Sample records for battery materials venture

  1. Battery Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation in Carbon CaptureAtriaPower SystemsRhode Island:Battery Ventures

  2. battery materials | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery materials battery materials Leads No leads are available at this time. Modeling Interfacial Glass-Water Reactions: Recent Advances and Current Limitations. Abstract: The...

  3. EMSL - battery materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery-materials en Modeling Interfacial Glass-Water Reactions: Recent Advances and Current Limitations. http:www.emsl.pnl.govemslwebpublicationsmodeling-interfacial-glass-wa...

  4. Advanced Battery Materials Characterization: Success stories...

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Battery Materials Characterization: Success stories from the High Temperature Materials Laboratory (HTML) User Program Advanced Battery Materials Characterization: Success...

  5. Disordered Materials Hold Promise for Better Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Disordered materials hold promise for better batteries Disordered Materials Hold Promise for Better Batteries February 21, 2014 | Tags: Chemistry, Hopper, Materials Science,...

  6. Cathode material for lithium batteries

    DOE Patents [OSTI]

    Park, Sang-Ho; Amine, Khalil

    2013-07-23T23:59:59.000Z

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  7. Making Li-air batteries rechargeable: material challenges. |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li-air batteries rechargeable: material challenges. Making Li-air batteries rechargeable: material challenges. Abstract: A Li-air battery could potentially provide three to five...

  8. Advanced Battery Materials Characterization: Success stories...

    Broader source: Energy.gov (indexed) [DOE]

    Battery Materials Characterization: Success stories from the High Temperature Materials Laboratory (HTML) User Program Dr. E. Andrew Payzant, ORNL Project ID lmp02payzant This...

  9. Characterization of Materials for Li-ion Batteries: Success Stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User Program Characterization of Materials for Li-ion Batteries: Success...

  10. Bimetallic Cathode Materials for Lithium Based Batteries

    E-Print Network [OSTI]

    Bimetallic Cathode Materials for Lithium Based Batteries Frontiers in Materials Science Seminar / Chemistryg g g g g y University at Buffalo ­ The State University of New York (SUNY) Abstract Batteries for implantable cardiac defibrillators (ICDs) are based on the Lithium/Silver vanadium oxide (SVO, Ag2V4O11

  11. Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /

    E-Print Network [OSTI]

    Lee, Dae Hoe

    2013-01-01T23:59:59.000Z

    spinel structures for lithium batteries. ElectrochemistryMaterials for Rechargeable Lithium Batteries. Journal of thefor Rechargeable Lithium Batteries. Electrochemical and

  12. In situ Characterizations of New Battery Materials and the Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    situ Characterizations of New Battery Materials and the Studies of High Energy Density Li-Air Batteries In situ Characterizations of New Battery Materials and the Studies of High...

  13. In Situ Characterizations of New Battery Materials and the Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Situ Characterizations of New Battery Materials and the Studies of High Energy Density Li-Air Batteries In Situ Characterizations of New Battery Materials and the Studies of High...

  14. Hierarchically Structured Materials for Lithium Batteries

    SciTech Connect (OSTI)

    Xiao, Jie; Zheng, Jianming; Li, Xiaolin; Shao, Yuyan; Zhang, Jiguang

    2013-09-25T23:59:59.000Z

    Lithium-ion battery (LIB) is one of the most promising power sources to be deployed in electric vehicles (EV), including solely battery powered vehicles, plug-in hybrid electric vehicles, and hybrid electrical vehicles. With the increasing demand on devices of high energy densities (>500 Wh/kg) , new energy storage systems, such as lithium-oxygen (Li-O2) batteries and other emerging systems beyond the conventional LIB also attracted worldwide interest for both transportation and grid energy storage applications in recent years. It is well known that the electrochemical performances of these energy storage systems depend not only on the composition of the materials, but also on the structure of electrode materials used in the batteries. Although the desired performances characteristics of batteries often have conflict requirements on the micro/nano-structure of electrodes, hierarchically designed electrodes can be tailored to satisfy these conflict requirements. This work will review hierarchically structured materials that have been successfully used in LIB and Li-O2 batteries. Our goal is to elucidate 1) how to realize the full potential of energy materials through the manipulation of morphologies, and 2) how the hierarchical structure benefits the charge transport, promotes the interfacial properties, prolongs the electrode stability and battery lifetime.

  15. Mechanical Properties of Lithium-Ion Battery Separator Materials

    E-Print Network [OSTI]

    Petta, Jason

    -ion batteries like on the inside Anode Separator Cathode 500 nm 20 um20 um Anode: Graphite SeparatorMechanical Properties of Lithium-Ion Battery Separator Materials Patrick Sinko B.S. Materials and motivation ­ Why study lithium-ion batteries? ­ Lithium-ion battery fundamentals ­ Why study the mechanical

  16. Anode materials for lithium-ion batteries

    DOE Patents [OSTI]

    Sunkara, Mahendra Kumar; Meduri, Praveen; Sumanasekera, Gamini

    2014-12-30T23:59:59.000Z

    An anode material for lithium-ion batteries is provided that comprises an elongated core structure capable of forming an alloy with lithium; and a plurality of nanostructures placed on a surface of the core structure, with each nanostructure being capable of forming an alloy with lithium and spaced at a predetermined distance from adjacent nanostructures.

  17. Argonne's Advanced Battery Materials Synthesis and

    E-Print Network [OSTI]

    Kemner, Ken

    don't want to take on the financial risk of process scale-up and development for materials that haven in battery, fuel cell, and other budding technologies supporting the nation's energy and portable development, Argonne researchers use proven industrial software programs to create simulations and unit

  18. Secondary battery material and synthesis method

    DOE Patents [OSTI]

    Liu, Hongjian; Kepler, Keith Douglas; Wang, Yu

    2013-10-22T23:59:59.000Z

    A composite Li.sub.1+xMn.sub.2-x-yM.sub.yO.sub.4 cathode material stabilized by treatment with a second transition metal oxide phase that is highly suitable for use in high power and energy density Li-ion cells and batteries. A method for treating a Li.sub.1+xMn.sub.2-x-yM.sub.yO.sub.4 cathode material utilizing a dry mixing and firing process.

  19. Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /

    E-Print Network [OSTI]

    Lee, Dae Hoe

    2013-01-01T23:59:59.000Z

    Electrode for Sodium Ion Batteries. Chemistry of Materialsnickel fluoride in Li ion batteries. Electrochimica Actafor advanced lithium ion batteries. Materials Science and

  20. Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /

    E-Print Network [OSTI]

    Lee, Dae Hoe

    2013-01-01T23:59:59.000Z

    graphite negative electrode for lithium-ion batteries.batteries. The Na anode materials must not be overlooked since graphite-

  1. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries

    E-Print Network [OSTI]

    Lin, Feng

    2014-01-01T23:59:59.000Z

    O 2 Cathode Material in Lithium Ion Batteries. Adv. Energysolvent decomposition in lithium ion batteries: first-Cathode Materials for Lithium-Ion Batteries. Adv. Funct.

  2. Develop high energy high power Li-ion battery cathode materials : a first principles computational study

    E-Print Network [OSTI]

    Xu, Bo; Xu, Bo

    2012-01-01T23:59:59.000Z

    of cathode materials for lithium batteries guided by first-facing rechargeable lithium batteries. Nature, 2001. 414(M.S. Whittingham, Lithium batteries and cathode materials.

  3. Characterization of Materials for Li-ion Batteries: Success Stories...

    Broader source: Energy.gov (indexed) [DOE]

    Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User Program DOE 2010 Vehicle Technologies Annual Merit Review and Peer...

  4. Electrode Materials for Rechargeable Lithium-Ion Batteries: A...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrode Materials for Rechargeable Lithium-Ion Batteries: A New Synthetic Approach Technology available for licensing: New high-energy cathode materials for use in rechargeable...

  5. Making Li-air batteries rechargeable: material challenges

    SciTech Connect (OSTI)

    Shao, Yuyan; Ding, Fei; Xiao, Jie; Zhang, Jian; Xu, Wu; Park, Seh Kyu; Zhang, Jiguang; Wang, Yong; Liu, Jun

    2013-02-25T23:59:59.000Z

    A Li-air battery could potentially provide three to five times higher energy density/specific energy than conventional batteries, thus enable the driving range of an electric vehicle comparable to a gasoline vehicle. However, making Li-air batteries rechargeable presents significant challenges, mostly related with materials. Herein, we discuss the key factors that influence the rechargeability of Li-air batteries with a focus on nonaqueous system. The status and materials challenges for nonaqueous rechargeable Li-air batteries are reviewed. These include electrolytes, cathode (electocatalysts), lithium metal anodes, and oxygen-selective membranes (oxygen supply from air). The perspective of rechargeable Li-air batteries is provided.

  6. Characterization of nanostructured materials for lithium-ion batteries and electrochemical capacitors

    E-Print Network [OSTI]

    Augustyn, Veronica

    2013-01-01T23:59:59.000Z

    of High Energy-Density Batteries. Electrochemistry: Past and1971). Huggins, R. A. Advanced Batteries: Materials ScienceC. A. & Scrosati, B. Modern Batteries: An Introduction to

  7. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries

    E-Print Network [OSTI]

    Lin, Feng

    2014-01-01T23:59:59.000Z

    Layered Oxides for Lithium Batteries. Nano Lett. 13, 3857–O 2 Cathode Material in Lithium Ion Batteries. Adv. Energydecomposition in lithium ion batteries: first-principles

  8. Low Cost Components: Screening of Advanced Battery Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mitsubishi Chemical, and ConocoPhillips Vehicle Technologies Program Barriers Identify lithium-ion battery materials, with enhanced stability, that lower cell-level costs while...

  9. Advanced Cathode Material Development for PHEV Lithium Ion Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Advanced Cathode Material Development for PHEV Lithium Ion Batteries High Energy Novel Cathode Alloy Automotive Cell Develop & evaluate...

  10. Advanced Cathode Material Development for PHEV Lithium Ion Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Advanced Cathode Material Development for PHEV Lithium Ion Batteries Vehicle Technologies Office Merit Review 2014: High Energy Novel...

  11. By losing their shape, material fails batteries | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    longer lasting materials for rechargeable batteries in devices including cell phones and electric cars. The international team of scientists worked at EMSL, and their findings...

  12. Characterization of electrochemical systems and batteries: Materials and systems

    SciTech Connect (OSTI)

    McBreen, J.

    1992-01-01T23:59:59.000Z

    Materials are a pacing problem in battery development. The battery environment, particularly in rechargeable batteries, places great demands on materials. Characterization of battery materials is difficult because of their complex nature. In many cases meaningful characterization requires iii situ methods. Fortunately, several new electrochemical and spectroscopic techniques for in situ characterization studies have recently become available, and reports of new techniques have become more frequent. The opportunity now exists to utilize advanced instrumentation to define detailed features, participating chemical species and interfacial structure of battery materials with a precision heretofore not possible. This overview gives key references to these techniques and discusses the application of x-ray absorption spectroscopy to the study of battery materials.

  13. Characterization of electrochemical systems and batteries: Materials and systems

    SciTech Connect (OSTI)

    McBreen, J.

    1992-12-01T23:59:59.000Z

    Materials are a pacing problem in battery development. The battery environment, particularly in rechargeable batteries, places great demands on materials. Characterization of battery materials is difficult because of their complex nature. In many cases meaningful characterization requires iii situ methods. Fortunately, several new electrochemical and spectroscopic techniques for in situ characterization studies have recently become available, and reports of new techniques have become more frequent. The opportunity now exists to utilize advanced instrumentation to define detailed features, participating chemical species and interfacial structure of battery materials with a precision heretofore not possible. This overview gives key references to these techniques and discusses the application of x-ray absorption spectroscopy to the study of battery materials.

  14. Hierarchically Structured Materials for Lithium Batteries. |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium-ion battery (LIB) is one of the most promising power sources to be deployed in electric vehicles (EV), including solely battery powered vehicles, plug-in hybrid electric...

  15. Material review of Li ion battery separators

    SciTech Connect (OSTI)

    Weber, Christoph J., E-mail: Christoph.Weber@freudenberg-nw.com; Geiger, Sigrid, E-mail: Christoph.Weber@freudenberg-nw.com [Freudenberg Vliesstoffe SE and Co KG, 69465 Weinheim (Germany); Falusi, Sandra; Roth, Michael [Freudenberg Forschungsdienste SE and Co KG, 69465 Weinheim (Germany)

    2014-06-16T23:59:59.000Z

    Separators for Li Ion batteries have a strong impact on cell production, cell performance, life, as well as reliability and safety. The separator market volume is about 500 million m{sup 2} mainly based on consumer applications. It is expected to grow strongly over the next decade for mobile and stationary applications using large cells. At present, the market is essentially served by polyolefine membranes. Such membranes have some technological limitations, such as wettability, porosity, penetration resistance, shrinkage and meltdown. The development of a cell failure due to internal short circuit is potentially closely related to separator material properties. Consequently, advanced separators became an intense area of worldwide research and development activity in academia and industry. New separator technologies are being developed especially to address safety and reliability related property improvements.

  16. Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques

    E-Print Network [OSTI]

    Doeff, Marca M.

    2013-01-01T23:59:59.000Z

    Alternatives to Current Lithium-Ion Batteries. Adv. EnergyMaterials for Lithium Ion Batteries. Materials Matters. 7 4.to the Study of Lithium Ion Batteries. J. Solid State

  17. Ab-initio study of cathode materials for lithium batteries

    E-Print Network [OSTI]

    Reed, John Stuart, 1968-

    2003-01-01T23:59:59.000Z

    Using first principles calculations the effect of electronic structure on the stability of positive electrode materials for lithium rechargeable batteries is investigated. The investigation focuses upon lithiated ?-NaFeO? ...

  18. Packaging material for thin film lithium batteries

    DOE Patents [OSTI]

    Bates, John B. (116 Baltimore Dr., Oak Ridge, TN 37830); Dudney, Nancy J. (11634 S. Monticello Rd., Knoxville, TN 37922); Weatherspoon, Kim A. (223 Wadsworth Pl., Oak Ridge, TN 37830)

    1996-01-01T23:59:59.000Z

    A thin film battery including components which are capable of reacting upon exposure to air and water vapor incorporates a packaging system which provides a barrier against the penetration of air and water vapor. The packaging system includes a protective sheath overlying and coating the battery components and can be comprised of an overlayer including metal, ceramic, a ceramic-metal combination, a parylene-metal combination, a parylene-ceramic combination or a parylene-metal-ceramic combination.

  19. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries

    E-Print Network [OSTI]

    Lin, Feng

    2014-01-01T23:59:59.000Z

    Layered Oxides for Lithium Batteries. Nano Lett. 13, 3857–Material in Lithium Ion Batteries. Adv. Energy Mater. n/a–n/decomposition in lithium ion batteries: first-principles

  20. EV Everywhere Batteries Workshop - Materials Processing and Manufactur...

    Energy Savers [EERE]

    More Documents & Publications EV Everywhere Batteries Workshop - Next Generation Lithium Ion Batteries Breakout Session Report EV Everywhere Batteries Workshop - Beyond...

  1. Nanostructured material for advanced energy storage : magnesium battery cathode development.

    SciTech Connect (OSTI)

    Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

    2010-11-01T23:59:59.000Z

    Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

  2. Venture Capital Finance

    Broader source: Energy.gov [DOE]

    Plenary III: Project Finance and Investment Venture Capital Finance Brian Baynes, Partner, Flagship Ventures

  3. High capacity nickel battery material doped with alkali metal cations

    DOE Patents [OSTI]

    Jackovitz, John F. (Monroeville, PA); Pantier, Earl A. (Penn Hills, PA)

    1982-05-18T23:59:59.000Z

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  4. Production of battery grade materials via an oxalate method

    DOE Patents [OSTI]

    Belharouak, Ilias; Amine, Khalil

    2014-04-29T23:59:59.000Z

    An active electrode material for electrochemical devices such as lithium ion batteries includes a lithium transition metal oxide which is free of sodium and sulfur contaminants. The lithium transition metal oxide is prepared by calcining a mixture of a lithium precursor and a transition metal oxalate. Electrochemical devices use such active electrodes.

  5. Post-Test Analysis of Lithium-Ion Battery Materials at Argonne...

    Broader source: Energy.gov (indexed) [DOE]

    Test Analysis of Lithium-Ion Battery Materials at Argonne National Laboratory Post-Test Analysis of Lithium-Ion Battery Materials at Argonne National Laboratory 2013 DOE Hydrogen...

  6. Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Graphite and Olivine-Based Materials for Li-Ion Batteries Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries Presentation from the U.S. DOE Office of Vehicle...

  7. Hard templating synthesis of mesoporous and nanowire SnO2 lithium battery anode materials

    E-Print Network [OSTI]

    Cho, Jaephil

    Hard templating synthesis of mesoporous and nanowire SnO2 lithium battery anode materials Hyesun materials for lithium batteries were prepared using KIT-6 and SBA-15 SiO2 templates as an anode material for lithium batteries due to its high capacity (>600 mAh gŔ1 ) compared with graphite

  8. Computational Research on Lithium Ion Battery Materials A Dissertation Submitted to the Graduate Faculty of

    E-Print Network [OSTI]

    Holzwarth, Natalie

    Computational Research on Lithium Ion Battery Materials by Ping Tang A Dissertation Submitted Research interest in lithium battery materials 1 1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.2 LiFePO4 battery material . . . . . . . . . . . . . . . . . . . . . . . . 3 1.2.1 Why LiFePO4

  9. Electrode materials and lithium battery systems

    DOE Patents [OSTI]

    Amine, Khalil (Downers Grove, IL); Belharouak, Ilias (Westmont, IL); Liu, Jun (Naperville, IL)

    2011-06-28T23:59:59.000Z

    A material comprising a lithium titanate comprising a plurality of primary particles and secondary particles, wherein the average primary particle size is about 1 nm to about 500 nm and the average secondary particle size is about 1 .mu.m to about 4 .mu.m. In some embodiments the lithium titanate is carbon-coated. Also provided are methods of preparing lithium titanates, and devices using such materials.

  10. Olivine Composite Cathode Materials for Improved Lithium Ion Battery Performance

    SciTech Connect (OSTI)

    Ward, R.M.; Vaughey, J.T.

    2006-01-01T23:59:59.000Z

    Composite cathode materials in lithium ion batteries have become the subject of a great amount of research recently as cost and safety issues related to LiCoO2 and other layered structures have been discovered. Alternatives to these layered materials include materials with the spinel and olivine structures, but these present different problems, e.g. spinels have low capacities and cycle poorly at elevated temperatures, and olivines exhibit extremely low intrinsic conductivity. Previous work has shown that composite structures containing spinel and layered materials have shown improved electrochemical properties. These types of composite structures have been studied in order to evaluate their performance and safety characteristics necessary for use in lithium ion batteries in portable electronic devices, particularly hybrid-electric vehicles. In this study, we extended that work to layered-olivine and spinel-olivine composites. These materials were synthesized from precursor salts using three methods: direct reaction, ball-milling, and a coreshell synthesis method. X-ray diffraction spectra and electrochemical cycling data show that the core-shell method was the most successful in forming the desired products. The electrochemical performance of the cells containing the composite cathodes varied dramatically, but the low overpotential and reasonable capacities of the spinel-olivine composites make them a promising class for the next generation of lithium ion battery cathodes.

  11. Improved Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas Edward

    2012-01-01T23:59:59.000Z

    commercial Li-ion batteries today use graphite or a mixturein certain primary batteries). Graphite has a potential of

  12. Novel carbonaceous materials for lithium secondary batteries

    SciTech Connect (OSTI)

    Sandi, G.; Winans, R.E.; Carrado, K.A.; Johnson, C.S.

    1997-07-01T23:59:59.000Z

    Carbonaceous materials have been synthesized using pillared clays (PILCs) as templates. The PILC was loaded with organic materials such as pyrene in the liquid and vapor phase, styrene in the vapor phase, trioxane, ethylene and propylene. The samples were then pyrolyzed at 700 C in an inert atmosphere, followed by dissolution of the inorganic template by conventional demineralization methods. X-ray powder diffraction of the carbons showed broad d{sub 002} peaks in the diffraction pattern, indicative of a disordered or turbostratic system. N{sub 2} BET surface areas of the carbonaceous materials range from 10 to 100 m{sup 2}/g. There is some microporosity (r < 1 nm) in the highest surface area carbons. Most of the surface area, however, comes from a mixture of micro and mesopores with radii of 2--5 nm. Electrochemical studies were performed on these carbons. Button cells were fabricated with capacity- limiting carbon pellets electrodes as the cathode a/nd metallic lithium foil as the anode. Large reversible capacities (up to 850 mAh/g) were achieved for most of the samples. The irreversible capacity loss was less than 180 mAh/g after the first cycle, suggesting that these types of carbon materials are very stable to lithium insertion and de-insertion reactions.

  13. The Science of Electrode Materials for Lithium Batteries

    SciTech Connect (OSTI)

    Fultz, Brent

    2007-03-15T23:59:59.000Z

    Rechargeable lithium batteries continue to play the central role in power systems for portable electronics, and could play a role of increasing importance for hybrid transportation systems that use either hydrogen or fossil fuels. For example, fuel cells provide a steady supply of power, whereas batteries are superior when bursts of power are needed. The National Research Council recently concluded that for dismounted soldiers "Among all possible energy sources, hybrid systems provide the most versatile solutions for meeting the diverse needs of the Future Force Warrior. The key advantage of hybrid systems is their ability to provide power over varying levels of energy use, by combining two power sources." The relative capacities of batteries versus fuel cells in a hybrid power system will depend on the capabilities of both. In the longer term, improvements in the cost and safety of lithium batteries should lead to a substantial role for electrochemical energy storage subsystems as components in fuel cell or hybrid vehicles. We have completed a basic research program for DOE BES on anode and cathode materials for lithium batteries, extending over 6 years with a 1 year phaseout period. The emphasis was on the thermodynamics and kinetics of the lithiation reaction, and how these pertain to basic electrochemical properties that we measure experimentally — voltage and capacity in particular. In the course of this work we also studied the kinetic processes of capacity fade after cycling, with unusual results for nanostructued Si and Ge materials, and the dynamics underlying electronic and ionic transport in LiFePO4. This document is the final report for this work.

  14. Performance Characteristics of Cathode Materials for Lithium-Ion Batteries: A Monte Carlo Strategy

    E-Print Network [OSTI]

    Subramanian, Venkat

    Performance Characteristics of Cathode Materials for Lithium-Ion Batteries: A Monte Carlo Strategy to study the performance of cathode materials in lithium-ion batteries. The methodology takes into account. Published September 26, 2008. Lithium-ion batteries are state-of-the-art power sources1 for por- table

  15. Nanoparticle iron-phosphate anode material for Li-ion battery Dongyeon Son

    E-Print Network [OSTI]

    Park, Byungwoo

    density.1 The graphite generally used in lithium rechargeable batteries has a capacity of 372 mNanoparticle iron-phosphate anode material for Li-ion battery Dongyeon Son School of Materials rechargeable batteries. The electrochemical properties of the nanoparticle iron phosphates were characterized

  16. NANOWIRE CATHODE MATERIAL FOR LITHIUM-ION BATTERIES

    SciTech Connect (OSTI)

    John Olson, PhD

    2004-07-21T23:59:59.000Z

    This project involved the synthesis of nanowire ă-MnO2 and characterization as cathode material for high-power lithium-ion batteries for EV and HEV applications. The nanowire synthesis involved the edge site decoration nanowire synthesis developed by Dr. Reginald Penner at UC Irvine (a key collaborator in this project). Figure 1 is an SEM image showing ă-MnO2 nanowires electrodeposited on highly oriented pyrolytic graphite (HOPG) electrodes. This technique is unique to other nanowire template synthesis techniques in that it produces long (>500 um) nanowires which could reduce or eliminate the need for conductive additives due to intertwining of fibers. Nanowire cathode for lithium-ion batteries with surface areas 100 times greater than conventional materials can enable higher power batteries for electric vehicles (EVs) and hybrid electric vehicles (HEVs). The synthesis of the ă-MnO2 nanowires was successfully achieved. However, it was not found possible to co-intercalate lithium directly in the nanowire synthesis. Based on input from proposal reviewers, the scope of the project was altered to attempt the conversion into spinel LiMn2O4 nanowire cathode material by solid state reaction of the ă-MnO2 nanowires with LiNO3 at elevated temperatures. Attempts to perform the conversion on the graphite template were unsuccessful due to degradation of the graphite apparently caused by oxidative attack by LiNO3. Emphasis then shifted to quantitative removal of the nanowires from the graphite, followed by the solid state reaction. Attempts to quantitatively remove the nanowires by several techniques were unsatisfactory due to co-removal of excess graphite or poor harvesting of nanowires. Intercalation of lithium into ă-MnO2 electrodeposited onto graphite was demonstrated, showing a partial demonstration of the ă-MnO2 material as a lithium-ion battery cathode material. Assuming the issues of nanowires removal can be solved, the technique does offer potential for creating high-power lithium-ion battery cathode needed for advanced EV and HEVs. Several technical advancements will still be required to meet this goal, and are likely topics for future SBIR feasibility studies.

  17. New materials for batteries and fuel cells. Materials Research Society symposium proceedings, Volume 575

    SciTech Connect (OSTI)

    Doughty, D.H.; Nazar, L.F.; Arakawa, Masayasu; Brack, H.P.; Naoi, Katsuhiko [eds.

    2000-07-01T23:59:59.000Z

    This proceedings volume is organized into seven sections that reflect the materials systems and issues of electrochemical materials R and D in batteries, fuel cells, and capacitors. The first three parts are largely devoted to lithium ion rechargeable battery materials since that electrochemical system has received much of the attention from the scientific community. Part 1 discusses cathodes for lithium ion rechargeable batteries as well as various other battery systems. Part 2 deals with electrolytes and cell stability, and Part 3 discusses anode developments, focusing on carbon and metal oxides. Part 4 focuses on another rechargeable system that has received substantial interest, nickel/metal hydride battery materials. The next two parts discuss fuel cells--Part 5 deals with Proton Exchange Membrane (PEM) fuel cells, and Part 6 discusses oxide materials for solid oxide fuel cells. The former has the benefit of operating around room temperature, whereas the latter has the benefit of operating with a more diverse (non-hydrogen) fuel source. Part 7 presents developments in electrochemical capacitors, termed Supercapacitors. These devices are receiving renewed interest and have shown substantial improvements in the past few years. In all, the results presented at this symposium gave a deeper understanding of the relationship between synthesis, properties, and performance of power source materials. Papers are processed separately for inclusion on the data base.

  18. Improved Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas Edward

    2012-01-01T23:59:59.000Z

    T. , Tozawa, K. Prog. Batteries Solar Cells 1990, 9, 209. E.Costs of Lithium-Ion Batteries for Vechicles. ” Center forin Solids: Solid State Batteries and Devices, Ed. by W. vn

  19. Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries

    E-Print Network [OSTI]

    Schmidt, Volker

    Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries Ralf August 30, 2010 Abstract Battery technology plays an important role in energy storage. In particular, lithium­ ion (Li-ion) batteries are of great interest, because of their high capacity, long cycle life

  20. Sidorenkite (Na3MnPO4CO3): A New Intercalation Cathode Material for Na-Ion Batteries

    E-Print Network [OSTI]

    Ceder, Gerbrand

    - 180 Wh/kg) than other rechargeable batteries, such as lead-acid and Ni-Cd batteries. Na-ion batteriesSidorenkite (Na3MnPO4CO3): A New Intercalation Cathode Material for Na-Ion Batteries Hailong Chen, Cambridge, United Kingdom *S Supporting Information ABSTRACT: Na-ion batteries represent an effective energy

  1. Study of polypyrrole graphite composite as anode material for secondary lithium-ion batteries

    E-Print Network [OSTI]

    Popov, Branko N.

    Study of polypyrrole graphite composite as anode material for secondary lithium-ion batteries of the composite. The composite material has been studied for specific discharge capacity, coulombic efficiency for the Li-ion battery. Of various carbon materials that have been tried, graphite is favored because it (i

  2. Materials for electrical battery technology. (Latest citations from Metadex). Published Search

    SciTech Connect (OSTI)

    NONE

    1995-12-01T23:59:59.000Z

    The bibliography contains citations concerning materials used in batteries. Among materials discussed are lead, nickel, magnesium and zinc alloys, rare-earth-based hydrogen, aluminum, and lead-calcium alloys. Recovery and recycling of polypropylene from automotive batteries are referenced, and use of polyphase as rechargeable electrodes in advanced battery systems is also examined.(Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  3. Materials for electrical battery technology. (Latest citations from Metadex). NewSearch

    SciTech Connect (OSTI)

    Not Available

    1994-10-01T23:59:59.000Z

    The bibliography contains citations concerning materials used in batteries. Among materials discussed are lead, nickel, magnesium and zinc alloys, rare-earth-based hydrogen, aluminum, and lead-calcium alloys. Recovery and recycling of polypropylene from automotive batteries are referenced, and use of polyphase as rechargeable electrodes in advanced battery systems is also examined. (Contains a minimum of 153 citations and includes a subject term index and title list.)

  4. Nanostructured materials for lithium-ion batteries: Surface conductivity vs. bulk

    E-Print Network [OSTI]

    Ryan, Dominic

    Nanostructured materials for lithium-ion batteries: Surface conductivity vs. bulk ion cathode materials for high capacity lithium-ion batteries. Owing to their inherently low electronic-ion batteries. Lithium transition metal phosphates such as LiFePO4,1 LiMnPO4,2 Li3V2(PO4)3 3 and LiVPO4F4 have

  5. Study of Sn-Coated Graphite as Anode Material for Secondary Lithium-Ion Batteries

    E-Print Network [OSTI]

    Popov, Branko N.

    Study of Sn-Coated Graphite as Anode Material for Secondary Lithium-Ion Batteries Basker Sandia National Laboratories, Albuquerque, New Mexico, USA Tin-graphite composites have been developed as an alternate anode material for Li-ion batteries using an autocatalytic deposition technique. The specific

  6. Layered cathode materials for lithium ion rechargeable batteries

    DOE Patents [OSTI]

    Kang, Sun-Ho (Naperville, IL); Amine, Khalil (Downers Grove, IL)

    2007-04-17T23:59:59.000Z

    A number of materials with the composition Li.sub.1+xNi.sub..alpha.Mn.sub..beta.Co.sub..gamma.M'.sub..delta.O.sub.2-- zF.sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, .alpha. is between about 0.2 and 0.6, .beta. is between about 0.2 and 0.6, .gamma. is between about 0 and 0.3, .delta. is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling.

  7. Facile synthesis of nanostructured vanadium oxide as cathode materials for efficient Li-ion batteries

    E-Print Network [OSTI]

    Cao, Guozhong

    -ion batteries Yanyi Liu,a Evan Uchaker,a Nan Zhou,ab Jiangang Li,ac Qifeng Zhanga and Guozhong Cao*a Received 23 and VO2 (B) nanorods were tested as active cathode materials for Li-ion batteries. The V2O5 sheet for efficient Li-ion batteries. Introduction The expansion and demands for energy use in the past several

  8. Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries

    E-Print Network [OSTI]

    , Li-ion batteries suffer from strong self-heating, which limits their life-time and creates* Nano-Device Laboratory, Department of Electrical Engineering and Materials Science and Engineering, automotive and aerospace industries. Li-ion batteries are an essential part of the hybrid electric vehicles

  9. The structural design of electrode materials for high energy lithium batteries.

    SciTech Connect (OSTI)

    Thackeray, M.; Chemical Sciences and Engineering Division

    2007-01-01T23:59:59.000Z

    Lithium batteries are used to power a diverse range of applications from small compact devices, such as smart cards and cellular telephones to large heavy duty devices such as uninterrupted power supply units and electric- and hybrid-electric vehicles. This paper briefly reviews the approaches to design advanced materials to replace the lithiated graphite and LiCoO{sub 2} electrodes that dominate today's lithium-ion batteries in order to increase their energy and safety. The technological advantages of lithium batteries are placed in the context of water-based- and high-temperature battery systems.

  10. Simulation of NMR Fermi contact shifts for Lithium battery materials: the need of an efficient hybrid functional approach

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    shift calculations for assisting structural characterization of battery materials, we propose1 Simulation of NMR Fermi contact shifts for Lithium battery materials: the need of an efficient-ion batteries: olivine LiMPO4 (M = Mn, Fe, Co, Ni), anti-NASICON type Li3M2(PO4)3 (M = Fe, V), and antifluorite

  11. Novel mixed polyanions lithium-ion battery cathode materials predicted by high-throughput ab initio computations

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Novel mixed polyanions lithium-ion battery cathode materials predicted by high-throughput ab initio (>700 Wh/kg) cathode materials for lithium-ion batteries. 1 Introduction The widespread use of lithium-ion monoclinic phase).5 However, the field of lithium-ion batteries is very active, and a large number

  12. Novel Energy Sources -Material Architecture and Charge Transport in Solid State Ionic Materials for Rechargeable Li ion Batteries

    SciTech Connect (OSTI)

    Katiyar, Ram S; Gómez, M; Majumder, S B; Morell, G; Tomar, M S; Smotkin, E; Bhattacharya, P; Ishikawa, Y

    2009-01-19T23:59:59.000Z

    Since its introduction in the consumer market at the beginning of 1990s by Sony Corporation ‘Li-ion rechargeable battery’ and ‘LiCoO2 cathode’ is an inseparable couple for highly reliable practical applications. However, a separation is inevitable as Li-ion rechargeable battery industry demand more and more from this well serving cathode. Spinel-type lithium manganate (e.g., LiMn2O4), lithium-based layered oxide materials (e.g., LiNiO2) and lithium-based olivine-type compounds (e.g., LiFePO4) are nowadays being extensively studied for application as alternate cathode materials in Li-ion rechargeable batteries. Primary goal of this project was the advancement of Li-ion rechargeable battery to meet the future demands of the energy sector. Major part of the research emphasized on the investigation of electrodes and solid electrolyte materials for improving the charge transport properties in Li-ion rechargeable batteries. Theoretical computational methods were used to select electrodes and electrolyte material with enhanced structural and physical properties. The effect of nano-particles on enhancing the battery performance was also examined. Satisfactory progress has been made in the bulk form and our efforts on realizing micro-battery based on thin films is close to give dividend and work is progressing well in this direction.

  13. Investigation on Aluminum-Based Amorphous Metallic Glass as New Anode Material in Lithium Ion Batteries

    E-Print Network [OSTI]

    Meng, Shirley Y.

    Aluminum based amorphous metallic glass powders were produced and tested as the anode materials for the lithium ion rechargeable batteries. Ground Al??Ni₁?La₁? was found to have a ...

  14. Material characterization of high-voltage lithium-ion battery models for crashworthiness analysis

    E-Print Network [OSTI]

    Meier, Joseph D. (Joseph David)

    2013-01-01T23:59:59.000Z

    A three-phased study of the material properties and post-impact behavior of prismatic pouch lithium-ion battery cells was conducted to refine computational finite element models and explore the mechanisms of thermal runaway ...

  15. Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries

    Broader source: Energy.gov (indexed) [DOE]

    Graphite and Olivine-Based Materials for Li-Ion Batteries K. Zaghib Hydro-Qubec (IREQ), 1800 Lionel-Boulet Varennes, QC, Canada, J3X 1S1 BATT Review Meeting February 25 - 28,...

  16. A layered sodium titanate as promising anode material for sodium ion batteries

    E-Print Network [OSTI]

    Wu, Di, S.M. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Sodium ion batteries have recently received great attention for large-scale energy applications because of the abundance and low cost of sodium source. Although some cathode materials with desirable electrochemical properties ...

  17. Thin film lithium-based batteries and electrochromic devices fabricated with nanocomposite electrode materials

    DOE Patents [OSTI]

    Gillaspie, Dane T; Lee, Se-Hee; Tracy, C. Edwin; Pitts, John Roland

    2014-02-04T23:59:59.000Z

    Thin-film lithium-based batteries and electrochromic devices (10) are fabricated with positive electrodes (12) comprising a nanocomposite material composed of lithiated metal oxide nanoparticles (40) dispersed in a matrix composed of lithium tungsten oxide.

  18. New nanocrystalline manganese oxides as cathode materials for lithium batteries : electron microscopy, electrochemical and X-ray absorption studies

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 New nanocrystalline manganese oxides as cathode materials for lithium batteries : electron: manganese oxide, lithium batteries, nanomaterials Corresponding author: Pierre Strobel, tel. 33 476 887 940 with lithium iodide in aqueous medium at room temperature. Transmission electron microscopy (TEM) showed

  19. Silver particles improve performance of battery material | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at the U.S. Department of Energy's Argonne National Laboratory are working to create an electric car battery that is smaller, cheaper and allows drivers to go farther on a...

  20. Battery Anodes > Batteries & Fuel Cells > Research > The Energy Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Batteries Batteries An error occurred. Try watching

  1. Battery Cathodes > Batteries & Fuel Cells > Research > The Energy Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Batteries Batteries An error occurred. Try watchingCenter

  2. Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries

    E-Print Network [OSTI]

    Cui, Yi

    Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries Hyun diameters less than 10 nm and lengths of several micrometers. Galvanostatic battery testing showed that Li, lithium ion battery, LiMn2O4 nanowires, high power density, Jahn-Teller distortion T he high energy

  3. High-Capacity Micrometer-Sized Li2S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries

    E-Print Network [OSTI]

    Cui, Yi

    Lithium-Ion Batteries Yuan Yang, Guangyuan Zheng, Sumohan Misra,§ Johanna Nelson,§ Michael F. Toney for lithium metal-free rechargeable batteries. It has a theoretical capacity of 1166 mAh/g, which is nearly 1 as the cathode material for rechargeable lithium-ion batteries with high specific energy. INTRODUCTION

  4. STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES

    E-Print Network [OSTI]

    Wilcox, James D.

    2010-01-01T23:59:59.000Z

    facing rechargeable lithium batteries. Nature, 2001. 414(of rechargeable lithium batteries, I. Lithium manganeseof rechargeable lithium batteries, II. Lithium ion

  5. Material and Energy Flows in the Materials Production, Assembly, and End-of-Life Stages of the Automotive Lithium-Ion Battery Life Cycle

    SciTech Connect (OSTI)

    Dunn, Jennifer B. [Argonne National Lab. (ANL), Argonne, IL (United States); Gaines, Linda [Argonne National Lab. (ANL), Argonne, IL (United States); Barnes, Matthew [Argonne National Lab. (ANL), Argonne, IL (United States); Sullivan, John L. [Argonne National Lab. (ANL), Argonne, IL (United States); Wang, Michael [Argonne National Lab. (ANL), Argonne, IL (United States)

    2014-01-01T23:59:59.000Z

    This document contains material and energy flows for lithium-ion batteries with an active cathode material of lithium manganese oxide (LiMn?O?). These data are incorporated into Argonne National Laboratory’s Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, replacing previous data for lithium-ion batteries that are based on a nickel/cobalt/manganese (Ni/Co/Mn) cathode chemistry. To identify and determine the mass of lithium-ion battery components, we modeled batteries with LiMn?O? as the cathode material using Argonne’s Battery Performance and Cost (BatPaC) model for hybrid electric vehicles, plug-in hybrid electric vehicles, and electric vehicles. As input for GREET, we developed new or updated data for the cathode material and the following materials that are included in its supply chain: soda ash, lime, petroleum-derived ethanol, lithium brine, and lithium carbonate. Also as input to GREET, we calculated new emission factors for equipment (kilns, dryers, and calciners) that were not previously included in the model and developed new material and energy flows for the battery electrolyte, binder, and binder solvent. Finally, we revised the data included in GREET for graphite (the anode active material), battery electronics, and battery assembly. For the first time, we incorporated energy and material flows for battery recycling into GREET, considering four battery recycling processes: pyrometallurgical, hydrometallurgical, intermediate physical, and direct physical. Opportunities for future research include considering alternative battery chemistries and battery packaging. As battery assembly and recycling technologies develop, staying up to date with them will be critical to understanding the energy, materials, and emissions burdens associated with batteries.

  6. Material and energy flows in the materials production, assembly, and end-of-life stages of the automotive lithium-ion battery life cycle

    SciTech Connect (OSTI)

    Dunn, J.B.; Gaines, L.; Barnes, M.; Wang, M.; Sullivan, J. (Energy Systems)

    2012-06-21T23:59:59.000Z

    This document contains material and energy flows for lithium-ion batteries with an active cathode material of lithium manganese oxide (LiMn{sub 2}O{sub 4}). These data are incorporated into Argonne National Laboratory's Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, replacing previous data for lithium-ion batteries that are based on a nickel/cobalt/manganese (Ni/Co/Mn) cathode chemistry. To identify and determine the mass of lithium-ion battery components, we modeled batteries with LiMn{sub 2}O{sub 4} as the cathode material using Argonne's Battery Performance and Cost (BatPaC) model for hybrid electric vehicles, plug-in hybrid electric vehicles, and electric vehicles. As input for GREET, we developed new or updated data for the cathode material and the following materials that are included in its supply chain: soda ash, lime, petroleum-derived ethanol, lithium brine, and lithium carbonate. Also as input to GREET, we calculated new emission factors for equipment (kilns, dryers, and calciners) that were not previously included in the model and developed new material and energy flows for the battery electrolyte, binder, and binder solvent. Finally, we revised the data included in GREET for graphite (the anode active material), battery electronics, and battery assembly. For the first time, we incorporated energy and material flows for battery recycling into GREET, considering four battery recycling processes: pyrometallurgical, hydrometallurgical, intermediate physical, and direct physical. Opportunities for future research include considering alternative battery chemistries and battery packaging. As battery assembly and recycling technologies develop, staying up to date with them will be critical to understanding the energy, materials, and emissions burdens associated with batteries.

  7. Evaluation of Aerogel Materials for High-Temperature Batteries

    SciTech Connect (OSTI)

    Ashley, Carol S.; Guidotti, Ronald A.; Reed, Scott T.; Reinhardt, Frederick W.

    1999-05-04T23:59:59.000Z

    Siiica aerogels have 1/3 the thermal conductivity of the best commercial composite insulations, or ~13 mW/m-K at 25°C. However, aerogels are transparent in the near IR region of 4-7 µm, which is where the radiation peak from a thermal-battery stack occurs. Titania and carbon- black powders were examined as thermal opacifiers, to reduce radiation at temperatures between 300°C and 600°C, which spans the range of operating temperature for most thermal batteries. The effectiveness of the various opacifiers depended on the loading, with the best overall results being obtained using aerogels filled with carbon black. Fabrication and strength issues still remain, however.

  8. Factors Affecting the Battery Performance of Anthraquinone-based Organic Cathode Materials

    SciTech Connect (OSTI)

    Xu, Wu; Read, Adam L.; Koech, Phillip K.; Hu, Dehong; Wang, Chong M.; Xiao, Jie; Padmaperuma, Asanga B.; Graff, Gordon L.; Liu, Jun; Zhang, Jiguang

    2012-02-01T23:59:59.000Z

    Two organic cathode materials based on poly(anthraquinonyl sulfide) structure with different substitution positions were synthesized and their electrochemical behavior and battery performances were investigated. The substitution positions on the anthraquinone structure, binders for electrode preparation and electrolyte formulations have been found to have significant effects on the battery performances of such organic cathode materials. The substitution position with less steric stress has higher capacity, longer cycle life and better high-rate capability. Polyvinylidene fluoride binder and ether-based electrolytes are favorable for the high capacity and long cycle life of the quinonyl organic cathodes.

  9. Surface treated natural graphite as anode material for high-power Li-ion battery applications.

    SciTech Connect (OSTI)

    Liu, J.; Vissers, D. R.; Amine, K.; Barsukov, I. V.; Henry, F.; Doniger, J.; Chemical Engineering; Superior Graphite Co.

    2006-01-01T23:59:59.000Z

    High power application of Li-ion battery in hybrid electrical vehicles requires low cost and safe cell materials. Among the various carbon anode materials used in lithium ion batteries, natural graphite shows the most promise with advantages in performance and cost. However, natural graphite is not compatible with propylene carbonate (PC)-based electrolytes, which have a lower melting point and improved safety characteristics. The problem with it is that the molecules of propylene carbonate intercalate with Li+ into graphite, and that frequently leads to the exfoliation of the graphite matrix.

  10. Synthesis, Characterization and Testing of Novel Anode and Cathode Materials for Li-Ion Batteries

    SciTech Connect (OSTI)

    White, Ralph E.; Popov, Branko N.

    2002-10-31T23:59:59.000Z

    During this program we have synthesized and characterized several novel cathode and anode materials for application in Li-ion batteries. Novel synthesis routes like chemical doping, electroless deposition and sol-gel method have been used and techniques like impedance, cyclic voltammetry and charge-discharge cycling have been used to characterize these materials. Mathematical models have also been developed to fit the experimental result, thus helping in understanding the mechanisms of these materials.

  11. Method of preparation of carbon materials for use as electrodes in rechargeable batteries

    DOE Patents [OSTI]

    Doddapaneni, Narayan (Alburquerque, NM); Wang, James C. F. (Livermore, CA); Crocker, Robert W. (Fremont, CA); Ingersoll, David (Alburquerque, NM); Firsich, David W. (Dayton, OH)

    1999-01-01T23:59:59.000Z

    A method of producing carbon materials for use as electrodes in rechargeable batteries. Electrodes prepared from these carbon materials exhibit intercalation efficiencies of .apprxeq.80% for lithium, low irreversible loss of lithium, long cycle life, are capable of sustaining a high rates of discharge and are cheap and easy to manufacture. The method comprises a novel two-step stabilization process in which polymeric precursor materials are stabilized by first heating in an inert atmosphere and subsequently heating in air. During the stabilization process, the polymeric precursor material can be agitated to reduce particle fusion and promote mass transfer of oxygen and water vapor. The stabilized, polymeric precursor materials can then be converted to a synthetic carbon, suitable for fabricating electrodes for use in rechargeable batteries, by heating to a high temperature in a flowing inert atmosphere.

  12. Method of preparation of carbon materials for use as electrodes in rechargeable batteries

    DOE Patents [OSTI]

    Doddapaneni, N.; Wang, J.C.F.; Crocker, R.W.; Ingersoll, D.; Firsich, D.W.

    1999-03-16T23:59:59.000Z

    A method is described for producing carbon materials for use as electrodes in rechargeable batteries. Electrodes prepared from these carbon materials exhibit intercalation efficiencies of {approx_equal} 80% for lithium, low irreversible loss of lithium, long cycle life, are capable of sustaining a high rates of discharge and are cheap and easy to manufacture. The method comprises a novel two-step stabilization process in which polymeric precursor materials are stabilized by first heating in an inert atmosphere and subsequently heating in air. During the stabilization process, the polymeric precursor material can be agitated to reduce particle fusion and promote mass transfer of oxygen and water vapor. The stabilized, polymeric precursor materials can then be converted to a synthetic carbon, suitable for fabricating electrodes for use in rechargeable batteries, by heating to a high temperature in a flowing inert atmosphere. 4 figs.

  13. Nanoscale fabrication and modification of selected battery materials

    SciTech Connect (OSTI)

    Kostecki, Robert; Song, Xiang Yun; Kinoshita, Kim; McLarnon, Frank

    2001-06-22T23:59:59.000Z

    Carbon is an integral part of many battery electrodes. We explored the use of semiconductor-processing techniques that involve photolithography to pattern photoresists and subsequent pyrolysis to form carbon microstructures that function as microelectrodes. In this study, we describe the status of the fabrication of carbon microelectrodes obtained by pyrolysis of photoresist. Electrochemical nanometer-scale patterning of the surface of a conducting lithium manganese oxide (LiMn{sub 2}O{sub 4}) by scanning probe microscopy (SPM) was studied. We show that a localized surface chemical change can be confined to a depth which depends on the oxide-tip voltage difference and ambient humidity The ability to produce nanometer-size patterns of chemically modified oxide or nanometer-sized alterations of the oxide morphology is demonstrated and discussed with reference to possible mechanisms.

  14. Template Synthesis of Hollow Sb Nanoparticles as a High-Performance Lithium Battery Anode Material

    E-Print Network [OSTI]

    Cho, Jaephil

    Template Synthesis of Hollow Sb Nanoparticles as a High-Performance Lithium Battery Anode Material­14 the use of metal and carbon composites,15­20 and the introduction of nano- sized metals,21­25 have been reported. Studies involving hollow lithium reactive metal, however, have yet to be reported, although

  15. Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques

    SciTech Connect (OSTI)

    Mehta, Apurva; Stanford Synchrotron Radiation Lightsource; Doeff, Marca M.; Chen, Guoying; Cabana, Jordi; Richardson, Thomas J.; Mehta, Apurva; Shirpour, Mona; Duncan, Hugues; Kim, Chunjoong; Kam, Kinson C.; Conry, Thomas

    2013-04-30T23:59:59.000Z

    We describe the use of synchrotron X-ray absorption spectroscopy (XAS) and X-ray diffraction (XRD) techniques to probe details of intercalation/deintercalation processes in electrode materials for Li ion and Na ion batteries. Both in situ and ex situ experiments are used to understand structural behavior relevant to the operation of devices.

  16. Alkali slurry ozonation to produce a high capacity nickel battery material

    DOE Patents [OSTI]

    Jackovitz, John F. (Monroeville, PA); Pantier, Earl A. (Penn Hills, PA)

    1984-11-06T23:59:59.000Z

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  17. Monomer-Capped Tin Metal Nanoparticles for Anode Materials in Lithium Secondary Batteries

    E-Print Network [OSTI]

    Cho, Jaephil

    Monomer-Capped Tin Metal Nanoparticles for Anode Materials in Lithium Secondary Batteries Mijung Graphite can store 372 mAh/g corresponding to LiC6, and tin can store 970 mAh/g corresponding to Li4.4Sn close to graphite. The reason for failure is believed to be the inhomogeneous volume expansion

  18. Evaluation of Tavorite-Structured Cathode Materials for Lithium-Ion Batteries Using High-Throughput Computing

    E-Print Network [OSTI]

    Mueller, Tim

    Cathode materials with structure similar to the mineral tavorite have shown promise for use in lithium-ion batteries, but this class of materials is relatively unexplored. We use high-throughput density-functional-theory ...

  19. Materials for electrochemical energy storage and conversion II -- Batteries, capacitors and fuel cells. Materials Research Society symposium proceedings, Volume 496

    SciTech Connect (OSTI)

    Ginley, D.S.; Doughty, D.H.; Scrosati, B.; Takamura, T.; Zhang, Z.J. [eds.

    1998-07-01T23:59:59.000Z

    Our energy-hungry world is increasingly relying on new methods to store and convert energy for portable electronics, as well as new, environmentally friendly modes of transportation and electrical energy generation. The availability of advanced materials is linked to the commercial success of improved power sources such as batteries, fuel cells and capacitors with higher specific energy and power, longer cycle life and rapid change/discharge rates. The papers in this symposium were heavily weighted toward lithium batteries. The proceedings volume is organized into six sections highlighting: general papers on a wide variety of rechargeable battery technologies; new approaches to modeling of Li batteries; advances in fuel-cell technology; new work on Li battery cathodes; anodes and electrolytes; and work on super-capacitors. The authors think the volume is an excellent snapshot of the current state of the art in energy storage and conversion technologies, many of which will make a significant impact on society. Separate abstracts were prepared for most papers in this volume.

  20. Materials - Imaging atoms for better batteries ... | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the material's atomic arrangement. These location-dependent changes rely on nickel swapping with lithium, and can raise or lower energy barriers for lithium-ion...

  1. X-ray diffraction and EXAFS analysis of materials for lithium-based rechargeable batteries

    SciTech Connect (OSTI)

    Sharkov, M. D., E-mail: mischar@mail.ioffe.ru; Boiko, M. E.; Bobyl, A. V.; Ershenko, E. M.; Terukov, E. I. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Zubavichus, Y. V. [National Research Centre “Kurchatov Institute” (Russian Federation)

    2013-12-15T23:59:59.000Z

    Lithium iron phosphate LiFePO{sub 4} (triphylite) and lithium titanate Li{sub 4}Ti{sub 5}O{sub 12} are used as components of a number of active materials in modern rechargeable batteries. Samples of these materials are studied by X-ray diffraction and extended X-ray absorption fine structure (EXAFS) spectroscopy. Hypotheses about the phase composition of the analyzed samples are formulated.

  2. Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /

    E-Print Network [OSTI]

    Lee, Dae Hoe

    2013-01-01T23:59:59.000Z

    battery-grade DMC (Novolyte, packed and sealed in Kapton under Ar atmosphere. Electrochemical characterization

  3. CUBICON Materials that Outperform Lithium-Ion Batteries - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C o . C l a r8.0 - HOISTING30,April 2010,Portal

  4. Hydridable material for the negative electrode in a nickel-metal hydride storage battery

    DOE Patents [OSTI]

    Knosp, Bernard (Neuilly-sur-Seine, FR); Bouet, Jacques (Paris, FR); Jordy, Christian (Dourdan, FR); Mimoun, Michel (Neuilly-sur-Marne, FR); Gicquel, Daniel (Lanorville, FR)

    1997-01-01T23:59:59.000Z

    A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula: Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.e where ##EQU1##

  5. Novel air electrode for metal-air battery with new carbon material and method of making same

    DOE Patents [OSTI]

    Ross, P.N. Jr.

    1988-06-21T23:59:59.000Z

    This invention relates to a rechargeable battery or fuel cell. More particularly, this invention relates to a novel air electrode comprising a new carbon electrode support material and a method of making same. 3 figs.

  6. Battery cell feedthrough apparatus

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL)

    1995-01-01T23:59:59.000Z

    A compact, hermetic feedthrough apparatus comprising interfitting sleeve portions constructed of chemically-stable materials to permit unique battery designs and increase battery life and performance.

  7. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01T23:59:59.000Z

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  8. A nuclear magnetic resonance study of hydrogen in battery and chemically prepared material

    SciTech Connect (OSTI)

    Hill, R.J.; Jessel, A.M.

    1987-06-01T23:59:59.000Z

    Solid-state magic-angle-spinning nuclear magnetic resonance studies have been undertaken on positive plate material from lead-acid batteries and on samples of both pure ..cap alpha..-PbO/sub 2/ and pure ..beta..-PbO/sub 2/ prepared by nonelectrochemical methods. Battery positive plate samples contain protons in two different surface and near surface configurations. One of these proton species is associated with mobile, isolated, adsorbed hydroxyl groups, and/or water molecules that can be removed by outgassing. The other proton species is not removed by outgassing; it probably corresponds to water molecules and/of closely spaced hydroxyl groups trapped on internal crystal surfaces. The proton species present in fresh (uncycled) positive plate material are not significantly different in either configuration or abundance from those in extensively cycled samples. Thus, it is unlikely that decline in battery capacity with cycling service is associated with a change in the hydrogen content of PbO/sub 2/.

  9. STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES

    E-Print Network [OSTI]

    Wilcox, James D.

    2010-01-01T23:59:59.000Z

    Solid Solutions: Coupled Lithium-Ion and Electron Mobility.lithium batteries, II. Lithium ion rechargeable batteries.1/4)Ni(3/4)O(2) for lithium-ion batteries. Electrochimica

  10. Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques

    E-Print Network [OSTI]

    Doeff, Marca M.

    2013-01-01T23:59:59.000Z

    Rechargeable Sodium-Ion Batteries: Potential Alternatives toCurrent Lithium-Ion Batteries. Adv. Energy Mater. 2 (2012):J. , Rojo, T. Na-ion Batteries, Recent Advances and Present

  11. STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES

    E-Print Network [OSTI]

    Wilcox, James D.

    2010-01-01T23:59:59.000Z

    Linden, D. , Handbook of Batteries. 2nd ed. 1995, New York:rechargeable lithium batteries. Nature, 2001. 414(6861): p.of rechargeable lithium batteries, I. Lithium manganese

  12. Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques

    E-Print Network [OSTI]

    Doeff, Marca M.

    2013-01-01T23:59:59.000Z

    Charge Distribution in a Lithium Battery Electrode. J. Phys.Aluminum is used for lithium ion battery cathodes and alland copper is used for lithium ion battery anodes. After the

  13. Characterization of nanostructured materials for lithium-ion batteries and electrochemical capacitors

    E-Print Network [OSTI]

    Augustyn, Veronica

    2013-01-01T23:59:59.000Z

    for a 2 V Rechargeable Lithium Battery. Journal of Thein a rechargeable lithium battery. Journal of Power Sourcesexception being the lithium-ion battery (Table 2.1). Table

  14. STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES

    E-Print Network [OSTI]

    Wilcox, James D.

    2010-01-01T23:59:59.000Z

    of LiFePO(4) as lithium battery cathode and comparison withImproved LiFePO(4) Lithium Battery Cathode. ElectrochemicalOptimized LiFePO(4) for lithium battery cathodes. Journal of

  15. Project Description In the search for superior batteries, the road to success is paved with advanced materials: better

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    Project Description In the search for superior batteries, the road to success is paved with advanced materials: better cathodes, better anodes, better electrolytes. The universe of candidates is so vast and the cost of selection and testing them is so great that conventional approaches to materials

  16. Electrochemical Properties of Nanostructured Al1-xCux Alloys as Anode Materials for Rechargeable Lithium-Ion Batteries

    E-Print Network [OSTI]

    Ceder, Gerbrand

    controlling these two properties is the mag- nitude of interaction between the active and the inactiveElectrochemical Properties of Nanostructured Al1-xCux Alloys as Anode Materials for Rechargeable Lithium-Ion Batteries C. Y. Wang,a, * Y. S. Meng,b, * G. Ceder,c, *,z and Y. Lia,d,z a Advanced Materials

  17. Composit, Nanoparticle-Based Anode material for Li-ion Batteries Applied in Hybrid Electric (HEV's)

    SciTech Connect (OSTI)

    Dr. Malgorzata Gulbinska

    2009-08-24T23:59:59.000Z

    Lithium-ion batteries are promising energy storage devices in hybrid and electric vehicles with high specific energy values ({approx}150 Wh/kg), energy density ({approx}400 Wh/L), and long cycle life (>15 years). However, applications in hybrid and electric vehicles require increased energy density and improved low-temperature (<-10 C) performance. Silicon-based anodes are inexpensive, environmentally benign, and offer excellent theoretical capacity values ({approx}4000 mAh/g), leading to significantly less anode material and thus increasing the overall energy density value for the complete battery (>500 Wh/L). However, tremendous volume changes occur during cycling of pure silicon-based anodes. The expansion and contraction of these silicon particles causes them to fracture and lose electrical contact to the current collector ultimately severely limiting their cycle life. In Phase I of this project Yardney Technical Products, Inc. proposed development of a carbon/nano-silicon composite anode material with improved energy density and silicon's cycleability. In the carbon/nano-Si composite, silicon nanoparticles were embedded in a partially-graphitized carbonaceous matrix. The cycle life of anode material would be extended by decreasing the average particle size of active material (silicon) and by encapsulation of silicon nanoparticles in a ductile carbonaceous matrix. Decreasing the average particle size to a nano-region would also shorten Li-ion diffusion path and thus improve rate capability of the silicon-based anodes. Improved chemical inertness towards PC-based, low-temperature electrolytes was expected as an additional benefit of a thin, partially graphitized coating around the active electrode material.

  18. Block copolymer electrolytes for lithium batteries

    E-Print Network [OSTI]

    Hudson, William Rodgers

    2011-01-01T23:59:59.000Z

    facing rechargeable lithium batteries. Nature 414, 359-367 (lithium and lithium-ion batteries. Solid State Ionics 135,electrolytes for lithium-ion batteries. Advanced Materials

  19. Vehicle Technologies Office: Advanced Battery Development, System...

    Broader source: Energy.gov (indexed) [DOE]

    materials and applied battery research into full battery systems for vehicles. The Vehicle Technologies Office's (VTO) Advanced Battery Development, System Analysis, and...

  20. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    for rechargeable lithium batteries. Advanced Materials 10,Protection of Secondary Lithium Batteries. Journal of thein Rechargeable Lithium Batteries for Overcharge Protection.

  1. Block copolymer electrolytes for lithium batteries

    E-Print Network [OSTI]

    Hudson, William Rodgers

    2011-01-01T23:59:59.000Z

    polymer electrolytes for lithium batteries. Nature 394, 456-facing rechargeable lithium batteries. Nature 414, 359-367 (vanadium oxides for lithium batteries. Journal of Materials

  2. Layer cathode methods of manufacturing and materials for Li-ion rechargeable batteries

    DOE Patents [OSTI]

    Kang, Sun-Ho (Naperville, IL); Amine, Khalil (Downers Grove, IL)

    2008-01-01T23:59:59.000Z

    A positive electrode active material for lithium-ion rechargeable batteries of general formula Li.sub.1+xNi.sub..alpha.Mn.sub..beta.A.sub..gamma.O.sub.2 and further wherein A is Mg, Zn, Al, Co, Ga, B, Zr, or Ti and 0material is manufactured by employing either a solid state reaction method or an aqueous solution method or a sol-gel method which is followed by a rapid quenching from high temperatures into liquid nitrogen or liquid helium.

  3. Mesoporous carbon -Cr2O3 composite as an anode material for lithium ion batteries

    SciTech Connect (OSTI)

    Guo, Bingkun [ORNL; Chi, Miaofang [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

    2012-01-01T23:59:59.000Z

    Mesoporous carbon-Cr2O3 (M-C-Cr2O3) composite was prepared by co-assembly of in-situ formed phenolic resin, chromium precursor, and Pluronic block copolymer under acidic conditions, followed by carbonization at 750oC under Argon. The TEM results confirmed that the Cr2O3 nanoparticles, ranging from 10 to 20 nm, were well dispersed in the matrix of mesoporous carbon. The composite exhibited an initial reversible capacity of 710 mAh g-1 and good cycling stability, which is mainly due to the synergic effects of carbons within the composites, i.e. confining the crystal growth of Cr2O3 during the high temperature treatment step and buffering the volume change of Cr2O3 during the cycling step. This composite material is a promising anode material for lithium ion batteries.

  4. California Lithium Battery, Inc.

    Broader source: Energy.gov [DOE]

    California Lithium Battery (CaLBattery), based in Los Angeles, California, is developing a low-cost, advanced lithium-ion battery that employs a novel silicon graphene composite material that will substantially improve battery cycle life. When combined with other advanced battery materials, it could effectively lower battery life cycle cost by up to 70 percent. Over the next year, CALBattery will be working with Argonne National Laboratory to combine their patented silicon-graphene anode material process together with other advanced ANL cathode and electrolyte battery materials.

  5. Opportunities and challenges for first-principles materials design and applications to Li battery materials

    E-Print Network [OSTI]

    Ceder, Gerbrand

    The idea of first-principles methods is to determine the properties of materials by solving the basic equations of quantum mechanics and statistical mechanics. With such an approach, one can, in principle, predict the ...

  6. Florida Venture Capital Program (Florida)

    Broader source: Energy.gov [DOE]

    The Florida Venture Capital Program provides equity investments and convertible debt instruments to emerging Florida companies and companies locating in Florida with long-term growth potential. ...

  7. Cr-Ga-N materials for negative electrodes in Li rechargeable batteries : structure, synthesis and electrochemical performance

    E-Print Network [OSTI]

    Kim, Miso

    2007-01-01T23:59:59.000Z

    Electrochemical performances of two ternary compounds (Cr2GaN and Cr3GaN) in the Cr-Ga-N system as possible future anode materials for lithium rechargeable batteries were studied. Motivation for this study was dealt in ...

  8. Rate Characteristics of Anatase TiO2 Nanotubes and Nanorods for Lithium Battery Anode Materials at Room

    E-Print Network [OSTI]

    Cho, Jaephil

    ratio.11 Repulsive Coulombic interactions be- tween lithium ions are expected to be responsibleRate Characteristics of Anatase TiO2 Nanotubes and Nanorods for Lithium Battery Anode Materials for lithium content to x = 0.7. Li surface storage on nanometer-sized particles can be energetically more

  9. Electronic transport in Lithium Nickel Manganese Oxide, a high-voltage cathode material for Lithium-Ion batteries

    E-Print Network [OSTI]

    Ransil, Alan Patrick Adams

    2013-01-01T23:59:59.000Z

    Potential routes by which the energy densities of lithium-ion batteries may be improved abound. However, the introduction of Lithium Nickel Manganese Oxide (LixNi1i/2Mn3/2O4, or LNMO) as a positive electrode material appears ...

  10. Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries

    E-Print Network [OSTI]

    Cho, Jaephil

    Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries Hyunjung Lee an increase in the cut-off voltage of the cell from 4.2 V to 4.4 V (vs. graphite). As an alterna- tive, we can

  11. CRADA (AL-C-2009-02) Final Report: Phase I. Lanthanum-based Start Materials for Hydride Batteries

    SciTech Connect (OSTI)

    Gschneidner, Jr., Karl [Ames Laboratory; Schmidt, Frederick [Ames Laboratory] [Ames Laboratory; Frerichs, A.E. [Ames Laboratory] [Ames Laboratory; Ament, Katherine A. [Ames Laboratory] [Ames Laboratory

    2013-05-01T23:59:59.000Z

    The purpose of Phase I of this work is to focus on developing a La-based start material for making nickel-metal (lanthanum)-hydride batteries based on our carbothermic-silicon process. The goal is to develop a protocol for the manufacture of (La{sub 1-x}R{sub x})(Ni{sub 1-y}M{sub y})(Si{sub z}), where R is a rare earth metal and M is a non-rare earth metal, to be utilized as the negative electrode in nickel-metal hydride (NiMH) rechargeable batteries.

  12. LANS Venture Acceleration Fund

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 - -/e),,s - 6157Bioenergy » CPO:missionVenture

  13. West Virginia Venture Capital (West Virginia)

    Broader source: Energy.gov [DOE]

    The West Virginia Venture Capital provides investment funds to eligible businesses stimulating economic growth and providing or retaining jobs within the state through qualified venture capital...

  14. Career Advice Venturing into New

    E-Print Network [OSTI]

    Ferrara, Katherine W.

    , then reduce the capital and energy expenditures of production to keep costs below $80 per barrel. Expecting 80Career Advice Venturing into New Ventures Intent on starting a business, Loleta Robinson (who has at the world, what you'll see is the business of science," predicts Judith Kjelstrom, director

  15. New sealed rechargeable batteries and supercapacitors

    SciTech Connect (OSTI)

    Barnett, B.M. (ed.) (Arthur D. Little, Inc., Cambridge, MA (United States)); Dowgiallo, E. (ed.) (Dept. of Energy, Washington, DC (United States)); Halpert, G. (ed.) (Jet Propulsion Lab., Pasadena, CA (United States)); Matsuda, Y. (ed.) (Yamagushi Univ., Ube (Japan)); Takehara, Z.I. (ed.) (Kyoto Univ. (Japan))

    1993-01-01T23:59:59.000Z

    This conference was divided into the following sections: supercapacitors; nickel-metal hydride batteries; lithium polymer batteries; lithium/carbon batteries; cathode materials; and lithium batteries. Separate abstracts were prepared for the 46 papers of this conference.

  16. Search for new manganese-cobalt oxides as positive electrode materials for lithium batteries P. Strobel, J. Tillier, A. Diaz, A. Ibarra-Palos, F. Thiry and J.B. Soupart *

    E-Print Network [OSTI]

    Boyer, Edmond

    positive electrode material for lithium batteries ; last but not least, copper or cobalt substitutionSearch for new manganese-cobalt oxides as positive electrode materials for lithium batteries P new mixed manganese-cobalt oxides for lithium battery positive electrode materials were obtained using

  17. Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques

    E-Print Network [OSTI]

    Doeff, Marca M.

    2013-01-01T23:59:59.000Z

    Graphite and LiCoO 2 are the most commonly employed negative and positive electrodes, respectively, for lithium ion batteries.

  18. Mechanical characterization of lithium-ion battery micro components for development of homogenized and multilayer material models

    E-Print Network [OSTI]

    Miller, Kyle M. (Kyle Mark)

    2014-01-01T23:59:59.000Z

    The overall battery research of the Impact and Crashworthiness Laboratory (ICL) at MIT has been focused on understanding the battery's mechanical properties so that individual battery cells and battery packs can be ...

  19. Nano-structured anode material for high-power battery system in electric vehicles.

    SciTech Connect (OSTI)

    Amine, K.; Belharouak, I.; Chen, Z.; Taison, T.; Yumoto, H.; Ota, N.; Myung, S.-T.; Sun, Y.-K. (Chemical Sciences and Engineering Division); (Enerdel Lithium Power Systems); (Iwate Univ.); (Hanyang Univ.)

    2010-07-27T23:59:59.000Z

    A new MSNP-LTO anode is developed to enable a high-power battery system that provides three times more power than any existing battery system. It shows excellent cycle life and low-temperature performance, and exhibits unmatched safety characteristics.

  20. Battery cell feedthrough apparatus

    DOE Patents [OSTI]

    Kaun, T.D.

    1995-03-14T23:59:59.000Z

    A compact, hermetic feedthrough apparatus is described comprising interfitting sleeve portions constructed of chemically-stable materials to permit unique battery designs and increase battery life and performance. 8 figs.

  1. STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES

    SciTech Connect (OSTI)

    Wilcox, James D.

    2008-12-18T23:59:59.000Z

    The development of advanced lithium-ion batteries is key to the success of many technologies, and in particular, hybrid electric vehicles. In addition to finding materials with higher energy and power densities, improvements in other factors such as cost, toxicity, lifetime, and safety are also required. Lithium transition metal oxide and LiFePO{sub 4}/C composite materials offer several distinct advantages in achieving many of these goals and are the focus of this report. Two series of layered lithium transition metal oxides, namely LiNi{sub 1/3}Co{sub 1/3-y}M{sub y}Mn{sub 1/3}O{sub 2} (M=Al, Co, Fe, Ti) and LiNi{sub 0.4}Co{sub 0.2-y}M{sub y}Mn{sub 0.4}O{sub 2} (M = Al, Co, Fe), have been synthesized. The effect of substitution on the crystal structure is related to shifts in transport properties and ultimately to the electrochemical performance. Partial aluminum substitution creates a high-rate positive electrode material capable of delivering twice the discharge capacity of unsubstituted materials. Iron substituted materials suffer from limited electrochemical performance and poor cycling stability due to the degradation of the layered structure. Titanium substitution creates a very high rate positive electrode material due to a decrease in the anti-site defect concentration. LiFePO{sub 4} is a very promising electrode material but suffers from poor electronic and ionic conductivity. To overcome this, two new techniques have been developed to synthesize high performance LiFePO{sub 4}/C composite materials. The use of graphitization catalysts in conjunction with pyromellitic acid leads to a highly graphitic carbon coating on the surface of LiFePO{sub 4} particles. Under the proper conditions, the room temperature electronic conductivity can be improved by nearly five orders of magnitude over untreated materials. Using Raman spectroscopy, the improvement in conductivity and rate performance of such materials has been related to the underlying structure of the carbon films. The combustion synthesis of LiFePO4 materials allows for the formation of nanoscale active material particles with high-quality carbon coatings in a quick and inexpensive fashion. The carbon coating is formed during the initial combustion process at temperatures that exceed the thermal stability limit of LiFePO{sub 4}. The olivine structure is then formed after a brief calcination at lower temperatures in a controlled environment. The carbon coating produced in this manner has an improved graphitic character and results in superior electrochemical performance. The potential co-synthesis of conductive carbon entities, such as carbon nanotubes and fibers, is also briefly discussed.

  2. Black Conductive Titanium Oxide High-Capacity Materials for Battery Electrodes

    SciTech Connect (OSTI)

    Han, W.

    2011-05-18T23:59:59.000Z

    Stoichiometric titanium dioxide (TiO{sub 2}) is one of the most widely studied transitionmetal oxides because of its many potential applications in photoelectrochemical systems, such as dye-sensitized TiO{sub 2} electrodes for photovoltaic solar cells, and water-splitting catalysts for hydrogen generation, and in environmental purification for creating or degrading specific compounds. However, TiO{sub 2} has a wide bandgap and high electrical resistivity, which limits its use as an electrode. A set of non-stoichiometric titanium oxides called the Magneli phases, having a general formula of Ti{sub n}O{sub 2n-1} with n between 4 and 10, exhibits lower bandgaps and resistivities, with the highest electrical conductivities reported for Ti{sub 4}O{sub 7}. These phases have been formulated under different conditions, but in all reported cases the resulting oxides have minimum grain sizes on the order of micrometers, regardless of the size of the starting titanium compounds. In this method, nanoparticles of TiO{sub 2} or hydrogen titanates are first coated with carbon using either wet or dry chemistry methods. During this process the size and shape of the nanoparticles are 'locked in.' Subsequently the carbon-coated nanoparticles are heated. This results in the transformation of the original TiO{sub 2} or hydrogen titanates to Magneli phases without coarsening, so that the original size and shape of the nanoparticles are maintained to a precise degree. People who work on batteries, fuel cells, ultracapacitors, electrosynthesis cells, electro-chemical devices, and soil remediation have applications that could benefit from using nanoscale Magneli phases of titanium oxide. Application of these electrode materials may not be limited to substitution for TiO{sub 2} electrodes. Combining the robustness and photosensitivity of TiO{sub 2} with higher electrical conductivity may result in a general electrode material.

  3. Structural Underpinnings of the Enhanced Cycling Stability upon Al-Substitution in LiNi0.45Mn0.45Co0.1-yAlyO2 Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas E.

    2013-01-01T23:59:59.000Z

    materials for Li-ion batteries Thomas E. Conry, a,b Apurvamaterials in Li-ion batteries. Synchrotron-based high-materials for Li-ion batteries. LiNi z Mn z Co 1-2z O 2 (NMC

  4. Venture Capital Program (North Dakota)

    Broader source: Energy.gov [DOE]

    The Venture Capital Program, provided by the ND Department of Commerce, is an innovative financial program that provides flexible financing through debt and equity investments for new or expanding...

  5. Economic assessment of candidate materials for key components in a grid-scale liquid metal battery

    E-Print Network [OSTI]

    Parent, Michael C. (Michael Calvin)

    2011-01-01T23:59:59.000Z

    In order to satisfy the growing demand for renewable resources as a supply of electricity, much effort is being placed toward the development of battery energy storage systems that can effectively interface these new sources ...

  6. Developing Next-Gen Batteries With Help From NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NERSC Helps Develop Next-Gen Batteries NERSC Helps Develop Next-Gen Batteries A genomics approach to materials research could speed up advancements in battery performance December...

  7. Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries

    E-Print Network [OSTI]

    Zhu, Jianxin

    2014-01-01T23:59:59.000Z

    0 lithium batteries. J. Electrochem. Soc.for rechargeable lithium batteries. Advanced Materials 1998,for rechargeable lithium batteries. J. Electrochem. Soc.

  8. Electrochemical properties of lithium polymer batteries with doped polyaniline as cathode material

    SciTech Connect (OSTI)

    Manuel, James [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 660-701 (Korea, Republic of)] [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 660-701 (Korea, Republic of); Kim, Jae-Kwang; Matic, Aleksandar; Jacobsson, Per [Department of Applied Physics, Chalmers University of Technology, SE-41296 Göteborg (Sweden)] [Department of Applied Physics, Chalmers University of Technology, SE-41296 Göteborg (Sweden); Chauhan, Ghanshyam S. [Department of Chemistry, Himachal Pradesh University, Shimla 171005 (India)] [Department of Chemistry, Himachal Pradesh University, Shimla 171005 (India); Ha, Jong Keun; Cho, Kwon-Koo [Department of Materials Science and Engineering, Gyeongsang National University, 900, Gajwa-dong, Jinju 660-701 (Korea, Republic of)] [Department of Materials Science and Engineering, Gyeongsang National University, 900, Gajwa-dong, Jinju 660-701 (Korea, Republic of); Ahn, Jou-Hyeon, E-mail: jhahn@gnu.ac.kr [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 660-701 (Korea, Republic of)] [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 660-701 (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    Graphical abstract: -- Abstract: Polyaniline (PANI) was doped with different lithium salts such as LiPF{sub 6} and LiClO{sub 4} and evaluated as cathode-active material for application in room-temperature lithium batteries. The doped PANI was characterized by FTIR and XPS measurements. In the FTIR spectra, the characteristic peaks of PANI are shifted to lower bands as a consequence of doping, and it is more shifted in the case of PANI doped with LiPF{sub 6}. The cathodes prepared using PANI doped with LiPF{sub 6} and LiClO{sub 4} delivered initial discharge capacities of 125 mAh g{sup ?1} and 112 mAh g{sup ?1} and stable reversible capacities of 114 mAh g{sup ?1} and 81 mAh g{sup ?1}, respectively, after 10 charge–discharge cycles. The cells were also tested using polymer electrolyte, which delivered highest discharge capacities of 142.6 mAh g{sup ?1} and 140 mAh g{sup ?1} and stable reversible capacities of 117 mAh g{sup ?1} and 122 mAh g{sup ?1} for PANI-LiPF{sub 6} and PANI-LiClO{sub 4}, respectively, after 10 cycles. The cathode prepared with LiPF{sub 6} doped PANI shows better cycling performance and stability as compared to the cathode prepared with LiClO{sub 4} doped PANI using both liquid and polymer electrolytes.

  9. Novel Laser-Based Manufacturing of nano-LiFePO4-Based Materials for High Power Li Ion Batteries

    E-Print Network [OSTI]

    Horne, Craig R.; Jaiswal, Abhishek; Chang, On; Crane, S.; Doeff, Marca M.; Wang, Emile

    2006-01-01T23:59:59.000Z

    II “Olivines in Lithium Batteries” The Beckman Institute,for High Power Li Ion Batteries C.R. Horne 1 , A. Jaiswal

  10. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Ya [Brookhaven National Lab. (BNL), Upton, NY (United States); Yu, Xiqian [Brookhaven National Lab. (BNL), Upton, NY (United States); You, Ya [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Chemistry; Yin, Yaxia [Brookhaven National Lab. (BNL), Upton, NY (United States); Nam, Kyung -Wan [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01T23:59:59.000Z

    Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmosphere during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. The Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.

  11. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Ya; Yu, Xiqian; You, Ya; Yin, Yaxia; Nam, Kyung -Wan

    2015-01-01T23:59:59.000Z

    Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmospheremore »during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. The Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.« less

  12. An Introduction to Venture Capital Granite representatives

    E-Print Network [OSTI]

    Anderson, Richard

    May 2006 An Introduction to Venture Capital #12;2 Granite representatives Sam Kingsland ­ Managing;3 Introduction to Granite Ventures Founded in 1992 Granite has 9 investment professionals Over $1B under

  13. Layered manganese oxide intergrowth electrodes for rechargeable lithium batteries: Part 1-substitution with Co or Ni

    E-Print Network [OSTI]

    Dolle, Mickael; Patoux, Sebastien; Doeff, Marca M.

    2004-01-01T23:59:59.000Z

    Cathode Materials for Lithium Batteries, 2003, Massachusettsfor Rechargeable Lithium Batteries: Part 1-Substitution withelectrode materials for lithium batteries because of their

  14. Batteries and Energy Storage | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPOTLIGHT Batteries and Energy Storage Argonne's all- encompassing battery research program spans the continuum from basic materials research and diagnostics to scale-up processes...

  15. Develop high energy high power Li-ion battery cathode materials : a first principles computational study

    E-Print Network [OSTI]

    Xu, Bo; Xu, Bo

    2012-01-01T23:59:59.000Z

    Simulation in Materials Science and Engineering, 2000. 8(3):Dept. of Materials Science and Engineering. , Designing newDept. of Materials Science and Engineering. , First

  16. Graphdiyne as a high-capacity lithium ion battery anode material

    SciTech Connect (OSTI)

    Jang, Byungryul; Koo, Jahyun; Park, Minwoo; Kwon, Yongkyung; Lee, Hoonkyung, E-mail: hkiee3@konkuk.ac.kr [School of Physics, Konkuk University, Seoul 143-701 (Korea, Republic of)] [School of Physics, Konkuk University, Seoul 143-701 (Korea, Republic of); Lee, Hosik [School of Mechanical and Advanced Materials Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798 (Korea, Republic of)] [School of Mechanical and Advanced Materials Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 689-798 (Korea, Republic of); Nam, Jaewook [School of Chemical Engineering, Sungkyunkwan University, Suwon 300 (Korea, Republic of)] [School of Chemical Engineering, Sungkyunkwan University, Suwon 300 (Korea, Republic of)

    2013-12-23T23:59:59.000Z

    Using the first-principles calculations, we explored the feasibility of using graphdiyne, a 2D layer of sp and sp{sup 2} hybrid carbon networks, as lithium ion battery anodes. We found that the composite of the Li-intercalated multilayer ?-graphdiyne was C{sub 6}Li{sub 7.31} and that the calculated voltage was suitable for the anode. The practical specific/volumetric capacities can reach up to 2719?mAh?g{sup ?1}/2032?mAh?cm{sup ?3}, much greater than the values of ?372?mAh?g{sup ?1}/?818?mAh?cm{sup ?3}, ?1117?mAh?g{sup ?1}/?1589?mAh?cm{sup ?3}, and ?744?mAh?g{sup ?1} for graphite, graphynes, and ?-graphdiyne, respectively. Our calculations suggest that multilayer ?-graphdiyne can serve as a promising high-capacity lithium ion battery anode.

  17. In-situ Spectroscopic and Structural Studies of Electrode Materials for Advanced Battery Applications

    SciTech Connect (OSTI)

    Daniel A Scherson

    2013-03-14T23:59:59.000Z

    Techniques have been developed and implemented to gain insight into fundamental factors that affect the performance of electrodes in Li and Li-ion batteries and other energy storage devices. These include experimental strategies for monitoring the Raman scattering spectra of single microparticles of carbon and transition metal oxides as a function of their state of charge. Measurements were performed in electrolytes of direct relevance to Li and Li-Ion batteries both in the static and dynamic modes. In addition, novel strategies were devised for performing conventional experiments in ultrahigh vacuum environments under conditions which eliminate effects associated with presence of impurities, using ultrapure electrolytes, both of the polymeric and ionic liquid type that display no measurable vapor pressure. Also examined was the reactivity of conventional non aqueous solvent toward ultrapure Li films as monitored in ultrahigh vacuum with external reflection Fourier transform infrared spectroscopy. Also pursued were efforts toward developing applying Raman-scattering for monitoring the flow of charge of a real Li ion battery. Such time-resolved, spatially-resolved measurements are key to validating the results of theoretical simulations involving real electrode structures.

  18. Transmission electron microscopy (TEM) investigations of Mn-oxide rich cathodic material from spent disposable alkaline batteries

    SciTech Connect (OSTI)

    Krekeler, Mark P.S. [Department of Environmental Science and Policy, George Mason University, Fairfax, VA 22030 (United States)], E-mail: mark.krekeler@gmail.com

    2008-11-15T23:59:59.000Z

    Transmission electron microscopy (TEM) techniques were used to investigate the spent cathodic material of a single common brand of disposable alkaline batteries. Mn-oxide particles are anhedral and irregular in shape and compose an estimated 99-95% of the <10 {mu}m size fraction of sample material. Diameters of particles vary widely and typically are between 50 nm and 3 {mu}m; however, most particles are approximately 200-400 nm in diameter. Chemical composition varies for Mn-oxide particles with concentrations being SiO{sub 2} (0.00-1.52 wt%), TiO{sub 2} (0.49-4.58 wt%), MnO (65.85-92.06 wt%), ZnO (1.00-7.53 wt%), K{sub 2}O (4.97-20.48 wt%) and SO{sub 3} (0.43-2.21 wt%). Discrete prismatic zinc crystals occur and vary from a maximum of approximately 0.8 {mu}m long x 0.15 {mu}m wide, to 100 nm long x 20 nm wide. Titanium metal was also observed in samples and composes approximately 0.25-1.0% of the <10 {mu}m size fraction of sample material. Results of this study suggest that battery components may be recycled in some special applications. Examples are low energy-low material requirement products such as paint pigments and Zn nanoparticles. This investigation provides detailed constraints on the nature of spent cathodic materials to improve existing recycling methods and develop new technologies.

  19. AH 18/02/2011 Page 1 of 12 Tech Venture Creation Programme 2011

    E-Print Network [OSTI]

    Humphrys, Mark

    : applicable to new venture creation Legal structures Liability Negligence, Duty of Care Statutory Regulation is Selling? Selling Technology Products Managing your Sales Pipeline Case Material/Practical Exercises: TBC

  20. Development of Low Cost Carbonaceous Materials for Anodes in Lithium-Ion Batteries for Electric and Hybrid Electric Vehicles

    SciTech Connect (OSTI)

    Barsukov, Igor V.

    2002-12-10T23:59:59.000Z

    Final report on the US DOE CARAT program describes innovative R & D conducted by Superior Graphite Co., Chicago, IL, USA in cooperation with researchers from the Illinois Institute of Technology, and defines the proper type of carbon and a cost effective method for its production, as well as establishes a US based manufacturer for the application of anodes of the Lithium-Ion, Lithium polymer batteries of the Hybrid Electric and Pure Electric Vehicles. The three materials each representing a separate class of graphitic carbon, have been developed and released for field trials. They include natural purified flake graphite, purified vein graphite and a graphitized synthetic carbon. Screening of the available on the market materials, which will help fully utilize the graphite, has been carried out.

  1. Batteries: Overview of Battery Cathodes

    E-Print Network [OSTI]

    Doeff, Marca M

    2011-01-01T23:59:59.000Z

    M=Mn, Ni, Co) in Lithium Batteries at 50°C. Electrochem.Electrodes for Lithium Batteries. J. Am. Ceram. Soc. 82:S CIENCE AND T ECHNOLOGY Batteries: Overview of Battery

  2. Batteries: Overview of Battery Cathodes

    SciTech Connect (OSTI)

    Doeff, Marca M

    2010-07-12T23:59:59.000Z

    The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and electric vehicles (EVs); a market predicted to be potentially ten times greater than that of consumer electronics. In fact, only Liion batteries can meet the requirements for PHEVs as set by the U.S. Advanced Battery Consortium (USABC), although they still fall slightly short of EV goals. In the case of Li-ion batteries, the trade-off between power and energy shown in Figure 1 is a function both of device design and the electrode materials that are used. Thus, a high power battery (e.g., one intended for an HEV) will not necessarily contain the same electrode materials as one designed for high energy (i.e., for an EV). As is shown in Figure 1, power translates into acceleration, and energy into range, or miles traveled, for vehicular uses. Furthermore, performance, cost, and abuse-tolerance requirements for traction batteries differ considerably from those for consumer electronics batteries. Vehicular applications are particularly sensitive to cost; currently, Li-ion batteries are priced at about $1000/kWh, whereas the USABC goal is $150/kWh. The three most expensive components of a Li-ion battery, no matter what the configuration, are the cathode, the separator, and the electrolyte. Reduction of cost has been one of the primary driving forces for the investigation of new cathode materials to replace expensive LiCoO{sub 2}, particularly for vehicular applications. Another extremely important factor is safety under abuse conditions such as overcharge. This is particularly relevant for the large battery packs intended for vehicular uses, which are designed with multiple cells wired in series arrays. Premature failure of one cell in a string may cause others to go into overcharge during passage of current. These considerations have led to the development of several different types of cathode materials, as will be covered in the next section. Because there is not yet one ideal material that can meet requirements for all applications, research into cathodes for Li-ion batteries is, as of this writ

  3. Organic salts as super-high rate capability materials for lithium-ion batteries Y. Y. Zhang, Y. Y. Sun, S. X. Du, H.-J. Gao, and S. B. Zhang

    E-Print Network [OSTI]

    Gao, Hongjun

    Organic salts as super-high rate capability materials for lithium-ion batteries Y. Y. Zhang, Y. Y of electrode nanomaterials in lithium-ion battery: The effects of surface stress J. Appl. Phys. 112, 103507://apl.aip.org/about/rights_and_permissions #12;Organic salts as super-high rate capability materials for lithium-ion batteries Y. Y. Zhang,1,2 Y

  4. Mechanical design of flow batteries

    E-Print Network [OSTI]

    Hopkins, Brandon J. (Brandon James)

    2013-01-01T23:59:59.000Z

    The purpose of this research is to investigate the design of low-cost, high-efficiency flow batteries. Researchers are searching for next-generation battery materials, and this thesis presents a systems analysis encompassing ...

  5. Three-dimensional graphene/LiFePO{sub 4} nanostructures as cathode materials for flexible lithium-ion batteries

    SciTech Connect (OSTI)

    Ding, Y.H., E-mail: yhding@xtu.edu.cn [College of Chemical Engineering, Xiangtan University, Hunan 411105 (China); Institute of Rheology Mechanics, Xiangtan University, Hunan 411105 (China); Ren, H.M. [Institute of Rheology Mechanics, Xiangtan University, Hunan 411105 (China); Huang, Y.Y. [BTR New Energy Materials Inc., Shenzhen 518000 (China); Chang, F.H.; Zhang, P. [Institute of Rheology Mechanics, Xiangtan University, Hunan 411105 (China)

    2013-10-15T23:59:59.000Z

    Graphical abstract: Graphene/LiFePO{sub 4} composites as a high-performance cathode material for flexible lithium-ion batteries have been prepared by using a co-precipitation method to synthesize graphene/LiFePO4 powders as precursors and then followed by a solvent evaporation process. - Highlights: • Flexible LiFePO{sub 4}/graphene films were prepared first time by a solvent evaporation process. • The flexible electrode exhibited a high discharge capacity without conductive additives. • Graphene network offers the electrode adequate strength to withstand repeated flexing. - Abstract: Three-dimensional graphene/LiFePO{sub 4} nanostructures for flexible lithium-ion batteries were successfully prepared by solvent evaporation method. Structural characteristics of flexible electrodes were investigated by X-ray diffraction (XRD), atomic force microscopy (AFM) and scanning electron microscopy (SEM). Electrochemical performance of graphene/LiFePO{sub 4} was examined by a variety of electrochemical testing techniques. The graphene/LiFePO{sub 4} nanostructures showed high electrochemical properties and significant flexibility. The composites with low graphene content exhibited a high capacity of 163.7 mAh g{sup ?1} at 0.1 C and 114 mAh g{sup ?1} at 5 C without further incorporation of conductive agents.

  6. Factors Affecting the Battery Performance of Anthraquinone-based...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Affecting the Battery Performance of Anthraquinone-based Organic Cathode Materials. Factors Affecting the Battery Performance of Anthraquinone-based Organic Cathode Materials....

  7. Overview of the Batteries for Advanced Transportation Technologies...

    Broader source: Energy.gov (indexed) [DOE]

    Material BATT and the Battery Industry Block copolymer electrolytes for Li-metal batteries (Balsara) being commercialized by Seeo, Inc. Advanced cathode materials (Manthiram)...

  8. Battery utilizing ceramic membranes

    DOE Patents [OSTI]

    Yahnke, Mark S. (Berkeley, CA); Shlomo, Golan (Haifa, IL); Anderson, Marc A. (Madison, WI)

    1994-01-01T23:59:59.000Z

    A thin film battery is disclosed based on the use of ceramic membrane technology. The battery includes a pair of conductive collectors on which the materials for the anode and the cathode may be spin coated. The separator is formed of a porous metal oxide ceramic membrane impregnated with electrolyte so that electrical separation is maintained while ion mobility is also maintained. The entire battery can be made less than 10 microns thick while generating a potential in the 1 volt range.

  9. In search of high performance anode materials for Mg batteries: computational studies of Mg in Ge, Si, and Sn

    E-Print Network [OSTI]

    Malyi, Oleksandr I; Manzhos, Sergei; 10.1016/j.jpowsour.2013.01.114

    2013-01-01T23:59:59.000Z

    We present ab initio studies of structures, energetics, and diffusion properties of Mg in Si, Ge, and Sn diamond structures to evaluate their potential as insertion type anode materials for Mg batteries. We show that Si could provide the highest specific capacities (3817 mAh g-1) and the lowest average insertion voltage (~0.15 eV vs. Mg) for Mg storage. Nevertheless, due to its significant percent lattice expansion (~216%) and slow Mg diffusion, Sn and Ge are more attractive; both anodes have lower lattice expansions (~120 % and ~178 %, respectively) and diffusion barriers (~0.50 and ~0.70 eV, respectively for single-Mg diffusion) than Si. We show that Mg-Mg interactions at different stages of charging can decrease significantly the diffusion barrier compared to the single atom diffusion, by up to 0.55 eV.

  10. Nb{sub 2}O{sub 5} hollow nanospheres as anode material for enhanced performance in lithium ion batteries

    SciTech Connect (OSTI)

    Sasidharan, Manickam [Department of Chemistry, Faculty of Science and Engineering, Saga University, 1 Honjo-machi, Saga 840-8502 (Japan)] [Department of Chemistry, Faculty of Science and Engineering, Saga University, 1 Honjo-machi, Saga 840-8502 (Japan); Gunawardhana, Nanda [Advanced Research Center, Saga University, 1341 Yoga-machi, Saga 840-0047 (Japan)] [Advanced Research Center, Saga University, 1341 Yoga-machi, Saga 840-0047 (Japan); Yoshio, Masaki, E-mail: yoshio@cc.saga-u.ac.jp [Advanced Research Center, Saga University, 1341 Yoga-machi, Saga 840-0047 (Japan)] [Advanced Research Center, Saga University, 1341 Yoga-machi, Saga 840-0047 (Japan); Nakashima, Kenichi, E-mail: nakashik@cc.saga-u.ac.jp [Department of Chemistry, Faculty of Science and Engineering, Saga University, 1 Honjo-machi, Saga 840-8502 (Japan)] [Department of Chemistry, Faculty of Science and Engineering, Saga University, 1 Honjo-machi, Saga 840-8502 (Japan)

    2012-09-15T23:59:59.000Z

    Graphical abstract: Nb{sub 2}O{sub 5} hollow nanosphere constructed electrode delivers high capacity of 172 mAh g{sup ?1} after 250 cycles and maintains structural integrity and excellent cycling stability. Highlights: ? Nb{sub 2}O{sub 5} hollow nanospheres synthesis was synthesized by soft-template. ? Nb{sub 2}O{sub 5} hollow nanospheres were investigated as anode material in Li-ion battery. ? Nanostructured electrode delivers high capacity of 172 mAh g{sup ?1} after 250 cycles. ? The electrode maintains the structural integrity and excellent cycling stability. ? Nanosized shell domain facilitates fast lithium intercalation/deintercalation. -- Abstract: Nb{sub 2}O{sub 5} hollow nanospheres of average diameter ca. ?29 nm and hollow cavity size ca. 17 nm were synthesized using polymeric micelles with core–shell–corona architecture under mild conditions. The hollow particles were thoroughly characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), infrared spectroscopy (FTIR), thermal (TG/DTA) and nitrogen adsorption analyses. Thus obtained Nb{sub 2}O{sub 5} hollow nanospheres were investigated as anode materials for lithium ion rechargeable batteries for the first time. The nanostructured electrode delivers high capacity of 172 mAh g{sup ?1} after 250 cycles of charge/discharge at a rate of 0.5 C. More importantly, the hollow particles based electrodes maintains the structural integrity and excellent cycling stability even after exposing to high current density 6.25 A g{sup ?1}. The enhanced electrochemical behavior is ascribed to hollow cavity coupled with nanosized Nb{sub 2}O{sub 5} shell domain that facilitates fast lithium intercalation/deintercalation kinetics.

  11. Venture Capital Institutions and Venture Capitalists’ Investment Activities: An Empirical Study on China 

    E-Print Network [OSTI]

    Guo, Di

    2010-01-01T23:59:59.000Z

    This thesis explores institutions under which venture capital investment operates in China and whether and how these institutions affect venture capitalists’ (VCs) investment preferences, ex-ante project screening ...

  12. STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES

    E-Print Network [OSTI]

    Wilcox, James D.

    2010-01-01T23:59:59.000Z

    material prepared by molten- salt synthesis. Journal ofthe sodium for lithium in a molten salt. 13 The large ionic

  13. Tuning charge–discharge induced unit cell breathing in layer-structured cathode materials for lithium-ion batteries

    SciTech Connect (OSTI)

    Zhou, Yong-Ning [Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry; Ma, Jun [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Hu, Enyuan [Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry; Yu, Xiqian [Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry; Gu, Lin [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Nam, Kyung -Wan [Dongguk Univ., Seoul (Korea, Republic of); Chen, Liquan [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Wang, Zhaoxiang [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Yang, Xiao -Qing [Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry

    2014-11-18T23:59:59.000Z

    Through a systematic study of lithium molybdenum trioxide (Li2MoO3), a new ‘unit cell breathing’ mechanism is introduced based on both crystal and electronic structural changes of transition metal oxide cathode materials during charge–discharge: For widely used LiMO2 (M = Co, Ni, Mn), lattice parameters, a and b, contracts during charge. However, for Li2MoO3, such changes are in opposite directions. Metal–metal bonding is used to explain such ‘abnormal’ behaviour and a generalized hypothesis is developed. The expansion of M–M bond becomes the controlling factor for a(b) evolution during charge, in contrast to the shrinking M–O as controlling factor in ‘normal’ materials. The cation mixing caused by migration of Mo ions at higher oxidation state provides the benefits of reducing the c expansion range in early stage of charging and suppressing the structure collapse at high voltage charge. These results open a new strategy for designing and engineering layered cathode materials for high energy density lithium-ion batteries.

  14. Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries

    DOE Patents [OSTI]

    Deng, Haixia; Belharouak, Ilias; Amine, Khalil

    2012-10-02T23:59:59.000Z

    Nano-sized structured dense and spherical layered positive active materials provide high energy density and high rate capability electrodes in lithium-ion batteries. Such materials are spherical second particles made from agglomerated primary particles that are Li.sub.1+.alpha.(Ni.sub.xCo.sub.yMn.sub.z).sub.1-tM.sub.tO.sub.2-dR.sub.d- , where M is selected from can be Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, Zr, or a mixture of any two or more thereof, R is selected from F, Cl, Br, I, H, S, N, or a mixture of any two or more thereof, and 0.ltoreq..alpha..ltoreq.0.50; 0materials and their use in electrochemical devices are also described.

  15. Tuning charge–discharge induced unit cell breathing in layer-structured cathode materials for lithium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Yong-Ning [Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry; Ma, Jun [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Hu, Enyuan [Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry; Yu, Xiqian [Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry; Gu, Lin [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Nam, Kyung -Wan [Dongguk Univ., Seoul (Korea, Republic of); Chen, Liquan [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Wang, Zhaoxiang [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Yang, Xiao -Qing [Brookhaven National Lab. (BNL), Upton, NY (United States). Dept. of Chemistry

    2014-11-18T23:59:59.000Z

    Through a systematic study of lithium molybdenum trioxide (Li2MoO3), a new ‘unit cell breathing’ mechanism is introduced based on both crystal and electronic structural changes of transition metal oxide cathode materials during charge–discharge: For widely used LiMO2 (M = Co, Ni, Mn), lattice parameters, a and b, contracts during charge. However, for Li2MoO3, such changes are in opposite directions. Metal–metal bonding is used to explain such ‘abnormal’ behaviour and a generalized hypothesis is developed. The expansion of M–M bond becomes the controlling factor for a(b) evolution during charge, in contrast to the shrinking M–O as controlling factor in ‘normal’ materials. The cation mixing caused by migration of Mo ions at higher oxidation state provides the benefits of reducing the c expansion range in early stage of charging and suppressing the structure collapse at high voltage charge. These results open a new strategy for designing and engineering layered cathode materials for high energy density lithium-ion batteries.

  16. Tuning charge–discharge induced unit cell breathing in layer-structured cathode materials for lithium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Yong-Ning; Ma, Jun; Hu, Enyuan; Yu, Xiqian; Gu, Lin; Nam, Kyung -Wan; Chen, Liquan; Wang, Zhaoxiang; Yang, Xiao -Qing

    2014-11-18T23:59:59.000Z

    Through a systematic study of lithium molybdenum trioxide (Li2MoO3), a new ‘unit cell breathing’ mechanism is introduced based on both crystal and electronic structural changes of transition metal oxide cathode materials during charge–discharge: For widely used LiMO2 (M = Co, Ni, Mn), lattice parameters, a and b, contracts during charge. However, for Li2MoO3, such changes are in opposite directions. Metal–metal bonding is used to explain such ‘abnormal’ behaviour and a generalized hypothesis is developed. The expansion of M–M bond becomes the controlling factor for a(b) evolution during charge, in contrast to the shrinking M–O as controlling factor in ‘normal’ materials.more »The cation mixing caused by migration of Mo ions at higher oxidation state provides the benefits of reducing the c expansion range in early stage of charging and suppressing the structure collapse at high voltage charge. These results open a new strategy for designing and engineering layered cathode materials for high energy density lithium-ion batteries.« less

  17. Flexographically Printed Rechargeable Zinc-based Battery for Grid Energy Storage

    E-Print Network [OSTI]

    Wang, Zuoqian

    2013-01-01T23:59:59.000Z

    Performance for Lithium Batteries,” J. Electrochem. Soc. ,developments in lithium ion batteries,” Materials Sciencefor advanced lithium-ion batteries,” Journal of Power

  18. Advanced Battery Manufacturing (VA)

    SciTech Connect (OSTI)

    Stratton, Jeremy

    2012-09-30T23:59:59.000Z

    LiFeBATT has concentrated its recent testing and evaluation on the safety of its batteries. There appears to be a good margin of safety with respect to overheating of the cells and the cases being utilized for the batteries are specifically designed to dissipate any heat built up during charging. This aspect of LiFeBATT’s products will be even more fully investigated, and assuming ongoing positive results, it will become a major component of marketing efforts for the batteries. LiFeBATT has continued to receive prismatic 20 Amp hour cells from Taiwan. Further testing continues to indicate significant advantages over the previously available 15 Ah cells. Battery packs are being assembled with battery management systems in the Danville facility. Comprehensive tests are underway at Sandia National Laboratory to provide further documentation of the advantages of these 20 Ah cells. The company is pursuing its work with Hybrid Vehicles of Danville to critically evaluate the 20 Ah cells in a hybrid, armored vehicle being developed for military and security applications. Results have been even more encouraging than they were initially. LiFeBATT is expanding its work with several OEM customers to build a worldwide distribution network. These customers include a major automotive consulting group in the U.K., an Australian maker of luxury off-road campers, and a number of makers of E-bikes and scooters. LiFeBATT continues to explore the possibility of working with nations that are woefully short of infrastructure. Negotiations are underway with Siemens to jointly develop a system for using photovoltaic generation and battery storage to supply electricity to communities that are not currently served adequately. The IDA has continued to monitor the progress of LiFeBATT’s work to ensure that all funds are being expended wisely and that matching funds will be generated as promised. The company has also remained current on all obligations for repayment of an IDA loan and lease payments for space to the IDA. A commercial venture is being formed to utilize the LiFeBATT product for consumer use in enabling photovoltaic powered boat lifts. Field tests of the system have proven to be very effective and commercially promising. This venture is expected to result in significant sales within the next six months.

  19. Battery system

    DOE Patents [OSTI]

    Dougherty, Thomas J; Wood, Steven J; Trester, Dale B; Andrew, Michael G

    2013-08-27T23:59:59.000Z

    A battery module includes a plurality of battery cells and a system configured for passing a fluid past at least a portion of the plurality of battery cells in a parallel manner.

  20. Factors influencing the discharge characteristics of Na0.44MnO2-based positive electrode materials for rechargeable lithium batteries

    E-Print Network [OSTI]

    Doeff, M.M.

    2011-01-01T23:59:59.000Z

    for Rechargeable Lithium Batteries Marca M. Doeff, Kwang-For Rechargeable Lithium Batteries Marca M. Doefr*, Kwang-FOR RECHARGEABLE LITHIUM BATTERIES Marca M. Doeff * , Kwang-

  1. Food Battery Competition Sponsored by

    E-Print Network [OSTI]

    Tennessee, University of

    and outstanding lithium-ion batteries, you can recognize the progress. Lithium provides good voltages and powerFood Battery Competition Sponsored by: The University of Tennessee, Materials Advantage (MA not have enough natural resources to support our growing populations and energy needs forever. Batteries

  2. MRI Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer Plant Jump to:LandownersLuther, Oklahoma:EnergyECO Auger <SmarTurbineMIT-MRI Ventures

  3. Hydrogen Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEIHesperia, California:ProjectPrograms | OpenVentures Jump to:

  4. Palomar Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri:EnergyOssian, NewPalisades Park, NewPalomar Ventures Jump to:

  5. Artiman Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: Energy ResourcesInformation Arizona'sin DevelopingArtiman Ventures

  6. Independent Directors and Board Control in Venture Finance

    E-Print Network [OSTI]

    Broughman, Brian

    2008-01-01T23:59:59.000Z

    of venture capital finance. Journal of Law, Economics, andventures. Journal of Finance 60, 2513-2549. Dewatripont,venture capital. Journal of Finance 50, Grossman, S. , Hart,

  7. Batteries: Overview of Battery Cathodes

    E-Print Network [OSTI]

    Doeff, Marca M

    2011-01-01T23:59:59.000Z

    M=Mn, Ni, Co) in Lithium Batteries at 50°C. Electrochem.Spinel Electrodes for Lithium Batteries. J. Am. Ceram. Soc.for Rechargeable Lithium Batteries. J. Power Sources 54:

  8. Batteries: Overview of Battery Cathodes

    E-Print Network [OSTI]

    Doeff, Marca M

    2011-01-01T23:59:59.000Z

    used graphite anode. After charging, the batteries are readylithium ion batteries (i.e. , to lithiate graphite anodes soGraphite Electrodes Due to the Deposition of Manganese Ions on Them in Li-Ion Batteries.

  9. Vehicle Technologies Office Merit Review 2015: High Energy Anode Material Development for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Sinode Systems at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy anode material...

  10. Characterization of nanostructured materials for lithium-ion batteries and electrochemical capacitors

    E-Print Network [OSTI]

    Augustyn, Veronica

    2013-01-01T23:59:59.000Z

    reactivity of vanadium oxide aerogels." Electrochimica Acta,B. Dunn. “Vanadium Oxide Aerogels: Nanostructured MaterialsE. & Dunn, B. V 2 O 5 aerogel as a versatile host for metal

  11. Corporate Venture Capital (CVC) Seeking Innovation and

    E-Print Network [OSTI]

    , Technology Innovation Program, National Institute of Standards and Technology #12;Corporate Venture Capital, Deputy Director Technology Innovation Program Marc G. Stanley, Director #12;ii Acknowledgments T his policymakers in the role of corporate venture capital (CVC) in technology innovation. The research included

  12. Puna Geothermal Venture Hydrologic Monitoring Program

    SciTech Connect (OSTI)

    None

    1990-04-01T23:59:59.000Z

    This document provides the basis for the Hydrologic Monitoring Program (HMP) for the Puna Geothermal Venture. The HMP is complementary to two additional environmental compliance monitoring programs also being submitted by Puma Geothermal Venture (PGV) for their proposed activities at the site. The other two programs are the Meteorology and Air Quality Monitoring Program (MAQMP) and the Noise Monitoring Program (NMP), being submitted concurrently.

  13. Factors influencing the discharge characteristics of Na0.44MnO2-based positive electrode materials for rechargeable lithium batteries

    E-Print Network [OSTI]

    Doeff, M.M.

    2011-01-01T23:59:59.000Z

    in rechargeable lithium battery configurations. 1,2,3 Theseprior to use in a lithium battery configuration,. Partial

  14. Author's personal copy Developments in electrode materials and electrolytes for aluminiumeair batteries

    E-Print Network [OSTI]

    Gravell, Andrew M.

    developed in the 1960s. This review shows the influence of the materials, including: aluminium alloy, oxygen%) aluminium alloyed with traces of Mg, Sn, In and Ga are used to inhibit corrosion or to break down the passive hydroxide layer. Since high-purity aluminium alloys are expensive, an alternative approach

  15. Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries

    E-Print Network [OSTI]

    Zhu, Jianxin

    2014-01-01T23:59:59.000Z

    and characterization of spinel Li 4 Ti 5 O 12 nanoparticles anode materials for lithium ion battery.Li-ion battery performance. Figure 34. Characterization of

  16. Development of High Energy Lithium Batteries for Electric Vehicles...

    Broader source: Energy.gov (indexed) [DOE]

    Kasei * Focused on High Capacity Manganese Rich (HCMR TM ) cathodes & Silicon-Carbon composite anodes for Lithium ion batteries * Envia's high energy Li-ion battery materials...

  17. Battery Company Puts New Nanowire Technology into Production...

    Office of Environmental Management (EM)

    batteries for niche market applications. Silicon offers a number of advantages over pure graphite, the current material of choice for lithium ion batteries. In particular,...

  18. Making better batteries with metal oxide & graphene composites

    SciTech Connect (OSTI)

    None

    2011-03-01T23:59:59.000Z

    Learn how PNNL and Princeton scientists create better materials for batteries, materials that assemble on their own into durable nanocomposites.

  19. Making better batteries with metal oxide & graphene composites

    ScienceCinema (OSTI)

    None

    2012-12-31T23:59:59.000Z

    Learn how PNNL and Princeton scientists create better materials for batteries, materials that assemble on their own into durable nanocomposites.

  20. Self-charging solar battery

    SciTech Connect (OSTI)

    Curiel, R.F.

    1987-03-03T23:59:59.000Z

    This patent describes a flashlight employing a self-charging solar battery assembly comprising: a flashlight housing formed at least partially of a transparent material, an open-ended cylindrical battery housing formed at least partially of a transparent material, a rechargeable battery cell means mounted in the battery housing with its transparent material positioned adjacent the transparent material of the flashlight housing and comprising positive and negative terminals, one at each end thereof, a solar electric panel comprising photo-voltaic cell means having positive and negative terminals, the panel being mounted within the battery housing with the photo-voltaic cell means juxtapositioned to the transparent material of the battery housing such that solar rays may pass through the transparent material of the flashlight housing and the battery housing and excite the photo-voltaic cell means, a first means for connecting the positive terminal of the photo-voltaic cell means to the positive terminal of the battery cell means, and a second means for connecting the negative terminal of the battery cell means to the negative terminal of the photo-voltaic cell means.

  1. Technology Venture Development Community Partnerships Strategic Initiatives

    E-Print Network [OSTI]

    Technology Venture Development Community Partnerships · Strategic Initiatives · Faculty Outreach) 587-3836 Technology Commercialization Office (TCO) Intellectual Property Protection · Technology and Start the Commercialization Process www.TeCh venTUreS.UTAh.eDU Technology commercialization starts

  2. Battery utilizing ceramic membranes

    DOE Patents [OSTI]

    Yahnke, M.S.; Shlomo, G.; Anderson, M.A.

    1994-08-30T23:59:59.000Z

    A thin film battery is disclosed based on the use of ceramic membrane technology. The battery includes a pair of conductive collectors on which the materials for the anode and the cathode may be spin coated. The separator is formed of a porous metal oxide ceramic membrane impregnated with electrolyte so that electrical separation is maintained while ion mobility is also maintained. The entire battery can be made less than 10 microns thick while generating a potential in the 1 volt range. 2 figs.

  3. Soluble Lead Flow Battery: Soluble Lead Flow Battery Technology

    SciTech Connect (OSTI)

    None

    2010-09-01T23:59:59.000Z

    GRIDS Project: General Atomics is developing a flow battery technology based on chemistry similar to that used in the traditional lead-acid battery found in nearly every car on the road today. Flow batteries store energy in chemicals that are held in tanks outside the battery. When the energy is needed, the chemicals are pumped through the battery. Using the same basic chemistry as a traditional battery but storing its energy outside of the cell allows for the use of very low cost materials. The goal is to develop a system that is far more durable than today’s lead-acid batteries, can be scaled to deliver megawatts of power, and which lowers the cost of energy storage below $100 per kilowatt hour.

  4. Khalil Amine on Lithium-air Batteries

    SciTech Connect (OSTI)

    Khalil Amine

    2009-09-14T23:59:59.000Z

    Khalil Amine, materials scientist at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  5. Khalil Amine on Lithium-air Batteries

    ScienceCinema (OSTI)

    Khalil Amine

    2010-01-08T23:59:59.000Z

    Khalil Amine, materials scientist at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  6. Self-charging solar battery

    SciTech Connect (OSTI)

    Curiel, R.F.

    1986-01-07T23:59:59.000Z

    This self-charging solar battery consists of: a flashlight housing formed at least partially of a transparent material, an open-ended cylindrical battery housing formed at least partially of a transparent material, a rechargeable battery cell means mounted in the battery housing (with its transparent material positioned adjacent the transparent material of the flashlight housing and comprising positive and negative terminals, one at each end thereof), a solar electric panel comprising photo-voltaic cell means having positive and negative terminals, and a diode means mounted in the battery housing and comprising an anode and a cathode. The solar battery also has: a first means for connecting the positive terminal of the photo-voltaic cell means to the anode and for connecting the cathode to the positive terminal of the battery cell means, a second means for connecting the negative terminal of the battery cell means to the negative terminal of the photo-voltaic cell means, and cap means for closing each end of the battery housing.

  7. FeO0.7F1.3/C Nanocomposite as a High-Capacity Cathode Material for Sodium-Ion Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Yong-Ning [Brookhaven National Laboratory, Department of Chemistry, Uptown, NY (United States); Sina, Masha [Rutgers Univ., Materials and Engineering, Piscataway, NJ (United States); Pereira, Nathalie [Rutgers Univ., Energy Storage Research Group (ESRG), Piscataway, NJ (United States); Yu, Xiquian [Brookhaven National Laboratory, Department of Chemistry, Uptown, NY (United States); Amatucci, Glenn G. [Rutgers Univ., Energy Storage Research Group (ESRG), Piscataway, NJ (United States); Yang, Xiao-Qing [Brookhaven National Laboratory, Department of Chemistry, Uptown, NY (United States); Cosandey, Frederic [Rutgers Univ., Materials and Engineering, Piscataway, NJ (United States); Nam, Kyung-Wan [Dongguk University-Seoul (Korea, Republic of). Dept. of Energy and Materials Engineering

    2015-02-01T23:59:59.000Z

    Searching high capacity cathode materials is one of the most important fields of the research and development of sodium-ion batteries (SIBs). Here, we report a FeO0.7F1.3/C nanocomposite synthesized via a solution process as a new cathode material for SIBs. This material exhibits a high initial discharge capacity of 496 mAh g-1 in a sodium cell at 50 °C. From the 3rd to 50th cycle, the capacity fading is only 0.14% per cycle (from 388 mAh g-1 at 3rd the cycle to 360 mAh g-1 at the 50th cycle), demonstrating superior cyclability. A high energy density of 650 Wh kg-1 is obtained at the material level. The reaction mechanism studies of FeO0.7F1.3/C with sodium show a hybridized mechanism of both intercalation and conversion reaction.

  8. ESTABLISHING SUSTAINABLE US HEV/PHEV MANUFACTURING BASE: STABILIZED LITHIUM METAL POWDER, ENABLING MATERIAL AND REVOLUTIONARY TECHNOLOGY FOR HIGH ENERGY LI-ION BATTERIES

    SciTech Connect (OSTI)

    Yakovleva, Marina

    2012-12-31T23:59:59.000Z

    FMC Lithium Division has successfully completed the project “Establishing Sustainable US PHEV/EV Manufacturing Base: Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy Li-ion Batteries”. The project included design, acquisition and process development for the production scale units to 1) produce stabilized lithium dispersions in oil medium, 2) to produce dry stabilized lithium metal powders, 3) to evaluate, design and acquire pilot-scale unit for alternative production technology to further decrease the cost, and 4) to demonstrate concepts for integrating SLMP technology into the Li- ion batteries to increase energy density. It is very difficult to satisfy safety, cost and performance requirements for the PHEV and EV applications. As the initial step in SLMP Technology introduction, industry can use commercially available LiMn2O4 or LiFePO4, for example, that are the only proven safer and cheaper lithium providing cathodes available on the market. Unfortunately, these cathodes alone are inferior to the energy density of the conventional LiCoO2 cathode and, even when paired with the advanced anode materials, such as silicon composite material, the resulting cell will still not meet the energy density requirements. We have demonstrated, however, if SLMP Technology is used to compensate for the irreversible capacity in the anode, the efficiency of the cathode utilization will be improved and the cost of the cell, based on the materials, will decrease.

  9. Designing the organizational structure for an entrepreneurial venture

    E-Print Network [OSTI]

    Martinez Delgado, Juan Carlos

    2010-01-01T23:59:59.000Z

    BS Grupo is a Peruvian entrepreneurial venture begun in 2000. The company has grown relatively fast, becoming a leading training provider in Peru. The venture delivers high level and specialized training services in the ...

  10. Lab seeks venture acceleration initiative partners

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home asLCLS ExperimentalFiveVenture Acceleration FundVenture

  11. Venture Global Calcasieu Pass, LLC- (Formerly Venture Global LNG, LLC)- 14-88-LNG

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy gives notice of receipt of an application filed on May 13, 2014, by Venture Global LNG, LLC (VGP) requesting long-term, multi-contract authority to export (in addition...

  12. Technology Venture Development Community Partnerships Strategic Initiatives

    E-Print Network [OSTI]

    Technology Venture Development Community Partnerships · Strategic Initiatives · Faculty Outreach) 587-3836 Technology Commercialization Office (TCO) Intellectual Property Protection · Technology) 585-3844 INTRODUCTION www.TeCh venTUreS.UTAh.eDUwww.TeCh venTUreS.UTAh.eDU Technology

  13. Direct Access to Mesoporous Crystalline TiO2/Carbon Composites with Large and Uniform Pores for Use as Anode Materials in Lithium Ion Batteries

    SciTech Connect (OSTI)

    Lee, Jinwoo; Jung, Yoon S.; Warren, Scott C.; Kamperman, Marleen; Oh, Seung M.; DiSalvo, Francis J.; Wiesner, Ulrich

    2011-01-01T23:59:59.000Z

    Mesoporous and highly crystalline TiO{sub 2} (anatase)/carbon composites with large (>5?nm) and uniform pores were synthesized using PI-b-PEO block copolymers as structure directing agents. Pore sizes could be tuned by utilizing block copolymers with different molecular weights. The resulting mesoporous TiO{sub 2}/carbon was successfully used as an anode material for Li ion batteries. Without addition of conducting aid (Super P), the electrode showed high capacity during the first insertion/desertion cycle due to carbon wiring inside the walls of mesoporous TiO{sub 2}/carbon. The electrode further showed stable cycle performance up to 50 cycles and the specific charge capacity at 30?C was 38?mA h (g of TiO{sub 2}){sup ?1}, which indicates CCM-TiO{sub 2}/carbon can be used as a material for high rate use.

  14. LiMn{sub 2}O{sub 4} nanoparticles anchored on graphene nanosheets as high-performance cathode material for lithium-ion batteries

    SciTech Connect (OSTI)

    Lin, Binghui; Yin, Qing; Hu, Hengrun; Lu, Fujia [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Xia, Hui, E-mail: xiahui@njust.edu.cn [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Herbert Gleiter Institute of Nanoscience, Nanjing University of Science and Technology, Nanjing 210094 (China)

    2014-01-15T23:59:59.000Z

    Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite has been successfully synthesized by a one-step hydrothermal method without post-heat treatment. In the nanocomposite, LiMn{sub 2}O{sub 4} nanoparticles of 10–30 nm in size are well crystallized and homogeneously anchored on the graphene nanosheets. The graphene nanosheets not only provide a highly conductive matrix for LiMn{sub 2}O{sub 4} nanoparticles but also effectively reduce the agglomeration of LiMn{sub 2}O{sub 4} nanoparticles. The nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite exhibited greatly improved electrochemical performance in terms of specific capacity, cycle performance, and rate capability compared with the bare LiMn{sub 2}O{sub 4} nanoparticles. The superior electrochemical performance of the nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite makes it promising as cathode material for high-performance lithium-ion batteries. - Graphical abstract: Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets (GNS) nanocomposite exhibit superior cathode performance for lithium-ion batteries compared to the bare LiMn{sub 2}O{sub 4} nanoparticles. Display Omitted - Highlights: • LiMn{sub 2}O{sub 4}/graphene nanocomposite is synthesized by a one-step hydrothermal method. • LiMn{sub 2}O{sub 4} nanoparticles are uniformly anchored on the graphene nanosheets. • The nanocomposite exhibits excellent cathode performance for lithium-ion batteries.

  15. Manganese Oxide Composite Electrodes for Lithium Batteries |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Oxide Composite Electrodes for Lithium Batteries Technology available for licensing: Improved spinel-containing "layered-layered" lithium metal oxide electrodes Materials...

  16. Safety Hazards of Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Safety Hazards of Batteries Battery technology is at the heart of much of our technological revolution. One of the most prevalent rechargeable batteries in use today is the...

  17. Solid Electrolyte Batteries

    Broader source: Energy.gov (indexed) [DOE]

    Present Li-ion Batteries Insertion compounds have limited capacity Li Air batteries are inefficient if used for electrical energy storage Li S batteries have too...

  18. Electrochemical performance of Sol-Gel synthesized LiFePO4 in lithium batteries

    E-Print Network [OSTI]

    Hu, Yaoqin; Doeff, Marca M.; Kostecki, Robert; Finones, Rita

    2003-01-01T23:59:59.000Z

    LiFePO 4 in Lithium Batteries Yaoqin Hu,* Marca M. Doeff,*material in lithium ion batteries based on environmental and

  19. LNG ventures raise economic, technical, partnership issues

    SciTech Connect (OSTI)

    Acord, H.K. [Mobil Oil Corp., Fairfax, VA (United States)

    1995-07-03T23:59:59.000Z

    The author feels that natural gas will remain a competitive energy alternative and the preferred fuel for many residential and industrial customers around the globe. The article attempts to explain where liquefied natural gas will fit into the global picture. The paper discusses the growth in the Asia-Pacific region; the complex interactions in a LNG project involving buyers, sellers, governments, financial institutions, and shipping companies; the cost of development of such projects; and the elements of a LNG venture.

  20. Autonomic Materials for Smarter, Safer, Longer-Lasting Batteries (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Thackeray, Michael (Director, Center for Electrical Energy Storage); CEES Staff

    2011-11-02T23:59:59.000Z

    'Autonomic Materials for Smarter, Safer, Longer-Lasting Batteries' was submitted by the Center for Electrical Energy Storage (CEES) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. CEES, an EFRC directed by Michael Thackery at Argonne National Laboratory is a partnership of scientists from three institutions: ANL (lead), Northwestern University, and the University of Illinois at Urbana-Champaign. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of the Center for Electrical Energy Storage is 'to acquire a fundamental understanding of interfacial phenomena controlling electrochemical processes that will enable dramatic improvements in the properties and performance of energy storage devices, notable Li ion batteries.' Research topics are: electrical energy storage, batteries, battery electrodes, electrolytes, adaptive materials, interfacial characterization, matter by design; novel materials synthesis, charge transport, and defect tolerant materials.

  1. Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries

    E-Print Network [OSTI]

    Shim, J.; Guerfi, A.; Zaghib, K.; Striebel, K.A.

    2003-01-01T23:59:59.000Z

    Cathode for Lithium-Ion Batteries J. Shim a , A. Guerfi b ,material for Li rechargeable batteries because of low-cost,is a part of BATT (Batteries for Advanced Transportation

  2. Venture Capital Fund Performance and the IPO Market

    E-Print Network [OSTI]

    McKenzie, Michael; Janeway, William

    2008-01-01T23:59:59.000Z

    concluding comments. I. Literature Survey The principal source of venture investment data is a commercial database maintained by the Venture Economics5 (VE hereafter) unit of Thompson Financial group. This database contains aggregate information... 5 Formerly known as the Venture eXpert database. The authors would like to thank Thompson Reuters for providing access to this database. 6 information about the performance of private equity investing using data on the returns to individual...

  3. Joint Venture Established Between Russian Weapons Plant And the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Venture Established Between Russian Weapons Plant And the Largest Dialysis Provider in the U.S. | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS...

  4. CRADA Final Report for NFE-08-01826: Development and application of processing and processcontrol for nano-composite materials for lithium ion batteries

    SciTech Connect (OSTI)

    Daniel, C.; Armstrong, B.; Maxey, C.; Sabau, A.; Wang, H.; Hagans, P. (A123 Systems, Inc.); and Babinec, S. (A123 Systems, Inc.)

    2012-12-15T23:59:59.000Z

    Oak Ridge National Laboratory and A123 Systems, Inc. collaborated on this project to develop a better understanding, quality control procedures, and safety testing for A123 System’s nanocomposite separator (NCS) technology which is a cell based patented technology and separator. NCS demonstrated excellent performance. x3450 prismatic cells were shown to survive >8000 cycles (1C/2C rate) at room temperature with greater than 80% capacity retention with only NCS present as an alternative to conventional polyolefin. However, for a successful commercialization, the coating conditions required to provide consistent and reliable product had not been optimized and QC techniques for being able to remove defective material before incorporation into a cell had not been developed. The work outlined in this report addresses these latter two points. First, experiments were conducted to understand temperature profiles during the different drying stages of the NCS coating when applied to both anode and cathode. One of the more interesting discoveries of this study was the observation of the large temperature decrease experienced by the wet coating between the end of the infrared (IR) drying stage and the beginning of the exposure to the convection drying oven. This is not a desirable situation as the temperature gradient could have a deleterious effect on coating quality. Based on this and other experimental data a radiative transfer model was developed for IR heating that also included a mass transfer module for drying. This will prove invaluable for battery coating optimization especially where IR drying is being employed. A stress model was also developed that predicts that under certain drying conditions tensile stresses are formed in the coating which could lead to cracking that is sometimes observed after drying is complete. Prediction of under what conditions these stresses form is vital to improving coating quality. In addition to understanding the drying process other parameters such as slurry quality and equipment optimization were examined. Removal of particles and gels by filtering, control of viscosity by %solids and mixing adjustments, removal of trapped gas in the slurry and modification of coater speed and slot die gap were all found to be important for producing uniform and flaw-free coatings. Second, an in-line Hi-Pot testing method has been developed specifically for NCS that will enable detection of coating flaws that could lead to soft or hard electrical shorts within the cell. In this way flawed material can be rejected before incorporation into the cell thus greatly reducing the amount of scrap that is generated. Improved battery safety is an extremely important benefit of NCS. Evaluation of battery safety is usually accomplished by conducting a variety of tests including nail penetration, hot box, over charge, etc. For these tests entire batteries must be built but the resultant temperature and voltage responses reveal little about the breakdown mechanism. In this report is described a pinch test which is used to evaluate NCS quality at various stages including coated anode and cathode as well as assembled cell. Coupled with post-microscopic examination of the damaged ‘pinch point’ test data can assist in the coating optimization from an improved end-use standpoint. As a result of this work two invention disclosures, one for optimizing drying methodology and the other for an in-line system for flaw detection, have been filed. In addition, 2 papers are being written for submission to peer-reviewed journals.

  5. Final Report - Recovery Act - Development and application of processing and process control for nano-composite materials for lithium ion batteries

    SciTech Connect (OSTI)

    Daniel, Claus [ORNL; Armstrong, Beth L [ORNL; Maxey, L Curt [ORNL; Sabau, Adrian S [ORNL; Wang, Hsin [ORNL; Hagans, Patrick [A123 Systems, Inc.; Babinec, Sue [A123 Systems, Inc.

    2013-08-01T23:59:59.000Z

    Oak Ridge National Laboratory and A123 Systems, Inc. collaborated on this project to develop a better understanding, quality control procedures, and safety testing for A123 System s nanocomposite separator (NCS) technology which is a cell based patented technology and separator. NCS demonstrated excellent performance. x3450 prismatic cells were shown to survive >8000 cycles (1C/2C rate) at room temperature with greater than 80% capacity retention with only NCS present as an alternative to conventional polyolefin. However, for a successful commercialization, the coating conditions required to provide consistent and reliable product had not been optimized and QC techniques for being able to remove defective material before incorporation into a cell had not been developed. The work outlined in this report addresses these latter two points. First, experiments were conducted to understand temperature profiles during the different drying stages of the NCS coating when applied to both anode and cathode. One of the more interesting discoveries of this study was the observation of the large temperature decrease experienced by the wet coating between the end of the infrared (IR) drying stage and the beginning of the exposure to the convection drying oven. This is not a desirable situation as the temperature gradient could have a deleterious effect on coating quality. Based on this and other experimental data a radiative transfer model was developed for IR heating that also included a mass transfer module for drying. This will prove invaluable for battery coating optimization especially where IR drying is being employed. A stress model was also developed that predicts that under certain drying conditions tensile stresses are formed in the coating which could lead to cracking that is sometimes observed after drying is complete. Prediction of under what conditions these stresses form is vital to improving coating quality. In addition to understanding the drying process other parameters such as slurry quality and equipment optimization were examined. Removal of particles and gels by filtering, control of viscosity by %solids and mixing adjustments, removal of trapped gas in the slurry and modification of coater speed and slot die gap were all found to be important for producing uniform and flaw-free coatings. Second, an in-line Hi-Pot testing method has been developed specifically for NCS that will enable detection of coating flaws that could lead to soft or hard electrical shorts within the cell. In this way flawed material can be rejected before incorporation into the cell thus greatly reducing the amount of scrap that is generated. Improved battery safety is an extremely important benefit of NCS. Evaluation of battery safety is usually accomplished by conducting a variety of tests including nail penetration, hot box, over charge, etc. For these tests entire batteries must be built but the resultant temperature and voltage responses reveal little about the breakdown mechanism. In this report is described a pinch test which is used to evaluate NCS quality at various stages including coated anode and cathode as well as assembled cell. Coupled with post-microscopic examination of the damaged pinch point test data can assist in the coating optimization from an improved end-use standpoint. As a result of this work two invention disclosures, one for optimizing drying methodology and the other for an in-line system for flaw detection, have been filed. In addition, 2 papers are being written for submission to peer-reviewed journals.

  6. Materials Engineering Research Facility | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Engineering Research Facility Argonne's new Materials Engineering Research Facility (MERF) supports the laboratory's Advanced Battery Materials Synthesis and...

  7. Enhanced performance of graphite anode materials by AlF3 coating for lithium-ion batteries

    SciTech Connect (OSTI)

    Ding, Fei; Xu, Wu; Choi, Daiwon; Wang, Wei; Li, Xiaolin; Engelhard, Mark H.; Chen, Xilin; Yang, Zhenguo; Zhang, Jiguang

    2012-04-27T23:59:59.000Z

    In order to form the stable surface film and to further enhance the long-term cycling stability of the graphite anodes of lithium-ion batteries, the surface of graphite powders has been modified by AlF3 coating through chemical precipitation method. The AlF3-coated graphite shows no evident changes in the bulk structure and a thin AlF3-coating layer of about 2 nm thick is found to uniformly cover the graphite particles with 2 wt% AlF3 content. However, it delivers a higher initial discharge capacity and largely improved rate performances compared to the pristine graphite. Remarkably, AlF3 coated graphite demonstrated a much better cycle life. After 300 cycles, AlF3 coated graphite and uncoated graphite show capacity retention of 92% and 81%, respectively. XPS measurement shows that a more conductive solid electrode interface (SEI) layer was formed on AlF3 coated graphite as compared to uncoated graphite. SEM monograph also reveals that the AlF3-coated graphite particles have a much more stable surface morphology after long-term cycling. Therefore, the improved electrochemical performance of AlF3 coated graphite can be attributed to a more stable and conductive SEI formed on coated graphite anode during cycling process.

  8. Construction of a Li Ion Battery (LIB) Cathode Production Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of LIB Cathode Materials Process for Low Cost Domestic Production of LIB Cathode Materials Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio...

  9. Electrode Structures and Surfaces for Lithium Batteries | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structures and Surfaces for Lithium Batteries Technology available for licensing: Lithium-metal-oxide electrode materials with modified surfaces to protect the materials from...

  10. Investigation of critical parameters in Li-ion battery electrodes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Negative Electrodes: Novel and Optimized Materials Novel and Optimized Materials Phases for High Energy Density Batteries FY 2012 Annual Progress Report for Energy Storage R&D...

  11. Lithium-ion battery modeling using non-equilibrium thermodynamics

    E-Print Network [OSTI]

    Ferguson, Todd R. (Todd Richard)

    2014-01-01T23:59:59.000Z

    The focus of this thesis work is the application of non-equilibrium thermodynamics in lithium-ion battery modeling. As the demand for higher power and longer lasting batteries increases, the search for materials suitable ...

  12. High-throughput data mined prediction of inorganic compounds and computational discovery of new lithium-ion battery cathode materials

    E-Print Network [OSTI]

    Hautier, Geoffroy (Geoffroy T. F.)

    2011-01-01T23:59:59.000Z

    The ability to computationally predict the properties of new materials, even prior to their synthesis, has been made possible due to the current accuracy of modern ab initio techniques. In some cases, high-throughput ...

  13. Vehicle Technologies Office Merit Review 2015: Materials Development for High Energy High Power Battery Exceeding PHEV-40 Requirements

    Broader source: Energy.gov [DOE]

    Presentation given by TIAX LLC at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about materials development for high...

  14. Battery components employing a silicate binder

    SciTech Connect (OSTI)

    Delnick, Frank M. (Albuquerque, NM); Reinhardt, Frederick W. (Albuquerque, NM); Odinek, Judy G. (Rio Rancho, NM)

    2011-05-24T23:59:59.000Z

    A battery component structure employing inorganic-silicate binders. In some embodiments, casting or coating of components may be performed using aqueous slurries of silicates and electrode materials or separator materials.

  15. Solar Array Ventures Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries Pvt LtdShawangunk, New York:SiG26588°,SocorromercurySolaire Direct NameVentures

  16. Lab seeks ideas for Venture Acceleration Fund

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home asLCLS ExperimentalFiveVenture Acceleration Fund ideas

  17. Lab seeks ideas for venture acceleration fund

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home asLCLS ExperimentalFiveVenture Acceleration Fund

  18. Venture Acceleration Fund now accepting 2012 applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsing Maps1 - USAFof EnergyVendor InformationVenture

  19. Pangaea Ventures Ltd (Canada) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall,Missouri:EnergyOssian, NewPalisades Park, NewPalomarPangaea Ventures Ltd

  20. El Dorado Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model,DOEHazel Crest, Illinois:Edinburgh University akaCajon,Cerrito,Ventures Place:

  1. Applied Ventures LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: Energy Resources JumpAnaconda,Anza ElectricInc JumpApplied Ventures

  2. Arch Venture Partners (Washington) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: Energy Resources JumpAnaconda,Anza ElectricIncAboutAquilaArch Venture

  3. Technology Ventures Corporation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with formSoutheastern ILSunseekerTallahatchie ValleyInnovationTechnology Ventures

  4. Clear Power Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCity ofClarkEnergy - QPower Ventures Jump

  5. Foothills Energy Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdf Jump to:ar-80m.pdfFillmoreGabbs Valley Area(Sasada,Foothills Energy Ventures

  6. Redox Flow Batteries, a Review

    E-Print Network [OSTI]

    Weber, Adam Z.

    2013-01-01T23:59:59.000Z

    battery configuration. Lead-acid batteries do not shuttleincluding lead-acid, nickel-based, and lithium-ion batteries

  7. Investment performance of life-science venture capital investment funds, persistence, and subsector analysis

    E-Print Network [OSTI]

    Behrens, Jeffrey S

    2007-01-01T23:59:59.000Z

    Venture capital investment performance data and performance attribution are not typically published. Venture investors articulate (and sell to LPs) conflicting strategies; the popular business literature and culture is ...

  8. Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and ultrahigh power lithium-ion batteries

    SciTech Connect (OSTI)

    Xu, Wu; Chen, Xilin; Wang, Wei; Choi, Daiwon; Ding, Fei; Zheng, Jianming; Nie, Zimin; Choi, Young Joon; Zhang, Jiguang; Yang, Zhenguo

    2013-08-15T23:59:59.000Z

    The commercial Li4Ti5O12 (LTO) is successfully modified by AlF3 via a low temperature process. After being calcined at 400oC for 5 hours, AlF3 reacts with LTO to form a composite material which mainly consists of Al3+ and F- co-doped LTO with small amounts of anatase TiO2 and Li3AlF6. Al3+ and F- co-doped LTO demonstrates largely improved rate capability comparing to the pristine LTO. Since the amount of the byproduct TiO2 is relatively small, the modified LTO electrodes retain the main voltage characteristics of LTO with a minor feature similar to those of anatase TiO2. The doped LTO anodes deliver higher discharge capacity and significantly improved high-rate performance when compared to the pristine LTO anode. They also demonstrate excellent long-term cycling stability at elevated temperatures. Therefore, Al3+ and F- co-doped LTO synthesized at low temperature is an excellent anode for stable and ultra-high power lithium-ion batteries.

  9. Storage Characteristics of LiNi0.8Co0.1+xMn0.1-xO2 (x = 0, 0.03, and 0.06) Cathode Materials for Lithium Batteries

    E-Print Network [OSTI]

    Cho, Jaephil

    Storage Characteristics of LiNi0.8Co0.1+xMn0.1-xO2 (x = 0, 0.03, and 0.06) Cathode Materials for Lithium Batteries Junho Eom,a Min Gyu Kim,b and Jaephil Choa, *,z a Department of Applied Chemistry for 15 h. Using these powders, their storage charac- teristics upon exposure to air and electrolytes

  10. Understanding local degradation of cycled Ni-rich cathode materials at high operating temperature for Li-ion batteries

    SciTech Connect (OSTI)

    Hwang, Sooyeon; Kim, Dong Hyun; Chung, Kyung Yoon; Chang, Wonyoung, E-mail: cwy@kist.re.kr [Center for Energy Convergence, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of)

    2014-09-08T23:59:59.000Z

    We utilize transmission electron microscopy in conjunction with electron energy loss spectroscopy to investigate local degradation that occurs in Li{sub x}Ni{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} cathode materials (NCA) after 30 cycles with cutoff voltages of 4.3?V and 4.8?V at 55?°C. NCA has a homogeneous crystallographic structure before electrochemical reactions; however, we observed that 30 cycles of charge/discharge reactions induced inhomogeneity in the crystallographic and electronic structures and also introduced porosity particularly at surface area. These changes were more noticeable in samples cycled with higher cutoff voltage of 4.8?V. Effect of operating temperature was further examined by comparing electronic structures of oxygen of the NCA particles cycled at both room temperature and 55?°C. The working temperature has a greater impact on the NCA cathode materials at a cutoff voltage of 4.3?V that is the practical the upper limit voltage in most applications, while a cutoff voltage of 4.8?V is high enough to cause surface degradation even at room temperature.

  11. Ventures in science status report, Summer 1992

    SciTech Connect (OSTI)

    Not Available

    1992-11-01T23:59:59.000Z

    The Ventures in Science summer program is directed towards students who are from underrepresented minority groups in mathematics and science professions. The target group of 40 was drawn from eligible students who will be entering high school freshman in the fall of 1992. 450 students applied. The theme for the summer is Chicago as an Ecosystem. The students are instructed in integrated math and science (2 hours), English/ESL (1 1/2 hrs.), counseling (1 hr.) and, physical education (1 hr.) each day four days a week. Integrated math and science are team taught. Parents are invited to participate in two workshops that will be presented based on their input. Parents may also visit the program at any time and participate in any field trip.

  12. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22T23:59:59.000Z

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  13. Household batteries: Evaluation of collection methods

    SciTech Connect (OSTI)

    Seeberger, D.A.

    1992-01-01T23:59:59.000Z

    While it is difficult to prove that a specific material is causing contamination in a landfill, tests have been conducted at waste-to-energy facilities that indicate that household batteries contribute significant amounts of heavy metals to both air emissions and ash residue. Hennepin County, MN, used a dual approach for developing and implementing a special household battery collection. Alternative collection methods were examined; test collections were conducted. The second phase examined operating and disposal policy issues. This report describes the results of the grant project, moving from a broad examination of the construction and content of batteries, to a description of the pilot collection programs, and ending with a discussion of variables affecting the cost and operation of a comprehensive battery collection program. Three out-of-state companies (PA, NY) were found that accept spent batteries; difficulties in reclaiming household batteries are discussed.

  14. Household batteries: Evaluation of collection methods

    SciTech Connect (OSTI)

    Seeberger, D.A.

    1992-12-31T23:59:59.000Z

    While it is difficult to prove that a specific material is causing contamination in a landfill, tests have been conducted at waste-to-energy facilities that indicate that household batteries contribute significant amounts of heavy metals to both air emissions and ash residue. Hennepin County, MN, used a dual approach for developing and implementing a special household battery collection. Alternative collection methods were examined; test collections were conducted. The second phase examined operating and disposal policy issues. This report describes the results of the grant project, moving from a broad examination of the construction and content of batteries, to a description of the pilot collection programs, and ending with a discussion of variables affecting the cost and operation of a comprehensive battery collection program. Three out-of-state companies (PA, NY) were found that accept spent batteries; difficulties in reclaiming household batteries are discussed.

  15. Vorbeck Materials Corp. | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    is developing a low-cost, advanced lithium-ion battery that employs a novel silicon graphene composite material that will substantially improve battery cycle life. When combined...

  16. Transformational Materials Science Initiative Review June 29...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    mode Easiness of assembly in discharged state Less corrosive nature of cathode materials <3> ZEBRA battery cost projection * * R.C. Galloway, C.-H. Dustmann, "ZEBRA Battery...

  17. Carbon-enhanced VRLA batteries.

    SciTech Connect (OSTI)

    Enos, David George; Hund, Thomas D.; Shane, Rod (East Penn Manufacturing, Lyon Station, PA)

    2010-10-01T23:59:59.000Z

    The addition of certain forms of carbon to the negative plate in valve regulated lead acid (VRLA) batteries has been demonstrated to increase the cycle life of such batteries by an order of magnitude or more under high-rate, partial-state-of-charge operation. Such performance will provide a significant impact, and in some cases it will be an enabling feature for applications including hybrid electric vehicles, utility ancillary regulation services, wind farm energy smoothing, and solar photovoltaic energy smoothing. There is a critical need to understnd how the carbon interacts with the negative plate and achieves the aforementioned benefits at a fundamental level. Such an understanding will not only enable the performance of such batteries to be optimzied, but also to explore the feasibility of applying this technology to other battery chemistries. In partnership with the East Penn Manufacturing, Sandia will investigate the electrochemical function of the carbon and possibly identify improvements to its anti-sulfation properties. Shiomi, et al. (1997) discovered that the addition of carbon to the negative active material (NAM) substantially reduced PbSO{sub 4} accumulation in high rate, partial state of charge (HRPSoC) cycling applications. This improved performance with a minimal cost. Cycling applications that were uneconomical for traditional VRLA batteries are viable for the carbon enhanced VRLA. The overall goal of this work is to quantitatively define the role that carbon plays in the electrochemistry of a VRLA battery.

  18. Thermal Batteries for Electric Vehicles

    SciTech Connect (OSTI)

    None

    2011-11-21T23:59:59.000Z

    HEATS Project: UT Austin will demonstrate a high-energy density and low-cost thermal storage system that will provide efficient cabin heating and cooling for EVs. Compared to existing HVAC systems powered by electric batteries in EVs, the innovative hot-and-cold thermal batteries-based technology is expected to decrease the manufacturing cost and increase the driving range of next-generation EVs. These thermal batteries can be charged with off-peak electric power together with the electric batteries. Based on innovations in composite materials offering twice the energy density of ice and 10 times the thermal conductivity of water, these thermal batteries are expected to achieve a comparable energy density at 25% of the cost of electric batteries. Moreover, because UT Austin’s thermal energy storage systems are modular, they may be incorporated into the heating and cooling systems in buildings, providing further energy efficiencies and positively impacting the emissions of current building heating/cooling systems.

  19. Vehicle Battery Safety Roadmap Guidance

    SciTech Connect (OSTI)

    Doughty, D. H.

    2012-10-01T23:59:59.000Z

    The safety of electrified vehicles with high capacity energy storage devices creates challenges that must be met to assure commercial acceptance of EVs and HEVs. High performance vehicular traction energy storage systems must be intrinsically tolerant of abusive conditions: overcharge, short circuit, crush, fire exposure, overdischarge, and mechanical shock and vibration. Fail-safe responses to these conditions must be designed into the system, at the materials and the system level, through selection of materials and safety devices that will further reduce the probability of single cell failure and preclude propagation of failure to adjacent cells. One of the most important objectives of DOE's Office of Vehicle Technologies is to support the development of lithium ion batteries that are safe and abuse tolerant in electric drive vehicles. This Roadmap analyzes battery safety and failure modes of state-of-the-art cells and batteries and makes recommendations on future investments that would further DOE's mission.

  20. Modification of carbon nanotubes by CuO-doped NiO nanocomposite for use as an anode material for lithium-ion batteries

    SciTech Connect (OSTI)

    Mustansar Abbas, Syed, E-mail: qau_abbas@yahoo.com [Nanoscience and Catalysis Division, National Centre for Physics, Islamabad 45320 (Pakistan); Department of Chemistry, Quaid-e-Azam University, Islamabad (Pakistan); Tajammul Hussain, Syed [Nanoscience and Catalysis Division, National Centre for Physics, Islamabad 45320 (Pakistan); Ali, Saqib [Department of Chemistry, Quaid-e-Azam University, Islamabad (Pakistan); Ahmad, Nisar [Department of Chemistry, Hazara University, Mansehra (Pakistan); Ali, Nisar [Department of Physics, University of Punjab, Lahore (Pakistan); Abbas, Saghir [Department of Chemistry, Quaid-e-Azam University, Islamabad (Pakistan); Ali, Zulfiqar [Nanoscience and Catalysis Division, National Centre for Physics, Islamabad 45320 (Pakistan); College of Earth and Environmental Sciences, University of Punjab, Lahore (Pakistan)

    2013-06-15T23:59:59.000Z

    CuO-doped NiO (CuNiO) with porous hexagonal morphology is fabricated via a modified in-situ co-precipitation method and its nanocomposite is prepared with carbon nanotubes (CNTs). The electrochemical properties of CuNiO/CNT nanocomposite are investigated by cyclic voltammetry (CV), galvanostatic charge–discharge tests and electrochemical impedance spectroscopy (EIS). Since Cu can both act as conductor and a catalyst, the CuNiO/CNT nanocomposite exhibits higher initial coulombic efficiency (82.7% of the 2nd cycle) and better capacity retention (78.6% on 50th cycle) than bare CuNiO (78.9% of the 2nd cycle), CuO/CNT (76.8% of the 2nd cycle) and NiO/CNT (77.7% of the 2nd cycle) at the current density of 100 mA /g. This high capacity and good cycling ability is attributed to the partial substitution of Cu{sup +2} for Ni{sup +2}, resulting in an increase of holes concentration, and therefore improved p-type conductivity along with an intimate interaction with CNTs providing large surface area, excellent conduction, mechanical strength and chemical stability. - Graphical abstract: The porous CuNiO/CNT nanocomposite synthesized via a modified co-precipitation method in combination with subsequent calcination was applied in the negative electrode materials for lithium-ion batteries and exhibited high electrochemical performance. - Highlights: • CuO doped NiO/CNTs nano composite is achieved via a simple co-precipitation method. • Monodispersity, shape and sizes of sample particles is specifically controlled. • Good quality adhesion between CNTs and CuNiO is visible from TEM image. • High electrochemical performance is achieved. • Discharge capacity of 686 mA h/g after 50 cycles with coulombic efficiency (82.5%)

  1. Small Business Venture Capital Tax Credit Program (Manitoba, Canada)

    Broader source: Energy.gov [DOE]

    The Small Business Venture Capital Tax Credit Program (SBVCTC) assists eligible small corporations to issue new equity to primarily new investors. The small corporation will be able to issue from ...

  2. A collaborative research venture between the minerals industry and

    E-Print Network [OSTI]

    Michelson, David G.

    A collaborative research venture between the minerals industry and The University of British Columbia MDRUMINERAL DEPOSIT RESEARCH UNIT To increase the understanding of mineral deposits and highly trained geologists for employment in the minerals industry. Mission Vision MDRU

  3. United States -- Mexican joint ventures: A case history approach

    SciTech Connect (OSTI)

    Moore, N.L.; Chidester, R.J.; Hughes, K.R.; Fowler, R.A.

    1993-03-01T23:59:59.000Z

    Because the Mexican government has encouraged investment in Mexico by increasing the percentage of ownership of a Mexican business that a US company can hold, joint ventures are more attractive now than they had been in the past. This study provides preliminary information for US renewable energy companies who are interested in forming a joint venture with a Mexican company. This report is not intended to be a complete reference but does identifies a number of important factors that should be observed when forming a Mexican joint venture: (1)Successful joint ventures achieve the goals of each partner. (2)It is essential that all parties agree to the allocation of responsibilities. (3)Put everything in writing. (4)Research in depth the country or countries in which you are considering doing business.

  4. Lasting social impact : Community Development Venture Capital investing

    E-Print Network [OSTI]

    Silberberg, Hattie Paige

    2008-01-01T23:59:59.000Z

    Community Development Venture Capital Funds (CDVC) funds are an emerging group of Community Development Financial Institutions, that make equity investments in businesses in economically distressed areas. As equity investors, ...

  5. Methods for thermodynamic evaluation of battery state of health

    DOE Patents [OSTI]

    Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T

    2013-05-21T23:59:59.000Z

    Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.

  6. Intercalation dynamics in lithium-ion batteries

    E-Print Network [OSTI]

    Burch, Damian

    2009-01-01T23:59:59.000Z

    A new continuum model has been proposed by Singh, Ceder, and Bazant for the ion intercalation dynamics in a single crystal of rechargeable-battery electrode materials. It is based on the Cahn-Hilliard equation coupled to ...

  7. Characterization of Li-ion Batteries using Neutron Diffraction...

    Broader source: Energy.gov (indexed) [DOE]

    Li-ion batteries Using Neutron Diffraction and Infrared Imaging Techniques: Success Stories from the High Temperature Materials Laboratory (HTML) User Program DOE 2011 Vehicle...

  8. Surface Modification Agents for Lithium-Ion Batteries | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Modification Agents for Lithium-Ion Batteries Technology available for licensing: A process to modify the surface of the active material used in an electrochemical device...

  9. Redox Flow Batteries: An Engineering Perspective

    SciTech Connect (OSTI)

    Chalamala, Babu R.; Soundappan, Thiagarajan; Fisher, Graham R.; Anstey, Mitchell A.; Viswanathan, Vilayanur V.; Perry, Mike L.

    2014-10-01T23:59:59.000Z

    Redox flow batteries are well suited to provide modular and scalable energy storage systems for a wide range of energy storage applications. In this paper, we review the development of redox flow battery technology including recent advances in new redox active materials and systems. We discuss cost, performance, and reliability metrics that are critical for deployment of large flow battery systems. The technology, while relatively young, has the potential for significant improvement through reduced materials costs, improved energy and power efficiency, and significant reduction in the overall system cost.

  10. High-discharge-rate lithium ion battery

    SciTech Connect (OSTI)

    Liu, Gao; Battaglia, Vincent S; Zheng, Honghe

    2014-04-22T23:59:59.000Z

    The present invention provides for a lithium ion battery and process for creating such, comprising higher binder to carbon conductor ratios than presently used in the industry. The battery is characterized by much lower interfacial resistances at the anode and cathode as a result of initially mixing a carbon conductor with a binder, then with the active material. Further improvements in cycleability can also be realized by first mixing the carbon conductor with the active material first and then adding the binder.

  11. AVTA: Battery Testing - DC Fast Charging's Effects on PEV Batteries...

    Energy Savers [EERE]

    DC Fast Charging's Effects on PEV Batteries AVTA: Battery Testing - DC Fast Charging's Effects on PEV Batteries The Vehicle Technologies Office's Advanced Vehicle Testing Activity...

  12. batteries | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Science Computing Facility: Quiet Wing Science Theme: Biosystem Dynamics & Design Terrestrial & Subsurface Ecosystems Energy Materials & Processes Atmospheric...

  13. Anode material for lithium batteries

    DOE Patents [OSTI]

    Belharouak, Ilias (Bolingbrook, IL); Amine, Khalil (Downers Grove, IL)

    2008-06-24T23:59:59.000Z

    Primary and secondary Li-ion and lithium-metal based electrochemical cell system. The suppression of gas generation is achieved through the addition of an additive or additives to the electrolyte system of respective cell, or to the cell itself whether it be a liquid, a solid- or plastized polymer electrolyte system. The gas suppression additives are primarily based on unsaturated hydrocarbons.

  14. Anode material for lithium batteries

    DOE Patents [OSTI]

    Belharouak, Ilias (Westmont, IL); Amine, Khalil (Downers Grove, IL)

    2012-01-31T23:59:59.000Z

    Primary and secondary Li-ion and lithium-metal based electrochemical cell systems. The suppression of gas generation is achieved through the addition of an additive or additives to the electrolyte system of respective cell, or to the cell itself whether it be a liquid, a solid- or plasticized polymer electrolyte system. The gas suppression additives are primarily based on unsaturated hydrocarbons.

  15. Anode material for lithium batteries

    DOE Patents [OSTI]

    Belharouak, Ilias (Bolingbrook, IL); Amine, Khalil (Oak Brook, IL)

    2011-04-05T23:59:59.000Z

    Primary and secondary Li-ion and lithium-metal based electrochemical cell systems. The suppression of gas generation is achieved through the addition of an additive or additives to the electrolyte system of respective cell, or to the cell itself whether it be a liquid, a solid- or plasticized polymer electrolyte system. The gas suppression additives are primarily based on unsaturated hydrocarbons.

  16. Synthesis and electrochemical performance of LiNi{sub 0.7}Co{sub 0.15}Mn{sub 0.15}O{sub 2} as gradient cathode material for lithium batteries

    SciTech Connect (OSTI)

    Zhang, Lipeng; Dong, Tao [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China); Yu, Xianjin, E-mail: hgxyzlp@sdut.edu.cn [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China); Dong, Yunhui; Zhao, Zengdian; Li, Heng [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)] [School of Chemical Engineering, Shandong University of Technology, Zibo 255049 (China)

    2012-11-15T23:59:59.000Z

    Highlights: ? The gradient precursors Ni{sub 0.7}Co{sub 0.15}Mn{sub 0.15}(OH){sub 2} is prepared by hydroxide co-precipitating. ? The cathode materials is synthesized by mixing the precursor with 5% excess LiOH·H{sub 2}O. ? The XRD results show that cathode materials present layered ?-NaFeO{sub 2} typical crystal. ? Material sintered at 850 °C shows the best performance, with high-capacity and recyclability. -- Abstract: LiNi{sub 0.7}Co{sub 0.15}Mn{sub 0.15}O{sub 2} as a cathode material for lithium batteries was synthesized by mixing hydroxide co-precipitated precursors with 5% excess LiOH·H{sub 2}O. Its structural and electrochemical properties were investigated using X-ray diffractometry, scanning electron microscopy, galvanostatic charge–discharge test, and electrochemical impedance spectroscopy. The results indicated that well-ordering layered LiNi{sub 0.7}Co{sub 0.15}Mn{sub 0.15}O{sub 2} cathode materials were successfully prepared in air at 750, 800, and 850°C with ?-NaFeO{sub 2} typical crystal. The results of charge–discharge test demonstrated that the gradient cathode material sintered at 850 °C exhibited the best electrochemical performance with the initial discharge capacity of 164 mA h g{sup ?1} at 0.2 C and lower electrochemical impedance. Nickel has low price. LiNiO{sub 2} cathode materials have high specific capacity, their theoretical capacity is 274 mA h g{sup ?1} and with low self-discharge rate. So the Ni, Co, Mn ternary layer-structural compounds with high Ni content are showing to be promising cathode materials for lithium batteries. The techniques and research results in this paper are utilizable for the study of this kind of lithium battery materials.

  17. NREL: Energy Storage - Battery Ownership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    publications. Updating United States Advanced Battery Consortium and Department of Energy Battery Technology Targets for Battery Electric Vehicles Sensitivity of Plug-In Hybrid...

  18. RECHARGEABLE HIGH-TEMPERATURE BATTERIES

    E-Print Network [OSTI]

    Cairns, Elton J.

    2014-01-01T23:59:59.000Z

    F. Eshman, High-Performance Batteries for Electric-VehicleS. Sudar, High Performance Batteries for Electric-VehicleHIGH-TEMPERATURE BATTERIES Elton J. Cairns January 1981 TWO-

  19. Quick charge battery

    SciTech Connect (OSTI)

    Parise, R.J.

    1998-07-01T23:59:59.000Z

    Electric and hybrid electric vehicles (EVs and HEVs) will become a significant reality in the near future of the automotive industry. Both types of vehicles will need a means to store energy on board. For the present, the method of choice would be lead-acid batteries, with the HEV having auxiliary power supplied by a small internal combustion engine. One of the main drawbacks to lead-acid batteries is internal heat generation as a natural consequence of the charging process as well as resistance losses. This limits the re-charging rate to the battery pack for an EV which has a range of about 80 miles. A quick turnaround on recharge is needed but not yet possible. One of the limiting factors is the heat buildup. For the HEV the auxiliary power unit provides a continuous charge to the battery pack. Therefore heat generation in the lead-acid battery is a constant problem that must be addressed. Presented here is a battery that is capable of quick charging, the Quick Charge Battery with Thermal Management. This is an electrochemical battery, typically a lead-acid battery, without the inherent thermal management problems that have been present in the past. The battery can be used in an all-electric vehicle, a hybrid-electric vehicle or an internal combustion engine vehicle, as well as in other applications that utilize secondary batteries. This is not restricted to only lead-acid batteries. The concept and technology are flexible enough to use in any secondary battery application where thermal management of the battery must be addressed, especially during charging. Any battery with temperature constraints can benefit from this advancement in the state of the art of battery manufacturing. This can also include nickel-cadmium, metal-air, nickel hydroxide, zinc-chloride or any other type of battery whose performance is affected by the temperature control of the interior as well as the exterior of the battery.

  20. Progress of DOE Materials, Manufacturing Process R&D, and ARRA...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of DOE Materials, Manufacturing Process R&D, and ARRA Battery Manufacturing Grants Progress of DOE Materials, Manufacturing Process R&D, and ARRA Battery Manufacturing Grants 2011...

  1. american-polish joint venture: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    337 389 494 In 1977, 175 joint fishing ventures with the participation-215. In 1981,193 joint ventures with the par- ticipation of Japanese capital were operating in 47 nations...

  2. Venture Global Calcasieu Pass, LLC- FE Dkt. No.- 15-25-LNG

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy gives notice of receipt of an Application filed February 9, 2015, by Venture Global Calcasieu Pass, LLC (Venture Global), seeking a long-term multi-contract...

  3. Technology Venturing and Innovation Management The MSc programme Industrial Engineering and Management (IEM) has four

    E-Print Network [OSTI]

    Twente, Universiteit

    Technology Venturing and Innovation Management The MSc programme Industrial Engineering. One of the topics that IEM students can focus on is Technology Venturing en Innovation Management & Organization of Technology Innovation (191810840), or b) Organisation, Technology & Innovation (201000088) n

  4. Venture Capital and private equity in India : systems analysis and development framework

    E-Print Network [OSTI]

    Surineni, Shravan Kumar

    2012-01-01T23:59:59.000Z

    Venture Capital (VC) has been an important driver of innovation, entrepreneurship and economic growth in the U.S. and around the world for the past few decades. The astounding success of Venture Capital prompted various ...

  5. Startup valuation by venture capitalists: an empirical study Tarek Miloud*, Arild Aspelund and Mathieu Cabrol

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    a supplementary method to value an early-stage new venture when extant valuation methods fail to yield consistent

  6. Recombinant electric storage battery

    SciTech Connect (OSTI)

    Flicker, R.P.; Fenstermacher, S.

    1989-10-10T23:59:59.000Z

    This patent describes a recombinant storage battery. It comprises: a plurality of positive plates containing about 2 to 4 percent of antimony based upon the total weight of the alloy and positive active material, and essentially antimony free negative plates in a closed case; a fibrous sheet plate separator between adjacent ones of the plates, and a body of an electrolyte to which the sheet separators are inert absorbed by each of the separators and maintained in contact with each of the adjacent ones of the plates. Each of the separator sheets comprising first fibers which impart to the sheet a given absorbency greater than 90 percent relative to the electrolyte and second fibers which impart to the sheet a different absorbency less than 80 percent relative to the electrolyte. The first and second fibers being present in such proportions that each of the sheet separators has an absorbency with respect to the electrolyte of from 75 to 95 percent and the second fibers being present in such proportions that the battery has a recombination rate adequate to compensate for gassing.

  7. Lithium sulfide compositions for battery electrolyte and battery electrode coatings

    DOE Patents [OSTI]

    Liang, Chengdu; Liu, Zengcai; Fu, Wujun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

    2014-10-28T23:59:59.000Z

    Method of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electrolytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

  8. Lithium sulfide compositions for battery electrolyte and battery electrode coatings

    SciTech Connect (OSTI)

    Liang, Chengdu; Liu, Zengcai; Fu, Wunjun; Lin, Zhan; Dudney, Nancy J; Howe, Jane Y; Rondinone, Adam J

    2013-12-03T23:59:59.000Z

    Methods of forming lithium-containing electrolytes are provided using wet chemical synthesis. In some examples, the lithium containing electroytes are composed of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7. The solid electrolyte may be a core shell material. In one embodiment, the core shell material includes a core of lithium sulfide (Li.sub.2S), a first shell of .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7, and a second shell including one or .beta.-Li.sub.3PS.sub.4 or Li.sub.4P.sub.2S.sub.7 and carbon. The lithium containing electrolytes may be incorporated into wet cell batteries or solid state batteries.

  9. University Venture Development Fund Transforming today's research and development into tomorrow's businesses

    E-Print Network [OSTI]

    Bertini, Robert L.

    University Venture Development Fund Transforming today's research and development into tomorrow: University Venture Development Fund P.O. Box 243 Portland, OR 97207 Phone (503) 725-4911 It is highly this process. Thank you for supporting the University Venture Development Fund! PDX_DOCS:401207.2 [33137

  10. 2014 RICE ALLIANCE ENERGY & CLEAN TECHNOLOGY VENTURE FORUM PARTICIPATING SPEAKERS & INVESTORS

    E-Print Network [OSTI]

    2014 RICE ALLIANCE ENERGY & CLEAN TECHNOLOGY VENTURE FORUM PARTICIPATING SPEAKERS & INVESTORS Louis for full-scale commercialization. #12;2014 RICE ALLIANCE ENERGY & CLEAN TECHNOLOGY VENTURE FORUM Albanese Investment Manager Louis Albanese is an investment manager at Saudi Aramco Energy Ventures (SAEV

  11. Negative Electrodes for Li-Ion Batteries

    SciTech Connect (OSTI)

    Kinoshita, Kim; Zaghib, Karim

    2001-10-01T23:59:59.000Z

    Graphitized carbons have played a key role in the successful commercialization of Li-ion batteries. The physicochemical properties of carbon cover a wide range; therefore identifying the optimum active electrode material can be time consuming. The significant physical properties of negative electrodes for Li-ion batteries are summarized, and the relationship of these properties to their electrochemical performance in nonaqueous electrolytes, are discussed in this paper.

  12. Structural phase transition and electrode characteristics of LiMn{sub 2{minus}x}Mg{sub x}O{sub 4} positive electrode material for the lithium secondary battery

    SciTech Connect (OSTI)

    Idemoto, Y.; Udagawa, K.; Koura, N.; Richardson, J. W., Jr.; Takeuchi, K.; Loong, C.-K.

    1999-12-10T23:59:59.000Z

    With in mind improving the cycle performance of 4V class lithium manganese oxide positive electrode material for the lithium secondary battery, the authors have been investigating the effects of partial substitution of Mn by another metal. The crystal phase transition in the quaternary spinel LiMn{sub 2{minus}x}Mg{sub x}O{sub 4} was studied by neutron powder diffraction at 200K and DSC measurements at low temperatures. They find that substituting Mn by Mg resulted in a more stable crystal structure with the Jahn-Teller transition suppressed down to low temperature. The charge-discharge characteristics of these positive electrode active materials were investigated at 4V range. Although the discharge capacity decreased with increasing Mg content, the cycle performance was improved with increasing Mg content.

  13. Highly - conductive cathode for lithium-ion battery using M13 phage - SWCNT complex

    E-Print Network [OSTI]

    Adams, Melanie Chantal

    2013-01-01T23:59:59.000Z

    Lithium-ion batteries are commonly used in portable electronics, and the rapid growth of mobile technology calls for an improvement in battery capabilities. Reducing the particle size of electrode materials in synthesis ...

  14. Improved zinc electrode and rechargeable zinc-air battery

    DOE Patents [OSTI]

    Ross, P.N. Jr.

    1988-06-21T23:59:59.000Z

    The invention comprises an improved rechargeable zinc-air cell/battery having recirculating alkaline electrolyte and a zinc electrode comprising a porous foam support material which carries the active zinc electrode material. 5 figs.

  15. A lithium oxygen secondary battery

    SciTech Connect (OSTI)

    Semkow, K.W.; Sammells, A.F.

    1987-08-01T23:59:59.000Z

    In principle the lithium-oxygen couple should provide one of the highest energy densities yet investigated for advanced battery systems. The problem to this time has been one of identifying strategies for achieving high electrochemical reversibilities at each electrode under conditions where one might anticipate to also achieve long materials lifetimes. This has been addressed in recent work by us via the application of stabilized zirconia oxygen vacancy conducting solid electrolytes, for the effective separation of respective half-cell reactions.

  16. Characterization of New Cathode Materials using Synchrotron-based...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and the Studies of High Energy Density Li-Air Batteries In Situ Characterizations of New Battery Materials and the Studies of High Energy Density Li-Air Batteries Characterization...

  17. The Fabrication of Titanium Dioxide Based Anode Material Using Aerosol Method

    E-Print Network [OSTI]

    Zhao, Lin

    2013-01-01T23:59:59.000Z

    Whittingham, M.S. , Lithium batteries and cathode materials.Whittingham, M.S. , Lithium batteries and cathode materials.applications of lithium secondary batteries. 2012: Wiley-VCH

  18. Sandia National Laboratories: Batteries & Energy Storage Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    StorageBatteries & Energy Storage Publications Batteries & Energy Storage Publications Batteries & Energy Storage Fact Sheets Achieving Higher Energy Density in Flow Batteries at...

  19. Negative Electrodes for Li-Ion Batteries

    E-Print Network [OSTI]

    Kinoshita, Kim; Zaghib, Karim

    2001-01-01T23:59:59.000Z

    on New Sealed Rechargeable Batteries and Supercapacitors, B.10. S. Hossain, in Handbook of Batteries, Second Edition, D.Workshop on Advanced Batteries (Lithium Batteries), February

  20. Design and Simulation of Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Doyle, C.M.

    2010-01-01T23:59:59.000Z

    of a Rechargeable Lithium Battery," J. Power Sources, 24,Wada, "Rechargeable Lithium Battery Based on Pyrolytic Car-Li-Ion Battery," Lithium Battery Symposium, Electrochemical

  1. Flow Battery System Design for Manufacturability.

    SciTech Connect (OSTI)

    Montoya, Tracy Louise; Meacham, Paul Gregory; Perry, David; Broyles, Robin S.; Hickey, Steven; Hernandez, Jacquelynne

    2014-10-01T23:59:59.000Z

    Flow battery energy storage systems can support renewable energy generation and increase energy efficiency. But, presently, the costs of flow battery energy storage systems can be a significant barrier for large-scale market penetration. For cost- effective systems to be produced, it is critical to optimize the selection of materials and components simultaneously with the adherence to requirements and manufacturing processes to allow these batteries and their manufacturers to succeed in the market by reducing costs to consumers. This report analyzes performance, safety, and testing requirements derived from applicable regulations as well as commercial and military standards that would apply to a flow battery energy storage system. System components of a zinc-bromine flow battery energy storage system, including the batteries, inverters, and control and monitoring system, are discussed relative to manufacturing. The issues addressed include costs and component availability and lead times. A service and support model including setup, maintenance and transportation is outlined, along with a description of the safety-related features of the example flow battery energy storage system to promote regulatory and environmental, safety, and health compliance in anticipation of scale manufacturing.

  2. Critical Materials Strategy Summary

    Broader source: Energy.gov (indexed) [DOE]

    in magnets, batteries, photovoltaic films and phosphors; environmentally sound mining and materials processing; and recycling. The eight programs and policies address...

  3. Lithium transition metal fluorophosphates (Li{sub 2}CoPO{sub 4}F and Li{sub 2}NiPO{sub 4}F) as cathode materials for lithium ion battery from atomistic simulation

    SciTech Connect (OSTI)

    Lee, Sanghun, E-mail: sh0129.lee@samsung.com; Park, Sung Soo, E-mail: sung.s.park@samsung.com

    2013-08-15T23:59:59.000Z

    Lithium transition metal fluorophosphates (Li{sub 2}MPO{sub 4}F, M: Co and Ni) have been investigated from atomistic simulation. In order to predict the characteristics of these materials as cathode materials for lithium ion batteries, structural property, defect chemistry, and Li{sup +} ion transportation property are characterized. The core–shell model with empirical force fields is employed to reproduce the unit-cell parameters of crystal structure, which are in good agreement with the experimental data. In addition, the formation energies of intrinsic defects (Frenkel and antisite) are determined by energetics calculation. From migration energy calculations, it is found that these flurophosphates have a 3D Li{sup +} ion diffusion network forecasting good Li{sup +} ion conducting performances. Accordingly, we expect that this study provides an atomic scale insight as cathode materials for lithium ion batteries. - Graphical abstract: Lithium transition metal fluorophosphates (Li{sub 2}CoPO{sub 4}F and Li{sub 2}NiPO{sub 4}F). Display Omitted - Highlights: • Lithium transition metal fluorophosphates (Li{sub 2}MPO{sub 4}F, M: Co and Ni) are investigated from classical atomistic simulation. • The unit-cell parameters from experimental studies are reproduced by the core–shell model. • Li{sup +} ion conducting Li{sub 2}MPO{sub 4}F has a 3D Li{sup +} ion diffusion network. • It is predicted that Li/Co or Li/Ni antisite defects are well-formed at a substantial concentration level.

  4. A review of battery life-cycle analysis : state of knowledge and critical needs.

    SciTech Connect (OSTI)

    Sullivan, J. L.; Gaines, L.; Energy Systems

    2010-12-22T23:59:59.000Z

    A literature review and evaluation has been conducted on cradle-to-gate life-cycle inventory studies of lead-acid, nickel-cadmium, nickel-metal hydride, sodium-sulfur, and lithium-ion battery technologies. Data were sought that represent the production of battery constituent materials and battery manufacture and assembly. Life-cycle production data for many battery materials are available and usable, though some need updating. For the remaining battery materials, lifecycle data either are nonexistent or, in some cases, in need of updating. Although battery manufacturing processes have occasionally been well described, detailed quantitative information on energy and material flows is missing. For all but the lithium-ion batteries, enough constituent material production energy data are available to approximate material production energies for the batteries, though improved input data for some materials are needed. Due to the potential benefit of battery recycling and a scarcity of associated data, there is a critical need for life-cycle data on battery material recycling. Either on a per kilogram or per watt-hour capacity basis, lead-acid batteries have the lowest production energy, carbon dioxide emissions, and criteria pollutant emissions. Some process-related emissions are also reviewed in this report.

  5. 1992 five year battery forecast

    SciTech Connect (OSTI)

    Amistadi, D.

    1992-12-01T23:59:59.000Z

    Five-year trends for automotive and industrial batteries are projected. Topic covered include: SLI shipments; lead consumption; automotive batteries (5-year annual growth rates); industrial batteries (standby power and motive power); estimated average battery life by area/country for 1989; US motor vehicle registrations; replacement battery shipments; potential lead consumption in electric vehicles; BCI recycling rates for lead-acid batteries; US average car/light truck battery life; channels of distribution; replacement battery inventory end July; 2nd US battery shipment forecast.

  6. Costs of lithium-ion batteries for vehicles

    SciTech Connect (OSTI)

    Gaines, L.; Cuenca, R.

    2000-08-21T23:59:59.000Z

    One of the most promising battery types under development for use in both pure electric and hybrid electric vehicles is the lithium-ion battery. These batteries are well on their way to meeting the challenging technical goals that have been set for vehicle batteries. However, they are still far from achieving the current cost goals. The Center for Transportation Research at Argonne National Laboratory undertook a project for the US Department of Energy to estimate the costs of lithium-ion batteries and to project how these costs might change over time, with the aid of research and development. Cost reductions could be expected as the result of material substitution, economies of scale in production, design improvements, and/or development of new material supplies. The most significant contributions to costs are found to be associated with battery materials. For the pure electric vehicle, the battery cost exceeds the cost goal of the US Advanced Battery Consortium by about $3,500, which is certainly enough to significantly affect the marketability of the vehicle. For the hybrid, however, the total cost of the battery is much smaller, exceeding the cost goal of the Partnership for a New Generation of Vehicles by only about $800, perhaps not enough to deter a potential buyer from purchasing the power-assist hybrid.

  7. High-energy metal air batteries

    DOE Patents [OSTI]

    Zhang, Ji-Guang; Xiao, Jie; Xu, Wu; Wang, Deyu; Williford, Ralph E.; Liu, Jun

    2013-07-09T23:59:59.000Z

    Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.

  8. High-energy metal air batteries

    DOE Patents [OSTI]

    Zhang, Ji-Guang; Xiao, Jie; Xu, Wu; Wang, Deyu; Williford, Ralph E.; Liu, Jun

    2014-07-01T23:59:59.000Z

    Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.

  9. Remote Control Inserting the batteries

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    Top View Rear View Inserting the batteries 1 3Press in on the arrow mark and slide in the direction of the arrow to remove the battery cover. 2 Insert two AA size batteries, making sure their polarities match the and marks inside the battery compartment. Insert the side tabs of the battery cover into their slots

  10. Recombination device for storage batteries

    DOE Patents [OSTI]

    Kraft, Helmut (Liederbach, DE); Ledjeff, Konstantin (Bad Krozingen, DE)

    1985-01-01T23:59:59.000Z

    A recombination device including a gas-tight enclosure connected to receive he discharge gases from a rechargeable storage battery. Catalytic material for the recombination of hydrogen and oxygen to form water is supported within the enclosure. The enclosure is sealed from the atmosphere by a liquid seal including two vertical chambers interconnected with an inverted U-shaped overflow tube. The first chamber is connected at its upper portion to the enclosure and the second chamber communicates at its upper portion with the atmosphere. If the pressure within the enclosure differs as overpressure or vacuum by more than the liquid level, the liquid is forced into one of the two chambers and the overpressure is vented or the vacuum is relieved. The recombination device also includes means for returning recombined liquid to the battery and for absorbing metal hydrides.

  11. Recombination device for storage batteries

    DOE Patents [OSTI]

    Kraft, H.; Ledjeff, K.

    1984-01-01T23:59:59.000Z

    A recombination device including a gas-tight enclosure connected to receive the discharge gases from a rechargeable storage battery. Catalytic material for the recombination of hydrogen and oxygen to form water is supported within the enclosure. The enclosure is sealed from the atmosphere by a liquid seal including two vertical chambers interconnected with an inverted U-shaped overflow tube. The first chamber is connected at its upper portion to the enclosure and the second chamber communicates at its upper portion with the atmosphere. If the pressure within the enclosure differs as overpressure or vacuum by more than the liquid level, the liquid is forced into one of the two chambers and the overpressure is vented or the vacuum is relieved. The recombination device also includes means for returning recombined liquid to the battery and for absorbing metal hydrides.

  12. Electrochemical performance of polyaniline coated LiMn{sub 2}O{sub 4} cathode active material for lithium ion batteries

    SciTech Connect (OSTI)

    ?ahan, Halil, E-mail: halil@erciyes.edu.tr; Dokan, Fatma K?l?c, E-mail: halil@erciyes.edu.tr; Ayd?n, Abdülhamit, E-mail: halil@erciyes.edu.tr; Özdemir, Burcu, E-mail: halil@erciyes.edu.tr; Özdemir, Nazl?, E-mail: halil@erciyes.edu.tr; Patat, ?aban, E-mail: halil@erciyes.edu.tr [Department of Chemistry, Science Faculty, Erciyes University, Kayseri, 38039 (Turkey)

    2013-12-16T23:59:59.000Z

    LiMn{sub 2}O{sub 4} compound are synthesized by combustion method using glycine as a fuel at temperature (T), 800°C which was coated by a polyaniline. The goal of this procedure is to promote better electronic conductivity of the LiMn{sub 2}O{sub 4} particles in order to improve their electrochemical performance for their application as cathodes in secondary lithium ion batteries. The structures of prepared products have been investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). To investigate the effect of polyaniline coating galvanostatic charge-discharge cycling (148 mA g{sup ?1}) studies are made in the voltage range of 3.5-4.5 V vs. Li at room temperature. Electrochemical performance of the LiMn{sub 2}O{sub 4} was significantly improved by the polaniline coating.

  13. Lithium battery management system

    DOE Patents [OSTI]

    Dougherty, Thomas J. (Waukesha, WI)

    2012-05-08T23:59:59.000Z

    Provided is a system for managing a lithium battery system having a plurality of cells. The battery system comprises a variable-resistance element electrically connected to a cell and located proximate a portion of the cell; and a device for determining, utilizing the variable-resistance element, whether the temperature of the cell has exceeded a predetermined threshold. A method of managing the temperature of a lithium battery system is also included.

  14. Material Challenges and Perspectives

    SciTech Connect (OSTI)

    Choi, Daiwon; Wang, Wei; Yang, Zhenguo

    2011-12-14T23:59:59.000Z

    General history and principals of Li-ion battery, characterization techniques and terminology of its operation will be discussed and explained. Current Li-ion battery applications and comparison to other energy storage and conversion systems will be outlined. Chemistry, material and design of currently commercialized Li-ion batteries will be discussed including various electrode materials for cathodes and anodes. The electrode material candidates and its physical and chemical properties including crystal structure, capacity, cycling stability, cost and safety. Also, current limitations of Li-ion batteries will be discussed.

  15. Better Battery Performance | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for the practical application of several high-energy-density battery systems for powering electric vehicles and storing renewable energy on the grid. Summary Researchers from the...

  16. Boosting batteries | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    way for widespread adoption of lithium ion batteries for applications such as powering electric vehicles and storing renewable energy on the grid. The Science Rechargeable...

  17. Battery Safety Testing

    Broader source: Energy.gov (indexed) [DOE]

    Battery Safety Testing Christopher J. Orendorff, Leigh Anna M. Steele, Josh Lamb, and Scott Spangler Sandia National Laboratories 2014 Energy Storage Annual Merit Review...

  18. Ion implantation of highly corrosive electrolyte battery components

    DOE Patents [OSTI]

    Muller, R.H.; Zhang, S.

    1997-01-14T23:59:59.000Z

    A method of producing corrosion resistant electrodes and other surfaces in corrosive batteries using ion implantation is described. Solid electrically conductive material is used as the ion implantation source. Battery electrode grids, especially anode grids, can be produced with greatly increased corrosion resistance for use in lead acid, molten salt, and sodium sulfur. 6 figs.

  19. Ion implantation of highly corrosive electrolyte battery components

    DOE Patents [OSTI]

    Muller, Rolf H. (Berkeley, CA); Zhang, Shengtao (Berkeley, CA)

    1997-01-01T23:59:59.000Z

    A method of producing corrosion resistant electrodes and other surfaces in corrosive batteries using ion implantation is described. Solid electrically conductive material is used as the ion implantation source. Battery electrode grids, especially anode grids, can be produced with greatly increased corrosion resistance for use in lead acid, molten salt, end sodium sulfur.

  20. OUT Success Stories: Battery Electricity Storage for Quality Power

    SciTech Connect (OSTI)

    Recca, L.

    2000-08-31T23:59:59.000Z

    A 3.5-megawatt valve-regulated lead-acid (VRLA) battery system installed at a lead recycling plant in California provides one hour of energy storage for both peak-shaving and uninterruptible power. It incorporates improvements in battery materials, manufacturing processes, and quality control.

  1. Redox Flow Batteries, a Review

    E-Print Network [OSTI]

    Weber, Adam Z.

    2013-01-01T23:59:59.000Z

    P. C. Butler, "Advanced Batteries for Electric Vehicles andIntroduction," in Hnadbook of Batteries, 3rd Edition, D.T. B. Reddy, Handbook of Batteries, 2002). [67] R. Zito, US

  2. Breakthrough Flow Battery Cell Stack: Transformative Electrochemical Flow Storage System (TEFSS)

    SciTech Connect (OSTI)

    None

    2010-09-09T23:59:59.000Z

    GRIDS Project: UTRC is developing a flow battery with a unique design that provides significantly more power than today's flow battery systems. A flow battery is a cross between a traditional battery and a fuel cell. Flow batteries store their energy in external tanks instead of inside the cell itself. Flow batteries have traditionally been expensive because the battery cell stack, where the chemical reaction takes place, is costly. In this project, UTRC is developing a new stack design that achieves 10 times higher power than today’s flow batteries. This high power output means the size of the cell stack can be smaller, reducing the amount of expensive materials that are needed. UTRC’s flow battery will reduce the cost of storing electricity for the electric grid, making widespread use feasible.

  3. 2012 Jonathan G. Lange IMPROVING LITHIUM-ION BATTERY POWER AND ENERGY DENSITIES USING

    E-Print Network [OSTI]

    Braun, Paul

    1 ©2012 Jonathan G. Lange #12;1 IMPROVING LITHIUM-ION BATTERY POWER AND ENERGY DENSITIES USING ABSTRACT Lithium-ion batteries are commonly used as energy storage devices in a variety of applications. The cathode architectures and materials have a large influence on the performance of lithium-ion batteries

  4. Efficient Reformulation of Solid-Phase Diffusion in Physics-Based Lithium-Ion Battery Models

    E-Print Network [OSTI]

    Subramanian, Venkat

    Efficient Reformulation of Solid-Phase Diffusion in Physics-Based Lithium-Ion Battery Models, Berkeley, California 94720-8168, USA Lithium-ion batteries are typically modeled using porous electrode the active materials of porous electrodes for a pseudo-two- dimensional model for lithium-ion batteries

  5. Efficient Reformulation of Solid-Phase Diffusion in Physics-Based Lithium-Ion Battery Models

    E-Print Network [OSTI]

    Subramanian, Venkat

    Efficient Reformulation of Solid-Phase Diffusion in Physics-Based Lithium-Ion Battery Models materials of porous electrodes for a rigorous pseudo-2D model for lithium-ion batteries. Concentration-ion battery models is the inclusion of solid phase diffusion in a second dimension r. It increases

  6. Porous Doped Silicon Nanowires for Lithium Ion Battery Anode with Long Cycle Life

    E-Print Network [OSTI]

    Zhou, Chongwu

    Porous Doped Silicon Nanowires for Lithium Ion Battery Anode with Long Cycle Life Mingyuan Ge material in a lithium ion battery. Even after 250 cycles, the capacity remains stable above 2000, 1600 in energy storage has stimulated significant interest in lithium ion battery research. The lithium ion

  7. Biologically Activated Noble Metal Alloys at the Nanoscale: For Lithium Ion Battery

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Biologically Activated Noble Metal Alloys at the Nanoscale: For Lithium Ion Battery Anodes Yun Jung as anode materials for lithium ion batteries. Using two clones, one for specificity (p8#9 virus) and one choice for lithium ion batteries, these noble metal/alloy nanowires serve as great model systems to study

  8. Effect of Sn and Ca doping on the corrosion of Pb anodes in lead acid batteries

    E-Print Network [OSTI]

    Popov, Branko N.

    Effect of Sn and Ca doping on the corrosion of Pb anodes in lead acid batteries Dragan Slavkova of lead anodes used in lead acid batteries. However, one drawback of these materials is their increased reserved. Keywords: Corrosion; Pb anodes; Lead acid batteries; Doping tin; Calcium 1. Introduction

  9. Crab Shells as Sustainable Templates from Nature for Nanostructured Battery Electrodes

    E-Print Network [OSTI]

    Cui, Yi

    electrodes is four times that of existing LiCoO2/graphite batteries.3-5 However, lithium reactsCrab Shells as Sustainable Templates from Nature for Nanostructured Battery Electrodes Hongbin Yao materials issues for enabling next-generation high capacity lithium ion batteries for portable electronics

  10. Thermal conductivity of thermal-battery insulations

    SciTech Connect (OSTI)

    Guidotti, R.A.; Moss, M.

    1995-08-01T23:59:59.000Z

    The thermal conductivities of a variety of insulating materials used in thermal batteries were measured in atmospheres of argon and helium using several techniques. (Helium was used to simulate the hydrogen atmosphere that results when a Li(Si)/FeS{sub 2} thermal battery ages.) The guarded-hot-plate method was used with the Min-K insulation because of its extremely low thermal conductivity. For comparison purposes, the thermal conductivity of the Min-K insulating board was also measured using the hot-probe method. The thermal-comparator method was used for the rigid Fiberfrax board and Fiberfrax paper. The thermal conductivity of the paper was measured under several levels of compression to simulate the conditions of the insulating wrap used on the stack in a thermal battery. The results of preliminary thermal-characterization tests with several silica aerogel materials are also presented.

  11. Servant dictionary battery, map

    E-Print Network [OSTI]

    Rosenthal, Jeffrey S.

    Attic *** book teachest Servant dictionary scarf [11] Winery demijohn battery, map AuntLair X Cupboard1 wireless Potting gloves aunt[3] Storage dumbwaiter wrench OldFurn parcel, med whistle Over] EastAnnex battery[4] Cupboard2 [2] mask DeadEnd rucksack AlisonWriting [16] TinyBalcony [17] gold key

  12. battery, map parcel, med

    E-Print Network [OSTI]

    Rosenthal, Jeffrey S.

    Attic *** book teachest Servant dictionary scarf [11] Winery demijohn battery, map AuntLair X Cupboard1 wireless Potting gloves aunt[3] Storage dumbwaiter wrench OldFurn parcel, med whistle Over] EastAnnex battery[4] Cupboard2 [2] mask DeadEnd rucksack AlisonWriting [16] TinyBalcony [17] gold key

  13. Facile synthesis of mesophase pitch/exfoliated graphite nanoplatelets nanocomposite and its application as anode materials for lithium-ion batteries

    SciTech Connect (OSTI)

    Yang Yishuang [Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); Wang Chengyang, E-mail: cywang@tju.edu.c [Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); Chen Mingming; Shi Zhiqiang; Zheng Jiaming [Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China)

    2010-09-15T23:59:59.000Z

    Mesophase pitch (MP)/exfoliated graphite nanoplatelets (GNPs) nanocomposite has been prepared by an efficient method with an initiation of graphite intercalation compounds (GIC). X-ray diffraction, optical microscopy, high-resolution transmission electron microscopy and scanning electron microscopy analysis techniques are used to characterize the samples. It is observed that GIC has exfoliated completely into GNPs during the formation of MP/GNPs nanocomposite and the GNPs are distributed uniformly in MP matrix, which represent a conductive path for a movement of electrons throughout the composites. Electrochemical tests demonstrate that the carbonized MP/GNPs nanocomposite displays higher capacity and better cycle performance in comparison with the pure carbonized MP. It is concluded that such a large improvement of electrochemical performance within the nanocomposite may in general be related to the enhanced electronic conductivity, which is achieved by good dispersion of GNPs within MP matrix and formation of a 3D network of GNPs. - Graphical abstract: Uniform mesophase pitch/exfoliated graphite nanoplatelets nanocomposite has been efficiently fabricated with an initiation of graphite intercalation compounds. The as-prepared composite electrode exhibited high electrochemical performance for Li-ion batteries.

  14. Effect of fuel rate and annealing process of LiFePO{sub 4} cathode material for Li-ion batteries synthesized by flame spray pyrolysis method

    SciTech Connect (OSTI)

    Halim, Abdul; Setyawan, Heru; Machmudah, Siti; Nurtono, Tantular; Winardi, Sugeng [Chemical Engineering, Sepuluh Nopember Institute of Technology, Kampus Sukolilo Surabaya Indonesia 60111 (Indonesia)

    2014-02-24T23:59:59.000Z

    In this study the effect of fuel rate and annealing on particle formation of LiFePO{sub 4} as battery cathode using flame spray pyrolysis method was investigated numerically and experimentally. Numerical study was done using ANSYS FLUENT program. In experimentally, LiFePO{sub 4} was synthesized from inorganic aqueous solution followed by annealing. LPG was used as fuel and air was used as oxidizer and carrier gas. Annealing process attempted in inert atmosphere at 700°C for 240 min. Numerical result showed that the increase of fuel rate caused the increase of flame temperature. Microscopic observation using Scanning Electron Microscopy (SEM) revealed that all particles have sphere and polydisperse. Increasing fuel rate caused decreasing particle size and increasing particles crystallinity. This phenomenon attributed to the flame temperature. However, all produced particles still have more amorphous phase. Therefore, annealing needed to increase particles crystallinity. Fourier Transform Infrared (FTIR) analysis showed that all particles have PO4 function group. Increasing fuel rate led to the increase of infrared spectrum absorption corresponding to the increase of particles crystallinity. This result indicated that phosphate group vibrated easily in crystalline phase. From Electrochemical Impedance Spectroscopy (EIS) analysis, annealing can cause the increase of Li{sup +} diffusivity. The diffusivity coefficient of without and with annealing particles were 6.84399×10{sup ?10} and 8.59888×10{sup ?10} cm{sup 2} s{sup ?1}, respectively.

  15. Methods and systems for thermodynamic evaluation of battery state of health

    DOE Patents [OSTI]

    Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T

    2014-12-02T23:59:59.000Z

    Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.

  16. Mixed Polyanion Glasses for Lithium Ion Battery Cathodes | ornl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mixed Polyanion Glasses for Lithium Ion Battery Cathodes May 06 2015 09:30 AM - 10:30 AM Andrew K. Kercher, Division Staff Materials Science and Technology Division Seminar...

  17. Overview of the Batteries for Advanced Transportation Technologies...

    Broader source: Energy.gov (indexed) [DOE]

    of lithium intercalation and may hold the key to high-energy T. Richardson and G. Chen (LBNL) batteries T. Richardson and G. Chen (LBNL) Material Modifications on the Nanoscale L...

  18. Developments in lithium-ion battery technology in the Peoples Republic of China.

    SciTech Connect (OSTI)

    Patil, P. G.; Energy Systems

    2008-02-28T23:59:59.000Z

    Argonne National Laboratory prepared this report, under the sponsorship of the Office of Vehicle Technologies (OVT) of the U.S. Department of Energy's (DOE's) Office of Energy Efficiency and Renewable Energy, for the Vehicles Technologies Team. The information in the report is based on the author's visit to Beijing; Tianjin; and Shanghai, China, to meet with representatives from several organizations (listed in Appendix A) developing and manufacturing lithium-ion battery technology for cell phones and electronics, electric bikes, and electric and hybrid vehicle applications. The purpose of the visit was to assess the status of lithium-ion battery technology in China and to determine if lithium-ion batteries produced in China are available for benchmarking in the United States. With benchmarking, DOE and the U.S. battery development industry would be able to understand the status of the battery technology, which would enable the industry to formulate a long-term research and development program. This report also describes the state of lithium-ion battery technology in the United States, provides information on joint ventures, and includes information on government incentives and policies in the Peoples Republic of China (PRC).

  19. Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries

    E-Print Network [OSTI]

    Zhu, Jianxin

    2014-01-01T23:59:59.000Z

    ion batteries In current lithium ion battery technology,ion batteries The first commercialized lithium-ion batteryfirst lithium-ion battery. Compared to the other batteries,

  20. BEEST: Electric Vehicle Batteries

    SciTech Connect (OSTI)

    None

    2010-07-01T23:59:59.000Z

    BEEST Project: The U.S. spends nearly a $1 billion per day to import petroleum, but we need dramatically better batteries for electric and plug-in hybrid vehicles (EV/PHEV) to truly compete with gasoline-powered cars. The 10 projects in ARPA-E’s BEEST Project, short for “Batteries for Electrical Energy Storage in Transportation,” could make that happen by developing a variety of rechargeable battery technologies that would enable EV/PHEVs to meet or beat the price and performance of gasoline-powered cars, and enable mass production of electric vehicles that people will be excited to drive.

  1. CNEEC - Batteries Tutorial by Prof. Cui

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Batteries BatteriesCAES HomeMaterials

  2. CNEEC - Batteries Tutorial by Prof. Cui

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Batteries BatteriesCAES HomeMaterialsComputational

  3. Lightweight, durable lead-acid batteries

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar (Lenoir City, TN); An, Ke (Knoxville, TX); Kiggans, Jr., James O. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Contescu, Cristian I. (Knoxville, TN); Baker, Frederick S. (Oak Ridge, TN); Armstrong, Beth L. (Clinton, TN)

    2011-09-13T23:59:59.000Z

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  4. Lightweight, durable lead-acid batteries

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar; An, Ke; Kiggans, Jr., James O; Dudney, Nancy J; Contescu, Cristian I; Baker, Frederick S; Armstrong, Beth L

    2013-05-21T23:59:59.000Z

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  5. Rechargeable Lithium-Air Batteries: Development of Ultra High Specific Energy Rechargeable Lithium-Air Batteries Based on Protected Lithium Metal Electrodes

    SciTech Connect (OSTI)

    None

    2010-07-01T23:59:59.000Z

    BEEST Project: PolyPlus is developing the world’s first commercially available rechargeable lithium-air (Li-Air) battery. Li-Air batteries are better than the Li-Ion batteries used in most EVs today because they breathe in air from the atmosphere for use as an active material in the battery, which greatly decreases its weight. Li-Air batteries also store nearly 700% as much energy as traditional Li-Ion batteries. A lighter battery would improve the range of EVs dramatically. Polyplus is on track to making a critical breakthrough: the first manufacturable protective membrane between its lithium–based negative electrode and the reaction chamber where it reacts with oxygen from the air. This gives the battery the unique ability to recharge by moving lithium in and out of the battery’s reaction chamber for storage until the battery needs to discharge once again. Until now, engineers had been unable to create the complex packaging and air-breathing components required to turn Li-Air batteries into rechargeable systems.

  6. SOLAR BATTERY CHARGERS FOR NIMH BATTERIES1 Abstract -This paper proposes new solar battery

    E-Print Network [OSTI]

    Lehman, Brad

    SOLAR BATTERY CHARGERS FOR NIMH BATTERIES1 Abstract - This paper proposes new solar battery chargers for NiMH batteries. Used with portable solar panels, existing charge control methods are shown of consumer portable solar arrays. These new arrays are lightweight, durable, and flexible and have been

  7. Selection of a Wear-Resistant Tractor Drivetrain Material: Success...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stories from the High Temperature Materials Laboratory (HTML) User Program Advanced Battery Materials Characterization: Success stories from the High Temperature Materials...

  8. WindPole Ventures LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTown ofNationwideWTEDBird,Wilsonville, Oregon:WindPole Ventures LLC Jump to:

  9. Lab announces selection of partner for venture acceleration initiative

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home asLCLS Experimental RunProcedureofUWVoluntaryLabVenture

  10. Lab announces selection of Venture Acceleration Fund recipients

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 - -/e),,s -Lab Subcontractoractive inVenture

  11. Five companies received funding through new venture acceleration fund

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.New MexicoFinancingProof ofofDownloadsNew venture acceleration

  12. Emergent Ventures India Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model,DOEHazel Crest,Energy Information ElkhornElwood,EmcoreEmergent Ventures India

  13. Alvan Blanch Green Fuels joint venture | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTriWildcat Place:Alvan Blanch Green Fuels joint venture Jump to:

  14. I Sol Ventures GmbH | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup | OpenHunan Runhua New Energy DevelopmentListI Sol Ventures GmbH Jump

  15. IFCI Venture Capital Funds Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup | OpenHunan Runhua New Energy DevelopmentListIIFCI Venture Capital Funds

  16. Ten local businesses to receive Venture Acceleration Fund awards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesis of 2D AlloysTrails Howtemplates 36 inchVenture

  17. Method of assembling and sealing an alkali metal battery

    DOE Patents [OSTI]

    Elkins, P.E.; Bell, J.E.; Harlow, R.A.; Chase, G.G.

    1983-03-01T23:59:59.000Z

    A method of initially assembling and then subsequently hermetically sealing a container portion of an alkali metal battery to a ceramic portion of such a battery is disclosed. Sealing surfaces are formed respectively on a container portion and a ceramic portion of an alkali metal battery. These sealing surfaces are brought into juxtaposition and a material is interposed there between. This interposed material is one which will diffuse into sealing relationship with both the container portion and the ceramic portion of the alkali metal battery at operational temperatures of such a battery. A pressure is applied between these sealing surfaces to cause the interposed material to be brought into intimate physical contact with such juxtaposed surfaces. A temporary sealing material which will provide a seal against a flow of alkali metal battery reactants there through at room temperatures and is applied over the juxtaposed sealing surfaces and material interposed there between. The entire assembly is heated to an operational temperature so that the interposed material diffuses into the container portion and the ceramic portion to form a hermetic seal there between. The pressure applied to the juxtaposed sealing surfaces is maintained in order to ensure the continuation of the hermetic seal. 4 figs.

  18. Advanced Flow Battery Electrodes: Low-cost, High-Performance 50-Year Electrode

    SciTech Connect (OSTI)

    None

    2010-09-01T23:59:59.000Z

    GRIDS Project: Primus Power is developing zinc-based, rechargeable liquid flow batteries that could produce substantially more energy at lower cost than conventional batteries. A flow battery is similar to a conventional battery, except instead of storing its energy inside the cell it stores that energy for future use in chemicals that are kept in tanks that sit outside the cell. One of the most costly components in a flow battery is the electrode, where the electrochemical reactions actually occur. Primus Power is investigating and developing mixed-metal materials for their electrodes that could ultimately reduce the lifetime cost of flow batteries because they are more durable and long-lasting than electrodes found in traditional batteries. Using these electrodes, Primus Power’s flow batteries can be grouped together into robust, containerized storage pods for use by utilities, renewable energy developers, businesses, and campuses.

  19. Nanostructured Electrode Materials for Supercapacitors

    E-Print Network [OSTI]

    Wu, Shin-Tson

    and batteries/fuel cells. Nanostructured electrode materials have demonstrated superior electrochemical of polymethine dyes electronic spectra is crucial for successful design of the new molecules with optimized

  20. A Look Inside SLAC's Battery Lab

    SciTech Connect (OSTI)

    Wei Seh, Zhi

    2014-07-17T23:59:59.000Z

    In this video, Stanford materials science and engineering graduate student Zhi Wei Seh shows how he prepares battery materials in SLAC's energy storage laboratory, assembles dime-sized prototype "coin cells" and then tests them to see how many charge-discharge cycles they can endure without losing their ability to hold a charge. Results to date have already set records: After 1,000 cycles, they retain 70 percent of their original charge.

  1. A Look Inside SLAC's Battery Lab

    ScienceCinema (OSTI)

    Wei Seh, Zhi

    2014-07-21T23:59:59.000Z

    In this video, Stanford materials science and engineering graduate student Zhi Wei Seh shows how he prepares battery materials in SLAC's energy storage laboratory, assembles dime-sized prototype "coin cells" and then tests them to see how many charge-discharge cycles they can endure without losing their ability to hold a charge. Results to date have already set records: After 1,000 cycles, they retain 70 percent of their original charge.

  2. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone...

  3. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01T23:59:59.000Z

    Anodes for Aluminum-Air Batteries. J. Electrochem. Soc.Anodes for Aluminum-Air Batteries. J. Electrochem. Soc.ALLOYS FOR ALUMINUM AIR BATTERIES. J. Electrochem. Soc.

  4. Design and Simulation of Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Doyle, C.M.

    2010-01-01T23:59:59.000Z

    Gabano, Ed. , Lithium Batteries, Academic Press, New York,K. V. Kordesch, "Primary Batteries 1951-1976," J. Elec- n ~.Rechargeable Lithium Batteries," J. Electrochem. Soc. , [20

  5. Ionic liquids for rechargeable lithium batteries

    E-Print Network [OSTI]

    Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz, John; Newman, John

    2008-01-01T23:59:59.000Z

    their use in lithium-ion batteries. However, applications atresponse of lithium rechargeable batteries,” Journal of therechargeable lithium batteries (Preliminary report, Sept.

  6. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca

    2014-01-01T23:59:59.000Z

    Company-v3832/Lithium-Ion-Batteries- Outlook-Alternative-Anodes for Sodium Ion Batteries Marca M. Doeff * , Jordirechargeable sodium ion batteries, particularly for large-

  7. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    Secondary Lithium Batteries. Journal of the Electrochemicalin Rechargeable Lithium Batteries for Overcharge Protection.G. M. in Handbook of Batteries (eds Linden, D. & Reddy, T.

  8. Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer, Longer-lasting Batteries Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer,...

  9. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    Anodes for Sodium Ion Batteries Identification of a suitabledevelopment of sodium ion batteries, because graphite, theanode for lithium ion batteries, does not undergo sodium

  10. Sodium Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    for  Sodium  Ion  Batteries   One   of   the   challenges  of   sodium   ion   batteries   is   identification   of  for   use   in   batteries.   Our   recent   work   has  

  11. Sodium Titanate Anodes for Dual Intercalation Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    for Dual Intercalation Batteries Lithium supply securityinterest in sodium-ion batteries. These devices operate muchsodium-ion or lithium-ion batteries that utilize them as

  12. Block copolymer electrolytes for lithium batteries

    E-Print Network [OSTI]

    Hudson, William Rodgers

    2011-01-01T23:59:59.000Z

    K. M. Directions in secondary lithium battery research-and-runaway inhibitors for lithium battery electrolytes. Journalrunaway inhibitors for lithium battery electrolytes. Journal

  13. Lithium Metal Anodes for Rechargeable Batteries. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Anodes for Rechargeable Batteries. Lithium Metal Anodes for Rechargeable Batteries. Abstract: Rechargeable lithium metal batteries have much higher energy density than those...

  14. Design and Simulation of Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Doyle, C.M.

    2010-01-01T23:59:59.000Z

    J. -P. Gabano, Ed. , Lithium Batteries, Academic Press, Newfor Rechargeable Lithium Batteries," J. Electrochem.for Rechargeable Lithium Batteries," J. Electroclzern.

  15. Ionic liquids for rechargeable lithium batteries

    E-Print Network [OSTI]

    Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz, John; Newman, John

    2008-01-01T23:59:59.000Z

    for rechargeable lithium batteries (Preliminary report,applications using lithium batteries, we must be sure thattemperature range. For lithium batteries in hybrid vehicles,

  16. Advances in lithium-ion batteries

    E-Print Network [OSTI]

    Kerr, John B.

    2003-01-01T23:59:59.000Z

    Advances in Lithium-Ion Batteries Edited by Walter A. vanpuzzling mysteries of lithium ion batteries. The book beginssuch importance to lithium ion batteries one is amazed that

  17. Better Battery Performance | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the study could pave the way for the practical application of several high-energy-density battery systems for powering electric vehicles and storing renewable energy on the grid....

  18. Parallel flow diffusion battery

    DOE Patents [OSTI]

    Yeh, H.C.; Cheng, Y.S.

    1984-01-01T23:59:59.000Z

    A parallel flow diffusion battery for determining the mass distribution of an aerosol has a plurality of diffusion cells mounted in parallel to an aerosol stream, each diffusion cell including a stack of mesh wire screens of different density.

  19. Battery Charger Efficiency

    Office of Environmental Management (EM)

    Marine Battery Banks don't look like power tools Marine and RV Chargers Differ from Automotive Chargers * The core strategy in the CEC standard is to shut down the charger when...

  20. Battery packaging - Technology review

    SciTech Connect (OSTI)

    Maiser, Eric [The German Engineering Federation (VDMA), Battery Production Industry Group, Lyoner Str. 18, 60528 Frankfurt am Main (Germany)

    2014-06-16T23:59:59.000Z

    This paper gives a brief overview of battery packaging concepts, their specific advantages and drawbacks, as well as the importance of packaging for performance and cost. Production processes, scaling and automation are discussed in detail to reveal opportunities for cost reduction. Module standardization as an additional path to drive down cost is introduced. A comparison to electronics and photovoltaics production shows 'lessons learned' in those related industries and how they can accelerate learning curves in battery production.

  1. Battery SEAB Presentation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureComments fromofBatteries from Brine Batteries from

  2. Strategic alliance announcements and new venture stock market returns: signaling and resource-based perspectives on the effects of partner firm, new venture firm, and alliance characteristics 

    E-Print Network [OSTI]

    Holmes Jr, Robert Michael

    2009-05-15T23:59:59.000Z

    Firms form marketing and technology alliances to access other firms’ resources, and these alliances act as signals to investors. Investors use these signals to adjust expectations about new venture performance prospects, but our understanding...

  3. Trends in U.S. Venture Capital Investments Related to Energy: 1980-2007

    SciTech Connect (OSTI)

    Dooley, James J.

    2008-10-10T23:59:59.000Z

    This report documents trends in U.S. venture capital investments over the period 1980-2008. Particular attention is given to U.S. venture capital investments for “internet-specific”, biotechnology, and energy / industrial sectors over the period 1980-2007. During the early 1980s, U.S. venture capital investments in the energy / industrial area accounted for more than 20% of all venture capital investments. However subsequent periods of low energy prices and the emergence of fast growing new industries like computers (both hardware and software), biotechnology and the Internet quickly reduced the priority accorded to energy / industrial investments as by 2000 these investments accounted for only 1% of the $119 billion dollars invested that year by the U.S. venture capital community. The significant increase in the real price of oil that began in 2003-2004 correlates with renewed interest and increased investment by the venture capital community in energy / industrial investment opportunities. Venture capital investments in 2007 for the energy / industrial sector accounted for $3 billion or slightly more than 10% of all venture capital invested that year.

  4. TIP Proposal Preparation Kit Exhibit 4. The NIST-1022A Form, "Other Joint Venture Members".

    E-Print Network [OSTI]

    Magee, Joseph W.

    TIP Proposal Preparation Kit 2010 61 Exhibit 4. The NIST-1022A Form, "Other Joint Venture Members to identify specific information on each joint venture member (exclud- ing the organization submitting in the organization to be contacted regarding technical portion of the proposal), and Congressional District (home

  5. Thin film battery and method for making same

    DOE Patents [OSTI]

    Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

    1994-01-01T23:59:59.000Z

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

  6. Thin film battery and method for making same

    DOE Patents [OSTI]

    Bates, J.B.; Dudney, N.J.; Gruzalski, G.R.; Luck, C.F.

    1994-08-16T23:59:59.000Z

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between [minus]15 C and 150 C. 9 figs.

  7. Life-cycle energy analyses of electric vehicle storage batteries. Final report

    SciTech Connect (OSTI)

    Sullivan, D; Morse, T; Patel, P; Patel, S; Bondar, J; Taylor, L

    1980-12-01T23:59:59.000Z

    The results of several life-cycle energy analyses of prospective electric vehicle batteries are presented. The batteries analyzed were: Nickel-zinc; Lead-acid; Nickel-iron; Zinc-chlorine; Sodium-sulfur (glass electrolyte); Sodium-sulfur (ceramic electrolyte); Lithium-metal sulfide; and Aluminum-air. A life-cycle energy analysis consists of evaluating the energy use of all phases of the battery's life, including the energy to build it, operate it, and any credits that may result from recycling of the materials in it. The analysis is based on the determination of three major energy components in the battery life cycle: Investment energy, i.e., The energy used to produce raw materials and to manufacture the battery; operational energy i.e., The energy consumed by the battery during its operational life. In the case of an electric vehicle battery, this energy is the energy required (as delivered to the vehicle's charging circuit) to power the vehicle for 100,000 miles; and recycling credit, i.e., The energy that could be saved from the recycling of battery materials into new raw materials. The value of the life-cycle analysis approach is that it includes the various penalties and credits associated with battery production and recycling, which enables a more accurate determination of the system's ability to reduce the consumption of scarce fuels. The analysis of the life-cycle energy requirements consists of identifying the materials from which each battery is made, evaluating the energy needed to produce these materials, evaluating the operational energy requirements, and evaluating the amount of materials that could be recycled and the energy that would be saved through recycling. Detailed descriptions of battery component materials, the energy requirements for battery production, and credits for recycling, and the operational energy for an electric vehicle, and the procedures used to determine it are discussed.

  8. Modeling and Simulation of Lithium-Ion Batteries from a Systems Engineering Perspective

    SciTech Connect (OSTI)

    Ramadesigan, V.; Northrop, P. W. C.; De, S.; Santhanagopalan, S.; Braatz, R. D.; Subramanian, Venkat R.

    2012-01-01T23:59:59.000Z

    The lithium-ion battery is an ideal candidate for a wide variety of applications due to its high energy/power density and operating voltage. Some limitations of existing lithium-ion battery technology include underutilization, stress-induced material damage, capacity fade, and the potential for thermal runaway. This paper reviews efforts in the modeling and simulation of lithium-ion batteries and their use in the design of better batteries. Likely future directions in battery modeling and design including promising research opportunities are outlined.

  9. Self-doped molecular composite battery electrolytes

    DOE Patents [OSTI]

    Harrup, Mason K.; Wertsching, Alan K.; Stewart, Frederick F.

    2003-04-08T23:59:59.000Z

    This invention is in solid polymer-based electrolytes for battery applications. It uses molecular composite technology, coupled with unique preparation techniques to render a self-doped, stabilized electrolyte material suitable for inclusion in both primary and secondary batteries. In particular, a salt is incorporated in a nano-composite material formed by the in situ catalyzed condensation of a ceramic precursor in the presence of a solvated polymer material, utilizing a condensation agent comprised of at least one cation amenable to SPE applications. As such, the counterion in the condensation agent used in the formation of the molecular composite is already present as the electrolyte matrix develops. This procedure effectively decouples the cation loading levels required for maximum ionic conductivity from electrolyte physical properties associated with condensation agent loading levels by utilizing the inverse relationship discovered between condensation agent loading and the time domain of the aging step.

  10. A User Programmable Battery Charging System

    E-Print Network [OSTI]

    Amanor-Boadu, Judy M

    2013-05-07T23:59:59.000Z

    Rechargeable batteries are found in almost every battery powered application. Be it portable, stationary or motive applications, these batteries go hand in hand with battery charging systems. With energy harvesting being targeted in this day and age...

  11. Nickel coated aluminum battery cell tabs

    DOE Patents [OSTI]

    Bucchi, Robert S.; Casoli, Daniel J.; Campbell, Kathleen M.; Nicotina, Joseph

    2014-07-29T23:59:59.000Z

    A battery cell tab is described. The battery cell tab is anodized on one end and has a metal coating on the other end. Battery cells and methods of making battery cell tabs are also described.

  12. Status of the DOE Battery and Electrochemical Technology Program V

    SciTech Connect (OSTI)

    Roberts, R.

    1985-06-01T23:59:59.000Z

    The program consists of two activities, Technology Base Research (TBR) managed by the Lawrence Berkeley Laboratory (LBL) and Exploratory Technology Development and Testing (EDT) managed by the Sandia National Laboratories (SNL). The status of the Battery Energy Storage Test (BEST) Facility is presented, including the status of the batteries to be tested. ECS program contributions to the advancement of the lead-acid battery and specific examples of technology transfer from this program are given. The advances during the period December 1982 to June 1984 in the characterization and performance of the lead-acid, iron/nickel-oxide, iron/air, aluminum/air, zinc/bromide, zinc/ferricyanide, and sodium/sulfur batteries and in fuel cells for transport are summarized. Novel techniques and the application of established techniques to the study of electrode processes, especially the electrode/electrolyte interface, are described. Research with the potential of leading to improved ceramic electrolytes and positive electrode container and current-collectors for the sodium/sulfur battery is presented. Advances in the electrocatalysis of the oxygen (air) electrode and the relationship of these advances to the iron/air and aluminum/air batteries and to the fuel cell are noted. The quest for new battery couples and battery materials is reviewed. New developments in the modeling of electrochemical cell and electrode performance with the approaches to test these models are reported.

  13. The characteristic of carbon-coated LiFePO{sub 4} as cathode material for lithium ion battery synthesized by sol-gel process in one step heating and varied pH

    SciTech Connect (OSTI)

    Triwibowo, J., E-mail: joko.triwibowo@lipi.go.id [Research Center for Physics LIPI, Kawasan PUSPIPTEK Serpong (Indonesia); Yuniarti, E.; Suharyadi, E. [Gadjah Mada University, Faculty of Mathematics and Natural Sciences, Sekip Utara Yogyakarta (Indonesia)

    2014-09-25T23:59:59.000Z

    This research has been done on the synthesis of carbon coated LiFePO{sub 4} through sol-gel process. Carbon layer serves for improving electronic conductivity, while the variation of pH in the sol-gel process is intended to obtain the morphology of the material that may improve battery performance. LiFePO{sub 4}/C precursors are Li{sub 2}CO{sub 3}, NH{sub 4}H{sub 2}PO{sub 4} and FeC{sub 2}O{sub 4}.H{sub 2}O and citric acid. In the synthesis process, consisting of a colloidal suspension FeC{sub 2}O{sub 4}.H{sub 2}O and distilled water mixed with a colloidal suspension consisting of NH{sub 4}H{sub 2}PO{sub 4}, Li{sub 2}CO{sub 3}, and distilled water. Variations addition of citric acid is used to control the pH of the gel formed by mixing two colloidal suspensions. Sol in this study had a pH of 5, 5.4 and 5.8. The obtained wet gel is further dried in the oven and then sintered at a temperature 700°C for 10 hours. The resulting material is further characterized by XRD to determine the phases formed. The resulting powder morphology is observed through SEM. Specific surface area of the powder was tested by BET, while the electronic conductivity characterized with EIS.

  14. Testimonials- Partnerships in Battery Technologies- CalBattery

    Broader source: Energy.gov [DOE]

    Phil Roberts, CEO and Founder of California Lithium Battery (CalBattery), describes the new growth and development that was possible through partnering with the U.S. Department of Energy.

  15. Techno-Economic Analysis of PEV Battery Second Use: Repurposed-Battery Selling Price and Commercial and Industrial End-User Value

    SciTech Connect (OSTI)

    Neubauer, J.; Pesaran, A.; Williams, B.; Ferry, M.; Eyer, J.

    2012-06-01T23:59:59.000Z

    Accelerated market penetration of plug-in electric vehicles and deployment of grid-connected energy storage are restricted by the high cost of lithium-ion batteries. Research, development, and manufacturing are underway to lower material costs, enhance process efficiencies, and increase production volumes. A fraction of the battery cost may be recovered after vehicular service by reusing the battery where it may have sufficient performance for other energy-storage applications. By extracting post-vehicle additional services and revenue from the battery, the total lifetime value of the battery is increased. The overall cost of energy-storage solutions for both primary (automotive) and secondary (grid) customer could be decreased. This techno-economic analysis of battery second use considers effects of battery degradation in both automotive and grid service, repurposing costs, balance-of-system costs, the value of aggregated energy-storage to commercial and industrial end users, and competitive technology. Batteries from plug-in electric vehicles can economically be used to serve the power quality and reliability needs of commercial and industrial end users. However, the value to the automotive battery owner is small (e.g., $20-$100/kWh) as declining future battery costs and other factors strongly affect salvage value. Repurposed automotive battery prices may range from $38/kWh to $132/kWh.

  16. Battery venting system and method

    DOE Patents [OSTI]

    Casale, T.J.; Ching, L.K.W.; Baer, J.T.; Swan, D.H.

    1999-01-05T23:59:59.000Z

    Disclosed herein is a venting mechanism for a battery. The venting mechanism includes a battery vent structure which is located on the battery cover and may be integrally formed therewith. The venting mechanism includes an opening extending through the battery cover such that the opening communicates with a plurality of battery cells located within the battery case. The venting mechanism also includes a vent manifold which attaches to the battery vent structure. The vent manifold includes a first opening which communicates with the battery vent structure opening and second and third openings which allow the vent manifold to be connected to two separate conduits. In this manner, a plurality of batteries may be interconnected for venting purposes, thus eliminating the need to provide separate vent lines for each battery. The vent manifold may be attached to the battery vent structure by a spin-welding technique. To facilitate this technique, the vent manifold may be provided with a flange portion which fits into a corresponding groove portion on the battery vent structure. The vent manifold includes an internal chamber which is large enough to completely house a conventional battery flame arrester and overpressure safety valve. In this manner, the vent manifold, when installed, lessens the likelihood of tampering with the flame arrester and safety valve. 8 figs.

  17. Battery venting system and method

    DOE Patents [OSTI]

    Casale, Thomas J. (Aurora, CO); Ching, Larry K. W. (Littleton, CO); Baer, Jose T. (Gaviota, CA); Swan, David H. (Monrovia, CA)

    1999-01-05T23:59:59.000Z

    Disclosed herein is a venting mechanism for a battery. The venting mechanism includes a battery vent structure which is located on the battery cover and may be integrally formed therewith. The venting mechanism includes an opening extending through the battery cover such that the opening communicates with a plurality of battery cells located within the battery case. The venting mechanism also includes a vent manifold which attaches to the battery vent structure. The vent manifold includes a first opening which communicates with the battery vent structure opening and second and third openings which allow the vent manifold to be connected to two separate conduits. In this manner, a plurality of batteries may be interconnected for venting purposes, thus eliminating the need to provide separate vent lines for each battery. The vent manifold may be attached to the battery vent structure by a spin-welding technique. To facilitate this technique, the vent manifold may be provided with a flange portion which fits into a corresponding groove portion on the battery vent structure. The vent manifold includes an internal chamber which is large enough to completely house a conventional battery flame arrester and overpressure safety valve. In this manner, the vent manifold, when installed, lessens the likelihood of tampering with the flame arrester and safety valve.

  18. Battery Vent Mechanism And Method

    DOE Patents [OSTI]

    Ching, Larry K. W. (Littleton, CO)

    2000-02-15T23:59:59.000Z

    Disclosed herein is a venting mechanism for a battery. The venting mechanism includes a battery vent structure which is located on the battery cover and may be integrally formed therewith. The venting mechanism includes an opening extending through the battery cover such that the opening communicates with a plurality of battery cells located within the battery case. The venting mechanism also includes a vent manifold which attaches to the battery vent structure. The vent manifold includes a first opening which communicates with the battery vent structure opening and second and third openings which allow the vent manifold to be connected to two separate conduits. In this manner, a plurality of batteries may be interconnected for venting purposes, thus eliminating the need to provide separate vent lines for each battery. The vent manifold may be attached to the battery vent structure by a spin-welding technique. To facilitate this technique, the vent manifold may be provided with a flange portion which fits into a corresponding groove portion on the battery vent structure. The vent manifold includes an internal chamber which is large enough to completely house a conventional battery flame arrester and overpressure safety valve. In this manner, the vent manifold, when installed, lessens the likelihood of tampering with the flame arrester and safety valve.

  19. Electrocatalysts for Nonaqueous Lithium–Air Batteries:...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrocatalysts for Nonaqueous Lithium–Air Batteries: Status, Challenges, and Perspective. Electrocatalysts for Nonaqueous Lithium–Air Batteries: Status, Challenges,...

  20. Testimonials - Partnerships in Battery Technologies - Capstone...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battery Technologies - Capstone Turbine Corporation Testimonials - Partnerships in Battery Technologies - Capstone Turbine Corporation Addthis Text Version The words Office of...

  1. No. 2 battery design and start-up at Bethlehem`s Burns Harbor Div.

    SciTech Connect (OSTI)

    Mayton, L.R. [Bethlehem Steel Corp., Chesteron, IN (United States); Buss, W.E. [Thyssen Still Otto Technical Services, Pittsburgh, PA (United States)

    1995-07-01T23:59:59.000Z

    On November 1, 1993, the No. 2 battery at the Burns Harbor Div. was shutdown in preparation for a pad up rebuild. Work for this project had been ongoing for several years. Awarding of the turnkey contract for the rebuild had occurred in Sept. 1992, to a Davy International/Davy Songer joint venture and Thyssen Still Otto for the design and construction of the facility. The project was to include the replacement of the existing 82 oven facility, utilizing the latest in battery design and technology. The overall design philosophy was to construct a battery having a 30-year operational life capability, incorporating emission control systems to comply with existing and future Clean Air Act regulation. Construction work for the project was completed two months ahead of schedule, with the first charges made on Dec. 17, 1994. Beginning with the first pushes on the following day, the battery began stable operations at the 24-hr coking rate Jan. 3, 1995. At that time, production began increasing in planned states, with the designed coking rate achieved on March 13. The paper will detail the overall design philosophy for No. 2 battery along with related facilities, highlight key features of the design providing for 30-year life and environmental compliance, review the start-up and detail current operational performance.

  2. Circulating current battery heater

    DOE Patents [OSTI]

    Ashtiani, Cyrus N. (West Bloomfield, MI); Stuart, Thomas A. (Toledo, OH)

    2001-01-01T23:59:59.000Z

    A circuit for heating energy storage devices such as batteries is provided. The circuit includes a pair of switches connected in a half-bridge configuration. Unidirectional current conduction devices are connected in parallel with each switch. A series resonant element for storing energy is connected from the energy storage device to the pair of switches. An energy storage device for intermediate storage of energy is connected in a loop with the series resonant element and one of the switches. The energy storage device which is being heated is connected in a loop with the series resonant element and the other switch. Energy from the heated energy storage device is transferred to the switched network and then recirculated back to the battery. The flow of energy through the battery causes internal power dissipation due to electrical to chemical conversion inefficiencies. The dissipated power causes the internal temperature of the battery to increase. Higher internal temperatures expand the cold temperature operating range and energy capacity utilization of the battery. As disclosed, either fixed frequency or variable frequency modulation schemes may be used to control the network.

  3. Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems

    DOE Patents [OSTI]

    Tuffner, Francis K. (Richland, WA); Kintner-Meyer, Michael C. W. (Richland, WA); Hammerstrom, Donald J. (West Richland, WA); Pratt, Richard M. (Richland, WA)

    2012-05-22T23:59:59.000Z

    Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems. According to one aspect, a battery charging control method includes accessing information regarding a presence of at least one of a surplus and a deficiency of electrical energy upon an electrical power distribution system at a plurality of different moments in time, and using the information, controlling an adjustment of an amount of the electrical energy provided from the electrical power distribution system to a rechargeable battery to charge the rechargeable battery.

  4. Rechargeable lithium battery for use in applications requiring a low to high power output

    DOE Patents [OSTI]

    Bates, John B. (Oak Ridge, TN)

    1996-01-01T23:59:59.000Z

    Rechargeable lithium batteries which employ characteristics of thin-film batteries can be used to satisfy power requirements within a relatively broad range. Thin-film battery cells utilizing a film of anode material, a film of cathode material and an electrolyte of an amorphorus lithium phosphorus oxynitride can be connected in series or parallel relationship for the purpose of withdrawing electrical power simultaneously from the cells. In addition, such battery cells which employ a lithium intercalation compound as its cathode material can be connected in a manner suitable for supplying power for the operation of an electric vehicle. Still further, by incorporating within the battery cell a relatively thick cathode of a lithium intercalation compound, a relatively thick anode of lithium and an electrolyte film of lithium phosphorus oxynitride, the battery cell is rendered capable of supplying power for any of a number of consumer products, such as a laptop computer or a cellular telephone.

  5. Rechargeable lithium battery for use in applications requiring a low to high power output

    DOE Patents [OSTI]

    Bates, John B. (Oak Ridge, TN)

    1997-01-01T23:59:59.000Z

    Rechargeable lithium batteries which employ characteristics of thin-film batteries can be used to satisfy power requirements within a relatively broad range. Thin-film battery cells utilizing a film of anode material, a film of cathode material and an electrolyte of an amorphous lithium phosphorus oxynitride can be connected in series or parallel relationship for the purpose of withdrawing electrical power simultaneously from the cells. In addition, such battery cells which employ a lithium intercalation compound as its cathode material can be connected in a manner suitable for supplying power for the operation of an electric vehicle. Still further, by incorporating within the battery cell a relatively thick cathode of a lithium intercalation compound, a relatively thick anode of lithium and an electrolyte film of lithium phosphorus oxynitride, the battery cell is rendered capable of supplying power for any of a number of consumer products, such as a laptop computer or a cellular telephone.

  6. Sealed Battery Block Provided With A Cooling System

    DOE Patents [OSTI]

    Verhoog, Roelof (Bordeaux, FR); Barbotin, Jean-Loup (Pompignac, FR)

    1999-11-16T23:59:59.000Z

    The present invention relates to a sealed battery block operating at a pressure of at least 1 bar relative, the battery including a container made of a plastics material and made up of a lid and of a case subdivided into wells by at least one partition, said battery being provided with a cooling system including two cheek plates made of a plastics material and co-operating with the outside faces of respective ones of two opposite walls of said case, each cheek plate co-operating with the corresponding wall to define a compartment provided with a plurality of ribs forming baffles for fluid flow purposes, and with an inlet orifice and an outlet orifice for the fluid, said battery being characterized in that each of said ribs extends in a direction that forms an angle relative to the plane of said partition lying in the range 60.degree. to 90.degree..

  7. Multi-cell storage battery

    DOE Patents [OSTI]

    Brohm, Thomas (Hattersheim, DE); Bottcher, Friedhelm (Kelkheim, DE)

    2000-01-01T23:59:59.000Z

    A multi-cell storage battery, in particular to a lithium storage battery, which contains a temperature control device and in which groups of one or more individual cells arranged alongside one another are separated from one another by a thermally insulating solid layer whose coefficient of thermal conductivity lies between 0.01 and 0.2 W/(m*K), the thermal resistance of the solid layer being greater by at least a factor .lambda. than the thermal resistance of the individual cell. The individual cell is connected, at least in a region free of insulating material, to a heat exchanger, the thermal resistance of the heat exchanger in the direction toward the neighboring cell being selected to be greater by at least a factor .lambda. than the thermal resistance of the individual cell and, in addition, the thermal resistance of the heat exchanger toward the temperature control medium being selected to be smaller by at least a factor of about 10 than the thermal resistance of the individual cell, and .lambda. being the ratio of the energy content of the individual cell to the amount of energy that is needed to trigger a thermally induced cell failure at a defined upper operating temperature limit.

  8. Synthesis of Na1.25V3O8 Nanobelts with Excellent Long-Term Stability for Rechargeable Lithium-Ion Batteries

    E-Print Network [OSTI]

    Cao, Guozhong

    by the calcination temperatures. As cathode materials for lithium ion batteries, the Na1.25V3O8 nanobelts synthesized.25V3O8 nanobelts are promising cathode materials for secondary lithium batteries. KEYWORDS: sodium vanadium oxide, nanobelts, sol-gel, lithium-ion batteries, long-term stability 1. INTRODUCTION Because

  9. Effects of Mg doping on the remarkably enhanced electrochemical performance of Na3V2(PO4)3 cathode materials for sodium ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Hui [Beijing Inst. of Technology, Beijing (China). Key Lab. of Environmental Science and Engineering, School of Chemical Engineering and Environment; Yu, Xiqian [Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Bai, Ying [Beijing Inst. of Technology, Beijing (China). Key Lab. of Environmental Science and Engineering, School of Chemical Engineering and Environment; Wu, Feng [Beijing Inst. of Technology, Beijing (China). Key Lab. of Environmental Science and Engineering, School of Chemical Engineering and Environment; Wu, Chuan [Beijing Inst. of Technology, Beijing (China). Key Lab. of Environmental Science and Engineering, School of Chemical Engineering and Environment; Liu, Liang-Yu [Beijing Inst. of Technology, Beijing (China). Key Lab. of Environmental Science and Engineering, School of Chemical Engineering and Environment; Yang, Xiao-Qing [Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.

    2015-01-01T23:59:59.000Z

    Na3V2-xMgx(PO4)3/C composites with different Mg2+ doping contents (x=0, 0.01, 0.03, 0.05, 0.07 and 0.1) were prepared by a facile sol-gel method. The doping effects on the crystal structure were investigated by XRD, XPS and EXAFS. The results show that low dose doping Mg2+ does not alter the structure of the material, and magnesium is successfully substituted for vanadium site. The Mg doped Na3V2-xMgx(PO4)3/C composites exhibit significant improvements on the electrochemistry performances in terms of the rate capability and cycle performance, especially for the Na3V1.95Mg0.05(PO4)3/C. For example, when the current density increased from 1 C to 30 C, the specific capacity only decreased from 112.5 mAh g-1 to 94.2 mAh g-1 showing very good rate capability. Moreover, even cycling at a high rate of 20 C, an excellent capacity retention of 81% is maintained from the initial value of 106.4 mAh g-1 to 86.2 mAh g-1 at the 50th cycle. Enhanced rate capability and cycle performance can be attributed to the optimized particle size, structural stability and enhanced ionic and electronic conductivity induced by Mg doping.

  10. Effects of Mg doping on the remarkably enhanced electrochemical performance of Na3V2(PO4)3 cathode materials for sodium ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Hui; Yu, Xiqian; Bai, Ying; Wu, Feng; Wu, Chuan; Liu, Liang-Yu; Yang, Xiao-Qing

    2015-01-01T23:59:59.000Z

    Na3V2-xMgx(PO4)3/C composites with different Mg2+ doping contents (x=0, 0.01, 0.03, 0.05, 0.07 and 0.1) were prepared by a facile sol-gel method. The doping effects on the crystal structure were investigated by XRD, XPS and EXAFS. The results show that low dose doping Mg2+ does not alter the structure of the material, and magnesium is successfully substituted for vanadium site. The Mg doped Na3V2-xMgx(PO4)3/C composites exhibit significant improvements on the electrochemistry performances in terms of the rate capability and cycle performance, especially for the Na3V1.95Mg0.05(PO4)3/C. For example, when the current density increased from 1 C to 30 C, the specific capacitymore »only decreased from 112.5 mAh g-1 to 94.2 mAh g-1 showing very good rate capability. Moreover, even cycling at a high rate of 20 C, an excellent capacity retention of 81% is maintained from the initial value of 106.4 mAh g-1 to 86.2 mAh g-1 at the 50th cycle. Enhanced rate capability and cycle performance can be attributed to the optimized particle size, structural stability and enhanced ionic and electronic conductivity induced by Mg doping.« less

  11. Battery Charger Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureComments fromofBatteries from Brine Batteries from Brine March 31,

  12. Batteries | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Batteries Batteries An error occurred. Try watching this

  13. Three dimensional neutronics calculations for the TAMU Nuclear Science Center Triga reactor using BOLD VENTURE

    E-Print Network [OSTI]

    Yupari, Ricardo

    1985-01-01T23:59:59.000Z

    using the computer code BOLD VENTURE. BOLD VENTURE is a modular type computational system which was developed by Oak Ridge National Laborator y for nuclear r eactor analysis. VENTURE is the neutronics module which implements a f inite...-dif'ference solution of the multigroup diffusion equations in 3-D geometry. The computer code was loaded and compiled on the TAMU AMDAHL computer, and sample pr oblems were run in or der to test the performance of each of the computational modules. The effective...

  14. Battery with a microcorrugated, microthin sheet of highly porous corroded metal

    DOE Patents [OSTI]

    LaFollette, Rodney M.

    2005-09-27T23:59:59.000Z

    Microthin sheet technology is disclosed by which superior batteries are constructed which, among other things, accommodate the requirements for high load rapid discharge and recharge, mandated by electric vehicle criteria. The microthin sheet technology has process and article overtones and can be used to form thin electrodes used in batteries of various kinds and types, such as spirally-wound batteries, bipolar batteries, lead acid batteries silver/zinc batteries, and others. Superior high performance battery features include: (a) minimal ionic resistance; (b) minimal electronic resistance; (c) minimal polarization resistance to both charging and discharging; (d) improved current accessibility to active material of the electrodes; (e) a high surface area to volume ratio; (f) high electrode porosity (microporosity); (g) longer life cycle; (h) superior discharge/recharge characteristics; (i) higher capacities (A.multidot.hr); and (j) high specific capacitance.

  15. Process to produce lithium-polymer batteries

    DOE Patents [OSTI]

    MacFadden, Kenneth Orville (Highland, MD)

    1998-01-01T23:59:59.000Z

    A polymer bonded sheet product suitable for use as an electrode in a non-aqueous battery system. A porous electrode sheet is impregnated with a solid polymer electrolyte, so as to diffuse into the pores of the electrode. The composite is allowed to cool, and the electrolyte is entrapped in the porous electrode. The sheet products composed have the solid polymer electrolyte composition diffused into the active electrode material by melt-application of the solid polymer electrolyte composition into the porous electrode material sheet. The solid polymer electrolyte is maintained at a temperature that allows for rapid diffusion into the pores of the electrode. The composite electrolyte-electrode sheets are formed on current collectors and can be coated with solid polymer electrolyte prior to battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte coating has low resistance.

  16. Process to produce lithium-polymer batteries

    DOE Patents [OSTI]

    MacFadden, K.O.

    1998-06-30T23:59:59.000Z

    A polymer bonded sheet product is described suitable for use as an electrode in a non-aqueous battery system. A porous electrode sheet is impregnated with a solid polymer electrolyte, so as to diffuse into the pores of the electrode. The composite is allowed to cool, and the electrolyte is entrapped in the porous electrode. The sheet products composed have the solid polymer electrolyte composition diffused into the active electrode material by melt-application of the solid polymer electrolyte composition into the porous electrode material sheet. The solid polymer electrolyte is maintained at a temperature that allows for rapid diffusion into the pores of the electrode. The composite electrolyte-electrode sheets are formed on current collectors and can be coated with solid polymer electrolyte prior to battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte coating has low resistance. 1 fig.

  17. Structural Integration of Silicon Solar Cells and Lithium-ion Batteries Using Printed Electronics

    E-Print Network [OSTI]

    Kang, Jin Sung

    2012-01-01T23:59:59.000Z

    Solar Energy Materials and Solar Cells, vol. 93, 2009, pp.Solar energy materials and solar cells, vol. 91, 2007, pp.to integrate thin-film solar cells and batteries (2)

  18. Three-dimensional batteries using a liquid cathode

    E-Print Network [OSTI]

    Malati, Peter Moneir

    2013-01-01T23:59:59.000Z

    3 and 4, secondary lithium batteries based on using lithiumcommercial primary lithium batteries. The final part of thislithium batteries. ..

  19. Conductive polymeric compositions for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles A. (Mesa, AZ); Xu, Wu (Tempe, AZ)

    2009-03-17T23:59:59.000Z

    Novel chain polymers comprising weakly basic anionic moieties chemically bound into a polyether backbone at controllable anionic separations are presented. Preferred polymers comprise orthoborate anions capped with dibasic acid residues, preferably oxalato or malonato acid residues. The conductivity of these polymers is found to be high relative to that of most conventional salt-in-polymer electrolytes. The conductivity at high temperatures and wide electrochemical window make these materials especially suitable as electrolytes for rechargeable lithium batteries.

  20. Battery testing for photovoltaic applications

    SciTech Connect (OSTI)

    Hund, T.

    1996-11-01T23:59:59.000Z

    Battery testing for photovoltaic (PV) applications is funded at Sandia under the Department of Energy`s (DOE) Photovoltaic Balance of Systems (BOS) Program. The goal of the PV BOS program is to improve PV system component design, operation, reliability, and to reduce overall life-cycle costs. The Sandia battery testing program consists of: (1) PV battery and charge controller market survey, (2) battery performance and life-cycle testing, (3) PV charge controller development, and (4) system field testing. Test results from this work have identified market size and trends, PV battery test procedures, application guidelines, and needed hardware improvements.

  1. Current balancing for battery strings

    DOE Patents [OSTI]

    Galloway, James H. (New Baltimore, MI)

    1985-01-01T23:59:59.000Z

    A battery plant is described which features magnetic circuit means for balancing the electrical current flow through a pluraliircuitbattery strings which are connected electrically in parallel. The magnetic circuit means is associated with the battery strings such that the conductors carrying the electrical current flow through each of the battery strings pass through the magnetic circuit means in directions which cause the electromagnetic fields of at least one predetermined pair of the conductors to oppose each other. In an alternative embodiment, a low voltage converter is associated with each of the battery strings for balancing the electrical current flow through the battery strings.

  2. Battery electrode growth accommodation

    DOE Patents [OSTI]

    Bowen, Gerald K. (Cedarburg, WI); Andrew, Michael G. (Wauwatosa, WI); Eskra, Michael D. (Fredonia, WI)

    1992-01-01T23:59:59.000Z

    An electrode for a lead acid flow through battery, the grids including a plastic frame, a plate suspended from the top of the frame to hang freely in the plastic frame and a paste applied to the plate, the paste being free to allow for expansion in the planar direction of the grid.

  3. Method and apparatus for smart battery charging including a plurality...

    Office of Scientific and Technical Information (OSTI)

    Re-direct Destination: A method for managing the charging and discharging of batteries wherein at least one battery is connected to a battery charger, the battery charger...

  4. Johnson Controls Develops an Improved Vehicle Battery, Works...

    Energy Savers [EERE]

    Johnson Controls Develops an Improved Vehicle Battery, Works to Cut Battery Costs in Half Johnson Controls Develops an Improved Vehicle Battery, Works to Cut Battery Costs in Half...

  5. Bipolar battery with array of sealed cells

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL); Smaga, John A. (Lemont, IL)

    1987-01-01T23:59:59.000Z

    A lithium alloy/metal sulfide battery as a dipolar battery is disclosed with an array of stacked cells with the anode and cathode electrode materials in each cell sealed in a confining structure and separated from one another except across separator material interposed therebetween. The separator material is contained in a module having separate perforated metallic sheets that sandwich opposite sides of the separator material for the cell and an annular insulating spacer that surrounds the separator material beyond the perforations and is also sandwiched between and sealed to the sheets. The peripheral edges of the sheets project outwardly beyond the spacer, traverse the side edges of the adjacent electrode material to form cup-like electrode holders, and are fused to the adjacent current collector or end face members of the array. Electrolyte is infused into the electrolyte cavity through the perforations of one of the metallic sheets with the perforations also functioning to allow ionic conductance across the separator material between the adjacent electrodes. A gas-tight housing provides an enclosure of the array.

  6. Interaction model of private equity and venture capital developing factors in Chile and Latin America

    E-Print Network [OSTI]

    Sevil Esteban, Ángel

    2012-01-01T23:59:59.000Z

    Private equity and venture capital (PE/VC) are efficient resource allocation systems that provide equity capital to selected entrepreneurs, industries or firms that contribute to advance the economic welfare of society. ...

  7. Seeds of growth : the challenges of venture capital in the Australian landscape

    E-Print Network [OSTI]

    Lu, Adrian C. (Adrian Chian)

    2012-01-01T23:59:59.000Z

    The Australian venture capital (VC) industry is young and relatively immature compared to the United States. Even though the first Australian VC firm appeared in 1970, the industry remained a niche with low levels of ...

  8. Agency conflicts in financial contracting with applications to venture capital and CDO markets

    E-Print Network [OSTI]

    Garrison, Kedran

    2005-01-01T23:59:59.000Z

    In these papers I examine efficient financial contracting when incentive problems play a significant role. In the first chapter (joint with Z. Fluck and S. Myers) we focus on the venture capital industry. We build a two-stage ...

  9. Growth strategies : how software start-ups can leverage alliances, acquisitions, IPOs and venture capital

    E-Print Network [OSTI]

    Ybanez, Sergio D

    2007-01-01T23:59:59.000Z

    The identification of the different factors impacting a software start-up company's decision to pursue an alliance, acquisition, IPO or venture capital to sustain growth is the main objective of this research study. First ...

  10. The role of venture capitalists in financing and developing high-technology start-ups

    E-Print Network [OSTI]

    Hsu, David H

    2001-01-01T23:59:59.000Z

    This dissertation addresses the interaction between venture capitalists (VCs) and start-up development through three essays. A common theme is that VCs serve important extra-financial and information brokering roles. In ...

  11. University of Minnesota Start-up Guide Office for Technology Commercialization (OTC) -Venture Center

    E-Print Network [OSTI]

    Amin, S. Massoud

    ....................................................................................... 18 APPENDIX D: UNIVERSITY FUNDING OPPORTUNITIESUniversity of Minnesota Start-up Guide Office for Technology Commercialization (OTC) - Venture on University of Minnesota research Revised September 2010 1000 Westgate Drive: Suite 160 St. Paul, MN 55114 612

  12. Venture Capitalists' Decision to Withdraw: The Role of Portfolio Configuration From a Real Options Lens

    E-Print Network [OSTI]

    Li, Yong; Chi, Tailan

    2012-01-01T23:59:59.000Z

    When does a venture capital firm withdraw from an investment project prior to its completion? This study offers a real options view on this decision by examining the contingent effects of portfolio configuration. We explore how project withdrawal...

  13. Nonprofit disease foundation investments in biotechnology companies : an evaluation of venture philanthropy

    E-Print Network [OSTI]

    Fielding, Sarah (Sarah Tabbals)

    2011-01-01T23:59:59.000Z

    In the past decade, the practice of venture philanthropy, defined in this research as the provision of capital by a nonprofit entity to a for-profit company, has become an increasingly common asset allocation strategy for ...

  14. Coated porous carbon cathodes for lithium ion batteries

    SciTech Connect (OSTI)

    Kercher, Andrew K [ORNL; Dudney, Nancy J [ORNL; Kiggans, Jim [ORNL; Klett, James William [ORNL

    2008-01-01T23:59:59.000Z

    Coated porous carbon cathodes for automotive lithium batteries are being developed with the goal of overcoming the problems with capacity fade and poor thermal management in conventional polymer-bonded cathodes. The active cathode material (lithium iron phosphate nanoparticles) is carbon-bonded to the porous carbon support material. Cathodes have been developed with high specific energy and power and with good cycling behavior.

  15. Process for Low Cost Domestic Production of LIB Cathode Materials

    Broader source: Energy.gov (indexed) [DOE]

    information" 4 Approach BASF has a low cost production process for Li ion battery cathode materials. In this project, the cathode materials developed in the laboratory will be...

  16. New Energy Storage and Energy Generation Materials from First...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    energy storage (Li ion and multivalent ion batteries) and energy generation (thermoelectric materials). The second part of this talk will focus on the Materials Project (MP),...

  17. Intercalation Kinetics and Ion Mobility in Electrode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intercalation Kinetics and Ion Mobility in Electrode Materials for Advanced Lithium Ion Batteries Intercalation Kinetics and Ion Mobility in Electrode Materials for Advanced...

  18. Method and apparatus for measuring the state of charge in a battery based on volume of battery components

    DOE Patents [OSTI]

    Rouhani, S. Zia (Idaho Falls, ID)

    1996-10-22T23:59:59.000Z

    The state of charge of electrochemical batteries of different kinds is determined by measuring the incremental change in the total volume of the reactive masses in the battery. The invention is based on the principle that all electrochemical batteries, either primary or secondary (rechargeable), produce electricity through a chemical reaction with at least one electrode, and the chemical reactions produce certain changes in the composition and density of the electrode. The reactive masses of the electrodes, the electrolyte, and any separator or spacers are usually contained inside a battery casing of a certain volume. As the battery is used, or recharged, the specific volume of at least one of the electrode masses will change and, since the masses of the materials do not change considerably, the total volume occupied by at least one of the electrodes will change. These volume changes may be measured in many different ways and related to the state of charge in the battery. In one embodiment, the volume change can be measured by monitoring the small changes in one of the principal dimensions of the battery casing as it expands or shrinks to accommodate the combined volumes of its components.

  19. "Tailoring synthesis of new materials at multiple length scales."

    E-Print Network [OSTI]

    Acton, Scott

    for a lithium-ion battery cathode material. · Published a method to tailor the transition metal composition in battery electrode materials. · Published a previously unreported safety issue with a popular lithium-ion to dramatically increase the energy density of lithium-ion batteries. We employ a hierarchical, multiscale

  20. Washington: Battery Manufacturer Brings Material Production Home...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    most of the project's equipment, and this project is helping to build out a domestic industry that creates jobs for U.S. workers. EnerG2 created more than 200 temporary...

  1. Autumn 2009 New materials for better batteries

    E-Print Network [OSTI]

    Keeler, James

    ? In a petrol engine, partially oxidised hydrocarbons such as aldehydes and carbon monoxide are pro- duced

  2. Battery materials for ultrafast charging and discharging

    E-Print Network [OSTI]

    Ceder, Gerbrand

    be achieved with super- capacitors, which trade high power for low energy density as they only store energy

  3. Vehicle Technologies Office: Exploratory Battery Materials Research |

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group current C3EDepartmentDepartment ofConstruction|(EVSE)EachResearch

  4. Disordered Materials Hold Promise for Better Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisitingContract ManagementDiscovering How Muscles Really Work Disksuperlattices

  5. Washington: Battery Manufacturer Brings Material Production Home |

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed off Energy.gov. Are you sureReportsofDepartmentSeries |Attacks |VisualizingWarm Weather and

  6. Batteries - Materials Processing and Manufacturing Breakout session

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy China U.S. Department ofJune 2, 2015 TheB2 March 5, 2014) TheBagdadThe20585

  7. Nanocomposite Materials for Lithium-Ion Batteries

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in Many Devils Wash,Energy NRELNamrata Kolachalam AboutDepartment

  8. Nanotube Composite Anode Materials | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    available for licensng: A composite material suitable for use in an anode for a lithium-ion battery Reduces manufacturing costs. Provides increase capacity, safety, long-term...

  9. Ecological and biomedical effects of effluents from near-term electric vehicle storage battery cycles

    SciTech Connect (OSTI)

    Not Available

    1980-05-01T23:59:59.000Z

    An assessment of the ecological and biomedical effects due to commercialization of storage batteries for electric and hybrid vehicles is given. It deals only with the near-term batteries, namely Pb/acid, Ni/Zn, and Ni/Fe, but the complete battery cycle is considered, i.e., mining and milling of raw materials, manufacture of the batteries, cases and covers; use of the batteries in electric vehicles, including the charge-discharge cycles; recycling of spent batteries; and disposal of nonrecyclable components. The gaseous, liquid, and solid emissions from various phases of the battery cycle are identified. The effluent dispersal in the environment is modeled and ecological effects are assessed in terms of biogeochemical cycles. The metabolic and toxic responses by humans and laboratory animals to constituents of the effluents are discussed. Pertinent environmental and health regulations related to the battery industry are summarized and regulatory implications for large-scale storage battery commercialization are discussed. Each of the seven sections were abstracted and indexed individually for EDB/ERA. Additional information is presented in the seven appendixes entitled; growth rate scenario for lead/acid battery development; changes in battery composition during discharge; dispersion of stack and fugitive emissions from battery-related operations; methodology for estimating population exposure to total suspended particulates and SO/sub 2/ resulting from central power station emissions for the daily battery charging demand of 10,000 electric vehicles; determination of As air emissions from Zn smelting; health effects: research related to EV battery technologies. (JGB)

  10. Pyro-E | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    University 31 likes SiNode Systems is a battery materials venture developing silicon-graphene anodes for the next generation of lithium-ion batteries. SiNode anodes offer higher...

  11. Bioadhesive Alliance | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    University 31 likes SiNode Systems is a battery materials venture developing silicon-graphene anodes for the next generation of lithium-ion batteries. SiNode anodes offer higher...

  12. Inviroment | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    University 31 likes SiNode Systems is a battery materials venture developing silicon-graphene anodes for the next generation of lithium-ion batteries. SiNode anodes offer higher...

  13. SiNode Systems | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    University SiNode Systems is a battery materials venture developing silicon-graphene anodes for the next generation of lithium-ion batteries. SiNode anodes offer higher...

  14. Bearing Analytics | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    University 31 likes SiNode Systems is a battery materials venture developing silicon-graphene anodes for the next generation of lithium-ion batteries. SiNode anodes offer higher...

  15. Picasolar | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    University 31 likes SiNode Systems is a battery materials venture developing silicon-graphene anodes for the next generation of lithium-ion batteries. SiNode anodes offer higher...

  16. Applying the Battery Ownership Model in Pursuit of Optimal Battery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Vehicle Technologies Office: 2013 Energy Storage R&D Progress Report, Sections 4-6 Analysis of Electric Vehicle Battery Performance...

  17. Innovative Manufacturing and Materials for Low-Cost Lithium-Ion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacturing and Materials for Low-Cost Lithium-Ion Batteries Innovative Manufacturing and Materials for Low-Cost Lithium-Ion Batteries 2012 DOE Hydrogen and Fuel Cells Program...

  18. Enhanced performance of graphite anode materials by AlF3 coating...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    performance of graphite anode materials by AlF3 coating for lithium-ion batteries. Enhanced performance of graphite anode materials by AlF3 coating for lithium-ion batteries....

  19. Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |IsLove Your Home andDisposition | NationalMaterials

  20. United States Advanced Battery Consortium

    Broader source: Energy.gov (indexed) [DOE]

    of internal short circuit as a potential failure mechanism * Public Perception: - Media and other promotion of unrealistic expectations for battery capabilities present a...

  1. Synthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium-Ion Batteries

    E-Print Network [OSTI]

    Cui, Yi

    on larger scales. Im- provement of the safety of lithium-ion batteries must occur if they are to be utilized in aqueous cells. However, the choice of a suitable anode material for an aqueous lithium-ion battery is moreSynthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium-Ion

  2. SnO2 Filled Mesoporous Tin Phosphate High Capacity Negative Electrode for Lithium Secondary Battery

    E-Print Network [OSTI]

    Cho, Jaephil

    SnO2 Filled Mesoporous Tin Phosphate High Capacity Negative Electrode for Lithium Secondary Battery insulators, and optics.1-6 On the other hand, their applications to electrode materials in lithium secondary batteries have received little attention because of the very limited candidates.7,8 Recently

  3. J. Electrochem. Soc., in press (1998) MicroMacroscopic Coupled Modeling of Batteries and Fuel Cells

    E-Print Network [OSTI]

    Wang, Chao-Yang

    , as well as various fuel cells, are widely used in consumer applications and electric vehicles materials and interface morphology and chemistry, has been developed for advanced batteries and fuel cells. Modeling and simulation of battery and fuel cell systems has been a rapidly expanding field, thanks in part

  4. Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4

    E-Print Network [OSTI]

    Cui, Yi

    nanostructure devices as a powerful new diagnostic tool for batteries with LiMn2O4 nanorod materials energy storage devices for portable electronic devices, power tools, and electrical vehicles.1-4 Anodes applied to battery researches. This work represents the first example of single nanostructure device

  5. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battery Electrodes Print Friday, 26 July 2013 14:18 The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone...

  6. Advanced battery modeling using neural networks

    E-Print Network [OSTI]

    Arikara, Muralidharan Pushpakam

    1993-01-01T23:59:59.000Z

    Batteries have gained importance as power sources for electric vehicles. The main problem with the battery technology available today is that the design of the battery system has not been optimized for different applications. No comprehensive...

  7. Advanced battery modeling using neural networks 

    E-Print Network [OSTI]

    Arikara, Muralidharan Pushpakam

    1993-01-01T23:59:59.000Z

    Batteries have gained importance as power sources for electric vehicles. The main problem with the battery technology available today is that the design of the battery system has not been optimized for different applications. No comprehensive...

  8. Energy Storage & Battery | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage & Battery Leading the charge in battery R&D Argonne National Laboratory is a global leader in the development of advanced battery technologies and has a portfolio of...

  9. Block copolymer electrolytes for lithium batteries

    E-Print Network [OSTI]

    Hudson, William Rodgers

    2011-01-01T23:59:59.000Z

    D. Thin-film lithium and lithium-ion batteries. Solid StateH. Polymer electrolytes for lithium-ion batteries. AdvancedReviews, 2010). Ozawa, K. Lithium-ion rechargeable batteries

  10. Advances in lithium-ion batteries

    E-Print Network [OSTI]

    Kerr, John B.

    2003-01-01T23:59:59.000Z

    Advances in Lithium-Ion Batteries Edited by Walter A. vantolerance of these batteries this is a curious omission andmysteries of lithium ion batteries. The book begins with an

  11. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    simulate those in a lithium battery. Chapter 3 TransientModel for Aging of Lithium-Ion Battery Cells. Journal of TheRole in Nonaqueous Lithium-Oxygen Battery Electrochemistry.

  12. Good upkeep adds to battery life

    SciTech Connect (OSTI)

    Jackson, D.

    1983-01-01T23:59:59.000Z

    The care and maintenance of underground mine batteries is discussed. A guide to motive power battery manufacturers in USA is included, plus a list of definitions of battery terms.

  13. Design and Simulation of Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Doyle, C.M.

    2010-01-01T23:59:59.000Z

    to Thermal Rise in Lead-Acid Batteries Used in Electricon Advances in Lead-Acid Batteries, The Electrochemicalbattery market is for lead-acid batteries for SLI (starting,

  14. Materials Science and Materials Chemistry for Large Scale Electrochemical Energy Storage: From Transportation to Electrical Grid

    SciTech Connect (OSTI)

    Liu, Jun; Zhang, Jiguang; Yang, Zhenguo; Lemmon, John P.; Imhoff, Carl H.; Graff, Gordon L.; Li, Liyu; Hu, Jian Z.; Wang, Chong M.; Xiao, Jie; Xia, Guanguang; Viswanathan, Vilayanur V.; Baskaran, Suresh; Sprenkle, Vincent L.; Li, Xiaolin; Shao, Yuyan; Schwenzer, Birgit

    2013-02-15T23:59:59.000Z

    Large-scale electrical energy storage has become more important than ever for reducing fossil energy consumption in transportation and for the widespread deployment of intermittent renewable energy in electric grid. However, significant challenges exist for its applications. Here, the status and challenges are reviewed from the perspective of materials science and materials chemistry in electrochemical energy storage technologies, such as Li-ion batteries, sodium (sulfur and metal halide) batteries, Pb-acid battery, redox flow batteries, and supercapacitors. Perspectives and approaches are introduced for emerging battery designs and new chemistry combinations to reduce the cost of energy storage devices.

  15. Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications

    SciTech Connect (OSTI)

    None

    2010-10-01T23:59:59.000Z

    BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key parts—a positive and negative electrode and an electrolyte—that exchange ions to store and release electricity. Using different materials for these components changes a battery’s chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

  16. Mathematical modeling of the nickel/metal hydride battery system

    SciTech Connect (OSTI)

    Paxton, B K [Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering

    1995-09-01T23:59:59.000Z

    A group of compounds referred to as metal hydrides, when used as electrode materials, is a less toxic alternative to the cadmium hydroxide electrode found in nickel/cadmium secondary battery systems. For this and other reasons, the nickel/metal hydride battery system is becoming a popular rechargeable battery for electric vehicle and consumer electronics applications. A model of this battery system is presented. Specifically the metal hydride material, LaNi{sub 5}H{sub 6}, is chosen for investigation due to the wealth of information available in the literature on this compound. The model results are compared to experiments found in the literature. Fundamental analyses as well as engineering optimizations are performed from the results of the battery model. In order to examine diffusion limitations in the nickel oxide electrode, a ``pseudo 2-D model`` is developed. This model allows for the theoretical examination of the effects of a diffusion coefficient that is a function of the state of charge of the active material. It is found using present data from the literature that diffusion in the solid phase is usually not an important limitation in the nickel oxide electrode. This finding is contrary to the conclusions reached by other authors. Although diffusion in the nickel oxide active material is treated rigorously with the pseudo 2-D model, a general methodology is presented for determining the best constant diffusion coefficient to use in a standard one-dimensional battery model. The diffusion coefficients determined by this method are shown to be able to partially capture the behavior that results from a diffusion coefficient that varies with the state of charge of the active material.

  17. Cahn-Hilliard Reaction Model for Isotropic Li-ion Battery Particles Yi Zeng1, Martin Z. Bazant1,2

    E-Print Network [OSTI]

    Bazant, Martin Z.

    cathode material for lithium-ion batteries, present ongoing challenges for mathematical modeling. In spite of the fundamental lithium-ion battery dynamics. The first mathematical model on two-phase intercalation dynamicsCahn-Hilliard Reaction Model for Isotropic Li-ion Battery Particles Yi Zeng1, Martin Z. Bazant1,2 1

  18. Sandia National Laboratories: Evaluating Powerful Batteries for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ClimateECEnergyEvaluating Powerful Batteries for Modular Electric Grid Energy Storage Evaluating Powerful Batteries for Modular Electric Grid Energy Storage Sandian Spoke at the...

  19. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    experimental data from plastic lithium ion cells. Journal ofelectrolyte additive for lithium-ion batteries. Elec-A. Aging Mechanisms in Lithium-Ion Batteries. Journal of

  20. Progress in Grid Scale Flow Batteries

    E-Print Network [OSTI]

    2011Year #12;Flow Battery Research at PNNL and Sandia #12 with industries and universities New Generation Redox Flow Batteries, PNNL Developed new generation redox flow

  1. Advanced Battery Manufacturing Facilities and Equipment Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Equipment Program Advanced Battery Manufacturing Facilities and Equipment Program AVTA: 2010 Honda Civic HEV with Experimental Ultra Lead Acid Battery Testing Results...

  2. 'Thirsty' Metals Key to Longer Battery Lifetimes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    needed. In all three cases, today's batteries simply do not hold enough charge. Replacing lithium with other metals with multiple charges could greatly increase battery capacity....

  3. Ionic liquids for rechargeable lithium batteries

    E-Print Network [OSTI]

    Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz, John; Newman, John

    2008-01-01T23:59:59.000Z

    molten salts as lithium battery electrolyte,” ElectrochimicaFigure 15. Rechargeable lithium-ion battery. Figure 16 showsbattery. It is essential that an ionic liquid – lithium salt

  4. Upgrading the Vanadium Redox Battery | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Upgrading the Vanadium Redox Battery Upgrading the Vanadium Redox Battery New electrolyte mix increases energy storage by 70 percent After developing a more effective...

  5. Washington: Graphene Nanostructures for Lithium Batteries Recieves...

    Energy Savers [EERE]

    Washington: Graphene Nanostructures for Lithium Batteries Recieves 2012 R&D 100 Award Washington: Graphene Nanostructures for Lithium Batteries Recieves 2012 R&D 100 Award February...

  6. Promising Magnesium Battery Research at ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the current lithium-ion-based car batteries are at the forefront of the automotive industry's research agenda-manufacturers want to build cars with longer battery...

  7. High Capacity Pouch-Type Li-air Batteries

    SciTech Connect (OSTI)

    Wang, Deyu; Xiao, Jie; Xu, Wu; Zhang, Jiguang

    2010-05-05T23:59:59.000Z

    The pouch-type Li-air batteries operated in ambient condition are reported in this work. The battery used a heat sealable plastic membrane as package material, O2¬ diffusion membrane and moisture barrier. The large variation in internal resistance of the batteries is minimized by a modified separator which can bind the cell stack together. The cells using the modified separators show improved and repeatable discharge performances. It is also found that addition of about 20% of 1,2-dimethoxyethane (DME) in PC:EC (1:1) based electrolyte solvent improves can improve the wetability of carbon electrode and the discharge capacities of Li-air batteries, but further increase in DME amount lead to a decreased capacity due to increase electrolyte loss during discharge process. The pouch-type Li-air batteries with the modified separator and optimized electrolyte has demonstrated a specific capacity of 2711 mAh g-1 based on carbon and a specific energy of 344 Wh kg-1 based on the complete batteries including package.

  8. A Failure and Structural Analysis of Block Copolymer Electrolytes for Rechargeable Lithium Metal Batteries

    E-Print Network [OSTI]

    Stone, Gregory Michael

    2012-01-01T23:59:59.000Z

    lithium-ion battery is the most advanced rechargeable battery technology in use today. These batteries

  9. Separator material for electrochemical cells

    DOE Patents [OSTI]

    Cieslak, W.R.; Storz, L.J.

    1991-03-26T23:59:59.000Z

    An electrochemical cell is characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

  10. Breakthrough materials for energy storage

    E-Print Network [OSTI]

    Breakthrough materials for energy storage November 4, 2009 #12;#12;This revolution is happening;Electronics: our early market 5 hours #12;Progress on energy density... #12;Has reached a limit #12;Battery basics Anode Cathode #12;Battery basics Anode Cathode #12;Silicon leads in energy density

  11. Separator material for electrochemical cells

    DOE Patents [OSTI]

    Cieslak, Wendy R. (1166 Laurel Loop NE., Albuquerque, NM 87122); Storz, Leonard J. (2215 Ambassador NE., Albuquerque, NM 87112)

    1991-01-01T23:59:59.000Z

    An electrochemical cell characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

  12. PHEV Battery Cost Assessment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in ManyDepartmentOutreachDepartment ofProgram49,PHEV Battery Cost

  13. Trends in U.S. Venture Capital Investments Related to Energy: 1980 through the Third Quarter of 2010

    SciTech Connect (OSTI)

    Dooley, James J.

    2010-11-08T23:59:59.000Z

    This report documents trends in U.S. venture capital investments over the period 1980 through the third quarter of calendar year 2010 (2010 Q1+Q2+Q3). Particular attention is given to U.S. venture capital investments in the energy/industrial sector over the period 1980-2010 Q1+Q2+Q3 as well as in the more recently created cross-cutting category of CleanTech over the period 1995-2010 Q1+Q2+Q3. During the early 1980s, U.S. venture capital investments in the energy/industrial sector accounted for more than 20% of all venture capital investments. However subsequent periods of low energy prices, the deregulation of large aspects of the energy industry, and the emergence of fast growing new industries like computers (both hardware and software), biotechnology and the Internet quickly reduced the priority accorded to energy/industrial investments. To wit, venture capital investments related to the energy/industrial sector accounted for only 1% of the $132 billion (in real 2010 US$) invested in 2000 by the U.S. venture capital community. The significant increase in the real price of oil that began in 2003-2004 correlates with renewed interest and increased investment by the venture capital community in energy/industrial investment opportunities. Venture capital investments for 2009 for the energy/industrial sector accounted for $2.4 billion or slightly more than 13% of all venture capital invested that year. The total venture capital invested in energy/industrial during the first three quarters of 2010 is close to $2.4 billion accounting for slightly less than 15% of all venture capital investments during the first three quarters of 2010. In 2009, the aggregate amount invested in CleanTech was $2.1 billion (11% of the total US venture capital invested in that lean year) and for the first three quarters of 2010 US venture capital investments in CleanTech have already exceeded $2.8 billion (18% of all US venture capital investments made during the first three quarters of 2010). Between 2004 and 2009, U.S. venture capital investments in energy/industrial as well as CleanTech have more than quadrupled in real terms.

  14. Trends in U.S. Venture Capital Investments Related to Energy: 1980 through the Second Quarter of 2010

    SciTech Connect (OSTI)

    Dooley, James J.

    2010-07-29T23:59:59.000Z

    This report documents trends in U.S. venture capital investments over the period 1980 through the second quarter of calendar year 2010 (2010Q1+Q2). Particular attention is given to U.S. venture capital investments in the energy/industrial sector over the period 1980-2010Q1+Q2 as well as in the more recently created cross-cutting category of CleanTech over the period 1995-2010Q1+Q2. During the early 1980s, U.S. venture capital investments in the energy/industrial sector accounted for more than 20% of all venture capital investments. However subsequent periods of low energy prices, the deregulation of large aspects of the energy industry, and the emergence of fast growing new industries like computers (both hardware and software), biotechnology and the Internet quickly reduced the priority accorded to energy/industrial investments. To wit, venture capital investments related to the energy/industrial sector accounted for only 1% of the $119 billion dollars invested in 2000 by the U.S. venture capital community. The significant increase in the real price of oil that began in 2003-2004 correlates with renewed interest and increased investment by the venture capital community in energy/industrial investment opportunities. Venture capital investments for 2009 for the energy/industrial sector accounted for $2.1 billion or slightly more than 13% of all venture capital invested that year. The total venture capital invested in energy/industrial during the first two quarters of 2010 is close to $1.8 billion accounting for 17% of all venture capital investments during the first two quarters of 2010. In 2009, the aggregate amount invested in CleanTech was $1.8 billion (30% of the total US venture capital invested in that lean year) and for the first two quarters of 2010 US venture capital investments in CleanTech have already exceeded $1.9 billion (19% of all US venture capital investments made during the first half of 2010). Between 2004 and 2009, U.S. venture capital investments in energy/industrial as well as CleanTech have more than quadrupled in real terms.

  15. Battery system with temperature sensors

    DOE Patents [OSTI]

    Wood, Steven J.; Trester, Dale B.

    2012-11-13T23:59:59.000Z

    A battery system to monitor temperature includes at least one cell with a temperature sensing device proximate the at least one cell. The battery system also includes a flexible member that holds the temperature sensor proximate to the at least one cell.

  16. Redox Flow Batteries, a Review

    SciTech Connect (OSTI)

    U. Tennessee Knoxville; U. Texas Austin; McGill U; Weber, Adam Z.; Mench, Matthew M.; Meyers, Jeremy P.; Ross, Philip N.; Gostick, Jeffrey T.; Liu, Qinghua

    2011-07-15T23:59:59.000Z

    Redox flow batteries are enjoying a renaissance due to their ability to store large amounts of electrical energy relatively cheaply and efficiently. In this review, we examine the components of redox flow batteries with a focus on understanding the underlying physical processes. The various transport and kinetic phenomena are discussed along with the most common redox couples.

  17. Composite Metal-hydrogen Electrodes for Metal-Hydrogen Batteries

    SciTech Connect (OSTI)

    Ruckman, M W; Wiesmann, H; Strongin, M; Young, K; Fetcenko, M

    1997-04-01T23:59:59.000Z

    The purpose of this project is to develop and conduct a feasibility study of metallic thin films (multilayered and alloy composition) produced by advanced sputtering techniques for use as anodes in Ni-metal hydrogen batteries. The anodes could be incorporated in thin film solid state Ni-metal hydrogen batteries that would be deposited as distinct anode, electrolyte and cathode layers in thin film devices. The materials could also be incorporated in secondary consumer batteries (i.e. type AF(4/3 or 4/5)) which use electrodes in the form of tapes. The project was based on pioneering studies of hydrogen uptake by ultra-thin Pd-capped metal-hydrogen ratios exceeding and fast hydrogen charging and Nb films, these studies suggested that materials with those of commercially available metal hydride materials discharging kinetics could be produced. The project initially concentrated on gas phase and electrochemical studies of Pd-capped niobium films in laboratory-scale NiMH cells. This extended the pioneering work to the wet electrochemical environment of NiMH batteries and exploited advanced synchrotron radiation techniques not available during the earlier work to conduct in-situ studies of such materials during hydrogen charging and discharging. Although batteries with fast charging kinetics and hydrogen-metal ratios approaching unity could be fabricated, it was found that oxidation, cracking and corrosion in aqueous solutions made pure Nb films-and multiiayers poor candidates for battery application. The project emphasis shifted to alloy films based on known elemental materials used for NiMH batteries. Although commercial NiMH anode materials contain many metals, it was found that 0.24 µm thick sputtered Zr-Ni films cycled at least 50 times with charging efficiencies exceeding 95% and [H]/[M] ratios of 0.7-1.0. Multilayered or thicker Zr-Ni films could be candidates for a thin film NiMH battery that may have practical applications as an integrated power source for modern electronic devices.

  18. Lithium-ion batteries with intrinsic pulse overcharge protection

    DOE Patents [OSTI]

    Chen, Zonghai; Amine, Khalil

    2013-02-05T23:59:59.000Z

    The present invention relates in general to the field of lithium rechargeable batteries, and more particularly relates to the positive electrode design of lithium-ion batteries with improved high-rate pulse overcharge protection. Thus the present invention provides electrochemical devices containing a cathode comprising at least one primary positive material and at least one secondary positive material; an anode; and a non-aqueous electrolyte comprising a redox shuttle additive; wherein the redox potential of the redox shuttle additive is greater than the redox potential of the primary positive material; the redox potential of the redox shuttle additive is lower than the redox potential of the secondary positive material; and the redox shuttle additive is stable at least up to the redox potential of the secondary positive material.

  19. Semi-Solid Flowable Battery Electrodes: Semi-Solid Flow Cells for Automotive and Grid-Level Energy Storage

    SciTech Connect (OSTI)

    2010-09-01T23:59:59.000Z

    BEEST Project: Scientists at 24M are crossing a Li-Ion battery with a fuel cell to develop a semi-solid flow battery. This system relies on some of the same basic chemistry as a standard Li-Ion battery, but in a flow battery the energy storage material is held in external tanks, so storage capacity is not limited by the size of the battery itself. The design makes it easier to add storage capacity by simply increasing the size of the tanks and adding more paste. In addition, 24M's design also is able to extract more energy from the semi-solid paste than conventional Li-Ion batteries. This creates a cost-effective, energy-dense battery that can improve the driving range of EVs or be used to store energy on the electric grid.

  20. Women & early-stage entrepreneurship : examining the impact of the venture funding crisis on male and female-led technology start-ups

    E-Print Network [OSTI]

    Swaminathan, Shuba

    2010-01-01T23:59:59.000Z

    Women in technology have always been a minority and the number of women who are founders of venture backed start-ups is even lower. This research empirically investigates venture capital funding received by entrepreneurs ...