National Library of Energy BETA

Sample records for baseload nitrate salt

  1. Baseload Nitrate Salt Central Receiver Power Plant Design Final Report

    SciTech Connect (OSTI)

    Tilley, Drake; Kelly, Bruce; Burkholder, Frank

    2014-12-12

    The objectives of the work were to demonstrate that a 100 MWe central receiver plant, using nitrate salt as the receiver coolant, thermal storage medium, and heat transport fluid in the steam generator, can 1) operate, at full load, for 6,400 hours each year using only solar energy, and 2) satisfy the DOE levelized energy cost goal of $0.09/kWhe (real 2009 $). To achieve these objectives the work incorporated a large range of tasks relating to many different aspects of a molten salt tower plant. The first Phase of the project focused on developing a baseline design for a Molten Salt Tower and validating areas for improvement. Tasks included a market study, receiver design, heat exchanger design, preliminary heliostat design, solar field optimization, baseline system design including PFDs and P&IDs and detailed cost estimate. The baseline plant met the initial goal of less than $0.14/kWhe, and reinforced the need to reduce costs in several key areas to reach the overall $0.09/kWhe goal. The major improvements identified from Phase I were: 1) higher temperature salt to improve cycle efficiency and reduce storage requirements, 2) an improved receiver coating to increase the efficiency of the receiver, 3) a large receiver design to maximize storage and meet the baseload hours objective, and 4) lower cost heliostat field. The second Phase of the project looked at advancing the baseline tower with the identified improvements and included key prototypes. To validate increasing the standard solar salt temperature to 600 °C a dynamic test was conducted at Sandia. The results ultimately proved the hypothesis incorrect and showed high oxide production and corrosion rates. The results lead to further testing of systems to mitigate the oxide production to be able to increase the salt temperature for a commercial plant. Foster Wheeler worked on the receiver design in both Phase I and Phase II looking at both design and lowering costs utilizing commercial fossil boiler manufacturing. The cost and design goals for the project were met with this task, but the most interesting results had to do with defining the failure modes and looking at a “shakedown analysis” of the combined creep-fatigue failure. A separate task also looked at improving the absorber coatings on the receiver tubes that would improve the efficiency of the receiver. Significant progress was made on developing a novel paint with a high absorptivity that was on par with the current Pyromark, but shows additional potential to be optimized further. Although the coating did not meet the emissivity goals, preliminary testing the new paint shows potential to be much more durable, and potential to improve the receiver efficiency through a higher average absorptivity over the lifetime. Additional coatings were also designed and modeled results meet the project goals, but were not tested. Testing for low cycle fatigue of the full length receiver tubes was designed and constructed, but is still currently undergoing testing. A novel small heliostat was developed through an extensive brainstorming and down select. The concept was then detailed further with inputs from component testing and eventually a full prototype was built and tested. This task met or exceeded the accuracy and structure goals and also beat the cost goal. This provides a significant solar field costs savings for Abengoa that will be developed further to be used in future commercial plants. Ultimately the $0.09/kWhe (real 2009 $) and 6,400 hours goals of the project were met.

  2. Project Profile: Modular and Scalable Baseload Molten Salt Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility Project Profile: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility...

  3. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container...

    Broader source: Energy.gov (indexed) [DOE]

    LLC. The Order, at paragraph 22, requires the Permittees to submit a WIPP Nitrate Salt Bearing Waste Container Isolation Plan for identified nitrate salt bearing waste...

  4. Nitrate Salt Surrogate Blending Scoping Test Plan

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    Test blending equipment identified in the “Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing”. Determine if the equipment will provide adequate mixing of zeolite and surrogate salt/Swheat stream; optimize equipment type and operational sequencing; impact of baffles and inserts on mixing performance; and means of validating mixing performance

  5. Supplemental Cooling for Nitrate Salt Waste

    SciTech Connect (OSTI)

    Goldberg, Mitchell S.

    2015-08-19

    In July 2015, Los Alamos National Laboratory completed installation of a supplemental cooling system in the structure where remediated nitrate salt waste drums are stored. Although the waste currently is in a safe configuration and is monitored daily,controlling the temperature inside the structure adds another layer of protection for workers, the public,and the environment.This effort is among several layers of precautions designed to secure the waste.

  6. WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update May 12, 2015 Panel 6 and Panel 7, Room 7 a. Rollback * Contamination Assessment-This prerequisite is...

  7. Engineering Options Assessment Report. Nitrate Salt Waste Stream Processing

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    This report examines and assesses the available systems and facilities considered for carrying out remediation activities on remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The assessment includes a review of the waste streams consisting of 60 RNS, 29 above-ground UNS, and 79 candidate below-ground UNS containers that may need remediation. The waste stream characteristics were examined along with the proposed treatment options identified in the Options Assessment Report . Two primary approaches were identified in the five candidate treatment options discussed in the Options Assessment Report: zeolite blending and cementation. Systems that could be used at LANL were examined for housing processing operations to remediate the RNS and UNS containers and for their viability to provide repackaging support for remaining LANL legacy waste.

  8. Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-18

    This report examines and assesses the available systems and facilities considered for carrying out remediation activities on remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The assessment includes a review of the waste streams consisting of 60 RNS, 29 aboveground UNS, and 79 candidate belowground UNS containers that may need remediation. The waste stream characteristics were examined along with the proposed treatment options identified in the Options Assessment Report . Two primary approaches were identified in the five candidate treatment options discussed in the Options Assessment Report: zeolite blending and cementation. Systems that could be used at LANL were examined for housing processing operations to remediate the RNS and UNS containers and for their viability to provide repackaging support for remaining LANL legacy waste.

  9. Low-melting point inorganic nitrate salt heat transfer fluid

    DOE Patents [OSTI]

    Bradshaw, Robert W. (Livermore, CA); Brosseau, Douglas A. (Albuquerque, NM)

    2009-09-15

    A low-melting point, heat transfer fluid made of a mixture of four inorganic nitrate salts: 9-18 wt % NaNO.sub.3, 40-52 wt % KNO.sub.3, 13-21 wt % LiNO.sub.3, and 20-27 wt % Ca(NO.sub.3).sub.2. These compositions can have liquidus temperatures less than 100 C; thermal stability limits greater than 500 C; and viscosity in the range of 5-6 cP at 300 C; and 2-3 cP at 400 C.

  10. Options assessment report: Treatment of nitrate salt waste at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Robinson, Bruce Alan; Stevens, Patrice Ann

    2015-09-16

    This report documents the methodology used to select a method of treatment for the remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The method selected should treat the containerized waste in a manner that renders the waste safe and suitable for transport and final disposal in the Waste Isolation Pilot Plant (WIPP) repository, under specifications listed in the WIPP Waste Acceptance Criteria (DOE/CBFO, 2013). LANL recognized that the results must be thoroughly vetted with the New Mexico Environment Department (NMED) and the a modification to the LANL Hazardous Waste Facility Permit is a necessary step before implementation of this or any treatment option. Likewise, facility readiness and safety basis approvals must be received from the Department of Energy (DOE). This report presents LANL's preferred option, and the documentation of the process for reaching the recommended treatment option for RNS and UNS waste, and is presented for consideration by NMED and DOE.

  11. Options Assessment Report: Treatment of Nitrate Salt Waste at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Robinson, Bruce Alan; Stevens, Patrice Ann

    2015-12-17

    This report documents the methodology used to select a method of treatment for the remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The method selected should treat the containerized waste in a manner that renders the waste safe and suitable for transport and final disposal in the Waste Isolation Pilot Plant (WIPP) repository, under specifications listed in the WIPP Waste Acceptance Criteria (DOE/CBFO, 2013). LANL recognizes that the results must be thoroughly vetted with the New Mexico Environment Department (NMED) and that a modification to the LANL Hazardous Waste Facility Permit is a necessary step before implementation of this or any treatment option. Likewise, facility readiness and safety basis approvals must be received from the Department of Energy (DOE). This report presents LANL’s preferred option, and the documentation of the process for reaching the recommended treatment option for RNS and UNS waste, and is presented for consideration by NMED and DOE.

  12. Materials corrosion of high temperature alloys immersed in 600C binary nitrate salt.

    SciTech Connect (OSTI)

    Kruizenga, Alan Michael; Gill, David Dennis; LaFord, Marianne Elizabeth

    2013-03-01

    Thirteen high temperature alloys were immersion tested in a 60/40 binary nitrate salt. Samples were interval tested up to 3000 hours at 600%C2%B0C with air as the ullage gas. Chemical analysis of the molten salt indicated lower nitrite concentrations present in the salt, as predicted by the equilibrium equation. Corrosion rates were generally low for all alloys. Corrosion products were identified using x-ray diffraction and electron microprobe analysis. Fe-Cr based alloys tended to form mixtures of sodium and iron oxides, while Fe-Ni/Cr alloys had similar corrosion products plus oxides of nickel and chromium. Nickel based alloys primarily formed NiO, with chromium oxides near the oxide/base alloy interface. In625 exhibited similar corrosion performance in relation to previous tests, lending confidence in comparisons between past and present experiments. HA230 exhibited internal oxidation that consisted of a nickel/chromium oxide. Alloys with significant aluminum alloying tended to exhibit superior performance, due formation of a thin alumina layer. Soluble corrosion products of chromium, molybdenum, and tungsten were also formed and are thought to be a significant factor in alloy performance.

  13. Polyethylene encapsulatin of nitrate salt wastes: Waste form stability, process scale-up, and economics

    SciTech Connect (OSTI)

    Kalb, P.D.; Heiser, J.H. III; Colombo, P.

    1991-07-01

    A polyethylene encapsulation system for treatment of low-level radioactive, hazardous, and mixed wastes has been developed at Brookhaven National Laboratory. Polyethylene has several advantages compared with conventional solidification/stabilization materials such as hydraulic cements. Waste can be encapsulated with greater efficiency and with better waste form performance than is possible with hydraulic cement. The properties of polyethylene relevant to its long-term durability in storage and disposal environments are reviewed. Response to specific potential failure mechanisms including biodegradation, radiation, chemical attack, flammability, environmental stress cracking, and photodegradation are examined. These data are supported by results from extensive waste form performance testing including compressive yield strength, water immersion, thermal cycling, leachability of radioactive and hazardous species, irradiation, biodegradation, and flammability. The bench-scale process has been successfully tested for application with a number of specific problem'' waste streams. Quality assurance and performance testing of the resulting waste form confirmed scale-up feasibility. Use of this system at Rocky Flats Plant can result in over 70% fewer drums processed and shipped for disposal, compared with optimal cement formulations. Based on the current Rocky Flats production of nitrate salt per year, polyethylene encapsulation can yield an estimated annual savings between $1.5 million and $2.7 million, compared with conventional hydraulic cement systems. 72 refs., 23 figs., 16 tabs.

  14. LPG-recovery processes for baseload LNG plants examined

    SciTech Connect (OSTI)

    Chiu, C.H.

    1997-11-24

    With demand on the rise, LPG produced from a baseload LNG plant becomes more attractive as a revenue-earning product similar to LNG. Efficient use of gas expanders in baseload LNG plants for LPG production therefore becomes more important. Several process variations for LPG recovery in baseload LNG plants are reviewed here. Exergy analysis (based on the Second Law of Thermodynamics) is applied to three cases to compare energy efficiency resulting from integration with the main liquefaction process. The paper discusses extraction in a baseload plant, extraction requirements, process recovery parameters, extraction process variations, and exergy analysis.

  15. The reactivity of cesium nickel ferrocyanide towards nitrate and nitrite salts

    SciTech Connect (OSTI)

    Burger, L.L.; Scheele, R.D.

    1991-09-01

    Beginning in late 1988, the Pacific Northwest Laboratory (PNL) began an experimental program at the request of Westinghouse Hanford Company (WHC) to investigate the effects of temperature on the oxidation reaction between synthetic nickel cesium ferrocyanide (FeCN) and nitrates and nitrites representative of materials present in some of the Hanford single-shell tanks (SSTs). After completing a preliminary series of experiments in 1988, the program was expanded to include five tasks to evaluate the effect of selected compositional and operational parameters on the reaction and explosion temperatures of FeCN and nitrate and/or nitrite mixtures. 10 refs., 4 figs., 6 tabs.

  16. Sandia Energy - Molten Nitrate Salt Initial Flow Testing is a Tremendous

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust, High-Throughput Analysis ofSampleLignin-Feasting MicrobeMesaAnalysisSuccess Nitrate

  17. Project Profile: Modular and Scalable Baseload Molten Salt Plant Conceptual

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrderNATIONALofDefine

  18. Non-sea-salt sulfate and nitrate in trade wind aerosols at Barbados: Evidence for long-range transport

    E-Print Network [OSTI]

    Savoie, Dennis L; Prospero, Joseph M; Saltzman, Eric S

    1989-01-01

    878, 1977. and Nitrate at Barbados Kendall, M. G. , and A.in the trade winds at Barbados' Impact of the Africanand J. in the and Nitrate at Barbados Savoie, D. L. , J. M.

  19. CSP Heat Integration for Baseload Renewable Energy Deployment

    Broader source: Energy.gov [DOE]

    In October 2013, DOE announced an award under the Concentrating Solar Power (CSP) Heat Integration for Baseload Renewable Energy Development (HIBRED) program to advance the state of the art in CSP hybrid plants, which incorporate thermal and or chemical energy from a CSP system into a fossil fueled power generation system, managed by the SunShot Initiative.

  20. Ferrocyanide Safety Project Dynamic X-Ray Diffraction studies of sodium nickel ferrocyanide reactions with equimolar nitrate/nitrite salts

    SciTech Connect (OSTI)

    Dodds, J.N. [Washington State Univ., Pullman, WA (United States). Dept. of Chemical Engineering]|[UNOCAL, Brea, CA (United States). Hartley Research Center

    1994-07-01

    Dynamic X-ray Diffraction (DXRD) has been to used to identify and quantify the solid state reactions that take place between sodium nickel ferrocyanide, Na{sub 2}NiFe(CN){sub 6}, and equimolar concentrations of sodium nitrate/nitrite, reactions of interest to the continued environmental safety of several large underground waste storage tanks at the Hanford site in eastern Washington. The results are supportive of previous work, which indicated that endothermic dehydration and melting of the nitrates take place before the occurrence of exothermic reactions that being about 300{degrees}C. The DXRD results show that a major reaction set at these temperatures is the occurrence of a series reaction that produces sodium cyanate, NaCNO, as an intermediate in a mildly exothermic first step. In the presence of gaseous oxygen, NaCNO subsequently reacts exothermally and at a faster rate to form metal oxides. Measurements of the rate of this reaction are used to estimate the heat release. Comparisons of this estimated heat release rate with heat transfer rates from a hypothetical ``hot spot`` show that, even in a worst-case scenario, the heat transfer rates are approximately eight times higher than the rate of energy release from the exothermic reactions.

  1. Supplying Baseload Power and Reducing Transmission Requirements by Interconnecting Wind Farms

    E-Print Network [OSTI]

    Supplying Baseload Power and Reducing Transmission Requirements by Interconnecting Wind Farms is not used to supply baseload electric power today. Interconnecting wind farms through the transmission grid farms are interconnected in an array, wind speed correlation among sites decreases and so does

  2. Flexible Coal: Evolution from Baseload to Peaking Plant (Brochure)

    SciTech Connect (OSTI)

    Cochran, J.; Lew, D.; Kumar, N.

    2013-12-01

    Twenty-first century power systems, with higher penetration levels of low-carbon energy, smart grids, and other emerging technologies, will favor resources that have low marginal costs and provide system flexibility (e.g., the ability to cycle on and off to follow changes in variable renewable energy plant output). Questions remain about both the fate of coal plants in this scenario and whether they can cost-effectively continue to operate if they cycle routinely. The experience from the CGS plant demonstrates that coal plants can become flexible resources. This flexibility - namely the ability to cycle on and off and run at lower output (below 40% of capacity) - requires limited hardware modifications but extensive modifications to operational practice. Cycling does damage the plant and impact its life expectancy compared to baseload operations. Nevertheless, strategic modifications, proactive inspections and training programs, among other operational changes to accommodate cycling, can minimize the extent of damage and optimize the cost of maintenance. CGS's cycling, but not necessarily the associated price tag, is replicable. Context - namely, power market opportunities and composition of the generation fleet - will help determine for other coal plants the optimal balance between the level of cycling-related forced outages and the level of capital investment required to minimize those outages. Replicating CGS's experience elsewhere will likely require a higher acceptance of forced outages than regulators and plant operators are accustomed to; however, an increase in strategic maintenance can minimize the impact on outage rates.

  3. Baseload Solar Power for California? Ammonia-based Solar Energy Storage Using Trough Concentrators

    E-Print Network [OSTI]

    Baseload Solar Power for California? Ammonia-based Solar Energy Storage Using Trough Concentrators.1. Storing Solar Energy with Ammonia H2 / N2 gas liquid NH3 Heat Exchangers Power Generation (Steam Cycle Concentrator (Dish or Trough) Figure 1--1 : An overview of ammonia-based solar energy storage. (Sourced from

  4. STANDARD OPERATING PROCEDURE HEAVY METAL SALTS (selected)

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    (s): ___________________________________________________ Chemical(s): heavy metal salts: acetates, chlorides, sulfates, nitrates, anhydrides, oxides, hydroxides, etc., of arsenic, cadmium, chromium, cobalt, lead, mercury, osmium, silver, and uranium. Specific

  5. Brayton-Cycle Baseload Power Tower CSP System

    SciTech Connect (OSTI)

    Anderson, Bruce

    2013-12-31

    The primary objectives of Phase 2 of this Project were: 1. Engineer, fabricate, and conduct preliminary testing on a low-pressure, air-heating solar receiver capable of powering a microturbine system to produce 300kWe while the sun is shining while simultaneously storing enough energy thermally to power the system for up to 13 hours thereafter. 2. Cycle-test a high-temperature super alloy, Haynes HR214, to determine its efficacy for the system’s high-temperature heat exchanger. 3. Engineer the thermal energy storage system This Phase 2 followed Wilson’s Phase 1, which primarily was an engineering feasibility study to determine a practical and innovative approach to a full Brayton-cycle system configuration that could meet DOE’s targets. Below is a summary table of the DOE targets with Wilson’s Phase 1 Project results. The results showed that a Brayton system with an innovative (low pressure) solar receiver with ~13 hours of dry (i.e., not phase change materials or molten salts but rather firebrick, stone, or ceramics) has the potential to meet or exceed DOE targets. Such systems would consist of pre-engineered, standardized, factory-produced modules to minimize on-site costs while driving down costs through mass production. System sizes most carefully analyzed were in the range of 300 kWe to 2 MWe. Such systems would also use off-the-shelf towers, blowers, piping, microturbine packages, and heliostats. Per DOE’s instructions, LCOEs are based on the elevation and DNI levels of Daggett, CA, for a 100 MWe power plant following 2 GWe of factory production of the various system components. Success criteria DOE targets Wilson system LCOE DOE’s gas price $6.75/MBtu 9 cents/kWh 7.7 cents/kWh LCOE Current gas price $4.71/MBtu NA 6.9 cents/kWh Capacity factor 75% (6500hr) 75-100% Solar fraction 85% (5585hr) >5585hr Receiver cost $170/kWe $50/kWe Thermal storage cost $20/kWhth $13/kWhth Heliostat cost $120/m2 $89.8/m2

  6. Evaluation of Composite Alumina Nanoparticle and Nitrate Eutectic Materials for use in Concentrating Solar Power Plants 

    E-Print Network [OSTI]

    Malik, Darren R.

    2010-07-14

    The focus of this research was to create and characterize high temperature alumina and nitrate salt eutectic nanofluids for use in thermal energy storage (TES) systems. The nitrate eutectic was originally used in the TES system demonstrated as part...

  7. Sulfur Based Thermochemical Heat Storage for Baseload Concentrated Solar Power Generation

    SciTech Connect (OSTI)

    wong, bunsen

    2014-11-20

    This project investigates the engineering and economic feasibility of supplying baseload power using a concentrating solar power (CSP) plant integrated with sulfur based thermochemical heat storage. The technology stores high temperature solar heat in the chemical bonds of elemental sulfur. Energy is recovered as high temperature heat upon sulfur combustion. Extensive developmental and design work associated with sulfur dioxide (SO2) disproportionation and sulfuric acid (H2SO4) decomposition chemical reactions used in this technology had been carried out in the two completed phases of this project. The feasibility and economics of the proposed concept was demonstrated and determined.

  8. Batteries using molten salt electrolyte

    DOE Patents [OSTI]

    Guidotti, Ronald A. (Albuquerque, NM)

    2003-04-08

    An electrolyte system suitable for a molten salt electrolyte battery is described where the electrolyte system is a molten nitrate compound, an organic compound containing dissolved lithium salts, or a 1-ethyl-3-methlyimidazolium salt with a melting temperature between approximately room temperature and approximately 250.degree. C. With a compatible anode and cathode, the electrolyte system is utilized in a battery as a power source suitable for oil/gas borehole applications and in heat sensors.

  9. Using Encapsulated Phase Change Material in Thermal Energy Storage for Baseload Concentrating Solar Power (EPCM-TES)

    SciTech Connect (OSTI)

    Mathur, Anoop

    2013-12-15

    Terrafore successfully demonstrated and optimized the manufacturing of capsules containing phase-changing inorganic salts. The phase change was used to store thermal energy collected from a concentrating solar-power plant as latent heat. This latent heat, in addition to sensible heat increased the energy density (energy stored per unit weight of salt) by over 50%, thus requiring 40% less salt and over 60% less capsule container. Therefore, the cost to store high-temperature thermal energy collected in a concentrating solar power plant will be reduced by almost 40% or more, as compared to conventional two-tank, sensible-only storage systems. The cost for thermal energy storage (TES) system is expected to achieve the Sun Shot goal of $15 per kWh(t). Costs associated with poor heat-transfer in phase change materials (PCM) were also eliminated. Although thermal energy storage that relies on the latent heat of fusion of PCM improves energy density by as much as 50%, upon energy discharge the salt freezes and builds on the heat transfer surfaces. Since these salts have low thermal conductivity, large heat-transfer areas, or larger conventional heat-exchangers are needed, which increases costs. By encapsulating PCM in small capsules we have increased the heat transfer area per unit volume of salt and brought the heat transfer fluid in direct contact with the capsules. These two improvements have increased the heat transfer coefficient and boosted heat transfer. The program was successful in overcoming the phenomenon of melt expansion in the capsules, which requires the creation of open volume in the capsules or shell to allow for expansion of the molten salt on melting and is heated above its melting point to 550°C. Under contract with the Department of Energy, Terrafore Inc. and Southwest Research Institute, developed innovative method(s) to economically create the open volume or void in the capsule. One method consists of using a sacrificial polymer coating as the middle layer between the salt prill and the shell material. The selected polymer decomposes at temperatures below the melting point of the salt and forms gases which escape through the pores in the capsule shell thus leaving a void in the capsule. We have demonstrated the process with a commonly used inorganic nitrate salt in a low-cost shell material that can withstand over 10,000 high-temperature thermal cycles, or a thirty-year or greater life in a solar plant. The shell used to encapsulate the salt was demonstrated to be compatible with molten salt heat transfer fluid typically used in CSP plants to temperatures up to 600 °C. The above findings have led to the concept of a cascaded arrangement. Salts with different melting points can be encapsulated using the same recipe and contained in a packed bed by cascading the salt melting at higher melting point at the top over the salt melting at lower melting point towards the bottom of the tank. This cascaded energy storage is required to effectively transfer the sensible heat collected in heat transfer fluids between the operating temperatures and utilize the latent heat of fusion in the salts inside the capsule. Mathematical models indicate that over 90% of the salts will undergo phase change by using three salts in equal proportion. The salts are selected such that the salt at the top of the tank melts at about 15°C below the high operating-temperature, and the salt at the bottom of the tank melts 15°C above the low operating-temperature. The salt in the middle of tank melts in-between the operating temperature of the heat transfer fluid. A cascaded arrangement leads to the capture of 90% of the latent-heat of fusion of salts and their sensible heats. Thus the energy density is increased by over 50% from a sensible-only, two-tank thermal energy storage. Furthermore, the Terrafore cascaded storage method requires only one tank as opposed to the two-tanks used in sensible heat storage. Since heat is transferred from the heat transfer fluid by direct contact with capsules, external heat-exchangers are not required

  10. Development and Demonstration of an Innovative Thermal Energy Storage System for Baseload Power Generation

    SciTech Connect (OSTI)

    D. Y. Goswami

    2012-09-04

    The objective of this project is to research and develop a thermal energy storage system (operating range 3000C ���¢�������� 450 0C ) based on encapsulated phase change materials (PCM) that can meet the utility-scale base-load concentrated solar power plant requirements at much lower system costs compared to the existing thermal energy storage (TES) concepts. The major focus of this program is to develop suitable encapsulation methods for existing low-cost phase change materials that would provide a cost effective and reliable solution for thermal energy storage to be integrated in solar thermal power plants. This project proposes a TES system concept that will allow for an increase of the capacity factor of the present CSP technologies to 75% or greater and reduce the cost to less than $20/kWht.

  11. Nitrate Salt Bearing Transuranic Waste Container Monitoring

    Broader source: Energy.gov [DOE]

    Supporting Technical Document for the Radiological Release Accident Investigation Report (Phase II Report)

  12. Flexible Coal: An Example Evolution from Baseload to Peaking Plant (Presentation)

    SciTech Connect (OSTI)

    Cochran, J.

    2014-08-01

    Twenty-first century power systems, with higher penetration levels of low-carbon energy, smart grids, and other emerging technologies, will favor resources that have low marginal costs and provide system flexibility (e.g., the ability to cycle on and off to follow changes in variable renewable energy plant output). Questions remain about both the fate of coal plants in this scenario and whether they can cost-effectively continue to operate if they cycle routinely. The experience from the CGS plant demonstrates that coal plants can become flexible resources. This flexibility - namely the ability to cycle on and off and run at lower output (below 40% of capacity) - requires limited hardware modifications but extensive modifications to operational practice. Cycling does damage the plant and impact its life expectancy compared to baseload operations. Nevertheless, strategic modifications, proactive inspections and training programs, among other operational changes to accommodate cycling, can minimize the extent of damage and optimize the cost of maintenance. CGS's cycling, but not necessarily the associated price tag, is replicable. Context - namely, power market opportunities and composition of the generation fleet - will help determine for other coal plants the optimal balance between the level of cycling-related forced outages and the level of capital investment required to minimize those outages. Replicating CGS's experience elsewhere will likely require a higher acceptance of forced outages than regulators and plant operators are accustomed to; however, an increase in strategic maintenance can minimize the impact on outage rates.

  13. Flexible Coal: An Example Evolution from Baseload to Peaking Plant (Presentation)

    SciTech Connect (OSTI)

    Cochran, J.

    2014-05-01

    Twenty-first century power systems, with higher penetration levels of low-carbon energy, smart grids, and other emerging technologies, will favor resources that have low marginal costs and provide system flexibility (e.g., the ability to cycle on and off to follow changes in variable renewable energy plant output). Questions remain about both the fate of coal plants in this scenario and whether they can cost-effectively continue to operate if they cycle routinely. The experience from the CGS plant demonstrates that coal plants can become flexible resources. This flexibility - namely the ability to cycle on and off and run at lower output (below 40% of capacity) - requires limited hardware modifications but extensive modifications to operational practice. Cycling does damage the plant and impact its life expectancy compared to baseload operations. Nevertheless, strategic modifications, proactive inspections and training programs, among other operational changes to accommodate cycling, can minimize the extent of damage and optimize the cost of maintenance. CGS's cycling, but not necessarily the associated price tag, is replicable. Context - namely, power market opportunities and composition of the generation fleet - will help determine for other coal plants the optimal balance between the level of cycling-related forced outages and the level of capital investment required to minimize those outages. Replicating CGS's experience elsewhere will likely require a higher acceptance of forced outages than regulators and plant operators are accustomed to; however, an increase in strategic maintenance can minimize the impact on outage rates.

  14. CX-010503: Categorical Exclusion Determination | Department of...

    Office of Environmental Management (EM)

    Categorical Exclusion Determination Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9, B3.6, B5.17 Date: 06032013 Location(s): Colorado,...

  15. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

    1983-01-01

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

  16. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, I.D.; Poris, J.; Huggins, R.A.

    1980-07-18

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell which may be operated at temperatures between about 100 to 170/sup 0/C. The cell is comprised of an electrolyte, which preferably includes lithium nitrate, and a lithium or lithium alloy electrode.

  17. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

    1982-02-09

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

  18. Thermochemical nitrate destruction

    DOE Patents [OSTI]

    Cox, J.L.; Hallen, R.T.; Lilga, M.A.

    1992-06-02

    A method is disclosed for denitrification of nitrates and nitrites present in aqueous waste streams. The method comprises the steps of (1) identifying the concentration nitrates and nitrites present in a waste stream, (2) causing formate to be present in the waste stream, (3) heating the mixture to a predetermined reaction temperature from about 200 C to about 600 C, and (4) holding the mixture and accumulating products at heated and pressurized conditions for a residence time, thereby resulting in nitrogen and carbon dioxide gas, and hydroxides, and reducing the level of nitrates and nitrites to below drinking water standards.

  19. NITRATE DESTRUCTION LITERATURE SURVEY AND EVALUATION CRITERIA

    SciTech Connect (OSTI)

    Steimke, J.

    2011-02-01

    This report satisfies the initial phase of Task WP-2.3.4 Alternative Sodium Recovery Technology, Subtask 1; Develop Near-Tank Nitrate/Nitrite Destruction Technology. Some of the more common anions in carbon steel waste tanks at SRS and Hanford Site are nitrate which is corrosive, and nitrite and hydroxide which are corrosion inhibitors. At present it is necessary to periodically add large quantities of 50 wt% caustic to waste tanks. There are three primary reasons for this addition. First, when the contents of salt tanks are dissolved, sodium hydroxide preferentially dissolves and is removed. During the dissolution process the concentration of free hydroxide in the tank liquid can decrease from 9 M to less than 0.2 M. As a result, roughly half way through the dissolution process large quantities of sodium hydroxide must be added to the tank to comply with requirements for corrosion control. Second, hydroxide is continuously consumed by reaction with carbon dioxide which occurs naturally in purge air used to prevent buildup of hydrogen gas inside the tanks. The hydrogen is generated by radiolysis of water. Third, increasing the concentration of hydroxide increases solubility of some aluminum compounds, which is desirable in processing waste. A process that converts nitrate and nitrite to hydroxide would reduce certain costs. (1) Less caustic would be purchased. (2) Some of the aluminum solid compounds in the waste tanks would become more soluble so less mass of solids would be sent to High Level Vitrification and therefore it would be not be necessary to make as much expensive high level vitrified product. (3) Less mass of sodium would be fed to Saltstone at SRS or Low Level Vitrification at Hanford Site so it would not be necessary to make as much low level product. (4) At SRS less nitrite and nitrate would be sent to Defense Waste Processing Facility (DWPF) so less formic acid would be consumed there and less hydrogen gas would be generated. This task involves literature survey of technologies to perform the nitrate to hydroxide conversion, selection of the most promising technologies, preparation of a flowsheet and design of a system. The most promising technologies are electrochemical reduction of nitrates and chemical reduction with hydrogen or ammonia. The primary reviewed technologies are listed and they aredescribed in more detail later in the report: (1) Electrochemical destruction; (2) Chemical reduction with agents such as ammonia, hydrazine or hydrogen; (3) Hydrothermal reduction process; and (4) Calcination. Only three of the technologies on the list have been demonstrated to generate usable amounts of caustic; electrochemical reduction and chemical reduction with ammonia, hydrazine or hydrogen and hydrothermal reduction. Chemical reduction with an organic reactant such as formic acid generates carbon dioxide which reacts with caustic and is thus counterproductive. Treatment of nitrate with aluminum or other active metals generates a solid product. High temperature calcination has the potential to generate sodium oxide which may be hydrated to sodium hydroxide, but this is unproven. The following criteria were developed to evaluate the most suitable option. The numbers in brackets after the criteria are relative weighting factors to account for importance: (1) Personnel exposure to radiation for installation, routine operation and maintenance; (2) Non-radioactive safety issues; (3) Whether the technology generates caustic and how many moles of caustic are generated per mole of nitrate plus nitrite decomposed; (4) Whether the technology can handle nitrate and nitrite at the concentrations encountered in waste; (5) Maturity of technology; (6) Estimated annual cost of operation (labor, depreciation, materials, utilities); (7) Capital cost; (8) Selectivity to nitrogen as decomposition product (other products are flammable and/or toxic); (9) Impact of introduced species; (10) Selectivity for destruction of nitrate vs. nitrite; and (11) Cost of deactivation and demolition. Each technology was given a score from one

  20. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container

    Office of Environmental Management (EM)

    environment." Additionally, the Order requires information regarding the "volumetric flow rate for ventilation in the WIPP underground, a description of how the volumetric flow...

  1. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container

    E-Print Network [OSTI]

    Napp, Nils

    and closure has been initiated. The radiological release contaminated portions of the underground facility (WIPP) underground disposal facility. The Order also requests an implementation schedule for this Plan (CAM) detected airborne radiation in the WIPP underground facility. When the CAM alarmed, underground

  2. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container Isolation

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-Sessions | DepartmentResidential Savings|Washington ,ProductivityPlan |

  3. Project Profile: Advanced Nitrate Salt Central Receiver Power Plant |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrderNATIONALofDefine ReviewImpact AssessmentsMaterials for

  4. THERMODYNAMIC PROPERTIES OF MOLTEN NITRATE SALTS Joseph G. Cordaro

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With LivermoreSustainableDEPARTMENT OF ENERGY Office

  5. WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentricN A 035(92/02) nerg *4 o**ColoradoDOE Awards

  6. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentricN A 035(92/02) nergFeet)DepartmentWaste

  7. Treatment of Remediated Nitrate Salts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaicsState ofSavingsTransmissionin PEMFC27,Inc. ||

  8. Nitrate and Prussic Acid Poisoning 

    E-Print Network [OSTI]

    Stichler, Charles; Reagor, John C.

    2001-09-05

    Nitrate and prussic acid poisoning in cattle are noninfectious conditions that can kill livestock. This publication explains the causes and symptoms of these conditions as well as preventive measures and sampling and testing steps....

  9. Plutonium nitrate bottle counter manual

    SciTech Connect (OSTI)

    Menlove, H.O.; Adams, E.L.; Holbrooks, O.R.

    1984-03-01

    A neutron coincidence counter has been designed for plutonium nitrate assay in large storage bottles. This assay system can be used in the reprocessing plant or in the nitrate-to-oxide conversion facility. The system is based on the family of neutron detectors similar to the high-level neutron coincidence counter. This manual describes the system and gives performance and calibration parameters for typical applications. 4 references, 11 figures, 9 tables.

  10. Salt Waste Processing Initiatives

    Office of Environmental Management (EM)

    Patricia Suggs Salt Processing Team Lead Assistant Manager for Waste Disposition Project Office of Environmental Management Savannah River Site Salt Waste Processing Initiatives 2...

  11. Electrolyte salts for power sources

    DOE Patents [OSTI]

    Doddapaneni, N.; Ingersoll, D.

    1995-11-28

    Electrolyte salts are disclosed for power sources comprising salts of phenyl polysulfonic acids and phenyl polyphosphonic acids. The preferred salts are alkali and alkaline earth metal salts, most preferably lithium salts. 2 figs.

  12. Process for reducing aqueous nitrate to ammonia

    DOE Patents [OSTI]

    Mattus, A.J.

    1993-11-30

    Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product. 3 figures.

  13. Salt never calls itself sweet.

    E-Print Network [OSTI]

    Baliga, Ragavendra R; Narula, Jagat

    2009-01-01

    54. 11. Frohlich ED. The role of salt in hypertension: theblockade, diuretics, and salt restriction for the managementa low- sodium high-potassium salt in hypertensive patients

  14. Slime-busting Salt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    past issues All Issues submit Slime-busting Salt A potential new treatment gets bacteria deep in their hiding places May 1, 2015 Slime-busting Salt Biofilms are made of...

  15. Molten salt electrolyte separator

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL)

    1996-01-01

    A molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication.

  16. Free amino acids, nitrate, and nitrate reductase in nitrogen fixation by soybean nodules 

    E-Print Network [OSTI]

    Madtes, Paul Clayton

    1978-01-01

    FREE AMINO ACIDS, NITRATE, AND NITRATE REDUCTASE IN NITROGEN FIXATION BY SOYBEAN NODULES A Thesis by PAUL CLAYTON MADTES, JR. Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE December 1978 Major Subject: Biophysics FREE AMINO ACIDS, NITRATE, AND NITRATE REDUCTASE IN NITROGEN FIXATION BY SOYBEAN NPDULES A Thesis by PAUL CLAYTON MADTES, JR. Approved as to style and content by: g jap (Chairman...

  17. Dosimetry using silver salts

    DOE Patents [OSTI]

    Warner, Benjamin P. (Los Alamos, NM)

    2003-06-24

    The present invention provides a method for detecting ionizing radiation. Exposure of silver salt AgX to ionizing radiation results in the partial reduction of the salt to a mixture of silver salt and silver metal. The mixture is further reduced by a reducing agent, which causes the production of acid (HX) and the oxidized form of the reducing agent (R). Detection of HX indicates that the silver salt has been exposed to ionizing radiation. The oxidized form of the reducing agent (R) may also be detected. The invention also includes dosimeters employing the above method for detecting ionizing radiation.

  18. A Dash of Salt 

    E-Print Network [OSTI]

    Supercinski, Danielle

    2006-01-01

    stream_source_info A dash of salt.pdf.txt stream_content_type text/plain stream_size 9159 Content-Encoding ISO-8859-1 stream_name A dash of salt.pdf.txt Content-Type text/plain; charset=ISO-8859-1 tx H2O | pg. 18 A... Texas A&M researcher is assessing the impact of using moderately saline water for irrigating urban landscapes in West Texas and southern New Mexico. A DASH OF SALT Researcher assesses salinity impacts on grasses, trees and shrubs A Dash of Salt...

  19. NOVEL SALTS OF GRAPHITE AND A BORON NITRIDE SALT

    E-Print Network [OSTI]

    Bartlett, Neil

    2011-01-01

    ~ i\\f'{y AND DOCUMENTS SECTION NOVEL SALTS OF GRAPHITE ANDA BORON NITRIDE SALT Neil Bartlett, R. N. Biagioni, B. W.privately owned rights. Novel Salts of Graphite and a Boron

  20. Nitrates and Prussic Acid in Forages 

    E-Print Network [OSTI]

    Provin, Tony; Pitt, John L.

    2003-01-06

    When nitrates and prussic acid accumulate in forage, the feed may not be safe for livestock consumption. Learn the symptoms of nitrate and prussic acid poisoning and which plants are most likely to pose a risk to livestock. Also learn sampling...

  1. Hydroxycarboxylic acids and salts

    SciTech Connect (OSTI)

    Kiely, Donald E; Hash, Kirk R; Kramer-Presta, Kylie; Smith, Tyler N

    2015-02-24

    Compositions which inhibit corrosion and alter the physical properties of concrete (admixtures) are prepared from salt mixtures of hydroxycarboxylic acids, carboxylic acids, and nitric acid. The salt mixtures are prepared by neutralizing acid product mixtures from the oxidation of polyols using nitric acid and oxygen as the oxidizing agents. Nitric acid is removed from the hydroxycarboxylic acids by evaporation and diffusion dialysis.

  2. Molten salt electrolyte separator

    DOE Patents [OSTI]

    Kaun, T.D.

    1996-07-09

    The patent describes a molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication. 5 figs.

  3. Water purification using organic salts

    DOE Patents [OSTI]

    Currier, Robert P.

    2004-11-23

    Water purification using organic salts. Feed water is mixed with at least one organic salt at a temperature sufficiently low to form organic salt hydrate crystals and brine. The crystals are separated from the brine, rinsed, and melted to form an aqueous solution of organic salt. Some of the water is removed from the aqueous organic salt solution. The purified water is collected, and the remaining more concentrated aqueous organic salt solution is reused.

  4. Crushed Salt Constitutive Model

    SciTech Connect (OSTI)

    Callahan, G.D.

    1999-02-01

    The constitutive model used to describe the deformation of crushed salt is presented in this report. Two mechanisms -- dislocation creep and grain boundary diffusional pressure solution -- are combined to form the basis for the constitutive model governing the deformation of crushed salt. The constitutive model is generalized to represent three-dimensional states of stress. Upon complete consolidation, the crushed-salt model reproduces the Multimechanism Deformation (M-D) model typically used for the Waste Isolation Pilot Plant (WIPP) host geological formation salt. New shear consolidation tests are combined with an existing database that includes hydrostatic consolidation and shear consolidation tests conducted on WIPP and southeastern New Mexico salt. Nonlinear least-squares model fitting to the database produced two sets of material parameter values for the model -- one for the shear consolidation tests and one for a combination of the shear and hydrostatic consolidation tests. Using the parameter values determined from the fitted database, the constitutive model is validated against constant strain-rate tests. Shaft seal problems are analyzed to demonstrate model-predicted consolidation of the shaft seal crushed-salt component. Based on the fitting statistics, the ability of the model to predict the test data, and the ability of the model to predict load paths and test data outside of the fitted database, the model appears to capture the creep consolidation behavior of crushed salt reasonably well.

  5. Molten Salt Test Loop (MSTL) system customer interface document.

    SciTech Connect (OSTI)

    Gill, David Dennis; Kolb, William J.; Briggs, Ronald D.

    2013-09-01

    The National Solar Thermal Test Facility at Sandia National Laboratories has a unique test capability called the Molten Salt Test Loop (MSTL) system. MSTL is a test capability that allows customers and researchers to test components in flowing, molten nitrate salt. The components tested can range from materials samples, to individual components such as flex hoses, ball joints, and valves, up to full solar collecting systems such as central receiver panels, parabolic troughs, or linear Fresnel systems. MSTL provides realistic conditions similar to a portion of a concentrating solar power facility. The facility currently uses 60/40 nitrate %E2%80%9Csolar salt%E2%80%9D and can circulate the salt at pressure up to 40 bar (600psi), temperature to 585%C2%B0C, and flow rate of 44-50kg/s(400-600GPM) depending on temperature. The purpose of this document is to provide a basis for customers to evaluate the applicability to their testing needs, and to provide an outline of expectations for conducting testing on MSTL. The document can serve as the basis for testing agreements including Work for Others (WFO) and Cooperative Research and Development Agreements (CRADA). While this document provides the basis for these agreements and describes some of the requirements for testing using MSTL and on the site at Sandia, the document is not sufficient by itself as a test agreement. The document, however, does provide customers with a uniform set of information to begin the test planning process.

  6. Salt Repository Research,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Salt Repository Research, Design, and Operation La Fonda Hotel Santa Fe, New Mexico September 7 - 11, 2014 Please join us Sunday September 7, 2014 for a welcome and reception at...

  7. Salt Repository Research,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 th USGerman Workshop on Salt Repository Research, Design, and Operation Hotel Pullmann Dresden Newa Dresden September 7 - 9, 2015 September 7- Monday 08:00-08:30 Registration...

  8. Amine salts of nitroazoles

    DOE Patents [OSTI]

    Kienyin Lee; Stinecipher, M.M.

    1993-10-26

    Compositions of matter, a method of providing chemical energy by burning said compositions, and methods of making said compositions are described. These compositions are amine salts of nitroazoles. 1 figure.

  9. Introduction Current methods to determine nitrate (NO3

    E-Print Network [OSTI]

    Sigman, Daniel M.

    with nitrate reduction using spongy cadmium) also allows for isotopic analysis of both nitrate and nitrite (Mc205 Introduction Current methods to determine nitrate (NO3 ­ ) nitrogen (N) and oxygen (O) isotope of nitrate versus that of nitrite in a given sample. In the case of the ammonia distillation (Cline

  10. Process for the preparation of an energetic nitrate ester

    DOE Patents [OSTI]

    Chavez, David E; Naud, Darren L; Hiskey, Michael A

    2013-12-17

    A process for the preparation of an energetic nitrate ester compound and related intermediates is provided.

  11. CRITICALITY SAFETY OF PROCESSING SALT SOLUTION AT SRS

    SciTech Connect (OSTI)

    Stephens, K; Davoud Eghbali, D; Michelle Abney, M

    2008-01-15

    High level radioactive liquid waste generated as a result of the production of nuclear material for the United States defense program at the Savannah River Site has been stored as 36 million gallons in underground tanks. About ten percent of the waste volume is sludge, composed of insoluble metal hydroxides primarily hydroxides of Mn, Fe, Al, Hg, and most radionuclides including fission products. The remaining ninety percent of the waste volume is saltcake, composed of primarily sodium (nitrites, nitrates, and aluminates) and hydroxides. Saltcakes account for 30% of the radioactivity while the sludge accounts for 70% of the radioactivity. A pilot plant salt disposition processing system has been designed at the Savannah River Site for interim processing of salt solution and is composed of two facilities: the Actinide Removal Process Facility (ARPF) and the Modular Caustic Side Solvent Extraction Unit (MCU). Data from the pilot plant salt processing system will be used for future processing salt at a much higher rate in a new salt processing facility. Saltcake contains significant amounts of actinides, and other long-lived radioactive nuclides such as strontium and cesium that must be extracted prior to disposal as low level waste. The extracted radioactive nuclides will be mixed with the sludge from waste tanks and vitrified in another facility. Because of the presence of highly enriched uranium in the saltcake, there is a criticality concern associated with concentration and/or accumulation of fissionable material in the ARP and MCU.

  12. Synthesis of a new energetic nitrate ester

    SciTech Connect (OSTI)

    Chavez, David E

    2008-01-01

    Nitrate esters have been known as useful energetic materials since the discovery of nitroglycerin by Ascanio Sobrero in 1846. The development of methods to increase the safety and utility of nitroglycerin by Alfred Nobel led to the revolutionary improvement in the utility of nitroglycerin in explosive applications in the form of dynamite. Since then, many nitrate esters have been prepared and incorporated into military applications such as double-based propellants, detonators and as energetic plasticizers. Nitrate esters have also been shown to have vasodilatory effects in humans and thus have been studied and used for treatments of ailments such as angina. The mechanism of the biological response towards nitrate esters has been elucidated recently. Interestingly, many of the nitrate esters used for military purposes are liquids (ethylene glycol dinitrate, propylene glycol dinitrate, etc). Pentaerythritol tetranitrate (PETN) is one of the only solid nitrate esters, besides nitrocellulose, that is used in any application. Unfortunately, PETN melting point is above 100 {sup o}C, and thus must be pressed as a solid for detonator applications. A more practical material would be a melt-castable explosive, for potential simplification of manufacturing processes. Herein we describe the synthesis of a new energetic nitrate ester (1) that is a solid at ambient temperatures, has a melting point of 85-86 {sup o}C and has the highest density of any known nitrate ester composed only of carbon, hydrogen, nitrogen and oxygen. We also describe the chemical, thermal and sensitivity properties of 1 as well as some preliminary explosive performance data.

  13. Nitrates and detinning in canned carrots 

    E-Print Network [OSTI]

    Florine, Thomas Edward

    1968-01-01

    NITRATES AND DETINNING IN CANNED CARROTS A Thesis by Thomas Edward Florine Submitted to the Graduate College of the Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1968 Major... Subject: Food Technology NITRATES AND DETINNING IN CANNED CARROTS A Thesis by Thomas Edward Florine Approved as to style and content by: / C-~ (Chairman of Cemi. tee) Head of Department Member) (Member) :-'i ~ (Member) (Member) (Member...

  14. Process for decomposing nitrates in aqueous solution

    DOE Patents [OSTI]

    Haas, Paul A. (Knoxville, TN)

    1980-01-01

    This invention is a process for decomposing ammonium nitrate and/or selected metal nitrates in an aqueous solution at an elevated temperature and pressure. Where the compound to be decomposed is a metal nitrate (e.g., a nuclear-fuel metal nitrate), a hydroxylated organic reducing agent therefor is provided in the solution. In accordance with the invention, an effective proportion of both nitromethane and nitric acid is incorporated in the solution to accelerate decomposition of the ammonium nitrate and/or selected metal nitrate. As a result, decomposition can be effected at significantly lower temperatures and pressures, permitting the use of system components composed of off-the-shelf materials, such as stainless steel, rather than more costly materials of construction. Preferably, the process is conducted on a continuous basis. Fluid can be automatically vented from the reaction zone as required to maintain the operating temperature at a moderate value--e.g., at a value in the range of from about 130.degree.-200.degree. C.

  15. Fundamental Properties of Salts

    SciTech Connect (OSTI)

    Toni Y Gutknecht; Guy L Fredrickson

    2012-11-01

    Thermal properties of molten salt systems are of interest to electrorefining operations, pertaining to both the Fuel Cycle Research & Development Program (FCR&D) and Spent Fuel Treatment Mission, currently being pursued by the Department of Energy (DOE). The phase stability of molten salts in an electrorefiner may be adversely impacted by the build-up of fission products in the electrolyte. Potential situations that need to be avoided, during electrorefining operations, include (i) fissile elements build up in the salt that might approach the criticality limits specified for the vessel, (ii) electrolyte freezing at the operating temperature of the electrorefiner due to changes in the liquidus temperature, and (iii) phase separation (non-homogenous solution). The stability (and homogeneity) of the phases can be monitored by studying the thermal characteristics of the molten salts as a function of impurity concentration. Simulated salt compositions consisting of the selected rare earth and alkaline earth chlorides, with a eutectic mixture of LiCl-KCl as the carrier electrolyte, were studied to determine the melting points (thermal characteristics) using a Differential Scanning Calorimeter (DSC). The experimental data were used to model the liquidus temperature. On the basis of the this data, it became possible to predict a spent fuel treatment processing scenario under which electrorefining could no longer be performed as a result of increasing liquidus temperatures of the electrolyte.

  16. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  17. Understanding and eliminating iron interference in colorimetric nitrate and nitrite analysis

    E-Print Network [OSTI]

    Colman, Benjamin P.

    2010-01-01

    to cadmium for photomet- ric nitrate determinations in waterNitrogen, nitrate–nitrite (spectrophotometric, cadmiumDetermination of nitrate in sea water by cadmium- copper

  18. RECHARGEABLE MOLTEN-SALT CELLS

    E-Print Network [OSTI]

    Cairns, Elton J.

    2013-01-01

    KC! /FeS 2 cell lithium-silicon magnesium oxide molten-saltmolten-salt cells Na/Na glass/Na:z.Sn-S cell Na/NazO•xA!Symposium on Molten Salts, Physical Electrochemistry

  19. Actinide removal from spent salts

    DOE Patents [OSTI]

    Hsu, Peter C. (Pleasanton, CA); von Holtz, Erica H. (Livermore, CA); Hipple, David L. (Livermore, CA); Summers, Leslie J. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

    2002-01-01

    A method for removing actinide contaminants (uranium and thorium) from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents are added to precipitate the thorium as thorium oxide and/or the uranium as either uranium oxide or as a diuranate salt. The precipitated materials are filtered, dried and packaged for disposal as radioactive waste. About 90% of the thorium and/or uranium present is removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 0.1 ppm of thorium or uranium.

  20. Treatment of waste by the Molten Salt Oxidation process at the Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Crosley, S.M.; Lorenzo, D.K.; Van Cleve, J.E. [Oak Ridge National Lab., TN (United States); Gay, R.L.; Barclay, K.M.; Newcomb, J.C.; Yosim, S.J. [Rockwell International Corp., Canoga Park, CA (United States)

    1993-03-01

    The Molten Salt Oxidation (MSO) process has been under development by the Energy Technology Engineering Center (ETEC) to treat hazardous, radioactive, and mixed waste. Testing of the system was done on a number of wastes to demonstrate the technical feasibility of the process. This testing included simulated intermediate level waste (ILW) from the Oak Ridge National Laboratory. The intermediate level waste stream consisted of a slurry of concentrated aqueous solutions of sodium hydroxide and sodium nitrate, with a small amount of miscellaneous combustible components (PVC, TBP, kerosene, and ion exchange resins). The purpose of these tests was to evaluate the destruction of the organics, evaporation of the water, and conversion of the hazardous salts (hydroxide and nitrate) to non-hazardous sodium carbonate. Results of the tests are discussed and analyzed, and the possibilities of applying the MSO process to different waste streams at ORNL in the future are explored.

  1. Design considerations for concentrating solar power tower systems employing molten salt.

    SciTech Connect (OSTI)

    Moore, Robert Charles; Siegel, Nathan Phillip; Kolb, Gregory J.; Vernon, Milton E.; Ho, Clifford Kuofei

    2010-09-01

    The Solar Two Project was a United States Department of Energy sponsored project operated from 1996 to 1999 to demonstrate the coupling of a solar power tower with a molten nitrate salt as a heat transfer media and for thermal storage. Over all, the Solar Two Project was very successful; however many operational challenges were encountered. In this work, the major problems encountered in operation of the Solar Two facility were evaluated and alternative technologies identified for use in a future solar power tower operating with a steam Rankine power cycle. Many of the major problems encountered can be addressed with new technologies that were not available a decade ago. These new technologies include better thermal insulation, analytical equipment, pumps and values specifically designed for molten nitrate salts, and gaskets resistant to thermal cycling and advanced equipment designs.

  2. APPLICATIONS OF SALT IN ELECTROFISHING

    E-Print Network [OSTI]

    APPLICATIONS OF SALT IN ELECTROFISHING iNlarine Biological Laboratory LIB55.A.K.Y WOODS HOLE, MASS OF SALT IN ELECTROFISHING By Robert E . Lennon and Phillip S . Parker Fishery Research Biologists Leetown. Electric fisliliiK. 2. Salt. i. Farker, Phillip Slieridaii, 192t>- .joiut author, ii. Title. ( Series : IT

  3. ORNL/TM-2008/048 Uranyl Nitrate Flow Loop

    E-Print Network [OSTI]

    Pennycook, Steve

    ORNL/TM-2008/048 Uranyl Nitrate Flow Loop October 2008 Jennifer L. Ladd-Lively #12;DOCUMENT Government or any agency thereof. #12;ORNL/TM-2008/048 Nuclear Science and Technology Division URANYL NITRATE

  4. Formation mechanisms and quantification of organic nitrates in atmospheric aerosol

    E-Print Network [OSTI]

    Rollins, Andrew Waite

    2010-01-01

    limonene-1-nitrate, 1-hydroxy-butane- 2-nitrate, 3-hydroxy-our measured spectra of the butane hydroxynitrate we foundstandards except for the butane hydroxynitrate the O/C based

  5. Shock compression of water and solutions of ammonium nitrate

    E-Print Network [OSTI]

    Morley, Michael James

    2011-07-12

    Modern mining explosives employ solutions of ammonium nitrate, where the solution is the oxidising component of a fuel/oxidiser mixture. This thesis is primarily concerned with the shock response of water and of aqueous solutions of ammonium nitrate...

  6. Potentiometric Nitrate Sensors in the Form of Plant Roots

    E-Print Network [OSTI]

    Tatyana Bendikov; Nicole Jurisch; Mallory Davidson; Thomas Harmon

    2005-01-01

    cadmium reactant) Potentiometric Response for NO 3 Ion Electrochemical deposition (constant current conditions) of polypyrrole dopped with nitrate

  7. Spatial Inference of Nitrate Concentrations in Groundwater

    E-Print Network [OSTI]

    Woodard, Dawn B.

    Spatial Inference of Nitrate Concentrations in Groundwater DAWN B. WOODARD, ROBERT L. WOLPERT in groundwater over the mid-Atlantic states, using measurements gathered during a pe- riod of ten years. A map- trations in air, pesticide concentrations in groundwater, or any other quantity that varies over

  8. RECHERCHE DES NITRATES DANS LES FOURRAGES ET LES ENSILAGES

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    'une purification des extraits puis de la réduction des nitrates en nitrites par le cadmium. Les nitrites sontH sur la réduction par le cadmium de solutions pures de nitrates de concentrations variables. La méthode réduction par le cadmium des nitrates en nitrites lesquels sont dosés par colorimétrie (de BoRGER et JENNEN

  9. Reducing nitrate loads from corn and soybean, tile-drained, agricultural production systems in the Upper Mississippi River

    E-Print Network [OSTI]

    David, Mark B.

    ). Tile woodchip bioreactors had good nitrate removal in 2012 (80% nitrate reduction), and wetlands had

  10. Enhanced liquid-liquid anion exchange using macrocyclic anion receptors: effect of receptor structure on sulphate-nitrate exchange selectivity

    SciTech Connect (OSTI)

    Moyer, Bruce A; Sloop Jr, Frederick {Fred} V; Fowler, Christopher J; Haverlock, Tamara; Kang, Hyun Ah; Delmau, Laetitia Helene; Bau, Diadra; Hossain, Alamgir; Bowman-James, Kristin; Shriver, James A.; Gross, Mr. Dustin E.; Bill, Nathan; Marquez, Manuel; Lynch, Vincent M.; Sessler, Jonathan L.

    2010-01-01

    When certain macrocyclic anion receptors are added to a chloroform solution of the nitrate form of a lipophilic quaternary ammonium salt (methyltri-C8,10-ammonium nitrate, Aliquat 336N), the extraction of sulphate from an aqueous sodium nitrate solution via exchange with the organic-phase nitrate is significantly enhanced. Eight macrocycles were surveyed, including two derivatives of a tetraamide macrocycle, five derivatives of calix[4]pyrrole and -decafluorocalix[5]pyrrole. Under the hypothesis that the enhancement originates from sulphate binding by the anion receptors in the chloroform phase, it was possible to obtain reasonable fits to the sulphate distribution survey data based on the formation of 1:1 and 2:1 receptor:sulphate complexes in the chloroform phase. Apparent 1:1 sulphate-binding constants obtained from the model in this system fell in the range . Comparison of the results for the various anion receptors included in this study reveals that sulphate binding is sensitive to the nature of the substituents on the parent macrocycle scaffolds in a way that does not follow straightforwardly from simple chemical expectations, such as electron-withdrawing effects on hydrogen-bond donor strength.

  11. Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids

    SciTech Connect (OSTI)

    Raade, Justin; Roark, Thomas; Vaughn, John; Bradshaw, Robert

    2013-07-22

    Concentrating solar power (CSP) facilities are comprised of many miles of fluid-filled pipes arranged in large grids with reflective mirrors used to capture radiation from the sun. Solar radiation heats the fluid which is used to produce steam necessary to power large electricity generation turbines. Currently, organic, oil-based fluid in the pipes has a maximum temperature threshold of 400 °C, allowing for the production of electricity at approximately 15 cents per kilowatt hour. The DOE hopes to foster the development of an advanced heat transfer fluid that can operate within higher temperature ranges. The new heat transfer fluid, when used with other advanced technologies, could significantly decrease solar electricity cost. Lower costs would make solar thermal electricity competitive with gas and coal and would offer a clean, renewable source of energy. Molten salts exhibit many desirable heat transfer qualities within the range of the project objectives. Halotechnics developed advanced heat transfer fluids (HTFs) for application in solar thermal power generation. This project focused on complex mixtures of inorganic salts that exhibited a high thermal stability, a low melting point, and other favorable characteristics. A high-throughput combinatorial research and development program was conducted in order to achieve the project objective. Over 19,000 candidate formulations were screened. The workflow developed to screen various chemical systems to discover salt formulations led to mixtures suitable for use as HTFs in both parabolic trough and heliostat CSP plants. Furthermore, salt mixtures which will not interfere with fertilizer based nitrates were discovered. In addition for use in CSP, the discovered salt mixtures can be applied to electricity storage, heat treatment of alloys and other industrial processes.

  12. Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response Instructions

    Broader source: Energy.gov [DOE]

    Supporting Technical Document for the Radiological Release Accident Investigation Report (Phase II Report)

  13. EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container...

    Office of Environmental Management (EM)

    release of internal contents to atmosphere 4. Evidence of fire or smoke 5. Blistering paint on a container 6. A container temperature measurement that is greater than 15 F...

  14. Memo - Legacy Technical Area (TA)-55 Nitrate Salt Wastes at TA...

    Office of Environmental Management (EM)

    2 Radiological Release Event at the Waste Isolation Pilot Plant on February 14, 2014, report in Attachment F. Bibliography and References, are available on various public...

  15. Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response...

    Office of Environmental Management (EM)

    2 Radiological Release Event at the Waste Isolation Pilot Plant on February 14, 2014, report in Attachment F. Bibliography and References, are available on various public...

  16. Molten Nitrate Salt Development for Thermal Energy Storage in Parabolic Trough Solar Power Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJessework uses concrete7Modifications forTeresaMolecularES2008-54174 This

  17. Electrolyte salts for nonaqueous electrolytes

    DOE Patents [OSTI]

    Amine, Khalil; Zhang, Zhengcheng; Chen, Zonghai

    2012-10-09

    Metal complex salts may be used in lithium ion batteries. Such metal complex salts not only perform as an electrolyte salt in a lithium ion batteries with high solubility and conductivity, but also can act as redox shuttles that provide overcharge protection of individual cells in a battery pack and/or as electrolyte additives to provide other mechanisms to provide overcharge protection to lithium ion batteries. The metal complex salts have at least one aromatic ring. The aromatic moiety may be reversibly oxidized/reduced at a potential slightly higher than the working potential of the positive electrode in the lithium ion battery. The metal complex salts may also be known as overcharge protection salts.

  18. Customer interface document for the Molten Salt Test Loop (MSTL) system.

    SciTech Connect (OSTI)

    Pettit, Kathleen; Kolb, William J.; Gill, David Dennis; Briggs, Ronald D.

    2012-03-01

    The National Solar Thermal Test Facility at Sandia National Laboratories has a unique test capability called the Molten Salt Test Loop (MSTL) system. MSTL is a test capability that allows customers and researchers to test components in flowing, molten nitrate salt. The components tested can range from materials samples, to individual components such as flex hoses, ball joints, and valves, up to full solar collecting systems such as central receiver panels, parabolic troughs, or linear Fresnel systems. MSTL provides realistic conditions similar to a portion of a concentrating solar power facility. The facility currently uses 60/40 nitrate 'solar salt' and can circulate the salt at pressure up to 600psi, temperature to 585 C, and flow rate of 400-600GPM depending on temperature. The purpose of this document is to provide a basis for customers to evaluate the applicability to their testing needs, and to provide an outline of expectations for conducting testing on MSTL. The document can serve as the basis for testing agreements including Work for Others (WFO) and Cooperative Research and Development Agreements (CRADA). While this document provides the basis for these agreements and describes some of the requirements for testing using MSTL and on the site at Sandia, the document is not sufficient by itself as a test agreement. The document, however, does provide customers with a uniform set of information to begin the test planning process.

  19. Electrochromic Salts, Solutions, and Devices

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

    2008-10-14

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  20. Electrochromic salts, solutions, and devices

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky,7,064,212 T. Mark (Los Alamos, NM)

    2006-06-20

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  1. Electrochromic Salts, Solutions, and Devices

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

    2008-11-11

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  2. RECHARGEABLE MOLTEN-SALT CELLS

    E-Print Network [OSTI]

    Cairns, Elton J.

    2013-01-01

    polysulfide sodium/sulfur cell solid electrolyte Ti0 2ion conducting solid electrolyte would add flexibility forwith a combination of a solid electrolyte and a molten salt

  3. Plant salt-tolerance mechanisms

    SciTech Connect (OSTI)

    Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

    2014-06-01

    Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selection and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.

  4. Plant salt-tolerance mechanisms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

    2014-06-01

    Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selectionmore »and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.« less

  5. Status of the direct absorption receiver panel research experiment: Salt flow and solar test requirements and plans

    SciTech Connect (OSTI)

    Tyner, C.E.

    1989-03-01

    The Panel Research Experiment (PRE) is the first large-scale solar test of the molten nitrate salt direct absorption receiver (DAR) concept. The purpose of the PRE is to demonstrate the engineering feasibility and practicality of the DAR. We will conduct the test at the Central Receiver Test Facility in Albuquerque in two phases: salt flow testing and solar testing. This is a working document to define PRE test objectives and requirements, document the test hardware design, and define test plans. 13 refs., 12 figs., 1 tab.

  6. Formation mechanisms and quantification of organic nitrates in atmospheric aerosol

    E-Print Network [OSTI]

    Rollins, Andrew Waite

    2010-01-01

    and J. Viidanoja, Atmospheric chemistry of c 3 -c 6organic nitrates, Atmospheric Chemistry and Physics, 9 (4),organic aerosol yields, Atmospheric Chemistry and Physics

  7. Report seeks solutions for nitrate in drinking water

    E-Print Network [OSTI]

    Editors, By

    2012-01-01

    Nitrate in California’s Drinking Water report http://ANR Healthy Crops, Safe Water http://ucanr.edu/News/crops,_safe_water http://californiaagriculture.ucanr.edu •

  8. Nitrate Leaching from Intensive Fiber Production on Abandoned Agricultural Land

    SciTech Connect (OSTI)

    Williams, T.M.

    1999-01-01

    Paper outlines nitrate leaching results of loblolly pine and sweet gum that were grown with irrigation, continuous fertilization and insect pest control on a year old abandoned peanut field. Wells and tension lysimeters were used to measure nitrate in soil moisture and groundwater on three replicate transects for two years. Groundwater nitrate concentration beneath the minimum treatment was much higher than the maximum treatment and old field. All three treatments often exceeded the drinking water standard. Forest and lake edge had low levels while the soil moisture nitrate concentrations in the two plantation treatments were much higher than the old field.

  9. Structural Interactions within Lithium Salt Solvates: Acyclic...

    Office of Scientific and Technical Information (OSTI)

    Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters Citation Details In-Document Search Title: Structural Interactions within Lithium Salt Solvates:...

  10. Evaluation of ferrocyanide/nitrate explosive hazard

    SciTech Connect (OSTI)

    Cady, H.H.

    1992-06-01

    Los Alamos National Laboratory agreed to assist Pacific Northwest Laboratory in the Ferrocyanide Safety Evaluation Program by helping to evaluate the explosive hazard of several mixtures of simulated ferrocyanide waste-tank sludge containing sodium nitrite and sodium nitrate. This report is an evaluation of the small-scale safety tests used to assess the safety of these materials from an explosive point of view. These tests show that these materials are not initiated by mechanical insult, and they require an external heat source before any exothermic chemical reaction can be observed.

  11. Energetic Material - Electro Nitration - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansas NuclearElectronic StructureElyElectro Nitration Idaho National

  12. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two aromatic hydrocarbons, 17 nitrated PAHs (NPAHs) and 8 oxygenated PAHs (OPAHs) were carried out during hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic hydrocarbons

  13. SULFATE AND NITRATE COATINGS ON MINERAL DUSTS: CRYSTALLINE OR AQUEOUS?

    E-Print Network [OSTI]

    SULFATE AND NITRATE COATINGS ON MINERAL DUSTS: CRYSTALLINE OR AQUEOUS? Scot T. Martin, Hui Observational evidence shows that mineral dusts in Asian outflows become coated by sulfates and nitrates. Layer), and the asymmetry parameter. The aqueous coatings also provide milieu for aqueous chemical reactions

  14. Use of tensiometer for in situ measurement of nitrate leaching

    SciTech Connect (OSTI)

    Li, K.; Reddy, M.R.

    1999-07-01

    In order to monitor nitrate leaching from non-point source pollution, this study used tensiometers to measure in situ nitrate concentration and soil-moisture potential. Instead of filling the tensiometers with pure water, the study filled the tensiometers with nitrate ionic strength adjuster (ISA, 1 M (NH{sub 4}){sub 2}SO{sub 4}). After the installation of the tensiometers at various depths along soil profiles, a portable pressure transducer was used to measure the soil moisture potential, and a nitrate electrode attached to an ion analyzer was used to measure the nitrate concentration in situ. The measurement was continuous and non-destructive. To test this method in the laboratory, eight bottles filled with pure sand were treated with known nitrate solutions, and a tensiometer was placed in each bottle. Measurements were taken every day for 30 days. Laboratory test showed a linear relationship between the known nitrate concentration and the tensiometer readings (R{sup 2} = 0.9990). Then a field test was conducted in a watermelon field with green manure mulch. Field data indicated a potential of nitrate leaching below the soil depth of 100 cm when crop uptake of nutrients was low.

  15. GROUNDWATER NITRATE REMOVAL CAPACITY OF RIPARIAN ZONES IN

    E-Print Network [OSTI]

    Gold, Art

    GROUNDWATER NITRATE REMOVAL CAPACITY OF RIPARIAN ZONES IN URBANIZING WATERSHEDS BY TARA KIMBERLY the watershed, however, is not well understood. Nitrate in groundwater moving through the "biologically active and geomorphology of riparian zones, potentially changing riparian groundwater denitrification capacity. Little work

  16. River biogeochemistry and source identification of nitrate by means of

    E-Print Network [OSTI]

    Snow-melt r=0.67 n=14, pLandnutzung und 15N-NO3 0 50;Isotopensignaturen in Flüssen und Landnutzung 0 20 40 60 80 100 Nitrate from Farmland [%] 100 80 60 40 20 0 Kokemäenjoki Peene Vistula #12;Isotopensignaturen in Flüssen und Landnutzung 0 20 40 60 80 100 Nitrate from

  17. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.; Bonnesen, Peter V.

    2006-06-01

    The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of low-activity waste immobilization. Principles of ion recognition are being researched toward discovery of liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudohydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Studies at PNNL are directed toward new solvent formulation for the practical sodium pseudohydroxide extraction systems.

  18. BYU Salt Lake Center Financial Assistance

    E-Print Network [OSTI]

    Hart, Gus

    BYU Salt Lake Center Financial Assistance Program 2015 A financial assistance program of the Brigham Young University Division of Continuing Education BYU Salt Lake Center 345 West North Temple Street 3 Triad Center Salt Lake City, UT 84180 Fax: (801) 933­9456 Email: slc@byu.edu #12;BYU Salt Lake

  19. Removal of gadolinium nitrate from heavy water

    SciTech Connect (OSTI)

    Wilde, E.W.

    2000-03-22

    Work was conducted to develop a cost-effective process to purify 181 55-gallon drums containing spent heavy water moderator (D2O) contaminated with high concentrations of gadolinium nitrate, a chemical used as a neutron poison during former nuclear reactor operations at the Savannah River Site (SRS). These drums also contain low level radioactive contamination, including tritium, which complicates treatment options. Presently, the drums of degraded moderator are being stored on site. It was suggested that a process utilizing biological mechanisms could potentially lower the total cost of heavy water purification by allowing the use of smaller equipment with less product loss and a reduction in the quantity of secondary waste materials produced by the current baseline process (ion exchange).

  20. ARRAYS OF BOTTLES OF PLUTONIUM NITRATE SOLUTION

    SciTech Connect (OSTI)

    Margaret A. Marshall

    2012-09-01

    In October and November of 1981 thirteen approaches-to-critical were performed on a remote split table machine (RSTM) in the Critical Mass Laboratory of Pacific Northwest Laboratory (PNL) in Richland, Washington using planar arrays of polyethylene bottles filled with plutonium (Pu) nitrate solution. Arrays of up to sixteen bottles were used to measure the critical number of bottles and critical array spacing with a tight fitting Plexiglas® reflector on all sides of the arrays except the top. Some experiments used Plexiglas shells fitted around each bottles to determine the effect of moderation on criticality. Each bottle contained approximately 2.4 L of Pu(NO3)4 solution with a Pu content of 105 g Pu/L and a free acid molarity H+ of 5.1. The plutonium was of low 240Pu (2.9 wt.%) content. These experiments were sponsored by Rockwell Hanford Operations because of the lack of experimental data on the criticality of arrays of bottles of Pu solution such as might be found in storage and handling at the Purex Facility at Hanford. The results of these experiments were used “to provide benchmark data to validate calculational codes used in criticality safety assessments of [the] plant configurations” (Ref. 1). Data for this evaluation were collected from the published report (Ref. 1), the approach to critical logbook, the experimenter’s logbook, and communication with the primary experimenter, B. Michael Durst. Of the 13 experiments preformed 10 were evaluated. One of the experiments was not evaluated because it had been thrown out by the experimenter, one was not evaluated because it was a repeat of another experiment and the third was not evaluated because it reported the critical number of bottles as being greater than 25. Seven of the thirteen evaluated experiments were determined to be acceptable benchmark experiments. A similar experiment using uranyl nitrate was benchmarked as U233-SOL-THERM-014.

  1. Brayton Cycle Baseload Power Tower CSP System

    Broader source: Energy.gov [DOE]

    This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23–25, 2013 near Phoenix, Arizona.

  2. Fracture and Healing of Rock Salt Related to Salt Caverns

    SciTech Connect (OSTI)

    Chan, K.S.; Fossum, A.F.; Munson, D.E.

    1999-03-01

    In recent years, serious investigations of potential extension of the useful life of older caverns or of the use of abandoned caverns for waste disposal have been of interest to the technical community. All of the potential applications depend upon understanding the reamer in which older caverns and sealing systems can fail. Such an understanding will require a more detailed knowledge of the fracture of salt than has been necessary to date. Fortunately, the knowledge of the fracture and healing of salt has made significant advances in the last decade, and is in a position to yield meaningful insights to older cavern behavior. In particular, micromechanical mechanisms of fracture and the concept of a fracture mechanism map have been essential guides, as has the utilization of continuum damage mechanics. The Multimechanism Deformation Coupled Fracture (MDCF) model, which is summarized extensively in this work was developed specifically to treat both the creep and fracture of salt, and was later extended to incorporate the fracture healing process known to occur in rock salt. Fracture in salt is based on the formation and evolution of microfractures, which may take the form of wing tip cracks, either in the body or the boundary of the grain. This type of crack deforms under shear to produce a strain, and furthermore, the opening of the wing cracks produce volume strain or dilatancy. In the presence of a confining pressure, microcrack formation may be suppressed, as is often the case for triaxial compression tests or natural underground stress situations. However, if the confining pressure is insufficient to suppress fracture, then the fractures will evolve with time to give the characteristic tertiary creep response. Two first order kinetics processes, closure of cracks and healing of cracks, control the healing process. Significantly, volume strain produced by microfractures may lead to changes in the permeability of the salt, which can become a major concern in cavern sealing and operation. The MDCF model is used in three simulations of field experiments in which indirect measures were obtained of the generation of damage. The results of the simulations help to verify the model and suggest that the model captures the correct fracture behavior of rock salt. The model is used in this work to estimate the generation and location of damage around a cylindrical storage cavern. The results are interesting because stress conditions around the cylindrical cavern do not lead to large amounts of damage. Moreover, the damage is such that general failure can not readily occur, nor does the extent of the damage suggest possible increased permeation when the surrounding salt is impermeable.

  3. Salt Dynamics in Non-Riparian Freshwater Wetlands

    E-Print Network [OSTI]

    Stacey, Mark T

    2007-01-01

    Resources Center Project “Salt Dynamics in Non-RiparianTechnical Completion Report “Salt Dynamics in Non-Riparianindicate that the flux of salt between the soil and water

  4. Salt Stress in Desulfovibrio vulgaris Hildenborough: An integrated genomics approach

    E-Print Network [OSTI]

    Mukhopadhyay, Aindrila

    2010-01-01

    machinery against salt-induced damage in Synechococcus.Lactobacillus plantarum to salt and nonelectrolyte stress. Jregulation of acid, heat, and salt tolerance in Escherichia

  5. Reduction of Nitrate in Shewanella oneidensis depends on atypical...

    Office of Scientific and Technical Information (OSTI)

    deletion mutants, we propose that NapB is able to favor nitrate reduction by routing electrons to NapA exclusively. Authors: Gao, Haichun ; Yang, Zamin ; Barua, Soumitra ; Reed,...

  6. Formation mechanisms and quantification of organic nitrates in atmospheric aerosol

    E-Print Network [OSTI]

    Rollins, Andrew Waite

    2010-01-01

    the nitrate radical (no 3 ) with isoprene, 1,3-butadiene and2,3-dimethyl- 1,3-butadiene in air, Atmos. Environ. , 26A(Isoprene (2-methyl-1,3-butadiene) is globally the most

  7. Decontamination of water using nitrate selective ion exchange resin

    DOE Patents [OSTI]

    Lockridge, J.E.; Fritz, J.S.

    1990-07-31

    A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C[sub 3] or larger.

  8. Immobilization of sodium nitrate waste with polymers: Topical report

    SciTech Connect (OSTI)

    Franz, E.M.; Heiser, J.H. III; Colombo, P.

    1987-04-01

    This report describes the development of solidification systems for sodium nitrate waste. Sodium nitrate waste was solidified in the polymers polyethylene, polyester-styrene (PES), and water-extendible polyester-styrene (WEP). Evaluations were made of the properties of waste forms containing various amounts of sodium nitrate by leaching immersion in water, measuring compressive strengths and by the EPA Extraction Procedure. Results of the leaching test are presented as cumulative fraction leached (CFL), incremental leaching rate, and average leaching indices (LI). For waste forms containing 30 to 70 wt% sodium nitrate, the CFL ranged from 9.0 x 10/sup -3/ to 7.3 x 10/sup -1/ and the LI from 11 to 7.8. After ninety days immersion in water, the compressive strengths ranged from 720 psi to 2550 psi. The nitrate releases from these samples using the EPA Extraction Procedure were below 500 ppM. The nitrate releases from PES waste forms were similar to those from polyethylene waste forms at the same waste loadings. The compressive yield strengths, measured after ninety-day immersion in water, ranged between 2070 and 7710 psi. In the case of WEP waste forms, only 30 wt% loaded samples passed the immersion test. 23 refs., 24 figs., 12 tabs.

  9. Molten Salt-Carbon Nanotube Thermal Energy Storage for Concentrating Solar Power Systems Final Report

    SciTech Connect (OSTI)

    Michael Schuller; Frank Little; Darren Malik; Matt Betts; Qian Shao; Jun Luo; Wan Zhong; Sandhya Shankar; Ashwin Padmanaban

    2012-03-30

    We demonstrated that adding nanoparticles to a molten salt would increase its utility as a thermal energy storage medium for a concentrating solar power system. Specifically, we demonstrated that we could increase the specific heat of nitrate and carbonate salts containing 1% or less of alumina nanoparticles. We fabricated the composite materials using both evaporative and air drying methods. We tested several thermophysical properties of the composite materials, including the specific heat, thermal conductivity, latent heat, and melting point. We also assessed the stability of the composite material with repeated thermal cycling and the effects of adding the nanoparticles on the corrosion of stainless steel by the composite salt. Our results indicate that stable, repeatable 25-50% improvements in specific heat are possible for these materials. We found that using these composite salts as the thermal energy storage material for a concentrating solar thermal power system can reduce the levelized cost of electricity by 10-20%. We conclude that these materials are worth further development and inclusion in future concentrating solar power systems.

  10. Salt marsh geomorphology: Physical and ecological effects on landform Keywords: salt marsh geomorphology; AGU Chapman Conference

    E-Print Network [OSTI]

    Fagherazzi, Sergio

    Editorial Salt marsh geomorphology: Physical and ecological effects on landform Keywords: salt marsh geomorphology; AGU Chapman Conference Evidence that the three-dimensional structure of salt marsh, and the ratio of marsh edge:marsh interior have all been shown to affect the distribution and density of salt

  11. First Robert Stobie SALT Workshop Science with SALT Workshop Proceedings, Vol. 2, 2004

    E-Print Network [OSTI]

    Bershady, Matthew A.

    First Robert Stobie SALT Workshop Science with SALT Workshop Proceedings, Vol. 2, 2004 D.A.H. Buckley Galaxy Kinematics with SALT M. A. Bershady1, M. A. W. Verheijen2, D. R. Andersen3, R. A. Swaters4-gathering power of SALT coupled with the high-throughput performance of the Prime Focus Imaging Spec- trograph

  12. Prevention of Salt Damage inPrevention of Salt Damage in LimestoneLimestone

    E-Print Network [OSTI]

    Petta, Jason

    Prevention of Salt Damage inPrevention of Salt Damage in LimestoneLimestone Kathy Whitaker.jpg #12;Introduction: Sodium Sulfate Thenardite: Na2SO4 Mirabilite: Na2SO4·10H2O Salt exposure for 5 weeks the stone by capillary uptake of water containing the dissolved salt. Degradation of mortar. #12

  13. Great Salt Lake Basin Hydrologic Observatory

    E-Print Network [OSTI]

    Tarboton, David

    Great Salt Lake Basin Hydrologic Observatory Contact Information David Tarboton Utah State University of Utah 135 South 1460 East Rm 719 Salt Lake City, Utah (801) 581-5033 wjohnson. The Great Salt Lake Basin Hydrologic Observatory development team is highly committed to this concept

  14. 2013 -2014 SALT Center SCHOLARSHIP AWARD APPLICATION

    E-Print Network [OSTI]

    Watkins, Joseph C.

    2013 - 2014 SALT Center SCHOLARSHIP AWARD APPLICATION Deadline: March 1, 2013 Scholarship Awards of the candidate. (Factors considered: FAFSA, GPA, SALT Center usage) Scholarship Awards are based upon available funds. Scholarship Awards apply to SALT Center program fees only. Scholarship Application materials

  15. Salt in Dutchess Co. Waters Stuart Findlay

    E-Print Network [OSTI]

    Berkowitz, Alan R.

    Salt in Dutchess Co. Waters Stuart Findlay Vicky Kelly Where are we now? Compared to what? Where or Groundwater? STREAM · Road salt biggest source ­ others? #12;SOIL CORES HOLD Cl LONGER THAN WATER Kincaid be increasing · What else is coming along? #12;Scope for Action · Reduced Salt is in Everyone's Interest

  16. Thermophysical properties of reconsolidating crushed salt.

    SciTech Connect (OSTI)

    Bauer, Stephen J.; Urquhart, Alexander

    2014-03-01

    Reconsolidated crushed salt is being considered as a backfilling material placed upon nuclear waste within a salt repository environment. In-depth knowledge of thermal and mechanical properties of the crushed salt as it reconsolidates is critical to thermal/mechanical modeling of the reconsolidation process. An experimental study was completed to quantitatively evaluate the thermal conductivity of reconsolidated crushed salt as a function of porosity and temperature. The crushed salt for this study came from the Waste Isolation Pilot Plant (WIPP). In this work the thermal conductivity of crushed salt with porosity ranging from 1% to 40% was determined from room temperature up to 300oC, using two different experimental methods. Thermal properties (including thermal conductivity, thermal diffusivity and specific heat) of single-crystal salt were determined for the same temperature range. The salt was observed to dewater during heating; weight loss from the dewatering was quantified. The thermal conductivity of reconsolidated crushed salt decreases with increasing porosity; conversely, thermal conductivity increases as the salt consolidates. The thermal conductivity of reconsolidated crushed salt for a given porosity decreases with increasing temperature. A simple mixture theory model is presented to predict and compare to the data developed in this study.

  17. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.; Bryan, Jeffrey C.; Bonnesen, Peter V.

    1999-06-01

    The objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of major sodium salts from alkaline high-level wastes stored in underground tanks at Hanford, Savannah River, and Oak Ridge sites. Disposal of high level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Since the residual bulk chemicals must still undergo expensive treatment and disposal after most of the hazardous radionuclides have been removed, large cost savings will result from processes that reduce the overall waste volume. It is proposed that major cost savings can be expected if sodium hydroxide needed for sludge washing can be obtained from the waste itself, thus avoiding the addition of yet another bulk chemical to the waste and still further increase of the waste volume and disposal cost. Secondary priority is given to separating potassium an d abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  18. Analytical Characterization of the Thorium Nitrate Stockpile

    SciTech Connect (OSTI)

    Mattus, CH

    2003-12-30

    For several years, Oak Ridge National Laboratory (ORNL) has been supporting the Defense Logistics Agency-Defense National Stockpile Center with stewardship of a thorium nitrate (ThN) stockpile. The effort for fiscal year 2002 was to prepare a sampling and analysis plan and to use the activities developed in the plan to characterize the ThN stockpile. The sampling was performed in June and July 2002 by RWE NUKEM with oversight by ORNL personnel. The analysis was performed by Southwest Research Institute of San Antonio, Texas, and data validation was performed by NFT, Inc., of Oak Ridge, Tennessee. Of the {approx} 21,000 drums in the stockpile, 99 were sampled and 53 were analyzed for total metals composition, radiological constituents (using alpha and gamma spectrometry), and oxidizing characteristics. Each lot at the Curtis Bay Depot was sampled. Several of the samples were also analyzed for density. The average density of the domestic ThN was found to be 1.89 {+-} 0.08 g/cm{sup 3}. The oxidizer test was performed following procedures issued by the United Nations in 1999. Test results indicated that none of the samples tested was a Division 5.1 oxidizer per Department of Transportation definition. The samples were analyzed for total metals following the U.S. Environmental Protection Agency methods SW-846-6010B and 6020 (EPA 2003) using a combination of inductively coupled plasma--atomic emission spectroscopy and inductively coupled plasma--mass spectroscopy techniques. The results were used to compare the composition of the eight Resource Conservation and Recovery Act metals present in the sample (arsenic, barium, cadmium, chromium, lead, mercury, selenium, and silver) to regulatory limits. None of the samples was found to be hazardous for toxicity characteristics. The radiological analyses confirmed, when possible, the results obtained by the inductively coupled plasma analyses. These results--combined with the historical process knowledge acquired on the material and the results of previous tests--classified the ThN as low-level radioactive waste for disposal purposes. This characterization was necessary to continue the efforts associated with disposition of the material at the Nevada Test Site, Mercury, Nevada. With the current work presented in this report, the analytical characterization phase is completed for this source material stockpile.

  19. Thorium Nitrate Stockpile--From Here to Eternity

    SciTech Connect (OSTI)

    Hermes, W. H.; Hylton, T. D.; Mattus, C.H.; Storch, S. N.; Singley, P.S.; Terry. J. W.; Pecullan, M.; Reilly, F. K.

    2003-02-26

    The Defense National Stockpile Center (DNSC), a field level activity of the Defense Logistics Agency (DLA) has stewardship of a stockpile of thorium nitrate that has been in storage for decades. The stockpile is made up of approximately 3.2 million kg (7 million lb) of thorium nitrate crystals (hydrate form) stored at two depot locations in the United States. DNSC sought technical assistance from Oak Ridge National Laboratory (ORNL) to define and quantify the management options for the thorium nitrate stockpile. This paper describes methodologies and results comprising the work in Phase 1 and Phase 2. The results allow the DNSC to structure and schedule needed tasks to ensure continued safe long-term storage and/or phased disposal of the stockpile.

  20. Groundwater nitrates in the Seymour Aquifer: problem or resource? 

    E-Print Network [OSTI]

    Arreola-Triana, Alejandra

    2012-01-01

    stream_source_info Groundwater nitrates in the seymour aquifer.pdf.txt stream_content_type text/plain stream_size 7802 Content-Encoding ISO-8859-1 stream_name Groundwater nitrates in the seymour aquifer.pdf.txt Content-Type text.../plain; charset=ISO-8859-1 24 tx H2O Fall 2012 Story by Alejandra Arreola-Triana In the Rolling Plains of Texas, the Seymour Aquifer is the major source of water for Haskell, Jones and Knox counties. ?e water from the Seymour Aquifer, however...

  1. STRUCTURE OF PENTAKIS (UREA) DIOXOURANIUM(VI)NITRATE LUO2 (OC (NH2)2)5 (NO3) 2

    E-Print Network [OSTI]

    Zalkin, Allan

    2011-01-01

    DIFfERENCES (ALL f(O,O.t» URANYL UREA NITRATE FOB AND FCASTRUCTURE FACTORS CONTINUEC URANYL ~REA NITRATE L FO~ FAG! SFACTORS CO~TINUE& FOf URANYL UREA NITRATE l F[) B PAGE . ,

  2. Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard reference material 1649a (urban dust) and

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard nitrated polycylic aromatic hydrocarbons (NPAHs) and 9 oxygenated polycylic aromatic hydrocarbons (OPAHs aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic

  3. Prenatal Exposure to Nitrates, Nitrites, and Nitrosatable Drugs and Preterm Births 

    E-Print Network [OSTI]

    Vuong, Ann Minh

    2013-10-28

    , we examined the relation between preterm births and: 1) prenatal nitrosatable drug usage; 2) dietary intake of nitrates/nitrites; 3) joint exposures to nitrosatable drugs and nitrate/nitrite intake; and 4) nitrosatable drugs and vitamin C intake among...

  4. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two;2 Abstract The size distribution of polycyclic aromatic hydrocarbons (PAHs) and PAH derivatives of compounds. Keywords: Polycyclic aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated

  5. Interior cavern conditions and salt fall potential

    SciTech Connect (OSTI)

    Munson, D.E.; Molecke, M.A. [Sandia National Labs., Albuquerque, NM (United States); Myers, R.E. [Strategic Petroleum Reserve, New Orleans, LA (United States)

    1998-03-01

    A relatively large number of salt caverns are used for fluid hydrocarbon storage, including an extensive set of facilities in the Gulf Coast salt domes for the Strategic Petroleum Reserve (SPR) Program. Attention is focused on the SPR caverns because of available histories that detail events involving loss and damage of the hanging string casing. The total number of events is limited, making the database statistically sparse. The occurrence of the events is not evenly distributed, with some facilities, and some caverns, more susceptible than others. While not all of these events could be attributed to impacts from salt falls, many did show the evidence of such impacts. As a result, a study has been completed to analyze the potential for salt falls in the SPR storage caverns. In this process, it was also possible to deduce some of the cavern interior conditions. Storage caverns are very large systems in which many factors could possibly play a part in casing damage. In this study, all of the potentially important factors such as salt dome geology, operational details, and material characteristics were considered, with all being logically evaluated and most being determined as secondary in nature. As a result of the study, it appears that a principal factor in determining a propensity for casing damage from salt falls is the creep and fracture characteristics of salt in individual caverns. In addition the fracture depends strongly upon the concentration of impurity particles in the salt. Although direct observation of cavern conditions is not possible, the average impurity concentration and the accumulation of salt fall material can be determined. When this is done, there is a reasonable correlation between the propensity for a cavern to show casing damage events and accumulation of salt fall material. The accumulation volumes of salt fall material can be extremely large, indicating that only a few of the salt falls are large enough to cause impact damage.

  6. Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity

    SciTech Connect (OSTI)

    West, J. Palmer; Hwu, Shiou-Jyh

    2012-11-15

    The synthesis and structural features of a newly emerged class of salt-inclusion solids (SISs) are reviewed. The descriptive chemistry with respect to the role of ionic salt and its correlation with bulk noncentrosymmetricity and polarity of the covalent oxide lattice in question is discussed by means of structure analysis. These unprecedented discoveries have opened doors to novel materials synthesis via the utilities of salt-inclusion chemistry (SIC) that are otherwise known as the molten-salt approach. The result of these investigations prove that the bulk acentricity, or cancellation of which, can be accounted for from the perspective of ionic and/or salt lattices. Highlights: Black-Right-Pointing-Pointer Synthesis and structure of newly emerged salt-inclusion solids are reviewed. Black-Right-Pointing-Pointer Salt lattice and its symmetry correlation with polar framework are discussed. Black-Right-Pointing-Pointer Preservation of acentricity is accounted for from the perspective of ionic and salt lattices.

  7. Independent Oversight Assessment, Salt Waste Processing Facility...

    Broader source: Energy.gov (indexed) [DOE]

    Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility Project The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight),...

  8. Granular Salt Summary: Reconsolidation Principles and Applications

    SciTech Connect (OSTI)

    Hansen, Frank; Popp, Till; Wieczorek, Klaus; Stührenberg, Dieter

    2014-07-01

    The purposes of this paper are to review the vast amount of knowledge concerning crushed salt reconsolidation and its attendant hydraulic properties (i.e., its capability for fluid or gas transport) and to provide a sufficient basis to understand reconsolidation and healing rates under repository conditions. Topics covered include: deformation mechanisms and hydro-mechanical interactions during reconsolidation; the experimental data base pertaining to crushed salt reconsolidation; transport properties of consolidating granulated salt and provides quantitative substantiation of its evolution to characteristics emulating undisturbed rock salt; and extension of microscopic and laboratory observations and data to the applicable field scale.

  9. Electrolytic orthoborate salts for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles Austen (Mesa, AZ); Xu, Wu (Tempe, AZ)

    2008-01-01

    Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

  10. Electrolytic orthoborate salts for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles Austen [Mesa, AZ; Xu, Wu [Tempe, AZ

    2009-05-05

    Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

  11. Multiphase Flow and Cavern Abandonment in Salt

    SciTech Connect (OSTI)

    Ehgartner, Brian; Tidwell, Vince

    2001-02-13

    This report will explore the hypothesis that an underground cavity in gassy salt will eventually be gas filled as is observed on a small scale in some naturally occurring salt inclusions. First, a summary is presented on what is known about gas occurrences, flow mechanisms, and cavern behavior after abandonment. Then, background information is synthesized into theory on how gas can fill a cavern and simultaneously displace cavern fluids into the surrounding salt. Lastly, two-phase (gas and brine) flow visualization experiments are presented that demonstrate some of the associated flow mechanisms and support the theory and hypothesis that a cavity in salt can become gas filled after plugging and abandonment

  12. SEN3: Potentiometric Nitrate Sensors in the Form of Plant Roots

    E-Print Network [OSTI]

    Tatyana Bendikov (UCLA); Nicole Jurisch (U Wash); Mallory Davidson (U Wash); Thomas Harmon (UCM)

    2005-01-01

    cadmium reactant) Potentiometric Response for NO 3 Ion Electrochemical deposition (constant current conditions) of polypyrrole dopped with nitrate

  13. A High-Performance Micromachined Amperometric Nitrate Sensor for Environmental Monitoring (SEN 8)

    E-Print Network [OSTI]

    Dohyun Kim; Ira B. Goldberg; Michael Glickman; Jack W. Judy

    2006-01-01

    0.038× 10 -3 cm 2 ) • polyimide insulation layer Nitratespecies when nitrate is Polyimide not present - PO 43- , Ca

  14. Molten Salt Power Tower Cost Model for the System Advisor Model (SAM)

    SciTech Connect (OSTI)

    Turchi, C. S.; Heath, G. A.

    2013-02-01

    This report describes a component-based cost model developed for molten-salt power tower solar power plants. The cost model was developed by the National Renewable Energy Laboratory (NREL), using data from several prior studies, including a contracted analysis from WorleyParsons Group, which is included herein as an Appendix. The WorleyParsons' analysis also estimated material composition and mass for the plant to facilitate a life cycle analysis of the molten salt power tower technology. Details of the life cycle assessment have been published elsewhere. The cost model provides a reference plant that interfaces with NREL's System Advisor Model or SAM. The reference plant assumes a nominal 100-MWe (net) power tower running with a nitrate salt heat transfer fluid (HTF). Thermal energy storage is provided by direct storage of the HTF in a two-tank system. The design assumes dry-cooling. The model includes a spreadsheet that interfaces with SAM via the Excel Exchange option in SAM. The spreadsheet allows users to estimate the costs of different-size plants and to take into account changes in commodity prices. This report and the accompanying Excel spreadsheet can be downloaded at https://sam.nrel.gov/cost.

  15. An Unexpected Nitrate Decline in New Hampshire Streams

    E-Print Network [OSTI]

    Goodale, Christine L.

    An Unexpected Nitrate Decline in New Hampshire Streams Christine L. Goodale,1 * John D. Aber,1 and Peter M. Vitousek2 1 Complex Systems Research Center, University of New Hampshire, Durham, New Hampshire stands on Mount Moosilauke, New Hampshire (Vi- tousek and Reiners 1975; Bioscience 25:376­381). We

  16. Predicting Ground Water Nitrate Concentration from Land Use

    E-Print Network [OSTI]

    Vogel, Richard M.

    to assess the effects of land use on ground water quality. Exploratory data analysis was applied to historic-foot radius of a well are reliable predictors of nitrate concentration in ground water. Similarly with highly permeable materials to evaluate potential effects of development on ground water quality

  17. VOCs, Pesticides, Nitrate, and Their Mixtures in Groundwater Used for

    E-Print Network [OSTI]

    VOCs, Pesticides, Nitrate, and Their Mixtures in Groundwater Used for Drinking Water in the United, Rapid City, South Dakota 57702 Samples of untreated groundwater from 1255 domestic drinking-water wells of the groundwater resource and, thus, were distributed geographically across large aquifers, primarily in rural

  18. WHAT CAUSES NITRATE CONTAMINATION? While there are several potential sources, the three most common are

    E-Print Network [OSTI]

    Radcliffe, David

    WHAT CAUSES NITRATE CONTAMINATION? While there are several potential sources, the three most common. Contamination problems occur when nitrate from these sources is overapplied to lawns, gardens, crop land contamination. Septic systems are another source of nitrate found in well water. Septic systems that have been

  19. Study of nitrate stress in Desulfovibrio vulgaris Hildenborough using iTRAQ

    E-Print Network [OSTI]

    Hazen, Terry

    tagging; nitrate INTRODUCTION Anaerobic sulphate-reducing bacteria (SRB) such as Desulfovibrio vulgaris The response of Desulfovibrio vulgaris Hildenborough (DvH), a sulphate-reducing bacterium, to nitrate stress as in iron^sulphur-cluster-containing proteins, however, appear to be specific to nitrate exposure. Finally

  20. MICHIGAN'S SOIL NITRATE TEST FOR CORN MSU SOIL AND PLANT NUTRIENT LAB

    E-Print Network [OSTI]

    Isaacs, Rufus

    MICHIGAN'S SOIL NITRATE TEST FOR CORN MSU SOIL AND PLANT NUTRIENT LAB Michigan State University Extension Crop and Soil Sciences Department Michigan State University WHY TEST SOIL FOR NITRATES Nitrate testing of soil is an excellent and inexpensive way of evaluating the available nitrogen (N) status

  1. NITRATE MOVEMENT IN SOUTHEASTERN COASTAL PLAIN SOILS UNDER CONSERVATION-TILLED VEGETABLE PRODUCTION

    E-Print Network [OSTI]

    Decoteau, Dennis R.

    NITRATE MOVEMENT IN SOUTHEASTERN COASTAL PLAIN SOILS UNDER CONSERVATION-TILLED VEGETABLE PRODUCTION G.D. Hoyt1 , D.C. Sanders2 , J.T. D.R. Decoteau3 , ABSTRACT Movement of soil nitrates by leaching. This study measured soil nitrate-N with depth at planting and after cucumber harvest at Clinton, NC, Florence

  2. Supplementary Figure S1 Additional characterization of salt responses of [Low] and [High] responsive salt cells.

    E-Print Network [OSTI]

    Faraon, Andrei

    Supplementary Figure S1 Additional characterization of salt responses of [Low] and [High] responsive salt cells. (a) Diagram illustrating the imaging preparation (see Methods for details). Taste buds.e.m. dF/F responses for the [Low] and [High] salt-responding cells (n3). (c) TRCs activated by low

  3. Occurrence Reporting and Processing System (ORPS)- Potential for the Presence of Untreated Nitrate Waste Salts in TRU Waste Packages

    Office of Energy Efficiency and Renewable Energy (EERE)

    Supporting Technical Document for the Radiological Release Accident Investigation Report (Phase II Report)

  4. Metal salt catalysts for enhancing hydrogen spillover

    SciTech Connect (OSTI)

    Yang, Ralph T; Wang, Yuhe

    2013-04-23

    A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

  5. New selective anion-exchange resins for nitrate removal from contaminated drinking water and studies on analytical anion-exchange chromatography

    SciTech Connect (OSTI)

    Lockridge, J.E.

    1989-01-01

    Phosphonium resins and ammonium resins of composition resin-R{sub 3}P{sup +}A{sup {minus}} where R is varied from methyl to pentyl were evaluated for nitrate/sulfate selectivity, capacity and nitrate decontamination of drinking water. Phosphonium resins were found to be more nitrate selective and have higher capacities than ammonium resins. A mixed bed process, where nitrate removal and water softening is accomplished in a single column, was also evaluated. A small piece of silver wire, coated with an insoluble silver salt, works well as a selective potentiometric detector for halide ions in ion chromatography. A silver-silver chloride electrode was found to be a selective and reproducible detector for chloride, bromide, iodide, thiocyanate and thiosulfate anions separated by ion chromatography. Calibration curves were non-linear and had slopes ranging from 40 to 60 mV/log concentrations. A working range of 0.05 to 2 mM was used. Two methods for the determination of aluminum by anion chromatography are presented. In the first method, a standard excess of fluoride ion is added to the sample. Evidence is given for the formation of a strong complex of neutral aluminum trifluoride which elutes very quickly from an anion exchange column. The excess fluoride is retained and can be determined. The aluminum concentration can then be related to the difference in fluoride peak height between the sample and standard. In a second method, Al(III) is determined directly by anion chromatography when sodium phthalate is used as an eluent. It was found that Al(III)-phthalate complexes thus formed would show some retention on an anion exchange column. The method is uniquely insensitive to the presence of many foreign cations. Al(III) was successfully determined, by this method, in a 40-fold molar excess of iron(III).

  6. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2001-06-01

    Disposal of high-level nuclear waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  7. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2000-06-01

    Disposal of high- level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid- liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  8. Neutrinoless Double Beta Decay in Light of SNO Salt Data

    E-Print Network [OSTI]

    Murayama, Hitoshi

    2009-01-01

    Beta Decay in Light of SNO Salt Data Hitoshi Murayama andBeta Decay in Light of SNO Salt Data Hitoshi Murayama ? andIn the SNO data from its salt run, probably the most signi?

  9. THERMAL GRADIENT MIGRATION OF BRINE INCLUSIONS IN SALT

    E-Print Network [OSTI]

    Yagnik, S.K.

    2010-01-01

    OF BRINE INCLUSIONS IN SALT Suresh K. Yagnik February 1982 TOF BRINE INCLUSIONS IN SALT by Suresh K. Yagnik Materialsb u i l t in future. The salt deposits, however, are known

  10. THE MECHANISM OF INTRAGRANULAR MIGRATION OF BRINE INCLUSIONS IN SALT

    E-Print Network [OSTI]

    Machiels, A.J.

    2010-01-01

    of Brine Inclusions in a Salt Repository", ORM. -5526 (JulyOF BRINE INCLUSIONS IN SALT A.J. Machiels, S. Yagnik, D.R.OF BRINE INCLUSIONS IN SALT by A.J. Machiels S. Yagnik D.R.

  11. Advances in alleviating growth limitations of maize under salt stress

    E-Print Network [OSTI]

    Schubert, Sven

    2009-01-01

    during the first phase of salt stress. J. Appl. Bot. 2004;during the first phase of salt stress. J. Plant Nutr. SoilC, Hartung W, Schubert S. Salt resistance is determined by

  12. Solar Policy Environment: Salt Lake

    Broader source: Energy.gov [DOE]

    The overall objective of the “Solar Salt Lake” (SSL) team is to develop a fully-scoped city and county-level implementation plan that will facilitate at least an additional ten megawatts of solar photovoltaic (PV) installations in the government, commercial, industrial, and residential sectors by 2015. To achieve this aggressive goal, the program strategy includes a combination of barrier identification, research, and policy analysis that utilizes the input of various stakeholders. Coupled with these activities will be the development and implementation of pilot installations in the government and residential sectors, and broad outreach to builders and potential practitioners of solar energy products in the process. In this way, while creating mechanisms to enable a demand for solar, SSL will also facilitate capacity building for suppliers, thereby helping to ensure long-term sustainability for the regional market.

  13. DOE - Office of Legacy Management -- Penn Salt Manufacturing...

    Office of Legacy Management (LM)

    Salt Manufacturing Co Whitemarsh Research Laboratories - PA 20 FUSRAP Considered Sites Site: PENN SALT MANUFACTURING CO., WHITEMARSH RESEARCH LABORATORIES (PA.20) Eliminated from...

  14. Development of Molten-Salt Heat Trasfer Fluid Technology for...

    Energy Savers [EERE]

    Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar...

  15. EIA - Natural Gas Pipeline Network - Salt Cavern Storage Reservoir...

    U.S. Energy Information Administration (EIA) Indexed Site

    Salt Cavern Storage Reservoir Configuration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates Salt Cavern...

  16. Hybrid Polymer/Lipid Vesicles via Salt and Agitation Induced...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Hybrid PolymerLipid Vesicles via Salt and Agitation Induced Fusion. Citation Details In-Document Search Title: Hybrid PolymerLipid Vesicles via Salt and...

  17. Energy Department Completes Salt Coolant Material Transfer to...

    Office of Environmental Management (EM)

    Completes Salt Coolant Material Transfer to Czech Republic for Advanced Reactor Research Energy Department Completes Salt Coolant Material Transfer to Czech Republic for Advanced...

  18. Microsoft Word - UFD-salt-testing-technical-baseline-FCRD-UFD...

    Energy Savers [EERE]

    pressure, room closure, salt permeability, salt resistivity, active and passive seismic, self-potential, and gas-generation were all being observed during the...

  19. Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Anions for Lithium Salts and Ionic Liquids for Lithium Battery Electrolytes Inexpensive, Nonfluorinated Anions for Lithium Salts and Ionic Liquids for Lithium Battery Electrolytes...

  20. Correlation of Creep Behavior of Domal Salts

    SciTech Connect (OSTI)

    Munson, D.E.

    1999-02-16

    The experimentally determined creep responses of a number of domal salts have been reported in, the literature. Some of these creep results were obtained using standard (conventional) creep tests. However, more typically, the creep data have come from multistage creep tests, where the number of specimens available for testing was small. An incremental test uses abrupt changes in stress and temperature to produce several time increments (stages) of different creep conditions. Clearly, the ability to analyze these limited data and to correlate them with each other could be of considerable potential value in establishing the mechanical characteristics of salt domes, both generally and specifically. In any analysis, it is necessary to have a framework of rules to provide consistency. The basis for the framework is the Multimechanism-Deformation (M-D) constitutive model. This model utilizes considerable general knowledge of material creep deformation to supplement specific knowledge of the material response of salt. Because the creep of salt is controlled by just a few micromechanical mechanisms, regardless of the origin of the salt, certain of the material parameters are values that can be considered universal to salt. Actual data analysis utilizes the methodology developed for the Waste Isolation Pilot Plant (WIPP) program, and the response of a bedded pure WIPP salt as the baseline for comparison of the domal salts. Creep data from Weeks Island, Bryan Mound, West Hackberry, Bayou Choctaw, and Big Hill salt domes, which are all sites of Strategic Petroleum Reserve (SPR) storage caverns, were analyzed, as were data from the Avery Island, Moss Bluff, and Jennings salt domes. The analysis permits the parameter value sets for the domal salts to be determined in terms of the M-D model with various degrees of completeness. In turn this permits detailed numerical calculations simulating cavern response. Where the set is incomplete because of the sparse database, reasonable assumptions permit the set to be completed. From the analysis, two distinct response groups were evident, with the salts of one group measurably more creep resistant than the other group. Interestingly, these groups correspond well with the indirectly determined creep closure of the SPR storage caverns, a correlation that probably should be expected. Certainly, the results suggest a simple laboratory determination of the creep characteristics of a salt material from a dome site can indicate the relative behavior of any potential cavern placed within that dome.

  1. Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Lin, Y.

    1998-06-23

    A method is described for extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process. 7 figs.

  2. Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Lin, Yuehe (Moscow, ID)

    1998-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent is described. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  3. Combined Utilization of Cation Exchanger and Neutral Receptor to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.

    2004-03-29

    In this report, novel approaches to the selective liquid-liquid extraction separation of sodium hydroxide and sodium nitrate from high-level alkaline tank waste will be discussed. Sodium hydroxide can be successfully separated from alkaline tank-waste supernatants by weakly acidic lipophilic hydroxy compounds via a cation-exchange mechanism referred to as pseudo hydroxide extraction. In a multi-cycle process, as sodium hydroxide in the aqueous phase becomes depleted, it is helpful to have a neutral sodium receptor in the extraction system to exploit the high nitrate concentration in the waste solution to promote sodium removal by an ion-pair extraction process. Simultaneous utilization of an ionizable organic hydroxy compound and a neutral extractant (crown ether) in an organic phase results in the synergistic enhancement of ion exchange and improved separation selectivity due to the receptor's strong and selective sodium binding. Moreover, combination of the hydroxy compound and the crown ether provides for mutually increased solubility, even in a non-polar organic solvent. Accordingly, application of Isopar{reg_sign} L, a kerosene-like alkane solvent, becomes feasible. This investigation involves examination of such dual-mechanism extraction phases for sodium extraction from simulated and actual salt cake waste solutions. Sodium salts can be regenerated upon the contact of the loaded extraction phases with water. Finally, conditions of potential extraction/strip cycling will be discussed.

  4. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.; Lumetta, Gregg J.

    2004-06-30

    In this project, now completing its third year of its second renewal period, a collaborative project involving Oak Ridge National Laboratory, Pacific Northwest National Laboratory, and the University of North Texas has been addressing outstanding questions regarding the separation of the bulk sodium constituents of alkaline tank waste. The principal potential benefit of this research is a major reduction in the volume of radioactive tank waste, obviating the building of expensive new tanks and reducing the costs of vitrification. As a general approach, principles of ion recognition are being explored toward discovery and basic understanding of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium salts from waste-like matrices. Questions being addressed pertain to applicable extraction equilibria and how extraction properties relate to extractant structure. Progress has included the elucidation of the promising concept of pseudo hydroxide extraction (PHE), demonstration of crown-ether synergized PHE, demonstration of combined sodium hydroxide/sodium nitrate separation, and synthesis of novel ditopic receptors for ditopic PHE. In future efforts (pending renewal), a thermochemical study of PHE relating extractant acidity to extraction strength is proposed, and this study will be extended to systems containing crown ethers, including proton-ionizable ones. A series of crown ethers will be synthesized for this purpose and to investigate the extraction of bulk sodium salts (e.g., nitrate, nitrite, and sulfate), possibly in combination with sodium hydroxide. Simple proof-of-principle tests with real tank waste at PNNL will provide feedback toward solvent designs that have desirable properties. In view of the upcoming milestone of completion of the second renewal period, this report will, in addition to providing a summary of the past year's progress, summarize all of the work completed since the start of this project.

  5. Examination of Liquid Fluoride Salt Heat Transfer

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L

    2014-01-01

    The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

  6. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.; Bonnesen, Peter V.

    2005-06-01

    The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of low-activity waste immobilization. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudohydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

  7. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Bonnesen, Peter V.; Custelcean, Radu; Delmau, Laetitia H.; Engle, Nancy L.; Kang, Hyun-Ah; Keever, Tamara J.; Marchand, Alan P.; Gadthula, Srinivas; Gore, Vinayak K.; Huang, Zilin; Sivappa, Rasapalli; Tirunahari, Pavan K.; Levitskaia, Tatiana G.; Lumetta, Gregg J.

    2005-09-26

    The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of vitrification. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudo hydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

  8. Seasonal variations in N and O isotopes of nitrate in snow at Summit, Greenland: Implications for the study of nitrate in snow and ice cores

    E-Print Network [OSTI]

    Sigman, Daniel M.

    Seasonal variations in N and O isotopes of nitrate in snow at Summit, Greenland: Implications for the study of nitrate in snow and ice cores Meredith G. Hastings Department of Geosciences, Princeton measured in snow and firn from Summit, Greenland. The 15 N/14 N and 18 O/16 O ratios of NO3 À in recently

  9. Director, Salt Waste Processing Facility Project Office

    Broader source: Energy.gov [DOE]

    This position is located within The Department of Energy (DOE) Savannah River (SR) Operations Office, Salt Waste Processing Facility Project Office (SWPFPO). SR is located in Aiken, South Carolina....

  10. Determining Salt Tolerance Among Sunflower Genotypes 

    E-Print Network [OSTI]

    Masor, Laura Lee

    2012-02-14

    Crop lands around the world are becoming more salt-affected due to natural processes and agricultural practices. Due to this increase of salinization, acquisition of saline tolerant germplasm for breeding purposes is becoming a priority. Although...

  11. Advanced heat exchanger development for molten salts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sabharwall, Piyush; Clark, Denis; Glazoff, Michael; Zheng, Guiqiu; Sridharan, Kumar; Anderson, Mark

    2014-12-01

    This study addresses present work concerned with advanced heat exchanger development for molten salt in nuclear and non nuclear thermal systems. The molten salt systems discussed herein use alloys, such as Hastelloy N and 242, which show corrosion resistance to molten salt at nominal operating temperatures up to 700°C. These alloys were diffusion welded, and the corresponding information is presented. Test specimens were prepared for exposing diffusion welds to molten salt environments. Hastelloy N and 242 were found to be weldable by diffusion welding, with ultimate tensile strengths about 90% of base metal values. Both diffusion welds and sheet materialmore »in Hastelloy N were corrosion tested in?58 mol% KF and 42 mol% ZrF4 at 650, 700, and 850°C for 200, 500, and 1,000 hours. Corrosion rates found were similar between welded and nonwelded materials, typically « less

  12. Molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, William A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA); Pruneda, Cesar O. (Livermore, CA)

    1995-01-01

    A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor.

  13. The Effect of Salt Water on Rice. 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1909-01-01

    NO. izz. June, 1909. THE EFFECT OF SALT WATE ON RICE, LAPS, Che Postoffice College Station, 1 --- Texas. TEXAS AGRICULTURAL EXPERIMENT S I'ATIONS. OFFICERS. GOVERNING BOARD. (Board of Directors A. and M. College..., Texas. Reports and bulletins are sent upon application to the Director. The Effect of Salt Water on Rice. . ...... By G. S. FRAPS. At some of the rice farms located near the coast, the amount of water lxml~etl is sometimes greater than...

  14. SchoolFEFLOW Exercise Salt Intrusion From Top

    E-Print Network [OSTI]

    Kornhuber, Ralf

    Summer SchoolFEFLOW® Exercise Salt Intrusion From Top Vertical cross section #12;Summer SchoolSalt refinement (via Rubberbox and Border Options) FEFLOW Mesh Generation Height approx. 100 m #12;Summer SchoolSalt time stepping, FE/BE time integration Final time: 36500 days (100 years) #12;Summer SchoolSalt

  15. SALT--Structured Assertion Language for Temporal Logic

    E-Print Network [OSTI]

    Cengarle, María Victoria

    SALT--Structured Assertion Language for Temporal Logic Andreas Bauer, Martin Leucker , and Jonathan,leucker,streit}@informatik.tu-muenchen.de Abstract. This paper presents Salt. Salt is a general purpose speci- fication and assertion language other formalisms used for temporal specification of properties, Salt does not target a specific domain

  16. SALT---Structured Assertion Language for Temporal Logic

    E-Print Network [OSTI]

    Leucker, Martin

    SALT---Structured Assertion Language for Temporal Logic Andreas Bauer, Martin Leucker,leucker,streit}@informatik.tu­muenchen.de Abstract. This paper presents Salt. Salt is a general purpose speci­ fication and assertion language other formalisms used for temporal specification of properties, Salt does not target a specific domain

  17. Salt Concentration Differences Alter Membrane Resistance in Reverse Electrodialysis Stacks

    E-Print Network [OSTI]

    Salt Concentration Differences Alter Membrane Resistance in Reverse Electrodialysis Stacks Geoffrey is usually measured by immersing the membrane in a salt solution at a single, fixed concentration. While salt resistance of the membranes separating different salt concentration solutions has implications for modeling

  18. Non-Normal Effects on Salt Finger Growth IAN EISENMAN

    E-Print Network [OSTI]

    Eisenman, Ian

    , but the more rapid diffusion of heat than salt in water allows the potential energy stored in the salinity pockets of salty or sugary water called salt fingers. Since solar heating of the up- per ocean leads 2004) ABSTRACT Salt fingers, which occur because of the difference in diffusivities of salt and heat

  19. Real time in situ detection of organic nitrates in atmospheric aerosols

    SciTech Connect (OSTI)

    Rollins, Andrew W.; Smith, Jared D.; Wilson, Kevin R.; Cohen, Ronald C.

    2010-06-11

    A new field instrument is described that quantifies total particle phase organic nitrates. The instrument is based on the thermal dissociation laser induced fluorescence (TD-LIF) method that thermally converts nitrates to NO2 which is then detected by LIF. This instrument is unique in its ability to provide fast sensitive measurements of particle phase organic nitrates, without interference from inorganic nitrate. Here we use it to quantify organic nitrates in SOA generated from high-NOx photooxidation of limonene, a-pinene, D-3-carene, and tridecane. In these experiments the organic nitrate moiety is observed to be 6-15percent of the total SOA mass, depending on the organic precursor.

  20. [Task 1.] Biodenitrification of low nitrate solar pond waters using sequencing batch reactors. [Task 2.] Solidification/stabilization of high strength and biodenitrified heavy metal sludges with a Portland cement/flyash system

    SciTech Connect (OSTI)

    Figueroa, L.; Cook, N.E.; Siegrist, R.L.; Mosher, J.; Terry, S.; Canonico, S.

    1995-09-22

    Process wastewater and sludges were accumulated on site in solar evaporation ponds during operations at the Department of Energy's Rocky Flats Plant (DOE/RF). Because of the extensive use of nitric acid in the processing of actinide metals, the process wastewater has high concentrations of nitrate. Solar pond waters at DOE/RF contain 300-60,000 mg NO{sub 3}{sup {minus}}/L. Additionally, the pond waters contain varying concentrations of many other aqueous constituents, including heavy metals, alkali salts, carbonates, and low level radioactivity. Solids, both from chemical precipitation and soil material deposition, are also present. Options for ultimate disposal of the pond waters are currently being evaluated and include stabilization and solidification (S/S) by cementation. Removal of nitrates can enhance a wastes amenability to S/S, or can be a unit operation in another treatment scheme. Nitrate removal is also a concern for other sources of pollution at DOE/RF, including contaminated groundwater collected by interceptor trench systems. Finally, nitrate pollution is a problem at many other DOE facilities where actinide metals were processed. The primary objective of this investigation was to optimize biological denitrification of solar pond waters with nitrate concentrations of 300--2,100 mg NO{sub 3}{sup {minus}}/L to below the drinking water standard of 45 mg NO{sub 3}{sup {minus}}/L (10 mg N/L). The effect of pH upon process stability and denitrification rate was determined. In addition, the effect Cr(VI) on denitrification and fate of Cr(VI) in the presence of denitrifying bacteria was evaluated.

  1. Impact of elevated nitrate on sulfate-reducing bacteria: A comparative study of Desulfovibrio vulgaris

    SciTech Connect (OSTI)

    He, Q.; He, Z.; Joyner, D.C.; Joachimiak, M.; Price, M.N.; Yang, Z.K.; Yen, H.-C. B.; Hemme, C. L.; Chen, W.; Fields, M.; Stahl, D. A.; Keasling, J. D.; Keller, M.; Arkin, A. P.; Hazen, T. C.; Wall, J. D.; Zhou, J.

    2010-07-15

    Sulfate-reducing bacteria have been extensively studied for their potential in heavy-metal bioremediation. However, the occurrence of elevated nitrate in contaminated environments has been shown to inhibit sulfate reduction activity. Although the inhibition has been suggested to result from the competition with nitrate-reducing bacteria, the possibility of direct inhibition of sulfate reducers by elevated nitrate needs to be explored. Using Desulfovibrio vulgaris as a model sulfate-reducing bacterium, functional genomics analysis reveals that osmotic stress contributed to growth inhibition by nitrate as shown by the upregulation of the glycine/betaine transporter genes and the relief of nitrate inhibition by osmoprotectants. The observation that significant growth inhibition was effected by 70 mM NaNO{sub 3} but not by 70 mM NaCl suggests the presence of inhibitory mechanisms in addition to osmotic stress. The differential expression of genes characteristic of nitrite stress responses, such as the hybrid cluster protein gene, under nitrate stress condition further indicates that nitrate stress response by D. vulgaris was linked to components of both osmotic and nitrite stress responses. The involvement of the oxidative stress response pathway, however, might be the result of a more general stress response. Given the low similarities between the response profiles to nitrate and other stresses, less-defined stress response pathways could also be important in nitrate stress, which might involve the shift in energy metabolism. The involvement of nitrite stress response upon exposure to nitrate may provide detoxification mechanisms for nitrite, which is inhibitory to sulfate-reducing bacteria, produced by microbial nitrate reduction as a metabolic intermediate and may enhance the survival of sulfate-reducing bacteria in environments with elevated nitrate level.

  2. Nitrate Distribution in Soil Moisture and Groundwater with Intensive Plantation Management on Abandoned Agricultural Land

    SciTech Connect (OSTI)

    Williams, T.M.

    1998-01-01

    Paper outlines nitrate leaching results of loblolly pine and sweet gum that were grown with irrigation, continuous fertilization and insect pest control on a year old abandoned peanut field. Wells and tension lysimeters were used to measure nitrate in soil moisture and groundwater on three replicate transects for two years. Groundwater nitrate concentration beneath the minimum treatment was much higher than the maximum treatment and old field. All three treatments often exceeded the drinking water standard. Forest and lake edge had low levels while the soil moisture nitrate concentrations in the two plantations treatments were much higher than the old field.

  3. Laser-induced breakdown spectroscopic study of ammonium nitrate plasma

    SciTech Connect (OSTI)

    Hanif, M.; Salik, M.; Baig, M. A.

    2013-12-15

    We present the optical emission studies of the ammonium nitrate plasma produced by the fundamental (1064 nm) and second (532 nm) harmonics of a Q-switched Nd: YAG laser. The target material was placed in front of the laser beam in an open atmospheric air. The spectrum reveals numerous transitions of neutral nitrogen. We have studied the spatial behavior of the plasma temperature (T{sub e}) and electron number density (N{sub e}) determined using the Boltzmann plot method and Stark broadened line profiles, respectively. Besides, we have studied the variation of the plasma parameters as a function of the laser irradiance.

  4. Applicability of hydroxylamine nitrate reductant in pulse-column contactors

    SciTech Connect (OSTI)

    Reif, D.J.

    1983-05-01

    Uranium and plutonium separations were made from simulated breeder reactor spent fuel dissolver solution with laboratory-sized pulse column contactors. Hydroxylamine nitrate (HAN) was used for reduction of plutonium (1V). An integrated extraction-partition system, simulating a breeder fuel reprocessing flowsheet, carried out a partial partition of uranium and plutonium in the second contactor. Tests have shown that acceptable coprocessing can be ontained using HAN as a plutonium reductant. Pulse column performance was stable even though gaseous HAN oxidation products were present in the column. Gas evolution rates up to 0.27 cfm/ft/sup 2/ of column cross section were tested and found acceptable.

  5. Brine flow in heated geologic salt.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  6. Distribution and Invasion Potential of Limonium ramosissimum subsp. provinciale in San Francisco Estuary Salt Marshes

    E-Print Network [OSTI]

    Archbald, Gavin; Boyer, Katharyn E.

    2014-01-01

    of southern California coastal salt marshes: a communitygrowth and cation uptake of salt marsh plants. New Phytolof vegetation patterns in salt marshes of central Argentina.

  7. The Effect of Salt Water on Rice. 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1927-01-01

    *. .. r * - .=.-ksl-, G v $. THE EFFECT OF SALT WATER ON RICE AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS T. 0. WALTON, President \\ STATION ,,,bfINISTRATION: *B. YOUNGBLOOD, M. S., Ph. D.,, Director A B CONNER M. S Actrng Drrector R: E: KARPER: B.... SYNOPSIS Rice farmers sometimes have trouble with salt in the water used for irrigation. Varying conditions, such as character of soil, amount of water already on the land, stage of growth of the rice, and others, render it difficult to say how much...

  8. Materials Chemistry and Physics 100 (2006) 3840 X-ray irradiation induced degradation of cellulose nitrate

    E-Print Network [OSTI]

    Yu, Peter K.N.

    2006-01-01

    Materials Chemistry and Physics 100 (2006) 38­40 X-ray irradiation induced degradation of cellulose the thickness of the cellulose nitrate layer of the commonly used LR 115 solid-state nuclear track detector spectrometry will induce degradation of the cellulose nitrate. For this purpose, Fourier transform infrared

  9. Materials Chemistry and Physics 95 (2006) 307312 Chemical etching characteristics for cellulose nitrate

    E-Print Network [OSTI]

    Yu, Peter K.N.

    2006-01-01

    Materials Chemistry and Physics 95 (2006) 307­312 Chemical etching characteristics for cellulose; received in revised form 31 May 2005; accepted 12 June 2005 Abstract Cellulose nitrate films (commercially was consistent with the expected range. © 2005 Published by Elsevier B.V. Keywords: Cellulose nitrate

  10. Polycyclic Aromatic Hydrocarbons (PAHs), nitrated PAHs and oxygenated PAHs in ambient air of the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Polycyclic Aromatic Hydrocarbons (PAHs), nitrated PAHs and oxygenated PAHs in ambient air + particle phases) of 16 polycyclic aromatic hydrocarbons (PAHs), 17 nitrated PAHs (NPAHs) and 9 oxygenated when (before or during the sampling) the OPAHs are formed. Keywords: Polycyclic aromatic hydrocarbons

  11. Sampling precautions for the measurement of nitrated polycyclic aromatic hydrocarbons in ambient air

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Sampling precautions for the measurement of nitrated polycyclic aromatic hydrocarbons in ambient of polycyclic aromatic hydrocarbons (PAHs) and of their oxidation products, such as nitrated and oxygenated PAHs samplers (cascade impactor and conventional high volume sampler) installed in parallel during several field

  12. Cosmogenic production and climate contributions to nitrate record in the TALDICE Antarctic ice core

    E-Print Network [OSTI]

    Usoskin, Ilya G.

    Nitrate Holocene TALDICE a b s t r a c t This paper presents the results of a comparative wavelet the TALDICE drilling project (Talos Dome, Antarctica), which covers the age range 12,000­700 BP (years before present, i.e. before 1950) and includes records of nitrate as well as climatic proxies, such as Naþ , Ca2þ

  13. Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state,

    E-Print Network [OSTI]

    Flury, Markus

    Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state), Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state, variably and colloid transport through coarse Hanford sediments under steady state, variably saturated flow'' by Kelly

  14. Catalytic liquid-phase hydrogenation of aqueous nitrate solutions: A kinetic investigation

    SciTech Connect (OSTI)

    Pintar, A.; Batista, J.; Levec, J. [National Inst. of Chemistry, Ljubljana (Slovenia); Kajiuchi, Toshio [Tokyo Inst. of Technology, Yokohama (Japan)

    1996-12-31

    Liquid-phase reduction using a solid Pd/Cu bimetallic catalyst provides a potential technique for the removal of nitrates from waters. Kinetic measurements were performed in an isothermal semi-batch slurry reactor operating at atmospheric pressure. The proposed intrinsic rate expression for nitrate disappearance is based on the conventional Langmuir-Hinshelwood kinetic approach, considering both equilibrium nitrate as well as dissociative hydrogen adsorption processes to different types of active sites, and assuming an irreversible bimolecular surface reaction between adsorbed reactant species to be the rate-controlling step. The apparent activation energy for catalytic liquid-phase nitrate reduction and the heat of nitrate adsorption, in the temperature range 280.5-293 K, were found to be 47 and -22 kJ/mol, respectively. 6 refs., 3 figs.

  15. Practical considerations in the concentration and recovery of spent nitration acids

    SciTech Connect (OSTI)

    Evans, C.M. [Chemetics International Co. Ltd., Vancouver, British Columbia (Canada)

    1995-12-01

    Most organic nitrations employ sulphuric acid or oleum in the nitration acid. Even in rare nitric acid only nitrations, sulphuric acid is used as the dehydrating agent to produce 99% nitric acid. The used sulphuric acid is discharged in a diluted form contaminated with organic components and nitric/nitrous species. Pressures are emloyed to reconcentrate and reprocess such spent acids. Acid recovery and concentration is expensive. This paper discusses some of the aspects which must be considered when contemplating acid recovery. In the current industrial climate, acid recovery and recycle should be regarded as an integral part of a nitration process development rather than an afterthought. Case histories will be given in which such considerations influenced the course of the development of the nitration process itself. Emphasis will be placed on the importance of well planned bench and pilot scale test programmes.

  16. Temporal dynamics of Prochlorococcus cells with the potential for nitrate assimilation in the subtropical Atlantic and Pacific oceans

    E-Print Network [OSTI]

    Berube, Paul M.

    Utilization of nitrate as a nitrogen source is broadly conserved among marine phytoplankton, yet many strains of Prochlorococcus lack this trait. Among cultured strains, nitrate assimilation has only been observed within ...

  17. A hypothesis concerning the distribution of salt and salt structures in the Gulf of Mexico 

    E-Print Network [OSTI]

    Antoine, John Woodworth

    1970-01-01

    is that the Gu'f v;as a shallow sea during latest Triassic and Jusas ic time (the age cf the salt) and thick salt deposits accumulated across the entire sea, including the present Sigsbee Deep (Fig. 1). Later, the central part subsided and received great... is that the Gulf always has been a deep bas n, and during Triassic and Jurassic times salt v as deposited in beth the shallow marginal areas and the deep central basin. T?e diapirs su?sequently began to form. Schmalz's (1969) genetic model for the deposition...

  18. A computational study of novel nitratoxycarbon, nitritocarbonyl, and nitrate compounds and their potential as high energy materials

    E-Print Network [OSTI]

    Rzepa, Henry S.

    ] and pentaerythritol tetranitrate (PETN) [5]. (In the latter case, the nitroxy group is formed through the nitration

  19. Ketone Production from the Thermal Decomposition of Carboxylate Salts 

    E-Print Network [OSTI]

    Landoll, Michael 1984-

    2012-08-15

    The MixAlco process uses an anaerobic, mixed-culture fermentation to convert lignocellulosic biomass to carboxylate salts. The fermentation broth must be clarified so that only carboxylate salts, water, and minimal impurities remain. Carboxylate...

  20. Waste Isolation Pilot Plant's Excavated Salt Agreement Supports...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program, benefits from the agreement by not having to dispose of the salt and put it in a landfill. Except for the excavated salt that is removed as a result of this agreement -...

  1. Accident Investigation of the February 5, 2014, Underground Salt...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5, 2014, Underground Salt Haul Truck Fire at the Waste Isolation Pilot Plant, Carlsbad NM Accident Investigation of the February 5, 2014, Underground Salt Haul Truck Fire at the...

  2. Salt Wells Geothermal Exploratory Drilling Program EA(DOI-BLM...

    Open Energy Info (EERE)

    Salt Wells Geothermal Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells...

  3. Summary - Salt Waste Processing Facility Design at the Savannah...

    Office of Environmental Management (EM)

    Management (DOE-EM) External Technical Review of the Salt Waste Processing Facility Design at the Savannah River Site (SRS) Why DOE-EM Did This Review The Salt Waste Processing...

  4. Nuclear salt-in-crude monitor

    SciTech Connect (OSTI)

    Sheikh, S.; Richter, A.P.

    1983-05-01

    The Arabian American Oil Co. (ARAMCO) recently installed a nuclear salt-in-crude monitor (SICM) that continuously measures the salt content of a flowing stream of crude oil. This device was developed by Texaco Inc.'s Bellaire (TX) Research Laboratory. The monitor consists of two parts: a counting chamber and an instrument console. The counting chamber is a length of 24-in.-diameter pipe containing a long-life neutron source and a gamma ray detector, both mounted in cross pipes so that there is no direct contact with the flowing crude. Neutrons from the source are absorbed by chloride ions in the stream, which in turn emit gamma rays. The intensity of the gamma rays is proportional to the amount of chlorine in the crude. The gamma ray detector is electrically connected to the instrument console, which is located in a control room. The console contains the necessary instrumentation to process the data from the detector, to compute the salt concentration, and to provide a continuous printed record of the salt per thousand barrels (PTB).

  5. Hybrid Molten Salt Reactor (HMSR) System Study

    SciTech Connect (OSTI)

    Woolley, Robert D; Miller, Laurence F

    2014-04-01

    Can the hybrid system combination of (1) a critical fission Molten Salt Reactor (MSR) having a thermal spectrum and a high Conversion Ratio (CR) with (2) an external source of high energy neutrons provide an attractive solution to the world's expanding demand for energy? The present study indicates the answer is an emphatic yes.

  6. Salt repository project closeout status report

    SciTech Connect (OSTI)

    1988-06-01

    This report provides an overview of the scope and status of the US Department of Energy (DOE`s) Salt Repository Project (SRP) at the time when the project was terminated by the Nuclear Waste Policy Amendments Act of 1987. The report reviews the 10-year program of siting a geologic repository for high-level nuclear waste in rock salt formations. Its purpose is to aid persons interested in the information developed during the course of this effort. Each area is briefly described and the major items of information are noted. This report, the three salt Environmental Assessments, and the Site Characterization Plan are the suggested starting points for any search of the literature and information developed by the program participants. Prior to termination, DOE was preparing to characterize three candidate sites for the first mined geologic repository for the permanent disposal of high-level nuclear waste. The sites were in Nevada, a site in volcanic tuff; Texas, a site in bedded salt (halite); and Washington, a site in basalt. These sites, identified by the screening process described in Chapter 3, were selected from the nine potentially acceptable sites shown on Figure I-1. These sites were identified in accordance with provisions of the Nuclear Waste Policy Act of 1982. 196 refs., 21 figs., 11 tabs.

  7. Analysis of Enriched Uranyl Nitrate in Nested Annular Tank Array

    SciTech Connect (OSTI)

    John D. Bess; James D. Cleaver

    2009-06-01

    Two series of experiments were performed at the Rocky Flats Critical Mass Laboratory during the 1980s using highly enriched (93%) uranyl nitrate solution in annular tanks. [1, 2] Tanks were of typical sizes found in nuclear production plants. Experiments looked at tanks of varying radii in a co-located set of nested tanks, a 1 by 2 array, and a 1 by 3 array. The co-located set of tanks had been analyzed previously [3] as a benchmark for inclusion within the International Handbook of Evaluated Criticality Safety Benchmark Experiments. [4] The current study represents the benchmark analysis of the 1 by 3 array of a series of nested annular tanks. Of the seventeen configurations performed in this set of experiments, twelve were evaluated and nine were judged as acceptable benchmarks.

  8. Combined Extraction of Cesium and Strontium from Akaline Nitrate Solutions

    SciTech Connect (OSTI)

    Delmau, Laetitia Helene; Bonnesen, Peter V; Engle, Nancy L; Haverlock, Tamara; Sloop Jr, Frederick {Fred} V; Moyer, Bruce A

    2006-01-01

    The combined extraction of cesium and strontium from caustic wastes can be achieved by adding a crown ether and a carboxylic acid to the Caustic-Side Solvent Extraction (CSSX) solvent. The ligand 4,4'(5')-di(tert-butyl)cyclohexano-18-crown-6 and one of four different carboxylic acids were combined with the components of the CSSX solvent optimized for the extraction of cesium, allowing for the simultaneous extraction of cesium and strontium from alkaline nitrate media simulating alkaline high level wastes present at the U.S. Department of Energy Savannah River Site. Extraction and stripping experiments were conducted independently and exhibited adequate results for mimicking waste simulant processing through batch contacts. The promising results of these batch tests showed that the system could reasonably be tested on actual waste.

  9. Method for preparing salt solutions having desired properties

    DOE Patents [OSTI]

    Ally, Moonis R. (Oak Ridge, TN); Braunstein, Jerry (Clinton, TN)

    1994-01-01

    The specification discloses a method for preparing salt solutions which exhibit desired thermodynamic properties. The method enables prediction of the value of the thermodynamic properties for single and multiple salt solutions over a wide range of conditions from activity data and constants which are independent of concentration and temperature. A particular application of the invention is in the control of salt solutions in a process to provide a salt solution which exhibits the desired properties.

  10. Energy Efficient Buildings, Salt Lake County, Utah

    SciTech Connect (OSTI)

    Barnett, Kimberly

    2012-04-30

    Executive Summary Salt Lake County's Solar Photovoltaic Project - an unprecedented public/private partnership Salt Lake County is pleased to announce the completion of its unprecedented solar photovoltaic (PV) installation on the Calvin R. Rampton Salt Palace Convention Center. This 1.65 MW installation will be one the largest solar roof top installations in the country and will more than double the current installed solar capacity in the state of Utah. Construction is complete and the system will be operational in May 2012. The County has accomplished this project using a Power Purchase Agreement (PPA) financing model. In a PPA model a third-party solar developer will finance, develop, own, operate, and maintain the solar array. Salt Lake County will lease its roof, and purchase the power from this third-party under a long-term Power Purchase Agreement contract. In fact, this will be one of the first projects in the state of Utah to take advantage of the recent (March 2010) legislation which makes PPA models possible for projects of this type. In addition to utilizing a PPA, this solar project will employ public and private capital, Energy Efficiency and Conservation Block Grants (EECBG), and public/private subsidized bonds that are able to work together efficiently because of the recent stimulus bill. The project also makes use of recent changes to federal tax rules, and the recent re-awakening of private capital markets that make a significant public-private partnership possible. This is an extremely innovative project, and will mark the first time that all of these incentives (EECBG grants, Qualified Energy Conservation Bonds, New Markets tax credits, investment tax credits, public and private funds) have been packaged into one project. All of Salt Lake County's research documents and studies, agreements, and technical information is available to the public. In addition, the County has already shared a variety of information with the public through webinars, site tours, presentations, and written correspondence.

  11. Method to Reduce Molten Salt Penetration into Bulk Vitrification Refractory Materials

    SciTech Connect (OSTI)

    Bagaasen, L.M.; Hrma, P.R.; Kim, D.S.; Schweiger, M.J.; Matyas, J.; Rodriguez, C.P. [Pacific Northwest National Laboratory, Richland WA (United States); Witwer, K.S. [AMEC Nuclear Holdings Ltd., GeoMelt Division, Richland, WA (United States)

    2008-07-01

    Bulk vitrification (BV) is a process that heats a feed material consisting of glass-forming solids and dried low-activity waste (LAW) in a disposable refractory-lined metal box using electrical power supplied through carbon electrodes. The feed is heated to the point that the LAW decomposes and combines with the solids to generate a vitreous waste form. However, the castable refractory block (CRB) portion of the refractory lining has sufficient porosity to allow the low-viscosity molten ionic salt (MIS), which contains technetium (Tc) in a soluble form, to penetrate the CRB. This limits the effectiveness of the final waste form. This paper describes tests conducted to develop a method aimed at reducing the quantities of soluble Tc in the CRB. Tests showed that MIS formed in significant quantities at temperatures above 300 deg. C, remained stable until roughly 550 deg. C where it began to thermally decompose, and was completely decomposed by 800 deg. C. The estimated volume fraction of MIS in the feed was greater than 40%, and the CRB material contained 11 to 15% open porosity, a combination allowing a large quantity of MIS to migrate through the feed and penetrate the open porosity of the CRB. If the MIS is decomposed at temperatures below 300 deg. C or can be contained in the feed until it fully decomposes by 800 deg. C, MIS migration into the CRB can be avoided. Laboratory and crucible-scale experiments showed that a variety of methods, individually or in combination, can decrease MIS penetration into the CRB. Modifying the CRB to block MIS penetration was not deemed practical as a method to prevent the large quantities of MIS penetration seen in the full-scale tests, but it may be useful to reduce the impacts of lower levels of MIS penetration. Modifying the BV feed materials to better contain the MIS proved to be more successful. A series of qualitative and quantitative crucible tests were developed that allowed screening of feed modifications that might be used to reduce MIS penetration. These tests showed that increasing the specific surface area of the soil (used as the primary glass-forming solid in the baseline process) by grinding stopped MIS penetration nearly entirely for feeds that contained waste simulants with lower quantities of nitrate salts. Grinding soil significantly reduced MIS penetration in feeds with higher nitrate quantities, but it was necessary to add carbohydrates (sucrose or cellulose) to destroy a portion of the nitrate at low temperatures to reach the same low levels of MIS penetration seen for the lower nitrate feeds. Developing feeds to reduce MIS penetration in full-scale BV applications resulted in two additional refinements. Soil-grinding to the necessary levels proved to be difficult and expensive, so the fine soil was replaced with readily available fine-grained glass-forming minerals. Cellulose was shown to have less impact on dryer operation than sucrose and was chosen as the carbohydrate source to use in subsequent engineering- and full-scale tests. (authors)

  12. REVIEW SHEET 3 (1) A tank contains 100 gallon of salt water which ...

    E-Print Network [OSTI]

    2014-04-30

    REVIEW SHEET 3. (1) A tank contains 100 gallon of salt water which contains 10 lbs of salt. A salt solution of 2lbs of salt per gallon enters the tank at a rate of 3 ...

  13. Molten Salt Synthesis of Calcium Hydroxyapatite Whiskers A. Cuneyt Tas*,

    E-Print Network [OSTI]

    Tas, A. Cuneyt

    Molten Salt Synthesis of Calcium Hydroxyapatite Whiskers A. Cu¨neyt Tas¸*, Department hydroxyapatite (HA) whiskers and crystals were produced by the route of molten salt synthesis. The effects. A tentative X-ray diffraction pattern was proposed for the HA whiskers. Molten salt synthesis with a K2SO4

  14. Graphic: FL Dept. of Environmental Protection Please pass the Salt!!

    E-Print Network [OSTI]

    Graphic: FL Dept. of Environmental Protection Please pass the Salt!! Mangroves are a very unique protruding from the tree trunk and branches. These prop roots are special because they exclude salt from actually absorb saltwater through their roots, but have specially designed leaves with salt glands

  15. New York State Salt Marsh Restoration and Monitoring Guidelines

    E-Print Network [OSTI]

    #12;New York State Salt Marsh Restoration and Monitoring Guidelines prepared by: Nancy L. Niedowski;The Salt Marsh Restoration and Monitoring Guidelines were prepared under the National OceanicState,Division of CoastalResources,41 State Street,Albany, New York 12231. December 2000 #12;PREFACE All salt marsh

  16. Developing salt-tolerant crop plants: challenges and opportunities

    E-Print Network [OSTI]

    Blumwald, Eduardo

    Developing salt-tolerant crop plants: challenges and opportunities Toshio Yamaguchi and Eduardo areas of the world; the need to produce salt-tolerant crops is evident. Two main approaches are being used to improve salt tolerance: (i) the exploitation of natural genetic variations, either through

  17. South Bay Salt Pond Restoration Project SYNTHESES OF SCIENTIFIC KNOWLEDGE

    E-Print Network [OSTI]

    South Bay Salt Pond Restoration Project SYNTHESES OF SCIENTIFIC KNOWLEDGE for Maintaining and Improving Functioning of the South Bay Ecosystem and Restoring Tidal Salt Marsh and Associated Habitats over) Maintaining and Improving Functioning of the South Bay Ecosystem and (2) Restoring tidal salt marsh

  18. SALT-flSH INPUSTRIES FISHERY LEAFLET 240

    E-Print Network [OSTI]

    SALT-flSH INPUSTRIES FISHERY LEAFLET 240 FISH AND WILDLIFE SERVICE UNITED STATES DEPARTMENT, Albert M. Day, Director #12;THE VENEZUKLAN SALT-FISH INDUSTRIES CONTE^fTS Part II Potential Productive and Craft 29 Development of Unused or Underutilized Species 29 Development of New Areas 35 Salt 35 Studies

  19. Production of carboxylic acid and salt co-products

    DOE Patents [OSTI]

    Hanchar, Robert J.; Kleff, Susanne; Guettler, Michael V.

    2014-09-09

    This invention provide processes for producing carboxylic acid product, along with useful salts. The carboxylic acid product that is produced according to this invention is preferably a C.sub.2-C.sub.12 carboxylic acid. Among the salts produced in the process of the invention are ammonium salts.

  20. Influence of Salt Purity on Na+ and Palmitic Acid Interactions

    E-Print Network [OSTI]

    Influence of Salt Purity on Na+ and Palmitic Acid Interactions Zishuai Huang, Wei Hua, Dominique of salt purity on the interactions between Na+ ions and the carboxylate (COO- ) head group of palmitic frequency generation (VSFG) spectroscopy. Ultrapure (UP) and ACS grade NaCl salts are used for aqueous

  1. Simulation of salt migrations in density dependent groundwater flow

    E-Print Network [OSTI]

    Vuik, Kees

    Simulation of salt migrations in density dependent groundwater flow E.S. van Baaren Master's Thesis for the salt migration in the groundwater underneath the polders near the coast. The problem description of this thesis is to investigate the possibilities of modelling salt migrations in density dependent groundwater

  2. SOLUTION MINING IN SALT DOMES OF THE GULF COAST EMBAYMENT

    SciTech Connect (OSTI)

    Griswold, G. B.

    1981-02-01

    Following a description of salt resources in the salt domes of the gulf coast embayment, mining, particularly solution mining, is described. A scenario is constructed which could lead to release of radioactive waste stored in a salt dome via inadvertent solution mining and the consequences of this scenario are analyzed.

  3. Tracking the Salt Front Page 1 Name __________________________________________ Date____________________

    E-Print Network [OSTI]

    Lance, Veronica P.

    , moving the salt front inland. Scientists track the salt front using Hudson River Miles, abbreviated HRM, is HRM 0. The George Washington Bridge is at HRM 12, the city of Kingston at HRM 91. Ocean tides reach the Federal Dam in Troy at HRM 153. Using the graph "Hudson River Salt Front: Average Location by Month

  4. Capillary forces and osmotic gradients in salt water -oil systems

    E-Print Network [OSTI]

    Kjelstrup, Signe

    Capillary forces and osmotic gradients in salt water - oil systems Georg Ellila Chemical study. This is to my knowledge the first time the transport mechanisms in capillary oil-salt water and the Vista Program. 1 #12;Abstract This project looks at the capillary systems with salt water and oil

  5. Structural restoration of Louann Salt and overlying sediments, De Soto Canyon Salt Basin, northeastern Gulf of Mexico 

    E-Print Network [OSTI]

    Guo, Mengdong

    1997-01-01

    The continental margin of the northeastern Gulf of Mexico is suited for seismic stratigraphic analysis and salt tectonism analysis. Jurassic strata include the Louann Salt on the continental shelf and upper slope of the Destin Dome OCS area...

  6. Polymeric salt bridges for conducting electric current in microfluidic devices

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Tichenor, Mark S. (San Diego, CA); Artau, Alexander (Humacao, PR)

    2009-11-17

    A "cast-in-place" monolithic microporous polymer salt bridge for conducting electrical current in microfluidic devices, and methods for manufacture thereof is disclosed. Polymeric salt bridges are formed in place in capillaries or microchannels. Formulations are prepared with monomer, suitable cross-linkers, solvent, and a thermal or radiation responsive initiator. The formulation is placed in a desired location and then suitable radiation such as UV light is used to polymerize the salt bridge within a desired structural location. Embodiments are provided wherein the polymeric salt bridges have sufficient porosity to allow ionic migration without bulk flow of solvents therethrough. The salt bridges form barriers that seal against fluid pressures in excess of 5000 pounds per square inch. The salt bridges can be formulated for carriage of suitable amperage at a desired voltage, and thus microfluidic devices using such salt bridges can be specifically constructed to meet selected analytical requirements.

  7. Pyrochemical process for extracting plutonium from an electrolyte salt

    DOE Patents [OSTI]

    Mullins, L.J.; Christensen, D.C.

    1982-09-20

    A pyrochemical process for extracting plutonium from a plutonium-bearing salt is disclosed. The process is particularly useful in the recovery of plutonium for electrolyte salts which are left over from the electrorefining of plutonium. In accordance with the process, the plutonium-bearing salt is melted and mixed with metallic calcium. The calcium reduces ionized plutonium in the salt to plutonium metal, and also causes metallic plutonium in the salt, which is typically present as finely dispersed metallic shot, to coalesce. The reduced and coalesced plutonium separates out on the bottom of the reaction vessel as a separate metallic phase which is readily separable from the overlying salt upon cooling of the mixture. Yields of plutonium are typically on the order of 95%. The stripped salt is virtually free of plutonium and may be discarded to low-level waste storage.

  8. Pyrochemical process for extracting plutonium from an electrolyte salt

    DOE Patents [OSTI]

    Mullins, Lawrence J. (Los Alamos, NM); Christensen, Dana C. (Los Alamos, NM)

    1984-01-01

    A pyrochemical process for extracting plutonium from a plutonium-bearing salt is disclosed. The process is particularly useful in the recovery of plutonium from electrolyte salts which are left over from the electrorefining of plutonium. In accordance with the process, the plutonium-bearing salt is melted and mixed with metallic calcium. The calcium reduces ionized plutonium in the salt to plutonium metal, and also causes metallic plutonium in the salt, which is typically present as finely dispersed metallic shot, to coalesce. The reduced and coalesced plutonium separates out on the bottom of the reaction vessel as a separate metallic phase which is readily separable from the overlying salt upon cooling of the mixture. Yields of plutonium are typically on the order of 95%. The stripped salt is virtually free of plutonium and may be discarded to low-level waste storage.

  9. Dense QCD: a Holographic Dyonic Salt

    E-Print Network [OSTI]

    Mannque Rho; Sang-Jin Sin; Ismail Zahed

    2009-10-23

    Dense QCD at zero temperature with a large number of colors is a crystal. We show that in the holographic dual description, the crystal is made out of pairs of dyons with $e=g=\\pm 1$ charges in a salt-like arrangement. We argue that with increasing density the dyon masses and topological charges equalize, turning the salt-like configuration to a bcc of half-instantons. The latter is dual to a cubic crystal of half-skyrmions. We estimate the transition from an fcc crystal of instantons to a bcc crystal of dyons to about 3 times nuclear matter density with a dyon binding energy of about 180 MeV.

  10. Advanced heat exchanger development for molten salts

    SciTech Connect (OSTI)

    Sabharwall, Piyush; Clark, Denis; Glazoff, Michael; Zheng, Guiqiu; Sridharan, Kumar; Anderson, Mark

    2014-12-01

    This study addresses present work concerned with advanced heat exchanger development for molten salt in nuclear and non nuclear thermal systems. The molten salt systems discussed herein use alloys, such as Hastelloy N and 242, which show corrosion resistance to molten salt at nominal operating temperatures up to 700°C. These alloys were diffusion welded, and the corresponding information is presented. Test specimens were prepared for exposing diffusion welds to molten salt environments. Hastelloy N and 242 were found to be weldable by diffusion welding, with ultimate tensile strengths about 90% of base metal values. Both diffusion welds and sheet material in Hastelloy N were corrosion tested in?58 mol% KF and 42 mol% ZrF4 at 650, 700, and 850°C for 200, 500, and 1,000 hours. Corrosion rates found were similar between welded and nonwelded materials, typically <10 mils per year. For materials of construction, nickel and alloys with dense nickel coatings are effectively inert to corrosion in fluorides, but not so in chlorides. Hence, additional testing of selected alloys for resistance to intergranular corrosion is needed, as is a determination of corrosion rate as a function of contaminant type and alloy composition with respect to chromium and carbon to better define the optimal chromium and carbon composition, independent of galvanic or differential solubility effects. Also presented is the division of the nuclear reactor and high temperature components per ASME standards, along with design requirements for a subcritical Rankine power cycle heat exchanger that has to overcome pressure difference of about 17 MPa.

  11. Stationary phase deposition based on onium salts

    DOE Patents [OSTI]

    Wheeler, David R. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM); Dirk, Shawn M. (Albuquerque, NM); Trudell, Daniel E. (Albuquerque, NM)

    2008-01-01

    Onium salt chemistry can be used to deposit very uniform thickness stationary phases on the wall of a gas chromatography column. In particular, the stationary phase can be bonded to non-silicon based columns, especially microfabricated metal columns. Non-silicon microfabricated columns may be manufactured and processed at a fraction of the cost of silicon-based columns. In addition, the method can be used to phase-coat conventional capillary columns or silicon-based microfabricated columns.

  12. NITRATE CONVERSION OF HB-LINE REILLEXTM HPQ RESIN

    SciTech Connect (OSTI)

    Steimke, J.; Williams, M.; Steeper, T.; Leishear, R.

    2012-05-29

    Reillex{trademark} HPQ ion exchange resin is used by HB Line to remove plutonium from aqueous streams. Reillex{trademark} HPQ resin currently available from Vertellus Specialties LLC is a chloride ionic form, which can cause stress corrosion cracking in stainless steels. Therefore, HB Line Engineering requested that Savannah River National Laboratory (SRNL) convert resin from chloride form to nitrate form in the Engineering Development Laboratory (EDL). To perform this task, SRNL treated two batches of resin in 2012. The first batch of resin from Reilly Industries Batch 80302MA was initially treated at SRNL in 2001 to remove chloride. This batch of resin, nominally 30 liters, has been stored wet in carboys since that time until being retreated in 2012. The second batch of resin from Batch 23408 consisted of 50 kg of new resin purchased from Vertellus Specialties in 2012. Both batches were treated in a column designed to convert resin using downflow of 1.0 M sodium nitrate solution through the resin bed followed by rinsing with deionized water. Both batches were analyzed for chloride concentration, before and after treatment, using Neutron Activation Analysis (NAA). The resin specification [Werling, 2003] states the total chlorine and chloride concentration shall be less than 250 ppm. The resin condition for measuring this concentration is not specified; however, in service the resin would always be fully wet. Measurements in SRNL showed that changing from oven dry resin to fully wet resin, with liquid in the particle interstices but no supernatant, increases the total weight by a factor of at least three. Therefore, concentration of chlorine or chloride expressed as parts per million (ppm) decreases by a factor of three. Therefore, SRNL recommends measuring chlorine concentration on an oven dry basis, then dividing by three to estimate chloride concentration in the fully wet condition. Chloride concentration in the first batch (No.80302MA) was nearly the same before the current treatment (759 ppm dry) and after treatment (745 ppm dry or {approx}248 ppm wet). Treatment of the second batch of resin (No.23408) was very successful. Chloride concentration decreased from 120,000 ppm dry to an average of 44 ppm dry or {approx}15ppm wet, which easily passes the 250 ppm wet criterion. Per guidance from HB Line Engineering, SRNL blended Batch 80302 resin with Batch P9059 resin which had been treated previously by ResinTech to remove chloride. The chloride concentrations for the two drums of Batch P9059 were 248 ppm dry ({approx}83 ppm wet) {+-}22.8% and 583 ppm dry ({approx}194 ppm wet) {+-} 11.8%. The blended resin was packaged in five gallon buckets.

  13. Waste Isolation Pilot Plant Salt Decontamination Testing

    SciTech Connect (OSTI)

    Rick Demmer; Stephen Reese

    2014-09-01

    On February 14, 2014, americium and plutonium contamination was released in the Waste Isolation Pilot Plant (WIPP) salt caverns. At the request of WIPP’s operations contractor, Idaho National Laboratory (INL) personnel developed several methods of decontaminating WIPP salt, using surrogate contaminants and also americium (241Am). The effectiveness of the methods is evaluated qualitatively, and to the extent possible, quantitatively. One of the requirements of this effort was delivering initial results and recommendations within a few weeks. That requirement, in combination with the limited scope of the project, made in-depth analysis impractical in some instances. Of the methods tested (dry brushing, vacuum cleaning, water washing, strippable coatings, and mechanical grinding), the most practical seems to be water washing. Effectiveness is very high, and it is very easy and rapid to deploy. The amount of wastewater produced (2 L/m2) would be substantial and may not be easy to manage, but the method is the clear winner from a usability perspective. Removable surface contamination levels (smear results) from the strippable coating and water washing coupons found no residual removable contamination. Thus, whatever is left is likely adhered to (or trapped within) the salt. The other option that shows promise is the use of a fixative barrier. Bartlett Nuclear, Inc.’s Polymeric Barrier System (PBS) proved the most durable of the coatings tested. The coatings were not tested for contaminant entrapment, only for coating integrity and durability.

  14. Denaturation of DNA at high salt concentrations

    E-Print Network [OSTI]

    Maity, Arghya; Singh, Navin

    2015-01-01

    Cations present in the solution are important for the stability of two negative strands of DNA molecules. Experimental as well as theoretical results show that the DNA molecule is more stable as the concentration of salt (or cations) increases. It is known that the two strands of DNA molecule carry negative charge due to phosphate group along the strands. These cations act as a shielding particles to the two like charge strands. Recently, in an experiment it is shown that there is a critical value in the concentration of salts (or cations) that can stabilize the helical structure of DNA. If one add more salt in the solution beyond this critical value, the stability of the DNA molecule will disrupt. In this work we study the stability of DNA molecules at higher concentrations. How the stability at higher concentration can be explained through some theoretical calculations is the aim of this manuscript. We consider the PBD model with proper modifications that can explain the negative stability of the molecule a...

  15. Denaturation of DNA at high salt concentrations

    E-Print Network [OSTI]

    Arghya Maity; Amar Singh; Navin Singh

    2015-08-19

    Cations present in the solution are important for the stability of two negative strands of DNA molecules. Experimental as well as theoretical results show that the DNA molecule is more stable as the concentration of salt (or cations) increases. It is known that the two strands of DNA molecule carry negative charge due to phosphate group along the strands. These cations act as a shielding particles to the two like charge strands. Recently, in an experiment it is shown that there is a critical value in the concentration of salts (or cations) that can stabilize the helical structure of DNA. If one add more salt in the solution beyond this critical value, the stability of the DNA molecule will disrupt. In this work we study the stability of DNA molecules at higher concentrations. How the stability at higher concentration can be explained through some theoretical calculations is the aim of this manuscript. We consider the PBD model with proper modifications that can explain the negative stability of the molecule at higher concentration. Our findings are in close match with the experimental results.

  16. New public information resources on salt caverns.

    SciTech Connect (OSTI)

    Tomasko, D.; Veil, J. A.

    1999-08-25

    For the past decade, interest has been growing in using underground salt caverns for disposing of wastes. The Railroad Commission of Texas has permitted a few caverns for disposal of nonhazardous oil field waste (NOW) and one cavern for disposal of naturally occurring radioactive materials (NORM) from oil field activities. Several salt caverns in Canada have also been permitted for disposal of NOW. In addition, oil and gas agencies in Louisiana and New Mexico are developing cavern disposal regulations. The US Department of Energy (DOE) has funded several studies to evaluate the technical feasibility, legality, economic viability, and risk of disposing of NOW and NORM in caverns. The results of these studies have been disseminated to the scientific and regulatory communities. However, as use of caverns for waste disposal increases, more government and industry representatives and members of the public will become aware of this practice and will need adequate information about how disposal caverns operate and the risks they pose. In anticipation of this need, DOE has fi.mded Argonne National Laboratory to develop a salt cavern public outreach program. Key components of this program are an informational brochure designed for nontechnical persons and a website that provides greater detail on cavern operations and allows downloadable access to the reports on the topic funded by DOE. This paper provides an overview of the public outreach program.

  17. New public information resources on salt caverns.

    SciTech Connect (OSTI)

    Tomasko, D.; Veil, J. A.

    1999-08-25

    For the past decade, interest has been growing in using underground salt caverns for disposing of wastes. The Railroad Commission of Texas has permitted a few caverns for disposal of nonhazardous oil field waste (NOW) and one cavern for disposal of naturally occurring radioactive materials (NORM) from oil field activities. Several salt caverns in Canada have also been permitted for disposal of NOW. In addition, oil and gas agencies in Louisiana and New Mexico are developing cavern disposal regulations. The US Department of Energy (DOE) has funded several studies to evaluate the technical feasibility, legality, economic viability, and risk of disposing of NOW and NORM in caverns. The results of these studies have been disseminated to the scientific and regulatory communities. However, as use of caverns for waste disposal increases, more government and industry representatives and members of the public will become aware of this practice and will need adequate information about how disposal caverns operate and the risks they pose. In anticipation of this need, DOE has funded Argonne National Laboratory to develop a salt cavern public outreach program. Key components of this program are an informational brochure designed for nontechnical persons and a website that provides greater detail on cavern operations and allows downloadable access to the reports on the topic funded by DOE. This paper provides an overview of the public outreach program.

  18. Denitrification as a means of addressing nitrate-contaminated groundwater on Cape Cod, Massachusetts

    E-Print Network [OSTI]

    Motolenich-Salas, Kenneth M. (Kenneth Michael)

    1997-01-01

    The residents of Cape Cod face a problem of nitrate contamination of their groundwater (their primary source of drinking water) and their coastal and aquatic environments. Groundwater is the only source of drinking water ...

  19. Syntheses and Characterizations of One-Dimensional Coordination Polymers Generated from Cadmium Nitrate and Bipyridine Ligands

    E-Print Network [OSTI]

    zur Loye, Hans-Conrad

    Syntheses and Characterizations of One-Dimensional Coordination Polymers Generated from Cadmium Nitrate and Bipyridine Ligands Yu-Bin Dong, Ralph C. Layland, Mark D. Smith, Neil G. Pschirer, Uwe H. F

  20. Effect of potential Hanford ferrocyanide waste constituents on the reaction between ferrocyanide and nitrates/nitrites

    SciTech Connect (OSTI)

    Scheele, R.D.; Burger, L.L.; Sell, R.L.

    1993-02-01

    During the 1950s, ferrocyanide- and nitrate-bearing wastes were produced at Hanford. A concern about continued safe storage and future treatment of these wastes has arisen because ferrocyanide and nitrate mixtures can explode when heated. Because of this concern, the Pacific Northwest Laboratory has performed experimental studies to determine the conditions needed to continue storing the wastes safely. In this paper, we present the results of our studies on the effects of other potential ferrocyanide waste constituents on the explosivity of mixtures of sodium nickel ferrocyanide and sodium nitrate and nitrite. In particular, this paper presents the results of investigations on the diluent effects of equimolar sodium nitrate and nitrite, sodium nickel ferrocyanide, and sodium aluminate, and the catalyst or initiator effects of nickel sulfide.

  1. The Effect of Nanoparticle Concentration on Thermo-physical Properties of Alumina-nitrate Nanofluid 

    E-Print Network [OSTI]

    Shao, Qian

    2013-02-15

    The objective of this study was to determine how Al2O3 nanoparticle concentration affected the specific heat, heat of fusion, melting point, thermal diffusivity and thermal conductivity of Alumina-Nitrate nanofluids. Al2O3 nanoparticles were...

  2. Ecohydrological Analysis of the Transport of Nitrate and Ammonium in Sandy Desert Soils in Southern California

    E-Print Network [OSTI]

    Scanlan, Julie Marie

    2012-01-01

    of nitrate beneath desert soils. Science 302:1021-1024. DOI:deposition on vegetation and soils in Joshua Tree NationalAndraski B.J. (1997) Soil-water movement under natural-site

  3. Isomeric differentiation of polycyclic aromatic hydrocarbons using silver nitrate reactive desorption electrospray ionization

    E-Print Network [OSTI]

    Zare, Richard N.

    Isomeric differentiation of polycyclic aromatic hydrocarbons using silver nitrate reactive hydrocarbons (PAHs) are nonpolar and difficult to detect by desorption electrospray ionization. We present. Polycyclic aromatic hydrocarbons (PAHs) are one of the most prevalent forms of aquatic environmental

  4. Nighttime Measurements of Dinitrogen Pentoxide and the Nitrate Radical via Cavity Ring-Down Spectroscopy 

    E-Print Network [OSTI]

    Perkins, Katie C.

    2010-10-12

    technique, known as cavity ring-down spectroscopy, will be introduced for simultaneously measuring the nitrate radical and dinitrogen pentoxide. The cavity ring-down spectrometer was initially designed and constructed based on the experiments by Steven Brown...

  5. Nitrate ions spikes in ice cores are not suitable proxies for solar proton events

    E-Print Network [OSTI]

    Duderstadt, Katharine A; Jackman, Charles H; Randall, Cora E; Schwadron, Nathan A; Solomon, Stanley C; Spence, Harlan E; Yudin, Valery A

    2015-01-01

    Nitrate ion spikes in polar ice cores are contentiously used to estimate the intensity, frequency, and probability of historical solar proton events, quantities that are needed to prepare for potentially society-crippling space weather events. We use the Whole Atmosphere Community Climate Model to calculate how large an event would have to be to produce enough odd nitrogen throughout the atmosphere to be discernible as nitrate peaks at the Earth's surface. These hypothetically large events are compared with probability of occurrence estimates derived from measured events, sunspot records, and cosmogenic radionuclides archives. We conclude that the fluence and spectrum of solar proton events necessary to produce odd nitrogen enhancements equivalent to the spikes of nitrate ions in Greenland ice cores are unlikely to have occurred throughout the Holocene, confirming that nitrate ions in ice cores are not suitable proxies for historical individual solar proton events.

  6. Salt disposal of heat-generating nuclear waste.

    SciTech Connect (OSTI)

    Leigh, Christi D.; Hansen, Francis D.

    2011-01-01

    This report summarizes the state of salt repository science, reviews many of the technical issues pertaining to disposal of heat-generating nuclear waste in salt, and proposes several avenues for future science-based activities to further the technical basis for disposal in salt. There are extensive salt formations in the forty-eight contiguous states, and many of them may be worthy of consideration for nuclear waste disposal. The United States has extensive experience in salt repository sciences, including an operating facility for disposal of transuranic wastes. The scientific background for salt disposal including laboratory and field tests at ambient and elevated temperature, principles of salt behavior, potential for fracture damage and its mitigation, seal systems, chemical conditions, advanced modeling capabilities and near-future developments, performance assessment processes, and international collaboration are all discussed. The discussion of salt disposal issues is brought current, including a summary of recent international workshops dedicated to high-level waste disposal in salt. Lessons learned from Sandia National Laboratories' experience on the Waste Isolation Pilot Plant and the Yucca Mountain Project as well as related salt experience with the Strategic Petroleum Reserve are applied in this assessment. Disposal of heat-generating nuclear waste in a suitable salt formation is attractive because the material is essentially impermeable, self-sealing, and thermally conductive. Conditions are chemically beneficial, and a significant experience base exists in understanding this environment. Within the period of institutional control, overburden pressure will seal fractures and provide a repository setting that limits radionuclide movement. A salt repository could potentially achieve total containment, with no releases to the environment in undisturbed scenarios for as long as the region is geologically stable. Much of the experience gained from United States repository development, such as seal system design, coupled process simulation, and application of performance assessment methodology, helps define a clear strategy for a heat-generating nuclear waste repository in salt.

  7. Innovative Phase hange Thermal Energy Storage Solution for Baseload Power

    Office of Energy Efficiency and Renewable Energy (EERE)

    This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23–25, 2013 near Phoenix, Arizona.

  8. Project Profile: Innovative Thermal Energy Storage for Baseload...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lower system costs. Approach Existing thermal energy storage (TES) concepts cost about 27 per kilowatt hour thermal (kWht). The University of South Florida proposes a...

  9. Innovative Phase Change Thermal Energy Storage Solution for Baseload...

    Office of Scientific and Technical Information (OSTI)

    Report Research Org: Infinia Corporation Sponsoring Org: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE) Country of Publication: United States Language:...

  10. Project Profile: Baseload CSP Generation Integrated with Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    bonds of the storage medium. Publications, Patents, and Awards R. Buckingham, B. Wong, L. Brown, C. Sattler, F. Schaube, and A. Woerner. "Metal Oxide Based Thermochemical...

  11. Baseload coal investment decisions under uncertain carbon legislation

    SciTech Connect (OSTI)

    Joule A. Bergerson; Lester B. Lave

    2007-05-15

    More than 50% of electricity in the U.S. is generated by coal. The U.S. has large coal resources, the cheapest fuel in most areas. Coal fired power plants are likely to continue to provide much of U.S. electricity. However, the type of power plant that should be built is unclear. Technology can reduce pollutant discharges and capture and sequester the CO{sub 2} from coal-fired generation. The U.S. Energy Policy Act of 2005 provides incentives for large scale commercial deployment of Integrated Coal Gasification Combined Cycle (IGCC) systems (e.g., loan guarantees and project tax credits). This analysis examines whether a new coal plant should be pulverized coal (PC) or IGCC. Do stricter emissions standards (PM, SO{sub 2}, NOx, Hg) justify the higher costs of IGCC over PC? How does potential future carbon legislation affect the decision to add carbon capture and storage (CCS) technology? Finally, can the impact of uncertain carbon legislation be minimized? We find that SO{sub 2}, NOx, PM, and Hg emission standards would have to be far more stringent than twice current standards to justify the increased costs of the IGCC system. A CO{sub 2} tax less than $29/ton would lead companies to continuing to choose PC, paying the tax for emitted CO{sub 2}. The earlier a decision-maker believes the carbon tax will be imposed and the higher the tax, the more likely companies will choose IGCC with CCS. Having government announce the date and level of a carbon tax would promote more sensible decisions, but government would have to use a tax or subsidy to induce companies to choose the technology that is best for society. 14 refs., 6 figs., 4 tabs.

  12. Climate Change Update: Baseload Geothermal is One of the Lowest...

    Broader source: Energy.gov (indexed) [DOE]

    over 30 GWe from new hydrothermal resources, and more than 100 GWe from enhanced geothermal systems (EGS). Together, these technologies could lead to greater than 10 percent of...

  13. Project Profile: Baseload CSP Generation Integrated with Sulfur-Based

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrderNATIONALofDefine ReviewImpact AssessmentsMaterials

  14. Project Profile: Brayton Cycle Baseload Power Tower | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrderNATIONALofDefine ReviewImpact AssessmentsMaterialsBrayton

  15. Project Profile: Innovative Thermal Energy Storage for Baseload Solar Power

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrderNATIONALofDefine ReviewImpactDepartmentGeneration | Department

  16. Innovative Phase Change Thermal Energy Storage Solution for Baseload Power

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article)lasers(JournalatBaBarthe Gold-Ionic25-dimethylhexane. (JournalPhase 1

  17. Innovative Phase Change Thermal Energy Storage Solution for Baseload Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR0987P UncertaintyInitiativesInnovativeAdvancedPhase

  18. Baseload Concentrating Solar Power Generation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram:Y-12Power, Inc |Bartlesville Energy Research Center

  19. Tank 37H Salt Removal Batch Process and Salt Dissolution Mixing Study

    SciTech Connect (OSTI)

    Kwon, K.C.

    2001-09-18

    Tank 30H is the receipt tank for concentrate from the 3H Evaporator. Tank 30H has had problems, such as cooling coil failure, which limit its ability to receive concentrate from the 3H Evaporator. SRS High Level Waste wishes to use Tank 37H as the receipt tank for the 3H Evaporator concentrate. Prior to using Tank 37H as the 3H Evaporator concentrate receipt tank, HLW must remove 50 inches of salt cake from the tank. They requested SRTC to evaluate various salt removal methods for Tank 37H. These methods include slurry pumps, Flygt mixers, the modified density gradient method, and molecular diffusion.

  20. Laboratory study of nitrate photolysis in Antarctic snow. I. Observed quantum yield, domain of photolysis, and secondary chemistry

    SciTech Connect (OSTI)

    Meusinger, Carl; Johnson, Matthew S. [Department of Chemistry, University of Copenhagen, Copenhagen (Denmark); Berhanu, Tesfaye A.; Erbland, Joseph; Savarino, Joel, E-mail: jsavarino@lgge.obs.ujf-grenoble.fr [Univ. Grenoble Alpes, LGGE, F-38000 Grenoble (France); CNRS, LGGE, F-38000 Grenoble (France)

    2014-06-28

    Post-depositional processes alter nitrate concentration and nitrate isotopic composition in the top layers of snow at sites with low snow accumulation rates, such as Dome C, Antarctica. Available nitrate ice core records can provide input for studying past atmospheres and climate if such processes are understood. It has been shown that photolysis of nitrate in the snowpack plays a major role in nitrate loss and that the photolysis products have a significant influence on the local troposphere as well as on other species in the snow. Reported quantum yields for the main reaction spans orders of magnitude – apparently a result of whether nitrate is located at the air-ice interface or in the ice matrix – constituting the largest uncertainty in models of snowpack NO{sub x} emissions. Here, a laboratory study is presented that uses snow from Dome C and minimizes effects of desorption and recombination by flushing the snow during irradiation with UV light. A selection of UV filters allowed examination of the effects of the 200 and 305 nm absorption bands of nitrate. Nitrate concentration and photon flux were measured in the snow. The quantum yield for loss of nitrate was observed to decrease from 0.44 to 0.003 within what corresponds to days of UV exposure in Antarctica. The superposition of photolysis in two photochemical domains of nitrate in snow is proposed: one of photolabile nitrate, and one of buried nitrate. The difference lies in the ability of reaction products to escape the snow crystal, versus undergoing secondary (recombination) chemistry. Modeled NO{sub x} emissions may increase significantly above measured values due to the observed quantum yield in this study. The apparent quantum yield in the 200 nm band was found to be ?1%, much lower than reported for aqueous chemistry. A companion paper presents an analysis of the change in isotopic composition of snowpack nitrate based on the same samples as in this study.

  1. Experimental studies of actinides in molten salts

    SciTech Connect (OSTI)

    Reavis, J.G.

    1985-06-01

    This review stresses techniques used in studies of molten salts containing multigram amounts of actinides exhibiting intense alpha activity but little or no penetrating gamma radiation. The preponderance of studies have used halides because oxygen-containing actinide compounds (other than oxides) are generally unstable at high temperatures. Topics discussed here include special enclosures, materials problems, preparation and purification of actinide elements and compounds, and measurements of various properties of the molten volts. Property measurements discussed are phase relationships, vapor pressure, density, viscosity, absorption spectra, electromotive force, and conductance. 188 refs., 17 figs., 6 tabs.

  2. Salt Wells Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-bRenewableSMUD Wind FarmSmart Grid Project Jump to:Salt

  3. The Salt or Sodium Chloride Content of Feeds 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach); Lomanitz, S. (Sebastian)

    1920-01-01

    STATION AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS W. B. BIZZELL, Preeident BULLETIN NO. 271 OCTOBER, 1920 DIVISION OF CHEMISTRY THE SALT OR SODIUM CHLORIDE CONTENT OF FEEDS B. YOUNGBLOOD, DIRECTOK COLLEGE STATION, BRAZOS COUNTT, TEXAS I..... ................... Summary ancl conclusions. Page. l1 [Blank Page in Original Bulletin] BULLETIN XO. 271. OCTOBE- '"On THE SALT OR SODIUM CHLORIDE CONTENT OF FEI The Texas feed law requires the statement of the ingredients of many mixed feeds. Common salt or sodium...

  4. Molecular dynamics study of salt–solution interface: Solubility and surface charge of salt in water

    SciTech Connect (OSTI)

    Kobayashi, Kazuya; Liang, Yunfeng E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Matsuoka, Toshifumi E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Sakka, Tetsuo

    2014-04-14

    The NaCl salt–solution interface often serves as an example of an uncharged surface. However, recent laser-Doppler electrophoresis has shown some evidence that the NaCl crystal is positively charged in its saturated solution. Using molecular dynamics (MD) simulations, we have investigated the NaCl salt–solution interface system, and calculated the solubility of the salt using the direct method and free energy calculations, which are kinetic and thermodynamic approaches, respectively. The direct method calculation uses a salt–solution combined system. When the system is equilibrated, the concentration in the solution area is the solubility. In the free energy calculation, we separately calculate the chemical potential of NaCl in two systems, the solid and the solution, using thermodynamic integration with MD simulations. When the chemical potential of NaCl in the solution phase is equal to the chemical potential of the solid phase, the concentration of the solution system is the solubility. The advantage of using two different methods is that the computational methods can be mutually verified. We found that a relatively good estimate of the solubility of the system can be obtained through comparison of the two methods. Furthermore, we found using microsecond time-scale MD simulations that the positively charged NaCl surface was induced by a combination of a sodium-rich surface and the orientation of the interfacial water molecules.

  5. Leached salt cavern design using a fracture criterion for rock salt

    SciTech Connect (OSTI)

    Preece, D.S.; Wawersik, W.R.

    1984-01-01

    In 1975 Congress passed the Energy Conservation Act to establish a US Strategic Petroleum Reserve (SPR) with a capacity of 750 million barrels of crude oil. The most economic storage medium was determined to be salt caverns leached in salt domes in Louisiana and Texas. Salt caverns existed at several sites when the reserve was created. These were obtained by the US Department of Energy (DOE) and used to initiate SPR oil storage. In order to meet the storage capacity approved by Congress, new caverns also had to be leached. To support the resulting design effort, finite element computer programs have been used to determine the creep closure and structural stability of salt caverns. Using site specific material properties including creep models, elastic moduli and fracture data, the finite element analyses have been replaced earlier empirical approaches to cavern design. This report presents results of such finite element analyses to determine the best cavern roof shape and the minimum pillar to diameter ratio, P/D. These numerical predictions indicate that the current cavern design is safe. 12 references, 7 figures, 2 tables.

  6. Independent Oversight Review, Savannah River Site Salt Waste...

    Broader source: Energy.gov (indexed) [DOE]

    of the Savannah River Site Salt Waste Processing Facility Construction Quality and Fire Protection Systems The U.S. Department of Energy (DOE) Office of Enforcement and...

  7. Accident Investigation of the February 5, 2014, Underground Salt...

    Office of Environmental Management (EM)

    Accident Investigation of the February 5, 2014, Underground Salt Haul Truck Fire at the Waste Isolation Pilot Plant, Carlsbad NM Accident Investigation of the February 5, 2014,...

  8. Molten salt bath circulation design for an electrolytic cell

    DOE Patents [OSTI]

    Dawless, Robert K. (Monroeville, PA); LaCamera, Alfred F. (Trafford, PA); Troup, R. Lee (Murrysville, PA); Ray, Siba P. (Murrysville, PA); Hosler, Robert B. (Sarver, PA)

    1999-01-01

    An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride.

  9. Salt River Electric- Residential Energy Efficiency Rebate Programs

    Broader source: Energy.gov [DOE]

    Salt River Electric serves as the rural electric provider in Kentucky's Bullitt, Nelson, Spencer, and Washington counties. Residential customers are eligible for a variety of cash incentives for...

  10. Multispectral Imaging At Columbus Salt Marsh Area (Shevenell...

    Open Energy Info (EERE)

    Multispectral Imaging At Columbus Salt Marsh Area (Shevenell, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Multispectral Imaging...

  11. Controlled Source Frequency-Domain Magnetics At Salt Wells Area...

    Open Energy Info (EERE)

    Controlled Source Frequency-Domain Magnetics At Salt Wells Area (Montgomery, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  12. Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot...

    Broader source: Energy.gov (indexed) [DOE]

    addresses granular salt reconsolidation from three vantage points: laboratory testing, modeling, and petrofabrics. The experimental data 1) provide greater insight and...

  13. Compound and Elemental Analysis At Salt Wells Area (Coolbaugh...

    Open Energy Info (EERE)

    Compound and Elemental Analysis At Salt Wells Area (Coolbaugh, Et Al., 2006) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and...

  14. Independent Oversight Review, Savannah River Site Salt Waste...

    Broader source: Energy.gov (indexed) [DOE]

    Savannah River Site Salt Waste Processing Facility Construction Quality and Fire Protection Systems The U.S. Department of Energy (DOE) Office of Enforcement and Oversight...

  15. Project Profile: Molten Salt-Carbon Nanotube Thermal Storage

    Office of Energy Efficiency and Renewable Energy (EERE)

    Texas Engineering Experiment Station (TEES), under the Thermal Storage FOA, created a composite thermal energy storage material by embedding nanoparticles in a molten salt base material.

  16. Method for the production of uranium chloride salt

    DOE Patents [OSTI]

    Westphal, Brian R.; Mariani, Robert D.

    2013-07-02

    A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

  17. Compound and Elemental Analysis At Salt Wells Area (Shevenell...

    Open Energy Info (EERE)

    Compound and Elemental Analysis At Salt Wells Area (Shevenell & Garside, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and...

  18. Surface Indicators of Geothermal Activity at Salt Wells, Nevada...

    Open Energy Info (EERE)

    Surface Indicators of Geothermal Activity at Salt Wells, Nevada, USA, Including Warm Ground, Borate Deposits, and Siliceous Alteration Jump to: navigation, search OpenEI Reference...

  19. Development Wells At Salt Wells Area (Nevada Bureau of Mines...

    Open Energy Info (EERE)

    Development Wells At Salt Wells Area (Nevada Bureau of Mines and Geology, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Development Wells...

  20. Independent Oversight Review, Savannah River Site Salt Waste...

    Broader source: Energy.gov (indexed) [DOE]

    Savannah River Site Salt Waste Processing Facility Safety Basis and Design Development. This report documents the results of an independent oversight review of the safety basis and...

  1. Domestic Material Content in Molten-Salt Concentrating Solar...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Domestic Material Content in Molten-Salt Concentrating Solar Power Plants Craig Turchi, Parthiv Kurup, Sertac Akar, and Francisco Flores Technical Report NRELTP-5500-64429 August...

  2. Savannah River Site - Salt Waste Processing Facility Independent...

    Office of Environmental Management (EM)

    SALT WASTE PROCESSING FACILITY INDEPENDENT TECHNICAL REVIEW November 22, 2006 Conducted by: Harry Harmon, Team Lead CivilStructural Sub Team Facility Safety Sub Team Engineering...

  3. Savannah River Site Salt Waste Processing Facility Technology...

    Office of Environmental Management (EM)

    Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report Kurt D. Gerdes Harry D. Harmon Herbert G. Sutter Major C. Thompson John R. Shultz Sahid C....

  4. Molten salt bath circulation design for an electrolytic cell

    DOE Patents [OSTI]

    Dawless, R.K.; LaCamera, A.F.; Troup, R.L.; Ray, S.P.; Hosler, R.B.

    1999-08-17

    An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride. 4 figs.

  5. Project Profile: Novel Molten Salts Thermal Energy Storage for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    characteristics compared to current salts: Lower melting point Higher energy density Lower power-generation cost This program aims to develop a heat transfer fluidstorage...

  6. Uranyl nitrate-exposed rat alveolar macrophages cell death: Influence of superoxide anion and TNF ? mediators

    SciTech Connect (OSTI)

    Orona, N.S.; Tasat, D.R.

    2012-06-15

    Uranium compounds are widely used in the nuclear fuel cycle, military and many other diverse industrial processes. Health risks associated with uranium exposure include nephrotoxicity, cancer, respiratory, and immune disorders. Macrophages present in body tissues are the main cell type involved in the internalization of uranium particles. To better understand the pathological effects associated with depleted uranium (DU) inhalation, we examined the metabolic activity, phagocytosis, genotoxicity and inflammation on DU-exposed rat alveolar macrophages (12.5–200 ?M). Stability and dissolution of DU could differ depending on the dissolvent and in turn alter its biological action. We dissolved DU in sodium bicarbonate (NaHCO{sub 3} 100 mM) and in what we consider a more physiological vehicle resembling human internal media: sodium chloride (NaCl 0.9%). We demonstrate that uranyl nitrate in NaCl solubilizes, enters the cell, and elicits its cytotoxic effect similarly to when it is diluted in NaHCO{sub 3}. We show that irrespective of the dissolvent employed, uranyl nitrate impairs cell metabolism, and at low doses induces both phagocytosis and generation of superoxide anion (O{sub 2}{sup ?}). At high doses it provokes the secretion of TNF? and through all the range of doses tested, apoptosis. We herein suggest that at DU low doses O{sub 2}{sup ?} may act as the principal mediator of DNA damage while at higher doses the signaling pathway mediated by O{sub 2}{sup ?} may be blocked, prevailing damage to DNA by the TNF? route. The study of macrophage functions after uranyl nitrate treatment could provide insights into the pathophysiology of uranium?related diseases. -- Highlights: ? Uranyl nitrate effect on cultured macrophages is linked to the doses and independent of its solubility. ? At low doses uranyl nitrate induces generation of superoxide anion. ? At high doses uranyl nitrate provokes secretion of TNF?. ? Uranyl nitrate induces apoptosis through all the range of doses tested.

  7. Nitrogen Accumulation and Changes in Nitrate Leaching After Four Years of Intensive Forest Culture on Marginal Agricultural Land

    SciTech Connect (OSTI)

    Williams, T.M.; Gresham, C.A.

    2000-02-15

    Loblolly pine and sweetgum were grown with irrigation, continuous fertilizer application and insect pest control on a year old abandoned peanut field. Wells and tension lysimeters were used to measure nitrate-nitrogen in soil moisture and groundwater on three replicate transects for four years. Years 1 and 2, groundwater nitrate-nitrogen concentration exceeded drinking water standards. Years 3 and 4, groundwater nitrate-nitrogen concentration decreased where the greatest reduction occurred in soil moisture at the shallowest depths.

  8. Salt Screening and Selection: New Challenges and Considerations in the Modern

    E-Print Network [OSTI]

    Capecchi, Mario R.

    Salt Screening and Selection: New Challenges and Considerations in the Modern Pharmaceutical R · Introduction · Theoretical Considerations · pH-solubility profiles, pKa and salt formation · Prediction of salt solubility · Solubility product and in situ salt screening · Solubility/dissolution rate of salts

  9. Lead and other metals distribution in local cooking salt from the Fofi salt- spring in Akwana, Middle Benue Trough, Nigeria

    SciTech Connect (OSTI)

    Dim, L.A.; Kinyua, A.M.; Munyithya, J.M.; Adetunji, J. (Centre for Nuclear Science Techniques, Faculty of Engineering, University of Nairobi (Kenya))

    1991-06-01

    Energy Dispersive X-ray Fluorescence (EDXRF) technique has been used to determine the concentrations of lead(Pb) and other heavy metals in local cooking salts (LCS) from Akwana village, Middle Benue Trough, Nigeria. The comparison of the distribution of these metals in LCS, fake salt (FS) and the usual common salts (CS) are given. Lead was found to be enriched in LCS by factor exceeding 200 times compared to the other salts. The origin of Pb contamination in the LCS is examined and its effects on the inhabitants of the village are considered.

  10. Laboratory study of nitrate photolysis in Antarctic snow. II. Isotopic effects and wavelength dependence

    SciTech Connect (OSTI)

    Berhanu, Tesfaye A.; Erbland, Joseph; Savarino, Joël [Laboratoire de Glaciologie et Géophysique de l’Environnement, CNRS, F-38041 Grenoble (France); Univ. Grenoble Alpes, LGGE, F-38041 Grenoble (France); Meusinger, Carl; Johnson, Matthew S. [Copenhagen Center for Atmospheric Research (CCAR), Department of Chemistry, University of Copenhagen, Copenhagen (Denmark); Jost, Rémy [Laboratoire de Interdisciplinaire de Physique (LIPHY) Univ. de Grenoble, Grenoble (France); Bhattacharya, S. K. [Research Center for Environmental Changes, Academia Sinica, Nangang, Taipei 115, Taiwan (China)

    2014-06-28

    Atmospheric nitrate is preserved in Antarctic snow firn and ice. However, at low snow accumulation sites, post-depositional processes induced by sunlight obscure its interpretation. The goal of these studies (see also Paper I by Meusinger et al. [“Laboratory study of nitrate photolysis in Antarctic snow. I. Observed quantum yield, domain of photolysis, and secondary chemistry,” J. Chem. Phys. 140, 244305 (2014)]) is to characterize nitrate photochemistry and improve the interpretation of the nitrate ice core record. Naturally occurring stable isotopes in nitrate ({sup 15}N, {sup 17}O, and {sup 18}O) provide additional information concerning post-depositional processes. Here, we present results from studies of the wavelength-dependent isotope effects from photolysis of nitrate in a matrix of natural snow. Snow from Dome C, Antarctica was irradiated in selected wavelength regions using a Xe UV lamp and filters. The irradiated snow was sampled and analyzed for nitrate concentration and isotopic composition (?{sup 15}N, ?{sup 18}O, and ?{sup 17}O). From these measurements an average photolytic isotopic fractionation of {sup 15}? = (?15 ± 1.2)‰ was found for broadband Xe lamp photolysis. These results are due in part to excitation of the intense absorption band of nitrate around 200 nm in addition to the weaker band centered at 305 nm followed by photodissociation. An experiment with a filter blocking wavelengths shorter than 320 nm, approximating the actinic flux spectrum at Dome C, yielded a photolytic isotopic fractionation of {sup 15}? = (?47.9 ± 6.8)‰, in good agreement with fractionations determined by previous studies for the East Antarctic Plateau which range from ?40 to ?74.3‰. We describe a new semi-empirical zero point energy shift model used to derive the absorption cross sections of {sup 14}NO{sub 3}{sup ?} and {sup 15}NO{sub 3}{sup ?} in snow at a chosen temperature. The nitrogen isotopic fractionations obtained by applying this model under the experimental temperature as well as considering the shift in width and center well reproduced the values obtained in the laboratory study. These cross sections can be used in isotopic models to reproduce the stable isotopic composition of nitrate found in Antarctic snow profiles.

  11. Laboratory investigation of crushed salt consolidation and fracture healing

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    A laboratory test program was conducted to investigate the consolidation behavior of crushed salt and fracture healing in natural and artificial salt. Crushed salt is proposed for use as backfill in a nuclear waste repository in salt. Artificial block salt is proposed for use in sealing a repository. Four consolidation tests were conducted in a hydrostatic pressure vessel at a maximum pressure of 2500 psi (17.2 MPa) and at room temperature. Three 1-month tests were conducted on salt obtained from the Waste Isolation Pilot Plant and one 2-month test was conducted on salt from Avery Island. Permeability was obtained using argon and either a steady-state or transient method. Initial porosities ranged from 0.26 to 0.36 and initial permeabilities from 2000 to 50,000 md. Final porosities and permeabilities ranged from 0.05 to 0.19 and from <10/sup -5/ md to 110 md, respectively. The lowest final porosity (0.05) and permeability (<10/sup -5/ md) were obtained in a 1-month test in which 2.3% moisture was added to the salt at the beginning of the test. The consolidation rate was much more rapid than in any of the dry salt tests. The fracture healing program included 20 permeability tests conducted on fractured and unfractured samples. The tests were conducted in a Hoek cell at hydrostatic pressures up to 3000 psi (20.6 MPa) with durations up to 8 days. For the natural rock salt tested, permeability was strongly dependent on confining pressure and time. The effect of confining pressure was much weaker in the artificial salt. In most cases the combined effects of time and pressure were to reduce the permeability of fractured samples to the same order of magnitude (or less) as the permeability measured prior to fracturing.

  12. Salt-sensitive hypertension in mitochondrial superoxide dismutase deficiency is associated with intra-renal oxidative stress and inflammation

    E-Print Network [OSTI]

    Jin, K; Vaziri, ND

    2014-01-01

    tion, autoimmunity and salt-sensitive hypertension. Clin ExpSOD deficiency with salt-sensitive hypertension andblood pressure levels in salt-sensitive hypertension. Am J

  13. Why SALT WorksSALTwascreatedbythenonprofitAmericanStudentAssistance(ASA),who'sbeenhelpingstudents managetheireducationdebtfor50+years.ASAhasworkedwithnearly1.4millionstudentswithcollege

    E-Print Network [OSTI]

    Spirtes, Peter

    Why SALT Works. FinancialEducation SALT'sfinancialeducationcoursesuseatraditionalmethodology,aswell asself,attherighttime,intherightformat,resultinginbetter educationaloutcomes. EducationDebtManagement ThroughSALT

  14. The "salt hypothesis" is that higher levels of salt in the diet lead to higher levels of blood pressure, increasing the risk of cardiovascular disease. Intersalt, a cross-

    E-Print Network [OSTI]

    Freedman, David A.

    The "salt hypothesis" is that higher levels of salt in the diet lead to higher levels of blood pressure, increasing the risk of cardiovascular disease. Intersalt, a cross- sectional study of salt levels and blood pressures in 52 populations, is often cited to support the salt hypothesis, but the data

  15. CONTROLLED CRYSTALLIZATION OF SALTS FROM NUCLEAR WASTE SOLUTIONS

    E-Print Network [OSTI]

    Gallivan, Martha A.

    CONTROLLED CRYSTALLIZATION OF SALTS FROM NUCLEAR WASTE SOLUTIONS Daniel Gri n Martha Grover Yoshiaki Kawajiri Ronald Rousseau Published in Proceedings of the Waste Management Conference, Phoenix, AR-activity salt from nuclear waste solutions. The viability of such a process hinges on the ability to partition

  16. Leucobacter salsicius sp. nov., from a salt-fermented food

    E-Print Network [OSTI]

    Bae, Jin-Woo

    Leucobacter salsicius sp. nov., from a salt- fermented food Ji-Hyun Yun,1 Seong Woon Roh,1,2 Min, Daejeon 305-806, Republic of Korea Strain M1-8T was isolated from jeotgal, a Korean salt-fermented food contained 2,4-diaminobutyric acid, glutamic acid, alanine, glycine and c-aminobutyric acid. The major

  17. Molten salts and nuclear energy production Christian Le Bruna*

    E-Print Network [OSTI]

    Boyer, Edmond

    with solid fuels, liquid fuel in molten salt reactor, solvents for spent nuclear solid fuel in the caseMolten salts and nuclear energy production Christian Le Bruna* a Laboratoire de Physique or chlorides) have been taken in consideration very soon in nuclear energy production researches

  18. Alternative Waste Forms for Electro-Chemical Salt Waste

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Sundaram, S. K.; Riley, Brian J.; Matyas, Josef; Arreguin, Shelly A.; Vienna, John D.

    2009-10-28

    This study was undertaken to examine alternate crystalline (ceramic/mineral) and glass waste forms for immobilizing spent salt from the Advanced Fuel Cycle Initiative (AFCI) electrochemical separations process. The AFCI is a program sponsored by U.S. Department of Energy (DOE) to develop and demonstrate a process for recycling spent nuclear fuel (SNF). The electrochemical process is a molten salt process for the reprocessing of spent nuclear fuel in an electrorefiner and generates spent salt that is contaminated with alkali, alkaline earths, and lanthanide fission products (FP) that must either be cleaned of fission products or eventually replaced with new salt to maintain separations efficiency. Currently, these spent salts are mixed with zeolite to form sodalite in a glass-bonded waste form. The focus of this study was to investigate alternate waste forms to immobilize spent salt. On a mole basis, the spent salt is dominated by alkali and Cl with minor amounts of alkaline earth and lanthanides. In the study reported here, we made an effort to explore glass systems that are more compatible with Cl and have not been previously considered for use as waste forms. In addition, alternate methods were explored with the hope of finding a way to produce a sodalite that is more accepting of as many FP present in the spent salt as possible. This study was done to investigate two different options: (1) alternate glass families that incorporate increased concentrations of Cl; and (2) alternate methods to produce a mineral waste form.

  19. Treatment of plutonium process residues by molten salt oxidation

    SciTech Connect (OSTI)

    Stimmel, J.; Wishau, R.; Ramsey, K.B.; Montoya, A.; Brock, J.; Heslop, M.; Wernly, K.

    1999-04-01

    Molten Salt Oxidation (MSO) is a thermal process that can remove more than 99.999% of the organic matrix from combustible {sup 238}Pu material. Plutonium processing residues are injected into a molten salt bed with an excess of air. The salt (sodium carbonate) functions as a catalyst for the conversion of the organic material to carbon dioxide and water. Reactive species such as fluorine, chlorine, bromine, iodine, sulfur, phosphorous and arsenic in the organic waste react with the molten salt to form the corresponding neutralized salts, NaF, NaCl, NaBr, NaI, Na{sub 2}SO{sub 4}, Na{sub 3}PO{sub 4} and NaAsO{sub 2} or Na{sub 3}AsO4. Plutonium and other metals react with the molten salt and air to form metal salts or oxides. Saturated salt will be recycled and aqueous chemical separation will be used to recover the {sup 238}Pu. The Los Alamos National Laboratory system, which is currently in the conceptual design stage, will be scaled down from current systems for use inside a glovebox.

  20. SALT DAMAGE CRITERION PROOF-OF-CONCEPT RESEARCH

    SciTech Connect (OSTI)

    Kerry L. DeVries; Kirby D. Mellegard; Gary D. Callahan

    2002-11-01

    The purpose of this study was to conduct a field-scale application demonstrating the use of continuum damage mechanics to determine the minimum allowable operating pressure of compressed natural gas storage caverns in salt formations. A geomechanical study was performed of two natural gas storage caverns (one existing and one planned) utilizing state-of-the-art salt mechanics to assess the potential for cavern instability and collapse. The geomechanical study consisted primarily of laboratory testing, theoretical development, and analytical/numerical tasks. A total of 50 laboratory tests was performed on salt specimens to aid in the development and definition of the material model used to predict the behavior of rock salt. Material model refinement was performed that improved the predictive capability of modeling salt during damage healing, recovery of work-hardened salt, and the behavior of salt at stress states other than triaxial compression. Results of this study showed that the working gas capacity of the existing cavern could be increased by 18 percent and the planned cavern could be increased by 8 percent using the proposed method compared to a conventional stress-based method. Further refinement of the continuum damage model is recommended to account for known behavior of salt at stress conditions other than triaxial compression that is not characterized accurately by the existing model.

  1. Salt River (Rio Salado Oeste), Phoenix, Maricopa County, Arizona

    E-Print Network [OSTI]

    US Army Corps of Engineers

    Salt River (Rio Salado Oeste), Phoenix, Maricopa County, Arizona 18 October 2006 Abstract: The Rio of Phoenix encompassing eight miles of the Salt River from 19th to 83rd Avenues on the southwest side is $164,950,000. The project cost will be shared between the Federal government and the city of Phoenix

  2. Synthesis of permethyldodecaborate and paramagnetic dodecaborate salt

    DOE Patents [OSTI]

    Hawthorne, M. Frederick (Encino, CA); Peymann, Toralf (Los Angeles, CA)

    2002-01-01

    The dodecamethyl closo-borane dianion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.2- and anion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.- were synthesized and characterized. Dodecamethyl-closo dodecaborate (2-) was produced from [closo-B.sub.12 H.sub.12 ].sup.2-, using trimethylaluminum, and methyl iodide and modified Friedel-Crafts reaction conditions. The anion was produced from the dianion by chemical oxidation using ceric (4) ammonium nitrate in acetonitrile. The anion and dianion were both characterized by .sup.1 H and .sup.11 B NMR spectroscopy, high-resolution fast atom bombardment (FAB) mass spectrometry, cyclic voltammetry, and single-crystal X-ray diffraction. The "camouflaged" polyhedral borane anion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.2-, can be used as a precursor to materials that offer a broad spectrum of novel applications ranging from drug applications and supramolecular chemistry to use as a weakly-coordinating dianion.

  3. Does jasmonic acid control the maize shoot growth during the first phase of salt stress?

    E-Print Network [OSTI]

    Shahzad, Ahmad Naeem; Pollmann, Stephan; Schubert, Sven

    2009-01-01

    Introduction Salt stress affects plant growth in twohormones, pH) in response to salt/drought stress is notin response to osmotic/salt stress (Creelman and Mullet

  4. Global transcriptional, physiological and metabolite analyses of Desulfovibrio vulgaris Hildenborough responses to salt adaptation

    E-Print Network [OSTI]

    He, Z.

    2010-01-01

    Zhou, and J. D. Keasling. 2006. Salt stress in Desulfovibrioregulation of acid, heat, and salt tolerance in EscherichiaMR-1 in response to elevated salt conditions. J. Bacteriol.

  5. Salt stress affects polyamine concentrations and plasma membrane H+-ATPase proton pumping in maize

    E-Print Network [OSTI]

    Ingold, Mariko; Hanstein, Stefan; Schubert, Sven

    2009-01-01

    during the first phase of salt stress? J. Plant Nutr. SoilH + -ATPase in roots, is lowered by salt treatment.synthesis of polyamines under salt stress may contribute to

  6. PEP-carboxylase activity supports organic acid metabolism of maize (Zea mays) under salt stress

    E-Print Network [OSTI]

    Hatzig, Sarah Vanessa; Kumar, Ashwani; Neubert, Anja; Schubert, Sven

    2009-01-01

    physical basis for improving salt resistance in maize. Inand their expression under salt stress. J. Plant Physiol.may have a function for the salt resistance of maize during

  7. An Algorithm for Locating Microseismic Events Brian L.F. Daku, J. Eric Salt, Li Sha

    E-Print Network [OSTI]

    Saskatchewan, University of

    An Algorithm for Locating Microseismic Events Brian L.F. Daku, J. Eric Salt, Li Sha University is potash mines. Potash mines produce potash salts, and potas- sium, extracted from potash salts, is a major

  8. Invasive Spartina densiflora Brongn. Reduces Primary Productivity in a Northern California Salt Marsh

    E-Print Network [OSTI]

    Lagarde, Luc A.

    2012-01-01

    and Distichlis spicata in salt marshes at Humboldt Bay,Carolina Spartina alterniflora salt marsh. Estuaries 4:97-die-off of southern U.S. salt marshes. Science 310:1803-

  9. Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt

    E-Print Network [OSTI]

    Suo, Zhigang

    Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt 2014; published online 14 October 2014) Polyacrylamide hydrogels containing salt as electrolyte have of polyacrylamide hydrogel by introducing highly hydratable salts into the hydrogel. These hydrogels show enhanced

  10. Low time resolution analysis of polar ice cores cannot detect impulsive nitrate events

    E-Print Network [OSTI]

    Smart, D F; Melott, A L; Laird, C M

    2015-01-01

    Ice cores are archives of climate change and possibly large solar proton events (SPEs). Wolff et al. (2012) used a single event, a nitrate peak in the GISP2-H core, which McCracken et al. (2001a) time associated with the poorly quantified 1859 Carrington event, to discredit SPE-produced, impulsive nitrate deposition in polar ice. This is not the ideal test case. We critique the Wolff et al. analysis and demonstrate that the data they used cannot detect impulsive nitrate events because of resolution limitations. We suggest re-examination of the top of the Greenland ice sheet at key intervals over the last two millennia with attention to fine resolution and replicate sampling of multiple species. This will allow further insight into polar depositional processes on a sub-seasonal scale, including atmospheric sources, transport mechanisms to the ice sheet, post-depositional interactions, and a potential SPE association.

  11. Molten-Salt Depleted-Uranium Reactor

    E-Print Network [OSTI]

    Dong, Bao-Guo; Gu, Ji-Yuan

    2015-01-01

    The supercritical, reactor core melting and nuclear fuel leaking accidents have troubled fission reactors for decades, and greatly limit their extensive applications. Now these troubles are still open. Here we first show a possible perfect reactor, Molten-Salt Depleted-Uranium Reactor which is no above accident trouble. We found this reactor could be realized in practical applications in terms of all of the scientific principle, principle of operation, technology, and engineering. Our results demonstrate how these reactors can possess and realize extraordinary excellent characteristics, no prompt critical, long-term safe and stable operation with negative feedback, closed uranium-plutonium cycle chain within the vessel, normal operation only with depleted-uranium, and depleted-uranium high burnup in reality, to realize with fission nuclear energy sufficiently satisfying humanity long-term energy resource needs, as well as thoroughly solve the challenges of nuclear criticality safety, uranium resource insuffic...

  12. Technical review of Molten Salt Oxidation

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The process was reviewed for destruction of mixed low-level radioactive waste. Results: extensive development work and scaleup has been documented on coal gasification and hazardous waste which forms a strong experience base for this MSO process; it is clearly applicable to DOE wastes such as organic liquids and low-ash wastes. It also has potential for processing difficult-to-treat wastes such as nuclear grade graphite and TBP, and it may be suitable for other problem waste streams such as sodium metal. MSO operating systems may be constructed in relatively small units for small quantity generators. Public perceptions could be favorable if acceptable performance data are presented fairly; MSO will likely require compliance with regulations for incineration. Use of MSO for offgas treatment may be complicated by salt carryover. Figs, tabs, refs.

  13. Analysis of Multistage and Other Creep Data for Domal Salts

    SciTech Connect (OSTI)

    Munson, D.E.

    1998-10-01

    There have existed for some time relatively sparse creep databases for a number of domal salts. Although all of these data were analyzed at the time they were reported, to date there has not been a comprehensive, overall evaluation within the same analysis framework. Such an evaluation may prove of value. The analysis methodology is based on the Multimechanism Deformation (M-D) description of salt creep and the corresponding model parameters determined from conventional creep tests. The constitutive model of creep wss formulated through application of principles involved in micromechanical modeling. It was possible, at minimum, to obtain the steady state parameters of the creep model from the data on the domal salts. When this was done, the creep of the domal salts, as compared to the well-defined Waste Isolation Pilot Plant (WIPP) bedded clean salt, was either essentially identical to, or significantly harder (more creep resistant) than WIPP salt. Interestingly, the domal salts form two distinct groups, either sofl or hard, where the difference is roughly a factor often in creep rate between the twcl groups. As might be expected, this classification corresponds quite well to the differences in magnitude of effective creep volume losses of the Strategic Petroleum Reserve (SPR) caverns as determined by the CAVEMAN cavern pressure history analysis, depending upon the specific dome or region within the dome. Creep response shoulcl also correlate to interior cavern conditions that produce salt falls. WMle, in general, the caverns in hard sah have a noticeably greater propensity for salt falls, a smaller number of similar events are exhibited even in the caverns in soft salt.

  14. Parametric study of natural circulation flow in molten salt fuel in molten salt reactor

    SciTech Connect (OSTI)

    Pauzi, Anas Muhamad; Cioncolini, Andrea; Iacovides, Hector

    2015-04-29

    The Molten Salt Reactor (MSR) is one of the most promising system proposed by Generation IV Forum (GIF) for future nuclear reactor systems. Advantages of the MSR are significantly larger compared to other reactor system, and is mainly achieved from its liquid nature of fuel and coolant. Further improvement to this system, which is a natural circulating molten fuel salt inside its tube in the reactor core is proposed, to achieve advantages of reducing and simplifying the MSR design proposed by GIF. Thermal hydraulic analysis on the proposed system was completed using a commercial computation fluid dynamics (CFD) software called FLUENT by ANSYS Inc. An understanding on theory behind this unique natural circulation flow inside the tube caused by fission heat generated in molten fuel salt and tube cooling was briefly introduced. Currently, no commercial CFD software could perfectly simulate natural circulation flow, hence, modeling this flow problem in FLUENT is introduced and analyzed to obtain best simulation results. Results obtained demonstrate the existence of periodical transient nature of flow problem, hence improvements in tube design is proposed based on the analysis on temperature and velocity profile. Results show that the proposed system could operate at up to 750MW core power, given that turbulence are enhanced throughout flow region, and precise molten fuel salt physical properties could be defined. At the request of the authors and the Proceedings Editor the name of the co-author Andrea Cioncolini was corrected from Andrea Coincolini. The same name correction was made in the Acknowledgement section on page 030004-10 and in reference number 4. The updated article was published on 11 May 2015.

  15. 1 | De-icing salt damage to trees | November 2011 Pathology Advisory Note

    E-Print Network [OSTI]

    1 | De-icing salt damage to trees | November 2011 Pathology Advisory Note (No. 11) De-icing salt damage to trees De-icing Salt Damage to Trees Joan F Webber, David R Rose, Martin C Dobson #12;2 | De-icing salt damage to trees | November 2011 S a l t D a m a g e De-icing Salt Damage Introduction Rock salt

  16. A search for regulatory mutants of the nitrate utilization pathway of Neurospora Crassa 

    E-Print Network [OSTI]

    McDaniel, Claude Steven

    1976-01-01

    A SEARCH FOR REGULATORI MUTANTS OF THE NITRATE UTILIZATION PATHWAl OF NEUROSPORA CRASSA A Thesis by CLAUDE STEVEN MCDANIEL Submitted to the Graduate College of Texas ARM University in partial fu1fillment of the requirements for the degree... of MASTER OF SCIENCE December 1976 Major Subject: Genetics A SEARCH FOR REGULATORY MUTANTS OF THE NITRATE U1'IIIZA1'ION PA1'NNAY OF ~N A Thesis by CLAUDE STEVEN MCDANIEL Approved as to style and content by: (Chairman of Committ e) (Head oi' epar...

  17. Turning a negative into a positive: Researchers find promising use for excessive nitrate 

    E-Print Network [OSTI]

    Wythe, Kathy

    2009-01-01

    of the water pumped from the Seymour in Knox, Haskell, Baylor, Wichita, Wilbarger, and Fisher counties is used for irrigation. Based on estimates prepared by DeLaune, each part per million of nitrate/nitrogen in irrigation water will add 0.23 pounds per...=ISO-8859-1 Dr. Cristine Morgan, Texas AgriLife Research soil scientist, takes soil cores for nitrate analysis before the drip irrigation system was installed. Story by Kathy Wythe Turning a negative into a positive Researchers fi nd...

  18. Proceedings of 3rd US/German Workshop on Salt Repository Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Proceedings of 3rd USGerman Workshop on Salt Repository Research, Design, and Operation Proceedings of 3rd USGerman Workshop on Salt Repository Research, Design, and Operation...

  19. Sandia Energy - 2014 US/German Workshop on Salt Repository Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2014 USGerman Workshop on Salt Repository Research, Design, and Operation Home Stationary Power Nuclear Fuel Cycle Nuclear Energy Workshops 2014 USGerman Workshop on Salt...

  20. Sandia Energy - 2016 US/German Workshop on Salt Repository Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2016 USGerman Workshop on Salt Repository Research, Design, and Operation Home Stationary Power Nuclear Fuel Cycle Nuclear Energy Workshops 2016 USGerman Workshop on Salt...

  1. Sandia Energy - 2015 US/German Workshop on Salt Repository Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2015 USGerman Workshop on Salt Repository Research, Design, and Operation Home Stationary Power Nuclear Fuel Cycle Nuclear Energy Workshops 2015 USGerman Workshop on Salt...

  2. Protein Diffusiophoresis and Salt Osmotic Diffusion in Aqueous Onofrio Annunziata,* Daniela Buzatu,

    E-Print Network [OSTI]

    Annunziata, Onofrio

    Protein Diffusiophoresis and Salt Osmotic Diffusion in Aqueous Solutions Onofrio Annunziata salt osmotic diffusion induced by a protein concentration gradient, and is related to protein

  3. Energy Savings Calculations for Heat Island Reduction Strategies in Baton Rouge, Sacramento and Salt Lake City

    E-Print Network [OSTI]

    Konopacki, S.; Akbari, H.

    2000-01-01

    Commission Report P300-94-007. Sacramento, CA. Commercialthe (New Orleans, Sacramento & Salt Lake City) MetropolitanStrategies in Baton Rouge, Sacramento and Salt Lake City S.

  4. Invasive Spartina densiflora Brongn. Reduces Primary Productivity in a Northern California Salt Marsh

    E-Print Network [OSTI]

    Lagarde, Luc A.

    2012-01-01

    alterniflora and benthic microalgae in salt marsh food webs:dynamics of benthic microalgae in salt marshes. Pages 81-106primary productivity of microalgae and cyanobacteria (Geider

  5. Levels of metals from salt marsh plants from Southern California, USA

    E-Print Network [OSTI]

    Hoyt, Kimberly Ann

    2009-01-01

    alterniflora and benthic microalgae in salt marsh foodalterniflora and benthic microalgae in salt marsh foodSpartina, but feed on microalgae (Currin,1990). Isotope

  6. Elucidation of Mechanisms of Salinity Tolerance in Zoysia matrella Cultivars: A Study of Structure and Function of Salt Glands 

    E-Print Network [OSTI]

    Rao, Sheetal

    2012-07-16

    Salt glands are important structural adaptations in some plant and animal species that are involved in the excretion of excess salts. Zoysia matrella is a highly salt tolerant turf grass that has salt glands. Two cultivars of Z. matrella, ‘Diamond...

  7. NITRATE UTILIZATION BY PHYTOPLANKTON IN LAKE SUPERIOR IS IMPAIRED BY LOW NUTRIENT (P, Fe) AVAILABILITY AND SEASONAL LIGHT LIMITATION--

    E-Print Network [OSTI]

    Sterner, Robert W.

    NITRATE UTILIZATION BY PHYTOPLANKTON IN LAKE SUPERIOR IS IMPAIRED BY LOW NUTRIENT (P, Fe utilization in this oligotrophic system. Clean sampling methods were used to collect water from Lake Superior during spring and summer 2004, and nitrate utilization was measured by monitoring bioreporter

  8. Ion aggregation in high salt solutions. III. Computational vibrational spectroscopy of HDO in aqueous salt solutions

    SciTech Connect (OSTI)

    Choi, Jun-Ho; Lim, Sohee; Chon, Bonghwan; Cho, Minhaeng; Kim, Heejae; Kim, Seongheun

    2015-05-28

    The vibrational frequency, frequency fluctuation dynamics, and transition dipole moment of the O—D stretch mode of HDO molecule in aqueous solutions are strongly dependent on its local electrostatic environment and hydrogen-bond network structure. Therefore, the time-resolved vibrational spectroscopy the O—D stretch mode has been particularly used to investigate specific ion effects on water structure. Despite prolonged efforts to understand the interplay of O—D vibrational dynamics with local water hydrogen-bond network and ion aggregate structures in high salt solutions, still there exists a gap between theory and experiment due to a lack of quantitative model for accurately describing O—D stretch frequency in high salt solutions. To fill this gap, we have performed numerical simulations of Raman scattering and IR absorption spectra of the O—D stretch mode of HDO in highly concentrated NaCl and KSCN solutions and compared them with experimental results. Carrying out extensive quantum chemistry calculations on not only water clusters but also ion-water clusters, we first developed a distributed vibrational solvatochromic charge model for the O—D stretch mode in aqueous salt solutions. Furthermore, the non-Condon effect on the vibrational transition dipole moment of the O—D stretch mode was fully taken into consideration with the charge response kernel that is non-local polarizability density. From the fluctuating O—D stretch mode frequencies and transition dipole vectors obtained from the molecular dynamics simulations, the O—D stretch Raman scattering and IR absorption spectra of HDO in salt solutions could be calculated. The polarization effect on the transition dipole vector of the O—D stretch mode is shown to be important and the asymmetric line shapes of the O—D stretch Raman scattering and IR absorption spectra of HDO especially in highly concentrated NaCl and KSCN solutions are in quantitative agreement with experimental results. We anticipate that this computational approach will be of critical use in interpreting linear and nonlinear vibrational spectroscopies of HDO molecule that is considered as an excellent local probe for monitoring local electrostatic and hydrogen-bonding environment in not just salt but also other confined and crowded solutions.

  9. Occurrence Reporting and Processing System (ORPS)- Receipt of Administrative Order Relative to the Management of Hazardous Nitrate Salt Bearing Waste Drums at LANL

    Broader source: Energy.gov [DOE]

    Supporting Technical Document for the Radiological Release Accident Investigation Report (Phase II Report)

  10. Fluoroalkyl containing salts combined with fluorinated solvents for electrolytes

    SciTech Connect (OSTI)

    Tikhonov, Konstantin; Yip, Ka Ki; Lin, Tzu-Yuan; Erickson, Michael Jason

    2015-04-21

    Provided are electrochemical cells and electrolytes used to build such cells. An electrolyte may include a fluoroalkyl-substituted LiPF.sub.6 salt or a fluoroalkyl-substituted LiBF.sub.4 salt. In some embodiments, at least one fluorinated alkyl of the salt has a chain length of from 1 to 8 or, more specifically, between about 2 and 8. These fluorinated alkyl groups, in particular, relatively large fluorinated alkyl groups improve solubility of these salts in fluorinated solvents that are less flammable than, for example, conventional carbonate solvents. At the same time, the size of fluoroalkyl-substituted salts should be limited to ensure adequate concentration of the salt in an electrolyte and low viscosity of the electrolyte. In some embodiments, the concentration of a fluoroalkyl-substituted salt is at least about 0.5M. Examples of fluorinated solvents include various fluorinated esters, fluorinated ethers, and fluorinated carbonates, such a 1-methoxyheptafluoropropane, methyl nonafluorobutyl ether, ethyl nonafluorobutyl ether, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane, 3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-trifluoromethyl-hexane, and 1,1,1,2,3,3-hexafluoro-4-(1,1,2,3,3,3-hexafluoropropoxy)-pentane.

  11. Experimental Investigation of Two-Phase Flow in Rock Salt

    SciTech Connect (OSTI)

    Malama, Bwalya; Howard, Clifford L.

    2014-07-01

    This Test Plan describes procedures for conducting laboratory scale flow tests on intact, damaged, crushed, and consolidated crushed salt to measure the capillary pressure and relative permeability functions. The primary focus of the tests will be on samples of bedded geologic salt from the WIPP underground. However, the tests described herein are directly applicable to domal salt. Samples being tested will be confined by a range of triaxial stress states ranging from atmospheric pressure up to those approximating lithostatic. Initially these tests will be conducted at room temperature, but testing procedures and equipment will be evaluated to determine adaptability to conducting similar tests under elevated temperatures.

  12. Electrolyte materials containing highly dissociated metal ion salts

    DOE Patents [OSTI]

    Lee, Hung-Sui (East Setauket, NY); Geng, Lin (Coram, NY); Skotheim, Terje A. (Shoreham, NY)

    1996-07-23

    The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity.

  13. The Thorium Molten Salt Reactor : Moving on from the MSBR

    E-Print Network [OSTI]

    L. Mathieu; D. Heuer; R. Brissot; C. Le Brun; E. Liatard; J. M. Loiseaux; O. Méplan; E. Merle-Lucotte; A. Nuttin; J. Wilson; C. Garzenne; D. Lecarpentier; E. Walle; the GEDEPEON Collaboration

    2005-06-02

    A re-evaluation of the Molten Salt Breeder Reactor concept has revealed problems related to its safety and to the complexity of the reprocessing considered. A reflection is carried out anew in view of finding innovative solutions leading to the Thorium Molten Salt Reactor concept. Several main constraints are established and serve as guides to parametric evaluations. These then give an understanding of the influence of important core parameters on the reactor's operation. The aim of this paper is to discuss this vast research domain and to single out the Molten Salt Reactor configurations that deserve further evaluation.

  14. A mechanical model of early salt dome growth 

    E-Print Network [OSTI]

    Irwin, Frank Albert

    1988-01-01

    salt and the upper layer representing the overlying sediment, is used to study the mechanics of growth in the early stages of salt dome formation. Three cases of this model, each representing a particular rate of removal of the surface topography..., are examined to determine which case best fits observations of salt domes in East Texas, Northwest Germany, and the North Sea. These observations include the spacing and growth rate of the dome and the amount of deformation of the sediments above the dome...

  15. Electrolyte materials containing highly dissociated metal ion salts

    DOE Patents [OSTI]

    Lee, H.S.; Geng, L.; Skotheim, T.A.

    1996-07-23

    The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity. 2 figs.

  16. Gradient zone boundary control in salt gradient solar ponds

    DOE Patents [OSTI]

    Hull, John R. (Downers Grove, IL)

    1984-01-01

    A method and apparatus for suppressing zone boundary migration in a salt gradient solar pond includes extending perforated membranes across the pond at the boundaries, between the convective and non-convective zones, the perforations being small enough in size to prevent individual turbulence disturbances from penetrating the hole, but being large enough to allow easy molecular diffusion of salt thereby preventing the formation of convective zones in the gradient layer. The total area of the perforations is a sizable fraction of the membrane area to allow sufficient salt diffusion while preventing turbulent entrainment into the gradient zone.

  17. Sol-gel processing with inorganic metal salt precursors

    DOE Patents [OSTI]

    Hu, Zhong-Cheng

    2004-10-19

    Methods for sol-gel processing that generally involve mixing together an inorganic metal salt, water, and a water miscible alcohol or other organic solvent, at room temperature with a macromolecular dispersant material, such as hydroxypropyl cellulose (HPC) added. The resulting homogenous solution is incubated at a desired temperature and time to result in a desired product. The methods enable production of high quality sols and gels at lower temperatures than standard methods. The methods enable production of nanosize sols from inorganic metal salts. The methods offer sol-gel processing from inorganic metal salts.

  18. Effect of nitrate on the performance of single chamber air cathode microbial fuel cells

    E-Print Network [OSTI]

    Tullos, Desiree

    and Ecological Engineering, Oregon State University, 116 Gilmore Hall, Corvallis, OR 97331, USA b Department due to the competition between the electricity generation and denitrification processes. Over 84 by the electricity generation process. No electricity was generated when the MFC fed with 8.0 mM nitrate was moved

  19. Timed application of ammonium nitrate for optimum yield of uniform sweetpotato (lpomoea batatas) tuberous roots 

    E-Print Network [OSTI]

    Marshall, Kelly Lynn

    2001-01-01

    Sweetpotato, Ipomoea batatas L., was grown under 6 different nitrogen treatments for two lengths of time in pots of vermiculite and watered with a nutrient solution. The treatments were 50kg/Ha ammonium nitrate (NH?NO?) applied either when...

  20. Using nitrate dual isotopic composition (d15 O) as a tool for

    E-Print Network [OSTI]

    Paytan, Adina

    of NO3 À uptake and nitrification result in NO3 À with low d15 N and high d18 O values. A simple steady Francisco Bay, the largest estuary on the west coast, over 95% of the historical saltmarsh has been lost high loads of N [Los Huertos et al., 2001]. The chronic exposure to high nitrate (NO3 À ) and eutrophic

  1. Horizontal Transfer of a Nitrate Assimilation Gene Cluster and Ecological Transitions in Fungi: A

    E-Print Network [OSTI]

    Hibbett, David S.

    majority of terrestrial fungi. We propose that the acquisition of high affinity nitrate assimilation of described species of filamentous, terrestrial fungi. Without regard to clustering, nrt2 is widely metabolic pathways in the fungi [9,10]. Examples mainly involve secondary metabolite clusters, which do

  2. Nitration of Benzo[a]pyrene Adsorbed on Coal Fly Ash Particles

    E-Print Network [OSTI]

    Dutta, Prabir K.

    Nitration of Benzo[a]pyrene Adsorbed on Coal Fly Ash Particles by Nitrogen Dioxide: Role of ThermalP) by nitrogen dioxide (NO2) adsorbed on the surface of thermally activated coal fly ash and model hydrocarbons on coal fly ash by reaction with nitrogen oxides can occur in the smokestack, but with the aging

  3. 29The North Carolina Geographer The Effects of Local Weather Patterns on Nitrate and Sulfate

    E-Print Network [OSTI]

    Gamble, Douglas W.

    29The North Carolina Geographer The Effects of Local Weather Patterns on Nitrate and Sulfate Rainwater Concentrations in Wilmington, North Carolina Sarah Beth Jenkins Douglas W. Gamble Michael M. Benedetti Joan Willey University of North Carolina Wilmington Analysis of weather patterns on a synoptic

  4. Ammonium Oxidation and Nitrate Reduction in Sediments of a Hypereutrophic Lake

    E-Print Network [OSTI]

    Florida, University of

    Ammonium Oxidation and Nitrate Reduction in Sediments of a Hypereutrophic Lake E. M. D'Angelo and K. R. Reddy* ABSTRACT Internal N cycling processes in sediments and the overlying water column may is through biological oxidation and reduction of N species in the aerobic and anaerobic sediment zones

  5. Engineering Evaluation of Proposed Alternative Salt Transfer Method for the Molten Salt Reactor Experiement for the Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Carlberg, Jon A.; Roberts, Kenneth T.; Kollie, Thomas G.; Little, Leslie E.; Brady, Sherman D.

    2009-09-30

    This evaluation was performed by Pro2Serve in accordance with the Technical Specification for an Engineering Evaluation of the Proposed Alternative Salt Transfer Method for the Molten Salt Reactor Experiment at the Oak Ridge National Laboratory (BJC 2009b). The evaluators reviewed the Engineering Evaluation Work Plan for Molten Salt Reactor Experiment Residual Salt Removal, Oak Ridge National Laboratory, Oak Ridge, Tennessee (DOE 2008). The Work Plan (DOE 2008) involves installing a salt transfer probe and new drain line into the Fuel Drain Tanks and Fuel Flush Tank and connecting them to the new salt transfer line at the drain tank cell shield. The probe is to be inserted through the tank ball valve and the molten salt to the bottom of the tank. The tank would then be pressurized through the Reactive Gas Removal System to force the salt into the salt canisters. The Evaluation Team reviewed the work plan, interviewed site personnel, reviewed numerous documents on the Molten Salt Reactor (Sects. 7 and 8), and inspected the probes planned to be used for the transfer. Based on several concerns identified during this review, the team recommends not proceeding with the salt transfer via the proposed alternate salt transfer method. The major concerns identified during this evaluation are: (1) Structural integrity of the tanks - The main concern is with the corrosion that occurred during the fluorination phase of the uranium removal process. This may also apply to the salt transfer line for the Fuel Flush Tank. Corrosion Associated with Fluorination in the Oak Ridge National Laboratory Fluoride Volatility Process (Litman 1961) shows that this problem is significant. (2) Continued generation of Fluorine - Although the generation of Fluorine will be at a lower rate than experienced before the uranium removal, it will continue to be generated. This needs to be taken into consideration regardless of what actions are taken with the salt. (3) More than one phase of material - There are likely multiple phases of material in the salt (metal or compound), either suspended through the salt matrix, layered in the bottom of the tank, or both. These phases may contribute to plugging during any planned transfer. There is not enough data to know for sure. (4) Probe heat trace - The alternate transfer method does not include heat tracing of the bottom of the probe. There is a concern that this may cool the salt and other phases of materials present enough to block the flow of salt. (5) Stress-corrosion cracking - Additionally, there is a concern regarding moisture that may have been introduced into the tanks. Due to time constraints, this concern was not validated. However, if moisture was introduced into the tanks and not removed during heating the tanks before HF and F2 sparging, there would be an additional concern regarding the potential for stress-corrosion cracking of the tank walls.

  6. Solidification/Stabilization of High Nitrate and Biodenitrified Heavy Metal Sludges with a Portland Cement/Flyash System

    SciTech Connect (OSTI)

    Canonico, J.S.

    1995-07-26

    Pond 207C at Rocky Flats Environmental Technology Site (RFETS) contains process wastewaters characterized by high levels of nitrates and other salts, heavy metal contamination, and low level alpha activity. The purpose of this research was to investigate the feasibility of treating a high-nitrate waste, contaminated with heavy metals, with a coupled dewateriug and S/S process, as well as to investigate the effects of biodenitrification pretreatment on the S/S process. Pond 207C residuals served as the target waste. A bench-scale treatability study was conducted to demonstrate an S/S process that would minimize final product volume without a significant decrease in contaminant stabilization or loss of desirable physical characteristics. The process formulation recommended as a result a previous S/S treatability study conducted on Pond 207C residuals was used as the baseline formulation for this research. Because the actual waste was unavailable due to difficulties associated with radioactive waste handling and storage, a surrogate waste, of known composition and representative of Pond 207C residuals, was used throughout this research. The contaminants of regulatory concern added to the surrogate were cadmium, chromium, nickel, and silver. Product volume reduction was achieved by dewatering the waste prior to S/S treatment. The surrogate was dewatered by evaporation at 60 to 80 C to total solids contents from 43% to 78% by weight, and treated with Portland cement and fly ash. Two cement to flyash ratios were tested, 2:1 and 1:2, by weight. Contaminant leachability testing was conducted with a 0.5 water to pozzolan (the cement/flyash mixture) ratio and both cement to flyash ratios. Each product was tested for unconfined compressive strength (UCS) and for contaminant leachability by the Toxicity Characteristics Leaching Procedure (TCLP). At the highest solids content achieved by dewatering, 78% solids by weight, the predicted final waste form volume f or Pond 207C residuals after S/S processing was reduced by over 60 A when compared to the baseline process. All tested process formulations produced final waste forms with an average UCS of 100 psi or greater. Percent fixation of Chrome (VI) increased at higher solids contents. Fixation of nickel varied from over 87% to 69%, and cadmium fixation was greater than 99% at every solids content tested. Silver TCLP extract concentrations were below detection limits in all cases except for one anomalous measurement. Final product volume reduction was not achieved with coupled dewatering and S/S processing after biodenitrification pretreatment. The waste slurry became too viscous to mix with reagents after dewatering to approximately 55% solids. Fixation of contaminant constituents and final product UCSs were similar to the results of S/S processing without biodenitrification. Due to the lack of volume reduction, biodenitrification was not successful as a pretreatment for S/S processing under the test conditions of this research.

  7. Determining the extragalactic extinction law with SALT

    E-Print Network [OSTI]

    Ido Finkelman; Noah Brosch; Alexei Y. Kniazev; David Buckley; Darragh O'Donoghue; Yas Hashimoto; Nicola Loaring; Encarni Romero; Martin Still; Petri Vaisanen

    2008-08-05

    We present CCD imaging observations of early-type galaxies with dark lanes obtained with the Southern African Large Telescope (SALT) during its performance-verification phase. We derive the extinction law by the extragalactic dust in the dark lanes in the spectral range 1.11mu m^{-1} < lambda^{-1} < 2.94 mu m^{-1} by fitting model galaxies to the unextinguished parts of the image, and subtracting from these the actual images. We find that the extinction curves run parallel to the Galactic extinction curve, which implies that the properties of dust in the extragalactic enviroment are similar to those of the Milky Way. The ratio of the total V band extinction to the selective extinction between the V and B bands is derived for each galaxy with an average of 2.82+-0.38, compared to a canonical value of 3.1 for the Milky Way. The similar values imply that galaxies with well-defined dark lanes have characteristic dust grain sizes similar to those of Galactic dust.

  8. Expected brine movement at potential nuclear waste repository salt sites

    SciTech Connect (OSTI)

    McCauley, V.S.; Raines, G.E.

    1987-08-01

    The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

  9. Continuous Commissioning of Salt Lake Community College South City Campus 

    E-Print Network [OSTI]

    Deng, S.; Turner, W. D.; Hood, J.

    2004-01-01

    The State of Utah's Department of Natural Resources funded two projects in Salt Lake City to demonstrate the feasibility of the Continuous Commissioning® (CC®)1 process. The two sites selected were a modern state building, the Matheson Courthouse [1...

  10. Polyimide amic acid salts and polyimide membranes formed therefrom

    DOE Patents [OSTI]

    Ding, Yong; Bikson, Benjamin; Nelson, Joyce Katz; Macheras, James Timothy

    2004-04-06

    The invention relates to preparation and uses of novel polymeric materials, polyimide amic acid salts (PIAAS). The use of these materials for the fabrication of fluid separation membranes is further disclosed.

  11. Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance...

    Open Energy Info (EERE)

    To The Hydrocarbon Exploration In The Tuz Golu (Salt Lake) Basin, Central Anatolia, Turkey Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  12. Salt Tolerance of Landscape Plants Common to the Southwest 

    E-Print Network [OSTI]

    Miyamoto, S.

    2008-01-01

    With sharply increasing costs of providing potable water, many communities in the Southwest are attempting to utilize non-potable saline water for irrigating large landscapes. This publication provides the information related to salt effects...

  13. Regional Gravity Survey of the Northern Great Salt Lake Desert...

    Open Energy Info (EERE)

    Regional Gravity Survey of the Northern Great Salt Lake Desert and Adjacent Areas in Utah, Nevada, and Idaho Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  14. Enterprise Assessments Review of the Savannah River Site Salt...

    Broader source: Energy.gov (indexed) [DOE]

    a review of construction quality and startup test plans at the DOE Savannah River Site Salt Waste Processing Facility from November 3-7, 2014. EA is performing a series of these...

  15. Salt-induced changes of colloidal interactions in critical mixtures

    E-Print Network [OSTI]

    Ursula Nellen; Julian Dietrich; Laurent Helden; Shirish Chodankar; Kim Nygard; J. Friso van der Veen; Clemens Bechinger

    2011-04-28

    We report on salt-dependent interaction potentials of a single charged particle suspended in a binary liquid mixture above a charged wall. For symmetric boundary conditions (BC) we observe attractive particle-wall interaction forces which are similar to critical Casimir forces previously observed in salt-free mixtures. However, in case of antisymmetric BC we find a temperature-dependent crossover from attractive to repulsive forces which is in strong contrast to salt-free conditions. Additionally performed small-angle x-ray scattering experiments demonstrate that the bulk critical fluctuations are not affected by the addition of salt. This suggests that the observed crossover can not be attributed alone to critical Casimir forces. Instead our experiments point towards a possible coupling between the ionic distributions and the concentration profiles in the binary mixture which then affects the interaction potentials in such systems.

  16. Development of Molten-Salt Heat Trasfer Fluid Technology for...

    Office of Environmental Management (EM)

    f luids molt en salt s of f er a suf f icient reduct ion in levelized energy cost s t o pursue f urt her development , and t o develop t he component s required f or t...

  17. Prediction of Heat Capacities of Solid Inorganic Salts from Group

    Office of Scientific and Technical Information (OSTI)

    Prediction of Heat Capacities of Solid Inorganic Salts from Group Contributions. )&-SUB -- 7 5- g 7 A. T. M. Golam Mostafa, James M. Eakman* Department of Chemical Engineering New...

  18. Conversion of carboxylate salts to carboxylic acids via reactive distillation 

    E-Print Network [OSTI]

    Williamson, Shelly Ann

    2000-01-01

    , municipal solid wastes, sewage sludge, and industrial biosludge. Using a proprietary technology owned by Texas A&M University the wastes are first treated with lime to enhance reactivity. Then they are converted to calcium carboxylate salts using a mixed...

  19. Molten salt electrolyte battery cell with overcharge tolerance

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL); Nelson, Paul A. (Wheaton, IL)

    1989-01-01

    A molten salt electrolyte battery having an increased overcharge tolerance employs a negative electrode with two lithium alloy phases of different electrochemical potential, one of which allows self-discharge rates which permits battery cell equalization.

  20. Geomorphic structure of tidal hydrodynamics in salt marsh creeks

    E-Print Network [OSTI]

    Fagherazzi, Sergio

    .1029/2007WR006289. 1. Introduction [2] Salt marshes are important transitional areas between terrestrial providing preferen- tial pathways for marsh flooding and drainage during the tidal cycle. Because

  1. Oxidation of aqueous pollutants using ultrasound: Salt-induced enhancement

    SciTech Connect (OSTI)

    Seymour, J.D.; Gupta, R.B.

    1997-09-01

    Ultrasound can be used to oxidize aqueous pollutants; however, due to economic reasons, higher oxidation/destruction rates are needed. This study reports enhancements of reaction rates by the addition of sodium chloride salt. Using 20 kHz ultrasound, large salt-induced enhancements are observed--6-fold for chlorobenzene, 7-fold for p-ethylphenol, and 3-fold for phenol oxidation. The reaction rate enhancements are proportional to the diethyl ether--water partitioning coefficient of the pollutants. It appears that the majority of oxidation reactions occur in the bubble-bulk interface region. The addition of salt increases the ionic strength of the aqueous phase which drives the organic pollutants toward the bubble-bulk interface. A first order reaction rate equation is proposed which can represent the observed enhancement with a good accuracy. A new sonochemical-waste-oxidation process is proposed utilizing the salt-induced enhancement.

  2. EM Gains Insight from Germany on Salt-Based Repositories

    Broader source: Energy.gov [DOE]

    KARLSRUHE and PEINE, Germany – EM officials recently took part in workshops in Germany to benefit from the exchange of research and experience operating salt-based repositories for radioactive waste.

  3. Degradation of perchloroethylene and nitrate by high-activity modified green rusts 

    E-Print Network [OSTI]

    Choi, Jeong Yun

    2006-10-30

    Green rusts (GRs), a group of layered Fe(II)-Fe(III) hydroxide salts, have been observed to be effective reductants for degrading organic and inorganic contaminants under suboxic conditions. Furthermore, the addition of a ...

  4. Liquid Salt Heat Exchanger Technology for VHTR Based Applications

    SciTech Connect (OSTI)

    Anderson, Mark; Sridhara, Kumar; Allen, Todd; Peterson, Per

    2012-10-11

    The objective of this research is to evaluate performance of liquid salt fluids for use as a heat carrier for transferring high-temperature process heat from the very high-temperature reactor (VHTR) to chemical process plants. Currently, helium is being considered as the heat transfer fluid; however, the tube size requirements and the power associated with pumping helium may not be economical. Recent work on liquid salts has shown tremendous potential to transport high-temperature heat efficiently at low pressures over long distances. This project has two broad objectives: To investigate the compatibility of Incoloy 617 and coated and uncoated SiC ceramic composite with MgCl2-KCl molten salt to determine component lifetimes and aid in the design of heat exchangers and piping; and, To conduct the necessary research on the development of metallic and ceramic heat exchangers, which are needed for both the helium-to-salt side and salt-to-process side, with the goal of making these heat exchangers technologically viable. The research will consist of three separate tasks. The first task deals with material compatibility issues with liquid salt and the development of techniques for on-line measurement of corrosion products, which can be used to measure material loss in heat exchangers. Researchers will examine static corrosion of candidate materials in specific high-temperature heat transfer salt systems and develop an in situ electrochemical probe to measure metallic species concentrations dissolved in the liquid salt. The second task deals with the design of both the intermediate and process side heat exchanger systems. Researchers will optimize heat exchanger design and study issues related to corrosion, fabrication, and thermal stresses using commercial and in-house codes. The third task focuses integral testing of flowing liquid salts in a heat transfer/materials loop to determine potential issues of using the salts and to capture realistic behavior of the salts in a small scale prototype system. This includes investigations of plugging issues, heat transfer, pressure drop, and the corrosion and erosion of materials in the flowing system.

  5. Characterization of Organic Coatings on Hygroscopic Salt Particles and their Atmospheric Impacts

    SciTech Connect (OSTI)

    Zelenyuk, Alla; Ezell, Michael J.; Perraud, Veronique; Johnson, Stanley N.; Bruns, Emily; Yu, Yong; Imre, D.; Alexander, M. L.; Finlayson-Pitts, Barbara J.

    2010-03-30

    The photooxidation of ?-pinene in the presence of NO2, with and without added NaNO3 seed particles, has been studied in a large diameter flow tube. Particles formed by homogeneous nucleation and by condensation on the pre-existing seeds were sampled at various stages of the reaction, dried using four diffusion dryers, size selected at different mobility diameters (dm) using a differential mobility analyzer (DMA), and characterized with a single particle mass spectrometer (SPLAT II). It was found that homogeneously nucleated particles are spherical, have a density (?) of 1.25 ± 0.02 g cm-3 (± 2 ?) and contain a significant amount of organic nitrates. The mass spectra of the low volatility products condensed on the NaNO3 seed particles were found to be virtually the same as in the case of homogeneous nucleation. The data show that the presence of even a submonolayer of organics on the NaNO3 particles causes water retention that leads to a decrease in particle density and that the amount of water retained increases with organic coating thickness. Thicker coatings appear to inhibit water evaporation from the particle seeds altogether. This suggests that in the atmosphere, where low volatility organics are plentiful, some hygroscopic salts will retain water and have different densities and refractive indices than expected in the absence of the organic coating. This water retention combined with the organic shell on the particles can potentially impact light scattering by these particles and activity as cloud condensation nuclei (CCN), as well as heterogeneous chemistry and photochemistry on the particles.

  6. Screening of hydrodynamic interactions for polyelectrolytes in salt solution

    E-Print Network [OSTI]

    Jens Smiatek; Friederike Schmid

    2008-09-30

    We provide numerical evidence that hydrodynamic interactions are screened for charged polymers in salt solution on time scales below the Zimm time. At very short times, a crossover to hydrodynamic behavior is observed. Our conclusions are drawn from extensive coarse-grained computer simulations of polyelectrolytes in explicit solvent and explicit salt, and discussed in terms of analytical arguments based on the Debye-Hueckel approximation.

  7. Salt Bridge Formation, Rev 9.1.99 Warner Instrument Corporation1

    E-Print Network [OSTI]

    Movileanu, Liviu

    Salt Bridge Formation, Rev 9.1.99 Warner Instrument Corporation1 A procedure for the formation of agar salt bridges. The purpose of an agar salt bridge is to provide an electrical connection the following procedure to create salt bridges. This procedure involves: 1) formation of bridges 2) preparing

  8. Efficient salt removal in a continuously operated upflow microbial desalination cell with an air cathode

    E-Print Network [OSTI]

    Efficient salt removal in a continuously operated upflow microbial desalination cell with an air of salt removal. During the 4-month operation, the UMDC constantly removed salts and generated bio-electricity. At a hydraulic retention time (HRT) of 4 days (salt solution) and current production of $62 mA, the UMDC was able

  9. Global sea-salt modeling: Results and validation against multicampaign shipboard measurements

    E-Print Network [OSTI]

    Global sea-salt modeling: Results and validation against multicampaign shipboard measurements of sea-salt concentrations from five different campaigns are used to validate the sea-salt). The validity of the sea-salt parameterizations is tested by employing a global forecasting model and transport

  10. Journal of Marine Research, 69, 5777, 2011 Secondary instability of salt sheets

    E-Print Network [OSTI]

    Smyth, William David

    Journal of Marine Research, 69, 57­77, 2011 Secondary instability of salt sheets by Satoshi Kimura1), the salt-fingering instability is supplanted by the salt-sheet instability. Previous direct numerical simulation (DNS) experiments on salt sheets revealed that flow becomes turbulent via secondary instabilities

  11. Ion Secretion by Salt Glands of Desert Iguanas (Dipsosaurus dorsalis) Lisa C. Hazard*

    E-Print Network [OSTI]

    Hazard, Lisa C.

    22 Ion Secretion by Salt Glands of Desert Iguanas (Dipsosaurus dorsalis) Lisa C. Hazard* DepartmentCl-secreting salt glands of many birds and reptiles, the nasal salt glands of lizards can secrete potassium as well iguana, Dipsosaurus dorsalis. Lizards were given combinations of ions for several days, and secreted salt

  12. ECOSYSTEM ECOLOGY The effects of tree establishment on water and salt dynamics

    E-Print Network [OSTI]

    Nacional de San Luis, Universidad

    ECOSYSTEM ECOLOGY The effects of tree establishment on water and salt dynamics in naturally salt an imprint on salt accumulation and distribution patterns. We explored how the conversion of native grasslands to oak plantations affected the abundance and distribution of salts on soils and groundwater

  13. Damage in porous media due to salt crystallization

    E-Print Network [OSTI]

    Noushine Shahidzadeh-Bonn; Julie Desarnaud; François Bertrand; Xavier Chateau; Daniel Bonn

    2010-07-13

    We investigate the origins of salt damage in sandstones for the two most common salts: sodium chloride and sulfate. The results show that the observed difference in damage between the two salts is directly related to the kinetics of crystallization and the interfacial properties of the salt solutions and crystals with respect to the stone. We show that, for sodium sulfate, the existence of hydrated and anhydrous crystals and specifically their dissolution and crystallization kinetics are responsible for the damage. Using magnetic resonance imaging and optical microscopy we show that when water imbibes sodium sulfate contaminated sandstones, followed by drying at room temperature, large damage occurs in regions where pores are fully filled with salts. After partial dissolution, anhydrous sodium sulfate salt present in these regions gives rise to a very rapid growth of the hydrated phase of sulfate in the form of clusters that form on or close to the remaining anhydrous microcrystals. The rapid growth of these clusters generates stresses in excess of the tensile strength of the stone leading to the damage. Sodium chloride only forms anhydrous crystals that consequently do not cause damage in the experiments.

  14. CAVERN ROOF STABILITY FOR NATURAL GAS STORAGE IN BEDDED SALT

    SciTech Connect (OSTI)

    DeVries, Kerry L; Mellegard, Kirby D; Callahan, Gary D; Goodman, William M

    2005-06-01

    This report documents research performed to develop a new stress-based criterion for predicting the onset of damage in salt formations surrounding natural gas storage caverns. Laboratory tests were conducted to investigate the effects of shear stress, mean stress, pore pressure, temperature, and Lode angle on the strength and creep characteristics of salt. The laboratory test data were used in the development of the new criterion. The laboratory results indicate that the strength of salt strongly depends on the mean stress and Lode angle. The strength of the salt does not appear to be sensitive to temperature. Pore pressure effects were not readily apparent until a significant level of damage was induced and the permeability was increased to allow penetration of the liquid permeant. Utilizing the new criterion, numerical simulations were used to estimate the minimum allowable gas pressure for hypothetical storage caverns located in a bedded salt formation. The simulations performed illustrate the influence that cavern roof span, depth, roof salt thickness, shale thickness, and shale stiffness have on the allowable operating pressure range. Interestingly, comparison of predictions using the new criterion with that of a commonly used criterion indicate that lower minimum gas pressures may be allowed for caverns at shallow depths. However, as cavern depth is increased, less conservative estimates for minimum gas pressure were determined by the new criterion.

  15. EIS-0099: Remedial Actions at the Former Vitro Chemical Company Site, South Salt Lake, Salt Lake County, Utah

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Energy developed this statement to evaluate the environmental impacts of various scenarios associated with the cleanup of those residues remaining at the abandoned uranium mill tailings site located in South Salt Lake, Utah.

  16. The effect of sources of nitrogen on nitrate formation and nitrogen uptake by cotton plants growing on Miller clay loam 

    E-Print Network [OSTI]

    Marcos, Zilmar Ziller

    1958-01-01

    LIB RARV A & M COLLEGE OF TEXAS THE EFFECT OF SOURCES OF NITROGEN ON NITRATE FORMATION AND NITROGEN UPTAKE HX COTTON PIANTS GROWXNG ON MILLER CIAY LOAN A Thesis ZXINAR ZXLLER NARCOS AAS Submitted, to the Graduate School of the Agricultural... ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ o ~ 66 APPEEDIXt ~ ~ ~ ~ ~ ~ ~ 73 Tables l. Treatments Used in the Study. 2 Nitrate Content (ppm) of Miller Clay (0-6 ') on the 10th of July as Affected. by Rate and Source of' Nitrogen, Avexage oi' Two Repli- Nitrate Content (ppm) of Miller...

  17. Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor

    SciTech Connect (OSTI)

    Scheele, Randall D.; Casella, Andrew M.

    2010-09-28

    This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

  18. A coarse-grained model with implicit salt for RNAs: Predicting 3D structure, stability and salt effect

    SciTech Connect (OSTI)

    Shi, Ya-Zhou; Wang, Feng-Hua; Wu, Yuan-Yan; Tan, Zhi-Jie

    2014-09-14

    To bridge the gap between the sequences and 3-dimensional (3D) structures of RNAs, some computational models have been proposed for predicting RNA 3D structures. However, the existed models seldom consider the conditions departing from the room/body temperature and high salt (1M NaCl), and thus generally hardly predict the thermodynamics and salt effect. In this study, we propose a coarse-grained model with implicit salt for RNAs to predict 3D structures, stability, and salt effect. Combined with Monte Carlo simulated annealing algorithm and a coarse-grained force field, the model folds 46 tested RNAs (?45 nt) including pseudoknots into their native-like structures from their sequences, with an overall mean RMSD of 3.5 Å and an overall minimum RMSD of 1.9 Å from the experimental structures. For 30 RNA hairpins, the present model also gives the reliable predictions for the stability and salt effect with the mean deviation ? 1.0 °C of melting temperatures, as compared with the extensive experimental data. In addition, the model could provide the ensemble of possible 3D structures for a short RNA at a given temperature/salt condition.

  19. LIFE Materails: Molten-Salt Fuels Volume 8

    SciTech Connect (OSTI)

    Moir, R; Brown, N; Caro, A; Farmer, J; Halsey, W; Kaufman, L; Kramer, K; Latkowski, J; Powers, J; Shaw, H; Turchi, P

    2008-12-11

    The goals of the Laser Inertial Fusion Fission Energy (LIFE) is to use fusion neutrons to fission materials with no enrichment and minimum processing and have greatly reduced wastes that are not of interest to making weapons. Fusion yields expected to be achieved in NIF a few times per day are called for with a high reliable shot rate of about 15 per second. We have found that the version of LIFE using TRISO fuel discussed in other volumes of this series can be modified by replacing the molten-flibe-cooled TRISO fuel zone with a molten salt in which the same actinides present in the TRISO particles are dissolved in the molten salt. Molten salts have the advantage that they are not subject to radiation damage, and hence overcome the radiation damage effects that may limit the lifetime of solid fuels such as TRISO-containing pebbles. This molten salt is pumped through the LIFE blanket, out to a heat exchanger and back into the blanket. To mitigate corrosion, steel structures in contact with the molten salt would be plated with tungsten or nickel. The salt will be processed during operation to remove certain fission products (volatile and noble and semi-noble fission products), impurities and corrosion products. In this way neutron absorbers (fission products) are removed and neutronics performance of the molten salt is somewhat better than that of the TRISO fuel case owing to the reduced parasitic absorption. In addition, the production of Pu and rare-earth elements (REE) causes these elements to build up in the salt, and leads to a requirement for a process to remove the REE during operation to insure that the solubility of a mixed (Pu,REE)F3 solid solution is not exceeded anywhere in the molten salt system. Removal of the REE will further enhance the neutronics performance. With molten salt fuels, the plant would need to be safeguarded because materials of interest for weapons are produced and could potentially be removed.

  20. DWPF coupled feed flowsheet material balance with batch one sludge and copper nitrate catalyst

    SciTech Connect (OSTI)

    Choi, A.S.

    1993-09-28

    The SRTC has formally transmitted a recommendation to DWPF to replace copper formate with copper nitrate as the catalyst form during precipitate hydrolysis [1]. The SRTC was subsequently requested to formally document the technical bases for the recommendation. A memorandum was issued on August 23, 1993 detailing the activities (and responsible individuals) necessary to address the impact of this change in catalyst form on process compatibility, safety, processibility environmental impact and product glass quality [2]. One of the activities identified was the preparation of a material balance in which copper nitrate is substituted for copper formate and the identification of key comparisons between this material balance and the current Batch 1 sludge -- Late Wash material balance [3].

  1. Reduction of Perchlorate and Nitrate by Aluminum Activated by pH Change and Electrochemically Induced Pitting Corrosion. 

    E-Print Network [OSTI]

    Raut Desai, Aditya B.

    2011-08-08

    Highly oxidized species like perchlorate and nitrate that are released into the environment by anthropogenic activities are a source of concern as they have been known to contaminate groundwater. These species are extremely ...

  2. Impact of pH on the removal of fluoride, nitrate and boron by nanofiltration/reverse osmosis 

    E-Print Network [OSTI]

    Richards, Laura A.; Vuachère, Marion; Schäfer, Andrea

    2010-01-01

    The objective of this study was to evaluate the impact of pH on boron, fluoride, and nitrate retention by comparing modelled speciation predictions with retention using six different nanofiltration (NF) and reverse osmosis ...

  3. Using Nitrogen and Oxygen Isotope Compositions of Nitrate to Distinguish Contaminant Sources in Hanford Soil and Groundwater

    E-Print Network [OSTI]

    Conrad, Mark

    2008-01-01

    of unsaturated zone and groundwater nitrate contaminationfor Past and Current Groundwater Flow and Contaminationwater extracted B1L4W8 T4 groundwater B1L4Y3 T4 groundwater

  4. Nitrogen cycling in oxygen deficient zones : insights from [delta]¹?N and [delta]¹?O of nitrite and nitrate

    E-Print Network [OSTI]

    Buchwald, Carolyn

    2013-01-01

    The stable isotopes, [delta]¹?N and [delta]¹?O, of nitrite and nitrate can be powerful tools used to interpret nitrogen cycling in the ocean. They are particularly useful in regions of the ocean where there are multiple ...

  5. Nitrate movement in soils and nitrogen uptake efficiency as affected by nitrogen source, time of application, and a nitrification inhibitor 

    E-Print Network [OSTI]

    Banks, Kenneth Phanon

    1976-01-01

    NITRATE MOVEMENT IN SOILS AND NITROGEN UPTAKE EFFICIENCY AS AFFECTED BY NITROGEN SOURCEs TINE OF APPLICATIONs AIJD A NITRIFICATION INHIBITOR A Thesis by KENNETH PHAIJON BANKS Submitted to the Graduate College of Texas A&N University..., Norwood silt loam (Typic Udifluvent) and Houston Black clay (Udic Pellustert) to determine the amount of N03-N leaching from various N fertilizer sources. Nitrate N movement, as affected by time of application, was determined for (NHq)2 Sop, urea...

  6. Nitrate and nutrient accumulation in two varieties of bermudagrass (Cynodon dactylon (L.) Pers.) as influenced by soil applied fertilizer nutrients 

    E-Print Network [OSTI]

    Lovelace, Dale Allen

    1968-01-01

    NITRATE AND NUTRIENT ACCUMULATION IN TWO VARIETIES OF BDRKIDllddlidd (C~d ~dt L (L. ) F . ) AS INFLUENCED BY SOIL APPLIED FERTILIZER NUTRIENTS A Thesis By DALE A. LOVELACE Submitted to the Graduate College of the TEXAS A6H UNIVERSITY... in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1968 Major Subject: Agronomy NITRATE AND NUTRIENT ACCUMULATION IN TWO VARIETIES DP EEEEDDECEEEE EC~d ~dt L EL. ) P . ) AS INFLUENCED BY SOIL APPLIED FERTILIZER NUTRl...

  7. The influence of dose-rest cycles on the nitrate concentration of deep percolate below septic fields 

    E-Print Network [OSTI]

    Allison, John Bryan

    1976-01-01

    THE INFLUENCE OF DOSE-REST CYCLES ON THE NITRATE CONCENTRATION OF DEEP PERCOLATE BELOW SEPTIC FIELDS A Thesis by JOHN BRYAN ALLISON Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE December 1976 Major Subject: Soil Science THE INFLUENCE OF DOSE-REST CYCLES ON THE NITRATE CONCENTRATION OF DEEP PERCOLATE BELOW SEPTIC FIELDS A Thesis by JOHN BRYAN ALLISON Approved as to style and content by...

  8. TREATMENT TESTS FOR EX SITU REMOVAL OF CHROMATE & NITRATE & URANIUM (VI) FROM HANFORD (100-HR-3) GROUNDWATER FINAL REPORT

    SciTech Connect (OSTI)

    BECK MA; DUNCAN JB

    1994-01-03

    This report describes batch and ion exchange column laboratory scale studies investigating ex situ methods to remove chromate (chromium [VI]), nitrate (NO{sub 3}{sup -}) and uranium (present as uranium [VI]) from contaminated Hanford site groundwaters. The technologies investigated include: chemical precipitation or coprecipitation to remove chromate and uranium; and anion exchange to remove chromate, uranium and nitrate. The technologies investigated were specified in the 100-HR-3 Groundwater Treatability Test Plan. The method suggested for future study is anion exchange.

  9. Effect of water in salt repositories. Final report

    SciTech Connect (OSTI)

    Baes, C.F. Jr.; Gilpatrick, L.O.; Kitts, F.G.; Bronstein, H.R.; Shor, A.J.

    1983-09-01

    Additional results confirm that during most of the consolidation of polycrystalline salt in brine, the previously proposed rate expression applies. The final consolidation, however, proceeds at a lower rate than predicted. The presence of clay hastens the consolidation process but does not greatly affect the previously observed relationship between permeability and void fraction. Studies of the migration of brine within polycrystalline salt specimens under stress indicate that the principal effect is the exclusion of brine as a result of consolidation, a process that evidently can proceed to completion. No clear effect of a temperature gradient could be identified. A previously reported linear increase with time of the reciprocal permeability of salt-crystal interfaces to brine was confirmed, though the rate of increase appears more nearly proportional to the product of sigma ..delta..P rather than sigma ..delta..P/sup 2/ (sigma is the uniaxial stress normal to the interface and ..delta..P is the hydraulic pressure drop). The new results suggest that a limiting permeability may be reached. A model for the permeability of salt-crystal interfaces to brine is developed that is reasonably consistent with the present results and may be used to predict the permeability of bedded salt. More measurements are needed, however, to choose between two limiting forms of the model.

  10. Vitrification of IFR and MSBR halide salt reprocessing wastes

    SciTech Connect (OSTI)

    Siemer, D.D.

    2013-07-01

    Both of the genuinely sustainable (breeder) nuclear fuel cycles (IFR - Integral Fast Reactor - and MSBR - Molten Salt Breeder Reactor -) studied by the USA's national laboratories would generate high level reprocessing waste (HLRW) streams consisting of a relatively small amount ( about 4 mole %) of fission product halide (chloride or fluoride) salts in a matrix comprised primarily (about 95 mole %) of non radioactive alkali metal halide salts. Because leach resistant glasses cannot accommodate much of any of the halides, most of the treatment scenarios previously envisioned for such HLRW have assumed a monolithic waste form comprised of a synthetic analog of an insoluble crystalline halide mineral. In practice, this translates to making a 'substituted' sodalite ('Ceramic Waste Form') of the IFR's chloride salt-based wastes and fluoroapatite of the MSBR's fluoride salt-based wastes. This paper discusses my experimental studies of an alternative waste management scenario for both fuel cycles that would separate/recycle the waste's halide and immobilize everything else in iron phosphate (Fe-P) glass. It will describe both how the work was done and what its results indicate about how a treatment process for both of those wastes should be implemented (fluoride and chloride behave differently). In either case, this scenario's primary advantages include much higher waste loadings, much lower overall cost, and the generation of a product (glass) that is more consistent with current waste management practices. (author)

  11. Oil field waste disposal in salt caverns: An information website

    SciTech Connect (OSTI)

    Tomasko, D.; Veil, J. A.

    1999-12-10

    Argonne National Laboratory has completed the construction of a Website for the US Department of Energy (DOE) that provides detailed information on salt caverns and their use for disposing of nonhazardous oil field wastes (NOW) and naturally occurring radioactive materials (NORM). Specific topics in the Website include the following: descriptions of salt deposits and salt caverns within the US, salt cavern construction methods, potential types of wastes, waste emplacement, regulatory issues, costs, carcinogenic and noncarcinogenic human health risks associated with postulated cavern release scenarios, new information on cavern disposal (e.g., upcoming meetings, regulatory issues, etc.), other studies supported by the National Petroleum Technology Office (NPTO) (e.g., considerations of site location, cavern stability, development issues, and bedded salt characterization in the Midland Basin), and links to other associated Web sites. In addition, the Website allows downloadable access to reports prepared on the topic that were funded by DOE. Because of the large quantities of NOW and NORM wastes generated annually by the oil industry, information presented on this Website is particularly interesting and valuable to project managers, regulators, and concerned citizens.

  12. Method for making a uranium chloride salt product

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Lockport, IL)

    2004-10-05

    The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

  13. Aqueous nitrate waste treatment: Technology comparison, cost/benefit, and market analysis

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The purpose of this analysis is to provide information necessary for the Department of Energy (DOE) to evaluate the practical utility of the Nitrate to Ammonia and Ceramic or Glass (NAC/NAG/NAX) process, which is under development in the Oak Ridge National Laboratory. The NAC/NACx/NAX process can convert aqueous radioactive nitrate-laden waste to a glass, ceramic, or grout solid waste form. The tasks include, but are not limited to, the following: Identify current commercial technologies to meet hazardous and radiological waste disposal requirements. The technologies may be thermal or non-thermal but must be all inclusive (i.e., must convert a radionuclide-containing nitrate waste with a pH around 12 to a stable form that can be disposed at permitted facilities); evaluate and compare DOE-sponsored vitrification, grouting, and minimum additive waste stabilization projects for life-cycle costs; compare the technologies above with respect to material costs, capital equipment costs, operating costs, and operating efficiencies. For the NAC/NAG/NAX process, assume aluminum reactant is government furnished and ammonia gas may be marketed; compare the identified technologies with respect to frequency of use within DOE for environmental management applications with appropriate rationale for use; Assess the potential size of the DOE market for the NAC/NAG/NAX process; assess and off-gas issues; and compare with international technologies, including life-cycle estimates.

  14. Effect of Phosphate, Fluoride, and Nitrate on Gibbsite Dissolution Rate and Solubility

    SciTech Connect (OSTI)

    Herting, Daniel L.

    2014-01-29

    Laboratory tests have been completed with simulated tank waste samples to investigate the effects of phosphate, fluoride, and nitrate on the dissolution rate and equilibrium solubility of gibbsite in sodium hydroxide solution at 22 and 40{degrees}C. Results are compared to relevant literature data and to computer model predictions. The presence of sodium nitrate (3 M) caused a reduction in the rate of gibbsite dissolution in NaOH, but a modest increase in the equilibrium solubility of aluminum. The increase in solubility was not as large, though, as the increase predicted by the computer model. The presence of phosphate, either as sodium phosphate or sodium fluoride phosphate, had a negligible effect on the rate of gibbsite dissolution, but caused a slight increase in aluminum solubility. The magnitude of the increased solubility, relative to the increase caused by sodium nitrate, suggests that the increase is due to ionic strength (or water activity) effects, rather than being associated with the specific ion involved. The computer model predicted that phosphate would cause a slight decrease in aluminum solubility, suggesting some Al-PO4 interaction. No evidence was found of such an interaction.

  15. Development of high temperature transport technology for LiCl-KCl eutectic salt in pyroprocessing

    SciTech Connect (OSTI)

    Lee, Sung Ho; Lee, Hansoo; Kim, In Tae; Kim, Jeong-Guk

    2013-07-01

    The development of high-temperature transport technologies for molten salt is a prerequisite and a key issue in the industrialization of pyro-reprocessing for advanced fuel cycle scenarios. The solution of a molten salt centrifugal pump was discarded because of the high corrosion power of a high temperature molten salt, so the suction pump solution was selected. An apparatus for salt transport experiments by suction was designed and tested using LiC-KCl eutectic salt. The experimental results of lab-scale molten salt transport by suction showed a 99.5% transport rate (ratio of transported salt to total salt) under a vacuum range of 100 mtorr - 10 torr at 500 Celsius degrees. The suction system has been integrated to the PRIDE (pyroprocessing integrated inactive demonstration) facility that is a demonstrator using non-irradiated materials (natural uranium and surrogate materials). The performance of the suction pump for the transport of molten salts has been confirmed.

  16. Tests of prototype salt stripper system for IFR fuel cycle

    SciTech Connect (OSTI)

    Carls, E.L.; Blaskovitz, R.J.; Johnson, T.R. [Argonne National Lab., IL (United States); Ogata, T. [Central Research Inst. of Electric Power Industry, Tokyo (Japan)

    1993-09-01

    One of the waste treatment steps for the on-site reprocessing of spent fuel from the Integral Fast Reactor fuel cycles is stripping of the electrolyte salt used in the electrorefining process. This involves the chemical reduction of the actinides and rare earth chlorides forming metals which then dissolve in a cadmium pool. To develop the equipment for this step, a prototype salt stripper system has been installed in an engineering scale argon-filled glovebox. Pumping trails were successful in transferring 90 kg of LiCl-KCl salt containing uranium and rare earth metal chlorides at 500{degree}C from an electrorefiner to the stripper vessel at a pumping rate of about 5 L/min. The freeze seal solder connectors which were used to join sections of the pump and transfer line performed well. Stripping tests have commenced employing an inverted cup charging device to introduce a Cd-15 wt % Li alloy reductant to the stripper vessel.

  17. Injector nozzle for molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, William A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA)

    1996-01-01

    An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath.

  18. Injector nozzle for molten salt destruction of energetic waste materials

    DOE Patents [OSTI]

    Brummond, W.A.; Upadhye, R.S.

    1996-02-13

    An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath. 2 figs.

  19. Salt transport extraction of transuranium elements from lwr fuel

    DOE Patents [OSTI]

    Pierce, R. Dean (Naperville, IL); Ackerman, John P. (Downers Grove, IL); Battles, James E. (Oak Forest, IL); Johnson, Terry R. (Wheaton, IL); Miller, William E. (Naperville, IL)

    1992-01-01

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl.sub.2 and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750.degree. C. to about 850.degree. C. to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl.sub.2 having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO.sub.2. The Ca metal and CaCl.sub.2 is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including Mg Cl.sub.2 to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy.

  20. Salt transport extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Pierce, R.D.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Miller, W.E.

    1992-11-03

    A process is described for separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl[sub 2] and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750 C to about 850 C to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl[sub 2] having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO[sub 2]. The Ca metal and CaCl[sub 2] is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including MgCl[sub 2] to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy. 2 figs.

  1. Attenuation of acoustic waves in glacial ice and salt domes

    E-Print Network [OSTI]

    P. B. Price

    2005-06-27

    Two classes of natural solid media (glacial ice and salt domes) are under consideration as media in which to deploy instruments for detection of neutrinos with energy >1e18 eV. Though insensitive to 1e11 to 1e16 eV neutrinos for which observatories (e.g., AMANDA and IceCube) that utilize optical Cherenkov radiation detectors are designed, radio and acoustic methods are suited for searches for the very low fluxes of neutrinos with energies >1017 eV. This is because, due to the very long attenuation lengths of radio and acoustic waves in ice and salt, detection modules can be spaced very far apart. In this paper, I calculate the absorption and scattering coefficients as a function of frequency and grain size for acoustic waves in glacial ice and salt domes and show that experimental measurements on laboratory samples and in glacial ice and salt domes are consistent with theory. For South Pole ice with grain size 0.2 cm at -51 degrees C, scattering lengths are calculated to be 2000 km and 25 km at 10 kHz and 30 kHz, respectively, and the absorption length is calculated to be 9 km at frequencies above 100 Hz. For NaCl (rock salt) with grain size 0.75 cm, scattering lengths are calculated to be 120 km and 1.4 km at 10 kHz and 30 kHz, and absorption lengths are calculated to be 30,000 km and 3300 km at 10 kHz and 30 kHz. Existing measurements are consistent with theory. For ice, absorption is the limiting factor; for salt, scattering is the limiting factor.

  2. The role of plasma membrane H+-ATPase and apoplastic pH in adaptation of maize (Zea mays) to salt stress

    E-Print Network [OSTI]

    Pitann, Britta; Mühling, Karl H.

    2009-01-01

    NaCl is the predominant salt species, whose principleconcept for understanding of salt-induced growth repressionthe purpose of designing salt- resistant crops, the complete

  3. Avian Communities in Tidal Salt Marshes of San Francisco Bay: A Review of Functional Groups by Foraging Guild and Habitat Association

    E-Print Network [OSTI]

    2011-01-01

    report on the Cargill Salt Ponds. Senate select committee onartificial salt evaporation ponds of the San Francisco BayMA. 2005. South Bay salt ponds restoration project short-

  4. Materials and methods for stabilizing nanoparticles in salt solutions

    DOE Patents [OSTI]

    Robinson, David Bruce; Zuckermann, Ronald; Buffleben, George M.

    2013-06-11

    Sequence-specific polymers are proving to be a powerful approach to assembly and manipulation of matter on the nanometer scale. Ligands that are peptoids, or sequence-specific N-functional glycine oligomers, allow precise and flexible control over the arrangement of binding groups, steric spacers, charge, and other functionality. We have synthesized short peptoids that can prevent the aggregation of gold nanoparticles in high-salt environments including divalent salt, and allow co-adsorption of a single DNA molecule. This degree of precision and versatility is likely to prove essential in bottom-up assembly of nanostructures and in biomedical applications of nanomaterials.

  5. Damage due to salt crystallization in porous media

    E-Print Network [OSTI]

    Noushine Shahidzadeh Bonn; Francois Bertrand; Daniel Bonn

    2009-06-13

    We investigate salt crystallization in porous media that can lead to their disintegration. For sodium sulfate we show for the first time experimentally that when anhydrous crystals are wetted with water, there is very rapid growth of the hydrated form of sulfate in clusters that nucleate on anhydrous salt micro crystals. The molar volume of the hydrated crystals being four times bigger, the growth of these clusters can generate stresses in excess of the tensile strength of the stone and lead therefore to damage.

  6. Simulation of water transport in heated rock salt

    SciTech Connect (OSTI)

    Schlich, M.; Jockwer, N.

    1986-01-01

    This paper summarizes computer simulation studies on water transport in German rock salt. Based on JOCKWERS experimental investigations on water content and water liberation, the object of these studies was to select a water transport model, that matches the water inflow which was measured in some heater experiments in the Asse Salt Mine. The main result is, that an evaporation front model, with Knudsen-type vapor transport combined with fluid transport by thermal expansion of the adsorbed water layers in the non evaporated zone, showed the best agreement with experimental evidence.

  7. Control of Soluble Salts in Farming and Gardening. 

    E-Print Network [OSTI]

    Longenecker, D. E.; Lyerly, P. J.

    1974-01-01

    by the high salinity of the ground waters of that area. Many wells in the smaller irrigated areas of 9: * -- West Central Texas contain enough soluble salts to affect crop growth. In the extensive High Plains irrigated area, gradual depletion of good... and how these problems often can be rec- ognized, minimized or even eliminated by good man- agement or simple know-how. 'From paper by C. Godfrey (27) and recent unpublished studies by the SOLUBLE SALTS IN WATERS AND SOILS 1 Trvar Water Development...

  8. Chemical reactivity of nitrates and nitrites towards TBP and potassium nickel ferrocyanide between 30 and 300 deg

    SciTech Connect (OSTI)

    Lambertin, D.; Chartier, D.; Joussot-Dubien, C. [CEA Valrho, DTCD/SPDE/L2ED, 30 - Bagnols sur Ceze (France)

    2007-07-01

    Since the late sixties, bitumen has been widely used by the nuclear industry as a matrix for the immobilization of low- and intermediate level radioactive waste originating mainly from the nuclear activities: precipitation or evaporator concentrates, ion exchange resins, incinerator ashes, and filter materials. Depending on bitumen and operating conditions, bituminization of radioactive waste can be operated between 130 and 180 deg. C, so chemical reaction can be induced with nitrate or nitrite towards elements contained in waste (TPB, potassium nickel ferrocyanide and cobalt compound) and bitumen. These reactions are mainly exothermic this is the reason why the enthalpy reaction and their temperature of initiation have to be determined independently of their concentration in waste. In this work, we have studied by Calvet Calorimetry at 0.1 deg. C/min heating rates, the behaviour of chemical elements especially oxido-reduction couples that can react at a temperature range 100- 300 deg. C (Nitrate/PPFeNi, Nitrite/PPFeNi, Nitrate/TBP, Nitrite/TBP, Nitrate/bitumen and Nitrite/bitumen). The initial temperature reaction of nitrates or nitrites towards potassium nickel ferrocyanide (PPFeNi) has been studied and is equal respectively to 225 deg. C and 175 deg. C. Because of the large scale temperature reaction of nitrate and PPFeNi, enthalpy reaction can not be calculated, although enthalpy reaction of nitrite and PPFeNi is equal to 270 kJ/mol of nitrite. Sodium Nitrate and TBP behaviour has been investigated, and an exothermic reaction at 135 deg. C until 250 deg. C is evidenced. The exothermic energy reaction is a function of TBP concentration and the enthalpy reaction has been determined. (authors)

  9. Review: The World of the Salt Marsh: Appreciating and Protecting the Tidal Marshes of the Southeastern Atlantic Coast

    E-Print Network [OSTI]

    Miller, Ryder W.

    2013-01-01

    Review: The World of the Salt Marsh: Appreciating andCharles. The World of the Salt Marsh: Appreciating andseafood movement. World of the Salt Marsh can be a “Silent

  10. Effects of Nutrient Additions on Three Coastal Salt Marsh Plants Found in Sunset Cove, Texas 

    E-Print Network [OSTI]

    Rulon, Leslie

    2012-02-14

    Eutrophication, particularly due to nitrogen (N) and phosphorus (P) input, has been massively altered by anthropogenic activities. Thus it is important to understand the impact on salt marsh plants; however studies on salt ...

  11. Supporting Information Geobacter sp. SD-1 with enhanced electrochemical activity in high salt

    E-Print Network [OSTI]

    1 Supporting Information Geobacter sp. SD-1 with enhanced electrochemical activity in high salt title: Geobacter sp. SD-1 in high salt solutions #12;2 Fig. S1. Current generation as a function of time

  12. Supplementary Information for: In situ spatially and temporally resolved measurements of salt

    E-Print Network [OSTI]

    Santiago, Juan G.

    Supplementary Information for: In situ spatially and temporally resolved measurements of salt additional figures. #12;SI1 SI1: Additional comparisons of salt concentration profiles In Figure SI1, we

  13. New Opportunities for Metals Extraction and Waste Treatment by Electrochemical Processing in Molten Salts

    E-Print Network [OSTI]

    Sadoway, Donald R.

    2001-01-01

    Molten salt electrolysis is a proven technology for the extraction of metals -- all the world's primary aluminum is produced in this manner. The unique properties of molten salts also make them

  14. Sample results from the interim salt disposition program macrobatch 9 tank 21H qualification samples

    SciTech Connect (OSTI)

    Peters, T. B.

    2015-11-01

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 9 for the Interim Salt Disposition Program (ISDP). This document reports characterization data on the samples of Tank 21H.

  15. Examination of the Effects of Sea Salt Aerosols on Southeast Texas Ozone and Secondary Organic Aerosol 

    E-Print Network [OSTI]

    Benoit, Mark David

    2013-02-06

    of this research is to examine sea salt aerosols and their impact on polluted environments. Sea salt aerosols act as Cloud Condensation Nuclei (CCN) as well as providing a surface for heterogeneous reactions. Such reactions have implications for trace gases...

  16. How different home styles are valued in the Salt Lake City market

    E-Print Network [OSTI]

    Peterson, Barrett, 1976-

    2003-01-01

    This thesis focuses on market valuation of attributes of single family housing in the Salt Lake City market. Using data from different sub-regions of Salt Lake County, this paper addresses the question of buyer demand with ...

  17. Transport Processes in a Salt-Dome Environment

    E-Print Network [OSTI]

    Kornhuber, Ralf

    Transport Processes in a Salt-Dome Environment Sylvia Rockel Sebastian Sklorz Maurizio Vaccaro Summerschool in Modelling of Mass and Energy Transport in Porous Media With Practical Applications Berlin, 15 october 2010 #12;Problem · Subsurface flow and transport within a vertical cross section of a sedimentary

  18. Molten salt processing of mixed wastes with offgas condensation

    SciTech Connect (OSTI)

    Cooper, J.F.; Brummond, W.; Celeste, J.; Farmer, J.; Hoenig, C.; Krikorian, O.H.; Upadhye, R. ); Gay, R.L.; Stewart, A.; Yosim, S. . Energy Systems Group)

    1991-05-13

    We are developing an advanced process for treatment of mixed wastes in molten salt media at temperatures of 700--1000{degrees}C. Waste destruction has been demonstrated in a single stage oxidation process, with destruction efficiencies above 99.9999% for many waste categories. The molten salt provides a heat transfer medium, prevents thermal surges, and functions as an in situ scrubber to transform the acid-gas forming components of the waste into neutral salts and immobilizes potentially fugitive materials by a combination of particle wetting, encapsulation and chemical dissolution and solvation. Because the offgas is collected and assayed before release, and wastes containing toxic and radioactive materials are treated while immobilized in a condensed phase, the process avoids the problems sometimes associated with incineration processes. We are studying a potentially improved modification of this process, which treats oxidizable wastes in two stages: pyrolysis followed by catalyzed molten salt oxidation of the pyrolysis gases at ca. 700{degrees}C. 15 refs., 5 figs., 1 tab.

  19. Decommissioning of the Molten Salt Reactor Experiment: A technical evaluation

    SciTech Connect (OSTI)

    Notz, K.J.

    1988-01-01

    This report completes a technical evaluation of decommissioning planning for the former Molten Salt Reactor Experiment, which was shut down in December, 1969. The key issues revolve around the treatment and disposal of some five tons of solid fuel salt which contains over 30 kg of fissionable uranium-233 plus fission products and higher actinides. The chemistry of this material is complicated by the formation of elemental fluorine via a radiolysis reaction under certain conditions. Supporting studies carried out as part of this evaluation include (a) a broad scope analysis of possible options for storage/disposal of the salts, (b) calculation of nuclide decay in future years, (c) technical evaluation of the containment facility and hot cell penetrations, (d) review and update of surveillance and maintenance procedures, (e) measurements of facility groundwater radioactivity and sump pump operation, (f) laboratory studies of the radiolysis reaction, and (g) laboratory studies which resulted in finding a suitable getter for elemental fluorine. In addition, geologic and hydrologic factors of the surrounding area were considered, and also the implications of entombment of the fuel in-place with concrete. The results of this evaluation show that the fuel salt cannot be left in its present form and location permanently. On the other hand, extended storage in its present form is quite acceptable for 20 to 30 years, or even longer. For continued storage in-place, some facility modifications are recommended. 30 refs., 5 figs., 9 tabs.

  20. Project Profile: Long-Shafted Molten Salt Pump

    Office of Energy Efficiency and Renewable Energy (EERE)

    Pratt & Whitney Rocketdyne (PWR), under the CSP R&D FOA, is validating the manufacturability of a large-scale molten salt receiver panel and then confirming its operation in prototypic solar flux. This work is an important step in reducing the LCOE from a central receiver solar power plant.

  1. Technology for treatment of salt residue stored at NPPs

    SciTech Connect (OSTI)

    Kobelev, A.P.; Savkin, A.E.; Sinjakin, O.G.; Kachalova, E.A.; Sorokoletova, A.N.; Nechaev, V.R. [SUE Moscow SIA Radon (Russian Federation)

    2007-07-01

    At Moscow SIA 'Radon', three (3) options for NPP salt residue treatment were developed and tested. Option 1 consists of dissolving the salt residue and subsequent treatment by ozonization, separation of the deposits formed from ozonization and selective cleaning by ferrocyanide sorbents. Option 2 consists of fusion of the salt residue, addition of glass-forming additives and melting of borosilicate glass in a melter such as a 'cold crucible'. Option 3 consists of dissolving the salt residue, oxidation of the solution obtained, removal of radionuclides by collectors and the separate handling of formed deposits and the solution. The deposits containing more than 99 % of the activity are directed to vitrification and the solution is directed either to a concentrates dryer or to cementation. The vitrified waste product is placed in repository for solid radioactive waste storage and the solidified product from the solution goes to an industrial waste disposal site or a repository specially developed at NPP sites for 'exempt waste' products by IAEA classification. (authors)

  2. Standard practice for modified salt spray (fog) testing

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2009-01-01

    1.1 This practice covers and sets forth conditions for five modifications in salt spray (fog) testing for specification purposes. These are in chronological order of their development: 1.1.1 Annex A1, acetic acid-salt spray test, continuous. 1.1.2 Annex A2, cyclic acidified salt spray test. 1.1.3 Annex A3, seawater acidified test, cyclic (SWAAT). 1.1.4 Annex A4, SO2 salt spray test, cyclic. 1.1.5 Annex A5, dilute electrolyte cyclic fog dry test. 1.2 This practice does not prescribe the type of modification, test specimen or exposure periods to be used for a specific product, nor the interpretation to be given to the results. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to consult and establish appropriate safety and health practices and determine the applicabilit...

  3. TGS measurements of pyrochemical salts at Rocky Flats

    SciTech Connect (OSTI)

    Mercer, D. J.; Hansen, J. S.; Lestone, J. P.; Prettyman, T. H.

    2001-01-01

    A new skid-mounted tomographic gamma scanner (TGS) was designed to assist in the decommissioning of Rocky Flats Building 37 1, This instrument was used to assay pyrochemical salts as a prerequisite for disposal at the Waste Isolation Pilot Plant (WIPP). The following paper discusses measurement challenges and results from the first year of operation of the instrument.

  4. The Estimation of Salt and Molasses in Mixed Feeds 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1931-01-01

    . KNOX, M. S., Animal IIushandry A. K. MACKEY, M. S., Animnl Hrrshondry *Dean School of Veterinary Medicine. ?As of May 1. 1931. **In cooperation with U. S. Department of Agriculture. A statement of the percentage of salt in mixed feeds is required...

  5. Sample Results from Routine Salt Batch 7 Samples

    SciTech Connect (OSTI)

    Peters, T.

    2015-05-13

    Strip Effluent Hold Tank (SEHT) and Decontaminated Salt Solution Hold Tank (DSSHT) samples from several of the “microbatches” of Integrated Salt Disposition Project (ISDP) Salt Batch (“Macrobatch”) 7B have been analyzed for 238Pu, 90Sr, 137Cs, Inductively Coupled Plasma Emission Spectroscopy (ICPES), and Ion Chromatography Anions (IC-A). The results from the current microbatch samples are similar to those from earlier samples from this and previous macrobatches. The Actinide Removal Process (ARP) and the Modular Caustic-Side Solvent Extraction Unit (MCU) continue to show more than adequate Pu and Sr removal, and there is a distinct positive trend in Cs removal, due to the use of the Next Generation Solvent (NGS). The Savannah River National Laboratory (SRNL) notes that historically, most measured Concentration Factor (CF) values during salt processing have been in the 12-14 range. However, recent processing gives CF values closer to 11. This observation does not indicate that the solvent performance is suffering, as the Decontamination Factor (DF) has still maintained consistently high values. Nevertheless, SRNL will continue to monitor for indications of process upsets. The bulk chemistry of the DSSHT and SEHT samples do not show any signs of unusual behavior.

  6. MANAGEMENT OF GROUNDWATER IN SALT WATER INGRESS COASTAL AQUIFERS

    E-Print Network [OSTI]

    Kumar, C.P.

    MANAGEMENT OF GROUNDWATER IN SALT WATER INGRESS COASTAL AQUIFERS C. P. Kumar Scientist `E1 dealing with exploitation, restoration and management of fresh groundwater in coastal aquifers, the key is disturbed by groundwater withdrawals and other human activities that lower groundwater levels, reduce fresh

  7. Salt Lake City, Utah: Solar in Action (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01

    This brochure provides an overview of the challenges and successes of Salt Lake City, UT, a 2007 Solar America City awardee, on the path toward becoming a solar-powered community. Accomplishments, case studies, key lessons learned, and local resource information are given.

  8. Dynamic Salting Route Optimisation using Evolutionary Computation Hisashi Handa

    E-Print Network [OSTI]

    Yao, Xin

    , if salt is spread when it is not actually required, there are unnecessary financial and environ- mental realises daily dynamic routing and it will yield considerable ben- efits for areas with a marginal ice effective use of resources (i.e. treat- ment vehicles, personnel and de-icing chemical material). The aim

  9. Anionic Salt Programs for Close-Up Dry Cows 

    E-Print Network [OSTI]

    Stokes, Sandra R.

    1998-12-17

    Dairy farmers can improve long-term milk production by having a well-managed program for dry cows during the last 3 weeks before calving. This publication explains how an anionic salt program can help control subclinical hypocalcemia and "droopy cow...

  10. SALT DAMAGE CRITERION PROOF-OF-CONCEPT RESEARCH

    SciTech Connect (OSTI)

    Kerry L. DeVries; Kirby D. Mellegard; Gary D. Callahan

    2001-12-01

    This document is the annual technical progress report for Department of Energy Contract No. DE-FC26-00NT41026 entitled Proof-of-Concept Research for an Advanced Design Criterion to Improve Working Gas Capacity for Natural Gas Storage Caverns in Salt Formations. This report covers the reporting period from October 1, 2000, through September 30, 2001. During this reporting period, the project was initiated and work was performed to develop structural models that will be used to evaluate two compressed natural gas storage caverns in the McIntosh Dome northwest of Mobile, Alabama. Information necessary to define the structural models include site-specific stress, temperature, geometry, stratigraphy, and operating scenarios in the dome and for the caverns. Additionally, material model development for the salt at the McIntosh Dome was initiated. Material model development activities include acquisition of salt core for testing, laboratory testing, and regression analyses to determine site-specific model parameter values that describe the behavior of salt around a storage cavern. Although not performed during this reporting period, the information and models developed will be used to perform advanced design storage cavern analyses for the Bay Gas caverns to determine the operating pressure ranges to maintain stable conditions.

  11. Cold adaptation of the mononuclear molybdoenzyme periplasmic nitrate reductase from the Antarctic bacterium Shewanella gelidimarina

    SciTech Connect (OSTI)

    Simpson, Philippa J.L.; Codd, Rachel; School of Medical Sciences and Bosch Institute, University of New South Wales, New South Wales 2006

    2011-11-04

    Highlights: Black-Right-Pointing-Pointer Cold-adapted phenotype of NapA from the Antarctic bacterium Shewanella gelidimarina. Black-Right-Pointing-Pointer Protein homology model of NapA from S. gelidimarina and mesophilic homologue. Black-Right-Pointing-Pointer Six amino acid residues identified as lead candidates governing NapA cold adaptation. Black-Right-Pointing-Pointer Molecular-level understanding of designing cool-temperature in situ oxyanion sensors. -- Abstract: The reduction of nitrate to nitrite is catalysed in bacteria by periplasmic nitrate reductase (Nap) which describes a system of variable protein subunits encoded by the nap operon. Nitrate reduction occurs in the NapA subunit, which contains a bis-molybdopterin guanine dinucleotide (Mo-MGD) cofactor and one [4Fe-4S] iron-sulfur cluster. The activity of periplasmic nitrate reductase (Nap) isolated as native protein from the cold-adapted (psychrophilic) Antarctic bacterium Shewanella gelidimarina (Nap{sub Sgel}) and middle-temperature adapted (mesophilic) Shewanella putrefaciens (Nap{sub Sput}) was examined at varied temperature. Irreversible deactivation of Nap{sub Sgel} and Nap{sub Sput} occurred at 54.5 and 65 Degree-Sign C, respectively. When Nap{sub Sgel} was preincubated at 21-70 Degree-Sign C for 30 min, the room-temperature nitrate reductase activity was maximal and invariant between 21 and 54 Degree-Sign C, which suggested that Nap{sub Sgel} was poised for optimal catalysis at modest temperatures and, unlike Nap{sub Sput}, did not benefit from thermally-induced refolding. At 20 Degree-Sign C, Nap{sub Sgel} reduced selenate at 16% of the rate of nitrate reduction. Nap{sub Sput} did not reduce selenate. Sequence alignment showed 46 amino acid residue substitutions in Nap{sub Sgel} that were conserved in NapA from mesophilic Shewanella, Rhodobacter and Escherichia species and could be associated with the Nap{sub Sgel} cold-adapted phenotype. Protein homology modeling of Nap{sub Sgel} using a mesophilic template with 66% amino acid identity showed the majority of substitutions occurred at the protein surface distal to the Mo-MGD cofactor. Two mesophilic {r_reversible} psychrophilic substitutions (Asn {r_reversible} His, Val {r_reversible} Trp) occurred in a region close to the surface of the NapA substrate funnel resulting in potential interdomain {pi}-{pi} and/or cation-{pi} interactions. Three mesophilic {r_reversible} psychrophilic substitutions occurred within 4.5 A of the Mo-MGD cofactor (Phe {r_reversible} Met, Ala {r_reversible} Ser, Ser {r_reversible} Thr) resulting in local regions that varied in hydrophobicity and hydrogen bonding networks. These results contribute to the understanding of thermal protein adaptation in a redox-active mononuclear molybdenum enzyme and have implications in optimizing the design of low-temperature environmental biosensors.

  12. Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc (Lakewood, CO)

    2003-06-24

    A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

  13. Electrodialysis-based separation process for salt recovery and recycling from waste water

    DOE Patents [OSTI]

    Tsai, Shih-Perng (Naperville, IL)

    1997-01-01

    A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid.

  14. Electrodialysis-based separation process for salt recovery and recycling from waste water

    DOE Patents [OSTI]

    Tsai, S.P.

    1997-07-08

    A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants-containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid. 6 figs.

  15. Standard test method for isotopic abundance analysis of uranium hexa?uoride and uranyl nitrate solutions by multi-collector, inductively coupled plasma-mass spectrometry

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01

    Standard test method for isotopic abundance analysis of uranium hexa?uoride and uranyl nitrate solutions by multi-collector, inductively coupled plasma-mass spectrometry

  16. BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Lee, S.

    2012-05-10

    Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. A three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.

  17. Comparison of FTIR and Particle Mass Spectrometry for the Measurement of Paticulate Organic Nitrates

    SciTech Connect (OSTI)

    Bruns, Emily; Perraud, Veronique; Zelenyuk, Alla; Ezell, Michael J.; Johnson, Stanley N.; Yu, Yong; Imre, D.; Finlayson-Pitts, Barbara J.; Alexander, M. L.

    2010-02-01

    While multifunctional organic nitrates are formed during the atmospheric oxidation of volatile organic compounds, relatively little is known about their signatures in particle mass spectrometers. High resolution time-of-flight aerosol mass spectrometry (HR-ToF-AMS) was applied to NH4NO3, NaNO3 and isosorbide 5-mononitrate (IMN) particles, and to secondary organic aerosol (SOA) from NO3 radical reactions at 22 C and 1 atm in air with and pinene, 3-carene, limonene and isoprene. For comparison, single particle laser ablation mass spectra (SPLAT II) were also obtained for IMN and SOA from the pinene reaction. The mass spectra of all particles exhibit significant intensity at m/z 30, and for the SOA, weak peaks corresponding to various organic fragments containing nitrogen [CxHyNzOa]+ were identified using HR-ToF-AMS. The NO+/NO2+ ratios from HR-ToF-AMS were 10-15 for IMN and the SOA from the and pinene, 3-carene and limonene reactions, ~5 for the isoprene reaction, 2.4 for NH4NO3 and 80 for NaNO3. The N/H ratios from HR-ToF-AMS for the SOA were smaller by a factor of 2 to 4 than the -ONO2/C-H ratios measured using FTIR on particles impacted on ZnSe windows. While the NO+/NO2+ ratio may provide a generic indication of organic nitrates under some conditions, specific identification of particulate organic nitrates awaits further development of particle mass spectrometry techniques.

  18. Role of Symmetry Breaking on the Optical Transitions in Lead-Salt Quantum Dots

    E-Print Network [OSTI]

    Van Stryland, Eric

    Role of Symmetry Breaking on the Optical Transitions in Lead-Salt Quantum Dots Gero Nootz to explain optical transitions in lead-salt QDs. Thus, while the band anisotropy of the bulk semiconductor functions. These studies clarify the controversy of the origin of spectral features in lead-salt QDs

  19. Flow, Sedimentation, and Biomass Production on a Vegetated Salt Marsh in South Carolina

    E-Print Network [OSTI]

    Mudd, Simon Marius

    . Introduction Vegetated salt marshes are a common feature along tectonically quiescent coastal mar- gins9 Flow, Sedimentation, and Biomass Production on a Vegetated Salt Marsh in South Carolina: Toward, sedimentation, and plant community evolution on a salt marsh populated by Spartina alterniflora is deve- loped

  20. Active salt tectonics in the Needles District, Canyonlands (Utah) as detected by interferometric

    E-Print Network [OSTI]

    Mueller, Karl

    Active salt tectonics in the Needles District, Canyonlands (Utah) as detected by interferometric. Mueller, and J. Wahr (2007), Active salt tectonics in the Needles District, Canyonlands (Utah) as detected, overlying a mobile layer of evaporites (the Paradox Formation) that originated mostly as salt deposited

  1. Ionic cloud distribution close to a charged surface in the presence of salt

    E-Print Network [OSTI]

    Podgornik, Rudolf

    OFFPRINT Ionic cloud distribution close to a charged surface in the presence of salt O. Punkkinen close to a charged surface in the presence of salt O. Punkkinen1,2(a) , A. Naji3 , R. Podgornik4,5,6 , I salts, etc. Abstract ­ Despite its importance, the understanding of ionic cloud distribution close

  2. Salt Lake Community College Articulations USU General Education Articulation 2012-2013

    E-Print Network [OSTI]

    Flann, Nicholas

    Salt Lake Community College Articulations USU General Education Articulation 2012-2013 General Education The following courses taken at Salt Lake Community College will meet USU General Education requirements. Below the names of the USU categories, the names of the Salt Lake Community College General

  3. Salt dissolution and sinkhole formation along the Dead Sea shore Eyal Shalev,1

    E-Print Network [OSTI]

    Lyakhovsky, Vladimir

    Salt dissolution and sinkhole formation along the Dead Sea shore Eyal Shalev,1 Vladimir Lyakhovsky cavities formed by salt dissolution. This dissolution is related to the recession of the Dead Sea by freshwater. Our finite element modeling shows that dissolution of this salt layer is a plausible mechanism

  4. RAY TRACING IN THE SMOOTHED ACOUSTIC SEG/EAGE SALT MODEL.

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    RAY TRACING IN THE SMOOTHED ACOUSTIC SEG/EAGE SALT MODEL. PART 1: SEISMOGRAMS V â?? ACLAV BUCHA­waves in the smoothed acoustic SEG/EAGE Salt Model are computed. The shot­receiver configuration is derived from that the smoothed SEG/EAGE Salt Model is suitable for two­point ray tracing. KEY WORDS Velocity model, ray tracing

  5. Global identification of miRNAs and targets in Populus euphratica under salt stress

    E-Print Network [OSTI]

    Deng, Xing-Wang

    Global identification of miRNAs and targets in Populus euphratica under salt stress Bosheng Li, a typical hydro-halophyte, is ideal for studying salt stress responses in woody plants. MicroRNAs (miRNA may regulate tolerance to salt stress but this has not been widely studied in P. euphratica

  6. Salt diapirs in the Dead Sea basin and their relationship to Quaternary extensional tectonics

    E-Print Network [OSTI]

    ten Brink, Uri S.

    Salt diapirs in the Dead Sea basin and their relationship to Quaternary extensional tectonics extension of a brittle overburden and underlying salt causes differential loading that is thought example of a large salt diapir in the Dead Sea pull-apart basin, the Lisan diapir, which we believe

  7. Zr-Hf separation based on a molten salt/metal

    E-Print Network [OSTI]

    Langendoen, Koen

    Zr-Hf separation based on a molten salt/metal equilibrium )URP ROGIDVKLRQHG Ã?DVKEXOEV to newfangled. These involve complicated multistep batch processes. This new purification method is based on molten salt to raw zirconium and hafnium metal, so a molten metal stream can be achieved and tin chloride salts

  8. Ray tracing computations in the smoothed SEG/EAGE Salt Model

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    Ray tracing computations in the smoothed SEG/EAGE Salt Model V#19;aclav Bucha Department to compute rays and synthetic seismograms of refracted and re ected P-waves in the smoothed SEG/EAGE Salt The original 3-D SEG/EAGE Salt Model (Aminzadeh et al. 1997) is very complex model and cannot be used for ray

  9. Sample Results from the Interim Salt Disposition Program Macrobatch 6 Tank 21H Qualification Samples

    SciTech Connect (OSTI)

    Peters, T. B.; Fink, S. D.

    2012-12-11

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 6 for the Interim Salt Disposition Project (ISDP). This document reports partial results of the analyses of samples of Tank 21H. No issues with the projected Salt Batch 6 strategy are identified.

  10. Doctoral Defense "Frost Deterioration in Concrete Due to Deicer Salt Exposure

    E-Print Network [OSTI]

    Kamat, Vineet R.

    Doctoral Defense "Frost Deterioration in Concrete Due to Deicer Salt Exposure: Mechanism-freeze climate zone. During winter a deicer-salt application is needed to melt snow on highways. Freezing in the presence of a deicer salt solution is considered a severe concrete exposure condition. Prolonged exposure

  11. FEATURE ARTICLE Unified Molecular Picture of the Surfaces of Aqueous Acid, Base, and Salt Solutions

    E-Print Network [OSTI]

    FEATURE ARTICLE Unified Molecular Picture of the Surfaces of Aqueous Acid, Base, and Salt Solutions inorganic ions. Molecular dynamics calculations show that in salt solutions and bases the positively charged, consequently, these acids (unlike bases and salts) reduce the surface tension of water. The results

  12. ENVIRONMENTAL MICROBIOLOGY Arcellacea (Testate Amoebae) as Bio-indicators of Road Salt

    E-Print Network [OSTI]

    Patterson, Timothy

    ENVIRONMENTAL MICROBIOLOGY Arcellacea (Testate Amoebae) as Bio-indicators of Road Salt in a significant reduction in road accidents. Deicing salts can, however, pose a major threat to water quality lakes that have become contaminated by winter deicing salts, particularly sodium chloride. We analysed

  13. A potential mechanism for disturbance-mediated channel migration in a southeastern United States salt marsh

    E-Print Network [OSTI]

    Lottig, Noah R.

    salt marsh Noah R. Lottig, Justin M. Fox University of Wisconsin-Madison Center for Limnology 680 North September 2006; accepted 8 September 2006 Available online 27 October 2006 Abstract Coastal salt marsh tidal Elsevier B.V. All rights reserved. Keywords: Wrack; Disturbance; Salt marsh tidal creek; Channel migration

  14. HORTSCIENCE 47(10):15041511. 2012. Sodium Distribution in Salt-stressed

    E-Print Network [OSTI]

    Burns, Jacqueline K.

    HORTSCIENCE 47(10):1504­1511. 2012. Sodium Distribution in Salt-stressed Citrus Rootstock Seedlings 33850 Additional index words. Na+ exclusion, Na+ transport, salinity tolerance, salt stress, vacuole sequestration Abstract. Although citrus trees are considered relatively salt-sensitive, there are consistent

  15. Molten salt as heat transfer fluid for a 500 m2 dish concentrator

    E-Print Network [OSTI]

    Molten salt as heat transfer fluid for a 500 m2 dish concentrator Nicolás del Pozo 1 , Rebecca Dunn salt based thermal storage system with the ANU SG4 500 m2 dish solar concentrator was performed. Specifically, the objective was to research the behaviour of molten salt as a heat transfer fluid for the SG4

  16. Salt removal using multiple microbial desalination cells under continuous flow conditions

    E-Print Network [OSTI]

    Salt removal using multiple microbial desalination cells under continuous flow conditions Youpeng that inhibit bacterial metabolism. The salt solution also moved through each desalination chamber in series. Increasing the hydraulic retention times (HRTs) of the salt so- lution from 1 to 2 days increased total Na

  17. Sheared salt fingers: Instability in a truncated system Francesco Paparella and Edward A. Spiegel

    E-Print Network [OSTI]

    Paparella, Francesco

    Sheared salt fingers: Instability in a truncated system Francesco Paparella and Edward A. Spiegel custom we shall call the more slowly diffusing property salt and the other temperature. In a particular called salt fingers. This configuration allows the fluid to take advantage of the diffusive effects

  18. Ray tracing in the smoothed acoustic SEG/EAGE Salt Model.

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    Ray tracing in the smoothed acoustic SEG/EAGE Salt Model. Part 2: Maps of re ections V#19;aclav of the P-wave re ected from the at bottom interface in the smoothed acoustic SEG/EAGE Salt Model. The illumination of the large shadow area below the trunk of the salt body is discussed. Keywords Velocity model

  19. Kinetics of Bile Salt Binding to Liposomes Revealed by Carboxyfluorescein Release and

    E-Print Network [OSTI]

    Hinow, Peter

    Kinetics of Bile Salt Binding to Liposomes Revealed by Carboxyfluorescein Release and Mathematical by the binding of different bile salts to the leaflets of the lipid bilayer. We find that the permeability of the liposomal bilayer depends on the difference in the concentrations of bile salt in the inner and outer

  20. Unusual Salt Stability in Highly Charged Diblock Co-polypeptide Hydrogels

    E-Print Network [OSTI]

    Breedveld, Victor

    Unusual Salt Stability in Highly Charged Diblock Co-polypeptide Hydrogels Andrew P. Nowak, Victor of poly(L-lysine HBr) or poly(L-glutamic acid sodium salt), and helical, hydrophobic segments of poly as low as 0.25 wt %, stability in salt or buffer solutions was found to be only achieved at moderately

  1. Zeolite Salt Occlusion: A Potential Route for the Immobilisation of Iodine-129? Neil C. Hyatt,1*

    E-Print Network [OSTI]

    Sheffield, University of

    Zeolite ­ Salt Occlusion: A Potential Route for the Immobilisation of Iodine-129? Neil C. Hyatt,1 examined as possible starting routes to the long term immobilisation of iodine-129. Heating the salts, where the iodide salt migrates into the zeolite pores. Detailed studies of the Na-A / 5AgI complex

  2. Hydrotropic salt promotes anionic surfactant self-assembly into vesicles and ultralong fibers

    E-Print Network [OSTI]

    Huang, Jianbin

    Hydrotropic salt promotes anionic surfactant self-assembly into vesicles and ultralong fibers November 2011 Available online 6 December 2011 Keywords: Surfactant self-assembly Hydrotropic salt Fiber dodecylbenzene sulfo- nate, SDBS) and a hydrotropic salt (benzylamine hydrochloride, BzCl) in aqueous solution

  3. Enhancement of charged macromolecule capture by nanopores in a salt gradient

    E-Print Network [OSTI]

    Levine, Alex J.

    Enhancement of charged macromolecule capture by nanopores in a salt gradient Tom Choua Department. However, recent experiments have shown that salt concentration gradients applied across nanopores can also length, we obtain accurate analytic expressions showing how salt gradients control the local conductivity

  4. Water Dynamics in Salt Solutions Studied with Ultrafast Two-Dimensional Infrared (2D IR)

    E-Print Network [OSTI]

    Fayer, Michael D.

    Water Dynamics in Salt Solutions Studied with Ultrafast Two-Dimensional Infrared (2D IR. Many of these species are charged. In the ocean, water interacts with dissolved salts. In biological systems, water interacts with dissolved salts as well as charged amino acids, the zwitterionic head groups

  5. Hydrogen Generation in Microbial Reverse-Electrodialysis Electrolysis Cells Using a Heat-Regenerated Salt Solution

    E-Print Network [OSTI]

    -Regenerated Salt Solution Joo-Youn Nam, Roland D. Cusick, Younggy Kim, and Bruce E. Logan* Department of Civil-gradient energy such as river water and seawater solutions. Here, it is shown that ammonium bicarbonate salts be successfully operated using ammonium bicarbonate salts that can be regenerated using conventional distillation

  6. Salt-and-Pepper Noise Removal by Median-type Noise Detectors and

    E-Print Network [OSTI]

    Chan, Raymond

    1 Salt-and-Pepper Noise Removal by Median-type Noise Detectors and Detail-preserving Regularization for removing salt-and-pepper impulse noise. In the first phase, an adaptive median filter is used to identify remove salt-and-pepper-noise with noise level as high as 90%. Index Terms Impulse noise, adaptive median

  7. Salt Effect on Microstructures in Cationic Gemini Surfactant Solutions as Studied by Dynamic Light Scattering

    E-Print Network [OSTI]

    Huang, Jianbin

    Salt Effect on Microstructures in Cationic Gemini Surfactant Solutions as Studied by Dynamic Light, C12C12C12(Et) underwent a typical "ordinary-to-extraordinary (o-e) transition" with decreasing salt concentration to zero. At higher salt concentration, a single relaxation mode, corresponding to the diffusion

  8. Salt-stabilized globular protein structure in 7 M aqueous urea solution

    E-Print Network [OSTI]

    Wider, Gerhard

    1 Salt-stabilized globular protein structure in 7 M aqueous urea solution V. Dötsch,1 G. Wider, G Hochschule- Hönggerberg, CH-8093 Zürich, Switzerland Keywords Protein folding; Urea denaturation; Salt changing the solution conditions. In this paper we describe the influence of various salts or non

  9. Salt Sensitivity and the Activities of the H+ -ATPases in Cotton Seedlings

    E-Print Network [OSTI]

    Schumaker, Karen

    Salt Sensitivity and the Activities of the H+ -ATPases in Cotton Seedlings Howard Lin, Sandra S environ- ments. Sensitivityto high levels of salt in plants is associated with an inability to effectively+ -pumping ATPases may provide the driving force for Na+ transport via Na+ -H+ exchangers. In a salt

  10. Molten salt synthesis of potassium-containing hydroxyapatite microparticles used as protein substrate

    E-Print Network [OSTI]

    Tas, A. Cuneyt

    Molten salt synthesis of potassium-containing hydroxyapatite microparticles used as protein Molten salt synthesis Bovine serum albumin Adsorption a b s t r a c t The bioactivity of a material may-containing calcium phosphate bioceramic microparticles were manufac- tured by molten salt synthesis. The effects

  11. Salt stress response in rice: genetics, molecular biology, and comparative genomics

    E-Print Network [OSTI]

    Blumwald, Eduardo

    REVIEW Salt stress response in rice: genetics, molecular biology, and comparative genomics Chandan. Evidence show that salt tolerance in plants is a quantitative trait. Several traditional cultivars materials for donation of requisite salt tolerance genes. A large number of quantitative trait loci (QTL

  12. Sample Results From The Interim Salt Disposition Program Macrobatch 6 Tank 21H Qualification Samples

    SciTech Connect (OSTI)

    Peters, T. B.; Fink, S. D.

    2012-12-20

    Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 6 for the Interim Salt Disposition Project (ISDP). This document reports partial results of the analyses of samples of Tank 21H. No issues with the projected Salt Batch 6 strategy are identified.

  13. Salt Accumulation in the Loessial Sequence in the Be'er Sheva Basin, Israel

    E-Print Network [OSTI]

    Gvirtzman, Haim

    Salt Accumulation in the Loessial Sequence in the Be'er Sheva Basin, Israel MORDECKAIMAGARr / Evidence of climatic changes is recorded in the salt content of the surface sediments in arid zones, In wetter periods airborne salts are removed downward by leaching to the groundwater, whereas in drier

  14. SALT: An XML Application for Web-based Multimodal Dialog Kuansan Wang

    E-Print Network [OSTI]

    SALT: An XML Application for Web-based Multimodal Dialog Management Kuansan Wang Speech Technology://research.microsoft.com/stg Abstract This paper describes the Speech Application Language Tags, or SALT, an XML based spoken dialog standard for multimodal or speech-only applications. A key premise in SALT design is that speech

  15. RAY TRACING IN THE SMOOTHED ACOUSTIC SEG/EAGE SALT MODEL.

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    RAY TRACING IN THE SMOOTHED ACOUSTIC SEG/EAGE SALT MODEL. PART 2: MAPS OF REFLECTIONS V â?? ACLAV­wave reflected from the flat bottom interface in the smoothed acoustic SEG/EAGE Salt Model are calculated of the large shadow area below the trunk of the salt body is discussed. KEY WORDS Velocity model, ray tracing

  16. Salt Dependence of Ion Transport and DNA Translocation through Solid-State

    E-Print Network [OSTI]

    Dekker, Nynke

    Salt Dependence of Ion Transport and DNA Translocation through Solid-State Nanopores Ralph M. M of the salt dependence of ion transport and DNA translocation through solid-state nanopores. The ionic conductance shows a three-order-of-magnitude decrease with decreasing salt concentrations from 1 M to 1 µ

  17. Bases, Assumptions, and Results of the Flowsheet Calculations for the Decision Phase Salt Disposition Alternatives

    SciTech Connect (OSTI)

    Elder, H.H.

    2001-07-11

    The HLW salt waste (salt cake and supernate) now stored at the SRS must be treated to remove insoluble sludge solids and reduce the soluble concentration of radioactive cesium radioactive strontium and transuranic contaminants (principally Pu and Np). These treatments will enable the salt solution to be processed for disposal as saltstone, a solid low-level waste.

  18. Brine Rejection from Freezing Salt Solutions: A Molecular Dynamics Study Lubos Vrbka and Pavel Jungwirth*

    E-Print Network [OSTI]

    Zhigilei, Leonid V.

    Brine Rejection from Freezing Salt Solutions: A Molecular Dynamics Study Lubos Vrbka and Pavel process of brine rejection from freezing salt solutions is investigated with atomic resolution using. The presence of salt slows down the freezing process, which leads to the formation of an almost neat ice next

  19. Role of the Salt-bridge between Switch-1 and Switch-2 of Dictyostelium Myosin

    E-Print Network [OSTI]

    Manstein, Dietmar J.

    Role of the Salt-bridge between Switch-1 and Switch-2 of Dictyostelium Myosin Marcus Furch1-phosphate. The closed form seems to be necessary for hydrolysis and is stabilised by the formation of a salt-bridge between an arginine residue in N2 and a glutamate residue in N3. We examined the role of this salt-bridge

  20. Standard test method for isotopic analysis of hydrolyzed uranium hexafluoride and uranyl nitrate solutions by thermal ionization mass spectrometry

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2005-01-01

    1.1 This method applies to the determination of isotopic composition in hydrolyzed nuclear grade uranium hexafluoride. It covers isotopic abundance of 235U between 0.1 and 5.0 % mass fraction, abundance of 234U between 0.0055 and 0.05 % mass fraction, and abundance of 236U between 0.0003 and 0.5 % mass fraction. This test method may be applicable to other isotopic abundance providing that corresponding standards are available. 1.2 This test method can apply to uranyl nitrate solutions. This can be achieved either by transforming the uranyl nitrate solution to a uranyl fluoride solution prior to the deposition on the filaments or directly by depositing the uranyl nitrate solution on the filaments. In the latter case, a calibration with uranyl nitrate standards must be performed. 1.3 This test method can also apply to other nuclear grade matrices (for example, uranium oxides) by providing a chemical transformation to uranyl fluoride or uranyl nitrate solution. 1.4 This standard does not purport to address al...