Sample records for ba sin uinta

  1. 05671_UintaWaterStudy | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water-Related Issues Affecting Conventional Oil and Gas Recovery and Potential Oil Shale Development in the Uinta Basin, Utah Last Reviewed 5152012 DE-NT0005671 Goal The goal of...

  2. Hydrotreating Uinta Basin bitumen-derived heavy oils

    SciTech Connect (OSTI)

    Longstaff, D.C.; Balaji, G.V.; Kim, J.W. [Univ. of Utah, Salt Lake City, UT (United States)] [and others

    1995-12-31T23:59:59.000Z

    Heavy oils derived from Uinta Basin bitumens have been hydrotreated under varying conditions. The process variables investigated included total reactor pressure (11.0-16.9 MPa), reactor temperature (616-711 K), feed rate (0.29-1.38 WHSV), and catalyst composition. The extent of heteroatom removal and residuum conversion were determined by the feed molecular weight and catalyst selection. Catalytic activity for heteroatom conversion removal was primarily influenced by metal loading. The heteroatom removal activity of the catalysts studied were ranked HDN catalysts > HDM catalysts > HDN-support. Catalytic activity for residuum conversion was influenced by both metal loading and catalyst surface area. The residuum conversion activity of HDN catalysts were always higher than the activity of HDM catalysts and HDN supports. The residuum conversion activity of HDN-supports surpassed the activity of HDM catalyst at higher temperatures. The conversions achieved with HDN catalysts relative to the HDM catalysts indicated that the low metals contents of the Uinta Basin bitumens obviate the need for hydrodemetallation as an initial upgrading step with these bitumens. The upgrading of Uinta Basin bitumens for integration into refinery feed slates should emphasize molecular weight and boiling range reduction first, followed by hydrotreating of the total liquid product produced in the pyrolysis process. Kinetics of residuum conversion can be modeled by invoking a consecutive-parallel mechanism in which native residuum in the feed is rapidly converted to volatile products and to product residuum. Deep conversion of residuum is only achieved when the more refractory product residuum is converted to volatile products.

  3. Western Gas Sands Project: production histories of the Piceance and Uinta basins of Colorado and Utah

    SciTech Connect (OSTI)

    Anderson, S.; Kohout, J. (comp.)

    1980-11-20T23:59:59.000Z

    Current United States geological tight sand designations in the Piceance and Uinta Basins' Western Gas Sands Project include the Mesaverde Group, Fort Union and Wasatch Formations. Others, such as the Dakota, Cedar Mountain, Morrison and Mancos may eventually be included. Future production from these formations will probably be closely associated with existing trends. Cumulative gas production through December 1979, of the Mesaverde Group, Fort Union and Wasatch Formations in the Piceance and Uinta Basins is less than 275 billion cubic feet. This contrasts dramatically with potential gas in place estimates of 360 trillion cubic feet. If the geology can be fully understood and engineering problems surmounted, significant potential reserves can be exploited.

  4. Primary oil-shale resources of the Green River Formation in the eastern Uinta Basin, Utah

    SciTech Connect (OSTI)

    Trudell, L.G.; Smith, J.W.; Beard, T.N.; Mason, G.M.

    1983-04-01T23:59:59.000Z

    Resources of potential oil in place in the Green River Formation are measured and estimated for the primary oil-shale resource area east of the Green River in Utah's Uinta Basin. The area evaluated (Ts 7-14 S, Rs 19-25 E) includes most of, and certainly the best of Utah's oil-shale resource. For resource evaluation the principal oil-shale section is divided into ten stratigraphic units which are equivalent to units previously evaluated in the Piceance Creek Basin of Colorado. Detailed evaluation of individual oil-shale units sampled by cores, plus estimates by extrapolation into uncored areas indicate a total resource of 214 billion barrels of shale oil in place in the eastern Uinta Basin.

  5. Reservoir Characterization of the Lower Green River Formation, Southwest Uinta Basin, Utah

    SciTech Connect (OSTI)

    Morgan, Craig D.; Chidsey, Jr., Thomas C.; McClure, Kevin P.; Bereskin, S. Robert; Deo, Milind D.

    2002-12-02T23:59:59.000Z

    The objectives of the study were to increase both primary and secondary hydrocarbon recovery through improved characterization (at the regional, unit, interwell, well, and microscopic scale) of fluvial-deltaic lacustrine reservoirs, thereby preventing premature abandonment of producing wells. The study will encourage exploration and establishment of additional water-flood units throughout the southwest region of the Uinta Basin, and other areas with production from fluvial-deltaic reservoirs.

  6. Characterization and interwell connectivity evaluation of Green Rver reservoirs, Wells Draw study area, Uinta Basin, Utah

    E-Print Network [OSTI]

    Abiazie, Joseph Uchechukwu

    2009-05-15T23:59:59.000Z

    and seal rocks of the Green River petroleum system. Datum is Mahoganey oil shale bed (1). 49 27 Fig. 11?Cross-section of thermal maturity of oil accumulations in the Green River petroleum system. 49 28 Fig. 12? Lake Uinta depositional... This petroleum system has produced more than 450 MMBO mainly from two formations, the Green River and Colton Formations. 7 The Green River Formation contains the source rock and most of the reservoir and seal rocks (Fig. 10). 49 Most of the kerogen-rich oil...

  7. RESERVOIR CHARACTERIZATION OF THE LOWER GREEN RIVER FORMATION, SOUTHWEST UINTA BASIN, UTAH

    SciTech Connect (OSTI)

    S. Robert Bereskin

    2003-02-11T23:59:59.000Z

    Anastamosing, low gradient distributary channels produce {approx}30 gravity, paraffinic oils from the Middle Member of the lacustrine Eocene Green River Formation in the south-central portion of the Uinta Basin. This localized depocenter was situated along the fluctuating southern shoreline of Lake Uinta, where complex deposits of marginal-lacustrine to lower delta plain accumulations are especially characteristic. The Middle Member contains several fining-upward parasequences that can be recognized in outcrop, core, and downhole logs. Each parasequence is about 60 to 120 feet thick and consists of strata deposited during multiple lake level fluctuations that approach 30 to 35 feet in individual thickness. Such parasequences represent 300,000-year cycles based on limited absolute age dating. The subaerial to subaqueous channels commonly possess an erosional base and exhibit a fining upward character. Accordingly, bedding features commonly range from large-scale trough and planar cross bedding or lamination at the base, to a nonreservoir, climbing ripple assemblage near the uppermost reservoir boundary. The best reservoir quality occurs within the laminated to cross-stratified portions, and the climbing ripple phase usually possesses more deleterious micas and/or detrital clays. Diagenesis also exerts a major control on reservoir quality. Certain sandstones were cemented by an early, iron-poor calcite cement, which can be subsequently leached. Secondary intergranular porosity (up to 20%) is largely responsible for the 10 -100 millidarcy rock, which represents petrophysical objectives for both primary and secondary production. Otherwise, intense compaction, silicic and iron-rich carbonate cements, and authigenic clays serve to reduce reservoir quality to marginal economic levels.

  8. Depositional environment of lower Green River Formation sandstones (Eocene), Red Wash field (Uinta Basin), Uintah County, Utah

    E-Print Network [OSTI]

    McClain, Anthony Scott

    1985-01-01T23:59:59.000Z

    ) occurred. The resulting increase in water supply to Lake Uinta while sediment remained trapped in the northern basin caused a period of exceptionally high biologic activity. This allowed the deposition of the rich oil shales for which the Green River... brown, brittle shales make up the majority of this unit. Minor amounts of limestone, dolomite, and siltstone are also present. Some of the shales are "oil shales". This 440 ft ( 134 m) thick Member is responsible for most of the production from...

  9. Managing asbestos: Ten costly sins

    SciTech Connect (OSTI)

    Denson, F.A.; Onderick, W.A.

    1993-01-01T23:59:59.000Z

    This article describes how to build an ongoing, continuous, and improved asbestos management program. Asbestos management is one of the toughest jobs facing a plant or environmental engineer today; even seasoned engineers can make mistakes. Much confusion exists about how best to manage this issue, especially in plant settings. Whether the company is small, medium, or large, asbestos has the power to steal from profits if not managed properly. To help POWER readers examine their current asbestos management programs, here are 10 common errors that could be stopped or avoided by practicing preventive techniques. The 10 costly sins presented are not mutually exclusive, and they certainly are not all-inclusive. They are offered as a way to stimulate ideas on how to build an ongoing, continuous, and improved asbestos management program. These include Sin 1: No written policy. Sin 2: Lack of corporate guidance. Sin 3: Not complying with regulations. Sin 4: Not worrying about other respirable fibers. Sin 5: Lawsuits--not culpable. Sin 6: No visible emissions, no problems. Sin 7: Managing asbestos manually.

  10. Water-related Issues Affecting Conventional Oil and Gas Recovery and Potential Oil-Shale Development in the Uinta Basin, Utah

    SciTech Connect (OSTI)

    Michael Vanden Berg; Paul Anderson; Janae Wallace; Craig Morgan; Stephanie Carney

    2012-04-30T23:59:59.000Z

    Saline water disposal is one of the most pressing issues with regard to increasing petroleum and natural gas production in the Uinta Basin of northeastern Utah. Conventional oil fields in the basin provide 69 percent of Utah?s total crude oil production and 71 percent of Utah?s total natural gas, the latter of which has increased 208% in the past 10 years. Along with hydrocarbons, wells in the Uinta Basin produce significant quantities of saline water ? nearly 4 million barrels of saline water per month in Uintah County and nearly 2 million barrels per month in Duchesne County. As hydrocarbon production increases, so does saline water production, creating an increased need for economic and environmentally responsible disposal plans. Current water disposal wells are near capacity, and permitting for new wells is being delayed because of a lack of technical data regarding potential disposal aquifers and questions concerning contamination of freshwater sources. Many companies are reluctantly resorting to evaporation ponds as a short-term solution, but these ponds have limited capacity, are prone to leakage, and pose potential risks to birds and other wildlife. Many Uinta Basin operators claim that oil and natural gas production cannot reach its full potential until a suitable, long-term saline water disposal solution is determined. The enclosed project was divided into three parts: 1) re-mapping the base of the moderately saline aquifer in the Uinta Basin, 2) creating a detailed geologic characterization of the Birds Nest aquifer, a potential reservoir for large-scale saline water disposal, and 3) collecting and analyzing water samples from the eastern Uinta Basin to establish baseline water quality. Part 1: Regulators currently stipulate that produced saline water must be disposed of into aquifers that already contain moderately saline water (water that averages at least 10,000 mg/L total dissolved solids). The UGS has re-mapped the moderately saline water boundary in the subsurface of the Uinta Basin using a combination of water chemistry data collected from various sources and by analyzing geophysical well logs. By re-mapping the base of the moderately saline aquifer using more robust data and more sophisticated computer-based mapping techniques, regulators now have the information needed to more expeditiously grant water disposal permits while still protecting freshwater resources. Part 2: Eastern Uinta Basin gas producers have identified the Birds Nest aquifer, located in the Parachute Creek Member of the Green River Formation, as the most promising reservoir suitable for large-volume saline water disposal. This aquifer formed from the dissolution of saline minerals that left behind large open cavities and fractured rock. This new and complete understanding the aquifer?s areal extent, thickness, water chemistry, and relationship to Utah?s vast oil shale resource will help operators and regulators determine safe saline water disposal practices, directly impacting the success of increased hydrocarbon production in the region, while protecting potential future oil shale production. Part 3: In order to establish a baseline of water quality on lands identified by the U.S. Bureau of Land Management as having oil shale development potential in the southeastern Uinta Basin, the UGS collected biannual water samples over a three-year period from near-surface aquifers and surface sites. The near-surface and relatively shallow groundwater quality information will help in the development of environmentally sound water-management solutions for a possible future oil shale and oil sands industry and help assess the sensitivity of the alluvial and near-surface bedrock aquifers. This multifaceted study will provide a better understanding of the aquifers in Utah?s Uinta Basin, giving regulators the tools needed to protect precious freshwater resources while still allowing for increased hydrocarbon production.

  11. CORE-BASED INTEGRATED SEDIMENTOLOGIC, STRATIGRAPHIC, AND GEOCHEMICAL ANALYSIS OF THE OIL SHALE BEARING GREEN RIVER FORMATION, UINTA BASIN, UTAH

    SciTech Connect (OSTI)

    Lauren P. Birgenheier; Michael D. Vanden Berg,

    2011-04-11T23:59:59.000Z

    An integrated detailed sedimentologic, stratigraphic, and geochemical study of Utah's Green River Formation has found that Lake Uinta evolved in three phases (1) a freshwater rising lake phase below the Mahogany zone, (2) an anoxic deep lake phase above the base of the Mahogany zone and (3) a hypersaline lake phase within the middle and upper R-8. This long term lake evolution was driven by tectonic basin development and the balance of sediment and water fill with the neighboring basins, as postulated by models developed from the Greater Green River Basin by Carroll and Bohacs (1999). Early Eocene abrupt global-warming events may have had significant control on deposition through the amount of sediment production and deposition rates, such that lean zones below the Mahogany zone record hyperthermal events and rich zones record periods between hyperthermals. This type of climatic control on short-term and long-term lake evolution and deposition has been previously overlooked. This geologic history contains key points relevant to oil shale development and engineering design including: (1) Stratigraphic changes in oil shale quality and composition are systematic and can be related to spatial and temporal changes in the depositional environment and basin dynamics. (2) The inorganic mineral matrix of oil shale units changes significantly from clay mineral/dolomite dominated to calcite above the base of the Mahogany zone. This variation may result in significant differences in pyrolysis products and geomechanical properties relevant to development and should be incorporated into engineering experiments. (3) This study includes a region in the Uinta Basin that would be highly prospective for application of in-situ production techniques. Stratigraphic targets for in-situ recovery techniques should extend above and below the Mahogany zone and include the upper R-6 and lower R-8.

  12. Nonassociated gas resources in low-permeability sandstone reservoirs, lower tertiary Wasatch Formation, and upper Cretaceous Mesaverde Group, Uinta Basin, Utah

    SciTech Connect (OSTI)

    Fouch, T.D.; Schmoker, J.W.; Boone, L.E.; Wandrey, C.J.; Crovelli, R.A.; Butler, W.C.

    1994-08-01T23:59:59.000Z

    The US Geological Survey recognizes six major plays for nonassociated gas in Tertiary and Upper Cretaceous low-permeability strata of the Uinta Basin, Utah. For purposes of this study, plays without gas/water contacts are separated from those with such contacts. Continuous-saturation accumulations are essentially single fields, so large in areal extent and so heterogeneous that their development cannot be properly modeled as field growth. Fields developed in gas-saturated plays are not restricted to structural or stratigraphic traps and they are developed in any structural position where permeability conduits occur such as that provided by natural open fractures. Other fields in the basin have gas/water contacts and the rocks are water-bearing away from structural culmination`s. The plays can be assigned to two groups. Group 1 plays are those in which gas/water contacts are rare to absent and the strata are gas saturated. Group 2 plays contain reservoirs in which both gas-saturated strata and rocks with gas/water contacts seem to coexist. Most units in the basin that have received a Federal Energy Regulatory Commission (FERC) designation as tight are in the main producing areas and are within Group 1 plays. Some rocks in Group 2 plays may not meet FERC requirements as tight reservoirs. However, we suggest that in the Uinta Basin that the extent of low-permeability rocks, and therefore resources, extends well beyond the limits of current FERC designated boundaries for tight reservoirs. Potential additions to gas reserves from gas-saturated tight reservoirs in the Tertiary Wasatch Formation and Cretaceous Mesaverde Group in the Uinta Basin, Utah is 10 TCF. If the potential additions to reserves in strata in which both gas-saturated and free water-bearing rocks exist are added to those of Group 1 plays, the volume is 13 TCF.

  13. BA War & Society Module Information

    E-Print Network [OSTI]

    Harman, Neal.A.

    BA War & Society Module Information 2014-2015 www.swansea.ac.uk/artsandhumanities Arts Studies BA War & Society BA War & Society The scope and scale of the BA (Hons) War and Society degree Theories of War 1 (compulsory) HUA102 War and Warfare in the Modern World (compulsory) HIH118 World History

  14. sin[n Delta t sin (n Delta t1)] as a source of unpredictable dynamics

    E-Print Network [OSTI]

    Stefano Morosetti

    2014-08-13T23:59:59.000Z

    We investigate the ability of the function sin[n Delta t sin (n Delta t1)], where n is an integer and growing number, to produce unpredictable sequences of numbers. Classical mathematical tools for distinguishing periodic from chaotic or random behaviour, such as sensitivity to the initial conditions, Fourier analysis, and autocorrelation are used. Moreover, the function acos{sin[n Delta t sin (n Delta t1)]}/pigreek is introduced to have an uniform density of numbers in the interval [0,1], so it can be submitted to a battery of widely used tests for random number generators. All these tools show that a proper choice of Delta t and Delta t1, can produce a sequence of numbers behaving as unpredictable dynamics.

  15. Intermediate Major Full Major BUSIBA.I Intmd Business BA ARTHBA Art History BA

    E-Print Network [OSTI]

    Tipple, Brett

    Studies HBS GEOSBS Geoscience BSG ESS.BA Exercise & Sport Sci BA GEOSHBS Geoscience HSG ESS.BS Exercise & Sport Sci BS GERMBA German BA ESS.HBS Exercise & Sport Sci HBS GERMHBA German HBA ESS.BS.T Exercise

  16. LANDS WITH WILDERNESS CHARACTERISTICS, RESOURCE MANAGEMENT PLAN CONSTRAINTS, AND LAND EXCHANGES: CROSS-JURISDICTIONAL MANAGEMENT AND IMPACTS ON UNCONVENTIONAL FUEL DEVELOPMENT IN UTAH’S UINTA BASIN

    SciTech Connect (OSTI)

    Keiter, Robert; Ruple, John; Holt, Rebecca; Tanana, Heather; McNeally, Phoebe; Tribby, Clavin

    2012-10-01T23:59:59.000Z

    Utah is rich in oil shale and oil sands resources. Chief among the challenges facing prospective unconventional fuel developers is the ability to access these resources. Access is heavily dependent upon land ownership and applicable management requirements. Understanding constraints on resource access and the prospect of consolidating resource holdings across a fragmented management landscape is critical to understanding the role Utah’s unconventional fuel resources may play in our nation’s energy policy. This Topical Report explains the historic roots of the “crazy quilt” of western land ownership, how current controversies over management of federal public land with wilderness character could impact access to unconventional fuels resources, and how land exchanges could improve management efficiency. Upon admission to the Union, the State of Utah received the right to title to more than one-ninth of all land within the newly formed state. This land is held in trust to support public schools and institutions, and is managed to generate revenue for trust beneficiaries. State trust lands are scattered across the state in mostly discontinuous 640-acre parcels, many of which are surrounded by federal land and too small to develop on their own. Where state trust lands are developable but surrounded by federal land, federal land management objectives can complicate state trust land development. The difficulty generating revenue from state trust lands can frustrate state and local government officials as well as citizens advocating for economic development. Likewise, the prospect of industrial development of inholdings within prized conservation landscapes creates management challenges for federal agencies. One major tension involves whether certain federal public lands possess wilderness character, and if so, whether management of those lands should emphasize wilderness values over other uses. On December 22, 2010, Secretary of the Interior Ken Salazar issued Secretarial Order 3310, Protecting Wilderness Characteristics on Lands Managed by the Bureau of Land Management. Supporters argue that the Order merely provides guidance regarding implementation of existing legal obligations without creating new rights or duties. Opponents describe Order 3310 as subverting congressional authority to designate Wilderness Areas and as closing millions of acres of public lands to energy development and commodity production. While opponents succeeded in temporarily defunding the Order’s implementation and forcing the Bureau of Land Management (BLM) to adopt a more collaborative approach, the fundamental questions remain: Which federal public lands possess wilderness characteristics and how should those lands be managed? The closely related question is: How might management of such resources impact unconventional fuel development within Utah? These questions remain pressing independent of the Order because the BLM, which manages the majority of federal land in Utah, is statutorily obligated to maintain an up-to-date inventory of federal public lands and the resources they contain, including lands with wilderness characteristics. The BLM is also legally obligated to develop and periodically update land use plans, relying on information obtained in its public lands inventory. The BLM cannot sidestep these hard choices, and failure to consider wilderness characteristics during the planning process will derail the planning effort. Based on an analysis of the most recent inventory data, lands with wilderness characteristics — whether already subject to mandatory protection under the Wilderness Act, subject to discretionary protections as part of BLM Resource Management Plan revisions, or potentially subject to new protections under Order 3310 — are unlikely to profoundly impact oil shale development within Utah’s Uinta Basin. Lands with wilderness characteristics are likely to v have a greater impact on oil sands resources, particularly those resources found in the southern part of the state. Management requirements independent of l

  17. BA Philosophy, Politics and Law

    E-Print Network [OSTI]

    Harman, Neal.A.

    BA Philosophy, Politics and Law (PPL) Module Information 2013-2014 Arts and Humanities College of www.swansea.ac.uk/artsandhumanities Department of Politcial and Cultural Studies #12;PPL at Swansea Swansea offers one of only two PPL degrees in the UK. Building on the successfully launch of our PPE

  18. BA Economics and BA Financial Economics Assessment Plan Program Learning Objectives

    E-Print Network [OSTI]

    Cantlon, Jessica F.

    BA Economics and BA Financial Economics ­ Assessment Plan Program Learning Objectives The program will prepare graduates: 1. Understand the "economic way model economic decisions. 3. The ability to analyze historical and current events

  19. Ceramic Technology Project database: September 1990 summary report. [SiC, SiN, whisker-reinforced SiN, ZrO-toughened aluminas, zirconias, joints

    SciTech Connect (OSTI)

    Keyes, B.L.P.

    1992-06-01T23:59:59.000Z

    Data generated within the Ceramic Technology Project (CTP) represent a valuable resource for both research and industry. The CTP database was created to provide easy access to this information in electronic and hardcopy forms by using a computerized database and by issuing periodic hardcopy reports on the database contents. This report is the sixth in a series of semiannual database summaries and covers recent additions to the database, including joined brazed specimen test data. It covers 1 SiC, 34 SiN, 10 whisker-reinforced SiN, 2 zirconia-toughened aluminas, 8 zirconias, and 34 joints.

  20. Track Finding Efficiency in BaBar

    E-Print Network [OSTI]

    T. Allmendinger; B. Bhuyan; D. N. Brown; H. Choi; S. Christ; R. Covarelli; M. Davier; A. G. Denig; M. Fritsch; A. Hafner; R. Kowalewski; O. Long; A. M. Lutz; M. Martinelli; D. R. Muller; I. M. Nugent; D. Lopes Pegna; M. V. Purohit; E. Prencipe; J. M. Roney; G. Simi; E. P. Solodov; A. V. Telnov; E. Varnes; R. Waldi; W. F. Wang; R. M. White

    2012-07-12T23:59:59.000Z

    We describe several studies to measure the charged track reconstruction efficiency and asymmetry of the BaBar detector. The first two studies measure the tracking efficiency of a charged particle using $\\tau$ and initial state radiation decays. The third uses the $\\tau$ decays to study the asymmetry in tracking, the fourth measures the tracking efficiency for low momentum tracks, and the last measures the reconstruction efficiency of $K_S^0$ particles. The first section also examines the stability of the measurements vs BaBar running periods.

  1. Hadron Physics in BaBar

    SciTech Connect (OSTI)

    Lafferty, G.D.; /Manchester U.

    2005-08-29T23:59:59.000Z

    Some recent results in hadron physics from the BaBar experiment are discussed. In particular, the observation of two new charmed states, the D*{sub sJ}{sup +}(2317) and the D*{sub sJ}{sup +}(2457), is described, and results are presented on the first measurement of the rare decay mode of the B meson, B{sup 0} {pi}{sup 0}{pi}{sup 0}.

  2. New Spectroscopy at BaBar

    SciTech Connect (OSTI)

    Mazzoni, M.A.; /INFN, Rome

    2007-04-18T23:59:59.000Z

    The Babar experiment at the SLAC B factory has accumulated a high luminosity that offers the possibility of systematic studies of quarkonium spectroscopy and of investigating rare new phenomena. Recent results in this field are presented. In recent times spectroscopy has become exciting again, after the discovery of new states that are not easily explained by conventional models. States such as the X(3872) and the Y(4260) could be new excited charmonium states, but require precise measurements for positive identification. The BaBar experiment [1] is installed at the asymmetric storage ring PEP-II. 90% of the data accumulated by BaBar are taken at the Y(4S) (10.58 GeV) and 10% just below (10.54 GeV). The BaBar detector includes a 5-layer, double-sided silicon vertex tracker and a 40-layer drift chamber in a 1.5 T solenoidal magnetic field, which detect charged particles and measures their momenta and ionization energy losses. Photons, electrons, and neutral hadrons are detected with a CsI(Tl)-crystal electromagnetic calorimeter. An internally reflecting ring-imaging Cherenkov is also used for particle id. Penetrating muon and neutral hadrons are identified by an array of resistive-plate chambers embedded in the steel of the flux return. The detector allows good track and vertex resolution, good particle id and good photon detection so it is especially suited for spectroscopy studies.

  3. The Uinta Basin Case Robert J. Bayer

    E-Print Network [OSTI]

    Utah, University of

    Overburden Tailings Oil Shale Mining Open Pit Underground Ex situ extraction Ex situ thermal conversion EIS for Oil Sands and Oil Shale Ongoing concerns with Basin-wide air quality Wildlife and wildlife

  4. Annealing properties of open volumes in strained SiN films studied by monoenergetic positron beams

    SciTech Connect (OSTI)

    Uedono, A.; Ito, K.; Narumi, T.; Sometani, M.; Yamabe, K.; Miyagawa, Y.; Murata, T.; Honda, K.; Hattori, N.; Matsuura, M.; Asai, K.; Ohdaira, T.; Suzuki, R. [Institute of Applied Physics, University of Tsukuba, Tsukuba, Ibaraki 305-8573 (Japan); Process Technology Development Division, Renesas Technology Corp., 4-1 Mizuhara, Itami, Hyogo 664-0005 (Japan); National Institute of Advanced Industrial Science and Technology, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568 (Japan)

    2007-09-15T23:59:59.000Z

    The effect of annealing on open volumes in strained SiN films deposited on Si by plasma enhanced chemical vapor deposition was studied using monoenergetic positron beams. For compressive SiN, the stress was reduced by postdeposition annealing; this effect was attributed to the relaxation of matrix structures accompanied by an expansion of small open spaces intrinsically existing in the matrix and the introduction of large open volumes. For tensile SiN, although annealing tends to decrease the concentration of large open volumes, the size of the small open spaces and the film stress were almost constant up to 1000 deg. C annealing. This was attributed to the network structure related to the open spaces remaining stable even at 1000 deg. C annealing, and this mainly determines the stress in the tensile film.

  5. Precision Measurement of sin^2 theta_W at a Reactor

    E-Print Network [OSTI]

    J. M. Conrad; J. M. Link; M. H. Shaevitz

    2005-10-24T23:59:59.000Z

    This paper presents a strategy for measuring sin^2 theta_W to ~1% at a reactor-based experiment, using antineutrinos electron elastic scattering. This error is comparable to the NuTeV, SLAC E158, and APV results on sin^2 theta_W, but with substantially different contributions to the systematics. An improved method for identifying antineutrino proton events, which serve both as a background and as a normalization sample, is described. The measurement can be performed using the near detector of the presently proposed reactor-based oscillation experiments. We conclude that an absolute error of delta(sin^2 theta_W)=0.0019 may be achieved.

  6. ChampionSin the Classroom, in the Community, and in Competition HailtotHeBuff&Blue

    E-Print Network [OSTI]

    Vertes, Akos

    Supporting ChampionSin the Classroom, in the Community, and in Competition #12;HailtotHeBuff&Blue, and the Buff & Blue Fund is the cornerstone of GW Athletics. Through the Buff & Blue Fund, donors are providing that, the Buff & Blue Fund represents: An athletic experience that mirrors the overall excellence of GW

  7. Measuring Sin^22?_13 with the Daya Bay Nuclear Reactors

    E-Print Network [OSTI]

    Yifang Wang

    2006-10-09T23:59:59.000Z

    Angle \\theta_13 is one of the two unknown neutrino mixing parameters to be determined. Its value may determine the future trend of the neutrino physics. We propose to measure sin^22\\theta_13 with a sensitivity better than 0.01 (90% C.L) at the Daya Bay reactor power plant.

  8. Roadmap: Paralegal Studies Bachelor of Arts [AS-BA-PLST

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Paralegal Studies ­ Bachelor of Arts [AS-BA-PLST] College of Arts and Sciences Department of Sociology Catalog Year: 2013-2014 Page 1 of 3 | Last Updated: 7-May-13/LNHD This roadmap is a recommended on page 2 #12;Roadmap: Paralegal Studies ­ Bachelor of Arts [AS-BA-PLST] College of Arts and Sciences

  9. FourYear Academic Plan 20122013 BA in Geology

    E-Print Network [OSTI]

    FourYear Academic Plan 20122013 BA in Geology Internal Use Version Year 1 Year 2 Year 3 Year 4: Total UD Credits: 46 Total Credits: 120 3/19/12 #12;FourYear Academic Plan 20122013 BA in Geology

  10. Combined Honours BA Digital Journalism and Communication, Media, and Film

    E-Print Network [OSTI]

    Combined Honours BA Digital Journalism and Communication, Media, and Film Are you looking in Digital Journalism (DJ) and Communication, Media, and Film (CMF) is for you. That's because our DJ Honours BA Digital Journalism and Communication, Media, and Film We look forward to meeting you! Student

  11. Radioactive contamination of BaF2 crystal scintillator

    E-Print Network [OSTI]

    Polischuk, O G; Bernabei, R; Cappella, F; Caracciolo, V; Cerulli, R; Di Marco, A; Danevich, F A; Incicchitti, A; Poda, D V; Tretyak, V I

    2013-01-01T23:59:59.000Z

    Barium fluoride (BaF$_2$) crystal scintillators are promising detectors to search for double beta decay processes in $^{130}$Ba ($Q_{2{\\beta}}$ = 2619(3) keV) and $^{132}$Ba ($Q_{2{\\beta}}$ = 844(1) keV). The $^{130}$Ba isotope is of particular interest because of the indications on 2${\\beta}$ decay found in two geochemical experiments. The radioactive contamination of BaF$_2$ scintillation crystal with mass of 1.714 kg was measured over 113.4 hours in a low-background DAMA/R&D set-up deep underground (3600 m w.e.) at the Gran Sasso National Laboratories of INFN (LNGS, Italy). The half-life of $^{212}$Po (present in the crystal scintillator due to contamination by radium) was estimated as $T_{1/2}$ = 298.8 $\\pm$ 0.8(stat.) $\\pm$ 1.4(syst.) ns by analysis of the events pulse profiles.

  12. The interaction of NO2 with BaO: from cooperative adsorption...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The interaction of NO2 with BaO: from cooperative adsorption to Ba(NO3)2 formation. The interaction of NO2 with BaO: from cooperative adsorption to Ba(NO3)2 formation. Abstract:...

  13. Water-induced Bulk Ba(NO3)2 Formation From NO2 Exposed Thermally...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bulk Ba(NO3)2 Formation From NO2 Exposed Thermally Aged BaOAl2O3. Water-induced Bulk Ba(NO3)2 Formation From NO2 Exposed Thermally Aged BaOAl2O3. Abstract: Phase changes in high...

  14. Microstructure and Cs Behavior of Ba-Doped Aluminosilicate Pollucite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    its environmental impact. Aluminosilicate pollucite CsAlSi2O6 is selected as a model waste form to study the decay-induced structural effects. While Ba-containing precipitates...

  15. Page 1 | B.A. in Art History | Academic Plan of Study Updated March 2014 B.A. in Art History

    E-Print Network [OSTI]

    Raja, Anita

    Coordinator: Dr. James Frakes (Rowe 218, jffrakes@uncc.edu, 704-687-0182). PROGRAM REQUIREMENTS BA in Art

  16. Page 1 | B.A. in Middle Grades Education | Academic Plan of Study Updated March 2014 B.A. in Middle Grades Education

    E-Print Network [OSTI]

    Raja, Anita

    Page 1 | B.A. in Middle Grades Education | Academic Plan of Study Updated March 2014 B.A. in Middle 2 | B.A. in Middle Grades Education | Academic Plan of Study Updated March 2014 Middle Grades Grades Education Academic Plan of Study College of Education Department of Middle, Secondary and K-12

  17. Esta informacin puede ser usada en parte o en su integridad sin necesidad de citar fuentes 1 Ciencia y Tecnologa

    E-Print Network [OSTI]

    Ministerio de Ciencia y Tecnología Intervención del Sr. Ministro JOSEP PIQUÉ en el acto de apertura de la información puede ser usada en parte o en su integridad sin necesidad de citar fuentes 2 Ministerio de Ciencia

  18. Precision measurement of sin/sup 2/theta/sub W/ from semileptonic neutrino scattering

    SciTech Connect (OSTI)

    Abramowicz, H.; Belusevic, R.; Blondel, A.; Bluemer, H.; Boeckmann, P.; Brummel, H.D.; Buchholz, P.; Burkhardt, H.; Debu, P.; Duda, J.; Dydak, F.; Falkenburg, B.; Fiedler, M.; Geiges, R.; Geweniger, C.; Grant, A.L.; Guyot, C.; Hagelberg, R.; Hepp, V.; Hughes, E.W.; Kampschulte, B.; Keilwerth, H.; Kleinknecht, K.; Knobloch, J.; Krasny, M.; Kro-acute-accentlikowski, J.; Kurz, N.; Lipniacka, A.; Merlo, J.; Mueller, E.; Para, A.; Perez, P.; Perrier, F.; Pollman, D.; Ranjard, F.; Renk, B.; Schuller, J.; Taureg, H.; Tittel, K.; Turlay, R.; Vallage, B.; Wachsmuth, H.; Wotschack, J.

    1986-07-21T23:59:59.000Z

    The ratio R-italic/sub ..nu../ of the neutral- to charged-current cross sections of neutrinos in iron has been measured in an exposure of the CERN-Dortmund-Heidelberg-Saclay neutrino detector to a 160-GeV/c-italic neutrino narrow-band beam at the CERN Super Proton Synchrotron. The result is R-italic/sub ..nu../ = 0.3072 +- 0.0025(stat) +- 0.0020(syst), for hadronic energy greater than 10 GeV. The electroweak mixing parameter is sin/sup 2/theta/sub W/ = 0.225 +- 0.005(expt ) +- 0.003(theor)+0.013(m-italic/sub c-italic/-1. 5 GeV/c-italic/sup 2/), where m-italic/sub c-italic/ is the charm-quark mass.

  19. Recent results of. mu. CF experiments at SIN (Swiss Institute For Nuclear Research)

    SciTech Connect (OSTI)

    Breunlich, W.H.; Cargnelli, M.; Bistirlich, J.; Crowe, K.M.; Justice, M.; Kurck, J.; Petitjean, C.; Sherman, R.H.; Bossy, H.; Daniel, H.

    1986-09-01T23:59:59.000Z

    Important topics concerning Muon Catalyzed Fusion were investigated in experiments at the Swiss Institute for Nuclear Research (SIN), including transient and steady state rates for the main d..mu..t cycle as well as detailed information about the competing d..mu..d and t..mu..t fusion branches. The basic kinetic parameters were determined and striking features of the resonant d..mu..t formation process were revealed (density effect, epithermal behavior). DT sticking was measured with independent techniques, i.e., detection of fusion neutrons as well as ..mu..He x-rays after fusion. Fusion yields per muon of 113 +- 10 were observed at liquid conditions, yields exceeding 200 are anticipated for optimal conditions from our results. 43 refs., 8 figs., 3 tabs.

  20. Distributed Online Conditions Database of the BaBar Experiment

    SciTech Connect (OSTI)

    Khan, A.; /Brunel U.; Gaponenko, I.A.; Brown, D.N.; /LBL, Berkeley

    2011-11-21T23:59:59.000Z

    This paper presents CDB - The distributed Conditions Database of the BaBar Experiment. CDB is the second major iteration of the database deployed in BaBar for production use as of October 2002. It replaced the original version of the database used through the first three years of the data taking. The new design and its implementation aims to improve the performance and scalability of the original database and addresses the emerging challenges of the distributed data production and analysis system of the Experiment.

  1. Effect of BaO Morphology on NOx Abatement: NO Interaction with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as well as unsupported and ?-Al&8322;O&8323;-supported BaO clusters. Adsorption of NO&8322; over BaO of different morphologies studied with the same method allowed...

  2. Adsorption and Formation of BaO Overlayers on Gamma-Al2O3 Surfaces...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formation of BaO Overlayers on Gamma-Al2O3 Surfaces . Adsorption and Formation of BaO Overlayers on Gamma-Al2O3 Surfaces . Abstract: First-principles density functional theory slab...

  3. The Effect of Water on the Adsorption of NO in Na- and Ba-Y,FAU...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water on the Adsorption of NO in Na- and Ba-Y,FAU Zeolites: A Combined FTIR and TPD Investigation. The Effect of Water on the Adsorption of NO in Na- and Ba-Y,FAU Zeolites: A...

  4. NO2 Adsorption on BaO/Al2O3: The Nature of Nitrate Species. ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NO2 Adsorption on BaOAl2O3: The Nature of Nitrate Species. NO2 Adsorption on BaOAl2O3: The Nature of Nitrate Species. Abstract: The nature of nitrate species formed in the...

  5. NOx Uptake Mechanism on Pt/BaO/Al2O3 Catalysts. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Al2O3 Catalysts. NOx Uptake Mechanism on PtBaOAl2O3 Catalysts. Abstract: The NOx adsorption mechanism on PtBaOAl2O3 catalysts was investigated by performing NOx storage...

  6. Evolution of ferroelectric domain structures embedded inside polychrystalline BaTiO3 during heating

    E-Print Network [OSTI]

    Varlioglu, Mesut

    2010-01-01T23:59:59.000Z

    Polycrystalline BaTiO 3 during Heating Mesut Varlioglu, 1under quasistatic heating by using polychromatic scanning X-180.47° or 0.47°. While heating the polycrystalline BaTiO 3

  7. Water-induced morphology changes in BaO/?-Al2O3 NOx storage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials. Water-induced morphology changes in BaO?-Al2O3 NOx storage materials. Abstract: Exposure of NO2-saturated BaO?-Al2O3 NOx storage materials to H2O vapour...

  8. Superconductivity in gallium-substituted Ba8Si46 clathrates

    E-Print Network [OSTI]

    Li, Yang; Zhang, Ruihong; Liu, Yang; Chen, Ning; Luo, Z. P.; Ma, Xingqiao; Cao, Guohui; Feng, Z. S.; Hu, Chia-Ren; Ross, Joseph H., Jr.

    2007-01-01T23:59:59.000Z

    superconductor, with an onset at T-C approximate to 3.3 K. For x=10 and higher, no superconductivity was observed down to T=1.8 K. This represents a strong suppression of superconductivity with increasing Ga content, compared to Ba8Si46 with T-C approximate to 8...

  9. Roadmap: Art History Bachelor of Arts [CA-BA-ARTH

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Art History ­ Bachelor of Arts [CA-BA-ARTH] College of the Arts School of Art Catalog Year: 2012­2013 Page 1 of 2 | Last Updated: 29-May-12/JS This roadmap is a recommended semester Elective (upper division) 3 Minor Requirements or General Electives 9 See note 2 on page 2 #12;Roadmap

  10. Roadmap: Art History Bachelor of Arts [CA-BA-ARTH

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Art History ­ Bachelor of Arts [CA-BA-ARTH] College of the Arts School of Art Catalog Year: 2013­2014 Page 1 of 2 | Last Updated: 30-Apr-13/JS This roadmap is a recommended semester Elective (upper division) 3 Minor Requirements or General Electives 9 See note 2 on page 2 #12;Roadmap

  11. Roadmap: Biology -Bachelor of Arts [AS-BA-BSCI

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Biology - Bachelor of Arts [AS-BA-BSCI] College of Arts and Sciences Department of Biological Sciences Catalog Year: 2012­2013 Page 1 of 3 | Last Updated: 2-May-12/LNHD This roadmap hours and minimum 42 upper- division credit hours #12;Roadmap: Biology - Bachelor of Arts [AS

  12. Roadmap: English Bachelor of Arts [AS-BA-ENG

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: English ­ Bachelor of Arts [AS-BA-ENG] College of Arts and Sciences Department of English Catalog Year: 2013-2014 Page 1 of 4 | Last Updated: 7-May-13/LNHD This roadmap is a recommended semester 5 on page 3 General Electives (upper division) 6 #12;Roadmap: English ­ Bachelor of Arts [AS

  13. Superconductivity in gallium-substituted Ba8Si46 clathrates 

    E-Print Network [OSTI]

    Li, Yang; Zhang, Ruihong; Liu, Yang; Chen, Ning; Luo, Z. P.; Ma, Xingqiao; Cao, Guohui; Feng, Z. S.; Hu, Chia-Ren; Ross, Joseph H., Jr.

    2007-01-01T23:59:59.000Z

    superconductor, with an onset at T-C approximate to 3.3 K. For x=10 and higher, no superconductivity was observed down to T=1.8 K. This represents a strong suppression of superconductivity with increasing Ga content, compared to Ba8Si46 with T-C approximate to 8...

  14. BA in ECONOMICS (736020) MAP Sheet Department of Economics

    E-Print Network [OSTI]

    Olsen Jr., Dan R.

    BA in ECONOMICS (736020) MAP Sheet Department of Economics For students entering the degree program The Economics Department requires a minimum of 21 hours in the major to be taken in residency at BYU courses: complete the following with a grade of C- or better: Econ 110* Economics Principles and Problems

  15. BA in ECONOMICS (736020) MAP Sheet Department of Economics

    E-Print Network [OSTI]

    Olsen Jr., Dan R.

    BA in ECONOMICS (736020) MAP Sheet Department of Economics For students entering the degree program from approved list from approved list Econ 110* from approved list personal choice The Economics: complete the following with a grade of C- or better: Econ 110* Economics Principles and Problems Econ 378

  16. Structural phase transitions in BaPrO{sub 3}

    SciTech Connect (OSTI)

    Saines, Paul J. [School of Chemistry, University of Sydney, Sydney, New South Wales 2006 (Australia); Kennedy, Brendan J. [School of Chemistry, University of Sydney, Sydney, New South Wales 2006 (Australia)], E-mail: b.kennedy@chem.usyd.edu.au; Smith, Ronald I. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Harwell Science and Innovation Campus, Didcot OX11 0QX (United Kingdom)

    2009-04-02T23:59:59.000Z

    The crystal structures adopted by BaPrO{sub 3} at and above ambient temperature have been examined using a combination of synchrotron X-ray and neutron diffraction. BaPrO{sub 3} has been established to undergo a series of phase transitions from Pbnmorthorhombic{yields}Ibmmorthorhombic{yields}R3-bar crhombohedral{yields}Pm3-barm cubic. BaPrO{sub 3} is the second A{sup 2+}B{sup 4+}O{sub 3} perovskite found to adopt rhombohedral symmetry in preference to the I4/mcm tetragonal structure. Analysis of the octahedral tilting through the rhombohedral to cubic phase transition indicates that this transformation is continuous and tricritical in nature. The tricritical behaviour of this transition is likely to be a result of the competition between tetragonal and rhombohedral structures to be the preferred phase, with the rhombohedral symmetry adopted by BaPrO{sub 3} being stabilised by the unusually large B-site cation.

  17. MAJOR TO CAREER GUIDE B.A. Chemistry

    E-Print Network [OSTI]

    Walker, Lawrence R.

    MAJOR TO CAREER GUIDE B.A. Chemistry College of Sciences www.unlv.edu/chemistry Mission of the College of Sciences The College of Sciences offers programs in life sciences, chemistry, geoscience: 702-895-2077 Campus Location: MPE-A 130 www.unlv.edu/sciences/advising About the Chemistry Career

  18. Measurements of Form Factors with the BaBar Experiment

    SciTech Connect (OSTI)

    Li, Selina Z.; /SLAC

    2011-08-25T23:59:59.000Z

    Selected recent results on measurements of form factors by the BaBar Collaboration are reviewed, including e{sup +}e{sup -} {yields} {eta}{prime}{gamma}, leptonic and semileptonic charm decays from data collected at or near the {Upsilon}(4S) resonance.

  19. Combined Honours BA Digital Journalism and Communication, Media, and Film

    E-Print Network [OSTI]

    Combined Honours BA Digital Journalism and Communication, Media, and Film Are you looking in Digital Journalism (DJ) and Communication, Media, and Film (CMF) is for you. That's because our DJ for a career combining your interests in media with a practical skill-set? If so, the Combined Honours program

  20. BaBar Note 295 May 16th, 1996

    E-Print Network [OSTI]

    and cooling system. Three types of hybrid will be used in BaBar SVT, di ering in the number of chips from 10 generated on the hybrid. We have realized that lateral walls of the channel help the heat exchange between of the cooling system in keeping the front-end chips into their optimal working condition. Thermo

  1. Hysteretic electrical transport in BaTiO{sub 3}/Ba{sub 1?x}Sr{sub x}TiO{sub 3}/Ge heterostructures

    SciTech Connect (OSTI)

    Ngai, J. H.; Kumah, D. P.; Walker, F. J. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Ahn, C. H. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Department of Mechanical Engineering and Materials Science, Yale University, 10 Hillhouse Avenue, New Haven, Connecticut 06520-8267 (United States)

    2014-02-10T23:59:59.000Z

    We present electrical transport measurements of heterostructures comprised of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} epitaxially grown on Ge. Sr alloying imparts compressive strain to the BaTiO{sub 3}, which enables the thermal expansion mismatch between BaTiO{sub 3} and Ge to be overcome to achieve c-axis oriented growth. The conduction bands of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} are nearly aligned with the conduction band of Ge, which facilitates electron transport. Electrical transport measurements through the dielectric stack exhibit rectifying behavior and hysteresis, where the latter is consistent with ferroelectric switching.

  2. The Determination of sin{sup 2} {theta}{sub W} in Neutrino Scattering: no more anomaly

    SciTech Connect (OSTI)

    Thomas, A. W. [ARC Centre of Excellence in Particle Physics at the Tera-scale (CoEPP) and CSSM, School of Chemistry and Physics, University of Adelaide, Adelaide SA 5005 (Australia)

    2011-12-14T23:59:59.000Z

    We review the corrections to the NuTeV determination of sin{sup 2} {theta}{sub W}, concluding that it is no longer appropriate to present it as an ''anomaly''. Indeed, when well understood corrections associated with charge symmetry violation and the iso-vector nuclear force are properly included, the measurement is completely consistent with the Standard Model.

  3. Distributed delay model for density wave dynamics in gas lifted wells Laure Sin`egre, Nicolas Petit

    E-Print Network [OSTI]

    Distributed delay model for density wave dynamics in gas lifted wells Laure Sin`egre, Nicolas Petit in the tubing D. dynamical choking is used to stabilise the density wave instability. In this paper, we propose instabilities cause production losses. One of these instabilities, referred to as the "density-wave

  4. Page 1 | B.A. in Earth Sciences | Academic Plan of Study Updated March 2014 B.A. in Earth Sciences

    E-Print Network [OSTI]

    Raja, Anita

    Page 1 | B.A. in Earth Sciences | Academic Plan of Study Updated March 2014 B.A. in Earth Sciences Academic Plan of Study College of Liberal Arts & Sciences Department of Geography & Earth Sciences geoearth. · Minimum Grades/GPA: minimum GPA is 2.0 · Teacher Licensure: YES in Earth Sciences. Students preparing

  5. Page 1 | B.A. in Earth Sciences | Academic Plan of Study Updated April 2014 B.A. in Earth Sciences

    E-Print Network [OSTI]

    Raja, Anita

    Page 1 | B.A. in Earth Sciences | Academic Plan of Study Updated April 2014 B.A. in Earth Sciences Academic Plan of Study College of Liberal Arts & Sciences Department of Geography & Earth Sciences geoearth. · Minimum Grades/GPA: minimum GPA is 2.0 · Teacher Licensure: YES in Earth Sciences. Students preparing

  6. Page 1 | B.A. in Special Education General Curriculum | Academic Plan of Study Updated May 2014 B.A. in Special Education (General Curriculum)

    E-Print Network [OSTI]

    Raja, Anita

    Page 1 | B.A. in Special Education ­ General Curriculum | Academic Plan of Study Updated May 2014 B.A. in Special Education (General Curriculum) Academic Plan of Study College of Education Department of Special Education and Child Development http://spcd.uncc.edu/ PROGRAM SUMMARY · Credit Hours: 120 hours

  7. Page 1 | B.A. in Elementary Education | Academic Plan of Study Updated March 2014 B.A. in Elementary Education

    E-Print Network [OSTI]

    Raja, Anita

    Page 1 | B.A. in Elementary Education | Academic Plan of Study Updated March 2014 B.A. in Elementary Education Academic Plan of Study College of Education Department of Reading and Elementary Education education.uncc.edu/reel PROGRAM SUMMARY · Credit Hours: 120-121 · Concentrations: No · Declaring

  8. Structural and chemical characterization of BaTiO{sub 3} nanorods

    SciTech Connect (OSTI)

    Zagar, K.; Recnik, A.; Sturm, S. [Department for Nanostructured Materials, Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)] [Department for Nanostructured Materials, Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Gajovic, A. [Molecular Physics Laboratory, Division of Materials Physics, Ruder Boskovic Institute, Bijenicka 54, HR-1002 Zagreb (Croatia)] [Molecular Physics Laboratory, Division of Materials Physics, Ruder Boskovic Institute, Bijenicka 54, HR-1002 Zagreb (Croatia); Ceh, M., E-mail: miran.ceh@ijs.si [Department for Nanostructured Materials, Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)

    2011-03-15T23:59:59.000Z

    Research highlights: {yields} Polycrystalline BaTiO{sub 3} nanorods were synthesized with EPD into AAO templates. {yields} Nanorods are composed of crystalline, nanosized grains with pseudo-cubic structure. {yields} Integrowth of hexagonal BaTiO{sub 3} polymorph within pseudo-cubic structure was observed. -- Abstract: An electron-microscopy investigation was performed on BaTiO{sub 3} nanorods that were processed by sol-gel electrophoretic deposition (EPD) into anodic aluminium oxide (AAO) membranes. The BaTiO{sub 3} nanorods grown within the template membranes had diameters ranging from 150 to 200 nm, with an average length of 10-50 {mu}m. By using various electron-microscopy techniques we showed that the processed BaTiO{sub 3} nanorods were homogeneous in their chemical composition. The BaTiO{sub 3} nanorods were always polycrystalline and were composed of well-crystallized, defect-free, pseudo-cubic BaTiO{sub 3} grains, ranging from 10 to 30 nm. No intergranular phases were observed between the BaTiO{sub 3} grains. A low-temperature hexagonal polymorph that is coherently intergrown with the BaTiO{sub 3} perovskite matrix was also observed as a minor phase. When annealing the AAO templates containing the BaTiO{sub 3} sol in an oxygen atmosphere the presence of the hexagonal polymorph was diminished.

  9. Measurement of the CP-Violation Parameter sin2?? with a New Tagging Method at the ?(5S) Resonance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sato, Y.; Yamamoto, H.; Aihara, H.; Asner, D. M.; Aulchenko, V.; Aushev, T.; Aziz, T.; Bakich, A. M.; Bhardwaj, V.; Bhuyan, B.; et al

    2012-04-01T23:59:59.000Z

    We report a measurement of the CP-violation parameter sin2?? at the ?(5S) resonance using a new tagging method, called “B-? tagging.” In ?(5S) decays containing a neutral B meson, a charged B, and a charged pion, the neutral B is reconstructed in the J/?K0SCP-eigenstate decay channel. The initial flavor of the neutral B meson at the moment of the ?(5S) decay is opposite to that of the charged B and may thus be inferred from the charge of the pion without reconstructing the charged B. From the asymmetry between B-?? and B?? tagged J/?K0S yields, we determine sin2??=0.57±0.58(stat)±0.06(syst). The resultsmore »are based on 121 fb?¹ of data recorded by the Belle detector at the KEKB e?e? collider.« less

  10. Measurement of the CP-Violation Parameter sin2?? with a New Tagging Method at the ?(5S) Resonance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sato, Y.; Yamamoto, H.; Aihara, H.; Asner, D. M.; Aulchenko, V.; Aushev, T.; Aziz, T.; Bakich, A. M.; Bhardwaj, V.; Bhuyan, B.; Bischofberger, M.; Bondar, A.; Bozek, A.; Bra?ko, M.; Browder, T. E.; Chang, P.; Chen, P.; Cheon, B. G.; Chilikin, K.; Chistov, R.; Cho, I.-S.; Cho, K.; Choi, S.-K.; Choi, Y.; Dalseno, J.; Doležal, Z.; Drásal, Z.; Eidelman, S.; Epifanov, D.; Fast, J. E.; Gaur, V.; Gabyshev, N.; Goh, Y. M.; Golob, B.; Haba, J.; Hara, T.; Hayasaka, K.; Hayashii, H.; Horii, Y.; Hoshi, Y.; Hou, W.-S.; Hyun, H. J.; Ishikawa, A.; Itoh, R.; Iwabuchi, M.; Iwasaki, Y.; Iwashita, T.; Julius, T.; Kapusta, P.; Kawasaki, T.; Kichimi, H.; Kiesling, C.; Kim, H. J.; Kim, H. O.; Kim, J. B.; Kim, J. H.; Kim, K. T.; Kim, M. J.; Kim, S. K.; Kim, Y. J.; Kinoshita, K.; Ko, B. R.; Kobayashi, N.; Kodyš, P.; Korpar, S.; Križan, P.; Krokovny, P.; Kuhr, T.; Kumar, R.; Kumita, T.; Kuzmin, A.; Kwon, Y.-J.; Lange, J. S.; Lee, S.-H.; Li, J.; Li, Y.; Liu, C.; Liu, Z. Q.; Louvot, R.; McOnie, S.; Miyabayashi, K.; Miyata, H.; Mizuk, R.; Mohanty, G. B.; Moll, A.; Muramatsu, N.; Nakano, E.; Nakao, M.; Nakazawa, H.; Natkaniec, Z.; Nishida, S.; Nishimura, K.; Nitoh, O.; Ogawa, S.; Ohshima, T.; Okuno, S.; Olsen, S. L.; Onuki, Y.; Ostrowicz, W.; Pakhlov, P.; Pakhlova, G.; Park, C. W.; Park, H.; Park, H. K.; Pedlar, T. K.; Petri?, M.; Piilonen, L. E.; Poluektov, A.; Röhrken, M.; Ryu, S.; Sahoo, H.; Sakai, Y.; Sanuki, T.; Schneider, O.; Schwanda, C.; Schwartz, A. J.; Seidl, R.; Senyo, K.; Seon, O.; Sevior, M. E.; Shapkin, M.; Shen, C. P.; Shibata, T.-A.; Shiu, J.-G.; Shwartz, B.; Sibidanov, A.; Simon, F.; Smerkol, P.; Sohn, Y.-S.; Sokolov, A.; Solovieva, E.; Stani?, S.; Stari?, M.; Stypula, J.; Sumihama, M.; Sumiyoshi, T.; Tanaka, S.; Tatishvili, G.; Teramoto, Y.; Trabelsi, K.; Uchida, M.; Uglov, T.; Unno, Y.; Uno, S.; Urquijo, P.; Varner, G.; Varvell, K. E.; Wang, C. H.; Wang, M.-Z.; Wang, P.; Wang, X. L.; Watanabe, M.; Watanabe, Y.; Wicht, J.; Won, E.; Yabsley, B. D.; Yamashita, Y.; Yusa, Y.; Zhang, Z. P.; Zhilich, V.; Zhulanov, V.; Zupanc, A.

    2012-04-01T23:59:59.000Z

    We report a measurement of the CP-violation parameter sin2?? at the ?(5S) resonance using a new tagging method, called “B-? tagging.” In ?(5S) decays containing a neutral B meson, a charged B, and a charged pion, the neutral B is reconstructed in the J/?K0SCP-eigenstate decay channel. The initial flavor of the neutral B meson at the moment of the ?(5S) decay is opposite to that of the charged B and may thus be inferred from the charge of the pion without reconstructing the charged B. From the asymmetry between B-?? and B?? tagged J/?K0S yields, we determine sin2??=0.57±0.58(stat)±0.06(syst). The results are based on 121 fb?¹ of data recorded by the Belle detector at the KEKB e?e? collider.

  11. Precise Measurement of the CP Violation Parameter sin2?1 in B??(cc?)K? Decays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adachi, I.; Aihara, H.; Asner, D. M.; Aulchenko, V.; Aushev, T.; Aziz, T.; Bakich, A. M.; Bay, A.; Bhardwaj, V.; Bhuyan, B.; Bischofberger, M.; Bondar, A.; Bozek, A.; Bra?ko, M.; Browder, T. E.; Chen, P.; Cheon, B. G.; Chilikin, K.; Chistov, R.; Cho, K.; Choi, S.-K.; Choi, Y.; Dalseno, J.; Danilov, M.; Doležal, Z.; Drásal, Z.; Eidelman, S.; Epifanov, D.; Fast, J. E.; Gaur, V.; Gabyshev, N.; Garmash, A.; Goh, Y. M.; Golob, B.; Haba, J.; Hara, K.; Hara, T.; Hayasaka, K.; Hayashii, H.; Higuchi, T.; Horii, Y.; Hoshi, Y.; Hou, W.-S.; Hsiung, Y. B.; Hyun, H. J.; Iijima, T.; Ishikawa, A.; Itoh, R.; Iwabuchi, M.; Iwasaki, Y.; Iwashita, T.; Julius, T.; Kapusta, P.; Katayama, N.; Kawasaki, T.; Kichimi, H.; Kiesling, C.; Kim, H. J.; Kim, H. O.; Kim, J. B.; Kim, J. H.; Kim, K. T.; Kim, Y. J.; Kinoshita, K.; Ko, B. R.; Koblitz, S.; Kodyš, P.; Korpar, S.; Križan, P.; Krokovny, P.; Kuhr, T.; Kumar, R.; Kumita, T.; Kuzmin, A.; Kwon, Y.-J.; Lange, J. S.; Lee, S.-H.; Li, J.; Li, Y.; Liu, C.; Liu, Y.; Liu, Z. Q.; Liventsev, D.; Louvot, R.; Matvienko, D.; McOnie, S.; Miyabayashi, K.; Miyata, H.; Miyazaki, Y.; Mizuk, R.; Mohanty, G. B.; Mori, T.; Muramatsu, N.; Nakano, E.; Nakao, M.; Nakazawa, H.; Neubauer, S.; Nishida, S.; Nishimura, K.; Nitoh, O.; Ogawa, S.; Ohshima, T.; Okuno, S.; Olsen, S. L.; Onuki, Y.; Ozaki, H.; Pakhlov, P.; Pakhlova, G.; Park, H. K.; Park, K. S.; Pedlar, T. K.; Pestotnik, R.; Petri?, M.; Piilonen, L. E.; Poluektov, A.; Röhrken, M.; Rozanska, M.; Sahoo, H.; Sakai, K.; Sakai, Y.; Sanuki, T.; Sato, Y.; Schneider, O.; Schwanda, C.; Schwartz, A. J.; Senyo, K.; Shebalin, V.; Shen, C. P.; Shibata, T.-A.; Shiu, J.-G.; Shwartz, B.; Sibidanov, A.; Simon, F.; Singh, J. B.; Smerkol, P.; Sohn, Y.-S.; Sokolov, A.; Solovieva, E.; Stani?, S.; Stari?, M.; Sumihama, M.; Sumisawa, K.; Sumiyoshi, T.; Tanaka, S.; Tatishvili, G.; Teramoto, Y.; Tikhomirov, I.; Trabelsi, K.; Tsuboyama, T.; Uchida, M.; Uehara, S.; Uglov, T.; Unno, Y.; Uno, S.; Ushiroda, Y.; Vahsen, S. E.; Varner, G.; Varvell, K. E.; Vinokurova, A.; Vorobyev, V.; Wang, C. H.; Wang, M.-Z.; Wang, P.; Watanabe, M.; Watanabe, Y.; Williams, K. M.; Won, E.; Yabsley, B. D.; Yamamoto, H.; Yamashita, Y.; Yamauchi, M.; Yusa, Y.; Zhang, Z. P.; Zhilich, V.; Zupanc, A.; Zyukova, O.

    2012-04-01T23:59:59.000Z

    We present a precise measurement of the CP violation parameter sin2?1 and the direct CP violation parameter Af using the final data sample of 772×10? BB¯¯¯ pairs collected at the ?(4S) resonance with the Belle detector at the KEKB asymmetric-energy e?e? collider. One neutral B meson is reconstructed in a J/?K0S, ?(2S)K0S, ?c1K0S, or J/?K0L CP eigenstate and its flavor is identified from the decay products of the accompanying B meson. From the distribution of proper-time intervals between the two B decays, we obtain the following CP violation parameters: sin2?1=0.667±0.023(stat)±0.012(syst) and Af=0.006±0.016(stat)±0.012(syst).

  12. Syntheses, crystal structures and characterizations of BaZn(SeO{sub 3}){sub 2} and BaZn(TeO{sub 3})Cl{sub 2}

    SciTech Connect (OSTI)

    Jiang Hailong [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, and the Graduate School of the Chinese Academy of Sciences, Fuzhou 350002 (China); Feng Meiling [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, and the Graduate School of the Chinese Academy of Sciences, Fuzhou 350002 (China); Mao Jianggao [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, and the Graduate School of the Chinese Academy of Sciences, Fuzhou 350002 (China)]. E-mail: mjg@ms.fjirsm.ac.cn

    2006-06-15T23:59:59.000Z

    Two new barium zinc selenite and tellurite, namely, BaZn(SeO{sub 3}){sub 2} and BaZn(TeO{sub 3})Cl{sub 2}, have been synthesized by the solid state reaction. The structure of BaZn(SeO{sub 3}){sub 2} features double chains of [Zn(SeO{sub 3}){sub 2}]{sup 2-} anions composed of four- and eight-member rings which are alternatively along a-axis. The double chains of [Zn{sub 2}(TeO{sub 3}){sub 2}Cl{sub 3}]{sup 3-} anions in BaZn(TeO{sub 3})Cl{sub 2} are formed by Zn{sub 3}Te{sub 3} rings in which each tellurite group connects with three ZnO{sub 3}Cl tetrahedra. BaZn(SeO{sub 3}){sub 2} and BaZn(TeO{sub 3})Cl{sub 2} are wide bandgap semiconductors based on optical diffuse reflectance spectrum measurements. -- Graphical abstract: Two new barium zinc selenite and tellurite, namely, BaZn(SeO{sub 3}){sub 2} and BaZn(TeO{sub 3})Cl{sub 2}, have been synthesized by solid state reaction. The structure of BaZn(SeO{sub 3}){sub 2} features 1D double chains of [Zn(SeO{sub 3}){sub 2}]{sup 2-} anions composed of four- and eight-member rings which are alternatively along a-axis. The 1D double chains of [Zn{sub 2}(TeO{sub 3}){sub 2}Cl{sub 3}]{sup 3-} anions in BaZn(TeO{sub 3})Cl{sub 2} are formed by Zn{sub 3}Te{sub 3} rings in which each tellurite group connects with one ZnO{sub 3}Cl and two ZnO{sub 2}Cl{sub 2} tetrahedra. BaZn(SeO{sub 3}){sub 2} and BaZn(TeO{sub 3})Cl{sub 2} are wide bandgap semiconductors based on optical diffuse reflectance spectrum measurements.

  13. Selected Topics on Hadronic B Decays From BaBar

    SciTech Connect (OSTI)

    Suzuki, K.; /SLAC

    2011-11-23T23:59:59.000Z

    Recent measurements of branching fractions and decay-rate asymmetries in charmless hadronic B decays at the BaBar experiment are presented. The selected topics include Dalitz plot analyses of B {yields} K{sup +} {pi}{sup -}{pi} and signal searches in B {yields} PP and PV, where isoscalar mesons are involved, and in B {yields} b{sub 1}P, P and V denote a pseudoscalar and vector meson, respectively. Several measurements in charmless hadronic B decays have indicated possible deviations from the theoretical predictions within the Standard Model. The measurements presented would contribute to searching for and resolving such puzzles.

  14. SeeBA Energiesysteme GmbH | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2,AUDITCalifornia Sector: WindRiegotecSeaScape Energy LtdSeeBA

  15. BA Tirunelveli Bundled Wind Project | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass Conversions Inc Jump to:AurigaPlantillas Jump to:­nculosAzurRB9 EnergyBA

  16. Surface donor states distribution post SiN passivation of AlGaN/GaN heterostructures

    SciTech Connect (OSTI)

    Goyal, Nitin, E-mail: nitin@unik.no [Carinthian Tech Research CTR AG, Europastraße 4/1, Technologiepark Villach, A- 9524 Villach/St. Magdalen (Austria); Department of Electronics and Telecommunication, Norwegian University of Science and Technology, Trondheim NO7034 (Norway); Fjeldly, Tor A. [Department of Electronics and Telecommunication, Norwegian University of Science and Technology, Trondheim NO7034 (Norway)

    2014-07-21T23:59:59.000Z

    In this paper, we present a physics based analytical model to describe the effect of SiN passivation on two-dimensional electron gas density and surface barrier height in AlGaN/GaN heterostructures. The model is based on an extraction technique to calculate surface donor density and surface donor level at the SiN/AlGaN interface. The model is in good agreement with the experimental results and promises to become a useful tool in advanced design and characterization of GaN based heterostructures.

  17. Data:7384572d-1390-4e2b-a18d-239ed8ba37eb | Open Energy Information

    Open Energy Info (EERE)

    a18d-239ed8ba37eb No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic...

  18. INTRODUCTION The Uinta Mountain region contains a relatively

    E-Print Network [OSTI]

    Pederson, Joel L.

    Uplift Joel L. Pederson* and Kevin W. Hadder* ABSTRACT The Green River's turn south from Browns Park University, Logan, UT 84321 bolo@cc.usu.edu Pederson, J.L., and Hadder, K.W., 2005, Revisiting the classic

  19. Uinta Basin Oil and Gas Development Air Quality Constraints

    E-Print Network [OSTI]

    Utah, University of

    Production EASTERN UTAH BLM Proposed Leasing for Oil Shale and Tar Sands Development "Indian Country" ­ Regulatory Authority Controlled by the Tribes and EPA Oil Shale Leasing Tar Sands Leasing "Indian Country

  20. 05671_UintaWaterStudy | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) - Energy Innovation Portal Advanced Materialsj3Fabry-Perot

  1. Uinta County, Wyoming: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTown of Ladoga, IndianaTurtle Airships JumpTypeforUSDOI -Informationin

  2. Roadmap: German Literature, Culture and Translation Bachelor of Arts [AS-BA-GLCT

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: German Literature, Culture and Translation ­ Bachelor of Arts [AS-BA-GLCT] College of Arts Updated: 24-May12/LNHD This roadmap is a recommended semester-by-semester plan of study for this major;Roadmap: German Literature, Culture and Translation ­ Bachelor of Arts [AS-BA-GLCT] College of Arts

  3. Roadmap: Classics Latin Concentration Bachelor of Arts [AS-BA-CLSS-LAT

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Classics ­ Latin Concentration ­ Bachelor of Arts [AS-BA-CLSS-LAT] College of Arts Updated: 11-Jun-12/LNHD This roadmap is a recommended semester-by-semester plan of study for this major;Roadmap: Classics ­ Latin Concentration ­ Bachelor of Arts [AS-BA-CLSS-LAT] College of Arts and Sciences

  4. A facile method for the preparation of Eu{sup 2+}-doped nanocrystalline BaFCl

    SciTech Connect (OSTI)

    Wang, Xianglei; Liu, Zhiqiang [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, UNSW Canberra (ADFA), Canberra, ACT 2600 (Australia); Stevens-Kalceff, Marion A. [School of Physics and Electron Microscope Unit, Mark Wainwright Analytical Centre, The University of New South Wales, Sydney, NSW 2052 (Australia); Riesen, Hans, E-mail: h.riesen@adfa.edu.au [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, UNSW Canberra (ADFA), Canberra, ACT 2600 (Australia)

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: • A facile co-precipitation method for the preparation of Eu{sup 2+}-doped BaFCl. • Reduction of Eu{sup 3+} to Eu{sup 2+} by zinc granular under nitrogen flow. • Photoluminescence and cathodoluminescence spectroscopy of the as-prepared BaFCl:Eu{sup 2+}. • Temperature dependent photoluminescence properties of Eu{sup 2+} ions in BaFCl. - Abstract: A facile method for the preparation of Eu{sup 2+}-doped BaFCl is reported. The method is based on the co-precipitation of aqueous solutions of BaCl{sub 2} and NH{sub 4}F to yield BaFCl. The doping by europium in the 2+ oxidation state is realized by the reduction of Eu{sup 3+} to Eu{sup 2+} employing granular zinc in the BaCl{sub 2} solution under nitrogen. Powder X-ray diffraction and electron microscopy have been used to confirm the BaFCl phase and photoluminescence, in the temperature range of 2.5–290 K, and room-temperature cathodoluminescence spectra have been measured to characterize the Eu{sup 2+} ions in the sample.

  5. Reactivity of a Thick BaO Film Supported on Pt(111): Adsorption...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a Thick BaO Film Supported on Pt(111): Adsorption and Reaction of NO2, H2O and CO2. Reactivity of a Thick BaO Film Supported on Pt(111): Adsorption and Reaction of NO2, H2O and...

  6. ECONOMICS BA DEGREE MAJOR REQUIREMENTS FLOWCHART FOR ACADEMIC YEAR 2012-2013

    E-Print Network [OSTI]

    Wu, Shin-Tson

    ECONOMICS BA DEGREE MAJOR REQUIREMENTS FLOWCHART FOR ACADEMIC YEAR 2012-2013 (see http://www.catalog.sdes.ucf.edu/) All B.A. Economics majors will be required to take a minimum of seven (7) electives by choosing from the following: PREREQUISITES REQUIRED ECO 3223 Money and Banking ECO 3410 Mathematical Economics ECO 3703

  7. The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An In Situ FTIR and TPDTPR Study. The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An In Situ FTIR and TPDTPR...

  8. The effect of BaCO3 on the hydration of OPC and composite cements

    E-Print Network [OSTI]

    Sheffield, University of

    The effect of BaCO3 on the hydration of OPC and composite cements Claire A. Utton* and Neil B of ordinary Portland cement (OPC) and up to 90% blast furnace slag (BFS), are used to encapsulate Intermediate. The effect of BaCO3 on the hydration properties of composite cements is being studied. This paper reports

  9. Submillimeter and microwave residual losses in epitaxial films of Y-Ba-Cu-O and Tl-Ca-Ba-Cu-O

    SciTech Connect (OSTI)

    Miller, D.; Richards, P.L. [Lawrence Berkeley Lab., CA (United States); Garrison, S.M.; Newman, N. [Conductus, Inc., Sunnyvale, CA (United States); Eom, C.B.; Geballe, T.H. [Stanford Univ., CA (United States). Dept. of Applied Physics; Etemad, S.; Inam, A.; Venkatesan, T. [Bell Communications Research, Inc., Red Bank, NJ (United States); Martens, J.S. [Sandia National Labs., Albuquerque, NM (United States); Lee, W.Y. [International Business Machines Corp., San Jose, CA (United States); Bourne, L.C. [Superconductor Technologies, Inc., Santa Barbara, CA (United States)

    1992-03-01T23:59:59.000Z

    We have used a novel bolometric technique and a resonant technique to obtain accurate submillimeter and microwave residual loss data for epitaxial thin films of YBa{sub 2}Cu{sub 3}O{sub 7}, Tl{sub 2}Ca{sub 2}Ba{sub 2}Cu{sub 3}O{sub 10} and Tl{sub 2}CaBa{sub 2}Cu{sub 2}O{sub 8}. For all films we obtain good agreement between the submillimeter and microwave data, with the residual losses in both the Y-Ba-Cu-O and Tl-Ca-Ba-Cu-O films scaling approximately as frequency squared below {approximately} 1 THz. We are able to fit the losses in the Y-Ba-Cu-O films to a weakly coupled grain model for the a-b plane conductivity, in good agreement with results from a Kramers-Kronig analysis of the loss data. We observe strong phonon structure in the Tl-Ca-Ba-Cu-O films for frequencies between 2 and 21 THz, and are unable to fit these losses to the simple weakly coupled grain model. This is in strong contrast to the case for other high {Tc} superconductors such as YBa{sub 2}Cu{sub 3}O{sub 7}, where phonon structure observed in ceramic samples is absent in epitaxial oriented films and crystals because of the electronic screening due to the high conductivity of the a-b planes.

  10. Phonon properties of BaFe?X? (X=S, Se) spin ladder compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Popovicq, Z. V.; Petrovic, C.; Scepanovic, M.; Lazarevic, N.; Opacic, M.; Radonjic, M. M.; Tanaskovic, D.; Lei, Hechang

    2015-02-01T23:59:59.000Z

    We present the Raman scattering spectra of the S=2 spin ladder compounds BaFe?X? (X=S,Se) in a temperature range between 20 and 400 K. Although the crystal structures of these two compounds are both orthorhombic and very similar, they are not isostructural. The unit cell of BaFe?S? (BaFe?Se?) is base-centered Cmcm (primitive Pnma), giving 18 (36) modes to be observed in the Raman scattering experiment. We have detected almost all Raman active modes, predicted by factor group analysis, which can be observed from the cleavage planes of these compounds. Assignment of the observed Raman modes of BaFe?S(Se)? is supported by themore »lattice dynamics calculations. The antiferromagnetic long-range spin ordering in BaFe?Se? below TN=255K leaves a fingerprint both in the A1g and B3g phonon mode linewidth and energy.« less

  11. First results about hydrogen loading by means of pulsed electrolysis of Y$_{1}$Ba$_{2}$Cu$_{3}$O$_{7}$ pellets

    E-Print Network [OSTI]

    Celani, F; Di Gioacchino, D; Spallone, A; Tripodi, P; Pace, S; Polichetti, M; Marini, P

    1994-01-01T23:59:59.000Z

    First results about hydrogen loading by means of pulsed electrolysis of Y$_{1}$Ba$_{2}$Cu$_{3}$O$_{7}$ pellets

  12. Oklahoma State University Honors Degrees (May. 1969 -May, 2013) Barber Frank A. Chemistry (B.A.) AS MAY 1969

    E-Print Network [OSTI]

    Veiga, Pedro Manuel Barbosa

    .A.) AS MAY 1976 McGuigan Patrick B. History (B.A.) AS MAY 1976 Holmes William J. Humanities (B.A.) AS MAY.S.) AS MAY 1969 Seebo Thomas C. II Political Science (B.A.) AS MAY 1970 Stewart Elisabeth French (B Charles E. Spanish (B.A.) AS DEC 1972 Miller Amanda K. English (B.S.) AS MAY 1973 Potts Jon R. III History

  13. Catalytic decomposition of Ba(NO3)2 on Pt(111)

    SciTech Connect (OSTI)

    Mudiyanselage, Kumudu; Weaver, Jason F.; Szanyi, Janos

    2011-04-07T23:59:59.000Z

    The decomposition of Ba(NO3)2 formed on BaO/Pt(111) (Pt(111) surface is partially covered by BaO) in the presence of CO was studied using temperature programmed desorption (TPD), infrared reflection absorption (IRA) and X-ray photoelectron (XP) spectroscopies. The exposure of BaO/Pt(111) to elevated NO2 pressure (1.0×10-4 Torr) at 450 K leads to the formation of Ba(NO3)2, chemisorbed O (OPt) and Pt-oxide-like domains. During TPD, the Ba(NO3)2 begins to thermally decompose near 490 K, releasing NO and NO2 with the maximum NOx desorption rate seen at 605 K. The OPt species formed following the exposure of BaO/Pt(111) to NO2 react with CO to release CO2 at 450 K. The consumption of OPt during CO oxidation initiates the migration of O from the Pt-oxide-like domains to the chemisorbed phase, where the CO oxidation reaction occurs. Therefore, the removal of OPt by CO leads to the reduction of oxidized Pt, and to the formation of metallic Pt(111) domains, where, subsequently, catalytic decomposition of Ba(NO3)2 can take place. The Pt-catalyzed decomposition of Ba(NO3)2 occurs readily at 450 K, a temperature much lower than the onset of the decomposition temperature of Ba(NO3)2 in the presence of oxidized Pt. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  14. The Co-repressor mSin3A Is a Functional Component of the REST-CoREST Repressor Complex*

    E-Print Network [OSTI]

    Miska, Eric

    The Co-repressor mSin3A Is a Functional Component of the REST-CoREST Repressor Complex* (Received-neural tissues. We find that REST re- pression involves two distinct repressor proteins. One of these, Co. Sci. U. S. A. 96, 9873­9878). Here we show that the co-repressor mSin3A also interacts with REST

  15. Synthesis and magnetic properties of the double layer perovskite CeBaFe2O5+w

    E-Print Network [OSTI]

    de Lima, Oscar Ferreira

    Synthesis and magnetic properties of the double layer perovskite CeBaFe2O5+w R. L. de Almeida,1 O The synthesis, crystallographic structure, and magnetic properties of polycrystalline single-phase samples of CeBaFe results on the successful prepara- tion and characterization of polycrystalline CeBaFe2O5+w samples. Ideal

  16. Determination of transition frequencies in a single $^{138}$Ba$^{+}$ ion

    E-Print Network [OSTI]

    Dijck, E A; Grier, A T; Jungmann, K; Mohanty, A; Valappol, N; Willmann, L

    2015-01-01T23:59:59.000Z

    Transition frequencies between low-lying energy levels in a single trapped $^{138}$Ba$^{+}$ ion have been measured with laser spectroscopy referenced to an optical frequency comb. By extracting the frequencies of one-photon and two-photon components of the line shape using an eight-level optical Bloch model, we achieved 0.1 MHz accuracy for the 5d $^{2}$D$_{3/2}$ - 6p $^{2}$P$_{1/2}$ and 6s $^{2}$S$_{1/2}$ - 5d $^{2}$D$_{3/2}$ transition frequencies, and 0.2 MHz for the 6s $^{2}$S$_{1/2}$ - 6p $^{2}$P$_{1/2}$ transition frequency.

  17. Synthesis and crystal structure of new layered BaNaSc(BO{sub 3}){sub 2} and BaNaY(BO{sub 3}){sub 2} orthoborates

    SciTech Connect (OSTI)

    Seryotkin, Yurii V., E-mail: yuvs@uiggm.nsc.r [Institute of Geology and Mineralogy RAS, 3, Koptyuga avenue, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, 2, Pirogova street, 630090 Novosibirsk (Russian Federation); Bakakin, Vladimir V. [Institute of Inorganic Chemistry RAS, 3, Lavrentieva avenue, 630090 Novosibirsk (Russian Federation); Kokh, Aleksandr E.; Kononova, Nadezhda G. [Institute of Geology and Mineralogy RAS, 3, Koptyuga avenue, 630090 Novosibirsk (Russian Federation); Svetlyakova, Tatyana N. [Institute of Geology and Mineralogy RAS, 3, Koptyuga avenue, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, 2, Pirogova street, 630090 Novosibirsk (Russian Federation); Kokh, Konstantin A. [Institute of Geology and Mineralogy RAS, 3, Koptyuga avenue, 630090 Novosibirsk (Russian Federation); Drebushchak, Tatyana N. [Novosibirsk State University, 2, Pirogova street, 630090 Novosibirsk (Russian Federation); Institute of Solid State Chemistry and Mechanochemistry RAS, 18, Kutateladze street, 630128 Novosibirsk (Russian Federation)

    2010-05-15T23:59:59.000Z

    Crystals of two new layered BaNaSc(BO{sub 3}){sub 2} (I) and BaNaY(BO{sub 3}){sub 2} (II) orthoborates are grown from the melt-solution by the spontaneous crystallization onto the platinum loop. Single crystal X-ray analysis showed that the compounds are isostructural with the space group R3-bar, a=5.23944(12) and 5.3338(2) A, and c=34.5919(11) and 35.8303(19) A for I and II, respectively, Z=6. The distinctive feature of the structure is the close-packed composite anion-cation (Ba,Na)(BO{sub 3}) layers. The layers are combined into the base building packages of two types: {l_brace}M{sup 3+}[Ba{sup 2+}(BO{sub 3}){sup 3-}]{sub 2}{r_brace}{sup +} and {l_brace}M{sup 3+}[Na{sup +}(BO{sub 3}){sup 3-}]{sub 2}{r_brace}{sup -}, where M is Sc or Y. Neutral-charge two-package (four-layer) blocks are stacked by the rhombohedral principle into twelve layers of the cubic packing. - Graphical abstract: The distinctive feature of new orthoborate crystals BaNaSc(BO{sub 3}){sub 2} and BaNaY(BO{sub 3}){sub 2} is the combination of base building packages of two types: {l_brace}M{sup 3+}[Ba{sup 2+}(BO{sub 3}){sup 3-}]{sub 2}{r_brace}{sup +} and {l_brace}M{sup 3+}[Na{sup +}(BO{sub 3}){sup 3-}]{sub 2}{r_brace}{sup -}, where M is Sc or Y.

  18. THE SINS SURVEY: MODELING THE DYNAMICS OF z {approx} 2 GALAXIES AND THE HIGH-z TULLY-FISHER RELATION

    SciTech Connect (OSTI)

    Cresci, G.; Hicks, E. K. S.; Genzel, R.; Schreiber, N. M. Foerster; Davies, R.; Bouche, N.; Buschkamp, P.; Genel, S.; Tacconi, L.; Eisenhauer, F.; Gerhard, O.; Lutz, D. [Max-Planck-Institut fuer extraterrestrische Physik, Postfach 1312, D-85741 Garching (Germany); Shapiro, K. [Department of Astronomy, Campbell Hall, University of California, Berkeley, CA 94720 (United States); Sommer-Larsen, J. [Excellence Cluster Universe, Technische Universitaet Muenchen, Boltzmanstr. 2, D-85748 Garching (Germany); Burkert, A.; Naab, T. [Universitaets-Sternwarte Ludwig-Maximilians Universitaet (USM), Scheinerstr. 1, Muenchen D-81679 (Germany); Sternberg, A. [School of Physics and Astronomy, Tel Aviv University, Tel Aviv 69978 (Israel); Cimatti, A. [Dipartimento di Astronomia, Universita degli Studi di Bologna, via Ranzani 1, I-40127 Bologna (Italy); Daddi, E. [CEA, Laboratoire AIM-CNRS-Universite Paris Diderot, Irfu/SAp, Orme des Merisiers, F-91191 Gif-sur-Yvette (France); Erb, D. K. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)], E-mail: gcresci@mpe.mpg.de (and others)

    2009-05-20T23:59:59.000Z

    We present the modeling of SINFONI integral field dynamics of 18 star-forming galaxies at z {approx} 2 from H{alpha} line emission. The galaxies are selected from the larger sample of the SINS survey, based on the prominence of ordered rotational motions with respect to more complex merger-induced dynamics. The quality of the data allows us to carefully select systems with kinematics dominated by rotation, and to model the gas dynamics across the whole galaxy using suitable exponential disk models. We obtain a good correlation between the dynamical mass and the stellar mass, finding that large gas fractions (M {sub gas} {approx} M {sub *}) are required to explain the difference between the two quantities. We use the derived stellar mass and maximum rotational velocity V {sub max} from the modeling to construct for the first time the stellar mass Tully-Fisher relation at z {approx} 2.2. The relation obtained shows a slope similar to what is observed at lower redshift, but we detect an evolution of the zero point. We find that at z {approx} 2.2 there is an offset in log(M {sub *}) for a given rotational velocity of 0.41 {+-} 0.11 with respect to the local universe. This result is consistent with the predictions of the latest N-body/hydrodynamical simulations of disk formation and evolution, which invoke gas accretion onto the forming disk in filaments and cooling flows. This scenario is in agreement with other dynamical evidence from SINS, where gas accretion from the halo is required to reproduce the observed properties of a large fraction of the z {approx} 2 galaxies.

  19. Thermodynamic Model for the Solubility of Ba(SeO4, SO4) Precipitates

    SciTech Connect (OSTI)

    Rai, D.; Felmy, Andrew R.; Moore, Dean A.; Kitamura, Akira; Yoshikawa, Hideki; Doi, Reisuke; Yoshida, Yasushi

    2014-08-15T23:59:59.000Z

    Abstract: The solubility of Ba(SeO4, SO4) precipitates was determined as a function of the BaSeO4 mole fractions, ranging from 0.0015 to 0.3830, and time with an equilibration period extending to as long as 302 days. Equilibrium/steady state conditions in this system are reached in ? 65 days. Pitzer’s ion interaction model was used to calculate solid and aqueous phase activity coefficients. Thermodynamic analyses showed that the data do not satisfy Gibbs-Duhem equation, thereby demonstrating that a single-solid solution phase does not control both the selenate and sulfate concentrations. Our extensive data with log 10 [Ba] ranging from ?3.6 to ?5.9 mol kg?1, log 10 [SeO4] rangingfrom?3.6 to -5.2 mol kg?1, and log 10 [SO4] ranging from?4.0 to ?5.3 mol kg?1 can be explained with the formation of an ideal BaSeO4 solid solution phase that controls the selenium concentrations and a slightly disordered/less-crystalline BaSO4(s) (log 10𝐾?sp = ?9.5 instead of ?10.05 for barite) that controls the sulfate concentrations. In these experiments the BaSO4 component of the solid solution phase never reaches thermodynamic equilibrium with the aqueous phase. Thermodynamic interpretations of the data show that both the ideal BaSeO4 solid solution phase and less-crystalline BaSO4 (s) phase are in equilibrium with each other in the entire range of BaSeO 4 mole fractions investigated in this study.

  20. Nanolamellar magnetoelectric BaTiO3–CoFe2O4 bicrystal

    E-Print Network [OSTI]

    Ren, Shenqiang; Laver, Mark; Wuttig, Manfred

    2009-10-13T23:59:59.000Z

    Nanolamellar magnetoelectric BaTiO3–CoFe2O4 bicrystal Shenqiang Ren,1 Mark Laver,2 and Manfred Wuttig1,a#1; 1Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742-2115, USA 2NIST Center for Neutron... Research, Gaithersburg, Maryland 20899-6103, USA #1;Received 30 July 2009; accepted 9 September 2009; published online 13 October 2009#2; Here, we report a spontaneously formed nanolamellar BaTiO3–CoFe2O4 bicrystal. #1;11¯0#2; interfaces join the BaTiO3...

  1. BA Political Economy Political Economy caters for students who wish to understand the

    E-Print Network [OSTI]

    Miall, Chris

    BA Political Economy Political Economy caters for students who wish to understand the political, philosophical and social underpinnings of modern economies,andwhomayfeeluncomfortablewiththehighly mathematical to International Relations; Introduction to Political Economy; Problems of World History/End of Empire

  2. The George R. Brown School of Engineering Degrees Offered: BA, MStat, MA, PhD

    E-Print Network [OSTI]

    Richards-Kortum, Rebecca

    Introduction to Engineering Computation · STAT 310 Probability and Statistics · STAT 410 Introduction246 Statistics The George R. Brown School of Engineering Degrees Offered: BA, MStat, MA, PhD Course engineering, computational and applied mathematics, managerial studies, mathematics, political science

  3. The George R. Brown School of Engineering Degrees Offered: BA, MStat, MA, PhD

    E-Print Network [OSTI]

    Richards-Kortum, Rebecca

    Introduction to Engineering Computation · STAT 310 Probability and Statistics · STAT 410 Introduction253 Statistics The George R. Brown School of Engineering Degrees Offered: BA, MStat, MA, PhD Course engineering, computational and applied mathematics, managerial studies, mathematics, political science

  4. Reaction of NO2 with a pure, thick BaO film: the effect of temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    film: the effect of temperature on the nature of NOx species formed. Abstract: The adsorption and reaction of NO2 on a thick (>30 ML), pure BaO film deposited onto an Al2O3...

  5. BA in FAMILY HISTORY--GENEALOGY (734125) MAP Sheet Department of History

    E-Print Network [OSTI]

    Olsen Jr., Dan R.

    BA in FAMILY HISTORY--GENEALOGY (734125) MAP Sheet Department of History For students entering of the University Core Doctrinal Foundation and Religion requirement): Rel C 261* Intro to Family History (Genealogy

  6. BA in FAMILY HISTORY--GENEALOGY (734125) MAP Sheet Department of History

    E-Print Network [OSTI]

    Martinez, Tony R.

    BA in FAMILY HISTORY--GENEALOGY (734125) MAP Sheet Department of History For students entering requirement): Rel C 261* Intro to Family History (Genealogy) Rel C 293R*Specialized Studies in Family History

  7. Characteristics of Desulfation Behavior for Pre-Sulfated Pt-BaO...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is negligible, in agreement with the results of H2 TPRX. These results suggest that H2S produced by the reduction of BaSO4 is readily re-adsorbed on the ceria support to form...

  8. Excellent Sulfur Resistance of Pt/BaO/CeO2 Lean NOx Trap Catalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and CHF Peden.2008."Excellent Sulfur Resistance of PtBaOCeO2 Lean NOx Trap Catalysts."Applied Catalysis. B, Environmental 84(3-4):545-551. doi:10.1016j.apcatb.2008.05.009...

  9. Water-induced morphology changes in BaO/?-Al2O3 NOx storage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials: an FTIR, TPD, and time-resolved synchrotron XRD Water-induced morphology changes in BaO?-Al2O3 NOx storage materials: an FTIR, TPD, and time-resolved synchrotron...

  10. Changes in Jupiter's Great Red Spot (19792006) and Oval BA (20002006) Sushil Shetty *, Philip S. Marcus

    E-Print Network [OSTI]

    Marcus, Philip S.

    the magnitude of the PV anomaly of the Oval BA changed from 2000, when its cloud cover was white, to 2006, when its cloud cover was red. The best-fit results also show that the areas of the PV anomalies of the GRS and of the Oval BA are smaller than the areas of their corresponding cloud covers at all times. Using the best

  11. Multiferroic BaTiO3-CoFe2O4 Nanostructures

    E-Print Network [OSTI]

    Ramesh, R.

    an additional degree of freedom in the design of actuators, transducers, and storage devices. HoweverMultiferroic BaTiO3-CoFe2O4 Nanostructures H. Zheng,1 J. Wang,1 S. E. Lofland,3 Z. Ma,1 L. Mohaddes and magnetic order param- eters in a nanostructured BaTiO3-CoFe2O4 ferroelectromagnet. This facilitates

  12. Crystallography and Physical Properties of BaCo2As2, Ba0.94K0.06Co2As2, and Ba0.78K0.22Co2As2

    SciTech Connect (OSTI)

    Anand, V K [Ames Laboratory; Quirinale, Dante G [Ames Laboratory; Lee, Yongbin [Ames Laboratory; Harmon, Bruce N [Ames Laboratory; Furukawa, Yuji [Ames Laboratory; Ogloblichev, V V [Ural Division of Russian Academy of Science; Huq, A [Oak Ridge National Laboratory; Abernathy, D L [Oak Ridge National Laboratory; Stephens, P W [SUNY of Stony Brook; McQueeney, Robert J [Ames Laboratory; Kreyssig, Aandreas [Ames Laboratory; Goldman, Alan I [Ames Laboratory; Johnston, David C [Ames Laboratory

    2014-08-01T23:59:59.000Z

    The crystallographic and physical properties of polycrystalline and single crystal samples of BaCo2As2 and K-doped Ba{1-x}K{x}Co2As2 (x = 0.06, 0.22) are investigated by x-ray and neutron powder diffraction, magnetic susceptibility chi, magnetization, heat capacity Cp, {75}As NMR and electrical resistivity rho measurements versus temperature T. The crystals were grown using both Sn flux and CoAs self-flux, where the Sn-grown crystals contain 1.6-2.0 mol% Sn. All samples crystallize in the tetragonal ThCr2Si2-type structure (space group I4/mmm). For BaCo2As2, powder neutron diffraction data show that the c-axis lattice parameter exhibits anomalous negative thermal expansion from 10 to 300 K, whereas the a-axis lattice parameter and the unit cell volume show normal positive thermal expansion over this T range. No transitions in BaCo2As2 were found in this T range from any of the measurements. Below 40-50 K, we find rho ~ T^2 indicating a Fermi liquid ground state. A large density of states at the Fermi energy D(EF) ~ 18 states/(eV f.u.) for both spin directions is found from low-T Cp(T) measurements, whereas the band structure calculations give D(EF) = 8.23 states/(eV f.u.). The {75}As NMR shift data versus T have the same T dependence as the chi(T) data, demonstrating that the derived chi(T) data are intrinsic. The observed {75}As nuclear spin dynamics are consistent with the presence of ferromagnetic and/or stripe-type antiferromagnetic spin fluctuations. The crystals of Ba{0.78}K{0.22}Co2As2 were grown in Sn flux and show properties very similar to those of undoped BaCo2As2. On the other hand, the crystals from two batches of Ba{0.94}K{0.06}Co2As2 grown in CoAs self-flux show evidence of weak ferromagnetism at T < 10 K with small ordered moments at 1.8 K of 0.007 and 0.03 muB per formula unit, respectively.

  13. Narrow Bandgap in beta-BaZn2As2 and Its Chemical Origins

    E-Print Network [OSTI]

    Xiao, Zewen; Ueda, Shigenori; Toda, Yoshitake; Ran, Fan-Yong; Guo, Jiangang; Lei, Hechang; Matsuishi, Satoru; Hosono, Hideo; Kamiya, Toshio

    2015-01-01T23:59:59.000Z

    Beta-BaZn2As2 is known to be a p-type semiconductor with the layered crystal structure similar to that of LaZnAsO, leading to the expectation that beta-BaZn2As2 and LaZnAsO have similar bandgaps; however, the bandgap of beta-BaZn2As2 (previously-reported value ~0.2 eV) is one order of magnitude smaller than that of LaZnAsO (1.5 eV). In this paper, the reliable bandgap value of beta-BaZn2As2 is determined to be 0.23 eV from the intrinsic region of the tem-perature dependence of electrical conductivity. The origins of this narrow bandgap are discussed based on the chemi-cal bonding nature probed by 6 keV hard X-ray photoemission spectroscopy, hybrid density functional calculations, and the ligand theory. One origin is the direct As-As hybridization between adjacent [ZnAs] layers, which leads to a secondary splitting of As 4p levels and raises the valence band maximum. The other is that the non-bonding Ba 5dx2-y2 orbitals form unexpectedly deep conduction band minimum (CBM) in beta-BaZn2As2 although the CBM of L...

  14. Photoluminescent BaMoO{sub 4} nanopowders prepared by complex polymerization method (CPM)

    SciTech Connect (OSTI)

    Azevedo Marques, Ana Paula de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil)]. E-mail: apamarques@liec.ufscar.br; Melo, Dulce M.A. de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Paskocimas, Carlos A. [Departamento de Engenharia Mecanica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Pizani, Paulo S. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Joya, Miryam R. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Leite, Edson R. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, CMDMC, Departamento de Quimica, Universidade Federal de Sao Carlos 13565-905, Sao Carlos, SP (Brazil); Longo, Elson [CMDMC, LIEC, Instituto de Quimica, Universidade Estadual Paulista, 14801-907 Araraquara, SP (Brazil)

    2006-03-15T23:59:59.000Z

    The BaMoO{sub 4} nanopowders were prepared by the Complex Polymerization Method (CPM). The structure properties of the BaMoO{sub 4} powders were characterized by FTIR transmittance spectra, X-ray diffraction (XRD), Raman spectra, photoluminescence spectra (PL) and high-resolution scanning electron microscopy (HR-SEM). The XRD, FTIR and Raman data showed that BaMoO{sub 4} at 300 deg. C was disordered. At 400 deg. C and higher temperature, BaMoO{sub 4} crystalline scheelite-type phases could be identified, without the presence of additional phases, according to the XRD, FTIR and Raman data. The calculated average crystallite sizes, calculated by XRD, around 40 nm, showed the tendency to increase with the temperature. The crystallite sizes, obtained by HR-SEM, were around of 40-50 nm. The sample that presented the highest intensity of the red emission band was the one heat treated at 400 deg. C for 2 h, and the sample that displayed the highest intensity of the green emission band was the one heat treated at 700 deg. C for 2 h. The CPM was shown to be a low cost route for the production of BaMoO{sub 4} nanopowders, with the advantages of lower temperature, smaller time and reduced cost. The optical properties observed for BaMoO{sub 4} nanopowders suggested that this material is a highly promising candidate for photoluminescent applications.

  15. Ferroelectric and ferromagnetic properties in BaTiO{sub 3} thin films on Si (100)

    SciTech Connect (OSTI)

    Singamaneni, Srinivasa Rao, E-mail: ssingam@ncsu.edu; Prater, John T. [Materials Science Division, Army Research Office, Research Triangle Park, North Carolina 27709 (United States); Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Punugupati, Sandhyarani; Hunte, Frank; Narayan, Jagdish [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States)

    2014-09-07T23:59:59.000Z

    In this paper, we report on the epitaxial integration of room temperature lead-free ferroelectric BaTiO{sub 3} thin (?1050?nm) films on Si (100) substrates by pulsed laser deposition technique through a domain matching epitaxy paradigm. We employed MgO and TiN as buffer layers to create BaTiO{sub 3}/SrRuO{sub 3}/MgO/TiN/Si (100) heterostructures. C-axis oriented and cube-on-cube epitaxial BaTiO{sub 3} is formed on Si (100) as evidenced by the in-plane and out-of-plane x-ray diffraction, and transmission electron microscopy. X-ray photoemission spectroscopic measurements show that Ti is in 4(+) state. Polarization hysteresis measurements together with Raman spectroscopy and temperature-dependent x-ray diffraction confirm the room temperature ferroelectric nature of BaTiO{sub 3}. Furthermore, laser irradiation of BaTiO{sub 3} thin film is found to induce ferromagnetic-like behavior but affects adversely the ferroelectric characteristics. Laser irradiation induced ferromagnetic properties seem to originate from the creation of oxygen vacancies, whereas the pristine BaTiO{sub 3} shows diamagnetic behavior, as expected. This work has opened up the route for the integration of room temperature lead-free ferroelectric functional oxides on a silicon platform.

  16. Impacts of SiN passivation on the degradation modes of AlGaN/GaN high electron mobility transistors under reverse-bias stress

    SciTech Connect (OSTI)

    Chen, Wei-Wei; Ma, Xiao-Hua, E-mail: xhma@xidian.edu.cn, E-mail: yhao@xidian.edu.cn; Hou, Bin; Zhu, Jie-Jie [School of Advanced Materials and Nanotechnology, Xidian University, Xi'an 710071 (China); Key Laboratory of Wide Band-Gap Semiconductor Materials and Devices, School of Microelectronics, Xidian University, Xi'an 710071 (China); Chen, Yong-He; Zheng, Xue-Feng; Zhang, Jin-Cheng; Hao, Yue, E-mail: xhma@xidian.edu.cn, E-mail: yhao@xidian.edu.cn [Key Laboratory of Wide Band-Gap Semiconductor Materials and Devices, School of Microelectronics, Xidian University, Xi'an 710071 (China)

    2014-10-27T23:59:59.000Z

    Impacts of SiN passivation on the degradation modes of AlGaN/GaN high electron mobility transistors are investigated. The gate leakage current decreases significantly upon removing the SiN layer and no clear critical voltage for the sudden degradation of the gate leakage current can be observed in the reverse-bias step-stress experiments. Gate-lag measurements reveal the decrease of the fast-state surface traps and the increase of slow-state traps after the passivation layer removal. It is postulated that consistent surface charging relieves the electric field peak on the gate edge, thus the inverse piezoelectric effect is shielded.

  17. Measurements of the CKM Angle Alpha at BaBar

    SciTech Connect (OSTI)

    Stracka, Simone; /Milan U. /INFN, Milan; ,

    2012-04-04T23:59:59.000Z

    The authors present improved measurements of the branching fractions and CP-asymmetries fin the B{sup 0} {yields} {pi}{sup +}{pi}{sup -}, B{sup 0} {yields} {pi}{sup 0}{pi}{sup 0}, and B{sup +} {yields} {rho}{sup +}{rho}{sup 0} decays, which impact the determination of {alpha}. The combined branching fractions of B {yields} K{sub 1}(1270){pi} and B {yields} K{sub 1}(1400){pi} decays are measured for the first time and allow a novel determination of {alpha} in the B{sup 0} {yields} {alpha}{sub 1}(1260){sup {+-}}{pi}{sup {-+}} decay channel. These measurements are performed using the final dataset collected by the BaBar detector at the PEP-II B-factory. The primary goal of the experiments based at the B factories is to test the Cabibbo-Kobayashi-Maskawa (CKM) picture of CP violation in the standard model of electroweak interactions. This can be achieved by measuring the angles and sides of the Unitarity Triangle in a redundant way.

  18. High Dispersion Spectroscopy of Solar-type Superflare Stars. I. Temperature, Surface Gravity, Metallicity, and $v \\sin i$

    E-Print Network [OSTI]

    Notsu, Yuta; Maehara, Hiroyuki; Notsu, Shota; Shibayama, Takuya; Nogami, Daisaku; Shibata, Kazunari

    2014-01-01T23:59:59.000Z

    We conducted high dispersion spectroscopic observations of 50 superflare stars with Subaru/HDS, and measured the stellar parameters of them. These 50 targets were selected from the solar-type (G-type main sequence) superflare stars that we had discovered from the Kepler photometric data. As a result of these spectroscopic observations, we found that more than half (34 stars) of our 50 targets have no evidence of binary system. We then estimated effective temperature ($T_{\\rm{eff}}$), surface gravity ($\\log g$), metallicity ([Fe/H]), and projected rotational velocity ($v\\sin i$) of these 34 superflare stars on the basis of our spectroscopic data. The accuracy of our estimations is higher than that of Kepler Input Catalog (KIC) values, and the differences between our values and KIC values ($(\\Delta T_{\\rm{eff}})_{\\rm{rms}} \\sim 219$K, $(\\Delta \\log g)_{\\rm{rms}} \\sim 0.37$ dex, and $(\\Delta\\rm{[Fe/H]})_{\\rm{rms}} \\sim 0.46$ dex) are comparable to the large uncertainties and systematic differences of KIC values ...

  19. Search for compounds of the NaBaR(BO{sub 3}){sub 2} family (R = La, Nd, Gd, and Yb) and the new NaBaYb(BO{sub 3}){sub 2} orthoborate

    SciTech Connect (OSTI)

    Svetlyakova, T. N., E-mail: svetlyakovatn@gmail.com; Kokh, A. E.; Kononova, N. G. [Russian Academy of Sciences, Sobolev Institute of Geology and Mineralogy, Siberian Branch (Russian Federation)] [Russian Academy of Sciences, Sobolev Institute of Geology and Mineralogy, Siberian Branch (Russian Federation); Fedorov, P. P. [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation)] [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation); Rashchenko, S. V. [Russian Academy of Sciences, Sobolev Institute of Geology and Mineralogy, Siberian Branch (Russian Federation)] [Russian Academy of Sciences, Sobolev Institute of Geology and Mineralogy, Siberian Branch (Russian Federation); Maillard, A. [University of Metz and Supelec, Laboratoire Materiaux Optiques, Photonique et Systemes (France)] [University of Metz and Supelec, Laboratoire Materiaux Optiques, Photonique et Systemes (France)

    2013-01-15T23:59:59.000Z

    A search for compounds of the NaBaR(BO{sub 3}){sub 2} composition (where R = La{sup 3+}, Nd{sup 3+}, Gd{sup 3+}, or Yb{sup 3+}) is performed by solid state synthesis and spontaneous crystallization. A new compound, NaBaYb(BO{sub 3}){sub 2}, is found in this series. It crystallizes in space group R3{sup -} and belongs to the family of sublayer complex orthoborates with isolated BO{sub 3} groups NaBaR(BO{sub 3}){sub 2} (R = Y, Sc, and Yb). Theoretical X-ray powder diffraction patterns of NaBaY(BO{sub 3}){sub 2}, NaBaSc(BO{sub 3}){sub 2}, and NaBaYb(BO{sub 3}){sub 2} are calculated based on single-crystal data.

  20. Pressure dependence of the superconducting critical temperature of HgBa 2Ca 2Cu 3O 8 y and HgBa 2Ca 3Cu 4O 10 y up to 30 GPa

    E-Print Network [OSTI]

    Wijngaarden, Rinke J.

    Pressure dependence of the superconducting critical temperature of HgBa 2Ca 2Cu 3O 8 y and HgBa 2Ca of the reported pressure- induced Tc values well above 150 K in the mercury-based high-Tc superconductors has been superconducting transition temperature Tc have been observed in HgBa2Ca2Cu3O8 y Hg-1223 samples under very high

  1. Page 1 | B.A. in Special Education Adapted Curriculum | Academic Plan of Study Updated May 2014 B.A. in Special Education (Adapted Curriculum)

    E-Print Network [OSTI]

    Raja, Anita

    Page 1 | B.A. in Special Education ­ Adapted Curriculum | Academic Plan of Study Updated May 2014 B ­ Adapted Curriculum | Academic Plan of Study Updated May 2014 Special Education - Adapted Curriculum Areas.A. in Special Education (Adapted Curriculum) Academic Plan of Study College of Education Department of Special

  2. The new Hg-rich barium indium mercurides BaIn{sub x}Hg{sub 7?x} (x=3.1) and BaIn{sub x}Hg{sub 11?x} (x=0–2.8)

    SciTech Connect (OSTI)

    Wendorff, Marco; Schwarz, Michael; Röhr, Caroline, E-mail: caroline@ruby.chemie.uni-freiburg.de

    2013-07-15T23:59:59.000Z

    The title compounds BaIn{sub x}Hg{sub 7?x} (x=3.1(1)) and BaIn{sub x}Hg{sub 11?x} (x=0–2.8) were synthesized from stoichiometric ratios of the elements in Ta crucibles. Their crystal structures have been determined using single crystal X-ray data. BaIn{sub x}Hg{sub 7?x} (x=3.1(1)) crystallizes in a new structure type (orthorhombic, oC16, space group Cmmm: a=512.02(1), b=1227.68(3), c=668.61(2) pm, Z=2, R1=0.0311). In the structure, the atoms of the three crystallographically different mixed In/Hg positions form planar nets of four-, six- and eight-membered rings. These nets are shifted against each other such that the four-membered rings form empty distorted cubes. The cubes are connected via common edges, corners and folded ladders, which are also found in BaIn{sub 2}/BaHg{sub 2} (KHg{sub 2} structure type) and BaIn (?-NaHg type). The Ba atoms are centered in the eight-membered rings and exhibit an overall coordination number of 20. The [BaM{sub 20}] polyhedra and twice as many distorted [M{sub 8}] cubes tesselate the space. BaIn{sub 2.8}Hg{sub 8.2} (cubic, cP36, space group Pm3{sup ¯}m, a=961.83(1) pm, Z=3, R1=0.0243) is the border compound of the phase width BaIn{sub x}Hg{sub 11?x} of the rare BaHg{sub 11} structure type. In the structure, ideal [M{sub 8}] cubes (at the corners of the unit cell) and BaM{sub 20} polyhedra (at the edges of the unit cell) represent the building blocks comparable to the other new In mercuride. In accordance with the increased In/Hg content, additional M-pure regions appear: the center of the unit cell contains a huge [Hg(1)M(2){sub 12}M(3,4){sub 32}] polyhedron, a Hg-centered cuboctahedron of In/Hg atoms surrounded by a capped cantellated cube of 32 additional M atoms. For both structure types, the bonding situation and the ‘coloring’, i.e. the In/Hg distribution of the polyanionic network, are discussed considering the different sizes of the atoms and the charge distribution (Bader AIM charges), which have been calculated within the framework of FP-LAPW density functional theory. - Graphical abstract: BaIn{sub 2.6}Hg{sub 4.4}: distorted cubes [(In/Hg){sub 8}] (green, like in BaHg{sub 11}), folded ladders (violet, like in BaIn, BaHg{sub 2} and BaIn{sub 2}) and Ba coordination polyhedra [Ba(In/Hg){sub 20}] (blue, like in BaHg{sub 11}). - Highlights: • The Hg-rich In-mercuride BaIn{sub 3.1}Hg{sub 3.9} crystallizes with a singular structure type. • The phase width of the BaHg{sub 11} structure in BaIn{sub x}Hg{sub 11-x} ends at x=2.8. • The relations of both compounds with other alkaline-earth mercurides are outlined. • The Hg/In coloring of the polyanion is discussed considering the structure features. • Bonding aspects are explored using band structure calculations.

  3. Significant increase of Curie temperature in nano-scale BaTiO{sub 3}

    SciTech Connect (OSTI)

    Li, Yueliang; Liao, Zhenyu; Fang, Fang; Zhu, Jing, E-mail: jzhu@mail.tsinghua.edu.cn [National Center for Electron Microscopy in Beijing, School of Materials Science and Engineering, State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084 (China); Wang, Xiaohui; Li, Longtu [State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China)

    2014-11-03T23:59:59.000Z

    The low Curie temperature (T{sub c}?=?130?°C) of bulk BaTiO{sub 3} greatly limits its applications. In this work, the phase structures of BaTiO{sub 3} nanoparticles with sizes ranging from 2.5?nm to 10?nm were studied at various temperatures by using aberration-corrected transmission electron microscopy (TEM) equipped with an in-situ heating holder. The results implied that each BaTiO{sub 3} nanoparticle was composed of different phases, and the ferroelectric ones were observed in the shells due to the complicated surface structure. The ferroelectric phases in BaTiO{sub 3} nanoparticles remained at 600?°C, suggesting a significant increase of T{sub c}. Based on the in-situ TEM results and the data reported by others, temperature-size phase diagrams for BaTiO{sub 3} particles and ceramics were proposed, showing that the phase transition became diffused and the T{sub c} obviously increased with decreasing size. The present work sheds light on the design and fabrication of advanced devices for high temperature applications.

  4. Field-effect BaTiO{sub 3}-Si solar cells

    SciTech Connect (OSTI)

    Wang, Wentao; Liu, Fude, E-mail: fordliu@hku.hk; Man Lau, Chor; Wang, Lei; Yang, Guandong; Zheng, Dawei [Department of Mechanical Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong (China); Li, Zhigang [Department of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Hong Kong (China)

    2014-03-24T23:59:59.000Z

    Conventional solar cells make use of the spatial variation in electronic environment due to junctions for charge separation. We investigated field-effect BaTiO{sub 3}-Si solar cells that utilize the bound surface charges of BaTiO{sub 3} to separate charge carriers in silicon. Rectifying behavior and photovoltaic effect were observed on cells with forward polarization. Theoretical simulation indicated that the induced electric field due to BaTiO{sub 3} polarization could extend into the silicon layer, which is consistent with experimental observations. In addition, adjusting relevant parameters may optimize the electric field distribution. The cells are promising in terms of material selection, device design, and fabrication.

  5. EXPLAINING THE Sr AND Ba SCATTER IN EXTREMELY METAL-POOR STARS

    SciTech Connect (OSTI)

    Aoki, W.; Suda, T.; Boyd, R. N.; Kajino, T.; Famiano, M. A., E-mail: aoki.wako@nao.ac.jp, E-mail: takuma.suda@nao.ac.jp, E-mail: richard11boyde@comcast.net, E-mail: kajino@nao.ac.jp, E-mail: michael.famiano@wmich.edu [National Astronomical Observatory of Japan, 2-21-1 Mitaka, Tokyo 181-8588 (Japan)

    2013-03-20T23:59:59.000Z

    Compilations of abundances of strontium and barium in extremely metal-poor stars show that an apparent cutoff is observed for [Sr/Ba] at [Fe/H] < -3.6 and large fluctuations for [Fe/H] > -3.6 with a clear upper bound depending on metallicity. We study the factors that place upper limits on the logarithmic ratio [Sr/Ba]. A model is developed in which the collapses of type II supernovae are found to reproduce many of the features seen in the data. This model is consistent with galactic chemical evolution constraints of light-element enrichment in metal-poor stars. Effects of turbulence in an explosive site have also been simulated, and are found to be important in explaining the large scatter observed in the [Sr/Ba] data.

  6. Phase relationships in the BaO-Y?O?-Cu-O system

    E-Print Network [OSTI]

    Hegg, Turi

    1989-01-01T23:59:59.000Z

    Os ? CuO showing the solid solution region for "the other perovskite" after Roth et al. 107 59. I'he BaO ? YsOs ? Cu ? 0 base plane of the polyhedra The quaternary BaO ? YsOs ? Cu ? 0 system with the suggested primary phase fields . 61. Pseudo... become insulating svhen z::. 7. 1, this means that the 213 compound goes from an insulating to a semiconducting to a superconducting to an insulating state as oxygen is added. The 213 compound has an oxygen-deficient perovskite structure . Its unit...

  7. Energy Calibration of the BaBar EMC Using the Pi0 Invariant Mass Method

    SciTech Connect (OSTI)

    Tanner, David J.; /Manchester U.

    2007-04-06T23:59:59.000Z

    The BaBar electromagnetic calorimeter energy calibration method was compared with the local and global peak iteration procedures, of Crystal Barrel and CLEO-II. An investigation was made of the possibility of {Upsilon}(4S) background reduction which could lead to increased statistics over a shorter time interval, for efficient calibration runs. The BaBar software package was used with unreconstructed data to study the energy response of the calorimeter, by utilizing the {pi}{sup 0} mass constraint on pairs of photon clusters.

  8. The Radiation Dose Measurement System for the BaBar Electromagnetic Calorimeter

    SciTech Connect (OSTI)

    Khan, A.; /Brunel U.; Meyer, W.T.; /Iowa State U.; Stelzer, J.; /Stanford U., Phys. Dept.; Yi, Jong; /Manchester U.

    2006-08-14T23:59:59.000Z

    An array of 116 p-channel radiation sensitive MOSFET transistors (RadFETs) has been operational for the past 6 years at the BaBar experiment at the PEP-II asymmetric B-Factory at the Stanford Linear Accelerator Center (SLAC). This system maps the integrated dose absorbed by different regions of the Electromagnetic Calorimeter (EMC) during the running of the experiment. We report on the design and implementation of the system and finally, the performance of the monitoring system during the last 6 years of BaBar data-taking.

  9. College of Charleston Major Roadmap: Religious Studies, B.A. | 2014-15 Page 1 MAJOR ROADMAP

    E-Print Network [OSTI]

    Kasman, Alex

    College of Charleston Major Roadmap: Religious Studies, B.A. | 2014-15 Page 1 MAJOR ROADMAP Religious Studies, B.A. Catalog Year: 2014-15 This roadmap is a suggested semester-by-semester planning availability may vary from semester to semester. Roadmaps are not meant to cover every possibility

  10. NOx uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported on ?-Al2O3. NOx uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported on ?-Al2O3....

  11. PLAN OF STUDY Digital Media & Design SCHOOL OF FINE ARTS 2013-2014Catalog BA in DMD

    E-Print Network [OSTI]

    Alpay, S. Pamir

    PLAN OF STUDY ­ Digital Media & Design SCHOOL OF FINE ARTS 2013-2014Catalog BA in DMD ATTACH YOUR ______ _____ __ ______ ______ _____ __ ______ ______ _____ __ ______ ______ _____ __ ______ ______ _____ __ ______ ______ _____ __ ______ ______ _____ __ ______ ______ _____ __ ______ University of Connecticut DMD BA REQUIREMENTS: 51 credits DMD courses (21 credits): DMD 1000 (3) ­ Digital Foundation DMD 1030 (3) ­ Animation Lab DMD 2010 (3) ­ Digital Culture DMD 3050 (3) ­ Visible Language DMD

  12. JOB EVALUATION QUESTIONNAIRE (JEQ) This form is reusable. Write answers on the JEQ Answer Sheet (BA Form 803).

    E-Print Network [OSTI]

    Amin, S. Massoud

    JOB EVALUATION QUESTIONNAIRE (JEQ) This form is reusable. Write answers on the JEQ Answer Sheet (BA, they provide a more precise measure of a job's requirements than a few general questions do. 2. Use black ink or type when completing the Answer Sheet (BA Form 803) 3. Write a brief description of what the job

  13. Effect of Y-211 particle size on the growth of single grain Y–Ba–Cu–O bulk superconductors

    E-Print Network [OSTI]

    Thoma, Max; Shi, Yunhua; Dennis, Tony; Durrell, John; Cardwell, David

    2014-12-01T23:59:59.000Z

    The engineering of fine Y2Ba1Cu1O5 (Y-211) inclusions of average particle size 1?2 ?m within the continuous, superconducting YBa2Cu3O7?? (Y-123) phase matrix of single-grain, bulk high temperature Y–Ba–Cu–O (YBCO) superconductors is fundamental...

  14. An, Yanming, Professor, Languages. BA, 1982, MA, 1985, Fudan University (China); PhD, University of Michigan,

    E-Print Network [OSTI]

    Stuart, Steven J.

    253 Faculty An, Yanming, Professor, Languages. BA, 1982, MA, 1985, Fudan University (China); PhD, Environmental Engineering & Earth Sciences. BME, École Polytechnique of Montréal (Canada), 2005; MS, 2007, PhD & Biomolecular Engineering. BA, Clemson University, 1973; MS, 1977, PhD, 1981, University of Massachusetts

  15. "Father Forgive Me For I Have Sinned": Strategies of Apologia used by the Roman Catholic Church in Addressing the Sexual Abuse Crisis

    E-Print Network [OSTI]

    Lozano-Whitten, Cheryl Elaine

    2011-08-08T23:59:59.000Z

    . They were bolstering, defeasibility, and corrective action. I would like to address these as they parallel the actions taken by the Catholic Church when addressing the sexual 9 abuse crisis. Seeing the President in Jackson Square, the heart of New... ?FATHER FORGIVE ME FOR I HAVE SINNED?: STRATEGIES OF APOLOGIA USED BY THE ROMAN CATHOLIC CHURCH IN ADDRESSING THE SEXUAL ABUSE CRISIS A Thesis by CHERYL ELAINE LOZANO-WHITTEN Submitted to the Office of Graduate Studies of Texas...

  16. Computer Science B.A. Degree Curriculum Chart: 2013-2014

    E-Print Network [OSTI]

    Stuart, Josh

    Computer Science B.A. Degree Curriculum Chart: 2013-2014 http://ua.soe.ucsc.edu · advising Comparative Programming Languages CMPS 115 Software Methodology CMPS 122 Computer Security CMPS 140 Artificial Intelligence CMPS 160 Computer Graphics CMPS 180 Database Systems CMPE 110 Computer Architecture 2. Students

  17. Computer Science B.A. Degree 2014-2015 Curriculum Chart

    E-Print Network [OSTI]

    Stuart, Josh

    Computer Science B.A. Degree 2014-2015 Curriculum Chart CMPS 12B/M Data Structures *CMPS 13H to Prog: Java CMPS 11 Intermediate Programming *CMPE 13/L Computer Systems and C Programming OR OR *CMPE to Analysis of Algorithms CMPS 140 Artificial Intelligence CMPS 104A Compiler Design CMPS 160 Computer

  18. Adaptive risk management for certifiably sustainable forestry B.A. Wintle a,

    E-Print Network [OSTI]

    Adaptive risk management for certifiably sustainable forestry B.A. Wintle a, *, D.B. Lindenmayer b Adaptive risk management Due diligence Monitoring Population viability analysis (PVA) Multi-model inference for biodiversity, (ii) formal risk assessment of competing management options that integrate impacts

  19. Department of Mechanical Engineering University of Bath, Bath BA2 7AY, UK

    E-Print Network [OSTI]

    Burton, Geoffrey R.

    . The balance between activities has shifted through the years with an increasing emphasis on research), and today as City of Bristol College #12;Department of Mechanical Engineering University of Bath, Bath BA2 7 vision and energy. Ted retired in 1987, and was succeeded as Director by Cliff Burrows. In 1992 Kevin

  20. Roadmap: Criminology and Justice Studies Corrections Bachelor of Arts [AS-BA-CRJU-CORR

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Criminology and Justice Studies ­ Corrections ­ Bachelor of Arts [AS-BA-CRJU-CORR] College/LNHD This roadmap is a recommended semester-by-semester plan of study for this major. However, courses Hours] JUS 46792 Internship 0-6 Recommended but not required #12;Roadmap: Criminology and Justice

  1. Roadmap: Communication Studies Public Communication Bachelor of Arts [CI-BA-COMM-PCMM

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Communication Studies ­ Public Communication ­ Bachelor of Arts [CI-BA-COMM-PCMM] College: 23-May-12/LNHD This roadmap is a recommended semester-by-semester plan of study for this major 2 #12;Roadmap: Communication Studies ­ Public Communication ­ Bachelor of Arts [CI

  2. Roadmap: Criminology and Justice Studies Policing Bachelor of Arts [AS-BA-CRJU-POLG

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Criminology and Justice Studies ­ Policing ­ Bachelor of Arts [AS-BA-CRJU-POLG] College/LNHD This roadmap is a recommended semester-by-semester plan of study for this major. However, courses Elective 3 See note 3 on page 2 General Electives (upper division) 9 #12;Roadmap: Criminology

  3. Roadmap: Theatre Studies Theatre and Society-Bachelor of Arts [CA-BA-THEA-THSO

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Theatre Studies ­ Theatre and Society- Bachelor of Arts [CA-BA-THEA-THSO] College This roadmap is a recommended semester-by-semester plan of study for this major. However, courses Requirement 3 Kent Core Requirement 3 General Elective (upper division) 3 See note 2 on page 3 #12;Roadmap

  4. The George R. Brown School of Engineering Degrees Offered: BA, MStat, MA, PhD

    E-Print Network [OSTI]

    Richards-Kortum, Rebecca

    211Introduction to Engineering Computation · STAT310Probability and Statistics · STAT410Introduction263 Statistics The George R. Brown School of Engineering Degrees Offered: BA, MStat, MA, PhD Course engineering, computational and applied mathematics, managerial studies, mathematics, political science

  5. Spectroscopy, polarization and nonadiabatic dynamics of electronically excited Ba(Ar)n clusters: Theory and experiment

    E-Print Network [OSTI]

    Krylov, Anna I.

    Spectroscopy, polarization and nonadiabatic dynamics of electronically excited Ba(Ar)n clusters, France Received 13 September 1995; accepted 17 November 1995 Molecular Dynamics simulations using, a comprehensive picture of the excited state dynamics is given. It is found that upon excitation, energy

  6. Roadmap: Communication Studies -Applied Communication -Bachelor of Arts [CI-BA-COMM-APCO

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Communication Studies - Applied Communication - Bachelor of Arts [CI-BA-COMM-APCO] College of Communication and Information School of Communication Studies Catalog Year: 2012­2013 Page 1 of 3 | Last Updated Major GPA Important Notes Semester One: [16 Credit Hours] COMM 15000 Introduction to Human Communication

  7. Measurement of branching fraction and first evidence of CP violation in B??a?±(1260)?? decays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dalseno, J.; Adachi, I.; Aihara, H.; Asner, D. M.; Aulchenko, V.; Aushev, T.; Bakich, A. M.; Bay, A.; Belous, K.; Bhuyan, B.; et al

    2012-11-01T23:59:59.000Z

    We present a measurement of the branching fraction and time-dependent CP violation parameters in B??a±?(1260)?? decays. The results are obtained from the final data sample containing 772×10? BB¯¯¯ pairs collected at the ?(4S) resonance with the Belle detector at the KEKB asymmetric-energy e?e? collider. We obtain the product branching fraction B(B??a±?(1260)??)×B(a±?(1260)??±???±)=(11.1±1.0(stat)±1.4(syst))×10?? and an upper limit on the product branching fraction for a possible decay with the same final state B(B??a±?(1320)??)×B(a±?(1320)??±???±)more »respectively. Simultaneously, we also extract the CP-conserving parameters ?C=+0.54±0.11(stat)±0.07(syst), ?S=–0.09±0.14(stat)±0.06(syst), which, respectively, describe a rate difference and strong phase difference between the decay channels where the a±? does not contain the spectator quark and those where it does. We find first evidence of mixing-induced CP violation in B??a±?(1260)?? decays with 3.1? significance. The rate where the a±? does not contain the spectator quark from the B meson is found to dominate the rate where it does at the 4.1? level. However, there is no evidence for either time- and flavor-integrated direct CP violation or flavor-dependent direct CP violation.« less

  8. Atomic and electronic structure of the ferroelectric BaTiO{sub 3}/Ge(001) interface

    SciTech Connect (OSTI)

    Fredrickson, Kurt D.; Ponath, Patrick; Posadas, Agham B.; Demkov, Alexander A., E-mail: demkov@physics.utexas.edu [Department of Physics, The University of Texas at Austin, Austin, Texas 78712 (United States); McCartney, Martha R.; Smith, David J. [Department of Physics, Arizona State University, Tempe, Arizona 85287 (United States); Aoki, Toshihiro [LeRoy Eyring Center for Solid State Science, Arizona State University, Tempe, Arizona 85287 (United States)

    2014-06-16T23:59:59.000Z

    In this study, we demonstrate the epitaxial growth of BaTiO{sub 3} on Ge(001) by molecular beam epitaxy using a thin Zintl template buffer layer. A combination of density functional theory, atomic-resolution electron microscopy and in situ photoemission spectroscopy is used to investigate the electronic properties and atomic structure of the BaTiO{sub 3}/Ge interface. Aberration-corrected scanning transmission electron micrographs reveal that the Ge(001) 2?×?1 surface reconstruction remains intact during the subsequent BaTiO{sub 3} growth, thereby enabling a choice to be made between several theoretically predicted interface structures. The measured valence band offset of 2.7?eV matches well with the theoretical value of 2.5?eV based on the model structure for an in-plane-polarized interface. The agreement between the calculated and measured band offsets, which are highly sensitive to the detailed atomic arrangement, indicates that the most likely BaTiO{sub 3}/Ge(001) interface structure has been identified.

  9. Influence of Ba content on grain size and dynamics of crystallization in barium ferrite thin films

    E-Print Network [OSTI]

    Laughlin, David E.

    Influence of Ba content on grain size and dynamics of crystallization in barium ferrite thin films of the crystallization process, which ultimately determines the grain size, were studied in barium ferrite thin films. Rapid thermal annealing was used to crystallize the amorphous as-deposited barium ferrite films

  10. Internal conversion coefficients in (134)Cs, (137)Ba, and (139)La: A precise test of theory 

    E-Print Network [OSTI]

    Nica, N.; Hardy, John C.; Iacob, V. E.; Balonek, C.; Trzhaskovskaya, M. B.

    2008-01-01T23:59:59.000Z

    Recently we measured the ratio of K-shell internal conversion coefficients, alpha(K), for the 127.5-keV E3 transition in (134)Cs and the 661.7-keV M4 transition in (137)Ba. We here report a measurement of the 165.9-keV M1 ...

  11. Search for Physics Beyond the Standard Model at BaBar and Belle

    E-Print Network [OSTI]

    G. Calderini

    2012-04-19T23:59:59.000Z

    Recent results on the search for new physics at BaBar and Belle B-factories are presented. The search for a light Higgs boson produced in the decay of different Y resonances is shown. In addition, recent measurements aimed to discover invisible final states produced by new physics mechanisms beyond the standard model are presented.

  12. Computer Science Major Worksheet B.A. Degree Student: _______________________ ID#___________ Catalog:_________ Advisor _____________

    E-Print Network [OSTI]

    Delene, David J.

    10/15/2012 Computer Science Major Worksheet ­ B.A. Degree Student: _______________________ ID#___________ Catalog:_________ Advisor _____________ Computer Science Required Courses Cr. Semester Gr. CSci 160 Computer Science I 4 CSci 161 Computer Science II 4 CSci 230 Systems Programming 3 CSci 242 Algo. & Data

  13. NAME__________________________________ REQUIREMENTS FOR THE B.A. DEGREE IN COMPUTER SCIENCE

    E-Print Network [OSTI]

    Thomas, Andrew

    NAME__________________________________ REQUIREMENTS FOR THE B.A. DEGREE IN COMPUTER SCIENCE (effective entering class Fall 2013) 1) REQUIRED COMPUTER SCIENCE COURSES (Total of 47 CS credit hours) * COS.00 or greater as must the overall GPA. February 18, 2013 #12;Computer Science Summary Total Total CS Hrs Hrs Q

  14. Measurement of branching fraction and first evidence of CP violation in B??a?±(1260)?? decays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dalseno, J.; Adachi, I.; Aihara, H.; Asner, D. M.; Aulchenko, V.; Aushev, T.; Bakich, A. M.; Bay, A.; Belous, K.; Bhuyan, B.; Bozek, A.; Bra?ko, M.; Brovchenko, O.; Browder, T. E.; Chekelian, V.; Chen, A.; Chen, P.; Cheon, B. G.; Chilikin, K.; Chistov, R.; Cho, I.-S.; Cho, K.; Choi, Y.; Doležal, Z.; Drásal, Z.; Eidelman, S.; Fast, J. E.; Gaur, V.; Gabyshev, N.; Garmash, A.; Goh, Y. M.; Hayashii, H.; Horii, Y.; Hoshi, Y.; Hou, W.-S.; Hsiung, Y. B.; Hyun, H. J.; Iijima, T.; Inami, K.; Ishikawa, A.; Itoh, R.; Iwabuchi, M.; Iwasaki, Y.; Iwashita, T.; Julius, T.; Kang, J. H.; Kiesling, C.; Kim, H. O.; Kim, J. B.; Kim, Y. J.; Kinoshita, K.; Ko, B. R.; Koblitz, S.; Kodyš, P.; Korpar, S.; Križan, P.; Krokovny, P.; Kronenbitter, B.; Kuhr, T.; Kumita, T.; Kwon, Y.-J.; Lee, S.-H.; Li, J.; Libby, J.; Liu, C.; Liu, Z. Q.; Louvot, R.; MacNaughton, J.; Matvienko, D.; McOnie, S.; Miyabayashi, K.; Miyata, H.; Miyazaki, Y.; Mohanty, G. B.; Mohapatra, D.; Moll, A.; Muramatsu, N.; Nakao, M.; Natkaniec, Z.; Nedelkovska, E.; Ng, C.; Nishida, S.; Nishimura, K.; Nitoh, O.; Ogawa, S.; Ohshima, T.; Okuno, S.; Pakhlov, P.; Pakhlova, G.; Park, C. W.; Park, H. K.; Pedlar, T. K.; Pestotnik, R.; Petri?, M.; Piilonen, L. E.; Prim, M.; Prothmann, K.; Ritter, M.; Röhrken, M.; Sahoo, H.; Sakai, Y.; Sanuki, T.; Schneider, O.; Schwanda, C.; Schwartz, A. J.; Senyo, K.; Seon, O.; Sevior, M. E.; Shapkin, M.; Shebalin, V.; Shen, C. P.; Shibata, T.-A.; Shiu, J.-G.; Sibidanov, A.; Simon, F.; Smerkol, P.; Sohn, Y.-S.; Solovieva, E.; Stari?, M.; Sumihama, M.; Sumiyoshi, T.; Tatishvili, G.; Teramoto, Y.; Trabelsi, K.; Uchida, M.; Uehara, S.; Unno, Y.; Uno, S.; Urquijo, P.; Usov, Y.; Vanhoefer, P.; Varner, G.; Wang, C. H.; Wang, P.; Watanabe, M.; Watanabe, Y.; Williams, K. M.; Won, E.; Yabsley, B. D.; Yamashita, Y.; Zhang, Z. P.; Zhilich, V.; Zhulanov, V.; Zupanc, A.

    2012-11-01T23:59:59.000Z

    We present a measurement of the branching fraction and time-dependent CP violation parameters in B??a±?(1260)?? decays. The results are obtained from the final data sample containing 772×10? BB¯¯¯ pairs collected at the ?(4S) resonance with the Belle detector at the KEKB asymmetric-energy e?e? collider. We obtain the product branching fraction B(B??a±?(1260)??)×B(a±?(1260)??±???±)=(11.1±1.0(stat)±1.4(syst))×10?? and an upper limit on the product branching fraction for a possible decay with the same final state B(B??a±?(1320)??)×B(a±?(1320)??±???±)±? does not contain the spectator quark and those where it does. We find first evidence of mixing-induced CP violation in B??a±?(1260)?? decays with 3.1? significance. The rate where the a±? does not contain the spectator quark from the B meson is found to dominate the rate where it does at the 4.1? level. However, there is no evidence for either time- and flavor-integrated direct CP violation or flavor-dependent direct CP violation.

  15. BA in CHEMISTRY (692827) MAP Sheet Department of Chemistry and Biochemistry

    E-Print Network [OSTI]

    Olsen Jr., Dan R.

    BA in CHEMISTRY (692827) MAP Sheet Department of Chemistry and Biochemistry For students entering in major courses. --The Chemistry and Biochemistry Department requires the final 10 hours of required chemistry credit to be taken in residence at BYU for this degree program. These hours may also go toward BYU

  16. BA in CHEMISTRY (692827) MAP Sheet Department of Chemistry and Biochemistry

    E-Print Network [OSTI]

    Seamons, Kent E.

    BA in CHEMISTRY (692827) MAP Sheet Department of Chemistry and Biochemistry For students entering Chemistry and Biochemistry Department requires the final 10 hours of required chemistry credit to be taken for graduation. Complete the following: Chem 111* Honors Principles of Chemistry Chem 112 Principles of Chemistry

  17. Synthesis and Structure Determination of Ferromagnetic Semiconductors LaAMnSnO6 (A = Sr Ba)

    SciTech Connect (OSTI)

    T Yang; T Perkisas; J Hadermann; M Croft; A Ignatov; M Greenblatt

    2011-12-31T23:59:59.000Z

    LaAMnSnO{sub 6} (A = Sr, Ba) have been synthesized by high temperature solid-state reactions under dynamic 1% H{sub 2}/Ar flow. Rietveld refinements on room temperature powder X-ray diffraction data indicate that LaSrMnSnO{sub 6} crystallizes in the GdFeO{sub 3}-structure, with space group Pnma and, combined with transmission electron microscopy, LaBaMnSnO{sub 6} in Imma. Both space groups are common in disordered double-perovskites. The Mn{sup 3+} and Sn{sup 4+} ions whose valence states were confirmed by X-ray absorption spectroscopy, are completely disordered over the B-sites and the BO{sub 6} octahedra are slightly distorted. LaAMnSnO{sub 6} are ferromagnetic semiconductors with a T{sub C} = 83 K for the Sr- and 66 K for the Ba-compound. The title compounds, together with the previously reported LaCaMnSnO{sub 6} provide an interesting example of progression from Pnma to Imma as the tolerance factor increases. An analysis of the relationship between space group and tolerance factor for the series LaAMnMO{sub 6} (A = Ca, Sr, Ba; M = Sn, Ru) provides a better understanding of the symmetry determination for double perovskites.

  18. Roadmap: Communication Studies -Applied Communication -Bachelor of Arts CI-BA-COMM-APCO

    E-Print Network [OSTI]

    Khan, Javed I.

    Roadmap: Communication Studies - Applied Communication - Bachelor of Arts CI-BA-COMM-APCO College Semester Eight [14 Credits] COMM 46092 Practicum in Applied Communication 3 C ELR COMM Concentration 39 36 2.250 2.000 #12;Roadmap: Communication Studies - Applied Communication - Bachelor of Arts CI

  19. NetTRUST: mixed NETworks Trust infrastRUcture baSed on Threshold cryptography

    E-Print Network [OSTI]

    Boyer, Edmond

    NetTRUST: mixed NETworks Trust infrastRUcture baSed on Threshold cryptography Mawloud Omar Re and the performance evaluation prove the adequacy of this solution to mixed networks architectures. Keywords to military applications), but the combination of ad-hoc networks with infrastructure based networks

  20. Thermodynamic model for the solubility of BaSeO4(cr) in the aqueous Ba2+-SeO42--Na+-H+-OH--H2O system: Extending to high selenate concentrations

    SciTech Connect (OSTI)

    Rai, Dhanpat; Felmy, Andrew R.; Moore, Dean A.; Kitamura, Akira; Yoshikawa, Hideki; Doi, Reisuke; Yoshida, Yasushi

    2014-09-15T23:59:59.000Z

    The solubility of Ba(SeO4, SO4) precipitates was determined as a function of the BaSeO4 mole fractions, ranging from 0.0015 to 0.3830, and time with an equilibration period extending to as long as 302 days. Equilibrium/steady state conditions in this system are reached in ? 65 days. Pitzer’s ion interaction model was used to calculate solid and aqueous phase activity coefficients. Thermodynamic analyses showed that the data do not satisfy Gibbs-Duhem equation, thereby demonstrating that a single-solid solution phase does not control both the selenate and sulfate concentrations. Our extensive data with log10 [Ba]) ranging from -3.6 to -5.9 mol.kg-1, log10 [SeO4]) ranging from -3.6 to -5.2 mol.kg-1, and log10 [SO4] ranging from -4.0 to -5.3 mol.kg-1 can be explained with the formation of an ideal BaSeO4 solid solution phase that controls the selenium concentrations and a slightly disordered/less-crystalline BaSO4(s) (log10 K0sp = -9.5 instead of -10.05 for barite) that controls the sulfate concentrations. In these experiments the BaSO4 component of the solid solution phase never reaches thermodynamic equilibrium with the aqueous phase. Thermodynamic interpretations of the data show that both the ideal BaSeO4 solid solution phase and less-crystalline BaSO4(s) phase are in equilibrium with each other in the entire range of BaSeO4 mole fractions investigated in this study.

  1. Pressure dependence of the superconducting critical temperature of Tl 2Ba 2Ca 2Cu 3O 10 y and Tl 2Ba 2Ca 3Cu 4O12 y up to 21 GPa

    E-Print Network [OSTI]

    Wijngaarden, Rinke J.

    Pressure dependence of the superconducting critical temperature of Tl 2Ba 2Ca 2Cu 3O 10 y and Tl 2 of the superconducting transition temperature Tc of Tl2Ba2Ca2Cu3O10 y Tl-2223 and Tl2Ba2Ca3Cu4O12 y Tl-2234 has been it is determined by that of the inner CuO2 layers. S0163-1829 96 07134-2 I. INTRODUCTION Superconductivity in high

  2. Quasi-zero lattice mismatch and band alignment of BaTiO{sub 3} on epitaxial (110)Ge

    SciTech Connect (OSTI)

    Hudait, M. K.; Zhu, Y.; Jain, N. [Bradley Department of Electrical and Computer Engineering, Virginia Tech, Blacksburg, Virginia 24061 (United States); Maurya, D.; Zhou, Y.; Priya, S [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2013-07-14T23:59:59.000Z

    Growth, structural, and band alignment properties of pulsed laser deposited amorphous BaTiO{sub 3} on epitaxial molecular beam epitaxy grown (110)Ge layer, as well as their utilization in low power transistor are reported. High-resolution x-ray diffraction demonstrated quasi-zero lattice mismatch of BaTiO{sub 3} on (110)Ge. Cross-sectional transmission electron microscopy micrograph confirms the amorphous nature of BaTiO{sub 3} layer as well as shows a sharp heterointerface between BaTiO{sub 3} and Ge with no traceable interfacial layer. The valence band offset, {Delta}E{sub v}, of 1.99 {+-} 0.05 eV at the BaTiO{sub 3}/(110)Ge heterointerface is measured using x-ray photoelectron spectroscopy. The conduction band offset, {Delta}E{sub c}, of 1.14 {+-} 0.1 eV is calculated using the bandgap energies of BaTiO{sub 3} of 3.8 eV and Ge of 0.67 eV. These band offset parameters for carrier confinement and the interface chemical properties of the BaTiO{sub 3}/(110)Ge system are significant advancement towards designing Ge-based p-and n-channel metal-oxide semiconductor field-effect transistors for low-power application.

  3. Synthesis, structural and magnetic characterisation of the fully fluorinated compound 6H-BaFeO{sub 2}F

    SciTech Connect (OSTI)

    Clemens, Oliver, E-mail: oliverclemens@online.de [School of Chemistry, University of Birmingham, Birmingham B15 2TT (United Kingdom)] [School of Chemistry, University of Birmingham, Birmingham B15 2TT (United Kingdom); Wright, Adrian J.; Berry, Frank J. [School of Chemistry, University of Birmingham, Birmingham B15 2TT (United Kingdom)] [School of Chemistry, University of Birmingham, Birmingham B15 2TT (United Kingdom); Smith, Ronald I. [ISIS Facility, Rutherford Appleton Laboratory, Harwell Oxford, Didcot, OX11 0QX (United Kingdom)] [ISIS Facility, Rutherford Appleton Laboratory, Harwell Oxford, Didcot, OX11 0QX (United Kingdom); Slater, Peter R. [School of Chemistry, University of Birmingham, Birmingham B15 2TT (United Kingdom)] [School of Chemistry, University of Birmingham, Birmingham B15 2TT (United Kingdom)

    2013-02-15T23:59:59.000Z

    The compound 6H-BaFeO{sub 2}F (P6{sub 3}/mmc) was synthesised by the low temperature fluorination of 6H-BaFeO{sub 3-d} using polyvinylidenedifluoride (PVDF) as a fluorination agent. Structural characterisation by XRD and NPD suggests that the local positions of the oxygen and fluorine atoms vary with no evidence for ordering on the anion sites. This compound shows antiferromagnetic ordering at room temperature with antiparallel alignment of the magnetic moments along the c-axis. The use of PVDF also allows the possibility of tuning the fluorine content in materials of composition 6H-BaFeO{sub 3-d}F{sub y} to any value of 0BaFeO{sub 2}F. Highlights: Black-Right-Pointing-Pointer The crystal structure of the hexagonal perovskite phase 6H-BaFeO{sub 2}F. Black-Right-Pointing-Pointer H-BaFeO{sub 2}F and 6H-BaFeO{sub 3-d}F{sub y} were prepared via low temperature fluorination using PVDF. Black-Right-Pointing-Pointer A structural investigation of the compounds BaFeO{sub 2}F is presented in detail. Black-Right-Pointing-Pointer This analysis suggests differences for the local coordination of O{sup 2-} and F{sup -} anions. Black-Right-Pointing-Pointer H-BaFeO{sub 2}F shows antiferromagnetic ordering at 300 K. Black-Right-Pointing-Pointer The magnetic moments align parallel to the a-axis.

  4. Synthesis, structural and magnetic characterisation of the fluorinated compound 15R-BaFeO{sub 2}F

    SciTech Connect (OSTI)

    Clemens, Oliver, E-mail: oliverclemens@online.de [School of Chemistry, The University of Birmingham, Birmingham B15 2TT (United Kingdom); Berry, Frank J. [School of Chemistry, The University of Birmingham, Birmingham B15 2TT (United Kingdom); Bauer, Jessica [Anorganische Festkörperchemie, Universität des Saarlandes, Am Markt, Zeile 3, 66125 Saarbrücken (Germany); Wright, Adrian J. [School of Chemistry, The University of Birmingham, Birmingham B15 2TT (United Kingdom); Knight, Kevin S. [ISIS Facility, Rutherford Appleton Laboratory, Harwell Oxford, Didcot OX11 0QX (United Kingdom); Slater, Peter R. [School of Chemistry, The University of Birmingham, Birmingham B15 2TT (United Kingdom)

    2013-07-15T23:59:59.000Z

    The compounds 15R-BaFeO{sub 2}F and 15R-BaFeO{sub 2.27}F{sub 0.5} have been synthesised by the low temperature fluorination of 15R-BaFeO{sub 3?d}F{sub 0.2} using polyvinylidenedifluoride (PVDF) as a fluorination agent. The materials have been structurally characterised by Rietveld analysis of the X-ray- and HRPD-powder neutron diffraction data. A detailed analysis of bond valence sums suggests that the oxide and fluoride ions order on the different anion sites. A reinvestigation of our recently published structure (Clemens et al., 2013) [34] of 6H-BaFeO{sub 2}F is also reported and incorporation of fluoride in h-type layers is also confirmed in this compound. The magnetic moments for 15R-BaFeO{sub 2}F and 15R-BaFeO{sub 2.25}F{sub 0.5} align in the a/b-plane with antiferromagnetic alignment of the moments between adjacent layers, and are flipped by 90° as compared to the precursor compound. 15R-BaFeO{sub 2}F exhibits very robust antiferromagnetism with a Néel temperature between 300 and 400 °C. - Graphical abstract: The crystal and magnetic structure of the perovskite phase 15R-BaFeO{sub 2}F. - Highlights: • 15R-BaFeO{sub 2}F and 15R-BaFeO{sub 2.27}F{sub 0.5}were prepared via low temperature fluorination using PVDF. • A structural investigation of the compounds BaFeO{sub 2}F is presented in detail. • This analysis suggests ordering of O{sup 2?} and F{sup ?} anions between different layers. • 15R-BaFeO{sub 2}F shows antiferromagnetic ordering at 300 K with T{sub N} ?300–400 °C. • The magnetic moments align in the a/b-plane.

  5. Molten salt synthesis of anisometric particles in the SrONb2O5BaO system

    E-Print Network [OSTI]

    Messing, Gary L.

    Molten salt synthesis of anisometric particles in the SrO­Nb2O5­BaO system Cihangir Duran* , Gary L.5Ba0.5Nb2O6, and SrNb2O6 were synthesized in the SrO­BaO­Nb2O5 system, using KCl or SrCl2Á6H2O salts the salt and Nb2O5. Large, irregularly shaped (Sr-rich) Sr2Nb2O7 particles formed with increasing reaction

  6. The elastic and piezoelectric properties of tungsten bronze ferroelectric crystals ,,Sr0.7Ba0.3...2NaNb5O15 and ,,Sr0.3Ba0.7...2NaNb5O15

    E-Print Network [OSTI]

    Cao, Wenwu

    The elastic and piezoelectric properties of tungsten bronze ferroelectric crystals ,,Sr0.7Ba0 and piezoelectric constants of tungsten bronze ferroelectric crystals Sr0.7Ba0.3 2NaNb5O15 SBNN70 and Sr0.3Ba0.7 2Na. INTRODUCTION Ferroelectric crystals with tungsten bronze structure are another attractive family beside

  7. Data:209b4880-04bc-4f18-9295-39ba0506f055 | Open Energy Information

    Open Energy Info (EERE)

    f18-9295-39ba0506f055 No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic...

  8. Infrared-optical spectroscopy of transparent conducting perovskite (La,Ba)SnO{sub 3} thin films

    SciTech Connect (OSTI)

    Seo, Dongmin; Yu, Kwangnam; Jun Chang, Young; Choi, E. J., E-mail: echoi@uos.ac.kr [Department of Physics, University of Seoul, Seoul 130-743 (Korea, Republic of); Sohn, Egon; Hoon Kim, Kee [Center for Novel States of Complex Materials Research, Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of)

    2014-01-13T23:59:59.000Z

    We have performed optical transmission, reflection, spectroscopic ellipsometry, and Hall effect measurements on the electron-doped La{sub x}Ba{sub 1–x}SnO{sub 3} (x?=?0.04) transparent thin films. From the infrared Drude response and plasma frequency analysis we determine the effective mass of the conducting electron m*?=?0.35m{sub 0}. In the visible-UV region the optical band gap shifts to high energy in (La,Ba)SnO{sub 3} by 0.18?eV compared with undoped BaSnO{sub 3} which, in the context of the Burstein-Moss analysis, is consistent with the infrared-m*. m* of BaSnO{sub 3} is compared with other existing transparent conducting oxides (TCO), and implication on search for high-mobility TCO compounds is discussed.

  9. Superconductivity at 34 K in the K/Ba/Bi/O system

    SciTech Connect (OSTI)

    Jones, N.L.; Parise, J.B.; Flippen, R.B.; Sleight, A.W. (E.I. DuPont de Nemours and Co., Wilmington, DE (USA))

    1989-02-01T23:59:59.000Z

    The critical temperature for superconductivity in the (Ba, K)BiO{sub 3} system has been increased to 34 K. With each such increase of T{sub c} in a system containing no copper it becomes increasingly likely that the mechanisms for superconductivity in the Bi-based and the Cu-based oxide superconductors are very closely related to each other. Since the (Ba, K)BiO{sub 3} superconductors possess the cubic perovskite structure, the mechanism for high T{sub c} would then not related directly to the two-dimensional character of the copper oxide superconductors or to the magnetism in such systems. 12 refs., 1 fig.

  10. User Defined Data in the New Analysis Model of the BaBar Experiment

    SciTech Connect (OSTI)

    De Nardo, G.

    2005-04-06T23:59:59.000Z

    The BaBar experiment has recently revised its Analysis Model. One of the key ingredient of BaBar new Analysis Model is the support of the capability to add to the Event Store user defined data, which can be the output of complex computations performed at an advanced stage of a physics analysis, and are associated to analysis objects. In order to provide flexibility and extensibility with respect to object types, template generic programming has been adopted. In this way the model is non-intrusive with respect to reconstruction and analysis objects it manages, not requiring changes in their interfaces and implementations. Technological details are hidden as much as possible to the user, providing a simple interface. In this paper we present some of the limitations of the old model and how they are addressed by the new Analysis Model.

  11. Optical properties of Pr-doped BaY{sub 2}F{sub 8}

    SciTech Connect (OSTI)

    Andrade, Adriano B., E-mail: abandrade1@gmail.com; Mello, Ana C. S. de; Valerio, Mário E. G. [Physics Department, Federal University of Sergipe, 49100-000 São Cristovão, SE (Brazil); Rezende, Marcos V. dos S. [Physics Department, Federal University of Sergipe, 49500-000 Itabaiana, SE (Brazil); Baldochi, Sonia L. [IPEN-CNEN/SP, CEP 11049, 05422-970 São Paulo, SP (Brazil)

    2014-08-07T23:59:59.000Z

    Crystalline samples of Pr-doped BaY{sub 2}F{sub 8} (BaYF) were prepared by zone melting technique. The pure phase obtained was identified by X-ray diffraction measurement. Optical absorption result was evaluated and it showed that the formation of the absorption bands can be connected to color centers generated by radiation in the matrix. Radioluminescence emission measurements after excitation by X-ray showed that the material exhibited components responsible for long lasting phosphorescence. Short decay times were also evaluated, the measurements showed a fast component around 70?ns associated to the 4f{sup 1}5d{sup 1} ? 4f{sup 2} transition of the Pr{sup 3+} ion. The Thermoluminescence (TL) results indicate the presence of two trapping centers.

  12. Zinc ferrite nanoparticles as MRI contrast agentsw Carlos Ba rcena,a

    E-Print Network [OSTI]

    Gao, Jinming

    Zinc ferrite nanoparticles as MRI contrast agentsw Carlos Ba´ rcena,a Amandeep K. Sra,a Girija S, a series of spinel-structured ferrites, MFe2O4 (M = Mn2+ , Fe2+ , Co2+ , Ni2+ ), were reported as novel MRI.e., Mn2+ occupies both A and B sites), whereas the other metal ferrites have an inverse spinel structure

  13. Lifshitz Transition and Chemical Instabilities in Ba1 xKxFe2As2 Superconductors

    SciTech Connect (OSTI)

    Khan, Suffian N. [University of Illinois, Urbana-Champaign] [University of Illinois, Urbana-Champaign; Johnson, Duane D. [University of Illinois, Urbana-Champaign] [University of Illinois, Urbana-Champaign

    2014-01-01T23:59:59.000Z

    Forsolid-solutionBa1 xKxFe2As2FermisurfaceevolutionismappedviaBlochspectralfunctionscalculatedusingdensityfunctionaltheoryimplementedinKorringa-Kohn-Rostokermultiplescatteringtheorywiththecoherent-potentialapproximation.Spectralfunctionsrevealelectronicdispersion,topology,orbitalcharacter,andbroadening(electron-lifetimeeffects)duetochemicaldisorder.Dissolutionofelectroncylindersoccursnearx 0.9withanonuniform,topological(Lifshitz)transition,reducingtheinterbandinteractions;yetthedispersionmaintainsitsdxzordyzcharacter.Formationenergiesindicatealloyingatx 0.35,asobserved,andatendencyforsegregationontheK-rich(x>0.6)side,explainingthedifficultyofcontrollingsamplequalityandtheconflictingresultsbetweencharacterizedelectronicstructures.OurresultsrevealFermisurfacetransitionsinalloyedsamplesthatinfluencestonodalsuperconductivityandsuggesttheoriginfordeviationsofcommontrendsinFe-basedsuperconductors,suchasBud ko-Ni-Canfieldscaling.

  14. Hydrostatic pressure (8 GPa) dependence of electrical resistivity of BaCo{sub 2}As{sub 2} single crystal

    SciTech Connect (OSTI)

    Ganguli, Chandreyee; Matsubayashi, Kazuyuki; Ohgushi, Kenya [Institute for Solid State Physics, The University of Tokyo, Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Uwatoko, Yoshiya, E-mail: uwatoko@issp.u-tokyo.ac.jp [Institute for Solid State Physics, The University of Tokyo, Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Kanagaraj, Moorthi [Centre for High Pressure Research, School of Physics, Bharathidasan University, Tiruchirappalli 620024 (India); Arumugam, Sonachalam, E-mail: sarumugam1963@yahoo.com [Centre for High Pressure Research, School of Physics, Bharathidasan University, Tiruchirappalli 620024 (India)

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: • Single crystals of BaCo{sub 2}As{sub 2} were grown by CoAs self-flux method. • We have studied pressure effects (8 GPa) on dc electrical resistivity of BaCo{sub 2}As{sub 2}. • On applied external pressure BaCo{sub 2}As{sub 2} remains a metallic state up to 8 GPa. • Superconductivity is absent in BaCo{sub 2}As{sub 2} because of its proximity to ferromagnetism. - Abstract: The pressure dependence of the electrical resistivity of BaCo{sub 2}As{sub 2} single crystal as a function of temperature was measured at ambient and high pressures up to 8 GPa for the first time using cubic anvil high pressure cell. It is observed that at room temperature the resistivity monotonically decreases with increasing pressure and it remains in the metallic state even at an applied pressure of 8 GPa. From the temperature dependence of the resistivity measurements under pressure, we found that superconductivity is absent up to 8 GPa. The value of the electron's scattering factor (A) is found to be large at ambient pressure and it decreases with the application of pressure, indicating that the substantial electron correlation effect of BaCo{sub 2}As{sub 2} is reduced under pressure, revealing a dramatic change of density of states at the Fermi energy.

  15. Two- and Three-Body Charmless B Decays at BaBar

    SciTech Connect (OSTI)

    Stracka, Simone; /Milan U. /INFN, Milan; ,

    2012-04-05T23:59:59.000Z

    We report recent measurements of rare charmless B decays performed by BaBar. The results are based on the final BaBar dataset of 424 fb{sup -1} collected at the PEP-II B-factory based at the SLAC National Accelerator Laboratory. The study of rare B decays is a key ingredient to meet two of the main goals of the B-factories: assessing the validity of the Cabibbo-Kobayashi-Maskawa (CKM) picture of CP-violation by precisely measuring the elements of the Unitarity Triangle (UT), and searching for hints of New Physics (NP), or otherwise constraining NP scenarios, in processes which are suppressed in the Standard Model (SM). In loop processes, in particular, NP at some higher energy scale may manifest itself in the low energy effective theory as new couplings, such as those introduced by new very massive virtual particles in the loop. In NP searches hadronic uncertainties can play a major role, expecially for branching fraction measurements. Many theoretical uncertainties cancel in ratios of amplitudes, and most NP probes are therefore of this kind. In the following sections we report recent measurements, performed by the BaBar Collaboration, that are relevant to NP searches in charmless hadronic B decays.

  16. The new barium zinc mercurides Ba{sub 3}ZnHg{sub 10} and BaZn{sub 0.6}Hg{sub 3.4} - Synthesis, crystal and electronic structure

    SciTech Connect (OSTI)

    Schwarz, Michael; Wendorff, Marco [Institut fuer Anorganische und Analytische Chemie, University of Freiburg, Albertstr. 21, D-79104 Freiburg (Germany)] [Institut fuer Anorganische und Analytische Chemie, University of Freiburg, Albertstr. 21, D-79104 Freiburg (Germany); Roehr, Caroline, E-mail: caroline@ruby.chemie.uni-freiburg.de [Institut fuer Anorganische und Analytische Chemie, University of Freiburg, Albertstr. 21, D-79104 Freiburg (Germany)] [Institut fuer Anorganische und Analytische Chemie, University of Freiburg, Albertstr. 21, D-79104 Freiburg (Germany)

    2012-12-15T23:59:59.000Z

    The title compounds Ba{sub 3}ZnHg{sub 10} and BaZn{sub 0.6}Hg{sub 3.4} were synthesized from stoichiometric ratios of the elements in Ta crucibles. Their crystal structures, which both represent new structure types, have been determined using single crystal X-ray data. The structure of Ba{sub 3}ZnHg{sub 10} (orthorhombic, oP28, space group Pmmn, a=701.2(3), b=1706.9(8), c=627.3(3)pm, Z=2, R1=0.0657) contains folded 4{sup 4} Hg nets, where the meshes form the bases of flat rectangular pyramids resembling the structure of BaAl{sub 4}. The flat pyramids are connected via Hg-Zn/Hg bonds, leaving large channels at the folds, in which Ba(1) and Hg(2) atoms alternate. Whereas the remaining Hg/Zn atoms form a covalent 3D network of three- to five-bonded atoms with short M-M distances (273-301 pm; CN 9-11), the Hg(2) atoms in the channels adopt a comparatively large coordination number of 12 and increased distances (317-348 pm) to their Zn/Hg neighbours. In the structure of BaZn{sub 0.6}Hg{sub 3.4} (cubic, cI320, space group I4{sup Macron }3d, a=2025.50(7) pm, Z=64, R1=0.0440), with a chemical composition not much different from that of Ba{sub 3}ZnHg{sub 10}, the Zn/Hg atoms of the mixed positions M(1/2) are arranged in an slightly distorted primitive cubic lattice with a 4 Multiplication-Sign 4 Multiplication-Sign 4 subcell relation to the unit cell. The 24 of the originating 64 cubes contain planar cis tetramers Hg(5,6){sub 4} with Hg in a nearly trigonal planar or tetrahedral coordination. In another 24 of the small cubes, two opposing faces are decorated by Hg(3,4){sub 2} dumbbells, two by Ba(2) atoms respectively. The third type of small cubes are centered by Ba(1) atoms only. The complex 3D polyanionic Hg/Zn network thus formed is compared with the Hg partial structure in Rb{sub 3}Hg{sub 20} applying a group-subgroup relation. Despite their different overall structures, the connectivity of the negatively charged Hg atoms, the rather metallic Zn bonding characteristic (as obtained from FP-LAPW band structure calculations) and the coordination number of 16 for all Ba cations relate the two title compounds. - Graphical abstract: Six of the 64 small sub-cubes of three types (A, B, C) forming the unit cell of the Hg-rich mercuride BaZn{sub 0.6}Hg{sub 3.4}. Highlights: Black-Right-Pointing-Pointer Two new Hg-rich Ba mercurides, both synthesized from the elements in pure phase. Black-Right-Pointing-Pointer BaZn{sub 0.6}HgG{sub 3.4} and Ba{sub 3}ZnHg{sub 10} with new complex structure types. Black-Right-Pointing-Pointer Structure relation to other complex cubic intermetallics. Black-Right-Pointing-Pointer Discussion of covalent and metallic bonding aspects, as found by the structure features and band structure calculations.

  17. Potential variations around grain boundaries in impurity-doped BaSi? epitaxial films evaluated by Kelvin probe force microscopy

    SciTech Connect (OSTI)

    Tsukahara, D.; Baba, M.; Honda, S.; Toko, K. [Institute of Applied Physics, University of Tsukuba, Tsukuba, Ibaraki 305-8573 (Japan); Imai, Y. [Institute of Applied Physics, University of Tsukuba, Tsukuba, Ibaraki 305-8573 (Japan); AIST, Tsukuba, Ibaraki 305-8565 (Japan); Hara, K. O.; Usami, N. [Graduate School of Engineering, Nagoya University, Nagoya 464-8603 (Japan); Japan Science and Technology Agency, CREST, Chiyoda, Tokyo 102-0075 (Japan); Werner, J. H. [Institute for Photovoltaics, University of Stuttgart, Stuttgart 70569 (Germany); Suemasu, T. [Institute of Applied Physics, University of Tsukuba, Tsukuba, Ibaraki 305-8573 (Japan); Japan Science and Technology Agency, CREST, Chiyoda, Tokyo 102-0075 (Japan); Institute for Photovoltaics, University of Stuttgart, Stuttgart 70569 (Germany)

    2014-09-28T23:59:59.000Z

    Potential variations around the grain boundaries (GBs) in antimony (Sb)-doped n-type and boron (B)-doped p-type BaSi? epitaxial films on Si(111) were evaluated by Kelvin probe force microscopy. Sb-doped n-BaSi? films exhibited positively charged GBs with a downward band bending at the GBs. The average barrier height for holes was approximately 10 meV for an electron concentration n ? 10¹? cm?³. This downward band bending changed to upward band bending when n was increased to n = 1.8 × 10¹?cm?³. In the B-doped p-BaSi? films, the upward band bending was observed for a hole concentration p ? 10¹?cm?³. The average barrier height for electrons decreased from approximately 25 to 15 meV when p was increased from p = 2.7 × 10¹? to p = 4.0 × 10¹? cm?³. These results are explained under the assumption that the position of the Fermi level E{sub f} at GBs depends on the degree of occupancy of defect states at the GBs, while E{sub f} approached the bottom of the conduction band or the top of the valence band in the BaSi? grain interiors with increasing impurity concentrations. In both cases, such small barrier heights may not deteriorate the carrier transport properties. The electronic structures of impurity-doped BaSi? are also discussed using first-principles pseudopotential method to discuss the insertion sites of impurity atoms and clarify the reason for the observed n-type conduction in the Sb-doped BaSi? and p-type conduction in the B-doped BaSi?.

  18. BaBar technical design report: Chapter 9, Magnet coil and flux return

    SciTech Connect (OSTI)

    O`Connor, T.; The BaBar Collaboration

    1995-03-01T23:59:59.000Z

    The BaBar magnet is a thin, 1.5 T superconducting solenoid with a hexagonal flux return. This chapter discusses the physics requirements and performance goals for the magnet, describes key interfaces, and summarizes the projected magnet performance. It also presents the design of the superconducting solenoid, including magnetic design, cold mass design, quench protection and stability, cold mass cooling, cryostat design, and coil assembly and transportation. The cryogenic supply system and instrumentation are described briefly, and the flux return is described.

  19. Magnetoelastically coupled structural, magnetic, and superconducting order parameters in BaFe?(As??xPx)?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kuo, H.-H.; Analytis, James G.; Chu, J.-H.; Fernandes, R. M.; Schmalian, J.; Fisher, I. R.

    2012-10-01T23:59:59.000Z

    We measure the transport properties of mechanically strained single crystals of BaFe?(As??xPx)? over a wide range of x. The Néel transition is extremely sensitive to stress and this sensitivity increases as optimal doping is approached (doping with the highest superconducting Tc), even though the magnetic transition itself is strongly suppressed. Furthermore, we observe significant changes in the superconducting transition temperature with applied strain, which mirror changes in the composition x. These experiments are a direct illustration of the intimate coupling between different degrees of freedom in iron-based superconductors, revealing the importance of magnetoelastic coupling to the magnetic and superconducting transition temperatures.

  20. Cation ordering transformations in Ba(Mg{sub 1/3}Ta{sub 2/3})O{sub 3}-BaZrO{sub 3} perovskite solid solutions

    SciTech Connect (OSTI)

    Chai, L.; Akbas, M.A.; Davies, P.K. [Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Materials Science and Engineering] [Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Materials Science and Engineering; Parise, J.B. [Univ. of New York, Stony Brook, NY (United States). Dept. of Earth and Space Sciences] [Univ. of New York, Stony Brook, NY (United States). Dept. of Earth and Space Sciences

    1997-09-01T23:59:59.000Z

    The effect of the substitution of BaZrO{sub 3} on the cation ordering in Ba(Mg{sub 1/3}Ta{sub 2/3})O{sub 3} was studied using TEM and X-ray and neutron diffraction. Almost no solubility of Zr was found in the 1:2 ordered, trigonal structure of the Ba(Mg{sub 1/3}Ta{sub 2/3})O{sub 3} end-member (P{bar 3}m1), and a transformation to a 1:1 ordered, cubic (Fm{bar 3}m) phase with a = 2a{sub per} occurs for substitution levels between {approximately}10 and 25 mol% BaZrO{sub 3}. The structure of this Ba({beta}{prime}{sub 1/2}{beta}{double_prime}{sub 1/2})O{sub 3}-type phase consists of two distinct octahedral sites, {beta}{prime} and {beta}{double_prime}. The occupancies of the two cation positions, refined using the Rietveld method, were found to be consistent with a random site model in which {beta}{double_prime} is occupied by Ta, and {beta}{prime} by a random distribution of the remaining cations. The homogeneity range of the 1:1 solid solutions predicted by this model, Ba{l_brace}[Mg{sub (2{minus}y)/3} Ta{sub (1{minus}2y)/3} Zr{sub y}]{sub 1/2}[Ta]{sub 1/2}{r_brace}O{sub 3} (0.0 < y {le} 0.5), is in excellent agreement with that observed experimentally.

  1. High temperature crystal structures and superionic properties of SrCl{sub 2}, SrBr{sub 2}, BaCl{sub 2} and BaBr{sub 2}

    SciTech Connect (OSTI)

    Hull, Stephen, E-mail: stephen.hull@stfc.ac.uk [The ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Norberg, Stefan T. [The ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Ahmed, Istaq; Eriksson, Sten G. [Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Mohn, Chris E. [Department of Chemistry and Centre for Materials Science and Nanotechnology, University of Oslo, P.O. Box 1033 Blindern, N-0315 Oslo (Norway)

    2011-11-15T23:59:59.000Z

    The structural properties of the binary alkaline-earth halides SrCl{sub 2}, SrBr{sub 2}, BaCl{sub 2} and BaBr{sub 2} have been investigated from ambient temperature up to close to their melting points, using the neutron powder diffraction technique. Fluorite-structured SrCl{sub 2} undergoes a gradual transition to a superionic phase at 900-1100 K, characterised by an increasing concentration of anion Frenkel defects. At a temperature of 920(3) K, the tetragonal phase of SrBr{sub 2} undergoes a first-order transition to a cubic fluorite phase. This high temperature phase shows the presence of extensive disorder within the anion sublattice, which differs from that found in superionic SrCl{sub 2}. BaCl{sub 2} and BaBr{sub 2} both adopt the cotunnite crystal structure under ambient conditions. BaCl{sub 2} undergoes a first-order structural transition at 917(5) K to a disordered fluorite-structured phase. The relationship between the (disordered) crystal structures and the ionic conductivity behaviour is discussed and the influence of the size of the mobile anion on the superionic behaviour is explored. - Graphical abstract: Anomalous behaviour of the lattice expansion of SrCl{sub 2} at temperatures of {approx}1000 K is associated with the gradual transition to a superionic phase, whilst SrBr{sub 2} undergoes a first-order structural transition ({beta}{yields}{alpha}) to a fluorite-structured superionic phase at 920(3) K. Highlights: > Anomalous behaviour of the lattice expansion of SrCl{sub 2} occurs at temperatures {approx}1000 K. > Crystal structure of {beta}-SrBr{sub 2} is described in detail. > On heating, SrBr{sub 2} and BaCl{sub 2} transform to a fluorite-structured superionic phase. > Temperature dependence of the BaCl{sub 2} and BaBr{sub 2} structures is presented. > Nature of the superionic phases within the alkaline-earth halides is discussed.

  2. Avoided Quantum Criticality and Magnetoelastic Coupling in BaFe2-xNixAs2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Xingye; Gretarsson, H.; Zhang, Rui; Liu, Xuerong; Luo, Huiqian; Tian, Wei; Laver, Mark; Yamani, Z.; Kim, Young-June; Nevidomskyy, A. H.; Si, Qimiao; Dai, Pengcheng

    2013-06-01T23:59:59.000Z

    We study the structural and magnetic orders in electron-doped BaFe2?xNixAs2 by high-resolution synchrotron x-ray and neutron scatterings. Upon Ni doping x, the nearly simultaneous tetragonal-to-orthorhombic structural (Ts) and antiferromagnetic (TN) phase transitions in BaFe2As2 are gradually suppressed and separated, resulting in Ts>TN with increasing x, as was previously observed. However, the temperature separation between Ts and TN decreases with increasing x for x?0.065, tending toward a quantum bicritical point near optimal superconductivity at x?0.1. The zero-temperature transition is preempted by the formation of a secondary incommensurate magnetic phase in the region 0.088?x?0.104, resulting in a finite value of TN?Tc+10??K above the superconducting dome around x?0.1. Our results imply an avoided quantum critical point, which is expected to strongly influence the properties of both the normal and superconducting states.

  3. $(h_{11/2})^2$ alignments in neutron-rich $^{132}$Ba with negative-parity pairs

    E-Print Network [OSTI]

    Yang Lei; Zhengyu Xu

    2015-03-01T23:59:59.000Z

    The shell-model collective-pair truncation with negative-parity pairs is adopted to study the $(h_{11/2})^2$ alignment in $^{132}$Ba. The proton $(h_{11/2})^2$-alignment state is predicted as an $E\\sim4.6$ MeV and $\\tau\\sim 0.5~\\mu$s isomer with relatively strong E3 decay channels. The oblately deformed neutron $(h_{11/2})^{-2}$ alignment in the yrast band and four negative-parity bands are confirmed, even although two of these negative-parity bands favor the prolate deformation, which directly manifests the $\\gamma$ unstability of $^{132}$Ba.

  4. Evidence for a phosphorylation-independent role for Ser 32 and 36 in proteasome inhibitor-resistant (PIR) InBa degradation in B cells

    E-Print Network [OSTI]

    Miyamoto, Shigeki

    -resistant (PIR) InBa degradation in B cells Shelby O'Connor, Stephanie Markovina, Shigeki MiyamotoT Program is maintained through proteasome inhibitor-resistant (PIR) InBa degradation in a manner that requires Ser 32 whether dual phosphorylation of Ser 32 and 36 was required for PIR degradation. Through mutagenesis

  5. Page 1 | B.A. in Special Education (General Curriculum) and Elementary Education (K-6) Dual Major | Academic Plan of Study

    E-Print Network [OSTI]

    Raja, Anita

    | Academic Plan of Study Updated May 2014 B.A. in Special Education (General Curriculum) and ElementaryPage 1 | B.A. in Special Education (General Curriculum) and Elementary Education (K-6) Dual Major Education (K-6) Dual Program Academic Plan of Study College of Education Department of Special Education

  6. Studies on catalytic and structural properties of BaRuO3 type perovskite1 material for diesel soot oxidation2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Studies on catalytic and structural properties of BaRuO3 type perovskite1 material for diesel by co-precipitation24 method and its catalytic activity has been tested for diesel soot oxidation processes and vehicle exhaust.33 Key words: BaRuO3, perovskite, diesel soot oxidation, vehicular exhaust

  7. Controlling internal barrier in low loss BaTiO3 supercapacitors U-C. Chung, C. Elissalde, S. Mornet and M. Maglione

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Controlling internal barrier in low loss BaTiO3 supercapacitors U-C. Chung, C. Elissalde, S Supercapacitor behavior has been reported in a number of oxides including reduced BaTiO3 ferroelectric ceramics to process bulk composites having supercapacitor features with low dielectric losses and temperature

  8. TOPIC TIME LOCATION CATEGORY TITLE AUTHORS INSTITUTION Advanced Energy Systems 10:15 to 10:35 AM BA1180 CSME

    E-Print Network [OSTI]

    :30 to 11:45 AM BA2139 CSME An Autonomous Vehicle for Navigation and Path Following in Outdoor Farms F FUEL CELL ELECTRODES S. M. R. Niya ,M. Hoorfar University of British Columbia Advanced Energy Systems 4:05 to 4:25 PM BA1180 CSME Effect of Hygrothermal Fatigue on Damage Propagation in PEM Fuel Cell Membrane R

  9. Guided wave absorption and uorescence in epitaxial Er:BaTiO3 on MgO D.M. Gilla,*, G.M. Fordb

    E-Print Network [OSTI]

    Ho, Seng-Tiong

    . Keywords: Er:BaTiO3; Fluorescence; Luminescence 1. Introduction The development of low-cost composite waveguides fabricated in erbium-doped thin-®lm epitaxial BaTiO3. Luminescence transient measurements indicate strategies toward the realization of this type of opto-electronic circuit. Proposed designs of hybrid opto

  10. 11196. Proposed by Mohammad Hossein Mehrabi, Iran University of Science and Technology, Tehran, Iran. Let A and B be real n n matrices. Show that if AB -BA is invertible and A2

    E-Print Network [OSTI]

    Heckman, Christopher Carl

    11196. Proposed by Mohammad Hossein Mehrabi, Iran University of Science and Technology, Tehran, Iran. Let A and B be real n Ã? n matrices. Show that if AB - BA is invertible and A2 + B2 = 3(AB - BA

  11. Isotopic and internal CX{sub 3} (X=D,H) rotational motion effects in the Ba{center_dot}{center_dot}{center_dot}FCX{sub 3}+h{nu}{yields}BaF+CX{sub 3} intracluster reactions

    SciTech Connect (OSTI)

    Rinaldi, C. A.; Gasmi, K.; Skowronek, S.; Gonzalez Urena, A. [Unidad de Laseres y Haces Moleculares, Instituto Pluridisciplinar, Universidad Complutense de Madrid, Paseo Juan XXIII-1, 28040 Madrid (Spain)

    2006-06-28T23:59:59.000Z

    Photodepletion and action spectra of the laser-induced Ba{center_dot}{center_dot}{center_dot}FCD{sub 3} fragmentation have been measured over the 16 075-16 380 cm{sup -1} range. The observed band and peak structures allowed us to estimate the vibrational and rotational structures of the excited complex at the transition state configuration. The relative reaction probability P{sub R}(E) for the intracluster Ba{center_dot}{center_dot}{center_dot}FCD{sub 3}+h{nu}{yields}BaF+CD{sub 3} reaction has been determined over the cited energy range. P{sub R}(E) shows a peak structure with an energy spacing of 8.9 cm{sup -1} which was attributed to an internal rotation of the CD{sub 3} group in the intermediate state. A comparison with previous Ba{center_dot}{center_dot}{center_dot}FCH{sub 3} photofragmentation spectra reveals the dynamical role of the internal CX{sub 3} (X=H,D) motion which is manifested by the presence of rotational resonances in the laser-induced intracluster reaction.

  12. Topics for BA and MA Theses at the chair of Prof. Klasen The list below gives contains proposals for Bachelor (BA) and Master (MA) thesis topics. You can also

    E-Print Network [OSTI]

    Krivobokova, Tatyana

    (mainly case study of Indonesia) BA/MA Causality between economic development, energy consumption: Trends in migration and land use change: Does reverse causality exist? Evidence from the Indonesian Filipiak, Ute: Household Finance and Consumption in Europe: Culture Clash between North and South? MA

  13. Measurement of the Forward-Backward Charge Asymmetry and Extraction of sin(2) ?[eff over W] in pp-bar?Z/?*+X?e(+)e(?)+X Events Produced at s?=1.96??TeV

    E-Print Network [OSTI]

    Baringer, Philip S.; Bean, Alice; Hensel, Carsten; Clutter, Justace Randall; Moulik, Tania; Wilson, Graham Wallace; Abazov, V. M.; Abbott, B.; Abolins, M.; Acharya, B. S.; Adams, M.

    2008-11-06T23:59:59.000Z

    is measured as a function of the invariant mass of the electron-positron pair, and found to be consistent with the standard model prediction. We use the AFB measurement to extract the effective weak mixing angle sin(2)?[eff over W]=0.2326±0.0018(stat)±0.0006...

  14. European Photovoltaic Solar Energy Conference, Valencia, Spain, 6-10 September 2010, 2AO.2.3 EFFECT OF SiN DEPOSITION TEMPERATURE ON SURFACE PASSIVATION OF N-TYPE CZ SILICON

    E-Print Network [OSTI]

    25th European Photovoltaic Solar Energy Conference, Valencia, Spain, 6-10 September 2010, 2AO.2N deposition leads to increasing the hydrogen content of the SiN layers. This improves the supply of hydrogen silicon using thermally grown oxide or amorphous films based on hydrogenated silicon compounds has been

  15. Hall-Coefficient for Oriented Tl2ba2cacu2o8+delta Thin-Films

    E-Print Network [OSTI]

    WANG, PS; WILLIAMS, JC; RATHNAYAKA, KDD; HENNINGS, BD; Naugle, Donald G.; KAISER, AB.

    1993-01-01T23:59:59.000Z

    Measurements of the Hall coefficient and resistivity for highly oriented Tl2Ba2CaCu2O8+delta thin films are reported. The temperature dependence of cotTHETA(H), where THETA(H) is the normal-state Hall angle, for a single-phase (2:2:1:2) film sample...

  16. Roadmap: Pan-African Studies Pan-African Studies Bachelor of Arts [AS-BA-PAS-PAS

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Pan-African Studies ­ Pan-African Studies ­ Bachelor of Arts [AS-BA-PAS-PAS] College: 22-Apr-13/LNHD This roadmap is a recommended semester-by-semester plan of study for this major Non-PAS Elective 3 General Elective (upper division) 9 #12;Roadmap: Pan-African Studies ­ Pan

  17. Electron irradiation of Co, Ni, and P-doped BaFe2As2type iron-based superconductors

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ± superconductivity in the multiband iron-based superconductors [1, 2], with a sign-changing order parameter betweenElectron irradiation of Co, Ni, and P-doped BaFe2As2­type iron-based superconductors Cornelis-scale point-like disorder on superconductivity in these materials [5, 6]. In particular, interband scattering

  18. Office of the Faculty of Engineering Syllabus for the Degree Project for the B.A. in Industrial Design

    E-Print Network [OSTI]

    Office of the Faculty of Engineering Syllabus for the Degree Project for the B.A. in Industrial Design Approved by the Board of the Faculty of Engineering on 2nd March 2009 and valid from 1 st January of compulsory courses that can be accredited to the degree of Bachelor of Arts in Industrial Design. Exemption

  19. Hysteresis analysis of CoTi substituted M-type BaSr hexagonal ferrite Charanjeet Singh a,

    E-Print Network [OSTI]

    Koledintseva, Marina Y.

    Hysteresis analysis of Co­Ti substituted M-type Ba­Sr hexagonal ferrite Charanjeet Singh a, , S.5Sr0.5CoxTixFe(12 - 2x)O19 ferrite have been investigated by XRD, SEM and VSM. XRD and SEM confirm M ferrites are known for their strong uniaxial magne- tocrystalline anisotropy with ease of magnetization

  20. Computer Science Educational Effectiveness Assessment Plan Page 1 of 23 B.S., B.A, Minor in Computer Science

    E-Print Network [OSTI]

    Mock, Kenrick

    Computer Science Educational Effectiveness Assessment Plan Page 1 of 23 B.S., B.A, Minor in Computer Science Educational Effectiveness Assessment Plan Version 1.3 Adopted by The Computer Science of Academic Affairs: #12;Computer Science Educational Effectiveness Assessment Plan Page 2 of 23 TABLE

  1. High temperature thermoelectric properties of Czochralski-pulled Ba8Ga16Ge30 M. Christensen1

    E-Print Network [OSTI]

    High temperature thermoelectric properties of Czochralski-pulled Ba8Ga16Ge30 M. Christensen1 , G, Pasadena, California 91125 Abstract High temperature thermoelectric properties have been measured/m-K around 900K, and ZT reaches a maximum of 0.9 at 1000 K. Introduction The interest in thermoelectric

  2. Oval BA (and the Great Red Spot) extend down to a supersolar water cloud layer in Jupiter's atmosphere

    E-Print Network [OSTI]

    Marcus, Philip S.

    Oval BA (and the Great Red Spot) extend down to a supersolar water cloud layer in Jupiter in Jupiter's troposphere, with stable layers near cloud bases [4,6,7]. We use these two results to determine horizontal band in Fig. 2 shows that vortex- model derived static stability (white bars) is consistent

  3. PETROGRAPHY AND CHEMISTRY OF IMPACT-MELT CLASTS IN APOLLO 16 BRECCIAS. B.A. , S.J. Symes2

    E-Print Network [OSTI]

    Cohen, Barbara Anne

    PETROGRAPHY AND CHEMISTRY OF IMPACT-MELT CLASTS IN APOLLO 16 BRECCIAS. B.A. Cohen1 , S.J. Symes2 samples of unequivocal impact origin, from either the Apollo collection or lunar meteorites, suggest of samples, impact melts and crystalline lunar spherules (CLS) within demonstrably old Apollo breccias

  4. La-doped BaTiO{sub 3} heterostructures: Compensating the polarization discontinuity

    SciTech Connect (OSTI)

    Kumah, D. P.; Clarke, R., E-mail: royc@umich.edu [Applied Physics Program, University of Michigan, Ann Arbor, Michigan 48109 (United States); Yacoby, Y. [Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel); Pauli, S. A.; Willmott, P. R. [Swiss Light Source, Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland)

    2013-12-01T23:59:59.000Z

    We demonstrate a route to manipulate the polarization and internal electric field of a complex oxide heterostructure using a layering sequence based on the LaAlO{sub 3}-SrTiO{sub 3} interface. By combining sensitive atomic-level mapping of the structure using direct x-ray phase-retrieval methods with theoretical modeling of the electrostatic charge and polarization, we have devised a novel single-domain polar heterostructure. We find that ionic rearrangement results in strain and free energy minimization, and eliminates the polarization discontinuity leading to a two-fold increase of the spontaneous polarization towards the surface of an ultra-thin single-domain BaTiO{sub 3} film.

  5. Microscopic description of spherical to {gamma}-soft shape transitions in Ba and Xe nuclei

    SciTech Connect (OSTI)

    Li, Z. P. [State Key Laboratory of Nuclear Physics and Technology, School of Physics, Peking University, Beijing 100871 (China); Physics Department, Faculty of Science, University of Zagreb, 10000 Zagreb (Croatia); Niksic, T.; Vretenar, D. [Physics Department, Faculty of Science, University of Zagreb, 10000 Zagreb (Croatia); Meng, J. [State Key Laboratory of Nuclear Physics and Technology, School of Physics, Peking University, Beijing 100871 (China); School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China)

    2010-03-15T23:59:59.000Z

    The rapid transition between spherical and {gamma}-soft shapes in Ba and Xe nuclei in the mass region A>=130 is analyzed using excitation spectra and collective wave functions obtained by diagonalization of a five-dimensional Hamiltonian for quadrupole vibrational and rotational degrees of freedom, with parameters determined by constrained self-consistent relativistic mean-field calculations for triaxial shapes. The results reproduce the characteristic evolution of excitation spectra and E2 transition probabilities, and in general, a good agreement with available data is obtained. The calculated spectra display fingerprints of a second-order shape phase transition that can approximately be described by analytic solutions corresponding to the E(5) dynamical symmetry.

  6. Precipitation method for barium metaborate (BaB{sub 2}O{sub 4}) synthesis from borax solution

    SciTech Connect (OSTI)

    Ak?ener, Eymen; Figen, Aysel Kantürk; Pi?kin, Sabriye [Yildiz Technical University, Chem. Eng. Dept., Davutpasa Campus, 34210, Istanbul (Turkey)

    2013-12-16T23:59:59.000Z

    In this study, barium metaborate (BaB{sub 2}O{sub 4}, BMB) synthesis from the borax solution was carried out. BMB currently is used in production of ceramic glazes, luminophors, oxide cathodes as well as additives to pigments for aqueous emulsion paints and also ??BaB{sub 2}O{sub 4} single crystals are the best candidate for fabrication of solid-state UV lasers operating at a wavelength of 200 nm due to excellent nonlinear optical properties. In the present study, synthesis was carried out from the borax solution (Na{sub 2}B{sub 4}O{sub 7?}10H{sub 2}O, BDH) and barium chloride (BaCI{sub 2?}2H{sub 2}O, Ba) in the glass-batch reactor with stirring. The effect of, times (5-15 min), molar ratio [stoich.ration (1.0:2.0), 1.25:2.0, 1.5:2.0, 2.5:2:0, 3.0:2.0, 3.5:2.0,4.0:2.0, 5.0:2.0] and also crystallization time (2-6 hour) on the BMB yield (%) was investigated at 80 °C reaction temperature. It is found that, BMB precipitation synthesis with 90 % yield can be performed from 0.50 molar ration (BDH:Ba), under 80 °C, 15 minute, and 6 hours crystallization time. The structural properties of BMB powders were characterized by using XRD, FT-IR and DTA-TG instrumental analysis technique.

  7. Investigation of novel decay B _____ ____(2S)____K at BaBar

    SciTech Connect (OSTI)

    Schalch, Jacob; /Oberlin Coll. /SLAC

    2011-06-22T23:59:59.000Z

    We investigate the undocumented B meson decay, B{sup +} {yields} {Psi}(2S){omega}K{sup +}. The data were collected with the BaBar detector at the SLAC PEP-II asymmetric-energy e{sup +}e{sup -} collier operating at the {gamma}(4S) resonance, a center-of-mass energy of 10.58 GeV/c{sup 2}. The {gamma}(4S) resonance primarily decays to pairs of B-mesons. The BaBar collaboration at the PEP-II ring was located at the SLAC National Accelerator Laboratory and was designed to study the collisions of positrons and electrons. The e{sup -}e{sup +} pairs collide at asymmetric energies, resulting in a center of mass which is traveling at relativistic speeds. The resulting time dilation allows the decaying particles to travel large distances through the detector before undergoing their rapid decays, a process that occurs in the in the center of mass frame over extremely small distances. As they travel through silicon vertex trackers, a drift chamber, a Cerenkov radiation detector and finally an electromagnetic calorimeter, we measure the charge, energy, momentum, and particle identification in order to reconstruct the decays that have occurred. While all well understood mesons currently fall into the qq model, the quark model has no a priori exclusion of higher configuration states such as qqqq which has led experimentalists and theorists alike to seek evidence supporting the existence of such states. Currently, there are hundreds of known decay modes of the B mesons cataloged by the Particle Data Group, but collectively they only account for approximately 60% of the B branching fraction and it is possible that many more exist.

  8. Investigations of Ba{sub x}Sr{sub 1?x}TiO{sub 3} ceramics and powders prepared by direct current arc discharge technique

    SciTech Connect (OSTI)

    Li, Shuangbin; Wang, Xiaohan [Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Yao, Ying, E-mail: yaoy1125@hotmail.com; Jia, Yongzhong; Xie, Shaolei; Jing, Yan [Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008 (China); Yuzyuk, Yu. I. [Faculty of Physics, Southern Federal University, 5, Zorge str., Rostov-on-Don 344090 (Russian Federation)

    2014-09-01T23:59:59.000Z

    Ba{sub x}Sr{sub 1?x}TiO{sub 3} ceramics with x ranging from 0 to 1 were prepared by direct current arc discharge technique and studied by means of x-ray diffraction (XRD) and Raman spectroscopy. The cubic-tetragonal ferroelectric phase transition in Ba{sub x}Sr{sub 1?x}TiO{sub 3} ceramics was found to occur at x???0.75. XRD investigation of as-grown BaTiO{sub 3} ceramics revealed co-existence of tetragonal and hexagonal modifications with a small amount of impurity phase BaTi{sub 4}O{sub 9}. No evidences of hexagonal phase were observed in Raman spectra of as-grown BaTiO{sub 3} ceramics, while Raman peaks related to hexagonal phase were clearly observed in the spectrum of fine-grain powders prepared from the same ceramics. A core-shell model for BaTiO{sub 3} ceramics prepared by direct current arc discharge technique is proposed. Absence of the hexagonal phase in any Ba{sub x}Sr{sub 1?x}TiO{sub 3} solid solution with x?

  9. Novel kinds of down/up-conversion luminescent rare earth doped fluoride BaMgF{sub 4}: RE{sup 3+} microcrystals

    SciTech Connect (OSTI)

    Yan, Zhi-Yuan; Yan, Bing, E-mail: byan@tongji.edu.cn; Jia, Li-Ping

    2013-10-15T23:59:59.000Z

    Graphical abstract: We achieve the liquid phase chemical synthesis of rare earth fluoride system BaMgF4: RE{sup 3+} microphosphors, which realize down/up-conversion luminescence. - Highlights: • Doped BaMgF{sub 4} microphosphors are firstly prepared by hydrothermal process. • Doped BaMgF{sub 4} nanosheets are firstly prepared by high temperature solution reaction. • The down-conversion luminescence is realized in the rare earth doped BaMgF{sub 4}. • The upconversion luminescence is realized in the rare earth doped BaMgF{sub 4}. - Abstract: In this paper, we realize the liquid-phase chemical synthesis of high-quality orthorhombic polycrystalline BaMgF{sub 4}: RE{sup 3+} (RE = Eu, Tb, Sm, Dy, Yb–Er/Tm) compounds with hydrothermal and high-temperature solution methods, respectively. The products from hydrothermal technology show the micrometer size while the products from hydrothermal technology present nanosheet morphology. The rare earth ions doped BaMgF{sub 4} from hydrothermal synthesis are discussed in details, which can realize the downconversion luminescence for doped Eu{sup 3+} or Tb{sup 3+} and upconversion luminescence for Yb{sup 3+}/Er{sup 3+} (Tm{sup 3+}), respectively. To our knowledge, the hydrothermal or high temperature solution synthesis and photoluminescence (Eu{sup 3+}, Tb{sup 3+} or Yb{sup 3+}/Er{sup 3+}(Tm{sup 3+})) of these fluoride systems are firstly reported.

  10. Coordinated Fee Structure for Developed Recreation Sites on the Ashley, Uinta, and Wasatch-Cache

    E-Print Network [OSTI]

    Standiford, Richard B.

    Federal and State agencies and private campgrounds in geographical areas of concern to determine fee, such as water, sewer, electricity and recreational equipment/infrastructure. 1 An abbreviated version

  11. A better understanding of a Uinta Basin channelized analog reservoir through geostatistics and reservoir simulation

    E-Print Network [OSTI]

    Robbana, Enis

    2002-01-01T23:59:59.000Z

    Mahogany oil-shale bed Middle marker NC Jacks Canyon A' Sunnyside Peters Point Fh Tar sand Miural Bu tes pa 'ette Bench Altamom-Bluebell Field (A. B) island Ouchesne, Monument Redwash Field (Rwl soco Horseshoe Bend ''';&&, or sir K] Marginal...

  12. Data:85ed0bec-9f0b-4c0c-b7df-7552714728ba | Open Energy Information

    Open Energy Info (EERE)

    b-4c0c-b7df-7552714728ba No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic...

  13. Data:D2d5e5ec-0361-4cdb-8855-0ee359ba1f27 | Open Energy Information

    Open Energy Info (EERE)

    5-0ee359ba1f27 No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic Information...

  14. Data:8e449c5c-00e4-47a0-ba6d-17eeb6c671f8 | Open Energy Information

    Open Energy Info (EERE)

    ba6d-17eeb6c671f8 No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic...

  15. Structural and magnetic properties and superconductivity in Ba(Fe{sub 1-x}TM{sub x}){sub 2}As{sub 2}

    SciTech Connect (OSTI)

    Thaler, Alexander

    2012-07-23T23:59:59.000Z

    We studied the effects on structural and magnetic phase transitions and the emergence of superconductivity in transition metal substituted BaFe{sub 2}As{sub 2}. We grew four series of Ba(Fe{sub 1-x}TM{sub x}){sub 2}As{sub 2} (TM=Ru, Mn, Co+Cr and Co+Mn) and characterized them by crystallographic, magnetic and transport measurements. We also subjected Ba(Fe{sub 1-x}Cr{sub x}){sub 2}As{sub 2} and Ba(Fe{sub 1-x}Co{sub x}){sub 2}As{sub 2} to heat treatment to explore what changes might be induced.

  16. Data:5fec70a4-9a2b-44ba-9633-a56fd0275901 | Open Energy Information

    Open Energy Info (EERE)

    fec70a4-9a2b-44ba-9633-a56fd0275901 No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading......

  17. Data:07657709-0dbd-4f7d-9ba5-16de8191e070 | Open Energy Information

    Open Energy Info (EERE)

    d-9ba5-16de8191e070 No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic...

  18. Is the Communicative Language Teaching Approach More Effective Than the Grammar Translation Method at Teaching the Ba-Construction in Mandarin Chinese to American Undergraduate Students?

    E-Print Network [OSTI]

    Wang, Jun

    2013-12-31T23:59:59.000Z

    (CLT) with that of Grammar Translation Method (GT) at teaching Chinese as a foreign language (CFL). The present study fills this gap. The purpose of this study is to investigate quantitatively which method is more effective at teaching the ba...

  19. Temperature and composition phase diagram in the iron-based ladder compounds Ba 1 - x Cs x Fe 2 Se 3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hawai, Takafumi; Nambu, Yusuke; Ohgushi, Kenya; Du, Fei; Hirata, Yasuyuki; Avdeev, Maxim; Uwatoko, Yoshiya; Sekine, Yurina; Fukazawa, Hiroshi; Ma, Jie; Chi, Songxue; Ueda, Yutaka; Yoshizawa, Hideki; Sato, Taku J.

    2015-05-01T23:59:59.000Z

    We investigated the iron-based ladder compounds (Ba,Cs)Fe?Se?. Their parent compounds BaFe?Se? and CsFe?Se? have different space groups, formal valences of Fe, and magnetic structures. Electrical resistivity, specific heat, magnetic susceptibility, x-ray diffraction, and powder neutron diffraction measurements were conducted to obtain a temperature and composition phase diagram of this system. Block magnetism observed in BaFe?Se? is drastically suppressed with Cs doping. In contrast, stripe magnetism observed in CsFe?Se? is not so fragile against Ba doping. A new type of magnetic structure appears in intermediate compositions, which is similar to stripe magnetism of CsFe?Se?, but interladder spin configuration is different. Intermediate compounds show insulating behavior, nevertheless a finite T-linear contribution in specific heat was obtained at low temperatures.

  20. JOURNAL DE PHYSIQUE Colfoque Cl, supplkrnent au no 4, Tome 38, Auril 1977, page Cl-333 METAL-OXIDES COMPOSITES FOR BaFe,,Ol PERMANENT MAGNETS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    the possibility of producing composites of Ba ferrite with various metals such as cobalt, nickel, iron, copper of a CO deposit with preferential orientation obtained by chemical reduction and electrodeposition. 2. CO

  1. Heat capacity of the site-diluted spin dimer system Ba?(Mn1-xVx)?O?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

    2011-08-01T23:59:59.000Z

    Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba?(Mn1-xVx)?O?. The parent compound Ba?Mn?O? is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d² Mn?? ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d? V?? ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0?x?0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for a phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.

  2. Coherency strain enhanced dielectric-temperature property of rare-earth doped BaTiO{sub 3}

    SciTech Connect (OSTI)

    Jeon, Sang-Chae; Kang, Suk-Joong L. [Materials Interface Laboratory, Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 373-1, Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)] [Materials Interface Laboratory, Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 373-1, Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)

    2013-03-18T23:59:59.000Z

    Core/shell-grained BaTiO{sub 3} samples were prepared with addition of rare earth elements. The core/shell interface was semi-coherent, and many misfit dislocations formed in Dy-doped samples. In contrast, a coherent interface and few dislocations were observed in Ho- and Er-doped samples. Dy-doped samples exhibited poor temperature stability, showing a peak with no frequency dispersion. Ho- and Er-doped samples exhibited a broad curve with frequency dispersion. This improved temperature stability is attributed to the coherency strain, which leads to the formation of polar nano-regions in the shell. Coherency at the core/shell interface is critical to improve the temperature stability of core/shell-structured BaTiO{sub 3}.

  3. Two-dimensional resonant magnetic excitation in BaFe1.84Co0.16As2

    SciTech Connect (OSTI)

    Lumsden, Mark D [ORNL; Christianson, Andrew D [ORNL; Parshall, Daniel [ORNL; Stone, Matthew B [ORNL; Nagler, Stephen E [ORNL; Mook Jr, Herbert A [ORNL; Lokshin, Konstantin A [ORNL; Egami, Takeshi [ORNL; Abernathy, Douglas L [ORNL; Goremychkin, E. A. [ISIS Facility, Rutherford Appleton Laboratory; Osborn, R. [Argonne National Laboratory (ANL); McGuire, Michael A [ORNL; Safa-Sefat, Athena [ORNL; Jin, Rongying [ORNL; Sales, Brian C [ORNL; Mandrus, David [ORNL

    2009-01-01T23:59:59.000Z

    Inelastic neutron scattering measurements on single crystals of superconducting BaFe1.84Co0.16As2 clearly reveal a magnetic excitation located at wavevectors (1/2 1/2 L) in tetragonal notation. The scattering is much broader in L than are spin waves observed in the parent compound BaFe2As2 indicating that the excitations in the superconducting material are more two-dimensional in nature. The excitation appears gapless for T > TC and becomes gapped on cooling below TC. The observed gap energy is approximately 9.6 meV corresponding to 5 kBTC which is remarkably similar to the canonical value for the resonance energy in the cuprates.

  4. Behavior of vortices near twin boundaries in underdoped Ba(Fe 1 ? x Co x ) 2 As 2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kalisky, B.; Kirtley, J. R.; Analytis, J. G.; Chu, J.-H.; Fisher, I. R.; Moler, K. A.

    2011-02-01T23:59:59.000Z

    We use scanning superconducting quantum interference device (SQUID) microscopy to investigate the behavior of vortices in the presence of twin boundaries in the pnictide superconductor Ba(Fe1-xCox)?As?. We show that the vortices avoid pinning on twin boundaries. Individual vortices move in a preferential way when manipulated with the SQUID: They tend to not cross a twin boundary, but rather to move parallel to it. This behavior can be explained by the observation of enhanced superfluid density on twin boundaries in Ba(Fe1-xCox)?As?. The observed repulsion from twin boundaries may be a mechanism for enhanced critical currents observed in twinned samples in pnictides and other superconductors.

  5. Proton diffusion pathways and rates in Y-doped BaZrO3 solid oxide electrolyte from quantum mechanics

    E-Print Network [OSTI]

    Goddard III, William A.

    Proton diffusion pathways and rates in Y-doped BaZrO3 solid oxide electrolyte from quantum barriers for intraoctahedral and interoctahedral proton transfers. We find activation energy Ea values of 0.48 and 0.49 eV for the intraoctahedral proton transfers on O­O edges 2.58 and 2.59 Å of ZrO6 and YO6

  6. OXYDATION COMPARE DU NIOBIUM ET D'UN ALLIAGE (P 353 M) A BA SE DE NIOBIUM

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    519 OXYDATION COMPARÉE DU NIOBIUM ET D'UN ALLIAGE (P 353 M) A BA SE DE NIOBIUM E. FRIES, C. MARHIC'oxydation comparée du Niobium pur et d'un alliage à base de Niobium de composition suivante : W V Ti Zr C 10 % 1 100 h. Dans les deux cas (niobium et alliage) on a mis en évidence la présence de trois formes de l

  7. The Magnetic Sensitivity of the Ba II D1 and D2 Lines of the Fraunhofer Spectrum

    E-Print Network [OSTI]

    Luca Belluzzi; Javier Trujillo Bueno; Egidio Landi Degl'Innocenti

    2007-04-30T23:59:59.000Z

    The physical interpretation of the spectral line polarization produced by the joint action of the Hanle and Zeeman effects offers a unique opportunity to obtain empirical information about hidden aspects of solar and stellar magnetism. To this end, it is important to achieve a complete understanding of the sensitivity of the emergent spectral line polarization to the presence of a magnetic field. Here we present a detailed theoretical investigation on the role of resonance scattering and magnetic fields on the polarization signals of the Ba II D1 and D2 lines of the Fraunhofer spectrum, respectively at 4934 \\AA\\ and 4554 \\AA. We adopt a three-level model of Ba II, and we take into account the hyperfine structure that is shown by the $^{135}$Ba and $^{137}$Ba isotopes. Despite of their relatively small abundance (18%), the contribution coming from these two isotopes is indeed fundamental for the interpretation of the polarization signals observed in these lines. We consider an optically thin slab model, through which we can investigate in a rigorous way the essential physical mechanisms involved (resonance polarization, Zeeman, Paschen-Back and Hanle effects), avoiding complications due to radiative transfer effects. We assume the slab to be illuminated from below by the photospheric solar continuum radiation field, and we investigate the radiation scattered at 90 degrees, both in the absence and in the presence of magnetic fields, deterministic and microturbulent. We show in particular the existence of a differential magnetic sensitivity of the three-peak Q/I profile that is observed in the D2 line in quiet regions close to the solar limb, which is of great interest for magnetic field diagnostics.

  8. High field nuclear magnetic resonance in transition metal substituted BaFe{sub 2}As{sub 2}

    SciTech Connect (OSTI)

    Garitezi, T. M., E-mail: thalesmg@ifi.unicamp.br; Lesseux, G. G.; Rosa, P. F. S.; Adriano, C.; Pagliuso, P. G.; Urbano, R. R. [Instituto de Física “Gleb Wataghin,” UNICAMP, Campinas, SP 13083-859 (Brazil); Reyes, A. P.; Kuhns, P. L. [National High Magnetic Field Laboratory, FSU, Tallahassee, Florida 32306-4005 (United States)

    2014-05-07T23:59:59.000Z

    We report high field {sup 75}As nuclear magnetic resonance (NMR) measurements on Co and Cu substituted BaFe{sub 2}As{sub 2} single crystals displaying same structural/magnetic transition T{sub 0}?128??K. From our anisotropy studies in the paramagnetic state, we strikingly found virtually identical quadrupolar splitting and consequently the quadrupole frequency ?{sub Q}?2.57(1)??MHz for both compounds, despite the claim that each Cu delivers 2 extra 3d electrons in BaFe{sub 2}As{sub 2} compared to Co substitution. These results allow us to conclude that a subtle change in the crystallographic structure, particularly in the Fe–As tetrahedra, must be the most probable tuning parameter to determine T{sub 0} in this class of superconductors rather than electronic doping. Furthermore, our NMR data around T{sub 0} suggest coexistence of tetragonal/paramagnetic and orthorhombic/antiferromagnetic phases between the structural and the spin density wave magnetic phase transitions, similarly to what was reported for K-doped BaFe{sub 2}As{sub 2} [Urbano et al., Phys. Rev. Lett. 105, 107001 (2010)].

  9. Structural and magnetic properties of the Kagome antiferromagnet YbBaCo{sub 4}O{sub 7}

    SciTech Connect (OSTI)

    Huq, A. [Intense Pulsed Neutron Source, Argonne National Laboratory, 9700 S. Cass Ave., Argonne, IL 60439 (United States); Mitchell, J.F. [Materials Science Division, Argonne National Laboratory, 9700 S. Cass Ave., Argonne, IL 60439 (United States)]. E-mail: mitchell@anl.gov; Zheng, H. [Materials Science Division, Argonne National Laboratory, 9700 S. Cass Ave., Argonne, IL 60439 (United States); Chapon, L.C. [ISIS Facility, Rutherford Appleton Laboratory-CCLRC, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Radaelli, P.G. [ISIS Facility, Rutherford Appleton Laboratory-CCLRC, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Knight, K.S. [ISIS Facility, Rutherford Appleton Laboratory-CCLRC, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Stephens, P.W. [Department of Physics and Astronomy, SUNY Stonybrook, NY 11794 (United States)

    2006-04-15T23:59:59.000Z

    The mixed-valent compound YbBaCo{sub 4}O{sub 7} is built up of Kagome sheets of CoO{sub 4} tetrahedra, linked in the third dimension by a triangular layer of CoO{sub 4} tetrahedra in an analogous fashion to that found in the known geometrically frustrated magnets such as pyrochlores and SrCr{sub 9} {sub x} Ga{sub 12-9} {sub x} O{sub 19} (SCGO). We have undertaken a study of the structural and magnetic properties of this compound using combined high-resolution powder neutron and synchrotron X-ray diffraction. YbBaCo{sub 4}O{sub 7} undergoes a first-order trigonal{sup {yields}}orthorhombic phase transition at 175 K. We show that this transition occurs as a response to a markedly underbonded Ba{sup 2+} site in the high-temperature phase and does not appear to involve charge ordering of Co{sup 2+}/Co{sup 3+} ions in the tetrahedra. The symmetry lowering relieves the geometric frustration of the structure, and a long-range-ordered 3-D antiferromagnetic state develops below 80 K.

  10. High temperature superconductor step-edge Josephson junctions using Ti-Ca-Ba-Cu-O

    DOE Patents [OSTI]

    Ginley, D.S.; Hietala, V.M.; Hohenwarter, G.K.G.; Martens, J.S.; Plut, T.A.; Tigges, C.P.; Vawter, G.A.; Zipperian, T.E.

    1994-10-25T23:59:59.000Z

    A process is disclosed for formulating non-hysteretic and hysteretic Josephson junctions using HTS materials which results in junctions having the ability to operate at high temperatures while maintaining high uniformity and quality. The non-hysteretic Josephson junction is formed by step-etching a LaAlO[sub 3] crystal substrate and then depositing a thin film of TlCaBaCuO on the substrate, covering the step, and forming a grain boundary at the step and a subsequent Josephson junction. Once the non-hysteretic junction is formed the next step to form the hysteretic Josephson junction is to add capacitance to the system. In the current embodiment, this is accomplished by adding a thin dielectric layer, LaA1O[sub 3], followed by a cap layer of a normal metal where the cap layer is formed by first depositing a thin layer of titanium (Ti) followed by a layer of gold (Au). The dielectric layer and the normal metal cap are patterned to the desired geometry. 8 figs.

  11. Measurement of D0-D0bar Mixing and CP Violation at BaBar

    E-Print Network [OSTI]

    Giulia Casarosa; for the BaBar Collaboration

    2012-08-31T23:59:59.000Z

    We report on a measurement of D0-D0bar mixing and a search for CP violation in the D0->K+K-, pi+pi- and K+-pi-+ channels. We use D0's coming from D*+ decays, so that the flavour of the D0 at production is tagged by the charge of the pion that is also emitted. We also use an independent set of D0's coming directly from the hadronization of the charm quark, but in this case the flavour of the charmed meson is not known. We analyze events collected by the BaBar experiment at the PEP-II asymmetric-energy e+e- collider, corresponding to an integrated luminosity of 468 fb-1. We measure the mixing parameter value to be yCP = [0.72 +- 0.18 (stat) +- 0.12 (syst)]%, and exclude the no-mixing hypothesis at 3.3sigma significance. We find no evidence of CP violation, observing DeltaY = [0.09 +- 0.26 (stat) +- 0.06 syst)]% which is consistent with zero.

  12. Fluorine sites in glasses and transparent glass-ceramics of the system Na{sub 2}O/K{sub 2}O/Al{sub 2}O{sub 3}/SiO{sub 2}/BaF{sub 2}

    SciTech Connect (OSTI)

    Bocker, Christian, E-mail: christian.bocker@uni-jena.d [Otto-Schott-Institut, Jena University, Fraunhoferstr. 6, 07743 Jena (Germany); Munoz, Francisco; Duran, Alicia [Instituto de Ceramica y Vidrio (CSIC), Kelsen 5, 28049 Madrid (Spain); Ruessel, Christian [Otto-Schott-Institut, Jena University, Fraunhoferstr. 6, 07743 Jena (Germany)

    2011-02-15T23:59:59.000Z

    The transparent glass-ceramics obtained in the silicate system Na{sub 2}O/K{sub 2}O/SiO{sub 2}/BaF{sub 2} show homogeneously dispersed BaF{sub 2} nano crystals with a narrow size distribution. The X-ray diffraction and the nuclear magnetic resonance spectroscopy were applied to glasses and the respective glass-ceramics in order to clarify the crystallization mechanism and the role of fluorine during crystallization. With an increasing annealing time, the concentration and also the number of crystals remain approximately constant. With an increasing annealing temperature, the crystalline fraction increases until a saturation limit is reached, while the number of crystals decreases and the size of the crystals increases. Fluoride in the glassy network occurs as Al-F-Ba, Al-F-Na and also as Ba-F structures. The latter are transformed into crystalline BaF{sub 2} and fluoride is removed from the Al-F-Ba/Na bonds. However, some fluorine is still present in the glassy phase after the crystallization. -- Graphical abstract: The X-ray diffraction and the nuclear magnetic resonance spectroscopy were applied to glasses in the silicate system Na{sub 2}O/K{sub 2}O/SiO{sub 2}/BaF{sub 2} and the respective glass-ceramics with BaF{sub 2} nano crystals in order to clarify the crystallization mechanism and the role of fluorine during crystallization. Display Omitted Research highlights: {yields} BaF{sub 2} nano crystals are precipitated from a silicate glass system. {yields} Ostwald ripening during the late stage of crystallization does not occur. {yields} Fluorine in the glass is coordinated with Ba as well as Al together with Ba or Na.{yields} In the glass-ceramics, the residual fluorine is coordinated as Al-F-Ba/Na.

  13. First-principles study of structural, electronic, vibrational, dielectric and elastic properties of tetragonal Ba{sub 2}YTaO{sub 6}

    SciTech Connect (OSTI)

    Ganeshraj, C.; Santhosh, P. N., E-mail: santhosh@physics.iitm.ac.in [Low Temperature Physics Laboratory, Department of Physics, Indian Institute of Technology Madras, Chennai 600 036, Tamil Nadu (India)

    2014-10-14T23:59:59.000Z

    We report first-principles study of structural, electronic, vibrational, dielectric, and elastic properties of Ba{sub 2}YTaO{sub 6}, a pinning material in high temperature superconductors (HTS), by using density functional theory. By using different exchange-correlation potentials, the accuracy of the calculated lattice constants of Ba{sub 2}YTaO{sub 6} has been achieved with GGA-RPBE, since many important physical quantities crucially depend on change in volume. We have calculated the electronic band structure dispersion, total and partial density of states to study the band gap origin and found that Ba{sub 2}YTaO{sub 6} is an insulator with a direct band gap of 3.50?eV. From Mulliken population and charge density studies, we conclude that Ba{sub 2}YTaO{sub 6} have a mixed ionic-covalent character. Moreover, the vibrational properties, born effective charges, and the dielectric permittivity tensor have been calculated using linear response method. Vibrational spectrum determined through our calculations agrees well with the observed Raman spectrum, and allows assignment of symmetry labels to modes. We perform a detailed analysis of the contribution of the various infrared-active modes to the static dielectric constant to explain its anisotropy, while electronic dielectric tensor of Ba{sub 2}YTaO{sub 6} is nearly isotropic, and found that static dielectric constant is in good agreement with experimental value. The six independent elastic constants were calculated and found that tetragonal Ba{sub 2}YTaO{sub 6} is mechanically stable. Other elastic properties, including bulk modulus, shear modulus, Young's modulus, Poisson's ratio, and elastic anisotropy ratios are also investigated and found that Poisson's ratio and Young's modulus of Ba{sub 2}YTaO{sub 6} are similar to that of other pinning materials in HTS.

  14. Properties of polycarbonate containing BaTiO{sub 3} nanoparticles

    SciTech Connect (OSTI)

    Lomax, J. F.; Lomax, E. A.; Lomax, P. Q. [Chemistry Department, U.S. Naval Academy, Annapolis, Maryland 21402 (United States); Fontanella, J. J., E-mail: fontanel@Comcast.net; Edmondson, C. A.; Wintersgill, M. C.; Westgate, M. A. [Physics Department, U.S. Naval Academy, Annapolis, Maryland 21402 (United States); Wolak, M. A. [U.S. Naval Research Lab, Washington, DC 20375 (United States); Bogle, X.; Rúa, A.; Greenbaum, S. G. [Department of Physics and Astronomy, Hunter College, New York, New York 10021 (United States)

    2014-03-14T23:59:59.000Z

    The real part of the relative permittivity, ??, and dielectric loss, tan??, have been determined at audio frequencies at temperatures from about 5?K to 350?K for nano-composites composed of BaTiO{sub 3} nanoparticles and polycarbonate. The room temperature breakdown strength was also measured and thermal analysis, nuclear magnetic resonance and scanning electron microscopy studies were carried out. For some films the nanoparticles were surface-treated (STNP) while for others they were not (UNP). For concentrations of UNP greater than about 3.4 vol. %, ?? is much larger than expected on the basis of laws of mixing. On the other hand, ?? for materials made using STNP is well-behaved. Correspondingly, increased loss (?? or tan??) in the vicinity of room temperature is observed for the materials made from UNP. The anomalously large values of relative permittivity and increased loss are attributed to the presence of large aggregates in the materials made using the UNP. For both UNP-and STNP-based materials, the breakdown strength is found to decrease as nanoparticle concentration increases. The breakdown strength for the materials made using STNP is found to be larger for all concentrations than for those containing UNP despite the presence of large aggregates in some of the STNP-based materials. This shows that breakdown is strongly affected by the nanoparticle surfaces and/or the interface layer. It is also found that the breakdown strength for materials made using UNP increases as particle size increases. Finally, variable temperature and pressure proton nuclear magnetic resonance relaxation measurements were made to assess the effect of nanoparticle inclusion on polymer motion, and the effects were found to be very minor.

  15. Correlation between upconversion photoluminescence and dielectric response in Ba-substituted (Sr{sub 1?x}Ba{sub x}){sub 4}(La{sub 0.85}Ho{sub 0.025}Yb{sub 0.125}){sub 2}Ti{sub 4}Nb{sub 6}O{sub 30}

    SciTech Connect (OSTI)

    Wei, T., E-mail: weitong.nju@gmail.com [College of Science, Civil Aviation University of China, Tianjin 300300 (China); Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China); Wang, X. D. [College of Science, Civil Aviation University of China, Tianjin 300300 (China); Zhao, C. Z. [School of Electronics and Information Engineering, Tianjin Polytechnic University, Tianjin 300160 (China); Liu, M. F.; Liu, J. M., E-mail: liujm@nju.edu.cn [Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China)

    2014-06-30T23:59:59.000Z

    The filled tetragonal tungsten bronze (Sr{sub 1?x}Ba{sub x}){sub 4}(La{sub 0.85}Ho{sub 0.025}Yb{sub 0.125}){sub 2}Ti{sub 4}Nb{sub 6}O{sub 30} (SBLTNx: Ho-Yb) ceramics with different Ba substitution levels (x) are prepared. The upconversion photoluminescence (UC-PL) and dielectric permittivity are investigated. The substitution of Sr{sup 2+} ions at the A{sub 2}-sites by larger Ba{sup 2+} ions results in substantial variation of the UC-PL intensity as a function of substitution level x. Furthermore, the dielectric response to the substitution of Sr{sup 2+} by Ba{sup 2+} suggests a close correlation between the UC-PL intensity and dielectric permittivity. The origin for this correlation is discussed based on the random stress field (RSF) model.

  16. Synthesis of BaTiO[subscript 3]-20wt%CoFe[subscript 2]O[subscript 4] Nanocomposites via Spark Plasma Sintering

    SciTech Connect (OSTI)

    Ghosh, Dipankar; Han, Hyuksu; Nino, Juan C.; Subhash, Ghatu; Jones, Jacob L. (Florida)

    2012-10-23T23:59:59.000Z

    Barium titanate-20wt% cobalt ferrite (BaTiO{sub 3}-20wt%CoFe{sub 2}O{sub 4}) nanocomposites were sintered from nanocrystalline BaTiO{sub 3} and CoFe{sub 2}O{sub 4} powders using spark plasma sintering (SPS) and pressureless sintering (PS) techniques. Using SPS, dense polycrystalline composites were obtained at a sintering temperature as low as 860 C and a time of 5 min whereas PS required a higher sintering temperature (1150 C) and time (120 min) to obtain similarly dense composites. Microstructural analysis of the composites showed that both the techniques retained nanocrystalline grain sizes after sintering. High resolution X-ray diffraction measurements revealed that the BaTiO{sub 3}-20wt%CoFe{sub 2}O{sub 4} composites sintered by the SPS technique did not exhibit formation of any new phase(s) due to reaction between the BaTiO{sub 3} and CoFe{sub 2}O{sub 4} phases during sintering. However, the PS technique resulted in the formation of additional phases (other than the BaTiO{sub 3} and CoFe{sub 2}O{sub 4} phases) in the composites. While the composites synthesized by SPS were of superior phase-purity, evidence of Fe diffusion from the spinel to the perovskite phase was found from X-ray diffraction and permittivity measurements.

  17. High temperature phase stabilities and electrochemical properties of InBaCo4-xZnxO7 cathodes for intermediate temperature solid oxide fuel cells

    SciTech Connect (OSTI)

    Kim, Jung-Hyun [ORNL; Young Nam, Kim [University of Texas, Austin; Bi, Zhonghe [ORNL; Manthiram, Arumugam [University of Texas, Austin; Paranthaman, Mariappan Parans [ORNL; Huq, Ashfia [ORNL

    2011-01-01T23:59:59.000Z

    InBaCo4-xZnxO7 oxides have been synthesized and characterized as cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFC). The effect of Zn substitution for Co on the structure, phase stability, thermal expansion, and electrochemical properties of the InBaCo4-xZnxO7 has been investigated. The increase in the Zn content from x = 1 to 1.5 improves the high temperature phase stability at 600 oC and 700 oC for 100 h, and chemical stability against a Gd0.2Ce0.8O1.9 (GDC) electrolyte. Thermal expansion coefficient (TEC) values of the InBaCo4-xZnxO7 (x = 1, 1.5, 2) specimens were determined to be 8.6 10-6 9.6 10-6 /oC in the range of 80 900 oC, which provides good thermal expansion compatibility with the standard SOFC electrolyte materials. The InBaCo4-xZnxO7 + GDC (50:50 wt. %) composite cathodes exhibit improved cathode performances compared to those obtained from the simple InBaCo4-xZnxO7 cathodes due to the extended triple-phase boundary (TPB) and enhanced oxide-ion conductivity through the GDC portion in the composites.

  18. (Sr,Ba)(Si,Ge){sub 2} for thin-film solar-cell applications: First-principles study

    SciTech Connect (OSTI)

    Kumar, Mukesh, E-mail: Kumar.Mukesh@nims.go.jp, E-mail: mkgarg79@gmail.com [Environmental Remediation Materials Unit, National Institute for Materials Science, Ibaraki 305-0044 (Japan); Umezawa, Naoto [Environmental Remediation Materials Unit, National Institute for Materials Science, Ibaraki 305-0044 (Japan); PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama 332-0012 (Japan); TU-NIMS Joint Research Center, School of Materials Science and Engineering, Tianjin University, 92 Weijin Road, Nankai District, Tianjin (China); Imai, Motoharu [Superconducting Properties Unit, National Institute for Materials Science, Ibaraki 305-0047 (Japan)

    2014-05-28T23:59:59.000Z

    In order to meet the increasing demand for electric power generation from solar energy conversion, the development of efficient light absorber materials has been awaited. To this end, the electronic and optical properties of advanced alkaline-earth-metals disilicides and digermanides (SrSi{sub 2}, BaSi{sub 2}, SrGe{sub 2}, and BaGe{sub 2}) are studied by means of the density functional theory using HSE06 exchange-correlation energy functional. Our calculations show that all these orthorhombic structured compounds have fundamental indirect band gaps in the range E{sub g} ? 0.89–1.25 eV, which is suitable for solar cell applications. The estimated lattice parameters and band gaps are in good agreement with experiments. Our calculations show that the electronic band structures of all four compounds are very similar except in the vicinity of the ?-point. The valence band of these compounds is made up by Si(Ge)-p states, whereas the conduction band is composed of Sr(Ba)-d states. Their band alignments are carefully determined by estimating the work function of each compound using slab model. The optical properties are discussed in terms of the complex dielectric function ?(?)?=??{sub 1}(?)?+?i?{sub 2}(?). The static and high-frequency dielectric constants are calculated, taking into account the ionic contribution. The absorption coefficient ?(?) demonstrates that a low energy dispersion of the conduction band, which results in a flat conduction band minimum, leads to large optical activity in these compounds. Therefore, alkaline-earth-metals disilicides and digermanides possess great potential as light absorbers for applications in thin-film solar cell technologies.

  19. Synthesis, structural characterization and properties of SrAl{sub 4?x}Ge{sub x}, BaAl{sub 4?x}Ge{sub x}, and EuAl{sub 4?x}Ge{sub x} (x?0.3–0.4)—Rare examples of electron-rich phases with the BaAl{sub 4} structure type

    SciTech Connect (OSTI)

    Zhang, Jiliang; Bobev, Svilen, E-mail: bobev@udel.edu

    2013-09-15T23:59:59.000Z

    Three solid solutions with the general formula AEAl{sub 4?x}Ge{sub x} (AE=Eu, Sr, Ba; 0.32(1)?x?0.41(1)) have been synthesized via the aluminum self-flux method, and their crystal structures have been established from powder and single-crystal X-ray diffraction. They are isotypic and crystallize with the well-known BaAl{sub 4} structure type, adopted by the three AEAl{sub 4} end members. In all structures, Ge substitutes Al only at the 4e Wyckoff site. Results from X-rays photoelectron spectroscopy on EuAl{sub 4?x}Ge{sub x} and EuAl{sub 4} indicate that the interactions between the Eu{sup 2+} cations and the polyanionic framework are enhanced in the Ge-doped structure, despite the slightly elevated Fermi level. Magnetic susceptibility measurements confirm the local moment magnetism, expected for the [Xe]4f{sup 7} electronic configuration of Eu{sup 2+} and suggest strong ferromagnetic interactions at cryogenic temperatures. Resistivity data from single-crystalline samples show differences between the title compounds, implying different bonding characteristics despite the close Debye temperatures. A brief discussion on the observed electron count and homogeneity ranges for AEAl{sub 4?x}Ge{sub x} (AE=Eu, Sr, Ba) is also presented. - Graphical abstract: AEAl{sub 4?x}Ge{sub x} (AE=Eu, Sr, Ba; 0.32(1)?x?0.41(1)), three “electron-rich” phases with BaAl{sub 4} structure type have been synthesized and characterized. Display Omitted - Highlights: • Three BaAl{sub 4}-type ternary aluminum germanides have been synthesized with Eu, Sr and Ba. • Eu, Sr and Ba cations have no apparent influence on the solubility of Ge. • The Ge atoms substitute Al on one of two framework sites, thereby strengthening the interactions between the cations and the polyanionic framework.

  20. Zn-Doping Dependence of Stripe Order in La1.905Ba0.095CuO4

    SciTech Connect (OSTI)

    Hucker, M.; Zimmermann, M.v.; Xu, Z.J.; Wen, J.S.; Gu, G.D.; Tian, W.; Zarestky, J.; Tranquada, J.M.

    2011-04-01T23:59:59.000Z

    The effect of Zn-doping on the stripe order in La{sub 1.905}Ba{sub 0.095}CuO{sub 4} has been studied by means of x-ray and neutron diffraction as well as magnetization measurements. While 1% Zn leads to an increase of the spin stripe order, it unexpectedly causes a wipe out of the visibility of the charge stripe order. A magnetic field of 10 Tesla applied along the c-axis has no reversing effect on the charge order. We compare this observation with the Zn-doping dependence of the crystal structure, superconductivity, and normal state magnetism.

  1. Time-Dependent CP Asymmetries in b --> s qbar q Transitions and sin2phi1 in B0 --> J/psi K0 Decays with 386 Million BBbar Pairs

    E-Print Network [OSTI]

    The Belle Collaboration; K. Abe

    2005-07-08T23:59:59.000Z

    We present measurements of time-dependent CP asymmetries in B0 --> phi(1020) K0, eta' K0, Ks Ks Ks, Ks pi0, f0(980) Ks, omega Ks and K+ K- Ks decays based on a sample of 386 x 10^6 BBbar pairs collected at the Upsilon(4S) resonance with the Belle detector at the KEKB energy-asymmetric e+e- collider. These decays are dominated by the b --> s gluonic penguin transition and are sensitive to new CP-violating phases from physics beyond the standard model. One neutral B meson is fully reconstructed in one of the specified decay channels, and the flavor of the accompanying B meson is identified from its decay products. CP-violation parameters sin2phi1^eff and {\\cal A} for each of the decay modes are obtained from the asymmetries in the distributions of the proper-time intervals between the two B decays. We also perform an improved measurement of CP asymmetries in B0 --> J/psi K0 decays using the same data sample. The same analysis procedure mentioned above yields sin2phi1 = +0.652 +/- 0.039(stat) +/- 0.020(syst), which serves as a reference point for the standard model, and {\\cal A} = +0.010 +/- 0.026(stat) +/- 0.036(syst).

  2. Structural evolution across the insulator-metal transition in oxygen-deficient BaTiO3-? studied using neutron total scattering and Rietveld analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jeong, I.-K.; Lee, Seunghun; Jeong, Se-Young; Won, C. J.; Hur, N.; Llobet, A.

    2011-08-01T23:59:59.000Z

    Oxygen-deficient BaTiO3-? exhibits an insulator-metal transition with increasing ?. We performed neutron total scattering measurements to study structural evolution across an insulator-metal transition in BaTiO3-?. Despite its significant impact on resistivity, slight oxygen reduction (?=0.09) caused only a small disturbance on the local doublet splitting of Ti-O bond. This finding implies that local polarization is well preserved under marginal electric conduction. In the highly oxygen-deficient metallic state (?=0.25), however, doublet splitting of the Ti-O bond became smeared. The smearing of the local Ti-O doublet is complemented with long-range structural analysis and demonstrates that the metallic conduction in the highly oxygen-reducedmore »BaTiO3-? is due to the appearance of nonferroelectric cubic lattice.« less

  3. Structural evolution across the insulator-metal transition in oxygen-deficient BaTiO3-? studied using neutron total scattering and Rietveld analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jeong, I.-K.; Lee, Seunghun; Jeong, Se-Young; Won, C. J.; Hur, N.; Llobet, A.

    2011-08-01T23:59:59.000Z

    Oxygen-deficient BaTiO3-? exhibits an insulator-metal transition with increasing ?. We performed neutron total scattering measurements to study structural evolution across an insulator-metal transition in BaTiO3-?. Despite its significant impact on resistivity, slight oxygen reduction (?=0.09) caused only a small disturbance on the local doublet splitting of Ti-O bond. This finding implies that local polarization is well preserved under marginal electric conduction. In the highly oxygen-deficient metallic state (?=0.25), however, doublet splitting of the Ti-O bond became smeared. The smearing of the local Ti-O doublet is complemented with long-range structural analysis and demonstrates that the metallic conduction in the highly oxygen-reduced BaTiO3-? is due to the appearance of nonferroelectric cubic lattice.

  4. (Y0.5In0.5)Ba(Co,Zn)4O7 cathodes with superior high-temperature phase stability for solid oxide fuel cells

    SciTech Connect (OSTI)

    Young Nam, Kim [University of Texas, Austin; Kim, Jung-Hyun [ORNL; Paranthaman, Mariappan Parans [ORNL; Manthiram, Arumugam [University of Texas, Austin; Huq, Ashfia [ORNL

    2012-01-01T23:59:59.000Z

    (Y0.5In0.5)BaCo4-xZnxO7 (1.0 x 2.0) oxides crystallizing in a trigonal P31c structure have been synthesized and explored as cathode materials for solid oxide fuel cells (SOFC). At a given Zn content, the (Y0.5In0.5)BaCo4-xZnxO7 sample with 50 % Y and 50 % In exhibits much improved phase stability at intermediate temperatures (600 - 800 oC) compared to the samples with 100 % Y or In. However, the substitution of Zn for Co in (Y0.5In0.5)Ba(Co4-xZnx)O7 (1.0 x 2.0) decreases the amount of oxygen loss on heating, total electrical conductivity, and cathode performance in SOFC while providing good long-term phase stability at high temperatures. Among the various chemical compositions investigated in the (Y0.5In0.5)Ba(Co4-xZnx)O7 system, the (Y0.5In0.5)BaCo3ZnO7 sample offers a combination of good electrochemical performance and low thermal expansion coefficient (TEC) while maintaining superior phase stability at 600 800 oC for 100 h. Fuel cell performances of the (Y0.5In0.5)Ba(Co3Zn)O7 + Ce0.8Gd0.2O1.9 (GDC) (50 : 50 wt. %) composite cathodes collected with anode-supported single cell reveal a maximum power density value of 521 mW cm-2 at 700 oC.

  5. X-ray and neutron powder diffraction studies of Ba(Nd{sub x}Y{sub 2-x})CuO{sub 5}

    SciTech Connect (OSTI)

    Liu, G. [Ceramics Division, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States); Huang, Q. [NIST Center for Neutron Research, Naperville, IL 60563 (United States); Kaduk, J.A. [INEOS Technologies, Naperville, IL 60563 (United States); Yang, Z. [Yunnan Normal University, Kunming 650092 (China); Lucas, C. [Chemistry and Biochemistry Department, University of Maryland, College Park, MD 20742 (United States); Wong-Ng, W. [Ceramics Division, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States)], E-mail: Winnie.wong-ng@nist.gov

    2008-12-15T23:59:59.000Z

    Ba(R,R'){sub 2}CuO{sub 5} (R,R'=lanthanides and Y) plays an important role as a flux-pinning agent in enhancing the superconducting properties of the Ba{sub 2}(R,R')Cu{sub 3}O{sub 6+x} (R,R'=lanthanides and Y) coated conductors. Using X-ray diffraction and neutron diffraction, we found that the Ba(Nd{sub x}Y{sub 2-x})CuO{sub 5} solid solution adopts two structure types. In the Nd-rich region (1.8{<=}x{<=}2.0), the materials are of brown color (commonly referred to as the 'brown phase'), and the structure is tetragonal with space group I4/mbm (no. 127). In the Y-rich region (0.0{<=}x{<=}1.4), the materials are green (commonly referred to as the 'green phase') and the structure is orthorhombic with space group Pnma (no. 62). A two-phase region (1.4Ba(Nd{sub x}Y{sub 2-x})CuO{sub 5} (isostructural to BaY{sub 2}CuO{sub 5}), are discussed in this paper. - Graphical abstract: Perspective view of the 'green phase' Ba(Nd{sub x}Y{sub 2-x})CuO{sub 5} structure along the b-axis, showing the isolated square pyramids of [CuO{sub 5}] and the trigonal prisms, RO{sub 7}, around the lanthanide sites.

  6. Metal-semiconductor-transition observed in Bi{sub 2}Ca(Sr, Ba){sub 2}Co{sub 2}O{sub 8+?} single crystals

    SciTech Connect (OSTI)

    Dong, Song-Tao [National Laboratory of Solid State Microstructures and Department of Material Science and Engineering, Nanjing University, Nanjing 210093 (China); Institute of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003 (China); Zhang, Bin-Bin; Zhang, Lun-Yong; Yao, Shu-Hua, E-mail: ybchen@nju.edu.cn, E-mail: shyao@nju.edu.cn; Zhou, Jian; Zhang, Shan-Tao; Gu, Zheng-Bin; Chen, Yan-Feng [National Laboratory of Solid State Microstructures and Department of Material Science and Engineering, Nanjing University, Nanjing 210093 (China); Chen, Y. B., E-mail: ybchen@nju.edu.cn, E-mail: shyao@nju.edu.cn [National Laboratory of Solid State Microstructures and Department of Physics and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China)

    2014-07-28T23:59:59.000Z

    Electrical property evolution of Bi{sub 2}AE{sub 2}Co{sub 2}O{sub 8+?} single crystals (AE?=?Ca, Sr and Ba) is systematically explored. When AE changes from Ca to Ba, the electrical property of Bi{sub 2}Ca{sub 2}Co{sub 2}O{sub 8+?} and Bi{sub 2}Sr{sub 2}Co{sub 2}O{sub 8+?} demonstrates semiconductor-like properties. But Bi{sub 2}Ba{sub 2}Co{sub 2}O{sub 8+?} shows the metallic behavior. Analysis of temperature-dependent resistance substantiates that from metallic Bi{sub 2}Ba{sub 2}Co{sub 2}O{sub 8+?} to semiconductor-like Bi{sub 2}Sr{sub 2}Co{sub 2}O{sub 8+?} can be attributed to Anderson localization. However the semiconductor behaviour of Bi{sub 2}Sr{sub 2}Co{sub 2}O{sub 8+?} and Bi{sub 2}Ca{sub 2}Co{sub 2}O{sub 8+?} is related to electronic correlations effect that is inferred by large negative magnetoresistance (?70%). The theoretical electronic structures and valence X-ray photoemission spectroscopy substantiate that there is a relative large density of state around Fermi level in Bi{sub 2}Ba{sub 2}Co{sub 2}O{sub 8+?} compared with other two compounds. It suggests that Bi{sub 2}Ba{sub 2}Co{sub 2}O{sub 8+?} is more apt to be metal in this material system.

  7. Effect of annealing on the specific heat of Ba(Fe 1 ? x Co x ) 2 As 2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gofryk, K.; Vorontsov, A. B.; Vekhter, I.; Sefat, A. S.; Imai, T.; Bauer, E. D.; Thompson, J. D.; Ronning, F.

    2011-02-01T23:59:59.000Z

    We report on the effect of annealing on the temperature and field dependencies of the low-temperature specific heat of the electron-doped Ba(Fe1-xCox)?As? for under- (x = 0.045), optimally (x = 0.08), and over- (x = 0.105 and 0.14) doped regimes. We observed that annealing significantly improves some superconducting characteristics in Ba(Fe1-xCox)?As?. It considerably increases Tc, decreases ?? in the superconducting state, and suppresses the Schottky-like contribution at very low temperatures. The improved sample quality allows for a better identification of the superconducting gap structure of these materials. We examine the effects of doping and annealing within a self-consistent framework for an extended s-wave pairing scenario. At optimal doping our data indicate that the sample is fully gapped, while for both under- and overdoped samples significant low-energy excitations remain, possibly consistent with a nodal structure. The difference of sample quality offers a natural explanation for the variation in low-temperature power laws observed by many techniques.

  8. Inclusion property of Cs, Sr, and Ba impurities in LiCl crystal formed by layer-melt crystallization

    SciTech Connect (OSTI)

    Choi, Jung-Hoon; Cho, Yung-Zun; Lee, Tae-Kyo; Eun, Hee-Chul; Kim, Jun-Hong; Park, Hwan-Seo; Kim, In-Tae; Park, Geun-Il [Nuclear Fuel Cycle Waste Treatment Research Division, Korea Atomic Energy Research Institute, Daejeon, 305-353 (Korea, Republic of)

    2013-07-01T23:59:59.000Z

    Pyroprocessing is one of the promising technologies enabling the recycling of spent nuclear fuels from a commercial light water reactor (LWR). In general, pyroprocessing uses dry molten salts as electrolytes. In particular, LiCl waste salt after pyroprocessing contains highly radioactive I/II group fission products mainly composed of Cs, Sr, and Ba impurities. Therefore, it is beneficial to reuse LiCl salt in the pyroprocessing as an electrolyte for economic and environmental issues. Herein, to understand the inclusion property of impurities within LiCl crystal, the physical properties such as lattice parameter change, bulk modulus, and substitution enthalpy of a LiCl crystal having 0-6 at% Cs{sup +} or Ba{sup 2+} impurities under existence of 1 at% Sr{sup 2+} impurity were calculated via the first-principles density functional theory. The substitution enthalpy of LiCl crystals having 1 at% Sr{sup 2+} showed slightly decreased value than those without Sr{sup 2+} impurity. Therefore, through the substitution enthalpy calculation, it is expected that impurities will be incorporated within LiCl crystal as co-existed form rather than as a single component form. (authors)

  9. BaZn{sub 2}Si{sub 2}O{sub 7} and the solid solution series BaZn{sub 2?x}Co{sub x}Si{sub 2}O{sub 7} (0

    SciTech Connect (OSTI)

    Kerstan, Marita; Thieme, Christian; Grosch, Matthias; Müller, Matthias; Rüssel, Christian, E-mail: ccr@rz.uni-jena.de

    2013-11-15T23:59:59.000Z

    For sealing of solid oxide fuel cells, glasses from which crystalline phases with high coefficient of thermal expansion (CTE) can be crystallized are required. In this paper, a new solid solution series BaZn{sub 2?x}Co{sub x}Si{sub 2}O{sub 7} (0BaZn{sub 2}Si{sub 2}O{sub 7}). Sintered specimens were characterized by dilatometry. The introduction of Co{sup 2+} does not lead to a change in the space group. All compounds show a transition of a low to a high temperature modification. The attributed temperature increases from 300 °C for BaZn{sub 2}Si{sub 2}O{sub 7} to 850 °C for BaCo{sub 2}Si{sub 2}O{sub 7}. The volume expansion which runs parallel to the phase transition decreases with increasing cobalt concentration. The phase BaZn{sub 2}Si{sub 2}O{sub 7} shows the largest CTE and a steep volume effect during phase transition. For the compound BaZn{sub 0.25}Co{sub 1.75}Si{sub 2}O{sub 7} the CTE is minimum (8.6×10{sup ?6} K{sup ?1} (50–900 °C)) and increases again until for the compound BaCo{sub 2}Si{sub 2}O{sub 7} a CTE of 16.6×10{sup ?6} K{sup ?1} (50–900 °C) is reached. In the cobalt rich composition range, the CTEs are in the right range for high temperature fuel cells and can be adjusted by the composition. - Graphical abstract: The composition of the solid solution BaZn{sub 2?x}Co{sub x}Si{sub 2}O{sub 7} strongly affects the thermal expansion. Display Omitted - Highlights: • We examined the thermal expansion of solid solutions BaZn{sub 2?x}Co{sub x}Si{sub 2}O{sub 7} (0BaZn{sub 2}Si{sub 2}O{sub 7} exhibits the highest thermal expansion due to a phase transition. • Substitution of small amounts of Zn{sup 2+} against Co{sup 2+} lead to decreasing thermal expansion. • The thermal expansions re-increased with further increasing Co{sup 2+} concentrations. • Seals based on these solid solutions should be suitable for solid oxide fuel cells.

  10. Electronic structure and transport properties of Ba{sub 6}Cu{sub 12}Fe{sub 13}S{sub 27}

    SciTech Connect (OSTI)

    Llanos, J.; Mujica, C. [Univ. Catolica del Norte, Casilla (Chile). Dept. de Quimica] [Univ. Catolica del Norte, Casilla (Chile). Dept. de Quimica

    1997-09-01T23:59:59.000Z

    The electrical properties and bonding in Ba{sub 6}Cu{sub 12}Fe{sub 13}S{sub 27} are analyzed with the extended Hueckel tight-binding method. Because the Fermi level crosses several bands, metallic properties could be expected for this material. The electrical conductivity measurements as well as diffuse reflectance spectrum show that Ba{sub 6}Cu{sub 12}S{sub 13}S{sub 27} is a semiconductor with a band gap of 2.49 eV. The discrepancy between the theoretical and experimental electrical properties is attributed to a random distribution of the Cu and Fe atoms in the structure.

  11. Poisoning Incidence in Wisconsin: Does Age Ma2er? Thomas Leschke, BA; Clare Guse, MS; Amy Schlo2hauer, MPH; Peter Layde, MD, MSc IntroducEon

    E-Print Network [OSTI]

    Poisoning Incidence in Wisconsin: Does Age Ma2er? Thomas Leschke, BA; Clare groups for both intenEonal opioid and non-opioid poisonings Opioid range: 6 and ICD -10 codes were used to divide poisoning incidents by agent (opioid vs

  12. First Principles Calculations of Oxygen Vacancy Formation and Migration in Ba1?xSrxCo1?yFeyO3?? Perovskites

    SciTech Connect (OSTI)

    Merkle, Rotraut; Mastrikov, Yuri; Kotomin, Eugene Alexej; Kukla, Maija M.; Maier, Joachim

    2011-12-28T23:59:59.000Z

    Based on first principles DFT calculations, we analyze oxygen vacancy formation and migration energies as a function of chemical composition in complex multicomponent (Ba,Sr)(Co,Fe)O3?? perovskites which are candidate materials for SOFC cathodes and permeation membranes. The atomic relaxation, electronic charge redistribution and energies of the transition states of oxygen migration are compared for several perovskites to elucidate the atomistic reason for the exceptionally low migration barrier in Ba0.5Sr0.5Co0.8Fe0.2O3?? that was previously determined experimentally. The critical comparison of Ba1?xSrxCo1?yFeyO3?? perovskites with different cation compositions and arrangements shows that in addition to the geometric constraints the electronic structure plays a considerable role for the height of the oxygen migration barrier in these materials. These findings help understand advantages and limitations of the fast oxygen permeation and exchange properties of Ba0.5Sr0.5Co0.8Fe0.2O3??.

  13. Strong blue and white photoluminescence emission of BaZrO{sub 3} undoped and lanthanide doped phosphor for light emitting diodes application

    SciTech Connect (OSTI)

    Romero, V.H. [Centro de Investigaciones en Optica, A. P. 1-948, Leon Gto., 37160 (Mexico)] [Centro de Investigaciones en Optica, A. P. 1-948, Leon Gto., 37160 (Mexico); De la Rosa, E., E-mail: elder@cio.mx [Centro de Investigaciones en Optica, A. P. 1-948, Leon Gto., 37160 (Mexico); Salas, P. [Centro de Fisica Aplicada y Tecnologia Avanzada, Universidad Nacional Autonoma de Mexico, A.P. 1-1010, Queretaro, Qro. 76000 (Mexico)] [Centro de Fisica Aplicada y Tecnologia Avanzada, Universidad Nacional Autonoma de Mexico, A.P. 1-1010, Queretaro, Qro. 76000 (Mexico); Velazquez-Salazar, J.J. [Department of Physics and Astronomy, The University of Texas at San Antonio One UTSA Circle, San Antonio TX 78249 (United States)] [Department of Physics and Astronomy, The University of Texas at San Antonio One UTSA Circle, San Antonio TX 78249 (United States)

    2012-12-15T23:59:59.000Z

    In this paper, we report the obtained strong broadband blue photoluminescence (PL) emission centered at 427 nm for undoped BaZrO{sub 3} observed after 266 nm excitation of submicron crystals prepared by hydrothermal/calcinations method. This emission is enhanced with the introduction of Tm{sup 3+} ions and is stronger than the characteristic PL blue emission of such lanthanide. The proposed mechanism of relaxation for host lattice emission is based on the presence of oxygen vacancies produced during the synthesis process and the charge compensation due to the difference in the electron valence between dopant and substituted ion in the host. Brilliant white light emission with a color coordinate of (x=0.29, y=0.32) was observed by combining the blue PL emission from the host with the green and red PL emission from Tb{sup 3+} and Eu{sup 3+} ions, respectively. The color coordinate can be tuned by changing the ratio between blue, green and red band by changing the concentration of lanthanides. - Graphical abstract: Strong blue emission from undoped BaZrO{sub 3} phosphor and white light emission by doping with Tb{sup 3+} (green) and Eu{sup 3+} (red) after 266 nm excitation. Highlights: Black-Right-Pointing-Pointer Blue emission from BaZrO{sub 3} phosphor. Black-Right-Pointing-Pointer Blue emission enhanced with Tm{sup 3+}. Black-Right-Pointing-Pointer White light from BaZrO{sup 3+} phosphor.

  14. Characterization of the reaction products that develop in the processing of Al{sub 2}O{sub 3}/BaZrO{sub 3} laminated composites

    SciTech Connect (OSTI)

    Gladysz, G.M. [Youngstown State Univ., OH (United States). Dept. of Chemical Engineering] [Youngstown State Univ., OH (United States). Dept. of Chemical Engineering; Schmuecker, M.; Schneider, H. [German Aerospace Establishment, Cologne (Germany)] [German Aerospace Establishment, Cologne (Germany); Chawla, K.K. [Univ. of Alabama, Birmingham, AL (United States). Dept. of Materials and Mechanical Engineering] [Univ. of Alabama, Birmingham, AL (United States). Dept. of Materials and Mechanical Engineering; Joslin, D.L.; Ferber, M.K. [Oak Ridge National Lab., TN (United States)] [Oak Ridge National Lab., TN (United States)

    1998-04-01T23:59:59.000Z

    The absence of a chemical reaction at an interface is conventionally thought to be an important criterion in producing a tough ceramic matrix composite (CMC). As a result of this criterion, interphases in CMCs were chosen on the basis of their chemical reactivity. A weak interface results in crack deflection, crack bridging, and, in fiber-reinforced ceramics, fiber pullout, resulting in an increased fracture toughness. In this paper, the authors present microstructural observations on alumina (Al{sub 2}O{sub 3})-barium zirconate (BaZrO{sub 3}) laminated composites wherein the reaction products that develop during processing resulted in sharp interfaces and appear to be weak enough to deflect cracks. These in situ reaction products in Al{sub 2}O{sub 3}-BaZrO{sub 3} laminated composites were characterized with the use of a scanning electron microscope, an electron microprobe, and a transmission electron microscope. The phases that develop, ZrO{sub 2}, BaO{center_dot}Al{sub 2}O{sub 3}, and BaO{center_dot}6 Al{sub 2}O{sub 3}, produced sharp interfaces and are arranged in a sequence that could be predicted by using information from the phase diagram.

  15. Single Phase Melt Processed Powellite (Ba,Ca) MoO{sub 4} For The Immobilization Of Mo-Rich Nuclear Waste

    SciTech Connect (OSTI)

    Brinkman, Kyle [Savannah River Site (SRS), Aiken, SC (United States); Marra, James [Savannah River Site (SRS), Aiken, SC (United States); Fox, Kevin [Savannah River Site (SRS), Aiken, SC (United States); Reppert, Jason [Savannah River Site (SRS), Aiken, SC (United States); Crum, Jarrod [Paci fic Northwest National Laboratory , Richland, WA (United States); Tang, Ming [Los Alamos National Laboratory , Los Alamos, NM (United States)

    2012-09-17T23:59:59.000Z

    Crystalline and glass composite materials are currently being investigated for the immobilization of combined High Level Waste (HLW) streams resulting from potential commercial fuel reprocessing scenarios. Several of these potential waste streams contain elevated levels of transition metal elements such as molybdenum (Mo). Molybdenum has limited solubility in typical silicate glasses used for nuclear waste immobilization. Under certain chemical and controlled cooling conditions, a powellite (Ba,Ca)MoO{sub 4} crystalline structure can be formed by reaction with alkaline earth elements. In this study, single phase BaMoO{sub 4} and CaMoO{sub 4} were formed from carbonate and oxide precursors demonstrating the viability of Mo incorporation into glass, crystalline or glass composite materials by a melt and crystallization process. X-ray diffraction, photoluminescence, and Raman spectroscopy indicated a long range ordered crystalline structure. In-situ electron irradiation studies indicated that both CaMoO{sub 4} and BaMoO{sub 4} powellite phases exhibit radiation stability up to 1000 years at anticipated doses with a crystalline to amorphous transition observed after 1 X 10{sup 13} Gy. Aqueous durability determined from product consistency tests (PCT) showed low normalized release rates for Ba, Ca, and Mo (<0.05 g/m{sup 2}).

  16. Essential Studies Worksheet B.A. with major in Computer Science I. Communication 9 Credits (6 credits writing and 3 credits Oral Communication)

    E-Print Network [OSTI]

    Delene, David J.

    Essential Studies Worksheet ­ B.A. with major in Computer Science I. Communication 9 Credits (6 credits writing and 3 credits Oral Communication) Special Emphasis Area: Course: Credits: Semester Special Emphasis Area requirements that may fall outside of Communication, Social Sciences, Arts

  17. Greenhouse Heating Checklist1 R. A. Bucklin, P. H. Jones, B.A. Barmby, D. B. McConnell, and R. W. Henley2

    E-Print Network [OSTI]

    Watson, Craig A.

    CIR791 Greenhouse Heating Checklist1 R. A. Bucklin, P. H. Jones, B.A. Barmby, D. B. Mc heating is the union of an appropriate heat source and an efficient heat distribu- tion system. The best greenhouse heat source in the world is useless if the heat cannot be transferred to the plant environment

  18. Barium Titanate and Bismuth Oxide Nanocomposites Barium titanate, BaTiO3, and bismuth oxide Bi2O3 are transparent materials with

    E-Print Network [OSTI]

    Harmon, Julie P.

    Barium Titanate and Bismuth Oxide Nanocomposites Barium titanate, BaTiO3, and bismuth oxide Bi2O3 that are lead-free. If we cannot shield effectively at nanofiller levels where transparency is maintained, we, Condensed Matter, Vol. 15, 8927 (2003). 21. "Highly Nonlinear Bismuth-Oxide Fiber for Smooth Supercontinuun

  19. Data:68ce477e-490b-4d2b-a92e-a7309a5ce45b | Open Energy Information

    Open Energy Info (EERE)

    >> Category:Categories Retrieved from "http:en.openei.orgwindex.php?titleData:68ce477e-490b-4d2b-a92e-a7309a5ce45b&oldid756745" Category: Utility Rates What links...

  20. The School offers the Bachelor of Science (B.S.) and Bachelor of Arts (B.A) degrees in computer science.

    E-Print Network [OSTI]

    Thomas, Andrew

    The School offers the Bachelor of Science (B.S.) and Bachelor of Arts (B.A) degrees in computer science. Computer science is the foundation of computing and information technology. Computer scientists and services. The required course work in computer science provides the student with an understanding

  1. Effect of strain on tunability in Ba0.60Sr0.40TiO3 thin films on PtSi substrates

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Effect of strain on tunability in Ba0.60Sr0.40TiO3 thin films on Pt­Si substrates D. M. Potrepkaa, M. W. Cole, and W. D. Nothwang Weapons & Materials Research Directorate, Active Materials Research discussed the effects that postannealing in oxygen can have to overcome limits on oxygen diffusion

  2. 54 Club Business International | APrIL 2013 | ihrsa.org Download the Free IHrSA App: ihrsa.org/app CBI goes BaCK to

    E-Print Network [OSTI]

    Ginzel, Matthew

    .org/app CBI goes BaCK to sCHooL to Find oUt wHat's new C lub operators understand the value and importance asymmetries in the body. At Springfield, students complete a class in basic exercise testing and prescrip

  3. CDMA Uplink Power Control as a Noncooperative Game 1 Tansu Alpcan 2 , Tamer Ba sar 2 , R. Srikant 2 , and Eitan Altman 3

    E-Print Network [OSTI]

    Srikant, Rayadurgam

    , Univeridad de Los Andes, Merida, Venezuela. 1 #12; Power control in CDMA systems are in either open control algorithm converges under a wide variety of interference models. Another distributed power controlCDMA Uplink Power Control as a Noncooperative Game 1 Tansu Alpcan 2 , Tamer Ba#24;sar 2 , R

  4. Oxygen-related dielectric relaxation and leakage characteristics of Pt,,Ba,Sr...TiO3 Pt thin-film capacitors

    E-Print Network [OSTI]

    Cao, Wenwu

    Oxygen-related dielectric relaxation and leakage characteristics of PtÕ,,Ba,Sr...TiO3 ÕPt thin to the postannealing temperature in oxygen and nitrogen atmosphere. High leakage currents and low-frequency dielectric and subsequently annealed in oxygen at 350 °C. Such results are related to the mobile oxygen ions and oxygen

  5. Data:Bce2f4c5-a03a-4631-8a13-bf8a9d9ba7ab | Open Energy Information

    Open Energy Info (EERE)

    Bce2f4c5-a03a-4631-8a13-bf8a9d9ba7ab No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading......

  6. Accuracy Test for Link Prediction in terms of Similarity Index: The Case of WS and BA Models

    E-Print Network [OSTI]

    Ahn, Min-Woo

    2015-01-01T23:59:59.000Z

    Link prediction is a technique that uses the topological information in a given network to infer the missing links in it. Since past research on link prediction has primarily focused on enhancing performance for given empirical systems, negligible attention has been devoted to link prediction with regard to network models. In this paper, we thus apply link prediction to two network models: The Watts-Strogatz (WS) model and Barab\\'asi-Albert (BA) model. We attempt to gain a better understanding of the relation between accuracy and each network parameter (mean degree, the number of nodes and the rewiring probability in the WS model) through network models. Six similarity indices are used, with precision and area under the ROC curve (AUC) value as the accuracy metrics. We observe a positive correlation between mean degree and accuracy, and size independence of the AUC value.

  7. Signatures of quantum criticality in the thermopower of Ba(Fe1?xCox)2As2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Arsenijevi?, S.; Hodovanets, H.; Gaál, R.; Forró, L.; Bud'ko, S. L.; Canfield, P. C.

    2013-06-01T23:59:59.000Z

    We demonstrate that the thermopower (S) can be used to probe the spin fluctuations (SFs) in proximity to the quantum critical point (QCP) in Fe-based superconductors. The sensitivity of S to the entropy of charge carriers allows us to observe an increase of S/T in Ba(Fe1?xCox)2As2 close to the spin-density-wave (SDW) QCP. This behavior is due to the coupling of low-energy conduction electrons to two-dimensional SFs, similar to heavy-fermion systems. The low-temperature enhancement of S/T in the Co substitution range 0.02c?0.05, close to the highest superconducting Tc. This analysis indicates that low-T thermopower is influenced by critical spin fluctuations which are important for the superconducting mechanism.

  8. Heterojunction band offsets and dipole formation at BaTiO{sub 3}/SrTiO{sub 3} interfaces

    SciTech Connect (OSTI)

    Balaz, Snjezana [Department of Physics and Astronomy, Youngstown State University, One University Plaza, Youngstown, Ohio 44555 (United States)] [Department of Physics and Astronomy, Youngstown State University, One University Plaza, Youngstown, Ohio 44555 (United States); Zeng, Zhaoquan [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States)] [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States); Brillson, Leonard J. [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States) [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States); Department of Physics, The Ohio State University, 191 West Woodruff, Columbus, Ohio 43210 (United States)

    2013-11-14T23:59:59.000Z

    We used a complement of photoemission and cathodoluminescence techniques to measure formation of the BaTiO{sub 3} (BTO) on SrTiO{sub 3} (STO) heterojunction band offset grown monolayer by monolayer by molecular beam epitaxy. X-ray photoemission spectroscopy (XPS) provided core level and valence band edge energies to monitor the valence band offset in-situ as the first few crystalline BTO monolayers formed on the STO substrate. Ultraviolet photoemission spectroscopy (UPS) measured Fermi level positions within the band gap, work functions, and ionization potentials of the growing BTO film. Depth-resolved cathodoluminescence spectroscopy measured energies and densities of interface states at the buried heterojunction. Kraut-based XPS heterojunction band offsets provided evidence for STO/BTO heterojunction linearity, i.e., commutativity and transitivity. In contrast, UPS and XPS revealed a large dipole associated either with local charge transfer or strain-induced polarization within the BTO epilayer.

  9. Physical properties and electronic structure of a new barium titanate suboxide Ba1+?Ti13-?O?? (? = 0.11)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rotundu, Costel R.; Jiang, Shan; Deng, Xiaoyu; Qian, Yiting; Khan, Saeed; Hawthorn, David G.; Kotliar, Gabriel; Ni, Ni

    2015-04-01T23:59:59.000Z

    The structure, transport, thermodynamic properties, x-ray absorption spectra (XAS), and electronic structure of a new barium titanate suboxide, Ba1+?Ti13-?O?? (? = 0.11), are reported. It is a paramagnetic poor metal with hole carriers dominating the transport. Fermi liquid behavior appears at low temperature. The oxidization state of Ti obtained by the XAS is consistent with the metallic Ti²? state. Local density approximation band structure calculations reveal the material is near the Van Hove singularity. The pseudogap behavior in the Ti-d band and the strong hybridization between the Ti-d and O-p orbitals reflect the characteristics of the building blocks of themore »Ti?? semi-cluster and the TiO? quasi-squares, respectively.« less

  10. Physical properties and electronic structure of a new barium titanate suboxide Ba1+?Ti13-?O?? (? = 0.11)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rotundu, Costel R. [Univ. of California Los Angeles, Los Angeles, CA (United States); Jiang, Shan [Univ. of California Los Angeles, Los Angeles, CA (United States); Deng, Xiaoyu [Rutgers Univ., Piscataway, NJ (United States)] (ORCID:0000000178020966); Qian, Yiting [Univ. of Waterloo, Waterloo (Canada)] (ORCID:0000000250175517); Khan, Saeed [Univ. of California Los Angeles, Los Angeles, CA (United States); Hawthorn, David G. [Univ. of Waterloo, Waterloo (Canada)] (ORCID:0000000270020416); Kotliar, Gabriel [Rutgers Univ., Piscataway, NJ (United States); Ni, Ni [Univ. of California Los Angeles, Los Angeles, CA (United States)

    2015-04-01T23:59:59.000Z

    The structure, transport, thermodynamic properties, x-ray absorption spectra (XAS), and electronic structure of a new barium titanate suboxide, Ba1+?Ti13-?O?? (? = 0.11), are reported. It is a paramagnetic poor metal with hole carriers dominating the transport. Fermi liquid behavior appears at low temperature. The oxidization state of Ti obtained by the XAS is consistent with the metallic Ti²? state. Local density approximation band structure calculations reveal the material is near the Van Hove singularity. The pseudogap behavior in the Ti-d band and the strong hybridization between the Ti-d and O-p orbitals reflect the characteristics of the building blocks of the Ti?? semi-cluster and the TiO? quasi-squares, respectively.

  11. Superconducting Tl/sub 2/Ba/sub 2/CuO/sub 6/: the orthorhombic form

    SciTech Connect (OSTI)

    Parise, J.B.; Gopalakrishnan, J.; Subramanian, M.A.; Sleight, A.W.

    1988-10-01T23:59:59.000Z

    The structure of an orthorhombic variant of Tl/sub 2/Ba/sub 2/CuO/sub 6/ (Z = 4), with a superconducting onset at 90K, has been studied using neutron powder diffractometry at 12 K (a = 5.4834(3), b = 5.4586(3), c = 23.198(1) /Angstrom/), 60 K (a = 5.4834(3), b = 5.4585(3), c = 23.199(1) /Angstrom/), and 293 K (a = 5.4967(3), b = 5.4651(3), c = 23.246(1) /Angstrom/). The distortion from I4/mmm symmetry, reported in single-crystal X-ray investigations, to Abma is manifested in the Tl-O layer. At the temperatures studied, the coordination of Tl to oxygen is (2 + 1 + 2) square pyramidal rather than octahedral. At lower temperatures, distortion decreases but does not disappear. Despite the orthorhombic symmetry the CuO/sub 2/-layers remain flat.

  12. Giant magnetocaloric effect in magnetoelectric Eu{sub 1-x}Ba{sub x}TiO{sub 3}

    SciTech Connect (OSTI)

    Rubi, Km; Kumar, Pawan; Maheswar Repaka, D. V.; Chen, Ruofan; Wang, Jian-Sheng; Mahendiran, R., E-mail: phyrm@nus.edu.sg [Department of Physics, 2 Science Drive 3, Faculty of Science, National University of Singapore, Singapore 117551 (Singapore)

    2014-01-20T23:59:59.000Z

    We report the magnetic entropy change (?S{sub m}) in magnetoelectric Eu{sub 1-x}Ba{sub x}TiO{sub 3} for 0.1???x???0.9. We find ??S{sub m}?=?11 (40) J/kg·K in x?=?0.1 for a field change of 1 (5) T, respectively, which is the largest value among all Eu-based oxides. ?S{sub m} arises from the field-induced suppression of the spin entropy of Eu{sup 2+}:4f{sup 7} localized moments. While ???S{sub m}? decreases with increasing x, ???S{sub m}??=?6.58?J/kg·K observed in the high spin diluted composition x?=?0.9 is larger than that in many manganites. Our results indicate that these magnetoelectrics are potential candidates for cryogenic magnetic refrigeration.

  13. Low-energy planar magnetic defects in BaFe2As2: Nanotwins, twins, antiphase, and domain boundaries

    SciTech Connect (OSTI)

    Khan, S. N. [Ames Laboratory] [Ames Laboratory; Alam, A. [Ames Laboratory] [Ames Laboratory; Johnson, Duane D. [University of Illinois, Urbana-Champaign] [University of Illinois, Urbana-Champaign

    2013-01-01T23:59:59.000Z

    In BaFe2As2, structural and magnetic planar defects begin to proliferate below the structural phase transition, affecting descriptions of magnetism and superconductivity.We study, using density-functional theory, the stability and magnetic properties of competing antiphase and domain boundaries, twins and isolated nanotwins (twin nuclei), and spin excitations proposed and/or observed. These nanoscale defects have a very low surface energy (22 210 m Jm 2), with twins favorable to the mesoscale. Defects exhibit smaller moments confined near their boundaries making a uniform-moment picture inappropriate for long-range magnetic order in real samples. Nanotwins explain features in measured pair distribution functions so should be considered when analyzing scattering data. All these defects can be weakly mobile and/or can have fluctuations that lower

  14. Low-energy planar magnetic defects in BaFe2As2: Nanotwins, twins, antiphase, and domain boundaries

    SciTech Connect (OSTI)

    Khan, Suffian N. [Ames Laboratory; Alam, Aftab [Ames Laboratory; Johnson, Duane D. [Ames Laboratory

    2013-11-27T23:59:59.000Z

    In BaFe2As2, structural and magnetic planar defects begin to proliferate below the structural phase transition, affecting descriptions of magnetism and superconductivity. We study, using density-functional theory, the stability and magnetic properties of competing antiphase and domain boundaries, twins and isolated nanotwins (twin nuclei), and spin excitations proposed and/or observed. These nanoscale defects have a very low surface energy (22–210 m Jm?2), with twins favorable to the mesoscale. Defects exhibit smaller moments confined near their boundaries—making a uniform-moment picture inappropriate for long-range magnetic order in real samples. Nanotwins explain features in measured pair distribution functions so should be considered when analyzing scattering data. All these defects can be weakly mobile and/or can have fluctuations that lower assessed “ordered” moments from longer spatial and/or time averaging and should be considered directly.

  15. Coexistence of the spini-density-wave and superconductivity in the Ba1-xKxFe2As2

    SciTech Connect (OSTI)

    Bao, Wei [Los Alamos National Laboratory; Chen, H [HEFEI NAT. LAB; Ren, Y [ANL; Qiu, Y [NIST CENTER FOR NEUTRON; Liu, R [HEFEI NAT. LAB.; Wu, G H [HEFEI NAT. LAB; Wu, T [HEFEI NAT. LAB.; Xie, Y L [HEFEI NAT. LAB; Wang, F [HEFEI NAT. LAB.; Huang, Q [NIST CENTER FOR NEUTRON; Chen, X H [HEFEI NAT. LAB

    2008-01-01T23:59:59.000Z

    The relation between the spin-density-wave (SDW) and superconducting order is a central topic in current research on the FeAs-based high T{sub c} superconductors. Conflicting results exist in the LaFeAs(O,F)-class of materials, for which whether the SDW and superconductivity are mutually exclusive or they can coexist has not been settled. Here we show that for the (Ba,K)Fe{sub 2}As{sub 2} system, the SDW and superconductivity can coexist in an extended range of compositions. The availability of single crystalline samples and high value of the energy gaps would make the materials a model system to investigate the high T{sub c} ferropnictide superconductivity.

  16. Novel chemically stable Ba3Ca1.18Nb1.82-xYxO9- proton conductor: improved proton conductivity through tailored cation ordering

    SciTech Connect (OSTI)

    Wang, Siwei [University of South Carolina, Columbia] [University of South Carolina, Columbia; Chen, Yan [ORNL] [ORNL; Fang, Shumin [University of South Carolina, Columbia] [University of South Carolina, Columbia; Zhang, Lingling [University of South Carolina, Columbia] [University of South Carolina, Columbia; Tang, Ming [Los Alamos National Laboratory (LANL)] [Los Alamos National Laboratory (LANL); An, Ke [ORNL] [ORNL; Brinkman, Dr. Kyle S. [Savannah River National Laboratory (SRNL), Aiken, S.C.] [Savannah River National Laboratory (SRNL), Aiken, S.C.; Chen, Fanglin [University of South Carolina, Columbia] [University of South Carolina, Columbia

    2014-01-01T23:59:59.000Z

    Simple perovskite-structured proton conductors encounter significant challenges to simultaneously achieving excellent chemical stability and proton conductivity that are desirable for many important applications in energy conversion and storage. This work demonstrates that Y-doped complex-perovskite-structured Ba3Ca1.18Nb1.82 xYxO9 materials possess both improved proton conductivity and exceptional chemical stability. Neutron powder diffraction refinement revealed a Fm3 m perovskite-structure and increased oxygen vacancy concentration due to the Y doping. High-resolution TEM analysis confirmed the perturbation of the B site cation ordering in the structure for the Ba3Ca1.18Nb1.82 xYxO9 materials. Such combined effects led to improved proton conductivity with a value of 5.3 10 3 S cm 1 at 600 C for Ba3Ca1.18Nb1.52Y0.3O9 (BCNY0.3), a value 2.4 times higher compared with that of the undoped Ba3Ca1.18Nb1.82O9 . The Ba3Ca1.18Nb1.82 xYxO9 materials showed remarkable chemical stability toward water and demonstrated no observable reactions to CO2 exposure. Ionic transport number studies showed that BCNY0.3 had predominantly proton conduction below 600 C. Solid oxide fuel cells using BCNY0.3 as an electrolyte demonstrated cell power output of 103 mW cm 2 at 750 C. These results suggest that a doping strategy that tailors the cation ordering in complex perovskites provides a new direction in the search for novel proton conducting ceramics.

  17. Josefina Plá: Su partida sin retorno

    E-Print Network [OSTI]

    Bogado, Ví ctor

    1999-04-01T23:59:59.000Z

    Almería. Es en la revista Donostía de San Sebastián donde publica su primer poema, a los 6 años. En 1926 contrae matrimonio con el ceramista paraguayo Julián de la Herrería y ya en tierra guaraní se incorpora al proceso cultural trabajando como..., Herib Campos Cervera, Elvio Romero, Oscar Ferreiro, entre otros. En 1952 es miembro fundador del movimiento "Arte Nuevo," punta de lanza para la renovación de la plástica moderna paraguaya. En 1957 obtiene, junto a su discípulo José Laterza, el premio...

  18. Sr{sub 7}Ge{sub 6}, Ba{sub 7}Ge{sub 6} and Ba{sub 3}Sn{sub 2} -Three new binary compounds containing dumbbells and four-membered chains of tetrel atoms with considerable Ge-Ge {pi}-bonding character

    SciTech Connect (OSTI)

    Siggelkow, Lisa; Hlukhyy, Viktor [Department Chemie, Technische Universitaet Muenchen, Lichtenbergstr. 4, D-85747 Garching (Germany); Faessler, Thomas F., E-mail: thomas.faessler@lrz.tum.de [Department Chemie, Technische Universitaet Muenchen, Lichtenbergstr. 4, D-85747 Garching (Germany)

    2012-07-15T23:59:59.000Z

    The germanides Sr{sub 7}Ge{sub 6} and Ba{sub 7}Ge{sub 6} as well as the stannide Ba{sub 3}Sn{sub 2} were prepared by arc melting and annealing in welded tantalum ampoules using induction as well as resistance furnaces. The compounds were investigated by powder and single crystal X-ray diffraction. Sr{sub 7}Ge{sub 6} and Ba{sub 7}Ge{sub 6} crystallize in the Ca{sub 7}Sn{sub 6} structure type (space group Pmna, Z=4: a=7.777(2) A, b=23.595(4) A, c=8.563(2) A, wR{sub 2}=0.081 (all data), 2175 independent reflections, 64 variable parameters for Sr{sub 7}Ge{sub 6} and a=8.0853(6) A, b=24.545(2) A, c=8.9782(8) A, wR{sub 2}=0.085 (all data), 2307 independent reflections, 64 variable parameters for Ba{sub 7}Ge{sub 6}). Ba{sub 3}Sn{sub 2} crystallizes in an own structure type with the space group P4{sub 3}2{sub 1}2, Z=4, a=6.6854(2) A, c=17.842(2) A, wR{sub 2}=0.037 (all data), 1163 independent reflections, 25 variable parameters. In Sr{sub 7}Ge{sub 6} and Ba{sub 7}Ge{sub 6} the Ge atoms are arranged as Ge{sub 2} dumbbells and Ge{sub 4} four-membered atom chains. Their crystal structures cannot be rationalized according to the (8-N) rule. In contrast, Ba{sub 3}Sn{sub 2} presents Sn{sub 2} dumbbells as a main structural motif and thereby can be described as an electron precise Zintl phase. The chemical bonding situation in these structures is discussed on the basis of partial and total Density Of States (DOS) curves, band structures including fatbands, topological analysis of the Electron Localization Function (ELF) as well as Bader analysis of the bond critical points using the programs TB-LMTO-ASA and WIEN2K. While Ba{sub 3}Sn{sub 2} reveals semiconducting behaviour, all germanides Ae{sub 7}Ge{sub 6} (Ae=Ca, Sr, and Ba) show metallic properties and a considerable {pi}-bonding character between the Ge atoms of the four-membered chains and the dumbbells. The {pi}-bonding character of the germanides is best reflected by the resonance hybrid structures {l_brace}[Ge-Ge]{sup 6-}/[Ge-{sup ....}Ge-{sup ....}Ge-{sup ....}Ge]{sup 8-}{r_brace}{r_reversible}{l_brace}[Ge=Ge]{sup 4-}/[Ge-Ge-Ge-Ge]{sup 10-}{r_brace}. - Graphical abstract: The structure of Ba{sub 3}Sn{sub 2} contains Sn{sub 2} dumbbells as a main structural motif and thereby can be described as an electron precise Zintl phase. Ge{sub 2} dumbbells and Ge{sub 4} four-membered atom chains are the predominant features in Sr{sub 7}Ge{sub 6} and Ba{sub 7}Ge{sub 6}. Their crystal structures cannot be rationalized according to the (8-N) rule. While Ba{sub 3}Sn{sub 2} reveals semiconducting behaviour, the germanides Ae{sub 7}Ge{sub 6} (Ae=Ca, Sr, and Ba) show metallic properties and a considerable {pi}-bonding character between the Ge atoms of the four-membered chains and the dumbbells. Highlights: Black-Right-Pointing-Pointer The germanides Sr{sub 7}Ge{sub 6} and Ba{sub 7}Ge{sub 6} as well as the stannide Ba{sub 3}Sn{sub 2} have been synthesized. Black-Right-Pointing-Pointer In Sr{sub 7}Ge{sub 6} and Ba{sub 7}Ge{sub 6} the Ge atoms are arranged as dumbbells and four-membered atom chains. Black-Right-Pointing-Pointer Ba{sub 3}Sn{sub 2} presents Sn{sub 2} dumbbells as a main structural motif. Black-Right-Pointing-Pointer The chemical bonding situation within these structures is discussed.

  19. Hunter College of the City University of New York -Office of the Registrar DEGREE AUDIT APPLICATION FORM (DAAF) Attachment BA in Adolescent Education: Spanish 7-12 (E80)

    E-Print Network [OSTI]

    Qiu, Weigang

    APPLICATION FORM (DAAF) Attachment BA in Adolescent Education: Spanish 7-12 (E80) LIBERAL ARTS AND SCIENCE Summer SEDC 452.80 Student Teaching in Grades 7-12: Spanish 5 Fall Spring Summer SPED 308* Teaching

  20. Infrared Measurement of the Pseudogap of P-Doped and Co-Doped High-Temperature BaFe2As2 Superconductors

    SciTech Connect (OSTI)

    Moon, S.J.; Schafgans, A.A.; Kasahara, S.; Shibauchi, T.; Terashima, T.; Matsuda, Y.; Tanatar, Makariy A.; Prozorov, Ruslan; Thaler, Alexander; Canfield, Paul C.; Sefat, A.S.; Mandrus, D.; Basov, D.N.

    2012-07-13T23:59:59.000Z

    We report on infrared studies of charge dynamics in a prototypical pnictide system: the BaFe2As2 family. Our experiments have identified hallmarks of the pseudogap state in the BaFe2As2 system that mirror the spectroscopic manifestations of the pseudogap in the cuprates. The magnitude of the infrared pseudogap is in accord with that of the spin-density-wave gap of the parent compound. By monitoring the superconducting gap of both P- and Co-doped compounds, we find that the infrared pseudogap is unrelated to superconductivity. The appearance of the pseudogap is found to correlate with the evolution of the antiferromagnetic fluctuations associated with the spin-density-wave instability. The strong-coupling analysis of infrared data further reveals the interdependence between the magnetism and the pseudogap in the iron pnictides.

  1. Abnormal thermal conductivity in tetragonal tungsten bronze Ba{sub 6?x}Sr{sub x}Nb{sub 10}O{sub 30}

    SciTech Connect (OSTI)

    Kolodiazhnyi, T., E-mail: kolodiazhnyi.taras@nims.go.jp; Sakurai, H.; Vasylkiv, O.; Borodianska, H. [National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Mozharivskyj, Y. [Department of Chemistry and Chemical Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario L8S4M1 (Canada)

    2014-03-17T23:59:59.000Z

    Ba{sub 6?x}Sr{sub x}Nb{sub 10}O{sub 30} solid solution with 0???x???6 crystallizes in centrosymmetric tetragonal “tungsten bronze” structure (space group P4/mbm). We report on the x dependence of thermal conductivity of polycrystalline samples measured in the 2–400?K temperature interval. Substitution of Sr for Ba brings about a significant decrease in thermal conductivity at x???3 accompanied by development of a low-temperature (T???10–30?K) “plateau” region reminiscent of a glass-like compounds. We explain this behaviour based on a size-driven site occupancy and atomic displacement parameters associated with an alkaline earth atomic positions in the title compounds.

  2. PUGLIA BARI ALTAMURA FIORENZO SARA BA 70022 VIA LAV1GNA. 2 0803212459 Dal lune& al Venerdl dalle ore 09.00 alle ore 13 DO e dalle

    E-Print Network [OSTI]

    Malerba, Donato

    ore 09.00 alle ore 13 DO e dalle ore 16:00 alle ore 20 00. Sabato dalle 09:00 alle 1310 PUGLIA BARI Venerdì dalle ore 09:00 alle ore 13:00 e dalle ore I6:00 alle ore 19:00 PUGLIA BARI GIOVINAllO ILLUZZI MARIA LUCIA BA 70054 VIA TRIESTE, 7 0803946280 0803946280 Dal lancia al Venerdì dalle ore 10 OD alle ore

  3. Structural and electronic properties of Sr{sub x}Ba{sub 1-x}SnO{sub 3} from first principles calculations

    SciTech Connect (OSTI)

    Moreira, E. [Departamento de Fisica Teorica e Experimental, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil); Henriques, J.M. [Centro de Educacao e Saude, Universidade Federal de Campina Grande, Campus Cuite, 58175-000 Cuite-PB (Brazil); Azevedo, D.L. [Departamento de Fisica, Universidade Federal do Maranhao, Centro de Ciencias Exatas e Tecnologia, 65085-580 Sao Luis-MA (Brazil); Caetano, E.W.S., E-mail: ewcaetano@gmail.com [Instituto Federal de Educacao, Ciencia e Tecnologia do Ceara, 60040-531 Fortaleza-CE (Brazil); Freire, V.N. [Departamento de Fisica, Universidade Federal do Ceara, Centro de Ciencias, Caixa Postal 6030, Campus do Pici, 60455-760 Fortaleza-CE (Brazil); Albuquerque, E.L. [Departamento de Biofisica e Farmacologia, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil)

    2012-03-15T23:59:59.000Z

    Neutron diffraction data for Sr{sub x}Ba{sub 1-x}SnO{sub 3} (x=0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) solid solutions were used as inputs to obtain optimized geometries and electronic properties using the density functional theory (DFT) formalism considering both the local density and generalized gradient approximations, LDA and GGA, respectively. The crystal structures and SnO{sub 6} octahedra tilting angles found after total energy minimization agree well with experiment, specially for the GGA data. Elastic constants were also obtained and compared with theoretical and experimental results for cubic BaSnO{sub 3}. While the alloys with cubic unit cell have an indirect band gap, tetragonal and orthorhombic alloys exhibit direct band gaps (exception made to x=1.0). The Kohn-Sham minimum electronic band gap oscillates from 1.52 eV (cubic x=0.0, LDA) to 2.61 eV (orthorhombic x=1.0, LDA), and from 0.74 eV (cubic BaSnO{sub 3}, GGA) to 1.97 eV (orthorhombic SrSnO{sub 3}, GGA). Parabolic interpolation of bands has allowed us to estimate the effective masses for charge carriers, which are shown to be anisotropic and larger for holes. - Graphical Abstract: Highlights: Black-Right-Pointing-Pointer DFT calculations were performed on Sr{sub x}Ba{sub 1-x}SnO{sub 3} solid solutions. Black-Right-Pointing-Pointer Calculated crystal structures agree well with experiment. Black-Right-Pointing-Pointer Alloys have direct or indirect gaps depending on the Sr molar fraction. Black-Right-Pointing-Pointer The Kohn-Sham gap variation from x=0.0 to x=1.0 is close to the experimental value. Black-Right-Pointing-Pointer Carrier effective masses are very anisotropic, specially for holes.

  4. Low-Temperature Crystallization of SolGel Processed Pb0.5Ba0.5TiO3: Powders and Oriented Thin Films

    E-Print Network [OSTI]

    for depositing thin-film lead barium titanate has been developed. X-ray diffraction analysis showed perovskite. Deposition of the sol by spin coating on single-crystal and thin-film MgO on silicon resulted in highlyO, whereas entirely (100) films were obtained on thin-film MgO. I. Introduction TO USE Pb0.5Ba0.5TiO3 (PBT

  5. PHYSICAL REVIEW B 84, 014511 (2011) Comparative study of the phonons in nonsuperconducting BaC6 and superconducting CaC6 using

    E-Print Network [OSTI]

    Sheldon, Nathan D.

    2011-01-01T23:59:59.000Z

    and superconducting CaC6 using inelastic x-ray scattering A. C. Walters,1,2,* C. A. Howard,2 M. H. Upton,3,4 M. P. M as a function of temperature using inelastic x-ray scattering (IXS). In the case of the non-superconductor BaC6, in contrast to the reasonable agreement found in superconducting CaC6. Additional IXS intensity is observed

  6. Measurement of the B0 ---> Psi (2S) Lambda0 Branching Fraction on BaBar at the Stanford Linear Accelerator Center (Abstract Only)

    SciTech Connect (OSTI)

    Olivas, Alexander Raymond, Jr.; /Colorado U.

    2005-11-16T23:59:59.000Z

    The decays of B{sup 0} mesons to hadronic final states remains a rich area of physics on BaBar. Not only do the c{bar c}-K final states (e.g. B{sup 0} {yields} {psi}(2S)K{sup 0}) allow for the measurement of CP Violation, but the branching fractions provide a sensitive test of the theoretical methods used to account for low energy non-perturbative QCD effects. They present the measurement of the branching fraction for the decay B{sup 0} {yields} {psi}(2S)K{sub s}. The data set consists of 88.8 {+-} 1.0 x 10{sup 6} B{bar b} pairs collected on the e{sup +}e{sup -} {yields} {Upsilon}(4S) resonance on BaBar/PEP-II at the Stanford Linear Accelerator Center (SLAC). This analysis features a modification of present cuts, with respect to those published so far on BaBar, on the K{sub S} {yields} {pi}{sup +}{pi}{sup -} and {psi}(2S) {yields} J/{psi}{pi}{sup +}{pi}{sup -} which aim at reducing the background while keeping the signal intact. Various data selection criteria are studied for the lepton modes (e{sup +}e{sup -} and {mu}{sup +}{mu}{sup -}) of the J/{psi} and {psi}(2S) to improve signal purity as well as study the stability of the resultant branching fractions.

  7. Magnetisation studies of phase co-existence in Gd{sub 1-x}Ca{sub x}BaCo{sub 2}O{sub 5.5}

    SciTech Connect (OSTI)

    Thirumurugan, N. [Condensed Matter Physics Division, Indira Gandhi Centre for Atomic Research, Kalpakkam (India)] [Condensed Matter Physics Division, Indira Gandhi Centre for Atomic Research, Kalpakkam (India); Bharathi, A., E-mail: bharathi@igcar.gov.in [Condensed Matter Physics Division, Indira Gandhi Centre for Atomic Research, Kalpakkam (India); Arulraj, A.; Sundar, C.S. [Condensed Matter Physics Division, Indira Gandhi Centre for Atomic Research, Kalpakkam (India)] [Condensed Matter Physics Division, Indira Gandhi Centre for Atomic Research, Kalpakkam (India)

    2012-04-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer The series Gd{sub 1-x}Ca{sub x}BaCo{sub 2}O{sub 5.5} was synthesised by solid state reaction. Black-Right-Pointing-Pointer Magnetisation studies were carried out in the 4-300 K temperature range in magnetic fields upto 16 Tesla. Black-Right-Pointing-Pointer Results were used to formulate the T versus Ca fraction, phase diagram. Black-Right-Pointing-Pointer Evidence for Magnet-electronic phase separation is shown for the first time in the compound. -- Abstract: Magnetic properties of hole doped, oxygen deficient double perovskite compounds, Gd{sub 1-x}Ca{sub x}BaCo{sub 2}O{sub 5.5}, have been investigated. Ferromagnetic transition temperatures increase and the anti-ferromagnetic transition temperatures decrease with Ca substitution leading to stabilisation of ferromagnetisim for x {>=} 0.05. A detailed study of the ferromagnetic phase indicates the presence of double hysterisis loops for Ca fractions, 0.05 {<=} x {<=} 0.2 in the 50-200 K temperature range, suggestive of the co-existence of two ferromagnetic phases with different co-ercivities. Based on the magnetisation and transport measurements a phase diagram is proposed for Ca doped GdBaCo{sub 2}O{sub 5.5}.

  8. Structural and thermoelectric properties of BaRCo{sub 4}O{sub 7} (R = Dy, Ho, Er, Tm, Yb, and Lu)

    SciTech Connect (OSTI)

    Wong-Ng, W.; Yan, Y.; Liu, G. [Ceramics Division, NIST, Gaithersburg, Maryland 20899 (United States); Xie, W.; Tritt, T. [Department of Physics, Clemson University, Greensville, South Carolina 29634 (United States); Kaduk, J. [Illinois Institute of Technology, Chicago, Illinois 60616 (United States); Thomas, E. [Air Force Research Laboratory, Wright Pattersen, Ohio 45433 (United States)

    2011-12-01T23:59:59.000Z

    The structure and thermoelectric properties of a series of barium lanthanide cobaltites, BaRCo{sub 4}O{sub 7} (R = Dy, Ho, Er, Tm, Yb, and Lu), which were prepared using the spark plasma synthesis technique, have been investigated. The space group of these compounds was re-determined and confirmed to be P31c instead of the reported P6{sub 3}mc. The lattice parameters a and c range from 6.26279(2) Angst to 6.31181(6) Angst , and from 10.22468(6) Angst to 10.24446(15) Angst for R = Lu to Dy, respectively. The crystal structure of BaRCo{sub 4}O{sub 7} is built up from Kagome sheets of CoO{sub 4} tetrahedra, linked by triangular layers of CoO{sub 4} tetrahedra. The values of figure of merit (ZT) of the BaRCo{sub 4}O{sub 7} samples were determined to be around 0.02 at 800 K. X-ray diffraction patterns of these samples have been determined and submitted to the Powder Diffraction File.

  9. Multiferroicity and magneto-electric effect in Gd{sub 2}BaNiO{sub 5}

    SciTech Connect (OSTI)

    Chowki, S.; Mohapatra, N., E-mail: niharika@iitbbs.ac.in [Indian Institute of Technology Bhubaneswar, Bhubaneswar, Odisha 751013 (India); Basu, Tathamay; Singh, K.; Sampathkumaran, E. V. [Tata Institute of Fundamental Research, Homi Bhabha Road, Colaba, Mumbai 400005 (India)

    2014-06-07T23:59:59.000Z

    We report the observation of electric polarization in the magnetically ordered state of the Haldane chain compound, Gd{sub 2}BaNiO{sub 5}, with strongly correlated magnetic and dielectric properties. The results of dc magnetic susceptibility and heat capacity measurements indicate two magnetic transitions, one corresponding to the anti-ferromagnetic order at T{sub N}???55?K and the other to spin-reorientation transition at T{sub SR}???24?K. The dielectric permittivity (?{sub r}{sup ?}) and loss (tan?) also exhibit anomalies in the vicinity of T{sub SR} and T{sub N}, respectively. Below the spin-reorientation transition, concurrently magnetic-field-induced spin-flop and the meta-electric transitions are observed at a critical magnetic field in isothermal magnetization and magneto-dielectric results, respectively. Another interesting finding is that ??{sub r}{sup ?} (=(?{sub r}{sup ?}(H)??{sub r}{sup ?}(0))/?{sub r}{sup ?}(0)) changes its sign at the critical magnetic field. The origin of the observed magneto-electric effect is discussed on the basis of spin–phonon coupling.

  10. Superconducting gap evolution in overdoped BaFe?(As1-xPx)? single crystals through nanocalorimetry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Campanini, D.; Diao, Z.; Fang, L.; Kwok, W.-K.; Welp, U.; Rydh, A.

    2015-06-01T23:59:59.000Z

    We report on specific heat measurements on clean overdoped BaFe?(As1-xPx)? single crystals performed with a high resolution membrane-based nanocalorimeter. A nonzero residual electronic specific heat coefficient at zero temperature ?r=C/T|T?0 is seen for all doping compositions, indicating a considerable fraction of the Fermi surface ungapped or having very deep minima. The remaining superconducting electronic specific heat is analyzed through a two-band s-wave ? model in order to investigate the gap structure. Close to optimal doping we detect a single zero-temperature gap of ??~5.3 me V, corresponding to ??/kBTc ~ 2.2. Increasing the phosphorus concentration x, the main gap reduces tillmore »a value of ?? ~ 1.9 meV for x = 0.55 and a second weaker gap becomes evident. From the magnetic field effect on ?r, all samples however show similar behavior [?r(H) - ?r (H = 0)? Hn, with n between 0.6 and 0.7]. This indicates that, despite a considerable redistribution of the gap weights, the total degree of gap anisotropy does not change drastically with doping.« less

  11. Demonstrating the Model Nature of the High-Temperature Superconductor HgBa2CuO4+d

    SciTech Connect (OSTI)

    Barisic, Neven; Li, Yuan; Zhao, Xudong; Cho, Yong-Chan; Chabot-Couture, Guillaume; Yu, Guichuan; Greven, Martin; /SLAC, SSRL /Boskovic Inst., Zagreb /Stanford U., Phys. Dept. /Jilin U. /Stanford U., Appl. Phys. Dept.

    2008-09-30T23:59:59.000Z

    The compound HgBa{sub 2}CuO{sub 4+{delta}} (Hg1201) exhibits a simple tetragonal crystal structure and the highest superconducting transition temperature (T{sub c}) among all single Cu-O layer cuprates, with T{sub c} = 97 K (onset) at optimal doping. Due to a lack of sizable single crystals, experimental work on this very attractive system has been significantly limited. Thanks to a recent breakthrough in crystal growth, such crystals have now become available. Here, we demonstrate that it is possible to identify suitable heat treatment conditions to systematically and uniformly tune the hole concentration of Hg1201 crystals over a wide range, from very underdoped (T{sub c} = 47 K, hole concentration p {approx} 0.08) to overdoped (T{sub c} = 64 K, p {approx} 0.22). We then present quantitative magnetic susceptibility and DC charge transport results that reveal the very high-quality nature of the studied crystals. Using XPS on cleaved samples, we furthermore demonstrate that it is possible to obtain large surfaces of good quality. These characterization measurements demonstrate that Hg1201 should be viewed as a model high-temperature superconductor, and they provide the foundation for extensive future experimental work.

  12. Resonant Spin Excitation in the High Temperature Superconductor Ba0.6K0.4Fe2As2

    SciTech Connect (OSTI)

    Christianson, Andrew D [ORNL; Goremychkin, E. A. [ISIS Facility, Rutherford Appleton Laboratory; Osborn, R. [Argonne National Laboratory (ANL); Rosenkranz, Stephen [Argonne National Laboratory (ANL); Lumsden, Mark D [ORNL; Malliakas, C. [Northwestern University, Evanston; Todorov, L. [Northwestern University, Evanston; Claus, H. [Northwestern University, Evanston; Chung, D.Y. [Northwestern University, Evanston; Kanatzidis, M. [Northwestern University, Evanston; Bewley, Robert I. [ISIS Facility, Rutherford Appleton Laboratory; Guidi, T. [ISIS Facility, Rutherford Appleton Laboratory

    2008-01-01T23:59:59.000Z

    A new family of superconductors containing layers of iron arsenide has attracted considerable interest because of their high transition temperatures (T{sub c}), some of which are >50 K, and because of similarities with the high-{sub c} copper oxide superconductors. In both the iron arsenides and the copper oxides, superconductivity arises when an antiferromagnetically ordered phase has been suppressed by chemical doping. A universal feature of the copper oxide superconductors is the existence of a resonant magnetic excitation, localized in both energy and wavevector, within the superconducting phase. This resonance, which has also been observed in several heavy-fermion superconductors is predicted to occur when the sign of the superconducting energy gap takes opposite values on different parts of the Fermi surface, an unusual gap symmetry which implies that the electron pairing interaction is repulsive at short range. Angle-resolved photoelectron spectroscopy shows no evidence of gap anisotropy in the iron arsenides, but such measurements are insensitive to the phase of the gap on separate parts of the Fermi surface. Here we report inelastic neutron scattering observations of a magnetic resonance below T{sub c} in Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2}, a phase-sensitive measurement demonstrating that the superconducting energy gap has unconventional symmetry in the iron arsenide superconductors.

  13. Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Ba/Rh NOx Traps for Design and Optimization

    SciTech Connect (OSTI)

    Michael Harold; Vemuri Balakotaiah

    2010-05-31T23:59:59.000Z

    In this project a combined experimental and theoretical approach was taken to advance our understanding of lean NOx trap (LNT) technology. Fundamental kinetics studies were carried out of model LNT catalysts containing variable loadings of precious metals (Pt, Rh), and storage components (BaO, CeO{sub 2}). The Temporal Analysis of Products (TAP) reactor provided transient data under well-characterized conditions for both powder and monolith catalysts, enabling the identification of key reaction pathways and estimation of the corresponding kinetic parameters. The performance of model NOx storage and reduction (NSR) monolith catalysts were evaluated in a bench scale NOx trap using synthetic exhaust, with attention placed on the effect of the pulse timing and composition on the instantaneous and cycle-averaged product distributions. From these experiments we formulated a global model that predicts the main spatio-temporal features of the LNT and a mechanistic-based microkinetic models that incorporates a detailed understanding of the chemistry and predicts more detailed selectivity features of the LNT. The NOx trap models were used to determine its ability to simulate bench-scale data and ultimately to evaluate alternative LNT designs and operating strategies. The four-year project led to the training of several doctoral students and the dissemination of the findings as 47 presentations in conferences, catalysis societies, and academic departments as well 23 manuscripts in peer-reviewed journals. A condensed review of NOx storage and reduction was published in an encyclopedia of technology.

  14. Superconducting gap evolution in overdoped BaFe?(As1-xPx)? single crystals through nanocalorimetry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Campanini, D.; Diao, Z.; Fang, L.; Kwok, W.-K.; Welp, U.; Rydh, A.

    2015-06-01T23:59:59.000Z

    We report on specific heat measurements on clean overdoped BaFe?(As1-xPx)? single crystals performed with a high resolution membrane-based nanocalorimeter. A nonzero residual electronic specific heat coefficient at zero temperature ?r=C/T|T?0 is seen for all doping compositions, indicating a considerable fraction of the Fermi surface ungapped or having very deep minima. The remaining superconducting electronic specific heat is analyzed through a two-band s-wave ? model in order to investigate the gap structure. Close to optimal doping we detect a single zero-temperature gap of ??~5.3 me V, corresponding to ??/kBTc ~ 2.2. Increasing the phosphorus concentration x, the main gap reduces till a value of ?? ~ 1.9 meV for x = 0.55 and a second weaker gap becomes evident. From the magnetic field effect on ?r, all samples however show similar behavior [?r(H) - ?r (H = 0)? Hn, with n between 0.6 and 0.7]. This indicates that, despite a considerable redistribution of the gap weights, the total degree of gap anisotropy does not change drastically with doping.

  15. NdBaFe{sub 2}O{sub 5+w} and steric effect of Nd on valence mixing and ordering of Fe

    SciTech Connect (OSTI)

    Linden, J. [Department of Physics, AAbo Akademi, FI-20500 Turku (Finland); Karen, P., E-mail: pavel.karen@kjemi.uio.n [Department of Chemistry, University of Oslo, P.O.Box 1033, Blindern, N-0315 Oslo (Norway)

    2010-11-15T23:59:59.000Z

    NdBaFe{sub 2}O{sub 5} above and below Verwey transition is studied by synchrotron X-ray powder diffraction and Moessbauer spectroscopy and compared with GdBaFe{sub 2}O{sub 5} that adopts a higher-symmetry charge-ordered structure typical of the Sm-Ho variants of the title phase. Differences are investigated by Moessbauer spectroscopy accounting for iron valence states at their local magnetic and ionic environments. In the charge-ordered state, the orientation of the electric-field gradient (EFG) versus the internal magnetic field (B) agrees with experiment only when contribution from charges of the ordered d{sub xz} orbitals of Fe{sup 2+} is included, proving thus the orbital ordering. The EFG magnitude indicates that only some 60% of the orbital order occurring in the Sm-Ho variants is achieved in NdBaFe{sub 2}O{sub 5}. The consequent diminishing of the orbit contribution (of opposite sign) to the field B at the Fe{sup 2+} nucleus explains why B is larger than for the Sm-Ho variants. The decreased orbital ordering in NdBaFe{sub 2}O{sub 5} causes a corresponding decrease in charge ordering, which is achieved by decreasing both the amount of the charge-ordered iron states in the sample and their fractional valence separation as seen by the Moessbauer isomer shift. The charge ordering in NdBaFe{sub 2}O{sub 5+w} is more easily suppressed by the oxygen nonstoichiometry (w) than in the Sm-Ho variants. Also the valence mixing into Fe{sup 2.5+} is destabilized by the large size of Nd. The orientation of the EFG around this valence-mixed iron can only be accounted for when the valence-mixing electron is included in the electrostatic ligand field. This proves that the valence mixing occurs between the two iron atoms facing each other across the structural plane of the rare-earth atoms. -- Graphical Abstract: Moessbauer spectrum detects ordering of d{sub xz} orbitals of Fe{sup II}O{sub 5} via the electric-field gradient (EFG) of the orbital, which makes the main component of the total EFG parallel with the magnetic moment B. Display Omitted

  16. Structures and self-activating photoluminescent properties of Sr{sub 3-x}A{sub x}GaO{sub 4}F (A=Ba, Ca) materials

    SciTech Connect (OSTI)

    Green, Robert [Nanocenter and Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208 (United States)] [Nanocenter and Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208 (United States); Vogt, Thomas, E-mail: tvogt@mailbox.sc.edu [Nanocenter and Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208 (United States)] [Nanocenter and Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208 (United States)

    2012-10-15T23:59:59.000Z

    The synthesis, structures and photoluminescent properties of mixed oxyfluorides of the type Sr{sub 3-x}A{sub x}GaO{sub 4}F are compared to Sr{sub 3-x}A{sub x}AlO{sub 4}F (A=Ca, Ba) materials. In these compounds the F{sup -} and O{sup 2-} ions are ordered and located on two distinct crystallographic sites. When substituting Sr{sup 2+} by Ba{sup 2+} and Ca{sup 2+}, we find in Sr{sub 3-x}A{sub x}GaO{sub 4}F materials an ordering of the alkaline earth cations over the two crystallographic sites. The amount of Ba{sup 2+} ions that can be substituted into Sr{sub 3-x}A{sub x}GaO{sub 4}F is x{<=}1.2, which is slightly more than can be incorporated into the previously reported Al-analog Sr{sub 3-x}A{sub x}AlO{sub 4}F (x=1.0). Conversely, the amount of Ca{sup 2+} ions that can be substituted into Sr{sub 3-x}Ca{sub x}GaO{sub 4}F (x=0.3) is significantly less than in Sr{sub 3-x}Ca{sub x}AlO{sub 4}F (x=1.0). A post-synthesis reduction step causes these materials to exhibit self-activating broad band photoluminescence where the emitted colors vary with the amount of ions substituted into the host lattice. - Graphical abstract: TOC Statement The structures of the self-activating phosphors Sr{sub 3-x}A{sub x}MO{sub 4}F (A=Ba, Ca and M=Al, Ga) can be rationalized as alternating layers of bond compression and elongation, which impact the photoluminescence. Highlights: Black-Right-Pointing-Pointer Comparison of the structural changes in Sr{sub 3-x}A{sub x}AlO{sub 4}F and Sr{sub 3-x}A{sub x}GaO{sub 4}F (A=Ba, Ca) and its influence on the photoluminescence of these self-activating phosphors. Black-Right-Pointing-Pointer Analysis of the Global Instability Index of the Sr{sub 3-x}A{sub x}AlO{sub 4}F and Sr{sub 3-x}A{sub x}GaO{sub 4}F (A=Ba, Ca). Black-Right-Pointing-Pointer Comparison of the photoluminescence between the self-activating phosphors Sr{sub 3-x}A{sub x}AlO{sub 4}F and Sr{sub 3-x}A{sub x}GaO{sub 4}F (A=Ba, Ca).

  17. Study of optical response of high-{Tc} YBaCuO and BaKBiO thin films by terahertz spectroscopy

    SciTech Connect (OSTI)

    Liu, Y.; Gao, F.; Whitaker, J.F.; Uher, C. [Univ. of Michigan, Ann Arbor, MI (United States). Center for Ultrafast Optical Science; Platt, C.E. [Univ. of Illinois, Urbana, IL (United States)

    1994-12-31T23:59:59.000Z

    The authors investigate the superfluid and quasiparticle response for high temperature superconductor films of YBa{sub 2}Cu{sub 3}O{sub 7} and Ba{sub 0.6}K{sub 0.4}BiO{sub 3} under optical radiation. This is done through direct measurement of the complex conductivity of the illuminated superconductors using a coherent terahertz-bandwidth spectroscopy technique. The nature of the detected signals is discussed in the context of bolometric and nonbolometric response.

  18. Photorefractive properties of Ce- and Ca-doped Sr/sub 0. 6/Ba/sub 0. 4/Nb/sub 2/O/sub 6/

    SciTech Connect (OSTI)

    Rakuljic, G.A.; Sayano, K.; Agranat, A.; Yariv, A.; Neurgaonkar, R.R.

    1988-10-17T23:59:59.000Z

    We present the results of experimental study of the absorption coefficient, two-beam photorefractive coupling constant, and photorefractive response time of a doubly Ce- and Ca-doped Sr/sub 0.6/Ba/sub 0.4/Nb/sub 2/O/sub 6/. This crystal displays enhanced photorefractive response at near infrared wavelengths when compared to Ce-doped SBN:60. The temperature dependence of the coupling constant over the range from -30 to 40 /sup 0/C has also been studied.

  19. Infrared photorefractive passive phase conjugation with BaTiO/sub 3/: Demonstrations with GaAlAs and 1. 09-. mu. m Ar/sup +/ lasers

    SciTech Connect (OSTI)

    Cronin-Golomb, M.; Lau, K.Y.; Yariv, A.

    1985-09-15T23:59:59.000Z

    We report photorefractive passive phase conjugation of GaAlAs laser radiation at 815--865 nm and Ar/sup +/ laser radiation at 1090 nm. A ring passive phase conjugate mirror was used with BaTiO/sub 3/ as the real-time holographic gain medium. With GaAlAs lasers phase conjugate reflectivities of up to 16% uncorrected for Fresnel losses were recorded. Effects of the strong associated feedback to the laser and attempts at mode locking are described. At 1090 nm the reflectivity remains approximately the same, but with a significantly longer time constant.

  20. Nonlinear absorption and optical strength of BaF{sub 2} and Al{sub 2}O{sub 3} at the wavelength of 248 nm

    SciTech Connect (OSTI)

    Morozov, Nikolai V; Sergeev, P B [P.N. Lebedev Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation); Reiterov, V M [All-Russian Scientific Centre 'S.I. Vavilov State Optical Institute', St Petersburg (Russian Federation)

    1999-11-30T23:59:59.000Z

    An experimental investigation was made of the dependence of the transmission of BaF{sub 2} and Al{sub 2}O{sub 3} samples on the intensity of KrF-laser radiation ({lambda} = 248 nm) pulses of 85 ns duration. The two-photon absorption coefficients were found at {lambda} = 248 nm and their values for these two crystals were 0.5 {+-} 0.2 and 2 {+-} 1 cm Gw{sup -1}. The surface and bulk laser breakdown thresholds were determined for these samples. (nonlinear optical phenomena)

  1. Crystal Growth And Characterization of the Model High-Temperature Superconductor HgBa{sub 2}CuO{sub 4+{delta}}

    SciTech Connect (OSTI)

    Zhao, Xudong; Yu, Guichuan; Cho, Yong-Chan; Chabot-Couture, Guillaume; Barisic, Neven; Bourges, Philippe; Kaneko, Nobuhisa; Li, Yuan; Lu, Li; Motoyama, Eugene M.; Vajk,; Greven, Martin; /Stanford U., Appl. Phys. Dept. /SLAC, SSRL /Jilin U. /Stanford U., Phys. Dept. /Saclay /NIST, Wash., D.C.

    2007-03-16T23:59:59.000Z

    Since the discovery of high-transition-temperature (T{sub c}) superconductivity in La{sub 2-x}Ba{sub x}CuO{sub 4} in 1986, the study of the lamellar copper oxides has remained at the forefront of condensed matter physics. Apart from their unusually high values of T{sub c}, these materials also exhibit a variety of complex phenomena and phases. This rich behavior is a consequence of the lamellar crystal structures, formed of copper-oxygen sheets separated by charge reservoir layers, and of the strong electron-electron correlations in the copper-oxygen sheets. After two decades of intensive research, which has stimulated many valuable new insights into correlated electron systems in general, there remains a lack of consensus regarding the correct theory for high-T{sub c} superconductivity. The ultimate technological goal of room-temperature superconductivity might only be attained after the development of a deeper understanding of the mercury-based compounds HgBa{sub 2}Ca{sub n-1}Cu{sub n}OI{sub 2n+2+{delta}}, which currently exhibit the highest T{sub c}values. One very important issue in this regard is the role of electronic versus chemical and structural inhomogeneities in these materials, and the associated need to separate material-specific properties from those that are essential to superconductivity. Unfortunately, there has been remarkably little scientific work on the mercury-based compounds because sizable crystals have not been available; quantitative measurements of any kind would be invaluable benchmarks for testing the theories of high-T{sub c} superconductivity. The compounds HgBa{sub 2}Ca{sub n-1}Cu{sub n}OI{sub 2n+2+{delta}} can be viewed as model systems not only because of their record high-T{sub c} values, but also because of their high-symmetry crystal structures. Of particular interest is the simplest member of this materials family, HgBa{sub 2}CuO{sub 4+{delta}} (Hg1201), which possesses only one copper-oxygen sheet per unit cell (n = 1), as shown schematically in Figure 1a. The largest crystals obtained by previous growth methods do not exceed 1 mm{sup 3}, and hence are insufficient in size for detailed studies by many experimental techniques. Here we report a novel recipe for the growth of Hg1201 crystals as well as detailed sample characterization results, including initial inelastic magnetic neutron scattering data. We note that samples grown by the method described here have already enabled recent optical conductivity, inelastic X-ray scattering, and angle-resolved photoemission studies.

  2. The features of structural transformations in lanthanum manganites La{sub 1?x}A{sub x}MnO{sub 3+?} (A = Ca, Sr, Ba)

    SciTech Connect (OSTI)

    Sedykh, Vera D., E-mail: sedykh@issp.ac.ru [Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka (Russian Federation)

    2014-10-27T23:59:59.000Z

    In this work, the effect of the ionic radius and concentration of a doping element on the features of the structural transformations in polycrystalline lanthanum manganites, La{sub 1?x}A{sub x}MnO{sub 3+?} (A = Ca, Sr, Ba), has been studied by Mössbauer spectroscopy and X-ray diffraction analysis. For Mössbauer investigations, a small amount of {sup 57}Fe (2 at%) Mössbauer isotope was introduced into the samples. It follows from the analysis of the obtained data that both common features of the structural transformations and differences between them exist in lanthanum manganites depending on ionic radius and concentration of a doping element.

  3. Structural and magnetic properties of transition metal substituted BaFe{sub 2}As{sub 2} compounds studied by x-ray and neutron scattering

    SciTech Connect (OSTI)

    Kim, Min Gyu [Ames Laboratory

    2012-08-28T23:59:59.000Z

    The purpose of my dissertation is to understand the structural and magnetic properties of the newly discovered FeAs-based superconductors and the interconnection between superconductivity, antiferromagnetism, and structure. X-ray and neutron scattering techniques are powerful tools to directly observe the structure and magnetism in this system. I used both xray and neutron scattering techniques on di#11;erent transition substituted BaFe2As2 compounds in order to investigate the substitution dependence of structural and magnetic transitions and try to understand the connections between them.

  4. Neutron-Scattering Evidence for a Periodically Modulated Superconducting Phase in the Underdoped Cuprate La1.905Ba0.095CuO4

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Zhijun [Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Mater Physics and Materials Science Dept.; Stock, C. [National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research; Chi, Songxue [National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research; Kolesnikov, A. I. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Div.; Xu, Guangyong I. [Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Mater Physics and Materials Science Dept.; Gu, Genda [Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Mater Physics and Materials Science Dept.; Tranquada, J. M. [Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Mater Physics and Materials Science Dept.

    2014-10-01T23:59:59.000Z

    The role of antiferromagnetic spin correlations in high-temperature superconductors remains a matter of debate. We present inelastic neutron-scattering evidence that gapless spin fluctuations coexist with superconductivity in La1.905Ba0.095CuO4. Furthermore, we observe that both the low-energy magnetic spectral weight and the spin incommensurability are enhanced with the onset of superconducting correlations. We propose that the coexistence occurs through intertwining of spatial modulations of the pair wave function and the antiferromagnetic correlations. This proposal is also directly relevant to sufficiently underdoped La2-xSrxCuO4 and YBa2Cu3O6+x.

  5. Possible origin of the nonmonotonic doping dependence of the in-plane resistivity anisotropy of Ba(Fe1-xTx)?As? (T=Co, Ni and Cu)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kuo, Hsueh-Hui; Chu, Jiun-Haw; Riggs, Scott C.; Yu, Leo; McMahon, Peter L.; De Greve, Kristiaan; Yamamoto, Yoshihisa; Analytis, James G.; Fisher, Ian R.

    2011-08-01T23:59:59.000Z

    The in-plane resistivity anisotropy has been measured for detwinned single crystals of Ba(Fe1-xNix)?As? and Ba(Fe1-xCux)?As?. The data reveal a nonmonotonic doping dependence, similar to previous observations for Ba(Fe1-xCox)?As?. Magnetotransport measurements of the parent compound reveal a nonlinear Hall coefficient and a large linear term in the transverse magnetoresistance. Both effects are rapidly suppressed with chemical substitution over a similar compositional range as the onset of the large in-plane resistivity anisotropy. This suggests that the relatively small in-plane anisotropy of the parent compound in the spin-density wave state is due to the presence of an isotropic, high mobility pocket of the reconstructed Fermi surface. Progressive suppression of the contribution to the conductivity arising from this isotropic pocket with chemical substitution eventually reveals the underlying in-plane anisotropy associated with the remaining Fermi surface pockets

  6. abstract-BA.docx

    E-Print Network [OSTI]

    Angelo Camerlenghi

    Unconventional resources: Petrophysical (seismic) properties of oil and gas shales. J. M. Carcione. OGS, Trieste, Italy. Source rocks (self-resourcing shales),

  7. BA-PIRC

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureComments fromof Energy Automationj. Indirect Charges

  8. Structure and dielectric properties of Ba{sub 5}NdCu{sub 1.5}Nb{sub 8.5}O{sub 30??} tungsten bronze ceramics

    SciTech Connect (OSTI)

    Tan, Yan-Qing; Yu, Yuan [College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, 19(A) Yu Quan Road, Beijing 100049 (China); Hao, Yong-Mei, E-mail: ymhao@ucas.ac.cn [College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, 19(A) Yu Quan Road, Beijing 100049 (China); Dong, Su-Ying; Yang, Yi-Wen [Beijing National Day School, 66 Yu Quan Road, Beijing 100039 (China)

    2013-05-15T23:59:59.000Z

    Highlights: ? Tetragonal tungsten bronze ceramic Ba{sub 5}NdCu{sub 1.5}Nb{sub 8.5}O{sub 30??} was prepared. ? Titanium was replaced by copper in M{sub 5}RTi{sub 3}Nb{sub 7}O{sub 30} for the first time. ? Detailed structural information was retrieved by Rietveld refinement. ? An obvious relaxor-like dielectric behavior was observed in this ceramic, ion disorders in A1 and B sites contribute to this behavior. - Abstract: A new type of tungsten bronze ceramic Ba{sub 5}NdCu{sub 1.5}Nb{sub 8.5}O{sub 30??} has been prepared by a conventional solid-state reaction technique. Its structural, dielectric properties were investigated. Rietveld analysis shows that Ba{sub 5}NdCu{sub 1.5}Nb{sub 8.5}O{sub 30??} has a single-phase tetragonal (space group P4bm and lattice constants a = b = 12.4961(4) ?, c = 3.9426(8) ?, V = 615.66(4) ?{sup 3}) tungsten bronze structure. The occupations of sites A and B are quite interesting. A1 sites are fully disordered occupied by Ba ions and Nd ions and A2 sites for Ba ions only, while B-sites are equal for both Cu and Nb ions to occupy. This material exhibits an obvious relaxation behavior in the 213–573 K temperature range. The dielectric constants have been fitted by the modified Curie–Weiss law and all the estimated ? values are close to 2, confirming the typical relaxor ferroelectric behavior. The disorders of Ba{sup 2+} or Nd{sup 3+} in A1 sites and Nb{sup 5+}, Cu{sup 2+} in B sites induced by the oxygen vacancies may contribute to this dielectric behavior.

  9. Determination of anisotropic He2 up to 46 T in (BaO.55K0.45)Fe2As2 single crystals

    SciTech Connect (OSTI)

    Altarawneh, M M [Los Alamos National Laboratory; Collar, K N [Los Alamos National Laboratory; Mielke, C H [Los Alamos National Laboratory; Ni, N [IOWA STATE UNIV; Bud'ko, S [IOWA STATE UNIV.; Canfield, P [IOWA STATE UNIV

    2008-01-01T23:59:59.000Z

    The magnetoresistance and the radio frequency penetration depth was measured in the superconductor (Ba{sub 0.55}K{sub 0.45})Fe{sub 2}As{sub 2} under pulsed arid static magnetic fields extending to 46 tesla and down to 20 K. Using these data we are able to infer a H{sub c2}(T), H - T phase diagram, for applied fields parallel and perpendicular to the crystallographic c-axis. The upper critical field anisotropy is moderate, {approx} 3.5 close to T{sub c} , and decreases with the decrease of temperature, reaching {approx} 1.5 at T {approx} 20K. These data and analysis indicate that (i) (Ba{sub 0.55}K{sub 0.45})Fe{sub 2}As{sub 2} is well described by Ginzburg-Landau theory and at 20 K is very close to a dimensional crossover and (ii) H{sub c2}(T = 0) for this compound may easily approach fields of 75 tesla.

  10. Microstructural features and domain formation in (Ba,Sr){sub 2}TiSi{sub 2}O{sub 8} fresnoites

    SciTech Connect (OSTI)

    Wong, Chui Ling, E-mail: wong0233@e.ntu.edu.sg [School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Ferraris, Cristiano [Laboratoire de Mineralogie et Cosmchimie du Museum National d'Historie Naturelle, UMR-CNRS 7202, CP 52, 61 Rue Buffon, 75005 Paris (France); White, T.J. [School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Centre for Advanced Microscopy, The Australian National University, Canberra ACT 0200 (Australia)

    2011-07-15T23:59:59.000Z

    The formation and co-existence of crystallographically modulated and non-modulated regions in (Ba,Sr){sub 2}TiSi{sub 2}O{sub 8} fresnoites is reviewed, particularly the dependence on local composition. It is shown that perturbations of the average fresnoite structure, determined from appreciable single crystals, are in some cases better described as nanometric domain intergrowths where departures from ideal stoichiometry are characteristics of incommensuration, while modulation is absent from volumes that are less perturbed chemically. Evidence for this differentiation is obtained from selected area electron diffraction (SAED) patterns and high-resolution transmission electron microscopy (HRTEM) images. The domains are readily distinguished by their unique contrast in bright field electron micrographs. Fourier reconstructions of HRTEM images collected from areas with darker contrast show that modulation can change within relatively small volumes. Nearby areas with lighter contrast were found by SAED to be free of structural disorder and incommensurate reflections. - Graphical abstract: Fresnoite layers contain SiO{sub 4} and TiO{sub 5} polyhedra that undergo run rotation and tilting to create 3D, 4D and 5D structural modulations that can be directly observed by electron diffraction and high resolution imaging. Highlights: {yields}(Ba,Sr){sub 2}TiSi{sub 2}O{sub 8} fresnoites contain commensurate and incommensurate domains. > Departures in stoichiometry promote the formation of nanostructured domains. > Domains formation may provide a means for reducing strain in single crystals.

  11. Thermoelectric Properties of Au- Containing Type-I Clathrates Ba8AuxGa16-3xGe30+2x

    SciTech Connect (OSTI)

    Ye, Zuxin [Optimal Inc., Plymouth, Michigan 48170, USA] [Optimal Inc., Plymouth, Michigan 48170, USA; Cho, Jung Young [Optimal Inc., Plymouth, Michigan 48170, USA] [Optimal Inc., Plymouth, Michigan 48170, USA; Tessema, Misle M. [Optimal Inc., Plymouth, Michigan 48170, USA] [Optimal Inc., Plymouth, Michigan 48170, USA; Salvador, James R. [General Motors, Global Research and Development] [General Motors, Global Research and Development; Waldo, Richard A. [General Motors, Global Research and Development] [General Motors, Global Research and Development; Yang, Jihui [University of Washington] [University of Washington; Wang, Hsin [ORNL] [ORNL; Cai, Wei [ORNL] [ORNL; Kirkham, Melanie J [ORNL] [ORNL; Yang, Jiong [Chinese Academy of Sciences (CAS)] [Chinese Academy of Sciences (CAS); Zhang, Wenqing [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS)] [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS)

    2014-01-01T23:59:59.000Z

    Type I clathrates, with compositions based on Ba8Ga16Ge30, are a class of promising thermoelectric materials due to their intrinsically low thermal conductivity. It has been demonstrated previously that the thermoelectric performance can be improved by transition metal substitution of the framework atoms. In this study, the effects of Au substitution for Ga/Ge on thermal and electrical transport properties of type I clathrate compounds have been investigated. Polycrystalline samples with a large range of Au content have been synthesized using conventional solid state techniques with the actual compositions of resulting materials approximately following Zintl-Klemm rules. The charge carrier type changes from electrons (n) to holes (p) as the Au content increases. The Seebeck coefficient (S) and power factor (S2/ where is the electrical resistivity) were improved by Au substitution and the resulting overall thermoelectric properties were enhanced by Au substitution with a thermoelectric figure of merit ZT ~ 0.63 at temperature T = 740 K for the composition Ba8Au5.47Ge39.96. The results presented herein show that Au-containing type I clathrates are promising p-type thermoelectric materials for high temperature applications.

  12. Enhancement in the multiferroic properties of BiFeO{sub 3} by charge compensated aliovalent substitution of Ba and Nb

    SciTech Connect (OSTI)

    Makhdoom, A. R., E-mail: javedakhtar6@gmail.com, E-mail: a.r.makhdoom@gmail.com; Rafiq, M. A.; Hasan, M. M. [Department of Metallurgy and Materials Engineering, Pakistan Institute of Engineering and Applied Sciences Nilore, Islamabad (Pakistan)] [Department of Metallurgy and Materials Engineering, Pakistan Institute of Engineering and Applied Sciences Nilore, Islamabad (Pakistan); Akhtar, M. J., E-mail: javedakhtar6@gmail.com, E-mail: a.r.makhdoom@gmail.com; Siddique, M.; Iqbal, M. [Physics Division, PINSTECH, P.O. Nilore, Islamabad (Pakistan)] [Physics Division, PINSTECH, P.O. Nilore, Islamabad (Pakistan)

    2014-03-15T23:59:59.000Z

    Polycrystalline ceramics, Bi{sub 1-2x}Ba{sub 2x}Fe{sub 1-x}Nb{sub x}O{sub 3} (x = 0.00–0.15), were synthesized by solid state reactions method. X-ray diffraction data have revealed elimination of impurity phases and an increase in unit cell volume with Ba and Nb substitution. Diffraction peak splitting is found to be suppressed which indicates a decrease in octahedral distortion. The Mössbauer spectra demonstrate the suppression of spiral spin modulation of the magnetic moments resulting in enhanced ferromagnetism with increasing dopant concentration. The leakage current density of the sample with x = 0.10 is found to be greatly reduced up to six orders of magnitude as compared to the undoped sample. Ohmic conduction is found to be dominant mechanism in all the samples, however, undoped sample showed space charge limited conduction in high electric filed region, while the sample with x = 0.15 exhibited grain boundary limited conduction in low electric field region.

  13. Specific heat to Hc2: Evidence for nodes or deep minima in the superconducting gap of underdoped and overdoped Ba(Fe1–xCox)?As?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, J. S.; Faeth, B. D.; Wang, Y.; Hirschfeld, P. J.; Stewart, G. R.; Gofryk, K.; Ronning, F.; Sefat, A. S.; Choi, K. Y.; Kim, K. H.

    2012-07-01T23:59:59.000Z

    Low-temperature specific heat, C, in magnetic fields up to Hc2 is reported for underdoped Ba(Fe?.???Co?.???)?As? (Tc = 8 K) and for three overdoped samples Ba(Fe??xCox)?As? (x = 0.103, 0.13, and 0.15; Tc = 17.2, 16.5, and 11.7 K, respectively). Previous measurements of thermal conductivity (as a function of temperature and field) and penetration depth on comparable-composition samples gave some disagreement as to whether there was fully gapped/nodal behavior in the under-/overdoped materials, respectively. The present work shows that the measured behavior of the specific heat ? (?C/T as T ? 0, i.e., a measure of the electronic density of states at the Fermi energy) as a function of field approximately obeys ? ? H0.5±0.1, similar to the Volovik effect for nodal superconductors, for both the underdoped and the most overdoped Co samples. However, for the two overdoped compositions x = 0.103 and 0.13, the low-field (H ? 10 T) data show a Volovik-like behavior of ? ? H0.3–0.4, followed by an inflection point, followed at higher fields by ? ? H¹. We argue that, within the two-band theory of superconductivity, an inflection point may occur if the interband coupling is dominant.

  14. Systematics of the temperature-dependent interplane resistivity in Ba(Fe1-xMx)?As? (M=Co, Rh, Ni, and Pd)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tanatar, M. A.; Ni, N.; Thaler, A.; Bud’ko, S. L.; Canfield, P. C.; Prozorov, R.

    2011-07-01T23:59:59.000Z

    Temperature-dependent interplane resistivity ?c(T) was measured systematically as a function of transition-metal substitution in the iron-arsenide superconductors Ba(Fe1-xMx)?As?, M=Ni, Pd, Rh. The data are compared with the behavior found in Ba(Fe1-xCox)?As?, revealing resistive signatures of pseudogap. In all compounds we find resistivity crossover at a characteristic pseudogap temperature T* from nonmetallic to metallic temperature dependence on cooling. Suppression of T* proceeds very similarly in cases of Ni and Pd doping and much faster than in similar cases of Co and Rh doping. In cases of Co and Rh doping an additional minimum in the temperature-dependent ?c emerges for high dopings, when superconductivity is completely suppressed. These features are consistent with the existence of a charge gap covering part of the Fermi surface. The part of the Fermi surface affected by this gap is notably larger for Ni- and Pd-doped compositions than in Co- and Rh-doped compounds.

  15. Pressure effects on magnetic pair-breaking in Mn- and Eu-substituted BaFe{sub 2}As{sub 2}

    SciTech Connect (OSTI)

    Rosa, P. F. S., E-mail: ferrari@ifi.unicamp.br [Instituto de Física “Gleb Wataghin,” UNICAMP, Campinas-SP 13083-859 (Brazil); University of California, Irvine, California 92697-4574 (United States); Garitezi, T. M.; Adriano, C.; Urbano, R. R.; Pagliuso, P. G. [Instituto de Física “Gleb Wataghin,” UNICAMP, Campinas-SP 13083-859 (Brazil); Grant, T.; Fisk, Z. [University of California, Irvine, California 92697-4574 (United States); Fernandes, R. M. [School of Physics and Astronomy, University of Minnesota, Minneapolis, Minnesota 55455 (United States)

    2014-05-07T23:59:59.000Z

    We report a combined study of hydrostatic pressure (P ? 25 kbar) and chemical substitution on the magnetic pair-breaking effect in Eu- and Mn-substituted BaFe{sub 2}As{sub 2} single crystals. At ambient pressure, both substitutions suppress the superconducting (SC) transition temperature (T{sub c}) of BaFe{sub 2–x}Co{sub x}As{sub 2} samples slightly under the optimally doped region, indicating the presence of a pair-breaking effect. At low pressures, an increase of T{sub c} is observed for all studied compounds followed by an expected decrease at higher pressures. However, in the Eu dilute system, T{sub c} further increases at higher pressure along with a narrowing of the SC transition, suggesting that a pair-breaking mechanism reminiscent of the Eu Kondo single impurity regime is being suppressed by pressure. Furthermore, Electron Spin Resonance (ESR) measurements indicate the presence of Mn{sup 2+} and Eu{sup 2+} local moments and the microscopic parameters extracted from the ESR analysis reveal that the Abrikosov–Gor'kov expression for magnetic pair-breaking in a conventional sign-preserving superconducting state cannot describe the observed reduction of T{sub c}.

  16. Light scattering from ,,K0.5Na0.5...0.2,,Sr0.75Ba0.25...0.9Nb2O6 with the tungsten bronze structure: An analogy with relaxor ferroelectrics

    E-Print Network [OSTI]

    Light scattering from ,,K0.5Na0.5...0.2,,Sr0.75Ba0.25...0.9Nb2O6 with the tungsten bronze structure a complex single crystal from the tungsten­bronze family, K0.5Na0.5 0.2 Sr0.75Ba0.25 0.9Nb2O6 doped with Cu2 photorefractive material.1 KNSBN originates from the tungsten­bronze family of ferroelectrics. KNSBN has two close

  17. Giant magnetocaloric effect of Mn{sub 0.92}Ba{sub 0.08}As thin film grown on Al{sub 2}O{sub 3}(0001) substrate

    SciTech Connect (OSTI)

    Dang Duc Dung [Department of Physics, University of Ulsan, Ulsan 690-749 (Korea, Republic of); Department of General Physics, School of Engineering, Ha Noi University of Science and Technology, 1 Dai Co Viet road, Ha Noi (Viet Nam); Duong Anh Tuan; Duong Van Thiet; Shin, Yooleemi; Cho, Sunglae [Department of Physics, University of Ulsan, Ulsan 690-749 (Korea, Republic of)

    2012-04-01T23:59:59.000Z

    The epitaxial Mn{sub 0.92}Ba{sub 0.08}As thin film was grown on Al{sub 2}O{sub 3}(0001) substrate by molecular beam epitaxy. The Curie temperature (T{sub C}) around 350 K was enhanced with the addition of Ba, compared to that of bulk MnAs (T{sub C} {approx} 318 K). We have observed the linear resistivity versus the square of temperature and high negative magnetoresistance near Curie temperature. Moreover, the giant magnetocaloric effect was found with maximum magnetic entropy change, 65 J/kgK, around room temperature at 5 T.

  18. An apparatus to manipulate and identify individual Ba ions from bulk liquid Xe K. Twelker, S. Kravitz, M. Montero Dez, G. Gratta, W. Fairbank Jr., J. B. Albert, D. J. Auty, P. S. Barbeau, D.

    E-Print Network [OSTI]

    Piepke, Andreas G.

    . Kravitz, M. Montero Díez, G. Gratta, W. Fairbank Jr., J. B. Albert, D. J. Auty, P. S. Barbeau, D. Beck, C to manipulate and identify individual Ba ions from bulk liquid Xe K. Twelker,1 S. Kravitz,1 M. Montero Díez,1,a

  19. Magnetoelectric effect in La{sub 0.7}Sr{sub 0.3}MnO{sub 3}–BaTiO{sub 3} core–shell nanocomposite

    SciTech Connect (OSTI)

    Nayek, Chiranjib; Sahoo, Kishor Kumar [Department of Physics, Indian Institute of Technology Madras, Chennai 600036 (India); Murugavel, P., E-mail: muruga@iitm.ac.in [Department of Physics, Indian Institute of Technology Madras, Chennai 600036 (India)

    2013-03-15T23:59:59.000Z

    Highlights: ? The BaTiO{sub 3} in the core–shell structure undergoes large compressive strain. ? The LSMO in the core–shell structure exhibits enhanced magnetic moment. ? The anomaly in magnetization data indicates inherent magnetoelectric coupling. ? Overall the nanocomposite shows good magnetoelectric voltage coefficient value. - Abstract: We report the magnetoelectric properties of La{sub 0.7}Sr{sub 0.3}MnO{sub 3}–BaTiO{sub 3} core–shell nanostructure synthesized by sol–gel method. X-ray diffraction analysis suggests that the BaTiO{sub 3} undergoes large strain in the core–shell structure which can be attributed to lattice induced strain. Interestingly, the core–shell nanoparticle exhibits enhanced magnetization (143 emu/g) compared to the ferromagnetic La{sub 0.7}Sr{sub 0.3}MnO{sub 3} bare core (20 emu/g). The core–shell structure also exhibits inherent magnetoelectric coupling which is reflected as an anomaly at the ferroelectric transition in the magnetization measurement. The direct magnetoelectric measurement on La{sub 0.7}Sr{sub 0.3}MnO{sub 3}–BaTiO{sub 3} nanocomposite revealed the magnetoelectric voltage coefficient value as 54.5 mV/cm Oe at 1 kOe, which is a promising result compared to the other perovskite based nanocomposites.

  20. Origin of the superior conductivity of perovskite Ba(Sr)SnO3 Heng-Rui Liu, Ji-Hui Yang, H. J. Xiang, X. G. Gong, and Su-Huai Wei

    E-Print Network [OSTI]

    Gong, Xingao

    Origin of the superior conductivity of perovskite Ba(Sr)SnO3 Heng-Rui Liu, Ji-Hui Yang, H. J. Xiang(Sr)SnO3 Heng-Rui Liu,1 Ji-Hui Yang,1 H. J. Xiang,1 X. G. Gong,1 and Su-Huai Wei2 1 Key Laboratory

  1. How to Obtain Your DARS to Declare the BA Economics Major Once you've logged into the BU Brain and entered your B#, you will need to do the following

    E-Print Network [OSTI]

    Suzuki, Masatsugu

    How to Obtain Your DARS to Declare the BA Economics Major Once you've logged into the BU Brain DARS" The following screen prints will show you how to run the pre-declaration DARS for Economics the "Economics Pre-Declaration" DARS appears. Click "Economics Pre-Declaration" to open. Print the entire

  2. Transition from Three-Dimensional Anisotropic Spin Excitations to Two-Dimensional Spin Excitations by Electron Doping the FeAs-Based BaFe1:96Ni0:04As2 Superconductor

    E-Print Network [OSTI]

    Hu, Jiangping

    by Electron Doping the FeAs-Based BaFe1:96Ni0:04As2 Superconductor Leland W. Harriger,1 Astrid Schneidewind,2 arsenides is important because high-transition temperature (high-Tc) superconductivity arises from electron optimal superconductivity [4­6], the gapped spin wave excitations were replaced by a gapless continuum

  3. Two-Dimensional Superconducting Fluctuations in Stripe-Ordered La1:875Ba0:125CuO4 Q. Li, M. Hucker, G. D. Gu, A. M. Tsvelik, and J. M. Tranquada

    E-Print Network [OSTI]

    Two-Dimensional Superconducting Fluctuations in Stripe-Ordered La1:875Ba0:125CuO4 Q. Li, M. Hu of two-dimensional (2D) fluctuating superconductivity, which eventually reaches a 2D superconductingÿxBaxCuO4 frustrates three-dimensional superconducting phase order, but is fully compatible with 2D

  4. Stage en soins infirmiers : informations (anne acadmique 2012-2013 / 2013-2014) A l'issue du BA1, les lves mdecins qui ont russi en 1e

    E-Print Network [OSTI]

    Cerf, Nicolas

    Stage en soins infirmiers : informations (année académique 2012-2013 / 2013-2014) A l'issue du BA1 infirmiers durant l'été 2013 (2 semaines d'affilée en journée, 40 heures / semaine, jours fériés inclus). Les pratique de certains actes infirmiers de base. Sensibiliser au respect des règles de l

  5. Role of S??hayk??h Muh?ammad K??hiya?ba?ni? and the Democratic Movement of Azerbaijan in the socio-political history of Iran 1910-1920 

    E-Print Network [OSTI]

    Tabatabai Khatambakhsh, Mohammad-Taghi

    1984-01-01T23:59:59.000Z

    and foreign dynasties, we had to study a great deal about the lives of individual Kings; but hardly any space was allocated to the history of social and political movements in Iran. The names of patriots and political thinkers such as K?h?iya?ba?ni? were not...

  6. In situ pulsed laser deposition of superconducting Ba sub 1 minus x K sub x BiO sub 3 thin films

    SciTech Connect (OSTI)

    Moon, B.M.; Platt, C.E.; Schweinfurth, R.A.; Van Harlingen, D.J. (Science and Technology Center for Superconductivity Department of Physics, University of Illinois at Urbana-Champaign, Urbana, Illinois (USA))

    1991-10-07T23:59:59.000Z

    We have grown superconducting thin films of Ba{sub 1{minus}{ital x}}K{sub {ital x}}BiO{sub 3} by {ital in} {ital situ} pulsed laser deposition from a stoichiometric ({ital x}=0.4) target. The best films exhibit an onset transition temperature of 28 K and have zero resistance as high as 26 K. Films are single phase and highly oriented in the (100) or (110) direction on MgO, SrTiO{sub 3}, LaAlO{sub 3}, and Al{sub 2}O{sub 3} substrates. We have observed high-quality normal-insulator-superconductor and superconductor-insulator-superconductor quasiparticle tunneling characteristics with the films.

  7. Critical factor for epitaxial growth of cobalt-doped BaFe{sub 2}As{sub 2} films by pulsed laser deposition

    SciTech Connect (OSTI)

    Hiramatsu, Hidenori, E-mail: h-hirama@lucid.msl.titech.ac.jp; Kamiya, Toshio [Materials and Structures Laboratory, Tokyo Institute of Technology, Mailbox R3-1, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503 (Japan); Materials Research Center for Element Strategy, Tokyo Institute of Technology, Mailbox S2-16, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503 (Japan); Sato, Hikaru [Materials and Structures Laboratory, Tokyo Institute of Technology, Mailbox R3-1, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503 (Japan); Katase, Takayoshi [Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503 (Japan); Hosono, Hideo [Materials and Structures Laboratory, Tokyo Institute of Technology, Mailbox R3-1, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503 (Japan); Materials Research Center for Element Strategy, Tokyo Institute of Technology, Mailbox S2-16, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503 (Japan); Frontier Research Center, Tokyo Institute of Technology, Mailbox S2-13, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503 (Japan)

    2014-04-28T23:59:59.000Z

    We heteroepitaxially grew cobalt-doped BaFe{sub 2}As{sub 2} films on (La,Sr)(Al,Ta)O{sub 3} single-crystal substrates by pulsed laser deposition using four different wavelengths and investigated how the excitation wavelength and pulse energy affected growth. Using the tilting and twisting angles of X-ray diffraction rocking curves, we quantitatively analyzed the crystallinity of each film. We found that the optimal deposition rate, which could be tuned by pulse energy, was independent of laser wavelength. The high-quality film grown at the optimal pulse energy (i.e., the optimum deposition rate) exhibited high critical current density over 1 MA/cm{sup 2} irrespective of the laser wavelength.

  8. Moessbauer spectroscopy and magnetic properties of the three-dimensional cubic phase Ba{sub 6}Cu{sub 12}Fe{sub 13}S{sub 27}

    SciTech Connect (OSTI)

    Roig, A.; Molins, E.; Casan-Pastor, N.; Gomez-Romero, P. [CSIC, Bellaterra (Spain). Inst. de Ciencia de Materials de Barcelona] [CSIC, Bellaterra (Spain). Inst. de Ciencia de Materials de Barcelona; Mujica, C.; Llanos, J. [Univ. Catolica del Norte, Antofagasta (Chile)] [Univ. Catolica del Norte, Antofagasta (Chile)

    1998-09-01T23:59:59.000Z

    The complex sulfide Ba{sub 6}Cu{sub 12}Fe{sub 13}S{sub 27} constitutes a cubic phase that crystallizes in the djerfisherite structure type. It contains octahedral and tetrahedral sites occupied by transition metal ions and a central SBa{sub 6} octahedron. By means of Moessbauer spectroscopy, the oxidation state and distribution of iron atoms were determined. The results confirm the occupation of site 1b by Fe(III) and the presence of only Fe(II) ions in the tetrahedral sites (24m). The magnetic properties are consistent with the clustering of iron atoms and rule out the possibility of a spin-glass behavior.

  9. Epitaxial Ba{sub 2}IrO{sub 4} thin-films grown on SrTiO{sub 3} substrates by pulsed laser deposition

    SciTech Connect (OSTI)

    Nichols, J., E-mail: john.nichols@uky.edu; Korneta, O. B.; Terzic, J.; Cao, G.; Brill, J. W.; Seo, S. S. A. [Department of Physics and Astronomy, University of Kentucky, Lexington, Kentucky 40506 (United States)

    2014-03-24T23:59:59.000Z

    We have synthesized epitaxial Ba{sub 2}IrO{sub 4} (BIO) thin-films on SrTiO{sub 3} (001) substrates by pulsed laser deposition and studied their electronic structure by dc-transport and optical spectroscopic experiments. We have observed that BIO thin-films are insulating but close to the metal-insulator transition boundary with significantly smaller transport and optical gap energies than its sister compound, Sr{sub 2}IrO{sub 4}. Moreover, BIO thin-films have both an enhanced electronic bandwidth and electronic-correlation energy. Our results suggest that BIO thin-films have great potential for realizing the interesting physical properties predicted in layered iridates.

  10. Strain-induced orbital polarization and multiple phase transitions in Ba{sub 2}MnWO{sub 6} from first principles

    SciTech Connect (OSTI)

    Ju, Weiwei; Zhao, Bao; Yang, Zhongqin, E-mail: zyang@fudan.edu.cn [State Key Laboratory of Surface Physics and Key Laboratory for Computational Physical Sciences (MOE) and Department of Physics, Fudan University, Shanghai 200433 (China)] [State Key Laboratory of Surface Physics and Key Laboratory for Computational Physical Sciences (MOE) and Department of Physics, Fudan University, Shanghai 200433 (China)

    2013-11-28T23:59:59.000Z

    Electronic structures of double perovskite Ba{sub 2}MnWO{sub 6} with epitaxial strain are explored by using methods based on density functional theory. An in-plane compressive strain is found not only resulting in a semiconductor-metal transition (SMT), but also altering the magnetic structures, from different kinds of antiferromagnetic to ferromagnetic orders. Orbital polarization and different orbital occupancies of Mn d{sub z{sup 2}} and d{sub x{sup 2}?y{sup 2}} states, induced by the epitaxial strain, are employed to understand the SMT. The rich magnetic phase transitions are rationalized by a magnetic stabilization mechanism. Our results show that many technological applications may be carried out in the material with the control of epitaxial strain.

  11. Effect of electron irradiation on superconductivity in single crystals of Ba(Fe1-xRux)2As2 (x=0.24)

    SciTech Connect (OSTI)

    Prozorov, Ruslan [Ames Laboratory; Konczykowski, M [Laboratoire des Solides Irradies; Tanatar, Makariy A. [Ames Laboratory; Thaler, Alexander [Ames Laboratory; Budko, Serguei L [Ames Laboratory; Canfield, Paul C [Ames Laboratory; Mishra, V [Argonne National Laboratory; Hirschfeld, P J [University of Florida

    2014-11-01T23:59:59.000Z

    A single crystal of isovalently substituted Ba(Fe1?xRux)2As2 (x=0.24) is sequentially irradiated with 2.5 MeV electrons up to a maximum dose of 2.1×1019 e?/cm2. The electrical resistivity is measured in situ at T=22??K during the irradiation and ex situ as a function of temperature between subsequent irradiation runs. Upon irradiation, the superconducting transition temperature Tc decreases and the residual resistivity ?0 increases. We find that electron irradiation leads to the fastest suppression of Tc compared to other types of artificially introduced disorder, probably due to the strong short-range potential of the pointlike irradiation defects. A more detailed analysis within a multiband scenario with variable scattering potential strength shows that the observed Tc versus ?0 is fully compatible with s± pairing, in contrast to earlier claims that this model leads to a too rapid suppression of Tc with scattering.

  12. First-principle calculation and assignment for vibrational spectra of Ba(Mg{sub 1/3}Nb{sub 2/3})O{sub 3} microwave dielectric ceramic

    SciTech Connect (OSTI)

    Diao, Chuan-Ling [College of Physics and Electronics, Shandong Normal University, Jinan 250014 (China); State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Wang, Chun-Hai; Lu, Jing [State Key Laboratory for Artificial Microstructure and Mesoscopic Physics, School of Physics, Peking University, Beijing 100871 (China); Luo, Neng-Neng; Jing, Xi-Ping, E-mail: sf751106@sina.com.cn, E-mail: xpjing@pku.edu.cn [State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Qi, Ze-Ming; Shao, Tao; Wang, Yu-Yin [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Wang, Quan-Chao; Kuang, Xiao-Jun; Fang, Liang [MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004 (China); Shi, Feng, E-mail: sf751106@sina.com.cn, E-mail: xpjing@pku.edu.cn [College of Physics and Electronics, Shandong Normal University, Jinan 250014 (China)

    2014-03-21T23:59:59.000Z

    1:2 B-site cation ordered Ba(Mg{sub 1/3}Nb{sub 2/3})O{sub 3} ceramic was synthesized using conventional solid-state reaction at 1600?°C for 12?h. The structure parameters were obtained through Rietveld refinement of X-ray diffraction data. The Raman peak frequencies were obtained by Lorenz fitting on Raman spectrum. Four-parameter semiquantum model was used to fit the infrared (IR) reflectivity spectrum, and the fitted parameters were used to calculate the dielectric permittivity ? and dielectric loss tan?. A total of 9 active Raman and 16 active IR modes were obtained using first-principle calculations based on density functional theory with local density approximation. All of the vibrational modes were assigned and represented by linear combinations of the symmetry coordinates deduced using group theory analysis. The Raman mode with the highest frequency A{sub 1g}{sup (4)} (789?cm{sup ?1}) can be described as the breathing vibration of NbO{sub 6}. The IR modes E{sub u}{sup (1)} (149?cm{sup ?1}) and A{sub 2u}{sup (2)} (212?cm{sup ?1}), which can be described as the twisting vibrations of Ba–MgO{sub 6}/Ba–NbO{sub 6} on the a–b plane and the stretching vibrations of Ba–MgO{sub 6}/Ba–NbO{sub 6} along the c direction, respectively, are the dominant contributing modes to ? and tan?. The dielectric property parameters obtained using IR spectrum fittings, first-principal calculations, and microwave measurements were compared.

  13. The new model of chemical evolution of r-process elements based on the hierarchical galaxy formation. I. Ba and Eu

    SciTech Connect (OSTI)

    Komiya, Yutaka; Suda, Takuma [National Astronomical Observatory of Japan, Osawa, Mitaka, Tokyo 181-8588 (Japan); Yamada, Shimako [Department of Cosmoscience, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Fujimoto, Masayuki Y. [Nuclear reaction data center, Graduate School of Science, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan)

    2014-03-10T23:59:59.000Z

    We investigate the chemical enrichment of r-process elements in the early evolutionary stages of the Milky Way halo within the framework of hierarchical galaxy formation using a semi-analytic merger tree. In this paper, we focus on heavy r-process elements, Ba and Eu, of extremely metal-poor (EMP) stars and give constraints on their astronomical sites. Our models take into account changes of the surface abundances of EMP stars by the accretion of interstellar medium (ISM). We also consider metal-enrichment of intergalactic medium by galactic winds and the resultant pre-enrichment of proto-galaxies. The trend and scatter of the observed r-process abundances are well reproduced by our hierarchical model with ?10% of core-collapse supernovae in low-mass end (?10 M {sub ?}) as a dominant r-process source and the star formation efficiency of ?10{sup –10} yr{sup –1}. For neutron star mergers as an r-process source, their coalescence timescale has to be ?10{sup 7} yr, and the event rates ?100 times larger than currently observed in the Galaxy. We find that the accretion of ISM is a dominant source of r-process elements for stars with [Ba/H] < –3.5. In this model, a majority of stars at [Fe/H] < –3 are formed without r-process elements, but their surfaces are polluted by the ISM accretion. The pre-enrichment affects ?4% of proto-galaxies, and yet, is surpassed by the ISM accretion in the surface of EMP stars.

  14. Measurement of sin2 ??eff and Z-light quark couplings using the forward-backward charge asymmetry in pp? -> Z/gamma* -> e+e- events with L=5.0 fb-1 at ?s=1.96 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Abazov, V M [Dubna, JINR; Abbott, B [Oklahoma U.; Acharya, B S [Tata Inst.; Adams, M [Illinois U., Chicago; Adams, T [Florida State U.; Alexeev, G D [Dubna, JINR; Alkhazov, G [St. Petersburg, INP; Alton, A [Augustana Coll., Sioux Falls; Michigan U.; Alverson, G [Northeastern U.; Alves, G A [Rio de Janeiro, CBPF; Ancu, L S [NIKHEF, Amsterdam; Fermilab

    2011-07-26T23:59:59.000Z

    We measure the mass dependence of the forward-backward charge asymmetry in 157,553 pp? = Z/?* = e+e- interactions, corresponding to 5.0 fb-1 of integrated luminosity collected by the D0 experiment at the Fermilab Tevatron Collider at ?s = 1.96 TeV. The effective weak mixing angle (??eff) from this process involving predominantly the first generation of quarks is extracted as sin2 ??eff = 0.2309 ± 0.0008 (stat.) ± 0.0006 (syst.). We also present the most precise direct measurement of the vector and axial-vector couplings of u and d quarks to the Z boson.

  15. Symmetry determination on Pb-free piezoceramic 0.5Ba(Zr{sub 0.2}Ti{sub 0.8})O{sub 3}-0.5(Ba{sub 0.7}Ca{sub 0.3})TiO{sub 3} using convergent beam electron diffraction method

    SciTech Connect (OSTI)

    Gao, Jinghui, E-mail: gaojinghui@mail.xjtu.edu.cn; Zhong, Lisheng [Multi-Disciplinary Materials Research Center, State Key Lab of Electrical Insulation and Power Equipment and Frontier Institute of Science and Technology, Xi'an, 710049 (China); Zhang, Lixue; Xue, Dezhen [Multi-Disciplinary Materials Research Center, State Key Lab of Electrical Insulation and Power Equipment and Frontier Institute of Science and Technology, Xi'an, 710049 (China); State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049 (China); Kimoto, Takayoshi [Ferroic Physics Group, National Institute for Materials Science, Tsukuba, 305-0047, Ibaraki (Japan); Song, Minghui [Electron Microscopy Group, National Institute for Materials Science, Tsukuba, 305-0047, Ibaraki (Japan); Ren, Xiaobing [Multi-Disciplinary Materials Research Center, State Key Lab of Electrical Insulation and Power Equipment and Frontier Institute of Science and Technology, Xi'an, 710049 (China); State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049 (China); Ferroic Physics Group, National Institute for Materials Science, Tsukuba, 305-0047, Ibaraki (Japan)

    2014-02-07T23:59:59.000Z

    (1?x)(Ba(Zr{sub 0.2}Ti{sub 0.8})O{sub 3}-x(Ba{sub 0.7}Ca{sub 0.3})TiO{sub 3} (BZT-xBCT) Pb-free piezoceramic has been reported showing ultrahigh piezoelectric performance in its morphotropic phase boundary (MPB) region. However, the crystal structure characteristic for the MPB composition of BZT-xBCT is still under debate—between single orthorhombic phase and tetragonal + rhombohedral two phase mixture. In the present study, we perform the local symmetry determination on the MPB composition x = 0.5 using convergent beam electron diffraction analysis (CBED). Our CBED results from multiple zone axes suggest that there are two coexisting phases with the point group symmetries of 4?mm (tetragonal) and 3?m (rhombohedral) respectively, which agree with two phase mixture model. The strong piezoelectricity can thus be understood by considering the polarization rotation between tetragonal and rhombohedral phases by external field.

  16. Unification of the negative electrocaloric effect in Bi{sub 1/2}Na{sub 1/2}TiO{sub 3}-BaTiO{sub 3} solid solutions by Ba{sub 1/2}Sr{sub 1/2}TiO{sub 3} doping

    SciTech Connect (OSTI)

    Uddin, Sarir [Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); Materials Research Laboratory, Institute of Physics and Electronics, University of Peshawar, Peshawar 25120 (Pakistan); Zheng, Guang-Ping, E-mail: mmzheng@polyu.edu.hk [Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); School of Materials Science and Engineering, The University of Shanghai for Science and Technology, Shanghai (China); Iqbal, Yaseen [Materials Research Laboratory, Institute of Physics and Electronics, University of Peshawar, Peshawar 25120 (Pakistan); Ubic, Rick [Department of Materials Science and Engineering, Boise State University, Boise, Idaho 83725-2090 (United States); Yang, Junhe [School of Materials Science and Engineering, The University of Shanghai for Science and Technology, Shanghai (China)

    2013-12-07T23:59:59.000Z

    The microscopic mechanisms of the negative electrocaloric effect (ECE) of the single-phase (1?x)(0.94Bi{sub 1/2}Na{sub 1/2}TiO{sub 3}-0.06BaTiO{sub 3})-xBa{sub 1/2}Sr{sub 1/2}TiO{sub 3} (BNT-BT-BST) perovskite solid solutions fabricated via the sol-gel technique are explored in this study. Dielectric and mechanical relaxation analyses are employed to investigate the ferroelectric and structural transitions of the samples. The electrocaloric properties of the samples were measured by thermodynamics Maxwell relations. The difference between the depolarization temperature (T{sub d}) and the maximum dielectric constant temperature (T{sub m}) was found to decrease with increasing BST content. Doping with BST stabilized the ferroelectric phase along with unifying the EC temperature changes (?T) to only negative values. The origin of the uniform negative ECE of BNT-BT-BST is discussed.

  17. Development of ferroelectric correlations in the quantum paraelectric and antiferrodistortive regimes in Ba{sub x}Sr{sub 1-x}TiO{sub 3} (x ? 0.10)

    SciTech Connect (OSTI)

    Hassnain Jaffari, G.; Mehmood, Zahid; Iqbal, Asad M. [Department of Physics, Quaid-i-Azam University, Islamabad 45320 (Pakistan); Hasanain, S. K. [National Center for Physics, Quaid-I-Azam University Campus, Islamabad 45320 (Pakistan); Ismat Shah, S. [Department of Physics and Astronomy, University of Delaware, Newark, Delaware 19716 (United States)

    2014-08-28T23:59:59.000Z

    The dielectric response ?(T)? of Ba{sub x}Sr{sub 1-x}TiO{sub 3} (x???0.1) for compositions at and below the critical composition for the ferroelectric transition has been studied. With progressive Ba substitution, the growth of ferroelectric correlations and the weakening of the Antiferrodistortive (AFD) and the quantum paraelectric (QPE) effects have been studied by monitoring the changes in both the in and out of phase parts of the dielectric response. For the compositions close to pure SrTiO{sub 3} (x?=?0 and x?=?0.02), the temperature dependence exhibits a continuous rise in the in-phase part and no ferroelectric peak, consistent with the QPE behavior. With increasing Ba substitution, the low temperature behavior of the in phase part ?{sup ?} progressively changes from a continuous rise to exhibit a weak maximum and finally to a well developed cusp. For higher Ba concentrations, the low temperature peak (T???50K), which corresponds to ferroelectric correlations, becomes increasingly sharper until at the critical composition, x?=?0.10, the system shows a single well defined ferroelectric peak. However, the out of phase response of the x?=?0.1 composition exhibited a succession of three BaTiO{sub 3} type ferroelectric transitions. For x?0.04, the out of phase part shows evidence of an ordering around T???100K, which is the expected AFD ordering temperature. The deviations of the ?{sup ?}(T) data from the Curie-Weiss law have been analyzed within the frame work of two different theoretical models. It was determined that the dielectric behavior for lower concentrations of Ba (up to x???0.08) was explainable in terms of a model of non-interacting regions which are themselves homogeneously polarized and undergo a second order phase transition. For the phase boundary composition, i.e., x?=?0.1, on the other hand, the data are explainable in terms of the Sherrington and Kirkpatrick model which includes the effects of weak correlations between the polar regions characterized by a glassy order parameter.

  18. Measurement of Branching Fractions and CP-Violating Asymmetries in B0 to K0K0bar and B+ to K0barK+ Decays at the BaBar Experiment

    SciTech Connect (OSTI)

    Biesiada, Jedrzej

    2007-07-10T23:59:59.000Z

    Over the last few years, the B factories have established the Cabbibo-Kobayashi-Maskawa mechanism of CP violation in the Standard Model through the study of the decays of B mesons. The focus of Belle and BaBar has now expanded to the search for signatures of new physics beyond the Standard Model, particularly through examination of flavor-changing neutral-current transitions, which proceed through diagrams involving virtual loops. These decays are suppressed in the Standard Model, increasing sensitivity to new-physics effects but decreasing branching fractions. Exploiting large and growing datasets, BaBar and Belle have made many measurements in loop decays where a b quark transitions to an s quark, observing hints of possible deviations from Standard Model expectations in CP-violating measurements.

  19. Structural, electrical, and magnetic properties of Ba{sub 0.9}Ca{sub 0.1}Ti{sub 0.97}Fe{sub 0.03}O{sub 3} and the effect of oxygen vacancies

    SciTech Connect (OSTI)

    Chakraborty, Tanushree [Centre for Advanced Materials, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032 (India); Meneghini, Carlo [Dipartimento di Scienze, Universitá Roma Tre, Via della Vasca Navale, 84 I-00146 Roma (Italy); Aquilanti, Giuliana [Elettra-Sincrotrone Trieste S.C.p.A., s.s. 14, km 163.5 34149 Basovizza, Trieste (Italy); Ray, Sugata [Centre for Advanced Materials, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032 (India); Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032 (India)

    2013-12-14T23:59:59.000Z

    Detailed experimental studies have been carried out on a new possible dilute magnetic insulator Ba{sub 0.9}Ca{sub 0.1}Ti{sub 0.97}Fe{sub 0.03}O{sub 3??} and its oxygen deficient counterpart. Both the samples stabilize in overall tetragonal BaTiO{sub 3} structure at room temperature as indicated by x-ray diffraction and do exhibit room temperature magnetic order with obvious dependencies on ?. Apart from this, the as-grown sample also retains ferroelectricity at room temperature, which could potentially open up a possibility of achieving multifunctionality at room temperature. However, even though the magnetism is positively influenced by oxygen vacancies, the microscopic phase and ferroelectricity get adversely affected. Finally, using local structural probes, existence of diffused phases has been found, which successfully explains all the observed physical properties.

  20. Data:21adf8ba-6c27-4de2-be0d-eb3b9e4d94e9 | Open Energy Information

    Open Energy Info (EERE)

    http%3A%2F%2Fpsc.wi.gov%2Fapps40%2Ftariffs%2Fviewfile.aspx%3Ftype%3Delectric%26id%3D5940&eibLmEU9-kDIqSyATb34D4BA&usgAFQjCNHQszMM37DZ2RABeDOYr8qMUj5yA Source Parent: Comments...

  1. Magnetic and dielectric behavior of the spin-chain compound Er{sub 2}BaNiO{sub 5} well below its Néel temperature

    SciTech Connect (OSTI)

    Basu, Tathamay; Singh, Kiran; Sampathkumaran, E. V. [Tata Institute of Fundamental Research, Homi Bhabha Road, Colaba, Mumbai 400005 (India); Mohapatra, N. [School of Basic Sciences, Indian Institute of Technology Bhubaneshwar, Bhubaneshwar 751013 (India)

    2014-09-21T23:59:59.000Z

    We have recently reported that the Haldane spin-chain system, Er{sub 2}BaNiO{sub 5}, undergoing antiferromagnetic order below (T{sub N}=) 32?K, is characterized by the onset of ferroelectricity near 60?K due to magnetoelectric coupling induced by short-range magnetic-order within spin-chains. We have carried out additional magnetic and dielectric studies to understand the properties well below T{sub N}. We emphasize here on the following: (i) A strong frequency dependent behaviors of ac magnetic susceptibility and complex dielectric properties have been observed at much lower temperatures (<8?K), that is, “reentrant multiglass-like” phenomenon, naturally suggesting the existence of an additional transition well below T{sub N}. (ii) “Magnetoelectric phase coexistence” is observed at very low temperature (e.g., T?=?2?K), where the high-field magnetoelectric phase is partially arrested on returning to zero magnetic field after a cycling through metamagnetic transition.

  2. Structural characterisation of BaTiO{sub 3} thin films deposited on SrRuO{sub 3}/YSZ buffered silicon substrates and silicon microcantilevers

    SciTech Connect (OSTI)

    Colder, H.; Jorel, C., E-mail: corentin.jorel@unicaen.fr; Méchin, L. [GREYC, UMR 6072, CNRS, ENSICAEN, UCBN, 6 bd du Maréchal Juin, 14050 Caen Cedex (France); Domengès, B. [LAMIPS, CRISMAT-NXP Semiconductors-Presto Engineering laboratory, CNRS-UMR 6508, ENSICAEN, UCBN, 2 rue de la Girafe, 14 000 Caen (France); Marie, P.; Boisserie, M. [CIMAP, UMR 6252, CNRS, ENSICAEN, UCBN, CEA, 6 bd du Maréchal Juin, 14050 Caen Cedex (France); Guillon, S.; Nicu, L. [LAAS, CNRS, Univ de Toulouse, 7 avenue du Colonel Roche, 31400 Toulouse (France); Galdi, A. [GREYC, UMR 6072, CNRS, ENSICAEN, UCBN, 6 bd du Maréchal Juin, 14050 Caen Cedex (France); Department of Industrial Engineering, CNR-SPIN Salerno, Università di Salerno, 84084 Fisciano, Salerno (Italy)

    2014-02-07T23:59:59.000Z

    We report on the progress towards an all epitaxial oxide layer technology on silicon substrates for epitaxial piezoelectric microelectromechanical systems. (101)-oriented epitaxial tetragonal BaTiO{sub 3} (BTO) thin films were deposited at two different oxygen pressures, 5.10{sup ?2} mbar and 5.10{sup ?3} mbar, on SrRuO{sub 3}/Yttria-stabilized zirconia (YSZ) buffered silicon substrates by pulsed laser deposition. The YSZ layer full (001) orientation allowed the further growth of a fully (110)-oriented conductive SrRuO{sub 3} electrode as shown by X-ray diffraction. The tetragonal structure of the BTO films, which is a prerequisite for the piezoelectric effect, was identified by Raman spectroscopy. In the BTO film deposited at 5.10{sup ?2} mbar strain was mostly localized inside the BTO grains whereas at 5.10{sup ?3} mbar, it was localized at the grain boundaries. The BTO/SRO/YSZ layers were finally deposited on Si microcantilevers at an O{sub 2} pressure of 5.10{sup ?3} mbar. The strain level was low enough to evaluate the BTO Young modulus. Transmission electron microscopy (TEM) was used to investigate the epitaxial quality of the layers and their epitaxial relationship on plain silicon wafers as well as on released microcantilevers, thanks to Focused-Ion-Beam TEM lamella preparation.

  3. Electro-caloric effect in lead-free Sn doped BaTiO{sub 3} ceramics at room temperature and low applied fields

    SciTech Connect (OSTI)

    Upadhyay, Sanjay Kumar; Reddy, V. Raghavendra, E-mail: varimalla@yahoo.com, E-mail: vrreddy@csr.res.in; Bag, Pallab; Rawat, R. [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452001 (India); Gupta, S. M. [Ceramic Laboratory, LMDDD, RRCAT, Indore 452013 (India); Gupta, Ajay [Amity Center for Spintronic Materials, Amity University, Noida 201303 (India)

    2014-09-15T23:59:59.000Z

    Structural, dielectric, ferroelectric (FE), {sup 119}Sn Mössbauer, and specific heat measurements of polycrystalline BaTi{sub 1–x}Sn{sub x}O{sub 3} (x?=?0% to 15%) ceramics are reported. Phase purity and homogeneous phase formation with Sn doping is confirmed from x-ray diffraction and {sup 119}Sn Mössbauer measurements. With Sn doping, the microstructure is found to change significantly. Better ferroelectric properties at room temperature, i.e., increased remnant polarization (38% more) and very low field switchability (225% less) are observed for x?=?5% sample as compared to other samples and the results are explained in terms of grain size effects. With Sn doping, merging of all the phase transitions into a single one is observed for x???10% and for x?=?5%, the tetragonal to orthorhombic transition temperature is found close to room temperature. As a consequence better electro-caloric effects are observed for x?=?5% sample and therefore is expected to satisfy the requirements for non-toxic, low energy (field) and room temperature based applications.

  4. Direct submillimeter absorptivity measurements on epitaxial Ba{sub 1-x}K{sub x}BiO{sub 3}films at 2K

    SciTech Connect (OSTI)

    Miller, D.; Richards, P.L. [Lawrence Berkeley Lab., CA (United States); Nicol, E.J. [California Univ., Santa Barbara, CA (United States); Hellman, E.S.; Hartford, E.H. Jr. [AT and T Bell Labs., Murray Hill, NJ (United States); Platt, C.E.; Schweinfurth, R.A.; VanHarlingen, D.J. [Illinois Univ., Urbana, IL (United States); Amano, J. [Hewlett-Packard Lab., Palo Alto, CA (United States)

    1993-04-01T23:59:59.000Z

    We have used a bolometric technique to obtain accurate low temperature loss data for epitaxial thin films of Ba{sub 0.6}K{sub 0.4}BiO{sub 3} from 30 to 700 cm{sup {minus}1}. These films were grown on MgO and SrTiO{sub 3} substrates by MBE, off-axis sputtering and laser deposition techniques. All films show a strong absorption onset near the BCS tunneling gap of 3.5k{sub B}T{sub c}. We have analyzed these data using a Kramers-Kronig transformation and have corrected for finite film thickness effects. Results indicate that the absorption onset is consistent with a superconducting energy gap. Comparison is made with predictions based on strong coupling Eliashberg theory using {alpha}{sup 2}F({omega}) spectra obtained from the literature. While we are able to fit the overall measured absorptivity, we are unable to fit the structure observed in our data.

  5. Hall, Seebeck, and Nernst Coefficients of Underdoped HgBa2CuO4+?: Fermi-Surface Reconstruction in an Archetypal Cuprate Superconductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Doiron-Leyraud, Nicolas; Lepault, S.; Cyr-Choinière, O.; Vignolle, B.; Grissonnanche, G.; Laliberté, F.; Chang, J.; Bariši?, N.; Chan, M. K.; Ji, L.; Zhao, X.; Li, Y.; Greven, M.; Proust, C.; Taillefer, Louis

    2013-06-01T23:59:59.000Z

    Charge-density-wave order has been observed in cuprate superconductors whose crystal structure breaks the square symmetry of the CuO2 planes, such as orthorhombic YBa2Cu3Oy (YBCO), but not so far in cuprates that preserve that symmetry, such as tetragonal HgBa2CuO4+? (Hg1201). We have measured the Hall (RH), Seebeck (S), and Nernst (?) coefficients of underdoped Hg1201 in magnetic fields large enough to suppress superconductivity. The high-field RH(T) and S(T) are found to drop with decreasing temperature and become negative, as also observed in YBCO at comparable doping. In YBCO, the negative RH and S are signatures of a small electron pocket caused by Fermi-surface reconstruction, attributed to charge-density-wave modulations observed in the same range of doping and temperature. We deduce that a similar Fermi-surface reconstruction takes place in Hg1201, evidence that density-wave order exists in this material. A striking similarity is also found in the normal-state Nernst coefficient ?(T), further supporting this interpretation. Given the model nature of Hg1201, Fermi-surface reconstruction appears to be common to all hole-doped cuprates, suggesting that density-wave order is a fundamental property of these materials.

  6. Tri-axial magnetic anisotropies in RE{sub 2}Ba{sub 4}Cu{sub 7}O{sub 15?y} superconductors

    SciTech Connect (OSTI)

    Horii, Shigeru, E-mail: horii.shigeru.7e@kyoto-u.ac.jp; Doi, Toshiya [Graduate School of Energy Science, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501 (Japan); Okuhira, Shota; Yamaki, Momoko [Department of Environmental Systems Engineering, Kochi University of Technology, Tosa-Yamada, Kami-shi, Kochi 782-8502 (Japan); Kishio, Kohji; Shimoyama, Jun-ichi [Department of Applied Chemistry, University of Tokyo, Bunkyo-ku, Tokyo 113-8656 (Japan)

    2014-03-21T23:59:59.000Z

    We report a novel quantification method of tri-axial magnetic anisotropy in orthorhombic substances containing rare earth (RE) ions using tri-axial magnetic alignment and tri-axial magnetic anisotropies depending on the type of RE in RE-based cuprate superconductors. From the changes in the axes for magnetization in magnetically aligned powders of (RE?{sub 1?x}RE?{sub x}){sub 2}Ba{sub 4}Cu{sub 7}O{sub y} [(RE?,RE?)247] containing RE ions with different single-ion magnetic anisotropies, the ratios of three-dimensional magnetic anisotropies between RE?247 and RE?247 could be determined. The results in (Y,Er)247, (Dy,Er)247, (Ho,Er)247, and (Y,Eu)247 systems suggest that magnetic anisotropies largely depended on the type of RE? (or RE?), even in the heavy RE ions with higher magnetic anisotropies. An appropriate choice of RE ions in RE-based cuprate superconductors enables the reduction of the required magnetic field for the production of their bulks and thick films based on the tri-axial magnetic alignment technique using modulated rotation magnetic fields.

  7. Spin dynamics, short range order and spin freezing in Y0.5Ca0.5BaCo4O7

    SciTech Connect (OSTI)

    Stewart, John Ross [ISIS Facility, Rutherford Appleton Laboratory; Ehlers, Georg [ORNL; Fouquet, Peter [Institut Laue-Langevin (ILL); Mutka, Hannu [Institut Laue-Langevin (ILL); Payen, Christophe [Institut des Materiaux Jean Rouxel (IMN), Universite de Nantes-CNRS; Lortz, Rolf [University of Geneva

    2011-01-01T23:59:59.000Z

    Y0.5Ca0.5BaCo4O7 was recently introduced as a possible candidate for capturing some of the predicted classical spin kagome ground-state features. Stimulated by this conjecture, we have taken up a more complete study of the spin correlations in this compound with neutron scattering methods on a powder sample characterized with high-resolution neutron diffraction and the temperature dependence of magnetic susceptibility and specific heat. We have found that the frustrated near-neighbor magnetic correlations involve not only the kagome planes but concern the full Co sublattice, as evidenced by the analysis of the wave-vector dependence of the short-range order. We conclude from our results that the magnetic moments are located on the Co sublattice as a whole and that correlations extend beyond the two-dimensional kagome planes. We identify intriguing dynamical properties, observing high-frequency fluctuations with a Lorentzian linewidth G?20 meV at ambient temperature. On cooling a low-frequency ({approx}1 meV) dynamical component develops alongside the high-frequency fluctuations, which eventually becomes static at temperatures below T {approx} 50 K. The high-frequency response with an overall linewidth of {approx}10 meV prevails at T?2 K, coincident with a fully elastic short-range-ordered contribution.

  8. Importance of the Fermi-surface topology to the superconducting state of the electron-doped pnictide Ba(Fe1-xCox)?As?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Chang; Palczewski, A. D.; Dhaka, R. S.; Kondo, Takeshi; Fernandes, R. M.; Mun, E. D.; Hodovanets, H.; Thaler, A. N.; Schmalian, J.; Bud’ko, S. L.; Canfield, P. C.; Kaminski, A.

    2011-07-01T23:59:59.000Z

    We used angle-resolved photoemission spectroscopy and thermoelectric power to study the poorly explored, highly overdoped side of the phase diagram of Ba(Fe1-xCox)?As? high-temperature superconductor. Our data demonstrate that several Lifshitz transitions—topological changes of the Fermi surface—occur for large x. The central hole barrel changes to ellipsoids that are centered at Z at x~0.11 and subsequently disappear around x~0.2; changes in thermoelectric power occur at similar x values. Tc decreases and goes to zero around x~0.15—between the two Lifshitz transitions. Beyond x=0.2 the central pocket becomes electron-like and superconductivity does not exist. Our observations reveal the importance of the underlying Fermiology in electron-doped iron arsenides. We speculate that a likely necessary condition for superconductivity in these materials is the presence of the central hole pockets rather than nesting between central and corner pockets.

  9. Probing the connections between superconductivity, stripe order, and structure in La?.???Ba?.???Cu1-yZnyO?

    SciTech Connect (OSTI)

    Wen, Jinsheng; Xu, Zhijun; Xu, Guangyong; Jie, Qing; Hücker, M.; Zheludev, A.; Tian, Wei; Winn, B. L.; Zarestky, J. L.; Singh, D. K.; Hong, Tao; Li, Qiang; Gu, Genda; Tranquada, J. M.

    2012-04-01T23:59:59.000Z

    The superconducting system La2-xBaxCuO? is known to show a minimum in the transition temperature Tc at x=1/8 where maximal stripe order is pinned by the anisotropy within the CuO? planes that occurs in the low-temperature-tetragonal (LTT) crystal structure. For x=0.095, where Tc reaches its maximum value of 32 K, there is a roughly coincident structural transition to a phase that is very close to LTT. Here, we present a neutron scattering study of the structural transition, and demonstrate how features of it correlate with anomalies in the magnetic susceptibility, electrical resistivity, thermal conductivity, and thermoelectric power. We also present measurements on a crystal with 1% Zn substituted for Cu, which reduces Tc to 17 K, enhances the spin stripe order, but has much less effect on the structural transition. We make the case that the structural transition correlates with a reduction of the Josephson coupling between the CuO? layers, which interrupts the growth of the superconducting order. We also discuss evidence for two-dimensional superconducting fluctuations in the normal state, analyze the effective magnetic moment per Zn impurity, and consider the significance of the anomalous thermopower often reported in the stripe-ordered phase.

  10. Ion beam-assisted pulsed laser deposition of (Ba,Sr)(Ti,Zr)O{sub 3} films on Pt-Si substrates

    SciTech Connect (OSTI)

    Sakai, Joe; Vayunandana Reddy, Y. K.; Autret-Lambert, Cecile; Lagrange, Jean-Francois; Motret, Olivier; Roger, Sylvain; Wolfman, Jerome [Laboratoire LEMA, UMR 6157 CNRS-CEA, Universite Francois Rabelais de Tours, Parc de Grandmont, 37200 Tours (France)

    2011-05-15T23:59:59.000Z

    Ion beam-assisted pulsed laser deposition with an Ar-oxygen ion mixture was used to prepare Ba{sub 0.6}Sr{sub 0.4}Ti{sub 0.7}Zr{sub 0.3}O{sub 3} (BSTZ) thin films on Pt-coated Si substrates. The ion beam with an anode voltage of 600 V was effective to reduce the thermal budget, i.e., to achieve similar crystallinity with approximately 100 deg. C lower deposition temperature compared to the cases without ionization. It was revealed that the dielectric properties (relative dielectric constant {epsilon}{sub r} and its electric field tunability), out-of-plane lattice parameter of (001)-oriented grains (a{sub 001}), and the existence of (110)-oriented grains are correlated with one another. Elongation of a{sub 001} was suppressed, resulting in large {epsilon}{sub r} values comparable with that of a ceramic bulk of the same composition, in the BSTZ films that contain (110)-oriented grains. Less volume of amorphous BSTZ region is supposed to be playing an important role for the bulklike properties of these BSTZ films.

  11. M o d e lin g B e d -L o a d T r a n sp o r t o f C o a r se S e d im e n ts in th e G r e a t B a y E stu a r y , N H , U sin g a 2 -D

    E-Print Network [OSTI]

    M o d e lin g B e d -L o a d T r a n sp o r t o f C o a r se S e d im e n ts in th e G r e a t B a y E stu a r y , N H , U sin g a 2 -D K in e m a tic F lo o d in g -D e w a te r in g M o d e l A . B ilg ili1 , M .R . S w ift2 , D .R . L y n c h 1 a n d J.T .C . Ip 1 1 D a rtm o u th C o lle g e H a n

  12. M o d e lin g B e d -L o a d T r a n sp o r t o f C o a r se S e d im e n ts in th e G r e a t B a y E stu a r y , N H , U sin g

    E-Print Network [OSTI]

    M o d e lin g B e d -L o a d T r a n sp o r t o f C o a r se S e d im e n ts in th e G r e a t B a y E stu a r y , N H , U sin g a 2 -D K in e m a tic M o d e l A . B ilg ili1 , M .R . S w ift2 , D .R . L y n c h 1 a n d J.T .C . Ip 1 1 D a rtm o u th C o lle g e H a n o v e r, N H 0 3 7 5 5 , U .S

  13. Study of CP Symmetry Violation in the Charmonium-K*(892) Channel By a Complete Time Dependent Angular Analysis (BaBar Experiment)

    SciTech Connect (OSTI)

    T'Jampens, Stephane; /Orsay

    2006-09-18T23:59:59.000Z

    This thesis presents the full-angular time-dependent analysis of the vector-vector channel B{sub d}{sup 0} {yields} J/{psi}(K{sub S}{sup 0}{pi}{sup 0})*{sup 0}. After a review of the CP violation in the B meson system, the phenomenology of the charmonium-K*(892) channels is exposed. The method for the measurement of the transversity amplitudes of the B {yields} J/{psi}K*(892), based on a pseudo-likelihood method, is then exposed. The results from a 81.9 fb{sup -1} of collected data by the BABAR detector at the {Upsilon}(4S) resonance peak are |A{sub 0}|{sup 2} = 0.565 {+-} 0.011 {+-} 0.004, |A{sub {parallel}}|{sup 2} = 0.206 {+-} 0.016 {+-} 0.007, |A{sub {perpendicular}}|{sup 2} = 0.228 {+-} 0.016 {+-} 0.007, {delta}{sub {parallel}} = -2.766 {+-} 0.105 {+-} 0.040 and {delta}{sub {perpendicular}} = 2.935 {+-} 0.067 {+-} 0.040. Note that ({delta}{sub {parallel}}, {delta}{sub {perpendicular}}) {yields} (-{delta}{sub {parallel}}, {pi} - {delta}{sub {perpendicular}}) is also a solution. The strong phases {delta}{sub {parallel}} and {delta}{sub {perpendicular}} are at {approx}> 3{sigma} from {+-}{pi}, signing the presence of final state interactions and the breakdown of the factorization hypothesis. The forward-backward analysis of the K{pi} mass spectrum revealed the presence of a coherent S-wave interfering with the K*(892). It is the first evidence of this wave in the K{pi} system coming from a B meson. The particularity of the B{sub d}{sup 0} {yields} J/{psi}(K{sub S}{sup 0}{pi}{sup 0})*{sup 0} channel is to have a time-dependent but also an angular distribution which allows to measure sin 2{beta} but also cos2{beta}. The results from an unbinned maximum likelihood fit are sin 2{beta} = -0.10 {+-} 0.57 {+-} 0.14 and cos 2{beta} = 3.32{sub -0.96}{sup +0.76} {+-} 0.27 with the transversity amplitudes fixed to the values given above. The other solution for the strong phases flips the sign of cos 2{beta}. Theoretical considerations based on the s-quark helicity conservation favor the choice of the strong phases given above, leading to a positive sign for cos 2{beta}. The sign of cos 2{beta} is the one predicted by the Standard Model.

  14. Interactions of Ba{sub 2}YCu{sub 3}O{sub 6+y} with the Gd{sub 3}NbO{sub 7} buffer layer in coated conductors

    SciTech Connect (OSTI)

    Wong-Ng, W., E-mail: Winnie.wong-ng@nist.go [Ceramics Division, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Yang, Z. [Ceramics Division, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Kaduk, J.A. [INEOS Technology, Naperville, IL 60566-7011 (United States); Cook, L.P. [Ceramics Division, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Paranthaman, M. [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States)

    2010-03-15T23:59:59.000Z

    A systematic study of the chemical interaction of Ba{sub 2}YCu{sub 3}O{sub 6+y} and Gd{sub 3}NbO{sub 7} was conducted under two processing conditions: purified air (21% p{sub o{sub 2}}), and 100 Pa p{sub o{sub 2}} (0.1% p{sub o{sub 2}}). Phases present along the pseudo-binary join Ba{sub 2}YCu{sub 3}O{sub 6z} and Gd{sub 3}NbO{sub 7} were found to be in two five-phase volumes within the BaO-1/2 Y{sub 2}O{sub 3}-1/2 Gd{sub 2}O{sub 3}-Nb{sub 2}O{sub 5}-CuO{sub y} system. Three common phases that are present in all samples are (Y,Gd){sub 2}Cu{sub 2}O{sub 5}, Ba(Y,Gd){sub 2}CuO{sub 5} and Cu{sub 2}O or CuO (depending on the processing conditions). The assemblies of phases can be categorized in three regions, with Ba{sub 2}YCu{sub 3}O{sub 6+y}: Gd{sub 3}NbO{sub 7} ratios of (I)<5.5:4.5; (II)=5.5:4.5; and (III)>5.5:4.5. The lowest melting temperature of the system was determined to be {approx}938 deg. C in air, and 850 deg. C at 100 Pa p{sub o{sub 2}}. Structure determinations of two selected phases, Ba{sub 2}(Gd{sub x}Y{sub 1-x})NbO{sub 6} (Fm3-barm, No. 225), and (Gd{sub x}Y{sub 3-x})NbO{sub 7} (C222{sub 1}, No. 20 and Ccmm, No. 63), were completed using the X-ray Rietveld refinement technique. Reference X-ray powder diffraction patterns for selected phases of Ba{sub 2}(Gd{sub x}Y{sub 1-x})NbO{sub 6} (x=0.2, 0.4, 0.6, and 0.8) and (Gd{sub x}Y{sub 3-x})NbO{sub 7} (x=0.6, 1.2, 1.8, 2.4 and 3) have been prepared for inclusion in the Powder Diffraction File (PDF). - Graphical abstract: Crystal structure for (Gd{sub x}Y{sub 3-x})NbO{sub 7} showing the partial layered feature. The alternate stacking of distorted NbO{sub 6} octahedra and (Gd,Y)O{sub 7} polyhedra are illustrated. The (Gd,Y)O{sub 8} polyhedra are omitted for clarity.

  15. Formation of solar cells based on Ba{sub 0.5}Sr{sub 0.5}TiO{sub 3} (BST) ferroelectric thick film

    SciTech Connect (OSTI)

    Irzaman,, E-mail: irzaman@yahoo.com; Syafutra, H., E-mail: irzaman@yahoo.com; Arif, A., E-mail: irzaman@yahoo.com; Alatas, H., E-mail: irzaman@yahoo.com [Department of Physics, FMIPA Bogor Agricultural Unversity, Campus Darmaga Gedung Wing S Bogor (Indonesia); Hilaluddin, M. N.; Kurniawan, A.; Iskandar, J.; Dahrul, M.; Ismangil, A.; Yosman, D.; Aminullah [Department of Biophysics, FMIPA Bogor Agricultural Unversity (Indonesia); Prasetyo, L. B. [Department of Forest Resources Conservation, FAHUTAN, Bogor Agricultural Unversity, Campus Darmaga Bogor (Indonesia); Yusuf, A.; Kadri, T. M. [LAPAN Rancabungur Ciampea Bogor (Indonesia)

    2014-02-24T23:59:59.000Z

    Growth of Ba{sub 0.5}Sr{sub 0.5}TiO{sub 3} (BST) 1 M thick films are conducted with variation of annealing hold time of 8 hours, 15 hours, 22 hours, and 29 hours at a constant temperature of 850 °C on p-type Si (100) substrate using sol-gel method then followed by spin coating process at 3000 rpm for 30 seconds. The BST thick film electrical conductivity is obtained to be 10{sup ?5} to 10{sup ?4} S/cm indicate that the BST thick film is classified as semiconductor material. The semiconductor energy band gap value of BST thick film based on annealing hold time of 8 hours, 15 hours, 22 hours, and 29 hours are 2.58 eV, 3.15 eV, 3.2 eV and 2.62 eV, respectively. The I-V photovoltaic characterization shows that the BST thick film is potentially solar cell device, and in accordance to annealing hold time of 8 hours, 15 hours, 22 hours and 29 hours have respective solar cell energy conversion efficiencies of 0.343%, 0.399%, 0.469% and 0.374%, respectively. Optical spectroscopy shows that BST thick film solar cells with annealing hold time of 8 hours, 15 hours, and 22 hours absorb effectively light energy at wavelength of ? 700 nm. BST film samples with annealing hold time of 29 hours absorb effectively light energy at wavelength of ? 700 nm. The BST thick film refraction index is between 1.1 to 1.8 at light wavelength between ±370 to 870 nm.

  16. IS C O N SIN FUSION TECHNOLOGY INSTITUTE

    E-Print Network [OSTI]

    OF WISCONSIN MADISON WISCONSIN A Resource Assessment and Extraction of Lunar 3He G.L. Kulcinski January 1992, Moscow. #12;A Resource Assessment and Extraction of Lunar 3He Gerald L. Kulcinski Wisconsin Center and 2. there was no known large 3He resource available prior to 1985.7 The situation with the D3He

  17. IS C O N SIN FUSION TECHNOLOGY INSTITUTE

    E-Print Network [OSTI]

    .A. El-Guebaly, D.L. Henderson, P.P.H. Wilson, A.E. Abdou, ARIES Team April 2002 UWFDM-1178 Presented Wall Chamber L.A. El-Guebaly, D.L. Henderson, P.P.H. Wilson, A.E. Abdou, ARIES Team Fusion Technology

  18. IS C O N SIN FUSION TECHNOLOGY INSTITUTE

    E-Print Network [OSTI]

    , results of the decay heat calculation are essential to examine the thermal re- sponse of the reactor OF WISCONSIN MADISON WISCONSIN Activation Analysis for the D-3He Reactor ARIES-III H.Y. Khater and M.E. Sawan Reactor ARIES-III H.Y. Khater and M.E. Sawan Fusion Technology Institute University of Wisconsin 1500

  19. The concentration of estradiol-17 gb sin bovine semen

    E-Print Network [OSTI]

    Godfrey, Robert Wayne

    1982-01-01T23:59:59.000Z

    indicated that the E2 was being added upon ejaculation (Ganjam and Amann, 1976). Sandberg et al. (1980) Cholesterol 17 OH Pregnenolone Progesterone Dehydroepiandrosterone 17 OH Progesterone Es tr i ol Androstenedione Testosterone Estrone Estradiol-17S... in the treatment of prostate cancer due to its ability to decrease testosterone production as well as decrease the growth of cancer cells in the prostate (Kenyon, 1950; Cant, 1976; Sandberg et al. , 1980). Seamark and White (1964) demonstrated that semen from...

  20. IS C O N SIN FUSION TECHNOLOGY INSTITUTE

    E-Print Network [OSTI]

    -MADISON 2004 #12;i Abstract Experiments are described that used an Inertial Electrostatic Confinement (IEC) fusion device to create radioisotopes for medical diagnostics. The IEC concept utilizes spherically this method is that the IEC device is small and relatively inexpensive, so it may be developed into a semi

  1. IS C O N SIN FUSION TECHNOLOGY INSTITUTE

    E-Print Network [OSTI]

    ­ Madison (UW ­ IEC) [J. F. Santarius, G. L. Kulcinski, R. P. Ashley, D. R. Boris, B. B. Cipiti, S. K. Deuterium anion current densities as high as 8.5 µA/cm2 have been measured at the wall of the UW IEC device. INTRODUCTION The inertial electrostatic confinement (IEC) fusion concept was first patented by Farnsworth1

  2. IS C O N SIN FUSION TECHNOLOGY INSTITUTE

    E-Print Network [OSTI]

    electrostatic confinement (IEC) devices plays an important role in the atomic and molecular physics processes dimensional rate equation model for the ion species composition in the source region of IEC devices is presented and compared with experimental measurements on the Wisconsin IEC device [J.F. Santarius, G

  3. Land degradation and climate change: a sin of omission?

    E-Print Network [OSTI]

    not solely responsible for the lack of awareness of the impacts of poor management practices, but we do play temperatures and the consequent increase in evaporative demand. During large rainfall events, land degradation a contributing role. At best, our increasing focus on climate change has an opportunity cost: there is less time

  4. agujas sin sistema: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    los Objetivos de?ltima actualizacin: 5 de abril de 2013 SISTEMA DE GARANTA DE CALIDAD DE LOS TTULOS DE LA Rey Juan Carlos, Universidad 393 DIA HORA AULA CURSO...

  5. Transcriptional functions of the corepressor Sin3A in skin

    E-Print Network [OSTI]

    Cox, Claire

    2013-03-12T23:59:59.000Z

    Upon activation in epidermal stem cells, the proto-oncogene c-Myc triggers their exit from the stem cell compartment resulting in an increase in progenitor cell proliferation and an induction in terminal differentiation. Whether c-Myc plays a direct...

  6. John Topham and Susan Redd Butler Off-Campus Faculty Research Awards James Ayres, University of Arizona, "The Manufacturing and Marketing of Railroad Ties in the Uinta

    E-Print Network [OSTI]

    Hart, Gus

    Idaho Phosphate Mining and Fertilizer Industry" Clyde Milner, Arkansas State University, "The West-War Intermountain West" Stephanie Capaldo, University of Arizona, "Smoke and Mirrors: Smelter Pollution and the Cultural Construction of Environmental Justice in the U.S.-Mexico Borderlands" Thomas Evans, Montana State

  7. Vraagstuk 15 y1 = sin(0.47380) -sin(0.47370) = 9.0000 10-5

    E-Print Network [OSTI]

    Sleijpen, Gerard

    twee bijna even grote getallen vermijden. We zien dat de relatieve fout hierbij inderaad een stuk relatieve fout nu dus een stuk kleiner. 2 #12;log(x) - log(x - 1), x 1 Als we deze grootheid uitrekenen

  8. Investigation of site preference of Zn doped Ba{sub 3}Co{sub 2?x}Zn{sub x}Fe{sub 24}O{sub 41} by Mössbauer spectroscopy

    SciTech Connect (OSTI)

    Lim, Jung Tae; Kim, Chul Sung, E-mail: cskim@kookmin.ac.kr [Department of Physics, Kookmin University, Seoul 136-702 (Korea, Republic of)

    2014-05-07T23:59:59.000Z

    The polycrystalline Ba{sub 3}Co{sub 2?x}Zn{sub x}Fe{sub 24}O{sub 41} (x?=?0.0, 0.5, 1.0) samples were prepared by using solid-state-reaction method. The crystal structures and magnetic properties of samples were investigated with x-ray diffractometer, vibrating sample magnetometer, and Mössbauer spectroscopy. The crystal structure of Ba{sub 3}Co{sub 2?x}Zn{sub x}Fe{sub 24}O{sub 41} (x?=?0.0, 0.5, 1.0) samples was determined to be a hexagonal structure with P6{sub 3}/mmc space group at 295 K, and the saturation magnetization (M{sub s}) of Ba{sub 3}Co{sub 2?x}Zn{sub x}Fe{sub 24}O{sub 41} (x?=?0.0, 0.5, 1.0) samples were found to be M{sub s} =?50.9, 53.1, 55.0 emu/g, respectively. From the temperature dependence of magnetization curves under 100 Oe between 4.2 and 740?K, we were able to observe the spin transition, and both spin transition temperature (T{sub s}) and Curie temperature (T{sub C}) decrease with increasing Zn concentration. Mössbauer spectra of all samples were obtained and analyzed at various temperatures ranging from 4.2 to 295 K. With ten-sextets for Fe sites corresponding to the Z-type hexagonal crystallographic sites, all spectra below T{sub C} were fitted by least-square method. In addition, from the site occupation numbers of Fe, calculated from the relative areas fitted to the Mössbauer spectra, we find that Zn ions preferentially occupy the tetrahedral sublattices of down sites.

  9. Dielectric, ferromagnetic and maganetoelectric properties of BaTiO{sub 3}–Ni{sub 0.7}Zn{sub 0.3}Fe{sub 2}O{sub 4} composite ceramics

    SciTech Connect (OSTI)

    Zhang, Rong-Fen [Department of Electronic Science, College of Science, Key Laboratory of Functional Composite Materials of Guizhou Province, Guizhou University, Guiyang, Guizhou 550025 (China); Deng, Chao-Yong, E-mail: cydeng@gzu.edu.cn [Department of Electronic Science, College of Science, Key Laboratory of Functional Composite Materials of Guizhou Province, Guizhou University, Guiyang, Guizhou 550025 (China); Ren, Li [Department of Electronic Science, College of Science, Key Laboratory of Functional Composite Materials of Guizhou Province, Guizhou University, Guiyang, Guizhou 550025 (China); Li, Zheng [Department of Materials Science and Engineering, State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University, Beijing 100084 (China); Zhou, Jian-Ping [College of Physics and Information Technology, Shaanxi Normal University, Xi’an 710062 (China)

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: • The lead-free ME ceramic composites BaTiO{sub 3}–Ni{sub 0.7}Zn{sub 0.3}Fe{sub 2}O{sub 4} were successfully synthesized. • The composites showed high dielectric constant and low dielectric loss. • The composite with 30% NiZn ferrite presented good soft magnetic properties and ME performance. - Abstract: Lead-free magnetoelectric composite ceramics (1 ? x)BaTiO{sub 3}–xNi{sub 0.7}Zn{sub 0.3}Fe{sub 2}O{sub 4} (x = 0.15, 0.3, 0.45) were successfully prepared by conventional oxide ceramic process. The tetragonal perovskite BaTiO{sub 3} and cubic spinel Ni{sub 0.7}Zn{sub 0.3}Fe{sub 2}O{sub 4} were confirmed by X-ray diffraction. The dielectric behaviors of all composite samples show a normal response to the increasing measurement frequency and Ni{sub 0.7}Zn{sub 0.3}Fe{sub 2}O{sub 4} ferrite content. Well defined ferromagnetic hysteresis loops and obvious magnetoelectric coupling effect are observed in the composite ceramics. The influence of applied dc bias magnetic field and Ni{sub 0.7}Zn{sub 0.3}Fe{sub 2}O{sub 4} ferrite content on the magnetoelectric coupling responding voltage is investigated. The strongest peak magnetoelectric coupling voltage coefficient is 124 ?V/cm Oe when x = 0.3, which corresponds to the maximum magnetoelectric coupling responding voltage of 200 ?V.

  10. Cu-doping effect on dielectric properties of organic gel synthesized Ba{sub 4}YMn{sub 3?x}Cu{sub x}O{sub 11.5±?}

    SciTech Connect (OSTI)

    Barbier, Tristan, E-mail: tristan.barbier@gmail.com [Université François Rabelais de Tours, CNRS, CEA, ENIVL, GREMAN UMR 7347, 37200 Tours (France); Autret-Lambert, Cécile [Université François Rabelais de Tours, CNRS, CEA, ENIVL, GREMAN UMR 7347, 37200 Tours (France); Andreazza, Pascal [Centre de Recherche sur la matière divisée (CRMD), Université d'Orléans, CNRS, FRE3520, 1B rue de la Férollerie, 45071 Orléans (France); Ruyter, Antoine; Honstettre, Christophe [Université François Rabelais de Tours, CNRS, CEA, ENIVL, GREMAN UMR 7347, 37200 Tours (France); Lambert, Sébastien [CEA—DAM, Le Ripault, 37260 Monts (France); Gervais, François; Lethiecq, Marc [Université François Rabelais de Tours, CNRS, CEA, ENIVL, GREMAN UMR 7347, 37200 Tours (France)

    2013-10-15T23:59:59.000Z

    Copper doped-Ba{sub 4}YMn{sub 3?x}Cu{sub x}O{sub 11.5±?} samples were synthesized by an organic gel assisted citrate process. X-ray diffraction of compositions with x=0.002, 0.005, 0.01, 0.02 and 0.04 does not reveal any change of hexagonal perovskite structure on doping. The effects of Cu-doping on the microstructure and dielectric properties were investigated. Cu doping modifies the electrical properties at the level of the impedance characteristics of both grain and grain boundary and to understand these different behaviours, we have carried out high-resolution transmission electron microscopy analysis. Among the Ba{sub 4}YMn{sub 3?x}Cu{sub x}O{sub 11.5±?} specimens studied, the composition x=0.002 shows a permittivity (??{sub r}) higher than the undoped compound and a lower loss tangent (tan?) over several orders of magnitude of frequency. - Graphical abstract: Highlighting of many stacking faults (intergrowths) in substituted compounds with x>0.01 (right picture), which could explain the different dielectric properties observed in these compounds. However compounds with x>0.01 remain with a better stacking sequence as we can see on the left picture. Display Omitted - Highlights: • High permittivity of the Ba{sub 4}YMn{sub 3?x}Cu{sub x}O{sub 11.5±?}. • Substitution leads to a mixed oxidation state for manganese: Mn{sup 4+}/Mn{sup 3+}. • Creation of oxygen vacancies which are responsible for stacking faults. • Highlighting relationship between Cu substitution and dielectric properties.

  11. Structural and magnetic properties of the quaternary oxides Ba{sub 6}Ln{sub 2}Fe{sub 4}O{sub 15} (Ln=Pr and Nd)

    SciTech Connect (OSTI)

    Abe, Kyosuke [Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810 (Japan); Doi, Yoshihiro [Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810 (Japan)], E-mail: doi@sci.hokudai.ac.jp; Hinatsu, Yukio [Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810 (Japan); Ohoyama, Kenji [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

    2009-02-15T23:59:59.000Z

    The crystal structures and magnetic properties of the quaternary lanthanide oxides Ba{sub 6}Ln{sub 2}Fe{sub 4}O{sub 15} (Ln=Pr and Nd) are reported. They crystallize in a hexagonal structure with space group P6{sub 3}mc and have the 'Fe{sub 4}O{sub 15} cluster' consisting of one FeO{sub 6} octahedron and three FeO{sub 4} tetrahedra. Measurements of the magnetic susceptibility, specific heat, and powder neutron diffraction reveal that this cluster behaves as a spin tetramer with a ferrimagnetic ground state of S{sub T}=5 even at room temperature. The cluster moments show a long-range antiferromagnetic ordering at 23.2 K (Ln=Pr) and 17.8 K (Nd), and the magnetic moments of the Ln{sup 3+} ions also order cooperatively. By applying the magnetic field ({approx}2 T), this antiferromagnetic ordering of the clusters changes to a ferromagnetic one. This result indicates that there exists a competition in the magnetic interaction between the clusters. - Graphical abstract: Quaternary oxides Ba{sub 6}Ln{sub 2}Fe{sub 4}O{sub 15} (Ln=Pr and Nd) have the Ba{sub 6}Nd{sub 2}Al{sub 4}O{sub 15}-type structure with space group P6{sub 3}mc. In them, the magnetic moments for the ferrimagnetic Fe{sub 4}O{sub 15} cluster (smaller circles: Fe{sup 3+} ions) and Ln{sup 3+} ions (larger ones) cooperatively show an antiferromagnetic ordering at low temperatures.

  12. Partial Spin Ordering and Complex Magnetic Structure in BaYFeO4: A Neutron Diffraction and High Temperature Susceptibility Study

    SciTech Connect (OSTI)

    Thompson, Corey [Florida State University, Tallahassee] [Florida State University, Tallahassee; Greedan, John [McMaster University] [McMaster University; Garlea, Vasile O [ORNL] [ORNL; Flacau, Roxana [National Research Council of Canada] [National Research Council of Canada; Tan, Malinda [California State University, Long Beach (CSULB)] [California State University, Long Beach (CSULB); Derakhshan, Shahab [California State University, Long Beach (CSULB)] [California State University, Long Beach (CSULB)

    2014-01-01T23:59:59.000Z

    The novel iron-based compound, BaYFeO4, crystallizes in the Pnma space group with two distinct Fe3+ sites, that are alternately corner-shared [FeO5]7 square pyramids and [FeO6]9 octahedra, forming into [Fe4O18]24 rings, which propagate as columns along the b-axis. A recent report shows two discernible antiferromagnetic (AFM) transitions at 36 and 48 K in the susceptibility, yet heat capacity measurements reveal no magnetic phase transitions at these temperatures. An upturn in the magnetic susceptibility measurements up to 400 K suggests the presence of shortrange magnetic behavior at higher temperatures. In this Article, variable-temperature neutron powder diffraction and hightemperature magnetic susceptibility measurements were performed to clarify the magnetic behavior. Neutron powder diffraction confirmed that the two magnetic transitions observed at 36 and 48 K are due to long-range magnetic order. Below 48 K, the magnetic structure was determined as a spin-density wave (SDW) with a propagation vector, k = (0, 0, 1/3), and the moments along the b-axis, whereas the structure becomes an incommensurate cycloid [k = (0, 0, 0.35)] below 36 K with the moments within the bc-plane. However, for both cases the ordered moments on Fe3+ are only of the order 3.0 B, smaller than the expected values near 4.5 B, indicating that significant components of the Fe moments remain paramagnetic to the lowest temperature studied, 6 K. Moreover, new high-temperature magnetic susceptibility measurements revealed a peak maximum at 550 K indicative of short-range spin correlations. It is postulated that most of the magnetic entropy is thus removed at high temperatures which could explain the absence of heat capacity anomalies at the long-range ordering temperatures. Published spin dimer calculations, which appear to suggest a k = (0, 0, 0) magnetic structure, and allow for neither low dimensionality nor geometric frustration, are inadequate to explain the observed complex magnetic structure.

  13. Donald Ostdiek Degree Offered: BA

    E-Print Network [OSTI]

    Richards-Kortum, Rebecca

    Palaeoclimate and Human Response ARCH 313 Sustainable Architecture BIOS 323 Conservation Biology BIOS 325 Ecology CEVE 201 Introduction to Environmental Systems CEVE 306 Global Environmental Law and Sustainable

  14. NREL-BA Team CARB

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in Many Devils Wash,Energy NREL Job Task

  15. Analysis of Beta-Decay Rates for Ag108, Ba133, Eu152, Eu154, Kr85, Ra226 And Sr90, Measured at the Physikalisch-Technische Bundesanstalt from 1990 to 1996

    E-Print Network [OSTI]

    Peter A. Sturrock; Ephraim Fischbach; Jere Jenkins

    2014-10-10T23:59:59.000Z

    We present the results of an analysis of measurements of the beta-decay rates of Ag108, Ba133, Eu152, Eu154, Kr85, Ra226, and Sr90 acquired at the Physikalisch-Technische Bundesanstalt from 1990 through 1995. Although the decay rates vary over a range of 165 to 1 and the measured detector current varies over a range of 19 to 1, the detrended and normalized current measurements exhibit a sinusoidal annual variation with amplitude in the small range 0.068% to 0.088% (mean 0.081%, standard deviation 0.0072%, an 11{\\sigma} rejection of the zero-amplitude hypothesis) and phase-of-maximum in the small range 0.062 to 0.083 (January 23 to January 30). In comparing these results with those of other related experiments that yield different results, it may be significant that this experiment, at a standards laboratory, seems to be unique in using a 4{\\pi} detector. These results are compatible with a solar influence, and appear not to be compatible with an experimental or environmental influence. It is possible that Ba133 measurements are subject also to a non-solar (possibly cosmic) influence.

  16. Neutron scattering study of underdoped Ba1-xKxFe?As? (x=0.09 and 0.17) self-flux-grown single crystals and the universality of the tricritical point

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rotundu, C. R.; Tian, W.; Rule, K. C.; Forrest, T. R.; Zhao, J.; Zarestky, J. L.; Birgeneau, R. J.

    2012-04-01T23:59:59.000Z

    We present a combination of elastic neutron scattering measurements in zero and 14.5 T and magnetization measurements in zero and 14 T on underdoped superconducting Ba1-xKxFe?As? (x=0.17), and the same measurements in zero field on a nonsuperconducting crystal with x=0.09. The data suggest that the underdoped materials may not be electronic phase separated but rather have slightly inhomogeneous potassium doping. The temperature dependence of the magnetic order parameter below the transition of the sample with x=0.09 is more gradual than that for the case of the undoped BaFe?As?, suggesting that this doping may be in the vicinity of a tricriticalmore »point. We advance therefore the hypothesis that the tricritical point is a common feature of all superconducting 122s. For the x=0.17 sample, while Tc is suppressed from ?17 to ?8 K by a magnetic field of 14 T, the intensity of the magnetic Bragg peaks (1 0 3) at 1.2 K is enhanced by 10%, showing competition of superconductivity and antiferromagnetism. The intensity of the magnetic Bragg peaks (1 0 3) in the (Tc, TN) temperature interval remain practically unchanged in 14.5 T within a 10% statistical error. The present results are discussed in the context of the existing literature.« less

  17. Neutron scattering study of underdoped Ba1-xKxFe?As? (x=0.09 and 0.17) self-flux-grown single crystals and the universality of the tricritical point

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rotundu, C. R.; Tian, W.; Rule, K. C.; Forrest, T. R.; Zhao, J.; Zarestky, J. L.; Birgeneau, R. J.

    2012-04-01T23:59:59.000Z

    We present a combination of elastic neutron scattering measurements in zero and 14.5 T and magnetization measurements in zero and 14 T on underdoped superconducting Ba1-xKxFe?As? (x=0.17), and the same measurements in zero field on a nonsuperconducting crystal with x=0.09. The data suggest that the underdoped materials may not be electronic phase separated but rather have slightly inhomogeneous potassium doping. The temperature dependence of the magnetic order parameter below the transition of the sample with x=0.09 is more gradual than that for the case of the undoped BaFe?As?, suggesting that this doping may be in the vicinity of a tricritical point. We advance therefore the hypothesis that the tricritical point is a common feature of all superconducting 122s. For the x=0.17 sample, while Tc is suppressed from ?17 to ?8 K by a magnetic field of 14 T, the intensity of the magnetic Bragg peaks (1 0 3) at 1.2 K is enhanced by 10%, showing competition of superconductivity and antiferromagnetism. The intensity of the magnetic Bragg peaks (1 0 3) in the (Tc, TN) temperature interval remain practically unchanged in 14.5 T within a 10% statistical error. The present results are discussed in the context of the existing literature.

  18. Neutron scattering study of underdoped Ba1-xKxFe?As? (x=0.09 and 0.17) self-flux-grown single crystals and the universality of the tricritical point

    SciTech Connect (OSTI)

    Rotundu, C. R.; Tian, W.; Rule, K. C.; Forrest, T. R.; Zhao, J.; Zarestky, J. L.; Birgeneau, R. J.

    2012-04-01T23:59:59.000Z

    We present a combination of elastic neutron scattering measurements in zero and 14.5 T and magnetization measurements in zero and 14 T on underdoped superconducting Ba1-xKxFe?As? (x=0.17), and the same measurements in zero field on a nonsuperconducting crystal with x=0.09. The data suggest that the underdoped materials may not be electronic phase separated but rather have slightly inhomogeneous potassium doping. The temperature dependence of the magnetic order parameter below the transition of the sample with x=0.09 is more gradual than that for the case of the undoped BaFe?As?, suggesting that this doping may be in the vicinity of a tricritical point. We advance therefore the hypothesis that the tricritical point is a common feature of all superconducting 122s. For the x=0.17 sample, while Tc is suppressed from ?17 to ?8 K by a magnetic field of 14 T, the intensity of the magnetic Bragg peaks (1 0 3) at 1.2 K is enhanced by 10%, showing competition of superconductivity and antiferromagnetism. The intensity of the magnetic Bragg peaks (1 0 3) in the (Tc, TN) temperature interval remain practically unchanged in 14.5 T within a 10% statistical error. The present results are discussed in the context of the existing literature.

  19. Domain wall motion and electromechanical strain in lead-free piezoelectrics: Insight from the model system (1 ? x)Ba(Zr{sub 0.2}Ti{sub 0.8})O{sub 3}–x(Ba{sub 0.7}Ca{sub 0.3})TiO{sub 3} using in situ high-energy X-ray diffraction during application of electric fields

    SciTech Connect (OSTI)

    Tutuncu, Goknur [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Li, Binzhi [Department of Chemical Engineering and Materials Science, University of California, Davis, Davis, California 95616 (United States); Bowman, Keith [Illinois Institute of Technology, Armour College of Engineering, Chicago, Illinois 60616 (United States); School of Materials Engineering, Purdue University, West Lafayette, Indiana 47907 (United States); Jones, Jacob L., E-mail: JacobJones@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States)

    2014-04-14T23:59:59.000Z

    The piezoelectric compositions (1 ? x)Ba(Zr{sub 0.2}Ti{sub 0.8})O{sub 3}–x(Ba{sub 0.7}Ca{sub 0.3})TiO{sub 3} (BZT-xBCT) span a model lead-free morphotropic phase boundary (MPB) between room temperature rhombohedral and tetragonal phases at approximately x?=?0.5. In the present work, in situ X-ray diffraction measurements during electric field application are used to elucidate the origin of electromechanical strain in several compositions spanning the tetragonal compositional range 0.6???x???0.9. As BCT concentration decreases towards the MPB, the tetragonal distortion (given by c/a-1) decreases concomitantly with an increase in 90° domain wall motion. The increase in observed macroscopic strain is predominantly attributed to the increased contribution from 90° domain wall motion. The results demonstrate that domain wall motion is a significant factor in achieving high strain and piezoelectric coefficients in lead-free polycrystalline piezoelectrics.

  20. Structure, solvation, and dynamics of Mg{sup 2+}, Ca{sup 2+}, Sr{sup 2+}, and Ba{sup 2+} complexes with 3-hydroxyflavone and perchlorate anion in acetonitrile medium: A molecular dynamics simulation study

    SciTech Connect (OSTI)

    Agieienko, Vira N.; Kolesnik, Yaroslav V.; Kalugin, Oleg N., E-mail: onkalugin@gmail.com [Department of Inorganic Chemistry, V. N. Karazin Kharkiv National University, Kharkiv 61022 (Ukraine)

    2014-05-21T23:59:59.000Z

    Molecular dynamics simulations of complexes of Mg{sup 2+}, Ca{sup 2+}, Sr{sup 2+}, and Ba{sup 2+} with 3-hydroxyflavone (flavonol, 3HF) and ClO {sub 4}{sup ?} in acetonitrile were performed. The united atoms force field model was proposed for the 3HF molecule using the results of DFT quantum chemical calculations. 3HF was interpreted as a rigid molecule with two internal degrees of freedom, i.e., rotation of the phenyl ring and of the OH group with respect to the chromone moiety. The interatomic radial distribution functions showed that interaction of the cations with flavonol occurs via the carbonyl group of 3HF and it is accompanied with substitution of one of the acetonitrile molecules in the cations’ first solvation shells. Formation of the cation–3HF complexes does not have significant impact on the rotation of the phenyl ring with respect to the chromone moiety. However, the orientation of the flavonol's OH-group is more sensitive to the interaction with doubly charged cations. When complex with Mg{sup 2+} is formed, the OH-group turns out of the plane of the chromone moiety that leads to rupture of intramolecular H-bond in the ligand molecule. Complexation of Ca{sup 2+}, Sr{sup 2+}, and BaClO {sub 4}{sup +} with 3HF produces two structures with different OH-positions, as in the free flavonol with the intramolecular H-bond and as in the complex with Mg{sup 2+} with disrupted H-bonding. It was shown that additional stabilization of the [MgClO{sub 4}(3HF)]{sup +} and [BaClO{sub 4}(3HF)]{sup +} complexes is determined by strong affinity of perchlorate anion to interact with flavonol via intracomplex hydrogen bond between an oxygen atom of the anion and the hydrogen atom of the 3-hydroxyl group. Noticeable difference in the values of the self-diffusion coefficients for Kt{sup 2+} from one side and ClO {sub 4}{sup ?}, 3HF, and AN in the cations’ coordination shell from another side implies quite weak interaction between cation, anion, and ligands in the investigated complexes.

  1. Order parameter and scaling behavior in BaZr{sub x}Ti{sub 1?x}O{sub 3} (0.3 < x < 0.6) relaxor ferroelectrics

    SciTech Connect (OSTI)

    Usman, Muhammad; Mumtaz, Arif, E-mail: arif@qau.edu.pk; Raoof, Sobia; Hasanain, S. K. [Department of Physics, Quaid-i-Azam University, Islamabad 45320 (Pakistan)] [Department of Physics, Quaid-i-Azam University, Islamabad 45320 (Pakistan)

    2013-12-23T23:59:59.000Z

    We report the relaxor behavior of the zirconium doped barium titanate BaZr{sub x}Ti{sub 1?x}O{sub 3} solid solutions and discuss the temperature, frequency, and concentration dependence in terms of correlations among the polar nanoregions. The relaxor behavior is analyzed within the mean field theory by estimating the Edward-Anderson order parameter q{sub EA}. Additionally, we find that q{sub EA} calculated for the different concentrations obeys a scaling behavior q{sub EA}=1?(T/T{sub m}){sup n}, where T{sub m} are the respective dielectric maxima temperatures and n?=?2.0?±?0.1. The frequency dependence of the q{sub EA} also shows results consistent with the above mentioned picture.

  2. Electrochemical properties of mixed conducting La{sub 1{minus}x}M{sub x}Co{sub 1{minus}y}Fe{sub y}O{sub 3{minus}{delta}} (M = Sr,Ca,Ba) perovskites

    SciTech Connect (OSTI)

    Stevenson, J.W.; Armstrong, T.R.; Pederson, L.R.; Weber, W.J. [Pacific Northwest Lab., Richland, WA (United States). Materials Sciences Dept.

    1995-10-01T23:59:59.000Z

    At elevated temperatures, some ABO{sub 3} perovskite type oxides having Co and Fe as B site cations exhibit substantial mixed (anionic and electronic) conductivity. Because of this behavior, they are candidate materials for applications such as solid oxide fuel cell cathodes and oxygen separation membranes. The purpose of the present study is to increase the understanding of the effects of composition, temperature, and environment on the electrochemical properties of selected materials within the La{sub 1{minus}x}M{sub x}Co{sub 1{minus}y}Fe{sub y}O{sub 3{minus}{delta}} (M=Sr,Ca,Ba) system in order to evaluate their applicability for the above-mentioned applications. Characterization techniques include XRD, SEM, TGA, dc conductivity, dilatometry, oxygen permeation measurements, and iodometric titration.

  3. Extrinsic mechanism for giant dielectric response in Ba{sub 0.70}Sr{sub 0.30}(Fe{sub 0.5}Nb{sub 0.5})O{sub 3} ceramic

    SciTech Connect (OSTI)

    Patel, Piyush Kumar, E-mail: klyadav35@yahoo.com; Yadav, K. L., E-mail: klyadav35@yahoo.com; Durgesh, E-mail: klyadav35@yahoo.com [Smart Materials Research Laboratory, Department of Physics, Indian Institute of Technology Roorkee, Roorkee-247667 (India)

    2014-04-24T23:59:59.000Z

    To obtain the high dielectric constant, the effect of sintering process on the electrical properties of Ba{sub 0.70}Sr{sub 0.30}(Fe{sub 0.5}Nb{sub 0.5})O{sub 3} ceramics were investigated. X-ray diffraction pattern of the samples at room temperature shows a monoclinic structure. Microstructure analysis shows well-grown and dense microstructure in all the samples. We found giant dielectric constant (?3.59 × 10{sup 5}) with low dielectric loss (?0.49) at room temperature for 2 hr sintered sample at 1250 °C. The extrinsic phenomena like interfacial polarization due to space charge accumulation at grain boundaries are discussed.

  4. Alternating and direct current field effects on the structure-property relationships in Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-x%BaTiO{sub 3} textured ceramics

    SciTech Connect (OSTI)

    Ge, Wenwei; Li, Jiefang; Viehland, D. [Department of Materials Science and Engineering, Virginia Tech, Blacksburg, Virginia 24061 (United States)] [Department of Materials Science and Engineering, Virginia Tech, Blacksburg, Virginia 24061 (United States); Maurya, Deepam; Priya, Shashank [Center for Energy Harvesting Materials and Systems (CEHMS), Bio-Inspired Materials and Devices Laboratory (BMDL), Virginia Tech, Blacksburg, Virginia 24061 (United States)] [Center for Energy Harvesting Materials and Systems (CEHMS), Bio-Inspired Materials and Devices Laboratory (BMDL), Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2013-06-03T23:59:59.000Z

    The influence of alternating (ac) and direct current (dc) fields on the structural and dielectric properties of [001]{sub PC} textured Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} (NBT-7%BT) ceramics has been investigated. X-ray diffraction measurements revealed that the depolarization at temperature T{sub d} in poled samples resulted from a tetragonal {yields} pseudo-cubic transition on heating. Moderate ac drive and dc bias had opposite influences on T{sub d}: ac drive decreased the T{sub d}, whereas dc bias increased it. These investigations suggested an effective method to expand the working temperature range of NBT-x%BT textured ceramics to a high temperature.

  5. Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K???Bi???TiO?-BaTiO?-Na???Bi???TiO? piezoelectric materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maurya, Deepam; Zhou, Yuan; Wang, Yaojin; Yan, Yongke; Li, Jiefang; Viehland, Dwight; Priya, Shashank

    2015-02-26T23:59:59.000Z

    We synthesized grain-oriented lead-free piezoelectric materials in (K???Bi???TiO?-BaTiO?-xNa???Bi???TiO? (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (~0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d?? ~ 190pC/N) and high temperature stability (~160°C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-180° domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectricmore »materials.« less

  6. Scaling of Dynamic Spin Correlations in BaCu2(Si0.5Ge0.5)2O7

    SciTech Connect (OSTI)

    Zheludev, Andrey I [ORNL; Masuda, T. [Yokohama City University, Japan; Dhalenne, G. [Universite Paris Sud, Orsay, France; Revcolevschi, A. [Universite Paris Sud, Orsay, France; Frost, C. [ISIS Facility, Rutherford Appleton Laboratory; Perring, T. G. [ISIS Facility, Rutherford Appleton Laboratory

    2007-01-01T23:59:59.000Z

    The magnetic dynamic structure factor of the one-dimensional S=1/2 chain system BaCu{sub 2}(Si{sub 0.5}Ge{sub 0.5}){sub 2}O{sub 7} is studied in a wide range of energy transfers and temperatures. Contrary to previous erroneous reports [T. Masuda et al., Phys. Rev. Lett. 93, 077206 (2004)], the scaling properties observed in the range 0.5-25 meV are found to be fully consistent with expectations for a Luttinger spin liquid. At higher energies, a breakdown of scaling laws is observed and attributed to lattice effects. The results are complementary to those found in literature for other S=1/2 chain compounds, such as KCuF{sub 3} and Cu benzoate.

  7. Rietveld refinement and dielectric studies of Bi{sub 0.8}Ba{sub 0.2}Fe{sub 0.95}V{sub 0.05}O{sub 3} ceramic

    SciTech Connect (OSTI)

    Priyanka,, E-mail: pgodara21@gmail.com; Agarwal, A., E-mail: pgodara21@gmail.com; Ahlawat, N., E-mail: pgodara21@gmail.com; Sanghi, S., E-mail: pgodara21@gmail.com; Rani, S., E-mail: pgodara21@gmail.com [Department of Applied Physics, Guru Jambheshwar University of Science and Technology, Hisar-125001, Haryana (India)

    2014-04-24T23:59:59.000Z

    Polycrystalline Bi{sub 0.8}Ba{sub 0.2}Fe{sub 0.95}V{sub 0.05}O{sub 3} ceramic has been prepared by the conventional solid state reaction technique. The Rietveld refinement of x-ray powder diffraction revealed that the sample has a rhombohedral crystal structure (space group R3c) with average particle size of 29 nm. The values of dielectric constant (??) and dielectric loss (tan ?) increases with increasing temperature at different frequencies which may be the result of increase in the number of charge carriers and their mobilities due to the thermal activation. The Jonscher’s universal power law used to analyze the ac conductivity. In the measured temperature range, the values of frequency exponent ‘s’ are less than one and shows a continous decrease which is attributed to the short range translational hopping assisted by large polaron hopping mechanisms.

  8. Microstructural and dielectric properties of Ba{sub 0.6}Sr{sub 0.4}Ti{sub 1-x}Zr{sub x}O{sub 3} based combinatorial thin film capacitors library

    SciTech Connect (OSTI)

    Liu Guozhen; Wolfman, Jerome; Autret-Lambert, Cecile; Sakai, Joe; Roger, Sylvain; Gervais, Monique; Gervais, Francois [Laboratoire d'Electrodynamique des Materiaux Avances (LEMA), UMR 6157 CNRS/CEA, Universite Francois Rabelais, Parc de Grandmont, 37200 Tours (France)

    2010-12-01T23:59:59.000Z

    Epitaxial growth of Ba{sub 0.6}Sr{sub 0.4}Ti{sub 1-x}Zr{sub x}O{sub 3} (0{<=}x{<=}0.3) composition spread thin film library on SrRuO{sub 3}/SrTiO{sub 3} layer by combinatorial pulsed laser deposition (PLD) is reported. X-ray diffraction and energy dispersive x-ray spectroscopy studies showed an accurate control of the film phase and composition by combinatorial PLD. A complex evolution of the microstructure and morphology with composition of the library is described, resulting from the interplay between epitaxial stress, increased chemical pressure, and reduced elastic energy upon Zr doping. Statistical and temperature-related capacitive measurements across the library showed unexpected variations in the dielectric properties. Doping windows with enhanced permittivity and tunability are identified, and correlated to microstructural properties.

  9. The effect of interface oxygen content on magnetoelectric effect of epitaxial La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/BaTiO{sub 3} bilayer

    SciTech Connect (OSTI)

    Tingxian, Li, E-mail: wxlltx@126.com [College of Physics and Electrical Engineering, Anyang Normal University, Anyang 455002 (China); Kuoshe, Li [National Engineering Research Central for Rare Earth Materials, General Research Institute for Nonferrous Metals, The Grirem Advanced materials Co. Ltd., Beijing 100088 (China)

    2014-01-28T23:59:59.000Z

    The epitaxial La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/BaTiO{sub 3} (LSMO/BTO) bilayer films are grown on (001) oriented LaAlO{sub 3} substrate by pulsed laser deposition technique. The oxygen-rich interface is obtained through in-situ annealing process in oxygen, and the oxygen-deficient interface is obtained without the annealing process. The results show that the ferromagnetic properties of the LSMO film and the magnetoelectric effect (ME) of the bilayer films strongly correlate to the oxygen content at the interface of LSMO/BTO. The saturated magnetization and the ME voltage coefficient of the oxygen-rich bilayer film are higher than that of oxygen-deficient one. It suggests a more effective ME coupling at the LSMO/BTO interface, which are generated through not only the interface strain but also the spin polarized carriers.

  10. High-field critical current enhancement by irradiation induced correlated and random defects in (Ba{sub 0.6}K{sub 0.4})Fe{sub 2}As{sub 2}

    SciTech Connect (OSTI)

    Kihlstrom, K. J.; Crabtree, G. W. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States) [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60607 (United States); Fang, L.; Jia, Y.; Shen, B.; Koshelev, A. E.; Welp, U.; Kwok, W.-K. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Kayani, A. [Department of Physics, Western Michigan University, Kalamazoo, Michigan 49008 (United States)] [Department of Physics, Western Michigan University, Kalamazoo, Michigan 49008 (United States); Zhu, S. F. [Physics Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Physics Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Wen, H.-H. [National Laboratory of Solid State Microstructures, Department of Physics, Center for Superconducting Physics and Materials, Nanjing University, Nanjing 210093 (China)] [National Laboratory of Solid State Microstructures, Department of Physics, Center for Superconducting Physics and Materials, Nanjing University, Nanjing 210093 (China)

    2013-11-11T23:59:59.000Z

    Mixed pinning landscapes in superconductors are emerging as an effective strategy to achieve high critical currents in high, applied magnetic fields. Here, we use heavy-ion and proton irradiation to create correlated and point defects to explore the vortex pinning behavior of each and combined constituent defects in the iron-based superconductor Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2} and find that the pinning mechanisms are non-additive. The major effect of p-irradiation in mixed pinning landscapes is the generation of field-independent critical currents in very high fields. At 7 T ? c and 5 K, the critical current density exceeds 5 MA/cm{sup 2}.

  11. Aging in the relaxor and ferroelectric state of Fe-doped (1-x)(Bi{sub 1/2}Na{sub 1/2})TiO{sub 3}-xBaTiO{sub 3} piezoelectric ceramics

    SciTech Connect (OSTI)

    Sapper, Eva; Dittmer, Robert; Rödel, Jürgen [Materials Science Department, Technische Universität Darmstadt, 64287 Darmstadt (Germany); Damjanovic, Dragan [Ceramics Laboratory, École Polytechnique Fédérale de Lausanne, Lausanne 1015 (Switzerland); Erdem, Emre [Institute of Physical Chemistry I, Universität Freiburg, 79104 Freiburg (Germany); Keeble, David J. [Division of Electronic Engineering and Physics, University of Dundee, Dundee DD1 4HN (United Kingdom); Jo, Wook [School of Materials Science and Engineering, Ulsan National Institute of Science and Technology, Ulsan 689-798 (Korea, Republic of); Granzow, Torsten [Centre de Recherche Public—Gabriel Lippmann, L-4422 Belvaux (Luxembourg)

    2014-09-14T23:59:59.000Z

    Aging of piezoelectric properties was investigated in lead-free (1???x)(Bi{sub 1/2}Na{sub 1/2})TiO{sub 3}-xBaTiO{sub 3} doped with 1at.?% Fe. The relaxor character of the un-poled material prevents macroscopic aging effects, while in the field-induced ferroelectric phase aging phenomena are similar to those found in lead zirconate titanate or barium titanate. Most prominent aging effects are the development of an internal bias field and the decrease of switchable polarization. These effects are temperature activated, and can be explained in the framework of defect complex reorientation. This picture is further supported by electron paramagnetic resonance spectra indicating the existence of (Fe{sub Ti}{sup ?}?V{sub O}{sup ••}){sup •} defect complexes in the Fe-doped material.

  12. Bifunction in Er{sup 3+}/Yb{sup 3+} co-doped BaTi{sub 2}O{sub 5}–Gd{sub 2}O{sub 3} glasses prepared by aerodynamic levitation method

    SciTech Connect (OSTI)

    Zhang, Minghui [State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); University of Chinese Academy of Sciences, Beijing 100039 (China); Yu, Jianding; Pan, Xiuhong [State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); Cheng, Yuxing [State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); University of Chinese Academy of Sciences, Beijing 100039 (China); Liu, Yan, E-mail: liuyan@mail.sic.ac.cn [State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China)

    2013-11-15T23:59:59.000Z

    Graphical abstract: - Highlights: • Novel BaTi{sub 2}O{sub 5}–Gd{sub 2}O{sub 3} based glasses have been prepared by aerodynamic levitation. • The obtained glasses show high thermal stability with T{sub g} = 763.3 °C. • Er{sup 3+}/Yb{sup 3+} co-doped glasses show strong upconversion based on a two-photon process. • Red emission is stronger than green emissions for EBT by high Yb{sup 3+} concentration. • Magnetic ions are paramagnetic and the distribution is homogeneous in the glasses. - Abstract: Novel Er{sup 3+}/Yb{sup 3+} co-doped BaTi{sub 2}O{sub 5}–Gd{sub 2}O{sub 3} spherical glasses have been fabricated by aerodynamic levitation method. The thermal stability, upconversion luminescence, and magnetic properties of the present glass have been studied. The glasses show high thermal stability with 763.3 °C of the onset temperature of the glass transition. Red and green emissions centered at 671 nm, 548 nm and 535 nm are obtained at 980 nm excitation. The upconversion is based on a two-photon process by energy transfer, excited-state absorption, and energy back transfer. Yb{sup 3+} ions are more than Er{sup 3+} ions in the glass, resulting in efficient energy back transfer from Er{sup 3+} to Yb{sup 3+}. So the red emission is stronger than the green emissions. Magnetization curves indicate that magnetic rare earth ions are paramagnetic and the distribution is homogeneous and random in the glass matrix. Aerodynamic levitation method is an efficient way to prepare glasses with homogeneous rare earth ions.

  13. Structural stability and depolarization of manganese-doped (Bi{sub 0.5}Na{sub 0.5}){sub 1?x}Ba{sub x}TiO{sub 3} relaxor ferroelectrics

    SciTech Connect (OSTI)

    Wang, Sheng-Fen [Department of Physics, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China); Tu, Chi-Shun, E-mail: 039611@mail.fju.edu.tw [Department of Physics, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China); Graduate Institute of Applied Science and Engineering, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China); Chang, Ting-Lun; Chen, Pin-Yi [Department of Mechanical Engineering, Ming-Chi University of Technology, New Taipei City 24301, Taiwan (China); Chen, Cheng-Sao [Department of Mechanical Engineering, Hwa-Hsia University of Technology, New Taipei City 23567, Taiwan (China); Hugo Schmidt, V. [Department of Physics, Montana State University, Bozeman, Montana 59717 (United States); Anthoniappen, J. [Graduate Institute of Applied Science and Engineering, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China)

    2014-10-21T23:59:59.000Z

    This work reveals that 0.5?mol. % manganese (Mn) doping in (Bi{sub 0.5}Na{sub 0.5}){sub 1?x}Ba{sub x}TiO{sub 3} (x?=?0 and 0.075) solid solutions can increase structural thermal stability, depolarization temperature (T{sub d}), piezoelectric coefficient (d{sub 33}), and electromechanical coupling factor (k{sub t}). High-resolution X-ray diffraction and transmission electron microscopy reveal coexistence of rhombohedral (R) R3c and tetragonal (T) P4bm phases in (Bi{sub 0.5}Na{sub 0.5}){sub 0.925}Ba{sub 0.075}TiO{sub 3} (BN7.5BT) and 0.5?mol. % Mn-doped BN7.5BT (BN7.5BT-0.5Mn). (Bi{sub 0.5}Na{sub 0.5})TiO{sub 3} (BNT) and BN7.5BT show an R???R?+?T phase transition, which does not occur in 0.5?mol. % Mn-doped BNT (BNT-0.5Mn) and BN7.5BT-0.5Mn. Dielectric permittivity (??) follows the Curie-Weiss equation, ???=?C/(T???T{sub o}), above the Burns temperature (T{sub B}), below which polar nanoregions begin to develop. The direct piezoelectric coefficient (d{sub 33}) and electromechanical coupling factor (k{sub t}) of BN7.5BT-0.5Mn reach 190 pC/N and 47%.

  14. "Atm o sp h e ric a n d O c e a n ic P ro c e sse s, D y n a m ic s, a n d C lim a te C h a n g e (AE 1 0 9 ) C o n fe re n c e " in "S P IE 's T h ird In te rn a tio n a l Asia -P a c ific E n v iro n m e n ta l R e m o te S e n sin g S y m p o siu m 2 0

    E-Print Network [OSTI]

    Wang, Junhong

    "Atm o sp h e ric a n d O c e a n ic P ro c e sse s, D y n a m ic s, a n d C lim a te C h a n g e (AE 1 0 9 ) C o n fe re n c e " in "S P IE 's T h ird In te rn a tio n a l Asia -P a c ific E n v iro n m e n ta l R e m o te S e n sin g S y m p o siu m 2 0 0 2 : R e m o te S e n sin g o f th e Atm o

  15. Synthesis and structural characterization of the ternary Zintl phases AE{sub 3}Al{sub 2}Pn{sub 4} and AE{sub 3}Ga{sub 2}Pn{sub 4} (AE=Ca, Sr, Ba, Eu; Pn=P, As)

    SciTech Connect (OSTI)

    He, Hua; Tyson, Chauntae; Saito, Maia [Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States); Bobev, Svilen, E-mail: bobev@udel.edu [Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States)

    2012-04-15T23:59:59.000Z

    Ten new ternary phosphides and arsenides with empirical formulae AE{sub 3}Al{sub 2}Pn{sub 4} and AE{sub 3}Ga{sub 2}Pn{sub 4} (AE=Ca, Sr, Ba, Eu; Pn=P, As) have been synthesized using molten Ga, Al, and Pb fluxes. They have been structurally characterized by single-crystal and powder X-ray diffraction to form with two different structures-Ca{sub 3}Al{sub 2}P{sub 4}, Sr{sub 3}Al{sub 2}As{sub 4}, Eu{sub 3}Al{sub 2}P{sub 4}, Eu{sub 3}Al{sub 2}As{sub 4}, Ca{sub 3}Ga{sub 2}P{sub 4}, Sr{sub 3}Ga{sub 2}P{sub 4}, Sr{sub 3}Ga{sub 2}As{sub 4}, and Eu{sub 3}Ga{sub 2}As{sub 4} crystallize with the Ca{sub 3}Al{sub 2}As{sub 4} structure type (space group C2/c, Z=4); Ba{sub 3}Al{sub 2}P{sub 4} and Ba{sub 3}Al{sub 2}As{sub 4} adopt the Na{sub 3}Fe{sub 2}S{sub 4} structure type (space group Pnma, Z=4). The polyanions in both structures are made up of TrPn{sub 4} tetrahedra, which share common corners and edges to form {sup 2}{sub {infinity}}[TrPn{sub 2}]{sub 3-} layers in the phases with the Ca{sub 3}Al{sub 2}As{sub 4} structure, and {sup 1}{sub {infinity}}[TrPn{sub 2}]{sub 3-} chains in Ba{sub 3}Al{sub 2}P{sub 4} and Ba{sub 3}Al{sub 2}As{sub 4} with the Na{sub 3}Fe{sub 2}S{sub 4} structure type. The valence electron count for all of these compounds follows the Zintl-Klemm rules. Electronic band structure calculations confirm them to be semiconductors. - Graphical abstract: AE{sub 3}Al{sub 2}Pn{sub 4} and AE{sub 3}Ga{sub 2}Pn{sub 4} (AE=Ca, Sr, Ba, Eu; Pn=P, As) crystallize in two different structures-Ca{sub 3}Al{sub 2}P{sub 4}, Sr{sub 3}Al{sub 2}As{sub 4}, Eu{sub 3}Al{sub 2}P{sub 4}, Eu{sub 3}Al{sub 2}As{sub 4}, Ca{sub 3}Ga{sub 2}P{sub 4}, Sr{sub 3}Ga{sub 2}P{sub 4}, Sr{sub 3}Ga{sub 2}As{sub 4}, and Eu{sub 3}Ga{sub 2}As{sub 4}, are isotypic with the previously reported Ca{sub 3}Al{sub 2}As{sub 4} (space group C2/c (No. 15)), while Ba{sub 3}Al{sub 2}P{sub 4} and Ba{sub 3}Al{sub 2}As{sub 4} adopt a different structure known for Na{sub 3}Fe{sub 2}S{sub 4} (space group Pnma (No. 62). The polyanions in both structures are made up of TrPn{sub 4} tetrahedra, which by sharing common corners and edges, form {sup 2}{sub {infinity}}[TrPn{sub 2}]{sub 3-}layers in the former and {sup 1}{sub {infinity}}[TrPn{sub 2}]{sub 3-} chains in Ba{sub 3}Al{sub 2}P{sub 4} and Ba{sub 3}Al{sub 2}As{sub 4}. Highlights: Black-Right-Pointing-Pointer AE{sub 3}Ga{sub 2}Pn{sub 4} (AE=Ca, Sr, Ba, Eu; Pn=P, As) are new ternary pnictides. Black-Right-Pointing-Pointer Ba{sub 3}Al{sub 2}P{sub 4} and Ba{sub 3}Al{sub 2}As{sub 4} adopt the Na{sub 3}Fe{sub 2}S{sub 4} structure type. Black-Right-Pointing-Pointer The Sr- and Ca-compounds crystallize with the Ca{sub 3}Al{sub 2}As{sub 4} structure type. Black-Right-Pointing-Pointer The valence electron count for all title compounds follows the Zintl-Klemm rules.

  16. MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT

    E-Print Network [OSTI]

    Fox, J. P.

    2012-01-01T23:59:59.000Z

    oil shales of the Green River Formation, Piceance Creek Basin, Colorado, and the Uinta Basin, Utah- a preliminary report, Chemical Geology,

  17. OIL SHALE RESEARCH. CHAPTER FROM THE ENERGY AND ENVIRONMENT DIVISION ANNUAL REPORT 1979

    E-Print Network [OSTI]

    ,

    2012-01-01T23:59:59.000Z

    Oil Shales of the Green River Formation, Piceance Creek Basin, Colorado, and the Uinta Basin, Utah--A Preliminary Report," Chemical Geology,

  18. ENERGY & ENVIRONMENT DIVISION ANNUAL REPORT 1979

    E-Print Network [OSTI]

    Cairns, E.J.

    2010-01-01T23:59:59.000Z

    Oil Shales of the Green River Formation, Piceance Creek Basin, Colorado, and the Uinta Basin, Utah--A Preliminary Report," Chemical Geology,

  19. WATER QUALITY EFFECTS OF LEACHATES FROM AN IN SITU OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J. P.

    2011-01-01T23:59:59.000Z

    Oil Shale of the Green River FonThction, Piceance Creek Basin, Colorado, and the Uinta Basin, Utah - A Prelirninary Report, Chemical Geology,

  20. ENERGY & ENVIRONMENT DIVISION. ANNUAL REPORT FY 1980

    E-Print Network [OSTI]

    Authors, Various

    2010-01-01T23:59:59.000Z

    Oil Shales of the Green River Formation, Piceance Creek Basin, Colorado, and the Uinta Basin, Utah—A Preliminary Report," Chemical Geology,

  1. U.S. Energy Information Administration (EIA) - Sector

    Gasoline and Diesel Fuel Update (EIA)

    -- -- -- -- 51 41 12 Uinta -- -- -- -- 7 21 11 Permian -- -- -- -- -- 67 27 Greater Green River -- -- -- -- -- 18 13 Black Warrior -- -- -- -- -- 4 5 Shale gas total 83 126 125...

  2. Determination of the optical properties of La2-xBaxCuO? for several dopings, including the anomalous x=1/8 phase

    SciTech Connect (OSTI)

    Homes, C. C.; Hücker, M.; Li, Q.; Xu, Z. J.; Wen, J. S.; Gu, G. D.; Tranquada, J. M.

    2012-04-01T23:59:59.000Z

    The optical properties of single crystals of the high-temperature superconductor La2-xBaxCuO? have been measured over a wide frequency and temperature range for light polarized in the a-b planes and along the c axis. Three different Ba concentrations have been examined, x=0.095 with a critical temperature Tc=32 K, x=0.125 where the superconductivity is dramatically weakened with Tc?2.4 K, and x=0.145 with Tc?24 K. The in-plane behavior of the optical conductivity for these materials at high temperature is described by a Drude-like response with a scattering rate that decreases with temperature. Below Tc in the x=0.095 and 0.145 materials there is a clear signature of the formation of a superconducting state in the optical properties allowing the superfluid density (?s0) and the penetration depth to be determined. In the anomalous 1/8 phase, some spectral weight shifts from lower to higher frequency (?300 cm?¹) on cooling below the spin-ordering temperature Tso?42 K, associated with the onset of spin-stripe order; we discuss alternative interpretations in terms of a conventional density-wave gap versus the response to pair-density-wave superconductivity. The two dopings for which a superconducting response is observed both fall on the universal scaling line ?s0/8?4.4?dcTc, which is consistent with the observation of strong dissipation within the a-b planes. The optical properties for light polarized along the c axis reveal an insulating character dominated by lattice vibrations, superimposed on a weak electronic background. No Josephson plasma edge is observed in the low-frequency reflectance along the c axis for x=1/8; however, sharp plasma edges are observed for x=0.095 and 0.145 below Tc.

  3. Induced lattice strain in epitaxial Fe-based superconducting films on CaF{sub 2} substrates: A comparative study of the microstructures of SmFeAs(O,F), Ba(Fe,Co){sub 2}As{sub 2}, and FeTe{sub 0.5}Se{sub 0.5}

    SciTech Connect (OSTI)

    Ichinose, Ataru, E-mail: ai@criepi.denken.or.jp; Tsukada, Ichiro [Central Research Institute of Electric Power Industry, 2-6-1 Nagasaka, Yokosuka 240-0195 (Japan); Nabeshima, Fuyuki; Imai, Yoshinori; Maeda, Atsutaka [Department of Basic Science, The University of Tokyo, Meguro, Tokyo 153-8902 (Japan); Kurth, Fritz; Holzapfel, Bernhard; Iida, Kazumasa [Institute for Metallic Materials, IFW Dresden, 01171 Dresden (Germany); Ueda, Shinya; Naito, Michio [Department of Applied Physics, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588 (Japan)

    2014-03-24T23:59:59.000Z

    The microstructures of SmFeAs(O,F), Ba(Fe,Co){sub 2}As{sub 2}, and FeTe{sub 0.5}Se{sub 0.5} prepared on CaF{sub 2} substrates were investigated using transmission electron microscopy. The SmFeAs(O,F)/CaF{sub 2} interface is steep, without a disordered layer. By contrast, a chemical reaction occurs at the interface in the cases of Ba(Fe,Co){sub 2}As{sub 2} and FeTe{sub 0.5}Se{sub 0.5}. The reaction layers are located on opposite sides of the interface for Ba(Fe,Co){sub 2}As{sub 2} and FeTe{sub 0.5}Se{sub 0.5}. We found that the lattice distortion of the three superconducting films on the CaF{sub 2} substrates enhances the T{sub C} values compared with films prepared on oxide substrates. The origin of this lattice deformation varies depending on the superconducting material.

  4. Substitution behavior of x(Na{sub 0.5}K{sub 0.5})NbO{sub 3}-(1???x)BaTiO{sub 3} ceramics for multilayer ceramic capacitors by a near edge x-ray absorption fine structure analysis

    SciTech Connect (OSTI)

    Ha, Jooyeon; Ryu, Jiseung; Lee, Heesoo, E-mail: heesoo@pusan.ac.kr [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)

    2014-06-30T23:59:59.000Z

    The doping effect of (Na{sub 0.5}K{sub 0.5})NbO{sub 3} (NKN) as alternatives for rare-earth elements on the electrical properties of BaTiO{sub 3} has been investigated, in terms of their substitution behavior. The dielectric constant of a specimen with x?=?0.05 was about 79% higher than that of pure BaTiO{sub 3}, and the temperature coefficient of capacitance was satisfied by the X7R specification. The specimen with x?=?0.05 showed the lowest tetragonality among the four compositions and had a fine grain size of <2 ?m. Although the addition of NKN decreased the specimen's tetragonality, the electrical properties were enhanced by the formation of defect dipoles and conduction electrons, which resulted from an acceptor and donor substitution behavior. Through O K-edge near edge x-ray absorption fine structure spectroscopy, the practical substitution behavior was defined by the change in Ti 3d orbital states. The energy separation of the Ti 3d orbitals was more apparent with the specimen of x?=?0.05, which is related to the donor level from the donor substitution of Nb{sup 5+} ion for Ti-sites. Therefore, the simultaneous substitution of Na{sup +}/K{sup +} and Nb{sup 5+} ions into BaTiO{sub 3} can improve dielectric properties, based on the charge-transfer process.

  5. Low-frequency inelastic light scattering in a ZBLAN (ZrF{sub 4}-BaF{sub 2}-LaF{sub 3}-AlF{sub 3}-NaF) glass

    SciTech Connect (OSTI)

    Adichtchev, S. V.; Malinovsky, V. K.; Surovtsev, N. V., E-mail: lab21@iae.nsk.su [Institute of Automation and Electrometry, Siberian Branch of Russian Academy of Sciences, Novosibirsk 630090 (Russian Federation); Ignatieva, L. N.; Merkulov, E. B. [Institute of Chemistry, Far East Branch of Russian Academy of Sciences, Vladivostok 690022 (Russian Federation)] [Institute of Chemistry, Far East Branch of Russian Academy of Sciences, Vladivostok 690022 (Russian Federation)

    2014-05-14T23:59:59.000Z

    Low-frequency (down to 30 GHz) inelastic light scattering is studied in a multicomponent glass ZBLAN (ZrF{sub 4}-BaF{sub 2}-LaF{sub 3}-AlF{sub 3}-NaF) in a wide temperature range. The contributions of the THz vibrational spectrum (boson peak) and of the fast relaxation are extracted and analyzed. It is shown that the fast relaxation spectrum is described by a distribution of relaxation times leading to a power-law ?{sup ?} dependence in the frequency range 30–300 GHz. Temperature dependence of ?(T) is well described by the Gilroy-Phillips model, while the integrated intensity of the fast relaxation increases significantly with the temperature. This feature distinguishes the fast relaxation in ZBLAN from the case of most single-component glasses. Thermodynamic and kinetic fragility indexes are significantly different for the ZBLAN glass. The correlations between the boson peak intensity, elastic moduli, and fragility index, found earlier for single-component glasses, are fulfilled for the thermodynamic fragility index of ZBLAN. In contrast, the correlation between the fast relaxation intensity at T{sub g} and the fragility holds better for the kinetic fragility index of ZBLAN. We propose that thermodynamic and kinetic fragilities reflect different aspects of glassy dynamics in the case of glass formers with the complex chemical composition and structure topology: the former correlates with the elastic properties and the boson peak, the latter with the relaxation.

  6. Strong Enhancement of Flux Pinning in YBa2Cu3O7-? Multilayers with Columnar Defects Comprised of Self-Assembled BaZrO3

    SciTech Connect (OSTI)

    Kang, Sukill [ORNL; Leonard, Keith J [ORNL; Martin, Patrick M [ORNL; Li, Jing [ORNL; Goyal, Amit [ORNL

    2007-01-01T23:59:59.000Z

    Multilayer structures comprising YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} (YBCO) films with columns of self-assembled BaZrO{sub 3} (BZO) nanodots with interlayers of CeO{sub 2} or pure YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} were grown on rolling-assisted biaxially textured substrates (RABiTSs) using pulsed laser deposition. A significant enhancement of the critical current density (J{sub c}) was observed for the multilayers compared with a single layer of YBCO + BZO. J{sub c} varies as J{sub c}{approx}H{sup -{alpha}} with a of 0.27 for single layer of YBCO + BZO and 0.34 for both multilayered films. Enhancement of pinning in the multilayers is attributed to the presence of columnar defects comprised of self-assembled nanodots of BZO as well as planar CuO-type stacking defects arising as a result of interfacial reactions in the multilayers.

  7. Effect of growth conditions on microstructure of BiFeO{sub 3}-0.33BaTiO{sub 3} films and performance of bulk acoustic wave resonators

    SciTech Connect (OSTI)

    Vorobiev, A., E-mail: andrei.vorobiev@chalmers.se; Gevorgian, S. [Department of Microtechnology and Nanoscience, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Löffler, M.; Olsson, E. [Department of Applied Physics, Chalmers University of Technology, SE-41296 Gothenburg (Sweden)

    2014-02-28T23:59:59.000Z

    The effect of growth conditions on the microstructure of BiFeO{sub 3}-0.33BaTiO{sub 3} (BF-BT) films and the performance of bulk acoustic wave (BAW) resonators is analyzed using test structures with the BF-BT films grown at different positions relative to the plume axis in the pulsed laser deposition system. The BF-BT film grain size and surface roughness reveal a strong asymmetric surface distribution and decrease significantly in the film region facing the laser beam-plume interaction area. The (100) BF-BT texturing is enhanced in this film region. The variations in the BF-BT film microstructure result in corresponding variations of the BAW resonator performance. Their correlations are established using the model of the roughness induced attenuation of the reflected acoustic waves and theory of the dc field induced piezoelectric effect. The BAW resonators with the highest parameters are obtained in the BF-BT film region facing the laser beam-plume interaction area. The BAW resonators located in this film region reveal a mechanical Q-factor of 200 at 4.2?GHz, an effective electromechanical coupling coefficient of 10% and a tunability of the series resonance frequency of 4.5%.

  8. Anode-supported tubular SOFCs based on BaZr0.1Ce0.7Y0.1Yb0.1O3?? electrolyte fabricated by dip coating

    SciTech Connect (OSTI)

    Chen, Changcheng; Liu, Mingfei; Bai, Yaohui; Yang, Lei; Xie, Erqing; Liu, Meilin

    2011-01-01T23:59:59.000Z

    Anode-supported tubular solid oxide fuel cells (SOFCs) based on a proton and oxide ion mixed conductor, BaZr{sub 0.1}Ce{sub 0.7}Y{sub 0.1}Yb{sub 0.1}O{sub 3 ? ?} (BZCYYb), have been fabricated using a dip coating and co-firing process. This new fabrication technique effectively reduced the Ohmic resistances of tubular cells to ~ 0.1 and ~ 0.3 ? cm{sup 2} at 750 and 600 °C, respectively. Typical tubular cells with Ni-BZCYYb anode, BZCYYb electrolyte, and La{sub 0.6}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3 ? ?} (LSCF)-BZCYYb composite cathode demonstrated much-improved performance, achieving peak power densities of 1.13, 0.81, 0.63, and 0.53 W cm{sup ? 2} at 750, 700, 650, and 600 °C, respectively, when humidified (3 v% water vapor) hydrogen was used as fuel and ambient air as oxidant.

  9. Double-sided Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} thin films based high temperature superconducting filter operating above 100?K

    SciTech Connect (OSTI)

    Xie, Wei; Wang, Pei; He, Ming, E-mail: heming@nankai.edu.cn; Qiao, Ren; Du, Jia-Nan; Gao, Xiao-Xin; Liu, Xin; Zhang, Xu; Ji, Lu; Chen, Hai-Hua; Zhao, Xin-Jie, E-mail: zhaoxj@nankai.edu.cn [College of Electronic Information and Optical Engineering, Nankai University, Tianjin 300071 (China)

    2014-09-01T23:59:59.000Z

    A high temperature superconducting (HTS) filter on double-sided Tl{sub 2}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} (Tl-2223) thin films is designed in this letter. High-quality double-sided Tl-2223 thin films are prepared on 10?×?10?×?0.5?mm{sup 3} LaAlO{sub 3} (001) substrate. The critical temperatures T{sub c} of the films are 120?±?1?K and the critical current densities J{sub c} are 3–4 MA/cm{sup 2} at 77?K for both sides. X-ray diffraction ?-2? scans and rotational ?-scans prove that the films are strongly textured with the c axis perpendicular to the substrate surface. A 3-pole band-pass filter is then fabricated on the Tl-2223 thin films with 4% relative bandwidth and a center frequency of 4.0 GHz. At 77?K, 100?K, and 102?K, the insertion loss in the passband is 0.088?dB, 0.21?dB, and 0.27?dB, respectively. These performances show that the proposed HTS filter is satisfying even when the operating temperature is above 100?K, which makes it possible to work in outer space without cryogenic systems.

  10. Enhanced dielectric constant and relaxor behavior realized by dual stage sintering of Sr{sub 0.5}Ba{sub 0.5}Nb{sub 2}O{sub 6}

    SciTech Connect (OSTI)

    Rathore, Satyapal S., E-mail: satish.vitta@iitb.ac.in; Vitta, Satish, E-mail: satish.vitta@iitb.ac.in [Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai- 400076 (India)

    2014-04-24T23:59:59.000Z

    The relaxor ferroelectric compound, Sr{sub 0.5}Ba{sub 0.5}Nb{sub 2}O{sub 6} (SBN50) was synthesized by solid state reaction followed by sintering under two different conditions: single and dual stage sintering. The impact of sintering process on structural and dielectric properties has been studied in detail using X-ray diffraction, scanning electron microscopy and broadband dielectric spectroscopy. The crystal structure determined by performing Rietveld refinement of X-ray diffractogram was found to be identical in both cases. SBN50 crystallizes in the ferroelectric tetragonal tungsten bronze, P4bm structure. It was observed that uniform grain growth can be controlled by dual stage sintering and relatively narrow distribution of grains can be achieved with an average grain size of ?15 ?m. The dielectric studies show that SBN50 exhibits a relaxor ferroelectric behavior with the transformation taking place at ? 380 K due to formation of polar nano regions. Although both single and dual stage sintered SBN50 exhibits relaxor behaviour, the maximum dielectric constant of dual stage sintered SBN50 is found to be 1550 compare to 1440 for single stage sintering.

  11. Spin dynamics, short-range order, and spin freezing in Y{sub 0.5}Ca{sub 0.5}BaCo{sub 4}O{sub 7}

    SciTech Connect (OSTI)

    Stewart, J. R. [ISIS Facility, Rutherford Appleton Laboratory, Didcot, Oxford OX11 0QX (United Kingdom); Ehlers, G. [Neutron Scattering Science Division, Oak Ridge National Laboratory, Building 8600, Oak Ridge, Tennessee 37831-6475 (United States); Mutka, H.; Fouquet, P. [Institut Laue-Langevin, 6 rue Jules Horowitz, BP 156, F-38042 Grenoble Cedex 9 (France); Payen, C. [Institut des Materiaux Jean Rouxel (IMN), Universite de Nantes-CNRS, BP 32229, F-44322 Nantes Cedex 3 (France); Lortz, R. [Department of Condensed Matter Physics, University of Geneva, 24 Quai Ernest-Ansermet, CH-1211 Geneva 4 (Switzerland)

    2011-01-15T23:59:59.000Z

    Y{sub 0.5}Ca{sub 0.5}BaCo{sub 4}O{sub 7} was recently introduced as a possible candidate for capturing some of the predicted classical spin kagome ground-state features. Stimulated by this conjecture, we have taken up a more complete study of the spin correlations in this compound with neutron scattering methods on a powder sample characterized with high-resolution neutron diffraction and the temperature dependence of magnetic susceptibility and specific heat. We have found that the frustrated near-neighbor magnetic correlations involve not only the kagome planes but concern the full Co sublattice, as evidenced by the analysis of the wave-vector dependence of the short-range order. We conclude from our results that the magnetic moments are located on the Co sublattice as a whole and that correlations extend beyond the two-dimensional kagome planes. We identify intriguing dynamical properties, observing high-frequency fluctuations with a Lorentzian linewidth {Gamma}{<=}20 meV at ambient temperature. On cooling a low-frequency ({approx}1 meV) dynamical component develops alongside the high-frequency fluctuations, which eventually becomes static at temperatures below T{approx_equal}50 K. The high-frequency response with an overall linewidth of {approx}10 meV prevails at T{<=}2 K, coincident with a fully elastic short-range-ordered contribution.

  12. Preparation and dielectric properties of Ba{sub 0.95}Ca{sub 0.05}Ti{sub 0.8}Zr{sub 0.2}O{sub 3}-polyethersulfone composites

    SciTech Connect (OSTI)

    Wang Fajun; Li Wen; Jiang Hongliu; Xue Mingshan; Lu Jinshan; Yao Junping [School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063 (China)

    2010-02-15T23:59:59.000Z

    We report the preparation and dielectric properties of ceramic-polymer composites using Ba{sub 0.95}Ca{sub 0.05}Ti{sub 0.8}Zr{sub 0.2}O{sub 3} (BCTZ) as a ceramic filler and polyethersulfone (PES) as a polymer matrix. The BCTZ powders were synthesized by a sol-gel method to fabricate BCZT-PES composites. The composites with various BCTZ volume fractions were prepared by a solution mixing and hot-pressing method. The composite with 50 vol % BCTZ showed high dielectric constant ({epsilon}=48.80) and low loss (tan {delta}=0.042) at 1 kHz and room temperature. Such excellent dielectric properties of the composites displayed an acceptable stability within a wide range of temperature (from 20 to 150 deg. C) and frequency (from 100 Hz to 100 kHz). The present work indicates that the BCTZ-PES composite can be a candidate for embedded capacitors.

  13. Neutron powder diffraction and difference maximum entropy method analysis of protium- and deuterium-dissolved BaSn{sub 0.5}In{sub 0.5}O{sub 2.75+{alpha}}

    SciTech Connect (OSTI)

    Nagasaki, Takanori, E-mail: nagasaki@esi.nagoya-u.ac.j [EcoTopia Science Institute, Nagoya University, Nagoya 464-8603 (Japan); Shiotani, Shinya [Graduate School of Engineering, Nagoya University, Nagoya 464-8603 (Japan); Igawa, Naoki [Quantum Beam Science Directorate, Japan Atomic Energy Agency, Tokai-mura, Ibaraki 319-1195 (Japan); Yoshino, Masahito; Iwasaki, Kouta [Graduate School of Engineering, Nagoya University, Nagoya 464-8603 (Japan); Fukazawa, Hiroshi; Utsumi, Wataru [Quantum Beam Science Directorate, Japan Atomic Energy Agency, Tokai-mura, Ibaraki 319-1195 (Japan)

    2009-10-15T23:59:59.000Z

    We propose a new method, a difference maximum entropy method (MEM) analysis of the neutron diffraction data, for revealing the detailed structure around hydrogen atoms in proton-conducting oxides. This MEM analysis uses the differences between the structure factors of protium- and deuterium-dissolved crystals. Simulations demonstrate that it not only provides the distribution of hydrogen atoms alone, but also improves the spatial resolution of MEM mapping around hydrogen atoms. Applied to actual diffraction data of protium- and deuterium-dissolved BaSn{sub 0.5}In{sub 0.5}O{sub 2.75+{alpha}} at 9 K, difference MEM analysis reveals that O-D bonds mostly tilt towards the second nearest oxygen atoms, and that the distributions of deuterium and oxygen atoms are probably insignificant in interstitial regions. - Graphical abstract: A novel method, difference maximum entropy method (MEM) analysis of the neutron diffraction data, is proposed for revealing the detailed structure around hydrogen atoms in proton-conducting oxides. This MEM analysis uses the differences between the structure factors of protium- and deuterium-dissolved crystals and improves the spatial resolution of the MEM mapping around the hydrogen atoms.

  14. Persistent luminescence in Ba{sub 5}(PO{sub 4}){sub 3}Cl:Eu{sup 2+},R{sup 3+} (R = Y, La, Ce, Gd, Tb and Lu)

    SciTech Connect (OSTI)

    Ju, Guifang; Hu, Yihua, E-mail: huyh@gdut.edu.cn; Chen, Li; Wang, Xiaojuan; Mu, Zhongfei

    2013-07-15T23:59:59.000Z

    Graphical abstract: - Highlights: • The persistent luminescence in Ba{sub 5}(PO{sub 4}){sub 3}Cl:Eu{sup 2+},R{sup 3+} was reported. • The influences of auxiliary codopants was discussed. • The concentration quenching of persistent luminescence was discussed. - Abstract: We investigated the persistent luminescence in europium-doped barium chloroapatite upon codoping with auxiliary rare earth ions. Luminescence properties of the phosphors, including photoluminescence, luminescence decay, and thermoluminescence are systematically studied. We formulated a model of persistent luminescence on the basis of the experimental results. In our model, some Eu{sup 2+} ions are oxidized to Eu{sup 3+} under short UV excitation, and the released electrons are trapped at the positive defect. The persistent luminescence arises from the recombination of these trapped electrons with the photo-ionized Eu{sup 3+} ions. The influence of auxiliary codopants was discussed in terms of ionic potential and ionic radius. Eventually, the concentration quenching of persistent luminescence was reported and discussed.

  15. Structural and luminescence studies on Eu{sup 3+}: B{sub 2}O{sub 3}-Li{sub 2}O-MO-LiF (M=Ba, Bi, Pb and Zn) glasses

    SciTech Connect (OSTI)

    Arunkumar, S.; Marimuthu, K. [Department of Physics, Gandhigram Rural Institute - Deemed University, Gandhigram - 624 302 (India)

    2012-06-05T23:59:59.000Z

    The present work reports structural and luminescence studies on 54B{sub 2}O{sub 3}+25Li{sub 2}O+15MO+ 5LiF+1Eu{sub 2}O{sub 3} (where M= Ba, Pb, Bi and Zn) glasses prepared by following melt quenching technique. The influence of the metal ions in the host matrix have been studied by measuring FTIR, absorption and luminescence spectra. The presence of the functional units in the prepared glasses have been explored through FTIR studies. The Judd-Ofelt (JO) intensity parameters have been determined from the luminescence spectra. The JO parameters have been used to calculate stimulated emission cross-section ({sigma}{sup E}{sub P}), branching ratios ({beta}{sub R}) and radiative lifetime ({tau}{sub R}) for the {sup 5}D{sub 0}{yields}{sup 7}F{sub J} (J= 1, 2, 3 and 4) transitions of the Eu{sup 3+} ions in the prepared glasses.

  16. Terahertz transmission of a Ba{sub 1{minus}{ital x}}K{sub {ital x}}BiO{sub 3} film probed by coherent time-domain spectroscopy

    SciTech Connect (OSTI)

    Gao, F.; Whitaker, J.F.; Liu, Y.; Uher, C. [Center for Ultrafast Optical Science, University of Michigan, Ann Arbor, Michigan 48109 (United States)] [Center for Ultrafast Optical Science, University of Michigan, Ann Arbor, Michigan 48109 (United States); Platt, C.E.; Klein, M.V. [Science and Technology Center for Superconductivity, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States)] [Science and Technology Center for Superconductivity, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States)

    1995-08-01T23:59:59.000Z

    The complex transmission coefficient for millimeter and submillimeter waves incident on a Ba{sub 0.6}K{sub 0.4}BiO{sub 3} thin film (82 nm) has been measured over a frequency range of 200--1200 GHz at temperatures above and below {ital T}{sub {ital c}} using coherent time-domain spectroscopy. We observe a dramatic change in both the magnitude and phase of the terahertz transmission in the superconducting state caused by a rapid carrier condensation. Both the real ({sigma}{sub 1}) and imaginary ({sigma}{sub 2}) parts of the complex conductivity are determined directly from the amplitude and phase of the transmitted electric field without the need for a Kramers-Kroenig analysis. By fitting {sigma}{sub 2} in the framework of BCS theory, a superconducting gap 2{Delta}(0)=6.9 meV=3.8{ital k}{sub {ital B}}{ital T}{sub {ital c}} is obtained. Below {ital T}{sub {ital c}}, the {sigma}{sub 1} is rapidly enhanced for {omega}/2{pi}{lt}500 GHz, which is attributed to the BCS coherence effects. However, the conductivity exhibits monotonic temperature dependence and no clear {sigma}{sub 1}({ital T}) peak is observed throughout the frequency range measured. The high-frequency penetration depth ({similar_to}600 nm) is also extracted and discussed. Our results are consistent with a picture of BCS moderate coupling superconductivity in an intermediate to dirty limit.

  17. Structural phase transition, narrow band gap, and room-temperature ferromagnetism in [KNbO{sub 3}]{sub 1?x}[BaNi{sub 1/2}Nb{sub 1/2}O{sub 3??}]{sub x} ferroelectrics

    SciTech Connect (OSTI)

    Zhou, Wenliang; Yang, Pingxiong, E-mail: pxyang@ee.ecnu.edu.cn; Chu, Junhao [Key Laboratory of Polar Materials and Devices, Ministry of Education, Department of Electronic Engineering, East China Normal University, Shanghai 200241 (China); Deng, Hongmei [Instrumental Analysis and Research Center, Institute of Materials, Shanghai University, 99 Shangda Road, Shanghai 200444 (China)

    2014-09-15T23:59:59.000Z

    Structural phase transition, narrow band gap (E{sub g}), and room-temperature ferromagnetism (RTFM) have been observed in the [KNbO{sub 3}]{sub 1?x}[BaNi{sub 1/2}Nb{sub 1/2}O{sub 3??}]{sub x} (KBNNO) ceramics. All the samples have single phase perovskite structure, but exhibit a gradual transition behaviour from the orthorhombic to a cubic structure with the increase of x. Raman spectroscopy analysis not only corroborates this doping-induced change in normal structure but also shows the local crystal symmetry for x ? 0.1 compositions to deviate from the idealized cubic perovskite structure. A possible mechanism for the observed specific changes in lattice structure is discussed. Moreover, it is noted that KBNNO with compositions x?=?0.1–0.3 have quite narrow E{sub g} of below 1.5?eV, much smaller than the 3.2?eV band gap of parent KNbO{sub 3} (KNO), which is due to the increasing Ni 3d electronic states within the gap of KNO. Furthermore, the KBNNO materials present RTFM near a tetragonal to cubic phase boundary. With increasing x from 0 to 0.3, the magnetism of the samples develops from diamagnetism to ferromagnetism and paramagnetism, originating from the ferromagnetic–antiferromagnetic competition. These results are helpful in the deeper understanding of phase transitions, band gap tunability, and magnetism variations in perovskite oxides and show the potential role, such materials can play, in perovskite solar cells and multiferroic applications.

  18. Phase stability study of Bi{sub 0.15}Sr{sub 0.85-x}Ae{sub x}CoO{sub 3-{delta}} (x = 0 and Ae = Ba{sub 0.28}; Ca{sub 0.17}) perovskites by in-situ neutron diffraction

    SciTech Connect (OSTI)

    Eriksson, A.K.; Eriksson, S.G. [Department of Environmental Inorganic Chemistry, Chalmers University of Technology, SE-412 96 Goeteborg (Sweden)] [Department of Environmental Inorganic Chemistry, Chalmers University of Technology, SE-412 96 Goeteborg (Sweden); Chapon, L.C. [STFC, Rutherford Appleton Lab, ISIS Facility, Didcot OX11 0 QX, Oxon (United Kingdom)] [STFC, Rutherford Appleton Lab, ISIS Facility, Didcot OX11 0 QX, Oxon (United Kingdom); Knee, C.S., E-mail: knee@chem.gu.se [Department of Chemistry, University of Gothenburg, SE-412 96 Goeteborg (Sweden)

    2010-12-15T23:59:59.000Z

    The oxygen deficient perovskites, Bi{sub 0.15}Sr{sub 0.85-x}Ae{sub x}CoO{sub 3-{delta}}, x = 0 and Ae{sub x} = Ba{sub 0.28}, Ca{sub 0.17}, were studied with in-situ neutron powder diffraction and combined TGA/DSC in order to investigate their behaviour at elevated temperatures in oxidising conditions. The phase stability of the I4/mmm supercell structure adopted by Bi{sub 0.15}Sr{sub 0.85}CoO{sub 3-{delta}} is shown to be dependent on temperature and the oxygen content of the phase, with three structural events, at T {approx} 250, 590 and 880 {sup o}C, detected. The first transition occurs as the perovskite supercell vanishes due to oxygen absorption; the second transition is also associated with oxidation and involves the decomposition of the perovskite phase via an exothermic process to yield a dominant hexagonal phase. Finally, at T {approx} 900 {sup o}C the perovskite phase re-forms. For the Ba and Ca containing materials the decomposition to the hexagonal phase occurs at T {approx} 600 {sup o}C and {approx} 650 {sup o}C respectively. The presence of Ca at the A-site is found to stabilise the I4/mmm supercell structure in the range RT - 650 {sup o}C. The antiferromagnetic to paramagnetic transitions occur at T{sub N} {approx} 250 {sup o}C, T{sub N} {approx} 175 {sup o}C and T{sub N} {approx} 145 {sup o}C for the samples with Ae{sub x} = Ba{sub 0.28}, x = 0 and Ae{sub x} = Ca{sub 0.17}, respectively.

  19. Microstructure, magnetic and electric properties of BaTiO{sub 3}–Ni{sub 0.5}Zn{sub 0.5}Fe{sub 1.5}Cr{sub 0.5}O{sub 4} nanocomposite

    SciTech Connect (OSTI)

    Mohamed, Mohamed Bakr, E-mail: mbm1977@yahoo.com [Physics Department, Faculty of Science, Ain Shams University, Cairo (Egypt); El-Sayed, Karimat [Physics Department, Faculty of Science, Ain Shams University, Cairo (Egypt)

    2013-05-15T23:59:59.000Z

    Highlights: ? BaTiO{sub 3}/Ni{sub 0.5}Zn{sub 0.5}Fe{sub 1.5}Cr{sub 0.5}O{sub 4} nanocomposites were synthesized by the sol–gel method. ? A large induced strain is induced in the composite. ? The ferroelectric phase transition dependence on the amount of ferrite. - Abstract: xBaTiO{sub 3} + (1 ? x)Ni{sub 0.5}Zn{sub 0.5}Fe{sub 1.5}Cr{sub 0.5}O{sub 4} (x = 0.35, 0.5, 0.65) nanocomposites were synthesized by the sol–gel method. The two corresponding intended nanocomposites phases were confirmed by X-ray diffraction, no other foreign phases were present. The microstrain of the nanocomposite was found to depend on the ratio amount of BaTiO{sub 3} (BTO) in the nanocomposites. The tetragonality ratio c/a of BTO approximates its values to be (a = c) at concentration of 65% BTO. Magnetic properties showed superparamgnetic behavior at room temperature. The temperature dependent of dielectric constant measurements showed that the Curie temperature (T{sub c}) of the ferroelectric phase transition varies with different composites ratio. The dielectric properties of the composite increased with increase of ferrite content. The compressed stress generated by the lattice mismatch of the in planes at the interface of the ferroelectric and magnetic phases cause large strain. The mediation of this strain causes strong electromagnetic coupling creating new materials with good quality.

  20. Crystal structure analysis of lead free Ba{sub 1-x}La{sub x}[Ti{sub 0.5}(Fe{sub 0.5}Nb{sub 0.5}){sub 0.5}]{sub 1-x/4}O{sub 3} Ceramics

    SciTech Connect (OSTI)

    Patel, Piyush Kumar; Rani, Jyoti; Yadav, K. L. [Smart Materials Research Laboratory, Department of Physics Indian Institute of Technology, Roorkee-247667 (India)

    2012-06-05T23:59:59.000Z

    Single phase Ba{sub 1-x}La{sub x}[Ti{sub 0.5}(Fe{sub 0.5}Nb{sub 0.5}){sub 0.5}]{sub 1-x/4}O{sub 3} [referred as BT-LFN]; x=0, 0.02, 0.04 and 0.06 ceramics have been synthesized by solid - state reaction process and were characterized by X-ray diffraction technique. The microstructure of the ceramics was examined by field emission-scanning electron microscopy (FE-SEM).

  1. A comparative study of SrO and BaO doping to CeO{sub 2}-ZrO{sub 2}: Characteristic and its catalytic performance for three-way catalysts

    SciTech Connect (OSTI)

    Guo, Jiaxiu, E-mail: guojiaxiu@scu.edu.cn [College of Architecture and Environment, Sichuan University, Chengdu 610065 (China) [College of Architecture and Environment, Sichuan University, Chengdu 610065 (China); National Engineering Research Center for Flue Gas Desulfurization, Chengdu 610065 (China); Shi, Zhonghua, E-mail: shizhonghua@scu.edu.cn [College of Chemistry, Sichuan University, Chengdu 610064 (China)] [College of Chemistry, Sichuan University, Chengdu 610064 (China); Wu, Dongdong [College of Chemistry, Sichuan University, Chengdu 610064 (China)] [College of Chemistry, Sichuan University, Chengdu 610064 (China); Yin, Huaqiang [College of Architecture and Environment, Sichuan University, Chengdu 610065 (China) [College of Architecture and Environment, Sichuan University, Chengdu 610065 (China); National Engineering Research Center for Flue Gas Desulfurization, Chengdu 610065 (China); Gong, Maochu [College of Chemistry, Sichuan University, Chengdu 610064 (China)] [College of Chemistry, Sichuan University, Chengdu 610064 (China); Chen, Yaoqiang [College of Chemistry, Sichuan University, Chengdu 610064 (China) [College of Chemistry, Sichuan University, Chengdu 610064 (China); National Engineering Research Center for Flue Gas Desulfurization, Chengdu 610065 (China)

    2013-02-15T23:59:59.000Z

    Graphical abstract: Display Omitted Highlights: ? The prepared materials have a face-centered cubic structure and nanosize particles. ?Comparing to CZB, aged CZS has 494 ?mol/g of OSC and 30 m{sup 2}/g of surface area. ? CZS and CZB have similar NO sorption and reductive properties and different H{sub 2} uptake. ? T{sub 50} of Pt-Rh/CZS/LA is as low as 199 °C for CO, 228 °C for NO, and 252 °C for C{sub 3}H{sub 8}. ? Pt-Rh/CZS/LA has wider working-window at 320 °C under different ? value. -- Abstract: Ceria-zirconia-strontia (Ce{sub 0.35}Zr{sub 0.55}Sr{sub 0.10}O{sub 1.9}) and ceria-zirconia-baria (Ce{sub 0.35}Zr{sub 0.55}Ba{sub 0.10}O{sub 1.9}) were synthesized using an oxidation-co-precipitation method with hydrogen peroxide (H{sub 2}O{sub 2}) as oxidant. The physical and chemical properties of the prepared materials were investigated using Brunauer–Emmett–Teller surface area characterization, transmission electron microscopy, X-ray diffraction, Raman spectra, X-ray photoelectron spectroscopy, and oxygen pulse reaction. The prepared materials were used in preparing three-way catalysts with low Pt and Rh content. Moreover, catalytic activities were evaluated at a fixed bed under a simulated gaseous mixture. The results are as follows: (1) the prepared materials have a face-centered cubic structure and are nano-sized; (2) aged Ce{sub 0.35}Zr{sub 0.55}Sr{sub 0.10}O{sub 1.9} has higher oxygen storage capacity (494 ?mol/g), better thermal stability (30 m{sup 2}/g), good low-temperature reducibility, and high hydrogen uptake after TPR-redox cycles; (3) the light-off temperature (T{sub 50}) of Pt-Rh/CZS/LA can be as low as 199 °C for CO, 228 °C for NO, and 252 °C for C{sub 3}H{sub 8}; and (4) Pt-Rh/CZS/LA has a fairly wide working-window.

  2. Appendix 8-Ba Revised October 2012

    E-Print Network [OSTI]

    Swaddle, John

    List Certification q YES q NO Progress Toward Degree: q YES q NO q N/A Date DateSports Medicine Medicine Department Medical Clearance: q YES q NO Date Cleared: ____________________________ Transfer General q Deg. Progress q Compliance Forms q Banner q Eligibility Center Distribution: q Original

  3. Appendix 8-Ba Revised July 2010

    E-Print Network [OSTI]

    Swaddle, John

    List Certification q YES q NO Progress Toward Degree: q YES q NO q N/A Date DateSports Medicine Medicine Department Medical Clearance: q YES q NO Date Cleared: ____________________________ Transfer General q Deg. Progress q Banner q Eligibility Center Distribution: q Original--Compliance File q Yellow

  4. BaBar: Searching for the Unexpected

    SciTech Connect (OSTI)

    Roodman, Aaron

    2006-04-24T23:59:59.000Z

    With over 300 million B-Bbar pairs delivered by the PEP-II B-factory, and over 200 publications, the Babar experiment has studied a very broad range of B, charm, tau, and QCD topics. In fact, the physics at Babar is so wide-ranging that it threatens to overwhelm any summary. Instead, in this colloquium I will focus on just a few topics selected for their potential to find a truly unexpected result. These include CP violation in rare B decays, leptonic B decays, and lepton-flavor violating tau decays. Each measurement, the currently predicted result, and the potential for uncovering the unexpected now and into the future, will be gently, but thoroughly, described.

  5. Bottomonium Results By BaBar

    SciTech Connect (OSTI)

    Tosi, Silvano; /Genoa U. /INFN, Genoa

    2012-04-03T23:59:59.000Z

    Summary: Observation of {eta}{sub b}; Energy scan above {Upsilon}(4S); Search for {Upsilon} {r_arrow} {gamma}A{sup 0}, A{sup 0} {r_arrow} invisible; Hadronic transitions {Upsilon}(4S) {r_arrow} {Upsilon}(nS).

  6. Disciplina: Anatomia Mdica I Cdigo: BA031

    E-Print Network [OSTI]

    Paraná, Universidade Federal do

    : Biologia Celular Código: BC016 Natureza: OBRIGATÓRIO ( X ) SEMESTRAL ( ) BIMESTRAL ( X) Número de Créditos celular, mitocôndrias, ciclo celular, núcleo interfásico, sistema de endomembranas, processos de síntese apoptose, alterações dos constituintes celulares e patologias associadas. Programa Prático: Introdução ao

  7. Futech BvBa | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating A PotentialJumpGermanFife EnergyFreightFulong WindFusermann Jump

  8. Behavior of vortices near twin boundaries in underdoped Ba(Fe 1 ? x Co x ) 2 As 2

    SciTech Connect (OSTI)

    Kalisky, B.; Kirtley, J. R.; Analytis, J. G.; Chu, J.-H.; Fisher, I. R.; Moler, K. A.

    2011-02-01T23:59:59.000Z

    We use scanning superconducting quantum interference device (SQUID) microscopy to investigate the behavior of vortices in the presence of twin boundaries in the pnictide superconductor Ba(Fe1-xCox)?As?. We show that the vortices avoid pinning on twin boundaries. Individual vortices move in a preferential way when manipulated with the SQUID: They tend to not cross a twin boundary, but rather to move parallel to it. This behavior can be explained by the observation of enhanced superfluid density on twin boundaries in Ba(Fe1-xCox)?As?. The observed repulsion from twin boundaries may be a mechanism for enhanced critical currents observed in twinned samples in pnictides and other superconductors.

  9. Measurements of Time-Dependent CP-Asymmetry Parameters in B Meson Decays to \\eta^{\\prime} K^0 and of Branching Fractions of SU(3) Related Modes with BaBar Experiment at SLAC

    SciTech Connect (OSTI)

    Biassoni, Pietro; /Milan U.

    2009-01-22T23:59:59.000Z

    In this thesis work we have measured the following upper limits at 90% of confidence level, for B meson decays (in units of 10{sup -6}), using a statistics of 465.0 x 10{sup 6} B{bar B} pairs: {Beta}(B{sup 0} {yields} {eta}K{sup 0}) < 1.6 {Beta}(B{sup 0} {yields} {eta}{eta}) < 1.4 {Beta}(B{sup 0} {yields} {eta}{prime}{eta}{prime}) < 2.1 {Beta}(B{sup 0} {yields} {eta}{phi}) < 0.52 {Beta}(B{sup 0} {yields} {eta}{omega}) < 1.6 {Beta}(B{sup 0} {yields} {eta}{prime}{phi}) < 1.2 {Beta}(B{sup 0} {yields} {eta}{prime}{omega}) < 1.7 We have no observation of any decay mode, statistical significance for our measurements is in the range 1.3-3.5 standard deviation. We have a 3.5{sigma} evidence for B {yields} {eta}{omega} and a 3.1 {sigma} evidence for B {yields} {eta}{prime}{omega}. The absence of observation of the B{sup 0} {yields} {eta}K{sup 0} open an issue related to the large difference compared to the charged mode B{sup +} {yields} {eta}K{sup +} branching fraction, which is measured to be 3.7 {+-} 0.4 {+-} 0.1 [118]. Our results represent substantial improvements of the previous ones [109, 110, 111] and are consistent with theoretical predictions. All these results were presented at Flavor Physics and CP Violation (FPCP) 2008 Conference, that took place in Taipei, Taiwan. They will be soon included into a paper to be submitted to Physical Review D. For time-dependent analysis, we have reconstructed 1820 {+-} 48 flavor-tagged B{sup 0} {yields} {eta}{prime}K{sup 0} events, using the final BABAR statistic of 467.4 x 10{sup 6} B{bar B} pairs. We use these events to measure the time-dependent asymmetry parameters S and C. We find S = 0.59 {+-} 0.08 {+-} 0.02, and C = -0.06 {+-} 0.06 {+-} 0.02. A non-zero value of C would represent a directly CP non-conserving component in B{sup 0} {yields} {eta}{prime}K{sup 0}, while S would be equal to sin2{beta} measured in B{sup 0} {yields} J/{psi}K{sub s}{sup 0} [108], a mixing-decay interference effect, provided the decay is dominated by amplitudes of a single weak phase. The new measured value of S can be considered in agreement with the expectations of the 'Standard Model', inside the experimental and theoretical uncertainties. Inconsistency of our result for S with CP conservation (S = 0) has a significance of 7.1 standard deviations (statistical and systematics included). Our result for the direct-CP violation parameter C is 0.9 standard deviations from zero (statistical and systematics included). Our results are in agreement with the previous ones [18]. Despite the statistics is only 20% larger than the one used in previous measurement, we improved of 20% the error on S and of 14% the error on C. This error is the smaller ever achieved, by both BABAR and Belle, in Time-Dependent CP Violation Parameters measurement is a b {yields} s transition.

  10. NAVY SPONSOR NOTIFICATION NAVPERS 1330/2 (2-73) SIN 0106-LF-063-7020

    E-Print Network [OSTI]

    Ginzel, Matthew

    -tie (males) Cold weather PT gear (watch cap, gloves, etc) 2 sets of PT gear Running shoes Admin: Register Coating Applications Research Laboratory A11 CDFS Child Development and Family Studies Building D8 CHAF

  11. Building KiMoSin : design requirements for kinetic interfaces in protein education

    E-Print Network [OSTI]

    Brown, Ashlie (Ashlie M.)

    2007-01-01T23:59:59.000Z

    Design guidelines for tools to enhance protein education are developed and applied to a prototype tool. A literature search and personal experience suggest kinetic, tangible models fill the current gaps in protein education. ...

  12. Luchando por Sus Derechos (Sin Tenerlos): Participacion Politica Informal en Wasco, California

    E-Print Network [OSTI]

    Michel-Dominguez, Vanessa

    2008-01-01T23:59:59.000Z

    informacion sobre Ia contaminacion ambiental debido al malasi como de Ia contaminacion de los mantos acuiferos por las

  13. Penas sin importancia y Tío Vania: Diálogo paródico entre Chejov y Gambaro

    E-Print Network [OSTI]

    Morell, Hortensia R.

    1997-10-01T23:59:59.000Z

    teatralmente con el tropo escénico romano del contaminatio, la contaminación o entrelace de un drama viejo y uno nuevo, tropo que Harold Bloom rescata para explicar el uso expreso de la influencia dentro del teatro contemporáneo. Bloom considera ese... entrelace como defensa de un autor con respecto a sus precursores (o rivales), o como una forma de su gozoso desprecio de las fuerzas literarias del pasado. Distingue la contaminación de la influencia en que aquélla es voluntaria, y la define como medida...

  14. a-sin films caused: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at Los Angeles, University of 19 Aerodynamic performance measurements of a film-cooled turbine stage MIT - DSpace Summary: The goal of this research is to measure the...

  15. Validation of the coupled Eta/SSiB model over South America Sin Chan Chou

    E-Print Network [OSTI]

    Xue, Yongkang

    the model and to investigate its biases and skill on the simulations of South American climate resolution and 38 vertical layers over the South American continent and part of the adjacent oceans. Analyses of the precipitation annual cycle observed in the central part of South America. The model was integrated continuously

  16. Luchando por Sus Derechos (Sin Tenerlos): Participacion Politica Informal en Wasco, California

    E-Print Network [OSTI]

    Michel-Dominguez, Vanessa

    2008-01-01T23:59:59.000Z

    el que se insertan, sumando Ia nueva experiencia politica asu formacion politica de origen. Estos cambios se generan enmanifiesta Ia partidpacion politica informal. Para entender

  17. Luchando por Sus Derechos (Sin Tenerlos): Participacion Politica Informal en Wasco, California

    E-Print Network [OSTI]

    Michel-Dominguez, Vanessa

    2008-01-01T23:59:59.000Z

    entiende derecho social, el derecho al bienestar economico yIa ciudadania social con el Estado de bienestar y Ia formaci

  18. Acta Mech Sin DOI 10.1007/s10409-010-0387-7

    E-Print Network [OSTI]

    Buehler, Markus J.

    amyloid fibrils Raffaella Paparcone · Steven Cranford · Markus J. Buehler Received: 12 July 2010 / Revised full atomistic simulations of A (1­40) amyloid fibrils to param- eterize a mesoscopic coarse-grained model, which is used to reproduce the elastic properties of amyloid fibrils. We then apply our

  19. Colusio?n sin evidencia directa en el Peru? ¿La sospecha basta?

    E-Print Network [OSTI]

    Defilippi, Enzo

    2012-01-01T23:59:59.000Z

    como lo señalaron Messer y Praxair durante el proceso, la3: Participación de Praxair en las compras de oxígeno de002-2008/CLC b. Que Praxair recibía de ESSALUD precios

  20. Predicting instabilities in gas-lifted wells simulation Laure Sin`egre, Nicolas Petit

    E-Print Network [OSTI]

    of instabilities occurring in practical applications of gas-lifted oil wells. The model underlying our analysis the drilling pipe (casing, point B) and the production pipe (tubing, point D) where it enters. Oil produced explained. The best identified instability is the "casing-heading". It consists of a succession of pressure

  1. Melt Processed Single Phase Hollandite Waste Forms For Nuclear Waste Immobilization: Ba{sub 1.0}Cs{sub 0.3}A{sub 2.3}Ti{sub 5.7}O{sub 16}; A = Cr, Fe, Al

    SciTech Connect (OSTI)

    Brinkman, Kyle [Savannah River National Laboratory, Aiken, SC 29808 (United States); Marra, James [Savannah River National Laboratory, Aiken, SC 29808 (United States); Amoroso, Jake [Savannah River National Laboratory, Aiken, SC 29808 (United States); Conradson, Steven D. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Tang, Ming [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2013-09-23T23:59:59.000Z

    Cs is one of the more problematic fission product radionuclides to immobilize due to its high volatility at elevated temperatures, ability to form water soluble compounds, and its mobility in many host materials. The hollandite structure is a promising crystalline host for Cs immobilization and has been traditionally fabricated by solid state sintering methods. This study presents the structure and performance of Ba{sub 1.0}Cs{sub 0.3}A{sub 2.3}Ti{sub 5.7}O{sub 16}; A = Cr, Fe, Al hollandite fabricated by melt processing. Melt processing is considered advantageous given that melters are currently in use for High Level Waste (HLW) vitrification in several countries. This work details the impact of Cr additions that were demonstrated to i) promote the formation of a Cs containing hollandite phase and ii) maintain the stability of the hollandite phase in reducing conditions anticipated for multiphase waste form processing.

  2. Direct evidence of correlations between relaxor behavior and polar nano-regions in relaxor ferroelectrics: A case study of lead-free piezoelectrics Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-x%BaTiO{sub 3}

    SciTech Connect (OSTI)

    Ge, Wenwei, E-mail: wenweige@gmail.com; Luo, Chengtao; Devreugd, Christopher P.; Li, Jiefang; Viehland, D. [Department of Materials Science and Engineering, Virginia Tech, Blacksburg, Virginia 24061 (United States)] [Department of Materials Science and Engineering, Virginia Tech, Blacksburg, Virginia 24061 (United States); Zhang, Qinhui; Luo, Haosu [Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800 (China)] [Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800 (China); Ren, Yang [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

    2013-12-09T23:59:59.000Z

    Diffuse scattering and relaxor behavior in Na{sub 0.5}Bi{sub 0.5}TiO{sub 3} (NBT) and NBT-5.6 at.?%BaTiO{sub 3} (NBT-5.6%BT) were investigated. X-ray diffraction revealed two types of diffuse scattering in NBT: (i) broad and (ii) asymmetric L-shaped. After modification with 5.6%BT, the broad diffuse scattering patterns became narrow, and the asymmetric L-shaped ones were replaced by symmetric ones. The symmetric diffuse scattering in NBT-5.6%BT disappeared with increasing dc electric field (E) for E???9.5?kV/cm where the frequency dispersion in the dielectric constant disappeared. These results demonstrate that the relaxor characteristics are directly correlated with the diffuse scattering and the presence polar nano-regions.

  3. Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K0.5Bi0.5TiO3-BaTiO3-Na0.5Bi0.5TiO3 piezoelectric materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maurya, Deepam; Zhou, Yuan; Wang, Yaojin; Yan, Yongke; Li, Jiefang; Viehland, Dwight; Priya, Shashank

    2015-02-26T23:59:59.000Z

    We synthesized grain-oriented lead-free piezoelectric materials in (K0.5Bi0.5TiO3-BaTiO3-Na0.5Bi0.5TiO3 (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (,0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d33 , 190pC/N) and high temperature stability (,1606C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-1806 domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectricmore »materials.« less

  4. Transverse shear deformation effects in composite laminated plates

    E-Print Network [OSTI]

    Coulter, Brett Ainsley

    1981-01-01T23:59:59.000Z

    , . . . . . . . . , . . . , . . . 42 'l 0 Nondimensionalized maximum mid-plane defiecticn fcE an anti- symmetric ang';e-ply laminate with angle 9; q=qosin (-x/a', sin3 (ny/b) and b/a = 1/3 . . . . . . . . . . . . . . . . . , . 43 Relative increase of mid-plane deflect', on from... CPT tc SDT for a [0/90]s laminate with o = qosin(mwx/a)sin(nwy/b) and b/a=1, where m and n are equal . . . . . . . . . . . . . . . . . . 45 12. Relative increase of mid-plane deflection from PT to SuT fcr a [0/90]s laminate with c = ccsin(mvx/a...

  5. Giant anelastic responses in (BaZrO -ZnO)-BaTiO

    E-Print Network [OSTI]

    Lakes, Roderic

    in the case of ceramic matrix composites which are usually synthesized via the solid-state reaction method. Porous interface and its brittleness nature are inevitable drawbacks for ceramic matrix composites, no experimental report is available (a)E-mail: lakes@engr.wisc.edu on ceramic matrix composites with negative

  6. Western gas sands project. Quarterly basin activities report, April 1-June 30, 1980

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    This report is a summary of drilling and testing operations in the four primary study areas of the WESP for this period. Greater Green River Basin, Northern Great Plains Province, Piceance Basin, and Uinta Basin. (DLC)

  7. Western Gas Sands Project. Quarterly basin activities report, January 1-March 31, 1980

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    This report is a summary of drilling and testing activities in the four primary study areas of the WGSP: Greater Green River Basin, Northern Great Plains Province, Uinta Basin, and Piceance Basin. (DLC)

  8. An analysis of lead-free (Bi{sub 0.5}Na{sub 0.5}){sub 0.915}-(Bi{sub 0.5}K{sub 0.5}){sub 0.05}Ba{sub 0.02}Sr{sub 0.015}TiO{sub 3} ceramic for efficient refrigeration and thermal energy harvesting

    SciTech Connect (OSTI)

    Vats, Gaurav; Vaish, Rahul, E-mail: rahul@iitmandi.ac.in [School of Engineering, Indian Institute of Technology Mandi, Himachal Pradesh 175 001 (India); Bowen, Chris R. [Department of Mechanical Engineering, Materials Research Centre, University of Bath, Bath BA2 7AY (United Kingdom)

    2014-01-07T23:59:59.000Z

    This article demonstrates the colossal energy harvesting capability of a lead-free (Bi{sub 0.5}Na{sub 0.5}){sub 0.915}-(Bi{sub 0.5}K{sub 0.5}){sub 0.05}Ba{sub 0.02}Sr{sub 0.015}TiO{sub 3} ceramic using the Olsen cycle. The maximum harvestable energy density estimated for this system is found to be 1523?J/L (1523?kJ/m{sup 3}) where the results are presented for extreme ambient conditions of 20–160?°C and electric fields of 0.1–4 MV/m. This estimated energy density is 1.7 times higher than the maximum reported to date for the lanthanum-doped lead zirconate titanate (thin film) system. Moreover, this study introduces a generalized and effective solid state refrigeration cycle in contrast to the ferroelectric Ericson refrigeration cycle. The cycle is based on a temperature induced polarization change on application of an unipolar electric field to ferroelectric ceramics.

  9. Effect of composition on electrical properties of lead-free Bi{sub 0.5}(Na{sub 0.80}K{sub 0.20}){sub 0.5}TiO{sub 3}-(Ba{sub 0.98}Nd{sub 0.02})TiO{sub 3} piezoelectric ceramics

    SciTech Connect (OSTI)

    Jaita, Pharatree [Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Watcharapasorn, Anucha; Jiansirisomboon, Sukanda [Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand)

    2013-07-14T23:59:59.000Z

    Lead-free piezoelectric ceramics with the composition of (1-x)Bi{sub 0.5}(Na{sub 0.80}K{sub 0.20}){sub 0.5}TiO{sub 3}-x(Ba{sub 0.98}Nd{sub 0.02})TiO{sub 3} or (1-x) BNKT-xBNdT (with x = 0-0.20 mol fraction) have been synthesized by a conventional mixed-oxide method. The compositional dependence of phase structure and electrical properties of the ceramics were systemically studied. The optimum sintering temperature of all BNKT-BNdT ceramics was found to be 1125 Degree-Sign C. X-ray diffraction pattern suggested that BNdT effectively diffused into BNKT lattice during sintering to form a solid solution with a perovskite structure. Scanning electron micrographs showed a slight reduction of grain size when BNdT was added. It was found that BNKT-0.10BNdT ceramic exhibited optimum electrical properties ({epsilon}{sub r} = 1716, tan{delta} = 0.0701, T{sub c} = 327 Degree-Sign C, and d{sub 33} = 211 pC/N), suggesting that this composition has a potential to be one of a promising lead-free piezoelectric candidate for dielectric and piezoelectric applications.

  10. High thermal stability of piezoelectric properties in (Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}){sub x}-(BaTiO{sub 3}){sub y}-(Na{sub 0.5}K{sub 0.5}NbO{sub 3}){sub 1-x-y} ceramics

    SciTech Connect (OSTI)

    Gupta, Shashaank; Priya, Shashank [Bio-Inspired Materials and Devices Laboratory (BMDL), Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States)] [Bio-Inspired Materials and Devices Laboratory (BMDL), Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2013-01-07T23:59:59.000Z

    We report the piezoelectric and ferroelectric properties of (Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}){sub x}-(BaTiO{sub 3}){sub y}-(Na{sub 0.5}K{sub 0.5}NbO{sub 3}){sub 1-x-y} ceramics for Na{sub 0.5}K{sub 0.5}NbO{sub 3} rich end of composition (x, y {<=} 0.04 mol. %). These compositions were found to exhibit significantly improved thermal stability of piezoresponse. Variation of dielectric constant as a function of temperature revealed that orthorhombic-tetragonal (T{sub o-t}) and tetragonal-cubic (T{sub c}) transition temperatures for these compositions were in the vicinity of 0 Degree-Sign C and 330 Degree-Sign C, respectively. Dynamic scaling and temperature dependent X-ray diffraction analysis were conducted. Results are discussed in terms of intrinsic and extrinsic contributions to the piezoelectric response explaining the temperature dependent behavior.

  11. Polar nanoregions and dielectric properties in high-strain lead-free 0.93(Bi{sub 1/2}Na{sub 1/2})TiO{sub 3}-0.07BaTiO{sub 3} piezoelectric single crystals

    SciTech Connect (OSTI)

    Chen, Cheng-Sao, E-mail: rickchen@cc.hwh.edu.tw [Department of Mechanical Engineering, Hwa-Hsia Institute of Technology, New Taipei City 23567, Taiwan (China); Chen, Pin-Yi [Department of Mechanical Engineering, Ming-Chi University of Technology, New Taipei City 24301, Taiwan (China); Tu, Chi-Shun [Graduate Institute of Applied Science and Engineering, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China)

    2014-01-07T23:59:59.000Z

    A structural coexistence of rhombohedral (R) and tetragonal (T) phases has been revealed in the (001){sub c}-cut lead-free 0.93(Bi{sub 1/2}Na{sub 1/2})TiO{sub 3}–0.07BaTiO{sub 3} (BNB7T) piezoelectric crystals, which grown by the self-flux method, in the lower temperatures by high-resolution synchrotron X-ray diffraction, reciprocal space mapping, and transmission electron microscopy. The dielectric permittivity exhibits a thermal hysteresis in the region of 120–260?°C, implying a first-order-like phase transition from R+T to T. The real part (??) of dielectric permittivity begins to deviates from the Curie-Weiss equation, ???=?C/(T ? T{sub o}), from the Burns temperature T{sub B}?=?460?°C, below which the polar nanoregions (or nanoclusters) develop and attenuate dielectric responses. The polar nanoregions of 5–10?nm were revealed by high-resolution transmission electron microscope. The normal piezoelectric coefficient d{sub 33} exhibits a rapid increase at E?=?15–20?kV/cm and reaches a maximum of d{sub 33} ?450 pC/N. The high piezoelectric response and E-field induced strain in BNB7T single crystals can be attributed to structural phase transitions under an E-field application.

  12. Council Document 2007-19August 2007 Sixth Annual Report to the Northwest Governors

    E-Print Network [OSTI]

    of the Bonneville Power Administration to Implement the Columbia River Basin Fish and Wildlife Program totalling $851.7 million to mitigate the impacts of hydropower dams on fish and wildlife of the Columbia and Conservation Council's Columbia River Ba- sin Fish and Wildlife Program. The remainder was money for which

  13. Weaver, P.P.E., Schmincke, H.-U., Firth, J.V., and Duffield, W. (Eds.), 1998 Proceedings of the Ocean Drilling Program, Scientific Results, Vol. 157

    E-Print Network [OSTI]

    a morphological barrier. The sedimentary ba- sin north of the Canary Islands extends ~200 km up to the Selvagem Islands, corresponding to the lateral extent of the moat because of the load of the Canary Islands (Watts interpreted in the light of results from Leg 157 (Sites 953 and 954). The shape of the submarine island flanks

  14. P3.17 DEVELOPMENT OF THE SECOND-GENERATION HYDROSPHERE-ATMOSPHERE RESEARCH MODEL (CHARM) FOR THE LAURENTIAN GREAT LAKES REGION

    E-Print Network [OSTI]

    , the prevailing wisdom remained that global warming leads to dropping lake levels. This pre- vailing wisdom, Michigan 1. INTRODUCTION* The question of what effect global warming might have on the amount of water to decreased net ba- sin water supply and lowered lake levels. More recently, Lofgren et al. (2002) carried out

  15. APPLIED AND ENVIRONMENTAL MICROBIOLOGY, Sept. 2003, p. 55035511 Vol. 69, No. 9 0099-2240/03/$08.00 0 DOI: 10.1128/AEM.69.9.55035511.2003

    E-Print Network [OSTI]

    Bennett, Philip

    aquifers, typically associated with geothermal regions and oil-field ba- sins, which play an important role on the phy- logeny of bacterial community 16S rRNA genes characterized filamentous microbial mats from libraries, most clones were affiliated with un- characterized environmental groups within the "Epsilonpro

  16. Simultaneous presence of (Si{sub 3}O{sub 10}){sup 8?} and (Si{sub 2}O{sub 7}){sup 6?} groups in new synthetic mixed sorosilicates: BaY{sub 4}(Si{sub 2}O{sub 7})(Si{sub 3}O{sub 10}) and isotypic compounds, studied by single-crystal X-ray diffraction, Raman spectroscopy and DFT calculations

    SciTech Connect (OSTI)

    Wierzbicka-Wieczorek, Maria, E-mail: maria.wierzbicka-wieczorek@uni-jena.de [Institut für Geowissenschaften, Friedrich-Schiller-Universität Jena, Carl-Zeiss-Promenade 10, D-07745 Jena (Germany); Többens, Daniel M. [Abteilung Kristallographie, Helmholtz-Zentrum Berlin, Hahn-Meitner-Platz 1, D-14109 Berlin (Germany); Kolitsch, Uwe [Mineralogisch-Petrographische Abt., Naturhistorisches Museum, Burgring 7, A-1010 Wien (Austria); Institut für Mineralogie und Kristallographie, Universität Wien, Geozentrum, Althanstraße 14, A-1090 Wien (Austria); Tillmanns, Ekkehart [Institut für Mineralogie und Kristallographie, Universität Wien, Geozentrum, Althanstraße 14, A-1090 Wien (Austria)

    2013-11-15T23:59:59.000Z

    Three new, isotypic silicate compounds, BaY{sub 4}(Si{sub 2}O{sub 7})(Si{sub 3}O{sub 10}), SrYb{sub 4}(Si{sub 2}O{sub 7})(Si{sub 3}O{sub 10}) and SrSc{sub 4}(Si{sub 2}O{sub 7})(Si{sub 3}O{sub 10}), were synthesized using high-temperature flux growth techniques, and their crystal structures were solved from single-crystal X-ray intensity data: monoclinic, P2{sub 1}/m, with a=5.532(1)/5.469(1)/5.278(1), b=19.734(4)/19.447(4)/19.221(4), c=6.868(1)/6.785(1)/6.562(1) Å, ?=106.53(3)/106.20(3)/106.50(3)°, V=718.8(2)/693.0(2)/638.3(2) Å{sup 3}, R(F)=0.0225/0.0204/0.0270, respectively. The topology of the novel structure type contains isolated horseshoe-shaped Si{sub 3}O{sub 10} groups (Si–Si–Si=93.15–95.98°), Si{sub 2}O{sub 7} groups (Si–O{sub bridge}–Si=180°, symmetry-restricted) and edge-sharing M(1)O{sub 6} and M(2)O{sub 6} octahedra. Single-crystal Raman spectra of the title compounds were measured and compared with Raman spectroscopic data of chemically and topologically related disilicates and trisilicates, including BaY{sub 2}(Si{sub 3}O{sub 10}) and SrY{sub 2}(Si{sub 3}O{sub 10}). The band assignments are supported by additional theoretical calculation of Raman vibrations by DFT methods. - Graphical abstract: View of BaY{sub 4}(Si{sub 2}O{sub 7})(Si{sub 3}O{sub 10}) along [100], showing zigzag chains and the tri- and disilicate groups. The unit cell is outlined. Display Omitted - Highlights: • We report a novel interesting crystal structure type for mixed sorosilicates containing Y, Yb, and Sc. • Synthesis of such mixed sorosilicates is possible by a high-temperature flux-growth technique. • Calculation of Raman vibrations by advanced DFT methods allows a considerably improved interpretation of measured Raman spectra.

  17. Neutron-Scattering Evidence for a Periodically Modulated Superconducting Phase in the Underdoped Cuprate La1.905Ba0.095CuO4

    SciTech Connect (OSTI)

    Xu, Zhijun [Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Mater Physics and Materials Science Dept.; Stock, C. [National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research; Chi, Songxue [National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research; Kolesnikov, A. I. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Div.; Xu, Guangyong I. [Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Mater Physics and Materials Science Dept.; Gu, Genda [Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Mater Physics and Materials Science Dept.; Tranquada, J. M. [Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Mater Physics and Materials Science Dept.

    2014-10-01T23:59:59.000Z

    The role of antiferromagnetic spin correlations in high-temperature superconductors remains a matter of debate. We present inelastic neutron-scattering evidence that gapless spin fluctuations coexist with superconductivity in La1.905Ba0.095CuO4. Furthermore, we observe that both the low-energy magnetic spectral weight and the spin incommensurability are enhanced with the onset of superconducting correlations. We propose that the coexistence occurs through intertwining of spatial modulations of the pair wave function and the antiferromagnetic correlations. This proposal is also directly relevant to sufficiently underdoped La2-xSrxCuO4 and YBa2Cu3O6+x.

  18. Me3SiN3 -Me Me Me,SiCI (Si-C1 insertion) path A

    E-Print Network [OSTI]

    Zare, Richard N.

    . Roark, and L. H. Sommer, J. Organomst. Chem., 66, 29 (1974); (e) C. M. Golino, R. D. Bush, and L. H. Sommer, J. Am. Chem. SOC.,96, 614 (1974); (f) L. H. Sommer and J. McLick, J. Or- ganomet. Chem., 101, 171 (1975); (g) R. D.Bush, C. M. Golino, 0 . D. Homer, and L. H. Sommer, bid., 80, 37 (1974); (h) P

  19. Love, Purification, and Forgiveness versus Justice, Punishment, and Satisfaction: The Debates on Purgatory and the Forgiveness of Sins

    E-Print Network [OSTI]

    Lasenby, Joan

    ' the Greeks to accept their doctrines.5 However, the refusal of Mark Eugenicus, Metropolitan of Ephesus,6

  20. Currents and waters at 140 cl t-¹ sin the western equatorial Atlantic during February-March-April

    E-Print Network [OSTI]

    Kelly, Francis Joseph

    1978-01-01T23:59:59.000Z

    CURRENTS AND WATERS AT 140 CI, T IN THE WESTERN EQUATORIAL ATLANTIC DURING FEBRUARY-MARCH-APRIL A Thesis by FRANCIS JOSEPH KELLY, JR. Submitted to the Graduate College of Texas ARM Univers ity in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE May 1978 Major Subject: Oceanography CURRENTS AND WATERS AT 140 CL T IN TIRE WESTER EQUATORIAL ATLANTIC DURING FEBRUARY-MARCH-APRIL A Thesis by FRANCIS JOSEPH KELLY, JR. Approved as to style and content by: Chairman o...

  1. A Real-Time Database Testbed and Performance Evaluation Kyoung-Don Kang, Phillip H. Sin, and Jisu Oh

    E-Print Network [OSTI]

    Kang, Kyoung-Don

    in a timely fashion using a large number of tem- poral data, e.g., current stock prices or traffic sensor@cs.virginia.edu Abstract A lot of real-time database (RTDB) research has been done to process transactions in a timely fashion using fresh data reflecting the current real world status. However, most existing RTDB work

  2. A Real-Time Database Testbed and Performance Evaluation Kyoung-Don Kang, Phillip H. Sin, and Jisu Oh

    E-Print Network [OSTI]

    Son, Sang H.

    ) are required to process trans- actions in a timely fashion using a large number of tem- poral data, e@cs.virginia.edu Abstract A lot of real-time database (RTDB) research has been done to process transactions in a timely fashion using fresh data reflecting the current real world sta- tus. However, most existing RTDB work

  3. A review of "Women, Madness and Sin in Early Modern England: The Autobiographical Writings of Dionys Fitzherbert" by Katherine Hodgkin

    E-Print Network [OSTI]

    Wells, Marion A.

    2011-01-01T23:59:59.000Z

    and howlers were removed. is comparison convinced me that Passion and Persuasion received no serious editing from the press before publication. Despite all the hard work that clearly went into this dissertation, Passion and Persuasion does not, alas..., contribute to our understanding of Dryden. e readings are either obvious or unoriginal (or, in a few instances, strained). But Skouen?s method does not allow for her to satisfy her dissertation committee and to break new ground. Skouen has re...

  4. Currents and waters at 140 cl t-¹ sin the western equatorial Atlantic during February-March-April 

    E-Print Network [OSTI]

    Kelly, Francis Joseph

    1978-01-01T23:59:59.000Z

    CURRENTS AND WATERS AT 140 CI, T IN THE WESTERN EQUATORIAL ATLANTIC DURING FEBRUARY-MARCH-APRIL A Thesis by FRANCIS JOSEPH KELLY, JR. Submitted to the Graduate College of Texas ARM Univers ity in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE May 1978 Major Subject: Oceanography CURRENTS AND WATERS AT 140 CL T IN TIRE WESTER EQUATORIAL ATLANTIC DURING FEBRUARY-MARCH-APRIL A Thesis by FRANCIS JOSEPH KELLY, JR. Approved as to style and content by: Chairman o...

  5. Sin Sacrificio No Hay Recompensa: Apoyo as (Im)migrant Parental Engagement in Farmworking Families of the California Central Valley

    E-Print Network [OSTI]

    Nava, Pedro Enrique

    2012-01-01T23:59:59.000Z

    for Petroleos Mexicanos (PEMEX). He would only go as far asemployment working for PEMEX, Mexican Petroleum, a state

  6. Thermal stability and in situ SiN passivation of InAlN/GaN high electron mobility heterostructures

    SciTech Connect (OSTI)

    Lugani, L.; Carlin, J.-F.; Py, M. A.; Grandjean, N. [ICMP, École Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne (Switzerland)

    2014-09-15T23:59:59.000Z

    We investigate the thermal stability of nearly lattice-matched InAlN layers under metal organic vapor phase epitaxy conditions for temperatures >800?°C and show that they are not fully stable. In particular, InAlN top layers undergo degradation during high temperature annealing due to a surface related process, which causes the loss of crystal quality. This strongly impacts the transport properties of InAlN/GaN HEMT heterostructures; in particular, the mobility is significantly reduced. However, we demonstrate that high thermal stability can be achieved by capping with a GaN layer as thin as 0.5?nm. Those findings enabled us to realize in situ passivated HEMT heterostructures with state of the art transport properties.

  7. Studies of Charmonium-Like States at BaBar

    SciTech Connect (OSTI)

    Mokhtar, Arafat Gabareen; /SLAC

    2012-04-09T23:59:59.000Z

    Several charmonium-like states above D{bar D} threshold have been discovered at the Belle and BABAR B-factories. Some of these states are produced via Initial State Radiation (e.g. Y(4260) and Y(4350)), and some are observed in B-meson decays (e.g. X(3872), and Y(3940)). The Belle observations of the enhancements in the {Psi}(2S){pi}{sup -} and {chi}{sub cl}{pi}{sup -}, i.e. the Z(4430){sup -}, Z{sub 1}(4050){sup -}, and Z{sub 2}(4250){sup -}, have generated a great deal of interest, because such states must have minimum quark content (c{bar c}d{bar u}), i.e. these are four-quark states. The BABAR Collaboration does not confirm the existence of the Z(4430){sup -}.

  8. BaBar Note 323 Temperature Monitoring and Interlocks

    E-Print Network [OSTI]

    supplies. #12;Contents 1 Introduction 3 1.1 HDI Thermal Characteristics in order to verify normal operation of the front-end electronics and its cooling system, to track thermal estimates for this project. 1.1 HDI Thermal Characteristics The SVT cooling system is described in Reference

  9. Appendix 5-Ba 12-Passenger Van Operators Checklist

    E-Print Network [OSTI]

    Swaddle, John

    as a maximum load. 2. Wear seat belts/shoulder harnesses as provided in the vehicle. 3. Drivers of College vehicles are required to operate vehicles in a safe manner and to obey all State laws. In many states, the use of a handheld cell phone while driving a vehicle is prohibited by State law except for emergency

  10. Shape Your Future BaSed on Your

    E-Print Network [OSTI]

    , Georgia and Kyrgyzstan. Some intriguing research projects that our students have worked on include: n

  11. Ann D. Cohen BA, University of Texas at Austin, 2000

    E-Print Network [OSTI]

    Sibille, Etienne

    or DA content in the striatum was observed in animals pretreated with GDNF. These data suggest that GDNF

  12. MAJOR TO CAREER GUIDE B.A. Mathematics

    E-Print Network [OSTI]

    Walker, Lawrence R.

    is being used in science and engineering in unprecedented ways: to plan the path of a robot arm, to model

  13. Impact Analysis: VTO Baseline and Scenario (BaSce) Activities

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    technology areas Component- level attributes Drivetrainsvehicle classes AEO2013 High Oil Price fuel prices, H 2 price from FCTO (no price elasticity) Little public...

  14. MAJOR REQUIREMENTS FOR A BA DEGREE IN SOCIAL WORK

    E-Print Network [OSTI]

    Hardy, Christopher R.

    204 GOVT 112 PSYC 100 SOCY 210 3.0 ____ ____ 3.0 ____ ____ 3.0 ____ ____ 3.0.0 credits) 3.0 ____ ____ 3.0 ____ ____ 3.0 ____ ____ 3.0 ____ ____ 3.0 ____ ____ 3.0 ____ ____ 3.0 ____ ____ 3.0 ____ ____ 3.0 ____ ____ 3.0 ____ ____ 3.0 ____

  15. BA in PHILOSOPHY (555320) MAP Sheet Department of Philosophy

    E-Print Network [OSTI]

    Olsen Jr., Dan R.

    to graduate #Classes 2 1 1 1­2 1 1 1 1 1 2 1 1 1­2 1­2 1 3­4 Variable Hours 4.0 2.0 2.0 3­6.0 3.0 3.0 3.0 3.0 3.0 6.0 3.0 3.0 3­5.0 3­7.0 3.0 6.0 Variable 30.0 120.0 Classes Rel A 121/H and 122/H Rel A 211/H Phil 414R Philosophy of Art, Architecture, Music, and Film Phil 416 Philosophy of Law 3.0 3.0 3.0 3.0 3.0

  16. Rare Decays And Exotic States With BaBar

    SciTech Connect (OSTI)

    Robertson, S.H.; /McGill U.

    2006-08-28T23:59:59.000Z

    Results from the BABAR experiment are presented for searches for several rare FCNC B and D meson decays, including the modes B{sup 0} {yields} {ell}{sup +}{ell}{sup -} and D{sup 0} {yields} {ell}{sup +}{ell}{sup -}, B {yields} ({rho},{omega}){gamma} and B{sup +} {yields} (K,{pi}){sup +}{nu}{bar {nu}}. Limits on lepton flavor violation in neutrino-less {tau} decays are also discussed. Finally, results of BABAR searches for the strange pentaquark states {Theta}{sup +}(1540), {Xi}{sup --}(1860) and {Xi}{sup 0}(1860) are summarized.

  17. Electroweak Penguin and Leptonic Decays at BaBar

    SciTech Connect (OSTI)

    Bucci, F.; /Pisa U. /INFN, Pisa

    2005-08-26T23:59:59.000Z

    Recent BABAR results on electroweak penguin and leptonic decays are reviewed. In particular, the measurements of B {yields} K{sup (*)}l{sup +}l{sup -} and the preliminary results on B {yields} X{sub s}l{sup +}l{sup -} are presented. Also summarized are the preliminary limits on B{sup +} {yields} l{sup +}{nu} (l = e,{mu}) and B{sup +} {yields} K{sup +}{nu}{bar {nu}}.

  18. Charm and Charmonium Spectroscopy in BaBar

    SciTech Connect (OSTI)

    Negrini, M.; /Ferrara U.

    2008-02-06T23:59:59.000Z

    The BABAR experiment at the PEP-II B-factory offers excellent opportunities in charm and charmonium spectroscopy. The recent observation of new states in the D{sub s} and in the charmonium mass regions revived the interest in this field. Recent BABAR results are presented.

  19. Electromagnetic Application: X-RAY Alawi H. Ba-Surrah

    E-Print Network [OSTI]

    Masoudi, Husain M.

    , Pulyui published high-quality x-ray images in journals in Paris and London. · Nikola Tesla In April 1887, Nikola Tesla began to investigate X-rays using high voltages and tubes of his own design, as well. The principle behind Tesla's device is called the Bremsstrahlung process, in which a high-energy secondary X

  20. Grid Application for the BaBar Experiment

    SciTech Connect (OSTI)

    Khan, A.; /Brunel U.; Wilson, F.; /Rutherford

    2006-08-14T23:59:59.000Z

    This paper discusses the use of e-Science Grid in providing computational resources for modern international High Energy Physics (HEP) experiments. We investigate the suitability of the current generation of Grid software to provide the necessary resources to perform large-scale simulation of the experiment and analysis of data in the context of multinational collaboration.

  1. CURRICULUM WORKSHEET HS_ELED_BA EDUCATION-ELEMENTARY

    E-Print Network [OSTI]

    Rhode Island, University of

    of semester or summer- Pass PLT & PRAXIS II & ML PRAXIS exam before sem. 3 in program. EDC 402 (3) EDC 452 (2

  2. A A S BA IMPORTANT ISSUES W BOOK TWO O

    Office of Environmental Management (EM)

    that have been specifically configured for processing heavy crude largely from Latin America that would be impacted in the event of a disruption of foreign crude supplies....

  3. BaBrI:Eu2 + , a new bright scintillator

    E-Print Network [OSTI]

    Bourret-Courchesne, E.D.

    2010-01-01T23:59:59.000Z

    of  a  divalent  europium  5d-­4f  transition.   F igureto   the   divalent   europium   5d-­4f   broadband  

  4. Microsoft Word - 2008 NTS BA final.doc

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronic Input Options Gary L. Hirsch Project Lead SAMSBIOLOGICAL ASSESSMENT FOR

  5. The analysis of Ytrium doped BaZrO3

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not FoundInformation DOEInformation Summary Big*The EffectiveTitle: Enhanced

  6. Conceptual Frame Work of an Enhanced BPA BA (EBBA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power Administration would like submitCollector/Receiver Characterization We use a variety !

  7. ba1d MASTER Inside Cover Volume 2 Cover Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsingWhatY-12ZeroVariations ofSeniorAugustVolume 1:Volume

  8. Gabriele Simi1 BaBar SVT: Radiation Damage and BaBar SVT: Radiation Damage and

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    Fiber cones (on B1 magnets) · 1200 Atom chips · 140K readout channels · 0.3 million micro bonds #12 Bonding Module Construction Pisa HDFA Bonding Module Construction UCSB Ribs,Endpieces UCSB Ribs

  9. Data:2fa483de-dace-46ba-a515-da25ba853cdc | Open Energy Information

    Open Energy Info (EERE)

    and delivery charges. Adjustment is power supply cost recovery factor and energy optimization surcharge. kWh << Previous 1 2 3 Next >> Category:Categories Retrieved...

  10. Chestnut Chocolate Torte Though sinfully rich, the torte is not overly sweet. It can be made in stages: the cake one

    E-Print Network [OSTI]

    Ulmer, Melville P.

    boiler; heat until chocolate is melted. [Watch consistency of mix if use canned puree, may be too running for dipping] Dip chestnut decorations in chocolate to coat half way. Put on wax paper until set. Set aside into dry ingredients. Beat 1 minute. Beat egg whites, cream of tartar, and salt until soft peaks form

  11. Center for Watershed Sciences | groundwaternitrate.ucdavis.edu | University of California, Davis Niveles mximos de concentracin de nitrato sin tratar reportado en sistemas pblicos comunitarios

    E-Print Network [OSTI]

    Pasternack, Gregory B.

    en el Valle de Salinas. Alrededor de 2.6 millones de personas en estas regiones dependen de las aguas Valle de Salinas de California, cuya agua potable se encuentra actualmente en peligro de estar en la cuenca del Lago Tulare y los mantos acuíferos del Valle de Salinas. La mayoría del nitrato que

  12. Distributed Scalable Network Association in Wireless Sensor Networks Hyung-Sin Kim, Jin-Seok Han, Jae-Seok Bang, and Yong-Hwan Lee

    E-Print Network [OSTI]

    Bahk, Saewoong

    @snu.ac.kr Abstract--Wireless sensor networks (WSNs) need to employ a network association mechanism that can securely centralized and broadcasting based network association mechanisms may consume large energy, and distributed of the proposed scheme is evaluated by computer simulation, showing remarkable performance improvement over

  13. STM images showing the morphology of BaO film (7 MLleft and 80 MLright) formed by the direct evaporation of the BaO.

    E-Print Network [OSTI]

    2008 EMSL Lead Investigator: Igor Lyubinetsky Microscopy Group, EMSL, PNNL Co-investigators: Yingge Du important in heterogeneous catalysis, metal oxides are widely used as both a support and an active catalyst oxide material. #12;It is essential to evaluate the fundamental structural issues of the growth mode

  14. Data:20b2a59f-4c34-4ba5-ad82-4c47a4797ba9 | Open Energy Information

    Open Energy Info (EERE)

    Information 2. Demand 3. Energy << Previous 1 2 3 Next >> Basic Information Utility name: Tri-County Elec Member Corp Effective date: 20081001 End date if known: Rate name:...

  15. Data:Ba7584ba-523d-40da-a2d1-dad7d115f4de | Open Energy Information

    Open Energy Info (EERE)

    primary voltage facilities beyond the Point of Delivery except meters, instrument transformers and their related wiring. Demand Charge (7 a.m. to 10 p.m., Daily, Excluding...

  16. Data:2ba424b9-6ef3-4c96-ba45-c8709ca36cb9 | Open Energy Information

    Open Energy Info (EERE)

    date: 20130506 End date if known: Rate name: Rate SE - Mercury Vapor 175 W - Aspen Sector: Lighting Description: Applicable to municipal, county, state and federal...

  17. Data:C90755a1-17ba-4b9a-b0ba-e4671517a041 | Open Energy Information

    Open Energy Info (EERE)

    and through one point of delivery. Source or reference: http:www.cmpco.comYourHomepricingpricingSchedulesdefault.html Source Parent: Comments Applicability Demand (kW)...

  18. Page 1 | B.A. in Software and Information Systems | Academic Plan of Study Updated May 2014 B.A. in Software and Information Systems

    E-Print Network [OSTI]

    Raja, Anita

    at least 2.5, accumulation of at least 12 credit hours at UNC Charlotte, completion of ITIS 1212/L or ITCS): Advising holds in effect each semester. Advising required each semester. Assigned advisors available Education W/O Course Notes Fall Semester ITIS 1600 Computing Professionals 1 ITCS 1212+L Introduction

  19. Aminopeptidase activities of Bacillus subtilis and Bacillus licheniformis

    E-Print Network [OSTI]

    Liu, Justin Sing

    1969-01-01T23:59:59.000Z

    AMINOPEPTIOASE ACTIVI1'1ES 0 BACILLNS SUBTILIS AND BA TI, LOS LICNLNIFORMIS A The, is Justin Sin- Liu Suhrnitted to the Oraduate Colleoe. of Texas AU' 'Jn'ver. ity in Partial fulfillteent of , . he requirement for the degree ot MASTER... OF SCIENCE May I. BS Major Su'ojen: Bio"henist y AMINOPEPTIDASE ACTIVITIES OF BACILLUS SUBTILIS AND BACILLUS LICHENIFOP'(IS A Thesis by Justin Sing Liu Approved as to style and content by: (Chairman cf Comsittee) r/ Head of Department) (Member...

  20. Cs-Ba ultrahigh-temperature solar TEC commutation element optimization

    SciTech Connect (OSTI)

    Ender, A.J.; Kuznetsov, V.I.; Babanin, B.I. [Ioffe Physico-Technical Institute, Polytekhnicheskaya St. 26, St. Petersburg, (Russia) 194021; Ogloblin, B.G.; Klimov, A.V.; Kirillov, E.J. [Central Design Bureau of Machine Building, Krasnogvardeyskaya Square 3, St. Petersburg, (Russia) 195272

    1996-03-01T23:59:59.000Z

    Theoretically studied is a problem involving the optimization of high-temperature thermionic energy converters (TEC) taking into account electrical and thermal losses in a metal jumper connecting at series TEC commutation the emitter of one diode with the collector of the other. It is shown that for emitter temperature of 2600 K at optimal selection of jumper dimensions the difference between an ideal conversion efficiency and actual converter efficiency amounts to about 4{percent}. {copyright} {ital 1996 American Institute of Physics.}