National Library of Energy BETA

Sample records for barrier coatings cxs

  1. Catalytic thermal barrier coatings

    DOE Patents [OSTI]

    Kulkarni, Anand A. (Orlando, FL); Campbell, Christian X. (Orlando, FL); Subramanian, Ramesh (Oviedo, FL)

    2009-06-02

    A catalyst element (30) for high temperature applications such as a gas turbine engine. The catalyst element includes a metal substrate such as a tube (32) having a layer of ceramic thermal barrier coating material (34) disposed on the substrate for thermally insulating the metal substrate from a high temperature fuel/air mixture. The ceramic thermal barrier coating material is formed of a crystal structure populated with base elements but with selected sites of the crystal structure being populated by substitute ions selected to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a higher rate than would the base compound without the ionic substitutions. Precious metal crystallites may be disposed within the crystal structure to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a lower light-off temperature than would the ceramic thermal barrier coating material without the precious metal crystallites.

  2. Thermal barrier coating

    DOE Patents [OSTI]

    Bowker, Jeffrey Charles (Gibsonia, PA); Sabol, Stephen M. (Orlando, FL); Goedjen, John G. (Oviedo, FL)

    2001-01-01

    A thermal barrier coating for hot gas path components of a combustion turbine based on a zirconia-scandia system. A layer of zirconium scandate having the hexagonal Zr.sub.3 Sc.sub.4 O.sub.12 structure is formed directly on a superalloy substrate or on a bond coat formed on the substrate.

  3. Multilayer thermal barrier coating systems

    DOE Patents [OSTI]

    Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

    2000-01-01

    The present invention generally describes multilayer thermal barrier coating systems and methods of making the multilayer thermal barrier coating systems. The thermal barrier coating systems comprise a first ceramic layer, a second ceramic layer, a thermally grown oxide layer, a metallic bond coating layer and a substrate. The thermal barrier coating systems have improved high temperature thermal and chemical stability for use in gas turbine applications.

  4. Thermal barrier coatings

    DOE Patents [OSTI]

    Alvin, Mary Anne (Pittsburg, PA)

    2010-06-22

    This disclosure addresses the issue of providing a metallic-ceramic overlay coating that potentially serves as an interface or bond coat layer to provide enhanced oxidation resistance to the underlying superalloy substrate via the formation of a diffusion barrier regime within the supporting base material. Furthermore, the metallic-ceramic coating is expected to limit the growth of a continuous thermally grown oxide (TGO) layer that has been primarily considered to be the principal cause for failure of existing TBC systems. Compositional compatibility of the metallic-ceramic with traditional yttria-stabilized zirconia (YSZ) top coats is provided to further limit debond or spallation of the coating during operational use. A metallic-ceramic architecture is disclosed wherein enhanced oxidation resistance is imparted to the surface of nickel-based superalloy or single crystal metal substrate, with simultaneous integration of the yttria stabilized zirconia (YSZ) within the metallic-ceramic overlayer.

  5. Low Conductivity Thermal Barrier Coatings

    E-Print Network [OSTI]

    Wadley, Haydn

    Low Conductivity Thermal Barrier Coatings A Dissertation Presented to The Faculty of the School ________________________________________________________________________ Abstract The dissertation begins by exploring the growth of 7YSZ coatings on vapor deposited NiCoCrAlY bond coats at different substrate rotation rates. The experiments show that as the rotation rate

  6. Discrete Element Modeling of Impact Damage on Thermal Barrier Coatings

    E-Print Network [OSTI]

    Minor, Peter Michel

    2013-01-01

    Thermal barrier coating morphology produced by air plasmacompared to other potential thermal barrier coating2 Thermal Barrier Coatings 2.1 System of

  7. Reaction, transformation and delamination of samarium zirconate thermal barrier coatings

    E-Print Network [OSTI]

    Wadley, Haydn

    Reaction, transformation and delamination of samarium zirconate thermal barrier coatings Hengbei zirconates have attracted interest for thermal barrier coatings (TBCs) because they have very low intrinsic. Here, columnar morphology SZO coatings have been deposited on bond coated superalloy substrates using

  8. Embedded Optical Sensors for Thermal Barrier Coatings

    SciTech Connect (OSTI)

    David R. Clarke

    2006-07-31

    The third year of this program on developing embedded optical sensors for thermal barrier coatings has been devoted to two principal topics: (i) continuing the assessment of the long-term, thermal cycle stability of the Eu{sup 3+} doped 8YSZ temperature sensor coatings, and (ii) improving the fiber-optic based luminescence detector system. Following the earlier, preliminary findings, it has been found that not only is the luminescence from the sensors not affected by prolonged thermal cycling, even after 195 hours at 1425 C, but the variation in luminescence lifetime with temperature remains unchanged. As the temperature of 1425 C is much higher than present engines attain or even planned in the foreseeable future, our findings indicate that the Eu{sup 3+} doped thermal barrier coating sensors are very robust and have the potential of being stable throughout the life of coatings. Investigation of Eu{sup 3+} doped coatings prepared by plasma-spraying exhibited the same luminescence characteristics as those prepared by electron-beam evaporation. This is of major significance since thermal barrier coatings can be prepared by both process technologies. A fiber-optic based luminescence system has been constructed in which the hottest section of fiber operates to at least 1250 C.

  9. Modelling the microstructure of thermal barrier coatings

    SciTech Connect (OSTI)

    Cirolini, S.; Marchese, M.; Jacucci, G.; Harding, J.H.; Mulheran, P.A.

    1994-12-31

    Thermal barrier coatings produced by plasma spraying have a characteristic microstructure of lamellae, pores and cracks. The lamellae are produced by the splashing of particles onto the substrate. As the coating grows, the lamellae pile on top of each other, producing an interlocking structure. In most cases the growth is rapid and chaotic. The result is a microstructure characterized by pores and cracks. The authors present an improved model for the deposition process of thermal barrier coatings. The task of modeling the coating growth is split into two parts: first the authors consider a description of the particle on arrival at the film, based on the available theoretical, numerical and experimental findings. Second they define and discuss a set of physically-based rules for combining these events to obtain the film. The splats run along the surface and are permitted to curl up (producing pores) or interlock. The computer model uses a mesh to combine these processes and build the coating. They discuss the use of the proposed model in predicting microstructures and hence in correlating the properties of these coatings with the parameters of the process used to make them.

  10. Molten silicate interactions with thermal barrier coatings Hengbei Zhao a,

    E-Print Network [OSTI]

    Wadley, Haydn

    Molten silicate interactions with thermal barrier coatings Hengbei Zhao a, , Carlos G. Levi b form 2 April 2014 Available online 12 April 2014 Keywords: Thermal barrier coatings Rare earth zirconate CMAS reaction The strain tolerance of thermal barrier coatings (TBCs) used in gas turbine engines

  11. Model Studies of Pore Stability and Evolution in Thermal Barrier Coatings (TBCs)

    E-Print Network [OSTI]

    Glaeser, A M

    2008-01-01

    durable thermal barrier coatings with novel microstructuresEB-PVD TBCs,” Surface & Coatings Technology, 151, 383-391 (in Thermal Barrier Coatings (TBCs) A. M. Glaeser M. Kitayama

  12. EMBEDDED OPTICAL SENSORS FOR THERMAL BARRIER COATINGS

    SciTech Connect (OSTI)

    David R. Clarke

    2004-12-16

    In this first year of the program we have focused on the selection of rare-earth dopants for luminescent sensing in thermal barrier coating materials, the effect of dopant concentration on several of the luminescence characteristics and initial fabrication of one type of embedded sensor, the ''red-line'' sensor. We have initially focused on erbium as the lanthanide dopant for luminescence doping of yttria-stabilized zirconia and europium as the lanthanide for luminescence doping of gadolinium zirconate. The latter exhibits a temperature-dependent luminescence lifetime up to at least 1100 C. A buried layer, ''red-line'' sensor in an electron-beam deposited yttria-stabilized zirconia coating with erbium has been demonstrated and exhibits a temperature-dependent luminescence lifetime up to at least 400 C.

  13. Delamination of multilayer thermal barrier coatings Sung Ryul Choi a

    E-Print Network [OSTI]

    Hutchinson, John W.

    Delamination of multilayer thermal barrier coatings Sung Ryul Choi a , John W. Hutchinson b,*, A coatings (TBCs) on superalloy substrates are comprised of an intermetallic bond coat, a thermally grown oxide (TGO) layer, and a porous zirconia top coat that provides thermal protection. The TGO attains

  14. Ion beam assisted deposition of thermal barrier coatings

    DOE Patents [OSTI]

    Youchison, Dennis L. (Albuquerque, NM); McDonald, Jimmie M. (Albuquerque, NM); Lutz, Thomas J. (Albuquerque, NM); Gallis, Michail A. (Albuquerque, NM)

    2010-11-23

    Methods and apparatus for depositing thermal barrier coatings on gas turbine blades and vanes using Electron Beam Physical Vapor Deposition (EBPVD) combined with Ion Beam Assisted Deposition (IBAD).

  15. Vapor deposited samarium zirconate thermal barrier coatings Hengbei Zhao a,

    E-Print Network [OSTI]

    Wadley, Haydn

    by Elsevier B.V. 1. Introduction Thermal barrier coating (TBC) systems have become an enabling materials technology for the gas turbine engines used for propulsion and power generation [1]. Through their abilityVapor deposited samarium zirconate thermal barrier coatings Hengbei Zhao a, , Carlos G. Levi b

  16. Thermal barrier coating resistant to sintering

    DOE Patents [OSTI]

    Subramanian, Ramesh; Seth, Brig B.

    2005-08-23

    A device (10) is made, having a ceramic thermal barrier coating layer (16) characterized by a microstructure having gaps (18) with a sintering inhibiting material (22) disposed on the columns (20) within the gaps (18). The sintering resistant material (22) is stable over the range of operating temperatures of the device (10), is not soluble with the underlying ceramic layer (16) and is applied by a process that is not an electron beam physical vapor deposition process. The sintering inhibiting material (22) has a morphology adapted to improve the functionality of the sintering inhibiting material (22), characterized as continuous, nodule, rivulet, grain, crack, flake and combinations thereof and being disposed within at least some of the vertical and horizontal gaps.

  17. Permeation Barrier Coatings for the Helical Heat Exchanger

    SciTech Connect (OSTI)

    Korinko, P.S.

    1999-05-26

    A permeation barrier coating was specified for the Helical Heat Exchanger (HHE) to minimize contamination through emissions and/or permeation into the nitrogen system for ALARA reasons. Due to the geometry of the HHE, a special coating practice was needed since the conventional method of high temperature pack aluminization was intractable. A survey of many coating companies was undertaken; their coating capabilities and technologies were assessed and compared to WSRC needs. The processes and limitations to coating the HHE are described. Slurry coating appears to be the most technically sound approach for coating the HHE.

  18. Embedded Optical Sensors for Thermal Barrier Coatings

    SciTech Connect (OSTI)

    David R. Clarke

    2005-11-09

    In the second year of this program on developing embedded optical sensors for thermal barrier coatings, our research has focused three topics: (1) Eu{sup 3+} doping for temperature sensing, (2) the effect of long-term, high-temperature aging on the characteristics of the luminescence from the Eu{sup 3+} ions of 8YSZ materials, (3) construction of a fiber-optic based luminescence detector system. It has been demonstrated that the variation in luminescence lifetime with temperature is identical for electron-beam evaporated Eu-doped YSZ coatings as for bulk ceramics of the same composition. Experiments indicate that the luminescence lifetime method of measuring temperatures is sensitive up to 1150 C for both Eu-doped YSZ coatings and Eu-doped Gd{sub 2}Zr{sub 2}O{sub 7}. Furthermore, the technique is sensitive up to 1250 C for the composition Eu{sub 2}Zr{sub 2}O{sub 7}. The luminescence spectra Eu-doped YSZ are insensitive to long-term aging at high-temperatures, even to 195 hours at 1425 C, except for a small frequency shift that is probably too small in measure except with instruments of the highest spectral resolution. The temperature of 1425 C is much higher than present engines attain or even planned in the foreseeable future. Nevertheless, experiments are on-going to explore longer term exposures. A fiber-optic based luminescence system has been constructed in which the hottest section of fiber operates to at least 1250 C.

  19. Plasma sprayed and electrospark deposited zirconium metal diffusion barrier coatings

    SciTech Connect (OSTI)

    Hollis, Kendall J; Pena, Maria I

    2010-01-01

    Zirconium metal coatings applied by plasma spraying and electrospark deposition (ESD) have been investigated for use as diffusion barrier coatings on low enrichment uranium fuel for research nuclear reactors. The coatings have been applied to both stainless steel as a surrogate and to simulated nuclear fuel uranium-molybdenum alloy substrates. Deposition parameter development accompanied by coating characterization has been performed. The structure of the plasma sprayed coating was shown to vary with transferred arc current during deposition. The structure of ESD coatings was shown to vary with the capacitance of the deposition equipment.

  20. Delamination resistance of thermal barrier coatings containing embedded ductile layers

    E-Print Network [OSTI]

    Wadley, Haydn

    of oxidation and hot corrosion of inter- nally cooled superalloy structures in gas turbine engines [1­ 4Delamination resistance of thermal barrier coatings containing embedded ductile layers Matthew R 93106, USA b Materials Science and Engineering, University of Virginia, Charlottesville, VA 22903, USA

  1. Environmental Barrier Coatings for the Energy Efficient Heat Engines Program

    SciTech Connect (OSTI)

    Katherine Faber

    2004-10-31

    This program aimed to develop a fundamental understanding of the microstructural, mechanical, and chemical properties of Ta{sub 2}O{sub 5}-based coatings for Si{sub 3}N{sub 4} (AS800) substrates and optimize such coatings for environmental barriers. The program consisted of three tasks: processing of Ta{sub 2}O{sub 5} coatings, phase and microstructural development, and life-limiting phenomena. Northwestern University formed a cross-functional team with Lehigh University, Honeywell Inc., and Oak Ridge National Laboratory. The major accomplishments are: (1) Conditions for the plasma spray of Ta{sub 2}O{sub 5} and its alloys were optimized to provide maximum density and thickness. (2) Adherent small particle plasma spray coatings of Ta{sub 2}O{sub 5} can be routinely prepared. (3) Ta{sub 2}O{sub 5} can be stabilized against its disruptive phase transformation to 1400 C by the addition of one or more oxides of Al, La, and/or Nb. (4) Residual stresses in the Ta{sub 2}O{sub 5} coatings were measured using X-rays and changed with thermal exposure. (5) Properly doped coatings are more resistant against thermal cycling than undoped coatings, and can be cycled many thousand times without spallation. (6) Water vapor testing in the ORNL Keiser Rig of adherent coatings showed that undoped Ta{sub 2}O{sub 5} is not an effective barrier at preventing chemical changes to the AS800. (7) Limited water vapor testing of doped and adherent coatings, which had successfully survived many thermal cycles, showed that in the water vapor environment, de-cohesion may occur.

  2. SPALLING FAILURE OF A THERMAL BARRIER COATING ASSOCIATED WITH ALUMINUM DEPLETION

    E-Print Network [OSTI]

    Clarke, David R.

    SPALLING FAILURE OF A THERMAL BARRIER COATING ASSOCIATED WITH ALUMINUM DEPLETION IN THE BOND-COAT EÐA plasma-sprayed thermal barrier coating is observed to spall after oxidation at 11218C from a CoNiCrAlY bond-coated superalloy at the interface between the thermally grown oxide (TGO) and the zir- conia

  3. Interface Science of Thermal Barrier Coatings

    SciTech Connect (OSTI)

    Besmann, Theodore M

    2009-01-01

    The drive for greater efficiency in propulsion and industrial/power production machinery has pushed metallurgy to develop ever better alloys and taken existing metallic components to their reliability threshold. Nowhere is that better illustrated than in turbine engine materials. The nickel-based superalloys currently in use for the most demanding areas of the engines melt at 1230-1315 aC and yet see combustion environments >1600 aC. The result is that these components require thermal protection to avoid failure from phenomena such as melting, creep, oxidation, thermal fatigue, and so on [1]. The stakes are high as the equipment must remain reliable for thousands of take-offs and landings for aircraft turbine engines, and up to 40,000 hours of operation in power generating land-based gas turbines [2, 3]. One of the most critical items that see both the greatest temperatures and experience the highest stresses is the hot-section turbine blades. Two strategies have been adopted to help the superalloy turbine blades survive the demanding environment: Active air cooling and ceramic thermal protection coatings, which together can reduce metal surface temperatures by >300 aC.[2]. The combination of turbine blade external film cooling and internal air cooling requires an exceptionally complex structure with flow passages and sets of small holes in the blades where air bled from a matching stage of the compressor is directed over the surface. Stecura [4] was among the first to describe a successful coating system, and today s the ceramic insulating layer alone is credited with reducing metal temperatures as much as 165 aC [1, 5].

  4. New Barrier Coating Materials for PV Module Backsheets: Preprint

    SciTech Connect (OSTI)

    Barber, G. D.; Jorgensen, G. J.; Terwilliger, K.; Glick, S. H.; Pern, J.; McMahon, T. J.

    2002-05-01

    This conference paper describes the high moisture barrier high resistivity coatings on polyethylene terepthalate (PET) have been fabricated and characterized for use in PV module back sheet applications. These thin film barriers exhibit water vapor transmission rates (WVTR) as low as 0.1 g/m2-day at 37.8 C and have shown excellent adhesion (> 10 N/mm) to both ethylene vinyl acetate (EVA) and PET even after filtered xenon arc lamp UV exposure. The WVTR and adhesion values for this construction are compared to and shown to be superior to candidate polymeric backsheet materials.

  5. Bond Coating Performance of Thermal Barrier Coatings for Industrial Gas Turbines

    SciTech Connect (OSTI)

    Wright, Ian G; Pint, Bruce A

    2005-01-01

    Thermal barrier coatings are intended to work in conjunction with internal cooling schemes to reduce the metal temperature of critical hot gas path components in gas turbine engines. The thermal resistance is typically provided by a 100--250 {mu}m thick layer of ceramic (most usually zirconia stabilized with an addition of 7--8 wt% of yttria), and this is deposited on to an approximately 50 {mu} thick, metallic bond coating that is intended to anchor the ceramic to the metallic surface, to provide some degree of mechanical compliance, and to act as a reservoir of protective scale-forming elements (Al) to protect the underlying superalloy from high-temperature corrosion. A feature of importance to the durability of thermal barrier coatings is the early establishment of a continuous, protective oxide layer (preferably {alpha}-alumina) at the bond coating-ceramic interface. Because zirconia is permeable to oxygen, this oxide layer continues to grow during service. Some superalloys are inherently resistant to high-temperature oxidation, so a separate bond coating may not be needed in those cases. Thermal barrier coatings have been in service in aeroengines for a number of years, and the use of this technology for increasing the durability and/or efficiency of industrial gas turbines is currently of significant interest. The data presented were taken from an investigation of routes to optimize bond coating performance, and the focus of the paper is on the influences of reactive elements and Pt on the oxidation behaviour of NiAl-based alloys determined in studies using cast versions of bond coating compositions.

  6. Lifetime Assessment for Thermal Barrier Coatings: Tests for Measuring Mixed Mode Delamination Toughness

    E-Print Network [OSTI]

    Hutchinson, John W.

    Lifetime Assessment for Thermal Barrier Coatings: Tests for Measuring Mixed Mode Delamination Mechanisms leading to degradation of the adherence of thermal barrier coatings (TBC) used in aircraft of coatings have not emerged based on predictions of the degradation processes due to their complexity

  7. Mechanics-based scaling laws for the durability of thermal barrier coatings

    E-Print Network [OSTI]

    Hutchinson, John W.

    Mechanics-based scaling laws for the durability of thermal barrier coatings A.G. Evans a, *, M.................................................................258 2.3. Role of TGO creep in redistributing stress in bond coat and TBC ..........260 * Corresponding author. E-mail address: anevans@princeton.edu (A.G. Evans). #12;1. Introduction Thermal barrier coatings

  8. Nondestructive evaluation of the oxidation stresses through thermal barrier coatings using Cr3

    E-Print Network [OSTI]

    Clarke, David R.

    Nondestructive evaluation of the oxidation stresses through thermal barrier coatings using Cr3 The stresses in the aluminum oxide formed during high-temperature oxidation of a bond-coated superalloy are shown to be measurable through zirconia thermal barrier coatings. The basis for the measurements

  9. Vacuum 59 (2000) 185}193 Development of composite thermal barrier coatings with

    E-Print Network [OSTI]

    Ghoniem, Nasr M.

    2000-01-01

    barrier composite coating was produced using a gas-tunnel-type plasma spraying torch. To enhance) in high-temperature turbine blade applications has led to the recognition that TBC-coated superalloys oVacuum 59 (2000) 185}193 Development of composite thermal barrier coatings with anisotropic

  10. Vacuum 65 (2002) 415425 Plasma spraying of micro-composite thermal barrier coatings

    E-Print Network [OSTI]

    Ghoniem, Nasr M.

    2002-01-01

    blades and vanes of gas turbine engines, turbine shrouds and combus- tor cans. These coatings increase. Keywords: Plasma spraying; Gas tunnel-type; Thermal barrier-composite coatings; Aluminum oxide; ZirconiumVacuum 65 (2002) 415­425 Plasma spraying of micro-composite thermal barrier coatings S. Sharafata

  11. Title: Improving Jet Engine Turbine Thermal Barrier Coatings via Reactive Element Addition to the Bond Coat Alloy

    E-Print Network [OSTI]

    Carter, Emily A.

    Title: Improving Jet Engine Turbine Thermal Barrier Coatings via Reactive Element Addition engine turbine blades can shield the temperature to which the underlying superalloy is exposed modifications that should inhibit the failure of these jet engine turbine thermal barrier coatings. Research

  12. Highly defective oxides as sinter resistant thermal barrier coating

    DOE Patents [OSTI]

    Subramanian, Ramesh

    2005-08-16

    A thermal barrier coating material formed of a highly defective cubic matrix structure having a concentration of a stabilizer sufficiently high that the oxygen vacancies created by the stabilizer interact within the matrix to form multi-vacancies, thereby improving the sintering resistance of the material. The concentration of stabilizer within the cubic matrix structure is greater than that concentration of stabilizer necessary to give the matrix a peak ionic conductivity value. The concentration of stabilizer may be at least 30 wt. %. Embodiments include a cubic matrix of zirconia stabilized by at least 30-50 wt. % yttria, and a cubic matrix of hafnia stabilized by at least 30-50 wt. % gadolinia.

  13. The influence of coating compliance on the delamination of thermal barrier coatings Hengbei Zhao , Zhuo Yu, Haydn N.G. Wadley

    E-Print Network [OSTI]

    Wadley, Haydn

    The influence of coating compliance on the delamination of thermal barrier coatings Hengbei Zhao zirconia coatings Thermal oxidation kinetics Delamination buckling Low relative density yttria stabilized zirconia (YSZ) thermal barrier coatings have been deposited on NiCoCrAlY over-lay bond-coated Hastelloy

  14. Tunable staged release of therapeutics from layer-by-layer coatings with clay interlayer barrier

    E-Print Network [OSTI]

    Tunable staged release of therapeutics from layer-by-layer coatings with clay interlayer barrier of coatings for medical devices and tissue engineering scaffolds, there is a need for thin coatings a self-assembled, polymer-based conformal coating, built by using a water-based layer-by-layer (Lb

  15. Determination of Elastic Properties and Characterization of Thermal Barrier Coatings using Resonant Ultrasound Spectroscopy

    SciTech Connect (OSTI)

    Shyam, Amit; Lara-Curzio, Edgar

    2009-01-01

    Mechanical properties of plasma sprayed ceramic coatings are extremely important to engine design. However, the determination of these properties is often difficult because of the unique and complicated microstructure of the coatings. In this presentation the determination of the elastic constants of plasma sprayed Yttria stabilized Zirconia thermal barrier coatings using resonant ultrasound spectroscopy will be described along with an analysis that enables the determination of the elastic constants as a function of temperature and coating direction. In this work, results on the following issues will be discussed: 1) the elastic anisotropy of thermal barrier coatings, which is associated with coating failure modes; 2) sintering effects on coating compliance comparing with thermal behavior, which is important to coating performance on engineering structures, such as turbine engines; 3) coating elastic modulus at high temperatures close to the service condition, which provides insights of coating mechanical behavior in both fundamental and practical studies.

  16. Europium-doped Pyrochlores for Use as Thermographic Phosphors in Thermal Barrier Coatings

    E-Print Network [OSTI]

    Walker, D. Greg

    for thermal barrier coatings must be developed to provide insulation for gas turbines operating above 1200° C and effects of heat fatigue · Insulation for components in gas turbines allows for higher operating thermal barrier coating material · YSZ can not be used reliably for temperatures > 1200° C · New materials

  17. Experiments and modeling of multilayered coatings and membranes : application to thermal barrier coatings and reverse osmosis membranes

    E-Print Network [OSTI]

    Luk-Cyr, Jacques

    2014-01-01

    In this thesis, I developed a novel methodology for characterizing interfacial delamination of thermal barrier coatings. The proposed methodology involves novel experiments-plus numerical simulations in order to determine ...

  18. Thermal barrier coatings: Coating methods, performance, and heat engine applications. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    1997-02-01

    The bibliography contains citations concerning conference proceedings on coating methods, performance evaluations, and applications of thermal barrier coatings as protective coatings for heat engine components against high temperature corrosions and chemical erosions. The developments of thermal barrier coating techniques for high performance and reliable gas turbines, diesel engines, jet engines, and internal combustion engines are presented. Topics include plasma sprayed coating methods, yttria stabilized zirconia coatings, coating life models, coating failure and durability, thermal shock and cycling, and acoustic emission analysis of coatings. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  19. Thermal barrier coatings: Coating methods, performance, and heat engine applications. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    The bibliography contains citations concerning conference proceedings on coating methods, performance evaluations, and applications of thermal barrier coatings as protective coatings for heat engine components against high temperature corrosions and chemical erosions. The developments of thermal barrier coating techniques for high performance and reliable gas turbines, diesel engines, jet engines, and internal combustion engines are presented. Topics include plasma sprayed coating methods, yttria stabilized zirconia coatings, coating life models, coating failure and durability, thermal shock and cycling, and acoustic emission analysis of coatings. (Contains a minimum of 243 citations and includes a subject term index and title list.)

  20. Thermal barrier coatings: Coating methods, performance, and heat engine applications. (Latest citations from the EI compendex*plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The bibliography contains citations concerning conference proceedings on coating methods, performance evaluations, and applications of thermal barrier coatings as protective coatings for heat engine components against high temperature corrosions and chemical erosions. The developments of thermal barrier coating techniques for high performance and reliable gas turbines, diesel engines, jet engines, and internal combustion engines are presented. Topics include plasma sprayed coating methods, yttria stabilized zirconia coatings, coating life models, coating failure and durability, thermal shock and cycling, and acoustic emission analysis of coatings. (Contains 250 citations and includes a subject term index and title list.)

  1. Thermal barrier coatings: Coating methods, performance, and heat engine applications. (Latest citations from the EI Compendex*plus database). Published Search

    SciTech Connect (OSTI)

    1995-11-01

    The bibliography contains citations concerning conference proceedings on coating methods, performance evaluations, and applications of thermal barrier coatings as protective coatings for heat engine components against high temperature corrosions and chemical erosions. The developments of thermal barrier coating techniques for high performance and reliable gas turbines, diesel engines, jet engines, and internal combustion engines are presented. Topics include plasma sprayed coating methods, yttria stabilized zirconia coatings, coating life models, coating failure and durability, thermal shock and cycling, and acoustic emission analysis of coatings. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  2. Degradation of Thermal Barrier Coatings from Deposits and Its Mitigation

    SciTech Connect (OSTI)

    Nitin Padture

    2011-12-31

    Ceramic thermal barrier coatings (TBCs) used in gas-turbine engines afford higher operating temperatures, resulting in enhanced efficiencies and performance. However, in the case of syngas-fired engines, fly ash particulate impurities that may be present in syngas can melt on the hotter TBC surfaces and form glassy deposits. These deposits can penetrate the TBCs leading to their failure. In experiments using lignite fly ash to simulate these conditions we show that conventional TBCs of composition 93wt% ZrO{sub 2} + 7wt% Y{sub 2}O{sub 3} (7YSZ) fabricated using the air plasma spray (APS) process are completely destroyed by the molten fly ash. The molten fly ash is found to penetrate the full thickness of the TBC. The mechanisms by which this occurs appear to be similar to those observed in degradation of 7YSZ TBCs by molten calcium-magnesium-aluminosilicate (CMAS) sand and by molten volcanic ash in aircraft engines. In contrast, APS TBCs of Gd{sub 2Zr{sub 2}O{sub 7} composition are highly resistant to attack by molten lignite fly ash under identical conditions, where the molten ash penetrates ~25% of TBC thickness. This damage mitigation appears to be due to the formation of an impervious, stable crystalline layer at the fly ash/Gd{sub 2}Zr{sub 2}O{sub 7} TBC interface arresting the penetrating moltenfly- ash front. Additionally, these TBCs were tested using a rig with thermal gradient and simultaneous accumulation of ash. Modeling using an established mechanics model has been performed to illustrate the modes of delamination, as well as further opportunities to optimize coating microstructure. Transfer of the technology was developed in this program to all interested parties.

  3. Method And Apparatus For Determining Health Of Thermal Barrier Coatings

    DOE Patents [OSTI]

    Srivastava, Alok Mani (Niskayuna, NY); Setlur, Anant Achyut (Niskayuna, NY); Comanzo, Holly Ann (Niskayuna, NY); Devitt, John William (Clifton Park, NY); Ruud, James Anthony (Delmar, NY); Brewer, Luke Nathaniel (Clifton Park, NY)

    2005-09-13

    A method for determining past-service conditions and/or remaining useful life of a component of a combustion engine and/or a thermal barrier coating ("TBC") of the component comprises providing a photoluminescent ("PL") material in the TBC, directing an exciting radiation at the TBC, measuring the intensity of a characteristic peak in the emission spectrum of the PL material, and correlating the intensity of the characteristic peak or another quantity derived therefrom to an amount of a new phase that has been formed as a result of the exposure of the component to extreme temperatures. An apparatus for carrying out the method comprises a radiation source that provides the exciting radiation to the TBC, a radiation detector for detecting radiation emitted by the PL material, and means for relating a characteristic of the emission spectrum of the PL material to the amount of the new phase in the TBC, thereby inferring the past-service conditions or the remaining useful life of the component.

  4. Thermal barrier and overlay coating systems comprising composite metal/metal oxide bond coating layers

    DOE Patents [OSTI]

    Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL); Vance, Steven J. (Orlando, FL)

    2001-01-01

    The present invention generally describes multilayer coating systems comprising a composite metal/metal oxide bond coat layer. The coating systems may be used in gas turbines.

  5. Oxidation and degradation of a plasma-sprayed thermal barrier coating system

    SciTech Connect (OSTI)

    Haynes, J.A.; Ferber, M.K.; Porter, W.D.

    1996-04-01

    The isothermal oxidation behavior of thermal barrier coating (TBC) specimens consisting of single-crystal superalloy substrates, vacuum plasma-sprayed Ni-22Cr-10Al-1Y bond coatings and air plasma-sprayed 7.5 wt.% yttria stabilized zirconia top coatings was evaluated by thermogravimetric analysis at 1150{degrees}C for up to 200 hours. Coating durability was assessed by furnace cycling at 1150{degrees}C. Coatings and reaction products were identified by x-ray diffraction, field-emission scanning electron microscopy and energy dispersive spectroscopy.

  6. EVOLUTION OF POROSITY AND TEXTURE IN THERMAL BARRIER COATINGS GROWN BY EB-PVD

    E-Print Network [OSTI]

    Clarke, David R.

    coatings (TBCs) have emerged as arguably the most critical materials issue for the next generation of gas of nearly three decades of service in gas turbines, full realization of the TBC potential remains hinderedEVOLUTION OF POROSITY AND TEXTURE IN THERMAL BARRIER COATINGS GROWN BY EB-PVD Scott G. Terry

  7. Simulation of the high temperature impression of thermal barrier coatings with columnar microstructure

    E-Print Network [OSTI]

    Hutchinson, John W.

    Thermal barrier systems used in gas turbines utilize various ternary oxides as the outermost insulatingSimulation of the high temperature impression of thermal barrier coatings with columnar of Engineering and Applied Sciences, Harvard University, 29 Oxford Street, Cambridge, MA 02138, USA c Materials

  8. Thermal barrier coating deposition by rarefied gas jet assisted processes: Simulations of deposition on a stationary airfoil

    E-Print Network [OSTI]

    Wadley, Haydn

    Thermal barrier coating deposition by rarefied gas jet assisted processes: Simulations) The uniform coating of a complex shaped substrate, such as a gas turbine airfoil, by collisionless physical thermal barrier coating are used to investigate fundamental aspects of the deposition process, including

  9. Initial Assessment of Environmental Barrier Coatings for the Prometheus Project

    SciTech Connect (OSTI)

    M. Frederick

    2005-12-15

    Depending upon final design and materials selections, a variety of engineering solutions may need to be considered to avoid chemical degradation of components in a notional space nuclear power plant (SNPP). Coatings are one engineered approach that was considered. A comprehensive review of protective coating technology for various space-reactor structural materials is presented, including refractory metal alloys [molybdenum (Mo), tungsten (W), rhenium (Re), tantalum (Ta), and niobium (Nb)], nickel (Ni)-base superalloys, and silicon carbide (Sic). A summary description of some common deposition techniques is included. A literature survey identified coatings based on silicides or iridium/rhenium as the primary methods for environmental protection of refractory metal alloys. Modified aluminide coatings have been identified for superalloys and multilayer ceramic coatings for protection of Sic. All reviewed research focused on protecting structural materials from extreme temperatures in highly oxidizing conditions. Thermodynamic analyses indicate that some of these coatings may not be protective in the high-temperature, impure-He environment expected in a Prometheus reactor system. Further research is proposed to determine extensibility of these coating materials to less-oxidizing or neutral environments.

  10. Zirconia and Pyrochlore Oxides for Thermal Barrier Coatings in Gas Turbine Engines

    SciTech Connect (OSTI)

    Fergus, Jeffrey W.

    2014-04-12

    One of the important applications of yttria stabilized zirconia is as a thermal barrier coating for gas turbine engines. While yttria stabilized zirconia performs well in this function, the need for increased operating temperatures to achieve higher energy conversion efficiencies, requires the development of improved materials. To meet this challenge, some rare-earth zirconates that form the cubic fluorite derived pyrochlore structure are being developed for use in thermal barrier coatings due to their low thermal conductivity, excellent chemical stability and other suitable properties. In this paper, the thermal conductivities of current and prospective oxides for use in thermal barrier coatings are reviewed. The factors affecting the variations and differences in the thermal conductivities and the degradation behaviors of these materials are discussed.

  11. A model for residual stress evolution in air-plasma-sprayed zirconia thermal barrier coatings

    SciTech Connect (OSTI)

    Nair, B. G.; Singh, J. P.; Grimsditch, M.

    2000-02-28

    Ruby fluorescence spectroscopy indicates that residual stress in air-plasma-sprayed zirconia thermal barrier coatings is a function of the local interface geometry. The stress profile of a simulated rough interface characterized by ``peaks'' and ``valleys'' was modeled with a finite-element approach that accounted for thermal mismatch, oxide scale growth, and top coat sintering. Dependence of the stress profile on interface geometry and microstructure was investigated, and the results were compared with measured stresses.

  12. Ultrasonic Detection of Delamination and Material Characterization of Thermal Barrier Coatings

    SciTech Connect (OSTI)

    Chen, Hung-Liang Roger; Zhang, Binwei; Alvin, Mary Anne; Lin, Yun

    2012-12-01

    This article describes ultrasonic nondestructive evaluation (NDE) to detect the changes of material properties and provide early warning of delamination in thermal barrier coating (TBC) systems. NDE tests were performed on single-crystal René N5 superalloy coupons that were coated with a commercially available MCrAlY bond coat and an air plasma sprayed 7% yttria-stabilized zirconia (YSZ) top coat deposited by Air Plasma Spray method, as well as Haynes 230 superalloy coupons coated with MCrA1Y bond coat, and an electron beam physical vapor deposit of 7% YSZ top coat. The TBC coupons were subjected to either cyclic or isothermal exposure for various lengths of time at temperatures ranging from 900 to 1100 °C. The ultrasonic measurements performed on the coupons had provided an early warning of delamination along the top coat/TGO interface before exposure time, when delamination occurred. The material's property (Young’s modulus) of the top coat was estimated using the measured wave speeds. Finite element analysis (FEA) of the ultrasonic wave propagation was conducted on a simplified TBC system to verify experimental observations. The technique developed was also demonstrated on an as-manufactured turbine blade to estimate normalized top coat thickness measurements.

  13. Advanced thermal barrier coatings for operation in high hydrogen content fueled gas turbines.

    SciTech Connect (OSTI)

    Sampath, Sanjay

    2015-04-02

    The Center for Thermal Spray Research (CTSR) at Stony Brook University in partnership with its industrial Consortium for Thermal Spray Technology is investigating science and technology related to advanced metallic alloy bond coats and ceramic thermal barrier coatings for applications in the hot section of gasified coal-based high hydrogen turbine power systems. In conjunction with our OEM partners (GE and Siemens) and through strategic partnership with Oak Ridge National Laboratory (ORNL) (materials degradation group and high temperature materials laboratory), a systems approach, considering all components of the TBC (multilayer ceramic top coat, metallic bond coat & superalloy substrate) is being taken during multi-layered coating design, process development and subsequent environmental testing. Recent advances in process science and advanced in situ thermal spray coating property measurement enabled within CTSR has been incorporated for full-field enhancement of coating and process reliability. The development of bond coat processing during this program explored various aspects of processing and microstructure and linked them to performance. The determination of the bond coat material was carried out during the initial stages of the program. Based on tests conducted both at Stony Brook University as well as those carried out at ORNL it was determined that the NiCoCrAlYHfSi (Amdry) bond coats had considerable benefits over NiCoCrAlY bond coats. Since the studies were also conducted at different cycling frequencies, thereby addressing an associated need for performance under different loading conditions, the Amdry bond coat was selected as the material of choice going forward in the program. With initial investigations focused on the fabrication of HVOF bond coats and the performance of TBC under furnace cycle tests , several processing strategies were developed. Two-layered HVOF bond coats were developed to render optimal balance of density and surface roughness and resulted in improved TBC lifetimes. Processing based approaches of identifying optimal processing regimes deploying advanced in-situ coating property measurements and in-flight diagnostic tools were used to develop process maps for bond coats. Having established a framework for the bond coat processing using the HVOF process, effort were channeled towards fabrication of APS and VPS bond coats with the same material composition. Comparative evaluation of the three deposition processes with regard to their microstrcuture , surface profiles and TBC performance were carried out and provided valuable insights into factors that require concurrent consideration for the development of bond coats for advanced TBC systems. Over the course of this program several advancements were made on the development of durable thermal barrier coatings. Process optimization techniques were utilized to identify processing regimes for both conventional YSZ as well as other TBC compositions such as Gadolinium Zirconate and other Co-doped materials. Measurement of critical properties for these formed the initial stages of the program to identify potential challenges in their implementation as part of a TBC system. High temperature thermal conductivity measurements as well as sintering behavior of both YSZ and GDZ coatings were evaluated as part of initial efforts to undersand the influence of processing on coating properties. By effectively linking fundamental coating properties of fracture toughness and elastic modulus to the cyclic performance of coatings, a durability strategy for APS YSZ coatings was developed. In order to meet the goals of fabricating a multimaterial TBC system further research was carried out on the development of a gradient thermal conductivity model and the evaluation of sintering behavior of multimaterial coatings. Layer optimization for desired properties in the multimaterial TBC was achieved by an iterative feedback approach utilizing process maps and in-situ and ex-situ coating property sensors. Addressing the challenges pertaining to the integration of th

  14. Damage evolution and residual stresses in plasma-sprayed zirconia thermal barrier coatings.

    SciTech Connect (OSTI)

    Singh, J. P.

    1999-02-03

    Air-plasma-sprayed zirconia thermal barrier coatings were subjected to thermal cycling and residual stress evolution in thermally grown oxide scale was studied by micro- and macro-ruby fluorescence spectroscopy. The macro approach reveals that compressive stress in the oxide scale increases with increasing number of thermal cycles (and thus increasing scale thickness), reaching a value of 1.8 GPa at a scale thickness of 3-4 {micro}m (80 cycles). Micro-ruby fluorescence spectroscopy indicates that protrusions of the zirconia top coat into the bond coat act as localized areas of high stress concentration, leading to damage initiation during thermal cycling.

  15. Factors affecting the microstructural stability and durability of thermal barrier coatings fabricated by air plasma spraying

    SciTech Connect (OSTI)

    Helminiak, M. A.; Yanar, N. M.; Pettit, F. S.; Taylor, T. A.; Meier, G. H.

    2012-10-01

    The high-temperature behavior of high-purity, low-density (HP-LD) air plasma sprayed (APS) thermal barrier coatings (TBCs) with NiCoCrAlY bond coats deposited by argon-shrouded plasma spraying is described. The high purity yttria-stabilized zirconia resulted in top coats which are highly resistant to sintering and transformation from the metastable tetragonal phase to the equilibrium mixture of monoclinic and cubic phases. The thermal conductivity of the as-processed TBC is low but increases during high temperature exposure even before densification occurs. The porous topcoat microstructure also resulted in good spallation resistance during thermal cycling. The actual failure mechanisms of the APS coatings were found to depend on topcoat thickness, topcoat density, and the thermal cycle frequency. The failure mechanisms are described and the durability of the HP-LD coatings is compared with that of state-of-the-art electron beam physical vapor deposition TBCs.

  16. Grain-Boundary Grooving of Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings

    E-Print Network [OSTI]

    Trice, Rodney W.

    Grain-Boundary Grooving of Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings as t0 -ZrO2.8,9 Non-transform- able zirconia is a non-equilibrium phase as the concentration of yttrium cations in the zirconia lattice is greater than the con- centration predicted by the ZrO2­Y2O3 phase

  17. Finite element study of multi-modal vibration damping for thermal barrier coating applications

    E-Print Network [OSTI]

    barriers for gas turbine blades, there is a growing interest in devel- oping multifunctional coatings methods is critical in many tech- nologies and especially so for gas turbine engines since many the spinning up of the turbine to avoid resonances. One of the advances made in gas turbine technologies, has

  18. Zirconia and Pyrochlore Oxides for Thermal Barrier Coatings in Gas Turbine Engines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fergus, Jeffrey W.

    2014-04-12

    One of the important applications of yttria stabilized zirconia is as a thermal barrier coating for gas turbine engines. While yttria stabilized zirconia performs well in this function, the need for increased operating temperatures to achieve higher energy conversion efficiencies, requires the development of improved materials. To meet this challenge, some rare-earth zirconates that form the cubic fluorite derived pyrochlore structure are being developed for use in thermal barrier coatings due to their low thermal conductivity, excellent chemical stability and other suitable properties. In this paper, the thermal conductivities of current and prospective oxides for use in thermal barrier coatingsmore »are reviewed. The factors affecting the variations and differences in the thermal conductivities and the degradation behaviors of these materials are discussed.« less

  19. A method for measuring non-linear elastic properties of thermal barrier coatings

    SciTech Connect (OSTI)

    Johnson, C.A.; Ruud, J.A.; Kaya, A.C.; deLorenzi, H.G.

    1995-06-01

    Accurate characterization of the elastic properties of thermal barrier coatings (TBC`s) is important for failure prediction. Thermally sprayed coatings often exhibit anisotropic and nonlinear elastic properties due to the coating microstructure that results from the thermal spray process. A method was developed for determining the elastic behavior of TBC`s on substrates by measuring the in-plane modulus as a function of residual coating stress. The in-plane modulus was determined by resonant frequency measurement, and the residual stress was measured from the substrate curvature. The residual stress was varied both by increasing the temperature of the TBC and substrate and by applying compressive plastic strain to the metal substrate. The stress-strain behavior of the TBC was derived from the data for modulus versus residual stress, and significant nonlinear elastic behavior was observed.

  20. Thick Thermal Barrier Coatings (TTBCs) for Low Emission, High Efficiency Diesel Engine Components

    SciTech Connect (OSTI)

    M. Brad Beardsley, Caterpillar Inc.; Dr. Darrell Socie, University of Illinois; Dr. Ed Redja, University of Illinois; Dr. Christopher Berndt, State University of New York at Stony Brook

    2006-03-02

    The objective of this program was to advance the fundamental understanding of thick thermal barrier coating (TTBC) systems for application to low heat rejection diesel engine combustion chambers. Previous reviews of thermal barrier coating technology concluded that the current level of understanding of coating system behavior is inadequate and the lack of fundamental understanding may impede the application of thermal barrier coating to diesel engines.(1) Areas of TTBC technology examined in this program include powder characteristics and chemistry; bond coating composition, coating design, microstructure and thickness as they affect properties, durability, and reliability; and TTBC "aging" effects (microstructural and property changes) under diesel engine operating conditions. Fifteen TTBC ceramic powders were evaluated. These powders were selected to investigate the effects of different chemistries, different manufacturing methods, lot-to-lot variations, different suppliers and varying impurity levels. Each of the fifteen materials has been sprayed using 36 parameters selected by a design of experiments (DOE) to determine the effects of primary gas (Ar and N2), primary gas flow rate, voltage, arc current, powder feed rate, carrier gas flow rate, and spraying distance. The deposition efficiency, density, and thermal conductivity of the resulting coatings were measured. A coating with a high deposition efficiency and low thermal conductivity is desired from an economic standpoint. An optimum combination of thermal conductivity and disposition efficiency was found for each lot of powder in follow-on experiments and disposition parameters were chosen for full characterization.(2) Strengths of the optimized coatings were determined using 4-point bending specimens. The tensile strength was determined using free-standing coatings made by spraying onto mild steel substrates which were subsequently removed by chemical etching. The compressive strengths of the coatings were determined using composite specimens of ceramic coated onto stainless steel substrates, tested with the coating in compression and the steel in tension. The strength of the coating was determined from an elastic bi-material analysis of the resulting failure of the coating in compression.(3) Altough initial comparisons of the materials would appear to be straight forward from these results, the results of the aging tests of the materials are necessary to insure that trends in properties remain after long term exposure to a diesel environment. Some comparisons can be made, such as the comparison between for lot-to-lot variation. An axial fatigue test to determine the high cycle fatigue behavior of TTBCs was developed at the University of Illinois under funding from this program.(4) A fatigue test apparatus has been designed and initial work performed which demonstrates the ability to provide a routine method of axial testing of coating. The test fixture replaces the normal load frame and fixtures used to transmit the hydraulic oil loading to the sample with the TTBC specimen itself. The TTBC specimen is a composite metal/coating with stainless steel ends. The coating is sprayed onto a mild steel center tube section onto which the stainless steel ends are press fit. The specimen is then machined. After machining, the specimen is placed in an acid bath which etches the mild steel away leaving the TTBC attached to the the stainless steel ends. Plugs are then installed in the ends and the composite specimen loaded in the test fixture where the hydraulic oil pressurizes each end to apply the load. Since oil transmits the load, bending loads are minimized. This test fixture has been modified to allow piston ends to be attached to the specimen which allows tensile loading as well as compressive loading of the specimen. In addition to the room temperature data, specimens have been tested at 800 Degrees C with the surprising result that at high temperature, the TTBC exhibits much higher fatigue strength. Testing of the TTBC using tension/compression cycling has been con

  1. Development of Diffusion barrier coatings and Deposition Technologies for Mitigating Fuel Cladding Chemical Interactions (FCCI)

    SciTech Connect (OSTI)

    Sridharan, Kumar; Allen, Todd; Cole, James

    2013-02-27

    The goal of this project is to develop diffusion barrier coatings on the inner cladding surface to mitigate fuel-cladding chemical interaction (FCCI). FCCI occurs due to thermal and radiation enhanced inter-diffusion between the cladding and fuel materials, and can have the detrimental effects of reducing the effective cladding wall thickness and lowering the melting points of the fuel and cladding. The research is aimed at the Advanced Burner Reactor (ABR), a sodium-cooled fast reactor, in which higher burn-ups will exacerbate the FCCI problem. This project will study both diffusion barrier coating materials and deposition technologies. Researchers will investigate pure vanadium, zirconium, and titanium metals, along with their respective oxides, on substrates of HT-9, T91, and oxide dispersion-strengthened (ODS) steels; these materials are leading candidates for ABR fuel cladding. To test the efficacy of the coating materials, the research team will perform high-temperature diffusion couple studies using both a prototypic metallic uranium fuel and a surrogate�¢����the rare-earth element lanthanum. Ion irradiation experiments will test the stability of the coating and the coating-cladding interface. A critical technological challenge is the ability to deposit uniform coatings on the inner surface of cladding. The team will develop a promising non-line-of-sight approach that uses nanofluids . Recent research has shown the feasibility of this simple yet novel approach to deposit coatings on test flats and inside small sections of claddings. Two approaches will be investigated: 1) modified electrophoretic deposition (MEPD) and 2) boiling nanofluids. The coatings will be evaluated in the as-deposited condition and after sintering.

  2. Apparatus for determining past-service conditions and remaining life of thermal barrier coatings and components having such coatings

    DOE Patents [OSTI]

    Srivastava, Alok Mani (Niskayuna, NY); Setlur, Anant Achyut (Niskayuna, NY); Comanzo, Holly Ann (Niskayuna, NY); Devitt, John William (Clifton Park, NY); Ruud, James Anthony (Delmar, NY); Brewer, Luke Nathaniel (Rexford, NY)

    2004-05-04

    An apparatus for determining past-service conditions and/or remaining useful life of a component of a combustion engine and/or a thermal barrier coating ("TBC") of the component comprises a radiation source that provides the exciting radiation to the TBC to excite a photoluminescent ("PL") material contained therein, a radiation detector for detecting radiation emitted by the PL material, and means for relating a characteristic of an emission spectrum of the PL material to the amount of a crystalline phase in the TBC, thereby inferring the past-service conditions or the remaining useful life of the component or the TBC.

  3. Thermal-barrier coatings: coating methods, performance, and heat-engine applications. July 1982-April 1989 (Citations from the EI Engineering Meetings data base). Report for July 1982-April 1989

    SciTech Connect (OSTI)

    Not Available

    1989-04-01

    This bibliography contains citations from conference proceedings concerning coating methods, performance evaluations, and applications of thermal-barrier coatings as protective coatings for heat-engine components against high temperature corrosions and chemical erosions. The developments of thermal barrier-coating techniques for high performance and reliable gas turbines, diesel engines, jet engines, and internal combustion engines are presented. Topics include plasma-sprayed-coating methods, yttria-stabilized zirconia coatings, coating-life models, coating failure and durability, thermal shock and cycling, and acoustic-emission analysis of coatings. (Contains 101 citations fully indexed and including a title list.)

  4. Hafnia-Based Nanostructured Thermal Barrier Coatings for Advanced Hydrogen Turbine Technology

    SciTech Connect (OSTI)

    Ramana, Chintalapalle; Choudhuri, Ahsan

    2013-01-31

    Thermal barrier coatings (TBCs) are critical technologies for future gas turbine engines of advanced coal based power generation systems. TBCs protect engine components and allow further increase in engine temperatures for higher efficiency. In this work, nanostructured HfO{sub 2}-based coatings, namely Y{sub 2}O{sub 3}-stabilized HfO{sub 2} (YSH), Gd{sub 2}O{sub 3}-stabilized HfO{sub 2} (GSH) and Y{sub 2}O{sub 3}-stabilized ZrO{sub 2}-HfO{sub 2} (YSZH) were investigated for potential TBC applications in hydrogen turbines. Experimental efforts are aimed at creating a fundamental understanding of these TBC materials. Nanostructured ceramic coatings of YSH, GSH and YSZH were grown by physical vapor deposition methods. The effects of processing parameters and ceramic composition on the microstructural evolution of YSH, GSH and YSZH nanostructured coatings was studied using combined X-ray diffraction (XRD) and Electron microscopy analyses. Efforts were directed to derive a detailed understanding of crystal-structure, morphology, and stability of the coatings. In addition, thermal conductivity as a function of composition in YSH, YSZH and GSH coatings was determined. Laboratory experiments using accelerated test environments were used to investigate the relative importance of various thermo-mechanical and thermo-chemical failure modes of TBCs. Effects of thermal cycling, oxidation and their complex interactions were evaluated using a syngas combustor rig.

  5. On the oxidation of high-temperature alloys, and its role in failure of thermal barrier coatings

    E-Print Network [OSTI]

    Loeffel, Kaspar Andreas

    2013-01-01

    Thermal barrier coating (TBC) systems are applied to superalloy turbine blades to provide thermal insulation and oxidation protection. A TBC system consists of (a) an outer oxide layer that imparts thermal insulation, and ...

  6. Thermal barrier characteristics of partially stabilized zirconia coatings on INCOLOY alloy 909; A controlled expansion alloy

    SciTech Connect (OSTI)

    Smith, G.D. )

    1991-01-01

    This paper reports on INCOLOY{sup 1} alloy 909 which is a low-expansion alloy used in critical seal and shaft applications within the gas turbine engine. However, because of its poor oxidation resistance at elevated temperatures, the maximum service temperature is limited. Since its coefficient of expansion is similar to that of partially stabilized zirconia for temperatures to 1200{degrees}F (649{degrees}C), it has been proposed to use this metal-ceramic combination for dimensionally critical, air-cooled jet engine components. This coating system should extend temperature limitations by reducing metal temperatures and providing oxidation resistance. The performance advantage offered by a thermal barrier coating has been investigated at temperatures up to 2000{degrees}F (1093{degrees}C) and the results are presented in this paper. Metal temperatures and heat flow rates of coated and bare specimens are compared for two air-cooling flow rates.

  7. NON-DESTRUCTIVE THERMAL BARRIER COATING SPALLATION PREDICTION BY A LOADBASED MICRO-INDENTATION TECHNIQUE

    SciTech Connect (OSTI)

    J. M. Tannenbaum; K. Lee; B. S.-J. Kang; M.A. Alvin

    2010-11-18

    Currently, the durability and life cycle of thermal barrier coatings (TBC) applied to gas turbine blades and combustor components are limiting the maximum temperature and subsequent efficiency at which gas turbine engines operate. The development of new materials, coating technologies and evaluation techniques is required if enhanced efficiency is to be achieved. Of the current ceramic coating materials used in gas turbine engines, yttria stabilized zirconia (YSZ) is most prevalent, its low thermal conductivity, high thermal expansion coefficient and outstanding mechanical strength make it ideal for use in TBC systems. However, residual stresses caused by coefficients of thermal expansion mismatches within the TBC system and unstable thermally grown oxides are considered the primary causes for its premature and erratic spallation failure. Through finite element simulations, it is shown that the residual stresses generated within the thermally grown oxide (TGO), bond coat (BC), YSZ and their interfaces create slight variations in indentation unloading surface stiffness response prior to spallation failure. In this research, seven air plasma sprayed and one electron beam physical vapor deposition yttria partially stabilized zirconia TBCs were subjected to isothermal and cyclic loadings at 1100°C. The associated coating degradation was evaluated using a non-destructive multiple partial unloading micro-indentation procedure. The results show that the proposed non-destructive micro-indentation evaluation technique can be an effective and specimenindependent TBC failure prediction tool capable of determining the location of initial spallation failure prior to its actual occurrence.

  8. Transient thermal analysis of a translucent thermal barrier coating on a metal wall

    SciTech Connect (OSTI)

    Siegel, R.

    1999-05-01

    A common ceramic used for thermal barrier coatings is zirconia, and it is partially transparent for radiative energy at wavelengths up to approximately 5 {micro}m. Hence, at elevated temperatures such as in a turbine engine combustor, the temperature distribution in a coating can be affected by absorption of incident radiation, by internal emission, and by scattering which is large for zirconia. Transient temperatures are needed of evaluating thermal stresses, and for translucent materials numerical procedures can be used to solve the transient energy equation coupled with radiative transfer relations. For radiation, both exact and approximate equations have been used. With general external conditions of convection and radiation for a translucent layer with diffuse surfaces, it was demonstrated in Siegel (1996) that the two-flux method compares well with more exact methods for predicting transient temperature distributions and heat fluxes, including large scattering as needed in a material such as zirconia. The two-flux differential equation for the internal radiative source is solved here with a Green`s function as in Siegel (1997), including two-band spectral property variations for zirconia. Finite difference relations are developed for transient temperatures in a translucent coating on a metal substrate. Illustrative results for heating a coated wall in a turbine engine combustor demonstrate transient heating behavior with translucent effects as compared with an opaque coating.

  9. PVD thermal barrier coating applications and process development for aircraft engines

    SciTech Connect (OSTI)

    Rigney, D.V.; Viguie, R.; Wortman, D.J.; Skelly, D.W.

    1995-10-01

    Thermal barrier coatings (TBC`s) have been developed for application to aircraft engine components to improve the life in an increasingly hostile thermal environment. The choice of TBC type is related to the component, intended use and economics. The selection of electron beam physical vapor deposition (EB PVD) processing for turbine blades is due in part to part size, surface finish requirements, thickness control needs, and hole closure issues. Process development of PVD TBC`s has been carried out at several different sites including GEAE. Some of the influences of processing variables on microstructure are discussed. The GEAE development coater and initial experiences of pilot line operation are discussed.

  10. The effect of thermal aging on the thermal conductivity of plasma sprayed and EB-PVD thermal barrier coatings

    SciTech Connect (OSTI)

    Dinwiddie, R.B.; Beecher, S.C.; Porter, W.D.; Nagaraj, B.A.

    1996-05-01

    Thermal barrier coatings (TBCs) applied to the hot gas components of turbine engines lead to enhanced fuel efficiency and component reliability. Understanding the mechanisms which control the thermal transport behavior of the TBCs is of primary importance. Electron beam-physical vapor deposition (EV-PVD) and air plasma spraying (APS) are the two most commonly used coating techniques. These techniques produce coatings with unique microstructures which control their performance and stability. The density of the APS coatings was controlled by varying the spray parameters. The low density APS yttria-partially stabilized zirconia (yttria-PSZ) coatings yielded a thermal conductivity that is lower than both the high density APS coatings and the EB-PVD coatings. The thermal aging of both fully and partially stabilized zirconia are compared. The thermal conductivity of the coatings permanently increases upon exposure to high temperatures. These increases are attributed to microstructural changes within the coatings. This increase in thermal conductivity can be modeled using a relationship which depends on both the temperature and time of exposure. Although the EB-PVD coatings are less susceptible to thermal aging effects, results suggest that they typically have a higher thermal conductivity than APS coatings before thermal aging. The increases in thermal conductivity due to thermal aging for plasma sprayed partially stabilized zirconia have been found to be less than for plasma sprayed fully stabilized zirconia coatings.

  11. Low Thermal Conductivity, High Durability Thermal Barrier Coatings for IGCC Environments

    SciTech Connect (OSTI)

    Jordan, Eric; Gell, Maurice

    2015-01-15

    Advanced thermal barrier coatings (TBC) are crucial to improved energy efficiency in next generation gas turbine engines. The use of traditional topcoat materials, e.g. yttria-stabilized zirconia (YSZ), is limited at elevated temperatures due to (1) the accelerated undesirable phase transformations and (2) corrosive attacks by calcium-magnesium-aluminum-silicate (CMAS) deposits and moisture. The first goal of this project is to use the Solution Precursor Plasma Spray (SPPS) process to further reduce the thermal conductivity of YSZ TBCs by introducing a unique microstructural feature of layered porosity, called inter-pass boundaries (IPBs). Extensive process optimization accompanied with hundreds of spray trials as well as associated SEM cross-section and laser-flash measurements, yielded a thermal conductivity as low as 0.62 Wm?¹K?¹ in SPPS YSZ TBCs, approximately 50% reduction of APS TBCs; while other engine critical properties, such as cyclic durability, erosion resistance and sintering resistance, were characterized to be equivalent or better than APS baselines. In addition, modifications were introduced to SPPS TBCs so as to enhance their resistance to CMAS under harsh IGCC environments. Several mitigation approaches were explored, including doping the coatings with Al?O? and TiO?, applying a CMAS infiltration-inhibiting surface layer, and filling topcoat cracks with blocking substances. The efficacy of all these modifications was assessed with a set of novel CMAS-TBC interaction tests, and the moisture resistance was tested in a custom-built high-temperature moisture rig. In the end, the optimal low thermal conductivity TBC system was selected based on all evaluation tests and its processing conditions were documented. The optimal coating consisted on a thick inner layer of YSZ coating made by the SPPS process having a thermal conductivity 50% lower than standard YSZ coatings topped with a high temperature tolerant CMAS resistant gadolinium zirconate Coating made by the SPPS process. Noteworthy was the fact that the YSZ to GZO interface made by the SPPS process was not the failure location as had been observed in APS coatings.

  12. Phase Stability of t;#8242;-Zirconia-Based Thermal Barrier Coatings: Mechanistic Insights

    SciTech Connect (OSTI)

    Krogstad, Jessica A.; Krämer, Stephan; Lipkin, Don M.; Johnson, Curtis A.; Mitchell, David R.G.; Cairney, Julie M.; Levi, Carlos G.

    2011-11-07

    The temperature capability of yttria-stabilized zirconia thermal barrier coatings (TBCs) is ultimately tied to the rate of evolution of the 'nontransformable' t' phase into a depleted tetragonal form predisposed to the monoclinic transformation on cooling. The t' phase, however, has been shown to decompose in a small fraction of the time necessary to form the monoclinic phase. Instead, a modulated microstructure consisting of a coherent array of Y-rich and Y-lean lamellar phases develops early in the process, with mechanistic features suggestive of spinodal decomposition. Coarsening of this microstructure leads to loss of coherency and ultimately transformation into the monoclinic form, making the kinetics of this process, and not the initial decomposition, the critical factor in determining the phase stability of TBCs. Transmission electron microscopy is shown to be essential not only for characterizing the microstructure but also for proper interpretation of X-ray diffraction analysis.

  13. Microwave Drilling of Ceramic Thermal-Barrier Coatings Faculty of Engineering, Tel Aviv University, Ramat Aviv 69978, Israel

    E-Print Network [OSTI]

    Jerby, Eli

    Microwave Drilling of Ceramic Thermal-Barrier Coatings Eli Jerby Faculty of Engineering, Tel Aviv, Schenectady, New York 12301 The microwave drill is a novel process for creating shaped holes in nonconductive materials. Its inherent material selec- tivity makes the microwave drill ideally suited for the con- trolled

  14. CHEMICALLY VAPOR DEPOSITED YTTRIA-STABILIZED ZIRCONIA (YSZ) FOR THERMAL AND ENVIRONMENTAL BARRIER COATING

    SciTech Connect (OSTI)

    Varanasi, V.G.; Besmann, T.M.; Lothian, J.L.; Xu, W.; Starr, T.L.

    2003-04-22

    Yttria-stabilized zirconia (YSZ) is used as a thermal barrier coating (TBC) to protect super-alloy blades such as Mar-M247 or Rene-N5 during engine operation. The current method for YSZ fabrication for TBC applications is by air-plasma spraying (APS) or electron beam physical vapor deposition (EB-PVD) (Haynes 1997). APS gives reasonable deposition rates, but has a limited life and aging effects due to its porous and lamellar structure. The EB-PVD coatings are more stable and can accommodate thermomechanical stresses due to their characteristic strain-tolerant, columnar microstructure. EB-PVD, however, is primarily line-of-sight, which often leaves ''hidden areas'' uncoated, has low throughput, and has high capital cost. The process of metal-organic chemical vapor deposition (MOCVD) is investigated here as an economical alternative to EB-PVD and APS, with the potential for better overall coverage as well as the ability to produce thick (100-250 {micro}m), strain-tolerant, columnar coatings. MOCVD of YSZ involves the use of zirconium and yttrium organometallic precursors reacting with an oxygen source. Previous researchers have used diketonate or chloride precursors and oxygen (Wahl et al. 2001a, Wahl et al. 2001b, Yamane and Harai 1989). These precursors have low transport rates due to their low carrier solvent solubility (Varanasi et al. 2003). Solvated zirconium and yttrium butoxide precursors were investigated here due to their higher vapor pressures and high solvent solubility. This work uses predictive equilibrium modeling and experiments involving butoxide precursors for tetragonal YSZ fabrication.

  15. Model Studies of Pore Stability and Evolution in Thermal Barrier Coatings (TBCs)

    E-Print Network [OSTI]

    Glaeser, A M

    2008-01-01

    Thermal conductivity of zirconia coatings with zig-zag poreconductivity vapor deposited zirconia microstructures,” Actaof a Yttria-stabilized zirconia coating fabricated by

  16. Spectral Modeling of Residual Stress and Stored Elastic Strain Energy in Thermal Barrier Coatings

    SciTech Connect (OSTI)

    Donegan, Sean; Rolett, Anthony

    2013-12-31

    Solutions to the thermoelastic problem are important for characterizing the response under temperature change of refractory systems. This work extends a spectral fast Fourier transform (FFT) technique to analyze the thermoelastic behavior of thermal barrier coatings (TBCs), with the intent of probing the local origins of failure in TBCs. The thermoelastic FFT (teFFT) approach allows for the characterization of local thermal residual stress and strain fields, which constitute the origins of failure in TBC systems. A technique based on statistical extreme value theory known as peaks-over-threshold (POT) is developed to quantify the extreme values ("hot spots") of stored elastic strain energy (i.e., elastic energy density, or EED). The resolution dependence of the teFFT method is assessed through a sensitivity study of the extreme values in EED. The sensitivity study is performed both for the local (point-by-point) #12;eld distributions as well as the grain scale #12;eld distributions. A convergence behavior to a particular distribution shape is demonstrated for the local #12;elds. The grain scale fields are shown to exhibit a possible convergence to a maximum level of EED. To apply the teFFT method to TBC systems, 3D synthetic microstructures are created to approximate actual TBC microstructures. The morphology of the grains in each constituent layer as well as the texture is controlled. A variety of TBC materials, including industry standard materials and potential future materials, are analyzed using the teFFT. The resulting hot spots are quantified using the POT approach. A correlation between hot spots in EED and interface rumpling between constituent layers is demonstrated, particularly for the interface between the bond coat (BC) and the thermally grown oxide (TGO) layer.

  17. Chemical and mechanical consequences of environmental barrier coating exposure to calcium-magnesium-aluminosilicate.

    SciTech Connect (OSTI)

    Harder, B.; Ramirez-Rico, J.; Almer, J. D.; Kang, L.; Faber, K.

    2011-06-01

    The success of Si-based ceramics as high-temperature structural materials for gas turbine applications relies on the use of environmental barrier coatings (EBCs) with low silica activity, such as Ba{sub 1-x}Sr{sub x}Al{sub 2}Si{sub 2}O{sub 8} (BSAS), which protect the underlying components from oxidation and corrosion in combustion environments containing water vapor. One of the current challenges concerning EBC lifetime is the effect of sandy deposits of calcium-magnesium-aluminosilicate (CMAS) glass that melt during engine operation and react with the EBC, changing both its composition and stress state. In this work, we study the effect of CMAS exposure at 1300 C on the residual stress state and composition in BSAS-mullite-Si-SiC multilayers. Residual stresses were measured in BSAS multilayers exposed to CMAS for different times using high-energy X-ray diffraction. Their microstructure was studied using a combination of scanning electron microscopy and transmission electron microscopy techniques. Our results show that CMAS dissolves the BSAS topcoat preferentially through the grain boundaries, dislodging the grains and changing the residual stress state in the topcoat to a nonuniform and increasingly compressive stress state with increasing exposure time. The presence of CMAS accelerates the hexacelsian-to-celsian phase transformation kinetics in BSAS, which reacts with the glass by a solution-reprecipitation mechanism. Precipitates have crystallographic structures consistent with Ca-doped celsian and Ba-doped anorthite.

  18. Vanadate-sulfate melt thermochemistry relating to hot corrosion of thermal barrier coatings. Final report

    SciTech Connect (OSTI)

    Jones, R.L.

    1997-10-30

    The gas turbine industry is moving strongly toward the use of ZrO2-based thermal barrier coatings (TBCs) on hot section vanes/blades to increase engine efficiency and durability. In some applications (e.g., ship propulsion or electricity generation), such TBCs may be corroded by molten vanadate-sulfate deposits from fuel impurities. This Report provides a synopsis of vanadate-sulfate thermochemistry relating to TBC hot corrosion, and summarizes research conducted on this topic at the Naval Research Laboratory. The interactions of Na2O, V2O5 and SO3, the melt components which determine the composition of the vanadate-sulfate deposits, were examined and clarified. Vanadate-sulfate melts were shown to be nonideal rather than ideal a point of some contention in the past literature and, for melts of Na/V = 1, to have a V205 activity coefficient (gamma) that ranges from 5 x 10(exp -4) up to essentially 1, depending on the S03 overpressure. Different NaVO3/Na2SO4 mixtures gave a detectable but small change in gamma(V2O5), suggesting that the Na/V ratio is relatively unimportant, for melts equilibrated with SO3, in determining gamma(V2O5). The reactions of several candidate ZrO2 stabilizers (MgO, CeO2, Sc2O3, In2O3, SnO2) with vanadate-sulfate melts are categorized and discussed.

  19. The origin of slow electron recombination processes in dye-sensitized solar cells with alumina barrier coatings

    SciTech Connect (OSTI)

    Fabregat-Santiago, Francisco; Garcia-Canadas, Jorge; Palomares, Emilio; Clifford, John N.; Haque, Saif A.; Durrant, James R.; Garcia-Belmonte, Germa; Bisquert, Juan [Departament de Ciencies Experimentals, Universitat Jaume I, 12080 Castello (Spain); Department of Chemistry, Imperial College, London SW7 2AY (United Kingdom); Institut de Ciencia Molecular Universitat de Valencia, C. P. 46100, Dr. Moliner 50, Burjassot, Valencia (Spain); Department of Chemistry, Imperial College, London SW7 2AY (United Kingdom); Departament de Ciencies Experimentals, Universitat Jaume I, 12080 Castello (Spain)

    2004-12-01

    We investigate the effect of a thin alumina coating of nanocrystalline TiO{sub 2} films on recombination dynamics of dye-sensitized solar cells. Both coated and uncoated cells were measured by a combination of techniques: transient absorption spectroscopy, electrochemical impedance spectroscopy, and open-circuit voltage decay. It is found that the alumina barrier reduces the recombination of photoinjected electrons to both dye cations and the oxidized redox couple. It is proposed that this observed retardation can be attributed primarily to two effects: almost complete passivation of surface trap states in TiO{sub 2} that are able to inject electrons to acceptor species, and slowing down by a factor of 3-4 the rate of interfacial charge transfer from conduction-band states.

  20. Method and apparatus for measuring on-line failure of turbine thermal barrier coatings

    DOE Patents [OSTI]

    Zombo, Paul J.; Lemieux, Dennis; Diatzikis, Evangelos

    2010-04-06

    A method of remotely monitoring the radiant energy (6) emitted from a turbine component such as a turbine blade (1) having a low-reflective surface coating (3) which may be undergoing potential degradation is used to determine whether erosion, spallation, delamination, or the like, of the coating (3) is occurring.

  1. A sintering model for thermal barrier coatings R.G. Hutchinson a

    E-Print Network [OSTI]

    Fleck, Norman A.

    a Cambridge University Engineering Department, Trumpington Street, Cambridge CB2 1PZ, UK b Department of Engineering, Leicester University, Leicester LE1 7RH, UK Received 15 September 2005; received in revised form-PVD coatings comprise a 100­200 lm thick layer of columnar yttria-stabilised zirconia (typically, 7YSZ

  2. Mechanisms Underpinning Degradation of Protective Oxides and Thermal Barrier Coatings in High Hydrogen Content (HHC) - Fueled Turbines

    SciTech Connect (OSTI)

    Mumm, Daniel

    2013-08-31

    The overarching goal of this research program has been to evaluate the potential impacts of coal-derived syngas and high-hydrogen content fuels on the degradation of turbine hot-section components through attack of protective oxides and thermal barrier coatings. The primary focus of this research program has been to explore mechanisms underpinning the observed degradation processes, and connections to the combustion environments and characteristic non-combustible constituents. Based on the mechanistic understanding of how these emerging fuel streams affect materials degradation, the ultimate goal of the program is to advance the goals of the Advanced Turbine Program by developing materials design protocols leading to turbine hot-section components with improved resistance to service lifetime degradation under advanced fuels exposures. This research program has been focused on studying how: (1) differing combustion environments – relative to traditional natural gas fired systems – affect both the growth rate of thermally grown oxide (TGO) layers and the stability of these oxides and of protective thermal barrier coatings (TBCs); and (2) how low levels of fuel impurities and characteristic non-combustibles interact with surface oxides, for instance through the development of molten deposits that lead to hot corrosion of protective TBC coatings. The overall program has been comprised of six inter-related themes, each comprising a research thrust over the program period, including: (i) evaluating the role of syngas and high hydrogen content (HHC) combustion environments in modifying component surface temperatures, heat transfer to the TBC coatings, and thermal gradients within these coatings; (ii) understanding the instability of TBC coatings in the syngas and high hydrogen environment with regards to decomposition, phase changes and sintering; (iii) characterizing ash deposition, molten phase development and infiltration, and associated corrosive/thermo-chemical attack mechanisms; (iv) developing a mechanics-based analysis of the driving forces for crack growth and delamination, based on molten phase infiltration, misfit upon cooling, and loss of compliance; (v) understanding changes in TGO growth mechanisms associated with these emerging combustion product streams; and (vi) identifying degradation resistant alternative materials (including new compositions or bi-layer concepts) for use in mitigating the observed degradation modes. To address the materials stability concerns, this program integrated research thrusts aimed at: (1) Conducting tests in simulated syngas and HHC environments to evaluate materials evolution and degradation mechanisms; assessing thermally grown oxide development unique to HHC environmental exposures; carrying out high-resolution imaging and microanalysis to elucidate the evolution of surface deposits (molten phase formation and infiltration); exploring thermo-chemical instabilities; assessing thermo-mechanical drivers and thermal gradient effects on degradation; and quantitatively measuring stress evolution due to enhanced sintering and thermo-chemical instabilities induced in the coating. (2) Executing experiments to study the melting and infiltration of simulated ash deposits, and identifying reaction products and evolving phases associated with molten phase corrosion mechanisms; utilizing thermal spray techniques to fabricate test coupons with controlled microstructures to study mechanisms of instability and degradation; facilitating thermal gradient testing; and developing new materials systems for laboratory testing; (3) Correlating information on the resulting combustion environments to properly assess materials exposure conditions and guide the development of lab-scale simulations of material exposures; specification of representative syngas and high-hydrogen fuels with realistic levels of impurities and contaminants, to explore differences in heat transfer, surface degradation, and deposit formation; and facilitating combustion rig testing of materials test coupons.

  3. The effect of thermal barrier coated piston crown on engine characteristics

    SciTech Connect (OSTI)

    Chan, S.H.; Khor, K.A.

    2000-02-01

    While there have been numerous research papers in recent years describing the theoretical benefits obtained from the use of ceramic components in reciprocating engines, the amount of literature that describes practical results is very limited. Although successes have been reported and ceramic components are now in service in production engines, mainly for reduced in-cylinder heat rejection, many researchers have experienced failures or a drop in engine performance. This article presents the work completed on a low heat rejection engine. Extensive experiments were conducted on a three-cylinder SI Daihatsu engine with piston crowns coated with a layer of ceramic, which consisted of yttria-stabilized zirconia (YSZ). Measurement and comparison of engine performance, in particular fuel consumption, were made before and after the application of YSZ coatings deposited onto the piston crowns. The details of the cylinder pressures during the combustion process were also investigated.

  4. EDDY CURRENT INVERSION AND ESTIMATION METRICS FOR EVALUATING THERMAL BARRIER COATINGS

    SciTech Connect (OSTI)

    Sabbagh, Harold A.; Murphy, R. Kim; Sabbagh, Elias H. [Victor Technologies LLC, Bloomington, IN 47401 (United States); Knopp, Jeremy S. [Air Force Research Laboratory, Wright-Patterson AFB, OH 45433 (United States); Aldrin, John C. [Computational Tools, Gurnee, IL 60031 (United States); Nyenhuis, John [Dept. of Electric Computer Engineering, Purdue University, West Lafayette, IN (United States)

    2010-02-22

    In this paper, sophisticated eddy-current techniques incorporating model-based inverse methods were successfully demonstrated to measure the thickness and remaining-life of high-temperature coatings. To further assure the performance of these inverse methods, several estimation metrics including Fisher Information, Cramer-Rao Lower Bound (CRLB), covariance, and singular value decomposition (SVD) are introduced. The connections and utility of these metrics are illustrated in the design of eddy current methods for estimating layer thickness, conductivity and probe liftoff.

  5. Aluminide coatings

    DOE Patents [OSTI]

    Henager, Jr; Charles, H [Kennewick, WA; Shin, Yongsoon [Richland, WA; Samuels, William D [Richland, WA

    2009-08-18

    Disclosed herein are aluminide coatings. In one embodiment coatings are used as a barrier coating to protect a metal substrate, such as a steel or a superalloy, from various chemical environments, including oxidizing, reducing and/or sulfidizing conditions. In addition, the disclosed coatings can be used, for example, to prevent the substantial diffusion of various elements, such as chromium, at elevated service temperatures. Related methods for preparing protective coatings on metal substrates are also described.

  6. Environmental barrier coating

    DOE Patents [OSTI]

    Pujari, Vimal K.; Vartabedian, Ara; Collins, William T.; Woolley, David; Bateman, Charles

    2012-12-18

    The present invention relates generally to a multi-layered article suitable for service in severe environments. The article may be formed of a substrate, such as silicon carbide and/or silicon nitride. The substrate may have a first layer of a mixture of a rare earth silicate and Cordierite. The substrate may also have a second layer of a rare earth silicate or a mixture of a rare earth silicate and cordierite.

  7. The effect of sintering and CMAS on the stability of plasma-sprayed zirconia thermal barrier coatings

    E-Print Network [OSTI]

    Shinozaki, Maya

    2013-07-09

    . The vapour evaporates according to a cosn characteristic in all areas of the chamber. The vapour of the coating material condenses onto a (preheated) substrate surface, forming a coating. If an oxide is being deposited, a controlled amount of oxygen may... . This has obvious aerodynamic advantages and eliminates the need for final polishing stages. In addition, the EB-PVD process deposits with minimal closure of cooling holes (0.25 – 0.5 mm diameter) in aerofoils and therefore requires less subsequent...

  8. COMPARISON OF THERMAL PROPERTIES OF THERMAL BARRIER COATING DEPOSITED ON IN738 USING STANDARD AIR PLASMA SPRAY WITH 100HE PLASMA SPRAY SYSTEM

    SciTech Connect (OSTI)

    Uppu, N.; Mensah, P.F.; Ofori, D.

    2006-07-01

    A typical blade material is made of Nickel super alloy and can bear temperatures up to 950°C. But the operating temperature of a gas turbine is above the melting point of super alloy nearly at 1500°C. This could lead to hot corrosions, high temperature oxidation, creep, thermal fatigue may takes place on the blade material. Though the turbine has an internal cooling system, the cooling is not adequate to reduce the temperature of the blade substrate. Therefore to protect the blade material as well as increase the efficiency of the turbine, thermal barrier coatings (TBCs) must be used. A TBC coating of 250 ?m thick can reduce the temperature by up to 200° C. Air Plasma Spray Process (APS) and High Enthalpy Plasma Spray Process (100HE) were the processes used for coating the blades with the TBCs. Because thermal conductivity increases with increase in temperature, it is desired that these processes yield very low thermal conductivities at high temperatures in order not to damage the blade. An experiment was carried out using Flash line 5000 apparatus to compare the thermal conductivity of both processes.The apparatus could also be used to determine the thermal diffusivity and specific heat of the TBCs. 75 to 2800 K was the temperature range used in the experimentation. It was found out that though 100HE has high deposition efficiency, the thermal conductivity increases with increase in temperatures whiles APS yielded low thermal conductivities.

  9. Protective coatings for sensitive materials

    DOE Patents [OSTI]

    Egert, C.M.

    1997-08-05

    An enhanced protective coating is disclosed to prevent interaction between constituents of the environment and devices that can be damaged by those constituents. This coating is provided by applying a synergistic combination of diffusion barrier and physical barrier materials. These materials can be, for example, in the form of a plurality of layers of a diffusion barrier and a physical barrier, with these barrier layers being alternated. Further protection in certain instances is provided by including at least one layer of a getter material to actually react with one or more of the deleterious constituents. The coating is illustrated by using alternating layers of an organic coating (such as Parylene-C{trademark}) as the diffusion barrier, and a metal coating (such as aluminum) as the physical barrier. For best results there needs to be more than one of at least one of the constituent layers. 4 figs.

  10. Protective coatings for sensitive materials

    DOE Patents [OSTI]

    Egert, Charles M. (Oak Ridge, TN)

    1997-01-01

    An enhanced protective coating to prevent interaction between constituents of the environment and devices that can be damaged by those constituents. This coating is provided by applying a synergistic combination of diffusion barrier and physical barrier materials. These materials can be, for example, in the form of a plurality of layers of a diffusion barrier and a physical barrier, with these barrier layers being alternated. Further protection in certain instances is provided by including at least one layer of a getter material to actually react with one or more of the deleterious constituents. The coating is illustrated by using alternating layers of an organic coating (such as Parylene-C.TM.) as the diffusion barrier, and a metal coating (such as aluminum) as the physical barrier. For best results there needs to be more than one of at least one of the constituent layers.

  11. ADVANCED ELECTRON BEAM TECHNIQUES FOR METALLIC AND CERAMIC PROTECTIVE COATING SYSTEMS

    E-Print Network [OSTI]

    Boone, Donald H.

    2013-01-01

    Intermetallic Systems as Coatings for High TemperatureAdvanced Gas Turbine Coatings for Minimally Processed Coaland P. E. Hodge, "Thermal Barrier Coatings for Heat Engine

  12. A multiscale constitutive model for the sintering of an air-plasma sprayed thermal barrier coating, and its response under hot isostatic pressing

    E-Print Network [OSTI]

    Fleck, Norman A.

    and under hot isostatic pressing. It is assumed that the splats of the coating are separated by penny to pancake-shaped polycrystals, termed `splats'. During service the splats of the APS coating sinter together of sintering of an APS coating and to (ii) explore the effect of free sintering and hot isostatic pressing (HIP

  13. Fact Sheet Radiant barriers and interior radiation control

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Radiant Barrier Fact Sheet Overview Radiant barriers and interior radiation control coatings 2 in the map below), radiant barriers could reduce your utility bills by as much as $150 per year load. Contents: Overview · What is a radiant barrier? · What is an interior radiation control coating

  14. Microstructural Evolution of 7 wt.% Y2O3 ZrO2 Thermal Barrier Coatings due to Stress Relaxation at Elevated Temperatures and the Concomitant changes in Thermal Conductivity

    SciTech Connect (OSTI)

    Petorak, Christopher [Purdue University; Ilavsky, Dr. Jan [Argonne National Laboratory (ANL); Wang, Hsin [ORNL; Porter, Wallace D [ORNL; Trice, Rodney [Purdue University

    2010-01-01

    The purpose of this study was to evaluate the combined effect of stress and temperature on the microstructure of air plasma-sprayed 7 wt.% Y{sub 2}O{sub 3}-ZrO{sub 2} thermal barrier coatings, and relate microstructural changes to the thermal conductivity, k{sub th}. To simulate TBC service conditions, stand-alone tubes of YSZ were stress relaxed, starting from a compressive stress of 60 MPa, at temperatures of 1000 C or 1200 C. The duration of the stress relaxation test was either 5 min or 3 h. Detailed scanning electron microscopy (SEM) and Porod's specific surface area (SSA) analysis of small angle neutron scattering (SANS) results were used to determine which void systems, either interlamellar pores or intralamellar cracks, contributed to the observed relaxation of stress in the coatings. SEM investigations revealed closure of intralamellar cracks located perpendicular to the stress direction. For thinner YSZ coatings, SANS measurements indicated a statistically significant reduction in the total SSA and SSA associated with intralamellar cracks after stress relaxation at the times, temperatures, and stress investigated compared to those samples that were exposed to identical times and temperatures, but no stress. The SSA associated with the interlamellar pores was not significantly smaller in YSZ coatings stress relaxed from 60 MPa at 1200 C for 3 h compared to as-sprayed coatings. The thermal conductivity of the coatings was strongly influenced by stress, with increases in kth observed after only 5 min at 60 MPa and 1200 C. Reductions in the total SSA were directly linked to increases in k{sub th}.

  15. Compositional Variations in Vapor Deposited Samarium Zirconate Coatings

    E-Print Network [OSTI]

    Wadley, Haydn

    Compositional Variations in Vapor Deposited Samarium Zirconate Coatings A Thesis Presented temperatures instead have relied on the development of thermal barrier coating (TBC) systems. The thermal barrier coating systems applied to superalloys consist of three layers: (i) an aluminum rich metallic bond

  16. Dense protective coatings, methods for their preparation and coated articles

    DOE Patents [OSTI]

    Tulyani, Sonia; Bhatia, Tania; Smeggil, John G.

    2015-12-29

    A method for depositing a protective coating on a complex shaped substrate includes the steps of: (1) dipping a complex shaped substrate into a slurry to form a base coat thereon, the slurry comprising an aqueous solution, at least one refractory metal oxide, and at least one transient fluid additive present in an amount of about 0.1 percent to 10 percent by weight of the slurry; (2) curing the dipped substrate; (3) dipping the substrate into a precursor solution to form a top barrier coat thereon; and (4) heat treating the dipped, cured substrate to form a protective coating.

  17. Preparation and thermophysical properties of (Sm{sub 1?x}Er{sub x}){sub 2}Ce{sub 2}O{sub 7} oxides for thermal barrier coatings

    SciTech Connect (OSTI)

    Xiaoge, Chen; Shusen, Yang; Hongsong, Zhang; Gang, Li; Zhenjun, Li.; Bo, Ren; Xudan, Dang; Haoming, Zhang; An, Tang

    2014-03-01

    Graphical abstract: - Highlights: • These ceramic materials with fluorite structure were synthesized. • Defect points lead to their lower thermal conductivities. • The lower ionic radius of Er{sup 3+} ion leads to the reduction of thermal expansion coefficient of (Sm{sub 1?x}Er{sub x}){sub 2}Ce{sub 2}O{sub 7} oxides. - Abstract: (Sm{sub 1?x}Er{sub x}){sub 2}Ce{sub 2}O{sub 7} ceramics were synthesized by sol–gel method and sintered at 1600 °C for 10 h in air. The influence of Er{sub 2}O{sub 3}-substitution on the phase structure and thermophysical properties of Sm{sub 2}Ce{sub 2}O{sub 7} was investigated. The phase structures of these ceramics were identified by X-ray diffraction showing that all synthesized ceramics have fluorite-type structure. The measurements for thermophysical properties of these ceramics show that their thermal conductivities and thermal expansion coefficients remarkably decreased through Er-substitution. However, the thermal expansion coefficients were higher than that of YSZ and their thermal conductivities were much lower than that of 8YSZ. The excellent thermophysical property implies that these solid solutions are potential materials for the ceramics layer in thermal barrier coatings.

  18. Vehicle barrier

    DOE Patents [OSTI]

    Hirsh, Robert A. (Bethel Park, PA)

    1991-01-01

    A vehicle security barrier which can be conveniently placed across a gate opening as well as readily removed from the gate opening to allow for easy passage. The security barrier includes a barrier gate in the form of a cable/gate member in combination with laterally attached pipe sections fixed by way of the cable to the gate member and lateral, security fixed vertical pipe posts. The security barrier of the present invention provides for the use of cable restraints across gate openings to provide necessary security while at the same time allowing for quick opening and closing of the gate areas without compromising security.

  19. Deformation Mechanisms in Compression-Loaded, Stand-Alone Plasma-Sprayed Alumina Coatings

    E-Print Network [OSTI]

    Trice, Rodney W.

    Deformation Mechanisms in Compression-Loaded, Stand-Alone Plasma-Sprayed Alumina Coatings Rodney W. It is proposed that the numerous defects in plasma- sprayed coatings, including porosity and microcracks, serve-SPRAYED coatings are frequently used as thermal-barrier coatings (TBCs) or wear-resistant coatings. Mechanical

  20. Hydrogen Permeation Resistant Coatings

    SciTech Connect (OSTI)

    KORINKO, PAUL; ADAMS, THAD; CREECH, GREGGORY

    2005-06-15

    As the National Hydrogen Economy continues to develop and evolve the need for structural materials that can resist hydrogen assisted degradation will become critical. To date austenitic stainless steel materials have been shown to be mildly susceptible to hydrogen attack which results in lower mechanical and fracture strengths. As a result, hydrogen permeation barrier coatings may be applied to these ferrous alloys to retard hydrogen ingress. Hydrogen is known to be very mobile in materials of construction. In this study, the permeation resistance of bare stainless steel samples and coated stainless steel samples was tested. The permeation resistance was measured using a modular permeation rig using a pressure rise technique. The coating microstructure and permeation results will be discussed in this document as will some additional testing.

  1. Process Improvements for Gas Barrier Thin Films Deposited Via Layer-By-Layer Assembly 

    E-Print Network [OSTI]

    Hagen, David Austin

    2015-05-04

    Thin layers of aluminum have provided good oxygen barrier for food packaging for many years, but aluminum coatings can easily crack, are completely opaque, and are not environmentally friendly. One gas barrier solution for food, to flexible...

  2. Corrosion resistant coatings suitable for elevated temperature application

    DOE Patents [OSTI]

    Chan, Kwai S. (San Antonio, TX); Cheruvu, Narayana Sastry (San Antonio, TX); Liang, Wuwei (Austin, TX)

    2012-07-31

    The present invention relates to corrosion resistance coatings suitable for elevated temperature applications, which employ compositions of iron (Fe), chromium (Cr), nickel (Ni) and/or aluminum (Al). The compositions may be configured to regulate the diffusion of metals between a coating and a substrate, which may then influence coating performance, via the formation of an inter-diffusion barrier layer. The inter-diffusion barrier layer may comprise a face-centered cubic phase.

  3. Gaseous modification of MCrAlY coatings

    DOE Patents [OSTI]

    Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

    2000-01-01

    The present invention generally describes methods for modifying MCrAlY coatings by using gaseous carburization, gaseous nitriding or gaseous carbonitriding. The modified MCrAlY coatings are useful in thermal barrier coating systems, which may be used in gas turbine engines.

  4. Computational design and experimental validation of new thermal barrier systems

    SciTech Connect (OSTI)

    Guo, Shengmin

    2015-03-31

    The focus of this project is on the development of a reliable and efficient ab initio based computational high temperature material design method which can be used to assist the Thermal Barrier Coating (TBC) bond-coat and top-coat design. Experimental evaluations on the new TBCs are conducted to confirm the new TBCs’ properties. Southern University is the subcontractor on this project with a focus on the computational simulation method development. We have performed ab initio density functional theory (DFT) method and molecular dynamics simulation on screening the top coats and bond coats for gas turbine thermal barrier coating design and validation applications. For experimental validations, our focus is on the hot corrosion performance of different TBC systems. For example, for one of the top coatings studied, we examined the thermal stability of TaZr2.75O8 and confirmed it’s hot corrosion performance.

  5. Protection of alodine coatings from thermal aging by removable polymer coatings.

    SciTech Connect (OSTI)

    Wagstaff, Brett R. (.); Bradshaw, Robert W.; Whinnery, LeRoy L., Jr. (.,; .)

    2006-12-01

    Removable polymer coatings were evaluated as a means to suppress dehydration of Alodine chromate conversion coatings during thermal aging and thereby retain the corrosion protection afforded by Alodine. Two types of polymer coatings were applied to Alodine-treated panels of aluminum alloys 7075-T73 and 6061-T6 that were subsequently aged for 15 to 50 hours at temperatures between 135 F to 200 F. The corrosion resistance of the thermally aged panels was evaluated, after stripping the polymer coatings, by exposure to a standard salt-fog corrosion test and the extent of pitting of the polymer-coated and untreated panels compared. Removable polymer coatings mitigated the loss of corrosion resistance due to thermal aging experienced by the untreated alloys. An epoxide coating was more effective than a fluorosilicone coating as a dehydration barrier.

  6. The displacement of the thermally grown oxide in thermal barrier systems upon temperature cycling

    E-Print Network [OSTI]

    Hutchinson, John W.

    barrier coatings; Thermal cycling; Oxidation 1. Introduction Thermal barrier systems used in gas turbines, Cambridge, MA 02138, USA c Materials Department, University of California, Santa Barbara, Santa Barbara, CA consistent with the observations whenever the bond coat and TGO both undergo plastic deformation. The TGO

  7. CX-010440: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Reduced Cost Bond Layers for Multi-Layer Thermal/Environmental Barrier Coatings CX(s) Applied: B3.6 Date: 06/21/2013 Location(s): Alabama Offices(s): National Energy Technology Laboratory

  8. CX-010441: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Reduced Cost Bond Layers for Multi-Layer Thermal/Environmental Barrier Coatings CX(s) Applied: B3.6 Date: 06/20/2013 Location(s): Alabama Offices(s): National Energy Technology Laboratory

  9. CX-012457: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Scalable and Cost Effective Barrier Layer Coating to Improve Stability and Performance of SOFC Cathode CX(s) Applied: A9, B3.6Date: 41877 Location(s): IllinoisOffices(s): National Energy Technology Laboratory

  10. CX-012450: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Scalable and Cost Effective Barrier Layer Coating to Improve Stability and Performance of SOFC Cathode CX(s) Applied: A9, B3.6Date: 41877 Location(s): West VirginiaOffices(s): National Energy Technology Laboratory

  11. CX-012451: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Scalable and Cost Effective Barrier Layer Coating to Improve Stability and Performance of SOFC Cathode CX(s) Applied: A9, B3.6Date: 41877 Location(s): ConnecticutOffices(s): National Energy Technology Laboratory

  12. Nematology, 2007, Vol. 9(1), 17-24 Role of the surface coat of Romanomermis culicivorax

    E-Print Network [OSTI]

    , the coat served as a disposable, renewable barrier between parasite and host that was intermittently shed immune system. In summary, shedding of the surface coat is an adaptive counter response by R. culicivorax

  13. Vapor deposition on doublet airfoil substrates: Coating thickness control Theron M. Rodgers, Hengbei Zhao, and Haydn N. G. Wadleya)

    E-Print Network [OSTI]

    Wadley, Haydn

    barrier coatings (TBCs) to gas turbine engine components,1­6 wear-resistant coatings to cutting tools,7Vapor deposition on doublet airfoil substrates: Coating thickness control Theron M. Rodgers to coatings on interior surfaces of the doublet airfoil geometry, which are only accessible through

  14. Edible Coating Development for Fresh-cut Cantaloupe 

    E-Print Network [OSTI]

    Martinon Gaspar, Mauricio

    2012-02-14

    healthy diet. One of the latest alternatives to reduce the decay of quality brought by minimal processing of fruits is the development of edible coatings. Acting as a barrier to moisture and gases, the coatings are expected to extend the shelf...

  15. Metal matrix coated fiber composites and the methods of manufacturing such composites

    DOE Patents [OSTI]

    Weeks, Jr., Joseph K. (Salt Lake City, UT); Gensse, Chantal (Salt Lake City, UT)

    1993-01-01

    A fiber coating which allows ceramic or metal fibers to be wetted by molten metals is disclosed. The coating inhibits degradation of the physical properties caused by chemical reaction between the fiber and the coating itself or between the fiber and the metal matrix. The fiber coating preferably includes at least a wetting layer, and in some applications, a wetting layer and a barrier layer between the fiber and the wetting layer. The wetting layer promotes fiber wetting by the metal matrix. The barrier layer inhibits fiber degradation. The fiber coating permits the fibers to be infiltrated with the metal matrix resulting in composites having unique properties not obtainable in pure materials.

  16. Assessing Process and Coating Reliability Through Monitoring of Process and Design

    E-Print Network [OSTI]

    Nakamura, Toshio

    on design- relevant coating properties were obtained for plasma-sprayed zirconia through recourse to novel barrier coatings, variability, yttria-stabilized zirconia 1. Background Plasma spray is a highly complex) system where new demands in engine performance require coatings to play the role of ``prime reliance

  17. Mechanisms of Ytterbium Monosilicate/Mullite/Silicon Coating Failure During Thermal Cycling in Water Vapor

    E-Print Network [OSTI]

    Wadley, Haydn

    Mechanisms of Ytterbium Monosilicate/Mullite/Silicon Coating Failure During Thermal Cycling barrier coating system on SiC test coupons. Significant differences in the thermal expansion preferentially oxidized the exposed Si bond coat to form b-cristobalite. Simultaneous ingress of the gaseous

  18. High efficiency turbine blade coatings.

    SciTech Connect (OSTI)

    Youchison, Dennis L.; Gallis, Michail A.

    2014-06-01

    The development of advanced thermal barrier coatings (TBCs) of yttria stabilized zirconia (YSZ) that exhibit lower thermal conductivity through better control of electron beam - physical vapor deposition (EB-PVD) processing is of prime interest to both the aerospace and power industries. This report summarizes the work performed under a two-year Lab-Directed Research and Development (LDRD) project (38664) to produce lower thermal conductivity, graded-layer thermal barrier coatings for turbine blades in an effort to increase the efficiency of high temperature gas turbines. This project was sponsored by the Nuclear Fuel Cycle Investment Area. Therefore, particular importance was given to the processing of the large blades required for industrial gas turbines proposed for use in the Brayton cycle of nuclear plants powered by high temperature gas-cooled reactors (HTGRs). During this modest (~1 full-time equivalent (FTE)) project, the processing technology was developed to create graded TBCs by coupling ion beam-assisted deposition (IBAD) with substrate pivoting in the alumina-YSZ system. The Electron Beam - 1200 kW (EB-1200) PVD system was used to deposit a variety of TBC coatings with micron layered microstructures and reduced thermal conductivity below 1.5 W/m.K. The use of IBAD produced fully stoichiometric coatings at a reduced substrate temperature of 600 oC and a reduced oxygen background pressure of 0.1 Pa. IBAD was also used to successfully demonstrate the transitioning of amorphous PVD-deposited alumina to the -phase alumina required as an oxygen diffusion barrier and for good adhesion to the substrate Ni2Al3 bondcoat. This process replaces the time consuming thermally grown oxide formation required before the YSZ deposition. In addition to the process technology, Direct Simulation Monte Carlo plume modeling and spectroscopic characterization of the PVD plumes were performed. The project consisted of five tasks. These included the production of layered periodic microstructures in the coating, the Direct Simulation Monte Carlo (DSMC) modeling of particle transport in the PVD plume, functional graded layer development, the deposition of all layers to form a complete coating, and materials characterization including thermal testing. Ion beam-assisted deposition, beam sharing through advanced digital rastering, substrate pivoting, hearth calorimetry, infrared imaging, fiber optic-enabled optical emission spectroscopy and careful thermal management were used to achieve all the milestones outlined in the FY02 LDRD proposal.

  19. Boron nitride nanosheets as oxygen-atom corrosion protective coatings

    SciTech Connect (OSTI)

    Yi, Min; Shen, Zhigang; Zhao, Xiaohu; Liang, Shuaishuai; Liu, Lei

    2014-04-07

    The research of two-dimensional nanomaterials for anticorrosion applications is just recently burgeoning. Herein, we demonstrate the boron nitride nanosheets (BNNSs) coatings for protecting polymer from oxygen-atom corrosion. High-quality BNNSs, which are produced by an effective fluid dynamics method with multiple exfoliation mechanisms, can be assembled into coatings with controlled thickness by vacuum filtration. After exposed in atom oxygen, the naked polymer is severely corroded with remarkable mass loss, while the BNNSs-coated polymer remains intact. Barrier and bonding effects of the BNNSs are responsible for the coating's protective performance. These preliminary yet reproducible results pave a way for resisting oxygen-atom corrosion.

  20. Puncture detecting barrier materials

    DOE Patents [OSTI]

    Hermes, R.E.; Ramsey, D.R.; Stampfer, J.F.; Macdonald, J.M.

    1998-03-31

    A method and apparatus for continuous real-time monitoring of the integrity of protective barrier materials, particularly protective barriers against toxic, radioactive and biologically hazardous materials has been developed. Conductivity, resistivity or capacitance between conductive layers in the multilayer protective materials is measured by using leads connected to electrically conductive layers in the protective barrier material. The measured conductivity, resistivity or capacitance significantly changes upon a physical breach of the protective barrier material. 4 figs.

  1. Puncture detecting barrier materials

    DOE Patents [OSTI]

    Hermes, Robert E. (Los Alamos, NM); Ramsey, David R. (Bothel, WA); Stampfer, Joseph F. (Santa Fe, NM); Macdonald, John M. (Santa Fe, NM)

    1998-01-01

    A method and apparatus for continuous real-time monitoring of the integrity of protective barrier materials, particularly protective barriers against toxic, radioactive and biologically hazardous materials has been developed. Conductivity, resistivity or capacitance between conductive layers in the multilayer protective materials is measured by using leads connected to electrically conductive layers in the protective barrier material. The measured conductivity, resistivity or capacitance significantly changes upon a physical breach of the protective barrier material.

  2. Development of ZnNiCd coatings by pulse electrodeposition process Prabhu Ganesan, Swaminatha P. Kumaraguru, Branko N. Popov

    E-Print Network [OSTI]

    Popov, Branko N.

    Development of Zn­Ni­Cd coatings by pulse electrodeposition process Prabhu Ganesan, Swaminatha P indicated that Zn­Ni­Cd alloys exhibit superior barrier properties when compared to Cd or Zn­Ni coatings of corrosion resistant coating in aerospace, electrical, and fastener industries due to its excel- lent

  3. Development of an Alginate-based Antimicrobial Edible Coating to Extend the Shelf-life of Fresh-cut Pineapple 

    E-Print Network [OSTI]

    Mantilla, Natalia

    2012-07-16

    and beneficial components of fresh-cut pineapple is coating the fruit with an edible material, a coating. This coating acts as a barrier against moisture loss and gas exchanges and can be a carrier of other components like antimicrobials, which can help to extend...

  4. Corrosion resistant coating

    DOE Patents [OSTI]

    Wrobleski, Debra A. (Los Alamos, NM); Benicewicz, Brian C. (Los Alamos, NM); Thompson, Karen G. (Orlando, FL); Bryan, Coleman J. (Merritt Island, FL)

    1997-01-01

    A method of protecting a metal substrate from corrosion including coating a metal substrate of, e.g., steel, iron or aluminum, with a conductive polymer layer of, e.g., polyaniline, coating upon said metal substrate, and coating the conductive polymer-coated metal substrate with a layer of a topcoat upon the conductive polymer coating layer, is provided, together with the resultant coated article from said method.

  5. Corrosion resistant coating

    DOE Patents [OSTI]

    Wrobleski, D.A.; Benicewicz, B.C.; Thompson, K.G.; Bryan, C.J.

    1997-08-19

    A method of protecting a metal substrate from corrosion including coating a metal substrate of, e.g., steel, iron or aluminum, with a conductive polymer layer of, e.g., polyaniline, coating upon said metal substrate, and coating the conductive polymer-coated metal substrate with a layer of a topcoat upon the conductive polymer coating layer, is provided, together with the resultant coated article from said method.

  6. Silicon Oxynitride Thin Film Barriers for PV Packaging (Poster)

    SciTech Connect (OSTI)

    del Cueto, J. A.; Glick, S. H.; Terwilliger, K. M.; Jorgensen, G. J.; Pankow, J. W.; Keyes, B. M.; Gedvilas, L. M.; Pern, F. J.

    2006-10-03

    Dielectric, adhesion-promoting, moisture barriers comprised of silicon oxynitride thin film materials (SiOxNy with various material stoichiometric compositions x,y) were applied to: 1) bare and pre-coated soda-lime silicate glass (coated with transparent conductive oxide SnO2:F and/or aluminum), and polymer substrates (polyethylene terephthalate, PET, or polyethylene napthalate, PEN); plus 2) pre- deposited photovoltaic (PV) cells and mini-modules consisting of amorphous silicon (a-Si) and copper indium gallium diselenide (CIGS) thin-film PV technologies. We used plasma enhanced chemical vapor deposition (PECVD) process with dilute silane, nitrogen, and nitrous oxide/oxygen gas mixtures in a low-power (< or = 10 milliW per cm2) RF discharge at ~ 0.2 Torr pressure, and low substrate temperatures < or = 100(degrees)C, over deposition areas ~ 1000 cm2. Barrier properties of the resulting PV cells and coated-glass packaging structures were studied with subsequent stressing in damp-heat exposure at 85(degrees)C/85% RH. Preliminary results on PV cells and coated glass indicate the palpable benefits of the barriers in mitigating moisture intrusion and degradation of the underlying structures using SiOxNy coatings with thicknesses in the range of 100-200 nm.

  7. ITP Nanomanufacturing: Nanostructured Superhydrophobic Coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanomanufacturing: Nanostructured Superhydrophobic Coatings ITP Nanomanufacturing: Nanostructured Superhydrophobic Coatings nanostructuredsuperhydrophobiccoatings.pdf More...

  8. Final Technical Report - Recovery Act: Organic Coatings as Encapsulants for Low Cost, High Performance PV Modules

    SciTech Connect (OSTI)

    Stuart Hellring; Jiping Shao; James Poole

    2011-12-05

    The objective of this project was to evaluate the feasibility of utilizing PPG's commercial organic coatings systems as efficient, modernized encapsulants for low cost, high performance, thin film photovoltaic modules. Our hypothesis was that the combination of an anticorrosive coating with a more traditional barrier topcoat would mitigate many electrochemical processes that are now responsible for the significant portion of photovoltaic (PV) failures, thereby nullifying the extremely high moisture barrier requirements of currently used encapsulation technology. Nine commercially available metal primer coatings and six commercially available top coatings were selected for screening. Twenty-one different primer/top coat combinations were evaluated. The primer coatings were shown to be the major contributor to corrosion inhibition, adhesion, and barrier properties. Two primer coatings and one top coating were downselected for testing on specially-fabricated test modules. The coated test modules passed initial current leakage and insulation testing. Damp Heat testing of control modules showed visible corrosion to the bus bar metal, whereas the coated modules showed none. One of the primer/top coat combinations retained solar power performance after Damp Heat testing despite showing some delamination at the EVA/solar cell interface. Thermal Cycling and Humidity Freeze testing resulted in only one test module retaining its power performance. Failure modes depended on the particular primer/top coating combination used. Overall, this study demonstrated that a relatively thin primer/top coating has the potential to replace the potting film and backsheet in crystalline silicon-based photovoltaic modules. Positive signals were received from commercially available coatings developed for applications having performance requirements different from those required for photovoltaic modules. It is likely that future work to redesign and customize these coatings would result in a coating system meeting the requirements for photovoltaic module encapsulation.

  9. Multilayer moisture barrier

    DOE Patents [OSTI]

    Pankow, Joel W; Jorgensen, Gary J; Terwilliger, Kent M; Glick, Stephen H; Isomaki, Nora; Harkonen, Kari; Turkulainen, Tommy

    2015-04-21

    A moisture barrier, device or product having a moisture barrier or a method of fabricating a moisture barrier having at least a polymer layer, and interfacial layer, and a barrier layer. The polymer layer may be fabricated from any suitable polymer including, but not limited to, fluoropolymers such as polyethylene terephthalate (PET) or polyethylene naphthalate (PEN), or ethylene-tetrafluoroethylene (ETFE). The interfacial layer may be formed by atomic layer deposition (ALD). In embodiments featuring an ALD interfacial layer, the deposited interfacial substance may be, but is not limited to, Al.sub.2O.sub.3, AlSiO.sub.x, TiO.sub.2, and an Al.sub.2O.sub.3/TiO.sub.2 laminate. The barrier layer associated with the interfacial layer may be deposited by plasma enhanced chemical vapor deposition (PECVD). The barrier layer may be a SiO.sub.xN.sub.y film.

  10. Hydrogen permeation resistant barrier

    DOE Patents [OSTI]

    McGuire, J.C.; Brehm, W.F.

    1980-02-08

    A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

  11. Electrocurtain coating process for coating solar mirrors

    SciTech Connect (OSTI)

    Kabagambe, Benjamin; Boyd, Donald W.; Buchanan, Michael J.; Kelly, Patrick; Kutilek, Luke A.; McCamy, James W.; McPheron, Douglas A.; Orosz, Gary R.; Limbacher, Raymond D.

    2013-10-15

    An electrically conductive protective coating or film is provided over the surface of a reflective coating of a solar mirror by flowing or directing a cation containing liquid and an anion containing liquid onto the conductive surface. The cation and the anion containing liquids are spaced from, and preferably out of contact with one another on the surface of the reflective coating as an electric current is moved through the anion containing liquid, the conductive surface between the liquids and the cation containing liquid to coat the conductive surface with the electrically conductive coating.

  12. Investigation of damage behavior of thermally sprayed coatings depending on coating thickness

    SciTech Connect (OSTI)

    Crostack, H.A.; Beller, U.

    1995-12-31

    In order to increase the lifetime of components used for diesel engines or gas turbines surfaces are coated by ceramics. In recent years it succeeded in spraying thermal barrier coatings based on zirconia up to a thickness of a few millimeters. A comparison of the damage behavior between yttria partially stabilized zirconia coatings with different thickness will be presented. The coatings are produced by atmospheric plasma spraying. The thickness is varied from 0.5 mm up to 2 mm. In order to characterize the mechanical as well as the damage processes different methods of destructive testing (tensile, bending, and loading test) are applied. Additionally, non-destructive testing methods were used to investigate the damage processes on micro structural level. The results will be discussed according to the microstructure.

  13. Spray Coating of Photoresists

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Spray Coating of Photoresists Revised: 2013-11-07 Source: www.microchemicals.eu sales@microchemicals.eu Spray Coating: Basics and Motivation Spray coating denotes the formation of a resist film via millions of µm-sized resist droplets moving towards the substrate. This coating technique

  14. Flow coating apparatus and method of coating

    DOE Patents [OSTI]

    Hanumanthu, Ramasubrahmaniam; Neyman, Patrick; MacDonald, Niles; Brophy, Brenor; Kopczynski, Kevin; Nair, Wood

    2014-03-11

    Disclosed is a flow coating apparatus, comprising a slot that can dispense a coating material in an approximately uniform manner along a distribution blade that increases uniformity by means of surface tension and transfers the uniform flow of coating material onto an inclined substrate such as for example glass, solar panels, windows or part of an electronic display. Also disclosed is a method of flow coating a substrate using the apparatus such that the substrate is positioned correctly relative to the distribution blade, a pre-wetting step is completed where both the blade and substrate are completed wetted with a pre-wet solution prior to dispensing of the coating material onto the distribution blade from the slot and hence onto the substrate. Thereafter the substrate is removed from the distribution blade and allowed to dry, thereby forming a coating.

  15. Apparatus for coating powders

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Kerns, John A. (Livermore, CA); Alford, Craig S. (Tracy, CA); McKernan, Mark A. (Livermore, CA)

    2000-01-01

    A process and apparatus for coating small particles and fibers. The process involves agitation by vibrating or tumbling the particles or fibers to promote coating uniformly, removing adsorbed gases and static charges from the particles or fibers by an initial plasma cleaning, and coating the particles or fibers with one or more coatings, a first coating being an adhesion coating, and with subsequent coatings being deposited in-situ to prevent contamination at layer interfaces. The first coating is of an adhesion forming element (i.e. W, Zr, Re, Cr, Ti) of a 100-10,000 .ANG. thickness and the second coating or final coating of a multiple (0.1-10 microns) being Cu or Ag, for example for brazing processes, or other desired materials that defines the new surface related properties of the particles. An essential feature of the coating process is the capability to deposit in-situ without interruption to prevent the formation of a contaminated interface that could adversely affect the coating adhesion. The process may include screening of the material to be coated and either continuous or intermittent vibration to prevent agglomeration of the material to be coated.

  16. Mercury Oxidation via Catalytic Barrier Filters Phase II

    SciTech Connect (OSTI)

    Wayne Seames; Michael Mann; Darrin Muggli; Jason Hrdlicka; Carol Horabik

    2007-09-30

    In 2004, the Department of Energy National Energy Technology Laboratory awarded the University of North Dakota a Phase II University Coal Research grant to explore the feasibility of using barrier filters coated with a catalyst to oxidize elemental mercury in coal combustion flue gas streams. Oxidized mercury is substantially easier to remove than elemental mercury. If successful, this technique has the potential to substantially reduce mercury control costs for those installations that already utilize baghouse barrier filters for particulate removal. Completed in 2004, Phase I of this project successfully met its objectives of screening and assessing the possible feasibility of using catalyst coated barrier filters for the oxidation of vapor phase elemental mercury in coal combustion generated flue gas streams. Completed in September 2007, Phase II of this project successfully met its three objectives. First, an effective coating method for a catalytic barrier filter was found. Second, the effects of a simulated flue gas on the catalysts in a bench-scale reactor were determined. Finally, the performance of the best catalyst was assessed using real flue gas generated by a 19 kW research combustor firing each of three separate coal types.

  17. Retractable barrier strip

    DOE Patents [OSTI]

    Marts, Donna J. (Idaho Falls, ID); Barker, Stacey G. (Idaho Falls, ID); Wowczuk, Andrew (Wheeling, WV); Vellenoweth, Thomas E. (Wheeling, WV)

    2002-01-01

    A portable barrier strip having retractable tire-puncture spikes for puncturing a vehicle tire. The tire-puncture spikes have an armed position for puncturing a tire and a retracted position for not puncturing a tire. The strip comprises a plurality of barrier blocks having the tire-puncture spikes removably disposed in a shaft that is rotatably disposed in each barrier block. The plurality of barrier blocks hare hingedly interconnected by complementary hinges integrally formed into the side of each barrier block which allow the strip to be rolled for easy storage and retrieval, but which prevent irregular or back bending of the strip. The shafts of adjacent barrier blocks are pivotally interconnected via a double hinged universal joint to accommodate irregularities in a roadway surface and to transmit torsional motion of the shaft from block to block. A single flexshaft cable is connected to the shaft of an end block to allow a user to selectively cause the shafts of a plurality of adjacently connected barrier blocks to rotate the tire-puncture spikes to the armed position for puncturing a vehicle tire, and to the retracted position for not puncturing the tire. The flexshaft is provided with a resiliently biased retracting mechanism, and a release latch for allowing the spikes to be quickly retracted after the intended vehicle tire is punctured.

  18. Ceramic plasma-sprayed coating of melting crucibles for casting metal fuel slugs

    SciTech Connect (OSTI)

    K.H. Kim; C.T. Lee; C.B. Lee; R.S. Fielding; J.R. Kennedy

    2013-10-01

    Thermal cycling and melt reaction studies of ceramic coatings plasma-sprayed on Nb substrates were carried out to evaluate the performance of barrier coatings for metallic fuel casting applications. Thermal cycling tests of the ceramic plasma-sprayed coatings to 1450 degrees C showed that HfN, TiC, ZrC, and Y2O3 coating had good cycling characteristics with few interconnected cracks even after 20 cycles. Interaction studies by 1550 degrees C melt dipping tests of the plasma-sprayed coatings also indicated that HfN and Y2O3 do not form significant reaction layer between U–20 wt.% Zr melt and the coating layer. Plasma-sprayed Y2O3 coating exhibited the most promising characteristics among HfN, TiC, ZrC, and Y2O3 coating.

  19. Recycler barrier RF buckets

    SciTech Connect (OSTI)

    Bhat, C.M.; /Fermilab

    2011-03-01

    The Recycler Ring at Fermilab uses a barrier rf systems for all of its rf manipulations. In this paper, I will give an overview of historical perspective on barrier rf system, the longitudinal beam dynamics issues, aspects of rf linearization to produce long flat bunches and methods used for emittance measurements of the beam in the RR barrier rf buckets. Current rf manipulation schemes used for antiproton beam stacking and longitudinal momentum mining of the RR beam for the Tevatron collider operation are explained along with their importance in spectacular success of the Tevatron luminosity performance.

  20. An Integrated Study of a Novel Thermal Coating for Nb-Based High Temperature Alloy

    SciTech Connect (OSTI)

    Yang, Shizhong

    2015-01-31

    This report summarizes our recent works of ab initio density functional theory (DFT) method and molecular dynamics (MD) simulation on the interfaces between niobium substrate and coatings at atomic level. Potential oxidation barrier bond coat, Nb?AlC and high entropy alloys, and top coat candidates were synthesized, characterized, and evaluated in our labs. The simulation methods, experimental validation techniques, achievements already reached, students and postdoc training, and future improvement are briefly introduced.

  1. Deposition of Graded Thermal Barrier Coatings for Gas Turbine Blades -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent BondingMeeting | Department|DepartmentalDay 49, 2010 6:00

  2. Workshop Summary Environmental Barrier Coatings for Microturbine and Industrial

    E-Print Network [OSTI]

    Pennycook, Steve

    and reducing emissions of gas turbines for power and combined heat and power generation. However, achievement of the benefits of ceramics for gas turbine engines for both power generation, aerospace, and military

  3. Discrete Element Modeling of Impact Damage on Thermal Barrier Coatings

    E-Print Network [OSTI]

    Minor, Peter Michel

    2013-01-01

    Gas turbine blade constructed of single-crystalline Ni-basedSimplified diagram of a gas turbine, illustrating the di?spraying . . . . . . Gas turbine blade showing significant

  4. Ultra-thin moisture barrier coatings for passive components

    E-Print Network [OSTI]

    Jensen, Robert A. (Robert Allen), 1980-

    2004-01-01

    Polymer Multi-Layer (PML) capacitors have demonstrated excellent performance for numerous power electronics applications, particularly where high temperature stability is required. These capacitors are sensitive to high ...

  5. Retractable barrier strip

    DOE Patents [OSTI]

    Marts, D.J.; Barker, S.G.; McQueen, M.A.

    1996-04-16

    A portable barrier strip is described having retractable tire-puncture means for puncturing a vehicle tire. The tire-puncture means, such as spikes, have an armed position for puncturing a tire and a retracted position for not puncturing a tire. The strip comprises a plurality of barrier blocks having the tire-puncture means removably disposed in a shaft that is rotatably disposed in each barrier block. The shaft removably and pivotally interconnects the plurality of barrier blocks. Actuation cables cause the shaft to rotate the tire-puncture means to the armed position for puncturing a vehicle tire and to the retracted position for not puncturing the tire. Each tire-puncture means is received in a hollow-bed portion of its respective barrier block when in the retracted position. The barrier strip rests in its deployed position and substantially motionless as a tire rolls thereon and over. The strip is rolled up for retrieval, portability, and storage purposes, and extended and unrolled in its deployed position for use. 13 figs.

  6. Method for formation of subsurface barriers using viscous colloids

    DOE Patents [OSTI]

    Apps, J.A.; Persoff, P.; Moridis, G.; Pruess, K.

    1998-11-17

    A method is described for formation of subsurface barriers using viscous liquids where a viscous liquid solidifies at a controlled rate after injection into soil and forms impermeable isolation of the material enclosed within the subsurface barriers. The viscous liquid is selected from the group consisting of polybutenes, polysiloxanes, colloidal silica and modified colloidal silica of which solidification is controlled by gelling, cooling or cross-linking. Solidification timing is controlled by dilution, addition of brines, coating with alumina, stabilization with various agents and by temperature. 17 figs.

  7. Materials Science and Engineering A 490 (2008) 2635 Mechanisms of cracking and delamination within thick thermal barrier

    E-Print Network [OSTI]

    Hutchinson, John W.

    2008-01-01

    that characterizes the susceptibility to delamination of thermal barrier coated (TBC) hot-section aero-turbine. Introduction The maximum temperature capability of thermal barrier systems used in gas turbines is oftenMaterials Science and Engineering A 490 (2008) 26­35 Mechanisms of cracking and delamination within

  8. SH Coatings LP

    Office of Energy Efficiency and Renewable Energy (EERE)

    SH Coatings, based in Dallas, Texas, employs Super Hydrophobic Coating (SHC) technology that protects power systems by preventing ice accumulation on power lines in ice storm threatened areas and contamination of power lines from salt on the coasts. In order to successfully utilize and commercialize the SHC technology for this application, tools to apply the coating onto new and existing lines must be developed. SH Coatings is developing these tools with the help of technology from Oak Ridge National Laboratory.

  9. Spin Coating of Photoresists

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Spin Coating of Photoresists Revised: 2009-11-05 Source: www.microchemicals.eu e-Mail: sales@microchemicals.eu Basics of Spin Coating During spincoating, the centrifugal force the substrate. Advantages: The high resist film thickness homogeneity as well as the short coating times make

  10. Coated Conductor Technology Development

    E-Print Network [OSTI]

    Coated Conductor Technology Development Roadmap Priority Research & Development Activities Leading for Electric Systems Program Prepared by: Energetics, Incorporated #12;Coated Conductor Development Roadmap of high-quality, low-cost coated conductors that will lead to industrial-scale commercial manufacturing

  11. Vacuum barrier for excimer lasers

    DOE Patents [OSTI]

    Shurter, R.P.

    1992-09-15

    A barrier for separating the vacuum area of a diode from the pressurized gas area of an excimer laser. The barrier is a composite material comprising layers of a metal such as copper, along with layers of polyimide, and a matrix of graphite fiber yarns impregnated with epoxy. The barrier is stronger than conventional foil barriers, and allows greater electron throughput. 3 figs.

  12. Vacuum barrier for excimer lasers

    DOE Patents [OSTI]

    Shurter, Roger P. (Jemez Springs, NM)

    1992-01-01

    A barrier for separating the vacuum area of a diode from the pressurized gas area of an excimer laser. The barrier is a composite material comprising layers of a metal such as copper, along with layers of polyimide, and a matrix of graphite fiber yarns impregnated with epoxy. The barrier is stronger than conventional foil barriers, and allows greater electron throughput.

  13. Antibacterial polymer coatings.

    SciTech Connect (OSTI)

    Wilson, Mollye C.; Allen, Ashley N.; Barnhart, Meghan; Tucker, Mark David; Hibbs, Michael R.

    2009-09-01

    A series of poly(sulfone)s with quaternary ammonium groups and another series with aldehyde groups are synthesized and tested for biocidal activity against vegetative bacteria and spores, respectively. The polymers are sprayed onto substrates as coatings which are then exposed to aqueous suspensions of organisms. The coatings are inherently biocidal and do not release any agents into the environment. The coatings adhere well to both glass and CARC-coated coupons and they exhibit significant biotoxicity. The most effective quaternary ammonium polymers kills 99.9% of both gram negative and gram positive bacteria and the best aldehyde coating kills 81% of the spores on its surface.

  14. Computational Design and Experimental Validation of New Thermal Barrier Systems

    SciTech Connect (OSTI)

    Guo, Shengmin; Yang, Shizhong; Khosravi, Ebrahim

    2012-10-01

    This project (10/01/2010-9/30/2013), “Computational Design and Experimental Validation of New Thermal Barrier Systems”, originates from Louisiana State University (LSU) Mechanical Engineering Department and Southern University (SU) Department of Computer Science. This project will directly support the technical goals specified in DEFOA- 0000248, Topic Area 3: Turbine Materials, by addressing key technologies needed to enable the development of advanced turbines and turbine-based systems that will operate safely and efficiently using coal-derived synthesis gases. We will develop and implement novel molecular dynamics method to improve the efficiency of simulation on novel TBC materials; perform high performance computing (HPC) on complex TBC structures to screen the most promising TBC compositions; perform material characterizations and oxidation/corrosion tests; and demonstrate our new thermal barrier coating (TBC) systems experimentally under integrated gasification combined cycle (IGCC) environments. The durability of the coating will be examined using the proposed Durability Test Rig.

  15. Micro heat barrier

    DOE Patents [OSTI]

    Marshall, Albert C.; Kravitz, Stanley H.; Tigges, Chris P.; Vawter, Gregory A.

    2003-08-12

    A highly effective, micron-scale micro heat barrier structure and process for manufacturing a micro heat barrier based on semiconductor and/or MEMS fabrication techniques. The micro heat barrier has an array of non-metallic, freestanding microsupports with a height less than 100 microns, attached to a substrate. An infrared reflective membrane (e.g., 1 micron gold) can be supported by the array of microsupports to provide radiation shielding. The micro heat barrier can be evacuated to eliminate gas phase heat conduction and convection. Semi-isotropic, reactive ion plasma etching can be used to create a microspike having a cusp-like shape with a sharp, pointed tip (<0.1 micron), to minimize the tip's contact area. A heat source can be placed directly on the microspikes. The micro heat barrier can have an apparent thermal conductivity in the range of 10.sup.-6 to 10.sup.-7 W/m-K. Multiple layers of reflective membranes can be used to increase thermal resistance.

  16. DEVELOPMENT AND ASSESSMENT OF COATINGS FOR FUTURE POWER GENERATION TURBINES

    SciTech Connect (OSTI)

    Alvin, Maryanne; Klotz, K.; McMordie, B.; Gleeson, B.; Zhu, D.; Warnes, B.; Kang, B.; Tannenbaum, J.

    2012-01-01

    The NETL-Regional University Alliance (RUA) continues to advance technology development critical to turbine manufacturer efforts for achieving DOE Fossil Energy (FE's) Advanced Turbine Program Goals. In conjunction with NETL, Coatings for Industry (CFI), the University of Pittsburgh, NASA GRC, and Corrosion Control Inc., efforts have been focused on development of composite thermal barrier coating (TBC) architectures that consist of an extreme temperature coating, a commercially applied 7-8 YSZ TBC, a reduced cost bond coat, and a diffusion barrier coating that are applied to nickel-based superalloys or single crystal airfoil substrate materials for use at temperatures >1450 C (> 2640 F). Additionally, construction of a unique, high temperature ({approx}1100 C; {approx}2010 F), bench-scale, micro-indentation, nondestructive (NDE) test facility at West Virginia University (WVU) was completed to experimentally address in-situ changes in TBC stiffness during extended cyclic oxidation exposure of coated single crystal coupons in air or steam containing environments. The efforts and technical accomplishments in these areas are presented in the following sections of this paper.

  17. Metal matrix coated fiber composites and the methods of manufacturing such composites

    DOE Patents [OSTI]

    Weeks, J.K. Jr.; Gensse, C.

    1993-09-14

    A fiber coating which allows ceramic or metal fibers to be wetted by molten metals is disclosed. The coating inhibits degradation of the physical properties caused by chemical reaction between the fiber and the coating itself or between the fiber and the metal matrix. The fiber coating preferably includes at least a wetting layer, and in some applications, a wetting layer and a barrier layer between the fiber and the wetting layer. The wetting layer promotes fiber wetting by the metal matrix. The barrier layer inhibits fiber degradation. The fiber coating permits the fibers to be infiltrated with the metal matrix resulting in composites having unique properties not obtainable in pure materials. 8 figures.

  18. OVERLAY COATINGS FOR GAS TURBINE AIRFOILS

    E-Print Network [OSTI]

    Boone, Donald H.

    2013-01-01

    NASA, "Refinement of Promising Coating Compositions forG. W. Goward, "Protective Coatings for High TemperatureLS No. 106, Materials Coating Techniques." OVERLAY COATINGS

  19. Materials Science and Engineering A 394 (2005) 4352 NiAl bond coats made by a directed vapor deposition approach

    E-Print Network [OSTI]

    Wadley, Haydn

    2005-01-01

    Materials Science and Engineering A 394 (2005) 43­52 NiAl bond coats made by a directed vapor materials in thermal barrier coating systems applied to nickel base super alloy components. They are usually to nickel base su- peralloy components used in gas turbine engines [1]. In these systems, a metallic bond

  20. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

    2003-10-14

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  1. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

    2004-08-31

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  2. Zinc phosphate conversion coatings

    DOE Patents [OSTI]

    Sugama, Toshifumi (Wading River, NY)

    1997-01-01

    Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate .alpha.-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal.

  3. Zinc phosphate conversion coatings

    DOE Patents [OSTI]

    Sugama, T.

    1997-02-18

    Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate {alpha}-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal. 33 figs.

  4. Proceedings of the 1987 coatings for advanced heat engines workshop

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    This Workshop was conducted to enhance communication among those involved in coating development for improved heat engine performance and durability. We were fortunate to have Bill Goward review the steady progress and problems encountered along the way in the use of thermal barrier coatings (TBC) in aircraft gas turbine engines. Navy contractors discussed their work toward the elusive goal of qualifying TBC for turbine airfoil applications. In the diesel community, Caterpillar and Cummins are developing TBC for combustion chamber components as part of the low heat rejection diesel engine concept. The diesel engine TBC work is based on gas turbine technology with a goal of more than twice the thickness used on gas turbine engine components. Adoption of TBC in production for diesel engines could justify a new generation of plasma spray coating equipment. Increasing interests in tribology were evident in this Workshop. Coatings have a significant role in reducing friction and wear under greater mechanical loadings at higher temperatures. The emergence of a high temperature synthetic lubricant could have an enormous impact on diesel engine design and operating conditions. The proven coating processes such as plasma spray, electron-beam physical vapor deposition, sputtering, and chemical vapor deposition have shown enhanced capabilities, particularly with microprocessor controls. Also, the newer coating schemes such as ion implantation and cathodic arc are demonstrating intriguing potential for engine applications. Coatings will play an expanding role in higher efficiency, more durable heat engines.

  5. Underground waste barrier structure

    DOE Patents [OSTI]

    Saha, Anuj J. (Hamburg, NY); Grant, David C. (Gibsonia, PA)

    1988-01-01

    Disclosed is an underground waste barrier structure that consists of waste material, a first container formed of activated carbonaceous material enclosing the waste material, a second container formed of zeolite enclosing the first container, and clay covering the second container. The underground waste barrier structure is constructed by forming a recessed area within the earth, lining the recessed area with a layer of clay, lining the clay with a layer of zeolite, lining the zeolite with a layer of activated carbonaceous material, placing the waste material within the lined recessed area, forming a ceiling over the waste material of a layer of activated carbonaceous material, a layer of zeolite, and a layer of clay, the layers in the ceiling cojoining with the respective layers forming the walls of the structure, and finally, covering the ceiling with earth.

  6. Barrier breaching device

    DOE Patents [OSTI]

    Honodel, C.A.

    1983-06-01

    A barrier breaching device that is designed primarily for opening holes in interior walls of buildings uses detonating fuse for explosive force. The fuse acts as the ribs or spokes of an umbrella-like device that may be opened up to form a cone. The cone is placed against the wall so that detonating fuse that rings the base of the device and which is ignited by the spoke-like fuses serves to cut a circular hole in the wall.

  7. Coatings and films derived from clay/wax nanocomposites

    DOE Patents [OSTI]

    Chaiko, David J.; Leyva, Argentina A.

    2006-11-14

    The invention provides methods for making clay/wax nanocomposites and coatings and films of same with improved chemical resistance and gas barrier properties. The invention further provides methods for making and using emulsions of such clay/wax nanocomposites. Typically, an organophillic clay is combined with a wax or wax/polymer blend such that the cohesion energy of the clay matches that of the wax or wax/polymer blend. Suitable organophilic clays include mica and phyllosilicates that have been surface-treated with edge or edge and surface modifying agents. The resulting nanocomposites have applications as industrial coatings and in protective packaging.

  8. Silicon nitride protective coatings for silvered glass mirrors

    DOE Patents [OSTI]

    Tracy, C.E.; Benson, D.K.

    1984-07-20

    A protective diffusion barrier for metalized mirror structures is provided by a layer or coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate prior to metal deposition thereon to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors.

  9. Improvements in Processing and Stretchability of Super Gas Barrier Multilayer Thin Films 

    E-Print Network [OSTI]

    Xiang, Fangming

    2015-03-31

    parameter. A 7-bilayer PEI/PAA thin film assembled using optimized spraying parameters exhibited better gas barrier than a dip-coated multilayer prepared using the same deposition time for each layer. These findings pave the way for using the LbL technique...

  10. Blue Coat Systems, Inc. Blue Coat Systems, Software Cryptographic Module

    E-Print Network [OSTI]

    Blue Coat Systems, Inc. Blue Coat Systems, Software Cryptographic Module SW Version: 1.0 FIPS 140: Blue Coat Systems, Inc. Corsec Security, Inc. 420 N. Mary Avenue Sunnyvale, CA 94085 United States://www.corsec.com #12;Security Policy, Version 1.9 April 24, 2014 Blue Coat Systems, Software Cryptographic Module Page

  11. Thermal Performance Evaluation of Attic Radiant Barrier Systems Using the Large Scale Climate Simulator (LSCS)

    SciTech Connect (OSTI)

    Shrestha, Som S [ORNL] [ORNL; Miller, William A [ORNL] [ORNL; Desjarlais, Andre Omer [ORNL] [ORNL

    2013-01-01

    Application of radiant barriers and low-emittance surface coatings in residential building attics can significantly reduce conditioning loads from heat flow through attic floors. The roofing industry has been developing and using various radiant barrier systems and low-emittance surface coatings to increase energy efficiency in buildings; however, minimal data are available that quantifies the effectiveness of these technologies. This study evaluates performance of various attic radiant barrier systems under simulated summer daytime conditions and nighttime or low solar gain daytime winter conditions using the large scale climate simulator (LSCS). The four attic configurations that were evaluated are 1) no radiant barrier (control), 2) perforated low-e foil laminated oriented strand board (OSB) deck, 3) low-e foil stapled on rafters, and 4) liquid applied low-emittance coating on roof deck and rafters. All test attics used nominal RUS 13 h-ft2- F/Btu (RSI 2.29 m2-K/W) fiberglass batt insulation on attic floor. Results indicate that the three systems with radiant barriers had heat flows through the attic floor during summer daytime condition that were 33%, 50%, and 19% lower than the control, respectively.

  12. Dip Coating C. Jeffrey Brinker

    E-Print Network [OSTI]

    Brinker, C. Jeffrey

    Chapter 10 Dip Coating C. Jeffrey Brinker 10.1 Introduction Among the various wet chemical thin film deposition methods dip coating represents the oldest commercially applied coating process-gel derived silica films [1]. Nowadays sol-gel [2] or more general CSD derived coatings are being studied

  13. Performing a local barrier operation

    DOE Patents [OSTI]

    Archer, Charles J; Blocksome, Michael A; Ratterman, Joseph D; Smith, Brian E

    2014-03-04

    Performing a local barrier operation with parallel tasks executing on a compute node including, for each task: retrieving a present value of a counter; calculating, in dependence upon the present value of the counter and a total number of tasks performing the local barrier operation, a base value, the base value representing the counter's value prior to any task joining the local barrier; calculating, in dependence upon the base value and the total number of tasks performing the local barrier operation, a target value of the counter, the target value representing the counter's value when all tasks have joined the local barrier; joining the local barrier, including atomically incrementing the value of the counter; and repetitively, until the present value of the counter is no less than the target value of the counter: retrieving the present value of the counter and determining whether the present value equals the target value.

  14. Performing a local barrier operation

    DOE Patents [OSTI]

    Archer, Charles J; Blocksome, Michael A; Ratterman, Joseph D; Smith, Brian E

    2014-03-04

    Performing a local barrier operation with parallel tasks executing on a compute node including, for each task: retrieving a present value of a counter; calculating, in dependence upon the present value of the counter and a total number of tasks performing the local barrier operation, a base value of the counter, the base value representing the counter's value prior to any task joining the local barrier; calculating, in dependence upon the base value and the total number of tasks performing the local barrier operation, a target value, the target value representing the counter's value when all tasks have joined the local barrier; joining the local barrier, including atomically incrementing the value of the counter; and repetitively, until the present value of the counter is no less than the target value of the counter: retrieving the present value of the counter and determining whether the present value equals the target value.

  15. Friction surfaced Stellite6 coatings

    SciTech Connect (OSTI)

    Rao, K. Prasad; Damodaram, R.; Rafi, H. Khalid; Ram, G.D. Janaki; Reddy, G. Madhusudhan; Nagalakshmi, R.

    2012-08-15

    Solid state Stellite6 coatings were deposited on steel substrate by friction surfacing and compared with Stellite6 cast rod and coatings deposited by gas tungsten arc and plasma transferred arc welding processes. Friction surfaced coatings exhibited finer and uniformly distributed carbides and were characterized by the absence of solidification structure and compositional homogeneity compared to cast rod, gas tungsten arc and plasma transferred coatings. Friction surfaced coating showed relatively higher hardness. X-ray diffraction of samples showed only face centered cubic Co peaks while cold worked coating showed hexagonally close packed Co also. - Highlights: Black-Right-Pointing-Pointer Stellite6 used as coating material for friction surfacing. Black-Right-Pointing-Pointer Friction surfaced (FS) coatings compared with casting, GTA and PTA processes. Black-Right-Pointing-Pointer Finer and uniformly distributed carbides in friction surfaced coatings. Black-Right-Pointing-Pointer Absence of melting results compositional homogeneity in FS Stellite6 coatings.

  16. Aluminum phosphate coatings

    DOE Patents [OSTI]

    Sambasivan, Sankar (Chicago, IL); Steiner, Kimberly A. (Chicago, IL); Rangan, Krishnaswamy K. (Evanston, IL)

    2007-12-25

    Aluminophosphate compounds and compositions as can be used for substrate or composite films and coating to provide or enhance, without limitation, planarization, anti-biofouling and/or anti-microbial properties.

  17. Vanadium Carbide Coating Process

    Broader source: Energy.gov [DOE]

    Traditional methods of coating steel surfaces with a layer of hard metal carbide require large capital investment, produce toxic and hazardous gases, are costly to operate, and require multiple...

  18. Multilayer optical dielectric coating

    DOE Patents [OSTI]

    Emmett, John L. (Pleasanton, CA)

    1990-01-01

    A highly damage resistant, multilayer, optical reflective coating includes alternating layers of doped and undoped dielectric material. The doping levels are low enough that there are no distinct interfaces between the doped and undoped layers so that the coating has properties nearly identical to the undoped material. The coating is fabricated at high temperature with plasma-assisted chemical vapor deposition techniques to eliminate defects, reduce energy-absorption sites, and maintain proper chemical stoichiometry. A number of differently-doped layer pairs, each layer having a thickness equal to one-quarter of a predetermined wavelength in the material are combined to form a narrowband reflective coating for a predetermined wavelength. Broadband reflectors are made by using a number of narrowband reflectors, each covering a portion of the broadband.

  19. SuperhydrophobicCoatings.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    properties as seen in Figure 3, where a water droplet is measured to have a 172 o contact angle, . Importantly, this superhydrophobic coating process can be applied to any...

  20. ORNL Radiant Barrier - ETSD Division

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ETSD Division EES Directorate ORNL Building Technologies Research and Integration Center Energy and Transportation Science Division Overview How do radiation barriers save energy?...

  1. Spin coating apparatus

    DOE Patents [OSTI]

    Torczynski, John R. (Albuquerque, NM)

    2000-01-01

    A spin coating apparatus requires less cleanroom air flow than prior spin coating apparatus to minimize cleanroom contamination. A shaped exhaust duct from the spin coater maintains process quality while requiring reduced cleanroom air flow. The exhaust duct can decrease in cross section as it extends from the wafer, minimizing eddy formation. The exhaust duct can conform to entrainment streamlines to minimize eddy formation and reduce interprocess contamination at minimal cleanroom air flow rates.

  2. Ceramic electrolyte coating methods

    DOE Patents [OSTI]

    Seabaugh, Matthew M.; Swartz, Scott L.; Dawson, William J.; McCormick, Buddy E.

    2004-10-12

    Processes for preparing aqueous suspensions of a nanoscale ceramic electrolyte material such as yttrium-stabilized zirconia. The invention also includes a process for preparing an aqueous coating slurry of a nanoscale ceramic electrolyte material. The invention further includes a process for depositing an aqueous spray coating slurry including a ceramic electrolyte material on pre-sintered, partially sintered, and unsintered ceramic substrates and products made by this process.

  3. On The Oxidation Behavior of Titanium within Coated Nickel-Based Superalloys

    E-Print Network [OSTI]

    Bennett, R. J.; Krakow, R.; Eggeman, A. S.; Jones, C. N.; Murakami, H.; Rae, C. M. F.

    2015-04-22

    combustion temperatures in commercial gas turbines make thermal barrier coatings a necessity for both turbine blades and static vanes operating in the first stage of the turbine. Thus increasing the longevity of these coatings, limited by TBC spallation... ;47:780. [31] He Y, Jonas JJ. J Appl Cryst 2007;40:559. [32] Zhang Y, Haynes JA, Pint BA, Wright IG, Lee WY. Surf Coat Technol 2003;163- 164:19–24. [33] Chen MW, Glynn ML, Ott RT, Hufnagel TC, Hemker KJ. Acta Mater 2003;51:4279. 20 [34] Morawiec, A. J...

  4. Computational Design and Experimental Validation of New Thermal Barrier Systems

    SciTech Connect (OSTI)

    Guo, Shengmin; Yang, Shizhong; Khosravi, Ebrahim

    2014-04-01

    This project (10/01/2010-9/30/2014), “Computational Design and Experimental Validation of New Thermal Barrier Systems”, originates from Louisiana State University (LSU) Mechanical Engineering Department and Southern University (SU) Department of Computer Science. This project will directly support the technical goals specified in DE-FOA-0000248, Topic Area 3: Turbine Materials, by addressing key technologies needed to enable the development of advanced turbines and turbine-based systems that will operate safely and efficiently using coal-derived synthesis gases. In this project, the focus is to develop and implement novel molecular dynamics method to improve the efficiency of simulation on novel TBC materials; perform high performance computing (HPC) on complex TBC structures to screen the most promising TBC compositions; perform material characterizations and oxidation/corrosion tests; and demonstrate our new thermal barrier coating (TBC) systems experimentally under integrated gasification combined cycle (IGCC) environments.

  5. Conductive Carbon Coatings for Electrode Materials

    E-Print Network [OSTI]

    Doeff, Marca M.; Kostecki, Robert; Wilcox, James; Lau, Grace

    2007-01-01

    Raman spectrum of the carbon coating. Deconvoluted peaksConductive Carbon Coatings for Electrode Materials Marca M.for optimizing the carbon coatings on non-conductive battery

  6. Sol-Gel Deposited Electrochromic Coatings

    E-Print Network [OSTI]

    Ozer, N.

    2010-01-01

    Deposited Electrochromic Coatings Nilgun Ozer and Carl M.the Optical Interference Coatings Topical Meeting, Tucson,Deposited Electrochromic Coatings Nilgun Ozer and Carl M.

  7. Dynamically Responsive Infrared Window Coatings | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Window Coatings Dynamically Responsive Infrared Window Coatings 1 of 5 An oxygen plasma etcher is used to clean test substrates for window coatings. Image: Pacific Northwest...

  8. A Review of Tribological Coatings for Control Drive Mechanisms in Space Reactors

    SciTech Connect (OSTI)

    CJ Larkin; JD Edington; BJ Close

    2006-02-21

    Tribological coatings must provide lubrication for moving components of the control drive mechanism for a space reactor and prevent seizing due to friction or diffusion welding to provide highly reliable and precise control of reflector position over the mission lifetime. Several coatings were evaluated based on tribological performance at elevated temperatures and in ultrahigh vacuum environments. Candidates with proven performance in the anticipated environment are limited primarily to disulfide materials. Irradiation data for these coatings is nonexistent. Compatibility issues between coating materials and structural components may require the use of barrier layers between the solid lubricant and structural components to prevent deleterious interactions. It would be advisable to consider possible lubricant interactions prior to down-selection of structural materials. A battery of tests was proposed to provide the necessary data for eventual solid lubricant/coating selection.

  9. Sandia Energy - Siting and Barrier Mitigation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Siting and Barrier Mitigation Home Stationary Power Energy Conversion Efficiency Wind Energy Siting and Barrier Mitigation Siting and Barrier MitigationTara Camacho-Lopez2015-08-12...

  10. CX-010296: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Thermal Barrier Coatings for the LTC Engine – Heat Loss, Combustion, Thermal vs. Catalytic Effects CX(s) Applied: A9, B3.6 Date: 05/03/2013 Location(s): California, South Carolina, Connecticut Offices(s): National Energy Technology Laboratory

  11. Preparation of hydrophobic coatings

    DOE Patents [OSTI]

    Branson, Eric D. (Albuquerque, NM); Shah, Pratik B. (Albuquerque, NM); Singh, Seema (Rio Rancho, NM); Brinker, C. Jeffrey (Albuquerque, NM)

    2009-02-03

    A method for preparing a hydrophobic coating by preparing a precursor sol comprising a metal alkoxide, a solvent, a basic catalyst, a fluoroalkyl compound and water, depositing the precursor sol as a film onto a surface, such as a substrate or a pipe, heating, the film and exposing the film to a hydrophobic silane compound to form a hydrophobic coating with a contact angle greater than approximately 150.degree.. The contact angle of the film can be controlled by exposure to ultraviolet radiation to reduce the contact angle and subsequent exposure to a hydrophobic silane compound to increase the contact angle.

  12. Coating of a stainless steel tube-wall catalytic reactor with thermally treated polysiloxane thick films

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Coating of a stainless steel tube-wall catalytic reactor with thermally treated polysiloxane thick stainless steel by plasma assisted chemical vapour deposition process. Thicknesses up to 10µm were developed barrier. Key-words: PACVD, TDMS, stainless steel, surface passivity. 1. Introduction The use of tube

  13. Manufacturing Barriers to High Temperature PEM Commercialization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Barriers to High Temperature PEM Commercialization Manufacturing Barriers to High Temperature PEM Commercialization Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D...

  14. Permeable Reactive Barriers | Department of Energy

    Office of Environmental Management (EM)

    reaction occurs with the barrier material that results in adsorption, mineral precipitation, or degradation to a harmless compound. Reactive barriers that do not incorporate...

  15. OVERLAY COATINGS FOR GAS TURBINE AIRFOILS

    E-Print Network [OSTI]

    Boone, Donald H.

    2013-01-01

    Materials Coating Techniques." OVERLAY COATINGS FOR GAS TURBINEGas Turbine Coatings for Minimally Processed Coal Derived Liquid Fuels," presented at the Conference on Advanced MaterialsCoating Technology and Processing Capabilities,'' proceedings 3rd Conference on Gas Turbine Materials

  16. Vehicle barrier with access delay

    DOE Patents [OSTI]

    Swahlan, David J; Wilke, Jason

    2013-09-03

    An access delay vehicle barrier for stopping unauthorized entry into secure areas by a vehicle ramming attack includes access delay features for preventing and/or delaying an adversary from defeating or compromising the barrier. A horizontally deployed barrier member can include an exterior steel casing, an interior steel reinforcing member and access delay members disposed within the casing and between the casing and the interior reinforcing member. Access delay members can include wooden structural lumber, concrete and/or polymeric members that in combination with the exterior casing and interior reinforcing member act cooperatively to impair an adversarial attach by thermal, mechanical and/or explosive tools.

  17. Large Area Vacuum Deposited Coatings

    SciTech Connect (OSTI)

    Martin, Peter M.

    2003-04-30

    It's easy to make the myriad of types of large area and decorative coatings for granted. We probably don't even think about most of them; the low-e and heat mirror coatings on our windows and car windows, the mirrors in displays, antireflection coatings on windows and displays, protective coatings on aircraft windows, heater coatings on windshields and aircraft windows, solar reflectors, thin film solar cells, telescope mirrors, Hubble mirrors, transparent conductive coatings, and the list goes on. All these products require large deposition systems and chambers. Also, don't forget that large batches of small substrates or parts are coated in large chambers. In order to be cost effective hundreds of ophthalmic lenses, automobile reflectors, display screens, lamp reflectors, cell phone windows, laser reflectors, DWDM filters, are coated in batches.

  18. ITP Nanomanufacturing: Nanostructured Superhydrophobic Coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanostructured Superhydrophobic Coatings Large-scale Implementation of Nanostructured Superhydrophobic (SH) Powders for Breakthrough Energy Savings Nanostructured superhydrophobic...

  19. Graphene Coating Coupled Emission

    E-Print Network [OSTI]

    Shyamasundar, R.K.

    Graphene Coating Coupled Emission A COMSET, A single sheet of sp2-hybridized carbon atoms, called of graphene and its unique properties, I will present amplification of surface graphene-Ag hybrid films which when graphene is used as the spacer layer in a conventional Ag- harnessed the nonlinear properties

  20. Biodegradation of polymer coatings

    SciTech Connect (OSTI)

    Jones, W.R.; Walch, M.; Jones-Meehan, J.

    1994-12-31

    Conventional paint removal methods include chemical stripping with VOCs blasting with plastic media, and delamination with high pressure water. These methods have many limitations, in that they are labor intensive, pose human health risks, are relatively expensive and pose significant waste disposal problems. However, polymeric coatings are known to contain structural components, such as ester, amide and urea linkages, that can be degraded biologically. The authors are working to develop a stable, enzyme-based, non-toxic paint stripping strategy that will be environmentally safe and cost effective. The specific objectives are to identify and characterize microbial systems capable of degrading polymeric coatings, to develop a quantitative degradation assay and to optimize activity levels for subsequent purification and concentration of the biological products required for rapid degradation of coatings. A water-dispersed colloid of an ester-based polyurethane polymer has been used in solid growth medium to screen about 100 different bacteria for microbial degradation activity. Those with demonstrable activity have been grown in the presence of epoxy-polyamide paint- and polyester polyurethane paint-coated aluminum coupons. The authors have demonstrated delamination under certain conditions and have developed a spectrophotometric method for quantitating degradation activity as a function of dye release.

  1. Relativistic tunneling through opaque barriers

    SciTech Connect (OSTI)

    De Leo, Stefano; Leonardi, Vinicius [Department of Applied Mathematics, State University of Campinas, SP 13083-970, Campinas (Brazil)

    2011-02-15

    We propose an analytical study of relativistic tunneling through opaque barriers. We obtain a closed formula for the phase time. This formula is in excellent agreement with the numerical simulations and corrects the standard formula obtained by the stationary phase method. An important result is found when the upper limit of the incoming energy distribution coincides with the upper limit of the tunneling zone. In this case, the phase time is proportional to the barrier width.

  2. Low friction and galling resistant coatings and processes for coating

    DOE Patents [OSTI]

    Johnson, Roger N. (Richland, WA)

    1987-01-01

    The present invention describes coating processes and the resultant coated articles for use in high temperature sodium environments, such as those found in liquid metal fast breeder reactors and their associated systems. The substrate to which the coating is applied may be either an iron base or nickel base alloy. The coating itself is applied to the substrate by electro-spark deposition techniques which result in metallurgical bonding between the coating and the substrate. One coating according to the present invention involves electro-spark depositing material from a cemented chromium carbide electrode and an aluminum electrode. Another coating according to the present invention involves electro-spark depositing material from a cemented chromium carbide electrode and a nickel-base hardfacing alloy electrode.

  3. Computational Design and Experimental Validation of New Thermal Barrier Systems

    SciTech Connect (OSTI)

    Guo, Shengmin; Yang, Shizhong; Khosravi, Ebrahim

    2011-12-31

    This project (10/01/2010-9/30/2013), “Computational Design and Experimental Validation of New Thermal Barrier Systems”, originates from Louisiana State University (LSU) Mechanical Engineering Department and Southern University (SU) Department of Computer Science. This proposal will directly support the technical goals specified in DE-FOA-0000248, Topic Area 3: Turbine Materials, by addressing key technologies needed to enable the development of advanced turbines and turbine-based systems that will operate safely and efficiently using coal-derived synthesis gases. We will develop novel molecular dynamics method to improve the efficiency of simulation on novel TBC materials; we will perform high performance computing (HPC) on complex TBC structures to screen the most promising TBC compositions; we will perform material characterizations and oxidation/corrosion tests; and we will demonstrate our new Thermal barrier coating (TBC) systems experimentally under Integrated gasification combined cycle (IGCC) environments. The durability of the coating will be examined using the proposed High Temperature/High Pressure Durability Test Rig under real syngas product compositions.

  4. Global interrupt and barrier networks

    DOE Patents [OSTI]

    Blumrich, Matthias A. (Ridgefield, CT); Chen, Dong (Croton-On-Hudson, NY); Coteus, Paul W. (Yorktown Heights, NY); Gara, Alan G. (Mount Kisco, NY); Giampapa, Mark E (Irvington, NY); Heidelberger, Philip (Cortlandt Manor, NY); Kopcsay, Gerard V. (Yorktown Heights, NY); Steinmacher-Burow, Burkhard D. (Mount Kisco, NY); Takken, Todd E. (Mount Kisco, NY)

    2008-10-28

    A system and method for generating global asynchronous signals in a computing structure. Particularly, a global interrupt and barrier network is implemented that implements logic for generating global interrupt and barrier signals for controlling global asynchronous operations performed by processing elements at selected processing nodes of a computing structure in accordance with a processing algorithm; and includes the physical interconnecting of the processing nodes for communicating the global interrupt and barrier signals to the elements via low-latency paths. The global asynchronous signals respectively initiate interrupt and barrier operations at the processing nodes at times selected for optimizing performance of the processing algorithms. In one embodiment, the global interrupt and barrier network is implemented in a scalable, massively parallel supercomputing device structure comprising a plurality of processing nodes interconnected by multiple independent networks, with each node including one or more processing elements for performing computation or communication activity as required when performing parallel algorithm operations. One multiple independent network includes a global tree network for enabling high-speed global tree communications among global tree network nodes or sub-trees thereof. The global interrupt and barrier network may operate in parallel with the global tree network for providing global asynchronous sideband signals.

  5. Plasma-sprayed coatings

    SciTech Connect (OSTI)

    Herman, H.

    1988-09-01

    Plasma spraying is one way to apply protective coatings. The hot, high-speed flame of a plasma gun can melt a powder of almost any ceramic or metal and spray it to form a coating for protection against corrosion, wear or high temperature. The technique carries much less risk of degrading the coating and substrate than many other high-temperature processes do, because the gas in the plasma flame is chemically inert and the target can be kept fairly cool. And yet a plasma gun can be only a little more cumbersome than a paint sprayer. Investigators are applying this technique to new materials. The General Electric Company is using vacuum plasma spraying to make freestanding components: intricate aircraft engine parts formed by plasma-spraying a superalloy on a removable substrate. Other workers spray ceramic particles or fibers and metal powder simulatious wrong, stiff composite materials: the ceramic particles dispersed in a matrix of metal. The author and colleagues at the U.S. Naval Research Laboratory have fabricated a thick film of high-temperature superconductor by plasma-spraying the compound in the form of a powder. 7 figs.

  6. Coating and curing apparatus and methods

    DOE Patents [OSTI]

    Brophy, Brenor L; Maghsoodi, Sina; Neyman, Patrick J; Gonsalves, Peter R; Hirsch, Jeffrey G; Yang, Yu S

    2015-02-24

    Disclosed are coating apparatus including flow coating and roll-coating that may be used for uniform sol-gel coating of substrates such as glass, solar panels, windows or part of an electronic display. Also disclosed are methods for substrate preparation, flow coating and roll coating. Lastly systems and methods for skin curing sol-gel coatings deposited onto the surface of glass substrates using a high temperature air-knife are disclosed.

  7. Al+LiF Coated Focal Plane

    E-Print Network [OSTI]

    Al+LiF Coated Mirror #2 Focal Plane Assemblies (4) Detectors (2) Al+LiF Coated Mirror #1 SiC Coated Mirror #2 SiC Coated Mirror #1 Rowland Circles Al+LiF Coated Grating #2 Al+LiF Coated Grating #1 SiC Coated Grating #2 z y x Figure 1 A schematic view of the FUSE optical system. 1. INTRODUCTION The Far

  8. Innovative Cathode Coating Enables Faster Battery Charging, Dischargin...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovative Cathode Coating Enables Faster Battery Charging, Discharging Technology available for licensing: Coating increases electrical conductivity of cathode materials Coating...

  9. Enhanced tunneling through nonstationary barriers

    SciTech Connect (OSTI)

    Palomares-Baez, J. P.; Rodriguez-Lopez, J. L. [Advanced Materials Department, Instituto Potosino de Investigacion Cientifica y Tecnologica, San Luis Potosi, San Luis Potosi 78231 (Mexico); Ivlev, B. [Department of Physics and Astronomy and NanoCenter, University of South Carolina, Columbia, South Carolina 29208 (United States); Instituto de Fisica, Universidad Autonoma de San Luis Potosi, San Luis Potosi, San Luis Potosi 78000 (Mexico)

    2007-11-15

    Quantum tunneling through a nonstationary barrier is studied analytically and by a direct numerical solution of Schroedinger equation. Both methods are in agreement and say that the main features of the phenomenon can be described in terms of classical trajectories which are solutions of Newton's equation in complex time. The probability of tunneling is governed by analytical properties of a time-dependent perturbation and the classical trajectory in the plane of complex time. Some preliminary numerical calculations of Euclidean resonance (an easy penetration through a classical nonstationary barrier due to an underbarrier interference) are presented.

  10. DEVELOPMENT OF PROTECTIVE COATINGS FOR SINGLE CRYSTAL TURBINE BLADES

    SciTech Connect (OSTI)

    Amarendra K. Rai

    2006-12-04

    Turbine blades in coal derived syngas systems are subject to oxidation and corrosion due to high steam temperature and pressure. Thermal barrier coatings (TBCs) are developed to address these problems. The emphasis is on prime-reliant design and a better coating architecture, having high temperature and corrosion resistance properties for turbine blades. In Phase I, UES Inc. proposed to develop, characterize and optimize a prime reliant TBC system, having smooth and defect-free NiCoCrAlY bond layer and a defect free oxide sublayer, using a filtered arc technology. Phase I work demonstrated the deposition of highly dense, smooth and defect free NiCoCrAlY bond coat on a single crystal CMSX-4 substrate and the deposition of alpha-alumina and yttrium aluminum garnet (YAG) sublayer on top of the bond coat. Isothermal and cyclic oxidation test and pre- and post-characterization of these layers, in Phase I work, (with and without top TBC layer of commercial EB PVD YSZ) revealed significant performance enhancement.

  11. Surface coatings. Science and technology

    SciTech Connect (OSTI)

    Paul, S.

    1985-01-01

    This book covers the coating field from the latest industry developments to current energy and pollution regulations. It explains the composition of coatings, how they are prepared and applied and the factors that control their ultimate performance. The author discusses the synthesis of polymeric binders, industrial resins, pigments, paints and paint properties, types of coatings, and new technologies. CONTENTS: Binders: Synthesis of Polymeric Binders; Industrial Resins; Pigments; Paints and Paint Properties: Pigment Dispersion; Surface Preparation and Paint Application; Paint Properties and Their Evaluation; Types of Coatings; New Technolgies.

  12. Dynaically Responsive IP Window Coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pacific Northwest National Laboratory Dynamically Responsive IR Window Coatings 2014 Building Technologies Office Peer Review 2 Project Summary Timeline: Start date:...

  13. Dynamically Responsive Infrared Window Coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dynamically Responsive Infrared Window Coatings 2015 Building Technologies Office Peer Review Dr. Kyle J. Alvine, kyle.alvine@pnnl.gov Pacific Northwest National Laboratory 21C...

  14. Ceramic electrolyte coating and methods

    DOE Patents [OSTI]

    Seabaugh, Matthew M. (Columbus, OH); Swartz, Scott L. (Columbus, OH); Dawson, William J. (Dublin, OH); McCormick, Buddy E. (Dublin, OH)

    2007-08-28

    Aqueous coating slurries useful in depositing a dense coating of a ceramic electrolyte material (e.g., yttrium-stabilized zirconia) onto a porous substrate of a ceramic electrode material (e.g., lanthanum strontium manganite or nickel/zirconia) and processes for preparing an aqueous suspension of a ceramic electrolyte material and an aqueous spray coating slurry including a ceramic electrolyte material. The invention also includes processes for depositing an aqueous spray coating slurry including a ceramic electrolyte material onto pre-sintered, partially sintered, and unsintered ceramic substrates and products made by this process.

  15. EERE Desal using Superhydrophobic Coatings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    * Prevents salt creep, keeping salt buildup localized & manageable * Inexpensive (the coating material costs is penniessquare yard) * Easy spray-on application * Non-toxic *...

  16. Vented Cavity Radiant Barrier Assembly And Method

    DOE Patents [OSTI]

    Dinwoodie, Thomas L. (Piedmont, CA); Jackaway, Adam D. (Berkeley, CA)

    2000-05-16

    A vented cavity radiant barrier assembly (2) includes a barrier (12), typically a PV module, having inner and outer surfaces (18, 22). A support assembly (14) is secured to the barrier and extends inwardly from the inner surface of the barrier to a building surface (14) creating a vented cavity (24) between the building surface and the barrier inner surface. A low emissivity element (20) is mounted at or between the building surface and the barrier inner surface. At least part of the cavity exit (30) is higher than the cavity entrance (28) to promote cooling air flow through the cavity.

  17. Electron-stimulated desorption from polished and vacuum fired 316LN stainless steel coated with Ti-Zr-Hf-V

    SciTech Connect (OSTI)

    Malyshev, Oleg B. Valizadeh, Reza; Hogan, Benjamin T.; Hannah, Adrian N.

    2014-11-01

    In this study, two identical 316LN stainless steel tubular samples, which had previously been polished and vacuum-fired and then used for the electron-stimulated desorption (ESD) experiments, were coated with Ti-Zr-Hf-V with different morphologies: columnar and dense. ESD measurement results after nonevaporable getter (NEG) activation to 150, 180, 250, and 350?°C indicated that the values for the ESD yields are significantly (2–20 times) lower than the data from our previous study with similar coatings on nonvacuum-fired samples. Based on these results, the lowest pressure and best long-term performance in particle accelerators will be achieved with a vacuum-fired vacuum chamber coated with dense Ti-Zr-Hf-V coating activated at 180?°C. This is likely due to the following facts: after NEG activation, the hydrogen concentration inside the NEG was lower than in the bulk stainless steel substrate; the NEG coating created a barrier for gas diffusion from the sample bulk to vacuum; the dense NEG coating performed better as a barrier than the columnar NEG coating.

  18. Plastic Schottky barrier solar cells

    DOE Patents [OSTI]

    Waldrop, James R. (Thousand Oaks, CA); Cohen, Marshall J. (Thousand Oaks, CA)

    1984-01-24

    A photovoltaic cell structure is fabricated from an active medium including an undoped, intrinsically p-type organic semiconductor comprising polyacetylene. When a film of such material is in rectifying contact with a magnesium electrode, a Schottky-barrier junction is obtained within the body of the cell structure. Also, a gold overlayer passivates the magnesium layer on the undoped polyacetylene film.

  19. Performance Testing of Radiant Barriers 

    E-Print Network [OSTI]

    Hall, J. A.

    1986-01-01

    TVA has conducted a study to determine the effects of radiant barriers (RBI (i.e., material with a low emissivity surface facing an air space), when used with fiberglass, on attic heat transfer during summer and winter. This study employed five...

  20. Carbonaceous film coating

    DOE Patents [OSTI]

    Maya, L.

    1988-04-27

    A method of making a carbonaceous film comprising heating tris(1,3,2-benzodiazaborolo)borazine or dodecahydro tris(1,3,2)diazaborine(1,2-a:1'2'-c:1''2''-e)borazine in an inert atmosphere in the presence of a substrate to a temperature at which the borazine compound decomposes, and the decomposition products deposit onto the substrate to form a thin, tenacious, highly reflective conductive coating having a narrow band gap which is susceptible of modification and a relatively low coefficient of friction.

  1. Overcoming Multifamily Sector Barriers in Austin, Texas | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Overcoming Multifamily Sector Barriers in Austin, Texas Overcoming Multifamily Sector Barriers in Austin, Texas Presents techniques on overcoming the barriers of multifamily energy...

  2. Advanced zinc phosphate conversion coatings. Final report, June 1996--December 1996

    SciTech Connect (OSTI)

    Handsy, C.I. [ATSTA-TMC, Warren, MI (United States); Sugama, T. [Brookhaven National Lab., Upton, NY (United States)

    1997-04-01

    A SERDP-sponsored program aims at developing environmentally benign zinc phosphate conversion coatings and their process technologies for the electrogalvanized steel (EGS). We succeeded in formulating an environmentally acceptable phosphate solution without Co- and Ni-related additives, and also in replacing a hexavalent Cr acid sealant applied over the zinc phosphate (Zh-Ph) layers with a water-based polysiloxane sealers. The specific advantages of the newly developed Zn-Ph coatings were as follows: (1) there was rapid growth of uniform, dense embryonic Zn-Ph crystals on the EGS surfaces due to the creation of short-circuited cells with Mn acting as the cathode and the galvanized (zinc) coatings as the anode, (2) an excellent protection layer against corrosion was formed, extending the service life of zinc layers as galvanic sacrifice barriers, and (3) adhesion to the electro-deposited polymeric primer coating was improved because of the interaction between the siloxane sealer and primer. A full-scale demonstration to evaluate the reproducibility of this new coating technology on mini-sized automotive door panels made from EGS was carried out in collaboration with the Palnut Company (as industrial coating applicator) in New Jersey. All of the 150 mini-door panels were successfully coated with Zn-Ph.

  3. Preparation of zirconia coatings by hydrolysis of zirconium alkoxide with hydrogen peroxide

    SciTech Connect (OSTI)

    Sakurai, Chihiro; Fukui, Toshimi; Okuyama, Masahiko )

    1993-04-01

    Zirconia has gained a great deal of attention because of its superior properties of mechanical strength, chemical resistance, and ionic conductivity. Zirconia coatings and thin films are receiving attention as tribological and thermal barrier coatings for engines, high-reflective coatings, solid electrolytes for fuel cells, oxygen sensors, etc. The sol-gel coating method has several advantages, such as low processing temperatures, homogeneity, control of micro-structure, and good productivity compared to chemical vapor deposition and physical vapor deposition. However, there are few reports concerning the preparation of zirconia coatings and thin films by the sol-gel method. Up to the present, zirconia coatings have been prepared from zirconium propoxide (not heated), zirconium tetrabutoxide modified by acetylacetone and ethyl acetoacetate, zirconium diethoxydichloride (ZrCl[sub 2](OC[sub 2]H[sub 5])[sub 2]), and a hydrosol prepared from a zirconium oxychloride solution. Coatings of 8.8-mol%-yttria-doped zirconia were fabricated using a transparent and spinnable sol prepared by hydrolysis of zirconium alkoxide with hydrogen peroxide and nitric acid. The sol gave a crack-free coating film consisting of fine grains. The crystalline phase was cubic after heating of 1,000 and 1,200 C and cubic and tetragonal at 1,350 C, with the coating being highly oriented in the (111) plane, especially at 1,000 C. Activation energy of the coating films was higher than that of the bulk. Transmittance through a film thickness of about 0.3 [mu]m on each side was 75%.

  4. SELECTIVE ABSORBER COATED FOILS FOR SOLAR COLLECTORS

    E-Print Network [OSTI]

    Lampert, Carl M.

    2013-01-01

    p. 1080. AES Second Coatings for Solar Collectors Symp. , 11coating concept is to use heavy starting stock which might be suitable for direct fabrication of solar collectorsolar collector panels. Here the major consideration is whether the coating

  5. DOE Discussion on Small Business Contract Barriers

    Broader source: Energy.gov [DOE]

    Small and large business representatives discussed barriers to competition at a well-attended Waste Management Conference session.

  6. Overcoming Multifamily Sector Barriers in Austin, Texas

    Broader source: Energy.gov [DOE]

    Presents techniques on overcoming the barriers of multifamily energy efficiency projects, including how to market to property managers.

  7. Tests Conducted with Strippable Coatings

    SciTech Connect (OSTI)

    K. E. Archibald; R. L. Demmer

    1999-08-01

    This report details the testing and evaluation of several strippable coatings and their use in decontamination. Pentek 604, Bartlett (TLC), and ALARA 1146 were products examined for their overall effectiveness and ease of use. Conclusions were reached about the effective use of these coatings, and field test examples, with radioactive contamination are incorporated.

  8. Thin film ion conducting coating

    DOE Patents [OSTI]

    Goldner, Ronald B. (Lexington, MA); Haas, Terry (Sudbury, MA); Wong, Kwok-Keung (Watertown, MA); Seward, George (Arlington, MA)

    1989-01-01

    Durable thin film ion conducting coatings are formed on a transparent glass substrate by the controlled deposition of the mixed oxides of lithium:tantalum or lithium:niobium. The coatings provide durable ion transport sources for thin film solid state storage batteries and electrochromic energy conservation devices.

  9. MICROSTRUCTURAL EXAMINATION AND DEUTERIUM PERMEATION TESTING OF ADVANCED COATINGS FOR TRITIUM SERVICE

    SciTech Connect (OSTI)

    Korinko, P.

    2004-01-24

    A plant directed research and development task to develop and study new, improved, and low cost tritium permeation barriers was initiated in FY02. The project was intended to determine the permeation rate and permeation reduction factor of substrate materials and coated materials. The samples were characterized for microstructural and microchemical consistency. Permeation tests were also run. The sample geometry and sample sealing method selected for the coatings posed significant schedule and technical challenges. Diffusivity were consistent with published values but permeation data exhibited an unexpected sample to sample variation. The effort has lead to an improved sample design that will be used to support a Process Development task.

  10. Coatings on reflective mask substrates

    DOE Patents [OSTI]

    Tong, William Man-Wai (Oakland, CA); Taylor, John S. (Livermore, CA); Hector, Scott D. (Oakland, CA); Mangat, Pawitter J. S. (Gilbert, AZ); Stivers, Alan R. (San Jose, CA); Kofron, Patrick G. (San Jose, CA); Thompson, Matthew A. (Austin, TX)

    2002-01-01

    A process for creating a mask substrate involving depositing: 1) a coating on one or both sides of a low thermal expansion material EUVL mask substrate to improve defect inspection, surface finishing, and defect levels; and 2) a high dielectric coating, on the backside to facilitate electrostatic chucking and to correct for any bowing caused by the stress imbalance imparted by either other deposited coatings or the multilayer coating of the mask substrate. An film, such as TaSi, may be deposited on the front side and/or back of the low thermal expansion material before the material coating to balance the stress. The low thermal expansion material with a silicon overlayer and a silicon and/or other conductive underlayer enables improved defect inspection and stress balancing.

  11. MONITORING SUBSURFACE BARRIER INTEGRITY USING PERFLUOROCARBON TRACERS

    E-Print Network [OSTI]

    National Laboratory, Hanford, Fernald, and Rocky Flats. Barriers are also considered an important reme (PFTs) have been tested as a means of barrier veri- fication at the Hanford geotech,¢cal test facility through the barrier. This paper discusses the experimental design, test reSUlts, data analysis

  12. Scalable superhydrophobic coatings based on fluorinated diatomaceous...

    Office of Scientific and Technical Information (OSTI)

    Scalable superhydrophobic coatings based on fluorinated diatomaceous earth Citation Details In-Document Search Title: Scalable superhydrophobic coatings based on fluorinated...

  13. Development of Industrially Viable Battery Electrode Coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrially Viable Battery Electrode Coatings Development of Industrially Viable Battery Electrode Coatings 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies...

  14. Coated Particle Fuel Development Lab (CPFDL) | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRISO Coating 50 mm Fluidized Bed Chemical Vapor Deposition System Computer control of coating temperature and gas composition Particle Classification Tabler, roller micrometer,...

  15. Precise Application of Transparent Conductive Oxide Coatings...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (TCO) coatings are deposited using atomic layer deposition (ALD). Provides uniform coating of complex, 3D nanostructures such as electrodes for next-generation PV cells...

  16. Metasurface optical antireflection coating

    SciTech Connect (OSTI)

    Zhang, Boyang [Univ. of Alabama, Huntsville, AL (United States). Department of Electrical and Computer Engineering.; Hendrickson, Joshua [Air Force Research Lab., Wright Patterson Air Force Base, OH (United States); Nader, Nima [Air Force Research Lab., Wright Patterson Air Force Base, OH (United States); Solid State Scientific Corporation, Nashua, New Hampshire (United States); Chen, Hou -Tong [Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Center for Integrated Nanotechnologies.; Guo, Junpeng [Univ. of Alabama, Huntsville, AL (United States). Department of Electrical and Computer Engineering.

    2014-12-15

    Light reflection at the boundary of two different media is one of the fundamental phenomena in optics, and reduction of reflection is highly desirable in many optical systems. Traditionally, optical antireflection has been accomplished using single- or multiple-layer dielectric films and graded index surface structures in various wavelength ranges. However, these approaches either impose strict requirements on the refractive index matching and film thickness, or involve complicated fabrication processes and non-planar surfaces that are challenging for device integration. Here, we demonstrate an antireflection coating strategy, both experimentally and numerically, by using metasurfaces with designer optical properties in the mid-wave infrared. Our results show that the metasurface antireflection is capable of eliminating reflection and enhancing transmission over a broad spectral band and a wide incidence angle range. The demonstrated antireflection technique has no requirement on the choice of materials and is scalable to other wavelengths.

  17. Metasurface optical antireflection coating

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Boyang; Hendrickson, Joshua; Nader, Nima; Chen, Hou -Tong; Guo, Junpeng

    2014-12-15

    Light reflection at the boundary of two different media is one of the fundamental phenomena in optics, and reduction of reflection is highly desirable in many optical systems. Traditionally, optical antireflection has been accomplished using single- or multiple-layer dielectric films and graded index surface structures in various wavelength ranges. However, these approaches either impose strict requirements on the refractive index matching and film thickness, or involve complicated fabrication processes and non-planar surfaces that are challenging for device integration. Here, we demonstrate an antireflection coating strategy, both experimentally and numerically, by using metasurfaces with designer optical properties in the mid-wave infrared.more »Our results show that the metasurface antireflection is capable of eliminating reflection and enhancing transmission over a broad spectral band and a wide incidence angle range. The demonstrated antireflection technique has no requirement on the choice of materials and is scalable to other wavelengths.« less

  18. Coated substrates and process

    DOE Patents [OSTI]

    Chu, Wei-kan (Chapel Hill, NC); Childs, Charles B. (Chapel Hill, NC)

    1991-01-01

    Disclosed herein is a coated substrate and a process for forming films on substrates and for providing a particularly smooth film on a substrate. The method of this invention involves subjecting a surface of a substrate to contact with a stream of ions of an inert gas having sufficient force and energy to substantially change the surface characteristics of said substrate, and then exposing a film-forming material to a stream of ions of an inert gas having sufficient energy to vaporize the atoms of said film-forming material and to transmit the vaporized atoms to the substrate surface with sufficient force to form a film bonded to the substrate. This process is particularly useful commercially because it forms strong bonds at room temperature. This invention is particularly useful for adhering a gold film to diamond and forming ohmic electrodes on diamond, but also can be used to bond other films to substrates.

  19. Ceramic composite coating

    DOE Patents [OSTI]

    Wicks, George G. (Aiken, SC)

    1997-01-01

    A thin, room-temperature-curing, ceramic composite for coating and patching etal substrates comprises a sol gel silica glass matrix filled with finely ground particles or fibers, preferably alumina. The sol gel glass is made by adding ethanol to water to form a first mixture, then separately adding ethanol to tetraethyl orthosilicate to form a second mixture, then slowly adding the first to the second mixture to make a third mixture, and making a slurry by adding the finely ground particles or fibers to the third mixture. The composite can be applied by spraying, brushing or trowelling. If applied to patch fine cracks, densification of the ceramic composite may be obtained to enhance sealing by applying heat during curing.

  20. Cryogenic Barrier Demonstration Project. Final report

    SciTech Connect (OSTI)

    Johnson, L.A.; Yarmak, E.; Long, E.L.

    2000-03-01

    A long-term frozen soil barrier was implemented at the HRE (Homogeneous Reactor Experiment) Pond facility at the Oak Ridge National Laboratory in 1997. This was performed to verify the technical feasibility and costs of deploying a frozen barrier at a radiologically contaminated site. Work began in September 1996 and progressed through to December 1999. The frozen barrier has been operational since November 1997. Verification of the barrier integrity was performed independently by the EPA's SITE Program. This project showed frozen barriers offer a proven technology to retain below grade hazardous substances at relatively low costs with minimal effect on the environment.

  1. Double barrier system for an in situ conversion process

    DOE Patents [OSTI]

    McKinzie, Billy John [Houston, TX; Vinegar, Harold J [Bellaire, TX; Cowan, Kenneth Michael [Sugar land, TX; Deeg, Wolfgang Friedrich Johann [Houston, TX; Wong, Sau-Wai [Rijswijk, NL

    2009-05-05

    A barrier system for a subsurface treatment area is described. The barrier system includes a first barrier formed around at least a portion of the subsurface treatment area. The first barrier is configured to inhibit fluid from exiting or entering the subsurface treatment area. A second barrier is formed around at least a portion of the first barrier. A separation space exists between the first barrier and the second barrier.

  2. Energy Efficiency Projects: Overcoming Internal Barriers to Implementa...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency Projects: Overcoming Internal Barriers to Implementation Energy Efficiency Projects: Overcoming Internal Barriers to Implementation This presentation discusses...

  3. Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems

    SciTech Connect (OSTI)

    Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Jordi Perez-Mariano; Angel Sanjurjo

    2006-06-30

    Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this period, we analyzed several coated and exposed samples of 409 steel by scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX). We report here on findings of this analysis: (1) A SS409 coupon that was coated with multilayered combined nitrides of Ti, Al, and Si showed adherent coatings on the surface; (2) A similarly coated coupon, after exposure to simulated coal gas at 900 C for 300 h, revealed that the coating has cracked during the exposure; (3) An SS409 coupon that was coated with nitrides of Ti and Si with a barrier layer of tungsten in between to improve the adhesion of the coating and to prevent outward diffusion of iron to the surface. (4) A porous coupon was coated with nitrides of Ti and Al and examination of the coupon revealed deposition of Ti at the interior surfaces. A similarly prepared coupon was exposed to simulated coal gas at 370 C for 300 h, and it showed no corrosion.

  4. barrier

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLos Alamos verifiesValidation ofUV-RSSSummary5 Kentuckybaikbarrier

  5. Synopsis: Thinner Stealth Coatings January 6, 2015

    E-Print Network [OSTI]

    Page, John

    Synopsis: Thinner Stealth Coatings January 6, 2015 Antireflective acoustic coatings for hiding coatings. The tiles in use today are a few centimeters thick, but the same degree of stealth protection could perhaps be provided by a much thinner coating, according to researchers in Canada and France

  6. Photoresist Coating Revised: 2009-11-05

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Photoresist Coating Techniques Revised: 2009-11-05 Source: www.microchemicals.eu e-Mail: sales@microchemicals.eu Criteria for the Resist Coating Technique Each photoresist for an understanding which coating technique is the best- suited coating method for a certain application. Hereby

  7. Cortical neuron cultures Plate and coverslip coating

    E-Print Network [OSTI]

    West, Anne

    Cortical neuron cultures 9/19/05 Plate and coverslip coating 1. PDL cat #P6407 from Sigma. Stock are always coated overnight at 37 in a 24 well plate. Plastic dishes can be coated for as little as 2 hours. PDL can be reused several times for up to 1-2 months, Store at 4 in between uses. Wash coated CS

  8. Functioning mechanism of AlF3 coating on the Li- and Mn-rich cathode materials

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Xiao, Jie; Polzin, Bryant; Yan, Pengfei; Chen, Xilin; Wang, Chong M.; Zhang, Jiguang

    2014-11-25

    Li- and Mn-rich (LMR) material is a very promising cathode for lithium ion batteries because of their high theoretical energy density (~900 Wh kg-1) and low cost. However, their poor long-term cycling stability, voltage fade, and low rate capability are significant barriers hindered their practical applications. Surface coating, e.g. AlF3 coating, can significantly improve the capacity retention and enhance the rate capability. However, the fundamental mechanism of this improvement and the microstructural evolution related to the surface coating is still not well understood. Here, we report systematic studies of the microstructural changes of uncoated and AlF3-coated materials before and after cycling using aberration-corrected scanning/transmission electron microscopy and electron energy loss spectroscopy. The results reveal that surface coating can reduce the oxidation of electrolyte at high voltage, thus suppressing the accumulation of SEI layer on electrode particle surface. Surface coating also enhances structural stability of the surface region (especially the electrochemically transformed spinel-like phase), and protects the electrode from severe etching/corrosion by the acidic species in the electrolyte, therefore limiting the degradation of the material. Moreover, surface coating can alleviate the undesirable voltage fade by minimize layered-spinel phase transformation in the bulk region of the materials. These fundamental findings may also be widely applied to explain the functioning mechanism of other surface coatings used in a broad range of electrode materials.

  9. Development of Recycling Compatible Pressure-Sensitive Adhesives and Coatings

    SciTech Connect (OSTI)

    Steven J. Severtson

    2010-02-15

    The objective of this project was the design of new water-based pressure-sensitive adhesive (PSA) products and coatings engineered for enhanced removal during the processing of recycled fiber. Research included the formulation, characterization, and performance measurements of new screenable coatings, testing of modified paper and board substrates and the design of test methods to characterize the inhibition of adhesive and coating fragmentation and relative removal efficiencies of developed formulations. This project was operated under the requirements that included commercially viable approaches be the focus, that findings be published in the open literature and that new strategies could not require changes in the methods and equipment used to produce PSA and PS labels or in the recycling process. The industrial partners benefited through the building of expertise in their company that they would not, and likely could not, have pursued if it had not been for the partnership. Results of research on water-based PSAs clearly identifies which PSA and paper facestock properties govern the fragmentation of the adhesive and provide multiple strategies for making (pressure-sensitive) PS labels for which the PSA is removed at very high efficiencies from recycling operations. The application of these results has led to the identification of several commercial products in Franklin International’s (industrial partner) product line that are recycling compatible. Several new formulations were also designed and are currently being scaled-up. Work on recycling compatible barrier coatings for corrugated containers examined the reinforcement of coatings using a small amount of exfoliated organically modified montmorillonite (OMMT). These OMMT/paraffin wax nanocomposites demonstrated significantly improved mechanical properties. Paraffin waxes containing clay were found to have significantly higher Young’s moduli and yield stress relative to the wax matrix, but the most impressive finding was the impact of the clay on the elongation at break; a nearly 400% increase was observed for a clay concentration of 0.5 wt.%. These coatings also demonstrate a number of other property enhancements, which make them a good candidate for continued research. Another approach explored in this research was the use of structured and self-cleaning surfaces. If the amount of coating utilized can be significantly reduced, the environmental impact is diminished.

  10. Method of measuring metal coating adhesion

    DOE Patents [OSTI]

    Roper, John R. (Northglenn, CO)

    1985-01-01

    A method for measuring metal coating adhesion to a substrate material comprising the steps of preparing a test coupon of substrate material having the metal coating applied to one surface thereof, applying a second metal coating of gold or silver to opposite surfaces of the test coupon by hot hollow cathode process, applying a coating to one end of each of two pulling rod members, joining the coated ends of the pulling rod members to said opposite coated surfaces of the test coupon by a solid state bonding technique and finally applying instrumented static tensile loading to the pulling rod members until fracture of the metal coating adhesion to the substrate material occurs.

  11. Prime coats materials and methods 

    E-Print Network [OSTI]

    Mantilla, Christian Augusto

    1994-01-01

    A prime coat is the application of a suitable bituminous binder applied to a nonbituminous granular base as a preliminary treatment before the application of a bituminous surfacing. The purpose of this research is to establish practical applications...

  12. PHOTOCATALYSIS ON TITANIA-COATED

    E-Print Network [OSTI]

    Cirkva, Vladimir

    PHOTOCATALYSIS ON TITANIA-COATED ELECTRODELESS DISCHARGE LAMPS #12;#12;PHOTOCATALYSIS ON TITANIA/Vis-illuminated Titania 39 Chapter 5 Novel Microwave Photocatalytic Reactors 41 Chapter 6 Microwave Photocatalysis

  13. Corrosion resistant neutron absorbing coatings

    DOE Patents [OSTI]

    Choi, Jor-Shan (El Cerrito, CA); Farmer, Joseph C. (Tracy, CA); Lee, Chuck K. (Hayward, CA); Walker, Jeffrey (Gaithersburg, MD); Russell, Paige (Las Vegas, NV); Kirkwood, Jon (Saint Leonard, MD); Yang, Nancy (Lafayette, CA); Champagne, Victor (Oxford, PA)

    2012-05-29

    A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.

  14. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, J.J.; Elling, D.; Reams, W.

    1990-03-13

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

  15. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, Jack J. (Shirley, NY); Elling, David (Centereach, NY); Reams, Walter (Shirley, NY)

    1990-01-01

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

  16. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, J.J.; Elling, D.; Reams, W.

    1988-05-26

    A sprayable electrically conductive polymer concrete coating for vertical and overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt% calcined coke breeze, 40 wt% vinyl ester resin with 3.5 wt% modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag. 4 tabs.

  17. Corrosion resistant neutron absorbing coatings

    DOE Patents [OSTI]

    Choi, Jor-Shan; Farmer, Joseph C; Lee, Chuck K; Walker, Jeffrey; Russell, Paige; Kirkwood, Jon; Yang, Nancy; Champagne, Victor

    2013-11-12

    A method of forming a corrosion resistant neutron absorbing coating comprising the steps of spray or deposition or sputtering or welding processing to form a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material. Also a corrosion resistant neutron absorbing coating comprising a composite material made of a spray or deposition or sputtering or welding material, and a neutron absorbing material.

  18. On Coating Durability of Polymer Coated Sheet Metal under Plastic Deformation 

    E-Print Network [OSTI]

    Huang, Yu-Hsuan

    2011-08-08

    Polymer coated sheet metal components find diverse applications in many industries. The manufacturing of the components generally involves forming of sheet metal into the desired shape and coating of the formed part with organic coating...

  19. Identification of Key Barriers in Workforce Development

    SciTech Connect (OSTI)

    2008-03-31

    This report documents the identification of key barriers in the development of an adequate national security workforce as part of the National Security Preparedness Project, being performed under a Department of Energy/National Nuclear Security Administration grant. Many barriers exist that prevent the development of an adequate number of propertly trained national security personnel. Some barriers can be eliminated in a short-term manner, whereas others will involve a long-term strategy that takes into account public policy.

  20. Co-Doping of Air Plasma-Sprayed Yttria-and Ceria-Stabilized Zirconia for Thermal Barrier Applications

    E-Print Network [OSTI]

    Trice, Rodney W.

    Co-Doping of Air Plasma-Sprayed Yttria- and Ceria-Stabilized Zirconia for Thermal Barrier typically consists of two layers, e.g., a B200 mm thick zirconia-based topcoat and a B100 mm me- tallic bond coat (MCrAlY, where M can be Co, Ni, or Fe).1 The zirconia layer is most often stabilized with Y2O3

  1. International Collaborations on Engineered Barrier Systems: Experiment...

    Energy Savers [EERE]

    interaction to evaluate sealing and clay barrier performance; 2) EBS Experiment -thermo-hydro-mechanical-chemical (THMC) behavior of the EBS under heating conditions and...

  2. Metal Nitride Diffusion Barriers for Copper Interconnects 

    E-Print Network [OSTI]

    Araujo, Roy A.

    2010-01-14

    Advancements in the semiconductor industry require new materials with improved performance. With the introduction of copper as the interconnect material for integrated circuits, efficient diffusion barriers are required ...

  3. Manufacturing Barriers to High Temperature PEM Commercialization

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improve cost 992011 10 Manufacturing Barriers BASF is interested in mass markets for fuel cells Market forces appear to favor distributed generation - combined heat and...

  4. Rejuvenating Permeable Reactive Barriers by Chemical Flushing

    Broader source: Energy.gov [DOE]

    Final Report:Rejuvenating Permeable Reactive Barriers by Chemical Flushing,U.S. Environmental Protection Agency, Region 8 Support.August 2004

  5. Hydrogenases and Barriers for Biotechnological Hydrogen Production...

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogenases and barriers for biotechnological hydrogen production technologies John W. Peters Department of Chemistry and Biochemistry Department of Microbiology Montana State...

  6. Evaluation of repeated electrowetting on three different fluoropolymer top coatings

    E-Print Network [OSTI]

    Koo, B; Kim, CJ

    2013-01-01

    across the fluoropolymer top coating (calculated) divided bydifferent fluoropolymer top coatings Bonhye Koo 1,3 andpopular fluoropolymer top coatings: Teflon, FluoroPel and

  7. PROTECTIVE SURFACE COATINGS ON SEMICONDUCTOR NUCLEAR RADIATION DETECTORS

    E-Print Network [OSTI]

    Hansen, W.L.

    2010-01-01

    Science PROTECTIVE SURFACE COATINGS ON SEMICONDUCTOR NUCLEARF PROTECTIVE SURFACE COATINGS ON SEMICONDUCTOR NUCLEARchannel for one particular coating is unrelated to the

  8. Tough Coating Proteins: Subtle Sequence Variation Modulates Cohesion

    E-Print Network [OSTI]

    2015-01-01

    toughness of M. californianus coating is much greater thanstrain (?120% vs 75%). The coatings of both species arepubs.acs.org/Biomac Tough Coating Proteins: Subtle Sequence

  9. Coating Microstructure-Property-Performance Issues

    SciTech Connect (OSTI)

    Terry C. Totemeier; Richard N. Wright

    2005-05-01

    Results of studies on the relationships between spray parameters and performance of thermally-sprayed intermetallic coatings for high-temperature oxidation and corrosion resistance are presented. Coating performance is being assessed by corrosion testing of free-standing coatings, thermal cycling of coating substrates, and coating ductility measurement. Coating corrosion resistance was measured in a simulated coal combustion gas environment (N2-CO-CO2-H2O-H2S) at temperatures from 500 to 800°C using thermo-gravimetric analysis (TGA). TGA testing was also performed on a typical ferritic-martensitic steel, austenitic stainless steel, and a wrought Fe3Al-based alloy for direct comparison to coating behavior. FeAl and Fe3Al coatings showed corrosion rates slightly greater than that of wrought Fe3Al, but markedly lower than the steels at all temperatures. The corrosion rates of the coatings were relatively independent of temperature. Thermal cycling was performed on coated 316SS and nickel alloy 600 substrates from room temperature to 800°C to assess the relative effects of coating microstructure, residual stress, and thermal expansion mismatch on coating cracking by thermal fatigue. Measurement of coating ductility was made by acoustic emission monitoring of coated 316SS tensile specimens during loading.

  10. Sputtering process and apparatus for coating powders

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Kerns, John A. (Livermore, CA); Alford, Craig S. (Tracy, CA); McKernan, Mark A. (Livermore, CA)

    2002-01-01

    A process and apparatus for coating small particles and fibers. The process involves agitation by vibrating or tumbling the particles or fibers to promote coating uniformly, removing adsorbed gases and static charges from the particles or fibers by an initial plasma cleaning, and coating the particles or fibers with one or more coatings, a first coating being an adhesion coating, and with subsequent coatings being deposited in-situ to prevent contamination at layer interfaces. The first coating is of an adhesion forming element (i.e. W, Zr, Re, Cr, Ti) of a 100-10,000 .ANG. thickness and the second coating or final coating of a multiple (0.1-10 microns) being Cu or Ag, for example for brazing processes, or other desired materials that defines the new surface related properties of the particles. An essential feature of the coating process is the capability to deposit in-situ without interruption to prevent the formation of a contaminated interface that could adversely affect the coating adhesion. The process may include screening of the material to be coated and either continuous or intermittent vibration to prevent agglomeration of the material to be coated.

  11. Active barrier films of PET for solar cell application: Processing and characterization

    SciTech Connect (OSTI)

    Rossi, Gabriella; Scarfato, Paola; Incarnato, Loredana [Department of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132 - 84084 Fisciano (Italy)

    2014-05-15

    A preliminary investigation was carried out on the possibility to improve the protective action offered by the standard multilayer structures used to encapsulate photovoltaic devices. With this aim, a commercial active barrier PET-based material, able to absorb oxygen when activated by liquid water, was used to produce flexible and transparent active barrier films, by means of a lab-scale film production plant. The obtained film, tested in terms of thermal, optical and oxygen absorption properties, shows a slow oxygen absorption kinetics, an acceptable transparency and an easy roll-to-roll processability, so proving itself as a good candidate for the development of protective coating for solar cells against the atmospheric degradation agents like the rain.

  12. Evaluation of End Mill Coatings

    SciTech Connect (OSTI)

    L. J. Lazarus; R. L. Hester,

    2005-08-01

    Milling tests were run on families of High Speed Steel (HSS) end mills to determine their lives while machining 304 Stainless Steel. The end mills tested were made from M7, M42 and T15-CPM High Speed Steels. The end mills were also evaluated with no coatings as well as with Titanium Nitride (TiN) and Titanium Carbo-Nitride (TiCN) coatings to determine which combination of HSS and coating provided the highest increase in end mill life while increasing the cost of the tool the least. We found end mill made from M42 gave us the largest increase in tool life with the least increase in cost. The results of this study will be used by Cutting Tool Engineering in determining which end mill descriptions will be dropped from our tool catalog.

  13. Subterranean barriers including at least one weld

    DOE Patents [OSTI]

    Nickelson, Reva A.; Sloan, Paul A.; Richardson, John G.; Walsh, Stephanie; Kostelnik, Kevin M.

    2007-01-09

    A subterranean barrier and method for forming same are disclosed, the barrier including a plurality of casing strings wherein at least one casing string of the plurality of casing strings may be affixed to at least another adjacent casing string of the plurality of casing strings through at least one weld, at least one adhesive joint, or both. A method and system for nondestructively inspecting a subterranean barrier is disclosed. For instance, a radiographic signal may be emitted from within a casing string toward an adjacent casing string and the radiographic signal may be detected from within the adjacent casing string. A method of repairing a barrier including removing at least a portion of a casing string and welding a repair element within the casing string is disclosed. A method of selectively heating at least one casing string forming at least a portion of a subterranean barrier is disclosed.

  14. Multi-layer waste containment barrier

    DOE Patents [OSTI]

    Smith, Ann Marie (Pocatello, ID); Gardner, Bradley M. (Idaho Falls, ID); Nickelson, David F. (Idaho Falls, ID)

    1999-01-01

    An apparatus for constructing an underground containment barrier for containing an in-situ portion of earth. The apparatus includes an excavating device for simultaneously (i) excavating earthen material from beside the in-situ portion of earth without removing the in-situ portion and thereby forming an open side trench defined by opposing earthen sidewalls, and (ii) excavating earthen material from beneath the in-situ portion of earth without removing the in-situ portion and thereby forming a generally horizontal underground trench beneath the in-situ portion defined by opposing earthen sidewalls. The apparatus further includes a barrier-forming device attached to the excavating device for simultaneously forming a side barrier within the open trench and a generally horizontal, multi-layer barrier within the generally horizontal trench. The multi-layer barrier includes at least a first layer and a second layer.

  15. Coated carbon nanotube array electrodes

    DOE Patents [OSTI]

    Ren, Zhifeng (Newton, MA); Wen, Jian (Newton, MA); Chen, Jinghua (Chestnut Hill, MA); Huang, Zhongping (Belmont, MA); Wang, Dezhi (Wellesley, MA)

    2008-10-28

    The present invention provides conductive carbon nanotube (CNT) electrode materials comprising aligned CNT substrates coated with an electrically conducting polymer, and the fabrication of electrodes for use in high performance electrical energy storage devices. In particular, the present invention provides conductive CNTs electrode material whose electrical properties render them especially suitable for use in high efficiency rechargeable batteries. The present invention also provides methods for obtaining surface modified conductive CNT electrode materials comprising an array of individual linear, aligned CNTs having a uniform surface coating of an electrically conductive polymer such as polypyrrole, and their use in electrical energy storage devices.

  16. Coated carbon nanotube array electrodes

    DOE Patents [OSTI]

    Ren, Zhifeng; Wen, Jian; Chen, Jinghua; Huang, Zhongping; Wang, Dezhi

    2006-12-12

    The present invention provides conductive carbon nanotube (CNT) electrode materials comprising aligned CNT substrates coated with an electrically conducting polymer, and the fabrication of electrodes for use in high performance electrical energy storage devices. In particular, the present invention provides conductive CNTs electrode material whose electrical properties render them especially suitable for use in high efficiency rechargeable batteries. The present invention also provides methods for obtaining surface modified conductive CNT electrode materials comprising an array of individual linear, aligned CNTs having a uniform surface coating of an electrically conductive polymer such as polypyrrole, and their use in electrical energy storage devices.

  17. High-Performance Nanostructured Coating

    Office of Energy Efficiency and Renewable Energy (EERE)

    The High-Performance Nanostructured Coating fact sheet details a SunShot project led by a University of California, San Diego research team working to develop a new high-temperature spectrally selective coating for receiver surfaces. These receiver surfaces, used in concentrating solar power systems, rely on high-temperature SSCs to effectively absorb solar energy without emitting much blackbody radiation.The optical properties of the SSC directly determine the efficiency and maximum attainable temperature of solar receivers, which in turn influence the power-conversion efficiency and overall system cost.

  18. Geomembrane barriers using integral fiber optics to monitor barrier integrity

    DOE Patents [OSTI]

    Staller, G.E.; Wemple, R.P.

    1996-10-22

    This invention provides a geomembrane or geotextile with embedded optical sensors that are used to monitor the status of containment site barriers. Fiber optic strands are used to form the sensors that can detect and monitor conditions at the sites such as breaches, slope creep, subsidence, leachate levels, fires, and types of materials present or leaking from the site. The strands are integral to the membrane or textile materials. The geosynthetic membrane is deployed at the site in a fashion similar to carpet laying. Edges of the membrane or textile are joined to form a liner and the ends of the membrane or textile become the connection zones for obtaining signals from the sensors. A connection interface with a control system to generate Optical Time Delay Response or other light signals for transmission to the optic fiber strands or sensors and also to receive reflected signals from the sensors is included in the system. Software to interpret the sensor signals can be used in the geosynthetic monitoring system. 6 figs.

  19. Geomembrane barriers using integral fiber optics to monitor barrier integrity

    DOE Patents [OSTI]

    Staller, George E. (Albuquerque, NM); Wemple, Robert P. (Albuquerque, NM)

    1996-01-01

    This invention provides a geomembrane or geotextile with embedded optical sensors that are used to monitor the status of containment site barriers. Fiber optic strands are used to form the sensors that can detect and monitor conditions at the sites such as breaches, slope creep, subsidence, leachate levels, fires, and types of materials present or leaking from the site. The strands are integral to the membrane or textile materials. The geosythetic membrane is deployed at the site in a fashion similar to carpet laying. Edges of the membrane or textile are joined to form a liner and the ends of the membrane or textile become the connection zones for obtaining signals from the sensors. A connection interface with a control system to generate Optical Time Delay Response or other light signals for transmission to the optic fiber strands or sensors and also to receive reflected signals from the sensors is included in the system. Software to interpret the sensor signals can be used in the geosythetic monitoring system.

  20. POLYIMIDE COATINGS FOR ELECTRONICS ridyid KMeinfelcl-

    E-Print Network [OSTI]

    Kleinfeld, David

    / POLYIMIDE COATINGS FOR ELECTRONICS ridyid KMeinfelcl- .Room 6H-.424 ' ' ATT Bell Laboratgri^;5i existing patent. ·Dn Pnnt Tpa«4o Print«riin tift & #12;POLYIMIDE COATINGS FOR ELECTRONICS \\ PRODUCT

  1. Multimaterial coatings with reduced thermal noise

    E-Print Network [OSTI]

    Yam, William

    The most sensitive measurements of time and space are made with resonant optical cavities, and these measurements are limited by coating thermal noise. The mechanical and optical performance requirements placed on coating ...

  2. Coated foams, preparation, uses and articles

    DOE Patents [OSTI]

    Duchane, D.V.; Barthell, B.L.

    1982-10-21

    Hydrophobic cellular material is coated with a thin hydrophilic polymer skin which stretches tightly over the foam but which does not fill the cells of the foam, thus resulting in a polymer-coated foam structure having a smoothness which was not possible in the prior art. In particular, when the hydrophobic cellular material is a specially chosen hydrophobic polymer foam and is formed into arbitrarily chosen shapes prior to the coating with hydrophilic polymer, inertial confinement fusion (ICF) targets of arbitrary shapes can be produced by subsequently coating the shapes with metal or with any other suitable material. New articles of manufacture are produced, including improved ICF targets, improved integrated circuits, and improved solar reflectors and solar collectors. In the coating method, the cell size of the hydrophobic cellular material, the viscosity of the polymer solution used to coat, and the surface tension of the polymer solution used to coat are all very important to the coating.

  3. SELECTIVE ABSORBER COATED FOILS FOR SOLAR COLLECTORS

    E-Print Network [OSTI]

    Lampert, Carl M.

    2013-01-01

    Proc. of 1977 Flat Plate Solar Collector Conference- USDOE,"Second Coatings for Solar Collectors Symp. , 11 Winter Park,COATED FOILS FOR SOLAR COLLECTORS Carl M. Lampert TWO-WEEK

  4. Effects of silica nanoparticle addition to the secondary coating of dual-coated optical fibers

    E-Print Network [OSTI]

    Matthewson, M. John

    Effects of silica nanoparticle addition to the secondary coating of dual-coated optical fibers J Available online 30 March 2006 Abstract The mechanical and optical properties of dual-coated optical fibers with silica nanoparticles added to the secondary (outer) coating have been investigated. Incorporation

  5. Friction- and wear-reducing coating

    DOE Patents [OSTI]

    Zhu, Dong (Farmington Hills, MI); Milner, Robert (Warren, MI); Elmoursi, Alaa AbdelAzim (Troy, MI)

    2011-10-18

    A coating includes a first layer of a ceramic alloy and a second layer disposed on the first layer and including carbon. The coating has a hardness of from 10 to 20 GPa and a coefficient of friction of less than or equal to 0.12. A method of coating a substrate includes cleaning the substrate, forming the first layer on the substrate, and depositing the second layer onto the first layer to thereby coat the substrate.

  6. Low Barrier Hydrogen Bonds in Acyclic Tertiary Diamines

    E-Print Network [OSTI]

    Khodagholian, Sevana

    2010-01-01

    9. S. Yaghmaei, In Search of a Low Barrier Hydrogen Bond inP.A. Frey, and J.A. Gerlt, “The Low Barrier Hydrogen Bond inConsiderations Show That Low-Barrier Hydrogen Bonds do not

  7. In situ control of lubricant properties for reduction of power cylinder friction through thermal barrier coating

    E-Print Network [OSTI]

    Molewyk, Mark Allen

    2014-01-01

    Lowering lubricant viscosity to reduce friction generally carries a side effect of increased metal-metal contact in mixed or boundary lubrication, for example near top ring reversal along the engine cylinder liner. A ...

  8. Model Studies of Pore Stability and Evolution in Thermal Barrier Coatings (TBCs)

    E-Print Network [OSTI]

    Glaeser, A M

    2008-01-01

    with their respective heat treatments Unetched SurfaceUST) Sample Name A-UST Orientation/ Heat Treatment SampleName Orientation/ Heat Treatment Sample Name Orientation/

  9. Elastodynamic erosion of thermal barrier coatings Man Wang, Norman A. Fleck* and Anthony G. Evans**

    E-Print Network [OSTI]

    Fleck, Norman A.

    ** Cambridge University, Department of Engineering, Trumpington Street, Cambridge, CB2 1PZ, UK Abstract, and typically comprises yttria-stabilized zirconia (YSZ). Oxidation resistance is achieved by an underlying

  10. Chemical vapor deposition of mullite coatings

    DOE Patents [OSTI]

    Sarin, Vinod (Lexington, MA); Mulpuri, Rao (Boston, MA)

    1998-01-01

    This invention is directed to the creation of crystalline mullite coatings having uniform microstructure by chemical vapor deposition (CVD). The process comprises the steps of establishing a flow of reactants which will yield mullite in a CVD reactor, and depositing a crystalline coating from the reactant flow. The process will yield crystalline coatings which are dense and of uniform thickness.

  11. Desert Rock Coatings Ronald I. Dorn

    E-Print Network [OSTI]

    Dorn, Ron

    Chapter 7 Desert Rock Coatings Ronald I. Dorn Introduction Desert landforms are characterized, that the supposed funda- mental bare-rock nature of desert landforms stretches the truth. In reality, rock coatings Petra tourist attraction of the Al-Khazneh Tomb fac¸ade is coated with a black manganese-rich varnish

  12. Bachelor project: Ferromagnetische radar absorberende coatings

    E-Print Network [OSTI]

    Vuik, Kees

    Bachelor project: Ferromagnetische radar absorberende coatings Begeleider: D.R. van der Heul niet alleen een bijzondere vormgeving, maar zijn ook bedekt met radar absorbing coatings. De radar absorbing coatings (RAC) zetten de inkomende elektromagnetische golven om in warmte, die vervolgens naar de

  13. Moisture Penetration Through Optical Fiber Coatings

    E-Print Network [OSTI]

    Matthewson, M. John

    Moisture Penetration Through Optical Fiber Coatings J. L. Armstrong, M. J. Matthewson and C. R Fiber Coatings Janet L. Armstrong, 1 M. John Matthewson, 1 Charles R. Kurkjian 2 1 Rutgers University for measuring the diffusion coefficients of water vapor through optical fiber polymer coatings has been

  14. Table of Contents White Coat 1

    E-Print Network [OSTI]

    Chapman, Michael S.

    Table of Contents White Coat 1 Staff Profiles 2/3/4 Recent Photos 5 New SOD'ers 6 State of School 7 on page six) Dental Bites October 2014 Class of 2017 Receives White Coats The Class of 2017 was recognized of patients. Seventy-five second-year dental students received their personalized white lab coats in a formal

  15. Constructing Hydraulic Barriers in Deep Geologic Formations

    SciTech Connect (OSTI)

    Carter, E.E.; Carter, P.E. [Technologies Co, Texas (United States); Cooper, D.C. [Ph.D. Idaho National Laboratory, Idaho Falls, ID (United States)

    2008-07-01

    Many construction methods have been developed to create hydraulic barriers to depths of 30 to 50 meters, but few have been proposed for depths on the order of 500 meters. For these deep hydraulic barriers, most methods are potentially feasible for soil but not for hard rock. In the course of researching methods of isolating large subterranean blocks of oil shale, the authors have developed a wax thermal permeation method for constructing hydraulic barriers in rock to depths of over 500 meters in competent or even fractured rock as well as soil. The technology is similar to freeze wall methods, but produces a permanent barrier; and is potentially applicable in both dry and water saturated formations. Like freeze wall barriers, the wax thermal permeation method utilizes a large number of vertical or horizontal boreholes around the perimeter to be contained. However, instead of cooling the boreholes, they are heated. After heating these boreholes, a specially formulated molten wax based grout is pumped into the boreholes where it seals fractures and also permeates radially outward to form a series of columns of wax-impregnated rock. Rows of overlapping columns can then form a durable hydraulic barrier. These barriers can also be angled above a geologic repository to help prevent influx of water due to atypical rainfall events. Applications of the technique to constructing containment structures around existing shallow waste burial sites and water shutoff for mining are also described. (authors)

  16. On the Emissivity of Silver Coated Panels, Effect of Long Term Stability and Effect of Coating Thickness

    E-Print Network [OSTI]

    On the Emissivity of Silver Coated Panels, Effect of Long Term Stability and Effect of Coating Thickness

  17. Barriers to CHP with Renewable Portfolio Standards, Draft White...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Barriers to CHP with Renewable Portfolio Standards, Draft White Paper, September 2007 Barriers to CHP with Renewable Portfolio Standards, Draft White Paper, September 2007 The...

  18. Barriers to Industrial Energy Efficiency - Report to Congress...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Report to Congress, June 2015 Barriers to Industrial Energy Efficiency - Report to Congress, June 2015 This report examines barriers that impede the adoption of energy efficient...

  19. Barriers to Industrial Energy Efficiency - Study (Appendix A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Study (Appendix A), June 2015 Barriers to Industrial Energy Efficiency - Study (Appendix A), June 2015 This study examines barriers that impede the adoption of energy efficient...

  20. Characterization of Single Barrier Microrefrigerators at Cryogenic Temperatures

    E-Print Network [OSTI]

    2009-01-01

    at Springerlink.com Characterization of Single Barriercooling) at 100 K. Characterization of Single BarrierThe experimental characterization of single barrier

  1. Thermal Bypass Air Barriers in the 2009 International Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Bypass Air Barriers in the 2009 International Energy Conservation Code - Building America Top Innovation Thermal Bypass Air Barriers in the 2009 International Energy...

  2. New Air and Water-Resistive Barrier Technologies for Commercial...

    Energy Savers [EERE]

    New Air and Water-Resistive Barrier Technologies for Commercial Buildings New Air and Water-Resistive Barrier Technologies for Commercial Buildings New Air and Water-Resistive...

  3. Overcoming Processing Cost Barriers of High-Performance Lithium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processing Cost Barriers of High-Performance Lithium-Ion Battery Electrodes Overcoming Processing Cost Barriers of High-Performance Lithium-Ion Battery Electrodes 2012 DOE Hydrogen...

  4. Market and Policy Barriers for Energy Storage Deployment

    Broader source: Energy.gov [DOE]

    Electric energy storage technologies can provide numerous grid services, there are a number of factors that restrict their current deployment. The most significant barrier to deployment is high capital costs, though several recent deployments indicate that capital costs are decreasing and energy storage may be the preferred economic alternative in certain situations. However, a number of other market and regulatory barriers persist, limiting further deployment. These barriers can be categorized into regulatory barriers, market (economic) barriers, utility and developer business model barriers, cross-cutting barriers and technology barriers.

  5. On-Bill Financing: Reducing Cost Barriers to Energy Efficiency...

    Office of Environmental Management (EM)

    On-Bill Financing: Reducing Cost Barriers to Energy Efficiency Improvements (201) On-Bill Financing: Reducing Cost Barriers to Energy Efficiency Improvements (201) October 8...

  6. February 5, 2014 Webinar - The Cementitious Barriers Partnership...

    Energy Savers [EERE]

    - The Cementitious Barriers Partnership Toolbox, Version 2.0 February 5, 2014 Webinar - Tools and Capabilities of the Cementitious Barriers Partnership Toolbox, Version 2.0 David...

  7. Geothermal Heat Pumps: Market Status, Barriers to Adoption, and...

    Open Energy Info (EERE)

    Geothermal Heat Pumps: Market Status, Barriers to Adoption, and Actions to Overcome Barriers Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Geothermal Heat Pumps:...

  8. Summary of Gaps and Barriers for Implementing Residential Building...

    Energy Savers [EERE]

    Gaps and Barriers for Implementing Residential Building Energy Efficiency Strategies Summary of Gaps and Barriers for Implementing Residential Building Energy Efficiency Strategies...

  9. Overcoming the Barrier to Achieving Large-Scale Production -...

    Office of Environmental Management (EM)

    Overcoming the Barrier to Achieving Large-Scale Production - A Case Study Overcoming the Barrier to Achieving Large-Scale Production - A Case Study This presentation summarizes the...

  10. Deployment Barriers to Distributed Wind Energy: Workshop Report...

    Energy Savers [EERE]

    Deployment Barriers to Distributed Wind Energy: Workshop Report, October 28, 2010 Deployment Barriers to Distributed Wind Energy: Workshop Report, October 28, 2010 This report...

  11. Phoenix Overcomes Barriers and Energizes Homeowners to Make Upgrades...

    Office of Environmental Management (EM)

    Phoenix Overcomes Barriers and Energizes Homeowners to Make Upgrades Phoenix Overcomes Barriers and Energizes Homeowners to Make Upgrades A photo of a residence. Energize Phoenix...

  12. Atomically Bonded Transparent Superhydrophobic Coatings

    SciTech Connect (OSTI)

    Aytug, Tolga

    2015-08-01

    Maintaining clarity and avoiding the accumulation of water and dirt on optically transparent surfaces such as US military vehicle windshields, viewports, periscope optical head windows, and electronic equipment cover glasses are critical to providing a high level of visibility, improved survivability, and much-needed safety for warfighters in the field. Through a combination of physical vapor deposition techniques and the exploitation of metastable phase separation in low-alkali borosilicate, a novel technology was developed for the fabrication of optically transparent, porous nanostructured silica thin film coatings that are strongly bonded to glass platforms. The nanotextured films, initially structurally superhydrophilic, exhibit superior superhydrophobicity, hence antisoiling ability, following a simple but robust modification in surface chemistry. The surfaces yield water droplet contact angles as high as 172°. Moreover, the nanostructured nature of these coatings provides increased light scattering in the UV regime and reduced reflectivity (i.e., enhanced transmission) over a broad range of the visible spectrum. In addition to these functionalities, the coatings exhibit superior mechanical resistance to abrasion and are thermally stable to temperatures approaching 500°C. The overall process technology relies on industry standard equipment and inherently scalable manufacturing processes and demands only nontoxic, naturally abundant, and inexpensive base materials. Such coatings, applied to the optical components of current and future combat equipment and military vehicles will provide a significant strategic advantage for warfighters. The inherent self-cleaning properties of such superhydrophobic coatings will also mitigate biofouling of optical windows exposed to high-humidity conditions and can help decrease repair/replacement costs, reduce maintenance, and increase readiness by limiting equipment downtime.

  13. UNDERWATER COATINGS FOR CONTAMINATION CONTROL

    SciTech Connect (OSTI)

    Julia L. Tripp; Kip Archibald; Ann Marie Phillips; Joseph Campbell

    2004-02-01

    The Idaho National Laboratory (INL) deactivated several aging nuclear fuel storage basins. Planners for this effort were greatly concerned that radioactive contamination present on the basin walls could become airborne as the sides of the basins became exposed during deactivation and allowed to dry after water removal. One way to control this airborne contamination was to fix the contamination in place while the pool walls were still submerged. There are many underwater coatings available on the market for marine, naval and other applications. A series of tests were run to determine whether the candidate underwater fixatives were easily applied and adhered well to the substrates (pool wall materials) found in INL fuel pools. Lab-scale experiments were conducted by applying fourteen different commercial underwater coatings to four substrate materials representative of the storage basin construction materials, and evaluating their performance. The coupons included bare concrete, epoxy painted concrete, epoxy painted carbon steel, and stainless steel. The evaluation criteria included ease of application, adherence to the four surfaces of interest, no change on water clarity or chemistry, non-hazardous in final applied form and be proven in underwater applications. A proprietary two-part, underwater epoxy owned by S. G. Pinney and Associates was selected from the underwater coatings tested for application to all four pools. Divers scrubbed loose contamination off the basin walls and floors using a ship hull scrubber and vacuumed up the sludge. The divers then applied the coating using a special powered roller with two separate heated hoses that allowed the epoxy to mix at the roller surface was used to eliminate pot time concerns. The walls were successfully coated and water was removed from the pools with no detectable airborne contamination releases.

  14. Pricing and hedging a barrier option 

    E-Print Network [OSTI]

    Bogossian, Alan

    2002-01-01

    . Monte-Carlo Simulations Many exotic derivatives, usually those that are path-dependent, cannot be computed using a closed form equation. As we have seen this, it is the case of barrier options with discontinuous barrier (daily or weekly barrier... would like to get the same price for the option each time we use the same parameter. This fact is really important in order to be able to measure the sensitivity of the option's price with respect to its determinants. A straightforward Monte Carlo...

  15. Transport Properties for Triangular Barriers in Graphene

    E-Print Network [OSTI]

    Abderrahim El Mouhafid; Ahmed Jellal

    2013-11-30

    We theoretically study the electronic transport properties of Dirac fermions through one and double triangular barriers in graphene. Using the transfer matrix method, we determine the transmission, conductance and Fano factor. They are obtained to be various parameters dependent such as well width, barrier height and barrier width. Therefore, different discussions are given and comparison with the previous significant works is done. In particular, it is shown that at Dirac point the Dirac fermions always own a minimum conductance associated with a maximum Fano factor and change their behaviors in an oscillatory way (irregularly periodical tunneling peaks) when the potential of applied voltage is increased.

  16. Approximating European Options by Rebate Barrier Options

    E-Print Network [OSTI]

    Song, Qingshuo

    2011-01-01

    When the underlying stock price is a strict local martingale process under an equivalent local martingale measure, Black-Scholes PDE associated with an European option may have multiple solutions. In this paper, we study an approximation for the smallest hedging price of such an European option. Our results show that a class of rebate barrier options can be used for this approximation, when its rebate and barrier are chosen appropriately. An asymptotic convergence rate is also achieved when the knocked-out barrier moves to infinity under suitable conditions.

  17. Method for forming a barrier layer

    DOE Patents [OSTI]

    Weihs, Timothy P. (Baltimore, MD); Barbee, Jr., Troy W. (Palo Alto, CA)

    2002-01-01

    Cubic or metastable cubic refractory metal carbides act as barrier layers to isolate, adhere, and passivate copper in semiconductor fabrication. One or more barrier layers of the metal carbide are deposited in conjunction with copper metallizations to form a multilayer characterized by a cubic crystal structure with a strong (100) texture. Suitable barrier layer materials include refractory transition metal carbides such as vanadium carbide (VC), niobium carbide (NbC), tantalum carbide (TaC), chromium carbide (Cr.sub.3 C.sub.2), tungsten carbide (WC), and molybdenum carbide (MoC).

  18. Corrosion prevention by protective coatings, Second edition

    SciTech Connect (OSTI)

    Munger, C.G.; Vincent, L.D.

    1999-07-01

    This much-used and relied upon book has been revised and updated by Louis D. Vincent to create the second edition. The comprehensive text covers all aspects of the use of high-performance coatings, including an introduction to corrosion as related to coatings, coating characteristics, influence of substrates, organic and zinc coatings, inspection, training, and others. Two new chapters, on elastomeric linings and computer-assisted coatings project management programs, treat new technology developed since the first edition was published. The book is a comprehensive reference tool for engineers, paint superintendents, and maintenance personnel.

  19. Method for making nanoporous hydrophobic coatings

    SciTech Connect (OSTI)

    Fan, Hongyou

    2013-04-23

    A simple coating method is used to form nanoporous hydrophobic films that can be used as optical coatings. The method uses evaporation-induced self-assembly of materials. The coating method starts with a homogeneous solution comprising a hydrophobic polymer and a surfactant polymer in a selective solvent. The solution is coated onto a substrate. The surfactant polymer forms micelles with the hydrophobic polymer residing in the particle core when the coating is dried. The surfactant polymer can be dissolved and selectively removed from the separated phases by washing with a polar solvent to form the nanoporous hydrophobic film.

  20. Channel cracks in atomic-layer and molecular-layer deposited multilayer thin film coatings

    SciTech Connect (OSTI)

    Long, Rong, E-mail: rlongmech@gmail.com [Department of Mechanical Engineering, University of Alberta, Edmonton, Alberta T6G 2G8 (Canada); Department of Mechanical Engineering, University of Colorado, Boulder, Colorado 80309 (United States); Dunn, Martin L. [Department of Mechanical Engineering, University of Colorado, Boulder, Colorado 80309 (United States); Singapore University of Technology and Design, Singapore 138682 (Singapore)

    2014-06-21

    Metal oxide thin film coatings produced by atomic layer deposition have been shown to be an effective permeation barrier. The primary failure mode of such coatings under tensile loads is the propagation of channel cracks that penetrate vertically into the coating films. Recently, multi-layer structures that combine the metal oxide material with relatively soft polymeric layers produced by molecular layer deposition have been proposed to create composite thin films with desired properties, including potentially enhanced resistance to fracture. In this paper, we study the effects of layer geometry and material properties on the critical strain for channel crack propagation in the multi-layer composite films. Using finite element simulations and a thin-film fracture mechanics formalism, we show that if the fracture energy of the polymeric layer is lower than that of the metal oxide layer, the channel crack tends to penetrate through the entire composite film, and dividing the metal oxide and polymeric materials into thinner layers leads to a smaller critical strain. However, if the fracture energy of the polymeric material is high so that cracks only run through the metal oxide layers, more layers can result in a larger critical strain. For intermediate fracture energy of the polymer material, we developed a design map that identifies the optimal structure for given fracture energies and thicknesses of the metal oxide and polymeric layers. These results can facilitate the design of mechanically robust permeation barriers, an important component for the development of flexible electronics.

  1. Determining collective barrier operation skew in a parallel computer

    DOE Patents [OSTI]

    Faraj, Daniel A.

    2015-12-24

    Determining collective barrier operation skew in a parallel computer that includes a number of compute nodes organized into an operational group includes: for each of the nodes until each node has been selected as a delayed node: selecting one of the nodes as a delayed node; entering, by each node other than the delayed node, a collective barrier operation; entering, after a delay by the delayed node, the collective barrier operation; receiving an exit signal from a root of the collective barrier operation; and measuring, for the delayed node, a barrier completion time. The barrier operation skew is calculated by: identifying, from the compute nodes' barrier completion times, a maximum barrier completion time and a minimum barrier completion time and calculating the barrier operation skew as the difference of the maximum and the minimum barrier completion time.

  2. Electrical contact arrangement for a coating process

    SciTech Connect (OSTI)

    Kabagambe, Benjamin; McCamy, James W; Boyd, Donald W

    2013-09-17

    A protective coating is applied to the electrically conductive surface of a reflective coating of a solar mirror by biasing a conductive member having a layer of a malleable electrically conductive material, e.g. a paste, against a portion of the conductive surface while moving an electrodepositable coating composition over the conductive surface. The moving of the electrodepositable coating composition over the conductive surface includes moving the solar mirror through a flow curtain of the electrodepositable coating composition and submerging the solar mirror in a pool of the electrodepositable coating composition. The use of the layer of a malleable electrically conductive material between the conductive member and the conductive surface compensates for irregularities in the conductive surface being contacted during the coating process thereby reducing the current density at the electrical contact area.

  3. Armor systems including coated core materials

    DOE Patents [OSTI]

    Chu, Henry S. (Idaho Falls, ID); Lillo, Thomas M. (Idaho Falls, ID); McHugh, Kevin M. (Idaho Falls, ID)

    2012-07-31

    An armor system and method involves providing a core material and a stream of atomized coating material that comprises a liquid fraction and a solid fraction. An initial layer is deposited on the core material by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is less than the liquid fraction of the stream of atomized coating material on a weight basis. An outer layer is then deposited on the initial layer by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is greater than the liquid fraction of the stream of atomized coating material on a weight basis.

  4. Armor systems including coated core materials

    DOE Patents [OSTI]

    2013-10-08

    An armor system and method involves providing a core material and a stream of atomized coating material that comprises a liquid fraction and a solid fraction. An initial layer is deposited on the core material by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is less than the liquid fraction of the stream of atomized coating material on a weight basis. An outer layer is then deposited on the initial layer by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is greater than the liquid fraction of the stream of atomized coating material on a weight basis.

  5. ULTRA BARRIER TOPSHEET (UBT) FOR FLEXIBLE PHOTOVOLTAICS

    SciTech Connect (OSTI)

    Alan, Nachtigal; Berniard, Tracie; Murray, Bill; Roehrig, Mark; Schubert, Charlene; Spagnola, Joseph; Weigel, Mark

    2013-01-01

    This poster describes the 3M Ultra-Barrier Solar Film and its application; production scale-up and data; reliability and qualification testing; and improvements in the next generation.

  6. Evapotranspiration studies for protective barriers: Experimental plans

    SciTech Connect (OSTI)

    Link, S.O.; Waugh, W.J.

    1989-11-01

    This document describes a general theory and experimental plans for predicting evapotranspiration in support of the Protective Barrier Program. Evapotranspiration is the combined loss of water from plants and soil surfaces to the atmosphere. 45 refs., 1 fig., 4 tabs.

  7. Underwater Sensor Barriers with Auction Stanley Barr

    E-Print Network [OSTI]

    Liu, Benyuan

    underwater pathways of them. This approach may require deploying large-scale underwater sensor networks network to detect moving objects. In 2-dimensional (2D) terrestrial strip sensor networks, a barrier

  8. Modeling of Residential Attics with Radiant Barriers 

    E-Print Network [OSTI]

    Wilkes, K. E.

    1988-01-01

    This paper gives a summary of the efforts at ORNL in modeling residential attics with radiant barriers. Analytical models based on a system of macroscopic heat balances have been developed. Separate models have been developed for horizontal radiant...

  9. ULTRA BARRIER TOPSHEET (UBT) FOR FLEXIBLE PHOTOVOLTAICS

    SciTech Connect (OSTI)

    DeScioli, Derek

    2013-06-01

    This slide-show presents 3M photovoltaic-related products, particularly flexible components. Emphasis is on the 3M Ultra Barrier Solar Films. Topics covered include reliability and qualification testing and flexible photovoltaic encapsulation costs.

  10. Photovoltaic and thermophotovoltaic devices with quantum barriers

    DOE Patents [OSTI]

    Wernsman, Bernard R. (Jefferson Hills, PA)

    2007-04-10

    A photovoltaic or thermophotovoltaic device includes a diode formed by p-type material and n-type material joined at a p-n junction and including a depletion region adjacent to said p-n junction, and a quantum barrier disposed near or in the depletion region of the p-n junction so as to decrease device reverse saturation current density while maintaining device short circuit current density. In one embodiment, the quantum barrier is disposed on the n-type material side of the p-n junction and decreases the reverse saturation current density due to electrons while in another, the barrier is disposed on the p-type material side of the p-n junction and decreases the reverse saturation current density due to holes. In another embodiment, both types of quantum barriers are used.

  11. Liquid junction schottky barrier solar cell

    DOE Patents [OSTI]

    Williams, Richard (Princeton, NJ)

    1980-01-01

    A mixture of ceric ions (Ce.sup.+4) and cerous ions (Ce.sup.+3) in an aqueous electrolyte solution forms a Schottky barrier at the interface between an active region of silicon and the electrolyte solution. The barrier height obtained for hydrogenated amorphous silicon using the Ce.sup.+4 /Ce.sup.+3 redox couple is about 1.7 eV.

  12. Field study plan for alternate barriers

    SciTech Connect (OSTI)

    Freeman, H.D.; Gee, G.W.; Relyea, J.F.

    1989-05-01

    Pacific Northwest Laboratory (PNL) is providing technical assistance in selecting, designing, evaluating, and demonstrating protective barriers. As part of this technical assistance effort, asphalt, clay, and chemical grout will be evaluated for use as alternate barriers. The purpose of the subsurface layer is to reduce the likelihood that extreme events (i.e., 100-year maximum storms, etc.) will cause significant drainage through the barrier. The tests on alternate barriers will include laboratory and field analysis of the subsurface layer performance. This field test plan outlines the activities required to test and design subsurface moisture barriers. The test plan covers activities completed in FY 1988 and planned through FY 1992 and includes a field-scale test of one or more of the alternate barriers to demonstrate full-scale application techniques and to provide performance data on a larger scale. Tests on asphalt, clay, and chemical grout were initiated in FY 1988 in small (30.5 cm diameter) tube-layer lysimeters. The parameters used for testing the materials were different for each one. The tests had to take into account the differences in material characteristics and response to change in conditions, as well as information provided by previous studies. 33 refs., 8 figs., 1 tab.

  13. High temperature solar selective coatings

    DOE Patents [OSTI]

    Kennedy, Cheryl E

    2014-11-25

    Improved solar collectors (40) comprising glass tubing (42) attached to bellows (44) by airtight seals (56) enclose solar absorber tubes (50) inside an annular evacuated space (54. The exterior surfaces of the solar absorber tubes (50) are coated with improved solar selective coatings {48} which provide higher absorbance, lower emittance and resistance to atmospheric oxidation at elevated temperatures. The coatings are multilayered structures comprising solar absorbent layers (26) applied to the meta surface of the absorber tubes (50), typically stainless steel, topped with antireflective Savers (28) comprising at least two layers 30, 32) of refractory metal or metalloid oxides (such as titania and silica) with substantially differing indices of refraction in adjacent layers. Optionally, at least one layer of a noble metal such as platinum can be included between some of the layers. The absorbent layers cars include cermet materials comprising particles of metal compounds is a matrix, which can contain oxides of refractory metals or metalloids such as silicon. Reflective layers within the coating layers can comprise refractory metal silicides and related compounds characterized by the formulas TiSi. Ti.sub.3SiC.sub.2, TiAlSi, TiAN and similar compounds for Zr and Hf. The titania can be characterized by the formulas TiO.sub.2, Ti.sub.3O.sub.5. TiOx or TiO.sub.xN.sub.1-x with x 0 to 1. The silica can be at least one of SiO.sub.2, SiO.sub.2x or SiO.sub.2xN.sub.1-x with x=0 to 1.

  14. Pedestal substrate for coated optics

    DOE Patents [OSTI]

    Hale, Layton C. (Livermore, CA); Malsbury, Terry N. (Tracy, CA); Patterson, Steven R. (Concord, NC)

    2001-01-01

    A pedestal optical substrate that simultaneously provides high substrate dynamic stiffness, provides low surface figure sensitivity to mechanical mounting hardware inputs, and constrains surface figure changes caused by optical coatings to be primarily spherical in nature. The pedestal optical substrate includes a disk-like optic or substrate section having a top surface that is coated, a disk-like base section that provides location at which the substrate can be mounted, and a connecting cylindrical section between the base and optics or substrate sections. The connecting cylindrical section may be attached via three spaced legs or members. However, the pedestal optical substrate can be manufactured from a solid piece of material to form a monolith, thus avoiding joints between the sections, or the disk-like base can be formed separately and connected to the connecting section. By way of example, the pedestal optical substrate may be utilized in the fabrication of optics for an extreme ultraviolet (EUV) lithography imaging system, or in any optical system requiring coated optics and substrates with reduced sensitivity to mechanical mounts.

  15. Kinetic regulation of coated vesicle secretion

    E-Print Network [OSTI]

    Lionel Foret; Pierre Sens

    2008-07-28

    The secretion of vesicles for intracellular transport often rely on the aggregation of specialized membrane-bound proteins into a coat able to curve cell membranes. The nucleation and growth of a protein coat is a kinetic process that competes with the energy-consuming turnover of coat components between the membrane and the cytosol. We propose a generic kinetic description of coat assembly and the formation of coated vesicles, and discuss its implication to the dynamics of COP vesicles that traffic within the Golgi and with the Endoplasmic Reticulum. We show that stationary coats of fixed area emerge from the competition between coat growth and the recycling of coat components, in a fashion resembling the treadmilling of cytoskeletal filaments. We further show that the turnover of coat components allows for a highly sensitive switching mechanism between a quiescent and a vesicle producing membrane, upon a slowing down of the exchange kinetics. We claim that the existence of this switching behaviour, also triggered by factors such as the presence of cargo and variation of the membrane mechanical tension, allows for efficient regulation of vesicle secretion. We propose a model, supported by different experimental observations, in which vesiculation of secretory membranes is impaired by the energy consuming desorption of coat proteins, until the presence of cargo or other factors triggers a dynamical switch into a vesicle producing state.

  16. Sputter target erosion and its effects on long duration DC magnetron sputter coating

    E-Print Network [OSTI]

    Schoff, Michael Elliott

    2009-01-01

    Duration DC Magnetron Sputter Coating A thesis submitted in1 II. Sputter Coating24 VII. Coating Rate vs.

  17. Anisotropic capillary barrier for waste site surface covers

    DOE Patents [OSTI]

    Stormont, John C. (Sandia Park, NM)

    1996-01-01

    Waste sites are capped or covered upon closure. The cover structure incorporates a number of different layers each having a contributory function. One such layer is the barrier layer. Traditionally the barriers have been compacted soil and geosynthetics. These types of barriers have not been successfully implemented in unsaturated ground conditions like those found in dry climates. Capillary barriers have been proposed as barrier layers in dry environments, but the divergence length of these barriers has been found to be inadequate. An alternative to the capillary barrier is a anisotropic capillary barrier. An anisotropic capillary barrier has an increased divergence length which results in more water being diverted laterally preventing the majority of water from percolating in a downward direction through the barrier.

  18. Longitudinal phase-space coating of beam in a storage ring

    E-Print Network [OSTI]

    Bhat, C M

    2015-01-01

    In this Letter, I report on a novel scheme for beam stacking without any beam emittance dilution using a barrier rf system in synchrotrons. The general principle of the scheme called longitudinal phase-space coating, validation of the concept via multi-particle beam dynamics simulations applied to the Fermilab Recycler, and its experimental demonstration are presented. In addition, it has been shown and illustrated that the rf gymnastics involved in this scheme can be used in measuring the incoherent synchrotron tune spectrum of the beam in barrier buckets and in producing a clean hollow beam in longitudinal phase space. The method of beam stacking in synchrotrons presented here is the first of its kind.

  19. Schottky barrier MOSFET systems and fabrication thereof

    DOE Patents [OSTI]

    Welch, James D. (10328 Pinehurst Ave., Omaha, NE 68124)

    1997-01-01

    (MOS) device systems-utilizing Schottky barrier source and drain to channel region junctions are disclosed. Experimentally derived results which demonstrate operation of fabricated N-channel and P-channel Schottky barrier (MOSFET) devices, and of fabricated single devices with operational characteristics similar to (CMOS) and to a non-latching (SRC) are reported. Use of essentially non-rectifying Schottky barriers in (MOS) structures involving highly doped and the like and intrinsic semiconductor to allow non-rectifying interconnection of, and electrical accessing of device regions is also disclosed. Insulator effected low leakage current device geometries and fabrication procedures therefore are taught. Selective electrical interconnection of drain to drain, source to drain, or source to source, of N-channel and/or P-channel Schottky barrier (MOSFET) devices formed on P-type, N-type and Intrinsic semiconductor allows realization of Schottky Barrier (CMOS), (MOSFET) with (MOSFET) load, balanced differential (MOSFET) device systems and inverting and non-inverting single devices with operating characteristics similar to (CMOS), which devices can be utilized in modulation, as well as in voltage controled switching and effecting a direction of rectification.

  20. Methods for fabricating a micro heat barrier

    DOE Patents [OSTI]

    Marshall, Albert C.; Kravitz, Stanley H.; Tigges, Chris P.; Vawter, Gregory A.

    2004-01-06

    Methods for fabricating a highly effective, micron-scale micro heat barrier structure and process for manufacturing a micro heat barrier based on semiconductor and/or MEMS fabrication techniques. The micro heat barrier has an array of non-metallic, freestanding microsupports with a height less than 100 microns, attached to a substrate. An infrared reflective membrane (e.g., 1 micron gold) can be supported by the array of microsupports to provide radiation shielding. The micro heat barrier can be evacuated to eliminate gas phase heat conduction and convection. Semi-isotropic, reactive ion plasma etching can be used to create a microspike having a cusp-like shape with a sharp, pointed tip (<0.1 micron), to minimize the tip's contact area. A heat source can be placed directly on the microspikes. The micro heat barrier can have an apparent thermal conductivity in the range of 10.sup.-6 to 10.sup.-7 W/m-K. Multiple layers of reflective membranes can be used to increase thermal resistance.

  1. Enhanced Densification of SDC Barrier Layers

    SciTech Connect (OSTI)

    Hardy, John S.; Templeton, Jared W.; Lu, Zigui; Stevenson, Jeffry W.

    2011-09-12

    This technical report explores the Enhanced Densification of SCD Barrier Layers A samaria-doped ceria (SDC) barrier layer separates the lanthanum strontium cobalt ferrite (LSCF) cathode from the yttria-stabilized zirconia (YSZ) electrolyte in a solid oxide fuel cell (SOFC) to prevent the formation of electrically resistive interfacial SrZrO{sub 3} layers that arise from the reaction of Sr from the LSCF with Zr from the YSZ. However, the sintering temperature of this SDC layer must be limited to {approx}1200 C to avoid extensive interdiffusion between SDC and YSZ to form a resistive CeO{sub 2}-ZrO{sub 2} solid solution. Therefore, the conventional SDC layer is often porous and therefore not as impervious to Sr-diffusion as would be desired. In the pursuit of improved SOFC performance, efforts have been directed toward increasing the density of the SDC barrier layer without increasing the sintering temperature. The density of the SDC barrier layer can be greatly increased through small amounts of Cu-doping of the SDC powder together with increased solids loading and use of an appropriate binder system in the screen print ink. However, the resulting performance of cells with these barrier layers did not exhibit the expected increase in accordance with that achieved with the prototypical PLD SDC layer. It was determined by XRD that increased sinterability of the SDC also results in increased interdiffusivity between the SDC and YSZ, resulting in formation of a highly resistive solid solution.

  2. Coated Metal Articles and Method of Making

    DOE Patents [OSTI]

    Boller, Ernest R.; Eubank, Lowell D.

    2004-07-06

    The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

  3. Coated metal articles and method of making

    DOE Patents [OSTI]

    Boller, Ernest R. (Van Buren Township, IN); Eubank, Lowell D. (Wilmington, DE)

    2004-07-06

    The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

  4. Optical coatings for laser fusion applications

    SciTech Connect (OSTI)

    Lowdermilk, W.H.; Milam, D.; Rainer, F.

    1980-04-24

    Lasers for fusion experiments use thin-film dielectric coatings for reflecting, antireflecting and polarizing surface elements. Coatings are most important to the Nd:glass laser application. The most important requirements of these coatings are accuracy of the average value of reflectance and transmission, uniformity of amplitude and phase front of the reflected or transmitted light, and laser damage threshold. Damage resistance strongly affects the laser's design and performance. The success of advanced lasers for future experiments and for reactor applications requires significant developments in damage resistant coatings for ultraviolet laser radiation.

  5. Method of identifying defective particle coatings

    DOE Patents [OSTI]

    Cohen, Mark E. (San Diego, CA); Whiting, Carlton D. (San Diego, CA)

    1986-01-01

    A method for identifying coated particles having defective coatings desig to retain therewithin a build-up of gaseous materials including: (a) Pulling a vacuum on the particles; (b) Backfilling the particles at atmospheric pressure with a liquid capable of wetting the exterior surface of the coated particles, said liquid being a compound which includes an element having an atomic number higher than the highest atomic number of any element in the composition which forms the exterior surface of the particle coating; (c) Drying the particles; and (d) Radiographing the particles. By television monitoring, examination of the radiographs is substantially enhanced.

  6. Coating Active Materials for Applications in Electrochemical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coating Active Materials for Applications in Electrochemical Devices Technology available for licensing: A process that includes suspendingdissolving an electro-active material...

  7. Prediction of tilted capillary barrier performance

    SciTech Connect (OSTI)

    Webb, S.W.; McCord, J.T.; Dwyer, S.F.

    1997-04-01

    Capillary barriers, consisting of tilted fine-over-coarse layers under unsaturated conditions, have been suggested as landfill covers to divert water infiltration away from sensitive underground regions, especially for arid and semi-arid regions. The Hydrological Evaluation of Landfill Performance (HELP) computer code is an evaluation tool for landfill covers used by designers and regulators. HELP is a quasi-two-dimensional model that predicts moisture movement into and through the underground soil and waste layers. Processes modeled within HELP include precipitation, runoff, evapotranspiration, unsaturated vertical drainage, saturated lateral drainage, and leakage through liners. Unfortunately, multidimensional unsaturated flow phenomena that are necessary for evaluating tilted capillary barriers are not included in HELP. Differences between the predictions of the HELP and those from a multidimensional unsaturated flow code are presented to assess the two different approaches. Comparisons are presented for the landfill covers including capillary barrier configurations at the Alternative Landfill Cover Demonstration (ALCD) being conducted at Sandia.

  8. Plastic yield inception of an indented coated flat and comparison with a flattened coated sphere

    E-Print Network [OSTI]

    Siegel, Paul H.

    . Introduction In many engineering applications, such as cutting tools, hard disk drives and electrical circuitsPlastic yield inception of an indented coated flat and comparison with a flattened coated sphere Keywords: Spherical indentation Hard coating Yield inception a b s t r a c t The yield inception

  9. Grain boundaries in coated conductors

    E-Print Network [OSTI]

    Weigand, Marcus

    2010-07-06

    ,757 • Bibliography: 5,087 ix Publications and Conference Presentations This thesis led to the following publications: • M. Weigand, S. C. Speller, G. M. Hughes, N. A. Rutter, S. Lozano-Perez, C. R. M. Grovenor and J. H. Durrell: “Individual grain boundary properties... and overall performance of metal-organic deposition coated conductors ”, Phys. Rev. B 81, 174537 (2010) • R. Hühne, J. Eickemeyer, V. S. Sarma, A. Güth, T. Thersleff, J. Freudenberger, O. de Haas, M. Weigand, J. H. Durrell, L. Schultz and B. Holzapfel: “Ap...

  10. Underwater Coatings for Contamination Control

    SciTech Connect (OSTI)

    Julia L. Tripp; Kip Archibald; Ann-Marie Phillips; Joseph Campbell

    2004-02-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) is deactivating several fuel storage basins. Airborne contamination is a concern when the sides of the basins are exposed and allowed to dry during water removal. One way of controlling this airborne contamination is to fix the contamination in place while the pool walls are still submerged. There are many underwater coatings available on the market that are used in marine, naval and other applications. A series of tests were run to determine whether the candidate underwater fixatives are easily applied and adhere well to the substrates (pool wall materials) found in INEEL fuel pools. The four pools considered included 1) Test Area North (TAN-607) with epoxy painted concrete walls; 2) Idaho Nuclear Technology and Engineering Center (INTEC) (CPP-603) with bare concrete walls; 3) Materials Test Reactor (MTR) Canal with stainless steel lined concrete walls; and 4) Power Burst Facility (PBF-620) with stainless steel lined concrete walls on the bottom and epoxy painted carbon steel lined walls on the upper portions. Therefore, the four materials chosen for testing included bare concrete, epoxy painted concrete, epoxy painted carbon steel, and stainless steel. The typical water temperature of the pools varies from 55oF to 80oF dependent on the pool and the season. These tests were done at room temperature. The following criteria were used during this evaluation. The underwater coating must: · Be easy to apply · Adhere well to the four surfaces of interest · Not change or have a negative impact on water chemistry or clarity · Not be hazardous in final applied form · Be proven in other underwater applications. In addition, it is desirable for the coating to have a high pigment or high cross-link density to prevent radiation from penetrating. This paper will detail the testing completed and the test results. A proprietary two-part, underwater epoxy owned by S. G. Pinney and Associates was selected to be applied by divers after scrubbing loose contamination off the basin walls and floors using a ship hull scrubber and vacuuming up the sludge. A special powered roller with two separate heated hoses that allowed the epoxy to mix at the roller surface was used to eliminate pot time concerns. The walls were successfully coated and water was removed from the pool with no airborne contamination problems.

  11. Pressurized security barrier and alarm system

    DOE Patents [OSTI]

    Carver, Don W. (Knoxville, TN)

    1995-01-01

    A security barrier for placement across a passageway is made up of interconnected pressurized tubing made up in a grid pattern with openings too small to allow passage. The tubing is connected to a pressure switch, located away from the barrier site, which activates an alarm upon occurrence of a pressure drop. A reinforcing bar is located inside and along the length of the tubing so as to cause the tubing to rupture and set off the alarm upon an intruder's making an attempt to crimp and seal off a portion of the tubing by application of a hydraulic tool. Radial and rectangular grid patterns are disclosed.

  12. Pressurized security barrier and alarm system

    DOE Patents [OSTI]

    Carver, D.W.

    1995-04-11

    A security barrier for placement across a passageway is made up of interconnected pressurized tubing made up in a grid pattern with openings too small to allow passage. The tubing is connected to a pressure switch, located away from the barrier site, which activates an alarm upon occurrence of a pressure drop. A reinforcing bar is located inside and along the length of the tubing so as to cause the tubing to rupture and set off the alarm upon an intruder`s making an attempt to crimp and seal off a portion of the tubing by application of a hydraulic tool. Radial and rectangular grid patterns are disclosed. 7 figures.

  13. Exploring PropertiesSurface Coatings: Nano-Toss! Try this!

    E-Print Network [OSTI]

    Exploring Properties­Surface Coatings: Nano-Toss! Try this! 1. Presenter. Visitors experiment with modifying nano-ball's surface with different coatings: polymers, or decorative rhinestone-like stickers, or electrical tape.) 3. Visitors throw the coated

  14. FIRE IMPACTS ON AN ENGINEERED BARRIER’S PERFORMANCE: THE HANFORD BARRIER ONE YEAR AFTER A CONTROLLED BURN

    SciTech Connect (OSTI)

    Ward, Anderson L.; Link, Steven O.; Leary, Kevin D.; Berlin, Gregory T.

    2010-03-31

    A critical unknown for long-term engineered barrier performance is the effect of wild fire during a post-institutional control environment where routine maintenance may be limited or non-existent. In September 2008, a controlled burn was conducted on one half of a vegetated, multilayered capillary barrier emplaced over a Hanford waste site. The effects on barrier performance have been monitored and documented over the past year. Soil physical, chemical, and hydrologic properties; plant floristics and density; and animal-use were characterized before and after the fire with the unburned half of the barrier serving as a control. Temperatures during the controlled burn ranged from 250 oC at 1.5 cm below the surface to over 700 oC at 1 m above the surface. Significant decreases in hydraulic conductivity and surface-soil wettability were observed immediately after the fire due primarily to hydrophobic conditions created by the fire. Major soil nutrients, pH, and electrical conductivity remain elevated post-fire. Up until June 2009, post-burn soil moisture content in the 0-1 m depth interval was significantly lower on the burned section than the unburned section and is attributed to differences in surface evaporation. Higher soil moisture contents in the 1-2 m interval on the burned section are attributed to insignificant water uptake owing to the absence of deep-rooted shrubs. Moisture profiles reversed after June to show lower water contents throughout the profile on the unburned section. Dense stands of sagebrush were destroyed from the fire allowing many more species to emerge thereby increasing species diversity. Seed sources contributing to this species diversification were from either the existing seedbank and/or wind-blown sources. Measurements are ongoing and the results are expected to help close a knowledge gap about barrier recovery after major disturbances.

  15. W-Coating for MEMS

    SciTech Connect (OSTI)

    Fleming, J.G.; Mani, S.S.; Sniegowski, J.J.

    1999-07-08

    The integration of miniaturized mechanical components has spawned a new technology known as microelectromechanical systems (MEMS). Surface micromachining, defined as the fabrication of micromechanical structures from deposited thin films, is one of the core technological processes underlying MEMS. Surface micromachined structures have a large ratio of surface area to volume which makes them particularly vulnerable to adhesion to the substrate or adjacent structures during release or in use--a problem is called stiction. Since microactuators can have surfaces in normal or sliding contact, function and wear are critical issues for reliable operation of MEMS devices. Surface modifications are needed to reduce adhesion and friction in micromechanical structures. In this paper, we will present a process used to selectively coat MEMS devices with Tungsten using a CVD (Chemical Vapor Deposition) process. We will discuss the effect of wet and vapor phase cleans along with different process variables. Endurance of the W coating is important, especially in applications where wear due to repetitive contacts with the film may occur. Further, tungsten is hard and chemically inert, Tungsten CVD is used in the integrated-circuit industry, which makes this, approach manufacturable.

  16. Measure Guideline. Transitioning From Three-Coat Stucco to One-Coat Stucco With EPS

    SciTech Connect (OSTI)

    Brozyna, K.; Davis, G.; Rapport, A.

    2012-04-01

    This measure guideline has been developed to help builders transition from using a traditional three-coat stucco wall-cladding system to a one-coat stucco wall-cladding system with expanded polystyrene (EPS) insulated sheathing. The one-coat system maintains the look of a traditional stucco system but uses only a base layer and a finish coat over EPS insulation that achieves higher levels of energy efficiency. Potential risks associated with the installation of a one-coat stucco system are addressed in terms of design, installation, and warranty concerns such as cracking and delamination, along with mitigation strategies to reduce these risks.

  17. Flexible Ultra Moisture Barrier Film for Thin-Film Photovoltaic Applications

    SciTech Connect (OSTI)

    David M. Dean

    2012-10-30

    Flexible Thin-film photovoltaic (TFPV) is a low cost alternative to incumbent c-Si PV products as it requires less volume of costly semiconductor materials and it can potentially reduce installation cost. Among the TFPV options, copper indium gallium diselenide (CIGS) has the highest efficiency and is believed to be one of the most attractive candidates to achieve PV cost reduction. However, CIGS cells are very moisture sensitive and require module water vapor transmission rate (WVTR) of less than 1x10-4 gram of water per square meter per day (g-H2O/m2/day). Successful development and commercialization of flexible transparent ultra moisture barrier film is the key to enable flexible CIGS TFPV products, and thus enable ultimate PV cost reduction. At DuPont, we have demonstrated at lab scale that we can successfully make polymer-based flexible transparent ultra moisture barrier film by depositing alumina on polymer films using atomic layer deposition (ALD) technology. The layer by layer ALD approach results in uniform and amorphous structure which effectively reduces pinhole density of the inorganic coating on the polymer, and thus allow the fabrication of flexible barrier film with WVTR of 10-5 g-H2O/m2/day. Currently ALD is a time-consuming process suitable only for high-value, relatively small substrates. To successfully commercialize the ALD-on-plastic technology for the PV industry, there is the need to scale up this technology and improve throughput. The goal of this contract work was to build a prototype demonstrating that the ALD technology could be scaled-up for commercial use. Unfortunately, the prototype failed to produce an ultra-barrier film by the close of the project.

  18. Cationic electrodepositable coating composition comprising lignin

    DOE Patents [OSTI]

    Fenn, David; Bowman, Mark P; Zawacky, Steven R; Van Buskirk, Ellor J; Kamarchik, Peter

    2013-07-30

    A cationic electrodepositable coating composition is disclosed. The present invention in directed to a cationic electrodepositable coating composition comprising a lignin-containing cationic salt resin, that comprises (A) the reaction product of: lignin, an amine, and a carbonyl compound; (B) the reaction product of lignin, epichlorohydrin, and an amine; or (C) combinations thereof.

  19. Automatic Object Colocation Based on Read Barriers

    E-Print Network [OSTI]

    Mössenböck, Hanspeter

    matches their access order in the program. We implemented this optimization for Sun Microsystems' Java HotSpotTM VM. The garbage collector, which moves objects during collection, assigns consecutive ad- dresses-called hot-field tables, which are then used by the garbage collector for colocation decisions. Read barriers

  20. RealReal heterojunctionsheterojunctions Schottky barrier current

    E-Print Network [OSTI]

    Pulfrey, David L.

    -EFFICIENCY CDTE AND CIGS THIN-FILM SOLAR CELLS: HIGHLIGHTS AND CHALLENGES. National Renewable Energy Laboratory1 RealReal heterojunctionsheterojunctions LECTURE 9 · Schottky barrier current · CdS/CIGS · Energy is the forward-bias current? #12;33 HeterostructureHeterostructure, thin film, cells: a lower, thin film, cells

  1. Radiant Barrier Performance during the Heating Season 

    E-Print Network [OSTI]

    Medina, M. A.; O'Neal, D. L.; Turner, W. D.

    1992-01-01

    . Extra null tests limit the number of radiant barrier tests that can be performed during short winter periods. However. nul1tesL~ were run during the months of June 1990 and April 1991 which confirmed that the houses still responded similarly...

  2. Ranking websites through prioritized web accessibility barriers

    E-Print Network [OSTI]

    Brajnik, Giorgio

    of these comments apply as well to the current WCAG 2.0 draft, to Section 508 and to the Italian official technical criteria in WCAG 2.0), or when they do it (like priority levels in WCAG 1.0) they do not depend on specificRanking websites through prioritized web accessibility barriers Giorgio Brajnik Dip. di Matematica

  3. Barrier Immune Radio Communications for Demand Response

    E-Print Network [OSTI]

    LBNL-2294E Barrier Immune Radio Communications for Demand Response F. Rubinstein, G. Ghatikar, J Ann Piette of Lawrence Berkeley National Laboratory's (LBNL) Demand Response Research Center (DRRC and Environment's (CIEE) Demand Response Emerging Technologies Development (DRETD) Program, under Work for Others

  4. Nanoscale Reinforced, Polymer Derived Ceramic Matrix Coatings

    SciTech Connect (OSTI)

    Rajendra Bordia

    2009-07-31

    The goal of this project was to explore and develop a novel class of nanoscale reinforced ceramic coatings for high temperature (600-1000 C) corrosion protection of metallic components in a coal-fired environment. It was focused on developing coatings that are easy to process and low cost. The approach was to use high-yield preceramic polymers loaded with nano-size fillers. The complex interplay of the particles in the polymer, their role in controlling shrinkage and phase evolution during thermal treatment, resulting densification and microstructural evolution, mechanical properties and effectiveness as corrosion protection coatings were investigated. Fe-and Ni-based alloys currently used in coal-fired environments do not possess the requisite corrosion and oxidation resistance for next generation of advanced power systems. One example of this is the power plants that use ultra supercritical steam as the working fluid. The increase in thermal efficiency of the plant and decrease in pollutant emissions are only possible by changing the properties of steam from supercritical to ultra supercritical. However, the conditions, 650 C and 34.5 MPa, are too severe and result in higher rate of corrosion due to higher metal temperatures. Coating the metallic components with ceramics that are resistant to corrosion, oxidation and erosion, is an economical and immediate solution to this problem. Good high temperature corrosion protection ceramic coatings for metallic structures must have a set of properties that are difficult to achieve using established processing techniques. The required properties include ease of coating complex shapes, low processing temperatures, thermal expansion match with metallic structures and good mechanical and chemical properties. Nanoscale reinforced composite coatings in which the matrix is derived from preceramic polymers have the potential to meet these requirements. The research was focused on developing suitable material systems and processing techniques for these coatings. In addition, we investigated the effect of microstructure on the mechanical properties and oxidation protection ability of the coatings. Coatings were developed to provide oxidation protection to both ferritic and austentic alloys and Ni-based alloys. The coatings that we developed are based on low viscosity pre-ceramic polymers. Thus they can be easily applied to any shape by using a variety of techniques including dip-coating, spray-coating and painting. The polymers are loaded with a variety of nanoparticles. The nanoparticles have two primary roles: control of the final composition and phases (and hence the properties); and control of the shrinkage during thermal decomposition of the polymer. Thus the selection of the nanoparticles was the most critical aspect of this project. Based on the results of the processing studies, the performance of selected coatings in oxidizing conditions (both static and cyclic) was investigated.

  5. Zero discharge organic coatings, powder paint - UV curable paint - E-coat. Volume 1. Final report, June 1993-June 1995

    SciTech Connect (OSTI)

    Leal, J.; Martin, D.R.; Spadafora, S.J.; Eng, A.T.; Stark, H.

    1995-06-01

    Zero Discharge Organic Coatings project developed powder paint, Ultraviolet (UV) curable paint, and electro- coating (E-coat) paint for military Applications. These technologies offer potential for high performance coatings with little or no volatile organic compound (VOC) emissions or hazardous waste generation. The ZDOC project focused on formulating non-toxic corrosion inhibitors into these coating technologies, and the applications development of powder coatings. Non-toxic replacements for traditional lead and chromate inhibitors were selected based on a previous NAWCADWAR investigation. Once incorporated, the performance of the coatings with and without inhibitors was compared. Also, the protective mechanisms of these inhibitors were studied. The applications development for powder coatings analyzed technologies to allow powder coating of non-conductive substrates and evaluated the use of IR energy to cure powder coatings. Inhibitors were successfully incorporated into electrocoatings and powder coatings, however corrosion performance results varied with coating formulation.

  6. Multilayer coatings for solar energy control applications

    SciTech Connect (OSTI)

    Kivaisi, R.T.; Mbise, G.

    1993-12-31

    This work presents some results for window coatings that are suitable for solar control applications. Selected research results are given for metal/dielectric based coatings optimized for normal incidence. These coatings can be used to improve the performance of windows both for architectural and automobile sectors. Surface coatings which are transparent at 0.3 < {lambda} < 0.7 {micro}m can be used to solar control windows. A thin homogeneous noble metal film (eg Ag) can combine short wavelength transmittance with high long wavelength reflectance. By embedding the metal film between high refractive index dielectric layers one can optimize the transmittance in the desired spectral region. Transmittance data for multilayer stacks designed for normal and non normal incidence to the coating are presented.

  7. The HMDS Coating Flaw Removal Tool

    SciTech Connect (OSTI)

    Monticelli, M V; Nostrand, M C; Mehta, N; Kegelmeyer, L; Johnson, M A; Fair, J; Widmayer, C

    2008-10-24

    In many high energy laser systems, optics with HMDS sol gel antireflective coatings are placed in close proximity to each other making them particularly susceptible to certain types of strong optical interactions. During the coating process, halo shaped coating flaws develop around surface digs and particles. Depending on the shape and size of the flaw, the extent of laser light intensity modulation and consequent probability of damaging downstream optics may increase significantly. To prevent these defects from causing damage, a coating flaw removal tool was developed that deploys a spot of decane with a syringe and dissolves away the coating flaw. The residual liquid is evacuated leaving an uncoated circular spot approximately 1mm in diameter. The resulting uncoated region causes little light intensity modulation and thus has a low probability of causing damage in optics downstream from the mitigated flaw site.

  8. Novel seed coat lignins in the Cactaceae: structure, distribution...

    Office of Scientific and Technical Information (OSTI)

    Novel seed coat lignins in the Cactaceae: structure, distribution and implications for the evolution of lignin diversity Citation Details In-Document Search Title: Novel seed coat...

  9. Project Profile: Cleanable and Hardcoat Coatings for Increased...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cleanable and Hardcoat Coatings for Increased Durability of Silvered Polymeric Mirrors Project Profile: Cleanable and Hardcoat Coatings for Increased Durability of Silvered...

  10. Engine Friction Reduction Through Surface Finish and Coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Friction Reduction Through Surface Finish and Coatings Engine Friction Reduction Through Surface Finish and Coatings Opportunities exist for friction reduction in piston rings and...

  11. Development of Steel Fastener Nano-Ceramic Coatings for Corrosion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steel Fastener Nano-Ceramic Coatings for Corrosion Protection of Magnesium Parts (AMD-704) Development of Steel Fastener Nano-Ceramic Coatings for Corrosion Protection of Magnesium...

  12. Vehicle Technologies Office Merit Review 2014: Can hard coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Can hard coatings and lubricant anti-wear additives work together? Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together?...

  13. Method for smoothing the surface of a protective coating

    DOE Patents [OSTI]

    Sangeeta, D. (Cincinnati, OH); Johnson, Curtis Alan (Schenectady, NY); Nelson, Warren Arthur (Clifton Park, NY)

    2001-01-01

    A method for smoothing the surface of a ceramic-based protective coating which exhibits roughness is disclosed. The method includes the steps of applying a ceramic-based slurry or gel coating to the protective coating surface; heating the slurry/gel coating to remove volatile material; and then further heating the slurry/gel coating to cure the coating and bond it to the underlying protective coating. The slurry/gel coating is often based on yttria-stabilized zirconia, and precursors of an oxide matrix. Related articles of manufacture are also described.

  14. Table I: Technical Targets for Catalyst Coated Membranes (CCMs...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    I: Technical Targets for Catalyst Coated Membranes (CCMs): Automotive Table I: Technical Targets for Catalyst Coated Membranes (CCMs): Automotive Technical targets for fuel cell...

  15. Coating thickness and coverage effects on the forces between...

    Office of Scientific and Technical Information (OSTI)

    Coating thickness and coverage effects on the forces between silica nanoparticles in water. Citation Details In-Document Search Title: Coating thickness and coverage effects on the...

  16. Project Profile: High-Temperature Solar Selective Coating Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Selective Coating Development for Power Tower Receivers Project Profile: High-Temperature Solar Selective Coating Development for Power Tower Receivers Sandia National...

  17. MENDING THE IN SITU MANIPULATION BARRIER

    SciTech Connect (OSTI)

    PETERSEN, S.W.

    2006-02-06

    In early 2004, the U.S. Department of Energy (DOE) Richland and Fluor Hanford requested technical assistance from the DOE Headquarters EM-23 Technical Assistance Program to provide a team of technical experts to develop recommendations for mending the In Situ Redox Manipulation (ISRM) Barrier in the 100-D Area of the Hanford Site in Washington State. To accommodate this request, EM-23 provided support to convene a group of technical experts from industry, a national laboratory, and a DOE site to participate in a 2 1/2-day workshop with the objective of identifying and recommending options to enhance the performance of the 100-D Area reactive barrier and of a planned extension to the northeast. This report provides written documentation of the team's findings and recommendations. In 1995, a plume of dissolved hexavalent chromium [Cr(VI)], which resulted from operation of the D/DR Reactors at the Hanford site, was discovered along the Columbia River shoreline and in the 100-D Area. Between 1999 and 2003, a reactive barrier using the In Situ Redox Manipulation (ISRM) technology, was installed a distance of 680 meters along the river to reduce the Cr(VI) in the groundwater. The ISRM technology creates a treatment zone within the aquifer by injection of sodium dithionite, a strong reducing agent that scavenges dissolved oxygen (DO) from the aquifer and reduces ferric iron [Fe(III)], related metals, and oxy-ions. The reduction of Fe(III) to ferrous [Fe(II)] iron provides the primary reduction capacity to reduce Cr(VI) to the +3 state, which is less mobile and less toxic. Bench-scale and field-scale treatability tests were initially conducted to demonstrate proof-of principle and to provide data for estimation of barrier longevity. These calculations estimated barrier longevity in excess of twenty years. However, several years after initial and secondary treatment, groundwater in a number of wells has been found to contain elevated chromium (Cr) concentrations, indicating some loss of reductive capacity within the aquifer. The Technical Assistance Team (TAT) was requested to perform the following activities: (1) evaluate the most probable condition(s) that has led to the presence of Cr(VI) in 12 different barrier wells (i.e. premature loss of reductive capacity), (2) recommend methods for determining the cause of the problem, (3) recommend methods for evaluating the magnitude of the problem, (4) recommend practicable method(s) for mending the barrier that involves a long-term solution, and (5) recommend methods for extending the barrier to the northeast (e.g., changing injection procedure, changing or augmenting the injected material). Since the March 2004 workshop, a decision has been made to place a hold on the barrier extension until more is known about the cause of the problem. However, the report complies with the original request for information on all of the above activities, but focuses on determining the cause of the problem and mending of the existing barrier.

  18. Adhesive flexible barrier film, method of forming same, and organic electronic device including same

    DOE Patents [OSTI]

    Blizzard, John Donald; Weidner, William Kenneth

    2013-02-05

    An adhesive flexible barrier film comprises a substrate and a barrier layer disposed on the substrate. The barrier layer is formed from a barrier composition comprising an organosilicon compound. The adhesive flexible barrier film also comprises an adhesive layer disposed on the barrier layer and formed from an adhesive composition. A method of forming the adhesive flexible barrier film comprises the steps of disposing the barrier composition on the substrate to form the barrier layer, disposing the adhesive composition on the barrier layer to form the adhesive layer, and curing the barrier layer and the adhesive layer. The adhesive flexible barrier film may be utilized in organic electronic devices.

  19. Effect of Superalloy Substrate and Bond Coating on TBC Lifetime

    SciTech Connect (OSTI)

    Pint, Bruce A; Haynes, James A; Zhang, Ying

    2010-01-01

    Several different single-crystal superalloys were coated with different bond coatings to study the effect of composition on the cyclic oxidation lifetime of an yttria-stabilized zirconia (YSZ) top coating deposited by electron beam physical vapor deposition from a commercial source. Three different superalloys were coated with a 7 {micro}m Pt layer that was diffused into the surface prior to YSZ deposition. One of the superalloys, N5, was coated with a low activity, Pt-modified aluminide coating and Pt-diffusion coatings with 3 and 7 {micro}m of Pt. Three coatings of each type were furnace cycled to failure in 1 h cycles at 1150 C to assess average coating lifetime. The 7 {micro}m Pt diffusion coating on N5 had an average YSZ coating lifetime >50% higher than a Pt-modified aluminide coating on N5. Without a YSZ coating, the Pt-modified aluminide coating on N5 showed the typical surface deformation during cycling, however, the deformation was greatly reduced when constrained by the YSZ coating. The 3 {micro}m Pt diffusion coating had a similar average lifetime as the Pt-modified aluminide coating but a much wider scatter. The Pt diffusion bond coating on superalloy X4 containing Ti exhibited the shortest YSZ coating lifetime, this alloy-coating combination also showed the worst alumina scale adhesion without a YSZ coating. The third generation superalloy N6 exhibited the longest coating lifetime with a 7 {micro}m Pt diffusion coating.

  20. Options for Energy Efficiency in India and Barriers to Their...

    Open Energy Info (EERE)

    Options for Energy Efficiency in India and Barriers to Their Adoption: A Scoping Study Jump to: navigation, search Name Options for Energy Efficiency in India and Barriers to Their...

  1. Overcoming Barriers to Wind Development in Appalachian Coal Country

    SciTech Connect (OSTI)

    Brent Bailey; Evan Hansen

    2012-10-09

    This research project synthesizes existing data and communication from experts to assess barriers to wind development in Pennsylvania, Maryland, West Virginia, Virginia, and Kentucky, and makes recommendations where feasible to reduce or eliminate those barriers.

  2. Energy Permitting Wizard Helps Reduce Project Barriers in Hawai...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Permitting Wizard Helps Reduce Project Barriers in Hawai'i Energy Permitting Wizard Helps Reduce Project Barriers in Hawai'i To address the complex permitting process for renewable...

  3. Simulation of localized barrier defects in resonant tunneling diodes 

    E-Print Network [OSTI]

    Stoneberg, Jason Neal

    1995-01-01

    defect assisted tunneling as a possible current mechanism. This study attempts to ascertain the effects of defect potentials in the barriers on current in a simulation of a double barrier resonant tunneling diode. Results indicate that these defects could...

  4. Coated Fiber Neutron Detector Test

    SciTech Connect (OSTI)

    Lintereur, Azaree T.; Ely, James H.; Kouzes, Richard T.; Stromswold, David C.

    2009-10-23

    Radiation portal monitors used for interdiction of illicit materials at borders include highly sensitive neutron detection systems. The main reason for having neutron detection capability is to detect fission neutrons from plutonium. The currently deployed radiation portal monitors (RPMs) from Ludlum and Science Applications International Corporation (SAIC) use neutron detectors based upon 3He-filled gas proportional counters, which are the most common large neutron detector. There is a declining supply of 3He in the world, and thus, methods to reduce the use of this gas in RPMs with minimal changes to the current system designs and sensitivity to cargo-borne neutrons are being investigated. Reported here are the results of tests of the 6Li/ZnS(Ag)-coated non-scintillating plastic fibers option. This testing measured the required performance for neutron detection efficiency and gamma ray rejection capabilities of a system manufactured by Innovative American Technology (IAT).

  5. TTI: 0-6071 Evaluation of Barriers for

    E-Print Network [OSTI]

    for future research are discussed. 17. Key Words High-Speed Roadways, Bridge Rail, Longitudinal BarriersTTI: 0-6071 Evaluation of Barriers for Very High Speed Roadways Research/Test Report 0. Title and Subtitle Evaluation of Barriers for Very High Speed Roadways 5. Report Date January 2010

  6. Pricing European Barrier Options Peter W.Buchen

    E-Print Network [OSTI]

    Sydney, University of

    barrier options which incorporate a con- stant rebate. The method exploits the symmetries and properties of elemen- tary solutions of the Black-Scholes partial differential equation. The rebate and non-rebate. If rebates apply then the first exit time densities through the barrier are also required. Barrier option

  7. Theoretical Analysis of the Rotational Barrier of Ethane

    E-Print Network [OSTI]

    Minnesota, University of

    Theoretical Analysis of the Rotational Barrier of Ethane YIRONG MO*, AND JIALI GAO*, Department The understanding of the ethane rotation barrier is fundamental for structural theory and the conformational a computational approach to probe the rotation barriers of ethane and its congeners in terms of steric repulsion

  8. Near-infrared radiation curable multilayer coating systems and methods for applying same

    SciTech Connect (OSTI)

    Bowman, Mark P; Verdun, Shelley D; Post, Gordon L

    2015-04-28

    Multilayer coating systems, methods of applying and related substrates are disclosed. The coating system may comprise a first coating comprising a near-IR absorber, and a second coating deposited on a least a portion of the first coating. Methods of applying a multilayer coating composition to a substrate may comprise applying a first coating comprising a near-IR absorber, applying a second coating over at least a portion of the first coating and curing the coating with near infrared radiation.

  9. Substrate solder barriers for semiconductor epilayer growth

    DOE Patents [OSTI]

    Drummond, Timothy J. (Tijeras, NM); Ginley, David S. (Albuquerque, NM); Zipperian, Thomas E. (Albuquerque, NM)

    1989-01-01

    During the growth of compound semiconductors by epitaxial processes, substrates are typically mounted to a support. In modular beam epitaxy, mounting is done using indium as a solder. This method has two drawbacks: the indium reacts with the substrate, and it is difficult to uniformly wet the back of a large diameter substrate. Both of these problems have been successfully overcome by sputter coating the back of the substrate with a thin layer of tungsten carbide or tungsten carbide and gold. In addition to being compatible with the growth of high quality semiconductor epilayers this coating is also inert in all standard substrate cleaning etchants used for compound semiconductors, and provides uniform distribution of energy in radiant heating.

  10. Method of applying coatings to substrates

    DOE Patents [OSTI]

    Hendricks, Charles D. (Livermore, CA)

    1991-01-01

    A method for applying novel coatings to substrates is provided. The ends of multiplicity of rods of different materials are melted by focused beams of laser light. Individual electric fields are applied to each of the molten rod ends, thereby ejecting charged particles that include droplets, atomic clusters, molecules, and atoms. The charged particles are separately transported, by the accelerations provided by electric potentials produced by an electrode structure, to substrates where they combine and form the coatings. Layered and thickness graded coatings comprised of hithereto unavailable compositions, are provided.

  11. Void forming pyrolytic carbon coating process

    DOE Patents [OSTI]

    Beatty, Ronald L. (Oak Ridge, TN); Cook, Jackie L. (Oak Ridge, TN)

    2000-01-01

    A pyrolytic carbon coated nuclear fuel particle and method of making it. The fuel particle has a core composed of a refractory compound of an actinide metal. The pyrolytic carbon coating surrounds the core so as to provide a void volume therebetween. The coating has an initial density of no greater than 1.45 grams/cm.sup.3 and an anisotropy factor than 3.0 and a final density upon heat treatment above about 2000.degree. C. of greater than 1.7 grams/cm.sup.3 and an anisotropy factor greater than 5.

  12. Corrosion control of metals by organic coatings

    SciTech Connect (OSTI)

    Ooij, W.J. van; Bierwagen, G.P.; Skerry, B.S.; Mills, D.

    1999-01-01

    The authors present a comprehensive treatment of the entire field of corrosion control of metals, from mechanisms and testing procedures to modification of metal surfaces and interfaces by silanes and plasma techniques. They discuss the new, sophisticated analytical tools, such as Time-of-Flight SIMS and electrochemical impedance spectroscopy, and all materials -- metals, pretreatments, and paint systems. The contents include: (1) Corrosion under organic coatings; (2) Mechanisms of corrosion control by organic coatings; (3) Metal pretreatments; (4) Techniques to study organic coating-metal interfaces; (5) Modification of metal surfaces and interfaces; (6) corrosion testing; (7) Adhesion testing; (8) Paint systems; (9) Conclusions and prospects references.

  13. Advanced Fuels Campaign Cladding & Coatings Meeting Summary

    SciTech Connect (OSTI)

    Not Listed

    2013-03-01

    The Fuel Cycle Research and Development (FCRD) Advanced Fuels Campaign (AFC) organized a Cladding and Coatings operational meeting February 12-13, 2013, at Oak Ridge National Laboratory (ORNL). Representatives from the U.S. Department of Energy (DOE), national laboratories, industry, and universities attended the two-day meeting. The purpose of the meeting was to discuss advanced cladding and cladding coating research and development (R&D); review experimental testing capabilities for assessing accident tolerant fuels; and review industry/university plans and experience in light water reactor (LWR) cladding and coating R&D.

  14. Self-assembled nanolaminate coatings (SV)

    SciTech Connect (OSTI)

    Fan, H.

    2012-03-01

    Sandia National Laboratories (Sandia) and Lockheed Martin Aeronautics (LM Aero) are collaborating to develop affordable, self-assembled, nanocomposite coatings and associated fabrication processes that will be tailored to Lockheed Martin product requirements. The purpose of this project is to develop a family of self-assembled coatings with properties tailored to specific performance requirements, such as antireflective (AR) optics, using Sandia-developed self-assembled techniques. The project met its objectives by development of a simple and economic self-assembly processes to fabricate multifunctional coatings. Specifically, materials, functionalization methods, and associated coating processes for single layer and multiple layers coatings have been developed to accomplish high reflective coatings, hydrophobic coatings, and anti-reflective coatings. Associated modeling and simulations have been developed to guide the coating designs for optimum optical performance. The accomplishments result in significant advantages of reduced costs, increased manufacturing freedom/producibility, improved logistics, and the incorporation of new technology solutions not possible with conventional technologies. These self-assembled coatings with tailored properties will significantly address LMC's needs and give LMC a significant competitive lead in new engineered materials. This work complements SNL's LDRD and BES programs aimed at developing multifunctional nanomaterials for microelectronics and optics as well as structure/property investigations of self-assembled nanomaterials. In addition, this project will provide SNL with new opportunities to develop and apply self-assembled nanocomposite optical coatings for use in the wavelength ranges of 3-5 and 8-12 micrometers, ranges of vital importance to military-based sensors and weapons. The SANC technologies will be applied to multiple programs within the LM Company including the F-35, F-22, ADP (Future Strike Bomber, UAV, UCAV, etc.). The SANC technologies will establish LMA and related US manufacturing capability for commercial and military applications therefore reducing reliance on off-shore development and production of related critical technologies. If these technologies are successfully licensed, production of these coatings in manufactory will create significant technical employment opportunities.

  15. Roof Coating Procedures and Their Productivity Gains 

    E-Print Network [OSTI]

    Bonaby, J.; Schaub, D.

    2006-01-01

    stream_source_info ESL-IE-06-05-12.pdf.txt stream_content_type text/plain stream_size 1795 Content-Encoding ISO-8859-1 stream_name ESL-IE-06-05-12.pdf.txt Content-Type text/plain; charset=ISO-8859-1 Roof Coating... of the installation of different roof coating technologies and comparable application procedures of these technologies are ambiguous. The focal point of this research is to determine the effective correlation between various commercially available roof coatings...

  16. Nuclear reactor vessel fuel thermal insulating barrier

    DOE Patents [OSTI]

    Keegan, C. Patrick; Scobel, James H.; Wright, Richard F.

    2013-03-19

    The reactor vessel of a nuclear reactor installation which is suspended from the cold leg nozzles in a reactor cavity is provided with a lower thermal insulating barrier spaced from the reactor vessel that has a hemispherical lower section that increases in volume from the center line of the reactor to the outer extent of the diameter of the thermal insulating barrier and smoothly transitions up the side walls of the vessel. The space between the thermal insulating harrier and the reactor vessel forms a chamber which can be flooded with cooling water through passive valving to directly cool the reactor vessel in the event of a severe accident. The passive inlet valve for the cooling water includes a buoyant door that is normally maintained sealed under its own weight and floats open when the cavity is Hooded. Passively opening steam vents are also provided.

  17. Diffusion barriers in modified air brazes

    DOE Patents [OSTI]

    Weil, Kenneth Scott (Richland, WA); Hardy, John S. (Richland, WA); Kim, Jin Yong (Richland, WA); Choi, Jung-Pyung (Richland, WA)

    2010-04-06

    A method for joining two ceramic parts, or a ceramic part and a metal part, and the joint formed thereby. The method provides two or more parts, a braze consisting of a mixture of copper oxide and silver, a diffusion barrier, and then heats the braze for a time and at a temperature sufficient to form the braze into a bond holding the two or more parts together. The diffusion barrier is an oxidizable metal that forms either a homogeneous component of the braze, a heterogeneous component of the braze, a separate layer bordering the braze, or combinations thereof. The oxidizable metal is selected from the group Al, Mg, Cr, Si, Ni, Co, Mn, Ti, Zr, Hf, Pt, Pd, Au, lanthanides, and combinations thereof.

  18. Diffusion barriers in modified air brazes

    DOE Patents [OSTI]

    Weil, Kenneth Scott; Hardy, John S; Kim, Jin Yong; Choi, Jung-Pyung

    2013-04-23

    A method for joining two ceramic parts, or a ceramic part and a metal part, and the joint formed thereby. The method provides two or more parts, a braze consisting of a mixture of copper oxide and silver, a diffusion barrier, and then heats the braze for a time and at a temperature sufficient to form the braze into a bond holding the two or more parts together. The diffusion barrier is an oxidizable metal that forms either a homogeneous component of the braze, a heterogeneous component of the braze, a separate layer bordering the braze, or combinations thereof. The oxidizable metal is selected from the group Al, Mg, Cr, Si, Ni, Co, Mn, Ti, Zr, Hf, Pt, Pd, Au, lanthanides, and combinations thereof.

  19. Microstructural characterization of a thin film ZrN diffusion barrier in an As-fabricated U–7Mo/Al matrix dispersion fuel plate

    SciTech Connect (OSTI)

    Keiser, Dennis D.; Perez, Emmanuel; Wiencek, Tom; Leenaers, Ann; Van den Berghe, Sven

    2015-03-01

    The United States High Performance Research Reactor Fuel Development program is developing low enriched uranium fuels for application in research and test reactors. One concept utilizes U–7 wt.% Mo (U–7Mo) fuel particles dispersed in Al matrix, where the fuel particles are coated with a 1 ?m-thick ZrN coating. The ZrN serves as a diffusion barrier to eliminate a deleterious reaction that can occur between U–7Mo and Al when a dispersion fuel is irradiated under aggressive reactor conditions. To investigate the final microstructure of a physically-vapor-deposited ZrN coating in a dispersion fuel plate after it was fabricated using a rolling process, characterization samples were taken from a fuel plate that was fabricated at 500 °C using ZrN-coated U–7Mo particles, Al matrix and AA6061 cladding. Scanning electron and transmission electron microscopy analysis were performed. Data from these analyses will be used to support future microstructural examinations of irradiated fuel plates, in terms of understanding the effects of irradiation on the ZrN microstructure, and to determine the role of diffusion barrier microstructure in eliminating fuel/matrix interactions during irradiation. The as-fabricated coating was determined to be cubic-ZrN (cF8) phase. It exhibited a columnar microstructure comprised of nanometer-sized grains and a region of relatively high porosity, mainly near the Al matrix. Small impurity-containing phases were observed at the U–7Mo/ZrN interface, and no interaction zone was observed at the ZrN/Al interface. The bonding between the U–7Mo and ZrN appeared to be mechanical in nature. A relatively high level of oxygen was observed in the ZrN coating, extending from the Al matrix in the ZrN coating in decreasing concentration. The above microstructural characteristics are discussed in terms of what may be most optimal for a diffusion barrier in a dispersion fuel plate application.

  20. Train derailment and railroad barrier interaction simulation 

    E-Print Network [OSTI]

    Zhang, Heping

    1990-01-01

    or eliminate the risk of the passenger track intrusion by derailing cars on adjacent track is of concern to the railroad authorities. The purpose of this study is through computer simulation to investigate the behavior of the train derailment and to determine... the feasibility of the use of a barrier wall to restrain derailing railroad cars. An analytical model has been developed for the simulation. In the theoretical analysis the equation of motion in the horizontal plane for each derailed car was derived...

  1. Plastic Schottky-barrier solar cells

    DOE Patents [OSTI]

    Waldrop, J.R.; Cohen, M.J.

    1981-12-30

    A photovoltaic cell structure is fabricated from an active medium including an undoped polyacetylene, organic semiconductor. When a film of such material is in rectifying contact with a metallic area electrode, a Schottky-barrier junction is obtained within the body of the cell structure. Also, a gold overlayer passivates a magnesium layer on the undoped polyacetylene film. With the proper selection and location of elements a photovoltaic cell structure and solar cell are obtained.

  2. Fission barriers and half-lives

    SciTech Connect (OSTI)

    Moeller, P.; Nix, J.R.; Swiatecki, W.J.

    1989-01-01

    We briefly review the development of theoretical models for the calculation of fission barriers and half-lives. We focus on how results of actual calculations in a unified macroscopic-microscopic approach provide an interpretation of the mechanisms behind some of the large number of phenomena observed in fission. As instructive examples we choose studies of the rapidly varying fission properties of elements at the end of the periodic system. 31 refs., 10 figs.

  3. QUANTITATIVE EVALUATION OF FIRE SEPARATION AND BARRIERS

    SciTech Connect (OSTI)

    Coutts, D

    2007-04-17

    Fire barriers, and physical separation are key components in managing the fire risk in Nuclear Facilities. The expected performance of these features have often been predicted using rules-of-thumb or expert judgment. These approaches often lack the convincing technical bases that exist when addressing other Nuclear Facility accident events. This paper presents science-based approaches to demonstrate the effectiveness of fire separation methods.

  4. Measure Guideline: Transitioning from Three-Coat Stucco to One-Coat Stucco with EPS

    SciTech Connect (OSTI)

    Brozyna, K.; Davis, G.; Rapport, A.

    2012-04-01

    This Measure Guideline has been developed to help builders transition from using a traditional three-coat stucco wall-cladding system to a one-coat stucco wall-cladding system with expanded polystyrene (EPS) insulated sheathing. The three-coat system uses a base layer, a fill layer, and a finish layer. The one-coat system maintains the look of a traditional stucco system but uses only a base layer and a finish coat over EPS insulation that achieves higher levels of energy efficiency. Potential risks associated with the installation of a one-coat stucco system are addressed in terms of design, installation, and warranty concerns such as cracking and delamination, along with mitigation strategies to reduce these risks.

  5. Oxynitride Thin Film Barriers for PV Packaging

    SciTech Connect (OSTI)

    Glick, S. H.; delCueto, J. A.; Terwilliger, K. M.; Jorgensen, G. J.; Pankow, J. W.; Keyes, B. M.; Gedvilas, L. M.; Pern, F. J.

    2005-11-01

    Dielectric thin-film barrier and adhesion-promoting layers consisting of silicon oxynitride materials (SiOxNy, with various stoichiometry) were investigated. For process development, films were applied to glass (TCO, conductive SnO2:F; or soda-lime), polymer (PET, polyethylene terephthalate), aluminized soda-lime glass, or PV cell (a-Si, CIGS) substrates. Design strategy employed de-minimus hazard criteria to facilitate industrial adoption and reduce implementation costs for PV manufacturers or suppliers. A restricted process window was explored using dilute compressed gases (3% silane, 14% nitrous oxide, 23% oxygen) in nitrogen (or former mixtures, and 11.45% oxygen mix in helium and/or 99.999% helium dilution) with a worst-case flammable and non-corrosive hazard classification. Method employed low radio frequency (RF) power, less than or equal to 3 milliwatts per cm2, and low substrate temperatures, less than or equal to 100 deg C, over deposition areas less than or equal to 1000 cm2. Select material properties for barrier film thickness (profilometer), composition (XPS/FTIR), optical (refractive index, %T and %R), mechanical peel strength and WVTR barrier performance are presented.

  6. MATERIALS, INTERFACES, AND ELECTROCHEMICAL PHENOMENA Hydrophilic Zeolite Coatings for Improved

    E-Print Network [OSTI]

    Aguilar, Guillermo

    MATERIALS, INTERFACES, AND ELECTROCHEMICAL PHENOMENA Hydrophilic Zeolite Coatings for Improved Heat on the surface of a bare, ZSM-5 coated, and Zeolite-A coated stainless steel 304 substrate at different initial surface temperatures was experimentally studied. ZSM-5 and Zeolite-A coated SS-304 are more much more

  7. Experimental study of 199Hg spin anti-relaxation coatings

    E-Print Network [OSTI]

    Z. Chowdhuri; M. Fertl; M. Horras; K. Kirch; J. Krempel; B. Lauss; A. Mtchedlishvili; D. Rebreyend; S. Roccia; P. Schmidt-Wellenburg; G. Zsigmond

    2013-09-04

    We report on a comparison of spin relaxation rates in a $^{199}$Hg magnetometer using different wall coatings. A compact mercury magnetometer was built for this purpose. Glass cells coated with fluorinated materials show longer spin coherence times than if coated with their hydrogenated homologues. The longest spin relaxation time of the mercury vapor was measured with a fluorinated paraffin wall coating.

  8. THE ANALYSIS OF COATING FLOWS NEAR THE CONTACT LINE

    E-Print Network [OSTI]

    THE ANALYSIS OF COATING FLOWS NEAR THE CONTACT LINE AVNER FRIEDMAN* and JUAN J.L. VELAZQUEZ** 0. Introduction. The term \\coating ows" refers to any viscous ow which is used to coat surfaces. Such ows are used for coating photographic lms, magnetic tapes, optical devices and, of course, for painting surfaces. Various

  9. Shape Memory Assisted Self-Healing Coating Xiaofan Luo

    E-Print Network [OSTI]

    Mather, Patrick T.

    Shape Memory Assisted Self-Healing Coating Xiaofan Luo and Patrick T. Mather* Department and characterization of new shape memory assisted self- healing (SMASH) coatings. The coatings feature a phase in a shape memory epoxy matrix. Mechanical damage to the coating can be self-healed via heating, which

  10. Appendix A. Fluorinated Silane Coating Procedure for Pyrex and Quartz

    E-Print Network [OSTI]

    Appendix A. Fluorinated Silane Coating Procedure for Pyrex and Quartz Coating Compound: United Chemical Technologies Compound #T2494 1. Mix the coating solution: a. Start with a 200 cm3 ethanol to 10 cm with distilled H2O. c. Dry thoroughly. 3. Apply the coating: a. Dip object in solution for 2-5 minutes. For large

  11. Performing a global barrier operation in a parallel computer

    DOE Patents [OSTI]

    Archer, Charles J; Blocksome, Michael A; Ratterman, Joseph D; Smith, Brian E

    2014-12-09

    Executing computing tasks on a parallel computer that includes compute nodes coupled for data communications, where each compute node executes tasks, with one task on each compute node designated as a master task, including: for each task on each compute node until all master tasks have joined a global barrier: determining whether the task is a master task; if the task is not a master task, joining a single local barrier; if the task is a master task, joining the global barrier and the single local barrier only after all other tasks on the compute node have joined the single local barrier.

  12. Soil surface stabilization using an in situ plutonium coating techniuqe at the Nevada Test Site

    SciTech Connect (OSTI)

    Lew, J.; Snipes, R. [Environmental Management and Enrichment Facilities, Oak Ridge, TN (United States); Tamura, T.

    1996-12-31

    The Hazardous Waste Remedial Actions Program (HAZWRAP), in collaboration with the University of Nevada at Reno (UNR), has developed and is investigating an in situ plutonium treatment for soils at the Nevada Test Site (NTS). The concept, conceived by Dr. T. Tamura and refined at HAZWRAP, was developed during the Nevada Applied Ecology Program investigation. In analyzing for plutonium in soils, it was noted that the alpha emanation of plutonium was greatly attenuated if traces of iron or manganese oxides were present in the final electroplating stage. The technique would reduce resuspension of alpha particles into the air by coating the contaminants in soils in situ with an environmentally compatible, durable, and nontoxic material. The coating materials (calcium hydroxide, ferrous sulfate) reduce resuspension by providing a cementitious barrier against radiation penetration while retaining soil porosity. This technique not only stabilizes plutonium-contaminated soils, but also provides an additional protection from worker exposure to radiation during remediation activities. Additionally, the coating would decrease the water solubility of the contaminant and, thus, reduce its migration through soil and uptake by plants.

  13. Deformation sensor based on polymer-supported discontinuous graphene multi-layer coatings

    SciTech Connect (OSTI)

    Carotenuto, G.; Schiavo, L.; Romeo, V.; Nicolais, L. [Institute for Composite and Biomedical Materials, National Research Council, Piazzale E. Fermi, 1, 80055 Portici (Italy)

    2014-05-15

    Graphene can be conveniently used in the modification of polymer surfaces. Graphene macromolecules are perfectly transparent to the visible light and electrically conductive, consequently these two properties can be simultaneously provided to polymeric substrates by surface coating with thin graphene layers. In addition, such coating process provides the substrates of: water-repellence, higher surface hardness, low-friction, self-lubrication, gas-barrier properties, and many other functionalities. Polyolefins have a non-polar nature and therefore graphene strongly sticks on their surface. Nano-crystalline graphite can be used as graphene precursor in some chemical processes (e.g., graphite oxide synthesis by the Hummer method), in addition it can be directly applied to the surface of a polyolefin substrate (e.g., polyethylene) to cover it by a thin graphene multilayer. In particular, the nano-crystalline graphite perfectly exfoliate under the application of a combination of shear and friction forces and the produced graphene single-layers perfectly spread and adhere on the polyethylene substrate surface. Such polymeric materials can be used as ITO (indium-tin oxide) substitute and in the fabrication of different electronic devices. Here the fabrication of transparent resistive deformation sensors based on low-density polyethylene films coated by graphene multilayers is described. Such devices are very sensible and show a high reversible and reproducible behavior.

  14. Method for fluidizing and coating ultrafine particles, device for fluidizing and coating ultrafine particles

    DOE Patents [OSTI]

    Li, Jie; Liu, Yung Y

    2015-01-20

    The invention provides a method for dispersing particles within a reaction field, the method comprising confining the particles to the reaction field using a standing wave. The invention also provides a system for coating particles, the system comprising a reaction zone; a means for producing fluidized particles within the reaction zone; a fluid to produce a standing wave within the reaction zone; and a means for introducing coating moieties to the reaction zone. The invention also provides a method for coating particles, the method comprising fluidizing the particles, subjecting the particles to a standing wave; and contacting the subjected particles with a coating moiety.

  15. Effect of Water Vapor on the 1100oC Oxidation Behavior of Plasma-Sprayed TBCs with HVOF NiCoCrAlX Bond Coatings

    SciTech Connect (OSTI)

    Haynes, James A; Unocic, Kinga A; Pint, Bruce A

    2013-01-01

    With the goal of investigating the reported detrimental effect of water vapor on thermal barrier coating (TBC) performance, furnace cycle experiments were conducted in dry O2 and air with 10 and 50% water vapor at 1100 C. The TBC systems evaluated were air plasma-sprayed (APS), yttria-stabilized zirconia (YSZ) top coatings with high velocity oxy fuel (HVOF)-deposited NiCoCrAlY or NiCoCrAlYHfSi bond coating. Average TBC lifetime was reduced by ~30% in air with 10% water vapor compared to cycling in dry O2, using 1h cycle durations. Superalloy substrates with Y and La additions also were investigated but showed no statistical change in the average TBC lifetime compared to the base CMSX4 superalloy. In all cases, the bond coating with Hf and Si additions increased YSZ lifetime by 20% or more. Experiments that increased water vapor to 50% showed no further decrease in TBC lifetime. Increasing the cycle frequency to 100h resulted in a large increase in TBC lifetime, especially for the NiCoCrAlYHfSi bond coatings. Co-doping the NiCoCrAl bond coat with Y and Hf was beneficial to TBC lifetime, but did not mitigate the detrimental impact of water vapor.

  16. Mechanical properties of phospholipid coated microbubbles 

    E-Print Network [OSTI]

    Morris, Julia Kathleen

    2014-11-27

    Phospholipid coated, inert gas filled microbubbles (MBs) are currently in widespread use in medical applications for the enhancement of diagnostic ultrasound images, and they are promising candidates for use in the area ...

  17. UV Curable Coatings in Aluminum Can Production 

    E-Print Network [OSTI]

    Donhowe, E. T.

    1994-01-01

    based coatings. The Coors Brewing Company Can Manufacturing Plant has been utilizing this technology in full scale aluminum can production since 1975, and therefore has had the opportunity to evaluate practical operations of the UV technology...

  18. Sol-gel antireflective coating on plastics

    DOE Patents [OSTI]

    Ashley, C.S.; Reed, S.T.

    1988-01-26

    An antireflection film made from reliquified sol-gel hydrolyzation, condensation polymeric reaction product of a silicon, alkoxides and/or metal alkoxides, or mixtures thereof. The film is particularly useful for coating plastics.

  19. Sol-gel antireflective coating on plastics

    DOE Patents [OSTI]

    Ashley, Carol S. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM)

    1990-01-01

    An antireflection film made from a reliquified sol-gel hydrolyzation, condensation polymeric reaction product of a silicon, alkoxides and/or metal alkoxides, or mixtures thereof. The film is particularly useful for coating plastics.

  20. Thin film-coated polymer webs

    DOE Patents [OSTI]

    Wenz, Robert P. (Cottage Grove, MN); Weber, Michael F. (Shoreview, MN); Arudi, Ravindra L. (Woodbury, MN)

    1992-02-04

    The present invention relates to thin film-coated polymer webs, and more particularly to thin film electronic devices supported upon a polymer web, wherein the polymer web is treated with a purifying amount of electron beam radiation.

  1. OVERLAY COATINGS FOR GAS TURBINE AIRFOILS

    E-Print Network [OSTI]

    Boone, Donald H.

    2013-01-01

    of Supperalloys for Gas Turbine Engines, 11 J. Metals, Q,1970, p. 545. R. Krutenat, Gas Turbine Materials ConferenceOVERLAY COATINGS FOR GAS TURBINE AIRFOILS Donald H. Boone

  2. Conformal chemically resistant coatings for microflow devices

    DOE Patents [OSTI]

    Folta, James A.; Zdeblick, Mark

    2003-05-13

    A process for coating the inside surfaces of silicon microflow devices, such as electrophoresis microchannels, with a low-stress, conformal (uniform) silicon nitride film which has the ability to uniformly coat deeply-recessed cavities with, for example, aspect ratios of up to 40:1 or higher. The silicon nitride coating allows extended exposure to caustic solutions. The coating enables a microflow device fabricated in silicon to be resistant to all classes of chemicals: acids, bases, and solvents. The process involves low-pressure (vacuum) chemical vapor deposition. The ultra-low-stress silicon nitride deposition process allows 1-2 .mu.m thick films without cracks, and so enables extended chemical protection of a silicon microflow device against caustics for up to 1 year. Tests have demonstrated the resistance of the films to caustic solutions at both ambient and elevated temperatures to 65.degree. C.

  3. Performance of Polymer Coatings Under Forming Conditions 

    E-Print Network [OSTI]

    Purohit, Zalak

    2012-02-14

    Prepainted metal sheets being environment friendly and cost effective as compared to postpainted metal sheets, are widely used in construction, packaging, transportation and automotive industries. One of the key requirements for prepainted coatings...

  4. Peptide coated quantum dots for biological applications

    E-Print Network [OSTI]

    2006-01-01

    23] W. C. W. Chan and S. M. Nie, “Quantum dot bioconjugatesThe resultant inorganic NIR QDOTs were also peptide-coatedInstitute of Health under Grant NIH 5 R01 EB000312. Asterisk

  5. SELECTIVE ABSORBER COATED FOILS FOR SOLAR COLLECTORS

    E-Print Network [OSTI]

    Lampert, Carl M.

    2013-01-01

    p. 1080. AES Second Coatings for Solar Collectors Symp. , 11solar collector panels. Here the major consideration is whether the coatingcoating concept is to use heavy starting stock which might be suitable for direct fabrication of solar collector

  6. OVERLAY COATINGS FOR GAS TURBINE AIRFOILS

    E-Print Network [OSTI]

    Boone, Donald H.

    2013-01-01

    of Supperalloys for Gas Turbine Engines, 11 J. Metals, Q,FT4, JT9D and other gas turbines, and their use continues toOVERLAY COATINGS FOR GAS TURBINE AIRFOILS Donald H. Boone

  7. Nickel coated aluminum battery cell tabs

    DOE Patents [OSTI]

    Bucchi, Robert S.; Casoli, Daniel J.; Campbell, Kathleen M.; Nicotina, Joseph

    2014-07-29

    A battery cell tab is described. The battery cell tab is anodized on one end and has a metal coating on the other end. Battery cells and methods of making battery cell tabs are also described.

  8. Neutron absorbing coating for nuclear criticality control

    DOE Patents [OSTI]

    Mizia, Ronald E. (Idaho Falls, ID); Wright, Richard N. (Idaho Falls, ID); Swank, William D. (Idaho Falls, ID); Lister, Tedd E. (Idaho Falls, ID); Pinhero, Patrick J. (Idaho Falls, ID)

    2007-10-23

    A neutron absorbing coating for use on a substrate, and which provides nuclear criticality control is described and which includes a nickel, chromium, molybdenum, and gadolinium alloy having less than about 5% boron, by weight.

  9. Backfill barrier as a component in a multiple barrier nuclear waste isolation system

    SciTech Connect (OSTI)

    Nowak, E.J.

    1980-05-01

    Quantitative estimates of the potential effectiveness of backfill barriers based on a linear sorption model are presented. Using getters such as clays (known sorbents), a backfill approximately 1-foot-thick can delay by 10/sup 4/ to 10/sup 5/ years the breakthrough of transuranics. A delay of 10/sup 3/ years is possible for major cationic fission products. These delays can be achieved provided that (1) the distribution coefficient (K/sub d/, a measure of affinity for sorbed species) for the barrier material is equal to or greater than 2000 ml/g for transuranics and 200 ml/g for fission products; (2) the interstitial groundwater velocity through the barrier is limited to 1 ft/year or less; (3) the effective porosity of the barrier is equal to or less than 0.1; and (4) the physical integrity of the barrier is maintained (no channels or cracks). Mixtures containing expanding clays such as smectites and other getters are expected to satisfy these criteria.

  10. Hybrid glass coatings for optical fibers: effect of coating thickness on strength and dynamic fatigue characteristics of silica fibers

    E-Print Network [OSTI]

    Matthewson, M. John

    Hybrid glass coatings for optical fibers: effect of coating thickness on strength and dynamic coatings. Recently developed sol-gel derived inorganic- organic hybrid materials called hybrid glass offered improved protective performance as compared to standard dual polymer coated fibers [1

  11. Thermal Spray Coatings for Coastal Infrastructure

    SciTech Connect (OSTI)

    Holcomb, G.R.; Covino, BernardS. Jr.; Cramer, S.D.; Bullard, S.J.

    1997-11-01

    Several protection strategies for coastal infrastructure using thermal-spray technology are presented from research at the Albany Research Center. Thermal-sprayed zinc coatings for anodes in impressed current cathodic protection systems are used to extend the service lives of reinforced concrete bridges along the Oregon coast. Thermal-sprayed Ti is examined as an alternative to the consumable zinc anode. Sealed thermal-sprayed Al is examined as an alternative coating to zinc dust filled polyurethane paint for steel structures.

  12. Strain-tolerant ceramic coated seal

    DOE Patents [OSTI]

    Schienle, James L. (Phoenix, AZ); Strangman, Thomas E. (Phoenix, AZ)

    1994-01-01

    A metallic regenerator seal is provided having multi-layer coating comprising a NiCrAlY bond layer, a yttria stabilized zirconia (YSZ) intermediate layer, and a ceramic high temperature solid lubricant surface layer comprising zinc oxide, calcium fluoride, and tin oxide. An array of discontinuous grooves is laser machined into the outer surface of the solid lubricant surface layer making the coating strain tolerant.

  13. Progress to Develop an Advanced Solar-Selective Coating

    SciTech Connect (OSTI)

    Kennedy, C. E.

    2008-03-01

    The progress to develop a durable advanced solar-selective coating will be described. Experimental work has focused on modeling high-temperature, solar-selective coatings; depositing the individual layers and modeled coatings; measuring the optical, thermal, morphology, and compositional properties and using the data to validate the modeled and deposited properties; re-optimizing the coating; and testing the coating performance and durability.

  14. HIGH-PERFORMANCE COATING MATERIALS

    SciTech Connect (OSTI)

    SUGAMA,T.

    2007-01-01

    Corrosion, erosion, oxidation, and fouling by scale deposits impose critical issues in selecting the metal components used at geothermal power plants operating at brine temperatures up to 300 C. Replacing these components is very costly and time consuming. Currently, components made of titanium alloy and stainless steel commonly are employed for dealing with these problems. However, another major consideration in using these metals is not only that they are considerably more expensive than carbon steel, but also the susceptibility of corrosion-preventing passive oxide layers that develop on their outermost surface sites to reactions with brine-induced scales, such as silicate, silica, and calcite. Such reactions lead to the formation of strong interfacial bonds between the scales and oxide layers, causing the accumulation of multiple layers of scales, and the impairment of the plant component's function and efficacy; furthermore, a substantial amount of time is entailed in removing them. This cleaning operation essential for reusing the components is one of the factors causing the increase in the plant's maintenance costs. If inexpensive carbon steel components could be coated and lined with cost-effective high-hydrothermal temperature stable, anti-corrosion, -oxidation, and -fouling materials, this would improve the power plant's economic factors by engendering a considerable reduction in capital investment, and a decrease in the costs of operations and maintenance through optimized maintenance schedules.

  15. Microstructure, Processing, Performance Relationships for High Temperature Coatings

    SciTech Connect (OSTI)

    Thomas M. Lillo; Richard N. Wright; W. David Swank; D.C Haggard; Dennis C. Kunerth; Denis E. Clark

    2008-07-01

    HVOF coating have shown high resistance to corrosion in fossil energy applications and it is generally accepted that mechanical failure, e.g. cracking or spalling, ultimately will determine coating lifetime. The high velocity oxygen-fuel method (HVOF) of applying coatings is one of the most commercially viable and allows the control of various parameters including powder particle velocity and temperature which influence coating properties, such as residual stress, bond coat strength and microstructure. Methods of assessing the mechanical durability of coatings are being developed in order to explore the relationship between HVOF spraying parameters and the mechanical properties of the coating and coating bond strength. The room temperature mechanical strength, as well as the resistance of the coating to cracking/spalling during thermal transients, is of considerable importance. Eddy current, acoustic emission and thermal imaging methods are being developed to detect coating failure during thermal cycling tests and room temperature tensile tests. Preliminary results on coating failure of HVOF FeAl coatings on carbon steel, as detected by eddy current measurements during thermal cycling, are presented. The influence of HVOF coating parameters of iron aluminides - applied to more relevant structural steels, like 316 SS and Grade 91 steel, - on coating durability will be explored once reliable methods for identification of coating failure have been developed.

  16. Assessment of ceramic coatings for metal fuel melting crucible

    SciTech Connect (OSTI)

    Kim, Ki-Hwan; Song, Hoon; Kim, Jong-Hwan; Oh, Seok-Jin; Kim, Hyung-Tae; Lee, Chan-Bock

    2013-07-01

    The objective of this study is to develop a coating method and material for crucibles to prevent material interactions with the U-Zr/U-TRU-Zr fuels during the manufacturing of SFR fuels. Refractory coatings were applied to niobium substrates by vacuum plasma-spray coating method. Melt dipping tests conducted were the coated rods lowered into the fuel melt at 1600 C. degrees, and withdrawn and cooled outside the crucible in the inert atmosphere of the induction furnace. Melt dipping tests of the coated Nb rods indicated that plasma-sprayed Y{sub 2}O{sub 3} coating doesn't form significant reaction layer between fuel melt and coating layer. Melt dipping tests of the coated Nb rods showed that TiC, TaC, and Y{sub 2}O{sub 3} coatings exhibited the promising performance among other ceramic coatings. These materials could be promising candidate materials for the reusable melt crucible of metal fuel for SFR. In addition, in order to develop the vacuum plasma-spray coating method for re-usable crucible of metal fuel slugs to be overcome the issue of thermal expansion mismatch between coating material and crucible, various combinations of coating conditions were investigated to find the bonding effect on the substrate in pursuit of more effective ways to withstand the thermal stresses. It is observed that most coating methods maintained sound coating state in U-Zr melt. (authors)

  17. X-ray diffraction and electron microscope studies of yttria stabilized zirconia (YSZ) ceramic coatings exposed to vanadia. Master's thesis

    SciTech Connect (OSTI)

    Kondos, K.G.

    1992-09-01

    The U.S. Navy sometimes has the requirement to use low cost fuels containing significant amounts of vanadium and sulfur in gas turbine engines. Unfortunately the yttria stabilized zirconia (YSZ) witch is used as a thermal barrier coating on gas turbine blades can be severely attacked by vanadia. Powders of YSZ containing 8-mol% Y203 and pure zirconia containing various and mounts Of V205 were annealed at 900 deg. C. These were then examined by X-ray diffraction and electron microscopy, as well as single crystals of pure Zro2 and YSZ ( 20% Wt Y203 ) exposed to V205 Melts, to study how the vanadia degrades the YSZ by reacting with the stabilizer to form YVO4 and how the vanadium transforms the cubic and tetragonal YSZ crystal structures to monoclinic which degrades rapidly as a gas turbine blade coating.

  18. The Advanced Coatings Lab is located at the National Center for Aviation Training and specializes in research, development and testing of aerospace coatings.

    E-Print Network [OSTI]

    The Advanced Coatings Lab is located at the National Center for Aviation Training and specializes in research, development and testing of aerospace coatings. ADVANCED COATINGS LAB CAPABILITIES ·New coatings coatings ·Materials/process evaluation and optimization ·Coatings application process improvement ·Product

  19. Breaking Barriers in Polymer Additive Manufacturing

    SciTech Connect (OSTI)

    Love, Lonnie J; Duty, Chad E; Post, Brian K; Lind, Randall F; Lloyd, Peter D; Kunc, Vlastimil; Peter, William H; Blue, Craig A

    2015-01-01

    Additive Manufacturing (AM) enables the creation of complex structures directly from a computer-aided design (CAD). There are limitations that prevent the technology from realizing its full potential. AM has been criticized for being slow and expensive with limited build size. Oak Ridge National Laboratory (ORNL) has developed a large scale AM system that improves upon each of these areas by more than an order of magnitude. The Big Area Additive Manufacturing (BAAM) system directly converts low cost pellets into a large, three-dimensional part at a rate exceeding 25 kg/h. By breaking these traditional barriers, it is possible for polymer AM to penetrate new manufacturing markets.

  20. Coastal Barrier Resources Act | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower Ventures Jump to: navigation, searchClover Hill HighPowerCoastal Barrier

  1. Issues for conversion coating of aluminum alloys with hydrotalcite

    SciTech Connect (OSTI)

    Drewien, C.A.; Buchheit, R.G.

    1993-12-01

    Hydrotalcite coatings on aluminum alloys are being developed for corrosion protection of aluminum in aggressive saline environments. Coating bath composition, surface pretreatment, and alloying elements in aluminum all influence the performance of these coatings during salt spray testing. The coating bath, comprised of lithium carbonate, requires aging by dissolution of aluminum into the bath in order to grow corrosion resistant coatings. Coatings formed in non- aged baths do not perform well in salt spray testing. The alloying elements in aluminum alloys, especially copper, influence the coating growth and formation leading to thin coatings. The effect of the alloy elements is to limit the supply of aluminum to the coating/electrolyte interface and hinder growth of hydrotalcite upon aluminum alloys.

  2. METAL FOILS FOR DIRECT APPLICATION OF ABSORBER COATINGS ON SOLAR COLLECTORS

    E-Print Network [OSTI]

    Lampert, Carl M.

    2011-01-01

    for Depositing Solar Collector Coatings i i • Proceedingsof the AES Coatings for Solar Collectors Symposium. Atlanta.48. REFERENCES C. M. • "Coatings for Enhanced Photothermal

  3. The POLARBEAR Cosmic Microwave Background Polarization Experiment and Anti-Reflection Coatings for Millimeter Wave Observations

    E-Print Network [OSTI]

    Quealy, Erin

    2012-01-01

    Flat Anti-Reflection Coating . . . . . . . . . . 4.3.2 Anti-Kam Arnold . . . . . . . . . . . . . . . . AR CoatingAnti-Reflection Coatings . . . . . 2.2.2 Signal and Mapping

  4. Applications in the Nuclear Industry for Thermal Spray Amorphous Metal and Ceramic Coatings

    E-Print Network [OSTI]

    Blink, J.; Farmer, J.; Choi, J.; Saw, C.

    2009-01-01

    jet cutting (left) and after coating with SAM2X5 (right).and applied as protective coatings on numerous prototypescor- rosion resistant coatings, and tunnel boring machine

  5. METAL FOILS FOR DIRECT APPLICATION OF ABSORBER COATINGS ON SOLAR COLLECTORS

    E-Print Network [OSTI]

    Lampert, Carl M.

    2011-01-01

    Sputtering for Depositing Solar Collector Coatings".Proceedings of the AES Coatings for Solar Collectorsanalysis is noted. This coating has some theoretical

  6. METAL FOILS FOR DIRECT APPLICATION OF ABSORBER COATINGS ON SOLAR COLLECTORS

    E-Print Network [OSTI]

    Lampert, Carl M.

    2011-01-01

    for Depositing Solar Collector Coatings". Proceedings of theSymposium on Coatings for Solar Collectors, . Louis,'MO,OF ABSORBER COATINGS ON SOLAR COLLECTORS Carl M. Lampert

  7. METAL FOILS FOR DIRECT APPLICATION OF ABSORBER COATINGS ON SOLAR COLLECTORS

    E-Print Network [OSTI]

    Lampert, Carl M.

    2011-01-01

    of the AES Coatings for Solar Collectors Symposium. Atlanta.Sputtering for Depositing Solar Collector Coatings".Symposium on Coatings for Solar Collectors, . Louis,'MO,

  8. Temporal and spatial study of drying of suspension and solution droplets for tablets coating purposes

    E-Print Network [OSTI]

    Sartori Velasco, Silvana

    2010-01-01

    Problem of Tablets Coating . . . . . . . . 4.2 Decelerationtablet . . . Figure 1.2: Particle Coating and Encapsulation:Figure 1.3: Particle Coating and Encapsulation:

  9. THERMAL DEGRADATION OF A BLACK CHROME SOLAR SELECTIVE ABSORBER COATING: SHORT TERM

    E-Print Network [OSTI]

    Lampert, Carl M.

    2011-01-01

    heat treatments, this coating shows growth of Cr o particlesall practical purposes the coating has failed between 500-re- search project. 5. The coating, for practical purposes,

  10. A simple, high-yield, apparatus for NEG coating of vacuum beamline elements

    E-Print Network [OSTI]

    Ron, Guy

    2011-01-01

    magnet arrange- ment. 4.1 Coating Thin Tubes Thin tubesyield, apparatus for NEG coating of vacuum beamline elementscost apparatus, which allows coating of very small diameter

  11. The influence of size, shape, and surface coating on the stability of aqueous nanoparticle suspensions

    E-Print Network [OSTI]

    Mulvihill, M.J.

    2011-01-01

    Size, Shape, and Surface Coating on the Stability of Aqueoussize, shape, and surface coating of cadmium selenideinstability of the ligand coatings, which varied directly

  12. Underground barrier construction apparatus with soil-retaining shield

    DOE Patents [OSTI]

    Gardner, B.M.; Smith, A.M.; Hanson, R.W.; Hodges, R.T.

    1998-08-04

    An apparatus is described for building a horizontal underground barrier by cutting through soil and depositing a slurry, preferably one which cures into a hardened material. The apparatus includes a digging means for cutting and removing soil to create a void under the surface of the ground, a shield means for maintaining the void, and injection means for inserting barrier-forming material into the void. In one embodiment, the digging means is a continuous cutting chain. Mounted on the continuous cutting chain are cutter teeth for cutting through soil and discharge paddles for removing the loosened soil. This invention includes a barrier placement machine, a method for building an underground horizontal containment barrier using the barrier placement machine, and the underground containment system. Preferably the underground containment barrier goes underneath and around the site to be contained in a bathtub-type containment. 17 figs.

  13. Underground barrier construction apparatus with soil-retaining shield

    DOE Patents [OSTI]

    Gardner, Bradley M. (Idaho Falls, ID); Smith, Ann Marie (Pocatello, ID); Hanson, Richard W. (Spokane, WA); Hodges, Richard T. (Deer Park, WA)

    1998-01-01

    An apparatus for building a horizontal underground barrier by cutting through soil and depositing a slurry, preferably one which cures into a hardened material. The apparatus includes a digging means for cutting and removing soil to create a void under the surface of the ground, a shield means for maintaining the void, and injection means for inserting barrier-forming material into the void. In one embodiment, the digging means is a continuous cutting chain. Mounted on the continuous cutting chain are cutter teeth for cutting through soil and discharge paddles for removing the loosened soil. This invention includes a barrier placement machine, a method for building an underground horizontal containment barrier using the barrier placement machine, and the underground containment system. Preferably the underground containment barrier goes underneath and around the site to be contained in a bathtub-type containment.

  14. Multiple capillary biochemical analyzer with barrier member

    DOE Patents [OSTI]

    Dovichi, Norman J. (Edmonton, CA); Zhang, Jian Z. (Edmonton, CA)

    1996-01-01

    A multiple capillary biochemical analyzer for sequencing DNA and performing other analyses, in which a set of capillaries extends from wells in a microtiter plate into a cuvette. In the cuvette the capillaries are held on fixed closely spaced centers by passing through a sandwich construction having a pair of metal shims which squeeze between them a rubber gasket, forming a leak proof seal for an interior chamber in which the capillary ends are positioned. Sheath fluid enters the chamber and entrains filament sample streams from the capillaries. The filament sample streams, and sheath fluid, flow through aligned holes in a barrier member spaced close to the capillary ends, into a collection chamber having a lower glass window. The filament streams are illuminated above the barrier member by a laser, causing them to fluoresce. The fluorescence is viewed end-on by a CCD camera chip located below the glass window. The arrangement ensures an equal optical path length from all fluorescing spots to the CCD chip and also blocks scattered fluorescence illumination, providing more uniform results and an improved signal to noise ratio.

  15. Multiple capillary biochemical analyzer with barrier member

    DOE Patents [OSTI]

    Dovichi, N.J.; Zhang, J.Z.

    1996-10-22

    A multiple capillary biochemical analyzer is disclosed for sequencing DNA and performing other analyses, in which a set of capillaries extends from wells in a microtiter plate into a cuvette. In the cuvette the capillaries are held on fixed closely spaced centers by passing through a sandwich construction having a pair of metal shims which squeeze between them a rubber gasket, forming a leak proof seal for an interior chamber in which the capillary ends are positioned. Sheath fluid enters the chamber and entrains filament sample streams from the capillaries. The filament sample streams, and sheath fluid, flow through aligned holes in a barrier member spaced close to the capillary ends, into a collection chamber having a lower glass window. The filament streams are illuminated above the barrier member by a laser, causing them to fluoresce. The fluorescence is viewed end-on by a CCD camera chip located below the glass window. The arrangement ensures an equal optical path length from all fluorescing spots to the CCD chip and also blocks scattered fluorescence illumination, providing more uniform results and an improved signal-to-noise ratio. 12 figs.

  16. Quantum calculation of Coulomb reorientation and near-barrier fusion

    E-Print Network [OSTI]

    Cédric Simenel; Michael Bender; Philippe Chomaz; Thomas Duguet; Gilles De France

    2006-05-08

    We investigate the role of deformation on the fusion probability around the barrier using the Time-Dependent Hartree-Fock theory with a full Skyrme force. We obtain a distribution of fusion probabilities around the nominal barrier due to the different contributions of the various orientations of the deformed nucleus at the touching point. It is also shown that the long range Coulomb reorientation reduces the fusion probability around the barrier.

  17. Test device for measuring permeability of a barrier material

    DOE Patents [OSTI]

    Reese, Matthew; Dameron, Arrelaine; Kempe, Michael

    2014-03-04

    A test device for measuring permeability of a barrier material. An exemplary device comprises a test card having a thin-film conductor-pattern formed thereon and an edge seal which seals the test card to the barrier material. Another exemplary embodiment is an electrical calcium test device comprising: a test card an impermeable spacer, an edge seal which seals the test card to the spacer and an edge seal which seals the spacer to the barrier material.

  18. 2D barrier in a superconducting niobium square

    SciTech Connect (OSTI)

    Joya, Miryam R. Barba-ortega, J.; Sardella, Edson

    2014-11-05

    The presence of barriers changes the vortex structure in superconducting Nb square in presence of a uniform applied magnetic field. The Cooper pair configurations in a mesoscopics superconducting square of Nb with a barrier are calculated within the nonlinear Ginzburg Landau equations. We predict the nucleation of multi-vortex states into the sample and a soft entry of the magnetic field inside and around into the barrier. A novel and non-conventional vortex configurations occurs at determined magnetic field.

  19. Neurophenomenological Constraints and Pushing Back the Subjectivity Barrier

    E-Print Network [OSTI]

    MacLennan, Bruce

    Neurophenomenological Constraints and Pushing Back the Subjectivity Barrier Extended commentary inversions), without appealing to weak arguments based on basic color categories; that is, I suggest

  20. Identifying and Overcoming Critical Barriers to Widespread Second...

    Office of Scientific and Technical Information (OSTI)

    Overcoming Critical Barriers to Widespread Second Use of PEV Batteries Neubauer, J.; Smith, K.; Wood, E.; Pesaran, A. 25 ENERGY STORAGE; 29 ENERGY PLANNING, POLICY AND ECONOMY...

  1. Hydrologic Behavior of Two Engineered Barriers Following Extreme Wetting

    SciTech Connect (OSTI)

    Porro, I.

    2000-09-30

    Many engineered barriers are expected to function for hundreds of years or longer. Over the course of time, it is likely that some barriers will experience infiltration to the point of breakthrough. This study compares the recovery from breakthrough of two storage- evapotranspiration type engineered barriers. Replicates of test plots comprising thick soil and capillary/biobarrier covers were wetted to breakthrough in 1997. Test plots were kept cleared of vegetation to maximize hydrologic stress during recovery. Following cessation of drainage resulting from the wetting irrigations, water storage levels in all plots were at elevated levels compared to pre-irrigation levels. As a result, infiltration of melting snow during the subsequent spring overloaded the storage capacity and produced drainage in all plots. Relatively rapid melting of accumulated snowfall produced the most significant infiltration events each year during the study. Capillary barriers yielded less total drainage than thick soil barriers. By limiting drainage, capillary barriers increased water storage in the upper portions of the test plots, which led to increased evaporation from the capillary barrier plots compared to thick soil plots. Increased evaporation in the capillary barrier plots allowed more water to infiltrate in the second season following the wetting tests without triggering drainage. All thick soil plots again yielded drainage in the second season. Within two years of intentionally induced breakthrough, evaporation alone (without transpiration) restored the capability of the capillary barrier covers to function as intended, although water storage in these covers remained at elevated levels.

  2. THREE VIRGINIA PROGRAMS OVERCOME BARRIERS TO UPGRADES | Department...

    Broader source: Energy.gov (indexed) [DOE]

    home energy improvements in different regions of the state. Three regional energy alliances operated individual pilot programs to address local needs and barriers: the Local...

  3. Panel 4, Grid-Scale Storage Technologies: Regulatory Barriers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grid-scale Storage Technologies Regulatory Barriers and Policy Instruments Hydrogen Energy Storage for Grid and Transportation Services May 15 th , 2014 Sacramento, CA Demand 599...

  4. Deployment Barriers to Distributed Wind Energy. Workshop Report

    SciTech Connect (OSTI)

    Ahlgrimm, Jim; Hartman, Liz; Barker, Bret; Fry, Chris; Meissner, John; Forsyth, Trudy; Baring-Gould, Ian; Newcomb, Charles

    2010-10-28

    This report presents key findings from the Department of Energy's Deployment Barriers to Distributed Wind Technology Workshop, held October 28, 2010 in Denver, Colorado.

  5. Resolving Code and Standard Barriers to Building America Innovations...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    resources for a Codes and Standards Innovation (CSI) team to assist research partners and industry in overcoming codes and standards barriers to high-performance innovations. The...

  6. Effects of barrier composition and electroplating chemistry on adhesion and voiding in copper/dielectric diffusion barrier films

    SciTech Connect (OSTI)

    Birringer, Ryan P.; Dauskardt, Reinhold H. [Department of Materials Science and Engineering, Stanford University, Durand Building, Stanford, California 94305-4034 (United States); Shaviv, Roey [Novellus Systems Inc., 4000 North First Street, San Jose, California 95134 (United States); Geiss, Roy H.; Read, David T. [National Institute of Standards and Technology, 325 Broadway, Boulder, Colorado 80305 (United States)

    2011-08-15

    The effects of electroplating chemistry and dielectric diffusion barrier composition on copper voiding and barrier adhesion are reported. Adhesion was quantified using the four-point bend thin film adhesion technique, and voiding in the Cu films was quantified using scanning electron microscopy. A total of 12 different film stacks were investigated, including three different Cu electroplating chemistries and four different barrier materials (SiN, N-doped SiC, O-doped SiC, and dual-layer SiC). Both plating chemistry and barrier composition have a large effect on interface adhesion and voiding in the Cu film. X-ray photoelectron spectroscopy was used to investigate the segregation of Cu electroplating impurities, such as S and Cl, to the Cu/barrier interface. Secondary ion mass spectrometry was used to quantify oxygen content at the Cu/barrier interface in a subset of samples. This interface oxygen content is correlated with measured adhesion values.

  7. Platinum-aluminide coating enhances durability

    SciTech Connect (OSTI)

    Punola, D.; Sikkenga, D.; Sutton, M. [Howmet Corp., Whitehall, MI (United States)

    1995-12-01

    Severe demands on coatings for gas turbine engines that must operate at significantly higher temperatures than previously required have led to the development of an advanced two-step platinum-modified-aluminide diffusion coating. The conventional system consists of platinum electroplating followed by a traditional pack cementation aluminizing process. This coating greatly extends the durability of hot-section components in environments characterized by high-temperature oxidation and corrosion. Conventionally deposited platinum aluminides, such as Howmet`s LDC2E, demonstrated that a change in material could deliver higher levels of durability. However, the next challenge was to develop a more controllable, faster, cleaner process with improved yield and quality levels. The challenge was met by chemical vapor deposition (CVD). This method is now used to apply aluminum to the part after platinum electroplating. It replaces the traditional pack cementation or above-the-pack techniques, and bypasses all the shortcomings associated with those processes.

  8. Polymeric complexes of polyaniline as anticorrosion coatings

    SciTech Connect (OSTI)

    Racicot, R.J.; Yang, S.C.; Brown, R.

    1998-07-01

    During the past few years there has been a strong interest in developing conducting polymers as an alternative to the traditional anticorrosion coatings. One of the driving forces for this research comes from the need for an environmentally friendly chromate-free anticorrosion coating for high-strength light weight aluminum alloys. The possibilities for a new scratch-tolerant paint for steel prompted the development of conductive polymer anticorrosion paints. By molecular engineering, the authors have synthesized a double-strand polymeric complex of polyaniline that is suitable as an anticorrosion paint on metals in low pH environments. In this article, the authors will discuss (1) the molecular design for solubility and adhesion, (2) the effectiveness of the electroactive coating under electrochemical impedance tests, and (3) a mechanistic study of the anticorrosion mechanism by examining the polymer/metal interfacial interactions.

  9. Method of fabricating boron containing coatings

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Jankowski, Alan F. (Livermore, CA)

    1999-01-01

    Hard coatings are fabricated from boron nitride, cubic boron nitride, and multilayer boron/cubic boron nitride, and the fabrication thereof involves magnetron sputtering in a selected atmosphere. These hard coatings may be applied to tools and engine and other parts, as well to reduce wear on tribological surfaces and electronic devices. These boron coatings contain no morphological growth features. For example, the boron is formed in an inert (e.g. argon) atmosphere, while the cubic boron nitride is formed in a reactive (e.g. nitrogen) atmosphere. The multilayer boron/cubic boron nitride, is produced by depositing alternate layers of boron and cubic boron nitride, with the alternate layers having a thickness of 1 nanometer to 1 micrometer, and at least the interfaces of the layers may be discrete or of a blended or graded composition.

  10. Figure correction of multilayer coated optics

    DOE Patents [OSTI]

    Chapman; Henry N. (Livermore, CA), Taylor; John S. (Livermore, CA)

    2010-02-16

    A process is provided for producing near-perfect optical surfaces, for EUV and soft-x-ray optics. The method involves polishing or otherwise figuring the multilayer coating that has been deposited on an optical substrate, in order to correct for errors in the figure of the substrate and coating. A method such as ion-beam milling is used to remove material from the multilayer coating by an amount that varies in a specified way across the substrate. The phase of the EUV light that is reflected from the multilayer will be affected by the amount of multilayer material removed, but this effect will be reduced by a factor of 1-n as compared with height variations of the substrate, where n is the average refractive index of the multilayer.

  11. Glass/ceramic coatings for implants

    DOE Patents [OSTI]

    Tomsia, Antoni P. (Pinole, CA); Saiz, Eduardo (Berkeley, CA); Gomez-Vega, Jose M. (Nagoya, JP); Marshall, Sally J. (Larkspur, CA); Marshall, Grayson W. (Larkspur, CA)

    2011-09-06

    Glass coatings on metals including Ti, Ti6A14V and CrCo were prepared for use as implants. The composition of the glasses was tailored to match the thermal expansion of the substrate metal. By controlling the firing atmosphere, time, and temperature, it was possible to control the reactivity between the glass and the alloy and to fabricate coatings (25-150 .mu.m thick) with excellent adhesion to the substrate. The optimum firing temperatures ranged between 800 and 840.degree. C. at times up to 1 min in air or 15 min in N.sub.2. The same basic technique was used to create multilayered coatings with concentration gradients of hydroxyapatite (HA) particles and SiO.sub.2.

  12. Multilayer ultra-high-temperature ceramic coatings

    DOE Patents [OSTI]

    Loehman, Ronald E. (Albuquerque, NM); Corral, Erica L. (Tucson, AZ)

    2012-03-20

    A coated carbon-carbon composite material with multiple ceramic layers to provide oxidation protection from ultra-high-temperatures, where if the carbon-carbon composite material is uninhibited with B.sub.4C particles, then the first layer on the composite material is selected from ZrB.sub.2 and HfB.sub.2, onto which is coated a layer of SiC coated and if the carbon-carbon composite material is inhibited with B.sub.4C particles, then protection can be achieved with a layer of SiC and a layer of either ZrB.sub.2 and HfB.sub.2 in any order.

  13. Method of fabricating boron containing coatings

    DOE Patents [OSTI]

    Makowiecki, D.M.; Jankowski, A.F.

    1999-04-27

    Hard coatings are fabricated from boron nitride, cubic boron nitride, and multilayer boron/cubic boron nitride, and the fabrication thereof involves magnetron sputtering in a selected atmosphere. These hard coatings may be applied to tools and engine and other parts, as well to reduce wear on tribological surfaces and electronic devices. These boron coatings contain no morphological growth features. For example, the boron is formed in an inert (e.g. argon) atmosphere, while the cubic boron nitride is formed in a reactive (e.g. nitrogen) atmosphere. The multilayer boron/cubic boron nitride, is produced by depositing alternate layers of boron and cubic boron nitride, with the alternate layers having a thickness of 1 nanometer to 1 micrometer, and at least the interfaces of the layers may be discrete or of a blended or graded composition. 3 figs.

  14. Colloidal spray method for low cost thin coating deposition

    DOE Patents [OSTI]

    Pham, Ai-Quoc; Glass, Robert S.; Lee, Tae H.

    2005-01-25

    A dense or porous coating of material is deposited onto a substrate by forcing a colloidal suspension through an ultrasonic nebulizer and spraying a fine mist of particles in a carrier medium onto a sufficiently heated substrate. The spraying rate is essentially matched to the evaporation rate of the carrier liquid from the substrate to produce a coating that is uniformly distributed over the surface of the substrate. Following deposition to a sufficient coating thickness, a single sintering step may be used to produce a dense ceramic coating. Using this method, coatings ranging in thickness from about one to several hundred microns can be obtained. By using a plurality of compounds in the colloidal suspension, coatings of mixed composition can be obtained. By using a plurality of solutions and separate pumps and a single or multiple ultrasonic nebulizer(s), and varying the individual pumping rates and/or the concentrations of the solutions, a coating of mixed and discontinuously graded (e.g., stepped) or continuously graded layers may be obtained. This method is particularly useful for depositing ceramic coatings. Dense ceramic coating materials on porous substrates are useful in providing improved electrode performance in devices such as high power density solid oxide fuel cells. Dense ceramic coatings obtained by the invention are also useful for gas turbine blade coatings, sensors, steam electrolyzers, etc. The invention has general use in preparation of systems requiring durable and chemically resistant coatings, or coatings having other specific chemical or physical properties.

  15. Colloidal spray method for low cost thin coating deposition

    DOE Patents [OSTI]

    Pham, Ai-Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA); Lee, Tae H. (Naperville, IL)

    2002-01-01

    A dense or porous coating of material is deposited onto a substrate by forcing a colloidal suspension through an ultrasonic nebulizer and spraying a fine mist of particles in a carrier medium onto a sufficiently heated substrate. The spraying rate is essentially matched to the evaporation rate of the carrier liquid from the substrate to produce a coating that is uniformly distributed over the surface of the substrate. Following deposition to a sufficient coating thickness, a single sintering step may be used to produce a dense ceramic coating. Using this method, coatings ranging in thickness from about one to several hundred microns can be obtained. By using a plurality of compounds in the colloidal suspension, coatings of mixed composition can be obtained. By using a plurality of solutions and separate pumps and a single or multiple ultrasonic nebulizer(s), and varying the individual pumping rates and/or the concentrations of the solutions, a coating of mixed and discontinuously graded (e.g., stepped) or continuously graded layers may be obtained. This method is particularly useful for depositing ceramic coatings. Dense ceramic coating materials on porous substrates are useful in providing improved electrode performance in devices such as high power density solid oxide fuel cells. Dense ceramic coatings obtained by the invention are also useful for gas turbine blade coatings, sensors, steam electrolyzers, etc. The invention has general use in preparation of systems requiring durable and chemically resistant coatings, or coatings having other specific chemical or physical properties.

  16. Optics and multilayer coatings for EUVL systems

    SciTech Connect (OSTI)

    Soufli, R; Bajt, S; Hudyma, R M; Taylor, J S

    2008-03-21

    EUV lithography (EUVL) employs illumination wavelengths around 13.5 nm, and in many aspects it is considered an extension of optical lithography, which is used for the high-volume manufacturing (HVM) of today's microprocessors. The EUV wavelength of illumination dictates the use of reflective optical elements (mirrors) as opposed to the refractive lenses used in conventional lithographic systems. Thus, EUVL tools are based on all-reflective concepts: they use multilayer (ML) coated optics for their illumination and projection systems, and they have a ML-coated reflective mask.

  17. Monolayer coated aerogels and method of making

    SciTech Connect (OSTI)

    Zemanian, Thomas Samuel (Richland, WA); Fryxell, Glen (Kennwick, WA); Ustyugov, Oleksiy A. (Spokane, WA)

    2006-03-28

    Aerogels having a monolayer coating are described. The aerogel and a monolayer forming precursor are provided in a supercritical fluid, whereupon the aerogel and the monolayer forming precursor are reacted in said supercritical fluid to form a covalent bond between the aerogel and the monolayer forming precursor. Suitable aerogels are ceramic oxides such as silica, alumina, aluminosilicate, and combinations thereof. Suitable monolayer forming precursors include alkyl silanes, chlorosilanes, boranes, chloroboranes, germanes, and combinations thereof. The method may also include providing a surface preparation agent such as water, or hydroetching an aerogel to enhance the coating of the monolayer.

  18. Coating thermal noise for arbitrary shaped beams

    E-Print Network [OSTI]

    Richard O'Shaughnessy

    2006-10-13

    Advanced LIGO's sensitivity will be limited by coating noise. Though this noise depends on beam shape, and though nongaussian beams are being seriously considered for advanced LIGO, no published analysis exists to compare the quantitative thermal noise improvement alternate beams offer. In this paper, we derive and discuss a simple integral which completely characterizes the dependence of coating thermal noise on shape. The derivation used applies equally well, with minor modifications, to all other forms of thermal noise in the low-frequency limit.

  19. The Cementitious Barriers Partnership (CBP) Software Toolbox Capabilities In Assessing The Degradation Of Cementitious Barriers

    SciTech Connect (OSTI)

    Flach, G. P.; Burns, H. H.; Langton, C.; Smith, F. G. III; Brown, K. G.; Kosson, D. S.; Garrabrants, A. C.; Sarkar, S.; van der Sloot, H.; Meeussen, J. C.L.; Samson, E.; Mallick, P.; Suttora, L.; Esh, D. W.; Fuhrmann, M. J.; Philip, J.

    2013-01-11

    The Cementitious Barriers Partnership (CBP) Project is a multi-disciplinary, multi-institutional collaboration supported by the U.S. Department of Energy (US DOE) Office of Tank Waste and Nuclear Materials Management. The CBP program has developed a set of integrated tools (based on state-of-the-art models and leaching test methods) that help improve understanding and predictions of the long-term structural, hydraulic and chemical performance of cementitious barriers used in nuclear applications. Tools selected for and developed under this program have been used to evaluate and predict the behavior of cementitious barriers used in near-surface engineered waste disposal systems for periods of performance up to 100 years and longer for operating facilities and longer than 1000 years for waste disposal. The CBP Software Toolbox has produced tangible benefits to the DOE Performance Assessment (PA) community. A review of prior DOE PAs has provided a list of potential opportunities for improving cementitious barrier performance predictions through the use of the CBP software tools. These opportunities include: 1) impact of atmospheric exposure to concrete and grout before closure, such as accelerated slag and Tc-99 oxidation, 2) prediction of changes in Kd/mobility as a function of time that result from changing pH and redox conditions, 3) concrete degradation from rebar corrosion due to carbonation, 4) early age cracking from drying and/or thermal shrinkage and 5) degradation due to sulfate attack. The CBP has already had opportunity to provide near-term, tangible support to ongoing DOE-EM PAs such as the Savannah River Saltstone Disposal Facility (SDF) by providing a sulfate attack analysis that predicts the extent and damage that sulfate ingress will have on the concrete vaults over extended time (i.e., > 1000 years). This analysis is one of the many technical opportunities in cementitious barrier performance that can be addressed by the DOE-EM sponsored CBP software tools. Modification of the existing tools can provide many opportunities to bring defense in depth in prediction of the performance of cementitious barriers over time.

  20. Iron-Based Amorphous Coatings Produced by HVOF Thermal Spray Processing-Coating Structure and Properties

    SciTech Connect (OSTI)

    Beardsley, M B

    2008-03-26

    The feasibility to coat large SNF/HLW containers with a structurally amorphous material (SAM) was demonstrated on sub-scale models fabricated from Type 316L stainless steel. The sub-scale model were coated with SAM 1651 material using kerosene high velocity oxygen fuel (HVOF) torch to thicknesses ranging from 1 mm to 2 mm. The process parameters such as standoff distance, oxygen flow, and kerosene flow, were optimized in order to improve the corrosion properties of the coatings. Testing in an electrochemical cell and long-term exposure to a salt spray environment were used to guide the selection of process parameters.

  1. Damage threshold of platinum coating used for optics for self...

    Office of Scientific and Technical Information (OSTI)

    Published Article: Damage threshold of platinum coating used for optics for self-seeding of soft x-ray free electron laser Title: Damage threshold of platinum coating used for...

  2. Polymer-coated iron oxide nanoparticles for medical imaging

    E-Print Network [OSTI]

    Chen, Suelin, Ph.D. Massachusetts Institute of Technology

    2010-01-01

    One of the most versatile and safe materials used in medicine are polymer-coated iron oxide nanoparticles. This dissertation describes several formulations for in vivo imaging applications. The paramagnetic polymer-coated ...

  3. Wear-Resistant, Nano-Composite Steel Coatings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wear-Resistant, Nano-Composite Steel Coatings Laser Processing Techniques Used for the Production of Wear-Resistant Steel Coatings from Iron-Based Glassy Powders Introduction Steel...

  4. The Addition of Graphene to Polymer Coatings for Improved Weathering

    E-Print Network [OSTI]

    Nuraje, Nurxat

    2013-01-01

    Graphene nanoflakes in different weight percentages were added to polyurethane top coatings, and the coatings were evaluated relative to exposure to two different experimental conditions: one a QUV accelerated weathering ...

  5. Hydrogen permeable protective coating for a catalytic surface

    DOE Patents [OSTI]

    Liu, Ping (Irvine, CA); Tracy, C. Edwin (Golen, CO); Pitts, J. Roland (Lakewood, CO); Lee, Se-Hee (Lakewood, CO)

    2007-06-19

    A protective coating for a surface comprising a layer permeable to hydrogen, said coating being deposited on a catalyst layer; wherein the catalytic activity of the catalyst layer is preserved.

  6. Apparatus for coating and impregnating filament with resin

    DOE Patents [OSTI]

    Robinson, S.C.; Pollard, R.E.

    1986-12-17

    The present invention is directed to an apparatus for evenly coating and impregnating a filament with binder material. Dimension control and repeatability of the coating and impregnating characteristics are obtained with the apparatus.

  7. Saccrifical Protective Coating Materials that can be Regenerated...

    Broader source: Energy.gov (indexed) [DOE]

    Membrane must sustain hot (>85C) WBL at pH of 13-14 Technical Approach Teledyne coating: both membrane surface and inner pore walls are coated without affecting flux ...

  8. MOF Coating a Promising Path to White LEDs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MOF Coating a Promising Path to White LEDs MOF Coating a Promising Path to White LEDs Print Friday, 27 February 2015 17:11 Hu et al. designed a new yellow phosphor with high...

  9. The possibility of forming a sacrificial anode coating for Mg

    SciTech Connect (OSTI)

    Dudney, Nancy J; Li, Juchuan; Sacci, Robert L; Thomson, Jeffery K

    2014-01-01

    Mg is the most active engineering metal, and is often used as a sacrificial anode/coating to protect other engineering metals from corrosion attack. So far no sacrificial anode coating has been developed or considered for Mg. This study explores the possibility of forming a sacrificial coating for Mg. A lithiated carbon coating and a metaphosphated coating are applied on the Mg surface, respectively, and their open-circuit-potentials are measured in saturated Mg(OH)2 solution. They exhibit more negative potentials than bare Mg. SEM reveals that the metaphosphated coating offers more effective and uniform protection for Mg than the lithiated carbon coating. These preliminary results indicate that development of a sacrificial anode coating for Mg is indeed possible.

  10. ULTRA BARRIER TOPSHEET (UBT) FOR FLEXIBLE PHOTOVOLTAICS

    SciTech Connect (OSTI)

    Schubert, Charlene

    2013-01-09

    This slideshow presents work intended to: Scale-up the Generation -1 UBT to 1+meter width full-scale manufacturing; Develop a Generation-2 UBT on the pilot line, targeting improved performance, longer lifetime and lower cost; Transfer Generation-2 UBT from the pilot line to the full-scale manufacturing line in 2014; and Validate service life of Generation-1 UBT for the 25+ year lifetime. 3M has scaled up UBT for production at 1.2 meter width. 3M is conducting extensive lifetime studies including: –Evaluation of customer processing and installation conditions; –Indoor accelerated testing of UBT film and full CIGS modules; –Outdoor testing of UBT film and CIGS modules. Results have been used to improve ultra barrier film performance for flex module applications.

  11. Quantum Walk Search through Potential Barriers

    E-Print Network [OSTI]

    Thomas G. Wong

    2015-09-24

    A randomly walking quantum particle searches for a marked vertex on the complete graph of $N$ vertices in Grover's $\\Theta(\\sqrt{N})$ steps, which is quadratically faster than a classical random walk's $\\Theta(N)$ steps. The basis of this speedup and the success of other quantum walk algorithms is often attributed to the quantum walk's ballistic propagation, which is quadratically faster than a classical random walk's diffusion. We show that this faster propagation is not the whole story, however. If sufficiently strong potential barriers hinder the quantum walk, it can lose its quantum speedup despite retaining ballistic dispersion. Thus ballistic spreading alone does not yield fast quantum walk algorithms. Closer inspection reveals that quantum walks search quickly by applying just the right phases for amplitude amplification to succeed.

  12. CHARACTERIZATION OF A RIGID BARRIER FILTER SYSTEM

    SciTech Connect (OSTI)

    Chiang, Ta-Kuan

    2001-11-06

    A mathematical model is formulated to describe the dynamics of a rigid barrier filter system. Complete with filtration, regeneration and particle re-deposition, this model provides sizing information for new filter systems and diagnostic information for operating filter systems. To turn this model into a practical and smart filter system predictive model, monitoring devices for variables such as real-time particle concentration and size distribution are currently under laboratory development. The program goal is to introduce a smart filter system to supervise its operation and to assure its system reliability. Primarily, a smart filter system will update operating information, sound up malfunction alarms, and provide self-activated measures such as adjusting the cleaning frequency, intensity and back-pulse duration.

  13. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, Roland R. (Lansdale, PA); Bond, James A. (Exton, PA)

    1994-01-01

    A high-voltage electrical insulator (21) for electrically insulating a thermoelectric module (17) in a spacecraft from a niobium-1% zirconium alloy wall (11) of a heat exchanger (13) filled with liquid lithium (16) while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator (21) has a single crystal alumina layer (SxAl.sub.2 O.sub.3, sapphire) with a niobium foil layer (32) bonded thereto on the surface of the alumina crystal (26) facing the heat exchanger wall (11), and a molybdenum layer (31) bonded to the niobium layer (32) to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface.

  14. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

  15. ORNL superhydrophobic glass coating offers clear benefits | ornl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interconnected nanoporous nature of our coatings significantly suppresses Fresnel light reflections from glass surfaces, providing enhanced transmission over a wide...

  16. Lithium battery electrodes with ultra-thin alumina coatings

    DOE Patents [OSTI]

    Se-Hee, Lee; George, Steven M.; Cavanagh, Andrew S.; Yoon Seok, Jung; Dillon, Anne C.

    2015-11-24

    Electrodes for lithium batteries are coated via an atomic layer deposition process. The coatings can be applied to the assembled electrodes, or in some cases to particles of electrode material prior to assembling the particles into an electrode. The coatings can be as thin as 2 .ANG.ngstroms thick. The coating provides for a stable electrode. Batteries containing the electrodes tend to exhibit high cycling capacities.

  17. Cube-corner reflectors with interference dielectric coating

    SciTech Connect (OSTI)

    Sokolov, A L; Murashkin, V V; Akent'ev, A S; Karaseva, E A

    2013-09-30

    The cube-corner reflectors (CCRs) with a special interference dielectric coating intended for ring retroreflector systems of space vehicles with uniaxial orientation are considered. The diffraction patterns of radiation reflected from the CCRs with different face coatings are studied. It is shown that the choice of the angle between the faces, the size and the coating of CCR faces allow essential variation in the diffraction pattern, thereby providing its optimisation for solving different navigation problems. (nanogradient dielectric coatings and metamaterials)

  18. Accurate calculation of thermal noise in multilayer coating

    E-Print Network [OSTI]

    Alexey Gurkovsky; Sergey Vyatchanin

    2010-05-18

    We derive accurate formulas for thermal fluctuations in multilayer interferometric coating taking into account light propagation inside the coating. In particular, we calculate the reflected wave phase as a function of small displacements of the boundaries between the layers using transmission line model for interferometric coating and derive formula for spectral density of reflected phase in accordance with Fluctuation-Dissipation Theorem. We apply the developed approach for calculation of the spectral density of coating Brownian noise.

  19. Progress in Large Period Multilayer Coatings for High Harmonic and Solar Applications

    E-Print Network [OSTI]

    Aquila, Andrew

    2008-01-01

    large period multilayer coatings for high harmonic and solarBerkeley, CA 94720 Multilayer coatings for normal incidence

  20. Tunneling of Graphene Massive Dirac Fermions through a Double Barrier

    E-Print Network [OSTI]

    Hocine Bahlouli; El Bouazzaoui Choubabi; Ahmed Jellal; Miloud Mekkaoui

    2011-10-04

    We study the tunneling of Dirac fermions in graphene through a double barrier potential allowing the carriers to have an effective mass inside the barrier as generated by a lattice miss-match with the boron nitride substrate. The consequences of this gap opening on the transmission are investigated. The realization of resonant tunneling conditions is also analyzed.