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Sample records for basin tx-la-ms salt

  1. Texas-Louisiana- Mississippi Salt Basin Greater Green River Basin

    Gasoline and Diesel Fuel Update (EIA)

    Texas-Louisiana- Mississippi Salt Basin Greater Green River Basin W. Gulf Coast Basin ... Major Tight Gas Plays, Lower 48 States 0 200 400 100 300 Miles Source: Energy ...

  2. Supai salt karst features: Holbrook Basin, Arizona

    SciTech Connect (OSTI)

    Neal, J.T.

    1994-12-31

    More than 300 sinkholes, fissures, depressions, and other collapse features occur along a 70 km (45 mi) dissolution front of the Permian Supai Formation, dipping northward into the Holbrook Basin, also called the Supai Salt Basin. The dissolution front is essentially coincident with the so-called Holbrook Anticline showing local dip reversal; rather than being of tectonic origin, this feature is likely a subsidence-induced monoclinal flexure caused by the northward migrating dissolution front. Three major areas are identified with distinctive attributes: (1) The Sinks, 10 km WNW of Snowflake, containing some 200 sinkholes up to 200 m diameter and 50 m depth, and joint controlled fissures and fissure-sinks; (2) Dry Lake Valley and contiguous areas containing large collapse fissures and sinkholes in jointed Coconino sandstone, some of which drained more than 50 acre-feet ({approximately}6 {times} 10{sup 4} m{sup 3}) of water overnight; and (3) the McCauley Sinks, a localized group of about 40 sinkholes 15 km SE of Winslow along Chevelon Creek, some showing essentially rectangular jointing in the surficial Coconino Formation. Similar salt karst features also occur between these three major areas. The range of features in Supai salt are distinctive, yet similar to those in other evaporate basins. The wide variety of dissolution/collapse features range in development from incipient surface expression to mature and old age. The features began forming at least by Pliocene time and continue to the present, with recent changes reportedly observed and verified on airphotos with 20 year repetition. The evaporate sequence along interstate transportation routes creates a strategic location for underground LPG storage in leached caverns. The existing 11 cavern field at Adamana is safely located about 25 miles away from the dissolution front, but further expansion initiatives will require thorough engineering evaluation.

  3. Tanzania wildcats to evaluate Jurassic Mandawa salt basin

    SciTech Connect (OSTI)

    Nagati, M.

    1996-10-07

    After 5 years of stagnant exploration in East Africa, Canadian independent Tanganyika Oil Co. of Vancouver, B.C., will drill two wildcats in Tanzania to evaluate the hydrocarbon potential of the coastal Jurassic Mandawa salt basin. Mita-1, spudded around Oct. 1, will be drilled to about 7,000 ft, East Lika-1 will be drilled in early December 1996 to approximately 6,000 ft. The two wells will test different structures and play concepts. The paper describes the exploration history, source rock potential, hydrocarbon shows, potential reservoir, and the prospects.

  4. BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

    SciTech Connect (OSTI)

    Ernest A. Mancini; Donald A. Goddard; Ronald K. Zimmerman

    2005-05-10

    The principal research effort for Year 2 of the project has been data compilation and the determination of the burial and thermal maturation histories of the North Louisiana Salt Basin and basin modeling and petroleum system identification. In the first nine (9) months of Year 2, the research focus was on the determination of the burial and thermal maturation histories, and during the remainder of the year the emphasis has basin modeling and petroleum system identification. Existing information on the North Louisiana Salt Basin has been evaluated, an electronic database has been developed, regional cross sections have been prepared, structure and isopach maps have been constructed, and burial history, thermal maturation history and hydrocarbon expulsion profiles have been prepared. Seismic data, cross sections, subsurface maps and related profiles have been used in evaluating the tectonic, depositional, burial and thermal maturation histories of the basin. Oil and gas reservoirs have been found to be associated with salt-supported anticlinal and domal features (salt pillows, turtle structures and piercement domes); with normal faulting associated with the northern basin margin and listric down-to-the-basin faults (state-line fault complex) and faulted salt features; and with combination structural and stratigraphic features (Sabine and Monroe Uplifts) and monoclinal features with lithologic variations. Petroleum reservoirs are mainly Upper Jurassic and Lower Cretaceous fluvial-deltaic sandstone facies and Lower Cretaceous and Upper Cretaceous shoreline, marine bar and shallow shelf sandstone facies. Cretaceous unconformities significantly contribute to the hydrocarbon trapping mechanism capacity in the North Louisiana Salt Basin. The chief petroleum source rock in this basin is Upper Jurassic Smackover lime mudstone beds. The generation of hydrocarbons from Smackover lime mudstone was initiated during the Early Cretaceous and continued into the Tertiary. Hydrocarbon expulsion commenced during the Early Cretaceous and continued into the Tertiary with peak expulsion occurring mainly during the Late Cretaceous.

  5. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect (OSTI)

    Ernest A. Mancini; Paul Aharon; Donald A. Goddard; Roger Barnaby

    2006-02-28

    The principal research effort for Year 3 of the project is basin modeling and petroleum system identification, comparative basin evaluation and resource assessment. In the first six (6) months of Year 3, the research focus is on basin modeling and petroleum system identification and the remainder of the year the emphasis is on the comparative basin evaluation and resource assessment. No major problems have been encountered to date, and the project is on schedule. The principal objectives of the project are to develop through basin analysis and modeling the concept that petroleum systems acting in a basin can be identified through basin modeling and to demonstrate that the information and analysis resulting from characterizing and modeling of these petroleum systems in the North Louisiana Salt Basin and the Mississippi Interior Salt Basin can be used in providing a more reliable and advanced approach for targeting stratigraphic traps and specific reservoir facies within a geologic system and in providing a refined assessment of undiscovered and underdeveloped reservoirs and associated oil and gas resources.

  6. Characterization of bedded salt for storage caverns -- A case study from the Midland Basin, Texas

    SciTech Connect (OSTI)

    Hovorka, Susan D.; Nava, Robin

    2000-06-13

    The geometry of Permian bedding salt in the Midland Basin is a product of interaction between depositional facies and postdepositional modification by salt dissolution. Mapping high-frequency cycle patterns in cross section and map view using wireline logs documents the salt geometry. Geologically based interpretation of depositional and dissolution processes provides a powerful tool for mapping and geometry of salt to assess the suitability of sites for development of solution-mined storage caverns. In addition, this process-based description of salt geometry complements existing data about the evolution of one of the best-known sedimentary basins in the world, and can serve as a genetic model to assist in interpreting other salts.

  7. Bibliography, geophysical data locations, and well core listings for the Mississippi Interior Salt Basin

    SciTech Connect (OSTI)

    1998-05-01

    To date, comprehensive basin analysis and petroleum system modeling studies have not been performed on any of the basins in the northeastern Gulf of Mexico. Of these basins, the Mississippi Interior Salt Basin has been selected for study because it is the most petroliferous basin in the northeastern Gulf of Mexico, small- and medium-size companies are drilling the majority of the exploration wells. These companies do not have the resources to perform basin analysis or petroleum system modeling research studies nor do they have the resources to undertake elaborate information searches through the volumes of publicly available data at the universities, geological surveys, and regulatory agencies in the region. The Advanced Geologic Basin Analysis Program of the US Department of Energy provides an avenue for studying and evaluating sedimentary basins. This program is designed to improve the efficiency of the discovery of the nation`s remaining undiscovered oil resources by providing improved access to information available in the public domain and by increasing the amount of public information on domestic basins. This report provides the information obtained from Year 1 of this study of the Mississippi Interior Salt Basin. The work during Year 1 focused on inventorying the data files and records of the major information repositories in the northeastern Gulf of Mexico and making these inventories easily accessible in an electronic format.

  8. Influence of impurities on the creep of salt from the Palo Duro Basin

    SciTech Connect (OSTI)

    Hansen, F.D.; Senseny, P.E.; Pfeifle, T.W.; Vogt, T.J.

    1987-05-01

    Twelve triaxial compression creep tests were performed on salt specimens from the Woods-Holtzclaw well in the Palo Duro Basin to assess the influence of impurities on creep deformation. Four nominal impurity levels were initially selected for investigation: pure salt, salt containing 10% anhydrite, salt containing 10% mud, and salt containing 20% mud. Subsequent petrological measurements show these idealized categories do not exist. Composition of the samples was measured by methods of wet chemistry coupled with ethylene diaminetetraacetic acid (EDTA) digestion and point counting on full-size polished sections. Overall, the 12 specimens comprise 71.6--96.6% halite, 2.4--7.5% anhydrite, and 0.2--24.7% clay. Nine of the 12 specimens are similar to many other tested specimens from the Lower San Andres Unit 5. They range from 90--97% halite and average 94% with a standard deviation of 2%. The remaining 6% impurities are disseminated clay and anhydrite. The other three specimens from the Lower San Andres Unit 4 contain large amounts (average 20%) of uniformly distributed clays and average only 75% halite. 11 refs., 21 figs., 5 tabs.

  9. BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

    SciTech Connect (OSTI)

    Ernest A. Mancini; Donald A. Goddard

    2005-08-01

    The principal research effort for Year 3 of the project is basin modeling and petroleum system identification, comparative basin evaluation and resource assessment. In the first six (6) months of Year 3, the research focus is on basin modeling and petroleum system identification and the remainder of the year the emphasis is on the comparative basin evaluation and resource assessment. No major problems have been encountered to date, and the project is on schedule.

  10. Basin Analysis of the Mississippi Interior Salt Basin and Petroleum System Modeling of the Jurassic Smackover Formation, Eastern Gulf Coastal Plain, Final Report and Topical Reports 5-8 on Smackover Petroleum system and Underdevelopment Reservoirs

    SciTech Connect (OSTI)

    Mancini, Ernest A.; Puckett, T. Markham; Parcell, William C.; Llinas, Juan Carlos; Kopaska-Merkel, David C.; Townsend, Roger N.

    2002-03-05

    The Smackover Formation, a major hydrocarbon-producing horizon in the Mississippi Interior Salt Basin (MISB), conformably overlies the Norphlet Formation and is conformably overlain by the Buckner Anhydrite Member of the Haynesville Formation. The Norphlet-Smackover contact can be either gradational or abrupt. The thickness and lithofacies distribution of the Smackover Formation were controlled by the configuration of incipient paleotopography. The Smackover Formation has been subdivided into three informal members, referred to as the lower, middle and upper members.

  11. Elements of an environmental decision support system for seasonal wetland salt management in a river basin subjected to water quality regulation

    SciTech Connect (OSTI)

    Quinn, N.W.T.

    2009-06-01

    Seasonally managed wetlands in the Grasslands Basin on the west-side of California's San Joaquin Valley provide food and shelter for migratory wildfowl during winter months and sport for waterfowl hunters during the annual duck season. Surface water supply to these wetlands contain salt which, when drained to the San Joaquin River during the annual drawdown period, can negatively impact water quality and cause concern to downstream agricultural riparian water diverters. Recent environmental regulation, limiting discharges salinity to the San Joaquin River and primarily targeting agricultural non-point sources, now also targets return flows from seasonally managed wetlands. Real-time water quality management has been advocated as a means of continuously matching salt loads discharged from agricultural, wetland and municipal operations to the assimilative capacity of the San Joaquin River. Past attempts to build environmental monitoring and decision support systems (EDSS's) to implement this concept have enjoyed limited success for reasons that are discussed in this paper. These reasons are discussed in the context of more general challenges facing the successful implementation of a comprehensive environmental monitoring, modelling and decision support system for the San Joaquin River Basin.

  12. Salt restrains maturation in subsalt plays

    SciTech Connect (OSTI)

    Mello, U.T. ); Anderson, R.N.; Karner, G.D. . Lamont-Doherty Earth Observatory)

    1994-01-31

    The thermal positive anomaly associated with the top of salt diapirs has attracted significant attention in modifying the temperature structure and history of a sedimentary basin. Here the authors explore the role of the negative thermal anomaly beneath salt in modifying the maturation history of the source rocks in subsalt sediments. Organic matter maturation is believed to follow temperature dependent chemical reactions. Therefore, any temperature anomaly associated with salt masses affects the nearby maturation of potential source rocks. The level of maturity of source rocks close to salt diapirs will differ from that predicted based on regional trends. The impact of the thermal anomaly on a given point will depend on the duration and distance of the thermal anomaly to this particular point. Consequently, the maturation history of source rocks in salt basins is closely related to the salt motion history, implying that a transient thermal analysis is necessary to evaluate the sure impact on maturation of the thermal anomalies associated with salt diapirism. The paper describes vitrinite kinetics, salt in evolving basins, correlation of salt and temperature, salt dome heat drains, and restrained maturation.

  13. Petrographic report on clay-rich samples from Permian Unit 4 salt, G. Friemel No. 1 well, Palo Duro Basin, Deaf Smith County, Texas: unanalyzed data

    SciTech Connect (OSTI)

    Fukui, L M

    1983-09-01

    This report presents the results of mineralogic and petrographic analyses performed on five samples of clay-rich rock from salt-bearing Permian strata sampled by drill core from G. Friemel No. 1 Well, Deaf Smith County, Texas. Five samples of clay-rich rock from depths of about 2457, 2458, 2521, 2548, and 2568 feet were analyzed to determine the amounts of soluble phase (halite) and the amounts and mineralogy of the insoluble phases. The amounts of halite found were 59, 79, 47, 40, and 4 weight percent, respectively, for the samples. The insoluble minerals are predominately clay (20 to 60 volume percent) and anhydrite (up to 17 volume percent), with minor (about 1.0%) and trace amounts of quartz, dolomite, muscovite, and gypsum. The clays include illite, chlorite, and interstratified chlorite-smectite. The results presented in this petrographic report are descriptive, uninterpreted data. 2 references, 7 tables.

  14. Sandia Energy - Molten Salt Test Loop Melted Salt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Salt Home Renewable Energy Energy News Concentrating Solar Power Solar Molten Salt Test Loop Melted Salt Previous Next Molten Salt Test Loop Melted Salt The Molten Salt Test...

  15. Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance...

    Open Energy Info (EERE)

    To The Hydrocarbon Exploration In The Tuz Golu (Salt Lake) Basin, Central Anatolia, Turkey Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  16. Salt Waste Processing Initiatives

    Office of Environmental Management (EM)

    Patricia Suggs Salt Processing Team Lead Assistant Manager for Waste Disposition Project Office of Environmental Management Savannah River Site Salt Waste Processing Initiatives 2 ...

  17. Electrolyte salts for power sources

    DOE Patents [OSTI]

    Doddapaneni, Narayan; Ingersoll, David

    1995-01-01

    Electrolyte salts for power sources comprising salts of phenyl polysulfonic acids and phenyl polyphosphonic acids. The preferred salts are alkali and alkaline earth metal salts, most preferably lithium salts.

  18. Slime-busting Salt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    past issues All Issues submit Slime-busting Salt A potential new treatment gets bacteria deep in their hiding places May 1, 2015 Slime-busting Salt Biofilms are made of...

  19. Ancient Salt Beds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ancient Salt Beds Dr. Jack Griffith The key to the search for life on other planets may go through WIPP's ancient salt beds. In 2008, a team of scientists led by Jack Griffith, from the University of North Carolina, Chapel Hill, retrieved salt samples from the WIPP underground and studied them with a transmission electron microscopy lab at the Lineberger Comprehensive Cancer Center of the University of North Carolina School of Medicine. In examining fluid inclusions in the salt and solid halite

  20. Preliminary analyses of scenarios for potential human interference for repositories in three salt formations

    SciTech Connect (OSTI)

    Not Available

    1985-10-01

    Preliminary analyses of scenarios for human interference with the performance of a radioactive waste repository in a deep salt formation are presented. The following scenarios are analyzed: (1) the U-Tube Connection Scenario involving multiple connections between the repository and the overlying aquifer system; (2) the Single Borehole Intrusion Scenario involving penetration of the repository by an exploratory borehole that simultaneously connects the repository with overlying and underlying aquifers; and (3) the Pressure Release Scenario involving inflow of water to saturate any void space in the repository prior to creep closure with subsequent release under near lithostatic pressures following creep closure. The methodology to evaluate repository performance in these scenarios is described and this methodology is applied to reference systems in three candidate formations: bedded salt in the Palo Duro Basin, Texas; bedded salt in the Paradox Basin, Utah; and the Richton Salt Dome, Mississippi, of the Gulf Coast Salt Dome Basin.

  1. South Atlantic sag basins: new petroleum system components

    SciTech Connect (OSTI)

    Henry, S.G. Mohriak, W.U.; Mello, M.R.

    1996-08-01

    Newly discovered pre-salt source rocks, reservoirs and seals need to be included as components to the petroleum systems of both sides of the South Atlantic. These new components lie between the pre-salt rift strata and the Aptian salt layers, forming large, post-rift, thermal subsidence sag basins. These are differentiated from the older rift basins by the lack of syn-rift faulting and a reflector geometry that is parallel to the base salt regional unconformity rather than to the Precambrian basement. These basins are observed in deep water regions overlying areas where both the mantle and the crust have been involved in the extension. This mantle involvement creates post-rift subsiding depocenters in which deposition is continuous while proximal rift-phase troughs with little or no mantle involvement are bypassed and failed to accumulate potential source rocks during anoxic times. These features have been recognized in both West African Kwanza Basin and in the East Brasil Rift systems. The pre-salt source rocks that are in the West African sag basins were deposited in lacustrine brackish to saline water environment and are geochemically distinct from the older, syn-rift fresh to brackish water lakes, as well as from younger, post-salt marine anoxic environments of the drift phase. Geochemical analyses of the source rocks and their oils have shown a developing source rock system evolving from isolated deep rift lakes to shallow saline lakes, and culminating with the infill of the sag basin by large saline lakes to a marginally marine restricted gulf. Sag basin source rocks may be important in the South Atlantic petroleum system by charging deep-water prospects where syn-rift source rocks are overmature and the post-salt sequences are immature.

  2. Parana basin

    SciTech Connect (OSTI)

    Zalan, P.V.; Wolff, S.; Conceicao, J.C.J.; Vieira, I.S.; Astolfi, M.A.; Appi, V.T.; Zanotto, O.; Neto, E.V.S.; Cerqueira, J.R.

    1987-05-01

    The Parana basin is a large intracratonic basin in South America, developed entirely on continental crust and filled with sedimentary and volcanic rocks ranging in age from Silurian to Cretaceous. It occupies the southern portion of Brazil (1,100,000 km/sup 2/ or 425,000 mi/sup 2/) and the eastern half of Paraguay (100,000 km/sup 2/ or 39,000 mi/sup 2/); its extension into Argentina and Uruguay is known as the Chaco-Parana basin. Five major depositional sequences (Silurian, Devonian, Permo-Carboniferous, Triassic, Juro-Cretaceous) constitute the stratigraphic framework of the basin. The first four are predominantly siliciclastic in nature, and the fifth contains the most voluminous basaltic lava flows of the planet. Maximum thicknesses are in the order of 6000 m (19,646 ft). The sequences are separated by basin wide unconformities related in the Paleozoic to Andean orogenic events and in the Mesozoic to the continental breakup and sea floor spreading between South America and Africa. The structural framework of the Parana basin consists of a remarkable pattern of criss-crossing linear features (faults, fault zones, arches) clustered into three major groups (N45/sup 0/-65/sup 0/W, N50/sup 0/-70/sup 0/E, E-W). The northwest- and northeast-trending faults are long-lived tectonic elements inherited from the Precambrian basement whose recurrent activity throughout the Phanerozoic strongly influenced sedimentation, facies distribution, and development of structures in the basin. Thermomechanical analyses indicate three main phases of subsidence (Silurian-Devonian, late Carboniferous-Permian, Late Jurassic-Early Cretaceous) and low geothermal gradients until the beginning of the Late Jurassic Permian oil-prone source rocks attained maturation due to extra heat originated from Juro-Cretaceous igneous intrusions. The third phase of subsidence also coincided with strong tectonic reactivation and creation of a third structural trend (east-west).

  3. Geomechanical Analysis and Design Considerations for Thin-Bedded Salt Caverns

    SciTech Connect (OSTI)

    Michael S. Bruno

    2005-06-15

    The bedded salt formations located throughout the United States are layered and interspersed with non-salt materials such as anhydrite, shale, dolomite and limestone. The salt layers often contain significant impurities. GRI and DOE have initialized this research proposal in order to increase the gas storage capabilities by providing operators with improved geotechnical design and operating guidelines for thin bedded salt caverns. Terralog has summarized the geologic conditions, pressure conditions, and critical design factors that may lead to: (1) Fracture in heterogeneous materials; (2) Differential deformation and bedding plane slip; (3) Propagation of damage around single and multiple cavern; and (4) Improved design recommendations for single and multiple cavern configurations in various bedded salt environments. The existing caverns within both the Permian Basin Complex and the Michigan and Appalachian Basins are normally found between 300 m to 1,000 m (1,000 ft to 3,300 ft) depth depending on local geology and salt dissolution depth. Currently, active cavern operations are found in the Midland and Anadarko Basins within the Permian Basin Complex and in the Appalachian and Michigan Basins. The Palo Duro and Delaware Basins within the Permian Basin Complex also offer salt cavern development potential. Terralog developed a number of numerical models for caverns located in thin bedded salt. A modified creep viscoplastic model has been developed and implemented in Flac3D to simulate the response of salt at the Permian, Michigan and Appalachian Basins. The formulation of the viscoplastic salt model, which is based on an empirical creep law developed for Waste Isolation Pilot Plant (WIPP) Program, is combined with the Drucker-Prager model to include the formation of damage and failure. The Permian salt lab test data provided by Pfeifle et al. 1983, are used to validate the assumptions made in the material model development. For the actual cavern simulations two baseline models are developed for single and multiple caverns, respectively. Different parameters that affect damage propagation and deformation of salt cavern, such as cavern pressure, operating conditions, cavern height/diameter ratio, overburden stiffness and roof thickness are analyzed and the respective results summarized. For multiple horizontal caverns numerical models are developed to determine the cavern interaction and the minimum safe center to center distance. A step by step methodology for operators to assess critical cavern design parameters for thin bedded salt formations is also presented.

  4. Information technology and decision support tools for stakeholder-driven river basin salinity management

    SciTech Connect (OSTI)

    Quinn, N.W.T; Cozad, D.B.; Lee, G.

    2010-01-01

    Innovative strategies for effective basin-scale salinity management have been developed in the Hunter River Basin of Australia and more recently in the San Joaquin River Basin of California. In both instances web-based stakeholder information dissemination has been a key to achieving a high level of stakeholder involvement and the formulation of effective decision support salinity management tools. A common element to implementation of salinity management strategies in both river basins has been the concept of river assimilative capacity for controlling export salt loading and the potential for trading of the right to discharge salt load to the river - the Hunter River in Australia and the San Joaquin River in California. Both rivers provide basin drainage and the means of exporting salt to the ocean. The paper compares and contrasts the use of monitoring, modeling and information dissemination in the two basins to achieve environmental compliance and sustain irrigated agriculture in an equitable and socially and politically acceptable manner.

  5. Dosimetry using silver salts

    DOE Patents [OSTI]

    Warner, Benjamin P.

    2003-06-24

    The present invention provides a method for detecting ionizing radiation. Exposure of silver salt AgX to ionizing radiation results in the partial reduction of the salt to a mixture of silver salt and silver metal. The mixture is further reduced by a reducing agent, which causes the production of acid (HX) and the oxidized form of the reducing agent (R). Detection of HX indicates that the silver salt has been exposed to ionizing radiation. The oxidized form of the reducing agent (R) may also be detected. The invention also includes dosimeters employing the above method for detecting ionizing radiation.

  6. Salt Selected (FINAL)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Technical Information Salt Lake Community College Spotlights Home DOE Applauds SLCC Science and Technical Programs Salt Lake City, Utah Architectural Technology Biology Biotechnology Biomanufacturing Chemistry Computer Science Electric Sector Training Energy Management Engineering Geographic Information Sciences Geosciences InnovaBio Manufacturing & Mechanical Engineering Technology Mathematics Physics SLCC Partners with DOE's Rocky Mountain Solar Training Program This program is a

  7. Hydroxycarboxylic acids and salts

    DOE Patents [OSTI]

    Kiely, Donald E; Hash, Kirk R; Kramer-Presta, Kylie; Smith, Tyler N

    2015-02-24

    Compositions which inhibit corrosion and alter the physical properties of concrete (admixtures) are prepared from salt mixtures of hydroxycarboxylic acids, carboxylic acids, and nitric acid. The salt mixtures are prepared by neutralizing acid product mixtures from the oxidation of polyols using nitric acid and oxygen as the oxidizing agents. Nitric acid is removed from the hydroxycarboxylic acids by evaporation and diffusion dialysis.

  8. Molten salt electrolyte separator

    DOE Patents [OSTI]

    Kaun, T.D.

    1996-07-09

    The patent describes a molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication. 5 figs.

  9. Water purification using organic salts

    DOE Patents [OSTI]

    Currier, Robert P.

    2004-11-23

    Water purification using organic salts. Feed water is mixed with at least one organic salt at a temperature sufficiently low to form organic salt hydrate crystals and brine. The crystals are separated from the brine, rinsed, and melted to form an aqueous solution of organic salt. Some of the water is removed from the aqueous organic salt solution. The purified water is collected, and the remaining more concentrated aqueous organic salt solution is reused.

  10. Playa basin development, southern High Plains, Texas and New Mexico

    SciTech Connect (OSTI)

    Gustavson, T.C. (Univ. of Texas, Austin, TX (United States)); Holliday, V.T. (Univ. of Wisconsin, Madison, WI (United States))

    1992-01-01

    More than 20,000 playa basins have formed on fine-grained eolian sediments of the Quaternary Blackwater Draw and Tertiary Ogallala Formations on the High Plains of TX and NM. Numerous hypotheses have been proposed for the development of playa basins: (1) subsidence due to dissolution of underlying Permian bedded salt, (2) dissolution of soil carbonate and piping of clastic sediment into the subsurface, (3) animal activity, and (4) deflation. Evidence of eolian processes includes lee dunes and straightened shorelines on the eastern and southern margins of many playas. Lee dunes, which occur on the eastern side of ca 15% of playa basins and contain sediment deflated from adjacent playas, are cresentic to oval in plain view and typically account for 15--40% of the volume of the playa basin. Quaternary fossil biotas and buried calcic soils indicate that grasslands and semi-arid to aid climatic conditions prevailed as these basins formed. Evidence of fluviolacustrine processes in playa basins includes centripetal drainage leading to fan deltas at playa margins and preserved deltaic and lacustrine sediments. Playa basins expanded as fluvial processes eroded basin slopes and carried sediment to the basin floor where, during periods of minimal vegetation cover, loose sediment was removed by deflation. Other processes that played secondary roles in the development of certain playa basins include subsidence induced by dissolution of deeply buried Permian salt, dissolution of soil carbonate and piping, and animal activity. Two small lake basins in Gray County, TX, occur above strata affected by dissolution-induced subsidence. Dissolution of soil carbonate was observed in exposures and cores of strata underlying playa basins. Cattle, and in the past vast numbers of migrating buffalo, destroy soil crusts in dry playas, making these sediments more susceptible to deflation, and carry sediment out of flooded playas on their hooves.

  11. Amine salts of nitroazoles

    DOE Patents [OSTI]

    Kienyin Lee; Stinecipher, M.M.

    1993-10-26

    Compositions of matter, a method of providing chemical energy by burning said compositions, and methods of making said compositions are described. These compositions are amine salts of nitroazoles. 1 figure.

  12. Salt Repository Research,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Downtown Santa Fe. Begins 10 AM. Map will be provided Day 2 September 9 - Tuesday TM-behavior of salt 08:30-08:50 Update on the "Joint Project on Constitutive Laws benchmark"...

  13. Basin Destination State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    43 0.0294 W - W W - - - Northern Appalachian Basin Florida 0.0161 W W W W 0.0216 W W W W W Northern Appalachian Basin Illinois W W - - - - - - - - - Northern Appalachian Basin...

  14. Basin Destination State

    Gasoline and Diesel Fuel Update (EIA)

    4. Estimated rail transportation rates for coal, basin to state, EIA data Basin Destination State 2008 2009 2010 2008-2010 2009-2010 Northern Appalachian Basin Delaware 26.24 - W...

  15. Basin Destination State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    3. Estimated rail transportation rates for coal, basin to state, EIA data Basin Destination State 2008 2009 2010 2008-2010 2009-2010 Northern Appalachian Basin Delaware 28.49 - W...

  16. the Central Basin Platform,

    Office of Scientific and Technical Information (OSTI)

    p q - o o f - - 2 3 - % 8 Overview of the Structural Geology and Tectonics of the Central Basin Platform, Delaware Basin, and Midland Basin, West Texas and New Mexico T ...

  17. Salt Repository Research,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Salt Lake City Gamma Shield Thunder Exercise Concludes National Nuclear Security Administration (NNSA) and the FBI announced today the completion of the Gamma Shield Thunder counterterrorism table-top exercise at LDS Hospital. The exercise is part of NNSA's Silent Thunder table-top series, which is aimed at giving federal, state and local

    6 th US/German Workshop on Salt Repository Research, Design, and Operation Hotel Pullmann Dresden Newa Dresden September 7 - 9, 2015 September 7- Monday

  18. Fundamental Properties of Salts

    SciTech Connect (OSTI)

    Toni Y Gutknecht; Guy L Fredrickson

    2012-11-01

    Thermal properties of molten salt systems are of interest to electrorefining operations, pertaining to both the Fuel Cycle Research & Development Program (FCR&D) and Spent Fuel Treatment Mission, currently being pursued by the Department of Energy (DOE). The phase stability of molten salts in an electrorefiner may be adversely impacted by the build-up of fission products in the electrolyte. Potential situations that need to be avoided, during electrorefining operations, include (i) fissile elements build up in the salt that might approach the criticality limits specified for the vessel, (ii) electrolyte freezing at the operating temperature of the electrorefiner due to changes in the liquidus temperature, and (iii) phase separation (non-homogenous solution). The stability (and homogeneity) of the phases can be monitored by studying the thermal characteristics of the molten salts as a function of impurity concentration. Simulated salt compositions consisting of the selected rare earth and alkaline earth chlorides, with a eutectic mixture of LiCl-KCl as the carrier electrolyte, were studied to determine the melting points (thermal characteristics) using a Differential Scanning Calorimeter (DSC). The experimental data were used to model the liquidus temperature. On the basis of the this data, it became possible to predict a spent fuel treatment processing scenario under which electrorefining could no longer be performed as a result of increasing liquidus temperatures of the electrolyte.

  19. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  20. Salt Repository Research,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    th US/German Workshop on Salt Repository Research, Design, and Operation Hotel Pullman Dresden Newa September 7 - 9, 2015 September 7- Monday 08:00-08:30 Registration 08:30-08:50 Welcome by the organizers T. Lautsch, DBE F. Hansen, SNL W. Steininger, PTKA 08:50-09:15 Welcome by BMWi U. Borak, BMWi 09:15-09:30 Welcome by USDOE N. Buschman, US DOE 09:30-10:00 NEA Salt Club J. Mönig, GRS SAFETY CASE ISSUES 10:00-10:30 WIPP recovery F. Hansen, SNL 10:30-11:00 Coffee break and photo event

  1. Salt Wells Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Salt Wells Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Salt Wells Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 2.1 Salt...

  2. Electrolytic orthoborate salts for lithium batteries (Patent...

    Office of Scientific and Technical Information (OSTI)

    Electrolytic orthoborate salts for lithium batteries Title: Electrolytic orthoborate salts for lithium batteries Orthoborate salts suitable for use as electrolytes in lithium ...

  3. Sandia Energy - Molten Salt Test Loop Commissioning

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Energy News EC News & Events Concentrating Solar Power Solar Molten Salt Test Loop Commissioning Previous Next Molten Salt Test Loop Commissioning The Molten Salt...

  4. Actinide removal from spent salts

    DOE Patents [OSTI]

    Hsu, Peter C.; von Holtz, Erica H.; Hipple, David L.; Summers, Leslie J.; Adamson, Martyn G.

    2002-01-01

    A method for removing actinide contaminants (uranium and thorium) from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents are added to precipitate the thorium as thorium oxide and/or the uranium as either uranium oxide or as a diuranate salt. The precipitated materials are filtered, dried and packaged for disposal as radioactive waste. About 90% of the thorium and/or uranium present is removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 0.1 ppm of thorium or uranium.

  5. Metals removal from spent salts

    DOE Patents [OSTI]

    Hsu, Peter C.; Von Holtz, Erica H.; Hipple, David L.; Summers, Leslie J.; Brummond, William A.; Adamson, Martyn G.

    2002-01-01

    A method and apparatus for removing metal contaminants from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents may be added to precipitate the metal oxide and/or the metal as either metal oxide, metal hydroxide, or as a salt. The precipitated materials are filtered, dried and packaged for disposal as waste or can be immobilized as ceramic pellets. More than about 90% of the metals and mineral residues (ashes) present are removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be spray-dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 1.0 ppm of contaminants.

  6. Basin Destination State

    Gasoline and Diesel Fuel Update (EIA)

    0.0323 0.0284 W - W W - - - Northern Appalachian Basin Florida 0.0146 W W W W 0.0223 W W W W W Northern Appalachian Basin Illinois W W - - - - - - - - - Northern Appalachian...

  7. Nocturnal Low-Level Jet in a Mountain Basin Complex. I. Evolution and Effects on Local Flows

    SciTech Connect (OSTI)

    Banta, Robert M.; Darby, Lisa S.; Fast, Jerome D.; Pinto, James O.; Whiteman, Charles D.; Shaw, William J.; Orr, Brad W.

    2004-10-01

    A Doppler lidar deployed to the center of the Great Salt Lake (GSL) basin during the Vertical Transport and Mixing Experiment (VTMX) in October 2000 found a diurnal cycle of the along-basin winds with northerly, up-basin flow during the day and a southerly, down-basin low-level jet at night. The emphasis of VTMX was on stable atmospheric processes in the cold-air pool that formed in the basin at night. During the night the jet was fully formed as it entered the GSL basin from the south. Thus it was a feature of the complex string of basins draining into the Great Salt Lake, which included at least the Utah Lake basin to the south. The timing of the evening reversal to down-basin flow was sensitive to the larger-scale north-south pressure gradient imposed on the basin complex. On nights when the pressure gradient was not too strong, local drainage flow (slope flows and canyon outflow) was well developed along the Wasatch Range to the east and coexisted with the basin jet. The coexistence of these two types of flow generated localized regions of convergence and divergence, in which regions of vertical motions and transport were focused. Mesoscale numerical simulations captured these features and indicated that updrafts on the order of 5 cm/s could persist in these localized convergence zones, contributing to vertical displacement of air masses within the basin cold pool.

  8. Salt Repository Research,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Salt Repository Research, Design, and Operation La Fonda Hotel Santa Fe, New Mexico September 7 - 11, 2014 Please join us Sunday September 7, 2014 for a welcome and reception at the La Fonda Hotel hosted by Sandia National Laboratories beginning at 6:00 PM. Day 1 Technical Agenda September 8 - Monday 08:00-08:45 Sign-in and distribution of meeting materials 08:45-09:45 Welcome addresses H.C. Pape (BMWi) US-DOE Offices Highlights of US/German Collaboration F. Hansen (SNL) W. Steininger (PTKA)

  9. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D.; Poris, Jaime; Huggins, Robert A.

    1982-02-09

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

  10. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D.; Poris, Jaime; Huggins, Robert A.

    1983-01-01

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

  11. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, I.D.; Poris, J.; Huggins, R.A.

    1980-07-18

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell which may be operated at temperatures between about 100 to 170/sup 0/C. The cell is comprised of an electrolyte, which preferably includes lithium nitrate, and a lithium or lithium alloy electrode.

  12. Electrolyte salts for nonaqueous electrolytes

    DOE Patents [OSTI]

    Amine, Khalil; Zhang, Zhengcheng; Chen, Zonghai

    2012-10-09

    Metal complex salts may be used in lithium ion batteries. Such metal complex salts not only perform as an electrolyte salt in a lithium ion batteries with high solubility and conductivity, but also can act as redox shuttles that provide overcharge protection of individual cells in a battery pack and/or as electrolyte additives to provide other mechanisms to provide overcharge protection to lithium ion batteries. The metal complex salts have at least one aromatic ring. The aromatic moiety may be reversibly oxidized/reduced at a potential slightly higher than the working potential of the positive electrode in the lithium ion battery. The metal complex salts may also be known as overcharge protection salts.

  13. Batteries using molten salt electrolyte

    DOE Patents [OSTI]

    Guidotti, Ronald A.

    2003-04-08

    An electrolyte system suitable for a molten salt electrolyte battery is described where the electrolyte system is a molten nitrate compound, an organic compound containing dissolved lithium salts, or a 1-ethyl-3-methlyimidazolium salt with a melting temperature between approximately room temperature and approximately 250.degree. C. With a compatible anode and cathode, the electrolyte system is utilized in a battery as a power source suitable for oil/gas borehole applications and in heat sensors.

  14. Electrochromic salts, solutions, and devices

    DOE Patents [OSTI]

    Burrell, Anthony K.; Warner, Benjamin P.; McClesky,7,064,212 T. Mark

    2006-06-20

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  15. Electrochromic Salts, Solutions, and Devices

    DOE Patents [OSTI]

    Burrell, Anthony K.; Warner, Benjamin P.; McClesky, T. Mark

    2008-11-11

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  16. Electrochromic Salts, Solutions, and Devices

    DOE Patents [OSTI]

    Burrell, Anthony K.; Warner, Benjamin P.; McClesky, T. Mark

    2008-10-14

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  17. DOE - Office of Legacy Management -- Salt_Lake

    Office of Legacy Management (LM)

    SaltLake Salt Lake City Sites utmap Salt Lake City Disposal Site Salt Lake City Processing Site Last Updated: 6172015...

  18. Plant salt-tolerance mechanisms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

    2014-06-01

    Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selectionmore » and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.« less

  19. Plant salt-tolerance mechanisms

    SciTech Connect (OSTI)

    Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

    2014-06-01

    Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selection and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.

  20. Structural Interactions within Lithium Salt Solvates: Acyclic...

    Office of Scientific and Technical Information (OSTI)

    Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters Citation Details In-Document Search Title: Structural Interactions within Lithium Salt Solvates: ...

  1. Enterprise Assessments Salt Waste Processing Facility Construction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Salt Waste Processing Facility Construction Quality and Fire Protection Systems Follow-up Review at the Savannah River Site - January 2016 Enterprise Assessments Salt Waste ...

  2. Basin Destination State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    10.68 12.03 13.69 14.71 16.11 19.72 20.69 9.1 4.9 Northern Appalachian Basin Massachusetts W W - - - - - - - - - Northern Appalachian Basin Michigan 6.74 8.16 W 8.10 W W...

  3. Basin Destination State

    Gasoline and Diesel Fuel Update (EIA)

    11.34 12.43 13.69 14.25 15.17 18.16 18.85 6.5 3.8 Northern Appalachian Basin Massachusetts W W - - - - - - - - - Northern Appalachian Basin Michigan 7.43 8.85 W 8.37 W W...

  4. Wave Basin | Open Energy Information

    Open Energy Info (EERE)

    Basin Jump to: navigation, search Retrieved from "http:en.openei.orgwindex.php?titleWaveBasin&oldid596392" Feedback Contact needs updating Image needs updating Reference...

  5. K Basin safety analysis

    SciTech Connect (OSTI)

    Porten, D.R.; Crowe, R.D.

    1994-12-16

    The purpose of this accident safety analysis is to document in detail, analyses whose results were reported in summary form in the K Basins Safety Analysis Report WHC-SD-SNF-SAR-001. The safety analysis addressed the potential for release of radioactive and non-radioactive hazardous material located in the K Basins and their supporting facilities. The safety analysis covers the hazards associated with normal K Basin fuel storage and handling operations, fuel encapsulation, sludge encapsulation, and canister clean-up and disposal. After a review of the Criticality Safety Evaluation of the K Basin activities, the following postulated events were evaluated: Crane failure and casks dropped into loadout pit; Design basis earthquake; Hypothetical loss of basin water accident analysis; Combustion of uranium fuel following dryout; Crane failure and cask dropped onto floor of transfer area; Spent ion exchange shipment for burial; Hydrogen deflagration in ion exchange modules and filters; Release of Chlorine; Power availability and reliability; and Ashfall.

  6. Petroleum systems of Jianghan Basin, Hubel Province, China

    SciTech Connect (OSTI)

    Cunningham, A.E.; Schaps, S.; McGregor, D.

    1996-12-31

    The Jianghan Basin is a Cretaceous-Tertiary nonmarine rift basin superimposed on a late Precambrian to Jurassic passive margin and foreland basin succession deformed by mid-Mesozoic folding and thrusting. Hence the basin has potential for superimposed petroleum systems. Oil production is established in a Tertiary petroleum system developed in two major depocenters, the Jiangling (west) and Qianjiang (east) Depressions. Lacustrine source beds in the early Eocene Xingouzhui and late Eocene Qianjiang Formations generated hydrocarbons during local maximum basin fill in the Oligocene to present. Very early, low temperature generation of petroleum occurs where Type 1S Qianjiang Formation kerogen is present. Tertiary fluvial and deltaic sandstones form reservoirs that trap oil in highs or rollover structures formed by normal faulting and salt movement. The pre-rift section contains large folds and good source-beds, but has high exploration risk. Factors limiting effectiveness of older petroleum systems are: (1) Uplift and erosion of thrust structures; (2) Overmaturation of pre-Permian source rocks prior to folding and thrusting; (3) Limited extent of secondary maturation of Late Paleozoic and Mesozoic source beds; and (4) Disruption of older traps and seals by widespread normal faulting. Production of hydrocarbons from Permian and Triassic rocks to the west of Hubei suggests that further seismic work and drilling are merited to evaluate pre-Tertiary potential in the Jianghan Basin.

  7. Petroleum systems of Jianghan Basin, Hubel Province, China

    SciTech Connect (OSTI)

    Cunningham, A.E. ); Schaps, S.; McGregor, D. )

    1996-01-01

    The Jianghan Basin is a Cretaceous-Tertiary nonmarine rift basin superimposed on a late Precambrian to Jurassic passive margin and foreland basin succession deformed by mid-Mesozoic folding and thrusting. Hence the basin has potential for superimposed petroleum systems. Oil production is established in a Tertiary petroleum system developed in two major depocenters, the Jiangling (west) and Qianjiang (east) Depressions. Lacustrine source beds in the early Eocene Xingouzhui and late Eocene Qianjiang Formations generated hydrocarbons during local maximum basin fill in the Oligocene to present. Very early, low temperature generation of petroleum occurs where Type 1S Qianjiang Formation kerogen is present. Tertiary fluvial and deltaic sandstones form reservoirs that trap oil in highs or rollover structures formed by normal faulting and salt movement. The pre-rift section contains large folds and good source-beds, but has high exploration risk. Factors limiting effectiveness of older petroleum systems are: (1) Uplift and erosion of thrust structures; (2) Overmaturation of pre-Permian source rocks prior to folding and thrusting; (3) Limited extent of secondary maturation of Late Paleozoic and Mesozoic source beds; and (4) Disruption of older traps and seals by widespread normal faulting. Production of hydrocarbons from Permian and Triassic rocks to the west of Hubei suggests that further seismic work and drilling are merited to evaluate pre-Tertiary potential in the Jianghan Basin.

  8. Geology and geohydrology of the Palo Duro Basin, Texas Panhandle. Report on the progress of nuclear waste isolation feasibility studies, 1979

    SciTech Connect (OSTI)

    Gustavson, T.C.; Presley, M.W.; Handford, C.R.; Finley, R.J.; Dutton, S.P.; Baumgardner, R.W. Jr.; McGillis, K.A.; Simpkins, W.W.

    1980-01-01

    Since early 1977, the Bureau of Economic Geology has been evaluating several salt-bearing basins within the State of Texas as part of the national nuclear repository program. The Bureau, a research unit of The University of Texas at Austin and the State of Texas, is carrying out a long-term program to gather and interpret all geologic and hydrologic information necessary for description, delineation, and evaluation of salt-bearing strata in the Palo Duro and Dalhart Basins of the Texas Panhandle. The program in FY 79 has been subdivided into four broad research tasks, which are addressed by a basin analysis group, a surface studies group, a geohydrology group, and a host-rock analysis group. The basin analysis group has delineated the structural and stratigraphic framework of the basins, initiated natural resource assessment, and integrated data from 8000 ft (2400 m) of core material into salt-stratigraphy models. Salt depth and thickness have been delineated for seven salt-bearing stratigraphic units. Concurrently, the surface studies group has collected ground and remotely sensed data to describe surficial processes, including salt solution, slope retreat/erosion mechanisms, geomorphic evolution, and fracture system development. The basin geohydrology group has begun evaluating both shallow and deep fluid circulation within the basins. The newly formed host-rock analysis group has initiated study of cores from two drilling sites for analysis of salt and the various lithologies overlying and interbedded with salt units. This paper, a summary report of progress in FY 79, presents principal conclusions and reviews methods used and types of data and maps generated.

  9. K Basin Hazard Analysis

    SciTech Connect (OSTI)

    PECH, S.H.

    2000-08-23

    This report describes the methodology used in conducting the K Basins Hazard Analysis, which provides the foundation for the K Basins Final Safety Analysis Report. This hazard analysis was performed in accordance with guidance provided by DOE-STD-3009-94, Preparation Guide for U. S. Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports and implements the requirements of DOE Order 5480.23, Nuclear Safety Analysis Report.

  10. K Basins Hazard Analysis

    SciTech Connect (OSTI)

    WEBB, R.H.

    1999-12-29

    This report describes the methodology used in conducting the K Basins Hazard Analysis, which provides the foundation for the K Basins Safety Analysis Report (HNF-SD-WM-SAR-062, Rev.4). This hazard analysis was performed in accordance with guidance provided by DOE-STD-3009-94, Preparation Guide for U. S. Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports and implements the requirements of DOE Order 5480.23, Nuclear Safety Analysis Report.

  11. Understanding Long-Term Solute Transport in Sedimentary Basins: Simulating Brine Migration in the Alberta Basin. Final Report

    SciTech Connect (OSTI)

    Alicia M. Wilson

    2009-11-30

    Mass transport in deep sedimentary basins places important controls on ore formation, petroleum migration, CO2 sequestration, and geochemical reactions that affect petroleum reservoir quality, but large-scale transport in this type of setting remains poorly understood. This lack of knowledge is highlighted in the resource-rich Alberta Basin, where geochemical and hydrogeologic studies have suggested residence times ranging from hundreds of millions of years to less than 5 My, respectively. Here we developed new hydrogeologic models that were constrained by geochemical observations to reconcile these two very different estimates. The models account for variable-density fluid flow, heat transport, solute transport, sediment deposition and erosion, sediment compressibility, and dissolution of salt deposits, including Cl/Br systematics. Prior interpretations of Cl/Br ratios in the Alberta Basin concluded that the brines were derived from evaporatively-concentrated brines that were subsequently diluted by seawater and freshwater; models presented here show that halite dissolution must have contributed strongly as well, which implies significantly greater rates of mass transport. This result confirms that Cl/Br ratios are subject to significant non-uniqueness and thus do not provide good independent indicators of the origin of brines. Salinity and Cl/Br ratios provided valuable new constraints for basin-scale models, however. Sensitivity studies revealed that permeabilities obtained from core- and field-scale tests were appropriate for basin-scale models, despite the differences in scale between the tests and the models. Simulations of groundwater age show that the residence time of porefluids in much of the basin is less than 100 My. Groundwater age increases with depth and approaches 200 My in the deepest part of the basin, but brines are significantly younger than their host rocks throughout the basin.

  12. Haynes Wave Basin | Open Energy Information

    Open Energy Info (EERE)

    Wave Basin Jump to: navigation, search Basic Specifications Facility Name Haynes Wave Basin Overseeing Organization Texas A&M (Haynes) Hydrodynamic Testing Facility Type Wave Basin...

  13. Production of chlorine from chloride salts

    DOE Patents [OSTI]

    Rohrmann, Charles A. (Kennewick, WA)

    1981-01-01

    A process for converting chloride salts and sulfuric acid to sulfate salts and elemental chlorine is disclosed. A chloride salt and sulfuric acid are combined in a furnace where they react to produce a sulfate salt and hydrogen chloride. Hydrogen chloride from the furnace contacts a molten salt mixture containing an oxygen compound of vanadium, an alkali metal sulfate and an alkali metal pyrosulfate to recover elemental chlorine. In the absence of an oxygen-bearing gas during the contacting, the vanadium is reduced, but is regenerated to its active higher valence state by separately contacting the molten salt mixture with an oxygen-bearing gas.

  14. Geology and geohydrology of the east Texas Basin. Report on the progress of nuclear waste isolation feasibility studies (1979)

    SciTech Connect (OSTI)

    Kreitler, C.W.; Agagu, O.K.; Basciano, J.M.

    1980-01-01

    The program to investigate the suitability of salt domes in the east Texas Basin for long-term nuclear waste repositories addresses the stability of specific domes for potential repositories and evaluates generically the geologic and hydrogeologic stability of all the domes in the region. Analysis during the second year was highlighted by a historical characterization of East Texas Basin infilling, the development of a model to explain the growth history of the domes, the continued studies of the Quaternary in East Texas, and a better understanding of the near-dome and regional hydrology of the basin. Each advancement represents a part of the larger integrated program addressing the critical problems of geologic and hydrologic stabilities of salt domes in the East Texas Basin.

  15. Treatment of Remediated Nitrate Salts

    Broader source: Energy.gov [DOE]

    Los Alamos National Laboratory, provided a presentation at the NNMCABs November 18, 2015 Board Meeting at New Mexico Highlands University. The topic of the presentation was the plan for remediation the nitrate salt waste from the 3706 campaign that is currently stored at Material Disposal Area G, presenter was David Funk, LANS.

  16. Salt Wells Geothermal Project | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Development Project: Salt Wells Geothermal Project Project Location Information Coordinates 39.580833333333,...

  17. Brine Migration Experimental Studies for Salt Repositories

    Broader source: Energy.gov [DOE]

    Experiments were used to examine water content in Permian salt samples including impact of variation in thermal regime on water content of evaporites and other mineral species, behavior of brine inclusions in salt, and evolution of the gas/liquid brine/salt system.

  18. Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics

    Broader source: Energy.gov [DOE]

    The report addresses granular salt reconsolidation from three vantage points: laboratory testing, modeling, and petrofabrics.

  19. Salt tectonics and structural styles in the deep-water province of the Cabo Frio Region, Rio de Janeiro, Brazil

    SciTech Connect (OSTI)

    Mohriak, W.U.; Macedo, J.M.; Castellani, R.T.

    1996-12-31

    The Cabo Frio region, offshore Rio de Janeiro, lies between two of the most prolific Brazilian oil provinces, the Campos and Santos basins. Major geologic features have been identified using a multidisciplinary approach integrating seismic, gravity, petrographic, and borehole data. The Cabo Frio frontier region is characterized by marked changes in stratigraphy and structural style and is unique among the Brazilian marginal basins. Major geologic features include the deflection of the coastline and pre-Aptian hings line from northeast to east; a large east-striking offshore graben related to salt tectonics; a northwest-trending lineament extending from oceanic crust to the continent; basement-involved landward-dipping (antithetic) normal faults in shallow water; a stable platform in the southern Campos Basin; a thick sequence of postbreakup intrusive and extrusive rocks; and, near the Santos Basin, a mobilized sequence of deep-water postrift strata affected by landward-dipping listric normal faults. These faults are unusual in salt-related passive margins in that they dip landward, apparently detach on the Aptian salt, and show large late Tertiary offsets. Locally, the older sequences do not show substantial growth in the downthrown blocks. South of the Rio de Janeiro coast, a phenomenal landward-dipping fault system detaches blocks of the Albian platform to the north and, to the south, coincides with the depositional limit of the Albian platform. Two end-member processes of salt tectonics in the Cabo Frio region result in either synthetic or antithetic basal shear along the fault weld under the overburden: (1) thin-skinned processes, in which the listric faults were caused by salt flow in response to gravity forces related to massive clastic progradation from the continent; and (2) thick-skinned processes, in which faulting was indirectly triggered by diastrophic causes or disequilibrium in the basement topography.

  20. Thermophysical properties of reconsolidating crushed salt.

    SciTech Connect (OSTI)

    Bauer, Stephen J.; Urquhart, Alexander

    2014-03-01

    Reconsolidated crushed salt is being considered as a backfilling material placed upon nuclear waste within a salt repository environment. In-depth knowledge of thermal and mechanical properties of the crushed salt as it reconsolidates is critical to thermal/mechanical modeling of the reconsolidation process. An experimental study was completed to quantitatively evaluate the thermal conductivity of reconsolidated crushed salt as a function of porosity and temperature. The crushed salt for this study came from the Waste Isolation Pilot Plant (WIPP). In this work the thermal conductivity of crushed salt with porosity ranging from 1% to 40% was determined from room temperature up to 300oC, using two different experimental methods. Thermal properties (including thermal conductivity, thermal diffusivity and specific heat) of single-crystal salt were determined for the same temperature range. The salt was observed to dewater during heating; weight loss from the dewatering was quantified. The thermal conductivity of reconsolidated crushed salt decreases with increasing porosity; conversely, thermal conductivity increases as the salt consolidates. The thermal conductivity of reconsolidated crushed salt for a given porosity decreases with increasing temperature. A simple mixture theory model is presented to predict and compare to the data developed in this study.

  1. Identifying suitable "piercement" salt domes for nuclear waste storage sites

    SciTech Connect (OSTI)

    Kehle, R.

    1980-08-01

    Piercement salt domes of the northern interior salt basins of the Gulf of Mexico are being considered as permanent storage sites for both nuclear and chemically toxic wastes. The suitable domes are stable and inactive, having reached their final evolutionary configuration at least 30 million years ago. They are buried to depths far below the level to which erosion will penetrate during the prescribed storage period and are not subject to possible future reactivation. The salt cores of these domes are themselves impermeable, permitting neither the entry nor exit of ground water or other unwanted materials. In part, a stable dome may be recognized by its present geometric configuration, but conclusive proof depends on establishing its evolutionary state. The evolutionary state of a dome is obtained by reconstructing the growth history of the dome as revealed by the configuration of sedimentary strata in a large area (commonly 3,000 square miles or more) surrounding the dome. A high quality, multifold CDP reflection seismic profile across a candidate dome will provide much of the necessary information when integrated with available subsurface control. Additional seismic profiles may be required to confirm an apparent configuration of the surrounding strata and an interpreted evolutionary history. High frequency seismic data collected in the near vicinity of a dome are also needed as a supplement to the CDP data to permit accurate depiction of the configuration of shallow strata. Such data must be tied to shallow drill hole control to confirm the geologic age at which dome growth ceased. If it is determined that a dome reached a terminal configuration many millions of years ago, such a dome is incapable of reactivation and thus constitutes a stable storage site for nuclear wastes.

  2. Granular Salt Summary: Reconsolidation Principles and Applications

    SciTech Connect (OSTI)

    Hansen, Frank; Popp, Till; Wieczorek, Klaus; Stuehrenberg, Dieter

    2014-07-01

    The purposes of this paper are to review the vast amount of knowledge concerning crushed salt reconsolidation and its attendant hydraulic properties (i.e., its capability for fluid or gas transport) and to provide a sufficient basis to understand reconsolidation and healing rates under repository conditions. Topics covered include: deformation mechanisms and hydro-mechanical interactions during reconsolidation; the experimental data base pertaining to crushed salt reconsolidation; transport properties of consolidating granulated salt and provides quantitative substantiation of its evolution to characteristics emulating undisturbed rock salt; and extension of microscopic and laboratory observations and data to the applicable field scale.

  3. Electrolytic orthoborate salts for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles Austen; Xu, Wu

    2008-01-01

    Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

  4. Electrolytic orthoborate salts for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles Austen [Mesa, AZ; Xu, Wu [Tempe, AZ

    2009-05-05

    Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

  5. SEPARATION OF INORGANIC SALTS FROM ORGANIC SOLUTIONS

    DOE Patents [OSTI]

    Katzin, L.I.; Sullivan, J.C.

    1958-06-24

    A process is described for recovering the nitrates of uranium and plutonium from solution in oxygen-containing organic solvents such as ketones or ethers. The solution of such salts dissolved in an oxygen-containing organic compound is contacted with an ion exchange resin whereby sorption of the entire salt on the resin takes place and then the salt-depleted liquid and the resin are separated from each other. The reaction seems to be based on an anion formation of the entire salt by complexing with the anion of the resin. Strong base or quaternary ammonium type resins can be used successfully in this process.

  6. Remediated Nitrate Salt Drums Safety Update

    Broader source: Energy.gov [DOE]

    At the March 9, 2016 Combined Committee Meeting Mr. Nickless, Environmental Management Los Alamos, Provided a presentation on the status of the Nitrate Salt waste at Los Alamos.

  7. Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity

    SciTech Connect (OSTI)

    West, J. Palmer; Hwu, Shiou-Jyh

    2012-11-15

    The synthesis and structural features of a newly emerged class of salt-inclusion solids (SISs) are reviewed. The descriptive chemistry with respect to the role of ionic salt and its correlation with bulk noncentrosymmetricity and polarity of the covalent oxide lattice in question is discussed by means of structure analysis. These unprecedented discoveries have opened doors to novel materials synthesis via the utilities of salt-inclusion chemistry (SIC) that are otherwise known as the molten-salt approach. The result of these investigations prove that the bulk acentricity, or cancellation of which, can be accounted for from the perspective of ionic and/or salt lattices. Highlights: Black-Right-Pointing-Pointer Synthesis and structure of newly emerged salt-inclusion solids are reviewed. Black-Right-Pointing-Pointer Salt lattice and its symmetry correlation with polar framework are discussed. Black-Right-Pointing-Pointer Preservation of acentricity is accounted for from the perspective of ionic and salt lattices.

  8. Savannah River Site - Salt Waste Processing Facility: Briefing on the Salt

    Energy Savers [EERE]

    Waste Processing Facility Independent Technical Review | Department of Energy Facility: Briefing on the Salt Waste Processing Facility Independent Technical Review Savannah River Site - Salt Waste Processing Facility: Briefing on the Salt Waste Processing Facility Independent Technical Review This is a presentation outlining the Salt Waste Processing Facility process, major risks, approach for conducting reviews, discussion of the findings, and conclusions. PDF icon Savannah River Site -

  9. Denver Basin Map | Open Energy Information

    Open Energy Info (EERE)

    Basin Map Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Denver Basin Map Abstract This webpage contains a map of the Denver Basin. Published Colorado...

  10. Metal salt catalysts for enhancing hydrogen spillover

    DOE Patents [OSTI]

    Yang, Ralph T; Wang, Yuhe

    2013-04-23

    A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

  11. Nitrate Salt Surrogate Blending Scoping Test Plan

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    Test blending equipment identified in the “Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing”. Determine if the equipment will provide adequate mixing of zeolite and surrogate salt/Swheat stream; optimize equipment type and operational sequencing; impact of baffles and inserts on mixing performance; and means of validating mixing performance

  12. Solar Policy Environment: Salt Lake

    Broader source: Energy.gov [DOE]

    The overall objective of the “Solar Salt Lake” (SSL) team is to develop a fully-scoped city and county-level implementation plan that will facilitate at least an additional ten megawatts of solar photovoltaic (PV) installations in the government, commercial, industrial, and residential sectors by 2015. To achieve this aggressive goal, the program strategy includes a combination of barrier identification, research, and policy analysis that utilizes the input of various stakeholders. Coupled with these activities will be the development and implementation of pilot installations in the government and residential sectors, and broad outreach to builders and potential practitioners of solar energy products in the process. In this way, while creating mechanisms to enable a demand for solar, SSL will also facilitate capacity building for suppliers, thereby helping to ensure long-term sustainability for the regional market.

  13. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect (OSTI)

    Ernest A. Mancini

    2006-07-31

    The principal research effort for Year 1 of Phase 2 (Concept Demonstration) of the project is Smackover petroleum system characterization and modeling. The necessary software applications are in the process of being acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.

  14. Basin Analysis and Petroleum System Characterization and Modelling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect (OSTI)

    Ernest A. Mancini

    2006-09-30

    The principal research effort for Year 1 of Phase 2 (Concept Demonstration) of the project is Smackover petroleum system characterization and modeling. The necessary software applications have been acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.

  15. Basin Analysis and Petroleum System Characterization and Modeling, Interior Salt Basins, Central and Eastern Gulf of Mexico

    SciTech Connect (OSTI)

    Ernest A. Mancini

    2006-12-31

    The principal research effort for Year 1 of Phase 2 (Concept Demonstration) of the project is Smackover petroleum system characterization and modeling. The necessary software applications have been acquired to accomplish this work. No major problems have been encountered to date, and the project is on schedule.

  16. Fifteenmile Basin Habitat Enhancement Project: Annual Report...

    Office of Scientific and Technical Information (OSTI)

    wild winter steelhead in the Fifteenmile Creek Basin under the Columbia River Basin Fish and Wildlife Program. The project is funded by through the Bonneville Power...

  17. Sediment Basin Flume | Open Energy Information

    Open Energy Info (EERE)

    Sediment Basin Flume Jump to: navigation, search Basic Specifications Facility Name Sediment Basin Flume Overseeing Organization University of Iowa Hydrodynamic Testing Facility...

  18. Great Basin Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Great Basin Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Great Basin Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3...

  19. Evaluation of Salt Coolants for Reactor Applications

    SciTech Connect (OSTI)

    Williams, David F

    2008-01-01

    Molten fluorides were initially developed for use in the nuclear industry as the high-temperature fluid fuel for the Molten Salt Reactor (MSR). The U.S. Department of Energy Office of Nuclear Energy is exploring the use of molten salts as primary and secondary coolants in a new generation of solid-fueled, thermal-spectrum, hightemperature reactors. This paper provides a review of relevant properties for use in evaluation and ranking of salt coolants for high-temperature reactors. Nuclear, physical, and chemical properties were reviewed, and metrics for evaluation are recommended. Chemical properties of the salt were examined to identify factors that affect materials compatibility (i.e., corrosion). Some preliminary consideration of economic factors for the candidate salts is also presented.

  20. SEPARATION OF METAL SALTS BY ADSORPTION

    DOE Patents [OSTI]

    Gruen, D.M.

    1959-01-20

    It has been found that certain metal salts, particularly the halides of iron, cobalt, nickel, and the actinide metals, arc readily absorbed on aluminum oxide, while certain other salts, particularly rare earth metal halides, are not so absorbed. Use is made of this discovery to separate uranium from the rare earths. The metal salts are first dissolved in a molten mixture of alkali metal nitrates, e.g., the eutectic mixture of lithium nitrate and potassium nitrate, and then the molten salt solution is contacted with alumina, either by slurrying or by passing the salt solution through an absorption tower. The process is particularly valuable for the separation of actinides from lanthanum-group rare earths.

  1. DOE - Office of Legacy Management -- Tatum Salt Dome Test Site...

    Office of Legacy Management (LM)

    Tatum Salt Dome Test Site - MS 01 FUSRAP Considered Sites Site: Tatum Salt Dome Test Site (MS.01) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site ...

  2. EIA - Natural Gas Pipeline Network - Salt Cavern Storage Reservoir...

    U.S. Energy Information Administration (EIA) Indexed Site

    Salt Cavern Underground Natural Gas Storage Reservoir Configuration Salt Cavern Underground Natural Gas Storage Reservoir Configuration Source: PB Energy Storage Services Inc.

  3. BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy...

    Open Energy Info (EERE)

    Ormat Technologies Salt Wells Geothermal Energy Project Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: BLM Fact Sheet- Ormat Technologies Salt Wells...

  4. Isotopic Analysis- Fluid At Salt Wells Area (Shevenell & Garside...

    Open Energy Info (EERE)

    At Salt Wells Area (Shevenell & Garside, 2003) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 2002 -...

  5. Compound and Elemental Analysis At Salt Wells Area (Shevenell...

    Open Energy Info (EERE)

    At Salt Wells Area (Shevenell & Garside, 2003) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Compound and Elemental Analysis Activity Date...

  6. Conceptual Model At Salt Wells Area (Faulds, Et Al., 2011) |...

    Open Energy Info (EERE)

    At Salt Wells Area (Faulds, Et Al., 2011) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Conceptual Model Activity Date 2011 Usefulness...

  7. Remediated Nitrate Salt Drums Storage at Los Alamos National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory As a part of its national security ...

  8. Geothermal Literature Review At Salt Wells Area (Faulds, Et Al...

    Open Energy Info (EERE)

    Salt Wells Area (Faulds, Et Al., 2011) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermal Literature Review At Salt Wells Area (Faulds,...

  9. Independent Oversight Review, Savannah River Site Salt Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 2013 Independent Oversight Review, Savannah River Site Salt Waste Processing Facility - August 2013 August 2013 Review of the Savannah River Site Salt Waste Processing...

  10. Sandia Energy - Molten Nitrate Salt Initial Flow Testing is a...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitrate Salt Initial Flow Testing is a Tremendous Success Home Renewable Energy News Concentrating Solar Power Solar Molten Nitrate Salt Initial Flow Testing is a Tremendous...

  11. Magnetotellurics At Salt Wells Area (Bureau of Land Management...

    Open Energy Info (EERE)

    Salt Wells Area (Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Magnetotellurics At Salt Wells Area (Bureau of...

  12. Salt Lake City, Utah: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Salt Lake City, Utah: Energy Resources (Redirected from Salt Lake City, UT) Jump to: navigation, search Equivalent URI DBpedia Coordinates 40.7607793, -111.8910474 Show Map...

  13. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container...

    Office of Environmental Management (EM)

    Nitrate Salt Bearing Waste Container Isolation Plan Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container Isolation Plan The purpose of this document is to provide the ...

  14. Savannah River Site Salt Waste Processing Facility Technology...

    Office of Environmental Management (EM)

    Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report ... of Energy Washington, D.C. SRS Salt Waste Processing Facility Technology Readiness ...

  15. Development of Molten-Salt Heat Trasfer Fluid Technology for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar ...

  16. Novel Molten Salts Thermal Energy Storage for Concentrating Solar...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation This presentation ...

  17. Molten salt heat transfer fluids and thermal storage technology...

    Office of Scientific and Technical Information (OSTI)

    Molten salt heat transfer fluids and thermal storage technology. Citation Details In-Document Search Title: Molten salt heat transfer fluids and thermal storage technology. No ...

  18. Liquid Salt Heat Exchanger Technology for VHTR Based Applications...

    Office of Scientific and Technical Information (OSTI)

    Liquid Salt Heat Exchanger Technology for VHTR Based Applications Citation Details In-Document Search Title: Liquid Salt Heat Exchanger Technology for VHTR Based Applications The ...

  19. Voluntary Protection Program Onsite Review, Parsons Corp., Salt...

    Office of Environmental Management (EM)

    Corp., Salt Waste Processing Facility Construction Project - May 2014 Voluntary Protection Program Onsite Review, Parsons Corp., Salt Waste Processing Facility Construction Project...

  20. DOE - Office of Legacy Management -- Penn Salt Manufacturing...

    Office of Legacy Management (LM)

    Salt Manufacturing Co Whitemarsh Research Laboratories - PA 20 FUSRAP Considered Sites Site: PENN SALT MANUFACTURING CO., WHITEMARSH RESEARCH LABORATORIES (PA.20) Eliminated from...

  1. Salt Lake County, Utah: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Creek Valley, Utah Magna, Utah Midvale, Utah Millcreek, Utah Mount Olympus, Utah Murray, Utah Riverton, Utah Salt Lake City, Utah Sandy, Utah South Jordan, Utah South Salt...

  2. Sandia Energy - Customer Interface Document for the Molten Salt...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Customer Interface Document for the Molten Salt Test Loop at the NSTTF Home Partnership News News & Events Publications Customer Interface Document for the Molten Salt Test Loop at...

  3. Sandia Energy - Molten Salt Test Loop Pump Installed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Energy News Concentrating Solar Power Solar Energy Storage Systems Molten Salt Test Loop Pump Installed Previous Next Molten Salt Test Loop Pump Installed The pump was...

  4. Salt Waste Processing Facility, Construction Turnover to Testing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Salt Waste Processing Facility, Construction Turnover to Testing and Commissioning Oversight This procedure establishes an oversight process for the Salt Waste Processing Facility ...

  5. Salt Waste Processing Facility, Line Management Review Board...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Line Management Review Board Charter Salt Waste Processing Facility, Line Management ... processes and associated deliverables for the Salt Waste Processing Facility (SWPF). ...

  6. The Salt Defense Disposal Investigations (SDDI)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Salt Defense Disposal Investigations (SDDI) will utilize a newly mined Underground Research Lab (URL) in WIPP to perform a cost effective, proof-of-principle feld test of the emplacement of heat-generating radioactive waste and validate modeling efforts. The goals of the SDDI Thermal Test are to: * Demonstrate a proof-of-principle concept for in-drift disposal in salt. * Investigate, in a specifc emplacement concept, the response of the salt to heat. * Develop a full-scale response for run-of-

  7. Examination of Liquid Fluoride Salt Heat Transfer

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L

    2014-01-01

    The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

  8. Molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, W.A.; Upadhye, R.S.; Pruneda, C.O.

    1995-07-18

    A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor. 4 figs.

  9. Molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, William A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA); Pruneda, Cesar O. (Livermore, CA)

    1995-01-01

    A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor.

  10. Salt Selection for the LS-VHTR

    SciTech Connect (OSTI)

    Williams, D.F.; Clarno, K.T.

    2006-07-01

    Molten fluorides were initially developed for use in the nuclear industry as the high temperature fluid-fuel for a Molten Salt Reactor (MSR). The Office of Nuclear Energy is exploring the use of molten fluorides as a primary coolant (rather than helium) in an Advanced High Temperature Reactor (AHTR) design, also know as the Liquid-Salt cooled Very High Temperature Reactor (LS-VHTR). This paper provides a review of relevant properties for use in evaluation and ranking of candidate coolants for the LS-VHTR. Nuclear, physical, and chemical properties were reviewed and metrics for evaluation are recommended. Chemical properties of the salt were examined for the purpose of identifying factors that effect materials compatibility (i.e., corrosion). Some preliminary consideration of economic factors for the candidate salts is also presented. (authors)

  11. Liquid salt environment stress-rupture testing

    DOE Patents [OSTI]

    Ren, Weiju; Holcomb, David E.; Muralidharan, Govindarajan; Wilson, Dane F.

    2016-03-22

    Disclosed herein are systems, devices and methods for stress-rupture testing selected materials within a high-temperature liquid salt environment. Exemplary testing systems include a load train for holding a test specimen within a heated inert gas vessel. A thermal break included in the load train can thermally insulate a load cell positioned along the load train within the inert gas vessel. The test specimen can include a cylindrical gage portion having an internal void filled with a molten salt during stress-rupture testing. The gage portion can have an inner surface area to volume ratio of greater than 20 to maximize the corrosive effect of the molten salt on the specimen material during testing. Also disclosed are methods of making a salt ingot for placement within the test specimen.

  12. Salt Lake City- High Performance Buildings Requirement

    Broader source: Energy.gov [DOE]

    Salt Lake City's mayor issued an executive order in July 2005 requiring that all public buildings owned and controlled by the city be built or renovated to meet the requirements of LEED "silver"...

  13. Director, Salt Waste Processing Facility Project Office

    Broader source: Energy.gov [DOE]

    This position is located within The Department of Energy (DOE) Savannah River (SR) Operations Office, Salt Waste Processing Facility Project Office (SWPFPO). SR is located in Aiken, South Carolina....

  14. Structural framework, stratigraphy, and evolution of Brazilian marginal basins

    SciTech Connect (OSTI)

    Ojeda, H.A.O.

    1982-06-01

    The structural framework of the Brazilian continental margin is basically composed of eight structural types: antithetic tilted step-fault blocks, synthetic untilted step-fault blocks, structural inversion axes, hinges with compensation grabens, homoclinal structures, growth faults with rollovers, diapirs, and igneous structures. The antithetic tilted and synthetic untilted step-fault blocks are considered as synchronous, complementary structural systems, separated by an inversion axis. Two evaporitic cycles (Paripueira and Ibura) were differentiated in the Sergipe-Alagoas type basin and tentatively correlated to the evaporitic section of other Brazilian marginal basis. Four phases are considered in the evolution of the Brazilian marginal basins: pre-rift, rift, transitional, and drift. During the pre-rift phase (Late Jurassic-Early Cretaceous), continental sediments were deposited in peripheral intracratonic basins. In the rift phase (Early Cretaceous), the breakup of the continental crust of the Gondwana continent gave rise to a central graben and rift valleys where lacustrine sediments were deposited. The transitional phase (Aptian) developed under relative tectonic stability, when evaporitic and clastic lacustrine sequences were being deposited. In the drift phase (Albian to Holocene), a regionl homoclinal structure developed, consisting of two distinct sedimentary sequences, a lower clastic-carbonate and an upper clastic. From the Albian to the Holocene Epoch, structures associated to plastic displacement of salt or shale developed in many Brazilian marginal basins. Two phases of major igneous activity occurred: one in the Early Cretaceous associated with the rift phase of the Gondwana continent, and the other in the Tertiary during the migration phase of the South American and African plates.

  15. Ethylenediamine salt of 5-nitrotetrazole and preparation

    DOE Patents [OSTI]

    Lee, Kien-yin; Coburn, Michael D.

    1985-01-01

    Ethylenediamine salt of 5-nitrotetrazole and preparation. This salt has been found to be useful as an explosive alone and in eutectic mixtures with ammonium nitrate and/or other explosive compounds. Its eutectic with ammonium nitrate has been demonstrated to behave in a similar manner to a monomolecular explosive such as TNT, and is less sensitive than the pure salt. Moreover, this eutectic mixture, which contains 87.8 mol % of ammonium nitrate, is close to the CO.sub.2 -balanced composition of 90 mol %, and has a relatively low melting point of 110.5 C. making it readily castable. The ternary eutectic system containing the ethylenediamine salt of 5-nitrotetrazole, ammonium nitrate and ethylenediamine dinitrate has a eutectic temperature of 89.5 C. and gives a measured detonation pressure of 24.8 GPa, which is 97.6% of the calculated value. Both the pure ethylenediamine salt and its known eutectic compounds behave in substantially ideal manner. Methods for the preparation of the salt are described.

  16. Thermal Characterization of Molten Salt Systems

    SciTech Connect (OSTI)

    Toni Y. Gutknecht; Guy L. Fredrickson

    2011-09-01

    The phase stability of molten salts in an electrorefiner (ER) may be adversely affected by the buildup of sodium, fission products, and transuranics in the electrolyte. Potential situations that need to be avoided are the following: (1) salt freezing due to an unexpected change in the liquidus temperature, (2) phase separation or non-homogeneity of the molten salt due to the precipitation of solids or formation of immiscible liquids, and (3) any mechanism that can result in the separation and concentration of fissile elements from the molten salt. Any of these situations would result in an off-normal condition outside the established safety basis for electrorefiner (ER) operations. The stability (and homogeneity) of the phases can potentially be monitored through the thermal characterization of the salts, which can be a function of impurity concentration. This report describes the experimental results of typical salts compositions, which consist of chlorides of potassium, lithium, strontium, samarium, praseodymium, lanthanum, barium, cerium, cesium, neodymium, sodium and gadolinium chlorides as a surrogate for both uranium and plutonium, used for the processing of used nuclear fuels.

  17. Salt Wells Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    by Gary Edmondo (MiniGIS, Inc., Reno, NV)24 modified by the Great Basin Center for Geothermal Energy to include symbols for geothermal surface features was used to actively...

  18. Savannah River Site - Salt Waste Processing Facility Independent Technical

    Energy Savers [EERE]

    Review | Department of Energy Facility Independent Technical Review Savannah River Site - Salt Waste Processing Facility Independent Technical Review Full Document and Summary Versions are available for download PDF icon Savannah River Site - Salt Waste Processing Facility Independent Technical Review PDF icon Summary - Salt Waste Processing Facility Design at the Savannah River Site More Documents & Publications Savannah River Site - Salt Waste Processing Facility: Briefing on the Salt

  19. Low temperature oxidation using support molten salt catalysts

    DOE Patents [OSTI]

    Weimer, Alan W.; Czerpak, Peter J.; Hilbert, Patrick M.

    2003-05-20

    Molten salt reactions are performed by supporting the molten salt on a particulate support and forming a fluidized bed of the supported salt particles. The method is particularly suitable for combusting hydrocarbon fuels at reduced temperatures, so that the formation NO.sub.x species is reduced. When certain preferred salts are used, such as alkali metal carbonates, sulfur and halide species can be captured by the molten salt, thereby reducing SO.sub.x and HCl emissions.

  20. Liquid fuel molten salt reactors for thorium utilization (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Journal Article: Liquid fuel molten salt reactors for thorium utilization Citation Details In-Document Search This content will become publicly available on April 8, 2017 Title: Liquid fuel molten salt reactors for thorium utilization Molten salt reactors (MSRs) represent a class of reactors that use liquid salt, usually fluoride- or chloride-based, as either a coolant with a solid fuel (such as fluoride salt-cooled high temperature reactors) or as a combined coolant and

  1. Chemistry control and corrosion mitigation of heat transfer salts for the fluoride salt reactor (FHR)

    SciTech Connect (OSTI)

    Kelleher, B. C.; Sellers, S. R.; Anderson, M. H.; Sridharan, K.; Scheele, R. D.

    2012-07-01

    The Molten Salt Reactor Experiment (MSRE) was a prototype nuclear reactor which operated from 1965 to 1969 at Oak Ridge National Laboratory. The MSRE used liquid fluoride salts as a heat transfer fluid and solvent for fluoride based {sup 235}U and {sup 233}U fuel. Extensive research was performed in order to optimize the removal of oxide and metal impurities from the reactor's heat transfer salt, 2LiF-BeF{sub 2} (FLiBe). This was done by sparging a mixture of anhydrous hydrofluoric acid and hydrogen gas through the FLiBe at elevated temperatures. The hydrofluoric acid reacted with oxides and hydroxides, fluorinating them while simultaneously releasing water vapor. Metal impurities such as iron and chromium were reduced by hydrogen gas and filtered out of the salt. By removing these impurities, the corrosion of reactor components was minimized. The Univ. of Wisconsin - Madison is currently researching a new chemical purification process for fluoride salts that make use of a less dangerous cleaning gas, nitrogen trifluoride. Nitrogen trifluoride has been predicted as a superior fluorinating agent for fluoride salts. These purified salts will subsequently be used for static and loop corrosion tests on a variety of reactor materials to ensure materials compatibility for the new FHR designs. Demonstration of chemistry control methodologies along with potential reduction in corrosion is essential for the use of a fluoride salts in a next generator nuclear reactor system. (authors)

  2. Characterization of the molten salt reactor experiment fuel and flush salts

    SciTech Connect (OSTI)

    Williams, D.F.; Peretz, F.J.

    1996-05-01

    Wise decisions about the handling and disposition of spent fuel from the Molten Salt Reactor Experiment (MSRE) must be based upon an understanding of the physical, chemical, and radiological properties of the frozen fuel and flush salts. These {open_quotes}static{close_quotes} properties can be inferred from the extensive documentation of process history maintained during reactor operation and the knowledge gained in laboratory development studies. Just as important as the description of the salt itself is an understanding of the dynamic processes which continue to transform the salt composition and govern its present and potential physicochemical behavior. A complete characterization must include a phenomenological characterization in addition to the typical summary of properties. This paper reports on the current state of characterization of the fuel and flush salts needed to support waste management decisions.

  3. Stormwater detention basin sediment removal

    SciTech Connect (OSTI)

    Gross, W.E.

    1995-12-31

    In the past, stormwater runoff from landfills has been treated mainly by focusing on reducing the peak storm discharge rates so as not to hydraulically impact downstream subsheds. However, with the advent of stricter water quality regulations based on the Federal Clean Water Act, and the related NPDES and SPDES programs, landfill owners and operators are now legally responsible for the water quality of the runoff once it leaves the landfill site. At the Fresh Kills Landfill in New York City, the world`s largest covering over 2000 acres, landfilling activities have been underway since 1945. With the main objective at all older landfill sites having focused on maximizing the available landfill footprint in order to obtain the most possible airspace volume, consideration was not given for the future siting of stormwater basin structures. Therefore, when SCS Engineers began developing the first comprehensive stormwater management plan for the site, the primary task was to locate potential sites for all the stormwater basins in order to comply with state regulations for peak stormwater runoff control. The basins were mostly constructed where space allowed, and were sized to be as large as possible given siting and subshed area constraints. Seventeen stormwater basins have now been designed and are being constructed to control the peak stormwater runoff for the 25-year, 24-hour storm as required by New York State. As an additional factor of safety, the basins were also designed for controlled discharge of the 100-year, 24 hour storm.

  4. Corrosion of aluminides by molten nitrate salt

    SciTech Connect (OSTI)

    Tortorelli, P.F.; Bishop, P.S.

    1990-01-01

    The corrosion of titanium-, iron-, and nickel-based aluminides by a highly aggressive, oxidizing NaNO{sub 3}(-KNO{sub 3})-Na{sub 2}O{sub 2} has been studied at 650{degree}C. It was shown that weight changes could be used to effectively evaluate corrosion behavior in the subject nitrate salt environments provided these data were combined with salt analyses and microstructural examinations. The studies indicated that the corrosion of relatively resistant aluminides by these nitrate salts proceeded by oxidation and a slow release from an aluminum-rich product layer into the salt at rates lower than that associated with many other types of metallic materials. The overall corrosion process and resulting rate depended on the particular aluminide being exposed. In order to minimize corrosion of nickel or iron aluminides, it was necessary to have aluminum concentrations in excess of 30 at. %. However, even at a concentration of 50 at. % Al, the corrosion resistance of TiAl was inferior to that of Ni{sub 3}Al and Fe{sub 3}Al. At higher aluminum concentrations, iron, nickel, and iron-nickel aluminides exhibited quite similar weight changes, indicative of the principal role of aluminum in controlling the corrosion process in NaNO{sub 3}(-KNO{sub 3})-Na{sub 2}O{sub 2} salts. 20 refs., 5 figs., 3 tabs.

  5. Ethylenediamine salt of 5-nitrotetrazole and preparation

    DOE Patents [OSTI]

    Lee, K.; Coburn, M.D.

    1984-05-17

    The ethylenediamine salt of 5-nitrotetrazole has been found to be useful as an explosive alone and in eutectic mixtures with ammonium nitrate and/or other explosive compounds. Its eutectic with ammonium nitrate has been demonstrated to behave in a similar manner to a monomolecular explosive such as TNT, and is less sensitive than the pure salt. Moreover, this eutectic mixture, which contains 87.8 mol% of ammonium nitrate, is close to the CO/sub 2/-balanced composition of 90 mol%, and has a relatively low melting point of 110.5 C making it readily castable. The ternary eutectic system containing the ethylenediamine salt of 5-nitrotetrazole, ammonium nitrate and ethylenediamine dinitrate has a eutectic temperature of 89.5 C and gives a measured detonation pressure of 24.8 GPa, which is 97.6% of the calculated value. Both the pure ethylenediamine salt and its known eutectic compounds behave in substantially ideal manner. Methods for the preparation of the salt are described.

  6. Regional hydrology of the Green River-Moab area, northwestern Paradox Basin, Utah

    SciTech Connect (OSTI)

    Rush, F.E.; Whitfield, M.S.; Hart, I.M.

    1982-12-01

    The Green River-Moab area encompasses about 7800 square kilometers or about 25% of the Paradox basin. The entire Paradox basin is a part of the Colorado Plateaus that is underlain by a thick sequence of evaporite (salt) beds of Pennsylvanian age. The rock units that underlie the area have been grouped into hydrogeologic units based on their water-transmitting ability. Confining beds consist of evaporite beds of mostly salt, and overlying and underlying thick sequences of rocks with minimal permeability; above and below these confining beds are aquifers. The upper Mesozoic sandstone aquifer, probably is the most permeable hydrogeologic unit of the area and is the subject of this investigation. The principal component of groundwater outflow from this aquifer probably is subsurface flow to regional streams (the Green and Colorado Rivers) and is about 100 million cubic meters per year. All other components of outflow are relatively small. The average annual recharge to the aquifer is about 130 million cubic meters, of which about 20 million cubic meters is from local precipitation. For the lower aquifer, all recharge and discharge probably is by subsurface flow and was not estimated. The aquifers are generally isolated from the evaporite beds by the bounding confining beds; as a result, most ground water has little if any contact with the evaporites. Brines are present in the confining beds, but solution of beds of salt probably is very slow in most parts of the area. No brine discharges have been identified.

  7. EA-64 Basin Electric Power Cooperative | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Basin Electric Power Cooperative EA-64 Basin Electric Power Cooperative Order authorizing Basin Electric Power Cooperative to export electric energy to Canada PDF icon EA-64 Basin Electric Power Cooperative More Documents & Publications EA-64-A

  8. EA-64-A Basin Electric Power Cooperative | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    -A Basin Electric Power Cooperative EA-64-A Basin Electric Power Cooperative Order authorizing Basin Electric Power Cooperative to export electric energy to Canada PDF icon EA-64-A Basin Electric Power Cooperative More Documents & Publications EA-64

  9. Brine flow in heated geologic salt.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  10. H-Area Seepage Basins

    SciTech Connect (OSTI)

    Stejskal, G.

    1990-12-01

    During the third quarter of 1990 the wells which make up the H-Area Seepage Basins (H-HWMF) monitoring network were sampled. Laboratory analyses were performed to measure levels of hazardous constituents, indicator parameters, tritium, nonvolatile beta, and gross alpha. A Gas Chromatograph Mass Spectrometer (GCMS) scan was performed on all wells sampled to determine any hazardous organic constituents present in the groundwater. The primary contaminants observed at wells monitoring the H-Area Seepage Basins are tritium, nitrate, mercury, gross alpha, nonvolatile beta, trichloroethylene (TCE), tetrachloroethylene, lead, cadmium, arsenic, and total radium.

  11. Hydrogeochemical Indicators for Great Basin Geothemal Resources

    Broader source: Energy.gov [DOE]

    Hydrogeochemical Indicators for Great Basin Geothemal Resources presentation at the April 2013 peer review meeting held in Denver, Colorado.

  12. High Temperature Fluoride Salt Test Loop

    SciTech Connect (OSTI)

    Aaron, Adam M.; Cunningham, Richard Burns; Fugate, David L.; Holcomb, David Eugene; Kisner, Roger A.; Peretz, Fred J.; Robb, Kevin R.; Wilson, Dane F.; Yoder, Jr, Graydon L.

    2015-12-01

    Effective high-temperature thermal energy exchange and delivery at temperatures over 600°C has the potential of significant impact by reducing both the capital and operating cost of energy conversion and transport systems. It is one of the key technologies necessary for efficient hydrogen production and could potentially enhance efficiencies of high-temperature solar systems. Today, there are no standard commercially available high-performance heat transfer fluids above 600°C. High pressures associated with water and gaseous coolants (such as helium) at elevated temperatures impose limiting design conditions for the materials in most energy systems. Liquid salts offer high-temperature capabilities at low vapor pressures, good heat transport properties, and reasonable costs and are therefore leading candidate fluids for next-generation energy production. Liquid-fluoride-salt-cooled, graphite-moderated reactors, referred to as Fluoride Salt Reactors (FHRs), are specifically designed to exploit the excellent heat transfer properties of liquid fluoride salts while maximizing their thermal efficiency and minimizing cost. The FHR s outstanding heat transfer properties, combined with its fully passive safety, make this reactor the most technologically desirable nuclear power reactor class for next-generation energy production. Multiple FHR designs are presently being considered. These range from the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) [1] design originally developed by UC-Berkeley to the Small Advanced High-Temperature Reactor (SmAHTR) and the large scale FHR both being developed at ORNL [2]. The value of high-temperature, molten-salt-cooled reactors is also recognized internationally, and Czechoslovakia, France, India, and China all have salt-cooled reactor development under way. The liquid salt experiment presently being developed uses the PB-AHTR as its focus. One core design of the PB-AHTR features multiple 20 cm diameter, 3.2 m long fuel channels with 3 cm diameter graphite-based fuel pebbles slowly circulating up through the core. Molten salt coolant (FLiBe) at 700°C flows concurrently (at significantly higher velocity) with the pebbles and is used to remove heat generated in the reactor core (approximately 1280 W/pebble), and supply it to a power conversion system. Refueling equipment continuously sorts spent fuel pebbles and replaces spent or damaged pebbles with fresh fuel. By combining greater or fewer numbers of pebble channel assemblies, multiple reactor designs with varying power levels can be offered. The PB-AHTR design is discussed in detail in Reference [1] and is shown schematically in Fig. 1. Fig. 1. PB-AHTR concept (drawing taken from Peterson et al., Design and Development of the Modular PB-AHTR Proceedings of ICApp 08). Pebble behavior within the core is a key issue in proving the viability of this concept. This includes understanding the behavior of the pebbles thermally, hydraulically, and mechanically (quantifying pebble wear characteristics, flow channel wear, etc). The experiment being developed is an initial step in characterizing the pebble behavior under realistic PB-AHTR operating conditions. It focuses on thermal and hydraulic behavior of a static pebble bed using a convective salt loop to provide prototypic fluid conditions to the bed, and a unique inductive heating technique to provide prototypic heating in the pebbles. The facility design is sufficiently versatile to allow a variety of other experimentation to be performed in the future. The facility can accommodate testing of scaled reactor components or sub-components such as flow diodes, salt-to-salt heat exchangers, and improved pump designs as well as testing of refueling equipment, high temperature instrumentation, and other reactor core designs.

  13. K Basins Groundwater Monitoring Task, K Basins Closure Project: Report for July, August, and September 2006

    SciTech Connect (OSTI)

    Peterson, Robert E.

    2006-12-08

    This report provides information on groundwater monitoring at the K Basins during July, August, and September 2006. Conditions remain very similar to those reported in the previous quarterly report, with no evidence in monitoring results to suggest groundwater impact from current loss of basin water to the ground. The K Basins monitoring network will be modified in the coming quarters as a consequence of remedial action at KE Basin, i.e., removal of sludge and basin demolition.

  14. Hybrid Molten Salt Reactor (HMSR) System Study

    SciTech Connect (OSTI)

    Woolley, Robert D; Miller, Laurence F

    2014-04-01

    Can the hybrid system combination of (1) a critical fission Molten Salt Reactor (MSR) having a thermal spectrum and a high Conversion Ratio (CR) with (2) an external source of high energy neutrons provide an attractive solution to the world's expanding demand for energy? The present study indicates the answer is an emphatic yes.

  15. Salt repository project closeout status report

    SciTech Connect (OSTI)

    1988-06-01

    This report provides an overview of the scope and status of the US Department of Energy (DOE`s) Salt Repository Project (SRP) at the time when the project was terminated by the Nuclear Waste Policy Amendments Act of 1987. The report reviews the 10-year program of siting a geologic repository for high-level nuclear waste in rock salt formations. Its purpose is to aid persons interested in the information developed during the course of this effort. Each area is briefly described and the major items of information are noted. This report, the three salt Environmental Assessments, and the Site Characterization Plan are the suggested starting points for any search of the literature and information developed by the program participants. Prior to termination, DOE was preparing to characterize three candidate sites for the first mined geologic repository for the permanent disposal of high-level nuclear waste. The sites were in Nevada, a site in volcanic tuff; Texas, a site in bedded salt (halite); and Washington, a site in basalt. These sites, identified by the screening process described in Chapter 3, were selected from the nine potentially acceptable sites shown on Figure I-1. These sites were identified in accordance with provisions of the Nuclear Waste Policy Act of 1982. 196 refs., 21 figs., 11 tabs.

  16. Accelerators for Subcritical Molten-Salt Reactors

    SciTech Connect (OSTI)

    Johnson, Roland

    2011-08-03

    Accelerator parameters for subcritical reactors have usually been based on using solid nuclear fuel much like that used in all operating critical reactors as well as the thorium burning accelerator-driven energy amplifier proposed by Rubbia et al. An attractive alternative reactor design that used molten salt fuel was experimentally studied at ORNL in the 1960s, where a critical molten salt reactor was successfully operated using enriched U235 or U233 tetrafluoride fuels. These experiments give confidence that an accelerator-driven subcritical molten salt reactor will work better than conventional reactors, having better efficiency due to their higher operating temperature, having the inherent safety of subcritical operation, and having constant purging of volatile radioactive elements to eliminate their accumulation and potential accidental release in dangerous amounts. Moreover, the requirements to drive a molten salt reactor can be considerably relaxed compared to a solid fuel reactor, especially regarding accelerator reliability and spallation neutron targetry, to the point that much of the required technology exists today. It is proposed that Project-X be developed into a prototype commercial machine to produce energy for the world by, for example, burning thorium in India and nuclear waste from conventional reactors in the USA.

  17. BLM Fact Sheet- Vulcan Power Company Salt Wells Geothermal Energy...

    Open Energy Info (EERE)

    Vulcan Power Company Salt Wells Geothermal Energy Project Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: BLM Fact Sheet- Vulcan Power Company Salt Wells...

  18. File:Salt2.pdf | Open Energy Information

    Open Energy Info (EERE)

    Salt2.pdf Jump to: navigation, search File File history File usage Metadata File:Salt2.pdf Size of this preview: 463 599 pixels. Other resolution: 464 600 pixels. Go to page...

  19. Completing Salt Waste Processing Facility is an EM Priority and...

    Office of Environmental Management (EM)

    Completing Salt Waste Processing Facility is an EM Priority and Key to SRS Cleanup Progress Completing Salt Waste Processing Facility is an EM Priority and Key to SRS Cleanup ...

  20. Development of Molten-Salt Heat Trasfer Fluid Technology for...

    Office of Environmental Management (EM)

    Abengoa Solar Sunshot Conf erence Project Review Development of M olt en-Salt Heat Transf ... generat ion of organic heat t ransport f luids w it h low f reeze point molt en salt s. ...

  1. Energy Efficient Buildings, Salt Lake County, Utah

    SciTech Connect (OSTI)

    Barnett, Kimberly

    2012-04-30

    Executive Summary Salt Lake County's Solar Photovoltaic Project - an unprecedented public/private partnership Salt Lake County is pleased to announce the completion of its unprecedented solar photovoltaic (PV) installation on the Calvin R. Rampton Salt Palace Convention Center. This 1.65 MW installation will be one the largest solar roof top installations in the country and will more than double the current installed solar capacity in the state of Utah. Construction is complete and the system will be operational in May 2012. The County has accomplished this project using a Power Purchase Agreement (PPA) financing model. In a PPA model a third-party solar developer will finance, develop, own, operate, and maintain the solar array. Salt Lake County will lease its roof, and purchase the power from this third-party under a long-term Power Purchase Agreement contract. In fact, this will be one of the first projects in the state of Utah to take advantage of the recent (March 2010) legislation which makes PPA models possible for projects of this type. In addition to utilizing a PPA, this solar project will employ public and private capital, Energy Efficiency and Conservation Block Grants (EECBG), and public/private subsidized bonds that are able to work together efficiently because of the recent stimulus bill. The project also makes use of recent changes to federal tax rules, and the recent re-awakening of private capital markets that make a significant public-private partnership possible. This is an extremely innovative project, and will mark the first time that all of these incentives (EECBG grants, Qualified Energy Conservation Bonds, New Markets tax credits, investment tax credits, public and private funds) have been packaged into one project. All of Salt Lake County's research documents and studies, agreements, and technical information is available to the public. In addition, the County has already shared a variety of information with the public through webinars, site tours, presentations, and written correspondence.

  2. New casing for salt problems ''hot item''

    SciTech Connect (OSTI)

    Rountree, R.

    1983-10-01

    Operators in the Williston Basin indicate interest in the high performance casing, which is designed to resist collapse. Lone Star Steel Co. offers custom designed, high performance casing to withstand high pressures and H/sub 2/S encroachment. A number of companies will continue to evaluate the results of the casing programs that employ high performance pipe with considerable interest.

  3. Molten salt considerations for accelerator-driven subcritical fission to

    Office of Scientific and Technical Information (OSTI)

    close the nuclear fuel cycle (Journal Article) | SciTech Connect Molten salt considerations for accelerator-driven subcritical fission to close the nuclear fuel cycle Citation Details In-Document Search Title: Molten salt considerations for accelerator-driven subcritical fission to close the nuclear fuel cycle The host salt selection, molecular modeling, physical chemistry, and processing chemistry are presented here for an accelerator-driven subcritical fission in a molten salt core

  4. Workplace Charging Challenge Partner: Salt River Project | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Salt River Project Workplace Charging Challenge Partner: Salt River Project Workplace Charging Challenge Partner: Salt River Project Joined the Challenge: December 2014 Headquarters: Tempe, AZ Charging Locations: Phoenix, AZ; Scottsdale, AZ; Tempe, AZ; Tolleson, AZ Domestic Employees: 4,900 The mission of Salt River Project's (SRP) Electric Vehicle Initiative is to encourage greater use of clean energy transportation. Under this program, SRP's headquarters received two Level 2

  5. PROJECT PROFILE: Salt Lake City Corporation (Solar Market Pathways) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Salt Lake City Corporation (Solar Market Pathways) PROJECT PROFILE: Salt Lake City Corporation (Solar Market Pathways) Title: Wasatch Solar Project WASATCH solar logo.png Funding Opportunity: Solar Market Pathways SunShot Subprogram: Soft Costs Location: Salt Lake City, UT Amount Awarded: $600,000 Awardee Cost Share: $164,645 Salt Lake City and its partners are developing a comprehensive long-term solar deployment strategy, which includes an analysis of the value of

  6. Savannah River Site Salt Waste Processing Facility Technology Readiness

    Energy Savers [EERE]

    Assessment Report | Department of Energy Salt Waste Processing Facility Technology Readiness Assessment Report Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report Full Document and Summary Versions are available for download PDF icon Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report PDF icon Summary - SRS Salt Waste Processing Facility More Documents & Publications Compilation of TRA Summaries Basis for Section

  7. Method for preparing salt solutions having desired properties

    DOE Patents [OSTI]

    Ally, Moonis R.; Braunstein, Jerry

    1994-01-01

    The specification discloses a method for preparing salt solutions which exhibit desired thermodynamic properties. The method enables prediction of the value of the thermodynamic properties for single and multiple salt solutions over a wide range of conditions from activity data and constants which are independent of concentration and temperature. A particular application of the invention is in the control of salt solutions in a process to provide a salt solution which exhibits the desired properties.

  8. Liquid Fluoride Salt Experimentation Using a Small Natural Circulation Cell

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Liquid Fluoride Salt Experimentation Using a Small Natural Circulation Cell Citation Details In-Document Search Title: Liquid Fluoride Salt Experimentation Using a Small Natural Circulation Cell A small molten fluoride salt experiment has been constructed and tested to develop experimental techniques for application in liquid fluoride salt systems. There were five major objectives in developing this test

  9. Combinations of fluorinated solvents with imide salts or methide salts for electrolytes

    DOE Patents [OSTI]

    Tikhonov, Konstantin; Yip, Ka Ki; Lin, Tzu-Yuan; Lei, Norman; Guerrero-Zavala, Guillermo; Kwong, Kristie W

    2015-11-10

    Provided are electrochemical cells and electrolytes used to build such cells. The electrolytes include imide salts and/or methide salts as well as fluorinated solvents capable of maintaining single phase solutions at between about -30.degree. C. to about 80.degree. C. The fluorinated solvents, such as fluorinated carbonates, fluorinated esters, and fluorinated esters, are less flammable than their non-fluorinated counterparts and improve safety characteristics of cells containing these solvents. The amount of fluorinated solvents in electrolytes may be between about 30% and 80% by weight not accounting weight of the salts. Linear and cyclic imide salts, such as LiN(SO.sub.2CF.sub.2CF.sub.3).sub.2, and LiN(SO.sub.2CF.sub.3).sub.2, as well as methide salts, such as LiC(SO.sub.2CF.sub.3).sub.3 and LiC(SO.sub.2CF.sub.2CF.sub.3).sub.3, may be used in these electrolytes. Fluorinated alkyl groups enhance solubility of these salts in the fluorinated solvents. In some embodiments, the electrolyte may also include a flame retardant, such as a phosphazene, and/or one or more ionic liquids.

  10. Slip and Dilation Tendency Analysis of the Salt Wells Geothermal Area

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Faulds, James E.

    2013-12-31

    Stress field variation within each focus area was approximated based on regional published data and the world stress database (Hickman et al., 2000; Hickman et al., 1998 Robertson-Tait et al., 2004; Hickman and Davatzes, 2010; Davatzes and Hickman, 2006; Blake and Davatzes 2011; Blake and Davatzes, 2012; Moeck et al., 2010; Moos and Ronne, 2010 and Reinecker et al., 2005) as well as local stress information if applicable. For faults within these focus systems we applied either a normal faulting stress regime where the vertical stress (sv) is larger than the maximum horizontal stress (shmax) which is larger than the minimum horizontal stress (sv>shmax>shmin) or strike-slip faulting stress regime where the maximum horizontal stress (shmax) is larger than the vertical stress (sv) which is larger than the minimum horizontal stress (shmax >sv>shmin) depending on the general tectonic province of the system. Based on visual inspection of the limited stress magnitude data in the Great Basin we used magnitudes such that shmin/shmax = .527 and shmin/sv= .46, which are consistent with complete and partial stress field determinations from Desert Peak, Coso, the Fallon area and Dixie valley (Hickman et al., 2000; Hickman et al., 1998 Robertson-Tait et al., 2004; Hickman and Davatzes, 2011; Davatzes and Hickman, 2006; Blake and Davatzes 2011; Blake and Davatzes, 2012). Slip and dilation tendency for the Salt Wells geothermal field was calculated based on the faults mapped in the Bunejug Mountains quadrangle (Hinz et al., 2011). The Salt Wells area lies in the Basin and Range Province (N. Hinz personal comm.) As such we applied a normal faulting stress regime to the Salt Wells area faults, with a minimum horizontal stress direction oriented 105, based on inspection of local and regional stress determinations. Under these stress conditions north-northeast striking, steeply dipping fault segments have the highest dilation tendency, while north-northeast striking 60 dipping fault segments have the highest tendency to slip. Several such faults intersect in high density in the core of the accommodation zone in the Bunejug Mountains and local to the Salt Wells geothermal .

  11. Production of carboxylic acid and salt co-products

    DOE Patents [OSTI]

    Hanchar, Robert J.; Kleff, Susanne; Guettler, Michael V.

    2014-09-09

    This invention provide processes for producing carboxylic acid product, along with useful salts. The carboxylic acid product that is produced according to this invention is preferably a C.sub.2-C.sub.12 carboxylic acid. Among the salts produced in the process of the invention are ammonium salts.

  12. EIA - Natural Gas Pipeline Network - Salt Cavern Storage Reservoir

    U.S. Energy Information Administration (EIA) Indexed Site

    Configuration Salt Cavern Storage Reservoir Configuration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Salt Cavern Underground Natural Gas Storage Reservoir Configuration Salt Cavern Underground Natural Gas Storage Reservoir Configuration Source: PB Energy Storage Services Inc.

  13. SOLUTION MINING IN SALT DOMES OF THE GULF COAST EMBAYMENT

    SciTech Connect (OSTI)

    Griswold, G. B.

    1981-02-01

    Following a description of salt resources in the salt domes of the gulf coast embayment, mining, particularly solution mining, is described. A scenario is constructed which could lead to release of radioactive waste stored in a salt dome via inadvertent solution mining and the consequences of this scenario are analyzed.

  14. CLEAR LAKE BASIN 2000 PROJECT

    SciTech Connect (OSTI)

    LAKE COUNTY SANITATION DISTRICT

    2003-03-31

    The following is a final report for the Clear Lake Basin 2000 project. All of the major project construction work was complete and this phase generally included final details and testing. Most of the work was electrical. Erosion control activities were underway to prepare for the rainy season. System testing including pump stations, electrical and computer control systems was conducted. Most of the project focus from November onward was completing punch list items.

  15. Advanced heat exchanger development for molten salts

    SciTech Connect (OSTI)

    Sabharwall, Piyush; Clark, Denis; Glazoff, Michael; Zheng, Guiqiu; Sridharan, Kumar; Anderson, Mark

    2014-12-01

    This study addresses present work concerned with advanced heat exchanger development for molten salt in nuclear and non nuclear thermal systems. The molten salt systems discussed herein use alloys, such as Hastelloy N and 242, which show corrosion resistance to molten salt at nominal operating temperatures up to 700°C. These alloys were diffusion welded, and the corresponding information is presented. Test specimens were prepared for exposing diffusion welds to molten salt environments. Hastelloy N and 242 were found to be weldable by diffusion welding, with ultimate tensile strengths about 90% of base metal values. Both diffusion welds and sheet material in Hastelloy N were corrosion tested in?58 mol% KF and 42 mol% ZrF4 at 650, 700, and 850°C for 200, 500, and 1,000 hours. Corrosion rates found were similar between welded and nonwelded materials, typically <10 mils per year. For materials of construction, nickel and alloys with dense nickel coatings are effectively inert to corrosion in fluorides, but not so in chlorides. Hence, additional testing of selected alloys for resistance to intergranular corrosion is needed, as is a determination of corrosion rate as a function of contaminant type and alloy composition with respect to chromium and carbon to better define the optimal chromium and carbon composition, independent of galvanic or differential solubility effects. Also presented is the division of the nuclear reactor and high temperature components per ASME standards, along with design requirements for a subcritical Rankine power cycle heat exchanger that has to overcome pressure difference of about 17 MPa.

  16. Supplemental Cooling for Nitrate Salt Waste

    SciTech Connect (OSTI)

    Goldberg, Mitchell S.

    2015-08-19

    In July 2015, Los Alamos National Laboratory completed installation of a supplemental cooling system in the structure where remediated nitrate salt waste drums are stored. Although the waste currently is in a safe configuration and is monitored daily,controlling the temperature inside the structure adds another layer of protection for workers, the public,and the environment.This effort is among several layers of precautions designed to secure the waste.

  17. Molten salt battery having inorganic paper separator

    DOE Patents [OSTI]

    Walker, Jr., Robert D.

    1977-01-01

    A high temperature secondary battery comprises an anode containing lithium, a cathode containing a chalcogen or chalcogenide, a molten salt electrolyte containing lithium ions, and a separator comprising a porous sheet comprising a homogenous mixture of 2-20 wt.% chrysotile asbestos fibers and the remainder inorganic material non-reactive with the battery components. The non-reactive material is present as fibers, powder, or a fiber-powder mixture.

  18. Advanced heat exchanger development for molten salts

    SciTech Connect (OSTI)

    Sabharwall, Piyush; Clark, Denis; Glazoff, Michael; Zheng, Guiqiu; Sridharan, Kumar; Anderson, Mark

    2014-12-01

    This study addresses present work concerned with advanced heat exchanger development for molten salt in nuclear and non nuclear thermal systems. The molten salt systems discussed herein use alloys, such as Hastelloy N and 242, which show corrosion resistance to molten salt at nominal operating temperatures up to 700C. These alloys were diffusion welded, and the corresponding information is presented. Test specimens were prepared for exposing diffusion welds to molten salt environments. Hastelloy N and 242 were found to be weldable by diffusion welding, with ultimate tensile strengths about 90% of base metal values. Both diffusion welds and sheet material in Hastelloy N were corrosion tested in?58 mol% KF and 42 mol% ZrF4 at 650, 700, and 850C for 200, 500, and 1,000 hours. Corrosion rates found were similar between welded and nonwelded materials, typically <10 mils per year. For materials of construction, nickel and alloys with dense nickel coatings are effectively inert to corrosion in fluorides, but not so in chlorides. Hence, additional testing of selected alloys for resistance to intergranular corrosion is needed, as is a determination of corrosion rate as a function of contaminant type and alloy composition with respect to chromium and carbon to better define the optimal chromium and carbon composition, independent of galvanic or differential solubility effects. Also presented is the division of the nuclear reactor and high temperature components per ASME standards, along with design requirements for a subcritical Rankine power cycle heat exchanger that has to overcome pressure difference of about 17 MPa.

  19. 2015 VIII MECHANICAL BEHAVIOR OF SALT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    VIII MECHANICAL BEHAVIOR OF SALT - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  20. Stationary phase deposition based on onium salts

    DOE Patents [OSTI]

    Wheeler, David R.; Lewis, Patrick R.; Dirk, Shawn M.; Trudell, Daniel E.

    2008-01-01

    Onium salt chemistry can be used to deposit very uniform thickness stationary phases on the wall of a gas chromatography column. In particular, the stationary phase can be bonded to non-silicon based columns, especially microfabricated metal columns. Non-silicon microfabricated columns may be manufactured and processed at a fraction of the cost of silicon-based columns. In addition, the method can be used to phase-coat conventional capillary columns or silicon-based microfabricated columns.

  1. Advanced heat exchanger development for molten salts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sabharwall, Piyush; Clark, Denis; Glazoff, Michael; Zheng, Guiqiu; Sridharan, Kumar; Anderson, Mark

    2014-12-01

    This study addresses present work concerned with advanced heat exchanger development for molten salt in nuclear and non nuclear thermal systems. The molten salt systems discussed herein use alloys, such as Hastelloy N and 242, which show corrosion resistance to molten salt at nominal operating temperatures up to 700°C. These alloys were diffusion welded, and the corresponding information is presented. Test specimens were prepared for exposing diffusion welds to molten salt environments. Hastelloy N and 242 were found to be weldable by diffusion welding, with ultimate tensile strengths about 90% of base metal values. Both diffusion welds and sheet materialmore » in Hastelloy N were corrosion tested in?58 mol% KF and 42 mol% ZrF4 at 650, 700, and 850°C for 200, 500, and 1,000 hours. Corrosion rates found were similar between welded and nonwelded materials, typically <10 mils per year. For materials of construction, nickel and alloys with dense nickel coatings are effectively inert to corrosion in fluorides, but not so in chlorides. Hence, additional testing of selected alloys for resistance to intergranular corrosion is needed, as is a determination of corrosion rate as a function of contaminant type and alloy composition with respect to chromium and carbon to better define the optimal chromium and carbon composition, independent of galvanic or differential solubility effects. Also presented is the division of the nuclear reactor and high temperature components per ASME standards, along with design requirements for a subcritical Rankine power cycle heat exchanger that has to overcome pressure difference of about 17 MPa.« less

  2. Waste Isolation Pilot Plant Salt Decontamination Testing

    SciTech Connect (OSTI)

    Rick Demmer; Stephen Reese

    2014-09-01

    On February 14, 2014, americium and plutonium contamination was released in the Waste Isolation Pilot Plant (WIPP) salt caverns. At the request of WIPP’s operations contractor, Idaho National Laboratory (INL) personnel developed several methods of decontaminating WIPP salt, using surrogate contaminants and also americium (241Am). The effectiveness of the methods is evaluated qualitatively, and to the extent possible, quantitatively. One of the requirements of this effort was delivering initial results and recommendations within a few weeks. That requirement, in combination with the limited scope of the project, made in-depth analysis impractical in some instances. Of the methods tested (dry brushing, vacuum cleaning, water washing, strippable coatings, and mechanical grinding), the most practical seems to be water washing. Effectiveness is very high, and it is very easy and rapid to deploy. The amount of wastewater produced (2 L/m2) would be substantial and may not be easy to manage, but the method is the clear winner from a usability perspective. Removable surface contamination levels (smear results) from the strippable coating and water washing coupons found no residual removable contamination. Thus, whatever is left is likely adhered to (or trapped within) the salt. The other option that shows promise is the use of a fixative barrier. Bartlett Nuclear, Inc.’s Polymeric Barrier System (PBS) proved the most durable of the coatings tested. The coatings were not tested for contaminant entrapment, only for coating integrity and durability.

  3. Pyrochemical process for extracting plutonium from an electrolyte salt

    DOE Patents [OSTI]

    Mullins, Lawrence J.; Christensen, Dana C.

    1984-01-01

    A pyrochemical process for extracting plutonium from a plutonium-bearing salt is disclosed. The process is particularly useful in the recovery of plutonium from electrolyte salts which are left over from the electrorefining of plutonium. In accordance with the process, the plutonium-bearing salt is melted and mixed with metallic calcium. The calcium reduces ionized plutonium in the salt to plutonium metal, and also causes metallic plutonium in the salt, which is typically present as finely dispersed metallic shot, to coalesce. The reduced and coalesced plutonium separates out on the bottom of the reaction vessel as a separate metallic phase which is readily separable from the overlying salt upon cooling of the mixture. Yields of plutonium are typically on the order of 95%. The stripped salt is virtually free of plutonium and may be discarded to low-level waste storage.

  4. Pyrochemical process for extracting plutonium from an electrolyte salt

    DOE Patents [OSTI]

    Mullins, L.J.; Christensen, D.C.

    1982-09-20

    A pyrochemical process for extracting plutonium from a plutonium-bearing salt is disclosed. The process is particularly useful in the recovery of plutonium for electrolyte salts which are left over from the electrorefining of plutonium. In accordance with the process, the plutonium-bearing salt is melted and mixed with metallic calcium. The calcium reduces ionized plutonium in the salt to plutonium metal, and also causes metallic plutonium in the salt, which is typically present as finely dispersed metallic shot, to coalesce. The reduced and coalesced plutonium separates out on the bottom of the reaction vessel as a separate metallic phase which is readily separable from the overlying salt upon cooling of the mixture. Yields of plutonium are typically on the order of 95%. The stripped salt is virtually free of plutonium and may be discarded to low-level waste storage.

  5. Liquid Fluoride Salt Experimentation Using a Small Natural Circulation Cell

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L; Heatherly, Dennis Wayne; Williams, David F; Elkassabgi, Yousri M.; Caja, Joseph; Caja, Mario; Jordan, John; Salinas, Roberto

    2014-04-01

    A small molten fluoride salt experiment has been constructed and tested to develop experimental techniques for application in liquid fluoride salt systems. There were five major objectives in developing this test apparatus: Allow visual observation of the salt during testing (how can lighting be introduced, how can pictures be taken, what can be seen) Determine if IR photography can be used to examine components submerged in the salt Determine if the experimental configuration provides salt velocity sufficient for collection of corrosion data for future experimentation Determine if a laser Doppler velocimeter can be used to quantify salt velocities. Acquire natural circulation heat transfer data in fluoride salt at temperatures up to 700oC All of these objectives were successfully achieved during testing with the exception of the fourth: acquiring velocity data using the laser Doppler velocimeter. This paper describes the experiment and experimental techniques used, and presents data taken during natural circulation testing.

  6. Polymeric salt bridges for conducting electric current in microfluidic devices

    DOE Patents [OSTI]

    Shepodd, Timothy J.; Tichenor, Mark S.; Artau, Alexander

    2009-11-17

    A "cast-in-place" monolithic microporous polymer salt bridge for conducting electrical current in microfluidic devices, and methods for manufacture thereof is disclosed. Polymeric salt bridges are formed in place in capillaries or microchannels. Formulations are prepared with monomer, suitable cross-linkers, solvent, and a thermal or radiation responsive initiator. The formulation is placed in a desired location and then suitable radiation such as UV light is used to polymerize the salt bridge within a desired structural location. Embodiments are provided wherein the polymeric salt bridges have sufficient porosity to allow ionic migration without bulk flow of solvents therethrough. The salt bridges form barriers that seal against fluid pressures in excess of 5000 pounds per square inch. The salt bridges can be formulated for carriage of suitable amperage at a desired voltage, and thus microfluidic devices using such salt bridges can be specifically constructed to meet selected analytical requirements.

  7. Reserves in western basins: Part 1, Greater Green River basin

    SciTech Connect (OSTI)

    Not Available

    1993-10-01

    This study characterizes an extremely large gas resource located in low permeability, overpressured sandstone reservoirs located below 8,000 feet drill depth in the Greater Green River basin, Wyoming. Total in place resource is estimated at 1,968 Tcf. Via application of geologic, engineering and economic criteria, the portion of this resource potentially recoverable as reserves is estimated. Those volumes estimated include probable, possible and potential categories and total 33 Tcf as a mean estimate of recoverable gas for all plays considered in the basin. Five plays (formations) were included in this study and each was separately analyzed in terms of its overpressured, tight gas resource, established productive characteristics and future reserves potential based on a constant $2/Mcf wellhead gas price scenario. A scheme has been developed to break the overall resource estimate down into components that can be considered as differing technical and economic challenges that must be overcome in order to exploit such resources: in other words, to convert those resources to economically recoverable reserves. Total recoverable reserves estimates of 33 Tcf do not include the existing production from overpressured tight reservoirs in the basin. These have estimated ultimate recovery of approximately 1.6 Tcf, or a per well average recovery of 2.3 Bcf. Due to the fact that considerable pay thicknesses can be present, wells can be economic despite limited drainage areas. It is typical for significant bypassed gas to be present at inter-well locations because drainage areas are commonly less than regulatory well spacing requirements.

  8. K Basins Groundwater Monitoring Task, K Basins Closure Project: Report for January, February, and March 2007

    SciTech Connect (OSTI)

    Peterson, Robert E.

    2007-04-01

    This report describes the results of groundwater monitoring near the K Basins for the period January, February, and March 2007.

  9. Hydrogeochemical Indicators for Great Basin Geothemal Resources...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogeochemical Indicators for Great Basin Geothemal Resources presentation at the April 2013 peer review meeting held in Denver, Colorado. PDF icon simmonshydrogeochemicalpeer2...

  10. Geothermal Resources Of California Sedimentary Basins | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Geothermal Resources Of California Sedimentary Basins Abstract The 2004 Department of Energy...

  11. An Overview of Liquid Fluoride Salt Heat Transport Technology

    SciTech Connect (OSTI)

    Cetiner, Mustafa Sacit; Holcomb, David Eugene

    2010-01-01

    Liquid fluoride salts are a leading candidate heat transport medium for high-temperature applications. This report provides an overview of the current status of liquid salt heat transport technology. The report includes a high-level, parametric evaluation of liquid fluoride salt heat transport loop performance to allow intercomparisons between heat-transport fluid options as well as providing an overview of the properties and requirements for a representative loop. Much of the information presented here derives from the earlier molten salt reactor program and a significant advantage of fluoride salts, as high temperature heat transport media is their consequent relative technological maturity. The report also includes a compilation of relevant thermophysical properties of useful heat transport fluoride salts. Fluoride salts are both thermally stable and with proper chemistry control can be relatively chemically inert. Fluoride salts can, however, be highly corrosive depending on the container materials selected, the salt chemistry, and the operating procedures used. The report also provides an overview of the state-of-the-art in reduction-oxidation chemistry control methodologies employed to minimize salt corrosion as well as providing a general discussion of heat transfer loop operational issues such as start-up procedures and freeze-up vulnerability.

  12. Tank 37H Salt Removal Batch Process and Salt Dissolution Mixing Study

    SciTech Connect (OSTI)

    Kwon, K.C.

    2001-09-18

    Tank 30H is the receipt tank for concentrate from the 3H Evaporator. Tank 30H has had problems, such as cooling coil failure, which limit its ability to receive concentrate from the 3H Evaporator. SRS High Level Waste wishes to use Tank 37H as the receipt tank for the 3H Evaporator concentrate. Prior to using Tank 37H as the 3H Evaporator concentrate receipt tank, HLW must remove 50 inches of salt cake from the tank. They requested SRTC to evaluate various salt removal methods for Tank 37H. These methods include slurry pumps, Flygt mixers, the modified density gradient method, and molecular diffusion.

  13. Salt disposal of heat-generating nuclear waste.

    SciTech Connect (OSTI)

    Leigh, Christi D.; Hansen, Francis D.

    2011-01-01

    This report summarizes the state of salt repository science, reviews many of the technical issues pertaining to disposal of heat-generating nuclear waste in salt, and proposes several avenues for future science-based activities to further the technical basis for disposal in salt. There are extensive salt formations in the forty-eight contiguous states, and many of them may be worthy of consideration for nuclear waste disposal. The United States has extensive experience in salt repository sciences, including an operating facility for disposal of transuranic wastes. The scientific background for salt disposal including laboratory and field tests at ambient and elevated temperature, principles of salt behavior, potential for fracture damage and its mitigation, seal systems, chemical conditions, advanced modeling capabilities and near-future developments, performance assessment processes, and international collaboration are all discussed. The discussion of salt disposal issues is brought current, including a summary of recent international workshops dedicated to high-level waste disposal in salt. Lessons learned from Sandia National Laboratories' experience on the Waste Isolation Pilot Plant and the Yucca Mountain Project as well as related salt experience with the Strategic Petroleum Reserve are applied in this assessment. Disposal of heat-generating nuclear waste in a suitable salt formation is attractive because the material is essentially impermeable, self-sealing, and thermally conductive. Conditions are chemically beneficial, and a significant experience base exists in understanding this environment. Within the period of institutional control, overburden pressure will seal fractures and provide a repository setting that limits radionuclide movement. A salt repository could potentially achieve total containment, with no releases to the environment in undisturbed scenarios for as long as the region is geologically stable. Much of the experience gained from United States repository development, such as seal system design, coupled process simulation, and application of performance assessment methodology, helps define a clear strategy for a heat-generating nuclear waste repository in salt.

  14. Delaware Basin Monitoring Annual Report

    SciTech Connect (OSTI)

    Washington Regulatory and Environmental Services; Washington TRU Solutions LLC

    2001-09-28

    The Delaware Basin Drilling Surveillance Program (DBDSP) is designed to monitor drilling activities in the vicinity of the Waste Isolation Pilot Plant (WIPP). This program is based on Environmental Protection Agency (EPA) requirements. EPA requires the Department of Energy (DOE) to demonstrate the expected performance of the disposal system using a probabilistic risk assessment or performance assessment (PA). This PA must show that the expected repository performance will not release radioactive material above limits set by the EPA's standard and must consider inadvertent drilling into the repository at some future time.

  15. K Basins Groundwater Monitoring Task, K Basins Closure Project: Report for October, November, and December 2006

    SciTech Connect (OSTI)

    Peterson, Robert E.

    2007-03-22

    This report provides information on groundwater monitoring at the K Basins during October, November, and December 2006. Conditions remained very similar to those reported in the previous quarterly report, with no evidence in monitoring results to suggest groundwater impact from current loss of basin water to the ground. The K Basins monitoring network will be modified in the coming months as a consequence of new wells having been installed near KW Basin as part of a pump-and-treat system for chromium contamination, and new wells installed between the KE Basin and the river to augment long-term monitoring in that area.

  16. Molecular dynamics study of saltsolution interface: Solubility and surface charge of salt in water

    SciTech Connect (OSTI)

    Kobayashi, Kazuya; Liang, Yunfeng E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Matsuoka, Toshifumi E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Sakka, Tetsuo

    2014-04-14

    The NaCl saltsolution interface often serves as an example of an uncharged surface. However, recent laser-Doppler electrophoresis has shown some evidence that the NaCl crystal is positively charged in its saturated solution. Using molecular dynamics (MD) simulations, we have investigated the NaCl saltsolution interface system, and calculated the solubility of the salt using the direct method and free energy calculations, which are kinetic and thermodynamic approaches, respectively. The direct method calculation uses a saltsolution combined system. When the system is equilibrated, the concentration in the solution area is the solubility. In the free energy calculation, we separately calculate the chemical potential of NaCl in two systems, the solid and the solution, using thermodynamic integration with MD simulations. When the chemical potential of NaCl in the solution phase is equal to the chemical potential of the solid phase, the concentration of the solution system is the solubility. The advantage of using two different methods is that the computational methods can be mutually verified. We found that a relatively good estimate of the solubility of the system can be obtained through comparison of the two methods. Furthermore, we found using microsecond time-scale MD simulations that the positively charged NaCl surface was induced by a combination of a sodium-rich surface and the orientation of the interfacial water molecules.

  17. Heat Transfer Salts for Nuclear Reactor Systems - Chemistry Control,

    Office of Scientific and Technical Information (OSTI)

    Corrosion Mitigation, and Modeling (Technical Report) | SciTech Connect Heat Transfer Salts for Nuclear Reactor Systems - Chemistry Control, Corrosion Mitigation, and Modeling Citation Details In-Document Search Title: Heat Transfer Salts for Nuclear Reactor Systems - Chemistry Control, Corrosion Mitigation, and Modeling The concept of a molten salt reactor has existed for nearly sixty years. Previously all work was done during a large collaborative effort at Oak Ridge National Laboratory,

  18. Independent Oversight Review, Savannah River Site Salt Waste Processing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Facility - April 2014 | Department of Energy Salt Waste Processing Facility - April 2014 Independent Oversight Review, Savannah River Site Salt Waste Processing Facility - April 2014 April 2014 Review of the Savannah River Site Salt Waste Processing Facility Construction Quality and Fire Protection Systems The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security, conducted an independent review of the

  19. Liquid Salt Heat Exchanger Technology for VHTR Based Applications

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Liquid Salt Heat Exchanger Technology for VHTR Based Applications Citation Details In-Document Search Title: Liquid Salt Heat Exchanger Technology for VHTR Based Applications The objective of this research is to evaluate performance of liquid salt fluids for use as a heat carrier for transferring high-temperature process heat from the very high-temperature reactor (VHTR) to chemical process plants. Currently, helium is being considered as the heat

  20. Enterprise Assessments Salt Waste Processing Facility Construction Quality

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Fire Protection Systems Follow-up Review at the Savannah River Site - January 2016 | Department of Energy Salt Waste Processing Facility Construction Quality and Fire Protection Systems Follow-up Review at the Savannah River Site - January 2016 Enterprise Assessments Salt Waste Processing Facility Construction Quality and Fire Protection Systems Follow-up Review at the Savannah River Site - January 2016 February 2016 Follow-up Review of the Salt Waste Processing Systems and Fire

  1. Voluntary Protection Program Onsite Review, Salt Waste Processing Facility

    Energy Savers [EERE]

    Construction Project - February 2013 | Department of Energy Salt Waste Processing Facility Construction Project - February 2013 Voluntary Protection Program Onsite Review, Salt Waste Processing Facility Construction Project - February 2013 February 2013 Evaluation to determine whether Salt Waste Processing Facility Construction Project is continuing to perform at a level deserving DOE-VPP Star recognition. The Team conducted its review during February 5 - 14, 2013 to determine whether

  2. DOE Issues Salt Waste Determination for the Savannah River Site |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Salt Waste Determination for the Savannah River Site DOE Issues Salt Waste Determination for the Savannah River Site January 18, 2006 - 10:49am Addthis WASHINGTON, DC - The U.S. Department of Energy (DOE) today issued the waste determination for the treatment and stabilization of low activity salt-waste at the Savannah River Site allowing for significant reductions in environmental and health risks posed by the material. Stored in forty-nine underground tanks,

  3. Salts of alkali metal anions and process of preparing same

    DOE Patents [OSTI]

    Dye, James L.; Ceraso, Joseph M.; Tehan, Frederick J.; Lok, Mei Tak

    1978-01-01

    Compounds of alkali metal anion salts of alkali metal cations in bicyclic polyoxadiamines are disclosed. The salts are prepared by contacting an excess of alkali metal with an alkali metal dissolving solution consisting of a bicyclic polyoxadiamine in a suitable solvent, and recovered by precipitation. The salts have a gold-color crystalline appearance and are stable in a vacuum at -10.degree. C. and below.

  4. Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory As a part of its national security mission, the Laboratory conducts research that generates waste contaminated with radioactive isotopes. During operations, waste is processed, packaged, and shipped to licensed disposal facilities. PDF icon Remediated-Nitrate-Salt-Drums-Storage-at-Los-Alamos-National-Laboratory.pdf More Documents

  5. Delivery system for molten salt oxidation of solid waste

    DOE Patents [OSTI]

    Brummond, William A. (Livermore, CA); Squire, Dwight V. (Livermore, CA); Robinson, Jeffrey A. (Manteca, CA); House, Palmer A. (Walnut Creek, CA)

    2002-01-01

    The present invention is a delivery system for safety injecting solid waste particles, including mixed wastes, into a molten salt bath for destruction by the process of molten salt oxidation. The delivery system includes a feeder system and an injector that allow the solid waste stream to be accurately metered, evenly dispersed in the oxidant gas, and maintained at a temperature below incineration temperature while entering the molten salt reactor.

  6. DOE - Office of Legacy Management -- Penn Salt Manufacturing Co Whitemarsh

    Office of Legacy Management (LM)

    Research Laboratories - PA 20 Salt Manufacturing Co Whitemarsh Research Laboratories - PA 20 FUSRAP Considered Sites Site: PENN SALT MANUFACTURING CO., WHITEMARSH RESEARCH LABORATORIES (PA.20) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Penn Salt Company PA.20-1 Location: Philiadelphia , Pennsylvania PA.20-1 Evaluation Year: 1987 PA.20-1 Site Operations: Conducted process studies for recovery of uranium from fluoride scrap. PA.20-1 Site

  7. Section 3116 Waste Determinationfor Salt Disposal at the Savannah River

    Office of Environmental Management (EM)

    Site, signed by Secretary of Energy, Samuel W. Bodman | Department of Energy Section 3116 Waste Determinationfor Salt Disposal at the Savannah River Site, signed by Secretary of Energy, Samuel W. Bodman Section 3116 Waste Determinationfor Salt Disposal at the Savannah River Site, signed by Secretary of Energy, Samuel W. Bodman PDF icon Section 3116 Waste Determinationfor Salt Disposal at the Savannah River Site, signed by Secretary of Energy, Samuel W. Bodman More Documents &

  8. PP-64 Basin Electric Power Cooperative | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Basin Electric Power Cooperative to construct, operate, and maintain transmission facilities at the U.S. - Canada Border. PDF icon PP-64 Basin Electric Power Cooperative More ...

  9. Geographic Information System At Nw Basin & Range Region (Nash...

    Open Energy Info (EERE)

    Nw Basin & Range Region (Nash & Johnson, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geographic Information System At Nw Basin & Range...

  10. L-Shaped Flume Wave Basin | Open Energy Information

    Open Energy Info (EERE)

    L-Shaped Flume Wave Basin Jump to: navigation, search Basic Specifications Facility Name L-Shaped Flume Wave Basin Overseeing Organization United States Army Corp of Engineers...

  11. Judith Basin County, Montana: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    6 Climate Zone Subtype B. Places in Judith Basin County, Montana Hobson, Montana Stanford, Montana Retrieved from "http:en.openei.orgwindex.php?titleJudithBasinCounty,...

  12. Northwest Basin and Range Geothermal Region | Open Energy Information

    Open Energy Info (EERE)

    Basin and Range Geothermal Region Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Northwest Basin and Range Geothermal Region Details Areas (51) Power Plants (10)...

  13. Climate Change and the Macroeconomy in the Caribbean Basin: Analysis...

    Open Energy Info (EERE)

    in the Caribbean Basin: Analysis and Projections to 2099 Jump to: navigation, search Name Climate Change and the Macroeconomy in the Caribbean Basin: Analysis and Projections to...

  14. Structure and Groundwater Flow in the Espanola Basin Near Rio...

    Office of Environmental Management (EM)

    Structure and Groundwater Flow in the Espanola Basin Near Rio Grande and Buckman Wellfield Structure and Groundwater Flow in the Espanola Basin Near Rio Grande and Buckman...

  15. Analysis of SPR salt cavern remedial leach program 2013. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Title: Analysis of SPR salt cavern remedial leach program 2013. The storage caverns of the US Strategic Petroleum Reserve (SPR) exhibit creep behavior resulting in reduction of ...

  16. ENEL Salt Wells Geothermal Facility | Open Energy Information

    Open Energy Info (EERE)

    Salt Wells Geothermal Facility Sector Geothermal energy Location Information Location Churchill, NV Coordinates 39.651603422063, -118.49778413773 Loading map......

  17. Hybrid Molten Salt Reactor (HMSR): Method and System to fully...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hybrid Molten Salt Reactor (HMSR): Method and System to fully fission actinides for electric power production without ... produce heat suitable for efficient electricity production. ...

  18. Assessment of Nuclear Safety Culture at the Salt Waste Processing...

    Office of Environmental Management (EM)

    Oversight Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility Project ... Commission (NRC), several nuclear power generating utilities, and associated ...

  19. Accident Investigation of the February 5, 2014, Underground Salt...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Accident Investigation of the February 5, 2014, Underground Salt Haul Truck Fire at the Waste Isolation Pilot Plant, Carlsbad NM March 26, 2014 Accident Investigation of the ...

  20. Lithium Salt-doped, Gelled Polymer Electrolyte with a Nanoporous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Lithium Salt-doped, Gelled Polymer Electrolyte with a ... electrolyte material for use in lithium ion batteries that exhibits better ion ...

  1. Project Profile: Novel Molten Salts Thermal Energy Storage for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovation Alabama's LMP molten salt is projected to have the following ... Lower melting point Higher energy density Lower power-generation cost This program aims to develop a ...

  2. Enterprise Assessments Review of the Savannah River Site Salt...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Startup Test Plans - June 2015 Enterprise Assessments Review of the Savannah River Site Salt Waste Processing Facility Construction Quality and Startup Test Plans - June ...

  3. Sandia Energy - New Liquid Salt Electrolytes Could Lead to Cost...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Salt Electrolytes Could Lead to Cost-Effective Flow Batteries Chemical technologist Harry Pratt synthesizes a copper-based ionic liquid. (Photo by Randy Montoya) Sandia...

  4. Radiometrics At Salt Wells Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    Henkle, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Radiometrics At Salt Wells Area (Henkle, Et Al., 2005) Exploration Activity...

  5. Development Wells At Salt Wells Area (Nevada Bureau of Mines...

    Open Energy Info (EERE)

    (Nevada Bureau of Mines and Geology, 2009) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Development Drilling Activity Date 2005 - 2005...

  6. Savannah River Site - Salt Waste Processing Facility: Briefing...

    Office of Environmental Management (EM)

    Salt Waste Processing Facility Independent Technical Review Harry Harmon January 9, 2007 2 U.S. Department of Energy Outline * SWPF Process Overview * Major Risks * Approach for ...

  7. Salt Wells Geothermal Energy Projects Environmental Impact Statement...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells Geothermal Energy Projects Environmental Impact Statement Abstract Abstract unavailable....

  8. Molten salt bath circulation design for an electrolytic cell

    DOE Patents [OSTI]

    Dawless, R.K.; LaCamera, A.F.; Troup, R.L.; Ray, S.P.; Hosler, R.B.

    1999-08-17

    An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride. 4 figs.

  9. Molten salt bath circulation design for an electrolytic cell

    DOE Patents [OSTI]

    Dawless, Robert K.; LaCamera, Alfred F.; Troup, R. Lee; Ray, Siba P.; Hosler, Robert B.

    1999-01-01

    An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride.

  10. Liquid Fluoride Salt Experimentation Using a Small Natural Circulation...

    Office of Scientific and Technical Information (OSTI)

    be introduced, how can pictures be taken, what can be seen) Determine if IR photography can be used to examine components submerged in the salt Determine if the ...

  11. Heat Transfer Salts for Nuclear Reactor Systems - Chemistry Control...

    Office of Scientific and Technical Information (OSTI)

    Heat Transfer Salts for Nuclear Reactor Systems - Chemistry Control, Corrosion Mitigation, ... guide to allow anyone to learn the fundamentals of chemistry, engineering, and safety ...

  12. Salt Waste Processing Facility, Line Management Review Board Charter

    Broader source: Energy.gov [DOE]

    The Line Management Review Board (LMRB) serves an important oversight function to monitor the readiness processes and associated deliverables for the Salt Waste Processing Facility (SWPF). The...

  13. Method for the production of uranium chloride salt

    DOE Patents [OSTI]

    Westphal, Brian R.; Mariani, Robert D.

    2013-07-02

    A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

  14. Evaluation of Salt Coolants for Reactor Applications (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Evaluation of Salt Coolants for Reactor Applications Citation Details In-Document Search Title: Evaluation of Salt Coolants for Reactor Applications Molten fluorides were initially developed for use in the nuclear industry as the high-temperature fluid fuel for the Molten Salt Reactor (MSR). The U.S. Department of Energy Office of Nuclear Energy is exploring the use of molten salts as primary and secondary coolants in a new generation of solid-fueled, thermal-spectrum,

  15. Analysis of SPR salt cavern remedial leach program 2013. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Analysis of SPR salt cavern remedial leach program 2013. Citation Details In-Document ... Sponsoring Org: USDOE National Nuclear Security Administration (NNSA) Country of ...

  16. Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolytes Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic Liquids for Lithium Battery Electrolytes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual...

  17. Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    pressure solution and dislocation creep, with both terms dependent on effective stress to account for the effects of porosity. This provides insight into granular salt...

  18. Exploratory Well At Salt Wells Area (Bureau of Land Management...

    Open Energy Info (EERE)

    Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Exploratory Well At Salt Wells Area (Bureau of Land Management,...

  19. Salt Lake City, Utah: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Salt Lake City, Utah: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 40.7607793, -111.8910474 Show Map Loading map... "minzoom":false,"mapping...

  20. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container

    Office of Environmental Management (EM)

    Nitrate Salt Bearing Waste Container Isolation Plan Prepared in Response to New Mexico ... (DOE) and Nuclear Waste Partnership LLC (NWP), collectively referred to as the Permittees. ...

  1. Project Profile: Molten Salt-Carbon Nanotube Thermal Storage

    Broader source: Energy.gov [DOE]

    Texas Engineering Experiment Station (TEES), under the Thermal Storage FOA, created a composite thermal energy storage material by embedding nanoparticles in a molten salt base material.

  2. Accelerator-driven subcritical fission in molten salt core: Closing...

    Office of Scientific and Technical Information (OSTI)

    Accelerator-driven subcritical fission in molten salt core: Closing the nuclear fuel cycle for green nuclear energy Citation Details In-Document Search Title: Accelerator-driven ...

  3. Molten salt considerations for accelerator-driven subcritical...

    Office of Scientific and Technical Information (OSTI)

    to close the nuclear fuel cycle Citation Details In-Document Search Title: Molten salt considerations for accelerator-driven subcritical fission to close the nuclear fuel cycle ...

  4. BLM Approves Salt Wells Geothermal Energy Projects | Open Energy...

    Open Energy Info (EERE)

    Energy Projects Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: BLM Approves Salt Wells Geothermal Energy Projects Abstract Abstract unavailable....

  5. Enterprise Assessments Review of the Savannah River Site Salt...

    Broader source: Energy.gov (indexed) [DOE]

    Salt Waste Processing Facility Construction Quality and Startup Test Plans June 2015 Office of Nuclear Safety and Environmental Assessments Office of Environment, Safety and...

  6. Voluntary Protection Program Onsite Review, Salt Waste Processing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Team conducted its review during February 5 - 14, 2013 to determine whether Parsons ... Voluntary Protection Program Onsite Review, Parsons Corporation Salt Waste Processing ...

  7. Independent Oversight Review, Savannah River Site Salt Waste...

    Office of Environmental Management (EM)

    Salt Waste Processing Facility - April 2014 Independent Oversight Review, Savannah River Site ... 2015 Independent Oversight Review, Waste Treatment and Immobilization Plant - May 2013

  8. Salt River Electric- Residential Energy Efficiency Rebate Programs

    Broader source: Energy.gov [DOE]

    Salt River Electric serves as the rural electric provider in Kentucky's Bullitt, Nelson, Spencer, and Washington counties. Residential customers are eligible for a variety of cash incentives for...

  9. WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update May 12, 2015 Panel 6 and Panel 7, Room 7 a. Rollback * Contamination Assessment-This prerequisite is ...

  10. Liquid fuel molten salt reactors for thorium utilization (Journal...

    Office of Scientific and Technical Information (OSTI)

    resulted in two experimental systems operating at ORNL in the 1960s, the Aircraft Reactor Experiment and the Molten Salt Reactor Experiment. Subsequent design studies in the ...

  11. Domestic Material Content in Molten-Salt Concentrating Solar...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Domestic Material Content in Molten-Salt Concentrating Solar Power Plants Craig Turchi, Parthiv Kurup, Sertac Akar, and Francisco Flores Technical Report NRELTP-5500-64429 August...

  12. Water Sampling At Salt Wells Area (Shevenell & Garside, 2003...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Salt Wells Area (Shevenell & Garside, 2003) Exploration Activity Details...

  13. Water Sampling At Salt Wells Area (Coolbaugh, Et Al., 2006) ...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Salt Wells Area (Coolbaugh, Et Al., 2006) Exploration Activity Details...

  14. Controlled Source Frequency-Domain Magnetics At Salt Wells Area...

    Open Energy Info (EERE)

    At Salt Wells Area (Montgomery, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Controlled Source Frequency-Domain Magnetics At...

  15. An Overview of Liquid Fluoride Salt Heat Transport Systems

    SciTech Connect (OSTI)

    Holcomb, David Eugene; Cetiner, Sacit M

    2010-09-01

    Heat transport is central to all thermal-based forms of electricity generation. The ever increasing demand for higher thermal efficiency necessitates power generation cycles transitioning to progressively higher temperatures. Similarly, the desire to provide direct thermal coupling between heat sources and higher temperature chemical processes provides the underlying incentive to move toward higher temperature heat transfer loops. As the system temperature rises, the available materials and technology choices become progressively more limited. Superficially, fluoride salts at {approx}700 C resemble water at room temperature being optically transparent and having similar heat capacity, roughly three times the viscosity, and about twice the density. Fluoride salts are a leading candidate heat-transport material at high temperatures. Fluoride salts have been extensively used in specialized industrial processes for decades, yet they have not entered widespread deployment for general heat transport purposes. This report does not provide an exhaustive screening of potential heat transfer media and other high temperature liquids such as alkali metal carbonate eutectics or chloride salts may have economic or technological advantages. A particular advantage of fluoride salts is that the technology for their use is relatively mature as they were extensively studied during the 1940s-1970s as part of the U.S. Atomic Energy Commission's program to develop molten salt reactors (MSRs). However, the instrumentation, components, and practices for use of fluoride salts are not yet developed sufficiently for commercial implementation. This report provides an overview of the current understanding of the technologies involved in liquid salt heat transport (LSHT) along with providing references to the more detailed primary information resources. Much of the information presented here derives from the earlier MSR program. However, technology has evolved over the intervening years, and this report also describes more recently developed technologies such as dry gas seals. This report also provides a high-level, parametric evaluation of LSHT loop performance to allow general intercomparisons between heat-transport fluid options as well as provide an overview of the properties and requirements for a representative loop. A compilation of relevant thermophysical properties of useful fluoride salts is also included for salt heat transport systems. Fluoride salts can be highly corrosive depending on the container materials selected, the salt chemistry, and the operating procedures used. The report includes an overview of the state-of-the-art in reduction-oxidation chemistry control methodologies employed to minimize corrosion issues. Salt chemistry control technology, however, remains at too low a level of understanding for widespread industrial usage. Loop operational issues such as start-up procedures and system freeze-up vulnerability are also discussed. Liquid fluoride salts are a leading candidate heat transport medium for high-temperature applications. This report provides an overview of the current status of liquid salt heat transport technology. The report includes a high-level, parametric evaluation of liquid fluoride salt heat transport loop performance to allow intercomparisons between heat-transport fluid options as well as providing an overview of the properties and requirements for a representative loop. Much of the information presented here derives from the earlier molten salt reactor program and a significant advantage of fluoride salts, as high temperature heat transport media is their consequent relative technological maturity. The report also includes a compilation of relevant thermophysical properties of useful heat transport fluoride salts. Fluoride salts are both thermally stable and with proper chemistry control can be relatively chemically inert. Fluoride salts can, however, be highly corrosive depending on the container materials selected, the salt chemistry, and the operating procedures used. The report also provides an overview of the state-of-the-art in reduction-oxidation chemistry control methodologies employed to minimize salt corrosion as well as providing a general discussion of heat transfer loop operational issues such as start-up procedures and freeze-up vulnerability.

  16. Laboratory investigation of crushed salt consolidation and fracture healing

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    A laboratory test program was conducted to investigate the consolidation behavior of crushed salt and fracture healing in natural and artificial salt. Crushed salt is proposed for use as backfill in a nuclear waste repository in salt. Artificial block salt is proposed for use in sealing a repository. Four consolidation tests were conducted in a hydrostatic pressure vessel at a maximum pressure of 2500 psi (17.2 MPa) and at room temperature. Three 1-month tests were conducted on salt obtained from the Waste Isolation Pilot Plant and one 2-month test was conducted on salt from Avery Island. Permeability was obtained using argon and either a steady-state or transient method. Initial porosities ranged from 0.26 to 0.36 and initial permeabilities from 2000 to 50,000 md. Final porosities and permeabilities ranged from 0.05 to 0.19 and from <10/sup -5/ md to 110 md, respectively. The lowest final porosity (0.05) and permeability (<10/sup -5/ md) were obtained in a 1-month test in which 2.3% moisture was added to the salt at the beginning of the test. The consolidation rate was much more rapid than in any of the dry salt tests. The fracture healing program included 20 permeability tests conducted on fractured and unfractured samples. The tests were conducted in a Hoek cell at hydrostatic pressures up to 3000 psi (20.6 MPa) with durations up to 8 days. For the natural rock salt tested, permeability was strongly dependent on confining pressure and time. The effect of confining pressure was much weaker in the artificial salt. In most cases the combined effects of time and pressure were to reduce the permeability of fractured samples to the same order of magnitude (or less) as the permeability measured prior to fracturing.

  17. Delaware Basin Monitoring Annual Report

    SciTech Connect (OSTI)

    Washington Regulatory and Environmental Services; Washington TRU Solutions LLC

    2003-09-30

    The Delaware Basin Drilling Surveillance Program (DBDSP) is designed to monitor drilling activities in the vicinity of the Waste Isolation Pilot Plant (WIPP). This program is based on Environmental Protection Agency (EPA) requirements. The EPA environmental standards for the management and disposal of transuranic (TRU) radioactive waste are codified in 40 CFR Part 191 (EPA 1993). Subparts B and C of the standard address the disposal of radioactive waste. The standard requires the Department of Energy (DOE) to demonstrate the expected performance of the disposal system using a probabilistic risk assessment or performance assessment (PA). This PA must show that the expected repository performance will not release radioactive material above limits set by the EPA's standard. This assessment must include the consideration of inadvertent drilling into the repository at some future time.

  18. Delaware Basin Monitoring Annual Report

    SciTech Connect (OSTI)

    Washington Regulatory and Environmental Services; Washington TRU Solutions LLC

    2004-09-30

    The Delaware Basin Drilling Surveillance Program (DBDSP) is designed to monitor drilling activities in the vicinity of the Waste Isolation Pilot Plant (WIPP). This program is based on Environmental Protection Agency (EPA) requirements. The EPA environmental standards for the management and disposal of transuranic (TRU) radioactive waste are codified in 40 CFR Part 191 (EPA 1993). Subparts B and C of the standard address the disposal of radioactive waste. The standard requires the Department of Energy (DOE) to demonstrate the expected performance of the disposal system using a probabilistic risk assessment or performance assessment (PA). This PA must show that the expected repository performance will not release radioactive material above limits set by the EPA's standard. This assessment must include the consideration of inadvertent drilling into the repository at some future time.

  19. Delaware Basin Monitoring Annual Report

    SciTech Connect (OSTI)

    Washington Regulatory and Environmental Services; Washington TRU Solutions LLC

    2002-09-21

    The Delaware Basin Drilling Surveillance Program (DBDSP) is designed to monitor drilling activities in the vicinity of the Waste Isolation Pilot Plant (WIPP). This program is based on Environmental Protection Agency (EPA) requirements. The EPA environmental standards for the management and disposal of transuranic (TRU) radioactive waste are codified in 40 CFR Part 191 (EPA 1993). Subparts B and C of the standard address the disposal of radioactive waste. The standard requires the Department of Energy (DOE) to demonstrate the expected performance of the disposal system using a probabilistic risk assessment or performance assessment (PA). This PA must show that the expected repository performance will not release radioactive material above limits set by the EPA's standard. This assessment must include the consideration of inadvertent drilling into the repository at some future time.

  20. Delaware Basin Monitoring Annual Report

    SciTech Connect (OSTI)

    Washington Regulatory and Environmental Services

    1999-09-30

    The Delaware Basin Drilling Surveillance Program (DBDSP) is designed to monitor drilling activities in the vicinity of the Waste Isolation Pilot Plant (WIPP). This program is based on Environmental Protection Agency (EPA) requirements. The EPA environmental standards for the management and disposal of transuranic (TRU) radioactive waste are codified in 40 CFR Part 191 (EPA 1993). Subparts B and C of the standard address the disposal of radioactive waste. The standard requires the Department of Energy (DOE) to demonstrate the expected performance of the disposal system using a probabilistic risk assessment or performance assessment (PA). This PA must show that the expected repository performance will not release radioactive material above limits set by the EPA's standard. This assessment must include the consideration of inadvertent drilling into the repository at some future time.

  1. Delaware Basin Monitoring Annual Report

    SciTech Connect (OSTI)

    Washington Regulatory and Environmental Services; Washington TRU Solutions LLC

    2000-09-28

    The Delaware Basin Drilling Surveillance Program (DBDSP) is designed to monitor drilling activities in the vicinity of the Waste Isolation Pilot Plant (WIPP). This program is based on Environmental Protection Agency (EPA) requirements. The EPA environmental standards for the management and disposal of transuranic (TRU) radioactive waste are codified in 40 CFR Part 191 (EPA 1993). Subparts B and C of the standard address the disposal of radioactive waste. The standard requires the Department of Energy (DOE) to demonstrate the expected performance of the disposal system using a probabilistic risk assessment or performance assessment (PA). This PA must show that the expected repository performance will not release radioactive material above limits set by the EPA's standard. This assessment must include the consideration of inadvertent drilling into the repository at some future time.

  2. Delaware Basin Monitoring Annual Report

    SciTech Connect (OSTI)

    Washington Regulatory and Environmental Services; Washington TRU Solutions LLC

    2005-09-30

    The Delaware Basin Drilling Surveillance Program (DBDSP) is designed to monitor drilling activities in the vicinity of the Waste Isolation Pilot Plant (WIPP). This program is based on Environmental Protection Agency (EPA) requirements. The EPA environmental standards for the management and disposal of transuranic (TRU) radioactive waste are codified in 40 CFR Part 191 (EPA 1993). Subparts B and C of the standard address the disposal of radioactive waste. The standard requires the Department of Energy (DOE) to demonstrate the expected performance of the disposal system using a probabilistic risk assessment or performance assessment (PA). This PA must show that the expected repository performance will not release radioactive material above limits set by the EPA's standard. This assessment must include the consideration of inadvertent drilling into the repository at some future time.

  3. Alternative Waste Forms for Electro-Chemical Salt Waste

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Sundaram, S. K.; Riley, Brian J.; Matyas, Josef; Arreguin, Shelly A.; Vienna, John D.

    2009-10-28

    This study was undertaken to examine alternate crystalline (ceramic/mineral) and glass waste forms for immobilizing spent salt from the Advanced Fuel Cycle Initiative (AFCI) electrochemical separations process. The AFCI is a program sponsored by U.S. Department of Energy (DOE) to develop and demonstrate a process for recycling spent nuclear fuel (SNF). The electrochemical process is a molten salt process for the reprocessing of spent nuclear fuel in an electrorefiner and generates spent salt that is contaminated with alkali, alkaline earths, and lanthanide fission products (FP) that must either be cleaned of fission products or eventually replaced with new salt to maintain separations efficiency. Currently, these spent salts are mixed with zeolite to form sodalite in a glass-bonded waste form. The focus of this study was to investigate alternate waste forms to immobilize spent salt. On a mole basis, the spent salt is dominated by alkali and Cl with minor amounts of alkaline earth and lanthanides. In the study reported here, we made an effort to explore glass systems that are more compatible with Cl and have not been previously considered for use as waste forms. In addition, alternate methods were explored with the hope of finding a way to produce a sodalite that is more accepting of as many FP present in the spent salt as possible. This study was done to investigate two different options: (1) alternate glass families that incorporate increased concentrations of Cl; and (2) alternate methods to produce a mineral waste form.

  4. Salt Lake County Residential Solar Financing Study | Department of Energy

    Energy Savers [EERE]

    Salt Lake City, Utah A White House Climate Action Champions Case Study INDEX Executive Summary.............................. 2 Climate Action Champion.................... 2 Project Spotlight.................................... 3 Challenges and lessons learned.......... 4 Resources & Contacts........................... 5 2 Executive Summary Salt Lake City has a robust set of ambitious climate goals that target reducing emissions while simultaneously prioritizing ways to become more resilient

  5. Treatment of plutonium process residues by molten salt oxidation

    SciTech Connect (OSTI)

    Stimmel, J.; Wishau, R.; Ramsey, K.B.; Montoya, A.; Brock, J.; Heslop, M.; Wernly, K.

    1999-04-01

    Molten Salt Oxidation (MSO) is a thermal process that can remove more than 99.999% of the organic matrix from combustible {sup 238}Pu material. Plutonium processing residues are injected into a molten salt bed with an excess of air. The salt (sodium carbonate) functions as a catalyst for the conversion of the organic material to carbon dioxide and water. Reactive species such as fluorine, chlorine, bromine, iodine, sulfur, phosphorous and arsenic in the organic waste react with the molten salt to form the corresponding neutralized salts, NaF, NaCl, NaBr, NaI, Na{sub 2}SO{sub 4}, Na{sub 3}PO{sub 4} and NaAsO{sub 2} or Na{sub 3}AsO4. Plutonium and other metals react with the molten salt and air to form metal salts or oxides. Saturated salt will be recycled and aqueous chemical separation will be used to recover the {sup 238}Pu. The Los Alamos National Laboratory system, which is currently in the conceptual design stage, will be scaled down from current systems for use inside a glovebox.

  6. Voluntary Protection Program Onsite Review, Parsons Corporation Salt Waste

    Office of Environmental Management (EM)

    Processing Facility Construction Project - October 2015 | Department of Energy Corporation Salt Waste Processing Facility Construction Project - October 2015 Voluntary Protection Program Onsite Review, Parsons Corporation Salt Waste Processing Facility Construction Project - October 2015 October 2015 Parsons SWPF Construction Project will continue participating in the Department of Energy Voluntary Protection Program and be elevated to a Star participant. This report summarizes the results

  7. Disposal of NORM waste in salt caverns

    SciTech Connect (OSTI)

    Veil, J.A.; Smith, K.P.; Tomasko, D.; Elcock, D.; Blunt, D.; Williams, G.P.

    1998-07-01

    Some types of oil and gas production and processing wastes contain naturally occurring radioactive materials (NORM). If NORM is present at concentrations above regulatory levels in oil field waste, the waste requires special disposal practices. The existing disposal options for wastes containing NORM are limited and costly. This paper evaluates the legality, technical feasibility, economics, and human health risk of disposing of NORM-contaminated oil field wastes in salt caverns. Cavern disposal of NORM waste is technically feasible and poses a very low human health risk. From a legal perspective, there are no fatal flaws that would prevent a state regulatory agency from approving cavern disposal of NORM. On the basis of the costs charged by caverns currently used for disposal of nonhazardous oil field waste (NOW), NORM waste disposal caverns could be cost competitive with existing NORM waste disposal methods when regulatory agencies approve the practice.

  8. Technical review of Molten Salt Oxidation

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The process was reviewed for destruction of mixed low-level radioactive waste. Results: extensive development work and scaleup has been documented on coal gasification and hazardous waste which forms a strong experience base for this MSO process; it is clearly applicable to DOE wastes such as organic liquids and low-ash wastes. It also has potential for processing difficult-to-treat wastes such as nuclear grade graphite and TBP, and it may be suitable for other problem waste streams such as sodium metal. MSO operating systems may be constructed in relatively small units for small quantity generators. Public perceptions could be favorable if acceptable performance data are presented fairly; MSO will likely require compliance with regulations for incineration. Use of MSO for offgas treatment may be complicated by salt carryover. Figs, tabs, refs.

  9. K Basins isolation barriers summary report

    SciTech Connect (OSTI)

    Strickland, G.C., Westinghouse Hanford

    1996-07-31

    The 105-K East and 105-K West fuel storage basins (105-K Basins) were designed and constructed in the early 1950`s for interim storage of irradiated fuel following its discharge from the reactors. The 105-K- East and 105-K West reactor buildings were constructed first, and the associated storage basins were added about a year later. The construction joint between each reactor building structure and the basin structure included a flexible membrane waterstop to prevent leakage. Water in the storage basins provided both radiation shielding and cooling to remove decay heat from stored fuel until its transfer to the Plutonium Uranium Extraction (PUREX) Facility for chemical processing. The 105-K West Reactor was permanently shut down in February 1970; the 105-K East Reactor was permanently shut down in February 1971. Except for a few loose pieces, fuel stored in the basins at that time was shipped to the PUREX Facility for processing. The basins were then left idle but were kept filled with water. The PUREX Facility was shut down and placed on wet standby in 1972 while N Reactor continued to operate. When the N Reactor fuel storage basin began to approach storage capacity, the decision was made to modify the fuel storage basins at 105-K East and 105-K West to provide additional storage capacity. Both basins were subsequently modified (105-K East in 1975 and 105-K West in 1981) to provide for the interim handling and storage of irradiated N Reactor fuel. The PUREX Facility was restarted in November 1983 to provide 1698 additional weapons-grade plutonium for the United States defense mission. The facility was shut down and deactivated in December 1992 when the U.S. Department of Energy (DOE) determined that the plant was no longer needed to support weapons-grade plutonium production. When the PUREX Facility was shut down, approximately 2.1 x 1 06 kg (2,100 metric tons) of irradiated fuel aged 7 to 23 years was left in storage in the 105-K Basins pending a decision on final disposition of the material. The Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1994), also known as the Tri-Party Agreement, commits to the removal of all fuel and sludge from the 105-K Basins by the year 2002.

  10. K Basins Sludge Treatment Process | Department of Energy

    Energy Savers [EERE]

    Process K Basins Sludge Treatment Process Full Document and Summary Versions are available for download PDF icon K Basins Sludge Treatment Process PDF icon Summary - K Basins Sludge Treatment Process More Documents & Publications Compilation of TRA Summaries K Basins Sludge Treatment Project Phase 1 Technology Readiness Assessment (TRA)/Technology Maturation Plan (TMP) Process Guide

  11. A new family of salts for lithium secondary batteries

    SciTech Connect (OSTI)

    Baril, D.; Beranger, S.; Ravet, N.; Michot, C.; Armand, M.

    2000-07-01

    A novel family of salts suitable for lithium battery application was synthesized and characterized. These salts have a large delocalized anion whose charge is spread over a single SO{sub 2} and a phenyl ring. Remarkable properties were obtained for the lithium N-(3-trifluoromethyl phenyl) trifluoromethanesulfonamide salt or LiTFPTS. The electrochemical stability window is around 4.0 V and its conductivity in solid poly(ethylene oxide) or PEO is close to the one of the lithium perchlorate salt. Calorimetric analysis also showed that LiTFPTS behaves as a plasticizer since it hinders, to a certain extent, the PEO crystallization when it is used in a solid polymer matrix. Above all, its synthesis is quite straightforward and leads to potentially inexpensive salts as the starting amines are made commercially on a large scale.

  12. K Basins Groundwater Monitoring Task, K Basins Closure Project: Report for April, May, and June 2007

    SciTech Connect (OSTI)

    Peterson, Robert E.

    2007-08-08

    This report provides information on groundwater monitoring near the K Basins during April, May, and June 2007. Conditions remained similar to those reported in the previous quarters report, with no evidence in monitoring results to suggest groundwater impact from current loss of shielding water from either basin to the ground. During the current quarter, the first results from two new wells installed between KE Basin and the river became available. Groundwater conditions at each new well are reasonably consistent with adjacent wells and expectations, with the exception of anomalously high chromium concentrations at one of the new wells. The K Basins monitoring network will be modified for FY 2008 to take advantage of new wells recently installed near KW Basin as part of a pump-and-treat system for chromium contamination, and also the new wells recently installed between the KE Basin and the river, which augment long-term monitoring capability in that area.

  13. Parametric study of natural circulation flow in molten salt fuel in molten salt reactor

    SciTech Connect (OSTI)

    Pauzi, Anas Muhamad; Cioncolini, Andrea; Iacovides, Hector

    2015-04-29

    The Molten Salt Reactor (MSR) is one of the most promising system proposed by Generation IV Forum (GIF) for future nuclear reactor systems. Advantages of the MSR are significantly larger compared to other reactor system, and is mainly achieved from its liquid nature of fuel and coolant. Further improvement to this system, which is a natural circulating molten fuel salt inside its tube in the reactor core is proposed, to achieve advantages of reducing and simplifying the MSR design proposed by GIF. Thermal hydraulic analysis on the proposed system was completed using a commercial computation fluid dynamics (CFD) software called FLUENT by ANSYS Inc. An understanding on theory behind this unique natural circulation flow inside the tube caused by fission heat generated in molten fuel salt and tube cooling was briefly introduced. Currently, no commercial CFD software could perfectly simulate natural circulation flow, hence, modeling this flow problem in FLUENT is introduced and analyzed to obtain best simulation results. Results obtained demonstrate the existence of periodical transient nature of flow problem, hence improvements in tube design is proposed based on the analysis on temperature and velocity profile. Results show that the proposed system could operate at up to 750MW core power, given that turbulence are enhanced throughout flow region, and precise molten fuel salt physical properties could be defined. At the request of the authors and the Proceedings Editor the name of the co-author Andrea Cioncolini was corrected from Andrea Coincolini. The same name correction was made in the Acknowledgement section on page 030004-10 and in reference number 4. The updated article was published on 11 May 2015.

  14. Regional geology of Georges Bank basin - OCS Sale 42 drilling results

    SciTech Connect (OSTI)

    High, L.R. Jr.

    1985-02-01

    Industry bid aggressively in OCS Sale 42, spending $816 million. Eight wildcats were drilled in 1981-82 to test 5 major plays. All wells were dry; no potential reservoir or source rocks were found. The tectonic-stratigraphic framework of the Georges Bank basin is that of an Atlantic-type plate margin. Two major unconformities divide the section into prerift, synrift, and postrift sequences. The prerift sequence consists of Paleozoic metasediments in basement fault blocks. Synrift sediments consist of Newark Group equivalents: the Argo Salt and the Iroquoi Formation. The postrift sequence consists of Mohican red beds overlain by progradational wedges, with the carbonate Abenaki Formation at the base. The objective in 4 of the 8 wildcats was the Iroquois Formation. Mobil 312-1 and Shell 357-1 were drilled into a seismic anomaly interpreted to be a reef. This structure was found to be a complex carbonate mound. Exxon 975-1 was drilled on a seismic amplitude anomaly variously interpreted to be the result of salt, coal, or porous carbonates. This anomaly proved to be caused by a salt bed. The objective in Shell 410-1R was carbonate banks over a basement horst block. No significant zones of porosity were found. The remaining 4 wildcats were drilled on Abenaki prospects. Mobil 273-1, Tenneco 187-1d, and Conoco 145-1 were drilled for possible carbonate banks over a salt structure. Only thin oolitic grainstone intervals were found. Exxon 133-1 was based on a seismic anomaly interpreted to be a patch reef. This feature was found to be a volcanic cone.

  15. 183-H Basin sludge treatability test report

    SciTech Connect (OSTI)

    Biyani, R.K.

    1995-12-31

    This document presents the results from the treatability testing of a 1-kg sample of 183-H Basin sludge. Compressive strength measurements, Toxic Characteristic Leach Procedure, and a modified ANSI 16.1 leach test were conducted

  16. Fifteenmile Basin Habitat Enhancement Project: Annual Report...

    Office of Scientific and Technical Information (OSTI)

    This goal was addressed under the Columbia River Basin Fish and Wildlife Program, Measure 703 (c) (1) - Action Item 4.2. Construction of fish habitat structures was completed on ...

  17. Carderock Maneuvering & Seakeeping Basin | Open Energy Information

    Open Energy Info (EERE)

    6.1 Water Type Freshwater Cost(per day) Contact POC Special Physical Features 10.7m deep x 15.2m wide trench along length of tank; the Maneuvering & Seakeeping Basin is spanned...

  18. K-Basins S/RIDS

    SciTech Connect (OSTI)

    Watson, D.J.

    1997-08-01

    The Standards/Requirements Identification Document (S/RID) is a list of the Environmental, Safety, and Health (ES{ampersand}H) and Safeguards and Security (SAS) standards/requirements applicable to the K Basins facility.

  19. Summary - K Basins Sludge Treatment Process

    Office of Environmental Management (EM)

    K Basin DOE is Proces the va at Han subsys oxidati objecti of-fact maturi Eleme Techn The as which seven * M * M * Pr * Pr * As The Ele Site: H roject: K P Report Date: A ited...

  20. Progress Update: H4 Basin Concrete Pour

    ScienceCinema (OSTI)

    None

    2012-06-14

    The Recovery Act funded project in the H area basin. A concrete ditch built longer than half a mile to prevent contaminated water from expanding and to reduce the footprint on the environment.

  1. Ion aggregation in high salt solutions. III. Computational vibrational spectroscopy of HDO in aqueous salt solutions

    SciTech Connect (OSTI)

    Choi, Jun-Ho; Lim, Sohee; Chon, Bonghwan; Cho, Minhaeng; Kim, Heejae; Kim, Seongheun

    2015-05-28

    The vibrational frequency, frequency fluctuation dynamics, and transition dipole moment of the OD stretch mode of HDO molecule in aqueous solutions are strongly dependent on its local electrostatic environment and hydrogen-bond network structure. Therefore, the time-resolved vibrational spectroscopy the OD stretch mode has been particularly used to investigate specific ion effects on water structure. Despite prolonged efforts to understand the interplay of OD vibrational dynamics with local water hydrogen-bond network and ion aggregate structures in high salt solutions, still there exists a gap between theory and experiment due to a lack of quantitative model for accurately describing OD stretch frequency in high salt solutions. To fill this gap, we have performed numerical simulations of Raman scattering and IR absorption spectra of the OD stretch mode of HDO in highly concentrated NaCl and KSCN solutions and compared them with experimental results. Carrying out extensive quantum chemistry calculations on not only water clusters but also ion-water clusters, we first developed a distributed vibrational solvatochromic charge model for the OD stretch mode in aqueous salt solutions. Furthermore, the non-Condon effect on the vibrational transition dipole moment of the OD stretch mode was fully taken into consideration with the charge response kernel that is non-local polarizability density. From the fluctuating OD stretch mode frequencies and transition dipole vectors obtained from the molecular dynamics simulations, the OD stretch Raman scattering and IR absorption spectra of HDO in salt solutions could be calculated. The polarization effect on the transition dipole vector of the OD stretch mode is shown to be important and the asymmetric line shapes of the OD stretch Raman scattering and IR absorption spectra of HDO especially in highly concentrated NaCl and KSCN solutions are in quantitative agreement with experimental results. We anticipate that this computational approach will be of critical use in interpreting linear and nonlinear vibrational spectroscopies of HDO molecule that is considered as an excellent local probe for monitoring local electrostatic and hydrogen-bonding environment in not just salt but also other confined and crowded solutions.

  2. Soil Sampling At Salt Wells Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    Salt Wells Area (Henkle, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Soil Sampling At Salt Wells Area (Henkle, Et Al., 2005)...

  3. Slim Holes At Salt Wells Area (Combs, Et Al., 1999) | Open Energy...

    Open Energy Info (EERE)

    Salt Wells Area (Combs, Et Al., 1999) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Slim Holes At Salt Wells Area (Combs, Et Al., 1999)...

  4. Thermal Gradient Holes At Salt Wells Area (Bureau of Land Management...

    Open Energy Info (EERE)

    Salt Wells Area (Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal Gradient Holes At Salt Wells Area...

  5. Fluoroalkyl containing salts combined with fluorinated solvents for electrolytes

    SciTech Connect (OSTI)

    Tikhonov, Konstantin; Yip, Ka Ki; Lin, Tzu-Yuan; Erickson, Michael Jason

    2015-04-21

    Provided are electrochemical cells and electrolytes used to build such cells. An electrolyte may include a fluoroalkyl-substituted LiPF.sub.6 salt or a fluoroalkyl-substituted LiBF.sub.4 salt. In some embodiments, at least one fluorinated alkyl of the salt has a chain length of from 1 to 8 or, more specifically, between about 2 and 8. These fluorinated alkyl groups, in particular, relatively large fluorinated alkyl groups improve solubility of these salts in fluorinated solvents that are less flammable than, for example, conventional carbonate solvents. At the same time, the size of fluoroalkyl-substituted salts should be limited to ensure adequate concentration of the salt in an electrolyte and low viscosity of the electrolyte. In some embodiments, the concentration of a fluoroalkyl-substituted salt is at least about 0.5M. Examples of fluorinated solvents include various fluorinated esters, fluorinated ethers, and fluorinated carbonates, such a 1-methoxyheptafluoropropane, methyl nonafluorobutyl ether, ethyl nonafluorobutyl ether, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane, 3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-trifluoromethyl-hexane, and 1,1,1,2,3,3-hexafluoro-4-(1,1,2,3,3,3-hexafluoropropoxy)-pentane.

  6. Fast Thorium Molten Salt Reactors Started with Plutonium

    SciTech Connect (OSTI)

    Merle-Lucotte, E.; Heuer, D.; Le Brun, C.; Brissot, R.; Liatard, E.; Meplan, O.; Nuttin, A.

    2006-07-01

    One of the pending questions concerning Molten Salt Reactors based on the {sup 232}Th/{sup 233}U fuel cycle is the supply of the fissile matter, and as a consequence the deployment possibilities of a fleet of Molten Salt Reactors, since {sup 233}U does not exist on earth and is not yet produced in the current operating reactors. A solution may consist in producing {sup 233}U in special devices containing Thorium, in Pressurized Water or Fast Neutrons Reactors. Two alternatives to produce {sup 233}U are examined here: directly in standard Molten Salt Reactors started with Plutonium as fissile matter and then operated in the Th/{sup 233}U cycle; or in dedicated Molten Salt Reactors started and fed with Plutonium as fissile matter and Thorium as fertile matter. The idea is to design a critical reactor able to burn the Plutonium and the minor actinides presently produced in PWRs, and consequently to convert this Plutonium into {sup 233}U. A particular reactor configuration is used, called 'unique channel' configuration in which there is no moderator in the core, leading to a quasi fast neutron spectrum, allowing Plutonium to be used as fissile matter. The conversion capacities of such Molten Salt Reactors are excellent. For Molten Salt Reactors only started with Plutonium, the assets of the Thorium fuel cycle turn out to be quickly recovered and the reactor's characteristics turn out to be equivalent to Molten Salt Reactors operated with {sup 233}U only. Using a combination of Molten Salt Reactors started or operated with Plutonium and of Molten Salt Reactors started with {sup 233}U, the deployment capabilities of these reactors fully satisfy the condition of sustainability. (authors)

  7. Electrolyte materials containing highly dissociated metal ion salts

    DOE Patents [OSTI]

    Lee, Hung-Sui; Geng, Lin; Skotheim, Terje A.

    1996-07-23

    The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity.

  8. Electrolyte materials containing highly dissociated metal ion salts

    DOE Patents [OSTI]

    Lee, H.S.; Geng, L.; Skotheim, T.A.

    1996-07-23

    The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity. 2 figs.

  9. Sol-gel processing with inorganic metal salt precursors

    DOE Patents [OSTI]

    Hu, Zhong-Cheng

    2004-10-19

    Methods for sol-gel processing that generally involve mixing together an inorganic metal salt, water, and a water miscible alcohol or other organic solvent, at room temperature with a macromolecular dispersant material, such as hydroxypropyl cellulose (HPC) added. The resulting homogenous solution is incubated at a desired temperature and time to result in a desired product. The methods enable production of high quality sols and gels at lower temperatures than standard methods. The methods enable production of nanosize sols from inorganic metal salts. The methods offer sol-gel processing from inorganic metal salts.

  10. Gradient zone boundary control in salt gradient solar ponds

    DOE Patents [OSTI]

    Hull, John R.

    1984-01-01

    A method and apparatus for suppressing zone boundary migration in a salt gradient solar pond includes extending perforated membranes across the pond at the boundaries, between the convective and non-convective zones, the perforations being small enough in size to prevent individual turbulence disturbances from penetrating the hole, but being large enough to allow easy molecular diffusion of salt thereby preventing the formation of convective zones in the gradient layer. The total area of the perforations is a sizable fraction of the membrane area to allow sufficient salt diffusion while preventing turbulent entrainment into the gradient zone.

  11. Experimental Investigation of Two-Phase Flow in Rock Salt

    SciTech Connect (OSTI)

    Malama, Bwalya; Howard, Clifford L.

    2014-07-01

    This Test Plan describes procedures for conducting laboratory scale flow tests on intact, damaged, crushed, and consolidated crushed salt to measure the capillary pressure and relative permeability functions. The primary focus of the tests will be on samples of bedded geologic salt from the WIPP underground. However, the tests described herein are directly applicable to domal salt. Samples being tested will be confined by a range of triaxial stress states ranging from atmospheric pressure up to those approximating lithostatic. Initially these tests will be conducted at room temperature, but testing procedures and equipment will be evaluated to determine adaptability to conducting similar tests under elevated temperatures.

  12. Engineering Evaluation of Proposed Alternative Salt Transfer Method for the Molten Salt Reactor Experiement for the Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Carlberg, Jon A.; Roberts, Kenneth T.; Kollie, Thomas G.; Little, Leslie E.; Brady, Sherman D.

    2009-09-30

    This evaluation was performed by Pro2Serve in accordance with the Technical Specification for an Engineering Evaluation of the Proposed Alternative Salt Transfer Method for the Molten Salt Reactor Experiment at the Oak Ridge National Laboratory (BJC 2009b). The evaluators reviewed the Engineering Evaluation Work Plan for Molten Salt Reactor Experiment Residual Salt Removal, Oak Ridge National Laboratory, Oak Ridge, Tennessee (DOE 2008). The Work Plan (DOE 2008) involves installing a salt transfer probe and new drain line into the Fuel Drain Tanks and Fuel Flush Tank and connecting them to the new salt transfer line at the drain tank cell shield. The probe is to be inserted through the tank ball valve and the molten salt to the bottom of the tank. The tank would then be pressurized through the Reactive Gas Removal System to force the salt into the salt canisters. The Evaluation Team reviewed the work plan, interviewed site personnel, reviewed numerous documents on the Molten Salt Reactor (Sects. 7 and 8), and inspected the probes planned to be used for the transfer. Based on several concerns identified during this review, the team recommends not proceeding with the salt transfer via the proposed alternate salt transfer method. The major concerns identified during this evaluation are: (1) Structural integrity of the tanks - The main concern is with the corrosion that occurred during the fluorination phase of the uranium removal process. This may also apply to the salt transfer line for the Fuel Flush Tank. Corrosion Associated with Fluorination in the Oak Ridge National Laboratory Fluoride Volatility Process (Litman 1961) shows that this problem is significant. (2) Continued generation of Fluorine - Although the generation of Fluorine will be at a lower rate than experienced before the uranium removal, it will continue to be generated. This needs to be taken into consideration regardless of what actions are taken with the salt. (3) More than one phase of material - There are likely multiple phases of material in the salt (metal or compound), either suspended through the salt matrix, layered in the bottom of the tank, or both. These phases may contribute to plugging during any planned transfer. There is not enough data to know for sure. (4) Probe heat trace - The alternate transfer method does not include heat tracing of the bottom of the probe. There is a concern that this may cool the salt and other phases of materials present enough to block the flow of salt. (5) Stress-corrosion cracking - Additionally, there is a concern regarding moisture that may have been introduced into the tanks. Due to time constraints, this concern was not validated. However, if moisture was introduced into the tanks and not removed during heating the tanks before HF and F2 sparging, there would be an additional concern regarding the potential for stress-corrosion cracking of the tank walls.

  13. Petroleum geology of principal sedimentary basins in eastern China

    SciTech Connect (OSTI)

    Lee, K.Y.

    1986-05-01

    The principal petroliferous basins in eastern China are the Songliao, Ordos, and Sichuan basins of Mesozoic age, and the North China, Jianghan, Nanxiang, and Subei basins of Cenozoic age. These basins contain mostly continental fluvial and lacustrine detrital sediments. Four different geologic ages are responsible for the oil and gas in this region: (1) Mesozoic in the Songliao, Ordos, and Sichuan basins; (2) Tertiary in the North China, Jianghan, Nanxiang, and Subei basins; (3) Permian-Carboniferous in the southern North China basin and the northwestern Ordos basin; and (4) Sinian in the southern Sichuan basin. The most prolific oil and gas sources are the Mesozoic of the Songliao basin and the Tertiary of the North China basin. Although the major source rocks in these basins are lacustrine mudstone and shale, their tectonic settings and the resultant temperature gradients differ. For example, in the Songliao, North China, and associated basins, trapping conditions commonly are associated with block faulting of an extensional tectonic regime; the extensional tectonics in turn contribute to a high geothermal gradient (40/sup 0/-60/sup 0/C/km), which results in early maturation and migration for relatively shallow deposits. However, the Ordos and Sichuan basins formed under compressional conditions and are cooler. Hence, maturation and migration occurred late, relative to reservoir deposition and burial, the result being a poorer quality reservoir.

  14. Category:Salt Lake City, UT | Open Energy Information

    Open Energy Info (EERE)

    UT Jump to: navigation, search Go Back to PV Economics By Location Media in category "Salt Lake City, UT" The following 16 files are in this category, out of 16 total....

  15. Surface Indicators of Geothermal Activity at Salt Wells, Nevada...

    Open Energy Info (EERE)

    of geothermal fluids. An example is provided by the Salt Wells geothermal system in Churchill County, Nevada, USA, where surface features define a 9-km-long area that matches the...

  16. BLM Approves Salt Wells Geothermal Plant in Churchill County...

    Open Energy Info (EERE)

    Plant in Churchill County Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: BLM Approves Salt Wells Geothermal Plant in Churchill County Abstract...

  17. Project Profile: Deep Eutectic Salt Formulations Suitable as...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    J.W. Raade and D. Padowitz, "Development of Molten Salt Heat Transfer Fluid with Low Melting Point and High Thermal Stability," Journal of Solar Energy Engineering, Vol. 133, No. ...

  18. Climate Action Champions: Salt Lake City, UT | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    decreasing total building energy use in the City by 5 percent, and generating 10 megawatts of solar energy in the community by 2015. In addition, Salt Lake City aims to reduce ...

  19. Prediction of Heat Capacities of Solid Inorganic Salts from Group

    Office of Scientific and Technical Information (OSTI)

    from Group Contributions. )&-SUB -- 7 5- g 7 A. T. M. Golam Mostafa, James M. Eakman* ... a group contribution method for predicting A H ? and A G F of solid inorganic salts. ...

  20. Project Profile: Modular and Scalable Baseload Molten Salt Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    J. E. Pacheco, C. Moursund, D. Rogers; D. Wasyluk. "Conceptual Design of a 100 MWe Modular Molten Salt Power Tower Plant" in Proceedings of SolarPACES 2011, Granada Spain, ...

  1. Salt Wells Geothermal Exploratory Drilling Program EA(DOI-BLM...

    Open Energy Info (EERE)

    Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells Geothermal Exploratory...

  2. Direct esterification of ammonium salts of carboxylic acids

    DOE Patents [OSTI]

    Halpern, Yuval

    2003-06-24

    A non-catalytic process for producing esters, the process comprising reacting an ammonium salt of a carboxylic acid with an alcohol and removing ammonia from the reaction mixture. Selectivities for the desired ester product can exceed 95 percent.

  3. Oxidation of aqueous pollutants using ultrasound: Salt-induced enhancement

    SciTech Connect (OSTI)

    Seymour, J.D.; Gupta, R.B.

    1997-09-01

    Ultrasound can be used to oxidize aqueous pollutants; however, due to economic reasons, higher oxidation/destruction rates are needed. This study reports enhancements of reaction rates by the addition of sodium chloride salt. Using 20 kHz ultrasound, large salt-induced enhancements are observed--6-fold for chlorobenzene, 7-fold for p-ethylphenol, and 3-fold for phenol oxidation. The reaction rate enhancements are proportional to the diethyl ether--water partitioning coefficient of the pollutants. It appears that the majority of oxidation reactions occur in the bubble-bulk interface region. The addition of salt increases the ionic strength of the aqueous phase which drives the organic pollutants toward the bubble-bulk interface. A first order reaction rate equation is proposed which can represent the observed enhancement with a good accuracy. A new sonochemical-waste-oxidation process is proposed utilizing the salt-induced enhancement.

  4. Apparatus and method for making metal chloride salt product

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Homer Glen, IL); Richmann, Michael K. (Carlsbad, NM)

    2007-05-15

    A method of producing metal chlorides is disclosed in which chlorine gas is introduced into liquid Cd. CdCl.sub.2 salt is floating on the liquid Cd and as more liquid CdCl.sub.2 is formed it separates from the liquid Cd metal and dissolves in the salt. The salt with the CdCl.sub.2 dissolved therein contacts a metal which reacts with CdCl.sub.2 to form a metal chloride, forming a mixture of metal chloride and CdCl.sub.2. After separation of bulk Cd from the salt, by gravitational means, the metal chloride is obtained by distillation which removes CdCl.sub.2 and any Cd dissolved in the metal chloride.

  5. Polyimide amic acid salts and polyimide membranes formed therefrom

    DOE Patents [OSTI]

    Ding, Yong; Bikson, Benjamin; Nelson, Joyce Katz; Macheras, James Timothy

    2004-04-06

    The invention relates to preparation and uses of novel polymeric materials, polyimide amic acid salts (PIAAS). The use of these materials for the fabrication of fluid separation membranes is further disclosed.

  6. DOE - Office of Legacy Management -- Salt Lake City Vitro Chemical...

    Office of Legacy Management (LM)

    Vitro Chemical - UT 0-04 FUSRAP Considered Sites Site: Salt Lake City Vitro Chemical (UT.0-04 ) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site ...

  7. Transfer Lines to Connect Liquid Waste Facilities and Salt Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... of tank waste at SRS. SWPF will separate the salt waste into a low-volume, high radioactivity fraction for vitrification in the Defense Waste Processing Facility (DWPF) and ...

  8. Salt River Electric Coop Corp | Open Energy Information

    Open Energy Info (EERE)

    River Electric Coop Corp Jump to: navigation, search Name: Salt River Electric Coop Corp Place: Kentucky References: EIA Form EIA-861 Final Data File for 2010 - File1a1 EIA Form...

  9. Expected brine movement at potential nuclear waste repository salt sites

    SciTech Connect (OSTI)

    McCauley, V.S.; Raines, G.E.

    1987-08-01

    The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

  10. Salt Wells, Eight Mile Flat | Open Energy Information

    Open Energy Info (EERE)

    Eight Mile Flat Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells, Eight Mile Flat Abstract Abstract unavailable. Author Nevada Bureau...

  11. Project Profile: Advanced Nitrate Salt Central Receiver Power Plant

    Broader source: Energy.gov [DOE]

    Abengoa, under the Baseload CSP FOA, will demonstrate a 100-megawatt electrical (MWe) central receiver plant using nitrate salt as the receiver coolant, thermal storage medium, and heat transport fluid in the steam generator.

  12. Molten salt electrolyte battery cell with overcharge tolerance

    DOE Patents [OSTI]

    Kaun, Thomas D.; Nelson, Paul A.

    1989-01-01

    A molten salt electrolyte battery having an increased overcharge tolerance employs a negative electrode with two lithium alloy phases of different electrochemical potential, one of which allows self-discharge rates which permits battery cell equalization.

  13. Molten Salt Heat Transfer Fluid (HTF) - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Molten Salt Heat Transfer Fluid (HTF) Sandia National ... Sandia has developed a heat transfer fluid (HTF) for use at elevated temperatures that has ...

  14. Current and proposed regulations for salt water disposal wells

    SciTech Connect (OSTI)

    Moody, T.

    1994-09-01

    In recent years, all aspects of hydrocarbon exploration and production (E & P) activities have drawn closer scrutiny in terms of existing and potential impairment of the environment. In addition to drilling, production, and transportation activities, the USEPA has focused on the nature of E & P generated wastes, and the subsequent management of both hazardous and nonhazardous E & P wastes. Approximately 98% of all of the volume of wastes generated by E & P activities is salt water associated with the recovery of hydrocarbons. By far the majority of this waste is disposed of in class II salt water disposal wells. Due to the tremendous volume of salt water generated, the USEPA continues to reevaluate the federal class II salt water injection well program, offering comments, revising its interpretation of existing regulations, and promulgating new regulations. The purpose of the presentation will be to provide a review of existing class II federal regulations, and to provide an overview of potential or newly promulgated regulations.

  15. Liquid Salt Heat Exchanger Technology for VHTR Based Applications

    SciTech Connect (OSTI)

    Anderson, Mark; Sridhara, Kumar; Allen, Todd; Peterson, Per

    2012-10-11

    The objective of this research is to evaluate performance of liquid salt fluids for use as a heat carrier for transferring high-temperature process heat from the very high-temperature reactor (VHTR) to chemical process plants. Currently, helium is being considered as the heat transfer fluid; however, the tube size requirements and the power associated with pumping helium may not be economical. Recent work on liquid salts has shown tremendous potential to transport high-temperature heat efficiently at low pressures over long distances. This project has two broad objectives: To investigate the compatibility of Incoloy 617 and coated and uncoated SiC ceramic composite with MgCl2-KCl molten salt to determine component lifetimes and aid in the design of heat exchangers and piping; and, To conduct the necessary research on the development of metallic and ceramic heat exchangers, which are needed for both the helium-to-salt side and salt-to-process side, with the goal of making these heat exchangers technologically viable. The research will consist of three separate tasks. The first task deals with material compatibility issues with liquid salt and the development of techniques for on-line measurement of corrosion products, which can be used to measure material loss in heat exchangers. Researchers will examine static corrosion of candidate materials in specific high-temperature heat transfer salt systems and develop an in situ electrochemical probe to measure metallic species concentrations dissolved in the liquid salt. The second task deals with the design of both the intermediate and process side heat exchanger systems. Researchers will optimize heat exchanger design and study issues related to corrosion, fabrication, and thermal stresses using commercial and in-house codes. The third task focuses integral testing of flowing liquid salts in a heat transfer/materials loop to determine potential issues of using the salts and to capture realistic behavior of the salts in a small scale prototype system. This includes investigations of plugging issues, heat transfer, pressure drop, and the corrosion and erosion of materials in the flowing system.

  16. Liquid Fuel Molten Salt Reactors For Thorium Utilization (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Liquid Fuel Molten Salt Reactors For Thorium Utilization Citation Details In-Document Search Title: Liquid Fuel Molten Salt Reactors For Thorium Utilization Authors: Gehin, Jess C [1] + Show Author Affiliations ORNL Publication Date: 2014-01-01 OSTI Identifier: 1185589 DOE Contract Number: AC05-00OR22725 Resource Type: Conference Resource Relation: Conference: 2014 ANS Winter Meeting and Nuclear Technology Expo, Anaheim, CA, USA, 20141109, 20141113 Research Org: Oak Ridge

  17. Molten salt heat transfer fluids and thermal storage technology.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Molten salt heat transfer fluids and thermal storage technology. Citation Details In-Document Search Title: Molten salt heat transfer fluids and thermal storage technology. No abstract prepared. Authors: Glatzmaier, Greg [1] ; Siegel, Nathan Phillip + Show Author Affiliations (NREL) Publication Date: 2010-06-01 OSTI Identifier: 1020492 Report Number(s): SAND2010-3826C TRN: US201116%%508 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource

  18. Salt Waste Processing Facility, Construction Turnover to Testing and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commissioning Oversight | Department of Energy Construction Turnover to Testing and Commissioning Oversight Salt Waste Processing Facility, Construction Turnover to Testing and Commissioning Oversight This procedure establishes an oversight process for the Salt Waste Processing Facility Project Office (SWPFPO) Integrated Project Team (IPT) personnel assigned to perform oversight of system turnover from Construction to Commissioning and Testing. September 2015 PDF icon Procedure Key Resources

  19. Mechanochemical Preparation of Phosphonium Salts and Phosphorus Ylides -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Industrial Technologies Industrial Technologies Find More Like This Return to Search Mechanochemical Preparation of Phosphonium Salts and Phosphorus Ylides Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Researchers at Iowa State University and Ames Laboratory have developed a unique, solvent-free mechanochemical preparation method to prepare phosphonium salts and phosphorous ylides. The phosphorous ylides are then utilized in carrying

  20. Pyrochemical investigations into recovering plutonium from americium extraction salt residues

    SciTech Connect (OSTI)

    Fife, K.W.; West, M.H.

    1987-05-01

    Progress into developing a pyrochemical technique for separating and recovering plutonium from spent americium extraction waste salts has concentrated on selective chemical reduction with lanthanum metal and calcium metal and on the solvent extraction of americium with calcium metal. Both techniques are effective for recovering plutonium from the waste salt, although neither appears suitable as a separation technique for recycling a plutonium stream back to mainline purification processes. 17 refs., 13 figs., 2 tabs.

  1. CAVERN ROOF STABILITY FOR NATURAL GAS STORAGE IN BEDDED SALT

    SciTech Connect (OSTI)

    DeVries, Kerry L; Mellegard, Kirby D; Callahan, Gary D; Goodman, William M

    2005-06-01

    This report documents research performed to develop a new stress-based criterion for predicting the onset of damage in salt formations surrounding natural gas storage caverns. Laboratory tests were conducted to investigate the effects of shear stress, mean stress, pore pressure, temperature, and Lode angle on the strength and creep characteristics of salt. The laboratory test data were used in the development of the new criterion. The laboratory results indicate that the strength of salt strongly depends on the mean stress and Lode angle. The strength of the salt does not appear to be sensitive to temperature. Pore pressure effects were not readily apparent until a significant level of damage was induced and the permeability was increased to allow penetration of the liquid permeant. Utilizing the new criterion, numerical simulations were used to estimate the minimum allowable gas pressure for hypothetical storage caverns located in a bedded salt formation. The simulations performed illustrate the influence that cavern roof span, depth, roof salt thickness, shale thickness, and shale stiffness have on the allowable operating pressure range. Interestingly, comparison of predictions using the new criterion with that of a commonly used criterion indicate that lower minimum gas pressures may be allowed for caverns at shallow depths. However, as cavern depth is increased, less conservative estimates for minimum gas pressure were determined by the new criterion.

  2. Independent Oversight Review, Savannah River Site Salt Waste Processing Facility- August 2013

    Broader source: Energy.gov [DOE]

    Review of the Savannah River Site Salt Waste Processing Facility Safety Basis and Design Development.

  3. EIS-0099: Remedial Actions at the Former Vitro Chemical Company Site, South Salt Lake, Salt Lake County, Utah

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this statement to evaluate the environmental impacts of various scenarios associated with the cleanup of those residues remaining at the abandoned uranium mill tailings site located in South Salt Lake, Utah.

  4. Independent focuses Philippines exploration on Visayan basin

    SciTech Connect (OSTI)

    Rillera, F.G.

    1995-08-21

    Cophil Exploration Corp., a Filipino public company, spearheaded 1995 Philippine oil and gas exploration activity with the start of its gas delineation drilling operations in Libertad, northern Cebu. Cophil and its Australian partners, Coplex Resources NL and PacRim Energy NL, have set out to complete a seven well onshore drilling program within this block this year. The companies are testing two modest shallow gas plays, Libertad and Dalingding, and a small oil play, Maya, all in northern Cebu about 500 km southeast of Manila. Following a short discussion on the geology and exploration history of the Visayan basin, this article briefly summarizes Cophil`s ongoing Cebu onshore drilling program. Afterwards, discussion focuses on identified exploration opportunities in the basin`s offshore sector.

  5. LIFE Materails: Molten-Salt Fuels Volume 8

    SciTech Connect (OSTI)

    Moir, R; Brown, N; Caro, A; Farmer, J; Halsey, W; Kaufman, L; Kramer, K; Latkowski, J; Powers, J; Shaw, H; Turchi, P

    2008-12-11

    The goals of the Laser Inertial Fusion Fission Energy (LIFE) is to use fusion neutrons to fission materials with no enrichment and minimum processing and have greatly reduced wastes that are not of interest to making weapons. Fusion yields expected to be achieved in NIF a few times per day are called for with a high reliable shot rate of about 15 per second. We have found that the version of LIFE using TRISO fuel discussed in other volumes of this series can be modified by replacing the molten-flibe-cooled TRISO fuel zone with a molten salt in which the same actinides present in the TRISO particles are dissolved in the molten salt. Molten salts have the advantage that they are not subject to radiation damage, and hence overcome the radiation damage effects that may limit the lifetime of solid fuels such as TRISO-containing pebbles. This molten salt is pumped through the LIFE blanket, out to a heat exchanger and back into the blanket. To mitigate corrosion, steel structures in contact with the molten salt would be plated with tungsten or nickel. The salt will be processed during operation to remove certain fission products (volatile and noble and semi-noble fission products), impurities and corrosion products. In this way neutron absorbers (fission products) are removed and neutronics performance of the molten salt is somewhat better than that of the TRISO fuel case owing to the reduced parasitic absorption. In addition, the production of Pu and rare-earth elements (REE) causes these elements to build up in the salt, and leads to a requirement for a process to remove the REE during operation to insure that the solubility of a mixed (Pu,REE)F3 solid solution is not exceeded anywhere in the molten salt system. Removal of the REE will further enhance the neutronics performance. With molten salt fuels, the plant would need to be safeguarded because materials of interest for weapons are produced and could potentially be removed.

  6. A coarse-grained model with implicit salt for RNAs: Predicting 3D structure, stability and salt effect

    SciTech Connect (OSTI)

    Shi, Ya-Zhou; Wang, Feng-Hua; Wu, Yuan-Yan; Tan, Zhi-Jie

    2014-09-14

    To bridge the gap between the sequences and 3-dimensional (3D) structures of RNAs, some computational models have been proposed for predicting RNA 3D structures. However, the existed models seldom consider the conditions departing from the room/body temperature and high salt (1M NaCl), and thus generally hardly predict the thermodynamics and salt effect. In this study, we propose a coarse-grained model with implicit salt for RNAs to predict 3D structures, stability, and salt effect. Combined with Monte Carlo simulated annealing algorithm and a coarse-grained force field, the model folds 46 tested RNAs (?45 nt) including pseudoknots into their native-like structures from their sequences, with an overall mean RMSD of 3.5 and an overall minimum RMSD of 1.9 from the experimental structures. For 30 RNA hairpins, the present model also gives the reliable predictions for the stability and salt effect with the mean deviation ? 1.0 C of melting temperatures, as compared with the extensive experimental data. In addition, the model could provide the ensemble of possible 3D structures for a short RNA at a given temperature/salt condition.

  7. Atlas of major Appalachian basin gas plays

    SciTech Connect (OSTI)

    Aminian, K.; Avary, K.L.; Baranoski, M.T.; Flaherty, K.; Humphreys, M.; Smosna, R.A.

    1995-06-01

    This regional study of gas reservoirs in the Appalachian basin has four main objectives: to organize all of the -as reservoirs in the Appalachian basin into unique plays based on common age, lithology, trap type and other geologic similarities; to write, illustrate and publish an atlas of major gas plays; to prepare and submit a digital data base of geologic, engineering and reservoir parameters for each gas field; and technology transfer to the oil and gas industry during the preparation of the atlas and data base.

  8. Hazard categorization of 105-KE basin debris removal project

    SciTech Connect (OSTI)

    Meichle, R.H.

    1996-01-25

    This supporting document provides the hazard categorization for 105-KE Basin Debris Removal Project activities planned in the K east Basin. All activities are categorized as less than Hazard Category 3.

  9. Colorado Division of Water Resources Denver Basin Webpage | Open...

    Open Energy Info (EERE)

    Denver Basin Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Colorado Division of Water Resources Denver Basin Webpage Abstract This is the...

  10. Designated Ground Water Basin Map | Open Energy Information

    Open Energy Info (EERE)

    Designated Ground Water Basin Map Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Designated Ground Water Basin Map Abstract This webpage provides...

  11. CRAD, Engineering - Office of River Protection K Basin Sludge...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engineering - Office of River Protection K Basin Sludge Waste System CRAD, Engineering - Office of River Protection K Basin Sludge Waste System May 2004 A section of Appendix C to ...

  12. Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor

    SciTech Connect (OSTI)

    Scheele, Randall D.; Casella, Andrew M.

    2010-09-28

    This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

  13. Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Gas Salt Lake City Fuels Vehicles With Natural Gas to someone by E-mail Share Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Facebook Tweet about Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Twitter Bookmark Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Google Bookmark Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Delicious Rank Alternative Fuels Data

  14. In-Drift Precipitates/Salts Model

    SciTech Connect (OSTI)

    P. Mariner

    2003-10-21

    As directed by ''Technical Work Plan For: Engineered Barrier System Department Modeling and Testing FY03 Work Activities'' (BSC 2003 [165601]), the In-Drift Precipitates/Salts (IDPS) model is developed and refined to predict the aqueous geochemical effects of evaporation in the proposed repository. The purpose of this work is to provide a model for describing and predicting the postclosure effects of evaporation and deliquescence on the chemical composition of water within the proposed Engineered Barrier System (EBS). Application of this model is to be documented elsewhere for the Total System Performance Assessment License Application (TSPA-LA). The principal application of this model is to be documented in REV 02 of ''Engineered Barrier System: Physical and Chemical Environment Model'' (BSC 2003 [165601]). The scope of this document is to develop, describe, and validate the IDPS model. This model is a quasi-equilibrium model. All reactions proceed to equilibrium except for several suppressed minerals in the thermodynamic database not expected to form under the proposed repository conditions within the modeling timeframe. In this revision, upgrades to the EQ3/6 code (Version 8.0) and Pitzer thermodynamic database improve the applicable range of the model. These new additions allow equilibrium and reaction-path modeling of evaporation to highly concentrated brines for potential water compositions of the system Na-K-H-Mg-Ca-Al-Cl-F-NO{sub 3}-SO{sub 4}-Br-CO{sub 3}-SiO{sub 2}-CO{sub 2}-O{sub 2}-H{sub 2}O at temperatures in the range of 0 C to 125 C, pressures in the atmospheric range, and relative humidity in the range of 0 to 100 percent. This system applies to oxidizing conditions only, and therefore limits the model to applications involving oxidizing conditions. A number of thermodynamic parameters in the Pitzer database have values that have not been determined or verified for the entire temperature range. In these cases, the known values are used to approximate the values for the rest of the temperature range. Although such treatment contributes to uncertainty in model outputs, the model validation test cases indicate that the model, with its associated uncertainty, is valid for its intended use. The intended use of this model is to estimate and tabulate, within an appropriate level of confidence, the effects of evaporation, deliquescence, and potential environmental conditions on the pH, ionic strength, and chemical compositions of water and minerals on the drip shield or other location within the drift during the postclosure period.

  15. Geothermal Literature Review At Nw Basin & Range Region (Laney...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermal Literature Review At Nw Basin & Range Region (Laney, 2005) Exploration Activity Details...

  16. Fifteenmile Basin Habitat Enhancement Project: Annual Report FY 1990.

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Technical Report: Fifteenmile Basin Habitat Enhancement Project: Annual Report FY 1990. Citation Details In-Document Search Title: Fifteenmile Basin Habitat Enhancement Project: Annual Report FY 1990. The goal of the Fifteenmile Creek Habitat Improvement project is to improve wild winter steelhead habitat in the Fifteenmile Creek Basin. This goal was addressed under the Columbia River Basin Fish and Wildlife Program, Measure 703 (c) (1) - Action Item 4.2.

  17. Modeling-Computer Simulations At Northern Basin & Range Region...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Modeling-Computer Simulations At Northern Basin & Range Region (Pritchett, 2004) Exploration Activity...

  18. Shirley Basin South, Wyoming, Disposal Site Fact Sheet

    Office of Legacy Management (LM)

    Shirley Basin South, Wyoming, Disposal Site This fact sheet provides information about the Shirley Basin South, Wyoming, Disposal Site. This site is managed by the U.S. Department of Energy Office of Legacy Management under Title II of the Uranium Mill Tailings Radiation Control Act of 1978. Location of the Shirley Basin South, Wyoming, Disposal Site Site Description and History The Shirley Basin South disposal site is located in rural Carbon County about 60 miles south of Casper and 35 miles

  19. Molten Salts for High Temperature Reactors: University of Wisconsin Molten Salt Corrosion and Flow Loop Experiments -- Issues Identified and Path Forward

    SciTech Connect (OSTI)

    Piyush Sabharwall; Matt Ebner; Manohar Sohal; Phil Sharpe; Thermal Hydraulics Group

    2010-03-01

    Considerable amount of work is going on regarding the development of high temperature liquid salts technology to meet future process needs of Next Generation Nuclear Plant. This report identifies the important characteristics and concerns of high temperature molten salts (with lesson learned at University of Wisconsin-Madison, Molten Salt Program) and provides some possible recommendation for future work

  20. The sup 36 Cl ages of the brines in the Magadi-Natron basin, east Africa

    SciTech Connect (OSTI)

    Kaufman, A.; Margaritz, M.A.; Hollos, G. ); Paul, M.; Boaretto, E. ); Hillaire-Marcel, C. ); Taieb, M. )

    1990-10-01

    The depression in the East African Rift which includes both Lake Magadi and Lake Natron forms a closed basin within which almost all the dissolved chloride originates in precipitation, since there is no important source of very ancient sedimentary chloride. This provides an ideal setting for the evaluation of the {sup 36}Cl methodology as a geochemical and hydrological tracer. The main source of recent water, as represented by the most dilute samples measured, is characterized by a {sup 36}Cl/Cl ratio of 2.5 {times} 10{sup {minus}14}, in agreement with the calculated value expected in precipitation. Surface evaporation increases the chlorinity of the local freshwater inflow by about a factor of 110 without changing the isotopic ratio, indicating that little chloride enters the system in the form of sediment leachate. A second type of brine found in the basin occurs in a hot deep groundwater reservoir and is characterized by lower {sup 36}Cl/Cl ratios (<1.2 {times} 10{sup {minus}14}). By comparing this value with the 2.5 {times} 10{sup {minus}14} in recent recharge, one obtains an approximate salt accumulation age of 760 Ka which is consistent with thee time of the first appearance of the lake. These older brines also have lower {sup 18}O and {sup 2}H values which indicate that they were recharged during a climatically different era. The {sup 36}Cl/Cl ratios in the inflowing waters and in the accumulated brine, together with the known age of the Lake Magadi basin, may be used to estimate the importance of the hypogene and epigene, as opposed to the meteoric, mode of {sup 36}Cl production. Such a calculation shows that the hypogene and epigene processes together contribute less than 6% of the total {sup 36}Cl present in the lake.

  1. Atmospheric dispersion in mountain valleys and basins

    SciTech Connect (OSTI)

    Allwine, K.J.

    1992-01-01

    The primary goal of the research is to further characterize and understand dispersion in valley and basin atmospheres. A secondary, and related goal, is to identify and understand the dominant physical processes governing this dispersion. This has been accomplished through a review of the current literature, and analyses of recently collected data from two field experiments. This work should contribute to an improved understanding of material transport in the atmospheric boundary layer. It was found that dispersion in a freely draining valley (Brush Creek valley, CO) atmosphere is much greater than in an enclosed basin (Roanoke, VA) atmosphere primarily because of the greater wind speeds moving past the release point and the greater turbulence levels. The development of a cold air pool in the Roanoke basin is the dominant process governing nighttime dispersion in the basin, while the nighttime dispersion in the Brush Creek valley is dominated by turbulent diffusion and plume confinement between the valley sidewalls. The interaction between valley flows and above ridgetops flows is investigated. A ``ventilation rate`` of material transport between the valley and above ridgetop flows is determined. This is important in regional air pollution modeling and global climate modeling. A simple model of dispersion in valleys, applicable through a diurnal cycle, is proposed.

  2. Atmospheric dispersion in mountain valleys and basins

    SciTech Connect (OSTI)

    Allwine, K.J.

    1992-01-01

    The primary goal of the research is to further characterize and understand dispersion in valley and basin atmospheres. A secondary, and related goal, is to identify and understand the dominant physical processes governing this dispersion. This has been accomplished through a review of the current literature, and analyses of recently collected data from two field experiments. This work should contribute to an improved understanding of material transport in the atmospheric boundary layer. It was found that dispersion in a freely draining valley (Brush Creek valley, CO) atmosphere is much greater than in an enclosed basin (Roanoke, VA) atmosphere primarily because of the greater wind speeds moving past the release point and the greater turbulence levels. The development of a cold air pool in the Roanoke basin is the dominant process governing nighttime dispersion in the basin, while the nighttime dispersion in the Brush Creek valley is dominated by turbulent diffusion and plume confinement between the valley sidewalls. The interaction between valley flows and above ridgetops flows is investigated. A ventilation rate'' of material transport between the valley and above ridgetop flows is determined. This is important in regional air pollution modeling and global climate modeling. A simple model of dispersion in valleys, applicable through a diurnal cycle, is proposed.

  3. Vitrification of IFR and MSBR halide salt reprocessing wastes

    SciTech Connect (OSTI)

    Siemer, D.D.

    2013-07-01

    Both of the genuinely sustainable (breeder) nuclear fuel cycles (IFR - Integral Fast Reactor - and MSBR - Molten Salt Breeder Reactor -) studied by the USA's national laboratories would generate high level reprocessing waste (HLRW) streams consisting of a relatively small amount ( about 4 mole %) of fission product halide (chloride or fluoride) salts in a matrix comprised primarily (about 95 mole %) of non radioactive alkali metal halide salts. Because leach resistant glasses cannot accommodate much of any of the halides, most of the treatment scenarios previously envisioned for such HLRW have assumed a monolithic waste form comprised of a synthetic analog of an insoluble crystalline halide mineral. In practice, this translates to making a 'substituted' sodalite ('Ceramic Waste Form') of the IFR's chloride salt-based wastes and fluoroapatite of the MSBR's fluoride salt-based wastes. This paper discusses my experimental studies of an alternative waste management scenario for both fuel cycles that would separate/recycle the waste's halide and immobilize everything else in iron phosphate (Fe-P) glass. It will describe both how the work was done and what its results indicate about how a treatment process for both of those wastes should be implemented (fluoride and chloride behave differently). In either case, this scenario's primary advantages include much higher waste loadings, much lower overall cost, and the generation of a product (glass) that is more consistent with current waste management practices. (author)

  4. CRITICALITY SAFETY OF PROCESSING SALT SOLUTION AT SRS

    SciTech Connect (OSTI)

    Stephens, K; Davoud Eghbali, D; Michelle Abney, M

    2008-01-15

    High level radioactive liquid waste generated as a result of the production of nuclear material for the United States defense program at the Savannah River Site has been stored as 36 million gallons in underground tanks. About ten percent of the waste volume is sludge, composed of insoluble metal hydroxides primarily hydroxides of Mn, Fe, Al, Hg, and most radionuclides including fission products. The remaining ninety percent of the waste volume is saltcake, composed of primarily sodium (nitrites, nitrates, and aluminates) and hydroxides. Saltcakes account for 30% of the radioactivity while the sludge accounts for 70% of the radioactivity. A pilot plant salt disposition processing system has been designed at the Savannah River Site for interim processing of salt solution and is composed of two facilities: the Actinide Removal Process Facility (ARPF) and the Modular Caustic Side Solvent Extraction Unit (MCU). Data from the pilot plant salt processing system will be used for future processing salt at a much higher rate in a new salt processing facility. Saltcake contains significant amounts of actinides, and other long-lived radioactive nuclides such as strontium and cesium that must be extracted prior to disposal as low level waste. The extracted radioactive nuclides will be mixed with the sludge from waste tanks and vitrified in another facility. Because of the presence of highly enriched uranium in the saltcake, there is a criticality concern associated with concentration and/or accumulation of fissionable material in the ARP and MCU.

  5. Fuel salt and container material studies for MOSART transforming system

    SciTech Connect (OSTI)

    Ignatiev, V.; Feynberg, O.; Merzlyakov, A.; Surenkov, A.; Zagnitko, A.; Afonichkin, V.; Bovet, A.; Khokhlov, V.; Subbotin, V.; Gordeev, M.; Panov, A.; Toropov, A.

    2013-07-01

    A study is under progress to examine the feasibility of single stream Molten Salt Actinide Recycling and Transmuting system without and with Th support (MOSART) fuelled with different compositions of actinide tri-fluorides (AnF{sub 3}) from used LWR fuel. New fast-spectrum design options with homogeneous core and fuel salts with high enough solubility for AnF{sub 3} are being examined because of new goals. The flexibility of single fluid MOSART concept with Th support is underlined, particularly, possibility of its operation in self-sustainable mode (Conversion Ratio: CR=1) using different loadings and make up. The paper summarizes the most current status of fuel salt and container material data for the MOSART concept received within ISTC-3749 and ROSATOM-MARS projects. Key physical and chemical properties of various fluoride fuel salts are reported. The issues like salt purification, the electroreduction of U(IV) to U(III) in LiF-ThF{sub 4} and the electroreduction of Yb(III) to Yb(II) in LiF-NaF are detailed.

  6. Method for making a uranium chloride salt product

    DOE Patents [OSTI]

    Miller, William E.; Tomczuk, Zygmunt

    2004-10-05

    The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

  7. Effect of water in salt repositories. Final report

    SciTech Connect (OSTI)

    Baes, C.F. Jr.; Gilpatrick, L.O.; Kitts, F.G.; Bronstein, H.R.; Shor, A.J.

    1983-09-01

    Additional results confirm that during most of the consolidation of polycrystalline salt in brine, the previously proposed rate expression applies. The final consolidation, however, proceeds at a lower rate than predicted. The presence of clay hastens the consolidation process but does not greatly affect the previously observed relationship between permeability and void fraction. Studies of the migration of brine within polycrystalline salt specimens under stress indicate that the principal effect is the exclusion of brine as a result of consolidation, a process that evidently can proceed to completion. No clear effect of a temperature gradient could be identified. A previously reported linear increase with time of the reciprocal permeability of salt-crystal interfaces to brine was confirmed, though the rate of increase appears more nearly proportional to the product of sigma ..delta..P rather than sigma ..delta..P/sup 2/ (sigma is the uniaxial stress normal to the interface and ..delta..P is the hydraulic pressure drop). The new results suggest that a limiting permeability may be reached. A model for the permeability of salt-crystal interfaces to brine is developed that is reasonably consistent with the present results and may be used to predict the permeability of bedded salt. More measurements are needed, however, to choose between two limiting forms of the model.

  8. In-Drift Precipitates/Salts Model

    SciTech Connect (OSTI)

    P. Mariner

    2004-11-09

    This report documents the development and validation of the in-drift precipitates/salts (IDPS) model. The IDPS model is a geochemical model designed to predict the postclosure effects of evaporation and deliquescence on the chemical composition of water within the Engineered Barrier System (EBS) in support of the Total System Performance Assessment for the License Application (TSPA-LA). Application of the model in support of TSPA-LA is documented in ''Engineered Barrier System: Physical and Chemical Environment Model'' (BSC 2004 [DIRS 169860]). Technical Work Plan for: Near-Field Environment and Transport In-Drift Geochemistry Model Report Integration (BSC 2004 [DIRS 171156]) is the technical work plan (TWP) for this report. It called for a revision of the previous version of the report (BSC 2004 [DIRS 167734]) to achieve greater transparency, readability, data traceability, and report integration. The intended use of the IDPS model is to estimate and tabulate, within an appropriate level of confidence, the effects of evaporation, deliquescence, and potential environmental conditions on the pH, ionic strength, and chemical compositions of water and minerals on the drip shield or other location within the drift during the postclosure period. Specifically, the intended use is as follows: (1) To estimate, within an appropriate level of confidence, the effects of evaporation and deliquescence on the presence and composition of water occurring within the repository during the postclosure period (i.e., effects on pH, ionic strength, deliquescence relative humidity, total concentrations of dissolved components in the system Na-K-H-Mg-Ca-Al-Cl-F-NO{sub 3}-SO{sub 4}-Br-CO{sub 3}-SiO{sub 2}-CO{sub 2}-O{sub 2}-H{sub 2}O, and concentrations of the following aqueous species that potentially affect acid neutralizing capacity: HCO{sub 3}{sup -}, CO{sub 3}{sup 2-}, OH{sup -}, H{sup +}, HSO{sub 4}{sup -}, Ca{sup 2+}, Mg{sup 2+}, CaHCO{sub 3}{sup +}, MgHCO{sub 3}{sup +}, HSiO{sub 3}{sup -}, and MgOH{sup +}); (2) To estimate, within an appropriate level of confidence, mineral precipitation resulting from the evaporation of water occurring within the repository during the postclosure period (specifically, minerals of the system Na-K-H-Mg-Ca-Al-Cl-F-NO{sub 3}-SO{sub 4}-Br-CO{sub 3}-SiO{sub 2}-CO{sub 2}-O{sub 2}-H{sub 2}O); (3) To provide a means for abstracting these effects into a set of lookup tables that provide input to downstream models used for performance assessment. The presence and composition of liquid water in the drift depend upon relative humidity, temperature, incoming water composition, in-drift gas composition, and relative rates of evaporation and seepage. In downstream applications of this model, intended input values for these parameters are abstracted results from thermal-hydrological-chemical models, water sample measurements, dust leachate samples, and values used in sensitivity and uncertainty analyses that encompass the expected ranges of these parameters.

  9. Okanogan Basin Spring Spawner Report for 2007.

    SciTech Connect (OSTI)

    Colville Tribes, Department of Fish & Wildlife

    2007-09-01

    The Okanogan Basin Monitoring and Evaluation Program collected data related to spring spawning anadromous salmonid stocks across the entire Okanogan River basin. Data were collected using redd surveys, traps, underwater video, and PIT-tag technology then summarized and analyzed using simple estimate models. From these efforts we estimated that 1,266 summer steelhead spawned in the Okanogan River basin and constructed 552 redds;152 of these fish where of natural origin. Of these, 121 summer steelhead, including 29 of natural origin, created an estimated 70 redds in the Canadian portion of the Okanagan basin. We estimated summer steelhead spawner escapement into each sub-watershed along with the number from natural origin and the number and density of redds. We documented redd desiccation in Loup Loup Creek, habitat utilization in Salmon Creek as a result of a new water lease program, and 10 spring Chinook returning to Omak Creek. High water through most of the redd survey period resulted in development of new modeling techniques and allowed us to survey additional tributaries including the observation of summer steelhead spawning in Wanacut Creek. These 2007 data provide additional support that redd surveys conducted within the United States are well founded and provide essential information for tracking the recovery of listed summer steelhead. Conversely, redd surveys do not appear to be the best approach for enumerating steelhead spawners or there distribution within Canada. We also identified that spawning distributions within the Okanogan River basin vary widely and stocking location may play an over riding roll in this variability.

  10. Analysis of K west basin canister gas

    SciTech Connect (OSTI)

    Trimble, D.J., Fluor Daniel Hanford

    1997-03-06

    Gas and Liquid samples have been collected from a selection of the approximately 3,820 spent fuel storage canisters in the K West Basin. The samples were taken to characterize the contents of the gas and water in the canisters providing source term information for two subprojects of the Spent Nuclear Fuel Project (SNFP) (Fulton 1994): the K Basins Integrated Water Treatment System Subproject (Ball 1996) and the K Basins Fuel Retrieval System Subproject (Waymire 1996). The barrels of ten canisters were sampled for gas and liquid in 1995, and 50 canisters were sampled in a second campaign in 1996. The analysis results from the first campaign have been reported (Trimble 1995a, 1995b, 1996a, 1996b). The analysis results from the second campaign liquid samples have been documented (Trimble and Welsh 1997; Trimble 1997). This report documents the results for the gas samples from the second campaign and evaluates all gas data in terms of expected releases when opening the canisters for SNFP activities. The fuel storage canisters consist of two closed and sealed barrels, each with a gas trap. The barrels are attached at a trunion to make a canister, but are otherwise independent (Figure 1). Each barrel contains up to seven N Reactor fuel element assemblies. A gas space of nitrogen was established in the top 2.2 to 2.5 inches (5.6 to 6.4 cm) of each barrel. Many of the fuel elements were damaged allowing the metallic uranium fuel to be corroded by the canister water. The corrosion releases fission products and generates hydrogen gas. The released gas mixes with the gas-space gas and excess gas passes through the gas trap into the basin water. The canister design does not allow canister water to be exchanged with basin water.

  11. Development of high temperature transport technology for LiCl-KCl eutectic salt in pyroprocessing

    SciTech Connect (OSTI)

    Lee, Sung Ho; Lee, Hansoo; Kim, In Tae; Kim, Jeong-Guk

    2013-07-01

    The development of high-temperature transport technologies for molten salt is a prerequisite and a key issue in the industrialization of pyro-reprocessing for advanced fuel cycle scenarios. The solution of a molten salt centrifugal pump was discarded because of the high corrosion power of a high temperature molten salt, so the suction pump solution was selected. An apparatus for salt transport experiments by suction was designed and tested using LiC-KCl eutectic salt. The experimental results of lab-scale molten salt transport by suction showed a 99.5% transport rate (ratio of transported salt to total salt) under a vacuum range of 100 mtorr - 10 torr at 500 Celsius degrees. The suction system has been integrated to the PRIDE (pyroprocessing integrated inactive demonstration) facility that is a demonstrator using non-irradiated materials (natural uranium and surrogate materials). The performance of the suction pump for the transport of molten salts has been confirmed.

  12. Injector nozzle for molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, William A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA)

    1996-01-01

    An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath.

  13. Analytical methods for determining the reactivity of pyrochemical salts

    SciTech Connect (OSTI)

    Phillips, A.G.; Stakebake, J.L.

    1994-05-01

    Pyrochemical processes used for the purification of plutonium have generated quantities of residue that contain varying amounts of reactive metals such as potassium, sodium, calcium, and magnesium. These residues are currently considered hazardous and are being managed under RCRA because of the reactivity characteristic. This designation is based solely on process knowledge. Currently there is no approved procedure for determining the reactivity of a solid with water. A method is being developed to rapidly evaluate the reactivity of pyrochemical salts with water by measuring the rate of hydrogen generation. The method was initially tested with a magnesium containing pyrochemical salt. A detection limit of approximately 0.004 g of magnesium was established. A surrogate molten salt extraction residue was also tested. Extrapolation of test data resulted in a hydrogen generation rate of 4.4 mg/(g min).

  14. Injector nozzle for molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, W.A.; Upadhye, R.S.

    1996-02-13

    An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath. 2 figs.

  15. Current and proposed regulations for salt-water disposal wells

    SciTech Connect (OSTI)

    Moody, T.

    1994-12-31

    In recent years, all aspects of hydrocarbon exploration and production (E&P) activities have drawn closer scrutiny in terms of existing and potential impairment of the environment. In addition to drilling, production, and transportation activities, the United States Environmental Protection Agency (USEPA) has focused on the nature of E&P wastes. Approximately 98% of the volume of wastes generated by E&P activities is salt water associated with the recovery of hydrocarbons. By far the majority of this waste is reinjected in Class II wells as a nonhazardous waste. Due to the tremendous volume of salt water disposed of in Class II injection wells, the USEPA continues to reevaluate the Federal salt-water injection well program, offering comments, revising its interpretation of existing regulations, and promulgating new regulations. The purpose of this paper is to provide a review of existing Federal Class II injection well regulations and to provide an overview of potential of newly promulgated regulations.

  16. Salt transport extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Pierce, R.D.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Miller, W.E.

    1992-11-03

    A process is described for separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl[sub 2] and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750 C to about 850 C to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl[sub 2] having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO[sub 2]. The Ca metal and CaCl[sub 2] is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including MgCl[sub 2] to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy. 2 figs.

  17. Salt transport extraction of transuranium elements from lwr fuel

    DOE Patents [OSTI]

    Pierce, R. Dean; Ackerman, John P.; Battles, James E.; Johnson, Terry R.; Miller, William E.

    1992-01-01

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl.sub.2 and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750.degree. C. to about 850.degree. C. to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl.sub.2 having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO.sub.2. The Ca metal and CaCl.sub.2 is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including Mg Cl.sub.2 to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy.

  18. Simulation of water transport in heated rock salt

    SciTech Connect (OSTI)

    Schlich, M.; Jockwer, N.

    1986-01-01

    This paper summarizes computer simulation studies on water transport in German rock salt. Based on JOCKWERS experimental investigations on water content and water liberation, the object of these studies was to select a water transport model, that matches the water inflow which was measured in some heater experiments in the Asse Salt Mine. The main result is, that an evaporation front model, with Knudsen-type vapor transport combined with fluid transport by thermal expansion of the adsorbed water layers in the non evaporated zone, showed the best agreement with experimental evidence.

  19. Materials and methods for stabilizing nanoparticles in salt solutions

    DOE Patents [OSTI]

    Robinson, David Bruce; Zuckermann, Ronald; Buffleben, George M.

    2013-06-11

    Sequence-specific polymers are proving to be a powerful approach to assembly and manipulation of matter on the nanometer scale. Ligands that are peptoids, or sequence-specific N-functional glycine oligomers, allow precise and flexible control over the arrangement of binding groups, steric spacers, charge, and other functionality. We have synthesized short peptoids that can prevent the aggregation of gold nanoparticles in high-salt environments including divalent salt, and allow co-adsorption of a single DNA molecule. This degree of precision and versatility is likely to prove essential in bottom-up assembly of nanostructures and in biomedical applications of nanomaterials.

  20. Molten-Salt-Based Growth of Group III Nitrides

    DOE Patents [OSTI]

    Waldrip, Karen E.; Tsao, Jeffrey Y.; Kerley, Thomas M.

    2008-10-14

    A method for growing Group III nitride materials using a molten halide salt as a solvent to solubilize the Group-III ions and nitride ions that react to form the Group III nitride material. The concentration of at least one of the nitride ion or Group III cation is determined by electrochemical generation of the ions.

  1. Sealing of boreholes using natural, compatible materials: Granular salt

    SciTech Connect (OSTI)

    Finley, R.E.; Zeuch, D.H.; Stormont, J.C.; Daemen, J.J.K.

    1994-05-01

    Granular salt can be used to construct high performance permanent seals in boreholes which penetrate rock salt formations. These seals are described as seal systems comprised of the host rock, the seal material, and the seal rock interface. The performance of these seal systems is defined by the complex interactions between these seal system components through time. The interactions are largely driven by the creep of the host formation applying boundary stress on the seal forcing host rock permeability with time. The immediate permeability of these seals is dependent on the emplaced density. Laboratory test results suggest that careful emplacement techniques could results in immediate seal system permeability on the order of 10{sup {minus}16} m{sup 2} to 10{sup {minus}18} m{sup 2} (10{sup {minus}4} darcy to 10{sup {minus}6}). The visco-plastic behavior of the host rock coupled with the granular salts ability to ``heal`` or consolidate make granular salt an ideal sealing material for boreholes whose permanent sealing is required.

  2. Molten salt processing of mixed wastes with offgas condensation

    SciTech Connect (OSTI)

    Cooper, J.F.; Brummond, W.; Celeste, J.; Farmer, J.; Hoenig, C.; Krikorian, O.H.; Upadhye, R. ); Gay, R.L.; Stewart, A.; Yosim, S. . Energy Systems Group)

    1991-05-13

    We are developing an advanced process for treatment of mixed wastes in molten salt media at temperatures of 700--1000{degrees}C. Waste destruction has been demonstrated in a single stage oxidation process, with destruction efficiencies above 99.9999% for many waste categories. The molten salt provides a heat transfer medium, prevents thermal surges, and functions as an in situ scrubber to transform the acid-gas forming components of the waste into neutral salts and immobilizes potentially fugitive materials by a combination of particle wetting, encapsulation and chemical dissolution and solvation. Because the offgas is collected and assayed before release, and wastes containing toxic and radioactive materials are treated while immobilized in a condensed phase, the process avoids the problems sometimes associated with incineration processes. We are studying a potentially improved modification of this process, which treats oxidizable wastes in two stages: pyrolysis followed by catalyzed molten salt oxidation of the pyrolysis gases at ca. 700{degrees}C. 15 refs., 5 figs., 1 tab.

  3. TGS measurements of pyrochemical salts at Rocky Flats

    SciTech Connect (OSTI)

    Mercer, D. J.; Hansen, J. S.; Lestone, J. P.; Prettyman, T. H.

    2001-01-01

    A new skid-mounted tomographic gamma scanner (TGS) was designed to assist in the decommissioning of Rocky Flats Building 37 1, This instrument was used to assay pyrochemical salts as a prerequisite for disposal at the Waste Isolation Pilot Plant (WIPP). The following paper discusses measurement challenges and results from the first year of operation of the instrument.

  4. Salt Lake City, Utah: Solar in Action (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01

    This brochure provides an overview of the challenges and successes of Salt Lake City, UT, a 2007 Solar America City awardee, on the path toward becoming a solar-powered community. Accomplishments, case studies, key lessons learned, and local resource information are given.

  5. Project Profile: Long-Shafted Molten Salt Pump

    Broader source: Energy.gov [DOE]

    Pratt & Whitney Rocketdyne (PWR), under the CSP R&D FOA, is validating the manufacturability of a large-scale molten salt receiver panel and then confirming its operation in prototypic solar flux. This work is an important step in reducing the LCOE from a central receiver solar power plant.

  6. Decommissioning of the Molten Salt Reactor Experiment: A technical evaluation

    SciTech Connect (OSTI)

    Notz, K.J.

    1988-01-01

    This report completes a technical evaluation of decommissioning planning for the former Molten Salt Reactor Experiment, which was shut down in December, 1969. The key issues revolve around the treatment and disposal of some five tons of solid fuel salt which contains over 30 kg of fissionable uranium-233 plus fission products and higher actinides. The chemistry of this material is complicated by the formation of elemental fluorine via a radiolysis reaction under certain conditions. Supporting studies carried out as part of this evaluation include (a) a broad scope analysis of possible options for storage/disposal of the salts, (b) calculation of nuclide decay in future years, (c) technical evaluation of the containment facility and hot cell penetrations, (d) review and update of surveillance and maintenance procedures, (e) measurements of facility groundwater radioactivity and sump pump operation, (f) laboratory studies of the radiolysis reaction, and (g) laboratory studies which resulted in finding a suitable getter for elemental fluorine. In addition, geologic and hydrologic factors of the surrounding area were considered, and also the implications of entombment of the fuel in-place with concrete. The results of this evaluation show that the fuel salt cannot be left in its present form and location permanently. On the other hand, extended storage in its present form is quite acceptable for 20 to 30 years, or even longer. For continued storage in-place, some facility modifications are recommended. 30 refs., 5 figs., 9 tabs.

  7. Sample Results from Routine Salt Batch 7 Samples

    SciTech Connect (OSTI)

    Peters, T.

    2015-05-13

    Strip Effluent Hold Tank (SEHT) and Decontaminated Salt Solution Hold Tank (DSSHT) samples from several of the microbatches of Integrated Salt Disposition Project (ISDP) Salt Batch (Macrobatch) 7B have been analyzed for 238Pu, 90Sr, 137Cs, Inductively Coupled Plasma Emission Spectroscopy (ICPES), and Ion Chromatography Anions (IC-A). The results from the current microbatch samples are similar to those from earlier samples from this and previous macrobatches. The Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU) continue to show more than adequate Pu and Sr removal, and there is a distinct positive trend in Cs removal, due to the use of the Next Generation Solvent (NGS). The Savannah River National Laboratory (SRNL) notes that historically, most measured Concentration Factor (CF) values during salt processing have been in the 12-14 range. However, recent processing gives CF values closer to 11. This observation does not indicate that the solvent performance is suffering, as the Decontamination Factor (DF) has still maintained consistently high values. Nevertheless, SRNL will continue to monitor for indications of process upsets. The bulk chemistry of the DSSHT and SEHT samples do not show any signs of unusual behavior.

  8. Evaluation of Sichuan Basin in China

    SciTech Connect (OSTI)

    Zhou, J.G.

    1996-06-01

    Sichuan basin lies in the central-south China, in a compression tectonic regime, with an area of approximately 180,000 km{sup 2}. It is a prolific basin with a upside resource potential of gas 5045.38 billion m{sup 3}, and oil 3.56 billion tons. By year-end 1993, the possible geological reserve of gas was 676.136 billion m{sup 3}, and oil 0.14 billion tons; totally about 140 billion m{sup 3} of gas and about 3.5 million tons of oil have been produced to date; thus, there will be 4,229 billion m{sup 3} gas yet to find. During about 40 years` exploration (1950 to 1990), 81 gas/oil fields, including 245 gas pools and 15 oil pools, had been discovered through 2357 wells (total footage 5,804,094 m). 257 surface structures and 189 buried structures (by 91,136 km seismic) had been found in the basin, of which 172 structures had been drilled. The basin contains 21 gas/oil reservoirs of commercial value, distributed from Sinian to Jurassic, in the depths ranging from 7,157 m (well-Guanji) to hundreds of meters. It is evident that the gas and water distribution is not controlled by regional structures or local anticlinal structure but depends on the local development of permeability and fracture porosity in reservoir objectives. Each local occurrence of permeability and porosity functions as a trap for both gas and water, and new gas reservoirs are continuously being found on anticlinal gas fields that have been on production for years.

  9. K Basin sludge treatment process description

    SciTech Connect (OSTI)

    Westra, A.G.

    1998-08-28

    The K East (KE) and K West (KW) fuel storage basins at the 100 K Area of the Hanford Site contain sludge on the floor, in pits, and inside fuel storage canisters. The major sources of the sludge are corrosion of the fuel elements and steel structures in the basin, sand intrusion from outside the buildings, and degradation of the structural concrete that forms the basins. The decision has been made to dispose of this sludge separate from the fuel elements stored in the basins. The sludge will be treated so that it meets Tank Waste Remediation System (TWRS) acceptance criteria and can be sent to one of the double-shell waste tanks. The US Department of Energy, Richland Operations Office accepted a recommendation by Fluor Daniel Hanford, Inc., to chemically treat the sludge. Sludge treatment will be done by dissolving the fuel constituents in nitric acid, separating the insoluble material, adding neutron absorbers for criticality safety, and reacting the solution with caustic to co-precipitate the uranium and plutonium. A truck will transport the resulting slurry to an underground storage tank (most likely tank 241-AW-105). The undissolved solids will be treated to reduce the transuranic (TRU) and content, stabilized in grout, and transferred to the Environmental Restoration Disposal Facility (ERDF) for disposal. This document describes a process for dissolving the sludge to produce waste streams that meet the TWRS acceptance criteria for disposal to an underground waste tank and the ERDF acceptance criteria for disposal of solid waste. The process described is based on a series of engineering studies and laboratory tests outlined in the testing strategy document (Flament 1998).

  10. Methods of producing sulfate salts of cations from heteroatomic compounds and dialkyl sulfates and uses thereof

    DOE Patents [OSTI]

    Friesen, Cody A.; Wolfe, Derek; Johnson, Paul Bryan

    2015-09-29

    Methods of preparing sulfate salts of heteroatomic compounds using dialkyl sulfates as a primary reactant are disclosed. Also disclosed are methods of making ionic liquids from the sulfate salts of the heteroatomic compound, and electrochemical cells comprising the ionic liquids.

  11. Corrosion in Very High-Temperature Molten Salt for Next Generation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Corrosion in Very High-Temperature Molten Salt for Next Generation CSP Systems Corrosion in Very High-Temperature Molten Salt for Next Generation CSP Systems This presentation was ...

  12. Sample results from the interim salt disposition program macrobatch 9 tank 21H qualification samples

    SciTech Connect (OSTI)

    Peters, T. B.

    2015-11-01

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 9 for the Interim Salt Disposition Program (ISDP). This document reports characterization data on the samples of Tank 21H.

  13. Annular core liquid-salt cooled reactor with multiple fuel and...

    Office of Scientific and Technical Information (OSTI)

    Annular core liquid-salt cooled reactor with multiple fuel and blanket zones Citation Details In-Document Search Title: Annular core liquid-salt cooled reactor with multiple fuel ...

  14. Molten Salt Test Loop (MSTL) system customer interface document.

    SciTech Connect (OSTI)

    Gill, David Dennis; Kolb, William J.; Briggs, Ronald D.

    2013-09-01

    The National Solar Thermal Test Facility at Sandia National Laboratories has a unique test capability called the Molten Salt Test Loop (MSTL) system. MSTL is a test capability that allows customers and researchers to test components in flowing, molten nitrate salt. The components tested can range from materials samples, to individual components such as flex hoses, ball joints, and valves, up to full solar collecting systems such as central receiver panels, parabolic troughs, or linear Fresnel systems. MSTL provides realistic conditions similar to a portion of a concentrating solar power facility. The facility currently uses 60/40 nitrate %E2%80%9Csolar salt%E2%80%9D and can circulate the salt at pressure up to 40 bar (600psi), temperature to 585%C2%B0C, and flow rate of 44-50kg/s(400-600GPM) depending on temperature. The purpose of this document is to provide a basis for customers to evaluate the applicability to their testing needs, and to provide an outline of expectations for conducting testing on MSTL. The document can serve as the basis for testing agreements including Work for Others (WFO) and Cooperative Research and Development Agreements (CRADA). While this document provides the basis for these agreements and describes some of the requirements for testing using MSTL and on the site at Sandia, the document is not sufficient by itself as a test agreement. The document, however, does provide customers with a uniform set of information to begin the test planning process.

  15. Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids

    SciTech Connect (OSTI)

    Raade, Justin; Roark, Thomas; Vaughn, John; Bradshaw, Robert

    2013-07-22

    Concentrating solar power (CSP) facilities are comprised of many miles of fluid-filled pipes arranged in large grids with reflective mirrors used to capture radiation from the sun. Solar radiation heats the fluid which is used to produce steam necessary to power large electricity generation turbines. Currently, organic, oil-based fluid in the pipes has a maximum temperature threshold of 400 °C, allowing for the production of electricity at approximately 15 cents per kilowatt hour. The DOE hopes to foster the development of an advanced heat transfer fluid that can operate within higher temperature ranges. The new heat transfer fluid, when used with other advanced technologies, could significantly decrease solar electricity cost. Lower costs would make solar thermal electricity competitive with gas and coal and would offer a clean, renewable source of energy. Molten salts exhibit many desirable heat transfer qualities within the range of the project objectives. Halotechnics developed advanced heat transfer fluids (HTFs) for application in solar thermal power generation. This project focused on complex mixtures of inorganic salts that exhibited a high thermal stability, a low melting point, and other favorable characteristics. A high-throughput combinatorial research and development program was conducted in order to achieve the project objective. Over 19,000 candidate formulations were screened. The workflow developed to screen various chemical systems to discover salt formulations led to mixtures suitable for use as HTFs in both parabolic trough and heliostat CSP plants. Furthermore, salt mixtures which will not interfere with fertilizer based nitrates were discovered. In addition for use in CSP, the discovered salt mixtures can be applied to electricity storage, heat treatment of alloys and other industrial processes.

  16. BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Lee, S.

    2012-05-10

    Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. A three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.

  17. Electrodialysis-based separation process for salt recovery and recycling from waste water

    DOE Patents [OSTI]

    Tsai, Shih-Perng

    1997-01-01

    A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid.

  18. Electrodialysis-based separation process for salt recovery and recycling from waste water

    DOE Patents [OSTI]

    Tsai, S.P.

    1997-07-08

    A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants-containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid. 6 figs.

  19. Summary - Salt Waste Processing Facility Design at the Savannah River Site

    Office of Environmental Management (EM)

    Salt Waste Processing Facility ETR Report Date: November 2006 ETR-4 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of the Salt Waste Processing Facility Design at the Savannah River Site (SRS) Why DOE-EM Did This Review The Salt Waste Processing Facility (SWPF) is intended to remove and concentrate the radioactive strontium (Sr), actinides, and cesium (Cs) from the bulk salt waste solutions in the SRS high-level waste tanks. The sludge

  20. Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc

    2003-06-24

    A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

  1. NATURAL GAS RESOURCES IN DEEP SEDIMENTARY BASINS

    SciTech Connect (OSTI)

    Thaddeus S. Dyman; Troy Cook; Robert A. Crovelli; Allison A. Henry; Timothy C. Hester; Ronald C. Johnson; Michael D. Lewan; Vito F. Nuccio; James W. Schmoker; Dennis B. Riggin; Christopher J. Schenk

    2002-02-05

    From a geological perspective, deep natural gas resources are generally defined as resources occurring in reservoirs at or below 15,000 feet, whereas ultra-deep gas occurs below 25,000 feet. From an operational point of view, ''deep'' is often thought of in a relative sense based on the geologic and engineering knowledge of gas (and oil) resources in a particular area. Deep gas can be found in either conventionally-trapped or unconventional basin-center accumulations that are essentially large single fields having spatial dimensions often exceeding those of conventional fields. Exploration for deep conventional and unconventional basin-center natural gas resources deserves special attention because these resources are widespread and occur in diverse geologic environments. In 1995, the U.S. Geological Survey estimated that 939 TCF of technically recoverable natural gas remained to be discovered or was part of reserve appreciation from known fields in the onshore areas and State waters of the United. Of this USGS resource, nearly 114 trillion cubic feet (Tcf) of technically-recoverable gas remains to be discovered from deep sedimentary basins. Worldwide estimates of deep gas are also high. The U.S. Geological Survey World Petroleum Assessment 2000 Project recently estimated a world mean undiscovered conventional gas resource outside the U.S. of 844 Tcf below 4.5 km (about 15,000 feet). Less is known about the origins of deep gas than about the origins of gas at shallower depths because fewer wells have been drilled into the deeper portions of many basins. Some of the many factors contributing to the origin of deep gas include the thermal stability of methane, the role of water and non-hydrocarbon gases in natural gas generation, porosity loss with increasing thermal maturity, the kinetics of deep gas generation, thermal cracking of oil to gas, and source rock potential based on thermal maturity and kerogen type. Recent experimental simulations using laboratory pyrolysis methods have provided much information on the origins of deep gas. Technologic problems are one of the greatest challenges to deep drilling. Problems associated with overcoming hostile drilling environments (e.g. high temperatures and pressures, and acid gases such as CO{sub 2} and H{sub 2}S) for successful well completion, present the greatest obstacles to drilling, evaluating, and developing deep gas fields. Even though the overall success ratio for deep wells is about 50 percent, a lack of geological and geophysical information such as reservoir quality, trap development, and gas composition continues to be a major barrier to deep gas exploration. Results of recent finding-cost studies by depth interval for the onshore U.S. indicate that, on average, deep wells cost nearly 10 times more to drill than shallow wells, but well costs and gas recoveries vary widely among different gas plays in different basins. Based on an analysis of natural gas assessments, many topical areas hold significant promise for future exploration and development. One such area involves re-evaluating and assessing hypothetical unconventional basin-center gas plays. Poorly-understood basin-center gas plays could contain significant deep undiscovered technically-recoverable gas resources.

  2. K Basins fuel encapsulation and storage hazard categorization

    SciTech Connect (OSTI)

    Porten, D.R.

    1994-12-01

    This document establishes the initial hazard categorization for K-Basin fuel encapsulation and storage in the 100 K Area of the Hanford site. The Hazard Categorization for K-Basins addresses the potential for release of radioactive and non-radioactive hazardous material located in the K-Basins and their supporting facilities. The Hazard Categorization covers the hazards associated with normal K-Basin fuel storage and handling operations, fuel encapsulation, sludge encapsulation, and canister clean-up and disposal. The criteria categorizes a facility based on total curies per radionuclide located in the facility. Tables 5-3 and 5-4 display the results in section 5.0. In accordance with DOE-STD-1027 and the analysis provided in section 5.0, the K East Basin fuel encapsulation and storage activity and the K West Basin storage are classified as a {open_quotes}Category 2{close_quotes} Facility.

  3. Bases, Assumptions, and Results of the Flowsheet Calculations for the Decision Phase Salt Disposition Alternatives

    SciTech Connect (OSTI)

    Elder, H.H.

    2001-07-11

    The HLW salt waste (salt cake and supernate) now stored at the SRS must be treated to remove insoluble sludge solids and reduce the soluble concentration of radioactive cesium radioactive strontium and transuranic contaminants (principally Pu and Np). These treatments will enable the salt solution to be processed for disposal as saltstone, a solid low-level waste.

  4. Sample Results from the Interim Salt Disposition Program Macrobatch 6 Tank 21H Qualification Samples

    SciTech Connect (OSTI)

    Peters, T. B.; Fink, S. D.

    2012-12-11

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 6 for the Interim Salt Disposition Project (ISDP). This document reports partial results of the analyses of samples of Tank 21H. No issues with the projected Salt Batch 6 strategy are identified.

  5. Sample Results From The Interim Salt Disposition Program Macrobatch 6 Tank 21H Qualification Samples

    SciTech Connect (OSTI)

    Peters, T. B.; Fink, S. D.

    2012-12-20

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 6 for the Interim Salt Disposition Project (ISDP). This document reports partial results of the analyses of samples of Tank 21H. No issues with the projected Salt Batch 6 strategy are identified.

  6. K basins interim remedial action health and safety plan

    SciTech Connect (OSTI)

    DAY, P.T.

    1999-09-14

    The K Basins Interim Remedial Action Health and Safety Plan addresses the requirements of the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA), as they apply to the CERCLA work that will take place at the K East and K West Basins. The provisions of this plan become effective on the date the US Environmental Protection Agency issues the Record of Decision for the K Basins Interim Remedial Action, currently planned in late August 1999.

  7. Cold test data for equipment acceptance into 105-KE Basin

    SciTech Connect (OSTI)

    Packer, M.J.

    1994-11-09

    This document provides acceptance testing of equipment to be installed in the 105-KE Basin for pumping sludge to support the discharge chute barrier doors installation.

  8. EIS-0522: Melvin R. Sampson Hatchery, Yakima Basin Coho Project...

    Energy Savers [EERE]

    Sampson Hatchery, Yakima Basin Coho Project; Kittitas County, Washington Contact Dave Goodman jdgoodman@bpa.gov (503) 230-4764 More Information http:efw.bpa.gov...

  9. CO2 Saline Storage Demonstration in Colorado Sedimentary Basins...

    Office of Scientific and Technical Information (OSTI)

    future increase in industrial efforts at CO2 storage in Colorado sedimentary basins. ... As a more sustainable energy industry is becoming a global priority, it is imperative to ...

  10. EIS-0495: Walla Walla Basin Spring Chinook Hatchery Program;...

    Broader source: Energy.gov (indexed) [DOE]

    Walla Walla Basin Spring Chinook Hatchery Program Public Comment Opportunities No public comment opportunities available at this time. Documents Available for Download...

  11. Geographic Information System At Northern Basin & Range Region...

    Open Energy Info (EERE)

    Nash & Johnson, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geographic Information System At Northern Basin & Range Region (Nash &...

  12. California - Los Angeles Basin Onshore Natural Gas Plant Liquids...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Natural Gas Plant Liquids, Proved Reserves (Million Barrels) California - Los Angeles Basin Onshore Natural Gas Plant Liquids, Proved Reserves (Million Barrels) Decade Year-0 ...

  13. California - San Joaquin Basin Onshore Natural Gas Plant Liquids...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Natural Gas Plant Liquids, Proved Reserves (Million Barrels) California - San Joaquin Basin Onshore Natural Gas Plant Liquids, Proved Reserves (Million Barrels) Decade Year-0 ...

  14. Geographic Information System At Northern Basin & Range Region...

    Open Energy Info (EERE)

    DOE-funding Unknown References Mark Coolbaugh, Richard Zehner, Corne Kreemer, David Blackwell, Gary Oppliger (2005) A Map Of Geothermal Potential For The Great Basin,...

  15. The petroleum geology of the sub-Andean basins

    SciTech Connect (OSTI)

    Mathalone, J.M.P.

    1996-08-01

    The sub-Andean trend of basins spans the entire length of South America from Venezuela in the north to Argentina in the south. All the basins produce hydrocarbons with the exception of the Argentinean Bolsones complex and the Peruvian Madro de Dios which is prospective but virtually unexplored. There have been some 119 billion barrels of oil and 190 TCF of gas discovered to date, comprising 93% of the continent`s oil reserves. The basins lie immediately east of the Andes mountain range and are mainly asymmetric Upper Tertiary, westerly dipping foreland basins that overlie a series of earlier Tertiary, Mesozoic and Paleozoic depocentres. All the basins have been compressively deformed as recently as the Upper Miocene, by the eastwards growth of the Andean Cordillera. Giant oil and gas fields sourced from shales of varying age, have been found along the whole trend of basins, with a predominance of gas in the south. The rich marine Upper Cretaceous La Luna and equivalent shales of Venezuela, Colombia and Ecuador have been responsible for generating 86% of the hydrocarbons discovered to date in the sub-Andean basins. Proven sources include Devonian, Carboniferous, Permian and Triassic shales in the central area, comprising Peru, Bolivia and northern Argentina. In southern Argentina, oils have been sourced from Uppermost Jurassic and Lower Cretaceous marine and lacustrine shales. Over 7500 wildcat wells have been drilled in basins along the trend, with a 15% success rate. Many of the basins are very lightly explored, with considerable potential for future discoveries.

  16. Kinematic model for postorogenic Basin and Range extension |...

    Open Energy Info (EERE)

    Article: Kinematic model for postorogenic Basin and Range extension Abstract The Raft River extensional shear zone is exposed in the Albion-Raft River-Grouse Creek...

  17. Lithium In Tufas Of The Great Basin- Exploration Implications...

    Open Energy Info (EERE)

    In Tufas Of The Great Basin- Exploration Implications For Geothermal Energy And Lithium Resources Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference...

  18. Field Mapping At Northern Basin and Range Geothermal Region ...

    Open Energy Info (EERE)

    extension over broad areas of the northern Basin and Range. References Dumitru, T.; Miller, E.; Savage, C.; Gans, P.; Brown, R. (1 April 1993) Fission track evidence for...

  19. Isotopic Analysis At Nw Basin & Range Region (Laney, 2005) |...

    Open Energy Info (EERE)

    Location Northwest Basin and Range Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  20. Compound and Elemental Analysis At Nw Basin & Range Region (Laney...

    Open Energy Info (EERE)

    Northwest Basin and Range Geothermal Region Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical...

  1. Compound and Elemental Analysis At Northern Basin & Range Region...

    Open Energy Info (EERE)

    Northern Basin and Range Geothermal Region Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical...

  2. Isotopic Analysis At Northern Basin & Range Region (Laney, 2005...

    Open Energy Info (EERE)

    Location Northern Basin and Range Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  3. Geothermal Resource Analysis and Structure of Basin and Range...

    Open Energy Info (EERE)

    Analysis and Structure of Basin and Range Systems, Especially Dixie Valley Geothermal Field, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Report:...

  4. Geothermal Resource Analysis And Structure Of Basin And Range...

    Open Energy Info (EERE)

    And Structure Of Basin And Range Systems, Especially Dixie Valley Geothermal Field, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geothermal...

  5. Geothermal Reservoir Assessment Case Study, Northern Basin and...

    Open Energy Info (EERE)

    Basin and Range Province, Northern Dixie Valley, Nevada Abstract NA Authors Elaine J. Bell, Lawrence T. Larson and Russell W. Juncal Published U.S. Department of Energy,...

  6. Geographic Information System At Nw Basin & Range Region (Coolbaugh...

    Open Energy Info (EERE)

    David Blackwell, Gary Oppliger (2005) A Map Of Geothermal Potential For The Great Basin, Usa- Recognition Of Multiple Geothermal Environments Additional References Retrieved from...

  7. Modeling-Computer Simulations At Nw Basin & Range Region (Blackwell...

    Open Energy Info (EERE)

    generic Basin and Range systems based on Dixie Valley data that help to understand the nature of large scale constraints on the location and characteristics of the geothermal...

  8. Modeling-Computer Simulations At Northern Basin & Range Region...

    Open Energy Info (EERE)

    generic Basin and Range systems based on Dixie Valley data that help to understand the nature of large scale constraints on the location and characteristics of the geothermal...

  9. Data Acquisition-Manipulation At Northern Basin & Range Region...

    Open Energy Info (EERE)

    - 2) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Data Acquisition-Manipulation At Northern Basin & Range Region (Coolbaugh, Et Al., 2005 - 2)...

  10. Data Acquisition-Manipulation At Nw Basin & Range Region (Coolbaugh...

    Open Energy Info (EERE)

    - 2) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Data Acquisition-Manipulation At Nw Basin & Range Region (Coolbaugh, Et Al., 2005 - 2)...

  11. Micro-Earthquake At Northwest Basin and Range Geothermal Region...

    Open Energy Info (EERE)

    Micro-Earthquake At Northwest Basin and Range Geothermal Region (1976) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Micro-Earthquake At...

  12. Geodetic Survey At Nw Basin & Range Region (Laney, 2005) | Open...

    Open Energy Info (EERE)

    Laney, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geodetic Survey At Nw Basin & Range Region (Laney, 2005) Exploration Activity...

  13. Geodetic Survey At Northern Basin & Range Region (Laney, 2005...

    Open Energy Info (EERE)

    Laney, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geodetic Survey At Northern Basin & Range Region (Laney, 2005) Exploration Activity...

  14. Independent Oversight Review, Hanford K Basin and Cold Vacuum...

    Broader source: Energy.gov (indexed) [DOE]

    Hanford K Basin and Cold Vacuum Drying Facility Found Fuel Multi-Canister Overpack Operations This report provides the results of an independent oversight review of operations...

  15. Contemporary Strain Rates in the Northern Basin and Range Province...

    Open Energy Info (EERE)

    province using data from continuous GPS (CGPS) networks, supplemented by additional campaign data from the Death Valley, northern Basin and Range, and Sierra Nevada-Great Valley...

  16. Modeling-Computer Simulations At Nw Basin & Range Region (Pritchett...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Modeling-Computer Simulations At Nw Basin & Range Region (Pritchett, 2004) Exploration Activity Details...

  17. Modeling-Computer Simulations At Nw Basin & Range Region (Biasi...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Modeling-Computer Simulations At Nw Basin & Range Region (Biasi, Et Al., 2009) Exploration Activity...

  18. Modeling-Computer Simulations At Northern Basin & Range Region...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Modeling-Computer Simulations At Northern Basin & Range Region (Biasi, Et Al., 2009) Exploration...

  19. Oregon Willamette River Basin Mitigation Agreement | Open Energy...

    Open Energy Info (EERE)

    River Basin Mitigation Agreement Author State of Oregon Recipient Bonneville Power Administration Published Publisher Not Provided, 10222010 DOI Not Provided Check for DOI...

  20. Data Acquisition-Manipulation At Nw Basin & Range Region (Blackwell...

    Open Energy Info (EERE)

    References D. D. Blackwell, K. W. Wisian, M. C. Richards, Mark Leidig, Richard Smith, Jason McKenna (2003) Geothermal Resource Analysis And Structure Of Basin And Range...

  1. Data Acquisition-Manipulation At Northern Basin & Range Region...

    Open Energy Info (EERE)

    References D. D. Blackwell, K. W. Wisian, M. C. Richards, Mark Leidig, Richard Smith, Jason McKenna (2003) Geothermal Resource Analysis And Structure Of Basin And Range...

  2. Field Mapping At Northern Basin & Range Region (Blewitt Et Al...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Field Mapping At Northern Basin & Range Region (Blewitt Et Al, 2005) Exploration Activity Details...

  3. Teleseismic-Seismic Monitoring At Nw Basin & Range Region (Biasi...

    Open Energy Info (EERE)

    Teleseismic-Seismic Monitoring At Nw Basin & Range Region (Biasi, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  4. Teleseismic-Seismic Monitoring At Northern Basin & Range Region...

    Open Energy Info (EERE)

    Teleseismic-Seismic Monitoring At Northern Basin & Range Region (Biasi, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  5. Geothermometry At Nw Basin & Range Region (Shevenell & De Rocher...

    Open Energy Info (EERE)

    Geothermometry At Nw Basin & Range Region (Shevenell & De Rocher, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Nw...

  6. Isotopic Analysis At Northern Basin & Range Region (Cole, 1983...

    Open Energy Info (EERE)

    Cole, 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Northern Basin & Range Region (Cole, 1983) Exploration Activity...

  7. Water Sampling At Northern Basin & Range Region (Laney, 2005...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Northern Basin & Range Region (Laney, 2005) Exploration Activity Details...

  8. Water Sampling At Nw Basin & Range Region (Laney, 2005) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Nw Basin & Range Region (Laney, 2005) Exploration Activity Details...

  9. Dixie Valley - Geothermal Development in the Basin and Range...

    Open Energy Info (EERE)

    Not Provided DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Dixie Valley - Geothermal Development in the Basin and Range Citation Dixie...

  10. Great Basin College Direct Use Geothermal Demonstration Project

    SciTech Connect (OSTI)

    Rice, John

    2014-10-21

    This is the final technical report for the Great Basin College Direct Use Geothermal Demonstrationn Project, outlining the technical aspects of the User Group System.

  11. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone “Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures” (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  12. Domestic Material Content in Molten-Salt Concentrating Solar Power Plants

    SciTech Connect (OSTI)

    Turchi, Craig; Kurup, Parthiv; Akar, Sertac; Flores, Francisco

    2015-08-26

    This study lists material composition data for two concentrating solar power (CSP) plant designs: a molten-salt power tower and a hypothetical parabolic trough plant, both of which employ a molten salt for the heat transfer fluid (HTF) and thermal storage media. The two designs have equivalent generating and thermal energy storage capacities. The material content of the saltHTF trough plant was approximately 25% lower than a comparably sized conventional oil-HTF parabolic trough plant. The significant reduction in oil, salt, metal, and insulation mass by switching to a salt-HTF design is expected to reduce the capital cost and LCOE for the parabolic trough system.

  13. Process for the preparation of protected dihydroxypropyl trialkylammonium salts and derivatives thereof

    DOE Patents [OSTI]

    Hollingsworth, Rawle I.; Wang, Guijun

    2000-01-01

    A process for the preparation of protected dihydroxypropyl trialkylammonium salts, particularly in chiral form is described. In particular, a process for the preparation of (2,2-dimethyl-1,3-dioxolan-4-ylmethyl)trialkylammonium salts, particularly in chiral form is described. Furthermore, a process is described wherein the (2,2-dimethyl-1,3-dioxolan-4ylmethyl)trialkylammonium salts is a 2,2-dimethyl-1,3-dioxolan-4-ylmethyl trimethylammonium salt, preferably in chiral form. The protected dihydroxypropyl trialkylammonium salts lead to L-carnitine (9) when in chiral form (5).

  14. Salt South Central Region Natural Gas Working Underground Storage (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Salt South Central Region Natural Gas Working Underground Storage (Billion Cubic Feet) Salt South Central Region Natural Gas Working Underground Storage (Billion Cubic Feet) Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 2010-Jan 01/01 159 01/08 123 01/15 91 01/22 102 01/29 108 2010-Feb 02/05 95 02/12 85 02/19 71 02/26 70 2010-Mar 03/05 63 03/12 71 03/19 80 03/26 89 2010-Apr 04/02 101 04/09 112 04/16 120

  15. Nuclear Hybrid Energy Systems: Molten Salt Energy Storage

    SciTech Connect (OSTI)

    P. Sabharwall; M. Green; S.J. Yoon; S.M. Bragg-Sitton; C. Stoots

    2014-07-01

    With growing concerns in the production of reliable energy sources, the next generation in reliable power generation, hybrid energy systems, are being developed to stabilize these growing energy needs. The hybrid energy system incorporates multiple inputs and multiple outputs. The vitality and efficiency of these systems resides in the energy storage application. Energy storage is necessary for grid stabilizing and storing the overproduction of energy to meet peak demands of energy at the time of need. With high thermal energy production of the primary nuclear heat generation source, molten salt energy storage is an intriguing option because of its distinct properties. This paper will discuss the different energy storage options with the criteria for efficient energy storage set forth, and will primarily focus on different molten salt energy storage system options through a thermodynamic analysis

  16. Heat Transfer Salts for Nuclear Reactor Systems - Chemistry

    Office of Scientific and Technical Information (OSTI)

    0-905 Heat Transfer Salts for Nuclear Reactor Systems - Chemistry Control, Corrosion Mitigation, and Modeling Reactor Concepts RD&D Dr. M ark Anderson U n iv e r s it y o f W i s c o n s i n , M a d i s o n In collaboration with: Pacific N o r t h w e s t N a t i o n a l La b o ra t o r y U n iv e r s it y o f California, B e r k e l e y Brian R o b i n s o n , Fede ra l POC M i c h a e l McKellar, Tec hnical POC Heat Transfer Salts for Nuclear Reactor Systems - chemistry control, corrosion

  17. Cooling molten salt reactors using “gas-lift”

    SciTech Connect (OSTI)

    Zitek, Pavel E-mail: klimko@kke.zcu.cz; Valenta, Vaclav E-mail: klimko@kke.zcu.cz; Klimko, Marek E-mail: klimko@kke.zcu.cz

    2014-08-06

    This study briefly describes the selection of a type of two-phase flow, suitable for intensifying the natural flow of nuclear reactors with liquid fuel - cooling mixture molten salts and the description of a “Two-phase flow demonstrator” (TFD) used for experimental study of the “gas-lift” system and its influence on the support of natural convection. The measuring device and the application of the TDF device is described. The work serves as a model system for “gas-lift” (replacing the classic pump in the primary circuit) for high temperature MSR planned for hydrogen production. An experimental facility was proposed on the basis of which is currently being built an experimental loop containing the generator, separator bubbles and necessary accessories. This loop will model the removal of gaseous fission products and tritium. The cleaning of the fuel mixture of fluoride salts eliminates problems from Xenon poisoning in classical reactors.

  18. Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters

    SciTech Connect (OSTI)

    Afroz, Taliman; Seo, D. M.; Han, Sang D.; Boyle, Paul D.; Henderson, Wesley A.

    2015-03-06

    Solvate crystal structures serve as useful models for the molecular-level interactions within the diverse solvates present in liquid electrolytes. Although acyclic carbonate solvents are widely used for Li-ion battery electrolytes, only three solvate crystal structures with lithium salts are known for these and related solvents. The present work, therefore, reports six lithium salt solvate structures with dimethyl and diethyl carbonate: (DMC)2:LiPF6, (DMC)1:LiCF3SO3, (DMC)1/4:LiBF4, (DEC)2:LiClO4, (DEC)1:LiClO4 and (DEC)1:LiCF3SO3 and four with the structurally related methyl and ethyl acetate: (MA)2:LiClO4, (MA)1:LiBF4, (EA)1:LiClO4 and (EA)1:LiBF4.

  19. Photosensitive dissolution inhibitors and resists based on onium salt carboxylates

    DOE Patents [OSTI]

    Dentinger, Paul M.; Simison, Kelby L.

    2005-11-29

    A photoresist composition that employs onium salt carboxylates as thermally stable dissolution inhibitors. The photoresist composition can be either an onium carboxylate salt with a phenolic photoresist, such as novolac, or an onium cation protected carboxylate-containing resin such as an acrylic/acrylic acid copolymer. The onium carboxylate can be an onium cholate, wherein the onium cholate is an iodonium cholate. Particularly preferred iodonium cholates are alkyloxyphenylphenyl iodonium cholates and most particularly preferred is octyloxyphenyphenyl iodonium cholate. The photoresist composition will not create nitrogen or other gaseous byproducts upon exposure to radiation, does not require water for photoactivation, has acceptable UV radiation transmission characteristics, and is thermally stable at temperatures required for solvent removal.

  20. Engineering Options Assessment Report. Nitrate Salt Waste Stream Processing

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    This report examines and assesses the available systems and facilities considered for carrying out remediation activities on remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The assessment includes a review of the waste streams consisting of 60 RNS, 29 above-ground UNS, and 79 candidate below-ground UNS containers that may need remediation. The waste stream characteristics were examined along with the proposed treatment options identified in the Options Assessment Report . Two primary approaches were identified in the five candidate treatment options discussed in the Options Assessment Report: zeolite blending and cementation. Systems that could be used at LANL were examined for housing processing operations to remediate the RNS and UNS containers and for their viability to provide repackaging support for remaining LANL legacy waste.

  1. Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-18

    This report examines and assesses the available systems and facilities considered for carrying out remediation activities on remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The assessment includes a review of the waste streams consisting of 60 RNS, 29 aboveground UNS, and 79 candidate belowground UNS containers that may need remediation. The waste stream characteristics were examined along with the proposed treatment options identified in the Options Assessment Report . Two primary approaches were identified in the five candidate treatment options discussed in the Options Assessment Report: zeolite blending and cementation. Systems that could be used at LANL were examined for housing processing operations to remediate the RNS and UNS containers and for their viability to provide repackaging support for remaining LANL legacy waste.

  2. Process Heat Exchanger Options for Fluoride Salt High Temperature Reactor

    SciTech Connect (OSTI)

    Piyush Sabharwall; Eung Soo Kim; Michael McKellar; Nolan Anderson

    2011-04-01

    The work reported herein is a significant intermediate step in reaching the final goal of commercial-scale deployment and usage of molten salt as the heat transport medium for process heat applications. The primary purpose of this study is to aid in the development and selection of the required heat exchanger for power production and process heat application, which would support large-scale deployment.

  3. Engineering Database of Liquid Salt Thermophysical and Thermochemical Properties

    SciTech Connect (OSTI)

    Manohar S. Sohal; Matthias A. Ebner; Piyush Sabharwall; Phil Sharpe

    2010-03-01

    The purpose of this report is to provide a review of thermodynamic and thermophysical properties of candidate molten salt coolants, which may be used as a primary coolant within a nuclear reactor or heat transport medium from the Next Generation Nuclear Plant (NGNP) to a processing plant, for example, a hydrogen-production plant. Thermodynamic properties of four types of molten salts, including LiF-BeF2 (67 and 33 mol%, respectively; also known as FLiBe), LiF-NaF-KF (46.5, 11.5, and 52 mol%, also known as FLiNaK), and KCl-MgCl2 (67 and 33 mol%), and sodium nitrate-sodium nitrite-potassium nitrate (NaNO3–NaNO2–KNO3, (7-49-44 or 7-40-53 mol%) have been investigated. Limitations of existing correlations to predict density, viscosity, specific heat capacity, surface tension, and thermal conductivity, were identified. The impact of thermodynamic properties on the heat transfer, especially Nusselt number was also discussed. Stability of the molten salts with structural alloys and their compatibility with the structural alloys was studied. Nickel and alloys with dense Ni coatings are effectively inert to corrosion in fluorides but not so in chlorides. Of the chromium containing alloys, Hastelloy N appears to have the best corrosion resistance in fluorides, while Haynes 230 was most resistant in chloride. In general, alloys with increasing carbon and chromium content are increasingly subject to corrosion by the fluoride salts FLiBe and FLiNaK, due to attack and dissolution of the intergranular chromium carbide. Future research to obtain needed information was identified.

  4. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof

    DOE Patents [OSTI]

    Bartlett, Neil; Whalen, J. Marc; Chacon, Lisa

    2000-12-12

    A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.

  5. Salt Waste Processing Facility (SWPF) System Turnover from Construction to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commissioning | Department of Energy Facility (SWPF) System Turnover from Construction to Commissioning Salt Waste Processing Facility (SWPF) System Turnover from Construction to Commissioning The SWPF Project Procedure establishes requirements and responsibilities that ensure the safe and orderly transition of jurisdictional control from Construction to Commissioning and Testing (C&T) for the system identified in Appendix A, SWPF Startup System Turnover Package List. Procedure

  6. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container

    Office of Environmental Management (EM)

    Nitrate Salt Bearing Waste Container Isolation Plan Prepared in Response to New Mexico Environment Department Administrative Order 05-20001 Issued May 20, 2014 1.0 INTRODUCTION The purpose of this document is to provide the Plan required by the New Mexico Environment Department (NMED) Administrative Order 05-20001 (Order) issued on May 20, 2014 to the U. S. Department of Energy (DOE) and Nuclear Waste Partnership LLC (NWP), collectively referred to as the Permittees. The Order, at paragraph 22,

  7. WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update May 12, 2015 Panel 6 and Panel 7, Room 7 a. Rollback * Contamination Assessment-This prerequisite is complete and therefore status updates are no longer required. * Fixing/Decontamination Activities-Decontaminated equipment has been removed from Room 7 of Panel 7 to prepare for Room 7 closure activities. Remaining items in Panel 7, Room 7 include thirteen empty magnesium oxide racks, about 200 roof bolts, nine messenger

  8. Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory

    Office of Environmental Management (EM)

    Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory Background Technical Area (TA) 54 is Los Alamos National Laboratory's transuranic (TRU) and low-level waste storage, characterization, and remediation area. The 63-acre site is located one mile from the community of White Rock and approximately one-eighth mile from the boundary be- tween Pueblo de San Ildefonso and the Laboratory. As a part of its national security mission, the Laboratory conducts research that generates

  9. Generic effluent monitoring system certification for salt well portable exhauster

    SciTech Connect (OSTI)

    Glissmeyer, J.A.; Maughan, A.D.

    1997-09-01

    Tests were conducted to verify that the Generic Effluent Monitoring System (GEMS), as it is applied to the Salt Well Portable Exhauster, meets all applicable regulatory performance criteria for air sampling systems at nuclear facilities. These performance criteria address both the suitability of the air sampling probe location and the transport of the sample to the collection devices. The criteria covering air sampling probe location ensure that the contaminants in the stack are well mixed with the airflow at the probe location such that the extracted sample represents the whole. The sample transport criteria ensure that the sampled contaminants are quantitatively delivered to the collection device. The specific performance criteria are described in detail in the report. The tests demonstrated that the GEMS/Salt Well Exhauster system meets all applicable performance criteria. Pacific Northwest National Laboratory conducted the testing using a mockup of the Salt Well Portable Exhauster stack at the Numatec Hanford Company`s 305 Building. The stack/sampling system configuration tested was designed to provide airborne effluent control for the Salt Well pumping operation at some U.S. Department of Energy (DOE) radioactive waste storage tanks at the Hanford Site, Washington. The portable design of the exhauster allows it to be used in other applications and over a range of exhaust air flowrates (approximately 200 - 1100 cubic feet per minute). The unit includes a stack section containing the sampling probe and another stack section containing the airflow, temperature and humidity sensors. The GEMS design features a probe with a single shrouded sampling nozzle, a sample delivery line, and sample collection system. The collection system includes a filter holder to collect the sample of record and an in-line detector head and filter for monitoring beta radiation-emitting particles.

  10. Epidemiology and Control of Infectious Diseases of Salmonids in the Columbia River Basin, 1987 Annual Report.

    SciTech Connect (OSTI)

    Fryer, John L.

    1989-01-01

    The Department of Microbiology at Oregon State University with funding from the Bonneville Power Administration has been conducting a study concerning the epidemiology and control of three fish pathogens which cause major disease problems in salmonids of the Columbia River basin. The pathogens studied include Cera to myxa Shasta, the myxosporean parasite which causes ceratomyxosis; Renibacterium salmoninarum, the bacterium which is the etiological agent of bacterial kidney disease; and the rhabdovirus which causes infectious hematopoietic necrosis (IHN). During this project, the host and geographic range of C. Shasta have been more precisely determined and the known geographic range has been significantly expanded. The effects of the parasite on fish migrating through the Columbia River and on their introduction into salt water have been examined. Similar studies have been conducted with R. salmoninarum and it has been shown that bacterial kidney disease occurs at all life stages of salmonids and is responsible for mortality in both fresh and salt water. It has also been demonstrated that different isolates of R. salmoninarum have different antigenic composition. Results of demonstration projects designed to control IHN by using UV treated water for early rearing of salmonid fry were equivocal. The scope of the project was considerably narrowed and focused during the past two years The project has concentrated on a study concerning the biology of C. Shasta and the identification of potential chemotherapeutants for control of bacterial kidney disease. The emphasis of work on C. Shasta has been its pathogenesis. This aspect of the parasite has been investigated using histopathologic and immunologic methodology. Mode of transmission, the nature of the infectious stage, and potential intermediate hosts of the parasite have also been areas of active research. Classes of chemotherapeutants with the highest potential for efficacy against R. salmoninarum have been identified through literature searches and consultation with pharmacologists. Experimental drugs have been requested and received from several pharmaceutical manufacturers. The in vitro sensitivity of R. salmoninarum and other selected fish pathogens to more than 100 antimicrobial compounds has been tested. The project is related to measure 704(h)(2)(d) of the Columbia River Basin Fish and Wildlife Program. The results will contribute to fish health which will directly contribute to the protection of fish.

  11. Transpiring wall supercritical water oxidation reactor salt deposition studies

    SciTech Connect (OSTI)

    Haroldsen, B.L.; Mills, B.E.; Ariizumi, D.Y.; Brown, B.G.

    1996-09-01

    Sandia National Laboratories has teamed with Foster Wheeler Development Corp. and GenCorp, Aerojet to develop and evaluate a new supercritical water oxidation reactor design using a transpiring wall liner. In the design, pure water is injected through small pores in the liner wall to form a protective boundary layer that inhibits salt deposition and corrosion, effects that interfere with system performance. The concept was tested at Sandia on a laboratory-scale transpiring wall reactor that is a 1/4 scale model of a prototype plant being designed for the Army to destroy colored smoke and dye at Pine Bluff Arsenal in Arkansas. During the tests, a single-phase pressurized solution of sodium sulfate (Na{sub 2}SO{sub 4}) was heated to supercritical conditions, causing the salt to precipitate out as a fine solid. On-line diagnostics and post-test observation allowed us to characterize reactor performance at different flow and temperature conditions. Tests with and without the protective boundary layer demonstrated that wall transpiration provides significant protection against salt deposition. Confirmation tests were run with one of the dyes that will be processed in the Pine Bluff facility. The experimental techniques, results, and conclusions are discussed.

  12. Sensitivity of storage field performance to geologic and cavern design parameters in salt domes.

    SciTech Connect (OSTI)

    Ehgartner, Brian L.; Park, Byoung Yoon

    2009-03-01

    A sensitivity study was performed utilizing a three dimensional finite element model to assess allowable cavern field sizes for strategic petroleum reserve salt domes. A potential exists for tensile fracturing and dilatancy damage to salt that can compromise the integrity of a cavern field in situations where high extraction ratios exist. The effects of salt creep rate, depth of salt dome top, dome size, caprock thickness, elastic moduli of caprock and surrounding rock, lateral stress ratio of surrounding rock, cavern size, depth of cavern, and number of caverns are examined numerically. As a result, a correlation table between the parameters and the impact on the performance of storage field was established. In general, slower salt creep rates, deeper depth of salt dome top, larger elastic moduli of caprock and surrounding rock, and a smaller radius of cavern are better for structural performance of the salt dome.

  13. Diffusion Welding of Alloys for Molten Salt Service - Status Report

    SciTech Connect (OSTI)

    Denis Clark; Ronald Mizia; Piyush Sabharwall

    2012-09-01

    The present work is concerned with heat exchanger development for molten salt service, including the proposed molten salt reactor (MSR), a homogeneous reactor in which the fuel is dissolved in a circulating fluid of molten salt. It is an outgrowth of recent work done under the Next Generation Nuclear Plant (NGNP) program; what the two reactor systems have in common is an inherently safe nuclear plant with a high outlet temperature that is useful for process heat as well as more conventional generation The NGNP program was tasked with investigating the application of a new generation of nuclear power plants to a variety of energy needs. One baseline reactor design for this program is a high temperature, gas-cooled reactor (HTGR), which provides many options for energy use. These might include the conventional Rankine cycle (steam turbine) generation of electricity, but also other methods: for example, Brayton cycle (gas turbine) electrical generation, and the direct use of the high temperatures characteristic of HTGR output for process heat in the chemical industry. Such process heat is currently generated by burning fossil fuels, and is a major contributor to the carbon footprint of the chemical and petrochemical industries. The HTGR, based on graphite fuel elements, can produce very high output temperatures; ideally, temperatures of 900 °C or even greater, which has significant energy advantages. Such temperatures are, of course, at the frontiers of materials limitations, at the upper end of the performance envelope of the metallic materials for which robust construction codes exist, and within the realm of ceramic materials, the fabrication and joining of which, on the scale of large energy systems, are at an earlier stage of development. A considerable amount of work was done in the diffusion welding of materials of interest for HTGR service with alloys such as 617 and 800H. The MSR output temperature is also materials limited, and is projected at about 700 °C. (RR E) A different set of alloys, such as Alloy N and 242, are needed to handle molten salts at this temperature. The diffusion welding development work described here builds on techniques developed during the NGNP work, as applied to these alloys. There is also the matter of dissimilar metal welding, since alloys suitable for salt service are generally not suited for service in gaseous oxidizing environments, and vice versa, and welding is required for the Class I boundaries in these systems, as identified in the relevant ASME codes.

  14. Diffusion Welding of Alloys for Molten Salt Service - Status Report

    SciTech Connect (OSTI)

    Denis Clark; Ronald Mizia

    2012-05-01

    The present work is concerned with heat exchanger development for molten salt service, including the proposed molten salt reactor (MSR), a homogeneous reactor in which the fuel is dissolved in a circulating fluid of molten salt. It is an outgrowth of recent work done under the Next Generation Nuclear Plant (NGNP) program; what the two reactor systems have in common is an inherently safe nuclear plant with a high outlet temperature that is useful for process heat as well as more conventional generation The NGNP program was tasked with investigating the application of a new generation of nuclear power plants to a variety of energy needs. One baseline reactor design for this program is a high temperature, gas-cooled reactor (HTGR), which provides many options for energy use. These might include the conventional Rankine cycle (steam turbine) generation of electricity, but also other methods: for example, Brayton cycle (gas turbine) electrical generation, and the direct use of the high temperatures characteristic of HTGR output for process heat in the chemical industry. Such process heat is currently generated by burning fossil fuels, and is a major contributor to the carbon footprint of the chemical and petrochemical industries. The HTGR, based on graphite fuel elements, can produce very high output temperatures; ideally, temperatures of 900 C or even greater, which has significant energy advantages. Such temperatures are, of course, at the frontiers of materials limitations, at the upper end of the performance envelope of the metallic materials for which robust construction codes exist, and within the realm of ceramic materials, the fabrication and joining of which, on the scale of large energy systems, are at an earlier stage of development. A considerable amount of work was done in the diffusion welding of materials of interest for HTGR service with alloys such as 617 and 800H. The MSR output temperature is also materials limited, and is projected at about 700 C. (RR E) A different set of alloys, such as Alloy N and 242, are needed to handle molten salts at this temperature. The diffusion welding development work described here builds on techniques developed during the NGNP work, as applied to these alloys. There is also the matter of dissimilar metal welding, since alloys suitable for salt service are generally not suited for service in gaseous oxidizing environments, and vice versa, and welding is required for the Class I boundaries in these systems, as identified in the relevant ASME codes.

  15. Coos Bay Field Gulf Coast Coal Region Williston Basin Illinois

    Gasoline and Diesel Fuel Update (EIA)

    C e n t r a l A p p a l a c h i a n B a s i n Michigan Basin Greater Green River Basin ... Coalbed Methane Fields, Lower 48 States 0 200 400 100 300 Miles Source: Energy ...

  16. Origin Basin Destination State STB EIA STB EIA Northern Appalachian...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Delaware W 28.49 W 131.87 21.6% 59 W 100.0% Northern Appalachian Basin Florida W - - - - - - - Northern Appalachian Basin Indiana W 20.35 W 64.82 31.4% 1,715 W 75.9% Northern...

  17. Origin Basin Destination State STB EIA STB EIA Northern Appalachian...

    Gasoline and Diesel Fuel Update (EIA)

    Florida W 38.51 W 140.84 27.3% 134 W 100.0% Northern Appalachian Basin Georgia - W - W W W - W Northern Appalachian Basin Indiana W 16.14 W 63.35 25.5% 1,681 W 88.5% Northern...

  18. Geodetic Survey At Nw Basin & Range Region (Blewitt Et Al, 2005...

    Open Energy Info (EERE)

    Geodetic Survey At Nw Basin & Range Region (Blewitt Et Al, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geodetic Survey At Nw Basin &...

  19. Fluid injection for salt water disposal and enhanced oil recovery as a potential problem for the WIPP: Proceedings of a June 1995 workshop and analysis

    SciTech Connect (OSTI)

    Silva, M.K.

    1996-08-01

    The Waste Isolation Pilot Plant (WIPP) is a facility of the U.S. Department of Energy (DOE), designed and constructed for the permanent disposal of transuranic (TRU) defense waste. The repository is sited in the New Mexico portion of the Delaware Basin, at a depth of 655 meters, in the salt beds of the Salado Formation. The WIPP is surrounded by reserves and production of potash, crude oil and natural gas. In selecting a repository site, concerns about extensive oil field development eliminated the Mescalero Plains site in Chaves County and concerns about future waterflooding in nearby oil fields helped eliminate the Alternate II site in Lea County. Ultimately, the Los Medanos site in Eddy County was selected, relying in part on the conclusion that there were no oil reserves at the site. For oil field operations, the problem of water migrating from the injection zone, through other formations such as the Salado, and onto adjacent property has long been recognized. In 1980, the DOE intended to prohibit secondary recovery by waterflooding in one mile buffer surrounding the WIPP Site. However, the DOE relinquished the right to restrict waterflooding based on a natural resources report which maintained that there was a minimal amount of crude oil likely to exist at the WIPP site, hence waterflooding adjacent to the WIPP would be unlikely. This document presents the workshop presentations and analyses for the fluid injection for salt water disposal and enhanced oil recovery utilizing fluid injection and their potential effects on the WIPP facility.

  20. Salt effects on isotope partitioning and their geochemical implications: An overview

    SciTech Connect (OSTI)

    Horita, J.; Cole, D.R.; Fortier, S.M.

    1996-01-01

    Essential to the use of stable isotopes as natural tracers and geothermometers is the knowledge of equilibrium isotope partitioning between different phases and species, which is usually a function of temperature only. The one exception known to date is oxygen and hydrogen isotope fractionation between liquid water and other phases (steam, gases, minerals), which changes upon the addition of salts to water, i.e., the isotope salt salt effect. Our knowledge of this effect, the difference between activity and composition (a-X) of isotopic water molecules in salt solutions, is very limited and controversial, especially at elevated temperatures. For the last several years, we have been conducting a detailed, systematic experimental study at Oak Ridge National Laboratory to determine the isotope salt effects from room temperature to elevated temperatures (currently to 500{degree}C). From this effort, a simple, coherent picture of the isotope salt effect is emerging, that differs markedly from the complex results reported in the literature. In this communication, we present an overview on the isotope salt effect, obtained chiefly from our study. Observed isotope salt effects in salt solutions are significant even at elevated temperatures. The importance and implications of the isotope salt effect for isotopic studies of brine-dominated systems are also discussed in general terms.

  1. Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation

    SciTech Connect (OSTI)

    Reddy, Ramana G.

    2013-10-23

    The explicit UA program objective is to develop low melting point (LMP) molten salt thermal energy storage media with high thermal energy storage density for sensible heat storage systems. The novel Low Melting Point (LMP) molten salts are targeted to have the following characteristics: 1. Lower melting point (MP) compared to current salts (<222ºC) 2. Higher energy density compared to current salts (>300 MJ/m3) 3. Lower power generation cost compared to current salt In terms of lower power costs, the program target the DOE's Solar Energy Technologies Program year 2020 goal to create systems that have the potential to reduce the cost of Thermal Energy Storage (TES) to less than $15/kWh-th and achieve round trip efficiencies greater than 93%. The project has completed the experimental investigations to determine the thermo-physical, long term thermal stability properties of the LMP molten salts and also corrosion studies of stainless steel in the candidate LMP molten salts. Heat transfer and fluid dynamics modeling have been conducted to identify heat transfer geometry and relative costs for TES systems that would utilize the primary LMP molten salt candidates. The project also proposes heat transfer geometry with relevant modifications to suit the usage of our molten salts as thermal energy storage and heat transfer fluids. The essential properties of the down-selected novel LMP molten salts to be considered for thermal storage in solar energy applications were experimentally determined, including melting point, heat capacity, thermal stability, density, viscosity, thermal conductivity, vapor pressure, and corrosion resistance of SS 316. The thermodynamic modeling was conducted to determine potential high temperature stable molten salt mixtures that have thermal stability up to 1000 °C. The thermo-physical properties of select potential high temperature stable (HMP) molten salt mixtures were also experimentally determined. All the salt mixtures align with the go/no-go goals stipulated by the DOE for this project. Energy densities of all salt mixtures were higher than that of the current solar salt. The salt mixtures costs have been estimated and TES system costs for a 2 tank, direct approach have been estimated for each of these materials. All estimated costs are significantly below the baseline system that used solar salt. These lower melt point salts offer significantly higher energy density per volume than solar salt – and therefore attractively smaller inventory and equipment costs. Moreover, a new TES system geometry has been recommended A variety of approaches were evaluated to use the low melting point molten salt. Two novel changes are recommended that 1) use the salt as a HTF through the solar trough field, and 2) use the salt to not only create steam but also to preheat the condensed feedwater for Rankine cycle. The two changes enable the powerblock to operate at 500°C, rather than the current 400°C obtainable using oil as the HTF. Secondly, the use of salt to preheat the feedwater eliminates the need to extract steam from the low pressure turbine for that purpose. Together, these changes result in a dramatic 63% reduction required for 6 hour salt inventory, a 72% reduction in storage volume, and a 24% reduction in steam flow rate in the power block. Round trip efficiency for the Case 5 - 2 tank “direct” system is estimated at >97%, with only small losses from time under storage and heat exchange, and meeting RFP goals. This attractive efficiency is available because the major heat loss experienced in a 2 tank “indirect” system - losses by transferring the thermal energy from oil HTF to the salt storage material and back to oil to run the steam generator at night - is not present for the 2 tank direct system. The higher heat capacity values for both LMP and HMP systems enable larger storage capacities for concentrating solar power.

  2. Baseload Nitrate Salt Central Receiver Power Plant Design Final Report

    SciTech Connect (OSTI)

    Tilley, Drake; Kelly, Bruce; Burkholder, Frank

    2014-12-12

    The objectives of the work were to demonstrate that a 100 MWe central receiver plant, using nitrate salt as the receiver coolant, thermal storage medium, and heat transport fluid in the steam generator, can 1) operate, at full load, for 6,400 hours each year using only solar energy, and 2) satisfy the DOE levelized energy cost goal of $0.09/kWhe (real 2009 $). To achieve these objectives the work incorporated a large range of tasks relating to many different aspects of a molten salt tower plant. The first Phase of the project focused on developing a baseline design for a Molten Salt Tower and validating areas for improvement. Tasks included a market study, receiver design, heat exchanger design, preliminary heliostat design, solar field optimization, baseline system design including PFDs and P&IDs and detailed cost estimate. The baseline plant met the initial goal of less than $0.14/kWhe, and reinforced the need to reduce costs in several key areas to reach the overall $0.09/kWhe goal. The major improvements identified from Phase I were: 1) higher temperature salt to improve cycle efficiency and reduce storage requirements, 2) an improved receiver coating to increase the efficiency of the receiver, 3) a large receiver design to maximize storage and meet the baseload hours objective, and 4) lower cost heliostat field. The second Phase of the project looked at advancing the baseline tower with the identified improvements and included key prototypes. To validate increasing the standard solar salt temperature to 600 °C a dynamic test was conducted at Sandia. The results ultimately proved the hypothesis incorrect and showed high oxide production and corrosion rates. The results lead to further testing of systems to mitigate the oxide production to be able to increase the salt temperature for a commercial plant. Foster Wheeler worked on the receiver design in both Phase I and Phase II looking at both design and lowering costs utilizing commercial fossil boiler manufacturing. The cost and design goals for the project were met with this task, but the most interesting results had to do with defining the failure modes and looking at a “shakedown analysis” of the combined creep-fatigue failure. A separate task also looked at improving the absorber coatings on the receiver tubes that would improve the efficiency of the receiver. Significant progress was made on developing a novel paint with a high absorptivity that was on par with the current Pyromark, but shows additional potential to be optimized further. Although the coating did not meet the emissivity goals, preliminary testing the new paint shows potential to be much more durable, and potential to improve the receiver efficiency through a higher average absorptivity over the lifetime. Additional coatings were also designed and modeled results meet the project goals, but were not tested. Testing for low cycle fatigue of the full length receiver tubes was designed and constructed, but is still currently undergoing testing. A novel small heliostat was developed through an extensive brainstorming and down select. The concept was then detailed further with inputs from component testing and eventually a full prototype was built and tested. This task met or exceeded the accuracy and structure goals and also beat the cost goal. This provides a significant solar field costs savings for Abengoa that will be developed further to be used in future commercial plants. Ultimately the $0.09/kWhe (real 2009 $) and 6,400 hours goals of the project were met.

  3. Blending of Radioactive Salt Solutions in Million Gallon Tanks - 13002

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R. [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)] [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)

    2013-07-01

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 - 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, 'One good experiment fixes a lot of good theory'. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks. (authors)

  4. Transportation of pyrochemical salts from Rocky Flats to Los Alamos

    SciTech Connect (OSTI)

    Schreiber, S.B.

    1997-02-01

    Radioactive legacy wastes or residues are currently being stored on numerous Sites around the former Department of Energy`s (DOE) Nuclear Weapons Complex. Since most of the operating facilities were shut down and have not operated since before the declared end to the Cold War in 1993, the historical method for treating these residues no longer exists. The risk associated with continued storage of these residues will dramatically increase with time. Thus, the DOE was directed by the Defense Nuclear Facility Safety Board in its Recommendation 94-1 to address and stabilize these residues and established an eight year time frame for doing so. There are only two options available to respond to this requirement: (1) restart existing facilities to treat and package the residues for disposal or (2) transport the residues to another operating facility within the Complex where they can be treated and packaged for disposal. This paper focuses on one such residue type, pyrochemical salts, produced at one Complex site, the Rocky Flats Plant located northwest of Denver, Colorado. One option for treating the salts is their shipment to Los Alamos, New Mexico, for handling at the Plutonium Facility. The safe transportation of these salts can be accomplished at present with several shipping containers including a DOT 6M, a DOE 9968, Type A or Type B quantity 55-gallon drum overpacks, or even the TRUPACT II. The tradeoffs between each container is examined with the conclusion that none of the available shipping containers is fully satisfactory. Thus, the advantageous aspects of each container must be utilized in an integrated and efficient way to effectively manage the risk involved. 1 fig.

  5. Blending Of Radioactive Salt Solutions In Million Gallon Tanks

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

    2012-12-10

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 ? 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, ?One good experiment fixes a lot of good theory?. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks.

  6. Rocky Mountain Basins Produced Water Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Historical records for produced water data were collected from multiple sources, including Amoco, British Petroleum, Anadarko Petroleum Corporation, United States Geological Survey (USGS), Wyoming Oil and Gas Commission (WOGC), Denver Earth Resources Library (DERL), Bill Barrett Corporation, Stone Energy, and other operators. In addition, 86 new samples were collected during the summers of 2003 and 2004 from the following areas: Waltman-Cave Gulch, Pinedale, Tablerock and Wild Rose. Samples were tested for standard seven component "Stiff analyses", and strontium and oxygen isotopes. 16,035 analyses were winnowed to 8028 unique records for 3276 wells after a data screening process was completed. [Copied from the Readme document in the zipped file available at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the Zipped file to your PC. When opened, it will contain four versions of the database: ACCESS, EXCEL, DBF, and CSV formats. The information consists of detailed water analyses from basins in the Rocky Mountain region.

  7. Biothem-based Mississippian transect from the Basin and Range Province to the Anadarko basin

    SciTech Connect (OSTI)

    Frye, M.W. ); Lane, H.R. ); Couples, G.D. )

    1991-03-01

    A west-to-east transect, constructed using the 'Biostratigraphic Package Approach' of Lane and Frye and illustrating the biostratigraphic, lithologic, and depositional sequence relationships within the Mississippian system, extends from the basin and range province across the Transcontinental Arch (TA) and into the Anadarko basin. The transect is based on both published and proprietary biostratigraphic data. It was constructed primarily to portray the regional distribution and exploration significance of biotherms relative to the axis of the TA. These biotherms are biostratigraphic units that are wedge- or lens-shaped bodies of strata that are bounded by paleontologically recognizable unconformities in their updip extents, are conformable with underlying and overlying biothems in their maximum shelfal development, are conformable or bounded by surfaces of nondeposition and or submarine erosion in their downdip, basinal extremities, and also contain a logical sequence of depositionally related facies. An unexpected result of constructing the transect was the recognition of an apparent compensatory temporal and spatial distribution of Mississippian biothems. This distribution is interpreted to imply that biothems deposited during relative highstand events on one flank of the TA are time-equivalent to biothems deposited during relative lowstand events on the opposite flank of the TA. Platescale tilting, along with local subsidence and uplift, is suggested as the overriding mechanism controlling deposition along the extent of the transect.

  8. Low-melting point inorganic nitrate salt heat transfer fluid

    DOE Patents [OSTI]

    Bradshaw, Robert W.; Brosseau, Douglas A.

    2009-09-15

    A low-melting point, heat transfer fluid made of a mixture of four inorganic nitrate salts: 9-18 wt % NaNO.sub.3, 40-52 wt % KNO.sub.3, 13-21 wt % LiNO.sub.3, and 20-27 wt % Ca(NO.sub.3).sub.2. These compositions can have liquidus temperatures less than 100 C; thermal stability limits greater than 500 C; and viscosity in the range of 5-6 cP at 300 C; and 2-3 cP at 400 C.

  9. SODIUM ALUMINOSILICATE FOULING AND CLEANING OF DECONTAMINATED SALT SOLUTION COALESCERS

    SciTech Connect (OSTI)

    Poirier, M; Thomas Peters, T; Fernando Fondeur, F; Samuel Fink, S

    2008-10-28

    During initial non-radioactive operations at the Modular Caustic Side Solvent Extraction Unit (MCU), the pressure drop across the decontaminated salt solution coalescer reached {approx}10 psi while processing {approx}1250 gallons of salt solution, indicating possible fouling or plugging of the coalescer. An analysis of the feed solution and the 'plugged coalescer' concluded that the plugging was due to sodium aluminosilicate solids. MCU personnel requested Savannah River National Laboratory (SRNL) to investigate the formation of the sodium aluminosilicate solids (NAS) and the impact of the solids on the decontaminated salt solution coalescer. Researchers performed developmental testing of the cleaning protocols with a bench-scale coalescer container 1-inch long segments of a new coalescer element fouled using simulant solution. In addition, the authors obtained a 'plugged' Decontaminated Salt Solution coalescer from non-radioactive testing in the MCU and cleaned it according to the proposed cleaning procedure. Conclusions from this testing include the following: (1) Testing with the bench-scale coalescer showed an increase in pressure drop from solid particles, but the increase was not as large as observed at MCU. (2) Cleaning the bench-scale coalescer with nitric acid reduced the pressure drop and removed a large amount of solid particles (11 g of bayerite if all aluminum is present in that form or 23 g of sodium aluminosilicate if all silicon is present in that form). (3) Based on analysis of the cleaning solutions from bench-scale test, the 'dirt capacity' of a 40 inch coalescer for the NAS solids tested is calculated as 450-950 grams. (4) Cleaning the full-scale coalescer with nitric acid reduced the pressure drop and removed a large amount of solid particles (60 g of aluminum and 5 g of silicon). (5) Piping holdup in the full-scale coalescer system caused the pH to differ from the target value. Comparable hold-up in the facility could lead to less effective cleaning and precipitation of bayerite solid particles. (6) Based on analysis of the cleaning solutions from the full-scale test, the 'dirt capacity' of a 40 inch coalescer for these NAS solids was calculated to be 40-170 grams.

  10. Method for removing semiconductor layers from salt substrates

    DOE Patents [OSTI]

    Shuskus, Alexander J.; Cowher, Melvyn E.

    1985-08-27

    A method is described for removing a CVD semiconductor layer from an alkali halide salt substrate following the deposition of the semiconductor layer. The semiconductor-substrate combination is supported on a material such as tungsten which is readily wet by the molten alkali halide. The temperature of the semiconductor-substrate combination is raised to a temperature greater than the melting temperature of the substrate but less than the temperature of the semiconductor and the substrate is melted and removed from the semiconductor by capillary action of the wettable support.

  11. Melting of Uranium Metal Powders with Residual Salts

    SciTech Connect (OSTI)

    Jin-Mok Hur; Dae-Seung Kang; Chung-Seok Seo

    2007-07-01

    The Advanced Spent Fuel Conditioning Process (ACP) of the Korea Atomic Energy Research Institute focuses on the conditioning of Pressurized Water Reactor spent oxide nuclear fuel. After the oxide reduction step of the ACP, the resultant metal powders containing {approx} 30 wt% residual LiCl-Li{sub 2}O should be melted for a consolidation of the fine metal powders. In this study, we investigated the melting behaviors of uranium metal powders considering the effects of a LiCl-Li{sub 2}O residual salt. (authors)

  12. Dilute acid/metal salt hydrolysis of lignocellulosics

    DOE Patents [OSTI]

    Nguyen, Quang A.; Tucker, Melvin P.

    2002-01-01

    A modified dilute acid method of hydrolyzing the cellulose and hemicellulose in lignocellulosic material under conditions to obtain higher overall fermentable sugar yields than is obtainable using dilute acid alone, comprising: impregnating a lignocellulosic feedstock with a mixture of an amount of aqueous solution of a dilute acid catalyst and a metal salt catalyst sufficient to provide higher overall fermentable sugar yields than is obtainable when hydrolyzing with dilute acid alone; loading the impregnated lignocellulosic feedstock into a reactor and heating for a sufficient period of time to hydrolyze substantially all of the hemicellulose and greater than 45% of the cellulose to water soluble sugars; and recovering the water soluble sugars.

  13. Method of preparing sodalite from chloride salt occluded zeolite

    DOE Patents [OSTI]

    Lewis, Michele A.; Pereira, Candido

    1997-01-01

    A method for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000.degree. K. to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

  14. Method of preparing sodalite from chloride salt occluded zeolite

    DOE Patents [OSTI]

    Lewis, M.A.; Pereira, C.

    1997-03-18

    A method is described for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000 K to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

  15. Source rocks of the Sub-Andean basins

    SciTech Connect (OSTI)

    Raedeke, L.D. )

    1993-02-01

    Seven source rock systems were mapped using a consistent methodology to allow basin comparison from Trinidad to southern Chile. Silurian and Devonian systems, deposited in passive margin and intracratonic settings, have fair-good original oil/gas potential from central and northern Bolivia to southern Peru. Kerogens range from mature in the foreland to overmature in the thrust belt. Permian to Carboniferous deposition in local restricted basins formed organic-rich shales and carbonates with very good original oil/gas potential, principally in northern Bolivia and southern Peru. Late Triassic to early Jurassic marine shales and limestones, deposited in deep, narrow, basins from Ecuador to north-central maturity. Locally, in the Cuyo rift basin of northern Argentina, a Triassic lacustrine unit is a very good, mature oil source. Early Cretaceous to Jurassic marine incursions into the back-arc basins of Chile-Argentina deposited shales and limestones. Although time transgressive (younging to the south), this system is the principal source in southern back-arc basins, with best potential in Neuquen, where three intervals are stacked A late Cretaceous marine transgressive shale is the most important source in northern South America. The unit includes the La Luna and equivalents extending from Trinidad through Venezuela, Colombia, Ecuador, and into northern Peru. Elsewhere in South America upper Cretaceous marine-lacustrine rocks are a possible source in the Altiplano and Northwest basins of Bolivia and Argentina. Middle Miocene to Oligocene source system includes shallow marine, deltaic, and lacustrine sediments from Trinidad to northern Peru.

  16. BASIN-CENTERED GAS SYSTEMS OF THE U.S.

    SciTech Connect (OSTI)

    Marin A. Popov; Vito F. Nuccio; Thaddeus S. Dyman; Timothy A. Gognat; Ronald C. Johnson; James W. Schmoker; Michael S. Wilson; Charles Bartberger

    2000-11-01

    The USGS is re-evaluating the resource potential of basin-centered gas accumulations in the U.S. because of changing perceptions of the geology of these accumulations, and the availability of new data since the USGS 1995 National Assessment of United States oil and gas resources (Gautier et al., 1996). To attain these objectives, this project used knowledge of basin-centered gas systems and procedures such as stratigraphic analysis, organic geochemistry, modeling of basin thermal dynamics, reservoir characterization, and pressure analysis. This project proceeded in two phases which had the following objectives: Phase I (4/1998 through 5/1999): Identify and describe the geologic and geographic distribution of potential basin-centered gas systems, and Phase II (6/1999 through 11/2000): For selected systems, estimate the location of those basin-centered gas resources that are likely to be produced over the next 30 years. In Phase I, we characterize thirty-three (33) potential basin-centered gas systems (or accumulations) based on information published in the literature or acquired from internal computerized well and reservoir data files. These newly defined potential accumulations vary from low to high risk and may or may not survive the rigorous geologic scrutiny leading towards full assessment by the USGS. For logistical reasons, not all basins received the level of detail desired or required.

  17. Advanced Thermal Storage System with Novel Molten Salt: December 8, 2011 - April 30, 2013

    SciTech Connect (OSTI)

    Jonemann, M.

    2013-05-01

    Final technical progress report of Halotechnics Subcontract No. NEU-2-11979-01. Halotechnics has demonstrated an advanced thermal energy storage system with a novel molten salt operating at 700 degrees C. The molten salt and storage system will enable the use of advanced power cycles such as supercritical steam and supercritical carbon dioxide in next generation CSP plants. The salt consists of low cost, earth abundant materials.

  18. Accident Investigation of the February 5, 2014, Underground Salt Haul Truck

    Energy Savers [EERE]

    Fire at the Waste Isolation Pilot Plant, Carlsbad NM | Department of Energy 5, 2014, Underground Salt Haul Truck Fire at the Waste Isolation Pilot Plant, Carlsbad NM Accident Investigation of the February 5, 2014, Underground Salt Haul Truck Fire at the Waste Isolation Pilot Plant, Carlsbad NM March 26, 2014 Accident Investigation of the February 5, 2014, Underground Salt Haul Truck Fire at the Waste Isolation Pilot Plant, Carlsbad NM The U.S. Department of Energy (DOE) Accident Prevention

  19. Accelerator-driven subcritical fission in molten salt core: Closing the

    Office of Scientific and Technical Information (OSTI)

    nuclear fuel cycle for green nuclear energy (Journal Article) | SciTech Connect Accelerator-driven subcritical fission in molten salt core: Closing the nuclear fuel cycle for green nuclear energy Citation Details In-Document Search Title: Accelerator-driven subcritical fission in molten salt core: Closing the nuclear fuel cycle for green nuclear energy A technology for accelerator-driven subcritical fission in a molten salt core (ADSMS) is being developed as a basis for the destruction of

  20. Salt Waste Disposal at the Savannah River Site | Department of Energy

    Energy Savers [EERE]

    Salt Waste Disposal at the Savannah River Site Salt Waste Disposal at the Savannah River Site Section 3116 of the Ronald W. Reagan National Defense Authorization Act for Fiscal Year 2005 authorizes the Secretary of Energy, in consultation with the Nuclear Regulatory Commission, to reclassify certain waste from reprocessing spent nuclear fuel from high-level waste to low-level waste if it meets the criteria set forth in Section 3116. Currently, DOE SRS has prepared one final (salt waste) and is

  1. Effect of hydrotropic salts on phase relationships involving hydrocarbons, water, and alcohols

    SciTech Connect (OSTI)

    Ho, P.C.; Kraus, K.A.

    1980-01-01

    Hydrotropic salts, which can increase the solubility of organic materials in aqueous solutions, are useful to tertiary oil recovery. We have examined effects on solubility of hydrocarbons in water (with and without alcohols) through addition of inorganic hydrotropic salts, such as perchlorates, thiocyanates, and iodides - high in the usual Hofmeister series - and of organic salts such as short chain alkyl benzene sulfonates and other salts based on substituted benzene derivatives. Although the inorganic salts are relatively ineffective in increasing solubility of hydrocarbons in water, many of the organic salts are excellent hydrotropic agents for hydrocarbons. We have examined the phase relationships for several series of aromatic salts such as sulfonates, carboxylates and hydroxycarboxylates, as a function of alkyl-carbon substitution in three-component (hydrocarbon, salt, water) and in four-component (hydrocarbon, salt, alcohol, water) systems. We have also examined miscibility relationships for a given hydrotropic salt as the chain length of alkanes and alkyl benzenes is systematically varied. While miscibilities decrease with increase in chain length of the hydrocarbon, the hydrotropic properties in these systems increase rapidly with the number of alkyl carbons on the benzene ring of the salts and they are relatively insensitive to the type of charged group (sulfonate vs carboxylate) attached to the benzene ring. However, there were significant increases in hydrotropy as one goes from equally substituted sulfonates or carboxylates to salicylates. A number of salts have been identified which have much greater hydrotropic properties for hydrocarbons than such well-known hydrotropic materials as toluene and xylene sulfonates.

  2. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOE Patents [OSTI]

    Lewis, Michele A.; Johnson, Terry R.

    1993-09-07

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  3. Maintaining molten salt electrolyte concentration in aluminum-producing electrolytic cell

    DOE Patents [OSTI]

    Barnett, Robert J.; Mezner, Michael B.; Bradford, Donald R

    2005-01-04

    A method of maintaining molten salt concentration in a low temperature electrolytic cell used for production of aluminum from alumina dissolved in a molten salt electrolyte contained in a cell free of frozen crust wherein volatile material is vented from the cell and contacted and captured on alumina being added to the cell. The captured volatile material is returned with alumina to cell to maintain the concentration of the molten salt.

  4. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOE Patents [OSTI]

    Lewis, Michele A. (Naperville, IL); Johnson, Terry R. (Wheaton, IL)

    1993-01-01

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  5. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, Eugene T.; Lin, Mow S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

  6. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed. The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts. For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates. 54 figs.

  7. Pebble Fuel Handling and Reactivity Control for Salt-Cooled High

    Office of Scientific and Technical Information (OSTI)

    Temperature Reactors (Technical Report) | SciTech Connect Pebble Fuel Handling and Reactivity Control for Salt-Cooled High Temperature Reactors Citation Details In-Document Search Title: Pebble Fuel Handling and Reactivity Control for Salt-Cooled High Temperature Reactors This report documents the work completed on the X-PREX facility under NEUP Project 11- 3172. This project seeks to demonstrate the viability of pebble fuel handling and reactivity control for fluoride salt-cooled

  8. Western Gas Sands Project: stratigrapy of the Piceance Basin

    SciTech Connect (OSTI)

    Anderson, S.

    1980-08-01

    The Western Gas Sands Project Core Program was initiated by US DOE to investigate various low permeability, gas bearing sandstones. Research to gain a better geological understanding of these sandstones and improve evaluation and stimulation techniques is being conducted. Tight gas sands are located in several mid-continent and western basins. This report deals with the Piceance Basin in northwestern Colorado. This discussion is an attempt to provide a general overview of the Piceance Basin stratigraphy and to be a useful reference of stratigraphic units and accompanying descriptions.

  9. Memo - Legacy Technical Area (TA)-55 Nitrate Salt Wastes at TA...

    Office of Environmental Management (EM)

    on February 14, 2014, report in Attachment F. Bibliography and References, are available on various public websites. PDF icon Memo - Legacy Technical Area (TA)-55 Nitrate Salt ...

  10. US/German Workshop on Salt Repository Research, Design and Operation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    following information: We have obtained the necessary DOE and Sandia approvals to start planning the 7 th USGerman Workshop on Salt Repository Research, Design, and Operation to...

  11. Hazard evaluation for cutting tank 241-A-101 salt well casing

    SciTech Connect (OSTI)

    Board, B.D.

    1997-01-10

    This document identifies the hazards of using an abrasive water jet to add perforations to the salt well screen in tank 241-A-101.

  12. Case studies of sealing methods and materials used in the salt...

    Office of Scientific and Technical Information (OSTI)

    Industrial experience, as determined from site visits and literature reviews, provides few examples of bulkheads built in salt and potash mines for control of water. Sealing ...

  13. Process for improving the energy density of feedstocks using formate salts

    DOE Patents [OSTI]

    Wheeler, Marshall Clayton; van Heiningen, Adriaan R.P.; Case, Paige A.

    2015-09-01

    Methods of forming liquid hydrocarbons through thermal deoxygenation of cellulosic compounds are disclosed. Aspects cover methods including the steps of mixing a levulinic acid salt-containing feedstock with a formic acid salt, exposing the mixture to a high temperature condition to form hydrocarbon vapor, and condensing the hydrocarbon vapor to form liquid hydrocarbons, where both the formic acid salt and the levulinic acid salt-containing feedstock decompose at the high temperature condition and wherein one or more of the mixing, exposing, and condensing steps is carried out a pressure between about vacuum and about 10 bar.

  14. ,"U.S. Natural Gas Salt Underground Storage Activity-Withdraw...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...dnavnghistn5450us2a.htm" ,"Source:","Energy Information Administration" ,"For Help, ... 1: U.S. Natural Gas Salt Underground Storage Activity-Withdraw (MMcf)" ...

  15. ,"U.S. Natural Gas Salt Underground Storage Activity-Net (MMcf...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...dnavnghistn5460us2m.htm" ,"Source:","Energy Information Administration" ,"For Help, ... 1: U.S. Natural Gas Salt Underground Storage Activity-Net (MMcf)" ...

  16. ,"U.S. Natural Gas Salt Underground Storage Activity-Injects...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...dnavnghistn5440us2a.htm" ,"Source:","Energy Information Administration" ,"For Help, ... 1: U.S. Natural Gas Salt Underground Storage Activity-Injects (MMcf)" ...

  17. ,"U.S. Natural Gas Non-Salt Underground Storage - Working Gas...

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas Non-Salt Underground Storage - Working Gas (MMcf)",1,"Monthly","2...dnavnghistn5510us2m.htm" ,"Source:","Energy Information Administration" ,"For Help, ...

  18. ,"U.S. Natural Gas Salt Underground Storage Activity-Net (MMcf...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...dnavnghistn5460us2a.htm" ,"Source:","Energy Information Administration" ,"For Help, ... 1: U.S. Natural Gas Salt Underground Storage Activity-Net (MMcf)" ...

  19. ,"U.S. Natural Gas Salt Underground Storage Activity-Injects...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...dnavnghistn5440us2m.htm" ,"Source:","Energy Information Administration" ,"For Help, ... 1: U.S. Natural Gas Salt Underground Storage Activity-Injects (MMcf)" ...

  20. ,"U.S. Natural Gas Non-Salt Underground Storage - Base Gas ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Natural Gas Non-Salt Underground Storage - Base Gas (MMcf)",1,"Monthly","22016" ...dnavnghistn5500us2m.htm" ,"Source:","Energy Information Administration" ,"For Help, ...