National Library of Energy BETA

Sample records for batch plant p-area

  1. Site Selection for Concrete Batch Plant to Support Plutonium Disposition Facilities at the Savannah River Site

    SciTech Connect (OSTI)

    Wike, L.D.

    2001-06-15

    WSRC conducted a site selection study to identify, assess, and rank candidate sites for an onsite concrete batch plant at the Savannah River Site in the vicinity of F-Area.

  2. The Building and Commissioning of the Batch Pyrolysis Plant in Studsvik, Sweden - 12447

    SciTech Connect (OSTI)

    Lindberg, Maria; Oesterberg, Carl; Vernersson, Thomas

    2012-07-01

    After a sequence of lab scale and bench scale trials the building of a pyrolysis plant could begin at the Studsvik site in Sweden. The facility is primarily aimed at treatment of uranium contaminated organic waste originating at fuel manufacturing plants and other facilities where the main contamination is uranium. The plant is an extension/addition to the already operating incinerator. In order to further widen the waste acceptance criteria the design of the off-gas treatment system does not have the same design as that of the incinerator. The building of the facility began in April 2011, and the first heating of the facility took place in late December, 2011. The site acceptance tests are planned for January, as are the first inactive trials aimed at optimisation of process control. The facility is planned to be operating with radioactive materials from February 2012. The pyrolysis unit is primarily aimed at treatment of uranium contaminated waste, under conditions that facilitate leaching and recovery of the uranium from the ashes. However, a number of other uses are conceivable. The batch fed pyrolysis unit, with its chosen design of the off-gas treatment system, enables treatment of some waste fractions that are difficult to treat in the incinerator. For instance small campaigns, i.e. smaller quantities of waste (typically <5 tonnes), or waste containing high levels of chlorine and sulphur are possible to treat in the pyrolysis unit. The pyrolysis unit is also expected to perform well in the treatment of other 'difficult' waste fractions, for instance waste containing pyrophoric materials, or other types of waste that benefit from the high level of process control, i.e. control of temperature and atmosphere throughout the process, that can be obtained in the pyrolysis unit compared to the incinerator. Furthermore, treatment in the pyrolysis unit minimises the risk of cross contamination between different waste treatment campaigns. This feature is obtained

  3. Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batch Jobs Batch Jobs Overview Batch jobs are jobs that run non-interactively under the control of a "batch script," which is a text file containing a number of job directives and LINUX commands or utilities. Batch scripts are submitted to the "batch system," where they are queued awaiting free resources on Hopper. The batch system on Hopper is known as "Torque." Bare-Bones Batch Script The simplest Hopper batch script will look something like this. #PBS -q regular

  4. Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that run non-interactively under the control of a "batch script," which is a text file (shell script) containing a number of job directives and LINUX commands. Batch scripts are...

  5. Development Of A Macro-Batch Qualification Strategy For The Hanford Tank Waste Treatment And Immobilization Plant

    SciTech Connect (OSTI)

    Herman, Connie C.

    2013-09-30

    The Savannah River National Laboratory (SRNL) has evaluated the existing waste feed qualification strategy for the Hanford Tank Waste Treatment and Immobilization Plant (WTP) based on experience from the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF) waste qualification program. The current waste qualification programs for each of the sites are discussed in the report to provide a baseline for comparison. Recommendations on strategies are then provided that could be implemented at Hanford based on the successful Macrobatch qualification strategy utilized at SRS to reduce the risk of processing upsets or the production of a staged waste campaign that does not meet the processing requirements of the WTP. Considerations included the baseline WTP process, as well as options involving Direct High Level Waste (HLW) and Low Activity Waste (LAW) processing, and the potential use of a Tank Waste Characterization and Staging Facility (TWCSF). The main objectives of the Hanford waste feed qualification program are to demonstrate compliance with the Waste Acceptance Criteria (WAC), determine waste processability, and demonstrate unit operations at a laboratory scale. Risks to acceptability and successful implementation of this program, as compared to the DWPF Macro-Batch qualification strategy, include: Limitations of mixing/blending capability of the Hanford Tank Farm; The complexity of unit operations (i.e., multiple chemical and mechanical separations processes) involved in the WTP pretreatment qualification process; The need to account for effects of blending of LAW and HLW streams, as well as a recycle stream, within the PT unit operations; and The reliance on only a single set of unit operations demonstrations with the radioactive qualification sample. This later limitation is further complicated because of the 180-day completion requirement for all of the necessary waste feed qualification steps. The primary recommendations/changes include the

  6. Transferring Data from Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transferring Data from Batch Jobs Transferring Data from Batch Jobs Examples Once you are set up for automatic authentication (see HPSS Passwords) you can access HPSS within batch...

  7. Submitting Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Submitting Batch Jobs Submitting Batch Jobs Debug Jobs Short jobs requesting less than 30 minutes and requiring 512 nodes (2,048 cores) or fewer can run in the debug queue. From 5am-6pm Pacific Time, 256 nodes are reserved for debugging and interactive use. See also, running Interactive Jobs. Sample Batch Scripts The following batch script requests 8 cores on 2 nodes with a 10 minute wall clock limit in the debug queue. Torque directive lines tell the batch system how to run a job and begin with

  8. P-Area Acid/Caustic Basin groundwater monitoring report, fourth quarter 1991 and 1991 summary

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    During fourth quarter 1991, samples from the PAC monitoring wells at the P-Area Acid/Caustic Basin of Savannah River Plant were analyzed for indicator parameters, turbidity, major ions, volatile organic compounds, radionuclides, and other constituents. Monitoring results that exceeded the US Environmental Protection Agency Primary Drinking Water Standards (PDWS) and the Savannah River Site (SRS) flagging criteria and turbidity standards during the quarter, with summary results for the year, are presented in this report.

  9. Running Interactive Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interactive Batch Jobs Running Interactive Batch Jobs You cannot login to the PDSF batch nodes directly but you can run an interactive session on a batch node using either qlogin or qsh. This can be useful if you are doing something that is potentially disruptive or if the interactive nodes are overloaded. qlogin will give you an interactive session in the same window as your original session on PDSF, however, you must have your ssh keys in place. You can do this locally on PDSF by following

  10. Example Batch Scripts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Example Batch Scripts Example Batch Scripts Sample Batch Scripts One of the most noted differences between the Hopper system and other NERSC systems is the number of cores per node is NOT a power of two. This means if you want to run a job on 32 cores, two nodes will be used and some cores will remain idle. Basic Batch Script This script uses the default 24 cores per node, (except on the remainder node when the number of cores requested is not a multiple of 24) #PBS -q debug #PBS -l

  11. Example Hopper Batch Scripts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    batch system must wait for the desired big memory nodes to become available. Running Hybrid MPIOpenMP Applications Hybrid MPIOpenMP Example: New Recommendations (recommended)...

  12. P-Area Acid/Caustic Basin groundwater monitoring report

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1993-03-01

    During fourth quarter 1992, samples from the six PAC monitoring wells at the P-Area Acid/Caustic Basin were analyzed for indicator parameters, groundwater quality parameters, and parameters characterizing suitability as a drinking water supply. Monitoring results that exceeded the final Primary Drinking Water Standards (PDWS) or the Savannah River Site (SRS) flagging criteria or turbidity standard during the quarter are discussed in this report. During fourth quarter 1992, a sample from well PAC 6 exceeded the SRS turbidity standard. Iron and manganese each exceeded its Flag 2 criterion in wells PAC 2, 5, and 6. No analytes exceeded the final PDWS in wells at the P-Area Acid/Caustic Basin during 1992.

  13. SCOPING SUMMARY FOR THE P-AREA OPERABLE UNIT

    SciTech Connect (OSTI)

    Kupar, J; Sadika Baladi, S; Mark Amidon, M

    2007-05-22

    This scoping summary supports development of the combined Remedial Investigation (RI)/Baseline Risk Assessment (BRA)/Feasibility Study (FS) for the P-Area Operable Unit (PAOU), or Combined document, which will be submitted on or before 09/28/2007. The objective of this Feasibility Study scoping summary meeting is to agree on the likely response actions to be evaluated and developed as alternatives in the combined document and agree on the uncertainties identified and whether they have been adequately managed.

  14. P-Area Acid/Caustic Basin groundwater monitoring report: Second quarter 1992

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-09-01

    During second quarter 1992, samples from the six PAC monitoring wells at the P-Area Acid/Caustic Basin of Savannah River Plant were analyzed for herbicides, indicator parameters, major ions, pesticides, radionuclides, turbidity and other constituents. Monitoring results that exceeded the US Environmental Protection Agency Primary Drinking Water Standards (PDWS) or the Savannah River Site (SRS) flagging criteria and turbidity standards during the quarter, are discussed in this report. Sulfate exceeded the PDWS in well PAC 5 at the P-Area Acid/Caustic Basin. No wells exceeded the SRS turbidity standard during second quarter 1992. Total organic halogens exceeded the Flag 2 criterion in well PAC 1; iron exceeded the Flag 2 criterion in wells PAC 1, 2, and 6; and manganese exceeded the Flag 2 criterion in wells PAC 2, 5, and 6.

  15. P-Area Acid/Caustic Basin groundwater monitoring report, first quarter 1992

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-06-01

    During first quarter 1992, samples from the six PAC monitoring wells at the P-Area Acid/Caustic Basin of Savannah River Plant were analyzed for herbicides, indicator parameters, major ions, pesticides, radionuclides, turbidity, volatile organic compounds, and other constituents. Monitoring results that exceeded the US Environmental Protection Agency Primary Drinking Water Standards (PDWS) and the Savannah River Site (SRS) flagging criteria and turbidity standards during the quarter are discussed in this report. No constituent exceeded the PDWS in the PAC wells at the P-Area Acid/Caustic Basin and no wells exceeded the SRS turbidity standard during first quarter 1992. Total organic halogens exceeded the Flag 2 criterion in wells PAC 1, 2, 3, 4, and 6; iron exceeded the Flag 2 Criterion in Wells PAC 2, 5, and 6; and manganese exceeded the Flag 2 criterion in wells PAC 5 and 6.

  16. Example batch scripts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Example batch scripts Example batch scripts Access to the BurstBuffer resource is integrated with the Scheduler of the system (i.e. SLURM). The Scheduler provides the ability to provision the BurstBuffer resource to be shared by a set of users or jobs. Using the Burst Buffer on Cori Phase 1 can be as simple as adding a line to your slurm batch script. Here we give examples of how to use the Burst Buffer as a scratch space and as a persistent reservation, and how to stage data in and out of the

  17. Submitting Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The following batch script requests 8 cores on 2 nodes with a 10 minute wall clock limit ... runs since it is the user's intention to exceed wall clock limit for the first job. ...

  18. Parallel Batch Scripts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Parallel Batch Scripts Parallel Batch Scripts Parallel Environments on Genepool You can run parallel jobs that use MPI or OpenMP on Genepool as long as you make the appropriate changes to your submission script! To investigate the parallel environments that are available on Genepool, you can use Command Description qconf -sp <pename> Show the configuration for the specified parallel environment. qconf -spl Show a list of all currently configured parallel environments. Basic Parallel

  19. Example Batch Scripts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Example Batch Scripts Example Batch Scripts Here are some sample job scripts that cover the most of the use cases on Edison. If you find anything that you need is missing, please let us know at consult at nersc dot gov. Note, Edison queue may still undergo configuration change as we gain more insight about how Slurm works with Edison workload. Basic Job Scripts #!/bin/bash -l #SBATCH -p regular #SBATCH -N 2 #SBATCH -t 04:00:00 #SBATCH -J my_job #SBATCH -o my_job.o%j #SBATCH -L SCRATCH,project

  20. Batch Script Examples

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batch Script Examples Batch Script Examples My First Script This is a simple example that you can use to make sure that your settings are correct before submitting more complicated jobs. First, copy the contents of hello.sh into a file. genepool% cat hello.sh #!/bin/bash sleep 120 echo "Hello World" Then submit your job with the qsub command genepool% qsub hello.sh Monitor your job with the qstat command: genepool% qs -u <username> You can also get more detailed information about

  1. Savannah River Site - P-Area Groundwater Operable Unit | Department of

    Office of Environmental Management (EM)

    Energy P-Area Groundwater Operable Unit Savannah River Site - P-Area Groundwater Operable Unit January 1, 2013 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName, State: Savannah River Site, SC Responsible DOE Office: Savannah River Site Plume Name: P-Area Groundwater Operable Unit Remediation Contractor: Savannah River Nuclear Solutions, LLC PBS Number: 30 Report Last Updated: 2013 Contaminants Halogenated VOCs/SVOCs Present?: Yes VOC

  2. NDA BATCH 2009-7

    SciTech Connect (OSTI)

    Lawrence Livermore National Laboratory

    2009-10-30

    The testing facility is LLNL plutonium facility segmented gamma scanner. 100% of the radioassay data in the batch data report is reviewed.

  3. Transferring Data from Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transferring Data from Batch Jobs Transferring Data from Batch Jobs Examples Once you are set up for automatic authentication (see HPSS Passwords) you can access HPSS within batch scripts. You can add the following lines at the end of your batch script. HSI will accept one-line commands on the HSI command line, e.g., hsi put filename HSI, ftp and pftp read from the standard input (stdin) and a list of commands can be placed in a text file (script) and redirected into the given utility, e.g., htp

  4. Using the PDSF Batch System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    System Using the PDSF Batch System Submitting PDSF Jobs An introduction to submitting jobs to the PDSF batch system. Read More » I/O Resources I/O resources are an essential tool at PDSF, please use them. Read More » Running Interactive Batch Jobs When you should consider working in an interactive batch session and how to do it. Read More » Monitoring and Managing Jobs How to check on your jobs after you have submitted them. Read More » Using Job Arrays Using job arrays helps reduce the load

  5. Progressing batch hydrolysis process

    DOE Patents [OSTI]

    Wright, John D.

    1986-01-01

    A progressive batch hydrolysis process for producing sugar from a lignocellulosic feedstock, comprising passing a stream of dilute acid serially through a plurality of percolation hydrolysis reactors charged with said feedstock, at a flow rate, temperature and pressure sufficient to substantially convert all the cellulose component of the feedstock to glucose; cooling said dilute acid stream containing glucose, after exiting the last percolation hydrolysis reactor, then feeding said dilute acid stream serially through a plurality of prehydrolysis percolation reactors, charged with said feedstock, at a flow rate, temperature and pressure sufficient to substantially convert all the hemicellulose component of said feedstock to glucose; and cooling the dilute acid stream containing glucose after it exits the last prehydrolysis reactor.

  6. Progressing batch hydrolysis process

    DOE Patents [OSTI]

    Wright, J.D.

    1985-01-10

    A progressive batch hydrolysis process is disclosed for producing sugar from a lignocellulosic feedstock. It comprises passing a stream of dilute acid serially through a plurality of percolation hydrolysis reactors charged with feed stock, at a flow rate, temperature and pressure sufficient to substantially convert all the cellulose component of the feed stock to glucose. The cooled dilute acid stream containing glucose, after exiting the last percolation hydrolysis reactor, serially fed through a plurality of pre-hydrolysis percolation reactors, charged with said feedstock, at a flow rate, temperature and pressure sufficient to substantially convert all the hemicellulose component of said feedstock to glucose. The dilute acid stream containing glucose is cooled after it exits the last prehydrolysis reactor.

  7. Batch extracting process using magneticparticle held solvents...

    Office of Scientific and Technical Information (OSTI)

    Patent: Batch extracting process using magneticparticle held solvents Citation Details In-Document Search Title: Batch extracting process using magneticparticle held solvents A ...

  8. Batch compositions for cordierite ceramics

    DOE Patents [OSTI]

    Hickman, David L.

    1994-07-26

    Ceramic products consisting principally of cordierite and a method for making them are provided, the method employing batches comprising a mineral component and a chemical component, the mineral component comprising clay and talc and the chemical component consisting essentially of a combination of the powdered oxides, hydroxides, or hydrous oxides of magnesium, aluminum and silicon. Ceramics made by extrusion and firing of the batches can exhibit low porosity, high strength and low thermal expansion coefficients.

  9. NDA BATCH 2002-02

    SciTech Connect (OSTI)

    Lawrence Livermore National Laboratory

    2009-12-09

    QC sample results (daily background checks, 20-gram and 100-gram SGS drum checks) were within acceptable criteria established by WIPP's Quality Assurance Objectives for TRU Waste Characterization. Replicate runs were performed on 5 drums with IDs LL85101099TRU, LL85801147TRU, LL85801109TRU, LL85300999TRU and LL85500979TRU. All replicate measurement results are identical at the 95% confidence level as established by WIPP criteria. Note that the batch covered 5 weeks of SGS measurements from 23-Jan-2002 through 22-Feb-2002. Data packet for SGS Batch 2002-02 generated using gamma spectroscopy with the Pu Facility SGS unit is technically reasonable. All QC samples are in compliance with established control limits. The batch data packet has been reviewed for correctness, completeness, consistency and compliance with WIPP's Quality Assurance Objectives and determined to be acceptable. An Expert Review was performed on the data packet between 28-Feb-02 and 09-Jul-02 to check for potential U-235, Np-237 and Am-241 interferences and address drum cases where specific scan segments showed Se gamma ray transmissions for the 136-keV gamma to be below 0.1 %. Two drums in the batch showed Pu-238 at a relative mass ratio more than 2% of all the Pu isotopes.

  10. P-Area Acid/Caustic Basin groundwater monitoring report, second quarter 1994

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    During second quarter 1994, groundwater from the six PAC monitoring wells at the P-Area Acid/Caustic Basin was analyzed for herbicides/pesticides, radium-226, radium-228, turbidity, and comprehensive constituents. Monitoring results that exceeded the final Primary Drinking Water Standards (PDWS) or the Savannah River Site (SRS) flagging criteria or turbidity standard during the quarter are discussed in this report. During second quarter 1994, no constituents exceeded the final PDWS. Aluminum exceeded its SRS Flag 2 criterion in five PAC wells. Iron and manganese exceeded Flag 2 criteria in three wells, while specific conductance was elevated in one well. Groundwater flow direction and rate in the water table beneath the P-Area Acid/Caustic Basin were similar to past quarters.

  11. P-AREA WETLAND STUDIES SOILS AND BIOTA Final Project Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P-AREA WETLAND STUDIES SOILS AND BIOTA Final Project Report Savannah River Ecology Laboratory University of Georgia Drawer E Aiken, SC 29802 June 2012 SREL Contacts: Stacey L. Lance (lance@srel.edu) John C. Seaman (seaman@srel.edu) David E. Scott (scott@srel.edu) A. Lawrence Bryan, Jr. (lbryan@srel.edu) Julian H. Singer (singer@srel.edu) ii TABLE OF CONTENTS LIST OF ACRONYMS AND ABBREVIATIONS ................................................................................... III EXECUTIVE

  12. P-Area Acid/Caustic Basin groundwater monitoring report, third quarter 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    During third quarter 1992, samples from the six PAC monitoring wells at the P-Area Acid/Caustic Basin were analyzed for indicator parameters, groundwater quality parameters, and parameters characterizing suitability as a drinking water supply. Monitoring results that exceeded the US Environmental Protection Agency's Primary Drinking Water Standards (PDWS) or the Savannah River Site (SRS) flagging criteria or turbidity standards during the quarter are discussed in this report.

  13. Your Unanswered Questions…. Answered- Batch 2

    Broader source: Energy.gov [DOE]

    Secretary Chu hosted an online town hall to discuss President Obama's clean energy innovation agenda -- and while he was able to answer about 10 questions submitted online during the event, we received more than 200! Here is our second batch of questions and answers.

  14. Heidi Poxon Cobalt Batch System on Theta

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Running and Tuning Programs on Cray XC Systems with KNL Heidi Poxon Cobalt Batch System on Theta 2 EXAMPLE: qsub -n 2 -t 15 --mode script -A Theta_ESP -q cache-quad --env OMP_NUM_THREADS=16 \ ./runScript qsub -n <number of nodes> -t <wallclock time> --mode script -A <project(allocation)> \ -q <queue> --env <var1=value1:var2=value2....> myScriptFile #!/bin/bash -evx # Command line options will override the three settings below: #COBALT -t 5 #COBALT -q cache-quad

  15. TANK 50 BATCH 0 SALTSTONE FORMULATION CONFIRMATION

    SciTech Connect (OSTI)

    Langton, C.

    2006-06-05

    Savannah River National Laboratory (SRNL) personnel were requested to confirm the Tank 50 Batch 0 grout formulation per Technical Task Request, SSF-TTR-2006-0001 (task 1 of 2) [1]. Earlier Batch 0 formulation testing used a Tank 50 sample collected in September 2005 and is described elsewhere [2]. The current testing was performed using a sample of Tank 50 waste collected in May 2006. This work was performed according to the Technical Task and Quality Assurance Plan (TT/QAP), WSRC-RP-2006-00594 [3]. The salt solution collected from Tank 50 in May 2006 contained approximately 3 weight percent more solids than the sample collected in September 2005. The insoluble solids took longer to settle in the new sample which was interpreted as indicating finer particles in the current sample. The saltstone formulation developed for the September 2005 Tank 50 Batch 0 sample was confirmed for the May 2006 sample with one minor exception. Saltstone prepared with the Tank 50 sample collected in May 2006 required 1.5 times more Daratard 17 set retarding admixture than the saltstone prepared with the September In addition, a sample prepared with lower shear mixing (stirring with a spatula) had a higher plastic viscosity (57 cP) than samples made with higher shear mixing in a blender (23cP). The static gel times of the saltstone slurries made with low shear mixing were also shorter ({approx}32 minutes) than those for comparable samples made in the blender ({approx}47 minutes). The addition of the various waste streams (ETP, HEU-HCAN, and GPE-HCAN) to Tank 50 from September 2005 to May 2006 has increased the amount of set retarder, Daratard 17, required for processing saltstone slurries through the Saltstone facility. If these streams are continued to be added to Tank 50, the quantity of admixtures required to maintain the same processing conditions for the Saltstone facility will probably change and additional testing is recommended to reconfirm the Tank 50 Saltstone formulation.

  16. Uranium and Strontium Batch Sorption and Diffusion Kinetics into...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Uranium and Strontium Batch Sorption and Diffusion Kinetics into Mesoporous Silica Friday, ... and fate of radioactive material such as uranium (U) and strontium (Sr) in the environment ...

  17. Proof of concept and performance optimization of high gravity batch type centrifuge for dewatering fine coal

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.E. Jr.

    1991-04-23

    Coal Technology Corporation (CTC) believes that the new CTC high gravity, high production, batch type centrifugal dryer technology can play a significant role in improving the product quality as well as costs of operation in coal processing plants. It is further believed that the new centrifugal dryer technology can form an important part in systems used to clean up millions of tons of coal fines in refuse piles and ponds. It is anticipated that the new centrifuge can become an important ancillary to the advanced deep cleaning processes for coal. Because of these convictions, CTC has been engaged in a pioneering research effort into the new art of drying fine clean coal in high gravity, high production, batch type of centrifuge, since 1981. This work has progressed to the point where the new centrifugal dryer technology is nearly ready for commercialization. It promises to provide needed fine coal drying capability at somewhat lower capital costs and at substantially lower operating costs than competitive systems. It also promises to do so with no detrimental effects on either the coal quality or the environment. The primary objective of this project is to prove the concept of a high gravity batch centrifuge for drying coal fines in a commercial coal processing plant environment. The proof of concept tests also include testing with a variety of coals from different regions. A further objective is to optimize the efficiency and the cost effectiveness of the new centrifugal dryer technology. 2 figs., 3 tabs.

  18. What to expect from a batch solar water heater

    SciTech Connect (OSTI)

    Stickney, B.

    1984-01-01

    Batch solar water heaters are becoming more popular because of their low initial cost and simplicity of operation. Batch type water heaters have the following features in common: a water tank or tanks, an insulated tank enclosure, a glazed collecter surface, and a reflector system. The advantages of this type of solar water heater are discussed.

  19. SLUDGE BATCH VARIABILITY STUDY WITH FRIT 418

    SciTech Connect (OSTI)

    Johnson, F.; Edwards, T.

    2010-11-29

    The Defense Waste Processing Facility (DWPF) initiated processing Sludge Batch 6 (SB6) in the summer of 2010. In support of processing, the Savannah River National Laboratory (SRNL) provided a recommendation to utilize Frit 418 to process SB6. This recommendation was based on assessments of the compositional projections for SB6 available at the time from the Liquid Waste Organization (LWO) and SRNL (using a model-based approach). To support qualification of SB6, SRNL executed a variability study to assess the applicability of the current durability models for SB6. The durability models were assessed over the expected Frit 418-SB6 composition range. Seventeen glasses were selected for the variability study based on the sludge projections used in the frit recommendation. Five of the glasses are based on the centroid of the compositional region, spanning a waste loading (WL) range of 32 to 40%. The remaining twelve glasses are extreme vertices (EVs) of the sludge region of interest for SB6 combined with Frit 418 and are all at 36% WL. These glasses were fabricated and characterized using chemical composition analysis, X-ray diffraction (XRD) and the Product Consistency Test (PCT). After initiating the SB6 variability study, the measured composition of the SB6 Tank 51 qualification glass produced at the SRNL Shielded Cells Facility indicated that thorium was present in the glass at an appreciable concentration (1.03 wt%), which made it a reportable element for SB6. This concentration of ThO{sub 2} resulted in a second phase of experimental studies. Five glasses were formulated that were based on the centroid of the new sludge compositional region combined with Frit 418, spanning a WL range of 32 to 40%. These glasses were fabricated and characterized using chemical composition analysis and the PCT. Based on the measured PCT response, all of the glasses (with and without thorium) were acceptable with respect to the Environmental Assessment (EA) reference glass

  20. SLUDGE BATCH 7B GLASS VARIABILITY STUDY

    SciTech Connect (OSTI)

    Johnson, F.; Edwards, T.

    2011-10-25

    The Defense Waste Processing Facility (DWPF) is preparing to initiate processing Sludge Batch 7b (SB7b). In support of the upcoming processing, the Savannah River National Laboratory (SRNL) provided a recommendation to utilize Frits 418 with a 6% Na{sub 2}O addition (26 wt% Na{sub 2}O in sludge) and 702 with a 4% Na{sub 2}O addition (24 wt% Na{sub 2}O in sludge) to process SB7b. This recommendation was based on assessments of the compositional projections for SB7b available at the time from the Savannah River Remediation (SRR). To support qualification of SB7b, SRNL executed a variability study to assess the applicability of the current durability models for SB7b. The durability models were assessed over the expected composition range of SB7b, including potential caustic additions, combined with Frits 702 and 418 over a 32-40% waste loading (WL) range. Thirty four glasses were selected based on Frits 418 and 702 coupled with the sludge projections with an additional 4-6% Na{sub 2}O to reflect the potential caustic addition. Six of these glasses, based on average nominal sludge compositions including the appropriate caustic addition, were developed for both Frit 418 and Frit 702 at 32, 36 and 40% WL to provide coverage in the center of the anticipated SB7b glass region. All glasses were fabricated and characterized using chemical composition analysis, X-ray diffraction (XRD) and the Product Consistency Test (PCT). To comply with the DWPF Glass Product Control Program, a total of thirty four glasses were fabricated to assess the applicability of the current DWPF PCCS durability models. Based on the measured PCT response, all of the glasses were acceptable with respect to the Environmental Assessment (EA) benchmark glass regardless of thermal history. The NL[B] values of the SB7b variability study glasses were less than 1.99 g/L as compared to 16.695 g/L for EA. A small number of the D-optimally selected 'outer layer' extreme vertices (EV) glasses were not predictable

  1. Proof of concept and performance optimization of high gravity batch type centrifuge for dewatering fine coal

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.E. Jr.

    1990-07-24

    Coal Technology Corporation (CTC) believes that the new CTC high gravity, high production, batch type centrifugal dryer technology can play a significant role in improving the product quality as well as costs of operation in coal processing plants. It is further believed that the new centrifugal dryer technology can form an important part in systems used to clean up the millions of tons of coal fines in refuse piles and ponds. It is anticipated that the new centrifuge can become an important ancillary to the advanced deep cleaning processes for coal. Because of these convictions, CTC has been engaged in a pioneering research effort into the new art of drying fine clean coal in high gravity, high production, batch type centrifuges, since 1981. This work has progressed to the point where the new centrifugal dryer technology is nearly ready for commercialization. It promises to provide needed fine coal drying capability at somewhat lower capital costs and at substantially lower operating costs than competitive systems. It also promises to do so with no detrimental effects on either the coal quality or the evironment. The primary objective of this project is to prove the concept in a commercial coal processing plant environment. The proof of concept tests will also include testing with a variety of coals from different regions. A further objective will be to optimize the efficiency and the cost effectiveness of the new centrifugal dryer technology.

  2. Small Scale Mixing Demonstration Batch Transfer and Sampling Performance of Simulated HLW - 12307

    SciTech Connect (OSTI)

    Jensen, Jesse; Townson, Paul; Vanatta, Matt

    2012-07-01

    The ability to effectively mix, sample, certify, and deliver consistent batches of High Level Waste (HLW) feed from the Hanford Double Shell Tanks (DST) to the Waste treatment Plant (WTP) has been recognized as a significant mission risk with potential to impact mission length and the quantity of HLW glass produced. At the end of 2009 DOE's Tank Operations Contractor, Washington River Protection Solutions (WRPS), awarded a contract to EnergySolutions to design, fabricate and operate a demonstration platform called the Small Scale Mixing Demonstration (SSMD) to establish pre-transfer sampling capacity, and batch transfer performance data at two different scales. This data will be used to examine the baseline capacity for a tank mixed via rotational jet mixers to transfer consistent or bounding batches, and provide scale up information to predict full scale operational performance. This information will then in turn be used to define the baseline capacity of such a system to transfer and sample batches sent to WTP. The Small Scale Mixing Demonstration (SSMD) platform consists of 43'' and 120'' diameter clear acrylic test vessels, each equipped with two scaled jet mixer pump assemblies, and all supporting vessels, controls, services, and simulant make up facilities. All tank internals have been modeled including the air lift circulators (ALCs), the steam heating coil, and the radius between the wall and floor. The test vessels are set up to simulate the transfer of HLW out of a mixed tank, and collect a pre-transfer sample in a manner similar to the proposed baseline configuration. The collected material is submitted to an NQA-1 laboratory for chemical analysis. Previous work has been done to assess tank mixing performance at both scales. This work involved a combination of unique instruments to understand the three dimensional distribution of solids using a combination of Coriolis meter measurements, in situ chord length distribution measurements, and electro

  3. STATISTICAL EVALUATION OF SMALL SCALE MIXING DEMONSTRATION SAMPLING AND BATCH TRANSFER PERFORMANCE - 12093

    SciTech Connect (OSTI)

    GREER DA; THIEN MG

    2012-01-12

    The ability to effectively mix, sample, certify, and deliver consistent batches of High Level Waste (HLW) feed from the Hanford Double Shell Tanks (DST) to the Waste Treatment and Immobilization Plant (WTP) presents a significant mission risk with potential to impact mission length and the quantity of HLW glass produced. DOE's Tank Operations Contractor, Washington River Protection Solutions (WRPS) has previously presented the results of mixing performance in two different sizes of small scale DSTs to support scale up estimates of full scale DST mixing performance. Currently, sufficient sampling of DSTs is one of the largest programmatic risks that could prevent timely delivery of high level waste to the WTP. WRPS has performed small scale mixing and sampling demonstrations to study the ability to sufficiently sample the tanks. The statistical evaluation of the demonstration results which lead to the conclusion that the two scales of small DST are behaving similarly and that full scale performance is predictable will be presented. This work is essential to reduce the risk of requiring a new dedicated feed sampling facility and will guide future optimization work to ensure the waste feed delivery mission will be accomplished successfully. This paper will focus on the analytical data collected from mixing, sampling, and batch transfer testing from the small scale mixing demonstration tanks and how those data are being interpreted to begin to understand the relationship between samples taken prior to transfer and samples from the subsequent batches transferred. An overview of the types of data collected and examples of typical raw data will be provided. The paper will then discuss the processing and manipulation of the data which is necessary to begin evaluating sampling and batch transfer performance. This discussion will also include the evaluation of the analytical measurement capability with regard to the simulant material used in the demonstration tests. The

  4. Comparative performance indices for solar batch water heaters

    SciTech Connect (OSTI)

    Stickney, B.L.; Aaboe, E.H.

    1981-01-01

    A simple method is developed to allow direct comparison of various solar batch water heaters. Certain system variables must be determined by calculation or measurement which may vary with season. These include Thermal Efficiency of Collection, Tank R value, Collector Surface to Tank Volume Ratio, Clear Day Collection Period in Hours, System Cost, and Installed Solar Heatings Fraction (optional). These variables are used to compute any one of four performance indices. This method allows a valid comparison not only between various solar batch water heaters but between other types of solar water heaters as well. This system may be used by consumers or designers to choose the most cost and performance effective options.

  5. HIGH LEVEL WASTE SLUDGE BATCH 4 VARIABILITY STUDY

    SciTech Connect (OSTI)

    Fox, K; Tommy Edwards, T; David Peeler, D; David Best, D; Irene Reamer, I; Phyllis Workman, P

    2006-10-02

    The Defense Waste Processing Facility (DWPF) is preparing for vitrification of High Level Waste (HLW) Sludge Batch 4 (SB4) in early FY2007. To support this process, the Savannah River National Laboratory (SRNL) has provided a recommendation to utilize Frit 503 for vitrifying this sludge batch, based on the composition projection provided by the Liquid Waste Organization on June 22, 2006. Frit 418 was also recommended for possible use during the transition from SB3 to SB4. A critical step in the SB4 qualification process is to demonstrate the applicability of the durability models, which are used as part of the DWPF's process control strategy, to the glass system of interest via a variability study. A variability study is an experimentally-driven assessment of the predictability and acceptability of the quality of the vitrified waste product that is anticipated from the processing of a sludge batch. At the DWPF, the durability of the vitrified waste product is not directly measured. Instead, the durability is predicted using a set of models that relate the Product Consistency Test (PCT) response of a glass to the chemical composition of that glass. In addition, a glass sample is taken during the processing of that sludge batch, the sample is transmitted to SRNL, and the durability is measured to confirm acceptance. The objective of a variability study is to demonstrate that these models are applicable to the glass composition region anticipated during the processing of the sludge batch - in this case the Frit 503 - SB4 compositional region. The success of this demonstration allows the DWPF to confidently rely on the predictions of the durability/composition models as they are used in the control of the DWPF process.

  6. Utilisation of single added fatty acids by consortia of digester sludge in batch culture

    SciTech Connect (OSTI)

    Wagner, Andreas Otto; Gstrauntaler, Gudrun; Illmer, Paul

    2010-10-15

    Inocula derived from an anaerobic digester were used to study (i) their potential for methane production and (ii) the utilisation rates of different short chain fatty acids (SCFAs) by the microbial community in defined media with mono-carbon sources (formic-, acetetic-, propionic-, butyric acid) in batch culture. It could be demonstrated that the microbial reactor population could be transferred successfully to the lab, and its ability to build up methane was present even with deteriorating biogas plant performance. Therefore, this reduction in performance of the biogas plant was not due to a decrease in abundance, but due to an inactivity of the microbial community. Generally, the physico-chemical properties of the biogas plant seemed to favour hydrogenotrophic methanogens, as seen by the high metabolisation rates of formate compared with all other carbon sources. In contrast, acetoclastic methanogenesis could be shown to play a minor role in the methane production of the investigated biogas plant, although the origin of up to 66% of methane is generally suggested to be generated through acetoclastic pathway.

  7. Batch drilling program cuts time, costs for Liuhua development

    SciTech Connect (OSTI)

    Gray, G.E.; Hall, K.H.; Mu, H.C.

    1996-08-12

    The efficiency of batch drilling operations and the appropriate use of technology, teamwork, and thorough planning helped cut several days off the time to drill each of 10 subsea wells for the Liuhua 11-1 development project in the South China Sea. The overall development program calls for drilling and completing 20 subsea horizontal wells. The rig-of-opportunity phase was the initial phase of this development and used a contract rig to establish the subsea wellhead array and initiate drilling of the development wells. The wellhead array was the first critical step. It was the foundation for the building block construction process used to create Liuhua`s subsea production system on the seabed. The paper discusses conductor operations, batch drilling operations, surface hole section, intermediate and production hole sections, the ten wells, application of technology, and overall results.

  8. Using Sleepers to Manage Batch Access to HPSS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sleepers Using Sleepers to Manage Batch Access to HPSS Sleepers are only available using the HSI or PFTP clients from NERSC production machines. When scheduled maintenance or unexpected events necessitate taking HPSS down "sleepers" are enabled. This causes all jobs attempting to use HPSS to wait. Usually this causes no problems for these jobs which resume safely when sleepers are removed. However, users may wish to test for HPSS system availability and take alternate action if

  9. Farm-scale production of fuel ethanol and wet grain from corn in a batch process

    SciTech Connect (OSTI)

    Westby, C.A.; Gibbons, W.R.

    1982-07-01

    The batch production of fuel grade ethanol and distillers' wet grain (wet solids) in a farm-scale process (1240-15,580 L/batch) is described. The procedure employs yeast fermentation of amylase-treated corn mash and a two-stage distillation. Primary emphasis in this study was on the cooking, fermentation and centrifugation steps. Without recycling, fermentation of the mash yielded beers with 10.0-10.5% ethanol. Recycling of stillage supernatant at full, 75, or 50% strengths produced enriched mashes that after 48-hour fermentation yielded beers with 5-14% more ethanol. Recycling twice with full-strength stillage supernatant at pH 7.0 increased the ethanol yield in the final beer 16.5%; however, the time to complete the final fermentation was extended from 48 to 72 hours and salt buildup occurred. By recycling at pH 5.4, it was possible to avoid salt buildup and obtain beers with 10.3-10.5% ethanol. Recycling resulted in increased levels of glucose, starch, crude protein, and fat in the beer and a reduced moisture content while the wet solids showed an increased starch content. Centrifugation after cooking or fermentation instead of after distillation reduced the mash volume 17-20% and this lowered the ethanol yield in the subsequently produced beer. Fermentation of a volume-restored mash supernatant gave a beer with only 9.25% ethanol. Mash wet solids varied somewhat chemically from beer and stillage solids. An economic and energy balance analysis of various modes of plant operation are provided and plant design considerations are suggested. (Refs. 31).

  10. Microsoft Word - FINAL Rocky Flats LBNL report Batch #1.docx

    Office of Legacy Management (LM)

    the First Batch of Rocky Flats Water Samples Submitted to LBNL John N. Christensen Report date 9/16/13 Thirteen samples were submitted by SM Stoller to Lawrence Berkeley National Laboratory for uranium isotopic and concentration analysis- 12 surface water samples from two sites (WALPOC and GS10) covering the period Sept. 2011 to April 2013, and one groundwater sample taken on 5/14/12 from well 79102 (Table 1). Uranium isotopic compositions of the samples were determined at LBNL by MC- ICPMS

  11. Proof of concept and performance optimization of high gravity batch type centrifuge for dewatering fine coal

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.E. Jr.

    1990-10-24

    Coal Technology Corporation (CTC) believes that the new CTC high gravity, high production, batch type centrifugal dryer technology can play a significant role in improving the product quality as well as costs of operation in coal processing plants. It is further believed that the new centrifugal dryer technology can form an important part in systems used to clean up the millions of tons of coal fines in refuse piles and ponds. Work has progressed to the point where the new centrifugal dryer technology is nearly ready for commercialization. The primary objective of this project is to prove the concept in a commercial coal processing plant environment. The proof of concept tests will include testing with a variety of coals from different regions. A further objective will be to optimize the efficiency and the cost effectiveness of the new centrifugal dryer technology. To supply some perspective on the ability of the new centrifuges to successfully dry a variety of coals from various coal fields, it was decided that coals ranging from very fine to course size consists and with both low and high inherent moistures would be tested. Coals tested include: Pittsburgh no. 8 seam (Pennsylvania), Pittsburgh no. 8 seam (West Virginia), and Blue Creek Seam (Alabama). 6 figs.

  12. FLOWSHEET FOR ALUMINUM REMOVAL FROM SLUDGE BATCH 6

    SciTech Connect (OSTI)

    Pike, J; Jeffrey Gillam, J

    2008-12-17

    Samples of Tank 12 sludge slurry show a substantially larger fraction of aluminum than originally identified in sludge batch planning. The Liquid Waste Organization (LWO) plans to formulate Sludge Batch 6 (SB6) with about one half of the sludge slurry in Tank 12 and one half of the sludge slurry in Tank 4. LWO identified aluminum dissolution as a method to mitigate the effect of having about 50% more solids in High Level Waste (HLW) sludge than previously planned. Previous aluminum dissolution performed in a HLW tank in 1982 was performed at approximately 85 C for 5 days and dissolved nearly 80% of the aluminum in the sludge slurry. In 2008, LWO successfully dissolved 64% of the aluminum at approximately 60 C in 46 days with minimal tank modifications and using only slurry pumps as a heat source. This report establishes the technical basis and flowsheet for performing an aluminum removal process in Tank 51 for SB6 that incorporates the lessons learned from previous aluminum dissolution evolutions. For SB6, aluminum dissolution process temperature will be held at a minimum of 65 C for at least 24 days, but as long as practical or until as much as 80% of the aluminum is dissolved. As planned, an aluminum removal process can reduce the aluminum in SB6 from about 84,500 kg to as little as 17,900 kg with a corresponding reduction of total insoluble solids in the batch from 246,000 kg to 131,000 kg. The extent of the reduction may be limited by the time available to maintain Tank 51 at dissolution temperature. The range of dissolution in four weeks based on the known variability in dissolution kinetics can range from 44 to more than 80%. At 44% of the aluminum dissolved, the mass reduction is approximately 1/2 of the mass noted above, i.e., 33,300 kg of aluminum instead of 66,600 kg. Planning to reach 80% of the aluminum dissolved should allow a maximum of 81 days for dissolution and reduce the allowance if test data shows faster kinetics. 47,800 kg of the dissolved

  13. Low-cost Batch Solar Water Heater research and development project. Final report

    SciTech Connect (OSTI)

    Stickney, B.L.

    1983-06-01

    This report presents a summary of the development and testing of Batch Solar Water Heaters. Batch Heaters tested include several kinds of tank-under-glass (Breadbox) models and several types of Inverted Batch Solar Water Heaters with both fixed and moveable reflector systems. Temperature graphs and tables of performance indices are presented for each water heater tested. An Inverted Batch Water Heater was developed based upon the test results called the Bottomgainer. Two prototypes of the Bottomgainer model were installed and monitored in use on residences. The Bottomgainer concept could be adapted to commercial production.

  14. Increased CPC batch size study for Tank 42 sludge in the Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Daniel, W.E.

    2000-01-06

    A series of experiments have been completed at TNX for the sludge-only REDOX adjusted flowsheet using Tank 42 sludge simulant in response to the Technical Task Request HLW/DWPT/TTR-980013 to increase CPC batch sizes. By increasing the initial SRAT batch size, a melter feed batch at greater waste solids concentration can be prepared and thus increase melter output per batch by about one canister. The increased throughput would allow DWPF to dispose of more waste in a given time period thus shortening the overall campaign.

  15. Uranium Adsorption on Granular Activated Carbon – Batch Testing

    SciTech Connect (OSTI)

    Parker, Kent E.; Golovich, Elizabeth C.; Wellman, Dawn M.

    2013-09-26

    The uranium adsorption performance of two activated carbon samples (Tusaar Lot B-64, Tusaar ER2-189A) was tested using unadjusted source water from well 299-W19-36. These batch tests support ongoing performance optimization efforts to use the best material for uranium treatment in the Hanford Site 200 West Area groundwater pump-and-treat system. A linear response of uranium loading as a function of the solution-to-solid ratio was observed for both materials. Kd values ranged from ~380,000 to >1,900,000 ml/g for the B-64 material and ~200,000 to >1,900,000 ml/g for the ER2-189A material. Uranium loading values ranged from 10.4 to 41.6 g/g for the two Tusaar materials.

  16. Hydrothermal liquefaction of biomass: Developments from batch to continuous process

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Biller, Patrick; Ross, Andrew; Schmidt, Andrew J.; Jones, Susanne B.

    2015-02-01

    This review describes the recent results in hydrothermal liquefaction (HTL) of biomass in continuous-flow processing systems. Although much has been published about batch reactor tests of biomass HTL, there is only limited information yet available on continuous-flow tests, which can provide a more reasonable basis for process design and scale-up for commercialization. High-moisture biomass feedstocks are the most likely to be used in HTL. These materials are described and results of their processing are discussed. Engineered systems for HTL are described however they are of limited size and do not yet approach a demonstration scale of operation. With the results available process models have been developed and mass and energy balances determined. From these models process costs have been calculated and provide some optimism as to the commercial likelihood of the technology.

  17. SULFATE SOLUBILITY LIMIT VERIFICATION FOR DWPF SLUDGE BATCH 7A

    SciTech Connect (OSTI)

    Billings, A.

    2011-04-19

    During processing at the Defense Waste Processing Facility (DWPF), high sulfate concentrations in the feed are a concern to DWPF as it can lead to the formation of a detrimental, sulfate-rich, molten salt phase on the surface of the glass melt pool. To avoid these issues, a sulfate concentration limit was implemented into the Product Composition Control System (PCCS). Related to SB7a frit development efforts, the Savannah River National Laboratory (SRNL) assessed the viability of using the current 0.6 wt % SO{sub 4}{sup 2-} limit set for SB6 (in glass) and the possibility of increasing the SO{sub 4}{sup 2-} solubility limit in PCCS to account for anticipated sulfur concentrations, targeted waste loadings, and inclusion of secondary streams (e.g., Actinide Removal Process (ARP)) with two recommended frits (Frit 418 and Frit 702) for SB7a processing. For a nominal SB7a blend with a 63 inch SB6 heel remaining in Tank 40 (projection SB7a-63), a 0.60 wt% SO{sub 4}{sup 2-} in glass limit was determined for waste loadings of 34 wt% up to 40 wt% with Frit 418 based on crucible melts with batched chemicals. SRNL also examined the inclusion of ARP for the same blending scenario (SB7a-63-ARP) with Frit 418 and at least a 0.6 wt% SO{sub 4}{sup 2-} level, and waste loadings of 34 wt% to 40 wt% were also acceptable. When a visible yellow and/or white sulfate salt layer was visible on the surface of any cooled glass, it was assumed to have surpassed the solubility limit of SO{sub 4}{sup 2-} for that particular composition. All of the glasses fabricated at these concentrations did not exhibit a sulfate rich salt layer on the surface of the glass melt and retained the majority of the batched SO{sub 4}{sup 2-}. At higher levels of SO{sub 4}{sup 2-} 'spiked' into the projected sludge compositions over the aforementioned interval of waste loadings, with Frit 418, low viscosity sulfur layers were observed on the surface of glass melts which confirm exceeding the solubility limit. The

  18. REPORTABLE RADIONUCLIDES IN DWPF SLUDGE BATCH 7A (MACROBATCH 8)

    SciTech Connect (OSTI)

    Reboul, S.; Diprete, D.; Click, D.; Bannochie, C.

    2011-12-20

    The Waste Acceptance Product Specifications (WAPS) 1.2 require that the waste producer 'shall report the curie inventory of radionuclides that have half-lives longer than 10 years and that are, or will be, present in concentrations greater than 0.05 percent of the total inventory for each waste type indexed to the years 2015 and 3115.' As part of the strategy to meet WAPS 1.2, the Defense Waste Processing Facility (DWPF) will report for each waste type all radionuclides that have half-lives longer than 10 years and contribute greater than 0.01 percent of the total curie inventory from the time of production through the 1100 year period from 2015 through 3115. The initial list of radionuclides to be reported is based on the design-basis glass identified in the Waste Form Compliance Plan (WCP) and Waste Form Qualification Report. However, it is required that the list be expanded if other radionuclides with half-lives greater than 10 years are identified that meet the 'greater than 0.01% of the curie inventory' criterion. Specification 1.6 of the WAPS, International Atomic Energy Agency Safeguards Reporting for High Level Waste (HLW), requires that the ratio by weights of the following uranium and plutonium isotopes be reported: U-233, U-234, U-235, U-236, and U-238; and Pu-238, Pu-239, Pu-240, Pu-241, and Pu-242. Therefore, the complete list of reportable radionuclides must also include these sets of U and Pu isotopes - and the U and Pu isotopic mass distributions must be identified. The DWPF receives HLW sludge slurry from Savannah River Site (SRS) Tank 40. For Sludge Batch 7a (SB7a), the waste in Tank 40 contained a blend of the heel from Sludge Batch 6 (SB6) and the Sludge Batch 7 (SB7) material transferred to Tank 40 from Tank 51. This sludge blend is also referred to as Macrobatch 8. Laboratory analyses of a Tank 40 sludge sample were performed to quantify the concentrations of pertinent radionuclides in the SB7a waste. Subsequently, radiological decay and in

  19. SLUDGE BATCH 7 PREPARATION TANK 4 AND 12 CHARACTERIZATION

    SciTech Connect (OSTI)

    Bannochie, C.; Click, D.; Pareizs, J.

    2010-05-21

    Samples of PUREX sludge from Tank 4 and HM sludge from Tank 12 were characterized in preparation for Sludge Batch 7 (SB7) formulation in Tank 51. SRNL analyses on Tank 4 and Tank 12 were requested in separate Technical Assistance Requests (TAR). The Tank 4 samples were pulled on January 19, 2010 following slurry operations by F-Tank Farm. The Tank 12 samples were pulled on February 9, 2010 following slurry operations by H-Tank Farm. At the Savannah River National Laboratory (SRNL), two 200 mL dip samples of Tank 4 and two 200 mL dip samples of Tank 12 were received in the SRNL Shielded Cells. Each tank's samples were composited into clean 500 mL polyethylene storage bottles and weighed. The composited Tank 4 sample was 428.27 g and the composited Tank 12 sample was 502.15 g. As expected there are distinct compositional differences between Tank 4 and Tank 12 sludges. The Tank 12 slurry is much higher in Al, Hg, Mn, and Th, and much lower in Fe, Ni, S, and U than the Tank 4 slurry. The Tank 4 sludge definitely makes the more significant contribution of S to any sludge batch blend. This S, like that observed during SB6 washing, is best monitored by looking at the total S measured by digesting the sample and analyzing by inductively coupled plasma - atomic emission spectroscopy (ICPAES). Alternatively, one can measure the soluble S by ICP-AES and adjust the value upward by approximately 15% to have a pretty good estimate of the total S in the slurry. Soluble sulfate measurements by ion chromatography (IC) will be biased considerably lower than the actual total S, the difference being due to the non-sulfate soluble S and the undissolved S. Tank 12 sludge is enriched in U-235, and hence samples transferred into SRNL from the Tank Farm will need to be placed on the reportable special nuclear material inventory and tracked for total U per SRNL procedure requirements.

  20. Kinetics of steel slag leaching: Batch tests and modeling

    SciTech Connect (OSTI)

    De Windt, Laurent; Chaurand, Perrine; Rose, Jerome

    2011-02-15

    Reusing steel slag as an aggregate for road construction requires to characterize the leaching kinetics and metal releases. In this study, basic oxygen furnace (BOF) steel slag were subjected to batch leaching tests at liquid to solid ratios (L/S) of 10 and 100 over 30 days; the leachate chemistry being regularly sampled in time. A geochemical model of the steel slag is developed and validated from experimental data, particularly the evolution with leaching of mineralogical composition of the slag and trace element speciation. Kinetics is necessary for modeling the primary phase leaching, whereas a simple thermodynamic equilibrium approach can be used for secondary phase precipitation. The proposed model simulates the kinetically-controlled dissolution (hydrolysis) of primary phases, the precipitation of secondary phases (C-S-H, hydroxide and spinel), the pH and redox conditions, and the progressive release of major elements as well as the metals Cr and V. Modeling indicates that the dilution effect of the L/S ratio is often coupled to solubility-controlled processes, which are sensitive to both the pH and the redox potential. A sensitivity analysis of kinetic uncertainties on the modeling of element releases is performed.

  1. Methods for batch fabrication of cold cathode vacuum switch tubes

    DOE Patents [OSTI]

    Walker, Charles A.; Trowbridge, Frank R.

    2011-05-10

    Methods are disclosed for batch fabrication of vacuum switch tubes that reduce manufacturing costs and improve tube to tube uniformity. The disclosed methods comprise creating a stacked assembly of layers containing a plurality of adjacently spaced switch tube sub-assemblies aligned and registered through common layers. The layers include trigger electrode layer, cathode layer including a metallic support/contact with graphite cathode inserts, trigger probe sub-assembly layer, ceramic (e.g. tube body) insulator layer, and metallic anode sub-assembly layer. Braze alloy layers are incorporated into the stacked assembly of layers, and can include active metal braze alloys or direct braze alloys, to eliminate costs associated with traditional metallization of the ceramic insulator layers. The entire stacked assembly is then heated to braze/join/bond the stack-up into a cohesive body, after which individual switch tubes are singulated by methods such as sawing. The inventive methods provide for simultaneously fabricating a plurality of devices as opposed to traditional methods that rely on skilled craftsman to essentially hand build individual devices.

  2. Unusal pattern of product inhibition: batch acetic acid fermentation

    SciTech Connect (OSTI)

    Bar, R.; Gainer, J.L.; Kirwan, D.J.

    1987-04-20

    The limited tolerance of microorganisms to their metabolic products results in inhibited growth and product formation. The relationship between the specific growth rate, micro, and the concentration of an inhibitory product has been described by a number of mathematical models. In most cases, micro was found to be inversely proportional to the product concentration and invariably the rate of substrate utilization followed the same pattern. In this communication, the authors report a rather unusual case in which the formation rate of a product, acetic acid, increased with a decreasing growth rate of the microorganism, Acetobacter aceti. Apparently, a similar behavior was mentioned in a review report with respect to Clostridium thermocellum in a batch culture but was not published in the freely circulating literature. The fermentation of ethanol to acetic acid, C/sub 2/H/sub 5/OH + O/sub 2/ = CH/sub 3/COOH + H/sub 2/O is clearly one of the oldest known fermentations. Because of its association with the commercial production of vinegar it has been a subject of extensive but rather technically oriented studies. Suprisingly, the uncommon uncoupling between the inhibited microbial growth and the product formation appears to have been unnoticed. 13 references.

  3. Sample Results from Routine Salt Batch 7 Samples

    SciTech Connect (OSTI)

    Peters, T.

    2015-05-13

    Strip Effluent Hold Tank (SEHT) and Decontaminated Salt Solution Hold Tank (DSSHT) samples from several of the microbatches of Integrated Salt Disposition Project (ISDP) Salt Batch (Macrobatch) 7B have been analyzed for 238Pu, 90Sr, 137Cs, Inductively Coupled Plasma Emission Spectroscopy (ICPES), and Ion Chromatography Anions (IC-A). The results from the current microbatch samples are similar to those from earlier samples from this and previous macrobatches. The Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU) continue to show more than adequate Pu and Sr removal, and there is a distinct positive trend in Cs removal, due to the use of the Next Generation Solvent (NGS). The Savannah River National Laboratory (SRNL) notes that historically, most measured Concentration Factor (CF) values during salt processing have been in the 12-14 range. However, recent processing gives CF values closer to 11. This observation does not indicate that the solvent performance is suffering, as the Decontamination Factor (DF) has still maintained consistently high values. Nevertheless, SRNL will continue to monitor for indications of process upsets. The bulk chemistry of the DSSHT and SEHT samples do not show any signs of unusual behavior.

  4. Statistical Review of Data from DWPF's Process Samples for Batches 19 Through 30

    SciTech Connect (OSTI)

    Edwards, T.B.

    1999-04-06

    The measurements derived from samples taken during the processing of batches 19 through 30 at the Defense Waste Processing Facility (DWPF) affords an opportunity for review and comparisons. This report has looked at some of the statistics from these data. Only the data reported by the DWPF lab (that is, the data provided by the lab as representative of the samples taken) are available for this analysis. In some cases, the sample results reported may be a subset of the sample results generated by the analytical procedures. A thorough assessment of the DWPF lab's analytical procedures would require the complete set of data. Thus, the statistics reported here, specifically, as they relate to analytical uncertainties, are limited to the reported data for these samples, A fell for the consistency of the incoming slurry is the estimation of the components of variation for the Sludge Receipt and Adjustment Tank (SRAT) receipts. In general, for all of the vessels, the data from batches after 21 show smaller batch-to-batch variation than the data from all the batches. The relative contributions of batch-to-batch versus residual, which includes analytical, are presented in these analyses.

  5. Tc-99 Adsorption on Selected Activated Carbons - Batch Testing Results

    SciTech Connect (OSTI)

    Mattigod, Shas V.; Wellman, Dawn M.; Golovich, Elizabeth C.; Cordova, Elsa A.; Smith, Ronald M.

    2010-12-01

    CH2M HILL Plateau Remediation Company (CHPRC) is currently developing a 200-West Area groundwater pump-and-treat system as the remedial action selected under the Comprehensive Environmental Response, Compensation, and Liability Act Record of Decision for Operable Unit (OU) 200-ZP-1. This report documents the results of treatability tests Pacific Northwest National Laboratory researchers conducted to quantify the ability of selected activated carbon products (or carbons) to adsorb technetium-99 (Tc-99) from 200-West Area groundwater. The Tc-99 adsorption performance of seven activated carbons (J177601 Calgon Fitrasorb 400, J177606 Siemens AC1230AWC, J177609 Carbon Resources CR-1240-AW, J177611 General Carbon GC20X50, J177612 Norit GAC830, J177613 Norit GAC830, and J177617 Nucon LW1230) were evaluated using water from well 299-W19-36. Four of the best performing carbons (J177606 Siemens AC1230AWC, J177609 Carbon Resources CR-1240-AW, J177611 General Carbon GC20X50, and J177613 Norit GAC830) were selected for batch isotherm testing. The batch isotherm tests on four of the selected carbons indicated that under lower nitrate concentration conditions (382 mg/L), Kd values ranged from 6,000 to 20,000 mL/g. In comparison. Under higher nitrate (750 mg/L) conditions, there was a measureable decrease in Tc-99 adsorption with Kd values ranging from 3,000 to 7,000 mL/g. The adsorption data fit both the Langmuir and the Freundlich equations. Supplemental tests were conducted using the two carbons that demonstrated the highest adsorption capacity to resolve the issue of the best fit isotherm. These tests indicated that Langmuir isotherms provided the best fit for Tc-99 adsorption under low nitrate concentration conditions. At the design basis concentration of Tc 0.865 g/L(14,700 pCi/L), the predicted Kd values from using Langmuir isotherm constants were 5,980 mL/g and 6,870 mL/g for for the two carbons. These Kd values did not meet the target Kd value of 9,000 mL/g. Tests

  6. SLUDGE BATCH 6/TANK 51 SIMULANT CHEMICAL PROCESS CELL SIMULATIONS

    SciTech Connect (OSTI)

    Koopman, David; Best, David

    2010-04-28

    Qualification simulant testing was completed to determine appropriate processing conditions and assumptions for the Sludge Batch 6 (SB6) Shielded Cells demonstration of the DWPF flowsheet using the qualification sample from Tank 51 for SB6 after SRNL washing. It was found that an acid addition window of 105-139% of the DWPF acid equation (100-133% of the Koopman minimum acid equation) gave acceptable Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) results for nitrite destruction and hydrogen generation. Hydrogen generation occurred continuously after acid addition in three of the four tests. The three runs at 117%, 133%, and 150% stoichiometry (Koopman) were all still producing around 0.1 lb hydrogen/hr at DWPF scale after 42 hours of boiling in the SRAT. The 150% acid run reached 110% of the DWPF SRAT limit of 0.65 lb H{sub 2}/hr, and the 133% acid run reached 75% of the DWPF SME limit of 0.223 lb H{sub 2}/hr. Conversely, nitrous oxide generation was subdued compared to previous sludge batches, staying below 25 lb/hr in all four tests or about a fourth as much as in comparable SB4 testing. Two other processing issues were noted. First, incomplete mercury suspension impacted mercury stripping from the SRAT slurry. This led to higher SRAT product mercury concentrations than targeted (>0.45 wt% in the total solids). Associated with this issue was a general difficulty in quantifying the mass of mercury in the SRAT vessel as a function of time, especially as acid stoichiometry increased. About ten times more mercury was found after drying the 150% acid SME product to powder than was indicated by the SME product sample results. Significantly more mercury was also found in the 133% acid SME product samples than was found during the SRAT cycle sampling. It appears that mercury is segregating from the bulk slurry in the SRAT vessel, as mercury amalgam deposits for example, and is not being resuspended by the agitators. The second processing issue

  7. MELT RATE FURNACE TESTING FOR SLUDGE BATCH 5 FRIT OPTIMIZATION

    SciTech Connect (OSTI)

    Miller, D; Fox, K; Pickenheim, B; Stone, M

    2008-10-03

    Savannah River National Laboratory (SRNL) was requested to provide the Defense Waste Processing Facility (DWPF) with a frit composition for Sludge Batch 5 (SB5) to optimize processing. A series of experiments were designed for testing in the Melt Rate Furnace (MRF). This dry fed tool can be used to quickly determine relative melt rates for a large number of candidate frit compositions and lead to a selection for further testing. Simulated Sludge Receipt and Adjustment Tank (SRAT) product was made according to the most recent SB5 sludge projections and a series of tests were conducted with frits that covered a range of boron and alkali ratios. Several frits with relatively large projected operating windows indicated melt rates that would not severely impact production. As seen with previous MRF testing, increasing the boron concentration had positive impacts on melt rate on the SB5 system. However, there appears to be maximum values for both boron and sodium above which the there is a negative effect on melt rate. Based on these data and compositional trends, Frit 418 and a specially designed frit (Frit 550) have been selected for additional melt rate testing. Frit 418 and Frit 550 will be run in the Slurry Fed Melt Rate Furnace (SMRF), which is capable of distinguishing rheological properties not detected by the MRF. Frit 418 will be used initially for SB5 processing in DWPF (given its robustness to compositional uncertainty). The Frit 418-SB5 system will provide a baseline from which potential melt rate advantages of Frit 550 can be gauged. The data from SMRF testing will be used to determine whether Frit 550 should be recommended for implementation in DWPF.

  8. Please use "gres" settings in your batch scripts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Please use "gres" settings in your batch scripts Please use "gres" settings in your batch scripts September 4, 2012 by Helen He We would like to encourage you to use the generic resources ("gres") setting for various file systems that your batch jobs use. This feature is currently available on Hopper and Carver. The advantage of this setting is that your jobs won't start (thus won't fail) during a scheduled file system maintenance. The syntax for the

  9. Multi-batch slip stacking in the Main Injector at Fermilab

    SciTech Connect (OSTI)

    Seiya, K.; Berenc, T.; Chase, B.; Dey, J.; Joireman, P.; Kourbanis, I.; Reid, J.; /Fermilab

    2007-06-01

    The Main Injector (MI) at Fermilab is planning to use multi-batch slip stacking scheme in order to increase the proton intensity at the NuMI target by about a factor of 1.5.[1] [2] By using multi-batch slip stacking, a total of 11 Booster batches are merged into 6, 5 double ones and one single. We have successfully demonstrated the multibatch slip stacking in MI and accelerated a record intensity of 4.6E13 particle per cycle to 120 GeV. The technical issues and beam loss mechanisms for multibatch slip stacking scheme are discussed.

  10. Progress in Multi-Batch Slip Stacking in the Fermilab Main Injector and Future Plans

    SciTech Connect (OSTI)

    Seiya, K.; Chase, B.; Dey, J.; Joireman, P.; Kourbanis, I.; Reid, J.; /Fermilab

    2008-04-01

    The multi-batch slip stacking has been used for operations since January, 2008 and effectively increased proton intensity to the NuMI target by 50% in a Main Injector (MI) cycle. The MI accepts 11 batches at injection energy from the Booster, and sends two batches to antiproton production and nine to the NuMI beam line. The total beam power in a cycle was increased to 340 kW on average. We have been doing beam studies in order to increase the beam power to 400 kW and to control the beam loss. We will also discuss 12 batch slip stacking scheme which is going to be used for future neutrino experiments.

  11. Uranium Adsorption on Ion-Exchange Resins - Batch Testing

    SciTech Connect (OSTI)

    Mattigod, Shas V.; Golovich, Elizabeth C.; Wellman, Dawn M.; Cordova, Elsa A.; Smith, Ronald M.

    2010-12-01

    The uranium adsorption performance of five resins (Dowex 1, Dowex 21K 16-30 [fresh], Dowex 21K 16-30 [regenerated], Purofine PFA600/4740, and ResinTech SIR-1200) were tested using unspiked, nitrate-spiked, and nitrate-spiked/pH adjusted source water from well 299-W19-36. These batch tests were conducted in support of a resin selection process in which the best resin to use for uranium treatment in the 200-West Area groundwater pump-and-treat system will be identified. The results from these tests are as follows: The data from the high-nitrate (1331 mg/L) tests indicated that Dowex 1, Dowex 21K 16-30 (fresh), Purofine PFA600/4740, and ResinTech SIR-1200 all adsorbed uranium similarly well with Kd values ranging from ~15,000 to 95,000 ml/g. All four resins would be considered suitable for use in the treatment system based on uranium adsorption characteristics. Lowering the pH of the high nitrate test conditions from 8.2 to 7.5 did not significantly change the uranium adsorption isotherms for the four tested resins. The Kd values for these four resins under high nitrate (1338 mg/L), lower pH (7.5) ranged from ~15,000 to 80,000 ml/g. Higher nitrate concentrations greatly reduced the uranium adsorption on all four resins. Tests conducted with unspiked (no amendments; nitrate at 337 mg/L and pH at 8.2) source water yielded Kd values for Dowex 1, Dowex 21K 16-30 (fresh), Purofine PFA600/4740, and ResinTech SIR-1200 resins ranging from ~800,000 to >3,000,000 ml/g. These values are about two orders of magnitude higher than the Kd values noted from tests conducted using amended source water. Compared to the fresh resin, the regenerated Dowex 21K 16-30 resin exhibited significantly lower uranium-adsorption performance under all test conditions. The calculated Kd values for the regenerated resin were typically an order of magnitude lower than the values calculated for the fresh resin. Additional testing using laboratory columns is recommended to better resolve

  12. Tank 40 Final Sludge Batch 8 Chemical Characterization Results

    SciTech Connect (OSTI)

    Bannochie, Christopher J.

    2013-09-19

    A sample of Sludge Batch 8 (SB8) was pulled from Tank 40 in order to obtain radionuclide inventory analyses necessary for compliance with the Waste Acceptance Product Specifications (WAPS). The SB8 WAPS sample was also analyzed for chemical composition, including noble metals, and fissile constituents, and these results are reported here. These analyses along with the WAPS radionuclide analyses will help define the composition of the sludge in Tank 40 that is currently being fed to the Defense Waste Processing Facility (DWPF) as SB8. At SRNL, the 3-L Tank 40 SB8 sample was transferred from the shipping container into a 4-L high density polyethylene bottle and solids were allowed to settle. Supernate was then siphoned off and circulated through the shipping container to complete the transfer of the sample. Following thorough mixing of the 3-L sample, a 553 g sub-sample was removed. This sub-sample was then utilized for all subsequent slurry sample preparations. Eight separate aliquots of the slurry were digested, four with HNO{sub 3}/HCl (aqua regia) in sealed Teflon(r) vessels and four with NaOH/Na{sub 2}O{sub 2} (alkali or peroxide fusion) using Zr crucibles. Two Analytical Reference Glass - 1 (ARG-1) standards were digested along with a blank for each preparation. Each aqua regia digestion and blank was diluted to 1:100 mL with deionized water and submitted to Analytical Development (AD) for inductively coupled plasma - atomic emission spectroscopy (ICP-AES) analysis, inductively coupled plasma - mass spectrometry (ICP-MS) analysis, atomic absorption spectroscopy (AA) for As and Se, and cold vapor atomic absorption spectroscopy (CV-AA) for Hg. Equivalent dilutions of the alkali fusion digestions and blank were submitted to AD for ICP-AES analysis. Tank 40 SB8 supernate was collected from a mixed slurry sample in the SRNL Shielded Cells and submitted to AD for ICP-AES, ion chromatography (IC), total base/free OH-/other base, total inorganic carbon/total organic

  13. Production of branched-chain alcohols by recombinant Ralstonia eutropha in fed-batch cultivation

    SciTech Connect (OSTI)

    Fei, Q; Brigham, CJ; Lu, JN; Fu, RZ; Sinskey, AJ

    2013-09-01

    Branched-chain alcohols are considered promising green energy sources due to their compatibility with existing infrastructure and their high energy density. We utilized a strain of Ralstonia eutropha capable of producing branched-chain alcohols and examined its production in flask cultures. In order to increase isobutanol and 3-methyl-1-butanol (isoamyl alcohol) productivity in the engineered strain, batch, fed-batch, and two-stage fed-batch cultures were carried out in this work. The effects of nitrogen source concentration on branched-chain alcohol production were investigated under four different initial concentrations in fermenters. A maximum 380 g m(-3) of branched-chain alcohol production was observed with 2 kg m(-3) initial NH4Cl concentration in batch cultures. A pH-stat control strategy was utilized to investigate the optimum carbon source amount fed during fed-batch cultures for higher cell density. In cultures of R. eutropha strains that did not produce polyhydroxyalkanoate or branched-chain alcohols, a maximum cell dry weight of 36 kg m(-3) was observed using a fed-batch strategy, when 10 kg m(-3) carbon source was fed into culture medium. Finally, a total branched-chain alcohol titer of 790 g m(-3), the highest branched-chain alcohol yield of 0.03 g g(-1), and the maximum branched-chain alcohol productivity of 8.23 g m(-3) h(-1) were obtained from the engineered strain Re2410/pJL26 in a two-stage fed-batch culture system with pH-stat control. Isobutanol made up over 95% (mass fraction) of the total branched-chain alcohols titer produced in this study. (C) 2013 Published by Elsevier Ltd.

  14. SLUDGE BATCH 6/TANK 40 SIMULANT CHEMICAL PROCESS CELL SIMULATIONS

    SciTech Connect (OSTI)

    Koopman, David

    2010-04-28

    Phase III simulant flowsheet testing was completed using the latest composition estimates for SB6/Tank 40 feed to DWPF. The goals of the testing were to determine reasonable operating conditions and assumptions for the startup of SB6 processing in the DWPF. Testing covered the region from 102-159% of the current DWPF stoichiometric acid equation. Nitrite ion concentration was reduced to 90 mg/kg in the SRAT product of the lowest acid run. The 159% acid run reached 60% of the DWPF Sludge Receipt and Adjustment Tank (SRAT) limit of 0.65 lb H2/hr, and then sporadically exceeded the DWPF Slurry Mix Evaporator (SME) limit of 0.223 lb H2/hr. Hydrogen generation rates peaked at 112% of the SME limit, but higher than targeted wt% total solids levels may have been partially responsible for rates seen. A stoichiometric factor of 120% met both objectives. A processing window for SB6 exists from 102% to something close to 159% based on the simulant results. An initial recommendation for SB6 processing is at 115-120% of the current DWPF stoichiometric acid equation. The addition of simulated Actinide Removal Process (ARP) and Modular Caustic Side Solvent Extraction Unit (MCU) streams to the SRAT cycle had no apparent impact on the preferred stoichiometric factor. Hydrogen generation occurred continuously after acid addition in three of the four tests. The three runs at 120%, 118.4% with ARP/MCU, and 159% stoichiometry were all still producing around 0.1 lb hydrogen/hr at DWPF scale after 36 hours of boiling in the SRAT. The 120% acid run reached 23% of the SRAT limit and 37% of the SME limit. Conversely, nitrous oxide generation was subdued compared to previous sludge batches, staying below 29 lb/hr in all four tests or about a fourth as much as in comparable SB4 testing. Two processing issues, identified during SB6 Phase II flowsheet testing and qualification simulant testing, were monitored during Phase III. Mercury material balance closure was impacted by acid stoichiometry

  15. Case history: Effectively operating an RTO with batch VOC spikes

    SciTech Connect (OSTI)

    Hohl, H.M.

    1999-07-01

    The problem at a foam packaging plant in Texas was periodic spikes of expanded foam blowing agent to atmosphere. The amount of butane blowing agent released is a function of the thickness of the packaging foam desired. As the facility changed products on the multiple extrusion lines, volatile organic compound (VOC) emissions varied widely. The Texas Natural Resource Conservation Commission (TNRCC) requires abatement of the blowing agent. If the abatement device was not designed for the wide variation in VOCs, the abatement device could shut down under high temperature conditions. With the abatement device shutdown, the manufacturing operation must also be shut down. Two methods were used in the past to address the widely varied operating conditions. One was to operate an abatement device with a less thermally efficient recuperative style oxidizer. These units had thermal efficiencies in the range of 50 to 70%. The second method of dealing with the different operating conditions was to oversize the abatement device for the maximum VOC concentration. In this case a very large regenerative thermal oxidizer (RTO) was used to minimize operating costs. This paper will provide case history information on an innovative way to deal with effective operation in dealing with VOC spikes in an expanded foam packaging application. A hot gas bypass system was designed and installed to address the VOC spikes. As a result the system operates with lower overall operating costs than previous systems. The design, operation, and environmental performance for this unit will be reviewed during this presentation.

  16. Results Of Initial Analyses Of The Salt (Macro) Batch 9 Tank 21H Qualification Samples

    SciTech Connect (OSTI)

    Peters, T.

    2015-10-08

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Interim Salt Disposition Project (ISDP) Salt (Macro) Batch 9 for processing through the Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU). This document reports the initial results of the analyses of samples of Tank 21H. Analysis of the Tank 21H Salt (Macro) Batch 9 composite sample indicates that the material does not display any unusual characteristics. Further results on the chemistry and other tests will be issued in the future.

  17. Results of initial analyses of the salt (macro) batch 9 tank 21H qualification samples

    SciTech Connect (OSTI)

    Peters, T. B.

    2015-10-01

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Interim Salt Disposition Project (ISDP) Salt (Macro) Batch 9 for processing through the Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU). This document reports the initial results of the analyses of samples of Tank 21H. Analysis of the Tank 21H Salt (Macro) Batch 9 composite sample indicates that the material does not display any unusual characteristics or observations, such as floating solids, the presence of large amount of solids, or unusual colors. Further results on the chemistry and other tests will be issued in the future.

  18. Introducing On-demand in LCRC: Towards a Convergence of On-demand and Batch

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resource Allocation | Argonne Leadership Computing Facility Introducing On-demand in LCRC: Towards a Convergence of On-demand and Batch Resource Allocation Event Sponsor: CloudX Seminar Start Date: Aug 30 2016 - 12:00pm Building/Room: Building 240/Room 4301 Location: Argonne National Laboratory Speaker(s): Francis Liu The LCRC Pilot Project aims to explore a confluence of on-demand availability and environment management on one side, and batch scheduling on the other. The project seeks to

  19. Batch crystallization of rhodopsin for structural dynamics using an X-ray free-electron laser

    SciTech Connect (OSTI)

    Wu, Wenting; Nogly, Przemyslaw; Rheinberger, Jan; Kick, Leonhard M.; Gati, Cornelius; Nelson, Garrett; Deupi, Xavier; Standfuss, Jrg; Schertler, Gebhard; Panneels, Valrie

    2015-06-27

    A new batch preparation method is presented for high-density micrometre-sized crystals of the G protein-coupled receptor rhodopsin for use in time-resolved serial femtosecond crystallography at an X-ray free-electron laser using a liquid jet. Rhodopsin is a membrane protein from the G protein-coupled receptor family. Together with its ligand retinal, it forms the visual pigment responsible for night vision. In order to perform ultrafast dynamics studies, a time-resolved serial femtosecond crystallography method is required owing to the nonreversible activation of rhodopsin. In such an approach, microcrystals in suspension are delivered into the X-ray pulses of an X-ray free-electron laser (XFEL) after a precise photoactivation delay. Here, a millilitre batch production of high-density microcrystals was developed by four methodical conversion steps starting from known vapour-diffusion crystallization protocols: (i) screening the low-salt crystallization conditions preferred for serial crystallography by vapour diffusion, (ii) optimization of batch crystallization, (iii) testing the crystal size and quality using second-harmonic generation (SHG) imaging and X-ray powder diffraction and (iv) production of millilitres of rhodopsin crystal suspension in batches for serial crystallography tests; these crystals diffracted at an XFEL at the Linac Coherent Light Source using a liquid-jet setup.

  20. Analytical Plans Supporting The Sludge Batch 8 Glass Variability Study Being Conducted By Energysolutions And Cua's Vitreous State Laboratory

    SciTech Connect (OSTI)

    Edwards, T. B.; Peeler, D. K.

    2012-11-26

    EnergySolutions (ES) and its partner, the Vitreous State Laboratory (VSL) of The Catholic University of America (CUA), are to provide engineering and technical services support to Savannah River Remediation, LLC (SRR) for ongoing operation of the Defense Waste Processing Facility (DWPF) flowsheet as well as for modifications to improve overall plant performance. SRR has requested via a statement of work that ES/VSL conduct a glass variability study (VS) for Sludge Batch 8. SRR issued a technical task request (TTR) asking that the Savannah River National Laboratory (SRNL) provide planning and data reduction support for the ES/VSL effort. This document provides two analytical plans for use by ES/VSL: one plan is to guide the measurement of the chemical composition of the study glasses while the second is to guide the measurement of the durability of the study glasses. The measurements generated by ES/VSL are to be provided to SRNL for data reduction and evaluation. SRNL is to review the results of its evaluation with ES/VSL and SRR. The results will subsequently be incorporated into a joint report with ES/VSL as a deliverable to SRR to support the processing of SB8 at DWPF.

  1. Enhanced lipid lroduction by Rhodosporidium toruloides using different fed-batch feeding strategies with lignocellulosic hydrolysate as the sole carbon source

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fei, Qiang; O'Brien, Marykate; Nelson, Robert; Chen, Xiaowen; Lowell, Andrew; Dowe, Nancy

    2016-06-23

    Industrial biotechnology that is able to provide environmentally friendly bio-based products has attracted more attention in replacing petroleum-based industries. Currently, most of the carbon sources used for fermentation-based bioprocesses are obtained from agricultural commodities that are used as foodstuff for human beings. Lignocellulose-derived sugars as the non-food, green, and sustainable alternative carbon sources have great potential to avoid this dilemma for producing the renewable, bio-based hydrocarbon fuel precursors, such as microbial lipid. Efficient bioconversion of lignocellulose-based sugars into lipids is one of the critical parameters for industrial application. Therefore, the fed-batch cultivation, which is a common method used in industrialmore » applications, was investigated to achieve a high cell density culture along with high lipid yield and productivity. In this study, several fed-batch strategies were explored to improve lipid production using lignocellulosic hydrolysates derived from corn stover. Compared to the batch culture giving a lipid yield of 0.19 g/g, the dissolved-oxygen-stat feeding mode increased the lipid yield to 0.23 g/g and the lipid productivity to 0.33 g/L/h. The pulse feeding mode further improved lipid productivity to 0.35 g/L/h and the yield to 0.24 g/g. However, the highest lipid yield (0.29 g/g) and productivity (0.4 g/L/h) were achieved using an automated online sugar control feeding mode, which gave a dry cell weight of 54 g/L and lipid content of 59 % (w/w). The major fatty acids of the lipid derived from lignocellulosic hydrolysates were predominately palmitic acid and oleic acid, which are similar to those of conventional oilseed plants. Our results suggest that the fed-batch feeding strategy can strongly influence the lipid production. Lastly, the online sugar control feeding mode was the most appealing strategy for high cell density, lipid yield, and lipid productivity using lignocellulosic hydrolysates

  2. Plant Operational Status - Pantex Plant

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plant Operational Status Plant Operational Status Page Content Shift 1 - Day The Pantex Plant is open for normal Day Shift operations. Plant personnel are to report as assigned. Personnel may call 477-3000, Option 1 for additional details. Shift 2 - Swing The Pantex Plant is open for normal Swing Shift operations. Plant personnel are to report as assigned. Personnel may call 477-3000, Option 1 for additional details. Shift 3 - Grave The Pantex Plant is open for normal Graveyard Shift operations.

  3. Characterization Of The As-Received Sludge Batch 9 Qualification Sample (Htf-51-15-81)

    SciTech Connect (OSTI)

    Pareizs, J.

    2015-09-30

    Savannah River National Laboratory (SRNL) personnel have been requested to qualify the next sludge batch (Sludge Batch 9 – SB9) for processing at the Defense Waste Processing Facility (DWPF). To accomplish this task, Savannah River Remediation (SRR) has sent SRNL a 3-L slurried sample of Tank 51H (HTF-51-15-81) to be characterized, washed, and then used in a lab-scale demonstration of the DWPF flowsheet (potentially after combining with Tank 40H sludge). This report documents the first steps of the qualification process – characterization of the as-received Tank 51H qualification sample. These results will be used to support a reprojection of SB9 by SRR from which final Tank 51H washing, frit development, and Chemical Processing Cell (CPC) activities will be based.

  4. Removal of aqueous rinsable flux residues in a batch spray dishwater

    SciTech Connect (OSTI)

    Slanina, J.T.

    1992-02-01

    An alkaline detergent solution used in an industrial dishwasher was evaluated to remove aqueous rinsable flux residues on printed wiring boards (PWBs) after hot air solder leveling and hot oil solder dip and leveling. The dishwasher, a batch cleaning process, was compared to an existing conveyorized aqueous cleaning process. The aqueous soluble flux residues from both soldering processes were removed with a solution of a mild alkaline detergent dissolved in hot deionized (DI) water.

  5. SRS SLUDGE BATCH QUALIFICATION AND PROCESSING; HISTORICAL PERSPECTIVE AND LESSONS LEARNED

    SciTech Connect (OSTI)

    Cercy, M.; Peeler, D.; Stone, M.

    2013-09-25

    This report provides a historical overview and lessons learned associated with the SRS sludge batch (SB) qualification and processing programs. The report covers the framework of the requirements for waste form acceptance, the DWPF Glass Product Control Program (GPCP), waste feed acceptance, examples of how the program complies with the specifications, an overview of the Startup Program, and a summary of continuous improvements and lessons learned. The report includes a bibliography of previous reports and briefings on the topic.

  6. Fermentation of cellulosic substrates in batch and continuous culture by Clostridium thermocellum

    SciTech Connect (OSTI)

    Lynd, L.R.; Grethlein, H.E.; Wolkin, R.H. )

    1989-12-01

    Fermentation of dilute-acid-pretreated mixed hardwood and Avicel by Clostridium thermocellum was compared in batch and continuous cultures. Results indicate that fermentation parameters, with the exception of free cellulase activity, are essentially the same for pretreated mixed hardwood and Avicel under a variety of conditions. Hydrolysis yields obtained with C. thermocellum cellulase acting either in vitro or in vivo were comparable to those previously reported for Trichoderma reesei on the same substrates.

  7. Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cori runs native SLURM. "Native" means no interaction with Cray's Application Level Placement Scheduler (ALPS). Native SLURM serves the same purpose as MOABTorque, acting as both ...

  8. Wet oxidation of an azo dye: Lumped kinetics in batch and mixed flow reactors

    SciTech Connect (OSTI)

    Donlagic, J.; Levec, J.

    1999-12-01

    Oxidation of a dilute aqueous solution of a model azo dye pollutant (Orange II) was studied in batch and continuous well-mixed (CSTR) reactors. Both reactors operate at 200--250 C, and total pressures up to 50 bar and at oxygen partial pressure from 10 to 30 bar. The model pollutant concentrations were in a range between 100 and 1,000 mg/L, which may be found in industrial wastewaters. The dye oxidation undergoes parallel-consecutive reaction pathways, in which it first decomposes thermally and oxidatively to aromatic intermediates and via organic acids to the final product carbon dioxide. To develop a kinetic equation capable of predicting organic carbon reduction, all organic species present in solution were lumped by total organic carbon (TOC). The lumped oxidation rate in batch reactor exhibited second-order behavior, whereas in the CSTR is was found linearly proportional to its TOC concentration. The lump behavior in batch reactor was dominated by the refractory low molecular mass aliphatic acids formed during the oxidation.

  9. MODELING CST ION EXCHANGE FOR CESIUM REMOVAL FROM SCIX BATCHES 1 - 4

    SciTech Connect (OSTI)

    Smith, F.

    2011-04-25

    The objective of this work is, through modeling, to predict the performance of Crystalline Silicotitinate (CST) for the removal of cesium from Small Column Ion Exchange (SCIX) Batches 1-4 (as proposed in Revision 16 of the Liquid Waste System Plan). The scope of this task is specified in Technical Task Request (TTR) 'SCIX Feed Modeling', HLE-TTR-2011-003, which specified using the Zheng, Anthony, Miller (ZAM) code to predict CST isotherms for six given SCIX feed compositions and the VErsatile Reaction and SEparation simulator for Liquid Chromatography (VERSE-LC) code to predict ion-exchange column behavior. The six SCIX feed compositions provided in the TTR represent SCIX Batches 1-4 and Batches 1 and 2 without caustic addition. The study also investigated the sensitivity in column performance to: (1) Flow rates of 5, 10, and 20 gpm with 10 gpm as the nominal flow; and (2) Temperatures of 25, 35, and 45 C with 35 C as the nominal temperature. The isotherms and column predictions presented in this report reflect the expected performance of engineered CST IE-911. This form of CST was used in experiments conducted at the Savannah River National Laboratory (SRNL) that formed the basis for estimating model parameters (Hamm et al., 2002). As has been done previously, the engineered resin capacity is estimated to be 68% of the capacity of particulate CST without binder.

  10. Analysis Of DWPF Sludge Batch 7a (Macrobatch 8) Pour Stream Samples

    SciTech Connect (OSTI)

    Johnson, F. C.; Pareizs, J. M.

    2012-10-24

    The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 7a (SB7a), also referred to as Macrobatch 8 (MB8), in June 2011. SB7a is a blend of the heel of Tank 40 from Sludge Batch 6 (SB6) and the SB7a material that was transferred to Tank 40 from Tank 51. SB7a was processed using Frit 418. During processing of each sludge batch, the DWPF is required to take at least one glass sample to meet the objectives of the Glass Product Control Program (GPCP), which is governed by the DWPF Waste Compliance Plan, and to complete the necessary Production Records so that the final glass product may be disposed of at a Federal Repository. Three pour stream glass samples and two Melter Feed Tank (MFT) slurry samples were collected while processing SB7a. These additional samples were taken during SB7a to understand the impact of antifoam and the melter bubblers on glass redox chemistry. The samples were transferred to the Savannah River National Laboratory (SRNL) where they were analyzed.

  11. SLUDGE BATCH 7B QUALIFICATION ACTIVITIES WITH SRS TANK FARM SLUDGE

    SciTech Connect (OSTI)

    Pareizs, J.; Click, D.; Lambert, D.; Reboul, S.

    2011-11-16

    Waste Solidification Engineering (WSE) has requested that characterization and a radioactive demonstration of the next batch of sludge slurry - Sludge Batch 7b (SB7b) - be completed in the Shielded Cells Facility of the Savannah River National Laboratory (SRNL) via a Technical Task Request (TTR). This characterization and demonstration, or sludge batch qualification process, is required prior to transfer of the sludge from Tank 51 to the Defense Waste Processing Facility (DWPF) feed tank (Tank 40). The current WSE practice is to prepare sludge batches in Tank 51 by transferring sludge from other tanks. Discharges of nuclear materials from H Canyon are often added to Tank 51 during sludge batch preparation. The sludge is washed and transferred to Tank 40, the current DWPF feed tank. Prior to transfer of Tank 51 to Tank 40, SRNL typically simulates the Tank Farm and DWPF processes with a Tank 51 sample (referred to as the qualification sample). With the tight schedule constraints for SB7b and the potential need for caustic addition to allow for an acceptable glass processing window, the qualification for SB7b was approached differently than past batches. For SB7b, SRNL prepared a Tank 51 and a Tank 40 sample for qualification. SRNL did not receive the qualification sample from Tank 51 nor did it simulate all of the Tank Farm washing and decanting operations. Instead, SRNL prepared a Tank 51 SB7b sample from samples of Tank 7 and Tank 51, along with a wash solution to adjust the supernatant composition to the final SB7b Tank 51 Tank Farm projections. SRNL then prepared a sample to represent SB7b in Tank 40 by combining portions of the SRNL-prepared Tank 51 SB7b sample and a Tank 40 Sludge Batch 7a (SB7a) sample. The blended sample was 71% Tank 40 (SB7a) and 29% Tank 7/Tank 51 on an insoluble solids basis. This sample is referred to as the SB7b Qualification Sample. The blend represented the highest projected Tank 40 heel (as of May 25, 2011), and thus, the highest

  12. Evaluation of ISDP Batch 2 Qualification Compliance to 512-S, DWPF, Tank Farm, and Saltstone Waste Acceptance Criteria

    SciTech Connect (OSTI)

    Shafer, A.

    2010-05-05

    The purpose of this report is to document the acceptability of the second macrobatch (Salt Batch 2) of Tank 49H waste to H Tank Farm, DWPF, and Saltstone for operation of the Interim Salt Disposition Project (ISDP). Tank 49 feed meets the Waste Acceptance Criteria (WAC) requirements specified by References 11, 12, and 13. Salt Batch 2 material is qualified and ready to be processed through ARP/MCU to the final disposal facilities.

  13. Batch methods for enriching trace impurities in hydrogen gas for their further analysis

    DOE Patents [OSTI]

    Ahmed, Shabbir; Lee, Sheldon H.D.; Kumar, Romesh; Papdias, Dionissios D.

    2014-07-15

    Provided herein are batch methods and devices for enriching trace quantities of impurities in gaseous mixtures, such as hydrogen fuel. The methods and devices rely on concentrating impurities using hydrogen transport membranes wherein the time period for concentrating the sample is calculated on the basis of optimized membrane characteristics, comprising its thickness and permeance, with optimization of temperature, and wherein the enrichment of trace impurities is proportional to the pressure ratio P.sub.hi/P.sub.lo and the volume ratio V.sub.1/V.sub.2, with following detection of the impurities using commonly-available detection methods.

  14. Status of the first batch of niobium resonator production for the New Delhi booster linac.

    SciTech Connect (OSTI)

    Potukuchi, P. N.

    1999-03-16

    This paper reports the status and details of the costs of construction of niobium superconducting resonant cavities for a linear accelerator, presently being built as a booster for the 15 UD tandem Pelletron accelerator at the Nuclear Science Centre, New Delhi. The linear accelerator will have three cryostat modules, each holding eight quarter-wave resonators. Construction of a batch of ten resonators for the linac started at Argonne National Laboratory in May 1997. For production, all fabrication and all electron beam welding is being done through commercial vendors. Details of construction and present status of the project are presented.

  15. Characterization of the SRNL-Washed tank 51 sludge batch 9 qualification sample

    SciTech Connect (OSTI)

    Pareizs, J. M.

    2016-01-01

    Savannah River National Laboratory (SRNL) personnel have been requested to qualify the next sludge batch (Sludge Batch 9 – SB9) for processing at the Defense Waste Processing Facility (DWPF). To accomplish this task, Savannah River Remediation (SRR) sent SRNL a 3-L sample of Tank 51H slurry to be characterized, washed, and then used in a lab-scale demonstration of the DWPF flowsheet (after combining with Tank 40H sludge). SRNL has washed the Tank 51H sample per the Tank Farm washing strategy as of October 20, 2015. A part of the qualification process is extensive radionuclide and chemical characterization of the SRNL-washed Tank 51H slurry. This report documents the chemical characterization of the washed slurry; radiological characterization is in progress and will be documented in a separate report. The analytical results of this characterization are comparable to the Tank Farm projections. Therefore, it is recommended that SRNL use this washed slurry for the ongoing SB9 qualification activities.

  16. INTERPRETATION OF AT-LINE SPECTRA FROM AFS-2 BATCH #3 FERROUS SULFAMATE TREATMENT

    SciTech Connect (OSTI)

    Kyser, E.; O'Rourke, P.

    2013-12-10

    Spectra from the at-line spectrometer were obtained during the ferrous sulfamate (FS) valence adjustment step of AFS-2 Batch #3 on 9/18/2013. These spectra were analyzed by mathematical principal component regression (PCR) techniques to evaluate the effectiveness of this treatment. Despite the complications from Pu(IV), we conclude that all Pu(VI) was consumed during the FS treatment, and that by the end of the treatment, about 85% was as Pu(IV) and about 15% was as Pu(III). Due to the concerns about the odd shape of the Pu(IV) peak and the possibility of this behavior being observed in the future, a follow-up sample was sent to SRNL to investigate this further. Analysis of this sample confirmed the previous results and concluded that it odd shape was due to an intermediate acid concentration. Since the spectral evidence shows complete reduction of Pu(VI) we conclude that it is appropriate to proceed with processing of this the batch of feed solution for HB-Line including the complexation of the fluoride with aluminum nitrate.

  17. Mechanism of Phase Formation in the Batch Mixtures for Slag-Bearing Glass Ceramics - 12207

    SciTech Connect (OSTI)

    Stefanovsky, Sergey V.; Stefanovsky, Olga I.; Malinina, Galina A.

    2012-07-01

    Slag surrogate was produced from chemicals by heating to 900 deg. C and keeping at this temperature for 1 hr. The product obtained was intermixed with either sodium di-silicate (75 wt.% waste loading) or borax (85 wt.% slag loading). The mixtures were heat-treated within a temperature range of 25 to 1300 deg. C. The products were examined by X-ray diffraction and infrared spectroscopy. The products prepared at temperatures of up to 1000 deg. C contained both phase typical of the source slag and intermediate phases as well as phases typical of the materials melted at 1350 deg. C such as nepheline, britholite, magnetite and matrix vitreous phase. Vitrification process in batch mixtures consisting of slag surrogate and either sodium di-silicate or sodium tetraborate runs through formation of intermediate phases mainly silico-phosphates capable to incorporate Sm as trivalent actinides surrogate. Reactions in the batch mixtures are in the whole completed by ∼1000 deg. C but higher temperatures are required to homogenize the products. If in the borate-based system the mechanism is close to simple dissolution of slag constituents in the low viscous borate melt, then in the silicate-based system the mechanism was found to be much complicated and includes re-crystallization during melting with segregation of newly-formed nepheline type phase. (authors)

  18. Design of Mixed Batch Reactor and Column Studies at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Wu, Weimin; Criddle, Craig S.

    2015-11-16

    We (the Stanford research team) were invited as external collaborators to contribute expertise in environmental engineering and field research at the ORNL IFRC, Oak Ridge, TN, for projects carried out at the Argonne National Laboratory and funded by US DOE. Specifically, we assisted in the design of batch and column reactors using ORNL IFRC materials to ensure the experiments were relevant to field conditions. During the funded research period, we characterized ORNL IFRC groundwater and sediments in batch microcosm and column experiments conducted at ANL, and we communicated with ANL team members through email and conference calls and face-to-face meetings at the annual ERSP PI meeting and national meetings. Microcosm test results demonstrated that U(VI) in sediments was reduced to U(IV) when amended with ethanol. The reduced products were not uraninite but unknown U(IV) complexes associated with Fe. Fe(III) in solid phase was only partially reduced. Due to budget reductions at ANL, Stanford contributions ended in 2011.

  19. Determination Of Reportable Radionuclides For DWPF Sludge Batch 7B (Macrobatch 9)

    SciTech Connect (OSTI)

    Crawford, C. L.; Diprete, D. P.

    2012-12-17

    The DWPF is receiving radioactive sludge slurry from HLW Tank 40. The radioactive sludge slurry in Tank 40 is a blend of the heel from Sludge Batch 7a (SB7a) and Sludge Batch 7b (SB7b) that was transferred to Tank 40 from Tank 51. The blend of sludge in Tank 40 is also referred to as Macrobatch 9 (MB9). This report develops the list of reportable radionuclides and associated activities as a function of time. Twenty-seven radionuclides have been identified as reportable for DWPF SB7b. Each of these radionuclides has a half-life greater than ten years and contributes more than 0.01% of the radioactivity on a Curie basis at some point from production through the 1100 year period between 2015 and 3115. For SB7b, all of the radionuclides in the Design Basis glass are reportable except for three radionuclides: Pd-107, Cs-135, and Th-230. At no time during the 1100- year period between 2015 and 3115 did any of these three radionuclides contribute to more than 0.01% of the radioactivity on a Curie basis. The radionuclide measurements made for SB7b are the most extensive conducted to date. Some method development/refinement occurred during the conduct of these measurements, leading to lower detection limits and more accurate measurement of some isotopes than was previously possible.

  20. Determination of Reportable Radionuclides for DWPF Sludge Batch 3 (Macrobatch 4)

    SciTech Connect (OSTI)

    Bannochie, C

    2005-05-01

    The Waste Acceptance Product Specifications (WAPS) 1.2 require that ''The Producer shall report the inventory of radionuclides (in Curies) that have half-lives longer than 10 years and that are, or will be, present in concentrations greater than 0.05 percent of the total inventory for each waste type indexed to the years 2015 and 3115''. As part of the strategy to meet WAPS 1.2, the Defense Waste Processing Facility (DWPF) will report for each waste type, all radionuclides (with half-lives greater than 10 years) that have concentrations greater than 0.01 percent of the total inventory from time of production through the 1100 year period from 2015 through 3115. The initial listing of radionuclides to be included is based on the design-basis glass as identified in the Waste Form Compliance Plan (WCP) and Waste Form Qualification Report (WQR). However, it is required that this list be expanded if other radionuclides with half-lives greater than 10 years are identified that meet the greater than 0.01% criterion for Curie content. Specification 1.6 of the WAPS, IAEA Safeguards Reporting for HLW, requires that the ratio by weights of the following uranium and plutonium isotopes be reported: U-233, U-234, U-235, U-236, U-238, Pu-238, Pu-239, Pu-240, Pu-241, and Pu-242. Therefore, the complete set of reportable radionuclides must also include this set of U and Pu isotopes. The Defense Waste Processing Facility (DWPF) is receiving radioactive sludge slurry from High Level Waste Tank 40. The radioactive sludge slurry in Tank 40 is a blend of the previous contents of Tank 40 (Sludge Batch 2) and the sludge that was transferred to Tank 40 from Tank 51. The blend of sludge from Tank 51 and Tank 40 defines Macrobatch 4 (also referred to as Sludge Batch 3). This report develops the list of reportable radionuclides and associated activities and determines the radionuclide activities as a function of time. The DWPF will use this list and the activities as one of the inputs for the

  1. Proof of concept and performance optimization of high gravity batch type centrifuge for dewatering fine coal. Quarterly technical progress report No. 3, March 20, 1990--June 20, 1990, Revision

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.E. Jr.

    1990-07-24

    Coal Technology Corporation (CTC) believes that the new CTC high gravity, high production, batch type centrifugal dryer technology can play a significant role in improving the product quality as well as costs of operation in coal processing plants. It is further believed that the new centrifugal dryer technology can form an important part in systems used to clean up the millions of tons of coal fines in refuse piles and ponds. It is anticipated that the new centrifuge can become an important ancillary to the advanced deep cleaning processes for coal. Because of these convictions, CTC has been engaged in a pioneering research effort into the new art of drying fine clean coal in high gravity, high production, batch type centrifuges, since 1981. This work has progressed to the point where the new centrifugal dryer technology is nearly ready for commercialization. It promises to provide needed fine coal drying capability at somewhat lower capital costs and at substantially lower operating costs than competitive systems. It also promises to do so with no detrimental effects on either the coal quality or the evironment. The primary objective of this project is to prove the concept in a commercial coal processing plant environment. The proof of concept tests will also include testing with a variety of coals from different regions. A further objective will be to optimize the efficiency and the cost effectiveness of the new centrifugal dryer technology.

  2. ANALYSIS OF DWPF SLUDGE BATCH 7A (MACROBATCH 8) POUR STREAM SAMPLES

    SciTech Connect (OSTI)

    Johnson, F.

    2012-05-01

    The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 7a (SB7a), also referred to as Macrobatch 8 (MB8), in June 2011. SB7a is a blend of the heel of Tank 40 from Sludge Batch 6 (SB6) and the SB7a material that was transferred to Tank 40 from Tank 51. SB7a was processed using Frit 418. During processing of each sludge batch, the DWPF is required to take at least one glass sample to meet the objectives of the Glass Product Control Program (GPCP), which is governed by the DWPF Waste Compliance Plan, and to complete the necessary Production Records so that the final glass product may be disposed of at a Federal Repository. Three pour stream glass samples and two Melter Feed Tank (MFT) slurry samples were collected while processing SB7a. These additional samples were taken during SB7a to understand the impact of antifoam and the melter bubblers on glass redox chemistry. The samples were transferred to the Savannah River National Laboratory (SRNL) where they were analyzed. The following conclusions were drawn from the analytical results provided in this report: (1) The sum of oxides for the official SB7a pour stream glass is within the Product Composition Control System (PCCS) limits (95-105 wt%). (2) The average calculated Waste Dilution Factor (WDF) for SB7a is 2.3. In general, the measured radionuclide content of the official SB7a pour stream glass is in good agreement with the calculated values from the Tank 40 dried sludge results from the SB7a Waste Acceptance Program Specification (WAPS) sample. (3) As in previous pour stream samples, ruthenium and rhodium inclusions were detected by Scanning Electron Microscopy-Electron Dispersive Spectroscopy (SEM-EDS) in the official SB7a pour stream sample. (4) The Product Consistency Test (PCT) results indicate that the official SB7a pour stream glass meets the waste acceptance criteria for durability with a normalized boron release of 0.64 g/L, which is an order of magnitude less than the Environmental

  3. ANALYSIS OF DWPF SLUDGE BATCH 6 (MACROBATCH 7) POUR STREAM GLASS SAMPLES

    SciTech Connect (OSTI)

    Johnson, F.

    2012-01-20

    The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 6 (SB6), also referred to as Macrobatch 7 (MB7), in June 2010. SB6 is a blend of the heel of Tank 40 from Sludge Batch 5 (SB5), H-Canyon Np transfers and SB6 that was transferred to Tank 40 from Tank 51.1 SB6 was processed using Frit 418. Sludge is received into the DWPF Chemical Processing Cell (CPC) and is processed through the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator Tank (SME). The treated sludge slurry is then transferred to the Melter Feed Tank (MFT) and fed to the melter. During processing of each sludge batch, the DWPF is required to take at least one glass sample to meet the objectives of the Glass Product Control Program (GPCP) and to complete the necessary Production Records so that the final glass product may be disposed of at a Federal Repository. The DWPF requested various analyses of radioactive glass samples obtained from the melter pour stream during processing of SB6 as well as reduction/oxidation (REDOX) analysis of MFT samples to determine the impact of Argon bubbling. Sample analysis followed the Task Technical and Quality Assurance Plan (TTQAP) and an Analytical Study Plan (ASP). Four Pour Stream (PS) glass samples and two MFT slurry samples were delivered to the Savannah River National Laboratory (SRNL) from the DWPF. Table 1-1 lists the sample information for each pour stream glass sample. SB6 PS3 (S03472) was selected as the official pour stream sample for SB6 and full analysis was requested. This report details the visual observations of the as-received SB6 PS No.3 glass sample as well as results for the chemical composition, Product Consistency Test (PCT), radionuclide content, noble metals, and glass density. REDOX results will be provided for all four pour stream samples and vitrified samples of MFT-558 and MFT-568A. Where appropriate, data from other pour stream samples will be provided.

  4. Analysis Of The Sludge Batch 7b (Macrobatch 9) DWPF Pour Stream Glass Sample

    SciTech Connect (OSTI)

    Johnson, F. C.; Crawford, C. L.; Pareizs, J. M.

    2013-11-18

    The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 7b (SB7b), also referred to as Macrobatch 9 (MB9), in January 2012. SB7b is a blend of the heel of Tank 40 from Sludge Batch 7a (SB7a) and the SB7b material that was transferred to Tank 40 from Tank 51. SB7b was processed using Frit 418. During processing of each sludge batch, the DWPF is required to take at least one glass sample to meet the objectives of the Glass Product Control Program (GPCP), which is governed by the DWPF Waste Form Compliance Plan, and to complete the necessary Production Records so that the final glass product may be disposed of at a Federal Repository. Two pour stream glass samples were collected while processing SB7b. The samples were transferred to the Savannah River National Laboratory (SRNL) where one was analyzed and the other was archived. The following conclusions were drawn from the analytical results provided in this report: The sum of oxides for the official SB7b pour stream glass is within the Product Composition Control System (PCCS) limits (95-105 wt%); The average calculated Waste Dilution Factor (WDF) for SB7b is 2.3. In general, the measured radionuclide content of the official SB7b pour stream glass is in good agreement with the calculated values from the Tank 40 dried sludge results from the SB7b Waste Acceptance Program Specification (WAPS) sample; As in previous pour stream samples, ruthenium and rhodium inclusions were detected by Scanning Electron Microscopy-Electron Dispersive Spectroscopy (SEM-EDS) in the SB7b pour stream sample; The Product Consistency Test (PCT) results indicate that the official SB7b pour stream glass meets the waste acceptance criteria for durability with a normalized boron release of 0.8 g/L, which is an order of magnitude less than the Environmental Assessment (EA) glass; The measured density of the SB7b pour stream glass was 2.70 g/cm{sup 3}; The Fe{sup 2+}/ΣFe ratio of the SB7b pour stream samples was 0.07.

  5. Verification Of The Defense Waste Processing Facility's (DWPF) Process Digestion Methods For The Sludge Batch 8 Qualification Sample

    SciTech Connect (OSTI)

    Click, D. R.; Edwards, T. B.; Wiedenman, B. J.; Brown, L. W.

    2013-03-18

    This report contains the results and comparison of data generated from inductively coupled plasma – atomic emission spectroscopy (ICP-AES) analysis of Aqua Regia (AR), Sodium Peroxide/Sodium Hydroxide Fusion Dissolution (PF) and Cold Chem (CC) method digestions and Cold Vapor Atomic Absorption analysis of Hg digestions from the DWPF Hg digestion method of Sludge Batch 8 (SB8) Sludge Receipt and Adjustment Tank (SRAT) Receipt and SB8 SRAT Product samples. The SB8 SRAT Receipt and SB8 SRAT Product samples were prepared in the SRNL Shielded Cells, and the SRAT Receipt material is representative of the sludge that constitutes the SB8 Batch or qualification composition. This is the sludge in Tank 51 that is to be transferred into Tank 40, which will contain the heel of Sludge Batch 7b (SB7b), to form the SB8 Blend composition.

  6. DWPF coupled feed flowsheet material balance with batch one sludge and copper nitrate catalyst

    SciTech Connect (OSTI)

    Choi, A.S.

    1993-09-28

    The SRTC has formally transmitted a recommendation to DWPF to replace copper formate with copper nitrate as the catalyst form during precipitate hydrolysis [1]. The SRTC was subsequently requested to formally document the technical bases for the recommendation. A memorandum was issued on August 23, 1993 detailing the activities (and responsible individuals) necessary to address the impact of this change in catalyst form on process compatibility, safety, processibility environmental impact and product glass quality [2]. One of the activities identified was the preparation of a material balance in which copper nitrate is substituted for copper formate and the identification of key comparisons between this material balance and the current Batch 1 sludge -- Late Wash material balance [3].

  7. SLUDGE BATCH 4 FOLLOW-UP QUALIFICATION STUDIES TO EVALUATE HYDROGEN GENERATION

    SciTech Connect (OSTI)

    Pareizs, J; David Koopman, D; Dan Lambert, D; Cj Bannochie, C

    2007-08-23

    Follow-up testing was conducted to better understand the excessive hydrogen generation seen in the initial Sludge Batch 4 (SB4) qualification Sludge Receipt and Adjustment Tank/Slurry Mix Evaporator (SRAT/SME) simulation in the Savannah River National Laboratory (SRNL) Shielded Cells. This effort included both radioactive and simulant work. The initial SB4 qualification test produced 0.59 lbs/hr hydrogen in the SRAT, which was just below the DWPF SRAT limit of 0.65 lbs/hr, and the test produced over 0.5 lbs/hr hydrogen in the SME cycle on two separate occasions, which were over the DWPF SME limit of 0.223 lbs/hr.

  8. Numerical model for the vacuum pyrolysis of scrap tires in batch reactors

    SciTech Connect (OSTI)

    Yang, J.; Tanguy, P.A.; Roy, C.

    1995-06-01

    A quantitative model for scrap tire pyrolysis in a batch scale reactor developed comprises the following basic phenomena: conduction inside tire particles; conduction, convection, and radiation between the feedstock particles or between the fluids and the particles; tire pyrolysis reaction; exothermicity and endothermicity caused by tire decomposition and volatilization; and the variation of the composition and the thermal properties of tire particles. This model was used to predict the transient temperature and density distributions in the bed of particles, the volatile product evolution rate, the mass change, the energy consumption during the pyrolysis process, and the pressure history in a tire pyrolysis reactor with a load of 1 kg. The model predictions agree well with independent experimental data.

  9. Analysis of Tank 35H Samples in Support of Salt Batch Planning

    SciTech Connect (OSTI)

    Hay, M. S.; Coleman, C. J.; Diprete, D. P.

    2015-04-30

    Savannah River Remediation obtained three samples from different heights within Tank 35H. The samples were analyzed by Savannah River National Laboratory to support Salt Batch planning. The results from the analysis indicate the compositions of the three samples show increasing concentrations for most analytes going from HTF-35-15-17 through HTF-35-15-19 corresponding to successively deeper sampling locations. The data indicate some stratification within the tank. The plutonium and Sr-90 concentrations measured in the filtered samples were slightly lower than in the decanted (unfiltered) samples. The difference in the results for the filtered and unfiltered samples likely lies within the expected uncertainty for the measurement, but may indicate that filtration removed a small amount of suspended material from the samples.

  10. Analysis of tank 23H samples in support of salt batch planning

    SciTech Connect (OSTI)

    Hay, M. S.; Coleman, C. J.; Diprete, D. P.

    2015-08-14

    Savannah River Remediation obtained three samples from different heights within Tank 23H. The samples were analyzed by Savannah River National Laboratory to support salt batch planning. The results from the analysis indicate the top two samples from the tank appear similar in composition. The lowest sample from the tank contained significantly more solids and a more concentrated salt solution. The filtered supernate from the bottom sample showed ~60% lower Sr-90 and Pu-238 concentrations than the decanted (unfiltered) supernate results which may indicate the presence of some small amount of entrained solid particles in the decanted sample. The mercury concentrations measured in the filtered supernate were fairly low for all three samples ranging from 11.2 to 42.3 mg/L.

  11. Effects of propionate and acetate additions on solvent production in batch cultures of clostridium acetobutylicum

    SciTech Connect (OSTI)

    Huesemann, M.H.W. ); Papoutsakis, E.T. )

    1990-05-01

    Addition of acetate or propionate to uncontrolled-pH batch cultures does not affect the initiation of solventogenesis but does enhance final solvent concentrations compared with those of unchallenged cultures. This observation can be explained in terms of the increased buffering capacity of the medium brought about by the added acids, resulting in protection against premature growth inhibition due to low culture pH values at the end of the fermentation. The uptake of propionic acid from the medium does not proceed solely via the coenzyme A-transferase pathway, since less acetone than propanol is formed. Therefore, at least 50% of the propionic acid is taken up through the reversed kinase-phosphotransbutyrylase reaction pathway.

  12. Kinetics and dynamic modelling of batch anaerobic digestion of municipal solid waste in a stirred reactor

    SciTech Connect (OSTI)

    Nopharatana, Annop; Pullammanappallil, Pratap C.; Clarke, William P.

    2007-07-01

    A series of batch, slurry anaerobic digestion experiments were performed where the soluble and insoluble fractions, and unwashed MSW were separately digested in a 200 l stirred stainless steel vessel at a pH of 7.2 and a temperature of 38 deg. C. It was found that 7% of the total MSW COD was readily soluble, of which 80% was converted to biogas; 50% of the insoluble fraction was solubilised, of this only 80% was converted to biogas. The rate of digesting the insoluble fraction was about four times slower than the rate of digesting the soluble fraction; 48% of the total COD was converted to biogas and 40% of the total nitrogen was converted to ammonia. Soluble and insoluble fractions were broken down simultaneously. The minimum time to convert 95% of the degradable fraction to biogas was 20 days. The lag phase for the degradation of insoluble fraction of MSW can be overcome by acclimatising the culture with the soluble fraction. The rate of digestion and the methane yield was not affected by particle size (within the range of 2-50 mm). A dynamic model was developed to describe batch digestion of MSW. The parameters of the model were estimated using data from the separate digestion of soluble and insoluble fractions and validated against data from the digestion of unwashed MSW. Trends in the specific aceticlastic and formate-utilising methanogenic activity were used to estimate initial methanogenic biomass concentration and bacterial death rate coefficient. The kinetics of hydrolysis of insoluble fraction could be adequately described by a Contois equation and the kinetics of acidogenesis, and aceticlastic and hydrogen utilising methanogenesis by Monod equations.

  13. SLUDGE BATCH SUPPLEMENTAL SRAT RUNS EFFECTS OF YIELD STRESS AND CYCLE TIME INCREASE

    SciTech Connect (OSTI)

    Fernandez, A.

    2010-08-10

    The Defense Waste Processing Facility (DWPF) has transitioned from Sludge Batch 5 (SB5) processing to Sludge Batch 6 (SB6) processing. Phase III-Tank 40 Chemical Process Cell (CPC) flowsheet simulations have been completed to determine the initial processing conditions for the DWPF transition. The impact of higher yield stress (SB-25) and cycle time extension (SB6-26) on the physical and chemical effects of SB6 processing during the SRAT (Sludge Receipt and Adjustment Tank) cycle were evaluated. No significant impacts on the SRAT chemistry were noted during the higher yield stress run. In particular, no impact on mercury stripping was noted, indicating that settling of elemental mercury was not the primary factor in the low mercury recovery noted in the flowsheet testing. The SRAT product from this run retained the higher yield stress of the starting sludge. The run indicated that ultrasonication is an effective tool to increase the yield stress of simulants to targeted values and the chemistry of downstream processing is not impacted. Significant differences were noted in the cycle time extension test compared to the Phase III flowsheet baseline runs. Large decreases in the ammonia and hydrogen generation rates were noted along with reduced mercury stripping efficiency. The latter effect is similar to that of operating under a high acid stoichiometry. It is conceivable that, under the distinctly different conditions of high formic acid concentration (high acid run) or slow formic acid addition (extended run), that mercury could form amalgams with noble metals, possibly rendering both inert. Thus, the removal of free mercury and noble metals could decrease the rate of catalytic formic acid reactions which would decrease generation of ammonium and hydrogen. The potential underlying reasons for the behavior noted during this run would require additional testing.

  14. Experiences with a compost biofilter for VOC control from batch chemical manufacturing operations

    SciTech Connect (OSTI)

    Gilmore, G.L.; Briggs, T.G.

    1997-12-31

    The Synthetic Chemicals Division of Eastman Kodak Company makes a large number of complex organic chemicals using batch reactor syntheses. Exhaust gas, resulting from batch reactor operations, typically contains many different volatile organic chemicals with dynamic concentration profiles. Exhaust streams of this type have been considered difficult to treat effectively by biofiltration. Eastman Kodak Company was interested in exploring the applicability of biofiltration to treat these types of off-gas streams as an alternative to more costly control technologies. To this end, a 20,000 cfm capacity BIOTON{reg_sign} biofilter was installed in December 1995 in Kodak Park, Rochester, New York. A study was initiated to determine the overall efficiency of the biofilter, as well as the chemical specific efficiencies for a number of organic compounds. Flame ionization detectors operated continuously on the inlet and outlet of the biofilter to measure total hydrocarbon concentrations. A process mass spectrometer was installed to simultaneously monitor the concentrations of seven organics in the inlet and outlet of the biofilter. In addition, the process control software for the biofilter continuously recorded pressure drop, temperature, and moisture content of the bed. This paper presents operating and performance data for the BIOTON biofilter from start-up through about eleven months of continuous operation. Included are data collected over a wide range of loading conditions, during initial start-up, and during start-up after shutdown periods. Data for total hydrocarbons, methanol, acetone, and heptane are presented. The relationship between organic loading and removal efficiency is discussed in the biofilter, which typically operates significantly below its design loading specification. The overall control efficiency of the biofilter at design loadings exceeds the design control efficiency of 90%.

  15. VERIFICATION OF THE DEFENSE WASTE PROCESSING FACILITY'S (DWPF) PROCESS DIGESTION METHOD FOR THE SLUDGE BATCH 7A QUALIFICATION SAMPLE

    SciTech Connect (OSTI)

    Click, D.; Edwards, T.; Jones, M.; Wiedenman, B.

    2011-03-14

    For each sludge batch that is processed in the Defense Waste Processing Facility (DWPF), the Savannah River National Laboratory (SRNL) performs confirmation of the applicability of the digestion method to be used by the DWPF lab for elemental analysis of Sludge Receipt and Adjustment Tank (SRAT) receipt samples and SRAT product process control samples. DWPF SRAT samples are typically dissolved using a room temperature HF-HNO{sub 3} acid dissolution (i.e., DWPF Cold Chem Method, see DWPF Procedure SW4-15.201) and then analyzed by inductively coupled plasma - atomic emission spectroscopy (ICP-AES). This report contains the results and comparison of data generated from performing the Aqua Regia (AR), Sodium peroxide/Hydroxide Fusion (PF) and DWPF Cold Chem (CC) method digestions of Sludge Batch 7a (SB7a) SRAT Receipt and SB7a SRAT Product samples. The SB7a SRAT Receipt and SB7a SRAT Product samples were prepared in the SRNL Shielded Cells, and the SRAT Receipt material is representative of the sludge that constituates the SB7a Batch or qualification composition. This is the sludge in Tank 51 that is to be transferred into Tank 40, which will contain the heel of Sludge Batch 6 (SB6), to form the Sb7a Blend composition.

  16. Semi-Batch Deoxygenation of Canola- and Lard-Derived Fatty Acids to Diesel-Range Hydrocarbons

    SciTech Connect (OSTI)

    Ford, JP; Thapaliya, N; Kelly, MJ; Roberts, WL; Lamb, HH

    2013-12-01

    Fatty acids (FAs) derived via thermal hydrolysis of food-grade lard and canola oil were deoxygenated in the liquid phase using a commercially available 5 wt % Pd/C catalyst. Online quadrupole mass spectrometry and gas chromatography were used to monitor the effluent gases from the semi-batch stirred autoclave reactors. Stearic, oleic, and palmitic acids were employed as model compounds. A catalyst lifetime exceeding 2200 turnovers for oleic acid deoxygenation was demonstrated at 300 degrees C and 15 atm under 10% H-2. The initial decarboxylation rate of palmitic acid under 5% H-2 decreases sharply with increasing initial concentration; in contrast, the initial decarbonylation rate increases linearly, indicative of first-order kinetics. Scale-up of diesel-range hydrocarbon production was investigated by increasing the reactor vessel size, initial FA concentration, and FA/catalyst mass ratio. Lower CO2 selectivity and batch productivity were observed at the larger scales (600 and 5000 mL), primarily because of the higher initial FA concentration (67 wt %) employed. Because unsaturated FAs must be hydrogenated before deoxygenation can proceed at an appreciable rate, the additional batch time required for FA hydrogenation reduces the batch productivity for unsaturated feedstocks. Low-temperature hydrogenation of unsaturated feedstocks (using Pd/C or another less-expensive catalyst) prior to deoxygenation is recommended.

  17. THE SLUDGE BATCH 7A GLASS VARIABILITY STUDY WITH FRIT 418 AND FRIT 702

    SciTech Connect (OSTI)

    Peeler, D; Edwards, T

    2011-03-24

    The Defense Waste Processing Facility (DWPF) is preparing to initiate processing of Sludge Batch 7a (SB7a) in May 2011. To support qualification of SB7a, the Savannah River National Laboratory (SRNL) was requested to execute a variability study (VS) to assess the applicability of the current Product Composition Control System (PCCS) durability models for the Frit 418-SB7a compositional region of interest. The objective of this study was to demonstrate applicability of the current durability models to the SB7a compositional region of interest and acceptability of the SB7a glasses with respect to the Environmental Assessment (EA) glass in terms of durability as defined by the Product Consistency Test (PCT). To support programmatic objectives, twenty-eight SB7a glasses were selected based on the nominal sludge projections used to support the frit recommendation. Twenty-three of the SB7a VS glasses were based on the use of Frit 418, while 5 glasses were based on the use of Frit 702. Frit 702 was also identified as a viable candidate for SB7a, especially if SO{sub 4} concentrations are found to be higher than anticipated. Frit 702 has shown a higher SO{sub 4} retention capability as compared to Frit 418. With respect to acceptability, the PCT results of the SB7a-VS glasses are acceptable relative to the EA glass regardless of thermal history (quenched or canister centerline cooled) or compositional view (target or measured). More specifically, all of the SB7a glasses have normalized boron release values (NL [B]) less than 0.9 g/L as compared to the benchmark NL [B] value for EA of 16.695 g/L. With respect to the applicability of the current durability models to the SB7a VS compositional region of interest, all of the study glasses (based on target compositions) lie within the 95% confidence intervals of the model predictions. When model applicability is based on the measured compositions, all of the SB7a VS glasses are predictable with the exception of SB7aVS-02 and SB7

  18. Bagdad Plant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bagdad Plant 585 Silicon Drive Leechburg, P A 15656 * ATI Allegheny "'I Ludlum e-mail: Raymond.Polinski@ATImetals.com Mr. James Raba U.S. Department of Energy Office of Energy ...

  19. Method for automatically evaluating a transition from a batch manufacturing technique to a lean manufacturing technique

    DOE Patents [OSTI]

    Ivezic, Nenad; Potok, Thomas E.

    2003-09-30

    A method for automatically evaluating a manufacturing technique comprises the steps of: receiving from a user manufacturing process step parameters characterizing a manufacturing process; accepting from the user a selection for an analysis of a particular lean manufacturing technique; automatically compiling process step data for each process step in the manufacturing process; automatically calculating process metrics from a summation of the compiled process step data for each process step; and, presenting the automatically calculated process metrics to the user. A method for evaluating a transition from a batch manufacturing technique to a lean manufacturing technique can comprise the steps of: collecting manufacturing process step characterization parameters; selecting a lean manufacturing technique for analysis; communicating the selected lean manufacturing technique and the manufacturing process step characterization parameters to an automatic manufacturing technique evaluation engine having a mathematical model for generating manufacturing technique evaluation data; and, using the lean manufacturing technique evaluation data to determine whether to transition from an existing manufacturing technique to the selected lean manufacturing technique.

  20. Power/Performance Trade-offs of Small Batched LU Based Solvers on GPUs

    SciTech Connect (OSTI)

    Villa, Oreste; Fatica, Massimiliano; Gawande, Nitin A.; Tumeo, Antonino

    2013-08-26

    In this paper we propose and analyze a set of batched linear solvers for small matrices on Graphic Processing Units (GPUs), evaluating the various alternatives depending on the size of the systems to solve. We discuss three different solutions that operate with different level of parallelization and GPU features. The first, exploiting the CUBLAS library, manages matrices of size up to 32x32 and employs Warp level (one matrix, one Warp) parallelism and shared memory. The second works at Thread-block level parallelism (one matrix, one Thread-block), still exploiting shared memory but managing matrices up to 76x76. The third is Thread level parallel (one matrix, one thread) and can reach sizes up to 128x128, but it does not exploit shared memory and only relies on the high memory bandwidth of the GPU. The first and second solution only support partial pivoting, the third one easily supports partial and full pivoting, making it attractive to problems that require greater numerical stability. We analyze the trade-offs in terms of performance and power consumption as function of the size of the linear systems that are simultaneously solved. We execute the three implementations on a Tesla M2090 (Fermi) and on a Tesla K20 (Kepler).

  1. Organic and nitrogen removal from landfill leachate in aerobic granular sludge sequencing batch reactors

    SciTech Connect (OSTI)

    Wei Yanjie; Ji Min; Li Ruying; Qin Feifei

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Aerobic granular sludge SBR was used to treat real landfill leachate. Black-Right-Pointing-Pointer COD removal was analyzed kinetically using a modified model. Black-Right-Pointing-Pointer Characteristics of nitrogen removal at different ammonium inputs were explored. Black-Right-Pointing-Pointer DO variations were consistent with the GSBR performances at low ammonium inputs. - Abstract: Granule sequencing batch reactors (GSBR) were established for landfill leachate treatment, and the COD removal was analyzed kinetically using a modified model. Results showed that COD removal rate decreased as influent ammonium concentration increasing. Characteristics of nitrogen removal at different influent ammonium levels were also studied. When the ammonium concentration in the landfill leachate was 366 mg L{sup -1}, the dominant nitrogen removal process in the GSBR was simultaneous nitrification and denitrification (SND). Under the ammonium concentration of 788 mg L{sup -1}, nitrite accumulation occurred and the accumulated nitrite was reduced to nitrogen gas by the shortcut denitrification process. When the influent ammonium increased to a higher level of 1105 mg L{sup -1}, accumulation of nitrite and nitrate lasted in the whole cycle, and the removal efficiencies of total nitrogen and ammonium decreased to only 35.0% and 39.3%, respectively. Results also showed that DO was a useful process controlling parameter for the organics and nitrogen removal at low ammonium input.

  2. Completing Pre-Pilot Tasks To Scale Up Biomass Fractionation Pretreatment Apparatus From Batch To Continuous

    SciTech Connect (OSTI)

    Dick Wingerson

    2004-12-15

    PureVision Technology, Inc. (PureVision) was the recipient of a $200,000 Invention and Innovations (I&I) grant from the U. S. Department of Energy (DOE) to complete prepilot tasks in order to scale up its patented biomass fractionation pretreatment apparatus from batch to continuous processing. The initial goal of the I&I program, as detailed in PureVision's original application to the DOE, was to develop the design criteria to build a small continuous biomass fractionation pilot apparatus utilizing a retrofitted extruder with a novel screw configuration to create multiple reaction zones, separated by dynamic plugs within the reaction chamber that support the continuous counter-flow of liquids and solids at elevated temperature and pressure. Although the ultimate results of this 27-month I&I program exceeded the initial expectations, some of the originally planned tasks were not completed due to a modification of direction in the program. PureVision achieved its primary milestone by establishing the design criteria for a continuous process development unit (PDU). In addition, PureVision was able to complete the procurement, assembly, and initiate shake down of the PDU at Western Research Institute (WRI) in Laramie, WY during August 2003 to February 2004. During the month of March 2004, PureVision and WRI performed initial testing of the continuous PDU at WRI.

  3. Anaerobic sequencing batch reactor in pilot scale for treatment of tofu industry wastewater

    SciTech Connect (OSTI)

    Rahayu, Suparni Setyowati; Purwanto, Budiyono

    2015-12-29

    The small industry of tofu production process releases the waste water without being processed first, and the wastewater is directly discharged into water. In this study, Anaerobic Sequencing Batch Reactor in Pilot Scale for Treatment of Tofu Industry was developed through an anaerobic process to produce biogas as one kind of environmentally friendly renewable energy which can be developed into the countryside. The purpose of this study was to examine the fundamental characteristics of organic matter elimination of industrial wastewater with small tofu effective method and utilize anaerobic active sludge with Anaerobic Sequencing Bath Reactor (ASBR) to get rural biogas as an energy source. The first factor is the amount of the active sludge concentration which functions as the decomposers of organic matter and controlling selectivity allowance to degrade organic matter. The second factor is that HRT is the average period required substrate to react with the bacteria in the Anaerobic Sequencing Bath Reactor (ASBR).The results of processing the waste of tofu production industry using ASBR reactor with active sludge additions as starter generates cumulative volume of 5814.4 mL at HRT 5 days so that in this study it is obtained the conversion 0.16 L of CH{sub 4}/g COD and produce biogas containing of CH{sub 4}: 81.23% and CO{sub 2}: 16.12%. The wastewater treatment of tofu production using ASBR reactor is able to produce renewable energy that has economic value as well as environmentally friendly by nature.

  4. RASTtk: A modular and extensible implementation of the RAST algorithm for building custom annotation pipelines and annotating batches of genomes

    SciTech Connect (OSTI)

    Brettin, Thomas; Davis, James J.; Disz, Terry; Edwards, Robert A.; Gerdes, Svetlana; Olsen, Gary J.; Olson, Robert; Overbeek, Ross; Parrello, Bruce; Pusch, Gordon D.; Shukla, Maulik; Thomason, III, James A.; Stevens, Rick; Vonstein, Veronika; Wattam, Alice R.; Xia, Fangfang

    2015-02-10

    The RAST (Rapid Annotation using Subsystem Technology) annotation engine was built in 2008 to annotate bacterial and archaeal genomes. It works by offering a standard software pipeline for identifying genomic features (i.e., protein-encoding genes and RNA) and annotating their functions. Recently, in order to make RAST a more useful research tool and to keep pace with advancements in bioinformatics, it has become desirable to build a version of RAST that is both customizable and extensible. In this paper, we describe the RAST tool kit (RASTtk), a modular version of RAST that enables researchers to build custom annotation pipelines. RASTtk offers a choice of software for identifying and annotating genomic features as well as the ability to add custom features to an annotation job. RASTtk also accommodates the batch submission of genomes and the ability to customize annotation protocols for batch submissions. This is the first major software restructuring of RAST since its inception.

  5. The effect of SO2 on mineral carbonation in batch tests

    SciTech Connect (OSTI)

    Summers, Cathy A.; Dahlin, David C.; Ochs, Thomas L.

    2004-01-01

    CO2 sequestration is a key element of future emission-free fossil-fueled power plants. Other constituents of flue gas must also be captured and rendered innocuous. Contemporary power plants remove SOx from exit gases, but next-generation plants may simultaneously treat CO2, SOx, and other pollutants. Pioneering tests at the U.S. Department of Energy's Albany Research Center investigated the combined treatment of CO2 and SO2 in a mineral-carbonation process. SO2 was removed from the gas stream, and as a small fraction of the total volume of mineralizing gas, it did not inhibit the carbonation reaction. The results indicate that this approach to CO2 sequestration could be used to treat multiple pollutants.

  6. DETERMINATION OF REPORTABLE RADIONUCLIDES FOR DWPF SLUDGE BATCH 7B (MACROBATCH 9)

    SciTech Connect (OSTI)

    Crawford, C. L.; Diprete, D. P.

    2014-05-01

    The Waste Acceptance Product Specifications (WAPS) 1.2 require that “The Producer shall report the inventory of radionuclides (in Curies) that have half-lives longer than 10 years and that are, or will be, present in concentrations greater than 0.05 percent of the total inventory for each waste type indexed to the years 2015 and 3115”. As part of the strategy to comply with WAPS 1.2, the Defense Waste Processing Facility (DWPF) will report for each waste type, all radionuclides (with half-lives greater than 10 years) that have concentrations greater than 0.01 percent of the total inventory from time of production through the 1100 year period from 2015 through 3115. The initial listing of radionuclides to be included is based on the design-basis glass as identified in the Waste Form Compliance Plan (WCP) and Waste Form Qualification Report (WQR). However, it is required that this list be expanded if other radionuclides with half-lives greater than 10 years are identified that may meet the greater than 0.01% criterion for Curie content. Specification 1.6 of the WAPS, International Atomic Energy Agency (IAEA) Safeguards Reporting for High Level Waste (HLW), requires that the ratio by weights of the following uranium and plutonium isotopes be reported: U-233, U-234, U-235, U-236, U-238, Pu-238, Pu-239, Pu-240, Pu-241, and Pu- 242. Therefore, the complete set of reportable radionuclides must also include this set of U and Pu isotopes. The DWPF is receiving radioactive sludge slurry from HLW Tank 40. The radioactive sludge slurry in Tank 40 is a blend of the heel from Sludge Batch 7a (SB7a) and Sludge Batch 7b (SB7b) that was transferred to Tank 40 from Tank 51. The blend of sludge in Tank 40 is also referred to as Macrobatch 9 (MB9). This report develops the list of reportable radionuclides and associated activities as a function of time. The DWPF will use this list and the activities as one of the inputs for the development of the Production Records that relate to

  7. Determination Of Reportable Radionuclides For DWPF Sludge Batch 7B (Macrobatch 9)

    SciTech Connect (OSTI)

    Crawford, C. L.; DiPrete, D. P.

    2013-08-22

    The Waste Acceptance Product Specifications (WAPS) 1.2 require that “The Producer shall report the inventory of radionuclides (in Curies) that have half-lives longer than 10 years and that are, or will be, present in concentrations greater than 0.05 percent of the total inventory for each waste type indexed to the years 2015 and 3115”. As part of the strategy to comply with WAPS 1.2, the Defense Waste Processing Facility (DWPF) will report for each waste type, all radionuclides (with half-lives greater than 10 years) that have concentrations greater than 0.01 percent of the total inventory from time of production through the 1100 year period from 2015 through 3115. The initial listing of radionuclides to be included is based on the design-basis glass as identified in the Waste Form Compliance Plan (WCP) and Waste Form Qualification Report (WQR). However, it is required that this list be expanded if other radionuclides with half-lives greater than 10 years are identified that may meet the greater than 0.01% criterion for Curie content. Specification 1.6 of the WAPS, International Atomic Energy Agency (IAEA) Safeguards Reporting for High Level Waste (HLW), requires that the ratio by weights of the following uranium and plutonium isotopes be reported: U-233, U-234, U-235, U-236, U-238, Pu-238, Pu-239, Pu-240, Pu-241, and Pu-242. Therefore, the complete set of reportable radionuclides must also include this set of U and Pu isotopes. The DWPF is receiving radioactive sludge slurry from HLW Tank 40. The radioactive sludge slurry in Tank 40 is a blend of the heel from Sludge Batch 7a (SB7a) and Sludge Batch 7b (SB7b) that was transferred to Tank 40 from Tank 51. The blend of sludge in Tank 40 is also referred to as Macrobatch 9 (MB9). This report develops the list of reportable radionuclides and associated activities as a function of time. The DWPF will use this list and the activities as one of the inputs for the development of the Production Records that relate to

  8. SLUDGE WASHING AND DEMONSTRATION OF THE DWPF FLOWSHEET IN THE SRNL SHIELDED CELLS FOR SLUDGE BATCH 7A QUALIFICATION

    SciTech Connect (OSTI)

    Pareizs, J.; Billings, A.; Click, D.

    2011-07-08

    Waste Solidification Engineering (WSE) has requested that characterization and a radioactive demonstration of the next batch of sludge slurry (Sludge Batch 7a*) be completed in the Shielded Cells Facility of the Savannah River National Laboratory (SRNL) via a Technical Task Request (TTR). This characterization and demonstration, or sludge batch qualification process, is required prior to transfer of the sludge from Tank 51 to the Defense Waste Processing Facility (DWPF) feed tank (Tank 40). The current WSE practice is to prepare sludge batches in Tank 51 by transferring sludge from other tanks. Discharges of nuclear materials from H Canyon are often added to Tank 51 during sludge batch preparation. The sludge is washed and transferred to Tank 40, the current DWPF feed tank. Prior to transfer of Tank 51 to Tank 40, SRNL simulates the Tank Farm and DWPF processes with a Tank 51 sample (referred to as the qualification sample). Sludge Batch 7a (SB7a) is composed of portions of Tanks 4, 7, and 12; the Sludge Batch 6 heel in Tank 51; and a plutonium stream from H Canyon. SRNL received the Tank 51 qualification sample (sample ID HTF-51-10-125) following sludge additions to Tank 51. This report documents: (1) The washing (addition of water to dilute the sludge supernate) and concentration (decanting of supernate) of the SB7a - Tank 51 qualification sample to adjust sodium content and weight percent insoluble solids to Tank Farm projections. (2) The performance of a DWPF Chemical Process Cell (CPC) simulation using the washed Tank 51 sample. The simulation included a Sludge Receipt and Adjustment Tank (SRAT) cycle, where acid was added to the sludge to destroy nitrite and reduce mercury, and a Slurry Mix Evaporator (SME) cycle, where glass frit was added to the sludge in preparation for vitrification. The SME cycle also included replication of five canister decontamination additions and concentrations. Processing parameters were based on work with a non

  9. Waste Treatment Plant Liquid Effluent Treatability Evaluation

    SciTech Connect (OSTI)

    LUECK, K.J.

    2001-06-07

    Bechtel National, Inc. (BNI) provided a forecast of the radioactive, dangerous liquid effluents expected to be generated by the Waste Treatment Plant (WTP). The forecast represents the liquid effluents generated from the processing of 25 distinct batches of tank waste through the WTP. The WTP liquid effluents will be stored, treated, and disposed of in the Liquid Effluent Retention Facility (LERF) and the Effluent Treatment Facility (ETF). Fluor Hanford, Inc. (FH) evaluated the treatability of the WTP liquid effluents in the LERFIETF. The evaluation was conducted by comparing the forecast to the LERFIETF treatability envelope, which provides information on the items that determine if a liquid effluent is acceptable for receipt and treatment at the LERFIETF. The WTP liquid effluent forecast is outside the current LERFlETF treatability envelope. There are several concerns that must be addressed before the WTP liquid effluents can be accepted at the LERFIETF.

  10. Frit Development Efforts for Sludge Batch 4 (SB4): Model-Based Assessments

    SciTech Connect (OSTI)

    Peeler, D. K.; Edwards, T. B.

    2005-03-05

    The model-based assessments of nominal Sludge Batch 4 (SB4) compositions suggest that a viable frit candidate does not appear to be a limiting factor as the Closure Business Unit (CBU) considers various tank blending options and/or washing strategies. This statement is based solely on the projected operating windows derived from model predictions and does not include assessments of SO{sub 4} solubility or melt rate issues. The viable frit candidates covered a range of Na{sub 2}O concentrations (from 8% to 13%--including Frit 418 and Frit 320) using a ''sliding Na{sub 2}O scale'' concept (i.e., 1% increase in Na{sub 2}O being balanced by a 1% reduction in SiO{sub 2}) which effectively balances the alkali content of the incoming sludge with that in the frit to maintain and/or increase the projected operating window size while potentially leading to improved melt rate and/or waste loadings. This strategy or approach allows alternative tank blending strategies and/or different washing scenarios to be considered and accounted for in an effective manner without wholesale changes to the frit composition. In terms of projected operating windows, in general, the sludge/frit systems evaluated resulted in waste loading intervals from 25 to the mid-40%'s or even the mid-50%'s. The results suggest that a single frit could be selected for use with all 20 options which indicates some degree of frit robustness with respect to sludge compositional variation. In fact, use of Frit 418 or Frit 320 (the ''cornerstone'' frits given previous processing experience in the Defense Waste Processing Facility (DWPF)) are plausible for most (if not all) options being considered. However, the frit selection process also needs to consider potential processing issues such as melt rate. Based on historical trends between melt rate and total alkali content, one may elect to use the frit with the highest alkali content that still yields an acceptable operating window. However, other constraints may

  11. Deming Solar Plant Solar Power Plant | Open Energy Information

    Open Energy Info (EERE)

    Deming Solar Plant Solar Power Plant Jump to: navigation, search Name Deming Solar Plant Solar Power Plant Facility Deming Solar Plant Sector Solar Facility Type Photovoltaic...

  12. Prescott Airport Solar Plant Solar Power Plant | Open Energy...

    Open Energy Info (EERE)

    Prescott Airport Solar Plant Solar Power Plant Jump to: navigation, search Name Prescott Airport Solar Plant Solar Power Plant Facility Prescott Airport Solar Plant Sector Solar...

  13. Solana Generating Plant Solar Power Plant | Open Energy Information

    Open Energy Info (EERE)

    Solana Generating Plant Solar Power Plant Jump to: navigation, search Name Solana Generating Plant Solar Power Plant Facility Solana Generating Plant Sector Solar Facility Type...

  14. Better Plants

    Broader source: Energy.gov [DOE]

    Leading manufacturers and industrial-scale energy-using organizations demonstrate their commitment to improving energy performance by signing a voluntary pledge to reduce their energy intensity by 25% over a ten year period. The U.S. Department of Energys Better Buildings, Better Plants Program is an important partnership which consists of approximately 150 industrial companies, representing about 2,300 facilities and close to 11% of the total U.S. manufacturing energy footprint as well as several water and wastewater treatment organizations.

  15. Effect of fed-batch vs. continuous mode of operation on microbial fuel cell performance treating biorefinery wastewater

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pannell, Tyler C.; Goud, R. Kannaiah; Schell, Daniel J.; Borole, Abhijeet P.

    2016-05-01

    Bioelectrochemical systems have been shown to treat low-value biorefinery streams while recovering energy, however, low current densities and anode conversion efficiencies (ACE) limit their application. A bioanode was developed via enrichment of electroactive biofilm under fed-batch and continuous feeding conditions using corn stover-derived waste stream. The continuously-fed MFC exhibited a current density of 5.8±0.06 A/m2 and an ACE of 39%±4. The fed-batch MFC achieved a similar current density and an ACE of 19.2%, however, its performance dropped after 36 days of operation to 1.1 A/m2 and 0.5%, respectively. In comparison, the ACE of the continuously-fed MFC remained stable achieving anmore » ACE of 30% ± 3 after 48 days of operation. An MFC treating a biorefinery stream post fuel separation achieved a current density of 10.7±0.1 A/m2 and an ACE of 57% ± 9 at an organic loading of 12.5 g COD/L-day. Characterization of the microbial communities indicate higher abundance of Firmicutes and Proteobacteria and lower abundance of Bacteriodetes and a higher level of Geobacter spp. (1.4% vs. 0.2%) in continuously-fed MFC vs. fed-batch MFC. Finally, the results demonstrate that limiting substrate to the equivalent maximum current that the anode can generate, maintains MFC performance over a long term for high strength wastewaters, such as those generated in the biorefinery.« less

  16. VERIFICATION OF THE DEFENSE WASTE PROCESSING FACILITY PROCESS DIGESTION METHOD FOR THE SLUDGE BATCH 6 QUALIFICATION SAMPLE

    SciTech Connect (OSTI)

    Click, D.; Jones, M.; Edwards, T.

    2010-06-09

    For each sludge batch that is processed in the Defense Waste Processing Facility (DWPF), the Savannah River National Laboratory (SRNL) confirms applicability of the digestion method to be used by the DWPF lab for elemental analysis of Sludge Receipt and Adjustment Tank (SRAT) receipt samples and SRAT product process control samples.1 DWPF SRAT samples are typically dissolved using a room temperature HF-HNO3 acid dissolution (i.e., DWPF Cold Chem (CC) Method, see DWPF Procedure SW4-15.201) and then analyzed by inductively coupled plasma - atomic emission spectroscopy (ICPAES). In addition to the CC method confirmation, the DWPF lab's mercury (Hg) digestion method was also evaluated for applicability to SB6 (see DWPF procedure 'Mercury System Operating Manual', Manual: SW4-15.204. Section 6.1, Revision 5, Effective date: 12-04-03). This report contains the results and comparison of data generated from performing the Aqua Regia (AR), Sodium Peroxide/Hydroxide Fusion (PF) and DWPF Cold Chem (CC) method digestion of Sludge Batch 6 (SB6) SRAT Receipt and SB6 SRAT Product samples. For validation of the DWPF lab's Hg method, only SRAT receipt material was used and compared to AR digestion results. The SB6 SRAT Receipt and SB6 SRAT Product samples were prepared in the SRNL Shielded Cells, and the SRAT Receipt material is representative of the sludge that constitutes the SB6 Batch or qualification composition. This is the sludge in Tank 51 that is to be transferred into Tank 40, which will contain the heel of Sludge Batch 5 (SB5), to form the SB6 Blend composition. In addition to the 16 elements currently measured by the DWPF, this report includes Hg and thorium (Th) data (Th comprising {approx}2.5 - 3 Wt% of the total solids in SRAT Receipt and SRAT Product, respectively) and provides specific details of ICP-AES analysis of Th. Thorium was found to interfere with the U 367.007 nm emission line, and an inter-element correction (IEC) had to be applied to U data, which is also

  17. Characterization of Contaminant Levels in the P-Area Wetland...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory (SREL) has a strong research history on the ecological effects of contaminants on the Savannah River Site (SRS), including the effects of coal combustion wastes (CCW). ...

  18. Sludge Washing And Demonstration Of The DWPF Flowsheet In The SRNL Shielded Cells For Sludge Batch 8 Qualification

    SciTech Connect (OSTI)

    Pareizs, J. M.; Crawford, C. L.

    2013-04-26

    The current Waste Solidification Engineering (WSE) practice is to prepare sludge batches in Tank 51 by transferring sludge from other tanks to Tank 51. Tank 51 sludge is washed and transferred to Tank 40, the current Defense Waste Processing Facility (DWPF) feed tank. Prior to transfer of Tank 51 to Tank 40, the Savannah River National Laboratory (SRNL) typically simulates the Tank Farm and DWPF processes using a Tank 51 sample (referred to as the qualification sample). WSE requested the SRNL to perform characterization on a Sludge Batch 8 (SB8) sample and demonstrate the DWPF flowsheet in the SRNL shielded cells for SB8 as the final qualification process required prior to SB8 transfer from Tank 51 to Tank 40. A 3-L sample from Tank 51 (the SB8 qualification sample; Tank Farm sample HTF-51-12-80) was received by SRNL on September 20, 2012. The as-received sample was characterized prior to being washed. The washed material was further characterized and used as the material for the DWPF process simulation including a Sludge Receipt and Adjustment Tank (SRAT) cycle, a Slurry Mix Evaporator (SME) cycle, and glass fabrication and chemical durability measurements.

  19. RASTtk: A modular and extensible implementation of the RAST algorithm for building custom annotation pipelines and annotating batches of genomes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brettin, Thomas; Davis, James J.; Disz, Terry; Edwards, Robert A.; Gerdes, Svetlana; Olsen, Gary J.; Olson, Robert; Overbeek, Ross; Parrello, Bruce; Pusch, Gordon D.; et al

    2015-02-10

    The RAST (Rapid Annotation using Subsystem Technology) annotation engine was built in 2008 to annotate bacterial and archaeal genomes. It works by offering a standard software pipeline for identifying genomic features (i.e., protein-encoding genes and RNA) and annotating their functions. Recently, in order to make RAST a more useful research tool and to keep pace with advancements in bioinformatics, it has become desirable to build a version of RAST that is both customizable and extensible. In this paper, we describe the RAST tool kit (RASTtk), a modular version of RAST that enables researchers to build custom annotation pipelines. RASTtk offersmore » a choice of software for identifying and annotating genomic features as well as the ability to add custom features to an annotation job. RASTtk also accommodates the batch submission of genomes and the ability to customize annotation protocols for batch submissions. This is the first major software restructuring of RAST since its inception.« less

  20. SLUDGE WASHING AND DEMONSTRATION OF THE DWPF FLOWSHEET IN THE SRNL SHIELDED CELLS FOR SLUDGE BATCH 6 QUALIFICATION

    SciTech Connect (OSTI)

    Pareizs, J.; Pickenheim, B.; Bannochie, C.; Billings, A.; Bibler, N.; Click, D.

    2010-10-01

    Prior to initiating a new sludge batch in the Defense Waste Processing Facility (DWPF), Savannah River National Laboratory (SRNL) is required to simulate this processing, including Chemical Process Cell (CPC) simulation, waste glass fabrication, and chemical durability testing. This report documents this simulation for the next sludge batch, Sludge Batch 6 (SB6). SB6 consists of Tank 12 material that has been transferred to Tank 51 and subjected to Low Temperature Aluminum Dissolution (LTAD), Tank 4 sludge, and H-Canyon Pu solutions. Following LTAD and the Tank 4 addition, Liquid Waste Operations (LWO) provided SRNL a 3 L sample of Tank 51 sludge for SB6 qualification. Pu solution from H Canyon was also received. SB6 qualification included washing the sample per LWO plans/projections (including the addition of Pu from H Canyon), DWPF CPC simulations, waste glass fabrication (vitrification), and waste glass characterization and chemical durability evaluation. The following are significant observations from this demonstration. Sludge settling improved slightly as the sludge was washed. SRNL recommended (and the Tank Farm implemented) one less wash based on evaluations of Tank 40 heel projections and projections of the glass composition following transfer of Tank 51 to Tank 40. Thorium was detected in significant quantities (>0.1 wt % of total solids) in the sludge. In past sludge batches, thorium has been determined by Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS), seen in small quantities, and reported with the radionuclides. As a result of the high thorium, SRNL-AD has added thorium to their suite of Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) elements. The acid stoichiometry for the DWPF Sludge Receipt and Adjustment Tank (SRAT) processing of 115%, or 1.3 mol acid per liter of SRAT receipt slurry, was adequate to accomplish some of the goals of SRAT processing: nitrite was destroyed to below 1,000 mg/kg and mercury was removed to

  1. LIPID PRODUCTION BY DUNALIELLA SALINA IN BATCH CULTURE: EFFECTS OF NITROGEN LIMITATION AND LIGHT INTENSITY

    SciTech Connect (OSTI)

    Weldy, C.S.; Huesemann, M.

    2007-01-01

    Atmospheric carbon dioxide (CO2) concentrations are increasing and may cause unknown deleterious environmental effects if left unchecked. The Intergovernmental Panel on Climate Change (IPCC) has predicted in its latest report a 2C to 4C increase in global temperatures even with the strictest CO2 mitigation practices. Global warming can be attributed in large part to the burning of carbon-based fossil fuels, as the concentration of atmospheric CO2 is directly related to the burning of fossil fuels. Biofuels which do not add CO2 to the atmosphere are presently generated primarily from terrestrial plants, i.e., ethanol from corn grain and biodiesel from soybean oil. The production of biofuels from terrestrial plants is severely limited by the availability of fertile land. Lipid production from microalgae and its corresponding biodiesel production have been studied since the late 1970s but large scale production has remained economically infeasible due to the large costs of sterile growing conditions required for many algal species. This study focuses on the potential of the halophilic microalgae species Dunaliella salina as a source of lipids and subsequent biodiesel production. The lipid production rates under high light and low light as well as nitrogen suffi cient and nitrogen defi cient culture conditions were compared for D. salina cultured in replicate photobioreactors. The results show (a) cellular lipid content ranging from 16 to 44% (wt), (b) a maximum culture lipid concentration of 450mg lipid/L, and (c) a maximum integrated lipid production rate of 46mg lipid/L culture*day. The high amount of lipids produced suggests that D. salina, which can be mass-cultured in non-sterile outdoor ponds, has strong potential to be an economically valuable source for renewable oil and biodiesel production.

  2. SUMMARY REPORT FOR THE ANALYSIS OF THE SLUDGE BATCH 7A (MACROBATCH 8) DWPF POUR STREAM GLASS SAMPLE FOR CANISTER S03619

    SciTech Connect (OSTI)

    Johnson, F.

    2012-05-01

    In order to comply with the Waste Acceptance Specifications in Sludge Batch 7a (Macrobatch 8), Savannah River National Laboratory personnel characterized the Defense Waste Processing Facility (DWPF) pour stream glass sample collected while filling canister S03619. This report summarizes the results of the compositional analysis for reportable oxides and radionuclides, and the normalized Product Consistency Test (PCT) results. The PCT responses indicate that the DWPF produced glass that is significantly more durable than the Environmental Assessment glass. Results and further details are documented in 'Analysis of DWPF Sludge Batch 7a (Macrobatch 8) Pour Stream Samples,' SRNL-STI-2012-00017.

  3. Hydrogen Evolution and Sludge Suspension During the Preparation of the First Batch of Sludge at the Savannah River Site

    SciTech Connect (OSTI)

    Hay, M.S.; Lee, E.D.

    1995-03-01

    The first batch of High Level Radioactive Sludge for the Defense Waste Processing Facility is being prepared in two 4.9 million liter waste tanks. The preparation involves removing water soluble salts by washing (water addition, sludge suspension, settling and decantation). Sludge suspension is accomplished using long shafted slurry pumps that are mounted on rotating turntables. During the sludge suspension runs in 1993 and 1994, the slurry pumps` cleaning radius was determined to be less than that expected from previous determinations using synthetic sludge in a full size waste tank mockup. Hydrogen concentrations in the tanks` vapor space were monitored during the sludge suspension activities. As expected, the initial agitation of the sludge increased the hydrogen concentration, however, with the controls in place the hydrogen concentration was maintained below seven percent of the lower flammability limit

  4. CRC DEPLETION CALCULATIONS FOR THE RODDED ASSEMBLIES IN BATCHES 1, 2, 3, AND 1X OF CRYSTAL RIVER UNIT 3

    SciTech Connect (OSTI)

    Kenneth D. Wright

    1997-09-03

    The purpose of this design analysis is to document the SAS2H depletion calculations of certain rodded fuel assemblies from batches 1, 2, 3, and 1X of the Crystal River Unit 3 pressurized water reactor (PWR) that are required for Commercial Reactor Critical (CRC) evaluations to support the development of the disposal criticality methodology. A rodded assembly is one that contains a control rod assembly (CRA) or an axial power shaping rod assembly (APSRA) for some period of time during its irradiation history. The objective of this analysis is to provide SAS2H calculated isotopic compositions of depleted fuel and depleted burnable poison for each fuel assembly to be used in subsequent CRC reactivity calculations containing the fuel assemblies.

  5. CRC DEPLETION CALCULATIONS FOR THE NON-RODDED ASSEMBLIES IN BATCHES 1, 2, AND 3 OF CRYSTAL RIVER UNIT 3

    SciTech Connect (OSTI)

    Kenneth D. Wright

    1997-07-29

    The purpose of this design analysis is to document the SAS2H depletion calculations of certain non-rodded fuel assemblies from batches 1, 2, and 3 of the Crystal River Unit 3 pressurized water reactor (PWR) that are required for Commercial Reactor Critical (CRC) evaluations to support development of the disposal criticality methodology. A non-rodded assembly is one which never contains a control rod assembly (CRA) or an axial power shaping rod assembly (APSRA) during its irradiation history. The objective of this analysis is to provide SAS2H generated isotopic compositions for each fuel assembly's depleted fuel and depleted burnable poison materials. These SAS2H generated isotopic compositions are acceptable for use in CRC benchmark reactivity calculations containing the various fuel assemblies.

  6. CRC DEPLETION CALCULATIONS FOR THE NON-RODDED ASSEMBLIES IN BATCHES 4 AND 5 OF CRYSTAL RIVER UNIT 3

    SciTech Connect (OSTI)

    Kenneth D. Wright

    1997-07-30

    The purpose of this design analysis is to document the SAS2H depletion calculations of certain non-rodded fuel assemblies from batches 4 and 5 of the Crystal River Unit 3 pressurized water reactor (PWR) that are required for commercial Reactor Critical (CRC) evaluations to support the development of the disposal criticality methodology. A non-rodded assembly is one which never contains a control rod assembly (CRA) or an axial power shaping rod assembly (APSRA) during its irradiation history. The objective of this analysis is to provide SAS2H generated isotopic compositions for each fuel assembly's depleted fuel and depleted burnable poison materials. These SAS2H generated isotopic compositions are acceptable for use in CRC benchmark reactivity calculations containing the various fuel assemblies.

  7. CRC DEPLETION CALCULATIONS FOR THE NON-RODDED ASSEMBLIES IN BATCHES 8 AND 9 CRYSTAL RIVER UNIT 3

    SciTech Connect (OSTI)

    Michael L. Wilson

    2001-02-08

    The purpose of this design analysis is to document the SAS2H depletion calculations of certain non-rodded fuel assemblies from batches 8 and 9 of the Crystal River Unit 3 pressurized water reactor (PWR) that are required for Commercial Reactor Critical (CRC) evaluations to support the development of the disposal criticality methodology. A non-rodded assembly is one which never contains a control rod assembly (CRA) or an axial power shaping rod assembly (APSRA) during its irradiation history. The objective of this analysis is to provide SAS2H generated isotopic compositions for each fuel assembly's depleted fuel and depleted burnable poison materials. These SAS2H generated isotopic compositions are acceptable for use in CRC benchmark reactivity calculations containing the various fuel assemblies.

  8. Coal fly ash interaction with environmental fluids: Geochemical and strontium isotope results from combined column and batch leaching experiments

    SciTech Connect (OSTI)

    Brubaker, Tonya M.; Stewart, Brian W.; Capo, Rosemary C.; Schroeder, Karl T.; Chapman, Elizabeth C.; Spivak-Birndorf, Lev J.; Vesper, Dorothy J.; Cardone, Carol R.; Rohar, Paul C.

    2013-05-01

    The major element and Sr isotope systematics and geochemistry of coal fly ash and its interactions with environmental waters were investigated using laboratory flow-through column leaching experiments (sodium carbonate, acetic acid, nitric acid) and sequential batch leaching experiments (water, acetic acid, hydrochloric acid). Column leaching of Class F fly ash samples shows rapid release of most major elements early in the leaching procedure, suggesting an association of these elements with soluble and surface bound phases. Delayed release of certain elements (e.g., Al, Fe, Si) signals gradual dissolution of more resistant silicate or glass phases as leaching continues. Strontium isotope results from both column and batch leaching experiments show a marked increase in {sup 87}Sr/{sup 86}Sr ratio with continued leaching, yielding a total range of values from 0.7107 to 0.7138. For comparison, the isotopic composition of fluid output from a fly ash impoundment in West Virginia falls in a narrow range around 0.7124. The experimental data suggest the presence of a more resistant, highly radiogenic silicate phase that survives the combustion process and is leached after the more soluble minerals are removed. Strontium isotopic homogenization of minerals in coal does not always occur during the combustion process, despite the high temperatures encountered in the boiler. Early-released Sr tends to be isotopically uniform; thus the Sr isotopic composition of fly ash could be distinguishable from other sources and is a useful tool for quantifying the possible contribution of fly ash leaching to the total dissolved load in natural surface and ground waters.

  9. Plant-based Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plant-based Materials Catalysis Center for Energy Innovation teams with consumer goods and ... announced a research program with the Plant PET Technology Collaborative (PTC) to ...

  10. Design report: small-scale fuel alcohol plant

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    The objectives of the report are to (a) provide potential alcohol producers with a reference design and (b) provide a complete, demonstrated design of a small-scale fuel alcohol plant. This report describes a small-scale fuel alcohol plant designed and constructed for the DOE by EG and G Idaho, Inc., an operating contractor at the Idaho National Engineering Laboratory. The plant is reasonably complete, having the capability for feedstock preparation, cooking, saccharification, fermentation, distillation, by-product dewatering, and process steam generation. An interesting feature is an instrumentation and control system designed to allow the plant to run 24 hours per day with only four hours of operator attention. Where possible, this document follows the design requirements established in the DOE publication Fuel From Farms, which was published in February 1980. For instance, critical requirements such as using corn as the primary feedstock, production of 25 gallons of 190 proof ethanol per hour, and using batch fermentation were taken from Fuel From Farms. One significant deviation is alcohol dehydration. Fuel From Farms recommends the use of a molecular sieve for dehydration, but a preliminary design raised significant questions about the cost effectiveness of this approach. A cost trade-off study is currently under way to establish the best alcohol dehydration method and will be the subject of a later report. Volume one contains background information and a general description of the plant and process.

  11. Waste Isolation Pilot Plant

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Waste Isolation Pilot Plant AFFIDAVIT FOR SURVIVING RELATIVE STATE ) ) ss: COUNTY OF ) That I, , am the...

  12. Ethylene insensitive plants

    DOE Patents [OSTI]

    Ecker, Joseph R.; Nehring, Ramlah; McGrath, Robert B.

    2007-05-22

    Nucleic acid and polypeptide sequences are described which relate to an EIN6 gene, a gene involved in the plant ethylene response. Plant transformation vectors and transgenic plants are described which display an altered ethylene-dependent phenotype due to altered expression of EIN6 in transformed plants.

  13. Polyhydroxyalkanoate synthesis in plants

    DOE Patents [OSTI]

    Srienc, Friedrich; Somers, David A.; Hahn, J. J.; Eschenlauer, Arthur C.

    2000-01-01

    Novel transgenic plants and plant cells are capable of biosynthesis of polyhydroxyalkanoate (PHA). Heterologous enzymes involved in PHA biosynthesis, particularly PHA polymerase, are targeted to the peroxisome of a transgenic plant. Transgenic plant materials that biosynthesize short chain length monomer PHAs in the absence of heterologous .beta.-ketothiolase and acetoacetyl-CoA reductase are also disclosed.

  14. Plant fatty acid hydroxylases

    DOE Patents [OSTI]

    Somerville, Chris; Broun, Pierre; van de Loo, Frank

    2001-01-01

    This invention relates to plant fatty acyl hydroxylases. Methods to use conserved amino acid or nucleotide sequences to obtain plant fatty acyl hydroxylases are described. Also described is the use of cDNA clones encoding a plant hydroxylase to produce a family of hydroxylated fatty acids in transgenic plants. In addition, the use of genes encoding fatty acid hydroxylases or desaturases to alter the level of lipid fatty acid unsaturation in transgenic plants is described.

  15. Waste Treatment Plant Overview

    Office of Environmental Management (EM)

    Waste Isolation Pilot Plant Waste Isolation Pilot Plant Waste Isolation Pilot Plant | June 2007 Salt Disposal Investigations Waste Isolation Pilot Plant | June 2007 Salt Disposal Investigations The mission of the Waste Isolation Pilot Plant site is to provide permanent, underground disposal of TRU and TRU-mixed wastes (wastes that also have hazardous chemical components). TRU waste consists of clothing, tools, and debris left from the research and production of nuclear weapons. TRU waste is

  16. SLURRY MIX EVAPORATOR BATCH ACCEPTABILITY AND TEST CASES OF THE PRODUCT COMPOSITION CONTROL SYSTEM WITH THORIUM AS A REPORTABLE ELEMENT

    SciTech Connect (OSTI)

    Edwards, T.

    2010-10-07

    The Defense Waste Processing Facility (DWPF), which is operated by Savannah River Remediation, LLC (SRR), has recently begun processing Sludge Batch 6 (SB6) by combining it with Frit 418 at a nominal waste loading (WL) of 36%. A unique feature of the SB6/Frit 418 glass system, as compared to the previous glass systems processed in DWPF, is that thorium will be a reportable element (i.e., concentrations of elemental thorium in the final glass product greater than 0.5 weight percent (wt%)) for the resulting wasteform. Several activities were initiated based upon this unique aspect of SB6. One of these was an investigation into the impact of thorium on the models utilized in DWPF's Product Composition and Control System (PCCS). While the PCCS is described in more detail below, for now note that it is utilized by Waste Solidification Engineering (WSE) to evaluate the acceptability of each batch of material in the Slurry Mix Evaporator (SME) before this material is passed on to the melter. The evaluation employs models that predict properties associated with processability and product quality from the composition of vitrified samples of the SME material. The investigation of the impact of thorium on these models was conducted by Peeler and Edwards [1] and led to a recommendation that DWPF can process the SB6/Frit 418 glass system with ThO{sub 2} concentrations up to 1.8 wt% in glass. Questions also arose regarding the handling of thorium in the SME batch acceptability process as documented by Brown, Postles, and Edwards [2]. Specifically, that document is the technical bases of PCCS, and while Peeler and Edwards confirmed the reliability of the models, there is a need to confirm that the current implementation of DWPF's PCCS appropriately handles thorium as a reportable element. Realization of this need led to a Technical Task Request (TTR) prepared by Bricker [3] that identified some specific SME-related activities that the Savannah River National Laboratory (SRNL) was

  17. Sequence and batch language programs and alarm-related ``C`` programs for the 242-A MCS. Revision 2

    SciTech Connect (OSTI)

    Berger, J.F.

    1995-03-01

    A Distributive Process Control system was purchased by Project B-534, ``242-A Evaporator/Crystallizer Upgrades``. This control system, called the Monitor and Control System (MCS), was installed in the 242-A Evaporator located in the 200 East Area. The purpose of the MCS is to monitor and control the Evaporator and monitor a number of alarms and other signals from various Tank Farm facilities. Applications software for the MCS was developed by the Waste Treatment Systems Engineering (WTSE) group of Westinghouse. The standard displays and alarm scheme provide for control and monitoring, but do not directly indicate the signal location or depict the overall process. To do this, WTSE developed a second alarm scheme which uses special programs, annunciator keys, and process graphics. The special programs are written in two languages; Sequence and Batch Language (SABL), and ``C`` language. The WTSE-developed alarm scheme works as described below: SABL relates signals and alarms to the annunciator keys, called SKID keys. When an alarm occurs, a SABL program causes a SKID key to flash, and if the alarm is of yellow or white priority then a ``C`` program turns on an audible horn (the D/3 system uses a different audible horn for the red priority alarms). The horn and flashing key draws the attention of the operator.

  18. Fuel cell performance of palladium-platinum core-shell electrocatalysts synthesized in gram-scale batches

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khateeb, Siddique; Su, Dong; Guerreo, Sandra; Darling, Robert M.; Protsailo, Lesia V.; Shao, Minhua

    2016-05-03

    This article presents the performance of palladium-platinum core-shell catalysts (Pt/Pd/C) for oxygen reduction synthesized in gram-scale batches in both liquid cells and polymer-electrolyte membrane fuel cells. Core-shell catalyst synthesis and characterization, ink fabrication, and cell assembly details are discussed. The Pt mass activity of the Pt/Pd core-shell catalyst was 0.95 A mg–1 at 0.9 V measured in liquid cells (0.1 M HClO4), which was 4.8 times higher than a commercial Pt/C catalyst. The performances of Pt/Pd/C and Pt/C in large single cells (315 cm2) were assessed under various operating conditions. The core-shell catalyst showed consistently higher performance than commercial Pt/Cmore » in fuel cell testing. A 20–60 mV improvement across the whole current density range was observed on air. Sensitivities to temperature, humidity, and gas composition were also investigated and the core-shell catalyst showed a consistent benefit over Pt under all conditions. However, the 4.8 times activity enhancement predicated by liquid cell measurements was not fully realized in fuel cells.« less

  19. Plant Phenotype Characterization System

    SciTech Connect (OSTI)

    Daniel W McDonald; Ronald B Michaels

    2005-09-09

    This report is the final scientific report for the DOE Inventions and Innovations Project: Plant Phenotype Characterization System, DE-FG36-04GO14334. The period of performance was September 30, 2004 through July 15, 2005. The project objective is to demonstrate the viability of a new scientific instrument concept for the study of plant root systems. The root systems of plants are thought to be important in plant yield and thus important to DOE goals in renewable energy sources. The scientific study and understanding of plant root systems is hampered by the difficulty in observing root activity and the inadequacy of existing root study instrumentation options. We have demonstrated a high throughput, non-invasive, high resolution technique for visualizing plant root systems in-situ. Our approach is based upon low-energy x-ray radiography and the use of containers and substrates (artificial soil) which are virtually transparent to x-rays. The system allows us to germinate and grow plant specimens in our containers and substrates and to generate x-ray images of the developing root system over time. The same plant can be imaged at different times in its development. The system can be used for root studies in plant physiology, plant morphology, plant breeding, plant functional genomics and plant genotype screening.

  20. Plant centromere compositions

    DOE Patents [OSTI]

    Mach; Jennifer M. , Zieler; Helge , Jin; RongGuan , Keith; Kevin , Copenhaver; Gregory P. , Preuss; Daphne

    2011-11-22

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  1. Plant centromere compositions

    DOE Patents [OSTI]

    Mach, Jennifer; Zieler, Helge; Jin, James; Keith, Kevin; Copenhaver, Gregory; Preuss, Daphne

    2007-06-05

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  2. Plant centromere compositions

    DOE Patents [OSTI]

    Keith, Kevin; Copenhaver, Gregory; Preuss, Daphne

    2006-10-10

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  3. Plant centromere compositions

    DOE Patents [OSTI]

    Mach, Jennifer; Zieler, Helge; Jin, James; Keith, Kevin; Copenhaver, Gregory; Preuss, Daphne

    2006-06-26

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  4. Plant centromere compositions

    DOE Patents [OSTI]

    Mach, Jennifer M.; Zieler, Helge; Jin, RongGuan; Keith, Kevin; Copenhaver, Gregory P.; Preuss, Daphne

    2011-08-02

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  5. T Plant - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T Plant About Us About Hanford Cleanup Hanford History Hanford Site Wide Programs Contact ... and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage ...

  6. Plants & Animals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plants & Animals Plants & Animals Plant and animal monitoring is performed to determine whether Laboratory operations are impacting human health via the food chain. February 2, 2015 A rabbit on LANL land. A rabbit on Los Alamos National Laboratory land. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email We sample many plants and animals, including wild and domestic crops, game animals, fish, and food products from

  7. Plant-Scale Concentration Column Designs for SHINE Target Solution Utilizing AG 1 Anion Exchange Resin

    SciTech Connect (OSTI)

    Stepinski, Dominique C.; Vandegrift, G. F.

    2015-09-30

    Argonne is assisting SHINE Medical Technologies (SHINE) in their efforts to develop SHINE, an accelerator-driven process that will utilize a uranyl-sulfate solution for the production of fission product Mo-99. An integral part of the process is the development of a column for the separation and recovery of Mo-99, followed by a concentration column to reduce the product volume from 15-25 L to <1 L. Argonne has collected data from batch studies and breakthrough column experiments to utilize the VERSE (Versatile Reaction Separation) simulation program (Purdue University) to design plant-scale product recovery and concentration processes.

  8. Power Plant Cycling Costs

    SciTech Connect (OSTI)

    Kumar, N.; Besuner, P.; Lefton, S.; Agan, D.; Hilleman, D.

    2012-07-01

    This report provides a detailed review of the most up to date data available on power plant cycling costs. The primary objective of this report is to increase awareness of power plant cycling cost, the use of these costs in renewable integration studies and to stimulate debate between policymakers, system dispatchers, plant personnel and power utilities.

  9. Virginia Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal ... Electric & Power Co" "2 Plants 4 Reactors","3,501","26,572",100.0 "Note: ...

  10. SLUDGE BATCH 5 ACCEPTANCE EVALUATION RADIONUCLIDE CONCENTRATIONS IN TANK 51 SB5 QUALIFICATION SAMPLE PREPARED AT SRNL

    SciTech Connect (OSTI)

    Bannochie, C; Ned Bibler, N; David Diprete, D

    2008-07-28

    Presented in this report are radionuclide concentrations required as part of the program of qualifying Sludge Batch Five (SB5) for processing in the Defense Waste Processing Facility (DWPF). Part of this SB5 material is currently in Tank 51 being washed and prepared for transfer to Tank 40. The acceptance evaluation needs to be completed prior to the transfer of the material in Tank 51 to Tank 40 to complete the formation of SB5. The sludge slurry in Tank 40 has already been qualified for DWPF and is currently being processed as SB4. The radionuclide concentrations were measured or estimated in the Tank 51 SB5 Qualification Sample prepared at Savannah River National Laboratory (SRNL). This sample was prepared from the three liter sample of Tank 51 sludge slurry taken on March 21, 2008. The sample was delivered to SRNL where it was initially characterized in the Shielded Cells. Under direction of the Liquid Waste Organization it was then modified by five washes, six decants, an addition of Pu/Be from Canyon Tank 16.4, and an addition of NaNO2. This final slurry now has a composition expected to be similar to that of the slurry in Tank 51 after final preparations have been made for transfer of that slurry to Ta Determining the radionuclide concentrations in this Tank 51 SB5 Qualification Sample is part of the work requested in Technical Task Request (TTR) No. HLW-DWPF-TTR-2008-0010. The work with this qualification sample is covered by a Task Technical and Quality Assurance Plan and an Analytical Study Plan. The radionuclides included in this report are needed for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria (TSR/WAC) Evaluation, and the DWPF Solid Waste Characterization Program (TTR Task 2). Radionuclides required to meet the Waste Acceptance Product Specifications (TTR Task 5) will be measured at a later date after the slurry from Tank 51 has been transferred to Tank 40. Then a sample of the as-processed SB5 will be taken and

  11. SLUDGE BATCH 6 ACCEPTANCE EVALUATION: RADIONUCLIDE CONCENTRATIONS IN TANK 51 SB6 QUALIFICATION SAMPLE PREPARED AT SRNL

    SciTech Connect (OSTI)

    Bannochie, C.; Bibler, N.; Diprete, D.

    2010-05-21

    Presented in this report are radionuclide concentrations required as part of the program of qualifying Sludge Batch Six (SB6) for processing in the Defense Waste Processing Facility (DWPF). The SB6 material is currently in Tank 51 being washed and prepared for transfer to Tank 40. The acceptance evaluation needs to be completed prior to the transfer of the material in Tank 51 to Tank 40. The sludge slurry in Tank 40 has already been qualified for DWPF and is currently being processed as SB5. The radionuclide concentrations were measured or estimated in the Tank 51 SB6 Qualification Sample prepared at Savannah River National Laboratory (SRNL). This sample was prepared from the three liter sample of Tank 51 sludge slurry (HTF-51-09-110) taken on October 8, 2009. The sample was delivered to SRNL where it was initially characterized in the Shielded Cells. Under the direction of the Liquid Waste Organization it was then modified by eight washes, nine decants, an addition of Pu from Canyon Tank 16.3, and an addition of NaNO{sub 2}. This final slurry now has a composition expected to be similar to that of the slurry in Tank 51 after final preparations have been made for transfer of that slurry to Tank 40. Determining the radionuclide concentrations in this Tank 51 SB6 Qualification Sample is part of the work requested in Technical Task Request (TTR) No. HLW-DWPF-TTR-2009-0014. The work with this qualification sample is covered by a Task Technical and Quality Assurance Plan and an Analytical Study Plan. The radionuclides included in this report are needed for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria (TSR/WAC) Evaluation, and the DWPF Solid Waste Characterization Program (TTR Task I.2). Radionuclides required to meet the Waste Acceptance Product Specifications (TTR Task II.2.) will be measured at a later date after the slurry from Tank 51 has been transferred to Tank 40. Then a sample of the as-processed SB6 will be taken and transferred

  12. Low-Cost Batch Solar Water Heater Research and Development Project: results from extended field monitoring. Final report, January 1, 1983-May 15, 1983

    SciTech Connect (OSTI)

    Stickney, B.L.

    1984-02-01

    This report contains the results of a four month field test and evaluation of a 30 gallon inverted batch solar water heater known as the Bottomgainer. It was installed on a residence in Santa Fe and monitored with automatic data recorders including solar radiation meter, dual channel Btu meters, water meter and 16 channel strip chart temperature recorder. Average values of heat gain, heat loss, collection efficiency, solar heating fraction and cash benefits are presented and discussed.

  13. SLUDGE WASHING AND DEMONSTRATION OF THE DWPF FLOWSHEET IN THE SRNL SHIELDED CELLS FOR SLUDGE BATCH 5 QUALIFICATION

    SciTech Connect (OSTI)

    Pareizs, J; Cj Bannochie, C; Damon Click, D; Dan Lambert, D; Michael Stone, M; Bradley Pickenheim, B; Amanda Billings, A; Ned Bibler, N

    2008-11-10

    Sludge Batch 5 (SB5) is predominantly a combination of H-modified (HM) sludge from Tank 11 that underwent aluminum dissolution in late 2007 to reduce the total mass of sludge solids and aluminum being fed to the Defense Waste Processing Facility (DWPF) and Purex sludge transferred from Tank 7. Following aluminum dissolution, the addition of Tank 7 sludge and excess Pu to Tank 51, Liquid Waste Operations (LWO) provided the Savannah River National Laboratory (SRNL) a 3-L sample of Tank 51 sludge for SB5 qualification. SB5 qualification included washing the sample per LWO plans/projections (including the addition of a Pu/Be stream from H Canyon), DWPF Chemical Process Cell (CPC) simulations, waste glass fabrication (vitrification), and waste glass chemical durability evaluation. This report documents: (1) The washing (addition of water to dilute the sludge supernatant) and concentration (decanting of supernatant) of the Tank 51 qualification sample to adjust sodium content and weight percent insoluble solids to Tank Farm projections. (2) The performance of a DWPF CPC simulation using the washed Tank 51 sample. This includes a Sludge Receipt and Adjustment Tank (SRAT) cycle, where acid is added to the sludge to destroy nitrite and remove mercury, and a Slurry Mix Evaporator (SME) cycle, where glass frit is added to the sludge in preparation for vitrification. The SME cycle also included replication of five canister decontamination additions and concentrations. Processing parameters for the CPC processing were based on work with a non radioactive simulant. (3) Vitrification of a portion of the SME product and Product Consistency Test (PCT) evaluation of the resulting glass. (4) Rheology measurements of the initial slurry samples and samples after each phase of CPC processing. This work is controlled by a Task Technical and Quality Assurance Plan (TTQAP) , and analyses are guided by an Analytical Study Plan. This work is Technical Baseline Research and Development (R

  14. Analyses by the Defense Waste Processing Facility Laboratory of Thorium Glasses from the Sludge Batch 6 Variability Study

    SciTech Connect (OSTI)

    Edwards, T.; Click, D.; Feller, M.

    2011-02-28

    The Savannah River Remediation (SRR) Defense Waste Processing Facility (DWPF) is currently processing Sludge Batch 6 (SB6) with Frit 418. At times during the processing of this glass system, thorium is expected to be at concentrations in the final wasteform that make it a reportable element for the first time since startup of radioactive operations at the DWPF. The Savannah River National Laboratory (SRNL) supported the qualification of the processing of this glass system at the DWPF. A recommendation from the SRNL studies was the need for the DWPF Laboratory to establish a method to measure thorium by Inductively Coupled Plasma - Atomic Emission Spectroscopy (ICPAES). This recommendation led to the set of thorium-bearing glasses from the SB6 Variability Study (VS) being submitted to the DWPF Laboratory for chemical composition measurement. The measurements were conducted by the DWPF Laboratory using the sodium peroxide fusion preparation method routinely employed for analysis of samples from the Slurry Mix Evaporator (SME). These measurements are presented and reviewed in this report. The review indicates that the measurements provided by the DWPF Laboratory are comparable to those provided by Analytical Development's laboratory at SRNL for these same glasses. As a result, the authors of this report recommend that the DWPF Laboratory begin using its routine peroxide fusion dissolution method for the measurement of thorium in SME samples of SB6. The purpose of this technical report is to present the measurements generated by the DWPF Laboratory for the SB6 VS glasses and to compare the measurements to the targeted compositions for these VS glasses as well as to SRNL's measurements (both sets, targeted and measured, of compositional values were reported by SRNL in [2]). The goal of these comparisons is to provide information that will lead to the qualification of peroxide fusion dissolution as a method for the measurement by the DWPF Laboratory of thorium in SME

  15. Example Batch Scripts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Job Steps and Dependencies There is a qsub option -W dependdependencylist or a Torque Keyword PBS -W dependdependencylist for job dependencies. The most commonly used ...

  16. Batch Strategies for Maximizing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    u s t he b atch s ystem t o run

  17. Batch Strategies for Maximizing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    t o u se t he b atch s ystem to r un

  18. Example Batch Scripts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Examining Future Global Transportation Energy Demand For EIA Energy Conference July 11, 2016 | Washington, DC By John Maples Outline * Model overview - Passenger travel - Freight travel - Energy consumption for 16 regions: * USA, Canada, Mexico/Chile, OECD Europe, Japan, S. Korea, Australia/New Zealand * Russia, Non-OECD Europe/Eurasia, China, India, Non-OECD Asia, Middle East, Africa, Brazil, Other South/Central * IEO2016 Reference case transportation projections * Preliminary scenario results

  19. Submitting Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... PBSOHOST Hostname of system on which qsub was executed. This is typically a Carver login node. PBSJOBID Unique identifier for this job; important for tracking job status. ...

  20. Running Interactive Batch Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    You will be prompted to enter a passphrase. This is a text string, similar to a password, that you will use for passphrase authentication. Do not make it the same as your password. ...

  1. Towards the Integration of Dark- and Photo-Fermentative Waste Treatment. 4. Repeated Batch Sequential Dark- and Photofermentation using Starch as Substrate

    SciTech Connect (OSTI)

    Laurinavichene, T. V.; Belokopytov, B. F.; Laurinavichius, K. S.; Khusnutdinova, A. N.; Seibert, M.; Tsygankov, A. A.

    2012-05-01

    In this study we demonstrated the technical feasibility of a prolonged, sequential two-stage integrated process under a repeated batch mode of starch fermentation. In this durable scheme, the photobioreactor with purple bacteria in the second stage was fed directly with dark culture from the first stage without centrifugation, filtration, or sterilization (not demonstrated previously). After preliminary optimization, both the dark- and the photo-stages were performed under repeated batch modes with different process parameters. Continuous H{sub 2} production in this system was observed at a H{sub 2} yield of up to 1.4 and 3.9 mole mole{sup -1} hexose during the dark- and photo-stage, respectively (for a total of 5.3 mole mole{sup -1} hexose), and rates of 0.9 and 0.5 L L{sup -1} d{sup -1}, respectively. Prolonged repeated batch H{sub 2} production was maintained for up to 90 days in each stage and was rather stable under non-aseptic conditions. Potential for improvements in these results are discussed.

  2. Integration of the Uncertainties of Anion and TOC Measurements into the Flammability Control Strategy for Sludge Batch 8 at the DWPF

    SciTech Connect (OSTI)

    Edwards, T. B.

    2013-03-14

    The Savannah River National Laboratory (SRNL) has been working with the Savannah River Remediation (SRR) Defense Waste Processing Facility (DWPF) in the development and implementation of a flammability control strategy for DWPFs melter operation during the processing of Sludge Batch 8 (SB8). SRNLs support has been in response to technical task requests that have been made by SRRs Waste Solidification Engineering (WSE) organization. The flammability control strategy relies on measurements that are performed on Slurry Mix Evaporator (SME) samples by the DWPF Laboratory. Measurements of nitrate, oxalate, formate, and total organic carbon (TOC) standards generated by the DWPF Laboratory are presented in this report, and an evaluation of the uncertainties of these measurements is provided. The impact of the uncertainties of these measurements on DWPFs strategy for controlling melter flammability also is evaluated. The strategy includes monitoring each SME batch for its nitrate content and its TOC content relative to the nitrate content and relative to the antifoam additions made during the preparation of the SME batch. A linearized approach for monitoring the relationship between TOC and nitrate is developed, equations are provided that integrate the measurement uncertainties into the flammability control strategy, and sample calculations for these equations are shown to illustrate the impact of the uncertainties on the flammability control strategy.

  3. Early-warning process/control for anaerobic digestion and biological nitrogen transformation processes: Batch, semi-continuous, and/or chemostat experiments. Final report

    SciTech Connect (OSTI)

    Hickey, R.

    1992-09-01

    The objective of this project was to develop and test an early-warning/process control model for anaerobic sludge digestion (AD). The approach was to use batch and semi-continuously fed systems and to assemble system parameter data on a real-time basis. Specific goals were to produce a real-time early warning control model and computer code, tested for internal and external validity; to determine the minimum rate of data collection for maximum lag time to predict failure with a prescribed accuracy and confidence in the prediction; and to determine and characterize any trends in the real-time data collected in response to particular perturbations to feedstock quality. Trends in the response of trace gases carbon monoxide and hydrogen in batch experiments, were found to depend on toxicant type. For example, these trace gases respond differently for organic substances vs. heavy metals. In both batch and semi-continuously feed experiments, increased organic loading lead to proportionate increases in gas production rates as well as increases in CO and H{sub 2} concentration. An analysis of variance of gas parameters confirmed that CO was the most sensitive indicator variable by virtue of its relatively larger variance compared to the others. The other parameters evaluated including gas production, methane production, hydrogen, carbon monoxide, carbon dioxide and methane concentration. In addition, a relationship was hypothesized between gaseous CO concentration and acetate concentrations in the digester. The data from semicontinuous feed experiments were supportive.

  4. Better Plants Pre-In-Plant Training Webinars

    Office of Energy Efficiency and Renewable Energy (EERE)

    A listing of Better Plants pre-In-Plant Training webinars on reducing energy in a variety of systems.

  5. NEMS Modeling of Coal Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquid Fuels Market Module Model inputs for coal plants 3 * Existing coal plants - plant specific ... FF - Cost to convert to natural gas-fired steam plant - Cost to implement heat ...

  6. Conditional sterility in plants

    DOE Patents [OSTI]

    Meagher, Richard B.; McKinney, Elizabeth; Kim, Tehryung

    2010-02-23

    The present disclosure provides methods, recombinant DNA molecules, recombinant host cells containing the DNA molecules, and transgenic plant cells, plant tissue and plants which contain and express at least one antisense or interference RNA specific for a thiamine biosynthetic coding sequence or a thiamine binding protein or a thiamine-degrading protein, wherein the RNA or thiamine binding protein is expressed under the regulatory control of a transcription regulatory sequence which directs expression in male and/or female reproductive tissue. These transgenic plants are conditionally sterile; i.e., they are fertile only in the presence of exogenous thiamine. Such plants are especially appropriate for use in the seed industry or in the environment, for example, for use in revegetation of contaminated soils or phytoremediation, especially when those transgenic plants also contain and express one or more chimeric genes which confer resistance to contaminants.

  7. SLUDGE BATCH 7 ACCEPTANCE EVALUATION: RADIONUCLIDE CONCENTRATIONS IN TANK 51 SB7 QUALIFICATION SAMPLE PREPARED AT SRNL

    SciTech Connect (OSTI)

    Pareizs, J.; Hay, M.

    2011-02-22

    Presented in this report are radionuclide concentrations required as part of the program of qualifying Sludge Batch Seven (SB7) for processing in the Defense Waste Processing Facility (DWPF). The SB7 material is currently in Tank 51 being washed and prepared for transfer to Tank 40. The acceptance evaluation needs to be completed prior to the transfer of the material in Tank 51 to Tank 40. The sludge slurry in Tank 40 has already been qualified for DWPF and is currently being processed as SB6. The radionuclide concentrations were measured or estimated in the Tank 51 SB7 Qualification Sample prepared at Savannah River National Laboratory (SRNL). This sample was prepared from the three liter qualification sample of Tank 51 sludge slurry (HTF-51-10-125) received on September 18, 2010. The sample was delivered to SRNL where it was initially characterized in the Shielded Cells. With consultation from the Liquid Waste Organization, the qualification sample was then modified by several washes and decants, which included addition of Pu from H Canyon and sodium nitrite per the Tank Farm corrosion control program. This final slurry now has a composition expected to be similar to that of the slurry in Tank 51 after final preparations have been made for transfer of that slurry to Tank 40. Determining the radionuclide concentrations in this Tank 51 SB7 Qualification Sample is part of the work requested in Technical Task Request (TTR) No. HLW-DWPF-TTR-2010-0031. The radionuclides included in this report are needed for the DWPF Radiological Program Evaluation, the DWPF Waste Acceptance Criteria (TSR/WAC) Evaluation, and the DWPF Solid Waste Characterization Program (TTR Task I.2). Radionuclides required to meet the Waste Acceptance Product Specifications (TTR Task III.2.) will be measured at a later date after the slurry from Tank 51 has been transferred to Tank 40. Then a sample of the as-processed SB7 will be taken and transferred to SRNL for measurement of these radionuclides

  8. SLUDGE BATCH 7 (SB7) WASHING DEMONSTRATION TO DETERMINE SULFATE/OXALATE REMOVAL EFFICIENCY AND SETTLING BEHAVIOR

    SciTech Connect (OSTI)

    Reboul, S.; Click, D.; Lambert, D.

    2010-12-10

    To support Sludge Batch 7 (SB7) washing, a demonstration of the proposed Tank Farm washing operation was performed utilizing a real-waste test slurry generated from Tank 4, 7, and 12 samples. The purpose of the demonstration was twofold: (1) to determine the settling time requirements and washing strategy needed to bring the SB7 slurry to the desired endpoint; and (2) to determine the impact of washing on the chemical and physical characteristics of the sludge, particularly those of sulfur content, oxalate content, and rheology. Seven wash cycles were conducted over a four month period to reduce the supernatant sodium concentration to approximately one molar. The long washing duration was due to the slow settling of the sludge and the limited compaction. Approximately 90% of the sulfur was removed through washing, and the vast majority of the sulfur was determined to be soluble from the start. In contrast, only about half of the oxalate was removed through washing, as most of the oxalate was initially insoluble and did not partition to the liquid phase until the latter washes. The final sulfur concentration was 0.45 wt% of the total solids, and the final oxalate concentration was 9,900 mg/kg slurry. More oxalate could have been removed through additional washing, although the washing would have reduced the supernatant sodium concentration.The yield stress of the final washed sludge (35 Pa) was an order of magnitude higher than that of the unwashed sludge ({approx}4 Pa) and was deemed potentially problematic. The high yield stress was related to the significant increase in insoluble solids that occurred ({approx}8 wt% to {approx}18 wt%) as soluble solids and water were removed from the slurry. Reduction of the insoluble solids concentration to {approx}14 wt% was needed to reduce the yield stress to an acceptable level. However, depending on the manner that the insoluble solids adjustment was performed, the final sodium concentration and extent of oxalate removal

  9. Better Buildings, Better Plants:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings, Better Plants: AMO Technical Assistance Overview Andre de Fontaine This presentation does not contain any proprietary, confidential, or otherwise restricted information. 2 | Advanced Manufacturing Office Better Buildings, Better Plants Overview  Better Buildings, Better Plants is a national, voluntary industrial energy efficiency leadership initiative.  It is a key component of the President's Better Buildings Initiative, which seeks to improve the energy efficiency of

  10. SC Johnson Waxdale Plant

    SciTech Connect (OSTI)

    2010-01-01

    This is a combined heat and power (CHP) project profile on a 6.4 MW CHP application at SC Johnson Waxdale Plant in Racine, Wisconsin.

  11. Leatherwood prep plant upgrade

    SciTech Connect (OSTI)

    Hollis, R.W.; Jain, S.M.

    2007-06-15

    The Blue Diamond Coal Co. recently implemented major circuit modifications to the Leatherwood coal preparation plant (formerly known as the J.K. Cornett prep plant) in Slemp, KY, USA. The plant was originally built in the late 1980s, and then modified in 1999. The 2006 plant modifications included: two Krebs 33-inch heavy-media cyclones; five 10 x 20 ft single deck Conn-Weld Banana type vibrating screens; two 10 ft x 48 inch Eriez self-leveling magnetic separators; two Derrick Stacksizer high frequency screens; two CMI EBR-48 centrifugal dryers; Warman process pumps; and eight triple start MDL spiral concentrators. 2 figs.

  12. concentrating solar power plant

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    power plant - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy ...

  13. NUCLEAR POWER PLANT

    DOE Patents [OSTI]

    Carter, J.C.; Armstrong, R.H.; Janicke, M.J.

    1963-05-14

    A nuclear power plant for use in an airless environment or other environment in which cooling is difficult is described. The power plant includes a boiling mercury reactor, a mercury--vapor turbine in direct cycle therewith, and a radiator for condensing mercury vapor. (AEC)

  14. Better Plants Program Overview

    SciTech Connect (OSTI)

    2015-09-30

    The U.S. Department of Energy’s (DOE’s) Better Buildings, Better Plants Program is a voluntary partnership initiative to drive significant energy efficiency improvement across energy intensive companies and organizations. 157 leading manufacturers and public water and wastewater treatment utilities are partnering with DOE through Better Plants to improve energy efficiency, slash carbon emissions, and cut energy costs.

  15. Modulating lignin in plants

    DOE Patents [OSTI]

    Apuya, Nestor; Bobzin, Steven Craig; Okamuro, Jack; Zhang, Ke

    2013-01-29

    Materials and methods for modulating (e.g., increasing or decreasing) lignin content in plants are disclosed. For example, nucleic acids encoding lignin-modulating polypeptides are disclosed as well as methods for using such nucleic acids to generate transgenic plants having a modulated lignin content.

  16. Plant pathogen resistance

    SciTech Connect (OSTI)

    Greenberg, Jean T.; Jung, Ho Won; Tschaplinski, Timothy

    2015-10-20

    Azelaic acid or its derivatives or analogs induce a robust and a speedier defense response against pathogens in plants. Azelaic acid treatment alone does not induce many of the known defense-related genes but activates a plant's defense signaling upon pathogen exposure.

  17. Plant growth promoting rhizobacterium

    SciTech Connect (OSTI)

    Doktycz, Mitchel John; Pelletier, Dale A.; Schadt, Christopher Warren; Tuskan, Gerald A.; Weston, David

    2015-08-11

    The present invention is directed to the Pseudomonas fluorescens strain GM30 deposited under ATCC Accession No. PTA-13340, compositions containing the GM30 strain, and methods of using the GM30 strain to enhance plant growth and/or enhance plant resistance to pathogens.

  18. Plant pathogen resistance

    DOE Patents [OSTI]

    Greenberg, Jean T; Jung, Ho Won; Tschaplinski, Timothy

    2012-11-27

    Azelaic acid or its derivatives or analogs induce a robust and a speedier defense response against pathogens in plants. Azelaic acid treatment alone does not induce many of the known defense-related genes but activates a plant's defense signaling upon pathogen exposure.

  19. Plant fatty acid hydroxylase

    DOE Patents [OSTI]

    Somerville, Chris; van de Loo, Frank

    2000-01-01

    The present invention relates to the identification of nucleic acid sequences and constructs, and methods related thereto, and the use of these sequences and constructs to produce genetically modified plants for the purpose of altering the composition of plant oils, waxes and related compounds.

  20. Better Plants Program Partners

    Broader source: Energy.gov [DOE]

    DOE recognizes the following companies for their commitment to reducing the energy intensity of their U.S. manufacturing operations by 25% or more within 10 years. These Better Plants Program Partners set ambitious goals, establish energy management plans, and report progress annually to DOE. Click on the arrows below to view Better Plants Program Partner profiles and learn more about their commitment.

  1. Short contact time direct coal liquefaction using a novel batch reactor. Quarterly technical progress report, September 15, 1995--January 15, 1996

    SciTech Connect (OSTI)

    Klein, M.T.; Calkins, W.H.; Huang, He

    1996-01-26

    The objective of this research is to optimize the design and operation of the bench scale batch reactor (SCTBR) f or coal liquefaction at short contact times (0.01 to 10 minutes or longer). Additional objectives are to study the kinetics of direct coal liquefaction particularly at short reaction times, and to investigate the role of the organic oxygen components of coal and their reaction pathways during liquefaction. Many of those objectives have already been achieved and others are still in progress. This quarterly report covers further progress toward those objectives.

  2. Proof of concept and performance optimization of high gravity batch-type centrifugal dryer for dewatering fine coal

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.

    1991-01-01

    The primary objective of the project was to assemble, analyze and make use of those data that could help to clearly identify, optimize and confirm the technical and economic advantages that the new high gravity centrifugal dryer technology can provide to the coal industry and to end users. Other objectives were: to confirm the feasibility of the dryer for drying coals from a number of different seams; to use the data base for optimizing the dryer's systems, and: to produce projected technical and economic comparisons with thermal dryers as applied to an existing coal processing plant flow sheet. (JL)

  3. FRIB Cryogenic Plant Status

    SciTech Connect (OSTI)

    Dixon, Kelly D.; Ganni, Venkatarao; Knudsen, Peter N.; Casagranda, Fabio

    2015-12-01

    After practical changes were approved to the initial conceptual design of the cryogenic system for MSU FRIB and an agreement was made with JLab in 2012 to lead the design effort of the cryogenic plant, many activities are in place leading toward a cool-down of the linacs prior to 2018. This is mostly due to using similar equipment used at CHLII for the 12 GeV upgrade at JLab and an aggressive schedule maintained by the MSU Conventional Facilities department. Reported here is an updated status of the cryogenic plant, including the equipment procurement status, plant layout, facility equipment and project schedule.

  4. Wisconsin Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Wisconsin nuclear power plants, summer capacity and net generation, 2010" "Plant name..."8,291",62.4,"NextEra Energy Point Beach LLC" "2 Plants 3 Reactors","1,584","13,281",100.0

  5. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Photosynthesis: Plants Making...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Photosynthesis: Plants Making Fuel BIOENERGIZEME INFOGRAPHIC CHALLENGE: Photosynthesis: Plants Making Fuel BIOENERGIZEME INFOGRAPHIC CHALLENGE: Photosynthesis: Plants Making Fuel

  6. Plant Vascular Biology 2010

    SciTech Connect (OSTI)

    Ding, Biao

    2014-11-17

    This grant supported the Second International Conference on Plant Vascular Biology (PVB 2010) held July 24-28, 2010 on the campus of Ohio State University, Columbus, Ohio. Biao Ding (Ohio State University; OSU) and David Hannapel (Iowa State University; ISU) served as co-chairs of this conference. Biao Ding served as the local organizer. PVB is defined broadly here to include studies on the biogenesis, structure and function of transport systems in plants, under conditions of normal plant growth and development as well as of plant interactions with pathogens. The transport systems cover broadly the xylem, phloem, plasmodesmata and vascular cell membranes. The PVB concept has emerged in recent years to emphasize the integrative nature of the transport systems and approaches to investigate them.

  7. Desalination Plant Optimization

    Energy Science and Technology Software Center (OSTI)

    1992-10-01

    MSF21 and VTE21 perform design and costing calculations for multistage flash evaporator (MSF) and multieffect vertical tube evaporator (VTE) desalination plants. An optimization capability is available, if desired. The MSF plant consists of a recovery section, reject section, brine heater, and associated buildings and equipment. Operating costs and direct and indirect capital costs for plant, buildings, site, and intakes are calculated. Computations are based on the first and last stages of each section and amore » typical middle recovery stage. As a result, the program runs rapidly but does not give stage by stage parameters. The VTE plant consists of vertical tube effects, multistage flash preheater, condenser, and brine heater and associated buildings and equipment. Design computations are done for each vertical tube effect, but preheater computations are based on the first and last stages and a typical middle stage.« less

  8. B Plant facility description

    SciTech Connect (OSTI)

    Chalk, S.E.

    1996-10-04

    Buildings 225B, 272B, 282B, 282BA, and 294B were removed from the B Plant facility description. Minor corrections were made for tank sizes and hazardous and toxic inventories.

  9. Power Plant Cycling Costs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Intertek APTECH has organized the cycling cost data in consultation with NREL and WECC by the following eight generator plant types: 1. Small coal-fired sub-critical steam (35-299 ...

  10. Plant Phenotype Characterization System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plant Phenotype Characterization System Plant Phenotype Characterization System New X-Ray Technology Accelerates Plant Research The ability to analyze plant root structure and...

  11. Better Plants Overview SGH | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Plants Overview SGH 151007.pdf (315.86 KB) More Documents & Publications Better Plants Two-Page Overview Better Plants Progress Update Fall 2013 Better Plants Progress ...

  12. Special Better Plants Training Opportunities | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Assistance Better Plants Special Better Plants Training Opportunities Special Better Plants Training Opportunities Better Plants process heating training at an ...

  13. Washington Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Washington nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State ...

  14. Vermont Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net ...

  15. Quiz: Know Your Power Plants

    Office of Energy Efficiency and Renewable Energy (EERE)

    Think you know where coal, solar and other power plants are located around the country? Test your knowledge with our power plants quiz!

  16. Connecticut Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net ...

  17. Maryland Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net generation (percent)","Owner" "Calvert Cliffs Nuclear Power Plant ...

  18. Georgia Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net ...

  19. California Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    California nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State ...

  20. Pennsylvania Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Pennsylvania nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State ...

  1. Ohio Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Ohio nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net ...

  2. Virginia Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net ...

  3. Minnesota Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Minnesota nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear ...

  4. Alabama Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net ...

  5. Wisconsin Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Wisconsin nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear ...

  6. Texas Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net ...

  7. Tennessee Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Tennessee nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear ...

  8. Illinois Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Illinois nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear ...

  9. Michigan Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net ...

  10. Nebraska Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Nebraska nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear ...

  11. Florida Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Florida nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear ...

  12. Gasification Plant Databases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plant Databases Welcome to the U. S. Department of Energy, National Energy Technology Laboratory's Gasification Plant Databases Within these databases you will find current publicly available information on proposed projects and projects undergoing construction and initial operation within the United States and worldwide. Currently operating projects are excluded. The data have been compiled here to keep the public informed of the technologies and investments in major industrial coal

  13. Coal Preparation Plant Simulation

    Energy Science and Technology Software Center (OSTI)

    1992-02-25

    COALPREP assesses the degree of cleaning obtained with different coal feeds for a given plant configuration and mode of operation. It allows the user to simulate coal preparation plants to determine an optimum plant configuration for a given degree of cleaning. The user can compare the performance of alternative plant configurations as well as determine the impact of various modes of operation for a proposed configuration. The devices that can be modelled include froth flotationmore » devices, washers, dewatering equipment, thermal dryers, rotary breakers, roll crushers, classifiers, screens, blenders and splitters, and gravity thickeners. The user must specify the plant configuration and operating conditions and a description of the coal feed. COALPREP then determines the flowrates within the plant and a description of each flow stream (i.e. the weight distribution, percent ash, pyritic sulfur and total sulfur, moisture, BTU content, recoveries, and specific gravity of separation). COALPREP also includes a capability for calculating the cleaning cost per ton of coal. The IBM PC version contains two auxiliary programs, DATAPREP and FORLIST. DATAPREP is an interactive preprocessor for creating and editing COALPREP input data. FORLIST converts carriage-control characters in FORTRAN output data to ASCII line-feed (X''0A'') characters.« less

  14. Coal Preparation Plant Simulation

    Energy Science and Technology Software Center (OSTI)

    1992-02-25

    COALPREP assesses the degree of cleaning obtained with different coal feeds for a given plant configuration and mode of operation. It allows the user to simulate coal preparation plants to determine an optimum plant configuration for a given degree of cleaning. The user can compare the performance of alternative plant configurations as well as determine the impact of various modes of operation for a proposed configuration. The devices that can be modelled include froth flotationmore » devices, washers, dewatering equipment, thermal dryers, rotary breakers, roll crushers, classifiers, screens, blenders and splitters, and gravity thickeners. The user must specify the plant configuration and operating conditions and a description of the coal feed. COALPREP then determines the flowrates within the plant and a description of each flow stream (i.e. the weight distribution, percent ash, pyritic sulfur and total sulfur, moisture, BTU content, recoveries, and specific gravity of separation). COALPREP also includes a capability for calculating the cleaning cost per ton of coal.« less

  15. GEOTHERMAL POWER GENERATION PLANT

    SciTech Connect (OSTI)

    Boyd, Tonya

    2013-12-01

    Oregon Institute of Technology (OIT) drilled a deep geothermal well on campus (to 5,300 feet deep) which produced 196oF resource as part of the 2008 OIT Congressionally Directed Project. OIT will construct a geothermal power plant (estimated at 1.75 MWe gross output). The plant would provide 50 to 75 percent of the electricity demand on campus. Technical support for construction and operations will be provided by OIT’s Geo-Heat Center. The power plant will be housed adjacent to the existing heat exchange building on the south east corner of campus near the existing geothermal production wells used for heating campus. Cooling water will be supplied from the nearby cold water wells to a cooling tower or air cooling may be used, depending upon the type of plant selected. Using the flow obtained from the deep well, not only can energy be generated from the power plant, but the “waste” water will also be used to supplement space heating on campus. A pipeline will be construction from the well to the heat exchanger building, and then a discharge line will be construction around the east and north side of campus for anticipated use of the “waste” water by facilities in an adjacent sustainable energy park. An injection well will need to be drilled to handle the flow, as the campus existing injection wells are limited in capacity.

  16. Owners of nuclear power plants

    SciTech Connect (OSTI)

    Wood, R.S.

    1991-07-01

    This report indicates percentage ownership of commercial nuclear power plants by utility companies. The report includes all plants operating, under construction, docketed for NRC safety and environmental reviews, or under NRC antitrust review, but does not include those plants announced but not yet under review or those plants formally cancelled. Part 1 of the report lists plants alphabetically with their associated applicants or licensees and percentage ownership. Part 2 lists applicants or licensees alphabetically with their associated plants and percentage ownership. Part 1 also indicates which plants have received operating licenses (OLS).

  17. Geothermal Plant Capacity Factors

    SciTech Connect (OSTI)

    Greg Mines; Jay Nathwani; Christopher Richard; Hillary Hanson; Rachel Wood

    2015-01-01

    The capacity factors recently provided by the Energy Information Administration (EIA) indicated this plant performance metric had declined for geothermal power plants since 2008. Though capacity factor is a term commonly used by geothermal stakeholders to express the ability of a plant to produce power, it is a term frequently misunderstood and in some instances incorrectly used. In this paper we discuss how this capacity factor is defined and utilized by the EIA, including discussion on the information that the EIA requests from operations in their 923 and 860 forms that are submitted both monthly and annually by geothermal operators. A discussion is also provided regarding the entities utilizing the information in the EIA reports, and how those entities can misinterpret the data being supplied by the operators. The intent of the paper is to inform the facility operators as the importance of the accuracy of the data that they provide, and the implications of not providing the correct information.

  18. Willow plant name 'Preble'

    DOE Patents [OSTI]

    Abrahamson, Lawrence P.; Kopp, Richard F.; Smart, Lawrence B.; Volk, Timothy A.

    2014-06-10

    A distinct female cultivar of Salix viminalis.times.(Salix sachalinensis.times.Salix miyabeana) named `Preble`, characterized by rapid stem growth producing 29% more woody biomass than the average of three current production cultivars (Salix.times.dasyclados `SV1` (unpatented), Salix sachalinensis `SX61` (unpatented), and Salix miyabeana `SX64` (unpatented)) when grown in the same field for the same length of time (three growing seasons after coppice) in two different trials in Constableville, N.Y. and Middlebury, Vt. `Preble` can be planted from dormant stem cuttings, produces multiple stems after coppice and the stem biomass can be harvested when the plant is dormant. In the spring following harvest, the plant will re-sprout very vigorously, producing new stems that can be harvested repeatedly after two to four years of growth. `Preble` displays a low incidence of rust disease and is not damaged by potato leafhoppers.

  19. Owners of nuclear power plants

    SciTech Connect (OSTI)

    Not Available

    1982-11-01

    The list indicates percentage ownership of commercial nuclear power plants by utility companies as of September 1, 1982. The list includes all plants licensed to operate, under construction, docketed for NRC safety and environmental reviews, or under NRC antitrust review. Part I lists plants alphabetically with their associated applicants and percentage ownership. Part II lists applicants alphabetically with their associated plants and percentage ownership. Part I also indicates which plants have received operating licenses.

  20. Pantex Plant | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pantex Plant Pantex Plant Pantex Plant | September 2010 Aerial View Pantex Plant | September 2010 Aerial View The primary mission of the Pantex Plant is the assembly, disassembly, testing, and evaluation of nuclear weapons in support of the NNSA stockpile stewardship program. Pantex also performs research and development in conventional high explosives and serves as an interim storage site for plutonium pits removed from dismantled weapons. Enforcement April 8, 2015 Enforcement Letter, Packaging

  1. Fuel ethanol and high protein feed from corn and corn-whey mixtures in a farm-scale plant

    SciTech Connect (OSTI)

    Gibbons, W.R.; Westby, C.A.

    1983-09-01

    Distiller's wet grain (DWG) and 95% ethanol were produced from corn in a farm-scale process involving batch cooking-fermentation and continuous distillation-centrifugation. The energy balance was 2.26 and the cost was $1.86/gal (1981 cost). To improve the energy balance and reduce costs, various modifications were made in the plant. The first change, back-end (after liquefaction) serial recycling of stillage supernatant at 20 and 40% strengths, produced beers with 0.2 and 0.4% (v/v) more ethanol, respectively, than without recycling. This increased the energy balance by 0.22-0.43 units and reduced costs by $0.07-$0.10/gal. The DWGs from back-end recycling had increased fat. The second change, increasing the starch content from 17-19% to 27.5%, increased the ethanol in the beer from 10.5-14.9% at a cost savings of $0.41/gal. The energy balance increased by 1.08 units. No significant change was seen in DWG composition. The third change, using continuous cascade rather than batch fermentation, permitted batch-levels of ethanol (10%) in the beer but only at low dilution rates. Both the cost and energy balance were decreased slightly. The DWG composition remained constant. The last change, replacing part of the corn and all of the tap water in the mash with whole whey and using Kluyveromyces fragilis instead of Saccharomyces cerevisiae during fermentation, resulted in an energy balance increase of 0.16 units and a $0.27/gal cost reduction. Here, 10% ethanolic beers were produced and the DWGs showed increased protein and fat. Recommendations for farm-scale plants are provided. (Refs. 46).

  2. Monitoring Uranium Transformations Determined by the Evolution of Biogeochemical Processes: Design of Mixed Batch Reactor and Column Studies at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Criddle, Craig S.; Wu, Weimin

    2013-04-17

    With funds provided by the US DOE, Argonne National Laboratory subcontracted the design of batch and column studies to a Stanford University team with field experience at the ORNL IFRC, Oak Ridge, TN. The contribution of the Stanford group ended in 2011 due to budget reduction in ANL. Over the funded research period, the Stanford research team characterized ORNL IFRC groundwater and sediments and set up microcosm reactors and columns at ANL to ensure that experiments were relevant to field conditions at Oak Ridge. The results of microcosm testing demonstrated that U(VI) in sediments was reduced to U(IV) with the addition of ethanol. The reduced products were not uraninite but were instead U(IV) complexes associated with Fe. Fe(III) in solid phase was only partially reduced. The Stanford team communicated with the ANL team members through email and conference calls and face to face at the annual ERSP PI meeting and national meetings.

  3. Method and electrochemical cell for synthesis and treatment of metal monolayer electrocatalysts metal, carbon, and oxide nanoparticles ion batch, or in continuous fashion

    SciTech Connect (OSTI)

    Adzic, Radoslav; Zhang, Junliang; Sasaki, Kotaro

    2015-04-28

    An apparatus and method for synthesis and treatment of electrocatalyst particles in batch or continuous fashion is provided. In one embodiment, the apparatus comprises a sonication bath and a two-compartment chamber submerged in the sonication bath. The upper and lower compartments are separated by a microporous material surface. The upper compartment comprises a cover and a working electrode (WE) connected to a Pt foil contact, with the foil contact connected to the microporous material. The upper chamber further comprises reference counter electrodes. The lower compartment comprises an electrochemical cell containing a solution of metal ions. In one embodiment, the method for synthesis of electrocatalysts comprises introducing a plurality of particles into the apparatus and applying sonication and an electrical potential to the microporous material connected to the WE. After the non-noble metal ions are deposited onto the particles, the non-noble metal ions are displaced by noble-metal ions by galvanic displacement.

  4. U Plant - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Us Projects & Facilities U Plant About Us About Hanford Cleanup Hanford History Hanford Site Wide Programs Contact Us 100 Area 118-K-1 Burial Ground 200 Area 222-S Laboratory 242-A Evaporator 300 Area 324 Building 325 Building 400 Area/Fast Flux Test Facility 618-10 and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and Interim Storage Area Canyon Facilities Cold Test Facility D and DR Reactors Effluent Treatment Facility Environmental Restoration

  5. Waste Isolation Pilot Plant

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4-3542 Site Sustainability Plan Waste Isolation Pilot Plant Fiscal Year 2015 Narrative November 2014 Office of Site Operations Carlsbad Field Office U.S. Department of Energy Approved By: //signature on file// 12/30/14 Jose R. Franco, Date Manager, Carlsbad Field Office Site Sustainability Plan Waste Isolation Pilot Plant, Fiscal Year 2015 Narrative DOE/WIPP-14-3542 Page 2 of 48 TABLE OF CONTENTS I. EXECUTIVE SUMMARY 4 TABLE 1. DOE Goal Summary Table 6 II. PERFORMANCE REVIEW AND PLAN NARRATIVE

  6. B Plant - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plant About Us About Hanford Cleanup Hanford History Hanford Site Wide Programs Contact Us 100 Area 118-K-1 Burial Ground 200 Area 222-S Laboratory 242-A Evaporator 300 Area 324 Building 325 Building 400 Area/Fast Flux Test Facility 618-10 and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and Interim Storage Area Canyon Facilities Cold Test Facility D and DR Reactors Effluent Treatment Facility Environmental Restoration Disposal Facility F Reactor H Reactor

  7. Comparison of different liquid anaerobic digestion effluents as inocula and nitrogen sources for solid-state batch anaerobic digestion of corn stover

    SciTech Connect (OSTI)

    Xu Fuqing; Shi Jian; Lv Wen; Yu Zhongtang; Li Yebo

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer Compared methane production of solid AD inoculated with different effluents. Black-Right-Pointing-Pointer Food waste effluent (FWE) had the largest population of acetoclastic methanogens. Black-Right-Pointing-Pointer Solid AD inoculated with FWE produced the highest methane yield at F/E ratio of 4. Black-Right-Pointing-Pointer Dairy waste effluent (DWE) was rich of cellulolytic and xylanolytic bacteria. Black-Right-Pointing-Pointer Solid AD inoculated with DWE produced the highest methane yield at F/E ratio of 2. - Abstract: Effluents from three liquid anaerobic digesters, fed with municipal sewage sludge, food waste, or dairy waste, were evaluated as inocula and nitrogen sources for solid-state batch anaerobic digestion of corn stover in mesophilic reactors. Three feedstock-to-effluent (F/E) ratios (i.e., 2, 4, and 6) were tested for each effluent. At an F/E ratio of 2, the reactor inoculated by dairy waste effluent achieved the highest methane yield of 238.5 L/kgVS{sub feed}, while at an F/E ratio of 4, the reactor inoculated by food waste effluent achieved the highest methane yield of 199.6 L/kgVS{sub feed}. The microbial population and chemical composition of the three effluents were substantially different. Food waste effluent had the largest population of acetoclastic methanogens, while dairy waste effluent had the largest populations of cellulolytic and xylanolytic bacteria. Dairy waste also had the highest C/N ratio of 8.5 and the highest alkalinity of 19.3 g CaCO{sub 3}/kg. The performance of solid-state batch anaerobic digestion reactors was closely related to the microbial status in the liquid anaerobic digestion effluents.

  8. Grace adds hydroprocessing plant

    SciTech Connect (OSTI)

    Fattah, H.

    1997-01-01

    W.R. Grace`s Davison Refining Catalysts Division will build a 20-million lbs/year hydroprocessing catalysts plant at Lake Charles, LA. The plant, planned for startup in early 1998, is part of the company`s ongoing effort to increase capacity to take advantage of significant growth in the hydroprocessing markets. The move {open_quotes}signifies a major step in our long-term commitment to the market,{close_quotes} says Robert Bullard, v.p./hydroprocessing catalysts. Davison also has an expansion scheduled for startup in February at its hydroprocessing catalysts plant at Curtis Bay, MD that will raise capacity there to 30 million lbs/year. The Lake Charles plant and the expansion total $40 million in investment, Grace says. Catalyst Consultants (Spring House, PA) expects growth of hydroprocessing demand to outstrip capacity, which is projected to grow 2.5%-3.5%/year. Demand is largely being fueled by tough environmental requirements on the sulfur content of gasoline, as well as by increased use of heavy, sour crude oil.

  9. B Plant hazards assessment

    SciTech Connect (OSTI)

    Broz, R.E.

    1994-09-23

    This document establishes the technical basis in support of Emergency Planning Activities for B Plant on the Hanford Site. The document represents an acceptable interpretation of the implementing guidance document for DOE Order 5500.3A. Through this document, the technical basis for the development of facility specific , Emergency Action Levels and the Emergency Planning Zone is demonstrated.

  10. T Plant hazards assessment

    SciTech Connect (OSTI)

    Broz, R.E.

    1994-09-27

    This document establishes the technical basis in support of Emergency Planning activities for the T Plant on the Hanford Site. The document represents an acceptable interpretation of the implementing guidance document for DOE ORDER 5500.3A. Through this document, the technical basis for the development of facility specific Emergency Action Levels and the Emergency Planning Zone is demonstrated.