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Sample records for bakken formation producing

  1. Treating-pressure analysis in the Bakken formation

    SciTech Connect (OSTI)

    Cramer, D.D. )

    1992-01-01

    The Bakken formation is an oil-producing interval in the Williston basin. Usually, commercial Bakken wells are linked to an anisotropic natural fracture network. Hydraulic fracturing treatments have been used extensively in vertical wells and to a limited extent in horizontal wells. In this paper, bottom hole treating pressure (BHTP's) are analyzed to improve understanding of hydraulic fracture propagation in the Bakken.

  2. Regional geology and petroleum potential of Bakken Formation, southwestern Manitoba

    SciTech Connect (OSTI)

    Martiniuk, C.D.

    1988-07-01

    The Bakken Formation has been documented as an excellent petroleum source rock within the Williston basin and has, in some localities, been established as a producing zone. Recent exploration in the Daly field of southwestern Manitoba has led to the discovery and subsequent development of several oil pools within the middle member of the Bakken. The 21 active wells within these pools have produced 20,773.8 m/sup 3/ (130,667.2 bbl) of oil (40.2/degrees/ API) as of December 31, 1987. Through much of the Williston basin, the Bakken typically consists of three members: a lower, highly radioactive, black shale member; a middle siltstone member; and an upper black shale member (identical to the lower member). In southwestern Manitoba, the lower member is absent in most areas due to nondeposition and overstep of the overlying middle member. In these areas, the middle member unconformably overlies eroded red dolomitic shales of the Devonian Lyleton (Three Forks) Formation. The middle member is a relatively uniform blanket deposit averaging 4 m (13 ft) thick. It consists of interbedded tan to greenish-gray, very fine to medium-grained, well-sorted dolomitic sandstone and siltstone with angular to subrounded grains. Oil accumulation in the middle member is largely the result of stratigraphic trapping and appears, in part, to be localized where a basal sandstone (associated with middle member thickening) is concentrated in minor erosional lows on the Lyleton surface. The black shales of the upper member form a thin (2 m or 6.6 ft average), uniform cap throughout the map area and are overlain by the carbonates of the Mississippian Lodgepole Formation (Souris Valley Beds). Maximum thickness of the Bakken reaches 32 m (105 ft) in the Waskada field area, where the lower shale member is locally present.

  3. Source-potential rating index-evaluation of Bakken formation

    SciTech Connect (OSTI)

    Pirkle, F.L., Dembicki, H.

    1985-05-01

    The Bakken formation, an organic-rich, oil-prone unit, is the source of the crude oils found in the middle Bakken and overlying Madison Group. Thickness, organic carbon, and vitrinite reflectance data for the Bakken were gathered from 101 wells within the Williston basin and evaluated in terms of source potential. An index exists that combines sediment thickness, organic carbon content, and thermal maturity data into a single mappable parameter that indicates areas of potential hydrocarbon generation. Multiplying the average percent organic carbon by the effective source rock thickness of a formation yields a richness factor that is then multiplied by maturity scaling factors to give source potential ratings for oil and/or gas generation. By using burial-history curves and thermal-maturation modeling, the rating index can be used to look at source potential through geologic time. The Bakken Formation has been evaluated with the aid of the rating index. The source-potential rating index provides objective semiquantitative measures by which the source potential of a single formation can be compared within an area or the source potential of two or more formations can be compared within the same or different basins. The Bakken did not begin to reach high source potential until toward the end of the Late Cretaceous. This contrasts with previous authorities who believed the Bakken was at peak generation and expelling hydrocarbons throughout the Cretaceous.

  4. Petroleum generation and expulsion in the constrained Bakken petroleum system and its relevance to the formation of fractures

    SciTech Connect (OSTI)

    Muscio, G.P.A.; Horsfield, B.; Welte, D.

    1995-08-01

    The lack of direct and unequivocal evidence for the existence of fractures in the Bakken petroleum system (Williston Basin, U.S.A./Canada) has led to controversial discussions with respect to the magnitude, orientation and frequency of fractures and especially their formation mechanism. Amongst other hypotheses, the creation of overpressuring as a result of high petroleum generation rates was called upon to induce fracturing. On the basis of a comprehensive organic geochemical study incorporating source rock and reservoir data, the present contribution provides evidence for an alternative pressure-controlled fracture formation mechanism: Mass balance calculations performed on Bakken Shale samples covering a maturity spectrum from 0.3% to 1.1% R{sub o} has revealed that the main phase of petroleum formation took place very early during catagenesis (ca. 0.4 - 0.8% R{sub o}) and that its potential has already been realized in those areas of the basin which currently produce from Bakken reservoirs. (1) It has been shown recently that the Bakken petroleum system represents a closed system, i.e. the Bakken sourced oils have not entered the Madison reservoirs. Hence, overall high expulsion efficiencies indicate that Bakken Shale over- and underlying units might represent the principal reservoirs and, most importantly, the strata where overpressuring should be expected. (2) Detailed analysis of Bakken sourced oils which are produced from Bakken reservoirs imply that their bulk and molecular composition may have been altered by significant in-situ thermal alteration which took place after the main phase of expulsion. (3) The hypothesized process of reimpregnation of petroleum from the reservoir back into the source rock system may account for locally occurring high concentrations of solvent extractable organic matter in Bakken Shales.

  5. Geomechanical Study of Bakken Formation for Improved Oil Recovery

    SciTech Connect (OSTI)

    Ling, Kegang; Zeng, Zhengwen; He, Jun; Pei, Peng; Zhou, Xuejun; Liu, Hong; Huang, Luke; Ostadhassan, Mehdi; Jabbari, Hadi; Blanksma, Derrick; Feilen, Harry; Ahmed, Salowah; Benson, Steve; Mann, Michael; LeFever, Richard; Gosnold, Will

    2013-12-31

    On October 1, 2008 US DOE-sponsored research project entitled “Geomechanical Study of Bakken Formation for Improved Oil Recovery” under agreement DE-FC26-08NT0005643 officially started at The University of North Dakota (UND). This is the final report of the project; it covers the work performed during the project period of October 1, 2008 to December 31, 2013. The objectives of this project are to outline the methodology proposed to determine the in-situ stress field and geomechanical properties of the Bakken Formation in Williston Basin, North Dakota, USA to increase the success rate of horizontal drilling and hydraulic fracturing so as to improve the recovery factor of this unconventional crude oil resource from the current 3% to a higher level. The success of horizontal drilling and hydraulic fracturing depends on knowing local in-situ stress and geomechanical properties of the rocks. We propose a proactive approach to determine the in-situ stress and related geomechanical properties of the Bakken Formation in representative areas through integrated analysis of field and well data, core sample and lab experiments. Geomechanical properties are measured by AutoLab 1500 geomechanics testing system. By integrating lab testing, core observation, numerical simulation, well log and seismic image, drilling, completion, stimulation, and production data, in-situ stresses of Bakken formation are generated. These in-situ stress maps can be used as a guideline for future horizontal drilling and multi-stage fracturing design to improve the recovery of Bakken unconventional oil.

  6. Horizontal drilling the Bakken Formation, Williston basin: A new approach

    SciTech Connect (OSTI)

    Lefever, J.A. )

    1990-05-01

    Horizontal drilling is an attractive new approach to exploration and development of the Mississippian/Devonian Bakken Formation in the southwestern part of North Dakota. This drilling technique increases the probability of success, the profit potential, the effective drainage area maximizing recoverable reserves, and the productivity by encountering more natural occurring fractures. The target formation, the Mississippian/Devonian Bakken, consists of three members in an overlapping relationship, a lower organic-rich black shale, a middle siltstone/limestone, and an upper organic-rich black shale. It attains a maximum thickness of 145 ft and thins to a feather edge along its depositional limit. Considered to be a major source rock for the Williston basin, the Bakken is usually overpressured where productive. Overpressuring is attributed to intense hydrocarbon generation. Reservoir properties are poor with core fluid porosities being generally 5% or less and permeabilities ranging from 0.1 to 0.2 md. The presence of natural fractures in the shale are necessary for production. Two types of fractures are associated with Bakken reservoirs: large vertical fractures (of tectonic origin) and microfractures (probably related to hydrocarbon generation). An economic comparison between horizontal and vertical wells show that well completion costs are approximately two times higher (average costs; $1,500,000 for a horizontal to $850,000 for a vertical) with average payout for horizontal wells projected to occur in half the time (1.5 yr instead of 3.4 yr). Projected production and reserves are considered to be 2 to 4 times greater from a horizontal well.

  7. Conodonts of Bakken Formation (Devonian and Mississippian), Williston basin, North Dakota

    SciTech Connect (OSTI)

    Hayes, M.D.; Holland, F.D. Jr.

    1983-08-01

    The Bakken Formation is a thin (maximum 145 ft, 45 m), clastic unit in the subsurface of Williston basin in the United States and Canada. The Bakken is similar in lithologic character and stratigraphic position to other black shale units deposited on the North American craton during the Late Devonian and Early Mississippian. The Bakken was initially considered entirely Mississippian in age. Paleontologic study of regional physical equivalents and analysis of the macrofauna in Saskatchewan has suggested that the Bakken is actually both Devonian and Mississippian. Conodonts were obtained from cores of the Bakken in an effort to determine the age of the formation in North Dakota and to assess the oil generation potential. Nearly 700 conodonts have been recovered, but are unevenly distributed within the Bakken Formation. A majority was obtained from thin (approximately 0.5 cm), fossil-rich beds within the upper shale. Conodonts from the top of the upper shale reveal a Mississippian (Kinderhookian) age and are here assigned to the Lower Siphonodella crenulata Zone. Only rare, fragmentary conodonts have been found in the middle member. Conodont evidence from the middle of the lower shale suggests a late Devonian (Famennian) age (Upper Polygnathus styriacus Zone) for this member. Conodont color has been established as a geothermometer in carbonate rocks. Color alteration indices of conodonts from the Bakken range from 1.5 to approximately 2.5 and indicate a pattern of increasing temperature with depth. These results suggest possible hydrocarbon generation from shallower depths than has been reported previously for the Bakken. The lack of agreement in interpreted hydrocarbon generation depths may be due to, among other things, the clastic nature of the Bakken Formation.

  8. Horizontal drilling in the Bakken Formation - The hunt for an elephant that never left the source system

    SciTech Connect (OSTI)

    Price, L. ); Le Fever, J. )

    1991-06-01

    New organic-geochemical studies show that bitumen extracted from the upper and lower shale members of the Mississippian Madison Group oils, and that the Bakken shales have contributed only a minor percentage of the conventionally produced oil in the Williston basin. Instead, organic-rich madison marls are an adequate source for the Madison oils. Also, few pathways exist for vertical migration of Bakken-generated oil to shallower Madison reservoirs. Vertical wells in older Bakken oil pools are perforated in one or all of the three units adjacent to the two Bakken shales but are not necessarily perforated in the Bakken shales. Rock-Eval analyses of 6- to 12-in. spaced core samples show that where Bakken shales are thermally mature, the three adjacent organic-poor units contain 10-20 times the hydrocarbons (HCs) they could have generated. Thus, Bakken-generated HCs appear to have moved into the three adjacent units, probably via fractures created by volume expansion of organic matter during HC generation in the Bakken shales. Bakken well histories reveal that unsuccessful Bakken wells appear due to questionable techniques during these operations and not a lack of fractures. If a large in-place resource base exists in the Bakken source system, its commercial recovery will depend on new exploration, drilling, completion, and production technologies and on how much of the generated oil is in fractures rather than dispersed throughout the rocks.

  9. A comparison of the rates of hydrocarbon generation from Lodgepole, False Bakken, and Bakken formation petroleum source rocks, Williston Basin, USA

    SciTech Connect (OSTI)

    Jarvie, D.M.; Elsinger, R.J.; Inden, R.F.; Palacas, J.G.

    1996-06-01

    Recent successes in the Lodgepole Waulsortian Mound play have resulted in the reevaluation of the Williston Basin petroleum systems. It has been postulated that hydrocarbons were generated from organic-rich Bakken Formation source rocks in the Williston Basin. However, Canadian geoscientists have indicated that the Lodgepole Formation is responsible for oil entrapped in Lodgepole Formation and other Madison traps in portions of the Canadian Williston Basin. Furthermore, geoscientists in the U.S. have recently shown oils from mid-Madison conventional reservoirs in the U.S. Williston Basin were not derived from Bakken Formation source rocks. Kinetic data showing the rate of hydrocarbon formation from petroleum source rocks were measured on source rocks from the Lodgepole, False Bakken, and Bakken Formations. These results show a wide range of values in the rate of hydrocarbon generation. Oil prone facies within the Lodgepole Formation tend to generate hydrocarbons earlier than the oil prone facies in the Bakken Formation and mixed oil/gas prone and gas prone facies in the Lodgepole Formation. A comparison of these source rocks using a geological model of hydrocarbon generation reveals differences in the timing of generation and the required level of maturity to generate significant amounts of hydrocarbons.

  10. Thermal modeling of Bakken Formation of Williston basin

    SciTech Connect (OSTI)

    Anderson, D.

    1986-08-01

    Organic geochemical analyses provide a quantitative basis on which conceptual models of thermal maturation may be built. Contour maps of maturation indices of the Mississippian-Devonian Bakken Formation of the Williston basin show anomalous patterns that are not dependent on burial depth. One such area is on the western side of the Nesson anticline. One-dimensional modeling incorporating a uniform, constant heat flow, lithology-dependent thermal conductivities, and decompaction factors indicates that these areas are less mature than surrounding regions. This is due primarily to decreasing burial depth and thinning of low-thermal-conductivity Tertiary and Cretaceous shales. Additional heat transfer to these regions may be due in part to heat transfer by fluid movement through aquifers or vertical fractures. The influence of these fluid systems is simulated through the use of a two-dimensional finite difference program. Basic assumptions are made concerning heat flow, thermal properties, and ground-water flow rates through time. Modeling of the time-temperature history is simplified by restricting the study to the time of greatest maturation, the post-Jurassic.

  11. Petroleum source rocks and stratigraphy of Bakken formation in North Dakota

    SciTech Connect (OSTI)

    Webster, R.L.

    1984-07-01

    The Bakken Formation (Devonian and Mississippian) of North Dakota consists of upper and lower, black, organic-rich shales separated by a calcareous siltstone middle member. Organic-carbon measurements revealed the Bakken shales to be very organic-rich (average of 11.33 wt.% of organic carbon), and visual kerogen typing revealed this organic matter to be predominantly an amorphous type that is inferred to be sapropelic. The onset of hydrocarbon generation was determined to occur at an average depth of 9000 ft (2.74 km) by interpreting plots of geochemical parameters with depth (e.g., ratios of hydrocarbon to nonhydrocarbon, saturated hydrocarbon to organic carbon, pyrolytic hydrocarbon to organic carbon, and the pyrolysis production index). Hydrocarbon content and thermal kerogen breakdown increase greatly in the Bakken shales where they are buried at depths greater than 9000 ft (2.74 km). The effective source area of the Bakken, as determined by maps of the above geochemical parameters, lies mostly in McKenzie, Williams, Dunn, and Billings Counties. Oil generation was probably initiated in the Bakken about 75 Ma (Late Cretaceous) at a temperature of about 100/sup 0/C (212/sup 0/F), with initial expulsion of oil from the Bakken probably occurring 70 Ma (Late Cretaceous). The amount of oil generated by the Bakken in North Dakota, as calculated from pyrolysis data, is 92.3 billion bbl. If only 10% of this oil was actually expelled from the shales, it could easily account for the 3 billion bbl of known type II oil reserves in the Williston basin.

  12. A resource evaluation of the Bakken Formation (Upper Devonian and Lower Mississippian) continuous oil accumulation, Williston Basin, North Dakota and Montana

    SciTech Connect (OSTI)

    Schmoker, J.W.

    1996-01-01

    The Upper Devonian and Lower Mississippian Bakken Formation in the United States portion of the Williston Basin is both the source and the reservoir for a continuous oil accumulation -- in effect a single very large field -- underlying approximately 17,800 mi{sup 2} (46,100 km{sup 2}) of North Dakota and Montana. Within this area, the Bakken Formation continuous oil accumulation is not significantly influenced by the water column and cannot be analyzed in terms of conventional, discrete fields. Rather, the continuous accumulation can be envisioned as a collection of oil-charged cells, virtually all of which are capable of producing some oil, but which vary significantly in their production characteristics. Better well-performance statistics are linked regionally to higher levels of thermal maturity and to lower levels of reservoir heterogeneity. Although portions of the Bakken Formation continuous oil accumulation have reached a mature stage of development, the accumulation as a whole is far from depleted.

  13. Organic carbon in Bakken Formation, United States portion of Williston Basin

    SciTech Connect (OSTI)

    Schmoker, J.W.; Hester, T.C.

    1983-12-01

    The upper and lower members of the Mississippian and Devonian Bakken Formation in the United States portion of the Williston basin are black shales that are extremely rich in organic matter and are the source of much of the oil found in the basin. Organic-carbon values are calculated from formationdensity logs using the equation: TOC = (154.497//rho/) -57.261, where TOC is organic-carbon content (wt. %) and /rho/ is formation density (g/cm/sup 3/). Test calculations comparing this equation to laboratory organic-carbon analyses from 39 wells in North Dakota show an average absolute difference of 1.1% in organic-carbon content. Organic-carbon content, calculated at 159 locations in North Dakota and 107 in Montana, averages 12.1% for the upper member of the Bakken Formation and 11.5% for the lower member. There is a regional depletion of organic carbon, paralleling present-day isotherms, that reflects the conversion of organic matter to oil and subsequent expulsion of the oil from the formation. The mass of organic carbon in the Bakken Formation is approximately evenly divided between the upper and lower members, and it totals about 126 X 10/sup 12/ kg in the study area, of which 102 X 10/sup 12/ kg are in the thermally mature region. The assumption that 167 mg HC/g TOC have migrated out of the mature Bakken shales leads to a tentative estimate that hydrocarbons equivalent to 132 billion bbl of 43/sup 0/ (API gravity) oil have been expelled from the United States portion of the upper and lower members of the Bakken Formation.

  14. Macrofossils of Bakken Formation (Devonian and Mississippian), Williston Basin, North Dakota

    SciTech Connect (OSTI)

    Thrasher, L.; Holland, F.D. Jr.

    1983-08-01

    Results of this study of the macrofossils of the Bakken Formation in North Dakota have reinforced the suggestion, based on previous paleontological work in Saskatchewan, that the Bakken is of both Devonian and Mississippian age, rather than being entirely of Lower Mississippian age as originally considered. Increased drilling and coring activity in the North Dakota part of the Williston Basin has provided the opportunity for acquiring a larger fauna that was previously available. Based on lithologic character, the Bakken has been divided into three informal members. These consist of a calcareous siltstone unit between two lithologically similar units of carbonaceous shale. These black shales contain similar faunas distinct from that of the middle member. The black shales contain inarticulate brachiopods, conchostracans, and rare cephalopods and fish remains as well as more abundant conodonts, ostracods, and palynomorphs. The middle siltstone unit contains a more abundant and diverse fauna consisting of inarticulate and articulate brachiopods together with corals, gastropods, cephalopods, ostracods, echinoderm remains, and trace fossils. This is the first report of cephalopods, conchostracans, ostracods, corals, trace fossils, and some of the brachiopods in the Bakken, although all, except the gastropods, have been reported from stratigraphic equivalents (Exshaw Formation of south-central Montana, the Leatham Formation of northeastern Utah, and the middle member of the Pilot Shale in western Utah and eastern Nevada).

  15. Developing an oil generation model for resource assessment of Bakken formation, Williston Basin

    SciTech Connect (OSTI)

    Charpentier, R.R.; Krystinik, K.B.

    1984-04-01

    A model was developed for oil generation in the Devonian and Mississippian Bakken Formation, which has been proposed as the main hydrocarbon source rock within the Williston basin. The data consisted of formation temperatures and of density, neutron-porosity, resistivity, and gamma-ray logs from more than 250 wells in North Dakota and Montana. The upper and the lower shale members of the Bakken Formation were studied. Regression analysis, analysis of residuals, and cluster, discriminant, and factor analyses were used in an attempt to separate depositional effects--especially variations in organic content-from maturity. Regression and analysis of residuals indicate differences both areally and between the upper and lower members. In the upper member, and less strongly in the lower member, the center of the basin differs from the basin margins in that it has extreme residuals--either high or low. Clustering and residual analyses show roughly the same areal patterns. Inverse relationships, similar to those suggested by other workers, were found between formation temperature and organic content and between density logs and organic content. Also found, though, was that the addition of other factors, such as neutron porosity, helps to indicate organic content. Preliminary results show that it may be possible to model oil generation by using statistical techniques on well-log data. In particular, the model has the potential to refine estimates of the amount of hydrocarbons generated by the Bakken Formation in the Williston basin.

  16. SUBTASK 1.7 EVALUATION OF KEY FACTORS AFFECTING SUCCESSFUL OIL PRODUCTION IN THE BAKKEN FORMATION, NORTH DAKOTA PHASE II

    SciTech Connect (OSTI)

    Darren D. Schmidt; Steven A. Smith; James A. Sorensen; Damion J. Knudsen; John A. Harju; Edward N. Steadman

    2011-10-31

    Production from the Bakken and Three Forks Formations continues to trend upward as forecasts predict significant production of oil from unconventional resources nationwide. As the U.S. Geological Survey reevaluates the 3.65 billion bbl technically recoverable estimate of 2008, technological advancements continue to unlock greater unconventional oil resources, and new discoveries continue within North Dakota. It is expected that the play will continue to expand to the southwest, newly develop in the northeastern and northwestern corners of the basin in North Dakota, and fully develop in between. Although not all wells are economical, the economic success rate has been near 75% with more than 90% of wells finding oil. Currently, only about 15% of the play has been drilled, and recovery rates are less than 5%, providing a significant future of wells to be drilled and untouched hydrocarbons to be pursued through improved stimulation practices or enhanced oil recovery. This study provides the technical characterizations that are necessary to improve knowledge, provide characterization, validate generalizations, and provide insight relative to hydrocarbon recovery in the Bakken and Three Forks Formations. Oil-saturated rock charged from the Bakken shales and prospective Three Forks can be produced given appropriate stimulation treatments. Highly concentrated fracture stimulations with ceramic- and sand-based proppants appear to be providing the best success for areas outside the Parshall and Sanish Fields. Targeting of specific lithologies can influence production from both natural and induced fracture conductivity. Porosity and permeability are low, but various lithofacies units within the formation are highly saturated and, when targeted with appropriate technology, release highly economical quantities of hydrocarbons.

  17. Fracture-enhanced porosity and permeability trends in Bakken Formation, Williston basin, western North Dakota

    SciTech Connect (OSTI)

    Freisatz, W.B.

    1988-07-01

    Fractures play a critical role in oil production from the Bakken Formation (Devonian and Mississippian) in the North Dakota portion of the Williston basin. The Bakken Formation in the study area is known for its low matrix porosity and permeability, high organic content, thermal maturity, and relative lateral homogeneity. Core analysis has shown the effective porosity and permeability development within the Bakken Formation to be related primarily to fracturing. In theory, lineaments mapped on the surface reflect the geometry of basement blocks and the zones of fracturing propagated upward from them. Fracturing in the Williston basin is thought to have occurred along reactivated basement-block boundaries in response to varying tectonic stresses and crustal flexure throughout the Phanerozoic. Landsat-derived lineament maps were examined for the area between 47/degrees/ and 48/degrees/ north lat. and 103/degrees/ and 104/degrees/ west long. (northern Billings and Golden Valley Counties, and western McKenzie County, North Dakota) in an attempt to identify large-scale fracture trends. In the absence of major tectonic deformation in the craton, a subtle pattern of fracturing has propagated upward through the sedimentary cover and emerged as linear topographic features visible on these large-scale, remote-sensed images.

  18. Recognition of hydrocarbon expulsion using well logs: Bakken Formation, Williston Basin

    SciTech Connect (OSTI)

    Cunningham, R.; Zelt, F.B.; Morgan, S.R.; Passey, Q.R. ); Snavely, P.D. III; Webster, R.L. )

    1990-05-01

    The Upper Mississippian-Lower Devonian Bakken Formation forms a source/carrier/reservoir system in the Williston basin. Hydrocarbon expulsion within the Bakken has been identified by overlaying sonic and resistivity logs. Typically, these curves track in organically lean, water-saturated mudrocks because both respond mainly to porosity; however, in thermally mature organic-rich rocks and hydrocarbon reservoirs or carrier beds, the curves separate due to the anomalously high resistivity associated with replacement of pore water by hydrocarbons. Sonic/resistivity-log overlays for wells throughout the Montana and North Dakota parts of the Williston basin reveal significant increases and maximum in-curve separation within the middle siltstone member of the Bakken at subsurface temperatures of about 170 and 200{degree}F, respectively. Sequence-stratigraphic characteristics of the Bakken define the framework within which the expulsion process operates. The organic-rich upper and lower shale members represent the transgressive and early highstand systems tracts of two adjacent depositional sequences. A sequence boundary within the intervening middle siltstone member separates nearshore siltstone and sandstone of the late highstand systems tract in the lower sequence from cross-bedded subtidal to intertidal sandstones of the lowstand systems tract in the upper sequence. Reservoir properties vary across this sequence boundary. The authors attribute the log separation in the siltstone member to hydrocarbons expelled from the adjacent shales. Abrupt shifts in several geochemical properties of the shale members, indicative of hydrocarbon generation occur over the same subsurface temperature range as the rapid increase in log separation in the middle siltstone, thus indicating the contemporaneity of generation and expulsion.

  19. Subtask 1.8 - Investigation of Improved Conductivity and Proppant Applications in the Bakken Formation

    SciTech Connect (OSTI)

    Bethany Kurz; Darren Schmidt; Steven Smith Christopher Beddoe; Corey Lindeman; Blaise Mibeck

    2012-07-31

    Given the importance of hydraulic fracturing and proppant performance for development of the Bakken and Three Forks Formations within the Williston Basin, a study was conducted to evaluate the key factors that may result in conductivity loss within the reservoirs. Various proppants and reservoir rock cores were exposed to several different fracturing and formation fluids at reservoir conditions. The hardness of the rock cores and the strength of the proppants were evaluated prior to and following fluid exposure. In addition, the conductivity of various proppants, as well as formation embedment and spalling, was evaluated at reservoir temperatures and pressures using actual reservoir rock cores. The results of this work suggest that certain fluids may affect both rock and proppant strength, and therefore, fluid exposure needs to be considered in the field. In addition, conductivity decreases within the Bakken Formation appear to be a function of a variety of factors, including proppant and rock strength, as well as formation embedment and spalling. The results of this study highlight the need for advanced conductivity testing, coupled with quantification of formation embedment and spalling. Given the importance of proppant performance on conductivity loss and, ultimately, oil recovery, better understanding the effects of these various factors on proppant and rock strength in the field is vital for more efficient production within unconventional oil and gas reservoirs.

  20. Experience reveals better Bakken stimulation techniques

    SciTech Connect (OSTI)

    Cramer, D.D. )

    1991-04-29

    In the Bakken formation, stimulation treatments are used sparingly in horizontal well completions. but in vertical wells, stimulation is used extensively and successfully. This article shows the stimulation designs that are effective in the Bakken formation.

  1. Statistical model for source rock maturity and organic richness using well-log data, Bakken Formation, Williston basin, United States

    SciTech Connect (OSTI)

    Krystinik, K.B.; Charpentier, R.R.

    1987-01-01

    A study of the Bakken Formation, the proposed source rock for much of the hydrocarbons generated in the Williston basin, was done using bulk density, neutron porosity, and resistivity logs, and formation temperatures. Principal components, cluster, and discriminant analyses indicate that the present-day distribution of organic matter controls much of the variability in the log values. Present-day total organic carbon values are high in the central part of the basin near northeastern Montana and along the east edge of the basin, and low in the area of the Nesson anticline and along the southwest edge of the basin. Using a regression of density on temperature and the analysis of residuals from this regression, hydrocarbon maturity effects were partially separated from depositional effects. These analyses suggest that original concentrations of organic matter were low near the limits of the Bakken and increased to a high in northeastern Montana. The pre-maturation distribution of total organic carbon and the present-day total organic carbon distribution, as determined by statistical analyses of well-log data, agree with the results of geochemical analyses. The distributions can be explained by a relatively simple depositional pattern and thermal history for the Bakken. 6 figures, 3 tables.

  2. 05643_GeoMech_Bakken | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bakken Formation for Improved Oil Recovery Last Reviewed 6242014 DE-08NT0005643 Goal The goal of this project is to determine the geomechanical properties of the Bakken Formation ...

  3. A chemical kinetic model of hydrocarbon generation from the Bakken Formation, Williston Basin, North Dakota

    SciTech Connect (OSTI)

    Sweeney, J.J.; Braun, R.L.; Burnham, A.K. ); Gosnold, W.D. )

    1992-10-01

    This report describes a model of hydrocarbon generation and expulsion in the North Dakota portion of the Williston Basin. The modeling incorporates kinetic methods to simulate chemical reactions and 1-dimensional conductive heat flow models to simulate thermal histories of the Mississippian-Devonian Bakken Formation source rock. We developed thermal histories of the source rock for 53 wells in the basin using stratigraphic and heat flow data obtained by the University of North Dakota. Chemical kinetics for hydrocarbon generation, determined from Pyromat pyrolysis, were, then used with the diennal histories to calculate the present day value of the Rock-Eval T[sub max] for each well. The calculated Rock-Eval T[sub max] values agreed with measured values within amounts attributable to uncertainties in the chemical kinetics and the heat flow. These optimized thermal histories were then used with a more detailed chemical kinetic model of hydrocarbon generation and expulsion, modified from a model developed for the Cretaceous La Luna shale, to simulate pore pressure development and detailed aspects of the hydrocarbon chemistry. When compared to values estimated from sonic logs, the pore pressure calculation underestimates the role of hydrocarbon generation and overestimates the role of compaction disequilibrium, but it matches well the general areal extent of pore pressures of 0.7 times lithostatic and higher. The simulated chemistry agrees very well with measured values of HI, PI, H/C atomic ratio of the kerogen, and Rock-Eval S1. The model is not as successful in simulating the amount of extracted bitumen and its saturate content, suggesting that detailed hydrous pyrolysis experiments will probably be needed to further refine the chemical model.

  4. A chemical kinetic model of hydrocarbon generation from the Bakken Formation, Williston Basin, North Dakota

    SciTech Connect (OSTI)

    Sweeney, J.J.; Braun, R.L.; Burnham, A.K.; Gosnold, W.D.

    1992-10-01

    This report describes a model of hydrocarbon generation and expulsion in the North Dakota portion of the Williston Basin. The modeling incorporates kinetic methods to simulate chemical reactions and 1-dimensional conductive heat flow models to simulate thermal histories of the Mississippian-Devonian Bakken Formation source rock. We developed thermal histories of the source rock for 53 wells in the basin using stratigraphic and heat flow data obtained by the University of North Dakota. Chemical kinetics for hydrocarbon generation, determined from Pyromat pyrolysis, were, then used with the diennal histories to calculate the present day value of the Rock-Eval T{sub max} for each well. The calculated Rock-Eval T{sub max} values agreed with measured values within amounts attributable to uncertainties in the chemical kinetics and the heat flow. These optimized thermal histories were then used with a more detailed chemical kinetic model of hydrocarbon generation and expulsion, modified from a model developed for the Cretaceous La Luna shale, to simulate pore pressure development and detailed aspects of the hydrocarbon chemistry. When compared to values estimated from sonic logs, the pore pressure calculation underestimates the role of hydrocarbon generation and overestimates the role of compaction disequilibrium, but it matches well the general areal extent of pore pressures of 0.7 times lithostatic and higher. The simulated chemistry agrees very well with measured values of HI, PI, H/C atomic ratio of the kerogen, and Rock-Eval S1. The model is not as successful in simulating the amount of extracted bitumen and its saturate content, suggesting that detailed hydrous pyrolysis experiments will probably be needed to further refine the chemical model.

  5. Developing an oil generation model for resource assessment of the Bakken Formation, US portion of the Williston Basin

    SciTech Connect (OSTI)

    Krystinik, K.B.; Charpentier, R.R.

    1984-01-01

    A study of the Bakken Formation, the proposed source rock for much of the hydrocarbons generated in the Williston basin, was done using well-log data. Principal components analysis, cluster analysis, and discriminant analysis were used on bulk density, neutron porosity, and resistivity logs, and formation temperatures. These analyses indicate that the present-day distribution of organic matter controls much of the variability in the log values. The pattern of present-day total organic carbon (TOC) is high in the central part of the basin near northeastern Montana and along the east edge of the basin. Low values of TOC occur in the area of the Nesson anticline and along the southwest edge of the basin. Using the regression of density on temperature and the analysis of residuals from this regression, it is possible to separate maturity effects from those of original deposition. These analyses reveal that original concentrations of organic matter were low near the shoreline and increased offshore to a high in northeast Montana. The pre-maturation and present-day TOC distributions derived using statistical analyses and well-log data can easily be explained by the depositional pattern and thermal history that would be expected in this basin, and by geochemical analyses. 9 refs., 13 figs., 3 tabs.

  6. 05643_GeoMech_Bakken | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geomechanical Study of Bakken Formation for Improved Oil Recovery Last Reviewed 6/24/2014 DE-08NT0005643 Goal The goal of this project is to determine the geomechanical properties of the Bakken Formation in North Dakota, and use these results to increase the success rate of horizontal drilling and hydraulic fracturing in order to improve the ultimate recovery of this vast oil resource. Performer University of North Dakota, Grand Forks, ND 58202-7134 Background Compared to the success of

  7. The Bakken - An Unconventional Petroleum and Reservoir System

    SciTech Connect (OSTI)

    Sarg, J.

    2011-12-31

    An integrated geologic and geophysical study of the Bakken Petroleum System, in the Williston basin of North Dakota and Montana indicates that: (1) dolomite is needed for good reservoir performance in the Middle Bakken; (2) regional and local fractures play a significant role in enhancing permeability and well production, and it is important to recognize both because local fractures will dominate in on-structure locations; and (3) the organic-rich Bakken shale serves as both a source and reservoir rock. The Middle Bakken Member of the Bakken Formation is the target for horizontal drilling. The mineralogy across all the Middle Bakken lithofacies is very similar and is dominated by dolomite, calcite, and quartz. This Member is comprised of six lithofacies: (A) muddy lime wackestone, (B) bioturbated, argillaceous, calcareous, very fine-grained siltstone/sandstone, (C) planar to symmetrically ripple to undulose laminated, shaly, very fine-grained siltstone/sandstone, (D) contorted to massive fine-grained sandstone, to low angle, planar cross-laminated sandstone with thin discontinuous shale laminations, (E) finely inter-laminated, bioturbated, dolomitic mudstone and dolomitic siltstone/sandstone to calcitic, whole fossil, dolomitic lime wackestone, and (F) bioturbated, shaly, dolomitic siltstone. Lithofacies B, C, D, and E can all be reservoirs, if quartz and dolomite-rich (facies D) or dolomitized (facies B, C, E). Porosity averages 4-8%, permeability averages 0.001-0.01 mD or less. Dolomitic facies porosity is intercrystalline and tends to be greater than 6%. Permeability may reach values of 0.15 mD or greater. This appears to be a determinant of high productive wells in Elm Coulee, Parshall, and Sanish fields. Lithofacies G is organic-rich, pyritic brown/black mudstone and comprises the Bakken shales. These shales are siliceous, which increases brittleness and enhances fracture potential. Mechanical properties of the Bakken reveal that the shales have similar

  8. Subtask – CO2 storage and enhanced bakken recovery research program

    SciTech Connect (OSTI)

    Sorensen, James; Hawthorne, Steven; Smith, Steven; Braunberger, Jason; Liu, Guoxiang; Klenner, Robert; Botnen, Lisa; Steadman, Edward; Harju, John; Doll, Thomas

    2014-05-31

    Small improvements in productivity could increase technically recoverable oil in the Bakken Petroleum System by billions of barrels. The use of CO2 for enhanced oil recovery (EOR) in tight oil reservoirs is a relatively new concept. The large-scale injection of CO2 into the Bakken would also result in the geological storage of significant amounts of CO2. The Energy & Environmental Research Center (EERC) has conducted laboratory and modeling activities to examine the potential for CO2 storage and EOR in the Bakken. Specific activities included the characterization and subsequent modeling of North Dakota study areas as well as dynamic predictive simulations of possible CO2 injection schemes to predict the potential CO2 storage and EOR in those areas. Laboratory studies to evaluate the ability of CO2 to remove hydrocarbons from Bakken rocks and determine minimum miscibility pressures for Bakken oil samples were conducted. Data from a CO2 injection test conducted in the Elm Coulee area of Montana in 2009 were evaluated with an eye toward the possible application of knowledge gained to future injection tests in other areas. A first-order estimation of potential CO2 storage capacity in the Bakken Formation in North Dakota was also conducted. Key findings of the program are as follows. The results of the research activities suggest that CO2 may be effective in enhancing the productivity of oil from the Bakken and that the Bakken may hold the ability to geologically store between 120 Mt and 3.2 Gt of CO2. However, there are no clear-cut answers regarding the most effective approach for using CO2 to improve oil productivity or the storage capacity of the Bakken. The results underscore the notion that an unconventional resource will likely require unconventional methods of both assessment and implementation when it comes to the injection of CO

  9. Technology-Based Oil and Natural Gas Plays: Shale Shock! Could There Be Billions in the Bakken?

    Reports and Publications (EIA)

    2006-01-01

    This report presents information about the Bakken Formation of the Williston Basin: its location, production, geology, resources, proved reserves, and the technology being used for development. This is the first in a series intending to share information about technology-based oil and natural gas plays.

  10. Bakken shale typifies horizontal drilling success

    SciTech Connect (OSTI)

    Leibman, P.R. )

    1990-12-01

    Given the favorable production response that has been obtained from horizontal drilling in vertical- fractured reservoirs such as the Bakken shale and, more recently, the Austin chalk, industry interest in this technology has mushroomed in the U.S. Indeed, it is difficult to find a good-sized oil company these days that is not involved in a horizontal drilling project or is giving it serious consideration. In response to growing evidence of successful field applications, the realization is dawning on the investment community that horizontal drilling represents a significant technological development with positive implications for both the exploration and production business, and the oilfield services industry.

  11. Subtask1.10 – CO2 storage and enhanced bakken recovery research program

    SciTech Connect (OSTI)

    Sorensen, James

    2014-05-31

    Small improvements in productivity could increase technically recoverable oil in the Bakken Petroleum System by billions of barrels. The use of CO2 for enhanced oil recovery (EOR) in tight oil reservoirs is a relatively new concept. The large-scale injection of CO2 into the Bakken would also result in the geological storage of significant amounts of CO2. The Energy & Environmental Research Center (EERC) has conducted laboratory and modeling activities to examine the potential for CO2 storage and EOR in the Bakken. Specific activities included the characterization and subsequent modeling of North Dakota study areas as well as dynamic predictive simulations of possible CO2 injection schemes to predict the potential CO2 storage and EOR in those areas. Laboratory studies to evaluate the ability of CO2 to remove hydrocarbons from Bakken rocks and determine minimum miscibility pressures for Bakken oil samples were conducted. Data from a CO2 injection test conducted in the Elm Coulee area of Montana in 2009 were evaluated with an eye toward the possible application of knowledge gained to future injection tests in other areas. A first-order estimation of potential CO2 storage capacity in the Bakken Formation in North Dakota was also conducted. Key findings of the program are as follows. The results of the research activities suggest that CO2 may be effective in enhancing the productivity of oil from the Bakken and that the Bakken may hold the ability to geologically store between 120 Mt and 3.2 Gt of CO2. However, there are no clear-cut answers regarding the most effective approach for using CO2 to improve oil productivity or the storage capacity of the Bakken. The results underscore the notion that an unconventional resource will likely require unconventional methods of both assessment and implementation when it comes to the injection of CO

  12. Power systems utilizing the heat of produced formation fluid

    DOE Patents [OSTI]

    Lambirth, Gene Richard

    2011-01-11

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method includes treating a hydrocarbon containing formation. The method may include providing heat to the formation; producing heated fluid from the formation; and generating electricity from at least a portion of the heated fluid using a Kalina cycle.

  13. The Bakken-An Unconventional Petroleum and Reservoir System

    SciTech Connect (OSTI)

    Sarg, Frederick

    2012-03-01

    An integrated geologic and geophysical study of the Bakken Petroleum System, in the Williston basin of North Dakota and Montana indicates that: (1) dolomite is needed for good reservoir performance in the Middle Bakken; (2) regional and local fractures play a significant role in enhancing permeability and well production, and it is important to recognize both because local fractures will dominate in on-structure locations; and (3) the organic-rich Bakken shale serves as both a source and reservoir rock. Results from the lithofacies, mineral, and fracture analyses of this study were used to construct a dual porosity Petrel geo-model for a portion of the Elm Coulee Field. In this field, dolomitization enhances reservoir porosity and permeability. First year cumulative production helps locate areas of high well productivity and in deriving fracture swarm distribution. A fracture model was developed based on high productivity well distribution, and regional fracture distribution, and was combined with favorable matrix properties to build a dual porosity geo-model.

  14. Photogeneration of active formate decomposition catalysts to produce hydrogen from formate and water

    DOE Patents [OSTI]

    King, Jr., Allen D.; King, Robert B.; Sailers, III, Earl L.

    1983-02-08

    A process for producing hydrogen from formate and water by photogenerating an active formate decomposition catalyst from transition metal carbonyl precursor catalysts at relatively low temperatures and otherwise mild conditions is disclosed. Additionally, this process may be expanded to include the generation of formate from carbon monoxide and hydroxide such that the result is the water gas shift reaction.

  15. Systems and methods for producing hydrocarbons from tar sands formations

    DOE Patents [OSTI]

    Li, Ruijian; Karanikas, John Michael

    2009-07-21

    A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

  16. Breaking into Bakken potential on the Fort Peck reservation, northeastern Montana

    SciTech Connect (OSTI)

    Monson, L.M.; Lund, D.F. )

    1991-06-01

    Necessary ingredients for a Bakken play involve overpressuring, thermal maturity, stratigraphic thinning, hydrocarbon content, and the presence of fractures to free the oil. Bakken thickness varies on the reservation from 0 to 25 m. The Upper Shale Member is uniformly 3-4 m. Thickness is related to a northwest structural grain, especially in the northeast where fold axes are located parallel to the Opheim syncline. This strike is coincident with the general salt solution edge of the Devonian Prairie Evaporites. The Bakken is about 16 m thick along this dissolution boundary and may contain the necessary fracturing. Structural flexure near the Wolf Creek Nose, and especially off the northeast and eastern flanks of the Poplar dome, may have suitably fractured the Bakken as well. Well logs in this area have good resistivity separation in the Middle Siltstone Member of the Bakken, which may be used to detect fracturing in this low-porosity reservoir. Present depth of the Bakken varies from about 2,100 to 3,050 m. Electrical resistivities indicate, however, that much of the reservation's Bakken was subjected to sufficient depths to generate hydrocarbons. Other physical properties, based on porosity and gamma-ray logs, confirm that organic carbon content is adequate, if not exceptionally high. Regional and Laramide uplift, coupled with glacial erosion and rebound, probably explain the present elevation of the Bakken in this area. Significant overpressuring exists in the Bakken over at least half of the reservation as determined by sonic-log calculations and sparse drill-stem test pressures.

  17. Pyrolysis kinetics for the Bakken shale

    SciTech Connect (OSTI)

    Burnham, A.K.

    1992-01-01

    Pyrolysis kinetics are reported and compared for rapid open pyrolysis experiments: Py-TG-FTIR, Py-FID, and Py-MS. Where the type of information obtained overlapped, the results were very similar. The principal activation energy for total hydrocarbon generation using a parallel reaction model is 52 kcal/mol. As with most petroleum source rocks, carbon dioxide generation tends to lead oil formation while ethene and methane generation tend to lag oil generation. The midpoint of oil generation for a geological heating rate of 3 {degrees}C/m.y. is predicted to be between 130 and 140{degrees}C. 5 refs., 4 figs., 1 tab.

  18. Ron Ness will provide comments on the workforce needs of Bakken...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    needs of Bakken and North Dakota's energy industry and the tremendous growth in jobs over the past few years. He will focus on the Empower North Dakota initiatives on ...

  19. Bakken and other Devonian-Mississippian petroleum source rocks, northern Rocky Mtns.-Williston basin: Depositional and burial history and maturity estimations

    SciTech Connect (OSTI)

    Peterson, J.A.

    1996-06-01

    The three-member Devonian-Mississippian Bakken-Exshaw organic-rich shaly facies is widely distributed in the northern U.S. and southern Canadian Cordillera. Equivalent facies are also present as far south as Utah and Nevada. Paleogeographically, these rocks thin markedly or pinchout to the west approximately along the Devonian-Mississippian carbonate reef-mound belt of the Cordilleran shelf margin. Although these rocks reach maximum organic richness approximately at the Devonian-Carboniferous transition, similar but somewhat less organic-rich Bakken-like beds are also present in underlying Upper Devonian and overlying Lower Carboniferous carbonate depositional cycles. At least ten cycles are identified in the underlying Duperow and Jefferson Formations, characterized by basal organic-rich Bakken-like shale or shaly carbonate that grades upward into carbonate mound or reefal beds, overlain by evaporite or solution breccia. Cycles in the overlying Lodgepole and Mission Canyon Formations, as many as 10-12 in number, are similar except that the carbonates are composed of algal-oolith, crinoid, or mixed skeletal beds, and end-cycle evaporitic units are less prevalent in the lower cycles. These dark shaly beds are the most important source of hydrocarbon reserves in Montana and the Williston basin. Maximum net thickness of the Devonian-Mississippian organic-rich facies is in the Williston basin. However, variable thicknesses of these potential source rocks is present in parts of Montana as far west as the thrust belt. Burial history studies suggest that in some areas these rocks are probably thermally immature. However, in much of the area original burial depths are sufficient for them to reach the thermally mature stage, and therefore are of importance to further exploration efforts in the Devonian-Mississippian Madison-Duperow-Jefferson Formations.

  20. Thermal history of Bakken shale in Williston basin

    SciTech Connect (OSTI)

    Gosnold, W.D. Jr.; Lefever, R.D.; Crashell, J.J. )

    1989-12-01

    Stratigraphic and thermal conductivity data were combined to analyze the thermostratigraphy of the Williston basin. The present thermostratigraphy is characterized by geothermal gradients of the order of 60 mK/m in the Cenozoic and Mesozoic units, and 30 mK/m in the Paleozoic units. The differences in geothermal gradients are due to differences in thermal conductivities between the shale-dominated Mesozoic and Cenozoic units and the carbonate-dominated Paleozoic units. Subsidence and compaction rates were calculated for the basin and were used to determine models for time vs. depth and time vs. thermal conductivity relationships for the basin. The time/depth and time/conductivity relationships include factors accounting for thermal conductivity changes due to compaction, cementation, and temperature. The thermal history of the Bakken shale, a primary oil source rock in the Williston basin, was determined using four different models, and values for Lopatin's time-temperature index (TTI) were calculated for each model. The first model uses a geothermal gradient calculated from bottom-hole temperature data, the second uses present-day thermostratigraphy, the third uses the thermostratigraphic relationship determined in this analysis, and the fourth modifies the third by including assumed variations in continental heat flow. The thermal histories and the calculated TTI values differ markedly among the models with TTI values differing by a factor of about two between some models.

  1. Method of producing drive fluid in situ in tar sands formations

    DOE Patents [OSTI]

    Mudunuri, Ramesh Raju (Houston, TX); Jaiswal, Namit (Houston, TX); Vinegar, Harold J. (Bellaire, TX); Karanikas, John Michael (Houston, TX)

    2010-03-23

    Methods of treating a tar sands formation are described herein. Methods for treating a tar sands may include providing heat to at least part of a hydrocarbon layer in the formation from one or more heaters located in the formation. The heat may be allowed to transfer from the heaters to at least a portion of the formation such that a drive fluid is produced in situ in the formation. The drive fluid may move at least some mobilized, visbroken, and/or pyrolyzed hydrocarbons from a first portion of the formation to a second portion of the formation. At least some of the mobilized, visbroken, and/or pyrolyzed hydrocarbons may be produced from the formation.

  2. Basin Play State(s) Production Reserves Williston Bakken ND, MT, SD

    U.S. Energy Information Administration (EIA) Indexed Site

    tight oil plays: production and proved reserves, 2013-14 million barrels 2013 2013 Basin Play State(s) Production Reserves Williston Bakken ND, MT, SD 270 4,844 387 5,972 1,128 Western Gulf Eagle Ford TX 351 4,177 497 5,172 995 Permian Bone Spring, Wolfcamp NM, TX 21 335 53 722 387 Denver-Julesberg Niobrara CO, KS, NE, WY 2 17 42 512 495 Appalachian Marcellus* PA, WV 7 89 13 232 143 Fort Worth Barnett TX 9 58 9 47 -11 Sub-total 660 9,520 1,001 12,657 3,137 Other tight oil 41 523 56 708 185 U.S.

  3. Increasing Gas Hydrate Formation Temperature for Desalination of High Salinity Produced Water with Secondary Guests

    SciTech Connect (OSTI)

    Cha, Jong-Ho; Seol, Yongkoo

    2013-10-07

    We suggest a new gas hydrate-based desalination process using water-immiscible hydrate formers; cyclopentane (CP) and cyclohexane (CH) as secondary hydrate guests to alleviate temperature requirements for hydrate formation. The hydrate formation reactions were carried out in an isobaric condition of 3.1 MPa to find the upper temperature limit of CO2 hydrate formation. Simulated produced water (8.95 wt % salinity) mixed with the hydrate formers shows an increased upper temperature limit from -2 °C for simple CO2 hydrate to 16 and 7 °C for double (CO2 + CP) and (CO2 + CH) hydrates, respectively. The resulting conversion rate to double hydrate turned out to be similar to that with simple CO2 hydrate at the upper temperature limit. Hydrate formation rates (Rf) for the double hydrates with CP and CH are shown to be 22 and 16 times higher, respectively, than that of the simple CO2 hydrate at the upper temperature limit. Such mild hydrate formation temperature and fast formation kinetics indicate increased energy efficiency of the double hydrate system for the desalination process. Dissociated water from the hydrates shows greater than 90% salt removal efficiency for the hydrates with the secondary guests, which is also improved from about 70% salt removal efficiency for the simple hydrates.

  4. Method and system for producing lower alcohols. [Heteropolyatomic lead salt coated with alkali metal formate

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.; Heiberger, J.J.

    1983-09-26

    It is an object of the present invention to provide an improved catalyst for the reaction of carbon monoxide with water to produce methanol and other lower alcohols. It is a further object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol in which ethanol is also directly produced. It is another object to provide a process for the production of mixtures of methanol with ethanol and propanol from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. It is likewise an object to provide a system for the catalytic production of lower alcohols from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. In accordance with the present invention, a catalyst is provided for the reaction of carbon monoxide and water to produce lower alcohols. The catalyst includes a lead heteropolyatomic salt in mixture with a metal formate or a precursor to a metal formate.

  5. Inhibitive formation of nanocavities by introduction of Si atoms in Ge nanocrystals produced by ion implantation

    SciTech Connect (OSTI)

    Cai, R. S.; Shang, L.; Liu, X. H.; Zhang, Y. J.; Wang, Y. Q. E-mail: barba@emt.inrs.ca; Ross, G. G.; Barba, D. E-mail: barba@emt.inrs.ca

    2014-05-28

    Germanium nanocrystals (Ge-nc) were successfully synthesized by co-implantation of Si and Ge ions into a SiO{sub 2} film thermally grown on (100) Si substrate and fused silica (pure SiO{sub 2}), respectively, followed by subsequent annealing at 1150 °C for 1 h. Transmission electron microscopy (TEM) examinations show that nanocavities only exist in the fused silica sample but not in the SiO{sub 2} film on a Si substrate. From the analysis of the high-resolution TEM images and electron energy-loss spectroscopy spectra, it is revealed that the absence of nanocavities in the SiO{sub 2} film/Si substrate is attributed to the presence of Si atoms inside the formed Ge-nc. Because the energy of Si-Ge bonds (301 kJ·mol{sup −1}) are greater than that of Ge-Ge bonds (264 kJ·mol{sup −1}), the introduction of the Si-Ge bonds inside the Ge-nc can inhibit the diffusion of Ge from the Ge-nc during the annealing process. However, for the fused silica sample, no crystalline Si-Ge bonds are detected within the Ge-nc, where strong Ge outdiffusion effects produce a great number of nanocavities. Our results can shed light on the formation mechanism of nanocavities and provide a good way to avoid nanocavities during the process of ion implantation.

  6. Electricity Generation from Geothermal Resources on the Fort...

    Broader source: Energy.gov (indexed) [DOE]

    - hottest water - is intercepted when drilling through to Bakken Dirt and Rock Madison Formation (water) Bakken Formation (oil) DATA ANALYSIS *760 bottom hole temperatures ...

  7. 43291-1-8-eerc | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Proppant Applications in the Bakken Formation Last Reviewed 9172012 ... involving the use of proppants in the Bakken Formation, and thereby assist in ...

  8. The structure of C2b, a fragment of complement component C2 produced during C3 convertase formation

    SciTech Connect (OSTI)

    Krishnan, Vengadesan; Xu, Yuanyuan; Macon, Kevin; Volanakis, John E.; Narayana, Sthanam V. L.

    2009-03-01

    The crystal structure of C2b has been determined at 1.8 Å resolution, which reveals the arrangement of its three complement control protein (CCP) modules. A model for complement component C2 is presented and its conformational changes during the C3-convertase formation are also discussed. The second component of complement (C2) is a multi-domain serine protease that provides catalytic activity for the C3 and C5 convertases of the classical and lectin pathways of human complement. The formation of these convertases requires the Mg{sup 2+}-dependent binding of C2 to C4b and the subsequent cleavage of C2 by C1s or MASP2, respectively. The crystal structure of full-length C2 is not yet available, although the structure of its C-terminal catalytic segment C2a has been determined. The crystal structure of the N-terminal segment C2b of C2 determined to 1.8 Å resolution presented here reveals the arrangement of its three CCP domains. The domains are arranged differently compared with most other CCP-domain assemblies, but their arrangement is similar to that found in the Ba part of the full-length factor B structure. The crystal structures of C2a, C2b and full-length factor B are used to generate a model for C2 and a discussion of the domain association and possible interactions with C4b during formation of the C4b–C2 complex is presented. The results of this study also suggest that upon cleavage by C1s, C2a domains undergo conformational rotation while bound to C4b and the released C2b domains may remain folded together similar to as observed in the intact protein.

  9. Potential formation in a collisionless plasma produced in an open magnetic field in presence of volume negative ion source

    SciTech Connect (OSTI)

    Phukan, Ananya, E-mail: ananya.phukan26@gmail.com; Goswami, K. S.; Bhuyan, P. J. [Centre of Plasma Physics, Institute for Plasma Research Sonapur, Kamrup (M), Assam 782402 (India)

    2014-08-15

    The electric potential near a wall for a multi-species plasma with volume produced negative ions in presence of axially varying magnetic field is studied following an analytical-numerical approach. A constant negative ion source is assumed throughout the plasma volume, along with finite temperature positive ions and Boltzmann electrons. The particles are assumed to be guided by an open magnetic field that has its maximum at the centre, and field strength decreasing towards the walls. The one dimensional (1D) Poisson equation is derived using an analytical approach, and then solved numerically to study the potential profiles. Effect of (a) negative ion production rate, (b) magnetic field profile, and (c) negative ion temperature on the potential profile has been investigated. A potential peak appears near the wall when the negative ion temperature and density are sufficiently high. Also, the presence of negative ions further decreases the potential in the plasma region for a finite Debye Length (?{sub D})

  10. Altering wettability to recover more oil from tight formations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brady, Patrick V.; Bryan, Charles R.; Thyne, Geoffrey; Li, Huina

    2016-06-03

    We describe here a method for chemically modifying fracturing fluids and overflushes to chemically increase oil recovery from tight formations. Oil wetting of tight formations is usually controlled by adhesion to illite, kerogen, or both; adhesion to carbonate minerals may also play a role. Oil-illite adhesion is sensitive to salinity, dissolved divalent cation content, and pH. We measure oil-rock adhesion with middle Bakken formation oil and core to verify a surface complexation model of reservoir wettability. The agreement between the model and experiments suggests that wettability trends in tight formations can be quantitatively predicted and that fracturing fluid and overflushmore » compositions can be individually tailored to increase oil recovery.« less

  11. Formation resistivity as an indicator of oil generation in black shales

    SciTech Connect (OSTI)

    Hester, T.C.; Schmoker, J.W.

    1987-08-01

    Black, organic-rich shales of Late Devonian-Early Mississippi age are present in many basins of the North American craton and, where mature, have significant economic importance as hydrocarbon source rocks. Examples drawn from the upper and lower shale members of the Bakken Formation, Williston basin, North Dakota, and the Woodford Shale, Anadarko basin, Oklahoma, demonstrate the utility of formation resistivity as a direct in-situ indicator of oil generation in black shales. With the onset of oil generation, nonconductive hydrocarbons begin to replace conductive pore water, and the resistivity of a given black-shale interval increases from low levels associated with thermal immaturity to values approaching infinity. Crossplots of a thermal-maturity index (R/sub 0/ or TTI) versus formation resistivity define two populations representing immature shales and shales that have generated oil. A resistivity of 35 ohm-m marks the boundary between immature and mature source rocks for each of the three shales studied. Thermal maturity-resistivity crossplots make possible a straightforward determination of thermal maturity at the onset of oil generation, and are sufficiently precise to detect subtle differences in source-rock properties. For example, the threshold of oil generation in the upper Bakken shale occurs at R/sub 0/ = 0.43-0.45% (TTI = 10-12). The threshold increases to R/sub 0/ = 0.48-0.51% (TTI = 20-26) in the lower Bakken shale, and to R/sub 0/ = 0.56-0.57% (TTI = 33-48) in the most resistive Woodford interval.

  12. Complex facies relationships and regional stratigraphy of the Mississippian Ste. Genevieve, Paoli, and Aux Vases Formations, Illinois basin: A major hydrocarbon-producing interval

    SciTech Connect (OSTI)

    Cole, R.D.; Nelson, W.J. )

    1993-03-01

    The Mississippian Ste. Genevieve and Paoli Limestones and sandstones of the Aux Vases Formation are lateral facies of one another. This interpretation is based on comprehensive investigations of outcrops, and selected cores, samples of well cuttings, and geophysical logs conducted over a period of four years. Both units exhibit similar sedimentological characteristics and represent open marine, shallow subtidal, and intertidal environments. The presence of low-angle cross-laminae, ripple- and plane-laminae, climbing ripples, and ooid shoals suggest most deposition occurred under low energy conditions. Lenticular, channel-like scour and fill structures that contain both fine-grained quartz sand and abraded, disarticulated fossil fragments indicate localized higher energy deposition. The authors studies indicate that siliciclastic vs. carbonate deposition was controlled strictly by available sediment, and not by regressive (siliciclastic) and transgressive (carbonate) events, as inferred by previous workers. This conclusion is based on lateral facies relationships, and the supplanting of carbonates by clastics occurring in the upper part of the Ste. Genevieve through the middle part of the Paoli. The Aux Vases is thickest, coarsest, and least mature in the northwestern part of the Illinois Basin, and pinches out to the southeast. This implies a northwesterly source for clastics, perhaps the Transcontinental Arch. After early Chesterian time, the Transcontinental Arch apparently supplied little or no sediment to any flanking basin. The Ste. Genevieve, Paoli, and Aux Vases are major oil-producing units in the Illinois Basin. New understanding of regional relationships should enhance exploratory success and improve recovery from established fields.

  13. H. R. 1476: A bill to amend the Internal Revenue Code of 1986 to clarify the application of the credit for producing fuel from a nonconventional source with respect to gas produced from a tight formation and to make such credit permanent with respect to such gas and gas produced from Devonian shale. Introduced in the House of Representatives, One Hundredth First Congress, First Session, March 16, 1989

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    The determination of whether gas is produced from geopressured brines, Devonian shales, coal seams, or a tight formation is made from section 503 of the Natural Gas Policy Act of 1978. Permanent credit is for gas produced from a tight formation or Devonian shale only and applies to gas sold after July 1, 1987. The credit allowed for any taxable year shall not exceed the sum of the regular tax reduced by the sum of other credits allowable under other subsections of the Internal Revenue Code.

  14. U.S. monthly oil production tops 8 million barrels per day for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the Bakken formation in North Dakota and Montana hit 1 million barrels per day last November. However, winter storms caused a drop in the oil output from the Bakken formation ...

  15. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Technologies Office 2015 Peer Review 8250 Bakken wells 2275 Madison wells 437 ... 3.2 GW e to produce oil from the Bakken and Three Forks fields during the next ...

  16. Methods of producing transportation fuel

    DOE Patents [OSTI]

    Nair, Vijay; Roes, Augustinus Wilhelmus Maria; Cherrillo, Ralph Anthony; Bauldreay, Joanna M.

    2011-12-27

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing transportation fuel is described herein. The method for producing transportation fuel may include providing formation fluid having a boiling range distribution between -5.degree. C. and 350.degree. C. from a subsurface in situ heat treatment process to a subsurface treatment facility. A liquid stream may be separated from the formation fluid. The separated liquid stream may be hydrotreated and then distilled to produce a distilled stream having a boiling range distribution between 150.degree. C. and 350.degree. C. The distilled liquid stream may be combined with one or more additives to produce transportation fuel.

  17. STEVE SHEPHERD Bakken Workforce Development Panel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    isolated and have experienced persistent and historical poverty and chronic unemployment. ... the reservations in western North Dakota, and work toward breaking the cycle of poverty. ...

  18. Compositions produced using an in situ heat treatment process

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria; Nair, Vijay; Munsterman, Erwin Hunh; Van Bergen, Petrus Franciscus; Van Den Berg, Franciscus Gondulfus Antonius

    2013-05-28

    Methods for treating a subsurface formation and compositions produced therefrom are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  19. Method for producing viscous hydrocarbons

    DOE Patents [OSTI]

    Poston, Robert S. (Winter Park, FL)

    1982-01-01

    A method for recovering viscous hydrocarbons and synthetic fuels from a subterranean formation by drilling a well bore through the formation and completing the well by cementing a casing means in the upper part of the pay zone. The well is completed as an open hole completion and a superheated thermal vapor stream comprised of steam and combustion gases is injected into the lower part of the pay zone. The combustion gases migrate to the top of the pay zone and form a gas cap which provides formation pressure to produce the viscous hydrocarbons and synthetic fuels.

  20. Compositions produced using an in situ heat treatment process

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria; Nair, Vijay; Munsterman, Erwin Henh; Van Bergen, Petrus Franciscus; Van Den Berg, Franciscus Gondulfus Antonius

    2009-10-20

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.

  1. STATEMENT OF CHRISTOPHER SMITH PRINCIPAL DEPUTY ASSISTANT SECRETARY...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    quality guidelines. The key questions yet to be addressed are whether the chemical makeup of the crude oils from the Bakken and other tight oil formations differs from...

  2. Final Meeting Summary Page 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... The site of the proposed test borehole is within approximately fifty miles of active wells in the Bakken oil shale formation. The characterization test for the deep borehole ...

  3. This Week In Petroleum Summary Printer-Friendly Version

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Bakken and other U.S. shale formations. Operators are combining horizontal wells and hydraulic fracturing-the same technologies used to significantly boost shale gas...

  4. Press Room - Press Releases - U.S. Energy Information Administration...

    Gasoline and Diesel Fuel Update (EIA)

    Production increases over the past several years in the Bakken, Permian Basin, and Eagle Ford formations accounted for almost all of crude oil production growth in the United ...

  5. Albany, OR * Fairbanks, AK * Morgantown, WV * Pittsburgh, PA * Houston, TX

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NETL R&D Tackles Technological Challenges of the Williston Basin's Bakken Formation Recent development of the Bakken Formation in the Williston Basin of western North Dakota and eastern Montana is a good example of persistent analysis of geologic data and adaptation of new completion technologies overcoming the challenges posed by unconventional reservoirs. However, as with most unconventional plays, as Bakken development continues, questions regarding exactly how to refine newly applied

  6. Treating tar sands formations with karsted zones

    DOE Patents [OSTI]

    Vinegar, Harold J.; Karanikas, John Michael

    2010-03-09

    Methods for treating a tar sands formation are described herein. The tar sands formation may have one or more karsted zones. Methods may include providing heat from one or more heaters to one or more karsted zones of the tar sands formation to mobilize fluids in the formation. At least some of the mobilized fluids may be produced from the formation.

  7. This Week In Petroleum Summary Printer-Friendly Version

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    crudes with growing production, such as Bakken, and global seaborne crudes that are linked to the price of Brent have encouraged refiners to bring more domestically produced...

  8. Understanding the reservoir important to successful stimulation

    SciTech Connect (OSTI)

    Cramer, D.D. )

    1991-04-22

    In anisotropic Bakken shale reservoirs, fracture treatments serve to extend the well bore radius past a disturbed zone and vertically connect discrete intervals. Natural fractures in the near-well bore area strongly control the well deliverability rate. The Bakken is one of the few shale formations in the world with commercial oil production. This article covers the Bakken reservoir properties that influence production and stimulation treatments. The concluding part will discuss the design and effectiveness of the treatments.

  9. Development of a New Stratigraphic Trap Exploration Using Elastic-Wave Seismic Technology

    SciTech Connect (OSTI)

    Bryan DeVault

    2008-02-05

    Vecta acquired 9 square miles of 9-C seismic data in Mountrail County, North Dakota with the Mission Canyon shoreline as a primary target. Vecta contracted the Institute Francais du Petrole in order to co-develop a more rigorous multicomponent seismic interpretation product. The final interpretation was very unique in that it utilized not only the 9-C seismic data but also the new jointly developed software. A Mission Canyon anomaly was developed in 2006; however, it was of insufficient size to be a commercial target at the time. Therefore, Vecta analyzed the shear data for anisotropy within the Bakken formation and successfully reentered an abandoned producer within the project area and drilled a horizontal leg through the anomalous zones of the middle member of the Bakken formation. The well was open hole completed, swab tested, sand fraced, and swab tested some more. No shows of oil were ever seen from the Bakken formation, but the well yielded considerable amounts of formation water. The well has been abandoned as non-commercial. From the swab tests, one may conclude considerable permeability exists in the formation, thus confirming the utility of the shear wave to detect fractures within the targeted formation.

  10. Graphene Produces More Efficient Charge Transport Inside an Organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Graphene Produces More Efficient Charge Transport Inside an Organic Semiconductor Friday, ... devices, enabling the formation of efficient thin film and flexible devices. ...

  11. Method of producing hydrogen

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Wilding, Bruce M.; Zollinger, William T.

    2006-12-26

    A method of producing hydrogen is disclosed and which includes providing a first composition; providing a second composition; reacting the first and second compositions together to produce a chemical hydride; providing a liquid and reacting the chemical hydride with the liquid in a manner to produce a high pressure hydrogen gas and a byproduct which includes the first composition; and reusing the first composition formed as a byproduct in a subsequent chemical reaction to form additional chemical hydride.

  12. Treating tar sands formations with dolomite

    DOE Patents [OSTI]

    Vinegar, Harold J.; Karanikas, John Michael

    2010-06-08

    Methods for treating a tar sands formation are described herein. The tar sands formation may include dolomite and hydrocarbons. Methods may include providing heat at less than the decomposition temperature of dolomite from one or more heaters to at least a portion of the formation. At least some of the hydrocarbon fluids are mobilized in the formation. At least some of the hydrocarbon fluids may be produced from the formation.

  13. Coal markets squeeze producers

    SciTech Connect (OSTI)

    Ryan, M.

    2005-12-01

    Supply/demand fundamentals seem poised to keep prices of competing fossil fuels high, which could cushion coal prices, but increased mining and transportation costs may squeeze producer profits. Are markets ready for more volatility?

  14. Supporting Data-Producing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supporting Data-Producing Facilities and Instruments Co-Chairs: David Skinner & Stuart Campbell 1 Contributors * Kaki Kelly, LANL * David Smith, LLNL * Jeff Cunningham, LBNL * Yao Zhang, ANL * John Harney, ORNL * Stuart Campbell, ORNL * Ilana Stern, NCAR * David Skinner, NERSC * Craig Ulmer, Sandia * Dino Pavlakos, Sandia * Rudy Garcia, Sandia * Jack Deslippe, NERSC 2 Some Questions ? * How does a Data-Producing Facility or Instrument plug in to HPC facilities ? * Do we support facilities

  15. Particulate Formation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formation - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy

  16. Formation testers

    SciTech Connect (OSTI)

    Brieger, E.

    1980-07-01

    A description is given of a method for use in obtaining multiple pressure tests of an earth formation traversed by a well bore by use of a sidewall fluid sampler well tool which has a fluid pressure sampling chamber in the well tool in open fluid communication with a pad sealing means, comprising the steps of: for one selected level in a well bore, moving a pad sealing means on the well tool into engagement with the wall of a well bore and isolating a wall segment of the earth formation; after the pad sealing means engges the wall segment of the earth formation, generating a hydraulic pressure in the well tool and applying said hydraulic pressure to said fluid pressure sampling chamber for increasing the volume of said fluid pressure sampling chamber thereby to dray a fluid sample from the earth formation engaged by the pad sealing means into the fluid pressure sampling chamber, sensing the pressure of said fluid sample as it is drawn into the fluid pressure sampling chamber while the volume of the sampling chamber is being increased, relieving the hydraulic pressure in the well tool with respect to said fluid pressur sampling chamber for decreasing the volume of said fluid pressure sampling chamber thereby to contact the sampling chamber to dischrge the fluid sample through the pad sealing means; retracting the sealing pad means and, after retrction of sealing pad means from engagement from the wall of the well bore, moving the well tool to a second location at another level in the well bore and, at the second location, repeating the steps of the method performed at the one selected level for obtaining another fluid sample and pressure sensing at said second location.

  17. Formation testers

    SciTech Connect (OSTI)

    Brieger, E.F.

    1981-09-08

    A formation tester apparatus is disclosed for use in a well bore for multiple testing of pressures of earth formation fluids and the taking of a fluid sample. Pad and shoe means are selectively operable for sealingly engaging a well bore. Upon sealing engagement of the pad with the wall of a well bore, a fluid sample is ingested into an expanding chamber while its pressure is sensed. Upon completion of the pressure test, the pad is retracted from the wall of a well bore, and the expanding chamber contracts to expel the fluid sample. The pressure test may be repeated any number of times. The expanding chamber includes a piston operated with fluid pressure used to actuate the pad. A choke delays the application of pressure to the piston until after the pad seals on the wall of the well bore. When a fluid sample is desired, the fluid pressure used to actuate the pad is increased to operate a first valve which connects the pad of a water cushion sampling chamber. After a fluid sample is collected, the fluid pressure is further increased to operate a second valve which closes off the sampling chamber. When the formations are unconsolidated a slidable probe in the pad extends outwardly into the wall and forms a mechanical filter. When the probe retracts the filter is self-cleaning.

  18. METHOD OF PRODUCING NEUTRONS

    DOE Patents [OSTI]

    Imhoff, D.H.; Harker, W.H.

    1964-02-01

    A method for producing neutrons is described in which there is employed a confinement zone defined between longitudinally spaced localized gradient regions of an elongated magnetic field. Changed particles and neutralizing electrons, more specifically deuterons and tritons and neutralizng electrons, are injected into the confinement field from ion sources located outside the field. The rotational energy of the parrticles is increased at the gradients by imposing an oscillating transverse electrical field thereacross. The imposition of such oscillating transverse electrical fields improves the reflection capability of such gradient fielda so that the reactive particles are retained more effectively within the zone. With the attainment of appropriate densities of plasma particles and provided that such particles are at a sufficiently high temperature, neutron-producing reactions ensue and large quantities of neutrons emerge from the containment zone. (AEC)

  19. Process for producing silicon

    DOE Patents [OSTI]

    Olson, Jerry M. (Lakewood, CO); Carleton, Karen L. (Boulder, CO)

    1984-01-01

    A process for producing silicon includes forming an alloy of copper and silicon and positioning the alloy in a dried, molten salt electrolyte to form a solid anode structure therein. An electrically conductive cathode is placed in the electrolyte for plating silicon thereon. The electrolyte is then purified to remove dissolved oxides. Finally, an electrical potential is applied between the anode and cathode in an amount sufficient to form substantially pure silicon on the cathode in the form of substantially dense, coherent deposits.

  20. Method of producing imines

    DOE Patents [OSTI]

    Sithambaram, Shanthakumar; Son, Young-Chan; Suib, Steven L.

    2008-04-08

    A method for forming an imine comprises reacting a first reactant comprising a hydroxyl functionality, a carbonyl functionality, or both a hydroxyl functionality and a carbonyl functionality with a second reactant having an amine functionality in the presence of ordered porous manganese-based octahedral molecular sieves and an oxygen containing gas at a temperature and for a time sufficient for the imine to be produced.

  1. Process for producing silicon

    DOE Patents [OSTI]

    Olson, J.M.; Carleton, K.L.

    1982-06-10

    A process of producing silicon includes forming an alloy of copper and silicon and positioning the alloy in a dried, molten salt electrolyte to form a solid anode structure therein. An electrically conductive cathode is placed in the electrolyte for plating silicon thereon. The electrolyte is then purified to remove dissolved oxides. Finally, an electrical potential is applied between the anode and cathode in an amount sufficient to form substantially pure silicon on the cathode in the form of substantially dense, coherent deposits.

  2. Treating nahcolite containing formations and saline zones

    DOE Patents [OSTI]

    Vinegar, Harold J

    2013-06-11

    A method for treating a nahcolite containing subsurface formation includes removing water from a saline zone in or near the formation. The removed water is heated using a steam and electricity cogeneration facility. The heated water is provided to the nahcolite containing formation. A fluid is produced from the nahcolite containing formation. The fluid includes at least some dissolved nahcolite. At least some of the fluid is provided to the saline zone.

  3. Solid fuel volatilization to produce synthesis gas

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Dauenhauer, Paul J.; Degenstein, Nick J.; Dreyer, Brandon J.; Colby, Joshua L.

    2014-07-29

    A method comprising contacting a carbon and hydrogen-containing solid fuel and a metal-based catalyst in the presence of oxygen to produce hydrogen gas and carbon monoxide gas, wherein the contacting occurs at a temperature sufficiently high to prevent char formation in an amount capable of stopping production of the hydrogen gas and the carbon monoxide gas is provided. In one embodiment, the metal-based catalyst comprises a rhodium-cerium catalyst. Embodiments further include a system for producing syngas. The systems and methods described herein provide shorter residence time and high selectivity for hydrogen and carbon monoxide.

  4. New Models Help Optimize Development of Bakken Shale Resources...

    Energy Savers [EERE]

    Washington, DC - Exploration and field development in the largest continuous oil play in ... School of Mines (CSM), through research funded by FE's Oil and Natural Gas Program. ...

  5. Quadrennial Energy Review Public Meeting #9 Bakken Workforce...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... available over the years, our ability to deliver education and training grew. BSC began offering online programs in 1998 and was able to expand them exponentially (especially ...

  6. APPARATUS FOR PRODUCING SHADOWGRAPHS

    DOE Patents [OSTI]

    Wilson, R.R.

    1959-08-11

    An apparatus is presented for obtaining shadowgraphs or radiographs of an object exposed to x rays or the like. The device includes the combination of a cloud chamber having the interior illuminated and a portion thereof transparent to light rays and x'rays, a controlled source of x rays spaced therefrom, photographic recording disposed laterally of the linear path intermediate the source and the chamber portion in oblique angularity in aspect to the path. The object to be studied is disposed intermediate the x-ray source and chamber in the linear path to provide an x-ray transmission barrier therebetween. The shadowgraph is produced in the cloud chamber in response to initiation of the x- ray source and recorded photographically.

  7. Coal-Producing Region

    U.S. Energy Information Administration (EIA) Indexed Site

    . Coal Production by State (thousand short tons) Year to Date Coal-Producing Region and State January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change Alabama 2,446 2,298 4,022 2,446 4,022 -39.2 Alaska 310 328 265 310 265 16.7 Arizona 1,335 1,376 1,755 1,335 1,755 -23.9 Arkansas 11 18 21 11 21 -48.0 Colorado 2,482 3,258 5,263 2,482 5,263 -52.8 Illinois 11,312 11,886 16,779 11,312 16,779 -32.6 Indiana 7,224 7,264 9,463 7,224 9,463 -23.7 Kansas 27 55 53 27 53

  8. Produce diesel from gas

    SciTech Connect (OSTI)

    Singleton, A.H.; Regier, S.

    1983-05-01

    The Gulf Badger process converts natural gas directly to hydrocarbon liquids by a catalytic chemical route. Fischer-Tropsch process--which is a carbon monoxide polymerization/ hydrogenation process--is used. Because the process is exothermal, heat removal by either tubular fixed bed, fluidized bed, or slurry are considered. A wax build up of high molecular weight material is removed by hydro-stripping two-bed system. The demonstration plant flow diagram shows the process to be: natural gas is compressed, recycled with CO/sub 2/, sulfur is removed in a zinc oxide drum, CO is removed in amine scrubbers, H/sub 2//CO ratio is adjusted to produce a hydrogen rich stream, and stabilization and distribution follow. A monitoring system using computers is part of the demonstration unit.

  9. Process for thermochemically producing hydrogen

    DOE Patents [OSTI]

    Bamberger, Carlos E.; Richardson, Donald M.

    1976-01-01

    Hydrogen is produced by the reaction of water with chromium sesquioxide and strontium oxide. The hydrogen producing reaction is combined with other reactions to produce a closed chemical cycle for the thermal decomposition of water.

  10. System for treating produced water

    DOE Patents [OSTI]

    Sullivan, Enid J.; Katz, Lynn; Kinney, Kerry; Bowman, Robert S.; Kwon, Soondong

    2010-08-03

    A system and method were used to treat produced water. Field-testing demonstrated the removal of contaminants from produced water from oil and gas wells.

  11. Creating and maintaining a gas cap in tar sands formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Karanikas, John Michael (Houston, TX); Dinkoruk, Deniz Sumnu (Houston, TX); Wellington, Scott Lee (Bellaire, TX)

    2010-03-16

    Methods for treating a tar sands formation are disclosed herein. Methods for treating a tar sands formation may include providing heat to at least part of a hydrocarbon layer in the formation from one or more heaters located in the formation. Pressure may be allowed to increase in an upper portion of the formation to provide a gas cap in the upper portion. At least some hydrocarbons are produced from a lower portion of the formation.

  12. Heating tar sands formations while controlling pressure

    DOE Patents [OSTI]

    Stegemeier, George Leo [Houston, TX; Beer, Gary Lee [Houston, TX; Zhang, Etuan [Houston, TX

    2010-01-12

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. A pressure in the majority of the section may be maintained below a fracture pressure of the formation. The pressure in the majority of the section may be reduced to a selected pressure after the average temperature reaches a temperature that is above 240.degree. C. and is at or below pyrolysis temperatures of hydrocarbons in the section. At least some hydrocarbon fluids may be produced from the formation.

  13. Solution mining dawsonite from hydrocarbon containing formations with a chelating agent

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX)

    2009-07-07

    A method for treating an oil shale formation comprising dawsonite includes providing heat from one or more heaters to the formation to heat the formation. Hydrocarbon fluids are produced from the formation. At least some dawsonite in the formation is decomposed with the provided heat. A chelating agent is provided to the formation to dissolve at least some dawsonite decomposition products. The dissolved dawsonite decomposition products are produced from the formation.

  14. Methods for producing complex films, and films produced thereby

    SciTech Connect (OSTI)

    Duty, Chad E.; Bennett, Charlee J. C.; Moon, Ji -Won; Phelps, Tommy J.; Blue, Craig A.; Dai, Quanqin; Hu, Michael Z.; Ivanov, Ilia N.; Jellison, Jr., Gerald E.; Love, Lonnie J.; Ott, Ronald D.; Parish, Chad M.; Walker, Steven

    2015-11-24

    A method for producing a film, the method comprising melting a layer of precursor particles on a substrate until at least a portion of the melted particles are planarized and merged to produce the film. The invention is also directed to a method for producing a photovoltaic film, the method comprising depositing particles having a photovoltaic or other property onto a substrate, and affixing the particles to the substrate, wherein the particles may or may not be subsequently melted. Also described herein are films produced by these methods, methods for producing a patterned film on a substrate, and methods for producing a multilayer structure.

  15. In situ oxidation of subsurface formations

    DOE Patents [OSTI]

    Beer, Gary Lee; Mo, Weijian; Li, Busheng; Shen, Chonghui

    2011-01-11

    Methods and systems for treating a hydrocarbon containing formation described herein include providing heat to a first portion of the formation from a plurality of heaters in the first portion, producing produced through one or more production wells in a second portion of the formation, reducing or turning off heat provided to the first portion after a selected time, providing an oxidizing fluid through one or more of the heater wells in the first portion, providing heat to the first portion and the second portion through oxidation of at least some hydrocarbons in the first portion, and producing fluids through at least one of the production wells in the second portion. The produced fluids may include at least some oxidized hydrocarbons produced in the first portion.

  16. Horizontal natural gas storage caverns and methods for producing same

    DOE Patents [OSTI]

    Russo, Anthony

    1995-01-01

    The invention provides caverns and methods for producing caverns in bedded salt deposits for the storage of materials that are not solvents for salt. The contemplated salt deposits are of the bedded, non-domed variety, more particularly salt found in layered formations that are sufficiently thick to enable the production of commercially usefully sized caverns completely encompassed by walls of salt of the formation. In a preferred method, a first bore hole is drilled into the salt formation and a cavity for receiving insolubles is leached from the salt formation. Thereafter, at a predetermined distance away from the first bore hole, a second bore hole is drilled towards the salt formation. As this drill approaches the salt, the drill assumes a slant approach and enters the salt and drills through it in a horizontal direction until it intersects the cavity for receiving insolubles. This produces a substantially horizontal conduit from which solvent is controlledly supplied to the surrounding salt formation, leaching the salt and producing a concentrated brine which is removed through the first bore hole. Insolubles are collected in the cavity for receiving insolubles. By controlledly supplying solvent, a horizontal cavern is produced with two bore holes extending therefrom.

  17. Method for producing highly reflective metal surfaces

    DOE Patents [OSTI]

    Arnold, J.B.; Steger, P.J.; Wright, R.R.

    1982-03-04

    The invention is a novel method for producing mirror surfaces which are extremely smooth and which have high optical reflectivity. The method includes depositing, by electrolysis, an amorphous layer of nickel on an article and then diamond-machining the resulting nickel surface to increase its smoothness and reflectivity. The machined nickel surface then is passivated with respect to the formation of bonds with electrodeposited nickel. Nickel then is electrodeposited on the passivated surface to form a layer of electroplated nickel whose inside surface is a replica of the passivated surface. The mandrel then may be-re-passivated and provided with a layer of electrodeposited nickel, which is then recovered from the mandrel providing a second replica. The mandrel can be so re-used to provide many such replicas. As compared with producing each mirror-finished article by plating and diamond-machining, the new method is faster and less expensive.

  18. Varying heating in dawsonite zones in hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J.; Xie, Xueying; Miller, David Scott

    2009-07-07

    A method for treating an oil shale formation comprising dawsonite includes assessing a dawsonite composition of one or more zones in the formation. Heat from one or more heaters is provided to the formation such that different amounts of heat are provided to zones with different dawsonite compositions. The provided heat is allowed to transfer from the heaters to the formation. Fluids are produced from the formation.

  19. Heating tar sands formations to visbreaking temperatures

    DOE Patents [OSTI]

    Karanikas, John Michael; Colmenares, Tulio Rafael; Zhang, Etuan; Marino, Marian; Roes, Augustinus Wilhelmus Maria; Ryan, Robert Charles; Beer, Gary Lee; Dombrowski, Robert James; Jaiswal, Namit

    2009-12-22

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat may be controlled so that at least a majority of the section reaches an average temperature of between 200.degree. C. and 240.degree. C., which results in visbreaking of at least some hydrocarbons in the section. At least some visbroken hydrocarbon fluids may be produced from the formation.

  20. Treating tar sands formations with dolomite

    SciTech Connect (OSTI)

    Vinegar, Harold J.; Karanikas, John Michael

    2013-10-15

    A method for treating a karsted formation containing heavy hydrocarbons and dolomite includes providing heat to at least part of one or more karsted layers in the formation from one or more heaters located in the karsted layers. A temperature in at least one of the karsted layers is allowed to reach a decomposition temperature of dolomite in the formation. The dolomite is allowed to decompose and at least some hydrocarbons are produced from at least one of the karsted layers of the formation.

  1. Solution mining and heating by oxidation for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J.; Stegemeier, George Leo

    2009-06-23

    A method for treating an oil shale formation comprising nahcolite includes providing a first fluid to a portion of the formation. A second fluid is produced from the portion. The second fluid includes at least some nahcolite dissolved in the first fluid. A controlled amount of oxidant is provided to the portion of the formation. Hydrocarbon fluids are produced from the formation.

  2. This Week In Petroleum Printer-Friendly Version

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of oil from the layers of shale like those in the Bakken Formation is not the same as the extraction of oil from oil shale plays. See This Week In Petroleum, March 4, 2009.)...

  3. CX-005588: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Investigation of Improved Conductivity and Proppant Applications in the Bakken FormationCX(s) Applied: B3.6Date: 04/11/2011Location(s): Grand Forks, North DakotaOffice(s): Fossil Energy, National Energy Technology Laboratory

  4. Publications | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... PDF-2.55MB May, 2009: NETL R&D Tackles Technical Challenges of the Williston Basin's Bakken Formation PDF-2.3MB arrowsmdrkorange.gif Program Fact Sheets Natural Gas & Oil ...

  5. This Week In Petroleum Summary Printer-Friendly Version

    Gasoline and Diesel Fuel Update (EIA)

    to 8.7 million bd in 2014. Increasing production of light crude oil in low-permeability or tight resource formations in regions like the Bakken, Permian Basin, and Eagle...

  6. U.S. Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... in April of 2014. 51 The domestic oil boom is due primarily to new production of light sweet crude from unconventional tight-oil formations in North Dakota (Bakken) and Texas ...

  7. Method of producing submicron size particles and product produced thereby

    DOE Patents [OSTI]

    Bourne, R.S.; Eichman, C.C.; Welbon, W.W.

    1988-05-11

    Submicron size particles are produced by using a sputtering process to deposit particles into a liquid. The liquid is processed to recover the particles therefrom, and the particles have sizes in the range of twenty to two hundred Angstroms. Either metallic or non-metallic particles can be produced, and the metallic particles can be used in ''metallic inks.'' 4 figs.

  8. Method for producing a borohydride

    DOE Patents [OSTI]

    Kong, Peter C.

    2010-06-22

    A method for producing a borohydride is described that includes the steps of providing a source of borate; providing a material that chemically reduces the source of the borate to produce a borohydride; and reacting the source of the borate and the material by supplying heat at a temperature that substantially effects the production of the borohydride.

  9. Method for producing a borohydride

    DOE Patents [OSTI]

    Kong, Peter C.

    2008-09-02

    A method for producing a borohydride is described and which includes the steps of providing a source of borate; providing a material which chemically reduces the source of the borate to produce a borohydride; and reacting the source of borate and the material by supplying heat at a temperature which substantially effects the production of the borohydride.

  10. Method of producing molybdenum-99

    DOE Patents [OSTI]

    Pitcher, Eric John

    2013-05-28

    Method of producing molybdenum-99, comprising accelerating ions by means of an accelerator; directing the ions onto a metal target so as to generate neutrons having an energy of greater than 10 MeV; directing the neutrons through a converter material comprising techentium-99 to produce a mixture comprising molybdenum-99; and, chemically extracting the molybdenum-99 from the mixture.

  11. Method for producing high quality thin layer films on substrates

    DOE Patents [OSTI]

    Strongin, M.; Ruckman, M.; Strongin, D.

    1994-04-26

    A method for producing high quality, thin layer films of inorganic compounds upon the surface of a substrate is disclosed. The method involves condensing a mixture of preselected molecular precursors on the surface of a substrate and subsequently inducing the formation of reactive species using high energy photon or charged particle irradiation. The reactive species react with one another to produce a film of the desired compound upon the surface of the substrate. 4 figures.

  12. Method for producing high quality thin layer films on substrates

    DOE Patents [OSTI]

    Strongin, Myron; Ruckman, Mark; Strongin, Daniel

    1994-01-01

    A method for producing high quality, thin layer films of inorganic compounds upon the surface of a substrate is disclosed. The method involves condensing a mixture of preselected molecular precursors on the surface of a substrate and subsequently inducing the formation of reactive species using high energy photon or charged particle irradiation. The reactive species react with one another to produce a film of the desired compound upon the surface of the substrate.

  13. Methods for producing complex films, and films produced thereby...

    Office of Scientific and Technical Information (OSTI)

    This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and ... A method for producing a film, the method comprising melting a layer of precursor ...

  14. U.S. Energy Information Administration (EIA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 2014 ratio estimated at 3,600 cfb of oil produced. Like the Bakken Basin, Permian drilling has been almost exclusively oil-directed since early 2011. On June 20, Baker...

  15. Methods of producing cesium-131

    DOE Patents [OSTI]

    Meikrantz, David H; Snyder, John R

    2012-09-18

    Methods of producing cesium-131. The method comprises dissolving at least one non-irradiated barium source in water or a nitric acid solution to produce a barium target solution. The barium target solution is irradiated with neutron radiation to produce cesium-131, which is removed from the barium target solution. The cesium-131 is complexed with a calixarene compound to separate the cesium-131 from the barium target solution. A liquid:liquid extraction device or extraction column is used to separate the cesium-131 from the barium target solution.

  16. Cellulase producing microorganism ATCC 55702

    DOE Patents [OSTI]

    Dees, H.C.

    1997-12-30

    Bacteria which produce large amounts of cellulase--containing cell-free fermentate have been identified. The original bacterium (ATCC 55703) was genetically altered using nitrosoguanidine (MNNG) treatment to produce the enhanced cellulase producing bacterium (ATCC 55702), which was identified through replicate plating. ATCC 55702 has improved characteristics and qualifies for the degradation of cellulosic waste materials for fuel production, food processing, textile processing, and other industrial applications. ATCC 55702 is an improved bacterial host for genetic manipulations using recombinant DNA techniques, and is less likely to destroy genetic manipulations using standard mutagenesis techniques. 5 figs.

  17. Cellulase producing microorganism ATCC 55702

    DOE Patents [OSTI]

    Dees, H. Craig

    1997-01-01

    Bacteria which produce large amounts of cellulase--containing cell-free fermentate have been identified. The original bacterium (ATCC 55703) was genetically altered using nitrosoguanidine (MNNG) treatment to produce the enhanced cellulase producing bacterium (ATCC 55702), which was identified through replicate plating. ATCC 55702 has improved characteristics and qualifies for the degradation of cellulosic waste materials for fuel production, food processing, textile processing, and other industrial applications. ATCC 55702 is an improved bacterial host for genetic manipulations using recombinant DNA techniques, and is less likely to destroy genetic manipulations using standard mutagenesis techniques.

  18. Microorganisms for producing organic acids

    SciTech Connect (OSTI)

    Pfleger, Brian Frederick; Begemann, Matthew Brett

    2014-09-30

    Organic acid-producing microorganisms and methods of using same. The organic acid-producing microorganisms comprise modifications that reduce or ablate AcsA activity or AcsA homolog activity. The modifications increase tolerance of the microorganisms to such organic acids as 3-hydroxypropionic acid, acrylic acid, propionic acid, lactic acid, and others. Further modifications to the microorganisms increase production of such organic acids as 3-hydroxypropionic acid, lactate, and others. Methods of producing such organic acids as 3-hydroxypropionic acid, lactate, and others with the modified microorganisms are provided. Methods of using acsA or homologs thereof as counter-selectable markers are also provided.

  19. Produced water volumes and management practices in the United States.

    SciTech Connect (OSTI)

    Clark, C. E.; Veil, J. A.

    2009-09-01

    Produced water volume generation and management in the United States are not well characterized at a national level. The U.S. Department of Energy (DOE) asked Argonne National Laboratory to compile data on produced water associated with oil and gas production to better understand the production volumes and management of this water. The purpose of this report is to improve understanding of produced water by providing detailed information on the volume of produced water generated in the United States and the ways in which produced water is disposed or reused. As the demand for fresh water resources increases, with no concomitant increase in surface or ground water supplies, alternate water sources, like produced water, may play an important role. Produced water is water from underground formations that is brought to the surface during oil or gas production. Because the water has been in contact with hydrocarbon-bearing formations, it contains some of the chemical characteristics of the formations and the hydrocarbons. It may include water from the reservoir, water previously injected into the formation, and any chemicals added during the production processes. The physical and chemical properties of produced water vary considerably depending on the geographic location of the field, the geologic formation, and the type of hydrocarbon product being produced. Produced water properties and volume also vary throughout the lifetime of a reservoir. Produced water is the largest volume by-product or waste stream associated with oil and gas exploration and production. Previous national produced water volume estimates are in the range of 15 to 20 billion barrels (bbl; 1 bbl = 42 U.S. gallons) generated each year in the United States (API 1988, 2000; Veil et al. 2004). However, the details on generation and management of produced water are not well understood on a national scale. Argonne National Laboratory developed detailed national-level information on the volume of produced

  20. Method and apparatus for producing thermal vapor stream

    DOE Patents [OSTI]

    Cradeur, Robert R.; Sperry, John S.; Krajicek, Richard W.

    1979-01-01

    Method and apparatus for producing a thermal vapor stream for injecting into a subterranean formation for the recovery of liquefiable minerals therefrom, including a pressure vessel containing a high pressure combustion chamber for producing a heating gas for introduction into a heating gas injector. The heating gas injector is partly immersed in a steam generating section of the pressure vessel such that the heating gas is passed through the steam generating section to produce steam and combustion products which are directed between the pressure vessel and the combustion chamber for simultaneously cooling of the combustion chamber by further heating of the steam and combustion gases.

  1. Rocky Mountain Basins Produced Water Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Historical records for produced water data were collected from multiple sources, including Amoco, British Petroleum, Anadarko Petroleum Corporation, United States Geological Survey (USGS), Wyoming Oil and Gas Commission (WOGC), Denver Earth Resources Library (DERL), Bill Barrett Corporation, Stone Energy, and other operators. In addition, 86 new samples were collected during the summers of 2003 and 2004 from the following areas: Waltman-Cave Gulch, Pinedale, Tablerock and Wild Rose. Samples were tested for standard seven component "Stiff analyses", and strontium and oxygen isotopes. 16,035 analyses were winnowed to 8028 unique records for 3276 wells after a data screening process was completed. [Copied from the Readme document in the zipped file available at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the Zipped file to your PC. When opened, it will contain four versions of the database: ACCESS, EXCEL, DBF, and CSV formats. The information consists of detailed water analyses from basins in the Rocky Mountain region.

  2. Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria; Mo, Weijian; Muylle, Michel Serge Marie; Mandema, Remco Hugo; Nair, Vijay

    2009-09-01

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

  3. Production from multiple zones of a tar sands formation

    DOE Patents [OSTI]

    Karanikas, John Michael; Vinegar, Harold J

    2013-02-26

    A method for treating a tar sands formation includes providing heat to at least part of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat is allowed to transfer from the heaters to at least a portion of the formation. Fluids are produced from the formation through at least one production well that is located in at least two zones in the formation. The first zone has an initial permeability of at least 1 darcy. The second zone has an initial of at most 0.1 darcy. The two zones are separated by a substantially impermeable barrier.

  4. Laser beam pulse formatting method

    DOE Patents [OSTI]

    Daly, Thomas P.; Moses, Edward I.; Patterson, Ralph W.; Sawicki, Richard H.

    1994-01-01

    A method for formatting a laser beam pulse (20) using one or more delay loops (10). The delay loops (10) have a partially reflective beam splitter (12) and a plurality of highly reflective mirrors (14) arranged such that the laser beam pulse (20) enters into the delay loop (10) through the beam splitter (12) and circulates therein along a delay loop length (24) defined by the mirrors (14). As the laser beam pulse (20) circulates within the delay loop (10) a portion thereof is emitted upon each completed circuit when the laser beam pulse (20) strikes the beam splitter (12). The laser beam pulse (20) is thereby formatted into a plurality of sub-pulses (50, 52, 54 and 56). The delay loops (10) are used in combination to produce complex waveforms by combining the sub-pulses (50, 52, 54 and 56) using additive waveform synthesis.

  5. THE BLACK HOLE FORMATION PROBABILITY

    SciTech Connect (OSTI)

    Clausen, Drew; Piro, Anthony L.; Ott, Christian D.

    2015-02-01

    A longstanding question in stellar evolution is which massive stars produce black holes (BHs) rather than neutron stars (NSs) upon death. It has been common practice to assume that a given zero-age main sequence (ZAMS) mass star (and perhaps a given metallicity) simply produces either an NS or a BH, but this fails to account for a myriad of other variables that may effect this outcome, such as spin, binarity, or even stochastic differences in the stellar structure near core collapse. We argue that instead a probabilistic description of NS versus BH formation may be better suited to account for the current uncertainties in understanding how massive stars die. We present an initial exploration of the probability that a star will make a BH as a function of its ZAMS mass, P {sub BH}(M {sub ZAMS}). Although we find that it is difficult to derive a unique P {sub BH}(M {sub ZAMS}) using current measurements of both the BH mass distribution and the degree of chemical enrichment by massive stars, we demonstrate how P {sub BH}(M {sub ZAMS}) changes with these various observational and theoretical uncertainties. We anticipate that future studies of Galactic BHs and theoretical studies of core collapse will refine P {sub BH}(M {sub ZAMS}) and argue that this framework is an important new step toward better understanding BH formation. A probabilistic description of BH formation will be useful as input for future population synthesis studies that are interested in the formation of X-ray binaries, the nature and event rate of gravitational wave sources, and answering questions about chemical enrichment.

  6. Catalyst for producing lower alcohols

    DOE Patents [OSTI]

    Rathke, Jerome W.; Klingler, Robert J.; Heiberger, John J.

    1987-01-01

    A process and system for the production of the lower alcohols such as methanol, ethanol and propanol involves the reaction of carbon monoxide and water in the presence of a lead salt and an alkali metal formate catalyst combination. The lead salt is present as solid particles such as lead titanate, lead molybdate, lead vanadate, lead zirconate, lead tantalate and lead silicates coated or in slurry within molten alkali metal formate. The reactants, carbon monoxide and steam are provided in gas form at relatively low pressures below 100 atmospheres and at temperatures of 200-400.degree. C. The resulted lower alcohols can be separated into boiling point fractions and recovered from the excess reactants by distillation.

  7. Apparatus for producing laser targets

    DOE Patents [OSTI]

    Jarboe, T.R.; Baker, W.R.

    1975-09-23

    This patent relates to an apparatus and method for producing deuterium targets or pellets of 25u to 75u diameter. The pellets are sliced from a continuously spun solid deuterium thread at a rate of up to 10 pellets/second. The pellets after being sliced from the continuous thread of deuterium are collimated and directed to a point of use, such as a laser activated combustion or explosion chamber wherein the pellets are imploded by laser energy or laser produced target plasmas for neutral beam injection. (auth)

  8. Method for producing laser targets

    DOE Patents [OSTI]

    Jarboe, Thomas R.; Baker, William R.

    1977-01-01

    An apparatus and method for producing deuterium targets or pellets of 25.mu. to 75.mu. diameter. The pellets are sliced from a continuously spun solid deuterium thread at a rate of up to 10 pellets/second. The pellets after being sliced from the continuous thread of deuterium are collimated and directed to a point of use, such as a laser activated combustion or explosion chamber wherein the pellets are imploded by laser energy or laser produced target plasmas for neutral beam injection.

  9. Method for producing refractory nitrides

    DOE Patents [OSTI]

    Quinby, Thomas C.

    1989-01-24

    A process for making fine, uniform metal nitride powders that can be hot pressed or sintered. A metal salt is placed in a solvent with Melamine and warmed until a metal-Melamine compound forms. The solution is cooled and the metal-Melamine precipitate is calcined at a temperature below 700.degree. C. to form the metal nitrides and to avoid formation of the metal oxide.

  10. Method for producing highly reflective metal surfaces

    DOE Patents [OSTI]

    Arnold, Jones B.; Steger, Philip J.; Wright, Ralph R.

    1983-01-01

    The invention is a novel method for producing mirror surfaces which are extremely smooth and which have high optical reflectivity. The method includes electrolessly depositing an amorphous layer of nickel on an article and then diamond-machining the resulting nickel surface to increase its smoothness and reflectivity. The machined nickel surface then is passivated with respect to the formation of bonds with electrodeposited nickel. Nickel then is electrodeposited on the passivated surface to form a layer of electroplated nickel whose inside surface is a replica of the passivated surface. The electroplated nickel layer then is separated from the passivated surface. The mandrel then may be re-passivated and provided with a layer of electrodeposited nickel, which is then recovered from the mandrel providing a second replica. The mandrel can be so re-used to provide many such replicas. As compared with producing each mirror-finished article by plating and diamond-machining, the new method is faster and less expensive.

  11. Midwest Biodiesel Producers LLC | Open Energy Information

    Open Energy Info (EERE)

    Biodiesel Producers LLC Jump to: navigation, search Name: Midwest Biodiesel Producers LLC Place: Alexandria, South Dakota Zip: 57311 Product: South Dakota-based biodiesel producer....

  12. METHOD FOR PRODUCING DIBORON TETRACHLORIDE

    DOE Patents [OSTI]

    Frazer, J.W.; Holzmann, R.T.

    1961-08-01

    A method of producing diboron tetrachloride from boron trichloride is described. Gaseous boron trichloride is passed through a cavity resonating at a microwave frequency whereby a portion of the boron trichloride is converted into diboron tetrachloride. The diboron tetrachloride may then be separated from the boron trichloride by conventional means. (AEC)

  13. Process for producing chalcogenide semiconductors

    DOE Patents [OSTI]

    Noufi, Rommel; Chen, Yih-Wen

    1987-01-01

    A process for producing chalcogenide semiconductor material is disclosed. The process includes forming a base metal layer and then contacting this layer with a solution having a low pH and containing ions from at least one chalcogen to chalcogenize the layer and form the chalcogenide semiconductor material.

  14. Process for producing chalcogenide semiconductors

    DOE Patents [OSTI]

    Noufi, R.; Chen, Y.W.

    1985-04-30

    A process for producing chalcogenide semiconductor material is disclosed. The process includes forming a base metal layer and then contacting this layer with a solution having a low pH and containing ions from at least one chalcogen to chalcogenize the layer and form the chalcogenide semiconductor material.

  15. Hummingbird structure in southeastern Saskatchewan

    SciTech Connect (OSTI)

    Smith, D.D.

    1985-05-01

    Saskatchewan's first Devonian oil pool was discovered September 1966, at Hummingbird, 45 mi (72 km) southwest of Weyburn, Saskatchewan. The Hummingbird structure, located on the northwest flank of the Williston basin, is domal is nature and covers approximately 1 mi/sup 2/ (2.6 km/sup 2/). Oil production is from two zones. The Ratcliffe Member of the Mississippian Charles Formation produces from an algal and bioclastic limestone averaging 49 ft (15 m) thick. The Devonian Birdbear Formation produces from a finely crystalline vuggy dolomite averaging 56 ft (17 m) thick. The Hummingbird structure is a sedimentary structure resulting from multiple-stage salt solution and collapse. Recurring local solution of Middle Devonian Prairie Evaporite during Late Devonian and Early Mississippian time resulted in collapse of overlying strata and deposition of compensating thicknesses of Souris River, Duperow, and Bakken sediments. Between Mississippian and Cretaceous time, solution of Prairie Evaporite in the surrounding area caused collapse of all super-Prairie evaporite beds. The extra Souris River, Duperow, and Bakken strata at Hummingbird created the structure. Vertical migration of formation waters along a high-angle fault is suggested as the cause of the local salt solution at Hummingbird.

  16. Method for producing nanostructured metal-oxides

    DOE Patents [OSTI]

    Tillotson, Thomas M.; Simpson, Randall L.; Hrubesh, Lawrence W.; Gash, Alexander

    2006-01-17

    A synthetic route for producing nanostructure metal-oxide-based materials using sol-gel processing. This procedure employs the use of stable and inexpensive hydrated-metal inorganic salts and environmentally friendly solvents such as water and ethanol. The synthesis involves the dissolution of the metal salt in a solvent followed by the addition of a proton scavenger, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively. Using this method synthesis of metal-oxide nanostructured materials have been carried out using inorganic salts, such as of Fe.sup.3+, Cr.sup.3+, Al.sup.3+, Ga.sup.3+, In.sup.3+, Hf.sup.4+, Sn.sup.4+, Zr.sup.4+, Nb.sup.5+, W.sup.6+, Pr.sup.3+, Er.sup.3+, Nd.sup.3+, Ce.sup.3+, U.sup.3+ and Y.sup.3+. The process is general and nanostructured metal-oxides from the following elements of the periodic table can be made: Groups 2 through 13, part of Group 14 (germanium, tin, lead), part of Group 15 (antimony, bismuth), part of Group 16 (polonium), and the lanthanides and actinides. The sol-gel processing allows for the addition of insoluble materials (e.g., metals or polymers) to the viscous sol, just before gelation, to produce a uniformly distributed nanocomposites upon gelation. As an example, energetic nanocomposites of Fe.sub.xO.sub.y gel with distributed Al metal are readily made. The compositions are stable, safe, and can be readily ignited to thermitic reaction.

  17. PROCESS FOR PRODUCING URANIUM TETRAFLUORIDE

    DOE Patents [OSTI]

    Harvey, B.G.

    1954-09-14

    >This patent relates to improvements in the method for producing uranium tetrafluoride by treating an aqueous solutlon of a uranyl salt at an elevated temperature with a reducing agent effective in acld solutlon in the presence of hydrofluoric acid. Uranium tetrafluoride produced this way frequentiy contains impurities in the raw material serving as the source of uranium. Uranium tetrafluoride much less contaminated with impurities than when prepared by the above method can be prepared from materials containing such impurities by first adding a small proportion of reducing agent so as to cause a small fraction, for example 1 to 5% of the uranium tetrafluoride to be precipitated, rejecting such precipitate, and then precipitating and recovering the remainder of the uranium tetrafluoride.

  18. PROCESS FOR PRODUCING URANIUM HALIDES

    DOE Patents [OSTI]

    Murphree, E.V.

    1957-10-29

    A process amd associated apparatus for producing UF/sub 4/ from U/sub 3/ O/sub 8/ by a fluidized'' technique are reported. The U/sub 3/O/sub 8/ is first reduced to UO/sub 2/ by reaction with hydrogen, and the lower oxide of uranium is then reacted with gaseous HF to produce UF/sub 4/. In each case the reactant gas is used, alone or in combination with inert gases, to fluidize'' the finely divided reactant solid. The complete setup of the plant equipment including bins, reactor and the associated piping and valving, is described. An auxiliary fluorination reactor allows for the direct production of UF/sub 6/ from UF/sub 4/ and fluorine gas, or if desired, UF/sub 4/ may be collected as the product.

  19. Process for producing advanced ceramics

    DOE Patents [OSTI]

    Kwong, Kyei-Sing

    1996-01-01

    A process for the synthesis of homogeneous advanced ceramics such as SiC+AlN, SiAlON, SiC+Al.sub.2 O.sub.3, and Si.sub.3 N.sub.4 +AlN from natural clays such as kaolin, halloysite and montmorillonite by an intercalation and heat treatment method. Included are the steps of refining clays, intercalating organic compounds into the layered structure of clays, drying the intercalated mixture, firing the treated atmospheres and grinding the loosely agglomerated structure. Advanced ceramics produced by this procedure have the advantages of homogeneity, cost effectiveness, simplicity of manufacture, ease of grind and a short process time. Advanced ceramics produced by this process can be used for refractory, wear part and structure ceramics.

  20. Method for producing carbon nanotubes

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Chen, Chun-Ku

    2006-02-14

    Method for producing carbon nanotubes. Carbon nanotubes were prepared using a low power, atmospheric pressure, microwave-generated plasma torch system. After generating carbon monoxide microwave plasma, a flow of carbon monoxide was directed first through a bed of metal particles/glass beads and then along the outer surface of a ceramic tube located in the plasma. As a flow of argon was introduced into the plasma through the ceramic tube, ropes of entangled carbon nanotubes, attached to the surface of the tube, were produced. Of these, longer ropes formed on the surface portion of the tube located in the center of the plasma. Transmission electron micrographs of individual nanotubes revealed that many were single-walled.

  1. Fish Producers Aquaculture Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Aquaculture Low Temperature Geothermal Facility Jump to: navigation, search Name Fish Producers Aquaculture Low Temperature Geothermal Facility Facility Fish Producers...

  2. Method for producing hydrophobic aerogels

    DOE Patents [OSTI]

    Hrubesh, Lawrence W. (Pleasanton, CA); Poco, John F. (Livermore, CA); Coronado, Paul R. (Livermore, CA)

    1999-01-01

    A method for treating a dried monolithic aerogel containing non-dispersed particles, with an organometallic surface modifying agent to produce hydrophobic aerogels. The dried, porous hydrophobic aerogels contain a protective layer of alkyl groups, such as methyl groups, on the modified surfaces of the pores of the aerogel. The alkyl groups at the aerogel surface typically contain at least one carbon-metal bond per group.

  3. Method for producing monodisperse aerosols

    DOE Patents [OSTI]

    Ortiz, Lawrence W.; Soderholm, Sidney C.

    1990-01-01

    An aerosol generator is described which is capable of producing a monodisperse aerosol within narrow limits utilizing an aqueous solution capable of providing a high population of seed nuclei and an organic solution having a low vapor pressure. The two solutions are cold nebulized, mixed, vaporized, and cooled. During cooling, particles of the organic vapor condense onto the excess seed nuclei, and grow to a uniform particle size.

  4. Method of producing cyclohexasilane compounds

    DOE Patents [OSTI]

    Elangovan, Arumugasamy; Anderson, Kenneth; Boudjouk, Philip R; Schulz, Douglas L

    2015-03-10

    A method of preparing a cyclohexasilane compound from trichlorosilane is provided. The method includes contacting trichlorosilane with a reagent composition to produce a compound containing a tetradecahalocyclohexasilane dianion, such as a tetradecachlorocyclohexasilane dianion. The reagent composition typically includes (a) tertiary polyamine ligand; and (b) a deprotonating reagent, such as a tertiary amine having a pKa of at least about 10.5. Methods of converting the tetradecahalocyclohexasilane dianion-containing compound to cyclohexasilane or a dodecaorganocyclohexasilane are also provided.

  5. Method for producing hydrophobic aerogels

    SciTech Connect (OSTI)

    Hrubesh, L.W.; Poco, J.F.; Coronado, P.R.

    1999-12-21

    A method is described for treating a dried monolithic aerogel containing non-dispersed particles, with an organometallic surface modifying agent to produce hydrophobic aerogels. The dried, porous hydrophobic aerogels contain a protective layer of alkyl groups, such as methyl groups, on the modified surfaces of the pores of the aerogel. The alkyl groups at the aerogel surface typically contain at least one carbon-metal bond per group.

  6. Method for producing metallic microparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-06-29

    Method for producing metallic particles. The method converts metallic nanoparticles into larger, spherical metallic particles. An aerosol of solid metallic nanoparticles and a non-oxidizing plasma having a portion sufficiently hot to melt the nanoparticles are generated. The aerosol is directed into the plasma where the metallic nanoparticles melt, collide, join, and spheroidize. The molten spherical metallic particles are directed away from the plasma and enter the afterglow where they cool and solidify.

  7. Method for producing metallic nanoparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-02-10

    Method for producing metallic nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating non-oxidizing plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone to metal vapor. The metal vapor is directed away from the hot zone and to the plasma afterglow where it cools and condenses to form solid metallic nanoparticles.

  8. NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS

    SciTech Connect (OSTI)

    Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung

    2003-09-24

    of water quality data entry. (4) Acquisition of ground water data from the New Mexico State Engineer's office, including chloride content and TDS (Total Dissolved Solids) for over 30,000 data points in southeast New Mexico. (5) Creation of a web-based scale prediction tool, again with a web-based interface, that uses two common scaling indices to predict the likelihood of scaling. This prediction tool can either run from user input data, or the user can select samples from the water analysis database. (6) Creation of depth-to-groundwater maps for the study area. (7) Analysis of water quality data by formation. (8) Continuation of efforts to collect produced water quality information from operators in the southeast New Mexico area. (9) Qualitative assessment of produced water from various formations regarding corrosivity. (10) Efforts at corrosion education in the region through operator visits. Future work on this project will include: (1) Development of an integrated web and GIS interface for all the information collected in this effort. (2) Continued development of a fuzzy logic spill risk assessment tool that was initially developed prior to this project. Improvements will include addition of parameters found to be significant in determining the impact of a brine spill at a specific site. (3) Compilation of both hard copy and online corrosion toolkit material.

  9. NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS

    SciTech Connect (OSTI)

    Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung; Naomi Davidson; Ajeet Kumar Reddy; Mingzhen Wei

    2003-04-01

    accuracy and speed of water quality data entry. (4) Acquisition of ground water data from the New Mexico State Engineer's office, including chloride content and TDS (Total Dissolved Solids) for over 30,000 data points in southeast New Mexico. (5) Creation of a web-based scale prediction tool, again with a web-based interface, that uses two common scaling indices (Stiff-Davis and Oddo-Thomson) to predict the likelihood of scaling. This prediction tool can either run from user input data, or the user can select samples from the water analysis database. (6) Creation of depth-to-groundwater maps for the study area. (7) Analysis of water quality data by formation. (8) Continuation of efforts to collect produced water quality information from operators in the southeast New Mexico area. (9) Qualitative assessment of produced water from various formations regarding corrosivity. (10) Efforts at corrosion education in the region through operator visits. Future work on this project will include: (11) Development of an integrated web and GIS interface for all the information collected in this effort. (12) Continued development of a fuzzy logic spill risk assessment tool that was initially developed prior to this project. Improvements will include addition of parameters found to be significant in determining the impact of a brine spill at a specific site. (13) Cleanup and integration of water quality databases. (14) Compilation of both hard copy and online corrosion toolkit material.

  10. Method for producing a tube

    DOE Patents [OSTI]

    Peterson, Kenneth A.; Rohde, Steven B.; Pfeifer, Kent B.; Turner, Timothy S.

    2007-01-02

    A method is described for producing tubular substrates having parallel spaced concentric rings of electrical conductors that can be used as the drift tube of an Ion Mobility Spectrometer (IMS). The invention comprises providing electrodes on the inside of a tube that are electrically connected to the outside of the tube through conductors that extend between adjacent plies of substrate that are combined to form the tube. Tubular substrates are formed from flexible polymeric printed wiring board materials, ceramic materials and material compositions of glass and ceramic, commonly known as Low Temperature Co-Fired Ceramic (LTCC). The adjacent plies are sealed together around the electrode.

  11. METHOD FOR PRODUCING THORIUM TETRACHLORIDE

    DOE Patents [OSTI]

    Mason, E.A.; Cobb, C.M.

    1960-03-15

    A process for producing thorium tetrachloride from thorium concentrate comprises reacting thorium concentrates with a carbonaceous reducing agent in excess of 0.05 part by weight per part of thoriferous concentrate at a temperature in excess of 1300 deg C, cooling and comminuting the mass, chlorinating the resulting comminuting mass by suspending in a gaseous chlorinating agent in a fluidized reactor at a temperatare maintained between about l85 deg C and 770 deg C, and removing the resulting solid ThCl/sub 4/ from the reaction zone.

  12. Producing biofuels using polyketide synthases

    DOE Patents [OSTI]

    Katz, Leonard; Fortman, Jeffrey L; Keasling, Jay D

    2013-04-16

    The present invention provides for a non-naturally occurring polyketide synthase (PKS) capable of synthesizing a carboxylic acid or a lactone, and a composition such that a carboxylic acid or lactone is included. The carboxylic acid or lactone, or derivative thereof, is useful as a biofuel. The present invention also provides for a recombinant nucleic acid or vector that encodes such a PKS, and host cells which also have such a recombinant nucleic acid or vector. The present invention also provides for a method of producing such carboxylic acids or lactones using such a PKS.

  13. Fatty acid-producing hosts

    DOE Patents [OSTI]

    Pfleger, Brian F; Lennen, Rebecca M

    2013-12-31

    Described are hosts for overproducing a fatty acid product such as a fatty acid. The hosts include an exogenous nucleic acid encoding a thioesterase and, optionally, an exogenous nucleic acid encoding an acetyl-CoA carboxylase, wherein an acyl-CoA synthetase in the hosts are functionally delected. The hosts prefereably include the nucleic acid encoding the thioesterase at an intermediate copy number. The hosts are preferably recominantly stable and growth-competent at 37.degree. C. Methods of producing a fatty acid product comprising culturing such hosts at 37.degree. C. are also described.

  14. Autogenous electrolyte, non-pyrolytically produced solid capacitor structure

    DOE Patents [OSTI]

    Sharp, Donald J.; Armstrong, Pamela S.; Panitz, Janda Kirk G.

    1998-01-01

    A solid electrolytic capacitor having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects.

  15. Autogenous electrolyte, non-pyrolytically produced solid capacitor structure

    DOE Patents [OSTI]

    Sharp, D.J.; Armstrong, P.S.; Panitz, J.K.G.

    1998-03-17

    A solid electrolytic capacitor is described having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects. 2 figs.

  16. Solution mining systems and methods for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J.; de Rouffignac, Eric Pierre; Schoeling, Lanny Gene

    2009-07-14

    A method for treating an oil shale formation comprising nahcolite is disclosed. The method includes providing a first fluid to a portion of the formation through at least two injection wells. A second fluid is produced from the portion through at least one injection well until at least two injection wells are interconnected such that fluid can flow between the two injection wells. The second fluid includes at least some nahcolite dissolved in the first fluid. The first fluid is injected through one of the interconnected injection wells. The second fluid is produced from at least one of the interconnected injection wells. Heat is provided from one or more heaters to the formation to heat the formation. Hydrocarbon fluids are produced from the formation.

  17. Regional geologic characteristics relevant to horizontal drilling, Woodford Shale, Anadarko basin, Oklahoma

    SciTech Connect (OSTI)

    Hester, T.C.; Schmoker, J.W. )

    1991-06-01

    Horizontal drilling in the Late Devonian-Early Mississippian Bakken Formation of the Williston basin has spurred new interest in other black shales as primary hydrocarbon reservoirs. The Late Devonian-Early Mississippian Woodford Shale, which is similar in some respects to the Bakken Formation, is a major source of oil and gas in the Anadarko basin of Oklahoma and could prove to be a significant reservoir rock as well. The three regional geologic characteristics of the Woodford discussed here are of likely importance to horizontal drilling programs, although direct relations to drilling strategy cannot be developed until empirical data from horizontal tests become available. First, the Woodford Shale is composed of three distinct depositional units (the upper, middle, and lower informal members) with different physical and geochemical properties. Second, a paleotopographic high that was rising before and during Woodford deposition divided the Woodford Shale into northeast and southwest depocenters. Third, Woodford depositional patterns are overprinted by thermal-maturity trends shaped primarily by differential burial of the Woodford during Pennsylvanian and Permian time. The Woodford Shale northeast of the forebulge is generally immature to marginally mature, whereas its thermal maturity southwest of the forebulge ranges from mature to postmature with respect to oil generation. A formation resistivity of about 35 ohm-m approximates the updip limit of oil-saturated Woodford Shale from which free oil might be produced from fracture systems.

  18. Water management technologies used by Marcellus Shale Gas Producers.

    SciTech Connect (OSTI)

    Veil, J. A.; Environmental Science Division

    2010-07-30

    Natural gas represents an important energy source for the United States. According to the U.S. Department of Energy's (DOE's) Energy Information Administration (EIA), about 22% of the country's energy needs are provided by natural gas. Historically, natural gas was produced from conventional vertical wells drilled into porous hydrocarbon-containing formations. During the past decade, operators have increasingly looked to other unconventional sources of natural gas, such as coal bed methane, tight gas sands, and gas shales.

  19. Cogeneration systems and processes for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J.; Fowler, Thomas David; Karanikas, John Michael

    2009-12-29

    A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

  20. Method of producing metallic materials

    DOE Patents [OSTI]

    Branagan, Daniel J.

    2004-02-10

    The invention includes a method of producing a hard metallic material by forming a mixture containing at least 55% iron and at least one of B, C, Si and P. The mixture is formed into an alloy and cooled to form a metallic material having a hardness greater than about 9.2 GPa. The invention includes a method of forming a wire by combining a metal strip and a powder. The strip and the powder are rolled to form a wire containing at least 55% iron and from 2-7 additional elements including at least one of C, Si and B. The invention also includes a method of forming a hardened surface on a substrate by processing a solid mass to form a powder, applying the powder to a surface to form a layer containing metallic glass, and converting the glass to a crystalline material having a nanocrystalline grain size.

  1. ANTIPROTONS PRODUCED IN SUPERNOVA REMNANTS

    SciTech Connect (OSTI)

    Berezhko, E. G.; Ksenofontov, L. T.

    2014-08-20

    We present the energy spectrum of an antiproton cosmic ray (CR) component calculated on the basis of the nonlinear kinetic model of CR production in supernova remnants (SNRs). The model includes the reacceleration of antiprotons already existing in the interstellar medium as well as the creation of antiprotons in nuclear collisions of accelerated protons with gas nuclei and their subsequent acceleration by SNR shocks. It is shown that the production of antiprotons in SNRs produces a considerable effect in their resultant energy spectrum, making it essentially flatter above 10 GeV so that the spectrum at TeV energies increases by a factor of 5. The calculated antiproton spectrum is consistent with the PAMELA data, which correspond to energies below 100 GeV. As a consistency check, we have also calculated within the same model the energy spectra of secondary nuclei and show that the measured boron-to-carbon ratio is consistent with the significant SNR contribution.

  2. Reactor-Produced Medical Radionuclides

    SciTech Connect (OSTI)

    Mirzadeh, Saed; Mausner, Leonard; Garland, Marc A

    2011-01-01

    The therapeutic use of radionuclides in nuclear medicine, oncology and cardiology is the most rapidly growing use of medical radionuclides. Since most therapeutic radionuclides are neutron rich and decay by beta emission, they are reactor-produced. This chapter deals mainly with production approaches with neutrons. Neutron interactions with matter, neutron transmission and activation rates, and neutron spectra of nuclear reactors are discussed in some detail. Further, a short discussion of the neutron-energy dependence of cross sections, reaction rates in thermal reactors, cross section measurements and flux monitoring, and general equations governing the reactor production of radionuclides are presented. Finally, the chapter is concluded by providing a number of examples encompassing the various possible reaction routes for production of a number of medical radionuclides in a reactor.

  3. Number of Producing Gas Wells

    U.S. Energy Information Administration (EIA) Indexed Site

    Producing Gas Wells Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Area 2009 2010 2011 2012 2013 2014 View History U.S. 493,100 487,627 514,637 482,822 484,994 514,786 1989-2014 Alabama 6,913 7,026 7,063 6,327 6,165 6,118 1989-2014 Alaska 261 269 277 185 159 170 1989-2014 Arizona 6 5 5 5 5 5 1989-2014 Arkansas 6,314 7,397 8,388 8,538 9,843 10,150 1989-2014 California 1,643 1,580 1,308 1,423 1,335 1,118 1989-2014

  4. Methods for producing secreted polypeptides

    DOE Patents [OSTI]

    Maiyuran, Suchindra; Fidantsef, Ana; Brody, Howard

    2008-07-01

    The present invention relates to methods for producing a polypeptide, comprising: (a) cultivating a fungal host cell in a medium conducive for the production of the polypeptide, wherein the fungal host cell comprises a nucleic acid construct comprising a first nucleotide sequence encoding a signal peptide operably linked to a second nucleotide sequence encoding the polypeptide, wherein the first nucleotide sequence is foreign to the second nucleotide sequence and the 3' end of the first nucleotide sequence is immediately upstream of the initiator codon of the second nucleotide sequence. The present invention also relates to the isolated signal peptide sequences and to constructs, vectors, and fungal host cells comprising the signal peptide sequences operably linked to nucleotide sequences encoding polypeptides.

  5. Lifecycle of laser-produced air sparks

    SciTech Connect (OSTI)

    Harilal, S. S. Brumfield, B. E.; Phillips, M. C.

    2015-06-15

    We investigated the lifecycle of laser-generated air sparks or plasmas using multiple plasma diagnostic tools. The sparks were generated by focusing the fundamental radiation from an Nd:YAG laser in air, and studies included early and late time spark dynamics, decoupling of the shock wave from the plasma core, emission from the spark kernel, cold gas excitation by UV radiation, shock waves produced by the air spark, and the spark's final decay and turbulence formation. The shadowgraphic and self-emission images showed similar spark morphology at earlier and late times of its lifecycle; however, significant differences are seen in the midlife images. Spectroscopic studies in the visible region showed intense blackbody-type radiation at early times followed by clearly resolved ionic, atomic, and molecular emission. The detected spectrum at late times clearly contained emission from both CN and N{sub 2}{sup +}. Additional spectral features have been identified at late times due to emission from O and N atoms, indicating some degree of molecular dissociation and excitation. Detailed spatially and temporally resolved emission analysis provides insight about various physical mechanisms leading to molecular and atomic emission by air sparks, including spark plasma excitation, heating of cold air by UV radiation emitted by the spark, and shock-heating.

  6. Irregular spacing of heat sources for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Miller, David Scott (Katy, TX); Uwechue, Uzo Philip (Houston, TX)

    2012-06-12

    A method for treating a hydrocarbon containing formation includes providing heat input to a first section of the formation from one or more heat sources located in the first section. Fluids are produced from the first section through a production well located at or near the center of the first section. The heat sources are configured such that the average heat input per volume of formation in the first section increases with distance from the production well.

  7. I/O Formats

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formats I/O Formats Software I/O continues to be one of the main bottlenecks for scientific applications. Here are two software packages that many application developers use to manage input/output of heterogeneous types of binary application data used on many different platforms. HDF5 and NETCDF are both implemented on top of MPI-IO and have gained popularity as alternatives to basic POSIX API. HDF5 is a machine-independent and self-documenting file format. Each HDF5 file "looks" like

  8. Level Diagram Format Choice

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Which format should I use? There is no clear-cut answer to this question -- different solutions work better in different situations. In an effort to help you decide which will work best for you, we provide a discussion of the advantages and disadvantages of the three available formats. GIF: GIF stands for Graphic Interchange Format. It was developed by CompuServe as a device-independent way to store pictures. The files are well-compressed, so download time is relatively short. Most web browsers

  9. Sparse Image Format

    Energy Science and Technology Software Center (OSTI)

    2007-04-12

    The Sparse Image Format (SIF) is a file format for storing spare raster images. It works by breaking an image down into tiles. Space is savid by only storing non-uniform tiles, i.e. tiles with at least two different pixel values. If a tile is completely uniform, its common pixel value is stored instead of the complete tile raster. The software is a library in the C language used for manipulating files in SIF format. Itmore » supports large files (> 2GB) and is designed to build in Windows and Linux environments.« less

  10. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2012-06-05

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons including mobilized hydrocarbons are produced from the portion.

  11. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2010-06-08

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons are produced from the portion.

  12. Engineering microbes to produce biofuels

    SciTech Connect (OSTI)

    Wackett, LP

    2011-06-01

    The current biofuels landscape is chaotic. It is controlled by the rules imposed by economic forces and driven by the necessity of finding new sources of energy, particularly motor fuels. The need is bringing forth great creativity in uncovering new candidate fuel molecules that can be made via metabolic engineering. These next generation fuels include long-chain alcohols, terpenoid hydrocarbons, and diesel-length alkanes. Renewable fuels contain carbon derived from carbon dioxide. The carbon dioxide is derived directly by a photosynthetic fuel-producing organism(s) or via intermediary biomass polymers that were previously derived from carbon dioxide. To use the latter economically, biomass depolymerization processes must improve and this is a very active area of research. There are competitive approaches with some groups using enzyme based methods and others using chemical catalysts. With the former, feedstock and end-product toxicity loom as major problems. Advances chiefly rest on the ability to manipulate biological systems. Computational and modular construction approaches are key. For example, novel metabolic networks have been constructed to make long-chain alcohols and hydrocarbons that have superior fuel properties over ethanol. A particularly exciting approach is to implement a direct utilization of solar energy to make a usable fuel. A number of approaches use the components of current biological systems, but re-engineer them for more direct, efficient production of fuels.

  13. Method for producing high surface area chromia materials for catalysis

    DOE Patents [OSTI]

    Gash, Alexander E.; Satcher, Joe; Tillotson, Thomas; Hrubesh, Lawrence; Simpson, Randall

    2007-05-01

    Nanostructured chromium(III)-oxide-based materials using sol-gel processing and a synthetic route for producing such materials are disclosed herein. Monolithic aerogels and xerogels having surface areas between 150 m.sup.2/g and 520 m.sup.2/g have been produced. The synthetic method employs the use of stable and inexpensive hydrated-chromium(III) inorganic salts and common solvents such as water, ethanol, methanol, 1-propanol, t-butanol, 2-ethoxy ethanol, and ethylene glycol, DMSO, and dimethyl formamide. The synthesis involves the dissolution of the metal salt in a solvent followed by an addition of a proton scavenger, such as an epoxide, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively.

  14. Coke formation in visbreaking process

    SciTech Connect (OSTI)

    Yan, T.Y. )

    1987-04-01

    Visbreaking is a mild cracking process primarily used to reduce residual oil viscosity and thus decrease the amount of cutter stock required for blending to heavy fuels specification. It can also be used to produce incremental quantities of gasoline, middle distillates and catalytic cracker feeds. This process was widely used in the 1930s and 1940s and became obsolete until a few years ago. When the need for increased conversion of residues to light products became desirable, visbreaking offered economic advantages to many refining schemes - especially in Western Europe. Between 1978-1981, Exxon brought on stream seven visbreakers ranging from 1900 to 9100 tons/SD capacity. In January 1983, the world-wide visbreaking capacity was over 2 MM B/SD. The visbreaking process and its application in refinery operations have been well described. In general, the process economics improve as the process severity is increased but it is limited by coke formation in the process. For this reason, they have studied the kinetics of coke formation in the visbreaking process.

  15. The La Pica Formation-new ideas and more questions

    SciTech Connect (OSTI)

    Linares, Luz M.

    1996-08-01

    The La Pica Formation has been producing from the beginning of the century in the fields of the Santa Barbara-Jusepin trend and Pedernales field. These fields are located in the Eastern Venezuela Basin, one of the most prolific oil basins in Venezuela. The accumulative oil produced until now in Lagoven, S.A., area is 225,556 million barrels. The type of crude produced is ranging from light to heavy. The interval producing in the fields mentioned before measures in between 1000 and 3000 in. The La Pica formation is present in all of the Eastern Venezuela Basin and continues to be an important target for oil producing. In recent years, this formation has been drilled by several wells located in different areas apart from the traditional fields. These wells had provided new information which in some cases clarified some of the questions about the environment of deposition, geochemical composition age, reservoir quality and trap style. However, these wells also have raised new questions and La Pica Formation still has a number of problems. The La Pica Formation was deposited during the Late Miocene-Pliocene time, in continental to outer neritic environments. The sediments range from silts to fine sands with some shaly intervals. The first accumulations were discovered in pinchouts against highs. However, in recent seismic lines, La Pica Formation shows possible different style of traps for hydrocarbon that could contain commercial accumulations.

  16. formatting | OpenEI Community

    Open Energy Info (EERE)

    formatting Home Jweers's picture Submitted by Jweers(88) Contributor 7 August, 2013 - 18:23 New Robust References citation citing developer formatting reference Semantic Mediawiki...

  17. Gaussian entanglement of formation

    SciTech Connect (OSTI)

    Wolf, M.M.; Giedke, G.; Krueger, O.; Werner, R. F.; Cirac, J.I.

    2004-05-01

    We introduce a Gaussian version of the entanglement of formation adapted to bipartite Gaussian states by considering decompositions into pure Gaussian states only. We show that this quantity is an entanglement monotone under Gaussian operations and provide a simplified computation for states of arbitrary many modes. For the case of one mode per site the remaining variational problem can be solved analytically. If the considered state is in addition symmetric with respect to interchanging the two modes, we prove additivity of the considered entanglement measure. Moreover, in this case and considering only a single copy, our entanglement measure coincides with the true entanglement of formation.

  18. Method of condensing vaporized water in situ to treat tar sands formations

    DOE Patents [OSTI]

    Hsu, Chia-Fu

    2010-03-16

    Methods for treating a tar sands formation are described herein. Methods may include heating at least a section of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. Heat may be allowed to transfer from the heaters to at least a first portion of the formation. Conditions may be controlled in the formation so that water vaporized by the heaters in the first portion is selectively condensed in a second portion of the formation. At least some of the fluids may be produced from the formation.

  19. REDUCING PRODUCED WATER WITH DENSITY AND CONDUCTIVITY METERS

    SciTech Connect (OSTI)

    Jason T. Smith

    2004-08-01

    The work performed was an attempt to reduce the amount of produced water by using the well bore as an oil-water separator. The use of a flow meter, density meter and/or conductivity meter controlling a pumping unit would be used to achieve this goal. The natural physical differences between oil and water are easily detected inside the production stream with proper equipment. A coriolis mass meter, conductivity meter, data recorder, timer and relays were purchased and housed in a purpose-built field cabinet. The metering unit was hooked to four wells over the course of the project, Spencer No.8, Applegate Gray Unit No.1 (AGU No.1), Vollmer No.4 and Mohr No.1. All are located in the Illinois Basin, three with artificial lift pumps and one flowing well. Depth of producing formations ranges from a maximum of 846.13 m (2776 ft) to minimum of 316.69 m (1039 ft). All wells were completed in one formation of Mississippian or Pennsylvanian age. The data recorded were analyzed to determine what events could be detected. Events included pure oil or higher oil-cut fluid reaching the pump or reaching the metering equipment, the pump operating under capacity, and the well ''pumped down''. Based on how much oil and water is present in a fluid column, the pressure the fluid column imparts on a formation can be calculated. By knowing the amount of oil and water in a well bore and the maximum height water can reach, production equipment can be configured to only produce oil. However, the configuration may not be profitable. It became apparent during the course of this research the wells tested do not have an oil-water contact deep enough so traditional pumping equipment can be configured to recover oil by the proposed method. This method may work more successfully in deeper basins. Other interesting anomalies were also detected in the data.

  20. Methods of cracking a crude product to produce additional crude products

    DOE Patents [OSTI]

    Mo, Weijian; Roes, Augustinus Wilhelmus Maria; Nair, Vijay

    2009-09-08

    A method for producing a crude product is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce one or more crude products. At least one of the crude products has a boiling range distribution from 38.degree. C. and 343.degree. C. as determined by ASTM Method D5307. The crude product having the boiling range distribution from 38.degree. C. and 343.degree. C. is catalytically cracked to produce one or more additional crude products. At least one of the additional crude products is a second gas stream. The second gas stream has a boiling point of at most 38.degree. C. at 0.101 MPa.

  1. In situ heat treatment of a tar sands formation after drive process treatment

    DOE Patents [OSTI]

    Vinegar, Harold J.; Stanecki, John

    2010-09-21

    A method for treating a tar sands formation includes providing a drive fluid to a hydrocarbon containing layer of the tar sands formation to mobilize at least some hydrocarbons in the layer. At least some first hydrocarbons from the layer are produced. Heat is provided to the layer from one or more heaters located in the formation. At least some second hydrocarbons are produced from the layer of the formation. The second hydrocarbons include at least some hydrocarbons that are upgraded compared to the first hydrocarbons produced by using the drive fluid.

  2. Combustion chamber and thermal vapor stream producing apparatus and method

    DOE Patents [OSTI]

    Sperry, John S.; Krajicek, Richard W.; Cradeur, Robert R.

    1978-01-01

    A new and improved method and apparatus for burning a hydrocarbon fuel for producing a high pressure thermal vapor stream comprising steam and combustion gases for injecting into a subterranean formation for the recovery of liquefiable minerals therefrom, wherein a high pressure combustion chamber having multiple refractory lined combustion zones of varying diameters is provided for burning a hydrocarbon fuel and pressurized air in predetermined ratios injected into the chamber for producing hot combustion gases essentially free of oxidizing components and solid carbonaceous particles. The combustion zones are formed by zones of increasing diameters up a final zone of decreasing diameter to provide expansion zones which cause turbulence through controlled thorough mixing of the air and fuel to facilitate complete combustion. The high pressure air and fuel is injected into the first of the multiple zones where ignition occurs with a portion of the air injected at or near the point of ignition to further provide turbulence and more complete combustion.

  3. Formate-assisted pyrolysis

    SciTech Connect (OSTI)

    DeSisto, William Joseph; Wheeler, Marshall Clayton; van Heiningen, Adriaan R. P.

    2015-03-17

    The present invention provides, among other thing, methods for creating significantly deoxygenated bio-oils form biomass including the steps of providing a feedstock, associating the feedstock with an alkali formate to form a treated feedstock, dewatering the treated feedstock, heating the dewatered treated feedstock to form a vapor product, and condensing the vapor product to form a pyrolysis oil, wherein the pyrolysis oil contains less than 30% oxygen by weight.

  4. Control of microbially generated hydrogen sulfide in produced waters

    SciTech Connect (OSTI)

    Burger, E.D.; Vance, I.; Gammack, G.F.; Duncan, S.E.

    1995-12-31

    Production of hydrogen sulfide in produced waters due to the activity of sulfate-reducing bacteria (SRB) is a potentially serious problem. The hydrogen sulfide is not only a safety and environmental concern, it also contributes to corrosion, solids formation, a reduction in produced oil and gas values, and limitations on water discharge. Waters produced from seawater-flooded reservoirs typically contain all of the nutrients required to support SRB metabolism. Surface processing facilities provide a favorable environment in which SRB flourish, converting water-borne nutrients into biomass and H{sub 2}S. This paper will present results from a field trial in which a new technology for the biochemical control of SRB metabolism was successfully applied. A slip stream of water downstream of separators on a produced water handling facility was routed through a bioreactor in a side-steam device where microbial growth was allowed to develop fully. This slip stream was then treated with slug doses of two forms of a proprietary, nonbiocidal metabolic modifier. Results indicated that H{sub 2}S production was halted almost immediately and that the residual effect of the treatment lasted for well over one week.

  5. Process for producing ethanol from syngas

    DOE Patents [OSTI]

    Krause, Theodore R; Rathke, Jerome W; Chen, Michael J

    2013-05-14

    The invention provides a method for producing ethanol, the method comprising establishing an atmosphere containing methanol forming catalyst and ethanol forming catalyst; injecting syngas into the atmosphere at a temperature and for a time sufficient to produce methanol; and contacting the produced methanol with additional syngas at a temperature and for a time sufficient to produce ethanol. The invention also provides an integrated system for producing methanol and ethanol from syngas, the system comprising an atmosphere isolated from the ambient environment; a first catalyst to produce methanol from syngas wherein the first catalyst resides in the atmosphere; a second catalyst to product ethanol from methanol and syngas, wherein the second catalyst resides in the atmosphere; a conduit for introducing syngas to the atmosphere; and a device for removing ethanol from the atmosphere. The exothermicity of the method and system obviates the need for input of additional heat from outside the atmosphere.

  6. Cheap carbon sorbents produced from lignite by catalytic pyrolysis

    SciTech Connect (OSTI)

    Kuznetsov, B.N.; Schchipko, M.L.

    1995-12-01

    Some data are presented describing the new technology of carbon sorbent production from powdered lignite in the installation with fluidized bed of catalyst. It was shown the different types of char products with extended pore structure and high sorption ability can be produced from cheap and accessible lignite of Kansk-Achinsk coal pit in pilot installation with fluidized bed of Al-Cu-Cr oxide catalyst or catalytically active slag materials. In comparison with the conventional technologies of pyrolysis the catalytic pyrolysis allows to increase by 3-5 times the process productivity and to decrease significantly the formation of harmful compounds. The latter is accomplished by complete oxidation of gaseous pyrolysis products in the presence of catalysts and by avoiding the formation of pyrolysis tars - the source of cancerogenic compounds. The technology of cheap powdered sorbent production from lignites makes possible to obtain from lignite during the time of pyrolysis only a few seconds char products with porosity up to 0.6 cm{sup 3} /g, and specific surface area more than 400 m{sup 3} /g. Some methods of powdered chars molding into carbon materials with the different shape were proved for producing of firmness sorbents. Cheap carbon sorbents obtained by thermocatalytic pyrolysis can be successfully used in purification of different industrial pollutants as one-time sorbent or as adsorbents of long-term application with periodic regeneration.

  7. Fracture characteristics and their relationships to producing...

    Open Energy Info (EERE)

    characteristics and their relationships to producing zones in deep wells, Raft River geothermal area Jump to: navigation, search OpenEI Reference LibraryAdd to library Book:...

  8. California: Agricultural Residues Produce Renewable Fuel | Department...

    Broader source: Energy.gov (indexed) [DOE]

    technology is expected to produce biofuel that reduces greenhouse gas emissions by 80% compared to fossil fuel and help make California a leader in advanced biofuel production. ...

  9. Tribal Utility Formation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    I L L E P O W E R A D M I N I S T R A T I O N Tribal Utility Formation in the Bonneville Power Administration Service Territory Ken Johnston Acting Tribal Affairs Manager BPA TRIBAL AFFAIRS DEPARTMENT JULY 2015 B O N N E V I L L E P O W E R A D M I N I S T R A T I O N 2 The Basics  BPA markets power from 31 Federal dams, the Columbia Generating Station Nuclear Plant, and several small non- Federal power plants  About 80% of the power BPA sells is hydroelectric  BPA accounts for about

  10. Stable, fertile, high polyhydroxyalkanoate producing plants and methods of producing them

    DOE Patents [OSTI]

    Bohmert-Tatarev, Karen; McAvoy, Susan; Peoples, Oliver P.; Snell, Kristi D.

    2015-08-04

    Transgenic plants that produce high levels of polyhydroxybutyrate and methods of producing them are provided. In a preferred embodiment the transgenic plants are produced using plastid transformation technologies and utilize genes which are codon optimized. Stably transformed plants able to produce greater than 10% dwt PHS in tissues are also provided.

  11. Nanodot formation induced by femtosecond laser irradiation

    SciTech Connect (OSTI)

    Abere, M. J.; Kang, M.; Goldman, R. S.; Yalisove, S. M. [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Chen, C. [Applied Physics Program, University of Michigan, Ann Arbor, Michigan 48109 (United States); Rittman, D. R. [Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, Michigan 48109 (United States); Phillips, J. D. [Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, Michigan 48109 (United States); Torralva, B. [Department of Atmospheric, Oceanic, and Space Sciences, University of Michigan, Ann Arbor, Michigan 48109 (United States)

    2014-10-20

    The femtosecond laser generation of ZnSe nanoscale features on ZnSe surfaces was studied. Irradiation with multiple exposures produces 10100?nm agglomerations of nanocrystalline ZnSe while retaining the original single crystal structure of the underlying material. The structure of these nanodots was verified using a combination of scanning transmission electron microscopy, scanning electron microscopy, and atomic force microscopy. The nanodots continue to grow hours after irradiation through a combination of bulk and surface diffusion. We suggest that in nanodot formation the result of ultrafast laser induced point defect formation is more than an order of magnitude below the ZnSe ultrafast melt threshold fluence. This unique mechanism of point defect injection will be discussed.

  12. Method for producing microporous metal bodies

    DOE Patents [OSTI]

    Danko, Joseph C.

    1982-01-01

    Tungsten is vapor-deposited by hydrogen reduction of tungsten hexafluoride (WF.sub.6) to produce a tungsten body having from 40 to 100 ppm fluorine. The tungsten is then heated under vacuum to produce grain boundary porosity for a sufficient period of time to allow the pores along the grain boundaries to become interconnected.

  13. Novel alkyd-type coating resins produced using cationic polymerization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chisholm, Bret J.; Kalita, Harjyoti; Alam, Samim; Jayasooriyamu, Anurad; Fernando, Shashi; Samanata, Satyabrata; Bahr, James; Selvakumar, Sermadurai; Sibi, Mukund; Vold, Jessica; et al

    2015-05-06

    Novel, partially bio-based poly(vinyl ether) copolymers derived from soybean oil and cyclohexyl vinyl ether (CHVE) were produced by cationic polymerization and investigated for application as alkyd-type surface coatings. Compared to conventional alkyd resins, which are produced by high temperature melt condensation polymerization, the poly(v9nyl ether)s provide several advantages. These advantages include milder, more energy efficient polymer synthesis, elimination of issues associated with gelation during polymer synthesis, production of polymers with well-defined composition and relatively narrow molecular weight distribution, and elimination of film formation and physical property issues associated with entrained monomers, dimers, trimers, etc. The results of the studied showedmore » that the thermal, mechanical, and physical properties of the coatings produced from these novel polymers varied considerably as a function of polymer composition and cure temperature. Overall, the results suggest a good potential for these novel copolymers to be used for coatings cured by autoxidation.« less

  14. RAPID DUST FORMATION IN NOVAE: THE SPEED CLASSFORMATION TIMESCALE CORRELATION EXPLAINED

    SciTech Connect (OSTI)

    Williams, S. C.; Bode, M. F.; Darnley, M. J.; Evans, A.; Zubko, V.; Shafter, A. W.

    2013-11-10

    Observations show that the time of onset of dust formation in classical novae depends strongly on their speed class, with dust typically taking longer to form in slower novae. Using empirical relationships between speed class, luminosity and ejection velocity, it can be shown that dust formation timescale is expected to be essentially independent of speed class. However, following a nova outburst the spectrum of the central hot source evolves, with an increasing proportion of the radiation being emitted short-ward of the Lyman limit. The rate at which the spectrum evolves also depends on the speed class. We have therefore refined the simple model by assuming photons at energies higher than the Lyman limit are absorbed by neutral hydrogen gas internal to the dust formation sites, therefore preventing these photons reaching the nucleation sites. With this refinement the dust formation timescale is theoretically dependent on speed class and the results of our theoretical modification agree well with the observational data. We consider two types of carbon-based dust, graphite and amorphous carbon, with both types producing similar relationships. Our results can be used to predict when dust will form in a nova of a given speed class and hence when observations should optimally be taken to detect the onset of dust formation.

  15. Method for producing uranium atomic beam source

    DOE Patents [OSTI]

    Krikorian, Oscar H.

    1976-06-15

    A method for producing a beam of neutral uranium atoms is obtained by vaporizing uranium from a compound UM.sub.x heated to produce U vapor from an M boat or from some other suitable refractory container such as a tungsten boat, where M is a metal whose vapor pressure is negligible compared to that of uranium at the vaporization temperature. The compound, for example, may be the uranium-rhenium compound, URe.sub.2. An evaporation rate in excess of about 10 times that of conventional uranium beam sources is produced.

  16. APPARATUS FOR PRODUCING AND MANIPULATING PLASMAS

    DOE Patents [OSTI]

    Colgate, S.A.; Ferguson, J.P.; Furth, H.P.; Wright, R.E.

    1960-07-26

    An electrical pinch discharge apparatus is described for producing and manipulating high-temperature plasmas. The apparatus may be of either the linear or toroidal pinch discharge type. Arrangements are provided whereby stabilizing fields may be trapped in the plasma external to the main pinch discharge path and the boundary condition of the stabilizing field programed so as to stabilize the discharge or to promote instabilities in the discharge as desired. The produced plasmas may be employed for various purposes, and fusion neutrons have been produced with the apparatus.

  17. Producing X-rays at the APS

    ScienceCinema (OSTI)

    None

    2013-04-19

    An introduction and overview of the Advanced Photon Source at Argonne National Laboratory, the technology that produces the brightest X-ray beams in the Western Hemisphere, and the research carried out by scientists using those X-rays.

  18. Methods of producing compounds from plant materials

    DOE Patents [OSTI]

    Werpy, Todd A.; Schmidt, Andrew J.; Frye, Jr., John G.; Zacher, Alan H. , Franz; James A. , Alnajjar; Mikhail S. , Neuenschwander; Gary G. , Alderson; Eric V. , Orth; Rick J. , Abbas; Charles A. , Beery; Kyle E. , Rammelsberg; Anne M. , Kim; Catherine J.

    2010-01-26

    The invention includes methods of processing plant material by adding water to form a mixture, heating the mixture, and separating a liquid component from a solid-comprising component. At least one of the liquid component and the solid-comprising component undergoes additional processing. Processing of the solid-comprising component produces oils, and processing of the liquid component produces one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention includes a process of forming glycerol, ethylene glycol, lactic acid and propylene glycol from plant matter by adding water, heating and filtering the plant matter. The filtrate containing starch, starch fragments, hemicellulose and fragments of hemicellulose is treated to form linear poly-alcohols which are then cleaved to produce one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention also includes a method of producing free and/or complexed sterols and stanols from plant material.

  19. Methods of producing compounds from plant material

    DOE Patents [OSTI]

    Werpy, Todd A.; Schmidt, Andrew J.; Frye, Jr., John G.; Zacher, Alan H.; Franz, James A.; Alnajjar, Mikhail S.; Neuenschwander, Gary G.; Alderson, Eric V.; Orth, Rick J.; Abbas, Charles A.; Beery, Kyle E.; Rammelsberg, Anne M.; Kim, Catherine J.

    2006-01-03

    The invention includes methods of processing plant material by adding water to form a mixture, heating the mixture, and separating a liquid component from a solid-comprising component. At least one of the liquid component and the solid-comprising component undergoes additional processing. Processing of the solid-comprising component produces oils, and processing of the liquid component produces one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention includes a process of forming glycerol, ethylene glycol, lactic acid and propylene glycol from plant matter by adding water, heating and filtering the plant matter. The filtrate containing starch, starch fragments, hemicellulose and fragments of hemicellulose is treated to form linear poly-alcohols which are then cleaved to produce one or more of glycerol, ethylene glycol, lactic acid and propylene glycol. The invention also includes a method of producing free and/or complexed sterols and stanols from plant material.

  20. Methods and systems for producing syngas

    DOE Patents [OSTI]

    Hawkes, Grant L; O'Brien, James E; Stoots, Carl M; Herring, J. Stephen; McKellar, Michael G; Wood, Richard A; Carrington, Robert A; Boardman, Richard D

    2013-02-05

    Methods and systems are provided for producing syngas utilizing heat from thermochemical conversion of a carbonaceous fuel to support decomposition of at least one of water and carbon dioxide using one or more solid-oxide electrolysis cells. Simultaneous decomposition of carbon dioxide and water or steam by one or more solid-oxide electrolysis cells may be employed to produce hydrogen and carbon monoxide. A portion of oxygen produced from at least one of water and carbon dioxide using one or more solid-oxide electrolysis cells is fed at a controlled flow rate in a gasifier or combustor to oxidize the carbonaceous fuel to control the carbon dioxide to carbon monoxide ratio produced.

  1. California: Agricultural Residues Produce Renewable Fuel

    Broader source: Energy.gov [DOE]

    Logos Technologies and EERE are partnering with Edeniq of Visalia to build a plant that will produce cellulosic ethanol from switchgrass, wood chips, and corn leaves, stalks, and husks--all plentiful, nonfood feedstock sources in California.

  2. Produced Water Management and Beneficial Use

    SciTech Connect (OSTI)

    Terry Brown; Carol Frost; Thomas Hayes; Leo Heath; Drew Johnson; David Lopez; Demian Saffer; Michael Urynowicz; John Wheaton; Mark Zoback

    2007-10-31

    Large quantities of water are associated with the production of coalbed methane (CBM) in the Powder River Basin (PRB) of Wyoming. The chemistry of co-produced water often makes it unsuitable for subsequent uses such as irrigated agriculture. However, co-produced waters have substantial potential for a variety of beneficial uses. Achieving this potential requires the development of appropriate water management strategies. There are several unique characteristics of co-produced water that make development of such management strategies a challenge. The production of CBM water follows an inverse pattern compared to traditional wells. CBM wells need to maintain low reservoir pressures to promote gas production. This need renders the reinjection of co-produced waters counterproductive. The unique water chemistry of co-produced water can reduce soil permeability, making surface disposal difficult. Unlike traditional petroleum operations where co-produced water is an undesirable by-product, co-produced water in the PRB often is potable, making it a highly valued resource in arid western states. This research project developed and evaluated a number of water management options potentially available to CBM operators. These options, which focus on cost-effective and environmentally-sound practices, fall into five topic areas: Minimization of Produced Water, Surface Disposal, Beneficial Use, Disposal by Injection and Water Treatment. The research project was managed by the Colorado Energy Research Institute (CERI) at the Colorado School of Mines (CSM) and involved personnel located at CERI, CSM, Stanford University, Pennsylvania State University, the University of Wyoming, the Argonne National Laboratory, the Gas Technology Institute, the Montana Bureau of Mining and Geology and PVES Inc., a private firm.

  3. Method of producing amorphous thin films

    DOE Patents [OSTI]

    Brusasco, Raymond M.

    1992-01-01

    Disclosed is a method of producing thin films by sintering which comprises: a. coating a substrate with a thin film of an inorganic glass forming parulate material possessing the capability of being sintered, and b. irridiating said thin film of said particulate material with a laser beam of sufficient power to cause sintering of said material below the temperature of liquidus thereof. Also disclosed is the article produced by the method claimed.

  4. Could Aluminum Nitride Produce Quantum Bits?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home » News & Publications » News » Science News » Could Aluminum Nitride Produce Quantum Bits? Could Aluminum Nitride Produce Quantum Bits? After running simulations at NERSC researchers believe it's possible May 2, 2016 Linda Vu, lvu@lbl.gov, 510.495.2402 Graphical Abstract AlN Sci Rep no logo cropped This graphic illustrates an engineered nitrogen vacancy in aluminum nitride. Quantum computers have the potential to break common cryptography techniques, search huge datasets and

  5. Water management practices used by Fayetteville shale gas producers.

    SciTech Connect (OSTI)

    Veil, J. A.

    2011-06-03

    Water issues continue to play an important role in producing natural gas from shale formations. This report examines water issues relating to shale gas production in the Fayetteville Shale. In particular, the report focuses on how gas producers obtain water supplies used for drilling and hydraulically fracturing wells, how that water is transported to the well sites and stored, and how the wastewater from the wells (flowback and produced water) is managed. Last year, Argonne National Laboratory made a similar evaluation of water issues in the Marcellus Shale (Veil 2010). Gas production in the Marcellus Shale involves at least three states, many oil and gas operators, and multiple wastewater management options. Consequently, Veil (2010) provided extensive information on water. This current study is less complicated for several reasons: (1) gas production in the Fayetteville Shale is somewhat more mature and stable than production in the Marcellus Shale; (2) the Fayetteville Shale underlies a single state (Arkansas); (3) there are only a few gas producers that operate the large majority of the wells in the Fayetteville Shale; (4) much of the water management information relating to the Marcellus Shale also applies to the Fayetteville Shale, therefore, it can be referenced from Veil (2010) rather than being recreated here; and (5) the author has previously published a report on the Fayetteville Shale (Veil 2007) and has helped to develop an informational website on the Fayetteville Shale (Argonne and University of Arkansas 2008), both of these sources, which are relevant to the subject of this report, are cited as references.

  6. Help:Formatting | Open Energy Information

    Open Energy Info (EERE)

    it in two single quotes like ''this'' Contents 1 Text formatting markup 2 Paragraphs 3 HTML 4 Other formatting Text formatting markup Description You type You get character...

  7. Method and system for producing metallic iron nuggets

    SciTech Connect (OSTI)

    Iwasaki, Iwao; Kiesel, Richard F.; Englund, David J; Hendrickson, Dave

    2012-12-18

    A method and system for producing metallic iron nuggets may include providing multiple layers of agglomerates, such as briquettes, balls and extrusions, of a reducible mixture of reducing material (such as carbonaceous material) and of a reducible iron bearing material (such as iron oxide) on a hearth material layer (such as carbonaceous material) and providing a coarse overlayer of carbonaceous material over at least some of the agglomerates. Heating the agglomerates of reducible mixture to 1425.degree. C. or 1400.degree. C. or 1375.degree. C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.

  8. Method and system for producing metallic iron nuggets

    DOE Patents [OSTI]

    Iwasaki, Iwao; Lindgren, Andrew J.; Kiesel, Richard F.

    2013-06-25

    Method and system for producing metallic nuggets includes providing reducible mixture of reducing material (such as carbonaceous material) and reducible iron bearing material (such as iron oxide) that may be arranged in discrete portions, such as mounds or briquettes, on at least a portion of a hearth material layer (such as carbonaceous material). A coarse overlayer of carbonaceous material may be provided over at least some of the discrete portions. Heating the reducible mixture to 1425.degree. C. or 1400.degree. C. or 1375.degree. C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.

  9. ANAEROBIC BIOLOGICAL TREATMENT OF PRODUCED WATER

    SciTech Connect (OSTI)

    John R. Gallagher

    2001-07-31

    During the production of oil and gas, large amounts of water are brought to the surface and must be disposed of in an environmentally sensitive manner. This is an especially difficult problem in offshore production facilities where space is a major constraint. The chief regulatory criterion for produced water is oil and grease. Most facilities have little trouble meeting this criterion using conventional oil-water separation technologies. However, some operations have significant amounts of naphthenic acids in the water that behave as oil and grease but are not well removed by conventional technologies. Aerobic biological treatment of naphthenic acids in simulated-produced water has been demonstrated by others; however, the system was easily overloaded by the large amounts of low-molecular-weight organic acids often found in produced waters. The objective of this research was to determine the ability of an anaerobic biological system to treat these organic acids in a simulated produced water and to examine the potential for biodegradation of the naphthenic acids in the anaerobic environment. A small fixed-film anaerobic biological reactor was constructed and adapted to treat a simulated produced water. The bioreactor was tubular, with a low-density porous glass packing material. The inocula to the reactor was sediment from a produced-water holding pond from a municipal anaerobic digester and two salt-loving methanogenic bacteria. During start-up, the feed to the reactor contained glucose as well as typical produced-water components. When glucose was used, rapid gas production was observed. However, when glucose was eliminated and the major organic component was acetate, little gas was generated. Methane production from acetate may have been inhibited by the high salt concentrations, by sulfide, or because of the lack, despite seeding, of microbes capable of converting acetate to methane. Toluene, a minor component of the produced water (0.1 g/L) was removed in the

  10. Formatting PDFs for the Web

    Office of Energy Efficiency and Renewable Energy (EERE)

    After you've created or have a PDF, follow these steps to format it according to Office of Energy Efficiency and Renewable Energy (EERE) standards.

  11. A hybrid ED/RO process for TDS reduction of produced waters

    SciTech Connect (OSTI)

    Tsai, S.P.; Datta, R.; Frank, J.R.

    1995-12-31

    Large volumes of produced waters are generated from natural gas production. In the United States the prevailing management practice for produced waters is deep well injection, but this practice is costly. Therefore minimizing the need for deep well injection is desirable. A major treatment issue for produced waters is the reduction of total dissolved solids (TDS), which consist mostly of inorganic salts. A hybrid electrodialysis/reverse-osmosis (ED/RO) treatment process is being developed to concentrate the salts in produced waters and thereby reduce the volume of brine that needs to be managed for disposal. The desalted water can be used beneficially or discharged. In this study, laboratory feasibility experiments were conducted by using produced waters from multiple sites. A novel-membrane configuration approach to prevent fouling and scale formation was developed and demonstrated. Results of laboratory experiments and plans for field demonstration are discussed.

  12. APPARATUS FOR PRODUCING IONS OF VAPORIZABLE MATERIALS

    DOE Patents [OSTI]

    Wright, B.T.

    1958-01-28

    a uniform and copious supply of ions. The source comprises a hollow arc- block and means for establishing a magnetic field through the arc-block. Vaporization of the material to be ionized is produced by an electric heated filament. The arc producing structure within the arc-block consists of a cathode disposed between a pair of collimating electrodes along with an anode adjacent each collimating electrode on the side opposite the cathode. A positive potential applied to the anodes and collimating electrodes, with respect to the cathode, and the magnetic field act to accelerate the electrons from the cathode through a slit in each collimating clectrode towards the respective anode. In this manner a pair of collinear arc discharges are produced in the gas region which can be tapped for an abundant supply of ions of the material being analyzed.

  13. Characterization of Soluble Organics in Produced Water

    SciTech Connect (OSTI)

    Bostick, D.T.

    2002-01-16

    Soluble organics in produced water and refinery effluents represent treatment problems for the petroleum industry. Neither the chemistry involved in the production of soluble organics nor the impact of these chemicals on total effluent toxicity is well understood. The U.S. Department of Energy provides funding for Oak Ridge National Laboratory (ORNL) to support a collaborative project with Shell, Chevron, Phillips, and Statoil entitled ''Petroleum and Environmental Research Forum project (PERF 9844: Manage Water-Soluble Organics in Produced Water''). The goal of this project, which involves characterization and evaluation of these water-soluble compounds, is aimed at reducing the future production of such contaminants. To determine the effect that various drilling conditions might have on water-soluble organics (WSO) content in produced water, a simulated brine water containing the principal inorganic components normally found in Gulf of Mexico (GOM) brine sources was prepared. The GOM simulant was then contacted with as-received crude oil from a deep well site to study the effects of water cut, produced-water pH, salinity, pressure, temperature, and crude oil sources on the type and content of the WSO in produced water. The identities of individual semivolatile organic compounds (SVOCs) were determined in all as-received crude and actual produced water samples using standard USEPA Method (8270C) protocol. These analyses were supplemented with the more general measurements of total petroleum hydrocarbon (TPH) content in the gas (C{sub 6}-C{sub 10}), diesel (C{sub 10}-C{sub 20}), and oil (C{sub 20}-C{sub 28}) carbon ranges as determined by both gas chromatographic (GC) and infrared (IR) analyses. An open liquid chromatographic procedure was also used to differentiate the saturated hydrocarbon, aromatic hydrocarbon, and polar components within the extractable TPH. Inorganic constituents in the produced water were analyzed by ion-selective electrodes and inductively

  14. CLUSTERS OF SMALL ERUPTIVE FLARES PRODUCED BY MAGNETIC RECONNECTION IN THE SUN

    SciTech Connect (OSTI)

    Archontis, V.; Hansteen, V.

    2014-06-10

    We report on the formation of small solar flares produced by patchy magnetic reconnection between interacting magnetic loops. A three-dimensional (3D) magnetohydrodynamic (MHD) numerical experiment was performed, where a uniform magnetic flux sheet was injected into a fully developed convective layer. The gradual emergence of the field into the solar atmosphere results in a network of magnetic loops, which interact dynamically forming current layers at their interfaces. The formation and ejection of plasmoids out of the current layers leads to patchy reconnection and the spontaneous formation of several small (size ?1-2 Mm) flares. We find that these flares are short-lived (30 s3 minutes) bursts of energy in the range O(10{sup 25}-10{sup 27}) erg, which is basically the nanoflare-microflare range. Their persistent formation and co-operative action and evolution leads to recurrent emission of fast EUV/X-ray jets and considerable plasma heating in the active corona.

  15. Methods for producing silicon carbide fibers

    DOE Patents [OSTI]

    Garnier, John E.; Griffith, George W.

    2016-03-01

    Methods of producing silicon carbide fibers. The method comprises reacting a continuous carbon fiber material and a silicon-containing gas in a reaction chamber at a temperature ranging from approximately 1500.degree. C. to approximately 2000.degree. C. A partial pressure of oxygen in the reaction chamber is maintained at less than approximately 1.01.times.10.sup.2 Pascal to produce continuous alpha silicon carbide fibers. Continuous alpha silicon carbide fibers and articles formed from the continuous alpha silicon carbide fibers are also disclosed.

  16. Method for producing small hollow spheres

    DOE Patents [OSTI]

    Hendricks, C.D.

    1979-01-09

    Method is disclosed for producing small hollow spheres of glass, metal or plastic, wherein the sphere material is mixed with or contains as part of the composition a blowing agent which decomposes at high temperature (T [approx gt] 600 C). As the temperature is quickly raised, the blowing agent decomposes and the resulting gas expands from within, thus forming a hollow sphere of controllable thickness. The thus produced hollow spheres (20 to 10[sup 3] [mu]m) have a variety of application, and are particularly useful in the fabrication of targets for laser implosion such as neutron sources, laser fusion physics studies, and laser initiated fusion power plants. 1 fig.

  17. Methods for producing reinforced carbon nanotubes

    DOE Patents [OSTI]

    Ren, Zhifen; Wen, Jian Guo; Lao, Jing Y.; Li, Wenzhi

    2008-10-28

    Methods for producing reinforced carbon nanotubes having a plurality of microparticulate carbide or oxide materials formed substantially on the surface of such reinforced carbon nanotubes composite materials are disclosed. In particular, the present invention provides reinforced carbon nanotubes (CNTs) having a plurality of boron carbide nanolumps formed substantially on a surface of the reinforced CNTs that provide a reinforcing effect on CNTs, enabling their use as effective reinforcing fillers for matrix materials to give high-strength composites. The present invention also provides methods for producing such carbide reinforced CNTs.

  18. Method for producing small hollow spheres

    DOE Patents [OSTI]

    Hendricks, Charles D. [Livermore, CA

    1979-01-09

    Method for producing small hollow spheres of glass, metal or plastic, wherein the sphere material is mixed with or contains as part of the composition a blowing agent which decomposes at high temperature (T .gtorsim. 600.degree. C). As the temperature is quickly raised, the blowing agent decomposes and the resulting gas expands from within, thus forming a hollow sphere of controllable thickness. The thus produced hollow spheres (20 to 10.sup.3 .mu.m) have a variety of application, and are particularly useful in the fabrication of targets for laser implosion such as neutron sources, laser fusion physics studies, and laser initiated fusion power plants.

  19. Method of producing a high pressure gas

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Zollinger, William T.

    2006-07-18

    A method of producing a high pressure gas is disclosed and which includes providing a container; supplying the container with a liquid such as water; increasing the pressure of the liquid within the container; supplying a reactant composition such as a chemical hydride to the liquid under pressure in the container and which chemically reacts with the liquid to produce a resulting high pressure gas such as hydrogen at a pressure of greater than about 100 pounds per square inch of pressure; and drawing the resulting high pressure gas from the container.

  20. Collisionless Weibel shocks: Full formation mechanism and timing

    SciTech Connect (OSTI)

    Bret, A. [ETSI Industriales, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain); Instituto de Investigaciones Energticas y Aplicaciones Industriales, Campus Universitario de Ciudad Real, 13071 Ciudad Real (Spain); Stockem, A. [GoLP/Instituto de Plasmas e Fuso Nuclear, Instituto Superior Tcnico, Universidade de Lisboa, Lisbon (Portugal); Institut fr Theoretische Physik, Lehrstuhl IV: Weltraum- und Astrophysik, Ruhr-Universitt Bochum, D-44780 Bochum (Germany); Narayan, R. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, MS-51 Cambridge, Massachusetts 02138 (United States); Silva, L. O. [GoLP/Instituto de Plasmas e Fuso Nuclear, Instituto Superior Tcnico, Universidade de Lisboa, Lisbon (Portugal)

    2014-07-15

    Collisionless shocks in plasmas play an important role in space physics (Earth's bow shock) and astrophysics (supernova remnants, relativistic jets, gamma-ray bursts, high energy cosmic rays). While the formation of a fluid shock through the steepening of a large amplitude sound wave has been understood for long, there is currently no detailed picture of the mechanism responsible for the formation of a collisionless shock. We unravel the physical mechanism at work and show that an electromagnetic Weibel shock always forms when two relativistic collisionless, initially unmagnetized, plasma shells encounter. The predicted shock formation time is in good agreement with 2D and 3D particle-in-cell simulations of counterstreaming pair plasmas. By predicting the shock formation time, experimental setups aiming at producing such shocks can be optimised to favourable conditions.

  1. Produce through coiled tubing to keep marginal wells unloaded

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    The use of coiled tubing as an alternate production tubing string has been attempted or considered by numerous operators in the past. However, its use has been tempered due to several problems known to be inherent with coiled tubing recompletions. Some of the problems encountered are: Killing the well to allow for tubing installation always carries the risk of formation damage; Candidate wells normally are marginal producers and may not produce sufficient revenue to justify the cost of a major workover; Procedures followed to install surface equipment may be hazardous; Previous installation designs required running the coiled tubing to the top of the tree, affecting the functional loss of all existing wellhead equipment; Often substandard modifications were required to reconnect into existing production facilities. However, a prototype spool and tubing hanger that incorporated modifications designed to solve these problems has been developed jointly by Reeled Tubing, Inc., and Well-head Control Systems. The solution is a new concept in the coiled tubing hanger. The design incorporates a floating element, which is a combination slip bowl, seal element and retaining sub. The entire assembly is installed and activated in the bore of a specially designed spool installed between the primary and secondary master valves of the existing wellhead.

  2. Portable File Format (PFF) specifications.

    SciTech Connect (OSTI)

    Dolan, Daniel H.,

    2015-02-01

    Created at Sandia National Laboratories, the Portable File Format (PFF) allows binary data transfer across computer platforms. Although this capability is supported by many other formats, PFF files are still in use at Sandia, particularly in pulsed power research. This report provides detailed PFF specifications for accessing data without relying on legacy code.

  3. Spotlight on Austin, Texas: Best Offer Ever Produces Upgrades...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Best Offer Ever Produces Upgrades in Record Time Spotlight on Austin, Texas: Best Offer Ever Produces Upgrades in Record Time Spotlight on Austin, Texas: Best Offer Ever Produces ...

  4. United Wisconsin Grain Producers UWGP | Open Energy Information

    Open Energy Info (EERE)

    Name: United Wisconsin Grain Producers (UWGP) Place: Friesland, Wisconsin Product: Bioethanol producer using corn as feedstock References: United Wisconsin Grain Producers...

  5. Adaptive control system for gas producing wells

    SciTech Connect (OSTI)

    Fedor, Pashchenko; Sergey, Gulyaev; Alexander, Pashchenko

    2015-03-10

    Optimal adaptive automatic control system for gas producing wells cluster is proposed intended for solving the problem of stabilization of the output gas pressure in the cluster at conditions of changing gas flow rate and changing parameters of the wells themselves, providing the maximum high resource of hardware elements of automation.

  6. Producing dicarboxylic acids using polyketide synthases

    DOE Patents [OSTI]

    Katz, Leonard; Fortman, Jeffrey L; Keasling, Jay D

    2013-10-29

    The present invention provides for a polyketide synthase (PKS) capable of synthesizing a dicarboxylic acid (diacid). Such diacids include diketide-diacids and triketide-diacids. The invention includes recombinant nucleic acid encoding the PKS, and host cells comprising the PKS. The invention also includes methods for producing the diacids.

  7. Producing dicarboxylic acids using polyketide synthases

    DOE Patents [OSTI]

    Katz, Leonard; Fortman, Jeffrey L.; Keasling, Jay D.

    2015-05-26

    The present invention provides for a polyketide synthase (PKS) capable of synthesizing a dicarboxylic acid (diacid). Such diacids include diketide-diacids and triketide-diacids. The invention includes recombinant nucleic acid encoding the PKS, and host cells comprising the PKS. The invention also includes methods for producing the diacids.

  8. Performance Profiles of Major Energy Producers

    Reports and Publications (EIA)

    2011-01-01

    The information and analyses in Performance Profiles of Major Energy Producers is intended to provide a critical review, and promote an understanding, of the possible motivations and apparent consequences of investment decisions made by some of the largest corporations in the energy industry.

  9. RANDOM PULSE GENERATOR PRODUCING FIDUCIAL MARKS

    DOE Patents [OSTI]

    Nielsen, W.F.

    1960-02-01

    The apparatus for automatically applying a fiducial marking, having a nonrepetitive pattern, to a plurality of simultaneously made records comprises, in series, a bypass filter, a trigger circuit, and a pulse generator, with printing means connected to and controlled by the pulse generator for simultaneously making the visible fiducial marks on a plurality of simultaneously produced records.

  10. Methods of producing continuous boron carbide fibers

    SciTech Connect (OSTI)

    Garnier, John E.; Griffith, George W.

    2015-12-01

    Methods of producing continuous boron carbide fibers. The method comprises reacting a continuous carbon fiber material and a boron oxide gas within a temperature range of from approximately 1400.degree. C. to approximately 2200.degree. C. Continuous boron carbide fibers, continuous fibers comprising boron carbide, and articles including at least a boron carbide coating are also disclosed.

  11. Method of producing a chemical hydride

    DOE Patents [OSTI]

    Klingler, Kerry M.; Zollinger, William T.; Wilding, Bruce M.; Bingham, Dennis N.; Wendt, Kraig M.

    2007-11-13

    A method of producing a chemical hydride is described and which includes selecting a composition having chemical bonds and which is capable of forming a chemical hydride; providing a source of a hydrocarbon; and reacting the composition with the source of the hydrocarbon to generate a chemical hydride.

  12. Process for producing fluid fuel from coal

    DOE Patents [OSTI]

    Hyde, Richard W.; Reber, Stephen A.; Schutte, August H.; Nadkarni, Ravindra M.

    1977-01-01

    Process for producing fluid fuel from coal. Moisture-free coal in particulate form is slurried with a hydrogen-donor solvent and the heated slurry is charged into a drum wherein the pressure is so regulated as to maintain a portion of the solvent in liquid form. During extraction of the hydrocarbons from the coal, additional solvent is added to agitate the drum mass and keep it up to temperature. Subsequently, the pressure is released to vaporize the solvent and at least a portion of the hydrocarbons extracted. The temperature of the mass in the drum is then raised under conditions required to crack the hydrocarbons in the drum and to produce, after subsequent stripping, a solid coke residue. The hydrocarbon products are removed and fractionated into several cuts, one of which is hydrotreated to form the required hydrogen-donor solvent while other fractions can be hydrotreated or hydrocracked to produce a synthetic crude product. The heaviest fraction can be used to produce ash-free coke especially adapted for hydrogen manufacture. The process can be made self-sufficient in hydrogen and furnishes as a by-product a solid carbonaceous material with a useful heating value.

  13. Beneficial Reuse of San Ardo Produced Water

    SciTech Connect (OSTI)

    Robert A. Liske

    2006-07-31

    This DOE funded study was performed to evaluate the potential for treatment and beneficial reuse of produced water from the San Ardo oilfield in Monterey County, CA. The potential benefits of a successful full-scale implementation of this project include improvements in oil production efficiency and additional recoverable oil reserves as well as the addition of a new reclaimed water resource. The overall project was conducted in two Phases. Phase I identified and evaluated potential end uses for the treated produced water, established treated water quality objectives, reviewed regulations related to treatment, transport, storage and use of the treated produced water, and investigated various water treatment technology options. Phase II involved the construction and operation of a small-scale water treatment pilot facility to evaluate the process's performance on produced water from the San Ardo oilfield. Cost estimates for a potential full-scale facility were also developed. Potential end uses identified for the treated water include (1) agricultural use near the oilfield, (2) use by Monterey County Water Resources Agency (MCWRA) for the Salinas Valley Water Project or Castroville Seawater Intrusion Project, (3) industrial or power plant use in King City, and (4) use for wetlands creation in the Salinas Basin. All of these uses were found to have major obstacles that prevent full-scale implementation. An additional option for potential reuse of the treated produced water was subsequently identified. That option involves using the treated produced water to recharge groundwater in the vicinity of the oil field. The recharge option may avoid the limitations that the other reuse options face. The water treatment pilot process utilized: (1) warm precipitation softening to remove hardness and silica, (2) evaporative cooling to meet downstream temperature limitations and facilitate removal of ammonia, and (3) reverse osmosis (RO) for removal of dissolved salts, boron, and

  14. Characterization of aerosols produced by surgical procedures

    SciTech Connect (OSTI)

    Yeh, H.C.; Muggenburg, B.A.; Lundgren, D.L.; Guilmette, R.A.; Snipes, M.B.; Jones, R.K.; Turner, R.S.

    1994-07-01

    In many surgeries, especially orthopedic procedures, power tools such as saws and drills are used. These tools may produce aerosolized blood and other biological material from bone and soft tissues. Surgical lasers and electrocautery tools can also produce aerosols when tissues are vaporized and condensed. Studies have been reported in the literature concerning production of aerosols during surgery, and some of these aerosols may contain infectious material. Garden et al. (1988) reported the presence of papilloma virus DNA in the fumes produced from laser surgery, but the infectivity of the aerosol was not assessed. Moon and Nininger (1989) measured the size distribution and production rate of emissions from laser surgery and found that particles were generally less than 0.5 {mu}m diameter. More recently there has been concern expressed over the production of aerosolized blood during surgical procedures that require power tools. In an in vitro study, the production of an aerosol containing the human immunodeficiency virus (HIV) was reported when power tools were used to cut tissues with blood infected with HIV. Another study measured the size distribution of blood aerosols produced by surgical power tools and found blood-containing particles in a number of size ranges. Health care workers are anxious and concerned about whether surgically produced aerosols are inspirable and can contain viable pathogens such as HIV. Other pathogens such as hepatitis B virus (HBV) are also of concern. The Occupational Safety and Health funded a project at the National Institute for Inhalation Toxicology Research Institute to assess the extent of aerosolization of blood and other tissues during surgical procedures. This document reports details of the experimental and sampling approach, methods, analyses, and results on potential production of blood-associated aerosols from surgical procedures in the laboratory and in the hospital surgical suite.

  15. Controlling formation fines at their sources to maintain well productivity

    SciTech Connect (OSTI)

    Nguyen, P.D.; Weaver, J.D.; Rickman, R.D.; Dusterhoft, R.G.; Parker, M.A.

    2007-05-15

    Migration of formation fines has been shown to cause production decline in many wells. Despite the availability of new downhole tools for use in well stimulation and completion, the ability to sustain desired production levels is often plagued with fines migration problems. The solution to this problem is appropriate treatment to mitigate fines migration at its source. This paper describes the use of an ultra-thin tackifying agent (UTTA) for stabilizing fines in high-rate producing or injection wells. This UTTA is applied as part of an initial prepad in fracturing or gravel-packing operations, as a remedial treatment, or as a post-treatment following acid fracturing or matrix acidizing treatments. The primary purpose of UTTA application is to immobilize formation fines so that they will not detach, migrate with flowing fluids, plug the pore channels, and reduce the flow path permeability. Results of laboratory testing indicate that the UTTA system is applicable to most types of formation fines, including coals, sandstones, and carbonates. Once injected into the formation matrix or proppant pack, the UTTA forms a thin film on formation surfaces, encapsulating the fines. Capillary action helps pull the tackifier into the contact points, fixing the particulate in place without plugging the pore throat. The UTTA does not require a shut-in time after its application. The thin film tackifier does not harden, but remains flexible, enhancing the ability of a formation to withstand stress cycling and allowing the formation to handle high shear stress during high flow rates.

  16. Method of producing .sup.67 Cu

    DOE Patents [OSTI]

    O'Brien, Jr., Harold A.; Barnes, John W.; Taylor, Wayne A.; Thomas, Kenneth E.; Bentley, Glenn E.

    1984-01-01

    A method of producing carrier-free .sup.67 Cu by proton spallation combined with subsequent chemical separation and purification is disclosed. A target consisting essentially of pressed zinc oxide is irradiated with a high energy, high current proton beam to produce a variety of spallogenic nuclides, including .sup.67 Cu and other copper isotopes. The irradiated target is dissolved in a concentrated acid solution to which a palladium salt is added. In accordance with the preferred method, the spallogenic copper is twice coprecipitated with palladium, once with metallic zinc as the precipitating agent and once with hydrogen sulfide as the precipitating agent. The palladium/copper precipitate is then dissolved in an acid solution and the copper is separated from the palladium by liquid chromatography on an anion exchange resin.

  17. Method for producing /sup 67/Cu

    DOE Patents [OSTI]

    O'Brien, H.A. Jr.; Barnes, J.W.; Taylor, W.A.; Thomas, K.E.; Bentley, G.E.

    A method of producing carrier-free /sup 67/Cu by proton spallation combined with subsequent chemical separation and purification is disclosed. A target consisting essentially of pressed zinc oxide is irradiated with a high energy, high current proton beam to produce a variety of spallogenic nuclides, including /sup 67/Cu and other copper isotopes. The irradiated target is dissolved in a concentrated acid solution to which a palladium salt is added. In accordance with the preferred method, the spallogenic copper is twice coprecipitated with palladium, once with metallic zinc as the precipitating agent and once with hydrogen sulfide as the precipitating agent. The palladium/copper precipitate is then dissolved in an acid solution and the copper is separated from the palladium by liquid chromatography on an anion exchange resin.

  18. PROCESS FOR PRODUCING ALKYL ORTHOPHOSPHORIC ACID EXTRACTANTS

    DOE Patents [OSTI]

    Grinstead, R.R.

    1962-01-23

    A process is given for producing superior alkyl orthophosphoric acid extractants for use in solvent extraction methods to recover and purify various metals such as uranium and vanadium. The process comprises slurrying P/sub 2/O/ sub 5/ in a solvent diluent such as kerosene, benzene, isopropyl ether, and the like. An alipbatic alcohol having from nine to seventeen carbon atoms, and w- hcrein ihc OH group is situated inward of the terminal carbon atoms, is added to the slurry while the reaction temperature is mainiained below 60 deg C. The alcohol is added in the mole ratio of about 2 to l, alcohol to P/sub 2/O/sub 5/. A pyrophosphate reaotion product is formed in the slurry-alcohol mixture. Subsequently, the pyrophosphate reaction product is hydrolyzed with dilute mineral acid to produce the desired alkyl orthophosphoric aeid extractant. The extraetant may then be separated and utilized in metal-recovery, solvent- extraction processes. (AEC)

  19. Method of producing silicon carbide articles

    DOE Patents [OSTI]

    Milewski, John V.

    1985-01-01

    A method of producing articles comprising reaction-bonded silicon carbide (SiC) and graphite (and/or carbon) is given. The process converts the graphite (and/or carbon) in situ to SiC, thus providing the capability of economically obtaining articles made up wholly or partially of SiC having any size and shape in which graphite (and/or carbon) can be found or made. When the produced articles are made of an inner graphite (and/or carbon) substrate to which SiC is reaction bonded, these articles distinguish SiC-coated graphite articles found in the prior art by the feature of a strong bond having a gradual (as opposed to a sharply defined) interface which extends over a distance of mils. A method for forming SiC whisker-reinforced ceramic matrices is also given. The whisker-reinforced articles comprise SiC whiskers which substantially retain their structural integrity.

  20. Method for producing catalysts from coal

    DOE Patents [OSTI]

    Farcasiu, M.; Derbyshire, F.; Kaufman, P.B.; Jagtoyen, M.

    1998-02-24

    A method for producing catalysts from coal is provided comprising mixing an aqueous alkali solution with the coal, heating the aqueous mixture to treat the coal, drying the now-heated aqueous mixture, reheating the mixture to form carbonized material, cooling the mixture, removing excess alkali from the carbonized material, and recovering the carbonized material, wherein the entire process is carried out in controlled atmospheres, and the carbonized material is a hydrocracking or hydrodehalogenation catalyst for liquid phase reactions. The invention also provides for a one-step method for producing catalysts from coal comprising mixing an aqueous alkali solution with the coal to create a mixture, heating the aqueous mixture from an ambient temperature to a predetermined temperature at a predetermined rate, cooling the mixture, and washing the mixture to remove excess alkali from the treated and carbonized material, wherein the entire process is carried out in a controlled atmosphere. 1 fig.

  1. Method for producing catalysis from coal

    DOE Patents [OSTI]

    Farcasiu, Malvina; Derbyshire, Frank; Kaufman, Phillip B.; Jagtoyen, Marit

    1998-01-01

    A method for producing catalysts from coal is provided comprising mixing an aqueous alkali solution with the coal, heating the aqueous mixture to treat the coal, drying the now-heated aqueous mixture, reheating the mixture to form carbonized material, cooling the mixture, removing excess alkali from the carbonized material, and recovering the carbonized material, wherein the entire process is carried out in controlled atmospheres, and the carbonized material is a hydrocracking or hydrodehalogenation catalyst for liquid phase reactions. The invention also provides for a one-step method for producing catalysts from coal comprising mixing an aqueous alkali solution with the coal to create a mixture, heating the aqueous mixture from an ambient temperature to a predetermined temperature at a predetermined rate, cooling the mixture, and washing the mixture to remove excess alkali from the treated and carbonized material, wherein the entire process is carried out in a controlled atmosphere.

  2. Hydrogenase mimic produces hydrogen under the light

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Objective The Science Center Publications Graduate Research opportunities Undergraduate research opportunities EFRC-501 graduate class Seminar schedules Center News Research Highlights Center Research News Media about Center Center Video Library Bisfuel Picture Gallery Hydrogenase mimic produces hydrogen under the light 24 Jan 2013 Researchers from the laboratory of Giovanna Ghirlanda working on Subtask 3 (Fuel Production Complex) have achieved the synthesis of a peptide-based hydrogenase mimic

  3. Improved method for producing small hollow spheres

    DOE Patents [OSTI]

    Rosencwaig, A.; Koo, J.C.; Dressler, J.L.

    An improved method and apparatus for producing small hollow spheres of glass having an outer diameter ranging from about 100..mu.. to about 500..mu.. with a substantially uniform wall thickness in the range of about 0.5 to 20..mu.. are described. The method involves introducing aqueous droplets of a glass-forming solution into a long vertical drop oven or furnace having varying temperature regions.

  4. Process for producing furan from furfural aldehyde

    DOE Patents [OSTI]

    Diebold, J.P.; Evans, R.J.

    1987-04-06

    A process of producing furan and derivatives thereof as disclosed. The process includes generating furfural aldehyde vapors and then passing those vapors over a zeolite catalyst at a temperature and for a residence time effective to decarbonylate the furfural aldehydes to form furans and derivatives thereof. The resultant furan vapors and derivatives are then separated. In a preferred form, the furfural aldehyde vapors are generated during the process of converting biomass materials to liquid and gaseous fuels.

  5. Process for producing furan from furfural aldehyde

    DOE Patents [OSTI]

    Diebold, James P.; Evans, Robert J.

    1988-01-01

    A process of producing furan and derivatives thereof is disclosed. The process includes generating furfural aldehyde vapors and then passing those vapors over a zeolite catalyst at a temperature and for a residence time effective to decarbonylate the furfural aldehydes to form furans and derivatives thereof. The resultant furan vapors and derivatives are then separated. In a preferred form, the furfural aldehyde vapors are generated during the process of converting biomass materials to liquid and gaseous fuels.

  6. Method of producing encapsulated thermonuclear fuel particles

    DOE Patents [OSTI]

    Smith, Warren H.; Taylor, William L.; Turner, Harold L.

    1976-01-01

    A method of producing a fuel particle is disclosed, which comprises forming hollow spheroids which have a mass number greater than 50, immersing said spheroids while under the presence of pressure and heat in a gaseous atmosphere containing an isotope, such as deuterium and tritium, so as to diffuse the gas into the spheroid and thereafter cooling said spheroids up to about 77.degree. Kelvin to about 4.degree. Kelvin.

  7. Method and apparatus for producing cryogenic targets

    DOE Patents [OSTI]

    Murphy, J.T.; Miller, J.R.

    1984-08-07

    An improved method and apparatus are given for producing cryogenic inertially driven fusion targets in the fast isothermal freezing (FIF) method. Improved coupling efficiency and greater availability of volume near the target for diagnostic purposes and for fusion driver beam propagation result. Other embodiments include a new electrical switch and a new explosive detonator, all embodiments making use of a purposeful heating by means of optical fibers. 6 figs.

  8. Method and apparatus for producing cryogenic targets

    DOE Patents [OSTI]

    Murphy, James T.; Miller, John R.

    1984-01-01

    An improved method and apparatus are given for producing cryogenic inertially driven fusion targets in the fast isothermal freezing (FIF) method. Improved coupling efficiency and greater availability of volume near the target for diagnostic purposes and for fusion driver beam propagation result. Other embodiments include a new electrical switch and a new explosive detonator, all embodiments making use of a purposeful heating by means of optical fibers.

  9. Method of producing microchannel and nanochannel articles

    DOE Patents [OSTI]

    D'Urso, Brian R.

    2010-05-04

    A method of making an article having channels therethrough includes the steps of: providing a ductile structure defining at least one macro-channel, the macro-channel containing a salt; drawing the ductile structure in the axial direction of the at least one macro-channel to reduce diameter of the macro-channel; and contacting the salt with a solvent to dissolve the salt to produce an article having at least one microchannel.

  10. Scientists produce transparent, light-harvesting material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparent, light-harvesting material Scientists produce transparent, light-harvesting material The material could be used in development of transparent solar panels. November 3, 2010 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los Alamos National Laboratory sits on top of a