

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot-Humid Climate: New Orleans Building Technologies Program The U.S. Department of Energy's Builders Challenge recognizes quality homes that also save you money. U.S. homebuilders...

  1. BC Transit Fuel Cell Bus Project: Evaluation Results Report

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    The Quebec plant produces hydrogen using renewable methods-through electrolysis of water and using a chlor alkali waste recuperation process. Power for these processes comes...

  2. BC TIPS- Hot-Humid Climate: New Orleans

    Broader source: Energy.gov [DOE]

    Homes that provide substantial reductions in energy use and home-owner utility bills and recognizes the best practices for quality, comfort, health, and safety in the market.

  3. Measurement of the B+-_c Meson Lifetime Using B+-_c -> J/psi + l+- + X Decays

    SciTech Connect (OSTI)

    Hartz, Mark Patrick; /Pittsburgh U.

    2008-11-01

    This thesis describes a measurement of the average proper decay time of the B{sub c}{sup {+-}} mesons, the ground state of bottom and charm quark bound states. The lifetime measurement is carried out in the decay modes B{sub c}{sup {+-}} {yields} J/{psi} + e{sup {+-}} + X and B{sub c}{sup {+-}} {yields} J/{psi} + {mu}{sup {+-}} + X, where the J/{psi} decays as J/{psi} {yields} {mu}{sup +}{mu}{sup -} and the X are unmeasured particles such as {nu}{sub e} or {nu}{sub {mu}}. The data are collect by the CDF II detector which measures the properties of particles created in {radical}s = 1.96 TeV p{bar p} collisions delivered by the Fermilab Tevatron. This measurement uses {approx} 1 fb{sup -1} of integrated luminosity. The measured average proper decay time of B{sub c}{sup {+-}} mesons, {tau} = 0.475{sub -0.049}{sup +0.053}(stat.) {+-} 0.018(syst.) ps, is competitive with the most precise measurements in the world and confirms previous measurements and theoretical predictions.

  4. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Schuster, M D (1) TRIUMF, 4004 Wesbrook Mall, Vancouver, British Columbia, V6T 2A3 (1) ... P. ; TRIUMF, 4004 Wesbrook Mall, Vancouver, British Columbia, V6T 2A3 The exact ...

  5. BETO FY14 BC FOA Presentation for BETO 2015 Project Peer Review

    Broader source: Energy.gov (indexed) [DOE]

    ... Summary: * Develop and optimize a disruptive fermentation process using biomethane from biogas and engineered methanotropic bacteria for the production of lactic acid (HLA) * ...

  6. Observation of an Excited Bc± Meson State with the ATLAS Detector

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aad, G.; Abbott, B.; Abdallah, J.; Abdel Khalek, S.; Abdinov, O.; Aben, R.; Abi, B.; Abolins, M.; AbouZeid, O. S.; Abramowicz, H.; et al

    2014-11-21

    We perform a search for excited states of the B±c meson using 4.9 fb-1 of 7 TeV and 19.2 fb-1 of 8 TeV pp collision data collected by the ATLAS experiment at the LHC. A new state is observed through its hadronic transition to the ground state, with the latter detected in the decay B±c →J/ψπ±. The state appears in the m(B±c π+π₋)₋m(B±c )₋2m(π±) mass difference distribution with a significance of 5.2 standard deviations. The mass of the observed state is 6842±4±5 MeV, where the first error is statistical and the second is systematic. The mass and decay of thismore » state are consistent with expectations for the second S-wave state of the B±c meson, B±c (2S).« less

  7. Materials Data on Pr(BC)2 (SG:127) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  8. Materials Data on La(BC)2 (SG:127) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  9. Materials Data on Tb(BC)2 (SG:127) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-03-08

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  10. Materials Data on Tm(BC)2 (SG:127) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-03-08

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  11. Materials Data on Er(BC)2 (SG:127) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-03-08

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  12. Materials Data on Ce(BC)2 (SG:127) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  13. Materials Data on Lu(BC)2 (SG:127) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. Materials Data on Dy(BC)2 (SG:127) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  15. Materials Data on Ho(BC)2 (SG:127) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-03-08

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  16. Materials Data on Mg(BC)2 (SG:64) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  17. BC TIPS - Hot-Humid Climate: New Orleans | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Homes that provide substantial reductions in energy use and home-owner utility bills and recognizes the best practices for quality, comfort, health, and safety in the market. PDF ...

  18. Materials Data on Nb7(BC)4 (SG:71) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  19. Contract NO. DE-FG22-93BC14862 Department of Petroleum Engineering

    Office of Scientific and Technical Information (OSTI)

    Manager (DOE): F. John Fayers Khalid Aziz Thomas A. Hewett Sepehr Arbabi Marilyn Smith Thomas B. Reid - ; . ? --.i 4 . - - - - 9 r c . 1 > -- r n * : - * c-2 : , ...

  20. Materials Data on Y(BC)2 (SG:131) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2015-03-08

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  1. The Lifetime of a beautiful and charming meson: B_c lifetime measured using the D0 detector

    SciTech Connect (OSTI)

    Welty-Rieger, Leah Christine; /Indiana U.

    2008-09-01

    Using approximately 1.3 fb{sup -1} of data collected by the D0 detector between 2002 and 2006, the lifetime of the B{sub c}{sup {+-}} meson is studied in the B{sub c}{sup {+-}} {yields} J/{psi}{mu}{sup {+-}} + X final state. Using an unbinned likelihood simultaneous fit to J/{psi} + {mu} invariant mass and lifetime distributions, a signal of 810 {+-} 80(stat.) candidates is estimated and a lifetime measurement made of: {tau}(B{sub c}{sup {+-}}) = 0.448{sub -0.036}{sup +0.038}(stat) {+-} 0.032(sys) ps.

  2. Treatment and Outcomes in Patients With Primary Cutaneous B-Cell Lymphoma: The BC Cancer Agency Experience

    SciTech Connect (OSTI)

    Hamilton, Sarah N.; Wai, Elaine S.; Tan, King; Alexander, Cheryl; Gascoyne, Randy D.; Connors, Joseph M.

    2013-11-15

    Purpose: To review the treatment and outcomes of patients with primary cutaneous B-cell lymphoma (CBCL). Methods and Materials: Clinical characteristics, treatment, and outcomes were analyzed for all patients referred to our institution from 1981 through 2011 with primary CBCL without extracutaneous or distant nodal spread at diagnosis (n=136). Hematopathologists classified 99% of cases using the World Health Organization-European Organization for Research and Treatment of Cancer (WHO-EORTC) guidelines. Results: Median age at diagnosis was 62 years. Classification was 18% diffuse large B-cell leg-type (DLBCL-leg), 32% follicle center (FCCL), 45% marginal zone (MZL), and 6% nonclassifiable (OTHER). Of the 111 subjects with indolent lymphoma (FCCL, MZL, OTHER), 79% received radiation alone (RT), 11% surgery alone, 3% chemotherapy alone, 4% chemotherapy followed by RT, and 3% observation. Following treatment, 29% of subjects relapsed. In-field recurrence occurred in 2% treated with RT and in 33% treated with surgery alone. Of the 25 subjects with DLBCL-leg, 52% received chemotherapy followed by RT, 24% chemotherapy, 20% RT, and 4% surgery alone. Seventy-nine percent received CHOP-type chemotherapy (cyclophosphamide, doxorubicin or epirubicin, vincristine, prednisone), 47% with rituximab added. Overall and disease-specific survival and time to progression at 5 years were 81%, 92%, and 69% for indolent and 26%, 61%, and 54% for DLBCL-leg, respectively. On Cox regression analysis of indolent subjects, RT was associated with better time to progression (P=.05). RT dose, chemo, age >60 y, and >1 lesion were not significantly associated with time to progression. For DLBCL-leg, disease-specific survival at 5 years was 100% for those receiving rituximab versus 67% for no rituximab (P=.13). Conclusions: This review demonstrates better outcomes for indolent histology compared with DLBCL-leg, validating the prognostic utility of the WHO-EORTC classification. In the indolent group, RT was associated with 98% local control. DLBCL-leg is a more aggressive disease; the excellent results in the rituximab group suggest it has an important role in management.

  3. Radiation environment simulations at the Tevatron, studies of the beam profile and measurement of the Bc meson mass

    SciTech Connect (OSTI)

    Nicolas, Ludovic Y.

    2005-09-01

    The description of a computer simulation of the CDF detector at Fermilab and the adjacent accelerator parts is detailed, with MARS calculations of the radiation background in various elements of the model due to the collision of beams and machine-related losses. Three components of beam halo formation are simulated for the determination of the principal source of radiation background in CDF due to beam losses. The effect of a collimator as a protection for the detector is studied. The simulation results are compared with data taken by a CDF group. Studies of a 150 GeV Tevatron proton beam are performed to investigate the transverse diffusion growth and distribution. A technique of collimator scan is used to scrape the beam under various experimental conditions, and computer programs are written for the beam reconstruction. An average beam halo growth speed is given and the potential of beam tail reconstruction using the collimator scan is evaluated. A particle physics analysis is conducted in order to detect the B{sub c} {yields} J/{psi}{pi} decay signal with the CDF Run II detector in 360 pb{sup -1} of data. The cut variables and an optimization method to determine their values are presented along with a criterion for the detection threshold of the signal. The mass of the B{sub c} meson is measured with an evaluation of the significance of the signal.

  4. B_c Meson Production Around the Z^0 Peak at a High Luminosity e^+ e^- Collider

    SciTech Connect (OSTI)

    Yang, Zhi; Wu, Xing-Gang; Chen, Gu; Liao, Qi-Li; Zhang, Jia-Wei; /Chongqing U.

    2012-05-22

    Considering the possibility to build an e{sup +}e{sup -} collider at the energies around the Z{sup 0}-boson resonance with a planned luminosity so high as L {proportional_to} 10{sup 34} {approx} 10{sup 36} cm{sup -2}s{sup -1} (super Z-factory), we make a detailed discussion on the (c{bar b})-quarkonium production through e{sup +}e{sup -} {yields} (c{bar b})[n] + b + {bar c} within the framework of non-relativistic QCD. Here [n] stands for the Fock-states |(c{sub b}){sub 1}[{sup 1}S{sub 0}]>, |(c{bar b})8[{sup 1}S{sub 0}]g>, |(c{bar b} ){sub 1}[{sup 3}S{sub 1}]>, |(c{bar b}){sub 8}[{sup 3}S{sub 1}]g>, |(c{bar b}){sub 1}[{sup 1}P{sub 1}]> and |(c{bar b}){sub 1}[{sup 3}P{sub J}]> (with J = (1, 2, 3)) respectively. To simplify the hard-scattering amplitude as much as possible and to derive analytic expressions for the purpose of future events simulation, we adopt the 'improved trace technology' to do our calculation, which deals with the hard scattering amplitude directly at the amplitude level other than the conventional way at the squared-amplitude level. Total cross-section uncertainties caused by the quark masses are predicted by taking m{sub c} = 1.50 {+-} 0.30 GeV and m{sub b} = 4.90 {+-} 0.40 GeV. If all higher (c{bar b})-quarkonium states decay to the ground state B{sub c} (|(c{bar b}){sub 1}[{sup 1}S{sub 0}]>) with 100% efficiency, we obtain {sigma}{sub e{sup +}+e{sup -}{yields}B{sub c}+b+{bar c}} = 5.190{sub -2.419}{sup +6.222} pb, which shows that about 10{sup 5} {approx} 10{sup 7} B{sub c} events per operation year can be accumulated in the super Z-factory. If taking the collider energy runs slightly off the Z{sup 0}-peak, i.e. {radical}S = (1.00 {+-} 0.05)m{sub Z}, the total cross-section shall be lowered by about one-order from its peak value. Such a super Z-factory shall provide another useful platform to study the properties of B{sub c} meson, or even the properties of its excited P-wave states, in addition to its production at the hadronic colliders Tevatron and LHC.

  5. Di-photon and photon + b/c production cross sections at Ecm = 1.96- TeV

    SciTech Connect (OSTI)

    Gajjar, Anant; /Liverpool U.

    2005-05-01

    Measurements of the di-photon cross section have been made in the central region and are found to be in good agreement with NLO QCD predictions. The cross section of events containing a photon and additional heavy flavor jet have also been measured, as well as the ratio of photon + b to photon + c. The statistically limited sample shows good agreement with Leading Order predictions.

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Vancouver, British Columbia, V6T2A3 ; Green, K. L. ; Bangay, J. ; Varela, A. Diaz ; ... of stringent limits on, low-energy branches between potential multi-phonon levels. ...

  7. A hybrid fast-multipole technique for space-charge tracking with...

    Office of Scientific and Technical Information (OSTI)

    Authors: Jones, F. W. 1 + Show Author Affiliations TRIUMF, 4004 Wesbrook Mall, Vancouver, V6T 2A3 (Canada) Publication Date: 1998-11-05 OSTI Identifier: 21202286 Resource Type: ...

  8. Data:2bc1a91a-517b-42a1-8f30-4d35cf7ce439 | Open Energy Information

    Open Energy Info (EERE)

    under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic Information 2. Demand 3. Energy << Previous 1 2 3 Next >> Basic Information...

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    under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic Information 2. Demand 3. Energy << Previous 1 2 3 Next >> Basic Information...

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    edda-d0e1-40ee-aac2-c2b32603a6b4 No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1....

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    under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic Information 2. Demand 3. Energy << Previous 1 2 3 Next >> Basic Information...

  13. Data:A125b2bf-bc5f-4315-a944-c784a51a1dac | Open Energy Information

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    c784a51a1dac No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic Information 2....

  14. Variation of the radiative properties during black carbon aging...

    Office of Scientific and Technical Information (OSTI)

    A theoretical black carbon (BC) aging model is developed to account for three typical evolution stages, namely, freshly emitted aggregates, coated BC by soluble material, and BC ...

  15. Randomized Noninferiority Trial of Reduced High-Dose Volume Versus Standard Volume Radiation Therapy for Muscle-Invasive Bladder Cancer: Results of the BC2001 Trial (CRUK/01/004)

    SciTech Connect (OSTI)

    Huddart, Robert A.; Hall, Emma; Hussain, Syed A.; Jenkins, Peter; Rawlings, Christine; Tremlett, Jean; Crundwell, Malcolm; Adab, Fawzi A.; Sheehan, Denise; Syndikus, Isabel; Hendron, Carey; Lewis, Rebecca; Waters, Rachel; James, Nicholas D.

    2013-10-01

    Purpose: To test whether reducing radiation dose to uninvolved bladder while maintaining dose to the tumor would reduce side effects without impairing local control in the treatment of muscle-invasive bladder cancer. Methods and Materials: In this phase III multicenter trial, 219 patients were randomized to standard whole-bladder radiation therapy (sRT) or reduced high-dose volume radiation therapy (RHDVRT) that aimed to deliver full radiation dose to the tumor and 80% of maximum dose to the uninvolved bladder. Participants were also randomly assigned to receive radiation therapy alone or radiation therapy plus chemotherapy in a partial 2 2 factorial design. The primary endpoints for the radiation therapy volume comparison were late toxicity and time to locoregional recurrence (with a noninferiority margin of 10% at 2 years). Results: Overall incidence of late toxicity was less than predicted, with a cumulative 2-year Radiation Therapy Oncology Group grade 3/4 toxicity rate of 13% (95% confidence interval 8%, 20%) and no statistically significant differences between groups. The difference in 2-year locoregional recurrence free rate (RHDVRT ? sRT) was 6.4% (95% confidence interval ?7.3%, 16.8%) under an intention to treat analysis and 2.6% (?12.8%, 14.6%) in the per-protocol population. Conclusions: In this study RHDVRT did not result in a statistically significant reduction in late side effects compared with sRT, and noninferiority of locoregional control could not be concluded formally. However, overall low rates of clinically significant toxicity combined with low rates of invasive bladder cancer relapse confirm that (chemo)radiation therapy is a valid option for the treatment of muscle-invasive bladder cancer.

  16. Data:D2e8eb8e-d151-44bc-8a2c-7e468f57f91f | Open Energy Information

    Open Energy Info (EERE)

    a2c-7e468f57f91f No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic...

  17. Preparing for Tomorrow's Systems: Manycore Resilience Patterns...

    Office of Scientific and Technical Information (OSTI)

    BC, Canada.; Related Information: Proposed for presentation at the International Congress on Industrial and Applied Mathematics held July 19-22, 2011 in Vancouver, BC, Canada

  18. Photo Gallery - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recovery Act 284 West Boiler Demolition 284 West Boiler Demolition 284 West Boiler Demolition 284 West Boiler Demolition 284 West Boiler Demolition 284 West Boiler Demolition 284 West Boiler Demolition 284 West Boiler Demolition 284 West Boiler Demolition 284 West Boiler Demolition 284 West Boiler Demolition 284 West Boiler Demolition BC Control Area Last Truckload BC Control Area Last Truckload BC Control Area Before Remediation BC Control Area Before Remediation BC Control Area After

  19. Enhanced Solar Energy Absorption by Internally-mixed Black Carbon in Snow Grains

    SciTech Connect (OSTI)

    Flanner, M. G.; Liu, Xiaohong; Zhou, Cheng; Penner, Joyce E.; Jiao, C.

    2012-05-30

    Here we explore light absorption by snowpack containing black carbon (BC) particles residing within ice grains. Basic considerations of particle volumes and BC/snow mass concentrations show that there are generally 0:05-109 BC particles for each ice grain. This suggests that internal BC is likely distributed as multiple inclusions within ice grains, and thus the dynamic effective medium approximation (DEMA) (Chylek and Srivastava, 1983) is a more appropriate optical representation for BC/ice composites than coated-sphere or standard mixing approximations. DEMA calculations show that the 460 nm absorption cross-section of BC/ice composites, normalized to the mass of BC, is typically enhanced by factors of 1.8-2.1 relative to interstitial BC. BC effective radius is the dominant cause of variation in this enhancement, compared with ice grain size and BC volume fraction. We apply two atmospheric aerosol models that simulate interstitial and within-hydrometeor BC lifecycles. Although only {approx}2% of the atmospheric BC burden is cloud-borne, 71-83% of the BC deposited to global snow and sea-ice surfaces occurs within hydrometeors. Key processes responsible for within-snow BC deposition are development of hydrophilic coatings on BC, activation of liquid droplets, and subsequent snow formation through riming or ice nucleation by other species and aggregation/accretion of ice particles. Applying deposition fields from these aerosol models in offline snow and sea-ice simulations, we calculate that 32-73% of BC in global surface snow resides within ice grains. This fraction is smaller than the within-hydrometeor deposition fraction because meltwater flux preferentially removes internal BC, while sublimation and freezing within snowpack expose internal BC. Incorporating the DEMA into a global climate model, we simulate increases in BC/snow radiative forcing of 43-86%, relative to scenarios that apply external optical properties to all BC. We show that snow metamorphism

  20. Free Boundary, High Beta Equilibrium in a Large Aspect Ratio...

    Office of Scientific and Technical Information (OSTI)

    ... B.C. Stratton, E.J. Synakowski, G. Taylor, R.M. Wieland, M.C. Zarnstorff, J. ... B.C. Stratton, E.J. Synakowski, G. Taylor, R.M. Wieland, M.C. Zarnstorff, J. ...

  1. ARM - Field Campaign - SP2 Deployment at Boston College-Aerodyne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deployment at Boston College-Aerodyne led Coated Black Carbon Study (BC4) ARM Data ... Campaign : SP2 Deployment at Boston College-Aerodyne led Coated Black Carbon Study (BC4) ...

  2. SP2 Deployment at Boston College-Aerodyne-Led Coated Black Carbon...

    Office of Scientific and Technical Information (OSTI)

    Coated Black Carbon Study (BC4) Final Campaign Summary Citation Details In-Document Search Title: SP2 Deployment at Boston College-Aerodyne-Led Coated Black Carbon Study (BC4) ...

  3. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... FF is also the dominant local source type for BC column burden, deposition, and near-surface BC, while for all distant source regions combined the contribution of biomassbiofuel ...

  4. Impact Evaluation of the FY2012-13 Site-Specific Savings Portfolio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    17 shows the distribution of the BC ratios within each of the domains. Two measures had positive benefits but negative costs which resulted in an infinite value for the BC...

  5. Bonneville Power Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In reply refer to: PGPO Renata Kurschner Director, Generation Resource Management BC Hydro and Power Authority 691 1 Southpoint Drive, El5 Burnaby, B.C., Canada V3N 4 x 8 Dear...

  6. EIS-0170-SA-01: Supplement Analysis

    Broader source: Energy.gov [DOE]

    System Operation Review EIS, Bonneville Power Administration, and B.C. Hydro and Power Authority, British Columbia, Canada

  7. Variation of the radiative properties during black carbon aging: theoretical and experimental intercomparison

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, C.; Liou, K.-N.; Takano, Y.; Zhang, R.; Zamora, M. L.; Yang, P.; Li, Q.; Leung, L. R.

    2015-07-20

    A theoretical black carbon (BC) aging model is developed to account for three typical evolution stages, namely, freshly emitted aggregates, coated BC by soluble material, and BC particles undergoing further hygroscopic growth. The geometric-optics surface-wave (GOS) approach is employed to compute the BC single-scattering properties at each aging stage, which are subsequently compared with laboratory measurements. Theoretical calculations are consistent with measurements in extinction and absorption cross sections for fresh BC aggregates, but overestimate the scattering cross sections for BC mobility diameters of 155, 245, and 320 nm, because of uncertainties associated with theoretical calculations for small particles as wellmore » as laboratory scattering measurements. The measured optical cross sections for coated BC by sulfuric acid and for those undergoing further hygroscopic growth are captured by theoretical calculations using a concentric core-shell structure, with differences of less than 20 %. This suggests that the core-shell shape represents the realistic BC coating morphology reasonably well in this case, which is consistent with the observed strong structure compaction during aging. We find that the absorption and scattering properties of fresh BC aggregates vary by up to 60 % due to uncertainty in the BC refractive index, which, however, is a factor of two smaller in the case of coated BC particles. Sensitivity analyses on the BC morphology show that the optical properties of fresh BC aggregates are more sensitive to fractal dimension than primary spherule size. The absorption and scattering cross sections of coated BC particles vary by more than a factor of two due to different coating structures. We find an increase of 20–250 % in absorption and a factor of 3–15 in scattering during aging, significantly depending on coating morphology and aging stages. Applying the aging model to CalNex 2010 field measurements, we show that the resulting BC

  8. Modelled Black Carbon Radiative Forcing and Atmospheric Lifetime in AeroCom Phase II Constrained by Aircraft Observations

    SciTech Connect (OSTI)

    Samset, B. H.; Myhre, G.; Herber, Andreas; Kondo, Yutaka; Li, Shao-Meng; Moteki, N.; Koike, Makoto; Oshima, N.; Schwarz, Joshua P.; Balkanski, Y.; Bauer, S.; Bellouin, N.; Berntsen, T.; Bian, Huisheng; Chin, M.; Diehl, Thomas; Easter, Richard C.; Ghan, Steven J.; Iversen, T.; Kirkevag, A.; Lamarque, Jean-Francois; Lin, Guang; Liu, Xiaohong; Penner, Joyce E.; Schulz, M.; Seland, O.; Skeie, R. B.; Stier, P.; Takemura, T.; Tsigaridis, Kostas; Zhang, Kai

    2014-11-27

    Black carbon (BC) aerosols absorb solar radiation, and are generally held to exacerbate global warming through exerting a positive radiative forcing1. However, the total contribution of BC to the ongoing changes in global climate is presently under debate2-8. Both anthropogenic BC emissions and the resulting spatial and temporal distribution of BC concentration are highly uncertain2,9. In particular, long range transport and processes affecting BC atmospheric lifetime are poorly understood, leading to large estimated uncertainty in BC concentration at high altitudes and far from emission sources10. These uncertainties limit our ability to quantify both the historical, present and future anthropogenic climate impact of BC. Here we compare vertical profiles of BC concentration from four recent aircraft measurement campaigns with 13 state of the art aerosol models, and show that recent assessments may have overestimated present day BC radiative forcing. Further, an atmospheric lifetime of BC of less than 5 days is shown to be essential for reproducing observations in transport dominated remote regions. Adjusting model results to measurements in remote regions, and at high altitudes, leads to a 25% reduction in the multi-model median direct BC forcing from fossil fuel and biofuel burning over the industrial era.

  9. Evaluation of Preindustrial to Present-day Black Carbon and its Albedo Forcing from Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP)

    SciTech Connect (OSTI)

    Lee, Y. H.; Lamarque, J.-F.; Flanner, M. G.; Jiao, C.; Shindell, Drew; Berntsen, T.; Bisiauxs, M.; Cao, J.; Collins, W. J.; Curran, M.; Edwards, R.; Faluvegi, G.; Ghan, Steven J.; Horowitz, L.; McConnell, J.R.; Ming, J.; Myhre, G.; Nagashima, T.; Naik, Vaishali; Rumbold, S.; Skeie, R. B.; Sudo, K.; Takemura, T.; Thevenon, F.; Xu, B.; Yoon, Jin-Ho

    2013-03-05

    As a part of the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP), we evaluate the historical black carbon (BC) aerosols simulated by 8 ACCMIP models against the observations including 12 ice core records, a long-term surface mass concentrations and recent Arctic BC snowpack measurements. We also estimate BC albedo forcing by performing additional simulations using the NCAR Community Land and Sea-Ice model 4 with prescribed meteorology from 1996-2000, which includes the SNICAR BC-snow model. We evaluated the vertical profile of BC snow concentrations from these offline simulations to using recent BC snowpack measurements. Despite using the same BC emissions, global BC burden differs by approximately a factor of 3 among models due to the differences in aerosol removal parameterizations and simulated meteorology among models; 34 Gg to 103 Gg in 1850 and 82 Gg to 315 Gg in 2000. However,models agree well on 2.5~3 times increase in the global BC burden from preindustrial to present-day, which matches with the 2.5 times increase in BC emissions. We find a large model diversity at both NH and SH high latitude regions for BC burden and at SH high latitude regions for deposition fluxes. The ACCMIP simulations match the observed BC mass concentrations well in Europe and North America except at Jungfrauch and Ispra. However, the models fail to capture the Arctic BC seasonality due tosevere underestimations during winter and spring. Compared to recent snowpack measurements, the simulated vertically resolved BC snow concentrations are, on average, within a factor of 2-3 of observations except for Greenland and Arctic Ocean. However, model and observation differ widely due to missing interannual variations in emissions and possibly due to the choice of the prescribed meteorology period (i.e., 1996-2000).

  10. Quantification of black carbon mixing state from traffic: Implications for aerosol optical properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Willis, Megan D.; Healy, Robert M.; Riemer, Nicole; West, Matthew; Wang, Jon M.; Jeong, Cheol -Heon; Wenger, John C.; Evans, Greg J.; Abbatt, Jonathan P. D.; Lee, Alex K. Y.

    2016-04-14

    The climatic impacts of black carbon (BC) aerosol, an important absorber of solar radiation in the atmosphere, remain poorly constrained and are intimately related to its particle-scale physical and chemical properties. Using particle-resolved modelling informed by quantitative measurements from a soot-particle aerosol mass spectrometer, we confirm that the mixing state (the distribution of co-emitted aerosol amongst fresh BC-containing particles) at the time of emission significantly affects BC-aerosol optical properties even after a day of atmospheric processing. Both single particle and ensemble aerosol mass spectrometry observations indicate that BC near the point of emission co-exists with hydrocarbon-like organic aerosol (HOA) inmore » two distinct particle types: HOA-rich and BC-rich particles. The average mass fraction of black carbon in HOA-rich and BC-rich particle classes was  < 0.1 and 0.8, respectively. Notably, approximately 90 % of BC mass resides in BC-rich particles. This new measurement capability provides quantitative insight into the physical and chemical nature of BC-containing particles and is used to drive a particle-resolved aerosol box model. Lastly, significant differences in calculated single scattering albedo (an increase of 0.1) arise from accurate treatment of initial particle mixing state as compared to the assumption of uniform aerosol composition at the point of BC injection into the atmosphere.« less

  11. Quantifying sources of black carbon in Western North America using observationally based analysis and an emission tagging technique in the Community Atmosphere Model

    SciTech Connect (OSTI)

    Zhang, Rudong; Wang, Hailong; Hegg, D. A.; Qian, Yun; Doherty, Sarah J.; Dang, Cheng; Ma, Po-Lun; Rasch, Philip J.; Fu, Qiang

    2015-11-18

    The Community Atmosphere Model (CAM5), equipped with a technique to tag black carbon (BC) emissions by source regions and types, has been employed to establish source-receptor relationships for atmospheric BC and its deposition to snow over Western North America. The CAM5 simulation was conducted with meteorological fields constrained by reanalysis for year 2013 when measurements of BC in both near-surface air and snow are available for model evaluation. We find that CAM5 has a significant low bias in predicted mixing ratios of BC in snow but only a small low bias in predicted atmospheric concentrations over the Northwest USA and West Canada. Even with a strong low bias in snow mixing ratios, radiative transfer calculations show that the BC-in-snow darkening effect is substantially larger than the BC dimming effect at the surface by atmospheric BC. Local sources contribute more to near-surface atmospheric BC and to deposition than distant sources, while the latter are more important in the middle and upper troposphere where wet removal is relatively weak. Fossil fuel (FF) is the dominant source type for total column BC burden over the two regions. FF is also the dominant local source type for BC column burden, deposition, and near-surface BC, while for all distant source regions combined the contribution of biomass/biofuel (BB) is larger than FF. An observationally based Positive Matrix Factorization (PMF) analysis of the snow-impurity chemistry is conducted to quantitatively evaluate the CAM5 BC source-type attribution. While CAM5 is qualitatively consistent with the PMF analysis with respect to partitioning of BC originating from BB and FF emissions, it significantly underestimates the relative contribution of BB. In addition to a possible low bias in BB emissions used in the simulation, the model is likely missing a significant source of snow darkening from local soil found in the observations.

  12. Black Carbon Concentrations and Diesel Vehicle Emission FactorsDerived from Coefficient of Haze Measurements in California:1967-2003

    SciTech Connect (OSTI)

    Kirchstetter, Thomas W.; Aguiar, Jeffery; Tonse, Shaheen; Novakov, T.

    2007-10-01

    We have derived ambient black carbon (BC) concentrations and estimated emission factors for on-road diesel vehicles from archived Coefficient of Haze (COH) data that was routinely collected beginning in 1967 at 11 locations in the San Francisco Bay Area. COH values are a measure of the attenuation of light by particles collected on a white filter, and available data indicate they are proportional to BC concentrations measured using the conventional aethalometer. Monthly averaged BC concentrations are up to five times greater in winter than summer, and, consequently, so is the population's exposure to BC. The seasonal cycle in BC concentrations is similar for all Bay Area sites, most likely due to area-wide decreased pollutant dispersion during wintertime. A strong weekly cycle is also evident, with weekend concentrations significantly lower than weekday concentrations, consistent with decreased diesel traffic volume on weekends. The weekly cycle suggests that, in the Bay Area, diesel vehicle emissions are the dominant source of BC aerosol. Despite the continuous increase in diesel fuel consumption in California, annual Bay Area average BC concentrations decreased by a factor of {approx}3 from the late 1960s to the early 2000s. Based on estimated annual BC concentrations, on-road diesel fuel consumption, and recent measurements of on-road diesel vehicle BC emissions, diesel BC emission factors decreased by an order of magnitude over the study period. Reductions in the BC emission factor reflect improved engine technology, emission controls and changes in diesel fuel composition. A new BC monitoring network is needed to continue tracking ambient BC trends because the network of COH monitors has recently been retired.

  13. Black Carbon Concentrations and Diesel Vehicle Emission Factors Derived from Coefficient of Haze Measurements in California: 1967-2003

    SciTech Connect (OSTI)

    Tast, CynthiaL; Kirchstetter, Thomas W.; Aguiar, Jeffery; Tonse, Shaheen; Novakov, T.; Fairley, David

    2007-11-09

    We have derived ambient black carbon (BC) concentrations and estimated emission factors for on-road diesel vehicles from archived Coefficient of Haze (COH) data that was routinely collected beginning in 1967 at 11 locations in the San Francisco Bay Area. COH values are a measure of the attenuation of light by particles collected on a white filter, and available data indicate they are proportional to BC concentrations measured using the conventional aethalometer. Monthly averaged BC concentrations are up to five times greater in winter than summer, and, consequently, so is the population?s exposure to BC. The seasonal cycle in BC concentrations is similar for all Bay Area sites, most likely due to area-wide decreased pollutant dispersion during wintertime. A strong weekly cycle is also evident, with weekend concentrations significantly lower than weekday concentrations, consistent with decreased diesel traffic volume on weekends. The weekly cycle suggests that, in the Bay Area, diesel vehicle emissions are the dominant source of BC aerosol. Despite the continuous increase in diesel fuel consumption in California, annual Bay Area average BC concentrations decreased by a factor of ~;;3 from the late 1960s to the early 2000s. Based on estimated annual BC concentrations, on-road diesel fuel consumption, and recent measurements of on-road diesel vehicle BC emissions, diesel BC emission factors decreased by an order of magnitude over the study period. Reductions in the BC emission factor reflect improved engine technology, emission controls and changes in diesel fuel composition. A new BC monitoring network is needed to continue tracking ambient BC trends because the network of COH monitors has recently been retired.

  14. Quantifying sources of black carbon in Western North America using observationally based analysis and an emission tagging technique in the Community Atmosphere Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, R.; Wang, H.; Hegg, D. A.; Qian, Y.; Doherty, S. J.; Dang, C.; Ma, P.-L.; Rasch, P. J.; Fu, Q.

    2015-05-04

    The Community Atmosphere Model (CAM5), equipped with a technique to tag black carbon (BC) emissions by source regions and types, has been employed to establish source-receptor relationships for atmospheric BC and its deposition to snow over Western North America. The CAM5 simulation was conducted with meteorological fields constrained by reanalysis for year 2013 when measurements of BC in both near-surface air and snow are available for model evaluation. We find that CAM5 has a significant low bias in predicted mixing ratios of BC in snow but only a small low bias in predicted atmospheric concentrations over the Northwest USA andmore » West Canada. Even with a strong low bias in snow mixing ratios, radiative transfer calculations show that the BC-in-snow darkening effect is substantially larger than the BC dimming effect at the surface by atmospheric BC. Local sources contribute more to near-surface atmospheric BC and to deposition than distant sources, while the latter are more important in the middle and upper troposphere where wet removal is relatively weak. Fossil fuel (FF) is the dominant source type for total column BC burden over the two regions. FF is also the dominant local source type for BC column burden, deposition, and near-surface BC, while for all distant source regions combined the contribution of biomass/biofuel (BB) is larger than FF. An observationally based Positive Matrix Factorization (PMF) analysis of the snow-impurity chemistry is conducted to quantitatively evaluate the CAM5 BC source-type attribution. While CAM5 is qualitatively consistent with the PMF analysis with respect to partitioning of BC originating from BB and FF emissions, it significantly underestimates the relative contribution of BB. In addition to a possible low bias in BB emissions used in the simulation, the model is likely missing a significant source of snow darkening from local soil found in the observations.« less

  15. Quantifying sources of black carbon in western North America using observationally based analysis and an emission tagging technique in the Community Atmosphere Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, R.; Wang, H.; Hegg, D. A.; Qian, Y.; Doherty, S. J.; Dang, C.; Ma, P.-L.; Rasch, P. J.; Fu, Q.

    2015-11-18

    The Community Atmosphere Model (CAM5), equipped with a technique to tag black carbon (BC) emissions by source regions and types, has been employed to establish source–receptor relationships for atmospheric BC and its deposition to snow over western North America. The CAM5 simulation was conducted with meteorological fields constrained by reanalysis for year 2013 when measurements of BC in both near-surface air and snow are available for model evaluation. We find that CAM5 has a significant low bias in predicted mixing ratios of BC in snow but only a small low bias in predicted atmospheric concentrations over northwestern USA and westernmore » Canada. Even with a strong low bias in snow mixing ratios, radiative transfer calculations show that the BC-in-snow darkening effect is substantially larger than the BC dimming effect at the surface by atmospheric BC. Local sources contribute more to near-surface atmospheric BC and to deposition than distant sources, while the latter are more important in the middle and upper troposphere where wet removal is relatively weak. Fossil fuel (FF) is the dominant source type for total column BC burden over the two regions. FF is also the dominant local source type for BC column burden, deposition, and near-surface BC, while for all distant source regions combined the contribution of biomass/biofuel (BB) is larger than FF. An observationally based positive matrix factorization (PMF) analysis of the snow-impurity chemistry is conducted to quantitatively evaluate the CAM5 BC source-type attribution. While CAM5 is qualitatively consistent with the PMF analysis with respect to partitioning of BC originating from BB and FF emissions, it significantly underestimates the relative contribution of BB. In addition to a possible low bias in BB emissions used in the simulation, the model is likely missing a significant source of snow darkening from local soil found in the observations.« less

  16. Variation of the radiative properties during black carbon aging: theoretical and experimental intercomparison

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, C.; Liou, K.-N.; Takano, Y.; Zhang, R.; Levy Zamora, M.; Yang, P.; Li, Q.; Leung, L. R.

    2015-10-28

    A theoretical black carbon (BC) aging model is developed to account for three typical evolution stages, namely, freshly emitted aggregates, BC coated by soluble material, and BC particles undergoing further hygroscopic growth. The geometric-optics surface-wave (GOS) approach is employed to compute the BC single-scattering properties at each aging stage, which are subsequently compared with laboratory measurements. Theoretical calculations are consistent with measurements in extinction and absorption cross sections for fresh BC aggregates with different BC sizes (i.e., mobility diameters of 155, 245, and 320 nm), with differences of ≤ 25 %. The measured optical cross sections for BC coated bymore » sulfuric acid and for that undergoing further hygroscopic growth are generally captured (differences < 30 %) by theoretical calculations using a concentric core-shell structure, with an overestimate in extinction and absorption of the smallest BC size and an underestimate in scattering of the largest BC size. We find that the absorption and scattering cross sections of fresh BC aggregates vary by 20–40 and 50–65 %, respectively, due to the use of upper (1.95–0.79i) and lower (1.75–0.63i) bounds of BC refractive index, while the variations are < 20 % in absorption and < 50 % in scattering in the case of coated BC particles. Sensitivity analyses of the BC morphology show that the optical properties of fresh BC aggregates are more sensitive to fractal dimension than primary spherule size. The absorption and scattering cross sections of coated BC particles vary by more than a factor of 2 due to different coating structures. We find an increase of 20–250 % in absorption and a factor of 3–15 in scattering during aging, significantly depending on coating morphology and aging stages. This study suggests that an accurate estimate of BC radiative effects requires the incorporation of a dynamic BC aging process that accounts for realistic coating structures in

  17. Variation of Radiative Properties During Black Carbon Aging. Theoretical and Experimental Intercomparison

    SciTech Connect (OSTI)

    He, Cenlin; Liou, K. N.; Takano, Y.; Zhang, Renyi; Zamora, Misty L.; Yang, Ping; Li, Qinbin; Leung, Lai-Yung R.

    2015-10-28

    A theoretical model is developed to account for black carbon (BC) aging during three major evolution stages, i.e., freshly emitted aggregates, coated particles by soluble materials, and those after further hygroscopic growth. The geometric-optics surface-wave approach is employed to compute BC single-scattering properties at each stage, which are compared with laboratory measurements. Theoretical predictions using input parameters determined from experiments are consistent with measurements in extinction and scattering cross sections for coated BC (within 30 20%) and absorption enhancement from coating (within 15%). The calculated scattering cross sections of fresh BC aggregates are larger than those experimentally measured, because of uncertainties in measurements and calculations. We apply the aging model to compute BC direct radiative forcing (DRF) over the LA Basin using the CalNex 2010 field measurements. Our results demonstrate that accounting for the interactive radiative properties during BC aging is essential in obtaining reliable DRF estimates within a regional context.

  18. Characterization of Black Carbon Mixing State

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sedlacek, Arthur; S, Satheesh; Springston, Stephen

    2013-11-06

    This measurement characterizes the types of BC emissions that result in nearsurface BC containing particles in a region that is dominated by biomass and open pit/stove cooking. Specifically, examine three primary BC emission sources: (i) urban setting (e.g., fossil fuel emissions); and (ii) biomass burning. Source (i) are captured at the Indian Institute of Science (IISc) in Bangalore. Biomass emissions (ii) contains a series of 12 day measurement excursions to the rural area surrounding Bangalore.

  19. Municipalities and Renewable Energy Opportunities | Open Energy...

    Open Energy Info (EERE)

    Municipalities and Renewable Energy Opportunities Jump to: navigation, search BUILDING COMMUNITIES WITH RENEWABLE ENERGY --Rsiegent 20:06, 20 January 2010 (UTC) BC communities and...

  20. EM Contractor List.xls

    Office of Environmental Management (EM)

    Vrain Facility Improvements Project Idaho National Laboratory CD3A Sandia Corporation Lockheed Martin 001035 ID-0030B.C4 Accelerated Retrieval Project IX Idaho National Laboratory ...

  1. WS-J 14 Update Worksheet(20April14).xlsx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Modification 350, Attachment 4 HANFORD WASTE SITE ASSIGNMENT LIST Site Code Site Names Designated Area Assigned Contractor 100-B-1 100-B-1; Laydown Yard; Surface Chemical and Solid Waste Dumping Area 100B WCH 100-B-10 100-B-10; 107-B Basin Leak and Warm Springs 100B WCH 100-B-11 100-B-11; 115-B Tank; 115-B/C Caisson Site; 115-B/C Caisson Valve Pit; 115-BC Drywell; 115-BC Sump 100B WCH 100-B-12 100-B-12; Filter Box Radiological Materials Area (RMA) 100B WCH 100-B-14 100-B-14; 100-B Area Process

  2. Inflow/outflow boundary conditions for particle-based blood flow...

    Office of Scientific and Technical Information (OSTI)

    WA (United States) Univ. of Lugano, Lugano (Switzerland); Swiss Institute of Bioinformatics, Lausanne (Switzerland) Univ. of British Columbia, Vancouver, BC (Canada) ...

  3. The microscopic structure of charge density waves in underdoped...

    Office of Scientific and Technical Information (OSTI)

    of Liverpool, Liverpool (United Kingdom) Univ. of British Columbia, Vancouver, BC (Canada) Technical Univ. of Denmark, Lyngby (Denmark) Deutsches Elektronen-Synchrotron (DESY), ...

  4. Gravitational Instability of a Nonrotating Galaxy (Conference...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Conference: Invited talk at Particle Accelerator Conference (PAC 09), Vancouver, BC, Canada, 4-8 May 2009 Research Org: Stanford Linear Accelerator Center (SLAC) ...

  5. Supplement Analyses (SA) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis System Operation Review EIS, Bonneville Power Administration, and B.C. Hydro and Power Authority, British Columbia, Canada June 19, 2002 EIS-0265-SA-83:...

  6. Fact Sheet Fact Sheet Fact Sheet Fact Sheet Fact Sheet Fact Sheet

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    negotiation of operational agreements that provide mutual benefits to the Bonneville Power Administration and BC Hydro. BPA is seeking to negotiate a non-Treaty storage...

  7. Quantifying sources, transport, deposition, and radiative forcing of black carbon over the Himalayas and Tibetan Plateau

    SciTech Connect (OSTI)

    Zhang, Rudong; Wang, Hailong; Qian, Yun; Rasch, Philip J.; Easter, Richard C.; Ma, Po-Lun; Singh, Balwinder; Huang, Jianping; Fu, Qiang

    2015-01-01

    Black carbon (BC)particles over the Himalayas and Tibetan Plateau (HTP), both airborne and those deposited on snow, have been shown to affect snowmelt and glacier retreat. Since BC over the HTP may originate from a variety of geographical regions and emission sectors, it is essential to quantify the source-receptor relationships of BC in order to understand the contributions of natural and anthropogenic emissions and provide guidance for potential mitigation actions. In this study, we use the Community Atmosphere Model version 5 (CAM5) with a newly developed source tagging technique, nudged towards the MERRA meteorological reanalysis, to characterize the fate of BC particles emitted from various geographical regions and sectors. Evaluated against observations over the HTP and surrounding regions, the model simulation shows a good agreement in the seasonal variation of the near-surface airborne BC concentrations, providing confidence to use this modeling framework for characterizing BC source- receptor relationships. Our analysis shows that the relative contributions from different geographical regions and source sectors depend on seasons and the locations in the HTP. The largest contribution to annual mean BC burden and surface deposition in the entire HTP region is from biofuel and biomass (BB) emissions in South Asia, followed by fossil fuel (FF) emissions from South Asia, then FF from East Asia. The same roles hold for all the seasonal means except for the summer when East Asia FF becomes more important. For finer receptor regions of interest, South Asia BB and FF have the largest impact on BC in Himalayas and Central Tibetan Plateau, while East Asia FF and BB contribute the most to Northeast Plateau in all seasons and Southeast Plateau in the summer. Central Asia and Middle East FF emissions have relatively more important contributions to BC reaching Northwest Plateau, especially in the summer. Although the HTP local emissions only contribute about 10% of BC in

  8. Dr. David Snyder, Ph.D. Archaeology Reviews Manager Ohio Historic...

    Office of Environmental Management (EM)

    ... certain infrastructure elements), and proposed property ... BC, though these are quite rare and few have been studied. ... Why people first decided to heap earth over some of their ...

  9. DOE/SC-ARM-15-032 ARM-ACME V: ARM Airborne Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Airborne Carbon Measurements Project BC black carbon CARVE NASA Carbon in Arctic ... observations to regional scales, but focused on Alaska as a whole (Figure 2 and Figure 3). ...

  10. Fuel Tables.indd

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    F30: Total Energy Consumption, Price, and Expenditure Estimates, 2014 State Consumption Prices Expenditures a Residential b Commercial b Industrial b,c Transportation Total c ...

  11. Photo Gallery - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    All Galleries 284 East Explosive Demolition Settlers B Reactor 100DX Groundwater Treatment ... Ines Triay Visit August 2010 B Reactor 2011 BC Control Area Remediation Blue ...

  12. my title

    Office of Scientific and Technical Information (OSTI)

    Gschneidner, Jr.bc a School of Materials Science and Engineering, Zhejiang University, ... for various Mn-based compounds, e.g., direct exchange, double exchange, super ...

  13. Section J.14 Changes.xlsx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Modification 489 HANFORD WASTE SITE ASSIGNMENT LIST Site Code Site Names Designated Area Assigned Contractor 100-B-1 100-B-1; Laydown Yard; Surface Chemical and Solid Waste Dumping Area 100B WCH 100-B-10 100-B-10; 107-B Basin Leak and Warm Springs 100B WCH 100-B-11 100-B-11; 115-B Tank; 115-B/C Caisson Site; 115-B/C Caisson Valve Pit; 115-BC Drywell; 115-BC Sump 100B WCH 100-B-12 100-B-12; Filter Box Radiological Materials Area (RMA) 100B WCH 100-B-14 100-B-14; 100-B Area Process and Sanitary

  14. Emittance exchange results (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Conference: Presented at Particle Accelerator Conference (PAC 09), Vancouver, BC, Canada, 4-8 May 2009 Research Org: Fermi National Accelerator Laboratory...

  15. ARM - Publications: Science Team Meeting Documents: In-Situ Measuremen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbonaceous species (BC and OC) are responsible for most of the absorption associated with aerosol particles. The amount of radiant energy an aerosol absorbs has profound effects ...

  16. Bonneville Power Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    agreement (Agreement) between the BC Hydro and Power uthority (BCH) and the Bonneville Power Administration (BP A), jointly the Parties, which BA for accounting purposes is...

  17. Microsoft PowerPoint - Recovery Fact Sheet rev4.ppt [Read-Only...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    under current regulatory documents and current prime contracts, allowing work to begin contaminants, remediate soil contamination in in the 100 BC Areas, expandimprove...

  18. Toward a Minimal Representation of Aerosols in Climate Models...

    Office of Scientific and Technical Information (OSTI)

    and external mixing between aerosol components, treating numerous complicated aerosol ... black carbon (BC) with other aerosol components, merging of the MAM7 fine dust and fine ...

  19. Using an Explicit Emission Tagging Method in Global Modeling of Source-Receptor Relationships for Black Carbon in the Arctic: Variations, Sources and Transport Pathways

    SciTech Connect (OSTI)

    Wang, Hailong; Rasch, Philip J.; Easter, Richard C.; Singh, Balwinder; Zhang, Rudong; Ma, Po-Lun; Qian, Yun; Ghan, Steven J.; Beagley, Nathaniel

    2014-11-27

    We introduce an explicit emission tagging technique in the Community Atmosphere Model to quantify source-region-resolved characteristics of black carbon (BC), focusing on the Arctic. Explicit tagging of BC source regions without perturbing the emissions makes it straightforward to establish source-receptor relationships and transport pathways, providing a physically consistent and computationally efficient approach to produce a detailed characterization of the destiny of regional BC emissions and the potential for mitigation actions. Our analysis shows that the contributions of major source regions to the global BC burden are not proportional to the respective emissions due to strong region-dependent removal rates and lifetimes, while the contributions to BC direct radiative forcing show a near-linear dependence on their respective contributions to the burden. Distant sources contribute to BC in remote regions mostly in the mid- and upper troposphere, having much less impact on lower-level concentrations (and deposition) than on burden. Arctic BC concentrations, deposition and source contributions all have strong seasonal variations. Eastern Asia contributes the most to the wintertime Arctic burden. Northern Europe emissions are more important to both surface concentration and deposition in winter than in summer. The largest contribution to Arctic BC in the summer is from Northern Asia. Although local emissions contribute less than 10% to the annual mean BC burden and deposition within the Arctic, the per-emission efficiency is much higher than for major non-Arctic sources. The interannual variability (1996-2005) due to meteorology is small in annual mean BC burden and radiative forcing but is significant in yearly seasonal means over the Arctic. When a slow aging treatment of BC is introduced, the increase of BC lifetime and burden is source-dependent. Global BC forcing-per-burden efficiency also increases primarily due to changes in BC vertical distributions. The

  20. Carbonaceous aerosols recorded in a southeastern Tibetan glacier: analysis of temporal variations and model estimates of sources and radiative forcing

    SciTech Connect (OSTI)

    Wang, Mo; Xu, B.; Cao, J.; Tie, X.; Wang, Hailong; Zhang, Rudong; Qian, Yun; Rasch, Philip J.; Zhao, Shuyu; Wu, Guangjian; Zhao, Huabiao; Joswiak, Daniel R.; Li, Jiule; Xie, Ying

    2015-02-02

    High temporal resolution measurements of black carbon (BC) and organic carbon (OC) covering the time period of 1956–2006 in an ice core over the southeastern Tibetan Plateau show a distinct seasonal dependence of BC and OC with higher respective concentrations but a lower OC / BC ratio in the non-monsoon season than during the summer monsoon. We use a global aerosol-climate model, in which BC emitted from different source regions can be explicitly tracked, to quantify BC source–receptor relationships between four Asian source regions and the southeastern Tibetan Plateau as a receptor. The model results show that South Asia has the largest contribution to the present-day (1996–2005) mean BC deposition at the ice-core drilling site during the non-monsoon season (October to May) (81%) and all year round (74%), followed by East Asia (14% to the non-monsoon mean and 21% to the annual mean). The ice-core record also indicates stable and relatively low BC and OC deposition fluxes from the late 1950s to 1980, followed by an overall increase to recent years. This trend is consistent with the BC and OC emission inventories and the fuel consumption of South Asia (as the primary contributor to annual mean BC deposition). Moreover, the increasing trend of the OC / BC ratio since the early 1990s indicates a growing contribution of coal combustion and/or biomass burning to the emissions. The estimated radiative forcing induced by BC and OC impurities in snow has increased since 1980, suggesting an increasing potential influence of carbonaceous aerosols on the Tibetan glacier melting and the availability of water resources in the surrounding regions. Our study indicates that more attention to OC is merited because of its non-negligible light absorption and the recent rapid increases evident in the ice-core record.

  1. Carbonaceous aerosols recorded in a southeastern Tibetan glacier: analysis of temporal variations and model estimates of sources and radiative forcing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Mo; Xu, B.; Cao, J.; Tie, X.; Wang, Hailong; Zhang, Rudong; Qian, Yun; Rasch, Philip J.; Zhao, Shuyu; Wu, Guangjian; et al

    2015-02-02

    High temporal resolution measurements of black carbon (BC) and organic carbon (OC) covering the time period of 1956–2006 in an ice core over the southeastern Tibetan Plateau show a distinct seasonal dependence of BC and OC with higher respective concentrations but a lower OC / BC ratio in the non-monsoon season than during the summer monsoon. We use a global aerosol-climate model, in which BC emitted from different source regions can be explicitly tracked, to quantify BC source–receptor relationships between four Asian source regions and the southeastern Tibetan Plateau as a receptor. The model results show that South Asia hasmore » the largest contribution to the present-day (1996–2005) mean BC deposition at the ice-core drilling site during the non-monsoon season (October to May) (81%) and all year round (74%), followed by East Asia (14% to the non-monsoon mean and 21% to the annual mean). The ice-core record also indicates stable and relatively low BC and OC deposition fluxes from the late 1950s to 1980, followed by an overall increase to recent years. This trend is consistent with the BC and OC emission inventories and the fuel consumption of South Asia (as the primary contributor to annual mean BC deposition). Moreover, the increasing trend of the OC / BC ratio since the early 1990s indicates a growing contribution of coal combustion and/or biomass burning to the emissions. The estimated radiative forcing induced by BC and OC impurities in snow has increased since 1980, suggesting an increasing potential influence of carbonaceous aerosols on the Tibetan glacier melting and the availability of water resources in the surrounding regions. Our study indicates that more attention to OC is merited because of its non-negligible light absorption and the recent rapid increases evident in the ice-core record.« less

  2. Enhanced light absorption by mixed source black and brown carbon particles in UK winter

    SciTech Connect (OSTI)

    Liu, Shang; Aiken, Allison C.; Gorkowski, Kyle; Dubey, Manvendra K.; Cappa, Christopher D.; Williams, Leah R.; Herndon, Scott C.; Massoli, Paola; Fortner, Edward C.; Chhabra, Puneet S.; Brooks, William A.; Onasch, Timothy B.; Jayne, John T.; Worsnop, Douglas R.; China, Swarup; Sharma, Noopur; Mazzoleni, Claudio; Xu, Lu; Ng, Nga L.; Liu, Dantong; Allan, James D.; Lee, James D.; Fleming, Zoë L.; Mohr, Claudia; Zotter, Peter; Szidat, Sönke; Prévôt, André S. H.

    2015-09-30

    We report that black carbon (BC) and light-absorbing organic carbon (brown carbon, BrC) play key roles in warming the atmosphere, but the magnitude of their effects remains highly uncertain. Theoretical modelling and laboratory experiments demonstrate that coatings on BC can enhance BC’s light absorption, therefore many climate models simply assume enhanced BC absorption by a factor of ~1.5. However, recent field observations show negligible absorption enhancement, implying models may overestimate BC’s warming. Here we report direct evidence of substantial field-measured BC absorption enhancement, with the magnitude strongly depending on BC coating amount. Increases in BC coating result from a combination of changing sources and photochemical aging processes. When the influence of BrC is accounted for, observationally constrained model calculations of the BC absorption enhancement can be reconciled with the observations. In conclusion, we find that the influence of coatings on BC absorption should be treated as a source and regionally specific parameter in climate models.

  3. Black carbon aerosols and the third polar ice cap

    SciTech Connect (OSTI)

    Menon, Surabi; Koch, Dorothy; Beig, Gufran; Sahu, Saroj; Fasullo, John; Orlikowski, Daniel

    2010-04-15

    Recent thinning of glaciers over the Himalayas (sometimes referred to as the third polar region) have raised concern on future water supplies since these glaciers supply water to large river systems that support millions of people inhabiting the surrounding areas. Black carbon (BC) aerosols, released from incomplete combustion, have been increasingly implicated as causing large changes in the hydrology and radiative forcing over Asia and its deposition on snow is thought to increase snow melt. In India BC emissions from biofuel combustion is highly prevalent and compared to other regions, BC aerosol amounts are high. Here, we quantify the impact of BC aerosols on snow cover and precipitation from 1990 to 2010 over the Indian subcontinental region using two different BC emission inventories. New estimates indicate that Indian BC emissions from coal and biofuel are large and transport is expected to expand rapidly in coming years. We show that over the Himalayas, from 1990 to 2000, simulated snow/ice cover decreases by {approx}0.9% due to aerosols. The contribution of the enhanced Indian BC to this decline is {approx}36%, similar to that simulated for 2000 to 2010. Spatial patterns of modeled changes in snow cover and precipitation are similar to observations (from 1990 to 2000), and are mainly obtained with the newer BC estimates.

  4. Supporting technology for enhanced oil recovery for thermal processes

    SciTech Connect (OSTI)

    Reid, T.B.; Bolivar, J.

    1997-12-01

    This report contains the results of efforts under the six tasks of the Ninth Amendment and Extension of Annex IV, Enhanced Oil Recovery Thermal Processes of the Venezuela/USA Agreement. The report is presented in sections (for each of the 6 tasks) and each section contains one or more reports prepared by various individuals or groups describing the results of efforts under each of the tasks. A statement of each task, taken from the agreement, is presented on the first page of each section. The tasks are numbered 62 through 67. The first, second, third, fourth fifth, sixth, seventh, eighth, and ninth reports on Annex IV, [Venezuela MEM/USA-DOE Fossil Energy Report IV-1, IV-2, IV-3, IV-4, IV-5, IV-6, IV-7, and IV-8 (DOE/BETC/SP-83/15, DOE/BC-84/6/SP, DOE/BC-86/2/SP, DOE/BC-87/2/SP, DOE/BC-90/1/SP, DOE/BC-90/1/SP) (DOE/BC-92/1/SP, DOE/BC-93/3/SP, and DOE/BC-95/3/SP)] contain the results from the first 61 tasks. Those reports are dated April 1983, August 1984, March 1986, July 1987, November 1988, October 1991, February 1993, and March 1995 respectively.

  5. Supporting Technology for Enhanced Oil Recovery-EOR Thermal Processes Report IV-12

    SciTech Connect (OSTI)

    Izequeido, Alexandor

    2001-04-01

    This report contains the results of efforts under the six tasks of the Ninth Amendment and Extension of Annex IV, Enhanced Oil Recovery Thermal Processes of the Venezuela/USA Agreement. The report is presented in sections (for each of the 6 tasks) and each section contains one or more reports prepared by various individuals or groups describing the results of efforts under each of the tasks. A statement of each task, taken from the agreement, is presented on the first page of each section. The tasks are numbered 62 through 67. The first, second, third, fourth, fifth, sixth, seventh, eight, and ninth reports on Annex IV, [Venezuela MEM/USA-DOE Fossil Energy Report IV-1, IV-2, IV-3, IV-4, IV-5, IV-6, IV-7, and IV-8 (DOE/BETC/SP-83/15, DOE/BC-84/6/SP, DOE/BC-86/2/SP, DOE/BC-87/2/SP, DOE/BC-89/1/SP, DOE/BC-90/1/SP) DOE/BC-92/1/SP, DOE/BC-93/3/SP, and DOE/BC-95/3/SP] contain the results from the first 61 tasks. Those reports are dated April 1983, August 1984, March 1986, July 1! 987, November 1988, December 1989, October 1991, February 1993, and March 1995 respectively.

  6. Black Carbon Radiative Forcing over the Tibetan Plateau

    SciTech Connect (OSTI)

    He, Cenlin; Li, Qinbin; Liou, K. N.; Takano, Y.; Gu, Yu; Qi, L.; Mao, Yuhao; Leung, Lai-Yung R.

    2014-11-28

    We estimate the snow albedo forcing and direct radiative forcing (DRF) of black carbon (BC) in the Tibetan Plateau using a global chemical transport model in conjunction with a stochastic snow model and a radiative transfer model. Our best estimate of the annual BC snow albedo forcing in the Plateau is 2.9 W m-2 (uncertainty: 1.55.0 W m-226 ). We find that BC-snow internal mixing increases the albedo forcing by 40-60% compared with external mixing and coated BC increases the forcing by 30-50% compared with uncoated BC, whereas Koch snowflakes reduce the forcing by 20-40% relative to spherical snow grains. Our best estimate of the annual BC DRF at the top of the atmosphere is 2.3 W m-2 (uncertainty: 0.74.3 W m-230 ) in the Plateau after scaling the modeled BC absorption optical depth to Aerosol Robotic Network (AERONET) observations. The BC forcings are attributed to emissions from different regions.

  7. Enhanced light absorption by mixed source black and brown carbon particles in UK winter

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Shang; Aiken, Allison C.; Gorkowski, Kyle; Dubey, Manvendra K.; Cappa, Christopher D.; Williams, Leah R.; Herndon, Scott C.; Massoli, Paola; Fortner, Edward C.; Chhabra, Puneet S.; et al

    2015-09-30

    We report that black carbon (BC) and light-absorbing organic carbon (brown carbon, BrC) play key roles in warming the atmosphere, but the magnitude of their effects remains highly uncertain. Theoretical modelling and laboratory experiments demonstrate that coatings on BC can enhance BC’s light absorption, therefore many climate models simply assume enhanced BC absorption by a factor of ~1.5. However, recent field observations show negligible absorption enhancement, implying models may overestimate BC’s warming. Here we report direct evidence of substantial field-measured BC absorption enhancement, with the magnitude strongly depending on BC coating amount. Increases in BC coating result from a combinationmore » of changing sources and photochemical aging processes. When the influence of BrC is accounted for, observationally constrained model calculations of the BC absorption enhancement can be reconciled with the observations. In conclusion, we find that the influence of coatings on BC absorption should be treated as a source and regionally specific parameter in climate models.« less

  8. Black carbon emissions in the United Kingdom during the past four decades: An empirical analysis

    SciTech Connect (OSTI)

    Novakov, T.; Hansen, J.E.

    2004-04-22

    We use data from a unique 40-year record of 150 urban and rural stations in the ''Black Smoke and SO2 Network'' in Great Britain to infer information about sources of atmospheric black carbon (BC). The data show a rapid decline of ambient atmospheric BC between 1962 and the early 1990s that exceeds the decline in official estimates of BC emissions based only on amount of fuel use and mostly fixed emission factors. This provides empirical confirmation of the existence and large impact of a time-dependent ''technology factor'' that must multiply the rate of fossil fuel use. Current ambient BC amounts in Great Britain comparable to those in western and central Europe, with diesel engines being the principal present source. From comparison of BC and SO2 data we infer that current BC emission inventories understate true emissions in the U.K. by about a factor of two. The results imply that there is the potential for improved technology to achieve large reduction of global ambient BC. There is a need for comparable monitoring of BC in other countries.

  9. Open Boundary Conditions for Dissipative MHD

    SciTech Connect (OSTI)

    Meier, E T

    2011-11-10

    In modeling magnetic confinement, astrophysics, and plasma propulsion, representing the entire physical domain is often difficult or impossible, and artificial, or 'open' boundaries are appropriate. A novel open boundary condition (BC) for dissipative MHD, called Lacuna-based open BC (LOBC), is presented. LOBC, based on the idea of lacuna-based truncation originally presented by V.S. Ryaben'kii and S.V. Tsynkov, provide truncation with low numerical noise and minimal reflections. For hyperbolic systems, characteristic-based BC (CBC) exist for separating the solution into outgoing and incoming parts. In the hyperbolic-parabolic dissipative MHD system, such separation is not possible, and CBC are numerically unstable. LOBC are applied in dissipative MHD test problems including a translating FRC, and coaxial-electrode plasma acceleration. Solution quality is compared to solutions using CBC and zero-normal derivative BC. LOBC are a promising new open BC option for dissipative MHD.

  10. Decadal growth of black carbon emissions in India - article no. L02807

    SciTech Connect (OSTI)

    Sahu, S.K.; Beig, G.; Sharma, C.

    2008-01-15

    A Geographical Information System (GIS) based methodology has been used to construct the black carbon (BC) emission inventory for the Indian geographical region. The distribution of emissions from a broader level to a spatial resolution of 1{sup o} x 1{sup o} grid has been carried out by considering micro level details and activity data of fossil fuels and bio-fuels. Our calculated total BC emissions were 1343.78 Gg and 835.50 Gg for the base years 2001 and 1991 respectively with a decadal growth of around 61%, which is highly significant. The district level analysis shows a diverse spatial distribution with the top 10% emitting districts contributing nearly 50% of total BC emission. Coal contributes more than 50% of total BC emission. All the metropolitan cities show high BC emissions due to high population density giving rise to high vehicular emissions and more demand of energy.

  11. RCC Contract No. DE-AC06-05RL14655 TABLE B.2 SCHEDULE OF QUANTITIES AND TARGET COST

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contract No. DE-AC06-05RL14655 TABLE B.2 SCHEDULE OF QUANTITIES AND TARGET COST Section B 593 CLIN 1 CLIN 2 CLIN 3 CLIN 4 100 Area 100-B/C Area FR - 100 B/C Area Design 1.03.01.04.01 Fld. Rem.-100 B/C Area Design 1 LS $702,783 $702,783 Confirmatory Sampling Sites 1.03.01.01.03 Fld. Rem.-Conf Sampling Sites-100 B/C 10 EA $838,517 $838,517 Liquid Waste Site Remediation 1.03.01.02.04 Fld. Rem.-Liquid Waste Sites-100-BC-1 0 TONS $322,870 $322,870 Waste Site Remediation 1.03.01.02.05 / 1.03.01.03.05

  12. Sources of black carbon aerosols in South Asia and surrounding regions during the Integrated Campaign for Aerosols, Gases and Radiation Budget (ICARB)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumar, R.; Barth, M. C.; Nair, V. S.; Pfister, G. G.; Suresh Babu, S.; Satheesh, S. K.; Moorthy, K. Krishna; Carmichael, G. R.; Lu, Z.; Streets, D. G.

    2015-05-19

    This study examines differences in the surface black carbon (BC) aerosol loading between the Bay of Bengal (BoB) and the Arabian Sea (AS) and identifies dominant sources of BC in South Asia and surrounding regions during March–May 2006 (Integrated Campaign for Aerosols, Gases and Radiation Budget, ICARB) period. A total of 13 BC tracers are introduced in the Weather Research and Forecasting Model coupled with Chemistry to address these objectives. The model reproduced the temporal and spatial variability of BC distribution observed over the AS and the BoB during the ICARB ship cruise and captured spatial variability at the inlandmore » sites. In general, the model underestimates the observed BC mass concentrations. However, the model–observation discrepancy in this study is smaller compared to previous studies. Model results show that ICARB measurements were fairly well representative of the AS and the BoB during the pre-monsoon season. Elevated BC mass concentrations in the BoB are due to 5 times stronger influence of anthropogenic emissions on the BoB compared to the AS. Biomass burning in Burma also affects the BoB much more strongly than the AS. Results show that anthropogenic and biomass burning emissions, respectively, accounted for 60 and 37% of the average ± standard deviation (representing spatial and temporal variability) BC mass concentration (1341 ± 2353 ng m-3) in South Asia. BC emissions from residential (61%) and industrial (23%) sectors are the major anthropogenic sources, except in the Himalayas where vehicular emissions dominate. We find that regional-scale transport of anthropogenic emissions contributes up to 25% of BC mass concentrations in western and eastern India, suggesting that surface BC mass concentrations cannot be linked directly to the local emissions in different regions of South Asia.« less

  13. Sources of black carbon aerosols in South Asia and surrounding regions during the Integrated Campaign for Aerosols, Gases and Radiation Budget (ICARB)

    SciTech Connect (OSTI)

    Kumar, R.; Barth, M. C.; Nair, V. S.; Pfister, G. G.; Suresh Babu, S.; Satheesh, S. K.; Moorthy, K. Krishna; Carmichael, G. R.; Lu, Z.; Streets, D. G.

    2015-05-19

    This study examines differences in the surface black carbon (BC) aerosol loading between the Bay of Bengal (BoB) and the Arabian Sea (AS) and identifies dominant sources of BC in South Asia and surrounding regions during March–May 2006 (Integrated Campaign for Aerosols, Gases and Radiation Budget, ICARB) period. A total of 13 BC tracers are introduced in the Weather Research and Forecasting Model coupled with Chemistry to address these objectives. The model reproduced the temporal and spatial variability of BC distribution observed over the AS and the BoB during the ICARB ship cruise and captured spatial variability at the inland sites. In general, the model underestimates the observed BC mass concentrations. However, the model–observation discrepancy in this study is smaller compared to previous studies. Model results show that ICARB measurements were fairly well representative of the AS and the BoB during the pre-monsoon season. Elevated BC mass concentrations in the BoB are due to 5 times stronger influence of anthropogenic emissions on the BoB compared to the AS. Biomass burning in Burma also affects the BoB much more strongly than the AS. Results show that anthropogenic and biomass burning emissions, respectively, accounted for 60 and 37% of the average ± standard deviation (representing spatial and temporal variability) BC mass concentration (1341 ± 2353 ng m-3) in South Asia. BC emissions from residential (61%) and industrial (23%) sectors are the major anthropogenic sources, except in the Himalayas where vehicular emissions dominate. We find that regional-scale transport of anthropogenic emissions contributes up to 25% of BC mass concentrations in western and eastern India, suggesting that surface BC mass concentrations cannot be linked directly to the local emissions in different regions of South Asia.

  14. Linearity of Climate Response to Increases in Black Carbon Aerosols

    SciTech Connect (OSTI)

    Mahajan, Salil; Evans, Katherine J.; Hack, James J.; Truesdale, John

    2013-04-19

    The impact of absorbing aerosols on global climate are not completely understood. Here, we present results of idealized experiments conducted with the Community Atmosphere Model (CAM4) coupled to a slab ocean model (CAM4-SOM) to simulate the climate response to increases in tropospheric black carbon aerosols (BC) by direct and semi-direct effects. CAM4-SOM was forced with 0, 1x, 2x, 5x and 10x an estimate of the present day concentration of BC while maintaining their estimated present day global spatial and vertical distribution. The top of the atmosphere (TOA) radiative forcing of BC in these experiments is positive (warming) and increases linearly as the BC burden increases. The total semi-direct effect for the 1x experiment is positive but becomes increasingly negative for higher BC concentrations. The global average surface temperature response is found to be a linear function of the TOA radiative forcing. The climate sensitivity to BC from these experiments is estimated to be 0.42 K $ W^{-1} m^{2}$ when the semi-direct effects are accounted for and 0.22 K $ W^{-1} m^{2}$ with only the direct effects considered. Global average precipitation decreases linearly as BC increases, with a precipitation sensitivity to atmospheric absorption of 0.4 $\\%$ $W^{-1}m^{2}$ . The hemispheric asymmetry of BC also causes an increase in southward cross-equatorial heat transport and a resulting northward shift of the inter-tropical convergence zone in the simulations at a rate of 4$^{\\circ}$N $ PW^{-1}$. Global average mid- and high-level clouds decrease, whereas the low-level clouds increase linearly with BC. The increase in marine stratocumulus cloud fraction over the south tropical Atlantic is caused by increased BC-induced diabatic heating of the free troposphere.

  15. Evaluation of Black Carbon Estimations in Global Aerosol Models

    SciTech Connect (OSTI)

    Koch, D.; Schulz, M.; Kinne, Stefan; McNaughton, C. S.; Spackman, J. R.; Balkanski, Y.; Bauer, S.; Berntsen, T.; Bond, Tami C.; Boucher, Olivier; Chin, M.; Clarke, A. D.; De Luca, N.; Dentener, F.; Diehl, T.; Dubovik, O.; Easter, Richard C.; Fahey, D. W.; Feichter, J.; Fillmore, D.; Freitag, S.; Ghan, Steven J.; Ginoux, P.; Gong, S.; Horowitz, L.; Iversen, T.; Kirkevag, A.; Klimont, Z.; Kondo, Yutaka; Krol, M.; Liu, Xiaohong; Miller, R.; Montanaro, V.; Moteki, N.; Myhre, G.; Penner, J.; Perlwitz, Ja; Pitari, G.; Reddy, S.; Sahu, L.; Sakamoto, H.; Schuster, G.; Schwarz, J. P.; Seland, O.; Stier, P.; Takegawa, Nobuyuki; Takemura, T.; Textor, C.; van Aardenne, John; Zhao, Y.

    2009-11-27

    We evaluate black carbon (BC) model predictions from the AeroCom model intercomparison project by considering the diversity among year 2000 model simulations and comparing model predictions with available measurements. These model-measurement intercomparisons include BC surface and aircraft concentrations, aerosol absorption optical depth (AAOD) from AERONET and OMI retrievals and BC column estimations based on AERONET. In regions other than Asia, most models are biased high compared to surface concentration measurements. However compared with (column) AAOD or BC burden retreivals, the models are generally biased low. The average ratio of model to retrieved AAOD is less than 0.7 in South American and 0.6 in African biomass burning regions; both of these regions lack surface concentration measurements. In Asia the average model to observed ratio is 0.6 for AAOD and 0.5 for BC surface concentrations. Compared with aircraft measurements over the Americas at latitudes between 0 and 50N, the average model is a factor of 10 larger than observed, and most models exceed the measured BC standard deviation in the mid to upper troposphere. At higher latitudes the average model to aircraft BC is 0.6 and underestimate the observed BC loading in the lower and middle troposphere associated with springtime Arctic haze. Low model bias for AAOD but overestimation of surface and upper atmospheric BC concentrations at lower latitudes suggests that most models are underestimating BC absorption and should improve estimates for refractive index, particle size, and optical effects of BC coating. Retrieval uncertainties and/or differences with model diagnostic treatment may also contribute to the model-measurement disparity. Largest AeroCom model diversity occurred in northern Eurasia and the remote Arctic, regions influenced by anthropogenic sources. Changing emissions, aging, removal, or optical properties within a single model generated a smaller change in model predictions than the

  16. Quantifying sources, transport, deposition and radiative forcing of black carbon over the Himalayas and Tibetan Plateau

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, R.; Wang, H.; Qian, Y.; Rasch, P. J.; Easter, R. C.; Ma, P. -L.; Singh, B.; Huang, J.; Fu, Q.

    2015-01-07

    Black carbon (BC) particles over the Himalayas and Tibetan Plateau (HTP), both airborne and those deposited on snow, have been shown to affect snowmelt and glacier retreat. Since BC over the HTP may originate from a variety of geographical regions and emission sectors, it is essential to quantify the source–receptor relationships of BC in order to understand the contributions of natural and anthropogenic emissions and provide guidance for potential mitigation actions. In this study, we use the Community Atmosphere Model version 5 (CAM5) with a newly developed source tagging technique, nudged towards the MERRA meteorological reanalysis, to characterize the fatemore » of BC particles emitted from various geographical regions and sectors. Evaluated against observations over the HTP and surrounding regions, the model simulation shows a good agreement in the seasonal variation of the near-surface airborne BC concentrations, providing confidence to use this modeling framework for characterizing BC source–receptor relationships. Our analysis shows that the relative contributions from different geographical regions and source sectors depend on seasons and the locations in the HTP. The largest contribution to annual mean BC burden and surface deposition in the entire HTP region is from biofuel and biomass (BB) emissions in South Asia, followed by fossil fuel (FF) emissions from South Asia, then FF from East Asia. The same roles hold for all the seasonal means except for the summer when East Asia FF becomes more important. For finer receptor regions of interest, South Asia BB and FF have the largest impact on BC in Himalayas and Central Tibetan Plateau, while East Asia FF and BB contribute the most to Northeast Plateau in all seasons and Southeast Plateau in the summer. Central Asia and Middle East FF emissions have relatively more important contributions to BC reaching Northwest Plateau, especially in the summer. Although local emissions only contribute about 10% to

  17. Quantifying sources, transport, deposition, and radiative forcing of black carbon over the Himalayas and Tibetan Plateau

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, R.; Wang, H.; Qian, Y.; Rasch, P. J.; Easter, R. C.; Ma, P. -L.; Singh, B.; Huang, J.; Fu, Q.

    2015-06-08

    Black carbon (BC) particles over the Himalayas and Tibetan Plateau (HTP), both airborne and those deposited on snow, have been shown to affect snowmelt and glacier retreat. Since BC over the HTP may originate from a variety of geographical regions and emission sectors, it is essential to quantify the source–receptor relationships of BC in order to understand the contributions of natural and anthropogenic emissions and provide guidance for potential mitigation actions. In this study, we use the Community Atmosphere Model version 5 (CAM5) with a newly developed source-tagging technique, nudged towards the MERRA meteorological reanalysis, to characterize the fate ofmore » BC particles emitted from various geographical regions and sectors. Evaluated against observations over the HTP and surrounding regions, the model simulation shows a good agreement in the seasonal variation in the near-surface airborne BC concentrations, providing confidence to use this modeling framework for characterizing BC source–receptor relationships. Our analysis shows that the relative contributions from different geographical regions and source sectors depend on season and location in the HTP. The largest contribution to annual mean BC burden and surface deposition in the entire HTP region is from biofuel and biomass (BB) emissions in South Asia, followed by fossil fuel (FF) emissions from South Asia, then FF from East Asia. The same roles hold for all the seasonal means except for the summer, when East Asia FF becomes more important. For finer receptor regions of interest, South Asia BB and FF have the largest impact on BC in the Himalayas and central Tibetan Plateau, while East Asia FF and BB contribute the most to the northeast plateau in all seasons and southeast plateau in the summer. Central Asia and Middle East FF emissions have relatively more important contributions to BC reaching the northwest plateau, especially in the summer. Although local emissions only contribute about

  18. Observed high-altitude warming and snow cover retreat over Tibet and the Himalayas enhanced by black carbon aerosols

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Y.; Ramanathan, V.; Washington, W. M.

    2015-07-10

    Himalayan mountain glaciers and the snowpack over the Tibetan Plateau provide the headwater of several major rivers in Asia. In-situ observations of snow cover fraction since the 1960s suggest that the snow pack in the region have retreated significantly, accompanied by a surface warming of 22.5 C observed over the peak altitudes (5000 m). Using a high-resolution oceanatmosphere global climate model and an observationally constrained black carbon (BC) aerosol forcing, we attribute the observed altitude dependence of the warming trends as well as the spatial pattern of reductions in snow depths and snow cover fraction to various anthropogenic factors. Atmorethe Tibetan Plateau altitudes, the increase of atmospheric CO2 concentration exerted a warming of 1.7 C, BC 1.3 C where as cooling aerosols cause about 0.7 C cooling, bringing the net simulated warming consistent with the anomalously large observed warming. We therefore conclude that BC together with CO2 has contributed to the snow retreat trends. Especially, BC increase is the major factor in the strong elevation dependence of the observed surface warming. The atmospheric warming by BC as well as its surface darkening of snow are coupled with the positive snow albedo feedbacks to account for the disproportionately large role of BC in high-elevation regions. These findings reveal that BC impact needs to be properly accounted for in future regional climate projections, in particular on high-altitude cryosphere.less

  19. Century-long Record of Black Carbon in an Ice Core from the Eastern Pamirs: Estimated Contributions from Biomass Burning

    SciTech Connect (OSTI)

    Wang, Mo; Xu, B.; Kaspari, Susan D.; Gleixner, Gerd; Schwab, Valerie; Zhao, Huabiao; Wang, Hailong; Yao, Ping

    2015-08-01

    We analyzed refractory black carbon (rBC) in an ice core spanning 1875-2000 AD from Mt. Muztagh Ata, the Eastern Pamirs, using a Single Particle Soot Photometer (SP2). Additionally a pre-existing levoglucosan record from the same ice core was used to differentiate rBC that originated from open fires, energy-related combustion of biomass, and fossil fuel combustion. Mean rBC concentrations increased four-fold since the mid-1970s and reached maximum values at the end of 1980s. The observed decrease of the rBC concentrations during the 1990s was likely driven by the economic recession of former USSR countries in Central Asia. Levoglucosan concentrations showed a similar temporal trend to rBC concentrations, exhibiting a large increase around 1980 AD followed by a decrease in the 1990s that was likely due to a decrease in energy-related biomass combustion. The time evolution of levoglucosan/rBC ratios indicated stronger emissions from open fires during the 1940s-1950s, while the increase in rBC during the 1980s-1990s was caused from an increase in energy-related combustion of biomass and fossil fuels.

  20. Measured Black Carbon Deposition on the Sierra Nevada Snow Pack and Implication for Snow Pack Retreat

    SciTech Connect (OSTI)

    Hadley, O.L.; Corrigan, C.E.; Kirchstetter, T.W.; Cliff, S.S.; Ramanathan, V.

    2010-01-12

    Modeling studies show that the darkening of snow and ice by black carbon deposition is a major factor for the rapid disappearance of arctic sea ice, mountain glaciers and snow packs. This study provides one of the first direct measurements for the efficient removal of black carbon from the atmosphere by snow and its subsequent deposition to the snow packs of California. The early melting of the snow packs in the Sierras is one of the contributing factors to the severe water problems in California. BC concentrations in falling snow were measured at two mountain locations and in rain at a coastal site. All three stations reveal large BC concentrations in precipitation, ranging from 1.7 ng/g to 12.9 ng/g. The BC concentrations in the air after the snow fall were negligible suggesting an extremely efficient removal of BC by snow. The data suggest that below cloud scavenging, rather than ice nuclei, was the dominant source of BC in the snow. A five-year comparison of BC, dust, and total fine aerosol mass concentrations at multiple sites reveals that the measurements made at the sampling sites were representative of large scale deposition in the Sierra Nevada. The relative concentration of iron and calcium in the mountain aerosol indicates that one-quarter to one-third of the BC may have been transported from Asia.

  1. A 700 year sediment record of black carbon and polycyclic aromatic hydrocarbons near the EMEP air monitoring station in Aspvreten, Sweden

    SciTech Connect (OSTI)

    Marie Elmquist; Zdenek Zencak; Oerjan Gustafsson

    2007-10-15

    In view of poor constraints on historical combustion emissions, past environmental loadings of black carbon (BC) and polycyclic aromatic hydrocarbon (PAH) were reconstructed from dated lake sediment cores collected 70 km south of Stockholm, Sweden. Compared to several dramatic variations over the recent 150 years, the preindustrial loadings were steady within {+-}50% through the entire medieval with BC fluxes of 0.071 g m{sup -2} yr{sup -1} and PAH fluxes of 6 g m{sup -2} yr{sup -1}. In the wood-burning dominated century leading up to the industrial revolution around 1850, increasing BC fluxes were leading PAH fluxes. BC fluxes reached their millennial-scale maximum around 1920, whereas PAH fluxes increased exponentially to its record maximum around 1960, 50-fold above preindustrial values. For 1920-1950, BC fluxes consistently decreased as PAH fluxes kept increasing. Coal and coke represented >50% of the Swedish energy market in the 1930s. Combined with sharply decreasing (1,7-)/(1,7{+-}2,6-dimethylphenanthrene), indicative of diminishing wood combustion, and decreasing methylphenanthrenes/phenanthrene, indicative of higher-temperature combustion (coal instead of wood), the sediment archive suggests that the relative BC/PAH emission factors thus are lower for coal than for wood combustion. For the first time, both BC and PAH fluxes decreased after 1960. This trend break is a testament to the positive effects of decreasing reliance on petroleum fuels and a number of legislative actions aimed at curbing emissions and by 1990, the loading of BC was back at preindustrial levels, whereas that of PAH were the lowest since the 1910s. However, for the most recent period (1990-2004) the BC and PAH fluxes are no longer decreasing. 55 refs., 3 figs.

  2. Efficiency Advocates’ Ex Parte Communication with DOE on June 20, 2014

    Broader source: Energy.gov [DOE]

    The attendees identified above met on June 20, 2014, to discuss DOE’s efforts on setting energy efficiency standards for manufactured housing. (Docket No. EERE-2009-BT-BC-0021).

  3. TO: FILE MEMORANDUM FR0t-k

    Office of Legacy Management (LM)

    ... "Notification of Hazardous Haste Site" forms ,for our.Elmore,,Oh,io and'luckey, Ohio plants. Very truly yours, bc: ,G. S. Blome M. 8. Powers - I .-..I .v......, - ' ..' ...

  4. MEMORANDUrl TO: FILE

    Office of Legacy Management (LM)

    rr0b.c EQUIPMENT ORE OR RAW MATL FINAL PRODUCT WASTE & RESIDUE Control 0 Health Physics Protection 0 AECMED managed operations 0 Little or None U AECMED responsible for c ...

  5. Paul Loach | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    he is working to determine how LH1, the reaction center (RC) and the bc1 complex interact in the intact membrane. Professor of Biochemistry, Molecular Biology and Cell Biology Bio...

  6. APS Beamline 6-ID-B,C

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B,C Home Recent Publications Beamline Info Optics Instrumentation Software User Info Beamline 6-ID-B,C Beamline 6-ID-B,C is operated by the Magnetic Materials Group in the X-ray...

  7. Dr. Tristram Kidder | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tristram Kidder Ancient Lessons for Modern Times: An Environmental History of the Yellow River, China, 5000-2000 BC Original Event Info: November 10, 2015 - 7:00pm Mid-County ...

  8. done

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    "%&'()*+,*+-(%*'B"%&'(C%2,1&-2&D(*26%((E&F*11*:%'GA*&'(2(*(E& ... (E& M&K +*1& (E-( %'(&G+-(&D A*6'%A-(%*'2 :%11 ,1-K %' &'-1%'G 6(%1%(%&2 (* ...

  9. Bull Outdoor Products: Order (2015-CE-14014)

    Broader source: Energy.gov [DOE]

    DOE ordered Bull Outdoor Products, Inc. to pay a $8,000 civil penalty after finding Bull had failed to certify that refrigerator basic model BC-130 complies with the applicable energy conservation standards.

  10. Bull Outdoor Products: Proposed Penalty (2015-CE-14014)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Bull Outdoor Products, Inc. failed to certify refrigerator basic model BC-130 as compliant with the applicable energy conservation standards.

  11. Seminar Series | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tristram Kidder Ancient Lessons for Modern Times: An Environmental History of the Yellow River, China, 5000-2000 BC Read more about Dr. Tristram Kidder November 11, 2015 Donald Ort ...

  12. CX-014464: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replacement of Bayou Choctaw Deep Well Anode Ground Bed Sites (BC-OM-1472) CX(s) Applied: B1.3Date: 12/08/2015 Location(s): Multiple LocationsOffices(s): Strategic Petroleum Reserve Field Office

  13. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Project in the Southern Great Plains Torn, M.S.(a), Berry, J.(b), Riley, W.J.(a), Fischer, M.L.(a), Billesbach, B.(c), Helliker, B.(b), and Giles, L.(b), Lawrence Berkeley...

  14. 10-04-2010 CA-B-10-0154

    National Nuclear Security Administration (NNSA)

    4 Sandia National LaboratoriesCalifornia (SNLCA) will develop a novel fieldable laser-induced incandescence sensor to measure black carbon (BC) and brown carbon (BrC) organic ...

  15. Gravitational Instability of a Nonrotating Galaxy (Conference...

    Office of Scientific and Technical Information (OSTI)

    Number: AC02-76SF00515 Resource Type: Conference Resource Relation: Conference: Invited talk at Particle Accelerator Conference (PAC 09), Vancouver, BC, Canada, 4-8 May 2009...

  16. CX-004719: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Upgrade Communication/Control Systems to BC Brine Disposal Well (Government Furnished Equipment and Install)CX(s) Applied: B1.7Date: 11/23/2010Location(s): LouisianaOffice(s): Strategic Petroleum Reserve Field Office

  17. CX-008368: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Renovate 773-A B&C Wing Bathrooms CX(s) Applied: B1.3 Date: 03/28/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office

  18. Title FREEDOM OF INFORMATION ACT REQUEST (FOT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Section 3 Document Inf ormation Document FOIA-2009-0054TPRevision Title FREEDOM OF INFORMATION ACT REQUEST (FOT 2009-0054) bate 09022009 Originator RIEHLE bC Originator Co. ...

  19. Alternative Earth Resources Inc | Open Energy Information

    Open Energy Info (EERE)

    840 - 1140 West Pender St. Place: Vancouver, B.C. Zip: V6E 4G1 Sector: Geothermal energy Website: www.alternative-earth.comsHo References: Alternative Earth Website1...

  20. DOE-Idaho Operations Summary For October 2 to October 22, 2012

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The report is broken down by contractor: Advanced Mixed Waste Treatment Project (AMWTP), Idaho ... Decision 4 for PBS-40B.C1, Nuclear Facility Decontamination & Demolition (D&D). ...

  1. D0208002Rev1print.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fact Sheet Public Comment U.S. Department of Energy - Washington State Department of Ecology - U.S. Environmental Pr otection Agency 300 Are a 10 0- B,C 1 00- KW & KE 1 00- N 1 00-...

  2. The importance of China's household sector for black carbon emissions - article no. L12708

    SciTech Connect (OSTI)

    Streets, D.G.; Aunan, K.

    2005-06-30

    The combustion of coal and biofuels in Chinese households is a large source of black carbon (BC), representing about 10-15% of total global emissions during the past two decades, depending on the year. How the Chinese household sector develops during the next 50 years will have an important bearing on future aerosol concentrations, because the range of possible outcomes (about 550 Gg yr{sup -1}) is greater than total BC emissions in either the United States or Europe (each about 400-500 Gg yr{sup -1}). In some Intergovernmental Panel on Climate Change scenarios biofuels persist in rural China for at least the next 50 years, whereas in other scenarios a transition to cleaner fuels and technologies effectively mitigates BC emissions. This paper discusses measures and policies that would help this transition and also raises the possibility of including BC emission reductions as a post-Kyoto option for China and other developing countries.

  3. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Development of Consistent Cirrus Models for Use in the Satellite Community Yang, P. (a), Baum, B.A. (b), Nasiri, S.L. (c), Heymsfield, A.J. (d), McFarquhar, G.M. (d), Gao, B.-C....

  4. Day4Energy Inc | Open Energy Information

    Open Energy Info (EERE)

    Day4Energy Inc Place: Burnaby, British Columbia, Canada Zip: BC V5G 4X4 Product: Manufactures modules using crystalline silicon PV cells and a patented back-contact method, the...

  5. Parallel State Estimation Assessment with Practical Data (Conference...

    Office of Scientific and Technical Information (OSTI)

    DOE Contract Number: AC05-76RL01830 Resource Type: Conference Resource Relation: Conference: IEEE Power and Energy Society General Meeting (PES), July 21-25, 2013, Vancouver, BC, ...

  6. Parallel State Estimation Assessment with Practical Data (Conference...

    Office of Scientific and Technical Information (OSTI)

    DOE Contract Number: AC05-76RL01830 Resource Type: Conference Resource Relation: Conference: IEEE Power & Energy Society General Meeting (PES), July 27-31, 2014. Vancouver, BC ...

  7. Team Ontario 2009 Solar Decathlon House

    Broader source: Energy.gov [DOE]

    This photograph features Team Ontario/BC's solar-powered house that glows at night during the Lighting Design contest at the U.S. Department of Energy Solar Decathlon on the National Mall. Team...

  8. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T.P. (e), Remer, L. (f), and Gao, B-C. (g), NASA Langley Research Center (a), Science Applications International CorporationNASALaRC (b), Pacific Northwest National Laboratory ...

  9. Environmental Compliance Performance Scorecard ¬タモ Third...

    Office of Environmental Management (EM)

    ... MILESTONE FIELD ID MILESTONE NAME MILESTONE DESCRIPTION VARIANCE NARRATIVE FORECAST DATE ACTUAL DATE ARRA Project: N ARRA Project: N ID-0030B.C1-027 OU 3-14 Draft Phase II 90% ...

  10. Community Response to Concentrating Solar Power in the San Luis...

    Open Energy Info (EERE)

    Laboratory, University of Colorado Partner B.C. Farhar, L.M. Hunter, T.M. Kirkland, and K.J. Tierney Focus Area Solar Phase Bring the Right People Together, Evaluate Options, Get...

  11. Thermophysical properties of sodium nitrate and sodium chloride...

    Office of Scientific and Technical Information (OSTI)

    ... Authors: Xu, Tianfu ; Pruess, Karsten Publication Date: 2001-10-01 OSTI Identifier: 790019 Report Number(s): LBNL--48913 R&D Project: 80BC01; TRN: US0200332 DOE Contract Number: ...

  12. Modelled Black Carbon Radiative Forcing and Atmospheric Lifetime...

    Office of Scientific and Technical Information (OSTI)

    Adjusting model results to measurements in remote regions, and at high altitudes, leads to a 25% reduction in the multi-model median direct BC forcing from fossil fuel and biofuel ...

  13. Word Pro - S8

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Table 8.1 Nuclear Energy Overview Total Operable Units a,b Net Summer Capacity of Operable Units b,c Nuclear Electricity Net Generation Nuclear Share of Electricity Net Generation ...

  14. BIGHORN SHEEP: SUPPLEMENTAL ANALYSIS TO THE FOREST PLAN ENVIRONMENTAL...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    August 6 Committee call placeholder: Tuesday, August 13 @ 1:30 p.m. * ASCEM and Phoenix modeling - not time critical, "fill in" topic * Draft work plan for the BC cribs WA-1...

  15. http://pubs.usgs.gov/wri/wri964109/report.htm

    National Nuclear Security Administration (NNSA)

    ... events, and from 200 to more than 350 ft for larger events (Hudson and Smith, 1981). ... sheets, scale 1:4,800. Hudson, B.C., and Smith, J.R., 1981, Cavity radius uncertainties: ...

  16. Geoengineering: Plan B Remedy for Global Warming Andrew A. Lacis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mass-specific cross-sections (m2g) at 550 nm and 10 mm for black carbon (BC), sulfuric acid (SA), aluminum (AL) aerosols (A), and mass-specific cooling for SA aerosol for mass ...

  17. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bkgd-like etc. This tree is one of many possibilities... BDT Analysis: Boosted Decision Trees Alexis Aguilar-Arevalo TRIUMF Seminar Vancouver, BC, Canada Sept 27, 2007 BDT...

  18. CX-002883: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Procure and Install Analytical Chemistry Instrumentation, 773-A (B&C Wings)CX(s) Applied: B3.1Date: 06/02/2010Location(s): Aiken, South CarolinaOffice(s): Environmental Management, Savannah River Operations Office

  19. James L. Liveman, Acting AssLBtaOt

    Office of Legacy Management (LM)

    SD:ZTJ cc: B. ' veen, UL w. Smith, Am ' A. Baker, Utivc-oity of Nevada W. E. Not:, ECT, EQ Robert H. Bauc xanager . ' bc: OX , OFFICE SfiEfm,r SAFE -, -*-r SURNAME ias ce --&%y ...

  20. Russian anthropogenic black carbon: Emission reconstruction and Arctic black carbon simulation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Kan; Fu, Joshua S.; Prikhodko, Vitaly Y.; Storey, John M.; Romanov, Alexander; Hodson, Elke L.; Cresko, Joe; Morozova, Irina; Ignatieva, Yulia; Cabaniss, John

    2015-10-02

    Development of reliable source emission inventories is needed to advance the understanding of the origin of Arctic haze using chemical transport modeling. This paper develops a regional anthropogenic black carbon (BC) emission inventory for the Russian Federation, the largest country by land area in the Arctic Council. Activity data from combination of local Russia information and international resources, emission factors based on either Russian documents or adjusted values for local conditions, and other emission source data are used to approximate the BC emissions. Emissions are gridded at a resolution of 0.1° × 0.1° and developed into a monthly temporal profile.more » Total anthropogenic BC emission of Russia in 2010 is estimated to be around 224 Gg. Gas flaring, a commonly ignored black carbon source, contributes a significant fraction of 36.2% to Russia's total anthropogenic BC emissions. Other sectors, i.e., residential, transportation, industry, and power plants, contribute 25.0%, 20.3%, 13.1%, and 5.4%, respectively. Three major BC hot spot regions are identified: the European part of Russia, the southern central part of Russia where human population densities are relatively high, and the Urals Federal District where Russia's major oil and gas fields are located but with sparse human population. BC simulations are conducted using the hemispheric version of Community Multi-scale Air Quality Model with emission inputs from a global emission database EDGAR (Emissions Database for Global Atmospheric Research)-HTAPv2 (Hemispheric Transport of Air Pollution) and EDGAR-HTAPv2 with its Russian part replaced by the newly developed Russian BC emissions, respectively. The simulation using the new Russian BC emission inventory could improve 30–65% of absorption aerosol optical depth measured at the AERONET sites in Russia throughout the whole year as compared to that using the default HTAPv2 emissions. At the four ground monitoring sites (Zeppelin, Barrow, Alert

  1. Russian anthropogenic black carbon: Emission reconstruction and Arctic black carbon simulation

    SciTech Connect (OSTI)

    Huang, Kan; Fu, Joshua S.; Prikhodko, Vitaly Y.; Storey, John M.; Romanov, Alexander; Hodson, Elke L.; Cresko, Joe; Ignatieva, Yulia; Cabaniss, John

    2015-10-02

    Development of reliable source emission inventories is needed to advance the understanding of the origin of Arctic haze using chemical transport modeling. This paper develops a regional anthropogenic black carbon (BC) emission inventory for the Russian Federation, the largest country by land area in the Arctic Council. Activity data from combination of local Russia information and international resources, emission factors based on either Russian documents or adjusted values for local conditions, and other emission source data are used to approximate the BC emissions. Emissions are gridded at a resolution of 0.1° × 0.1° and developed into a monthly temporal profile. Total anthropogenic BC emission of Russia in 2010 is estimated to be around 224 Gg. Gas flaring, a commonly ignored black carbon source, contributes a significant fraction of 36.2% to Russia's total anthropogenic BC emissions. Other sectors, i.e., residential, transportation, industry, and power plants, contribute 25.0%, 20.3%, 13.1%, and 5.4%, respectively. Three major BC hot spot regions are identified: the European part of Russia, the southern central part of Russia where human population densities are relatively high, and the Urals Federal District where Russia's major oil and gas fields are located but with sparse human population. BC simulations are conducted using the hemispheric version of Community Multi-scale Air Quality Model with emission inputs from a global emission database EDGAR (Emissions Database for Global Atmospheric Research)-HTAPv2 (Hemispheric Transport of Air Pollution) and EDGAR-HTAPv2 with its Russian part replaced by the newly developed Russian BC emissions, respectively. The simulation using the new Russian BC emission inventory could improve 30–65% of absorption aerosol optical depth measured at the AERONET sites in Russia throughout the whole year as compared to that using the default HTAPv2 emissions. At the four ground monitoring sites (Zeppelin, Barrow, Alert, and

  2. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Finding a Method to Measure the Black Carbon State of Mixture Fiebig, M. and Ogren, J.A., National Oceanic and Administrative Administration - Climate Monitoring and Diagnostics Laboratory Fourteenth Atmospheric Radiation Measurement (ARM) Science Team Meeting Black carbon (BC), the predominant source of solar absorption in atmospheric aerosol, can be present therein as pure BC particles distinct from purely scattering particles (external mixture), homogeneously mixed with purely scattering

  3. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Relative Content of Black Carbon in Submicron Aerosol as a Sign of the Effect of Forest Fire Smokes V.S. Kozlov, M.V. Panchenko, and E.P. Yausheva Institute of Atmospheric Optics Tomsk, Russia Introduction Biomass burning occurs often in regions containing vast forest tracts and peat-bogs. These processes are accompanied by the emission of aerosol particles and crystal carbon (black carbon [BC], soot). BC is the predominant source of solar absorption in atmospheric aerosol, which impacts

  4. 2013 DOE Bioenergy Technologies Office (BETO) Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BC Process Improvements Validation Task (2.3.1.7) Date: May 21, 2013 Technology Area Review: Biochemical Conversion Principal Investigators: James D. (Jim) McMillan and Nancy Dowe Organization: NREL This presentation does not contain any proprietary, confidential, or otherwise restricted information NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. BC Process Improvements

  5. THE CLUSTER AND FIELD GALAXY ACTIVE GALACTIC NUCLEUS FRACTION AT z = 1-1.5: EVIDENCE FOR A REVERSAL OF THE LOCAL ANTICORRELATION BETWEEN ENVIRONMENT AND AGN FRACTION

    SciTech Connect (OSTI)

    Martini, Paul; Miller, E. D.; Bautz, M.; Brodwin, M.; Stanford, S. A.; Gonzalez, Anthony H.; Hickox, R. C.; Stern, D.; Eisenhardt, P. R.; Galametz, A.; Norman, D.; Dey, A.; Jannuzi, B. T.; Murray, S.; Jones, C.; Brown, M. J. I.

    2013-05-01

    The fraction of cluster galaxies that host luminous active galactic nuclei (AGNs) is an important probe of AGN fueling processes, the cold interstellar medium at the centers of galaxies, and how tightly black holes and galaxies co-evolve. We present a new measurement of the AGN fraction in a sample of 13 clusters of galaxies (M {>=} 10{sup 14} M{sub Sun }) at 1 < z < 1.5 selected from the Spitzer/IRAC Shallow Cluster Survey, as well as the field fraction in the immediate vicinity of these clusters, and combine these data with measurements from the literature to quantify the relative evolution of cluster and field AGN from the present to z {approx} 3. We estimate that the cluster AGN fraction at 1 < z < 1.5 is f{sub A} = 3.0{sup +2.4}{sub -1.4}% for AGNs with a rest-frame, hard X-ray luminosity greater than L{sub X,{sub H}} {>=} 10{sup 44} erg s{sup -1}. This fraction is measured relative to all cluster galaxies more luminous than M{sup *}{sub 3.6}(z) + 1, where M{sup *}{sub 3.6}(z) is the absolute magnitude of the break in the galaxy luminosity function at the cluster redshift in the IRAC 3.6 {mu}m bandpass. The cluster AGN fraction is 30 times greater than the 3{sigma} upper limit on the value for AGNs of similar luminosity at z {approx} 0.25, as well as more than an order of magnitude greater than the AGN fraction at z {approx} 0.75. AGNs with L{sub X,{sub H}} {>=} 10{sup 43} erg s{sup -1} exhibit similarly pronounced evolution with redshift. In contrast to the local universe, where the luminous AGN fraction is higher in the field than in clusters, the X-ray and MIR-selected AGN fractions in the field and clusters are consistent at 1 < z < 1.5. This is evidence that the cluster AGN population has evolved more rapidly than the field population from z {approx} 1.5 to the present. This environment-dependent AGN evolution mimics the more rapid evolution of star-forming galaxies in clusters relative to the field.

  6. Elastic properties, sp³ fraction, and Raman scattering in low and high pressure synthesized diamond-like boron rich carbides

    SciTech Connect (OSTI)

    Zinin, Pavel V.; Burgess, Katherine; Jia, Ruth; Sharma, Shiv; Ming, Li-Chung; Liu, Yongsheng; Ciston, Jim; Hong, Shiming

    2014-10-07

    Dense BC{sub x} phases with high boron concentration are predicted to be metastable, superhard, and conductors or superconductors depending on boron concentration. However, up to this point, diamond-like boron rich carbides BC{sub x} (dl-BC{sub x}) phases have been thought obtainable only through high pressure and high temperature treatment, necessitating small specimen volume. Here, we use electron energy loss spectroscopy combined with transmission electron microscopy, Raman spectroscopy, surface Brillouin scattering, laser ultrasonics (LU) technique, and analysis of elastic properties to demonstrate that low pressure synthesis (chemical vapor deposition) of BC{sub x} phases may also lead to the creation of diamond-like boron rich carbides. The elastic properties of the dl-BC{sub x} phases depend on the carbon sp²versus sp³ content, which decreases with increasing boron concentration, while the boron bonds determine the shape of the Raman spectra of the dl-BC{sub x} after high pressure-high temperature treatment. Using the estimation of the density value based on the sp³ fraction, the shear modulus μ of dl-BC₄, containing 10% carbon atoms with sp³ bonds, and dl-B₃C₂, containing 38% carbon atoms with sp³ bonds, were found to be μ = 19.3 GPa and μ = 170 GPa, respectively. The presented experimental data also imply that boron atoms lead to a creation of sp³ bonds during the deposition processes.

  7. Supporting technology for enhanced oil recovery: EOR thermal processes. Seventh Amendment and Extension to Annex 4, Enhanced oil recovery thermal processes

    SciTech Connect (OSTI)

    Reid, T B; Colonomos, P

    1993-02-01

    This report contains the results of efforts under the six tasks of the Seventh Amendment and Extension of Annex IV, Enhanced Oil Recovery Thermal Processes of the Venezuela/USA Agreement. The report is presented in sections (for each of the 6 tasks) and each section contains one or more reports prepared by various individuals or groups describing the results of efforts under each of the tasks. A statement of each task, taken from the agreement, is presented on the first page of each section. The tasks are numbered 50 through 55. The first, second, third, fourth, fifth, sixth and seventh reports on Annex IV, Venezuela MEM/USA-DOE Fossil Energy Report IV-1, IV-2, IV-3, IV-4, IV-5 and IV-6 (DOE/BETC/SP-83/15, DOE/BC-84/6/SP, DOE/BC-86/2/SP, DOE/BC-87/2/SP, DOE/BC-89/l/SP, DOE/BC-90/l/SP, and DOE/BC-92/l/SP) contain the results for the first 49 tasks. Those reports are dated April 1983, August 1984, March 1986, July 1987, November 1988, December 1989, and October 1991, respectively. Each task report has been processed separately for inclusion in the Energy Science and Technology Database.

  8. An AeroCom Assessment of Black Carbon in Arctic Snow and Sea Ice

    SciTech Connect (OSTI)

    Jiao, C.; Flanner, M. G.; Balkanski, Y.; Bauer, S.; Bellouin, N.; Berntsen, T.; Bian, Huisheng; Carslaw, K. S.; Chin, Mian; De Luca, N.; Diehl, Thomas; Ghan, Steven J.; Iversen, T.; Kirkevag, A.; Koch, Dorothy; Liu, Xiaohong; Mann, G. W.; Penner, Joyce E.; Pitari, G.; Schulz, M.; Seland, O.; Skeie, R. B.; Steenrod, Stephen D.; Stier, P.; Takemura, T.; Tsigaridis, Kostas; van Noije, T.; Yun, Yuxing; Zhang, Kai

    2014-03-07

    Though many global aerosols models prognose surface deposition, only a few models have been used to directly simulate the radiative effect from black carbon (BC) deposition to snow and sea-ice. Here, we apply aerosol deposition fields from 25 models contributing to two phases of the Aerosol Comparisons between Observations and Models (AeroCom) project to simulate and evaluate within snow BC concentrations and radiative effect in the Arctic. We accomplish this by driving the offline land and sea-ice components of the Community Earth System Model with different deposition fields and meteorological conditions from 2004-2009, during which an extensive field campaign of BC measurements in Arctic snow occurred. We find that models generally underestimate BC concentrations in snow in northern Russia and Norway, while overestimating BC amounts elsewhere in the Arctic. Although simulated BC distributions in snow are poorly correlated with measurements, mean values are reasonable. The multi-model mean (range) bias in BC concentrations, sampled over the same grid cells, snow depths, and months of measurements, are -4.4 (-13.2 to +10.7) ng g−1 for an earlier Phase of AeroCom models (Phase I), and +4.1 (-13.0 to +21.4) ng g−1 for a more recent Phase of AeroCom models (Phase II), compared to the observational mean of 19.2 ng g−1. Factors determining model BC concentrations in Arctic snow include Arctic BC emissions, transport of extra-Arctic aerosols, precipitation, deposition efficiency of aerosols within the Arctic, and meltwater removal of particles in snow. Sensitivity studies show that the model–measurement evaluation is only weakly affected by meltwater scavenging efficiency because most measurements were conducted in non-melting snow. The Arctic (60-90◦N) atmospheric residence time for BC in Phase II models ranges from 3.7 to 23.2 days, implying large inter-model variation in local BC deposition efficiency. Combined with the fact that most Arctic BC deposition

  9. IDCS J1433.2+3306: AN INFRARED-SELECTED GALAXY CLUSTER AT z = 1.89

    SciTech Connect (OSTI)

    Zeimann, Gregory R.; Stanford, S. A.; Brodwin, Mark; Gonzalez, Anthony H.; Mancone, Conor; Snyder, Gregory F.; Stern, Daniel; Eisenhardt, Peter; Dey, Arjun

    2012-09-10

    We report the discovery of an IR-selected galaxy cluster in the IRAC Distant Cluster Survey (IDCS). New data from the Hubble Space Telescope spectroscopically confirm IDCS J1433.2+3306 at z = 1.89 with robust spectroscopic redshifts for seven members, two of which are based on the 4000 A break. Detected emission lines such as [O II] and H{beta} indicate star formation rates of {approx}>20 M{sub Sun} yr{sup -1} for three galaxies within a 500 kpc projected radius of the cluster center. The cluster exhibits a red sequence with a scatter and color indicative of a formation redshift z{sub f} {approx}> 3.5. The stellar age of the early-type galaxy population is approximately consistent with those of clusters at lower redshift (1 <z < 1.5) suggesting that clusters at these redshifts are experiencing ongoing or increasing star formation.

  10. Observed high-altitude warming and snow cover retreat over Tibet and the Himalayas enhanced by black carbon aerosols

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Y.; Ramanathan, V.; Washington, W. M.

    2016-02-05

    Himalayan mountain glaciers and the snowpack over the Tibetan Plateau provide the headwater of several major rivers in Asia. In situ observations of snow cover extent since the 1960s suggest that the snowpack in the region have retreated significantly, accompanied by a surface warming of 2–2.5°C observed over the peak altitudes (5000 m). Using a high-resolution ocean–atmosphere global climate model and an observationally constrained black carbon (BC) aerosol forcing, we attribute the observed altitude dependence of the warming trends as well as the spatial pattern of reductions in snow depths and snow cover extent to various anthropogenic factors. At themore » Tibetan Plateau altitudes, the increase in atmospheric CO2 concentration exerted a warming of 1.7°C, BC 1.3°C where as cooling aerosols cause about 0.7°C cooling, bringing the net simulated warming consistent with the anomalously large observed warming. We therefore conclude that BC together with CO2 has contributed to the snow retreat trends. In particular, BC increase is the major factor in the strong elevation dependence of the observed surface warming. The atmospheric warming by BC as well as its surface darkening of snow is coupled with the positive snow albedo feedbacks to account for the disproportionately large role of BC in high-elevation regions. Here, these findings reveal that BC impact needs to be properly accounted for in future regional climate projections, in particular on high-altitude cryosphere.« less

  11. Observed high-altitude warming and snow cover retreat over Tibet and the Himalayas enhanced by black carbon aerosols

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Y.; Ramanathan, V.; Washington, W. M.

    2016-02-05

    Himalayan mountain glaciers and the snowpack over the Tibetan Plateau provide the headwater of several major rivers in Asia. In situ observations of snow cover extent since the 1960s suggest that the snowpack in the region have retreated significantly, accompanied by a surface warming of 2–2.5 °C observed over the peak altitudes (5000 m). Using a high-resolution ocean–atmosphere global climate model and an observationally constrained black carbon (BC) aerosol forcing, we attribute the observed altitude dependence of the warming trends as well as the spatial pattern of reductions in snow depths and snow cover extent to various anthropogenic factors. At the Tibetanmore » Plateau altitudes, the increase in atmospheric CO2 concentration exerted a warming of 1.7 °C, BC 1.3 °C where as cooling aerosols cause about 0.7 °C cooling, bringing the net simulated warming consistent with the anomalously large observed warming. We therefore conclude that BC together with CO2 has contributed to the snow retreat trends. In particular, BC increase is the major factor in the strong elevation dependence of the observed surface warming. The atmospheric warming by BC as well as its surface darkening of snow is coupled with the positive snow albedo feedbacks to account for the disproportionately large role of BC in high-elevation regions. These findings reveal that BC impact needs to be properly accounted for in future regional climate projections, in particular on high-altitude cryosphere.« less

  12. Black carbon emissions from Russian diesel sources. Case study of Murmansk

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Evans, M.; Kholod, N.; Malyshev, V.; Tretyakova, S.; Gusev, E.; Yu, S.; Barinov, A.

    2015-07-27

    Black carbon (BC) is a potent pollutant because of its effects on climate change, ecosystems and human health. Black carbon has a particularly pronounced impact as a climate forcer in the Arctic because of its effect on snow albedo and cloud formation. We have estimated BC emissions from diesel sources in the Murmansk Region and Murmansk City, the largest city in the world above the Arctic Circle. In this study we developed a detailed inventory of diesel sources including on-road vehicles, off-road transport (mining, locomotives, construction and agriculture), ships and diesel generators. For on-road transport, we conducted several surveys tomore » understand the vehicle fleet and driving patterns, and, for all sources, we also relied on publicly available local data sets and analysis. We calculated that BC emissions in the Murmansk Region were 0.40 Gg in 2012. The mining industry is the largest source of BC emissions in the region, emitting 69 % of all BC emissions because of its large diesel consumption and absence of emissions controls. On-road vehicles are the second largest source, emitting about 13 % of emissions. Old heavy duty trucks are the major source of emissions. Emission controls on new vehicles limit total emissions from on-road transportation. Vehicle traffic and fleet surveys show that many of the older cars on the registry are lightly or never used. We also estimated that total BC emissions from diesel sources in Russia were 50.8 Gg in 2010, and on-road transport contributed 49 % of diesel BC emissions. Agricultural machinery is also a significant source Russia-wide, in part because of the lack of controls on off-road vehicles.« less

  13. Black carbon emissions from Russian diesel sources. Case study of Murmansk

    SciTech Connect (OSTI)

    Evans, M.; Kholod, N.; Malyshev, V.; Tretyakova, S.; Gusev, E.; Yu, S.; Barinov, A.

    2015-07-27

    Black carbon (BC) is a potent pollutant because of its effects on climate change, ecosystems and human health. Black carbon has a particularly pronounced impact as a climate forcer in the Arctic because of its effect on snow albedo and cloud formation. We have estimated BC emissions from diesel sources in the Murmansk Region and Murmansk City, the largest city in the world above the Arctic Circle. In this study we developed a detailed inventory of diesel sources including on-road vehicles, off-road transport (mining, locomotives, construction and agriculture), ships and diesel generators. For on-road transport, we conducted several surveys to understand the vehicle fleet and driving patterns, and, for all sources, we also relied on publicly available local data sets and analysis. We calculated that BC emissions in the Murmansk Region were 0.40 Gg in 2012. The mining industry is the largest source of BC emissions in the region, emitting 69 % of all BC emissions because of its large diesel consumption and absence of emissions controls. On-road vehicles are the second largest source, emitting about 13 % of emissions. Old heavy duty trucks are the major source of emissions. Emission controls on new vehicles limit total emissions from on-road transportation. Vehicle traffic and fleet surveys show that many of the older cars on the registry are lightly or never used. We also estimated that total BC emissions from diesel sources in Russia were 50.8 Gg in 2010, and on-road transport contributed 49 % of diesel BC emissions. Agricultural machinery is also a significant source Russia-wide, in part because of the lack of controls on off-road vehicles.

  14. Measurement of the $$B_c^{\\pm}$$ production cross section in $$p\\bar{p}$$ collisions at $$\\sqrt{s}=1.96$$ TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aaltonen, Timo Antero

    2016-03-01

    Here, we describe a measurement of the ratio of the cross sections times branching fractions of the Bc+ meson in the decay mode Bc+ → J/ψμ+ν to the B+ meson in the decay mode B+ → J/ψK+ in proton-antiproton collisions at center-of-mass energy √s = 1.96 TeV. The measurement is based on the complete CDF Run II data set, which comes from an integrated luminosity of 8.7 fb-1. The ratio of the production cross sections times branching fractions for Bc+ and B+ mesons with momentum transverse to the beam greater than 6 GeV/c and rapidity magnitude smaller than 0.6 ismore » 0.211 ± 0.012(stat)-0.020+0.021(syst). Using the known B+ → J/ψK+ branching fraction, the known B+ production cross section, and a selection of the predicted Bc+ → J/ψμ+ν branching fractions, the range for the total Bc+ production cross section is estimated.« less

  15. {sup 25}Na and {sup 25}Mg fragmentation on {sup 12}C at 9.23 MeV per nucleon at TRIUMF

    SciTech Connect (OSTI)

    St-Onge, Patrick; Boisjoli, Mark; Fregeau, Marc-Olivier; Gauthier, Jerome; Wallace, Barton; Roy, Rene

    2012-10-20

    HERACLES is a multidetector that is used to study heavy-ion collisions, with ion beams with an energy range between 8 to 15 MeV per nucleon. It has 78 detectors axially distributed around the beam axis in 6 rings allowing detection of multiple charged fragments from nuclear reactions. HERACLES has 4 different types of detectors, BC408/BaF{sub 2} phoswich, Si/CsI(Tl) telescope, BC408/BC444 phoswich and CsI(Tl) detectors. The multidetector has been run with a radioactive {sup 25}Na beam and a stable {sup 25}Mg beam at 9.23 MeV per nucleon on a carbon target.

  16. Three dimensional simulation for bayou choctaw strategic petroleum reserve (SPR).

    SciTech Connect (OSTI)

    Ehgartner, Brian L. (Sandia National Laboratories, Albuquerque, NM); Park, Byoung Yoon; Lee, Moo Yul

    2006-12-01

    Three dimensional finite element analyses were performed to evaluate the structural integrity of the caverns located at the Bayou Choctaw (BC) site which is considered a candidate for expansion. Fifteen active and nine abandoned caverns exist at BC, with a total cavern volume of some 164 MMB. A 3D model allowing control of each cavern individually was constructed because the location and depth of caverns and the date of excavation are irregular. The total cavern volume has practical interest, as this void space affects total creep closure in the BC salt mass. Operations including both cavern workover, where wellhead pressures are temporarily reduced to atmospheric, and cavern enlargement due to leaching during oil drawdowns that use water to displace the oil from the caverns, were modeled to account for as many as the five future oil drawdowns in the six SPR caverns. The impacts on cavern stability, underground creep closure, surface subsidence, infrastructure, and well integrity were quantified.

  17. Upper critical field and Kondo effects in Fe(Te0.9Se0.1) thin films by pulsed field measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Salamon, Myron B.; Cornell, Nicholas; Jaime, Marcelo; Balakirev, Fedor F.; Zakhidov, Anvar; Huang, Jijie; Wang, Haiyan

    2016-02-10

    The transition temperatures of epitaxial films of Fe(Te0:9Se0:1) are remarkably insensitive to applied magnetic field, leading to predictions of upper critical fields Bc2(T = 0) in excess of 100 T. Using pulsed magnetic fields, we find Bc2(0) to be on the order of 45 T, similar to values in bulk material and still in excess of the paramagnetic limit. The same films show strong magnetoresistance in fields above Bc2(T), consistent with the observed Kondo minimum seen above Tc. Fits to the temperature dependence in the context of the WHH model, using the experimental value of the Maki parameter, require anmore » effective spin-orbit relaxation parameter of order unity. Lastly, we suggest that Kondo localization plays a similar role to spin-orbit pair breaking in making WHH fits to the data.« less

  18. What is the importance of climate model bias when projecting the impacts of climate change on land surface processes?

    SciTech Connect (OSTI)

    Liu, M. L.; Rajagopalan, K.; Chung, S. H.; Jiang, X.; Harrison, J. H.; Nergui, T.; Guenther, Alex B.; Miller, C.; Reyes, J.; Tague, C. L.; Choate, J. S.; Salathe, E.; Stockle, Claudio O.; Adam, J. C.

    2014-05-16

    Regional climate change impact (CCI) studies have widely involved downscaling and bias-correcting (BC) Global Climate Model (GCM)-projected climate for driving land surface models. However, BC may cause uncertainties in projecting hydrologic and biogeochemical responses to future climate due to the impaired spatiotemporal covariance of climate variables and a breakdown of physical conservation principles. Here we quantify the impact of BC on simulated climate-driven changes in water variables(evapotranspiration, ET; runoff; snow water equivalent, SWE; and water demand for irrigation), crop yield, biogenic volatile organic compounds (BVOC), nitric oxide (NO) emissions, and dissolved inorganic nitrogen (DIN) export over the Pacific Northwest (PNW) Region. We also quantify the impacts on net primary production (NPP) over a small watershed in the region (HJ Andrews). Simulation results from the coupled ECHAM5/MPI-OM model with A1B emission scenario were firstly dynamically downscaled to 12 km resolutions with WRF model. Then a quantile mapping based statistical downscaling model was used to downscale them into 1/16th degree resolution daily climate data over historical and future periods. Two series climate data were generated according to the option of bias-correction (i.e. with bias-correction (BC) and without bias-correction, NBC). Impact models were then applied to estimate hydrologic and biogeochemical responses to both BC and NBC meteorological datasets. These im20 pact models include a macro-scale hydrologic model (VIC), a coupled cropping system model (VIC-CropSyst), an ecohydrologic model (RHESSys), a biogenic emissions model (MEGAN), and a nutrient export model (Global-NEWS). Results demonstrate that the BC and NBC climate data provide consistent estimates of the climate-driven changes in water fluxes (ET, runoff, and water demand), VOCs (isoprene and monoterpenes) and NO emissions, mean crop yield, and river DIN export over the PNW domain. However

  19. Vitrification demonstration with surrogate Oak Ridge Reservation K-25 B and C pond sludge

    SciTech Connect (OSTI)

    Cicero, C.A.; Overcamp, T.J.; Erich, D.L.

    1996-07-01

    Surrogate Oak Ridge Reservation (ORR) K-25 B&C Pond sludge was vitrified in a pilot-scale EnVit Co melter operated by Clemson University at the DOE/Industrial Center for Vitrification Research Center. This demonstration was performed for the Savannah River Technology Center (SRTC) in support of a Department of Energy (DOE) - Office of Technology Development (OTD) Technical Task Plan. The intent of the demonstration was to determine the feasibility of vitrifying actual K-25 B&C Pond sludge in an EnVitCo type melter. B&C Pond sludge is a mixed waste consisting primarily of various amounts of Ca, Fe, and Si, with Ni and U as the principal hazardous and radioactive components. The demonstration was successfully completed and homogeneous, durable glass was produced. Characterization of the glass product, as well as details of the demonstration, will be discussed.

  20. Do We Really Know how Much it Costs to Construct High Performance Buildings?

    SciTech Connect (OSTI)

    Livingston, Olga V.; Dillon, Heather E.; Halverson, Mark A.; Antonopoulos, Chrissi A.; Madison, Michael C.; Lucas, Robert G.

    2012-08-31

    Understanding the cost of energy efficient construction is critical to decision makers in building design, code development, and energy analysis. How much does it cost to upgrade from R-13 to R-19 in a building wall? How much do low-e windows really cost? Can we put a dollar figure on commissioning? Answers to these questions have a fuzzy nature, based on educated guesses and industry lore. The response depends on location, perspective, bulk buying, and hand waving. This paper explores the development of a web tool intended to serve as a publicly available repository of building component costs. In 2011 the U.S. Department of Energy (DOE) funded the launch of a web tool called the Building Component Cost Community (BC3), dedicated to publishing building component costs from documented sources, actively gathering verifiable cost data from the users, and collecting feedback from a wide range of participants on the quality of the posted cost data. The updated BC3 database, available at http://bc3.pnnl.gov, went live on April 30, 2012. BC3 serves as the ultimate source of the energy-related component costs for DOEs residential code development activities, including cost-effectiveness analyses. The paper discusses BC3 objectives, structure, functionality and the current content of the database. It aims to facilitate a dialog about the lack of verifiable transparent cost data, as well as introduce a web tool that helps to address the problem. The questions posed above will also be addressed by this paper, but they have to be resolved by the user community by providing feedback and cost data to the BC3 database, thus increasing transparency and removing information asymmetry.

  1. River Corridor Closure Contract Section J, Attachment J-10

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 Contract No. DE-AC06-05RL14655 A000 1 SECTION J, ATTACHMENT J-10 RCC SUBCONTRACTS EXISTING AT TIME OF SOLICITATION The following subcontracts are/were available for assignment to the Contractor at the time Solicitation No. DE-RP06-04RL14655 was issued: End Date Current Value Description Supplier 02/28/05 $ 5,994,091 100 B/C AREA PIPELINES RCI ENVIRONMENTAL, INC. 10/31/06 $ 1,324,615 100-BC BURIAL GROUNDS AND REMAINING SITES FEDERAL ENGINEERS & CONSTRUCTORS 12/31/05 $ 3,400,000 116-N-1 CRIB

  2. Characterization of Black Carbon Mixing State

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sedlacek, Arthur; S, Satheesh; Springston, Stephen

    2013-11-06

    This measurement characterizes the types of BC emissions that result in near­surface BC­ containing particles in a region that is dominated by biomass and open pit/stove cooking. Specifically, examine three primary BC emission sources: (i) urban setting (e.g., fossil fuel emissions); and (ii) biomass burning. Source (i) are captured at the Indian Institute of Science (IISc) in Bangalore. Biomass emissions (ii) contains a series of 1­2 day measurement excursions to the rural area surrounding Bangalore.

  3. Microsoft Word - beam characterization and verification.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beam Characterization and Verification Detector Components and Arrangement The beam uniformity and flux are determined using an array of five particle detectors. Each detector consists of Bicron BC-400 scintillator, a Bicron BC-634A optical coupling pad, a Hamamatsu R1635 photomultiplier tube, and a Hamamatsu E1761-04 tube base. Four of the detectors are fixed in position as show in Figure 1 and set up to measure beam particle counting rates continuously at four characteristic points, each 1.64

  4. Collection efficiency of the soot-particle aerosol mass spectrometer (SP-AMS) for internally mixed particulate black carbon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-12-18

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam–laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements aremore » used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam–particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of 2. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.« less

  5. Collection efficiency of the Soot-Particle Aerosol Mass Spectrometer (SP-AMS) for internally mixed particulate black carbon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-05-26

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam–laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements aremore » used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam–particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of two. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.« less

  6. Science in St. Louis | Dr. Tristram R. Kidder | Photosynthetic Antenna

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Center Tristram R. Kidder Science in St. Louis | Dr. Tristram R. Kidder Ancient Lessons for Modern Times: An Environmental History of the Yellow River, China, 5000-2000 BC November 10, 2015 - 7:00pm Mid-County Branch, St. Louis County Library, 7821 Maryland Ave. St. Louis, MO 63105-3875

  7. ConferenceCall

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Non-Treaty Storage Agreement Update Public Open Houses May-June 2011 2 B O N N E V I L L E P O W E R A D M I N I S T R A T I O N Status of Non-Treaty Storage Agreement BPA and BC...

  8. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARESE II Measurements of Broadband Absorptance Valero, F.P.J. (a), Bucholtz, A. (a), Bush, B.C. (a), Cess, R.D. (b), Leitner, A.S. (a), Pope, S.K. (a), and Tooman, T.P. (c),...

  9. Nanometer-scale chemical heterogeneities of black carbon materials and their impacts on PCB sorption properties: soft X-ray spectromicroscopy study

    SciTech Connect (OSTI)

    Tae Hyun Yoon; Karim Benzerara; Sungwoo Ahn; Richard G. Luthy; Tolek Tyliszczak; Gordon E. Brown, Jr.

    2006-10-01

    Synchrotron-based soft X-ray spectromicroscopy was used to probe nanometer-scale chemical heterogeneities of black carbon (BC) materials, including anthracite coal, coke, and activated carbon (AC), and to study their impact on the partitioning of one type of polychlorinated biphenyls (PCB-166: 2,3,4,4',5,6 hexachloro biphenyl) onto AC particles. Various carbon species (e.g., aromatic, ketonic/phenolic, and carboxylic functional groups) were found in all of the BC materials examined, and impurities (e.g., carbonate and potassium ions in anthracite coal) were identified in nanometer-scale regions of these samples. The show that these chemical heterogeneities in AC particles influence their sorption of hydrophobic organic compounds (HOCs). PCB-166 was found to accumulate preferentially on AC particles with the highest content of aromatic functionalities. These new findings from X-ray spectromicroscopy have the following implications for the role of BC materials in the environment: (1) the functional groups of BC materials vary on a 25-nanometer scale, and so does the abundance of the HOCs; (2) molecular-level characterization of HOC sorption preferences on AC will lead to an improved understanding of AC sorption properties for the remediation of HOCs in soils and sediments. 40 refs., 3 figs.

  10. A.A. Aguilar-Arevalo,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A. Aguilar-Arevalo, 1 B. Batell, 2 B.C. Brown, 3 R. Carr, 4 R. Cooper, 5 P. deNiverville, 6 R. Dharmapalan, 7 R. Ford, 3 F.G. Garcia, 3 G. T. Garvey, 8 J. Grange, 9 W. Huelsnitz, 8...

  11. MiniBooNE darkmatter collaboration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MiniBooNE-DM Collaboration A.A. Aguilar-Arevalo,1 B. Batell,2 B.C. Brown,3 R. Carr,4 R. Cooper,5 P. deNiverville,6 R. Dharmapalan,7 R. Ford,3 F.G. Garcia,3 G. T. Garvey,8 J....

  12. Treatability studies of actual listed waste sludges from the Oak Ridge Reservation (ORR)

    SciTech Connect (OSTI)

    Jantzen, C.M.; Peeler, D.K.; Gilliam, T.M.; Bleier, A.; Spence, R.D.

    1996-05-06

    Oak Ridge National Laboratory (ORNL) and Savannah River Technology Center (SRTC) are investigating vitrification for various low-level and mixed wastes on the Oak Ridge Reservation (ORR). Treatability studies have included surrogate waste formulations at the laboratory-, pilot-, and field-scales and actual waste testing at the laboratory- and pilot-scales. The initial waste to be processing through SRTC`s Transportable Vitrification System (TVS) is the K-1407-B and K-1407-C (B/C) Pond sludge waste which is a RCRA F-listed waste. The B/C ponds at the ORR K-25 site were used as holding and settling ponds for various waste water treatment streams. Laboratory-, pilot-, and field- scale ``proof-of-principle`` demonstrations are providing needed operating parameters for the planned field-scale demonstration with actual B/C Pond sludge waste at ORR. This report discusses the applied systems approach to optimize glass compositions for this particular waste stream through laboratory-, pilot-, and field-scale studies with surrogate and actual B/C waste. These glass compositions will maximize glass durability and waste loading while optimizing melt properties which affect melter operation, such as melt viscosity and melter refractory corrosion. Maximum waste loadings minimize storage volume of the final waste form translating into considerable cost savings.

  13. Numerical calculation of protein-ligand binding rates through solution of the Smoluchowski equation using smoothed particle hydrodynamics

    SciTech Connect (OSTI)

    Pan, Wenxiao; Daily, Michael; Baker, Nathan A.

    2015-05-07

    Background: The calculation of diffusion-controlled ligand binding rates is important for understanding enzyme mechanisms as well as designing enzyme inhibitors. Methods: We demonstrate the accuracy and effectiveness of a Lagrangian particle-based method, smoothed particle hydrodynamics (SPH), to study diffusion in biomolecular systems by numerically solving the time-dependent Smoluchowski equation for continuum diffusion. Unlike previous studies, a reactive Robin boundary condition (BC), rather than the absolute absorbing (Dirichlet) BC, is considered on the reactive boundaries. This new BC treatment allows for the analysis of enzymes with imperfect reaction rates. Results: The numerical method is first verified in simple systems and then applied to the calculation of ligand binding to a mouse acetylcholinesterase (mAChE) monomer. Rates for inhibitor binding to mAChE are calculated at various ionic strengths and compared with experiment and other numerical methods. We find that imposition of the Robin BC improves agreement between calculated and experimental reaction rates. Conclusions: Although this initial application focuses on a single monomer system, our new method provides a framework to explore broader applications of SPH in larger-scale biomolecular complexes by taking advantage of its Lagrangian particle-based nature.

  14. Numerical calculation of protein-ligand binding rates through solution of the Smoluchowski equation using smoothed particle hydrodynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pan, Wenxiao; Daily, Michael; Baker, Nathan A.

    2015-05-07

    Background: The calculation of diffusion-controlled ligand binding rates is important for understanding enzyme mechanisms as well as designing enzyme inhibitors. Methods: We demonstrate the accuracy and effectiveness of a Lagrangian particle-based method, smoothed particle hydrodynamics (SPH), to study diffusion in biomolecular systems by numerically solving the time-dependent Smoluchowski equation for continuum diffusion. Unlike previous studies, a reactive Robin boundary condition (BC), rather than the absolute absorbing (Dirichlet) BC, is considered on the reactive boundaries. This new BC treatment allows for the analysis of enzymes with “imperfect” reaction rates. Results: The numerical method is first verified in simple systems and thenmore » applied to the calculation of ligand binding to a mouse acetylcholinesterase (mAChE) monomer. Rates for inhibitor binding to mAChE are calculated at various ionic strengths and compared with experiment and other numerical methods. We find that imposition of the Robin BC improves agreement between calculated and experimental reaction rates. Conclusions: Although this initial application focuses on a single monomer system, our new method provides a framework to explore broader applications of SPH in larger-scale biomolecular complexes by taking advantage of its Lagrangian particle-based nature.« less

  15. Historical emissions of black and organic carbon aerosol from energy-related combustion, 1850-2000 - article no. GB2018

    SciTech Connect (OSTI)

    Bond, T.C.; Bhardwaj, E.; Dong, R.; Jogani, R.; Jung, S.K.; Roden, C.; Streets, D.G.; Trautmann, N.M.

    2007-05-15

    We present an emission inventory of primary black carbon (BC) and primary organic carbon (OC) aerosols from fossil fuel and biofuel combustion between 1850 and 2000. We reconstruct fossil fuel consumption and represent changes in technology on a national and sectoral basis. Our estimates rely on new estimates of biofuel consumption, and updated emission factors for old technologies. Emissions of black carbon increase almost linearly, totaling about 1000 Gg in 1850, 2200 Gg in 1900, 3000 Gg in 1950, and 4400 Gg in 2000. Primary organic carbon shows a similar pattern, with emissions of 4100 Gg, 5800 Gg, 6700 Gg, and 8700 Gg in 1850, 1900, 1950, and 2000, respectively. Biofuel is responsible for over half of BC emission until about 1890, and dominates energy-related primary OC emission throughout the entire period. Coal contributes the greatest fraction of BC emission between 1880 and 1975, and is overtaken by emissions from biofuel around 1975, and by diesel engines around 1990. Previous work suggests a rapid rise in BC emissions between 1950 and 2000. This work supports a more gradual increase between 1950 and 2000, similar to the increase between 1850 and 1925; implementation of clean technology is a primary reason.

  16. Light absorption from particulate impurities in snow and ice determined by spectrophotometric analysis of filters

    SciTech Connect (OSTI)

    Grenfell, Thomas C.; Doherty, Sarah J.; Clarke, Antony D.; Warren, Stephen G.

    2011-05-10

    Light absorption by particulate impurities in snow and ice can affect the surface albedo and is important for the climate. The absorption properties of these particles can be determined by collecting and melting snow samples and extracting the particulate material by filtration of the meltwater. This paper describes the optical design and testing of a new instrument to measure the absorption spectrum from 400 to 750 nm wavelength of the particles collected on filters using an ''integrating-sandwich'' configuration. The measured absorption is shown to be unaffected by scattering of light from the deposited particulates. A set of calibration standards is used to derive an upper limit for the concentration of black carbon (BC) in the snow. The wavelength dependence of the absorption spectra from 450 to 600 nm is used to calculate an absorption Angstrom exponent for the aerosol. This exponent is used to estimate the actual BC concentration in the snow samples as well as the relative contributions of BC and non-BC constituents to the absorption of solar radiation integrated over the wavelength band 300 to 750 nm.

  17. Delegations - DOE Directives, Delegations, and Requirements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Delegations Current By Functional Area By Position Designations Assignments Rescinded by Website Administrator More filters Less filters Issue Date Start date End date Filters applied Δ Hide filters ∇ Show filters (0) [X] Remove all 604be8a4f5b9904f643538bf983bc723

  18. 08_15_2004.tex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 c,d 35.6 0.6 b,c , p 2, 3, 4, 6, 7, 9, 10, 12 2.32 20 c 3 + ; 1 350 30 c 4, 6, 7, 9, 10, 12 3.5 500 c 2 - 8 4 MeV c 6, 7 10.619 9 0 + ; 2 < 60 12 a See...

  19. CX-011224: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replacement of Deep-Anode Ground Bed Sites for Big Hill Cavern 104 and Site Unit 1 “A”, and BC Cavern 18 CX(s) Applied: B1.3 Date: 10/01/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  20. Concept design and optimization of MSW management system

    SciTech Connect (OSTI)

    Palmer, J.R.

    1999-03-01

    The maximum recovery of recyclables from municipal solid waste (MSW) using material recovery facility (MRF) technologies is determined. Two waste streams at Spangdahlem AB, Germany are analyzed; stationary container wastes and commingled recyclables. Three schemes are considered, one for each waste stream, and one for both. Multi-criteria decision making is the methodology. The criteria are recovery and annual benefit minus cost (B-C). Recovery is determined using the recovery factor transfer function of Diaz et al. (1982). Each technology, or unit operation, in a sequence is independent because particle size distribution of each waste component is considered. B-C is based on revenue from sold recyclables, tipping fees saved by not landfilling separated waste, and manual labor and amortized equipment costs. Six unit operations are considered: eddy current separator (ECS), magnet, air classifier, screen, manual sort, and shredder. Sequences one to six operations long are considered. Three heuristics eliminate 42,179 of 55,986 potential sequences as infeasible. The result is domination by a MRF to process both wastes and a tradeoff between 35.7% recovery of the total at an annual B-C of $0.95 million and recovery of 35.6% at an annual B-C of $1.02 million. Hand sort recovers the most, and is economical.

  1. Spatial and kinematic distributions of transition populations in intermediate redshift galaxy clusters

    SciTech Connect (OSTI)

    Crawford, Steven M.; Wirth, Gregory D.; Bershady, Matthew A. E-mail: wirth@keck.hawaii.edu

    2014-05-01

    We analyze the spatial and velocity distributions of confirmed members in five massive clusters of galaxies at intermediate redshift (0.5 < z < 0.9) to investigate the physical processes driving galaxy evolution. Based on spectral classifications derived from broad- and narrow-band photometry, we define four distinct galaxy populations representing different evolutionary stages: red sequence (RS) galaxies, blue cloud (BC) galaxies, green valley (GV) galaxies, and luminous compact blue galaxies (LCBGs). For each galaxy class, we derive the projected spatial and velocity distribution and characterize the degree of subclustering. We find that RS, BC, and GV galaxies in these clusters have similar velocity distributions, but that BC and GV galaxies tend to avoid the core of the two z ? 0.55 clusters. GV galaxies exhibit subclustering properties similar to RS galaxies, but their radial velocity distribution is significantly platykurtic compared to the RS galaxies. The absence of GV galaxies in the cluster cores may explain their somewhat prolonged star-formation history. The LCBGs appear to have recently fallen into the cluster based on their larger velocity dispersion, absence from the cores of the clusters, and different radial velocity distribution than the RS galaxies. Both LCBG and BC galaxies show a high degree of subclustering on the smallest scales, leading us to conclude that star formation is likely triggered by galaxy-galaxy interactions during infall into the cluster.

  2. An unusual insertion/deletion in the gene encoding the. beta. -subunit of propionyl-CoA carboxylase is a frequent mutation in Caucasian propionic acidemia

    SciTech Connect (OSTI)

    Tahara, T.; Kraus, J.P.; Rosenberg, L.E. )

    1990-02-01

    Propionic acidemia is an inherited disorder of organic acid metabolism that is caused by deficiency of propionly-CoA carboxylase. Affected patients fall into two complementation groups, pccA and pccBC (subgroups B, C, and BC), resulting from deficiency of the nonidentical {alpha} and {beta} subunits of PCC, respectively. The authors have detected an unusual insertion/deletion in the DNA of patients from the pccBC and pccC subgroups that replaces 14 nucleotides in the coding sequence of the {beta} subunit with 12 nucleotides unrelated to this region of the gene. Among 14 unrelated Caucasian patients in the pccBc complementation group, this unique mutation was found in 8 of 28 mutant alleles examined. Mutant allele-specific oligonucleotide hybridization to amplified genomic DNAs revealed that the inserted 12 nucleotides do not originate in an {approx}1000-bp region around the mutation. In the course of the investigation, they identified another mutation in the same exon: a 3-bp in-frame deletion that eliminates one of two isoleucine codons immediately preceding the Msp I site. Two unrelated patients were compound heterozygotes for this single-codon deletion and for the insertion/deletion described above. They conclude that either there is a propensity for the PCC {beta}-subunit gene to undergo mutations of this sort at this position or, more likely, the mutations in all of the involved Caucasian patients have a common origin in preceding generations.

  3. Small Modular Reactors - Key to Future Nuclear Power

    Broader source: Energy.gov (indexed) [DOE]

    Small Modular Reactors - Key to Future Nuclear Power Generation in the U.S. 1,2 Robert Rosner ... b,c Wind (On-shore) 90 9 Solar PV 180 18 Solar Thermal 250 25 Biomass 90-180 9-18 a. ...

  4. Development of an aerosol microphysical module: Aerosol Two-dimensional bin module for foRmation and Aging Simulation (ATRAS)

    SciTech Connect (OSTI)

    Matsui, H.; Koike, Makoto; Kondo, Yutaka; Fast, Jerome D.; Takigawa, M.

    2014-09-30

    Number concentrations, size distributions, and mixing states of aerosols are essential parameters for accurate estimation of aerosol direct and indirect effects. In this study, we developed an aerosol module, designated Aerosol Two-dimensional bin module for foRmation and Aging Simulation (ATRAS), that can represent these parameters explicitly by considering new particle formation (NPF), black carbon (BC) aging, and secondary organic aerosol (SOA) processes. A two-dimensional bin representation is used for particles with dry diameters from 40 nm to 10 m to resolve both aerosol size (12 bins) and BC mixing state (10 bins) for a total of 120 bins. The particles with diameters from 1 to 40 nm are resolved using an additional 8 size bins to calculate NPF. The ATRAS module was implemented in the WRF-chem model and applied to examine the sensitivity of simulated mass, number, size distributions, and optical and radiative parameters of aerosols to NPF, BC aging and SOA processes over East Asia during the spring of 2009. BC absorption enhancement by coating materials was about 50% over East Asia during the spring, and the contribution of SOA processes to the absorption enhancement was estimated to be 10 20% over northern East Asia and 20 35% over southern East Asia. A clear north-south contrast was also found between the impacts of NPF and SOA processes on cloud condensation nuclei (CCN) concentrations: NPF increased CCN concentrations at higher supersaturations (smaller particles) over northern East Asia, whereas SOA increased CCN concentrations at lower supersaturations (larger particles) over southern East Asia. Application of ATRAS to East Asia also showed that the impact of each process on each optical and radiative parameter depended strongly on the process and the parameter in question. The module can be used in the future as a benchmark model to evaluate the accuracy of simpler aerosol models and examine interactions between NPF, BC aging, and SOA processes

  5. Dissecting the cAMP-inducible allosteric switch in protein kinase A RI alpha

    SciTech Connect (OSTI)

    Sjoberg, T.J.; Kornev, A.P.; Taylor, S.S.; /SLAC

    2012-08-23

    The regulatory subunits of cAMP-dependent protein kinase (PKA) are the major receptors of cAMP in most eukaryotic cells. As the cyclic nucleotide binding (CNB) domains release cAMP and bind to the catalytic subunit of PKA, they undergo a major conformational change. The change is mediated by the B/C helix in CNB-A, which extends into one long helix that now separates the two CNB domains and docks onto the surface of the catalytic subunit. We explore here the role of three key residues on the B/C helix that dock onto the catalytic subunit, Arg226, Leu233, and Met 234. By replacing each residue with Ala, we show that each contributes significantly to creating the R:C interface. By also deleting the second CNB domain (CNB-B), we show furthermore that CNB-B is a critical part of the cAMP-induced conformational switch that dislodges the B/C helix from the surface of the catalytic subunit. Without CNB-B the K{sub a} for activation by cAMP increases from 80 to 1000 nM. Replacing any of the key interface residues with Ala reduces the K{sub a} to 25-40 nM. Leu233 and M234 contribute to a hydrophobic latch that binds the B/C helix onto the large lobe of the C-subunit, while Arg226 is part of an electrostatic switch that couples the B/C helix to the phosphate binding cassette where the cAMP docks.

  6. Single-Centre Experience with Percutaneous Cryoablation of Breast Cancer in 23 Consecutive Non-surgical Patients

    SciTech Connect (OSTI)

    Cazzato, Roberto Luigi; Lara, Christine Tunon de; Buy, Xavier Ferron, Stéphane Hurtevent, Gabrielle; Fournier, Marion; Debled, Marc; Palussière, Jean

    2015-10-15

    AimTo present our single-centre prospective experience on the use of cryoablation (CA) applied to treat primary breast cancer (BC) in a cohort of patients unsuitable for surgical treatment.Materials and MethodsTwenty-three consecutive post-menopausal female patients (median age 85 years; range 56–96) underwent percutaneous CA of unifocal, biopsy-proven BC, under ultrasound/computed tomography (US/CT) guidance. Clinical and dynamic contrast-enhanced magnetic resonance imaging (DCE-MRI) follow-ups were systematically scheduled at 3, 12, 18 and 24 months. Local tumour control was assessed by comparing baseline and follow-up DCE-MRI.ResultsTwenty-three BC (median size 14 mm) were treated under local anaesthesia (78.3 %) or local anaesthesia and conscious sedation (21.7 %). Median number of cryo-probes applied per session was 2.0. A “dual-freezing” protocol was applied for the first ten patients and a more aggressive “triple-freezing” protocol for the remaining 13. Median follow-up was 14.6 months. Five patients recurred during follow-up and two were successfully re-treated with CA. Five patients presented immediate CA-related complications: four hematomas evolved uneventfully at 3-month follow-up and one skin burn resulted in skin inflammation and skin retraction at 3 and 12 months, respectively.ConclusionsPercutaneous CA is safe and well tolerated for non-resected elderly BC patients. Procedures can be proposed under local anaesthesia only. Given the insulation properties of the breast gland, aggressive CA protocols are required. Prospective studies are needed to better understand the potential role of CA in the local treatment of early BC.

  7. Bromocriptine increased operant responding for high fat food but decreased chow intake in both obesity-prone and resistant rats

    SciTech Connect (OSTI)

    Thanos, P.K.; Wang, G.; Thanos, P.K.; Cho, J. Kim, R.; Michaelides, M.; Primeaux, S.; Bray, G.; Wang, G.-J.; Volkow, N.D.

    2010-10-27

    Dopamine (DA) and DAD{sub 2} receptors (D2R) have been implicated in obesity and are thought to be involved in the rewarding properties of food. Osborne-Mendel (OM) rats are susceptible to diet induced obesity (DIO) while S5B/P (S5B) rats are resistant when given a high-fat diet. Here we hypothesized that the two strains would differ in high-fat food self-administration (FSA) and that the D2R agonist bromocriptine (BC) would differently affect their behavior. Ad-libitum fed OM and S5B/P rats were tested in a FSA operant chamber and were trained to lever press for high-fat food pellets under a fixed-ratio (FR1) and a progressive ratio (PR) schedule. After sixteen days of PR sessions, rats were treated with three different doses of BC (1, 10 and 20 mg/kg). No significant differences were found between the two strains in the number of active lever presses. BC treatment (10 mg/kg and 20 mg/kg) increased the number of active lever presses (10 mg/kg having the strongest effect) whereas it decreased rat chow intake in the home cage with equivalent effects in both strains. These effects were not observed on the day of BC administration but on the day following its administration. Our results suggest that these two strains have similar motivation for procuring high fat food using this paradigm. BC increased operant responding for high-fat pellets but decreased chow intake in both strains, suggesting that D2R stimulation may have enhanced the motivational drive to procure the fatty food while correspondingly decreasing the intake of regular food. These findings suggest that susceptibility to dietary obesity (prior to the onset of obesity) may not affect operant motivation for a palatable high fat food and that differential susceptibility to obesity may be related to differential sensitivity to D2R stimulation.

  8. Quantification of online removal of refractory black carbon using laser-induced incandescence in the single particle soot photometer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aiken, Allison C.; McMeeking, Gavin R.; Levin, Ezra J. T.; Dubey, Manvendra K.; DeMott, Paul J.; Kreidenweis, Sonia M.

    2016-04-05

    Refractory black carbon (rBC) is an aerosol that has important impacts on climate and human health. rBC is often mixed with other species, making it difficult to isolate and quantify its important effects on physical and optical properties of ambient aerosol. To solve this measurement challenge, a new method to remove rBC was developed using laser-induced incandescence (LII) by Levin et al. in 2014. Application of the method with the Single Particle Soot Photometer (SP2) is used to determine the effects of rBC on ice nucleating particles (INP). Here, we quantify the efficacy of the method in the laboratory usingmore » the rBC surrogate Aquadag. Polydisperse and mobility-selected samples (100–500 nm diameter, 0.44–36.05 fg), are quantified by a second SP2. Removal rates are reported by mass and number. For the mobility-selected samples, the average percentages removed by mass and number of the original size are 88.9 ± 18.6% and 87.3 ± 21.9%, respectively. Removal of Aquadag is efficient for particles >100 nm mass-equivalent diameter (dme), enabling application for microphysical studies. However, the removal of particles ≤100 nm dme is less efficient. Absorption and scattering measurements are reported to assess its use to isolate brown carbon (BrC) absorption. Scattering removal rates for the mobility-selected samples are >90% on average, yet absorption rates are 53% on average across all wavelengths. Therefore, application to isolate effects of microphysical properties determined by larger sizes is promising, but will be challenging for optical properties. Lastly, the results reported also have implications for other instruments employing internal LII, e.g., the Soot Particle Aerosol Mass Spectrometer (SP-AMS).« less

  9. OzDES multifibre spectroscopy for the Dark Energy Survey: First-year operation and results

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yuan, Fang

    2015-07-29

    The Australian Dark Energy Survey (OzDES) is a five-year, 100-night, spectroscopic survey on the Anglo-Australian Telescope, whose primary aim is to measure redshifts of approximately 2500 Type Ia supernovae host galaxies over the redshift range 0.1 < z < 1.2, and derive reverberation-mapped black hole masses for approximately 500 active galactic nuclei and quasars over 0.3 < z < 4.5. This treasure trove of data forms a major part of the spectroscopic follow-up for the Dark Energy Survey for which we are also targeting cluster galaxies, radio galaxies, strong lenses, and unidentified transients, as well as measuring luminous red galaxiesmore » and emission line galaxies to help calibrate photometric redshifts. Here, we present an overview of the OzDES programme and our first-year results. Between 2012 December and 2013 December, we observed over 10 000 objects and measured more than 6 000 redshifts. Our strategy of retargeting faint objects across many observing runs has allowed us to measure redshifts for galaxies as faint as mr = 25 mag. We outline our target selection and observing strategy, quantify the redshift success rate for different types of targets, and discuss the implications for our main science goals. In conclusion, we highlight a few interesting objects as examples of the fortuitous yet not totally unexpected discoveries that can come from such a large spectroscopic survey.« less

  10. OzDES multifibre spectroscopy for the Dark Energy Survey: First-year operation and results

    SciTech Connect (OSTI)

    Yuan, Fang

    2015-07-29

    The Australian Dark Energy Survey (OzDES) is a five-year, 100-night, spectroscopic survey on the Anglo-Australian Telescope, whose primary aim is to measure redshifts of approximately 2500 Type Ia supernovae host galaxies over the redshift range 0.1 < z < 1.2, and derive reverberation-mapped black hole masses for approximately 500 active galactic nuclei and quasars over 0.3 < z < 4.5. This treasure trove of data forms a major part of the spectroscopic follow-up for the Dark Energy Survey for which we are also targeting cluster galaxies, radio galaxies, strong lenses, and unidentified transients, as well as measuring luminous red galaxies and emission line galaxies to help calibrate photometric redshifts. Here, we present an overview of the OzDES programme and our first-year results. Between 2012 December and 2013 December, we observed over 10 000 objects and measured more than 6 000 redshifts. Our strategy of retargeting faint objects across many observing runs has allowed us to measure redshifts for galaxies as faint as mr = 25 mag. We outline our target selection and observing strategy, quantify the redshift success rate for different types of targets, and discuss the implications for our main science goals. In conclusion, we highlight a few interesting objects as examples of the fortuitous yet not totally unexpected discoveries that can come from such a large spectroscopic survey.

  11. Sensitivity studies on the impacts of Tibetan Plateau snowpack pollution on the Asian hydrological cycle and monsoon climate

    SciTech Connect (OSTI)

    Qian, Yun; Flanner, M. G.; Leung, Lai-Yung R.; Wang, Weiguo

    2011-03-02

    The Tibetan Plateau (TP), the highest and largest plateau in the world, has long been identified to be critical in regulating the Asian monsoon climate and hydrological cycle. The snowpack and glaciers over the TP provide fresh water to billions of people in Asian countries, but the TP glaciers have been retreating extensively at a speed faster than any other part of the world. In this study a series of experiments with a global climate model are designed to simulate black carbon (BC) and dust in snow and their radiative forcing and to assess the relative impacts of anthropogenic CO2 and carbonaceous particles in the atmosphere and snow, respectively, on the snowpack over the TP, as well as their subsequent impacts on the Asian monsoon climate and hydrological cycle. Results show a large BC content in snow over the TP, especially the southern slope, with concentration larger than 100 k/kg. Because of the high aerosol content in snow and large incident solar radiation in the low latitude and high elevation, the TP exhibits the largest surface radiative forcing induced by aerosols (e.g. BC, Dust) in snow compared to other snow-covered regions in the world. The aerosol-induced snow albedo perturbations generate surface radiative forcing of 5-25 W m-2 during spring, with a maximum in April or May. BC-in-snow increases the surface air temperature by around 1.0oC averaged over the TP and reduces snowpack over the TP more than that induced by pre-industrial to present CO2 increase and carbonaceous particles in the atmosphere during spring. As a result, runoff increases during late winter and early spring but decreases during late spring and early summer (i.e. a trend toward earlier melt dates). The snowmelt efficacy, defined as the snowpack reduction per unit degree of warming induced by the forcing agent, is 1-4 times larger for BC-in-snow than CO2 increase during April-July, indicating that BC-in-snow more efficiently accelerates snowmelt because the increased net

  12. Molecular Siganture and Sources of Biochemical Recalcitrance of Organic C in Amozonian Dark Earths

    SciTech Connect (OSTI)

    Solomon,D.; Lehmann, J.; Thies, J.; Schafer, T.; Liang, B.; Kinyangi, J.; Neves, E.; Peterson, J.; Liuzao, F.; Skjemstad, J.

    2007-01-01

    Amazonian Dark Earths (ADE) are a unique type of soils developed through intense anthropogenic activities that transformed the original soils into Anthrosols throughout the Brazilian Amazon Basin. We conducted a comparative molecular-level investigation of soil organic C (SOC) speciation in ADE (ages between 600 and 8700 years B.P.) and adjacent soils using ultraviolet photo-oxidation coupled with {sup 13}C cross polarization-magic angle spinning nuclear magnetic resonance (CP-MAS NMR), synchrotron-based Fourier transform infrared-attenuated total reflectance (Sr-FTIR-ATR) and C (1s) near edge X-ray absorption fine structure (NEXAFS) spectroscopy to obtain deeper insights into the structural chemistry and sources of refractory organic C compounds in ADE. Our results show that the functional group chemistry of SOC in ADE was considerably different from adjacent soils. The SOC in ADE was enriched with: (i) aromatic-C structures mostly from H- and C-substituted aryl-C, (ii) O-rich organic C forms from carboxylic-C, aldehyde-C, ketonic-C and quinine-C, and (iii) diverse group of refractory aliphatic-C moieties. The SOC in adjacent soils was predominantly composed of O-alkyl-C and methoxyl-C/N-alkyl-C structures and elements of labile aliphatic-C functionalities. Our study suggests that the inherent molecular structures of organic C due to selective accumulation of highly refractory aryl-C structures seems to be the key factor for the biochemical recalcitrance and stability of SOC in ADE. Anthropogenic enrichment with charred carbonaceous residues from biomass-derived black C (BC) is presumed to be the precursor of these recalcitrant polyaromatic structures. Our results also highlight the complementary role that might be played by organic C compounds composed of O-containing organic C moieties and aliphatic-C structures that persisted for millennia in these anthropic soils as additional or secondary sources of chemical recalcitrance of SOC in ADE. These organic C

  13. A Study of the Optical Properties of Ice Crystals with Black Carbon Inclusions

    SciTech Connect (OSTI)

    Arienti, Marco; Yang, Xiaoyuan; Kopacz, Adrian M; Geier, Manfred

    2015-09-01

    The report focu ses on the modification of the optical properties of ice crystals due to atmospheric black car bon (BC) contamination : the objective is to advance the predictive capabilities of climate models through an improved understanding of the radiative properties of compound particles . The shape of the ice crystal (as commonly found in cirrus clouds and cont rails) , the volume fraction of the BC inclusion , and its location inside the crystal are the three factors examined in this study. In the multiscale description of this problem, where a small absorbing inclusion modifies the optical properties of a much la rger non - absorbing particle, state - of - the - art discretization techniques are combined to provide the best compromise of flexibility and accuracy over a broad range of sizes .

  14. Near-Term Climate Mitigation by Short-Lived Forcers

    SciTech Connect (OSTI)

    Smith, Steven J.; Mizrahi, Andrew H.

    2013-08-12

    Emissions reductions focused on anthropogenic climate forcing agents with relatively short atmospheric lifetimes such as methane (CH4) and black carbon (BC) have been suggested as a strategy to reduce the rate of climate change over the next several decades. We find that reductions of methane and BC would likely have only a modest impact on near-term climate warming. Even with maximally feasible reductions phased in from 2015 to 2035, global mean temperatures in 2050 are reduced by 0.16 °C, with an uncertainty range of 0.04-0.36°C, with the high end of this range only possible if total historical aerosol forcing is small. More realistic mitigation scenarios would likely provide a smaller climate benefit. The climate benefits from targeted reductions in short-lived forcing agents are smaller than previously estimated and are not substantially different in magnitude from the benefits due to a comprehensive climate policy.

  15. Measurement of the B-cmeson lifetime in the decay B-c→J/ψπ⁻

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aaltonen, T.; Álvarez González, B.; Amerio, S.; Amidei, D.; Anastassov, A.; Annovi, A.; Antos, J.; Apollinari, G.; Appel, J. A.; Arisawa, T.; et al

    2013-01-02

    The lifetime of the B-c meson is measured using 272 exclusive B-c→J/ψ(→μ⁺μ⁻)π⁻ decays reconstructed in data from proton-antiproton collisions corresponding to an integrated luminosity of 6.7 fb⁻¹ recorded by the CDF II detector at the Fermilab Tevatron. The lifetime of the B-cmeson is measured to be τ(B-c)=0.452±0.048(stat)±0.027(syst) ps. This is the first measurement of the B-c meson lifetime in a fully reconstructed hadronic channel, and it agrees with previous results and has comparable precision.

  16. Pacific Northwest Storms Situation Report # 7

    SciTech Connect (OSTI)

    2006-12-21

    Despite a small storm that came through the area last night with wind gusts peaking at 45 MPH, progress continues to be made in restoring power to customers who lost power during the December 14-15 storms which hit the Pacific Northwest region. Currently, 95,971 customers remain without power, down from 1.8 million customers. The wind storm which affected the area yesterday was not as bad as previously expected, with the majority of the customer outages in the BC Hydro region, and 3,000 additional customer outages in the Puget Sound Energy service area. The customers without power represent 5 percent of customers in the affected utility service areas of Washington. The majority of customers without power are served by Puget Sound Energy, BC Hydro, and Seattle City Light.

  17. RANDOM BALLISTIC INTERPRETATION OF NONLINEAR GUIDING CENTER THEORY

    SciTech Connect (OSTI)

    Ruffolo, D.; Pianpanit, T.; Matthaeus, W. H.; Chuychai, P. E-mail: th_ee@hotmail.com E-mail: p.chuychai@sci.mfu.ac.th

    2012-03-10

    Nonlinear guiding center (NLGC) theory has been used to explain the asymptotic perpendicular diffusion coefficient {kappa} of energetic charged particles in a turbulent magnetic field, which can be applied to better understand cosmic ray transport. Here we re-derive NLGC, replacing the assumption of diffusive decorrelation with random ballistic decorrelation (RBD), which yields an explicit formula for {kappa} . We note that scattering processes can cause a reversal of the guiding center motion along the field line, i.e., 'backtracking', leading to partial cancellation of contributions to {kappa}, especially for low-wavenumber components of the magnetic turbulence. We therefore include a heuristic backtracking correction (BC) that can be used in combination with RBD. In comparison with computer simulation results for various cases, NLGC with RBD and BC provides a substantially improved characterization of the perpendicular diffusion coefficient for a fluctuation amplitude less than or equal to the large-scale magnetic field.

  18. Measurement of boron and carbon fluxes in cosmic rays with the PAMELA experiment

    SciTech Connect (OSTI)

    Adriani, O.; Bongi, M.; Barbarino, G. C.; Bazilevskaya, G. A.; Bellotti, R.; Bruno, A.; Boezio, M.; Bonvicini, V.; Carbone, R.; Bogomolov, E. A.; Bottai, S.; Cafagna, F.; Campana, D.; Carlson, P.; Casolino, M.; De Donato, C.; De Santis, C.; De Simone, N.; Castellini, G.; Danilchenko, I. A.; and others

    2014-08-20

    The propagation of cosmic rays inside our galaxy plays a fundamental role in shaping their injection spectra into those observed at Earth. One of the best tools to investigate this issue is the ratio of fluxes for secondary and primary species. The boron-to-carbon (B/C) ratio, in particular, is a sensitive probe to investigate propagation mechanisms. This paper presents new measurements of the absolute fluxes of boron and carbon nuclei as well as the B/C ratio from the PAMELA space experiment. The results span the range 0.44-129 GeV/n in kinetic energy for data taken in the period 2006 July to 2008 March.

  19. CO2 Supermarket Refrigeration Systems for Southeast Asia and the USA

    SciTech Connect (OSTI)

    Sharma, Vishaldeep; Fricke, Brian A; Bansal, Pradeep

    2014-01-01

    This paper presents a comparative analysis of the annual energy consumption of these refrigeration systems in eighty eight cities from all climate zones in Southeast Asia. Also, the performance of the CO2 refrigeration systems is compared to the baseline R404A multiplex direct expansion (DX) system. Finally, the overall performance of the CO2 refrigeration systems in various climatic conditions in Southeast Asia is compared to that in the United States. For the refrigeration systems investigated, it was found that the Transcritical Booster System with Bypass Compressor (TBS-BC) performs better or equivalent to the R404A multiplex DX system in the northern regions of Southeast Asia (China and Japan). In the southern regions of Southeast Asia (India, Bangladesh, Burma), the R404A multiplex DX system and the Combined Secondary Cascade (CSC) system performs better than the TBS-BC.

  20. Revised DOE Acquisition Guide Chapter 71.1 Headquarters Business Clearance

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process | Department of Energy 71.1 Headquarters Business Clearance Process Revised DOE Acquisition Guide Chapter 71.1 Headquarters Business Clearance Process There was mention in the National Academy of Public Administration (NAPA) report titled "Managing at the Speed of Light - Improving Mission Support Performance" that Departmental procurement personnel don't understand the Business Clearance (BC) process. In an effort to address this issue, each Procurement Director (PD) and

  1. The Secretary of Energy

    Office of Legacy Management (LM)

    ' The Secretary of Energy cj L. _ Washington. bC 20585 1 .) :-. . . The .Honora.l$eZ William S. Cohen . Secretary ofDefense Washington, D.C. 203Oi .' .&a.rMr.Secietary: ' , ' - a- - * . ' The Congress recently sent to the President for signature the Energy and Water Development Appropriations Act, 1998. Among other provisions, this bill would immediately transfer responsibility for the Forrnerly' Utilized Sites Remedial Action Program (FUSRAP) from the Department of Energy to the United

  2. The Secretary of Energy

    Office of Legacy Management (LM)

    The Secretary of Energy 0 ' -. . . _ Washington, bC 20585 . October 10, 1997 ' , :-. The FIonorable% William S. Cohen : Secretary ofijefense Washington, D.C. 203Oi -' 8 1 .' *- . A .' JharMiSecietary: , ' The Congress recently sent to the Fresident for signature the Energy and Water ' Development Appropriations Act, 1998. Among other provisions, this bill would immediately transfer responsibility for the Formerly Utilized Sites Remedial Action Program (FUSRAP) from the Department -of Energy to

  3. The Secretary of Energy

    Office of Legacy Management (LM)

    The Secretary of Energy Washington. bC-20585 -.. October 10, 1997 . - The Honorable Wlliam S. Cohen ' Secretary ofDefense Washington, D.C. 2030' 1 Dear Mr. Secremy: ' The Congress recently sent to the President for signature the Energy and Water Development Appropriations A&' 1998. Among other provisions, this bill would immediately transfer responsibility for the Formerly ' Utilized Sites Remedial Action Program (FUSMP) from the Department of Energy to the United States Army Corps of

  4. One-Dimensional Nanostructures for Neutron Detection

    SciTech Connect (OSTI)

    Zhu, Yong; Eapen, Jacob; Hawari, Ayman

    2015-05-04

    This report consists of four parts in addition to a publication/presentation list. Part I is on electronic structure simulations on boron nitride (BN) and BCxN nanotubes using density function theory (DFT), Part II is on fabrication and characterization of nanowire sensors, Part III is on irradiation response of BN nanotubes using molecular dynamics (MD) simulations, and Part IV is on the in-situ transmission electron microscopy (TEM) study of irradiation response of BN nanotubes.

  5. The

    Office of Legacy Management (LM)

    blA.o$-/3 The _ Secretary of Energy 0 .- Washington. bC 20585 October 10, 1997 . . The Honorable William S. Cohen Secretary ofDefense Washington, DC. 20301 .. 1 .- QearMr. Secietary: ' . The Congress recently sent to the President for signature the Energy and Water Development Appropriations Act,' 1998. Among other provisions, this bill would immediately transfer responsibility for the Formerly~Utilized Sites Remedial Action Program (FUSRAP) from the Department of Energy to the United Strites

  6. The .Hoiorable William S. Cohen'

    Office of Legacy Management (LM)

    Secretary of Energy' Washington, bC 20585 October 10, 1997 ' . , :. . The .Hoiorable William S. Cohen' Secretary of' eefense Washing+, D.C. 203Oi .' Dear Mr. Se&etm: ,_ -_ . . ' ,I. ' . a- / 4 ' . \ ' . The Congr&s recently se$ tp the President for signature the' Energy and Water Development Appropriations Act, 1998. Among other provi$ions, this bill would immediately transfer responsibility forthe Formerly:U&zed Sites Remedial Action . Program (FUSRAP) from the Department of Energy

  7. The IIonorable W

    Office of Legacy Management (LM)

    . ' -. _ The Secretary of Energy Washington, bC 20585 October 10, 1997 ' The IIonorable W illiam S. Cohen : Secretary ofDefense t. " .,.. ,- - Washington, D.C. 20301 .. 5 &arMr. Secietay: . * ' : The Congress recently sent to the President for signature the Ene&y and Water Development Appropriations Act,' 1998. Among other provisions, this bill would immediately transfer responsibility for the Formerly ' Utilized Sites Remedial Action Program (FUSRAP) from the Department of Energy

  8. The Secretary of Energy

    Office of Legacy Management (LM)

    The Secretary of Energy 0, .: ., Washington, bC-20585 . . October 10, 19g7 ' , .-. , The Honorable W illiam S. Cohen Secretary ofDefense Washington, D.C. 203Oi .. . . &arMi.Se&etaQ: ~ , . ' . The Congress recently sent to the President for signature the Energy and Water . Development Appropriations Act,' 1998. Among other provisions, this bill would immediately transfer responsibility for' the Formerly~Utilized Sites Remedial Action Program (FUSRAP) from the Department of Energy to the

  9. The Secretary of Energy'

    Office of Legacy Management (LM)

    :c> 2" ' $,,. I ,- ; ' . The Secretary of Energy' 0 "-. Washington. bC 20585 ._. . . October 10, 1997 ' \ . : ' . Y' . -. - The Honorable Wdliam S. Cohen " Smetary ofDefense Washington, D.C. 20301 .' .&r Mr. Secretary: f : ,~The' Congress recently sent to,the ,President' for signature the Energy and Water Development Appropriations Act, 1998., ;Among other provisions, ,this bi would immediately transfer responsibility for the Formerly~Utilized Sites Remedial Action Program

  10. DRAFT Central Plateau Cleanup Strategy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    J.D. Dowell: DOE-RL John Price: Ecology Dennis Faulk: EPA October 9, 2012 2 River Corridor * 100 Area interim actions extended to - Incorporate 154 additional waste sites - Address prior extensive deep excavation of hexavalent chromium contamination * 100 Area decision documents - Extend 100 B/C decision documents schedule to enable collection of additional groundwater data for cleanup decision - Delay 100-N document several months to avoid overlap of public comment 3 River Corridor * 100 Area -

  11. CARES: Carbonaceous Aerosol and Radiative Effects Study Science Plan

    SciTech Connect (OSTI)

    Zaveri, RA; Shaw, WJ; Cziczo, DJ

    2010-05-27

    Carbonaceous aerosol components, which include black carbon (BC), urban primary organic aerosols (POA), biomass burning aerosols, and secondary organic aerosols (SOA) from both urban and biogenic precursors, have been previously shown to play a major role in the direct and indirect radiative forcing of climate. The primary objective of the CARES 2010 intensive field study is to investigate the evolution of carbonaceous aerosols of different types and their effects on optical and cloud formation properties.

  12. Using SA508/533 for the HTGR Vessel Material

    SciTech Connect (OSTI)

    Larry Demick

    2012-06-01

    This paper examines the influence of High Temperature Gas-cooled Reactor (HTGR) module power rating and normal operating temperatures on the use of SA508/533 material for the HTGR vessel system with emphasis on the calculated times at elevated temperatures approaching or exceeding ASME Code Service Limits (Levels B&C) to which the reactor pressure vessel could be exposed during postulated pressurized and depressurized conduction cooldown events over its design lifetime.

  13. Simulating Black Carbon and Dust and their Radiative Forcing in Seasonal Snow: A Case Study over North China with Field Campaign Measurements

    SciTech Connect (OSTI)

    Zhao, Chun; Hu, Zhiyuan; Qian, Yun; Leung, Lai-Yung R.; Huang, J.; Huang, Maoyi; Jin, Jiming; Flanner, M. G.; Zhang, Rudong; Wang, Hailong; Yan, Huiping; Lu, Zifeng; Streets, D. G.

    2014-10-30

    A state-of-the-art regional model, WRF-Chem, is coupled with the SNICAR model that includes the sophisticated representation of snow metamorphism processes available for climate study. The coupled model is used to simulate the black carbon (BC) and dust concentrations and their radiative forcing in seasonal snow over North China in January-February of 2010, with extensive field measurements used to evaluate the model performance. In general, the model simulated spatial variability of BC and dust mass concentrations in the top snow layer (hereafter BCS and DSTS, respectively) are quantitatively or qualitatively consistent with observations. The model generally moderately underestimates BCS in the clean regions but significantly overestimates BCS in some polluted regions. Most model results fall into the uncertainty ranges of observations. The simulated BCS and DSTS are highest with >5000 ng g-1 and up to 5 mg g-1, respectively, over the source regions and reduce to <50 ng g-1 and <1 ?g g-1, respectively, in the remote regions. BCS and DSTS introduce similar magnitude of radiative warming (~10 W m-2) in snowpack, which is comparable to the magnitude of surface radiative cooling due to BC and dust in the atmosphere. This study represents the first effort in using a regional modeling framework to simulate BC and dust and their direct radiative forcing in snow. Although a variety of observational datasets have been used to attribute model biases, some uncertainties in the results remain, which highlights the need for more observations, particularly concurrent measurements of atmospheric and snow aerosols and the deposition fluxes of aerosols, in future campaigns.

  14. Seminar Series | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Seminar Series Seminar Series Dr. Tristram Kidder Ancient Lessons for Modern Times: An Environmental History of the Yellow River, China, 5000-2000 BC Donald Ort Too Green? Dr. Terry Bricker Structural Interactions of the Extrinsic Proteins in Higher Plant Photosystem II Dr. David Tiede "Wiring Photosynthetic and Redox Proteins for Solar Fuels Function" Dr. Su Lin "Electron Transfer Kinetics in Bacterial Reaction Center" Dr. Donald Bryant "Far-red light photoacclimation

  15. 2013 DOE Bioenergy Technologies Office (BETO) Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biochemical Feedstock Supply Interface Garold Gresham, INL Nick Nagle, NREL May 20, 2013 2 | Bioenergy Technologies Office eere.energy.gov Goals: Support Biochemical Conversion Pathway: "reducing the cost of converting lignocellulosic biomass to sugars and other fuels intermediates." 1 - Facilitate establishment of pathway(s) toward optimization and cost-reduction; 2 - Develop tools & models to evaluate feedstock costs & quality for BC conversion process (biological, chemical,

  16. predictive-models | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    predictive-models DOE/BC-88/1/SP. EOR Predictive Models: Handbook for Personal Computer Versions of Enhanced Oil Recovery Predictive Models. BPO Staff. February 1988. 76 pp. NTIS Order No. DE89001204. FORTRAN source code and executable programs for the five EOR Predictive Models shown below are available. The five recovery processes modeled are Steamflood, In-Situ Combustion, Polymer, Chemical Flooding, and CO2 Miscible Flooding. The models are available individually. Min Req.: IBM PC/XT, PS-2,

  17. SNP in TXNRD2 Associated With Radiation-Induced Fibrosis: A Study of Genetic Variation in Reactive Oxygen Species Metabolism and Signaling

    SciTech Connect (OSTI)

    Edvardsen, Hege; K. G. Jebsen Breast cancer centre, Institute for Clinical Medicine, University of Oslo, Oslo ; Landmark-Hyvik, Hege; K. G. Jebsen Breast cancer centre, Institute for Clinical Medicine, University of Oslo, Oslo ; Reinertsen, Kristin V.; Zhao, Xi; K. G. Jebsen Breast cancer centre, Institute for Clinical Medicine, University of Oslo, Oslo ; Grenaker-Alns, Grethe Irene; Nebdal, Daniel; Syvnen, Ann-Christine; Rdningen, Olaug; Alsner, Jan; Overgaard, Jens; Borresen-Dale, Anne-Lise; K. G. Jebsen Breast cancer centre, Institute for Clinical Medicine, University of Oslo, Oslo ; Foss, Sophie D.; National Resource Centre for Late Effects after Cancer Treatment, OUS Radiumhospitalet, Oslo ; Kristensen, Vessela N.; K. G. Jebsen Breast cancer centre, Institute for Clinical Medicine, University of Oslo, Oslo; Department of Clinical Molecular Biology , Division of Medicine, Ahus University Hospital

    2013-07-15

    Purpose: The aim of the study was to identify noninvasive markers of treatment-induced side effects. Reactive oxygen species (ROS) are generated after irradiation, and genetic variation in genes related to ROS metabolism might influence the level of radiation-induced adverse effects (AEs). Methods and Materials: 92 breast cancer (BC) survivors previously treated with hypofractionated radiation therapy were assessed for the AEs subcutaneous atrophy and fibrosis, costal fractures, lung fibrosis, pleural thickening, and telangiectasias (median follow-up time 17.1 years). Single-nucleotide polymorphisms (SNPs) in 203 genes were analyzed for association to AE grade. SNPs associated with subcutaneous fibrosis were validated in an independent BC survivor material (n=283). The influence of the studied genetic variation on messenger ribonucleic acid (mRNA) expression level of 18 genes previously associated with fibrosis was assessed in fibroblast cell lines from BC patients. Results: Subcutaneous fibrosis and atrophy had the highest correlation (r=0.76) of all assessed AEs. The nonsynonymous SNP rs1139793 in TXNRD2 was associated with grade of subcutaneous fibrosis, the reference T-allele being more prevalent in the group experiencing severe levels of fibrosis. This was confirmed in another sample cohort of 283 BC survivors, and rs1139793 was found significantly associated with mRNA expression level of TXNRD2 in blood. Genetic variation in 24 ROS-related genes, including EGFR, CENPE, APEX1, and GSTP1, was associated with mRNA expression of 14 genes previously linked to fibrosis (P?.005). Conclusion: Development of subcutaneous fibrosis can be associated with genetic variation in the mitochondrial enzyme TXNRD2, critically involved in removal of ROS, and maintenance of the intracellular redox balance.

  18. Tuning a RANS k-e model for jet-in-crossflow simulations.

    SciTech Connect (OSTI)

    Lefantzi, Sophia; Ray, Jaideep; Arunajatesan, Srinivasan; DeChant, Lawrence Justin

    2013-09-01

    We develop a novel calibration approach to address the problem of predictive ke RANS simulations of jet-incrossflow. Our approach is based on the hypothesis that predictive ke parameters can be obtained by estimating them from a strongly vortical flow, specifically, flow over a square cylinder. In this study, we estimate three ke parameters, C%CE%BC, Ce2 and Ce1 by fitting 2D RANS simulations to experimental data. We use polynomial surrogates of 2D RANS for this purpose. We conduct an ensemble of 2D RANS runs using samples of (C%CE%BC;Ce2;Ce1) and regress Reynolds stresses to the samples using a simple polynomial. We then use this surrogate of the 2D RANS model to infer a joint distribution for the ke parameters by solving a Bayesian inverse problem, conditioned on the experimental data. The calibrated (C%CE%BC;Ce2;Ce1) distribution is used to seed an ensemble of 3D jet-in-crossflow simulations. We compare the ensemble's predictions of the flowfield, at two planes, to PIV measurements and estimate the predictive skill of the calibrated 3D RANS model. We also compare it against 3D RANS predictions using the nominal (uncalibrated) values of (C%CE%BC;Ce2;Ce1), and find that calibration delivers a significant improvement to the predictive skill of the 3D RANS model. We repeat the calibration using surrogate models based on kriging and find that the calibration, based on these more accurate models, is not much better that those obtained with simple polynomial surrogates. We discuss the reasons for this rather surprising outcome.

  19. Barrow Black Carbon Source and Impact Study Final Campaign Report

    SciTech Connect (OSTI)

    Barrett, Tate

    2014-07-01

    The goal of the Barrow Black Carbon Source and Impact campaign was to characterize the concentration and isotopic composition of carbonaceous atmospheric particulate matter (PM) at the Atmospheric Radiation Measurement (ARM) Climate Research Facility site in Barrow, Alaska. The carbonaceous component was characterized by measuring the organic and black carbon (OC and BC) components of the total PM. To facilitate complete characterization of the PM, filter-based collections were used, including a medium volume PM2.5 sampler and a high volume PM10 sampler. Thirty-eight fine PM fractions (PM2.5) and 49 coarse (PM10) PM fractions were collected at weekly and bi-monthly intervals. The PM2.5 sampler operated with minimal maintenance during the 12 month campaign. The PM10 sampler used for the Barrow Black Carbon Source and Impact (BBCSI) study used standard Tisch “hi-vol” motors that have a known lifetime of approximately 1 month under constant use; this necessitated monthly maintenance, and it is suggested that, for future deployment in the Arctic, the motors be upgraded to industrial blowers. The BBCSI sampling campaign successfully collected and archived 87 ambient atmospheric PM samples from Barrow, Alaska, from July 2012 to June 2013. Preliminary analysis of the OC and BC concentrations has been completed. This campaign confirmed known trends of high BC lasting from the winter through to spring haze periods and low BC concentrations in the summer. However, the annual OC concentrations had a very different seasonal pattern with the highest concentrations during the summer, lowest concentrations during the fall, and increased concentrations during the winter and spring (Figure 1).

  20. D O

    Office of Legacy Management (LM)

    D O E F 1325.8 . Isee) 0 3 fcmo U n ite d S ta tes G o v e r n m e n t D A T E : O C T 0 8 1 9 9 2 bc .22-I R E F L Y T O A l T N OF: E M - 4 2 1 ( W . A . W illiams, 9 0 3 - 8...

  1. GiiJ

    Office of Legacy Management (LM)

    _ _' . :* .- 2' ' .T,, * -Mfj. 2- q + liiJ&pQ -s- # ; .;' ~ ?* 1, -- GiiJ . ,. ' " \ n ..&,: 8 ~blT& --_ The Secretary of Energy Washington. bC 20585 October 10, 1997 ' / :. . The Honorable William S. Cohen ' Secretary ofDefense Washington, D.C. 203Oi -' . .* cj , ' ^. . . . 4 ' . .- - . QarMr.Secietary: ~ , I . ' The Congress recently sent to the President for signature the Energy and Water Development Appropriations Act,. 1998. ' ~ ,, Among other provisions, this bill would

  2. Conferences and Workshops

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conferences and Workshops Below are events that are specifically related to Gasification. Also visit the NETL Events page to learn about other events. CONFERENCE DATES LOCATION 2016 International Advanced Coal Technologies Conference TBD TBD 2016 Gasification Technologies Conference 10/16/16-10/19/16 Vancouver, BC Power-Gen International 2016 12/13/16-12/15/16 Orlando, FL 34th International Pittsburgh Coal Conference, 2017 TBD TBD Conference Proceedings 2015 Gasification Systems and Coal &

  3. Conferences and Workshops

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conferences and Workshops Below are events that are specifically related to Gasification. Also visit the NETL Events page to learn about other events. CONFERENCE DATES LOCATION 2016 International Advanced Coal Technologies Conference TBD TBD 2016 Gasification Technologies Conference 10/16/16-10/19/16 Vancouver, BC Power-Gen International 2016 12/13/16-12/15/16 Orlando, FL 34th International Pittsburgh Coal Conference, 2017 TBD TBD Conference Proceedings 2015 Gasification Systems and Coal &

  4. Concomitant Microbial Generation of Palladium Nanoparticles and Hydrogen To Immobilize Chromate

    SciTech Connect (OSTI)

    Chidambaram, D.; Hennebel, T; Taghavi, S; Mast, J; Boon, N; Verstraete, W; Van Der Lelie, D; Fitts, J

    2010-01-01

    The catalytic properties of various metal nanoparticles have led to their use in environmental remediation. Our aim is to develop and apply an efficient bioremediation method based on in situ biosynthesis of bio-Pd nanoparticles and hydrogen. C. pasteurianum BC1 was used to reduce Pd(II) ions to form Pd nanoparticles (bio-Pd) that primarily precipitated on the cell wall and in the cytoplasm. C. pasteurianum BC1 cells, loaded with bio-Pd nanoparticle in the presence of glucose, were subsequently used to fermentatively produce hydrogen and to effectively catalyze the removal of soluble Cr(VI) via reductive transformation to insoluble Cr(III) species. Batch and aquifer microcosm experiments using C. pasteurianum BC1 cells loaded with bio-Pd showed efficient reductive Cr(VI) removal, while in control experiments with killed or viable but Pd-free bacterial cultures no reductive Cr(VI) removal was observed. Our results suggest a novel process where the in situ microbial production of hydrogen is directly coupled to the catalytic bio-Pd mediated reduction of chromate. This process offers significant advantages over the current groundwater treatment technologies that rely on introducing preformed catalytic nanoparticles into groundwater treatment zones and the costly addition of molecular hydrogen to above ground pump and treat systems.

  5. Demand forecasting and revenue requirements, with implications for consideration in British Columbia

    SciTech Connect (OSTI)

    Acton, J.P.

    1983-05-01

    This paper was filed as an exhibit on behalf of The Consumers' Association of Canada (B.C. Branch), The Federated Anti-Poverty Groups of B.C., The Sierra Club of Western Canada, and the B.C. Old Age Pensioners' Organization. It was subjected to cross-examination on October 29, 1982, during Phase I of the hearings. The Utilities Commission had designated Phase I for consideration of (1) demand, (2) assets in service, (3) revenue requirements excluding return, and (4) financing and capital requirements. This paper presents a general discussion of the elements of a rate structure and their relationship to the demand for electricity, a systematic review of some 50 empirical studies of the demand for electricity as a function of price and other factors by the three principal classes of customers, and a discussion of the notion of revenue requirements. The paper should be of interest to utility regulators, rate specialists, and forecasters for its review of demand models and to academics concerned with the study of energy demand.

  6. Strong sorption of native PAHs to pyrogenic and unburned carbonaceous geosorbents in sediments

    SciTech Connect (OSTI)

    Gerard Cornelissen; Gijs D. Breedveld; Stavros Kalaitzidis; Kimon Christanis; Anne Kibsgaard; Amy M.P. Oen

    2006-02-15

    It has recently been shown that the presence of carbonaceous geosorbents (CG, including black carbon (BC), unburned coal, and kerogen) can cause strong sorption of polycyclic aromatic hydrocarbons (PAHs) in sediments. The authors studied sorption of native PAHs in four Norwegian harbor sediments of which high fractions (21-56%) of the total organic carbon (TOC) consisted of CG carbon (CGC), as shown by organic petrography. PAH sorption coefficients were 1-2 orders of magnitude above predictions based on amorphous organic carbon partitioning alone. In recent studies, such strong sorption was attributed solely to BC sorption under the implicit assumption that sorption is linear for coal and kerogen. The most important result of the present study is that total sorption is better explained by considering all three nonlinearly sorbing CGC materials than by only considering BC. In addition, it was evaluated whether activated carbon (AC) amendments could be effective in reducing the freely dissolved porewater concentrations (C{sub W}) and thus the environmental risks of the PAHs in such strongly sorbing sediments. The results indicated that an addition of 2 weight % AC reduced the C{sub W} by factors of 21-153 for the four sediments (average values for all PAHs). It was shown that phenanthrene sorption to AC was, on average, reduced by a factor of 6 in sediment-AC mixtures compared to pure AC. 33 refs., 5 figs., 2 tabs.

  7. Barrow Black Carbon Source and Impact Study Final Campaign Report

    SciTech Connect (OSTI)

    Barrett, Tate

    2014-07-01

    The goal of the Barrow Black Carbon Source and Impact (BBCSI) Study was to characterize the concentration and isotopic composition of carbonaceous atmospheric particulate matter (PM) at the Atmospheric Radiation Measurement site in Barrow, AK. The carbonaceous component was characterized via measurement of the organic and black carbon (OC and BC) components of the total PM. To facilitate complete characterization of the particulate matter, filter-based collections were used, including a medium volume PM2.5 sampler and a high volume PM10 sampler. Thirty-eight fine (PM2.5) and 49 coarse (PM10) particulate matter fractions were collected at weekly and bi-monthly intervals. The PM2.5 sampler operated with minimal maintenance during the 12 month campaign. The PM10 sampler used for the BBCSI used standard Tisch hi-vol motors which have a known lifetime of ~1 month under constant use; this necessitated monthly maintenance and it is suggested that the motors be upgraded to industrial blowers for future deployment in the Arctic. The BBCSI sampling campaign successfully collected and archived 87 ambient atmospheric particulate matter samples from Barrow, AK from July 2012 to June 2013. Preliminary analysis of the organic and black carbon concentrations has been completed. This campaign confirmed known trends of high BC lasting from the winter through to spring haze periods and low BC concentrations in the summer.

  8. Laboratory Experiments and Instrument Development for the Study of Atmospheric Aerosols

    SciTech Connect (OSTI)

    Davidovits, Paul

    2011-12-10

    Soot particles are generated by incomplete combustion of fossil and biomass fuels. Through direct effects clear air aerosols containing black carbon (BC) such as soot aerosols, absorb incoming light heating the atmosphere, while most other aerosols scatter light and produce cooling. Even though BC represents only 1-2% of the total annual emissions of particulate mass to the atmosphere, it has been estimated that the direct radiative effect of BC is the second-most important contributor to global warming after absorption by CO2. Ongoing studies continue to underscore the climate forcing importance of black carbon. However, estimates of the radiative effects of black carbon on climate remain highly uncertain due to the complexity of particles containing black carbon. Quantitative measurement of BC is challenging because BC often occurs in highly non-spherical soot particles of complex morphology. Freshly emitted soot particles are typically fractal hydrophobic aggregates. The aggregates consist of black carbon spherules with diameters typically in the range of about 15-40 nm, and they are usually coated by adsorbed polyaromatic hydrocarbons (PAHs) produced during combustion. Diesel-generated soot particles are often emitted with an organic coating composed primarily of lubricating oil and unburned fuel, as well as well as PAH compounds. Sulfuric acid has also been detected in diesel and aircraft-emitted soot particles. In the course of aging, these particle coatings may be substantially altered by chemical reactions and/or the deposition of other materials. Such processes transform the optical and CCN properties of the soot aerosols in ways that are not yet well understood. Our work over the past seven years consisted of laboratory research, instrument development and characterization, and field studies with the central focus of improving our understanding of the black carbon aerosol climate impacts. During the sixth year as well as during this seventh year (no

  9. ASSEMBLY OF THE RED SEQUENCE IN INFRARED-SELECTED GALAXY CLUSTERS FROM THE IRAC SHALLOW CLUSTER SURVEY

    SciTech Connect (OSTI)

    Snyder, Gregory F.; Brodwin, Mark; Mancone, Conor M.; Gonzalez, Anthony H.; Zeimann, Gregory R.; Stanford, S. A.; Stern, Daniel; Eisenhardt, Peter R. M.; Brown, Michael J. I.; Dey, Arjun; Jannuzi, Buell; Perlmutter, Saul

    2012-09-10

    We present results for the assembly and star formation histories (SFHs) of massive ({approx}L*) red sequence galaxies (RSGs) in 11 spectroscopically confirmed, infrared-selected galaxy clusters at 1.0 < z < 1.5, the precursors to present-day massive clusters with M {approx} 10{sup 15} M{sub Sun }. Using rest-frame optical photometry, we investigate evolution in the color and scatter of the RSG population, comparing with models of possible SFHs. In contrast to studies of central cluster galaxies at lower redshift (z < 1), these data are clearly inconsistent with the continued evolution of stars formed and assembled primarily at a single, much earlier time. Specifically, we find that the colors of massive cluster galaxies at z Almost-Equal-To 1.5 imply that the bulk of star formation occurred at z {approx} 3, whereas by z Almost-Equal-To 1 their colors imply formation at z {approx} 2; therefore these galaxies exhibit approximately the same luminosity-weighted stellar age at 1 < z < 1.5. This likely reflects star formation that occurs over an extended period, the effects of significant progenitor bias, or both. Our results generally indicate that massive cluster galaxy populations began forming a significant mass of stars at z {approx}> 4, contained some red spheroids by z Almost-Equal-To 1.5, and were actively assembling much of their final mass during 1 < z < 2 in the form of younger stars. Qualitatively, the slopes of the cluster color-magnitude relations are consistent with no significant evolution relative to local clusters.

  10. The era of star formation in galaxy clusters

    SciTech Connect (OSTI)

    Brodwin, M.; Stanford, S. A.; Gonzalez, Anthony H.; Mancone, C. L.; Gettings, D. P.; Zeimann, G. R.; Snyder, G. F.; Ashby, M. L. N.; Pope, A.; Alberts, S.; Eisenhardt, P. R.; Stern, D.; Moustakas, L. A.; Brown, M. J. I.; Chary, R.-R.; Dey, Arjun; Galametz, A.; Jannuzi, B. T.; Miller, E. D.; Moustakas, J.

    2013-12-20

    We analyze the star formation properties of 16 infrared-selected, spectroscopically confirmed galaxy clusters at 1 < z < 1.5 from the Spitzer/IRAC Shallow Cluster Survey (ISCS). We present new spectroscopic confirmation for six of these high-redshift clusters, five of which are at z > 1.35. Using infrared luminosities measured with deep Spitzer/Multiband Imaging Photometer for Spitzer observations at 24 μm, along with robust optical + IRAC photometric redshifts and spectral-energy-distribution-fitted stellar masses, we present the dust-obscured star-forming fractions, star formation rates, and specific star formation rates in these clusters as functions of redshift and projected clustercentric radius. We find that z ∼ 1.4 represents a transition redshift for the ISCS sample, with clear evidence of an unquenched era of cluster star formation at earlier times. Beyond this redshift, the fraction of star-forming cluster members increases monotonically toward the cluster centers. Indeed, the specific star formation rate in the cores of these distant clusters is consistent with field values at similar redshifts, indicating that at z > 1.4 environment-dependent quenching had not yet been established in ISCS clusters. By combining these observations with complementary studies showing a rapid increase in the active galactic nucleus (AGN) fraction, a stochastic star formation history, and a major merging episode at the same epoch in this cluster sample, we suggest that the starburst activity is likely merger-driven and that the subsequent quenching is due to feedback from merger-fueled AGNs. The totality of the evidence suggests we are witnessing the final quenching period that brings an end to the era of star formation in galaxy clusters and initiates the era of passive evolution.

  11. THE FAINT END OF THE CLUSTER-GALAXY LUMINOSITY FUNCTION AT HIGH REDSHIFT

    SciTech Connect (OSTI)

    Mancone, Conor L.; Baker, Troy; Gonzalez, Anthony H.; Ashby, Matthew L. N.; Snyder, Greg; Stanford, Spencer A.; Brodwin, Mark; Eisenhardt, Peter R. M.; Stern, Daniel; Wright, Edward L.

    2012-12-20

    We measure the faint-end slope of the galaxy luminosity function (LF) for cluster galaxies at 1 < z < 1.5 using Spitzer IRAC data. We investigate whether this slope, {alpha}, differs from that of the field LF at these redshifts, and with the cluster LF at low redshifts. The latter is of particular interest as low-luminosity galaxies are expected to undergo significant evolution. We use seven high-redshift spectroscopically confirmed galaxy clusters drawn from the IRAC Shallow Cluster Survey to measure the cluster-galaxy LF down to depths of M* + 3 (3.6 {mu}m) and M* + 2.5 (4.5 {mu}m). The summed LF at our median cluster redshift (z = 1.35) is well fit by a Schechter distribution with {alpha}{sub 3.6{mu}m} = -0.97 {+-} 0.14 and {alpha}{sub 4.5{mu}m} = -0.91 {+-} 0.28, consistent with a flat faint-end slope and is in agreement with measurements of the field LF in similar bands at these redshifts. A comparison to {alpha} in low-redshift clusters finds no statistically significant evidence of evolution. Combined with past studies which show that M* is passively evolving out to z {approx} 1.3, this means that the shape of the cluster LF is largely in place by z {approx} 1.3. This suggests that the processes that govern the buildup of the mass of low-mass cluster galaxies have no net effect on the faint-end slope of the cluster LF at z {approx}< 1.3.

  12. A CLOSE-PAIR ANALYSIS OF DAMP MERGERS AT INTERMEDIATE REDSHIFTS

    SciTech Connect (OSTI)

    Chou, Richard C. Y.; Abraham, Roberto G.; Bridge, Carrie R. E-mail: abraham@astro.utoronto.ca

    2012-12-01

    We have studied the kinematics of {approx}2800 candidate close-pair galaxies at 0.1 < z < 1.2 identified from the Canada-France-Hawaii Telescope Legacy Survey fields. Spectra of these systems were obtained using spectrometers on the 6.5 m Magellan and 5 m Hale telescopes. These data allow us to constrain the rate of dry mergers at intermediate redshifts and to test the 'hot halo' model for quenching of star formation. Using virial radii estimated from the correlation between dynamical and stellar masses published by Leauthaud et al., we find that around 1/5 of our candidate pairs are likely to share a common dark matter halo (our metric for close physical association). These pairs are divided into red-red, blue-red, and blue-blue systems using the rest-frame colors classification method introduced in Chou et al.. Galaxies classified as red in our sample have very low star formation rates, but they need not be totally quiescent, and hence we refer to them as 'damp', rather than 'dry', systems. After correcting for known selection effects, the fraction of blue-blue pairs is significantly greater than that of red-red and blue-red pairs. Red-red pairs are almost entirely absent from our sample, suggesting that damp mergers are rare at z {approx} 0.5. Our data support models with a short merging timescale (<0.5 Gyr) in which star formation is enhanced in the early phase of mergers, but quenched in the late phase. Hot halo models may explain this behavior, but only if virial shocks that heat gas are inefficient until major mergers are nearly complete.

  13. STELLAR POPULATIONS FROM SPECTROSCOPY OF A LARGE SAMPLE OF QUIESCENT GALAXIES AT Z > 1: MEASURING THE CONTRIBUTION OF PROGENITOR BIAS TO EARLY SIZE GROWTH

    SciTech Connect (OSTI)

    Belli, Sirio; Ellis, Richard S.; Newman, Andrew B.

    2015-02-01

    We analyze the stellar populations of a sample of 62 massive (log M {sub *}/M {sub ☉} > 10.7) galaxies in the redshift range 1 < z < 1.6, with the main goal of investigating the role of recent quenching in the size growth of quiescent galaxies. We demonstrate that our sample is not biased toward bright, compact, or young galaxies, and thus is representative of the overall quiescent population. Our high signal-to-noise ratio Keck/LRIS spectra probe the rest-frame Balmer break region that contains important absorption line diagnostics of recent star formation activity. We obtain improved measures of the various stellar population parameters, including the star formation timescale τ, age, and dust extinction, by fitting templates jointly to both our spectroscopic and broadband photometric data. We identify which quiescent galaxies were recently quenched and backtrack their individual evolving trajectories on the UVJ color-color plane finding evidence for two distinct quenching routes. By using sizes measured in the previous paper of this series, we confirm that the largest galaxies are indeed among the youngest at a given redshift. This is consistent with some contribution to the apparent growth from recent arrivals, an effect often called progenitor bias. However, we calculate that recently quenched objects can only be responsible for about half the increase in average size of quiescent galaxies over a 1.5 Gyr period, corresponding to the redshift interval 1.25 < z < 2. The remainder of the observed size evolution arises from a genuine growth of long-standing quiescent galaxies.

  14. NuSTAR OBSERVATION OF A TYPE I X-RAY BURST FROM GRS 1741.9-2853

    SciTech Connect (OSTI)

    Barrire, Nicolas M.; Krivonos, Roman; Tomsick, John A.; Boggs, Steven E.; Craig, William W.; Bachetti, Matteo; Chakrabarty, Deepto; Christensen, Finn E.; Hailey, Charles J.; Mori, Kaya; Harrison, Fiona A.; Hong, Jaesub; Stern, Daniel; Zhang, William W.

    2015-02-01

    We report on two NuSTAR observations of GRS 1741.9-2853, a faint neutron star (NS) low-mass X-ray binary burster located 10' away from the Galactic center. NuSTAR detected the source serendipitously as it was emerging from quiescence: its luminosity was 6 10{sup 34}ergs{sup 1} on 2013 July 31 and 5 10{sup 35}ergs{sup 1} in a second observation on 2013 August 3. A bright, 800s long, H-triggered mixed H/He thermonuclear Type I burst with mild photospheric radius expansion (PRE) was present during the second observation. Assuming that the luminosity during the PRE was at the Eddington level, an H mass fraction X = 0.7 in the atmosphere, and an NS mass M = 1.4 M {sub ?}, we determine a new lower limit on the distance for this source of 6.3 0.5 kpc. Combining with previous upper limits, this places GRS 1741.9-2853 at a distance of 7kpc. Energy independent (achromatic) variability is observed during the cooling of the NS, which could result from the disturbance of the inner accretion disk by the burst. The large dynamic range of this burst reveals a long power-law decay tail. We also detect, at a 95.6% confidence level (1.7?), a narrow absorption line at 5.46 0.10 keV during the PRE phase of the burst, reminiscent of the detection by Waki et al. We propose that the line, if real, is formed in the wind above the photosphere of the NS by a resonant K? transition from H-like Cr gravitationally redshifted by a factor 1 + z = 1.09, corresponding to a radius range of 29.0-41.4km for a mass range of 1.4-2.0 M {sub ?}.

  15. UPPER BOUND ON THE FIRST STAR FORMATION HISTORY

    SciTech Connect (OSTI)

    Inoue, Yoshiyuki; Madejski, Grzegorz M.; Tanaka, Yasuyuki T.; Domnguez, Alberto

    2014-02-01

    Our understanding of the nature of the extragalactic background light (EBL) has improved with the recent development of gamma-ray observation techniques. An open subject in the context of the EBL is the reionization epoch, which is an important probe of the formation history of first stars, the so-called Population III (Pop III) stars. Although the mechanisms for the formation of PopIII stars are rather well understood on theoretical grounds, their formation history is still veiled in mystery because of their faintness. To shed light on this matter, we study jointly the gamma-ray opacity of distant objects and the reionization constraints from studies of intergalactic gas. By combining these studies, we obtain a sensitive upper bound on the PopIII star formation rate density of ?-dot {sub ?}(z)<0.01[(1+z)/(1+7.0)]{sup 3.4}(f{sub esc}/0.2){sup ?1}(C/3.0)M{sub ?}yr{sup ?1}Mpc{sup ?3} at z ? 7, where f {sub esc} and C are the escape fraction of ionizing photons from galaxies and the clumping factor of the intergalactic hydrogen gas. This limit is a ?10times tighter constraint compared with previous studies that take into account gamma-ray opacity constraints only. Even if we do not include the current gamma-ray constraints, the results do not change. This is because the detected gamma-ray sources are still at z ? 4.35 where the reionization has already finished.

  16. Characterization of Ambient Aerosols in Mexico City during the MCMA-2003 Campaign with Aerosol Mass Spectrometry. Results from the CENICA Supersite

    SciTech Connect (OSTI)

    Salcedo, D.; Onasch, Timothy B.; Dzepina, K.; Canagaratna, M. R.; Zhang, Q.; Huffman, A. J.; DeCarlo, Peter; Jayne, J. T.; Mortimer, P.; Worsnop, Douglas R.; Kolb, C. E.; Johnson, Kirsten S.; Zuberi, Bilal M.; Marr, L.; Volkamer, Rainer M.; Molina, Luisa; Molina, Mario J.; Cardenas, B.; Bernabe, R.; Marquez, C.; Gaffney, Jeffrey S.; Marley, Nancy A.; Laskin, Alexander; Shutthanandan, V.; Xie, YuLong; Brune, W. H.; Lesher, R.; Shirley, T.; Jiminez, J. L.

    2006-03-24

    An Aerodyne Aerosol Mass Spectrometer (AMS) was deployed at the CENICA Supersite, while another was deployed in the Aerodyne Mobile Laboratory (AML) during the Mexico City Metropolitan Area field study (MCMA-2003) from March 29-May 4, 2003 to investigate particle concentrations, sources, and processes. This is the first of a series of papers reporting the AMS results from this campaign. The AMS provides real time information on mass concentration and composition of the non-refractory species in particulate matter less than 1 ?m (NR PM1) with high time and size resolution. For the first time, we report field results from a beam width probe, which was used to study the shape and mixing state of the particles and to quantify potential losses of irregular particles due to beam broadening inside the AMS. Data from this probe show that no significant amount of irregular particles was lost due to excessive beam broadening. A comparison of the CENICA and AML AMSs measurements is presented, being the first published intercomparison between two quadrupole AMSs. The speciation, and mass concentrations reported by the two AMSs compared well. In order to account for the refractory material in the aerosol, we also present measurements of Black Carbon (BC) using an aethalometer and an estimate of the aerosol soil component obtained from PIXE analysis of filters. Comparisons of (AMS + BC + soil) mass concentration with other collocated particle instruments (a LASAIR Optical Particle Counter, a Tapered Element Oscillating Microbalance (TEOM) and a DustTrack Aerosol Monitor) are also presented. The comparisons show that the (AMS + BC + soil) mass concentration during MCMC-2003 is a good approximation to the total PM??? mass concentration.

  17. Negative feedback regulation of Homer 1a on norepinephrine-dependent cardiac hypertrophy

    SciTech Connect (OSTI)

    Chiarello, Carmelina; Bortoloso, Elena; Carpi, Andrea; Furlan, Sandra; Volpe, Pompeo

    2013-07-15

    Homers are scaffolding proteins that modulate diverse cell functions being able to assemble signalling complexes. In this study, the presence, sub-cellular distribution and function of Homer 1 was investigated. Homer 1a and Homer 1b/c are constitutively expressed in cardiac muscle of both mouse and rat and in HL-1 cells, a cardiac cell line. As judged by confocal immunofluorescence microscopy, Homer 1a displays sarcomeric and peri-nuclear localization. In cardiomyocytes and cultured HL-1 cells, the hypertrophic agonist norepinephrine (NE) induces α{sub 1}-adrenergic specific Homer 1a over-expression, with a two-to-three-fold increase within 1 h, and no up-regulation of Homer 1b/c, as judged by Western blot and qPCR. In HL-1 cells, plasmid-driven over-expression of Homer 1a partially antagonizes activation of ERK phosphorylation and ANF up-regulation, two well-established, early markers of hypertrophy. At the morphometric level, NE-induced increase of cell size is likewise and partially counteracted by exogenous Homer 1a. Under the same experimental conditions, Homer 1b/c does not have any effect on ANF up-regulation nor on cell hypertrophy. Thus, Homer 1a up-regulation is associated to early stages of cardiac hypertrophy and appears to play a negative feedback regulation on molecular transducers of hypertrophy. -- Highlights: • Homer 1a is constitutively expressed in cardiac tissue. • In HL-1 cells, norepinephrine activates signaling pathways leading to hypertrophy. • Homer 1a up-regulation is an early event of norepinephrine-induced hypertrophy. • Homer 1a plays a negative feedback regulation modulating pathological hypertrophy. • Over-expression of Homer 1a per se does not induce hypertrophy.

  18. Subsurface Flow and Contaminant Transport

    Energy Science and Technology Software Center (OSTI)

    2000-09-19

    FACT is a transient three-dimensional, finite element code for simulating isothermal groundwater flow, moisture movement, and solute transport in variably and/or fully saturated subsurface porous media. Both single and dual-domain transport formulations are available. Transport mechanisms considered include advection, hydrodynamic dispersion, linear adsorption, mobile/immobile mass transfer and first-order degradation. A wide range of acquifier conditions and remediation systems commonly encountered in the field can be simulated. Notable boundary condition (BC) options include, a combined rechargemore » and drain BC for simulating recirculation wells, and a head dependent well BC that computes flow based on specified drawdown. The code is designed to handle highly heterogenous, multi-layer, acquifer systems in a numerically efficient manner. Subsurface structure is represented with vertically distorted rectangular brick elements in a Cartesian system. The groundwater flow equation is approximated using the Bubnov-Galerkin finite element method in conjunction with an efficient symmetric Preconditioned Conjugate Gradient (PCG) ICCG matrix solver. The solute transport equation is approximated using an upstream weighted residual finite element method designed to alleviate numerical oscillation. An efficient asymmetric PCG (ORTHOMIN) matrix solver is employed for transport. For both the flow and transport equations, element matrices are computed from either influence coefficient formulas for speed, or two point Gauss-Legendre quadrature for accuracy. Non-linear flow problems can be solved using either Newton-Ralphson linearization or Picard iteration, with under-relaxation formulas to further enhance convergence. Dynamic memory allocation is implemented using Fortran 90 constructs. FACT coding is clean and modular.« less

  19. A New Approach to Modeling Aerosol Effects on East Asian Climate: Parametric Uncertainties Associated with Emissions, Cloud Microphysics and their Interactions

    SciTech Connect (OSTI)

    Yan, Huiping; Qian, Yun; Zhao, Chun; Wang, Hailong; Wang, Minghuai; Yang, Ben; Liu, Xiaohong; Fu, Qiang

    2015-09-16

    In this study, we adopt a parametric sensitivity analysis framework that integrates the quasi-Monte Carlo parameter sampling approach and a surrogate model to examine aerosol effects on the East Asian Monsoon climate simulated in the Community Atmosphere Model (CAM5). A total number of 256 CAM5 simulations are conducted to quantify the model responses to the uncertain parameters associated with cloud microphysics parameterizations and aerosol (e.g., sulfate, black carbon (BC), and dust) emission factors and their interactions. Results show that the interaction terms among parameters are important for quantifying the sensitivity of fields of interest, especially precipitation, to the parameters. The relative importance of cloud-microphysics parameters and emission factors (strength) depends on evaluation metrics or the model fields we focused on, and the presence of uncertainty in cloud microphysics imposes an additional challenge in quantifying the impact of aerosols on cloud and climate. Due to their different optical and microphysical properties and spatial distributions, sulfate, BC, and dust aerosols have very different impacts on East Asian Monsoon through aerosol-cloud-radiation interactions. The climatic effects of aerosol do not always have a monotonic response to the change of emission factors. The spatial patterns of both sign and magnitude of aerosol-induced changes in radiative fluxes, cloud, and precipitation could be different, depending on the aerosol types, when parameters are sampled in different ranges of values. We also identify the different cloud microphysical parameters that show the most significant impact on climatic effect induced by sulfate, BC and dust, respectively, in East Asia.

  20. A multi-model assessment of pollution transport to the Arctic

    SciTech Connect (OSTI)

    Shindell, D T; Chin, M; Dentener, F; Doherty, R M; Faluvegi, G; Fiore, A M; Hess, P; Koch, D M; MacKenzie, I A; Sanderson, M G; Schultz, M G; Schulz, M; Stevenson, D S; Teich, H; Textor, C; Wild, O; Bergmann, D J; Bey, I; Bian, H; Cuvelier, C; Duncan, B N; Folberth, G; Horowitz, L W; Jonson, J; Kaminski, J W; Marmer, E; Park, R; Pringle, K J; Schroeder, S; Szopa, S; Takemura, T; Zeng, G; Keating, T J; Zuber, A

    2008-03-13

    We examine the response of Arctic gas and aerosol concentrations to perturbations in pollutant emissions from Europe, East and South Asia, and North America using results from a coordinated model intercomparison. These sensitivities to regional emissions (mixing ratio change per unit emission) vary widely across models and species. Intermodel differences are systematic, however, so that the relative importance of different regions is robust. North America contributes the most to Arctic ozone pollution. For aerosols and CO, European emissions dominate at the Arctic surface but East Asian emissions become progressively more important with altitude, and are dominant in the upper troposphere. Sensitivities show strong seasonality: surface sensitivities typically maximize during boreal winter for European and during spring for East Asian and North American emissions. Mid-tropospheric sensitivities, however, nearly always maximize during spring or summer for all regions. Deposition of black carbon (BC) onto Greenland is most sensitive to North American emissions. North America and Europe each contribute {approx}40% of total BC deposition to Greenland, with {approx}20% from East Asia. Elsewhere in the Arctic, both sensitivity and total BC deposition are dominated by European emissions. Model diversity for aerosols is especially large, resulting primarily from differences in aerosol physical and chemical processing (including removal). Comparison of modeled aerosol concentrations with observations indicates problems in the models, and perhaps, interpretation of the measurements. For gas phase pollutants such as CO and O{sub 3}, which are relatively well-simulated, the processes contributing most to uncertainties depend on the source region and altitude examined. Uncertainties in the Arctic surface CO response to emissions perturbations are dominated by emissions for East Asian sources, while uncertainties in transport, emissions, and oxidation are comparable for European

  1. WRF-Chem Simulations of Aerosols and Anthropogenic Aerosol Radiative Forcing in East Asia

    SciTech Connect (OSTI)

    Gao, Yi; Zhao, Chun; Liu, Xiaohong; Zhang, Meigen; Leung, Lai-Yung R.

    2014-08-01

    This study aims to provide a first comprehensive evaluation of WRF-Chem for modeling aerosols and anthropogenic aerosol radiative forcing (RF) over East Asia. Several numerical experiments were conducted from November 2007 to December 2008. Comparison between model results and observations shows that the model can generally reproduce the observed spatial distributions of aerosol concentration, aerosol optical depth (AOD) and single scattering albedo (SSA) from measurements at different sites, including the relatively higher aerosol concentration and AOD over East China and the relatively lower AOD over Southeast Asia, Korean, and Japan. The model also depicts the seasonal variation and transport of pollutions over East Asia. Particulate matter of 10 um or less in the aerodynamic diameter (PM10), black carbon (BC), sulfate (SO42-), nitrate (NO3-) and ammonium (NH4+) concentrations are higher in spring than other seasons in Japan due to the pollutant transport from polluted area of East Asia. AOD is high over Southwest and Central China in winter, spring and autumn and over North China in summer while is low over South China in summer due to monsoon precipitation. SSA is lowest in winter and highest in summer. The model also captures the dust events at the Zhangye site in the semi-arid region of China. Anthropogenic aerosol RF is estimated to range from -5 to -20 W m-2 over land and -20 to -40 W m-2 over ocean at the top of atmosphere (TOA), 5 to 30 W m-2 in the atmosphere (ATM) and -15 to -40 W m-2 at the bottom (BOT). The warming effect of anthropogenic aerosol in ATM results from BC aerosol while the negative aerosol RF at TOA is caused by scattering aerosols such as SO4 2-, NO3 - and NH4+. Positive BC RF at TOA compensates 40~50% of the TOA cooling associated with anthropogenic aerosol.

  2. Crystal Structure of the alpha6beta6 Holoenzyme of propionyl-coenzyme A Carboxylase

    SciTech Connect (OSTI)

    Huang, C.; Sadre-Bazzaz, K; Shen, Y; Deng, B; Zhou, Z; Tong, L

    2010-01-01

    Propionyl-coenzyme A carboxylase (PCC), a mitochondrial biotin-dependent enzyme, is essential for the catabolism of the amino acids Thr, Val, Ile and Met, cholesterol and fatty acids with an odd number of carbon atoms. Deficiencies in PCC activity in humans are linked to the disease propionic acidaemia, an autosomal recessive disorder that can be fatal in infants. The holoenzyme of PCC is an {alpha}{sub 6}{beta}{sub 6} dodecamer, with a molecular mass of 750 kDa. The {alpha}-subunit contains the biotin carboxylase (BC) and biotin carboxyl carrier protein (BCCP) domains, whereas the {beta}-subunit supplies the carboxyltransferase (CT) activity. Here we report the crystal structure at 3.2-{angstrom} resolution of a bacterial PCC {alpha}{sub 6}{beta}{sub 6} holoenzyme as well as cryo-electron microscopy (cryo-EM) reconstruction at 15-{angstrom} resolution demonstrating a similar structure for human PCC. The structure defines the overall architecture of PCC and reveals unexpectedly that the {alpha}-subunits are arranged as monomers in the holoenzyme, decorating a central {beta}{sub 6} hexamer. A hitherto unrecognized domain in the {alpha}-subunit, formed by residues between the BC and BCCP domains, is crucial for interactions with the {beta}-subunit. We have named it the BT domain. The structure reveals for the first time the relative positions of the BC and CT active sites in the holoenzyme. They are separated by approximately 55 {angstrom}, indicating that the entire BCCP domain must translocate during catalysis. The BCCP domain is located in the active site of the {beta}-subunit in the current structure, providing insight for its involvement in the CT reaction. The structural information establishes a molecular basis for understanding the large collection of disease-causing mutations in PCC and is relevant for the holoenzymes of other biotin-dependent carboxylases, including 3-methylcrotonyl-CoA carboxylase (MCC) and eukaryotic acetyl-CoA carboxylase (ACC).

  3. Emission Regulations Reduced Impact of Climate Change in CA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Emission Regulations Reduced Impact of Climate Change in CA Emission Regulations Reduced Impact of Climate Change in CA Study shows clean diesel programs slashed black carbon, a powerful short-term contributor to global warming June 13, 2013 Jon Weiner 510-486-4014 jrweiner@lbl.gov CA-BC-graphic.jpg Sacramento - Reductions in emissions of black carbon since the late 1980s, mostly from diesel engines as a result of air quality programs, have resulted in a measurable reduction of concentrations of

  4. River and Plateau Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    December 2011) Page 1 Area RAP Committee Area of Interest Issue Manager(s) (*denotes lead) Other interested committee members Focus/Product For FY2012 Framing Questions/Issues (Articulated by Issue Managers) Cross- cutting River Corridor 100 & 300 Areas * 100 B/C Area * 100 K Area * 100 N Area * 100 D & H Areas * 100 F Area * 300 Area Shelley Cimon Dale Engstrom* Liz Mattson Jean Vanni Gerry Pollet Bob Suyama Wade Riggsbee 6 RODs RI/FS and Proposed Plans to be issued between now &

  5. The Secretary of Energy'

    Office of Legacy Management (LM)

    ? >g*+. , . dc*rb&.+ :c-r.3-b. g ;.i' 8 . I. ' . . 3 @ g. -- Q ' \ 4,: 6 L;Is)zLTEsdi# ' -. . ! h -. The Secretary of Energy' Washington, bC 20585 u , October 10, 1997 ' The .Honorabie William S . Cohen Secretary ofDefense Washington, D.C. 20301 -' &arMr. Secietary: !I " .,.. *- . = . . # ' The Congress recently se@ to the President for signature the Energy and Water ,, Development Appropriations Act, 1998. Among other provisions, this bill would immediately transfer

  6. ARM - Instrument - aeth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsaeth Documentation AETH : Handbook ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Instrument : Aethalometer (AETH) Instrument Categories Aerosols Picture of the Aerosol Observing System The aethalometer is an instrument that provides a real-time readout of the concentration of "black" or "elemental" carbon aerosol particles (BC or E) in an air stream. It is a self-contained

  7. Signature-Dependent Electromagnetic Transition Rates in the {pi}h{sub 11/2} Rotational Sequence of {sub 73}{sup 167}Ta

    SciTech Connect (OSTI)

    R. Chapman; K.-M. Spohr; M.B. Smith; R.A. Bark; G.J. Campbell; G.B. Hagemann; N. Keeley; D.J. Middleton; H. Ryde; P.O. Tjom

    1999-12-31

    Excited states in {sup 167}Ta, populated in the {sup 141}Pr({sup 30}Si, 4n){sup 167}Ta reaction, have been studied using the NORDBALL Ge detector array. For the {pi}h{sub 11/2}[514]{sub 2}{sup 9}{sup -} decay sequence, strong signature-dependent effects in the transition quadrupole moment ratio, Q{sub 1}(I {yields} I - 1)/Q{sub 2}(I {yields} I - 2), have been observed over the spin range {sub 2}{sup 21}{<=}I{<=}{sub 2}{sup 39} which encompasses a BC neutron alignment. This is interpreted as strong evidence for departure from axial symmetry.

  8. Signature-dependent electromagnetic transition rates in the {pi}h{sub 11/2} rotational sequence of {sub 73}{sup 167}Ta

    SciTech Connect (OSTI)

    Chapman, R.; Spohr, K.-M.; Smith, M. B.; Campbell, G. J.; Middleton, D. J.; Bark, R. A.; Ryde, H.; Hagemann, G. B.; Keeley, N.; Tjoem, P. O.

    1999-11-16

    Excited states in {sup 167}Ta, populated in the {sup 141}Pr({sup 30}Si,4n){sup 167}Ta reaction, have been studied using the NORDBALL Ge detector array. For the {pi}h{sub 11/2}[514]9/2{sup -} decay sequence, strong signature-dependent effects in the transition quadrupole moment ratio, Q{sub 1}(I{yields}I-1)/Q{sub 2}(I{yields}I-2), have been observed over the spin range 21/2{<=}I{<=}39/2 which encompasses a BC neutron alignment. This is interpreted as strong evidence for departure from axial symmetry.

  9. PII: 0022-3115(93)90328-V

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Journal of Nuclear Materials 2CO (1993) 177-183 North-Holland B,C solid target boronization of the MST reversed-field pinch D.J. Den Hartog, M. Cekic, G. Fiksel, S.A. Hokin, R.D. Kendrick, S.C. Prager and M.R. Stoneking University of Wisconsin-Madison, Department of Physics, Madison, WI 53706, USA Received 8 October 1992; accepted 20 November 1992 A solid rod of hot-pressed boron carbide is being used as the source of boron during boronization of MST. The most striking result of this procedure

  10. Particles and Forces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quarks, Gluons, and Co. Meet the Quirky Inhabitants of the Proton Saturday Morning Physics Saturday Morning Physics -- -- Texas A&M University Texas A&M University Dr. Rainer J. Fries February 21, 2009 Quarks, Gluons and Co. 2 Zooming in on the World around us Quarks, Gluons and Co. 3 Atoms Democritus, Greek philosopher ~ 400 B.C: "All matter is made up of very small indivisible elements" He called them 'atomos'. 19 th century chemistry confirms: there are only 92 different

  11. Materials and Modules for Low Cost, High Performance Fuel Cell Humidifiers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kick-off Meeting, Wash. D.C - 10/01/2009 Materials and Modules for Low Cost, High Performance Fuel Cell Humidifiers Prime Contractor: W. L. Gore & Associates Elkton, MD Principal Investigator: William B. Johnson Sub-Contractor: dPoint Technologies Vancouver, BC W. L. Gore & Associates, Inc. DOE Kick-off Meeting, Wash. D.C - 10/01/2009 Ahluwalia, et. al, ibid. Mirza, Z. DOE Hydrogen Program Review, June 9-13, 2008; Washington, DC Background W. L. Gore & Associates, Inc. DOE Kick-off

  12. Carbon Dioxide Information Analysis Center and World Data Center-A for atomspheric trace gases: Catalog of data bases and reports

    SciTech Connect (OSTI)

    Burtis, M.D.

    1995-04-01

    This document provides information about the many reports and other materials made available by the US Department of Energy`s Global Change Research Program (GCRP). Section A provides information about the activities, scope, and direction of the GCRP; Sections B,C, D, and E contain information about research that has been sponsered by GCRP; Sections F and G contains information about the numeric data packages and computer model pa kages the have been compiled by the GCRP; Section H describes reports about research dealing with the responses of vegetation to carbon dioxide; and Section I conatins reports from various workshops, symposia, and reviews.

  13. The FIonorable W

    Office of Legacy Management (LM)

    . L1 >.t,,:.r*. L * . .* -+rT[ $ @ . . . 8, r ' ! f? , 13% ii&-q 4 ;' ;' . 0; .' - .s* I -- 8 ..h! ,z * _ The Secretary of Energi' . Washington, bC 20585 . * & 3hTap. *-. October 10, 1997 ' , :- 1 . , The FIonorable W illiam S. Cohen a: .. Secretary ofDefense se . Washington, D.C. 203Oi .. . , JkarMr.Secietaxy ~ , ; , * _ ' . The Congress recently sent to the President for signature the Energy and Water Development Appropriations Act, 1998. Among other provisions, this bill would

  14. DRAFT Central Plateau Cleanup Strategy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Doug Shoop: DOE-RL John Price: Ecology Dave Einan: EPA November 2, 2012 2 River Corridor * 100 Area interim actions extended to 3/31/17 - Incorporate 154 additional waste sites - Address prior extensive deep excavation of hexavalent chromium contamination * 100 Area decision documents - Extend 100 B/C decision documents schedule to 12/15/16 to enable collection of additional groundwater data for cleanup decision - Delay 100-N document to 6/30/13 to avoid too many documents out for public comment

  15. Document # FOIA-2009-0054 Revision Title FREEDOM OF INFORMATION ACT REQUEST (FOI

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4] Document Inf ormation Document # FOIA-2009-0054 Revision Title FREEDOM OF INFORMATION ACT REQUEST (FOI 2009-0054) Date 09/02/2009 Originator RIEHLE bC Originator Co. bOE-RL Recipient JAR VI5 R Recipient Co. HEART OF __________AMERICA NW References Keywords OCE, FOTA, SENSITIVE, PRIVATE CITIZEN Projects Other Information___________________________ WHC-SD-W025-RPT-001, Rev. 0 ECN o. TDescription of Change W-025-017 If the installer elects to weld geomembrane seams in ambient temperatures below

  16. ARM - Field Campaign - Black Carbon at the Mt. Bachelor Observatory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsBlack Carbon at the Mt. Bachelor Observatory Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Black Carbon at the Mt. Bachelor Observatory 2016.06.15 - 2016.10.01 Lead Scientist : Daniel Jaffe Abstract Black carbon (BC) is a key component in the earth system and a significant climate forcing agent. Observations at remote sites and in free-tropospheric air are extremely sparse. We propose to utilize one of the ARM SP2 (Single

  17. ARM - Field Campaign - Colorado: SP2 Deployment at StormVEx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SP2 Deployment at StormVEx ARM Data Discovery Browse Data Related Campaigns Colorado: The Storm Peak Lab Cloud Property Validation Experiment (STORMVEX) 2010.11.15, Mace, AMF Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Colorado: SP2 Deployment at StormVEx 2010.11.15 - 2011.04.25 Lead Scientist : Arthur Sedlacek For data sets, see below. Abstract How does the boundary layer influence BC encapsulation? Is there a correlation between

  18. Tanzania wildcats to evaluate Jurassic Mandawa salt basin

    SciTech Connect (OSTI)

    Nagati, M.

    1996-10-07

    After 5 years of stagnant exploration in East Africa, Canadian independent Tanganyika Oil Co. of Vancouver, B.C., will drill two wildcats in Tanzania to evaluate the hydrocarbon potential of the coastal Jurassic Mandawa salt basin. Mita-1, spudded around Oct. 1, will be drilled to about 7,000 ft, East Lika-1 will be drilled in early December 1996 to approximately 6,000 ft. The two wells will test different structures and play concepts. The paper describes the exploration history, source rock potential, hydrocarbon shows, potential reservoir, and the prospects.

  19. Tri-Party Agreement Agencies - Public involvement calendar - fiscal year 2015

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 2014 December 2014 January 2015 February 2015 March 2015 April 2015 Federal Holidays November 11 November 27 December 25 January 1 January 19 February 16 Hanford Advisory Board (HAB) http://www.hanford.gov/page.cfm/hab November 5-6 Richland Red Lion February 4-5 April 8-9 HAB Committee Weeks http://www.hanford.gov/?page=455 River and Plateau (RAP) Health, Safety and Environmental Protection (HSEP) Tank Waste (TW) Public Involvement and Communications (PIC) Budgets and Contracts (BC)

  20. U.S. Department of Energy - Washington State Department of Ecology - U.S. Environmental Protection Agency

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Washington State Department of Ecology - U.S. Environmental Protection Agency 300 Area 100-B,C 100-KW & KE 100-N 100-D & DR 100-H 100-F 400 Area (FFTF) 200 West Area 200 East Area Changes Proposed to the Schedule for Cleaning Up Hanford's Plutonium Finishing Plant U.S. Department of Energy * U.S. Environmental Protection Agency * Washington State Department of Ecology Fact Sheet of its buildings over the next 14 years. There are 15 additional actions being proposed. Some of these actions

  1. Microsoft Word - WIPP Update 5_23-14.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "##$%#&'()*$+,-$./0$.123$ 4565789-$85,:$;<78=7>5?$=7@5?8=A,8=<7$=7$#,75B$C$ !"#$"%&'()*$+"*,-..*$"'/*"0$"%"&*122/*3*24*.'0"5*3*$2*26$'70*'&&7$720'5*87&"2*422$'9"*'0&* :+2$29%':+#*24*$+"*:';<*24*&%=/#*$+'$*70;5=&"#*$+"*6%"';+"&*&%=/*$+'$*:2$"0$7'55(*;20$%76=$"&*$2*$+"*

  2. Photoproduction of B{sub c} mesons

    SciTech Connect (OSTI)

    Berezhnoy, A.V.; Likhoded, A.K.; Shevlyagin, M.V.

    1995-10-01

    The cross section for the process {gamma}{gamma} {yields} B{sub c}(B{sub c}{sup *}){bar b}c is calculated. It is shown numerically that the fragmentation mechanism of B{sub c} production is not realized at any energies and that, near the threshold, the production of the pseudoscalar state is strongly suppressed in relation to the production of the vector state. A method is used in which the direct calculation of the amplitudes of the corresponding subprocesses by means of a FORTRAN program is followed by numerical Monte Carlo integration over the phase space. 10 refs., 7 figs.

  3. Microsoft PowerPoint - Dirac Materials QDM Mar 2015 short

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dirac Materials A.V. Balatsky *New class of materials *What is the definition of Dirac Materials? *Similarities and differences between d-wave superconductors, Graphene and Topological Insulators: All are Dirac materials with some common features *Imaging of k and r space *Local electronics and spins in graphene and TI *Gap or no gap in TI? J. X. Zhu, I. Martin, M. Salkola, T. Das, - Los Alamos D. Abergel, A. Black-Schaffer Nordita H. Dahal - BC T. Wehling, A. Lichtenstein, K. Scharnberg, R.

  4. Microsoft PowerPoint - Overview of 200 Areas.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanford's 200 Areas Ken Niles, Assistant Director Oregon Department of Energy Central Plateau Hanford Central Plateau 200 West & East Areas 200 West 200 East 200 West & East Areas 200 West 200 East WTP ERDF US Ecology 200 BC Cribs "Adjacent" Areas Tank Farms 200 West T-TX-TY S-SX-SY U B-BX-BY A-AX-AY-AZ AN-AP-AW C 200 East 18 Tank Farms in 5 Waste Management Areas Tanks Canyons T-Plant B-Plant PUREX U-Plant REDOX Canyons Other Facilities/Waste Streams PFP PUREX Tunnels WESF

  5. Searching

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Searching for Dark Matter Searches with MiniBooNE Presented to the FNAL PAC Dec 16, 2013 The MiniBooNE Collaboration R. Dharmapalan, & I. Stancu University of Alabama, Tuscaloosa, AL 35487 R. A. Johnson, & D.A. Wickremasinghe University of Cincinnati, Cincinnati, OH 45221 R. Carr, G. Karagiorgi, & M. H. Shaevitz Columbia University; New York, NY 10027 B.C. Brown, F.G. Garcia , R. Ford, T. Kobilarcik, W. Marsh, C. D. Moore, D. Perevalov, & W. Wester Fermi National Accelerator

  6. Higgs Hunting at the Large Hadron Collider

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sinjini Sengupta Saturday Morning Physics Texas A&M University 26 th Jan 2013  Introduction to the Standard Model  What is the Higgs really?  Hunting grounds: LHC and the detectors  How do we hunt for particles?  How would we know we see a Higgs?  What have we found so far?  What"s next? SMP 1/26/2013 2 Sinjini Sengupta  The idea that all matter is composed of elementary particles dates as far back as the 6 th century BC. ◦ Most of these were philosophical

  7. simulators | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulators DOE/BC-89/3/SP. Handbook for Personal Computer Version of BOAST II: A Three- Dimensional, Three-Phase Black Oil Applied Simulation Tool. Bartlesville Project Office. January 1989. 82 pp. NTIS Order No. DE89000725. FORTRAN source code and executable program. Min. Req.: IBM PC/AT, PS-2, or compatible computer with 640 Kbytes of memory. Download 464 KB Manual 75 KB Manual 404 KB Reference paper (1033-3,v1) by Fanchi, et al. Manual 83 KB Reference paper (1033-3,v2) by Fanchi, et al. BOAST

  8. PROP re-refined oil engine test performance

    SciTech Connect (OSTI)

    Linnard, R.E.

    1980-11-01

    Using conventional, commercially-available nonproprietary (to Phillips) additive treatments, engine test programs have successfully demonstrated Phillips Re-refined Oil Process (PROP) oils' compliance with the performance requirements of MIL-L-46152A and API Services SE/CC. This paper reports on the engine testing experience with PROP refined oils as produced in a full-scale 2 MM GPY PROP plant operating with Buyer-collected used oil feedstocks. Comment is also made on the status of the first two PROP plants, one built for the state of North Carolina and the other for Mohawk Oil Company, Ltd., Vancouver B.C., Canada.

  9. Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GCPCC's collaboration and publication policy Beamline acknowledgement Publication List Please contact us when you have a publication resulting from work done at the GCPCC PX beamline. Miller MD, Phillips GN Jr., White MA, Fox RO, Craft BC III The development of the GCPCC Protein Crystallography Beamline at CAMD. Application of Accelerators in Research and Industry -- Sixteenth Int'l Conf., J.L. Duggan and I.L. Morgan eds., 734-737 (2001). {PDF} Qiu C, Tarrant MK, Choi SH, Sathyamurthy A, Bose R,

  10. RAP Meeting Transcribed Flipcharts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October 9, 2012 NRDA IAP - Next Steps  November Board meeting update, notice of comment period  20 minute presentation  Outline of Plan o Final Plan by mid-January 2013 Page 1 100 K Sampling Plan and Overall Update Follow up: - RI/FS Proposed Plan ready for comment in May 2013 - D/H, F - Draft A (regulators) in December - 100N - Draft A in June 2013 - 300 Area - Jan/Feb 2013 - B/C  way out, drilling wells Page 2 Groundwater/Vadoze Zone Executive Council Follow up  Issue manager

  11. Commitment to Public Involvement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Create a Sustainable Future » Commitment to Public Involvement Commitment to Public Involvement LANL is committed to our neighbors August 1, 2013 Lab Director McMillan talks with Lab historian Ellen McGhee during Lab tour Lab Director McMillan talks with Lab historian Ellen McGhee during Lab tour RELATED IMAGES http://farm4.staticflickr.com/3815/9442115459_390e5bc841_t.jpg Enlarge http://farm8.staticflickr.com/7111/7650961650_ed1571174f_t.jpg Enlarge

  12. Evaluation of the carbon content of aerosols from the burn- ing of biomass in the Brazilian Amazon using thermal, op- tical and thermal-optical analysis methods

    SciTech Connect (OSTI)

    Soto-Garcia, Lydia L.; Andreae, Meinrat O.; Andreae, Tracey W.; taxo, Paulo Ar-; Maenhaut, Willy; Kirchstetter, Thomas; Novakov, T.; Chow, Judith C.; Mayol-Bracero, Olga L.

    2011-06-03

    Aerosol samples were collected at a pasture site in the Amazon Basin as part of the project LBA-SMOCC-2002 (Large-Scale Biosphere-Atmosphere Experiment in Amazonia - Smoke Aerosols, Clouds, Rainfall and Climate: Aerosols from Biomass Burning Perturb Global and Regional Climate). Sampling was conducted during the late dry season, when the aerosol composition was dominated by biomass burning emissions, especially in the submicron fraction. A 13-stage Dekati low-pressure impactor (DLPI) was used to collect particles with nominal aerodynamic diameters (D{sub p}) ranging from 0.03 to 0.10 m. Gravimetric analyses of the DLPI substrates and filters were performed to obtain aerosol mass concentrations. The concentrations of total, apparent elemental, and organic carbon (TC, EC{sub a}, and OC) were determined using thermal and thermal-optical analysis (TOA) methods. A light transmission method (LTM) was used to determine the concentration of equivalent black carbon (BC{sub e}) or the absorbing fraction at 880 nm for the size-resolved samples. During the dry period, due to the pervasive presence of fires in the region upwind of the sampling site, concentrations of fine aerosols (D{sub p} < 2.5 {mu}m: average 59.8 {mu}g m{sup -3}) were higher than coarse aerosols (D{sub p} > 2.5 {mu}m: 4.1 {mu}g m{sup -3}). Carbonaceous matter, estimated as the sum of the particulate organic matter (i.e., OC x 1.8) plus BC{sub e}, comprised more than 90% to the total aerosol mass. Concentrations of EC{sub a} (estimated by thermal analysis with a correction for charring) and BCe (estimated by LTM) averaged 5.2 {+-} 1.3 and 3.1 {+-} 0.8 {mu}g m{sup -3}, respectively. The determination of EC was improved by extracting water-soluble organic material from the samples, which reduced the average light absorption {angstrom} exponent of particles in the size range of 0.1 to 1.0 {mu}m from > 2.0 to approximately 1.2. The size-resolved BC{sub e} measured by the LTM showed a clear maximum between 0.4 and

  13. Preparation and uses of amorphous boron carbide coated substrates

    DOE Patents [OSTI]

    Riley, R.E.; Newkirk, L.R.; Valencia, F.A.; Wallace, T.C.

    1979-12-05

    Cloth is coated at a temperature below about 1000/sup 0/C with amorphous boron-carbon deposits in a process which provides a substantially uniform coating on all the filaments making up each yarn fiber bundle of the cloth. The coated cloths can be used in the as-deposited condition for example as wear surfaces where high hardness values are needed; or multiple layers of coated cloths can be hot-pressed to form billets useful for example in fusion reactor wall armor. Also provided is a method of controlling the atom ratio of B:C of boron-carbon deposits onto any of a variety of substrates, including cloths.

  14. Preparation and uses of amorphous boron carbide coated substrates

    DOE Patents [OSTI]

    Riley, Robert E.; Newkirk, Lawrence R.; Valencia, Flavio A.

    1981-09-01

    Cloth is coated at a temperature below about 1000.degree. C. with amorphous boron-carbon deposits in a process which provides a substantially uniform coating on all the filaments making up each yarn fiber bundle of the cloth. The coated cloths can be used in the as-deposited condition for example as wear surfaces where high hardness values are needed; or multiple layers of coated cloths can be hot-pressed to form billets useful for example in fusion reactor wall armor. Also provided is a method of controlling the atom ratio of B:C of boron-carbon deposits onto any of a variety of substrates, including cloths.

  15. A :netao '?X,S vrtttcn (XX-x-162) to ;,r+ allison dascrllltnPr a m?neral 7m~rM o

    Office of Legacy Management (LM)

    A :netao '?X,S vrtttcn (XX-x-162) to ;,r+ allison dascrllltnPr a m?neral 7m~rM of metallurKic.%l, fabrication, and nhysicnf stuJles whtch owht to be carried out as lntcnsively as -loseible stnrtinr: imiaedintely, in order to Tmvide information for the desicn of efficient methods of using atomic noxer. This nrescnt memo becomes more snecific in q entionini: lines of vmr!: which the idetholis and iinterlals Section believes to bc of lnortence. It also tells names of neonle and olaces where useful

  16. I

    Office of Legacy Management (LM)

    . I .\ Departin& of Energy 8 Washington, ,bC 20585 iii10 1995 The Honorable Richard M. Daley,, Jr. 121 N. LaSalle Street Chicago, Illinois 60602 Dear Mayor Daley: ,. '~ : , Secretary of Energy Raze1 O'Leary 'has announced a'new approach to openness in the Department.of Energy (DOE) and its communications with the public. In : support of this initiative, we are.pleased to forward the.enclosed information-, related to the former Hydroblast Corp.-site in, your~jurisdiction that performed work

  17. I*

    Office of Legacy Management (LM)

    :c* - . 2e. a.;*. _ . . . -&3&G &q, ,;, -%+ ., . I* .g* 1 . . @ 3 - . a .b,: & ' b-Q&8 " ' , .-. . The Secretary of Energy Washington, bC 20585 ,&q!. 0s .". 3 0 .' . ..; October 10, 1997 . . The ,Honorable William S. Cohen Secretary of Defense Washington, D.C. 20301 . # ._ &tar Mr. Secretary: . ' The Congress recently sent to the President for signature the Energy and Water Development Appropriations Act,' 1998. Among other provisions, this bill would

  18. Measurements of the Rate of Type Ia Supernovae at Redshift z < ~0.3 from the SDSS-II Supernova Survey

    SciTech Connect (OSTI)

    Dilday, Benjamin; Smith, Mathew; Bassett, Bruce; Becker, Andrew; Bender, Ralf; Castander, Francisco; Cinabro, David; Filippenko, Alexei V.; Frieman, Joshua A.; Galbany, Lluis; Garnavich, Peter M.; /Notre Dame U. /Stockholm U., OKC /Stockholm U.

    2010-01-01

    We present a measurement of the volumetric Type Ia supernova (SN Ia) rate based on data from the Sloan Digital Sky Survey II (SDSS-II) Supernova Survey. The adopted sample of supernovae (SNe) includes 516 SNe Ia at redshift z {approx}< 0.3, of which 270 (52%) are spectroscopically identified as SNe Ia. The remaining 246 SNe Ia were identified through their light curves; 113 of these objects have spectroscopic redshifts from spectra of their host galaxy, and 133 have photometric redshifts estimated from the SN light curves. Based on consideration of 87 spectroscopically confirmed non-Ia SNe discovered by the SDSS-II SN Survey, we estimate that 2.04{sub -0.95}{sup +1.61}% of the photometric SNe Ia may be misidentified. The sample of SNe Ia used in this measurement represents an order of magnitude increase in the statistics for SN Ia rate measurements in the redshift range covered by the SDSS-II Supernova Survey. If we assume a SN Ia rate that is constant at low redshift (z < 0.15), then the SN observations can be used to infer a value of the SN rate of r{sub V} = (2.69{sub -0.30-0.01}{sup +0.34+0.21}) x 10{sup -5} SNe yr{sup -1} Mpc{sup -3} (H{sub 0}/(70 km s{sup -1} Mpc{sup -1})){sup 3} at a mean redshift of {approx} 0.12, based on 79 SNe Ia of which 72 are spectroscopically confirmed. However, the large sample of SNe Ia included in this study allows us to place constraints on the redshift dependence of the SN Ia rate based on the SDSS-II Supernova Survey data alone. Fitting a power-law model of the SN rate evolution, r{sub V} (z) = A{sub p} x ((1+z)/(1+z{sub 0})){sup {nu}}, over the redshift range 0.0 < z < 0.3 with z{sub 0} = 0.21, results in A{sub p} = (3.43{sub -0.15}{sup +0.15}) x 10{sup -5} SNe yr{sup -1} Mpc{sup -3} (H{sub 0}/(70 km s{sup -1} Mpc{sup -1})){sup 3} and {nu} = 2.04{sub -0.89}{sup +0.90}.

  19. Mass calibration of galaxy clusters at redshift 0.11.0 using weak lensing in the Sloan Digital Sky Survey Stripe 82 co-add

    SciTech Connect (OSTI)

    Wiesner, Matthew P.; Lin, Huan; Soares-Santos, Marcelle

    2015-07-08

    We present galaxy cluster massrichness relations found in the Sloan Digital Sky Survey Stripe 82 co-add using clusters found using a Voronoi tessellation cluster finder. These relations were found using stacked weak lensing shear observed in a large sample of galaxy clusters. These massrichness relations are presented for four redshift bins, 0.1 < z ? 0.4, 0.4 < z ? 0.7, 0.7 < z ? 1.0 and 0.1 < z ? 1.0. We describe the sample of galaxy clusters and explain how these clusters were found using a Voronoi tessellation cluster finder. We fit a Navarro-Frenk-White profile to the stacked weak lensing shear signal in redshift and richness bins in order to measure virial mass (M200). We describe several effects that can bias weak lensing measurements, including photometric redshift bias, the effect of the central BCG, halo miscentering, photometric redshift uncertainty and foreground galaxy contamination. We present massrichness relations using richness measure NVT with each of these effects considered separately as well as considered altogether. We also examine redshift evolution of the massrichness relation. As a result, we present measurements of the mass coefficient (M200|20) and the power-law slope (?) for power-law fits to the mass and richness values in each of the redshift bins. We find values of the mass coefficient of 8.49 0.526, 14.1 1.78, 30.2 8.74 and 9.23 0.525 1013 h1 M? for each of the four redshift bins, respectively. As a result, we find values of the power-law slope of 0.905 0.0585, 0.948 0.100, 1.33 0.260 and 0.883 0.0500, respectively.

  20. The Effect of Cellulose Crystal Structure and Solid-State Morphology on the Activity of Cellulases

    SciTech Connect (OSTI)

    Stipanovic, Arthur J

    2014-11-17

    Consistent with the US-DOE and USDA “Roadmap” objective of producing ethanol and chemicals from cellulosic feedstocks more efficiently, a three year research project entitled “The Effect of Cellulose Crystal Structure and Solid-State Morphology on the Activity of Cellulases” was initiated in early 2003 under DOE sponsorship (Project Number DE-FG02-02ER15356). A three year continuation was awarded in June 2005 for the period September 15, 2005 through September 14, 2008. The original goal of this project was to determine the effect of cellulose crystal structure, including allomorphic crystalline form (Cellulose I, II, III, IV and sub-allomorphs), relative degree of crystallinity and crystallite size, on the activity of different types of genetically engineered cellulase enzymes to provide insight into the mechanism and kinetics of cellulose digestion by “pure” enzymes rather than complex mixtures. We expected that such information would ultimately help enhance the accessibility of cellulose to enzymatic conversion processes thereby creating a more cost-effective commercial process yielding sugars for fermentation into ethanol and other chemical products. Perhaps the most significant finding of the initial project phase was that conversion of native bacterial cellulose (Cellulose I; BC-I) to the Cellulose II (BC-II) crystal form by aqueous NaOH “pretreatment” provided an increase in cellulase conversion rate approaching 2-4 fold depending on enzyme concentration and temperature, even when initial % crystallinity values were similar for both allomorphs.

  1. Substantial Contribution of Anthropogenic Air Pollution to Catastrophic Floods in Southwest China

    SciTech Connect (OSTI)

    Fan, Jiwen; Rosenfeld, Daniel; Yang, Yan; Zhao, Chun; Leung, Lai-Yung R.; Li, Zhanqing

    2015-07-20

    Extreme events such as heat waves, floods, and droughts, have become more frequent since the 1950s1-2. This is likely caused through changes in greenhouse gases and aerosols that perturb the radiative balance and alter cloud processes3-8. On 8-9 July, 2013 a catastrophic flood devastated several metropolitan areas at the foothills of the Sichuan Basin. Using a high-resolution coupled atmosphere-chemistry model, we show that this disaster was not entirely natural. Ensemble simulations robustly show that the severe anthropogenic pollution in the Sichuan Basin significantly enhanced rainfall intensity over the mountainous area northwest of the basin. The heavy air pollution (mainly black carbon) absorbs solar radiation in the lower atmosphere at the expense of surface cooling, which stabilizes the atmosphere and suppresses convection and precipitation over the basin. The enhanced moisture and moist static energy over the basin are then transported by the prevailing winds towards the mountains during daytime. As the excessive moist air that reaches the foothills at night is orographically lifted, very strong convection develops and produces extremely heavy precipitation. Reducing black carbon (BC) emissions in the basin can effectively mitigate the extreme precipitation in the mountains. Unfortunately, BC emissions have been increasing in many developing countries including China9, making them more vulnerable to enhanced disasters as reported here.

  2. Physics with gamma-beams and charged particle detectors: I) Nuclear structure II) Nuclear astrophysics

    SciTech Connect (OSTI)

    Gai, Moshe

    2015-02-24

    The Charged Particle Working Group (CPWG) is proposing to construct large area Silicon Strip Detector (SSD), a gas Time Projection Chamber detector read by an electronic readout system (eTPC) and a Bubble Chamber (BC) containing superheated high purity water to be used in measurements utilizing intense gamma-ray beams from the newly constructed ELI-NP facility at Magurele, Bucharest in Romania. We intend to use the SSD and eTPC detectors to address essential problems in nuclear structure physics, such as clustering and the many alpha-decay of light nuclei such as {sup 12}C and {sup 16}O. All three detectors (SSD, eTPC and BC) will be used to address central problems in nuclear astrophysics such as the astrophysical cross section factor of the {sup 12}C(α,γ) reaction and other processes central to stellar evolution. The CPWG intends to submit to the ELI-NP facility a Technical Design Report (TDR) for the proposed detectors.

  3. Measurement of the ratio of the production cross sections times branching fractions of $$B_{c}^{\\pm} \\to J/\\psi \\pi^{\\pm}$$ and $$B^{\\pm} \\to J/\\psi K^{\\pm}$$ and $$\\mathcal{B}(B_{c}^{\\pm} \\to J/\\psi \\pi^{\\pm}\\pi^{\\pm}\\pi^{\\mp})/\\mathcal{B}(B_{c}^{\\pm} \\to J/\\psi \\pi^{\\pm})$$ in pp collisions at $$\\sqrt{s} =$$ 7 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, Vardan

    2015-01-13

    The ratio of the production cross sections times branching fractions (σ(B±c)B(B±c→J/ψπ±))/(σ(B±)B(B±→J/ψK±)) is studied in proton-proton collisions at a center of-mass energy of 7 TeV with the CMS detector at the LHC. The kinematic region investigated requires B c ± and B± mesons with transverse momentum p T > 15 GeV and rapidity |y|< 1.6. The data sample corresponds to an integrated luminosity of 5.1 fb-1. The ratio is determined to be [0.48±0.05(stat)± 0.03(syst)±0.05 (τBc)]%. The B c ± → J/ψπ ± π ± π ∓ decay is also observed in the same data sample. Using a model-independent method developed tomore » measure the efficiency given the presence of resonant behaviour in the three-pion system, the ratio of the branching fractions B(B±c→J/ψπ±π±π∓)/B(B±c→J/ψπ±) is measured to be 2.55±0.80(stat)±0.33(syst)+0.04-0.01(τBc), consistent with the previous LHCb result.« less

  4. Particle Physics at the University of Pittsburgh Summary Report for Proposal Period FY'09-11

    SciTech Connect (OSTI)

    Boudreau, Joe; Dytman, Steven; Mueller, James; Naples, Donna; Paolone, Vittorio; Savinov, Vladimir

    2012-10-01

    Presented is the final summary report for grant DOE-FG02-91ER40646. The HEP group at the University consists of three tasks: B,D and L. Task B supports Pitt's CDF group at the energy frontier which includes Joe Boudreau and Paul Shepard. Work of the group includes Hao Song's thesis on the measurement of the B_c lifetime using exclusive J/psi+pion decays, and an update of the previous B_c semi-leptonic analyses under the supervision of Paul Shepard. Task D supports Pitt's neutrino group at the intensity frontier which includes PIs Dytman, Naples and Paolone. The group also includes postdoctoral research associate Danko, and thesis students Isvan (MINOS), Eberly (Minerva ), Ren (Minerva )and Hansen (T2K). This report summarizes their progress on ongoing experiments which are designed to make significant contributions to a detailed understanding of the neutrino mixing matrix. Task L supports Pitt's ATLAS group at the energy frontier and includes investigators Vladimir Savinov, James Mueller and Joe Boudreau. This group contributed both to hardware (calorimeter electronics, Savinov) and to software (Simulation, Detector Description, and Visualization: Boudreau and Mueller; MC generators: Savinov) and a summary of their progress is presented.

  5. Chemical Bonding and Structural Information of Black CarbonReference Materials and Individual Carbonaceous AtmosphericAerosols

    SciTech Connect (OSTI)

    Hopkins, Rebecca J.; Tivanski, Alexei V.; Marten, Bryan D.; Gilles, Mary K.

    2007-04-25

    The carbon-to-oxygen ratios and graphitic nature of a rangeof black carbon standard reference materials (BC SRMs), high molecularmass humic-like substances (HULIS) and atmospheric particles are examinedusing scanning transmission X-ray microscopy (STXM) coupled with nearedge X-ray absorption fine structure (NEXAFS) spectroscopy. UsingSTXM/NEXAFS, individual particles with diameter>100 nm are studied,thus the diversity of atmospheric particles collected during a variety offield missions is assessed. Applying a semi-quantitative peak fittingmethod to the NEXAFS spectra enables a comparison of BC SRMs and HULIS toparticles originating from anthropogenic combustion and biomass burns,thus allowing determination of the suitability of these materials forrepresenting atmospheric particles. Anthropogenic combustion and biomassburn particles can be distinguished from one another using both chemicalbonding and structural ordering information. While anthropogeniccombustion particles are characterized by a high proportion ofaromatic-C, the presence of benzoquinone and are highly structurallyordered, biomass burn particles exhibit lower structural ordering, asmaller proportion of aromatic-C and contain a much higher proportion ofoxygenated functional groups.

  6. Metallography and microstructure interpretation of some archaeological tin bronze vessels from Iran

    SciTech Connect (OSTI)

    Oudbashi, Omid; Davami, Parviz

    2014-11-15

    Archaeological excavations in western Iran have recently revealed a significant Luristan Bronzes collection from Sangtarashan archaeological site. The site and its bronze collection are dated to Iron Age II/III of western Iran (10th–7th century BC) according to archaeological research. Alloy composition, microstructure and manufacturing technique of some sheet metal vessels are determined to reveal metallurgical processes in western Iran in the first millennium BC. Experimental analyses were carried out using Scanning Electron Microscopy–Energy Dispersive X-ray Spectroscopy and Optical Microscopy/Metallography methods. The results allowed reconstructing the manufacturing process of bronze vessels in Luristan. It proved that the samples have been manufactured with a binary copper–tin alloy with a variable tin content that may relates to the application of an uncontrolled procedure to make bronze alloy (e.g. co-smelting or cementation). The presence of elongated copper sulphide inclusions showed probable use of copper sulphide ores for metal production and smelting. Based on metallographic studies, a cycle of cold working and annealing was used to shape the bronze vessels. - Highlights: • Sangtarashan vessels are made by variable Cu-Sn alloys with some impurities. • Various compositions occurred due to applying uncontrolled smelting methods. • The microstructure represents thermo-mechanical process to shape bronze vessels. • In one case, the annealing didn’t remove the eutectoid remaining from casting. • The characteristics of the bronzes are similar to other Iron Age Luristan Bronzes.

  7. A Sensitivity Study on Modeling Black Carbon in Snow and its Radiative Forcing over the Arctic and Northern China

    SciTech Connect (OSTI)

    Qian, Yun; Wang, Hailong; Zhang, Rudong; Flanner, M. G.; Rasch, Philip J.

    2014-06-02

    Black carbon in snow (BCS) simulated in the Community Atmosphere Model (CAM5) is evaluated against measurements over Northern China and the Arctic, and its sensitivity to atmospheric deposition and two parameters that affect post-depositional enrichment is explored. The BCS concentration is overestimated (underestimated) by a factor of two in Northern China (Arctic) in the default model, but agreement with observations is good over both regions in the simulation with improvements in BC transport and deposition. Sensitivity studies indicate that uncertainty in the melt-water scavenging efficiency (MSE) parameter substantially affects BCS and its radiative forcing (by a factor of 2-7) in the Arctic through post-depositional enrichment. The MSE parameter has a relatively small effect on the magnitude of BCS seasonal cycle but can alter its phase in Northern China. The impact of the snow aging scaling factor (SAF) on BCS, partly through the post-depositional enrichment effect, shows more complex latitudinal and seasonal dependence. Similar to MSE, SAF affects more significantly the magnitude (phase) of BCS season cycle over the Arctic (Northern China). While uncertainty associated with the representation of BC transport and deposition processes in CAM5 is more important than that associated with the two snow model parameters in Northern China, the two uncertainties have comparable effect in the Arctic.

  8. ISDAC - NRC Convair-580 Flight Hours Date Flight From To Start

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - NRC Convair-580 Flight Hours Date Flight From To Start End hrs 03/21/08 F01-Test-01 Ottawa Ottawa 16:15Z 18:15Z 2.2 03/22/08 F02-Test-02 Ottawa Ottawa 12:45Z 15:50Z 3.3 03/28/08 F03-Transit-01 Ottawa, ON Kenora, ON 12:23Z 15:44Z 3.6 03/28/08 F04-Transit-02 Kenora, ON Calgary, AB 16:30Z 19:36Z 3.3 03/28/08 F05-Transit-03 Calgary, AB Comox, BC 20:24Z 22:17Z 2.1 03/29/08 F06-Transit-04 Comox, BC Whitehorse, YK 17:43Z 20:50Z 3.3 03/29/08 F07-Transit-05 Whitehorse, YK Fairbanks 21:51Z 23:42Z 2.1

  9. Nanostructures of Liquid Crystal Phases in Mixtures of Bent-core and Rod-shaped Molecules

    SciTech Connect (OSTI)

    S Hong; R Verduzco; J Gleeson; S Sprunt; A Jakli

    2011-12-31

    We report small angle x-ray scattering (SAXS) studies of isotropic, nematic, and smectic mesophases formed by binary mixtures of bent-core (BC) and rod-shaped (RS) molecules. While optical studies indicate that the components are fully miscible, SAXS reveals fascinating structures that are consistent with segregation on a nanoscopic scale. We find that tilted smectic clusters, which have been previously reported in both the nematic and isotropic states of the pure BC materials, are also present in mixtures with up to 50 wt% of the RS compound; this is consistent with previous dielectric and flexoelectric studies on such mixtures. Unexpectedly in this concentration range the clusters are present in the isotropic and in the induced smectic phase range, as well as throughout the nematic phase. The results in the smectic phase also reveal complex layering phenomena, providing important insight into the interaction between bent and rod-shaped molecules. These studies will be crucial in the design of promising new functional nanomaterials.

  10. Nanostructures of liquid crystal phases in mixtures of bent-core and rod-shaped molecules

    SciTech Connect (OSTI)

    Hong, S. H.; Gleeson, J. T.; Sprunt, S.; Verduzco, R.; Jakli, A.

    2011-06-15

    We report small angle x-ray scattering (SAXS) studies of isotropic, nematic, and smectic mesophases formed by binary mixtures of bent-core (BC) and rod-shaped (RS) molecules. While optical studies indicate that the components are fully miscible, SAXS reveals fascinating structures that are consistent with segregation on a nanoscopic scale. We find that tilted smectic clusters, which have been previously reported in both the nematic and isotropic states of the pure BC materials, are also present in mixtures with up to 50 wt% of the RS compound; this is consistent with previous dielectric and flexoelectric studies on such mixtures. Unexpectedly in this concentration range the clusters are present in the isotropic and in the induced smectic phase range, as well as throughout the nematic phase. The results in the smectic phase also reveal complex layering phenomena, providing important insight into the interaction between bent and rod-shaped molecules. These studies will be crucial in the design of promising new functional nanomaterials.

  11. Comparative analysis of various CO2 configurations in supermarket refrigeration systems

    SciTech Connect (OSTI)

    Sharma, Vishaldeep; Fricke, Brian; Bansal, Pradeep

    2014-07-09

    Our paper presents an analysis of various CO2 transcritical and cascade/secondary loop refrigeration systems that are becoming popular in supermarket applications with the objective of optimizing the operating parameters of these systems. In addition, the performance of selected CO2-based refrigeration systems is compared to the baseline R404A multiplex direct expansion system using bin analyses in the eight climate zones of the United States. Moreover, for the refrigeration systems investigated, it was found that the Transcritical Booster System with Bypass Compressor (TBS-BC) had the lowest energy consumption for ambient temperatures (Tamb) less than 8 °C, and for higher ambient temperatures the R404A direct expansion system was found to have the lowest energy consumption. Finally, the TBS-BC performs equivalent to or better than the R404A direct expansion system in the northern two-thirds of the US. For the southern portion of the US, the R404A multiplex DX system performs better than CO2 systems.

  12. Ancient and Modern Laminated Composites - From the Great Pyramid of Gizeh to Y2K

    SciTech Connect (OSTI)

    Wadsworth, J.; Lesuer, D.R.

    2000-03-14

    Laminated metal composites have been cited in antiquity; for example, a steel laminate that may date as far back as 2750 B.C., was found in the Great Pyramid in Gizeh in 1837. A laminated shield containing bronze, tin, and gold layers, is described in detail by Homer. Well-known examples of steel laminates, such as an Adze blade, dating to 400 B.C. can be found in the literature. The Japanese sword is a laminated composite at several different levels and Merovingian blades were composed of laminated steels. Other examples are also available, including composites from China, Thailand, Indonesia, Germany, Britain, Belgium, France, and Persia. The concept of lamination to provide improved properties has also found expression in modern materials. Of particular interest is the development of laminates including high carbon and low carbon layers. These materials have unusual properties that are of engineering interest; they are similar to ancient welded Damascus steels. The manufacture of collectable knives, labeled ''welded Damascus'', has also been a focus of contemporary knifemakers. Additionally, in the Former Soviet Union, laminated composite designs have been used in engineering applications. Each of the above areas will be briefly reviewed, and some of the metallurgical principles will be described that underlie improvement in properties by lamination. Where appropriate, links are made between these property improvements and those that may have been present in ancient artifacts.

  13. Waste management project's alternatives: A risk-based multi-criteria assessment (RBMCA) approach

    SciTech Connect (OSTI)

    Karmperis, Athanasios C.; Sotirchos, Anastasios; Aravossis, Konstantinos; Tatsiopoulos, Ilias P.

    2012-01-15

    Highlights: Black-Right-Pointing-Pointer We examine the evaluation of a waste management project's alternatives. Black-Right-Pointing-Pointer We present a novel risk-based multi-criteria assessment (RBMCA) approach. Black-Right-Pointing-Pointer In the RBMCA the evaluation criteria are based on the quantitative risk analysis of the project's alternatives. Black-Right-Pointing-Pointer Correlation between the criteria weight values and the decision makers' risk preferences is examined. Black-Right-Pointing-Pointer Preference to the multi-criteria against the one-criterion evaluation process is discussed. - Abstract: This paper examines the evaluation of a waste management project's alternatives through a quantitative risk analysis. Cost benefit analysis is a widely used method, in which the investments are mainly assessed through the calculation of their evaluation indicators, namely benefit/cost (B/C) ratios, as well as the quantification of their financial, technical, environmental and social risks. Herein, a novel approach in the form of risk-based multi-criteria assessment (RBMCA) is introduced, which can be used by decision makers, in order to select the optimum alternative of a waste management project. Specifically, decision makers use multiple criteria, which are based on the cumulative probability distribution functions of the alternatives' B/C ratios. The RBMCA system is used for the evaluation of a waste incineration project's alternatives, where the correlation between the criteria weight values and the decision makers' risk preferences is analyzed and useful conclusions are discussed.

  14. Comparative analysis of various CO2 configurations in supermarket refrigeration systems

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sharma, Vishaldeep; Fricke, Brian; Bansal, Pradeep

    2014-07-09

    Our paper presents an analysis of various CO2 transcritical and cascade/secondary loop refrigeration systems that are becoming popular in supermarket applications with the objective of optimizing the operating parameters of these systems. In addition, the performance of selected CO2-based refrigeration systems is compared to the baseline R404A multiplex direct expansion system using bin analyses in the eight climate zones of the United States. Moreover, for the refrigeration systems investigated, it was found that the Transcritical Booster System with Bypass Compressor (TBS-BC) had the lowest energy consumption for ambient temperatures (Tamb) less than 8 °C, and for higher ambient temperatures themore » R404A direct expansion system was found to have the lowest energy consumption. Finally, the TBS-BC performs equivalent to or better than the R404A direct expansion system in the northern two-thirds of the US. For the southern portion of the US, the R404A multiplex DX system performs better than CO2 systems.« less

  15. Numerical calculation of protein-ligand binding rates through solution of the Smoluchowski equation using smooth particle hydrodynamics

    SciTech Connect (OSTI)

    Pan, Wenxiao; Daily, Michael D.; Baker, Nathan A.

    2015-12-01

    We demonstrate the accuracy and effectiveness of a Lagrangian particle-based method, smoothed particle hydrodynamics (SPH), to study diffusion in biomolecular systems by numerically solving the time-dependent Smoluchowski equation for continuum diffusion. The numerical method is first verified in simple systems and then applied to the calculation of ligand binding to an acetylcholinesterase monomer. Unlike previous studies, a reactive Robin boundary condition (BC), rather than the absolute absorbing (Dirichlet) boundary condition, is considered on the reactive boundaries. This new boundary condition treatment allows for the analysis of enzymes with "imperfect" reaction rates. Rates for inhibitor binding to mAChE are calculated at various ionic strengths and compared with experiment and other numerical methods. We find that imposition of the Robin BC improves agreement between calculated and experimental reaction rates. Although this initial application focuses on a single monomer system, our new method provides a framework to explore broader applications of SPH in larger-scale biomolecular complexes by taking advantage of its Lagrangian particle-based nature.

  16. HOT GAS LINES IN T TAURI STARS

    SciTech Connect (OSTI)

    Ardila, David R.; Herczeg, Gregory J.; Gregory, Scott G.; Hillenbrand, Lynne A.; Ingleby, Laura; Bergin, Edwin; Bethell, Thomas; Calvet, Nuria; France, Kevin; Brown, Alexander; Edwards, Suzan; Johns-Krull, Christopher; Linsky, Jeffrey L.; Yang, Hao; Valenti, Jeff A.; Abgrall, Herve; Alexander, Richard D.; Brown, Joanna M.; Espaillat, Catherine; Hussain, Gaitee; and others

    2013-07-01

    For Classical T Tauri Stars (CTTSs), the resonance doublets of N V, Si IV, and C IV, as well as the He II 1640 A line, trace hot gas flows and act as diagnostics of the accretion process. In this paper we assemble a large high-resolution, high-sensitivity data set of these lines in CTTSs and Weak T Tauri Stars (WTTSs). The sample comprises 35 stars: 1 Herbig Ae star, 28 CTTSs, and 6 WTTSs. We find that the C IV, Si IV, and N V lines in CTTSs all have similar shapes. We decompose the C IV and He II lines into broad and narrow Gaussian components (BC and NC). The most common (50%) C IV line morphology in CTTSs is that of a low-velocity NC together with a redshifted BC. For CTTSs, a strong BC is the result of the accretion process. The contribution fraction of the NC to the C IV line flux in CTTSs increases with accretion rate, from {approx}20% to up to {approx}80%. The velocity centroids of the BCs and NCs are such that V{sub BC} {approx}> 4 V{sub NC}, consistent with the predictions of the accretion shock model, in at most 12 out of 22 CTTSs. We do not find evidence of the post-shock becoming buried in the stellar photosphere due to the pressure of the accretion flow. The He II CTTSs lines are generally symmetric and narrow, with FWHM and redshifts comparable to those of WTTSs. They are less redshifted than the CTTSs C IV lines, by {approx}10 km s{sup -1}. The amount of flux in the BC of the He II line is small compared to that of the C IV line, and we show that this is consistent with models of the pre-shock column emission. Overall, the observations are consistent with the presence of multiple accretion columns with different densities or with accretion models that predict a slow-moving, low-density region in the periphery of the accretion column. For HN Tau A and RW Aur A, most of the C IV line is blueshifted suggesting that the C IV emission is produced by shocks within outflow jets. In our sample, the Herbig Ae star DX Cha is the only object for which we find a

  17. Life cycle assessment of base-load heat sources for district heating system options

    SciTech Connect (OSTI)

    Ghafghazi, Saeed; Sowlati, T.; Sokhansanj, Shahabaddine; Melin, Staffan

    2011-03-01

    Purpose There has been an increased interest in utilizing renewable energy sources in district heating systems. District heating systems are centralized systems that provide heat for residential and commercial buildings in a community. While various renewable and conventional energy sources can be used in such systems, many stakeholders are interested in choosing the feasible option with the least environmental impacts. This paper evaluates and compares environmental burdens of alternative energy source options for the base load of a district heating center in Vancouver, British Columbia (BC) using the life cycle assessment method. The considered energy sources include natural gas, wood pellet, sewer heat, and ground heat. Methods The life cycle stages considered in the LCA model cover all stages from fuel production, fuel transmission/transportation, construction, operation, and finally demolition of the district heating system. The impact categories were analyzed based on the IMPACT 2002+ method. Results and discussion On a life-cycle basis, the global warming effect of renewable energy options were at least 200 kgeqCO2 less than that of the natural gas option per MWh of heat produced by the base load system. It was concluded that less than 25% of the upstream global warming impact associated with the wood pellet energy source option was due to transportation activities and about 50% of that was resulted from wood pellet production processes. In comparison with other energy options, the wood pellets option has higher impacts on respiratory of inorganics, terrestrial ecotoxicity, acidification, and nutrification categories. Among renewable options, the global warming impact of heat pump options in the studied case in Vancouver, BC, were lower than the wood pellet option due to BC's low carbon electricity generation profile. Ozone layer depletion and mineral extraction were the highest for the heat pump options due to extensive construction required for these

  18. INTEGRATED OUTCROP AND SUBSURFACE STUDIES OF THE INTERWELL ENVIRONMENT OF CARBONATE RESERVOIRS: CLEAR FORK (LEONARDIAN-AGE) RESERVOIRS, WEST TEXAS AND NEW MEXICO

    SciTech Connect (OSTI)

    F. Jerry Lucia

    2002-01-31

    This is the final report of the project ''Integrated Outcrop and Subsurface Studies of the Interwell Environment of Carbonate Reservoirs: Clear Fork (Leonardian-Age) Reservoirs, West Texas and New Mexico'', Department of Energy contract no. DE-AC26-98BC15105 and is the third in a series of similar projects funded jointly by the U.S. Department of Energy and The University of Texas at Austin, Bureau of Economic Geology, Reservoir Characterization Research Laboratory for Carbonates. All three projects focus on the integration of outcrop and subsurface data for the purpose of developing improved methods for modeling petrophysical properties in the interwell environment. The first project, funded by contract no. DE-AC22-89BC14470, was a study of San Andres outcrops in the Algerita Escarpment, Guadalupe Mountains, Texas and New Mexico, and the Seminole San Andres reservoir, Permian Basin. This study established the basic concepts for constructing a reservoir model using sequence-stratigraphic principles and rock-fabric, petrophysical relationships. The second project, funded by contract no. DE-AC22-93BC14895, was a study of Grayburg outcrops in the Brokeoff Mountains, New Mexico, and the South Cowden Grayburg reservoir, Permian Basin. This study developed a sequence-stratigraphic succession for the Grayburg and improved methods for locating remaining hydrocarbons in carbonate ramp reservoirs. The current study is of the Clear Fork Group in Apache Canyon, Sierra Diablo Mountains, West Texas, and the South Wasson Clear Fork reservoir, Permian Basin. The focus was on scales of heterogeneity, imaging high- and low-permeability layers, and the impact of fractures on reservoir performance. In this study (1) the Clear Fork cycle stratigraphy is defined, (2) important scales of petrophysical variability are confirmed, (3) a unique rock-fabric, petrophysical relationship is defined, (4) a porosity method for correlating high-frequency cycles and defining rock-fabric flow layers

  19. EVALUATION OF VADOSE ZONE TREATMENT TECHNOLOGIES TO IMMOBILIZE TECHNETIUM-99

    SciTech Connect (OSTI)

    PETERSEN, S.W.

    2006-03-15

    The Hanford Site End State Vision document (DOE/RL-2003-59) states: ''There should be an aggressive plan to develop technology for remediation of the contamination that could get to the groundwater (particularly the technetium [{sup 99}Tc])''. In addition, there is strong support from the public and regulatory agencies for the above statement, with emphasis on investigation of treatment alternatives. In July 2004, PNNL completed a preliminary evaluation of remediation technologies with respect to their effectiveness and implementability for immobilization of {sup 99}Tc beneath the BC Cribs in the 200 West Area (Truex, 2004). As a result of this evaluation, PNNL recommended treatability testing of in situ soil desiccation, because it has the least uncertainty of those technologies evaluated in July 2004 (Treatability Test Outline, September 30, 2004). In 2005, DOE-RL and Fluor Hanford convened an independent technical panel to review alternative remediation technologies, including desiccation, at a three-day workshop in Richland, Washington. The panel was composed of experts in vadose-zone transport, infiltration control, hydrology, geochemistry, environmental engineering, and geology. Their backgrounds include employment in academia, government laboratories, industry, and consulting. Their review, presented in this document, is based upon written reports from Hanford, oral presentations from Hanford staff, and each panel members' years of experience in their particular field of expertise. The purpose of this report is to document the panel's evaluation of various treatment alternatives with potential for minimizing contaminant migration in the deep vadose zone at the Department of Energy Hanford Site. The panel was tasked with assessing the most viable and practical approach and making recommendations for testing. The evaluation of vadose-zone treatment alternatives was conducted to be broadly applicable at a variety of locations at Hanford. However, because of

  20. Nickel aluminide alloy suitable for structural applications

    DOE Patents [OSTI]

    Liu, Chain T.

    1998-01-01

    Alloys for use in structural applications based upon NiAl to which are added selected elements to enhance room temperature ductility and high temperature strength. Specifically, small additions of molybdenum produce a beneficial alloy, while further additions of boron, carbon, iron, niobium, tantalum, zirconium and hafnium further improve performance of alloys at both room temperature and high temperatures. A preferred alloy system composition is Ni--(49.1.+-.0.8%)Al--(1.0.+-.0.8%)Mo--(0.7.+-.0.5%)Nb/Ta/Zr/Hf--(nearly zero to 0.03%)B/C, where the % is at. % in each of the concentrations. All alloys demonstrated good oxidation resistance at the elevated temperatures. The alloys can be fabricated into components using conventional techniques.

  1. Nickel aluminide alloy suitable for structural applications

    DOE Patents [OSTI]

    Liu, C.T.

    1998-03-10

    Alloys are disclosed for use in structural applications based upon NiAl to which are added selected elements to enhance room temperature ductility and high temperature strength. Specifically, small additions of molybdenum produce a beneficial alloy, while further additions of boron, carbon, iron, niobium, tantalum, zirconium and hafnium further improve performance of alloys at both room temperature and high temperatures. A preferred alloy system composition is Ni--(49.1{+-}0.8%)Al--(1.0{+-}0.8%)Mo--(0.7 + 0.5%)Nb/Ta/Zr/Hf--(nearly zero to 0.03%)B/C, where the % is at. % in each of the concentrations. All alloys demonstrated good oxidation resistance at the elevated temperatures. The alloys can be fabricated into components using conventional techniques. 4 figs.

  2. SOLICITATION, OFFER AND AWARD

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SOLICITATION, OFFER AND AWARD !, TI11S COllT!<'}.l~f l8 AW.TEO ORDER Vr;OER O?>.$ (IS CfR TCO) fiATJtiG I 3 ~-DATE 1SSli[O ] Ii. RE,QU:siilO!i'f'lJRCl-'ASE !llcl/BC.R 15F:M002922 EMCHC U.S. Dep:1rl".!n0.nt of Energy EM Consoliciat.ed Businnss CeriLer 250 E:. Sth Str~at, S11ite 500 Cincinnnl.i Ofl 4S20~ - - - - - - - - - - - - - - - - - - - - - - - - - - - - ---------- NOTE: fft1U]*4 b!d Ut(j!1\lo~1 *0Ntf"3od ''1lff£10('mol'1"bj.j*and._'"""'~"c'°~* - - -

  3. Small-angle fragmentation of carbon ions at 0.6 GeV/n: A comparison with models of ion-ion interactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Krutenkova, A. P.; Abramov, B. M.; Alekseev, P. N.; Borodin, Yu. A.; Bulychjov, S. A.; Dukhovskoy, I. A.; Khanov, A. I.; Kulikov, V. V.; Martemianov, M. A.; Mashnik, S. G.; et al

    2015-05-29

    Momentum distributions of hydrogen and helium isotopes from ¹²C fragmentation at 3.5° were measured at 0.6 GeV/nucleon in the FRAGM experiment at ITEP TWA heavy ion accelerator. The fragments were selected by correlated time of flight and dE/dx measurements with a magnetic spectrometer with scintillation counters. The main attention was drawn to the high momentum region where the fragment velocity exceeds the velocity of the projectile nucleus. The momentum spectra of fragments span the region of the fragmentation peak as well as the cumulative region. The differential cross sections cover six orders of magnitude. The distributions measured are compared tomore » the predictions of three ion-ion interaction models: BC, QMD and LAQGSM03.03. The kinetic energy spectra of fragments in the projectile rest frame have an exponential shape with two temperatures, being defined by their slope parameters.« less

  4. EXECUTIVE SUMMARY OF STATE DATA RELATED TO ABANDONED CENTRALIZED AND COMMERCIAL DRILLING-FLUID DISPOSAL SITES IN LOUISIANA, NEW MEXICO, OKLAHOMA, AND TEXAS

    SciTech Connect (OSTI)

    H. Seay Nance

    2003-03-01

    This 2003 Spring Semi-Annual Report contains a summary of the Final Technical Report being prepared for the Soil Remediation Requirements at Commercial and Centralized Drilling-Fluid Disposal (CCDD) Sites project funded by the United States Department of Energy under DOE Award No. DE-AC26-99BC15225. The summary describes (1) the objectives of the investigation, (2) a rationale and methodology of the investigation, (3) sources of data, assessment of data quality, and data availability, (4) examples of well documented centralized and commercial drilling-fluid disposal (CCDD) sites and other sites where drilling fluid was disposed of, and (5) examples of abandoned sites and measures undertaken for their assessment and remediation. The report also includes most of the figures, tables, and appendices that will be included in the final report.

  5. Analytical description of the Jc(B) dependence of high Tc superconducting thin films in small perpendicular fields

    SciTech Connect (OSTI)

    Hanisch, Jens; Grilli, Francesco; Holzapfel, Bernhard

    2008-01-01

    The field dependencies of J{sub c} of YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} based high-temperature superconducting thin films are measured in fine steps for B||c in a wide temperature range. It is found that J{sub c}(B) of all samples can be described by a generalization of Kim's critical state model with two additional variables. At very low fields, a plateau of constant J{sub c} is observed, for which two possible reasons are discussed - self-field effects and a strong single-vortex pinning mechanism. Around 1 T we identified a small 'peak' which may be responsible for ultralow experimental {alpha} values in high-quality samples.

  6. Peptides whose uptake by cells is controllable

    DOE Patents [OSTI]

    Jiang, Tao; Olson, Emilia S.; Whitney, Michael; Tsien, Roger

    2011-07-26

    A generic structure for the peptides of the present invention includes A-X-B-C, where C is a cargo moiety, the B portion includes basic amino acids, X is a cleavable linker sequence, and the A portion includes acidic amino acids. The intact structure is not significantly taken up by cells; however, upon extracellular cleavage of X, the B-C portion is taken up, delivering the cargo to targeted cells. Cargo may be, for example, a contrast agent for diagnostic imaging, a chemotherapeutic drug, or a radiation-sensitizer for therapy. X may be cleaved extracellularly or intracellularly. The molecules of the present invention may be linear, cyclic, branched, or have a mixed structure.

  7. Peptides whose uptake by cells is controllable

    DOE Patents [OSTI]

    Jiang, Tao; Olson, Emilia S.; Whitney, Michael; Tsien, Roger

    2015-07-07

    A generic structure for the peptides of the present invention includes A-X-B-C, where C is a cargo moiety, the B portion includes basic amino acids, X is a cleavable linker sequence, and the A portion includes acidic amino acids. The intact structure is not significantly taken up by cells; however, upon extracellular cleavage of X, the B-C portion is taken up, delivering the cargo to targeted cells. Cargo may be, for example, a contrast agent for diagnostic imaging, a chemotherapeutic drug, or a radiation-sensitizer for therapy. X may be cleaved extracellularly or intracellularly. The molecules of the present invention may be linear, cyclic, branched, or have a mixed structure.

  8. Library Resources for Bac End Sequencing. Final Technical Report

    SciTech Connect (OSTI)

    Pieter J. de Jong

    2000-10-01

    Studies directed towards the specific aims outlined for this research award are summarized. The RPCI II Human Bac Library has been expanded by the addition of 6.9-fold genomic coverage. This segment has been generated from a MBOI partial digest of the same anonymous donor DNA used for the rest of the library. A new cloning vector, pTARBAC1, has been constructed and used in the construction of RPCI-II segment 5. This new cloning vector provides a new strategy in identifying targeted genomic regions and will greatly facilitate a large-scale analysis for positional cloning. A new maleCS7BC/6J mouse BAC library has been constructed. RPCI-23 contain 576 plates (approx 210,000 clones) and represents approximately 11-fold coverage of the mouse genome.

  9. Project Records Information System (PRIS) user's manual

    SciTech Connect (OSTI)

    Smith, P.S.; Nations, J.A.; Short, R.D.

    1991-08-01

    The Projects Record Information System (PRIS) is an interactive system developed for the Information Services Division (ISD) of Martin Marietta Energy Systems, Inc., to perform indexing, maintenance, and retrieval of information about Engineering project record documents for which they are responsible. This PRIS User's Manual provides instruction on the use of this system. Section 2.0 of this manual presents an overview of PRIS, describing the system's purpose; the data that it handles, functions it performs; hardware, software, and access; and help and error functions. Section 3.0 describes the interactive menu-driven operation of PRIS. Appendixes A, B,C, and D contain the data dictionary, help screens, report descriptions, and a primary menu structure diagram, respectively.

  10. Impact of Different Economic Performance Metrics on the Perceived Value of Solar Photovoltaics

    SciTech Connect (OSTI)

    Drury, E.; Denholm, P.; Margolis, R.

    2011-10-01

    Photovoltaic (PV) systems are installed by several types of market participants, ranging from residential customers to large-scale project developers and utilities. Each type of market participant frequently uses a different economic performance metric to characterize PV value because they are looking for different types of returns from a PV investment. This report finds that different economic performance metrics frequently show different price thresholds for when a PV investment becomes profitable or attractive. Several project parameters, such as financing terms, can have a significant impact on some metrics [e.g., internal rate of return (IRR), net present value (NPV), and benefit-to-cost (B/C) ratio] while having a minimal impact on other metrics (e.g., simple payback time). As such, the choice of economic performance metric by different customer types can significantly shape each customer's perception of PV investment value and ultimately their adoption decision.

  11. Small-angle fragmentation of carbon ions at 0.6 GeV/n. A comparison with models of ion-ion interactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Krutenkova, Anna P.; Abramov, B. M.; Alekseev, P. N.; Borodin, Yu. A.; Bulychjov, S. A.; Dukhovskoy, I. A.; Khanov, A. I.; Kulikov, V. V.; Martemianov, M. A.; Mashnik, Stepan Georgievich; et al

    2015-05-29

    The momentum distributions of hydrogen and helium isotopes from 12C fragmentation at 3.5° were measured at 0.6 GeV/nucleon in the FRAGM experiment at ITEP TWA heavy ion accelerator. The fragments were selected by correlated time of flight and dE/dx measurements with a magnetic spectrometer with scintillation counters. The main attention was drawn to the high momentum region where the fragment velocity exceeds the velocity of the projectile nucleus. The momentum spectra of fragments span the region of the fragmentation peak as well as the cumulative region. Moreover, the differential cross sections cover six orders of magnitude. The distributions measured aremore » compared to the predictions of three ion-ion interaction models: BC, QMD and LAQGSM03.03. The kinetic energy spectra of fragments in the projectile rest frame have an exponential shape with two temperatures, being defined by their slope parameters.« less

  12. Revised DOE Acquisition Guide Chapter 7 1.1 Headquarters Business Clearance Process (wrong document under this file name)

    Broader source: Energy.gov [DOE]

    There was mention in the National Academy of Public Administration (NAPA) report titled "Managing at the Speed of Light - Improving Mission Support Performance" that Departmental procurement personnel don't understand the Business Clearance (BC) process. In an effort to address this issue, each Procurement Director (PD) and Head of Contracting Activity (HCA) was ask to review Acquisition Guide Chapter 7 1.1 Headquarters Business Clearance Process and identify anything that was unclear, as well as recommend changes or ideas which could improve Acquisition Guide Chapter 71.1 and the understanding of the Business Clearance process. Attached is the revised Acquisition Guide Chapter 71.1 (May 20 10) which reflects the comments and suggestions received.

  13. Sundance 2.0 tutorial.

    SciTech Connect (OSTI)

    Long, Kevin R.

    2004-07-01

    Sundance is a system of software components that allows construction of an entire parallel simulator and its derivatives using a high-level symbolic language. With this high-level problem description, it is possible to specify a weak formulation of a PDE and its discretization method in a small amount of user-level code; furthermore, because derivatives are easily available, a simulation in Sundance is immediately suitable for accelerated PDE-constrained optimization algorithms. This paper is a tutorial for setting up and solving linear and nonlinear PDEs in Sundance. With several simple examples, we show how to set up mesh objects, geometric regions for BC application, the weak form of the PDE, and boundary conditions. Each example then illustrates use of an appropriate solver and solution visualization.

  14. Fast beam studies of free radical photodissociation

    SciTech Connect (OSTI)

    Neumark, D.M.

    1993-12-01

    The authors have developed a novel technique for studying the photodissociation spectroscopy and dynamics of free radicals. In these experiments, radicals are generated by laser photodetachment of a fast (6-8 keV) mass-selected negative ion beam. The resulting radicals are photodissociated with a second laser, and the photofragments are collected and detected with high efficiency using a microchannel plate detector. The overall process is: ABC{sup -} {yields} ABC + e{sup -} {yields} A + BC, AB + C. Two types of fragment detection schemes are used. To map out the photodissociation cross-section of the radical, the photodissociation laser is scanned and the total photofragment yield is measured as a function of wavelength. In other experiments, the photodissociation frequency is fixed and the photofragment masses, kinetic energy release, and scattering angle is determined for each photodissociation event.

  15. Anomalous magnetic structure and spin dynamics in magnetoelectric LiFePO4

    SciTech Connect (OSTI)

    Toft-Petersen, Rasmus; Reehuis, Manfred; Jensen, Thomas B. S.; Andersen, Niels H.; Li, Jiying; Le, Manh Duc; Laver, Mark; Niedermayer, Christof; Klemke, Bastian; Lefmann, Kim; Vaknin, David

    2015-07-06

    We report significant details of the magnetic structure and spin dynamics of LiFePO4 obtained by single-crystal neutron scattering. Our results confirm a previously reported collinear rotation of the spins away from the principal b axis, and they determine that the rotation is toward the a axis. In addition, we find a significant spin-canting component along c. Furthermore, the possible causes of these components are discussed, and their significance for the magnetoelectric effect is analyzed. Inelastic neutron scattering along the three principal directions reveals a highly anisotropic hard plane consistent with earlier susceptibility measurements. While using a spin Hamiltonian, we show that the spin dimensionality is intermediate between XY- and Ising-like, with an easy b axis and a hard c axis. As a result, it is shown that both next-nearest neighbor exchange couplings in the bc plane are in competition with the strongest nearest neighbor coupling.

  16. Terahertz radiation from a laser bunched relativistic electron beam in a magnetic wiggler

    SciTech Connect (OSTI)

    Kumar, Manoj; Tripathi, V. K. [Department of Physics, Indian Institute of Technology, Delhi, New Delhi 110016 (India)

    2012-07-15

    We develop a formalism for tunable coherent terahertz radiation generation from a relativistic electron beam, modulated by two laser beams, as it passes through a magnetic wiggler of wave vector k{sub w}z-caret. The lasers exert a beat frequency ponderomotive force on beam electrons, and modulate their velocity. In the drift space, velocity modulation translates into density modulation. As the beam bunches pass through the wiggler, they acquire a transverse velocity, constituting a transverse current that acts as an antenna to produce coherent THz radiation, when {omega}{sub 1}-{omega}{sub 2}=k{sub w}c/(cos{theta}-v{sub 0b}/c), where {omega}{sub 1}, {omega}{sub 2} are the frequencies of the lasers, v{sub 0b}z-caret is the beam velocity, and {theta} is the direction of maximum radiated intensity with respect to the direction of propagation of the beam.

  17. Peptides whose uptake by cells is controllable

    DOE Patents [OSTI]

    Jiang, Tao; Tsien, Roger Y.

    2012-02-07

    A generic structure for the peptides of the present invention includes A-X-B-C, where C is a cargo moiety, the B portion includes basic amino acids, X is a cleavable linker sequence, and the A portion includes acidic amino acids. The intact structure is not significantly taken up by cells; however, upon extracellular cleavage of X, the B-C portion is taken up, delivering the cargo to targeted cells. Cargo may be, for example, a contrast agent for diagnostic imaging, a chemotherapeutic drug, or a radiation-sensitizer for therapy. Cleavage of X allows separation of A from B, unmasking the normal ability of the basic amino acids in B to drag cargo C into cells near the cleavage event. X is cleaved extracellularly, preferably under physiological conditions. D-amino acids are preferred for the A and B portions, to minimize immunogenicity and nonspecific cleavage by background peptidases or proteases.

  18. The Utilization of the Microflora Indigenous to and Present in Oil-Bearing Formations to Selectively Plug the More Porous Zones Thereby Increasing Oil Recovery During Waterflooding

    SciTech Connect (OSTI)

    Brown, Lewis R.; Byrnes, Martin J.; Stephens, James O.; Vadie, Alex A.

    1999-07-01

    This project was designed to demonstrate that a microbially enhanced oil recovery process (MEOR), developed in part under DOE Contract No. DE-AC22-90BC14665, will increase oil recovery from fluvial dominated deltaic oil reservoirs. The process involves stimulating the in-situ indigenous microbial population in the reservoir to grow in the more permeable zones, thus diverting flow to other areas of the reservoir, thereby increasing the effectiveness of the waterflood. This five and a half year project is divided into three phases, Phase I, Planning and Analysis (9 months), Phase II, Implementation (45 months), and Phase III, Technology Transfer (12 months). Phase I was completed and reported in the first annual report. This fifth annual report covers the completion of Phase II and the first six months of Phase III.

  19. SOLICITATION, OFFER AND AWARD

    Office of Environmental Management (EM)

    SOLICITATION, OFFER AND AWARD !, TI11S COllT!<'}.l~f l8 AW.TEO ORDER Vr;OER O?>.$ (IS CfR TCO) fiATJtiG I 3 ~-DATE 1SSli[O ] Ii. RE,QU:siilO!i'f'lJRCl-'ASE !llcl/BC.R 15F:M002922 EMCHC U.S. Dep:1rl".!n0.nt of Energy EM Consoliciat.ed Businnss CeriLer 250 E:. Sth Str~at, S11ite 500 Cincinnnl.i Ofl 4S20~ - - - - - - - - - - - - - - - - - - - - - - - - - - - - ---------- NOTE: fft1U]*4 b!d Ut(j!1\lo~1 *0Ntf"3od ''1lff£10('mol'1"bj.j*and._'"""'~"c'°~* - - -

  20. Peptides whose uptake by cells is controllable

    DOE Patents [OSTI]

    Jiang, Tao; Tsien, Roger Y.

    2008-10-07

    A generic structure for the peptides of the present invention includes A-X-B-C, where C is a cargo moiety, the B portion includes basic amino acids, X is a cleavable linker sequence, and the A portion includes acidic amino acids. The intact structure is not significantly taken up by cells; however, upon extracellular cleavage of X, the B-C portion is taken up, delivering the cargo to targeted cells. Cargo may be, for example, a contrast agent for diagnostic imaging, a chemotherapeutic drug, or a radiation-sensitizer for therapy. Cleavage of X allows separation of A from B, unmasking the normal ability of the basic amino acids in B to drag cargo C into cells near the cleavage event. X is cleaved extracellularly, preferably under physiological conditions. D-amino acids are preferred for the A and B portions, to minimize immunogenicity and nonspecific cleavage by background peptidases or proteases.

  1. Peptides whose uptake by cells is controllable

    DOE Patents [OSTI]

    Jiang, Tao; Tsien, Roger Y

    2014-02-04

    A generic structure for the peptides of the present invention includes A-X-B-C, where C is a cargo moiety, the B portion includes basic amino acids, X is a cleavable linker sequence, and the A portion includes acidic amino acids. The intact structure is not significantly taken up by cells; however, upon extracellular cleavage of X, the B-C portion is taken up, delivering the cargo to targeted cells. Cargo may be, for example, a contrast agent for diagnostic imaging, a chemotherapeutic drug, or a radiation-sensitizer for therapy. Cleavage of X allows separation of A from B, unmasking the normal ability of the basic amino acids in B to drag cargo C into cells near the cleavage event. X is cleaved extracellularly, preferably under physiological conditions. D-amino acids are preferred for the A and B portions, to minimize immunogenicity and nonspecific cleavage by background peptidases or proteases.

  2. Small angle neutron scattering as fingerprinting of ancient potteries from Sicily (Southern Italy)

    SciTech Connect (OSTI)

    Barone, G.; Mazzoleni, P.; Crupi, V.; Majolino, D.; Venuti, V.; Teixeira, J.

    2009-09-01

    Small angle neutron scattering measurements have been carried out in order to investigate, in microdestructive way, the mesoscopic structure of a variety of potteries of relevance to cultural heritage coming from different Sicilian (Southern Italy) archeological sites belonging to the 'Strait of Messina' area and dated back to 7th-3rd century B.C. Data have been compared with the mesoscopic parameters extracted for two series of clayey sediments typical of the Strait of Messina area and fired under controlled conditions. The observed agreement between the features of reference and archeological samples allowed us to estimate the maximum firing temperature of the latter. Information on the pore sizes was obtained by the use of the concept of fractal surface, and compared with porosimetry results.

  3. Gypsy Field project in reservoir characterization

    SciTech Connect (OSTI)

    Castagna, John P.; Jr., O'Meara, Daniel J.

    2000-01-12

    The overall objective of this project was to use extensive Gypsy Field Laboratory and data as a focus for developing and testing reservoir characterization methods that are targeted at improved recovery of conventional oil. This report describes progress since project report DOE/BC/14970-7 and covers the period June 1997-September 1998 and represents one year of funding originally allocated for the year 1996. During the course of the work previously performed, high resolution geophysical and outcrop data revealed the importance of fractures at the Gypsy site. In addition, personnel changes and alternative funding (OCAST and oil company support of various kinds) allowed the authors to leverage DOE contributions and focus more on geophysical characterization.

  4. Pacific Northwest Storms Situation Report # 1

    SciTech Connect (OSTI)

    2006-12-15

    Severe wind and snow storms hit the Pacific Northwest region on December 14 – 15, 2006, following severe flooding during the past few days. The severe weather resulted in major power outages through the region. At peak there were 1.8 million customers without power which included BC Hydro in Canada. Currently, there are over 1.5 million outages in the region as a result of the Pacific Northwest Storms. This represents about 42 percent of customers in affected utility service areas in Oregon and Washington. See table below. Because the current wind and snow storms are coming on the heels of extensive flooding in the region, electric utilities are experiencing damage. Wind gusts reached close to 100 mph in some areas of the region. The storm is expected to bring its strong winds and heavy snow into Idaho, Montana and Wyoming Friday and into the weekend. There are currently no reported major impacts to the petroleum and natural gas infrastructure.

  5. Bat Surveys of Retired Facilitiies Scheduled for Demolition by Washington Closure Hanford

    SciTech Connect (OSTI)

    Gano, K. A.; Lucas, J. G.; Lindsey, C. T.

    2011-06-30

    This project was conducted to evaluate buildings and facilities remaining in the Washington Closure Hanford (WCH) deactivation, decontamination, decommissioning, and demolition schedule for bat roost sites. The project began in spring of 2009 and was concluded in spring of 2011. A total of 196 buildings and facilities were evaluated for the presence of bat roosting sites. The schedule for the project was prioritized to accommodate the demolition schedule. As the surveys were completed, the results were provided to the project managers to facilitate planning and project completion. The surveys took place in the 300 Area, 400 Area, 100-H, 100-D, 100-N, and 100-B/C Area. This report is the culmination of all the bat surveys and summarizes the findings by area and includes recommended mitigation actions where bat roosts were found.

  6. The Standards Forum, September 2001

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    %*+"%,-.%/"0+12034%5*3163'6$%%%%% 7'(8'3)%-&&20"%9/57-:% ;(21*%<"$=(1$2>242*?%.$*3>42$+"6%&('%/#(%,-.%/"0+12034%5*3163'6$% !! "!#$"%!&''()!*+,!-./.!0%123*4%"*!,5!6"%378!90:6;!13%123<"7!2=*<><? *<%@)!0A?BC!2"D!6E?CF)!273%%D!*,!G,<"*H8!@I23%!3%@1,"@<J<H<*8!5,3!*I%!*%=I"<=2H!D%>%H?

  7. Influence of potentially lethal temperature and food on the behavior of juvenile chum salmon, Oncorhynchus keta, under simulated marine conditions. Canadian data report of fisheries and aquatic sciences Number 1040

    SciTech Connect (OSTI)

    Korstrom, J.S.

    1998-12-31

    This is one of a series of reports that describe results of field and laboratory studies on the effect of heated sea water on juvenile chum salmon. The studies were initiated in response to potential increases in the thermal discharge from BC Hydro`s Burrard Generating Station into the marine waters of Port Moody Arm, Burrard Inlet. The report presents results of the first of two 1997 studies, in which the behaviour of chum salmon in response to heated sea water was investigated in the laboratory using a water column simulator that mimicked conditions the fish may encounter in Port Moody Arm. The behaviour of the salmon was examined under controlled conditions during a changing thermal regime and under thermally stratified conditions. The response of the fish to food, their swimming, and school positions were quantified in relation to experimental conditions.

  8. Vertical distribution of juvenile chum salmon, Oncorhynchus keta, in relation to a thermal discharge into Port Moody Arm, Burrard Inlet, British Columbia. Canadian technical report of fisheries and aquatic sciences Number 2235

    SciTech Connect (OSTI)

    Birtwell, I.K.

    1998-12-31

    This is one of a series of reports that describe results of field and laboratory studies on the effect of heated sea water on juvenile chum salmon. The studies were initiated in response to potential increases in the thermal discharge from BC Hydro`s Burrard Generating Station into the marine waters of Port Moody Arm, Burrard Inlet. The report presents results of the second of two 1997 studies, in which preference/avoidance cages in Port Moody Arm were used to examine the vertical distribution of chum salmon at a reference location and at sites 70, 250, and 1,200 metres from the heated cooling water discharge. The results were related to the ambient aquatic conditions to reveal differences or similarities in the vertical distribution of salmon with proximity to discharge location, and to identify variables that accounted for these changes.

  9. Small-angle fragmentation of carbon ions at 0.6 GeV/n: A comparison with models of ion-ion interactions

    SciTech Connect (OSTI)

    Krutenkova, A. P.; Abramov, B. M.; Alekseev, P. N.; Borodin, Yu. A.; Bulychjov, S. A.; Dukhovskoy, I. A.; Khanov, A. I.; Kulikov, V. V.; Martemianov, M. A.; Mashnik, S. G.; Matsyuk, M. A.; Turdakina, E. N.; Bravina, L.; Foka, Y.; Kabana, S.

    2015-05-29

    Momentum distributions of hydrogen and helium isotopes from C fragmentation at 3.5 were measured at 0.6 GeV/nucleon in the FRAGM experiment at ITEP TWA heavy ion accelerator. The fragments were selected by correlated time of flight and dE/dx measurements with a magnetic spectrometer with scintillation counters. The main attention was drawn to the high momentum region where the fragment velocity exceeds the velocity of the projectile nucleus. The momentum spectra of fragments span the region of the fragmentation peak as well as the cumulative region. The differential cross sections cover six orders of magnitude. The distributions measured are compared to the predictions of three ion-ion interaction models: BC, QMD and LAQGSM03.03. The kinetic energy spectra of fragments in the projectile rest frame have an exponential shape with two temperatures, being defined by their slope parameters.

  10. Delivery of the Canadian Entitlement : Final Environmental Impact Statement : Record of Decision, Summary..

    SciTech Connect (OSTI)

    United States. Bonneville Power Administration.

    1996-01-01

    The US Entity (the Administrator of the Bonneville Power Administration (BPA) and the Division Engineer, North Pacific Division of the US Army Corps of Engineers) has decided to fulfill its obligation under the Columbia River Treaty (Treaty) between the US and Canada by delivering Canada`s Entitlement under the Treaty to a point on the US/Canada border near Oliver, British Columbia (BC). Delivering the Entitlement at that location will require BPA to construct and operate a new single-circuit 500-kV transmission line from Grand Coulee or Chief Joseph Substation to the US/Canada border, a distance of 135 to 155 kilometers (85 to 95 miles), depending on the alignment selected. This paper describes the decision process and its environmental impacts.

  11. HEALTH AhO SAFETY DIVISION Industrial Hygiene or Medical Dept.

    Office of Legacy Management (LM)

    ALYTICAL DATA SHEET ANALYTICAL DEPT. - HEALTH AhO SAFETY DIVISION Industrial Hygiene or Medical Dept. m 1956 w I. H.# 7g2 Semplb Nos l2 Date Collected- 512 by RlX -----Route to EA LocetionKN(U[YTr-r-ETyp of Sample ~hd%---Analyzed for F Alphaxx Rema&mre t&n from the furnace and from U= Beta JOC slap ladles. No, Ro Oil PH Be Th Nc0 NO 8506 BcA-j &A- ii \JC cL"w-- Anolyticol Chemistry Secrion: Date Received--!b4-56 by Lab* Date Reported 6-X-66 bu I&b , Method of Analyair

  12. Design and construction of pulsed neutron diagnostic system for plasma focus device (SBUPF1)

    SciTech Connect (OSTI)

    Moghadam, Sahar Rajabi; Davani, Fereydoon Abbasi

    2010-07-15

    In this paper, two designs of pulsed neutron counter structure are introduced. To increase the activation counter efficiency, BC-400 plastic scintillator plates along with silver foils are utilized. Rectangular cubic and cylindrical geometries for activation counter cell are modeled using MCNP4C code. Eventually, an optimum length of 14 cm is calculated for the detector cell and optimum numbers of 20 silver foils for rectangular cubic geometry and ten foils for cylindrical geometry have been acquired. Due to the high cost of cutting, polishing of plastics, and etc., the rectangular cubic design is found to be more economical than the other design. In order to examine the functionality and ensure the detector output and corresponding designing, neutron yield of a 2.48 kJ plasma focus device (SBUPF1) in 8 mbar pressure with removal source method for calibration was measured (3.71{+-}0.32)x10{sup 7} neutrons per shot.

  13. Community Loblolly Pine Slash Pine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Community _ Loblolly Pine _ Slash Pine oMixed Pine/Hardwood D Upland Hardwod LJ Bottomland Hardwood IJ::J Carolina Bay Wetland * Wastesites N Streams I)iI, Utility ROW /l\W Roads oTES Plants (2) o SRS Bays D Three Rivers Landfill E2J Hydric Soils 280 o Soils Soil Series and Phase D BcB 1iii0g DOrA _ OrB D Rm _ TrB D WaB 280 I Il~ I ~ Figure 23-1. Plant cOllllllunities and soils associated with the Dry Bay Set-Aside Area. 23-7 Set-Aside 23: Dry Bay

  14. A New WRF-Chem Treatment for Studying Regional Scale Impacts of Cloud-Aerosol Interactions in Parameterized Cumuli

    SciTech Connect (OSTI)

    Berg, Larry K.; Shrivastava, ManishKumar B.; Easter, Richard C.; Fast, Jerome D.; Chapman, Elaine G.; Liu, Ying

    2015-01-01

    A new treatment of cloud-aerosol interactions within parameterized shallow and deep convection has been implemented in WRF-Chem that can be used to better understand the aerosol lifecycle over regional to synoptic scales. The modifications to the model to represent cloud-aerosol interactions include treatment of the cloud dropletnumber mixing ratio; key cloud microphysical and macrophysical parameters (including the updraft fractional area, updraft and downdraft mass fluxes, and entrainment) averaged over the population of shallow clouds, or a single deep convective cloud; and vertical transport, activation/resuspension, aqueous chemistry, and wet removal of aerosol and trace gases in warm clouds. Thesechanges have been implemented in both the WRF-Chem chemistry packages as well as the Kain-Fritsch cumulus parameterization that has been modified to better represent shallow convective clouds. Preliminary testing of the modified WRF-Chem has been completed using observations from the Cumulus Humilis Aerosol Processing Study (CHAPS) as well as a high-resolution simulation that does not include parameterized convection. The simulation results are used to investigate the impact of cloud-aerosol interactions on the regional scale transport of black carbon (BC), organic aerosol (OA), and sulfate aerosol. Based on the simulations presented here, changes in the column integrated BC can be as large as -50% when cloud-aerosol interactions are considered (due largely to wet removal), or as large as +35% for sulfate in non-precipitating conditions due to the sulfate production in the parameterized clouds. The modifications to WRF-Chem version 3.2.1 are found to account for changes in the cloud drop number concentration (CDNC) and changes in the chemical composition of cloud-drop residuals in a way that is consistent with observations collected during CHAPS. Efforts are currently underway to port the changes described here to WRF-Chem version 3.5, and it is anticipated that they

  15. Protonation Studies of a Mono-Dinitrogen Complex of Chromium Supported by a 12-Membered Phosphorus Macrocycle Containing Pendant Amines

    SciTech Connect (OSTI)

    Mock, Michael T.; Pierpont, Aaron W.; Egbert, Jonathan D.; O'Hagan, Molly J.; Chen, Shentan; Bullock, R. Morris; Dougherty, William G.; Kassel, W. S.; Rousseau, Roger J.

    2015-05-18

    The first example of a mono-dinitrogen Cr0 complex, Cr(N2)(dmpe)(PPh3NBn3), 2(N2), (PPh3NBn3 = 1,5,9-tribenzyl-3,7,11-triphenyl-1,5,9-triaza-3,7,11-triphosphacyclododecane; dmpe = 1,2-bis(dimethylphosphino)ethane) containing a pentaphosphine coordination environment is described. 2(N2) is supported by a unique facially coordinating 12-membered phosphorus macrocycle containing pendant amine groups in the second coordination sphere. Treatment of 2(N2) at -78 C with 1 equiv of [H(OEt2)2][B(C6F5)4] results in protonation of the metal center, generating the 7-coordinate Cr(II)-N2 hydride complex, [Cr(H)(N2)(dmpe)(PPh3NBn3)][B(C6F5)4], [2(H)(N2)]+. Treatment of 2(15N2) with excess triflic acid at -50 C afforded a trace amount of 15NH4+ from the reduction of the coordinated 15N2 ligand (electrons originate from Cr). Augmenting the acid reactivity studies, electronic structure calculations evaluated the pKa values of three sites of 2(N2) (metal center, pendant amine, and N2 ligand) to elucidate possible Cr-NxHy intermediates involved in the N2 reduction pathways from the protonation of 2(N2). This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Computational resources provided by the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  16. Synthesis and characterization of model MgO supported catalyst with Pt-Mo interactions.

    SciTech Connect (OSTI)

    Alexeev, O.; Kawi, S.; Gates, B.C. [Univ. of California, Davis, CA (United States)] [Univ. of California, Davis, CA (United States); Shelef, M. [Ford Motor Co., Dearborn, MI (United States)] [Ford Motor Co., Dearborn, MI (United States)

    1996-01-04

    MgO supported platinum and platinum-molybdenum catalysts were prepared from organometallic precursors and charaterized structurally to determine how the nature of the bimetallic precursors and the treatment conditions affected the interaction between the two metals. Samples were prepared from [PtCl{sub 2}(PhCN){sub 2}], [PtCl{sub 2}(PhCN){sub 2}] + [Mo(CO){sub 6}], and [C@Pt[Mo(CO){sub 3}(C{sub 5}H{sub 5})]{sub 2}(PhCN){sub 2}] BC@ characterized by infrared and extended X-ray absorption fine structure (EXAFS) spectroscopies, tranmission electron microscopy, and chemisorption of H{sub 2}, CO, and O{sub 2}. The samples were treated in H{sub 2} at 400{degree}C prior to most of the characterizatons. Incorporation of Mo reduced the chemisorption of CO and of H{sub 2}. EXAFS spectra measured at the Pt L{sub III} edge and at the Mo K edge showed substantial Pt-Mo contributions with a Pt-Mo cordination number of about 2 and an average distance of 2.63 A for the sample prepared from [C@Pt[Mo(CO){sub 3}(C{sub 5}H{sub 5})]{sub 2}(PhCN){sub 2}] BC@. In constract, no significant Pt-Mo contribution was observed for the sample prepared from [PtCl{sub 2}(PhCN){sub 2}]+ [Mo(CO){sub 6}]. Electron micrographs and EXAFS results show that interaction between Pt and Mo ions in the former sample helped to maintain the platinum in a highly dispersed form, with supported platinum clusters being smaller than about 10 A. 53 refs., 9 figs., 9 tabs.

  17. Measurement of the ratio of the production cross sections times branching fractions of $B_{c}^{\\pm} \\to J/\\psi \\pi^{\\pm}$ and $B^{\\pm} \\to J/\\psi K^{\\pm}$ and $\\mathcal{B}(B_{c}^{\\pm} \\to J/\\psi \\pi^{\\pm}\\pi^{\\pm}\\pi^{\\mp})/\\mathcal{B}(B_{c}^{\\pm} \\to J/\\psi \\pi^{\\pm})$ in pp collisions at $\\sqrt{s} =$ 7 TeV

    SciTech Connect (OSTI)

    Khachatryan, Vardan

    2015-01-13

    The ratio of the production cross sections times branching fractions (σ(B±c)B(B±c→J/ψπ±))/(σ(B±)B(B±→J/ψK±)) is studied in proton-proton collisions at a center of-mass energy of 7 TeV with the CMS detector at the LHC. The kinematic region investigated requires B c ± and B± mesons with transverse momentum p T > 15 GeV and rapidity |y|< 1.6. The data sample corresponds to an integrated luminosity of 5.1 fb-1. The ratio is determined to be [0.48±0.05(stat)± 0.03(syst)±0.05 (τBc)]%. The B c ± → J/ψπ ± π ± π decay is also observed in the same data sample. Using a model-independent method developed to measure the efficiency given the presence of resonant behaviour in the three-pion system, the ratio of the branching fractions B(B±c→J/ψπ±π±π)/B(B±c→J/ψπ±) is measured to be 2.55±0.80(stat)±0.33(syst)+0.04-0.01Bc), consistent with the previous LHCb result.

  18. Geomechanical testing of Bayou Choctaw 102B core for SPR analysis

    SciTech Connect (OSTI)

    Ingraham, Mathew Duffy; Broome, Scott Thomas; Bauer, Stephen J.; Barrow, Perry Carl; Flint, Gregory Mark

    2014-02-01

    A laboratory testing program was developed to examine the short-term mechanical and time-dependent (creep) behavior of salt from the Bayou Choctaw Salt Dome. This report documents the test methodologies, and constitutive properties inferred from tests performed. These are used to extend our understanding of the mechanical behavior of the Bayou Choctaw domal salt and provide a data set for numerical analyses. The resulting information will be used to support numerical analyses of the current state of the Bayou Choctaw Dome as it relates to its crude oil storage function as part of the US Strategic Petroleum Reserve. Core obtained from Drill Hole BC-102B was tested under creep and quasi-static constant mean stress axisymmetric compression, and constant mean stress axisymmetric extension conditions. Creep tests were performed at 100 degrees Fahrenheit, and the axisymmetric tests were performed at ambient temperatures (72-78 degrees Fahrenheit). The testing performed indicates that the dilation criterion is pressure and stress state dependent. It was found that as the mean stress increases, the shear stress required to cause dilation increases. The results for this salt are reasonably consistent with those observed for other domal salts. Also it was observed that tests performed under extensile conditions required consistently lower shear stress to cause dilation for the same mean stress, which is consistent with other domal salts. Young's moduli ranged from 3.95 x 106 to 8.51 x 106 psi with an average of 6.44 x 106 psi, with Poisson's ratios ranging from 0.10 to 0.43 with an average of 0.30. Creep testing indicates that the BC salt is intermediate in creep resistance when compared with other bedded and domal salt steady-state behavior.

  19. Interallelic complementation of mutations in propionic acidemia by microinjection of mutant cDNAs into fibroblasts of affected patients

    SciTech Connect (OSTI)

    Loyer, M.; Leclerc, D.; Gravel, R.A.

    1994-09-01

    Propionic acidemia is a rare autosomal recessive disorder resulting from defects of the {alpha} or {beta} subunit of biotin-dependent propionyl-CoA carboxylase (PCC). Mutations are assigned to defects of the PCCA ({alpha} subunit) or PCCB ({beta} subunit) gene through complementation studies after somatic fusion of patient cell lines. About two-thirds of patients with {beta} subunit defects (complementation group pccBC) show interallelic complementation in cell fusion experiments (subgroups pccB and pccC), monitored by the PCC-dependent metabolisms of {sup 14}C-propionate. Most patient cell lines are heteroallelic for two different mutations, leaving ambiguous the identity of the mutation participating in interallelic complementation. To identify the complementing mutations, we have expressed {beta}-subunit cDNAs containing individual mutations by microinjection of the cDNAs in recipient cells from patients with {beta} subunit defects. Correction of the PCC defect was monitored by autoradiography of {sup 14}C-propionate incorporation. In some experiments, cDNAs were co-injected with a plasmid expressing the E. coli lacZ gene as a positive control for successful injection. Two mutations from the pccB subgroup showed complementation when injected into pccC cells; dupKICK140-143 and Pro228Leu. Similarly, two mutations from the pccC subgroup complemented after injection into pccB cells; {Delta}Ile408 and Arg410Trp. No mutation complemented with mutation of the pccBC group which are classified as non-complementing in cell fusion experiments. The results show that the complementing pccB mutations are found in the N-terminal half of the {beta} subunit, while the complementing pccC mutations cluxter at a site in the C-terminal half. The latter site is a candidate for the propionyl-CoA binding site based on sequence identity with a region of transcarboxylase from Propionibacterium shermanii.

  20. A Voltage Controlled Oscillator for a Phase-Locked Loop Frequency Synthesizer in a Silicon-on-Sapphire Process

    SciTech Connect (OSTI)

    Garrison, Sean

    2009-05-21

    Engineers from a government-owned engineering and manufacturing facility were contracted by government-owned research laboratory to design and build an S-band telemetry transmitter using Radio Frequency Integrated Circuit (RFIC) technology packaged in a Low-Temperature Co-fired Ceramic (LTCC) Multi-Chip Module. The integrated circuit technology chosen for the Phase-Locked Loop Frequency Synthesizer portion of the telemetry transmitter was a 0.25 um CMOS process that utilizes a sapphire substrate and is fabricated by Peregrine Semiconductor corporation. This thesis work details the design of the Voltage Controlled Oscillator (VCO) portion of the PLL frequency synthesizer and constitutes an fully integrated VCO core circuit and a high-isolation buffer amplifier. The high-isolation buffer amplifier was designed to provide 16 dB of gain for 2200-3495 MHz as well as 60 dB of isolation for the oscillator core to provide immunity to frequency pulling due to RF load mismatch. Actual measurements of the amplifier gain and isolation showed the gain was approximately 5 dB lower than the simulated gain when all bond-wire and test substrate parasitics were taken into account. The isolation measurements were shown to be 28 dB at the high end of the frequency band but the measurement was more than likely compromised due to the aforementioned bond-wire and test substrate parasitics. The S-band oscillator discussed in this work was designed to operate over a frequency range of 2200 to 2300 MHz with a minimum output power of 0 dBm with a phase-noise of -92 dBc/Hz at a 100 kHz offset from the carrier. The tuning range was measured to be from 2215 MHz to 2330 MHz with a minimum output power of -7 dBm over the measured frequency range. A phase-noise of -90 dBc was measured at a 100 kHz offset from the carrier.

  1. A new WRF-Chem treatment for studying regional-scale impacts of cloud processes on aerosol and trace gases in parameterized cumuli

    SciTech Connect (OSTI)

    Berg, L. K.; Shrivastava, M.; Easter, R. C.; Fast, J. D.; Chapman, E. G.; Liu, Y.; Ferrare, R. A.

    2015-02-24

    A new treatment of cloud effects on aerosol and trace gases within parameterized shallow and deep convection, and aerosol effects on cloud droplet number, has been implemented in the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) version 3.2.1 that can be used to better understand the aerosol life cycle over regional to synoptic scales. The modifications to the model include treatment of the cloud droplet number mixing ratio; key cloud microphysical and macrophysical parameters (including the updraft fractional area, updraft and downdraft mass fluxes, and entrainment) averaged over the population of shallow clouds, or a single deep convective cloud; and vertical transport, activation/resuspension, aqueous chemistry, and wet removal of aerosol and trace gases in warm clouds. These changes have been implemented in both the WRF-Chem chemistry packages as well as the Kain–Fritsch (KF) cumulus parameterization that has been modified to better represent shallow convective clouds. Testing of the modified WRF-Chem has been completed using observations from the Cumulus Humilis Aerosol Processing Study (CHAPS). The simulation results are used to investigate the impact of cloud–aerosol interactions on regional-scale transport of black carbon (BC), organic aerosol (OA), and sulfate aerosol. Based on the simulations presented here, changes in the column-integrated BC can be as large as –50% when cloud–aerosol interactions are considered (due largely to wet removal), or as large as +40% for sulfate under non-precipitating conditions due to sulfate production in the parameterized clouds. The modifications to WRF-Chem are found to account for changes in the cloud droplet number concentration (CDNC) and changes in the chemical composition of cloud droplet residuals in a way that is consistent with observations collected during CHAPS. Efforts are currently underway to port the changes described here to the latest version of WRF-Chem, and it is

  2. Mutations participating in interallelic complementation in propionic acidemia

    SciTech Connect (OSTI)

    Gravel, R.A.; Akerman, B.R.; Lamhonwah, A.M.; Loyer, M.; Leon-del-Rio, A.; Italiano, I. )

    1994-07-01

    Deficiency of propionyl-CoA carboxylase (PCC; [alpha][sub 4][beta][sub 4]) results in the rare, autosomal recessive disease propionic acidemia. Cell fusion experiments have revealed two complementation groups, pccA and pccB, corresponding to defects of the PCCA ([alpha]-subunit) and PCCB ([beta]-subunit) genes, respectively. The pccBCC group includes subgroups, pccB and pccC, which are thought to reflect interallelic complementation between certain mutations of the PCCB gene. In this study, the authors have identified the mutations in two pccB, one pccC, and two pccBC cell lines and have deduced those alleles participating in interallelic complementation. One pccB line was a compound hetrozygote of Pro228Leu and Asn536Asp. The latter mutation was also detected in a noncomplementing pccBC line. This leaves Pro228Leu responsible for complementation in the pccB cells. The second pccB line contained an insertional duplication, dupKICK140-143, and a splice mutation IVS+1 G[yields]T, located after Lys466. The authors suggest that the dupKICK mutation is the complementing allele, since the second allele is incompatible with normal splicing. The pccC line studied was homozygous for Arg410Trp, which is necessarily the complementing allele in that line. For a second pccC line, they previously had proposed that [Delta]Ile408 was the complementing allele. They now show that its second allele, [open quotes]Ins[center dot]Del[close quotes], a 14-bp deletion replaced by a 12-bp insertion beginning at codon 407, fails to complement in homozygous form. The authors conclude that the interallelic complementation results from mutations in domains that can interact between [beta]-subunits in the PCC heteromer to restore enzymatic function. On the basis of sequence homology with the Propionibacterium shermanii transcarboxylase 12S subunit, they suggest that the pccC domain, defined by Ile408 and Arg410, may involve the propionyl-CoA binding site. 37 refs., 5 figs., 2 tabs.

  3. A new WRF-Chem treatment for studying regional-scale impacts of cloud processes on aerosol and trace gases in parameterized cumuli

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Berg, L. K.; Shrivastava, M.; Easter, R. C.; Fast, J. D.; Chapman, E. G.; Liu, Y.; Ferrare, R. A.

    2015-02-24

    A new treatment of cloud effects on aerosol and trace gases within parameterized shallow and deep convection, and aerosol effects on cloud droplet number, has been implemented in the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) version 3.2.1 that can be used to better understand the aerosol life cycle over regional to synoptic scales. The modifications to the model include treatment of the cloud droplet number mixing ratio; key cloud microphysical and macrophysical parameters (including the updraft fractional area, updraft and downdraft mass fluxes, and entrainment) averaged over the population of shallow clouds, or a single deep convectivemore » cloud; and vertical transport, activation/resuspension, aqueous chemistry, and wet removal of aerosol and trace gases in warm clouds. These changes have been implemented in both the WRF-Chem chemistry packages as well as the Kain–Fritsch (KF) cumulus parameterization that has been modified to better represent shallow convective clouds. Testing of the modified WRF-Chem has been completed using observations from the Cumulus Humilis Aerosol Processing Study (CHAPS). The simulation results are used to investigate the impact of cloud–aerosol interactions on regional-scale transport of black carbon (BC), organic aerosol (OA), and sulfate aerosol. Based on the simulations presented here, changes in the column-integrated BC can be as large as –50% when cloud–aerosol interactions are considered (due largely to wet removal), or as large as +40% for sulfate under non-precipitating conditions due to sulfate production in the parameterized clouds. The modifications to WRF-Chem are found to account for changes in the cloud droplet number concentration (CDNC) and changes in the chemical composition of cloud droplet residuals in a way that is consistent with observations collected during CHAPS. Efforts are currently underway to port the changes described here to the latest version of WRF-Chem, and it

  4. Aerosol climate effects and air quality impacts from 1980 to 2030

    SciTech Connect (OSTI)

    Menon, Surabi; Menon, Surabi; Unger, Nadine; Koch, Dorothy; Francis, Jennifer; Garrett, Tim; Sednev, Igor; Shindell, Drew; Streets, David

    2007-11-26

    We investigate aerosol effects on climate for 1980, 1995 (meant to reflect present-day) and 2030 using the NASA Goddard Institute for Space Studies climate model coupled to an on-line aerosol source and transport model with interactive oxidant and aerosol chemistry. Aerosols simulated include sulfates, organic matter (OM), black carbon (BC), sea-salt and dust and additionally, the amount of tropospheric ozone is calculated, allowing us to estimate both changes to air quality and climate for different time periods and emission amounts. We include both the direct aerosol effect and indirect aerosol effects for liquid-phase clouds. Future changes for the 2030 A1B scenario are examined, focusing on the Arctic and Asia, since changes are pronounced in these regions. Our results for the different time periods include both emission changes and physical climate changes. We find that the aerosol indirect effect (AIE) has a large impact on photochemical processing, decreasing ozone amount and ozone forcing, especially for the future (2030-1995). Ozone forcings increase from 0 to 0.12 Wm{sup -2} and the total aerosol forcing increases from -0.10 Wm{sup -2} to -0.94 Wm{sup -2} (AIE increases from -0.13 to -0.68 Wm{sup -2}) for 1995-1980 versus 2030-1995. Over the Arctic we find that compared to ozone and the direct aerosol effect, the AIE contributes the most to net radiative flux changes. The AIE, calculated for 1995-1980, is positive (1.0 Wm{sup -2}), but the magnitude decreases (-0.3Wm{sup -2}) considerably for the future scenario. Over Asia, we evaluate the role of biofuel and transportation-based emissions (for BC and OM) via a scenario (2030A) that includes a projected increase (factor of two) in biofuel and transport-based emissions for 2030 A1B over Asia. Projected changes from present-day due to the 2030A emissions versus 2030 A1B are a factor of 4 decrease in summertime precipitation in Asia. Our results are sensitive to emissions used. Uncertainty in present

  5. Multiple parton interaction studies at DØ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lincoln, D.

    2016-04-01

    Here, we present the results of studies of multiparton interactions done by the DØ collaboration using the Fermilab Tevatron at a center of mass energy of 1.96 TeV. We also present three analyses, involving three distinct final signatures: (a) a photon with at least 3 jets ( γ + 3jets), (b) a photon with a bottom or charm quark tagged jet and at least 2 other jets ( γ + b/c + 2jets), and (c) two J/ ψ mesons. The fraction of photon + jet events initiated by double parton scattering is about 20%, while the fraction for events inmore » which two J/ ψ mesons were produced is 30 ± 10. While the two measurements are statistically compatible, the difference might indicate differences in the quark and gluon distribution within a nucleon. Finally, this speculation originates from the fact that photon + jet events are created by collisions with quarks in the initial states, while J/ ψ events are produced preferentially by a gluonic initial state.« less

  6. Geologic setting, petrophysical characteristics, and regional heterogeneity patterns of the Smackover in southwest Alabama. Draft topical report on Subtasks 2 and 3

    SciTech Connect (OSTI)

    Kopaska-Merkel, D.C.; Mann, S.D.; Tew, B.H.

    1992-06-01

    This is the draft topical report on Subtasks 2 and 3 of DOE contract number DE-FG22-89BC14425, entitled ``Establishment of an oil and gas database for increased recovery and characterization of oil and gas carbonate reservoir heterogeneity.`` This volume constitutes the final report on Subtask 3, which had as its primary goal the geological modeling of reservoir heterogeneity in Smackover reservoirs of southwest Alabama. This goal was interpreted to include a thorough analysis of Smackover reservoirs, which was required for an understanding of Smackover reservoir heterogeneity. This report is divided into six sections (including this brief introduction). Section two, entitled ``Geologic setting,`` presents a concise summary of Jurassic paleogeography, structural setting, and stratigraphy in southwest Alabama. This section also includes a brief review of sedimentologic characteristics and stratigraphic framework of the Smackover, and a summary of the diagenetic processes that strongly affected Smackover reservoirs in Alabama. Section three, entitled ``Analytical methods,`` summarizes all nonroutine aspects of the analytical procedures used in this project. The major topics are thin-section description, analysis of commercial porosity and permeability data, capillary-pressure analysis, and field characterization. ``Smackover reservoir characteristics`` are described in section four, which begins with a general summary of the petrographic characteristics of porous and permeable Smackover strata. This is followed by a more-detailed petrophysical description of Smackover reservoirs.

  7. Electron localization in a mixed-valence diniobium benzene complex

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gianetti, Thomas L.; Nocton, Grégory; Minasian, Stefan G.; Kaltsoyannis, Nikolas; Kilcoyne, A. L. David; Kozimor, Stosh A.; Shuh, David K.; Tyliszczak, Tolek; Bergman, Robert G.; Arnold, John

    2014-11-11

    Reaction of the neutral diniobium benzene complex {[Nb(BDI)NtBu]2(μ-C6H6)} (BDI = N,N'-diisopropylbenzene-β-diketiminate) with Ag[B(C6F5)4] results in a single electron oxidation to produce a cationic diniobium arene complex, {[Nb(BDI)NtBu]2(μ-C6H6)}{B(C6F5)4}. Investigation of the solid state and solution phase structure using single-crystal X-ray diffraction, cyclic voltammetry, magnetic susceptibility, and multinuclear NMR spectroscopy indicates that the oxidation results in an asymmetric molecule with two chemically inequivalent Nb atoms. Further characterization using density functional theory (DFT) calculations, UV-visible, Nb L3,2-edge X-ray absorption near-edge structure (XANES), and EPR spectroscopies supports assignment of a diniobium complex, in which one Nb atom carries a single unpaired electron that ismore » not largely delocalized on the second Nb atom. During the oxidative transformation, one electron is removed from the δ-bonding HOMO, which causes a destabilization of the molecule and formation of an asymmetric product. Subsequent reactivity studies indicate that the oxidized product allows access to metal-based chemistry with substrates that did not exhibit reactivity with the starting neutral complex.« less

  8. Secrets in the Ancient Goatskins: X-Rays Reveal Archimedes' Oldest Writings

    ScienceCinema (OSTI)

    Bergmann, Uwe [SLAC Linear Accelerator Center, United States

    2010-01-08

    Archimedes of Syracruse (287 - 212 B.C.) is considered one of the most brilliant thinkers of all time. The tenth-century parchment known as the Archimedes Palimpsest is by far the oldest surviving manuscript containing works of Archimedes. it is also the unique source for three of the Greek's treatises: the Stomachion, the Method of Mechanical Theorems, and the Greek version of On Floating Bodies. The privately owned palimpsest is the subject of a integrated campaign of conservation, imaging, and scholarship being undertaken at the Walters Art Museum in Baltimore. Much of the text has been imaged by various optical techniques, but significant gaps in our knowledge of the writing of Archimedes remained. A breakthrough in uncovering the missing Archimedes writings was achieved at the Stanford Synchrotron Radiation Laboratory. Using x-ray fluorescence imaging, writings from faint traces of the partly erased iron gall ink were brought to light. The x-ray image revealed Archimedes writings from some of his most important works covered by twelfth-century biblical texts and twentieth-century gold forgeries. This talk will focus on the fascinating journal of a 1,000 year old parchment from its origin in the Mediterranean city of Constantinople to an x-ray beamline at SLAC.

  9. Final environmental impact statement, Washington Water Power/B.C. Hydro Transmission Interconnection Project

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    Washington Water Power (WWP) proposes to construct and operate an electric transmission line that would connect with the electrical system of the British Columbia Hydro and Power Authority (B.C. Hydro). The project would be composed of a double-circuit, 230-kilovolt (kV) transmission line from WWP`s existing Beacon Substation located northeast of Spokane, Washington to the international border located northwest of Metaline Falls, Washington. The original Presidential permit application and associated proposed route presented in the draft environmental impact statement (DEIS) have been modified to terminate at the Beacon Substation, instead of WWP`s initially proposed termination point at the planned Marshall Substation located southwest of Spokane. A supplemental draft EIS was prepared and submitted for review to not only examine the new proposed 5.6 miles of route, but to also compare the new Proposed Route to the other alternatives previously analyzed in the DEIS. This final EIS (FEIS) assesses the environmental effects of the proposed transmission line through construction, operation, maintenance, and abandonment activities and addresses the impacts associated with the Proposed Action, Eastern Alternative, Western Alternative, Northern Crossover Alternative, Southern Crossover Alternative, and No Action Alternative. The FEIS also contains the comments received and the responses to these comments submitted on the DEIS and Supplemental DEIS.

  10. Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Songchen; Boschen, Jeffery S.; Biswas, Abhranil; Kobayashi, Takeshi; Pruski, Marek; Windus, Theresa L.; Sadow, Aaron D.

    2015-08-17

    An electrophilic, coordinatively unsaturated rhodium complex supported by borate-linked oxazoline, oxazoline-coordinated silylene, and N-heterocyclic carbene donors [{κ³-N,Si,C-PhB(OxMe²)(OxMe²SiHPh)ImMes}Rh(H)CO][HB(C₆F₅)₃] (2, OxMe² = 4,4-dimethyl-2-oxazoline; ImMes = 1-mesitylimidazole) is synthesized from the neutral rhodium silyl {PhB(OxMe²)₂ImMes}RhH(SiH2Ph)CO (1) and B(C6F5)3. The unusual oxazoline-coordinated silylene structure in 2 is proposed to form by rearrangement of an unobserved isomeric cationic rhodium silylene species [{PhB(OxMe²)₂ImMes}RhH(SiHPh)CO][HB(C₆F₅)₃] generated by H abstraction. Complex 2 catalyzes reductions of organic carbonyl compounds with silanes to give hydrosilylation products or deoxygenation products. The pathway to these reactions is primarily influenced by the degree of substitution of the organosilane. Reactions with primary silanes give deoxygenationmore » of esters to ethers, amides to amines, and ketones and aldehydes to hydrocarbons, whereas tertiary silanes react to give 1,2-hydrosilylation of the carbonyl functionality. In contrast, the strong Lewis acid B(C₆F₅)₃ catalyzes the complete deoxygenation of carbonyl compounds to hydrocarbons with PhSiH₃ as the reducing agent.« less

  11. Evidence for an unorthodox firing sequence employed by the Berlin Painter. Deciphering ancient ceramic firing conditions through high-resolution material characterization and replication

    SciTech Connect (OSTI)

    Cianchetta, I.; Trentelman, K.; Maish, J.; Saunders, D.; Foran, B.; Walton, M.; Sciau, Ph.; Wang, T.; Pouyet, E.; Cotte, M.; Meirer, F.; Liu, Y.; Pianetta, P.; Mehta, A.

    2014-12-10

    XANES spectroscopy was used to complement the results previously obtained with Raman spectroscopy by the same group to determine the firing conditions used in the production of a single vessel painted by the Berlin Painter in the 5th century B.C. The vessel, part of the collection of the J. Paul Getty Museum, presents a complicated layered architecture of black and red gloss, with different stratigraphies present on the interior and exterior surfaces. The study of two samples, one each from the interior and exterior surface of the vessel, was performed with the complementary analytical techniques of X-ray nano- and micro-spectroscopy (X-ray fluorescence spectroscopy (XRF) and full-field transmission X-ray micro-spectroscopy (FF-XANES) across the Fe K edge), and supported by a replication study. The replicates, made in a laboratory furnace providing complete control over the firing temperature and oxygen partial pressure, provided a paradigm for the comparison of the mineralogical phases observed in the ancient samples, which led to a deeper understanding of the firing conditions necessary for the production of the Berlin Painter's vessel. Our results confirm the necessity of multiple firings and painting applications to obtain the Berlin Painter's architecture and provide a further example of the multiplicity of techniques and practices employed by the potters of the Kerameikos in ancient Athens.

  12. Evidence for an unorthodox firing sequence employed by the Berlin Painter. Deciphering ancient ceramic firing conditions through high-resolution material characterization and replication

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cianchetta, I.; Trentelman, K.; Maish, J.; Saunders, D.; Foran, B.; Walton, M.; Sciau, Ph.; Wang, T.; Pouyet, E.; Cotte, M.; et al

    2014-12-10

    XANES spectroscopy was used to complement the results previously obtained with Raman spectroscopy by the same group to determine the firing conditions used in the production of a single vessel painted by the Berlin Painter in the 5th century B.C. The vessel, part of the collection of the J. Paul Getty Museum, presents a complicated layered architecture of black and red gloss, with different stratigraphies present on the interior and exterior surfaces. The study of two samples, one each from the interior and exterior surface of the vessel, was performed with the complementary analytical techniques of X-ray nano- and micro-spectroscopymore » (X-ray fluorescence spectroscopy (XRF) and full-field transmission X-ray micro-spectroscopy (FF-XANES) across the Fe K edge), and supported by a replication study. The replicates, made in a laboratory furnace providing complete control over the firing temperature and oxygen partial pressure, provided a paradigm for the comparison of the mineralogical phases observed in the ancient samples, which led to a deeper understanding of the firing conditions necessary for the production of the Berlin Painter's vessel. Our results confirm the necessity of multiple firings and painting applications to obtain the Berlin Painter's architecture and provide a further example of the multiplicity of techniques and practices employed by the potters of the Kerameikos in ancient Athens.« less

  13. The human genome project and novel aspects of cytochrome P450 research

    SciTech Connect (OSTI)

    Ingelman-Sundberg, Magnus . E-mail: maging@ki.se

    2005-09-01

    Currently, 57 active cytochrome P450 (CYP) genes and 58 pseudogenes are known to be present in the human genome. Among the genes discovered by initiatives in the human genome project are CYP2R1, CYP2W1, CYP2S1, CYP2U1 and CYP3A43, the latter apparently encoding a pseudoenzyme. The function, polymorphism and regulation of these genes are still to be discovered to a great extent. The polymorphism of drug metabolizing CYPs is extensive and influences the outcome of drug therapy causing lack of response or adverse drug reactions. The basis for the differences in the global distribution of the polymorphic variants is inactivating gene mutations and subsequent genetic drift. However, polymorphic alleles carrying multiple active gene copies also exist and are suggested in case of CYP2D6 to be caused by positive selection due to development of alkaloid resistance in North East Africa about 10,000-5000 BC. The knowledge about the CYP genes and their polymorphisms is of fundamental importance for effective drug therapy and for drug development as well as for understanding metabolic activation of carcinogens and other xenobiotics. Here, a short review of the current knowledge is given.

  14. Preparations and characterizations of novel graphite-like materials and some high oxidation state fluorine chemistry

    SciTech Connect (OSTI)

    Shen, Ciping

    1992-11-01

    Novel graphite-like materials, BC{sub x} (6>x{ge}3), have been prepared using BCl{sub 3} and C{sub 6}H{sub 6} at 800--1000C, and C{sub x}N (14>x{ge}5) have been synthesized using C{sub 5}H{sub 5}N and Cl{sub 2} at 680C--986C. Bulk and thin film characterization were used to study the structure and bonding in these solids. C{sub 8}K(NH{sub 3}){sub 1.1} was prepared by reacting C{sub 8}K with gaseous NH{sub 3}. The carbon sub-lattice is hexagonal: a = 2.47 {Angstrom}, c = 6.47 {Angstrom}. The smaller a parameter and lower conductivity are attributed to smaller electron transfer from K to the conduction band solvation of K by NH{sub 3}. A simplified liquid phase method for synthesizing Li-graphite intercalation compounds has been developed; synthesis of a lamellar mixed conductor, C{sub x}{sup +}Li{sub 2}N{sup {minus}}, has been attempted. Stability and conductivity of (BN){sub 3}SO{sub 3}F have been studied; it was shown to be metallic with a specific conductivity of 1.5 S{center_dot}cm{sup {minus}1}. Its low conductivity is attributed to the low mobility of holes in BN sheets.

  15. Nucleophilic substitutions of 1-alkenylcyclopropyl esters and 1-alkynylcyclopropyl chlorides catalyzed by palladium (0)

    SciTech Connect (OSTI)

    Stolle, A. |; Ollivier, J.; Salauen, J.

    1992-05-20

    The 1-ethenylcyclopropylsulfonates 2e,f and 2-cyclopropylideneethyl esters 10b,c, readily available from cyclopropanone hemiacetal 1, undergo regioselective Pd(0) catalyzed nucleophilic substitution via the unsymmetric 1,1-dimethylene-{pi}-allyl complex 23. With stabilized anions (enolates of malonic ester, {beta}-dicarbonyl compounds, {beta}-sulfonyl ester, and Schiff bases as well as acetate anion, sulfonamide anion, etc.) the nucleophilic substitution occurs at the terminal vinylic position exclusively, providing cyclopropylideneethyl derivatives as building blocks of high synthetic potential. Competition experiments have disclosed that 1-ethenylcyclopropyl tosylate (2e) and cyclopropylideneethyl acetate (10b) are more reactive than dimethylallyl acetates 19 and 22, respectively. Use of chiral phosphines as ligands in the palladium catalyst can provide optically active methylenecyclopropane derivatives. With phenyl-, methyl-, and even n-butylzinc chloride as nucleophiles, the reaction apparently proceeds with initial transfer of the organic residue to palladium, followed by reductive elimination entailing tertiary substitution on the cyclopropane ring exclusively; the same type of product is obtained with azide and bis(trimethylsilyl)amide. But the site of hydride attack to yield reduction products depends on the hydride source. 1-Alkynylcyclopropyl chlorides 12, 13, and 14 react only with organozinc chlorides (nonstabilized nucleophiles) to provide mixtures of ethenylidenecyclopropanes 65 and alkynylcyclopropanes 66, via the {sigma}-palladium complexes 69 and 70, while chloride 15 undergoes mainly reduction. Other transition metal catalysts (Ni, Mo) also induce substitutions, but with poorer regioselectivity. 81 refs., 9 figs., 3 tabs.

  16. Transportation engine commercialization at Ballard Power Systems

    SciTech Connect (OSTI)

    Otto, N.C.; Howard, P.F.

    1996-12-31

    Ballard is adapting its leading fuel cell technology for transit bus engines in three phases. In the first phase, completed in 1993, Ballard developed and demonstrated a 125 HP fuel cell engine in a 32-foot light duty transit bus. This was the world`s first zero-emission vehicle (ZEV) powered completely by PEM fuel cells. The bus is a reliable, smooth performing vehicle that clearly established the viability of Ballard Fuel Cells for zero-emission transit bus operation. In the second phase, completed in 1995, Ballard refined its fuel cell technology, building a 275 HP fuel cell engine for a 40-foot heavy duty transit bus. The fuel cell engine fits in the existing engine compartment and meets the performance of a combustion powered vehicle, but with no pollution. In the third phase, small fleets of ZEV buses will be tested with Chicago Transit Authority and BC Transit. These test fleets will provide the performance, cost and reliability data necessary for commercial production. Commercial production of Ballard`s environmentally clean engines will begin in the 1998-1999 timeframe.

  17. Battery charger and state of charge indicator. Final report

    SciTech Connect (OSTI)

    Latos, T.S.

    1984-04-15

    The battery charger has a full-wave rectifier in series with a transformer isolated 20 kHz dc-dc converter with high frequency switches which are programmed to actively shape the input ac line current to be a mirror image of the ac line voltage. The power circuit is capable of operating at 2 kW peak and 1 kW average power. The BC/SCI has two major subsystems: (1) the battery charger power electronics with its controls; and (2) a microcomputer subsystem which is used to acquire battery terminal data and exercise the state-of-charge software programs. The state-of-charge definition employed is the energy remaining in the battery when extracted at a 10 kW rate divided by the energy capacity of a fully charged new battery. The battery charger circuit is an isolated boost converter operating at an internal frequency of 20 kHz. The switches selected for the battery charger are the single most important item in determining its efficiency. The combination of voltage and current requirements dictated the use of high power NPN Darlington switching transistors. The power circuit topology developed is a three switch design utilizing a power FET on the center tap of the isolation transformer and the power Darlingtons on each of the two ends. An analog control system is employed to accomplish active input current waveshaping as well as the necessary regulation.

  18. Effects of hydrogen atoms on surface conductivity of diamond film

    SciTech Connect (OSTI)

    Liu, Fengbin Cui, Yan; Qu, Min; Di, Jiejian

    2015-04-15

    To investigate the effects of surface chemisorbed hydrogen atoms and hydrogen atoms in the subsurface region of diamond on surface conductivity, models of hydrogen atoms chemisorbed on diamond with (100) orientation and various concentrations of hydrogen atoms in the subsurface layer of the diamond were built. By using the first-principles method based on density functional theory, the equilibrium geometries and densities of states of the models were studied. The results showed that the surface chemisorbed hydrogen alone could not induce high surface conductivity. In addition, isolated hydrogen atoms in the subsurface layer of the diamond prefer to exist at the bond centre site of the C-C bond. However, such a structure would induce deep localized states, which could not improve the surface conductivity. When the hydrogen concentration increases, the C-H-C-H structure and C-3H{sub bc}-C structure in the subsurface region are more stable than other configurations. The former is not beneficial to the increase of the surface conductivity. However, the latter would induce strong surface states near the Fermi level, which would give rise to high surface conductivity. Thus, a high concentration of subsurface hydrogen atoms in diamond would make significant contributions to surface conductivity.

  19. Distance dependent quenching and gamma-ray spectroscopy in tin-loaded polystyrene scintillators

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feng, Patrick L; Mengesha, Wondwosen; Anstey, Mitchell R.; Cordaro, Joseph Gabriel

    2016-02-01

    In this study, we report the synthesis and inclusion of rationally designed organotin compounds in polystyrene matrices as a route towards plastic scintillators capable of gamma-ray spectroscopy. Tin loading ratios of up to 15% w/w have been incorporated, resulting in photopeak energy resolution values as low as 10.9% for 662 keV gamma-rays. Scintillator constituents were selected based upon a previously reported distance-dependent quenching mechanism. Data obtained using UV-Vis and photoluminescence measurements are consistent with this phenomenon and are correlated with the steric and electronic properties of the respective organotin complexes. We also report fast scintillation decay behavior that is comparablemore » to the quenched scintillators 0.5% trans-stilbene doped bibenzyl and the commercial plastic scintillator BC-422Q-1%. These observations are discussed in the context of practical considerations such as optical transparency, ease-of-preparation/scale-up, and total scintillator cost.« less

  20. Factors affecting the indoor concentrations of carbonaceous aerosols of outdoor origin

    SciTech Connect (OSTI)

    Lunden, Melissa M.; Kirchstetter, Thomas W.; Thatcher, Tracy L.; Hering, Susanne V.; Brown, Nancy J.

    2007-06-25

    A field study was conducted in an unoccupied single story residence in Clovis, California to provide data to address issues important to assess the indoor exposure to particles of outdoor origin. Measurements of black and organic carbonaceous aerosols were performed using a variety of methods, resulting in both near real-time measurements as well as integrated filter based measurements. Comparisons of the different measurement methods show that it is crucial to account for gas phase adsorption artifacts when measuring organic carbon (OC). Measured concentrations affected by the emissions of organic compounds sorbed to indoor surfaces imply a higher degree of infiltration of outdoor organic carbon aerosols into the indoor environment for our unoccupied house. Analysis of the indoor and outdoor data for black carbon (BC) aerosols show that, on average, the indoor concentration of black carbon aerosols behaves in a similar manner to sulfate aerosols. In contrast, organic carbon aerosols are subject to chemical transformations indoors that, for our unoccupied home, resulted in lower indoor OC concentrations than would be expected by physical loss mechanisms alone. These results show that gas to particle partitioning of organic compounds, as well as gas to surface interactions within the residence, are an important process governing the indoor concentration to OC aerosols of outdoor origin.

  1. A laboratory approach for determining the effect of oils and dispersants on mangroves

    SciTech Connect (OSTI)

    Baca, B.J.

    1982-10-01

    An experimental approach was developed and applied to testing the effects of oil and dispersant combinations on the growth of mangrove seedlings (trees of the intertidal tropics). A controlled growth chamber was employed to test the effects of different oils and dispersed oils in an array of dosages applied to different parts of the plants. Preliminary test results are reported for two species of mangroves collected from five localities, including both oiled and unoiled estuaries. Differences occurred between species, substances, dosages, the part of the plant dosed, and the presence of chronic oil pollution at localities from which the stocks were collected. Avicennia germinans (L.) L. (black mangrove) was more sensitive than Rhizophora mangle L. (red mangrove) when exposed to almost all substances tested. Light Arabian crude oil (LA) and light Arabian crude oil dispersed (LAD) were the most toxic substances tested. No. 2 fuel oil (N2) and No. 2 fuel oil dispersed (N2D) were as toxic as LA and LAD, except for an increase (an enhancement effect) in foliage and stem growth in Avicennia at lower dosages. Bunker C oil (BC) was the least toxic of the oils tested, resulting in the reduction of foliage and stem growth only at the highest dosage tested in Avicennia. Bunker C oil dispersed (BCD) failed to show effects in either species at any dosage tested. The leaves of Rhizophora were the most sensitive part of the plant tested.

  2. Design of a synchrotron radiation detector for the test beam lines at the Superconducting Super Collider Laboratory

    SciTech Connect (OSTI)

    Hutton, R.D.

    1994-01-01

    As part of the particle- and momentum-tagging instrumentation required for the test beam lines of the Superconducting Super Collider (SSC), the synchrotron radiation detector (SRD) was designed to provide electron tagging at momentum above 75 GeV. In a parallel effort to the three test beam lines at the SSC, schedule demands required testing and calibration operations to be initiated at Fermilab. Synchrotron radiation detectors also were to be installed in the NM and MW beam lines at Femilab before the test beam lines at the SSC would become operational. The SRD is the last instrument in a series of three used in the SSC test beam fines. It follows a 20-m drift section of beam tube downstream of the last silicon strip detector. A bending dipole just in of the last silicon strip detector produces the synchrotron radiation that is detected in a 50-mm-square cross section NaI crystal. A secondary scintillator made of Bicron BC-400 plastic is used to discriminate whether it is synchrotron radiation or a stray particle that causes the triggering of the NaI crystal`s photo multiplier tube (PMT).

  3. The Crystal Structure of Cobra Venom Factor, a Cofactor for C3- and C5-Convertase CVFBb

    SciTech Connect (OSTI)

    Krishnan, Vengadesan; Ponnuraj, Karthe; Xu, Yuanyuan; Macon, Kevin; Volanakis, John E.; Narayana, Sthanam V.L.

    2009-05-26

    Cobra venom factor (CVF) is a functional analog of human complement component C3b, the active fragment of C3. Similar to C3b, in human and mammalian serum, CVF binds factor B, which is then cleaved by factor D, giving rise to the CVFBb complex that targets the same scissile bond in C3 as the authentic complement convertases C4bC2a and C3bBb. Unlike the latter, CVFBb is a stable complex and an efficient C5 convertase. We solved the crystal structure of CVF, isolated from Naja naja kouthia venom, at 2.6 {angstrom} resolution. The CVF crystal structure, an intermediate between C3b and C3c, lacks the TED domain and has the CUB domain in an identical position to that seen in C3b. The similarly positioned CUB and slightly displaced C345c domains of CVF could play a vital role in the formation of C3 convertases by providing important primary binding sites for factor B.

  4. The molecular structure and conformational characteristics of some specific benzodiazepine receptor ligands: A molecular orbital study of C3-substituted betacarboline derivatives

    SciTech Connect (OSTI)

    Konschin, H.; Tylli, H. ); Gynther, J. ); Rouvinen, J. )

    1989-01-01

    The molecular structures of the benzodiazepine receptor ligands {beta}-carboline-3-carboxylic acid (BCCA), its methyl, ethyl, and propyl esters (BCCM, BCCE, and BCCP, respectively), and 3-CN-{beta}-carboline (BC-3-CN) have been investigated on a minimal basis STO-3G level of accuracy. For BCCM, BCCE, and BCCP semiempirical AM 1 calculations have also been performed. Fully optimized molecular geometries are reported. Comparisons with available experimental structures indicate that minimal basis results may have a useful predictive value. For the mobile ester side chains, a study of chosen points on the conformational surface was made. Both the STO-3G and the AM 1 results give the planar conformers is the most stable structures with small barriers to internal rotation, provided the ester side chain remains extended. The calculated STO-3G rotational barriers are higher than are the corresponding AM 1 barriers. Partial optimization, i.e., of side-chain structure parameters only, seems sufficient to map the conformational characteristics of these compounds. The orientation of the dipole moment vector and its magnitude may have consequences for possible interaction with a receptor. On the basis of the sidechain internal dynamics, the intramolecular flexibility tends to be confined to certain regions of conformational space.

  5. Investigation of Hexavalent Chromium Flux to Groundwater at the 100-C-7:1 Excavation Site

    SciTech Connect (OSTI)

    Truex, Michael J.; Vermeul, Vincent R.; Fritz, Brad G.; Mackley, Rob D.; Horner, Jacob A.; Johnson, Christian D.; Newcomer, Darrell R.

    2012-11-16

    Deep excavation of soil has been conducted at the 100-C-7 and 100-C-7:1 waste sites within the 100-BC Operable Unit at the Department of Energy (DOE) Hanford Site to remove hexavalent chromium (Cr(VI)) contamination with the excavations reaching to near the water table. Soil sampling showed that Cr(VI) contamination was still present at the bottom of the 100-C-7:1 excavation. In addition, Cr(VI) concentrations in a downgradient monitoring well have shown a transient spike of increased Cr(VI) concentration following initiation of excavation. Potentially, the increased Cr(VI) concentrations in the downgradient monitoring well are due to Cr(VI) from the excavation site. However, data were needed to evaluate this possibility and to quantify the overall impact of the 100-C-7:1 excavation site on groundwater. Data collected from a network of aquifer tubes installed across the floor of the 100-C-7:1 excavation and from temporary wells installed at the bottom of the entrance ramp to the excavation were used to evaluate Cr(VI) releases into the aquifer and to estimate local-scale hydraulic properties and groundwater flow velocity.

  6. Piano-stool lutetium amido and imido compounds supported by a constrained bis(oxazoline)cyclopentadienyl ligand

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lampland, Nicole L.; Zhu, Jing; Hovey, Megan; Jana, Barun; Ellern, Arkady; Sadow, Aaron D.

    2015-06-25

    {BoMCptet}Lu(CH2Ph)2 (1; BoMCptet = MeC(OxMe2 2C5Me4; OxMe2 = 4,4-dimethyl-2-oxazoline) was prepared in 95% yield from the reaction of BoMCptetH and Lu(CH2Ph)3THF3. Compound 1 reacts with 1 or 2 equiv of H2NCH2R (R = C6H5, 1-C10H7) to give the corresponding imido complexes [{BoMCptet}LuNCH2R]2 (R = C6H5 (2a), 1-C10H7 (2b)) or amido complexes {BoMCptet}Lu(NHCH2R)2 (R = C6H5 (3a), 1-C10H7 (3b)). When isolated, the imido species are insoluble in nonprotic organic solvents. Crystallographic characterization reveals dimeric [{BoMCptet}LuNCH2(1-C10H7)]2 in the solid state. The reaction of 1 and NH3B(C6F5)3 affords crystallographically characterized {BoMCptet}Lu{NHB(C6F5)2}C6F5. This species is proposed to form via a transient lutetium imido, whichmore » undergoes C6F5 migration to the lutetium center.« less

  7. The Utilization of the Microflora Indignous to and Present in Oil-Bearing Formations to Selectively Plug the more Porous Zones Thereby Increasing Oil Recovery During Waterflooding

    SciTech Connect (OSTI)

    Brown, L.R.; Vadie, A.A.

    1997-04-20

    The objective of this work is to demonstrate the use of indigenous microbes as a method of profile control in waterfloods. It is expected that as the microbial population is induced to increase, that the expanded biomass will selectively block the more permeable zones of the reservoir thereby forcing injection water to flow through the less permeable zones which will result in improved sweep efficiency. This increase in microbial population will be accomplished by injecting a nutrient solution into four injectors. Four other injectors will act as control wells. During Phase 1, two wells will be cored through the zone of interest. The core will be subjected to special core analyses in order to arrive at the optimum nutrient formulation. During Phase 11, nutrient injection will begin, the results monitored, and adjustments to the nutrient composition made, if necessary. Phase 11 also will include the drilling of three wells for postmortem core analysis. Phase III will focus on technology transfer of the results. It should be pointed out that one expected outcome of this new technology will be a prolongation of economical waterflooding operations, i.e. economical oil recovery should continue for much longer periods in the producing wells subjected to this selective plugging technique. Results from work under DOE Contract No. DE-AC22-90BC14665 will be incorporated as appropriate.

  8. The Utilization of the Microflora Indigenous to and Present in Oil-Bearing Formations to Selectively Plug the More Porous Zones Thereby Increasing Oil Recovery During Waterflooding

    SciTech Connect (OSTI)

    Brown, Lewis R.; Vadie, Alex A.

    1996-10-20

    The objective of this work is to demonstrate the use of indigenous microbes as a method of profile control in waterfloods. It is expected that as the microbial population is induced to increase, that the expanded biomass will selectively block the more permeable zones of the reservoir thereby forcing injection water to flow through the less permeable zones which will result in improved sweep efficiency. This increase in microbial population will be accomplished by injecting a nutrient solution into four injectors. Four other injectors will act as control wells. During Phase I, two wells will be cored through the zone of interest. The core will be subjected to special core analyses in order to arrive at the optimum nutrient formulation. During Phase II, nutrient injection will begin, the results monitored, and adjustments to the nutrient composition made, if necessary. Phase II also will include the drilling of three wells for post-mortem core analysis. Phase III will focus on technology transfer of the results. It should be pointed out that one expected outcome of this new technology will be a prolongation of economical waterflooding operations, i.e. economical oil recovery should continue for much longer periods in the producing wells subjected to this selective plugging technique. Results from work under DOE Contract No. DE-AC22-90BC14665 will be incorporated as appropriate.

  9. Ancient Blacksmiths, The Iron Age, Damascus Steels, and Modern Metallurgy

    SciTech Connect (OSTI)

    Sherby, O.D.; Wadsworth, J.

    2000-09-11

    The history of iron and Damascus steels is described through the eyes of ancient blacksmiths. For example, evidence is presented that questions why the Iron Age could not have begun at about the same time as the early Bronze Age (i.e. approximately 7000 B.C.). It is also clear that ancient blacksmiths had enough information from their forging work, together with their observation of color changes during heating and their estimate of hardness by scratch tests, to have determined some key parts of the present-day iron-carbon phase diagram. The blacksmiths' greatest artistic accomplishments were the Damascus and Japanese steel swords. The Damascus sword was famous not only for its exceptional cutting edge and toughness, but also for its beautiful surface markings. Damascus steels are ultrahigh carbon steels (UHCSs) that contain from 1.0 to 2.1%. carbon. The modern metallurgical understanding of UHCSs has revealed that remarkable properties can be obtained in these hypereutectoid steels. The results achieved in UHCSs are attributed to the ability to place the carbon, in excess of the eutectoid composition, to do useful work that enhances the high temperature processing of carbon steels and that improves the low and intermediate temperature mechanical properties.

  10. Single-mode deformation via nanoindentation in dc-Si

    SciTech Connect (OSTI)

    Wong, Sherman; Haberl, Bianca; Williams, James S.; Bradby, Jodie E.

    2015-01-01

    The mixture of the metastable body-centered cubic (bc8) and rhombohedral (r8) phases of silicon that is formed via nanoindentation of diamond cubic (dc) silicon exhibits properties that are of scientifc and technological interest. This letter demonstrates that large regions of this mixed phase can be formed in crystalline Si via nanoindentation without signifcant damage to the surrounding crystal. Cross-sectional transmission electron microscopy is used to show that volumes 6 um wide and up to 650 nm deep can be generated in this way using a spherical tip of 21.5 um diameter. The phase transformed region is characterised using both Raman microspectroscopy and transmission electron microscopy. It is found that uniform loading using large spherical indenters can favor phase transformation as the sole deformation mechanism as long as the maximum load is below a critical level. We suggest that the sluggish nature of the transformation from the dc-Si phase to the metallic (b-Sn) phase normally results in competing deformation mechanisms such as slip and cracking but these can be suppressed by controlled loading conditions.

  11. NON-DESTRUCTIVE THERMAL BARRIER COATING SPALLATION PREDICTION BY A LOADBASED MICRO-INDENTATION TECHNIQUE

    SciTech Connect (OSTI)

    J. M. Tannenbaum; K. Lee; B. S.-J. Kang; M.A. Alvin

    2010-11-18

    Currently, the durability and life cycle of thermal barrier coatings (TBC) applied to gas turbine blades and combustor components are limiting the maximum temperature and subsequent efficiency at which gas turbine engines operate. The development of new materials, coating technologies and evaluation techniques is required if enhanced efficiency is to be achieved. Of the current ceramic coating materials used in gas turbine engines, yttria stabilized zirconia (YSZ) is most prevalent, its low thermal conductivity, high thermal expansion coefficient and outstanding mechanical strength make it ideal for use in TBC systems. However, residual stresses caused by coefficients of thermal expansion mismatches within the TBC system and unstable thermally grown oxides are considered the primary causes for its premature and erratic spallation failure. Through finite element simulations, it is shown that the residual stresses generated within the thermally grown oxide (TGO), bond coat (BC), YSZ and their interfaces create slight variations in indentation unloading surface stiffness response prior to spallation failure. In this research, seven air plasma sprayed and one electron beam physical vapor deposition yttria partially stabilized zirconia TBCs were subjected to isothermal and cyclic loadings at 1100C. The associated coating degradation was evaluated using a non-destructive multiple partial unloading micro-indentation procedure. The results show that the proposed non-destructive micro-indentation evaluation technique can be an effective and specimenindependent TBC failure prediction tool capable of determining the location of initial spallation failure prior to its actual occurrence.

  12. Miscible Applied Simulation Techniques for Energy Recovery

    Energy Science and Technology Software Center (OSTI)

    2005-07-01

    During the use of MASTER at the New Mexico Petroleum Recovery Research Center (PRRC) as research division of New Mexico Institute of Mining and Technology a number of modification have been made to the original MASTER. We have worked at minimizing programming errors and incorporating a foaming option for surfactant solution (aqueous phase) injection altemating with gas (SAG) The original program checks and modifications performed at PRRC were under the direction of Dr. Shih-Hsien Changmore » under previous DOE contracts. The final modifications and completion of the documentation were performed by Dr. Zhengwen Zeng under DOE Contract Number DE-FG26-01BC15364. Drs. Chang and Zeng worked under Dr. Reid B. Grigg in the Gas Flooding Processes and Flow Heterogeneities Section of PRRC. This work is not intended to have any long-term support from the PRRC, but any errors should be reported to the Department of Energy for inclusion in future releases of MASTER. MASTER is an effective reservoir simulator for modeling a number of fluid flow problems and is a straight forward and economical program. We thank the Department of Energy for the original development of this program and the availability for our use.« less

  13. Establish and Operate a Geologic Core and Sample Repository in Midland, Texas

    SciTech Connect (OSTI)

    Tyler, Noel

    2000-08-14

    Shell Oil Company donated its proprietary core and sample repository to the Bureau of Economic Geology, The University of Texas at Austin, in 1994. This collection of geologic materials is composed of 325,000 boxes of rocks and samples housed in a 32,700-ft{sup 2} warehouse in Midland, Texas. The material includes cores from more than 3,000 wells (75,000 boxes) and cuttings from more than 90,000 wells (260,000 boxes). In addition to the warehouse space, the repository consists of layout rooms, a processing room, and office space. The U.S. Department of Energy provided $375,000 under Grant Number DE-FG22-94BC14854 for organizing the collection, staffing the facility, and making the material available to the public for the first 5 years of operation. Shell Oil Company provided an endowment of $1.3 million to cover the cost of operating the facility after the fifth year of operation.

  14. 4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir

    SciTech Connect (OSTI)

    Richard D. Miller; Abdelmoneam E. Raef; Alan P. Byrnes; William E. Harrison

    2007-06-30

    The objective of this research project was to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data in the hopes of observing changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE No.DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansas City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 30 months of seismic monitoring, one baseline and eight monitor surveys clearly detected changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators and observed in production data. Attribute analysis was a very useful tool in enhancing changes in seismic character present, but difficult to interpret on time amplitude slices. Lessons learned from and tools/techniques developed during this project will allow high-resolution seismic imaging to be routinely applied to many CO{sub 2} injection programs in a large percentage of shallow carbonate oil fields in the midcontinent.

  15. Modeling gated neutron images of THD capsules

    SciTech Connect (OSTI)

    Wilson, Douglas Carl; Grim, Gary P; Tregillis, Ian L; Wilke, Mark D; Morgan, George L; Loomis, Eric N; Wilde, Carl H; Oertel, John A; Fatherley, Valerie E; Clark, David D; Schmitt, Mark J; Merrill, Frank E; Wang, Tai - Sen F; Danly, Christopher R; Batha, Steven H; Patel, M; Sepke, S; Hatarik, R; Fittinghoff, D; Bower, D; Marinak, M; Munro, D; Moran, M; Hilko, R; Frank, M; Buckles, R

    2010-01-01

    Time gating a neutron detector 28m from a NIF implosion can produce images at different energies. The brighter image near 14 MeV reflects the size and symmetry of the capsule 'hot spot'. Scattered neutrons, {approx}9.5-13 MeV, reflect the size and symmetry of colder, denser fuel, but with only {approx}1-7% of the neutrons. The gated detector records both the scattered neutron image, and, to a good approximation, an attenuated copy of the primary image left by scintillator decay. By modeling the imaging system the energy band for the scattered neutron image (10-12 MeV) can be chosen, trading off the decayed primary image and the decrease of scattered image brightness with energy. Modeling light decay from EJ399, BC422, BCF99-55, Xylene, DPAC-30, and Liquid A leads to a preference from BCF99-55 for the first NIF detector, but DPAC 30 and Liquid A would be preferred if incorporated into a system. Measurement of the delayed light from the NIF scintillator using implosions at the Omega laser shows BCF99-55 to be a good choice for down-scattered imaging at 28m.

  16. Toxicity of Select Organic Acids to the Slightly Thermophilic Acidophile Acidithiobaccillus Caldus

    SciTech Connect (OSTI)

    John E Aston; William A Apel; Brady D Lee; Brent M Peyton

    2009-02-01

    Acidithiobacillus caldus is a thermophilic acidophile found in commercial biomining, acid mine drainage systems, and natural environments. Previous work has characterized A. caldus as a chemolithotrophic autotroph capable of utilizing reduced sulfur compounds under aerobic conditions. Organic acids are especially toxic to chemolithotrophs in low-pH environments, where they diffuse more readily into the cell and deprotonate within the cytoplasm. In the present study, the toxic effects of oxaloacetate, pyruvate, 2-ketoglutarate, acetate, malate, succinate, and fumarate on A. caldus strain BC13 were examined under batch conditions. All tested organic acids exhibited some inhibitory effect. Oxaloacetate was observed to inhibit growth completely at a concentration of 250 M, whereas other organic acids were completely inhibitory at concentrations of between 1,000 and 5,000 M. In these experiments, the measured concentrations of organic acids decreased with time, indicating uptake or assimilation by the cells. Phospholipid fatty acid analyses indicated an effect of organic acids on the cellular envelope. Notable differences included an increase in cyclic fatty acids in the presence of organic acids, indicating possible instability of the cellular envelope. This was supported by field emission scanning-electron micrographs showing blebbing and sluffing in cells grown in the presence of organic acids.

  17. Emergence of recombinant forms in geographic regions with co-circulating HIV subtypes in the dynamic HIV-1 epidemic

    SciTech Connect (OSTI)

    Zhang, Ming; Letiner, Thomas K; Korber, Bette T; Foley, Brian

    2009-01-01

    We have reexamined the subtype designations of {approx}10,000 subtype A, B, C, G, and AG, BC, BF recombinant sequences, and compared the results of the new analysis with their published designations. Intersubtype recombinants dominate HIV epidemics in three different geographical regions. The circulating recombinant from (CRF) CRF02-AG, common in West Central Africa, appears to result from a recombination event that occurred early in the divergence between subtypes A and G, although additional more recent recombination events may have contributed to the breakpoint pattern in this recombinant lineage as well. The Chinese recombinant epidemic strains CRF07 and CRF08, in contrast, result from recent recombinations between more contemporary strains. Nevertheless, CRF07 and CRF08 contributed to many subsequent recombination events. The BF recombinant epidemics in two HIV-1 epicenters in South America are not independent and BF epidemics in South America have an unusually high fraction of unique recombinant forms (URFs) that have each been found only once and carry distinctive breakpoints. Taken together, these analyses reveal a complex and dynamic picture of the current HIV-1 epidemic, and suggest a means of grouping and tracking relationships between viruses through preservation of shared breakpints.

  18. Anomalous magnetic structure and spin dynamics in magnetoelectric LiFePO4

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Toft-Petersen, Rasmus; Reehuis, Manfred; Jensen, Thomas B. S.; Andersen, Niels H.; Li, Jiying; Le, Manh Duc; Laver, Mark; Niedermayer, Christof; Klemke, Bastian; Lefmann, Kim; et al

    2015-07-06

    We report significant details of the magnetic structure and spin dynamics of LiFePO4 obtained by single-crystal neutron scattering. Our results confirm a previously reported collinear rotation of the spins away from the principal b axis, and they determine that the rotation is toward the a axis. In addition, we find a significant spin-canting component along c. Furthermore, the possible causes of these components are discussed, and their significance for the magnetoelectric effect is analyzed. Inelastic neutron scattering along the three principal directions reveals a highly anisotropic hard plane consistent with earlier susceptibility measurements. While using a spin Hamiltonian, we showmore » that the spin dimensionality is intermediate between XY- and Ising-like, with an easy b axis and a hard c axis. As a result, it is shown that both next-nearest neighbor exchange couplings in the bc plane are in competition with the strongest nearest neighbor coupling.« less

  19. Kootenai River Biological Baseline Status Report : Annual Report, 1996.

    SciTech Connect (OSTI)

    Richards, Diana

    1997-02-01

    The Kootenai River ecosystem in Idaho, Montana and British Columbia (B.C.) Canada has been severely degraded during the past 50 years. This aquatic ecosystem has changed from one that was culturally eutrophic, to one that is oligotrophic due to channelization, diking, impoundment (construction and operation of Libby Dam), and pollution abatement measures in the watershed. As a result of these influences, flow regimes, temperature patterns, and water quality were altered, resulting in changes in primary production and aquatic insect and fish populations. Construction of Libby Dam (creation of Lake Koocanusa) and closure of Cominco`s fertilizer plant resulted in decreased phosphorus load to the Kootenai River to below historical levels. Dissolved orthophosphorus concentrations averaged 0.383 mg/L in 1970 as compared to 0.039 mg/L in 1979. Total phosphorus concentrations followed a similar pattern. Both total phosphorus and soluble reactive phosphorus concentrations remained below 0.05 mg/L from 1976 to 1994, characterizing the river as oligotrophic. Post Libby Dam primary productivity levels in the river represent an ultra-oligotrophic to mesotrophic system. Since the construction and operation of Libby Dam, invertebrate densities immediately downstream from the dam increased, but species diversity decreased. Insect diversity increased with increasing distance from the dam, but overall species diversity was lower than would be expected in a free-flowing river. Fish species composition and abundance has also changed as a result of the changes in the river and its watershed.

  20. Phase transformation as the single-mode mechanical deformation of silicon

    SciTech Connect (OSTI)

    Wong, Sherman; Haberl, Bianca; Williams, James S.; Bradby, Jodie E.

    2015-06-25

    The mixture of the metastable body-centered cubic (bc8) and rhombohedral (r8) phases of silicon that is formed via nanoindentation of diamond cubic (dc) silicon exhibits properties that are of scientifc and technological interest. This letter demonstrates that large regions of this mixed phase can be formed in crystalline Si via nanoindentation without signifcant damage to the surrounding crystal. Cross-sectional transmission electron microscopy is used to show that volumes 6 μm wide and up to 650 nm deep can be generated in this way using a spherical tip of ~21.5 μm diameter. The phase transformed region is characterised using both Raman microspectroscopy and transmission electron microscopy. It is found that uniform loading using large spherical indenters can favor phase transformation as the sole deformation mechanism as long as the maximum load is below a critical level. We suggest that the sluggish nature of the transformation from the dc-Si phase to the metallic (b-Sn) phase normally results in competing deformation mechanisms such as slip and cracking but these can be suppressed by controlled loading conditions.

  1. Phase transformation as the single-mode mechanical deformation of silicon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wong, Sherman; Haberl, Bianca; Williams, James S.; Bradby, Jodie E.

    2015-06-25

    The mixture of the metastable body-centered cubic (bc8) and rhombohedral (r8) phases of silicon that is formed via nanoindentation of diamond cubic (dc) silicon exhibits properties that are of scientifc and technological interest. This letter demonstrates that large regions of this mixed phase can be formed in crystalline Si via nanoindentation without signifcant damage to the surrounding crystal. Cross-sectional transmission electron microscopy is used to show that volumes 6 μm wide and up to 650 nm deep can be generated in this way using a spherical tip of ~21.5 μm diameter. The phase transformed region is characterised using both Ramanmore » microspectroscopy and transmission electron microscopy. It is found that uniform loading using large spherical indenters can favor phase transformation as the sole deformation mechanism as long as the maximum load is below a critical level. We suggest that the sluggish nature of the transformation from the dc-Si phase to the metallic (b-Sn) phase normally results in competing deformation mechanisms such as slip and cracking but these can be suppressed by controlled loading conditions.« less

  2. Archaeological Lead Findings in the Ukraine

    SciTech Connect (OSTI)

    Danevich, F. A.; Kobychev, V. V.; Kropivyansky, B. N.; Mokina, V. M.; Nagorny, S. S.; Nikolaiko, A. S.; Poda, D. V.; Tretyak, V. I.; Kim, S. K.; Kim, H. J.; Kostezh, A. B.; Laubenstein, M.; Nisi, S.; Voronov, S. A.

    2007-03-28

    In June-August 2006 an expedition with the aim to look for low-radioactive archaeological lead at the bottom of the Black Sea, near the Crimean peninsula (Ukraine) was organised by a Korean-Ukrainian collaboration. The first samples with {approx}0.2 tons of total mass were found at a depth of 28 m among the relics of an ancient Greek ship. Their age has been dated to the first century B.C. This lead was used as ballast in the keel of the ship. The element composition of the samples was measured by means of X-ray fluorescence and ICP-MS analyses. The first preliminary limits on the 210Pb contamination of the samples are less than a few hundreds mBq/kg. The measurements were performed using gamma spectroscopy with HPGe-detectors and alpha spectroscopy with commercial {alpha}-detectors. Measurements of 40K, Th/U in the lead samples were undertaken in Kiev and in the underground laboratories of the Laboratori Nazionali del Gran Sasso (LNGS, Italy). If it was found to be radio-clean this lead could be used as high efficiency shield for ultra low-level detectors, and as raw material for growing radio-pure scintillation crystals such as PbMoO4 or PbWO4 for the search for rare processes.

  3. Comparison of environmental and isolate Sulfobacillus genomes reveals diverse carbon, sulfur, nitrogen, and hydrogen metabolisms

    SciTech Connect (OSTI)

    Justice, Nicholas B.; Norman, Anders; Brown, Christopher T.; Singh, Andrea; Thomas, Brian C.; Banfield, Jillian F.

    2014-12-15

    Bacteria of the genus Sulfobacillus are found worldwide as members of microbial communities that accelerate sulfide mineral dissolution in acid mine drainage environments (AMD), acid-rock drainage environments (ARD), as well as in industrial bioleaching operations. Despite their frequent identification in these environments, their role in biogeochemical cycling is poorly understood. Here we report draft genomes of five species of the Sulfobacillus genus (AMDSBA1-5) reconstructed by cultivation-independent sequencing of biofilms sampled from the Richmond Mine (Iron Mountain, CA). Three of these species (AMDSBA2, AMDSBA3, and AMDSBA4) have no cultured representatives while AMDSBA1 is a strain of S. benefaciens, and AMDSBA5 a strain of S. thermosulfidooxidans. We analyzed the diversity of energy conservation and central carbon metabolisms for these genomes and previously published Sulfobacillus genomes. Pathways of sulfur oxidation vary considerably across the genus, including the number and type of subunits of putative heterodisulfide reductase complexes likely involved in sulfur oxidation. The number and type of nickel-iron hydrogenase proteins varied across the genus, as does the presence of different central carbon pathways. Only the AMDSBA3 genome encodes a dissimilatory nitrate reducatase and only the AMDSBA5 and S. thermosulfidooxidans genomes encode assimilatory nitrate reductases. Lastly, within the genus, AMDSBA4 is unusual in that its electron transport chain includes a cytochrome bc type complex, a unique cytochrome c oxidase, and two distinct succinate dehydrogenase complexes. Overall, the results significantly expand our understanding of carbon, sulfur, nitrogen, and hydrogen metabolism within the Sulfobacillus genus.

  4. Evidence for change in climate variability during the late-holocene inferred from a sequence of Lake Michigan dune ridges

    SciTech Connect (OSTI)

    Lichter, J. (Univ. of Minnesota, St. Paul, MN (United States))

    1994-06-01

    The timing of ridge formation at a sequence of northern Lake Michigan foredune ridges was calibrated with the historical lake-level record and with climate records to reconstruct a history of climate-related lake-level variation. Foredune ridges are constructed during receding and low lake levels related to regional drought. Shore recession during high lake levels may promote eolian erosion which modifies the shore-parallel foredune ridges into parabolic dunes. A chronology of ridge formation over the last 2400 years indicates that parabolic dunes developed only during periods of frequent ridge formation and drought. Analysis of ridge formation during the historical record of lake-level variation suggest that this association results from increase variability in regional water balances as opposed to variation in sediment supply. Periods of high variability in regional water balances occurred between 380 BC and AD 20, AD 20, AD 20-300, AD 880-990, AD 1180-1280, and AD 1520-1650.

  5. Wintertime aerosol chemical composition, volatility, and spatial variability in the greater London area

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, L.; Williams, L. R.; Young, D. E.; Allan, J. D.; Coe, H.; Massoli, P.; Fortner, E.; Chhabra, P.; Herndon, S.; Brooks, W. A.; et al

    2016-02-02

    The composition of PM1 (particulate matter with diameter less than 1 µm) in the greater London area was characterized during the Clean Air for London (ClearfLo) project in winter 2012. Two high-resolution time-of-flight aerosol mass spectrometers (HR-ToF-AMS) were deployed at a rural site (Detling, Kent) and an urban site (North Kensington, London). The simultaneous and high-temporal resolution measurements at the two sites provide a unique opportunity to investigate the spatial distribution of PM1. We find that the organic aerosol (OA) concentration is comparable between the rural and urban sites, but the contribution from different sources is distinctly different between the two sites.more » The concentration of solid fuel OA at the urban site is about twice as high as at the rural site, due to elevated domestic heating in the urban area. While the concentrations of oxygenated OA (OOA) are well-correlated between the two sites, the OOA concentration at the rural site is almost twice that of the urban site. At the rural site, more than 70 % of the carbon in OOA is estimated to be non-fossil, which suggests that OOA is likely related to aged biomass burning considering the small amount of biogenic SOA in winter. Thus, it is possible that the biomass burning OA contributes a larger fraction of ambient OA in wintertime than what previous field studies have suggested. A suite of instruments was deployed downstream of a thermal denuder (TD) to investigate the volatility of PM1 species at the rural Detling site. After heating at 250 °C in the TD, 40 % of the residual mass is OA, indicating the presence of non-volatile organics in the aerosol. Although the OA associated with refractory black carbon (rBC; measured by a soot-particle aerosol mass spectrometer) only accounts for < 10 % of the total OA (measured by a HR-ToF-AMS) at 250 °C, the two measurements are well-correlated, suggesting that the non-volatile organics have similar sources or have

  6. STANDARDS CONTROLLING AIR EMISSIONS FOR THE SOIL DESICCATION PILOT TEST

    SciTech Connect (OSTI)

    BENECKE MW

    2010-09-08

    This air emissions document supports implementation of the Treatability Test Plan for Soil Desiccation as outlined in the Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau (DOE/RL-2007-56). Treatability testing supports evaluation of remedial technologies for technetium-99 (Tc-99) contamination in the vadose zone at sites such as the BC Cribs and Trenches. Soil desiccation has been selected as the first technology for testing because it has been recommended as a promising technology in previous Hanford Site technology evaluations and because testing of soil desiccation will provide useful information to enhance evaluation of other technologies, in particular gas-phase remediation technologies. A soil desiccation pilot test (SDPT) will evaluate the desiccation process (e.g., how the targeted interval is dried) and the long-term performance for mitigation of contaminant transport. The SDPT will dry out a moist zone contaminated by Tc-99 and nitrate that has been detected at Well 299-E13-62 (Borehole C5923). This air emissions document applies to the activities to be completed to conduct the SDPT in the 200-BC-1 operable unit located in the 200 East Area of the Hanford Site. Well 299-E13-62 is planned to be used as an injection well. This well is located between and approximately equidistant from cribs 216-B-16, 216-B-17, 216-B-18. and 216-B-19. Nitrogen gas will be pumped at approximately 300 ft{sup 3}/min into the 299-EI3-62 injection well, located approximately 12 m (39 ft) away from extraction well 299-EI3-65. The soil gas extraction rate will be approximately 150 ft{sup 3}/min. The SDPT will be conducted continuously over a period of approximately six months. The purpose of the test is to evaluate soil desiccation as a potential remedy for protecting groundwater. A conceptual depiction is provided in Figure 1. The soil desiccation process will physically dry, or evaporate, some of the water from the moist zone of interest. As such, it is

  7. Final Report: Characterization of Hydrogen Adsorption in Carbon-Based Materials by NMR

    SciTech Connect (OSTI)

    Wu, Yue; Kleinhammes, Alfred

    2011-07-11

    In support of DOE/EERE's Fuel Cell Technologies Program Hydrogen Sorption Center of Excellence (HSCoE), UNC conducted Nuclear Magnetic Resonance (NMR) measurements that contributed spectroscopic information as well as quantitative analysis of adsorption processes. While NMR based Langmuir isotherms produce reliable H2 capacity measurements, the most astute contribution to the center is provided by information on dihydrogen adsorption on the scale of nanometers, including the molecular dynamics of hydrogen in micropores, and the diffusion of dihydrogen between macro and micro pores. A new method to assess the pore width using H2 as probe of the pore geometry was developed and is based on the variation of the observed chemical shift of adsorbed dihydrogen as function of H2 pressure. Adsorbents designed and synthesized by the Center were assessed for their H2 capacity, the binding energy of the adsorption site, their pore structure and their ability to release H2. Feedback to the materials groups was provided to improve the materials properties. To enable in situ NMR measurements as a function of H2 pressure and temperature, a unique, specialized NMR system was designed and built. Pressure can be varied between 10-4 and 107 Pa while the temperature can be controlled between 77K and room temperature. In addition to the 1H investigation of the H2 adsorption process, NMR was implemented to measure the atomic content of substituted elements, e.g. boron in boron substituted graphitic material as well as to determine the local environment and symmetry of these substituted nuclei. The primary findings by UNC are the following: Boron substituted for carbon in graphitic material in the planar BC3 configuration enhances the binding energy for adsorbed hydrogen. Arrested kinetics of H2 was observed below 130K in the same boron substituted carbon samples that combine enhanced binding energy with micropore structure. Hydrogen storage material made from activated PEEK is

  8. Soot Particle Studies - Instrument Inter-Comparison Project Overview

    SciTech Connect (OSTI)

    Cross, E.; Sedlacek, A.; Onasch, T. B.; Ahern, A.; Wrobel, W.; Slowik, J. G.; Olfert, J.; Lack, D. A.; Massoli, P.; Cappa, C. D.; Schwarz, J.; Spackman, J. R.; Fahey, D. W.; Trimborn, A.; Jayne, J. T.; Freedman, A.; Williams, L. R.; Ng, N. L.; Mazzoleni, C.; Dubey, M.; Brem, B.; Kok, G.; Subramanian, R.; Freitag, S.; Clarke, A.; Thornhill, D.; Marr, L.; Kolb, C. E.; Worsnop, D. R.; Davidovits, P.

    2010-03-06

    An inter-comparison study of instruments designed to measure the microphysical and optical properties of soot particles was completed. The following mass-based instruments were tested: Couette Centrifugal Particle Mass Analyzer (CPMA), Time-of-Flight Aerosol Mass Spectrometer - Scanning Mobility Particle Sizer (AMS-SMPS), Single Particle Soot Photometer (SP2), Soot Particle-Aerosol Mass Spectrometer (SP-AMS) and Photoelectric Aerosol Sensor (PAS2000CE). Optical instruments measured absorption (photoacoustic, interferometric, and filter-based), scattering (in situ), and extinction (light attenuation within an optical cavity). The study covered an experimental matrix consisting of 318 runs that systematically tested the performance of instruments across a range of parameters including: fuel equivalence ratio (1.8 {le} {phi} {le} 5), particle shape (mass-mobility exponent (D{sub f m}), 2.0 {le} D{sub f m} {le} 3.0), particle mobility size (30 {le} d{sub m} {le} 300 nm), black carbon mass (0.07 {le} m{sub BC} {le} 4.2 fg) and particle chemical composition. In selected runs, particles were coated with sulfuric acid or dioctyl sebacate (DOS) (0.5 {le} {Delta}r{sub ve} {le} 201 nm) where {Delta}r{sub ve} is the change in the volume equivalent radius due to the coating material. The effect of non-absorbing coatings on instrument response was determined. Changes in the morphology of fractal soot particles were monitored during coating and denuding processes and the effect of particle shape on instrument response was determined. The combination of optical and mass based measurements was used to determine the mass specific absorption coefficient for denuded soot particles. The single scattering albedo of the particles was also measured. An overview of the experiments and sample results are presented.

  9. Estimating costs of low-level radioactive waste disposal alternatives for the Commonwealth of Massachusetts

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    This report was prepared for the Commonwealth of Massachusetts by the Idaho National Engineering Laboratory, National Low-Level Waste Management Program. It presents planning life-cycle cost (PLCC) estimates for four sizes of in-state low-level radioactive waste (LLRW) disposal facilities. These PLCC estimates include preoperational and operational expenditures, all support facilities, materials, labor, closure costs, and long-term institutional care and monitoring costs. It is intended that this report bc used as a broad decision making tool for evaluating one of the several complex factors that must be examined when deciding between various LLRW management options -- relative costs. Because the underlying assumptions of these analyses will change as the Board decides how it will manage Massachusett`s waste and the specific characteristics any disposal facility will have, the results of this study are not absolute and should only be used to compare the relative costs of the options presented. The disposal technology selected for this analysis is aboveground earth-mounded vaults. These vaults are reinforced concrete structures where low-level waste is emplaced and later covered with a multi-layered earthen cap. The ``base case`` PLCC estimate was derived from a preliminary feasibility design developed for the Illinois Low-Level Radioactive Waste Disposal Facility. This PLCC report describes facility operations and details the procedure used to develop the base case PLCC estimate for each facility component and size. Sensitivity analyses were performed on the base case PLCC estimate by varying several factors to determine their influences upon the unit disposal costs. The report presents the results of the sensitivity analyses for the five most significant cost factors.

  10. Spectral Modeling of Residual Stress and Stored Elastic Strain Energy in Thermal Barrier Coatings

    SciTech Connect (OSTI)

    Donegan, Sean; Rolett, Anthony

    2013-12-31

    Solutions to the thermoelastic problem are important for characterizing the response under temperature change of refractory systems. This work extends a spectral fast Fourier transform (FFT) technique to analyze the thermoelastic behavior of thermal barrier coatings (TBCs), with the intent of probing the local origins of failure in TBCs. The thermoelastic FFT (teFFT) approach allows for the characterization of local thermal residual stress and strain fields, which constitute the origins of failure in TBC systems. A technique based on statistical extreme value theory known as peaks-over-threshold (POT) is developed to quantify the extreme values ("hot spots") of stored elastic strain energy (i.e., elastic energy density, or EED). The resolution dependence of the teFFT method is assessed through a sensitivity study of the extreme values in EED. The sensitivity study is performed both for the local (point-by-point) #12;eld distributions as well as the grain scale #12;eld distributions. A convergence behavior to a particular distribution shape is demonstrated for the local #12;elds. The grain scale fields are shown to exhibit a possible convergence to a maximum level of EED. To apply the teFFT method to TBC systems, 3D synthetic microstructures are created to approximate actual TBC microstructures. The morphology of the grains in each constituent layer as well as the texture is controlled. A variety of TBC materials, including industry standard materials and potential future materials, are analyzed using the teFFT. The resulting hot spots are quantified using the POT approach. A correlation between hot spots in EED and interface rumpling between constituent layers is demonstrated, particularly for the interface between the bond coat (BC) and the thermally grown oxide (TGO) layer.

  11. SU-E-QI-12: Morphometry Based Measurements of the Structural Response to Whole Brain Radiation

    SciTech Connect (OSTI)

    Fuentes, D; Castillo, R; Castillo, E; Guerrero, T

    2014-06-15

    Purpose: Although state of the art radiation therapy techniques for treating intracranial malignancies have eliminated acute brain injury, cognitive impairment occurs in 50–90% of patients who survive >6mo post irradiation. Quantitative characterization of therapy response is needed to facilitate therapeutic strategies to minimize radiation induced cognitive impairment [1]. Deformation based morphometry techniques [2, 3] are presented as a quantitative imaging biomarker of therapy response in patients receiving whole brain radiation for treating medulloblastoma. Methods: Post-irradiation magnetic resonance imaging (MRI) data sets were retrospectively analyzed in N=15 patients, >60 MR image datasets. As seen in Fig 1(a), volume changes at multiple time points post-irradiation were quantitatively measured in the cerebrum and ventricles with respect to pre-irradiation MRI. A high resolution image Template, was registered to the pre-irradiation MRI of each patient to create a brain atlas for the cerebrum, cerebellum, and ventricles. Skull stripped images for each patient were registered to the initial pre-treatment scan. Average volume changes in the labeled regions were measured using the determinant of the displacement field Jacobian. Results: Longitudinal measurements, Fig 1(b-c), show a negative correlation p=.06, of the cerebral volume change with the time interval from irradiation. A corresponding positive correlation, p=.01, between ventricular volume change and time interval from irradiation is seen. One sample t-test for correlations were computed using a Spearman method. An average decrease in cerebral volume, p=.08, and increase in ventricular volume, p<.001, was observed. The radiation dose was seen directly proportional to the induced volume changes in the cerebrum, r=−.44, p<.001, Fig 1(d). Conclusion: Results indicate that morphometric monitoring of brain tissue volume changes may potentially be used to quantitatively assess toxicity and response to

  12. Virtual impact: visualizing the potential effects of cosmic impact in human history

    SciTech Connect (OSTI)

    Masse, W Bruce; Janecky, David R; Forte, Maurizio; Barrientos, Gustavo

    2009-01-01

    Current models indicate that catastrophic impacts by asteroids and comets capable of killing more than one quarter of Earth's human population have occurred on average once every million years; smaller impacts, such the 1908 Tunguska impact that leveled more than 2,000 square km of Siberian forest, occur every 200-300 years. Therefore, cosmic impact likely significantly affected hominine evolution and conceivably played a role in Holocene period human culture history. Regrettably, few archaeologists are trained to appreciate the nature and potential effects of cosmic impact. We have developed a conceptual model for an extensible set of educational and research tools based on virtual reality collaborative environments to engage archaeologists and the general public on the topic of the role of cosmic impact in human history. Our initial focus is on two documented asteroid impacts in Argentina during the period of 4000 to 1000 B.C. Campo del Cicio resulted in an energy release of around 2-3 megatons (100-150 times the Hiroshima atomic weapon), and left several craters and a strewn field covering 493 km{sup 2} in northeastern Argentina. Rio Cuarto was likely more than 1000 megatons and may have devastated an area greater than 50,000 km{sup 2} in central Argentina. We are focusing on reconstructions of these events and their potential effects on contemporary hunter and gatherers. Our vinual reality tools also introduce interactive variables (e.g., impactor physical properties, climate, vegetation, topography, and social complexity) to allow researchers and students to better investigate and evaluate the factors that significantly influence cosmic impact effects.

  13. ADVANCED SIMULATION CAPABILITY FOR ENVIRONMENTAL MANAGEMENT- CURRENT STATUS AND PHASE II DEMONSTRATION RESULTS

    SciTech Connect (OSTI)

    Seitz, R.

    2013-02-26

    The U.S. Department of Energy (USDOE) Office of Environmental Management (EM), Office of Soil and Groundwater, is supporting development of the Advanced Simulation Capability for Environmental Management (ASCEM). ASCEM is a state-of-the-art scientific tool and approach for understanding and predicting contaminant fate and transport in natural and engineered systems. The modular and open source high-performance computing tool facilitates integrated approaches to modeling and site characterization that enable robust and standardized assessments of performance and risk for EM cleanup and closure activities. The ASCEM project continues to make significant progress in development of computer software capabilities with an emphasis on integration of capabilities in FY12. Capability development is occurring for both the Platform and Integrated Toolsets and High-Performance Computing (HPC) Multiprocess Simulator. The Platform capabilities provide the user interface and tools for end-to-end model development, starting with definition of the conceptual model, management of data for model input, model calibration and uncertainty analysis, and processing of model output, including visualization. The HPC capabilities target increased functionality of process model representations, toolsets for interaction with Platform, and verification and model confidence testing. The Platform and HPC capabilities are being tested and evaluated for EM applications in a set of demonstrations as part of Site Applications Thrust Area activities. The Phase I demonstration focusing on individual capabilities of the initial toolsets was completed in 2010. The Phase II demonstration completed in 2012 focused on showcasing integrated ASCEM capabilities. For Phase II, the Hanford Site deep vadose zone (BC Cribs) served as an application site for an end-to-end demonstration of capabilities, with emphasis on integration and linkages between the Platform and HPC components. Other demonstrations

  14. Research Extension and Education Programs on Bio-based Energy Technologies and Products

    SciTech Connect (OSTI)

    Jackson, Sam; Harper, David; Womac, Al

    2010-03-02

    The overall objectives of this project were to provide enhanced educational resources for the general public, educational and development opportunities for University faculty in the Southeast region, and enhance research knowledge concerning biomass preprocessing and deconstruction. All of these efforts combine to create a research and education program that enhances the biomass-based industries of the United States. This work was broken into five primary objective areas: • Task A - Technical research in the area of biomass preprocessing, analysis, and evaluation. • Tasks B&C - Technical research in the areas of Fluidized Beds for the Chemical Modification of Lignocellulosic Biomass and Biomass Deconstruction and Evaluation. • Task D - Analyses for the non-scientific community to provides a comprehensive analysis of the current state of biomass supply, demand, technologies, markets and policies; identify a set of feasible alternative paths for biomass industry development and quantify the impacts associated with alternative path. • Task E - Efforts to build research capacity and develop partnerships through faculty fellowships with DOE national labs The research and education programs conducted through this grant have led to three primary results. They include: • A better knowledge base related to and understanding of biomass deconstruction, through both mechanical size reduction and chemical processing • A better source of information related to biomass, bioenergy, and bioproducts for researchers and general public users through the BioWeb system. • Stronger research ties between land-grant universities and DOE National Labs through the faculty fellowship program. In addition to the scientific knowledge and resources developed, funding through this program produced a minimum of eleven (11) scientific publications and contributed to the research behind at least one patent.

  15. Kinetic description of intense nonneutral beam propagation through a periodic solenoidal focusing field based on the nonlinear Vlasov-Maxwell equations

    SciTech Connect (OSTI)

    Davidson, R.C.; Chen, C.

    1997-08-01

    A kinetic description of intense nonneutral beam propagation through a periodic solenoidal focusing field B{sup sol}({rvec x}) is developed. The analysis is carried out for a thin beam with characteristic beam radius r{sub b} {much_lt} S, and directed axial momentum {gamma}{sub b}m{beta}{sub b}c (in the z-direction) large compared with the transverse momentum and axial momentum spread of the beam particles. Making use of the nonlinear Vlasov-Maxwell equations for general distribution function f{sub b}({rvec x},{rvec p},t) and self-consistent electrostatic field consistent with the thin-beam approximation, the kinetic model is used to investigate detailed beam equilibrium properties for a variety of distribution functions. Examples are presented both for the case of a uniform solenoidal focusing field B{sub z}(z) = B{sub 0} = const. and for the case of a periodic solenoidal focusing field B{sub z}(z + S) = B{sub z}(z). The nonlinear Vlasov-Maxwell equations are simplified in the thin-beam approximation, and an alternative Hamiltonian formulation is developed that is particularly well-suited to intense beam propagation in periodic focusing systems. Based on the present analysis, the Vlasov-Maxwell description of intense nonneutral beam propagation through a periodic solenoidal focusing field {rvec B}{sup sol}({rvec x}) is found to be remarkably tractable and rich in physics content. The Vlasov-Maxwell formalism developed here can be extended in a straightforward manner to investigate detailed stability behavior for perturbations about specific choices of beam equilibria.

  16. GALACTIC COSMIC-RAY ENERGY SPECTRA AND COMPOSITION DURING THE 2009-2010 SOLAR MINIMUM PERIOD

    SciTech Connect (OSTI)

    Lave, K. A.; Binns, W. R.; Israel, M. H.; Wiedenbeck, M. E.; Christian, E. R.; De Nolfo, G. A.; Von Rosenvinge, T. T.; Cummings, A. C.; Davis, A. J.; Leske, R. A.; Mewaldt, R. A.; Stone, E. C.

    2013-06-20

    We report new measurements of the elemental energy spectra and composition of galactic cosmic rays during the 2009-2010 solar minimum period using observations from the Cosmic Ray Isotope Spectrometer (CRIS) onboard the Advanced Composition Explorer. This period of time exhibited record-setting cosmic-ray intensities and very low levels of solar activity. Results are given for particles with nuclear charge 5 {<=} Z {<=} 28 in the energy range {approx}50-550 MeV nucleon{sup -1}. Several recent improvements have been made to the earlier CRIS data analysis, and therefore updates of our previous observations for the 1997-1998 solar minimum and 2001-2003 solar maximum are also given here. For most species, the reported intensities changed by less than {approx}7%, and the relative abundances changed by less than {approx}4%. Compared with the 1997-1998 solar minimum relative abundances, the 2009-2010 abundances differ by less than 2{sigma}, with a trend of fewer secondary species observed in the more recent time period. The new 2009-2010 data are also compared with results of a simple ''leaky-box'' galactic transport model combined with a spherically symmetric solar modulation model. We demonstrate that this model is able to give reasonable fits to the energy spectra and the secondary-to-primary ratios B/C and (Sc+Ti+V)/Fe. These results are also shown to be comparable to a GALPROP numerical model that includes the effects of diffusive reacceleration in the interstellar medium.

  17. Geophex Airborne Unmanned Survey System (GAUSS). Topical report, October 1993--September 1996

    SciTech Connect (OSTI)

    1998-12-31

    This document is a Final Technical Report that describes the results of the Geophex Airborne Unmanned Survey System (GAUSS) research project. The objectives were to construct a geophysical data acquisition system that uses a remotely operated unmanned aerial vehicle (UAV) and to evaluate its effectiveness for characterization of hazardous environmental sites. The GAUSS is a data acquisition system that mitigates the potential risk to personnel during geophysical characterization of hazardous or radioactive sites. The fundamental basis of the GAUSS is as follows: (1) an unmanned survey vehicle carries geophysical sensors into a hazardous location, (2) the pilot remains outside the hazardous site and operates the vehicle using radio control, (3) geophysical measurements and their spatial locations are processed by an automated data-acquisition system which displays data on an off-site monitor in real-time, and (4) the pilot uses the display to direct the survey vehicle for complete site coverage. The objective of our Phase I research was to develop a data acquisition and processing (DAP) subsystem and geophysical sensors suitable for UAV deployment. We integrated these two subsystems to produce an automated, hand-held geophysical surveying system. The objective of the Phase II effort was to modify the subsystems and integrate them into an airborne prototype. The completed GAUSS DAP system consists of a UAV platform, a laser tracking and ranging subsystem, a telemetry subsystem, light-weight geophysical sensors, a base-station computer (BC), and custom-written survey control software (SCS). We have utilized off-the-shelf commercial products, where possible, to reduce cost and design time.

  18. Synthesis of superconducting Nb3Sn coatings on Nb substrates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Barzi, E.; Franz, S.; Reginato, F.; Turrioni, D.; Bestetti, M.

    2015-12-01

    In the present work the electrochemical and thermal syntheses of superconductive Nb3Sn films are investigated. The Nb3Sn phase is obtained by electrodeposition of Sn layers and Cu intermediate layers onto Nb substrates followed by high temperature diffusion in inert atmosphere. Electrodeposition was performed from aqueous solutions at current densities in the 20 to 50 mA/cm2 range and at temperatures between 40 and 50°C. Subsequent thermal treatments were realized to obtain the Nb3Sn superconductive phase. Glow discharge optical emission spectrometry (GDOES) demonstrated that after thermal treatment interdiffusion of Nb and Sn occurred across a thickness of about 13 μm. Scanning Electronmore » Microscopy (SEM) allowed accurately measuring the thickness of the Nb3Sn phase, whose average for the various types of film samples was between 5.7 and 8.0 μm. X-ray diffraction (XRD) patterns confirmed the presence of a cubic Nb3Sn phase (A15 structure) having (210) preferred orientation. The maximum obtained Tc was 17.68 K and the Bc20 ranged between 22.5 T and 23.8 T. With the procedure described in the present paper, coating complex shapes cost-effectively becomes possible, which is typical of electrochemical techniques. Furthermore, this approach can be implemented in classical wire processes such as "Jelly Roll" or "Rod in Tube", or directly used for producing superconducting surfaces. In conclusion, the potential of this method for Superconducting Radiofrequency (SRF) structures is also outlined.« less

  19. Comparison of environmental and isolate Sulfobacillus genomes reveals diverse carbon, sulfur, nitrogen, and hydrogen metabolisms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Justice, Nicholas B.; Norman, Anders; Brown, Christopher T.; Singh, Andrea; Thomas, Brian C.; Banfield, Jillian F.

    2014-12-15

    Bacteria of the genus Sulfobacillus are found worldwide as members of microbial communities that accelerate sulfide mineral dissolution in acid mine drainage environments (AMD), acid-rock drainage environments (ARD), as well as in industrial bioleaching operations. Despite their frequent identification in these environments, their role in biogeochemical cycling is poorly understood. Here we report draft genomes of five species of the Sulfobacillus genus (AMDSBA1-5) reconstructed by cultivation-independent sequencing of biofilms sampled from the Richmond Mine (Iron Mountain, CA). Three of these species (AMDSBA2, AMDSBA3, and AMDSBA4) have no cultured representatives while AMDSBA1 is a strain of S. benefaciens, and AMDSBA5 amore » strain of S. thermosulfidooxidans. We analyzed the diversity of energy conservation and central carbon metabolisms for these genomes and previously published Sulfobacillus genomes. Pathways of sulfur oxidation vary considerably across the genus, including the number and type of subunits of putative heterodisulfide reductase complexes likely involved in sulfur oxidation. The number and type of nickel-iron hydrogenase proteins varied across the genus, as does the presence of different central carbon pathways. Only the AMDSBA3 genome encodes a dissimilatory nitrate reducatase and only the AMDSBA5 and S. thermosulfidooxidans genomes encode assimilatory nitrate reductases. Lastly, within the genus, AMDSBA4 is unusual in that its electron transport chain includes a cytochrome bc type complex, a unique cytochrome c oxidase, and two distinct succinate dehydrogenase complexes. Overall, the results significantly expand our understanding of carbon, sulfur, nitrogen, and hydrogen metabolism within the Sulfobacillus genus.« less

  20. STIMULI-RESPONSIVE POLYMERS WITH ENHANCED EFFICIENCY IN RESERVOIR RECOVERY PROCESSES

    SciTech Connect (OSTI)

    Charles McCormick; Roger Hester

    2004-09-30

    This sixth and final progress report for DOE Award Number DE-FC26-01BC15317 describes research during the period March 01, 2004 through August 31, 2004 performed at the University of Southern Mississippi on ''Stimuli Responsive Polymers with Enhanced Efficiency in Reservoir Recovery'' processes. Significantly, terpolymers that are responsive to changes in pH and ionic strength have been synthesized, characterized, and their solution properties have been extensively examined. Terpolymers composed of acrylamide, a carboxylated acrylamido monomer (AMBA), and a quaternary ammonium monomer (AMBATAC) with balanced compositions of the latter two, exhibit increases in aqueous solution viscosity as NaCl concentration is increased. This increase in polymer coil size can be expected upon injection of this type of polymer into oil reservoirs of moderate-to-high salinity, leading to better mobility control. The opposite effect (loss of viscosity) is observed for conventional polymer systems. Additionally polymer mobility characteristics have been conducted for a number of hydrophilic copolymers utilizing an extensional flow apparatus and size exclusion chromatography. This study reveled that oil recovery enhancement through use of polymers in a water flood is due to the polymer's resistance to deformation as it flows through the reservoir. Individual polymers when in aqueous solution form coils. The larger the polymer's coil size, the greater the polymer's resistance to extensional flow and the more effective the polymer is in enhancing oil recovery. Large coil sizes are obtained by increasing the polymer molecular weight and having macromolecular structures that favor greater swelling of the coil by the aqueous solvent conditions (temperature, pH and electrolyte concentration) existing in the reservoir.

  1. SciFri PM: Topics 06: The influence of regional dose sensitivity on salivary loss and recovery in the parotid gland

    SciTech Connect (OSTI)

    Clark, H; Thomas, S; Moiseenko, V; Hovan, A; Wu, J

    2014-08-15

    Purpose: The Quantitative Analyses of Normal Tissue Effects in the Clinic (QUANTEC 2010) survey of radiation dose-volume effects on salivary gland function has called for improved understanding of intragland dose sensitivity and the effectiveness of partial sparing in salivary glands. Regional dose susceptibility of sagittally- and coronally-sub-segmented parotid gland has been studied. Specifically, we examine whether individual consideration of sub-segments leads to improved prediction of xerostomia compared with whole parotid mean dose. Methods: Data from 102 patients treated for head-and-neck cancers at the BC Cancer Agency were used in this study. Whole mouth stimulated saliva was collected before (baseline), three months, and one year after cessation of radiotherapy. Organ volumes were contoured using treatment planning CT images and sub-segmented into regional portions. Both non-parametric (local regression) and parametric (mean dose exponential fitting) methods were employed. A bootstrap technique was used for reliability estimation and cross-comparison. Results: Salivary loss is described well using non-parametric and mean dose models. Parametric fits suggest a significant distinction in dose response between medial-lateral and anterior-posterior aspects of the parotid (p<0.01). Least-squares and least-median squares estimates differ significantly (p<0.00001), indicating fits may be skewed by noise or outliers. Salivary recovery exhibits a weakly arched dose response: the highest recovery is seen at intermediate doses. Conclusions: Salivary function loss is strongly dose dependent. In contrast no useful dose dependence was observed for function recovery. Regional dose dependence was observed, but may have resulted from a bias in dose distributions.

  2. D0 Silicon Upgrade: Redesign of the Low Conductivity Water (LCW) System at D-Zero

    SciTech Connect (OSTI)

    Zaczek, Mariusz; /Fermilab

    1996-10-15

    Due to the relocation of a magnet power supply, the installation of a buss, and an installation of chokes. and their need for cooling water a redesign of the Low Conductivity Water (LCW) system has been undertaken. This new system required the determination of an optimal pipe diameter for the High Bay pipe as well as the determination of the pressure drop and temperature rise in the buss. Based on numerous calculations it has been determined that the High Bay pipe should be 1 1/2 inch (1.90 O.D. x 1.610 I.D-40S steel). While the pressure drop in the buss was calculated to be 7.699 psi. Based on such a low pressure drop, no need for any additional pumps has presented itself. Finally, the temperature rise in the buss has been determined to be about 29.39 F for the Assembly Hall (route No.1). and 13.93 F for the Collision Hall (route No.2). The purpose of this engineering note is to explain the redesign of the low conductivity water system (LCW) at D-Zero. The areas to be covered include the sizing of the High Bay, the pressure drop and temperature rise in the buss. In addition, I will try to determine if any more pumps are needed to support this new system. Originally, the purpose of the LCW was to provide cooling for the EF, CF, SAMUS magnets and the magnet power supply. The water source is composed of two 1 1/2 BC, 20 hp, centrifugal pumps (see Table No.2) which are located in room 604 of the D-Zero Assembly building.

  3. Durability of metals from archaeological objects, metal meteorites, and native metals

    SciTech Connect (OSTI)

    Johnson, A.B. Jr.; Francis, B.

    1980-01-01

    Metal durability is an important consideration in the multi-barrier nuclear waste storage concept. This study summarizes the ancient metals, the environments, and factors which appear to have contributed to metal longevity. Archaeological and radiochemical dating suggest that human use of metals began in the period 6000 to 7000 BC. Gold is clearly the most durable, but many objects fashioned from silver, copper, bronze, iron, lead, and tin have survived for several thousand years. Dry environments, such as tombs, appear to be optimum for metal preservation, but some metals have survived in shipwrecks for over a thousand years. The metal meteorites are Fe-base alloys with 5 to 60 wt% Ni and minor amounts of Co, I, and S. Some meteoritic masses with ages estimated to be 5,000 to 20,000 years have weathered very little, while other masses from the same meteorites are in advanced stages of weathering. Native metals are natural metallic ores. Approximately five million tonnes were mined from native copper deposits in Michigan. Copper masses from the Michigan deposits were transported by the Pleistocene glaciers. Areas on the copper surfaces which appear to represent glacial abrasion show minimal corrosion. Dry cooling tower technology has demonstrated that in pollution-free moist environments, metals fare better at temperatures above than below the dewpoint. Thus, in moderate temperature regimes, elevated temperatures may be useful rather than detrimental for exposures of metal to air. In liquid environments, relatively complex radiolysis reactions can occur, particularly where multiple species are present. A dry environment largely obviates radiolysis effects.

  4. Wintertime aerosol chemical composition, volatility, and spatial variability in the greater London area

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, L.; Williams, L. R.; Young, D. E.; Allan, J. D.; Coe, H.; Massoli, P.; Fortner, E.; Chhabra, P.; Herndon, S.; Brooks, W. A.; et al

    2015-08-28

    The composition of PM1 (particulate matter with diameter less than 1 ?m) in the greater London area was characterized during the Clean Air for London (ClearfLo) project in winter 2012. Two High-Resolution Time-of-Flight Aerosol Mass Spectrometers (HR-ToF-AMS) were deployed at a rural site (Detling, Kent) and an urban site (North Kensington, London). The simultaneous and high-temporal resolution measurements at the two sites provide a unique opportunity to investigate the spatial distribution of PM1. We find that the organic aerosol (OA) concentration is comparable between the rural and urban sites, but the sources of OA are distinctly different. The concentration ofmoresolid fuel OA at the urban site is about twice as high as at the rural site, due to elevated domestic heating in the urban area. While the concentrations of oxygenated OA (OOA) are well-correlated between the two sites, the OOA concentration at the rural site is almost twice that of the urban site. At the rural site, more than 70 % of the carbon in OOA is estimated to be non-fossil, which suggests that OOA is likely related to aged biomass burning considering the small amount of biogenic SOA in winter. Thus, it is possible that the biomass burning OA contributes a larger fraction of ambient OA in wintertime than what previous field studies have suggested. A suite of instruments was deployed downstream of a thermal denuder (TD) to investigate the volatility of PM1 species at the rural Detling site. After heating at 250 C in the TD, 40 % of the residual mass is OA, indicating the presence of non-volatile organics in the aerosol. Although the OA associated with refractory black carbon (rBC, measured by a soot-particle aerosol mass spectrometer) only accounts for less

  5. Atomic structure of defects in GaN:Mg grown with Ga polarity

    SciTech Connect (OSTI)

    Liliental-Weber, Z.; Tomaszewicz, T.; Zakharov, D.; Jasinski, J.; O'Keefe, M.A.; Hautakangas, S.; Laakso, A.; Saarinen, K.

    2003-11-25

    Electron microscope phase images, produced by direct reconstruction of the scattered electron wave from a focal series of high-resolution images, were used to determine the nature of defects formed in GaN:Mg crystals. We studied bulk crystals grown from dilute solutions of atomic nitrogen in liquid gallium at high pressure and thin films grown by the MOCVD method. All the crystals were grown with Ga-polarity. In both types of samples the majority of defects were three dimensional Mg-rich hexagonal pyramids with bases on the (0001) plane and six walls on {l_brace}11{und 2}3{r_brace} planes seen in cross-section as triangulars. Some other defects appear in cross-section as trapezoidal (rectangular) defects as a result of presence of truncated pyramids. Both type of defects have hollow centers. They are decorated by Mg on all six side walls and a base. The GaN which grows inside on the defect walls shows polarity inversion. It is shown that change of polarity starts from the defect tip and propagates to the base, and that the stacking sequence changes from ab in the matrix to bc inside the defect. Exchange of the Ga sublattice with the N sublattice within the defect leads to 0.6 {+-} 0.2{angstrom} displacement between Ga sublattices outside and inside the defects. It is proposed that lateral overgrowth of the cavities formed within the defect takes place to restore matrix polarity on the defect base.

  6. Tracing the 4000 year history of organic thin films: From monolayers on liquids to multilayers on solids

    SciTech Connect (OSTI)

    Greene, J. E.

    2015-03-15

    The recorded history of organic monolayer and multilayer thin films spans approximately 4000 years. Fatty-acid-based monolayers were deposited on water by the ancients for applications ranging from fortune telling in King Hammurabi's time (?1800 BC, Mesopotamia) to stilling choppy waters for sailors and divers as reported by the Roman philosopher Pliny the Elder in ?78 AD, and then much later (1774) by the peripatetic American statesman and natural philosopher Benjamin Franklin, to Japanese floating-ink art (suminagashi) developed ?1000 years ago. The modern science of organic monolayers began in the late-1800s/early-1900s with experiments by Lord Rayleigh and the important development by Agnes Pockels, followed two decades later by Irving Langmuir, of the tools and technology to measure the surface tension of liquids, the surface pressure of organic monolayers deposited on water, interfacial properties, molecular conformation of the organic layers, and phase transitions which occur upon compressing the monolayers. In 1935, Katherine Blodgett published a landmark paper showing that multilayers can be synthesized on solid substrates, with controlled thickness and composition, using an apparatus now known as the Langmuir-Blodgett (L-B) trough. A disadvantage of LB films for some applications is that they form weak physisorbed bonds to the substrate. In 1946, Bigelow, Pickett, and Zisman demonstrated, in another seminal paper, the growth of organic self-assembled monolayers (SAMs) via spontaneous adsorption from solution, rather than from the water/air interface, onto SiO{sub 2} and metal substrates. SAMs are close-packed two-dimensional organic crystals which exhibit strong covalent bonding to the substrate. The first multicomponent adsorbed monolayers and multilayer SAMs were produced in the early 1980s. Langmuir monolayers, L-B multilayers, and self-assembled mono- and multilayers have found an extraordinarily broad range of applications including controlled

  7. Management Plan for Experimental Reintroduction of Sockeye into Skaha Lake; Proposed Implementation, Monitoring, and Evaluation, 2004 Technical Report.

    SciTech Connect (OSTI)

    Wright, Howie; Smith, Howard

    2004-01-01

    Okanagan River sockeye salmon, which spawn near the town of Oliver, B.C., have their farther upstream migration limited by several water control and diversion dams. Stock numbers have been declining for many years and the Okanagan Native Alliance Fisheries Department (ONAFD) has been the principal advocate of a program to restore their numbers and range by reintroducing them into upstream waters where they may once have occurred in substantial numbers Some investigators have warned that without effective intervention Okanagan sockeye are at considerable risk of extinction. Among a host of threats, the quality of water in the single nursery areas in Osoyoos Lake. is deteriorating and a sanctuary such as that afforded in larger lakes higher in the system could be essential. Because the proposed reintroduction upstream has implications for other fish species, (particularly kokanee, the so-called ''landlocked sockeye'' which reside in many Okanagan lakes), the proponents undertook a three-year investigation, with funding from the Bonneville Power Administration and the Confederated Tribes of the Colville Reservation, to identify possible problem areas, and they committed to an interim experimental reintroduction to Skaha Lake where any problems could be worked out before a more ambitious reintroduction, (e.g. to Okanagan Lake) could be formally considered. The three-year investigation was completed in the spring of 2003. It included an assessment of risks from disease or the possible introduction of unwanted exotic species. It also considered the present quality and quantity of sockeye habitat, and opportunities for expanding or improving it. Finally ecological complexity encouraged the development of a life history model to examine interactions of sockeye with other fishes and their food organisms. While some problem areas were exposed in the course of these studies, they appeared to be manageable and the concept of an experimental reintroduction was largely supported

  8. Characterization of the Kootenai River Algae Community and Primary Productivity Before and After Experimental Nutrient Addition, 2004–2007 [Chapter 2, Kootenai River Algal Community Characterization, 2009 KTOI REPORT].

    SciTech Connect (OSTI)

    Holderman, Charlie; Anders, Paul; Shafii, Bahman

    2009-07-01

    The Kootenai River ecosystem (spelled Kootenay in Canada) has experienced numerous ecological changes since the early 1900s. Some of the largest impacts to habitat, biological communities, and ecological function resulted from levee construction along the 120 km of river upstream from Kootenay Lake, completed by the 1950s, and the construction and operation of Libby Dam on the river near Libby Montana, completed in 1972. Levee construction isolated tens of thousands of hectares of historic functioning floodplain habitat from the river channel downstream in Idaho and British Columbia (B.C.) severely reducing natural biological productivity and habitat diversity crucial to large river-floodplain ecosystem function. Libby Dam greatly reduces sediment and nutrient transport to downstream river reaches, and dam operations cause large changes in the timing, duration, and magnitude of river flows. These and other changes have contributed to the ecological collapse of the post-development Kootenai River ecosystem and its native biological communities. In response to large scale loss of nutrients, experimental nutrient addition was initiated in the North Arm of Kootenay Lake in 1992, in the South Arm of Kootenay Lake in 2004, and in the Kootenai River at the Idaho-Montana border during 2005. This report characterizes baseline chlorophyll concentration and accrual (primary productivity) rates and diatom and algal community composition and ecological metrics in the Kootenai River for four years, one (2004) before, and three (2005 through 2007) after nutrient addition. The study area encompassed a 325 km river reach from the upper Kootenay River at Wardner, B.C. (river kilometer (rkm) 445) downstream through Montana and Idaho to Kootenay Lake in B.C. (rkm 120). Sampling reaches included an unimpounded reach furthest upstream and four reaches downstream from Libby Dam affected by impoundment: two in the canyon reach (one with and one without nutrient addition), a braided reach

  9. SILENE Benchmark Critical Experiments for Criticality Accident Alarm Systems

    SciTech Connect (OSTI)

    Miller, Thomas Martin; Reynolds, Kevin H.

    2011-01-01

    In October 2010 a series of benchmark experiments was conducted at the Commissariat a Energie Atomique et aux Energies Alternatives (CEA) Valduc SILENE [1] facility. These experiments were a joint effort between the US Department of Energy (DOE) and the French CEA. The purpose of these experiments was to create three benchmarks for the verification and validation of radiation transport codes and evaluated nuclear data used in the analysis of criticality accident alarm systems (CAASs). This presentation will discuss the geometric configuration of these experiments and the quantities that were measured and will present some preliminary comparisons between the measured data and calculations. This series consisted of three single-pulsed experiments with the SILENE reactor. During the first experiment the reactor was bare (unshielded), but during the second and third experiments it was shielded by lead and polyethylene, respectively. During each experiment several neutron activation foils and thermoluminescent dosimeters (TLDs) were placed around the reactor, and some of these detectors were themselves shielded from the reactor by high-density magnetite and barite concrete, standard concrete, and/or BoroBond. All the concrete was provided by CEA Saclay, and the BoroBond was provided by Y-12 National Security Complex. Figure 1 is a picture of the SILENE reactor cell configured for pulse 1. Also included in these experiments were measurements of the neutron and photon spectra with two BICRON BC-501A liquid scintillators. These two detectors were provided and operated by CEA Valduc. They were set up just outside the SILENE reactor cell with additional lead shielding to prevent the detectors from being saturated. The final detectors involved in the experiments were two different types of CAAS detectors. The Babcock International Group provided three CIDAS CAAS detectors, which measured photon dose and dose rate with a Geiger-Mueller tube. CIDAS detectors are currently in

  10. Partial Spin Ordering and Complex Magnetic Structure in BaYFeO4: A Neutron Diffraction and High Temperature Susceptibility Study

    SciTech Connect (OSTI)

    Thompson, Corey; Greedan, John; Garlea, Vasile O; Flacau, Roxana; Tan, Malinda; Derakhshan, Shahab

    2014-01-01

    The novel iron-based compound, BaYFeO4, crystallizes in the Pnma space group with two distinct Fe3+ sites, that are alternately corner-shared [FeO5]7 square pyramids and [FeO6]9 octahedra, forming into [Fe4O18]24 rings, which propagate as columns along the b-axis. A recent report shows two discernible antiferromagnetic (AFM) transitions at 36 and 48 K in the susceptibility, yet heat capacity measurements reveal no magnetic phase transitions at these temperatures. An upturn in the magnetic susceptibility measurements up to 400 K suggests the presence of shortrange magnetic behavior at higher temperatures. In this Article, variable-temperature neutron powder diffraction and hightemperature magnetic susceptibility measurements were performed to clarify the magnetic behavior. Neutron powder diffraction confirmed that the two magnetic transitions observed at 36 and 48 K are due to long-range magnetic order. Below 48 K, the magnetic structure was determined as a spin-density wave (SDW) with a propagation vector, k = (0, 0, 1/3), and the moments along the b-axis, whereas the structure becomes an incommensurate cycloid [k = (0, 0, 0.35)] below 36 K with the moments within the bc-plane. However, for both cases the ordered moments on Fe3+ are only of the order 3.0 B, smaller than the expected values near 4.5 B, indicating that significant components of the Fe moments remain paramagnetic to the lowest temperature studied, 6 K. Moreover, new high-temperature magnetic susceptibility measurements revealed a peak maximum at 550 K indicative of short-range spin correlations. It is postulated that most of the magnetic entropy is thus removed at high temperatures which could explain the absence of heat capacity anomalies at the long-range ordering temperatures. Published spin dimer calculations, which appear to suggest a k = (0, 0, 0) magnetic structure, and allow for neither low dimensionality nor geometric frustration, are inadequate to explain the observed complex magnetic

  11. FINAL CLOSE-OUT REPORT

    SciTech Connect (OSTI)

    Mark A. Carl

    2004-08-03

    The Interstate Oil and Gas Compact Commission (IOGCC) engaged in numerous projects outlined under the scope of work discussed in the United States Department of Energy (DOE) grant number DE-FG26-01BC15336 awarded to the IOGCC. Numerous projects were completed that were extremely valuable to state oil and gas agencies as a result of work performed utilizing resources provided by the grant. There are numerous areas in which state agencies still need assistance. This additional assistance will need to be addressed under another grant because funding resources have been exhausted under The scope of work objectives for the eight projects covered under this grant is as follows: (1) Improve uniformity within state oil and gas data management efforts. (2) Conduct environmental compliance workshops and related educational projects on natural gas and oil exploration and production. (3) Improve regulatory efficiency through partnering opportunities provided by the Appalachian Illinois Basin Directors. (4) Promote the development and implementation of risk-based environmental regulation at the state level through an expertise-sharing program that brings stakeholders together to develop guidelines and models to meet regulatory challenges. (5) Support the IOGCC's regulatory streamlining efforts, including the identification and elimination of unnecessary duplications of effort between state and federal programs dealing with exploration and production on public lands, and identify the need to enhance and regionalize regulatory coordination and cooperation among the states. (6) Involve states and provinces of Canada that have offshore petroleum exploration and production in a regulatory sharing alliance to identify areas of concern that may be incorporated into standard practices for offshore environmental and regulatory compliance. (7) Coordinate efforts with the U.S. Environmental Protection Agency (EPA) to ensure that adequate information is available to the public regarding

  12. TREATMENT OF PRODUCED WATERS USING A SURFACTANT MODIFIED ZEOLITE/VAPOR PHASE BIOREATOR SYSTEM

    SciTech Connect (OSTI)

    LYNN E. KATZ; KERRY A. KINNEY; R.S. BOWMAN; E.J. SULLIVAN

    2003-10-01

    Co-produced water from the oil and gas industry is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some of them must be treated to remove organic constituents before the water is discharged. An efficient, cost-effective treatment technology is needed to remove these constituents. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. Our previous DOE research work (DE-AC26-99BC15221) demonstrated that SMZ could successfully remove BTEX compounds from the produced water. In addition, SMZ could be regenerated through a simple air sparging process. The primary goal of this project is to develop a robust SMZ/VPB treatment system to efficiently remove the organic constituents from produced water in a cost-effective manner. This report summarizes work of this project from March 2003 through September 2003. We have continued our investigation of SMZ regeneration from our previous DOE project. Ten saturation/stripping cycles have been completed for SMZ columns saturated with BTEX compounds. The results suggest that BTEX sorption capacity is not lost after ten saturation/regeneration cycles. The composition of produced water from a site operated by Crystal Solutions Ltd. in Wyoming has been characterized and was used to identify key semi-volatile components. Isotherms with selected semi-volatile components have been initiated and preliminary results have been obtained. The experimental vapor phase bioreactors for this project have been designed and

  13. Treatment of Produced Water Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System

    SciTech Connect (OSTI)

    Lynn E. Katz; Kerry A. Kinney; Robert S. Bowman; Enid J. Sullivan; Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Craig R. Altare

    2006-01-31

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. Produced waters typically contain a high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component as well as chemicals added during the oil-production process. It has been estimated that a total of 14 billion barrels of produced water were generated in 2002 from onshore operations (Veil, 2004). Although much of this produced water is disposed via reinjection, environmental and cost considerations can make surface discharge of this water a more practical means of disposal. In addition, reinjection is not always a feasible option because of geographic, economic, or regulatory considerations. In these situations, it may be desirable, and often necessary from a regulatory viewpoint, to treat produced water before discharge. It may also be feasible to treat waters that slightly exceed regulatory limits for re-use in arid or drought-prone areas, rather than losing them to reinjection. A previous project conducted under DOE Contract DE-AC26-99BC15221 demonstrated that surfactant modified zeolite (SMZ) represents a potential treatment technology for produced water containing BTEX. Laboratory and field experiments suggest that: (1) sorption of benzene, toluene, ethylbenzene and xylenes (BTEX) to SMZ follows linear isotherms in which sorption increases with increasing solute hydrophobicity; (2) the presence of high salt concentrations substantially increases the capacity of the SMZ for BTEX; (3) competitive sorption among the BTEX compounds is negligible; and, (4) complete recovery of the SMZ sorption capacity for BTEX can be achieved by air sparging the SMZ. This report summarizes research for a follow on project to optimize the regeneration process for multiple sorption/regeneration cycles, and to develop and incorporate a vapor phase bioreactor (VPB) system for treatment of the off-gas generated during

  14. Effects of Cougar Predation and Nutrition on Mule Deer Population Declines in the Intermountain Province of the Columbia Basin, 2001-2002 Annual Report.

    SciTech Connect (OSTI)

    Wielgus, Robert B.; Shipley, Lisa

    2002-07-01

    Construction of the Grand Coulee and Chief Joseph dams has resulted in inundation and loss of 29,125 total habitat units for mule deer and irrigation agriculture in many parts the Intermountain Province (IM) of the Columbia Basin. Mule deer in the Shrub-Steppe are ranked high priority target species for mitigation and management and are declining in most portions of the subbasins of the IM. Reasons for the decline are unknown but believed to be related to habitat changes resulting from dams and irrigation agriculture. White-tailed deer are not ranked as target species and are believed to be increasing throughout the basin because of habitat changes brought about by the dams and irrigation agriculture. Recent research (1997-2000) in the NE IM and adjacent Canadian portions of the Columbia Basin (conducted by this author and funded by the Columbia Basin Fish & Wildlife Compensation Program B.C.), suggest that the increasing white-tailed deer populations (because of dams and irrigation agriculture) are resulting in increased predation by cougars on mule deer (apparent competition or alternate prey hypothesis). The apparent competition hypothesis predicts that as alternate prey (white-tailed deer) densities increase, so do densities of predators, resulting in increased incidental predation on sympatric native prey (mule deer). Apparent competition can result in population declines and even extirpation of native prey in some cases. Such a phenomenon may account for declines of mule deer in the IM and throughout arid and semi-arid West where irrigation agriculture is practiced. We will test the apparent competition hypothesis by conducting a controlled, replicated ''press'' experiment in at least 2 treatment and 2 control areas of the IM subbasins by reducing densities of white-tailed deer and observing any changes in cougar predation on mule deer. Deer densities will be monitored by WADFW personnel using annual aerial surveys and/or other trend indices. Predation rates

  15. Effects of Cougar Predation and Nutrition on Mule Deer Population Declines in the IM Province of the Columbia Basin, Annual Report 2002-2003.

    SciTech Connect (OSTI)

    Wielgus, Robert; Shipley, Lisa; Myers, Woodrow

    2003-09-01

    Construction of the Grand Coulee and Chief Joseph dams has resulted in inundation and loss of 29,125 total habitat units for mule deer and irrigation agriculture in many parts the Intermountain Province (IM) of the Columbia Basin. Mule deer in the Shrub-Steppe are ranked high priority target species for mitigation and management and are declining in most portions of the sub basins of the IM. Reasons for the decline are unknown but believed to be related to habitat changes resulting from dams and irrigation agriculture. White-tailed deer are believed to be increasing throughout the basin because of habitat changes brought about by the dams and irrigation agriculture. Recent research (1997-2000) in the NE IM and adjacent Canadian portions of the Columbia Basin (conducted by this author and funded by the Columbia Basin Fish & Wildlife Compensation Program B.C.), suggest that the increasing white-tailed deer populations (because of dams and irrigation agriculture) are resulting in increased predation by cougars on mule deer (apparent competition or alternate prey hypothesis). The apparent competition hypothesis predicts that as alternate prey (white-tailed deer) densities increase, so do densities of predators, resulting in increased incidental predation on sympatric native prey (mule deer). Apparent competition can result in population declines and even extirpation of native prey in some cases. Such a phenomenon may account for declines of mule deer in the IM and throughout arid and semi-arid West where irrigation agriculture is practiced. We will test the apparent competition hypothesis by conducting a controlled, replicated 'press' experiment in at least 2 treatment and 2 control areas of the IM sub basins by reducing densities of white-tailed deer and observing any changes in cougar predation on mule deer. Deer densities will be monitored by WADFW personnel using annual aerial surveys and/or other trend indices. Predation rates and population growth rates of deer

  16. Wigwam River McNeil Substrate Sampling Program : 1998-2002 Summary Report.

    SciTech Connect (OSTI)

    Tepper, Herb

    2003-01-01

    The Wigwam River is an important fisheries stream in the East Kootenay region of British Columbia that supports healthy populations of both bull trout (Salvelinus confluentus) and Westslope cutthroat trout (Oncorhynchus clarki lewisi). The river has been characterized as the single most important bull trout spawning steam in the Kootenay Region (Baxter and Westover 2000), and thus has been the focus of numerous studies in the last ten years (Cope 1998; Cope and Morris 2001; Cope, Morris and Bisset 2002; Kohn Crippen Consultants Ltd. 1998; Westover 1999a; Westover 1999b; Westover and Conroy 1997). Although bull trout populations in the East Kootenay region remain healthy, bull trout populations in other parts of British Columbia and within their traditional range in northwestern United States have declined. Thus, bull trout were blue listed as vulnerable in British Columbia by the B.C. Conservation Data Centre (Cannings 1993) and remain a species of special concern. Bull trout in the north-western United States, within the Columbia River watershed, were listed as threatened in 1998 under the Endangered Species Act by the U.S. Fish and Wildlife Service. In 1999, the Ministry of Water, Land and Air Protection applied and received funding from the Bonneville Power Administration (BPA) to assess and monitor the status of wild, native stocks of bull trout in tributaries to Lake Koocanusa (Libby Reservoir) and the upper Kootenay River. The purpose of this report is to summarize one of the many studies undertaken to ''Monitor and Protect Bull Trout for Koocanusa Reservoir'' (BPA Project Number 2000-04-00). Three permanent sampling sites were established on the Wigwam River in April 1998. At each site, substrate samples were obtained using a McNeil Core sampler in April of each year from 1998 to 2002. The objectives of this study were to assess the quality of stream-bed substrates used by bull trout for spawning prior to major resource development in the Wigwam watershed

  17. Experimental Component Characterization, Monte-Carlo-Based Image Generation and Source Reconstruction for the Neutron Imaging System of the National Ignition Facility

    SciTech Connect (OSTI)

    Barrera, C A; Moran, M J

    2007-08-21

    The Neutron Imaging System (NIS) is one of seven ignition target diagnostics under development for the National Ignition Facility. The NIS is required to record hot-spot (13-15 MeV) and downscattered (6-10 MeV) images with a resolution of 10 microns and a signal-to-noise ratio (SNR) of 10 at the 20% contour. The NIS is a valuable diagnostic since the downscattered neutrons reveal the spatial distribution of the cold fuel during an ignition attempt, providing important information in the case of a failed implosion. The present study explores the parameter space of several line-of-sight (LOS) configurations that could serve as the basis for the final design. Six commercially available organic scintillators were experimentally characterized for their light emission decay profile and neutron sensitivity. The samples showed a long lived decay component that makes direct recording of a downscattered image impossible. The two best candidates for the NIS detector material are: EJ232 (BC422) plastic fibers or capillaries filled with EJ399B. A Monte Carlo-based end-to-end model of the NIS was developed to study the imaging capabilities of several LOS configurations and verify that the recovered sources meet the design requirements. The model includes accurate neutron source distributions, aperture geometries (square pinhole, triangular wedge, mini-penumbral, annular and penumbral), their point spread functions, and a pixelated scintillator detector. The modeling results show that a useful downscattered image can be obtained by recording the primary peak and the downscattered images, and then subtracting a decayed version of the former from the latter. The difference images need to be deconvolved in order to obtain accurate source distributions. The images are processed using a frequency-space modified-regularization algorithm and low-pass filtering. The resolution and SNR of these sources are quantified by using two surrogate sources. The simulations show that all LOS

  18. Real-Time Active Cosmic Neutron Background Reduction Methods

    SciTech Connect (OSTI)

    Mukhopadhyay, Sanjoy; Maurer, Richard; Wolff, Ronald; Mitchell, Stephen; Guss, Paul

    2013-09-01

    Neutron counting using large arrays of pressurized 3He proportional counters from an aerial system or in a maritime environment suffers from the background counts from the primary cosmic neutrons and secondary neutrons caused by cosmic ray-induced mechanisms like spallation and charge-exchange reaction. This paper reports the work performed at the Remote Sensing Laboratory–Andrews (RSL-A) and results obtained when using two different methods to reduce the cosmic neutron background in real time. Both methods used shielding materials with a high concentration (up to 30% by weight) of neutron-absorbing materials, such as natural boron, to remove the low-energy neutron flux from the cosmic background as the first step of the background reduction process. Our first method was to design, prototype, and test an up-looking plastic scintillator (BC-400, manufactured by Saint Gobain Corporation) to tag the cosmic neutrons and then create a logic pulse of a fixed time duration (~120 μs) to block the data taken by the neutron counter (pressurized 3He tubes running in a proportional counter mode). The second method examined the time correlation between the arrival of two successive neutron signals to the counting array and calculated the excess of variance (Feynman variance Y2F)1 in the neutron count distribution from Poisson distribution. The dilution of this variance from cosmic background values ideally would signal the presence of man-made neutrons.2 The first method has been technically successful in tagging the neutrons in the cosmic-ray flux and preventing them from being counted in the 3He tube array by electronic veto—field measurement work shows the efficiency of the electronic veto counter to be about 87%. The second method has successfully derived an empirical relationship between the percentile non-cosmic component in a neutron flux and the Y2F of the measured neutron count distribution. By using shielding materials alone, approximately 55% of the neutron flux

  19. Piano-stool lutetium amido and imido compounds supported by a constrained bis(oxazoline)cyclopentadienyl ligand

    SciTech Connect (OSTI)

    Lampland, Nicole L.; Zhu, Jing; Hovey, Megan; Jana, Barun; Ellern, Arkady; Sadow, Aaron D.

    2015-06-25

    {BoMCptet}Lu(CH2Ph)2 (1; BoMCptet = MeC(OxMe2 2C5Me4; OxMe2 = 4,4-dimethyl-2-oxazoline) was prepared in 95% yield from the reaction of BoMCptetH and Lu(CH2Ph)3THF3. Compound 1 reacts with 1 or 2 equiv of H2NCH2R (R = C6H5, 1-C10H7) to give the corresponding imido complexes [{BoMCptet}LuNCH2R]2 (R = C6H5 (2a), 1-C10H7 (2b)) or amido complexes {BoMCptet}Lu(NHCH2R)2 (R = C6H5 (3a), 1-C10H7 (3b)). When isolated, the imido species are insoluble in nonprotic organic solvents. Crystallographic characterization reveals dimeric [{BoMCptet}LuNCH2(1-C10H7)]2 in the solid state. The reaction of 1 and NH3B(C6F5)3 affords crystallographically characterized {BoMCptet}Lu{NHB(C6F5)2}C6F5. This species is proposed to form via a transient lutetium imido, which undergoes C6F5 migration to the lutetium center.

  20. ENHANCED OIL RECOVERY WITH DOWNHOLE VIBRATION STIMULATION IN OSAGE COUNTY OKLAHOMA

    SciTech Connect (OSTI)

    Robert Westermark; J. Ford Brett

    2003-11-01

    This Final Report covers the entire project from July 13, 2000 to June 30, 2003. The report summarizes the details of the work done on the project entitled ''Enhanced Oil Recovery with Downhole Vibration Stimulation in Osage County Oklahoma'' under DOE Contract Number DE-FG26-00BC15191. The project was divided into nine separate tasks. This report is written in an effort to document the lessons learned during the completion of each task. Therefore each task will be discussed as the work evolved for that task throughout the duration of the project. Most of the tasks are being worked on simultaneously, but certain tasks were dependent on earlier tasks being completed. During the three years of project activities, twelve quarterly technical reports were submitted for the project. Many individual topic and task specific reports were included as appendices in the quarterly reports. Ten of these reports have been included as appendices to this final report. Two technical papers, which were written and accepted by the Society of Petroleum Engineers, have also been included as appendices. The three primary goals of the project were to build a downhole vibration tool (DHVT) to be installed in seven inch casing, conduct a field test of vibration stimulation in a mature waterflooded field and evaluate the effects of the vibration on both the produced fluid characteristics and injection well performance. The field test results are as follows: In Phase I of the field test the DHVT performed exceeding well, generating strong clean signals on command and as designed. During this phase Lawrence Berkeley National Laboratory had installed downhole geophones and hydrophones to monitor the signal generated by the downhole vibrator. The signals recorded were strong and clear. Phase II was planned to be ninety-day reservoir stimulation field test. This portion of the field tests was abruptly ended after one week of operations, when the DHVT became stuck in the well during a routine

  1. 2010 Dry and 2009 - 2010 Wet Season Branchiopod Survey Report, Site 300

    SciTech Connect (OSTI)

    Dexter, W

    2011-03-14

    Lawrence Livermore National Laboratory (LLNL) requested that Condor Country Consulting, Inc. (CCCI) perform wet season surveys and manage the dry season sampling for listed branchiopods in two ponded locations within the Site 300 Experimental Test Site. Site 300 is located in Alameda and San Joaquin Counties, located between the Cities of Livermore and Tracy. The two pool locations have been identified for possible amphibian enhancement activities in support of the Compensation Plan for impacts tied to the Building 850 soil clean-up project. The Building 850 project design resulted in formal consultation with the U.S. Fish and Wildlife Service (USFWS) as an amendment (File 81420-2009-F-0235) to the site-wide Biological Opinion (BO) (File 1-1-02-F-0062) in the spring of 2009 and requires mitigation for the California tiger salamander (AMCA, Ambystoma californiense) and California red-legged frog (CRLF, Rana draytonii) habitat loss. Both pools contain breeding AMCA, but do not produce metamorphs due to limited hydroperiod. The pool to the southeast (Pool BC-FS-2) is the preferred site for amphibian enhancement activities, and the wetland to northwest (Pool OA-FS-1) is the alternate location for enhancement. However, prior to enhancement, LLNL has been directed by USFWS (BO Conservation Measure 17 iii) to 'conduct USFWS protocol-level branchiopod surveys to determine whether listed brachiopod species are present within the compensation area.' CCCI conducted surveys for listed branchiopods in the 2009-2010 wet season to determine the presence of federally-listed branchiopods at the two pools (previous surveys with negative findings were performed by CCCI in 2001-2002 and 2002-2003 onsite). Surveys were conducted to partially satisfy the survey requirements of the USFWS 'Interim Survey Guidelines to Permittees for Recovery Permits under Section 10(a)(1)(A) of the Endangered Species Act for the Listed Vernal Pool Branchiopods' ('Guidelines, USFWS 1996 and BO Conservation

  2. Binding of flexible and constrained ligands to the Grb2 SH2 domain: structural effects of ligand preorganization

    SciTech Connect (OSTI)

    Clements, John H.; DeLorbe, John E.; Benfield, Aaron P.; Martin, Stephen F.

    2010-10-01

    Structures of the Grb2 SH2 domain complexed with a series of flexible and constrained replacements of the phosphotyrosine residue in tripeptides derived from Ac-pYXN (where X = V, I, E and Q) were compared to determine what, if any, structural differences arise as a result of ligand preorganization. Structures of the Grb2 SH2 domain complexed with a series of pseudopeptides containing flexible (benzyl succinate) and constrained (aryl cyclopropanedicarboxylate) replacements of the phosphotyrosine (pY) residue in tripeptides derived from Ac-pYXN-NH{sub 2} (where X = V, I, E and Q) were elucidated by X-ray crystallography. Complexes of flexible/constrained pairs having the same pY + 1 amino acid were analyzed in order to ascertain what structural differences might be attributed to constraining the phosphotyrosine replacement. In this context, a given structural dissimilarity between complexes was considered to be significant if it was greater than the corresponding difference in complexes coexisting within the same asymmetric unit. The backbone atoms of the domain generally adopt a similar conformation and orientation relative to the ligands in the complexes of each flexible/constrained pair, although there are some significant differences in the relative orientations of several loop regions, most notably in the BC loop that forms part of the binding pocket for the phosphate group in the tyrosine replacements. These variations are greater in the set of complexes of constrained ligands than in the set of complexes of flexible ligands. The constrained ligands make more direct polar contacts to the domain than their flexible counterparts, whereas the more flexible ligand of each pair makes more single-water-mediated contacts to the domain; there was no correlation between the total number of proteinligand contacts and whether the phosphotyrosine replacement of the ligand was preorganized. The observed differences in hydrophobic interactions between the complexes of each

  3. Columbia River Treaty 2014/2024 Review Phase 1 Report

    SciTech Connect (OSTI)

    2010-07-01

    Under the Columbia River Treaty (Treaty or CRT) of 1964, Canada and the United States (U.S.) jointly regulate and manage the Columbia River as it flows from British Columbia into the U.S. The Treaty has provided substantial flood control and power generation benefits to both nations. The Treaty established Canadian and U.S. Entities as implementing agents for each government. British Columbia Hydro and Power Authority (BC Hydro) was designated as the Canadian Entity. The Bonneville Power Administration (BPA) Administrator and the U.S. Army Corps of Engineers (Corps) Division Engineer, Northwestern Division, were designated as the U.S. Entity. The Canadian and U.S. Entities are empowered by their respective governments with broad discretion to implement the existing Columbia River Treaty. They are not, however, authorized to terminate, renegotiate, or otherwise modify the Treaty. In the U.S., authority over international treaties rests with the President, assisted in foreign relations and international negotiations by the Department of State and subject in certain cases to the advice and consent of the U.S. Senate. In Canada, international treaties are within the prerogative of the executive branch of the federal government. Under current policy, treaties are tabled in the House of Commons, and are subject to a waiting period before the executive branch brings the treaty into effect. In the case of the Columbia River Treaty, Canada has assigned certain rights and obligations relating to the Treaty to British Columbia pursuant to the Canada-B.C. Agreement. The Phase 1 report is provided to those respective governmental bodies to support possible independent and/or joint decisions that may be made with respect to the future of the Treaty. The Treaty contains two important provisions that take effect on and after September 16, 2024, that could impact the current power and flood control benefits: 1. Canadian flood control obligations automatically change from a pre

  4. Conceptual Ideas for New Nondestructive UF6 Cylinder Assay Techniques

    SciTech Connect (OSTI)

    Miller, Karen A.

    2012-05-02

    for this application and should be assessed quantitatively. The next set of techniques leverage scintillator detectors that are sensitive to both neutron and gamma radiation. The first is the BC-523A capture-gated organic liquid scintillator. The detector response from several different neutron energies has been characterized and is included in the study. The BC-523A has not yet been tested with UF{sub 6} cylinders, but the application appears to be well suited for this technology. The second detector type is a relatively new inorganic scintillator called CLYC. CLYC provides a complementary detection approach to the HEVA and PNEM systems that could be used to determine uranium enrichment in UF{sub 6} cylinders. In this section, the conceptual idea for an integrated CLYC-HEVA/PNEM system is explored that could yield more precision and robustness against systemic uncertainties than any one of the systems by itself. This is followed by a feasibility study on using alpha-particle-induced reaction gamma-rays as a way to estimate {sup 234}U abundance in UF{sub 6}. Until now, there has been no readily available estimate of the strength of these reaction gamma-rays. Thick target yields of the chief reaction gammas are computed and show that they are too weak for practical safeguards applications. In special circumstances where long count times are permissible, the 1,275 keV F({alpha},x{gamma}) is observable. Its strength could help verify an operator declaration provided other knowledge is available (especially the age). The other F({alpha},x{gamma}) lines are concealed by the dominant uranium line spectrum and associated continuum. Finally, the last section provides several ideas for electromagnetic and acoustic nondestructive evaluation (NDE) techniques. These can be used to measure cylinder wall thickness, which is a source of systematic uncertainty for gamma-ray-based NDA techniques; characterize the UF{sub 6} filling profile inside the cylinder, which is a source of

  5. Study of the production of the sigma b*+- with the CDF detector at the Tevatron

    SciTech Connect (OSTI)

    Calancha Paredes, Constantino; /Madrid, CIEMAT /Madrid U.

    2011-02-01

    The composition of matter is a topic in which the man has been interested throughout History. Since the introduction of the atom by Democritus in the 5th century BC until the establishment of the Standard Model, our successful theory that contains our current knowledge on the matter and their interactions, it has come a long way trying to solve this fundamental question. The efforts of many of the greatest minds to perform crucial experiments and develop theoretical models have helped to get deeper insight into the origin of the matter. Today we know that indivisible atoms postulated by Democritus are no longer true, and they are actually composed of a nucleus made of protons and neutrons (nucleons) with orbiting electrons through electromagnetic interactions. Also the nucleons are not fundamental particles but are composed of more fundamental ones called quarks. According to the present state of our knowledge, matter is composed of two types of particles: quarks and leptons. Leptons are believed to be fundamental particles and can occur freely in nature. Quarks are also fundamental particles, and there are no free in nature, but are confined to form hadrons. The hadrons may consist of a quark and an antiquark (mesons) or three quarks or three antiquarks (baryons). These quarks and leptons interact through the exchange of particles called bosons. Figure 1.1 summary the elementary particles in the Standard Model. Despite its enormous success we know that the Standard Model is incomplete. Some of the issues left unresolved by the Standard Model are the mechanism for electroweak symmetry breaking, the mass spectrum of the Standard Model or that the Universe is much more matter than antimatter. That means that it should exist a more general theory which include the Standard Model as a valid approximation for low energy. This more general theory must give answers to the previous unresolved questions. Accumulate more experimental information is crucial to get a deeper

  6. MEASUREMENT OF COMPRESSIONAL-WAVE SEISMIC VELOCITIES IN 29 WELLS AT THE HANFORD SITE

    SciTech Connect (OSTI)

    PETERSON SW

    2010-10-08

    Check shot seismic velocity surveys were collected in 100 B/C, 200 East, 200-PO-1 Operational Unit (OU), and the Gable Gap areas in order to provide time-depth correlation information to aid the interpretation of existing seismic reflection data acquired at the Hanford Site (Figure 1). This report details results from 5 wells surveyed in fiscal year (FY) 2008, 7 wells in FY 2009, and 17 wells in FY 2010 and provides summary compressional-wave seismic velocity information to help guide future seismic survey design as well as improve current interpretations of the seismic data (SSC 1979/1980; SGW-39675; SGW-43746). Augmenting the check shot database are four surveys acquired in 2007 in support of the Bechtel National, Inc. Waste Treatment Plant construction design (PNNL-16559, PNNL-16652), and check shot surveys in three wells to support seismic testing in the 200 West Area (Waddell et al., 1999). Additional sonic logging was conducted during the late 1970s and early 1980s as part of the Basalt Waste Isolation Program (BWIP) (SSC 1979/1980) and check shot/sonic surveys as part of the safety report for the Skagit/Hanford Nuclear project (RDH/10-AMCP-0164). Check shot surveys are used to obtain an in situ measure of compressional-wave seismic velocity for sediment and rock in the vicinity of the well point, and provide the seismic-wave travel time to geologic horizons of interest. The check shot method deploys a downhole seismic receiver (geophone) to record the arrival of seismic waves generated by a source at the ground surface. The travel time of the first arriving seismic-wave is determined and used to create a time-depth function to correlate encountered geologic intervals with the seismic data. This critical tie with the underlying geology improves the interpretation of seismic reflection profile information. Fieldwork for this investigation was conducted by in house staff during the weeks of September 22, 2008 for 5 wells in the 200 East Area (Figure 2); June 1

  7. SPECT Imaging for in vivo tracking of NIS containing stem cells

    SciTech Connect (OSTI)

    Lee, Zhenghong

    2013-04-02

    The proposed study contains two groups of imaging experiments: 1) human mesenchymal stem cells supporting in vivo survival of unrelated donor hematopoietic stem cells; 2) gene transduction and selection of mutant MGMT genes on human hematopoietic stem cells conferring resistance to BC+BCNU. There is increasing evidence that adult human tissues harbor stem and progenitor cells that can be used for therapeutic purposes. We had focused on the Mesenchymal Stem Cells (MSCs) found in human bone marrow and investigated these cells in the context of autologous and allogeneic hematopoietic stem cell transplantation to a) facilitate rapid hematopoietic engraftment in cancer patients receiving high dose chemotherapy and b) to modulate the graft-versus-host disease (GVHD). We have demonstrated that culture-expanded autologous and allogeneic MSCs can be safely infused into humans and the preliminary results showed that MSCs facilitate hematopoietic engraftment and reduce GVHD. On the other hand, studies of gene transfer with drug resistant selection suggest major perturbations to the process of hematopoietic reconstitution and the confounding issue of organ toxicity and recovery that takes place in the host. We have found that limiting numbers of hematopoietic stem cells transduced with MGMT repopulate the bone marrow of primary and secondary recipient mice. We are also particularly interested in the dynamics of engraftment and selection in regions of bones, liver, spleen and lung, where we have previously seen marked evidence of engraftment. All the measurements have required animal sacrifice and single point determinations of engraftment in individual and cohorts of mice. Heretofore it has not been possible to study the dynamics of engraftment and enrichment. In the upcoming application, we propose to develop an imaging method to track intravenously infused stem cells in vivo at preset time points to understand their homing and proliferation. Specifically, we propose to use

  8. INCREASING OIL RECOVERY THROUGH ADVANCED REPROCESSING OF 3D SEISMIC, GRANT CANYON AND BACON FLAT FIELDS, NYE COUNTY, NEVADA

    SciTech Connect (OSTI)

    Eric H. Johnson; Don E. French

    2001-06-01

    Makoil, Inc., of Orange, California, with the support of the U.S. Department of Energy has reprocessed and reinterpreted the 3D seismic survey of the Grant Canyon area, Railroad Valley, Nye County, Nevada. The project was supported by Dept. of Energy Grant DE-FG26-00BC15257. The Grant Canyon survey covers an area of 11 square miles, and includes Grant Canyon and Bacon Flat oil fields. These fields have produced over 20 million barrels of oil since 1981, from debris slides of Devonian rocks that are beneath 3,500 to 5,000 ft of Tertiary syntectonic deposits that fill the basin of Railroad Valley. High-angle and low-angle normal faults complicate the trap geometry of the fields, and there is great variability in the acoustic characteristics of the overlying valley fill. These factors combine to create an area that is challenging to interpret from seismic reflection data. A 3D seismic survey acquired in 1992-93 by the operator of the fields has been used to identify development and wildcat locations with mixed success. Makoil believed that improved techniques of processing seismic data and additional well control could enhance the interpretation enough to improve the chances of success in the survey area. The project involved the acquisition of hardware and software for survey interpretation, survey reprocessing, and reinterpretation of the survey. SeisX, published by Paradigm Geophysical Ltd., was chosen as the interpretation software, and it was installed on a Dell Precision 610 computer work station with the Windows NT operating system. The hardware and software were selected based on cost, possible addition of compatible modeling software in the future, and the experience of consulting geophysicists in the Billings area. Installation of the software and integration of the hardware into the local office network was difficult at times but was accomplished with some technical support from Paradigm and Hewlett Packard, manufacturer of some of the network equipment. A

  9. Advanced Simulation Capability for Environmental Management (ASCEM) Phase II Demonstration

    SciTech Connect (OSTI)

    Freshley, M.; Hubbard, S.; Flach, G.; Freedman, V.; Agarwal, D.; Andre, B.; Bott, Y.; Chen, X.; Davis, J.; Faybishenko, B.; Gorton, I.; Murray, C.; Moulton, D.; Meyer, J.; Rockhold, M.; Shoshani, A.; Steefel, C.; Wainwright, H.; Waichler, S.

    2012-09-28

    quality assurance. The Platform and HPC capabilities are being tested and evaluated for EM applications through a suite of demonstrations being conducted by the Site Applications Thrust. In 2010, the Phase I Demonstration focused on testing initial ASCEM capabilities. The Phase II Demonstration, completed in September 2012, focused on showcasing integrated ASCEM capabilities. For Phase II, the Hanford Site Deep Vadose Zone (BC Cribs) served as an application site for an end-to-end demonstration of ASCEM capabilities on a site with relatively sparse data, with emphasis on integration and linkages between the Platform and HPC components. Other demonstrations included in this Phase II report included addressing attenuation-based remedies at the Savannah River Site F-Area, to exercise linked ASCEM components under data-dense and complex geochemical conditions, and conducting detailed simulations of a representative waste tank. This report includes descriptive examples developed by the Hanford Site Deep Vadose Zone, the SRS F-Area Attenuation-Based Remedies for the Subsurface, and the Waste Tank Performance Assessment working groups. The integrated Phase II Demonstration provides test cases to accompany distribution of the initial user release (Version 1.0) of the ASCEM software tools to a limited set of users in 2013. These test cases will be expanded with each new release, leading up to the release of a version that is qualified for regulatory applications in the 2015 time frame.

  10. Coalbed Methane Procduced Water Treatment Using Gas Hydrate Formation at the Wellhead

    SciTech Connect (OSTI)

    BC Technologies

    2009-12-30

    Water associated with coalbed methane (CBM) production is a significant and costly process waste stream, and economic treatment and/or disposal of this water is often the key to successful and profitable CBM development. In the past decade, advances have been made in the treatment of CBM produced water. However, produced water generally must be transported in some fashion to a centralized treatment and/or disposal facility. The cost of transporting this water, whether through the development of a water distribution system or by truck, is often greater than the cost of treatment or disposal. To address this economic issue, BC Technologies (BCT), in collaboration with Oak Ridge National Laboratory (ORNL) and International Petroleum Environmental Consortium (IPEC), proposed developing a mechanical unit that could be used to treat CBM produced water by forming gas hydrates at the wellhead. This process involves creating a gas hydrate, washing it and then disassociating hydrate into water and gas molecules. The application of this technology results in three process streams: purified water, brine, and gas. The purified water can be discharged or reused for a variety of beneficial purposes and the smaller brine can be disposed of using conventional strategies. The overall objectives of this research are to develop a new treatment method for produced water where it could be purified directly at the wellhead, to determine the effectiveness of hydrate formation for the treatment of produced water with proof of concept laboratory experiments, to design a prototype-scale injector and test it in the laboratory under realistic wellhead conditions, and to demonstrate the technology under field conditions. By treating the water on-site, producers could substantially reduce their surface handling costs and economically remove impurities to a quality that would support beneficial use. Batch bench-scale experiments of the hydrate formation process and research conducted at ORNL

  11. Long Term Field Development of a Surfactant Modified Zeolite/Vapor Phase Bioreactor System for Treatment of Produced Waters for Power Generation

    SciTech Connect (OSTI)

    Lynn Katz; Kerry Kinney; Robert Bowman; Enid Sullivan; Soondong Kwon; Elaine Darby; Li-Jung Chen; Craig Altare

    2007-12-31

    The main goal of this research was to investigate the feasibility of using a combined physicochemical/biological treatment system to remove the organic constituents present in saline produced water. In order to meet this objective, a physical/chemical adsorption process was developed and two separate biological treatment techniques were investigated. Two previous research projects focused on the development of the surfactant modified zeolite adsorption process (DE-AC26-99BC15221) and development of a vapor phase biofilter (VPB) to treat the regeneration off-gas from the surfactant modified zeolite (SMZ) adsorption system (DE-FC26-02NT15461). In this research, the SMZ/VPB was modified to more effectively attenuate peak loads and to maintain stable biodegradation of the BTEX constituents from the produced water. Specifically, a load equalization system was incorporated into the regeneration flow stream. In addition, a membrane bioreactor (MBR) system was tested for its ability to simultaneously remove the aromatic hydrocarbon and carboxylate components from produced water. The specific objectives related to these efforts included the following: (1) Optimize the performance VPBs treating the transient loading expected during SMZ regeneration: (a) Evaluate the impact of biofilter operating parameters on process performance under stable operating conditions. (b) Investigate how transient loads affect biofilter performance, and identify an appropriate technology to improve biological treatment performance during the transient regeneration period of an SMZ adsorption system. (c) Examine the merits of a load equalization technology to attenuate peak VOC loads prior to a VPB system. (d) Evaluate the capability of an SMZ/VPB to remove BTEX from produced water in a field trial. (2) Investigate the feasibility of MBR treatment of produced water: (a) Evaluate the biodegradation of carboxylates and BTEX constituents from synthetic produced water in a laboratory-scale MBR. (b

  12. Vadose Zone Transport Field Study: Summary Report

    SciTech Connect (OSTI)

    Ward, Andy L.; Conrad, Mark E.; Daily, William D.; Fink, James B.; Freedman, Vicky L.; Gee, Glendon W.; Hoversten, Gary M.; Keller, Jason M.; Majer, Ernest L.; Murray, Christopher J.; White, Mark D.; Yabusaki, Steven B.; Zhang, Z. F.

    2006-07-31

    (e.g. BC Cribs and Trenches). The improved models have been also coupled with inverse models and newly-developed parameter scaling techniques to allow estimation of field-scale and effective transport parameters for the vadose zone. The development and utility of pedotransfer functions for describing fine-scale hydrogeochemical heterogeneity and for incorporating this heterogeneity into reactive transport models was explored. An approach based on grain-size statistics appears feasible and has been used to describe heterogeneity in hydraulic properties and sorption properties, such as the cation exchange capacity and the specific surface area of Hanford sediments. This work has also led to the development of inverse modeling capabilities for time-dependent, subsurface, reactive transport with transient flow fields using an automated optimization algorithm. In addition, a number of geophysical techniques investigated for their potential to provide detailed information on the subtle changes in lithology and bedding surfaces; plume delineation, leak detection. High-resolution resistivity is now being used for detecting saline plumes at several waste sites at Hanford, including tank farms. Results from the field studies and associated analysis have appeared in more than 46 publications generated over the past 4 years. These publications include test plans and status reports, in addition to numerous technical notes and peer reviewed papers.

  13. Molybdenum Hydride and Dihydride Complexes Bearing Diphosphine Ligands with a Pendant Amine: Formation of Complexes With Bound Amines

    SciTech Connect (OSTI)

    Zhang, Shaoguang; Bullock, R. Morris

    2015-07-06

    CpMo(CO)(PNP)H complexes (PNP = (R2PCH2)2NMe, R = Et or Ph) were synthesized by displacement of two CO ligands of CpMo(CO)3H by the PNP ligand; these complexes were characterized by IR and variable temperature 1H and 31P NMR spectroscopy. CpMo(CO)(PNP)H complexes are formed as mixture of cis and trans-isomers. Both cis-CpMo(CO)(PEtNMePEt)H and trans-CpMo(CO)(PPhNMePPh)H were analyzed by single crystal X-ray diffraction. Electrochemical oxidation of CpMo(CO)(PEtNMePEt)H and CpMo(CO)(PPhNMePPh)H in CH3CN are both irreversible at slow scan rates and quasi-reversible at higher scan rates, with E1/2 = -0.36 V (vs. Cp2Fe+/0) for CpMo(CO)(PEtNMePEt)H and E1/2 = -0.18 V for CpMo(CO)(PPhNMePPh)H. Hydride abstraction from CpMo(CO)(PNP)H with [Ph3C]+[A]- (A = B(C6F5)4 or BArF4; [ArF = 3,5-bis(trifluoromethyl)phenyl]) afforded “tuck-in” [CpMo(CO)(κ3-PNP)]+ complexes that feature the amine bound to the metal. Displacement of the κ3 Mo-N bond by CD3CN gives [CpMo(CO)(PNP)(CD3CN)]+. The kinetics of this reaction were studied by NMR spectroscopy, providing the activation parameters ΔH‡ = 22.1 kcal/mol, ΔS‡ = 1.89 cal/(mol·K), Ea = 22.7 kcal/mol. Protonation of CpMo(CO)(PEtNMePEt)H affords [CpMo(CO)(κ2-PEtNMePEt)(H)2]+ as a Mo dihydride complex, which loses H2 to generate [CpMo(CO)(κ3-PEtNMePEt)]+ at room temperature. CpMo(CO)(dppp)H (dppp = 1,2-bis(diphenylphosphino)propane) was studied as a Mo diphosphine analogue without a pendant amine, and the product of protonation of this complex gives [CpMo(CO)(dppp)(H)2]+. Our results show that the pendant amine has a strong driving force to form stable “tuck-in” [CpMo(CO)(κ3-PNP)]+ complexes, and also promotes hydrogen elimination from [CpMo(CO)(PNP)(H)2]+ complexes by formation of Mo-N dative bond. We thank the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences for support. Pacific Northwest National Laboratory is operated by

  14. 3-D RESERVOIR AND STOCHASTIC FRACTURE NETWORK MODELING FOR ENHANCED OIL RECOVERY, CIRCLE RIDGE PHOSPHORIA/TENSLEEP RESERVOIR, WIND RIVER RESERVATION, ARAPAHO AND SHOSHONE TRIBES, WYOMING

    SciTech Connect (OSTI)

    Paul La Pointe; Jan Hermanson; Robert Parney; Thorsten Eiben; Mike Dunleavy; Ken Steele; John Whitney; Darrell Eubanks; Roger Straub

    2002-11-18

    This report describes the results made in fulfillment of contract DE-FG26-00BC15190, ''3-D Reservoir and Stochastic Fracture Network Modeling for Enhanced Oil Recovery, Circle Ridge Phosphoria/Tensleep Reservoir, Wind River Reservation, Arapaho and Shoshone Tribes, Wyoming''. The goal of this project is to improve the recovery of oil from the Tensleep and Phosphoria Formations in Circle Ridge Oilfield, located on the Wind River Reservation in Wyoming, through an innovative integration of matrix characterization, structural reconstruction, and the characterization of the fracturing in the reservoir through the use of discrete fracture network models. Fields in which natural fractures dominate reservoir permeability, such as the Circle Ridge Field, often experience sub-optimal recovery when recovery processes are designed and implemented that do not take advantage of the fracture systems. For example, a conventional waterflood in a main structural block of the Field was implemented and later suspended due to unattractive results. It is estimated that somewhere less than 20% of the OOIP in the Circle Ridge Field have been recovered after more than 50 years' production. Marathon Oil Company identified the Circle Ridge Field as an attractive candidate for several advanced IOR processes that explicitly take advantage of the natural fracture system. These processes require knowledge of the distribution of matrix porosity, permeability and oil saturations; and understanding of where fracturing is likely to be well-developed or poorly developed; how the fracturing may compartmentalize the reservoir; and how smaller, relatively untested subthrust fault blocks may be connected to the main overthrust block. For this reason, the project focused on improving knowledge of the matrix properties, the fault block architecture and to develop a model that could be used to predict fracture intensity, orientation and fluid flow/connectivity properties. Knowledge of matrix properties was

  15. Remote Automatic Material On-Line Sensor

    SciTech Connect (OSTI)

    Magnuson, Erik

    2005-12-20

    moisture ranging from 2% to over 140% (referenced to the wood's dry weight). Accuracy exceeded that offered by existing instrumentation when the moisture content was in excess of the fiber saturation point ({approx}20%). Accuracy was independent of the wood form: solid wood, wood chips or sawdust. The prototype NMR system was designed and built for incorporation and use in a beta test site. Beta testing is under way at the pilot plant operated by the Pulp and Paper Research Institute of Canada (PAPRICAN) in Vancouver, B.C. Other industries were also investigated. For example, laboratory testing demonstrated that low-field NMR is capable of measuring the hydrogen content of calcium oxide (quicklime). Hydrogen content measurement can be done both rapidly (on the order of 1 second) and nondestructively. Measurement of moisture in quicklime affects energy consumption in the steel industry. Further advances in system electronics, ongoing under DOD support, will enable yet more substantial system cost reductions over the prototype system, opening up a wider range of utility.

  16. TECHNICAL BASIS FOR EVALUATING SURFACE BARRIERS TO PROTECT GROUNDWATER FROM DEEP VADOSE ZONE CONTAMINATION

    SciTech Connect (OSTI)

    FAYER JM; FREEDMAN VL; WARD AL; CHRONISTER GB

    2010-02-24

    tasks to achieve those outcomes. Full understanding of contaminant behavior in the deep vadose zone is constrained by four key data gaps: limited access; limited data; limited time; and the lack of an accepted predictive capability for determining whether surface barriers can effectively isolate deep vadose zone contaminants. Activities designed to fill these data gaps need to have these outcomes: (1) common evaluation methodology that provides a clear, consistent, and defensible basis for evaluating groundwater impacts caused by placement of a surface barrier above deep vadose zone contamination; (2) deep vadose zone data that characterize the lithology, the spatial distribution of moisture and contaminants, the physical, chemical, and biological process that affect the mobility of each contaminant, and the impacts to the contaminants following placement of a surface barrier; (3) subsurface monitoring to provide subsurface characterization of initial conditions and changes that occur during and following remediation activities; and (4) field observations that span years to decades to validate the evaluation methodology. A set of six proposed tasks was identified to provide information needed to address the above outcomes. The proposed tasks are: (1) Evaluation Methodology - Develop common evaluation methodology that will provide a clear, consistent, and defensible basis for evaluating groundwater impacts caused by placement of a surface barrier above deep vadose zone contamination. (2) Case Studies - Conduct case studies to demonstrate the applicability ofthe common evaluation methodology and provide templates for subsequent use elsewhere. Three sites expected to have conditions that would yield valuable information and experience pertinent to deep vadose zone contamination were chosen to cover a range of conditions. The sites are BC Cribs and Trenches, U Plant Cribs, and the T Farm Interim Cover. (3) Subsurface Monitoring Technologies - Evaluate minimally invasive

  17. Comparison of the One-electron Oxidations of CO-Bridged vs Unbridged Bimetallic Complexes: Electron-transfer Chemistry of Os2Cp2(CO)4 and Os2Cp*2(μ-CO)2(CO)2 (Cp = η5-C5H5, Cp* = η5-C5Me5)

    SciTech Connect (OSTI)

    Laws, Derek R.; Bullock, R. Morris; Lee, Richmond; Huang, Kuo-Wei; Geiger, William J.

    2014-09-22

    The one-electron oxidations of two dimers of half-sandwich osmium carbonyl complexes have been examined by electrochemistry, spectro-electrochemistry, and computational methods. The all-terminal carbonyl complex Os2Cp2(CO)4 (1, Cp = η5-C5H5) undergoes a reversible one-electron anodic reaction at E1/2 = 0.41 V vs ferrocene in CH2Cl2/0.05 M [NBu4][B(C6F5)4], giving a rare example of a metal-metal bonded radical cation unsupported by bridging ligands. The IR spectrum of 1+ is consistent with an approximately 1:1 mixture of anti and gauche structures for the 33 e- radical cation in which it has retained all-terminal bonding of the CO ligands. DFT calculations, including orbital-occupancy-perturbed Mayer bond-order analyses, show that the HOMOs of anti-1 and gauche-1 are metal-ligand delocalized. Removal of an electron from 1 has very little effect on the Os-Os bond order, accounting for the resistance of 1+ to heterolytic cleavage. The Os-Os bond distance is calculated to decrease by 0.10 Å and 0.06 Å as a consequence of one-electron oxidation of anti-1 and gauche-1, respectively. The CO-bridged complex Os2Cp*2(μ-CO)2(CO)2 (Cp* = η5-C5Me5), trans-2, undergoes a more facile oxidation, E1/2 = - 0.11 V, giving a persistent radical cation shown by solution IR analysis to preserve its bridged-carbonyl structure. However, ESR analysis of frozen solutions of 2+ is interpreted in terms of the presence of two isomers, most likely anti-2+ and trans-2+, at low temperature. Calculations show that the HOMO of trans-2 is highly delocalized over the metal-ligand framework, with the bridging carbonyls accounting for about half of the orbital makeup. The Os-Os bond order again changes very little with removal of an electron, and the Os-Os bond length actually undergoes minor shortening. Calculations suggest that the second isomer of 2+ has both the trans CO-bridged and the anti all-terminal CO structures. DRL and WEG acknowledge the support of the National Science Foundation under

  18. Deployment Effects of Marin Renewable Energy Technologies

    SciTech Connect (OSTI)

    Brian Polagye; Mirko Previsic

    2010-06-17

    Identifying Key Environmental Concerns This is the second report in the sequence and describes the results of conceptual feasibility studies of tidal power plants deployed in Tacoma Narrows, Washington. The Narrows contain many of the same competing stakeholder interactions identified at other tidal power sites and serves as a representative case study. Tidal power remains at an early stage of development. As such, a wide range of different technologies are being pursued by different manufacturers. In order to properly characterize impacts, it is useful to characterize the range of technologies that could be deployed at the site of interest. An industry survey informs the process of selecting representative tidal power devices. The selection criteria is that such devices are at an advanced stage of development to reduce technical uncertainties and that enough data are available from the manufacturers to inform the conceptual design process of this study. Further, an attempt is made to cover the range of different technologies under development to capture variations in potential environmental effects. A number of other developers are also at an advanced stage of development including Verdant Power, which has demonstrated an array of turbines in the East River of New York, Clean Current, which has demonstrated a device off Race Rocks, BC, and OpenHydro, which has demonstrated a device at the European Marine Energy Test Center and is on the verge of deploying a larger device in the Bay of Fundy. MCT demonstrated their device both at Devon (UK) and Strangford Narrows (Northern Ireland). Furthermore OpenHydro, CleanCurrent, and MCT are the three devices being installed at the Minas Passage (Canada). Environmental effects will largely scale with the size of tidal power development. In many cases, the effects of a single device may not be measurable, while larger scale device arrays may have cumulative impacts that differ significantly from smaller scale deployments. In order to