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Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
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1

SunShot Initiative: Modular and Scalable Baseload Molten Salt Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

Modular and Scalable Baseload Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility to someone by E-mail Share SunShot Initiative: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility on Facebook Tweet about SunShot Initiative: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility on Twitter Bookmark SunShot Initiative: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility on Google Bookmark SunShot Initiative: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility on Delicious Rank SunShot Initiative: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility on Digg Find More places to share SunShot Initiative: Modular and Scalable

2

SunShot Initiative: Advanced Nitrate Salt Central Receiver Power Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Nitrate Salt Central Receiver Power Plant Advanced Nitrate Salt Central Receiver Power Plant Abengoa logo Photo of two lit towers surrounded by much smaller blue flat plates that are mounted on the ground. Commercial central receiver plant designs Abengoa, under the Baseload CSP FOA, will demonstrate a 100-megawatt electrical (MWe) central receiver plant using nitrate salt as the receiver coolant, thermal storage medium, and heat transport fluid in the steam generator. Approach The plan is to operate the plant at full load for 6,400 hours each year using only solar energy. Abengoa is working to create a team of suppliers capable of deploying a commercially ready nitrate salt central receiver technology that can be competitive in the current power marketplace. Innovation Abengoa is developing a new molten-salt power tower technology with a surround heliostat field. Key components include:

3

SunShot Initiative: Baseload Concentrating Solar Power Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

Concentrating Solar Power Generation Concentrating Solar Power Generation In 2010, DOE issued the Baseload Concentrating Solar Power (CSP) Generation funding opportunity announcement (FOA). The following projects were selected under this competitive solicitation: Abengoa: Advanced Nitrate Salt Central Receiver Power Plant eSolar: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility General Atomics: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage HiTek: Low-Cost Heliostat Development Infinia: Innovative Phase Change Thermal Energy Storage Solution for Baseload Power PPG: Next-Generation Low-Cost Reflector Rocketdyne: Solar Power Tower Improvements with the Potential to Reduce Costs SENER: High-Efficiency Thermal Storage System for Solar Plants

4

Molten nitrate salt technology development status report  

SciTech Connect

Recognizing thermal energy storage as potentially critical to the successful commercialization of solar thermal power systems, the Department of Energy (DOE) has established a comprehensive and aggressive thermal energy storage technology development program. Of the fluids proposed for heat transfer and energy storage molten nitrate salts offer significant economic advantages. The nitrate salt of most interest is a binary mixture of NaNO/sub 3/ and KNO/sub 3/. Although nitrate/nitrite mixtures have been used for decades as heat transfer and heat treatment fluids the use has been at temperatures of about 450/sup 0/C and lower. In solar thermal power systems the salts will experience a temperature range of 350 to 600/sup 0/C. Because central receiver applications place more rigorous demands and higher temperatures on nitrate salts a comprehensive experimental program has been developed to examine what effects, if any, the new demands and temperatures have on the salts. The experiments include corrosion testing, environmental cracking of containment materials, and determinations of physical properties and decomposition mechanisms. This report details the work done at Sandia National Laboratories in each area listed. In addition, summaries of the experimental programs at Oak Ridge National Laboratory, the University of New York, EIC Laboratories, Inc., and the Norwegian Institute of Technology on molten nitrate salts are given. Also discussed is how the experimental programs will influence the near-term central receiver programs such as utility repowering/industrial retrofit and cogeneration. The report is designed to provide easy access to the latest information and data on molten NaNO/sub 3//KNO/sub 3/ for the designers and engineers of future central receiver projects.

Carling, R.W.; Kramer, C.M.; Bradshaw, R.W.; Nissen, D.A.; Goods, S.H.; Mar, R.W.; Munford, J.W.; Karnowsky, M.M.; Biefeld, R.N.; Norem, N.J.

1981-03-01T23:59:59.000Z

5

SunShot Initiative: Advanced Nitrate Salt Central Receiver Power...  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Nitrate Salt Central Receiver Power Plant to someone by E-mail Share SunShot Initiative: Advanced Nitrate Salt Central Receiver Power Plant on Facebook Tweet about SunShot...

6

Corrosion of aluminides by molten nitrate salt  

DOE Green Energy (OSTI)

The corrosion of titanium-, iron-, and nickel-based aluminides by a highly aggressive, oxidizing NaNO{sub 3}(-KNO{sub 3})-Na{sub 2}O{sub 2} has been studied at 650{degree}C. It was shown that weight changes could be used to effectively evaluate corrosion behavior in the subject nitrate salt environments provided these data were combined with salt analyses and microstructural examinations. The studies indicated that the corrosion of relatively resistant aluminides by these nitrate salts proceeded by oxidation and a slow release from an aluminum-rich product layer into the salt at rates lower than that associated with many other types of metallic materials. The overall corrosion process and resulting rate depended on the particular aluminide being exposed. In order to minimize corrosion of nickel or iron aluminides, it was necessary to have aluminum concentrations in excess of 30 at. %. However, even at a concentration of 50 at. % Al, the corrosion resistance of TiAl was inferior to that of Ni{sub 3}Al and Fe{sub 3}Al. At higher aluminum concentrations, iron, nickel, and iron-nickel aluminides exhibited quite similar weight changes, indicative of the principal role of aluminum in controlling the corrosion process in NaNO{sub 3}(-KNO{sub 3})-Na{sub 2}O{sub 2} salts. 20 refs., 5 figs., 3 tabs.

Tortorelli, P.F.; Bishop, P.S.

1990-01-01T23:59:59.000Z

7

New baseload power plants  

Science Conference Proceedings (OSTI)

This is a listing of 221 baseload power plant units currently in the planning stage. The list shows the plant owner, capacity, fuel, engineering firm, constructor, major equipment suppliers (steam generator, turbogenerator, and flue gas desulfurization system), partner, and date the plant is to be online. This data is a result of a survey by the journal of power plant owners.

Not Available

1994-04-01T23:59:59.000Z

8

Industrial use of molten nitrate/nitrite salts  

DOE Green Energy (OSTI)

Nitrate salts have been used for years as a high-temperature heat transfer medium in the chemical and metal industries. This experience is often cited as an argument for the use of these salts in large-scale solar energy systems. However, this industrial experience has not been well documented and a study was carried out to provide such information to the solar community and to determine the applicability of this data base. Seven different industrial plants were visited and the plant operators were interviewed with regard to operating history and experience. In all cases the molten salt systems operate without problems. However, it is not possible to apply the base of industrial experience directly to solar thermal energy applications because of differences in operating temperature, salt composition, alloys used, and thermal/mechanical conditions.

Carling, R.W.; Mar, R.W.

1981-12-01T23:59:59.000Z

9

New baseload power plants  

Science Conference Proceedings (OSTI)

This is a tabulation of the results of this magazines survey of current plans for new baseload power plants. The table lists the unit name, capacity, fuel, engineering firm, constructor, suppliers for steam generator, turbine generator and flue gas desulfurization equipment, date due on-line, and any non-utility participants. The table includes fossil-fuel plants, nuclear plants, geothermal, biomass and hydroelectric plants.

Not Available

1993-04-01T23:59:59.000Z

10

Low-melting point inorganic nitrate salt heat transfer fluid  

DOE Patents (OSTI)

A low-melting point, heat transfer fluid made of a mixture of four inorganic nitrate salts: 9-18 wt % NaNO.sub.3, 40-52 wt % KNO.sub.3, 13-21 wt % LiNO.sub.3, and 20-27 wt % Ca(NO.sub.3).sub.2. These compositions can have liquidus temperatures less than 100 C; thermal stability limits greater than 500 C; and viscosity in the range of 5-6 cP at 300 C; and 2-3 cP at 400 C.

Bradshaw, Robert W. (Livermore, CA); Brosseau, Douglas A. (Albuquerque, NM)

2009-09-15T23:59:59.000Z

11

Utilities expand baseload power plant plans  

Science Conference Proceedings (OSTI)

This article examines the plans being made by electric utilities to expand the number of baseload plants to accommodate increasing power demands. The results of a survey of utility's construction plans is presented. The topics include current construction, construction planning in the Southeast, current baseload technology, nuclear potential, and incorporation of environmental externalities impact in planning.

Smock, R.

1993-04-01T23:59:59.000Z

12

SunShot Initiative: CSP Heat Integration for Baseload Renewable...  

NLE Websites -- All DOE Office Websites (Extended Search)

CSP Heat Integration for Baseload Renewable Energy Deployment to someone by E-mail Share SunShot Initiative: CSP Heat Integration for Baseload Renewable Energy Deployment on...

13

SunShot Initiative: Innovative Thermal Energy Storage for Baseload...  

NLE Websites -- All DOE Office Websites (Extended Search)

Innovative Thermal Energy Storage for Baseload Solar Power Generation to someone by E-mail Share SunShot Initiative: Innovative Thermal Energy Storage for Baseload Solar Power...

14

Equipment evaluation for low density polyethylene encapsulated nitrate salt waste at the Rocky Flats Plant  

SciTech Connect

Mixed wastes at the Rocky Flats Plant (RFP) are subject to regulation by the Resource Conservation and Recovery Act (RCRA). Polymer solidification is being developed as a final treatment technology for several of these mixed wastes, including nitrate salts. Encapsulation nitrate salts with low density polyethylene (LDPE) has been the preliminary focus of the RFP polymer solidification effort. Literature reviews, industry surveys, and lab-scale and pilot-scale tests have been conducted to evaluate several options for encapsulating nitrate salts with LDPE. Most of the effort has focused on identifying compatible drying and extrusion technologies. Other processing options, specifically meltration and non-heated compounding machines, were also investigated. The best approach appears to be pretreatment of the nitrate salt waste brine in either a vertical or horizontal thin film evaporator followed by compounding of the dried waste with LDPE in an intermeshing, co-rotating, twin-screw extruder. Additional pilot-scale tests planned for the fall of 1993 should further support this recommendation. Preliminary evaluation work indicates that meltration is not possible at atmospheric pressure with the LDPE (Chevron PE-1409) provided by RFP. However, meltration should be possible at atmospheric pressure using another LDPE formulation with altered physical and rheological properties: Lower molecular weight and lower viscosity (Epoline C-15). Contract modifications are now in process to allow a follow-on pilot scale demonstration. Questions regarding changed safety and physical properties of the resultant LDPE waste form due to use of the Epoline C-15 will be addressed. No additional work with non-heated mixer compounder machines is planned at this time.

Yamada, W.I.; Faucette, A.M.; Jantzen, R.C.; Logsdon, B.W.; Oldham, J.H.; Saiki, D.M.; Yudnich, R.J.

1993-08-30T23:59:59.000Z

15

SunShot Initiative: Brayton Cycle Baseload Power Tower  

NLE Websites -- All DOE Office Websites (Extended Search)

Brayton Cycle Baseload Power Brayton Cycle Baseload Power Tower to someone by E-mail Share SunShot Initiative: Brayton Cycle Baseload Power Tower on Facebook Tweet about SunShot Initiative: Brayton Cycle Baseload Power Tower on Twitter Bookmark SunShot Initiative: Brayton Cycle Baseload Power Tower on Google Bookmark SunShot Initiative: Brayton Cycle Baseload Power Tower on Delicious Rank SunShot Initiative: Brayton Cycle Baseload Power Tower on Digg Find More places to share SunShot Initiative: Brayton Cycle Baseload Power Tower on AddThis.com... Concentrating Solar Power Systems Components Competitive Awards CSP Research & Development Thermal Storage CSP Recovery Act Baseload CSP SunShot Multidisciplinary University Research Initiative CSP Heat Integration for Baseload Renewable Energy Deployment

16

Laboratory scale vitrification of low-level radioactive nitrate salts and soils from the Idaho National Engineering Laboratory  

SciTech Connect

INEL has radiologically contaminated nitrate salt and soil waste stored above and below ground in Pad A and the Acid Pit at the Radioactive Waste Management Complex. Pad A contain uranium and transuranic contaminated potassium and sodium nitrate salts generated from dewatered waste solutions at the Rocky Flats Plant. The Acid Pit was used to dispose of liquids containing waste mineral acids, uranium, nitrate, chlorinated solvents, and some mercury. Ex situ vitrification is a high temperature destruction of nitrates and organics and immobilizes hazardous and radioactive metals. Laboratory scale melting of actual radionuclides containing INEL Pad A nitrate salts and Acid Pit soils was performed. The salt/soil/additive ratios were varied to determine the range of glass compositions (resulted from melting different wastes); maximize mass and volume reduction, durability, and immobilization of hazardous and radioactive metals; and minimize viscosity and offgas generation for wastes prevalent at INEL and other DOE sites. Some mixtures were spiked with additional hazardous and radioactive metals. Representative glasses were leach tested and showed none. Samples spiked with transuranic showed low nuclide leaching. Wasteforms were two to three times bulk densities of the salt and soil. Thermally co-processing soils and salts is an effective remediation method for destroying nitrate salts while stabilizing the radiological and hazardous metals they contain. The measured durability of these low-level waste glasses approached those of high-level waste glasses. Lab scale vitrification of actual INEL contaminated salts and soils was performed at General Atomics Laboratory as part of the INEL Waste Technology Development and Environmental Restoration within the Buried Waste Integrated Demonstration Program.

Shaw, P. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Anderson, B. [General Atomics, San Diego, CA (United States). NRT Div.; Davis, D. [Envitco Inc., Toledo, OH (United States)

1993-07-01T23:59:59.000Z

17

SunShot Initiative: Baseload Concentrating Solar Power Generation  

NLE Websites -- All DOE Office Websites (Extended Search)

Concentrating Solar Concentrating Solar Power Generation to someone by E-mail Share SunShot Initiative: Baseload Concentrating Solar Power Generation on Facebook Tweet about SunShot Initiative: Baseload Concentrating Solar Power Generation on Twitter Bookmark SunShot Initiative: Baseload Concentrating Solar Power Generation on Google Bookmark SunShot Initiative: Baseload Concentrating Solar Power Generation on Delicious Rank SunShot Initiative: Baseload Concentrating Solar Power Generation on Digg Find More places to share SunShot Initiative: Baseload Concentrating Solar Power Generation on AddThis.com... Concentrating Solar Power Systems Components Competitive Awards CSP Research & Development Thermal Storage CSP Recovery Act Baseload CSP SunShot Multidisciplinary University Research Initiative

18

Investigation of cold filling receiver panels and piping in molten-nitrate-salt central-receiver solar power plants  

DOE Green Energy (OSTI)

Cold filling refers to flowing a fluid through piping or tubes that are at temperatures below the fluid`s freezing point. Since the piping and areas of the receiver in a molten-nitrate salt central-receiver solar power plant must be electrically heated to maintain their temperatures above the nitrate salt freezing point (430{degrees}F, 221{degrees}C), considerable energy could be used to maintain such temperatures during nightly shut down and bad weather. Experiments and analyses have been conducted to investigate cold filling receiver panels and piping as a way of reducing parasitic electrical power consumption and increasing the availability of the plant. The two major concerns with cold filling are: (1) how far can the molten salt penetrate cold piping before freezing closed and (2) what thermal stresses develop during the associated thermal shock. Cold fill experiments were conducted by flowing molten salt at 550{degrees}F (288{degrees}C) through cold panels, manifolds, and piping to determine the feasibility of cold filling the receiver and piping. The transient thermal responses were measured and heat transfer coefficients were calculated from the data. Nondimensional analysis is presented which quantifies the thermal stresses in a pipe or tube undergoing thermal shock. In addition, penetration distances were calculated to determine the distance salt could flow in cold pipes prior to freezing closed.

Pacheco, J.E.; Ralph, M.E.; Chavez, J.M.

1994-12-31T23:59:59.000Z

19

Flexible Coal: Evolution from Baseload to Peaking Plant (Brochure...  

NLE Websites -- All DOE Office Websites (Extended Search)

the transformation of power systems Flexible Coal Evolution from Baseload to Peaking Plant The experience cited in this paper is from a generating station with multiple units...

20

LPG-recovery processes for baseload LNG plants examined  

SciTech Connect

With demand on the rise, LPG produced from a baseload LNG plant becomes more attractive as a revenue-earning product similar to LNG. Efficient use of gas expanders in baseload LNG plants for LPG production therefore becomes more important. Several process variations for LPG recovery in baseload LNG plants are reviewed here. Exergy analysis (based on the Second Law of Thermodynamics) is applied to three cases to compare energy efficiency resulting from integration with the main liquefaction process. The paper discusses extraction in a baseload plant, extraction requirements, process recovery parameters, extraction process variations, and exergy analysis.

Chiu, C.H. [Bechtel Corp., Houston, TX (United States)

1997-11-24T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Investment Decisions for Baseload Power Plants  

NLE Websites -- All DOE Office Websites (Extended Search)

Investment Decisions for Investment Decisions for Baseload Power Plants January 29, 2010 402/012910 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United

22

Temperature-dependent mechanical property testing of nitrate thermal storage salts.  

DOE Green Energy (OSTI)

Three salt compositions for potential use in trough-based solar collectors were tested to determine their mechanical properties as a function of temperature. The mechanical properties determined were unconfined compressive strength, Young's modulus, Poisson's ratio, and indirect tensile strength. Seventeen uniaxial compression and indirect tension tests were completed. It was found that as test temperature increases, unconfined compressive strength and Young's modulus decreased for all salt types. Empirical relationships were developed quantifying the aforementioned behaviors. Poisson's ratio tends to increase with increasing temperature except for one salt type where there is no obvious trend. The variability in measured indirect tensile strength is large, but not atypical for this index test. The average tensile strength for all salt types tested is substantially higher than the upper range of tensile strengths for naturally occurring rock salts. Interest in raising the operating temperature of concentrating solar technologies and the incorporation of thermal storage has motivated studies on the implementation of molten salt as the system working fluid. Recently, salt has been considered for use in trough-based solar collectors and has been shown to offer a reduction in levelized cost of energy as well as increasing availability (Kearney et al., 2003). Concerns regarding the use of molten salt are often related to issues with salt solidification and recovery from freeze events. Differences among salts used for convective heat transfer and storage are typically designated by a comparison of thermal properties. However, the potential for a freeze event necessitates an understanding of salt mechanical properties in order to characterize and mitigate possible detrimental effects. This includes stress imparted by the expanding salt. Samples of solar salt, HITEC salt (Coastal Chemical Co.), and a low melting point quaternary salt were cast for characterization tests to determine unconfined compressive strength, indirect tensile strength, coefficient of thermal expansion (CTE), Young's modulus, and Poisson's ratio. Experiments were conducted at multiple temperatures below the melting point to determine temperature dependence.

Everett, Randy L.; Iverson, Brian D.; Broome, Scott Thomas; Siegel, Nathan Phillip; Bronowski, David R.

2010-09-01T23:59:59.000Z

23

Effect of chloride content of molten nitrate salt on corrosion of A516 carbon steel.  

SciTech Connect

The corrosion behavior of A516 carbon steel was evaluated to determine the effect of the dissolved chloride content in molten binary Solar Salt. Corrosion tests were conducted in a molten salt consisting of a 60-40 weight ratio of NaNO{sub 3} and KNO{sub 3} at 400{sup o}C and 450{sup o}C for up to 800 hours. Chloride concentrations of 0, 0.5 and 1.0 wt.% were investigated to determine the effect on corrosion of this impurity, which can be present in comparable amounts in commercial grades of the constituent salts. Corrosion rates were determined by descaled weight losses, corrosion morphology was examined by metallographic sectioning, and the types of corrosion products were determined by x-ray diffraction. Corrosion proceeded by uniform surface scaling and no pitting or intergranular corrosion was observed. Corrosion rates increased significantly as the concentration of dissolved chloride in the molten salt increased. The adherence of surface scales, and thus their protective properties, was degraded by dissolved chloride, fostering more rapid corrosion. Magnetite was the only corrosion product formed on the carbon steel specimens, regardless of chloride content or temperature.

Bradshaw, Robert W.; Clift, W. Miles

2010-11-01T23:59:59.000Z

24

Emissions and Energy Efficiency Assessment of Baseload Wind  

E-Print Network (OSTI)

. Many technologies exist that are capable of storing electrical energy, including pumped hydro storage). A wind energy system using a pure storage system such as pumped hydro would require a greater peak powerEmissions and Energy Efficiency Assessment of Baseload Wind Energy Systems P A U L D E N H O L M

Sheridan, Jennifer

25

Salt  

NLE Websites -- All DOE Office Websites (Extended Search)

Salt Salt Nature Bulletin No. 340-A April 12, 1969 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation SALT It is fortunate that Salt -- common salt, known to chemists as sodium chloride and to mineralogists as Halite -- is one of the most abundant substances on earth, because most of us crave it and must have it. Eskimos get along without salt because they live mostly on the uncooked flesh of fish and mammals. A few nomad tribes never eat it and do not need it because their diet contains so much milk cheese, and meat eaten raw or roasted. We people who eat boiled meat and many vegetables must have salt. Of the millions of tons produced commercially each year, only about three percent is used as table salt. Large quantities are required for refrigeration meat packing, curing and preserving fish, pickles, sauerkraut, and for other foods prepared in brine. A lot of it is needed for livestock. Salt is spread on sidewalks, streets and highways to melt ice in winter. It is used to glaze pottery, sewer pipe and other ceramics. It is required in many metallurgical processes, chemical industries, and the manufacture of such products as leather, glass, soap, bleaching powder and photographic supplies. It has about 14,000 uses.

26

SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based  

NLE Websites -- All DOE Office Websites (Extended Search)

CSP Generation CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage to someone by E-mail Share SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Facebook Tweet about SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Twitter Bookmark SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Google Bookmark SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Delicious Rank SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on Digg Find More places to share SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage on

27

Ferrocyanide Safety Project Dynamic X-Ray Diffraction studies of sodium nickel ferrocyanide reactions with equimolar nitrate/nitrite salts  

Science Conference Proceedings (OSTI)

Dynamic X-ray Diffraction (DXRD) has been to used to identify and quantify the solid state reactions that take place between sodium nickel ferrocyanide, Na{sub 2}NiFe(CN){sub 6}, and equimolar concentrations of sodium nitrate/nitrite, reactions of interest to the continued environmental safety of several large underground waste storage tanks at the Hanford site in eastern Washington. The results are supportive of previous work, which indicated that endothermic dehydration and melting of the nitrates take place before the occurrence of exothermic reactions that being about 300{degrees}C. The DXRD results show that a major reaction set at these temperatures is the occurrence of a series reaction that produces sodium cyanate, NaCNO, as an intermediate in a mildly exothermic first step. In the presence of gaseous oxygen, NaCNO subsequently reacts exothermally and at a faster rate to form metal oxides. Measurements of the rate of this reaction are used to estimate the heat release. Comparisons of this estimated heat release rate with heat transfer rates from a hypothetical ``hot spot`` show that, even in a worst-case scenario, the heat transfer rates are approximately eight times higher than the rate of energy release from the exothermic reactions.

Dodds, J.N. [Washington State Univ., Pullman, WA (United States). Dept. of Chemical Engineering]|[UNOCAL, Brea, CA (United States). Hartley Research Center

1994-07-01T23:59:59.000Z

28

Flexible Coal: Evolution from Baseload to Peaking Plant (Brochure)  

Science Conference Proceedings (OSTI)

Twenty-first century power systems, with higher penetration levels of low-carbon energy, smart grids, and other emerging technologies, will favor resources that have low marginal costs and provide system flexibility (e.g., the ability to cycle on and off to follow changes in variable renewable energy plant output). Questions remain about both the fate of coal plants in this scenario and whether they can cost-effectively continue to operate if they cycle routinely. The experience from the CGS plant demonstrates that coal plants can become flexible resources. This flexibility - namely the ability to cycle on and off and run at lower output (below 40% of capacity) - requires limited hardware modifications but extensive modifications to operational practice. Cycling does damage the plant and impact its life expectancy compared to baseload operations. Nevertheless, strategic modifications, proactive inspections and training programs, among other operational changes to accommodate cycling, can minimize the extent of damage and optimize the cost of maintenance. CGS's cycling, but not necessarily the associated price tag, is replicable. Context - namely, power market opportunities and composition of the generation fleet - will help determine for other coal plants the optimal balance between the level of cycling-related forced outages and the level of capital investment required to minimize those outages. Replicating CGS's experience elsewhere will likely require a higher acceptance of forced outages than regulators and plant operators are accustomed to; however, an increase in strategic maintenance can minimize the impact on outage rates.

Cochran, J.; Lew, D.; Kumar, N.

2013-12-01T23:59:59.000Z

29

Supplying Baseload Power and Reducing Transmission Requirements by Interconnecting Wind Farms  

Science Conference Proceedings (OSTI)

Wind is the world’s fastest growing electric energy source. Because it is intermittent, though, wind is not used to supply baseload electric power today. Interconnecting wind farms through the transmission grid is a simple and effective way of ...

Cristina L. Archer; Mark Z. Jacobson

2007-11-01T23:59:59.000Z

30

SunShot Initiative: Baseload CSP Generation Integrated with Sulfur-Based  

NLE Websites -- All DOE Office Websites (Extended Search)

CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage General Atomics logo Graphic of a diagram of squares and circles connected by arrows. Sulfur-based TES can compensate for diurnal and seasonal insolation fluctuations. General Atomics, under the Baseload CSP FOA, is demonstrating the engineering feasibility of using a sulfur-based thermochemical cycle to store heat from a CSP plant and support baseload power generation. Approach There are three main project objectives under this award: Study the sulfur generating disproportionation reaction and develop it into a practical engineering process step. Carry out preliminary process components design and experimental validation. The engineering data will be used for process integration between the CSP plant, the sulfur processing and storage plant, and the electricity generation unit.

31

Calcium nitrate explosive composition  

SciTech Connect

A blasting agent is composed of about 40% by wt of a mixture of calcium nitrate, water, a second inorganic oxidizing salt, and a water miscible organic fuel. These 4 components are provided in proportions to each other so as to provide an effective blasting agent. Optionally, up to 60% of additives well known in the explosives art, e.g., organic and inorganic fuels, sensitizers, density control agents, thickeners and gelling agents, inorganic nitrate based explosive compositions, can be incorporated into the blasting agent to provide certain desired characteristics. (42 claims)

Clark, W.F.; Slykhouse, T.E.

1974-10-01T23:59:59.000Z

32

CX-003201: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9 Date: 08042010 Location(s): Colorado Office(s): Energy...

33

Categorical Exclusion Determinations: Golden Field Office | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-003201: Categorical Exclusion Determination Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9 Date: 08042010 Location(s): Colorado Office(s):...

34

SunShot Initiative: Power Tower  

NLE Websites -- All DOE Office Websites (Extended Search)

Polymeric Mirrors (CSP R&D FOA) Abengoa Solar: Advanced Nitrate Salt Central Receiver Power Plant (Baseload CSP FOA) Abengoa Solar: Reducing the Cost of Thermal Energy Storage...

35

Ammonium nitrate explosive systems  

SciTech Connect

Novel explosives which comprise mixtures of ammonium nitrate and an ammonium salt of a nitroazole in desired ratios are disclosed. A preferred nitroazole is 3,5-dinitro-1,2,4-triazole. The explosive and physical properties of these explosives may readily be varied by the addition of other explosives and oxidizers. Certain of these mixtures have been found to act as ideal explosives.

Stinecipher, Mary M. (Los Alamos, NM); Coburn, Michael D. (Los Alamos, NM)

1981-01-01T23:59:59.000Z

36

Large heavy-duty gas turbines for base-load power generation and heat cogeneration  

SciTech Connect

The predominant role of large gas turbines has shifted from peaking-load duty to midrange and base-load electric power generation, especially within combined-cycle plants. Such applications require heavy-duty industrial gas turbines to ensure the same high reliability and availability for continuous service as the associated steam turbines. It is also important that the gas turbines be designed for low maintenance to minimize the necessary outage times and costs for component repair and replacement. The basic design principles and applications of Model V94 gas turbines are discussed with special reference to highly reliable and economic bulk power generation.

Joyce, J.S.

1985-01-01T23:59:59.000Z

37

Optimization of disk generator performance for base-load power plant systems applications  

SciTech Connect

Disk generators for use in base-load MHD power plants are examined for both open-cycle and closed-cycle operating modes. The OCD cases are compared with PSPEC results for a linear channel; enthalpy extractions up to 23% with 71% isentropic efficiency are achievable with generator inlet conditions similar to those used in PSPEC, thus confirming that the disk configuration is a viable alternative for base-load power generation. The evaluation of closed-cycle disks includes use of a simplified cycle model. High system efficiencies over a wide range of power levels are obtained for effective Hall coefficients in the range 2.3 to 4.9. Cases with higher turbulence (implying ..beta../sub eff/ less than or equal to 2.4) yield high system efficiencies at power levels of 100 to 500 MW/sub e/. All these CCD cases compare favorably with linear channels reported in the GE ECAS study, yielding higher isentropic efficiences for a given enthalpy extraction. Power densities in the range 70 to 170 MW/m/sup 3/ appear feasible, leading to very compact generator configurations.

Teare, J.D.; Loubsky, W.J.; Lytle, J.K.; Louis, J.F.

1980-01-01T23:59:59.000Z

38

Development and Demonstration of an Innovative Thermal Energy Storage System for Baseload Power Generation  

Science Conference Proceedings (OSTI)

The objective of this project is to research and develop a thermal energy storage system (operating range 3000C ���¢�������� 450 0C ) based on encapsulated phase change materials (PCM) that can meet the utility-scale base-load concentrated solar power plant requirements at much lower system costs compared to the existing thermal energy storage (TES) concepts. The major focus of this program is to develop suitable encapsulation methods for existing low-cost phase change materials that would provide a cost effective and reliable solution for thermal energy storage to be integrated in solar thermal power plants. This project proposes a TES system concept that will allow for an increase of the capacity factor of the present CSP technologies to 75% or greater and reduce the cost to less than $20/kWht.

D. Y. Goswami

2012-09-04T23:59:59.000Z

39

Nuclear power: least cost option for base-load electricity in Finland  

E-Print Network (OSTI)

As a result of the outstanding operating experience and the low electricity production costs of the existing Finnish nuclear power plants, energy-intensive process industries in particular have a strong belief in nuclear power. There is a potential interest in building more nuclear capacity, the fifth unit, in order to guarantee for Finnish industry the availability of cheap electrical energy in the future. In any case more baseload generation capacity will be needed by 2010 to meet the future growth of electricity consumption in Finland. Nuclear power generation matches excellently with the long-duration load profile of the Finnish power system. The good performance of Finnish nuclear power has yielded benefits also to consumers through its contribution to decreasing the electricity price. Furthermore, the introduction of nuclear power has resulted in a clear drop in the carbon dioxide emissions from electricity generation during the 1970s and 1980s, as shown in Figure 1. In 1999 the four Finnish nuclear power units at Loviisa and Olkiluoto generated 22.1 TWh of electricity, roughly equivalent to one third of the total

Risto Tarjanne; Sauli Rissanen

2000-01-01T23:59:59.000Z

40

Advanced Gas Turbine Guidelines: Hot Gas Path Parts Condition and Remaining Life Assessment for GE 7FA in Baseload Operation  

Science Conference Proceedings (OSTI)

Based on two years experience operating four advanced gas turbines (AGT) General Electric MS 7221 FA at Martin CC of Florida Power & Light (FP&L), this guideline describes the operating and maintenance philosophy used for baseload AGT units and the integrity of the hot path components and their remaining life. The guideline will assist utilities operating the GE MS 7221FA class AGT plan inspections and comparisons with other units in this class.

1997-04-16T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Base-Load and Peak Electricity from a Combined Nuclear Heat and Fossil Combined-Cycle Plant  

SciTech Connect

A combined-cycle power plant is proposed that uses heat from a high-temperature reactor and fossil fuel to meet base-load and peak electrical demands. The high temperature gas turbine produces shaft power to turn an electric generator. The hot exhaust is then fed to a heat recovery steam generator (HRSG) that provides steam to a steam turbine for added electrical power production. A simplified computational model of the thermal power conversion system was developed in order to parametrically investigate two different steady-state operation conditions: base load nuclear heat only from an Advanced High Temperature Reactor (AHTR), and combined nuclear heat with fossil heat to increase the turbine inlet temperature. These two cases bracket the expected range of power levels, where any intermediate power level can result during electrical load following. The computed results indicate that combined nuclear-fossil systems have the potential to offer both low-cost base-load electricity and lower-cost peak power relative to the existing combination of base-load nuclear plants and separate fossil-fired peak-electricity production units. In addition, electric grid stability, reduced greenhouse gases, and operational flexibility can also result with using the conventional technology presented here for the thermal power conversion system coupled with the AHTR. (authors)

Conklin, James C.; Forsberg, Charles W. [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831 (United States)

2007-07-01T23:59:59.000Z

42

Base-Load and Peak Electricity from a Combined Nuclear Heat and Fossil Combined-Cycle Plant  

Science Conference Proceedings (OSTI)

A combined-cycle power plant is proposed that uses heat from a high-temperature reactor and fossil fuel to meet base-load and peak electrical demands. The high-temperature gas turbine produces shaft power to turn an electric generator. The hot exhaust is then fed to a heat recovery steam generator (HRSG) that provides steam to a steam turbine for added electrical power production. A simplified computational model of the thermal power conversion system was developed in order to parametrically investigate two different steady-state operation conditions: base load nuclear heat only from an Advanced High Temperature Reactor (AHTR), and combined nuclear heat with fossil heat to increase the turbine inlet temperature. These two cases bracket the expected range of power levels, where any intermediate power level can result during electrical load following. The computed results indicate that combined nuclear-fossil systems have the potential to offer both low-cost base-load electricity and lower-cost peak power relative to the existing combination of base-load nuclear plants and separate fossil-fired peak-electricity production units. In addition, electric grid stability, reduced greenhouse gases, and operational flexibility can also result with using the conventional technology presented here for the thermal power conversion system coupled with the AHTR.

Conklin, Jim [ORNL; Forsberg, Charles W [ORNL

2007-01-01T23:59:59.000Z

43

Batteries using molten salt electrolyte  

SciTech Connect

An electrolyte system suitable for a molten salt electrolyte battery is described where the electrolyte system is a molten nitrate compound, an organic compound containing dissolved lithium salts, or a 1-ethyl-3-methlyimidazolium salt with a melting temperature between approximately room temperature and approximately 250.degree. C. With a compatible anode and cathode, the electrolyte system is utilized in a battery as a power source suitable for oil/gas borehole applications and in heat sensors.

Guidotti, Ronald A. (Albuquerque, NM)

2003-04-08T23:59:59.000Z

44

Molten salt safety study. Final report  

DOE Green Energy (OSTI)

The considerations concerning safety in using molten salt (40% potassium nitrate, 60% sodium nitrate) in a solar central receiver plant are addressed. The considerations are of a general nature and do not cover any details of equipment or plant operation. The study includes salt chemical reaction, experiments with molten salt, dry storage and handling constraints, and includes data from the National Fire Protection Association. The contents of this report were evaluated by two utility companies and they concluded that no major safety problems exist in using a molten salt solar system.

Not Available

1980-01-01T23:59:59.000Z

45

SEPARATION OF METAL SALTS BY ADSORPTION  

DOE Patents (OSTI)

It has been found that certain metal salts, particularly the halides of iron, cobalt, nickel, and the actinide metals, arc readily absorbed on aluminum oxide, while certain other salts, particularly rare earth metal halides, are not so absorbed. Use is made of this discovery to separate uranium from the rare earths. The metal salts are first dissolved in a molten mixture of alkali metal nitrates, e.g., the eutectic mixture of lithium nitrate and potassium nitrate, and then the molten salt solution is contacted with alumina, either by slurrying or by passing the salt solution through an absorption tower. The process is particularly valuable for the separation of actinides from lanthanum-group rare earths.

Gruen, D.M.

1959-01-20T23:59:59.000Z

46

Innovative Phase Change Thermal Energy Storage Solution for Baseload Power Phase 1 Final Report  

SciTech Connect

The primary purpose of this project is to develop and validate an innovative, scalable phase change salt thermal energy storage (TES) system that can interface with Infinia’s family of free-piston Stirling engines (FPSE). This TES technology is also appropriate for Rankine and Brayton power converters. Solar TES systems based on latent heat of fusion rather than molten salt temperature differences, have many advantages that include up to an order of magnitude higher energy storage density, much higher temperature operation, and elimination of pumped loops for most of Infinia’s design options. DOE has funded four different concepts for solar phase change TES, including one other Infinia awarded project using heat pipes to transfer heat to and from the salt. The unique innovation in this project is an integrated TES/pool boiler heat transfer system that is the simplest approach identified to date and arguably has the best potential for minimizing the levelized cost of energy (LCOE). The Phase 1 objectives are to design, build and test a 1-hour TES proof-of-concept lab demonstrator integrated with an Infinia 3 kW Stirling engine, and to conduct a preliminary design of a 12-hour TES on-sun prototype.

Qiu, Songgang

2013-05-15T23:59:59.000Z

47

Alkali metal nitrate purification  

DOE Patents (OSTI)

A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

1986-02-04T23:59:59.000Z

48

CX-010503: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9, B3.6, B5.17 Date: 06032013 Location(s): Colorado,...

49

Nonaqueous purification of mixed nitrate heat transfer media  

DOE Patents (OSTI)

A nonaqueous, in-line method for removing carbonate and hydroxide contamination from a molten mixed sodium nitrate/potassium nitrate heat transfer salt. The method comprises dissolving a stoichiometric quantity of anhydrous Ca(NO.sub.3).sub.2 in the melt whereby an insoluble CaCO.sub.3 and Ca(OH).sub.2 precipitate is formed. The precipitate can be removed by settling, filtration or floatation techniques.

Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

1983-12-20T23:59:59.000Z

50

Molten salt lithium cells  

DOE Patents (OSTI)

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell which may be operated at temperatures between about 100 to 170/sup 0/C. The cell is comprised of an electrolyte, which preferably includes lithium nitrate, and a lithium or lithium alloy electrode.

Raistrick, I.D.; Poris, J.; Huggins, R.A.

1980-07-18T23:59:59.000Z

51

Molten salt lithium cells  

DOE Patents (OSTI)

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

1983-01-01T23:59:59.000Z

52

Molten salt lithium cells  

DOE Patents (OSTI)

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

1982-02-09T23:59:59.000Z

53

Thermochemical nitrate destruction  

DOE Patents (OSTI)

A method is disclosed for denitrification of nitrates and nitrates present in aqueous waste streams. The method comprises the steps of (1) identifying the concentration nitrates and nitrites present in a waste stream, (2) causing formate to be present in the waste stream, (3) heating the mixture to a predetermined reaction temperature from about 200.degree. C. to about 600.degree. C., and (4) holding the mixture and accumulating products at heated and pressurized conditions for a residence time, thereby resulting in nitrogen and carbon dioxide gas, and hydroxides, and reducing the level of nitrates and nitrites to below drinking water standards.

Cox, John L. (Richland, WA); Hallen, Richard T. (Richland, WA); Lilga, Michael A. (Richland, WA)

1992-01-01T23:59:59.000Z

54

SEPARATION OF INORGANIC SALTS FROM ORGANIC SOLUTIONS  

DOE Patents (OSTI)

A process is described for recovering the nitrates of uranium and plutonium from solution in oxygen-containing organic solvents such as ketones or ethers. The solution of such salts dissolved in an oxygen-containing organic compound is contacted with an ion exchange resin whereby sorption of the entire salt on the resin takes place and then the salt-depleted liquid and the resin are separated from each other. The reaction seems to be based on an anion formation of the entire salt by complexing with the anion of the resin. Strong base or quaternary ammonium type resins can be used successfully in this process.

Katzin, L.I.; Sullivan, J.C.

1958-06-24T23:59:59.000Z

55

Drinking Water Problems: Nitrates  

E-Print Network (OSTI)

High levels of nitrates in drinking water can be harmful for very young infants and susceptible adults. This publication explains how people are exposed to nitrates, what health effects are caused by them in drinking water and how to remove them.

Dozier, Monty; Melton, Rebecca; Hare, Michael; Hopkins, Janie; Lesikar, Bruce J.

2008-03-28T23:59:59.000Z

56

Thermochemical nitrate destruction  

DOE Patents (OSTI)

A method is disclosed for denitrification of nitrates and nitrites present in aqueous waste streams. The method comprises the steps of (1) identifying the concentration nitrates and nitrites present in a waste stream, (2) causing formate to be present in the waste stream, (3) heating the mixture to a predetermined reaction temperature from about 200 C to about 600 C, and (4) holding the mixture and accumulating products at heated and pressurized conditions for a residence time, thereby resulting in nitrogen and carbon dioxide gas, and hydroxides, and reducing the level of nitrates and nitrites to below drinking water standards.

Cox, J.L.; Hallen, R.T.; Lilga, M.A.

1992-06-02T23:59:59.000Z

57

Betting Big on Baseload  

Science Conference Proceedings (OSTI)

Some risks are unavoidable. Rather than pretending to forecast the future, successful companies will need to learn from other cyclical, capital-intensive industries: investing wisely, learning to build asset portfolios consonant with their owners' appetite for risk, and relentlessly seeking opportunities to improve efficiency. (author)

Gabaldon, Daniel; Spiegel, Eric; Van den Berg, Joe

2006-08-15T23:59:59.000Z

58

Thermochemical nitrate reduction  

DOE Green Energy (OSTI)

A series of preliminary experiments was conducted directed at thermochemically converting nitrate to nitrogen and water. Nitrates are a major constituent of the waste stored in the underground tanks on the Hanford Site, and the characteristics and effects of nitrate compounds on stabilization techniques must be considered before permanent disposal operations begin. For the thermochemical reduction experiments, six reducing agents (ammonia, formate, urea, glucose, methane, and hydrogen) were mixed separately with {approximately}3 wt% NO{sub 3}{sup {minus}} solutions in a buffered aqueous solution at high pH (13); ammonia and formate were also mixed at low pH (4). Reactions were conducted in an aqueous solution in a batch reactor at temperatures of 200{degrees}C to 350{degrees}C and pressures of 600 to 2800 psig. Both gas and liquid samples were analyzed. The specific components analyzed were nitrate, nitrite, nitrous oxide, nitrogen, and ammonia. Results of experimental runs showed the following order of nitrate reduction of the six reducing agents in basic solution: formate > glucose > urea > hydrogen > ammonia {approx} methane. Airnmonia was more effective under acidic conditions than basic conditions. Formate was also effective under acidic conditions. A more thorough, fundamental study appears warranted to provide additional data on the mechanism of nitrate reduction. Furthermore, an expanded data base and engineering feasibility study could be used to evaluate conversion conditions for promising reducing agents in more detail and identify new reducing agents with improved performance characteristics.

Cox, J.L.; Lilga, M.A.; Hallen, R.T.

1992-09-01T23:59:59.000Z

59

VOLUME 46 JOURNAL OF APPLIED METEOROLOGY AND CLIMATOLOGY NOVEMBER 2007 Supplying Baseload Power and Reducing Transmission Requirements by Interconnecting Wind Farms  

E-Print Network (OSTI)

Wind is the world’s fastest growing electric energy source. Because it is intermittent, though, wind is not used to supply baseload electric power today. Interconnecting wind farms through the transmission grid is a simple and effective way of reducing deliverable wind power swings caused by wind intermittency. As more farms are interconnected in an array, wind speed correlation among sites decreases and so does the probability that all sites experience the same wind regime at the same time. The array consequently behaves more and more similarly to a single farm with steady wind speed and thus steady deliverable wind power. In this study, benefits of interconnecting wind farms were evaluated for 19 sites, located in the midwestern United States, with annual average wind speeds at 80 m above ground, the hub height of modern wind turbines, greater than 6.9 m s ?1 (class 3 or greater). It was found that an average of 33 % and a maximum of 47 % of yearly averaged wind power from interconnected farms can be used as reliable, baseload electric power. Equally significant, interconnecting multiple wind farms to a common point and then connecting that point to a far-away city can allow the long-distance portion of transmission capacity to be reduced, for example, by 20 % with only a 1.6 % loss of energy. Although most parameters, such as intermittency, improved less than linearly as the number of interconnected sites increased, no saturation of the benefits

Cristina L. Archer; Mark; Z. Jacobson

2006-01-01T23:59:59.000Z

60

Crystallization of sodium nitrate from radioactive waste  

SciTech Connect

From the 1940s to the 1980s, the Institute of Physical Chemistry of the Russian Academy of Sciences (IPC/RAS) conducted research and development on processes to separate acetate and nitrate salts and acetic acid from radioactive wastes by crystallization. The research objective was to decrease waste volumes and produce the separated decontaminated materials for recycle. This report presents an account of the IPC/RAS experience in this field. Details on operating conditions, waste and product compositions, decontamination factors, and process equipment are described. The research and development was generally related to the management of intermediate-level radioactive wastes. The waste solutions resulted from recovery and processing of uranium, plutonium, and other products from irradiated nuclear fuel, neutralization of nuclear process solutions after extractant recovery, regeneration of process nitric acid, equipment decontamination, and other radiochemical processes. Waste components include nitric acid, metal nitrate and acetate salts, organic impurities, and surfactants. Waste management operations generally consist of two stages: volume reduction and processing of the concentrates for storage, solidification, and disposal. Filtration, coprecipitation, coagulation, evaporation, and sorption were used to reduce waste volume. 28 figs., 40 tabs.

Krapukhin, V.B.; Krasavina, E.P. Pikaev, A.K. [Russian Academy of Sciences, Moscow (Russian Federation). Institute of Physical Chemistry

1997-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Energetic Material – Electro Nitration  

INL has developed an improved method of nitrating a nitro compound by oxidizing a chemical mediator in the presence of a voltage in order to produce an oxidizing agent. Then, the agent reacts with a nitro compound and ion source in a solution in order ...

62

Brines formed by multi-salt deliquescence  

SciTech Connect

The FY05 Waste Package Environment testing program at Lawrence Livermore National Laboratory focused on determining the temperature, relative humidity, and solution compositions of brines formed due to the deliquescence of NaCl-KNO{sub 3}-NaNO{sub 3} and NaCl-KNO{sub 3}-NaNO{sub 3}-Ca(NO{sub 3}){sub 2} salt mixtures. Understanding the physical and chemical behavior of these brines is important because they define conditions under which brines may react with waste canister surfaces. Boiling point experiments show that NaCl-KNO{sub 3}-NaNO{sub 3} and NaCl-KNO{sub 3}-NaNO{sub 3}-Ca(NO{sub 3}){sub 2} salt mixtures form brines that transform to hydrous melts that do not truly 'dry out' until temperatures exceed 300 and 400 C, respectively. Thus a conducting solution is present for these salt assemblages over the thermal history of the repository. The corresponding brines form at lower relative humidity at higher temperatures. The NaCl-KNO{sub 3}-NaNO{sub 3} salt mixture has a mutual deliquescence relative humidity (MDRH) of 25.9% at 120 C and 10.8% at 180 C. Similarly, the KNO{sub 3}-NaNO{sub 3} salt mixture has MDRH of 26.4% at 120 C and 20.0% at 150 C. The KNO{sub 3}-NaNO{sub 3} salt mixture salts also absorb some water (but do not appear to deliquesce) at 180 C and thus may also contribute to the transfer of electrons at interface between dust and the waste package surface. There is no experimental evidence to suggest that these brines will degas and form less deliquescent salt assemblages. Ammonium present in atmospheric and tunnel dust (as the chloride, nitrate, or sulfate) will readily decompose in the initial heating phase of the repository, and will affect subsequent behavior of the remaining salt mixture only through the removal of a stoichiometric equivalent of one or more anions. Although K-Na-NO{sub 3}-Cl brines form at high temperature and low relative humidity, these brines are dominated by nitrate, which is known to inhibit corrosion at lower temperature. Nitrate to chloride ratios of the NaCl-KNO{sub 3}-NaNO{sub 3} salt mixture are about NO{sub 3}:Cl = 19:1. The role of nitrate on corrosion at higher temperatures is addressed in a companion report (Dixit et al., 2005).

Carroll, S; Rard, J; Alai, M; Staggs, K

2005-11-04T23:59:59.000Z

63

NITRATE DESTRUCTION LITERATURE SURVEY AND EVALUATION CRITERIA  

DOE Green Energy (OSTI)

This report satisfies the initial phase of Task WP-2.3.4 Alternative Sodium Recovery Technology, Subtask 1; Develop Near-Tank Nitrate/Nitrite Destruction Technology. Some of the more common anions in carbon steel waste tanks at SRS and Hanford Site are nitrate which is corrosive, and nitrite and hydroxide which are corrosion inhibitors. At present it is necessary to periodically add large quantities of 50 wt% caustic to waste tanks. There are three primary reasons for this addition. First, when the contents of salt tanks are dissolved, sodium hydroxide preferentially dissolves and is removed. During the dissolution process the concentration of free hydroxide in the tank liquid can decrease from 9 M to less than 0.2 M. As a result, roughly half way through the dissolution process large quantities of sodium hydroxide must be added to the tank to comply with requirements for corrosion control. Second, hydroxide is continuously consumed by reaction with carbon dioxide which occurs naturally in purge air used to prevent buildup of hydrogen gas inside the tanks. The hydrogen is generated by radiolysis of water. Third, increasing the concentration of hydroxide increases solubility of some aluminum compounds, which is desirable in processing waste. A process that converts nitrate and nitrite to hydroxide would reduce certain costs. (1) Less caustic would be purchased. (2) Some of the aluminum solid compounds in the waste tanks would become more soluble so less mass of solids would be sent to High Level Vitrification and therefore it would be not be necessary to make as much expensive high level vitrified product. (3) Less mass of sodium would be fed to Saltstone at SRS or Low Level Vitrification at Hanford Site so it would not be necessary to make as much low level product. (4) At SRS less nitrite and nitrate would be sent to Defense Waste Processing Facility (DWPF) so less formic acid would be consumed there and less hydrogen gas would be generated. This task involves literature survey of technologies to perform the nitrate to hydroxide conversion, selection of the most promising technologies, preparation of a flowsheet and design of a system. The most promising technologies are electrochemical reduction of nitrates and chemical reduction with hydrogen or ammonia. The primary reviewed technologies are listed and they aredescribed in more detail later in the report: (1) Electrochemical destruction; (2) Chemical reduction with agents such as ammonia, hydrazine or hydrogen; (3) Hydrothermal reduction process; and (4) Calcination. Only three of the technologies on the list have been demonstrated to generate usable amounts of caustic; electrochemical reduction and chemical reduction with ammonia, hydrazine or hydrogen and hydrothermal reduction. Chemical reduction with an organic reactant such as formic acid generates carbon dioxide which reacts with caustic and is thus counterproductive. Treatment of nitrate with aluminum or other active metals generates a solid product. High temperature calcination has the potential to generate sodium oxide which may be hydrated to sodium hydroxide, but this is unproven. The following criteria were developed to evaluate the most suitable option. The numbers in brackets after the criteria are relative weighting factors to account for importance: (1) Personnel exposure to radiation for installation, routine operation and maintenance; (2) Non-radioactive safety issues; (3) Whether the technology generates caustic and how many moles of caustic are generated per mole of nitrate plus nitrite decomposed; (4) Whether the technology can handle nitrate and nitrite at the concentrations encountered in waste; (5) Maturity of technology; (6) Estimated annual cost of operation (labor, depreciation, materials, utilities); (7) Capital cost; (8) Selectivity to nitrogen as decomposition product (other products are flammable and/or toxic); (9) Impact of introduced species; (10) Selectivity for destruction of nitrate vs. nitrite; and (11) Cost of deactivation and demolition. Each technology was given a score from one

Steimke, J.

2011-02-01T23:59:59.000Z

64

Iodized Salt  

NLE Websites -- All DOE Office Websites (Extended Search)

Iodized Salt Iodized Salt Name: Theresa Location: N/A Country: N/A Date: N/A Question: Why do they put iodine in salt? Replies: Iodine was introduced into salt at earlier this century when it was discovered that certain areas of the US had a mark deficiency in iodine in the diet of people, and people developed a neck swelling (goiter). The Great Lakes region is one of these areas where the soil is lacking iodine. Goiter can be caused when the thyroid gland swells because of a lack of iodine in the diet. Most medical advise now states that iodine in salt is no longer necessary due to our food sources arising from all over the world. Steve Sample Hi Theresa...see, there are a variety of elements and compounds that are necessary for the proper maintenance of our life. One of these is iodine, since a small quantity of iodine is needed for the adequate functioning of the thyroid gland. A deficiency of iodine produces dire effects, as goiter, where the thyroid gland swollens due to the lack of iodine traces in the diet. The iodine affects directly the tyrhoid gland secretions, which themselves, to a great extent, control heart action, nerve response to stimuli, rate of body growth and metabolism.

65

Purification of alkali metal nitrates  

DOE Patents (OSTI)

A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

Fiorucci, Louis C. (Hamden, CT); Gregory, Kevin M. (Woodridge, IL)

1985-05-14T23:59:59.000Z

66

Molten Salt Solar-Electric Experiment: Volumes 1 and 2  

Science Conference Proceedings (OSTI)

The Molten Salt Electric Experiment assembled and tested the first full-system experiment of a solar central receiver plant employing molten nitrate salt as the heat transport fluid and thermal storage medium. This report focuses on the last two phases of the project: testing/operation and evaluation. Overall project data will help utilities evaluate the central receiver concept's technical status, development requirements, and potential as a renewable source of electricity.

1990-01-03T23:59:59.000Z

67

Evaluation of nitrate destruction methods  

Science Conference Proceedings (OSTI)

A wide variety of high nitrate-concentration aqueous mixed [radioactive and Resource Conservation and Recovery Act (RCRA) hazardous] wastes are stored at various US Department of Energy (DOE) facilities. These wastes will ultimately be solidified for final disposal, although the waste acceptance criteria for the final waste form is still being determined. Because the nitrates in the wastes will normally increase the volume or reduce the integrity of all of the waste forms under consideration for final disposal, nitrate destruction before solidification of the waste will generally be beneficial. This report describes and evaluates various technologies that could be used to destroy the nitrates in the stored wastes. This work was funded by the Department of Energy`s Office of Technology Development, through the Chemical/Physical Technology Support Group of the Mixed Waste Integrated Program. All the nitrate destruction technologies will require further development work before a facility could be designed and built to treat the majority of the stored wastes. Several of the technologies have particularly attractive features: the nitrate to ammonia and ceramic (NAC) process produces an insoluble waste form with a significant volume reduction, electrochemical reduction destroys nitrates without any chemical addition, and the hydrothermal process can simultaneously treat nitrates and organics in both acidic and alkaline wastes. These three technologies have been tested using lab-scale equipment and surrogate solutions. At their current state of development, it is not possible to predict which process will be the most beneficial for a particular waste stream.

Taylor, P.A. [Oak Ridge National Lab., TN (United States); Kurath, D.E.; Guenther, R. [Pacific Northwest Lab., Richland, WA (United States)

1993-03-30T23:59:59.000Z

68

TREATMENT OF AMMONIUM NITRATE SOLUTIONS  

DOE Patents (OSTI)

The treatment of waste solutions obtained in the processing of neutron- irradiated uranium containing fission products and ammonium nitrate is described. The object of this process is to provide a method whereby the ammonium nitrate is destroyed and removed from the solution so as to permit subsequent concentration of the solution.. In accordance with the process the residual nitrate solutions are treated with an excess of alkyl acid anhydride, such as acetic anhydride. Preferably, the residual nitrate solution is added to an excess of the acetic anhydride at such a rate that external heat is not required. The result of this operation is that the ammonium nitrate and acetic anhydride react to form N/sub 2/ O and acetic acid.

Boyer, T.W.; MacHutchin, J.G.; Yaffe, L.

1958-06-10T23:59:59.000Z

69

Plutonium and americium recovery from spent molten-salt-extraction salts with aluminum-magnesium alloys  

Science Conference Proceedings (OSTI)

Development work was performed to determine the feasibility of removing plutonium and americium from spent molten-salt-extraction (MSE) salts using Al-Mg alloys. If the product buttons from this process are compatible with subsequent aqueous processing, the complex chloride-to-nitrate aqueous conversion step which is presently required for these salts may be eliminated. The optimum alloy composition used to treat spent 8 wt % MSE salts in the past yielded poor phase-disengagement characteristics when applied to 30 mol % salts. After a limited investigation of other alloy compositions in the Al-Mg-Pu-Am system, it was determined that the Al-Pu-Am system could yield a compatible alloy. In this system, experiments were performed to investigate the effects of plutonium loading in the alloy, excess magnesium, age of the spent salt on actinide recovery, phase disengagement, and button homogeneity. Experimental results indicate that 95 percent plutonium recoveries can be attained for fresh salts. Further development is required for backlog salts generated prior to 1981. A homogeneous product alloy, as required for aqueous processing, could not be produced.

Cusick, M.J.; Sherwood, W.G.; Fitzpatrick, R.F.

1984-04-23T23:59:59.000Z

70

Nitrates/Nitrites  

Science Conference Proceedings (OSTI)

Table 1   Corrosion rates of iron-base alloys in eutectic molten salt mixtures...Stainless steel μm/yr mils/yr μm/yr mils/yr NaNO 3 -NaCl-Na 2 SO 4 (86.3,8.4,5.3 mol%, respectively) 15 0.6 1 0.03 KNO 3 -KCl (94.6 mol%, respectively) 23 0.9 7.5 0.3 LiCl-KCl (58.42 mol%, respectively) 63 2.5 20 0.8...

71

Stainless steel corrosion by molten nitrates : analysis and lessons learned.  

SciTech Connect

A secondary containment vessel, made of stainless 316, failed due to severe nitrate salt corrosion. Corrosion was in the form of pitting was observed during high temperature, chemical stability experiments. Optical microscopy, scanning electron microscopy and energy dispersive spectroscopy were all used to diagnose the cause of the failure. Failure was caused by potassium oxide that crept into the gap between the primary vessel (alumina) and the stainless steel vessel. Molten nitrate solar salt (89% KNO{sub 3}, 11% NaNO{sub 3} by weight) was used during chemical stability experiments, with an oxygen cover gas, at a salt temperature of 350-700 C. Nitrate salt was primarily contained in an alumina vessel; however salt crept into the gap between the alumina and 316 stainless steel. Corrosion occurred over a period of approximately 2000 hours, with the end result of full wall penetration through the stainless steel vessel; see Figures 1 and 2 for images of the corrosion damage to the vessel. Wall thickness was 0.0625 inches, which, based on previous data, should have been adequate to avoid corrosion-induced failure while in direct contact with salt temperature at 677 C (0.081-inch/year). Salt temperatures exceeding 650 C lasted for approximately 14 days. However, previous corrosion data was performed with air as the cover gas. High temperature combined with an oxygen cover gas obviously drove corrosion rates to a much higher value. Corrosion resulted in the form of uniform pitting. Based on SEM and EDS data, pits contained primarily potassium oxide and potassium chromate, reinforcing the link between oxides and severe corrosion. In addition to the pitting corrosion, a large blister formed on the side wall, which was mainly composed of potassium, chromium and oxygen. All data indicated that corrosion initiated internally and moved outward. There was no evidence of intergranular corrosion nor were there any indication of fast pathways along grain boundaries. Much of the pitting occurred near welds; however this was the hottest region in the chamber. Pitting was observed up to two inches above the weld, indicating independence from weld effects.

Kruizenga, Alan Michael

2011-09-01T23:59:59.000Z

72

Using solvent extraction to process nitrate anion exchange column effluents  

SciTech Connect

Octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO), a new organophosphorous extractant, and a new centrifugal mixer-settler both recently developed at Argonne were evaluated for their potential use in the recovery of actinides from nitrate anion exchange column effluents. The performance of the extractant was evaluated by measuring the extraction coefficient values as a function of acid and salt concentration. Additional performance parameters include extraction coefficient behavior as a function of the total metal concentration in the organic phase, and comparison of different stripping and organic scrubbing techniques. A simulated effluent stream was used to evaluate the performance of the centrifugal mixer-settlers by comparing experimental and calculated interstage concentration profiles. Both the CMPO extractant and the centrifugal mixer-settlers have potential for processing nitrate column effluents, particularly if the stripping behavior can be improved. Details of the proposed process are presented in the flowsheet and contactor design analyses.

Yarbro, S.L.

1987-10-01T23:59:59.000Z

73

Process for reducing aqueous nitrate to ammonia  

DOE Patents (OSTI)

Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product.

Mattus, Alfred J. (Oak Ridge, TN)

1993-01-01T23:59:59.000Z

74

Process for reducing aqueous nitrate to ammonia  

DOE Patents (OSTI)

Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product. 3 figures.

Mattus, A.J.

1993-11-30T23:59:59.000Z

75

Biological denitrification of high concentration nitrate waste  

DOE Patents (OSTI)

Biological denitrification of nitrate solutions at concentrations of greater than one kilogram nitrate per cubic meter is accomplished anaerobically in an upflow column having as a packing material a support for denitrifying bacteria.

Francis, Chester W. (Oak Ridge, TN); Brinkley, Frank S. (Knoxville, TN)

1977-01-01T23:59:59.000Z

76

Emulsion explosives containing high concentrations of calcium nitrate  

SciTech Connect

A water-in-oil emulsion blasting agent is described having a discontinuous aqueous oxidizer salt solution phase which contains a calcium nitrate (CN) to ammonium nitrate (AN) weight ratio of 1.5 or greater, a continuous oil or water-immiscible liquid organic phase, an emulsifier, and, optionally, a density reducing agent. It is found that emulsion slurry blasting agents containing this relatively high amount of CN to AN have properties that conventional emulsion slurry explosives, those containing more AN than CN or solely AN, do not. Specifically, one property is that the high-CN emulsion blasting agents of the present composition can have much smaller critical diameters but yet pass the US DOT Blasting Agent tests. This result will be shown in the examples that follow. Thus, if AN is present as the principal oxidizer salt, emulsion explosives that have small critical diameters, and even those with relatively large critical diameters, generally are too sensitive to pass the Blasting Agent tests. If CN is the principal oxidizer, the emulsion blasting agents are less sensitive and more likely to pass the tests. This effect of CN has commercial significance. 10 claims.

Jessop, H.A.; Funk, A.G.

1982-10-26T23:59:59.000Z

77

Molten salt electrolyte separator  

DOE Patents (OSTI)

A molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication.

Kaun, Thomas D. (New Lenox, IL)

1996-01-01T23:59:59.000Z

78

Method of producing thin cellulose nitrate film  

DOE Patents (OSTI)

An improved method for forming a thin nitrocellulose film of reproducible thickness is described. The film is a cellulose nitrate film, 10 to 20 microns in thickness, cast from a solution of cellulose nitrate in tetrahydrofuran, said solution containing from 7 to 15 percent, by weight, of dioctyl phthalate, said cellulose nitrate having a nitrogen content of from 10 to 13 percent.

Lupica, S.B.

1975-12-23T23:59:59.000Z

79

Electrolytic production of uranous nitrate  

SciTech Connect

Efficient production of uranous nitrate is important in nuclear fuel reprocessing because U(IV) acts as a plutonium reductant in solvent extraction and can be coprecipitated with plutonium and/or throium as oxalates during fuel reprocessing. Experimental conditions are described for the efficient electrolytic production of uranous nitrate for use as a reductant in the SRP Purex process. The bench-scale, continuous-flow, electrolysis cell exhibits a current efficiency approaching 100% in combination with high conversion rates of U(VI) to U(IV) in simulated and actual SRP Purex solutions. High current efficiency is achieved with a voltage-controlled mercury-plated platinum electrode and the use of hydrazine as a nitrite scavenger. Conversion of U(VI) to U(IV) proceeds at 100% efficiency. Cathodic gas generation is minimal. The low rate of gas generation permits a long residence time within the cathode, a necessary condition for high conversions on a continuous basis. Design proposals are given for a plant-scale, continuous-flow unit to meet SRP production requirements. Results from the bench-scale tests indicate that an 8-kW unit can supply sufficient uranous nitrate reductant to meet the needs of the Purex process at SRP.

Orebaugh, E.G.; Propst, R.C.

1980-04-01T23:59:59.000Z

80

The Effects of Nanoparticle Augmentation of Nitrate Thermal Storage Materials for Use in Concentrating Solar Power Applications  

E-Print Network (OSTI)

The Department of Energy funded a project to determine if the specific heat of thermal energy storage materials could be improved by adding nanoparticles. The standard thermal energy storage materials are molten salts. The chosen molten salt was a sodium nitrate and potassium nitrate eutectic, commercially called Hitec Solar Salt. Two nanoparticle types were chosen, alumina and silica. The nanoparticle composite materials were fabricated by mixing the components in an aqueous solution, mixing that solution for a set amount of time using a sonic mixer, then removing the water from the aqueous solution, leaving the composite molten salt behind as a fine white powder. The thermal properties of the composite and plain material were measured using two techniques: American Society for Testing and Materials (ASTM) 1269E and Modulating Differential Scanning Calorimetry (MDSC). These two techniques measured the specific heat and the heat of fusion of the plain and composite materials. The results of all the ASTM and MDSC measurements suggest that the addition of the nanoparticles using the given manufacturing technique increased the specific heat of the molten salt by approximately 20 percent, with both measurement techniques showing approximately the same level of increase. The silica and the alumina improved the specific heat by nearly the same amount over the base material. The heat of fusion did not seem to be significantly altered compared to the observed heat of fusion value of the unmodified material. It was also observed that the nitrate and silica composite material's specific heat decreased if the material was raised to a temperature above 400C. The specific heat was observed to decrease over time, even when the temperature was well below 400C. It is unknown why this occurred. The nitrate plus alumina composite and the plain nitrate were stable to a temperature of 450C for the test duration.

Betts, Matthew

2011-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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81

Amine salts of nitroazoles  

DOE Patents (OSTI)

Compositions of matter, a method of providing chemical energy by burning said compositions, and methods of making said compositions. These compositions are amine salts of nitroazoles.

Lee, Kien-yin (Los Alamos, NM); Stinecipher, Mary M. (Los Alamos, NM)

1993-01-01T23:59:59.000Z

82

Molten salt electrolyte separator  

DOE Patents (OSTI)

The patent describes a molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication. 5 figs.

Kaun, T.D.

1996-07-09T23:59:59.000Z

83

Modeling of Sulfate Double-salts in Nuclear Wastes  

Science Conference Proceedings (OSTI)

Due to limited tank space at Hanford and Savannah River, the liquid nuclear wastes or supernatants have been concentrated in evaporators to remove excess water prior to the hot solutions being transferred to underground storage tanks. As the waste solutions cooled, the salts in the waste exceeded the associated solubility limits and precipitated in the form of saltcakes. The initial step in the remediation of these saltcakes is a rehydration process called saltcake dissolution. At Hanford, dissolution experiments have been conducted on small saltcake samples from five tanks. Modeling of these experimental results, using the Environmental Simulation Program (ESP), are being performed at the Diagnostic Instrumentation and Analysis Laboratory (DIAL) at Mississippi State University. The River Protection Project (RPP) at Hanford will use these experimental and theoretical results to determine the amount of water that will be needed for its dissolution and retrieval operations. A comprehensive effort by the RPP and the Tank Focus Area continues to validate and improve the ESP and its databases for this application. The initial effort focused on the sodium, fluoride, and phosphate system due to its role in the formation of pipeline plugs. In FY 1999, an evaluation of the ESP predictions for sodium fluoride, trisodium phosphate dodecahydrate, and natrophosphate clearly indicated that improvements to the Public database of the ESP were needed. One of the improvements identified was double salts. The inability of any equilibrium thermodynamic model to properly account for double salts in the system can result in errors in the predicted solid-liquid equilibria (SLE) of species in the system. The ESP code is evaluated by comparison with experimental data where possible. However, data does not cover the range of component concentrations and temperatures found in many tank wastes. Therefore, comparison of ESP with another code is desirable, and may illuminate problems with both. For this purpose, the SOLGASMIX code was used in conjunction with a small private database developed at ORNL. This code calculates thermodynamic equilibria through minimization of Gibbs Energy, and utilizes the Pitzer model for activity coefficients. The sodium nitrate-sulfate double salt and the sodium fluoride-sulfate double salt were selected for the FY 2000 validation study of ESP. Even though ESP does not include the sulfate-nitrate double salt, this study found that this omission does not appear to be a major consequence. In this case, the solubility predictions with and without the sulfate-nitrate double salt are comparable. In contrast, even though the sulfate-fluoride double salt is included within the ESP databank, comparison to previous experimental results indicates that ESP underestimates solubility. Thus, the prediction for the sulfate-fluoride system needs to be improved. A main consequence of the inability to accurately predict the SLE of double salts is its impact on the predicted ionic strength of the solution. The ionic strength has been observed to be an important factor in the formation of pipeline plugs. To improve the ESP prediction, solubility tests on the sulfate-fluoride system are underway at DIAL, and these experimental results will be incorporated into the Public database by OLI System, Inc. Preliminary ESP simulations also indicated difficulties with the SLE prediction for anhydrous sodium sulfate. The Public database for the ESP does not include fundamental parameters for this solid in mixed solutions below 32.4 C. The limitation, in the range of anhydrous sodium sulfate, leads to convergence problems in ESP and to inaccurate predictions of solubility near the invariant point when sodium sulfate decahydrate and other salts, such as sodium nitrate, were present. These difficulties were partially corrected through the use of an additional database. In conclusion, these results indicate the need for experimental data at temperatures above 25 C and in solutions containing both nitrate and hydroxide. Furthermore, the validation and do

Toghiani, B.

2000-10-30T23:59:59.000Z

84

Process for converting sodium nitrate-containing, caustic liquid radioactive wastes to solid insoluble products  

DOE Patents (OSTI)

A method for converting sodium nitrate-containing, caustic, radioactive wastes to a solid, relatively insoluble, thermally stable form is provided and comprises the steps of reacting powdered aluminum silicate clay, e.g., kaolin, bentonite, dickite, halloysite, pyrophyllite, etc., with the sodium nitrate-containing radioactive wastes which have a caustic concentration of about 3 to 7 M at a temperature of 30.degree. C to 100.degree. C to thereby entrap the dissolved radioactive salts in the aluminosilicate matrix. In one embodiment the sodium nitrate-containing, caustic, radioactive liquid waste, such as neutralized Purex-type waste, or salts or oxide produced by evaporation or calcination of these liquid wastes (e.g., anhydrous salt cake) is converted at a temperature within the range of 30.degree. C to 100.degree. C to the solid mineral form-cancrinite having an approximate chemical formula 2(NaAlSiO.sub.4) .sup.. xSalt.sup.. y H.sub.2 O with x = 0.52 and y = 0.68 when the entrapped salt is NaNO.sub.3. In another embodiment the sodium nitrate-containing, caustic, radioactive liquid is reacted with the powdered aluminum silicate clay at a temperature within the range of 30.degree. C to 100.degree. C, the resulting reaction product is air dried eitheras loose powder or molded shapes (e.g., bricks) and then fired at a temperature of at least 600.degree. C to form the solid mineral form-nepheline which has the approximate chemical formula of NaAlSiO.sub.4. The leach rate of the entrapped radioactive salts with distilled water is reduced essentially to that of the aluminosilicate lattice which is very low, e.g., in the range of 10.sup.-.sup.2 to 10.sup.-.sup.4 g/cm.sup.2 -- day for cancrinite and 10.sup.-.sup.3 to 10.sup.-.sup.5 g/cm.sup.2 -- day for nepheline.

Barney, Gary S. (Richland, WA); Brownell, Lloyd E. (Richland, WA)

1977-01-01T23:59:59.000Z

85

Molten salt test loop  

DOE Green Energy (OSTI)

The objective of the Molten Salt Test Loop Project was to design, construct, and demonstrate operation of an outdoor high temperature molten salt test facility. This facility is operational, and can now be used to evaluate materials and components, and the design features and operating procedures required for molten salt heat transport systems. The initial application of the loop was to demonstrate the feasibility of using molten salt as the heat transport medium for a high temperature distributed collector system. A commercially available eutectic salt blend is used as the heat transfer fluid. This salt has a composition of 40% NaNO/sub 2/, 7% NaNO/sub 3/, and 53% KNO/sub 3/ and is marketed under the trade name Hitec. It has a freezing (solidifying) point of 142/sup 0/C (288/sup 0/F) and has been satisfactorily used at temperatures as high as 594/sup 0/C (1100/sup 0/F). General Atomic (GA) installed a row of Fixed Mirror Solar Concentrators (FMSC's) in the loop. The system was started up and a test program conducted. Startup went smoothly, with the exception of some burned-out trace heaters. Salt temperatures as high as 571/sup 0/C (1060/sup 0/F) were achieved.

Schuster, J.R.; Eggers, G.H.

1980-01-01T23:59:59.000Z

86

The Transformation of Outdoor Ammonium Nitrate Aerosols in the...  

NLE Websites -- All DOE Office Websites (Extended Search)

The Transformation of Outdoor Ammonium Nitrate Aerosols in the Indoor Environment Title The Transformation of Outdoor Ammonium Nitrate Aerosols in the Indoor Environment...

87

Salt Waste Processing Initiatives  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Patricia Suggs Patricia Suggs Salt Processing Team Lead Assistant Manager for Waste Disposition Project Office of Environmental Management Savannah River Site Salt Waste Processing Initiatives 2 Overview * Current SRS Liquid Waste System status * Opportunity to accelerate salt processing - transformational technologies - Rotary Microfiltration (RMF) and Small Column Ion Exchange (SCIX) - Actinide Removal Process/Modular Caustic Side Solvent Extraction (ARP/MCU) extension with next generation extractant - Salt Waste Processing Facility (SWPF) performance enhancement - Saltstone enhancements * Life-cycle impacts and benefits 3 SRS Liquid Waste Total Volume >37 Million Gallons (Mgal) Total Curies 183 MCi (51% ) 175 MCi (49% ) >358 Million Curies (MCi) Sludge 34.3 Mgal (92% ) 3.0 Mgal (8%)

88

Amine salts of nitroazoles  

DOE Patents (OSTI)

Compositions of matter, a method of providing chemical energy by burning said compositions, and methods of making said compositions are described. These compositions are amine salts of nitroazoles. 1 figure.

Kienyin Lee; Stinecipher, M.M.

1993-10-26T23:59:59.000Z

89

Salt Selected (FINAL)  

NLE Websites -- All DOE Office Websites (Extended Search)

WHY SALT WAS SELECTED AS A DISPOSAL MEDIUM WHY SALT WAS SELECTED AS A DISPOSAL MEDIUM Waste Isolation Pilot Plant U.S. Department Of Energy Government officials and scientists chose the Waste Isolation Pilot Plant (WIPP) site through a selection process that started in the 1950s. At that time, the National Academy of Sciences conducted a nationwide search for geological formations stable enough to contain radioactive wastes for thousands of years. In 1955, after extensive

90

Molten Salt Test Loop (MSTL) system customer interface document.  

SciTech Connect

The National Solar Thermal Test Facility at Sandia National Laboratories has a unique test capability called the Molten Salt Test Loop (MSTL) system. MSTL is a test capability that allows customers and researchers to test components in flowing, molten nitrate salt. The components tested can range from materials samples, to individual components such as flex hoses, ball joints, and valves, up to full solar collecting systems such as central receiver panels, parabolic troughs, or linear Fresnel systems. MSTL provides realistic conditions similar to a portion of a concentrating solar power facility. The facility currently uses 60/40 nitrate %E2%80%9Csolar salt%E2%80%9D and can circulate the salt at pressure up to 40 bar (600psi), temperature to 585%C2%B0C, and flow rate of 44-50kg/s(400-600GPM) depending on temperature. The purpose of this document is to provide a basis for customers to evaluate the applicability to their testing needs, and to provide an outline of expectations for conducting testing on MSTL. The document can serve as the basis for testing agreements including Work for Others (WFO) and Cooperative Research and Development Agreements (CRADA). While this document provides the basis for these agreements and describes some of the requirements for testing using MSTL and on the site at Sandia, the document is not sufficient by itself as a test agreement. The document, however, does provide customers with a uniform set of information to begin the test planning process.

Gill, David Dennis; Kolb, William J.; Briggs, Ronald D.

2013-09-01T23:59:59.000Z

91

Study of the interactions of molten sodium nitrate-potassium nitrate 50 mol % mixture with water vapor and carbon dioxide in air. Final report, June 2, 1980-June 30, 1981  

DOE Green Energy (OSTI)

The interactions of aerial components such as water, carbon dioxide, and oxygen with the binary 50 mol % mixture of sodium nitrate and potassium nitrate have been studied in the temperature range 300 to 600/sup 0/C using electrochemical methods. In addition, the behavior of nitrite ions in this melt was investigated electrochemically. By judicious choice of techniques, in situ electroanalysis was possible and the necessary relevant data to accomplish this is presented, as well as insight into the corresponding electrochemical mechanisms associated with the electroactive species. The influence of each atmospheric component was examined separately. At temperatures above 300/sup 0/C, nitrite ions are found to accumulate due to thermal decomposition of the nitrate. Water is highly soluble in the salt mixture, but no hydrolytic reactions were observed. Two methods of in situ analysis for water are described. Pure carbon dioxide is found to attack the melt at all temperatures above 250/sup 0/C producing carbonate. (LEW)

White, S.H.; Twardoch, U.M.

1981-09-01T23:59:59.000Z

92

CRITICALITY SAFETY OF PROCESSING SALT SOLUTION AT SRS  

Science Conference Proceedings (OSTI)

High level radioactive liquid waste generated as a result of the production of nuclear material for the United States defense program at the Savannah River Site has been stored as 36 million gallons in underground tanks. About ten percent of the waste volume is sludge, composed of insoluble metal hydroxides primarily hydroxides of Mn, Fe, Al, Hg, and most radionuclides including fission products. The remaining ninety percent of the waste volume is saltcake, composed of primarily sodium (nitrites, nitrates, and aluminates) and hydroxides. Saltcakes account for 30% of the radioactivity while the sludge accounts for 70% of the radioactivity. A pilot plant salt disposition processing system has been designed at the Savannah River Site for interim processing of salt solution and is composed of two facilities: the Actinide Removal Process Facility (ARPF) and the Modular Caustic Side Solvent Extraction Unit (MCU). Data from the pilot plant salt processing system will be used for future processing salt at a much higher rate in a new salt processing facility. Saltcake contains significant amounts of actinides, and other long-lived radioactive nuclides such as strontium and cesium that must be extracted prior to disposal as low level waste. The extracted radioactive nuclides will be mixed with the sludge from waste tanks and vitrified in another facility. Because of the presence of highly enriched uranium in the saltcake, there is a criticality concern associated with concentration and/or accumulation of fissionable material in the ARP and MCU.

Stephens, K; Davoud Eghbali, D; Michelle Abney, M

2008-01-15T23:59:59.000Z

93

ELECTROLYTIC OXIDATION OF ZIRCONIUM IN NITRATE SOLUTIONS  

SciTech Connect

Zirconiurn alloys used in the fabrication of nuclear fuel elements can be disintegrated and converted to insoluble oxides by electrolytic treatment in concentrated nitrate solutions. This reaction shows promise as a technique for reprocessing nuclear fuels clad with Zircaloy-2. For a particular applied voltage, nitric acid achieves the highest rate of attack, but the reaction can be carried out at rates of 2 mg/(cm/sup 2/)(min) or greater in either 7.5M sodium nitrate or 2.3M aluminum nitrate. A reaction rate of 7 mg/(cm/sup 2/) (min) can be easily attained in either 8M nitric acid or 7.5M sodium nitrate. The rate of reaction is a function of the temperature and tho applied voltage. An as-yet unsolved problem is the carry--down of uranium with the insoluble zirconium oxide product. (auth)

Bomar, M.R.

1961-12-29T23:59:59.000Z

94

Process for the preparation of an energetic nitrate ester  

SciTech Connect

A process for the preparation of an energetic nitrate ester compound and related intermediates is provided.

Chavez, David E; Naud, Darren L; Hiskey, Michael A

2013-12-17T23:59:59.000Z

95

PREPARATION OF URANIUM(IV) NITRATE SOLUTIONS  

SciTech Connect

A procedure was developed for the preparation of uranium(IV) nitrate solutions in dilute nitric acid. Zinc metal was used as a reducing agent for uranium(VI) in dilute sulfuric acid. The uranium(IV) was precipitated as the hydrated oxide and dissolved in nitric acid. Uranium(IV) nitrate solutions were prepared at a maximum concentration of 100 g/l. The uranium(VI) content was less than 2% of the uranium(IV). (auth)

Ondrejcin, R.S.

1961-07-01T23:59:59.000Z

96

Synthesis of a new energetic nitrate ester  

DOE Green Energy (OSTI)

Nitrate esters have been known as useful energetic materials since the discovery of nitroglycerin by Ascanio Sobrero in 1846. The development of methods to increase the safety and utility of nitroglycerin by Alfred Nobel led to the revolutionary improvement in the utility of nitroglycerin in explosive applications in the form of dynamite. Since then, many nitrate esters have been prepared and incorporated into military applications such as double-based propellants, detonators and as energetic plasticizers. Nitrate esters have also been shown to have vasodilatory effects in humans and thus have been studied and used for treatments of ailments such as angina. The mechanism of the biological response towards nitrate esters has been elucidated recently. Interestingly, many of the nitrate esters used for military purposes are liquids (ethylene glycol dinitrate, propylene glycol dinitrate, etc). Pentaerythritol tetranitrate (PETN) is one of the only solid nitrate esters, besides nitrocellulose, that is used in any application. Unfortunately, PETN melting point is above 100 {sup o}C, and thus must be pressed as a solid for detonator applications. A more practical material would be a melt-castable explosive, for potential simplification of manufacturing processes. Herein we describe the synthesis of a new energetic nitrate ester (1) that is a solid at ambient temperatures, has a melting point of 85-86 {sup o}C and has the highest density of any known nitrate ester composed only of carbon, hydrogen, nitrogen and oxygen. We also describe the chemical, thermal and sensitivity properties of 1 as well as some preliminary explosive performance data.

Chavez, David E [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

97

Fundamental Properties of Salts  

SciTech Connect

Thermal properties of molten salt systems are of interest to electrorefining operations, pertaining to both the Fuel Cycle Research & Development Program (FCR&D) and Spent Fuel Treatment Mission, currently being pursued by the Department of Energy (DOE). The phase stability of molten salts in an electrorefiner may be adversely impacted by the build-up of fission products in the electrolyte. Potential situations that need to be avoided, during electrorefining operations, include (i) fissile elements build up in the salt that might approach the criticality limits specified for the vessel, (ii) electrolyte freezing at the operating temperature of the electrorefiner due to changes in the liquidus temperature, and (iii) phase separation (non-homogenous solution). The stability (and homogeneity) of the phases can be monitored by studying the thermal characteristics of the molten salts as a function of impurity concentration. Simulated salt compositions consisting of the selected rare earth and alkaline earth chlorides, with a eutectic mixture of LiCl-KCl as the carrier electrolyte, were studied to determine the melting points (thermal characteristics) using a Differential Scanning Calorimeter (DSC). The experimental data were used to model the liquidus temperature. On the basis of the this data, it became possible to predict a spent fuel treatment processing scenario under which electrorefining could no longer be performed as a result of increasing liquidus temperatures of the electrolyte.

Toni Y Gutknecht; Guy L Fredrickson

2012-11-01T23:59:59.000Z

98

Salt Creek Student Homepage  

NLE Websites -- All DOE Office Websites (Extended Search)

Salt Creek Investigation Salt Creek Investigation</2> "Whales Dying in the Pacific Ocean" "Fish Dying in Lake Michigan" Recent headlines remind us of environmental problems near and far away. Scientists have been wondering if these problems could be due to the warmer temperatures this past spring and summer or could there be other reasons? Lack of rain and near drought conditions have forced many areas to restrict water use. We know from past history that pollution affects our drinking water and marine life. Remember what we read about Lake Erie and from reading A River Ran Wild by Lynne Cherry. There are many factors affecting the environment around us . . . even in Salt Creek which runs through our area. We may not be able to investigate the Pacific Ocean and Lake Michigan

99

Gas releases from salt  

Science Conference Proceedings (OSTI)

The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

Ehgartner, B.; Neal, J.; Hinkebein, T.

1998-06-01T23:59:59.000Z

100

RECHARGEABLE MOLTEN-SALT CELLS  

E-Print Network (OSTI)

KC! /FeS 2 cell lithium-silicon magnesium oxide molten-saltmolten-salt cells Na/Na glass/Na:z.Sn-S cell Na/NazO•xA!Symposium on Molten Salts, Physical Electrochemistry

Cairns, Elton J.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Metals removal from spent salts  

DOE Patents (OSTI)

A method and apparatus for removing metal contaminants from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents may be added to precipitate the metal oxide and/or the metal as either metal oxide, metal hydroxide, or as a salt. The precipitated materials are filtered, dried and packaged for disposal as waste or can be immobilized as ceramic pellets. More than about 90% of the metals and mineral residues (ashes) present are removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be spray-dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 1.0 ppm of contaminants.

Hsu, Peter C. (Pleasanton, CA); Von Holtz, Erica H. (Livermore, CA); Hipple, David L. (Livermore, CA); Summers, Leslie J. (Livermore, CA); Brummond, William A. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

2002-01-01T23:59:59.000Z

102

Actinide removal from spent salts  

DOE Patents (OSTI)

A method for removing actinide contaminants (uranium and thorium) from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents are added to precipitate the thorium as thorium oxide and/or the uranium as either uranium oxide or as a diuranate salt. The precipitated materials are filtered, dried and packaged for disposal as radioactive waste. About 90% of the thorium and/or uranium present is removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 0.1 ppm of thorium or uranium.

Hsu, Peter C. (Pleasanton, CA); von Holtz, Erica H. (Livermore, CA); Hipple, David L. (Livermore, CA); Summers, Leslie J. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

2002-01-01T23:59:59.000Z

103

Evaluation of Composite Alumina Nanoparticle and Nitrate Eutectic Materials for use in Concentrating Solar Power Plants  

E-Print Network (OSTI)

The focus of this research was to create and characterize high temperature alumina and nitrate salt eutectic nanofluids for use in thermal energy storage (TES) systems. The nitrate eutectic was originally used in the TES system demonstrated as part of the Solar Two power tower and is currently employed as the TES material at Andasol 1 in Spain. Concentrations of alumina nanoparticles between 0.1% and 10% by weight were introduced into the base material in an effort to create nanofluids which would exhibit improved specific heat capacity to reduce the $/kWht thermal energy storage system costs. The composite materials were created using an aqueous mixing method in which both the nanoparticles and nitrate eutectic were placed into solution using acidic water. This solution was then sonicated in an ultrasonic bath in an effort to reduce nanoparticle agglomeration and to improve homogeneity. After boiling off the excess water, the nanoparticle-nitrate eutectic composite was recovered for characterization. The thermal properties of both the composite and base materials were characterized using the differential scanning calorimetry techniques outlined in ASTM E 1269. The created nanofluids were not stable and did not offer a cost-effective alternative to the current nitrate eutectic TES material. Despite these setbacks, a positive correlation between alumina concentration and nanofluid specific heat was demonstrated. Additionally, the specific heat capacities of the created nanofluids exceeded that predicted by the current theoretical models. These findings suggest that further work in the field of high temperature nanofluids for use in TES systems is warranted.

Malik, Darren R.

2010-05-01T23:59:59.000Z

104

Molten Salt-Carbon Nanotube Thermal Energy Storage for Concentrating Solar Power Systems  

Office of Scientific and Technical Information (OSTI)

Molten Salt-Carbon Nanotube Thermal Energy Storage for Concentrating Solar Power Systems Molten Salt-Carbon Nanotube Thermal Energy Storage for Concentrating Solar Power Systems Final Report March 31, 2012 Michael Schuller, Frank Little, Darren Malik, Matt Betts, Qian Shao, Jun Luo, Wan Zhong, Sandhya Shankar, Ashwin Padmanaban The Space Engineering Research Center Texas Engineering Experiment Station Texas A&M University Abstract We demonstrated that adding nanoparticles to a molten salt would increase its utility as a thermal energy storage medium for a concentrating solar power system. Specifically, we demonstrated that we could increase the specific heat of nitrate and carbonate salts containing 1% or less of alumina nanoparticles. We fabricated the composite materials using both evaporative and air drying methods. We tested several thermophysical properties of the composite materials,

105

The design and testing of a molten salt steam generator for solar application  

SciTech Connect

This paper describes the design and testing of the Steam Generator Subsystem (SGS) for the Molten Salt Electric Experiment at Sandia Laboratories in Albuquerque, New Mexico. The Molten Salt Electric Experiment (MSEE) has been established to demonstrate the feasibility of the molten salt central receiver concept. The experiment is capable of generating 0.75 megawatts of electric power from solar energy, with the capability of storing seven megawatt-hours of thermal energy. The steam generator subsystem transfers sensible heat from the solar-heated molten nitrate salt to produce steam to drive a conventional turbine. This paper discusses the design requirements dictated by the steam generator application and also reviews the process conditions. Details of each of the SGS components are given, featuring the aspects of the design and performance unique to the solar application. The paper concludes with a summary of the test results confirming the overall design of the subsystem.

Allman, W.A.; Smith, D.C.; Kakarala, C.R.

1988-02-01T23:59:59.000Z

106

Freeze-thaw tests of trough receivers employing a molten salt working fluid.  

SciTech Connect

Several studies predict an economic benefit of using nitrate-based salts instead of the current synthetic oil within a solar parabolic trough field. However, the expected economic benefit can only be realized if the reliability and optical performance of the salt trough system is comparable to today's oil trough. Of primary concern is whether a salt-freeze accident and subsequent thaw will lead to damage of the heat collection elements (HCEs). This topic was investigated by experiments and analytical analysis. Results to date suggest that damage will not occur if the HCEs are not completely filled with salt. However, if the HCE is completely filled at the time of the freeze, the subsequent thaw can lead to plastic deformation and significant bending of the absorber tube.

Moss, Timothy A.; Iverson, Brian D.; Siegel, Nathan Phillip; Kolb, Gregory J.; Ho, Clifford Kuofei

2010-05-01T23:59:59.000Z

107

Chemical stability of salt cake in the presence of organic materials. [Detonation hazard  

DOE Green Energy (OSTI)

High-level waste stored as salt cake is principally NaNO/sub 3/. Some organic material is known to have been added to the waste tanks. It has been suggested that some of this organic material may have become nitrated and transformed to a detonable state. Arguments are presented to discount the presence of nitrated organics in the waste tanks. Nitrated organics generated accidentally usually explode at the time of formation. Detonation tests show that salt cake and ''worst-case'' organic mixtures are not detonable. Organic mixtures with salt cake are compared with black powder, a related exothermic reactant. Black-powder mixtures of widely varying composition can and do burn explosively; ignition temperatures are 300-450/sup 0/C. However, black-powder-type mixes cannot be ignited by radiation and are shock-insensitive. Temperatures generated by radionuclide decay in the salt are below 175/sup 0/C and would be incapable of igniting any of these mixtures. The expected effect of radiation on organics in the waste tanks is a slow dehydrogenation and depolymerization along with a slight increase in sensitivity to oxidation. The greatest explosion hazard, if any exists, is a hydrogen--oxygen explosion from water radiolysis, but the hydrogen must first be generated and then trapped so that the concentration of hydrogen can rise above 4 vol percent. This is impossible in salt cake. Final confirmation of the safety against organic-related explosive reactions in the salt cake will be based upon analytical determinations of organic concentrations. 12 tables, 5 fig. (DLC)

Beitel, G.A.

1976-04-01T23:59:59.000Z

108

SEPARATION OF URANYL NITRATE BY EXTRACTION  

DOE Patents (OSTI)

A process is presented for obtaining U/sup 233/ from solutions containing Pa/sup 233/. A carrier precipitate, such as MnO/sub 2/, is formed in such solutions and carries with it the Pa/sup 233/ present. This precipitate is then dissolved in nitric acid and the solution is aged to allow decay of the Pa/ sup 233/ into U/sup 233/. After a sufficient length of time the U/sup 233/ bearing solution is made 2.5 to 4.5 Molar in manganese nitrate by addition thereof, and the solution is then treated with ether to obtain uranyl nitrate by solvent extraction techniques.

Stoughton, R.W.; Steahly, F.L.

1958-08-26T23:59:59.000Z

109

Salt Creek Scenario  

NLE Websites -- All DOE Office Websites (Extended Search)

Scenario Scenario HELP Index Summary Scenario References Student Pages Two branches of Salt Creek run through the city of Rolling Meadows, Illinois, not far from our school. Five members of our team of eighth grade teachers from different subject areas (science, language arts, bilingual education and special education), decided to develop an interdisciplinary study of Salt Creek as a way of giving our students authentic experiences in environmental studies. The unit begins when students enter school in August, running through the third week of September, and resuming for three weeks in October. Extension activities based on using the data gathered at the creek continue throughout the school year, culminating in a presentation at a city council meeting in the spring.

110

Design considerations for concentrating solar power tower systems employing molten salt.  

DOE Green Energy (OSTI)

The Solar Two Project was a United States Department of Energy sponsored project operated from 1996 to 1999 to demonstrate the coupling of a solar power tower with a molten nitrate salt as a heat transfer media and for thermal storage. Over all, the Solar Two Project was very successful; however many operational challenges were encountered. In this work, the major problems encountered in operation of the Solar Two facility were evaluated and alternative technologies identified for use in a future solar power tower operating with a steam Rankine power cycle. Many of the major problems encountered can be addressed with new technologies that were not available a decade ago. These new technologies include better thermal insulation, analytical equipment, pumps and values specifically designed for molten nitrate salts, and gaskets resistant to thermal cycling and advanced equipment designs.

Moore, Robert Charles; Siegel, Nathan Phillip; Kolb, Gregory J.; Vernon, Milton E.; Ho, Clifford Kuofei

2010-09-01T23:59:59.000Z

111

Formation mechanisms and quantification of organic nitrates in atmospheric aerosol  

E-Print Network (OSTI)

limonene-1-nitrate, 1-hydroxy-butane- 2-nitrate, 3-hydroxy-our measured spectra of the butane hydroxynitrate we foundstandards except for the butane hydroxynitrate the O/C based

Rollins, Andrew Waite

2010-01-01T23:59:59.000Z

112

Nitrate Removal in NITREXTM Permeable Reactive Barriers  

E-Print Network (OSTI)

was originally the injection site for our tracer solution, but instead it became our lone up-gradient well) and ~48 hours (low tide) after injection. At every time point, samples were collected from all wells and nitrate concentrations were estimated from samples taken from the injection well right before the solution

Vallino, Joseph J.

113

Formation mechanisms and quantification of organic nitrates in atmospheric aerosol  

E-Print Network (OSTI)

Atmospheric submicron aerosol . . . . . . . 2.3 Partitioningon SOA organic aerosol formation alkyl nitrate and secondaryPeroxy radical fate . . . . . . Aerosol . . . . . . . .

Rollins, Andrew Waite

2010-01-01T23:59:59.000Z

114

FLAME DENITRATION AND REDUCTION OF URANIUM NITRATE TO URANIUM DIOXIDE  

DOE Patents (OSTI)

A process is given for converting uranyl nitrate solution to uranium dioxide. The process comprises spraying fine droplets of aqueous uranyl nitrate solution into a hightemperature hydrocarbon flame, said flame being deficient in oxygen approximately 30%, retaining the feed in the flame for a sufficient length of time to reduce the nitrate to the dioxide, and recovering uranium dioxide. (AEC)

Hedley, W.H.; Roehrs, R.J.; Henderson, C.M.

1962-06-26T23:59:59.000Z

115

Solubilty and growth kinetics of silver nitrate in ethanol  

Science Conference Proceedings (OSTI)

The solubility of silver nitrate in ethanol was determined at various temperatures. The growth kinetics of silver nitrate in ethanol were then determined using initial derivaties of temperature and desupersaturation in a mixed-batch crystallizer. For ... Keywords: ethanol, growth kinetics, initial derivatives, silver nitrate, solubility

M. Manteghian; A. Ebrahimi

2002-08-01T23:59:59.000Z

116

salt lake city.cdr  

Office of Legacy Management (LM)

Locations of the Salt Lake City Processing and Disposal Sites Locations of the Salt Lake City Processing and Disposal Sites This fact sheet provides information about the Uranium Mill Tailings Radiation Control Act of 1978 Title I processing site and disposal site at Salt Lake City, Utah. These sites are managed by the U.S. Department of Energy Office of Legacy Management. Salt Lake City, Utah, Processing and Disposal Sites Site Descriptions and History Regulatory Setting The former Salt Lake City processing site is located about 4 miles south-southwest of the center of Salt Lake City, Utah, at 3300 South and Interstate 15. The Vitro Chemical Company processed uranium and vanadium ore at the site from 1951 until 1968. Milling operations conducted at the processing site created radioactive tailings, a predominantly sandy material.

117

Electrolyte salts for nonaqueous electrolytes  

Science Conference Proceedings (OSTI)

Metal complex salts may be used in lithium ion batteries. Such metal complex salts not only perform as an electrolyte salt in a lithium ion batteries with high solubility and conductivity, but also can act as redox shuttles that provide overcharge protection of individual cells in a battery pack and/or as electrolyte additives to provide other mechanisms to provide overcharge protection to lithium ion batteries. The metal complex salts have at least one aromatic ring. The aromatic moiety may be reversibly oxidized/reduced at a potential slightly higher than the working potential of the positive electrode in the lithium ion battery. The metal complex salts may also be known as overcharge protection salts.

Amine, Khalil; Zhang, Zhengcheng; Chen, Zonghai

2012-10-09T23:59:59.000Z

118

Electrochromic Salts, Solutions, and Devices  

DOE Patents (OSTI)

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

2008-11-11T23:59:59.000Z

119

Electrochromic salts, solutions, and devices  

DOE Patents (OSTI)

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky,7,064,212 T. Mark (Los Alamos, NM)

2006-06-20T23:59:59.000Z

120

Electrochromic Salts, Solutions, and Devices  

DOE Patents (OSTI)

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

2008-10-14T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids  

Science Conference Proceedings (OSTI)

Concentrating solar power (CSP) facilities are comprised of many miles of fluid-filled pipes arranged in large grids with reflective mirrors used to capture radiation from the sun. Solar radiation heats the fluid which is used to produce steam necessary to power large electricity generation turbines. Currently, organic, oil-based fluid in the pipes has a maximum temperature threshold of 400 °C, allowing for the production of electricity at approximately 15 cents per kilowatt hour. The DOE hopes to foster the development of an advanced heat transfer fluid that can operate within higher temperature ranges. The new heat transfer fluid, when used with other advanced technologies, could significantly decrease solar electricity cost. Lower costs would make solar thermal electricity competitive with gas and coal and would offer a clean, renewable source of energy. Molten salts exhibit many desirable heat transfer qualities within the range of the project objectives. Halotechnics developed advanced heat transfer fluids (HTFs) for application in solar thermal power generation. This project focused on complex mixtures of inorganic salts that exhibited a high thermal stability, a low melting point, and other favorable characteristics. A high-throughput combinatorial research and development program was conducted in order to achieve the project objective. Over 19,000 candidate formulations were screened. The workflow developed to screen various chemical systems to discover salt formulations led to mixtures suitable for use as HTFs in both parabolic trough and heliostat CSP plants. Furthermore, salt mixtures which will not interfere with fertilizer based nitrates were discovered. In addition for use in CSP, the discovered salt mixtures can be applied to electricity storage, heat treatment of alloys and other industrial processes.

Raade, Justin; Roark, Thomas; Vaughn, John; Bradshaw, Robert

2013-07-22T23:59:59.000Z

122

Molten Salts, Magnesium and Aluminum  

Science Conference Proceedings (OSTI)

Mar 1, 2011 ... Chloride 2011: Practice and Theory of Chloride-Based Metallurgy: Molten Salts, Magnesium and Aluminum Sponsored by: The Minerals, ...

123

Customer interface document for the Molten Salt Test Loop (MSTL) system.  

DOE Green Energy (OSTI)

The National Solar Thermal Test Facility at Sandia National Laboratories has a unique test capability called the Molten Salt Test Loop (MSTL) system. MSTL is a test capability that allows customers and researchers to test components in flowing, molten nitrate salt. The components tested can range from materials samples, to individual components such as flex hoses, ball joints, and valves, up to full solar collecting systems such as central receiver panels, parabolic troughs, or linear Fresnel systems. MSTL provides realistic conditions similar to a portion of a concentrating solar power facility. The facility currently uses 60/40 nitrate 'solar salt' and can circulate the salt at pressure up to 600psi, temperature to 585 C, and flow rate of 400-600GPM depending on temperature. The purpose of this document is to provide a basis for customers to evaluate the applicability to their testing needs, and to provide an outline of expectations for conducting testing on MSTL. The document can serve as the basis for testing agreements including Work for Others (WFO) and Cooperative Research and Development Agreements (CRADA). While this document provides the basis for these agreements and describes some of the requirements for testing using MSTL and on the site at Sandia, the document is not sufficient by itself as a test agreement. The document, however, does provide customers with a uniform set of information to begin the test planning process.

Pettit, Kathleen; Kolb, William J.; Gill, David Dennis; Briggs, Ronald D.

2012-03-01T23:59:59.000Z

124

GRAPHITE PRODUCTION UTILIZING URANYL NITRATE HEXAHYDRATE CATALYST  

DOE Patents (OSTI)

ABS>The graphitizing of a mixture composed of furfuryl alcohol binder and uranyl nitrate hexahydrate hardener and the subsequent curing, baking, and graphitizing with pressure being initially applied prior to curing are described. The pressure step may be carried out by extrusion, methyl cellulose being added to the mixture before the completion of extrusion. Uranium oxide may be added to the graphitizable mixture prior to the heating and pressure steps. The graphitizable mixture may consist of discrete layers of different compositions. (AEC)

Sheinberg, H.; Armstrong, J.R.; Schell, D.H.

1964-03-10T23:59:59.000Z

125

Developments in Molten Salt and Liquid-Salt-Cooled Reactors  

Science Conference Proceedings (OSTI)

In the last 5 years, there has been a rapid growth in interest in the use of high-temperature (700 to 1000 deg C) molten and liquid fluoride salts as coolants in nuclear systems. This renewed interest is a consequence of new applications for high-temperature heat and the development of new reactor concepts. Fluoride salts have melting points between 350 and 500 deg C; thus, they are of use only in high-temperature systems. Historically, steam cycles with temperature limits of {approx}550 deg C have been the only efficient method to convert heat to electricity. This limitation produced few incentives to develop high-temperature reactors for electricity production. However, recent advances in Brayton gas turbine technology now make it possible to convert higher-temperature heat efficiency into electricity on an industrial scale and thus have created the enabling technology for more efficient nuclear reactors. Simultaneously, there is a growing interest in using high-temperature nuclear heat for the production of hydrogen and shale oil. Five nuclear-related applications are being investigated: (1) liquid-salt heat-transport systems in hydrogen and shale oil production systems; (2) the advanced high-temperature reactor, which uses a graphite-matrix coated-particle fuel and a liquid salt coolant; (3) the liquid-salt-cooled fast reactor which uses metal-clad fuel and a liquid salt coolant; (4) the molten salt reactor, with the fuel dissolved in the molten salt coolant; and (5) fusion energy systems. The reasons for the new interest in liquid salt coolants, the reactor concepts, and the relevant programs are described. (author)

Forsberg, Charles W. [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831-6165 (United States)

2006-07-01T23:59:59.000Z

126

Extracting information from the molten salt database  

Science Conference Proceedings (OSTI)

Molten salt technology is a catchall phrase that includes some very diverse ... nologies are linked by the general characteristics of molten salts that can function

127

A nightly conditioning method to reduce parasitic power consumption in molten-salt central-receiver solar-power plants  

DOE Green Energy (OSTI)

A method to reduce nightly parasitic power consumption in a molten salt central receiver is discussed where salt is drained from the piping and heat tracing is turned off to allow the piping to cool to ambient overnight, then in the morning the pipes are filled while they are cold. Since the piping and areas of the receiver in a molten-nitrate salt central-receiver solar power plant must be electrically heated to maintain their temperatures above the nitrate salt freezing point (430{degrees}F, 221{degrees}C), considerable energy could be used to maintain such temperatures during nightly shut down and bad weather. Experiments and analyses have been conducted to investigate cold filling receiver panels and piping as a way of reducing parasitic electrical power consumption and increasing the availability of the plant. The two major concerns with cold filling are: (1) how far can the molten salt penetrate cold piping before freezing closed and (2) what thermal stresses develop during the associated thermal shock. Experiments and analysis are discussed.

Pacheco, J.E.

1995-06-01T23:59:59.000Z

128

Solar two: A molten salt power tower demonstration  

Science Conference Proceedings (OSTI)

A consortium of United States utility concerns led by the Southern California Edison Company (SCE) is conducting a cooperative project with the US Department of Energy (DOE), Sandia National Laboratories, and industry to convert the 10-MW Solar One Power Tower Pilot Plant to molten nitrate salt technology. The conversion involves installation of a new receiver, a new thermal storage system, and a new steam generator; it utilizes Solar One`s heliostat field and turbine generator. Successful operation of the converted plant, called Solar Two, will reduce economic risks in building initial commercial power tow projects and accelerate the commercial acceptance of this promising renewable energy technology. The estimated cost of Solar Two, including its three-year test period, is $48.5 million. The plant will begin operation in early 1996.

Tyner, C.E. [Sandia National Labs., Albuquerque, NM (United States); Sutherland, J.P. [Southern California Edison, Rosemead, CA (United States); Gould, W.R. Jr. [Bechtel Corp., San Francisco, CA (United States)

1995-08-01T23:59:59.000Z

129

Production and Handling Slide 15: Yellow Cake, Uranyl Nitrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents Yellow Cake, Uranyl Nitrate, ADU, UO2 Refer to caption below for image...

130

Aluminum nitrate recrystallization and recovery from liquid extraction raffinates  

SciTech Connect

The solid sludges resulting form biodenitrification of discarded aluminum nitrate are the largest Y-12 Plant process solid waste. Aluminum nitrate feedstocks also represent a major plant materials cost. The chemical constraints on aluminum nitrate recycle were investigated to determine the feasibility of increasing recycle while maintaining acceptable aluminum nitrate purity. Reported phase behavior of analogous systems, together with bench research, indicated that it would be possible to raise the recycle rate from 35% to between 70 and 90% by successive concentration and recrystallization of the mother liquor. A full scale pilot test successfully confirmed the ability to obtain 70% recycle in existing process equipment.

Griffith, W.L.; Compere, A.L.; Googin, J.M.; Huxtable, W.P.

1991-09-01T23:59:59.000Z

131

Production and Handling Slide 13: Yellow Cake, Uranyl Nitrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

ADU Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents Yellow Cake, Uranyl Nitrate, ADU Refer to caption below for image...

132

Electrochemical processing of nitrate waste solutions  

SciTech Connect

The second phase of research performed at The Electrosynthesis Co., Inc. has demonstrated the successful removal of nitrite and nitrate from a synthetic effluent stream via a direct electrochemical reduction at a cathode. It was shown that direct reduction occurs at good current efficiencies in 1,000 hour studies. The membrane separation process is not readily achievable for the removal of nitrites and nitrates due to poor current efficiencies and membrane stability problems. A direct reduction process was studied at various cathode materials in a flow cell using the complete synthetic mix. Lead was found to be the cathode material of choice, displaying good current efficiencies and stability in short and long term tests under conditions of high temperature and high current density. Several anode materials were studied in both undivided and divided cell configurations. A divided cell configuration was preferable because it would prevent re-oxidation of nitrite by the anode. The technical objective of eliminating electrode fouling and solids formation was achieved although anode materials which had demonstrated good stability in short term divided cell tests corroded in 1,000 hour experiments. The cause for corrosion is thought to be F[sup [minus

Genders, D.; Weinberg, N.; Hartsough, D. (Electrosynthesis Co., Inc., Cheektowaga, NY (United States))

1992-10-07T23:59:59.000Z

133

Molten salt thermal energy storage systems: salt selection  

DOE Green Energy (OSTI)

A research program aimed at the development of a molten salt thermal energy storage system commenced in June 1976. This topical report describes Work performed under Task I: Salt Selection is described. A total of 31 inorganic salts and salt mixtures, including 9 alkali and alkaline earth carbonate mixtures, were evaluated for their suitability as heat-of-fusion thermal energy storage materials at temperatures of 850 to 1000/sup 0/F. Thermophysical properties, safety hazards, corrosion, and cost of these salts were compared on a common basis. We concluded that because alkali carbonate mixtures show high thermal conductivity, low volumetric expansion on melting, low corrosivity and good stability, they are attractive as heat-of-fusion storage materials in this temperature range. A 35 wt percent Li/sub 2/CO/sub 3/-65 wt percent K/sub 2/CO/sub 3/ (50 mole percent Li/sub 2/CO/sub 3/-50 mole percent K/sub 2/CO/sub 3/) mixture was selected as a model system for further experimental work. This is a eutectoid mixture having a heat of fusion of 148 Btu/lb (82 cal/g) that forms an equimolar compound, LiKCO/sub 3/. The Li/sub 2/CO/sub 3/-K/sub 2/CO/sub 3/ mixture is intended to serve as a model system to define heat transfer characteristics, potential problems, and to provide ''first-cut'' engineering data required for the prototype system. The cost of a thermal energy storage system containing this mixture cannot be predicted until system characteristics are better defined. However, our comparison of different salts indicated that alkali and alkaline earth chlorides may be more attractive from a salt cost point of view. The long-term corrosion characteristics and the effects of volume change on melting for the chlorides should be investigated to determine their overall suitability as a heat-of-fusion storage medium.

Maru, H.C.; Dullea, J.F.; Huang, V.S.

1976-08-01T23:59:59.000Z

134

Method for improved decomposition of metal nitrate solutions  

DOE Patents (OSTI)

A method for co-conversion of aqueous solutions of one or more heavy metal nitrates wherein thermal decomposition within a temperature range of about 300.degree. to 800.degree. C. is carried out in the presence of about 50 to 500% molar concentration of ammonium nitrate to total metal.

Haas, Paul A. (Knoxville, TN); Stines, William B. (Knoxville, TN)

1983-10-11T23:59:59.000Z

135

Nitrate-Cancrinite Precipitation on Quartz Sand in Simulated Hanford  

E-Print Network (OSTI)

Nitrate-Cancrinite Precipitation on Quartz Sand in Simulated Hanford Tank Solutions B A R R Y R . B minerals at the U.S. Department of Energy's Hanford site in Washington. Nitrate-cancrinite began's (DOE) Hanford Site in southeast Washington since the late 1950s (1). To predict the fate

Illinois at Chicago, University of

136

Method for improved decomposition of metal nitrate solutions  

DOE Patents (OSTI)

A method for co-conversion of aqueous solutions of one or more heavy metal nitrates is described, wherein thermal decomposition within a temperature range of about 300 to 800/sup 0/C is carried out in the presence of about 50 to 500% molar concentration of ammonium nitrate to total metal.

Haas, P.A.; Stines, W.B.

1981-01-21T23:59:59.000Z

137

Survey of technology for storage of thermal energy in heat transfer salt  

DOE Green Energy (OSTI)

The widespread use of nitrate-based fused salt mixtures as heat transport media in the petroleum and chemical process industries and in metallurgical heat-treatment operations has led to the development of satisfactory equipment for handling and containing these materials. A mixture known as heat transfer salt (HTS), which is composed of 40 percent NaNO/sub 2/, 7 percent NaNO/sub 3/, and 53 percent KNO/sub 3/ by weight, has been used commercially in large quantities as a heat transfer fluid. It has been suggested that this salt be used for storing energy as sensible heat in the temperature range 200 to 540/sup 0/C (400 to 1000/sup 0/F). The eutectic 54 percent KNO/sub 3/--46 percent NaNO/sub 3/ by weight known as ''draw salt,'' which has undergone less testing but is more stable thermally and more attractive economically than HTS and has similar physical properties, may be a desirable alternative. Several specific energy storage applications, such as intermediate-load and peaking electric power, solar energy, and energy from fluidized-bed coal burners, are discussed. Long-term stability and corrosion data on these salts are presently available only to approximately 480/sup 0/C. However, for the design and construction of energy storage facilities to operate over many years at temperatures up to approximately 540/sup 0/C, long-term tests of thermal stability and corrosion are needed. Means for obtaining such information are proposed.

Silverman, M.D.; Engel, J.R.

1977-01-18T23:59:59.000Z

138

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect

The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of low-activity waste immobilization. Principles of ion recognition are being researched toward discovery of liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudohydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Studies at PNNL are directed toward new solvent formulation for the practical sodium pseudohydroxide extraction systems.

Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.; Bonnesen, Peter V.

2006-06-01T23:59:59.000Z

139

Freshwater fish in salt water  

NLE Websites -- All DOE Office Websites (Extended Search)

Freshwater fish in salt water Freshwater fish in salt water Name: Shannon Location: N/A Country: N/A Date: N/A Question: What would actually happen if a fresh water fish had to live in salt water? Replies: For most fish, they would die. But some, like eels and salmon, can move freely between the two at certain stages of their lives. To do this they have special mechanisms of excretion and absorption of salt and water. --ProfBill If you put a freshwater fish into saltwater, most fish would lose weight (from losing water from its body) and eventually die. Approximately 2% of all 21000 species of fish actually move from freshwater to saltwater or from salt to fresh at some point in their lives, the move would kill any other fish. But even with these special varieties of fish, the move must be gradual so their bodies can adjust, or they too, will die from the change. If you want to learn more about why the freshwater fish will lose water, (or why a saltwater fish in freshwater would gain water), look up the words "diffusion" and "osmosis"

140

Fracture and Healing of Rock Salt Related to Salt Caverns  

Science Conference Proceedings (OSTI)

In recent years, serious investigations of potential extension of the useful life of older caverns or of the use of abandoned caverns for waste disposal have been of interest to the technical community. All of the potential applications depend upon understanding the reamer in which older caverns and sealing systems can fail. Such an understanding will require a more detailed knowledge of the fracture of salt than has been necessary to date. Fortunately, the knowledge of the fracture and healing of salt has made significant advances in the last decade, and is in a position to yield meaningful insights to older cavern behavior. In particular, micromechanical mechanisms of fracture and the concept of a fracture mechanism map have been essential guides, as has the utilization of continuum damage mechanics. The Multimechanism Deformation Coupled Fracture (MDCF) model, which is summarized extensively in this work was developed specifically to treat both the creep and fracture of salt, and was later extended to incorporate the fracture healing process known to occur in rock salt. Fracture in salt is based on the formation and evolution of microfractures, which may take the form of wing tip cracks, either in the body or the boundary of the grain. This type of crack deforms under shear to produce a strain, and furthermore, the opening of the wing cracks produce volume strain or dilatancy. In the presence of a confining pressure, microcrack formation may be suppressed, as is often the case for triaxial compression tests or natural underground stress situations. However, if the confining pressure is insufficient to suppress fracture, then the fractures will evolve with time to give the characteristic tertiary creep response. Two first order kinetics processes, closure of cracks and healing of cracks, control the healing process. Significantly, volume strain produced by microfractures may lead to changes in the permeability of the salt, which can become a major concern in cavern sealing and operation. The MDCF model is used in three simulations of field experiments in which indirect measures were obtained of the generation of damage. The results of the simulations help to verify the model and suggest that the model captures the correct fracture behavior of rock salt. The model is used in this work to estimate the generation and location of damage around a cylindrical storage cavern. The results are interesting because stress conditions around the cylindrical cavern do not lead to large amounts of damage. Moreover, the damage is such that general failure can not readily occur, nor does the extent of the damage suggest possible increased permeation when the surrounding salt is impermeable.

Chan, K.S.; Fossum, A.F.; Munson, D.E.

1999-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Why Sequence Great Salt Lake?  

NLE Websites -- All DOE Office Websites (Extended Search)

Great Salt Lake? Great Salt Lake? On average, the Great Salt Lake is four times saltier than the ocean and also has heavy metals, high concentrations of sulfur and petroleum seeps. In spite of all this, the lake is the saltiest body of water to support life. The lake hosts brine shrimp, algae and a diverse array of microbes, not to mention the roughly 5 million birds that migrate there annually. The secret to these microbes' ability to survive under such harsh conditions might be revealed in their genes. Researchers expect the genetic data will provide insight into how the microorganisms tolerate pollutants such as sulfur and detoxify pollutants such as sulfur and heavy metals like mercury. The information could then be used to develop bioremediation techniques. Researchers also expect that sequencing microorganisms sampled

142

Salt Lake Community College | .EDUconnections  

NLE Websites -- All DOE Office Websites (Extended Search)

SLCC Partners with DOE's Rocky Mountain Solar Training Program This program is a joint partnership between DOE's Solar Energy Technogies Program, Salt Lake Community College, Solar Energy International, and the Utah Solar Energy Association that works to accelerate use of solar electric technologies, training and facilities at community and technical college solar training programs within a 15 western United States region. DOE Solar Instructor Training Network Salt Lake City, Utah DOE Applauds SLCC's Science and Technical Programs Architectural Technology Biology Biotechnology Biomanufacturing Chemistry Computer Science Electric Sector Training Energy Management Engineering Geographic Information Sciences Geosciences InnovaBio Manufacturing & Mechanical Engineering Technology

143

Closure of the condensed-phase organic-nitrate reaction USQ at hanford  

Science Conference Proceedings (OSTI)

A discovery Unreviewed Safety Question (USQ) was declared on the underground waste storage tanks at the Hanford Site in May 1996. The USQ was for condensed-phase organic-nitrate reactions (sometimes called organic complexant reactions) in the tanks. This paper outlines the steps taken to close the USQ, and resolve the related safety issue. Several processes were used at the Hanford Site to extract and/or process plutonium. These processes resulted in organic complexants (for chelating multivalent cations) and organic extraction solvents being sent to the underground waste storage tanks. This paper addresses the organic complexant hazard. The organic complexants are in waste matrices that include inert material, diluents, and potential oxidizers. In the presence of oxidizing material, the complexant salts can be made to react exothermically by heating to high temperatures or by applying an external ignition source of sufficient energy. The first organic complexant hazard assessments focused on determining whether a hulk runaway reaction could occur, similar to the 1957 accident at Kyshtm (a reprocessing plant in the former U.S.S.R.). Early analyses (1977 through 1994) examined organic-nitrate reaction onset temperatures and concluded that a bulk runaway reaction could not occur at the Hanford Site because tank temperatures were well below that necessary for bulk runaway. Therefore, it was believed that organic-nitrate reactions were adequately described in the then current Authorization Basis (AB). Subsequent studies examined a different accident scenario, propagation resulting from an external ignition source (e.g., lightning or welding slag) that initiates a combustion front that propagates through the organic waste. A USQ evaluation determined that localized high energy ignition sources were credible, and that point source ignition of organic complexant waste was not adequately addressed i n the then existing AB. Consequently, the USQ was declared on the underground storage tanks in May 1996 for condensed-phase organic-nitrate reactions. At the same time that the operating contractor recommended that the U. S. Department of Energy (DOE) declare a USQ. preventative coiitrols were implemented to minimize potential ignition sources and prevent a possible accident.

COWLEY, W.L.

1999-06-24T23:59:59.000Z

144

Production of chlorine from chloride salts  

DOE Patents (OSTI)

A process for converting chloride salts and sulfuric acid to sulfate salts and elemental chlorine is disclosed. A chloride salt and sulfuric acid are combined in a furnace where they react to produce a sulfate salt and hydrogen chloride. Hydrogen chloride from the furnace contacts a molten salt mixture containing an oxygen compound of vanadium, an alkali metal sulfate and an alkali metal pyrosulfate to recover elemental chlorine. In the absence of an oxygen-bearing gas during the contacting, the vanadium is reduced, but is regenerated to its active higher valence state by separately contacting the molten salt mixture with an oxygen-bearing gas.

Rohrmann, Charles A. (Kennewick, WA)

1981-01-01T23:59:59.000Z

145

Cathode for molten salt batteries  

DOE Patents (OSTI)

A molten salt electrochemical system for battery applications comprises tetravalent sulfur as the active cathode material with a molten chloroaluminate solvent comprising a mixture of AlCl.sub.3 and MCl having a molar ratio of AlCl.sub.3 /MCl from greater than 50.0/50.0 to 80/20.

Mamantov, Gleb (Knoxville, TN); Marassi, Roberto (Camerino, IT)

1977-01-01T23:59:59.000Z

146

Cleanup of plutonium oxide reduction black salts  

Science Conference Proceedings (OSTI)

This work describes pyrochemical processes employed to convert direc oxide reduction (DOR) black salts into discardable white salt and plutonium metal. The DOR process utilizes calcium metal as the reductant in a molten calcium chloride solvent salt to convert plutonium oxide to plutonium metal. An insoluble plutonium-rich dispersion called black salt sometimes forms between the metal phase and the salt phase. Black salts accumulated for processing were treated by one of two methods. One method utilized a scrub alloy of 70 wt % magnesium/30 wt % zinc. The other method utilized a pool of plutonium metal to agglomerate the metal phase. The two processes were similar in that calcium metal reductant and calcium chloride solvent salt were used in both cases. Four runs were performed by each method, and each method produced greater than 93% conversion of the black salt.

Giebel, R.E.; Wing, R.O.

1986-12-17T23:59:59.000Z

147

Dysprosium Extraction Using Molten Salt Electrolysis Process  

Science Conference Proceedings (OSTI)

AlCl3 was used as a chlorinating agent in order to enable an efficient dissolution of metal in the molten salt phase in the salt bath. The metal chloride which is ...

148

Decontamination of water using nitrate selective ion exchange resin  

DOE Patents (OSTI)

A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C[sub 3] or larger.

Lockridge, J.E.; Fritz, J.S.

1990-07-31T23:59:59.000Z

149

Production and Handling Slide 17: Yellow Cake, Uranyl Nitrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

, UF4 Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents Yellow Cake, Uranyl Nitrate, ADU, UO2, UF4 Refer to caption below for...

150

Decontamination of water using nitrate selective ion exchange resin  

DOE Patents (OSTI)

A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C.sub.3 or larger.

Lockridge, James E. (Ames, IA); Fritz, James S. (Ames, IA)

1990-07-31T23:59:59.000Z

151

Effects of 2-Ethylhexyl Nitrate on Diesel-Spray Processes  

DOE Green Energy (OSTI)

Diesel fuel ignition-enhancing additives, such as 2-ethylhexyl nitrate, are known to reduce emissions from diesel engines; however, the mechanisms by which the emissions reduction occur are not understood. This report covers the first phase of a research project supported by Ethyl Corporation that is aimed at developing a detailed understanding of how 2-ethylhexyl nitrate alters in-cylinder injection, ignition, and combustion processes to reduce diesel engine emissions.

Higgins, B.; Mueller, C.; Siebers, D.

1998-08-01T23:59:59.000Z

152

Molten Salt-Carbon Nanotube Thermal Energy Storage for Concentrating Solar Power Systems Final Report  

DOE Green Energy (OSTI)

We demonstrated that adding nanoparticles to a molten salt would increase its utility as a thermal energy storage medium for a concentrating solar power system. Specifically, we demonstrated that we could increase the specific heat of nitrate and carbonate salts containing 1% or less of alumina nanoparticles. We fabricated the composite materials using both evaporative and air drying methods. We tested several thermophysical properties of the composite materials, including the specific heat, thermal conductivity, latent heat, and melting point. We also assessed the stability of the composite material with repeated thermal cycling and the effects of adding the nanoparticles on the corrosion of stainless steel by the composite salt. Our results indicate that stable, repeatable 25-50% improvements in specific heat are possible for these materials. We found that using these composite salts as the thermal energy storage material for a concentrating solar thermal power system can reduce the levelized cost of electricity by 10-20%. We conclude that these materials are worth further development and inclusion in future concentrating solar power systems.

Michael Schuller; Frank Little; Darren Malik; Matt Betts; Qian Shao; Jun Luo; Wan Zhong; Sandhya Shankar; Ashwin Padmanaban

2012-03-30T23:59:59.000Z

153

Waste Isolation Pilot Plant's Excavated Salt Agreement Supports...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Plant's Excavated Salt Agreement Supports Conservation Education, Other Public Initiatives Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Conservation Education,...

154

Benchmark Evaluation of Plutonium Nitrate Solution Arrays  

Science Conference Proceedings (OSTI)

In October and November of 1981 thirteen approach-to-critical experiments were performed on a remote split table machine (RSTM) in the Critical Mass Laboratory of Pacific Northwest Laboratory (PNL) in Richland, Washington, using planar arrays of polyethylene bottles filled with plutonium (Pu) nitrate solution. Arrays of up to sixteen bottles were used to measure the critical number of bottles and critical array spacing with a tight fitting Plexiglas{reg_sign} reflector on all sides of the arrays except the top. Some experiments used Plexiglas shells fitted around each bottles to determine the effect of moderation on criticality. Each bottle contained approximately 2.4 L of Pu(NO3)4 solution with a Pu content of 105 g Pu/L and a free acid molarity H+ of 5.1. The plutonium was of low 240Pu (2.9 wt.%) content. These experiments were performed to fill a gap in experimental data regarding criticality limits for storing and handling arrays of Pu solution in reprocessing facilities. Of the thirteen approach-to-critical experiments eleven resulted in extrapolations to critical configurations. Four of the approaches were extrapolated to the critical number of bottles; these were not evaluated further due to the large uncertainty associated with the modeling of a fraction of a bottle. The remaining seven approaches were extrapolated to critical array spacing of 3-4 and 4-4 arrays; these seven critical configurations were evaluation for inclusion as acceptable benchmark experiments in the International Criticality Safety Benchmark Evaluation Project (ICSBEP) Handbook. Detailed and simple models of these configurations were created and the associated bias of these simplifications was determined to range from 0.00116 and 0.00162 {+-} 0.00006 ?keff. Monte Carlo analysis of all models was completed using MCNP5 with ENDF/BVII.0 neutron cross section libraries. A thorough uncertainty analysis of all critical, geometric, and material parameters was performed using parameter perturbation methods. It was found that uncertainty in the impurities in the polyethylene bottles, reflector position, bottle outer diameter, and critical array spacing had the largest effect. The total uncertainty ranged from 0.00651 to 0.00920 ?keff. Evaluation methods and results will be presented and discussed in greater detail in the full paper.

M. A. Marshall; J. D. Bess

2011-09-01T23:59:59.000Z

155

Heat transfer and pressure drop measurements in an air/molten salt direct-contact heat exchanger  

SciTech Connect

This paper presents a comparison of experimental data with a recently published model of heat exchange in irrigated packed beds. Heat transfer and pressure drop were measured in a 150 mm (ID) column with a 610-mm bed of metal Pall rings. Molten nitrate salt and preheated air were the working fluids with a salt inlet temperature of approximately 440{degree}C and air inlet temperatures of approximately 230{degree}C. A comparison between the experimental data and the heat transfer model is made on the basis of heat transfer from the salt. For the range of air and salt flow rates tested, 0.3 to 1.2 kg/m{sup 2} s air flow and 6 to 18 kg/m{sup 2} s salt flow, the data agree with the model within 22% standard deviation. In addition, a model for the column pressure drop was validated, agreeing with the experimental data within 18% standard deviation over the range of column pressure drop from 40 to 1250 Pa/m. 25 refs., 7 figs., 2 tabs.

Bohn, M.S.

1988-11-01T23:59:59.000Z

156

The Salt Defense Disposal Investigations (SDDI)  

NLE Websites -- All DOE Office Websites (Extended Search)

Salt Defense Disposal Investigations (SDDI) Salt Defense Disposal Investigations (SDDI) will utilize a newly mined Underground Research Lab (URL) in WIPP to perform a cost effective, proof-of-principle field test of the emplacement of heat-generating radioactive waste and validate modeling efforts. The goals of the SDDI Thermal Test are to: * Demonstrate a proof-of-principle concept for in-drift disposal in salt. * Investigate, in a specific emplacement concept, the response of the salt to heat. * Develop a full-scale response for run-of- mine (ROM) salt. * Develop a validated coupled process model for disposal of heat-generating wastes in salt. * Evaluate the environmental conditions of the

157

Nitrate Anion Exchange in Pu-238 Aqueous Scrap Recovery Operations  

SciTech Connect

Strong base, nitrate anion exchange (IX) is crucial to the purification of {sup 238}Pu solution feedstocks with gross levels of impurities. This paper discusses the work involved in bench scale experiments to optimize the nitrate anion exchange process. In particular, results are presented of experiments conducted to (a) demonstrate that high levels of impurities can be separated from {sup 238}Pu solutions via nitrate anion exchange and, (b) work out chemical pretreatment methodology to adjust and maintain {sup 238}Pu in the IV oxidation state to optimize the Pu(IV)-hexanitrato anionic complex sorption to Reillex-HPQ resin. Additional experiments performed to determine the best chemical treatment methodology to enhance recovery of sorbed Pu from the resin, and VIS-NIR absorption studies to determine the steady state equilibrium of Pu(IV), Pu(III), and Pu(VI) in nitric acid are discussed.

Pansoy-Hjelvik, M.E.; Silver, G.L.; Reimus, M.A.H.; Ramsey, K.B.

1999-01-31T23:59:59.000Z

158

Thorium Nitrate Stockpile--From Here to Eternity  

Science Conference Proceedings (OSTI)

The Defense National Stockpile Center (DNSC), a field level activity of the Defense Logistics Agency (DLA) has stewardship of a stockpile of thorium nitrate that has been in storage for decades. The stockpile is made up of approximately 3.2 million kg (7 million lb) of thorium nitrate crystals (hydrate form) stored at two depot locations in the United States. DNSC sought technical assistance from Oak Ridge National Laboratory (ORNL) to define and quantify the management options for the thorium nitrate stockpile. This paper describes methodologies and results comprising the work in Phase 1 and Phase 2. The results allow the DNSC to structure and schedule needed tasks to ensure continued safe long-term storage and/or phased disposal of the stockpile.

Hermes, W. H.; Hylton, T. D.; Mattus, C.H.; Storch, S. N.; Singley, P.S.; Terry. J. W.; Pecullan, M.; Reilly, F. K.

2003-02-26T23:59:59.000Z

159

Thermophysical Properties of Sodium Nitrate and Sodium Chloride  

Office of Scientific and Technical Information (OSTI)

Thermophysical Properties of Sodium Nitrate and Sodium Chloride Thermophysical Properties of Sodium Nitrate and Sodium Chloride Solutions and Their Effects on Fluid Flow in Unsaturated Media Tianfu Xu and Karsten Pruess Earth Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 ABSTRACT. Understanding movement of saline sodium nitrate (NaNO 3 ) waste solutions is important for assessing the contaminant migration near leaking waste storage tanks in the unsaturated zone at the Hanford site (Washington, USA). The purpose of this study is to contribute a basic understanding of effects of the thermophysical behavior of NaNO 3 solutions on fluid flow in unsaturated media. We first present mathematical expressions for the dependence of density, viscosity, solubility and vapor pressure of

160

Electrolytic orthoborate salts for lithium batteries  

DOE Patents (OSTI)

Orthoborate salts suitable for use as electrolytes in lithium batteries and methods for making the electrolyte salts are provided. The electrolytic salts have one of the formulae (I). In this formula anionic orthoborate groups are capped with two bidentate chelating groups, Y1 and Y2. Certain preferred chelating groups are dibasic acid residues, most preferably oxalyl, malonyl and succinyl, disulfonic acid residues, sulfoacetic acid residues and halo-substituted alkylenes. The salts are soluble in non-aqueous solvents and polymeric gels and are useful components of lithium batteries in electrochemical devices.

Angell, Charles Austen (Mesa, AZ); Xu, Wu (Tempe, AZ)

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Multiphase Flow and Cavern Abandonment in Salt  

Science Conference Proceedings (OSTI)

This report will explore the hypothesis that an underground cavity in gassy salt will eventually be gas filled as is observed on a small scale in some naturally occurring salt inclusions. First, a summary is presented on what is known about gas occurrences, flow mechanisms, and cavern behavior after abandonment. Then, background information is synthesized into theory on how gas can fill a cavern and simultaneously displace cavern fluids into the surrounding salt. Lastly, two-phase (gas and brine) flow visualization experiments are presented that demonstrate some of the associated flow mechanisms and support the theory and hypothesis that a cavity in salt can become gas filled after plugging and abandonment

Ehgartner, Brian; Tidwell, Vince

2001-02-13T23:59:59.000Z

162

Results of Salt Batch Qualification Testing  

• Reviews the past campaigns of salt disposition (Macrobatch 1 and 2). ... • Macrobatch 2 processed a total volume of 730,000 gallons from February ...

163

Applications of molten salts in plutonium processing  

Science Conference Proceedings (OSTI)

Plutonium is efficiently recovered from scrap at Los Alamos by a series of chemical reactions and separations conducted at temperatures ranging from 700 to 900/sup 0/C. These processes usually employ a molten salt or salt eutectic as a heat sink and/or reaction medium. Salts for these operations were selected early in the development cycle. The selection criteria are being reevaluated. In this article we describe the processes now in use at Los Alamos and our studies of alternate salts and eutectics.

Bowersox, D.F.; Christensen, D.C.; Williams, J.D.

1987-01-01T23:59:59.000Z

164

,"Natural Gas Salt Caverns Storage Capacity "  

U.S. Energy Information Administration (EIA) Indexed Site

Salt Caverns Storage Capacity " ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Natural Gas...

165

Metal salts of alkyl catechol dithiophosphoric acids and oil compositions containing the salts  

Science Conference Proceedings (OSTI)

Metal salts of alkyl catechol esters of dithiophosphoric acid suitable as additives in oil compositions are disclosed in this patent. Oil compositions containing the salts of such esters show improved extreme pressure/anti-wear and anit-oxidant properties.

Yamaguchi, E.S.; Liston, T.V.

1988-03-08T23:59:59.000Z

166

Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity  

SciTech Connect

The synthesis and structural features of a newly emerged class of salt-inclusion solids (SISs) are reviewed. The descriptive chemistry with respect to the role of ionic salt and its correlation with bulk noncentrosymmetricity and polarity of the covalent oxide lattice in question is discussed by means of structure analysis. These unprecedented discoveries have opened doors to novel materials synthesis via the utilities of salt-inclusion chemistry (SIC) that are otherwise known as the molten-salt approach. The result of these investigations prove that the bulk acentricity, or cancellation of which, can be accounted for from the perspective of ionic and/or salt lattices. Highlights: Black-Right-Pointing-Pointer Synthesis and structure of newly emerged salt-inclusion solids are reviewed. Black-Right-Pointing-Pointer Salt lattice and its symmetry correlation with polar framework are discussed. Black-Right-Pointing-Pointer Preservation of acentricity is accounted for from the perspective of ionic and salt lattices.

West, J. Palmer [Department of Chemistry, Clemson University, Clemson, SC 29634-0973 (United States)] [Department of Chemistry, Clemson University, Clemson, SC 29634-0973 (United States); Hwu, Shiou-Jyh, E-mail: shwu@clemson.edu [Department of Chemistry, Clemson University, Clemson, SC 29634-0973 (United States)] [Department of Chemistry, Clemson University, Clemson, SC 29634-0973 (United States)

2012-11-15T23:59:59.000Z

167

Drilling Waste Management Fact Sheet: Disposal in Salt Caverns  

NLE Websites -- All DOE Office Websites (Extended Search)

Salt Caverns Salt Caverns Fact Sheet - Disposal in Salt Caverns Introduction to Salt Caverns Underground salt deposits are found in the continental United States and worldwide. Salt domes are large, fingerlike projections of nearly pure salt that have risen to near the surface. Bedded salt formations typically contain multiple layers of salt separated by layers of other rocks. Salt beds occur at depths of 500 to more than 6,000 feet below the surface. Schematic Drawing click to view larger image Schematic Drawing of a Cavern in Domal Salt Schematic Drawing click to view larger image Schematic Drawing of a Cavern in Bedded Salt Salt caverns used for oil field waste disposal are created by a process called solution mining. Well drilling equipment is used to drill a hole

168

Testing thermocline filler materials and molten-salt heat transfer fluids for thermal energy storage systems used in parabolic trough solar power plants.  

DOE Green Energy (OSTI)

Parabolic trough power systems that utilize concentrated solar energy to generate electricity are a proven technology. Industry and laboratory research efforts are now focusing on integration of thermal energy storage as a viable means to enhance dispatchability of concentrated solar energy. One option to significantly reduce costs is to use thermocline storage systems, low-cost filler materials as the primary thermal storage medium, and molten nitrate salts as the direct heat transfer fluid. Prior thermocline evaluations and thermal cycling tests at the Sandia National Laboratories' National Solar Thermal Test Facility identified quartzite rock and silica sand as potential filler materials. An expanded series of isothermal and thermal cycling experiments were planned and implemented to extend those studies in order to demonstrate the durability of these filler materials in molten nitrate salts over a range of operating temperatures for extended timeframes. Upon test completion, careful analyses of filler material samples, as well as the molten salt, were conducted to assess long-term durability and degradation mechanisms in these test conditions. Analysis results demonstrate that the quartzite rock and silica sand appear able to withstand the molten salt environment quite well. No significant deterioration that would impact the performance or operability of a thermocline thermal energy storage system was evident. Therefore, additional studies of the thermocline concept can continue armed with confidence that appropriate filler materials have been identified for the intended application.

Kelly, Michael James; Hlava, Paul Frank; Brosseau, Douglas A.

2004-07-01T23:59:59.000Z

169

Molten Salt Power Tower Cost Model for the System Advisor Model (SAM)  

DOE Green Energy (OSTI)

This report describes a component-based cost model developed for molten-salt power tower solar power plants. The cost model was developed by the National Renewable Energy Laboratory (NREL), using data from several prior studies, including a contracted analysis from WorleyParsons Group, which is included herein as an Appendix. The WorleyParsons' analysis also estimated material composition and mass for the plant to facilitate a life cycle analysis of the molten salt power tower technology. Details of the life cycle assessment have been published elsewhere. The cost model provides a reference plant that interfaces with NREL's System Advisor Model or SAM. The reference plant assumes a nominal 100-MWe (net) power tower running with a nitrate salt heat transfer fluid (HTF). Thermal energy storage is provided by direct storage of the HTF in a two-tank system. The design assumes dry-cooling. The model includes a spreadsheet that interfaces with SAM via the Excel Exchange option in SAM. The spreadsheet allows users to estimate the costs of different-size plants and to take into account changes in commodity prices. This report and the accompanying Excel spreadsheet can be downloaded at https://sam.nrel.gov/cost.

Turchi, C. S.; Heath, G. A.

2013-02-01T23:59:59.000Z

170

Metal salt catalysts for enhancing hydrogen spillover  

DOE Patents (OSTI)

A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

Yang, Ralph T; Wang, Yuhe

2013-04-23T23:59:59.000Z

171

Embedded Network Sensing of Moisture and Nitrate Propagation During Irrigation with Reclaimed Wastewater  

E-Print Network (OSTI)

operation, thus optimizing discharge of nitrate-laden wastewater. rain gauge D ata acquisition a nd wireless

2004-01-01T23:59:59.000Z

172

Salt Wells Geothermal Exploratory Drilling Program EA  

Open Energy Info (EERE)

Salt Wells Geothermal Exploratory Drilling Program EA Salt Wells Geothermal Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells Geothermal Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) Abstract No abstract available. Author Bureau of Land Management Published U.S. Department of the Interior- Bureau of Land Management, Carson City Field Office, Nevada, 09/14/2009 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for Salt Wells Geothermal Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) Citation Bureau of Land Management. Salt Wells Geothermal Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) [Internet]. 09/14/2009. Carson City, NV. U.S. Department of the Interior- Bureau of Land Management,

173

Evaluation of Salt Coolants for Reactor Applications  

SciTech Connect

Molten fluorides were initially developed for use in the nuclear industry as the high-temperature fluid fuel for the Molten Salt Reactor (MSR). The U.S. Department of Energy Office of Nuclear Energy is exploring the use of molten salts as primary and secondary coolants in a new generation of solid-fueled, thermal-spectrum, hightemperature reactors. This paper provides a review of relevant properties for use in evaluation and ranking of salt coolants for high-temperature reactors. Nuclear, physical, and chemical properties were reviewed, and metrics for evaluation are recommended. Chemical properties of the salt were examined to identify factors that affect materials compatibility (i.e., corrosion). Some preliminary consideration of economic factors for the candidate salts is also presented.

Williams, David F [ORNL

2008-01-01T23:59:59.000Z

174

Electrochemical processing of nitrate waste solutions. Phase 2, Final report  

SciTech Connect

The second phase of research performed at The Electrosynthesis Co., Inc. has demonstrated the successful removal of nitrite and nitrate from a synthetic effluent stream via a direct electrochemical reduction at a cathode. It was shown that direct reduction occurs at good current efficiencies in 1,000 hour studies. The membrane separation process is not readily achievable for the removal of nitrites and nitrates due to poor current efficiencies and membrane stability problems. A direct reduction process was studied at various cathode materials in a flow cell using the complete synthetic mix. Lead was found to be the cathode material of choice, displaying good current efficiencies and stability in short and long term tests under conditions of high temperature and high current density. Several anode materials were studied in both undivided and divided cell configurations. A divided cell configuration was preferable because it would prevent re-oxidation of nitrite by the anode. The technical objective of eliminating electrode fouling and solids formation was achieved although anode materials which had demonstrated good stability in short term divided cell tests corroded in 1,000 hour experiments. The cause for corrosion is thought to be F{sup {minus}} ions from the synthetic mix migrating across the cation exchange membrane and forming HF in the acid anolyte. Other possibilities for anode materials were explored. A membrane separation process was investigated which employs an anion and cation exchange membrane to remove nitrite and nitrate, recovering caustic and nitric acid. Present research has shown poor current efficiencies for nitrite and nitrate transport across the anion exchange membrane due to co-migration of hydroxide anions. Precipitates form within the anion exchange membranes which would eventually result in the failure of the membranes. Electrochemical processing offers a highly promising and viable method for the treatment of nitrate waste solutions.

Genders, D.; Weinberg, N.; Hartsough, D. [Electrosynthesis Co., Inc., Cheektowaga, NY (US)

1992-10-07T23:59:59.000Z

175

Nitrate Enhanced Microbial Cr(VI) Reduction-Final Report  

Science Conference Proceedings (OSTI)

A major challenge for the bioremediation of radionuclides (i.e., uranium, technetium) and metals (i.e., Cr(VI), Hg) is the co-occurrence of nitrate as it can inhibit metal transformation. Denitrification (nitrate reduction to dinitrogen gas) is considered the most important ecological process. For many metal and metalloid reducing bacteria, however, ammonia is the end product through respiratory nitrate reduction (RNRA). The focus of this work was to determine how RNRA impacts Cr(VI) transformation. The goal was to elucidate the specific mechanism(s) that limits Cr(VI) reduction in the presence of nitrate and to use this information to develop strategies that enhance Cr(VI) reduction (and thus detoxification). Our central hypothesis is that nitrate impacts the biotransformation of metals and metalloids in three ways 1) as a competitive alternative electron acceptor (inhibiting transformation), 2) as a co-metabolite (i.e., concomitant reduction, stimulating transformation), and 3) as an inducer of specific proteins and pathways involved in oxidation/reduction reactions (stimulating transformation). We have identified three model organisms, Geobacter metallireducens (mechanism 1), Sulfurospirillum barnesii, (mechasism 2), and Desulfovibrio desulfuricans (mechanisms 3). Our specific aims were to 1) investigate the role of Cr(VI) concentration on the kinetics of both growth and reduction of nitrate, nitrite, and Cr(VI) in these three organisms; 2) develop a profile of bacterial enzymes involved in nitrate transformation (e.g., oxidoreductases) using a proteomic approach; 3) investigate the function of periplasmic nitrite reductase (Nrf) as a chromate reductase; and 4) develop a strategy to maximize microbial chromium reduction in the presence of nitrate. We found that growth on nitrate by G. metallireducens was inhibited by Cr(VI). Over 240 proteins were identified by LC/MS-MS. Redox active proteins, outer membrane heavy metal efflux proteins, and chemotaxis sensory proteins (Gmet_2478 and Gmet_1641) were up-regulated with exposure to Cr(VI). A nine-heme cytochrome C was purified that could reduce nitrite and could be oxidized by Cr(VI). For D. desulfuricans, we found that confirmed that Cr(VI) induced a prolonged lag period when Cr(VI) was reduced. Over three hundred proteins were unequivocally identified by LC/MS-MS and a significant number of down-regulated proteins for which the levels were changed >2 fold compared to control. Sulfite reductase levels were similar, however, nitrate and nitrite reductase were down-regulated. The supernatant of spent cultures was found to contain a filterable, heat stable compound that rapidly reduced Cr(VI). In addition, desulfoviridin was purified from nitrate grown cells and shown to have nitrite reductase activity that was inhibited by Cr(VI). For S. barnesii, periplasmic nitrate reductase (Nap), nitrite reductase (Nrf), and the metalloid reductase (Rar) were purified and characterized. The supernatant of spent cultures was also found to contain a filterable, heat stable compound that rapidly reduced Cr(VI) but that Rar also reduced Cr(VI). Our results from specific aims 1 through 3 indicate that for G. metallireducens, Cr(VI) inhibits nitrate respiration as it oxidizes cytochromes involved in nitrate respiration. Iron reduction is apparently not affected and the inhibitory affects of Cr(VI) may be attenuated by the addition of sufficient Fe(III) to generate Fe(II) that abiotically reduces the chromium. For S. barnesii, although the enzyme assays indicate that the components of the respiratory pathway for nitrate (e.g. Nap and Nrf) are inhibited by chromate, the organism has a mechanism to prevent this from actually occurring. Our current hypothesis is that the non-specific metalloid reductase (Rar) is providing resistance by reducing the Cr(VI). The strategy here would be to enhance its growth and metabolism in the natural setting. Lactate is a suitable electron donor for S. barnesii but other donors are possible. Although the version of the Phylochip used for monitoring the microb

John F. Stolz

2011-06-15T23:59:59.000Z

176

Modeling of Porous Electrodes in Molten-Salt Systems  

E-Print Network (OSTI)

of Porous Electrodes in Molten-Salt Systems^ John Newmanon High-Temperature Molten Salt B a t - teries, Argonneby the modeling of molten-salt cells, including some

Newman, John

1986-01-01T23:59:59.000Z

177

Direct and Indirect Shortwave Radiative Effects of Sea Salt Aerosols  

Science Conference Proceedings (OSTI)

Sea salt aerosols play a dual role in affecting the atmospheric radiative balance. Directly, sea salt particles scatter the incoming solar radiation and absorb the outgoing terrestrial radiation. By acting as cloud condensation nuclei, sea salt ...

Tarek Ayash; Sunling Gong; Charles Q. Jia

2008-07-01T23:59:59.000Z

178

Geothermometry At Salt Wells Area (Shevenell, Et Al., 2008) ...  

Open Energy Info (EERE)

search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Salt Wells Area (Shevenell, Et Al., 2008) Exploration Activity Details Location Salt Wells Area...

179

DOE - Office of Legacy Management -- Tatum Salt Dome Test Site...  

Office of Legacy Management (LM)

Tatum Salt Dome Test Site - MS 01 FUSRAP Considered Sites Site: Tatum Salt Dome Test Site (MS.01) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site...

180

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics Coupled Thermal-Hydrological-Mechanical Processes...

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

EIA - Natural Gas Pipeline Network - Salt Cavern Storage Reservoir...  

U.S. Energy Information Administration (EIA) Indexed Site

Salt Cavern Underground Natural Gas Storage Reservoir Configuration Salt Cavern Underground Natural Gas Storage Reservoir Configuration Source: PB Energy Storage Services Inc....

182

Notice of Availability of Section 3116 Determination for Salt...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Notice of Availability of Section 3116 Determination for Salt Waste Disposal at the Savannah River Site Notice of Availability of Section 3116 Determination for Salt Waste Disposal...

183

Molten Salt Breeder Reactors Academia Sinica, ITRI, NTHU  

E-Print Network (OSTI)

Power 4/8/12 Frank H. Shu Gen IV MSBR/LFTR Liquid fuel (molten salt) Molten salt coolant (unpopulated

Wang, Ming-Jye

184

Corrosion of High Temperature Alloys in Molten Salts  

Science Conference Proceedings (OSTI)

Fluoride and chloride salts are among the candidates for this application. However, materials corrosion is an issue in these molten salts, particularly in molten ...

185

Independent Oversight Review, Savannah River Site Salt Waste...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Savannah River Site Salt Waste Processing Facility - August 2013 Independent Oversight Review, Savannah River Site Salt Waste Processing Facility - August 2013 August 2013 Review...

186

Engineering study of the potential uses of salts from selective crystallization of Hanford tank wastes  

SciTech Connect

The Clean Salt Process (CSP) is the fractional crystallization of nitrate salts from tank waste stored on the Hanford Site. This study reviews disposition options for a CSP product made from Hanford Site tank waste. These options range from public release to onsite low-level waste disposal to no action. Process, production, safety, environment, cost, schedule, and the amount of CSP material which may be used are factors considered in each option. The preferred alternative is offsite release of clean salt. Savings all be generated by excluding the material from low-level waste stabilization. Income would be received from sales of salt products. Savings and income from this alternative amount to $1,027 million, excluding the cost of CSP operations. Unless public sale of CSP products is approved, the material should be calcined. The carbonate form of the CSP could then be used as ballast in tank closure and stabilization efforts. Not including the cost of CSP operations, savings of $632 million would be realized. These savings would result from excluding the material from low-level waste stabilization and reducing purchases of chemicals for caustic recycle and stabilization and closure. Dose considerations for either alternative are favorable. No other cost-effective alternatives that were considered had the capacity to handle significant quantities of the CSP products. If CSP occurs, full-scale tank-waste stabilization could be done without building additional treatment facilities after Phase 1 (DOE 1996). Savings in capital and operating cost from this reduction in waste stabilization would be in addition to the other gains described.

Hendrickson, D.W.

1996-04-30T23:59:59.000Z

187

Category:Salt Lake City, UT | Open Energy Information  

Open Energy Info (EERE)

UT UT Jump to: navigation, search Go Back to PV Economics By Location Media in category "Salt Lake City, UT" The following 16 files are in this category, out of 16 total. SVFullServiceRestaurant Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png SVFullServiceRestauran... 57 KB SVHospital Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png SVHospital Salt Lake C... 57 KB SVLargeHotel Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png SVLargeHotel Salt Lake... 55 KB SVLargeOffice Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png SVLargeOffice Salt Lak... 57 KB SVMediumOffice Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png SVMediumOffice Salt La... 62 KB SVMidriseApartment Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png

188

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Download CX-003844: Categorical Exclusion Determination Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility Project CX(s) Applied: A9, B3.6...

189

Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts  

DOE Patents (OSTI)

A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent is described. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Lin, Yuehe (Moscow, ID)

1998-01-01T23:59:59.000Z

190

Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts  

DOE Patents (OSTI)

A method is described for extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process. 7 figs.

Wai, C.M.; Smart, N.G.; Lin, Y.

1998-06-23T23:59:59.000Z

191

Nitrate and Perchlorate removal from groundwater by ion exchange  

SciTech Connect

This study was conducted to evaluate the performance of a small scale ion exchange unit (Krudico, Inc of Auborn, IA) for removal of nitrate and perchlorate from groundwater at Lawrence Livermore National Laboratory's Site 300. The unit was able to treat 3,600 gallons of Site 300 groundwater, at an average influent concentration of 100 mg/L NO{sub 3}{sup -} before breakthrough occurred. The unit contained 2.5 ft{sup 3} of Sybron SR-7 resin. Seventy gallons of regeneration waste were generated (water treated to waste ratio of 51:1). The effluent concentration was about 20 mg/L NO{sub 3}{sup -}, which is equivalent to a treatment efficiency of at least 80%. There are several options for implementing this technology at Site 300. A target well, in the 817 area, has been selected. It has a 3 to 4 gpm flow rate, and concentrations of 90 mg/L NO{sub 3}{sup -} and 40 {micro}g/L perchlorate. The different treatment options include ion exchange treatment of nitrate only, nitrate and perchlorate, or perchlorate only. Option 1: For the treatment of nitrate only, this unit will be able to treat 3,700 gallons of water before regeneration is required. If both columns of the ion exchange unit are used, 7,400 gallons could be treated before the columns will need to be regenerated (producing 140 gallons of waste, per cycle or every 1.5 days). The effluent nitrate concentration is expected to be about 17 mg/L. Annual operation and maintenance costs are estimated to be $0.14 per gallon of water treated. Option 2: If only perchlorate is to be removed with ion exchange at the 817 area, a smaller unit should be considered. A 55 gallon canister filled with ion exchange resin should be able to reduce perchlorate concentrations in the groundwater from 40 {micro}g/L to non-detect levels for three years before the resin would need to be replaced. The contaminant-laden resin would be disposed of as hazardous waste. It is not practical to regenerate the resin because of the extreme difficulty of removing perchlorate from the resin. Due to the selectivity of the ion exchange resin, it will also be possible to selectively remove perchlorate from nitrate-contaminated water. Annual operation and maintenance costs are estimated to be $0.02 per gallon of water treated. Option 3: Another alternative is to treat both perchlorate and nitrate. A three column unit would be built. The first column would capture perchlorate and the resin would be replaced rather than regenerated. The second and third column would be operated as under Option 1 to treat nitrate. Annual operation and maintenance costs are estimated to be $0.14 per gallon of water treated.

Burge, S; Halden, R

1999-09-15T23:59:59.000Z

192

Total Carbon Dioxide, Hydrographic, and Nitrate Measurements in the  

NLE Websites -- All DOE Office Websites (Extended Search)

Total Carbon Dioxide, Hydrographic, and Nitrate Measurements in the Southwest Pacific during Austral Autumn, 1990: Results from NOAA/PMEL CGC-90 Cruise. Total Carbon Dioxide, Hydrographic, and Nitrate Measurements in the Southwest Pacific during Austral Autumn, 1990: Results from NOAA/PMEL CGC-90 Cruise. NDP-052 (1995) data Download the Data and ASCII Documentation files of NDP-052 PDF Download a PDF of NDP-052 image Contributed by Marilyn F. Lamb and Richard A. Feely Pacific Marine Environmental Laboratory Seattle, Washington and Lloyd Moore and Donald K. Atwood Atlantic Oceanographic and Meteorological Laboratory Miami, Florida Prepared by Alexander Kozyr* Carbon Dioxide Information Analysis Center Oak Ridge National Laboratory Oak Ridge, Tennessee, U.S.A. *Energy, Environment, and Resources Center The University of Tennessee Knoxville, Tennessee Environmental Sciences Division Publication No. 4420 Date Published: September 1995

193

Shock compression of water and solutions of ammonium nitrate  

E-Print Network (OSTI)

4.3 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88 4.4 Bibliography . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 5 Shock compression of water 95 5.1 Cell development... .pwcs.com.au/display/assets/download.php?id=498. W. B. Sudweeks. Physical and chemical properties of industrial slurry explo- sives. Industrial & Engineering Chemistry Product Research and Development, 24(3):432–436, 1985. N. Taylor. Hot spots in Ammonium Nitrate. PhD thesis, University of Cam...

Morley, Michael James

2011-07-12T23:59:59.000Z

194

Salt Wells Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Salt Wells Geothermal Area Salt Wells Geothermal Area (Redirected from Salt Wells Area) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Salt Wells Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Future Plans 5 Exploration History 6 Well Field Description 7 Research and Development Activities 8 Technical Problems and Solutions 9 Geology of the Area 9.1 Regional Setting 9.2 Stratigraphy 9.3 Structure 10 Hydrothermal System 11 Heat Source 12 Geofluid Geochemistry 13 NEPA-Related Analyses (9) 14 Exploration Activities (28) 15 References Area Overview Geothermal Area Profile Location: Nevada Exploration Region: Northwest Basin and Range Geothermal Region GEA Development Phase: Operational"Operational" is not in the list of possible values (Phase I - Resource Procurement and Identification, Phase II - Resource Exploration and Confirmation, Phase III - Permitting and Initial Development, Phase IV - Resource Production and Power Plant Construction) for this property.

195

Plutonium and americium separation from salts  

DOE Patents (OSTI)

Salts or materials containing plutonium and americium are dissolved in hydrochloric acid, heated, and contacted with an alkali metal carbonate solution to precipitate plutonium and americium carbonates which are thereafter readily separable from the solution.

Hagan, Paul G. (Northglenn, CO); Miner, Frend J. (Boulder, CO)

1976-01-01T23:59:59.000Z

196

Molten salt destruction of energetic waste materials  

DOE Patents (OSTI)

A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor.

Brummond, William A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA); Pruneda, Cesar O. (Livermore, CA)

1995-01-01T23:59:59.000Z

197

Molten salt destruction of energetic waste materials  

DOE Patents (OSTI)

A molten salt destruction process is used to treat and destroy energetic waste materials such as high explosives, propellants, and rocket fuels. The energetic material is pre-blended with a solid or fluid diluent in safe proportions to form a fluid fuel mixture. The fuel mixture is rapidly introduced into a high temperature molten salt bath. A stream of molten salt is removed from the vessel and may be recycled as diluent. Additionally, the molten salt stream may be pumped from the reactor, circulated outside the reactor for further processing, and delivered back into the reactor or cooled and circulated to the feed delivery system to further dilute the fuel mixture entering the reactor. 4 figs.

Brummond, W.A.; Upadhye, R.S.; Pruneda, C.O.

1995-07-18T23:59:59.000Z

198

Salt Lake City- High Performance Buildings Requirement  

Energy.gov (U.S. Department of Energy (DOE))

Salt Lake City's mayor issued an executive order in July 2005 requiring that all public buildings owned and controlled by the city be built or renovated to meet the requirements of LEED "silver"...

199

Salt Dispersion in the Hudson Estuary  

Science Conference Proceedings (OSTI)

The seaward transport of salt by river discharge through an estuary is balanced under steady conditions by landward dispersion effected by various physical mixing processes. Observations of current and salinity in the lower Hudson estuary provide ...

Kenneth Hunkins

1981-05-01T23:59:59.000Z

200

PROCESSING OF MOLTEN SALT POWER REACTOR FUEL  

SciTech Connect

ABS> Fuel reprocessing methods are being investigated for molten salt nuclear reactors which use LiF--BeF/sub 2/ salt as a solvent for UF/sub 4/ and ThF/sub 4/. A liquid HF dissolution procedure coupled with fluorination has been developed for recovery of the uranium and LiF- BeF/sub 2/ solvent salt which is highly enriched in Li/sup 7/. The recovered salt is decontaminated in the process from the major reactor poisons; namely, rare earths and neptunium. A brief investigation of alternate methods, including oxide precipitation, partial freezing, and metal reduction, indicated that such methods may give some separation of the solvent salt from reactor poisons, but they do not appear to be sufficiently quantitative for a simple processing operation. Solubilities of LiF and BeF/sub 2/ in aqueous 70t0 100% HF are presented. The BeF/sub 2/ solubility is appreciably increased in the presence of water and large amounts of LiF. Salt solubilities of 150 g/liter are attainable. Tracer experiments indicate that rare earth solubilities, relative to LiF-- BeF/sub 2/ solvent salt solubility, increase from about 10/sup -4/ mole% in 98% HF to 0.003 mole% in 80% HF. Fluorination of uranium from LiF--BeF/sub 2/ salt was demonstrated. This appears feasible also for the recovery of the relatively small ccncentration of uranium produced in the LiF- BeF/sub 2/ThF/sub 4/ blanket. A proposed chemical flowsheet is presented on the basis of this exploratory work as applied to the semicontinuous processing of a 600 Mw power reactor. (auth)

Campbell, D.O.; Cathers, G.I.

1959-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect

The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of vitrification. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudo hydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

Moyer, Bruce A.; Bonnesen, Peter V.; Custelcean, Radu; Delmau, Laetitia H.; Engle, Nancy L.; Kang, Hyun-Ah; Keever, Tamara J.; Marchand, Alan P.; Gadthula, Srinivas; Gore, Vinayak K.; Huang, Zilin; Sivappa, Rasapalli; Tirunahari, Pavan K.; Levitskaia, Tatiana G.; Lumetta, Gregg J.

2005-09-26T23:59:59.000Z

202

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect

The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of low-activity waste immobilization. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudohydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.; Bonnesen, Peter V.

2005-06-01T23:59:59.000Z

203

Thermal Characterization of Molten Salt Systems  

Science Conference Proceedings (OSTI)

The phase stability of molten salts in an electrorefiner (ER) may be adversely affected by the buildup of sodium, fission products, and transuranics in the electrolyte. Potential situations that need to be avoided are the following: (1) salt freezing due to an unexpected change in the liquidus temperature, (2) phase separation or non-homogeneity of the molten salt due to the precipitation of solids or formation of immiscible liquids, and (3) any mechanism that can result in the separation and concentration of fissile elements from the molten salt. Any of these situations would result in an off-normal condition outside the established safety basis for electrorefiner (ER) operations. The stability (and homogeneity) of the phases can potentially be monitored through the thermal characterization of the salts, which can be a function of impurity concentration. This report describes the experimental results of typical salts compositions, which consist of chlorides of potassium, lithium, strontium, samarium, praseodymium, lanthanum, barium, cerium, cesium, neodymium, sodium and gadolinium chlorides as a surrogate for both uranium and plutonium, used for the processing of used nuclear fuels.

Toni Y. Gutknecht; Guy L. Fredrickson

2011-09-01T23:59:59.000Z

204

Waste Isolation Pilot Plant's Excavated Salt Agreement Supports  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Conservation Education, Other Public Initiatives Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Conservation Education, Other Public Initiatives November 14, 2013 - 12:00pm Addthis Approximately 1.8 million tons of salt have been mined out of the underground at WIPP. Approximately 1.8 million tons of salt have been mined out of the underground at WIPP. Proceeds from the WIPP salt allowed hundreds of southeast New Mexico students to learn about resource conservation. Proceeds from the WIPP salt allowed hundreds of southeast New Mexico students to learn about resource conservation. The crushed salt is used as a supplement in cattle feed. Since the salt from WIPP has been mined from the middle of a large salt formation, its quality is high, according to Magnum Minerals.

205

Waste Isolation Pilot Plant's Excavated Salt Agreement Supports  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Conservation Education, Other Public Initiatives Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Conservation Education, Other Public Initiatives November 14, 2013 - 12:00pm Addthis Approximately 1.8 million tons of salt have been mined out of the underground at WIPP. Approximately 1.8 million tons of salt have been mined out of the underground at WIPP. Proceeds from the WIPP salt allowed hundreds of southeast New Mexico students to learn about resource conservation. Proceeds from the WIPP salt allowed hundreds of southeast New Mexico students to learn about resource conservation. The crushed salt is used as a supplement in cattle feed. Since the salt from WIPP has been mined from the middle of a large salt formation, its quality is high, according to Magnum Minerals.

206

Baseload coal investment decisions under uncertain carbon legislation  

SciTech Connect

More than 50% of electricity in the U.S. is generated by coal. The U.S. has large coal resources, the cheapest fuel in most areas. Coal fired power plants are likely to continue to provide much of U.S. electricity. However, the type of power plant that should be built is unclear. Technology can reduce pollutant discharges and capture and sequester the CO{sub 2} from coal-fired generation. The U.S. Energy Policy Act of 2005 provides incentives for large scale commercial deployment of Integrated Coal Gasification Combined Cycle (IGCC) systems (e.g., loan guarantees and project tax credits). This analysis examines whether a new coal plant should be pulverized coal (PC) or IGCC. Do stricter emissions standards (PM, SO{sub 2}, NOx, Hg) justify the higher costs of IGCC over PC? How does potential future carbon legislation affect the decision to add carbon capture and storage (CCS) technology? Finally, can the impact of uncertain carbon legislation be minimized? We find that SO{sub 2}, NOx, PM, and Hg emission standards would have to be far more stringent than twice current standards to justify the increased costs of the IGCC system. A CO{sub 2} tax less than $29/ton would lead companies to continuing to choose PC, paying the tax for emitted CO{sub 2}. The earlier a decision-maker believes the carbon tax will be imposed and the higher the tax, the more likely companies will choose IGCC with CCS. Having government announce the date and level of a carbon tax would promote more sensible decisions, but government would have to use a tax or subsidy to induce companies to choose the technology that is best for society. 14 refs., 6 figs., 4 tabs.

Joule A. Bergerson; Lester B. Lave [University of Calgary, Calgary, AB (Canada)

2007-05-15T23:59:59.000Z

207

Salt Mechanics Primer for Near-Salt and Sub-Salt Deepwater Gulf of Mexico Field Developments  

Science Conference Proceedings (OSTI)

The Gulf of Mexico (GoM) is the most active deepwater region in the world and provides some of the greatest challenges in scope and opportunity for the oil and gas industry. The complex geologic settings and significant water and reservoir depths necessitate high development costs, in addition to requiring innovating technology. The investment costs are substantial: because of the extreme water depths (up to 8000 feet) and considerable reservoir depths (to 30,000 feet below mudline), the cost of drilling a single well can be upwards of 50 to 100 million dollars. Central, therefore, to successful economic exploitation are developments with a minimum number of wells combined with a well service lifetime of twenty to thirty years. Many of the wells that are planned for the most significant developments will penetrate thick salt formations, and the combined drilling costs for these fields are estimated in the tens of billions of dollars. In May 2001, Sandia National Laboratories initiated a Joint Industry Project focused on the identification, quantification, and mitigation of potential well integrity issues associated with sub-salt and near-salt deepwater GoM reservoirs. The project is jointly funded by the DOE (Natural Gas and Oil Technology Partnership) and nine oil companies (BHP Billiton Petroleum, BP, ChevronTexaco, Conoco, ExxonMobil, Halliburton, Kerr-McGee, Phillips Petroleum, and Shell). This report provides an assessment of the state of the art of salt mechanics, and identifies potential well integrity issues relevant to deepwater GoM field developments. Salt deformation is discussed and a deformation mechanism map is provided for salt. A bounding steady-state strain rate contour map is constructed for deepwater GoM field developments, and the critical issue of constraint in the subsurface, and resultant necessity for numerical analyses is discussed.

FOSSUM, ARLO F.; FREDRICH, JOANNE T.

2002-07-01T23:59:59.000Z

208

Salt Wells Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Salt Wells Geothermal Area Salt Wells Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Salt Wells Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Future Plans 5 Exploration History 6 Well Field Description 7 Research and Development Activities 8 Technical Problems and Solutions 9 Geology of the Area 9.1 Regional Setting 9.2 Stratigraphy 9.3 Structure 10 Hydrothermal System 11 Heat Source 12 Geofluid Geochemistry 13 NEPA-Related Analyses (9) 14 Exploration Activities (28) 15 References Area Overview Geothermal Area Profile Location: Nevada Exploration Region: Northwest Basin and Range Geothermal Region GEA Development Phase: Operational"Operational" is not in the list of possible values (Phase I - Resource Procurement and Identification, Phase II - Resource Exploration and Confirmation, Phase III - Permitting and Initial Development, Phase IV - Resource Production and Power Plant Construction) for this property.

209

Salt Wells Geothermal Project | Open Energy Information  

Open Energy Info (EERE)

Salt Wells Geothermal Project Salt Wells Geothermal Project Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Development Project: Salt Wells Geothermal Project Project Location Information Coordinates 39.580833333333°, -118.33444444444° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":39.580833333333,"lon":-118.33444444444,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

210

Brine flow in heated geologic salt.  

Science Conference Proceedings (OSTI)

This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

Kuhlman, Kristopher L.; Malama, Bwalya

2013-03-01T23:59:59.000Z

211

Fast Spectrum Molten Salt Reactor Options  

DOE Green Energy (OSTI)

During 2010, fast-spectrum molten-salt reactors (FS-MSRs) were selected as a transformational reactor concept for light-water reactor (LWR)-derived heavy actinide disposition by the Department of Energy-Nuclear Energy Advanced Reactor Concepts (ARC) program and were the subject of a preliminary scoping investigation. Much of the reactor description information presented in this report derives from the preliminary studies performed for the ARC project. This report, however, has a somewhat broader scope-providing a conceptual overview of the characteristics and design options for FS-MSRs. It does not present in-depth evaluation of any FS-MSR particular characteristic, but instead provides an overview of all of the major reactor system technologies and characteristics, including the technology developments since the end of major molten salt reactor (MSR) development efforts in the 1970s. This report first presents a historical overview of the FS-MSR technology and describes the innovative characteristics of an FS-MSR. Next, it provides an overview of possible reactor configurations. The following design features/options and performance considerations are described including: (1) reactor salt options-both chloride and fluoride salts; (2) the impact of changing the carrier salt and actinide concentration on conversion ratio; (3) the conversion ratio; (4) an overview of the fuel salt chemical processing; (5) potential power cycles and hydrogen production options; and (6) overview of the performance characteristics of FS-MSRs, including general comparative metrics with LWRs. The conceptual-level evaluation includes resource sustainability, proliferation resistance, economics, and safety. The report concludes with a description of the work necessary to begin more detailed evaluation of FS-MSRs as a realistic reactor and fuel cycle option.

Gehin, Jess C [ORNL; Holcomb, David Eugene [ORNL; Flanagan, George F [ORNL; Patton, Bruce W [ORNL; Howard, Rob L [ORNL; Harrison, Thomas J [ORNL

2011-07-01T23:59:59.000Z

212

Heated muds solve squeezing-salt problems  

Science Conference Proceedings (OSTI)

Squeezing salts have been responsible for major drilling problems in many areas of the world for over half a century. In NAM's area of operations, they occur primarily in the Zechstein group of evaporites. They are responsible for problems such as stuck pipe during drilling and casing failure during both drilling and casing failure during both drilling and production, sometimes as much as 12 years after drilling. Since 1960, some US $170 million (at 1992 drilling costs) have been spent redrilling wells with failed casing strings. In 1991, NAM was associated with a Billiton project to drill 2 wells for the solution mining of magnesium and potassium salts. Gauge holes were a prerequisite to identify the objective salts by electric logging. Excellent results were achieved by drilling with a heated salt mud that had been saturated on surface to downhole conditions. The heating requirements for the Billiton project were modest, as the top of the squeezing salt occurred at approximately 1,500 m (4,920 ft), requiring a circulating temperature of 45 C (113 F) to achieve the necessary saturation level. However, in NAM's operations, the top of the squeezing salt generally occurs between 2.500 m and 3,000 m (8,200 ft and 9,850 ft), requiring temperatures on the order of 70 C (158 F). Despite the need for higher temperatures, the success of the Billiton project prompted NAM to introduce the heating system on a trial basis. To date eight wells have been drilled using the system, resulting in the drilling of a virtual gauge hole with successful cementations being achieved in each case.

Muecke, N.B. (Nederlandse Aardolie, Maatschappij (Netherlands))

1993-11-01T23:59:59.000Z

213

SEPARATION OF BARIUM VALUES FROM URANYL NITRATE SOLUTIONS  

DOE Patents (OSTI)

The separation of radioactive barium values from a uranyl nitrate solution of neutron-irradiated uranium is described. The 10 to 20% uranyl nitrate solution is passed through a flrst column of a cation exchange resin under conditions favoring the adsorption of barium and certain other cations. The loaded resin is first washed with dilute sulfuric acid to remove a portion of the other cations, and then wash with a citric acid solution at pH of 5 to 7 to recover the barium along with a lesser amount of the other cations. The PH of the resulting eluate is adjusted to about 2.3 to 3.5 and diluted prior to passing through a smaller second column of exchange resin. The loaded resin is first washed with a citric acid solution at a pH of 3 to elute undesired cations and then with citric acid solution at a pH of 6 to eluts the barium, which is substantially free of undesired cations.

Tompkins, E.R.

1959-02-24T23:59:59.000Z

214

A Novel Integration of an Ultraviolet Nitrate Sensor On Board a Towed Vehicle for Mapping Open-Ocean Submesoscale Nitrate Variability  

Science Conference Proceedings (OSTI)

Initial results from a deployment of the SUV-6 ultraviolet spectrophotometer, integrated with the SeaSoar towed vehicle, are presented. The innovative, combined system measures nitrate concentration at high spatial resolution (4 m vertically, 5 ...

Rosalind Pidcock; Meric Srokosz; John Allen; Mark Hartman; Stuart Painter; Matt Mowlem; David Hydes; Adrian Martin

2010-08-01T23:59:59.000Z

215

A MOLTEN SALT NATURAL CONVECTION REACTOR SYSTEM  

SciTech Connect

Fuel-salt volumes external to the core of a molten-salt reactor are calculated for a system in which the fuel salt circulates through the core and primary exchanger by free convection. In the calculation of these volumes, the exchanger heights above the core top range from 5 to 20 ft. Coolants considered for the primary exchanger are a second molten salt and helium. External fuel holdup is found to be the same with either coolant. Two sets of terminal temperatures are selected for the helium. The first combination permits steam generation at 850 psia, 900 deg F. The second set is selected for a closed gas turbine cycle with an 1100 deg F turbine inlet temperature. Specific power (thermal kw/kg 235) is found to be about 900 Mv/kg, based on initial, clean conditions and a 60 Mw (thermal) output. A specific power of 1275 kw/kg is estimated for a forced convection system of the same rating. (auth)

Romie, F.E.; Kinyon, B.W.

1958-02-01T23:59:59.000Z

216

Salt repository project closeout status report  

SciTech Connect

This report provides an overview of the scope and status of the US Department of Energy (DOE`s) Salt Repository Project (SRP) at the time when the project was terminated by the Nuclear Waste Policy Amendments Act of 1987. The report reviews the 10-year program of siting a geologic repository for high-level nuclear waste in rock salt formations. Its purpose is to aid persons interested in the information developed during the course of this effort. Each area is briefly described and the major items of information are noted. This report, the three salt Environmental Assessments, and the Site Characterization Plan are the suggested starting points for any search of the literature and information developed by the program participants. Prior to termination, DOE was preparing to characterize three candidate sites for the first mined geologic repository for the permanent disposal of high-level nuclear waste. The sites were in Nevada, a site in volcanic tuff; Texas, a site in bedded salt (halite); and Washington, a site in basalt. These sites, identified by the screening process described in Chapter 3, were selected from the nine potentially acceptable sites shown on Figure I-1. These sites were identified in accordance with provisions of the Nuclear Waste Policy Act of 1982. 196 refs., 21 figs., 11 tabs.

1988-06-01T23:59:59.000Z

217

Accelerators for Subcritical Molten-Salt Reactors  

SciTech Connect

Accelerator parameters for subcritical reactors have usually been based on using solid nuclear fuel much like that used in all operating critical reactors as well as the thorium burning accelerator-driven energy amplifier proposed by Rubbia et al. An attractive alternative reactor design that used molten salt fuel was experimentally studied at ORNL in the 1960s, where a critical molten salt reactor was successfully operated using enriched U235 or U233 tetrafluoride fuels. These experiments give confidence that an accelerator-driven subcritical molten salt reactor will work better than conventional reactors, having better efficiency due to their higher operating temperature, having the inherent safety of subcritical operation, and having constant purging of volatile radioactive elements to eliminate their accumulation and potential accidental release in dangerous amounts. Moreover, the requirements to drive a molten salt reactor can be considerably relaxed compared to a solid fuel reactor, especially regarding accelerator reliability and spallation neutron targetry, to the point that much of the required technology exists today. It is proposed that Project-X be developed into a prototype commercial machine to produce energy for the world by, for example, burning thorium in India and nuclear waste from conventional reactors in the USA.

Johnson, Roland (Muons, Inc.)

2011-08-03T23:59:59.000Z

218

Internal Wave Overturns Produced by Salt Fingers  

Science Conference Proceedings (OSTI)

The salt finger fluxes obtained in small-domain direct numerical simulations (DNSs) are used to parameterize the fluxes in a larger domain that resolves internal gravity waves. For the case in which the molecular diffusivity ratio ? = KS/KT < 1 ...

Melvin E. Stern; Julian A. Simeonov

2002-12-01T23:59:59.000Z

219

Hanford Waste Vitrification Plant hydrogen generation study: Formation of ammonia from nitrate and nitrate in hydrogen generating systems  

DOE Green Energy (OSTI)

The Hanford Waste Vitrification Plant (HWVP) is being designed for the Departrnent of Energy (DOE) to immobilize pretreated highly radioactive wastes in glass for permanent disposal in the HWVP, formic acid is added to the waste before vitrification to adjust glass redox and melter feed rheology. The operation of the glass melter and durability of the glass are affected by the glass oxidation state. Formation of a conductive metallic sludge in an over-reduced melt can result in a shortened melter lifetime. An over-oxidized melt may lead to foaming and loss of ruthenium as volatile RuO{sub 4}. Historically, foaming in the joule heated ceramic melter has been attributed to gas generation in the melt which is controlled by instruction of a reductant such as formic acid into the melter feed. Formic acid is also found to decrease the melter feed viscosity thereby facilitating pumping. This technical report discusses the noble metal catalyzed formic acid reduction of nitrite and/or nitrate to ammonia, a problem of considerable concern because of the generation of a potential ammonium nitrate explosion hazard in the plant ventilation system.

King, R.B.; Bhattacharyya, N.K.

1996-02-01T23:59:59.000Z

220

Salt Wells, Eight Mile Flat | Open Energy Information  

Open Energy Info (EERE)

Salt Wells, Eight Mile Flat Salt Wells, Eight Mile Flat Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells, Eight Mile Flat Abstract Abstract unavailable. Author Nevada Bureau of Mines and Geology Published Online Nevada Encyclopedia, 2009 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for Salt Wells, Eight Mile Flat Citation Nevada Bureau of Mines and Geology. Salt Wells, Eight Mile Flat [Internet]. 2009. Online Nevada Encyclopedia. [updated 2009/03/24;cited 2013/08/07]. Available from: http://www.onlinenevada.org/articles/salt-wells-eight-mile-flat Related Geothermal Exploration Activities Activities (1) Areas (1) Regions (0) Development Wells At Salt Wells Area (Nevada Bureau of Mines and Geology, 2009) Salt Wells Geothermal Area

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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221

Brine Migration Experimental Studies for Salt Repositories | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Brine Migration Experimental Studies for Salt Repositories Brine Migration Experimental Studies for Salt Repositories Brine Migration Experimental Studies for Salt Repositories Experiments were used to examine water content in Permian salt samples (Salado Formation) collected from the WIPP site. The profile of water release and movement is recognized as a function of temperature from 30 to 275 oC using classical gravimetric methods to measure weight loss as a result of heating. The amount of water released from heating the salt was found to be correlated with the salts accessory mineral content (clay, other secondary minerals lost up to 3 wt % while pure halite salt lost less than 0.5 wt % water). Water released from salt at lower temperature was reversible and is attributed to clay hydration and dehydration processes. The analysis

222

The Salt Finger Experiments of Jevons (1857) and Rayleigh (1880)  

Science Conference Proceedings (OSTI)

Over a century before Melvin Stern discovered salt fingers, W. Stanley Jevons performed the first salt finger experiment in an attempt to model cirrus clouds. Remarkably, he seemed to realize that a more rapid diffusion of heat relative to solute ...

Raymond W. Schmitt

1995-01-01T23:59:59.000Z

223

DOE Issues Salt Waste Determination for the Savannah River Site...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Salt Waste Determination for the Savannah River Site DOE Issues Salt Waste Determination for the Savannah River Site January 18, 2006 - 10:49am Addthis WASHINGTON, DC - The U.S....

224

Colloidal stability of magnetic nanoparticles in molten salts  

E-Print Network (OSTI)

Molten salts are important heat transfer fluids used in nuclear, solar and other high temperature engineering systems. Dispersing nanoparticles in molten salts can enhance the heat transfer capabilities of the fluid. High ...

Somani, Vaibhav (Vaibhav Basantkumar)

2010-01-01T23:59:59.000Z

225

Similarity measures for spectral discrimination of salt-affected soils  

Science Conference Proceedings (OSTI)

This paper illustrates a pilot study designed to examine the spectral response of soils due to salt variations. The aim of the study includes determining whether salt-affected soils can be discriminated based on their spectral characteristics, by establishing ...

J. Farifteh; F. van der Meer; E. J. M. Carranza

2007-11-01T23:59:59.000Z

226

Brine Migration Experimental Studies for Salt Repositories | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Brine Migration Experimental Studies for Salt Repositories Brine Migration Experimental Studies for Salt Repositories Brine Migration Experimental Studies for Salt Repositories Experiments were used to examine water content in Permian salt samples (Salado Formation) collected from the WIPP site. The profile of water release and movement is recognized as a function of temperature from 30 to 275 oC using classical gravimetric methods to measure weight loss as a result of heating. The amount of water released from heating the salt was found to be correlated with the salts accessory mineral content (clay, other secondary minerals lost up to 3 wt % while pure halite salt lost less than 0.5 wt % water). Water released from salt at lower temperature was reversible and is attributed to clay hydration and dehydration processes. The analysis

227

Energy Efficient Buildings, Salt Lake County, Utah  

SciTech Connect

Executive Summary Salt Lake County's Solar Photovoltaic Project - an unprecedented public/private partnership Salt Lake County is pleased to announce the completion of its unprecedented solar photovoltaic (PV) installation on the Calvin R. Rampton Salt Palace Convention Center. This 1.65 MW installation will be one the largest solar roof top installations in the country and will more than double the current installed solar capacity in the state of Utah. Construction is complete and the system will be operational in May 2012. The County has accomplished this project using a Power Purchase Agreement (PPA) financing model. In a PPA model a third-party solar developer will finance, develop, own, operate, and maintain the solar array. Salt Lake County will lease its roof, and purchase the power from this third-party under a long-term Power Purchase Agreement contract. In fact, this will be one of the first projects in the state of Utah to take advantage of the recent (March 2010) legislation which makes PPA models possible for projects of this type. In addition to utilizing a PPA, this solar project will employ public and private capital, Energy Efficiency and Conservation Block Grants (EECBG), and public/private subsidized bonds that are able to work together efficiently because of the recent stimulus bill. The project also makes use of recent changes to federal tax rules, and the recent re-awakening of private capital markets that make a significant public-private partnership possible. This is an extremely innovative project, and will mark the first time that all of these incentives (EECBG grants, Qualified Energy Conservation Bonds, New Markets tax credits, investment tax credits, public and private funds) have been packaged into one project. All of Salt Lake County's research documents and studies, agreements, and technical information is available to the public. In addition, the County has already shared a variety of information with the public through webinars, site tours, presentations, and written correspondence.

Barnett, Kimberly

2012-04-30T23:59:59.000Z

228

Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state,  

E-Print Network (OSTI)

Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state), Correction to ``Nitrate and colloid transport through coarse Hanford sediments under steady state, variably and colloid transport through coarse Hanford sediments under steady state, variably saturated flow'' by Kelly

Flury, Markus

229

Removal of uranium and salt from the Molten Salt Reactor Experiment  

SciTech Connect

In 1994, migration of {sup 233}U was discovered to have occurred at the Molten Salt Reactor Experiment (MSRE) at Oak Ridge National Laboratory (ORNL). This paper describes the actions now underway to remove uranium from the off-gas piping and the charcoal bed, to remove and stabilize the salts, and to convert the uranium to a stable oxide for long-term storage.

Peretz, F.J.; Rushton, J.E.; Faulkner, R.L.; Walker, K.L.; Del Cul, G.D.

1998-06-01T23:59:59.000Z

230

Studies on the Effects of Inorganic Salts on Biochemical Treatment ...  

Science Conference Proceedings (OSTI)

Effects of two inorganic salts (sodium chloride and sodium sulphate) on biochemical ... Numerical Investigation of Heat Transfer Characteristics in Microwave ...

231

Method for preparing salt solutions having desired properties  

DOE Patents (OSTI)

The specification discloses a method for preparing salt solutions which exhibit desired thermodynamic properties. The method enables prediction of the value of the thermodynamic properties for single and multiple salt solutions over a wide range of conditions from activity data and constants which are independent of concentration and temperature. A particular application of the invention is in the control of salt solutions in a process to provide a salt solution which exhibits the desired properties.

Ally, Moonis R. (Oak Ridge, TN); Braunstein, Jerry (Clinton, TN)

1994-01-01T23:59:59.000Z

232

Molten Salt Heat Transfer Fluid (HTF) - Energy Innovation Portal  

Solar Thermal Industrial Technologies Energy Storage Molten Salt Heat Transfer Fluid (HTF) Sandia National Laboratories. Contact SNL About This ...

233

CO2 Emission Reduction through Innovative Molten Salt Electrolysis ...  

Science Conference Proceedings (OSTI)

Electrochemical metallurgy especially through high temperature molten salt electrolysis with renewable electricity stands for a great opportunity for producing

234

Does nitrate deposition following astrophysical ionizing radiation events pose an additional threat to amphibians?  

E-Print Network (OSTI)

It is known that amphibians are especially susceptible to the combination of heightened UVB radiation and increased nitrate concentrations. Various astrophysical events have been suggested as sources of ionizing radiation that could pose a threat to life on Earth, through destruction of the ozone layer and subsequent increase in UVB, followed by deposition of nitrate. In this study, we investigate whether the nitrate deposition following an ionizing event is sufficiently large to cause an additional stress beyond that of the heightened UVB previously considered. We have converted predicted nitrate depositions to concentration values, utilizing data from the New York State Department of Environmental Conservation Acid Rain Monitoring Network web site. Our results show that the increase in nitrate concentration in bodies of water following the most intense ionization event likely in the last billion years would not be sufficient to cause a serious additional stress on amphibian populations and may actually provide some benefit by acting as fertilizer.

Brian C. Thomas; Michelle D. Honeyman

2008-04-22T23:59:59.000Z

235

Amphibian nitrate stress as an additional terrestrial threat from astrophysical ionizing radiation events?  

E-Print Network (OSTI)

As diversity in amphibian species declines, the search for causes has intensified. Work in this area has shown that amphibians are especially susceptible to the combination of heightened UVB radiation and increased nitrate concentrations. Various astrophysical events have been suggested as sources of ionizing radiation that could pose a threat to life on Earth, through destruction of the ozone layer and subsequent increase in UVB, followed by deposition of nitrate. In this study, we investigate whether the nitrate deposition following an ionizing event is sufficiently large to cause an additional stress beyond that of the heightened UVB previously considered. We have converted predicted nitrate depositions to concentration values, utilizing data from the New York State Department of Environmental Conservation Acid Rain Monitoring Network web site. Our results show that the increase in nitrate concentration in bodies of water following the most intense ionization event likely in the last billion years would no...

Thomas, Brian C

2008-01-01T23:59:59.000Z

236

SOLUTION MINING IN SALT DOMES OF THE GULF COAST EMBAYMENT  

Science Conference Proceedings (OSTI)

Following a description of salt resources in the salt domes of the gulf coast embayment, mining, particularly solution mining, is described. A scenario is constructed which could lead to release of radioactive waste stored in a salt dome via inadvertent solution mining and the consequences of this scenario are analyzed.

Griswold, G. B.

1981-02-01T23:59:59.000Z

237

Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases in Whole-Air Samples Atmospheric Trace Gases in Whole-Air Samples Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples graphics Graphics data Data Investigator Donald Blake Department of Chemistry, University of California Irvine, California, 92697 USA Period of Record April 1979 - December 2012 Methods Whole-air samples are collected in conditioned, evacuated, 2-L stainless steel canisters; each canister is filled to ambient pressure over a period of about 1 minute (approximately 20 seconds to 2 minutes). These canisters are returned to the University of California at Irvine for chromatographic analysis. Analysis for methane includes gas chromatography with flame ionization, as

238

Analysis of Enriched Uranyl Nitrate in Nested Annular Tank Array  

SciTech Connect

Two series of experiments were performed at the Rocky Flats Critical Mass Laboratory during the 1980s using highly enriched (93%) uranyl nitrate solution in annular tanks. [1, 2] Tanks were of typical sizes found in nuclear production plants. Experiments looked at tanks of varying radii in a co-located set of nested tanks, a 1 by 2 array, and a 1 by 3 array. The co-located set of tanks had been analyzed previously [3] as a benchmark for inclusion within the International Handbook of Evaluated Criticality Safety Benchmark Experiments. [4] The current study represents the benchmark analysis of the 1 by 3 array of a series of nested annular tanks. Of the seventeen configurations performed in this set of experiments, twelve were evaluated and nine were judged as acceptable benchmarks.

John D. Bess; James D. Cleaver

2009-06-01T23:59:59.000Z

239

Containerized Wetland Bioreactor Evaluated for Perchlorate and Nitrate Degradation  

SciTech Connect

The U.S. Department of Energy (DOE) and Lawrence Livermore Laboratory (LLNL) designed and constructed an innovative containerized wetlands (bioreactor) system that began operation in November 2000 to biologically degrade perchlorate and nitrate under relatively low-flow conditions at a remote location at Site 300 known as Building 854. Since initial start-up, the system has processed over 3,463,000 liters of ground water and treated over 38 grams of perchlorate and 148 kilograms of nitrate. Site 300 is operated by the University of California as a high-explosives and materials testing facility supporting nuclear weapons research. The 11-square mile site located in northern California was added to the NPL in 1990 primarily due to the presence of elevated concentrations of volatile organic compounds (VOCs) in ground water. At the urging of the regulatory agencies, perchlorate was looked for and detected in the ground water in 1999. VOCs, nitrate and perchlorate were released into the soil and ground water in the Building 854 area as the result of accidental leaks during stability testing of weapons or from waste discharge practices that are no longer permitted at Site 300. Design of the wetland bioreactors was based on earlier studies showing that indigenous chlorate-respiring bacteria could effectively degrade perchlorate into nontoxic concentrations of chlorate, chlorite, oxygen, and chloride. Studies also showed that the addition of organic carbon would enhance microbial denitrification. Early onsite testing showed acetic acid to be a more effective carbon source than dried leaf matter, dried algae, or milk replacement starter; a nutrient and carbon source used in a Department of Defense phytoremediation demonstration. No inocula were added to the system. Groundwater was allowed to circulate through the bioreactor for three weeks to acclimate the wetland plants and to build a biofilm from indigenous flora. Using solar energy, ground water is pumped into granular activated carbon canisters to remove VOCs (Figure x). Following solar treatment, ground water containing approximately 46 mg/L of nitrate and 13 {micro}g/L of perchlorate is gravity-fed continuously into two parallel series of two-1,900 liter tank bioreactors. Each bioreactor contains coarse, aquarium-grade gravel and locally-obtained plant species such as cattails (Typha spp.), sedges (Cyperus spp.), and indigenous denitrifying microorganisms. No inocula were added to the system. Groundwater was allowed to circulate through the bioreactor for three weeks to acclimate the wetland plants and to build a biofilm from indigenous flora. Sodium acetate is added to the first bioreactor in each of the two series to promote growth and metabolic activity of rhizome microorganisms. The split flow from each series is combined, and flows through two back-up ion exchange columns to assure complete perchlorate removal. Effluent from the ground water treatment system is monitored and discharged an infiltration trench in accordance with the Substantive Requirements for Waste Discharge issued by the California Regional Water Quality Control Board.

Dibley, V R; Krauter, P W

2004-12-02T23:59:59.000Z

240

FUMIGATION, GROSS NITROGEN TRANSFORMATIONS, N-15, NITRATE, RATES, SOIL  

NLE Websites -- All DOE Office Websites (Extended Search)

FUMIGATION, GROSS NITROGEN TRANSFORMATIONS, N-15, FUMIGATION, GROSS NITROGEN TRANSFORMATIONS, N-15, NITRATE, RATES, SOIL 1909 Pushnik, J.C., R.S. Demaree, J.L.J. Houpis, W.B. Flory, S.M. Bauer, and P.D. Anderson. 1995. The effect of elevated carbon dioxide on a Sierra-Nevadan dominant species: Pinus ponderosa. Journal of Biogeography 22(2-3):249-254. The impact of increasing atmospheric CO2 has not been fully evaluated on western coniferous forest species. Two year old seedlings of Pinus ponderosa were grown in environmentally controlled chambers under increased CO2 conditions (525 mu L L(-1) and 700 mu L L(-1)) for 6 months. These trees exhibited morphological, physiological and biochemical alterations when compared to our controls (350 mu L L(- 1)). Analysis of whole plant biomass distribution has shown no

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Salt River Electric - Residential Energy Efficiency Rebate Program |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Salt River Electric - Residential Energy Efficiency Rebate Program Salt River Electric - Residential Energy Efficiency Rebate Program Salt River Electric - Residential Energy Efficiency Rebate Program < Back Eligibility Residential Savings Category Home Weatherization Commercial Weatherization Sealing Your Home Heating & Cooling Construction Commercial Heating & Cooling Design & Remodeling Other Ventilation Heat Pumps Program Info State Kentucky Program Type Utility Rebate Program Rebate Amount Varies by technology Provider Salt River Electric Cooperative Salt River Electric serves as the rural electric provider in Kentucky's Bullitt, Nelson, Spencer, and Washington counties. Residential customers are eligible for a variety of cash incentives for energy efficiency. The Touchstone Energy Home Program provides a rebate of up to $250 to customers

242

Salt River Project | Open Energy Information  

Open Energy Info (EERE)

Project Project Jump to: navigation, search Name Salt River Project Place Tempe, Arizona Utility Id 16572 Utility Location Yes Ownership P NERC Location WECC NERC WECC Yes Operates Generating Plant Yes Activity Generation Yes Activity Transmission Yes Activity Buying Transmission Yes Activity Distribution Yes Activity Wholesale Marketing Yes Activity Bundled Services Yes Alt Fuel Vehicle Yes Alt Fuel Vehicle2 Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] SGIC[2] Energy Information Administration Form 826[3] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Salt River Project Smart Grid Project was awarded $56,859,359 Recovery Act Funding with a total project value of $114,003,719.

243

Molten salts database for energy applications  

E-Print Network (OSTI)

The growing interest in energy applications of molten salts is justified by several of their properties. Their possibilities of usage as a coolant, heat transfer fluid or heat storage substrate, require thermo-hydrodynamic refined calculations. Many researchers are using simulation techniques, such as Computational Fluid Dynamics (CFD) for their projects or conceptual designs. The aim of this work is providing a review of basic properties (density, viscosity, thermal conductivity and heat capacity) of the most common and referred salt mixtures. After checking data, tabulated and graphical outputs are given in order to offer the most suitable available values to be used as input parameters for other calculations or simulations. The reviewed values show a general scattering in characterization, mainly in thermal properties. This disagreement suggests that, in several cases, new studies must be started (and even new measurement techniques should be developed) to obtain accurate values.

Serrano-López, Roberto; Cuesta-López, Santiago

2013-01-01T23:59:59.000Z

244

DETERMINATION OF CORROSION INHIBITOR CRITERIA FOR TYPE III/IIIA TANKS DURING SALT DISSOLUTION OPERATIONS SUMMARY DOCUMENT  

SciTech Connect

Dissolution of salt from Type III/IIIA waste tanks at the Savannah River Site may create solutions with inhibitor concentrations below those currently required (0.6M OH{sup -} and 1.1M OH{sup -} + NO{sub 2}{sup -}) per the Corrosion Control Program for high nitrate salt solutions (5.5 to 8.5M NO{sub 3}{sup -}). An experimental program was conducted to evaluate the corrosion susceptibility of grade A537 carbon steel for waste simulants containing 4.5-8.5M NaNO{sub 3} with maximum inhibitor concentrations of 0.6M NaOH and 0.2M NaNO{sub 2}. These maximum inhibitor concentrations used in this program are at a reduced level from those currently required. Current requirements were initially established for the Types I, II and IV tanks made of A285 carbon steel. The experimental program involved corrosion testing to evaluate the pitting and stress corrosion stress corrosion cracking (SCC) susceptibility of the Type III/IIIA waste tank materials. The program was conducted in two phases; the results of the first phase were reported previously (WSRC-STI-2006-00029). In this second phase, the corrosion specimens were modified to represent the 'as-fabricated' condition of the tank wall, and included specimens with mill scale, ground welds and stress-relief heat treatments. The complete description of the corrosion testing and the results are reported herein. The collective corrosion test results for A537 carbon steel in high nitrate waste simulants (4.5 - 8.5M) with the maximum inhibitor concentrations of 0.6M NaOH and 0.2M NaNO{sub 2} were as follows: (1) In long-term non-polarized U-bend testing, heat treatment, similar to the waste tank stress relief regime, reduced the incidence of cracking over the 18-month test period. Vapor space SCC was found to initiate on non-heat treated U-bend coupons. (2) In polarized U-bend testing, cracking occurred on U-bend coupons that had welds prepared similar to those in the waste tanks, i.e. ground and heat treated. (3) In electrochemical testing, pitting occurred on all coupons independent of heat treatment, inhibitor concentration, temperature, surface preparation, or welding. (4) In slow strain rate testing, cracking occurred on samples tested in solutions containing up to the maximum inhibitor concentration. The primary conclusion derived from this experimental program is that A537 carbon steel exposed to high nitrate (> 5.5M) solutions at inhibitor levels below the current specifications (0.6M OH{sup -} and 1.1M OH{sup -} + NO{sub 2}{sup -}) are susceptible to localized corrosion in the form of pitting and stress corrosion cracking. Long-term storage (e.g., greater than 100 days) of dissolved salt solutions not meeting the current inhibitor specifications for high nitrate salt chemistries in Type III waste tanks shall be avoided. Short term storage (e.g., less than 100 days) at low temperatures (e.g., less than 50 C) in these tanks is permissible for waste removal purposes. The stress relief process reduces the risk of SCC in the Type III waste tanks. On the other hand, the current inhibitor specifications should be strictly followed for the Type I, II and IV waste chemistry to prevent initiation of localized corrosion mechanisms. These tanks were not stress relieved and are more susceptible to SCC.

Mickalonis, J.; Wiersma, B.; Garcia-Diaz, B.

2009-10-01T23:59:59.000Z

245

Energy Efficient Buildings, Salt Lake County, Utah  

DOE Green Energy (OSTI)

Salt Lake County is pleased to announce the completion of its unprecedented solar photovoltaic (PV) installation on the Calvin R. Rampton Salt Palace Convention Center. This 1.65 MW installation will be one the largest solar roof top installations in the country and will more than double the current installed solar capacity in the state of Utah. Construction is complete and the system will be operational in May 2012. The County has accomplished this project using a Power Purchase Agreement (PPA) financing model. In a PPA model a third-party solar developer will finance, develop, own, operate, and maintain the solar array. Salt Lake County will lease its roof, and purchase the power from this third-party under a long-term Power Purchase Agreement contract. In fact, this will be one of the first projects in the state of Utah to take advantage of the recent (March 2010) legislation which makes PPA models possible for projects of this type. In addition to utilizing a PPA, this solar project will employ public and private capital, Energy Efficiency and Conservation Block Grants (EECBG), and public/private subsidized bonds that are able to work together efficiently because of the recent stimulus bill. The project also makes use of recent changes to federal tax rules, and the recent re-awakening of private capital markets that make a significant public-private partnership possible. This is an extremely innovative project, and will mark the first time that all of these incentives (EECBG grants, Qualified Energy Conservation Bonds, New Markets tax credits, investment tax credits, public and private funds) have been packaged into one project. All of Salt Lake County's research documents and studies, agreements, and technical information is available to the public. In addition, the County has already shared a variety of information with the public through webinars, site tours, presentations, and written correspondence.

Barnett, Kimberly

2012-04-30T23:59:59.000Z

246

Molten salt battery having inorganic paper separator  

DOE Patents (OSTI)

A high temperature secondary battery comprises an anode containing lithium, a cathode containing a chalcogen or chalcogenide, a molten salt electrolyte containing lithium ions, and a separator comprising a porous sheet comprising a homogenous mixture of 2-20 wt.% chrysotile asbestos fibers and the remainder inorganic material non-reactive with the battery components. The non-reactive material is present as fibers, powder, or a fiber-powder mixture.

Walker, Jr., Robert D. (Gainesville, FL)

1977-01-01T23:59:59.000Z

247

SALT-ANL. Systems Analysis Process Simulation  

Science Conference Proceedings (OSTI)

SALT (Systems Analysis Language Translator), a systems- analysis and process-simulation program for steady-state and dynamic systems, can also be used for optimization and sensitivity studies. SALT employs state-of-the-art numerical techniques including a hybrid steepest-descent/quasi-Newtonian multidimensional nonlinear equation solver, sequential quadratic programming methods for optimization, and multistep integration methods for both stiff and nonstiff systems of differential equations. Based on a preprocessor concept where a `new` system driver can be written for each application, SALT-ANL contains precompiled component models, several flow types, and a number of thermodynamic and transport property routines, including a gas chemical-equilibrium code. It has been applied to the study of open-cycle and liquid-metal magnetohydrodynamic systems, fuel cells, ocean thermal energy conversion, municipal solid-waste processing, fusion, breeder reactors, and geothermal and solar-energy systems. Models available include: combustor, compressor, deaerator, gas-diffuser, fuel-dryer, feedwater-heater, flash-tank, gas-turbine, heater, heat-exchanger, flow-initiator, fuel-flow-initiator, molten-carbonate fuel-cell, liquid-metal diffuser, magnetohydrodynamic-generator, liquid-metal magnetohydrodynamic-generator, liquid-metal nozzle, liquid-metal pipe, flow-mixer, gas-nozzle, phosphoric acid fuel-cell, pump, pipe-calculator, steam-condenser, steam-drum, liquid-gas separator, stack, solid-oxide fuel-cell, flow-splitter, steam-turbine, two-phase diffuser, two-phase mixer, and two-phase nozzle. Input data to the SALT program describe the system configuration for the specific problem to be analyzed and provide instructions defining system constraints, objective functions, parameter sweeps, etc. to generate a PL/I program representing the system problem and performing the various analytic tasks.

Berry, G.F.; Geyer, H.K. [Argonne National Lab., IL (United States)

1992-02-26T23:59:59.000Z

248

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics The report addresses granular salt reconsolidation from three vantage points: laboratory testing, modeling, and petrofabrics. The experimental data 1) provide greater insight and understanding into the role of elevated temperature and pressure regimes on physical properties of reconsolidated crushed salt, 2) can supplement an existing database used to develop a reconsolidation constitutive model and 3) provide data for model evaluation. The constitutive model accounts for the effects of moisture through pressure solution and dislocation creep, with both terms dependent

249

Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance To The  

Open Energy Info (EERE)

Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance To The Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance To The Hydrocarbon Exploration In The Tuz Golu (Salt Lake) Basin, Central Anatolia, Turkey Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance To The Hydrocarbon Exploration In The Tuz Golu (Salt Lake) Basin, Central Anatolia, Turkey Details Activities (0) Areas (0) Regions (0) Abstract: Due to activitiy of the Aksaray and Ecemis Faults, volcanic intrusion and westward movement of the Anatolian plate, diapiric salt structures were occurred in the Tuz Golu (Salt Lake) basin in central Anatolia, Turkey. With the collisions of the Arabian and Anatolian plates during the late Cretaceous and Miocene times, prominent ophiolitic

250

WIPP Shares Expertise with Salt Club Members | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Shares Expertise with Salt Club Members Shares Expertise with Salt Club Members WIPP Shares Expertise with Salt Club Members November 26, 2013 - 12:00pm Addthis Carlsbad Field Office’s Abe Van Luik, third from right, examines rock salt taken from the Morsleben mine in Germany. Carlsbad Field Office's Abe Van Luik, third from right, examines rock salt taken from the Morsleben mine in Germany. CARLSBAD, N.M. - EM's Carlsbad Field Office (CBFO) participated in the second meeting of the Nuclear Energy Agency's (NEA) Salt Club and the 4th U.S.-German Workshop on Salt Repository Research, Design & Operation in Berlin. CBFO, which has responsibility for the Waste Isolation Pilot Plant (WIPP) and the National Transuranic (TRU) Program, was represented by International Programs and Policy Advisor Dr. Abe Van Luik.

251

Salt Waste Contractor Reaches Contract Milestone | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Salt Waste Contractor Reaches Contract Milestone Salt Waste Contractor Reaches Contract Milestone Salt Waste Contractor Reaches Contract Milestone April 29, 2013 - 12:00pm Addthis Robert Brown, SRR tank farm operator, performs daily inspections of a salt disposition process facility. The inspections and improvement upgrades have resulted in continued successful operations. Robert Brown, SRR tank farm operator, performs daily inspections of a salt disposition process facility. The inspections and improvement upgrades have resulted in continued successful operations. AIKEN, S.C. - The liquid waste cleanup contractor for the EM program at the Savannah River Site (SRS) recently surpassed a 2013 contract milestone by processing more than 600,000 gallons of salt waste. Savannah River Remediation (SRR) salt disposition process facilities

252

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics The report addresses granular salt reconsolidation from three vantage points: laboratory testing, modeling, and petrofabrics. The experimental data 1) provide greater insight and understanding into the role of elevated temperature and pressure regimes on physical properties of reconsolidated crushed salt, 2) can supplement an existing database used to develop a reconsolidation constitutive model and 3) provide data for model evaluation. The constitutive model accounts for the effects of moisture through pressure solution and dislocation creep, with both terms dependent

253

Polymeric salt bridges for conducting electric current in microfluidic devices  

DOE Patents (OSTI)

A "cast-in-place" monolithic microporous polymer salt bridge for conducting electrical current in microfluidic devices, and methods for manufacture thereof is disclosed. Polymeric salt bridges are formed in place in capillaries or microchannels. Formulations are prepared with monomer, suitable cross-linkers, solvent, and a thermal or radiation responsive initiator. The formulation is placed in a desired location and then suitable radiation such as UV light is used to polymerize the salt bridge within a desired structural location. Embodiments are provided wherein the polymeric salt bridges have sufficient porosity to allow ionic migration without bulk flow of solvents therethrough. The salt bridges form barriers that seal against fluid pressures in excess of 5000 pounds per square inch. The salt bridges can be formulated for carriage of suitable amperage at a desired voltage, and thus microfluidic devices using such salt bridges can be specifically constructed to meet selected analytical requirements.

Shepodd, Timothy J. (Livermore, CA); Tichenor, Mark S. (San Diego, CA); Artau, Alexander (Humacao, PR)

2009-11-17T23:59:59.000Z

254

Pyrochemical process for extracting plutonium from an electrolyte salt  

DOE Patents (OSTI)

A pyrochemical process for extracting plutonium from a plutonium-bearing salt is disclosed. The process is particularly useful in the recovery of plutonium from electrolyte salts which are left over from the electrorefining of plutonium. In accordance with the process, the plutonium-bearing salt is melted and mixed with metallic calcium. The calcium reduces ionized plutonium in the salt to plutonium metal, and also causes metallic plutonium in the salt, which is typically present as finely dispersed metallic shot, to coalesce. The reduced and coalesced plutonium separates out on the bottom of the reaction vessel as a separate metallic phase which is readily separable from the overlying salt upon cooling of the mixture. Yields of plutonium are typically on the order of 95%. The stripped salt is virtually free of plutonium and may be discarded to low-level waste storage.

Mullins, Lawrence J. (Los Alamos, NM); Christensen, Dana C. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

255

Cementitious Stabilization of Mixed Wastes with High Salt Loadings  

SciTech Connect

Salt loadings approaching 50 wt % were tolerated in cementitious waste forms that still met leach and strength criteria, addressing a Technology Deficiency of low salt loadings previously identified by the Mixed Waste Focus Area. A statistical design quantified the effect of different stabilizing ingredients and salt loading on performance at lower loadings, allowing selection of the more effective ingredients for studying the higher salt loadings. In general, the final waste form needed to consist of 25 wt % of the dry stabilizing ingredients to meet the criteria used and 25 wt % water to form a workable paste, leaving 50 wt % for waste solids. The salt loading depends on the salt content of the waste solids but could be as high as 50 wt % if all the waste solids are salt.

Spence, R.D.; Burgess, M.W.; Fedorov, V.V.; Downing, D.J.

1999-04-01T23:59:59.000Z

256

Pyrochemical process for extracting plutonium from an electrolyte salt  

DOE Patents (OSTI)

A pyrochemical process for extracting plutonium from a plutonium-bearing salt is disclosed. The process is particularly useful in the recovery of plutonium for electrolyte salts which are left over from the electrorefining of plutonium. In accordance with the process, the plutonium-bearing salt is melted and mixed with metallic calcium. The calcium reduces ionized plutonium in the salt to plutonium metal, and also causes metallic plutonium in the salt, which is typically present as finely dispersed metallic shot, to coalesce. The reduced and coalesced plutonium separates out on the bottom of the reaction vessel as a separate metallic phase which is readily separable from the overlying salt upon cooling of the mixture. Yields of plutonium are typically on the order of 95%. The stripped salt is virtually free of plutonium and may be discarded to low-level waste storage.

Mullins, L.J.; Christensen, D.C.

1982-09-20T23:59:59.000Z

257

Reference repository design concept for bedded salt  

Science Conference Proceedings (OSTI)

A reference design concept is presented for the subsurface portions of a nuclear waste repository in bedded salt. General geologic, geotechnical, hydrologic and geochemical data as well as descriptions of the physical systems are provided for use on generic analyses of the pre- and post-sealing performance of repositories in this geologic medium. The geology of bedded salt deposits and the regional and repository horizon stratigraphy are discussed. Structural features of salt beds including discontinuities and dissolution features are presented and their effect on repository performance is discussed. Seismic hazards and the potential effects of earthquakes on underground repositories are presented. The effect on structural stability and worker safety during construction from hydrocarbon and inorganic gases is described. Geohydrologic considerations including regional hydrology, repository scale hydrology and several hydrological failure modes are presented in detail as well as the hydrological considerations that effect repository design. Operational phase performance is discussed with respect to operations, ventilation system, shaft conveyances, waste handling and retrieval systems and receival rates of nuclear waste. Performance analysis of the post sealing period of a nuclear repository is discussed, and parameters to be used in such an analysis are presented along with regulatory constraints. Some judgements are made regarding hydrologic failure scenarios. Finally, the design and licensing process, consistent with the current licensing procedure is described in a format that can be easily understood.

Carpenter, D.W.; Martin, R.W.

1980-10-08T23:59:59.000Z

258

NITRATE CONVERSION OF HB-LINE REILLEXTM HPQ RESIN  

SciTech Connect

Reillex{trademark} HPQ ion exchange resin is used by HB Line to remove plutonium from aqueous streams. Reillex{trademark} HPQ resin currently available from Vertellus Specialties LLC is a chloride ionic form, which can cause stress corrosion cracking in stainless steels. Therefore, HB Line Engineering requested that Savannah River National Laboratory (SRNL) convert resin from chloride form to nitrate form in the Engineering Development Laboratory (EDL). To perform this task, SRNL treated two batches of resin in 2012. The first batch of resin from Reilly Industries Batch 80302MA was initially treated at SRNL in 2001 to remove chloride. This batch of resin, nominally 30 liters, has been stored wet in carboys since that time until being retreated in 2012. The second batch of resin from Batch 23408 consisted of 50 kg of new resin purchased from Vertellus Specialties in 2012. Both batches were treated in a column designed to convert resin using downflow of 1.0 M sodium nitrate solution through the resin bed followed by rinsing with deionized water. Both batches were analyzed for chloride concentration, before and after treatment, using Neutron Activation Analysis (NAA). The resin specification [Werling, 2003] states the total chlorine and chloride concentration shall be less than 250 ppm. The resin condition for measuring this concentration is not specified; however, in service the resin would always be fully wet. Measurements in SRNL showed that changing from oven dry resin to fully wet resin, with liquid in the particle interstices but no supernatant, increases the total weight by a factor of at least three. Therefore, concentration of chlorine or chloride expressed as parts per million (ppm) decreases by a factor of three. Therefore, SRNL recommends measuring chlorine concentration on an oven dry basis, then dividing by three to estimate chloride concentration in the fully wet condition. Chloride concentration in the first batch (No.80302MA) was nearly the same before the current treatment (759 ppm dry) and after treatment (745 ppm dry or {approx}248 ppm wet). Treatment of the second batch of resin (No.23408) was very successful. Chloride concentration decreased from 120,000 ppm dry to an average of 44 ppm dry or {approx}15ppm wet, which easily passes the 250 ppm wet criterion. Per guidance from HB Line Engineering, SRNL blended Batch 80302 resin with Batch P9059 resin which had been treated previously by ResinTech to remove chloride. The chloride concentrations for the two drums of Batch P9059 were 248 ppm dry ({approx}83 ppm wet) {+-}22.8% and 583 ppm dry ({approx}194 ppm wet) {+-} 11.8%. The blended resin was packaged in five gallon buckets.

Steimke, J.; Williams, M.; Steeper, T.; Leishear, R.

2012-05-29T23:59:59.000Z

259

An Overview of Liquid Fluoride Salt Heat Transport Technology  

SciTech Connect

Liquid fluoride salts are a leading candidate heat transport medium for high-temperature applications. This report provides an overview of the current status of liquid salt heat transport technology. The report includes a high-level, parametric evaluation of liquid fluoride salt heat transport loop performance to allow intercomparisons between heat-transport fluid options as well as providing an overview of the properties and requirements for a representative loop. Much of the information presented here derives from the earlier molten salt reactor program and a significant advantage of fluoride salts, as high temperature heat transport media is their consequent relative technological maturity. The report also includes a compilation of relevant thermophysical properties of useful heat transport fluoride salts. Fluoride salts are both thermally stable and with proper chemistry control can be relatively chemically inert. Fluoride salts can, however, be highly corrosive depending on the container materials selected, the salt chemistry, and the operating procedures used. The report also provides an overview of the state-of-the-art in reduction-oxidation chemistry control methodologies employed to minimize salt corrosion as well as providing a general discussion of heat transfer loop operational issues such as start-up procedures and freeze-up vulnerability.

Cetiner, Mustafa Sacit [ORNL; Holcomb, David Eugene [ORNL

2010-01-01T23:59:59.000Z

260

Salt disposal of heat-generating nuclear waste.  

SciTech Connect

This report summarizes the state of salt repository science, reviews many of the technical issues pertaining to disposal of heat-generating nuclear waste in salt, and proposes several avenues for future science-based activities to further the technical basis for disposal in salt. There are extensive salt formations in the forty-eight contiguous states, and many of them may be worthy of consideration for nuclear waste disposal. The United States has extensive experience in salt repository sciences, including an operating facility for disposal of transuranic wastes. The scientific background for salt disposal including laboratory and field tests at ambient and elevated temperature, principles of salt behavior, potential for fracture damage and its mitigation, seal systems, chemical conditions, advanced modeling capabilities and near-future developments, performance assessment processes, and international collaboration are all discussed. The discussion of salt disposal issues is brought current, including a summary of recent international workshops dedicated to high-level waste disposal in salt. Lessons learned from Sandia National Laboratories' experience on the Waste Isolation Pilot Plant and the Yucca Mountain Project as well as related salt experience with the Strategic Petroleum Reserve are applied in this assessment. Disposal of heat-generating nuclear waste in a suitable salt formation is attractive because the material is essentially impermeable, self-sealing, and thermally conductive. Conditions are chemically beneficial, and a significant experience base exists in understanding this environment. Within the period of institutional control, overburden pressure will seal fractures and provide a repository setting that limits radionuclide movement. A salt repository could potentially achieve total containment, with no releases to the environment in undisturbed scenarios for as long as the region is geologically stable. Much of the experience gained from United States repository development, such as seal system design, coupled process simulation, and application of performance assessment methodology, helps define a clear strategy for a heat-generating nuclear waste repository in salt.

Leigh, Christi D. (Sandia National Laboratories, Carlsbad, NM); Hansen, Francis D.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Thermal decomposition study of hydroxylamine nitrate during storage and handling  

E-Print Network (OSTI)

Hydroxylamine nitrate (HAN), an important agent for the nuclear industry and the U.S. Army, has been involved in several costly incidents. To prevent similar incidents, the study of HAN safe storage and handling boundary has become extremely important for industries. However, HAN decomposition involves complicated reaction pathways due to its autocatalytic behavior and therefore presents a challenge for definition of safe boundaries of HAN storage and handling. This research focused on HAN decomposition behavior under various conditions and proposed isothermal aging testing and kinetic-based simulation to determine safety boundaries for HAN storage and handling. Specifically, HAN decomposition in the presence of glass, titanium, stainless steel with titanium, or stainless steel was examined in an Automatic Pressure Tracking Adiabatic Calorimeter (APTAC). n-th order kinetics was used for initial reaction rate estimation. Because stainless steel is a commonly used material for HAN containers, isothermal aging tests were conducted in a stainless steel cell to determine the maximum safe storage time of HAN. Moreover, by changing thermal inertia, data for HAN decomposition in the stainless steel cell were examined and the experimental results were simulated by the Thermal Safety Software package. This work offers useful guidance for industries that manufacture, handle, and store HAN. The experimental data acquired not only can help with aspects of process safety design, including emergency relief systems, process control, and process equipment selection, but also is a useful reference for the associated theoretical study of autocatalytic decomposition behavior.

Zhang, Chuanji

2003-05-01T23:59:59.000Z

262

Supai salt karst features: Holbrook Basin, Arizona  

SciTech Connect

More than 300 sinkholes, fissures, depressions, and other collapse features occur along a 70 km (45 mi) dissolution front of the Permian Supai Formation, dipping northward into the Holbrook Basin, also called the Supai Salt Basin. The dissolution front is essentially coincident with the so-called Holbrook Anticline showing local dip reversal; rather than being of tectonic origin, this feature is likely a subsidence-induced monoclinal flexure caused by the northward migrating dissolution front. Three major areas are identified with distinctive attributes: (1) The Sinks, 10 km WNW of Snowflake, containing some 200 sinkholes up to 200 m diameter and 50 m depth, and joint controlled fissures and fissure-sinks; (2) Dry Lake Valley and contiguous areas containing large collapse fissures and sinkholes in jointed Coconino sandstone, some of which drained more than 50 acre-feet ({approximately}6 {times} 10{sup 4} m{sup 3}) of water overnight; and (3) the McCauley Sinks, a localized group of about 40 sinkholes 15 km SE of Winslow along Chevelon Creek, some showing essentially rectangular jointing in the surficial Coconino Formation. Similar salt karst features also occur between these three major areas. The range of features in Supai salt are distinctive, yet similar to those in other evaporate basins. The wide variety of dissolution/collapse features range in development from incipient surface expression to mature and old age. The features began forming at least by Pliocene time and continue to the present, with recent changes reportedly observed and verified on airphotos with 20 year repetition. The evaporate sequence along interstate transportation routes creates a strategic location for underground LPG storage in leached caverns. The existing 11 cavern field at Adamana is safely located about 25 miles away from the dissolution front, but further expansion initiatives will require thorough engineering evaluation.

Neal, J.T.

1994-12-31T23:59:59.000Z

263

Independent Oversight Assessment, Salt Waste Processing Facility Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Salt Waste Processing Facility Salt Waste Processing Facility Project - January 2013 Independent Oversight Assessment, Salt Waste Processing Facility Project - January 2013 January 2013 Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility Project The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), conducted an independent assessment of nuclear safety culture at the Salt Waste Processing Facility (SWPF) Project. The primary objective of the evaluation was to provide information regarding the status of the safety culture at the SWPF Project. The data collection phase of the assessment occurred during August - September 2012. Independent Oversight Assessment, Salt Waste Processing Facility Project -

264

Disposing of nuclear waste in a salt bed  

NLE Websites -- All DOE Office Websites (Extended Search)

Disposing of nuclear waste in a salt bed Disposing of nuclear waste in a salt bed 1663 Los Alamos science and technology magazine Latest Issue:November 2013 All Issues » submit Disposing of nuclear waste in a salt bed Decades' worth of transuranic waste from Los Alamos is being laid to rest at the Waste Isolation Pilot Plant in southeastern New Mexico March 25, 2013 Disposing of nuclear waste in a salt bed Depending on the impurities embedded within it, the salt from WIPP can be anything from a reddish, relatively opaque rock to a clear crystal like the one shown here. Ordinary salt effectively seals transuranic waste in a long-term repository Transuranic waste, made of items such as lab coats and equipment that have been contaminated by radioactive elements heavier than uranium, is being shipped from the Los Alamos National Laboratory to a long-term storage

265

Genomic insights into salt adaptation in a desert poplar  

SciTech Connect

Despite the high economic and ecological importance of forests, our knowledge of the genomic evolution of trees under salt stress remains very limited. Here we report the genome sequence of the desert poplar, Populus euphratica, which exhibits high tolerance to sa lt stress. Its genome is very similar and collinear to that of the closely related mesophytic congener, P trichocarpa. However, we find that several gene families likely to be involved in tolerance to salt stress contain significantly more gene copies within the P euphratica lineage. Furthermore, genes showing evidence of positive selection are significantly enriched in functional categories related to salt stress. Some of these genes, and others within the same categories, are significantly upregulated under salt stress relative to their expression in another salt-sensitive poplar. Our results provide an important background for understanding tree adaptation to salt stress and facilitating the genetic improvement of cultivated poplars for saline soils.

Ma, Tao [Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences] [Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences; Wang, Junyi [BGI-Shenzhen, China] [BGI-Shenzhen, China; Zhou, Gongke [Key laboratory of Biofuels and Shandong Provincial Key Laboratory of Energy Genetics, Qingdao Instit] [Key laboratory of Biofuels and Shandong Provincial Key Laboratory of Energy Genetics, Qingdao Instit; Yue, Zhen [BGI-Shenzhen, China] [BGI-Shenzhen, China; Hu, Quanjun [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Chen, Yan [BGI-Shenzhen, China] [BGI-Shenzhen, China; Liu, Bingbing [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Qiu, Qiang [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Wang, Zhuo [BGI-Shenzhen, China] [BGI-Shenzhen, China; Zhang, Jian [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Wang, Kun [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Jaing, Dechun [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Gou, Caiyun [BGI-Shenzhen, China] [BGI-Shenzhen, China; Yu, Lili [BGI-Shenzhen, China] [BGI-Shenzhen, China; Zhan, Dongliang [BGI-Shenzhen, China] [BGI-Shenzhen, China; Zhou, Ran [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Luo, Wenchun [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Ma, Hui [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Yang, Yongzhi [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Pan, Shengkai [BGI-Shenzhen, China] [BGI-Shenzhen, China; Fang, Dongming [BGI-Shenzhen, China] [BGI-Shenzhen, China; Luo, Yadan [BGI-Shenzhen, China] [BGI-Shenzhen, China; Wang, Xia [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Wang, Gaini [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Wang, Juan [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Wang, Qian [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Lu, Xu [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Chen, Zhe [BGI-Shenzhen, China] [BGI-Shenzhen, China; Liu, Jinchao [BGI-Shenzhen, China] [BGI-Shenzhen, China; Lu, Yao [BGI-Shenzhen, China] [BGI-Shenzhen, China; Yin, Ye [BGI-Shenzhen, China] [BGI-Shenzhen, China; Yang, Huanming [BGI-Shenzhen, China] [BGI-Shenzhen, China; Abbott, Richard [School of Biology, University of St. Andrews, St andrews, Fife KY16 9TH, UK] [School of Biology, University of St. Andrews, St andrews, Fife KY16 9TH, UK; Wu, Yuxia [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Wan, Dongshi [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University; Li, Jia [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University] [State Key Laboratory of Grassland Agro-Ecosystem, Lanzhou University

2013-01-01T23:59:59.000Z

266

Integrated demonstration of molten salt oxidation with salt recycle for mixed waste treatment  

Science Conference Proceedings (OSTI)

Molten Salt Oxidation (MSO) is a thermal, nonflame process that has the inherent capability of completely destroying organic constituents of mixed wastes, hazardous wastes, and energetic materials while retaining inorganic and radioactive constituents in the salt. For this reason, MSO is considered a promising alternative to incineration for the treatment of a variety of organic wastes. Lawrence Livermore National Laboratory (LLNL) has prepared a facility and constructed an integrated pilot-scale MSO treatment system in which tests and demonstrations are performed under carefully controlled (experimental) conditions. The system consists of a MSO processor with dedicated off-gas treatment, a salt recycle system, feed preparation equipment, and equipment for preparing ceramic final waste forms. This integrated system was designed and engineered based on laboratory experience with a smaller engineering-scale reactor unit and extensive laboratory development on salt recycle and final forms preparation. In this paper we present design and engineering details of the system and discuss its capabilities as well as preliminary process demonstration data. A primary purpose of these demonstrations is identification of the most suitable waste streams and waste types for MSO treatment.

Hsu, P.C.

1997-11-01T23:59:59.000Z

267

Delivery system for molten salt oxidation of solid waste  

DOE Patents (OSTI)

The present invention is a delivery system for safety injecting solid waste particles, including mixed wastes, into a molten salt bath for destruction by the process of molten salt oxidation. The delivery system includes a feeder system and an injector that allow the solid waste stream to be accurately metered, evenly dispersed in the oxidant gas, and maintained at a temperature below incineration temperature while entering the molten salt reactor.

Brummond, William A. (Livermore, CA); Squire, Dwight V. (Livermore, CA); Robinson, Jeffrey A. (Manteca, CA); House, Palmer A. (Walnut Creek, CA)

2002-01-01T23:59:59.000Z

268

Salts of alkali metal anions and process of preparing same  

DOE Patents (OSTI)

Compounds of alkali metal anion salts of alkali metal cations in bicyclic polyoxadiamines are disclosed. The salts are prepared by contacting an excess of alkali metal with an alkali metal dissolving solution consisting of a bicyclic polyoxadiamine in a suitable solvent, and recovered by precipitation. The salts have a gold-color crystalline appearance and are stable in a vacuum at -10.degree. C. and below.

Dye, James L. (East Lansing, MI); Ceraso, Joseph M. (Lansing, MI); Tehan, Frederick J. (Utica, NY); Lok, Mei Tak (Urbana, IL)

1978-01-01T23:59:59.000Z

269

Long-duration thermal storage for solar-thermal high-pressure steam IPH  

DOE Green Energy (OSTI)

Solar-thermal central-receiver systems are cost effective for electric-power and industrial process-heat applications. Systems employing molten nitrate salt as both receiver working fluid and storage have previously been evaluated for diurnal thermal storage. This study evaluates the potential of employing a molten salt receiver for a baseload industrial process plant requiring saturated steam at 68 atm (1000 psi). Two types of thermal storage are evaluated: molten salt, and air and rock. When thermal storage of six hours or less is used, molten nitrate salt alone is the optimum storage. For more than six hours, the optimum storage is a combination of molten salt and air and rock. The air and rock system uses a molten-salt-to-air heat exchanger and a thermocline rock bed heated and cooled by the air. The economic potential of the system is determined. The results depend on the relative cost of fossil fuel and the solar thermal energy costs. The optimum quantity of storage is highly variable, and the range is from no storage to a long duration capacity - 48 hours.

Copeland, R.J.; Stern, C.; Leach, J.W.

1982-12-01T23:59:59.000Z

270

Columbus Salt Marsh Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Columbus Salt Marsh Geothermal Area Columbus Salt Marsh Geothermal Area (Redirected from Columbus Salt Marsh Area) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Columbus Salt Marsh Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (0) 9 Exploration Activities (3) 10 References Area Overview Geothermal Area Profile Location: California Exploration Region: Walker-Lane Transition Zone Geothermal Region GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure

271

Surface Indicators of Geothermal Activity at Salt Wells, Nevada...  

Open Energy Info (EERE)

Surface Indicators of Geothermal Activity at Salt Wells, Nevada, USA, Including Warm Ground, Borate Deposits, and Siliceous Alteration Jump to: navigation, search OpenEI Reference...

272

Development Wells At Salt Wells Area (Nevada Bureau of Mines...  

Open Energy Info (EERE)

Development Wells At Salt Wells Area (Nevada Bureau of Mines and Geology, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Development Wells...

273

Compound and Elemental Analysis At Salt Wells Area (Shevenell...  

Open Energy Info (EERE)

Compound and Elemental Analysis At Salt Wells Area (Shevenell & Garside, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and...

274

Natural Convection Fluoride Salt High Temperature Reactor Process ...  

... oil shale processing, hydrogen production, and production of synfuels from coal. The new nuclear reactor design employs a molten salt coolant in a natural ...

275

Energy Department Completes Salt Coolant Material Transfer to...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Republic's Ministry of Industry and Trade to complete the transfer of 75 kilograms of fluoride salt from the Department's Oak Ridge National Laboratory (ORNL) to the Czech Nuclear...

276

Electrochemical Behavior of Calcium-Bismuth Alloys in Molten Salt ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The electrochemical properties of calcium-bismuth alloys were investigated to ... Behavior of Silicon Electrodepositing in Fluoride Molten Salts.

277

Synthesis of acid addition salt of delta-aminolevulinic acid ...  

A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a ...

278

Haynesville-Bossier Shale Play, Texas-Louisiana Salt Basin  

U.S. Energy Information Administration (EIA)

Haynesville-Bossier Shale Play, Texas-Louisiana Salt Basin Source: Energy Information Administration based on data from HPDI, TX Railroad Commission, ...

279

Savannah River Site (SRS) Experience with Preparing Salt Batches  

• Beneficially reuse existing waste. 6 SRS Liquid Waste System Salt Processing. 7 Background • Tk49 is the feed tank to ARP / MCU facilities

280

Molten salt bath circulation design for an electrolytic cell  

DOE Patents (OSTI)

An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride.

Dawless, Robert K. (Monroeville, PA); LaCamera, Alfred F. (Trafford, PA); Troup, R. Lee (Murrysville, PA); Ray, Siba P. (Murrysville, PA); Hosler, Robert B. (Sarver, PA)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Salt Fluxes for Alkali and Alkaline Earth Element Removal from ...  

Science Conference Proceedings (OSTI)

Sep 1, 2001... for Alkali and Alkaline Earth Element Removal from Molten Aluminum ... Solid chloride salts containing MgC2 can be used to remove alkali ...

282

Ion Beam Experiment to Simulate Simultaneous Molten Salt ...  

Science Conference Proceedings (OSTI)

Experiments to expose candidate materials to simultaneous molten salt corrosion and ion-beam damage are staged at the Ion Beam Materials Laboratory at Los ...

283

Molten Salt Electrolysis for the Synthesis of Elemental Boron  

Science Conference Proceedings (OSTI)

An alternative method using molten salt electrolysis was developed in this work. The electrolyte system evaluated was MgF2-NaF-LiF with ...

284

Molten salt bath circulation design for an electrolytic cell  

DOE Patents (OSTI)

An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride. 4 figs.

Dawless, R.K.; LaCamera, A.F.; Troup, R.L.; Ray, S.P.; Hosler, R.B.

1999-08-17T23:59:59.000Z

285

Sensor Technology for Real Time Monitoring of Molten Salt ...  

Science Conference Proceedings (OSTI)

Presentation Title, Sensor Technology for Real Time Monitoring of Molten Salt Electrolytes During Nuclear Fuel Electrorefining. Author(s), Michael F. Simpson, ...

286

Method for the production of uranium chloride salt  

DOE Patents (OSTI)

A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

Westphal, Brian R.; Mariani, Robert D.

2013-07-02T23:59:59.000Z

287

Review of the Savannah River Site Salt Waste Processing Facility...  

NLE Websites -- All DOE Office Websites (Extended Search)

River Site Salt Waste Processing Facility Safety Basis and Design Development May 2011 August 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement...

288

Evaluation of the Miamsburg Salt-Gradient, Solar Pond  

SciTech Connect

This project is directed toward data collection and evaluation of the performance of the largest working, salt-gradient, solar pond in the world.

Wittenberg, Layton J.

1978-09-01T23:59:59.000Z

289

Regional Gravity Survey of the Northern Great Salt Lake Desert...  

Open Energy Info (EERE)

of the Northern Great Salt Lake Desert and Adjacent Areas in Utah, Nevada, and Idaho Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Regional Gravity...

290

Electroactive Materials for Anion Separation - Technetium from Nitrate  

DOE Green Energy (OSTI)

Many contaminants of interest to the U.S. Department of Energy (DOE) exist as anions. These include the high priority pollutants chromate, pertechnetate, and nitrate ions. In addition, there are also industrial and urban applications where the separation of anionic species from aqueous streams is critical. Examples include industrial water recycle and waste water treatment (e.g., chloride ion removal for the pulp and paper industry, borate ion in the chemical and nuclear industries) and drinking water and agricultural waste treatment (e.g., nitrate removal). In the proposed research, technetium is chosen as the target pollutant. Because of its half-life of 213,000 years, technetium (99Tc) presents a long-term hazard for waste disposal. Much of the 99Tc in the tank wastes is present as pertechnetate (TcO4-), accounting for its high solubility and mobility in aqueous systems. Several sorbents are available for removing TcO4- from alkaline waste brines, but each has important drawbacks. The use of commercial ion exchange (IX) resins to extract TcO4-, e.g., Reillex{trademark}-HPQ (Reilly Industries) and ABEC 5000 (Eichrom Industries), generates significant secondary waste. The elution of TcO4- from Reillex{trademark}-HPQ resins requires either concentrated nitric acid or a concentrated caustic solution of ethylene-diamine containing a small amount of tin chloride. This eluant has a short shelf life requiring frequent preparation, and the 99Tc is delivered in a complexed, reduced form. While TcO4- can be eluted from ABEC 5000 resins using de-ionized water, the much-reduced capacity of ABEC 5000 resins in comparison to the Reillex{trademark}-HPQ resins leads to a low column capacity. In general, unwanted secondary wastes are generated because (1) the only effective eluant happens to be hazardous and/or (2) the IX material has a low capacity or selectivity for the target ion, resulting in more frequent elution and column replacements. Alternative IX materials that have high capacities, can be regenerated easily, and are highly selective for TcO4- would avoid these problems. Electrochemically active IX media meet these criteria. Such an IX system uses electrically induced changes in the media to expel sorbed ions through a charge imbalance rather than requiring chemical eluants to ''strip'' them. Therefore, this medium eliminates the need to prepare, store, and dispose of many of the process chemicals normally required for IX operations. The focus of the project is to develop a fundamental understanding of how the physical and chemical properties of electroactive ion exchange (EaIX) materials control their efficiency when used as mass separation agents. Specifically, the desirable characteristics of EaIX materials for separation applications are (1) high reversibility, (2) high selectivity, (3) acceptable physical and chemical stability, (4) rapid intercalation and de-intercalation rates, and (5) high capacity. Because of these requirements, EaIX materials share many properties in common with conventional ion exchangers and electroactive polymers. For example, EaIX materials require the selectivity typically found in ion exchangers; they also require the redox reversibility of electroactive polymers. The results of this work will allow the rational design of new materials and processes tailored for the separation of specific anions.

Sukamto, Johanes H.; Smyrl, William H.; McBreen, James; Hubler, Timothy L.; Lilga, Michael A.

2000-06-01T23:59:59.000Z

291

An Overview of Liquid Fluoride Salt Heat Transport Systems  

SciTech Connect

Heat transport is central to all thermal-based forms of electricity generation. The ever increasing demand for higher thermal efficiency necessitates power generation cycles transitioning to progressively higher temperatures. Similarly, the desire to provide direct thermal coupling between heat sources and higher temperature chemical processes provides the underlying incentive to move toward higher temperature heat transfer loops. As the system temperature rises, the available materials and technology choices become progressively more limited. Superficially, fluoride salts at {approx}700 C resemble water at room temperature being optically transparent and having similar heat capacity, roughly three times the viscosity, and about twice the density. Fluoride salts are a leading candidate heat-transport material at high temperatures. Fluoride salts have been extensively used in specialized industrial processes for decades, yet they have not entered widespread deployment for general heat transport purposes. This report does not provide an exhaustive screening of potential heat transfer media and other high temperature liquids such as alkali metal carbonate eutectics or chloride salts may have economic or technological advantages. A particular advantage of fluoride salts is that the technology for their use is relatively mature as they were extensively studied during the 1940s-1970s as part of the U.S. Atomic Energy Commission's program to develop molten salt reactors (MSRs). However, the instrumentation, components, and practices for use of fluoride salts are not yet developed sufficiently for commercial implementation. This report provides an overview of the current understanding of the technologies involved in liquid salt heat transport (LSHT) along with providing references to the more detailed primary information resources. Much of the information presented here derives from the earlier MSR program. However, technology has evolved over the intervening years, and this report also describes more recently developed technologies such as dry gas seals. This report also provides a high-level, parametric evaluation of LSHT loop performance to allow general intercomparisons between heat-transport fluid options as well as provide an overview of the properties and requirements for a representative loop. A compilation of relevant thermophysical properties of useful fluoride salts is also included for salt heat transport systems. Fluoride salts can be highly corrosive depending on the container materials selected, the salt chemistry, and the operating procedures used. The report includes an overview of the state-of-the-art in reduction-oxidation chemistry control methodologies employed to minimize corrosion issues. Salt chemistry control technology, however, remains at too low a level of understanding for widespread industrial usage. Loop operational issues such as start-up procedures and system freeze-up vulnerability are also discussed. Liquid fluoride salts are a leading candidate heat transport medium for high-temperature applications. This report provides an overview of the current status of liquid salt heat transport technology. The report includes a high-level, parametric evaluation of liquid fluoride salt heat transport loop performance to allow intercomparisons between heat-transport fluid options as well as providing an overview of the properties and requirements for a representative loop. Much of the information presented here derives from the earlier molten salt reactor program and a significant advantage of fluoride salts, as high temperature heat transport media is their consequent relative technological maturity. The report also includes a compilation of relevant thermophysical properties of useful heat transport fluoride salts. Fluoride salts are both thermally stable and with proper chemistry control can be relatively chemically inert. Fluoride salts can, however, be highly corrosive depending on the container materials selected, the salt chemistry, and the operating procedures used. The report also provides an over

Holcomb, David Eugene [ORNL; Cetiner, Mustafa Sacit [ORNL

2010-09-01T23:59:59.000Z

292

Structural restoration of Louann Salt and overlying sediments, De Soto Canyon Salt Basin, northeastern Gulf of Mexico  

E-Print Network (OSTI)

The continental margin of the northeastern Gulf of Mexico is suited for seismic stratigraphic analysis and salt tectonism analysis. Jurassic strata include the Louann Salt on the continental shelf and upper slope of the Destin Dome OCS area, northeastern Gulf of Mexico. These sediments were deposited in a slowly subsiding, stable tectonic environment. Two-dimensional (2-D) seismic data, supplemented with well log, paleontologic and velocity information were used to infer structural and stratigraphic features, especially small faults in the deep part of the De Soto Canyon Salt Basin area. Six sequence boundaries or correlative paleohorizons were interpreted on Landmark seismic interpretation workstation. They are Base of Salt or Equivalent, Top of Salt, Top of Smackover Formation, Top of Cotton Valley Group, Middle Cretaceous sequence boundary, and Top of Upper Cretaceous. Information generated from structural and stratigraphic analysis are used to analyze the evolution of salt movement and salt mechanism in this area. I used a software package Restore (Dan Schultz-Ela and Ken Duncan, 1991) for structural restoration. This program is suitable for extensional terrane. The restoration of one depth section was achieved through steps introduced by Restore. Regional extension, gravity spreading, and gliding are the most important mechanism of salt flow, buoyancy and differential loading mainly contribute to the vertical development of salt structure in this area.

Guo, Mengdong

1997-01-01T23:59:59.000Z

293

Savannah River Site - Salt Waste Processing Facility: Briefing on the Salt Waste Processing Facility Independent Technical Review  

Energy.gov (U.S. Department of Energy (DOE))

This is a presentation outlining the Salt Waste Processing Facility process, major risks, approach for conducting reviews, discussion of the findings, and conclusions.

294

Ketone Production from the Thermal Decomposition of Carboxylate Salts  

E-Print Network (OSTI)

The MixAlco process uses an anaerobic, mixed-culture fermentation to convert lignocellulosic biomass to carboxylate salts. The fermentation broth must be clarified so that only carboxylate salts, water, and minimal impurities remain. Carboxylate salts are concentrated by evaporation and thermally decomposed into ketones. The ketones can then be chemically converted to a wide variety of chemicals and fuels. The presence of excess lime in the thermal decomposition step reduced product yield. Mixtures of calcium carboxylate salts were thermally decomposed at 450 degrees C. Low lime-to-salt ratios (g Ca(OH)2/g salt) of 0.00134 and less had a negligible effect on ketone yield. In contrast, salts with higher lime-to-salt ratios of 0.00461, 0.0190, and 0.272 showed 3.5, 4.6, and 9.4% loss in ketone yield, respectively. These losses were caused primarily by increases in tars and heavy oils; however, a three-fold increase in hydrocarbon production occurred as well. To predict ketone product distribution, a random-pairing and a Gibbs free energy minimization model were applied to thermal decompositions of mixed calcium and sodium carboxylate salts. Random pairing appears to better predict ketone product composition. For sodium and calcium acetate, two types of mixed sodium carboxylate salts, and two types of mixed calcium carboxylate salts, activation energy (EA) was determined using three isoconversional methods. For each salt type, EA varied significantly with conversion. The average EA for sodium and calcium acetate was 226.65 and 556.75 kJ/mol, respectively. The average EA for the two mixed sodium carboxylate salts were 195.61, and 218.18 kJ/mol. The average EA for the two mixed calcium carboxylate salts were 232.78, and 176.55 kJ/mol. In addition, three functions of conversion were employed to see which one best modeled the experimental data. The Sestak-Berggren model was the best overall. Possible reactor designs and configurations that address the challenges associated with the continuous thermal decomposition of carboxylate salts are also presented and discussed. Methods of fermentation broth clarification were tested. Flocculation showed little improvement in broth purity. Coagulation yielded broth of 93.23% purity. Filtration using pore sizes from 1 micrometer to 240 Daltons increased broth purity (90.79 to 98.33%) with decreasing pore size.

Landoll, Michael 1984-

2012-12-01T23:59:59.000Z

295

Impaired mitochondrial respiration and protein nitration in the rat hippocampus after acute inhalation of combustion smoke  

SciTech Connect

Survivors of massive inhalation of combustion smoke endure critical injuries, including lasting neurological complications. We have previously reported that acute inhalation of combustion smoke disrupts the nitric oxide homeostasis in the rat brain. In this study, we extend our findings and report that a 30-minute exposure of awake rats to ambient wood combustion smoke induces protein nitration in the rat hippocampus and that mitochondrial proteins are a sensitive nitration target in this setting. Mitochondria are central to energy metabolism and cellular signaling and are critical to proper cell function. Here, analyses of the mitochondrial proteome showed elevated protein nitration in the course of a 24-hour recovery following exposure to smoke. Mass spectrometry identification of several significantly nitrated mitochondrial proteins revealed diverse functions and involvement in central aspects of mitochondrial physiology. The nitrated proteins include the ubiquitous mitochondrial creatine kinase, F1-ATP synthase {alpha} subunit, dihydrolipoamide dehydrogenase (E3), succinate dehydrogenase Fp subunit, and voltage-dependent anion channel (VDAC1) protein. Furthermore, acute exposure to combustion smoke significantly compromised the respiratory capacity of hippocampal mitochondria. Importantly, elevated protein nitration and reduced mitochondrial respiration in the hippocampus persisted beyond the time required for restoration of normal oxygen and carboxyhemoglobin blood levels after the cessation of exposure to smoke. Thus, the time frame for intensification of the various smoke-induced effects differs between blood and brain tissues. Taken together, our findings suggest that nitration of essential mitochondrial proteins may contribute to the reduction in mitochondrial respiratory capacity and underlie, in part, the brain pathophysiology after acute inhalation of combustion smoke.

Lee, Heung M.; Reed, Jason; Greeley, George H. [Department of Surgery, University of Texas Medical Branch (United States); Englander, Ella W. [Department of Surgery, University of Texas Medical Branch (United States); Shriners Hospitals for Children, Galveston, TX (United States)], E-mail: elenglan@utmb.edu

2009-03-01T23:59:59.000Z

296

Synthesis of permethyldodecaborate and paramagnetic dodecaborate salt  

DOE Patents (OSTI)

The dodecamethyl closo-borane dianion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.2- and anion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.- were synthesized and characterized. Dodecamethyl-closo dodecaborate (2-) was produced from [closo-B.sub.12 H.sub.12 ].sup.2-, using trimethylaluminum, and methyl iodide and modified Friedel-Crafts reaction conditions. The anion was produced from the dianion by chemical oxidation using ceric (4) ammonium nitrate in acetonitrile. The anion and dianion were both characterized by .sup.1 H and .sup.11 B NMR spectroscopy, high-resolution fast atom bombardment (FAB) mass spectrometry, cyclic voltammetry, and single-crystal X-ray diffraction. The "camouflaged" polyhedral borane anion [closo-B.sub.12 (CH.sub.3).sub.12 ].sup.2-, can be used as a precursor to materials that offer a broad spectrum of novel applications ranging from drug applications and supramolecular chemistry to use as a weakly-coordinating dianion.

Hawthorne, M. Frederick (Encino, CA); Peymann, Toralf (Los Angeles, CA)

2002-01-01T23:59:59.000Z

297

Treatment of plutonium process residues by molten salt oxidation  

Science Conference Proceedings (OSTI)

Molten Salt Oxidation (MSO) is a thermal process that can remove more than 99.999% of the organic matrix from combustible {sup 238}Pu material. Plutonium processing residues are injected into a molten salt bed with an excess of air. The salt (sodium carbonate) functions as a catalyst for the conversion of the organic material to carbon dioxide and water. Reactive species such as fluorine, chlorine, bromine, iodine, sulfur, phosphorous and arsenic in the organic waste react with the molten salt to form the corresponding neutralized salts, NaF, NaCl, NaBr, NaI, Na{sub 2}SO{sub 4}, Na{sub 3}PO{sub 4} and NaAsO{sub 2} or Na{sub 3}AsO4. Plutonium and other metals react with the molten salt and air to form metal salts or oxides. Saturated salt will be recycled and aqueous chemical separation will be used to recover the {sup 238}Pu. The Los Alamos National Laboratory system, which is currently in the conceptual design stage, will be scaled down from current systems for use inside a glovebox.

Stimmel, J.; Wishau, R.; Ramsey, K.B.; Montoya, A.; Brock, J. [Los Alamos National Lab., NM (United States); Heslop, M. [Naval Surface Warfare Center (United States). Indian Head Div.; Wernly, K. [Molten Salt Oxidation Corp. (United States)

1999-04-01T23:59:59.000Z

298

May 29, 2010 The Hard Sell on Salt  

E-Print Network (OSTI)

May 29, 2010 The Hard Sell on Salt By MICHAEL MOSS With salt under attack for its ill effects -- an allure the industry has recognized for decades. "Once a preference is acquired," a top scientist at Frito adopting the lower standard for everyone as part of its review of nutrition standards. The food industry

Bent, Andrew F.

299

Disposal of NORM waste in salt caverns  

Science Conference Proceedings (OSTI)

Some types of oil and gas production and processing wastes contain naturally occurring radioactive materials (NORM). If NORM is present at concentrations above regulatory levels in oil field waste, the waste requires special disposal practices. The existing disposal options for wastes containing NORM are limited and costly. This paper evaluates the legality, technical feasibility, economics, and human health risk of disposing of NORM-contaminated oil field wastes in salt caverns. Cavern disposal of NORM waste is technically feasible and poses a very low human health risk. From a legal perspective, there are no fatal flaws that would prevent a state regulatory agency from approving cavern disposal of NORM. On the basis of the costs charged by caverns currently used for disposal of nonhazardous oil field waste (NOW), NORM waste disposal caverns could be cost competitive with existing NORM waste disposal methods when regulatory agencies approve the practice.

Veil, J.A.; Smith, K.P.; Tomasko, D.; Elcock, D.; Blunt, D.; Williams, G.P.

1998-07-01T23:59:59.000Z

300

Technical review of Molten Salt Oxidation  

Science Conference Proceedings (OSTI)

The process was reviewed for destruction of mixed low-level radioactive waste. Results: extensive development work and scaleup has been documented on coal gasification and hazardous waste which forms a strong experience base for this MSO process; it is clearly applicable to DOE wastes such as organic liquids and low-ash wastes. It also has potential for processing difficult-to-treat wastes such as nuclear grade graphite and TBP, and it may be suitable for other problem waste streams such as sodium metal. MSO operating systems may be constructed in relatively small units for small quantity generators. Public perceptions could be favorable if acceptable performance data are presented fairly; MSO will likely require compliance with regulations for incineration. Use of MSO for offgas treatment may be complicated by salt carryover. Figs, tabs, refs.

Not Available

1993-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Visualization of salt-induced stress perturbations.  

Science Conference Proceedings (OSTI)

An important challenge encountered during post-processing of finite element analyses is the visualizing of three-dimensional fields of real-valued second-order tensors. Namely, as finite element meshes become more complex and detailed, evaluation and presentation of the principal stresses becomes correspondingly problematic. In this paper, we describe techniques used to visualize simulations of perturbed in-situ stress fields associated with hypothetical salt bodies in the Gulf of Mexico. We present an adaptation of the Mohr diagram, a graphical paper and pencil method used by the material mechanics community for estimating coordinate transformations for stress tensors, as a new tensor glyph for dynamically exploring tensor variables within three-dimensional finite element models. This interactive glyph can be used as either a probe or a filter through brushing and linking.

Crossno, Patricia Joyce; Brannon, Rebecca Moss; Coblentz, David D.; Rogers, David H.

2004-10-01T23:59:59.000Z

302

Salt River Project SRP | Open Energy Information  

Open Energy Info (EERE)

SRP SRP Jump to: navigation, search Name Salt River Project (SRP) Place Tempe, Arizona Zip 85281-1298 Sector Biomass, Solar Product US utility which sources a percentage of its electricity from biomass plants. It is also involved in the solar power industry. Coordinates 33.42551°, -111.937419° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":33.42551,"lon":-111.937419,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

303

Independent Oversight Review, Savannah River Site Salt Waste Processing  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Savannah River Site Salt Waste Savannah River Site Salt Waste Processing Facility - August 2013 Independent Oversight Review, Savannah River Site Salt Waste Processing Facility - August 2013 August 2013 Review of the Savannah River Site Salt Waste Processing Facility Safety Basis and Design Development. This report documents the results of an independent oversight review of the safety basis and design development for the Salt Waste Processing Facility (SWPF) at the U.S. Department of Energy (DOE) Savannah River Site. The review was performed February 12-14, 2013 by DOE's Office of Safety and Emergency Management Evaluations, which is within the DOE Office of Health, Safety and Security. The purpose of the review was to evaluate the safety basis, design, and the associated technical documents developed for

304

BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project |  

Open Energy Info (EERE)

BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project Abstract No abstract available. Author Bureau of Land Management Organization Bureau of Land Management, Carson City Field Office, Nevada Published U.S. Department of the Interior, 2011 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project Citation Bureau of Land Management (Bureau of Land Management, Carson City Field Office, Nevada). 2011. BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project. Carson City, Nevada: U.S. Department of the

305

Independent Oversight Review, Savannah River Site Salt Waste Processing  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Savannah River Site Salt Waste Savannah River Site Salt Waste Processing Facility - August 2013 Independent Oversight Review, Savannah River Site Salt Waste Processing Facility - August 2013 August 2013 Review of the Savannah River Site Salt Waste Processing Facility Safety Basis and Design Development. This report documents the results of an independent oversight review of the safety basis and design development for the Salt Waste Processing Facility (SWPF) at the U.S. Department of Energy (DOE) Savannah River Site. The review was performed February 12-14, 2013 by DOE's Office of Safety and Emergency Management Evaluations, which is within the DOE Office of Health, Safety and Security. The purpose of the review was to evaluate the safety basis, design, and the associated technical documents developed for

306

ENEL Salt Wells Geothermal Facility | Open Energy Information  

Open Energy Info (EERE)

ENEL Salt Wells Geothermal Facility ENEL Salt Wells Geothermal Facility Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home ENEL Salt Wells Geothermal Facility General Information Name ENEL Salt Wells Geothermal Facility Facility Salt Wells Geothermal Facility Sector Geothermal energy Location Information Location Churchill, NV Coordinates 39.651603422063°, -118.49778413773° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":39.651603422063,"lon":-118.49778413773,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

307

Controlled Source Frequency-Domain Magnetics At Salt Wells Area  

Open Energy Info (EERE)

Controlled Source Frequency-Domain Magnetics At Salt Wells Area Controlled Source Frequency-Domain Magnetics At Salt Wells Area (Montgomery, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Controlled Source Frequency-Domain Magnetics At Salt Wells Area (Montgomery, Et Al., 2005) Exploration Activity Details Location Salt Wells Area Exploration Technique Controlled Source Frequency-Domain Magnetics Activity Date 2004 - 2004 Usefulness useful DOE-funding Unknown Exploration Basis AMP Resource contracted Willowstick Technologies, LLC to conduct a Controlled Source-Frequency Domain Magnetics (CS-FDM) geophysical investigation at Salt Wells in order to characterize and delineate areas showing the greatest concentrations and highest temperatures of geothermal groundwater. The investigation also sought to map blind faults beneath the

308

Method for Making a Uranium Chloride Salt Product  

DOE Patents (OSTI)

The subject apparatus provides a means to produce UCl3, in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl2 is formed. Due to is lower density, the CdCl2 rises through the Cd layer into a layer of molten LiCl-KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl2 reacts with the uranium to form UCl, and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl3 combines with the molten salt. During production the temperature is maintained at about 600 degrees C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl-KCl-30 mol% UCl3 is solidified.

Miller, William F.; Tomczuk, Zygmunt

2004-10-05T23:59:59.000Z

309

Continuous extraction of molten chloride salts with liquid cadmium alloys  

Science Conference Proceedings (OSTI)

A pyrochemical method is being developed at Argonne National Laboratory (ANL) to provide contnuous multistage extractions between molten chloride salts and liquid cadmium alloys at 500{degrees}C. The extraction method will be used to recover transuranic (TRU) elements from the process salt in the electroretiner used in the pyrochemical reprocessing of spent fuel from the Integral Fast Reactor (IFR). The IFR is one of the Department of Energy`s advanced power reactor concepts. The recovered TRU elements are returned to the electrorefiner. The extracted salt undergoes further processing to remove rare earths and other fission products so that most of the purified salt can also be returned to the electrorefiner, thereby extending the useful life of the process salt many times.

Chow, L.S.; Basco, J.K.; Ackerman, J.P.; Johnson, T.R.

1993-09-01T23:59:59.000Z

310

Perchlorate and Nitrate Remediation Efficiency and Microbial Diversity in a Containerized Wetland Bioreactor  

DOE Green Energy (OSTI)

We have developed a method to remove perchlorate (14 to 27 {micro}g/L) and nitrate (48 mg/L) from contaminated groundwater using a wetland bioreactor. The bioreactor has operated continuously in a remote field location for more than two years with a stable ecosystem of indigenous organisms. This study assesses the bioreactor for long-term perchlorate and nitrate remediation by evaluating influent and effluent groundwater for reduction-oxidation conditions and nitrate and perchlorate concentrations. Total community DNA was extracted and purified from 10-g sediment samples retrieved from vertical coring of the bioreactor during winter. Analysis by denaturing gradient gel electrophoresis of short, 16S rDNA, polymerase-chain-reaction products was used to identify dominant microorganisms. Bacteria genera identified were closely affiliated with bacteria widely distributed in soils, mud layers, and fresh water. Of the 17 dominant bands sequenced, most were gram negative and capable of aerobic or anaerobic respiration with nitrate as the terminal electron acceptor (Pseudomonas, Acinetobacter, Halomonas, and Nitrospira). Several identified genera (Rhizobium, Acinetobactor, and Xanthomonas) are capable of fixing atmospheric nitrogen into a combined form (ammonia) usable by host plants. Isolates were identified from the Proteobacteria class, known for the ability to reduce perchlorate. Initial bacterial assessments of sediments confirm the prevalence of facultative anaerobic bacteria capable of reducing perchlorate and nitrate in situ.

Jr., B D; Dibley, V; Pinkart, H; Legler, T

2004-06-09T23:59:59.000Z

311

Analysis of Multistage and Other Creep Data for Domal Salts  

SciTech Connect

There have existed for some time relatively sparse creep databases for a number of domal salts. Although all of these data were analyzed at the time they were reported, to date there has not been a comprehensive, overall evaluation within the same analysis framework. Such an evaluation may prove of value. The analysis methodology is based on the Multimechanism Deformation (M-D) description of salt creep and the corresponding model parameters determined from conventional creep tests. The constitutive model of creep wss formulated through application of principles involved in micromechanical modeling. It was possible, at minimum, to obtain the steady state parameters of the creep model from the data on the domal salts. When this was done, the creep of the domal salts, as compared to the well-defined Waste Isolation Pilot Plant (WIPP) bedded clean salt, was either essentially identical to, or significantly harder (more creep resistant) than WIPP salt. Interestingly, the domal salts form two distinct groups, either sofl or hard, where the difference is roughly a factor often in creep rate between the twcl groups. As might be expected, this classification corresponds quite well to the differences in magnitude of effective creep volume losses of the Strategic Petroleum Reserve (SPR) caverns as determined by the CAVEMAN cavern pressure history analysis, depending upon the specific dome or region within the dome. Creep response shoulcl also correlate to interior cavern conditions that produce salt falls. WMle, in general, the caverns in hard sah have a noticeably greater propensity for salt falls, a smaller number of similar events are exhibited even in the caverns in soft salt.

Munson, D.E.

1998-10-01T23:59:59.000Z

312

Factors influencing algal biomass in hydrologically dynamic salt ponds in a subtropical salt marsh  

E-Print Network (OSTI)

The interface between land and water is often a dynamic zone that responds to relatively short-term climatic and hydrologic forces. Coastal salt marshes occupy this zone between land and sea and typically are comprised of vegetated marsh intersected by channels and shallow ponds that are subject to flooding by winds, tides, and storm surges. Coastal salt marshes are widely regarded as zones of high macrophyte productivity. However, microalgae may contribute more to salt marsh productivity than previously realized, underscoring the importance of understanding algal dynamics in such systems. Benthic and planktonic chlorophyll-a (surrogate for total algal biomass), sediment AFDW, total suspended solids, salinity, and nutrients were examined in marsh ponds in the subtropical Guadalupe Estuary, TX, USA to determine the effects of hydrologic connections on algal biomass in this system. From May 2005 – May 2006 there were several pond connection, disconnection, and desiccation events. During periods of disconnection, algal biomass was higher in both the benthos and the water column than during connection events when supposed flushing occurred. Connection events also flushed out high NH4 accumulating in pond surface waters, but did not increase NOx. Therefore, the primary source of DIN seemed to be nutrient cycling within the ponds. There was a temporal effect on surface water salinity, which increased throughout the sampling period as bay water levels and subsequent pond connections decreased, demonstrating interannual variability and the link between seasons (wet vs. dry) and marsh inundation patterns (high water periods vs. low water periods) in this estuary.

Miller, Carrie J.

2007-05-01T23:59:59.000Z

313

Atomic structure of nitrate-binding protein crucial for photosynthetic productivity  

DOE Green Energy (OSTI)

Cyanobacteria, blue-green algae, are the most abundant autotrophs in aquatic environments and form the base of all aquatic food chains by fixing carbon and nitrogen into cellular biomass. The single most important nutrient for photosynthesis and growth is nitrate, which is severely limiting in many aquatic environments particularly the open ocean (1, 2). It is therefore not surprising that NrtA, the solute-binding component of the high-affinity nitrate ABC transporter, is the single-most abundant protein in the plasma membrane of these bacteria (3). Here we describe the first structure of a nitratespecific receptor, NrtA from Synechocystis sp. PCC 6803, complexed with nitrate and determined to a resolution of 1.5Å. NrtA is significantly larger than other oxyanionbinding proteins, representing a new class of transport proteins. From sequence alignments, the only other solute-binding protein in this class is CmpA, a bicarbonatebinding protein. Therefore, these organisms created a novel solute-binding protein for two of the most important nutrients; inorganic nitrogen and carbon. The electrostatic charge distribution of NrtA appears to force the protein off of the membrane while the flexible tether facilitates the delivery of nitrate to the membrane pore. The structure not only details the determinants for nitrate selectivity in NrtA, but also the bicarbonate specificity in CmpA. Nitrate and bicarbonate transport are regulated by the cytoplasmic proteins NrtC and CmpC, respectively. Interestingly, the residues lining the ligand binding pockets suggest that they both bind nitrate. This implies that the nitrogen and carbon uptake pathways are synchronized by intracellular nitrate and nitrite.3 The nitrate ABC transporter of cyanobacteria is composed of four polypeptides (Figure 1): a high-affinity periplasmic solute-binding lipoprotein (NrtA), an integral membrane permease (NrtB), a cytoplasmic ATPase (NrtD), and a unique ATPase/solute-binding fusion protein (NrtC) that regulates transport (4). NrtA binds both nitrate and nitrite (Kd = 0.3 mM) and is necessary for cell survival when nitrate is the primary nitrogen source (5). The role of NrtA is to scavenge nitrate/nitrite from the periplasm for delivery to the membrane permease, NrtB. The passage of solute through the transmembrane pore is linked to ATP hydrolysis by NrtC and NrtD. NrtD consists of a single ATPase domain. In contrast, NrtC contains both an ATPase domain and a Cterminal solute-binding domain that shares 50% amino acid sequence similarity with NrtA, and is required for the ammonium-mediated inhibition of nitrate transport (6, 7). Aside from the homologous transporter for bicarbonate, CmpABCD, there are no other known examples of ABC transporters that have an ATPase/solute-binding fusion component. The specificity of the nitrate transporter is conferred by NrtA (4). NrtA is ~49% identical (60% similar) in amino acid sequence to the bicarbonate receptor CmpA. In its entirety, it does not have significant homology to any other known protein. To elucidate the molecular determinants of nitrate specificity, we determined the crystal structure of the Synechocystis 6803 NrtA to 1.5 Å. While the general shape of NrtA is akin to that of other solute binding proteins, NrtA clearly represents a new and unique structural variant of these ‘C clamp’ proteins. From this structure and sequence alignments of other bicarbonate and nitrate transporters, the molecular basis for solute selectivity is clear and suggests that regulatory domains of both icarbonate and nitrate transport systems bind nitrate. Based on these findings, a model is presented that 4 demonstrates how such synergistic regulation of bicarbonate and nitrate transport is important in conserving energy during the process of carbon fixation and nitrogen assimilation.

Koropatkin, Nicole M.; Pakrasi, Himadri B.; Smith, Thomas J.

2006-06-27T23:59:59.000Z

314

Complexation of Lanthanides with Nitrate at Variable Temperatures: Thermodynamics and Coordination Modes  

SciTech Connect

Complexation of neodymium(III) with nitrate was studied at variable temperatures (25, 40, 55 and 70 C) by spectrophotometry and microcalorimetry. The NdNO{sub 3}{sup 2+} complex is weak and becomes slightly stronger as the temperature is increased. The enthalpy of complexation at 25 C was determined by microcalorimetry to be small and positive, (1.5 {+-} 0.2) kJ {center_dot} mol{sup -1}, in good agreement with the trend of the stability constant at variable temperatures. Luminescence emission spectra and lifetime of Eu(III) in nitrate solutions suggest that inner-sphere and bidentate complexes form between trivalent lanthanides (Nd{sup 3+} and Eu{sup 3+}) and nitrate in aqueous solutions. Specific Ion Interaction approach (SIT) was used to obtain the stability constants of NdNO{sub 3}{sup 2+} at infinite dilution and variable temperatures.

Rao, Linfeng; Tian, Guoxin

2008-12-10T23:59:59.000Z

315

In-Drift Precipitates/Salts Analysis  

SciTech Connect

As directed by a written development plan (CRWMS M&O 1999a), an analysis of the effects of salts and precipitates on the repository chemical environment is to be developed and documented in an Analyses/Model Report (AMR). The purpose of this analysis is to assist Performance Assessment Operations (PAO) and the Engineered Barrier Performance Department in modeling the geochemical environment within a repository drift, thus allowing PAO to provide a more detailed and complete in-drift geochemical model abstraction and to answer the key technical issues (KTI) raised in the NRC Issue Resolution Status Report (IRSR) for the Evolution of the Near Field Environment (NFE) Revision 2 (NRC 1999). The purpose of this ICN is to qualify and document qualification of the AMR's technical products. The scope of this document is to develop a model of the processes that govern salt precipitation and dissolution and resulting water composition in the Engineered Barrier System (EBS). This model is developed to serve as a basis for the in-drift geochemical modeling work performed by PAO and is to be used in subsequent PAO analyses including the EBS physical and chemical model abstraction effort. However, the concepts may also apply to some near and far field geochemical processes and can have conceptual application within the unsaturated zone and saturated zone transport modeling efforts. The intended use of the model developed in this report is to estimate, within an appropriate level of confidence, the pH, chloride concentration, and ionic strength of water on the drip shield or other location within the drift during the post-closure period. These estimates are based on evaporative processes that are subject to a broad range of potential environmental conditions and are independent of the presence or absence of backfill. An additional intended use is to estimate the environmental conditions required for complete vaporization of water. The presence and composition of liquid water in the drift (i.e., pH, chloride concentration, and ionic strength) are potentially important to corrosion and radionuclide transport calculations performed by PAO.

P. Mariner

2001-01-10T23:59:59.000Z

316

Gradient zone boundary control in salt gradient solar ponds  

SciTech Connect

A method and apparatus for suppressing zone boundary migration in a salt gradient solar pond includes extending perforated membranes across the pond at the boundaries, between the convective and non-convective zones, the perforations being small enough in size to prevent individual turbulence disturbances from penetrating the hole, but being large enough to allow easy molecular diffusion of salt thereby preventing the formation of convective zones in the gradient layer. The total area of the perforations is a sizable fraction of the membrane area to allow sufficient salt diffusion while preventing turbulent entrainment into the gradient zone.

Hull, John R. (Downers Grove, IL)

1984-01-01T23:59:59.000Z

317

The Thorium Molten Salt Reactor Moving on from the MSBR  

E-Print Network (OSTI)

A re-evaluation of the Molten Salt Breeder Reactor concept has revealed problems related to its safety and to the complexity of the reprocessing considered. A reflection is carried out anew in view of finding innovative solutions leading to the Thorium Molten Salt Reactor concept. Several main constraints are established and serve as guides to parametric evaluations. These then give an understanding of the influence of important core parameters on the reactor's operation. The aim of this paper is to discuss this vast research domain and to single out the Molten Salt Reactor configurations that deserve further evaluation.

Mathieu, L; Brissot, R; Le Brun, C; Liatard, E; Loiseaux, J M; Méplan, O; Merle-Lucotte, E; Nuttin, A; Wilson, J; Garzenne, C; Lecarpentier, D; Walle, E

2006-01-01T23:59:59.000Z

318

The Thorium Molten Salt Reactor : Moving on from the MSBR  

E-Print Network (OSTI)

A re-evaluation of the Molten Salt Breeder Reactor concept has revealed problems related to its safety and to the complexity of the reprocessing considered. A reflection is carried out anew in view of finding innovative solutions leading to the Thorium Molten Salt Reactor concept. Several main constraints are established and serve as guides to parametric evaluations. These then give an understanding of the influence of important core parameters on the reactor's operation. The aim of this paper is to discuss this vast research domain and to single out the Molten Salt Reactor configurations that deserve further evaluation.

L. Mathieu; D. Heuer; R. Brissot; C. Le Brun; E. Liatard; J. M. Loiseaux; O. Méplan; E. Merle-Lucotte; A. Nuttin; J. Wilson; C. Garzenne; D. Lecarpentier; E. Walle; the GEDEPEON Collaboration

2005-06-02T23:59:59.000Z

319

Molten salt/metal extractions for recovery of transuranic elements  

SciTech Connect

The integral fast reactor (EFR) is an advanced reactor concept that incorporates metallic driver and blanket fuels, an inherently safe, liquid-sodium-cooled, pool-type, reactor design, and on-site pyrochemical reprocessing (including electrorefining) of spent fuels and wastes. This paper describes a pyrochemical method that is being developed at Argonne National Laboratory to recover transuranic elements from the EFR electrorefiner process salt. The method uses multistage extractions between molten chloride salts and cadmium metal at high temperatures. The chemical basis of the salt extraction method, the test equipment, and a test plan are discussed.

Chow, L.S.; Basco, J.K.; Ackerman, J.P.; Johnson, T.R.

1992-01-01T23:59:59.000Z

320

Molten salt/metal extractions for recovery of transuranic elements  

SciTech Connect

The integral fast reactor (EFR) is an advanced reactor concept that incorporates metallic driver and blanket fuels, an inherently safe, liquid-sodium-cooled, pool-type, reactor design, and on-site pyrochemical reprocessing (including electrorefining) of spent fuels and wastes. This paper describes a pyrochemical method that is being developed at Argonne National Laboratory to recover transuranic elements from the EFR electrorefiner process salt. The method uses multistage extractions between molten chloride salts and cadmium metal at high temperatures. The chemical basis of the salt extraction method, the test equipment, and a test plan are discussed.

Chow, L.S.; Basco, J.K.; Ackerman, J.P.; Johnson, T.R.

1992-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Engineering Evaluation of Proposed Alternative Salt Transfer Method for the Molten Salt Reactor Experiement for the Oak Ridge National Laboratory  

SciTech Connect

This evaluation was performed by Pro2Serve in accordance with the Technical Specification for an Engineering Evaluation of the Proposed Alternative Salt Transfer Method for the Molten Salt Reactor Experiment at the Oak Ridge National Laboratory (BJC 2009b). The evaluators reviewed the Engineering Evaluation Work Plan for Molten Salt Reactor Experiment Residual Salt Removal, Oak Ridge National Laboratory, Oak Ridge, Tennessee (DOE 2008). The Work Plan (DOE 2008) involves installing a salt transfer probe and new drain line into the Fuel Drain Tanks and Fuel Flush Tank and connecting them to the new salt transfer line at the drain tank cell shield. The probe is to be inserted through the tank ball valve and the molten salt to the bottom of the tank. The tank would then be pressurized through the Reactive Gas Removal System to force the salt into the salt canisters. The Evaluation Team reviewed the work plan, interviewed site personnel, reviewed numerous documents on the Molten Salt Reactor (Sects. 7 and 8), and inspected the probes planned to be used for the transfer. Based on several concerns identified during this review, the team recommends not proceeding with the salt transfer via the proposed alternate salt transfer method. The major concerns identified during this evaluation are: (1) Structural integrity of the tanks - The main concern is with the corrosion that occurred during the fluorination phase of the uranium removal process. This may also apply to the salt transfer line for the Fuel Flush Tank. Corrosion Associated with Fluorination in the Oak Ridge National Laboratory Fluoride Volatility Process (Litman 1961) shows that this problem is significant. (2) Continued generation of Fluorine - Although the generation of Fluorine will be at a lower rate than experienced before the uranium removal, it will continue to be generated. This needs to be taken into consideration regardless of what actions are taken with the salt. (3) More than one phase of material - There are likely multiple phases of material in the salt (metal or compound), either suspended through the salt matrix, layered in the bottom of the tank, or both. These phases may contribute to plugging during any planned transfer. There is not enough data to know for sure. (4) Probe heat trace - The alternate transfer method does not include heat tracing of the bottom of the probe. There is a concern that this may cool the salt and other phases of materials present enough to block the flow of salt. (5) Stress-corrosion cracking - Additionally, there is a concern regarding moisture that may have been introduced into the tanks. Due to time constraints, this concern was not validated. However, if moisture was introduced into the tanks and not removed during heating the tanks before HF and F2 sparging, there would be an additional concern regarding the potential for stress-corrosion cracking of the tank walls.

Carlberg, Jon A.; Roberts, Kenneth T.; Kollie, Thomas G.; Little, Leslie E.; Brady, Sherman D.

2009-09-30T23:59:59.000Z

322

Estimation Of Retained Crude Oil Associated With Crushed Salt And Salt Cores In The Presence Of Near-Saturated Brine  

E-Print Network (OSTI)

This paper describes three experiments whose purpose is to determine the amount of retained oil on massive salt surfaces and in crushed salt in the presence of water and brine. These experiments have application to the decommissioning process for the Weeks Island mine. In the first experiment, oil-coated salt cores were immersed in either fresh water or in 85% brine. In the case of both fluids, the oil was completely removed from the cores within several hours. In the second experiment, oil-coated salt pieces were suspended in air and the oil was allowed to drain. The weight of retained oil clinging to the salt was determined. This experiment was used to estimate the total amount of oil clinging to the roofs of the mine. The total amount of oil clinging to the roofs of the mine is estimated to be between 240 and 400 m 3 (1500 and 2500 BBL). In the third experiment, a pan of oil-soaked crushed salt was immersed in 85% brine, and oil removal from the salt was monitored as a function of...

Timothy Hern Energetic; Timothy J. O’hern; Thomas E. Hinkebein; Thomas W. Grasser

1999-01-01T23:59:59.000Z

323

Stochastic hydro-economic modeling for optimal management of agricultural groundwater nitrate pollution under hydraulic conductivity uncertainty  

Science Conference Proceedings (OSTI)

In decision-making processes, reliability and risk aversion play a decisive role. This paper presents a framework for stochastic optimization of control strategies for groundwater nitrate pollution from agriculture under hydraulic conductivity uncertainty. ... Keywords: Fertilizer allocation, Groundwater, Nitrates, Optimization, Stochastic management model, Uncertainty

S. Peña-Haro; M. Pulido-Velazquez; C. Llopis-Albert

2011-08-01T23:59:59.000Z

324

Energy Department Completes Salt Coolant Material Transfer to Czech  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Completes Salt Coolant Material Transfer to Czech Completes Salt Coolant Material Transfer to Czech Republic for Advanced Reactor Research Energy Department Completes Salt Coolant Material Transfer to Czech Republic for Advanced Reactor Research May 20, 2013 - 12:52pm Addthis News Media Contact (202) 586-4940 PRAGUE, CZECH REPUBLIC - The U.S. Department of Energy recently joined with the U.S. Embassy in Prague and the Czech Republic's Ministry of Industry and Trade to complete the transfer of 75 kilograms of fluoride salt from the Department's Oak Ridge National Laboratory (ORNL) to the Czech Nuclear Research Institute Řež for experiments at Řež's critical test facility. This partnership builds on a strong history of U.S.-Czech energy collaboration and follows President Obama's speech in Prague in April 2009, where he laid out the importance of international

325

Surface Indicators of Geothermal Activity at Salt Wells, Nevada, USA,  

Open Energy Info (EERE)

Surface Indicators of Geothermal Activity at Salt Wells, Nevada, USA, Surface Indicators of Geothermal Activity at Salt Wells, Nevada, USA, Including Warm Ground, Borate Deposits, and Siliceous Alteration Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Surface Indicators of Geothermal Activity at Salt Wells, Nevada, USA, Including Warm Ground, Borate Deposits, and Siliceous Alteration Abstract Surface indicators of geothermal activity are often present above blind or concealed geothermal systems in the Great Basin, but their expressions are sometimes subtle. When mapped in detail, these indicators yield valuable information on the location, structural controls, and potential subsurface reservoir temperatures of geothermal fluids. An example is provided by the Salt Wells geothermal system in Churchill County, Nevada, USA, where

326

BLM Approves Salt Wells Geothermal Energy Projects | Open Energy  

Open Energy Info (EERE)

Energy Projects Energy Projects Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: BLM Approves Salt Wells Geothermal Energy Projects Abstract Abstract unavailable. Author Colleen Sievers Published U.S. Department of the Interior- Bureau of Land Management, Carson City Field Office, Nevada, 09/28/2011 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for BLM Approves Salt Wells Geothermal Energy Projects Citation Colleen Sievers. BLM Approves Salt Wells Geothermal Energy Projects [Internet]. 09/28/2011. Carson City, NV. U.S. Department of the Interior- Bureau of Land Management, Carson City Field Office, Nevada. [updated 2011/09/28;cited 2013/08/21]. Available from: http://www.blm.gov/nv/st/en/fo/carson_city_field/blm_information/newsroom/2011/september/blm_approves_salt.html

327

Magnetotellurics At Salt Wells Area (Bureau of Land Management, 2009) |  

Open Energy Info (EERE)

Salt Wells Area (Bureau of Land Management, 2009) Salt Wells Area (Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Magnetotellurics At Salt Wells Area (Bureau of Land Management, 2009) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Magnetotellurics Activity Date 2008 - 2008 Usefulness not indicated DOE-funding Unknown Exploration Basis Vulcan increased exploration efforts in the summer and fall of 2008, during which time the company drilled two temperature gradient holes (86-15 O on Pad 1 and 17-16 O on Pad 3); conducted seismic, gravity and magnetotelluric surveys; and drilled deep exploration wells at Pads 6 and 8 and binary wells at Pads 1, 2, 4, and 7. Notes Data from these wells is proprietary, and so were unavailable for inclusion

328

Salt Wells Geothermal Energy Projects Environmental Impact Statement | Open  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Salt Wells Geothermal Energy Projects Environmental Impact Statement Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells Geothermal Energy Projects Environmental Impact Statement Abstract Abstract unavailable. Author Bureau of Land Management Published U.S. Department of the Interior- Bureau of Land Management, Carson City Field Office, Nevada, 07/22/2011 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for Salt Wells Geothermal Energy Projects Environmental Impact Statement Citation Bureau of Land Management. Salt Wells Geothermal Energy Projects Environmental Impact Statement [Internet]. 07/22/2011. Carson City, NV. U.S. Department of the Interior- Bureau of Land Management, Carson City

329

DOE Issues Salt Waste Determination for the Savannah River Site |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Issues Salt Waste Determination for the Savannah River Site Issues Salt Waste Determination for the Savannah River Site DOE Issues Salt Waste Determination for the Savannah River Site January 18, 2006 - 10:49am Addthis WASHINGTON, DC - The U.S. Department of Energy (DOE) today issued the waste determination for the treatment and stabilization of low activity salt-waste at the Savannah River Site allowing for significant reductions in environmental and health risks posed by the material. Stored in forty-nine underground tanks, approximately 36 million gallons of radioactive waste is left over from plutonium production during the Cold War. In addition, the department issued an amended Record of Decision and Implementation Plan to the Defense Nuclear Facilities Safety Board. "Today's announcement clears the way for the removal and treatment of this

330

Salt River Project Smart Grid Project | Open Energy Information  

Open Energy Info (EERE)

Salt River Project Smart Grid Project Salt River Project Smart Grid Project Jump to: navigation, search Project Lead Salt River Project Country United States Headquarters Location Tempe, Arizona Recovery Act Funding $56,859,359.00 Total Project Value $114,003,719.00 Coverage Area Coverage Map: Salt River Project Smart Grid Project Coordinates 33.414768°, -111.9093095° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

331

DOE - Office of Legacy Management -- Penn Salt Manufacturing Co Whitemarsh  

NLE Websites -- All DOE Office Websites (Extended Search)

Penn Salt Manufacturing Co Penn Salt Manufacturing Co Whitemarsh Research Laboratories - PA 20 FUSRAP Considered Sites Site: PENN SALT MANUFACTURING CO., WHITEMARSH RESEARCH LABORATORIES (PA.20) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Penn Salt Company PA.20-1 Location: Philiadelphia , Pennsylvania PA.20-1 Evaluation Year: 1987 PA.20-1 Site Operations: Conducted process studies for recovery of uranium from fluoride scrap. PA.20-1 Site Disposition: Eliminated - AEC licensed operation. Potential for residual radioactive contamination considered remote due to limited quantities and scope of operations. PA.20-2 PA.20-1 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium PA.20-1 Radiological Survey(s): None Indicated

332

Salt Wells Geothermal Exploratory Drilling Program EA(DOI-BLM...  

Open Energy Info (EERE)

09142009 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Salt Wells Geothermal Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-...

333

Expected brine movement at potential nuclear waste repository salt sites  

SciTech Connect

The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

McCauley, V.S.; Raines, G.E.

1987-08-01T23:59:59.000Z

334

Meddy–Seamount Interactions: Implications for the Mediterranean Salt Tongue  

Science Conference Proceedings (OSTI)

A quasigeostrophic point vortex numerical model is used to explore interactions of eddies and seamounts. The ultimate objective of this study is to assess the role of meddy–seamount interaction as an input to Mediterranean salt tongue ...

Guohui Wang; William K. Dewar

2003-11-01T23:59:59.000Z

335

Bubbles Produced by Breaking Waves in Fresh and Salt Waters  

Science Conference Proceedings (OSTI)

A greater volume of air is entrained by breaking waves to produce many more bubbles in salt, than in fresh, water. There are, however, little differences in their sizes. These results are consistent with reported observations of whitecaps over ...

Jin Wu

2000-07-01T23:59:59.000Z

336

Evolution of a Mediterranean Salt Lens: Scalar Properties  

Science Conference Proceedings (OSTI)

The evolution of a Mediterranean salt lens (Meddy) over a two year period is examined. Several nondimensional numbers can be used to describe the overall decay in the structure of the Moddy. Two Rossby numbers, one using the central relative ...

Dave Hebert; Neil Oakey; Barry Ruddick

1990-09-01T23:59:59.000Z

337

Molten salt electrolyte battery cell with overcharge tolerance  

SciTech Connect

A molten salt electrolyte battery having an increased overcharge tolerance employs a negative electrode with two lithium alloy phases of different electrochemical potential, one of which allows self-discharge rates which permits battery cell equalization.

Kaun, Thomas D. (New Lenox, IL); Nelson, Paul A. (Wheaton, IL)

1989-01-01T23:59:59.000Z

338

Modeling of Molten Salt Mixtures: Thermodynamic Assessment of ...  

Science Conference Proceedings (OSTI)

Presentation Title, Modeling of Molten Salt Mixtures: Thermodynamic Assessment of CeBr3 and MBr-CeBr3 Systems (M=Li, Na, K, Rb). Author(s), Yue Wu, ...

339

System Requirements Document for the Molten Salt Reactor Experiment  

Science Conference Proceedings (OSTI)

The purpose of the conversion process is to convert the {sup 233}U fluoride compounds that are being extracted from the Molten Salt Reactor Experiment (MSRE) equipment to a stable oxide for long-term storage at Bldg. 3019.

Aigner, R.D.

2000-04-01T23:59:59.000Z

340

Michigan Natural Gas Underground Storage Salt Caverns Capacity ...  

U.S. Energy Information Administration (EIA)

Michigan Natural Gas Underground Storage Salt Caverns Capacity (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9; 1990's:

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

California GAMA Special Study: An isotopic and dissolved gas investigation of nitrate source and transport to a public supply well in California's Central Valley  

Science Conference Proceedings (OSTI)

This study investigates nitrate contamination of a deep municipal drinking water production well in Ripon, CA to demonstrate the utility of natural groundwater tracers in constraining the sources and transport of nitrate to deep aquifers in the Central Valley. The goal of the study was to investigate the origin (source) of elevated nitrate and the potential for the deep aquifer to attenuate anthropogenic nitrate. The site is ideal for such an investigation. The production well is screened from 165-325 feet below ground surface and a number of nearby shallow and deep monitoring wells were available for sampling. Furthermore, potential sources of nitrate contamination to the well had been identified, including a fertilizer supply plant located approximately 1000 feet to the east and local almond groves. A variety of natural isotopic and dissolved gas tracers including {sup 3}H-{sup 3}He groundwater age and the isotopic composition of nitrate are applied to identify nitrate sources and to characterize nitrate transport. An advanced method for sampling production wells is employed to help identify contaminant contributions from specific screen intervals. Nitrate transport: Groundwater nitrate at this field site is not being actively denitrified. Groundwater parameters indicate oxic conditions, the dissolved gas data shows no evidence for excess nitrogen as the result of denitrification, and nitrate-N and -O isotope compositions do not display patterns typical of denitrification. Contaminant nitrate source: The ambient nitrate concentration in shallow groundwater at the Ripon site ({approx}12 mg/L as nitrate) is typical of shallow groundwaters affected by recharge from agricultural and urban areas. Nitrate concentrations in Ripon City Well 12 (50-58 mg/L as nitrate) are significantly higher than these ambient concentrations, indicating an additional source of anthropogenic nitrate is affecting groundwater in the capture zone of this municipal drinking water well. This study provides two new pieces of evidence that the Ripon Farm Services Plant is the source of elevated nitrate in Ripon City Well 12. (1) Chemical mass balance calculations using nitrate concentration, nitrate isotopic composition, and initial tritium activity all indicate that that the source water for elevated nitrate to Ripon City Well 12 is a very small component of the water produced by City Well 12 and thus must have extremely high nitrate concentration. The high source water nitrate concentration ({approx}1500 mg/L as nitrate) required by these mass balance calculations precludes common sources of nitrate such as irrigated agriculture, dairy wastewater, and septic discharge. Shallow groundwater under the Ripon Farm Services RFS plant does contain extremely high concentrations of nitrate (>1700 mg/L as nitrate). (2) Nitrogen and oxygen isotope compositions of nitrate indicate that the additional anthropogenic nitrate source to Ripon City Well 12 is significantly enriched in {delta}{sup 18}O-NO{sub 3}, an isotopic signature consistent with synthetic nitrate fertilizer, and not with human or animal wastewater discharge (i.e. dairy operations, septic system discharge, or municipal wastewater discharge), or with organic fertilizer. Monitoring wells on and near the RFS plant also have high {delta}{sup 18}O-NO{sub 3}, and the plant has handled and stored synthetic nitrate fertilizer that will have this isotopic signature. The results described here highlight the complexity of attributing nitrate found in long screened, high capacity wells to specific sources. In this case, the presence of a very high concentration source near the well site combined with sampling using multiple isotopic tracer techniques and specialized depth-specific techniques allowed fingerprinting of the source in the mixed-age samples drawn from the production well.

Singleton, M J; Moran, J E; Esser, B K; Roberts, S K; Hillegonds, D J

2010-04-14T23:59:59.000Z

342

Long-term nitrate measurements in the ocean using the In Situ Ultraviolet Spectrophotometer: sensor integration into the Apex profiling float  

Science Conference Proceedings (OSTI)

Reagent-free, optical nitrate sensors (ISUS: In Situ Ultraviolet Spectrophotometer) can be used to detect nitrate throughout most of the ocean. Although the sensor is a relatively high power device when operated continuously (7.5 W typical), the ...

Kenneth S. Johnson; Luke J. Coletti; Hans W. Jannasch; Carole M. Sakamoto; Dana D. Swift; Stephen C. Riser

343

Application of a modified denitrifying bacteria method for analyzing groundwater and vadose zone pore water nitrate at the Hanford Site, WA, USA.  

E-Print Network (OSTI)

zone pore water nitrate at the Hanford Site, WA, USA. Woods,and Conrad, Mark The Hanford Site in southern WashingtonL have been reported for Hanford groundwaters, where nitrate

Woods, Katharine N.; Singleton, Michael J.; Conrad, Mark

2003-01-01T23:59:59.000Z

344

Nitrate and colloid transport through coarse Hanford sediments under steady state, variably saturated flow  

E-Print Network (OSTI)

Nitrate and colloid transport through coarse Hanford sediments under steady state, variably] At the U.S. Department of Energy's Hanford Reservation, colloid-facilitated transport is a potential of colloids through Hanford sediments under steady state, unsaturated flow conditions. We isolated colloids

Flury, Markus

345

BEDT-TFF salts with fluorinated sulfonate anions.  

Science Conference Proceedings (OSTI)

A number of layered conducting BEDT-TTF, bis(ethylenedithio)tetrathiafulvalene, salts with heavily fluorinated organosulfonate anions have been prepared and characterized. Of particular interest are the salts containing SF{sub 5}RSO{sub 3}{sup -} anions, where R is a partially fluorinated aliphatic backbone. While structurally similar --the {beta}' packing type predominates--the ground state of these salts varies from superconducting in the case of {beta}'-(BEDT-TTF){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} [1] to insulating. Many of the salts with insulating ground states are metallic at room temperature, but charge localization and disproportionation over crystallographically non-equivalent sites occurs at low temperature. The organosulfonate group exhibits a propensity to bind to lithium ions, thus ternary salts incorporating Li+ into the complex anion layer are often found. The fluorophilic effect in organofluorine compounds may be exploited to form salts where the conducting BEDT-TTF layers are separated by extremely bulky anion bilayers. The crystal structure of one such system, (BEDT-TTF){sub 3}[(CF{sub 3}){sub 2}CFC{sub 2}H{sub 4}SO{sub 3}]{sub 4}(H{sub 5}O{sub 2}){sub 2}, is described here.

Geiser, U.; Schlueter, J. A.; Kini, A. M.; Wang, H. H.; Ward, B. H.; Mohtasham, J.; Gard, G. L.; Portland State Univ.

2003-01-01T23:59:59.000Z

346

A PRELIMINARY STUDY OF MOLTEN SALT POWER REACTORS  

SciTech Connect

A preliminary study of molten salt pcwer reactors was made. The most promising fuel carrier salts were the fluorides and chlorides of the alkali metals, zirconium, and beryllium. The chlorides were found to have lower melting points but were less stable and more corrosive than the fluorides. A Li/sup 7/ F- - BeF/sub 2/ mixture with ThF/sub 4/ and UF/sub 4/appeared to perform best. Of the numerous alloys tested as container material, Inconel and a nickel-- molybdenum alloy INOR-8 appeared to be the most resistant to corrosion. To study the performance, safety, economics, and construction costs of a typical molten salt reactor, a reactor of specific type and size was chosen for study. The reference design reactor was a two-region homogeneous converter with a core salt of 70 mole% Li/sup 7/F and 30% BeF/sub 2. ThF/sub 4/ and enough VF/sub 4/ for criticality were added. Study in- dicated that a molten salt reactor would prcduce economical power, but the problem of developing a salt core and a container metal which would last for mamy years of operation needed further study. (M.C.G.)

MacPherson, H.G.; Alexander, L.G.; Carrison, D.A.; Estabrook, J.Y.; Kinyon, B.W.; Mann, L.A.; Roberts, J.T.; Romie, F.E.; VonderLage, F.C.

1957-04-29T23:59:59.000Z

347

Catalytic Gasification of Coal using Eutectic Salt Mixtures  

SciTech Connect

The objectives of this study are to: identify appropriate eutectic salt mixture catalysts for coal gasification; assess agglomeration tendency of catalyzed coal; evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; evaluate the recovery, regeneration and recycle of the spent catalysts; and conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process. A review of the collected literature was carried out. The catalysts which have been used for gasification can be roughly classified under the following five groups: alkali metal salts; alkaline earth metal oxides and salts; mineral substances or ash in coal; transition metals and their oxides and salts; and eutectic salt mixtures. Studies involving the use of gasification catalysts have been conducted. However, most of the studies focused on the application of individual catalysts. Only two publications have reported the study of gasification of coal char in CO2 and steam catalyzed by eutectic salt mixture catalysts. By using the eutectic mixtures of salts that show good activity as individual compounds, the gasification temperature can be reduced possibly with still better activity and gasification rates due to improved dispersion of the molten catalyst on the coal particles. For similar metal/carbon atomic ratios, eutectic catalysts were found to be consistently more active than their respective single salts. But the exact roles that the eutectic salt mixtures play in these are not well understood and details of the mechanisms remain unclear. The effects of the surface property of coals and the application methods of eutectic salt mixture catalysts with coal chars on the reactivity of gasification will be studied. Based on our preliminary evaluation of the literature, a ternary eutectic salt mixture consisting of Li- Na- and K- carbonates has the potential as gasification catalyst. To verify the literature reported, melting points for various compositions consisting of these three salts and the temperature range over which the mixture remained molten were determined in the lab. For mixtures with different concentrations of the three salts, the temperatures at which the mixtures were found to be in complete molten state were recorded. By increasing the amount of Li2CO3, the melting temperature range was reduced significantly. In the literature, the eutectic mixtures of Li- Na- and K-carbonates are claimed to have a lower activation energy than that of K2CO3 alone and they remain molten at a lower temperature than pure K2CO3. The slow increase in the gasification rates with eutectics reported in the literature is believed to be due to a gradual penetration of the coals and coal char particles by the molten and viscous catalyst phase. The even spreading of the salt phase seems to increase the overall carbon conversion rate. In the next reporting period, a number of eutectic salts and methods of their application on the coal will be identified and tested.

Atul Sheth; Pradeep Agrawal; Yaw D. Yeboah

1998-12-04T23:59:59.000Z

348

Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Salt Waste Processing Facility Salt Waste Processing Facility Technology Readiness Assessment Report Kurt D. Gerdes Harry D. Harmon Herbert G. Sutter Major C. Thompson John R. Shultz Sahid C. Smith July 13, 2009 Prepared by the U.S. Department of Energy Washington, D.C. SRS Salt Waste Processing Facility Technology Readiness Assessment July 13, 2009 ii This page intentionally left blank SRS Salt Waste Processing Facility Technology Readiness Assessment July 13, 2009 iii SRS Salt Waste Processing Facility Technology Readiness Assessment July 13, 2009 iii Signatures SRS Salt Waste Processing Facility Technology Readiness Assessment July 13, 2009 iv This page intentionally left blank SRS Salt Waste Processing Facility

349

Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Salt Lake City Fuels Salt Lake City Fuels Vehicles With Natural Gas to someone by E-mail Share Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Facebook Tweet about Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Twitter Bookmark Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Google Bookmark Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Delicious Rank Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Digg Find More places to share Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on AddThis.com... May 14, 2011 Salt Lake City Fuels Vehicles With Natural Gas W atch how Salt Lake City fuels vehicles with liquefied and compressed

350

LIFE Materails: Molten-Salt Fuels Volume 8  

SciTech Connect

The goals of the Laser Inertial Fusion Fission Energy (LIFE) is to use fusion neutrons to fission materials with no enrichment and minimum processing and have greatly reduced wastes that are not of interest to making weapons. Fusion yields expected to be achieved in NIF a few times per day are called for with a high reliable shot rate of about 15 per second. We have found that the version of LIFE using TRISO fuel discussed in other volumes of this series can be modified by replacing the molten-flibe-cooled TRISO fuel zone with a molten salt in which the same actinides present in the TRISO particles are dissolved in the molten salt. Molten salts have the advantage that they are not subject to radiation damage, and hence overcome the radiation damage effects that may limit the lifetime of solid fuels such as TRISO-containing pebbles. This molten salt is pumped through the LIFE blanket, out to a heat exchanger and back into the blanket. To mitigate corrosion, steel structures in contact with the molten salt would be plated with tungsten or nickel. The salt will be processed during operation to remove certain fission products (volatile and noble and semi-noble fission products), impurities and corrosion products. In this way neutron absorbers (fission products) are removed and neutronics performance of the molten salt is somewhat better than that of the TRISO fuel case owing to the reduced parasitic absorption. In addition, the production of Pu and rare-earth elements (REE) causes these elements to build up in the salt, and leads to a requirement for a process to remove the REE during operation to insure that the solubility of a mixed (Pu,REE)F3 solid solution is not exceeded anywhere in the molten salt system. Removal of the REE will further enhance the neutronics performance. With molten salt fuels, the plant would need to be safeguarded because materials of interest for weapons are produced and could potentially be removed.

Moir, R; Brown, N; Caro, A; Farmer, J; Halsey, W; Kaufman, L; Kramer, K; Latkowski, J; Powers, J; Shaw, H; Turchi, P

2008-12-11T23:59:59.000Z

351

Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor  

Science Conference Proceedings (OSTI)

This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

Scheele, Randall D.; Casella, Andrew M.

2010-09-28T23:59:59.000Z

352

High thermal energy storage density molten salts for parabolic trough solar power generation.  

E-Print Network (OSTI)

??New alkali nitrate-nitrite systems were developed by using thermodynamic modeling and the eutectic points were predicted based on the change of Gibbs energy of fusion.… (more)

Wang, Tao

2011-01-01T23:59:59.000Z

353

Conversion of carboxylate salts to carboxylic acids via reactive distillation  

E-Print Network (OSTI)

The purpose of this study is to convert carboxylate salts (e.g. calcium acetate, propionate, and butyrate) into carboxylic acids (e.g., acetic, propionic, and butyric acids). The carboxylate salts can be produced from wastes, such as paper fines, municipal solid wastes, sewage sludge, and industrial biosludge. Using a proprietary technology owned by Texas A&M University the wastes are first treated with lime to enhance reactivity. Then they are converted to calcium carboxylate salts using a mixed culture of microorganisms derived from cattle rumen or anaerobic waste treatment facilities. The paper fines and municipal solid waste provide energy, whereas the industrial biosludge and sewage sludge provide nutrients for the microorganisms. The calcium carboxylate salts are concentrated and reacted with a low-molecular-weight tertiary amine and carbon dioxide to precipitate calcium carbonate. In a distillation column, the low-molecular-weight amine carboxylate reacts with a high-molecular-weight tertiary amine allowing the low-molecular-weight amine to be recovered from the top of the column. The resulting high-molecular-weight amine carboxylate is converted to amine and carboxylic acid in a reactive distillation column. This project focuses on the conversion of the carboxylate salts produced via fermentation into their corresponding acids via reactive distillation. The primary objective is to determine the optimal operating conditions of the distillation. A secondary objective is to optimize the precipitation step in the recovery process.

Williamson, Shelly Ann

2000-01-01T23:59:59.000Z

354

Method for making a uranium chloride salt product  

DOE Patents (OSTI)

The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Lockport, IL)

2004-10-05T23:59:59.000Z

355

Effect of water in salt repositories. Final report  

Science Conference Proceedings (OSTI)

Additional results confirm that during most of the consolidation of polycrystalline salt in brine, the previously proposed rate expression applies. The final consolidation, however, proceeds at a lower rate than predicted. The presence of clay hastens the consolidation process but does not greatly affect the previously observed relationship between permeability and void fraction. Studies of the migration of brine within polycrystalline salt specimens under stress indicate that the principal effect is the exclusion of brine as a result of consolidation, a process that evidently can proceed to completion. No clear effect of a temperature gradient could be identified. A previously reported linear increase with time of the reciprocal permeability of salt-crystal interfaces to brine was confirmed, though the rate of increase appears more nearly proportional to the product of sigma ..delta..P rather than sigma ..delta..P/sup 2/ (sigma is the uniaxial stress normal to the interface and ..delta..P is the hydraulic pressure drop). The new results suggest that a limiting permeability may be reached. A model for the permeability of salt-crystal interfaces to brine is developed that is reasonably consistent with the present results and may be used to predict the permeability of bedded salt. More measurements are needed, however, to choose between two limiting forms of the model.

Baes, C.F. Jr.; Gilpatrick, L.O.; Kitts, F.G.; Bronstein, H.R.; Shor, A.J.

1983-09-01T23:59:59.000Z

356

Corrosion of stainless and carbon steels in molten mixtures of industrial nitrates  

DOE Green Energy (OSTI)

Corrosion behavior of two stainless steels and carbon steel in mixtures of NaNO{sub 3} and KNO{sub 3} was evaluated to determine if impurities found in commodity grades of alkali nitrates aggravate corrosivity as applicable to an advanced solar thermal energy system. Corrosion tests were conducted for 7000 hours with Types 304 and 316 stainless steels at 570C and A36 carbon steel at 316C in seven mixtures of NaNO{sub 3} and KNO{sub 3} containing variations in impurity concentrations. Corrosion tests were also conducted in a ternary mixture of NaNO{sub 3}, KNO{sub 3}, and Ca(NO{sub 3}){sub 2}. Corrosion rates were determined by descaled weight losses while oxidation products were examined by scanning electron microscopy, electron microprobe analysis, and X-ray diffraction. The nitrate mixtures were periodically analyzed for changes in impurity concentrations and for soluble corrosion products.

Goods, S.H.; Bradshaw, R.W. [Sandia National Labs., Livermore, CA (United States); Prairie, M.R.; Chavez, J.M. [Sandia National Labs., Albuquerque, NM (United States)

1994-03-01T23:59:59.000Z

357

USE OF A UNIQUE BIOBARRIER TO REMEDIATE NITRATE AND PERCHLORATE IN GROUNDWATER  

SciTech Connect

Research was conducted to evaluate a multiple-layer system of volcanic rock, limestone, Apatite mineral and a 'biobarrier' to impede migration of radionuclides, metals and colloids through shallow alluvial groundwater, while simultaneously destroying contaminants such as nitrate and perchlorate. The 'bio' portion of this Multi-Barrier system uses highly porous, slowly degradable, carbon-based material (pecan shells) that serves as an energy source and supports the growth of indigenous microbial populations capable of destroying biodegradable compounds. The studies, using elevated nitrate concentrations in groundwater, have demonstrated reduction from levels of 6.5-9.7 mM nitrate (400-600 mg/L) to below discharge limits (0.16 mM nitrate). Perchlorate levels of 4.3 {micro}M (350 {micro}g/L) were also greatly reduced. Elevated levels of nitrate in drinking water are a public health concern, particularly for infants and adults susceptible to gastric cancer. Primary sources of contamination include feedlots, agriculture (fertilization), septic systems, mining and nuclear operations. A major source of perchlorate contamination in water is ammonium perchlorate from manufacture/use of rocket propellants. Perchlorate, recently identified as an EPA contaminant of concern, may affect thyroid function and cause tumor formation. A biobarrier used to support the growth of microbial populations (i.e. a biofilm) is a viable and inexpensive tool for cleaning contaminated groundwater. Aquatic ecosystems and human populations worldwide are affected by contaminated water supplies. One of the most frequent contaminants is nitrate. Remediation of nitrate in groundwater and drinking water by biodegradation is a natural solution to this problem. Microbial processes play an extremely important role in in situ groundwater treatment technologies. The assumption of carbon limitation is the basis for addition of carbon-based substrates to a system in the development of bioremediation schemes for nitrate-contaminated groundwater. The biobarrier concept typically involves construction of a wall of porous carbon-based material that is placed in a trench perpendicular to the direction of groundwater flow that extends at least the width and depth of the contaminant plume. A biobarrier can be used as a stand-alone system when biodegradable materials are the only contaminants, or it can be used along with other barriers, as has been done in the LANL Multi-Barrier system, designed to remediate multiple contaminants. The groundwater system must be reasonably well characterized in terms of direction of flow, width and depth of plume, concentrations along the plume, flow velocity and hydraulic conductivity. Barrier technology is largely applicable to shallow, alluvial plumes (less than 20 feet deep), although permeable reactive barriers (PRBs) have been placed at much greater depths, up to 70 ft. deep. Under these conditions, a barrier could be placed across the plume downstream from the source to prevent migration from a controlled site. The most effective barrier materials are natural waste materials of high porosity, resistant to degradation, that will not require removal or replacement with time. Pecan shells are a significant waste problem in pecan-growing areas. The most commonly used solution is land disposal. Use in biobarriers provides a desirable alternative. Pecan shells are composed of cellulose and lignin, and they degrade very slowly, providing a 'time-release' carbon source. If left uncrushed, they provide a high porosity material. Fishbone is a waste product made of calcium phosphate, or hydroxyapatite, which is very resistant to deterioration. Apatite-II effectively removes dissolved metals and radionuclides from groundwater. The precipitates formed with metals and radionuclides are highly insoluble and very unlikely to leach subsequently from the barrier. The residual tissue associated with the fishbones provides nutrient materials that contribute to formation of a microbial population as an additional benefit. W

Strietelmeier, E. A. (Elizabeth A.); Espinosa, Melissa L. (Melissa L.); Adams, J. D. (Joshua D. ); Leonard, P. A. (Patricia A.); Hodge, E. M. (Evangeline M.)

2001-01-01T23:59:59.000Z

358

Salt Waste Processing Facility Fact Sheet | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Services » Waste Management » Tank Waste and Waste Processing » Services » Waste Management » Tank Waste and Waste Processing » Salt Waste Processing Facility Fact Sheet Salt Waste Processing Facility Fact Sheet Nuclear material production operations at SRS resulted in the generation of liquid radioactive waste that is being stored, on an interim basis, in 49 underground waste storage tanks in the F- and H-Area Tank Farms. SWPF Fact Sheet More Documents & Publications EIS-0082-S2: Amended Record of Decision Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report EIS-0082-S2: Record of Decision Waste Management Nuclear Materials & Waste Tank Waste and Waste Processing Waste Disposition Packaging and Transportation Site & Facility Restoration Deactivation & Decommissioning (D&D)

359

Savannah River Site - Salt Waste Processing Facility Independent Technical Review  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

SALT WASTE PROCESSING FACILITY SALT WASTE PROCESSING FACILITY INDEPENDENT TECHNICAL REVIEW November 22, 2006 Conducted by: Harry Harmon, Team Lead Civil/Structural Sub Team Facility Safety Sub Team Engineering Sub Team Peter Lowry, Lead James Langsted, Lead George Krauter, Lead Robert Kennedy Chuck Negin Art Etchells Les Youd Jerry Evatt Oliver Block Loring Wyllie Richard Stark Tim Adams Tom Anderson Todd LaPointe Stephen Gosselin Carl Costantino Norman Moreau Patrick Corcoran John Christian Ken Cooper Kari McDaniel _____________________________ Harry D. Harmon ITR Team Leader SPD-SWPF-217 SPD-SWPF-217: Salt Waste Processing Facility Independent Technical Review 11/22/2006 ACKNOWLEDGEMENT The ITR Team wishes to thank Shari Clifford of Pacific Northwest National Laboratory for

360

Columbus Salt Marsh Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Columbus Salt Marsh Geothermal Area Columbus Salt Marsh Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Columbus Salt Marsh Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (0) 9 Exploration Activities (3) 10 References Area Overview Geothermal Area Profile Location: California Exploration Region: Walker-Lane Transition Zone Geothermal Region GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure Operating Power Plants: 0 No geothermal plants listed.

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Injector nozzle for molten salt destruction of energetic waste materials  

DOE Patents (OSTI)

An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath. 2 figs.

Brummond, W.A.; Upadhye, R.S.

1996-02-13T23:59:59.000Z

362

Injector nozzle for molten salt destruction of energetic waste materials  

DOE Patents (OSTI)

An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath.

Brummond, William A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA)

1996-01-01T23:59:59.000Z

363

Tests of prototype salt stripper system for IFR fuel cycle  

Science Conference Proceedings (OSTI)

One of the waste treatment steps for the on-site reprocessing of spent fuel from the Integral Fast Reactor fuel cycles is stripping of the electrolyte salt used in the electrorefining process. This involves the chemical reduction of the actinides and rare earth chlorides forming metals which then dissolve in a cadmium pool. To develop the equipment for this step, a prototype salt stripper system has been installed in an engineering scale argon-filled glovebox. Pumping trails were successful in transferring 90 kg of LiCl-KCl salt containing uranium and rare earth metal chlorides at 500{degree}C from an electrorefiner to the stripper vessel at a pumping rate of about 5 L/min. The freeze seal solder connectors which were used to join sections of the pump and transfer line performed well. Stripping tests have commenced employing an inverted cup charging device to introduce a Cd-15 wt % Li alloy reductant to the stripper vessel.

Carls, E.L.; Blaskovitz, R.J.; Johnson, T.R. [Argonne National Lab., IL (United States); Ogata, T. [Central Research Inst. of Electric Power Industry, Tokyo (Japan)

1993-09-01T23:59:59.000Z

364

The Effect of Nanoparticle Concentration on Thermo-physical Properties of Alumina-nitrate Nanofluid  

E-Print Network (OSTI)

The objective of this study was to determine how Al2O3 nanoparticle concentration affected the specific heat, heat of fusion, melting point, thermal diffusivity and thermal conductivity of Alumina-Nitrate nanofluids. Al2O3 nanoparticles were dispersed in a eutectic of sodium nitrate and potassium nitrate (60:40 for mole fraction) to create nanofluids using a hot plate evaporation method and an air dryer method. The nominal Al2O3 (alumina) mass fraction was between 0 and 2%, and was determined as the ratio of the mass of Al2O3 nanoparticles to the total mass of the nanofluid. After the preparation of the nanofluids, Neutron Activation Analysis (NAA) was used to measure the actual Al2O3 mass fraction in the nanofluids. The specific heat, heat of fusion, and melting point were measured with a Modulated Differential Scanning Calorimeter (MDSC). The thermal diffusivity and thermal conductivity were measured with Laser Flash Analysis (LFA). The MDSC results showed that the addition of Al2O3 nanoparticles enhanced the specific heat of the nanofluids synthesize from both methods. There was a parabolic relation between the specific heat and the Al2O3 mass fraction for the nanofluids synthesized from the hot plate evaporation method, with a maximum 31% enhancement at 0.78% Al2O3 mass fraction. The nanofluids synthesized from the air dryer method also resulted in enhanced specific heats which were higher at the same Al2O3 mass fraction than those of the nanofluids synthesized from the hot plate evaporation method. It was not determined why this enhancement occurred. The results also showed that the introduction of Al2O3 nanoparticles had no significant effect on the heat of fusion and melting point of the nanofluids synthesized from either method. The LFA results showed that adding Al2O3 nanoparticles decreased the thermal diffusivity and the thermal conductivity of the nitrate eutectic.

Shao, Qian

2013-05-01T23:59:59.000Z

365

Salt transport extraction of transuranium elements from lwr fuel  

DOE Patents (OSTI)

A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl.sub.2 and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750.degree. C. to about 850.degree. C. to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl.sub.2 having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO.sub.2. The Ca metal and CaCl.sub.2 is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including Mg Cl.sub.2 to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy.

Pierce, R. Dean (Naperville, IL); Ackerman, John P. (Downers Grove, IL); Battles, James E. (Oak Forest, IL); Johnson, Terry R. (Wheaton, IL); Miller, William E. (Naperville, IL)

1992-01-01T23:59:59.000Z

366

Salt transport extraction of transuranium elements from LWR fuel  

DOE Patents (OSTI)

A process is described for separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl[sub 2] and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750 C to about 850 C to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl[sub 2] having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO[sub 2]. The Ca metal and CaCl[sub 2] is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including MgCl[sub 2] to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy. 2 figs.

Pierce, R.D.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Miller, W.E.

1992-11-03T23:59:59.000Z

367

Salt transport extraction of transuranium elements from LWR fuel  

DOE Patents (OSTI)

This report discusses a process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl{sub 2} and a Cu-Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750{degrees}C to about 850{degrees}C to precipitate uranium metal and some of the noble metal fission products leaving the Cu-Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl{sub 2} having Cao and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO{sub 2}. The Ca metal and CaCl{sub 2} is recycled to reduce additional oxide fuel. The Cu-Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including Mg C1{sub 2} to transfer Mg values from the transport salt to the Cu-Mg alloy .hile transuranium actinide and rare earth fission product metals transfer from the Cu-Mg alloy to the transport salt. Then the transport salt is mixed with a Mg-Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg-Zn alloy.

Pierce, R.D.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Miller, W.E.

1991-12-31T23:59:59.000Z

368

Nitrogen cycling in oxygen deficient zones : insights from [delta]¹?N and [delta]¹?O of nitrite and nitrate  

E-Print Network (OSTI)

The stable isotopes, [delta]¹?N and [delta]¹?O, of nitrite and nitrate can be powerful tools used to interpret nitrogen cycling in the ocean. They are particularly useful in regions of the ocean where there are multiple ...

Buchwald, Carolyn

2013-01-01T23:59:59.000Z

369

Aqueous nitrate waste treatment: Technology comparison, cost/benefit, and market analysis  

SciTech Connect

The purpose of this analysis is to provide information necessary for the Department of Energy (DOE) to evaluate the practical utility of the Nitrate to Ammonia and Ceramic or Glass (NAC/NAG/NAX) process, which is under development in the Oak Ridge National Laboratory. The NAC/NACx/NAX process can convert aqueous radioactive nitrate-laden waste to a glass, ceramic, or grout solid waste form. The tasks include, but are not limited to, the following: Identify current commercial technologies to meet hazardous and radiological waste disposal requirements. The technologies may be thermal or non-thermal but must be all inclusive (i.e., must convert a radionuclide-containing nitrate waste with a pH around 12 to a stable form that can be disposed at permitted facilities); evaluate and compare DOE-sponsored vitrification, grouting, and minimum additive waste stabilization projects for life-cycle costs; compare the technologies above with respect to material costs, capital equipment costs, operating costs, and operating efficiencies. For the NAC/NAG/NAX process, assume aluminum reactant is government furnished and ammonia gas may be marketed; compare the identified technologies with respect to frequency of use within DOE for environmental management applications with appropriate rationale for use; Assess the potential size of the DOE market for the NAC/NAG/NAX process; assess and off-gas issues; and compare with international technologies, including life-cycle estimates.

1994-01-01T23:59:59.000Z

370

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

SciTech Connect

This progress report on the Department of Energy project DE-FG-97FT97263 entitled, ''Catalytic Gasification of Coal Using Eutectic Salt Mixtures'', covers the period April-September 1998. The specific aims of the project for this period were to identify appropriate eutectic salt mixture catalysts for the gasification of Illinois No.6 coal, evaluate various impregnation or catalyst addition methods to improve catalyst dispersion, and evaluate gasification performance in a bench-scale fixed bed reactor. The project is being conducted jointly by Clark Atlanta University (CAU), the University of Tennessee Space Institute (UTSI) and the Georgia Institute of Technology (Georgia Tech) with CAU as the prime contractor. Several single salt catalysts and binary and ternary eutectic catalysts were investigated at Clark Atlanta University. Physical mixing and incipient wetness methods were investigated as catalyst addition techniques. Gasification was carried out using TGA at CAU and UTSI and with a fixed-bed reactor at UTSI. The results showed better gasification activity in the presence of the catalysts tested. The eutectic salt studies showed clear agreement between the melting points of the prepared eutectics and reported literature values. The order of catalytic activity observed was ternary > binary > single salt. With the soluble single salt catalysts, the incipient wetness method was found to give better results than physical mixing technique. Also, catalyst preparation conditions such as catalyst loading, drying time and temperature were found to influence the gasification rate. Based on the Clark Atlanta University studies on Task 1, the project team selected the 43.5%Li{sub 2}CO{sub 3}-31.5%Na{sub 2}CO{sub 3}-25%K{sub 2}CO{sub 3} ternary eutectic and the 29%Na{sub 2}CO{sub 3}-71%K{sub 2}CO{sub 3} and 2.3% KNO{sub 3}-97.7%K{sub 2}CO{sub 3} binary eutectic for the fixed bed studies at UTSI. The eutectic salts were found to be highly insoluble in aqueous medium. As a result the technique of adding the eutectic to the raw coal was found to be better than using wet methods. Also, addition of the catalyst to the raw coal appeared to give better gasification results than addition to pyrolyzed coal. In addition, eutectic catalysts added to the coal yielded better gasification rates than rates obtained by mixing the individual salts in the eutectic ratio with the coal. These results, especially with the eutectic catalysts are very significant since the use of the low melting eutectics will reduce the severity of gasification processes.

NONE

2000-04-01T23:59:59.000Z

371

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

Science Conference Proceedings (OSTI)

This progress report on the Department of Energy project DE-FG-97FT97263 entitled, ''Catalytic Gasification of Coal Using Eutectic Salt Mixtures,'' covers the period April-September 1998. The specific aims of the project for this period were to identify appropriate eutectic salt mixture catalysts for the gasification of Illinois No.6 coal, evaluate various impregnation or catalyst addition methods to improve catalyst dispersion, and evaluate gasification performance in a bench-scale fixed bed reactor. The project is being conducted jointly by Clark Atlanta University (CAU), the University of Tennessee Space Institute (UTSI) and the Georgia Institute of Technology (Georgia Tech) with CAU as the prime contractor. Several single salt catalysts and binary and ternary eutectic catalysts were investigated at Clark Atlanta University. Physical mixing and incipient wetness methods were investigated as catalyst addition techniques. Gasification was carried out using TGA at CAU and UTSI and with a fixed-bed reactor at UTSI. The results showed better gasification activity in the presence of the catalysts tested. The eutectic salt studies showed clear agreement between the melting points of the prepared eutectics and reported literature values. The order of catalytic activity observed was ternary > binary > single salt. With the soluble single salt catalysts, the incipient wetness method was found to give better results than physical mixing technique. Also, catalyst preparation conditions such as catalyst loading, drying time and temperature were found to influence the gasification rate. Based on the Clark Atlanta University studies on Task 1, the project team selected the 43.5%Li{sub 2}CO{sub 3}-31.5%Na{sub 2}CO{sub 3}-25%K{sub 2}CO{sub 3} ternary eutectic and the 29%Na{sub 2}CO{sub 3}-71%K{sub 2}CO{sub 3} and 2.3%KNO{sub 3}-97.7%K{sub 2}CO{sub 3} binary eutectic for the fixed bed studies at UTSI. The eutectic salts were found to be highly insoluble in aqueous medium. As a result the technique of adding the eutectic to the raw coal was found to be better than using wet methods. Also, addition of the catalyst to the raw coal appeared to give better gasification results than addition to pyrolyzed coal. In addition, eutectic catalysts added to the coal yielded better gasification rates than rates obtained by mixing the individual salts in the eutectic ratio with the coal. These results, especially with the eutectic catalysts are very significant since the use of the low melting eutectics will reduce the severity of gasification processes.

NONE

1998-10-01T23:59:59.000Z

372

Clean Cities Award Winning Coalition: Salt Lake City  

DOE Green Energy (OSTI)

Since its designation as a national Clean City in 1994, Salt Lake Clean Cities has put more than 2,600 alternative fuel vehicles (AFVs) on community streets. The 82 business, nonprofit, and government agencies that comprise the coalition are all dedicated to cleaning the air by reducing vehicle exhaust. Salt Lake Clean Cities has the third largest compressed natural gas and propane-refueling infrastructure in the country, with 98 locations available. They sponsor an annual ''Spring Soiree'' to increase public awareness about the program and educate the public about the benefits of alternative fuel and AFVs.

ICF Kaiser

1999-05-20T23:59:59.000Z

373

Simulation of water transport in heated rock salt  

Science Conference Proceedings (OSTI)

This paper summarizes computer simulation studies on water transport in German rock salt. Based on JOCKWERS experimental investigations on water content and water liberation, the object of these studies was to select a water transport model, that matches the water inflow which was measured in some heater experiments in the Asse Salt Mine. The main result is, that an evaporation front model, with Knudsen-type vapor transport combined with fluid transport by thermal expansion of the adsorbed water layers in the non evaporated zone, showed the best agreement with experimental evidence.

Schlich, M.; Jockwer, N.

1986-01-01T23:59:59.000Z

374

Reduction of Perchlorate and Nitrate by Aluminum Activated by pH Change and Electrochemically Induced Pitting Corrosion.  

E-Print Network (OSTI)

Highly oxidized species like perchlorate and nitrate that are released into the environment by anthropogenic activities are a source of concern as they have been known to contaminate groundwater. These species are extremely soluble in water and can migrate through aquifer systems, travelling substantial distances from the original site of contamination. Due to their high solubility, these oxy-anions cannot be treated using conventional treatment processes like filtration and sedimentation. Several treatment technologies are currently available to abate the human health risk due to exposure to perchlorate and nitrate. However, most of the existing treatment processes are expensive or have limitations, like generation of brines with high concentrations of perchlorate or nitrate. Aluminum can effectively reduce perchlorate and nitrate, if the protective oxide film that separates the thermodynamically reactive Al0 from most environments is removed. Aluminum was activated by pH change and electrochemically induced, pitting corrosion to remove the passivating oxide layer and expose the underlying, thermodynamically reactive, zero-valent aluminum. A partially oxidized species of aluminum, like monovalent aluminum, is believed to bring about the reduction of perchlorate and nitrate. This research studied the reduction of perchlorate and nitrate by aluminum that was activated by these two mechanisms. Results indicated that aluminum activated by pH change resulted in an instantaneous decrease in perchlorate concentration without any increase in chlorate or chloride concentrations, which suggests that the perchlorate might be adsorbed on the aluminum oxide surface. However, aluminum activated by electrochemically induced pitting corrosion can effectively reduce perchlorate to chlorate. Nitrate, on the other hand, was reduced completely to ammonia by both treatment mechanisms. The studies conducted in this dissertation suggest that aluminum can be effectively used as a reducing agent to develop a treatment process to reduce perchlorate and nitrate.

Raut Desai, Aditya B.

2010-05-01T23:59:59.000Z

375

Impact of nitrate-enhanced leachate recirculation on gaseous releases from a landfill bioreactor cell  

SciTech Connect

This study evaluates the impact of nitrate injection on a full scale landfill bioreactor through the monitoring of gaseous releases and particularly N{sub 2}O emissions. During several weeks, we monitored gas concentrations in the landfill gas collection system as well as surface gas releases with a series of seven static chambers. These devices were directly connected to a gas chromatograph coupled to a flame ionisation detector and an electron capture detector (GC-FID/ECD) placed directly on the field. Measurements were performed before, during and after recirculation of raw leachate and nitrate-enhanced leachate. Raw leachate recirculation did not have a significant effect on the biogas concentrations (CO{sub 2}, CH{sub 4} and N{sub 2}O) in the gas extraction network. However, nitrate-enhanced leachate recirculation induced a marked increase of the N{sub 2}O concentrations in the gas collected from the recirculation trench (100-fold increase from 0.2 ppm to 23 ppm). In the common gas collection system however, this N{sub 2}O increase was no more detectable because of dilution by gas coming from other cells or ambient air intrusion. Surface releases through the temporary cover were characterized by a large spatial and temporal variability. One automated chamber gave limited standard errors over each experimental period for N{sub 2}O releases: 8.1 {+-} 0.16 mg m{sup -2} d{sup -1} (n = 384), 4.2 {+-} 0.14 mg m{sup -2} d{sup -1} (n = 132) and 1.9 {+-} 0.10 mg m{sup -2} d{sup -1} (n = 49), during, after raw leachate and nitrate-enhanced leachate recirculation, respectively. No clear correlation between N{sub 2}O gaseous surface releases and recirculation events were evidenced. Estimated N{sub 2}O fluxes remained in the lower range of what is reported in the literature for landfill covers, even after nitrate injection.

Tallec, G.; Bureau, C. [Cemagref, UR HBAN, Parc de Tourvoie, BP44, F-92163 Antony (France); Peu, P.; Benoist, J.C. [Cemagref, UR GERE, 17 Avenue de Cucille, CS 64427, F-35044 Rennes (France); Lemunier, M. [Suez-Environnement, CIRADE, 38 Av. Jean Jaures, 78440 Gargenville (France); Budka, A.; Presse, D. [SITA France, 132 Rue des 3 Fontanot, 92000 Nanterre Cedex (France); Bouchez, T. [Cemagref, UR HBAN, Parc de Tourvoie, BP44, F-92163 Antony (France)], E-mail: theodore.bouchez@cemagref.fr

2009-07-15T23:59:59.000Z

376

Ion Partitioning at the liquid/vapor interface of a multi-component alkali halide solution: A model for aqueous sea salt aerosols  

E-Print Network (OSTI)

model for aqueous sea salt aerosols Sutapa Ghosal, 1 Matthewwith sea salt ice and aerosols has been implicated in theof aqueous sea salt aerosols and particles have been

Ghosal, Sutapa

2009-01-01T23:59:59.000Z

377

Optimization and preconceptual design of a 5 MWe salt-gradient solar pond power plant at Great Salt Lake  

DOE Green Energy (OSTI)

The techniques used to optimize and design a solar salt-gradient pond (SSP) power plant for installation at the Great Salt Lake are described. The method and results of the site selection study are described as well as the characteristics of the selected site. The figure of merit used as well as the characteristics of the selected site. The figure of merit used in the optimization study, the general optimization approach, and the specific optimization method used for each subsystem are described. Results are then discussed of the optimization of the pond configuration, total system, and piping. Pond design and ground rule sensitivity studies are reported. (LEW)

Drost, M.K.; Brown, L.M.; Barnhart, J.S.; Cavola, R.G.; Hauser, S.G.; Johnson, B.M.

1983-05-01T23:59:59.000Z

378

Categorical Exclusion Determinations: Golden Field Office | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

June 3, 2013 June 3, 2013 CX-010507: Categorical Exclusion Determination Development and Demonstration of Smart Grid Inverters for High-Penetration Photovoltaic Applications CX(s) Applied: A9, B3.6, B5.16 Date: 06/03/2013 Location(s): Hawaii Offices(s): Golden Field Office June 3, 2013 CX-010504: Categorical Exclusion Determination Installation of Additional Wind Turbine and Tower at NWTC Site 3.2 CX(s) Applied: B5.18 Date: 06/03/2013 Location(s): Colorado Offices(s): Golden Field Office June 3, 2013 CX-010503: Categorical Exclusion Determination Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9, B3.6, B5.17 Date: 06/03/2013 Location(s): Colorado, Colorado Offices(s): Golden Field Office June 3, 2013 CX-010502: Categorical Exclusion Determination Sacramento Municipal Utility District: Community Renewable Energy

379

Categorical Exclusion Determinations: B5.17 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

7 7 Categorical Exclusion Determinations: B5.17 Existing Regulations B5.17: Solar thermal systems The installation, modification, operation, and removal of commercially available small-scale solar thermal systems (including, but not limited to, solar hot water systems) located on or contiguous to a building, and if located on land, generally comprising less than 10 acres within a previously disturbed or developed area. Covered actions would be in accordance with applicable requirements (such as local land use and zoning requirements) in the proposed project area and would incorporate appropriate control technologies and best management practices. DOCUMENTS AVAILABLE FOR DOWNLOAD June 3, 2013 CX-010503: Categorical Exclusion Determination Baseload Nitrate Salt Central Receiver Power Plant Design

380

Categorical Exclusion (CX) Determinations By Date | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3, 2013 3, 2013 CX-010507: Categorical Exclusion Determination Development and Demonstration of Smart Grid Inverters for High-Penetration Photovoltaic Applications CX(s) Applied: A9, B3.6, B5.16 Date: 06/03/2013 Location(s): Hawaii Offices(s): Golden Field Office June 3, 2013 CX-010504: Categorical Exclusion Determination Installation of Additional Wind Turbine and Tower at NWTC Site 3.2 CX(s) Applied: B5.18 Date: 06/03/2013 Location(s): Colorado Offices(s): Golden Field Office June 3, 2013 CX-010503: Categorical Exclusion Determination Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9, B3.6, B5.17 Date: 06/03/2013 Location(s): Colorado, Colorado Offices(s): Golden Field Office June 3, 2013 CX-010502: Categorical Exclusion Determination Sacramento Municipal Utility District: Community Renewable Energy

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

61 - 4870 of 31,917 results. 61 - 4870 of 31,917 results. Download CX-010239: Categorical Exclusion Determination Low-Cost Gas Heat Pump for Building Space Heating CX(s) Applied: A9, B3.6 Date: 02/14/2013 Location(s): Tennessee Offices(s): Golden Field Office http://energy.gov/nepa/downloads/cx-010239-categorical-exclusion-determination Download CX-010503: Categorical Exclusion Determination Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9, B3.6, B5.17 Date: 06/03/2013 Location(s): Colorado, Colorado Offices(s): Golden Field Office http://energy.gov/nepa/downloads/cx-010503-categorical-exclusion-determination Download CX-010504: Categorical Exclusion Determination Installation of Additional Wind Turbine and Tower at NWTC Site 3.2 CX(s) Applied: B5.18 Date: 06/03/2013

382

Categorical Exclusion (CX) Determinations By Date | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3, 2013 3, 2013 CX-010503: Categorical Exclusion Determination Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9, B3.6, B5.17 Date: 06/03/2013 Location(s): Colorado, Colorado Offices(s): Golden Field Office June 3, 2013 CX-010502: Categorical Exclusion Determination Sacramento Municipal Utility District: Community Renewable Energy Deployment- Coenergy Solar Facility at Sutter's Landing Park CX(s) Applied: B5.16 Date: 06/03/2013 Location(s): California Offices(s): Golden Field Office June 3, 2013 CX-010697: Categorical Exclusion Determination Notice of Proposed Rulemaking for New Energy Conservation Standards for Residential Furnace Fans CX(s) Applied: B5.1 Date: 06/03/2013 Location(s): CX: none Offices(s): Golden Field Office June 3, 2013 CX-010673: Categorical Exclusion Determination

383

Categorical Exclusion Determinations: Colorado | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

August 4, 2010 August 4, 2010 CX-003201: Categorical Exclusion Determination Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9 Date: 08/04/2010 Location(s): Colorado Office(s): Energy Efficiency and Renewable Energy, Golden Field Office July 30, 2010 CX-003332: Categorical Exclusion Determination Reclamation Projects on Wedding Bell Mountain Lease Tract C-WM-17, Uranium Leasing Program CX(s) Applied: B1.28 Date: 07/30/2010 Location(s): Montrose County, Colorado Office(s): Legacy Management July 30, 2010 CX-003331: Categorical Exclusion Determination Reclamation Projects on Slick Rock Lease Tract C-SR-II, Uranium Leasing Program CX(s) Applied: B1.28 Date: 07/30/2010 Location(s): San Miguel County, Colorado Office(s): Legacy Management July 30, 2010 CX-003333: Categorical Exclusion Determination

384

Rapid Removal of Chlorine in Molten Salt Electrolysis of Magnesium ...  

Science Conference Proceedings (OSTI)

However, experimental data and modeling results in this study indicate that the ... bubbles on the current efficiency and the cell potential were investigated. ... High- Chloride Circuit for the Starfield Resources' Ferguson Lake Project · Direct Synthesis of Niobium Aluminides Powders by Sodiothermic Reduction in Molten Salts.

385

[Polymer-in-salt electrolytes]. Annual report and extension proposal  

DOE Green Energy (OSTI)

The research proposed for the current grant consisted of five components, of which the authors have made substantial progress on three and have performed some exploratory work on a sixth for which they present here an argument for extending. The components on which they have made progress are: (1) development of and improvement on the basic polymer-in-salt idea. This will be separated into parts dealing with improvements in salt constitution, and improvements in polymer type, emphasizing the role of anionic polymers; (2) modifications of the polymer-in-salt electrolyte to include the addition of solid particulates to the salt-polymer matrix; and (3) physical measurements. The new component on which they have made some preliminary measurements over the summer period concerns the use of electrolytes developed under the present and other programs for improving the performance of photovoltaic cells. The rationale is that hole/electron separation in semiconductors under irradiation is aided by trapping the holes on a redox species in an adjacent electrolyte solution. The efficiency is proportional to a number of factors not fully understood, one of which is determined by the character of the electrolyte. Since the authors have new types of electrolytes under development, and since solar energy via photovoltaic is an environmentally important aspect of the energy sciences, they felt it was a desirable aspect of materials science to study in a laboratory in Arizona. Achievements in the past year are summarized.

Angell, C.A.

1998-12-31T23:59:59.000Z

386

Lake-Breeze Fronts in the Salt Lake Valley  

Science Conference Proceedings (OSTI)

Winds at the Salt Lake City International Airport (SLC) during the April–October period from 1948 to 2003 have been observed to shift to the north (up-valley direction) between late morning and afternoon on over 70% of the days without ...

Daniel E. Zumpfe; John D. Horel

2007-02-01T23:59:59.000Z

387

Mixing in a Moderately Sheared Salt-Fingering Layer  

Science Conference Proceedings (OSTI)

Mixing due to sheared salt fingers is studied by means of direct numerical simulations (DNS) of a double-diffusively unstable shear layer. The focus is on the “moderate shear” case, where shear is strong enough to produce Kelvin–Helmholtz (KH) ...

W. D. Smyth; S. Kimura

2011-07-01T23:59:59.000Z

388

SEPARATION OF PROTACTINIUM FROM MOLTEN SALT REACTOR FUEL COMPOSITIONS  

DOE Patents (OSTI)

A method for selectively precipitating protactinium from a neutron- irradiated fused fluoride salt composition comprising at least one metal fluoride selected from the group consisting of an alkali metal fluoride and an alkaline earth metal fluoride containing dissolved thorium-232 values is presented. An inorganic metal oxide corresponding to any of the metal fluorides of the composition is also added. (AEC)

Shaffer, J.H.; Strain, J.E.; Cuneo, D.R.; Kelly, M.J.

1963-11-12T23:59:59.000Z

389

Marine Fog Droplets and Salt Nuclei -Part 11  

Science Conference Proceedings (OSTI)

In Past 1 of this fog study, the distribution of water with number and size of drops in some New England marine advection fogs was shown to be related to the distribution of number and size of salt particles found in marine air. It was indicated ...

Alfred H. Woodcock; Duncan C. Blanchard; James E. Jiusto

1981-01-01T23:59:59.000Z

390

Salt Lake City, Utah: Solar in Action (Brochure)  

DOE Green Energy (OSTI)

This brochure provides an overview of the challenges and successes of Salt Lake City, UT, a 2007 Solar America City awardee, on the path toward becoming a solar-powered community. Accomplishments, case studies, key lessons learned, and local resource information are given.

Not Available

2011-10-01T23:59:59.000Z

391

Separation of alcohol-water mixtures using salts  

DOE Green Energy (OSTI)

Use of a salt (KF or Na/sub 2/SO/sub 4/) to induce phase separation of alcohol-water mixtures was investigated in three process flowsheets to compare operating and capital costs with a conventional distillation process. The process feed was the Clostridia fermentation product, composed of 98 wt % water and 2 wt % solvents (70% 1-butanol, 27% 2-propanol, and 3% ethanol). The design basis was 150 x 10/sup 6/ kg/y of solvents. Phase equilibria and tieline data were obtained from literature and experiments. Three separation-process designs were developed and compared by an incremental economic analysis (+-30%) with the conventional separation technique using distillation alone. The cost of salt recovery for recycle was found to be the critical feature. High capital and operating costs make recovery of salt by precipitation uneconomical; however, a separation scheme using multiple-effect evaporation for salt recovery has comparable incremental capital costs ($1.72 x 10/sup 6/ vs $1.76 x 10/sup 6/) and lower incremental operating costs ($2.14 x 10/sup 6//y vs $4.83 x 10/sup 6//y) than the conventional separation process.

Card, J. C.; Farrell, L. M.

1982-04-01T23:59:59.000Z

392

Fabricating of Lithium-Battery-Grade Precursor Salt Cobaltous Carbonate  

Science Conference Proceedings (OSTI)

Some factors affect precursor capability, for example: raw material CoCl2 solution impurity?feeding methods of reactants?solutions’ pH value of deposition reaction?washing conditions, etc.. Cobalt chloride is chosen as raw ... Keywords: Salt Cobalt Carbonate, Cobalt Chloride, battery-grade Precursor, Shape

Jian Zhou; Li-jun Li; Gong-xiu He; Ke Chen

2010-05-01T23:59:59.000Z

393

Solvent-free mechanochemical preparation of phosphonium salts ...  

The present invention provides a method of preparing a phosphonium salt of the formula [R.sup.1R.sup.2R.sup.3P--CR.sup.4R.sup.5R.sup.6]X, comprising ball-milling a ...

394

Design of Complex Systems to Achieve Passive Safety: Natural Circulation Cooling of Liquid Salt Pebble Bed Reactors  

E-Print Network (OSTI)

K. T. Assessment of Candidate Molten Salt Coolants for theK. T. Assessment of Candidate Molten Salt Coolants for thebeginning efforts for a molten salt reactor (MSR) program.

Scarlat, Raluca Olga

2012-01-01T23:59:59.000Z

395

Proceedings of 3rd US/German Workshop on Salt Repository Research, Design,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Proceedings of 3rd US/German Workshop on Salt Repository Research, Proceedings of 3rd US/German Workshop on Salt Repository Research, Design, and Operation Proceedings of 3rd US/German Workshop on Salt Repository Research, Design, and Operation The 3rd U.S./German Workshop on Salt Repository Research, Design and Operation was held in Albuquerque and Carlsbad, New Mexico on October 8-11, 2012. Approximately 60 salt research scientists from Germany and the United States met to discuss repository science state of the art. Workshop topics included: 1) Safety case for heat-generating waste disposal in salt; 2) Benchmark modeling in preparation for thermomechanical field-scale tests; and 3) Reconsolidation of granular salt. Collaboration being pursued by U.S. and German salt repository researchers is presented in the report.

396

New Opportunities for Metals Extraction and Waste Treatment by Electrochemical Processing in Molten Salts  

E-Print Network (OSTI)

Molten salt electrolysis is a proven technology for the extraction of metals -- all the world's primary aluminum is produced in this manner. The unique properties of molten salts also make them

Sadoway, Donald R.

2001-01-01T23:59:59.000Z

397

How different home styles are valued in the Salt Lake City market  

E-Print Network (OSTI)

This thesis focuses on market valuation of attributes of single family housing in the Salt Lake City market. Using data from different sub-regions of Salt Lake County, this paper addresses the question of buyer demand with ...

Peterson, Barrett, 1976-

2003-01-01T23:59:59.000Z

398

Mechanisms Driving the Time-Dependent Salt Flux in a Partially Stratified Estuary  

Science Conference Proceedings (OSTI)

The subtidal salt balance and the mechanisms driving the downgradient salt flux in the Hudson River estuary are investigated using measurements from a cross-channel mooring array of current meters, temperature and conductivity sensors, and cross-...

James A. Lerczak; W. Rockwell Geyer; Robert J. Chant

2006-12-01T23:59:59.000Z

399

BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY  

SciTech Connect

Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. A three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.

Lee, S.

2012-05-10T23:59:59.000Z

400

Preconceptual design of a salt splitting process using ceramic membranes  

SciTech Connect

Inorganic ceramic membranes for salt splitting of radioactively contaminated sodium salt solutions are being developed for treating U. S. Department of Energy tank wastes. The process consists of electrochemical separation of sodium ions from the salt solution using sodium (Na) Super Ion Conductors (NaSICON) membranes. The primary NaSICON compositions being investigated are based on rare- earth ions (RE-NaSICON). Potential applications include: caustic recycling for sludge leaching, regenerating ion exchange resins, inhibiting corrosion in carbon-steel tanks, or retrieving tank wastes; reducing the volume of low-level wastes volume to be disposed of; adjusting pH and reducing competing cations to enhance cesium ion exchange processes; reducing sodium in high-level-waste sludges; and removing sodium from acidic wastes to facilitate calcining. These applications encompass wastes stored at the Hanford, Savannah River, and Idaho National Engineering Laboratory sites. The overall project objective is to supply a salt splitting process unit that impacts the waste treatment and disposal flowsheets and meets user requirements. The potential flowsheet impacts include improving the efficiency of the waste pretreatment processes, reducing volume, and increasing the quality of the final waste disposal forms. Meeting user requirements implies developing the technology to the point where it is available as standard equipment with predictable and reliable performance. This report presents two preconceptual designs for a full-scale salt splitting process based on the RE-NaSICON membranes to distinguish critical items for testing and to provide a vision that site users can evaluate.

Kurath, D.E.; Brooks, K.P.; Hollenberg, G.W.; Clemmer, R. [Pacific Northwest National Lab., Richland, WA (United States); Balagopal, S.; Landro, T.; Sutija, D.P. [Ceramatec, Inc., Salt Lake City, UT (United States)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters  

DOE Patents (OSTI)

A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

Moens, Luc (Lakewood, CO)

2003-06-24T23:59:59.000Z

402

Thermodynamic analysis of spent pyrochemical salts in the stored condition and in viable accident scenarios  

Science Conference Proceedings (OSTI)

This study involves examining ``spent`` electrorefining (ER) salts in the form present after usage (as stored), and then after exposure to water in a proposed accident scenario. Additionally, the equilibrium composition of the salt after extended exposure to air was also calculated by computer modeling and those results are also presented herein. It should be noted that these salts are extremely similar to spent MSE salts from the Rocky Flats MSE campaigns using NaCl-KCl- MgCl{sub 2}.

Axler, K.M.

1994-03-01T23:59:59.000Z

403

Electrodialysis-based separation process for salt recovery and recycling from waste water  

DOE Patents (OSTI)

A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants-containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid. 6 figs.

Tsai, S.P.

1997-07-08T23:59:59.000Z

404

Drying radioactive wastewater salts using a thin film dryer  

SciTech Connect

This paper describes the operational experience in drying brines generated at a radioactive wastewater treatment facility. The brines are composed of aqueous ammonium sulfate/sodium sulfate and aqueous sodium nitrate/sodium sulfate, The brine feeds receive pretreatment to preclude dryer bridging and fouling. The dryer products are a distillate and a powder. The dryer is a vertical thin film type consisting of a steam heated cylinder with rotor. Maintenance on the dryer has been minimal. Although many operability problems have had to be overcome, dryer performance can now be said to be highly reliable.

Scully, D.E.

1998-03-19T23:59:59.000Z

405

Sample Results from the Interim Salt Disposition Program Macrobatch 6 Tank 21H Qualification Samples  

SciTech Connect

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 6 for the Interim Salt Disposition Project (ISDP). This document reports partial results of the analyses of samples of Tank 21H. No issues with the projected Salt Batch 6 strategy are identified.

Peters, T. B.; Fink, S. D.

2012-12-11T23:59:59.000Z

406

Sample Results From The Interim Salt Disposition Program Macrobatch 6 Tank 21H Qualification Samples  

Science Conference Proceedings (OSTI)

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 6 for the Interim Salt Disposition Project (ISDP). This document reports partial results of the analyses of samples of Tank 21H. No issues with the projected Salt Batch 6 strategy are identified.

Peters, T. B.; Fink, S. D.

2012-12-20T23:59:59.000Z

407

Bases, Assumptions, and Results of the Flowsheet Calculations for the Decision Phase Salt Disposition Alternatives  

SciTech Connect

The HLW salt waste (salt cake and supernate) now stored at the SRS must be treated to remove insoluble sludge solids and reduce the soluble concentration of radioactive cesium radioactive strontium and transuranic contaminants (principally Pu and Np). These treatments will enable the salt solution to be processed for disposal as saltstone, a solid low-level waste.

Elder, H.H.

2001-07-11T23:59:59.000Z

408

Roles of double salt formation and NaNO{sub 3} in Na{sub 2}CO{sub 3}-promoted MgO absorbent for intermediate temperature CO{sub 2} removal  

Science Conference Proceedings (OSTI)

Absorption and desorption of carbon dioxide on Na{sub 2}CO{sub 3}-promoted MgO have been studied at temperatures compatible with warm gas cleanup (300–470 ?C) from a pre-combustion syngas. The absorbents are synthesized through the formation and activation of the precipitate resulting from the addition of sodium carbonate to an aqueous solution of magnesium nitrate. The absorbent, which comprises MgO, Na{sub 2CO{sub 3} and residual NaNO{sub 3} after activation, forms the double salt Na{sub 2}Mg(CO{sub 3}){sub 2} on exposure to CO{sub 2}. The thermodynamic properties of the double salt, obtained through computational calculation, predict that the preferred temperature range for absorption of CO{sub 2} with the double salt is significantly higher compared with MgO. Faster CO{sub 2} uptake can be achieved as a result of this higher temperature absorption window. Absorption tests indicate that the double salt absorbent as prepared has a capacity toward CO{sub 2} of 15 wt.% (3.4 mmol CO{sub 2}/g absorbent) and can be easily regenerated through both pressure swing and temperature swing absorption in multiple-cycle tests. Thermodynamic calculations also predict an important effect of CO{sub 2} partial pressure on the absorption capacity in the warm temperature range. The impurity phase, NaNO{sub 3}, is identified as a key component in facilitating CO{sub 2} absorption by these materials. The reason for reported difficulties in reproducing the performance of these materials can be traced to specific details of the synthesis method, which are reviewed in some detail.

Keling Zhanga,b, Xiaohong S. Li c, Yuhua Duand, David L. Kingc,?, Prabhakar Singha,b, Liyu Li

2012-11-12T23:59:59.000Z

409

SunShot Initiative: Encapsulated Phase Change Material in Thermal Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Encapsulated Phase Change Material in Thermal Storage for Baseload CSP Plants Encapsulated Phase Change Material in Thermal Storage for Baseload CSP Plants Terrafore logo Photo of gray balls grouped together. 10 to 15 millimeter capsules provide high heat transfer surface. Terrafore, under the Baseload CSP FOA, is developing novel encapsulated phase change materials (PCM) for use in thermal storage applications to significantly reduce the LCOE for baseload CSP plants. Approach Terrafore is determining a cost-effective way to produce small 10 mm to 15 mm capsules containing phase change material (PCM salt) in a suitable shell material. Large numbers of these PCM capsules provide high-heat transfer surface and store heat as sensible and latent heat of fusion of salt. The capsules with different PCMs inside the shell are stacked inside a single tank to provide a cascaded storage to effectively use the latent heat of fusion of salts over the solar collection temperature range.

410

Process for the preparation of protected dihydroxypropyl trialkylammonium salts and derivatives thereof  

DOE Patents (OSTI)

A process for the preparation of protected dihydroxypropyl trialkylammonium salts, particularly in chiral form is described. In particular, a process for the preparation of (2,2-dimethyl-1,3-dioxolan-4-ylmethyl)trialkylammonium salts, particularly in chiral form is described. Furthermore, a process is described wherein the (2,2-dimethyl-1,3-dioxolan-4ylmethyl)trialkylammonium salts is a 2,2-dimethyl-1,3-dioxolan-4-ylmethyl trimethylammonium salt, preferably in chiral form. The protected dihydroxypropyl trialkylammonium salts lead to L-carnitine (9) when in chiral form (5).

Hollingsworth, Rawle I. (Haslett, MI); Wang, Guijun (East Lansing, MI)

2000-01-01T23:59:59.000Z

411

Salt Lake City, Utah: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

(Redirected from Salt Lake City, UT) (Redirected from Salt Lake City, UT) Jump to: navigation, search Equivalent URI DBpedia Coordinates 40.7607793°, -111.8910474° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":40.7607793,"lon":-111.8910474,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

412

Salt River Electric Coop Corp | Open Energy Information  

Open Energy Info (EERE)

Salt River Electric Coop Corp Salt River Electric Coop Corp Place Kentucky Utility Id 16587 Utility Location Yes Ownership C NERC Location RFC NERC SERC Yes Activity Distribution Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png 100 (Decorative Underground) HPS 48 kWh Outdoor Lighting Lighting 100 Watt HPS 48 kWh Outdoor Lighting Lighting 175 Watt MV 75 kWh Outdoor Lighting Lighting 175 Wattage (Underground) MV 75 kWh (without pole) Lighting 250 Watt HPS 104 kWh Outdoor Lighting Lighting 400 Watt HPS 165 kWh Outdoor Lighting Lighting Cogeneration and small power production power purchase rate schedule less

413

Desalination of salt water by solar energy means  

SciTech Connect

Desalination apparatus using solar energy comprises a main insulated container with a subsidiary preheating container next to it; the main container is covered with a transparent cover serving as a selective filter to provide the greenhouse effect and also as a condensation surface for water vapor, and this transparent cover incorporates a hollow space, for example by making the cover double skinned. The hollow space forms part of a syphon which automatically regulates the water levels, transferring salt water from a preheating container to the main container as the level in the main container falls due to loss by evaporation leading to condensation and withdrawal of the desalinated water. The hollow part of the transparent cover thus serves also to preheat the incoming salt water with the heat lost upon condensation by the vapor within the main container.

La Rocca, A.

1979-01-23T23:59:59.000Z

414

STAINLESS STEEL INTERACTIONS WITH SALT CONTAINING PLUTONIUM OXIDES  

Science Conference Proceedings (OSTI)

Salt containing plutonium oxide materials are treated, packaged and stored within nested, stainless steel containers based on requirements established in the DOE 3013 Standard. The moisture limit for the stored materials is less than 0.5 weight %. Surveillance activities which are conducted to assess the condition of the containers and assure continuing 3013 container integrity include the destructive examination of a select number of containers to determine whether corrosion attack has occurred as a result of stainless steel interactions with salt containing plutonium oxides. To date, some corrosion has been observed on the innermost containers, however, no corrosion has been noted on the outer containers and the integrity of the 3013 container systems is not expected to be compromised over a 50 year storage lifetime.

Nelson, Z.; Chandler, G.; Dunn, K.; Stefek, T.; Summer, M.

2010-02-01T23:59:59.000Z

415

LABORATORY-SCALE DEMONSTRATION OF THE FUSED SALT VOLATILITY PROCESS  

SciTech Connect

The feasibility of processing enriched irradiated zirconium--uranium alloy fuel by the fused salt-fluoride volatility procedure has been demonstrated in laboratory tests with fuel having a burnup of over 10%. Uranium recoveries were greater than 99% and decontamination factors for radioactive fission products were 10/sup 6/ to 10/sup 6/. The UF/sub 6/ product contained significant quantities of nonradioactive impurities; additional work in this area is needed. (auth)

Cathers, G.I.; Jolley, R.L.; Moncrief, E.C.

1962-08-01T23:59:59.000Z

416

Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof  

DOE Green Energy (OSTI)

A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.

Bartlett, Neil (Orinda, CA); Whalen, J. Marc (Corning, NY); Chacon, Lisa (Corning, NY)

2000-12-12T23:59:59.000Z

417

Process Heat Exchanger Options for Fluoride Salt High Temperature Reactor  

Science Conference Proceedings (OSTI)

The work reported herein is a significant intermediate step in reaching the final goal of commercial-scale deployment and usage of molten salt as the heat transport medium for process heat applications. The primary purpose of this study is to aid in the development and selection of the required heat exchanger for power production and process heat application, which would support large-scale deployment.

Piyush Sabharwall; Eung Soo Kim; Michael McKellar; Nolan Anderson

2011-04-01T23:59:59.000Z

418

Sensitivity of storage field performance to geologic and cavern design parameters in salt domes.  

Science Conference Proceedings (OSTI)

A sensitivity study was performed utilizing a three dimensional finite element model to assess allowable cavern field sizes in strategic petroleum reserve salt domes. A potential exists for tensile fracturing and dilatancy damage to salt that can compromise the integrity of a cavern field in situations where high extraction ratios exist. The effects of salt creep rate, depth of salt dome top, dome size, caprock thickness, elastic moduli of caprock and surrounding rock, lateral stress ratio of surrounding rock, cavern size, depth of cavern, and number of caverns are examined numerically. As a result, a correlation table between the parameters and the impact on the performance of a storage field was established. In general, slower salt creep rates, deeper depth of salt dome top, larger elastic moduli of caprock and surrounding rock, and a smaller radius of cavern are better for structural performance of the salt dome.

Ehgartner, Brian L.; Park, Byoung Yoon; Herrick, Courtney Grant

2010-06-01T23:59:59.000Z

419

Sensitivity of storage field performance to geologic and cavern design parameters in salt domes.  

Science Conference Proceedings (OSTI)

A sensitivity study was performed utilizing a three dimensional finite element model to assess allowable cavern field sizes for strategic petroleum reserve salt domes. A potential exists for tensile fracturing and dilatancy damage to salt that can compromise the integrity of a cavern field in situations where high extraction ratios exist. The effects of salt creep rate, depth of salt dome top, dome size, caprock thickness, elastic moduli of caprock and surrounding rock, lateral stress ratio of surrounding rock, cavern size, depth of cavern, and number of caverns are examined numerically. As a result, a correlation table between the parameters and the impact on the performance of storage field was established. In general, slower salt creep rates, deeper depth of salt dome top, larger elastic moduli of caprock and surrounding rock, and a smaller radius of cavern are better for structural performance of the salt dome.

Ehgartner, Brian L. (Sandia National Laboratories, Albuquerque, NM); Park, Byoung Yoon

2009-03-01T23:59:59.000Z

420

Salt Producing Region Natural Gas Working Underground Storage (Billion  

Gasoline and Diesel Fuel Update (EIA)

Salt Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Salt Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Salt Producing Region Natural Gas Working Underground Storage (Billion Cubic Feet) Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 2006-Dec 12/29 101 2007-Jan 01/05 109 01/12 107 01/19 96 01/26 91 2007-Feb 02/02 78 02/09 63 02/16 52 02/23 54 2007-Mar 03/02 59 03/09 58 03/16 64 03/23 70 03/30 78 2007-Apr 04/06 81 04/13 80 04/20 80 04/27 83 2007-May 05/04 85 05/11 88 05/18 92 05/25 97 2007-Jun 06/01 100 06/08 101 06/15 102 06/22 102 06/29 102

Note: This page contains sample records for the topic "baseload nitrate salt" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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421

Molten salt thermal energy storage systems. Project 8981, final report  

DOE Green Energy (OSTI)

The feasibility of storing thermal energy at temperatures of 450/sup 0/ to 535/sup 0/C (850/sup 0/ to 1000/sup 0/F) in the form of latent heat of fusion has been examined for over 30 inorganic salts and salt mixtures. Alkali carbonate mixtures are attractive as phase-change storage materials in this temperature range because of their relatively high storage capacity and thermal conductivity, moderate cost, low volumetric expansion upon melting, low corrosivity, and good chemical stability. An equimolar mixture of Li/sub 2/CO/sub 3/ and K/sub 2/CO/sub 3/, which melts at 505/sup 0/C with a latent heat of 148 Btu/lb, was chosen for experimental study. The cyclic charge/discharge behavior of laboratory- and engineering-scale systems was determined and compared with predictions based on a mathematical heat-transfer model that was developed during this program. The thermal performance of one engineering-scale unit remained very stable during 1400 hours of cyclic operation. Several means of improving heat conduction through the solid salt were explored. Areas requiring further investigation have been identified.

Maru, H.C.; Dullea, J.F.; Kardas, A.; Paul, L.

1978-03-01T23:59:59.000Z

422

Transpiring wall supercritical water oxidation reactor salt deposition studies  

Science Conference Proceedings (OSTI)

Sandia National Laboratories has teamed with Foster Wheeler Development Corp. and GenCorp, Aerojet to develop and evaluate a new supercritical water oxidation reactor design using a transpiring wall liner. In the design, pure water is injected through small pores in the liner wall to form a protective boundary layer that inhibits salt deposition and corrosion, effects that interfere with system performance. The concept was tested at Sandia on a laboratory-scale transpiring wall reactor that is a 1/4 scale model of a prototype plant being designed for the Army to destroy colored smoke and dye at Pine Bluff Arsenal in Arkansas. During the tests, a single-phase pressurized solution of sodium sulfate (Na{sub 2}SO{sub 4}) was heated to supercritical conditions, causing the salt to precipitate out as a fine solid. On-line diagnostics and post-test observation allowed us to characterize reactor performance at different flow and temperature conditions. Tests with and without the protective boundary layer demonstrated that wall transpiration provides significant protection against salt deposition. Confirmation tests were run with one of the dyes that will be processed in the Pine Bluff facility. The experimental techniques, results, and conclusions are discussed.

Haroldsen, B.L.; Mills, B.E.; Ariizumi, D.Y.; Brown, B.G. [and others

1996-09-01T23:59:59.000Z

423

Speciation model selection by Monte Carlo analysis of optical absorption spectra: Plutonium(IV) nitrate complexes  

Science Conference Proceedings (OSTI)

Standard modeling approaches can produce the most likely values of the formation constants of metal-ligand complexes if a particular set of species containing the metal ion is known or assumed to exist in solution equilibrium with complexing ligands. Identifying the most likely set of species when more than one set is plausible is a more difficult problem to address quantitatively. A Monte Carlo method of data analysis is described that measures the relative abilities of different speciation models to fit optical spectra of open-shell actinide ions. The best model(s) can be identified from among a larger group of models initially judged to be plausible. The method is demonstrated by analyzing the absorption spectra of aqueous Pu(IV) titrated with nitrate ion at constant 2 molal ionic strength in aqueous perchloric acid. The best speciation model supported by the data is shown to include three Pu(IV) species with nitrate coordination numbers 0, 1, and 2. Formation constants are {beta}{sub 1}=3.2{+-}0.5 and {beta}{sub 2}=11.2{+-}1.2, where the uncertainties are 95% confidence limits estimated by propagating raw data uncertainties using Monte Carlo methods. Principal component analysis independently indicates three Pu(IV) complexes in equilibrium. (c) 2000 Society for Applied Spectroscopy.

Berg, John M. [Nuclear Materials Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Veirs, D. Kirk [Nuclear Materials Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Vaughn, Randolph B. [Nuclear Materials Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Cisneros, Michael R. [Nuclear Materials Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Smith, Coleman A. [Nuclear Materials Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

2000-06-01T23:59:59.000Z

424

LITERATURE SURVEY FOR GROUNDWATER TREATMENT OPTIONS FOR NITRATE IODINE-129 AND URANIUM 200-ZP-1 OPERABLE UNIT HANFORD SITE  

SciTech Connect

This literature review presents treatment options for nitrate, iodine-129, and uranium, which are present in groundwater at the 200-ZP-I Groundwater Operable Unit (OU) within the 200 West Area of the Hanford Site. The objective of this review is to determine available methods to treat or sequester these contaminants in place (i.e., in situ) or to pump-and-treat the groundwater aboveground (i.e., ex situ). This review has been conducted with emphasis on commercially available or field-tested technologies, but theoretical studies have, in some cases, been considered when no published field data exist. The initial scope of this literature review included only nitrate and iodine-I 29, but it was later expanded to include uranium. The focus of the literature review was weighted toward researching methods for treatment of nitrate and iodine-129 over uranium because of the relatively greater impact of those compounds identified at the 200-ZP-I OU.

BYRNES ME

2008-06-05T23:59:59.000Z

425

Savannah River Site - Salt Waste Processing Facility: Briefing on the Salt Waste Processing Facility Independent Technical Review  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Salt Waste Processing Facility Independent Technical Review Harry Harmon January 9, 2007 2 U.S. Department of Energy Outline * SWPF Process Overview * Major Risks * Approach for Conducting Review * Discussion of Findings * Conclusions 3 U.S. Department of Energy Salt Waste Processing Facility 4 U.S. Department of Energy SWPF Process Overview Alpha Finishing Process CSSX Alpha Strike Process MST/ Sludge Cs Strip Effluent DSS 5 U.S. Department of Energy BOTTOM LINE The SWPF Project is ready to move into final design. 6 U.S. Department of Energy Major Risks * Final geotechnical data potentially could result in redesign of the PC-3 CPA base mat and structure. * Cost and schedule impacts arising from the change from ISO-9001 to NQA-1 quality assurance requirements. * The "de-inventory, flush, and then hands-on

426

Diffusion Welding of Alloys for Molten Salt Service - Status Report  

SciTech Connect

The present work is concerned with heat exchanger development for molten salt service, including the proposed molten salt reactor (MSR), a homogeneous reactor in which the fuel is dissolved in a circulating fluid of molten salt. It is an outgrowth of recent work done under the Next Generation Nuclear Plant (NGNP) program; what the two reactor systems have in common is an inherently safe nuclear plant with a high outlet temperature that is useful for process heat as well as more conventional generation The NGNP program was tasked with investigating the application of a new generation of nuclear power plants to a variety of energy needs. One baseline reactor design for this program is a high temperature, gas-cooled reactor (HTGR), which provides many options for energy use. These might include the conventional Rankine cycle (steam turbine) generation of electricity, but also other methods: for example, Brayton cycle (gas turbine) electrical generation, and the direct use of the high temperatures characteristic of HTGR output for process heat in the chemical industry. Such process heat is currently generated by burning fossil fuels, and is a major contributor to the carbon footprint of the chemical and petrochemical industries. The HTGR, based on graphite fuel elements, can produce very high output temperatures; ideally, temperatures of 900 C or even greater, which has significant energy advantages. Such temperatures are, of course, at the frontiers of materials limitations, at the upper end of the performance envelope of the metallic materials for which robust construction codes exist, and within the realm of ceramic materials, the fabrication and joining of which, on the scale of large energy systems, are at an earlier stage of development. A considerable amount of work was done in the diffusion welding of materials of interest for HTGR service with alloys such as 617 and 800H. The MSR output temperature is also materials limited, and is projected at about 700 C. (RR E) A different set of alloys, such as Alloy N and 242, are needed to handle molten salts at this temperature. The diffusion welding development work described here builds on techniques developed during the NGNP work, as applied to these alloys. There is also the matter of dissimilar metal welding, since alloys suitable for salt service are generally not suited for service in gaseous oxidizing environments, and vice versa, and welding is required for the Class I boundaries in these systems, as identified in the relevant ASME codes.

Denis Clark; Ronald Mizia

2012-05-01T23:59:59.000Z

427

Diffusion Welding of Alloys for Molten Salt Service - Status Report  

Science Conference Proceedings (OSTI)

The present work is concerned with heat exchanger development for molten salt service, including the proposed molten salt reactor (MSR), a homogeneous reactor in which the fuel is dissolved in a circulating fluid of molten salt. It is an outgrowth of recent work done under the Next Generation Nuclear Plant (NGNP) program; what the two reactor systems have in common is an inherently safe nuclear plant with a high outlet temperature that is useful for process heat as well as more conventional generation The NGNP program was tasked with investigating the application of a new generation of nuclear power plants to a variety of energy needs. One baseline reactor design for this program is a high temperature, gas-cooled reactor (HTGR), which provides many options for energy use. These might include the conventional Rankine cycle (steam turbine) generation of electricity, but also other methods: for example, Brayton cycle (gas turbine) electrical generation, and the direct use of the high temperatures characteristic of HTGR output for process heat in the chemical industry. Such process heat is currently generated by burning fossil fuels, and is a major contributor to the carbon footprint of the chemical and petrochemical industries. The HTGR, based on graphite fuel elements, can produce very high output temperatures; ideally, temperatures of 900 °C or even greater, which has significant energy advantages. Such temperatures are, of course, at the frontiers of materials limitations, at the upper end of the performance envelope of the metallic materials for which robust construction codes exist, and within the realm of ceramic materials, the fabrication and joining of which, on the scale of large energy systems, are at an earlier stage of development. A considerable amount of work was done in the diffusion welding of materials of interest for HTGR service with alloys such as 617 and 800H. The MSR output temperature is also materials limited, and is projected at about 700 °C. (RR E) A different set of alloys, such as Alloy N and 242, are needed to handle molten salts at this temperature. The diffusion welding development work described here builds on techniques developed during the NGNP work, as applied to these alloys. There is also the matter of dissimilar metal welding, since alloys suitable for salt service are generally not suited for service in gaseous oxidizing environments, and vice versa, and welding is required for the Class I boundaries in these systems, as identified in the relevant ASME codes.

Denis Clark; Ronald Mizia; Piyush Sabharwall

2012-09-01T23:59:59.000Z

428

Functional Conceptual Design Criteria - 5-MW/sub e/ salt-gradient solar pond power plant at Great Salt Lake  

DOE Green Energy (OSTI)

The purpose of this solar pond plant facility would be to provide valid data on the cost, operation, and reliability of salt-gradient solar ponds as a means of producing power. A general facility description is given which includes design code requirements, site selection, site characteristics, and site-specific design requirements. Functional requirements discussed include: civil-structural; mechanical; electrical; and control, instrumentation and alarms. Occupational and environmental safety, security, and quality assurance are also discussed.

Brown, L.M.; Barnhart, J.S.; Cavola, R.G.; Drost, M.K.; Hauser, S.G.; Johnson, B.M.

1983-08-01T23:59:59.000Z

429

A literature review of radiolytic gas generation as a result of the decomposition of sodium nitrate wastes  

DOE Green Energy (OSTI)

The objective of this literature review is to determine expected chemical reactions and the gas generation associated with radiolytic decomposition of radioactive sodium nitrate wastes such as the wastes stored in the Melton Valley Storage Tanks (MVST) at Oak Ridge National Laboratory (ORNL). The literature survey summarizes expected chemical reactions and identifies the gases expected to be generated as a result of the radiolytic decomposition. The literature survey also identifies G values, which are the expression for radiation chemical yields as molecules of gas formed per 100 eV of absorbed energy, obtained from experimental studies of the radiolytic decomposition of water and sodium nitrate. 2 tabs., 32 refs.

Kasten, J.L.

1991-01-01T23:59:59.000Z

430

Application of the risk-based strategy to the Hanford tank waste organic-nitrate safety issue  

Science Conference Proceedings (OSTI)

This report describes the results from application of the Risk-Based Decision Management Approach for Justifying Characterization of Hanford Tank Waste to the organic-nitrate safety issue in Hanford single-shell tanks (SSTs). Existing chemical and physical models were used, taking advantage of the most current (mid-1997) sampling and analysis data. The purpose of this study is to make specific recommendations for planning characterization to help ensure the safety of each SST as it relates to the organic-nitrate safety issue. An additional objective is to demonstrate the viability of the Risk-Based Strategy for addressing Hanford tank waste safety issues.

Hunter, V.L.; Colson, S.D.; Ferryman, T.; Gephart, R.E.; Heasler, P.; Scheele, R.D.

1997-12-01T23:59:59.000Z

431

Radioactive waste isolation in salt: geochemistry of brine in rock salt in temperature gradients and gamma-radiation fields - a selective annotated bibliography  

SciTech Connect

Evaluation of the extensive research concerning brine geochemistry and transport is critically important to successful exploitation of a salt formation for isolating high-level radioactive waste. This annotated bibliography has been compiled from documents considered to provide classic background material on the interactions between brine and rock salt, as well as the most important results from more recent research. Each summary elucidates the information or data most pertinent to situations encountered in siting, constructing, and operating a mined repository in salt for high-level radioactive waste. The research topics covered include the basic geology, depositional environment, mineralogy, and structure of evaporite and domal salts, as well as fluid inclusions, brine chemistry, thermal and gamma-radiation effects, radionuclide migration, and thermodynamic properties of salts and brines. 4 figs., 6 tabs.

Hull, A.B.; Williams, L.B.

1985-07-01T23:59:59.000Z

432

Origin of fluid inclusion water in bedded salt deposits, Palo Duro Basin, Texas  

DOE Green Energy (OSTI)

Salt horizons in the Palo Duro Basin being considered for repository sites contain fluid inclusions which may represent connate water retained in the salt from the time of original salt deposition and/or external waters which have somehow penetrated the salt. The exact origin of this water is important to the question of whether or not internal portions of the salt deposit have been, and are likely to be, isolated from the hydrosphere for long periods of time. The /sup 18/O//sup 16/O and D/H ratios measured for water extracted from solid salt samples show the inclusions to be dissimilar in isotopic composition to meteoric waters and to formation waters above and below the salt. The fluid inclusions cannot be purely external waters which have migrated into the salt. The isotope data are readily explained in terms of mixed meteoric-marine connate evaporite waters which date back to the time of deposition and early diagenesis of the salt (>250 million years). Any later penetration of the salt by meteoric waters has been insufficient to flush out the connate brines.

Knauth, L.P.; Beeunas, M.A.

1985-07-01T23:59:59.000Z

433

Salt effects on isotope partitioning and their geochemical implications: An overview  

DOE Green Energy (OSTI)

Essential to the use of stable isotopes as natural tracers and geothermometers is the knowledge of equilibrium isotope partitioning between different phases and species, which is usually a function of temperature only. The one exception known to date is oxygen and hydrogen isotope fractionation between liquid water and other phases (steam, gases, minerals), which changes upon the addition of salts to water, i.e., the isotope salt salt effect. Our knowledge of this effect, the difference between activity and composition (a-X) of isotopic water molecules in salt solutions, is very limited and controversial, especially at elevated temperatures. For the last several years, we have been conducting a detailed, systematic experimental study at Oak Ridge National Laboratory to determine the isotope salt effects from room temperature to elevated temperatures (currently to 500{degree}C). From this effort, a simple, coherent picture of the isotope salt effect is emerging, that differs markedly from the complex results reported in the literature. In this communication, we present an overview on the isotope salt effect, obtained chiefly from our study. Observed isotope salt effects in salt solutions are significant even at elevated temperatures. The importance and implications of the isotope salt effect for isotopic studies of brine-dominated systems are also discussed in general terms.