National Library of Energy BETA

Sample records for battery voltage indicator

  1. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: High-Voltage Solid Polymer Batteries for Electric Drive Vehicles Citation Details In-Document Search Title: High-Voltage Solid Polymer Batteries for Electric ...

  2. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications High-Voltage Solid Polymer Batteries for Electric Drive Vehicles Vehicle Technologies Office Merit Review 2014: High-Voltage Solid Polymer Batteries ...

  3. Solid Electrolyte: the Key for High-Voltage Lithium Batteries...

    Office of Scientific and Technical Information (OSTI)

    Solid Electrolyte: the Key for High-Voltage Lithium Batteries Citation Details In-Document Search Title: Solid Electrolyte: the Key for High-Voltage Lithium Batteries Authors: Li, ...

  4. High Voltage Electrolyte for Lithium Batteries | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es113_amine_2011_p.pdf (246.67 KB) More Documents & Publications High Voltage Electrolyte for Lithium Batteries Vehicle Technologies Office Merit Review 2015: Fluorinated Electrolyte for 5-V Li-Ion Chemistry High Voltage Electrolytes for Li-ion Batteries

  5. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...

    Office of Scientific and Technical Information (OSTI)

    Title: High-Voltage Solid Polymer Batteries for Electric Drive Vehicles The purpose of this project was for Seeo to develop a high energy lithium based technology with targets of ...

  6. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...

    Office of Scientific and Technical Information (OSTI)

    Voltage Solid Polymer Batteries for Electric Drive Vehicles Eitouni, Hany; Yang, Jin; Pratt, Russell; Wang, Xiao; Grape, Ulrik The purpose of this project was for Seeo to develop a...

  7. High voltage series connected tandem junction solar battery

    DOE Patents [OSTI]

    Hanak, Joseph J.

    1982-01-01

    A high voltage series connected tandem junction solar battery which comprises a plurality of strips of tandem junction solar cells of hydrogenated amorphous silicon having one optical path and electrically interconnected by a tunnel junction. The layers of hydrogenated amorphous silicon, arranged in a tandem configuration, can have the same bandgap or differing bandgaps. The tandem junction strip solar cells are series connected to produce a solar battery of any desired voltage.

  8. State of charge indicators for a battery

    DOE Patents [OSTI]

    Rouhani, S. Zia

    1999-01-01

    The present invention relates to state of charge indicators for a battery. One aspect of the present invention utilizes expansion and contraction displacements of an electrode plate of a battery to gauge the state of charge in the battery. One embodiment of a battery of the present invention includes an anodic plate; a cathodic plate; an electrolyte in contact with the anodic and cathodic plates; plural terminals individually coupled with one of the anodic and cathodic plates; a separator intermediate the anodic and cathodic plates; an indicator configured to indicate an energy level of the battery responsive to movement of the separator; and a casing configured to house the anodic and cathodic plates, electrolyte, and separator.

  9. Solid electrolyte: The key for high-voltage lithium batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Juchuan; Ma, Cheng; Chi, Miaofang; Liang, Chengdu; Dudney, Nancy J.

    2014-10-14

    A solid-state high-voltage (5 V) lithium battery is demonstrated to deliver a cycle life of 10 000 with 90% capacity retention. Furthermore, the solid electrolyte enables the use of high-voltage cathodes and Li anodes with minimum side reactions, leading to a high Coulombic efficiency of 99.98+%.

  10. Method of inhibiting voltage suppression lithium/fluorinated carbon batteries

    SciTech Connect (OSTI)

    Shia, G.A.; Friedland, D.J.

    1987-08-11

    An improved lithium/fluorinated carbon battery is described wherein the cathode comprises a blend of at least two different CF/sub x/ compositions which are derived from petroleum-based coke products which have been prepared by heat treatment at a temperature between about 800/sup 0/C and 2,0006/sup 0/C: (a) a bulk CF/sub x/ and (b) an additive CF/sub x/ and wherein from about 0.5 percent to about 50 percent of (b) is characterized as having a closed circuit voltage of at least 150 mV above the plateau voltage of the bulk CF/sub x/ and a specific capacity above 600 mAH/g. A method is also described for the elimination of suppression of the closed circuit voltage of a Li/CF/sub x/ battery during the initial part of its discharge.

  11. Inhibiting voltage suppression in lithium/fluorinated carbon batteries

    SciTech Connect (OSTI)

    Shia, G.A.; Nalewajek, D.; Pyszczek, M.F.

    1988-12-13

    This patent describes a lithium/fluorinated carbon battery having a reduced initial voltage suppression which comprises the incorporation in the battery cathode of fluorinated carbon which has been reacted with a compound selected from the group consisting of a Group IA metal-alkyl compound and a Group IA metal-aryl compound, which Group IA metal-aryl compound has at least 10 carbon atoms, until surface fluorine on the fluorinated carbon has been stripped and alkyl or aryl groups from the Group IA metal-alkyl compound or Group IA metal-aryl compound are substituted for surface fluorine atoms.

  12. Method for improving voltage regulation of batteries, particularly Li/FeS.sub.2 thermal batteries

    DOE Patents [OSTI]

    Godshall, Ned A.

    1988-01-01

    Batteries are improved, especially with respect to voltage regulation properties, by employing as anode and cathode compositions, those which fall in a thermodynamically invariant region of the metallurgical phase diagram of the combination of the constituent components. The invention is especially useful in the Li/FeS.sub.2 system.

  13. Method for improving voltage regulation of batteries, particularly Li/FeS/sub 2/ thermal batteries

    DOE Patents [OSTI]

    Godshall, N.A.

    1986-06-10

    Batteries are improved, especially with respect to voltage regulation properties, by employing as anode and cathode compositions, those which fall in a thermodynamically invariant region of the metallurgical phase diagram of the combination of the constituent components. The invention is especially useful in the Li/FeS/sub 2/ system.

  14. Method of determining the open circuit voltage of a battery in a closed circuit

    DOE Patents [OSTI]

    Brown, William E.

    1980-01-01

    The open circuit voltage of a battery which is connected in a closed circuit is determined without breaking the circuit or causing voltage upsets therein. The closed circuit voltage across the battery and the current flowing through it are determined under normal load and then a fractional change is made in the load and the new current and voltage values determined. The open circuit voltage is then calculated, according to known principles, from the two sets of values.

  15. Lithium/fluorinated carbon battery with no voltage delay

    SciTech Connect (OSTI)

    Tung, H.S.; Friedland, D.J.; Sukornick, B.; Mc Curry, L.E.; Eibeck, R.E.; Lockyer, G.D.

    1987-07-21

    A method is described for producing an improved fluorinated carbon, for use as a cathode active material in a lithium fluorinated carbon battery, which inhibits initial voltage delay upon discharge, which comprises: (a) introducing a comminuted carbon into a static bed reactor; (b) foring a bed of the carbon to a depth of at least 0.5 cm; and (c) subjecting the carbon bed to a fluorination reaction under controlled reaction time with fluorine to produce an inhomogeneous fluorinated carbon product and until the carbon attains a weight gain of at least 10 percent.

  16. High Voltage Electrolytes for Li-ion Batteries | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting es024_jow_2012_o.pdf (6.21 MB) More Documents & Publications High Voltage Electrolytes for Li-ion Batteries High Voltage Electrolytes for Li-ion Batteries Progress in Electrolyte Component R&D within the ABR Program, 2009 thru 2013

  17. High Voltage Electrolytes for Li-ion Batteries | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es024_jow_2011_p.pdf (1.87 MB) More Documents & Publications High Voltage Electrolytes for Li-ion Batteries High Voltage Electrolytes for Li-ion Batteries Molecular dynamics simulation and ab intio studies of electrolytes and electrolyte/electrode interfaces

  18. Battery charger and state of charge indicator. Final report

    SciTech Connect (OSTI)

    Latos, T.S.

    1984-04-15

    The battery charger has a full-wave rectifier in series with a transformer isolated 20 kHz dc-dc converter with high frequency switches which are programmed to actively shape the input ac line current to be a mirror image of the ac line voltage. The power circuit is capable of operating at 2 kW peak and 1 kW average power. The BC/SCI has two major subsystems: (1) the battery charger power electronics with its controls; and (2) a microcomputer subsystem which is used to acquire battery terminal data and exercise the state-of-charge software programs. The state-of-charge definition employed is the energy remaining in the battery when extracted at a 10 kW rate divided by the energy capacity of a fully charged new battery. The battery charger circuit is an isolated boost converter operating at an internal frequency of 20 kHz. The switches selected for the battery charger are the single most important item in determining its efficiency. The combination of voltage and current requirements dictated the use of high power NPN Darlington switching transistors. The power circuit topology developed is a three switch design utilizing a power FET on the center tap of the isolation transformer and the power Darlingtons on each of the two ends. An analog control system is employed to accomplish active input current waveshaping as well as the necessary regulation.

  19. New technique for improving voltage regulation in Li/FeS/sub 2/ thermal batteries

    SciTech Connect (OSTI)

    Godshall, N.A.; Baldwin, A.R.

    1986-01-01

    Lithiation of the FeS/sub 2/ cathode material lowers the voltage of the initial discharge (which is often too high for many applications) and raises the voltage of the battery at the end of discharge (which is often too low due to a second voltage plateau). In the example of the Sandia ten-cell Li(Si)/FeS/sub 2/ long-life thermal battery, lithiating the cathode improves the voltage regulation from 12.8 to 0.5% during the initial 5 minutes of discharge and from 38 to 12% over the entire 60 minute discharge time. Batteries employing the new lithiated cathode material were also subjected to dynamic mechanical environments, both before and during electrochemical discharge. No adverse changes in either the electrical or mechanical properties of these batteries was observed, relative to standard composition batteries.

  20. Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malliakas, Christos D.; Leung, Kevin; Pupek, Krzysztof Z.; Shkrob, Ilya A.; Abraham, Daniel P.

    2016-03-31

    Fluorinated carbonate solvents are pursued as liquid electrolytes for high-voltage Li-ion batteries. We report aggregation of [Li+(FEC)3]n polymer species from fluoroethylene carbonate containing electrolytes and scrutinized the causes for this behavior.

  1. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect High-Voltage Solid Polymer Batteries for Electric Drive Vehicles Citation Details In-Document Search Title: High-Voltage Solid Polymer Batteries for Electric Drive Vehicles The purpose of this project was for Seeo to develop a high energy lithium based technology with targets of over 500 Wh/l and 325 Wh/kg. Seeo would leverage the work already achieved with its unique proprietary solid polymer DryLyteTM technology in cells which had a specific energy density of 220

  2. A class of polysulfide catholytes for lithium-sulfur batteries: energy density, cyclability, and voltage enhancement

    SciTech Connect (OSTI)

    Yu, XW; Manthiram, A

    2015-01-01

    Liquid-phase polysulfide catholytes are attracting much attention in lithium-sulfur (Li-S) batteries as they provide a facile dispersion and homogeneous distribution of the sulfur active material in the conductive matrix. However, the organic solvents used in lithium-polysulfide (Li-PS) batteries play an important role and have an impact on the physico-chemical characteristics of polysulfides. For instance, significantly higher voltages (similar to 2.7 V) of the S/S-n(2-) (4 <= n <= 8) redox couple are observed in Li-PS batteries with dimethyl sulfoxide (DMSO) and N-methyl-2-pyrrolidone (NMP) solvents. Accordingly, high power Li-PS batteries are presented here with the catholyte prepared with NMP solvent and operated with the highly reversible sulfur/long-chain polysulfide redox couple. On the other hand, a remarkable cyclability enhancement of the Li-PS battery is observed with the long-chain, ether-based tetraglyme (TEGDME) solvent. The voltage enhancement and the cyclability enhancement of the Li-PS batteries are attributed to the solvation effect, viscosity, and volatility of the solvents. Finally, highly concentrated polysulfide catholytes are successfully synthesized, with which high energy density Li-PS batteries are demonstrated by employing a multi-walled carbon nanotube (MWCNT) fabric electrode.

  3. Non-aqueous electrolyte for high voltage rechargeable magnesium batteries

    DOE Patents [OSTI]

    Doe, Robert Ellis; Lane, George Hamilton; Jilek, Robert E; Hwang, Jaehee

    2015-02-10

    An electrolyte for use in electrochemical cells is provided. The properties of the electrolyte include high conductivity, high Coulombic efficiency, and an electrochemical window that can exceed 3.5 V vs. Mg/Mg.sup.+2. The use of the electrolyte promotes the electrochemical deposition and dissolution of Mg without the use of any Grignard reagents, other organometallic materials, tetraphenyl borate, or tetrachloroaluminate derived anions. Other Mg-containing electrolyte systems that are expected to be suitable for use in secondary batteries are also described.

  4. Method for improving voltage regulation of batteries, particularly Li/FeS/sub 2/ thermal batteries

    SciTech Connect (OSTI)

    Godshall, N.A.

    1988-08-02

    In a battery composition useful as the cathode of a Li/-FeS/sub 2/ thermal battery, consisting essentially of substantially pure FeS/sub 2/, the improvement is described wherein sufficient lithium is added to the composition whereby the resultant composition falls into a three-phase thermodynamically invariant region of the Li/Fe/S phase diagram and has the formula Li/sub x/FeS/sub 2/ with the proviso that 0.05 less than or equal toxless than or equal to 1.5.

  5. Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors

    SciTech Connect (OSTI)

    Dr. Brian Dixon

    2008-12-30

    Magnesium has been used successfully in primary batteries, but its use in rechargeable cells has been stymied by the lack of suitable non-aqueous electrolyte that can conduct Mg+2 species, combined with poor stripping and plating properties. The development of a suitable cathode material for rechargeable magnesium batteries has also been a roadblock, but a nonflammable electrolyte is key. Likewise, the development of safe high voltage electrochemical supercapaitors has been stymied by the use of flammable solvents in the liquid electrolyte; to wit, acetonitrile. The purpose of the research conducted in this effort was to identify useful compositions of magnesium salts and polyphosphate solvents that would enable magnesium ions to be cycled within a secondary battery design. The polyphosphate solvents would provide the solvent for the magnesium salts while preventing the electrolyte from being flammable. This would enable these novel electrolytes to be considered as an alternative to THF-based electrolytes. In addition, we explored several of these solvents together with lithium slats for use as high voltage electrolytes for carbon-based electrochemical supercapacitors. The research was successful in that: 1) Magnesium imide dissolved in a phosphate ester solvent that contains a halogented phosphate ester appears to be the preferred electrolyte for a rechargeable Mg cell. 2) A combination of B-doped CNTs and vanadium phosphate appear to be the cathode of choice for a rechargeable Mg cell by virtue of higher voltage and better reversibility. 3) Magnesium alloys appear to perform better than pure magnesium when used in combination with the novel polyphosphate electrolytes. Also, this effort has established that Phoenix Innovation??s family of phosphonate/phosphate electrolytes together with specific lithium slats can be used in supercapacitor systems at voltages of greater than 10V.

  6. Evolution of a voltage-time model of thermal batteries. Technical memo

    SciTech Connect (OSTI)

    Knight, J.

    1991-02-01

    A temperature time model of thermal batteries has almost been completed and validated against experimental data. This Memorandum first summarises early attempts to integrate a voltage-time model into this, taking advantage of the instantaneous predictions of temperature, thermodynamic potentials, and internal resistance which the thermal model provides. It then describes how recent refinements of the voltage-time model have led to improved simulation of the discharges of a wide range of sizes and types of thermal battery under an equally wide range of test conditions. The semi-empirical approach adopted has been to provide a universally-applicable framework based on logical concepts to cover various effects such as polarisation etc, but with adjustable numerical parameters. It is shown that a moderately good simulation may be obtained for the majority of available discharge curves, using this one set of equations and without altering parameter values. Further improvements can be obtained when parameter values are optimised for one particular type of battery. Comparisons of model simulations against a body of experimental data have pinpointed remaining discrepancies which will guide further refinement efforts.

  7. A new low-voltage plateau of Na₃V₂(PO₄)₃ as an anode for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jian, Zelang; Sun, Yang; Ji, Xiulei

    2015-04-04

    A low-voltage plateau at ~0.3 V is discovered during the deep sodiation of Na₃V₂(PO₄)₃ by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na₃V₂(PO₄)₃, turning it into a promising anode for Na-ion batteries.

  8. Phosphorus Enrichment as a New Composition in the Solid Electrolyte Interphase of High-Voltage Cathodes and Its Effects on Battery Cycling

    SciTech Connect (OSTI)

    Yan, Pengfei; Zheng, Jianming; Kuppan, Saravanan; Li, Qiuyan; Lv, Dongping; Xiao, Jie; Chen, Guoying; Zhang, Jiguang; Wang, Chong M.

    2015-11-10

    Immersion of a solid into liquid often leads to the modification of both the structure and chemistry of surface of the solid, which subsequently affects the chemical and physical properties of the system. For the case of the rechargeable lithium ion battery, such a surface modification is termed as solid electrolyte interphase (SEI) layer, which has been perceived to play critical role for the stable operation of the batteries. However, the structure and chemical composition of SEI layer and its spatial distribution and dependence on the battery operating condition remain unclear. By using aberration corrected scanning transmission electron microscopy coupled with ultra-high sensitive energy dispersive x-ray spectroscopy, we probed the structure and chemistry of SEI layer on several high voltage cathodes. We show that layer-structured cathodes, when cycled at a high cut off voltage, can form a P-rich SEI layer on their surface, which is a direct evidence of Li-salt (LiPF6) decomposition. Our systematical investigations indicate such cathode/Li-salt side reaction shows strong dependence on structure of the cathode materials, operating voltage and temperature, indicating the feasibility of SEI engineering. These findings provide us valuable insights into the complex interface between the high-voltage cathode and the electrolyte.

  9. Automatic voltage imbalance detector

    DOE Patents [OSTI]

    Bobbett, Ronald E.; McCormick, J. Byron; Kerwin, William J.

    1984-01-01

    A device for indicating and preventing damage to voltage cells such as galvanic cells and fuel cells connected in series by detecting sequential voltages and comparing these voltages to adjacent voltage cells. The device is implemented by using operational amplifiers and switching circuitry is provided by transistors. The device can be utilized in battery powered electric vehicles to prevent galvanic cell damage and also in series connected fuel cells to prevent fuel cell damage.

  10. Arc voltage distribution skewness as an indicator of electrode gap during vacuum arc remelting

    DOE Patents [OSTI]

    Williamson, Rodney L.; Zanner, Frank J.; Grose, Stephen M.

    1998-01-01

    The electrode gap of a VAR is monitored by determining the skewness of a distribution of gap voltage measurements. A decrease in skewness indicates an increase in gap and may be used to control the gap.

  11. Arc voltage distribution skewness as an indicator of electrode gap during vacuum arc remelting

    DOE Patents [OSTI]

    Williamson, R.L.; Zanner, F.J.; Grose, S.M.

    1998-01-13

    The electrode gap of a VAR is monitored by determining the skewness of a distribution of gap voltage measurements. A decrease in skewness indicates an increase in gap and may be used to control the gap. 4 figs.

  12. Unconventional irreversible structural changes in a high-voltage Li–Mn-rich oxide for lithium-ion battery cathodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mohanty, Debasish; Sefat, Athena S.; Payzant, E. Andrew; Li, Jianlin; Wood, David L.; Daniel, Claus

    2015-02-19

    Making all-electric vehicles (EVs) commonplace in transportation applications will require affordable high-power and high-energy-density lithium-ion batteries (LIBs). The quest for suitable cathode materials to meet this end has currently plateaued with the discovery of high-voltage (≥4.7 V vs. Li+), high capacity (~250 mAh/g) lithium–manganese-rich (LMR) layered composite oxides. In spite of the promise of LMR oxides in high-energy-density LIBs, an irreversible structural change has been identified in this work that is governed by the formation of a ‘permanent’ spin-glass type magnetically frustrated phase indicating a dominant AB2O4 (A = Li, B = Mn) type spinel after a short-term lithium deintercalationmore » (charging) and intercalation (discharging) process. Furthermore, reduction of transition metal (Mn) ions from the 4+ state (pristine LMR) to 3+ (cycled LMR), which alters the intercalation redox chemistry and suggests the presence of ‘unfilled’ lithium vacancies and/or oxygen vacancies in the lattice after cycling, has presented a major stumbling block. Finally, these situations result in both loss of capacity and fading of the voltage profile, and these combined effects significantly reduce the high energy density over even short-term cycling.« less

  13. Vehicle Technologies Office Merit Review 2014: The Voltage Fade Project, A New Paradigm for Applied Battery Research

    Broader source: Energy.gov [DOE]

    Presentation given by the Department of Energy's Energy Storage area at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about a new approach to the challenge of voltage fade in batteries for plug-in electric vehicles.

  14. How voltage drops are manifested by lithium ion configurations at interfaces and in thin films on battery electrodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leung, Kevin; Leenheer, Andrew Jay

    2015-04-09

    Battery electrode surfaces are generally coated with electronically insulating solid films of thickness 1-50 nm. Both electrons and Li+ can move at the electrode–surface film interface in response to the voltage, which adds complexity to the “electric double layer” (EDL). We also apply Density Functional Theory (DFT) to investigate how the applied voltage is manifested as changes in the EDL at atomic length scales, including charge separation and interfacial dipole moments. Illustrating examples include Li3PO4, Li2CO3, and LixMn2O4 thin films on Au(111) surfaces under ultrahigh vacuum conditions. Adsorbed organic solvent molecules can strongly reduce voltages predicted in vacuum. We proposemore » that manipulating surface dipoles, seldom discussed in battery studies, may be a viable strategy to improve electrode passivation. We also distinguish the computed potential governing electrons, which is the actual or instantaneous voltage, and the “lithium cohesive energy”-based voltage governing Li content widely reported in DFT calculations, which is a slower-responding self-consistency criterion at interfaces. Furthermore, this distinction is critical for a comprehensive description of electrochemical activities on electrode surfaces, including Li+ insertion dynamics, parasitic electrolyte decomposition, and electrodeposition at overpotentials.« less

  15. How Voltage Drops are Manifested by Lithium Ion Configurations at Interfaces and in Thin Films on Battery Electrodes

    SciTech Connect (OSTI)

    Leung, Kevin; Leenheer, Andrew Jay

    2015-04-09

    Battery electrode surfaces are generally coated with electronically insulating solid films of thickness 150 nm. Both electrons and Li+ can move at the electrodesurface film interface in response to the voltage, which adds complexity to the electric double layer (EDL). We also apply Density Functional Theory (DFT) to investigate how the applied voltage is manifested as changes in the EDL at atomic length scales, including charge separation and interfacial dipole moments. Illustrating examples include Li3PO4, Li2CO3, and LixMn2O4 thin films on Au(111) surfaces under ultrahigh vacuum conditions. Adsorbed organic solvent molecules can strongly reduce voltages predicted in vacuum. We propose that manipulating surface dipoles, seldom discussed in battery studies, may be a viable strategy to improve electrode passivation. We also distinguish the computed potential governing electrons, which is the actual or instantaneous voltage, and the lithium cohesive energy-based voltage governing Li content widely reported in DFT calculations, which is a slower-responding self-consistency criterion at interfaces. Furthermore, this distinction is critical for a comprehensive description of electrochemical activities on electrode surfaces, including Li+ insertion dynamics, parasitic electrolyte decomposition, and electrodeposition at overpotentials.

  16. How voltage drops are manifested by lithium ion configurations at interfaces and in thin films on battery electrodes

    SciTech Connect (OSTI)

    Leung, Kevin; Leenheer, Andrew Jay

    2015-04-09

    Battery electrode surfaces are generally coated with electronically insulating solid films of thickness 1-50 nm. Both electrons and Li+ can move at the electrode–surface film interface in response to the voltage, which adds complexity to the “electric double layer” (EDL). We also apply Density Functional Theory (DFT) to investigate how the applied voltage is manifested as changes in the EDL at atomic length scales, including charge separation and interfacial dipole moments. Illustrating examples include Li3PO4, Li2CO3, and LixMn2O4 thin films on Au(111) surfaces under ultrahigh vacuum conditions. Adsorbed organic solvent molecules can strongly reduce voltages predicted in vacuum. We propose that manipulating surface dipoles, seldom discussed in battery studies, may be a viable strategy to improve electrode passivation. We also distinguish the computed potential governing electrons, which is the actual or instantaneous voltage, and the “lithium cohesive energy”-based voltage governing Li content widely reported in DFT calculations, which is a slower-responding self-consistency criterion at interfaces. Furthermore, this distinction is critical for a comprehensive description of electrochemical activities on electrode surfaces, including Li+ insertion dynamics, parasitic electrolyte decomposition, and electrodeposition at overpotentials.

  17. Characterization of the Li(Si)/CoS(2) couple for a high-voltage, high-power thermal battery

    SciTech Connect (OSTI)

    GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.

    2000-02-01

    In order to determined the capabilities of a thermal battery with high-voltage and high-power requirements, a detailed characterization of the candidate LiSi/LiCl-LiBr-LiF/CoS{sub 2} electrochemical couple was conducted. The rate capability of this system was investigated using 0.75 inch-dia. and 1.25 inch-dia. single and multiple cells under isothermal conditions, where the cells were regularly pulsed at increasingly higher currents. Limitations of the electronic loads and power supplies necessitated using batteries to obtain the desired maximum current densities possible for this system. Both 1.25 inch-dia. and 3 inch-dia. stacks were used with the number of cells ranging from 5 to 20. Initial tests involved 1.25 inch-dia. cells, where current densities in excess of 15 A/cm{sup 2} (>200 W/cm{sup 2}) were attained with 20-cell batteries during 1-s pulses. In subsequent follow-up tests with 3 inch-dia., 10-cell batteries, ten 400-A 1-s pulses were delivered over an operating period often minutes. These tests formed the foundation for subsequent full-sized battery tests with 125 cells with this chemistry.

  18. Method and apparatus for indicating electric charge remaining in batteries based on electrode weight and center of gravity

    DOE Patents [OSTI]

    Rouhani, S.Z.

    1996-12-03

    In most electrochemical batteries which generate electricity through the reaction of a battery electrode with an electrolyte solution, the chemical composition, and thus the weight and density, of the electrode changes as the battery discharges. The invention measures a parameter of the battery which changes as the weight of the electrode changes as the battery discharges and relates that parameter to the value of the parameter when the battery is fully charged and when the battery is functionally discharged to determine the state-of-charge of the battery at the time the parameter is measured. In one embodiment, the weight of a battery electrode or electrode unit is measured to determine the state-of-charge. In other embodiments, where a battery electrode is located away from the geometrical center of the battery, the position of the center of gravity of the battery or shift in the position of the center of gravity of the battery is measured (the position of the center of gravity changes with the change in weight of the electrode) and indicates the state-of-charge of the battery. 35 figs.

  19. Method and apparatus for indicating electric charge remaining in batteries based on electrode weight and center of gravity

    DOE Patents [OSTI]

    Rouhani, S. Zia

    1996-01-01

    In most electrochemical batteries which generate electricity through the reaction of a battery electrode with an electrolyte solution, the chemical composition, and thus the weight and density, of the electrode changes as the battery discharges. The invention measures a parameter of the battery which changes as the weight of the electrode changes as the battery discharges and relates that parameter to the value of the parameter when the battery is fully charged and when the battery is functionally discharged to determine the state-of-charge of the battery at the time the parameter is measured. In one embodiment, the weight of a battery electrode or electrode unit is measured to determine the state-of-charge. In other embodiments, where a battery electrode is located away from the geometrical center of the battery, the position of the center of gravity of the battery or shift in the position of the center of gravity of the battery is measured (the position of the center of gravity changes with the change in weight of the electrode) and indicates the state-of-charge of the battery.

  20. A new low-voltage plateau of Na3V2(PO4)(3) as an anode for Na-ion batteries

    SciTech Connect (OSTI)

    Jian, ZL; Sun, Y; Ji, XL

    2015-01-01

    A low-voltage plateau at similar to 0.3 V is discovered for the deep sodiation of Na3V2(PO4)(3) by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na3V2(PO4)(3), thus turning it into a promising anode for Na-ion batteries.

  1. Oxidation Potentials of Functionalized Sulfone Solvents for High-Voltage Li-Ion Batteries: A Computational Study

    SciTech Connect (OSTI)

    Shao, Nan; Sun, Xiao-Guang; Dai, Sheng; Jiang, Deen

    2012-01-01

    New electrolytes with large electrochemical windows are needed to meet the challenge for high-voltage Li-ion batteries. Sulfone as an electrolyte solvent boasts of high oxidation potentials. Here we examine the effect of multiple functionalization on sulfone's oxidation potential. We compute oxidation potentials for a series of sulfone-based molecules functionalized with fluorine, cyano, ester, and carbonate groups by using a quantum chemistry method within a continuum solvation model. We find that multifunctionalization is a key to achieving high oxidation potentials. This can be realized through either a fluorether group on a sulfone molecule or sulfonyl fluoride with a cyano or ester group.

  2. High voltage rechargeable magnesium batteries having a non-aqueous electrolyte

    DOE Patents [OSTI]

    Doe, Robert Ellis; Lane, George Hamilton; Jilek, Robert E.; Hwang, Jaehee

    2016-03-22

    A rechargable magnesium battery having an non-aqueous electrolyte is provided. The properties of the electrolyte include high conductivity, high Coulombic efficiency, and an electrochemical window that can exceed 3.5 V vs. Mg/Mg.sup.+2. The use of the electrolyte promotes the electrochemical deposition and dissolution of Mg without the use of any Grignard reagents, other organometallic materials, tetraphenyl borate, or tetrachloroaluminate derived anions. Other Mg-containing electrolyte systems that are expected to be suitable for use in secondary batteries are also described.

  3. Vehicle Technologies Office Merit Review 2014: High-Voltage Solid Polymer Batteries for Electric Drive Vehicles

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Seeo, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high-voltage solid polymer...

  4. CNEEC - Batteries Tutorial by Prof. Cui

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries

  5. Batteries

    Broader source: Energy.gov [DOE]

    From consumer electronics to laptops to vehicles, batteries are an important part of our everyday life. Learn about the Energy Department's innovative research and development in different energy storage options.

  6. Development of a high-voltage, high-power thermal battery

    SciTech Connect (OSTI)

    Guidotti, R.A.; Scharrer, G.L.; Binasiewicz, E.; Reinhardt, F.W.

    1998-04-01

    The power requirements for an inverter application were specified to be 500 V at 360 A, or 180 kW per each of six 1-s pulses delivered over a period of 10 minutes. Conventional high-power sources (e.g., flywheels) could not meet these requirements and the use of a thermal battery was considered. The final design involved four, 125-cell, 50-kW modules connected in series. A module using the LiSi/CoS{sub 2} couple and all-Li (LiCI-LiBr-LiF minimum-melting) electrolyte was successfully developed and tested. A power level of over 40 kW was delivered during a 0.5-s pulse. This translates into a specific power level of over 9 kW/kg or 19.2 kW/L delivered from a module. The module was still able to deliver over 30 kW during a 1-s pulse after 10 minutes.

  7. Charging a Battery-Powered Device with a Fiber-Optically Connected Photonic Power System for Achieving High-Voltage Isolation

    SciTech Connect (OSTI)

    Lizon, David C; Gioria, Jack G; Dale, Gregory E; Snyder, Hans R

    2008-01-01

    This paper describes the development and testing of a system to provide isolated power to the cathode-subsystem electronics of an x-ray tube. These components are located at the cathode potential of several hundred kilovolts, requiring a supply of power isolated from this high voltage. In this design a fiber-optically connected photonic power system (PPS) is used to recharge a lithium-ion battery pack, which will subsequently supply power to the cathode-subsystem electronics. The suitability of the commercially available JDSU PPS for this application is evaluated. The output of the ppe converter is characterized. The technical aspects of its use for charging a variety of Li-Ion batteries are discussed. Battery charge protection requirements and safety concerns are also addressed.

  8. High power impulse magnetron sputtering: Current-voltage-timecharacteristics indicate the onset of sustained self-sputtering

    SciTech Connect (OSTI)

    Anders, Andre; Andersson, Joakim; Ehiasarian, Arutiun

    2007-08-03

    The commonly used current-voltage characteristics are foundinadequate for describing the pulsed nature of the high power impulsemagnetron sputtering (HIPIMS) discharge, rather, the description needs tobe expanded to current-voltage-time characteristics for each initial gaspressure. Using different target materials (Cu, Ti, Nb, C, W, Al, Cr) anda pulsed constant-voltage supply it is shown that the HIPIMS dischargestypically exhibit an initial pressure dependent current peak followed bya second phase that is power and material dependent. This suggests thatthe initial phase of a HIPIMS discharge pulse is dominated by gas ionswhereas the later phase has a strong contribution from self-sputtering.For some materials the discharge switches into a mode of sustainedself-sputtering. The very large differences between materials cannot beascribed to the different sputter yields but they indicate thatgeneration and trapping ofsecondary electrons plays a major role forcurrent-voltage-time characteristics. In particular, it is argued thatthe sustained self-sputtering phase is associated with thegeneration ofmultiply charged ions because only they can cause potential emission ofsecondary electrons whereas the yield caused by singly charged metal ionsis negligibly small.

  9. Multicell Li/SOCl/sub 2/ reserve battery

    SciTech Connect (OSTI)

    Baldwin, A.R.; Garoutte, K.F.

    1984-01-01

    Recent development work on reserve lithium thionyl chloride (RLTC) batteries at SNLA and Honeywell has included safety and performance evaluations. The RLTC battery is being considered for applications that have traditionally been fulfilled by state-of-the-art thermal batteries and reserve silver oxide zinc electrochemical systems. These applications typically demand a reserve battery having a rapid voltage rise, high reliability, operational safety and useful active lifetime ranging from minutes to hours. The RLTC work reported here was directed toward a power battery capable of meeting or exceeding the design requirements. Performance and safety test data indicate that the RLTC battery may be better suited than thermal batteries for some long-life applications. Table II presents a comparison between a Li(Si)/FeS/sub 2/ thermal battery and an RLTC battery, both of which were designed to fulfill the requirements.

  10. Unraveling the Voltage-Fade Mechanism in High-Energy-Density Lithium-Ion Batteries: Origin of the Tetrahedral Cations for Spinel Conversion

    SciTech Connect (OSTI)

    Mohanty, Debasish; Li, Jianlin; Abraham, Daniel P.; Huq, Ashfia; Payzant, E. Andrew; Wood, David L.; Daniel, Claus

    2014-09-30

    Discovery of high-voltage layered lithium-and manganese-rich (LMR) composite oxide electrode has dramatically enhanced the energy density of current Li-ion energy storage systems. However, practical usage of these materials is currently not viable because of their inability to maintain a consistent voltage profile (voltage fading) during subsequent charge-discharge cycles. This report rationalizes the cause of this voltage fade by providing the evidence of layer to spinel-like (LSL) structural evolution pathways in the host Li1.2Mn0.55Ni0.15Co0.1O2 LMR composite oxide. By employing neutron powder diffraction, and temperature dependent magnetic susceptibility, we show that LSL structural rearrangement in LMR oxide occurs through a tetrahedral cation intermediate via: i) diffusion of lithium atoms from octahedral to tetrahedral sites of the lithium layer [(LiLioct →LiLitet] which is followed by the dispersal of the lithium ions from the adjacent octahedral site of the metal layer to the tetrahedral sites of lithium layer [LiTM oct → LiLitet]; and ii) migration of Mn from the octahedral sites of the transition metal layer to the permanent octahedral site of lithium layer via tetrahedral site of lithium layer [MnTMoct MnLitet MnLioct)]. The findings opens the door to the potential routes to mitigate this atomic restructuring in the high-voltage LMR composite oxide cathodes by manipulating the composition/structure for practical use in high-energy-density lithium-ion batteries.

  11. Unraveling the Voltage-Fade Mechanism in High-Energy-Density Lithium-Ion Batteries: Origin of the Tetrahedral Cations for Spinel Conversion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mohanty, Debasish; Li, Jianlin; Abraham, Daniel P.; Huq, Ashfia; Payzant, E. Andrew; Wood, David L.; Daniel, Claus

    2014-09-30

    Discovery of high-voltage layered lithium-and manganese-rich (LMR) composite oxide electrode has dramatically enhanced the energy density of current Li-ion energy storage systems. However, practical usage of these materials is currently not viable because of their inability to maintain a consistent voltage profile (voltage fading) during subsequent charge-discharge cycles. This report rationalizes the cause of this voltage fade by providing the evidence of layer to spinel-like (LSL) structural evolution pathways in the host Li1.2Mn0.55Ni0.15Co0.1O2 LMR composite oxide. By employing neutron powder diffraction, and temperature dependent magnetic susceptibility, we show that LSL structural rearrangement in LMR oxide occurs through a tetrahedral cationmore » intermediate via: i) diffusion of lithium atoms from octahedral to tetrahedral sites of the lithium layer [(LiLioct →LiLitet] which is followed by the dispersal of the lithium ions from the adjacent octahedral site of the metal layer to the tetrahedral sites of lithium layer [LiTM oct → LiLitet]; and ii) migration of Mn from the octahedral sites of the transition metal layer to the permanent octahedral site of lithium layer via tetrahedral site of lithium layer [MnTMoct MnLitet MnLioct)]. The findings opens the door to the potential routes to mitigate this atomic restructuring in the high-voltage LMR composite oxide cathodes by manipulating the composition/structure for practical use in high-energy-density lithium-ion batteries.« less

  12. Monitoring apparatus and method for battery power supply

    DOE Patents [OSTI]

    Martin, Harry L.; Goodson, Raymond E.

    1983-01-01

    A monitoring apparatus and method are disclosed for monitoring and/or indicating energy that a battery power source has then remaining and/or can deliver for utilization purposes as, for example, to an electric vehicle. A battery mathematical model forms the basis for monitoring with a capacity prediction determined from measurement of the discharge current rate and stored battery parameters. The predicted capacity is used to provide a state-of-charge indication. Self-calibration over the life of the battery power supply is enacted through use of a feedback voltage based upon the difference between predicted and measured voltages to correct the battery mathematical model. Through use of a microprocessor with central information storage of temperature, current and voltage, system behavior is monitored, and system flexibility is enhanced.

  13. Modification of Ni-Rich FCG NMC and NCA Cathodes by Atomic Layer Deposition: Preventing Surface Phase Transitions for High-Voltage Lithium-Ion Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mohanty, Debasish; Dahlberg, Kevin; King, David M.; David, Lamuel A.; Sefat, Athena S.; Wood, David L.; Daniel, Claus; Dhar, Subhash; Mahajan, Vishal; Lee, Myongjai; et al

    2016-05-26

    The energy density of current lithium-ion batteries (LIBs) based on layered LiMO2 cathodes (M=Ni, Mn, Co: NMC; M=Ni, Co, Al: NCA) needs to be improved significantly in order to compete with internal combustion engines and allow for widespread implementation of electric vehicles (EVs). In this report, we show that atomic layer deposition (ALD) of titania (TiO2) and alumina (Al2O3) on Ni-rich FCG NMC and NCA active material particles could substantially improve LIB performance and allow for increased upper cutoff voltage (UCV) during charging, which delivers significantly increased specific energy utilization. Our results show that Al2O3 coating improved the NMC cyclingmore » performance by 40% and the NCA cycling performance by 34% at 1C/₋1C with respectively 4.35V and 4.4V UCV in 2Ah pouch cells. High resolution TEM/SAED structural characterization revealed that Al2O3 coatings prevented surface-initiated layered-to-spinel phase transitions in coated materials which were prevalent in uncoated materials. Lastly, EIS confirmed that Al2O3-coated materials had significantly lower increase in the charge transfer component of impedance during cycling. In conclusion, the ability to mitigate degradation mechanisms for Ni-rich NMC and NCA illustrated in this report provides insight into a method to enable the performance of high-voltage LIBs.« less

  14. Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics

    SciTech Connect (OSTI)

    Mohanty, Debasish; Li, Jianlin; Nagpure, Shrikant C; Wood, III, David L; Daniel, Claus

    2015-12-21

    Materials diagnostic techniques are the principal tools used in the development of low-cost, high-performance electrodes for next-generation lithium-based energy storage technologies. Also, this review highlights the importance of materials diagnostic techniques in unraveling the structure and the structural degradation mechanisms in high-voltage, high-capacity oxides that have the potential to be implemented in high-energy-density lithium-ion batteries for transportation that can use renewable energy and is less-polluting than today. The rise in CO2 concentration in the earth’s atmosphere due to the use of petroleum products in vehicles and the dramatic increase in the cost of gasoline demand the replacement of current internal combustion engines in our vehicles with environmentally friendly, carbon free systems. Therefore, vehicles powered fully/partially by electricity are being introduced into today’s transportation fleet. As power requirements in all-electric vehicles become more demanding, lithium-ion battery (LiB) technology is now the potential candidate to provide higher energy density. Moreover, discovery of layered high-voltage lithium-manganese–rich (HV-LMR) oxides has provided a new direction toward developing high-energy-density LiBs because of their ability to deliver high capacity (~250 mA h/g) and to be operated at high operating voltage (~4.7 V). Unfortunately, practical use of HV-LMR electrodes is not viable because of structural changes in the host oxide during operation that can lead to fundamental and practical issues. This article provides the current understanding on the structure and structural degradation pathways in HV-LMR oxides, and manifests the importance of different materials diagnostic tools to unraveling the key mechanism(s). Furthermore, the fundamental insights reported, might become the tools to manipulate the chemical and/or structural aspects of HV-LMR oxides for low cost, high-energy-density LiB applications.

  15. Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mohanty, Debasish; Li, Jianlin; Nagpure, Shrikant C; Wood, III, David L; Daniel, Claus

    2015-12-21

    Materials diagnostic techniques are the principal tools used in the development of low-cost, high-performance electrodes for next-generation lithium-based energy storage technologies. Also, this review highlights the importance of materials diagnostic techniques in unraveling the structure and the structural degradation mechanisms in high-voltage, high-capacity oxides that have the potential to be implemented in high-energy-density lithium-ion batteries for transportation that can use renewable energy and is less-polluting than today. The rise in CO2 concentration in the earth’s atmosphere due to the use of petroleum products in vehicles and the dramatic increase in the cost of gasoline demand the replacement of current internalmore » combustion engines in our vehicles with environmentally friendly, carbon free systems. Therefore, vehicles powered fully/partially by electricity are being introduced into today’s transportation fleet. As power requirements in all-electric vehicles become more demanding, lithium-ion battery (LiB) technology is now the potential candidate to provide higher energy density. Moreover, discovery of layered high-voltage lithium-manganese–rich (HV-LMR) oxides has provided a new direction toward developing high-energy-density LiBs because of their ability to deliver high capacity (~250 mA h/g) and to be operated at high operating voltage (~4.7 V). Unfortunately, practical use of HV-LMR electrodes is not viable because of structural changes in the host oxide during operation that can lead to fundamental and practical issues. This article provides the current understanding on the structure and structural degradation pathways in HV-LMR oxides, and manifests the importance of different materials diagnostic tools to unraveling the key mechanism(s). Furthermore, the fundamental insights reported, might become the tools to manipulate the chemical and/or structural aspects of HV-LMR oxides for low cost, high-energy-density LiB applications.« less

  16. Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics

    SciTech Connect (OSTI)

    Mohanty, Debasish; Li, Jianlin; Nagpure, Shrikant C; Wood, III, David L; Daniel, Claus

    2015-01-01

    Materials diagnostic techniques are the principal tools used in the development of low-cost, high-performance electrodes for next-generation lithium-based energy storage technologies. Also, this review highlights the importance of materials diagnostic techniques in unraveling the structure and the structural degradation mechanisms in high-voltage, high-capacity oxides that have the potential to be implemented in high-energy-density lithium-ion batteries for transportation that can use renewable energy and is less-polluting than today. The rise in CO2 concentration in the earth’s atmosphere due to the use of petroleum products in vehicles and the dramatic increase in the cost of gasoline demand the replacement of current internal combustion engines in our vehicles with environmentally friendly, carbon free systems. Therefore, vehicles powered fully/partially by electricity are being introduced into today’s transportation fleet. As power requirements in all-electric vehicles become more demanding, lithium-ion battery (LiB) technology is now the potential candidate to provide higher energy density. Moreover, discovery of layered high-voltage lithium-manganese–rich (HV-LMR) oxides has provided a new direction toward developing high-energy-density LiBs because of their ability to deliver high capacity (~250 mA h/g) and to be operated at high operating voltage (~4.7 V). Unfortunately, practical use of HV-LMR electrodes is not viable because of structural changes in the host oxide during operation that can lead to fundamental and practical issues. This article provides the current understanding on the structure and structural degradation pathways in HV-LMR oxides, and manifests the importance of different materials diagnostic tools to unraveling the key mechanism(s). Furthermore, the fundamental insights reported, might become the tools to manipulate the chemical and/or structural aspects of HV-LMR oxides for low cost, high-energy-density LiB applications.

  17. Manifestation of Voltages on Pristine- and Thin Film-Coated Lithium...

    Office of Scientific and Technical Information (OSTI)

    voltage - most critical for modeling interfacial Electrochemical process in lithium ion batteries Voltage dependence governs Li+ intercalation into anodecathode, passivation ...

  18. Lithium battery

    SciTech Connect (OSTI)

    Ikeda, H.; Nakaido, S.; Narukara, S.

    1983-08-16

    In a lithium battery having a negative electrode formed with lithium as active material and the positive electrode formed with manganese dioxide, carbon fluoride or the like as the active material, the discharge capacity of the negative electrode is made smaller than the discharge capacity of the positive electrode, whereby a drop in the battery voltage during the final discharge stage is steepened, and prevents a device using such a lithium battery as a power supply from operating in an unstable manner, thereby improving the reliability of such device.

  19. Optical voltage reference

    DOE Patents [OSTI]

    Rankin, R.; Kotter, D.

    1994-04-26

    An optical voltage reference for providing an alternative to a battery source is described. The optical reference apparatus provides a temperature stable, high precision, isolated voltage reference through the use of optical isolation techniques to eliminate current and impedance coupling errors. Pulse rate frequency modulation is employed to eliminate errors in the optical transmission link while phase-lock feedback is employed to stabilize the frequency to voltage transfer function. 2 figures.

  20. Optical voltage reference

    DOE Patents [OSTI]

    Rankin, Richard; Kotter, Dale

    1994-01-01

    An optical voltage reference for providing an alternative to a battery source. The optical reference apparatus provides a temperature stable, high precision, isolated voltage reference through the use of optical isolation techniques to eliminate current and impedance coupling errors. Pulse rate frequency modulation is employed to eliminate errors in the optical transmission link while phase-lock feedback is employed to stabilize the frequency to voltage transfer function.

  1. Towards predicting voltage dependences of electrode/electrolyte...

    Office of Scientific and Technical Information (OSTI)

    Towards predicting voltage dependences of electrodeelectrolyte interfacial processesnin lithium ion batteries. Citation Details In-Document Search Title: Towards predicting ...

  2. Network for minimizing current imbalances in a faradaic battery

    DOE Patents [OSTI]

    Wozniak, Walter; Haskins, Harold J.

    1994-01-01

    A circuit for connecting a faradaic battery with circuitry for monitoring the condition of the battery includes a plurality of voltage divider networks providing battery voltage monitoring nodes and includes compensating resistors connected with the networks to maintain uniform discharge currents through the cells of the battery. The circuit also provides a reduced common mode voltage requirement for the monitoring circuitry by referencing the divider networks to one-half the battery voltage.

  3. Battery Second Use Offsets Electric Vehicle Expenses, Improves...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battery Second Use Offsets Electric Vehicle Expenses, Improves Grid Stability June 22, 2015 Photo of a man in a lab, holding cables. NREL's Jeremy Neubauer measures battery voltage ...

  4. A Symmetric Organic - Based Nonaqueous Redox Flow Battery and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Symmetric Organic - Based Nonaqueous Redox Flow Battery and Its State of Charge Diagnostics by FTIR (1) Symmetric Nonaqueous flow battery based on ambipolar PTIO (cell voltage ...

  5. Electrochemically controlled charging circuit for storage batteries

    DOE Patents [OSTI]

    Onstott, E.I.

    1980-06-24

    An electrochemically controlled charging circuit for charging storage batteries is disclosed. The embodiments disclosed utilize dc amplification of battery control current to minimize total energy expended for charging storage batteries to a preset voltage level. The circuits allow for selection of Zener diodes having a wide range of reference voltage levels. Also, the preset voltage level to which the storage batteries are charged can be varied over a wide range.

  6. Device for monitoring cell voltage

    DOE Patents [OSTI]

    Doepke, Matthias; Eisermann, Henning

    2012-08-21

    A device for monitoring a rechargeable battery having a number of electrically connected cells includes at least one current interruption switch for interrupting current flowing through at least one associated cell and a plurality of monitoring units for detecting cell voltage. Each monitoring unit is associated with a single cell and includes a reference voltage unit for producing a defined reference threshold voltage and a voltage comparison unit for comparing the reference threshold voltage with a partial cell voltage of the associated cell. The reference voltage unit is electrically supplied from the cell voltage of the associated cell. The voltage comparison unit is coupled to the at least one current interruption switch for interrupting the current of at least the current flowing through the associated cell, with a defined minimum difference between the reference threshold voltage and the partial cell voltage.

  7. Electric Vehicle Battery Performance

    Energy Science and Technology Software Center (OSTI)

    1992-02-20

    DIANE is used to analyze battery performance in electric vehicle (EV) applications. The principal objective of DIANE is to enable the prediction of EV performance on the basis of laboratory test data for batteries. The model provides a second-by-second simulation of battery voltage and current for any specified velocity/time or power/time profile. Two releases are included with the package. Diane21 has a graphics capability; DIANENP has no graphics capability.

  8. Piezonuclear battery

    DOE Patents [OSTI]

    Bongianni, Wayne L.

    1992-01-01

    A piezonuclear battery generates output power arising from the piezoelectric voltage produced from radioactive decay particles interacting with a piezoelectric medium. Radioactive particle energy may directly create an acoustic wave in the piezoelectric medium or a moderator may be used to generate collision particles for interacting with the medium. In one embodiment a radioactive material (.sup.252 Cf) with an output of about 1 microwatt produced a 12 nanowatt output (1.2% conversion efficiency) from a piezoelectric copolymer of vinylidene fluoride/trifluorethylene.

  9. Towards predicting the voltage drop between electrode and electrolyte...

    Office of Scientific and Technical Information (OSTI)

    drop between electrode and electrolyte in lithium ion batteries. Citation Details In-Document Search Title: Towards predicting the voltage drop between electrode and electrolyte ...

  10. How Voltage Drops are Manifested by Lithium Ion Configurations...

    Office of Scientific and Technical Information (OSTI)

    Title: How Voltage Drops are Manifested by Lithium Ion Configurations at Interfaces and in ... Subject: bio-inspired, energy storage (including batteries and capacitors), defects, ...

  11. DE-EE0005449 High-Voltage Solid Polymer ...

    Office of Scientific and Technical Information (OSTI)

    NATIONAL ENERGY TECHNOLOGY LABORATORY (NETL) UNITED STATES DEPARTMENT OF ENERGY Vi Final Technical Report High-Voltage Solid Polymer Batteries for Electric Drive Vehicles Award ...

  12. Nanoscale Morphological and Chemical Changes of High Voltage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Morphological and Chemical Changes of High Voltage Lithium-Manganese Rich NMC ... must understand the evolution of chemical composition and morphology of battery ...

  13. Current balancing for battery strings

    DOE Patents [OSTI]

    Galloway, James H.

    1985-01-01

    A battery plant is described which features magnetic circuit means for balancing the electrical current flow through a pluraliircuitbattery strings which are connected electrically in parallel. The magnetic circuit means is associated with the battery strings such that the conductors carrying the electrical current flow through each of the battery strings pass through the magnetic circuit means in directions which cause the electromagnetic fields of at least one predetermined pair of the conductors to oppose each other. In an alternative embodiment, a low voltage converter is associated with each of the battery strings for balancing the electrical current flow through the battery strings.

  14. Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study

    SciTech Connect (OSTI)

    Xu, Bo; Fell, Christopher R.; Chi, Miaofang; Meng, Ying Shirley

    2011-09-06

    High voltage cathode materials Li-excess layered oxide compounds Li[Ni{sub x}Li{sub 1/3-2x/3}Mn{sub 2/3-x/3}]O{sub 2} (0 < x < 1/2) are investigated in a joint study combining both computational and experimental methods. The bulk and surface structures of pristine and cycled samples of Li[Ni{sub 1/5}Li{sub 1/5}Mn{sub 3/5}]O{sub 2} are characterized by synchrotron X-Ray diffraction together with aberration corrected Scanning Transmission Electron Microscopy (a-S/TEM). Electron Energy Loss Spectroscopy (EELS) is carried out to investigate the surface changes of the samples before/after electrochemical cycling. Combining first principles computational investigation with our experimental observations, a detailed lithium de-intercalation mechanism is proposed for this family of Li-excess layered oxides. The most striking characteristics in these high voltage high energy density cathode materials are (1) formation of tetrahedral lithium ions at voltage less than 4.45 V and (2) the transition metal (TM) ions migration leading to phase transformation on the surface of the materials. We show clear evidence of a new spinel-like solid phase formed on the surface of the electrode materials after high-voltage cycling. It is proposed that such surface phase transformation is one of the factors contributing to the first cycle irreversible capacity and the main reason for the intrinsic poor rate capability of these materials.

  15. Alternator control for battery charging

    SciTech Connect (OSTI)

    Brunstetter, Craig A.; Jaye, John R.; Tallarek, Glen E.; Adams, Joseph B.

    2015-07-14

    In accordance with an aspect of the present disclosure, an electrical system for an automotive vehicle has an electrical generating machine and a battery. A set point voltage, which sets an output voltage of the electrical generating machine, is set by an electronic control unit (ECU). The ECU selects one of a plurality of control modes for controlling the alternator based on an operating state of the vehicle as determined from vehicle operating parameters. The ECU selects a range for the set point voltage based on the selected control mode and then sets the set point voltage within the range based on feedback parameters for that control mode. In an aspect, the control modes include a trickle charge mode and battery charge current is the feedback parameter and the ECU controls the set point voltage within the range to maintain a predetermined battery charge current.

  16. Electrode Materials for Rechargeable Lithium-Ion Batteries: A...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lowers battery pack cost. Layered cathode material contains low-cost manganese, which operates at high rate and high voltage and results in a high-energy-density battery with ...

  17. Battery system

    DOE Patents [OSTI]

    Dougherty, Thomas J; Wood, Steven J; Trester, Dale B; Andrew, Michael G

    2013-08-27

    A battery module includes a plurality of battery cells and a system configured for passing a fluid past at least a portion of the plurality of battery cells in a parallel manner.

  18. VOLTAGE REGULATOR

    DOE Patents [OSTI]

    Von Eschen, R.L.; Scheele, P.F.

    1962-04-24

    A transistorized voltage regulator which provides very close voitage regulation up to about 180 deg F is described. A diode in the positive line provides a constant voltage drop from the input to a regulating transistor emitter. An amplifier is coupled to the positive line through a resistor and is connected between a difference circuit and the regulating transistor base which is negative due to the difference in voltage drop across thc diode and the resistor so that a change in the regulator output causes the amplifier to increase or decrease the base voltage and current and incrcase or decrease the transistor impedance to return the regulator output to normal. (AEC)

  19. Lithium Batteries

    Office of Scientific and Technical Information (OSTI)

    Thin-Film Battery with Lithium Anode Courtesy of Oak Ridge National Laboratory, Materials Science and Technology Division Lithium Batteries Resources with Additional Information...

  20. High Voltage Electrolyte for Lithium Batteries

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  1. EVSE Features LED Charge Indicator Cellular Modem EVSE Specifcations

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Charge Indicator Cellular Modem EVSE Specifcations Grid connection Dual NEMA 6-50P Cordsets Connector type J1772 Approximate size (H x W x D inches) 16 x 24 x 6 Charge level AC Level 2 Input voltage 208 / 240 VAC Maximum input current 32 Amp Circuit breaker rating 40 Amp Test Conditions 1 Test date 12/5/2013 Nominal supply voltage (Vrms) 208.6 Supply frequency (Hz) 60.00 Initial ambient temperature (°F) 8 Test Vehicle 1,3 Make and model 2012 Chevrolet Volt Battery type Li-ion Steady state

  2. TRANSISTOR HIGH VOLTAGE POWER SUPPLY

    DOE Patents [OSTI]

    Driver, G.E.

    1958-07-15

    High voltage, direct current power supplies are described for use with battery powered nuclear detection equipment. The particular advantages of the power supply described, are increased efficiency and reduced size and welght brought about by the use of transistors in the circuit. An important feature resides tn the employment of a pair of transistors in an alternatefiring oscillator circuit having a coupling transformer and other circuit components which are used for interconnecting the various electrodes of the transistors.

  3. Self-Regulating, Nonflamable Rechargeable Lithium Batteries

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2010-06-23

    Rechargeable lithium batteries are superior to other rechargeable batteries due to their ability to store more energy per unit size and weight and to operate at higher voltages. The performance of lithium ion batteries available today, however, has been compromised by their tendency to overheat during operation. This condition, called “thermal runaway,” can melt the battery’s lithium metal and, in the most serious cases, result in explosive chemical reactions....

  4. Thermal battery comprising iron pyrite depolarizer and ferric sulfate additive

    SciTech Connect (OSTI)

    Winchester, C.S.; Williams, M.T.

    1987-06-23

    This patent describes a thermal battery having a salt electrolyte, means to activate the battery by melting the electrolyte, and a FeS/sub 2/ depolarizer. The improvement comprises an amount of ferric sulfate effective to cause the occurrence of a voltage transient of predetermined magnitude and duration on activation of the battery.

  5. High performance batteries with carbon nanomaterials and ionic liquids

    DOE Patents [OSTI]

    Lu, Wen

    2012-08-07

    The present invention is directed to lithium-ion batteries in general and more particularly to lithium-ion batteries based on aligned graphene ribbon anodes, V.sub.2O.sub.5 graphene ribbon composite cathodes, and ionic liquid electrolytes. The lithium-ion batteries have excellent performance metrics of cell voltages, energy densities, and power densities.

  6. Lithium Batteries

    Office of Scientific and Technical Information (OSTI)

    information about thin-film lithium batteries is available in full-text and on the Web. ... Additional Web Pages: Thin Films for Advanced Batteries Thin-Film Rechargeable Lithium, ...

  7. Battery Charger Efficiency

    Energy Savers [EERE]

    Battery Chargers Marine and RV battery chargers differ from power tool and small appliance chargers CEC Testing assumes all variables are known - battery chemistry, battery size. ...

  8. Overdischarge protection in high-temperature cells and batteries

    DOE Patents [OSTI]

    Redey, Laszlo

    1990-01-01

    Overdischarge indication and protection is provided in a lithium alloy - metal sulfide, secondary electrochemical cell and batteries of such cells through use of a low lithium activity phase that ordinarily is not matched with positive electrode material. Low lithium activity phases such as Li.sub.0.1 Al.sub.0.9 and LiAlSi in correspondence with positive electrode material cause a downward gradient in cell voltage as an indication of overdischarge prior to damage to the cell. Moreover, the low lithium activity phase contributes lithium into the electrolyte and provides a lithium shuttling current as overdischarge protection after all of the positive electrode material is discharged.

  9. Chloromethyl chlorosulfate as a voltage delay inhibitor in lithium cells

    SciTech Connect (OSTI)

    Delnick, F.M.

    1991-04-05

    Chloromethyl chlorosulfate (CMCS) is used as a passive film growth inhibitor in electrochemical cells to minimize voltage delay and low-voltage discharge. Film growth on lithium anodes is significantly diminished when CMCS is added to SOCl{sub 2} and SO{sub 2}Cl{sub 2} electrolytes of lithium batteries. The CMCS also has the effect of extending the shelf-life of Li/SOCl{sub 2} and Li/SO{sub 2}Cl{sub 2} batteries.

  10. Chloromethyl chlorosulfate as a voltage delay inhibitor in lithium cells

    DOE Patents [OSTI]

    Delnick, Frank M.

    1993-01-01

    Chloromethyl chlorosulfate (CMCS) is used as a passive film growth inhibitor in electrochemical cells to minimize voltage delay and low-voltage discharge. Film growth on lithium anodes is significantly diminished when CMCS is added to SOCl.sub.2 and SO.sub.2 Cl.sub.2 electrolytes of lithium batteries. The CMCS also has the effect of extending the shelf-life of Li/SOCl.sub.2 and Li/SO.sub.2 Cl.sub.2 batteries.

  11. Chloromethyl chlorosulfate as a voltage delay inhibitor in lithium cells

    DOE Patents [OSTI]

    Delnick, F.M.

    1993-04-13

    Chloromethyl chlorosulfate (CMCS) is used as a passive film growth inhibitor in electrochemical cells to minimize voltage delay and low-voltage discharge. Film growth on lithium anodes is significantly diminished when CMCS is added to SOCl[sub 2] and SO[sub 2]Cl[sub 2] electrolytes of lithium batteries. The CMCS also has the effect of extending the shelf-life of Li/SOCl[sub 2] and Li/SO[sub 2]Cl[sub 2] batteries.

  12. Power electronic interface circuits for batteries and ultracapacitors in electric vehicles and battery storage systems

    DOE Patents [OSTI]

    King, Robert Dean; DeDoncker, Rik Wivina Anna Adelson

    1998-01-01

    A method and apparatus for load leveling of a battery in an electrical power system includes a power regulator coupled to transfer power between a load and a DC link, a battery coupled to the DC link through a first DC-to-DC converter and an auxiliary passive energy storage device coupled to the DC link through a second DC-to-DC converter. The battery is coupled to the passive energy storage device through a unidirectional conducting device whereby the battery can supply power to the DC link through each of the first and second converters when battery voltage exceeds voltage on the passive storage device. When the load comprises a motor capable of operating in a regenerative mode, the converters are adapted for transferring power to the battery and passive storage device. In this form, resistance can be coupled in circuit with the second DC-to-DC converter to dissipate excess regenerative power.

  13. Power electronic interface circuits for batteries and ultracapacitors in electric vehicles and battery storage systems

    DOE Patents [OSTI]

    King, R.D.; DeDoncker, R.W.A.A.

    1998-01-20

    A method and apparatus for load leveling of a battery in an electrical power system includes a power regulator coupled to transfer power between a load and a DC link, a battery coupled to the DC link through a first DC-to-DC converter and an auxiliary passive energy storage device coupled to the DC link through a second DC-to-DC converter. The battery is coupled to the passive energy storage device through a unidirectional conducting device whereby the battery can supply power to the DC link through each of the first and second converters when battery voltage exceeds voltage on the passive storage device. When the load comprises a motor capable of operating in a regenerative mode, the converters are adapted for transferring power to the battery and passive storage device. In this form, resistance can be coupled in circuit with the second DC-to-DC converter to dissipate excess regenerative power. 8 figs.

  14. Effect of an Ultrathin Coating on Stabilizing Li-ion Battery...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes Sunday, January 31, 2016 Improvements in the high-voltage cycling stability of lithium ion battery cathode ...

  15. Battery Charger Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battery Charger Efficiency Issues with Marine and Recreational Vehicle Battery Chargers Marine and RV battery chargers differ from power tool and small appliance chargers CEC Testing assumes all variables are known - battery chemistry, battery size. This is not the case in Marine and RV applications. * The battery charger manufacturer has no influence on the selection of batteries. * The battery charger could be used to charge a single battery, single battery bank, multiple batteries or multiple

  16. Lithium Batteries

    Office of Scientific and Technical Information (OSTI)

    This greatly expands the potential medical uses of the batteries, including transdermal applications for heart regulation.' -Edited excerpt from Medical Applications of Non-medical ...

  17. Eliminate Excessive In-Plant Distribution System Voltage Drops

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Excessive In-Plant Distribution System Voltage Drops Studies indicate that in-plant electrical distribution system losses-due to voltage unbalance, over- and undervoltage, low ...

  18. KAir Battery

    Broader source: Energy.gov [DOE]

    KAir Battery, from Ohio State University, is commercializing highly energy efficient cost-effective potassium air batteries for use in the electrical stationary storage systems market (ESSS). Beyond, the ESSS market potential applications range from temporary power stations and electric vehicle.

  19. Voltage Fade, an ABR Deep Dive Project: Status and Outcomes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Voltage Fade, an ABR Deep Dive Project: Status and Outcomes Project ID: ES161 Anthony Burrell Voltage Fade Team Annual Merit Review Washington DC, June 16-20, 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information. 2 Overview Timeline * Start: October 1, 2012 * End: Sept. 30, 2014 * Percent complete: 75% Budget * Voltage Fade project * $3,900K Barriers * Calendar/cycle life of lithium-ion cells being developed for PHEV and EV batteries that

  20. New composite separator pellet to increase power density and reduce size of thermal batteries.

    SciTech Connect (OSTI)

    Mondy, Lisa Ann; Roberts, Christine Cardinal; Grillet, Anne Mary; Soehnel, Melissa Marie; Barringer, David Alan; DiAntonio, Christopher Brian; Chavez, Thomas P.; Ingersoll, David T.; Hughes, Lindsey Gloe; Evans, Lindsey R.; Fitchett, Stephanie

    2013-11-01

    We show that it is possible to manufacture strong macroporous ceramic films that can be backfilled with electrolyte to form rigid separator pellets suitable for use in thermal batteries. Several new ceramic manufacturing processes are developed to produce sintered magnesium oxide foams with connected porosities of over 80% by volume and with sufficient strength to withstand the battery manufacturing steps. The effects of processing parameters are quantified, and methods to imbibe electrolyte into the ceramic scaffold demonstrated. Preliminary single cell battery testing show that some of our first generation pellets exhibit longer voltage life with comparable resistance at the critical early times to that exhibited by a traditional pressed pellets. Although more development work is needed to optimize the processes to create these rigid separator pellets, the results indicate the potential of such ceramic separator pellets to be equal, if not superior to, current pressed pellets. Furthermore, they could be a replacement for critical material that is no longer available, as well as improving battery separator strength, decreasing production costs, and leading to shorter battery stacks for long-life batteries.

  1. Flow battery

    DOE Patents [OSTI]

    Lipka, Stephen M.; Swartz, Christopher R.

    2016-02-23

    An electrolyte system for a flow battery has an anolyte including [Fe(CN).sub.6].sup.3- and [Fe(CN).sub.6].sup.4- and a catholyte including Fe.sup.2+ and Fe.sup.3+.

  2. Bipolar battery

    DOE Patents [OSTI]

    Kaun, Thomas D.

    1992-01-01

    A bipolar battery having a plurality of cells. The bipolar battery includes: a negative electrode; a positive electrode and a separator element disposed between the negative electrode and the positive electrode, the separator element electrically insulating the electrodes from one another; an electrolyte disposed within at least one of the negative electrode, the positive electrode and the separator element; and an electrode containment structure including a cup-like electrode holder.

  3. RADIOACTIVE BATTERY

    DOE Patents [OSTI]

    Birden, J.H.; Jordan, K.C.

    1959-11-17

    A radioactive battery which includes a capsule containing the active material and a thermopile associated therewith is presented. The capsule is both a shield to stop the radiations and thereby make the battery safe to use, and an energy conventer. The intense radioactive decay taking place inside is converted to useful heat at the capsule surface. The heat is conducted to the hot thermojunctions of a thermopile. The cold junctions of the thermopile are thermally insulated from the heat source, so that a temperature difference occurs between the hot and cold junctions, causing an electrical current of a constant magnitude to flow.

  4. Thermal battery

    SciTech Connect (OSTI)

    Williams, M.T.; Winchester, C.S.; Jolson, J.D.

    1989-06-20

    A thermal battery is described comprising at least one electrochemical cell comprising an anode of alkali metal, alkaline earth metal or alloys thereof, a fusible salt electrolyte, a fluorocarbon polymer or fluorochlorocarbon polymer depolarizer, and means for heating the cell to melt the electrolyte.

  5. Electrode Materials for Rechargeable Lithium-Ion Batteries: A New Synthetic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Approach | Argonne National Laboratory Materials for Rechargeable Lithium-Ion Batteries: A New Synthetic Approach Technology available for licensing: New high-energy cathode materials for use in rechargeable lithium-ion cells and batteries synthesized by using a novel alternative approach Lowers battery pack cost. Layered cathode material contains low-cost manganese, which operates at high rate and high voltage and results in a high-energy-density battery with improved stability. PDF icon

  6. Batteries: Overview of Battery Cathodes

    SciTech Connect (OSTI)

    Doeff, Marca M

    2010-07-12

    The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid

  7. Selected test results from the neosonic polymer Li-ion battery.

    SciTech Connect (OSTI)

    Ingersoll, David T.; Hund, Thomas D.

    2010-07-01

    The performance of the Neosonic polymer Li-ion battery was measured using a number of tests including capacity, capacity as a function of temperature, ohmic resistance, spectral impedance, hybrid pulsed power test, utility partial state of charge (PSOC) pulsed cycle test, and an over-charge/voltage abuse test. The goal of this work was to evaluate the performance of the polymer Li-ion battery technology for utility applications requiring frequent charges and discharges, such as voltage support, frequency regulation, wind farm energy smoothing, and solar photovoltaic energy smoothing. Test results have indicated that the Neosonic polymer Li-ion battery technology can provide power levels up to the 10C{sub 1} discharge rate with minimal energy loss compared to the 1 h (1C) discharge rate. Two of the three cells used in the utility PSOC pulsed cycle test completed about 12,000 cycles with only a gradual loss in capacity of 10 and 13%. The third cell experienced a 40% loss in capacity at about 11,000 cycles. The DC ohmic resistance and AC spectral impedance measurements also indicate that there were increases in impedance after cycling, especially for the third cell. Cell No.3 impedance Rs increased significantly along with extensive ballooning of the foil pouch. Finally, at a 1C (10 A) charge rate, the over charge/voltage abuse test with cell confinement similar to a multi cell string resulted in the cell venting hot gases at about 45 C 45 minutes into the test. At 104 minutes into the test the cell voltage spiked to the 12 volt limit and continued out to the end of the test at 151 minutes. In summary, the Neosonic cells performed as expected with good cycle-life and safety.

  8. HIGH VOLTAGE GENERATOR

    DOE Patents [OSTI]

    Zito, G.V.

    1959-04-21

    This patent relates to high voltage supply circuits adapted for providing operating voltages for GeigerMueller counter tubes, and is especially directed to an arrangement for maintaining uniform voltage under changing conditions of operation. In the usual power supply arrangement for counter tubes the counter voltage is taken from across the power supply output capacitor. If the count rate exceeds the current delivering capaciiy of the capacitor, the capacitor voltage will drop, decreasing the counter voltage. The present invention provides a multivibrator which has its output voltage controlled by a signal proportional to the counting rate. As the counting rate increases beyond the current delivering capacity of the capacitor, the rectified voltage output from the multivibrator is increased to maintain uniform counter voltage.

  9. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  10. Rechargeable thin film battery and method for making the same

    DOE Patents [OSTI]

    Goldner, Ronald B.; Liu, Te-Yang; Goldner, Mark A.; Gerouki, Alexandra; Haas, Terry E.

    2006-01-03

    A rechargeable, stackable, thin film, solid-state lithium electrochemical cell, thin film lithium battery and method for making the same is disclosed. The cell and battery provide for a variety configurations, voltage and current capacities. An innovative low temperature ion beam assisted deposition method for fabricating thin film, solid-state anodes, cathodes and electrolytes is disclosed wherein a source of energetic ions and evaporants combine to form thin film cell components having preferred crystallinity, structure and orientation. The disclosed batteries are particularly useful as power sources for portable electronic devices and electric vehicle applications where high energy density, high reversible charge capacity, high discharge current and long battery lifetimes are required.

  11. Eliminate Voltage Unbalance

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Voltage unbalance degrades the performance and shortens the life of a three-phase motor. Voltage unbalance at the motor terminals can cause current unbalance that is far out of ...

  12. battery2.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6-1982J Solid-State Environmentally Safe Battery for Replacing Lithium Batteries 1. ... Signature 2. Joint Entry with High Power Battery Systems Company 5 Silkin Street, Apt. 40 ...

  13. Overdischarge protection in high-temperature cells and batteries

    DOE Patents [OSTI]

    Redey, L.

    1990-06-19

    Overdischarge indication and protection is provided in a lithium alloy metal sulfide, secondary electrochemical cell and batteries of such cells through use of a low lithium activity phase that ordinarily is not matched with positive electrode material. Low lithium activity phases such as Li[sub 0.1]Al[sub 0.9] and LiAlSi in correspondence with positive electrode material cause a downward gradient in cell voltage as an indication of overdischarge prior to damage to the cell. Moreover, the low lithium activity phase contributes lithium into the electrolyte and provides a lithium shuttling current as overdischarge protection after all of the positive electrode material is discharged. 8 figs.

  14. Hardware Architecture for Measurements for 50-V Battery Modules

    SciTech Connect (OSTI)

    Patrick Bald; Evan Juras; Jon P. Christophersen; William Morrison

    2012-06-01

    Energy storage devices, especially batteries, have become critical for several industries including automotive, electric utilities, military and consumer electronics. With the increasing demand for electric and hybrid electric vehicles and the explosion in popularity of mobile and portable electronic devices such as laptops, cell phones, e-readers, tablet computers and the like, reliance on portable energy storage devices such as batteries has likewise increased. Because many of the systems these batteries integrated into are critical, there is an increased need for an accurate in-situ method of monitoring battery state-of-health. Over the past decade the Idaho National Laboratory (INL), Montana Tech of the University of Montana (Tech), and Qualtech Systems, Inc. (QSI) have been developing the Smart Battery Status Monitor (SBSM), an integrated battery management system designed to monitor battery health, performance and degradation and use this knowledge for effective battery management and increased battery life. Key to the success of the SBSM is an in-situ impedance measurement system called the Impedance Measurement Box (IMB). One of the challenges encountered has been development of a compact IMB system that will perform rapid accurate measurements of a battery impedance spectrum working with higher voltage batteries of up to 300 volts. This paper discusses the successful realization of a system that will work up to 50 volts.

  15. Battery cell feedthrough apparatus

    DOE Patents [OSTI]

    Kaun, Thomas D.

    1995-01-01

    A compact, hermetic feedthrough apparatus comprising interfitting sleeve portions constructed of chemically-stable materials to permit unique battery designs and increase battery life and performance.

  16. battery electrode percolating network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery electrode percolating network - Sandia Energy Energy Search Icon Sandia Home ... Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel ...

  17. Non-contact current and voltage sensor

    DOE Patents [OSTI]

    Carpenter, Gary D; El-Essawy, Wael; Ferreira, Alexandre Peixoto; Keller, Thomas Walter; Rubio, Juan C; Schappert, Michael A

    2014-03-25

    A detachable current and voltage sensor provides an isolated and convenient device to measure current passing through a conductor such as an AC branch circuit wire, as well as providing an indication of an electrostatic potential on the wire, which can be used to indicate the phase of the voltage on the wire, and optionally a magnitude of the voltage. The device includes a housing that contains the current and voltage sensors, which may be a ferrite cylinder with a hall effect sensor disposed in a gap along the circumference to measure current, or alternative a winding provided through the cylinder along its axis and a capacitive plate or wire disposed adjacent to, or within, the ferrite cylinder to provide the indication of the voltage.

  18. System for instrumenting and manipulating apparatuses in high voltage

    DOE Patents [OSTI]

    Jordan, Kevin

    2016-06-07

    A system for energizing, operating and manipulating apparatuses in high voltage systems. The system uses a dielectric gas such as SF.sub.6 as a driving power supply for a pneumatic motor which ultimately charges a battery or other energy storage device. The stored energy can then be used for instrumentation equipment, or to power any electrical equipment, in the high voltage deck. The accompanying method provides for the use of the SF6 system for operating an electrical device in a high-voltage environment.

  19. Dynamic voltage compensation on distribution feeders using flywheel energy storage

    SciTech Connect (OSTI)

    Weissbach, R.S.; Karady, G.G.; Farmer, R.G.

    1999-04-01

    Advancements in power electronics bearings and materials have made flywheel energy storage systems a viable alternative to electrochemical batteries. A future application of such a device is as an uninterruptible power supply for critical loads on a distribution feeder. However, the same power electronics and flywheel system could also be used for dynamic voltage compensation. A comparison is made between series and parallel connection of such dynamic compensation techniques used to maintain rated load voltage on distribution feeders when there are momentary dips in the supply voltage. For each case a mathematical model is presented and analyzed. The two cases are compared and the series compensation technique is more effective.

  20. Price Incentivised Electric Vehicle Charge Control for Community Voltage Regulation

    SciTech Connect (OSTI)

    Kelly, Damian; Baroncelli, Fabio; Fowler, Christopher; Boundy, David; Pratt, Annabelle

    2014-11-03

    With the growing availability of Electric Vehicles, there is a significant opportunity to use battery 'smart-charging' for voltage regulation. This work designs and experimentally evaluates a system for price-incentivised electric vehicle charging. The system is designed to eliminate negative impacts to the user while minimising the cost of charging and achieving a more favourable voltage behaviour throughout the local grid over time. The practical issues associated with a real-life deployment are identified and resolved. The efficacy of the system is evaluated in the challenging scenario in which EVs are deployed in six closely distributed homes, serviced by the same low voltage residential distribution feeder.

  1. Advanced Battery Manufacturing (VA)

    SciTech Connect (OSTI)

    Stratton, Jeremy

    2012-09-30

    LiFeBATT has concentrated its recent testing and evaluation on the safety of its batteries. There appears to be a good margin of safety with respect to overheating of the cells and the cases being utilized for the batteries are specifically designed to dissipate any heat built up during charging. This aspect of LiFeBATTs products will be even more fully investigated, and assuming ongoing positive results, it will become a major component of marketing efforts for the batteries. LiFeBATT has continued to receive prismatic 20 Amp hour cells from Taiwan. Further testing continues to indicate significant advantages over the previously available 15 Ah cells. Battery packs are being assembled with battery management systems in the Danville facility. Comprehensive tests are underway at Sandia National Laboratory to provide further documentation of the advantages of these 20 Ah cells. The company is pursuing its work with Hybrid Vehicles of Danville to critically evaluate the 20 Ah cells in a hybrid, armored vehicle being developed for military and security applications. Results have been even more encouraging than they were initially. LiFeBATT is expanding its work with several OEM customers to build a worldwide distribution network. These customers include a major automotive consulting group in the U.K., an Australian maker of luxury off-road campers, and a number of makers of E-bikes and scooters. LiFeBATT continues to explore the possibility of working with nations that are woefully short of infrastructure. Negotiations are underway with Siemens to jointly develop a system for using photovoltaic generation and battery storage to supply electricity to communities that are not currently served adequately. The IDA has continued to monitor the progress of LiFeBATTs work to ensure that all funds are being expended wisely and that matching funds will be generated as promised. The company has also remained current on all obligations for repayment of an IDA loan and lease

  2. Voltage Control Technical Conference

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1-08-Voltage-Control-Technical-Conference Sign In About | Careers | Contact | Investors | bpa.gov Search News & Us Expand News & Us Projects & Initiatives Expand Projects &...

  3. Eliminate Voltage Unbalance

    SciTech Connect (OSTI)

    Not Available

    2000-01-01

    This two-page abstract provides tips for plant managers on checking and monitoring motor voltage unbalance to improve performance and life-span of industrial motors.

  4. Optima Batteries | Open Energy Information

    Open Energy Info (EERE)

    Optima Batteries Jump to: navigation, search Name: Optima Batteries Place: Milwaukee, WI Website: www.optimabatteries.com References: Optima Batteries1 Information About...

  5. Anti-Idling Battery for Truck Applications

    SciTech Connect (OSTI)

    Keith Kelly

    2011-09-30

    In accordance to the Assistance Agreement DE-EE0001036, the objective of this project was to develop an advanced high voltage lithium-ion battery for use in an all-electric HVAC system for Class-7-8 heavy duty trucks. This system will help heavy duty truck drivers meet the tough new anti-idling laws being implemented by over 23 states. Quallion will be partnering with a major OEM supplier of HVAC systems to develop this system. The major OEM supplier will provide Quallion the necessary interface requirements and HVAC hardware to ensure successful testing of the all-electric system. At the end of the program, Quallion will deliver test data on three (3) batteries as well as test data for the prototype HVAC system. The objectives of the program are: (1) Battery Development - Objective 1 - Define battery and electronics specifications in preparation for building the prototype module. (Completed - summary included in report) and Objective 2 - Establish a functional prototype battery and characterize three batteries in-house. (Completed - photos and data included in report); (2) HVAC Development - Objective 1 - Collaborate with manufacturers to define HVAC components, layout, and electronics in preparation for establishing the prototype system. (Completed - photos and data included in report) and Objective 2 - Acquire components for three functional prototypes for use by Quallion. (Completed - photos and data included in report).

  6. Modeling and Simulation of Lithium-Ion Batteries from a Systems Engineering Perspective

    SciTech Connect (OSTI)

    Ramadesigan, V.; Northrop, P. W. C.; De, S.; Santhanagopalan, S.; Braatz, R. D.; Subramanian, Venkat R.

    2012-01-01

    The lithium-ion battery is an ideal candidate for a wide variety of applications due to its high energy/power density and operating voltage. Some limitations of existing lithium-ion battery technology include underutilization, stress-induced material damage, capacity fade, and the potential for thermal runaway. This paper reviews efforts in the modeling and simulation of lithium-ion batteries and their use in the design of better batteries. Likely future directions in battery modeling and design including promising research opportunities are outlined.

  7. Additive for iron disulfide cathodes used in thermal batteries

    DOE Patents [OSTI]

    Armijo, James R.; Searcy, Jimmie Q.

    1983-01-01

    The invention comprises thermal batteries employing an FeS.sub.2 depolarizer, i.e. cathode material, and the depolarizer itself. A minor amount of CaSi.sub.2 preferably, 1-3% by weight is provided as an additive in the FeS.sub.2 depolarizer to eliminate the voltage transient (spike) which normally occurs upon activation of batteries of this type. The amount of FeS.sub.2 by weight generally comprises 64-90%.

  8. Additive for iron disulfide cathodes used in thermal batteries

    DOE Patents [OSTI]

    Not Available

    1982-03-23

    The invention comprises thermal batteries employing an FeS/sub 2/ depolarizer itself. A minor amount of CaSi/sub 2/ preferably 1-3% by weight is provided as an additive in the FeS/sub 2/ depolarizer to eliminate the voltage transient (spike) which normally occurs upon activation of batteries of this type. The amount of FeS/sub 2/ by weight generally comprises 64 to 90%.

  9. Triple voltage dc-to-dc converter and method

    DOE Patents [OSTI]

    Su, Gui-Jia

    2008-08-05

    A circuit and method of providing three dc voltage buses and transforming power between a low voltage dc converter and a high voltage dc converter, by coupling a primary dc power circuit and a secondary dc power circuit through an isolation transformer; providing the gating signals to power semiconductor switches in the primary and secondary circuits to control power flow between the primary and secondary circuits and by controlling a phase shift between the primary voltage and the secondary voltage. The primary dc power circuit and the secondary dc power circuit each further comprising at least two tank capacitances arranged in series as a tank leg, at least two resonant switching devices arranged in series with each other and arranged in parallel with the tank leg, and at least one voltage source arranged in parallel with the tank leg and the resonant switching devices, said resonant switching devices including power semiconductor switches that are operated by gating signals. Additional embodiments having a center-tapped battery on the low voltage side and a plurality of modules on both the low voltage side and the high voltage side are also disclosed for the purpose of reducing ripple current and for reducing the size of the components.

  10. Passivation-free solid state battery

    DOE Patents [OSTI]

    Abraham, K.M.; Peramunage, D.

    1998-06-16

    This invention pertains to passivation-free solid-state rechargeable batteries composed of Li{sub 4}Ti{sub 5}O{sub 12} anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn{sub 2}O{sub 4}, LiCoO{sub 2}, LiNiO{sub 2} and LiV{sub 2}O{sub 5} and their derivatives. 5 figs.

  11. Passivation-free solid state battery

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M.; Peramunage, Dharmasena

    1998-01-01

    This invention pertains to passivation-free solid-state rechargeable batteries composed of Li.sub.4 Ti.sub.5 O.sub.12 anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn.sub.2 O.sub.4, LiCoO.sub.2, LiNiO.sub.2 and LiV.sub.2 O.sub.5 and their derivatives.

  12. Voltage verification unit

    DOE Patents [OSTI]

    Martin, Edward J.

    2008-01-15

    A voltage verification unit and method for determining the absence of potentially dangerous potentials within a power supply enclosure without Mode 2 work is disclosed. With this device and method, a qualified worker, following a relatively simple protocol that involves a function test (hot, cold, hot) of the voltage verification unit before Lock Out/Tag Out and, and once the Lock Out/Tag Out is completed, testing or "trying" by simply reading a display on the voltage verification unit can be accomplished without exposure of the operator to the interior of the voltage supply enclosure. According to a preferred embodiment, the voltage verification unit includes test leads to allow diagnostics with other meters, without the necessity of accessing potentially dangerous bus bars or the like.

  13. DC BUFFERING AND FLOATING CURRENT FOR A HIGH VOLTAGE IMB APPLICATION

    SciTech Connect (OSTI)

    J.L. Morrison

    2014-08-01

    An interface technique for the latest generation of the Impedance Measurement Box (IMB) has been conceived to enable measurement of impedance spectra for battery modules up to 300V. A 300V capable or higher IMB is an enabling technology for in-situ diagnostics within electric vehicle charging stations or battery back-ups within power distribution sub-stations. It is possible that the existing IMB can be adapted via a 300V interface module to a test battery with voltage significantly greater than 50V. Recently a new concept was conceived for the calibration, algorithm and electronics of the IMB. That algorithm and calibration for that concept have been physically validated. The principal feature of the new electronics is the floating current source excitation of the battery under test. The single ended current excitation of the battery under test, used in the 50V IMB, requires that the negative terminal of the test battery must be the analog ground for the IMB. The new floating current technique allows the test battery to be fully high impedance isolated for a measurement. That isolation will improve IMB noise immunity and enable interrogation of cells internal to a battery module. All these techniques still use the same rapid concept for impedance measurement with the IMB. The purpose of this disclosure is to provide an overview of the analytical validation for three concepts to interface the floating current excitation to a high voltage battery. Recursive simulation models were used in different test scenarios to validate the various new concepts. The analysis will show that it is possible to interface the floating signal current to obtain an impedance measurement on a high voltage test battery. Additionally, the analysis will investigate stress seen by electronics while testing a 300V battery.

  14. Selected test results from the LiFeBatt iron phosphate Li-ion battery.

    SciTech Connect (OSTI)

    Ingersoll, David T.; Hund, Thomas D.

    2008-09-01

    In this paper the performance of the LiFeBatt Li-ion cell was measured using a number of tests including capacity measurements, capacity as a function of temperature, ohmic resistance, spectral impedance, high power partial state of charge (PSOC) pulsed cycling, pulse power measurements, and an over-charge/voltage abuse test. The goal of this work was to evaluate the performance of the iron phosphate Li-ion battery technology for utility applications requiring frequent charges and discharges, such as voltage support, frequency regulation, and wind farm energy smoothing. Test results have indicated that the LiFeBatt battery technology can function up to a 10C{sub 1} discharge rate with minimal energy loss compared to the 1 h discharge rate (1C). The utility PSOC cycle test at up to the 4C{sub 1} pulse rate completed 8,394 PSOC pulsed cycles with a gradual loss in capacity of 10 to 15% depending on how the capacity loss is calculated. The majority of the capacity loss occurred during the initial 2,000 cycles, so it is projected that the LiFeBatt should PSOC cycle well beyond 8,394 cycles with less than 20% capacity loss. The DC ohmic resistance and AC spectral impedance measurements also indicate that there were only very small changes after cycling. Finally, at a 1C charge rate, the over charge/voltage abuse test resulted in the cell venting electrolyte at 110 C after 30 minutes and then open-circuiting at 120 C with no sparks, fire, or voltage across the cell.

  15. Lithium ion batteries and their manufacturing challenges

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Daniel, Claus

    2015-03-01

    There is no single lithium ion battery. With the variety of materials and electrochemical couples available, it is possible to design battery cells specific to their applications in terms of voltage, state of charge use, lifetime needs, and safety. Selection of specific electrochemical couples also facilitates the design of power and energy ratios and available energy. Integration in a large format cell requires optimized roll-to-roll electrode manufacturing and use of active materials. Electrodes are coated on a metal current collector foil in a composite structure of active material, binders, and conductive additives, requiring careful control of colloidal chemistry, adhesion, andmore » solidification. But the added inactive materials and the cell packaging reduce energy density. Furthermore, degree of porosity and compaction in the electrode can affect battery performance.« less

  16. Thermal Evaluation of the Honda Insight Battery Pack: Preprint

    SciTech Connect (OSTI)

    Zolot, M.D.; Kelly, K.; Keyser, M.; Mihalic, M.; Pesaran, A.; Hieronymus, A.

    2001-06-18

    The hybrid vehicle test efforts at National Renewable Energy Laboratory (NREL), with a focus on the Honda Insight's battery thermal management system, are presented. The performance of the Insight's high voltage NiMH battery pack was characterized by conducting in-vehicle dynamometer testing at Environmental Testing Corporation's high altitude dynamometer test facility, on-road testing in the Denver area, and out-of-car testing in NREL's Battery Thermal Management Laboratory. It is concluded that performance does vary considerably due to thermal conditions the pack encounters. The performance variations are due to both inherent NiMH characteristics, and the Insight's thermal management system.

  17. Voltage balanced multilevel voltage source converter system

    DOE Patents [OSTI]

    Peng, F.Z.; Lai, J.S.

    1997-07-01

    Disclosed is a voltage balanced multilevel converter for high power AC applications such as adjustable speed motor drives and back-to-back DC intertie of adjacent power systems. This converter provides a multilevel rectifier, a multilevel inverter, and a DC link between the rectifier and the inverter allowing voltage balancing between each of the voltage levels within the multilevel converter. The rectifier is equipped with at least one phase leg and a source input node for each of the phases. The rectifier is further equipped with a plurality of rectifier DC output nodes. The inverter is equipped with at least one phase leg and a load output node for each of the phases. The inverter is further equipped with a plurality of inverter DC input nodes. The DC link is equipped with a plurality of rectifier charging means and a plurality of inverter discharging means. The plurality of rectifier charging means are connected in series with one of the rectifier charging means disposed between and connected in an operable relationship with each adjacent pair of rectifier DC output nodes. The plurality of inverter discharging means are connected in series with one of the inverter discharging means disposed between and connected in an operable relationship with each adjacent pair of inverter DC input nodes. Each of said rectifier DC output nodes are individually electrically connected to the respective inverter DC input nodes. By this means, each of the rectifier DC output nodes and each of the inverter DC input nodes are voltage balanced by the respective charging and discharging of the rectifier charging means and the inverter discharging means. 15 figs.

  18. Voltage balanced multilevel voltage source converter system

    DOE Patents [OSTI]

    Peng, Fang Zheng; Lai, Jih-Sheng

    1997-01-01

    A voltage balanced multilevel converter for high power AC applications such as adjustable speed motor drives and back-to-back DC intertie of adjacent power systems. This converter provides a multilevel rectifier, a multilevel inverter, and a DC link between the rectifier and the inverter allowing voltage balancing between each of the voltage levels within the multilevel converter. The rectifier is equipped with at least one phase leg and a source input node for each of the phases. The rectifier is further equipped with a plurality of rectifier DC output nodes. The inverter is equipped with at least one phase leg and a load output node for each of the phases. The inverter is further equipped with a plurality of inverter DC input nodes. The DC link is equipped with a plurality of rectifier charging means and a plurality of inverter discharging means. The plurality of rectifier charging means are connected in series with one of the rectifier charging means disposed between and connected in an operable relationship with each adjacent pair of rectifier DC output nodes. The plurality of inverter discharging means are connected in series with one of the inverter discharging means disposed between and connected in an operable relationship with each adjacent pair of inverter DC input nodes. Each of said rectifier DC output nodes are individually electrically connected to the respective inverter DC input nodes. By this means, each of the rectifier DC output nodes and each of the inverter DC input nodes are voltage balanced by the respective charging and discharging of the rectifier charging means and the inverter discharging means.

  19. Charging system and method for multicell storage batteries

    DOE Patents [OSTI]

    Cox, Jay A.

    1978-01-01

    A battery-charging system includes a first charging circuit connected in series with a plurality of battery cells for controlled current charging. A second charging circuit applies a controlled voltage across each individual cell for equalization of the cells to the fully charged condition. This controlled voltage is determined at a level above the fully charged open-circuit voltage but at a sufficiently low level to prevent corrosion of cell components by electrochemical reaction. In this second circuit for cell equalization, a transformer primary receives closely regulated, square-wave voltage which is coupled to a plurality of equal secondary coil windings. Each secondary winding is connected in parallel to each cell of a series-connected pair of cells through half-wave rectifiers and a shared, intermediate conductor.

  20. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  1. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles |

    Broader source: Energy.gov (indexed) [DOE]

    Systems on Combustion Engines | Department of Energy This poster reports on recent developments, achievements, and capabilities within a virtual environment to predict the dynamic behavior of the Rankine cycle within real driving cycles. p-11_janssens.pdf (168.59 KB) More Documents & Publications Biodiesel Impact on Engine Lubricant Oil Dilution Statistical Analysis of Transient Cycle Test Results in a 40 CFR Part 1065 Engine Dynamometer Test Cell Small-Particle Solar Receiver for

  2. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  3. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  4. Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance Technology available for licensing: Li4Ti5O12 spinel is a promising alternative to graphite electrodes with enhanced conductivity, voltage and energy density. Enhanced stability at lower cost Li4Ti5O12 spinel is a promising alternative to graphite electrodes with enhanced conductivity, voltage and energy density PDF icon LTO_anodes

  5. Battery cell feedthrough apparatus

    DOE Patents [OSTI]

    Kaun, T.D.

    1995-03-14

    A compact, hermetic feedthrough apparatus is described comprising interfitting sleeve portions constructed of chemically-stable materials to permit unique battery designs and increase battery life and performance. 8 figs.

  6. Anodes for Batteries

    SciTech Connect (OSTI)

    Windisch, Charles F.

    2003-01-01

    The purpose of this chapter is to discuss, "constructive corrosion" as it occurs in power generated devices, specifically batteries.

  7. Ultracapacitor/battery electronic interface development. Final report

    SciTech Connect (OSTI)

    King, R.D.; Salasoo, L.; Schwartz, J.; Cardinal, M.

    1998-06-30

    A flexible, highly efficient laboratory proof-of-concept Ultracapacitor/Battery Interface power electronic circuit with associated controls was developed on a cost-shared contract funded by the US Department of Energy (DOE), the New York State Energy Research and Development Authority (NYSERDA), and the General Electric Company (GE). This power electronic interface translates the varying dc voltage on an ultracapacitor with bi-directional power flow to the dc bus of an inverter-supplied ac propulsion system in an electric vehicle application. In a related application, the electronic interface can also be utilized to interface a low-voltage battery to a dc bus of an inverter supplied ac propulsion system. Variations in voltage for these two intended applications occur (1) while extracting energy (discharge) or supplying energy (charge) to an ultracapacitor, and (2) while extracting energy (discharge) or supplying energy (charge) to a low-voltage battery. The control electronics of this interface is designed to be operated as a stand-alone unit acting in response to an external power command. However, the interface unit`s control is not configured to provide any of the vehicle system control functions associated with load leveling or power splitting between the propulsion battery and the ultracapacitor in an electric or hybrid vehicle application. A system study/preliminary design effort established the functional specification of the interface unit, including voltage, current, and power ratings, to meet the program objectives and technical goals for the development of a highly efficient ultracapacitor/battery electronic interface unit; and performed a system/application study of a hybrid-electric transit bus including an ultracapacitor and appropriate electronic interface. The maximum power capability of the ultracapacitor/battery electronic interface unit is 25 kW.

  8. High voltage DC power supply

    DOE Patents [OSTI]

    Droege, Thomas F.

    1989-01-01

    A high voltage DC power supply having a first series resistor at the output for limiting current in the event of a short-circuited output, a second series resistor for sensing the magnitude of output current, and a voltage divider circuit for providing a source of feedback voltage for use in voltage regulation is disclosed. The voltage divider circuit is coupled to the second series resistor so as to compensate the feedback voltage for a voltage drop across the first series resistor. The power supply also includes a pulse-width modulated control circuit, having dual clock signals, which is responsive to both the feedback voltage and a command voltage, and also includes voltage and current measuring circuits responsive to the feedback voltage and the voltage developed across the second series resistor respectively.

  9. High voltage DC power supply

    DOE Patents [OSTI]

    Droege, T.F.

    1989-12-19

    A high voltage DC power supply having a first series resistor at the output for limiting current in the event of a short-circuited output, a second series resistor for sensing the magnitude of output current, and a voltage divider circuit for providing a source of feedback voltage for use in voltage regulation is disclosed. The voltage divider circuit is coupled to the second series resistor so as to compensate the feedback voltage for a voltage drop across the first series resistor. The power supply also includes a pulse-width modulated control circuit, having dual clock signals, which is responsive to both the feedback voltage and a command voltage, and also includes voltage and current measuring circuits responsive to the feedback voltage and the voltage developed across the second series resistor respectively. 7 figs.

  10. Second use of transportation batteries: Maximizing the value of batteries for transportation and grid services

    SciTech Connect (OSTI)

    Viswanathan, Vilayanur V.; Kintner-Meyer, Michael CW

    2010-09-30

    Plug-in hybrid electric vehicles (PHEVs) and electric vehicles (EVs) are expected to gain significant market share over the next decade. The economic viability for such vehicles is contingent upon the availability of cost-effective batteries with high power and energy density. For initial commercial success, government subsidies will be highly instrumental in allowing PHEVs to gain a foothold. However, in the long-term, for electric vehicles to be commercially viable, the economics have to be self-sustaining. Towards the end of battery life in the vehicle, the energy capacity left in the battery is not sufficient to provide the designed range for the vehicle. Typically, the automotive manufacturers indicated the need for battery replacement when the remaining energy capacity reaches 70-80%. There is still sufficient power (kW) and energy capacity (kWh) left in the battery to support various grid ancillary services such as balancing, spinning reserve, load following services. As renewable energy penetration increases, the need for such balancing services is expected to increase. This work explores optimality for the replacement of transportation batteries to be subsequently used for grid services. This analysis maximizes the value of an electric vehicle battery to be used as a transportation battery (in its first life) and then as a resource for providing grid services (in its second life). The results are presented across a range of key parameters, such as depth of discharge (DOD), number of batteries used over the life of the vehicle, battery life in vehicle, battery state of health (SOH) at end of life in vehicle and ancillary services rate. The results provide valuable insights for the automotive industry into maximizing the utility and the value of the vehicle batteries in an effort to either reduce the selling price of EVs and PHEVs or maximize the profitability of the emerging electrification of transportation.

  11. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Topouzian, Armenag

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which a flexible diaphragm sealing elements respectively engage opposite sides of a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  12. Battery Technology Life Verification Testing and Analysis

    SciTech Connect (OSTI)

    Jon P. Christophersen; Gary L. Hunt; Ira Bloom; Ed Thomas; Vince Battaglia

    2007-12-01

    A critical component to the successful commercialization of batteries for automotive applications is accurate life prediction. The Technology Life Verification Test (TLVT) Manual was developed to project battery life with a high level of statistical confidence within only one or two years of accelerated aging. The validation effort that is presently underway has led to several improvements to the original methodology. For example, a newly developed reference performance test revealed a voltage path dependence effect on resistance for lithium-ion cells. The resistance growth seems to depend on how a target condition is reached (i.e., by a charge or a discharge). Second, the methodology for assessing the level of measurement uncertainty was improved using a propagation of errors in the fundamental measurements to the derived response (e.g., resistance). This new approach provides a more realistic assessment of measurement uncertainty. Third, the methodology for allocating batteries to the test matrix has been improved. The new methodology was developed to assign batteries to the matrix such that the average of each test group would be representative of the overall population. These changes to the TLVT methodology will help to more accurately predict a battery technology’s life capability with a high degree of confidence.

  13. Spinel compounds as multivalent battery cathodes: A systematic evaluation based on ab initio calculations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Miao; Rong, Ziqin; Malik, Rahul; Canepa, Pieremanuele; Jain, Anubhav; Ceder, Gerbrand; Persson, Kristin A.

    2014-12-16

    In this study, batteries that shuttle multivalent ions such as Mg2+ and Ca2+ ions are promising candidates for achieving higher energy density than available with current Li-ion technology. Finding electrode materials that reversibly store and release these multivalent cations is considered a major challenge for enabling such multivalent battery technology. In this paper, we use recent advances in high-throughput first-principles calculations to systematically evaluate the performance of compounds with the spinel structure as multivalent intercalation cathode materials, spanning a matrix of five different intercalating ions and seven transition metal redox active cations. We estimate the insertion voltage, capacity, thermodynamic stabilitymore » of charged and discharged states, as well as the intercalating ion mobility and use these properties to evaluate promising directions. Our calculations indicate that the Mn2O4 spinel phase based on Mg and Ca are feasible cathode materials. In general, we find that multivalent cathodes exhibit lower voltages compared to Li cathodes; the voltages of Ca spinels are ~0.2 V higher than those of Mg compounds (versus their corresponding metals), and the voltages of Mg compounds are ~1.4 V higher than Zn compounds; consequently, Ca and Mg spinels exhibit the highest energy densities amongst all the multivalent cation species. The activation barrier for the Al³⁺ ion migration in the Mn₂O₄ spinel is very high (~1400 meV for Al3+ in the dilute limit); thus, the use of an Al based Mn spinel intercalation cathode is unlikely. Amongst the choice of transition metals, Mn-based spinel structures rank highest when balancing all the considered properties.« less

  14. AGM Batteries Ltd | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: AGM Batteries Ltd Place: United Kingdom Product: Manufactures lithium-ion cells and batteries for AEA Battery Systems Ltd. References: AGM Batteries Ltd1...

  15. High voltage pulse generator

    DOE Patents [OSTI]

    Fasching, George E.

    1977-03-08

    An improved high-voltage pulse generator has been provided which is especially useful in ultrasonic testing of rock core samples. An N number of capacitors are charged in parallel to V volts and at the proper instance are coupled in series to produce a high-voltage pulse of N times V volts. Rapid switching of the capacitors from the paralleled charging configuration to the series discharging configuration is accomplished by using silicon-controlled rectifiers which are chain self-triggered following the initial triggering of a first one of the rectifiers connected between the first and second of the plurality of charging capacitors. A timing and triggering circuit is provided to properly synchronize triggering pulses to the first SCR at a time when the charging voltage is not being applied to the parallel-connected charging capacitors. Alternate circuits are provided for controlling the application of the charging voltage from a charging circuit to be applied to the parallel capacitors which provides a selection of at least two different intervals in which the charging voltage is turned "off" to allow the SCR's connecting the capacitors in series to turn "off" before recharging begins. The high-voltage pulse-generating circuit including the N capacitors and corresponding SCR's which connect the capacitors in series when triggered "on" further includes diodes and series-connected inductors between the parallel-connected charging capacitors which allow sufficiently fast charging of the capacitors for a high pulse repetition rate and yet allow considerable control of the decay time of the high-voltage pulses from the pulse-generating circuit.

  16. Batteries and energy systems

    SciTech Connect (OSTI)

    Mantell, C.L.

    1982-01-01

    A historical review of the galvanic concept and a brief description of the theory of operation of batteries are followed by chapters on specific types of batteries and energy systems. Chapters contain a section on basic theory, performance and applications. Secondary cells discussed are: SLI batteries, lead-acid storage batteries, lead secondary cells, alkaline secondary cells, nickel and silver-cadmium systems and solid electrolyte systems. Other chapters discuss battery charging, regenerative electrochemical systems, solar cells, fuel cells, electric vehicles and windmills. (KAW)

  17. Nanoscale Morphological and Chemical Changes of High Voltage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium-Manganese Rich NMC Composite Cathodes with Cycling | Stanford Synchrotron Radiation Lightsource Nanoscale Morphological and Chemical Changes of High Voltage Lithium-Manganese Rich NMC Composite Cathodes with Cycling Friday, August 29, 2014 Renewable energy is critical for the future of humankind. One bottleneck is energy storage because the harvest and consumption of energy are typically separated in time and/or location. Hence, efficient, low-cost, safe and durable batteries are

  18. Small Electric Voltage Alters Conductivity in Key Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electric Voltage Alters Conductivity in Key Materials - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste

  19. Marine High Voltage Power Conditioning and Transmission System with Integrated Storage DE-EE0003640 Final Report

    SciTech Connect (OSTI)

    Frank Hoffmann, PhD; Aspinall, Rik

    2012-12-10

    Design, Development, and test of the three-port power converter for marine hydrokinetic power transmission. Converter provides ports for AC/DC conversion of hydrokinetic power, battery storage, and a low voltage to high voltage DC port for HVDC transmission to shore. The report covers the design, development, implementation, and testing of a prototype built by PPS.

  20. Spinel Compounds as Multivalent Battery Cathodes: A Systematic Evaluation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Based on ab initio Calculations - Joint Center for Energy Storage Research December 16, 2014, Research Highlights Spinel Compounds as Multivalent Battery Cathodes: A Systematic Evaluation Based on ab initio Calculations Evaluation of multivalent spinel compounds based on multiple performance characteristics such as voltage, specific energy, thermodynamic stability, thermal stability and intercalant mobility. The favorable (unfavorable) properties are represented with light (dark) color

  1. Finger wear detection for production line battery tester

    DOE Patents [OSTI]

    Depiante, E.V.

    1997-11-18

    A method is described for detecting wear in a battery tester probe. The method includes providing a battery tester unit having at least one tester finger, generating a tester signal using the tester fingers and battery tester unit with the signal characteristic of the electrochemical condition of the battery and the tester finger, applying wavelet transformation to the tester signal including computing a mother wavelet to produce finger wear indicator signals, analyzing the signals to create a finger wear index, comparing the wear index for the tester finger with the index for a new tester finger and generating a tester finger signal change signal to indicate achieving a threshold wear change. 9 figs.

  2. Finger wear detection for production line battery tester

    DOE Patents [OSTI]

    Depiante, Eduardo V.

    1997-01-01

    A method for detecting wear in a battery tester probe. The method includes providing a battery tester unit having at least one tester finger, generating a tester signal using the tester fingers and battery tester unit with the signal characteristic of the electrochemical condition of the battery and the tester finger, applying wavelet transformation to the tester signal including computing a mother wavelet to produce finger wear indicator signals, analyzing the signals to create a finger wear index, comparing the wear index for the tester finger with the index for a new tester finger and generating a tester finger signal change signal to indicate achieving a threshold wear change.

  3. Monitoring electrolyte concentrations in redox flow battery systems

    SciTech Connect (OSTI)

    Chang, On Kok; Sopchak, David Andrew; Pham, Ai Quoc; Kinoshita, Kimio

    2015-03-17

    Methods, systems and structures for monitoring, managing electrolyte concentrations in redox flow batteries are provided by introducing a first quantity of a liquid electrolyte into a first chamber of a test cell and introducing a second quantity of the liquid electrolyte into a second chamber of the test cell. The method further provides for measuring a voltage of the test cell, measuring an elapsed time from the test cell reaching a first voltage until the test cell reaches a second voltage; and determining a degree of imbalance of the liquid electrolyte based on the elapsed time.

  4. High voltage coaxial switch

    DOE Patents [OSTI]

    Rink, John P.

    1983-07-19

    A coaxial high voltage, high current switch having a solid cylindrical cold cathode coaxially surrounded by a thin hollow cylindrical inner electrode and a larger hollow cylindrical outer electrode. A high voltage trigger between the cathode and the inner electrode causes electrons to be emitted from the cathode and flow to the inner electrode preferably through a vacuum. Some of the electrons penetrate the inner electrode and cause a volumetric discharge in the gas (which may be merely air) between the inner and outer electrodes. The discharge provides a low impedance path between a high voltage charge placed on the outer electrode and a load (which may be a high power laser) coupled to the inner electrode. For high repetition rate the gas between the inner and outer electrodes may be continuously exchanged or refreshed under pressure.

  5. High voltage coaxial switch

    DOE Patents [OSTI]

    Rink, J.P.

    1983-07-19

    A coaxial high voltage, high current switch having a solid cylindrical cold cathode coaxially surrounded by a thin hollow cylindrical inner electrode and a larger hollow cylindrical outer electrode. A high voltage trigger between the cathode and the inner electrode causes electrons to be emitted from the cathode and flow to the inner electrode preferably through a vacuum. Some of the electrons penetrate the inner electrode and cause a volumetric discharge in the gas (which may be merely air) between the inner and outer electrodes. The discharge provides a low impedance path between a high voltage charge placed on the outer electrode and a load (which may be a high power laser) coupled to the inner electrode. For high repetition rate the gas between the inner and outer electrodes may be continuously exchanged or refreshed under pressure. 3 figs.

  6. Electron launching voltage monitor

    DOE Patents [OSTI]

    Mendel, C.W.; Savage, M.E.

    1992-03-17

    An electron launching voltage monitor measures MITL voltage using a relationship between anode electric field and electron current launched from a cathode-mounted perturbation. An electron launching probe extends through and is spaced from the edge of an opening in a first MITL conductor, one end of the launching probe being in the gap between the MITL conductor, the other end being adjacent a first side of the first conductor away from the second conductor. A housing surrounds the launching probe and electrically connects the first side of the first conductor to the other end of the launching probe. A detector detects the current passing through the housing to the launching probe, the detected current being representative of the voltage between the conductors. 5 figs.

  7. Electron launching voltage monitor

    DOE Patents [OSTI]

    Mendel, Clifford W.; Savage, Mark E.

    1992-01-01

    An electron launching voltage monitor measures MITL voltage using a relationship between anode electric field and electron current launched from a cathode-mounted perturbation. An electron launching probe extends through and is spaced from the edge of an opening in a first MITL conductor, one end of the launching probe being in the gap between the MITL conductor, the other end being adjacent a first side of the first conductor away from the second conductor. A housing surrounds the launching probe and electrically connects the first side of the first conductor to the other end of the launching probe. A detector detects the current passing through the housing to the launching probe, the detected current being representative of the voltage between the conductors.

  8. Voltage controlled current source

    DOE Patents [OSTI]

    Casne, Gregory M.

    1992-01-01

    A seven decade, voltage controlled current source is described for use in testing intermediate range nuclear instruments that covers the entire test current range of from 10 picoamperes to 100 microamperes. High accuracy is obtained throughout the entire seven decades of output current with circuitry that includes a coordinated switching scheme responsive to the input signal from a hybrid computer to control the input voltage to an antilog amplifier, and to selectively connect a resistance to the antilog amplifier output to provide a continuous output current source as a function of a preset range of input voltage. An operator controlled switch provides current adjustment for operation in either a real-time simulation test mode or a time response test mode.

  9. High voltage variable diameter insulator

    DOE Patents [OSTI]

    Vanacek, D.L.; Pike, C.D.

    1982-07-13

    A high voltage feedthrough assembly having a tubular insulator extending between the ground plane ring and the high voltage ring. The insulator is made of Pyrex and decreases in diameter from the ground plane ring to the high voltage ring, producing equipotential lines almost perpendicular to the wall of the insulator to optimize the voltage-holding capability of the feedthrough assembly.

  10. Standard Missile Block IV battery

    SciTech Connect (OSTI)

    Martin, J.

    1996-11-01

    During the 1980`s a trend in automatic primary battery technologies was the replacement of silver-zinc batteries by thermal battery designs. The Standard missile (SM 2) Block IV development is a noteworthy reversal of this trend. The SM2, Block IV battery was originally attempted as a thermal battery with multiple companies attempting to develop a thermal battery design. These attempts resulted in failure to obtain a production thermal battery. A decision to pursue a silver-zinc battery design resulted in the development of a battery to supply the SM 2, Block IV (thermal battery design goal) and also the projected power requirements of the evolving SM 2, Block IVA in a single silver-zinc battery design. Several advancements in silver-zinc battery technology were utilized in this design that improve the producibility and extend the boundaries of silver-zinc batteries.

  11. High voltage bus and auxiliary heater control system for an electric or hybrid vehicle

    DOE Patents [OSTI]

    Murty, Balarama Vempaty

    2000-01-01

    A control system for an electric or hybrid electric vehicle includes a vehicle system controller and a control circuit having an electric immersion heater. The heater is electrically connected to the vehicle's high voltage bus and is thermally coupled to a coolant loop containing a heater core for the vehicle's climate control system. The system controller responds to cabin heat requests from the climate control system by generating a pulse width modulated signal that is used by the control circuit to operate the heater at a duty cycle appropriate for the amount of cabin heating requested. The control system also uses the heater to dissipate excess energy produced by an auxiliary power unit and to provide electric braking when regenerative braking is not desirable and manual braking is not necessary. The control system further utilizes the heater to provide a safe discharge of a bank of energy storage capacitors following disconnection of the battery or one of the high voltage connectors used to transmit high voltage operating power to the various vehicle systems. The control circuit includes a high voltage clamping circuit that monitors the voltage on the bus and operates the heater to clamp down the bus voltage when it exceeds a pre-selected maximum voltage. The control system can also be used to phase in operation of the heater when the bus voltage exceeds a lower threshold voltage and can be used to phase out the auxiliary power unit charging and regenerative braking when the battery becomes fully charged.

  12. Multicomponent phase diagrams for battery applications. II. Oxygen impurities in the Li(Si)/FeS/sub 2/ battery cathode

    SciTech Connect (OSTI)

    Aselage, T.L.; Hellstrom, E.E.

    1987-08-01

    The effect on the voltage response of the Li(Si)/FeS/sub 2/ thermal battery due to Fe/sub 2/O/sub 3/, FeSO/sub 4/, and Fe/sub 2/(SO/sub 4/)/sub 3/ impurities in the FeS/sub 2/ cathode has been studied. Calculations were made of the pertinent equilibrium phase relations in the Li-Fe-S-O system at 400/sup 0/C, and of the voltage of each of the four-phase regions vs. a Li(Si) anode (44 weight percent Li). The calculations showed that these impurities in the FeS/sub 2/ cathode can all cause voltages that are higher than the steady-state voltage of the battery. The study showed that equilibrating FeS/sub 2/ cathode material that contains oxygen impurities with a small amount of a compound containing Li shifts the overall cathode composition into one of three four-phase regions that exhibits the steady-state battery voltage.

  13. High Energy Batteries for Hybrid Buses

    SciTech Connect (OSTI)

    Bruce Lu

    2010-12-31

    EnerDel batteries have already been employed successfully for electric vehicle (EV) applications. Compared to EV applications, hybrid electric vehicle (HEV) bus applications may be less stressful, but are still quite demanding, especially compared to battery applications for consumer products. This program evaluated EnerDel cell and pack system technologies with three different chemistries using real world HEV-Bus drive cycles recorded in three markets covering cold, hot, and mild climates. Cells were designed, developed, and fabricated using each of the following three chemistries: (1) Lithium nickel manganese cobalt oxide (NMC) - hard carbon (HC); (2) Lithium manganese oxide (LMO) - HC; and (3) LMO - lithium titanium oxide (LTO) cells. For each cell chemistry, battery pack systems integrated with an EnerDel battery management system (BMS) were successfully constructed with the following features: real time current monitoring, cell and pack voltage monitoring, cell and pack temperature monitoring, pack state of charge (SOC) reporting, cell balancing, and over voltage protection. These features are all necessary functions for real-world HEV-Bus applications. Drive cycle test data was collected for each of the three cell chemistries using real world drive profiles under hot, mild, and cold climate conditions representing cities like Houston, Seattle, and Minneapolis, respectively. We successfully tested the battery packs using real-world HEV-Bus drive profiles under these various climate conditions. The NMC-HC and LMO-HC based packs successfully completed the drive cycles, while the LMO-LTO based pack did not finish the preliminary testing for the drive cycles. It was concluded that the LMO-HC chemistry is optimal for the hot or mild climates, while the NMC-HC chemistry is optimal for the cold climate. In summary, the objectives were successfully accomplished at the conclusion of the project. This program provided technical data to DOE and the public for assessing

  14. Polyoxometalate flow battery

    DOE Patents [OSTI]

    Anderson, Travis M.; Pratt, Harry D.

    2016-03-15

    Flow batteries including an electrolyte of a polyoxometalate material are disclosed herein. In a general embodiment, the flow battery includes an electrochemical cell including an anode portion, a cathode portion and a separator disposed between the anode portion and the cathode portion. Each of the anode portion and the cathode portion comprises a polyoxometalate material. The flow battery further includes an anode electrode disposed in the anode portion and a cathode electrode disposed in the cathode portion.

  15. Battery utilizing ceramic membranes

    DOE Patents [OSTI]

    Yahnke, Mark S.; Shlomo, Golan; Anderson, Marc A.

    1994-01-01

    A thin film battery is disclosed based on the use of ceramic membrane technology. The battery includes a pair of conductive collectors on which the materials for the anode and the cathode may be spin coated. The separator is formed of a porous metal oxide ceramic membrane impregnated with electrolyte so that electrical separation is maintained while ion mobility is also maintained. The entire battery can be made less than 10 microns thick while generating a potential in the 1 volt range.

  16. Lithium battery management system

    DOE Patents [OSTI]

    Dougherty, Thomas J.

    2012-05-08

    Provided is a system for managing a lithium battery system having a plurality of cells. The battery system comprises a variable-resistance element electrically connected to a cell and located proximate a portion of the cell; and a device for determining, utilizing the variable-resistance element, whether the temperature of the cell has exceeded a predetermined threshold. A method of managing the temperature of a lithium battery system is also included.

  17. GBP Battery | Open Energy Information

    Open Energy Info (EERE)

    GBP Battery Jump to: navigation, search Name: GBP Battery Place: China Product: Shenzhen-China-based maker of Li-Poly and Li-ion batteries suitable for EVs and other applications....

  18. Rechargeable Heat Battery's Secret Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rechargeable Heat Battery Rechargeable Heat Battery's Secret Revealed Solar energy capture ... Contact: John Hules, JAHules@lbl.gov, +1 510 486 6008 2011-01-11-Heat-Battery.jpg A ...

  19. Battery availability for near-term (1998) electric vehicles

    SciTech Connect (OSTI)

    Burke, A.F.

    1991-06-01

    Battery Requirements were determined for a wide spectrum of electric vehicles ranging from 2-passenger sports cars and microvans to full-size vans with a payload of 500 kg. All the vehicles utilize ac, high voltage (340--360 V) powertrains and have acceleration performance (0--80 km/h in less than 15 seconds) expected to be the norm in 1988 electric vehicles. Battery packs were configured for each of the vehicles using families of sealed lead-acid and nickel-cadmium modules which are either presently available in limited quantities or are being developed by battery companies which market a similar battery technology. It was found that the battery families available encompass the Ah cell sizes required for the various vehicles and that they could be packaged in the space available in each vehicle. The acceleration performance and range of the vehicles were calculated using the SIMPLEV simulation program. The results showed that all the vehicles had the required acceleration characteristics and ranges between 80--160 km (50--100 miles) with the ranges using nickel-cadmium batteries being 40--60% greater than those using lead-acid batteries. Significant changes in the design of electric vehicles over the last fifteen years are noted. These changes make the design of the batteries more difficult by increasing the peak power density required from about 60 W/kg to 100--150 W/kg and by reducing the Ah cell size needed from about 150 Ah to 30--70 Ah. Both of these changes in battery specifications increase the difficulty of achieving low $/kWh cost and long cycle life. This true for both lead-acid and nickel-cadmium batteries. 25 refs., 6 figs., 16 tabs.

  20. Battery Thermal Characterization

    SciTech Connect (OSTI)

    Saxon, Aron; Powell, Mitchell; Shi, Ying

    2015-06-09

    This presentation provides an update of NREL's battery thermal characterization efforts for the 2015 U.S. Department of Energy Annual Merit Reviews.

  1. Ambient temperature thermal battery

    SciTech Connect (OSTI)

    Fletcher, A. N.; Bliss, D. E.; McManis III

    1985-11-26

    An ambient temperature thermal battery having two relatively high temperature melting electrolytes which form a low melting temperature electrolyte upon activation.

  2. Sodium/nickel-chloride battery development

    SciTech Connect (OSTI)

    Redey, L.; Prakash, J.; Vissers, D.R.; Dowgiallo, E.J.

    1994-02-28

    The performance of the Ni/NiCl{sub 2} positive electrode for the Na/NiCl{sub 2} battery has been significantly improved compared to that of our earlier electrodes, representative for 1990. This improvement has been achieved by lowering the impedance and increasing the usable capacity through the use of chemical additives and a tailored electrode morphology. The improved electrode has excellent performance even at 250{degrees}C and can be recharged within one hour. The performance of this new electrode was measured by the conventional interrupted galvanostatic method and under simulated driving profiles. These measurements were used to project the performance of 40- to 60-kWh batteries built with this new electrode combined with the already highly developed sodium/{beta}{double_prime}-alumina negative electrode. These calculated results yielded a specific power of 150--400 W/kg and a specific energy of 110--200 Wh/kg for batteries with single-tube and bipolar cell designs. This high performance, along with the high cell voltage, mid-temperature operation, fast recharge capability, and short-circuited failure mode of the electrode couple, makes the Na/NiCl{sub 2} battery attractive for electric vehicle applications.

  3. Rechargeable Thin-film Lithium Batteries

    DOE R&D Accomplishments [OSTI]

    Bates, J. B.; Gruzalski, G. R.; Dudney, N. J.; Luck, C. F.; Yu, Xiaohua

    1993-08-01

    Rechargeable thin film batteries consisting of lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have recently been developed. The batteries, which are typically less than 6 {mu}m thick, can be fabricated to any specified size, large or small, onto a variety of substrates including ceramics, semiconductors, and plastics. The cells that have been investigated include Li TiS{sub 2}, Li V{sub 2}O{sub 5}, and Li Li{sub x}Mn{sub 2}O{sub 4}, with open circuit voltages at full charge of about 2.5, 3.6, and 4.2, respectively. The development of these batteries would not have been possible without the discovery of a new thin film lithium electrolyte, lithium phosphorus oxynitride, that is stable in contact with metallic lithium at these potentials. Deposited by rf magnetron sputtering of Li{sub 3}PO{sub 4} in N{sub 2}, this material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46} and a conductivity at 25{degrees}C of 2 {mu}S/cm. The maximum practical current density obtained from the thin film cells is limited to about 100 {mu}A/cm{sup 2} due to a low diffusivity of Li{sup +} ions in the cathodes. In this work, the authors present a short review of their work on rechargeable thin film lithium batteries.

  4. ESR melting under constant voltage conditions

    SciTech Connect (OSTI)

    Schlienger, M.E.

    1997-02-01

    Typical industrial ESR melting practice includes operation at a constant current. This constant current operation is achieved through the use of a power supply whose output provides this constant current characteristic. Analysis of this melting mode indicates that the ESR process under conditions of constant current is inherently unstable. Analysis also indicates that ESR melting under the condition of a constant applied voltage yields a process which is inherently stable. This paper reviews the process stability arguments for both constant current and constant voltage operation. Explanations are given as to why there is a difference between the two modes of operation. Finally, constant voltage process considerations such as melt rate control, response to electrode anomalies and impact on solidification will be discussed.

  5. Battery SEAB Presentation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battery SEAB Presentation Battery SEAB Presentation Battery SEAB Presentation (1.43 MB) More Documents & Publications Overview of Battery R&D Activities Hybrid Electric Systems Overview of Battery R&D Activities

  6. Utility Battery Storage Systems Program plan: FY 1994--FY 1998

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    The Utility Battery Storage Systems Program, sponsored by the US Department of Energy (DOE), is addressing needed improvements so that the full benefits of these systems can be realized. A key element of the Program is the quantification of the benefits of batteries used in utility applications. The analyses of the applications and benefits are ongoing, but preliminary results indicate that the widespread introduction of battery storage by utilities could benefit the US economy by more than $26 billion by 2010 and create thousands of new jobs. Other critical elements of the DOE Program focus on improving the batteries, power electronics, and control subsystems and reducing their costs. These subsystems are then integrated and the systems undergo field evaluation. Finally, the most important element of the Program is the communication of the capabilities and benefits of battery systems to utility companies. Justifiably conservative, utilities must have proven, reliable equipment that is economical before they can adopt new technologies. While several utilities are leading the industry by demonstrating battery systems, a key task of the DOE program is to inform the entire industry of the value, characteristics, and availability of utility battery systems so that knowledgeable decisions can be made regarding future investments. This program plan for the DOE Utility Battery Storage Systems Program describes the technical and programmatic activities needed to bring about the widespread use of batteries by utilities. By following this plan, the DOE anticipates that many of the significant national benefits from battery storage will be achieved in the near future.

  7. Phylion Battery | Open Energy Information

    Open Energy Info (EERE)

    Phylion Battery Jump to: navigation, search Name: Phylion Battery Place: Suzhou, Jiangsu Province, China Zip: 215011 Sector: Vehicles Product: Jiangsu-province-based producer of...

  8. Battery Ventures | Open Energy Information

    Open Energy Info (EERE)

    Battery Ventures (Boston) Name: Battery Ventures (Boston) Address: 930 Winter Street, Suite 2500 Place: Waltham, Massachusetts Zip: 02451 Region: Greater Boston Area Product:...

  9. Prieto Battery | Open Energy Information

    Open Energy Info (EERE)

    Colorado Zip: 80526 Product: Colorado-based startup company that is developing lithium ion batteries based on nano-structured materials. References: Prieto Battery1 This...

  10. Consortium for Advanced Battery Simulation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battery Simulation - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us ... Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel ...

  11. HIGH VOLTAGE GENERATOR

    DOE Patents [OSTI]

    Schwemin, A.J.

    1959-03-17

    A generator is presented for producing relatively large currents at high voltages. In general, the invention comprises a plurality of capacitors connected in series by a plurality of switches alternately disposed with the capacitors. The circuit is mounted for movement with respect to contact members and switch closure means so that a load device and power supply are connected across successive numbers of capacitors, while the other capacitors are successively charged with the same power supply.

  12. High Voltage Connector

    SciTech Connect (OSTI)

    Kurita, C.H.; /Fermilab

    1987-03-06

    The originally designed high voltage connectors were to be made of brass. However, if treated like a Bellevile spring with the initially given dimensions, the stresses of the connector when crimped were calculated to be much higher than the yield stress of brass. Since the flange and outer diameters of the connector are to remain small, it was necessary to alter the other dimensions and choice of material in order to bring down the stresses applied to the connector.

  13. High voltage pulse conditioning

    DOE Patents [OSTI]

    Springfield, Ray M.; Wheat, Jr., Robert M.

    1990-01-01

    Apparatus for conditioning high voltage pulses from particle accelerators in order to shorten the rise times of the pulses. Flashover switches in the cathode stalk of the transmission line hold off conduction for a determinable period of time, reflecting the early portion of the pulses. Diodes upstream of the switches divert energy into the magnetic and electrostatic storage of the capacitance and inductance inherent to the transmission line until the switches close.

  14. HIGH VOLTAGE ION SOURCE

    DOE Patents [OSTI]

    Luce, J.S.

    1960-04-19

    A device is described for providing a source of molecular ions having a large output current and with an accelerated energy of the order of 600 kv. Ions are produced in an ion source which is provided with a water-cooled source grid of metal to effect maximum recombination of atomic ions to molecular ions. A very high accelerating voltage is applied to withdraw and accelerate the molecular ions from the source, and means are provided for dumping the excess electrons at the lowest possible potentials. An accelerating grid is placed adjacent to the source grid and a slotted, grounded accelerating electrode is placed adjacent to the accelerating grid. A potential of about 35 kv is maintained between the source grid and accelerating grid, and a potential of about 600 kv is maintained between the accelerating grid and accelerating electrode. In order to keep at a minimum the large number of oscillating electrons which are created when such high voltages are employed in the vicinity of a strong magnetic field, a plurality of high voltage cascaded shields are employed with a conventional electron dumping system being employed between each shield so as to dump the electrons at the lowest possible potential rather than at 600 kv.

  15. A smart control system for electric vehicle batteries

    SciTech Connect (OSTI)

    Arikara, M.P.; Dickinson, B.E.; Branum, B.

    1993-12-31

    A smart control system for electric vehicle (EV) batteries was designed and its performance was evaluated. The hardware for the system was based on the Motorola MC68HC11ENB micro controller. A zinc bromide (Zn/Br{sub 2}) battery was chosen since it is a good candidate as an EV battery and has a large number of user variable parameters that affect its performance. The flexibility of the system arises from the fact that the system can be programmed to do a wide variety of jobs. The use of real time interrupts and other features makes the system safe for use along with the battery systems. Test data indicates that real time control of the different parameters can increase the performance of the battery by 15%. In addition to optimizing the performance of the battery the control system incorporates essential safety features.

  16. APPARATUS FOR REGULATING HIGH VOLTAGE

    DOE Patents [OSTI]

    Morrison, K.G.

    1951-03-20

    This patent describes a high-voltage regulator of the r-f type wherein the modulation of the r-f voltage is accomplished at a high level, resulting in good stabilization over a large range of load conditions.

  17. Battery separator assembly

    SciTech Connect (OSTI)

    Faust, M.A.; Suchanski, M.R.; Osterhoudt, H.W.

    1988-05-03

    A separator assembly for use in batteries is described comprising a film bearing a thermal fuse in the form of a layer of wax coated fibers; wherein the assembly is sufficiently porous to allow continuous flow of ions in the battery.

  18. Battery Particle Simulation

    SciTech Connect (OSTI)

    2014-09-15

    Two simulations show the differences between a battery being drained at a slower rate, over a full hour, versus a faster rate, only six minutes (a tenth of an hour). In both cases battery particles go from being fully charged (green) to fully drained (red), but there are significant differences in the patterns of discharge based on the rate.

  19. High voltage variable diameter insulator

    DOE Patents [OSTI]

    Vanecek, David L.; Pike, Chester D.

    1984-01-01

    A high voltage feedthrough assembly (10) having a tubular insulator (15) extending between the ground plane ring (16) and the high voltage ring (30). The insulator (15) is made of Pyrex and decreases in diameter from the ground plane ring (16) to the high voltage ring (30), producing equipotential lines almost perpendicular to the wall (27) of the insulator (15) to optimize the voltage-holding capability of the feedthrough assembly (10).

  20. Charge-pump voltage converter

    DOE Patents [OSTI]

    Brainard, John P.; Christenson, Todd R.

    2009-11-03

    A charge-pump voltage converter for converting a low voltage provided by a low-voltage source to a higher voltage. Charge is inductively generated on a transfer rotor electrode during its transit past an inductor stator electrode and subsequently transferred by the rotating rotor to a collector stator electrode for storage or use. Repetition of the charge transfer process leads to a build-up of voltage on a charge-receiving device. Connection of multiple charge-pump voltage converters in series can generate higher voltages, and connection of multiple charge-pump voltage converters in parallel can generate higher currents. Microelectromechanical (MEMS) embodiments of this invention provide a small and compact high-voltage (several hundred V) voltage source starting with a few-V initial voltage source. The microscale size of many embodiments of this invention make it ideally suited for MEMS- and other micro-applications where integration of the voltage or charge source in a small package is highly desirable.

  1. Spinel compounds as multivalent battery cathodes: A systematic evaluation based on ab initio calculations

    SciTech Connect (OSTI)

    Liu, Miao; Rong, Ziqin; Malik, Rahul; Canepa, Pieremanuele; Jain, Anubhav; Ceder, Gerbrand; Persson, Kristin A.

    2014-12-16

    In this study, batteries that shuttle multivalent ions such as Mg2+ and Ca2+ ions are promising candidates for achieving higher energy density than available with current Li-ion technology. Finding electrode materials that reversibly store and release these multivalent cations is considered a major challenge for enabling such multivalent battery technology. In this paper, we use recent advances in high-throughput first-principles calculations to systematically evaluate the performance of compounds with the spinel structure as multivalent intercalation cathode materials, spanning a matrix of five different intercalating ions and seven transition metal redox active cations. We estimate the insertion voltage, capacity, thermodynamic stability of charged and discharged states, as well as the intercalating ion mobility and use these properties to evaluate promising directions. Our calculations indicate that the Mn2O4 spinel phase based on Mg and Ca are feasible cathode materials. In general, we find that multivalent cathodes exhibit lower voltages compared to Li cathodes; the voltages of Ca spinels are ~0.2 V higher than those of Mg compounds (versus their corresponding metals), and the voltages of Mg compounds are ~1.4 V higher than Zn compounds; consequently, Ca and Mg spinels exhibit the highest energy densities amongst all the multivalent cation species. The activation barrier for the Al³⁺ ion migration in the Mn₂O₄ spinel is very high (~1400 meV for Al3+ in the dilute limit); thus, the use of an Al based Mn spinel intercalation cathode is unlikely. Amongst the choice of transition metals, Mn-based spinel structures rank highest when balancing all the considered properties.

  2. EV Everywhere Batteries Workshop - Next Generation Lithium Ion Batteries

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Breakout Session Report | Department of Energy Next Generation Lithium Ion Batteries Breakout Session Report EV Everywhere Batteries Workshop - Next Generation Lithium Ion Batteries Breakout Session Report Breakout session presentation for the EV Everywhere Grand Challenge: Battery Workshop on July 26, 2012 held at the Doubletree OHare, Chicago, IL. report_out-next-generation_li-ion_b.pdf (136.48 KB) More Documents & Publications EV Everywhere Batteries Workshop - Beyond Lithium Ion

  3. Polymeric battery separators

    SciTech Connect (OSTI)

    Minchak, R. J.; Schenk, W. N.

    1985-06-11

    Configurations of cross-linked or vulcanized amphophilic or quaternized block copolymer of haloalkyl epoxides and hydroxyl terminated alkadiene polymers are useful as battery separators in both primary and secondary batteries, particularly nickel-zinc batteries. The quaternized block copolymers are prepared by polymerizing a haloalkyl epoxide in the presence of a hydroxyl terminated 1,3-alkadiene to form a block copolymer that is then reacted with an amine to form the quaternized or amphophilic block copolymer that is then cured or cross-linked with sulfur, polyamines, metal oxides, organic peroxides and the like.

  4. Battery utilizing ceramic membranes

    DOE Patents [OSTI]

    Yahnke, M.S.; Shlomo, G.; Anderson, M.A.

    1994-08-30

    A thin film battery is disclosed based on the use of ceramic membrane technology. The battery includes a pair of conductive collectors on which the materials for the anode and the cathode may be spin coated. The separator is formed of a porous metal oxide ceramic membrane impregnated with electrolyte so that electrical separation is maintained while ion mobility is also maintained. The entire battery can be made less than 10 microns thick while generating a potential in the 1 volt range. 2 figs.

  5. BEEST: Electric Vehicle Batteries

    SciTech Connect (OSTI)

    2010-07-01

    BEEST Project: The U.S. spends nearly a $1 billion per day to import petroleum, but we need dramatically better batteries for electric and plug-in hybrid vehicles (EV/PHEV) to truly compete with gasoline-powered cars. The 10 projects in ARPA-E’s BEEST Project, short for “Batteries for Electrical Energy Storage in Transportation,” could make that happen by developing a variety of rechargeable battery technologies that would enable EV/PHEVs to meet or beat the price and performance of gasoline-powered cars, and enable mass production of electric vehicles that people will be excited to drive.

  6. GP Batteries International Limited | Open Energy Information

    Open Energy Info (EERE)

    International Limited is principally engaged in the development, manufacture and marketing of batteries and battery-related products. References: GP Batteries International...

  7. RPM Flywheel Battery | Open Energy Information

    Open Energy Info (EERE)

    RPM Flywheel Battery Jump to: navigation, search Name: RPM Flywheel Battery Place: California Product: Start-up planning to develop, produce, and market flywheel batteries for...

  8. Ford Electric Battery Group | Open Energy Information

    Open Energy Info (EERE)

    Electric Battery Group Jump to: navigation, search Name: Ford Electric Battery Group Place: Dearborn, MI References: Ford Battery1 Information About Partnership with NREL...

  9. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone...

  10. Carbon Micro Battery LLC | Open Energy Information

    Open Energy Info (EERE)

    Micro Battery LLC Jump to: navigation, search Name: Carbon Micro Battery, LLC Place: California Sector: Carbon Product: Carbon Micro Battery, LLC, technology developer of micro and...

  11. Intellect Battery Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Intellect Battery Co Ltd Jump to: navigation, search Name: Intellect Battery Co Ltd Place: Guangdong Province, China Product: Producer of NiMH rechargeable batteries and...

  12. Advanced Battery Factory | Open Energy Information

    Open Energy Info (EERE)

    Battery Factory Place: Shen Zhen City, Guangdong Province, China Product: Producers of lithium polymer batteries, established in 1958. References: Advanced Battery Factory1 This...

  13. Ningbo Veken Battery Company | Open Energy Information

    Open Energy Info (EERE)

    search Name: Ningbo Veken Battery Company Place: China Product: Ningbo-based maker of Lithium polymer, aluminum-shell and lithium power batteries. References: Ningbo Veken Battery...

  14. Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer, Longer-lasting Batteries Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make ...

  15. Hierarchically Structured Materials for Lithium Batteries (Journal...

    Office of Scientific and Technical Information (OSTI)

    Hierarchically Structured Materials for Lithium Batteries Citation Details In-Document Search Title: Hierarchically Structured Materials for Lithium Batteries Lithium-ion battery ...

  16. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone ...

  17. 'Thirsty' Metals Key to Longer Battery Lifetimes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    'Thirsty' Metals Key to Longer Battery Lifetimes 'Thirsty' Metals Key to Longer Battery Lifetimes Computations at NERSC show how multiply charged metal ions impact battery capacity ...

  18. PHEV Battery Cost Assessment | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    es_02_barnett.pdf (615.99 KB) More Documents & Publications PHEV Battery Cost Assessment PHEV Battery Cost Assessment PHEV and LEESS Battery Cost Assessment

  19. Batteries and Energy Storage | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPOTLIGHT Batteries and Energy Storage Argonne's all- encompassing battery research ... We develop more robust, safer and higher-energy density lithium-ion batteries, while using ...

  20. Depletion Aggregation > Batteries & Fuel Cells > Research > The...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries & Fuel Cells In This Section Battery Anodes Battery Cathodes Depletion Aggregation Membranes Depletion Aggregation We are exploring a number of synthetic strategies to ...

  1. NERSC Helps Develop Next-Gen Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NERSC Helps Develop Next-Gen Batteries NERSC Helps Develop Next-Gen Batteries A genomics approach to materials research could speed up advancements in battery performance December ...

  2. Laor Batteries Ltd | Open Energy Information

    Open Energy Info (EERE)

    Laor Batteries Ltd Jump to: navigation, search Name: Laor Batteries Ltd. Place: Upper Nazareth, Israel Zip: 17105 Product: develops and distributes lead-acid batteries for variety...

  3. Aerospatiale Batteries ASB | Open Energy Information

    Open Energy Info (EERE)

    Aerospatiale Batteries ASB Jump to: navigation, search Name: Aerospatiale Batteries (ASB) Place: France Product: Research, design and manufacture of Thermal Batteries. References:...

  4. Optimal charging profiles for mechanically constrained lithium-ion batteries

    SciTech Connect (OSTI)

    Suthar, B; Ramadesigan, V; De, S; Braatz, RD; Subramanian, VR

    2014-01-01

    The cost and safety related issues of lithium-ion batteries require intelligent charging profiles that can efficiently utilize the battery. This paper illustrates the application of dynamic optimization in obtaining the optimal current profile for charging a lithium-ion battery using a single-particle model while incorporating intercalation-induced stress generation. In this paper, we focus on the problem of maximizing the charge stored in a given time while restricting the development of stresses inside the particle. Conventional charging profiles for lithium-ion batteries (e.g., constant current followed by constant voltage) were not derived by considering capacity fade mechanisms. These charging profiles are not only inefficient in terms of lifetime usage of the batteries but are also slower since they do not exploit the changing dynamics of the system. Dynamic optimization based approaches have been used to derive optimal charging and discharging profiles with different objective functions. The progress made in understanding the capacity fade mechanisms has paved the way for inclusion of that knowledge in deriving optimal controls. While past efforts included thermal constraints, this paper for the first time presents strategies for optimally charging batteries by guaranteeing minimal mechanical damage to the electrode particles during intercalation. In addition, an executable form of the code has been developed and provided. This code can be used to identify optimal charging profiles for any material and design parameters.

  5. Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stanford Synchrotron Radiation Lightsource Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes Sunday, January 31, 2016 Improvements in the high-voltage cycling stability of lithium ion battery cathode materials are needed to enable the wide-spread adoption of renewable energy technologies such as electric vehicles. One cathode material which exhibits significant advantages over the commonly-used commercial material LiCoO2 in terms of higher capacity, increased thermal

  6. Parallel flow diffusion battery

    DOE Patents [OSTI]

    Yeh, H.C.; Cheng, Y.S.

    1984-01-01

    A parallel flow diffusion battery for determining the mass distribution of an aerosol has a plurality of diffusion cells mounted in parallel to an aerosol stream, each diffusion cell including a stack of mesh wire screens of different density.

  7. Parallel flow diffusion battery

    DOE Patents [OSTI]

    Yeh, Hsu-Chi; Cheng, Yung-Sung

    1984-08-07

    A parallel flow diffusion battery for determining the mass distribution of an aerosol has a plurality of diffusion cells mounted in parallel to an aerosol stream, each diffusion cell including a stack of mesh wire screens of different density.

  8. Thermal battery degradation mechanisms

    SciTech Connect (OSTI)

    Missert, Nancy A.; Brunke, Lyle Brent

    2015-09-01

    Diffuse reflectance IR spectroscopy (DRIFTS) was used to investigate the effect of accelerated aging on LiSi based anodes in simulated MC3816 batteries. DRIFTS spectra showed that the oxygen, carbonate, hydroxide and sulfur content of the anodes changes with aging times and temperatures, but not in a monotonic fashion that could be correlated to phase evolution. Bands associated with sulfur species were only observed in anodes taken from batteries aged in wet environments, providing further evidence for a reaction pathway facilitated by H2S transport from the cathode, through the separator, to the anode. Loss of battery capacity with accelerated aging in wet environments was correlated to loss of FeS2 in the catholyte pellets, suggesting that the major contribution to battery performance degradation results from loss of active cathode material.

  9. Battery Life Predictive Model

    Energy Science and Technology Software Center (OSTI)

    2009-12-31

    The Software consists of a model used to predict battery capacity fade and resistance growth for arbitrary cycling and temperature profiles. It allows the user to extrapolate from experimental data to predict actual life cycle.

  10. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Mikkor, Mati

    1981-01-01

    This disclosure is directed to an improvement in a sodium sulfur battery construction in which a seal between various battery compartments is made by a structure in which a soft metal seal member is held in a sealing position by holding structure. A pressure applying structure is used to apply pressure on the soft metal seal member when it is being held in sealing relationship to a surface of a container member of the sodium sulfur battery by the holding structure. The improvement comprises including a thin, well-adhered, soft metal layer on the surface of the container member of the sodium sulfur battery to which the soft metal seal member is to be bonded.

  11. High voltage feedthrough bushing

    DOE Patents [OSTI]

    Brucker, John P.

    1993-01-01

    A feedthrough bushing for a high voltage diode provides for using compression sealing for all sealing surfaces. A diode assembly includes a central conductor extending through the bushing and a grading ring assembly circumferentially surrounding and coaxial with the central conductor. A flexible conductive plate extends between and compressively seals against the central conductor and the grading ring assembly, wherein the flexibility of the plate allows inner and outer portions of the plate to axially translate for compression sealing against the central conductor and the grading ring assembly, respectively. The inner portion of the plate is bolted to the central conductor for affecting sealing. A compression beam is also bolted to the central conductor and engages the outer portion of the plate to urge the outer portion toward the grading ring assembly to obtain compression sealing therebetween.

  12. battery2.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6-1982J Solid-State Environmentally Safe Battery for Replacing Lithium Batteries 1. Submitting Organization Sandia National Laboratories PO Box 5800, MS 1033 Albuquerque, NM USA 87158-1033 Randy A. Normann (505) 845-9675, (505) 844-3952 (fax), ranorma@sandia.gov Affi rmation I affi rm that all information submitted as a part of, or supplemental to, this entry is fair and accurate representation of this product. ________________________________________________________________ Submitter Signature

  13. Battery packaging - Technology review

    SciTech Connect (OSTI)

    Maiser, Eric

    2014-06-16

    This paper gives a brief overview of battery packaging concepts, their specific advantages and drawbacks, as well as the importance of packaging for performance and cost. Production processes, scaling and automation are discussed in detail to reveal opportunities for cost reduction. Module standardization as an additional path to drive down cost is introduced. A comparison to electronics and photovoltaics production shows 'lessons learned' in those related industries and how they can accelerate learning curves in battery production.

  14. New processing technique for DEB powder for thermal batteries

    SciTech Connect (OSTI)

    Szwarc, R.; Walton, R.D.

    1980-06-01

    The purpose of this paper is to explore how material processing influences thermal battery performance, and how battery performance can be improved by changes in processing. This discussion is confined to the class of thermal batteries designed by Sandia Laboratories and built under the supervision of General Electric in St. Petersburg, Florida. The electrochemical system employed is: Ca/LiCl-KCl-CaCrO/sub 4//Fe. These batteries are primary reserve batteries which employ a pelletized cell design. Each cell consists of an electrolyte-depolarizer pellet sandwiched between an anode and a heat pellet. The anode employed may be one of two forms: sheet calcium disc, mechanically attached to an iron or steel backing; or a substrate disc of iron or steel on which 3 to 5 mils of calcium had been evaporated. The depolarizer-electrolyte, commonly referred to as DEB, is composed of CaCrO/sub 4/, LiCl-KCl eutectic and SiO/sub 2/ binder powder, which has been blended and pressed into pellets. The DEB pellet serves as electrolyte and as active cathode when the salt becomes molten upon battery activation. The heat pellet serves the dual purpose of providing the heat necessary to activate the battery and as the cathode current collector. The heat pellet is composed of iron powder and KClO/sub 4/. A battery is made up of one or more stacks of about 12 cells connected in series to produce a voltage of 28 to 32 volts. Since activated life requirements for batteries vary from seconds up to one hour, the battery must be well insulated to conserve the heat produced by the ignition of the heat pellets to maintain the electrolyte in a molten state. This insulation is also important to protect sensitive electronic components in contact with the battery case. Because the electrolyte, particularly LiCl, is hygroscopic, the batteries are hermetically sealed in stainless steel cans, and are manufactured in dryrooms maintained at 3% relative humidity or better.

  15. Voltage Vehicles | Open Energy Information

    Open Energy Info (EERE)

    distributor specializing in the full spectrum of electric vehicles (EV) and full-performance alternative fuel vehicles (AFV). References: Voltage Vehicles1 This article is a...

  16. Category:Battery makers | Open Energy Information

    Open Energy Info (EERE)

    Battery makers Jump to: navigation, search Pages in category "Battery makers" The following 5 pages are in this category, out of 5 total. B Battery Ventures F Ford Electric Battery...

  17. Nickel coated aluminum battery cell tabs

    SciTech Connect (OSTI)

    Bucchi, Robert S.; Casoli, Daniel J.; Campbell, Kathleen M.; Nicotina, Joseph

    2014-07-29

    A battery cell tab is described. The battery cell tab is anodized on one end and has a metal coating on the other end. Battery cells and methods of making battery cell tabs are also described.

  18. New sealed rechargeable batteries and supercapacitors

    SciTech Connect (OSTI)

    Barnett, B.M. ); Dowgiallo, E. ); Halpert, G. ); Matsuda, Y. ); Takehara, Z.I. )

    1993-01-01

    This conference was divided into the following sections: supercapacitors; nickel-metal hydride batteries; lithium polymer batteries; lithium/carbon batteries; cathode materials; and lithium batteries. Separate abstracts were prepared for the 46 papers of this conference.

  19. BLE: Battery Life Estimator | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BLE: Battery Life Estimator BLE: Battery Life Estimator Argonne's Battery Life Estimator (BLE) software is a state-of-the-art tool kit for fitting battery aging data and for ...

  20. A Symmetric Organic - Based Nonaqueous Redox Flow Battery and Its State

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Charge Diagnostics by FTIR - Joint Center for Energy Storage Research March 10, 2016, Research Highlights A Symmetric Organic - Based Nonaqueous Redox Flow Battery and Its State of Charge Diagnostics by FTIR (1) Symmetric Nonaqueous flow battery based on ambipolar PTIO (cell voltage 1.7V; solubility 2.6M in MeCN; good cyclability) (2) FTIR-based state of charge monitoring Scientific Achievement A symmetric nonaqueous flow battery based on the highly soluble, ambipolar PTIO achieved a cell

  1. Development of Industrially Viable Battery Electrode Coatings...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Development of Industrially Viable Battery Electrode Coatings Development of Industrially Viable Battery Electrode Coatings Development of ...

  2. Battery, heal thyself: Inventing self-repairing batteries | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battery, heal thyself: Inventing self-repairing batteries By Louise Lerner * January 11, 2012 Tweet EmailPrint Imagine dropping your phone on the hard concrete sidewalk-but when...

  3. Testimonials- Partnerships in Battery Technologies- CalBattery

    Broader source: Energy.gov [DOE]

    Phil Roberts, CEO and Founder of California Lithium Battery (CalBattery), describes the new growth and development that was possible through partnering with the U.S. Department of Energy.

  4. Savings Potential of ENERGY STAR(R) External Power Adapters andBattery Chargers

    SciTech Connect (OSTI)

    Webber, Carrie; Korn, David; Sanchez, Marla

    2007-02-28

    External power adapters may lose 10 to 70 percent of theenergy they consume, dissipated as heat rather than converted into usefulenergy. Battery charging systems have more avenues for losses: inaddition to power conversion losses, power is consumed by the chargingcircuitry, and additional power may be needed after the battery is fullcharged to balance self-discharge. In 2005, the Environmental ProtectionAgency launched a new ENERGY STAR(R) label for external power supplies(EPSs) that convert line-voltage AC electricity into low-voltage DCelectricity for certain electronic devices. The specification includedpower supplies for products with battery charging functions (e.g. laptopsand cell phones), but excluded others. In January 2006, a separatespecification was issued for battery charging systems contained primarilyin small household appliances and power tools. In addition to the ENERGYSTAR(R) label, the state of California will implement minimum energyperformance standards for EPSs in 2007, and similar standards for EPSsand battery chargers are in development at the national level.Many of theproducts covered by these policies use relatively little power and havemodest per-unit savings potential compared to conventional energyefficiency targets. But with an estimated 1.5 billion adapters and 230million battery charging systems in use in the United States, theaggregate savings potential is quite high. This paper presents estimatesof the savings potential for external power adapters and battery chargingsystems through 2025.

  5. Battery venting system and method

    DOE Patents [OSTI]

    Casale, T.J.; Ching, L.K.W.; Baer, J.T.; Swan, D.H.

    1999-01-05

    Disclosed herein is a venting mechanism for a battery. The venting mechanism includes a battery vent structure which is located on the battery cover and may be integrally formed therewith. The venting mechanism includes an opening extending through the battery cover such that the opening communicates with a plurality of battery cells located within the battery case. The venting mechanism also includes a vent manifold which attaches to the battery vent structure. The vent manifold includes a first opening which communicates with the battery vent structure opening and second and third openings which allow the vent manifold to be connected to two separate conduits. In this manner, a plurality of batteries may be interconnected for venting purposes, thus eliminating the need to provide separate vent lines for each battery. The vent manifold may be attached to the battery vent structure by a spin-welding technique. To facilitate this technique, the vent manifold may be provided with a flange portion which fits into a corresponding groove portion on the battery vent structure. The vent manifold includes an internal chamber which is large enough to completely house a conventional battery flame arrester and overpressure safety valve. In this manner, the vent manifold, when installed, lessens the likelihood of tampering with the flame arrester and safety valve. 8 figs.

  6. Battery Vent Mechanism And Method

    SciTech Connect (OSTI)

    Ching, Larry K. W.

    2000-02-15

    Disclosed herein is a venting mechanism for a battery. The venting mechanism includes a battery vent structure which is located on the battery cover and may be integrally formed therewith. The venting mechanism includes an opening extending through the battery cover such that the opening communicates with a plurality of battery cells located within the battery case. The venting mechanism also includes a vent manifold which attaches to the battery vent structure. The vent manifold includes a first opening which communicates with the battery vent structure opening and second and third openings which allow the vent manifold to be connected to two separate conduits. In this manner, a plurality of batteries may be interconnected for venting purposes, thus eliminating the need to provide separate vent lines for each battery. The vent manifold may be attached to the battery vent structure by a spin-welding technique. To facilitate this technique, the vent manifold may be provided with a flange portion which fits into a corresponding groove portion on the battery vent structure. The vent manifold includes an internal chamber which is large enough to completely house a conventional battery flame arrester and overpressure safety valve. In this manner, the vent manifold, when installed, lessens the likelihood of tampering with the flame arrester and safety valve.

  7. Battery venting system and method

    SciTech Connect (OSTI)

    Casale, Thomas J.; Ching, Larry K. W.; Baer, Jose T.; Swan, David H.

    1999-01-05

    Disclosed herein is a venting mechanism for a battery. The venting mechanism includes a battery vent structure which is located on the battery cover and may be integrally formed therewith. The venting mechanism includes an opening extending through the battery cover such that the opening communicates with a plurality of battery cells located within the battery case. The venting mechanism also includes a vent manifold which attaches to the battery vent structure. The vent manifold includes a first opening which communicates with the battery vent structure opening and second and third openings which allow the vent manifold to be connected to two separate conduits. In this manner, a plurality of batteries may be interconnected for venting purposes, thus eliminating the need to provide separate vent lines for each battery. The vent manifold may be attached to the battery vent structure by a spin-welding technique. To facilitate this technique, the vent manifold may be provided with a flange portion which fits into a corresponding groove portion on the battery vent structure. The vent manifold includes an internal chamber which is large enough to completely house a conventional battery flame arrester and overpressure safety valve. In this manner, the vent manifold, when installed, lessens the likelihood of tampering with the flame arrester and safety valve.

  8. AVTA: Battery Testing - DC Fast Charging's Effects on PEV Batteries |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Battery Testing - DC Fast Charging's Effects on PEV Batteries AVTA: Battery Testing - DC Fast Charging's Effects on PEV Batteries The Vehicle Technologies Office's Advanced Vehicle Testing Activity carries out testing on a wide range of advanced vehicles and technologies on dynamometers, closed test tracks, and on-the-road. These results provide benchmark data that researchers can use to develop technology models and guide future research and development. The following

  9. AVTA: Battery Testing - Electric Drive and Advanced Battery and Components

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Testbed | Department of Energy Battery Testing - Electric Drive and Advanced Battery and Components Testbed AVTA: Battery Testing - Electric Drive and Advanced Battery and Components Testbed The Vehicle Technologies Office's Advanced Vehicle Testing Activity carries out testing on a wide range of advanced vehicles and technologies on dynamometers, closed test tracks, and on-the-road. These results provide benchmark data that researchers can use to develop technology models and guide future

  10. Voltage sensor and dielectric material

    DOE Patents [OSTI]

    Yakymyshyn, Christopher Paul; Yakymyshyn, Pamela Jane; Brubaker, Michael Allen

    2006-10-17

    A voltage sensor is described that consists of an arrangement of impedance elements. The sensor is optimized to provide an output ratio that is substantially immune to changes in voltage, temperature variations or aging. Also disclosed is a material with a large and stable dielectric constant. The dielectric constant can be tailored to vary with position or direction in the material.

  11. Temperature controlled high voltage regulator

    DOE Patents [OSTI]

    Chiaro, Jr., Peter J.; Schulze, Gerald K.

    2004-04-20

    A temperature controlled high voltage regulator for automatically adjusting the high voltage applied to a radiation detector is described. The regulator is a solid state device that is independent of the attached radiation detector, enabling the regulator to be used by various models of radiation detectors, such as gas flow proportional radiation detectors.

  12. Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems

    SciTech Connect (OSTI)

    Tuffner, Francis K.; Kintner-Meyer, Michael C. W.; Hammerstrom, Donald J.; Pratt, Richard M.

    2012-05-22

    Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems. According to one aspect, a battery charging control method includes accessing information regarding a presence of at least one of a surplus and a deficiency of electrical energy upon an electrical power distribution system at a plurality of different moments in time, and using the information, controlling an adjustment of an amount of the electrical energy provided from the electrical power distribution system to a rechargeable battery to charge the rechargeable battery.

  13. Circulating current battery heater

    DOE Patents [OSTI]

    Ashtiani, Cyrus N.; Stuart, Thomas A.

    2001-01-01

    A circuit for heating energy storage devices such as batteries is provided. The circuit includes a pair of switches connected in a half-bridge configuration. Unidirectional current conduction devices are connected in parallel with each switch. A series resonant element for storing energy is connected from the energy storage device to the pair of switches. An energy storage device for intermediate storage of energy is connected in a loop with the series resonant element and one of the switches. The energy storage device which is being heated is connected in a loop with the series resonant element and the other switch. Energy from the heated energy storage device is transferred to the switched network and then recirculated back to the battery. The flow of energy through the battery causes internal power dissipation due to electrical to chemical conversion inefficiencies. The dissipated power causes the internal temperature of the battery to increase. Higher internal temperatures expand the cold temperature operating range and energy capacity utilization of the battery. As disclosed, either fixed frequency or variable frequency modulation schemes may be used to control the network.

  14. Examination of VRLA cells sampled from a battery energy storage system (BESS) after 30-months of operations

    SciTech Connect (OSTI)

    SZYMBORSKI,JOSEPH; HUNT,GEORGE; TSAGALIS,ANGELO; JUNGST,RUDOLPH G.

    2000-06-08

    Valve-Regulated Lead-Acid (VRLA) batteries continue to be employed in a wide variety of applications for telecommunications and Uninterruptible Power Supply (UPS). With the rapidly growing penetration of internet services, the requirements for standby power systems appear to be changing. For example, at last year's INTELEC, high voltage standby power systems up to 300-vdc were discussed as alternatives to the traditional 48-volt power plant. At the same time, battery reliability and the sensitivity of VRLAS to charging conditions (e.g., in-rush current, float voltage and temperature), continue to be argued extensively. Charge regimes which provide off-line charging or intermittent charge to the battery have been proposed. Some of these techniques go against the widely accepted rules of operation for batteries to achieve optimum lifetime. Experience in the telecom industry with high voltage systems and these charging scenarios is limited. However, GNB has several years of experience in the installation and operation of large VRLA battery systems that embody many of the power management philosophies being proposed. Early results show that positive grid corrosion is not accelerated and battery performance is maintained even when the battery is operated at a partial state-of-charge for long periods of time.

  15. Safe battery solvents

    DOE Patents [OSTI]

    Harrup, Mason K.; Delmastro, Joseph R.; Stewart, Frederick F.; Luther, Thomas A.

    2007-10-23

    An ion transporting solvent maintains very low vapor pressure, contains flame retarding elements, and is nontoxic. The solvent in combination with common battery electrolyte salts can be used to replace the current carbonate electrolyte solution, creating a safer battery. It can also be used in combination with polymer gels or solid polymer electrolytes to produce polymer batteries with enhanced conductivity characteristics. The solvents may comprise a class of cyclic and acyclic low molecular weight phosphazenes compounds, comprising repeating phosphorus and nitrogen units forming a core backbone and ion-carrying pendent groups bound to the phosphorus. In preferred embodiments, the cyclic phosphazene comprises at least 3 phosphorus and nitrogen units, and the pendent groups are polyethers, polythioethers, polyether/polythioethers or any combination thereof, and/or other groups preferably comprising other atoms from Group 6B of the periodic table of elements.

  16. Battery switch for downhole tools

    DOE Patents [OSTI]

    Boling, Brian E.

    2010-02-23

    An electrical circuit for a downhole tool may include a battery, a load electrically connected to the battery, and at least one switch electrically connected in series with the battery and to the load. The at least one switch may be configured to close when a tool temperature exceeds a selected temperature.

  17. Seal for sodium sulfur battery

    DOE Patents [OSTI]

    Topouzian, Armenag; Minck, Robert W.; Williams, William J.

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which the sealing is accomplished by a radial compression seal made on a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  18. Design Optimization of Radionuclide Nano-Scale Batteries

    SciTech Connect (OSTI)

    Schoenfeld, D.W.; Tulenko, J.S.; Wang, J.; Smith, B.

    2004-10-06

    Radioisotopes have been used for power sources in heart pacemakers and space applications dating back to the 50's. Two key properties of radioisotope power sources are high energy density and long half-life compared to chemical batteries. The tritium battery used in heart pacemakers exceeds 500 mW-hr, and is being evaluated by the University of Florida for feasibility as a MEMS (MicroElectroMechanical Systems) power source. Conversion of radioisotope sources into electrical power within the constraints of nano-scale dimensions requires cutting-edge technologies and novel approaches. Some advances evolving in the III-V and II-IV semiconductor families have led to a broader consideration of radioisotopes rather free of radiation damage limitations. Their properties can lead to novel battery configurations designed to convert externally located emissions from a highly radioactive environment. This paper presents results for the analytical computational assisted design and modeling of semiconductor prototype nano-scale radioisotope nuclear batteries from MCNP and EGS programs. The analysis evaluated proposed designs and was used to guide the selection of appropriate geometries, material properties, and specific activities to attain power requirements for the MEMS batteries. Plans utilizing high specific activity radioisotopes were assessed in the investigation of designs employing multiple conversion cells and graded junctions with varying band gap properties. Voltage increases sought by serial combination of VOC s are proposed to overcome some of the limitations of a low power density. The power density is directly dependent on the total active areas.

  19. Soluble Lead Flow Battery: Soluble Lead Flow Battery Technology

    SciTech Connect (OSTI)

    2010-09-01

    GRIDS Project: General Atomics is developing a flow battery technology based on chemistry similar to that used in the traditional lead-acid battery found in nearly every car on the road today. Flow batteries store energy in chemicals that are held in tanks outside the battery. When the energy is needed, the chemicals are pumped through the battery. Using the same basic chemistry as a traditional battery but storing its energy outside of the cell allows for the use of very low cost materials. The goal is to develop a system that is far more durable than today’s lead-acid batteries, can be scaled to deliver megawatts of power, and which lowers the cost of energy storage below $100 per kilowatt hour.

  20. Low voltage nonprimary explosive detonator

    DOE Patents [OSTI]

    Dinegar, Robert H.; Kirkham, John

    1982-01-01

    A low voltage, electrically actuated, nonprimary explosive detonator is disclosed wherein said detonation is achieved by means of an explosive train in which a deflagration-to-detonation transition is made to occur. The explosive train is confined within a cylindrical body and positioned adjacent to low voltage ignition means have electrical leads extending outwardly from the cylindrical confining body. Application of a low voltage current to the electrical leads ignites a self-sustained deflagration in a donor portion of the explosive train which then is made to undergo a transition to detonation further down the train.

  1. Position indicator

    DOE Patents [OSTI]

    Tanner, David E.

    1981-01-01

    A nuclear reactor system is described in which a position indicator is provided for detecting and indicating the position of a movable element inside a pressure vessel. The movable element may be a valve element or similar device which moves about an axis. Light from a light source is transmitted from a source outside the pressure vessel to a first region inside the pressure vessel in alignment with the axis of the movable element. The light is redirected by a reflector prism to a second region displaced radially from the first region. The reflector prism moves in response to movement of the movable element about its axis such that the second region moves arcuately with respect to the first region. Sensors are arrayed in an arc corresponding to the arc of movement of the second region and signals are transmitted from the sensors to the exterior of the reactor vessel to provide indication of the position of the movable element.

  2. Batteries & Fuel Cells > Research > The Energy Materials Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries & Fuel Cells Here are the details of what we're doing in the labs to improve battery & fuel cell technology. Battery Anodes Battery Cathodes Depletion Aggregation ...

  3. China Hyper Battery Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Battery Co Ltd Jump to: navigation, search Name: China Hyper Battery Co Ltd Place: Shenzhen, China Zip: 518048 Product: Manufacturer and exporter of batteries and battery packs....

  4. Battery collection in municipal waste management in Japan: Challenges for hazardous substance control and safety

    SciTech Connect (OSTI)

    Terazono, Atsushi; Oguchi, Masahiro; Iino, Shigenori; Mogi, Satoshi

    2015-05-15

    Highlights: • Consumers need to pay attention to the specific collection rules for each type of battery in each municipality in Japan. • 6–10% of zinc carbon and alkaline batteries discarded in Japan currently could be regarded as containing mercury. • Despite announcements by producers and municipalities, only 2.0% of discarded cylindrical dry batteries were insulated. • Batteries made up an average of 4.6% of the total collected small WEEE under the small WEEE recycling scheme in Japan. • Exchangeable batteries were used in almost all of mobile phones, but the removal rate was as low as 22% for mobile phones. - Abstract: To clarify current collection rules of waste batteries in municipal waste management in Japan and to examine future challenges for hazardous substance control and safety, we reviewed collection rules of waste batteries in the Tokyo Metropolitan Area. We also conducted a field survey of waste batteries collected at various battery and small waste electric and electronic equipment (WEEE) collection sites in Tokyo. The different types of batteries are not collected in a uniform way in the Tokyo area, so consumers need to pay attention to the specific collection rules for each type of battery in each municipality. In areas where small WEEE recycling schemes are being operated after the enforcement of the Act on Promotion of Recycling of Small Waste Electrical and Electronic Equipment in Japan in 2013, consumers may be confused about the need for separating batteries from small WEEE (especially mobile phones). Our field survey of collected waste batteries indicated that 6–10% of zinc carbon and alkaline batteries discarded in Japan currently could be regarded as containing mercury. More than 26% of zinc carbon dry batteries currently being discarded may have a lead content above the labelling threshold of the EU Batteries Directive (2006/66/EC). In terms of safety, despite announcements by producers and municipalities about using

  5. Optimized Operating Range for Large-Format LiFePO4/Graphite Batteries

    SciTech Connect (OSTI)

    Jiang, Jiuchun; Shi, Wei; Zheng, Jianming; Zuo, Pengjian; Xiao, Jie; Chen, Xilin; Xu, Wu; Zhang, Jiguang

    2014-06-01

    e investigated the long-term cycling performance of large format 20Ah LiFePO4/graphite batteries when they are cycled in various state-of-charge (SOC) ranges. It is found that batteries cycled in the medium SOC range (ca. 20~80% SOC) exhibit superior cycling stability than batteries cycled at both ends (0-20% or 80-100%) of the SOC even though the capcity utilized in the medium SOC range is three times as large as those cycled at both ends of the SOC. Several non-destructive techniques, including a voltage interruption approach, model-based parameter identification, electrode impedance spectra analysis, ΔQ/ΔV analysis, and entropy change test, were used to investigate the performance of LiFePO4/graphite batteries within different SOC ranges. The results reveal that batteries at the ends of SOC exhibit much higher polarization impedance than those at the medium SOC range. These results can be attributed to the significant structural change of cathode and anode materials as revealed by the large entropy change within these ranges. The direct correlation between the polarization impedance and the cycle life of the batteries provides an effective methodology for battery management systems to control and prolong the cycle life of LiFePO4/graphite and other batteries.

  6. Evaluation of two lower-melting electrolytes in lithium silicon/iron disulfide thermal batteries

    SciTech Connect (OSTI)

    Morella, A.T.

    1991-08-02

    Two new thermal battery electrolyte materials were investigated with the intent of extending the life of lithium silicon/iron disulfide [Li(Si)/FeS{sub 2}] thermal batteries. These new electrolyte materials freeze at a lower temperature than the standard electrolyte, which should extend the life of the thermal batteries in which they are used. Sandia National Laboratories (SNL), Albuquerque requested that the GE Neutron Devices (GEND) Power Sources Engineering group evaluate these new electrolytes in 40 MC3575 thermal batteries and compare the performance to an established data base. It was found that the batteries using the lower-melting electrolytes performed equal to or better than the batteries in the data base using the standard LiCl/KCl electrolyte at the same test conditions. The usage of these electrolytes increased the battery life, suppressed the voltage spikes, reduced heat requirements, shortened battery stack heights, and produced faster rise times. All of these improvements would merit further investigation of the new electrolyte materials.

  7. Battery electrode growth accommodation

    DOE Patents [OSTI]

    Bowen, Gerald K.; Andrew, Michael G.; Eskra, Michael D.

    1992-01-01

    An electrode for a lead acid flow through battery, the grids including a plastic frame, a plate suspended from the top of the frame to hang freely in the plastic frame and a paste applied to the plate, the paste being free to allow for expansion in the planar direction of the grid.

  8. Battery Calorimetry Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Calorimetry Laboratory - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced

  9. Monitoring Current, Voltage and Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Monitoring Current, Voltage and Power in Photovoltaic Systems Anton Driesse 1 , Joshua S. Stein 2 , Daniel Riley 2 , Craig Carmignani 2 1 PV Performance Labs, Freiburg, Germany 2 Sandia National Laboratories, Albuquerque, New Mexico Abstract - Accurate photovoltaic system performance monitoring is critical for profitable long-term operation. Irradiance, temperature, power, current and voltage signals contain rapid fluctuations that are not observable by typical monitoring systems. Nevertheless

  10. A Matter of Quantum Voltages

    SciTech Connect (OSTI)

    Sellner, Bernhard; Kathmann, Shawn M.

    2014-11-14

    Voltages inside matter are relevant to crystallization, materials science, biology, catalysis, and aqueous chemistry. Electron holography is able to measure the variation of voltages in matter and modern supercomputers allow the calculation of quantum voltages with practically unlimited spatial and temporal resolution of bulk systems. Of particular interest is the Mean Inner Potential (Vo) - the spatial average of these voltages. Voltages are very sensitive to the distribution of electrons and provide metrics to understand interactions in condensed phases. In the present study, we find excellent agreement with measurements of Vo for vitrified water and salt crystals and demonstrate the impact of covalent and ionic bonding as well as intermolecular/atomic interactions. Furthermore, we predict Vo as well as the fluctuations of these voltages in aqueous NaCl electrolytes and characterize the changes in their behavior as the resolution increases below the size of atoms. This work was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle. This research used resources of the National Energy Research Scientific Computing Center, which is supported by the Office of Science of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231.

  11. Development and Testing of an UltraBattery-Equipped Honda Civic Hybrid

    SciTech Connect (OSTI)

    Sally Sun; Tyler Gray; Pattie Hovorka; Jeffrey Wishart; Donald Karner; James Francfort

    2012-08-01

    The UltraBattery Retrofit Project DP1.8 and Carbon Enriched Project C3, performed by ECOtality North America (ECOtality) and funded by the U.S. Department of Energy and the Advanced Lead Acid Battery Consortium (ALABC), are established to demonstrate the suitability of advanced lead battery technology in hybrid electrical vehicles (HEVs). A profile, termed the “Simulated Honda Civic HEV Profile” (SHCHEVP) has been developed in Project DP1.8 in order to provide reproducible laboratory evaluations of different battery types under real-world HEV conditions. The cycle is based on the Urban Dynamometer Driving Schedule and Highway Fuel Economy Test cycles and simulates operation of a battery pack in a Honda Civic HEV. One pass through the SHCHEVP takes 2,140 seconds and simulates 17.7 miles of driving. A complete nickel metal hydride (NiMH) battery pack was removed from a Honda Civic HEV and operated under SHCHEVP to validate the profile. The voltage behavior and energy balance of the battery during this operation was virtually the same as that displayed by the battery when in the Honda Civic operating on the dynamometer under the Urban Dynamometer Driving Schedule and Highway Fuel Economy Test cycles, thus confirming the efficacy of the simulated profile. An important objective of the project has been to benchmark the performance of the UltraBatteries manufactured by both Furukawa Battery Co., Ltd., Japan (Furakawa) and East Penn Manufacturing Co., Inc. (East Penn). Accordingly, UltraBattery packs from both Furakawa and East Penn have been characterized under a range of conditions. Resistance measurements and capacity tests at various rates show that both battery types are very similar in performance. Both technologies, as well as a standard lead-acid module (included for baseline data), were evaluated under a simple HEV screening test. Both Furakawa and East Penn UltraBattery packs operated for over 32,000 HEV cycles, with minimal loss in performance; whereas the

  12. NREL: Measurements and Characterization - Current Versus Voltage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of devices, including: open-circuit voltage (Voc), short-circuit current (Isc), fill factor (FF), maximum power output of the device (Pmax), voltage at maximum power...

  13. Electrochemical Lithium Ion Battery Performance Model

    Energy Science and Technology Software Center (OSTI)

    2007-03-29

    The Electrochemical Lithium Ion Battery Performance Model allows for the computer prediction of the basic thermal, electrical, and electrochemical performance of a lithium ion cell with simplified geometry. The model solves governing equations describing the movement of lithium ions within and between the negative and positive electrodes. The governing equations were first formulated by Fuller, Doyle, and Newman and published in J. Electrochemical Society in 1994. The present model solves the partial differential equations governingmore » charge transfer kinetics and charge, species, heat transports in a computationally-efficient manner using the finite volume method, with special consideration given for solving the model under conditions of applied current, voltage, power, and load resistance.« less

  14. AVTA: Battery Testing - DC Fast Charging's Effects on PEV Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Testing Reports DC Fast Charge Impacts on Battery Life and Vehicle Performance INL Efficiency and Security Testing of EVSE, DC Fast Chargers, and Wireless Charging Systems

  15. Applying the Battery Ownership Model in Pursuit of Optimal Battery...

    Broader source: Energy.gov (indexed) [DOE]

    Vehicle Technologies Office: 2013 Energy Storage R&D Progress Report, Sections 4-6 Analysis of Electric Vehicle Battery Performance Targets Building America Whole-House Solutions ...

  16. Voltage distortion in distribution feeders with nonlinear loads

    SciTech Connect (OSTI)

    Emanuel, A.E.; Janczak, J. ); Pileggi, D.J.; Gulachenski, E.M.; Root, C.E.; Breen, M. ); Gentile, T.J. )

    1994-01-01

    The voltage of three real-life 13.8kV feeders supplying customers with non-linear loads was analyzed by means of computer simulations. Three classes of non-linear loads were considered. Each class is characteristic for different types of ac to dc converters such as the input dc supply used for adjustable-speed-drives, battery chargers, PC's, TV's and electronically ballasted lights. The analysis is based on the determination of the most harmonic susceptible busses and their response to each harmonic frequency. A new expeditive method that takes into account the background harmonic voltage phasor, and an equivalent bus impedance was developed and used to compute the maximum non-linear loads that yields VTHD = 5%, (Voltage Total Harmonic Distortion). The main conclusion of this work is that when mitigation methods are not used, for a 15kV class feeder with a maximum 10MVA installed load, the total non-linear residential load should not exceed 300kW if the ITHD <30% (Current Total Harmonic Distortion), and 100kW if ITHD >100%.

  17. Battery charging stations

    SciTech Connect (OSTI)

    Bergey, M.

    1997-12-01

    This paper discusses the concept of battery charging stations (BCSs), designed to service rural owners of battery power sources. Many such power sources now are transported to urban areas for recharging. A BCS provides the opportunity to locate these facilities closer to the user, is often powered by renewable sources, or hybrid systems, takes advantage of economies of scale, and has the potential to provide lower cost of service, better service, and better cost recovery than other rural electrification programs. Typical systems discussed can service 200 to 1200 people, and consist of stations powered by photovoltaics, wind/PV, wind/diesel, or diesel only. Examples of installed systems are presented, followed by cost figures, economic analysis, and typical system design and performance numbers.

  18. Block copolymer battery separator

    DOE Patents [OSTI]

    Wong, David; Balsara, Nitash Pervez

    2016-04-26

    The invention herein described is the use of a block copolymer/homopolymer blend for creating nanoporous materials for transport applications. Specifically, this is demonstrated by using the block copolymer poly(styrene-block-ethylene-block-styrene) (SES) and blending it with homopolymer polystyrene (PS). After blending the polymers, a film is cast, and the film is submerged in tetrahydrofuran, which removes the PS. This creates a nanoporous polymer film, whereby the holes are lined with PS. Control of morphology of the system is achieved by manipulating the amount of PS added and the relative size of the PS added. The porous nature of these films was demonstrated by measuring the ionic conductivity in a traditional battery electrolyte, 1M LiPF.sub.6 in EC/DEC (1:1 v/v) using AC impedance spectroscopy and comparing these results to commercially available battery separators.

  19. Batteries Breakout Session

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EV Everywhere Workshop July 26, 2012 Breakout Session #1 - Discussion of Performance Targets and Barriers Comments on the Achievability of the Targets * Reasonable for EV100 and EV300, Power/energy does not box well for PHEV40 * Need to look at whole system view of EV300 (utilization is not high) * EV100 has much better utilization * Target needs to capture external conditions (consumer and infrastructure) * Capture Secondary use of batteries * EV100 Primary Vehicle, felt not practical? Barriers

  20. Battery Chargers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battery Chargers Battery Chargers The Department of Energy (DOE) develops standardized data templates for reporting the results of tests conducted in accordance with current DOE test procedures. Templates may be used by third-party laboratories under contract with DOE that conduct testing in support of ENERGY STAR® verification, DOE rulemakings, and enforcement of the federal energy conservation standards. Battery Chargers -- v1.0 (94 KB) More Documents & Publications Illuminated Exit Signs

  1. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery...

  2. SANIK Battery Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    SANIK Battery Co Ltd Jump to: navigation, search Name: SANIK Battery Co., Ltd. Place: China Product: Foshan City-based NiCd and NiMH rechargeable batteries producer for smaller...

  3. JYH Battery Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    JYH Battery Co Ltd Jump to: navigation, search Name: JYH Battery Co, Ltd Place: China Product: China-based maker of NiMH rechargeable batteries, also with some NiCd and Li-ion...

  4. Beijing Tianruichi Battery TRC | Open Energy Information

    Open Energy Info (EERE)

    Tianruichi Battery TRC Jump to: navigation, search Name: Beijing Tianruichi Battery (TRC) Place: China Product: China-based maker of Li-Poly, Li-Iron and Li-Ion batteries....

  5. Category:Batteries | Open Energy Information

    Open Energy Info (EERE)

    9 pages are in this category, out of 9 total. * Definition:Battery B Batteries and Energy Storage Technology BEST L Definition:Lead-acid battery L cont. Definition:DIY...

  6. Promising Magnesium Battery Research at ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Promising Magnesium Battery Research at ALS Promising Magnesium Battery Research at ALS Print Wednesday, 23 January 2013 16:59 toyota battery a) Cross-section of the in situ ...

  7. Washington: Battery Manufacturer Brings Material Production Home...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    can be used in ultracapacitors, lithium-ion batteries, and advanced lead acid batteries. ... EnerG2 Ribbon Cutting Ceremony for new battery materials plant in Albany, Oregon. Photo ...

  8. Self-charging solar battery

    SciTech Connect (OSTI)

    Curiel, R.F.

    1986-01-07

    This self-charging solar battery consists of: a flashlight housing formed at least partially of a transparent material, an open-ended cylindrical battery housing formed at least partially of a transparent material, a rechargeable battery cell means mounted in the battery housing (with its transparent material positioned adjacent the transparent material of the flashlight housing and comprising positive and negative terminals, one at each end thereof), a solar electric panel comprising photo-voltaic cell means having positive and negative terminals, and a diode means mounted in the battery housing and comprising an anode and a cathode. The solar battery also has: a first means for connecting the positive terminal of the photo-voltaic cell means to the anode and for connecting the cathode to the positive terminal of the battery cell means, a second means for connecting the negative terminal of the battery cell means to the negative terminal of the photo-voltaic cell means, and cap means for closing each end of the battery housing.

  9. Self-charging solar battery

    SciTech Connect (OSTI)

    Curiel, R.F.

    1987-03-03

    This patent describes a flashlight employing a self-charging solar battery assembly comprising: a flashlight housing formed at least partially of a transparent material, an open-ended cylindrical battery housing formed at least partially of a transparent material, a rechargeable battery cell means mounted in the battery housing with its transparent material positioned adjacent the transparent material of the flashlight housing and comprising positive and negative terminals, one at each end thereof, a solar electric panel comprising photo-voltaic cell means having positive and negative terminals, the panel being mounted within the battery housing with the photo-voltaic cell means juxtapositioned to the transparent material of the battery housing such that solar rays may pass through the transparent material of the flashlight housing and the battery housing and excite the photo-voltaic cell means, a first means for connecting the positive terminal of the photo-voltaic cell means to the positive terminal of the battery cell means, and a second means for connecting the negative terminal of the battery cell means to the negative terminal of the photo-voltaic cell means.

  10. EV Everywhere Challenge Battery Workshop

    Broader source: Energy.gov [DOE]

    Backsplash for the EV Everywhere Grand Challenge: Battery Workshop on July 26, 2012 held at the Doubletree O'Hare, Chicago, IL.

  11. Lessons Learned from the Puerto Rico Battery Energy Storage System

    SciTech Connect (OSTI)

    BOYES, JOHN D.; DE ANA, MINDI FARBER; TORRES, WENCESLANO

    1999-09-01

    The Puerto Rico Electric Power Authority (PREPA) installed a distributed battery energy storage system in 1994 at a substation near San Juan, Puerto Rico. It was patterned after two other large energy storage systems operated by electric utilities in California and Germany. The U.S. Department of Energy (DOE) Energy Storage Systems Program at Sandia National Laboratories has followed the progress of all stages of the project since its inception. It directly supported the critical battery room cooling system design by conducting laboratory thermal testing of a scale model of the battery under simulated operating conditions. The Puerto Rico facility is at present the largest operating battery storage system in the world and is successfully providing frequency control, voltage regulation, and spinning reserve to the Caribbean island. The system further proved its usefulness to the PREPA network in the fall of 1998 in the aftermath of Hurricane Georges. The owner-operator, PREPA, and the architect/engineer, vendors, and contractors learned many valuable lessons during all phases of project development and operation. In documenting these lessons, this report will help PREPA and other utilities in planning to build large energy storage systems.

  12. USFOE: Extended Summary - Lithium ion batteries and their manufacturing challenges

    SciTech Connect (OSTI)

    Daniel, Claus

    2014-01-01

    There is no one lithium ion battery. With the variety of materials and electrochemical couples at our disposal as shown in the previous talks, we have the opportunity to design battery cells specific for their applications. Such applications require optimization of voltage, state of charge utilization, lifetime needs, and safety considerations. Electrochemical couples allow for designing power and energy ratios and available energy for the application. Integration in a large format cell requires optimized roll to roll electrode manufacturing and active material utilization. Electrodes are coated on a current collector in a composite structure comprised of active material, binders, and conductive additives which requires careful control of colloidal chemistry, adhesion, and solidification. These added inactive materials and the cell packaging reduce energy density. Degree of porosity and compaction in the electrode can impede or enhance battery performance. Pathways are explored to bring batteries from currently commercially available 100Wh/kg and 200Wh/L at $500/kWh to 250Wh/kg and 400Wh/L at $125/kWh.

  13. Materials issues in lithium ion rechargeable battery technology

    SciTech Connect (OSTI)

    Doughty, D.H.

    1995-07-01

    Lithium ion rechargeable batteries are predicted to replace Ni/Cd as the workhorse consumer battery. The pace of development of this battery system is determined in large part by the availability of materials and the understanding of interfacial reactions between materials. Lithium ion technology is based on the use of two lithium intercalating electrodes. Carbon is the most commonly used anode material, while the cathode materials of choice have been layered lithium metal chalcogenides (LiMX{sub 2}) and lithium spinel-type compounds. Electrolytes may be either organic liquids or polymers. Although the first practical use of graphite intercalation compounds as battery anodes was reported in 1981 for molten salt cells and in 1983 for ambient temperature systems, it was not until Sony Energytech announced a new lithium ion intercalating carbon anode in 1990, that interest peaked. The reason for this heightened interest is that these electrochemical cells have the high energy density, high voltage and light weight of metallic lithium, but without the disadvantages of dendrite formation on charge, improving their safety and cycle life.

  14. Fluoride based cathodes and electrolytes for high energy thermal batteries

    SciTech Connect (OSTI)

    Briscoe, J.D.

    1998-07-01

    A research and development program is being conducted at the Saft Advanced Technologies Division in Hunt Valley, MD to double the energy density of a thermal battery. A study of high voltage cathodes to replace iron disulfide is in progress. Single cells are being studied with a lithium anode and either a copper(II) fluoride, silver(II) fluoride, or iron(III) fluoride cathode. Due to the high reactivity of these cathodes, conventional alkali metal chloride and bromide salt electrolytes must be replaced by alkali metal fluoride electrolytes. Parametric studies using design-of-experiments matrices will be performed so that the best cathode for an improved battery design can be selected. Titanium hardware for the design will provide a higher strength to weight ratio with lower emissivity than conventional stainless steel. The battery will consist of two power sections. The goals are battery activation in less than 0.2 s, 88 Wh/kg, 1,385 W/kg, and 179 Wh/L over an environmental temperature range of {minus}40 C to +70 C.

  15. Engineering process instructions and development summary MC3642 thermal battery

    SciTech Connect (OSTI)

    Jacobs, D.

    1981-06-01

    The MC3642 is a dual channel thermal battery used on the DE1010/W85 Command Disable Controller. It utilizes the CalCaCrO{sub 4} electrochemical system. The electrical requirements of this battery are as follows: RISE TIME PEAK VOLTAGE ACTIVE LIFE LOAD Channel 1 - 1.0 Sec. Max. 34 Volts 10 Sec. Min. 40.0 Ohms to 20 Volts above 20 Volts Channel 2 - .350 Sec. Max. 42 Volts 10 MSec. Min. 6.5 Ohms to 23 Volts above 23 Volts The battery consists of 14 cells connected in series (Channel 2) and 12 cells connected in series (Channel 1). Each cell is composed of an anode fabricated from a bimetallic sheet (0.005{double_prime} thick calcium on 0.005{double_prime} thick iron substrate), a depolarizer-electrolyte-binder (DEB) pellet and a heat pellet. Activation is achieved by mechanical primer. Optimum battery performance is achieved with a 35155/10 DEB pellet weighing .80g and a heat pellet, weighing 1.30 grams, of 88/12 heat powder.

  16. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  17. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  18. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  19. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  20. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Mapping Particle Charges in Battery Electrodes Print Friday, 26 July 2013 14:18 The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how

  1. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  2. Vehicle Battery Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battery Basics Vehicle Battery Basics November 22, 2013 - 1:58pm Addthis Vehicle Battery Basics Batteries are essential for electric drive technologies such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and all-electric vehicles (AEVs). WHAT IS A BATTERY? A battery is a device that stores chemical energy and converts it on demand into electrical energy. It carries out this process through an electrochemical reaction, which is a chemical reaction involving the

  3. 'Thirsty' Metals Key to Longer Battery Lifetimes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    'Thirsty' Metals Key to Longer Battery Lifetimes 'Thirsty' Metals Key to Longer Battery Lifetimes Computations at NERSC show how multiply charged metal ions impact battery capacity June 30, 2014 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov PCCPxantheascover Imagine a cell phone battery that lasted a whole week on a single charge. A car battery that worked for months between charges. A massive battery that stores the intermittent electricity from wind turbines and releases it when

  4. Electric Fuel Battery Corporation | Open Energy Information

    Open Energy Info (EERE)

    Fuel Battery Corporation Jump to: navigation, search Name: Electric Fuel Battery Corporation Place: Auburn, Alabama Zip: 36832 Product: Develops and manufactures BA-8180U high...

  5. Advanced Battery Manufacturing Facilities and Equipment Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. PDF icon esarravt002flicker2010p.pdf More Documents & Publications Advanced Battery Manufacturing Facilities and Equipment Program Advanced Battery Manufacturing...

  6. American Battery Charging Inc | Open Energy Information

    Open Energy Info (EERE)

    Battery Charging Inc Jump to: navigation, search Name: American Battery Charging Inc Place: Smithfield, Rhode Island Zip: 2917 Product: Manufacturer of industrial and railroad...

  7. Kayo Battery Industries Group | Open Energy Information

    Open Energy Info (EERE)

    started by Hong Kong Highpower Technology and Japan Kayo Group, active in producing Lithium and NiMH batteries for various applications including batteries suitable for...

  8. Bullith Batteries AG | Open Energy Information

    Open Energy Info (EERE)

    Batteries AG Place: Ismaning, Germany Zip: 85737 Product: Batteries producer using the lithium-polymer technology. Coordinates: 48.22727, 11.676305 Show Map Loading map......

  9. TCL Hyperpower Batteries Inc | Open Energy Information

    Open Energy Info (EERE)

    Batteries, Inc Place: China Product: China-based subsidiary of TCL Group, they make Lithium Polymer, NiMH and Primary batteries, primarily for smaller devices. References: TCL...

  10. Electrolytic orthoborate salts for lithium batteries (Patent...

    Office of Scientific and Technical Information (OSTI)

    Electrolytic orthoborate salts for lithium batteries Title: Electrolytic orthoborate salts for lithium batteries Orthoborate salts suitable for use as electrolytes in lithium ...

  11. Rechargeable Nanoelectrofuels for Flow Batteries | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rechargeable Nanoelectrofuels for Flow Batteries Four-page general brochure describing a groundbreaking energy storage concept that may revolutionize the world of batteries PDF...

  12. Cathode material for lithium batteries (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Title: Cathode material for lithium batteries A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium ...

  13. Zibo Storage Battery Factory | Open Energy Information

    Open Energy Info (EERE)

    Storage Battery Factory Jump to: navigation, search Name: Zibo Storage Battery Factory Place: Zibo, Shandong Province, China Zip: 255056 Product: China-based affiliate of CSIC...

  14. Advanced Lithium Ion Battery Technologies - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Advanced Lithium Ion Battery Technologies Lawrence ... improved battery life when used in the fabrication of negative silicon electrodes. ...

  15. Vehicle Technologies Office Battery Research Partner Requests...

    Office of Environmental Management (EM)

    Battery Research Partner Requests Proposals for Thermal Management Systems Vehicle Technologies Office Battery Research Partner Requests Proposals for Thermal Management Systems ...

  16. EV Everywhere Grand Challenge - Battery Workshop Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ...2012 EV Everywhere Grand Challenge -- Battery Workshop Thursday, July 26, 2012 - ... Technologies Program 9:25-9:50 AM EV BATTERY TECHNOLOGY-CURRENT STATUS & COST ...

  17. Dual Functional Cathode Additives for Battery Technologies -...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Return to Search Dual Functional Cathode Additives for Battery Technologies Brookhaven ... activation of the cell of a lithium battery having a primary metal sulfide additive ...

  18. Advanced Battery Manufacturing Facilities and Equipment Program...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Advanced Battery Manufacturing Facilities and Equipment Program Advanced Battery Manufacturing Facilities and Equipment Program Fact Sheet: Grid-Scale ...

  19. Advanced Battery Manufacturing Facilities and Equipment Program...

    Broader source: Energy.gov (indexed) [DOE]

    and Equipment Program Advanced Battery Manufacturing Facilities and Equipment Program AVTA: 2010 Honda Civic HEV with Experimental Ultra Lead Acid Battery Testing Results

  20. Washington: Graphene Nanostructures for Lithium Batteries Recieves...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Graphene Nanostructures for Lithium Batteries Recieves 2012 R&D 100 Award Washington: ... Improving charge time and these other battery characteristics could significantly expand ...

  1. Epitaxial Single Crystal Nanostructures for Batteries & PVs ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance ...

  2. Self-Regulating, Nonflamable Rechargeable Lithium Batteries ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Batteries Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryRechargeable lithium batteries are superior to ...

  3. Disordered Materials Hold Promise for Better Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Disordered materials hold promise for better batteries Disordered Materials Hold Promise for Better Batteries February 21, 2014 Contact: Linda Vu, +1 510 495 2402, lvu@lbl.gov ...

  4. Ovonic Battery Company Inc | Open Energy Information

    Open Energy Info (EERE)

    search Name: Ovonic Battery Company Inc Place: Michigan Zip: 48309 Sector: Hydro, Hydrogen Product: Focused on commercializing its patented and proprietary NiMH battery...

  5. electrochemical battery stress-induced degradation mechanisms

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electrochemical battery stress-induced degradation mechanisms - Sandia Energy Energy ... Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel ...

  6. Horizon Batteries formerly Electrosource | Open Energy Information

    Open Energy Info (EERE)

    Batteries formerly Electrosource Jump to: navigation, search Name: Horizon Batteries (formerly Electrosource) Place: Texas Sector: Vehicles Product: Manufacturer of high-power,...

  7. High voltage MOSFET switching circuit

    DOE Patents [OSTI]

    McEwan, T.E.

    1994-07-26

    The problem of source lead inductance in a MOSFET switching circuit is compensated for by adding an inductor to the gate circuit. The gate circuit inductor produces an inductive spike which counters the source lead inductive drop to produce a rectangular drive voltage waveform at the internal gate-source terminals of the MOSFET. 2 figs.

  8. High voltage MOSFET switching circuit

    DOE Patents [OSTI]

    McEwan, Thomas E.

    1994-01-01

    The problem of source lead inductance in a MOSFET switching circuit is compensated for by adding an inductor to the gate circuit. The gate circuit inductor produces an inductive spike which counters the source lead inductive drop to produce a rectangular drive voltage waveform at the internal gate-source terminals of the MOSFET.

  9. Battery resource assessment. Subtask II. 5. Battery manufacturing capability recycling of battery materials. Draft final report

    SciTech Connect (OSTI)

    Pemsler, P.

    1981-02-01

    Studies were conducted on the recycling of advanced battery system components for six different battery systems. These include: Nickel/Zinc, Nickel/Iron, Zinc/Chlorine, Zinc/Bromine, Sodium/Sulfur, and Lithium-Aluminum/Iron Sulfide. For each battery system, one or more processes has been developed which would permit recycling of the major or active materials. Each recycle process has been designed to produce a product material which can be used directly as a raw material by the battery manufacturer. Metal recoverabilities are in the range of 93 to 95% for all processes. In each case, capital and operating costs have been developed for a recycling plant which processes 100,000 electric vehicle batteries per year. These costs have been developed based on material and energy balances, equipment lists, factored installation costs, and manpower estimates. In general, there are no technological barriers for recycling in the Nickel/Zinc, Nickel/Iron, Zinc/Chlorine and Zinc/Bromine battery systems. The recycling processes are based on essentially conventional, demonstrate technology. The lead times required to build battery recycling plants based on these processes is comparable to that of any other new plant. The total elapsed time required from inception to plant operation is approximately 3 to 5 y. The recycling process for the sodium/sulfur and lithium-aluminum/sulfide battery systems are not based on conventional technology. In particular, mechanical systems for dismantling these batteries must be developed.

  10. Comparison of a synergetic battery pack drive system to a pulse width modulated AC induction motor drive for an electric vehicle

    SciTech Connect (OSTI)

    Davis, A.; Salameh, Z.M.; Eaves, S.S.

    1999-06-01

    A new battery configuration technique and accompanying control circuitry, termed a Synergetic Battery Pack (SBP), is designed to work with Lithium batteries, and can be used as both an inverter for an electric vehicle AC induction motor drive and as a battery charger. In this paper, the performance of a Synergetic Battery Pack during motor drive operation is compared via computer simulation with a conventional motor drive which uses sinusoidal pulse width modulation (SPWM) to determine its effectiveness as a motor drive. The study showed that the drive efficiency was compatible with the conventional system, and offered a significant advantage in the lower frequency operating ranges. The voltage total harmonic distortion (THD) of the SBP was significantly lower than the PWM drive output, but the current THD was slightly higher due to the shape of the harmonic spectrum. In conclusion, the SBP is an effective alternative to a conventional drive, but the real advantage lies in its battery management capabilities and charger operation.

  11. Battery system with temperature sensors

    DOE Patents [OSTI]

    Wood, Steven J.; Trester, Dale B.

    2012-11-13

    A battery system to monitor temperature includes at least one cell with a temperature sensing device proximate the at least one cell. The battery system also includes a flexible member that holds the temperature sensor proximate to the at least one cell.

  12. Scientists View Battery Under Microscope

    SciTech Connect (OSTI)

    2015-04-10

    PNNL researchers use a special microscope setup that shows the inside of a battery as it charges and discharges. This battery-watching microscope is located at EMSL, DOE's Environmental Molecular Sciences Laboratory that resides at PNNL. Researchers the world over can visit EMSL and use special instruments like this, many of which are the only one of their kind available to scientists.

  13. Redox Flow Batteries, a Review

    SciTech Connect (OSTI)

    U. Tennessee Knoxville; U. Texas Austin; McGill U; Weber, Adam Z.; Mench, Matthew M.; Meyers, Jeremy P.; Ross, Philip N.; Gostick, Jeffrey T.; Liu, Qinghua

    2011-07-15

    Redox flow batteries are enjoying a renaissance due to their ability to store large amounts of electrical energy relatively cheaply and efficiently. In this review, we examine the components of redox flow batteries with a focus on understanding the underlying physical processes. The various transport and kinetic phenomena are discussed along with the most common redox couples.

  14. Hydraulic seal battery terminal

    SciTech Connect (OSTI)

    Stadnick, S.J.

    1980-09-23

    A self-sealing battery terminal is described that includes a hydroformed Inconel outer case, a low shear strength sealant material, and a central post in the form of a bolt which acts as both a conductor and transmits the preload from a pair of Belleville washers to a lower ceramic washer. The lower ceramic washer acts like a piston to compress the sealant when the nut on the central post is tightened. The Belleville washers serve to maintain a minimum tension on the central post. A top ceramic washer is held in place by the tension in the central bolt as long as the tension exceeds a minimum value.

  15. Crash Models for Automotive Batteries (DOT/NHTSA Project Report)

    SciTech Connect (OSTI)

    Turner, John A; Allu, Srikanth; Gorti, Sarma B; Kalnaus, Sergiy; Lebrun-Grandie, Damien T; Pannala, Dr. Sreekanth; Simunovic, Srdjan; Slattery, Stuart R; Wang, Hsin

    2016-01-01

    Safety is a critical aspect of lithium-ion (Li-ion) battery design. Impact/crash conditions can trigger a complex interplay of mechanical contact, heat generation and electrical discharge which can result in thermal events. Thermal events have been linked to internal short circuits that are initiated by a critical size of short-circuit area. Different loading conditions and battery states may lead to micro (soft) shorts where burnout due to generated heat eliminates contact between the electrodes, or persistent (hard) shorts which can lead to more significant thermal events and potentially damage the entire battery system and beyond. Experimental characterization of individual battery components for the onset of internal shorts is limited, since it is impractical to canvas all possible variations in battery state of charge, operating conditions, and impact loading in a timely manner. This report provides a survey of modeling and simulation approaches and documents the first phase of a project initiated and funded by DOT/NHTSA to improve modeling and simulation capabilities in order to design tests that provide leading indicators of failure in batteries. In this phase, ORNL has demonstrated a computational infrastructure to conduct impact simulations of Li-ion batteries using models that resolve internal structures and electro-thermo-chemical and mechanical conditions. Initial comparisons to abuse experiments on cells and cell strings conducted at ORNL and Carderock for parameter estimation and model validation have been performed. This research has provided unique insight into the underlying kinematic mechanisms of deformation (both at cell and electrode level) and their relationship to the safety of batteries. The second step was to conduct higher-speed crush experiments and simulations to more closely approximate the effect of vehicle impact.

  16. Predicting the voltage dependence of interfacial electrochemical...

    Office of Scientific and Technical Information (OSTI)

    interfacial electrochemical processes at lithium-intercalated graphite edge planes ... Subject: bio-inspired, energy storage (including batteries and capacitors), defects, ...

  17. Electric Drive and Advanced Battery and Components Testbed (EDAB)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Feb 25 2013 Description / Specification Vehicle Configuration Series PHEV Traction Motor UQM 145 kW / single-speed gearbox APU UQM 145 kW / 5.3L gasoline engine Battery Pack Manufacturer EnerDel Model Type I EV Pack (A306) Chemistry Li-ion Cathode Mixed Oxide (Modified NMC) Anode Amorphous Hard Carbon Configuration 4 parallel strings of 96 cells Rated Capacity (Ah) 70 Nominal Voltage (V) 345 Pack mass (kg) 285 Cooling Type Passive (sealed enclosure) ESS Reference Performance Testing Results

  18. Electric Drive and Advanced Battery and Components Testbed (EDAB)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 2012 through June 6 2013 Description / Specification Vehicle Configuration Series PHEV Traction Motor UQM 145 kW / single-speed gearbox APU UQM 145 kW / 5.3L gasoline engine Battery Pack Manufacturer EnerDel Model Type I EV Pack (A306) Chemistry Li-ion Cathode Mixed Oxide (Modified NMC) Anode Amorphous Hard Carbon Configuration 4 parallel strings of 96 cells Rated Capacity (Ah) 70 Nominal Voltage (V) 345 Pack mass (kg) 285 Cooling Type Passive (sealed enclosure) ESS Reference Performance

  19. High voltage photovoltaic power converter

    DOE Patents [OSTI]

    Haigh, Ronald E.; Wojtczuk, Steve; Jacobson, Gerard F.; Hagans, Karla G.

    2001-01-01

    An array of independently connected photovoltaic cells on a semi-insulating substrate contains reflective coatings between the cells to enhance efficiency. A uniform, flat top laser beam profile is illuminated upon the array to produce electrical current having high voltage. An essentially wireless system includes a laser energy source being fed through optic fiber and cast upon the photovoltaic cell array to prevent stray electrical signals prior to use of the current from the array. Direct bandgap, single crystal semiconductor materials, such as GaAs, are commonly used in the array. Useful applications of the system include locations where high voltages are provided to confined spaces such as in explosive detonation, accelerators, photo cathodes and medical appliances.

  20. Battery Life Data Analysis

    Energy Science and Technology Software Center (OSTI)

    2008-07-01

    The FreedomCar Partnership has established life goals for batteries. Among them is a 15 year calendar life. The software and the underlying methodology attempt to predict cell and battery life using, at most, two years of test data. The software uses statistical models based on data from accelerated aging experiments to estimate cell life. The life model reflects the average cell performance under a given set of stress conditions with time. No specific form ofmore » the life model is assumed. The software will fit the model to experimental data. An error model, reflecting the cell-to-cell variability and measurement errors, is included in the software. Monte Carlo simulations, based on the developed models, are used to assess Lack-of-fit and develop uncertainty limis for the average cell life. The software has three operating modes: fit only, fit and simulation and simulation only. The user is given these options by means of means and alert boxes.« less

  1. The Science of Electrode Materials for Lithium Batteries

    SciTech Connect (OSTI)

    Fultz, Brent

    2007-03-15

    Rechargeable lithium batteries continue to play the central role in power systems for portable electronics, and could play a role of increasing importance for hybrid transportation systems that use either hydrogen or fossil fuels. For example, fuel cells provide a steady supply of power, whereas batteries are superior when bursts of power are needed. The National Research Council recently concluded that for dismounted soldiers "Among all possible energy sources, hybrid systems provide the most versatile solutions for meeting the diverse needs of the Future Force Warrior. The key advantage of hybrid systems is their ability to provide power over varying levels of energy use, by combining two power sources." The relative capacities of batteries versus fuel cells in a hybrid power system will depend on the capabilities of both. In the longer term, improvements in the cost and safety of lithium batteries should lead to a substantial role for electrochemical energy storage subsystems as components in fuel cell or hybrid vehicles. We have completed a basic research program for DOE BES on anode and cathode materials for lithium batteries, extending over 6 years with a 1 year phaseout period. The emphasis was on the thermodynamics and kinetics of the lithiation reaction, and how these pertain to basic electrochemical properties that we measure experimentally — voltage and capacity in particular. In the course of this work we also studied the kinetic processes of capacity fade after cycling, with unusual results for nanostructued Si and Ge materials, and the dynamics underlying electronic and ionic transport in LiFePO4. This document is the final report for this work.

  2. BEST (Battery Economics for more Sustainable Transportation)

    Energy Science and Technology Software Center (OSTI)

    2009-12-31

    Computer software for the simulation of battery economics based on various transportation business models.

  3. Battery Thermal Management System Design Modeling (Presentation)

    SciTech Connect (OSTI)

    Kim, G-H.; Pesaran, A.

    2006-10-01

    Presents the objectives and motivations for a battery thermal management vehicle system design study.

  4. A Novel Integrated Magnetic Structure Based DC/DC Converter for Hybrid Battery/Ultracapacitor Energy Storage Systems

    SciTech Connect (OSTI)

    Onar, Omer C

    2012-01-01

    This manuscript focuses on a novel actively controlled hybrid magnetic battery/ultracapacitor based energy storage system (ESS) for vehicular propulsion systems. A stand-alone battery system might not be sufficient to satisfy peak power demand and transient load variations in hybrid and plug-in hybrid electric vehicles (HEV, PHEV). Active battery/ultracapacitor hybrid ESS provides a better solution in terms of efficient power management and control flexibility. Moreover, the voltage of the battery pack can be selected to be different than that of the ultracapacitor, which will result in flexibility of design as well as cost and size reduction of the battery pack. In addition, the ultracapacitor bank can supply or recapture a large burst of power and it can be used with high C-rates. Hence, the battery is not subjected to supply peak and sharp power variations, and the stress on the battery will be reduced and the battery lifetime would be increased. Utilizing ultracapacitor results in effective capturing of the braking energy, especially in sudden braking conditions.

  5. Eliminate Voltage Unbalance | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Voltage unbalance degrades the performance and shortens the life of a three-phase motor. Voltage unbalance at the motor terminals can cause current unbalance that is far out of ...

  6. Eliminate Excessive In-Plant Distribution System Voltage Drops

    Broader source: Energy.gov [DOE]

    Studies indicate that in-plant electrical distribution system losses—due to voltage unbalance, over- and undervoltage, low power factor, undersized conductors, leakage to ground, and poor connections—can account for less than 1% to more than 4% of total plant electrical energy consumption.

  7. Load Leveling Battery System Costs

    Energy Science and Technology Software Center (OSTI)

    1994-10-12

    SYSPLAN evaluates capital investment in customer side of the meter load leveling battery systems. Such systems reduce the customer's monthly electrical demand charge by reducing the maximum power load supplied by the utility during the customer's peak demand. System equipment consists of a large array of batteries, a current converter, and balance of plant equipment and facilities required to support the battery and converter system. The system is installed on the customer's side of themore » meter and controlled and operated by the customer. Its economic feasibility depends largely on the customer's load profile. Load shape requirements, utility rate structures, and battery equipment cost and performance data serve as bases for determining whether a load leveling battery system is economically feasible for a particular installation. Life-cycle costs for system hardware include all costs associated with the purchase, installation, and operation of battery, converter, and balance of plant facilities and equipment. The SYSPLAN spreadsheet software is specifically designed to evaluate these costs and the reduced demand charge benefits; it completes a 20 year period life cycle cost analysis based on the battery system description and cost data. A built-in sensitivity analysis routine is also included for key battery cost parameters. The life cycle cost analysis spreadsheet is augmented by a system sizing routine to help users identify load leveling system size requirements for their facilities. The optional XSIZE system sizing spreadsheet which is included can be used to identify a range of battery system sizes that might be economically attractive. XSIZE output consisting of system operating requirements can then be passed by the temporary file SIZE to the main SYSPLAN spreadsheet.« less

  8. MEDIUM VOLTAGE INTEGRATED DRIVE AND MOTOR

    Broader source: Energy.gov [DOE]

    Calnetix Technologies – Cerritos, CA This project will focus on integrating a high voltage SiC device with advanced high-speed machine technology, medium voltage stators, high efficiency magnetic bearings and sensor high frequency drive technology that can work directly with high voltages, switch at high frequencies for low machine losses, and do so very efficiently. The new medium voltage motors are expected to achieve up to eight times the power density of similar traditional systems. Fact sheet coming soon.

  9. Vehicle Technologies Office: Batteries | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plug-in Electric Vehicles & Batteries » Vehicle Technologies Office: Batteries Vehicle Technologies Office: Batteries Vehicle Technologies Office: Batteries Improving the batteries for electric drive vehicles, including hybrid electric (HEV) and plug-in electric (PEV) cars, is key to improving vehicles' economic, social, and environmental sustainability. In fact, transitioning to a light-duty fleet of HEVs and PEVs could reduce U.S. foreign oil dependence by 30-60% and greenhouse gas

  10. Cell for making secondary batteries

    DOE Patents [OSTI]

    Visco, S.J.; Liu, M.; DeJonghe, L.C.

    1992-11-10

    The present invention provides all solid-state lithium and sodium batteries operating in the approximate temperature range of ambient to 145 C (limited by melting points of electrodes/electrolyte), with demonstrated energy and power densities far in excess of state-of-the-art high-temperature battery systems. The preferred battery comprises a solid lithium or sodium electrode, a polymeric electrolyte such as polyethylene oxide doped with lithium trifluorate (PEO[sub 8]LiCF[sub 3]SO[sub 3]), and a solid-state composite positive electrode containing a polymeric organosulfur electrode, (SRS)[sub n], and carbon black, dispersed in a polymeric electrolyte. 2 figs.

  11. Cell for making secondary batteries

    DOE Patents [OSTI]

    Visco, Steven J.; Liu, Meilin; DeJonghe, Lutgard C.

    1992-01-01

    The present invention provides all solid-state lithium and sodium batteries operating in the approximate temperature range of ambient to 145.degree. C. (limited by melting points of electrodes/electrolyte), with demonstrated energy and power densities far in excess of state-of-the-art high-temperature battery systems. The preferred battery comprises a solid lithium or sodium electrode, a polymeric electrolyte such as polyethylene oxide doped with lithium triflate (PEO.sub.8 LiCF.sub.3 SO.sub.3), and a solid-state composite positive electrode containing a polymeric organosulfur electrode, (SRS).sub.n, and carbon black, dispersed in a polymeric electrolyte.

  12. Solid polymer battery electrolyte and reactive metal-water battery

    DOE Patents [OSTI]

    Harrup, Mason K.; Peterson, Eric S.; Stewart, Frederick F.

    2000-01-01

    In one implementation, a reactive metal-water battery includes an anode comprising a metal in atomic or alloy form selected from the group consisting of periodic table Group 1A metals, periodic table Group 2A metals and mixtures thereof. The battery includes a cathode comprising water. Such also includes a solid polymer electrolyte comprising a polyphosphazene comprising ligands bonded with a phosphazene polymer backbone. The ligands comprise an aromatic ring containing hydrophobic portion and a metal ion carrier portion. The metal ion carrier portion is bonded at one location with the polymer backbone and at another location with the aromatic ring containing hydrophobic portion. The invention also contemplates such solid polymer electrolytes use in reactive metal/water batteries, and in any other battery.

  13. Portable battery-free charger for radiation dosimeters

    DOE Patents [OSTI]

    Manning, Frank W.

    1984-01-01

    This invention is a novel portable charger for dosimeters of the electrometer type. The charger does not require batteries or piezoelectric crystals and is of rugged construction. In a preferred embodiment, the charge includes a housing which carries means for mounting a dosimeter to be charged. The housing also includes contact means for impressing a charging voltage across the mounted dosimeter. Also, the housing carries a trigger for operating a charging system mounted in the housing. The charging system includes a magnetic loop including a permanent magnet for establishing a magnetic field through the loop. A segment of the loop is coupled to the trigger for movement thereby to positions opening and closing the loop. A coil inductively coupled with the loop generates coil-generated voltage pulses when the trigger is operated to open and close the loop. The charging system includes an electrical circuit for impressing voltage pulses from the coil across a capacitor for integrating the pulses and applying the resulting integrated voltage across the above-mentioned contact means for charging the dosimeter.

  14. A symmetric organic-based nonaqueous redox flow battery and its state of charge diagnostics by FTIR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Duan, Wentao; Vemuri, Rama Ses; Milshtein, Jarrod D.; Laramie, Sydney; Dmello, Rylan D.; Huang, Jinhua; Zhang, Lu; Hu, Dehong; Vijayakumar, M.; Wang, Wei; et al

    2016-03-10

    Redox flow batteries have shown outstanding promise for grid-scale energy storage to promote utilization of renewable energy and improve grid stability. Nonaqueous battery systems can potentially achieve high energy density because of their broad voltage window. In this paper, we report a new organic redox-active material for use in a nonaqueous redox flow battery, 2-phenyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide (PTIO) that has high solubility (>2.6 M) in organic solvents. PTIO exhibits electrochemically reversible disproportionation reactions and thus can serve as both anolyte and catholyte redox materials in a symmetric flow cell. The PTIO flow battery has a moderate cell voltage of ~1.7 V andmore » shows good cyclability under both cyclic voltammetry and flow cell conditions. Moreover, we demonstrate that FTIR can offer accurate estimation of the PTIO concentration in electrolytes and determine the state of charge of the PTIO flow cell, which suggests FTIR potentially as a powerful online battery status sensor. In conclusion, this study is expected to inspire more insights in this under-addressed area of state of charge analysis aiming at operational safety and reliability of flow batteries.« less

  15. Final Progress Report for Linking Ion Solvation and Lithium Battery

    Office of Scientific and Technical Information (OSTI)

    for Linking Ion Solvation and Lithium Battery Electrolyte Properties Henderson, Wesley 25 ENERGY STORAGE battery, electrolyte, solvation, ionic association battery, electrolyte,...

  16. Battery Lifetime Analysis and Simulation Tool (BLAST) Documentation

    Office of Scientific and Technical Information (OSTI)

    Battery Lifetime Analysis and Simulation Tool (BLAST) Documentation Neubauer, J. 25 ENERGY STORAGE BATTERY; LITHIUM-ION; STATIONARY ENERGY STORAGE; BLAST; BATTERY DEGRADATION;...

  17. Leading experts to speak at battery & energy storage technology...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    including: new battery chemistries, battery longevity and performance, energy storage in electric grid applications and the latest developments in fuel cells and flow batteries. ...

  18. ZAP Advanced Battery Technologies JV | Open Energy Information

    Open Energy Info (EERE)

    battery manufacturer Advanced Battery Technologies focusing on manufacturing and marketing of advanced batteries for electric cars using the latest in nanotechnology....

  19. Hunan Copower EV Battery Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Copower EV Battery Co Ltd Jump to: navigation, search Name: Hunan Copower EV Battery Co Ltd Place: Hunan Province, China Sector: Vehicles Product: Producer of batteries and...

  20. Guangzhou Fullriver Battery New Technology Co Ltd | Open Energy...

    Open Energy Info (EERE)

    Fullriver Battery New Technology Co, Ltd Place: China Product: China-based maker of Lithium Polymer and Lithium Iron batteries as well protection circuit modules and battery...

  1. Estimating the system price of redox flow batteries for grid...

    Office of Scientific and Technical Information (OSTI)

    Estimating the system price of redox flow batteries for grid storage Citation Details ... Subject: energy storage; flow battery; grid storage; lithium-ion battery; manufacturing ...

  2. Fact Sheet: Vanadium Redox Flow Batteries (October 2012)

    Office of Environmental Management (EM)

    temperature window by 83%, so the battery can operate between -5 and 50C. Other ... Old Battery Technology New Battery Technology The benefits of the new electrolyte include: ...

  3. EERE Success Story-Colorado: Isothermal Battery Calorimeter Quantifies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer, Longer-lasting Batteries EERE Success Story-Colorado: Isothermal Battery Calorimeter Quantifies ...

  4. Computer-Aided Engineering for Electric Drive Vehicle Batteries...

    Broader source: Energy.gov (indexed) [DOE]

    Overview of Computer-Aided Engineering of Batteries (CAEBAT) and Introduction to Multi-Scale, Multi-Dimensional (MSMD) Modeling of Lithium-Ion Batteries Battery Thermal Modeling ...

  5. EV Everywhere Batteries Workshop - Materials Processing and Manufactur...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications EV Everywhere Batteries Workshop - Next Generation Lithium Ion Batteries Breakout Session Report EV Everywhere Batteries Workshop - Beyond Lithium Ion ...

  6. Recent Developments and Trends in Redox Flow Batteries - Joint...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 1, 2015, Research Highlights Recent Developments and Trends in Redox Flow Batteries Different flow batteries schemes were investigated. The classic flow battery (top left, ...

  7. Sandia National Laboratories: Due Diligence on Lead Acid Battery...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Due Diligence on Lead Acid Battery Recycling March 23, 2011 Lead Acid Batteries on secondary containment pallet Lead Acid Batteries on secondary containment pallet In 2004, the US...

  8. Battery Ownership Model - Medium Duty HEV Battery Leasing & Standardization

    SciTech Connect (OSTI)

    Kelly, Ken; Smith, Kandler; Cosgrove, Jon; Prohaska, Robert; Pesaran, Ahmad; Paul, James; Wiseman, Marc

    2015-12-01

    Prepared for the U.S. Department of Energy, this milestone report focuses on the economics of leasing versus owning batteries for medium-duty hybrid electric vehicles as well as various battery standardization scenarios. The work described in this report was performed by members of the Energy Storage Team and the Vehicle Simulation Team in NREL's Transportation and Hydrogen Systems Center along with members of the Vehicles Analysis Team at Ricardo.

  9. Pushing the Theoretical Limit of Li-CFx Batteries: A Tale of Bi-functional Electrolyte

    SciTech Connect (OSTI)

    Rangasamy, Ezhiylmurugan; Li, Juchuan; Sahu, Gayatri; Dudney, Nancy J; Liang, Chengdu

    2014-01-01

    In a typical battery, electrodes deliver capacities less or equal the theoretical maxima of the electrode materials.1 The inert electrolyte functions solely as the ionic conductor without contribution to the cell capacity because of its distinct mono-function in the concept of conventional batteries. Here we demonstrate that the most energy-dense Li-CFx battery2 delivers a capacity exceeding the theoretical maximum of CFx with a solid electrolyte of Li3PS4 (LPS) that has dual functions: as the inert electrolyte at the anode and the active component at the cathode. Such a bi-functional electrolyte reconciles both inert and active characteristics through a synergistic discharge mechanism of CFx and LPS. Li3PS4 is known as an inactive solid electrolyte with a broad electrochemical window over 5 V.3 The synergy at the cathode is through LiF, the discharge product of CFx, which activates the electrochemical discharge of LPS at a close electrochemical potential of CFx. Therefore, the solid-state Li-CFx batteries output 126.6% energy beyond their theoretic limits without compromising the stability of the cell voltage. The extra energy comes from the electrochemical discharge of LPS, the inert electrolyte. This bi-functional electrolyte revolutionizes the concept of conventional batteries and opens a new avenue for the design of batteries with an unprecedentedly high energy density.

  10. High Energy Density Na-S/NiCl2 Hybrid Battery

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Lemmon, John P.; Kim, Jin Yong; Sprenkle, Vincent L.; Yang, Zhenguo

    2013-02-15

    High temperature (250-350C) sodium-beta alumina batteries (NBBs) are attractive energy storage devices for renewable energy integration and other grid related applications. Currently, two technologies are commercially available in NBBs, e.g., sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries. In this study, we investigated the combination of these two chemistries with a mixed cathode. In particular, the cathode of the cell consisted of molten NaAlCl4 as a catholyte and a mixture of Ni, NaCl and Na2S as active materials. During cycling, two reversible plateaus were observed in cell voltage profiles, which matched electrochemical reactions for Na-S and Na-NiCl2 redox couples. An irreversible reaction between sulfur species and Ni was identified during initial charge at 280C, which caused a decrease in cell capacity. The final products on discharge included Na2Sn with 1< n < 3, which differed from Na2S3 found in traditional Na-S battery. Reduction of sulfur in the mixed cathode led to an increase in overall energy density over ZEBRA batteries. Despite of the initial drop in cell capacity, the mixed cathode demonstrated relatively stable cycling with more than 95% of capacity retained over 60 cycles under 10mA/cm2. Optimization of the cathode may lead to further improvements in battery performance.

  11. Non-contact current and voltage sensor having detachable housing incorporating multiple ferrite cylinder portions

    DOE Patents [OSTI]

    Carpenter, Gary D.; El-Essawy, Wael; Ferreira, Alexandre Peixoto; Keller, Thomas Walter; Rubio, Juan C.; Schappert, Michael A.

    2016-04-26

    A detachable current and voltage sensor provides an isolated and convenient device to measure current passing through a conductor such as an AC branch circuit wire, as well as providing an indication of an electrostatic potential on the wire, which can be used to indicate the phase of the voltage on the wire, and optionally a magnitude of the voltage. The device includes a housing formed from two portions that mechanically close around the wire and that contain the current and voltage sensors. The current sensor is a ferrite cylinder formed from at least three portions that form the cylinder when the sensor is closed around the wire with a hall effect sensor disposed in a gap between two of the ferrite portions along the circumference to measure current. A capacitive plate or wire is disposed adjacent to, or within, the ferrite cylinder to provide the indication of the voltage.

  12. Non-contact current and voltage sensing method using a clamshell housing and a ferrite cylinder

    DOE Patents [OSTI]

    Carpenter, Gary D.; El-Essawy, Wael; Ferreira, Alexandre Peixoto; Keller, Thomas Walter; Rubio, Juan C.; Schappert, Michael

    2016-04-26

    A method of measurement using a detachable current and voltage sensor provides an isolated and convenient technique for to measuring current passing through a conductor such as an AC branch circuit wire, as well as providing an indication of an electrostatic potential on the wire, which can be used to indicate the phase of the voltage on the wire, and optionally a magnitude of the voltage. The device includes a housing that contains the current and voltage sensors, which may be a ferrite cylinder with a hall effect sensor disposed in a gap along the circumference to measure current, or alternative a winding provided through the cylinder along its axis and a capacitive plate or wire disposed adjacent to, or within, the ferrite cylinder to provide the indication of the voltage.

  13. VOLTAGE-CONTROLLED TRANSISTOR OSCILLATOR

    DOE Patents [OSTI]

    Scheele, P.F.

    1958-09-16

    This patent relates to transistor oscillators and in particular to those transistor oscillators whose frequencies vary according to controlling voltages. A principal feature of the disclosed transistor oscillator circuit resides in the temperature compensation of the frequency modulating stage by the use of a resistorthermistor network. The resistor-thermistor network components are selected to have the network resistance, which is in series with the modulator transistor emitter circuit, vary with temperature to compensate for variation in the parameters of the transistor due to temperature change.

  14. High voltage RF feedthrough bushing

    DOE Patents [OSTI]

    Grotz, Glenn F.

    1984-01-01

    Described is a multi-element, high voltage radio frequency bushing for trmitting RF energy to an antenna located in a vacuum container. The bushing includes a center conductor of complex geometrical shape, an outer coaxial shield conductor, and a thin-walled hollow truncated cone insulator disposed between central and outer conductors. The shape of the center conductor, which includes a reverse curvature portion formed of a radially inwardly directed shoulder and a convex portion, controls the uniformity of the axial surface gradient on the insulator cone. The outer shield has a first substantially cylindrical portion and a second radially inwardly extending truncated cone portion.

  15. Rechargeable Aluminum-Ion Batteries

    SciTech Connect (OSTI)

    Paranthaman, Mariappan Parans; Liu, Hansan; Sun, Xiao-Guang; Dai, Sheng; Brown, Gilbert M

    2015-01-01

    This chapter reports on the development of rechargeable aluminum-ion batteries. A possible concept of rechargeable aluminum/aluminum-ion battery based on low-cost, earth-abundant Al anode, ionic liquid EMImCl:AlCl3 (1-ethyl-3-methyl imidazolium chloroaluminate) electrolytes and MnO2 cathode has been proposed. Al anode has been reported to show good reversibility in acid melts. However, due to the problems in demonstrating the reversibility in cathodes, alternate battery cathodes and battery concepts have also been presented. New ionic liquid electrolytes for reversible Al dissolution and deposition are needed in the future for replacing corrosive EMImCl:AlCl3 electrolytes.

  16. Thermal battery with composite anode

    SciTech Connect (OSTI)

    Higley, L.R.

    1990-11-06

    This patent describes a thermal battery for generating electrical energy. It comprises: a sodium composite electrode comprising sodium metal and a protective metal; a cathode; and a separator located between the sodium composite electrode and the cathode.

  17. Electroactive materials for rechargeable batteries

    DOE Patents [OSTI]

    Wu, Huiming; Amine, Khalil; Abouimrane, Ali

    2015-04-21

    An as-prepared cathode for a secondary battery, the cathode including an alkaline source material including an alkali metal oxide, an alkali metal sulfide, an alkali metal salt, or a combination of any two or more thereof.

  18. Intercalation compounds and electrodes for batteries

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Sadoway, Donald R.; Jang, Young-Il; Huang, Biyan

    2004-09-07

    This invention concerns intercalation compounds and in particular lithium intercalation compounds which have improved properties for use in batteries. Compositions of the invention include particulate metal oxide material having particles of multicomponent metal oxide, each including an oxide core of at least first and second metals in a first ratio, and each including a surface coating of metal oxide or hydroxide that does not include the first and second metals in the first ratio formed by segregation of at least one of the first and second metals from the core. The core may preferably comprise Li.sub.x M.sub.y N.sub.z O.sub.2 wherein M and N are metal atom or main group elements, x, y and z are numbers from about 0 to about 1 and y and z are such that a formal charge on M.sub.y N.sub.z portion of the compound is (4-x), and having a charging voltage of at least about 2.5V. The invention may also be characterized as a multicomponent oxide microstructure usable as a lithium intercalation material including a multiphase oxide core and a surface layer of one material, which is a component of the multiphase oxide core, that protects the underlying intercalation material from chemical dissolution or reaction. In a particular preferred example the multicomponent oxide may be an aluminum-doped lithium manganese oxide composition. Such aluminum-doped lithium manganese oxide compositions, having an orthorhombic structure, also form a part of the invention. In addition, the invention includes articles, particularly electrodes, for batteries formed from the compositions of the invention, and batteries including such electrodes. The invention further relates to a composite intercalation material comprising at least two compounds in which at least one compound has an orthorhombic structure Li.sub.x Al.sub.y Mn.sub.1-y O.sub.2, where y is nonzero, or a mixture of orthorhombic and monoclinic Li.sub.x Al.sub.y Mn.sub.1-y O.sub.2.

  19. Method for voltage-gated protein fractionation (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Method for voltage-gated protein fractionation Title: Method for voltage-gated protein fractionation We report unique findings on the voltage dependence of protein exclusion from ...

  20. Applying the Battery Ownership Model in Pursuit of Optimal Battery Use Strategies (Presentation)

    SciTech Connect (OSTI)

    Neubauer, J.; Ahmad, P.; Brooker, A.; Wood, E.; Smith, K.; Johnson, C.; Mendelsohn, M.

    2012-05-01

    This Annual Merit Review presentation describes the application of the Battery Ownership Model for strategies for optimal battery use in electric drive vehicles (PEVs, PHEVs, and BEVs).

  1. The Battery Storage Hub is Making the Battery of the Future ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    September 8, 2014, Videos The Battery Storage Hub is Making the Battery of the Future Deputy Director Jeff Chamberlain (JCESR) details how JCESR research is aimed at developing ...

  2. Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer, Longer-lasting Batteries

    Broader source: Energy.gov [DOE]

    Partnered with NETZSCH, the National Renewable Energy Laboratory (NREL) developed an Isothermal Battery Calorimeter (IBC) used to quantify heat flow in battery cells and modules.

  3. Johnson Controls Develops an Improved Vehicle Battery, Works to Cut Battery Costs in Half

    Broader source: Energy.gov [DOE]

    Johnson Controls is working to increase energy density of vehicle batteries while reducing manufacturing costs for lithium-ion battery cells.

  4. Reinventing Batteries for Grid Storage

    SciTech Connect (OSTI)

    Banerjee, Sanjoy

    2012-01-01

    The City University of New York's Energy Institute, with the help of ARPA-E funding, is creating safe, low cost, rechargeable, long lifecycle batteries that could be used as modular distributed storage for the electrical grid. The batteries could be used at the building level or the utility level to offer benefits such as capture of renewable energy, peak shaving and microgridding, for a safer, cheaper, and more secure electrical grid.

  5. Batteries using molten salt electrolyte

    DOE Patents [OSTI]

    Guidotti, Ronald A.

    2003-04-08

    An electrolyte system suitable for a molten salt electrolyte battery is described where the electrolyte system is a molten nitrate compound, an organic compound containing dissolved lithium salts, or a 1-ethyl-3-methlyimidazolium salt with a melting temperature between approximately room temperature and approximately 250.degree. C. With a compatible anode and cathode, the electrolyte system is utilized in a battery as a power source suitable for oil/gas borehole applications and in heat sensors.

  6. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, M.; Abraham, K.M.

    1993-10-12

    This invention pertains to Lithium batteries using Li ion (Li[sup +]) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride). 3 figures.

  7. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, Mohamed; Abraham, Kuzhikalail M.

    1993-01-01

    This invention pertains to Lithium batteries using Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride).

  8. Alkali metal/sulfur battery

    DOE Patents [OSTI]

    Anand, Joginder N.

    1978-01-01

    Alkali metal/sulfur batteries in which the electrolyte-separator is a relatively fragile membrane are improved by providing means for separating the molten sulfur/sulfide catholyte from contact with the membrane prior to cooling the cell to temperatures at which the catholyte will solidify. If the catholyte is permitted to solidify while in contact with the membrane, the latter may be damaged. The improvement permits such batteries to be prefilled with catholyte and shipped, at ordinary temperatures.

  9. Reinventing Batteries for Grid Storage

    ScienceCinema (OSTI)

    Banerjee, Sanjoy

    2013-05-29

    The City University of New York's Energy Institute, with the help of ARPA-E funding, is creating safe, low cost, rechargeable, long lifecycle batteries that could be used as modular distributed storage for the electrical grid. The batteries could be used at the building level or the utility level to offer benefits such as capture of renewable energy, peak shaving and microgridding, for a safer, cheaper, and more secure electrical grid.

  10. Microsoft Word - RelaxedBattery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Persistent State-of-Charge Heterogeneity in Fully Relaxed Battery Electrode Particles Lithium ion batteries are used ubiquitously for portable energy storage in today's modern electronic devices and have served in that capacity for decades. Recently, budding energy storage markets - such as those of electric vehicles, large-scale renewable energy storage, and grid balancing - have emerged that require storage capabilities that are beyond what today's lithium ion technologies currently provide.

  11. Low power, scalable multichannel high voltage controller

    DOE Patents [OSTI]

    Stamps, James Frederick; Crocker, Robert Ward; Yee, Daniel Dadwa; Dils, David Wright

    2008-03-25

    A low voltage control circuit is provided for individually controlling high voltage power provided over bus lines to a multitude of interconnected loads. An example of a load is a drive for capillary channels in a microfluidic system. Control is distributed from a central high voltage circuit, rather than using a number of large expensive central high voltage circuits to enable reducing circuit size and cost. Voltage is distributed to each individual load and controlled using a number of high voltage controller channel switches connected to high voltage bus lines. The channel switches each include complementary pull up and pull down photo isolator relays with photo isolator switching controlled from the central high voltage circuit to provide a desired bus line voltage. Switching of the photo isolator relays is further controlled in each channel switch using feedback from a resistor divider circuit to maintain the bus voltage swing within desired limits. Current sensing is provided using a switched resistive load in each channel switch, with switching of the resistive loads controlled from the central high voltage circuit.

  12. Low power, scalable multichannel high voltage controller

    DOE Patents [OSTI]

    Stamps, James Frederick; Crocker, Robert Ward; Yee, Daniel Dadwa; Dils, David Wright

    2006-03-14

    A low voltage control circuit is provided for individually controlling high voltage power provided over bus lines to a multitude of interconnected loads. An example of a load is a drive for capillary channels in a microfluidic system. Control is distributed from a central high voltage circuit, rather than using a number of large expensive central high voltage circuits to enable reducing circuit size and cost. Voltage is distributed to each individual load and controlled using a number of high voltage controller channel switches connected to high voltage bus lines. The channel switches each include complementary pull up and pull down photo isolator relays with photo isolator switching controlled from the central high voltage circuit to provide a desired bus line voltage. Switching of the photo isolator relays is further controlled in each channel switch using feedback from a resistor divider circuit to maintain the bus voltage swing within desired limits. Current sensing is provided using a switched resistive load in each channel switch, with switching of the resistive loads controlled from the central high voltage circuit.

  13. Thermal Batteries for Electric Vehicles

    SciTech Connect (OSTI)

    2011-11-21

    HEATS Project: UT Austin will demonstrate a high-energy density and low-cost thermal storage system that will provide efficient cabin heating and cooling for EVs. Compared to existing HVAC systems powered by electric batteries in EVs, the innovative hot-and-cold thermal batteries-based technology is expected to decrease the manufacturing cost and increase the driving range of next-generation EVs. These thermal batteries can be charged with off-peak electric power together with the electric batteries. Based on innovations in composite materials offering twice the energy density of ice and 10 times the thermal conductivity of water, these thermal batteries are expected to achieve a comparable energy density at 25% of the cost of electric batteries. Moreover, because UT Austin’s thermal energy storage systems are modular, they may be incorporated into the heating and cooling systems in buildings, providing further energy efficiencies and positively impacting the emissions of current building heating/cooling systems.

  14. Using all energy in a battery

    SciTech Connect (OSTI)

    Dudney, Nancy J.; Li, Juchuan

    2015-01-09

    It is not simple to pull all the energy from a battery. For a battery to discharge, electrons and ions have to reach the same place in the active electrode material at the same moment. To reach the entire volume of the battery and maximize energy use, internal pathways for both electrons and ions must be low-resistance and continuous, connecting all regions of the battery electrode. Traditional batteries consist of a randomly distributed mixture of conductive phases within the active battery material. In these materials, bottlenecks and poor contacts may impede effective access to parts of the battery. On page 149 of this issue, Kirshenbaum et al. (1) explore a different approach, in which silver electronic pathways form on internal surfaces as the battery is discharged. Finally, the electronic pathways are well distributed throughout the electrode, improving battery performance.

  15. Using all energy in a battery

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dudney, Nancy J.; Li, Juchuan

    2015-01-09

    It is not simple to pull all the energy from a battery. For a battery to discharge, electrons and ions have to reach the same place in the active electrode material at the same moment. To reach the entire volume of the battery and maximize energy use, internal pathways for both electrons and ions must be low-resistance and continuous, connecting all regions of the battery electrode. Traditional batteries consist of a randomly distributed mixture of conductive phases within the active battery material. In these materials, bottlenecks and poor contacts may impede effective access to parts of the battery. On pagemore » 149 of this issue, Kirshenbaum et al. (1) explore a different approach, in which silver electronic pathways form on internal surfaces as the battery is discharged. Finally, the electronic pathways are well distributed throughout the electrode, improving battery performance.« less

  16. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P.; Cunningham, R.; Hockings, K.

    1997-12-31

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  17. Radical Compatibility with Nonaqueous Electrolytes and Its Impact on an All-Organic Redox Flow Battery

    SciTech Connect (OSTI)

    Wei, Xiaoliang; Xu, Wu; Huang, Jinhua; Zhang, Lu; Walter, Eric D.; Lawrence, Chad W.; Vijayakumar, M.; Henderson, Wesley A.; Liu, Tianbiao L.; Cosimbescu, Lelia; Li, Bin; Sprenkle, Vincent L.; Wang, Wei

    2015-07-20

    Nonaqueous redox flow batteries hold the promise to achieve higher energy density ascribed to the broader voltage window than their aqueous counterparts, but their current performance is limited by low redox material concentration, poor cell efficiency, and inferior cycling stability. We report a new nonaqueous total-organic flow battery based on high concentrations of 9-fluorenone as negative and 2,5-di-tert-butyl-1-methoxy-4-[2’-methoxyethoxy]benzene as positive redox materials. The supporting electrolytes are found to greatly affect the cycling stability of flow cells through varying chemical stabilities of the charged radical species, especially the 9-fluorenone radical anions, as confirmed by electron spin resonance. Such an electrolyte optimization sheds light on mechanistic understandings of capacity fading in flow batteries employing organic radical-based redox materials and demonstrates that rational design of supporting electrolyte is vital for stable cyclability.

  18. Nanoscale Silicon as Anode for Li-ion Batteries: The Fundamentals, Promise, and Challenges

    SciTech Connect (OSTI)

    Gu, Meng; He, Yang; Zheng, Jianming; Wang, Chong M.

    2015-09-24

    Silicon (Si), associated with its natural abundance, low discharge voltage vs. Li/Li+, and extremely high theoretical discharge capacity (~ 4200 mAh g-1,), has been extensively explored as anode for lithium ion battery. One of the key challenges for using Si as anode is the large volume change upon lithiation and delithiation, which causes a fast capacity fading. Over the last few years, dramatic progress has been made for addressing this issue. In this paper, we summarize the progress towards tailoring of Si as anode for lithium ion battery. The paper is organized such that it covers the fundamentals, the promise offered based on nanoscale designing, and the remaining challenges that need to be attacked to allow using of Si based materials as anode for battery.

  19. Graphene-based battery electrodes having continuous flow paths...

    Office of Scientific and Technical Information (OSTI)

    Title: Graphene-based battery electrodes having continuous flow paths Some batteries can ... Metal-air batteries can benefit from such electrodes. In particular Li-air batteries show ...

  20. Optimal management of batteries in electric systems

    DOE Patents [OSTI]

    Atcitty, Stanley; Butler, Paul C.; Corey, Garth P.; Symons, Philip C.

    2002-01-01

    An electric system including at least a pair of battery strings and an AC source minimizes the use and maximizes the efficiency of the AC source by using the AC source only to charge all battery strings at the same time. Then one or more battery strings is used to power the load while management, such as application of a finish charge, is provided to one battery string. After another charge cycle, the roles of the battery strings are reversed so that each battery string receives regular management.

  1. Unexpected Type of Failure of Thermal Battery Resulting in a Near Miss to a Serious Injury

    SciTech Connect (OSTI)

    Richter, Daena Kei

    2015-10-01

    On 6/26/2015 at 1445 in 894/136, a thermal battery (approximately the size of a commercial size C cell) experienced an unexpected failure following a routine test where the battery is activated. The failure occurred while a test operator was transferring the battery from the testing primary containment box to another containment box within the same room; initial indications are that the battery package ruptured after it went into thermal runaway which led to the operator receiving bruising to the palm of the hand from the pressure of the expulsion. The operator was wearing the prescribed PPE, which was safety glasses and a high temperature glove on the hand that was holding the battery.

  2. Innovative Cathode Coating Enables Faster Battery Charging, Dischargin...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Faster Battery Charging, Discharging Technology available for licensing: Coating increases electrical conductivity of cathode materials Coating does not hinder battery ...

  3. EV Everywhere Batteries Workshop - Next Generation Lithium Ion...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications EV Everywhere Batteries Workshop - Beyond Lithium Ion Breakout Session Report EV Everywhere Batteries Workshop - Materials Processing and ...

  4. Section IV.D.3 for DOE 2013 Annual Report: Novel Phosphazene-based Compounds to Enhance Safety and Stability of Cell Chemistries for High Voltage Applications (INL)

    SciTech Connect (OSTI)

    Kevin L. Gering; Mason K. Harrup; Eric J. Dufek; Sergiy V. Sazhin; Harry W. Rollins; David K. Jamison; Fred F. Stewart; John Burba

    2013-09-01

    Electrolytes play a central role in performance and aging in most electrochemical systems. As automotive and grid applications place a higher reliance on electrochemical stored energy, it becomes more urgent to have electrolyte components that enable optimal battery performance while promoting battery safety and longevity. Safety remains a foremost concern for widespread utilization of Li-ion technology in electric-drive vehicles, especially as the focus turns to higher voltage systems (5V). This work capitalizes on the long established INL expertise regarding phosphazene chemistry, aimed at battery-viable compounds for electrolytes and electrodes that are highly tolerant to abusive conditions. This report showcases our 2013 work for the DOE applied battery research (ABR) program, wherein testing results are summarized for INL electrolytes and alternative anode materials.

  5. Probing the initiation of voltage decay in Li-rich layered cathode materials at the atomic scale

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yan; Ma, Cheng; Yang, Jihui; Li, Zicheng; Allard, Jr., Lawrence Frederick; Liang, Chengdu; Chi, Miaofang

    2015-01-01

    Li-rich layered oxides hold great promise for improving the energy density of present-day Li-ion batteries. However, their application is limited by the voltage decay upon cycling, and the origin of such a phenomenon is poorly understood. A major issue is determining the voltage range over which detrimental reactions originate. In the present study, a unique yet effective approach was employed to probe this issue. Instead of studying the materials during the first cycle, electrochemical behavior and evolution of the atomic structures were compared in extensively cycled specimens under varied charge/discharge voltages. With the upper cutoff voltage lowered from 4.8 tomore » 4.4 V, the voltage decay ceased to occur even after 60 cycles. In the meantime, the material maintained its layered structure without any spinel phase emerging at the surface, which is unambiguously shown by the atomic-resolution Z-contrast imaging and electron energy loss spectroscopy. These results have conclusively demonstrated that structural/chemical changes responsible for the voltage decay began between 4.4 and 4.8 V, where the layered-to-spinel transition was the most dramatic structural change observed. Thus, this discovery lays important groundwork for the mechanistic understanding of the voltage decay in Li-rich layered cathode materials.« less

  6. High voltage load resistor array

    DOE Patents [OSTI]

    Lehmann, Monty Ray

    2005-01-18

    A high voltage resistor comprising an array of a plurality of parallel electrically connected resistor elements each containing a resistive solution, attached at each end thereof to an end plate, and about the circumference of each of the end plates, a corona reduction ring. Each of the resistor elements comprises an insulating tube having an electrode inserted into each end thereof and held in position by one or more hose clamps about the outer periphery of the insulating tube. According to a preferred embodiment, the electrode is fabricated from stainless steel and has a mushroom shape at one end, that inserted into the tube, and a flat end for engagement with the end plates that provides connection of the resistor array and with a load.

  7. High voltage feed through bushing

    DOE Patents [OSTI]

    Brucker, J.P.

    1993-04-06

    A feed through bushing for a high voltage diode provides for using compression sealing for all sealing surfaces. A diode assembly includes a central conductor extending through the bushing and a grading ring assembly circumferentially surrounding and coaxial with the central conductor. A flexible conductive plate extends between and compressively seals against the central conductor and the grading ring assembly, wherein the flexibility of the plate allows inner and outer portions of the plate to axially translate for compression sealing against the central conductor and the grading ring assembly, respectively. The inner portion of the plate is bolted to the central conductor for affecting sealing. A compression beam is also bolted to the central conductor and engages the outer portion of the plate to urge the outer portion toward the grading ring assembly to obtain compression sealing therebetween.

  8. Rechargeable thin-film lithium batteries

    SciTech Connect (OSTI)

    Bates, J.B.; Gruzalski, G.R.; Dudney, N.J.; Luck, C.F.; Yu, X.

    1993-09-01

    Rechargeable thin-film batteries consisting of lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have been fabricated and characterized. These include Li-TiS{sub 2}, Li-V{sub 2}O{sub 5}, and Li-Li{sub x}Mn{sub 2}O{sub 4} cells with open circuit voltages at full charge of about 2.5 V, 3.7 V, and 4.2 V, respectively. The realization of these robust cells, which can be cycled thousands of times, was possible because of the stability of the amorphous lithium electrolyte, lithium phosphorus oxynitride. This material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46}and a conductivity at 25 C of 2 {mu}S/cm. The thin-film cells have been cycled at 100% depth of discharge using current densities of 5 to 100 {mu}A/cm{sup 2}. Over most of the charge-discharge range, the internal resistance appears to be dominated by the cathode, and the major source of the resistance is the diffusion of Li{sup +} ions from the electrolyte into the cathode. Chemical diffusion coefficients were determined from ac impedance measurements.

  9. Thin-film Rechargeable Lithium Batteries

    DOE R&D Accomplishments [OSTI]

    Bates, J. B.; Gruzalski, G. R.; Dudney, N. J.; Luck, C. F.; Yu, X.

    1993-11-01

    Rechargeable thin films batteries with lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have been fabricated and characterized. The cathodes include TiS{sub 2}, the {omega} phase of V{sub 2}O{sub 5}, and the cubic spinel Li{sub x}Mn{sub 2}O{sub 4} with open circuit voltages at full charge of about 2.5 V, 3.7 V, and 4.2 V, respectively. The development of these robust cells, which can be cycled thousands of times, was possible because of the stability of the amorphous lithium electrolyte, lithium phosphorus oxynitride. This material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46} and a conductivity at 25 C of 2 {mu}S/cm. Thin film cells have been cycled at 100% depth of discharge using current densities of 2 to 100 {mu}A/cm{sup 2}. The polarization resistance of the cells is due to the slow insertion rate of Li{sup +} ions into the cathode. Chemical diffusion coefficients for Li{sup +} ions in the three types of cathodes have been estimated from the analysis of ac impedance measurements.

  10. Understanding and managing the effects of battery charger and inverter aging

    SciTech Connect (OSTI)

    Gunther, W. ); Aggarwal, S. )

    1992-01-01

    An aging assessment of battery chargers and inverters was conducted under the auspices of the NRC's Nuclear Plant Aging Research (NPAR) Program. The intentions of this program are to resolve issues related to the aging and service wear of equipment and systems at operating reactor facilities and to assess their impact on safety. Inverters and battery chargers are used in nuclear power plants to perform significant functions related to plant safety and availability. The specific impact of a battery charger or inverter failure varies with plant configuration. Operating experience data have demonstrated that reactor trips, safety injection system actuations, and inoperable emergency core cooling systems have resulted from inverter failures; and dc bus degradation leading to diesel generator inoperability or loss of control room annunication and indication have resulted from battery and battery charger failures. For the battery charger and inverter, the aging and service wear of subcomponents have contributed significantly to equipment failures. This paper summarizes the data and then describes methods that can be used to detect battery charger and inverter degradation prior to failure, as well as methods to minimize the failure effects. In both cases, the managing of battery charger and inverter aging is emphasized. 5 refs.

  11. Understanding and managing the effects of battery charger and inverter aging

    SciTech Connect (OSTI)

    Gunther, W.; Aggarwal, S.

    1992-06-01

    An aging assessment of battery chargers and inverters was conducted under the auspices of the NRC`s Nuclear Plant Aging Research (NPAR) Program. The intentions of this program are to resolve issues related to the aging and service wear of equipment and systems at operating reactor facilities and to assess their impact on safety. Inverters and battery chargers are used in nuclear power plants to perform significant functions related to plant safety and availability. The specific impact of a battery charger or inverter failure varies with plant configuration. Operating experience data have demonstrated that reactor trips, safety injection system actuations, and inoperable emergency core cooling systems have resulted from inverter failures; and dc bus degradation leading to diesel generator inoperability or loss of control room annunication and indication have resulted from battery and battery charger failures. For the battery charger and inverter, the aging and service wear of subcomponents have contributed significantly to equipment failures. This paper summarizes the data and then describes methods that can be used to detect battery charger and inverter degradation prior to failure, as well as methods to minimize the failure effects. In both cases, the managing of battery charger and inverter aging is emphasized. 5 refs.

  12. Wind Power Plant Voltage Stability Evaluation: Preprint

    SciTech Connect (OSTI)

    Muljadi, E.; Zhang, Y. C.

    2014-09-01

    Voltage stability refers to the ability of a power system to maintain steady voltages at all buses in the system after being subjected to a disturbance from a given initial operating condition. Voltage stability depends on a power system's ability to maintain and/or restore equilibrium between load demand and supply. Instability that may result occurs in the form of a progressive fall or rise of voltages of some buses. Possible outcomes of voltage instability are the loss of load in an area or tripped transmission lines and other elements by their protective systems, which may lead to cascading outages. The loss of synchronism of some generators may result from these outages or from operating conditions that violate a synchronous generator's field current limit, or in the case of variable speed wind turbine generator, the current limits of power switches. This paper investigates the impact of wind power plants on power system voltage stability by using synchrophasor measurements.

  13. Katech (Lithium Polymer) 4-Passenger NEV - Range and Battery Testing Report

    SciTech Connect (OSTI)

    J. Francfort; D. Karner

    2005-07-01

    The U.S. Department of Energy’s (DOE’s) Advanced Vehicle Testing Activity (AVTA) received a Neighborhood Electric Vehicle (NEV) from the Korea Automotive Technology Institute (KATECH) for vehicle and battery characterization testing. The KATECH NEV (called the Invita) was equipped with a lithium polymer battery pack from Kokam Engineering. The Invita was to be baseline performance tested by AVTA’s testing partner, Electric Transportation Applications (ETA), at ETA’s contract testing facilities and test track in Phoenix, Arizona, to AVTA’s NEVAmerica testing specifications and procedures. Before and during initial constant speed range testing, the Invita battery pack experienced cell failures, and the onboard charger failed. A Kokamsupplied off-board charger was used in place of the onboard charger to successfully perform a constant speed range test on the Invita. The Invita traveled a total of 47.9 miles in 1 hour 47 minutes, consuming 91.3 amp-hours and 6.19 kilowatt-hours. The Kokam Engineering lithium polymer battery was also scheduled for battery pack characterization testing, including the C/3 energy capacity, dynamic stress, and peak power tests. Testing was stopped during the initial C/3 energy capacity test, however, because the battery pack failed to withstand cycling without cell failures. After the third discharge/charge sequence was completed, it was discovered that Cell 6 had failed, with a voltage reading of 0.5 volts. Cell 6 was replaced, and the testing sequence was restarted. After the second discharge/charge sequence was complete, it was discovered that Cell 1 had failed, with its voltage reading 0.2 volts. At this point it was decided to stop all battery pack testing. During the discharge cycles, the battery pack supplied 102.21, 94.34, and 96.05 amp-hours consecutively before Cell 6 failed. After replacing Cell 6, the battery pack supplied 98.34 and 98.11 amp-hours before Cell 1 failed. The Idaho National Laboratory managed these

  14. A metal-free organic-inorganic aqueous flow battery

    SciTech Connect (OSTI)

    Huskinson, B; Marshak, MP; Suh, C; Er, S; Gerhardt, MR; Galvin, CJ; Chen, XD; Aspuru-Guzik, A; Gordon, RG; Aziz, MJ

    2014-01-08

    As the fraction of electricity generation from intermittent renewable sources-such as solar or wind-grows, the ability to store large amounts of electrical energy is of increasing importance. Solid-electrode batteries maintain discharge at peak power for far too short a time to fully regulate wind or solar power output(1,2). In contrast, flow batteries can independently scale the power (electrode area) and energy (arbitrarily large storage volume) components of the system by maintaining all of the electro-active species in fluid form(3-5). Wide-scale utilization of flow batteries is, however, limited by the abundance and cost of these materials, particularly those using redox-active metals and precious-metal electrocatalysts(6,7). Here we describe a class of energy storage materials that exploits the favourable chemical and electro-chemical properties of a family of molecules known as quinones. The example we demonstrate is ametal-free flow battery based on the redox chemistry of 9,10-anthraquinone-2,7-disulphonic acid (AQDS). AQDS undergoes extremely rapid and reversible two-electron two-proton reduction on a glassy carbon electrode in sulphuric acid. An aqueous flow battery with inexpensive carbon electrodes, combining the quinone/hydroquinone couple with the Br-2/Br- redox couple, yields a peak galvanic power density exceeding 0.6 W cm(-2) at 1.3 A cm(-2). Cycling of this quinone-bromide flow battery showed >99 per cent storage capacity retention per cycle. The organic anthraquinone species can be synthesized from inexpensive commodity chemicals(8). This organic approach permits tuning of important properties such as the reduction potential and solubility by adding functional groups: for example, we demonstrate that the addition of two hydroxy groups to AQDS increases the open circuit potential of the cell by 11% and we describe a pathway for further increases in cell voltage. The use of p-aromatic redox-active organic molecules instead of redox-active metals

  15. Interfacial morphology of low-voltage anodic aluminium oxide

    SciTech Connect (OSTI)

    Hu, Naiping; Dongcinn, Xuecheng; He, Xueying; Argekar, Sandip; Zhang, Yan; Browning, Jim; Schaefer, Dale

    2013-01-01

    X-ray reflectivity (XRR) and neutron reflectivity (NR), as well as ultra-smallangle X-ray scattering (USAXS), are used to examine the in-plane and surfacenormal structure of anodic films formed on aluminium alloy AA2024 and pure aluminium. Aluminium and alloy films up to 3500 A thick were deposited on Si wafers by electron beam evaporation of ingots. Porous anodic aluminium oxide (AAO) films are formed by polarizing at constant voltage up to 20 V noble to the open circuit potential. The voltage sweet spot (5 V) appropriate for constant-voltage anodization of such thin films was determined for both alloy and pure Al. In addition, a new concurrent voltage- and current-control protocol was developed to prepare films with larger pores (voltages higher than 5 V), but formed at a controlled current so that pore growth is slow enough to avoid stripping the aluminium substrate layer. USAXS shows that the pore size and interpore spacing are fixed in the first 10 s after initiation of anodization. Pores then grow linearly in time, at constant radius and interpore spacing. Using a combination of XRR and NR, the film density and degree of hydration of the films were determined from the ratio of scattering length densities. Assuming a chemical formula Al2O3xH2O, it was found that x varies from 0.29 for the native oxide to 1.29 for AAO grown at 20 V under concurrent voltage and current control. The average AAO film density of the porous film at the air surface is 2.45 (20) g cm3. The density of the barrier layer at the metal interface is 2.9 (4) g cm3, which indicates that this layer is also quite porous

  16. In Situ-Grown ZnCo2O4 on Single-Walled Carbon Nanotubes as Air Electrode Materials for Rechargeable Lithium–Oxygen Batteries

    SciTech Connect (OSTI)

    Liu, Bin; Xu, Wu; Yan, Pengfei; Bhattacharya, Priyanka; Cao, Ruiguo; Bowden, Mark E.; Engelhard, Mark H.; Wang, Chong M.; Zhang, Jiguang

    2015-10-12

    Although lithium-oxygen (Li-O2) batteries have great potential to be used as one of the next generation energy storage systems due to their ultrahigh theoretical specific energy, there are still many significant barriers before their practical applications. These barriers include electrolyte and electrode instability, poor ORR/OER efficiency and cycling capability, etc. Development of a highly efficient catalyst will not only enhance ORR/OER efficiency, it may also improve the stability of electrolyte because the reduced charge voltage. Here we report the synthesis of nano-sheet-assembled ZnCo2O4 spheres/single walled carbon nanotubes (ZCO/SWCNTs) composites as high performance air electrode materials for Li-O2 batteries. The ZCO catalyzed SWCNTs electrodes delivered high discharge capacities, decreased the onset of oxygen evolution reaction by 0.9 V during charge processes, and led to more stable cycling stability. These results indicate that ZCO/SWCNTs composite can be used as highly efficient air electrode for oxygen reduction and evolution reactions. The highly enhanced catalytic activity by uniformly dispersed ZnCo2O4 catalyst on nanostructured electrodes is expected to inspire

  17. Khalil Amine on Lithium-air Batteries

    ScienceCinema (OSTI)

    Khalil Amine

    2010-01-08

    Khalil Amine, materials scientist at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  18. Battery Wireless Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Solutions Inc Jump to: navigation, search Name: Battery & Wireless Solutions Inc Place: New Westminster, British Columbia, Canada Zip: V3M 5V9 Product: Distributor of battery and...

  19. Forever Battery Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Co Ltd Jump to: navigation, search Name: Forever Battery Co, Ltd Place: China Product: China-based producer of NiMH, NiCd and Li-ion batteries and packs primarily for smaller...

  20. Axion Battery Products Inc | Open Energy Information

    Open Energy Info (EERE)

    Axion Battery Products Inc Jump to: navigation, search Name: Axion Battery Products Inc Place: Woodbridge, Ontario, Canada Zip: L4L 5Y9 Product: Subsidiary of Axion Power...

  1. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion...

  2. Battery Life Predictor Model - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Battery Life Predictor Model National Renewable ... in order to meet the battery warrantee's end-of-life (EOL) power and energy requirements. ...

  3. Michael Thackery on Lithium-air Batteries

    ScienceCinema (OSTI)

    Michael Thackery

    2010-01-08

    Michael Thackery, Distinguished Fellow at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  4. Probability-theoretic characteristics of solar batteries

    SciTech Connect (OSTI)

    Lidorenko, N.S.; Asharin, L.N.; Borisova, N.A.; Evdokimov, V.M.; Ryabikov, S.V.

    1980-01-01

    Results are reported for an investigation into the characteristics of solar batteries on the basis of probability theory with the photocells treated as current generators; methods for reducing solar-battery circuit losses are considered.

  5. Michael Thackeray on Lithium-air Batteries

    ScienceCinema (OSTI)

    Thackeray, Michael

    2013-04-19

    Michael Thackeray, Distinguished Fellow at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  6. Khalil Amine on Lithium-air Batteries

    SciTech Connect (OSTI)

    Khalil Amine

    2009-09-14

    Khalil Amine, materials scientist at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  7. Group 3: Humidity, Temperature, and Voltage (Presentation)

    SciTech Connect (OSTI)

    Wohlgemuth, J.

    2013-05-01

    Group 3 is chartered to develop accelerated stress tests that can be used as comparative predictors of module lifetime versus stresses associated with humidity, temperature and voltage.

  8. Evaluation of lithium-ion synergetic battery pack as battery charger

    SciTech Connect (OSTI)

    Davis, A.; Salameh, Z.M.; Eaves, S.S.

    1999-09-01

    A new battery configuration technique and accompanying control circuitry, termed a Synergetic Battery Pack (SBP), is designed to work with Lithium batteries, and can be used as both an inverter for an electric vehicle AC induction motor drive and a battery charger. In this paper, the authors compare the performance of the Synergetic Battery Pack as a battery charger with several simple conventional battery charging circuits via computer simulation. The factors of comparison were power factor, harmonic distortion, and circuit efficiency. The simulations showed that the SBP is superior to the conventional charging circuits since the power factor is unity and harmonic distortion is negligible.

  9. Battery control system for hybrid vehicle and method for controlling a hybrid vehicle battery

    DOE Patents [OSTI]

    Bockelmann, Thomas R.; Hope, Mark E.; Zou, Zhanjiang; Kang, Xiaosong

    2009-02-10

    A battery control system for hybrid vehicle includes a hybrid powertrain battery, a vehicle accessory battery, and a prime mover driven generator adapted to charge the vehicle accessory battery. A detecting arrangement is configured to monitor the vehicle accessory battery's state of charge. A controller is configured to activate the prime mover to drive the generator and recharge the vehicle accessory battery in response to the vehicle accessory battery's state of charge falling below a first predetermined level, or transfer electrical power from the hybrid powertrain battery to the vehicle accessory battery in response to the vehicle accessory battery's state of charge falling below a second predetermined level. The invention further includes a method for controlling a hybrid vehicle powertrain system.

  10. Battery Thermal Modeling and Testing (Presentation)

    SciTech Connect (OSTI)

    Smith, K.

    2011-05-01

    This presentation summarizes NREL battery thermal modeling and testing work for the DOE Annual Merit Review, May 9, 2011.

  11. Nanocomposite Materials for Lithium Ion Batteries

    SciTech Connect (OSTI)

    2011-05-31

    Fact sheet describing development and application of processing and process control for nanocomposite materials for lithium ion batteries

  12. PHEV Battery Cost Assessment | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battery Cost Assessment PHEV Battery Cost Assessment 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting es111_gallagher_2012_o.pdf (1.1 MB) More Documents & Publications Promises and Challenges of Lithium- and Manganese-Rich Transition-Metal Layered-Oxide Cathodes PHEV Battery Cost Assessment EV Everywhere Grand Challenge - Battery Status and Cost Reduction Prospects

  13. California Lithium Battery, Inc. | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    California Lithium Battery, Inc. America's Next Top Energy Innovator Challenge 626 likes California Lithium Battery, Inc. Argonne National Laboratory California Lithium Battery ("CALBattery") is a start-up California company established in 2011 to develop and manufacture a breakthrough high energy density and long cycle life lithium battery for utility energy storage, transportation, and defense industries. The company is a joint venture between California-based Ionex Energy Storage

  14. Copper (II) chloride-tetrachloroaluminate battery

    SciTech Connect (OSTI)

    Erbacher, J.K.; Hussey, C.L.; King, L.A.

    1980-06-10

    A pelletized, light weight, thermal battery having copper (II) chloride and an alkali tetrachloroaluminate as electrolytic components is disclosed.

  15. Battery Thermal Management System Design Modeling

    SciTech Connect (OSTI)

    Pesaran, A.; Kim, G. H.

    2006-11-01

    Looks at the impact of cooling strategies with air and both direct and indirect liquid cooling for battery thermal management.

  16. Vehicle Battery Safety Roadmap Guidance

    SciTech Connect (OSTI)

    Doughty, D. H.

    2012-10-01

    The safety of electrified vehicles with high capacity energy storage devices creates challenges that must be met to assure commercial acceptance of EVs and HEVs. High performance vehicular traction energy storage systems must be intrinsically tolerant of abusive conditions: overcharge, short circuit, crush, fire exposure, overdischarge, and mechanical shock and vibration. Fail-safe responses to these conditions must be designed into the system, at the materials and the system level, through selection of materials and safety devices that will further reduce the probability of single cell failure and preclude propagation of failure to adjacent cells. One of the most important objectives of DOE's Office of Vehicle Technologies is to support the development of lithium ion batteries that are safe and abuse tolerant in electric drive vehicles. This Roadmap analyzes battery safety and failure modes of state-of-the-art cells and batteries and makes recommendations on future investments that would further DOE's mission.

  17. Fail safe controllable output improved version of the Electromechanical battery

    DOE Patents [OSTI]

    Post, Richard F.

    1999-01-01

    Mechanical means are provided to control the voltages induced in the windings of a generator/motor. In one embodiment, a lever is used to withdraw or insert the entire stator windings from the cavity where the rotating field exists. In another embodiment, voltage control and/or switching off of the output is achievable with a variable-coupling generator/motor. A stator is made up of two concentric layers of windings, with a larger number of turns on the inner layer of windings than the outer layer of windings. The windings are to be connected in series electrically, that is, their voltages add vectorially. The mechanical arrangement is such that one or both of the windings can be rotated with respect to the other winding about their common central axis. Another improved design for the stator assembly of electromechanical batteries provides knife switch contacts that are in electrical contact with the stator windings. The operation of this embodiment depends on the fact that an abnormally large torque will be exerted on the stator structure during any short-circuit condition.

  18. Fail safe controllable output improved version of the electromechanical battery

    DOE Patents [OSTI]

    Post, R.F.

    1999-01-19

    Mechanical means are provided to control the voltages induced in the windings of a generator/motor. In one embodiment, a lever is used to withdraw or insert the entire stator windings from the cavity where the rotating field exists. In another embodiment, voltage control and/or switching off of the output is achievable with a variable-coupling generator/motor. A stator is made up of two concentric layers of windings, with a larger number of turns on the inner layer of windings than the outer layer of windings. The windings are to be connected in series electrically, that is, their voltages add vectorially. The mechanical arrangement is such that one or both of the windings can be rotated with respect to the other winding about their common central axis. Another improved design for the stator assembly of electromechanical batteries provides knife switch contacts that are in electrical contact with the stator windings. The operation of this embodiment depends on the fact that an abnormally large torque will be exerted on the stator structure during any short-circuit condition. 4 figs.

  19. Electrothermal Analysis of Lithium Ion Batteries

    SciTech Connect (OSTI)

    Pesaran, A.; Vlahinos, A.; Bharathan, D.; Duong, T.

    2006-03-01

    This report presents the electrothermal analysis and testing of lithium ion battery performance. The objectives of this report are to: (1) develop an electrothermal process/model for predicting thermal performance of real battery cells and modules; and (2) use the electrothermal model to evaluate various designs to improve battery thermal performance.

  20. Jeff Chamberlain on Lithium-air batteries

    ScienceCinema (OSTI)

    Chamberlain, Jeff

    2013-04-19

    Jeff Chamberlain, technology transfer expert at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries. More information at http://www.anl.gov/Media_Center/News/2009/batteries090915.html

  1. Review of storage battery system cost estimates

    SciTech Connect (OSTI)

    Brown, D.R.; Russell, J.A.

    1986-04-01

    Cost analyses for zinc bromine, sodium sulfur, and lead acid batteries were reviewed. Zinc bromine and sodium sulfur batteries were selected because of their advanced design nature and the high level of interest in these two technologies. Lead acid batteries were included to establish a baseline representative of a more mature technology.

  2. Propagation testing multi-cell batteries.

    SciTech Connect (OSTI)

    Orendorff, Christopher J.; Lamb, Joshua; Steele, Leigh Anna Marie; Spangler, Scott Wilmer

    2014-10-01

    Propagation of single point or single cell failures in multi-cell batteries is a significant concern as batteries increase in scale for a variety of civilian and military applications. This report describes the procedure for testing failure propagation along with some representative test results to highlight the potential outcomes for different battery types and designs.

  3. Jeff Chamberlain on Lithium-air batteries

    SciTech Connect (OSTI)

    Chamberlain, Jeff

    2009-01-01

    Jeff Chamberlain, technology transfer expert at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries. More information at http://www.anl.gov/Media_Center/News/2009/batteries090915.html

  4. Practical thermodynamic quantities for aqueous vanadium- and iron-based flow batteries

    SciTech Connect (OSTI)

    Hudak, Nicholas S.

    2013-12-31

    A simple method for experimentally determining thermodynamic quantities for flow battery cell reactions is presented. Equilibrium cell potentials, temperature derivatives of cell potential (dE/dT), Gibbs free energies, and entropies are reported here for all-vanadium, iron–vanadium, and iron–chromium flow cells with state-of-the-art solution compositions. Proof is given that formal potentials and formal temperature coefficients can be used with modified forms of the Nernst Equation to quantify the thermodynamics of flow cell reactions as a function of state-of-charge. Such empirical quantities can be used in thermo-electrochemical models of flow batteries at the cell or system level. In most cases, the thermodynamic quantities measured here are significantly different from standard values reported and used previously in the literature. The data reported here are also useful in the selection of operating temperatures for flow battery systems. Because higher temperatures correspond to lower equilibrium cell potentials for the battery chemistries studied here, it can be beneficial to charge a cell at higher temperature and discharge at lower temperature. As a result, proof-of-concept of improved voltage efficiency with the use of such non-isothermal cycling is given for the all-vanadium redox flow battery, and the effect is shown to be more pronounced at lower current densities.

  5. Practical thermodynamic quantities for aqueous vanadium- and iron-based flow batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hudak, Nicholas S.

    2013-12-31

    A simple method for experimentally determining thermodynamic quantities for flow battery cell reactions is presented. Equilibrium cell potentials, temperature derivatives of cell potential (dE/dT), Gibbs free energies, and entropies are reported here for all-vanadium, iron–vanadium, and iron–chromium flow cells with state-of-the-art solution compositions. Proof is given that formal potentials and formal temperature coefficients can be used with modified forms of the Nernst Equation to quantify the thermodynamics of flow cell reactions as a function of state-of-charge. Such empirical quantities can be used in thermo-electrochemical models of flow batteries at the cell or system level. In most cases, the thermodynamic quantitiesmore » measured here are significantly different from standard values reported and used previously in the literature. The data reported here are also useful in the selection of operating temperatures for flow battery systems. Because higher temperatures correspond to lower equilibrium cell potentials for the battery chemistries studied here, it can be beneficial to charge a cell at higher temperature and discharge at lower temperature. As a result, proof-of-concept of improved voltage efficiency with the use of such non-isothermal cycling is given for the all-vanadium redox flow battery, and the effect is shown to be more pronounced at lower current densities.« less

  6. Sodium Battery | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sodium Battery Technology Improves Performance and Safety Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Sodium Battery Technology Improves Performance and Safety Imagination and innovation have always been in GE's DNA. While exploring the expanded use of hybrid power in the rail, mining and marine industries, GE began

  7. Solid-state lithium battery

    DOE Patents [OSTI]

    Ihlefeld, Jon; Clem, Paul G; Edney, Cynthia; Ingersoll, David; Nagasubramanian, Ganesan; Fenton, Kyle Ross

    2014-11-04

    The present invention is directed to a higher power, thin film lithium-ion electrolyte on a metallic substrate, enabling mass-produced solid-state lithium batteries. High-temperature thermodynamic equilibrium processing enables co-firing of oxides and base metals, providing a means to integrate the crystalline, lithium-stable, fast lithium-ion conductor lanthanum lithium tantalate (La.sub.1/3-xLi.sub.3xTaO.sub.3) directly with a thin metal foil current collector appropriate for a lithium-free solid-state battery.

  8. Sodium-sulfur thermal battery

    SciTech Connect (OSTI)

    Ludwig, F.A.

    1990-12-11

    This paper discusses a sodium-sulfur thermal battery for generating electrical energy at temperatures above the melting point of sodium metal and sulfur. It comprises a sodium electrode comprising sodium metal; a sulfur electrode comprising sulfur; and a separator located between the sodium and sulfur electrodes. The separator having sufficient porosity to allow preliminary migration of fluid sodium metal and fluid sulfur and fluid sodium polysulfides therethrough during operation of the thermal battery to form a mixed polysulfides electrolyte gradient within the separator.

  9. Wide-range voltage modulation

    SciTech Connect (OSTI)

    Rust, K.R.; Wilson, J.M.

    1992-06-01

    The Superconducting Super Collider`s Medium Energy Booster Abort (MEBA) kicker modulator will supply a current pulse to the abort magnets which deflect the proton beam from the MEB ring into a designated beam stop. The abort kicker will be used extensively during testing of the Low Energy Booster (LEB) and the MEB rings. When the Collider is in full operation, the MEBA kicker modulator will abort the MEB beam in the event of a malfunction during the filling process. The modulator must generate a 14-{mu}s wide pulse with a rise time of less than 1 {mu}s, including the delay and jitter times. It must also be able to deliver a current pulse to the magnet proportional to the beam energy at any time during ramp-up of the accelerator. Tracking the beam energy, which increases from 12 GeV at injection to 200 GeV at extraction, requires the modulator to operate over a wide range of voltages (4 kV to 80 kV). A vacuum spark gap and a thyratron have been chosen for test and evaluation as candidate switches for the abort modulator. Modulator design, switching time delay, jitter and pre-fire data are presented.

  10. Voltage regulation in linear induction accelerators

    DOE Patents [OSTI]

    Parsons, William M.

    1992-01-01

    Improvement in voltage regulation in a Linear Induction Accelerator wherein a varistor, such as a metal oxide varistor, is placed in parallel with the beam accelerating cavity and the magnetic core. The non-linear properties of the varistor result in a more stable voltage across the beam accelerating cavity than with a conventional compensating resistance.

  11. Voltage regulation in linear induction accelerators

    DOE Patents [OSTI]

    Parsons, W.M.

    1992-12-29

    Improvement in voltage regulation in a linear induction accelerator wherein a varistor, such as a metal oxide varistor, is placed in parallel with the beam accelerating cavity and the magnetic core is disclosed. The non-linear properties of the varistor result in a more stable voltage across the beam accelerating cavity than with a conventional compensating resistance. 4 figs.

  12. Vehicle Technologies Office Merit Review 2014: Daikin Advanced Lithium Ion Battery Technology – High Voltage Electrolyte

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Daikin America at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about Daikin advanced lithium ion...

  13. Corona and Motor Voltage Interim Report

    SciTech Connect (OSTI)

    Hsu, J.S.

    2005-05-06

    It has been suggested that to meet the FreedomCAR objectives for cost, size, weight, efficiency, and reliability higher buss voltages be utilized in HEV and FC automotive applications. The reasoning is that since electric power is equal to the product of voltage and current for a given power a higher voltage and lower current would result in smaller cable and inverter switching components. Consequently, the system can be lighter and smaller. On the other hand, higher voltages are known to require better and thicker electrical insulation that reduce the available slot area for motor windings. One cause of slow insulation breakdown is corona that gradually erodes the insulation and shortens the life expectancy of the motor. This study reports on the results of a study on corona initiating voltages for mush-wound and bobbin-wound stators. A unique testing method is illustrated.

  14. Flexible method for monitoring fuel cell voltage

    DOE Patents [OSTI]

    Mowery, Kenneth D.; Ripley, Eugene V.

    2002-01-01

    A method for equalizing the measured voltage of each cluster in a fuel cell stack wherein at least one of the clusters has a different number of cells than the identical number of cells in the remaining clusters by creating a pseudo voltage for the different cell numbered cluster. The average cell voltage of the all of the cells in the fuel cell stack is calculated and multiplied by a constant equal to the difference in the number of cells in the identical cell clusters and the number of cells in the different numbered cell cluster. The resultant product is added to the actual voltage measured across the different numbered cell cluster to create a pseudo voltage which is equivalent in cell number to the number of cells in the other identical numbered cell clusters.

  15. Voltage controlled spintronic devices for logic applications

    DOE Patents [OSTI]

    You, Chun-Yeol; Bader, Samuel D.

    2001-01-01

    A reprogrammable logic gate comprising first and second voltage-controlled rotation transistors. Each transistor comprises three ferromagnetic layers with a spacer and insulating layer between the first and second ferromagnetic layers and an additional insulating layer between the second and third ferromagnetic layers. The third ferromagnetic layer of each transistor is connected to each other, and a constant external voltage source is applied to the second ferromagnetic layer of the first transistor. As input voltages are applied to the first ferromagnetic layer of each transistor, the relative directions of magnetization of the ferromagnetic layers and the magnitude of the external voltage determines the output voltage of the gate. By altering these parameters, the logic gate is capable of behaving as AND, OR, NAND, or NOR gates.

  16. Models for Battery Reliability and Lifetime

    SciTech Connect (OSTI)

    Smith, K.; Wood, E.; Santhanagopalan, S.; Kim, G. H.; Neubauer, J.; Pesaran, A.

    2014-03-01

    Models describing battery degradation physics are needed to more accurately understand how battery usage and next-generation battery designs can be optimized for performance and lifetime. Such lifetime models may also reduce the cost of battery aging experiments and shorten the time required to validate battery lifetime. Models for chemical degradation and mechanical stress are reviewed. Experimental analysis of aging data from a commercial iron-phosphate lithium-ion (Li-ion) cell elucidates the relative importance of several mechanical stress-induced degradation mechanisms.

  17. Promising Magnesium Battery Research at ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Promising Magnesium Battery Research at ALS Promising Magnesium Battery Research at ALS Print Wednesday, 23 January 2013 16:59 toyota battery a) Cross-section of the in situ electrochemical/XAS cell with annotations. b) Drawing and c) photograph of the assembled cell. Alternatives to the current lithium-ion-based car batteries are at the forefront of the automotive industry's research agenda-manufacturers want to build cars with longer battery life, and to do that they're going to have to find

  18. Vehicle Technologies Office: Advanced Battery Development, System Analysis,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Testing | Department of Energy Advanced Battery Development, System Analysis, and Testing Vehicle Technologies Office: Advanced Battery Development, System Analysis, and Testing To develop better lithium-ion (Li-ion) batteries for plug-in electric vehicles, researchers must integrate the advances made in exploratory battery materials and applied battery research into full battery systems. The Vehicle Technologies Office's (VTO) Advanced Battery Development, System Analysis, and Testing

  19. Cathode material for lithium batteries

    DOE Patents [OSTI]

    Park, Sang-Ho; Amine, Khalil

    2015-01-13

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  20. Cathode material for lithium batteries

    DOE Patents [OSTI]

    Park, Sang-Ho; Amine, Khalil

    2013-07-23

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  1. Electric and hybrid vehicles charge efficiency tests of ESB EV-106 lead-acid batteries

    SciTech Connect (OSTI)

    Rowlette, J.J.

    1981-01-15

    Charge efficiencies were determined for ESB EV-106 lead-acid batteries by measurements made under widely differing conditions of temperature, charge procedure, and battery age. The measurements were used to optimize charge procedures and to evaluate the concept of a modified, coulometric state-of-charge indicator. Charge efficiency determinations were made by measuring gassing rates and oxygen fractions. A novel, positive displacement gas flow meter which proved to be both simple and highly accurate is described and illustrated.

  2. Lithium-Air Battery: High Performance Cathodes for Lithium-Air Batteries

    SciTech Connect (OSTI)

    2010-08-01

    BEEST Project: Researchers at Missouri S&T are developing an affordable lithium-air (Li-Air) battery that could enable an EV to travel up to 350 miles on a single charge. Todays EVs run on Li-Ion batteries, which are expensive and suffer from low energy density compared with gasoline. This new Li-Air battery could perform as well as gasoline and store 3 times more energy than current Li-Ion batteries. A Li-Air battery uses an air cathode to breathe oxygen into the battery from the surrounding air, like a human lung. The oxygen and lithium react in the battery to produce electricity. Current Li-Air batteries are limited by the rate at which they can draw oxygen from the air. The team is designing a battery using hierarchical electrode structures to enhance air breathing and effective catalysts to accelerate electricity production.

  3. GROUND CLEARANCE INDICATOR

    DOE Patents [OSTI]

    Skinner, L.V.

    1959-09-29

    A narrow-band frequency-modulated distance measuring system is described. Reflected wave energy is fed into a mixer circuit together with a direct wave energy portion from the transmitter. These two input signals are out of phase by an amount proportional to the distance. Two band pass filter s select two different frequency components (both multiples of transmitter modulation frequency) from the beat frequency. These component frequencies are rectified and their voltage values, which are representative of those frequencies, are compared. It has been found that these voltages will have equal values producing a null output only when an object attains a preselected distance. The null output may be utilized to operate a normally closed relay, for example. At other ranges the voltage comparison will yield a voltage sufficient to keep the relay energized. Ranges may be changed by varying the degree of modulation of the transmitter carrier frequency. A particular advantage of this system lies in its high degree of accuracy throughout a range of distances approaching zero as a minimum.

  4. The Science of Battery Degradation.

    SciTech Connect (OSTI)

    Sullivan, John P; Fenton, Kyle R; El Gabaly Marquez, Farid; Harris, Charles Thomas; Hayden, Carl C.; Hudak, Nicholas; Jungjohann, Katherine Leigh; Kliewer, Christopher Jesse; Leung, Kevin; McDaniel, Anthony H.; Nagasubramanian, Ganesan; Sugar, Joshua Daniel; Talin, Albert Alec; Tenney, Craig M; Zavadil, Kevin R.

    2015-01-01

    This report documents work that was performed under the Laboratory Directed Research and Development project, Science of Battery Degradation. The focus of this work was on the creation of new experimental and theoretical approaches to understand atomistic mechanisms of degradation in battery electrodes that result in loss of electrical energy storage capacity. Several unique approaches were developed during the course of the project, including the invention of a technique based on ultramicrotoming to cross-section commercial scale battery electrodes, the demonstration of scanning transmission x-ray microscopy (STXM) to probe lithium transport mechanisms within Li-ion battery electrodes, the creation of in-situ liquid cells to observe electrochemical reactions in real-time using both transmission electron microscopy (TEM) and STXM, the creation of an in-situ optical cell utilizing Raman spectroscopy and the application of the cell for analyzing redox flow batteries, the invention of an approach for performing ab initio simulation of electrochemical reactions under potential control and its application for the study of electrolyte degradation, and the development of an electrochemical entropy technique combined with x-ray based structural measurements for understanding origins of battery degradation. These approaches led to a number of scientific discoveries. Using STXM we learned that lithium iron phosphate battery cathodes display unexpected behavior during lithiation wherein lithium transport is controlled by nucleation of a lithiated phase, leading to high heterogeneity in lithium content at each particle and a surprising invariance of local current density with the overall electrode charging current. We discovered using in-situ transmission electron microscopy that there is a size limit to lithiation of silicon anode particles above which particle fracture controls electrode degradation. From electrochemical entropy measurements, we discovered that entropy

  5. A low cost, high energy density and long cycle life potassium-sulfur battery for grid-scale energy storage

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Bowden, Mark E.; Sprenkle, Vincent L.; Liu, Jun

    2015-08-15

    Alkali metal-sulfur batteries are attractive for energy storage applications because of their high energy density. Among the batteries, lithium-sulfur batteries typically use liquid in the battery electrolyte, which causes problems in both performance and safety. Sodium-sulfur batteries can use a solid electrolyte such as beta alumina but this requires a high operating temperature. Here we report a novel potassium-sulfur battery with K+-conducting beta-alumina as the electrolyte. Our studies indicate that liquid potassium exhibits much better wettability on the surface of beta-alumina compared to liquid sodium at lower temperatures. Based on this observation, we develop a potassium-sulfur battery that can operate at as low as 150°C with excellent performance. In particular, the battery shows excellent cycle life with negligible capacity fade in 1000 cycles because of the dense ceramic membrane. This study demonstrates a new battery with a high energy density, long cycle life, low cost and high safety, which is ideal for grid-scale energy storage.

  6. Electro-optical voltage sensor head

    DOE Patents [OSTI]

    Woods, Gregory K.

    1998-01-01

    A miniature electro-optic voltage sensor system capable of accurate operation at high voltages. The system employs a transmitter, a sensor disposed adjacent to but out of direct electrical contact with a conductor on which the voltage is to be measured, a detector, and a signal processor. The transmitter produces a beam of electromagnetic radiation which is routed into the sensor where the beam undergoes the Pockels electro-optic effect. The electro-optic effect causes phase shifting in the beam, which is in turn converted to a pair of independent beams, from which the voltage of a system based on its E-field is determined when the two beams are normalized by the signal processor. The sensor converts the beam by splitting the beam in accordance with the axes of the beam's polarization state (an ellipse whose ellipticity varies between -1 and +1 in proportion to voltage) into at least two AM signals. These AM signals are fed into a signal processor and processed to determine the voltage between a ground conductor and the conductor on which voltage is being measured.

  7. Electro-optical voltage sensor head

    DOE Patents [OSTI]

    Woods, G.K.

    1998-03-24

    A miniature electro-optic voltage sensor system capable of accurate operation at high voltages is disclosed. The system employs a transmitter, a sensor disposed adjacent to but out of direct electrical contact with a conductor on which the voltage is to be measured, a detector, and a signal processor. The transmitter produces a beam of electromagnetic radiation which is routed into the sensor where the beam undergoes the Pockels electro-optic effect. The electro-optic effect causes phase shifting in the beam, which is in turn converted to a pair of independent beams, from which the voltage of a system based on its E-field is determined when the two beams are normalized by the signal processor. The sensor converts the beam by splitting the beam in accordance with the axes of the beam`s polarization state (an ellipse whose ellipticity varies between -1 and +1 in proportion to voltage) into at least two AM signals. These AM signals are fed into a signal processor and processed to determine the voltage between a ground conductor and the conductor on which voltage is being measured. 6 figs.

  8. Lithiated vanadium oxide (LVO), gamma-lithium vanadium bronze (gamma-LiV2O5) and vanadium dioxide (Vo2) as thermal-battery cathode materials. Technical report

    SciTech Connect (OSTI)

    Richie, A.G.; Warner, K.

    1991-05-01

    Thermal batteries are high temperature reserve batteries, predominantly used in missiles. Modern designs use a lithium (or lithium alloy) anode, an immobilized molten salt electrolyte and an iron-disulphide cathode. These batteries have many advantages: high reliability, long storage life without maintenance, wide temperature range of operation and, sometimes, high power. However, the energy density is rather low and this could be improved if the individual cell voltage could be raised above the present 2.2 V/cell open circuit-voltage for the lithium iron-disulphide couple. A new cathode material, lithiated vanadium oxide (LVO), been invented at RAE with the advantage of the much higher open-circuit voltage of 2.6 V/cell versus lithium. The properties of LVO have been investigated and it has been shown that LVO consists of vanadium dioxide as the major component. Some lithium bromide is also present.

  9. The electrochemical oxidation of polyacetylene and its battery applications

    SciTech Connect (OSTI)

    Farrington, G.C.; DeNuzzio, J.; Frydrych, D.; Scrosati, B.

    1984-01-01

    When oxidized in a nonaqueous cell containing 1.0M LiClO/sub 4/ in propylene carbonate, polyacetylene develops a voltage of 3.4-4.0V vs. Li/Li/sup +/ ClO/sub 4//sup -/. Oxidation levels at least as high as (CH(CLO/sub 4/) /SUB 1/10/ ) /SUB x/ can be produced electrochemically and then reduced to the undoped state with nearly 100% coulombic efficiency. The electrochemical doping (oxidation) process is only efficient when carried out with a minimum of liquid electrolyte under ultraclean conditions. Similar results are observed with a LiAsF/sub 6/ electrolyte. Polyacetylene is an extraordinary material of great importance for electrochemistry. However, on the basis of this and other published research, it is not yet clear that it offers major advantages over current electrodes for high energy density nonaqueous batteries.

  10. Stand Alone Battery Thermal Management System

    SciTech Connect (OSTI)

    Brodie, Brad

    2015-09-30

    The objective of this project is research, development and demonstration of innovative thermal management concepts that reduce the cell or battery weight, complexity (component count) and/or cost by at least 20%. The project addresses two issues that are common problems with current state of the art lithium ion battery packs used in vehicles; low power at cold temperatures and reduced battery life when exposed to high temperatures. Typically, battery packs are “oversized” to satisfy the two issues mentioned above. The first phase of the project was spent making a battery pack simulation model using AMEsim software. The battery pack used as a benchmark was from the Fiat 500EV. FCA and NREL provided vehicle data and cell data that allowed an accurate model to be created that matched the electrical and thermal characteristics of the actual battery pack. The second phase involved using the battery model from the first phase and evaluate different thermal management concepts. In the end, a gas injection heat pump system was chosen as the dedicated thermal system to both heat and cool the battery pack. Based on the simulation model. The heat pump system could use 50% less energy to heat the battery pack in -20°C ambient conditions, and by keeping the battery cooler at hot climates, the battery pack size could be reduced by 5% and still meet the warranty requirements. During the final phase, the actual battery pack and heat pump system were installed in a test bench at DENSO to validate the simulation results. Also during this phase, the system was moved to NREL where testing was also done to validate the results. In conclusion, the heat pump system can improve “fuel economy” (for electric vehicle) by 12% average in cold climates. Also, the battery pack size, or capacity, could be reduced 5%, or if pack size is kept constant, the pack life could be increased by two years. Finally, the total battery pack and thermal system cost could be reduced 5% only if the

  11. Lithium sulfide compositions for battery electrolyte and battery electrode coatings

    DOE Patents [OSTI]

    Liang, Chengdu; Liu, Zengcai; Fu, Wunjun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

    2013-12-03

    Methods of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electroytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one or .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

  12. Lithium sulfide compositions for battery electrolyte and battery electrode coatings

    DOE Patents [OSTI]

    Liang, Chengdu; Liu, Zengcai; Fu, Wujun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

    2014-10-28

    Method of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electrolytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

  13. Analysis of Solar Cell Quality Using Voltage Metrics: Preprint

    SciTech Connect (OSTI)

    Toberer, E. S.; Tamboli, A. C.; Steiner, M.; Kurtz, S.

    2012-06-01

    The highest efficiency solar cells provide both excellent voltage and current. Of these, the open-circuit voltage (Voc) is more frequently viewed as an indicator of the material quality. However, since the Voc also depends on the band gap of the material, the difference between the band gap and the Voc is a better metric for comparing material quality of unlike materials. To take this one step further, since Voc also depends on the shape of the absorption edge, we propose to use the ultimate metric: the difference between the measured Voc and the Voc calculated from the external quantum efficiency using a detailed balance approach. This metric is less sensitive to changes in cell design and definition of band gap. The paper defines how to implement this metric and demonstrates how it can be useful in tracking improvements in Voc, especially as Voc approaches its theoretical maximum.

  14. Electro-optic high voltage sensor

    DOE Patents [OSTI]

    Davidson, James R.; Seifert, Gary D.

    2003-09-16

    A small sized electro-optic voltage sensor capable of accurate measurement of high voltages without contact with a conductor or voltage source is provided. When placed in the presence of an electric field, the sensor receives an input beam of electromagnetic radiation. A polarization beam displacer separates the input beam into two beams with orthogonal linear polarizations and causes one linearly polarized beam to impinge a crystal at a desired angle independent of temperature. The Pockels effect elliptically polarizes the beam as it travels through the crystal. A reflector redirects the beam back through the crystal and the beam displacer. On the return path, the polarization beam displacer separates the elliptically polarized beam into two output beams of orthogonal linear polarization. The system may include a detector for converting the output beams into electrical signals and a signal processor for determining the voltage based on an analysis of the output beams.

  15. Low voltage arc formation in railguns

    DOE Patents [OSTI]

    Hawke, R.S.

    1985-08-05

    A low voltage plasma arc is first established across the rails behind the projectile by switching a low voltage high current source across the rails to establish a plasma arc by vaporizing a fuse mounted on the back of the projectile, maintaining the voltage across the rails below the railgun breakdown voltage to prevent arc formation ahead of the projectile. After the plasma arc has been formed behind the projectile a discriminator switches the full energy bank across the rails to accelerate the projectile. A gas gun injector may be utilized to inject a projectile into the breech of a railgun. The invention permits the use of a gas gun or gun powder injector and an evacuated barrel without the risk of spurious arc formation in front of the projectile.

  16. Low voltage arc formation in railguns

    DOE Patents [OSTI]

    Hawke, Ronald S.

    1987-01-01

    A low voltage plasma arc is first established across the rails behind the projectile by switching a low voltage high current source across the rails to establish a plasma arc by vaporizing a fuse mounted on the back of the projectile, maintaining the voltage across the rails below the railgun breakdown voltage to prevent arc formation ahead of the projectile. After the plasma arc has been formed behind the projectile a discriminator switches the full energy bank across the rails to accelerate the projectile. A gas gun injector may be utilized to inject a projectile into the breech of a railgun. The invention permits the use of a gas gun or gun powder injector and an evacuated barrel without the risk of spurious arc formation in front of the projectile.

  17. Low voltage arc formation in railguns

    DOE Patents [OSTI]

    Hawke, R.S.

    1987-11-17

    A low voltage plasma arc is first established across the rails behind the projectile by switching a low voltage high current source across the rails to establish a plasma arc by vaporizing a fuse mounted on the back of the projectile, maintaining the voltage across the rails below the railgun breakdown voltage to prevent arc formation ahead of the projectile. After the plasma arc has been formed behind the projectile a discriminator switches the full energy bank across the rails to accelerate the projectile. A gas gun injector may be utilized to inject a projectile into the breech of a railgun. The invention permits the use of a gas gun or gun powder injector and an evacuated barrel without the risk of spurious arc formation in front of the projectile. 2 figs.

  18. Optimization and Domestic Sourcing of Lithium Ion Battery Anode Materials

    SciTech Connect (OSTI)

    Wood, III, D. L.; Yoon, S.

    2012-10-25

    The purpose of this Cooperative Research and Development Agreement (CRADA) between ORNL and A123Systems, Inc. was to develop a low-temperature heat treatment process for natural graphite based anode materials for high-capacity and long-cycle-life lithium ion batteries. Three major problems currently plague state-of-the-art lithium ion battery anode materials. The first is the cost of the artificial graphite, which is heat-treated well in excess of 2000°C. Because of this high-temperature heat treatment, the anode active material significantly contributes to the cost of a lithium ion battery. The second problem is the limited specific capacity of state-of-the-art anodes based on artificial graphites, which is only about 200-350 mAh/g. This value needs to be increased to achieve high energy density when used with the low cell-voltage nanoparticle LiFePO4 cathode. Thirdly, the rate capability under cycling conditions of natural graphite based materials must be improved to match that of the nanoparticle LiFePO4. Natural graphite materials contain inherent crystallinity and lithium intercalation activity. They hold particular appeal, as they offer huge potential for industrial energy savings with the energy costs essentially subsidized by geological processes. Natural graphites have been heat-treated to a substantially lower temperature (as low as 1000-1500°C) and used as anode active materials to address the problems described above. Finally, corresponding graphitization and post-treatment processes were developed that are amenable to scaling to automotive quantities.

  19. Improvements in Li(Si)/FeS/sub 2/ thermal battery technology

    SciTech Connect (OSTI)

    Searcy, J.Q.; Armijo, J.R.

    1982-06-01

    Potential improvements in Li(Si)/FeS/sub 2/ thermal battery technology were evaluated using as the test vehicle a 28 +- 4-V, 400-cm/sup 3/ battery discharged through a 28-..cap omega.. load. Successful improvements included incorporating a catholyte additive to improve voltage regulation during discharge, changing the catholyte composition and blending procedure to increase life and current carrying capability, changing the anode composition to obtain better voltage regulation, and optimizing the heat and mass input. One end-of-life mechanism for higher current drain batteries was determined to be electrolytic freeze-out at the anode at temperatures that increase as the current density increases. The increase in freezing temperature was caused by a change in the K/sup +//Li/sup +/ ratio in the electrolyte near the anode as the anode discharged. A balanced ratio of cathode to anode weight was determined for the two catholytes and anode powders considered. The balance was based on electrode polarization at various resistive loads.

  20. Tire-derived carbon composite anodes for sodium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Yunchao; Paranthaman, M. Parans; Akato, Kokouvi; Naskar, Amit K.; Levine, Alan M.; Lee, Richard J.; Kim, Sang-Ok; Zhang, Jinshui; Dai, Sheng; Manthiram, Arumugam

    2016-04-04

    We report that hard-carbon materials are considered as one of the most promising anodes for the emerging sodium-ion batteries. Here, we report a low-cost, scalable waste tire-derived carbon as an anode for sodium-ion batteries (SIBs). The tire-derived carbons obtained by pyrolyzing the acid-treated tire at 1100 °C, 1400 °C and 1600 °C show capacities of 179, 185 and 203 mAh g-1, respectively, after 100 cycles at a current density of 20 mA g-1 in sodium-ion batteries with good electrochemical stability. The portion of the low-voltage plateau region in the charge-discharge curves increases as the heat-treatment temperature increases. The low-voltage plateaumore » is beneficial to enhance the energy density of the full cell. However, this plateau suffers rapid capacity fade at higher current densities. This study provides a new pathway for inexpensive, environmentally benign and value-added waste tire-derived products towards large-scale energy storage applications.« less

  1. Joint voltages resulting from lightning currents.

    SciTech Connect (OSTI)

    Johnson, William Arthur; Warne, Larry Kevin; Merewether, Kimball O.; Chen, Kenneth C.

    2007-03-01

    Simple formulas are given for the interior voltages appearing across bolted joints from exterior lightning currents. External slot and bolt inductances as well as internal slot and bolt diffusion effects are included. Both linear and ferromagnetic wall materials are considered. A useful simplification of the slot current distribution into linear stripline and cylindrical parts (near the bolts) allows the nonlinear voltages to be estimated in closed form.

  2. Spark gap with low breakdown voltage jitter

    DOE Patents [OSTI]

    Rohwein, Gerald J.; Roose, Lars D.

    1996-01-01

    Novel spark gap devices and electrodes are disclosed. The novel spark gap devices and electrodes are suitable for use in a variety of spark gap device applications. The shape of the electrodes gives rise to local field enhancements and reduces breakdown voltage jitter. Breakdown voltage jitter of approximately 5% has been measured in spark gaps according the invention. Novel electrode geometries and materials are disclosed.

  3. Spark gap with low breakdown voltage jitter

    DOE Patents [OSTI]

    Rohwein, G.J.; Roose, L.D.

    1996-04-23

    Novel spark gap devices and electrodes are disclosed. The novel spark gap devices and electrodes are suitable for use in a variety of spark gap device applications. The shape of the electrodes gives rise to local field enhancements and reduces breakdown voltage jitter. Breakdown voltage jitter of approximately 5% has been measured in spark gaps according the invention. Novel electrode geometries and materials are disclosed. 13 figs.

  4. Constant voltage electro-slag remelting control

    DOE Patents [OSTI]

    Schlienger, M.E.

    1996-10-22

    A system for controlling electrode gap in an electro-slag remelt furnace has a constant regulated voltage and an electrode which is fed into the slag pool at a constant rate. The impedance of the circuit through the slag pool is directly proportional to the gap distance. Because of the constant voltage, the system current changes are inversely proportional to changes in gap. This negative feedback causes the gap to remain stable. 1 fig.

  5. Constant voltage electro-slag remelting control

    SciTech Connect (OSTI)

    Schlienger, Max E.

    1996-01-01

    A system for controlling electrode gap in an electro-slag remelt furnace has a constant regulated voltage and an eletrode which is fed into the slag pool at a constant rate. The impedance of the circuit through the slag pool is directly proportional to the gap distance. Because of the constant voltage, the system current changes are inversely proportional to changes in gap. This negative feedback causes the gap to remain stable.

  6. Improve Motor Operation at Off-Design Voltages | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Motor Operation at Off-Design Voltages Improve Motor Operation at Off-Design Voltages Motors are designed to operate within 10% of their nameplate rated voltages. When motors ...

  7. System for increasing corona inception voltage of insulating oils

    DOE Patents [OSTI]

    Rohwein, Gerald J.

    1998-01-01

    The Corona Inception Voltage of insulating oils is increased by repetitive cycles of prestressing the oil with a voltage greater than the corona inception voltage, and either simultaneously or serially removing byproducts of corona by evacuation and heating the oil.

  8. SPECIFIC HEAT INDICATOR

    DOE Patents [OSTI]

    Horn, F.L.; Binns, J.E.

    1961-05-01

    Apparatus for continuously and automatically measuring and computing the specific heat of a flowing solution is described. The invention provides for the continuous measurement of all the parameters required for the mathematical solution of this characteristic. The parameters are converted to logarithmic functions which are added and subtracted in accordance with the solution and a null-seeking servo reduces errors due to changing voltage drops to a minimum. Logarithmic potentiometers are utilized in a unique manner to accomplish these results.

  9. High-voltage miniature igniter development

    SciTech Connect (OSTI)

    Willkens, C.A.; Axelson, S.R.; Bateman, L.S.; Croucher, D.D.

    1996-09-01

    In 1988, Norton introduced its line of low-voltage 12- and 24-V miniature igniters made from a patented ceramic/intermetallic material. These igniters demonstrated superior strength and speed in a compact low-wattage assembly for gas-fired ignition. High-voltage igniters are being developed to complete the family of igniters for gas-fired ignition. These igniters have extremely low power requirements in the range of 50--100 W, are designed to operate at line voltages of 120 V, and are leading to designs for operation up to 230 V. These were developed using compositional and dimensional changes to the low voltage igniters. The 120 V igniter has exceeded 200,000 cycles in life testing and has been submitted for agency approval. These igniters are also undergoing field testing in various demanding gas-fired appliances. The evolution of the low-voltage igniter into the high-voltage model, as well as performance and material development issues are discussed.

  10. Hydrogen-Bromine Flow Battery: Hydrogen Bromine Flow Batteries for Grid Scale Energy Storage

    SciTech Connect (OSTI)

    2010-10-01

    GRIDS Project: LBNL is designing a flow battery for grid storage that relies on a hydrogen-bromine chemistry which could be more efficient, last longer and cost less than today’s lead-acid batteries. Flow batteries are fundamentally different from traditional lead-acid batteries because the chemical reactants that provide their energy are stored in external tanks instead of inside the battery. A flow battery can provide more energy because all that is required to increase its storage capacity is to increase the size of the external tanks. The hydrogen-bromine reactants used by LBNL in its flow battery are inexpensive, long lasting, and provide power quickly. The cost of the design could be well below $100 per kilowatt hour, which would rival conventional grid-scale battery technologies.

  11. Recombination device for storage batteries

    DOE Patents [OSTI]

    Kraft, Helmut; Ledjeff, Konstantin

    1985-01-01

    A recombination device including a gas-tight enclosure connected to receive he discharge gases from a rechargeable storage battery. Catalytic material for the recombination of hydrogen and oxygen to form water is supported within the enclosure. The enclosure is sealed from the atmosphere by a liquid seal including two vertical chambers interconnected with an inverted U-shaped overflow tube. The first chamber is connected at its upper portion to the enclosure and the second chamber communicates at its upper portion with the atmosphere. If the pressure within the enclosure differs as overpressure or vacuum by more than the liquid level, the liquid is forced into one of the two chambers and the overpressure is vented or the vacuum is relieved. The recombination device also includes means for returning recombined liquid to the battery and for absorbing metal hydrides.

  12. Cascade redox flow battery systems

    DOE Patents [OSTI]

    Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B.; Sha, Jay E.; Bose, Deepak

    2014-07-22

    A reduction/oxidation ("redox") flow battery system includes a series of electrochemical cells arranged in a cascade, whereby liquid electrolyte reacts in a first electrochemical cell (or group of cells) before being directed into a second cell (or group of cells) where it reacts before being directed to subsequent cells. The cascade includes 2 to n stages, each stage having one or more electrochemical cells. During a charge reaction, electrolyte entering a first stage will have a lower state-of-charge than electrolyte entering the nth stage. In some embodiments, cell components and/or characteristics may be configured based on a state-of-charge of electrolytes expected at each cascade stage. Such engineered cascades provide redox flow battery systems with higher energy efficiency over a broader range of current density than prior art arrangements.

  13. Recombination device for storage batteries

    DOE Patents [OSTI]

    Kraft, H.; Ledjeff, K.

    1984-01-01

    A recombination device including a gas-tight enclosure connected to receive the discharge gases from a rechargeable storage battery. Catalytic material for the recombination of hydrogen and oxygen to form water is supported within the enclosure. The enclosure is sealed from the atmosphere by a liquid seal including two vertical chambers interconnected with an inverted U-shaped overflow tube. The first chamber is connected at its upper portion to the enclosure and the second chamber communicates at its upper portion with the atmosphere. If the pressure within the enclosure differs as overpressure or vacuum by more than the liquid level, the liquid is forced into one of the two chambers and the overpressure is vented or the vacuum is relieved. The recombination device also includes means for returning recombined liquid to the battery and for absorbing metal hydrides.

  14. Modular high voltage power supply for chemical analysis

    DOE Patents [OSTI]

    Stamps, James F.; Yee, Daniel D.

    2007-01-09

    A high voltage power supply for use in a system such as a microfluidics system, uses a DC--DC converter in parallel with a voltage-controlled resistor. A feedback circuit provides a control signal for the DC--DC converter and voltage-controlled resistor so as to regulate the output voltage of the high voltage power supply, as well as, to sink or source current from the high voltage supply.

  15. Modular high voltage power supply for chemical analysis

    DOE Patents [OSTI]

    Stamps, James F.; Yee, Daniel D.

    2010-05-04

    A high voltage power supply for use in a system such as a microfluidics system, uses a DC-DC converter in parallel with a voltage-controlled resistor. A feedback circuit provides a control signal for the DC-DC converter and voltage-controlled resistor so as to regulate the output voltage of the high voltage power supply, as well as, to sink or source current from the high voltage supply.

  16. Modular high voltage power supply for chemical analysis

    DOE Patents [OSTI]

    Stamps, James F.; Yee, Daniel D.

    2008-07-15

    A high voltage power supply for use in a system such as a microfluidics system, uses a DC-DC converter in parallel with a voltage-controlled resistor. A feedback circuit provides a control signal for the DC-DC converter and voltage-controlled resistor so as to regulate the output voltage of the high voltage power supply, as well as, to sink or source current from the high voltage supply.

  17. Electrolytes for lithium ion batteries

    DOE Patents [OSTI]

    Vaughey, John; Jansen, Andrew N.; Dees, Dennis W.

    2014-08-05

    A family of electrolytes for use in a lithium ion battery. The genus of electrolytes includes ketone-based solvents, such as, 2,4-dimethyl-3-pentanone; 3,3-dimethyl 2-butanone(pinacolone) and 2-butanone. These solvents can be used in combination with non-Lewis Acid salts, such as Li.sub.2[B.sub.12F.sub.12] and LiBOB.

  18. Battery system with temperature sensors

    SciTech Connect (OSTI)

    Wood, Steven J; Trester, Dale B

    2014-02-04

    A battery system includes a platform having an aperture formed therethrough, a flexible member having a generally planar configuration and extending across the aperture, wherein a portion of the flexible member is coextensive with the aperture, a cell provided adjacent the platform, and a sensor coupled to the flexible member and positioned proximate the cell. The sensor is configured to detect a temperature of the cell.

  19. A lithium oxygen secondary battery

    SciTech Connect (OSTI)

    Semkow, K.W.; Sammells, A.F.

    1987-08-01

    In principle the lithium-oxygen couple should provide one of the highest energy densities yet investigated for advanced battery systems. The problem to this time has been one of identifying strategies for achieving high electrochemical reversibilities at each electrode under conditions where one might anticipate to also achieve long materials lifetimes. This has been addressed in recent work by us via the application of stabilized zirconia oxygen vacancy conducting solid electrolytes, for the effective separation of respective half-cell reactions.

  20. Batteries for Large Scale Energy Storage

    SciTech Connect (OSTI)

    Soloveichik, Grigorii L.

    2011-07-15

    In recent years, with the deployment of renewable energy sources, advances in electrified transportation, and development in smart grids, the markets for large-scale stationary energy storage have grown rapidly. Electrochemical energy storage methods are strong candidate solutions due to their high energy density, flexibility, and scalability. This review provides an overview of mature and emerging technologies for secondary and redox flow batteries. New developments in the chemistry of secondary and flow batteries as well as regenerative fuel cells are also considered. Advantages and disadvantages of current and prospective electrochemical energy storage options are discussed. The most promising technologies in the short term are high-temperature sodium batteries with β”-alumina electrolyte, lithium-ion batteries, and flow batteries. Regenerative fuel cells and lithium metal batteries with high energy density require further research to become practical.