National Library of Energy BETA

Sample records for basic oxygen pro

  1. Petrochemical feedstock from basic oxygen steel furnace

    SciTech Connect (OSTI)

    Greenwood, C.W.; Hardwick, W.E.

    1983-10-01

    Iron bath gasification in which coal, lime, steam and oxygen are injected into a bath of molten iron for the production of a medium-Btu gas is described. The process has its origin in basic oxygen steelmaking. It operates at high temperatures and is thus not restrictive on the type of coal used. The ash is retained in the slag. The process is also very efficient. The authors suggest that in the present economic climate in the iron and steel industry, such a plant could be sited where existing coal-handling, oxygen and steelmaking equipment are available.

  2. Improving the System Life of Basic Oxygen and Electric Arc Furnace Hoods, Roofs, and Side Vents

    Broader source: Energy.gov [DOE]

    This factsheet describes the benefits of a high-performance aluminum bronze alloy to basic oxygen furnace and electric arc furnace components such as hoods, roofs, and side vents.

  3. Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Basics Basics ATLAS users belong to the "atlas" NERSC repository, and the Principal Investigator (PI) for ATLAS computing at NERSC is Ian Hinchliffe. ALICE users work in the sl53 chos environment. See the Chos page for more information. For more information about ATLAS computing at PDSF see the ATLAS twiki webpages which are maintained by ATLAS users. Last edited: 2016-04-29 11:34:26

  4. Real-time optical diagnostics for the basic oxygen steelmaking process

    SciTech Connect (OSTI)

    Ottesen, D.K.; Hurt, R.H.; Hardesty, D.R.

    1993-02-01

    This article deals with the development of real-time optical diagnostic techniques for process control in basic oxygen steelmaking. Results are presented of pilot-scale feasibility experiments conducted in the two-ton basic oxygen furnace (BOF) at Bethlehem Steel Corporation`s Homer Research Laboratories. Two line-of-sight optical techniques are being evaluated for determining the concentration and temperature of infrared-active gases in the BOF off-gas. The primary objective is to relate the concentration of these gas-phase species to the carbon content of the molten metal, and thereby provide a real-time indication of the process endpoint. Three cw lasers were used to measure the extent of beam attenuation at three different wavelengths in the particle-laden off-gas. The primary attenuation mechanism appears to be scattering by a dense, sub-micron diameter FeO fume. Initial infrared emission experiments with a Fourier transform infrared spectrometer at 1-cm{sup {minus}1} spectral resolution show partially resolved lines in the P-branch of the fundamental CO ground state and first hot-band transitions; CO{sub 2} bandheads are also clearly observed at 2384 and 2397 cm{sup {minus}1}. A second set of experiments was conducted to test the feasibility of oxygen-lance based fiber-optic imaging/pyrometric sensors for measurements of melt temperature and reaction zone properties. During bottom injection of nitrogen, clearly defined images of the melt/slag surface were obtained using both visible and near-infrared video systems. During oxygen blowing, optical emission from the hot spot was observed to fluctuate widely, with characteristic frequencies in the range of 3--10 Hz. Near the end of the process, the emission is characterized by periodic intensity bursts, interpreted as individual ignition events of duration 10--50 msec. Hot spot temperatures were calculated from the emission at 800 and 950 nm wavelengths using a grey-body assumption.

  5. Aluminum Bronze Alloys to Improve the System Life of Basic Oxygen and Electric Arc Furnace Hoods, Roofs and Side Vents.

    SciTech Connect (OSTI)

    Lawrence C. Boyd Jr.; Dr. Vinod K. Sikka

    2006-12-29

    Energy Industries of Ohio was the lead organization for a consortium that examined the current situation involving the service life of electric arc and basic oxygen furnace hoods, roofs and side vents. Republic Engineered Products (REP), one of the project partners, installed a full-scale Al-Bronze “skirt” in their BOF at their Lorain OH facility, believed to be the first such installation of this alloy in this service. In 24 months of operation, the Al-Bronze skirt has processed a total of 4,563 heats, requiring only 2 shutdowns for maintenance, both related to physical damage to the skirt from operational mishaps. Yearly energy savings related to the REP facility are projected to be ~ 10 billion Btu's with significant additional environmental and productivity benefits. In recognition of the excellent results, this project was selected as the winner of the Ohio’s 2006 Governor’s Award for Excellence in Energy, the state’s award for outstanding achievements in energy efficiency.

  6. Genie Pro

    Energy Science and Technology Software Center (OSTI)

    2004-05-15

    Genie Pro is a general purpose, interactive, adaptive tool for automatically labeling regions and finding objects in large amounts of image data. Genie Pro uses supervised learning techniques to search for spatio-spectral algorithms that are best able to match exaple labels provided by a user during a training session. After Genie Pro has discovered a useful algorithm, this algorith can then be applied to other similar types of image data, to label regions and objectsmore » similar to those provided during the training session. Genie Pro was originally developed for analyzing multispectral satellite data, but it works equally well with panchromatic (grayscale) and hyperspectral satellite data, aerial imagery, and various kinds of medical imagery. AS a rough guideline, Genie Pro can work with any imagery where the scene being imaged is all approximately at a constant distance fromt he imaging device, and so the scale of imagery is fixed. Applications for Genie Pro include: Crop and terrain type mapping, Road and river network mapping, Broad area search for vehicles and buildings, and Cancer identification in histological images.« less

  7. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, William H.

    1986-01-01

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  8. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, W.H.

    1984-05-08

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  9. NREL: Learning - Hydrogen Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Basics Hydrogen is a clean-burning fuel, and when combined with oxygen in a fuel cell, it produces heat and electricity with only water vapor as a by-product. But hydrogen...

  10. AL PRO | Open Energy Information

    Open Energy Info (EERE)

    search Name: AL-PRO Place: Grossheide, Lower Saxony, Germany Zip: 26532 Sector: Wind energy Product: AL-PRO is an inndependent expert office for wind forecasts, wind...

  11. ProMat

    Energy Science and Technology Software Center (OSTI)

    2008-06-12

    ProMAT is a software tool for statistically analyzing data from enzyme-linked immunosorbent assay microarray experiments. The software estimates standard curves, sample protein concentrations and their uncertainties for multiple assays. ProMAT generates a set of comprehensive figures for assessing results and diagnosing process quality. The tool is available for Windows or Mac, and is distributed as open-source Java and R code

  12. Energy Basics

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    Students will complete a scavenger hunt worksheet in order to learn about the basics of energy and its sources.

  13. Energy Pro USA | Open Energy Information

    Open Energy Info (EERE)

    Pro USA Jump to: navigation, search Name: Energy Pro USA Place: Chesterfield, Missouri Zip: MO 63017 Product: Energy Pro funds and implements demand side energy savings programs to...

  14. Word Pro - S5

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Flow, 2014 (Million Barrels per Day) 1 Unfinished oils, hydrogen/oxygenates/renewables/other hydrocarbons, and motor gasoline and aviation gasoline blending components. 2 Renewable fuels and oxygenate plant net production (1.071), net imports (0.752) and adjustments (0.503) minus stock change (0.059) and product supplied (-0.002). 3 Finished petroleum products, liquefied petroleum gases, and pentanes plus. 4 Natural gas plant liquids. 5 Field production (2.964) and renewable fuels and

  15. Ethanol Basics

    SciTech Connect (OSTI)

    2015-01-30

    Ethanol is a widely-used, domestically-produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Learn more about this alternative fuel in the Ethanol Basics Fact Sheet, produced by the U.S. Department of Energy's Clean Cities program.

  16. MEMS Pro Design Kit - Parts A, B, and C

    Energy Science and Technology Software Center (OSTI)

    2006-06-15

    Part A: SUMMiT V design Kit components for use with MEMS Pro from SoftMEMS Part B: SUMMiT V remote DRC and gear generator source code for use with autocad visual basic Part C: SUMMiT V DRC rules source and test cases for Calibre DRC engine

  17. Word Pro - Untitled1

    U.S. Energy Information Administration (EIA) Indexed Site

    chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group: CH 3 -(CH 2 )n-OH (e.g., metha- nol, ethanol, and tertiary butyl alcohol). See Fuel Ethanol. Alternative Fuel: Alternative fuels, for transportation applications, include the following: methanol; denatured ethanol, and other alcohols; fuel mixtures contain- ing 85 percent or more by volume of methanol, denatured ethanol, and other

  18. Word Pro - Untitled1

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Table 10.5 Estimated Number of Alternative-Fueled Vehicles in Use and Fuel Consumption, 1992-2010 Year Alternative and Replacement Fuels 1 Liquefied Petroleum Gases Compressed Natural Gas Liquefied Natural Gas Methanol, 85 Percent (M85) 3 Methanol, Neat (M100) 4 Ethanol, 85 Percent (E85) 3,5 Ethanol, 95 Percent (E95) 3 Elec- tricity 6 Hydro- gen Other Fuels 7 Subtotal Oxygenates 2 Bio- diesel 10 Total Methyl Tertiary Butyl Ether 8 Ethanol in Gasohol 9 Total Alternative-Fueled Vehicles in Use

  19. DC Pro Software Tool Suite

    SciTech Connect (OSTI)

    2009-04-01

    This fact sheet describes how DOE's Data Center Energy Profiler (DC Pro) Software Tool Suite and other resources can help U.S. companies identify ways to improve the efficiency of their data centers.

  20. Word Pro - Untitled1

    Gasoline and Diesel Fuel Update (EIA)

    1 Table 5.1b Petroleum Overview, Selected Years, 1949-2011 (Thousand Barrels per Day) Year Field Production 1 Renewable Fuels and Oxygenates 5 Processing Gain 6 Trade Stock Change 8,10 Adjust- ments 11 Petroleum Products Supplied 8 Crude Oil 2 Natural Gas Plant Liquids 4 Total Imports 7,8 Exports Net Imports 8,9 48 States 3 Alaska Total 1949 5,046 0 5,046 430 5,477 NA -2 645 327 318 -8 -38 5,763 1950 5,407 0 5,407 499 5,906 NA 2 850 305 545 -56 -51 6,458 1955 6,807 0 6,807 771 7,578 NA 34 1,248

  1. Recycling and Reuse of Basic Oxygen Furnace (BOF)/Basic Oxygen Process (BOP) Steelmaking Slags

    Broader source: Energy.gov [DOE]

    This factsheet describes a project to develop technologies and methodologies to allow value-added utilization of steelmaking slag, thus reducing waste and saving energy.

  2. Basic Energy Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Basic Energy Sciences Basic Energy Sciences Supporing research to understand, predict and ... The DOE Office of Science's Basic Energy Sciences program equips scientists with a ...

  3. AgPro | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: AgPro Place: Massena, New York Product: Operator of biodiesel plant based on soy. References: AgPro1 This article is a stub. You can help OpenEI...

  4. Si Pro AS | Open Energy Information

    Open Energy Info (EERE)

    Pro AS Jump to: navigation, search Name: Si Pro AS Place: Glomfjord, Norway Zip: 8161 Product: Silicon recycler with facility in Singapore. Coordinates: 66.807991, 13.97315...

  5. SPR Pro Forma Contract | Department of Energy

    Energy Savers [EERE]

    Pro Forma Contract SPR Pro Forma Contract An exchange agreement for SPR oil involves return of the principal amount of similar quality crude oil to the SPR, plus payment of an in-kind premium determined according to the period negotiated for return. See the pro forma contract to become familiar with the provisions, including the required Letter of Credit format you might want to bring to the attention of your financial institution. PDF icon SPR Pro Forma Contract More Documents &

  6. ProPortal: A Database for Prochlorococcus

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Huang, Katherine [Chisholm lab, MIT

    Prochlorococcus is a marine cyanobacterium that numerically dominates the mid-latitude oceans, and is the smallest known oxygenic phototroph. All isolates described thus far can be assigned to either a tightly clustered high-light (HL) adapted clade, or a more divergent low-light (LL) adapted group. They are closely related to, but distinct from, marine Synechococcus. The genomes of 12 strains have been sequenced and they range in size from 1.6 to 2.6 Mbp. They represent diverse lineages, spanning the rRNA diversity (97 to 99.93% similarity) of cultured representatives of this group. Our analyses of these genomes inform our understanding of how adaptation occurs in the oceans along gradients of light, nutrients, and other environmental factors, providing essential context for interpreting rapidly expanding metagenomic datasets. [Copied from http://proportal.mit.edu/project/prochlorococcus/] ProPortal allows users to browse and search genome date for not only Prochlorococcus, but Cyanophage and Synechococcus. Microarray data, environmental cell concentration data, and metagenome information are also available.

  7. Vehicle Emission Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Basics Vehicle Emission Basics November 22, 2013 - 2:07pm Addthis Vehicle emissions are the gases emitted by the tailpipes of vehicles that use internal combustion engines. These vehicles can run on gasoline, diesel, biofuels, natural gas, or propane. Vehicle emissions are composed of varying amounts of: water vapor carbon dioxide (CO2) nitrogen oxygen pollutants such as: carbon monoxide (CO) nitrogen oxides (NOx) unburned hydrocarbons (UHCs) volatile organic compounds (VOCs)

  8. Basic Energy Sciences Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Basic Energy Sciences Reports Basic Energy Sciences Reports The list below of Basic Energy Sciences workshop reports addresses the status of some important research areas that can help identify research directions for a decades-to-century energy strategy. Basic Energy Sciences (BES) Workshop Reports The Energy Challenges Report: New Science for a Secure and Sustainable Energy Future This Basic Energy Sciences Advisory Committee (BESAC) report summarizes a 2008 study by the Subcommittee on Facing

  9. Pro Corn LLC | Open Energy Information

    Open Energy Info (EERE)

    Pro-Corn LLC Place: Preston, Minnesota Zip: 55965 Product: Minnesotan farmer owned bioethanol production company. Coordinates: 47.526531, -121.936019 Show Map Loading map......

  10. ProForm | Open Energy Information

    Open Energy Info (EERE)

    Spreadsheet ComplexityEase of Use: Simple Website: poet.lbl.govProform Cost: Free References: ProForm1 Related Tools General Equilibrium Modeling Package (GEMPACK)...

  11. Pro Ventum International | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Pro Ventum International Place: Forchheim, Germany Zip: 79362 Sector: Wind energy Product: German-based developer of wind power...

  12. Win pro energy group | Open Energy Information

    Open Energy Info (EERE)

    energy group Place: Berlin, Berlin, Germany Zip: 12165 Sector: Renewable Energy, Solar, Wind energy Product: Win:pro offers location search, development, implementation,...

  13. ProEco Energy | Open Energy Information

    Open Energy Info (EERE)

    Place: South Dakota Product: US South Dakota-based company specializing ethanol refinery project development. References: ProEco Energy1 This article is a stub. You can...

  14. ProLogis | Open Energy Information

    Open Energy Info (EERE)

    Name: ProLogis Place: Aurora, Colorado Zip: 80011 Sector: Services Product: Provider of distribution facilities and services. Coordinates: 39.325162, -79.54975 Show Map...

  15. ProLogis France IX EURL | Open Energy Information

    Open Energy Info (EERE)

    ProLogis France IX EURL Jump to: navigation, search Name: ProLogis France IX EURL Place: Aulnay-Sous-Bois Cedex, France Zip: 93614 Product: French subsidiary of ProLogis, a...

  16. Basic Energy Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Basic Energy Sciences Basic Energy Sciences Supporing research to understand, predict and ultimately control matter and energy at the electronic, atomic, and molecular levels. Get Expertise Toni Taylor (505) 665-0030 Email Quanxi Jia (505) 667-2716 Email David Morris (505) 665-6487 Email Claudia Mora (505) 665-7832 Email Research fosters fundamental scientific discoveries to meet energy, environmental, and national security challenges The DOE Office of Science's Basic Energy Sciences program

  17. Pro Sol Energia SA | Open Energy Information

    Open Energy Info (EERE)

    Sol Energia SA Jump to: navigation, search Name: Pro Sol Energia SA Place: Algarrobo-Costa (Malaga), Spain Zip: E-29750 Sector: Solar Product: Develops and builds solar power...

  18. Ethanol Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ethanol Fuel Basics Ethanol Fuel Basics July 30, 2013 - 12:00pm Addthis biomass in beekers Ethanol is a renewable fuel made from various plant materials collectively known as "biomass." Studies have estimated that ethanol and other biofuels could replace 30% or more of U.S. gasoline demand by 2030. More than 95% of U.S. gasoline contains ethanol in a low-level blend to oxygenate the fuel and reduce air pollution. Ethanol is also increasingly available in E85, an alternative fuel that

  19. Thermodynamic assessment of the Pr-O system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McMurray, Jake W.

    2015-12-24

    We found that the Calphad method was used to perform a thermodynamic assessment of the Pr–O system. Compound energy formalism representations were developed for the fluorite α-PrO 2–x and bixbyite σ-Pr 3 O 5 ± x solid solutions while the two-sublattice liquid model was used to describe the binary melt. The series of phases between Pr 2 O 3 and PrO 2 were taken to be stoichiometric. Moreover, the equilibrium oxygen pressure, phase equilibria, and enthalpy data were used to optimize the adjustable parameters of the models for a self-consistent representation of the thermodynamic behavior of the Pr–O system frommore » 298 K to melting.« less

  20. Thermodynamic assessment of the Pr-O system

    SciTech Connect (OSTI)

    McMurray, Jake W.

    2015-12-24

    We found that the Calphad method was used to perform a thermodynamic assessment of the Pr–O system. Compound energy formalism representations were developed for the fluorite α-PrO 2–x and bixbyite σ-Pr 3 O 5 ± x solid solutions while the two-sublattice liquid model was used to describe the binary melt. The series of phases between Pr 2 O 3 and PrO 2 were taken to be stoichiometric. Moreover, the equilibrium oxygen pressure, phase equilibria, and enthalpy data were used to optimize the adjustable parameters of the models for a self-consistent representation of the thermodynamic behavior of the Pr–O system from 298 K to melting.

  1. Biomass Basics Webinar

    Broader source: Energy.gov [DOE]

    The Bioenergy Technologies Office (BETO) is hosting a Biomass Basics Webinar on August 27, 2015, from 4:00-4:40pm EDT. This webinar will provide high school students and teachers with background...

  2. Ethanol Basics (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2015-01-01

    Ethanol is a widely-used, domestically-produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Learn more about this alternative fuel in the Ethanol Basics Fact Sheet, produced by the U.S. Department of Energy's Clean Cities program.

  3. Energy Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Services » Energy Basics Energy Basics The basics about renewable energy and energy efficiency technologies: learn how they work, what they're used for, and how they can improve our lives, homes, businesses, and industries. The basics about renewable energy and energy efficiency technologies: learn how they work, what they're used for, and how they can improve our lives, homes, businesses, and industries. RENEWABLE ENERGY TECHNOLOGIES Biomass Technology Basics Geothermal Technology Basics

  4. EA-155 ProMark | Department of Energy

    Energy Savers [EERE]

    Order authorizing ProMark Energy, Inc to export electric energy to Canada. PDF icon EA-155 ProMark More Documents & Publications EA-196-A Minnesota Power, Sales EA-220-A NRG Power ...

  5. Biomass Basics Webinar

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 27, 2015 Biomass Basics Alexis Martin Fellow, Bioenergy Technologies Office Department of Energy 2 | Bioenergy Technologies Office Agenda * Overview of Bioenergy * Biomass to Biofuels Life Cycle * Importance of Bioenergy * 2016 BioenergizeME Infographic Challenge 3 | Bioenergy Technologies Office Questions and Comments Please record any questions and comments you may have during the webinar and send them to BioenergizeME@ee.doe.gov As a follow-up to the webinar, the presenter(s) will

  6. NREL: Learning - Biofuels Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biofuels Basics This video provides an overview of NREL research on converting biomass to liquid fuels. Text Version Unlike other renewable energy sources, biomass can be converted directly into liquid fuels, called "biofuels," to help meet transportation fuel needs. The two most common types of biofuels in use today are ethanol and biodiesel. Ethanol is an alcohol, the same as in beer and wine (although ethanol used as a fuel is modified to make it undrinkable). It is most commonly

  7. Collateral Duties for Program Records Official (PRO) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Records Official (PRO) Collateral Duties for Program Records Official (PRO) PDF icon GUIDANCE - Collateral Duties for PRO FINAL 141224.pdf More Documents & Publications Collateral Duties for Records Management Field Officer (RMFO) Collateral Duties for Records Liaison Officer (RLO) DOE F 243.3

  8. Cryogenic system for BERLinPro

    SciTech Connect (OSTI)

    Anders, W.; Hellwig, A.; Knobloch, J.; Pflückhahn, D.; Rotterdam, S.

    2014-01-29

    In 2010 Helmholtz-Zentrum Berlin (HZB) received funding to design and build the Berlin Energy Recovery Linac Project BERLinPro. The goal of this compact Energy recovery linac (ERL) is to develop the accelerator physics and technology required to generate and accelerate a 100-mA, 1-mm mrad emittance electron beam. The BERLinPro know-how can then be transferred to various ERL-based applications. All accelerating RF cavities including the electron source are based on superconducting technology operated at 1.8 K. A Linde L700 helium liquefier is supplying 4.5 K helium. The subatmospheric pressure of 16 mbar of the helium bath of the cavities will be achieved by pumping with a set of cold compressors and warm vacuum pumps. While the L700 is already in operating, the 1.8 K system and the helium transfer system are in design phase.

  9. Perl Embedded in PTC's Pro/ENGINEER, Version 1

    Energy Science and Technology Software Center (OSTI)

    2003-12-22

    Pro-PERL (AKA Pro/PERL) is a Perl extension to the PTC Pro/TOOLKIT API to the PTC Pro/ENGINEER CAD application including an embedded interpreter. It can be used to automate and customize Pro/ENGINEER, create Vendor Neutral Archive (VNA) format files and re-create CAD models from the VNA files. This has applications in sanitizing classified CAD models created in a classified environment for transfer to an open environment, creating template models for modification to finished models by non-expertmore » users, and transfer of design intent data to other modeling technologies.« less

  10. Artificial oxygen transport protein

    DOE Patents [OSTI]

    Dutton, P. Leslie

    2014-09-30

    This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

  11. BasicODT

    Energy Science and Technology Software Center (OSTI)

    2007-09-25

    BasicODT is a Monte Carlo simulation that numerically implements One-Dimensional Turbulence (ODT), a stochastic model of turbulent flow that was developed by the author of the code. This code is set up to simulate channel flow, which is the flow between two parallel flat walls driven by a fixed pressure gradient, with no-slip conditions at the walls. The code writes output files containing flow statistics gathered during the simulation. The code is accompanied by documentationmore » that explains how ODT modeling principles are numerically implemented within the code. The code and documentation are intended as an introduction to ODT for use as a learning tool for people who are unfamiliar with the model and its numerical implementation. ODT is fully described in published literature.« less

  12. Infrared Basics | Open Energy Information

    Open Energy Info (EERE)

    Infrared Basics Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Infrared Basics Author Protherm Published Publisher Not Provided, 2013 DOI Not Provided...

  13. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

    1996-01-01

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

  14. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Chung, B.W.; Raistrick, I.D.; Brosha, E.L.

    1996-08-06

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer. 4 figs.

  15. Home Performance Contractor Pro Forma | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Home Performance Contractor Pro Forma, with program HR, assumptions, marketing actuals and costs, and more, as posted on the U.S. Department of Energy's Better Buildings ...

  16. BatPRO: Battery Manufacturing Cost Estimation | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BatPRO: Battery Manufacturing Cost Estimation BatPRO models a stiff prismatic pouch-type cell battery pack with cells linked in series. BatPRO models a stiff prismatic pouch-type cell battery pack with cells linked in series. BatPRO is the user-friendly, Windows-based version of BatPaC, a software modeling tool designed for policymakers and researchers who are interested in estimating the cost of lithium-ion batteries after they have reached a mature state of development and are being

  17. Pro Solar Solarstrom GmbH | Open Energy Information

    Open Energy Info (EERE)

    GmbH Jump to: navigation, search Name: Pro Solar Solarstrom GmbH Place: Ravensburg, Germany Zip: 88214 Sector: Solar Product: Distributor of PV modules, including Canadian...

  18. A Variational Pro jection Operator for Mapping of Internal Variables...

    Office of Scientific and Technical Information (OSTI)

    Title: A Variational Pro jection Operator for Mapping of Internal Variables. Authors: Mota, Alejandro ; Sun, WaiChing ; Ostien, Jakob ; Foulk, James W., III ; Long, Kevin...

  19. SolarPro Energy International | Open Energy Information

    Open Energy Info (EERE)

    Place: Granite Bay, California Zip: 95746 Sector: Solar Product: SolarPro Energy installs solar power systems using PV panels for residential and commercial properties. References:...

  20. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H.; Brosha, Eric L.

    1997-01-01

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures.

  1. Daylighting Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lighting & Daylighting » Daylighting Basics Daylighting Basics August 16, 2013 - 11:24am Addthis Energy 101: Daylighting Basics This video explains how homeowners and businesses can use highly efficient, strategically placed windows to save money. Text Version Daylighting is the use of windows and skylights to bring sunlight into buildings. Daylighting in businesses and commercial buildings can result in substantial savings on electric bills, and not only provides a higher quality of light

  2. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, D.W.

    1994-09-06

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

  3. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, Dennis W.

    1994-01-01

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured.

  4. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  5. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  6. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  7. Integrated turbomachine oxygen plant

    SciTech Connect (OSTI)

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  8. Alternative Fuels Data Center: Hydrogen Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Basics to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Basics on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Basics on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Basics on Google Bookmark Alternative Fuels Data Center: Hydrogen Basics on Delicious Rank Alternative Fuels Data Center: Hydrogen Basics on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Basics on AddThis.com... More in this section... Hydrogen Basics Production

  9. Alternative Fuels Data Center: Propane Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Basics to someone by E-mail Share Alternative Fuels Data Center: Propane Basics on Facebook Tweet about Alternative Fuels Data Center: Propane Basics on Twitter Bookmark Alternative Fuels Data Center: Propane Basics on Google Bookmark Alternative Fuels Data Center: Propane Basics on Delicious Rank Alternative Fuels Data Center: Propane Basics on Digg Find More places to share Alternative Fuels Data Center: Propane Basics on AddThis.com... More in this section... Propane Basics Production &

  10. OLED Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SSL Basics » OLED Basics OLED Basics OLEDs are organic LEDs, which means that their key building blocks are organic (i.e., carbon-based) materials. Unlike LEDs, which are small-point light sources, OLEDs are made in sheets that are diffuse-area light sources. OLED technology is developing rapidly, and there are a handful of product offerings with efficacy, lifetime, and color quality specs that are comparable to their LED counterparts. However, OLEDs are still some years away from widespread

  11. Oxygen-Enriched Combustion

    Broader source: Energy.gov [DOE]

    This tip sheet discusses how an increase in oxygen in combustion air can reduce the energy loss in the exhaust gases and increase process heating system efficiency.

  12. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Brosha, E.L.

    1997-12-09

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures. 6 figs.

  13. Energy Basics | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    The basics about renewable energy and energy efficiency technologies: learn how they work, what they're used for, and how they can improve our lives, homes, businesses, and ...

  14. Geothermal Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Information Resources » Geothermal Basics Geothermal Basics Geothermal heat is most prevalent in the western United States, where the heat resource can sometimes be spotted from the earth's surface. Geothermal heat is most prevalent in the western United States, where the heat resource can sometimes be spotted from the earth's surface. Geothermal energy-geo (earth) + thermal (heat)-is heat energy from the earth. What is a geothermal resource? Geothermal resources are reservoirs of hot water

  15. Biomass Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Education & Workforce Development » Resources » Biomass Basics Biomass Basics Biomass is an energy resource derived from organic matter, which includes wood, agricultural waste, and other living-cell material that can be burned to produce heat energy. It also includes algae, sewage, and other organic substances that may be used to make energy through chemical processes. Biomass currently supplies about 3% of total U.S. energy consumption in the form of electricity, process heat, and

  16. Biopower Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biopower Basics Biopower Basics Biomass power (biopower) technologies convert renewable biomass fuels into heat and electricity using processes similar to that used with fossil fuels. Next to hydropower, more electricity is generated from biomass than any other renewable energy resource in the United States. A key attribute of biomass is its availability upon demand-the energy is stored within the biomass until it is needed; whereas, other forms of renewable energy are dependent on variable

  17. Bioproducts Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bioproducts Basics Bioproducts Basics Today, petroleum is refined to make chemical feedstocks used in thousands of products. Many of these petroleum-based feedstocks could be replaced with value-added chemicals produced from biomass to manufacture clothing, plastics, lubricants, and other products. The emerging U.S. biobased products industry combines expertise and technology from the agriculture, forest products, and chemical industries to create plastics, chemicals, and composite materials

  18. Lighting Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Homes & Buildings » Lighting & Daylighting » Lighting Basics Lighting Basics August 15, 2013 - 5:12pm Addthis Text Version There are many different types of artificial lights (formally called "lamps" in the lighting industry,) which have different applications and uses. Types of lighting include: Fluorescent Lighting High-intensity Discharge Lighting Incandescent Lighting LED Lighting. New lamp designs that use energy-efficient technology are now readily available in the

  19. Microhydropower Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Hydropower » Microhydropower Basics Microhydropower Basics August 15, 2013 - 3:09pm Addthis Microhydropower systems are small hydroelectric power systems of less than 100 kilowatts (kW) used to produce mechanical energy or electricity for farms, ranches, homes, and villages. How a Microhydropower System Works All hydropower systems use the energy of flowing water to produce electricity or mechanical energy. Although there are several ways to harness moving water to produce

  20. SSL Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SSL Basics SSL Basics Solid-state lighting (SSL) differs from other kinds of lighting in that it's based on light-emitting diodes (LEDs) or organic LEDs (OLEDs) instead of filaments, plasma, or gases. In addition to having the potential to be more energy efficient than any other existing lighting technology, it also has a number of other advantages-including directionality, controllability, vibration resistance, long life, color tunability, and aesthetic appeal. But SSL is still at a relatively

  1. Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    repository and the Principal Investigator (PI) for ALICE computing at NERSC is Jeff Porter. ALICE users work in the sl53 chos environment. See the Chos page for more...

  2. Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in HPSS. The Principal Investigator (PI) for STAR computing at NERSC is Jeff Porter. In general STAR users should work in the chos environment sl53. This means that upon...

  3. Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Daya Bay has two "production accounts". The dayabay account is used for the automated software builds on common as well as for the diagnostic testing of the processed raw data...

  4. Home Performance Contractor Pro Forma | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Home Performance Contractor Pro Forma, with program HR, assumptions, marketing actuals and costs, and more, as posted on the U.S. Department of Energy's Better Buildings Neighborhood Program website

  5. ProForce marks 65 years protecting Sandia resources, facilities...

    National Nuclear Security Administration (NNSA)

    ProForce marks 65 years protecting Sandia resources, facilities, people Monday, October ... Over the past 65 years, the force has changed in size and structure but its mission has ...

  6. Pro2 Anlagentechnik GmbH | Open Energy Information

    Open Energy Info (EERE)

    Zip: 47877 Product: Pro2 delivers turn-key plants for utilisation of biogas, sewage, natural gas and landfill gas in the range from 100 to 3,600 kWe. Coordinates: 51.26439,...

  7. Alternative Fuels Data Center: Biodiesel Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Google Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Delicious Rank Alternative Fuels Data Center: Biodiesel Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Fuel Basics on AddThis.com... More in

  8. Alternative Fuels Data Center: Electricity Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Electricity Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Electricity Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Electricity Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Google Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Delicious Rank Alternative Fuels Data Center: Electricity Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Electricity Fuel Basics on

  9. Alternative Fuels Data Center: Ethanol Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Basics on AddThis.com... More in this

  10. Pennsylvania's Comprehensive, Statewide, Pro-Active Industrial Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency (E2) Program | Department of Energy Pennsylvania's Comprehensive, Statewide, Pro-Active Industrial Energy Efficiency (E2) Program Pennsylvania's Comprehensive, Statewide, Pro-Active Industrial Energy Efficiency (E2) Program Pennsylvania The U.S. Department of Energy's (DOE's) Advanced Manufacturing Office (AMO; formerly the Industrial Technologies Program) has developed multiple resources and a best practices suite of tools to help industrial manufacturers reduce their energy

  11. Basic research for environmental restoration

    SciTech Connect (OSTI)

    Not Available

    1990-12-01

    The Department of Energy (DOE) is in the midst of a major environmental restoration effort to reduce the health and environmental risks resulting from past waste management and disposal practices at DOE sites. This report describes research needs in environmental restoration and complements a previously published document, DOE/ER-0419, Evaluation of Mid-to-Long Term Basic Research for Environmental Restoration. Basic research needs have been grouped into five major categories patterned after those identified in DOE/ER-0419: (1) environmental transport and transformations; (2) advanced sampling, characterization, and monitoring methods; (3) new remediation technologies; (4) performance assessment; and (5) health and environmental effects. In addition to basic research, this document deals with education and training needs for environmental restoration. 2 figs., 6 tabs.

  12. Hydropower Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Information Resources » Hydropower Basics Hydropower Basics Content on this page requires a newer version of Adobe Flash Player. Get Adobe Flash player Most people associate water power with the Hoover Dam-a huge facility harnessing the power of an entire river behind its walls-but hydropower facilities come in all sizes. Some may be very large, but they can be tiny too, taking advantage of water flows in municipal water facilities or irrigation ditches. They can even be "dam-less,"

  13. Tool Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercial Buildings » Analysis Tools » Energy Asset Score » Tool Basics Tool Basics Asset Score Scale The Asset Score uses a 10-point scale to evaluate the energy efficiency of a building's physical characteristics and major energy-related systems. The point value is assigned based on a building's predicted source energy use intensity (EUI) according to the energy simulation results. Scores are rounded to the nearest half-point increment (i.e., "6", "6.5", "7",

  14. Financing Basics for RE Projects

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Basics for RE Projects 1 Agenda: * Overview & Summary Findings * Introduction to Project Finance * The Role of the Players * Structure and Negotiation of Key Documents * Conclusions 2 Overview & Summary Findings 3 Renewable Energy Options: * Wind * PV * Solar * Bio * The evaluative parameters used by financiers is different for each of these technologies - Example: DSC for Wind = 1.4 - 1.5; and DSC for Bio (due to fuel risk) = 1.5 - 1.6 4 Basic Elements #1: * Lots of money now

  15. DOE Office of Basic Sciences: An Overview of Basic Research Activities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office of Basic Sciences: An Overview of Basic Research Activities on Thermoelectrics DOE ... More Documents & Publications Basic Energy Sciences Overview Progress from DOE EF RC: ...

  16. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  17. Water Heating Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Heating Basics Water Heating Basics August 19, 2013 - 11:15am Addthis A variety of systems are available for water heating in homes and buildings. Learn about: Conventional Storage Water Heaters Demand (Tankless or Instantaneous) Water Heaters Heat Pump Water Heaters Solar Water Heaters Tankless Coil and Indirect Water Heaters Addthis Related Articles Tankless Demand Water Heater Basics Solar Water Heater Basics Heat Pump Water Heater Basics Energy Basics Home Renewable Energy Homes &

  18. Alternative Fuels Data Center: Vehicle Conversion Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Vehicle Conversion Basics to someone by E-mail Share Alternative Fuels Data Center: Vehicle Conversion Basics on Facebook Tweet about Alternative Fuels Data Center: Vehicle Conversion Basics on Twitter Bookmark Alternative Fuels Data Center: Vehicle Conversion Basics on Google Bookmark Alternative Fuels Data Center: Vehicle Conversion Basics on Delicious Rank Alternative Fuels Data Center: Vehicle Conversion Basics on Digg Find More places to share Alternative Fuels Data Center: Vehicle

  19. Lesson 2 - Electricity Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 - Electricity Basics Lesson 2 - Electricity Basics It's difficult to imagine life without convenient electricity. You just flip a switch or plug in an appliance, and it's there....

  20. Photovoltaic Technology Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Photovoltaic Technology Basics Photovoltaic Technology Basics August 16, 2013 - 4:47pm Addthis Text Version Photovoltaic (PV) materials and devices convert sunlight into ...

  1. Photovoltaic Cell Performance Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance Basics Photovoltaic Cell Performance Basics August 19, 2013 - 4:55pm Addthis Photovoltaic (PV), or solar cells use the energy in sunlight to produce electricity. ...

  2. Photovoltaic Cell Material Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Material Basics Photovoltaic Cell Material Basics August 19, 2013 - 4:43pm Addthis Although crystalline silicon cells are the most common type, photovoltaic (PV), or solar cells, ...

  3. Photovoltaic Crystalline Silicon Cell Basics | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Crystalline Silicon Cell Basics Photovoltaic Crystalline Silicon Cell Basics August 20, ... To create an electric field within a crystalline silicon photovoltaic (PV) cell, two ...

  4. Concentrator Photovoltaic System Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concentrator Photovoltaic System Basics Concentrator Photovoltaic System Basics August 20, 2013 - 4:12pm Addthis Concentrator photovoltaic (PV) systems use less solar cell material ...

  5. Biodiesel Basics (Fact Sheet), Vehicle Technologies Program ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel Basics (Fact Sheet), Vehicle Technologies Program (VTP) Biodiesel Basics (Fact Sheet), Vehicle Technologies Program (VTP) Fact sheet providing questions and answers on ...

  6. Basic energy properties of electrolytic solutions database. ...

    Office of Scientific and Technical Information (OSTI)

    Basic energy properties of electrolytic solutions database. Viscosity, thermal conductivity, density, enthalpy Citation Details In-Document Search Title: Basic energy properties ...

  7. Health Care Buildings : Basic Characteristics Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    Basic Characteristics Tables Buildings and Size Data by Basic Characteristics for Health Care Buildings Number of Buildings (thousand) Percent of Buildings Floorspace (million...

  8. Basic Matrix Library (bml), Version 0.x

    Energy Science and Technology Software Center (OSTI)

    2015-11-24

    The basic matrix library (bml) is a collection of various matrix data formats (in dense and sparse) and their associated algorithms for basic matrix operations.

  9. Basic Research Needs: Catalysis for Energy

    SciTech Connect (OSTI)

    Bell, Alexis T.; Gates, Bruce C.; Ray, Douglas; Thompson, Michael R.

    2008-03-11

    The report presents results of a workshop held August 6-8, 2007, by DOE SC Basic Energy Sciences to determine the basic research needs for catalysis research.

  10. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, P.

    1997-07-22

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

  11. Monolithic solid electrolyte oxygen pump

    DOE Patents [OSTI]

    Fee, Darrell C.; Poeppel, Roger B.; Easler, Timothy E.; Dees, Dennis W.

    1989-01-01

    A multi-layer oxygen pump having a one-piece, monolithic ceramic structure affords high oxygen production per unit weight and volume and is thus particularly adapted for use as a portable oxygen supply. The oxygen pump is comprised of a large number of small cells on the order of 1-2 millimeters in diameter which form the walls of the pump and which are comprised of thin, i.e., 25-50 micrometers, ceramic layers of cell components. The cell components include an air electrode, an oxygen electrode, an electrolyte and interconnection materials. The cell walls form the passages for input air and for exhausting the oxygen which is transferred from a relatively dilute gaseous mixture to a higher concentration by applying a DC voltage across the electrodes so as to ionize the oxygen at the air electrode, whereupon the ionized oxygen travels through the electrolyte and is converted to oxygen gas at the oxygen electrode.

  12. Alternative Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alternative Fuel Basics Alternative Fuel Basics August 19, 2013 - 5:42pm Addthis Photo of a man in goggles looking at test tubes full of biodiesel. There are a number of fuels available for alternative fuel vehicles. Learn about the following types of fuels: Biodiesel Electricity Ethanol Hydrogen Natural Gas Propane Addthis Related Articles Advanced Technology and Alternative Fuel Vehicle Basics Glossary of Energy-Related Terms Natural Gas Fuel Basics Energy Basics Home Renewable Energy Homes

  13. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, Paul

    1997-01-01

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

  14. NREL: Learning - Biomass Energy Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass Energy Basics Photo of a farmer standing in a field and inspecting corn crops. We have used biomass energy, or "bioenergy"-the energy from plants and plant-derived materials-since people began burning wood to cook food and keep warm. Wood is still the largest biomass energy resource today, but other sources of biomass can also be used. These include food crops, grassy and woody plants, residues from agriculture or forestry, oil-rich algae, and the organic component of municipal

  15. NREL: Learning - Geothermal Energy Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geothermal Energy Basics Photo of a hot spring. The Earth's heat-called geothermal energy-escapes as steam at a hot springs in Nevada. Many technologies have been developed to take advantage of geothermal energy-the heat from the earth. This heat can be drawn from several sources: hot water or steam reservoirs deep in the earth that are accessed by drilling; geothermal reservoirs located near the earth's surface, mostly located in the western U.S., Alaska, and Hawaii; and the shallow ground near

  16. NREL: Learning - Solar Energy Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Basics Photo of a solar electric system in Colorado with snow-covered mountain peaks in the background. Solar panels installed on a home in Colorado. Solar is the Latin word for sun-a powerful source of energy that can be used to heat, cool, and light our homes and businesses. That's because more energy from the sun falls on the earth in one hour than is used by everyone in the world in one year. A variety of technologies convert sunlight to usable energy for buildings. The most commonly

  17. NREL: Learning - Wind Energy Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wind Energy Basics We have been harnessing the wind's energy for hundreds of years. From old Holland to farms in the United States, windmills have been used for pumping water or grinding grain. Today, the windmill's modern equivalent-a wind turbine-can use the wind's energy to generate electricity. Wind turbines, like windmills, are mounted on a tower to capture the most energy. At 100 feet (30 meters) or more aboveground, they can take advantage of the faster and less turbulent wind. Turbines

  18. Direct Observation of the Oxygenated Species during Oxygen Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray ...

  19. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, Donald E.

    1992-01-01

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  20. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, D.E.

    1992-07-14

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  1. PC Basic Linear Algebra Subroutines

    Energy Science and Technology Software Center (OSTI)

    1992-03-09

    PC-BLAS is a highly optimized version of the Basic Linear Algebra Subprograms (BLAS), a standardized set of thirty-eight routines that perform low-level operations on vectors of numbers in single and double-precision real and complex arithmetic. Routines are included to find the index of the largest component of a vector, apply a Givens or modified Givens rotation, multiply a vector by a constant, determine the Euclidean length, perform a dot product, swap and copy vectors, andmore » find the norm of a vector. The BLAS have been carefully written to minimize numerical problems such as loss of precision and underflow and are designed so that the computation is independent of the interface with the calling program. This independence is achieved through judicious use of Assembly language macros. Interfaces are provided for Lahey Fortran 77, Microsoft Fortran 77, and Ryan-McFarland IBM Professional Fortran.« less

  2. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-08-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

  3. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

  4. Fuel cell oxygen electrode

    DOE Patents [OSTI]

    Shanks, H.R.; Bevolo, A.J.; Danielson, G.C.; Weber, M.F.

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A/sub x/WO/sub 3/ where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt/sub y/WO/sub 3/ where y is at least 0.8.

  5. Fuel cell oxygen electrode

    DOE Patents [OSTI]

    Shanks, Howard R. (Ames, IA); Bevolo, Albert J. (Ames, IA); Danielson, Gordon C. (Ames, IA); Weber, Michael F. (Wichita, KS)

    1980-11-04

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A.sub.x WO.sub.3 where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt.sub.y WO.sub.3 where y is at least 0.8.

  6. VWA-0015- In the Matter of Am-Pro Protective Services, Inc.

    Broader source: Energy.gov [DOE]

    This Initial Agency Decision concerns a whistleblower complaint filed by Barry Stutts, a former security officer for Am-Pro Protective Services, Inc. (Am-Pro). It is undisputed that: Mr. Stutts and...

  7. Photovoltaic System Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Basics Photovoltaic System Basics August 20, 2013 - 4:00pm Addthis A photovoltaic (PV), or solar electric system, is made up of several photovoltaic solar cells. An ...

  8. Photovoltaic Cell Structure Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Structure Basics Photovoltaic Cell Structure Basics August 19, 2013 - 4:50pm Addthis The actual structural design of a photovoltaic (PV), or solar cell, depends on the ...

  9. Photovoltaic Silicon Cell Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Silicon Cell Basics Photovoltaic Silicon Cell Basics August 20, 2013 - 2:19pm Addthis Silicon-used to make some the earliest photovoltaic (PV) devices-is still the most popular ...

  10. Photovoltaic Cell Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Basics Photovoltaic Cell Basics August 16, 2013 - 4:53pm Addthis Photovoltaic (PV) cells, or solar cells, take advantage of the photoelectric effect to produce electricity. PV ...

  11. Solar Water Heater Basics | Department of Energy

    Energy Savers [EERE]

    Water Heating Solar Water Heater Basics Solar Water Heater Basics August 19, 2013 - 3:01pm Addthis Illustration of an active, closed loop solar water heater. A large, flat panel ...

  12. Hydrogen Fuel Cell Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Basics Hydrogen Fuel Cell Basics Hydrogen is a versatile energy carrier that can be used to power nearly every end-use energy need. The fuel cell-an energy conversion ...

  13. Basic Research Needs for the Hydrogen Economy

    Fuel Cell Technologies Publication and Product Library (EERE)

    The Basic Energy Sciences (BES) Workshop on Hydrogen Production, Storage and Use was held May 13-15, 2003 to assess the basic research needs to assure a secure energy future. This report is based on t

  14. Basic Energy Sciences (BES) at LLNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Basic Energy Sciences at LLNL Eric Schwegler is the Point-of-Contact for DOE Office of Science Programs - Basic Energy Sciences (BES) at LLNL. Highlights Mesoscale Simulations of ...

  15. Wind Energy Resource Basics | Department of Energy

    Energy Savers [EERE]

    Wind Wind Energy Resource Basics Wind Energy Resource Basics July 30, 2013 - 3:11pm Addthis Wind energy can be produced anywhere in the world where the wind blows with a strong ...

  16. PIA - Savannah River Nuclear Solution SRNS ProRad Environment Management |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy SRNS ProRad Environment Management PIA - Savannah River Nuclear Solution SRNS ProRad Environment Management PIA - Savannah River Nuclear Solution SRNS ProRad Environment Management PDF icon PIA - Savannah River Nuclear Solution SRNS ProRad Environment Management More Documents & Publications PIA - Savannah River Nuclear Solutions (SRNS) Human Resource Management System (HRMS) PIA - Savannah River Nuclear Solution (SRNS) Procurement Cycle System (PCS) PIA - Savannah

  17. Lighting and Daylighting Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Homes & Buildings » Lighting and Daylighting Basics Lighting and Daylighting Basics August 15, 2013 - 5:05pm Addthis Buildings can be lit in two ways: by using artificial lighting, or by using daylighting, or the process of using natural sunlight, windows, and skylights to provide lighting. Learn more about: Lighting Daylighting Addthis Related Articles Daylighting Basics Energy 101: Daylighting The Biggest, Brightest Star of Energy Efficiency Energy Basics Home Renewable Energy Homes &

  18. Biomass Basics: The Facts About Bioenergy

    SciTech Connect (OSTI)

    2015-04-01

    Biomass Basics: The Facts About Bioenergy. This document provides general information about bioenergy and its creation and potential uses.

  19. Basic ReseaRch DiRections

    National Nuclear Security Administration (NNSA)

    Basic ReseaRch DiRections for User Science at the National Ignition Facility Report on the National Nuclear Security Administration - Office of Science Workshop on Basic Research Directions on User Science at the National Ignition Facility BASIC RESEARCH DIRECTIONS FOR USER SCIENCE AT THE NATIONAL IGNITION FACILITY Report on the National Nuclear Security Administration (NNSA) - Office of Science (SC) Workshop on Basic Research Directions on User Science at the National Ignition Facility Chairs:

  20. Oxygen Transport Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay

    2008-08-30

    The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phase membranes have been evaluated for structural properties. An increasing crack growth resistance was observed for the membranes heat-treated at 1000 C in air and N{sub 2} with increasing crack length. The combined effect of thermal and elastic mismatch stresses on the crack path was studied and the fracture behavior of the dual phase composite at the test conditions was analyzed. Ceramic/metal (C/M) seals are needed to form a leak-tight interface between the OTM and a nickel-base super alloy. It was concluded that Ni-based brazing alloys provided the best option in terms of brazing temperature and final operating conditions after analyzing several possible brazing systems. A mechanical testing procedure has been developed. This model was tested with model ceramic/metal systems but it is expected to be useful for testing concentric perovskite/metal seals.

  1. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  2. Energy Basics Website Contact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Basics Website Contact Energy Basics Website Contact Use this form to send us your comments, report problems, and/or ask questions about information on the Energy Basics website. Your Email Message Here * CAPTCHA This question is for testing whether you are a human visitor and to prevent automated spam submissions. Submit

  3. Composite oxygen transport membrane

    SciTech Connect (OSTI)

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  4. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2000-10-01

    This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

  5. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Arthur J. Ragauskas Lucian A. Lucia Hasan Jameel

    2005-09-30

    The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in yield and 4 cP in viscosity in comparison to high AA pulp for the oxygen delignification. This difference is also seen for high-kappa SW kraft pulps with an average improvement of {approx}3% in yield and 3 cP in viscosity for low AA high kappa number 50 pulp. Low AA hardwood kappa number 20 pulp had an average improvement of {approx}4% in yield and 6-12 cP in viscosity as compared to high AA pulp. Lower kraft cooking temperature (160 vs. 170 C) in combination with the medium AA provides a practical approach for integrating high kappa pulping of hardwoods (i.e., low rejects) with an advanced extended oxygen delignification stage. ECF pulp bleaching of low and high kappa kraft SW and HW pulps exhibit comparable optical and physical strength properties when bleached D(EPO)D.

  6. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on...

  7. Researchers Directly Observe Oxygen Signature in the Oxygen-evolving

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Complex of Photosynthesis Researchers Directly Observe Oxygen Signature in the Oxygen-evolving Complex of Photosynthesis Arguably the most important chemical reaction on earth is the photosynthetic splitting of water to molecular oxygen by the Mn-containing oxygen-evolving complex (Mn-OEC) in the protein known as photosystem II (PSII). It is this reaction which has, over the course of some 3.8 billion years, gradually filled our atmosphere with O2 and consequently enabled and sustained the

  8. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

  9. Oxygenates from synthesis gas

    SciTech Connect (OSTI)

    Falter, W.; Keim, W.

    1994-12-31

    The direct synthesis of oxygenates starting from synthesis gas is feasible by homogeneous and heterogeneous catalysis. Homogeneous Rh and Ru based catalysts yielding methyl formate and alcohols will be presented. Interestingly, modified heterogeneous catalysts based on {open_quotes}Isobutyl Oel{close_quotes} catalysis, practized in Germany (BRD) up to 1952 and in the former DDR until recently, yield isobutanol in addition to methanol. These {open_quotes}Isobutyl Oel{close_quotes} catalysts are obtained by adding a base such as Li < Na < K < Cs to a Zn-Cr{sub 2}O{sub 3} methanol catalyst. Isobutanol is obtained in up to 15% yield. Our best catalyst a Zr-Zn-Mn-Li-Pd catalyst produced isobotanol up to 60% at a rate of 740g isobutanol per liter catalyst and hour.

  10. Bio-Benefits Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Education & Workforce Development » Resources » Biomass Basics » Bio-Benefits Basics Bio-Benefits Basics Biomass is an important commodity for the future of the United States. Increased production and use of biofuels will result in a variety of benefits to the nation, including: Improved national energy security Increased economic growth Broad-based environmental benefits. Biomass and U.S. Energy Security The U.S. economy is heavily dependent on oil imports-containing 4% of the world's

  11. Wind Energy Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Information Resources » Wind Energy Basics Wind Energy Basics Wind Energy Basics Once called windmills, the technology used to harness the power of wind has advanced significantly over the past ten years, with the United States increasing its wind power capacity 30% year over year. Wind turbines, as they are now called, collect and convert the kinetic energy that wind produces into electricity to help power the grid. Wind energy is actually a byproduct of the sun. The sun's uneven heating of

  12. Air-Conditioning Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air-Conditioning Basics Air-Conditioning Basics August 16, 2013 - 1:59pm Addthis Air conditioning is one of the most common ways to cool homes and buildings. How Air Conditioners Work Air conditioners employ the same operating principles and basic components as refrigerators. Refrigerators use energy (usually electricity) to transfer heat from the cool interior of the refrigerator to the relatively warm surroundings; likewise, an air conditioner uses energy to transfer heat from the interior

  13. National Laboratory] Basic Biological Sciences(59) Biological...

    Office of Scientific and Technical Information (OSTI)

    Achievements of structural genomics Terwilliger, Thomas C. Los Alamos National Laboratory Basic Biological Sciences(59) Biological Science Biological Science Abstract Not...

  14. Electric-Drive Vehicle Basics (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2011-04-01

    Describes the basics of electric-drive vehicles, including hybrid electric vehicles, plug-in hybrid electric vehicles, all-electric vehicles, and the various charging options.

  15. NREL: Concentrating Solar Power Research - Technology Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology Basics Concentrating solar power (CSP) technologies can be a major contributor to our nation's future need for new, clean sources of energy, particularly in the Western...

  16. Vehicle Battery Basics | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Battery Basics Batteries are essential for electric drive technologies such as hybrid ... Batteries have three main parts, each of which plays a different role: the anode, cathode, ...

  17. Active Solar Heating Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    economics, selection and sizing, control systems, building codes and covenants, and installation and maintenance. Addthis Related Articles Linear Concentrator System Basics for ...

  18. Oxygen-reducing catalyst layer

    DOE Patents [OSTI]

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; Yang, Ruizhi; Easton, E. Bradley; Dahn, Jeffrey R.; O'Neill, David G.

    2011-03-22

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  19. EIA-819, Monthly Oxygenate Report ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (EIA) Form EIA-819, "Monthly Biofuel and Oxygenate Report," is used to collect data on ethanol production capacity, as well as stocks, receipts, inputs, production, and blending of...

  20. Rotation Manager Pro Version 1.0b1

    Energy Science and Technology Software Center (OSTI)

    2002-02-01

    The Rotation Manager Pro Package maintains databases of instructions to replicate plate tectonic movements. The instructions are in the standard of tectonic plate rotations, including plate identification and location and angle of the rotation pole. Each database is accompanied by various metadata, including information about each rotation pole and the database itself. The package provides a range of tools to actively manage the database using methods specifically required for rotations: rotation pole addition and subtraction,more » viewing of a rotation chain through the rotation hierarchy, and the rotation of data points.« less

  1. Liquefied Natural Gas: Understanding the Basic Facts | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Liquefied Natural Gas: Understanding the Basic Facts Liquefied Natural Gas: Understanding the Basic Facts PDF icon Liquefied Natural Gas: Understanding the Basic Facts More ...

  2. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-10-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  3. Review - basic research needs in fluid mechanics

    SciTech Connect (OSTI)

    Jones, O.C. Jr.; Kreith, F.; White, F.M.

    1981-12-01

    A small segment of the engineering community was surveyed to obtain their judgement regarding the long-range needs for basic research in fluid mechanics. It is the purpose of this paper to provide a summary of a more detailed report, which identifies basic research needed in fluid mechanics. 12 refs.

  4. Fuel cell electrolyte membrane with basic polymer

    DOE Patents [OSTI]

    Larson, James M.; Pham, Phat T.; Frey, Matthew H.; Hamrock, Steven J.; Haugen, Gregory M.; Lamanna, William M.

    2010-11-23

    The present invention is an electrolyte membrane comprising an acid and a basic polymer, where the acid is a low-volatile acid that is fluorinated and is either oligomeric or non-polymeric, and where the basic polymer is protonated by the acid and is stable to hydrolysis.

  5. Fuel cell electrolyte membrane with basic polymer

    DOE Patents [OSTI]

    Larson, James M.; Pham, Phat T.; Frey, Matthew H.; Hamrock, Steven J.; Haugen, Gregory M.; Lamanna, William M.

    2012-12-04

    The present invention is an electrolyte membrane comprising an acid and a basic polymer, where the acid is a low-volatile acid that is fluorinated and is either oligomeric or non-polymeric, and where the basic polymer is protonated by the acid and is stable to hydrolysis.

  6. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-02-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

  7. Oxygen detection using evanescent fields

    DOE Patents [OSTI]

    Duan, Yixiang; Cao, Weenqing

    2007-08-28

    An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

  8. V-210: HP LaserJet Pro Printer Bug Lets Remote Users Access Data

    Broader source: Energy.gov [DOE]

    A potential security vulnerability has been identified with certain HP LaserJet Pro printers. The vulnerability could be exploited remotely to gain unauthorized access to data.

  9. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana

    2003-08-07

    In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

  10. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-11-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

  11. Fusion Basics | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fusion Basics What is Plasma? Plasma is a state of matter along with solids, liquids and ... and Aurora Australis Fusion reactors, like NSTX, use plasma to fuse atoms to make energy. ...

  12. Basic Research Needs for Countering Terrorism

    SciTech Connect (OSTI)

    Stevens, W.; Michalske, T.; Trewhella, J.; Makowski, L.; Swanson, B.; Colson, S.; Hazen, T.; Roberto, F.; Franz, D.; Resnick, G.; Jacobson, S.; Valdez, J.; Gourley, P.; Tadros, M.; Sigman, M.; Sailor, M.; Ramsey, M.; Smith, B.; Shea, K.; Hrbek, J.; Rodacy, P.; Tevault, D.; Edelstein, N.; Beitz, J.; Burns, C.; Choppin, G.; Clark, S.; Dietz, M.; Rogers, R.; Traina, S.; Baldwin, D.; Thurnauer, M.; Hall, G.; Newman, L.; Miller, D.; Kung, H.; Parkin, D.; Shuh, D.; Shaw, H.; Terminello, L.; Meisel, D.; Blake, D.; Buchanan, M.; Roberto, J.; Colson, S.; Carling, R.; Samara, G.; Sasaki, D.; Pianetta, P.; Faison, B.; Thomassen, D.; Fryberger, T.; Kiernan, G.; Kreisler, M.; Morgan, L.; Hicks, J.; Dehmer, J.; Kerr, L.; Smith, B.; Mays, J.; Clark, S.

    2002-03-01

    To identify connections between technology needs for countering terrorism and underlying science issues and to recommend investment strategies to increase the impact of basic research on efforts to counter terrorism.

  13. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

    2003-11-01

    The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with the results from the previous batch.

  14. NREL: Hydrogen and Fuel Cells Research - Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Basics Photo of vehicle filling up at renewable hydrogen fueling station. NREL's hydrogen fueling station dispenses hydrogen produced via renewable electrolysis. Photo by Dennis Schroeder, NREL NREL researchers are working to unlock the potential of hydrogen as a fuel and to advance fuel cell technologies for automobiles, equipment, and buildings. View the Hydrogen Program video on NREL's YouTube channel to learn more about the basics of NREL's hydrogen and fuel cell

  15. Geothermal Technology Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Technology Basics Geothermal Technology Basics August 14, 2013 - 1:45pm Addthis Photo of steam pouring out of a geothermal plant. Geothermal technologies use the clean, sustainable heat from the Earth. Geothermal resources include the heat retained in shallow ground, hot water and rock found a few miles beneath the Earth's surface, and extremely high-temperature molten rock called magma located deep in the Earth. Learn more about: Direct-Use Geothermal Technologies Geothermal

  16. Hydropower Technology Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydropower Technology Basics Hydropower Technology Basics August 14, 2013 - 3:03pm Addthis Text Version Photo of the reservoir in front of a hydropower dam. Hydropower, or hydroelectric power, is the most common and least expensive source of renewable electricity in the United States today. According to the Energy Information Administration, more than 6% of the country's electricity was produced from hydropower resources in 2014, and about 48% of all renewable electricity generated in the United

  17. Industrial Energy Efficiency Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrial Energy Efficiency Basics Industrial Energy Efficiency Basics The industrial sector is vital to the U.S. economy, but at the same time consumes the most energy in the country to manufacture products we use every day. Among the most energy-intensive industries are aluminum, chemicals, forest product, glass, metal casting, mining, petroleum refining, and steel. The energy supply chain begins with electricity, steam, natural gas, coal, and other fuels supplied to a manufacturing plant

  18. Renewable Energy Technology Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy Technology Basics Renewable Energy Technology Basics Renewable energy technologies produce sustainable, clean energy from sources such as the sun, the wind, plants, and water. According to the Energy Information Administration, in 2007, renewable sources of energy accounted for about 7% of total energy consumption and 9.4% of total electricity generation in the United States. Renewable energy technologies have the potential to strengthen our nation's energy security, improve

  19. Solar Energy Technology Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Solar Energy Technology Basics Solar Energy Technology Basics August 16, 2013 - 4:37pm Addthis Solar energy technologies produce electricity from the energy of the sun. Small solar energy systems can provide electricity for homes, businesses, and remote power needs. Larger solar energy systems provide more electricity for contribution to the electric power system. Learn more about: Photovoltaics Concentrating Solar Power Solar Energy Resources Or learn about the latest solar

  20. Wind Energy Technology Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Wind Energy Technology Basics Wind Energy Technology Basics August 15, 2013 - 4:10pm Addthis Photo of a hilly field, with six visible wind turbines spinning in the wind. Wind energy technologies use the energy in wind for practical purposes such as generating electricity, charging batteries, pumping water, and grinding grain. Wind energy is a result of the sun's uneven heating of the atmosphere, the earth's irregular surfaces (mountains and valleys), and the planet's

  1. Ventilation System Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ventilation System Basics Ventilation System Basics August 16, 2013 - 1:33pm Addthis Ventilation is the process of moving air into and out of an interior space by natural or mechanical means. Ventilation is necessary for the health and comfort of occupants of all buildings. Ventilation supplies air for occupants to breathe and removes moisture, odors, and indoor pollutants like carbon dioxide. Too little ventilation may result in poor indoor air quality, while too much may cause unnecessarily

  2. Workplace Charging Station Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Station Basics Workplace Charging Station Basics As your organization moves forward with workplace charging, it is important to understand the fundamental differences and similarities between the types of charging stations, commonly referred to as electric vehicle supply equipment (EVSE) units. Charging stations deliver electrical energy from an electricity source to a plug-in electric vehicle (PEV) battery. There are three primary types of charging stations: AC Level 1, AC Level 2 and DC fast

  3. Evaporative Cooling Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaporative Cooling Basics Evaporative Cooling Basics August 16, 2013 - 1:53pm Addthis Evaporative cooling uses evaporated water to naturally and energy-efficiently cool. An illustration of an evaporative cooler. In this example of an evaporative cooler, a small motor (top) drives a large fan (center) which blows air out the bottom and into your home. The fan sucks air in through the louvers around the box, which are covered with water-saturated absorbent material. How Evaporative Coolers Work

  4. Biofuel Conversion Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biofuel Conversion Basics Biofuel Conversion Basics August 14, 2013 - 12:31pm Addthis The conversion of biomass solids into liquid or gaseous biofuels is a complex process. Today, the most common conversion processes are biochemical- and thermochemical-based. However, researchers are also exploring photobiological conversion processes. Biochemical Conversion Processes In biochemical conversion processes, enzymes and microorganisms are used as biocatalysts to convert biomass or biomass-derived

  5. Biomass Resource Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Resource Basics Biomass Resource Basics August 14, 2013 - 1:22pm Addthis Biomass resources include any plant-derived organic matter that is available on a renewable basis. These materials are commonly referred to as feedstocks. Biomass Feedstocks Biomass feedstocks include dedicated energy crops, agricultural crops, forestry residues, aquatic crops, biomass processing residues, municipal waste, and animal waste. Dedicated energy crops Herbaceous energy crops are perennials that are

  6. Enhanced Geothermal System Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal » Enhanced Geothermal System Basics Enhanced Geothermal System Basics A naturally occurring geothermal system, known as Enhanced Geothermal Systems (EGS), is another form of renewable energy. It is defined by three key elements: heat, fluid, and permeability at depth. Essentially, these are engineered reservoirs that produce energy from geothermal resources in areas that are not usually considered economically viable due to a lack of water and/or the ability of that water to pass

  7. Fuel Cell Vehicle Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicles & Fuels » Vehicles » Fuel Cell Vehicle Basics Fuel Cell Vehicle Basics August 20, 2013 - 9:11am Addthis Photo of a blue car with 'The Road to Hydrogen' written on it, filling up at a hydrogen fueling station. Fuel cell vehicles, powered by hydrogen, could greatly improve the sustainability of our transportation sector. Although electricity production may contribute to air pollution, they are more efficient than conventional internal combustion engine vehicles and produce no

  8. Geothermal Electricity Production Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Production Basics Geothermal Electricity Production Basics August 14, 2013 - 1:49pm Addthis A photo of steam emanating from geothermal power plants at The Geysers in California. Geothermal energy originates from deep within the Earth and produces minimal emissions. Photo credit: Pacific Gas & Electric Heat from the earth-geothermal energy-heats water that has seeped into underground reservoirs. These reservoirs can be tapped for a variety of uses, depending on the temperature of

  9. Geothermal Resource Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Geothermal » Geothermal Resource Basics Geothermal Resource Basics August 14, 2013 - 1:58pm Addthis Although geothermal heat pumps can be used almost anywhere, most direct-use and electrical production facilities in the United States are located in the west, where the geothermal resource base is concentrated. Current drilling technology limits the development of geothermal resources to relatively shallow water- or steam-filled reservoirs, most of which are found in the

  10. Hydrogen Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Hydrogen & Fuel Cells » Hydrogen Fuel Basics Hydrogen Fuel Basics August 14, 2013 - 2:06pm Addthis Hydrogen is a clean fuel that, when consumed in a fuel cell, produces only water. Hydrogen can be produced from a variety of domestic resources, such as natural gas, nuclear power, biomass, and renewable power like solar and wind. These qualities make it an attractive fuel option for transportation and electricity generation applications. It can be used in cars, in houses,

  11. Hydrogen Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicles & Fuels » Fuels » Hydrogen Fuel Basics Hydrogen Fuel Basics August 19, 2013 - 5:45pm Addthis Hydrogen (H2) is a potentially emissions-free alternative fuel that can be produced from domestic resources. Although not widely used today as a transportation fuel, government and industry research and development are working toward the goal of clean, economical, and safe hydrogen production and hydrogen-powered fuel cell vehicles. Hydrogen is the simplest and most abundant element in the

  12. Internal Combustion Engine Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Internal Combustion Engine Basics Internal Combustion Engine Basics November 22, 2013 - 2:02pm Addthis Internal combustion engines provide outstanding drivability and durability, with more than 250 million highway transportation vehicles in the United States relying on them. Along with gasoline or diesel, they can also utilize renewable or alternative fuels (e.g., natural gas, propane, biodiesel, or ethanol). They can also be combined with hybrid electric powertrains to increase fuel economy or

  13. Absorption Cooling Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cooling Basics Absorption Cooling Basics August 16, 2013 - 2:26pm Addthis Absorption coolers use heat rather than electricity as their energy source. Because natural gas is the most common heat source for absorption cooling, it is also referred to as gas-fired cooling. Other potential heat sources include propane, solar-heated water, or geothermal-heated water. Although mainly used in industrial or commercial settings, absorption coolers are commercially available for large residential homes.

  14. Anaerobic Digestion Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Anaerobic Digestion Basics Anaerobic Digestion Basics August 14, 2013 - 1:07pm Addthis Anaerobic digestion is a common technology in today's agriculture, municipal waste, and brewing industries. It uses bacteria to break down waste organic materials into methane and other gases, which can be used to produce electricity or heat. Methane and Anaerobic Bacteria Methane is a gas that contains molecules of methane with one atom of carbon and four atoms of hydrogen (CH4). It is the major component of

  15. Hydrogen Storage Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Education » Increase Your H2IQ » Hydrogen Storage Basics Hydrogen Storage Basics Developing safe, reliable, compact, and cost-effective hydrogen storage technologies is one of the most technically challenging barriers to the widespread use of hydrogen as a form of energy. To be competitive with conventional vehicles, hydrogen-powered cars must be able to travel more than 300 miles between fills. This is a challenging goal because hydrogen has physical characteristics that make it difficult to

  16. Lesson 1 - Energy Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 - Energy Basics Lesson 1 - Energy Basics This lesson covers the states and forms of energy, where energy comes from, as well as how the way we live is tied to our energy supply and what that means for the future. Specific topics include: States of energy Potential Kinetic Forms of energy Energy sources Primary and secondary sources Renewable and nonrenewable Conversion Conservation Environmental impacts Greenhouse effect Future sources File Lesson 1 - Energy.pptx More Documents &

  17. Electric Resistance Heating Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Resistance Heating Basics Electric Resistance Heating Basics August 16, 2013 - 3:10pm Addthis Electric resistance heat can be supplied by centralized forced-air electric furnaces or by heaters in each room. Electric resistance heating converts nearly all of the energy in the electricity to heat. Types of Electric Resistance Heaters Electric resistance heat can be provided by electric baseboard heaters, electric wall heaters, electric radiant heat, electric space heaters, electric

  18. Solar Photovoltaic Technology Basics | Department of Energy

    Office of Environmental Management (EM)

    Solar Photovoltaic System Design Basics Solar Photovoltaic System Design Basics August 20, 2013 - 4:00pm Addthis Solar photovoltaic modules are where the electricity gets generated, but are only one of the many parts in a complete photovoltaic (PV) system. In order for the generated electricity to be useful in a home or business, a number of other technologies must be in place. Mounting Structures PV arrays must be mounted on a stable, durable structure that can support the array and withstand

  19. A lithium oxygen secondary battery

    SciTech Connect (OSTI)

    Semkow, K.W.; Sammells, A.F.

    1987-08-01

    In principle the lithium-oxygen couple should provide one of the highest energy densities yet investigated for advanced battery systems. The problem to this time has been one of identifying strategies for achieving high electrochemical reversibilities at each electrode under conditions where one might anticipate to also achieve long materials lifetimes. This has been addressed in recent work by us via the application of stabilized zirconia oxygen vacancy conducting solid electrolytes, for the effective separation of respective half-cell reactions.

  20. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  1. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Download presentation slides from the June 19,...

  2. Alternative Fuels Data Center: Natural Gas Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Natural Gas Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Natural Gas Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Natural Gas Fuel Basics on Google Bookmark Alternative Fuels Data Center: Natural Gas Fuel Basics on Delicious Rank Alternative Fuels Data Center: Natural Gas Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Natural Gas Fuel Basics on

  3. Peer review, basic research, and engineering: Defining a role for QA professionals in basic research environments

    SciTech Connect (OSTI)

    Bodnarczuk, M.

    1989-02-01

    Within the context of doing basic research, this paper seeks to answer four major questions: (1) What is the authority structure of science. (2) What is peer review. (3) Where is the interface between basic physics research and standard engineering. and (4) Given the conclusions to the first three questions, what is the role of the QA professional in a basic research environment like Fermilab. 23 refs.

  4. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-05-01

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped Ti-substituted perovskites, La{sub 0.7}Sr{sub 0.3}Mn{sub 1-x}Ti{sub x}O{sub 3}, with 0 {le} x {le} 0.20, were investigated by neutron diffraction, magnetization, electric resistivity, and magnetoresistance (MR) measurements. All samples show a rhombohedral structure (space group R3C) from 10 K to room temperature. At room temperature, the cell parameters a, c and the unit cell volume increase with increasing Ti content. However, at 10 K, the cell parameter a has a maximum value for x = 0.10, and decreases for x > 0.10, while the unit cell volume remains nearly constant for x > 0.10. The average (Mn,Ti)-O bond length increases up to x = 0.15, and the (Mn,Ti)-O-(Mn,Ti) bond angle decreases with increasing Ti content to its minimum value at x = 0.15 at room temperature. Below the Curie temperature TC, the resistance exhibits metallic behavior for the x {le} 0.05 samples. A metal (semiconductor) to insulator transition is observed for the x {ge} 0.10 samples. A peak in resistivity appears below TC for all samples, and shifts to a lower temperature as x increases. The substitution of Mn by Ti decreases the 2p-3d hybridization between O and Mn ions, reduces the bandwidth W, and increases the electron-phonon coupling. Therefore, the TC shifts to a lower temperature and the resistivity increases with increasing Ti content. A field-induced shift of the resistivity maximum occurs at x {le} 0.10 compounds. The maximum MR effect is about 70% for La{sub 0.7}Sr{sub 0.3}Mn{sub 0.8}Ti{sub 0.2}O{sub 3}. The separation of TC and the resistivity maximum temperature T{sub {rho},max} enhances the MR effect in these compounds due to the weak coupling between the magnetic ordering and the resistivity as compared with La{sub 0.7}Sr{sub 0.3}MnO{sub 3}. The bulk densities of the membranes were determined using the Archimedes method. The bulk density was 5.029 and 5.57 g/cc for LSFT and dual phase membranes, respectively. The microstructure of the dual phase membrane was analyzed using SEM. It is evident from the micrograph that the microstructure is composed of dual phases. The dense circular regions are enclosed by the less dense, continuous phase which accommodates most of the pores. The pores are normally aggregated and found clustered along the dense regions where as the dense regions do not have pores. Upon closer observation of the micrograph it is revealed that the dense region has a clear circular cleavage or crack as their boundary. The circular cleavage clearly encompasses a dense region and which consists of no pore or any flaw that is visible. The size distribution of the dense, discontinuous regions is varying from 5 to 20 {micro}m with a D{sub 50} of 15 {micro}m. The grain size distribution was estimated from the micrographs using image analysis and a unimodal distribution of grains was observed with an average grain size of 1.99 {micro}m. The chemical compositions of the membranes were analyzed using EDS analysis and no other impurities were observed. The XRD analysis was carried out for the membranes and the phase purity was confirmed. The fracture toughness of LSFT membranes at room temperature has to be calculated using the Vickers indentation method. An electrochemical cell has been designed and built for measurements of the ionic conductivity by the use of blocking electrodes. Preliminary measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Modifications to the apparatus to improve the data quality have been completed. Electron microscopy studies of the origin of the slow kinetics on reduction of ferrites have been initiated. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  5. EVALUATING AN INNOVATIVE OXYGEN SENSOR FOR REMOTE SUBSURFACE OXYGEN MEASUREMENTS

    SciTech Connect (OSTI)

    Millings, M; Brian Riha, B; Warren Hyde, W; Karen Vangelas, K; Brian02 Looney, B

    2006-10-12

    Oxygen is a primary indicator of whether anaerobic reductive dechlorination and similar redox based processes contribute to natural attenuation remedies at chlorinated solvent contaminated sites. Thus, oxygen is a viable indicator parameter for documenting that a system is being sustained in an anaerobic condition. A team of researchers investigated the adaptation of an optical sensor that was developed for oceanographic applications. The optical sensor, because of its design and operating principle, has potential for extended deployment and sensitivity at the low oxygen levels relevant to natural attenuation. The results of the research indicate this tool will be useful for in situ long-term monitoring applications, but that the traditional characterization tools continue to be appropriate for characterization activities.

  6. Biomass Technology Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Technology Basics Biomass Technology Basics August 14, 2013 - 11:31am Addthis Photo of a pair of hands holding corn stover, the unused parts of harvested corn. There are many types of biomass-organic matter such as plants, residue from agriculture and forestry, and the organic component of municipal and industrial wastes-that can now be used to produce fuels, chemicals, and power. Wood has been used to provide heat for thousands of years. This flexibility has resulted in increased use of

  7. Ocean Energy Technology Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Ocean Energy Technology Basics Ocean Energy Technology Basics August 16, 2013 - 4:18pm Addthis Text Version Photo of low waves in the ocean. A dock is visible in the background. Oceans cover more than 70% of the Earth's surface. As the world's largest solar collectors, oceans contain thermal energy from the sun and produce mechanical energy from tides and waves. Even though the sun affects all ocean activity, the gravitational pull of the moon primarily drives tides, and wind

  8. Wave Energy Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ocean » Wave Energy Basics Wave Energy Basics August 16, 2013 - 4:30pm Addthis Photo of a large wave. Wave energy technologies extract energy directly from surface waves or from pressure fluctuations below the surface. Renewable energy analysts believe there is enough energy in ocean waves to provide up to 2 terawatts of electricity. (A terawatt is equal to a trillion watts.) However, wave energy cannot be harnessed everywhere. Wave power-rich areas of the world include the western coasts of

  9. Flexible Fuel Vehicle Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicles & Fuels » Vehicles » Flexible Fuel Vehicle Basics Flexible Fuel Vehicle Basics August 20, 2013 - 9:05am Addthis Photo of a gray van with 'E85 Ethanol' written on the side. Flexible fuel vehicles (FFVs) have an internal combustion engine and are capable of operating on gasoline, E85 (a high-level blend of gasoline and ethanol), or a mixture of both. There are more than 10.6 million flexible fuel vehicles on U.S. roads today. However, many flexible fuel vehicle owners don't realize

  10. Fuel Cell Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Hydrogen & Fuel Cells » Fuel Cell Basics Fuel Cell Basics August 14, 2013 - 2:09pm Addthis Text Version Photo of two hydrogen fuel cells. Fuel cells can provide heat and electricity for buildings and electrical power for vehicles and electronic devices. HOW FUEL CELLS WORK Fuel cells work like batteries, but they do not run down or need recharging. They produce electricity and heat as long as fuel is supplied. A fuel cell consists of two electrodes-a negative electrode

  11. Geothermal Heat Pump Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Heat Pump Basics Geothermal Heat Pump Basics August 19, 2013 - 11:12am Addthis Text Version Geothermal heat pumps use the constant temperature of the earth as an exchange medium for heat. Although many parts of the country experience seasonal temperature extremes-from scorching heat in the summer to sub-zero cold in the winter-the ground a few feet below the earth's surface remains at a relatively constant temperature. Depending on the latitude, ground temperatures range from 45°F

  12. Heat Pump System Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Space Heating & Cooling » Heat Pump System Basics Heat Pump System Basics August 19, 2013 - 11:02am Addthis Like a refrigerator, heat pumps use electricity to move heat from a cool space into a warm space, making the cool space cooler and the warm space warmer. Because they move heat rather than generate heat, heat pumps can provide up to four times the amount of energy they consume. Air-Source Heat Pump Transfers heat between the inside of a building and the outside air. Ductless

  13. Heating System Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Basics Heating System Basics August 16, 2013 - 2:32pm Addthis A variety of heating technologies are available today. You can learn more about what heating systems and heat pumps are commonly used today and how they work below. To learn how to use these technologies in your own home, see the Home Heating Systems section on Energy Saver. Furnaces and Boilers Furnaces heat air and distribute the heated air through a building using ducts. Boilers heat water, providing either hot water or

  14. Lesson 2 - Electricity Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 - Electricity Basics Lesson 2 - Electricity Basics It's difficult to imagine life without convenient electricity. You just flip a switch or plug in an appliance, and it's there. But how did it get there? Many steps go into providing the reliable electricity we take for granted. This lesson takes a closer look at electricity. It follows the path of electricity from the fuel source to the home, including the power plant and the electric power grid. It also covers the role of electric utilities

  15. Criticality safety basics, a study guide

    SciTech Connect (OSTI)

    V. L. Putman

    1999-09-01

    This document is a self-study and classroom guide, for criticality safety of activities with fissile materials outside nuclear reactors. This guide provides a basic overview of criticality safety and criticality accident prevention methods divided into three parts: theory, application, and history. Except for topic emphasis, theory and history information is general, while application information is specific to the Idaho National Engineering and Environmental Laboratory (INEEL). Information presented here should be useful to personnel who must know criticality safety basics to perform their assignments safely or to design critically safe equipment or operations. However, the guide's primary target audience is fissile material handler candidates.

  16. Tidal Energy Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Ocean » Tidal Energy Basics Tidal Energy Basics August 16, 2013 - 4:26pm Addthis Photo of the ocean rising along the beach. Some of the oldest ocean energy technologies use tidal power. All coastal areas experience two high tides and two low tides over a period of slightly more than 24 hours. For those tidal differences to be harnessed into electricity, the difference between high and low tides must be more than 16 feet (or at least 5 meters). However, there are only about

  17. BERLinPro Booster Cavity Design, Fabrication and Test Plans

    SciTech Connect (OSTI)

    Burrill, Andrew; Anders, W; Frahm, A.; Knobloch, Jens; Neumann, Axel; Ciovati, Gianluigi; Kneisel, Peter K.; Turlington, Larry D.

    2014-12-01

    The bERLinPro project, a 100 mA, 50 MeV superconducting RF (SRF) Energy Recovery Linac (ERL) is under construction at Helmholtz-Zentrum Berlin for the purpose of studying the technical challenges and physics of operating a high current, c.w., 1.3 GHz ERL. This machine will utilize three unique SRF cryomodules for the injector, booster and linac module respectively. The booster cryomodule will contain three 2-cell SRF cavities, based on the original design by Cornell University, and will be equipped with twin 115 kW RF power couplers in order to provide the appropriate acceleration to the high current electron beam. This paper will review the status of the fabrication of the 4 booster cavities that have been built for this project by Jefferson Laboratory and look at the challenges presented by the incorporation of fundamental power couplers capable of delivering 115 kW. The test plan for the cavities and couplers will be given along with a brief overview of the cryomodule design.

  18. Cancer Associated Fibroblasts express pro-inflammatory factors in human breast and ovarian tumors

    SciTech Connect (OSTI)

    Erez, Neta; Glanz, Sarah; Raz, Yael; Department of Obstetrics and Gynecology, LIS Maternity Hospital, Tel Aviv Sourasky Medical Center, affiliated with Sackler Faculty of Medicine, Tel Aviv University, Tel Aviv ; Avivi, Camilla; Barshack, Iris; Department of Pathology, Sheba Medical Center, Tel Hashomer, affiliated with Sackler Faculty of Medicine, Tel Aviv University, Tel Aviv

    2013-08-02

    Highlights: CAFs in human breast and ovarian tumors express pro-inflammatory factors. Expression of pro-inflammatory factors correlates with tumor invasiveness. Expression of pro-inflammatory factors is associated with NF-?b activation in CAFs. -- Abstract: Inflammation has been established in recent years as a hallmark of cancer. Cancer Associated Fibroblasts (CAFs) support tumorigenesis by stimulating angiogenesis, cancer cell proliferation and invasion. We previously demonstrated that CAFs also mediate tumor-enhancing inflammation in a mouse model of skin carcinoma. Breast and ovarian carcinomas are amongst the leading causes of cancer-related mortality in women and cancer-related inflammation is linked with both these tumor types. However, the role of CAFs in mediating inflammation in these malignancies remains obscure. Here we show that CAFs in human breast and ovarian tumors express high levels of the pro-inflammatory factors IL-6, COX-2 and CXCL1, previously identified to be part of a CAF pro-inflammatory gene signature. Moreover, we show that both pro-inflammatory signaling by CAFs and leukocyte infiltration of tumors are enhanced in invasive ductal carcinoma as compared with ductal carcinoma in situ. The pro-inflammatory genes expressed by CAFs are known NF-?B targets and we show that NF-?B is up-regulated in breast and ovarian CAFs. Our data imply that CAFs mediate tumor-promoting inflammation in human breast and ovarian tumors and thus may be an attractive target for stromal-directed therapeutics.

  19. Alternative Fuels Data Center: Codes and Standards Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Codes and Standards Basics to someone by E-mail Share Alternative Fuels Data Center: Codes and Standards Basics on Facebook Tweet about Alternative Fuels Data Center: Codes and Standards Basics on Twitter Bookmark Alternative Fuels Data Center: Codes and Standards Basics on Google Bookmark Alternative Fuels Data Center: Codes and Standards Basics on Delicious Rank Alternative Fuels Data Center: Codes and Standards Basics on Digg Find More places to share Alternative Fuels Data Center: Codes and

  20. Controlling Subsurface Fractures and Fluid Flow: A Basic Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda PDF icon BES Report Controlling ...

  1. Flow cytometry aids basic cell biology research and drug discovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flow cytometry aids basic cell biology research and drug discovery Flow cytometry aids basic cell biology research and drug discovery Life Technologies Corporation and LANL have ...

  2. Revolving Loan Funds: Basics and Best Practices | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This webinar, held on Aug. 26, 2009, provides basic information and best practices for ... Clean Energy Finance Guide (Chapter 5: Basic Concepts for Clean Energy Unsecured ...

  3. A Basic Overview of Occupational Radiation Exposure Monitoring...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis & Reporting A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis & Reporting September ...

  4. Chapter 5. Basic Concepts for Clean Energy Unsecured Lending...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chapter 5. Basic Concepts for Clean Energy Unsecured Lending and Loan Loss Reserve Funds Chapter 5. Basic Concepts for Clean Energy Unsecured Lending and Loan Loss Reserve Funds ...

  5. OSHA Rulemaking on Basic Program Elements for Federal Employee...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health Programs and Related Matters; 29 CFR 1960 OSHA Rulemaking on Basic Program Elements ...

  6. Pamphlet, A Basic Overview of Occupational Radiation Exposure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pamphlet, A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis & Reporting Pamphlet, A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis & ...

  7. Photovoltaic Polycrystalline Thin-Film Cell Basics | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polycrystalline Thin-Film Cell Basics Photovoltaic Polycrystalline Thin-Film Cell Basics ... Silicon Single-Crystalline Thin Films Addthis Related Articles Photovoltaic Cell Structure ...

  8. Photovoltaic Electrical Contact and Cell Coating Basics | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrical Contact and Cell Coating Basics Photovoltaic Electrical Contact and Cell Coating Basics August 19, 2013 - 4:12pm Addthis The outermost layers of photovoltaic (PV) cell, ...

  9. Tankless Coil and Indirect Water Heater Basics | Department of...

    Energy Savers [EERE]

    Homes & Buildings Water Heating Tankless Coil and Indirect Water Heater Basics Tankless Coil and Indirect Water Heater Basics August 19, 2013 - 3:03pm Addthis Illustration of ...

  10. Tribal Renewable Energy Webinar: Transmission and Grid Basics...

    Energy Savers [EERE]

    Transmission and Grid Basics for Tribal Economic and Energy Development Tribal Renewable Energy Webinar: Transmission and Grid Basics for Tribal Economic and Energy Development ...

  11. Clean Energy Finance Guide (Chapter 5: Basic Concepts for Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean Energy Finance Guide (Chapter 5: Basic Concepts for Clean Energy Unsecured Lending and Loan Loss Reserve Funds) Clean Energy Finance Guide (Chapter 5: Basic Concepts for ...

  12. Biomass Basics: The Facts About Bioenergy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Basics: The Facts About Bioenergy Biomass Basics: The Facts About Bioenergy This document provides general information about bioenergy and its creation and potential uses....

  13. Advanced Strategy Guideline: Air Distribution Basics and Duct...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Strategy Guideline: Air Distribution Basics and Duct Design Arlan Burdick IBACOS, ... waste i Advanced Strategy Guideline: Air Distribution Basics and Duct Design ...

  14. Highly-basic large-pore zeolite catalysts for NOx reduction at low temperatures

    DOE Patents [OSTI]

    Penetrante, Bernardino M.; Brusasco, Raymond M.; Merritt, Bernard T.; Vogtlin, George E.

    2004-02-03

    A high-surface-area (greater than 600 m2/g), large-pore (pore size diameter greater than 6.5 angstroms), basic zeolite having a structure such as an alkali metal cation-exchanged Y-zeolite is employed to convert NO.sub.x contained in an oxygen-rich engine exhaust to N.sub.2 and O.sub.2. Preferably, the invention relates to a two-stage method and apparatus for NO.sub.x reduction in an oxygen-rich engine exhaust such as diesel engine exhaust that includes a plasma oxidative stage and a selective reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and added hydrocarbons. The second stage employs a lean-NO.sub.x catalyst including the basic zeolite at relatively low temperatures to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O.

  15. VWA-0015- Deputy Secretary Decision- In the Matter of Am-Pro Protective Services, Inc.

    Broader source: Energy.gov [DOE]

    Barry Stutts, Complainant v. Am-Pro Protective Agency, Inc., Respondent, OHA Case No. VWA-0015 DECISION DENYING REVIEW OF INITIAL AGENCY DECISION This is a request for review by Complainant Barry...

  16. DC Pro Software Tool Suite, Data Center Fact Sheet, Industrial Technologies Program

    SciTech Connect (OSTI)

    Not Available

    2009-04-01

    This fact sheet describes how DOE's Data Center Energy Profiler (DC Pro) Software Tool Suite and other resources can help U.S. companies identify ways to improve the efficiency of their data centers.

  17. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2000-01-01

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  18. NREL: Transportation Research - Sustainable Transportation Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Basics Compare Vehicle Technologies 3-D illustration of electric car diagramming energy storage, power electronics, and climate control components. The following links to the U.S. Department of Energy's Alternative Fuels Data Center (AFDC) provide an introduction to sustainable transportation. NREL research supports development of electric, hybrid, hydrogen fuel cell, biofuel, natural gas, and propane vehicle technologies. Learn more about vehicles, fuels, and transportation

  19. NREL: Learning - Fuel Cell Vehicle Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cell Vehicle Basics Photo showing a silver four-door sedan being driven on a roadway and containing the words "hydrogen fuel cell electric" across the front and rear doors. This prototype hydrogen fuel cell electric vehicle was displayed at a recent conference of the National Hydrogen Association. Credit: Keith Wipke Researchers are developing fuel cells that can be used in vehicles to provide electricity for propulsion as well as for a car's electric and electronic equipment.

  20. NREL: Learning - Geothermal Electricity Production Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electricity Production Basics Photo of a geothermal power plant. This geothermal power plant generates electricity for the Imperial Valley in California. Geothermal power plants use steam produced from reservoirs of hot water found a few miles or more below the Earth's surface to produce electricity. The steam rotates a turbine that activates a generator, which produces electricity. There are three types of geothermal power plants: dry steam, flash steam, and binary cycle. Dry Steam Dry steam

  1. NREL: Learning - Solar Process Heat Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Process Heat Basics Photo of part of one side of a warehouse wall, where a perforated metal exterior skin is spaced about a foot out from the main building wall to form part of the transpired solar collector system. A transpired collector is installed at a FedEx facility in Denver, Colorado. Commercial and industrial buildings may use the same solar technologies-photovoltaics, passive heating, daylighting, and water heating-that are used for residential buildings. These nonresidential

  2. Biomass Basics: The Facts About Bioenergy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Basics: The Facts About Bioenergy Biomass Basics: The Facts About Bioenergy This document provides general information about bioenergy and its creation and potential uses. PDF icon biomass_basics.pdf More Documents & Publications Biomass Basics: The Facts About Bioenergy Bioenergy Impact Posters http://www.energy.gov/media/F...Biofuels_Lower_Gas_Prices.pdf

  3. Composite oxygen ion transport element

    DOE Patents [OSTI]

    Chen, Jack C.; Besecker, Charles J.; Chen, Hancun; Robinson, Earil T.

    2007-06-12

    A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

  4. Catalyst containing oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  5. Webtrends Archives by Fiscal Year - Energy Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Basics Webtrends Archives by Fiscal Year - Energy Basics From the EERE Web Statistics Archive: Corporate sites, Webtrends archives for the Energy Basics site by fiscal year. Microsoft Office document icon Energy Basics FY10 Microsoft Office document icon Energy Basics FY11 More Documents & Publications Webtrends Archives by Fiscal Year - Office of EERE Webtrends Archives by Fiscal Year - Social Media Site Webtrends Archives by Fiscal Year - International Activities

  6. NREL: Learning - Advanced Vehicles and Fuels Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Vehicles and Fuels Basics We can improve the fuel economy of our cars, trucks, and buses by designing them to use the energy in fuels more efficiently. And we can help to reduce our nation's growing reliance on imported oil by running our vehicles on renewable and alternative fuels. Advanced vehicles and fuels can also put the brakes on air pollution and improve our environment. At least 250 million vehicles are in use in the United States today. They include all kinds of passenger

  7. NREL: Learning - Solar Photovoltaic Technology Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photovoltaic Technology Basics Photo of a large silicon solar array on a roof with a blue sky and trees in background. A large silicon solar array installed on the roof of a commercial building. Photo of a traditional-looking home with blue solar tiles integrated into the brown roof. Thin-film solar tiles installed on the roof of a home in Ohio. Photo of a long, blue solar array in a field of grass. A large solar array in Germany. Solar cells, also called photovoltaic (PV) cells by scientists,

  8. Conceptual design report, CEBAF basic experimental equipment

    SciTech Connect (OSTI)

    1990-04-13

    The Continuous Electron Beam Accelerator Facility (CEBAF) will be dedicated to basic research in Nuclear Physics using electrons and photons as projectiles. The accelerator configuration allows three nearly continuous beams to be delivered simultaneously in three experimental halls, which will be equipped with complementary sets of instruments: Hall A--two high resolution magnetic spectrometers; Hall B--a large acceptance magnetic spectrometer; Hall C--a high-momentum, moderate resolution, magnetic spectrometer and a variety of more dedicated instruments. This report contains a short description of the initial complement of experimental equipment to be installed in each of the three halls.

  9. NREL: Learning - Geothermal Heat Pump Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heat Pump Basics Photo of the West Philadelphia Enterprise Center. The West Philadelphia Enterprise Center uses a geothermal heat pump system for more than 31,000 square feet of space. Geothermal heat pumps take advantage of the nearly constant temperature of the Earth to heat and cool buildings. The shallow ground, or the upper 10 feet of the Earth, maintains a temperature between 50° and 60°F (10°-16°C). This temperature is warmer than the air above it in the winter and cooler in the

  10. The mechanisms of oxygen reduction and evolution reactions in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and evolution reactions in nonaqueous lithium-oxygen batteries A mechanistic understanding of the oxygen reductionevolution reaction in non-aqueous lithium-oxygen batteries. ...

  11. ACAA fly ash basics: quick reference card

    SciTech Connect (OSTI)

    2006-07-01

    Fly ash is a fine powdery material created when coal is burned to generate electricity. Before escaping into the environment via the utility stacks, the ash is collected and may be stored for beneficial uses or disposed of, if necessary. The use of fly ash provides environmental benefits, such as the conservation of natural resources, the reduction of greenhouse gas emissions and eliminating the needed for ash disposal in landfills. It is also a valuable mineral resource that is used in construction and manufacturing. Fly ash is used in the production of Portland cement, concrete, mortars and stuccos, manufactured aggregates along with various agricultural applications. As mineral filler, fly ash can be used for paints, shingles, carpet backing, plastics, metal castings and other purposes. This quick reference card is intended to provide the reader basic source, identification and composition, information specifically related to fly ash.

  12. Basic concepts of contaminant sorption. Summary paper

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Robert S. Kerr Environmental Research Laboratory (RSKERL) has developed a number of issue papers and briefing documents which are designed to exchange up-to-date information related to the remediation of contaminated soil and ground water at hazardous waste sites. In an attempt to make the content of these documents available to a wider audience, RSKERL is developing a series of summary papers which are condensed versions of the original documents. Understanding the processes which dictate transport and fate characteristics of contaminants in soil and ground water is of paramount importance in designing and implementing remediation systems at hazardous waste sites. Sorption is often the most significant of these processes. The summary paper addresses the basic concepts of sorption in soil and ground water with an emphasis on organic contaminants having the characteristics of those often found at existing hazardous waste sites.

  13. Summary of recommendations on basic research

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    There has been considerable progress during the past four decades in organic geochemistry research applied to understanding the origin of coal, oil, and gas, and in understanding contemporary and ancient carbon cycles on Earth. Significant contributions have been made by academic research, government laboratories, and industrial research communities either working independently or with informal cooperation. But, important questions still remain. Among the questions answered in this paper are those dealing with the mechanisms of migration of hydrocarbons and the structure of kerogen and coal. During the final plenary session of the workshop, one way of dealing with the problem of coordinating basic research effects between industry, academic institutions, and government laboratories, strongly favored by some of the participants, was discussed--creation of a National Fossil Fuel Research Institute.

  14. Criticality Safety Basics for INL Emergency Responders

    SciTech Connect (OSTI)

    Valerie L. Putman

    2012-08-01

    This document is a modular self-study guide about criticality safety principles for Idaho National Laboratory emergency responders. This guide provides basic criticality safety information for people who, in response to an emergency, might enter an area that contains much fissionable (or fissile) material. The information should help responders understand unique factors that might be important in responding to a criticality accident or in preventing a criticality accident while responding to a different emergency.

    This study guide specifically supplements web-based training for firefighters (0INL1226) and includes information for other Idaho National Laboratory first responders. However, the guide audience also includes other first responders such as radiological control personnel.

    For interested readers, this guide includes clearly marked additional information that will not be included on tests. The additional information includes historical examples (Been there. Done that.), as well as facts and more in-depth information (Did you know …).

    INL criticality safety personnel revise this guide as needed to reflect program changes, user requests, and better information. Revision 0, issued May 2007, established the basic text. Revision 1 incorporates operation, program, and training changes implemented since 2007. Revision 1 increases focus on first responders because later responders are more likely to have more assistance and guidance from facility personnel and subject matter experts. Revision 1 also completely reorganized the training to better emphasize physical concepts behind the criticality controls that help keep emergency responders safe. The changes are based on and consistent with changes made to course 0INL1226.

  15. Air-Source Heat Pump Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Basics Air-Source Heat Pump Basics August 19, 2013 - 11:03am Addthis Air-source heat pumps transfer heat between the inside of a building and the outside air. How Air-Source...

  16. Flat-Plate Photovoltaic Balance of System Basics | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Flat-Plate Photovoltaic Balance of System Basics Flat-Plate Photovoltaic Balance of System Basics August 20, 2013 - 4:29pm Addthis Complete photovoltaic (PV) energy systems are ...

  17. Tankless Demand Water Heater Basics | Department of Energy

    Energy Savers [EERE]

    Water Heating Tankless Demand Water Heater Basics Tankless Demand Water Heater Basics August 19, 2013 - 2:57pm Addthis Illustration of an electric demand water heater. At the ...

  18. Montana Understanding the Basics of Water Law In Montana Webpage...

    Open Energy Info (EERE)

    Understanding the Basics of Water Law In Montana Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Montana Understanding the Basics of Water Law...

  19. Hydrogen and Fuel Cell Technology Basics | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Renewable Energy Hydrogen and Fuel Cell Technology Basics Hydrogen and Fuel Cell Technology Basics August 14, 2013 - 2:01pm Addthis Photo of a woman scientist using a machine...

  20. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y.S.

    1991-08-20

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

  1. Device and method for separating oxygen isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D.; Sander, Robert K.

    1984-01-01

    A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

  2. Identification of an Archean marine oxygen oasis

    SciTech Connect (OSTI)

    Riding, Dr Robert E; Fralick, Dr Philip; Liang, Liyuan

    2014-01-01

    The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insoluble Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.

  3. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Radoslav Adzic Co-workers: Jia Wang, Miomir Vukmirovic, Kotaro Sasaki, Stoyan Bliznakov, Yun Cai, Yu Zhang, ...

  4. Jupiter Oxygen Corporation | Open Energy Information

    Open Energy Info (EERE)

    Place: Schiller Park, Illinois Zip: 60176 Product: Illinois-based oxy-fuel combustion company involved in the capture of CO2. References: Jupiter Oxygen Corporation1...

  5. DEVICE FOR CONTROL OF OXYGEN PARTIAL PRESSURE

    DOE Patents [OSTI]

    Bradner, H.; Gordon, H.S.

    1957-12-24

    A device is described that can sense changes in oxygen partial pressure and cause a corresponding mechanical displacement sufficient to actuate meters, valves and similar devices. A piston and cylinder arrangement contains a charge of crystalline metal chelate pellets which have the peculiar property of responding to variations in the oxygen content of the ambient atmosphere by undergoing a change in dimension. A lever system amplifies the relative displacement of the piston in the cylinder, and actuates the controlled valving device. This partial pressure oxygen sensing device is useful in controlled chemical reactions or in respiratory devices such as the oxygen demand meters for high altitude aircraft.

  6. New Oxygen-Production Technology Proving Successful

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy's National Energy Technology Laboratory has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies.

  7. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2001-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

  8. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1997-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  9. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1996-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  10. Modelling Hydrogen Reduction and Hydrodeoxygenation of Oxygenates

    SciTech Connect (OSTI)

    Zhao, Y.; Xu, Q.; Cheah, S.

    2013-01-01

    Based on Density Functional Theory (DFT) simulations, we have studied the reduction of nickel oxide and biomass derived oxygenates (catechol, guaiacol, etc.) in hydrogen. Both the kinetic barrier and thermodynamic favorability are calculated with respect to the modeled reaction pathways. In early-stage reduction of the NiO(100) surface by hydrogen, the pull-off of the surface oxygen atom and simultaneous activation of the nearby Ni atoms coordinately dissociate the hydrogen molecules so that a water molecule can be formed, leaving an oxygen vacancy on the surface. In hydrogen reaction with oxygenates catalyzed by transition metals, hydrogenation of the aromatic carbon ring normally dominates. However, selective deoxygenation is of particular interest for practical application such as biofuel conversion. Our modeling shows that doping of the transition metal catalysts can change the orientation of oxygenates adsorbed on metal surfaces. The correlation between the selectivity of reaction and the orientation of adsorption are discussed.

  11. A mutation in the mitochondrial protein UQCRB promotes angiogenesis through the generation of mitochondrial reactive oxygen species

    SciTech Connect (OSTI)

    Chang, Junghwa; Jung, Hye Jin; Jeong, Seung Hun; Kim, Hyoung Kyu; Han, Jin; Kwon, Ho Jeong

    2014-12-12

    Highlights: • We constructed mitochondrial protein UQCRB mutant stable cell lines on the basis of a human case report. • These mutant cell lines exhibit pro-angiogenic activity with enhanced VEGF expression. • Proliferation of mutant cell lines was regulated by UQCRB inhibitors. • UQCRB may have a functional role in angiogenesis. - Abstract: Ubiquinol-cytochrome c reductase binding protein (UQCRB) is one of the subunits of mitochondrial complex III and is a target protein of the natural anti-angiogenic small molecule terpestacin. Previously, the biological role of UQCRB was thought to be limited to the maintenance of complex III. However, the identification and validation of UQCRB as a target protein of terpestacin enabled the role of UQCRB in oxygen sensing and angiogenesis to be elucidated. To explore the biological role of this protein further, UQCRB mutant stable cell lines were generated on the basis of a human case report. We demonstrated that these cell lines exhibited glycolytic and pro-angiogenic activities via mitochondrial reactive oxygen species (mROS)-mediated HIF1 signal transduction. Furthermore, a morphological abnormality in mitochondria was detected in UQCRB mutant stable cell lines. In addition, the proliferative effect of the UQCRB mutants was significantly regulated by the UQCRB inhibitors terpestacin and A1938. Collectively, these results provide a molecular basis for UQCRB-related biological processes and reveal potential key roles of UQCRB in angiogenesis and mitochondria-mediated metabolic disorders.

  12. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

  13. Home and Building Technology Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Home and Building Technology Basics Home and Building Technology Basics Homes and other buildings use energy every day for space heating and cooling, for lighting and hot water, and for appliances and electronics. Today's buildings consume more energy than any other sector of the U.S. economy, including transportation and industry. Learn more about: Heating and Cooling Passive Solar Design Water Heating Lighting and Daylighting Energy Basics Home Renewable Energy Homes & Buildings Lighting

  14. A Basic Overview of the Energy Employees Occupational Illness Compensation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program | Department of Energy Policy, Guidance & Reports » Worker Health & Safety » A Basic Overview of the Energy Employees Occupational Illness Compensation Program A Basic Overview of the Energy Employees Occupational Illness Compensation Program January 2015 A Basic Overview of the Energy Employees Occupational Illness Compensation Program This pamphlet is developed by the Department of Energy (DOE) as an outreach and awareness tool to assist former and current DOE Federal,

  15. OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational

    Energy Savers [EERE]

    Safety and Health Programs and Related Matters; 29 CFR 1960 | Department of Energy OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health Programs and Related Matters; 29 CFR 1960 OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health Programs and Related Matters; 29 CFR 1960 November 26, 2004 Federal Register copy of OSHA Rulemaking on Basic Program Elements for Federal Employee Occupational Safety and Health

  16. Large Scale Computing and Storage Requirements for Basic Energy Sciences:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Target 2014 Large Scale Computing and Storage Requirements for Basic Energy Sciences: Target 2014 BESFrontcover.png Final Report Large Scale Computing and Storage Requirements for Basic Energy Sciences, Report of the Joint BES/ ASCR / NERSC Workshop conducted February 9-10, 2010 Workshop Agenda The agenda for this workshop is presented here: including presentation times and speaker information. Read More » Workshop Presentations Large Scale Computing and Storage Requirements for Basic

  17. Basic Research for the Hydrogen Fuel Initiative | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Basic Research for the Hydrogen Fuel Initiative Basic Research for the Hydrogen Fuel Initiative PDF icon Basic Research for the Hydrogen Fuel Initiative More Documents & Publications FTA - SunLine Transit Agency - Final Report 2012 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program 2014 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office

  18. Technical Assistance Project (TAP) Revolving Loan Funds: Basics...

    Broader source: Energy.gov (indexed) [DOE]

    pwebinar20090826sifuentes.pdf More Documents & Publications Revolving Loan Funds: Basics and Best Practices LoanSTAR Revolving Loan Program Revolving Loan Funds: An Introduction...

  19. EPA Brownfields and Land Revitalization Website: Basic Information...

    Open Energy Info (EERE)

    Abstract This site provides basic information regarding EPA's Brownfields program. Author Environmental Protection Agency Published EPA, Date Not Provided DOI Not Provided Check...

  20. Electricity Grid Basics Webinar Presentation Slides and Text Version

    Broader source: Energy.gov [DOE]

    Download presentation slides and a text version of the audio from the DOE Office of Indian Energy webinar on electricity grid basics.

  1. Revolving Loan Funds: Basics and Best Practices Webinar

    Broader source: Energy.gov [DOE]

    Provides a webinar presentation, and supporting background materials, on basic information and characteristics for revolving loan funds , including best practices. Author: National Renewable Energy Laboratory

  2. Detter, John C. [Los Alamos National Laboratory] Basic Biological

    Office of Scientific and Technical Information (OSTI)

    State of the Art for Autonomous Detection Systems using Genomic Sequencing Detter, John C. Los Alamos National Laboratory Basic Biological Sciences(59) Biological Science...

  3. ORISE: Collaboration with the CDC yields Radiation Basics Made...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Online training designed to help public health and emergency medical professionals learn fundamentals of radiation How ORISE is Making a Difference Radiation Basics Made Simple, ...

  4. Electricity Grid Basics Webinar Presentation Slides and Text...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Grid Basics Webinar Presentation Slides and Text Version Download presentation slides and a text version of the audio from the DOE Office of Indian Energy webinar on ...

  5. Heating and Cooling System Support Equipment Basics | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Cooling System Support Equipment Basics Heating and Cooling System Support Equipment ... Thermostats and ducts provide opportunities for saving energy. Dehumidifying heat pipes ...

  6. Selective photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz; Blatter, Fritz; Sun, Hai

    1998-01-01

    A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

  7. HyPro: A Financial Tool for Simulating Hydrogen Infrastructure Development, Final Report

    SciTech Connect (OSTI)

    Brian D. James, Peter O. Schmidt, Julie Perez

    2008-12-01

    This report summarizes a multi-year Directed Technologies Inc. (DTI) project to study the build-out of hydrogen production facilities during the transition from gasoline internal combustion engine vehicle to hydrogen fuel cell vehicles. The primary objectives of the project are to develop an enhanced understanding of hydrogen production issues during the transition period (out to 2050) and to develop recommendations for the DOE on areas of further study. These objectives are achieved by conducting economic and scenario analysis to predict how industry would provide the hydrogen production, delivery and dispensing capabilities necessary to satisfy increased hydrogen demand. The primary tool used for the analysis is a custom created MatLab simulation tool entitled HyPro (short for Hydrogen Production). This report describes the calculation methodology used in HyPro, the baseline assumptions, the results of the baseline analysis and several corollary studies. The appendices of this report included a complete listing of model assumptions (capital costs, efficiencies, feedstock prices, delivery distances, etc.) and a step-by-step manual on the specific operation of the HyPro program. This study was made possible with funding from the U.S. Department of Energy (DOE).

  8. Oxygen-Enriched Combustion; Industrial Technologies Program ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in the combustion air or vacuum pressure swing adsorption units to remove some of the ... the cost of oxygen or of the vacuum pressure swing adsorption unit in the calculations. ...

  9. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-08-01

    This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  10. Removal of basic nitrogen compounds from hydrocarbon liquids

    DOE Patents [OSTI]

    Givens, Edwin N.; Hoover, David S.

    1985-01-01

    A method is provided for reducing the concentration of basic nitrogen compounds in hydrocarbonaceous feedstock fluids used in the refining industry by providing a solid particulate carbonaceous adsorbent/fuel material such as coal having active basic nitrogen complexing sites on the surface thereof and the coal with a hydrocarbonaceous feedstock containing basic nitrogen compounds to facilitate attraction of the basic nitrogen compounds to the complexing sites and the formation of complexes thereof on the surface of the coal. The adsorbent coal material and the complexes formed thereon are from the feedstock fluid to provide a hydrocarbonaceous fluid of reduced basic nitrogen compound concentration. The coal can then be used as fuel for boilers and the like.

  11. Engineering MulticomponentNanocatalystsfor Oxygen Reduction (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Engineering MulticomponentNanocatalystsfor Oxygen Reduction Citation Details In-Document Search Title: Engineering MulticomponentNanocatalystsfor Oxygen Reduction Authors: Guo, Shaojun [1] + Show Author Affiliations Los Alamos National Laboratory [Los Alamos National Laboratory Publication Date: 2014-03-27 OSTI Identifier: 1126640 Report Number(s): LA-UR-13-28233 DOE Contract Number: AC52-06NA25396 Resource Type: Conference Resource Relation: Conference: 247th ACS National

  12. Engineering MulticomponentNanocatalystsfor Oxygen Reduction (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Engineering MulticomponentNanocatalystsfor Oxygen Reduction Citation Details In-Document Search Title: Engineering MulticomponentNanocatalystsfor Oxygen Reduction × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology. A paper copy of

  13. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1998-01-01

    Preparation, structure, and properties of mixed metal oxide compositions and their uses are described. Mixed metal oxide compositions of the invention have stratified crystalline structure identifiable by means of powder X-ray diffraction patterns. In the form of dense ceramic membranes, the present compositions demonstrate an ability to separate oxygen selectively from a gaseous mixture containing oxygen and one or more other volatile components by means of ionic conductivities.

  14. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Download presentation slides from the June 19, 2012, Fuel Cell Technologies Program webinar, "BNL's Low-Platinum Electrocatalysts for Fuel Cell Electric Vehicles (FCEVs)." PDF icon BNL's Low-Platinum Electrocatalysts for Fuel Cell Electric Vehicles (FCEVs) Webinar Slides More Documents & Publications Contiguous Platinum

  15. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-01-01

    This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

  16. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

  17. Magnetism in LithiumOxygen Discharge Product

    SciTech Connect (OSTI)

    Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

    2013-05-13

    Nonaqueous lithiumoxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithiumoxygen batteries. We demonstrate that the major discharge product formed in the lithiumoxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

  18. Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency & ...

  19. Webinar: Testing Oxygen Reduction Reaction Activity with the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Above is the video recording for the webinar, "Testing Oxygen Reduction Reaction ...

  20. Testing Oxygen Reduction Reaction Activity with the Rotating...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique ...

  1. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for ...

  2. Selective reduction of NOx in oxygen rich environments with plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments with ...

  3. Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...

    Open Energy Info (EERE)

    Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Oxygen...

  4. Oxygen-Enriched Combustion for Military Diesel Engine Generators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and considerably lower peak pressure can result from oxygen-enriched diesel ...

  5. Artificial oxygen transport protein (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Artificial oxygen transport protein Citation Details In-Document Search Title: Artificial oxygen transport protein This invention provides heme-containing peptides capable...

  6. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-07-01

    Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

  7. Direct Observation of the Oxygenated Species during Oxygen Reduction on a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Platinum Fuel Cell Cathode | Stanford Synchrotron Radiation Lightsource Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode. The study shows that two types of hydroxyl intermediates (non-hydrated OH and hydrated OH) with distinct activities coexist on a fuel-cell

  8. Oxygen generator for medical applications (USIC)

    SciTech Connect (OSTI)

    Staiger, C. L.

    2012-03-01

    The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible using a Membrane-PSA system.

  9. DOE Selects Seven Contractors for Waste Treatment Basic Ordering Agreements

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Seven Contractors for Waste Treatment Basic Ordering Agreements DOE Selects Seven Contractors for Waste Treatment Basic Ordering Agreements June 4, 2015 - 12:00pm Addthis Media Contact: Lynn Chafin, (513) 246-0461, lynette.chafin@emcbc.doe.gov Cincinnati - The U.S. Department of Energy (DOE) issued seven Basic Ordering Agreements (BOAs) for the treatment of Low-Level Waste (LLW) and Mixed Low-Level Waste (MLLW). The LLW MLLW treatment services also include the

  10. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-02-01

    This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

  11. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  12. Oxygenates du`jour...MTBE? Ethanol? ETBE?

    SciTech Connect (OSTI)

    Wolfe, R.

    1995-12-31

    There are many different liquids that contain oxygen which could be blended into gasoline. The ones that have been tried and make the most sense are in the alcohol (R-OH) and ether (R-O-R) chemical family. The alcohols considered are: methanol (MeOH), ethanol (EtOH), tertiary butyl alcohol (TBA). The ethers are: methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), tertiary amyl ethyl ether (TAEE), di-isopropyl ether (DIPE). Of the eight oxygenates listed above, the author describes the five that are still waiting for widespread marketing acceptance (methanol, TBA, TAME, TAEE, and DIPE). He then discusses the two most widely used oxygenates in the US, MTBE and ethanol, along with the up-and-coming ethanol ether, ETBE. Selected physical properties for all of these oxygenates can be found in Table 2 at the end of this paper. A figure shows a simplified alcohol/ether production flow chart for the oxygenates listed above and how they are interrelated.

  13. Tutorial: The Basics of SAXS Data Analysis | Stanford Synchrotron Radiation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lightsource Tutorial: The Basics of SAXS Data Analysis Thursday, November 17, 2011 - 1:00pm SLAC, Redtail Hawk Conference Room 108A Dr. Alexander V. Shkumatov, Biological Small Angle Scattering Group, EMBL Hamburg

  14. Exploring Power Purchase Agreements- The Basics Part 1

    Broader source: Energy.gov [DOE]

    This webinar, held on July 27, 2011, provides information on the basics of Power Purchase Agreements, including risks and unique issues and benefits. Case studies include Salt Lake County, Utah, and Talbot County, Maryland.

  15. Photovoltaic Cell Quantum Efficiency Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Photovoltaic Cell Quantum Efficiency Basics August 20, 2013 - 3:05pm Addthis Quantum efficiency (QE) is the ratio of the number of charge carriers collected by a photovoltaic (PV) ...

  16. Inflation Basics (Technical Report) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Inflation Basics Authors: Green, Dan 1 + Show ... Sponsoring Org: USDOE Office of Science (SC), High Energy Physics (HEP) (SC-25) Country of ...

  17. Vehicle Technologies Office Merit Review 2015: Basic Energy Sciences Overview

    Broader source: Energy.gov [DOE]

    Presentation given by U.S. Department of Energy  at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation meeting about Basic Energy...

  18. Energy 101 Videos: Learn More About the Basics! | Department...

    Broader source: Energy.gov (indexed) [DOE]

    out the Energy Basics Web site last week. Because I'm going to talk about something on the site, I wanted to remind you all of what it is: a brand new Web site on EERE that talks ...

  19. Tutorial: The Basics of SAXS Data Analysis | Stanford Synchrotron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tutorial: The Basics of SAXS Data Analysis Thursday, November 17, 2011 - 1:00pm SLAC, Redtail Hawk Conference Room 108A Dr. Alexander V. Shkumatov, Biological Small Angle...

  20. Tribal Renewable Energy Foundational Course: Electricity Grid Basics

    Broader source: Energy.gov [DOE]

    Watch the U.S. Department of Energy Office of Indian Energy foundational course webinar on electricity grid basics by clicking on the .swf link below. You can also download the PowerPoint slides...

  1. Advanced Technology and Alternative Fuel Vehicle Basics | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Advanced Technology and Alternative Fuel Vehicle Basics Advanced Technology and Alternative Fuel Vehicle Basics August 20, 2013 - 9:00am Addthis Photo of a large blue truck with 'PG&amp;E Cleanair' written on the side. There are a variety of alternative fuel and advanced technology vehicles that run on fuels other than traditional petroleum. Learn about the following types of vehicles: Flexible Fuel Vehicles Fuel Cell Vehicles Hybrid and Plug-In Electric Vehicles Natural Gas

  2. Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda PDF icon BES Report Controlling Subsurface Fractures and Fluid Flow.pdf More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface SubTER Crosscut White Paper

  3. Combined Heat and Power Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Assistance » Combined Heat & Power Deployment » Combined Heat and Power Basics Combined Heat and Power Basics Combined heat and power (CHP), also known as cogeneration, is: A process flow diagram showing efficiency benefits of CHP The concurrent production of electricity or mechanical power and useful thermal energy (heating and/or cooling) from a single source of energy. A type of distributed generation, which, unlike central station generation, is located at or near the point

  4. Hydrogen and Fuel Cell Technology Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen and Fuel Cell Technology Basics Hydrogen and Fuel Cell Technology Basics August 14, 2013 - 2:01pm Addthis Photo of a scientist testing a photoelectrochemical water splitting system. Hydrogen is the simplest and most abundant element in the universe. It is a major component of water, oil, natural gas, and all living matter. Despite its simplicity and abundance, hydrogen rarely occurs naturally as a gas on Earth. It is almost always combined with other elements. It can be generated from

  5. Space Heating and Cooling Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Space Heating and Cooling Basics Space Heating and Cooling Basics August 16, 2013 - 1:04pm Addthis A wide variety of technologies are available for heating and cooling homes and other buildings. In addition, many heating and cooling systems have certain supporting equipment in common, such as thermostats and ducts, which provide opportunities for saving energy. Learn how these technologies and systems work. Learn about: Cooling Systems Heating Systems Heat Pump Systems Supporting Equipment for

  6. Vehicle Technology and Alternative Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technology and Alternative Fuel Basics Vehicle Technology and Alternative Fuel Basics Photo of an electric car plugged in and charging. Learn about exciting technologies and ongoing research in advanced technology vehicles and alternative fuel vehicles that run on fuels other than traditional petroleum.. ADVANCED TECHNOLOGY AND ALTERNATIVE FUEL VEHICLES There are a variety of alternative fuel vehicles and advanced technology vehicles available. Learn about: Flexible Fuel Vehicles Fuel

  7. Wood and Pellet Heating Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wood and Pellet Heating Basics Wood and Pellet Heating Basics August 16, 2013 - 3:02pm Addthis Wood-burning and pellet fuel appliances use biomass or waste resources to heat homes or buildings. Types of Wood- and Pellet-Burning Appliances The following is a brief overview of the different types of wood and pellet fuel appliances available. High-Efficiency Fireplaces and Fireplace Inserts Designed more for show, traditional open masonry fireplaces should not be considered heating devices.

  8. Microhydropower Turbine, Pump, and Waterwheel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Turbine, Pump, and Waterwheel Basics Microhydropower Turbine, Pump, and Waterwheel Basics August 16, 2013 - 3:58pm Addthis A microhydropower system needs a turbine, pump, or waterwheel to transform the energy of flowing water into rotational energy, which is then converted into electricity. Turbines Turbines are commonly used to power microhydropower systems. The moving water strikes the turbine blades, much like a waterwheel, to spin a shaft. But turbines are more compact in relation to their

  9. Crystalline Silicon Photovolatic Cell Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Crystalline Silicon Photovolatic Cell Basics Crystalline Silicon Photovolatic Cell Basics August 19, 2013 - 4:58pm Addthis Crystalline silicon cells are made of silicon atoms connected to one another to form a crystal lattice. This lattice comprises the solid material that forms the photovoltaic (PV) cell's semiconductors. This section describes the atomic structure and bandgap energy of these cells. Atomic Structure Illustration of a silicon crystal with its 14 electrons orbiting a nucleus of

  10. EV Everywhere: Electric Vehicle Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EV Everywhere: Electric Vehicle Basics EV Everywhere: Electric Vehicle Basics Just as there are a variety of technologies available in conventional vehicles, plug-in electric vehicles (also known as electric cars or EVs) have different capabilities that can accommodate different drivers' needs. EVs' major feature is that drivers can plug them in to charge from an off-board electric power source. This distinguishes them from hybrid electric vehicles, which supplement an internal combustion engine

  11. Geothermal Direct-Use Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Direct-Use Basics Geothermal Direct-Use Basics August 14, 2013 - 1:46pm Addthis Hot water near the surface of the Earth can be used for heat for a variety of commercial and industrial uses. Direct-use applications include heating buildings, growing plants in greenhouses, drying crops, heating water at fish farms, and several industrial processes such as pasteurizing milk. Learn more about direct-use of geothermal applications from the EERE Geothermal Technologies Office. Addthis Related Articles

  12. ORISE: Collaboration with the CDC yields Radiation Basics Made Simple

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    online training module Collaboration with CDC Yields Radiation Basics Made Simple Training Module Online training designed to help public health and emergency medical professionals learn fundamentals of radiation How ORISE is Making a Difference Radiation Basics Made Simple, the first in a series of online training modules developed by the Radiation Studies Branch (RSB) of the Centers for Disease Control and Prevention (CDC), delivers foundational knowledge about radiation to its audiences.

  13. Flow cytometry aids basic cell biology research and drug discovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flow cytometry aids basic cell biology research and drug discovery Flow cytometry aids basic cell biology research and drug discovery Life Technologies Corporation and LANL have released the Attune® Acoustic Focusing Cytometer, featuring a reduced footprint, reduced consumables, and an affordable price. April 3, 2012 Attune® Acoustic Focusing Cytometer The Attune® Acoustic Focusing Cytometer achieves sample throughput at rates over 10 times faster than other cytometers-up to 1,000 μL per

  14. Linear Concentrator System Basics for Concentrating Solar Power |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Linear Concentrator System Basics for Concentrating Solar Power Linear Concentrator System Basics for Concentrating Solar Power August 20, 2013 - 4:45pm Addthis Photo of numerous parallel rows of parabolic trough collectors tracking the sun. Cooling towers and other generator equipment are in the midst of the troughs, and two water tanks are in the background. The Solar Electric Generating Station IV power plant in California consists of many parallel rows of parabolic

  15. Institutional Change Basics for Sustainability | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Basics for Sustainability Institutional Change Basics for Sustainability Institutional change integrates technology, policy, and behavior to make new sustainability practices and perspectives become a typical part of how an agency operates. For example: Technology provides means to decrease energy and resource use. Policy provides directives to decrease energy and resource use. Institutional and individual behaviors provide avenues to ensure technologies and policies are used effectively in

  16. Guidance on Basic Best Practices in Management of Energy Performance

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Buildings | Department of Energy on Basic Best Practices in Management of Energy Performance Buildings Guidance on Basic Best Practices in Management of Energy Performance Buildings Building energy management best practices PDF icon 11_001_eecbg_sep_building_best_practice.pdf More Documents & Publications Energy Efficiency and Conservation Block Grant Financing Program Guidance Grantee Letter SEP Guidance National Energy Policy Act Guide for State Energy Program and Energy Efficiency and

  17. Large Scale Production Computing and Storage Requirements for Basic Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences: Target 2017 Large Scale Production Computing and Storage Requirements for Basic Energy Sciences: Target 2017 BES-Montage.png This is an invitation-only review organized by the Department of Energy's Office of Basic Energy Sciences (BES), Office of Advanced Scientific Computing Research (ASCR), and the National Energy Research Scientific Computing Center (NERSC). The goal is to determine production high-performance computing, storage, and services that will be needed for BES to

  18. Absorption process for producing oxygen and nitrogen and solution therefor

    DOE Patents [OSTI]

    Roman, I.C.; Baker, R.W.

    1990-09-25

    Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible. 1 figure

  19. Absorption process for producing oxygen and nitrogen and solution therefor

    DOE Patents [OSTI]

    Roman, Ian C. [Wilmington, DE; Baker, Richard W. [Palo Alto, CA

    1990-09-25

    Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible.

  20. Absorption process for producing oxygen and nitrogen and solution therefor

    DOE Patents [OSTI]

    Roman, Ian C.

    1984-01-01

    Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible.

  1. Influence of Pro-Qura-generated Plans on Postimplant Dosimetric Quality: A Review of a Multi-Institutional Database

    SciTech Connect (OSTI)

    Allen, Zachariah |||; Merrick, Gregory S. ||| Grimm, Peter; Blasko, John; Sylvester, John; Butler, Wayne; Chaudry, Usman-Ul-Haq; Sitter, Michael |||

    2008-10-01

    The influence of Pro-Qura-generated plans vs. community-generated plans on postprostate brachytherapy dosimetric quality was compared. In the Pro-Qura database, 2933 postplans were evaluated from 57 institutions. A total of 1803 plans were generated by Pro-Qura and 1130 by community institutions. Iodine-125 ({sup 125}I) plans outnumbered Palladium 103 ({sup 103}Pd) plans by a ratio of 3:1. Postimplant dosimetry was performed in a standardized fashion by overlapping the preimplant ultrasound and the postimplant computed tomography (CT). In this analysis, adequacy was defined as a V{sub 100} > 80% and a D{sub 90} of 90% to 140% for both isotopes along with a V{sub 150} < 60% for {sup 125}I and < 75% for {sup 103}Pd. The mean postimplant V{sub 100} and D{sub 90} were 88.6% and 101.6% vs. 89.3% and 102.3% for Pro-Qura and community plans, respectively. When analyzed in terms of the first 8 sequence groups (10 patients/sequence group) for each institution, Pro-Qura planning resulted in less postimplant variability for V{sub 100} (86.2-89.5%) and for D{sub 90} (97.4-103.2%) while community-generated plans had greater V{sub 100} (85.3-91.2%) and D{sub 90} (95.9-105.2%) ranges. In terms of sequence groups, postimplant dosimetry was deemed 'too cool' in 11% to 30% of cases and 'too hot' in 12% to 27%. On average, no clinically significant postimplant dosimetric differences were discerned between Pro-Qura and community-based planning. However, substantially greater variability was identified in the community-based plan cohort. It is possible that the Pro-Qura plan and/or the routine postimplant dosimetric evaluation may have influenced dosimetric outcomes at community-based centers.

  2. Ammonia producing engine utilizing oxygen separation

    DOE Patents [OSTI]

    Easley, Jr., William Lanier; Coleman, Gerald Nelson; Robel, Wade James

    2008-12-16

    A power system is provided having a power source, a first power source section with a first intake passage and a first exhaust passage, a second power source section with a second intake passage and a second exhaust passage, and an oxygen separator. The second intake passage may be fluidly isolated from the first intake passage.

  3. Novel Membranes and Processes for Oxygen Enrichment

    SciTech Connect (OSTI)

    Lin, Haiqing

    2011-11-15

    The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

  4. Basic research needs for management and disposal of DOE wastes

    SciTech Connect (OSTI)

    Grazis, B.M.; Horwitz, E.P. ); Schulz, W.W. )

    1991-04-01

    This document was chartered by the Department of Energy (DOE), Office of Energy Research. It identifies and describes 87 basic research needs in support of advanced technology for management and disposal of Department of Energy radioactive, hazardous chemical, and mixed wastes. A team of scientists and engineers from several DOE laboratories and sites, from academia, and from industry identified and described the basic research needs called out in this report. Special efforts were made to ensure that basic research needs related to management and disposal of any hazardous chemical wastes generated at nonnuclear DOE sites and facilities were properly identified. It is hoped that scientists in both DOE and nongovernment laboratories and institutions will find this document useful when formulating research efforts relevant to waste management and disposal. For management and disposal of DOE radioactive and mixed wastes, basic research needs are identified in nine separate action areas. Basic research needs for management and disposal of DOE hazardous chemical wastes are identified in five action areas. Sufficient description and background information are provided in the report for each particular research need to enable qualified and imaginative scientists to conceive research efforts and programs that will meet the need. 28 refs., 7 tabs.

  5. Mechanism of singlet oxygen deactivation in an electric discharge oxygen iodine laser

    SciTech Connect (OSTI)

    Azyazov, V N; Mikheyev, P A; Torbin, A P; Pershin, A A; Heaven, M C

    2014-12-31

    We have determined the influence of the reaction of molecular singlet oxygen with a vibrationally excited ozone molecule O{sub 2}(a {sup 1}?) + O{sub 3}(?) ? 2O{sub 2} + O on the removal rate of O{sub 2}(a {sup 1}?) in an electric-discharge-driven oxygen iodine laser. This reaction has been shown to be a major channel of O{sub 2}(a {sup 1}?) loss at the output of an electric-discharge singlet oxygen generator. In addition, it can also contribute significantly to the loss of O{sub 2}(a {sup 1}?) in the discharge region of the generator. (lasers)

  6. Assessment of the basic energy sciences program. Volume II. Appendices

    SciTech Connect (OSTI)

    Not Available

    1982-03-01

    A list of experts reviewing the Basic Energy Sciences (BES) program and their organizations are given. The assessment plan is explained; the program examined the following: quality of science being conducted in the program, quality of performers supported by the Basic Energy Sciences (BES) program, and the impact of the research on mission oriented needs. The intent of the assessment is to provide an indication of general status relative to these questions for the BES divisions. The approach to the assessment is described. The sampling plan which was used as a guide in determining the sample size and selecting the sample to evaluate the research program of the Office of Basic Energy Sciences are discussed. Special analyses were conducted on the dispersion of reviewers' ratings, the ratings of the lower funded projects, and the amount of time the principal investigator devoted to the project. These are presented in the final appendix together with histograms for individual rating variables for each program area. (MCW)

  7. Concentrating Solar Power Tower System Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tower System Basics Concentrating Solar Power Tower System Basics August 20, 2013 - 5:06pm Addthis In power tower concentrating solar power systems, numerous large, flat, sun-tracking mirrors, known as heliostats, focus sunlight onto a receiver at the top of a tall tower. A heat-transfer fluid heated in the receiver is used to generate steam, which, in turn, is used in a conventional turbine generator to produce electricity. Some power towers use water/steam as the heat-transfer fluid. Other

  8. Passive Solar Building Design Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Homes & Buildings » Passive Solar Building Design Basics Passive Solar Building Design Basics July 30, 2013 - 3:20pm Addthis The difference between a passive solar home and a conventional home is design. Passive solar homes and other buildings are designed to take advantage of the local climate. Passive solar design-also known as climatic design-involves using a building's windows, walls, and floors to collect, store, and distribute solar energy in the form of heat in the winter and reject

  9. Flat-Plate Photovoltaic Module Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Module Basics Flat-Plate Photovoltaic Module Basics August 20, 2013 - 4:25pm Addthis Flat-plate photovoltaic (PV) modules are made of several components, including the front surface materials, encapsulant, rear surface, and frame. Front Surface Materials The front surface of a flat-plate PV module must have a high transmission in the wavelengths that can be used by the solar cells in the module. For example, for silicon solar cells, the top surface must have high transmission of light with

  10. Flat-Plate Photovoltaic System Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Basics Flat-Plate Photovoltaic System Basics August 20, 2013 - 4:03pm Addthis The most common photovoltaic (PV) array design uses flat-plate PV modules or panels. These panels can be fixed in place or allowed to track the movement of the Illustration of a cutaway of a typical flat-plate module. The layers, in order from top to bottom, are: cover film, solar cell, encapsulant, substrate, cover film, seal, gasket, and frame. One typical flat-plate module design uses a substrate of metal,

  11. Manhattan Project: Basic Research at Los Alamos, 1943-1944

    Office of Scientific and Technical Information (OSTI)

    Norris Bradbury, Robert Oppenheimer, Richard Feynman, Enrico Fermi, and others, Los Alamos, 1946 BASIC RESEARCH AT LOS ALAMOS (Los Alamos: Laboratory, 1943-1944) Events > Bringing It All Together, 1942-1945 Establishing Los Alamos, 1942-1943 Early Bomb Design, 1943-1944 Basic Research at Los Alamos, 1943-1944 Implosion Becomes a Necessity, 1944 Oak Ridge and Hanford Come Through, 1944-1945 Final Bomb Design, 1944-1945 Atomic Rivals and the ALSOS Mission, 1938-1945 Espionage and the Manhattan

  12. Bio-Based Product Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Biomass » Bio-Based Product Basics Bio-Based Product Basics August 14, 2013 - 1:19pm Addthis Almost all of the products we currently make from fossil fuels can also be made from biomass. These bioproducts, or bio-based products, are not only made from renewable sources, but they also often require less energy to produce than petroleum-based ones. Researchers have discovered that the process for making biofuels also can be used to make antifreeze, plastics, glues, artificial

  13. Conventional Storage Water Heater Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Heating » Conventional Storage Water Heater Basics Conventional Storage Water Heater Basics July 30, 2013 - 3:39pm Addthis Illustration showing the components of a storage water heater. On top of the tank are two thin pipes; one pipe is the hot water outlet, and the other is the cold water inlet. A large pipe in the middle is called a vent pipe. A pressure/temperature relief valve is also on top of the tank and is connected to an open pipe that runs down the side of the tank. Another

  14. Heat Pump Water Heater Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Heating » Heat Pump Water Heater Basics Heat Pump Water Heater Basics August 19, 2013 - 2:59pm Addthis Illustration of a heat pump water heater, which looks like a tall cylinder with a small chamber on top and a larger one on the bottom. In the top chamber are a fan, a cylindrical compressor, and an evaporator that runs along the inside of the chamber. Jutting out from the exterior of the bottom chamber is a temperature and pressure relief valve. This valve has a tube called a hot water

  15. Large-Scale Hydropower Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy » Hydropower » Large-Scale Hydropower Basics Large-Scale Hydropower Basics August 14, 2013 - 3:11pm Addthis Large-scale hydropower plants are generally developed to produce electricity for government or electric utility projects. These plants are more than 30 megawatts (MW) in size, and there is more than 80,000 MW of installed generation capacity in the United States today. Most large-scale hydropower projects use a dam and a reservoir to retain water from a river. When the

  16. Ocean Thermal Energy Conversion Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ocean » Ocean Thermal Energy Conversion Basics Ocean Thermal Energy Conversion Basics August 16, 2013 - 4:22pm Addthis A process called ocean thermal energy conversion (OTEC) uses the heat energy stored in the Earth's oceans to generate electricity. OTEC works best when the temperature difference between the warmer, top layer of the ocean and the colder, deep ocean water is about 36°F (20°C). These conditions exist in tropical coastal areas, roughly between the Tropic of Capricorn and the

  17. High-Intensity Discharge Lighting Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Intensity Discharge Lighting Basics High-Intensity Discharge Lighting Basics August 15, 2013 - 5:59pm Addthis Illustration of a high-intensity discharge (HID) lIllustration amp. The lamp is a tall cylindrical shape, and a cutout of the outer tube shows the materials inside. A long, thin cylinder called the arc tube runs through the lamp between two electrodes. The space around the arc tube is labeled as a vacuum. High-intensity discharge (HID) lighting can provide high efficacy and long

  18. Building the Basic PVC Wind Turbine | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building the Basic PVC Wind Turbine Building the Basic PVC Wind Turbine Below is information about the student activity/lesson plan from your search. Grades 5-8, 9-12 Subject Wind Energy Summary This plan shows how to make a rugged and inexpensive classroom wind turbine that can be used for lab bench-based blade design experiments. While a few specialized parts are needed (a hub and DC motor), the rest of the components are easily found at most hardware stores. Curriculum Technology, Science

  19. Oxygen-producing inert anodes for SOM process

    SciTech Connect (OSTI)

    Pal, Uday B

    2014-02-25

    An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

  20. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

  1. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, Roland R.; Bond, James A.

    1994-01-01

    A high-voltage electrical insulator (21) for electrically insulating a thermoelectric module (17) in a spacecraft from a niobium-1% zirconium alloy wall (11) of a heat exchanger (13) filled with liquid lithium (16) while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator (21) has a single crystal alumina layer (SxAl.sub.2 O.sub.3, sapphire) with a niobium foil layer (32) bonded thereto on the surface of the alumina crystal (26) facing the heat exchanger wall (11), and a molybdenum layer (31) bonded to the niobium layer (32) to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface.

  2. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-10-01

    This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

  3. Basic principles of the surface harmonics method: Flat geometry

    SciTech Connect (OSTI)

    Kovalishin, A. A.

    2011-12-15

    The basic principles of the surface harmonics method are described. A one-dimensional problem is used to exemplify the specific features of the method and the algorithms for construction of finite-difference equations. The objective of this study is to popularize the surface harmonics method among specialists.

  4. Role of basic ecological knowledge in environmental assessment

    SciTech Connect (OSTI)

    Hildebrand, S.G.; Barnthouse, L.W.; Suter, G.W.

    1984-01-01

    The role of basic ecological knowledge in environmental impact assessment was examined. The focus was primarily on the NEPA process. Experience in population biology and ecosystem studies is discussed, the successes and limits of applicability are highlighted, and implications for long-term research needs are identified. Current attempts to develop a national assessment of acid deposition impacts are reviewed. 48 refs. (ACR)

  5. Oxygen stabilized zirconium vanadium intermetallic compound

    DOE Patents [OSTI]

    Mendelsohn, Marshall H.; Gruen, Dieter M.

    1982-01-01

    An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.

  6. Towards a 100mA Superconducting RF Photoinjector for BERLinPro

    SciTech Connect (OSTI)

    Neumann, Axel; Anders, W.; Burrill, Andrew; Jankowiak, Andreas; Kamps, T.; Knobloch, Jens; Kugeler, Oliver; Lauinger, P.; Matveenko, A.N.; Schmeisser, M.; Volker, J.; Ciovati, Gianluigi; Kneisel, Peter; Nietubyc, R.; Schubert, S.G.; Smedley, John; Sekutowicz, Jacek; Volkov, V.; Will, I.; Zaplatin, Evgeny

    2013-09-01

    For BERLinPro, a 100 mA CW-driven SRF energy recovery linac demonstrator facility, HZB needs to develop a photo-injector superconducting cavity which delivers a at least 1mm*mr emittance beam at high average current. To address these challenges of producing a high peak brightness beam at high repetition rate, at first HZB tested a fully superconducting injector with a lead cathode*,followed now by the design of a SC cavity allowing operation up to 4 mA using CW-modified TTF-III couplers and inserting a normal conducting high quantum efficiency cathode using the HZDR-style insert scheme. This talk will present the latest results and an overview of the measurements with the lead cathode cavity and will describe the design and optimization process, the first production results of the current design and an outlook to the further development steps towards the full power version.

  7. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-08-01

    This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

  8. DME-to-oxygenates process studies

    SciTech Connect (OSTI)

    Tartamella, T.L.; Sardesai, A.; Lee, S.; Kulik, C.J.

    1994-12-31

    The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

  9. Future steelmaking technologies and the role of basic research

    SciTech Connect (OSTI)

    Fruehan, R.J.

    1996-12-31

    The steel industry is going through a technological revolution which will not only change how steel is produced but, also, the entire structure of the industry. The drivers for the new or improved technologies, including reduction in capital requirements, possible shortages in raw materials such as coke and low residual scrap, environmental concerns and customer demands are briefly examined. The current status of research and development in the US and selected international producers was examined. As expected, it was found that the industry`s research capabilities have been greatly reduced. Furthermore, less than half of the companies which identified a given technology as critical have significant R and D programs addressing the technology. Examples of how basic research aided in process improvements in the past are given. The examples include demonstrating how fundamentals of reaction kinetics, improved nitrogen control, thermodynamics of systems helped reduce nozzle clogging and fluid flow studies reduced defects in casting. However, in general, basic research did not play a major role in processes previously developed, but helped understanding and aided optimization. To have a major impact, basic research must be focused and be an integral part of any new process development. An example where this has been done successfully is the AISI Direct Ironmaking and Waste Oxide Recycle Projects in which fundamental studies on reduction, slag foaming, and post combustion reactions have led to process understanding, control and optimization. Industry leaders recognize the value and need for basic research but insist it be truly relevant and done with industry input. From these examples the lessons learned on how to make basic research more effective are discussed.

  10. Vacuum pyrolysis of waste tires with basic additives

    SciTech Connect (OSTI)

    Zhang Xinghua; Wang Tiejun Ma Longlong; Chang Jie

    2008-11-15

    Granules of waste tires were pyrolyzed under vacuum (3.5-10 kPa) conditions, and the effects of temperature and basic additives (Na{sub 2}CO{sub 3}, NaOH) on the properties of pyrolysis were thoroughly investigated. It was obvious that with or without basic additives, pyrolysis oil yield increased gradually to a maximum and subsequently decreased with a temperature increase from 450 deg. C to 600 deg. C, irrespective of the addition of basic additives to the reactor. The addition of NaOH facilitated pyrolysis dramatically, as a maximal pyrolysis oil yield of about 48 wt% was achieved at 550 deg. C without the addition of basic additives, while a maximal pyrolysis oil yield of about 50 wt% was achieved at 480 deg. C by adding 3 wt% (w/w, powder/waste tire granules) of NaOH powder. The composition analysis of pyrolytic naphtha (i.b.p. (initial boiling point) {approx}205 deg. C) distilled from pyrolysis oil showed that more dl-limonene was obtained with basic additives and the maximal content of dl-limonene in pyrolysis oil was 12.39 wt%, which is a valuable and widely-used fine chemical. However, no improvement in pyrolysis was observed with Na{sub 2}CO{sub 3} addition. Pyrolysis gas was mainly composed of H{sub 2}, CO, CH{sub 4}, CO{sub 2}, C{sub 2}H{sub 4} and C{sub 2}H{sub 6}. Pyrolytic char had a surface area comparable to commercial carbon black, but its proportion of ash (above 11.5 wt%) was much higher.

  11. Impact of interstitial oxygen on the electronic and magnetic...

    Office of Scientific and Technical Information (OSTI)

    interstitial oxygen on the electronic and magnetic structure in superconducting Fe 1 + y Te O x thin films Citation Details In-Document Search Title: Impact of interstitial oxygen...

  12. Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical...

    Office of Scientific and Technical Information (OSTI)

    Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping Citation Details In-Document Search Title: Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping ...

  13. Oxygen Catalysis: The Other Half of the Equation

    SciTech Connect (OSTI)

    Turner, J.

    2008-10-01

    Artificial photosynthesis--splitting water with light--is an attractive way to make hydrogen, but what happens to the oxygen? A catalyst that aids in the efficient production of gaseous oxygen improves the viability of this approach.

  14. Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication 13159553.pdf (405 KB) Technology Marketing Summary This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen

  15. Probing oxygen vacancy concentration and homogeneity in solid...

    Office of Scientific and Technical Information (OSTI)

    on local lattice parameter measurements by scanning transmission electron microscopy. ... Subject: Oxygen Stoichimetry; Vacancy Ordering; Scanning Transmission Electron Microscopy ...

  16. Oxygen-Enriched Combustion for Military Diesel Engine Generators

    Broader source: Energy.gov [DOE]

    Substantial increases in brake power and considerably lower peak pressure can result from oxygen-enriched diesel combustion

  17. Dilute Oxygen Combustion Phase IV Final Report

    SciTech Connect (OSTI)

    Riley, M.F.

    2003-04-30

    Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

  18. DOE Announces $52.5 Million Solicitation for Basic Hydrogen Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    52.5 Million Solicitation for Basic Hydrogen Research Supporting President Bush's Advanced Energy Initiative DOE Announces 52.5 Million Solicitation for Basic Hydrogen Research ...

  19. A review of basic phenomena and techniques for sputter-deposition of high temperature superconducting films

    SciTech Connect (OSTI)

    Auciello, O. North Carolina State Univ., Raleigh, NC . Dept. of Materials Science and Engineering); Ameen, M.S.; Kingon, A.I.; Lichtenwalner, D.J. . Dept. of Materials Science and Engineering); Krauss, A.R. )

    1990-01-01

    The processes involved in plasma and ion beam sputter-deposition of high temperature superconducting thin films are critically reviewed. Recent advances in the development of these techniques are discussed in relation to basic physical phenomena, specific to each technique, which must be understood before high quality films can be produced. Control of film composition is a major issue in sputter-deposition of multicomponent materials. Low temperature processing of films is a common goal for each technique, particularly in relation to integrating high temperature superconducting films with the current microelectronics technology. It has been understood for some time that for Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7} deposition, the most intensely studied high-{Tc} compound, incorporation of sufficient oxygen into the film during deposition is necessary to produce as-deposited superconducting films at relatively substrate temperatures. Recent results have shown that with the use of suitable buffer layers, high quality Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7} sputtered films can be obtained on Si substrates without the need for post-deposition anneal processing. This review is mainly focussed on issues related to sputter-deposition of Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7} thin films, although representative results concerning the bismuth and thallium based compounds are included. 143 refs., 11 figs.

  20. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently andmore » a new strategy of developing the catalyst for oxygen evolution reaction.« less

  1. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithiumoxygen batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently and a new strategy of developing the catalyst for oxygen evolution reaction.

  2. Magnetic interaction in oxygenated alpha Fe-phthalocyanines

    SciTech Connect (OSTI)

    Kuzmann, Ern?, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltn; Horvth, Attila [Institute of Chemistry, Etvs Lornd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsr, Zoltn [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

    2014-10-27

    Alpha iron phthalocyanines (?-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mssbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mssbauer spectroscopy revealed that upon oxygenation of ?-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated ?-FePc was observed below 20 K. In-field Mssbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated ?-FePc.

  3. NREL: Distributed Grid Integration - Energy System Basics Video Series

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Printable Version Energy System Basics Video Series Learn the essential facts on energy systems in this six-part video series sponsored by the DOE SunShot Initiative and hosted by Dr. Ravel Ammerman. Part 1: Electricity Grid Overview Part 2: Electricity Grid: Traditional Generation Technologies Part 3: Electricity Grid: Transmission Systems Part 4: Electricity Grid: Substation Overview Part 5: Electricity Grid: Distribution System Overview Part 6: Electricity Grid: Renewable Energy Resources

  4. NREL: State and Local Governments - Clean Energy Policy Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Clean Energy Policy Basics States and local communities can create policy strategies to help them achieve their clean energy goals. To create effective strategies, it's helpful to understand how to build a clean energy policy portfolio and the different types of policies. Clean Energy Policy Portfolios Single policies don't transform markets for a clean energy economy in states and localities. The most effective approach is to apply a suite of policies in succession-from policies that prepare

  5. Events in time: Basic analysis of Poisson data

    SciTech Connect (OSTI)

    Engelhardt, M.E.

    1994-09-01

    The report presents basic statistical methods for analyzing Poisson data, such as the member of events in some period of time. It gives point estimates, confidence intervals, and Bayesian intervals for the rate of occurrence per unit of time. It shows how to compare subsets of the data, both graphically and by statistical tests, and how to look for trends in time. It presents a compound model when the rate of occurrence varies randomly. Examples and SAS programs are given.

  6. Electron Proton Hydrogen Deuterium Tritium Neutron Fusion Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Hydrogen Deuterium Tritium Neutron Fusion Basics Throughout history, the way in which the sun and stars produce their energy remained a mystery. During the 20th century, scientists discovered that the energy is produced through the fusion of light atoms. Albert Einstein's familiar formula, E=mc 2 , provided the basis for understanding that mass can be converted into energy. With fission, heavy atoms - such as uranium - can be split to release the internal energy that holds them together.

  7. Basic Data Report for Monitor Well AEC-7 Reconfiguration

    SciTech Connect (OSTI)

    Washington Regulatory and Environmental Services

    2005-01-20

    The New Mexico Office of the State Engineer (OSE) permitted well AEC-7 as C-2742. This well has been part of the far-field monitoring network since 1974. The well was used to obtain water level elevations and hydraulic parameters from both the Bell Canyon Formation and the Culebra Member of the Rustler Formation. This basic data report provides a historical account of the well from the original installation to the current configuration.

  8. Recombinant transfer in the basic genome of E. coli

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dixit, Purushottam; Studier, F. William; Pang, Tin Yau; Maslov, Sergei

    2015-07-07

    An approximation to the ~4-Mbp basic genome shared by 32 strains of E. coli representing six evolutionary groups has been derived and analyzed computationally. A multiple-alignment of the 32 complete genome sequences was filtered to remove mobile elements and identify the most reliable ~90% of the aligned length of each of the resulting 496 basic-genome pairs. Patterns of single bp mutations (SNPs) in aligned pairs distinguish clonally inherited regions from regions where either genome has acquired DNA fragments from diverged genomes by homologous recombination since their last common ancestor. Such recombinant transfer is pervasive across the basic genome, mostly betweenmoregenomes in the same evolutionary group, and generates many unique mosaic patterns. The six least-diverged genome-pairs have one or two recombinant transfers of length ~40115 kbp (and few if any other transfers), each containing one or more gene clusters known to confer strong selective advantage in some environments. Moderately diverged genome pairs (0.41% SNPs) show mosaic patterns of interspersed clonal and recombinant regions of varying lengths throughout the basic genome, whereas more highly diverged pairs within an evolutionary group or pairs between evolutionary groups having >1.3% SNPs have few clonal matches longer than a few kbp. Many recombinant transfers appear to incorporate fragments of the entering DNA produced by restriction systems of the recipient cell. A simple computational model can closely fit the data. As a result, most recombinant transfers seem likely to be due to generalized transduction by co-evolving populations of phages, which could efficiently distribute variability throughout bacterial genomes.less

  9. Basic research needed for the development of geothermal energy

    SciTech Connect (OSTI)

    Aamodt, R.L.; Riecker, R.E.

    1980-10-01

    Basic research needed to facilitate development of geothermal energy is identified. An attempt has been made to make the report representative of the ideas of productive workers in the field. The present state of knowledge of geothermal energy is presented and then specific recommendations for further research, with status and priorities, are listed. Discussion is limited to a small number of applicable concepts, namely: origin of geothermal flux; transport of geothermal energy; geothermal reservoirs; rock-water interactions, and geophysical and geochemical exploration.

  10. Nuclear data for basic and applied science. Volume 1

    SciTech Connect (OSTI)

    Young, P.G.; Brown, R.E.; Auchampaugh, G.F.; Lisowski, P.W.; Stewart, L.

    1985-01-01

    This book presents the papers given at a conference on nuclear data for basic and applied science. Topics considered included: nuclear data needs for fusion reactors; fast-neutron interaction with niobium; neutronic analysis of fusion-fusion (hybrid) blankets; measurements of 14 MeV neutron activation cross sections; recent experimental data on sub-barrier fission of light actinides; and intermediate structure in the fission cross sections of the even curium isotopes.

  11. Basic Energy Sciences Materials Sciences programs: FWP executive summaries

    SciTech Connect (OSTI)

    Vook, F.L.; Samara, G.A.

    1989-02-01

    The goals of our Basic Energy Sciences (BES) Materials Science Program at Sandia are: (1) Perform basic, forefront interdisciplinary research using the capabilities of several organizations. (2) Choose programs broadly complementary to Sandia's weapons laboratory mission, but separably identifiable. (3) Perform research in a setting which enhances technological impact because of Sandia's spectrum of basic research, applied research and development engineering. (4) Use large, capital-intensive research facilities not usually found at universities. The BES Materials Science program at Sandia Albuquerque has the central theme of Scientifically Tailored Materials. The major objective of this program is to combine Sandia's expertise and capabilities in the areas of solid state sciences, advanced atomic-level diagnostics, and materials-processing science to produce new classes of tailorable materials for the US energy industry, the electronics industry and for defense needs. Current research in this program includes ion-implantation-modified materials, physics and chemistry of ceramics, tailored surfaces for materials applications, strained-layer semiconductors, chemical vapor deposition, surface photo kinetics, organic and high-temperature superconductors, advanced growth techniques for improved semiconductor structures and boron-rich very high temperature semiconductors.

  12. Cathode architectures for alkali metal / oxygen batteries

    DOE Patents [OSTI]

    Visco, Steven J; Nimon, Vitaliy; De Jonghe, Lutgard C; Volfkovich, Yury; Bograchev, Daniil

    2015-01-13

    Electrochemical energy storage devices, such as alkali metal-oxygen battery cells (e.g., non-aqueous lithium-air cells), have a cathode architecture with a porous structure and pore composition that is tailored to improve cell performance, especially as it pertains to one or more of the discharge/charge rate, cycle life, and delivered ampere-hour capacity. A porous cathode architecture having a pore volume that is derived from pores of varying radii wherein the pore size distribution is tailored as a function of the architecture thickness is one way to achieve one or more of the aforementioned cell performance improvements.

  13. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

    2014-09-01

    The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2•-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2•- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

  14. Dilute Oxygen Combustion Phase I Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    1997-10-31

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  15. Electrochemical oxygen pumps. Final CRADA report.

    SciTech Connect (OSTI)

    Carter, J. D. Noble, J.

    2009-10-01

    All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

  16. Dilute Oxygen Combustion Phase 2 Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    2005-09-30

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  17. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

  18. Processing and Testing of the SRF Photoinjector Cavity for BERLinPro

    SciTech Connect (OSTI)

    Burrill, Andrew; Anders, W.; Frahm, A.; Knobloch, Jens; Neumann, Axel; Ciovati, Gianluigi; Clemens, William; Kneisel, Peter; Turlington, Larry; Zaplatin, Evgeny

    2014-07-01

    The BERLinPro project is a compact, c.w. SRF energy recovery linac (ERL) that is being built to develop the accelerator physics and technology required to operate the next generation of high current ERLs. The machine is designed to produce a 50 MeV 100 mA beam, with better than 1 mm-mrad emittance. The electron source for the ERL will be a SRF photoinjector equipped with a multi-alkali photocathode. In order to produce a SRF photoinjector to operate reliably at this beam current HZB has undertaken a 3 stage photoinjector development program to study the operation of SRF photoinjectors in detail. The 1.4 cell cavity being reported on here is the second stage of this development, and represents the first cavity designed by HZB for use with a high quantum efficiency multi-alkali photocathode. This paper will describe the work done to prepare the cavity for RF testing in the vertical testing dewar at Jefferson Laboratory as well as the results of these RF tests.

  19. Basic Data Report for Drillhole SNL-2 (C-2948)

    SciTech Connect (OSTI)

    Dennis W. Powers; Washington Regultory and Environmental Services

    2005-01-19

    SNL-2 was drilled in the northwest quarter of Section 12, T22S, R30E, in eastern Eddy County, New Mexico (Figure 2-1). It is located 574 ft from the north line (fnl) and 859 ft from the west line (fwl) of the section (Figure 2-2). This location places the drillhole east of the Livingston Ridge escarpment among oil wells of the Cabin Lake field. SNL-2 will be used to test hydraulic properties and to monitor ground water levels of the Culebra Dolomite Member of the Permian Rustler Formation. SNL-2 was permitted by the New Mexico State Engineer as C-2948. [Official correspondence regarding permitting and regulatory information must reference this permit number.] In the plan describing the integrated groundwater hydrology program (Sandia National Laboratories, 2003), SNL-2 is also codesignated WTS-1 because the location also satisfies needs for long-term monitoring of water quality and movement in the Culebra Dolomite for RCRA permitting; this program is under the management of Washington TRU Solutions LLC (WTS). In the event that additional wells are established on the SNL-2 drillpad to monitor other hydrological units (e.g., the Magenta Dolomite Member of the Permian Rustler Formation), the current drillhole will likely be referred to as SNL-2C because it is completed in the Culebra. Most drillholes at WIPP have been described after completion to provide an account of the geology, hydrology, or other basic data acquired during drilling and immediate completion of the drillhole. In addition, the basic data report provides an account of the drilling procedures and activities that may be helpful to later interpretations of data or for further work in the drillhole, including test activities and eventual plugging and abandoning activities. The basic data report also provides a convenient means of reporting information about administrative activities necessary to drill the hole.

  20. Effect of Oxygen Defects on the Catalytic Performance of VOx/CeO2 Catalysts for Oxidative Dehydrogenation of Methanol

    SciTech Connect (OSTI)

    Li, Yan; Wei, Zhehao; Gao, Feng; Kovarik, Libor; Baylon, Rebecca A.; Peden, Charles HF; Wang, Yong

    2015-05-01

    In this work, CeO2 nanocubes with controlled particle size and dominating (100) facets are synthesized as supports for VOx catalysts. Combined TEM, SEM, XRD, and Raman study reveals that the oxygen vacancy density of CeO2 supports can be tuned by tailoring the particle sizes without altering the dominating facets, where smaller particle sizes result in larger oxygen vacancy densities. At the same vanadium coverage, the VOx catalysts supported on small-sized CeO2 supports with higher oxygen defect densities exhibit promoted redox property and lower activation energy for methoxyl group decomposition, as evidenced by H2-TPR and methanol TPD study. These results further confirm that the presence of oxygen vacancies plays an important role in promoting the activity of VOx species in methanol oxidation. We gratefully acknowledge financial support from the U.S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. Part of this work was conducted in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is a multiprogram national laboratory operated for the DOE by Battelle.

  1. Basic visual observation skills training course: Appendix B. Final report

    SciTech Connect (OSTI)

    Toquam, J.L.; Morris, F.A.; Griggs, J.R.

    1995-06-01

    The purpose of the basic visual observation skills course is to help safeguards inspectors evaluate and improve their skills in making observations during inspections and in evaluating and interpreting this information. The first 12 hours of the course provide training in five skill areas: perception and recognition; attention to detail; memory; mental imaging, mapping, and modeling skills; and judgment and decision making. Following this training is an integrating exercise involving a simulated safeguards inspection. This report contains the in-class exercises in the five skill areas; pre- and post-course exercises in closure, hidden figures, map memory, and mental rotations; the final examination; a training evaluation form; and the integrating exercise.

  2. Transmission and Grid Basics for Tribal Economic and Energy Development

    Energy Savers [EERE]

    Transmission and Grid Basics for Tribal Economic and Energy Development March 30, 2016 11:00 am - 12:30 PM MDT Tribal Energy Development Operation and Management Best Practices 2 Todays Presenters * Sean Esterly sean.esterly@nrel.gov * Doug MacCourt Douglas.Maccourt@hq.doe.gov * Kurt Daniel Kdaniel@wapa.gov * Dave Narang david.narang@nrel.gov * Jon Steward Steward@wapa.gov * Tawnie Knight tawnieknight@utemountain.org * Scott Clow sclow@utemountain.org * Bob Easton aeaston@wapa.gov 3 Link to the

  3. NREL: Learning - Plug-In Hybrid Electric Vehicle Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plug-In Hybrid Electric Vehicle Basics Photo of a parked blue compact car with large decals on the doors stating that it is a plug-in hybrid achieving more than 120 miles per gallon. This Toyota Prius hybrid electric car was converted to a plug-in hybrid for research purposes. Credit: Keith Wipke Image of the cutaway top view of a passenger vehicle showing the drive train that contains an electric motor and a small internal combustion engine side by side in front. The motors are connected by

  4. Basic devices and techniques for supervisory control and telemetery systems

    SciTech Connect (OSTI)

    Knox, R.M.

    1984-04-01

    The microprocessor is creating extraordinary changes in the basic devices used for supervisory control and telemetry systems. Devices which incorporate microprocessors are providing new capabilities to monitor, to control, and to transmit data. These new capabilities provide the opportunity to utilize new techniques in achieving more efficient operation and control of gas transmission and distribution systems. This paper describes several devices being installed at Transcocontinental Gas Pipe Line Corporation and their impact on the planned techniques to be used to collect gas flow data and to implement supervisory control.

  5. SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION

    SciTech Connect (OSTI)

    Timothy L. Ward

    2002-07-01

    Mixed-conducting ceramics have the ability to conduct oxygen with perfect selectivity at elevated temperatures, making them extremely attractive as membrane materials for oxygen separation and membrane reactor applications. While the conductivity of these materials can be quite high at elevated temperatures (typically 800-1000 C), much higher oxygen fluxes, or, alternatively, equivalent fluxes at lower temperatures, could be provided by supported thin or thick film membrane layers. Based on that motivation, the objective of this project was to explore the use of ultrafine aerosol-derived powder of a mixed-conducting ceramic material for fabrication of supported thick-film dense membranes. The project focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} (SCFO) because of the desirable permeability and stability of that material, as reported in the literature. Appropriate conditions to produce the submicron SrCo{sub 0.5}FeO{sub x} powder using aerosol pyrolysis were determined. Porous supports of the same composition were produced by partial sintering of a commercially obtained powder that possessed significantly larger particle size than the aerosol-derived powder. The effects of sintering conditions (temperature, atmosphere) on the porosity and microstructure of the porous discs were studied, and a standard support fabrication procedure was adopted. Subsequently, a variety of paste and slurry formulations were explored utilizing the aerosol-derived SCFO powder. These formulations were applied to the porous SCFO support by a doctor blade or spin coating procedure. Sintering of the supported membrane layer was then conducted, and additional layers were deposited and sintered in some cases. The primary characterization methods were X-ray diffraction and scanning electron microscopy, and room-temperature nitrogen permeation was used to assess defect status of the membranes.We found that non-aqueous paste/slurry formulations incorporating dispersant, plasticizer and binder provided superior cracking resistance compared to simple water, alcohol, or polyethylene glycol (PEG) based formulations. With a formulation employing castor oil as dispersant, isopropyl alcohol/mineral spirits as solvent, polyvinyl butyral as binder, and dibutyl phthalate/PEG as plasticizer, sintered SCFO membrane layers approximately 5 {micro}m thick with no apparent cracks were prepared using spin coating with several coats and sintering cycles. A similar but more viscous formulation applied by doctor blade gave a {approx} 10 {micro}m thick membrane layer in one coat, but with some apparent cracking. We demonstrated that the membrane layer could be densified while retaining porosity in the chemically identical support. This was accomplished by pre-sintering the support in air (1050 C), which coarsened the grain size and provided a relatively stable plate-shaped granular microstructure, followed by membrane layer fabrication with the highly-sinterable aerosol powder. Final densification was conducted by sintering in nitrogen ({approx}1100 C), which provided accelerated sintering rates and led to the desired layered perovskite phase content. In spite of these successes, low-temperature pressure-driven permeation testing with N2 showed that even the best membranes were not sufficiently defect free for high-temperature oxygen permeation testing. The source of these defects were not readily apparent from scanning electron microscopy, though incomplete or nonuniform membrane layer coverage from edge to edge of the support was probably one important factor.

  6. METHOD OF COMBINING HYDROGEN AND OXYGEN

    DOE Patents [OSTI]

    McBride, J.P.

    1962-02-27

    A method is given for the catalytic recombination of radiolytic hydrogen and/or deulerium and oxygen resulting from the subjection or an aqueous thorium oxide or thorium oxide-uranium oxide slurry to ionizing radiation. An improved catalyst is prepared by providing paliadium nitrate in an aqueous thorium oxide sol at a concentration of at least 0.05 grams per gram of thorium oxide and contacting the sol with gaseous hydrogen to form flocculated solids. The solids are then recovered and added to the slurry to provide a palladium concentration of 100 to 1000 parts per million. Recombination is effected by the calalyst at a rate sufficient to support high nuclear reactor power densities. (AEC)

  7. Preliminary Study of Oxygen-Enhanced Longitudinal Relaxation in MRI: A Potential Novel Biomarker of Oxygenation Changes in Solid Tumors

    SciTech Connect (OSTI)

    O'Connor, James P.B.; Naish, Josephine H.; Parker, Geoff J.M.; Waterton, John C.; Watson, Yvonne; Jayson, Gordon C.; Buonaccorsi, Giovanni A.; Cheung, Sue; Buckley, David L.; McGrath, Deirdre M.; West, Catharine M.L.; Davidson, Susan E.; Roberts, Caleb; Mills, Samantha J.; Mitchell, Claire L.; Hope, Lynn; Ton, N. Chan; Jackson, Alan

    2009-11-15

    Purpose: There is considerable interest in developing non-invasive methods of mapping tumor hypoxia. Changes in tissue oxygen concentration produce proportional changes in the magnetic resonance imaging (MRI) longitudinal relaxation rate (R{sub 1}). This technique has been used previously to evaluate oxygen delivery to healthy tissues and is distinct from blood oxygenation level-dependent (BOLD) imaging. Here we report application of this method to detect alteration in tumor oxygenation status. Methods and materials: Ten patients with advanced cancer of the abdomen and pelvis underwent serial measurement of tumor R{sub 1} while breathing medical air (21% oxygen) followed by 100% oxygen (oxygen-enhanced MRI). Gadolinium-based dynamic contrast-enhanced MRI was then performed to compare the spatial distribution of perfusion with that of oxygen-induced DELTAR{sub 1}. Results: DELTAR{sub 1} showed significant increases of 0.021 to 0.058 s{sup -1} in eight patients with either locally recurrent tumor from cervical and hepatocellular carcinomas or metastases from ovarian and colorectal carcinomas. In general, there was congruency between perfusion and oxygen concentration. However, regional mismatch was observed in some tumor cores. Here, moderate gadolinium uptake (consistent with moderate perfusion) was associated with low area under the DELTAR{sub 1} curve (consistent with minimal increase in oxygen concentration). Conclusions: These results provide evidence that oxygen-enhanced longitudinal relaxation can monitor changes in tumor oxygen concentration. The technique shows promise in identifying hypoxic regions within tumors and may enable spatial mapping of change in tumor oxygen concentration.

  8. Dilute Oxygen Combustion - Phase 3 Report

    SciTech Connect (OSTI)

    Riley, Michael F.

    2000-05-31

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  9. Dilute Oxygen Combustion Phase 3 Final Report

    SciTech Connect (OSTI)

    Riley, M.F.; Ryan, H.M.

    2000-05-31

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  10. Basic Solar Energy Research in Japan (2011 EFRC Forum)

    SciTech Connect (OSTI)

    Domen, Kazunari

    2011-05-26

    Kazunari Domen, Chemical System Engineering Professor at the University of Tokyo, was the second speaker in the May 26, 2011 EFRC Forum session, "Global Perspectives on Frontiers in Energy Research." In his presentation, Professor Domen talked about basic solar energy research in Japan. The 2011 EFRC Summit and Forum brought together the EFRC community and science and policy leaders from universities, national laboratories, industry and government to discuss "Science for our Nation's Energy Future." In August 2009, the Office of Science established 46 Energy Frontier Research Centers. The EFRCs are collaborative research efforts intended to accelerate high-risk, high-reward fundamental research, the scientific basis for transformative energy technologies of the future. These Centers involve universities, national laboratories, nonprofit organizations, and for-profit firms, singly or in partnerships, selected by scientific peer review. They are funded at $2 to $5 million per year for a total planned DOE commitment of $777 million over the initial five-year award period, pending Congressional appropriations. These integrated, multi-investigator Centers are conducting fundamental research focusing on one or more of several “grand challenges” and use-inspired “basic research needs” recently identified in major strategic planning efforts by the scientific community. The purpose of the EFRCs is to integrate the talents and expertise of leading scientists in a setting designed to accelerate research that transforms the future of energy and the environment.

  11. Basic Solar Energy Research in Japan (2011 EFRC Forum)

    ScienceCinema (OSTI)

    Domen, Kazunari (University of Tokyo)

    2012-03-14

    Kazunari Domen, Chemical System Engineering Professor at the University of Tokyo, was the second speaker in the May 26, 2011 EFRC Forum session, "Global Perspectives on Frontiers in Energy Research." In his presentation, Professor Domen talked about basic solar energy research in Japan. The 2011 EFRC Summit and Forum brought together the EFRC community and science and policy leaders from universities, national laboratories, industry and government to discuss "Science for our Nation's Energy Future." In August 2009, the Office of Science established 46 Energy Frontier Research Centers. The EFRCs are collaborative research efforts intended to accelerate high-risk, high-reward fundamental research, the scientific basis for transformative energy technologies of the future. These Centers involve universities, national laboratories, nonprofit organizations, and for-profit firms, singly or in partnerships, selected by scientific peer review. They are funded at $2 to $5 million per year for a total planned DOE commitment of $777 million over the initial five-year award period, pending Congressional appropriations. These integrated, multi-investigator Centers are conducting fundamental research focusing on one or more of several ?grand challenges? and use-inspired ?basic research needs? recently identified in major strategic planning efforts by the scientific community. The purpose of the EFRCs is to integrate the talents and expertise of leading scientists in a setting designed to accelerate research that transforms the future of energy and the environment.

  12. Homogeneously dispersed, multimetal oxygen-evolving catalysts (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Homogeneously dispersed, multimetal oxygen-evolving catalysts Citation Details In-Document Search This content will become publicly available on March 24, 2017 Title: Homogeneously dispersed, multimetal oxygen-evolving catalysts Earth-abundant first-row (3d) transition-metal-based catalysts have been developed for the oxygen-evolution reaction (OER); however, they operate at overpotentials significantly above thermodynamic requirements. Density functional theory

  13. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of molecular oxygen ions in the upper-most atmosphere of Dione. March 3, 2012 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics

  14. Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrode Technique | Department of Energy Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Above is the video recording for the webinar, "Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique," originally held on March 12, 2013. In addition to this recording, you can access the presentation slides. A text version of

  15. Direct Observation of Localized Radial Oxygen Migration in Functioning

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tantalum Oxide Memristors Direct Observation of Localized Radial Oxygen Migration in Functioning Tantalum Oxide Memristors Direct Observation of Localized Radial Oxygen Migration in Functioning Tantalum Oxide Memristors Print Monday, 11 April 2016 14:29 As information bits of 0s and 1s are stored in crosspoint tantalum oxide memristors, or resistive random access memory (RRAM) cells, nanoscale-resolution in operando x-ray transmission spectromicroscopy is used to directly observe oxygen

  16. Electrocatalyst for Oxygen Reduction with Reduced Platinum Oxidation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is the most efficient electrocatalyst for accelerating the oxygen reduction reaction in fuel cells. Under operating conditions, though, platinum catalysts can dissolve. When used...

  17. Hybrid System for Separating Oxygen from Air - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate...

  18. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen ...

  19. Testing Oxygen Reduction Reaction Activity with the Rotating...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Date: Tuesday, March 12, 2013 Innovation for Our Energy Future Shyam S. Kocha: NREL Yannick ...

  20. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) ...

  1. Strain control of oxygen vacancies in epitaxial strontium cobaltite films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jeen, Hyoung Jeen; Choi, Woo Seok; Reboredo, Fernando A.; Freeland, John W.; Eres, Gyula; Lee, Ho Nyung; Petrie, Jonathan R.; Mitra, Chandrima; Meyer, Tricia L.

    2016-01-25

    In this study, the ability to manipulate oxygen anion defects rather than metal cations in complex oxides can facilitate creating new functionalities critical for emerging energy and device technologies. However, the difficulty in activating oxygen at reduced temperatures hinders the deliberate control of important defects, oxygen vacancies. Here, strontium cobaltite (SrCoOx) is used to demonstrate that epitaxial strain is a powerful tool for manipulating the oxygen vacancy concentration even under highly oxidizing environments and at annealing temperatures as low as 300 °C. By applying a small biaxial tensile strain (2%), the oxygen activation energy barrier decreases by ≈30%, resulting inmore » a tunable oxygen deficient steady-state under conditions that would normally fully oxidize unstrained cobaltite. These strain-induced changes in oxygen stoichiometry drive the cobaltite from a ferromagnetic metal towards an antiferromagnetic insulator. The ability to decouple the oxygen vacancy concentration from its typical dependence on the operational environment is useful for effectively designing oxides materials with a specific oxygen stoichiometry.« less

  2. Electrocatalyst for Oxygen Reduction with Reduced Platinum Oxidation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates The invention relates to platinum-metal oxide composite particles and their use as...

  3. Ultrafast kinetics subsequent to shock compression in an oxygen...

    Office of Scientific and Technical Information (OSTI)

    to shock compression in an oxygen-balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock ...

  4. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an ...

  5. The Electronic Structure of Oxygen Atom Vacancy and Hydroxyl...

    Office of Scientific and Technical Information (OSTI)

    Title: The Electronic Structure of Oxygen Atom Vacancy and Hydroxyl Impurity Defects on Titanium Dioxide (110) Surface Introducing a charge into a solid such as a metal oxide ...

  6. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    - - - - - - - - - - - - See footnotes at end of table. 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 116 Energy Information...

  7. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  8. Interplay between gadolinium dopants and oxygen vacancies in...

    Office of Scientific and Technical Information (OSTI)

    theory plus Hubbard U investigation Citation Details In-Document Search Title: Interplay between gadolinium dopants and oxygen vacancies in HfOsub 2: A density functional theory ...

  9. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen...

    Energy Savers [EERE]

    Review 2015: Intake Air Oxygen Sensor Vehicle Technologies Office Merit Review 2014: Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency...

  10. Vehicle Technologies Office Merit Review 2015: Intake Air Oxygen...

    Energy Savers [EERE]

    Office Merit Review 2014: Intake Air Oxygen Sensor Bosch Powertrain Technologies Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency...

  11. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, George E.; Merritt, Bernard T.; Hsiao, Mark C.; Wallman, P. Henrik; Penetrante, Bernardino M.

    1999-01-01

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO.sub.x reduction in oxygen-rich vehicle engine exhausts.

  12. Discovery of oxygen in atmosphere could mean life for Saturn...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is the possibility that on a moon with subsurface water, such as Jupiter's moon Europa, molecular oxygen could combine with carbon in subsurface lakes to form the building...

  13. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is the possibility that on a moon with subsurface water, such as Jupiter's moon Europa, molecular oxygen could combine with carbon in subsurface lakes to form the building...

  14. Kinetics of oxygen surface exchange on epitaxial Ruddlesden-Popper...

    Office of Scientific and Technical Information (OSTI)

    Kinetics of oxygen surface exchange on epitaxial Ruddlesden-Popper phases and correlations to first-principles descriptors Citation Details In-Document Search This content will ...

  15. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  16. Oxidation State and Interfacial Effects on Oxygen Vacancies in...

    Office of Scientific and Technical Information (OSTI)

    Oxygen Vacancies in Tantalum Pentoxide. Abstract not provided. Authors: Bondi, Robert James ; Marinella, Matthew Publication Date: 2014-10-01 OSTI Identifier: 1184499 Report...

  17. Reactivity of perovskites with water: Role of hydroxylation in wetting and implications for oxygen electrocatalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stoerzinger, Kelsey A.; Hong, Wesley T.; Azimi, Gisele; Crumlin, Ethan J.; Biegalski, Michael D.; Bluhm, Hendrik; Varanasi, Kripa K.; Shao-Horn, Yang; Giordano, Livia; Lee, Yueh -Lin

    2015-07-15

    Oxide materials play an important role in technical applications such as gas sensing and catalysis, where they can react notably with water in vapor or liquid form. We find that the coverage of (*OH) measured at fixed relative humidity trends with the electron donor (basic) character of wetted perovskite oxide surfaces, corresponding to low contact angles when removing a droplet of water. We report for the first time that the affinity toward hydroxylation, coincident with strong adsorption energies calculated for dissociative and molecular adsorption of water, leads to strong H-bonding detrimental to catalysis of the oxygen reduction reaction (ORR). Furthermore,more » this suggests that hydrophobic oxides with low tendency to hydroxylate may demonstrate improved catalytic activity for the ORR.« less

  18. Reactivity of perovskites with water: Role of hydroxylation in wetting and implications for oxygen electrocatalysis

    SciTech Connect (OSTI)

    Stoerzinger, Kelsey A.; Hong, Wesley T.; Azimi, Gisele; Crumlin, Ethan J.; Biegalski, Michael D.; Bluhm, Hendrik; Varanasi, Kripa K.; Shao-Horn, Yang; Giordano, Livia; Lee, Yueh -Lin

    2015-07-15

    Oxide materials play an important role in technical applications such as gas sensing and catalysis, where they can react notably with water in vapor or liquid form. We find that the coverage of (*OH) measured at fixed relative humidity trends with the electron donor (basic) character of wetted perovskite oxide surfaces, corresponding to low contact angles when removing a droplet of water. We report for the first time that the affinity toward hydroxylation, coincident with strong adsorption energies calculated for dissociative and molecular adsorption of water, leads to strong H-bonding detrimental to catalysis of the oxygen reduction reaction (ORR). Furthermore, this suggests that hydrophobic oxides with low tendency to hydroxylate may demonstrate improved catalytic activity for the ORR.

  19. Basic Research Needs for Advanced Nuclear Systems. Report of the Basic Energy Sciences Workshop on Basic Research Needs for Advanced Nuclear Energy Systems, July 31-August 3, 2006

    SciTech Connect (OSTI)

    Roberto, J.; Diaz de la Rubia, T.; Gibala, R.; Zinkle, S.; Miller, J.R.; Pimblott, S.; Burns, C.; Raymond, K.; Grimes, R.; Pasamehmetoglu, K.; Clark, S.; Ewing, R.; Wagner, A.; Yip, S.; Buchanan, M.; Crabtree, G.; Hemminger, J.; Poate, J.; Miller, J.C.; Edelstein, N.; Fitzsimmons, T.; Gruzalski, G.; Michaels, G.; Morss, L.; Peters, M.; Talamini, K.

    2006-10-01

    The global utilization of nuclear energy has come a long way from its humble beginnings in the first sustained nuclear reaction at the University of Chicago in 1942. Today, there are over 440 nuclear reactors in 31 countries producing approximately 16% of the electrical energy used worldwide. In the United States, 104 nuclear reactors currently provide 19% of electrical energy used nationally. The International Atomic Energy Agency projects significant growth in the utilization of nuclear power over the next several decades due to increasing demand for energy and environmental concerns related to emissions from fossil plants. There are 28 new nuclear plants currently under construction including 10 in China, 8 in India, and 4 in Russia. In the United States, there have been notifications to the Nuclear Regulatory Commission of intentions to apply for combined construction and operating licenses for 27 new units over the next decade. The projected growth in nuclear power has focused increasing attention on issues related to the permanent disposal of nuclear waste, the proliferation of nuclear weapons technologies and materials, and the sustainability of a once-through nuclear fuel cycle. In addition, the effective utilization of nuclear power will require continued improvements in nuclear technology, particularly related to safety and efficiency. In all of these areas, the performance of materials and chemical processes under extreme conditions is a limiting factor. The related basic research challenges represent some of the most demanding tests of our fundamental understanding of materials science and chemistry, and they provide significant opportunities for advancing basic science with broad impacts for nuclear reactor materials, fuels, waste forms, and separations techniques. Of particular importance is the role that new nanoscale characterization and computational tools can play in addressing these challenges. These tools, which include DOE synchrotron X-ray sources, neutron sources, nanoscale science research centers, and supercomputers, offer the opportunity to transform and accelerate the fundamental materials and chemical sciences that underpin technology development for advanced nuclear energy systems. The fundamental challenge is to understand and control chemical and physical phenomena in multi-component systems from femto-seconds to millennia, at temperatures to 1000?C, and for radiation doses to hundreds of displacements per atom (dpa). This is a scientific challenge of enormous proportions, with broad implications in the materials science and chemistry of complex systems. New understanding is required for microstructural evolution and phase stability under relevant chemical and physical conditions, chemistry and structural evolution at interfaces, chemical behavior of actinide and fission-product solutions, and nuclear and thermomechanical phenomena in fuels and waste forms. First-principles approaches are needed to describe f-electron systems, design molecules for separations, and explain materials failure mechanisms. Nanoscale synthesis and characterization methods are needed to understand and design materials and interfaces with radiation, temperature, and corrosion resistance. Dynamical measurements are required to understand fundamental physical and chemical phenomena. New multiscale approaches are needed to integrate this knowledge into accurate models of relevant phenomena and complex systems across multiple length and time scales.

  20. Oxygen diffusion of anodic surface oxide film on titanium studied by Auger electron spectroscopy. [Oxygen diffusivity

    SciTech Connect (OSTI)

    Wang, P.S.; Wittberg, T.N.; Keil, R.G.

    1982-01-01

    TiO/sub 2/ films of about 1000 A were grown onto titanium foils anodically under galvanostatic conditions at 20 mA/cm/sup 2/ in saturated aqueous solutions of ammonium tetraborate. The samples were then aged at 450, 500, and 550/sup 0/C, and oxygen diffusion was observed by Auger electron spectroscopy (AES) profilings. The oxygen diffusivities were calculated by Fick's Second Law, using the Boltzmann-Matano solution, to be 9.4 x 10/sup -17/, 2.6 x 10/sup -16/, and 1.2 x 10/sup -15/ cm/sup 2//sec at 450, 500, and 550/sup 0/C, respectively. The diffusivities obtained by this method were also compared with those obtained using an exact solution to Fick's Second Law. The activation energy was calculated to be 30 kcal/mole.

  1. Criticality Safety Basics for INL FMHs and CSOs

    SciTech Connect (OSTI)

    V. L. Putman

    2012-04-01

    Nuclear power is a valuable and efficient energy alternative in our energy-intensive society. However, material that can generate nuclear power has properties that require this material be handled with caution. If improperly handled, a criticality accident could result, which could severely harm workers. This document is a modular self-study guide about Criticality Safety Principles. This guide's purpose it to help you work safely in areas where fissionable nuclear materials may be present, avoiding the severe radiological and programmatic impacts of a criticality accident. It is designed to stress the fundamental physical concepts behind criticality controls and the importance of criticality safety when handling fissionable materials outside nuclear reactors. This study guide was developed for fissionable-material-handler and criticality-safety-officer candidates to use with related web-based course 00INL189, BEA Criticality Safety Principles, and to help prepare for the course exams. These individuals must understand basic information presented here. This guide may also be useful to other Idaho National Laboratory personnel who must know criticality safety basics to perform their assignments safely or to design critically safe equipment or operations. This guide also includes additional information that will not be included in 00INL189 tests. The additional information is in appendices and paragraphs with headings that begin with 'Did you know,' or with, 'Been there Done that'. Fissionable-material-handler and criticality-safety-officer candidates may review additional information at their own discretion. This guide is revised as needed to reflect program changes, user requests, and better information. Issued in 2006, Revision 0 established the basic text and integrated various programs from former contractors. Revision 1 incorporates operation and program changes implemented since 2006. It also incorporates suggestions, clarifications, and additional information from readers and from personnel who took course 00INL189. Revision 1 also completely reorganized the training to better emphasize physical concepts behind the criticality controls that fissionable material handlers and criticality safety officers must understand. The reorganization is based on and consistent with changes made to course 00INL189 due to a review of course exam results and to discussions with personnel who conduct area-specific training.

  2. BioenergizeME Office Hours Webinar: Biomass Basics

    Broader source: Energy.gov [DOE]

    Many students haven’t thought much about biomass as an option for generating electricity, transportation fuels, and other products. The Biomass Basics Webinar provides general information about bioenergy, its creation, and its potential uses, and is designed to assist teams competing in the 2016 BioenergizeME Infographic Challenge. This challenge, hosted by the U.S. Department of Energy’s Bioenergy Technologies Office (BETO), is a competition for high school students to learn about bioenergy, create infographics to present what they have learned, and share their infographics on social media. This webinar is part of the BioenergizeME Office Hours webinar series developed by BETO in conjunction with the 2016 BioenergizeME Infographic Challenge.

  3. Supporting Advanced Scientific Computing Research * Basic Energy Sciences * Biological

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy S ciences N etwork Enabling Virtual Science June 9, 2009 Steve C o/er steve@es.net Dept. H ead, E nergy S ciences N etwork Lawrence B erkeley N aDonal L ab The E nergy S ciences N etwork The D epartment o f E nergy's O ffice o f S cience i s o ne o f t he l argest s upporters o f basic r esearch i n t he p hysical s ciences i n t he U .S. * Directly s upports t he r esearch o f s ome 1 5,000 s cienDsts, p ostdocs a nd g raduate s tudents at D OE l aboratories, u niversiDes, o ther F

  4. Oximeter for reliable clinical determination of blood oxygen saturation in a fetus

    DOE Patents [OSTI]

    Robinson, Mark R.; Haaland, David M.; Ward, Kenneth J.

    1996-01-01

    With the crude instrumentation now in use to continuously monitor the status of the fetus at delivery, the obstetrician and labor room staff not only over-recognize the possibility of fetal distress with the resultant rise in operative deliveries, but at times do not identify fetal distress which may result in preventable fetal neurological harm. The invention, which addresses these two basic problems, comprises a method and apparatus for non-invasive determination of blood oxygen saturation in the fetus. The apparatus includes a multiple frequency light source which is coupled to an optical fiber. The output of the fiber is used to illuminate blood containing tissue of the fetus. In the preferred embodiment, the reflected light is transmitted back to the apparatus where the light intensities are simultaneously detected at multiple frequencies. The resulting spectrum is then analyzed for determination of oxygen saturation. The analysis method uses multivariate calibration techniques that compensate for nonlinear spectral response, model interfering spectral responses and detect outlier data with high sensitivity.

  5. W, F, and I : Three quantities basic to radiation physics. (Conference...

    Office of Scientific and Technical Information (OSTI)

    W, F, and I : Three quantities basic to radiation physics. Citation Details In-Document Search Title: W, F, and I : Three quantities basic to radiation physics. You are ...

  6. Energy Dept. Awards $22.7 Million for Basic Solar Energy Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    22.7 Million for Basic Solar Energy Research Energy Dept. Awards 22.7 Million for Basic Solar Energy Research May 22, 2007 - 1:24pm Addthis WASHINGTON, DC - The U.S. Department of ...

  7. Palladium-cobalt particles as oxygen-reduction electrocatalysts

    DOE Patents [OSTI]

    Adzic, Radoslav; Huang, Tao

    2009-12-15

    The present invention relates to palladium-cobalt particles useful as oxygen-reducing electrocatalysts. The invention also relates to oxygen-reducing cathodes and fuel cells containing these palladium-cobalt particles. The invention additionally relates to methods for the production of electrical energy by using the palladium-cobalt particles of the invention.

  8. Effects of oxygen and catalyst on tetraphenylborate decomposition rate

    SciTech Connect (OSTI)

    Walker, D.D.

    1999-12-15

    Previous studies indicate that palladium catalyzes rapid decomposition of alkaline tetraphenylborate slurries. Oxygen inhibits the reaction at low temperature (25 C), presumably by preventing activation of the catalyst. The present study investigated oxygen's inhibiting effectiveness at higher temperature (45 C) and catalyst concentrations.

  9. Low NOx combustion using cogenerated oxygen and nitrogen streams

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, Lawrence E.; Snyder, William J.

    2009-02-03

    Combustion of hydrocarbon fuel is achieved with less formation of NOx by feeding the fuel into a slightly oxygen-enriched atmosphere, and separating air into oxygen-rich and nitrogen-rich streams which are fed separately into the combustion device.

  10. Device for measuring the total concentration of oxygen in gases

    DOE Patents [OSTI]

    Isaacs, Hugh S.; Romano, Anthony J.

    1977-01-01

    This invention provides a CO equilibrium in a device for measuring the total concentration of oxygen impurities in a fluid stream. To this end, the CO equilibrium is produced in an electrochemical measuring cell by the interaction of a carbon element in the cell with the chemically combined and uncombined oxygen in the fluid stream at an elevated temperature.

  11. Willamette Oxygen Supplementation Studies : Annual Report 1994.

    SciTech Connect (OSTI)

    Ewing, R.D.; Ewing, S.K.; Sheahan, J.E.

    1994-09-01

    Hydropower development and operations in the Columbia River basin have caused the loss of 5 million to 11 million salmonids. An interim goal of the Northwest Power Planning Council is to reestablish these historical numbers by doubling the present runs from 2.5 million adult fish to 5.0 million adult fish. This increase in production will be accomplished through comprehensive management of both wild and hatchery fish, but artificial propagation will play a major role in the augmentation process. The current husbandry techniques in existing hatcheries require improvements that may include changes in rearing densities, addition of oxygen, removal of excess nitrogen, and improvement in raceway design. Emphasis will be placed on the ability to increase the number of fish released from hatcheries that survive to return as adults. Rearing density is one of the most important elements in fish culture. Fish culturists have attempted to rear fish in hatchery ponds at densities that most efficiently use the rearing space available. Such efficiency studies require a knowledge of cost of rearing and the return of adults to the fisheries and to the hatchery.

  12. Homogeneously dispersed, multimetal oxygen-evolving catalysts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Bo; Zheng, Xueli; Voznyy, Oleksandr; Comin, Riccardo; Bajdich, Michal; Garcia-Melchor, Max; Han, Lili; Xu, Jixian; Liu, Min; Zheng, Lirong; et al

    2016-03-24

    Earth-abundant first-row (3d) transition-metal-based catalysts have been developed for the oxygen-evolution reaction (OER); however, they operate at overpotentials significantly above thermodynamic requirements. Density functional theory suggested that non-3d high-valency metals such as tungsten can modulate 3d metal oxides, providing near-optimal adsorption energies for OER intermediates. We developed a room-temperature synthesis to produce gelled oxy-hydroxide materials with an atomically homogeneous metal distribution. These gelled FeCoW oxy-hydroxide exhibits the lowest overpotential (191 mV) reported at 10 mA per square centimeter in alkaline electrolyte. Here, the catalyst shows no evidence of degradation following more than 500 hours of operation. X-ray absorption and computationalmore » studies reveal a synergistic interplay between W, Fe and Co in producing a favorable local coordination environment and electronic structure that enhance the energetics for OER.« less

  13. Nanoparticulate-catalyzed oxygen transfer processes

    DOE Patents [OSTI]

    Hunt, Andrew T.; Breitkopf, Richard C.

    2009-12-01

    Nanoparticulates of oxygen transfer materials that are oxides of rare earth metals, combinations of rare earth metals, and combinations of transition metals and rare earth metals are used as catalysts in a variety of processes. Unexpectedly large thermal efficiencies are achieved relative to micron sized particulates. Processes that use these catalysts are exemplified in a multistage reactor. The exemplified reactor cracks C6 to C20 hydrocarbons, desulfurizes the hydrocarbon stream and reforms the hydrocarbons in the stream to produce hydrogen. In a first reactor stage the steam and hydrocarbon are passed through particulate mixed rare earth metal oxide to crack larger hydrocarbon molecules. In a second stage, the steam and hydrocarbon are passed through particulate material that desulfurizes the hydrocarbon. In a third stage, the hydrocarbon and steam are passed through a heated, mixed transition metal/rare earth metal oxide to reform the lower hydrocarbons and thereby produce hydrogen. Stages can be alone or combined. Parallel reactors can provide continuous reactant flow. Each of the processes can be carried out individually.

  14. Webinar: BioenergizeME Office Hours Webinar: Biomass Basics | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Biomass Basics Webinar: BioenergizeME Office Hours Webinar: Biomass Basics Webinar: BioenergizeME Office Hours Webinar: Biomass Basics PDF icon biomas_basics_webinar_20150827.pdf More Documents & Publications BioenergizeME Office Hours Webinar: Integrating Bioenergy into the 9th-12th Grade Classroom BioenergizeME Infographic Challenge Annual Update Webinar: BioenergizeME Office Hours Webinar: Guide to the 2016 BioenergizeME Infographic Challenge

  15. Direct tuyere injection of oxygen for enhanced coal combustion

    SciTech Connect (OSTI)

    Riley, M.F.

    1996-12-31

    Injecting oxygen directly into the tuyere blowpipe can enhance the ignition and combustion of injected pulverized coal, allowing the efficient use of higher coal rates at high furnace production levels. The effects of direct oxygen injection have been estimated from an analysis of the factors controlling the dispersion, heating, ignition, and combustion of injected coal. Injecting ambient temperature oxygen offers mechanical improvements in the dispersion of coal but provides little thermochemical benefit over increased blast enrichment. Injecting hot oxygen through a novel, patented thermal nozzle lance offers both mechanical and thermochemical benefits over increased enrichment or ambient oxygen injection. Plans for pilot-scale and commercial-scale testing of this new lance are described.

  16. Materials Issues in Advanced Nuclear Systems: Executive Summary of DOE Basic Research Needs Workshop, "Basic Research Needs for Advanced Nuclear Energy Systems"

    SciTech Connect (OSTI)

    Roberto, James B; Diaz de la Rubia, Tomas

    2007-01-01

    This article is reproduced from excerpts from the Report of the Basic Energy Sciences Workshop on Basic Research Needs for Advanced Nuclear Energy Systems, U.S. Department of Energy, October 2006, www.sc.doe.gov/bes/reports/files/ANES_rpt.pdf.

  17. Towards reversible basic linear algebra subprograms: A performance study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Perumalla, Kalyan S.; Yoginath, Srikanth B.

    2014-12-06

    Problems such as fault tolerance and scalable synchronization can be efficiently solved using reversibility of applications. Making applications reversible by relying on computation rather than on memory is ideal for large scale parallel computing, especially for the next generation of supercomputers in which memory is expensive in terms of latency, energy, and price. In this direction, a case study is presented here in reversing a computational core, namely, Basic Linear Algebra Subprograms, which is widely used in scientific applications. A new Reversible BLAS (RBLAS) library interface has been designed, and a prototype has been implemented with two modes: (1) amore » memory-mode in which reversibility is obtained by checkpointing to memory in forward and restoring from memory in reverse, and (2) a computational-mode in which nothing is saved in the forward, but restoration is done entirely via inverse computation in reverse. The article is focused on detailed performance benchmarking to evaluate the runtime dynamics and performance effects, comparing reversible computation with checkpointing on both traditional CPU platforms and recent GPU accelerator platforms. For BLAS Level-1 subprograms, data indicates over an order of magnitude better speed of reversible computation compared to checkpointing. For BLAS Level-2 and Level-3, a more complex tradeoff is observed between reversible computation and checkpointing, depending on computational and memory complexities of the subprograms.« less

  18. Basic features of the pion valence-quark distribution function

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chang, Lei; Mezrag, Cdric; Moutarde, Herv; Roberts, Craig D.; Rodrguez-Quintero, Jose; Tandy, Peter C.

    2014-10-07

    The impulse-approximation expression used hitherto to define the pion's valence-quark distribution function is flawed because it omits contributions from the gluons which bind quarks into the pion. A corrected leading-order expression produces the model-independent result that quarks dressed via the rainbowladder truncation, or any practical analogue, carry all the pion's light-front momentum at a characteristic hadronic scale. Corrections to the leading contribution may be divided into two classes, responsible for shifting dressed-quark momentum into glue and sea-quarks. Working with available empirical information, we use an algebraic model to express the principal impact of both classes of corrections. This enables amorerealistic comparison with experiment that allows us to highlight the basic features of the pion's measurable valence-quark distribution, q?(x); namely, at a characteristic hadronic scale, q?(x)~(1-x)2 for x?0.85; and the valence-quarks carry approximately two-thirds of the pion's light-front momentum.less

  19. Towards reversible basic linear algebra subprograms: A performance study

    SciTech Connect (OSTI)

    Perumalla, Kalyan S.; Yoginath, Srikanth B.

    2014-12-06

    Problems such as fault tolerance and scalable synchronization can be efficiently solved using reversibility of applications. Making applications reversible by relying on computation rather than on memory is ideal for large scale parallel computing, especially for the next generation of supercomputers in which memory is expensive in terms of latency, energy, and price. In this direction, a case study is presented here in reversing a computational core, namely, Basic Linear Algebra Subprograms, which is widely used in scientific applications. A new Reversible BLAS (RBLAS) library interface has been designed, and a prototype has been implemented with two modes: (1) a memory-mode in which reversibility is obtained by checkpointing to memory in forward and restoring from memory in reverse, and (2) a computational-mode in which nothing is saved in the forward, but restoration is done entirely via inverse computation in reverse. The article is focused on detailed performance benchmarking to evaluate the runtime dynamics and performance effects, comparing reversible computation with checkpointing on both traditional CPU platforms and recent GPU accelerator platforms. For BLAS Level-1 subprograms, data indicates over an order of magnitude better speed of reversible computation compared to checkpointing. For BLAS Level-2 and Level-3, a more complex tradeoff is observed between reversible computation and checkpointing, depending on computational and memory complexities of the subprograms.

  20. Assessment of basic research needs for greenhouse gas control technologies

    SciTech Connect (OSTI)

    Benson, S.M.; Chandler, W.; Edmonds, J.; Houghton, J.; Levine, M.; Bates, L.; Chum, H.; Dooley, J.; Grether, D.; Logan, J.; Wiltsee, G.; Wright, L.

    1998-09-01

    This paper is an outgrowth of an effort undertaken by the Department of Energy's Office of Energy Research to assess the fundamental research needs to support a national program in carbon management. Five topics were identified as areas where carbon management strategies and technologies might be developed: (1) capture of carbon dioxide, decarbonization strategies, and carbon dioxide disposal and utilization; (2) hydrogen development and fuel cells; (3) enhancement of the natural carbon cycle; (4) biomass production and utilization; and (5) improvement of the efficiency of energy production, conversion, and utilization. Within each of these general areas, experts came together to identify targets of opportunity for fundamental research likely to lead to the development of mid- to long-term solutions for stabilizing or decreasing carbon dioxide and other greenhouse gases in the atmosphere. Basic research to support the options outlined above are far reaching-from understanding natural global processes such as the ocean and terrestrial carbon cycles to development of new materials and concepts for chemical separation. Examples of fundamental research needs are described in this paper.

  1. Basic SCADA systems - from the sensors to the screen

    SciTech Connect (OSTI)

    Merlie, B.

    1995-12-01

    Supervisory Control and Data Acquisition (SCADA) Systems are specialized control systems used to monitor and control facilities which are geographically dispersed. They are commonly used in the gas, oil, electric, and water transmission and distribution industries. SCADA systems differ from other control systems in that they make extensive use of remote communications and are more tolerant to outages of the communications network than a typical control system installation in a plant environment. A basic SCADA system can be broken into five functional parts. These are: (1) Sensors and Actuators; (2) Remote Terminal Units (RTUs); (3) Communications Facilities; (4) Host Computer Systems; and (5) User Interfaces While the fundamental concepts of SCADA systems have changed little in the past 20 years, more sophisticated hardware and software has altered some of the traditional paradigms associated with these control systems. This is particularly true with respect to RTUs, host computer systems, and user interfaces. While this paper will focus on the fundamentals, it will attempt to provide the reader with current trends in the industry where applicable.

  2. Basic Studies of Non-Diffusive Transport in Plasmas

    SciTech Connect (OSTI)

    Morales, George J.; Maggs, James E.

    2014-10-25

    The project expanded and developed mathematical descriptions, and corresponding numerical modeling, of non-diffusive transport to incorporate new perspectives derived from basic transport experiments performed in the LAPD device at UCLA, and at fusion devices throughout the world. By non-diffusive it is meant that the transport of fundamental macroscopic parameters of a system, such as temperature and density, does not follow the standard diffusive behavior predicted by a classical Fokker-Planck equation. The appearance of non-diffusive behavior is often related to underlying microscopic processes that cause the value of a system parameter, at one spatial position, to be linked to distant events, i.e., non-locality. In the LAPD experiments the underlying process was traced to large amplitude, coherent drift-waves that give rise to chaotic trajectories. Significant advances were made in this project. The results have lead to a new perspective about the fundamentals of edge transport in magnetically confined plasmas; the insight has important consequences for worldwide studies in fusion devices. Progress was also made in advancing the mathematical techniques used to describe fractional diffusion.

  3. Flammability of selected heat resistant alloys in oxygen gas mixtures

    SciTech Connect (OSTI)

    Zawierucha, R.; McIlroy, K.; Million, J.F.

    1995-12-31

    Within recent years, the use of oxygen has increased in applications where elevated temperatures and corrosion may be significant factors. In such situations, traditional alloys used in oxygen systems will not be adequate. Where alternative alloys must be utilized, based upon environmental requirements, it is essential that they may be characterized with respect to their ignition and combustion resistance in oxygen. Promoted ignition and promoted ignition-combustion are terms which have been used to describe a situation where a substance with low oxygen supports the combustion of a compatibility ignites and more ignition resistant material. In this paper, data will be presented on the promoted ignition-combustion behavior of selected heat resistant engineering alloys that may be considered for gaseous oxygen applications in severe environments. In this investigation, alloys have been evaluated via both flowing and static (fixed volume) approaches using a rod configuration. Oxygen-nitrogen gas mixtures with compositions ranging from approximately 40 to 99.7% oxygen at pressures of 3.55 to 34.6 MPa were used in the comparative studies.

  4. Basic research needs to assure a secure energy future. A report from the Basic Energy Sciences Advisory Committee

    SciTech Connect (OSTI)

    2003-02-01

    This report has highlighted many of the possible fundamental research areas that will help our country avoid a future energy crisis. The report may not have adequately captured the atmosphere of concern that permeated the discussions at the workshop. The difficulties facing our nation and the world in meeting our energy needs over the next several decades are very challenging. It was generally felt that traditional solutions and approaches will not solve the total energy problem. Knowledge that does not exist must be obtained to address both the quantity of energy needed to increase the standard of living world-wide and the quality of energy generation needed to preserve the environment. In terms of investments, it was clear that there is no single research area that will secure the future energy supply. A diverse range of economic energy sources will be required--and a broad range of fundamental research is needed to enable these. Many of the issues fall into the traditional materials and chemical sciences research areas, but with specific emphasis on understanding mechanisms, energy related phenomena, and pursuing novel directions in, for example, nanoscience and integrated modeling. An important result from the discussions, which is hopefully apparent from the brief presentations above, is that the problems that must be dealt with are truly multidisciplinary. This means that they require the participation of investigators with different skill sets. Basic science skills have to be complemented by awareness of the overall nature of the problem in a national and world context, and with knowledge of the engineering, design, and control issues in any eventual solution. It is necessary to find ways in which this can be done while still preserving the ability to do first-class basic science. The traditional structure of research, with specific disciplinary groupings, will not be sufficient. This presents great challenges and opportunities for the funders of the research that must be done. For example, the applied research programs in the DOE need a greater awareness of the user facilities and an understanding of how to use them to solve their unique problems. The discussions reinforced what all of the participants already knew: the issue of energy security is of major importance both for the U.S. and for the world. Furthermore, it is clear that major changes in the primary energy sources, in energy conversion, and in energy use, must be achieved within the next fifty years. This time scale is determined by two drivers: increasing world population and increasing expectations of that population. Much of the research and development currently being done are concerned with incremental improvements in what has been done in the immediate past; and it is necessary to take this path because improvements will be needed across the board. These advances extend the period before the radical changes have to be made; however, they will not solve the underlying, long-range problem. The Subpanel recommends that a major program be funded to conduct a multidisciplinary research program to address the issues to ensure a secure energy future for the U.S. It is necessary to recognize that this program must be ensured of a long-term stability. It is also necessary that a management and funding structure appropriate for such an approach be developed. The Department of Energy's Office of Basic Energy Sciences is well positioned to support this initiative by enhancement of their already world-class scientific research programs and user facilities.

  5. Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms

    DOE Patents [OSTI]

    Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  6. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  7. Solid phases of spatially nanoconfined oxygen: A neutron scattering study

    SciTech Connect (OSTI)

    Kojda, Danny [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany) [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany); Freie Universitt Berlin, 14195 Berlin (Germany); Wallacher, Dirk; Hofmann, Tommy, E-mail: tommy.hofmann@helmholtz-berlin.de [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany)] [Helmholtz-Zentrum Berlin fr Materialien und Energie GmbH, 14109 Berlin (Germany); Baudoin, Simon; Hansen, Thomas [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France)] [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France); Huber, Patrick [Technische Universitt Hamburg-Harburg, 21073 Hamburg (Germany)] [Technische Universitt Hamburg-Harburg, 21073 Hamburg (Germany)

    2014-01-14

    We present a comprehensive neutron scattering study on solid oxygen spatially confined in 12 nm wide alumina nanochannels. Elastic scattering experiments reveal a structural phase sequence known from bulk oxygen. With decreasing temperature cubic ?-, orthorhombic ?- and monoclinic ?-phases are unambiguously identified in confinement. Weak antiferromagnetic ordering is observed in the confined monoclinic ?-phase. Rocking scans reveal that oxygen nanocrystals inside the tubular channels do not form an isotropic powder. Rather, they exhibit preferred orientations depending on thermal history and the very mechanisms, which guide the structural transitions.

  8. Hydrogen production using hydrogenase-containing oxygenic photosynthetic organisms

    DOE Patents [OSTI]

    Melis, Anastasios; Zhang, Liping; Benemann, John R.; Forestier, Marc; Ghirardi, Maria; Seibert, Michael

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  9. Probing oxygen vacancy concentration and homogeneity in solid-oxide

    Office of Scientific and Technical Information (OSTI)

    fuel-cell cathode materials on the subunit-cell level (Journal Article) | SciTech Connect Probing oxygen vacancy concentration and homogeneity in solid-oxide fuel-cell cathode materials on the subunit-cell level Citation Details In-Document Search Title: Probing oxygen vacancy concentration and homogeneity in solid-oxide fuel-cell cathode materials on the subunit-cell level Oxygen vacancy distributions and dynamics directly control the operation of solid-oxide fuel cells and are

  10. Boron nitride nanosheets as oxygen-atom corrosion protective coatings

    SciTech Connect (OSTI)

    Yi, Min; Shen, Zhigang; Zhao, Xiaohu; Liang, Shuaishuai; Liu, Lei

    2014-04-07

    The research of two-dimensional nanomaterials for anticorrosion applications is just recently burgeoning. Herein, we demonstrate the boron nitride nanosheets (BNNSs) coatings for protecting polymer from oxygen-atom corrosion. High-quality BNNSs, which are produced by an effective fluid dynamics method with multiple exfoliation mechanisms, can be assembled into coatings with controlled thickness by vacuum filtration. After exposed in atom oxygen, the naked polymer is severely corroded with remarkable mass loss, while the BNNSs-coated polymer remains intact. Barrier and bonding effects of the BNNSs are responsible for the coating's protective performance. These preliminary yet reproducible results pave a way for resisting oxygen-atom corrosion.

  11. Optical Basicity and Nepheline Crystallization in High Alumina Glasses

    SciTech Connect (OSTI)

    Rodriguez, Carmen P.; McCloy, John S.; Schweiger, M. J.; Crum, Jarrod V.; Winschell, Abigail E.

    2011-02-25

    The purpose of this study was to find compositions that increase waste loading of high-alumina wastes beyond what is currently acceptable while avoiding crystallization of nepheline (NaAlSiO4) on slow cooling. Nepheline crystallization has been shown to have a large impact on the chemical durability of high-level waste glasses. It was hypothesized that there would be some composition regions where high-alumina would not result in nepheline crystal production, compositions not currently allowed by the nepheline discriminator. Optical basicity (OB) and the nepheline discriminator (ND) are two ways of describing a given complex glass composition. This report presents the theoretical and experimental basis for these models. They are being studied together in a quadrant system as metrics to explore nepheline crystallization and chemical durability as a function of waste glass composition. These metrics were calculated for glasses with existing data and also for theoretical glasses to explore nepheline formation in Quadrant IV (passes OB metric but fails ND metric), where glasses are presumed to have good chemical durability. Several of these compositions were chosen, and glasses were made to fill poorly represented regions in Quadrant IV. To evaluate nepheline formation and chemical durability of these glasses, quantitative X-ray diffraction (XRD) analysis and the Product Consistency Test were conducted. A large amount of quantitative XRD data is collected here, both from new glasses and from glasses of previous studies that had not previously performed quantitative XRD on the phase assemblage. Appendix A critically discusses a large dataset to be considered for future quantitative studies on nepheline formation in glass. Appendix B provides a theoretical justification for choice of the oxide coefficients used to compute the OB criterion for nepheline formation.

  12. Basic Science Research to Support the Nuclear Materials Focus Area

    SciTech Connect (OSTI)

    Chipman, N. A.; Castle, P. M.; Boak, J. M.; Eller, P. G.

    2002-02-26

    The Department of Energy's (DOE's) Office of Environmental Management (EM) is responsible for managing more than 760,000 metric tons of nuclear material that is excess to the current DOE weapons program, as a result of shutdown of elements of the weapons program, mainly during the 1990s. EMowned excess nuclear material comprises a variety of material types, including uranium, plutonium, other actinides and other radioactive elements in numerous forms, all of which must be stabilized for storage and ultimate disposition. Much of this quantity has been in storage for many years. Shutdown of DOE sites and facilities requires removal of nuclear material and consolidation at other sites, and may be delayed by the lack of available technology. Within EM, the Office of Science and Technology (OST) is dedicated to providing timely, relevant technology to accelerate completion and reduce cleanup cost of the DOE environmental legacy. OST is organized around five focus areas, addressing crucial areas of end-user-defined technology need. The Focus Areas regularly identify potential technical solutions for which basic scientific research is needed to determine if the technical solution can be developed and deployed. To achieve a portfolio of projects that is balanced between near-term priorities driven by programmatic risks (such as site closure milestones) and long-term, high-consequence needs that depend on extensive research and development, OST has established the Environmental Management Science Program (EMSP) to develop the scientific basis for solutions to long-term site needs. The EMSP directs calls for proposals to address scientific needs of the focus areas. Needs are identified and validated annually by individual sites in workshops conducted across the complex. The process captures scope and schedule requirements of the sites, so that focus areas can identify technology that can be delivered to sites in time to complete site cleanup. The Nuclear Material Focus Area (NMFA) has identified over two hundred science and technology needs, of which more than thirty are science needs.

  13. Basic science research to support the nuclear material focus area

    SciTech Connect (OSTI)

    Boak, J. M.; Eller, P. Gary; Chipman, N. A.; Castle, P. M.

    2002-01-01

    The Department of Energy's (DOE'S) Office of Environmental Management (EM) is responsible for managing more than 760,000 metric tons of nuclear material that is excess to the current DOE weapons program, as a result of shutdown of elements of the weapons program, mainly during the 1990s. EMowned excess nuclear material comprises a variety of material types, including uranium, plutonium, other actinides and other radioactive elements in numerous forms, all of which must be stabilized for storage and ultimate disposition. Much of this quantity has been in storage for many years. Shutdown of DOE sites and facilities requires removal of nuclear material and consolidation at other sites, and may be delayed by the lack of available technology. Within EM, the Office of Science and Technology (OST) is dedicated to providing timely, relevant technology to accelerate completion and reduce cleanup cost of the DOE environmental legacy. OST is organized around five focus areas, addressing crucial areas of end-user-defined technology need. The Focus Areas regularly identify potential technical solutions for which basic scientific research is needed to determine if the technical solution can be developed and deployed. To achieve a portfolio of projects that is balanced between near-term priorities driven by programmatic risks (such as site closure milestones) and long-term, high-consequence needs that depend on extensive research and development, OST has established the Environmental Management Science Program (EMSP) to develop the scientific basis for solutions to long-term site needs. The EMSP directs calls for proposals to address scientific needs of the focus areas. Needs are identified and validated annually by individual sites in workshops conducted across the complex. The process captures scope and schedule requirements of the sites, so that focus areas can identify technology that can be delivered to sites in time to complete site cleanup. The Nuclear Material Focus Area (NMFA) has identified over two hundred science and technology needs, of which more than thirty are science needs.

  14. Oxygen enriched combustion system performance study. Phase 2: 100 percent oxygen enriched combustion in regenerative glass melters, Final report

    SciTech Connect (OSTI)

    Tuson, G.B.; Kobayashi, H.; Campbell, M.J.

    1994-08-01

    The field test project described in this report was conducted to evaluate the energy and environmental performance of 100% oxygen enriched combustion (100% OEC) in regenerative glass melters. Additional objectives were to determine other impacts of 100% OEC on melter operation and glass quality, and to verify on a commercial scale that an on-site Pressure Swing Adsorption oxygen plant can reliably supply oxygen for glass melting with low electrical power consumption. The tests constituted Phase 2 of a cooperative project between the United States Department of Energy, and Praxair, Inc. Phase 1 of the project involved market and technical feasibility assessments of oxygen enriched combustion for a range of high temperature industrial heating applications. An assessment of oxygen supply options for these applications was also performed during Phase 1, which included performance evaluation of a pilot scale 1 ton per day PSA oxygen plant. Two regenerative container glass melters were converted to 100% OEC operation and served as host sites for Phase 2. A 75 ton per day end-fired melter at Carr-Lowrey Glass Company in Baltimore, Maryland, was temporarily converted to 100% OEC in mid- 1990. A 350 tpd cross-fired melter at Gallo Glass Company in Modesto, California was rebuilt for permanent commercial operation with 100% OEC in mid-1991. Initially, both of these melters were supplied with oxygen from liquid storage. Subsequently, in late 1992, a Pressure Swing Adsorption oxygen plant was installed at Gallo to supply oxygen for 100% OEC glass melting. The particular PSA plant design used at Gallo achieves maximum efficiency by cycling the adsorbent beds between pressurized and evacuated states, and is therefore referred to as a Vacuum/Pressure Swing Adsorption (VPSA) plant.

  15. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor

    Broader source: Energy.gov [DOE]

    Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

  16. Vehicle Technologies Office Merit Review 2015: Intake Air Oxygen Sensor

    Broader source: Energy.gov [DOE]

    Presentation given by Robert Bosch at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensor.

  17. Hybrid membrane--PSA system for separating oxygen from air

    DOE Patents [OSTI]

    Staiger, Chad L.; Vaughn, Mark R.; Miller, A. Keith; Cornelius, Christopher J.

    2011-01-25

    A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

  18. An Oxygen Isotope Study Of Silicates In The Larderello Geothermal...

    Open Energy Info (EERE)

    Silicates In The Larderello Geothermal Field, Italy Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: An Oxygen Isotope Study Of Silicates In The...

  19. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Armstrong, M R; Zaug, J M; Grant, C D; Crowhurst, J C; Bastea, S 75...

  20. COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION...

    Office of Scientific and Technical Information (OSTI)

    COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION OF sup 26Al BY A NEARBY SUPERNOVA Citation Details In-Document Search Title: COLLATERAL EFFECTS ON SOLAR ...

  1. In-situ generation of oxygen-releasing metal peroxides

    DOE Patents [OSTI]

    Looney, Brian B.; Denham, Miles E.

    2007-01-09

    A method for remediation of contaminants in soil and groundwater is disclosed. The method generates oxygen releasing solids in groundwater or soil by injecting an aqueous energetic oxidant solution containing free radicals, oxidative conditions can be created within or ahead of a contaminant plume. Some contaminants may be remediated directly by reaction with the free radicals. Additionally and more importantly, the free radicals create an oxidative condition whereby native or injected materials, especially metals, are converted to peroxides. These peroxides provide a long-term oxygen reservoir, releasing oxygen relatively slowly over time. The oxygen can enhance microbial metabolism to remediate contaminants, can react with contaminant metals either to form immobile precipitants or to mobilize other metals to permit remediation through leaching techniques. Various injection strategies for injecting the energetic oxidant solution are also disclosed.

  2. Enhancing SNCR-aided combustion with oxygen addition

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Wu, Kuang Tsai; Bool, III, Lawrence E.

    2004-03-09

    NOx emissions from combustion are reduced, NOx reduction efficiency by SNCR is improved, and other efficiencies are realized, by injecting oxygen into a fuel-rich combustion zone under controlled conditions.

  3. Missing Oxygen Atoms Are Key to Robust Spintronic Material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Missing Oxygen Atoms Are Key to Robust Spintronic Material Missing Oxygen Atoms Are Key to Robust Spintronic Material Print Friday, 01 April 2016 11:44 The endless pursuit of faster, more energy-efficient computers has led to the emergence of the field of spintronics, where the manipulation and detection of electron spins are utilized in electronic circuits. A particular class of materials called dilute magnetic oxides are promising candidates for spintronics applications because they exhibit

  4. Ab Initio Calculations of Even Oxygen Isotopes with Chiral

    Office of Scientific and Technical Information (OSTI)

    Two-Plus-Three-Nucleon Interactions (Journal Article) | SciTech Connect Initio Calculations of Even Oxygen Isotopes with Chiral Two-Plus-Three-Nucleon Interactions Citation Details In-Document Search Title: Ab Initio Calculations of Even Oxygen Isotopes with Chiral Two-Plus-Three-Nucleon Interactions Authors: Hergert, H. ; Binder, S. ; Calci, A. ; Langhammer, J. ; Roth, R. Publication Date: 2013-06-10 OSTI Identifier: 1102833 Type: Publisher's Accepted Manuscript Journal Name: Physical

  5. Sulfur Resistant Electrodes for Zirconia Oxygen Sensors - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Sulfur Resistant Electrodes for Zirconia Oxygen Sensors Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing SummaryTerbium-Yttrium-zirconium oxide (Tb-YSZ) is high-temperature, sulfur-resistant material for manufacture of electrodes for oxygen (O2) sensors. The Tb-YSZ sensor is resistant to sulfur and other acidic compounds present in exhaust gases and offers increased lifetime, stability, and accuracy over O2 sensors on the market

  6. Oxygen enhanced switching to combustion of lower rank fuels

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.; Wu, Kuang Tsai

    2004-03-02

    A furnace that combusts fuel, such as coal, of a given minimum energy content to obtain a stated minimum amount of energy per unit of time is enabled to combust fuel having a lower energy content, while still obtaining at least the stated minimum energy generation rate, by replacing a small amount of the combustion air fed to the furnace by oxygen. The replacement of oxygen for combustion air also provides reduction in the generation of NOx.

  7. Method for making oxygen-reducing catalyst layers

    DOE Patents [OSTI]

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; O'Neill, David G.

    2010-06-22

    Methods are provided for making oxygen-reducing catalyst layers, which include simultaneous or sequential stops of physical vapor depositing an oxygen-reducing catalytic material onto a substrate, the catalytic material comprising a transition metal that is substantially free of platinum; and thermally treating the catalytic material. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  8. Oxygen-permeable ceramic membranes for gas separation

    SciTech Connect (OSTI)

    Balachandran, U.; Ma, B.; Maiya, P.S.; Dusek, J.T.; Mieville, R.L.; Picciolo, J.J.

    1998-02-01

    Mixed-conducting oxides have a wide range of applications, including fuel cells, gas separation systems, sensors, and electrocatalytic equipment. Dense ceramic membranes made of mixed-conducting oxides are particularly attractive for gas separation and methane conversion processes. Membranes made of Sr-Fe-Co oxide, which exhibits high combined electronic and oxygen ionic conductivities, can be used to selectively transport oxygen during the partial oxidation of methane to synthesis gas (syngas, i.e., CO + H{sub 2}). The authors have fabricated tubular Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes and tested them (some for more than 1,000 h) in a methane conversion reactor that was operating at 850--950 C. An oxygen permeation flux of {approx} 10 scc/cm{sup 2} {center_dot} min was obtained at 900 C in a tubular membrane with a wall thickness of 0.75 mm. Using a gas-tight electrochemical cell, the authors have also measured the steady-state oxygen permeability of flat Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes as a function of temperature and oxygen partial pressure(pO{sub 2}). Steady-state oxygen permeability increases with increasing temperature and with the difference in pO{sub 2} on the two sides of the membrane. At 900 C, an oxygen permeability of {approx} 2.5 scc/cm{sup 2} {center_dot} min was obtained in a 2.9-mm-thick membrane. This value agrees with that obtained in methane conversion reactor experiments. Current-voltage (I-V) characteristics determined in the gas-tight cell indicate that bulk effect, rather than surface exchange effect, is the main limiting factor for oxygen permeation of {approx} 1-mm-thick Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes at elevated temperatures (> 650 C).

  9. Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced

    Office of Scientific and Technical Information (OSTI)

    mixture of nitromethane and hydrogen peroxide (Conference) | SciTech Connect kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Authors: Armstrong, M R ; Zaug, J M ; Grant, C D ; Crowhurst, J C ; Bastea, S Publication Date: 2014-06-24 OSTI Identifier: 1149544 Report Number(s):

  10. Constitutive NF-?B activation and tumor-growth promotion by Romo1-mediated reactive oxygen species production

    SciTech Connect (OSTI)

    Chung, Jin Sil; Lee, Sora; Yoo, Young Do

    2014-08-08

    Highlights: Romo1 expression is required for constitutive nuclear DNA-binding activity of NF-?B. Romo1 depletion suppresses tumor growth in vivo. Romo1 presents a potential therapeutic target for diseases. - Abstract: Deregulation of nuclear factor-?B (NF-?B) and related pathways contribute to tumor cell proliferation and invasion. Mechanisms for constitutive NF-?B activation are not fully explained; however, the underlying defects appear to generate and maintain pro-oxidative conditions. In hepatocellular carcinoma (HCC) tissues, up-regulation of reactive oxygen species modulator 1 (Romo1) correlates positively with tumor size. In the present study, we showed that Romo1 expression is required to maintain constitutive nuclear DNA-binding activity of NF-?B and transcriptional activity through constitutive I?B? phosphorylation. Overexpression of Romo1 promoted p65 nuclear translocation and DNA-binding activity. We also show that Romo1 depletion suppressed anchorage-independent colony formation by HCC cells and suppressed tumor growth in vivo. Based on these findings, Romo1 may be a principal regulatory factor in the maintenance of constitutive NF-?B activation in tumor cells. In the interest of anti-proliferative treatments for cancer, Romo1 may also present a productive target for drug development.

  11. Basic Physics of Tokamak Transport Final Technical Report.

    SciTech Connect (OSTI)

    Sen, Amiya K.

    2014-05-12

    The goal of this grant has been to study the basic physics of various sources of anomalous transport in tokamaks. Anomalous transport in tokamaks continues to be one of the major problems in magnetic fusion research. As a tokamak is not a physics device by design, direct experimental observation and identification of the instabilities responsible for transport, as well as physics studies of the transport in tokamaks, have been difficult and of limited value. It is noted that direct experimental observation, identification and physics study of microinstabilities including ITG, ETG, and trapped electron/ion modes in tokamaks has been very difficult and nearly impossible. The primary reasons are co-existence of many instabilities, their broadband fluctuation spectra, lack of flexibility for parameter scans and absence of good local diagnostics. This has motivated us to study the suspected tokamak instabilities and their transport consequences in a simpler, steady state Columbia Linear Machine (CLM) with collisionless plasma and the flexibility of wide parameter variations. Earlier work as part of this grant was focused on both ITG turbulence, widely believed to be a primary source of ion thermal transport in tokamaks, and the effects of isotope scaling on transport levels. Prior work from our research team has produced and definitively identified both the slab and toroidal branches of this instability and determined the physics criteria for their existence. All the experimentally observed linear physics corroborate well with theoretical predictions. However, one of the large areas of research dealt with turbulent transport results that indicate some significant differences between our experimental results and most theoretical predictions. Latter years of this proposal were focused on anomalous electron transport with a special focus on ETG. There are several advanced tokamak scenarios with internal transport barriers (ITB), when the ion transport is reduced to neoclassical values by combined mechanisms of ExB and diamagnetic flow shear suppression of the ion temperature gradient (ITG) instabilities. However, even when the ion transport is strongly suppressed, the electron transport remains highly anomalous. The most plausible physics scenario for the anomalous electron transport is based on electron temperature gradient (ETG) instabilities. This instability is an electron analog of and nearly isomorphic to the ITG instability, which we had studied before extensively. However, this isomorphism is broken nonlinearily. It is noted that as the typical ETG mode growth rates are larger (in contrast to ITG modes) than ExB shearing rates in usual tokamaks, the flow shear suppression of ETG modes is highly unlikely. This motivated a broader range of investigations of other physics scenarios of nonlinear saturation and transport scaling of ETG modes.

  12. Interaction of light with the ZnO surface: Photon induced oxygen breathing, oxygen vacancies, persistent photoconductivity, and persistent photovoltage

    SciTech Connect (OSTI)

    Gurwitz, Ron; Cohen, Rotem; Shalish, Ilan

    2014-01-21

    ZnO surfaces adsorb oxygen in the dark and emit CO{sub 2} when exposed to white light, reminiscent of the lungs of living creatures. We find that this exchange of oxygen with the ambient affects the integrity of the ZnO surface. Thus, it forms a basis for several interesting surface phenomena in ZnO, such as photoconductivity, photovoltage, and gas sensing, and has a role in ZnO electrical conduction. Using x-ray photoelectron spectroscopy on ZnO nanowires, we observed a decomposition of ZnO under white light and formation of oxygen-depleted surface, which explains photoconductivity by the electron donation of oxygen vacancies. Our findings suggest that the observed decomposition of the ZnO lattice may only take place due to photon-induced reduction of ZnO by carbon containing molecules (or carbo-photonic reduction), possibly from the ambient gas, accounting in a consistent way for both the reduced demands on the energy required for decomposition and for the observed emission of lattice oxygen in the form of CO{sub 2}. The formation of oxygen-vacancy rich surface is suggested to induce surface delta doping, causing accumulation of electrons at the surface, which accounts for both the increase in conductivity and the flattening of the energy bands. Using surface photovoltage spectroscopy in ultra high vacuum, we monitored changes in the deep level spectrum. We observe a wide optical transition from a deep acceptor to the conduction band, which energy position coincides with the position of the so called green luminescence in ZnO. This green transition disappears with the formation of surface oxygen vacancies. Since the oxygen vacancies are donors, while the green transition involves surface acceptors, the results suggest that the initial emission of oxygen originates at the defect sites of the latter, thereby eliminating each other. This suggests that the green transition originates at surface Zn vacancy acceptors. Removing an oxygen atom from a Zn vacancy completes the vacancy to become a full ZnO molecule vacancy, which does not produce deep levels. Our results explain why ZnO finds use as an electrical detector for oxygen and for carbon containing gas molecules. They may also shed new light on photocatalytic uses of ZnO. It is suggested that similar surface phenomena may affect other semiconducting oxides.

  13. Basic Energy Sciences Advisory Committee (BESAC) Homepage | U.S. DOE Office

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Science (SC) BESAC Home Basic Energy Sciences Advisory Committee (BESAC) BESAC Home Meetings BESAC 2016-2017 Membership Charges/Reports Charter .pdf file (128KB) BES Committees of Visitors Federal Advisory Committees BES Home Print Text Size: A A A FeedbackShare Page The Basic Energy Sciences Advisory Committee (BESAC) - established on September 4, 1986 - provides valuable, independent advice to the Department of Energy on the Basic Energy Sciences program regarding the complex scientific

  14. KineticsFinal Report Cover Page Bakajin, O 59 BASIC BIOLOGICAL...

    Office of Scientific and Technical Information (OSTI)

    KineticsFinal Report Cover Page Bakajin, O 59 BASIC BIOLOGICAL SCIENCES; 42 ENGINEERING; CONSUMPTION RATES; DEAD TIME; DETECTION; DIFFUSION; DNA; ENERGY TRANSFER; FABRICATION;...

  15. Chapter 5: Basic Concepts for Clean Energy Unsecured Lending and Loan Loss Reserve Funds

    Broader source: Energy.gov [DOE]

    Clean Energy Finance Guide, Third Edition, December 9, 2010, Chapter 5: Basic Concepts for Clean Energy Unsecured Lending and Loan Loss Reserve Funds.

  16. Natural Ores as Oxygen Carriers in Chemical Looping Combustion

    SciTech Connect (OSTI)

    Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

    2013-08-01

    Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

  17. High fidelity modeling of thermal relaxation and dissociation of oxygen

    SciTech Connect (OSTI)

    Andrienko, Daniil A. Boyd, Iain D.

    2015-11-15

    A master equation study of vibrational relaxation and dissociation of oxygen is conducted using state-specific O{sub 2}–O transition rates, generated by extensive trajectory simulations. Both O{sub 2}–O and O{sub 2}–O{sub 2} collisions are concurrently simulated in the evolving nonequilibrium gas system under constant heat bath conditions. The forced harmonic oscillator model is incorporated to simulate the state-to-state relaxation of oxygen in O{sub 2}–O{sub 2} collisions. The system of master equations is solved to simulate heating and cooling flows. The present study demonstrates the importance of atom-diatom collisions due to the extremely efficient energy randomization in the intermediate O{sub 3} complex. It is shown that the presence of atomic oxygen has a significant impact on vibrational relaxation time at temperatures observed in hypersonic flow. The population of highly-excited O{sub 2} vibrational states is affected by the amount of atomic oxygen when modeling the relaxation under constant heat bath conditions. A model of coupled state-to-state vibrational relaxation and dissociation of oxygen is also discussed.

  18. Surface control of epitaxial manganite films via oxygen pressure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tselev, Alexander; Vasudevan, Rama K.; Gianfrancesco, Anthony G.; Qiao, Liang; Ganesh, Panchapakesan; Meyer, Tricia L.; Lee, Ho Nyung; Biegalski, Michael D.; Baddorf, Arthur P.; Kalinin, Sergei

    2015-03-11

    The trend to reduce device dimensions demands increasing attention to atomic-scale details of structure of thin films as well as to pathways to control it. We found that this is of special importance in the systems with multiple competing interactions. We have used in situ scanning tunneling microscopy to image surfaces of La5/8Ca3/8MnO3 films grown by pulsed laser deposition. The atomically resolved imaging was combined with in situ angle-resolved X-ray photoelectron spectroscopy. We find a strong effect of the background oxygen pressure during deposition on structural and chemical features of the film surface. Deposition at 50 mTorr of O2 leadsmore » to mixed-terminated film surfaces, with B-site (MnO2) termination being structurally imperfect at the atomic scale. Moreover, a relatively small reduction of the oxygen pressure to 20 mTorr results in a dramatic change of the surface structure leading to a nearly perfectly ordered B-site terminated surface with only a small fraction of A-site (La,Ca)O termination. This is accompanied, however, by surface roughening at a mesoscopic length scale. The results suggest that oxygen has a strong link to the adatom mobility during growth. The effect of the oxygen pressure on dopant surface segregation is also pronounced: Ca surface segregation is decreased with oxygen pressure reduction.« less

  19. Evaluation of the effect of organic pro-degradant concentration in polypropylene exposed to the natural ageing

    SciTech Connect (OSTI)

    Montagna, L. S. E-mail: andrecatto@terra.com.br E-mail: mmcforte@hotmail.com Catto, A. L. E-mail: andrecatto@terra.com.br E-mail: mmcforte@hotmail.com Rossini, K. E-mail: andrecatto@terra.com.br E-mail: mmcforte@hotmail.com Forte, M. M. C. E-mail: andrecatto@terra.com.br E-mail: mmcforte@hotmail.com Santana, R. M. C. E-mail: andrecatto@terra.com.br E-mail: mmcforte@hotmail.com

    2014-05-15

    The production and consumption of plastics in the last decade has recorded a remarkable increase in the scientific and industrial interest in environmentally degradable polymer (EDPs). Polymers wastes are deposited improperly, such as dumps, landfills, rivers and seas, causing a serious problem by the accumulation in the environment. The abiotic processes, like the photodegradation, are the most efficient occurring in the open environmental, where the polymers undergo degradation from the action of sunlight that result from direct exposure to solar radiation, however depend of the type of chemical ageing, which is the principal component of climatic ageing. The subject of this work is to study the influence of concentration of organic pro-degradant (1, 2 and 3 % w/w) in the polypropylene (PP) exposed in natural ageing. PP samples with and without the additive were processed in plates square form, obtained by thermal compression molding (TCM) using a press at 200C under 2 tons for 5 min, and then were exposed at natural ageing during 120 days. The presence of organic additive influenced on PP degradability, this fact was assessed by changes in the thermal and morphology properties of the samples after 120 days of natural ageing. Scanning Electronic Microscopy (SEM) results of the morphological surface of the modified PP samples showed greater degradation photochemical oxidative when compared to neat PP, due to increase of rugosity and formation of microvoids. PP samples with different pro-degradant concentration under natural ageing presented a degree of crystallinity, obtained by Differential Scanning Calorimeter (DSC) increases in comparing the neat PP.

  20. C.R.S. 37-92-102 - Basic Tenets of Colorado Water Law | Open...

    Open Energy Info (EERE)

    C.R.S. 37-92-102 - Basic Tenets of Colorado Water Law Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: C.R.S. 37-92-102 - Basic...