National Library of Energy BETA

Sample records for axis 3 2

  1. Charge-screening role of c-axis atomic displacements in YBa2Cu3O6+x and related superconductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    E. S. Bozin; Huq, A.; Shen, Bing; Claus, H.; Kwok, W. K.; Tranquada, J. M.

    2016-02-29

    Here, the importance of charge reservoir layers for supplying holes to the CuO2 planes of cuprate superconductors has long been recognized. Less attention has been paid to the screening of the charge transfer by the intervening ionic layers. We address this issue in the case of YBa2Cu3O6+x, where CuO chains supply the holes for the planes. We present a simple dielectric-screening model that gives a linear correlation between the relative displacements of ions along the c axis, determined by neutron powder diffraction, and the hole density of the planes. Applying this model to the temperature-dependent shifts of ions along themore » c axis, we infer a charge transfer of 5–10% of the hole density from the planes to the chains on warming from the superconducting transition to room temperature. Given the significant coupling of c-axis displacements to the average charge density, we point out the relevance of local displacements for screening charge modulations and note recent evidence for dynamic screening of in-plane quasiparticles. This line of argument leads us to a simple model for atomic displacements and charge modulation that is consistent with images from scanning-tunneling microscopy for underdoped Bi2Sr2CaCu2O8+δ.« less

  2. Axis-1 diode simulations I: standard 2-inch cathode

    SciTech Connect (OSTI)

    Ekdahl, Carl [Los Alamos National Laboratory

    2011-01-11

    The standard configuration of the DARHT Axis-I diode features a 5.08-cm diameter velvet emitter mounted in the flat surface of the cathode shroud. The surface of the velvet is slightly recessed {approx}2.5 mm. This configuration produces a 1.75 kA beam when a 3.8-MV pulse is applied to the anode-cathode (AK) gap. This note addresses some of the physics of this diode through the use of finite-element simulations.

  3. Vertical Axis Wind Turbine

    Energy Science and Technology Software Center (OSTI)

    2002-04-01

    Blade fatigue life is an important element in determining the economic viability of the Vertical-Axis Wind Turbine (VAWT). VAWT-SAL Vertical Axis Wind Turbine- Stochastic Aerodynamic Loads Ver 3.2 numerically simulates the stochastic (random0 aerodynamic loads of the Vertical-Axis Wind Turbine (VAWT) created by the atomspheric turbulence. The program takes into account the rotor geometry, operating conditions, and assumed turbulence properties.

  4. Effect of strain along C-axis NbS{sub 2}

    SciTech Connect (OSTI)

    Singh, Tapender Kumar, Jagdish Sastri, O. S. K. S.

    2015-05-15

    We have studied electronic properties of double layered hexagonal structure of the Niobium Di-Sulphide (2H-NbS{sub 2}) superconductor for various strains introduced along the c-axis using ab-initio calculations. The DFT calculations based on Full Potential Linearized Augmented Plane Wave (FPLAPW) method are performed using the ELK code. The total energy curve (E vs a), Density of States (DOS) and the Band structure calculations obtained in this work are matching with the earlier reports. The Pressure-Volume (P-V) diagram for 2H-NbS{sub 2} was obtained using the Equation of State(EOS) calculations, which provides the relationship between the pressure and strain applied along the c-axis. The band structures for various strains ranging from 0 percent to 10 percent along c-axis in steps of 2 percent are obtained. We note that there are increasing number of bands crossing over the Fermi energy level with increase in strain. Thus, we conclude that with increasing strain along c-axis, number of conduction bands crossing the E{sub F} increases, which gives rise to more conduction states and hence higher conductivity.

  5. Dual axis radiographic hydrodynamic test facility. Final environmental impact statement, Volume 2: Public comments and responses

    SciTech Connect (OSTI)

    1995-08-01

    On May 12, 1995, the U.S. Department of Energy (DOE) issued the draft Dual Axis Radiographic Hydrodynamic Test Facility Environmental Impact Statement (DARHT EIS) for review by the State of New Mexico, Indian Tribes, local governments, other Federal agencies, and the general public. DOE invited comments on the accuracy and adequacy of the draft EIS and any other matters pertaining to their environmental reviews. The formal comment period ran for 45 days, to June 26, 1995, although DOE indicated that late comments would be considered to the extent possible. As part of the public comment process, DOE held two public hearings in Los Alamos and Santa Fe, New Mexico, on May 31 and June 1, 1995. In addition, DOE made the draft classified supplement to the DARHT EIS available for review by appropriately cleared individuals with a need to know the classified information. Reviewers of the classified material included the State of New Mexico, the U.S. Environmental Protection Agency, the Department of Defense, and certain Indian Tribes. Volume 2 of the final DARHT EIS contains three chapters. Chapter 1 includes a collective summary of the comments received and DOE`s response. Chapter 2 contains the full text of the public comments on the draft DARHT EIS received by DOE. Chapter 3 contains DOE`s responses to the public comments and an indication as to how the comments were considered in the final EIS.

  6. LayTracks3D: A new approach for meshing general solids using medial axis transform

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Quadros, William Roshan

    2015-08-22

    This study presents an extension of the all-quad meshing algorithm called LayTracks to generate high quality hex-dominant meshes of general solids. LayTracks3D uses the mapping between the Medial Axis (MA) and the boundary of the 3D domain to decompose complex 3D domains into simpler domains called Tracks. Tracks in 3D have no branches and are symmetric, non-intersecting, orthogonal to the boundary, and the shortest path from the MA to the boundary. These properties of tracks result in desired meshes with near cube shape elements at the boundary, structured mesh along the boundary normal with any irregular nodes restricted to themore » MA, and sharp boundary feature preservation. The algorithm has been tested on a few industrial CAD models and hex-dominant meshes are shown in the Results section. Work is underway to extend LayTracks3D to generate all-hex meshes.« less

  7. Four Pulse Drive System for the Beam Induction Cells for DARHT Axis 2

    SciTech Connect (OSTI)

    Downing, J.; Carlson, R.; Melton, J.; Fockler, J.

    1999-06-28

    The proposed drive system allows for the generation of up to four (4) high-quality radiographic pulses along one line-of-sight, having arbitrary pulse spacing ({approximately}500 ns), using demonstrated technologies. This concept uses a four-pulse drive system to drive both a 16-MeV ensemble of 250-kV, 4-kA induction cells and a four-pulse, 4-MeV injector. The key to this approach lies in the method used to combine four pulses from different generators in a manner that does not compromise the voltage flatness requirement of {+-} 1%. The induction cells use core material for only a single pulse. A simple reverse bias circuit is used to reset the cores between pulses, and the insulator has been redesigned to withstand the reverse reset voltage. This approach can be installed in stages so that the facility can be used for dual axis radiography while implementing the multi-pulsing capability. A dual double-pulse format has been identified which provides a sequence of two pulses along one line-of-sight within a 2-{micro}sec window. The 2-{micro}sec windows can be separated by arbitrary time intervals of 2- to 10-{micro}sec.

  8. Beamline 3.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.3.2 Print General x-ray testing station GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 4-20 keV Monochromator...

  9. Beamline 3.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.3.2 Print General x-ray testing station GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 4-20 keV Monochromator Si(111) Endstations Hutch with 2 x 3 ft optical table Calculated spot size at sample Up to 30 x 10 mm Sample format Mount off optical table Sample environment Ambient, air Scientific disciplines Applied science Scientific applications Semiconductor characterization Spokesperson This e-mail address is being protected

  10. Beamline 3.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.3.2 Print General x-ray testing station GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 4-20 keV Monochromator Si(111) Endstations Hutch with 2 x 3 ft optical table Calculated spot size at sample Up to 30 x 10 mm Sample format Mount off optical table Sample environment Ambient, air Scientific disciplines Applied science Scientific applications Semiconductor characterization Spokesperson This e-mail address is being protected

  11. Beamline 3.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.3.2 Print General x-ray testing station GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 4-20 keV Monochromator Si(111) Endstations Hutch with 2 x 3 ft optical table Calculated spot size at sample Up to 30 x 10 mm Sample format Mount off optical table Sample environment Ambient, air Scientific disciplines Applied science Scientific applications Semiconductor characterization Spokesperson This e-mail address is being protected

  12. MHK ISDB/Instruments/AXYS 3 Metre Buoy | Open Energy Information

    Open Energy Info (EERE)

    Velocity Planar Measurement (Current), 3D Velocity Volumetric Measurement (Current), Density (Ice), Direction (Ice), Speed (Ice), Thickness (Ice), Pressure (Tidal), Sea Surface...

  13. Epitaxial YBa{sub 2}Cu{sub 3}O{sub 7{minus}{delta}}/Sr{sub 2}RuO{sub 4} heterostructures

    SciTech Connect (OSTI)

    Schlom, D.G.; Merritt, B.A.; Madhavan, S. [Pennsylvania State Univ., University Park, PA (United States). Dept. of Materials Science and Engineering] [and others

    1997-09-01

    The anisotropic oxide superconductors YBa{sub 2}Cu{sub 3}O{sub 7{minus}{delta}} and Sr{sub 2}RuO{sub 4} have been epitaxially combined in various ways (c-axis on c-axis, c-axis on a-axis, and a-axis on a-axis) though the use of appropriate substrates. Phase-pure a-axis oriented or c-axis oriented epitaxial Sr{sub 2}RuO{sub 4} films were grown by pulsed laser deposition. YBa{sub 2}Cu{sub 3}O{sub 7{minus}{delta}} films were then grown on both orientations of Sr{sub 2}RuO{sub 4} films and the resulting epitaxy was characterized.

  14. Effect of mechanical deformation on the evolution of c-axis texture of Bi{sub 1.6}Pb{sub 0.4}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub z} superconductor HIP cladded on Ag substrate

    SciTech Connect (OSTI)

    Yoo, J.M.; Mukherjee, K.

    1994-12-31

    The c-axis texture evolution of 2223 BSCCO superconductor has been studied by x-ray polefigure method, using ``popLA`` software package, which can elucidate the evolution of texture associated with mechanical processing of BSCCO compound. The specimens were fabricated on Ag substrate by a HIP cladding technique to induce randomly oriented state as the starting material, and to investigate the role of non (001) grain during deformation. As the amount of cold rolling reduction (%) increased, a tighter clustering of the (00{und 14}) poles around the surface normal, indicated that randomly oriented c-axes` grains from initial HIP cladded surface rotated towards the normal direction. In addition (105), (109), and (110) experimental polefigure studies indicated that under deformation, those plane normals tend to form a fiber texture around the compression direction of rolling (normal direction). After achieving certain degrees of texturing, saturation due to textural hardening was also observed. Detailed texture analysis, along with inverse polefigure, and microstructure analysis are reported.

  15. Epitaxial c-axis oriented BaTiO{sub 3} thin films on SrTiO{sub 3}-buffered Si(001) by atomic layer deposition

    SciTech Connect (OSTI)

    Ngo, Thong Q.; McDaniel, Martin D.; Ekerdt, John G., E-mail: ekerdt@che.utexas.edu [Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States); Posadas, Agham B.; Demkov, Alexander A. [Department of Physics, The University of Texas at Austin, Austin, Texas 78712 (United States); Hu, Chengqing; Yu, Edward T. [Department of Electrical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States); Bruley, John [IBM Research Division, Yorktown Heights, New York 10593 (United States)

    2014-02-24

    Atomic layer deposition (ALD) of epitaxial c-axis oriented BaTiO{sub 3} (BTO) on Si(001) using a thin (1.6?nm) buffer layer of SrTiO{sub 3} (STO) grown by molecular beam epitaxy is reported. The ALD growth of crystalline BTO films at 225??C used barium bis(triisopropylcyclopentadienyl), titanium tetraisopropoxide, and water as co-reactants. X-ray diffraction (XRD) reveals a high degree of crystallinity and c-axis orientation of as-deposited BTO films. Crystallinity is improved after vacuum annealing at 600??C. Two-dimensional XRD confirms the tetragonal structure and orientation of 720-nm thick films. The effect of the annealing process on the BTO structure is discussed. A clean STO/Si interface is found using in-situ X-ray photoelectron spectroscopy and confirmed by cross-sectional scanning transmission electron microscopy. The capacitance-voltage characteristics of 720?nm-thick BTO films are examined and show an effective dielectric constant of ?660 for the heterostructure.

  16. L .~$;2-3

    Office of Legacy Management (LM)

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  17. SU-E-T-623: Delivery of 3D Conformal Proton-Therapy Fields at Extended Source- To-Axis Distances

    SciTech Connect (OSTI)

    Kryck, E; Slopsema, R

    2014-06-15

    Purpose: To evaluate the dosimetric properties of proton dose distributions delivered at extended source-to-skin distances (SSD). Methods: Radiation was delivered with a gantry-mounted proton double scattering system (Proteus 230, IBA). This system has a maximum field diameter of 24 cm at isocenter and a nominal source-to-axis distance of 230 cm. Dose was measured at nominal SSD as well as at -10, +10, +25, +50, +75, and +100 cm for several range and modulation width combinations. Depth dose distributions were measured with a multi-layer ionization chamber (MLIC), and lateral dose distributions with a 2D ionization chamber array as well as with a diode in a water phantom. Results: The maximum field diameter was found to increase from 24.0 cm at nominal SSD to 29.1 cm and 33.3 cm at +50 cm and +100 cm respectively. Field flatness remained below 3% for all SSD. Tilt in the spread-out Bragg peak depth dose distribution increased with SSD up to 0.4 %-per-g/cm2 at +100 cm. The measured range decreased with 1.1x10-3 g/cm2 per centimeter shift in SSD due to proton energy loss in air, very close to the theoretically calculated value of 1.06x10-3 g/cm3. The output and dose rate decrease with the inverse of the SSD squared as expected. Conclusion: Extending the SSD up to 100 cm increases the maximum field diameter from 24.0 cm to 33.3 cm while the dose uniformity remains acceptable.

  18. table3.2

    Gasoline and Diesel Fuel Update (EIA)

    ... NAICS Code(a) Subsector and Industry Total Net Electricity(b... RSE Row Factors Table 3.2 Fuel Consumption, 2002; Level: ... of Energy Markets and End Use, Energy Consumption ...

  19. BEAMLINE 2-3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-3 CURRENT STATUS: Open SUPPORTED TECHNIQUES: X-ray absorption spectroscopy imaging MAIN SCIENTIFIC DISCIPLINES: Biology / Materials / Chemistry / Environmental % TIME GENERAL USE: 100% SCHEDULING: Proposal Submittal and Scheduling Procedures Current SPEAR and Beam Line Schedules SOURCE: 1.3 Tesla Bend Magnet BEAM LINE SPECIFICATIONS: energy range resolution DE/E spot size flux angular acceptance unfocused 4500-24000 eV ~5 x 10-4 2 x 2 microns ~1010 0.75 mrad OPTICS: Kirkpatrick-Baez system

  20. Fibroblast growth factor-2 up-regulates the expression of nestin through the RasRafERKSp1 signaling axis in C6 glioma cells

    SciTech Connect (OSTI)

    Chang, Kai-Wei; Huang, Yuan-Li; Wong, Zong-Ruei; Su, Peng-Han; Huang, Bu-Miin; Ju, Tsai-Kai; Technology Commons, College of Life Science, National Taiwan University, Taipei 106, Taiwan ; Yang, Hsi-Yuan

    2013-05-17

    Highlights: Nestin expression in C6 glioma cells is induced by FGF-2. Nestin expression is induced by FGF-2 via de novo RNA and protein synthesis. The FGFR inhibitor SU5402 blocks the FGF-2-induced nestin expression. The mRNA of FGFR1 and 3 are detected in C6 glioma cells. RasRafERKSp1 signaling pathway is responsibe for FGF-2-induced nestin expression. -- Abstract: Nestin is a 240-kDa intermediate filament protein expressed mainly in neural and myogenic stem cells. Although a substantial number of studies have focused on the expression of nestin during development of the central nervous system, little is known about the factors that induce and regulate its expression. Fibroblast growth factor-2 (FGF-2) is an effective mitogen and stimulates the proliferation and differentiation of a subset of nestin-expressing cells, including neural progenitor cells, glial precursor cells, and smooth muscle cells. To assess whether FGF-2 is a potent factor that induces the expression of nestin, C6 glioma cells were used. The results showed that nestin expression was up-regulated by FGF-2 via de novo RNA and protein synthesis. Our RT-PCR results showed that C6 glioma cells express FGFR1/3, and FGFRs is required for FGF-2-induced nestin expression. Further signaling analysis also revealed that FGF-2-induced nestin expression is mediated through FGFRMAPKERK signaling axis and the transcriptional factor Sp1. These findings provide new insight into the regulation of nestin in glial system and enable the further studies on the function of nestin in glial cells.

  1. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure...

  2. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2.2 Beamline 5.3.2.2 Print Tuesday, 20 October 2009 08:37 Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized

  3. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 5.3.2.2 Beamline 5.3.2.2 Print Tuesday, 20 October 2009 08:37 Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active

  4. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 5.3.2.2 Beamline 5.3.2.2 Print Tuesday, 20 October 2009 08:37 Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active

  5. Dual Axis Radiographic Hydrodynamic Test Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DARHT DARHT Facility: A critical component of stockpile stewardship A new research frontier awaits! Our door is open and we thrive on mutually beneficial partnerships, collaborations that drive innovations and new technologies. April 12, 2012 Dominic Tafoya and Dave Honaberger prepare a refurbished DARHT (Dual Axis Radiographic Hydrotest Facility) 2nd axis accelerator cell for magnetic axis alignment measurements. Contact Group Leader Terry Priestley (505) 665-1330 Email Deputy Group Leader Tim

  6. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8.3.2 Print Tuesday, 20 October 2009 08:56 Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological...

  7. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION...

  8. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8.3.2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE...

  9. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.3.2 Beamline 12.3.2 Print Tuesday, 20 October 2009 09:34 Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000

  10. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5.3.2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25

  11. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5.3.2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25

  12. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 5.3.2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample

  13. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25 nm

  14. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 5.3.2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample

  15. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 5.3.2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample

  16. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 5.3.2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample

  17. Three axis velocity probe system

    DOE Patents [OSTI]

    Fasching, George E.; Smith, Jr., Nelson S.; Utt, Carroll E.

    1992-01-01

    A three-axis velocity probe system for determining three-axis positional velocities of small particles in fluidized bed systems and similar applications. This system has a sensor head containing four closely-spaced sensing electrodes of small wires that have flat ends to establish a two axis plane, e.g. a X-Y plane. Two of the sensing electrodes are positioned along one of the axes and the other two are along the second axis. These four sensing electrodes are surrounded by a guard electrode, and the outer surface is a ground electrode and support member for the sensing head. The electrodes are excited by, for example, sinusoidal voltage having a peak-to-peak voltage of up to 500 volts at a frequency of 2 MHz. Capacitive currents flowing between the four sensing electrodes and the ground electrode are influenced by the presence and position of a particle passing the sensing head. Any changes in these currents due to the particle are amplified and synchronously detected to produce positional signal values that are converted to digital form. Using these digital forms and two values of time permit generation of values of the three components of the particle vector and thus the total velocity vector.

  18. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25 nm

  19. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25 nm

  20. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25 nm

  1. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25 nm

  2. Beamline 5.3.2.2

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    2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25 nm

  3. Beamline 5.3.2.2

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    2.2 Print Polymer Scanning Transmission X-Ray Microscopy (STXM) @ 5.3.2.2 GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 250-780 eV Monochromator Low-dispersion, spherical-grating monochromator, one grating Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25 nm

  4. Beamline 12.3.2

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    2 Beamline 12.3.2 Print Tuesday, 20 October 2009 09:34 Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors

  5. Beamline 10.3.2

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    3.2 Beamline 10.3.2 Print Tuesday, 20 October 2009 09:15 Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7

  6. Beamline 12.3.2

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    3.2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  7. Beamline 8.3.2

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    2 Beamline 8.3.2 Print Tuesday, 20 October 2009 08:56 Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft

  8. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Beamline 11.3.2 Print Tuesday, 20 October 2009 09:23 Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5

  9. Beamline 8.3.2

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    3.2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft optical table in hutch for radiography and

  10. Beamline 8.3.2

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    3.2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft optical table in hutch for radiography and

  11. Beamline 8.3.2

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    3.2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft optical table in hutch for radiography and

  12. Beamline 10.3.2

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    0.3.2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE)

  13. Beamline 10.3.2

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    0.3.2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE)

  14. Beamline 10.3.2

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    10.3.2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE)

  15. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.3.2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE)

  16. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE) 7000

  17. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  18. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  19. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  20. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  1. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  2. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  3. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  4. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  5. Q2 Q3 Season Q2 Q3 Season Q2 Q3 Season

    U.S. Energy Information Administration (EIA) Indexed Site

    Q2 Q3 Season Q2 Q3 Season Q2 Q3 Season Nominal Prices (dollars per gallon) WTI Crude Oil (Spot) a 1.38 1.11 1.24 1.08 1.06 1.07 -21.4 -4.5 -13.7 Brent Crude Oil Price (Spot) 1.47 1.20 1.33 1.08 1.08 1.08 -26.1 -10.2 -18.8 U.S. Refiner Average Crude Oil Cost 1.37 1.14 1.25 1.00 1.03 1.02 -26.6 -8.8 -18.5 Wholesale Gasoline Price b 2.01 1.84 1.93 1.58 1.46 1.52 -21.6 -20.6 -21.1 Wholesale Diesel Fuel Price b 1.89 1.61 1.75 1.41 1.43 1.42 -25.4 -11.4 -18.8 Regular Gasoline Retail Price c 2.67 2.60

  6. Beamline 3.2.1

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    2.1 Print Commercial deep-etch x-ray lithography (LIGA) GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 3-12 keV Monochromator None Endstations Hutch with automated scanner Calculated spot size at sample 100 x 10 mm Sample format 3- and 4-in. wafer format; x-ray mask and LIGA substrate Sample environment Ambient, air Scientific disciplines Applied science Scientific applications Deep-etch x-ray lithography (LIGA) Spokesperson

  7. Beamline 3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.1 Print Commercial deep-etch x-ray lithography (LIGA) GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 3-12 keV Monochromator None Endstations Hutch with automated scanner Calculated spot size at sample 100 x 10 mm Sample format 3- and 4-in. wafer format; x-ray mask and LIGA substrate Sample environment Ambient, air Scientific disciplines Applied science Scientific applications Deep-etch x-ray lithography (LIGA) Spokesperson

  8. Beamline 3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.1 Print Commercial deep-etch x-ray lithography (LIGA) GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 3-12 keV Monochromator None Endstations Hutch with automated scanner Calculated spot size at sample 100 x 10 mm Sample format 3- and 4-in. wafer format; x-ray mask and LIGA substrate Sample environment Ambient, air Scientific disciplines Applied science Scientific applications Deep-etch x-ray lithography (LIGA) Spokesperson

  9. Beamline 3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.1 Print Commercial deep-etch x-ray lithography (LIGA) GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 3-12 keV Monochromator None Endstations Hutch with automated scanner Calculated spot size at sample 100 x 10 mm Sample format 3- and 4-in. wafer format; x-ray mask and LIGA substrate Sample environment Ambient, air Scientific disciplines Applied science Scientific applications Deep-etch x-ray lithography (LIGA) Spokesperson

  10. Beamline 3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.1 Print Commercial deep-etch x-ray lithography (LIGA) GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 3-12 keV Monochromator None Endstations Hutch with automated scanner Calculated spot size at sample 100 x 10 mm Sample format 3- and 4-in. wafer format; x-ray mask and LIGA substrate Sample environment Ambient, air Scientific disciplines Applied science Scientific applications Deep-etch x-ray lithography (LIGA) Spokesperson

  11. Beamline 3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.1 Print Commercial deep-etch x-ray lithography (LIGA) GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 3-12 keV Monochromator None Endstations Hutch with automated scanner Calculated spot size at sample 100 x 10 mm Sample format 3- and 4-in. wafer format; x-ray mask and LIGA substrate Sample environment Ambient, air Scientific disciplines Applied science Scientific applications Deep-etch x-ray lithography (LIGA) Spokesperson

  12. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 6.3.2 Print EUV Calibrations Scientific discipline: Applied sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Bend magnet Energy range 25-1300 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) <7,000 Endstations Reflectometer Characteristics 2-circle goniometer with x, y, z, q movement of sample Spatial resolution Can position to 10 µm, 0.01° Detectors Photodiode, channeltron Spot size at

  13. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 6.3.2 Print EUV Calibrations Scientific discipline: Applied sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Bend magnet Energy range 25-1300 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) <7,000 Endstations Reflectometer Characteristics 2-circle goniometer with x, y, z, q movement of sample Spatial resolution Can position to 10 µm, 0.01° Detectors Photodiode, channeltron Spot size at

  14. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 6.3.2 Print EUV Calibrations Scientific discipline: Applied sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Bend magnet Energy range 25-1300 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) <7,000 Endstations Reflectometer Characteristics 2-circle goniometer with x, y, z, q movement of sample Spatial resolution Can position to 10 µm, 0.01° Detectors Photodiode, channeltron Spot size at

  15. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 6.3.2 Print EUV Calibrations Scientific discipline: Applied sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Bend magnet Energy range 25-1300 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) <7,000 Endstations Reflectometer Characteristics 2-circle goniometer with x, y, z, q movement of sample Spatial resolution Can position to 10 µm, 0.01° Detectors Photodiode, channeltron Spot size at

  16. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft optical table in hutch for radiography and

  17. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft optical table in hutch for radiography and

  18. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft optical table in hutch for radiography and

  19. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft optical table in hutch for radiography and

  20. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft optical table in hutch for radiography and

  1. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft optical table in hutch for radiography and

  2. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (1.9 GeV, 4.37 tesla) Energy range 6-46 keV ML mode Monochromator None or two ML or two Si(111) Flux (1.9 GeV, 500 mA) ~105hv/sec/µm2 in ML mode Resolving power (E/ΔE) White beam/ 1% / 0.02% Endstation 12 x 3 ft optical table in hutch for radiography and

  3. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  4. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  5. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  6. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  7. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  8. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  9. Vertical axis wind turbines

    DOE Patents [OSTI]

    Krivcov, Vladimir; Krivospitski, Vladimir; Maksimov, Vasili; Halstead, Richard; Grahov, Jurij

    2011-03-08

    A vertical axis wind turbine is described. The wind turbine can include a top ring, a middle ring and a lower ring, wherein a plurality of vertical airfoils are disposed between the rings. For example, three vertical airfoils can be attached between the upper ring and the middle ring. In addition, three more vertical airfoils can be attached between the lower ring and the middle ring. When wind contacts the vertically arranged airfoils the rings begin to spin. By connecting the rings to a center pole which spins an alternator, electricity can be generated from wind.

  10. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.3.2 Print Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5 microns Spatial resolution 60 nm Sample format

  11. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.3.2 Print Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5 microns Spatial resolution 60 nm Sample format

  12. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.3.2 Print Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5 microns Spatial resolution 60 nm Sample format

  13. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.3.2 Print Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5 microns Spatial resolution 60 nm Sample format

  14. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.3.2 Print Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5 microns Spatial resolution 60 nm Sample format

  15. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.3.2 Print Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5 microns Spatial resolution 60 nm Sample format

  16. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.3.2 Print Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5 microns Spatial resolution 60 nm Sample format

  17. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.3.2 Print Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5 microns Spatial resolution 60 nm Sample format

  18. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.3.2 Print Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5 microns Spatial resolution 60 nm Sample format

  19. Beamline 11.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.3.2 Print Inspection of EUV lithography masks GENERAL BEAMLINE INFORMATION Operational Yes, but not open to users Source characteristics Bend magnet Energy range 50-1000 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) 7000 Endstations The SEMATECH Berkeley Actinic Inspection Tool Detector 2048 x 2048 EUV CCD Characteristics 900-1000x zoneplate microscope Spot size at sample 1-5 microns Spatial resolution 60 nm Sample format

  20. One-Axis Trackers -- Improved Reliability, Durability, Performance, and Cost Reduction; Final Subcontract Technical Status Report, 2 May 2006 - 31 August 2007

    SciTech Connect (OSTI)

    Shingleton, J.

    2008-02-01

    The overall objective of this subcontract is to reduce the total cost of electricity generated by single-axis tracking solar energy systems for utility and other large-scale commercial applications by improving performance and reliability and by reducing installation time, cost, and environmental impact.

  1. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure...

  2. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION...

  3. mol2.3.dvi

    Office of Scientific and Technical Information (OSTI)

    Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA 2 Department of Chemistry, University of California, Berkeley, California 94720, USA (Dated: Phys. Rev. ...

  4. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic,...

  5. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print EUV Calibrations Scientific discipline: Applied sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Bend magnet Energy range 25-1300 eV...

  6. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE) 7000

  7. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE) 7000

  8. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE) 7000

  9. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE) 7000

  10. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE) 7000

  11. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE) 7000

  12. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE) 7000

  13. Beamline 10.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Environmental and Materials Science, Micro X-Ray Absorption Spectroscopy (µXAS, µEXAFS) Scientific disciplines: Earth and environmental science, material science GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet (beamline optics collect 0.166 horizontal mrad) Energy range 2.5-17 keV Monochromator Monochromatic, with Si(111) two-crystal, constant-exit monochromator Measured flux 9 x 109 photons/s into 16 x 7 µm2 spot at 6 keV Resolving power (E/ΔE) 7000

  14. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (EE) <7,000 Endstations Reflectometer Characteristics 2-circle goniometer with x, y, z, q movement of sample Spatial resolution Can position to 10 m, 0.01 Detectors...

  15. 1-2-3 - Economic Indicators.123

    National Nuclear Security Administration (NNSA)

    Airline Passengers December 2009 3,097,382 3,234,705 3,164,313 -4.2% -2.1% Gaming Revenue December 2009 753,169,630 750,798,061 771,800,158 0.3% -2.4% Visitor Volume (all...

  16. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print EUV Calibrations Scientific discipline: Applied sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Bend magnet Energy range 25-1300 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) <7,000 Endstations Reflectometer Characteristics 2-circle goniometer with x, y, z, q movement of sample Spatial resolution Can position to 10 µm, 0.01° Detectors Photodiode, channeltron Spot size at sample 300 µm

  17. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print EUV Calibrations Scientific discipline: Applied sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Bend magnet Energy range 25-1300 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) <7,000 Endstations Reflectometer Characteristics 2-circle goniometer with x, y, z, q movement of sample Spatial resolution Can position to 10 µm, 0.01° Detectors Photodiode, channeltron Spot size at sample 300 µm

  18. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print EUV Calibrations Scientific discipline: Applied sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Bend magnet Energy range 25-1300 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) <7,000 Endstations Reflectometer Characteristics 2-circle goniometer with x, y, z, q movement of sample Spatial resolution Can position to 10 µm, 0.01° Detectors Photodiode, channeltron Spot size at sample 300 µm

  19. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print EUV Calibrations Scientific discipline: Applied sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Bend magnet Energy range 25-1300 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) <7,000 Endstations Reflectometer Characteristics 2-circle goniometer with x, y, z, q movement of sample Spatial resolution Can position to 10 µm, 0.01° Detectors Photodiode, channeltron Spot size at sample 300 µm

  20. Beamline 6.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print EUV Calibrations Scientific discipline: Applied sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Bend magnet Energy range 25-1300 eV Monochromator VLS-PGM Calculated flux (1.9 GeV, 400 mA) 1011 photons/s/0.01%BW at 100 eV Resolving power (E/ΔE) <7,000 Endstations Reflectometer Characteristics 2-circle goniometer with x, y, z, q movement of sample Spatial resolution Can position to 10 µm, 0.01° Detectors Photodiode, channeltron Spot size at sample 300 µm

  1. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  2. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  3. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  4. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  5. Beamline 9.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Chemical and Materials Scientific disciplines: Surfaces, interfaces, catalysis, environmental science, material science, electrochemistry Endstations: Ambient pressure X-ray Photoelectron Spectroscopy (APXPS)* Ambient pressure photoemission GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 30-850 eV Monochromator SGM (gratings: 100, 600 lines/mm) Calculated flux (1.9 GeV, 400 mA) up to 1.5 x 1011 photons/sec, energy dependent Resolving power

  6. CESP Tool 2.3: Stakeholder Agenda

    Broader source: Energy.gov [DOE]

    Tool 2.3: Stakeholder Agenda from Step 2: Identify and Engage Stakeholders of the Guide to Community Energy Strategic Planning.

  7. Measurement of the 3s1/2-3p3/2 resonance line of sodiumlike Eu52+

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Trbert, E.; Beiersdorfer, P.; Hell, N.; Brown, G. V.

    2015-08-20

    We have measured the 3s1/2-3p3/2 transition in sodiumlike Eu52+ situated at 41.232 with an uncertainty of 73 ppm. Our measurement extends previous high-precision measurements into the 561/2-3p3/2 and 3p1/2-3d3/2 transitions in the neighboring magnesiumlike, aluminumlike, and siliconlike europium ions.

  8. Superconductivity in semimetallic Bi3O2S3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, L.; Parker, D.; Babkevich, P.; Yang, L.; Ronnow, H. M.; Sefat, A. S.

    2015-03-12

    We report in this paper a further investigation on the thermodynamic and transport properties, and an assessment of theoretical calculations, for the BiS2-layered Bi3O2S3 superconductor. The polycrystalline sample is synthesized with a superconducting transition temperature of Tconset=5.75K and Tczero=4.03K (≈Tcmag) that drops to 3.3 K by applying a hydrostatic pressure of 6 kbar. Density-of-states (DOS) calculations give substantial hybridization between Bi, O, and S, with Bi the largest component of DOS, which supports the idea that the BiS2 layer is relevant for producing electron-phonon coupling. An analysis of previously published specific heat data for Bi3O2S3 is additionally suggestive of amore » strong electron-phonon interaction in the Bi-O-S system. The analysis of the Seebeck coefficient results strongly suggests that Bi3O2S3 is a semimetal. In fact, we found the semimetallic or narrow band gap behavior may occur in certain other materials in the BiS2-layered class of materials, such as Bi4O4S3.« less

  9. Vertical axis wind turbine airfoil

    DOE Patents [OSTI]

    Krivcov, Vladimir; Krivospitski, Vladimir; Maksimov, Vasili; Halstead, Richard; Grahov, Jurij Vasiljevich

    2012-12-18

    A vertical axis wind turbine airfoil is described. The wind turbine airfoil can include a leading edge, a trailing edge, an upper curved surface, a lower curved surface, and a centerline running between the upper surface and the lower surface and from the leading edge to the trailing edge. The airfoil can be configured so that the distance between the centerline and the upper surface is the same as the distance between the centerline and the lower surface at all points along the length of the airfoil. A plurality of such airfoils can be included in a vertical axis wind turbine. These airfoils can be vertically disposed and can rotate about a vertical axis.

  10. Two-axis angular effector

    DOE Patents [OSTI]

    Vaughn, Mark R.; Robinett, III, Rush D.; Phelan, John R.; Van Zuiden, Don M.

    1997-01-21

    A new class of coplanar two-axis angular effectors. These effectors combine a two-axis rotational joint analogous to a Cardan joint with linear actuators in a manner to produce a wider range of rotational motion about both axes defined by the joint. This new class of effectors also allows design of robotic manipulators having very high strength and efficiency. These effectors are particularly suited for remote operation in unknown surroundings, because of their extraordinary versatility. An immediate application is to the problems which arise in nuclear waste remediation.

  11. Table 3.2 Fuel Consumption, 2010;

    Gasoline and Diesel Fuel Update (EIA)

    2 Fuel Consumption, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: ... Next MECS will be fielded in 2015 Table 3.2 Fuel Consumption, 2010; Level: National and ...

  12. Influence of the Torsion Angle in 3,3'-Dimethyl-2,2'-bipyridine...

    Office of Scientific and Technical Information (OSTI)

    Title: Influence of the Torsion Angle in 3,3'-Dimethyl-2,2'-bipyridine on the Intermediate Valence of Yb in (C5Me5)2 Yb(3,3'-Me2-bipy) The synthesis and X-ray crystal structures of ...

  13. Measurement of the 3s1/2-3p3/2 resonance line of sodiumlike Eu52+

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Träbert, E.; Beiersdorfer, P.; Hell, N.; Brown, G. V.

    2015-08-20

    We have measured the 3s1/2-3p3/2 transition in sodiumlike Eu52+ situated at 41.232 Å with an uncertainty of 73 ppm. Our measurement extends previous high-precision measurements into the 56< Z< 78 range of atomic numbers. We also present measurements of 3s1/2-3p3/2 and 3p1/2-3d3/2 transitions in the neighboring magnesiumlike, aluminumlike, and siliconlike europium ions.

  14. AcqGuide3pt2.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chapter 3.2 (March 2004) Antitrust Teaming Arrangements [Reference: FAR 3.3, 9.6; DEAR 903.3; DCAA Contract Audit Manual Vol. 1, Section 4-705; FTC/DOJ Antitrust Guidelines for Collaborations Among Competitors (April 2000)] Overview This section provides guidance that is in use Government-wide to assist the Department's Contracting Officers in identifying whether certain contractor teaming arrangements may unduly restrict competition. Although no specific situations within the Department have

  15. A two-dimensional matrix correction for off-axis portal dose prediction errors

    SciTech Connect (OSTI)

    Bailey, Daniel W.; Kumaraswamy, Lalith; Bakhtiari, Mohammad; Podgorsak, Matthew B.

    2013-05-15

    Purpose: This study presents a follow-up to a modified calibration procedure for portal dosimetry published by Bailey et al. ['An effective correction algorithm for off-axis portal dosimetry errors,' Med. Phys. 36, 4089-4094 (2009)]. A commercial portal dose prediction system exhibits disagreement of up to 15% (calibrated units) between measured and predicted images as off-axis distance increases. The previous modified calibration procedure accounts for these off-axis effects in most regions of the detecting surface, but is limited by the simplistic assumption of radial symmetry. Methods: We find that a two-dimensional (2D) matrix correction, applied to each calibrated image, accounts for off-axis prediction errors in all regions of the detecting surface, including those still problematic after the radial correction is performed. The correction matrix is calculated by quantitative comparison of predicted and measured images that span the entire detecting surface. The correction matrix was verified for dose-linearity, and its effectiveness was verified on a number of test fields. The 2D correction was employed to retrospectively examine 22 off-axis, asymmetric electronic-compensation breast fields, five intensity-modulated brain fields (moderate-high modulation) manipulated for far off-axis delivery, and 29 intensity-modulated clinical fields of varying complexity in the central portion of the detecting surface. Results: Employing the matrix correction to the off-axis test fields and clinical fields, predicted vs measured portal dose agreement improves by up to 15%, producing up to 10% better agreement than the radial correction in some areas of the detecting surface. Gamma evaluation analyses (3 mm, 3% global, 10% dose threshold) of predicted vs measured portal dose images demonstrate pass rate improvement of up to 75% with the matrix correction, producing pass rates that are up to 30% higher than those resulting from the radial correction technique alone. As in

  16. TableHC2.3.xls

    Gasoline and Diesel Fuel Update (EIA)

    Income Relative to Poverty Line Below 100 Percent......2.3 Q Q Q 0.4 1. Below 150 percent of poverty line or 60 percent of median State ...

  17. 3:2:1 Crack Spread

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    To calculate the 3:2:1 crack spread for a Gulf Coast refinery that processes Louisiana Light Sweet (LLS) crude oil, add the spot price for two barrels of Gulf Coast conventional ...

  18. The Vapor Pressure of 1-(2,2,3,3-Tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-prop anol

    SciTech Connect (OSTI)

    Steele, W.V.

    2002-01-29

    The vapor pressure of the compound 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol was measured over the temperature range 62 to 92 C using a Knudsen effusion technique. This compound, known as Cs-7SB, is the modifier component in the caustic-side solvent extraction process solvent. The vapor pressure is related to temperature by the equation ln(p/Pa) = (32.202 {+-} 0.265) - (12154 {+-} 93)/T, where p is the pressure, expressed in pascals; Pa is the reference pressure of 1 pascal; and T is the temperature, expressed in degrees kelvin. The derived heat of vaporization is 101.1 {+-} 0.8{sup kJ{center_dot}mol{sup 1} at 351 K. Because the vapor pressures over the temperature range of 15 to 50 C were lower than the design capabilities of the Knudsen effusion apparatus, the vapor pressures at these temperature limits were obtained by extrapolation. The estimated values are 4.6 {+-} 0.3E-05 (3.5 {+-} 0.2E-07 mm Hg) and 4.5 {+-} 0.1E-03 Pa (3.4 {+-} 0.1E-05 mm Hg) for 15 C and 50 C, respectively.

  19. THE SYNTHESIS AND CRYSTAL STRUCTURE OF UCp{sub 3}(C{sub 3}H{sub 3}N{sub 2}). A NEW MODE OF PYRAZOLATE BONDING

    SciTech Connect (OSTI)

    Eigenbrot, Jr., Charles W.; Raymond, Kenneth N.

    1980-08-01

    The title compound has been prepared by the reaction of tris(cyclopentadienyl) uranium chloride (UCp{sub 3}Cl) and sodium pyrazolate (NaC{sub 3}H{sub 3}N{sub 2}) in tetrahydrofuran (THF). The compound has been characterized by its infrared, visible-near IR, pmr, and mass spectra; and by single crystal X-ray diffraction. The molecular structure consists of discrete UCp{sub 3}(C{sub 3}H{sub 3}N{sub 2}) molecules in which the uranium(IV) ion is coordinated by three {eta}{sup 5} Cp rings in a nearly trigonal array similar to that of other lanthanide and actinide MCp{sub 3}X structures. However, unlike these other structures, an eleven-coordinate geometry is achieved by having both the adjacent nitrogen atoms of the pyrazolate ring coordinate to the metal ion, such that the local twofold axis of the pyrazolate ring and the local threefold axis of the UCp{sub 3} fragment coincide. This is the first example of this type of endo-bidentate {eta}{sup 2} coordination for the pyrazolate anion. Red-brown crystals from toluene conform to space group P2{sub 1}/a (an alternate setting of P2{sub 1}/c) with a = 14.295(1), b = 8.383(1), c = 14.282(1) {angstrom}, S = 112.80(1) {degrees}, and there are four molecules per unit cell. For the 3631 independent reflections collected by counter methods with F{sup 2} > 3{sigma}(F{sup 2}). the final weighted and unweighted R factors are both 3.14 percent. The U-N distances are 2.40(1) and 2.36(1) {angstrom}. The average U-C distance of 2.76 {angstrom} is consistent with that predicted for an eleven-coordinate uranium(IV) cyclopentadienyl complex. The 90 MHz proton resonances of the Cp rings occur at -9.51 (35°C), -11.59 (-l0°C). -14.22 (-50°C), and -15.84 (-75°C) ppm. Susceptibility studies from 5 to 80 K show a temperature-independent paramagnetism from 7.5 to 37.1 K; above this temperature {mu}{sub eff} = 2.67 {mu}{sub B}·

  20. Safety testing of AGR-2 UO2 compacts 3-3-2 and 3-4-2

    SciTech Connect (OSTI)

    Hunn, John D.; Morris, Robert Noel; Baldwin, Charles A.; Montgomery, Fred C.

    2015-09-01

    Post-irradiation examination (PIE) is in progress on tristructural-isotropic (TRISO) coated-particle fuel compacts from the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program second irradiation experiment (AGR-2) [Collin 2014]. The AGR-2 PIE will build upon new information and understanding acquired throughout the recently-concluded six-year AGR-1 PIE campaign [Demkowicz et al. 2015] and establish a database for the different AGR-2 fuel designs.

  1. Li{sub 2}B{sub 3}O{sub 4}F{sub 3}, a new lithium-rich fluorooxoborate

    SciTech Connect (OSTI)

    Pilz, Thomas; Nuss, Hanne; Jansen, Martin

    2012-02-15

    The new lithium fluorooxoborate, Li{sub 2}B{sub 3}O{sub 4}F{sub 3}, is obtained by a solid state reaction from LiBO{sub 2} and LiBF{sub 4} at 553 K and crystallizes in the acentric orthorhombic space group P2{sub 1}2{sub 1}2{sub 1} (no. 19) with the cell parameters a=4.8915(9), b=8.734(2), and c=12.301(2) A. Chains of fluorinated boroxine rings along the b axis consists of BO{sub 3} triangles and BO{sub 2}F{sub 2} as well as BO{sub 3}F tetrahedra. Mobile lithium ions are compensating the negative charge of the anionic chain, in which the fourfold coordinated boron atoms bear a negative formal charge. Annealing Li{sub 2}B{sub 3}O{sub 4}F{sub 3} at temperatures above 573 K leads to conversion into Li{sub 2}B{sub 6}O{sub 9}F{sub 2}. The title compound is an ionic conductor with the highest ion conductivity among the hitherto know lithium fluorooxoborates, with conductivities of 1.6 Multiplication-Sign 10{sup -9} and 1.8 Multiplication-Sign 10{sup -8} S cm{sup -1} at 473 and 523 K, respectively. - Graphical abstract: Repetition unit of Li{sub 2}B{sub 3}O{sub 4}F{sub 3}. Highlights: Black-Right-Pointing-Pointer Li{sub 2}B{sub 3}O{sub 4}F{sub 3} is the third member within the family of lithium fluorooxoborates. Black-Right-Pointing-Pointer It shows the highest lithium ion conductivity among them. Black-Right-Pointing-Pointer Chains of interconnected fluorinated boroxine rings run along the b axis. Black-Right-Pointing-Pointer Acentric space group meets the requirement for second harmonic generation.

  2. Beamline 5.3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5.3.2.1 Beamline 5.3.2.1 Print Thursday, 26 February 2015 12:20 Scanning Transmission X-Ray Microscopy (STXM) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 600-2000eV eV Monochromator Low-dispersion, spherical-grating monochromator, two gratings Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal

  3. Eribium Doped Y2O3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect of Local Coordination on the Photoluminescence Properties of Er-doped Y2O3 Thin Films Miniaturizing the erbium-doped optical fiber amplifier (~20 m in length) into a small, compact amplifier that can be integrated with other optical and electronic devices on a single chip (optoelectronics) offers great promise in optical communication as an alternative to the electronic technology.1,2, The gain of these miniaturized devices is limited by the solubility, concentration, and distribution of

  4. Flexible helical-axis stellarator

    DOE Patents [OSTI]

    Harris, Jeffrey H.; Hender, Timothy C.; Carreras, Benjamin A.; Cantrell, Jack L.; Morris, Robert N.

    1988-01-01

    An 1=1 helical winding which spirals about a conventional planar, circular central conductor of a helical-axis stellarator adds a significant degree of flexibility by making it possible to control the rotational transform profile and shear of the magnetic fields confining the plasma in a helical-axis stellarator. The toroidal central conductor links a plurality of toroidal field coils which are separately disposed to follow a helical path around the central conductor in phase with the helical path of the 1=1 winding. This coil configuration produces bean-shaped magnetic flux surfaces which rotate around the central circular conductor in the same manner as the toroidal field generating coils. The additional 1=1 winding provides flexible control of the magnetic field generated by the central conductor to prevent the formation of low-order resonances in the rotational transform profile which can produce break-up of the equilibrium magnetic surfaces. Further, this additional winding can deepen the magnetic well which together with the flexible control provides increased stability.

  5. 1,2,3-triazolium ionic liquids

    DOE Patents [OSTI]

    Luebke, David; Nulwala, Hunaid; Tang, Chau

    2014-12-09

    The present invention relates to compositions of matter that are ionic liquids, the compositions comprising substituted 1,2,3-triazolium cations combined with any anion. Compositions of the invention should be useful in the separation of gases and, perhaps, as catalysts for many reactions.

  6. KIVA-3V, Release 2: Improvements to KIVA-3V

    SciTech Connect (OSTI)

    Anthony A. Amsden

    1999-05-01

    This report describes the changes made in the KIVA-3V computer program since its initial release version dated 24 March 1997. A variety of new features enhance the robustness, efficiency, and usefulness of the overall program for engine modeling. Among these are an automatic restart of the cycle with a reduced timestep in case of iteration limit or temperature overflow, which should greatly reduce the likelihood of having the code crash in mid run. A new option is the automatic deactivation of a port region when it is closed off from the engine cylinder and its reactivation when it again communicates with the cylinder. A number of corrections throughout the code improve accuracy, one of which also corrects the 2-D planar option to make it properly independent of the third dimension. Extensions to the particle-based liquid wall film model make the model somewhat more complete, although it is still considered a work-in-progress. In response to current research in fuel-injected engines, a split-injection option has been added. A new subroutine monitors the whereabouts of the liquid and gaseous phases of the fuel, and for combustion runs the energy balance data and emissions are monitored and printed. New features in the grid generator K3PREP and the graphics post-processor K3POST are also discussed.

  7. 2.3 Understanding Chemical Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6/1/2011 2.3 Understanding Chemical Reactions The molecular features that influence the rate of chemical reactions were poorly understood until the mid- 1960s, when Dudley Herschbach and his postdoctoral student Yuan T. Lee began a series of experiments at Harvard University. With funding from the Office of Science and predecessor agencies, they explained in detail how chemical reactions take place, and solved the problem of how to observe the random directions and velocities of molecules in a

  8. DC 12m telescope. Preliminary calculations. Investigation of elevation axis position.

    SciTech Connect (OSTI)

    Guarino, V. J.; High Energy Physics

    2009-12-18

    This paper examines some simple calculations of a 2D model of a telescope in order to understand how different design parameters affect the design. For the design of a telescope it is assumed that they need a design that minimizes deflections of the dish and also minimizes the size of the motors and torques needed to rotate in elevation. A common belief is that a lighter dish and minimum counterweight is desirable. However, these calculations show this is not necessarily true. The torque needed for rotation depends on the moment of inertia and if the telescope is balanced about the elevation axis. A light dish with no CW requires that the elevation axis be several meters in front of the dish (8-9m) in order to be balanced. This is not practical from a structural point of view. If the elevation axis is only 2m in front of the dish and there is no counterweight then the telescope will be unbalanced and the toruqes required will be very high - much higher than the torques needed only to overcome inertia. A heavy dish though can act as its own counterweight and the elevation axis only has to be 2-3m in front of the dish in order to achieve a balanced telescope. Also the struts that support the camera from the dish place a load on the dish which will put a bending moment on the dish. This bending moment will deform the dish and require it to be stiffer. A counterweight structure performs two functions. First, it allows the telescope to be balanced about the elevation axis. Second, it applies a force on the dish that opposes the forces from the camera struts, thereby reducing the bending moment and deformations of the dish.

  9. Converse magnetoelectric coupling in NiFe/Pb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3}PbTiO{sub 3} nanocomposite thin films grown on Si substrates

    SciTech Connect (OSTI)

    Feng, Ming; Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping 136000 ; Hu, Jiamian; Wang, Jianjun; Li, Zheng; Shu, Li; Nan, C. W.

    2013-11-04

    Multiferroic NiFe (?30 nm)/Pb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3}PbTiO{sub 3}(PMNPT, ?220 nm) bilayered thin films were grown on common Pt/Ti/SiO{sub 2}/Si substrates by a combination of off-axis magnetron sputtering and sol-gel spin-coating technique. By using AC-mode magneto-optical Kerr effect technique, the change in the Kerr signal (magnetization) of the NiFe upon applying a low-frequency AC voltage to the PMNPT film was in situ acquired at zero magnetic field. The obtained Kerr signal versus voltage loop essentially tracks the electromechanical strain curve of the PMNPT thin film, clearly demonstrating a strain-mediated converse magnetoelectric coupling, i.e., voltage-modulated magnetization, in the NiFe/PMNPT nanocomposite thin films.

  10. High critical currents in heavily doped (Gd,Y)Ba2Cu3Ox superconductor tapes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Selvamanickam, V.; Gharahcheshmeh, M. Heydari; Xu, A.; Galstyan, E.; Delgado, L.; Cantoni, C.

    2015-01-20

    REBa2Cu3Ox superconductor tapes with moderate levels of dopants have been optimized for high critical current density in low magnetic fields at 77 K, but they do not exhibit exemplary performance in conditions of interest for practical applications, i.e., temperatures less than 50 K and fields of 2–30 T. Heavy doping of REBCO tapes has been avoided by researchers thus far due to deterioration in properties. Here, we report achievement of critical current densities (Jc) above 20 MA/cm2 at 30 K, 3 T in heavily doped (25 mol. % Zr-added) (Gd,Y)Ba2Cu3Ox superconductor tapes, which is more than three times higher thanmore » the Jc typically obtained in moderately doped tapes. Pinning force levels above 1000 GN/m3 have also been attained at 20 K. A composition map of lift factor in Jc (ratio of Jc at 30 K, 3 T to the Jc at 77 K, 0 T) has been developed which reveals the optimum film composition to obtain lift factors above six, which is thrice the typical value. A highly c-axis aligned BaZrO3 (BZO) nanocolumn defect density of nearly 7 × 1011 cm–2 as well as 23nm sized particles rich in Cu and Zr have been found in the high Jc films.« less

  11. Beamline 5.3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5.3.2.1 Print Scanning Transmission X-Ray Microscopy (STXM) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 600-2000eV eV Monochromator Low-dispersion, spherical-grating monochromator, two gratings Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25-100 nm

  12. Beamline 5.3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5.3.2.1 Print Scanning Transmission X-Ray Microscopy (STXM) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 600-2000eV eV Monochromator Low-dispersion, spherical-grating monochromator, two gratings Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25-100 nm

  13. Beamline 5.3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 5.3.2.1 Print Scanning Transmission X-Ray Microscopy (STXM) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 600-2000eV eV Monochromator Low-dispersion, spherical-grating monochromator, two gratings Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25-100

  14. Beamline 5.3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5.3.2.1 Print Scanning Transmission X-Ray Microscopy (STXM) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 600-2000eV eV Monochromator Low-dispersion, spherical-grating monochromator, two gratings Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25-100 nm

  15. Beamline 5.3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5.3.2.1 Print Scanning Transmission X-Ray Microscopy (STXM) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 600-2000eV eV Monochromator Low-dispersion, spherical-grating monochromator, two gratings Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25-100 nm

  16. Beamline 5.3.2.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5.3.2.1 Print Scanning Transmission X-Ray Microscopy (STXM) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Bend magnet Energy range 600-2000eV eV Monochromator Low-dispersion, spherical-grating monochromator, two gratings Calculated flux (1.9 GeV, 500 mA) 1 x 107 photons/s at sample Resolving power (E/ΔE) ≤ 5,000 Endstations Scanning transmission x-ray microscope (STXM) Characteristics Active servo-stabilized toroidal premirror Spot size at sample (FWHM) 25-100 nm

  17. Dual Axis Radiographic Hydrodynamic Test Facility | National...

    National Nuclear Security Administration (NNSA)

    Dual Axis Radiographic Hydrodynamic Test Facility An integral part of the national ... radiographic images of the imploding test object, in which materials are moving at ...

  18. Helical axis stellarator with noninterlocking planar coils

    DOE Patents [OSTI]

    Reiman, Allan; Boozer, Allen H.

    1987-01-01

    A helical axis stellarator using only noninterlocking planar, non-circular coils, generates magnetic fields having a magnetic well and large rotational transform with resultant large equilibrium beta.

  19. Biotransformation of 2,3,3,3-tetrafluoropropene (HFO-1234yf)

    SciTech Connect (OSTI)

    Schuster, Paul; Bertermann, Ruediger; Snow, Timothy A.; Han Xing; Rusch, George M.; Jepson, Gary W.; Dekant, Wolfgang

    2008-12-01

    2,3,3,3-Tetrafluoropropene (HFO-1234yf) is a non-ozone-depleting fluorocarbon replacement with a low global warming potential which has been developed as refrigerant. The biotransformation of HFO-1234yf was investigated after inhalation exposure. Male Sprague-Dawley rats were exposed to air containing 2000, 10,000, or 50,000 ppm HFO-1234yf for 6 h and male B6C3F1 mice were exposed to 50,000 ppm HFO-1234yf for 3.5 h in a dynamic exposure chamber (n = 5/concentration). After the end of the exposure, animals were individually housed in metabolic cages and urines were collected at 6 or 12-hour intervals for 48 h. For metabolite identification, urine samples were analyzed by {sup 1}H-coupled and decoupled {sup 19}F-NMR and by LC/MS-MS or GC/MS. Metabolites were identified by {sup 19}F-NMR chemical shifts, signal multiplicity, {sup 1}H-{sup 19}F coupling constants and by comparison with synthetic reference compounds. In all urine samples, the predominant metabolites were two diastereomers of N-acetyl-S-(3,3,3-trifluoro-2-hydroxy-propyl)-L-cysteine. In {sup 19}F-NMR, the signal intensity of these metabolites represented more than 85% (50,000 ppm) of total {sup 19}F related signals in the urine samples. Trifluoroacetic acid, 3,3,3-trifluorolactic acid, 3,3,3-trifluoro-1-hydroxyacetone, 3,3,3-trifluoroacetone and 3,3,3-trifluoro-1,2-dihydroxypropane were present as minor metabolites. Quantification of N-acetyl-S-(3,3,3-trifluoro-2-hydroxy-propyl)-L-cysteine by LC/MS-MS showed that most of this metabolite (90%) was excreted within 18 h after the end of exposure (t{sub 1/2} app. 6 h). In rats, the recovery of N-acetyl-S-(3,3,3-trifluoro-2-hydroxy-propyl)-L-cysteine excreted within 48 h in urine was determined as 0.30 {+-} 0.03, 0.63 {+-} 0.16, and 2.43 {+-} 0.86 {mu}mol at 2000, 10,000 and 50,000 ppm, respectively suggesting only a low extent (<< 1% of dose received) of biotransformation of HFO-1234yf. In mice, the recovery of this metabolite was 1.774 {+-} 0.4 {mu

  20. Genotoxicity of 2-bromo-3?-chloropropiophenone

    SciTech Connect (OSTI)

    Meng, Fanxue; Yan, Jian; Li, Yan; Fu, Peter P.; Fossom, Linda H.; Sood, Ramesh K.; Mans, Daniel J.; Chu, Pei-I; Moore, Martha M.; Chen, Tao

    2013-07-15

    Impurities are present in any drug substance or drug product. They can be process-related impurities that are not completely removed during purification or are formed due to the degradation of the drug substance over the product shelf-life. Unlike the drug substance, impurities generally do not have beneficial effects and may present a risk without associated benefit. Therefore, their amount should be minimized. 2-Bromo-3?-chloropropiophenone (BCP) is an impurity of bupropion, a second-generation antidepressant and a smoking cessation aid. The United States Pharmacopeia recommends an acceptable level for BCP that is not more than 0.1% of the bupropion. Because exposure to genotoxic impurities even at low levels is of significant concern, it is important to determine whether or not BCP is genotoxic. Therefore, in this study the Ames test and the in vitro micronucleus assay were conducted to evaluate the genotoxicity of BCP. BCP was mutagenic with S9 metabolic activation, increasing the mutant frequencies in a concentration-dependent manner, up to 22- and 145-fold induction over the controls in Salmonella strains TA100 and TA1535, respectively. BCP was also positive in the in vitro micronucleus assay, resulting in up to 3.3- and 5.1-fold increase of micronucleus frequency for treatments in the absence and presence of S9, respectively; and 9.9- and 7.4-fold increase of aneuploidies without and with S9, respectively. The addition of N-acetyl-L-cysteine, an antioxidant, reduced the genotoxicity of BCP in both assays. Further studies showed that BCP treatment resulted in induction of reactive oxygen species (ROS) in the TK6 cells. The results suggest that BCP is mutagenic, clastogenic, and aneugenic, and that these activities are mediated via generation of reactive metabolites. - Highlights: 2-Bromo-3?-chloropropiophenone is an impurity of bupropion. BCP was positive in both the Ames test and the in vitro micronucleus assay. It induced high frequencies of mutations

  1. OVIS 3.2 user's guide.

    SciTech Connect (OSTI)

    Mayo, Jackson R.; Gentile, Ann C.; Brandt, James M.; Houf, Catherine A.; Thompson, David C.; Roe, Diana C.; Wong, Matthew H.; Pebay, Philippe Pierre

    2010-10-01

    This document describes how to obtain, install, use, and enjoy a better life with OVIS version 3.2. The OVIS project targets scalable, real-time analysis of very large data sets. We characterize the behaviors of elements and aggregations of elements (e.g., across space and time) in data sets in order to detect meaningful conditions and anomalous behaviors. We are particularly interested in determining anomalous behaviors that can be used as advance indicators of significant events of which notification can be made or upon which action can be taken or invoked. The OVIS open source tool (BSD license) is available for download at ovis.ca.sandia.gov. While we intend for it to support a variety of application domains, the OVIS tool was initially developed for, and continues to be primarily tuned for, the investigation of High Performance Compute (HPC) cluster system health. In this application it is intended to be both a system administrator tool for monitoring and a system engineer tool for exploring the system state in depth. OVIS 3.2 provides a variety of statistical tools for examining the behavior of elements in a cluster (e.g., nodes, racks) and associated resources (e.g., storage appliances and network switches). It provides an interactive 3-D physical view in which the cluster elements can be colored by raw or derived element values (e.g., temperatures, memory errors). The visual display allows the user to easily determine abnormal or outlier behaviors. Additionally, it provides search capabilities for certain scheduler logs. The OVIS capabilities were designed to be highly interactive - for example, the job search may drive an analysis which in turn may drive the user generation of a derived value which would then be examined on the physical display. The OVIS project envisions the capabilities of its tools applied to compute cluster monitoring. In the future, integration with the scheduler or resource manager will be included in a release to enable intelligent

  2. Synthesis and crystal structure of the palladium oxides NaPd{sub 3}O{sub 4}, Na{sub 2}PdO{sub 3} and K{sub 3}Pd{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Panin, Rodion V. Khasanova, Nellie R.; Abakumov, Artem M.; Antipov, Evgeny V.; Tendeloo, Gustaaf van; Schnelle, Walter

    2007-05-15

    NaPd{sub 3}O{sub 4}, Na{sub 2}PdO{sub 3} and K{sub 3}Pd{sub 2}O{sub 4} have been prepared by solid-state reaction of Na{sub 2}O{sub 2} or KO{sub 2} and PdO in sealed silica tubes. Crystal structures of the synthesized phases were refined by the Rietveld method from X-ray powder diffraction data. NaPd{sub 3}O{sub 4} (space group Pm3-barn, a=5.64979(6) A, Z=2) is isostructural to NaPt{sub 3}O{sub 4}. It consists of NaO{sub 8} cubes and PdO{sub 4} squares, corner linked into a three-dimensional framework where the planes of neighboring PdO{sub 4} squares are perpendicular to each other. Na{sub 2}PdO{sub 3} (space group C2/c, a=5.3857(1) A, b=9.3297(1) A, c=10.8136(2) A, {beta}=99.437(2){sup o}, Z=8) belongs to the Li{sub 2}RuO{sub 3}-structure type, being the layered variant of the NaCl structure, where the layers of octahedral interstices filled with Na{sup +} and Pd{sup 4+} cations alternate with Na{sub 3} layers along the c-axis. Na{sub 2}PdO{sub 3} exhibits a stacking disorder, detected by electron diffraction and Rietveld refinement. K{sub 3}Pd{sub 2}O{sub 4}, prepared for the first time, crystallizes in the orthorhombic space group Cmcm (a=6.1751(6) A, b=9.1772(12) A, c=11.3402(12) A, Z=4). Its structure is composed of planar PdO{sub 4} units connected via common edges to form parallel staggered PdO{sub 2} strips, where potassium atoms are located between them. Magnetic susceptibility measurements of K{sub 3}Pd{sub 2}O{sub 4} reveal a Curie-Weiss behavior in the temperature range above 80 K. - Graphical abstract: Na{sub 2}PdO{sub 3} (space group C2/c, a=5.3857(1) A, b=9.3297(1) A, c=10.8136(2) A, {beta}=99.437(2), Z=8) belongs to the Li{sub 2}RuO{sub 3}-structure type, being the layered variant of the NaCl structure, where the layers of octahedral interstices filled with Na{sup +} and Pd{sup 4+} cations (NaPd{sub 2}O{sub 6} slabs) alternate with Na{sub 3} layers along the c-axis.

  3. October 2 & 3, 2013 Meeting of the Electricity Advisory Committee...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    October 2 & 3, 2013 Meeting of the Electricity Advisory Committee October 2 & 3, 2013 Meeting of the Electricity Advisory Committee Note: This meeting has been cancelled The ...

  4. Explosive Release Atmospheric Dispersal 3.2

    Energy Science and Technology Software Center (OSTI)

    2001-06-26

    ERAD (Explosive Release Atmospheric Dispersal) is a 3D numerical transport and diffusion model, used to model the consequences associated with the buoyant (or nonbuoyant) dispersal of radioactive material It incorporates an integral plume rise model to simulate the buoyant rise of heated gases following an explosive detonation. treating buoyancy effects from time zero onward, eliminating the need for the stabilized doud assumption, and enabling the penetration of inversions. Modeling of the atmospheric boundary layer usesmore » contemporary parameterization based on scaling theories derived from observational, laboratory and numerical studies. A Monte Carlo stochastic process simulates particle dispersion. Results were validated for both dose and deposition against measurements taken during Operation Roller Coaster (a joint US-UK test performed at NTS). Meteorology is defined using a single vertical sounding containing wind speed and direction and temperature as a function of height. Post processing applies 50-year CEDE DCFs (either ICRP 26 or 60) to determine the contribution of the relevant dose pathways (inhalation, submersion, and ground shine) as well as the total dose received. Dose and deposition contours are overlaid on a fully integrated worldwide GIS and tabulates hearth effects (fatalities and casualties) to resident population. The software runs on a laptop and takes less than 2 minutes to process. The Municipal version of ERAD does not include the ability to model the mitigation effects of aqueous foam.« less

  5. Double-exchange selection rule for the c-axis conductivity in...

    Office of Scientific and Technical Information (OSTI)

    Double-exchange selection rule for the c-axis conductivity in layered Lasub 2-2xSrsub 1+2xMnsub 2Osub 7 single crystals below Tsub c Citation Details In-Document Search ...

  6. RSE Table 3.2 Relative Standard Errors for Table 3.2

    U.S. Energy Information Administration (EIA) Indexed Site

    Corn Milling",1,2,0,1,3,0,0,0,0 31131," Sugar ",0,0,0,0,0,0,0,0,0 311421," Fruit and ... Corn Milling",0,0,0,0,0,0,0,0,0 31131," Sugar ",0,0,0,0,0,0,0,0,0 311421," Fruit and ...

  7. Superconductivity in semimetallic B i 3 O 2 S 3 (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Superconductivity in semimetallic B i 3 O 2 S 3 Citation Details In-Document Search Title: Superconductivity in semimetallic B i 3 O 2 S 3 Authors: Li, L. ; Parker, D. ; Babkevich, ...

  8. Phonon mean free path of graphite along the c-axis

    SciTech Connect (OSTI)

    Wei, Zhiyong; Yang, Juekuan; Chen, Weiyu; Bi, Kedong; Chen, Yunfei, E-mail: yunfeichen@seu.edu.cn [Jiangsu Key Laboratory for Design and Manufacture of Micro/Nano Biomedical Instruments and School of Mechanical Engineering, Southeast University, Nanjing 210096 (China); Li, Deyu, E-mail: deyu.li@vanderbilt.edu [Department of Mechanical Engineering, Vanderbilt University, Nashville, Tennessee 37235-1592 (United States)

    2014-02-24

    Phonon transport in the c-axis direction of graphite thin films has been studied using non-equilibrium molecular dynamics (MD) simulation. The simulation results show that the c-axis thermal conductivities for films of thickness ranging from 20 to 500 atomic layers are significantly lower than the bulk value. Based on the MD data, a method is developed to construct the c-axis thermal conductivity as an accumulation function of phonon mean free path (MFP), from which we show that phonons with MFPs from 2 to 2000?nm contribute ?80% of the graphite c-axis thermal conductivity at room temperature, and phonons with MFPs larger than 100?nm contribute over 40% to the c-axis thermal conductivity. These findings indicate that the commonly believed value of just a few nanometers from the simple kinetic theory drastically underestimates the c-axis phonon MFP of graphite.

  9. Investigation of structural changes in chiral magnet Cr{sub 1?3}NbS{sub 2} under application of pressure

    SciTech Connect (OSTI)

    Mito, M. Tsuruta, K.; Deguchi, H.; Tajiri, T.; Kishine, J.; Inoue, K.; Kousaka, Y.; Nakao, Y.; Akimitsu, J.

    2015-05-14

    We perform structural analysis experiments on the chiral magnet Cr{sub 1?3}NbS{sub 2}, in which Cr{sup 3+} ions are inserted between hexagonal NbS{sub 2} layers. The noncentrosymmetrical nature of the inserted Cr{sup 3+} appears as a distorted CrS{sub 6} octahedron. Under the application of hydrostatic pressure, the lattice shrinks significantly along the c-axis rather than the a-axis. However, at a pressure P of approximately 34?GPa, a kink in the rate of decrease in the lattice parameters is observed, and the slight movement of a Nb atom along the c-axis brings about a decrease in the distortion of the CrS{sub 6} octahedron. This structural change qualitatively suggests a decrease in the strength of the Dzyaloshinskii-Moriya (D-M) interaction. Under hydrostatic pressure, the magnetic ordering temperature T{sub C} decreases, and dT{sub C}/dP exhibits a slight change at around 3?GPa. A series of experiments indicates that the change in the structural symmetry of the CrS{sub 6} octahedron influences the exchange network between Cr{sup 3+} ions as well as the D-M interaction.

  10. Actuator assembly including a single axis of rotation locking member

    DOE Patents [OSTI]

    Quitmeyer, James N.; Benson, Dwayne M.; Geck, Kellan P.

    2009-12-08

    An actuator assembly including an actuator housing assembly and a single axis of rotation locking member fixedly attached to a portion of the actuator housing assembly and an external mounting structure. The single axis of rotation locking member restricting rotational movement of the actuator housing assembly about at least one axis. The single axis of rotation locking member is coupled at a first end to the actuator housing assembly about a Y axis and at a 90.degree. angle to an X and Z axis providing rotation of the actuator housing assembly about the Y axis. The single axis of rotation locking member is coupled at a second end to a mounting structure, and more particularly a mounting pin, about an X axis and at a 90.degree. angle to a Y and Z axis providing rotation of the actuator housing assembly about the X axis. The actuator assembly is thereby restricted from rotation about the Z axis.

  11. Superconductivity versus structural phase transition in the closely related Bi2Rh3.5S2 and Bi2Rh3S2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kaluarachchi, Udhara S.; Xie, Weiwei; Lin, Qisheng; Taufour, Valentin; Bud'ko, Sergey L.; Miller, Gordon J.; Canfield, Paul C.

    2015-05-19

    Single crystals of Bi2Rh3S2 and Bi2Rh3.5S2 were synthesized by solution growth, and the crystal structures and thermodynamic and transport properties of both compounds were studied. In the case of Bi2Rh3S2, a structural first-order transition at around 165 K is identified by single-crystal diffraction experiments, with clear signatures visible in resistivity, magnetization, and specific heat data. No superconducting transition for Bi2Rh3S2 was observed down to 0.5 K. In contrast, no structural phase transition at high temperature was observed for Bi2Rh3.5S2; however, bulk superconductivity with a critical temperature, Tc ≈ 1.7 K, was observed. The Sommerfeld coefficient γ and the Debye temperaturemore » (ΘD) were found to be 9.41 mJ mol–1K–2 and 209 K, respectively, for Bi2Rh3S2, and 22 mJ mol–1K–2 and 196 K, respectively, for Bi2Rh3.5S2. As a result, the study of the specific heat in the superconducting state of Bi2Rh3.5S2 suggests that Bi2Rh3.5S2 is a weakly coupled, BCS superconductor.« less

  12. 3-(2-Biphenyl)sydnone

    SciTech Connect (OSTI)

    Riddle, Gordon B.; Grossie, David A.; Turnbull, Kenneth

    2010-11-16

    The title compound, C{sub 14}H{sub 10}N{sub 2}O{sub 2}, is one of many sydnones which have been synthesized in order to investigate the influence of substituents and sydnone-ring stability. There is medicinal interest in the sydnone if the ring can predictably release NO. Bond lengths and angles of the sydnone ring were compared with those of other published sydnone compounds and were found to fit the average of the published data.

  13. HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3...

    Office of Scientific and Technical Information (OSTI)

    ...6Cr-4Al-2W-0.3Ti-0.3Y2O3 ODS Steel Citation Details In-Document Search Title: HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3 ODS Steel You are accessing a ...

  14. HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3...

    Office of Scientific and Technical Information (OSTI)

    HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3 ODS Steel Citation Details In-Document Search Title: HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3 ...

  15. Yaw dynamics of horizontal axis wind turbines

    SciTech Connect (OSTI)

    Hansen, A.C. )

    1992-05-01

    Designers of a horizontal axis wind turbine yaw mechanism are faced with a difficult decision. They know that if they elect to use a yaw- controlled rotor then the system will suffer increased initial cost and increased inherent maintenance and reliability problems. On the other hand, if they elect to allow the rotor to freely yaw they known they will have to account for unknown and random, though bounded, yaw rates. They will have a higher-risk design to trade-off against the potential for cost savings and reliability improvement. The risk of a yaw-free system could be minimized if methods were available for analyzing and understanding yaw behavior. The complexity of yaw behavior has, until recently, discouraged engineers from developing a complete yaw analysis method. The objectives of this work are to (1) provide a fundamental understanding of free-yaw mechanics and the design concepts most effective at eliminating yaw problems, and (2) provide tested design tools and guidelines for use by free-yaw wind systems manufacturers. The emphasis is on developing practical and sufficiently accurate design methods.

  16. Buildings Energy Data Book: 3.2 Commercial Sector Characteristics

    Buildings Energy Data Book [EERE]

    2 Principal Commercial Building Types, as of 2003 (Percent of Total Floorspace) (1) Office 17% 17% 19% Mercantile 16% 14% 18% Retail 6% 9% 5% Enclosed & Strip Malls 10% 4% 13% Education 14% 8% 11% Warehouse and Storage 14% 12% 7% Lodging 7% 3% 7% Service 6% 13% 4% Public Assembly 5% 6% 5% Religious Worship 5% 8% 2% Health Care 4% 3% 8% Inpatient 3% 0% 6% Outpatient 2% 2% 2% Food Sales 2% 5% 5% Food Service 2% 6% 6% Public Order and Safety 2% 1% 2% Other 2% 2% 4% Vacant 4% 4% 1% Total 100%

  17. Innovative Offshore Vertical-Axis Wind Turbine Rotors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Offshore Vertical-Axis Wind Turbine Rotors - Sandia Energy Energy Search Icon Sandia Home ... Google + Vimeo Newsletter Signup SlideShare Innovative Offshore Vertical-Axis Wind Turbine ...

  18. DARHT: Dual-Axis Radiographic Hydrodynamic Test Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DARHT: Dual-Axis Radiographic Hydrodynamic Test Facility DARHT: Dual-Axis Radiographic Hydrodynamic Test Facility DARHT, supports a critical component of LANL's primary mission: to...

  19. table2.3_02.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonfuel (Feedstock) Use of Combustible Energy, 2002; Level: National and Regional Data; Row: Values of Shipments and Employment Sizes; Column: Energy Sources; Unit: Trillion Btu. RSE Economic Residual Distillate Natural LPG and Coke and Row Characteristic(a) Total Fuel Oil Fuel Oil(b) Gas(c) NGL(d) Coal Breeze Other(e) Factors Total United States RSE Column Factors: 1 0.4 6.4 0.6 0.5 1.1 1.7 0.8 Value of Shipments and Receipts (million dollars) Under 20 94 * 6 19 W W W W 9 20-49 135 19 3 8 W W

  20. DARHT Axis-I Diode Simulations II: Geometrical Scaling

    SciTech Connect (OSTI)

    Ekdahl, Carl A. Jr.

    2012-06-14

    Flash radiography of large hydrodynamic experiments driven by high explosives is a venerable diagnostic technique in use at many laboratories. Many of the largest hydrodynamic experiments study mockups of nuclear weapons, and are often called hydrotests for short. The dual-axis radiography for hydrodynamic testing (DARHT) facility uses two electron linear-induction accelerators (LIA) to produce the radiographic source spots for perpendicular views of a hydrotest. The first of these LIAs produces a single pulse, with a fixed {approx}60-ns pulsewidth. The second axis LIA produces as many as four pulses within 1.6-{micro}s, with variable pulsewidths and separation. There are a wide variety of hydrotest geometries, each with a unique radiographic requirement, so there is a need to adjust the radiographic dose for the best images. This can be accomplished on the second axis by simply adjusting the pulsewidths, but is more problematic on the first axis. Changing the beam energy or introducing radiation attenuation also changes the spectrum, which is undesirable. Moreover, using radiation attenuation introduces significant blur, increasing the effective spot size. The dose can also be adjusted by changing the beam kinetic energy. This is a very sensitive method, because the dose scales as the {approx}2.8 power of the energy, but it would require retuning the accelerator. This leaves manipulating the beam current as the best means for adjusting the dose, and one way to do this is to change the size of the cathode. This method has been proposed, and is being tested. This article describes simulations undertaken to develop scaling laws for use as design tools in changing the Axis-1 beam current by changing the cathode size.

  1. The compact molecular core toward G34. 3 + 0. 2 - VLA observations in the (2,2) and (3,3) lines of ammonia

    SciTech Connect (OSTI)

    Garay, G.; Rodriguez, L.F. Harvard-Sithsonian Center for Astrophysics, Cambridge, MA Universidad Nacional Autonoma de Mexico, Coyoacan )

    1990-10-01

    The VLA was used to map the NH3 emission in the lines of the (J,K) = (2,2) and (J,K) = (3,3) inversion transitions toward the warm molecular cloud associated with the compact H II region G34.3 + 0.2. The main HF line of the (2,2) inversion transition is detected in absorption in the western half of the source and in emission in the eastern half. The main HF line of the (3,3) inversion transition is detected in emission over the whole source. The HF satellite lines of the (2,2) and (2,3) inversion transitions are detected only in emission. A molecular cloud exhibits a core-halo structure in which the emission from the HF satellite lines arise from an ultracompact region near the center of the cloud and the emission in the main HF component of the (3,3) transition arises from a disklike structure. The rotational temperature increases from about 70 K near the edges of the core to about 185 K at the position of the ultracompact molecular core. The hydrogen molecular density in the ultracompact core is about 7 x 10 to the 7th/cu cm. 20 refs.

  2. Radiative Bottomonium Spectroscopy at the Y(2, 3S) Resonances...

    Office of Scientific and Technical Information (OSTI)

    Radiative Bottomonium Spectroscopy at the Y(2, 3S) Resonances at BaBar Citation Details In-Document Search Title: Radiative Bottomonium Spectroscopy at the Y(2, 3S) Resonances at ...

  3. Modular off-axis solar concentrator

    DOE Patents [OSTI]

    Plesniak, Adam P; Hall, John C

    2015-01-27

    A solar concentrator including a housing defining a vertical axis and including a receiving wall connected to a reflecting wall to define an internal volume and an opening into the internal volume, wherein the reflecting wall defines at least one primary optical element, and wherein at least a portion of the reflecting wall includes a layer of reflective material, the housing further including a cover connected to the receiving wall and the reflecting wall to seal the opening, and at least one receiver mounted on the receiving wall such that a vertical axis of the receiver is disposed at a non-zero angle relative to the vertical axis of the housing, the receiver including at least one photovoltaic cell.

  4. Enclosed, off-axis solar concentrator

    DOE Patents [OSTI]

    Benitez, Pablo; Grip, Robert E; Minano, Juan C; Narayanan, Authi A; Plesniak, Adam; Schwartz, Joel A

    2013-11-26

    A solar concentrator including a housing having receiving wall, a reflecting wall and at least two end walls, the receiving, reflecting and end walls defining a three-dimensional volume having an inlet, wherein a vertical axis of the housing is generally perpendicular to the inlet, a receiver mounted on the receiving wall of the housing, the receiver including at least one photovoltaic cell, wherein a vertical axis of the receiver is disposed at a non-zero angle relative to the vertical axis of the housing, at least one clip disposed on the reflecting wall an optical element received within the three-dimensional volume, the optical element including at least one tab, the tab being engaged by the clip to align the optical element with the receiver, and a window received over the inlet to enclose the housing.

  5. Aeroelastically coupled blades for vertical axis wind turbines

    DOE Patents [OSTI]

    Paquette, Joshua; Barone, Matthew F.

    2016-02-23

    Various technologies described herein pertain to a vertical axis wind turbine blade configured to rotate about a rotation axis. The vertical axis wind turbine blade includes at least an attachment segment, a rear swept segment, and optionally, a forward swept segment. The attachment segment is contiguous with the forward swept segment, and the forward swept segment is contiguous with the rear swept segment. The attachment segment includes a first portion of a centroid axis, the forward swept segment includes a second portion of the centroid axis, and the rear swept segment includes a third portion of the centroid axis. The second portion of the centroid axis is angularly displaced ahead of the first portion of the centroid axis and the third portion of the centroid axis is angularly displaced behind the first portion of the centroid axis in the direction of rotation about the rotation axis.

  6. Quality Assurance Exchange August 2007, Volume 3 Issue 2

    Broader source: Energy.gov [DOE]

    Quality Assurance Exchange August 2007, Volume 3 Issue 2 U.S. Department of Energy Office of Corporate Safety Analysis

  7. Tax Deduction Qualified Software Tas version 9.3.2

    Office of Energy Efficiency and Renewable Energy (EERE)

    Information about the Tas version 9.3.2 qualified computer software and federal tax incentive requirements for commercial buildings.

  8. Tool Gear Version 2.3

    Energy Science and Technology Software Center (OSTI)

    2011-12-05

    Tool Gear Version 2 is an expanded collection of programs and software libraries that form the infrastructure on which software tools may be built. The software tools help application developers understand the performance of the programs or help them find programming errors. Tool Gear includes components for gathering data from target programs, either through direct instrumentations or by parsing the output of third-party tools, transmitting the data to a databse, organizing and storing the data,more » presenting it through a variety of graphical interfaces. Tool Gear is designed to be an extensible system, so users can manage a variety of data and create new ways to present it. Too Gear is sesigned to work with both sequential and parallel programs on multiple computer platforms« less

  9. JAS3D v. 2.4

    Energy Science and Technology Software Center (OSTI)

    2009-06-29

    JAS3D is a three-dimensional finite element program originally designed to solve Lagrangian quasistatic non-linear mechanics problems, and subsequently extended to include both implicit and explicit dynamics. A set of continuum equations describes the nonlinear mechanics involving large rotation and strain. Innovative multilevel nonlinear iterative methods are used to solve the equations. A wide variety of material constitutive models are available, and contact interface logic is implemented. Two Lagrangian uniform-strain elements are available: an eighth-node hexahedronmore » for solids and a four-node quadrilateral for shells. Both use hourglass stiffness to control zero-energy modes. In addition, a version of the hexahedron is available with uniform pressure and a deviatoric response scalable from the mean response of the original element up to a fully-integrated response. Bodies under analysis may be loaded by surface pressures and concentrated forces, specified displacements, or body forces from gravity, steady-state transport, or thermal expansion.« less

  10. Two-axis tracking solar collector mechanism

    SciTech Connect (OSTI)

    Johnson, K.C.

    1990-11-06

    This patent describes a tracking solar collector mechanism. It comprises: a stationary base structure which supports the tracking components; two parallel rows of uniformly spaced axial polar bearings attached to the base structure, each row comprising at least one bearing, wherein each member bearing of each row is coaligned with an associated bearing of the other row, the line joining each pair of coaligned polar bearings defining an associated polar tracking axis wherein the pair's polar axes are mutually parallel and are adapted to be aligned with the Earth's axis; at least one tracking module, each of which is supported by and turns on one of the pairs of coaligned polar bearings.

  11. Sonochemical synthesis of highly luminescent Ln2O3:Eu3+ (Y, La, Gd) nanocrystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Alammar, Tarek; Cybinska, Joanna; Campbell, Paul S.; Mudring, Anja -Verena

    2015-05-12

    In this study, sonication of Ln(CH3COO)3·H2O, Eu(CH3COO)3·H2O and NaOH dissolved in the ionic liquid-butyl-3-methylimidazolium bis(trifluoromethane)sulfonylamide lead to Ln(OH)3:Eu (Ln: Gd, La, Y) nanoparticles. Subsequent calcination at 800 °C for 3 h allowed to obtain Ln2O3:Eu nanopowders. Gd2O3 and Y2O3 were obtained in the C-type lanthanide sequioxide structure, whereas La2O3 crystallized in the A-type. Structure, morphology, and luminescent properties of the nano-oxides were investigated by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), dispersive X-ray (EDX), and photoluminescence (PL). SEM studies revealed that the synthesized Gd2O3:Eu, La2O3:Eu, and Y2O3:Eu formed nano-spindle, -sheets, and -rods in shape, respectively. The nanoscale materials showmore »very efficient red emission due to the intraconfigurational f–f transitions of Eu3+. The quantum yields for Ln2O3:Eu (5%) were determined to be 4.2% for Ln=Gd, 13.8% for Ln=Y and 5.2% for Ln=La. The asymmetric ratio I02/I01 of Eu3+ varies from 5.3 for Gd2O3, to 5.6 for Y2O3 to 6.5 for La2O3, which increased the color chromaticity.« less

  12. Sonochemical synthesis of highly luminescent Ln2O3:Eu3+ (Y, La, Gd) nanocrystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Alammar, Tarek; Cybinska, Joanna; Campbell, Paul S.; Mudring, Anja -Verena

    2015-05-12

    In this study, sonication of Ln(CH3COO)3·H2O, Eu(CH3COO)3·H2O and NaOH dissolved in the ionic liquid-butyl-3-methylimidazolium bis(trifluoromethane)sulfonylamide lead to Ln(OH)3:Eu (Ln: Gd, La, Y) nanoparticles. Subsequent calcination at 800 °C for 3 h allowed to obtain Ln2O3:Eu nanopowders. Gd2O3 and Y2O3 were obtained in the C-type lanthanide sequioxide structure, whereas La2O3 crystallized in the A-type. Structure, morphology, and luminescent properties of the nano-oxides were investigated by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), dispersive X-ray (EDX), and photoluminescence (PL). SEM studies revealed that the synthesized Gd2O3:Eu, La2O3:Eu, and Y2O3:Eu formed nano-spindle, -sheets, and -rods in shape, respectively. The nanoscale materials showmore » very efficient red emission due to the intraconfigurational f–f transitions of Eu3+. The quantum yields for Ln2O3:Eu (5%) were determined to be 4.2% for Ln=Gd, 13.8% for Ln=Y and 5.2% for Ln=La. The asymmetric ratio I02/I01 of Eu3+ varies from 5.3 for Gd2O3, to 5.6 for Y2O3 to 6.5 for La2O3, which increased the color chromaticity.« less

  13. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    2 Residential Energy Prices, by Year and Fuel Type ($2010) LPG ($/gal) 1980 2.24 1981 2.51 1982 2.30 1983 2.14 1984 2.10 1985 1.96 1986 1.54 1987 1.42 1988 1.39 1989 1.48 1990 1.69 1991 1.56 1992 1.40 1993 1.33 1994 1.27 1995 1.22 1996 1.37 1997 1.34 1998 1.15 1999 1.16 2000 1.70 2001 1.59 2002 1.42 2003 1.67 2004 1.84 2005 2.36 2006 2.64 2007 2.81 2008 3.41 2009 2.52 2010 2.92 2011 3.62 2012 3.65 2013 3.43 2014 3.60 2015 3.74 2016 3.79 2017 3.86 2018 3.89 2019 3.92 2020 3.96 2021 3.99 2022 4.02

  14. Sandia vertical axis wind turbines (VAWTs) demonstrate offshore advantages

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vertical axis wind turbines (VAWTs) demonstrate offshore advantages - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy

  15. Innovative Offshore Vertical-Axis Wind Turbine Rotors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Offshore Vertical-Axis Wind Turbine Rotors - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management

  16. Structure of trans-methyl 2-phenylhexahydro-2H-isoxazolo (2,3-a)-pyridine-3-carboxylate

    SciTech Connect (OSTI)

    Ul-Haque, M.; Horne, W.; Ali, S.A. )

    1993-02-01

    The title compound, a 1,3-dipolar cycloaddition product, crystallizes in the monoclinic space group P2[sub 1]/c, with a = 8.199(3), b = 16.908(1), c = 10.248(2) [angstrom],[beta] = 93.58(2)[degrees] and Z = 4. The structure was solved by direct methods and refined by full matrix least squares methods to R = 0.038 for 1687 observed reflections. The stereochemistry of this compound was found to have the [open quotes]ee[close quotes] conformation in the solid state as well as in solution. The piperidine ring in the molecule is in the chair form and the isoxazolidine ring adopts an envelope conformation.

  17. Aeroelastic Modeling of Large Off-shore Vertical-axis Wind Turbines...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... K. Dixon, C. Ferreira, C. Hofemann, G. van Bussel, and G. van Kuik, "A 3D unsteady panel method for vertical axis wind turbines," Proceedings of the European Wind Energy ...

  18. RSE Table N3.1 and N3.2. Relative Standard Errors for Tables N3.1 and N3.2

    U.S. Energy Information Administration (EIA) Indexed Site

    N3.1 and N3.2. Relative Standard Errors for Tables N3.1 and N3.2;" " Unit: Percents." " "," "," ",," "," "," "," "," "," "," ",," " "NAICS"," "," ","Net","Residual","Distillate",,"LPG and",,"Coke"," " "Code(a)","Subsector and

  19. RSE Table S3.1 and S3.2. Relative Standard Errors for Tables S3.1 and S3.2

    U.S. Energy Information Administration (EIA) Indexed Site

    S3.1 and S3.2. Relative Standard Errors for Tables S3.1 and S3.2;" " Unit: Percents." " "," " "SIC"," "," ","Net","Residual","Distillate",,"LPG and",,"Coke"," " "Code(a)","Major Group and Industry","Total","Electricity(b)","Fuel Oil","Fuel Oil(c)","Natural

  20. NH3-Selective Catalytic Reduction over Ag/Al2O3 Catalysts

    Broader source: Energy.gov [DOE]

    DRIFT spectroscopy used together with flow reactor experiments to investigate the role of H2 for SCR over Ag/Al2O3

  1. In situ preparation and transport properties of YBa sub 2 Cu sub 3 O sub 7 films on sapphire with Zr(Y)O sub 2 buffer layers

    SciTech Connect (OSTI)

    Adrian, G.; Grabe, G.; Wilkens, W. ); Adrian, H.; Huth, M.; Walkenhorst, A. )

    1991-12-01

    YBa{sub 2}Cu{sub 3}O{sub 7} films on sapphire substrates prepared by laser ablation show {ital c}-axis-oriented growth and critical temperatures as high as {ital T}{sub {ital c}}({ital R}=0)=90 K. Due to diffusion processes and the formation of a nonsuperconducting intermediate layer the critical current density {ital J}{sub {ital c}} is comparatively low. To overcome these difficulties the sapphire substrates were covered by Zr(Y)O{sub 2} films acting as diffusion barriers. The preparation of these films was performed by laser ablation using a multitarget system. The structure and the surfaces of the films were characterized by x-ray diffraction and scanning electron microscopy, respectively. The transport properties of the superconductor films are similar to those on suited substrates. Critical current densities up to {ital J}{sub {ital c}} (77 K)=5{times}10{sup 5} A/cm{sup 2} were achieved. In order to gain information about the pinning mechanisms measurements of the dependencies of {ital J}{sub {ital c}} on the orientation between the crystal {ital c} axis and the external magnetic fields were carried out using samples with different buffer layer thicknesses. From the received data no indication of pinning by point defects in addition to the intrinsic planar pinning mechanism was detected.

  2. MHK ISDB/Instruments/CDL MiniPOSNAV3 | Open Energy Information

    Open Energy Info (EERE)

    3 CDL MiniRLG2 AirMar 42183 Heading Sensor ... further results 3-axis Velocity (Translation) (6) Dynamic Motion Sensors 0.05 RMS INS CDL TOGSNav CDL MiniPOSNAV CDL MiniRLG2...

  3. Structures and phases transition in hexylenediammonium pentachlorobismuthate (III) [NH{sub 3}(CH{sub 2}){sub 6}NH{sub 3}]BiCl{sub 5} crystal

    SciTech Connect (OSTI)

    Ouasri, A.; Jeghnou, H.; Rhandour, A.; Roussel, P.

    2013-04-15

    The crystal structure of [NH{sub 3}(CH{sub 2}){sub 6}NH{sub 3}]BiCl{sub 5} was determined at: 223 K [P2{sub 1}2{sub 1}2{sub 1} (Z=4), a=7.788(1), b=13.886(2), c=13.972(2) Å], 308 K [P2{sub 1}/n (Z=8), a=19.972(3), b=7.772(2), c=20.166(3) Å, β=92.32(1)°] and 378 K [Pnma (Z=4), a=13911(2), b=7.834(7), c=14.457(2) Å]. It was consisted of isolated (BiCl{sub 5}{sup 2−}){sub n} anionic chains composed by distorted octahedra BiCl{sub 6}{sup 3−} sharing two corners and {sup +}NH{sub 3}(CH{sub 2}){sub 6}NH{sub 3}{sup +} cations placed in the free cavities between anionic chains. In the β phase, there are two crystallographically inequivalent cations and two one-dimensional anionic chains (BiCl{sub 5}{sup 2−}){sub n} in which BiCl{sub 6}{sup 3−} octahedra was doubly tilted and simply tilted. Two structural phase transitions at low and high temperatures α (P2{sub 1}2{sub 1}2{sub 1}, 223 K)↔β (P2{sub 1}/n, 308 K)↔γ (Pnma, 373 K) are observed and discussed. It was crystallographically showed that both anionic and cationic entities contribute to phase transitions mechanisms. The BiCl{sub 6}{sup 3−} octahedra were found to posses significant distortions on decreasing temperature and became more distorted in α (223 K) phase. It is argued that these deformations are caused by weak to moderate N--H···Cl hydrogen bonding. - Graphical abstract: Projection of the crystal structure of [NH{sub 3}(CH{sub 2}){sub 6}NH{sub 3}]BiCl{sub 5} down the a axis at 208 K. Highlights: ► The crystal shows two phase transitions: α(223 K)↔β(308 K)↔γ(373 K). ► A discontinuous transition may be occurred between α and β phases. ► The α↔β and β↔γ phase transitions are of first order. ► Both anionic and cationic motions contribute to phase transition mechanisms. ► The BiCl{sub 6}{sup 3−} octahedra showed significant distortions on decreasing temperature.

  4. Synthesis and Characterization of Th2N2(NH) Isomorphous to Th2N3

    SciTech Connect (OSTI)

    Silva, G W Chinthaka M; Yeamans, Charles B.; Hunn, John D; Sattelberger, Alfred P; Czerwinski, Ken R.; Weck, Dr. Phil F

    2012-01-01

    Using a new, low-temperature, fluoride-based process, thorium nitride imide of the chemical formula Th{sub 2}N{sub 2}(NH) was synthesized from thorium dioxide via an ammonium thorium fluoride intermediate. The resulting product phase was characterized by powder X-ray diffraction (XRD) analysis and was found to be crystallographically similar to Th{sub 2}N{sub 3}. Its unit cell was hexagonal with a space group of P3m{bar 1} and lattice parameters of a = b = 3.886(1) and c = 6.185(2) {angstrom}. The presence of -NH in the nitride phase was verified by Fourier transform infrared spectroscopy (FTIR). Total energy calculations performed using all-electron scalar relativistic density functional theory (DFT) showed that the hydrogen atom in the Th{sub 2}N{sub 2}(NH) prefers to bond with nitrogen atoms occupying 1a Wyckoff positions of the unit cell. Lattice fringe disruptions observed in nanoparticle areas of the nitride species by high-resolution transmission electron microscopic (HRTEM) images also displayed some evidence for the presence of -NH group. As ThO{sub 2} was identified as an impurity, possible reaction mechanisms involving its formation are discussed.

  5. Experimental Station 2-3 | Stanford Synchrotron Radiation Lightsource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 BL2-3 is a bending magnet side station dedicated to X-ray imaging and micro X-ray absorption spectroscopy as well as micro diffraction of biological, material, and geological samples. A Kirkpatrick-Baez mirrors system is used to achieve microfocus with a beam size of ~ 2 x 2 microns. The energy range of the beam line optics at BL 2-3 covers from 5-23 keV, with detection of fluorescent X-rays as low as Si. Beamline 2-3 is equipped with a Vortex silicon drift detector and ionization chambers.

  6. Preparation of 1,1'-dinitro-3,3'-azo-1,2,4-triazole. [1,1'-dinitro-3,3'-azo-1,2,4-triazole

    DOE Patents [OSTI]

    Lee, K.Y.

    1985-03-05

    A new high density composition of matter, 1,1'-dinitro-3,3'-azo-1,2,4-triazole, has been synthesized using inexpensive, commonly available compounds. This compound has been found to be an explosive, and its use as a propellant is anticipated. 1 fig., 1 tab.

  7. Inferior Pancreaticoduodenal Artery Aneurysms Associated with Occlusive Lesions of the Celiac Axis: Diagnosis, Treatment Options, Outcomes, and Review of the Literature

    SciTech Connect (OSTI)

    Flood, Karen Nicholson, Anthony A.

    2013-06-15

    Purpose. To describe the presentation, treatment, and outcomes for 14 patients with aneurysms of the inferior pancreaticoduodenal arteries associated with occlusive lesions of the celiac axis, and to review the literature for similar cases. Methods, Over a period of 12 years, 14 patients (10 women and 4 men) ranging in age from 26 to 50 (mean 46) years were demonstrated to have aneurysms of the inferior pancreaticoduodenal artery origin associated with stenosis or occlusion of the celiac axis. All patients were treated by a combination of surgery and interventional radiology. Results. Outcome data collected between 3 months and 4 years (mean 2 years) demonstrated that all aneurysms remained excluded, and all 14 patients were well. The 49 case reports in the literature confirm the findings of this cohort. Conclusion. In inferior pancreaticoduodenal artery aneurysm resulting from celiac occlusive disease, endovascular treatment is best achieved by stenting the celiac axis and/or embolizing the aneurysm when necessary.

  8. Synthesis ofN-(2-chloro-5-methylthiophenyl)-N'-(3-methyl-thiophenyl)-N'-[3H3]methylguanidine, l brace [3H3]CNS-5161 r brace

    SciTech Connect (OSTI)

    Gibbs, Andrew R.; Morimoto, Hiromi; VanBrocklin, Henry F.; Williams, Philip G.; Biegon, Anat

    2001-09-28

    The preparation of the title compound, [{sup 3}H{sub 3}]CNS-5161, was accomplished in three steps starting with the production of [{sup 3}H{sub 3}]iodomethane (CT{sub 3}I). The intermediate N-[{sup 3}H{sub 3}]methyl-3-(thiomethylphenyl)cyanamide was prepared in 77% yield by the addition of CT{sub 3}I to 3-(thiomethylphenyl)cyanamide, previously treated with sodium hydride. Reaction of this tritiated intermediate with 2-chloro-5-thiomethylaniline hydrochloride formed the guanidine compound [{sup 3}H{sub 3}]CNS-5161. Purification by HPLC gave the desired labeled product in an overall yield of 9% with greater than 96% radiochemical purity and a final specific activity of 66 Ci mmol{sup -1}.

  9. Tuning the DARHT Axis-II linear induction accelerator focusing

    SciTech Connect (OSTI)

    Ekdahl, Carl A.

    2012-04-24

    Flash radiography of large hydrodynamic experiments driven by high explosives is a well-known diagnostic technique in use at many laboratories, and the Dual-Axis Radiography for Hydrodynamic Testing (DARHT) facility at Los Alamos produces flash radiographs of large hydrodynamic experiments. Two linear induction accelerators (LIAs) make the bremsstrahlung radiographic source spots for orthogonal views of each test. The 2-kA, 20-MeV Axis-I LIA creates a single 60-ns radiography pulse. The 1.7-kA, 16.5-MeV Axis-II LIA creates up to four radiography pulses by kicking them out of a longer pulse that has a 1.6-{mu}s flattop. The Axis-II injector, LIA, kicker, and downstream transport (DST) to the bremsstrahlung converter are described. Adjusting the magnetic focusing and steering elements to optimize the electron-beam transport through an LIA is often called 'tuning.' As in all high-current LIAs, the focusing field is designed to be as close to that of the ideal continuous solenoid as physically possible. In ideal continuous solenoidal transport a smoothly varying beam size can easily be found for which radial forces balance, and the beam is said to be 'matched' to the focusing field. A 'mismatched' beam exhibits unwanted oscillations in size, which are a source of free energy that contributes to emittance growth. This is undesirable, because in the absence of beam-target effects, the radiographic spot size is proportional to the emittance. Tuning the Axis-II LIA is done in two steps. First, the solenoidal focusing elements are set to values designed to provide a matched beam with little or no envelope oscillations, and little or no beam-breakup (BBU) instability growth. Then, steering elements are adjusted to minimize the motion of the centroid of a well-centered beam at the LIA exit. This article only describes the design of the tune for the focusing solenoids. The DARHT Axis-II LIA was required to be re-tuned after installing an accelerator cell to replace a failed

  10. High Current-Carrying Capability in c -Axis-Oriented Superconducting...

    Office of Scientific and Technical Information (OSTI)

    High Current-Carrying Capability in c -Axis-Oriented Superconducting MgBsub 2 Thin Films Citation Details In-Document Search Title: High Current-Carrying Capability in c ...

  11. Condensed phase preparation of 2,3-pentanedione

    DOE Patents [OSTI]

    Miller, D.J.; Perry, S.M.; Fanson, P.T.; Jackson, J.E.

    1998-11-03

    A condensed phase process for the preparation of purified 2,3-pentanedione from lactic acid and an alkali metal lactate is described. The process uses elevated temperatures between about 200 to 360 C for heating a reaction mixture of lactic acid and an alkali metal lactate to produce the 2,3-pentanedione in a reaction vessel. The 2,3-pentanedione produced is vaporized from the reaction vessel and condensed with water. 5 figs.

  12. Condensed phase preparation of 2,3-pentanedione

    DOE Patents [OSTI]

    Miller, Dennis J.; Perry, Scott M.; Fanson, Paul T.; Jackson, James E.

    1998-01-01

    A condensed phase process for the preparation of purified 2,3-pentanedione from lactic acid and an alkali metal lactate is described. The process uses elevated temperatures between about 200.degree. to 360.degree. C. for heating a reaction mixture of lactic acid and an alkali metal lactate to produce the 2,3-pentanedione in a reaction vessel. The 2,3-pentanedione produced is vaporized from the reaction vessel and condensed with water.

  13. EVMS Training Snippet: 2.3 The Integrated Program Management...

    Office of Environmental Management (EM)

    EVMS Training Snippet: 2.3 The Integrated Program Management Report (IPMR) This EVMS Training Snippet sponsored by the Office of Project Management (PM) explains the Integrated ...

  14. Energy Emergency Preparedness Quarterly Vol 3, Issue 2 - Spring...

    Broader source: Energy.gov (indexed) [DOE]

    the Energy Assurance page. Energy Emergency Preparedness Quarterly Vol 3 Issue 2 - SpringSummer 2014 More Documents & Publications Energy Emergency Preparedness Quarterly Vol...

  15. Microsoft PowerPoint - 3_FG2 scoping_Ameren

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Meredosia Plant Location - Meredosia, IL Operated by Ameren Energy Resources 4 existing units, 3-coal fired (2 suspended), 1-oil-fired Illinois and Western Coal Truck & barge ...

  16. OVIS 2.0 user%3CU%2B2019%3Es guide.

    SciTech Connect (OSTI)

    Mayo, Jackson R.; Gentile, Ann C.; Brandt, James M.; Thompson, David C.; Roe, Diana C.; Wong, Matthew H.; Pebay, Philippe Pierre

    2009-04-01

    This document describes how to obtain, install, use, and enjoy a better life with OVIS version 2.0. The OVIS project targets scalable, real-time analysis of very large data sets. We characterize the behaviors of elements and aggregations of elements (e.g., across space and time) in data sets in order to detect anomalous behaviors. We are particularly interested in determining anomalous behaviors that can be used as advance indicators of significant events of which notification can be made or upon which action can be taken or invoked. The OVIS open source tool (BSD license) is available for download at ovis.ca.sandia.gov. While we intend for it to support a variety of application domains, the OVIS tool was initially developed for, and continues to be primarily tuned for, the investigation of High Performance Compute (HPC) cluster system health. In this application it is intended to be both a system administrator tool for monitoring and a system engineer tool for exploring the system state in depth. OVIS 2.0 provides a variety of statistical tools for examining the behavior of elements in a cluster (e.g., nodes, racks) and associated resources (e.g., storage appliances and network switches). It calculates and reports model values and outliers relative to those models. Additionally, it provides an interactive 3D physical view in which the cluster elements can be colored by raw element values (e.g., temperatures, memory errors) or by the comparison of those values to a given model. The analysis tools and the visual display allow the user to easily determine abnormal or outlier behaviors. The OVIS project envisions the OVIS tool, when applied to compute cluster monitoring, to be used in conjunction with the scheduler or resource manager in order to enable intelligent resource utilization. For example, nodes that are deemed less healthy, that is, nodes that exhibit outlier behavior in some variable, or set of variables, that has shown to be correlated with future failure

  17. High payload six-axis load sensor

    DOE Patents [OSTI]

    Jansen, John F.; Lind, Randall F.

    2003-01-01

    A repairable high-payload six-axis load sensor includes a table, a base, and at least three shear-pin load transducers removably mounted between the table and the base. Removable mounting permits easy replacement of damaged shear pins. Preferably, the shear-pin load transducers are responsive to shear forces imparted along the two axes perpendicular to an axis of minimum sensitivity characteristic of the transducer. Responsive to an applied shear force, each shear-pin load transducer can produce an electrical signal proportional to the reaction force. The load sensor can further include a structure for receiving the proportional electrical signals and computing the applied load corresponding to the proportional electrical signals. The computed load can be expressed in terms of a three-dimensional XYZ Cartesian coordinate system.

  18. Categorical Exclusion Determinations: B2.3 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    May 18, 2015 CX-100237 Categorical Exclusion Determination High-efficiency Low Global-Warm... Determination Implement SRNL DNFSB 2004-2 Gap Closure Activity CX(s) Applied: B2.3 Date: ...

  19. Comparison of 2D and 3D gamma analyses

    SciTech Connect (OSTI)

    Pulliam, Kiley B.; Huang, Jessie Y.; Howell, Rebecca M.; Followill, David; Kry, Stephen F.; Bosca, Ryan; ODaniel, Jennifer

    2014-02-15

    Purpose: As clinics begin to use 3D metrics for intensity-modulated radiation therapy (IMRT) quality assurance, it must be noted that these metrics will often produce results different from those produced by their 2D counterparts. 3D and 2D gamma analyses would be expected to produce different values, in part because of the different search space available. In the present investigation, the authors compared the results of 2D and 3D gamma analysis (where both datasets were generated in the same manner) for clinical treatment plans. Methods: Fifty IMRT plans were selected from the authors clinical database, and recalculated using Monte Carlo. Treatment planning system-calculated (evaluated dose distributions) and Monte Carlo-recalculated (reference dose distributions) dose distributions were compared using 2D and 3D gamma analysis. This analysis was performed using a variety of dose-difference (5%, 3%, 2%, and 1%) and distance-to-agreement (5, 3, 2, and 1 mm) acceptance criteria, low-dose thresholds (5%, 10%, and 15% of the prescription dose), and data grid sizes (1.0, 1.5, and 3.0 mm). Each comparison was evaluated to determine the average 2D and 3D gamma, lower 95th percentile gamma value, and percentage of pixels passing gamma. Results: The average gamma, lower 95th percentile gamma value, and percentage of passing pixels for each acceptance criterion demonstrated better agreement for 3D than for 2D analysis for every plan comparison. The average difference in the percentage of passing pixels between the 2D and 3D analyses with no low-dose threshold ranged from 0.9% to 2.1%. Similarly, using a low-dose threshold resulted in a difference between the mean 2D and 3D results, ranging from 0.8% to 1.5%. The authors observed no appreciable differences in gamma with changes in the data density (constant difference: 0.8% for 2D vs 3D). Conclusions: The authors found that 3D gamma analysis resulted in up to 2.9% more pixels passing than 2D analysis. It must be noted

  20. Response to comment on "Environmental fate of the next generation refrigerant 2,3,3,3-tetrafluoropropene (HFO-1234yf)

    SciTech Connect (OSTI)

    Im, Jeongdae; Walshe-Langford, Gillian E.; Moon, Ji Won; Loeffler, Frank E.

    2015-06-11

    In this study, refrigerant 2,3,3,3-tetrafluoropropene (HFO-1234yf) has been developed for use in mobile air conditioning systems to replace 1,1,1,2-tetrafluoroethane (HFC-134a), which has a much greater global warming potential.

  1. Structureproperty relations of orthorhombic [(CH{sub 3}){sub 3}NCH{sub 2}COO]{sub 2}(CuCl{sub 2}){sub 3}2H{sub 2}O

    SciTech Connect (OSTI)

    Hausshl, Eiken; Schreuer, Jrgen; Wiehl, Leonore; Paulsen, Natalia

    2014-04-01

    Large single crystals of orthorhombic [(CH{sub 3}){sub 3}NCH{sub 2}COO]{sub 2}(CuCl{sub 2}){sub 3}2H{sub 2}O with dimensions up to 404030 mm{sup 3} were grown from aqueous solutions. The elastic and piezoelastic coefficients were derived from ultrasonic resonance frequencies and their shifts upon variation of pressure, respectively, using the plate-resonance technique. Additionally, the coefficients of thermal expansion were determined between 95 K and 305 K by dilatometry. The elastic behaviour at ambient conditions is dominated by the 2-dimensional network of strong hydrogen bonds within the (001) plane leading to a corresponding pseudo-tetragonal anisotropy of the longitudinal elastic stiffness. The variation of elastic properties with pressure, however, as well as the thermal expansion shows strong deviations from the pseudo-tetragonal symmetry. These deviations are probably correlated with tilts of the elongated tri-nuclear betaineCuCl{sub 2}water complexes. Neither the thermal expansion nor the specific heat capacity gives any hint on a phase transition in the investigated temperature range. - Graphical abstract: Single crystal of orthorhombic [(CH{sub 3}){sub 3}NCH{sub 2}COO]{sub 2}(CuCl{sub 2}){sub 3}2H{sub 2}O. - Highlights: Large single crystals (40 40 30 mm{sup 3}) of [(CH{sub 3}){sub 3}NCH{sub 2}COO]{sub 2}(CuCl{sub 2}){sub 3}2H{sub 2}O were grown. The elastic and piezoelastic coefficients were derived from ultrasonic resonance frequencies. Thermal expansion (95 K305 K) and heat capacity (113 K323 K) were determined. The orthorhombic structure shows pseudo-tetragonal elastic anisotropy at ambient conditions. The crystal structure is stable in the investigated range (11600 bar, 95303 K)

  2. Electron-irradiation induced phase transformation in La{sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3}: La{sup 3+} displacement in a preserved NASICON framework

    SciTech Connect (OSTI)

    Crosnier-Lopez, M.P. . E-mail: marie-pierre.crosnier-lopez@univ-lemans.fr; Barre, M.; Le Berre, F.; Fourquet, J.L.

    2006-08-15

    The La{sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3} NASICON-type compound (S.G. P3-bar - neutron and X-ray diffraction experiments) is investigated by transmission electron microscopy (TEM) technique, selected area electron diffraction (SAED) and high-resolution electron microscopy (HREM), in order to study locally the lanthanum distribution. An irreversible structural transformation (P-bar -bar -bar ->P-bar c-bar ->R-bar -bar -bar ) is observed, without modification of the atomic content and cell size, as soon as the phase is illuminated by the electron beam. The progressive disappearance of the spots which do not check the R conditions on the SAED patterns is clearly shown along two zone axis, [001] and [100]. This transformation implies the displacement of the two La{sup 3+} cations in a preserved classical [Zr{sub 2}(PO{sub 4}){sub 3}]{sup -} network. This interesting behavior is in good agreement with the La{sup 3+} ionic conductivity observed in La{sub 1/3}Zr{sub 2}(PO{sub 4}){sub 3} (4.09x10{sup -7}Scm{sup -1} at 700 deg. C). To our knowledge, this is the first time that a complete TEM study is done on a NASICON-type phase.

  3. Structural characterization of Bi{sub 2}Te{sub 3} and Sb{sub 2}Te{sub 3} as a function of temperature using neutron powder diffraction and extended X-ray absorption fine structure techniques

    SciTech Connect (OSTI)

    Mansour, A. N.; Wong-Ng, W.; Huang, Q.; Tang, W.; Thompson, A.; Sharp, J.

    2014-08-28

    The structure of Bi{sub 2}Te{sub 3} (Seebeck coefficient Standard Reference Material (SRM™ 3451)) and the related phase Sb{sub 2}Te{sub 3} have been characterized as a function of temperature using the neutron powder diffraction (NPD) and the extended X-ray absorption fine structure (EXAFS) techniques. The neutron structural studies were carried out from 20 K to 300 K for Bi{sub 2}Te{sub 3} and from 10 K to 298 K for Sb{sub 2}Te{sub 3}. The EXAFS technique for studying the local structure of the two compounds was conducted from 19 K to 298 K. Bi{sub 2}Te{sub 3} and Sb{sub 2}Te{sub 3} are isostructural, with a space group of R3{sup ¯}m. The structure consists of repeated quintuple layers of atoms, Te2-M-Te1-M-Te2 (where M = Bi or Sb) stacking along the c-axis of the unit cell. EXAFS was used to examine the bond distances and static and thermal disorders for the first three shells of Bi{sub 2}Te{sub 3} and Sb{sub 2}Te{sub 3} as a function of temperature. The temperature dependencies of thermal disorders were analyzed using the Debye and Einstein models for lattice vibrations. The Debye and Einstein temperatures for the first two shells of Bi{sub 2}Te{sub 3} are similar to those of Sb{sub 2}Te{sub 3} within the uncertainty in the data. However, the Debye and Einstein temperatures for the third shell of Bi-Bi are significantly lower than those of the third shell of Sb-Sb. The Einstein temperature for the third shell is consistent with a soft phonon mode in both Bi{sub 2}Te{sub 3} and Sb{sub 2}Te{sub 3}. The lower Einstein temperature of Bi-Bi relative to Sb-Sb is consistent with the lower value of thermal conductivity of Bi{sub 2}Te{sub 3} relative to Sb{sub 2}Te{sub 3}.

  4. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    8 2035 Residential Energy End-Use Expenditure Splits, by Fuel Type ($2010 Billion) (1) Natural Petroleum Gas Distil. LPG Kerosene Total Coal Electricity Total Percent Space Heating (2) 44.3 10.3 7.7 18.6 0.0 16.0 79.0 27.4% Space Cooling (3) 0.0 40.6 40.6 14.1% Water Heating 17.6 1.2 1.2 2.3 17.7 37.6 13.0% Lighting 15.5 15.5 5.4% Refrigeration (4) 17.0 17.0 5.9% Electronics (5) 14.2 14.2 4.9% Wet Cleaning (6) 0.9 10.4 11.3 3.9% Cooking 3.2 0.8 0.8 4.8 8.9 3.1% Computers 8.7 8.7 3.0% Other (7)

  5. Anionic ordering and thermal properties of FeF3·3H2O

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burbano, Mario; Duttine, Mathieu; Borkiewicz, Olaf; Wattiaux, Alain; Demourgues, Alain; Salanne, Mathieu; Groult, Henri; Dambournet, Damien

    2015-09-17

    In this study, iron fluoride tri-hydrate can be used to prepare iron hydroxyfluoride with the Hexagonal-Tungsten-Bronze (HTB) type structure, a potential cathode material for batteries. To understand this phase transformation, a structural description of β-FeF3·3H2O is first performed by means of DFT calculations and Mössbauer spectroscopy. The structure of this compound consists of infinite chains of [FeF6]n and [FeF2(H2O)4]n. The decomposition of FeF3·3H2O induces a collapse and condensation of these chains, which lead to the stabilization, under specific conditions, of a hydroxyfluoride network FeF3-x(OH)x with the HTB structure. The release of H2O and HF was monitored by thermal analysis andmore » physical characterizations during the decomposition of FeF3·3H2O. An average distribution of FeF4(OH)2 distorted octahedra in HTB-FeF3-x(OH)x was obtained subsequent to the thermal hydrolysis/olation of equatorial anionic positions involving F- and H2O. This study provides a clear understanding of the structure and thermal properties of FeF3·3H2O, a material that can potentially bridge the recycling of pickling sludge from the steel industry by preparing battery electrodes.« less

  6. Feasibility and optical performance of one axis three positions sun-tracking polar-axis aligned CPCs for photovoltaic applications

    SciTech Connect (OSTI)

    Tang, Runsheng; Yu, Yamei

    2010-09-15

    A new design concept, called one axis three positions sun-tracking polar-axis aligned CPCs (3P-CPCs, in short), was proposed and theoretically studied in this work for photovoltaic applications. The proposed trough-like CPC is oriented in the polar-axis direction, and the aperture is daily adjusted eastward, southward, and westward in the morning, noon and afternoon, respectively, by rotating the CPC trough, to ensure efficient collection of beam radiation nearly all day. To investigate the optical performance of such CPCs, an analytical mathematical procedure is developed to estimate daily and annual solar gain captured by such CPCs based on extraterrestrial radiation and monthly horizontal radiation. Results show that the acceptance half-angle of 3P-CPCs is a unique parameter to determine their optical performance according to extraterrestrial radiation, and the annual solar gain stays constant if the acceptance half-angle, {theta}{sub a}, is less than one third of {omega}{sub 0,min}, the sunset hour angle in the winter solstice, otherwise decreases with the increase of {theta}{sub a}. For 3P-CPCs used in China, the annual solar gain, depending on the climatic conditions in site, decreased with the acceptance half-angle, but such decrease was slow for the case of {theta}{sub a}{<=}{omega}{sub 0,min}/3, indicating that the acceptance half-angle should be less than one third of {omega}{sub 0,min} for maximizing annual energy collection. Compared to fixed east-west aligned CPCs (EW-CPCs) with a yearly optimal acceptance half-angle, the fixed south-facing polar-axis aligned CPCs (1P-CPCs) with the same acceptance half-angle as the EW-CPCs annually collected about 65-74% of that EW-CPCs did, whereas 3P-CPCs annually collected 1.26-1.45 times of that EW-CPCs collected, indicating that 3P-CPCs were more efficient for concentrating solar radiation onto their coupling solar cells. (author)

  7. Improvements to MARFA Code (released as MARFA version 3.2.3)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Code (released as MARFA version 3.2.3) The software will be used to assess long-term migration of radioactive material and other contaminants beneath the surface of the Earth....

  8. Development of a MEMS dual-axis differential capacitance floating element shear stress sensor

    SciTech Connect (OSTI)

    Barnard, Casey; Griffin, Benjamin

    2015-09-01

    A single-axis MEMS wall shear stress sensor with differential capacitive transduction method is produced. Using a synchronous modulation and demodulation interface circuit, the system is capable of making real time measurements of both mean and fluctuating wall shear stress. A sensitivity of 3.44 mV/Pa is achieved, with linearity in response demonstrated up to testing limit of 2 Pa. Minimum detectable signals of 340 μPa at 100 Hz and 120 μPa at 1 kHz are indicated, with a resonance of 3.5 kHz. Multiple full scale wind tunnel tests are performed, producing spectral measurements of turbulent boundary layers in wind speeds ranging up to 0.5 Ma (18 Pa of mean wall shear stress). The compact packaging allows for minimally invasive installation, and has proven relatively robust over multiple testing events. Temperature sensitivity, likely due to poor CTE matching of packaged materials, is an ongoing concern being addressed. These successes are being directly leveraged into a development plan for a dual-axis wall shear stress sensor, capable of producing true vector estimates at the wall.

  9. Characterization of reactively sputtered c-axis aligned nanocrystalline InGaZnO{sub 4}

    SciTech Connect (OSTI)

    Lynch, David M.; Zhu, Bin; Ast, Dieter G.; Thompson, Michael O.; Levin, Barnaby D. A.; Muller, David A.; Greene, Raymond G.

    2014-12-29

    Crystallinity and texturing of RF sputtered c-axis aligned crystal InGaZnO{sub 4} (CAAC IGZO) thin films were quantified using X-ray diffraction techniques. Above 190?C, nanocrystalline films with an X-ray peak at 2??=?30 (009 planes) developed with increasing c-axis normal texturing up to 310?C. Under optimal conditions (310?C, 10% O{sub 2}), films exhibited a c-axis texture full-width half-maximum of 20. Cross-sectional high-resolution transmission electron microscopy confirmed these results, showing alignment variation of 9 over a 15 15?nm field of view and indicating formation of much larger aligned domains than previously reported. At higher deposition temperatures, c-axis alignment was gradually lost as polycrystalline films developed.

  10. Categorical Exclusion Determinations: B3.2 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Categorical Exclusion Determinations: B3.2 Existing Regulations B3.2: Aviation activities Aviation activities for survey, monitoring, or security purposes that comply with Federal Aviation Administration regulations. DOCUMENTS AVAILABLE FOR DOWNLOAD February 25, 2016 CX-100511 Categorical Exclusion Determination Discovering Blind Geothermal Systems in the Great Basin Region: An Integrated Geologic and Geophysical Approach for Establishing Geothermal Play Fairways Award Number: DE-EE0006731

  11. SSQ V3 N2_Final_13aug13.indd

    National Nuclear Security Administration (NNSA)

    2 * August 2013 Message from the Assistant Deputy Administrator for Research, Development, Test Capabilities and Evaluation, Chris Deeney Defense Programs Stockpile Stewardship in Action Volume 3, Number 2 Inside this Issue 2 Roadrunner-On the Road to Trinity 3 The Cielo Petascale Capability Supercomputer: Providing Large-Scale Computing for Stockpile Stewardship 7 Sequoia, NNSA's Most Powerful Computer, Prepares for Classified Work 8 Toward Exascale with Co-design and Proxy Applications U p to

  12. Offshore Ambitions for the Vertical-Axis Wind Turbine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ambitions for the Vertical-Axis Wind Turbine - Sandia Energy Energy Search Icon Sandia ... Offshore Ambitions for the Vertical-Axis Wind Turbine HomeEnergy, News, News & Events, ...

  13. Luminescence improvement in Pr{sup 3+} and Gd{sup 3+} activated Sr{sub 2}Mg(BO{sub 3}){sub 2} inorganic phosphor

    SciTech Connect (OSTI)

    Gawande, A.B.; Sonekar, R.P.; Omanwar, S.K.

    2014-12-15

    Highlights: • Sr{sub 2}Mg(BO{sub 3}){sub 2} doped Gd{sup 3+} and Pr{sup 3+} have been synthesized by solution combustion synthesis technique. • Effect of doping concentration of Gd{sup 3+} and Pr{sup 3+} on the luminescence of synthesized material is discussed. • Effect of charge compensation by Li{sup +}, Na{sup +} and K{sup +} on emission intensity is studied in detail. • Efficient energy transfer from Pr{sup 3+} to Gd{sup 3+} in Sr{sub 2}Mg(BO{sub 3}){sub 2} was observed. • Optimum concentration and critical transfer distance for optimum concentration have been determined. - Abstract: The photoluminescence properties of (Sr{sub 1−x}Pr{sub x}){sub 2}Mg(BO{sub 3}){sub 2}; (Sr{sub 1−2x}Pr{sub x}M{sub x}){sub 2}Mg(BO{sub 3}){sub 2,} (M = Li, Na, K); (Sr{sub 1−x}Gd{sub x}){sub 2}Mg(BO{sub 3}){sub 2}; (Sr{sub 1−2x}Gd{sub x}M{sub x}){sub 2}Mg(BO{sub 3}){sub 2}, (M = Li, Na, K) and (Sr{sub 1−4x}Pr{sub x}Gd{sub x}Na{sub 2x}){sub 2}Mg(BO{sub 3}){sub 2} inorganic phosphors prepared by solution combustion synthesis technique are discussed. The structure of the prepared phosphor characterized using Thermogravimetric–differential thermal analysis, X-ray diffraction and fourier transform-infrared. Scanning electron microscopy images of the prepared materials show irregular grains with agglomerate phenomena. Photoluminescence properties were studied at room temperature. Optimum concentration and critical transfer distance of the synthesized phosphors were determined.

  14. Three-axis asymmetric radiation detector system

    DOE Patents [OSTI]

    Martini, Mario Pierangelo (Oak Ridge, TN); Gedcke, Dale A. (Oak Ridge, TN); Raudorf, Thomas W. (Oak Ridge, TN); Sangsingkeow, Pat (Knoxville, TN)

    2000-01-01

    A three-axis radiation detection system whose inner and outer electrodes are shaped and positioned so that the shortest path between any point on the inner electrode and the outer electrode is a different length whereby the rise time of a pulse derived from a detected radiation event can uniquely define the azimuthal and radial position of that event, and the outer electrode is divided into a plurality of segments in the longitudinal axial direction for locating the axial location of a radiation detection event occurring in the diode.

  15. Crystal Splitting in the Growth of Bi2S3

    SciTech Connect (OSTI)

    Tang, Jing; Alivisatos, A. Paul

    2006-06-15

    Novel Bi{sub 2}S{sub 3} nanostructures with a sheaf-like morphology are obtained via reaction of bismuth acetate-oleic acid complex with elemental sulfur in 1-octadecence. We propose these structures form by the splitting crystal growth mechanism, which is known to account for the morphology some mineral crystals assume in nature. By controlling the synthetic parameters, different forms of splitting, analogous to observed in minerals, are obtained in our case of Bi{sub 2}S{sub 3}. These new and complex Bi{sub 2}S{sub 3} nanostructures are characterized by TEM, SEM, XRD and ED.

  16. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    5 2010 Residential Energy End-Use Expenditure Splits, by Fuel Type ($2010 Billion) (1) Natural Petroleum Gas Distil. LPG Kerosene Total Coal Electricity Total Percent Space Heating (2) 38.7 11.2 8.0 19.8 0.0 14.3 72.9 28.9% Space Cooling (3) 0.0 35.4 35.4 14.0% Water Heating (4) 14.3 2.1 2.0 4.0 14.2 32.6 12.9% Lighting 22.6 22.6 9.0% Refrigeration (5) 14.9 14.9 5.9% Electronics (6) 17.8 17.8 7.1% Cooking 2.4 0.8 0.8 6.0 9.2 3.7% Wet Cleaning (7) 0.6 10.7 11.3 4.5% Computers 5.6 5.6 2.2% Other

  17. Selective interlayer ferromagnetic coupling between the Cu spins in YBa2Cu3O7–x grown on top of La0.7Ca0.3MnO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, S. W.; Wray, L. Andrew; Jeng, Horng -Tay; Tra, V. T.; Lee, J. M.; Langner, M. C.; Chen, J. M.; Roy, S.; Chu, Y. H.; Schoenlein, R. W.; et al

    2015-11-17

    Studies to date on ferromagnet/d-wave superconductor heterostructures focus mainly on the effects at or near the interfaces while the response of bulk properties to heterostructuring is overlooked. Here we use resonant soft x-ray scattering spectroscopy to reveal a novel c-axis ferromagnetic coupling between the in-plane Cu spins in YBa2Cu3O7–x (YBCO) superconductor when it is grown on top of ferromagnetic La0.7Ca0.3MnO3 (LCMO) manganite layer. This coupling, present in both normal and superconducting states of YBCO, is sensitive to the interfacial termination such that it is only observed in bilayers with MnO2 but not with La0.7Ca0.3O interfacial termination. Thus, such contrasting behaviors,more » we propose, are due to distinct energetic of CuO chain and CuO2 plane at the La0.7Ca0.3O and MnO2 terminated interfaces respectively, therefore influencing the transfer of spin-polarized electrons from manganite to cuprate differently. Our findings suggest that the superconducting/ferromagnetic bilayers with proper interfacial engineering can be good candidates for searching the theorized Fulde-Ferrel-Larkin-Ovchinnikov (FFLO) state in cuprates and studying the competing quantum orders in highly correlated electron systems.« less

  18. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    6 2015 Residential Energy End-Use Expenditure Splits, by Fuel Type ($2010 Billion) (1) Natural Petroleum Gas Distil. LPG Kerosene Total Coal Electricity Total Percent Space Heating (2) 35.0 13.0 8.1 21.6 0.0 14.0 70.6 29.2% Space Cooling (3) 0.0 33.8 33.8 14.0% Water Heating 13.5 1.9 1.5 3.4 15.8 32.7 13.5% Lighting 17.6 17.6 7.3% Refrigeration (4) 15.0 15.0 6.2% Electronics (5) 10.9 10.9 4.5% Wet Cleaning (6) 0.6 10.8 11.4 4.7% Cooking 2.2 0.9 0.9 3.8 6.8 2.8% Computers 6.3 6.3 2.6% Other (7)

  19. Synthesis and structure of triphenylbismuth bis(3-phenylprop-2-enoate)

    SciTech Connect (OSTI)

    Andreev, P. V. Somov, N. V.; Kalistratova, O. S.; Gushchin, A. V.; Chuprunov, E. V.

    2015-07-15

    The newly synthesized triphenylbismuth bis(3-phenylprop-2-enoate) was studied by X-ray diffraction and by IR, UV, and NMR spectroscopy. The crystals are monoclinic, sp. gr. C2/c, Z = 4, a = 13.2820(4) Å, b = 21.3750(2) Å, c = 12.2407(2) Å, β = 119.936(1)°. The coordination polyhedron of the bismuth atom can be described as a distorted pentagonal bipyramid.

  20. Tax Deduction Qualified Software: TRACE Version 6.3.2

    Office of Energy Efficiency and Renewable Energy (EERE)

    Provides required documentation that the TRACE version 6.3.2 meets Internal Revenue Code §179D (c)(1) and (d) Regulations Notice 2006-52, Section 6 requirements as amplified by Notice 2008-40, Section 4 requirements.

  1. Microsoft Word - MP 5 2 Final Rev 3

    Office of Environmental Management (EM)

    Form 4.1-1 U. S. Department of Energy Carlsbad Field Office MANAGEMENT PROCEDURE CBFO MP 5.2, Rev. 3 Effective: 15 November 2010 SUBJECT: TRU WASTE SITE CERTIFICATION...

  2. Strip2CubeFace user%3CU%2B2019%3Es manual.

    SciTech Connect (OSTI)

    Forden, Geoffrey Ethan

    2013-03-01

    Commercial Off The Shelf (COTS) software for producing linked virtual tours based on 360 degree panoramas are becoming more and more available. However, the best current products for taking the images, stitching them into 360 degree panoramas, and then linking them together into complex virtual tours require different and incompatible input and output formats. This program is designed to bridge the gap between the iPix Interactive Studio export format, which consists of a single JPEG with the six faces of a cube connected horizontally, with the six individual JPEGs needed to be imported into Panotour Pro software. This report describes how to use the software program Strip2CubeFace, which takes the cube-strip JPEG exported from iPix Studio and coverts it into six JPEGs representing the six cube faces that Panotour Pro imports. As such, it represents a necessary link between the two COTS software programs key to making virtual tours quickly and easily. It becomes one member of the suite of software programs known as %E2%80%9CRaPP-TOURS%E2%80%9D or Rapid Processing of PanoTours Software necessary to simulate managed access and other permission requesting arms control-type training exercises.

  3. Energy Emergency Preparedness Quarterly Vol 2, Issue 3 - July 2013 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Emergency Preparedness Quarterly Vol 2, Issue 3 - July 2013 Energy Emergency Preparedness Quarterly Vol 2, Issue 3 - July 2013 The Energy Emergency Preparedness Quarterly is published by the Infrastructure Security and Energy Restoration (ISER) Division of the Office of Electricity Delivery and Energy Reliability (OE) to highlight a few of the OE/ISER energy preparedness activities that occur each quarter. For more information about how OE is protecting and

  4. The Role of Anti-Phase Domains in InSb-Based Structures Grown on On-Axis and Off-Axis Ge Substrates

    SciTech Connect (OSTI)

    Debnath, M. C.; Mishima, T. D.; Santos, M. B.; Hossain, K.; Holland, O. W.

    2011-12-26

    Anti-phase domains form in InSb epilayers and InSb/Al{sub 0.20}In{sub 0.80}Sb single quantum wells when grown upon on-axis (001) Ge substrates by molecular beam epitaxy. Domain formation is partially suppressed through growth on Ge substrates with surfaces that are several degrees off the (001) or (211) axis. By using off-axis Ge substrates, room-temperature electron mobilities increased to {approx}60,000 cm{sup 2}/V-s and {approx}14,000 cm{sup 2}/V-s for a 4.0-{mu}m-thick InSb epilayer and a 25-nm InSb quantum well, respectively.

  5. Buildings Energy Data Book: 3.2 Commercial Sector Characteristics

    Buildings Energy Data Book [EERE]

    4 Share of Commercial Floorspace, by Census Region and Vintage, as of 2003 (Percent) Region Prior to 1960 1960 to 1989 1990 to 2003 Total Northeast 9% 8% 3% 20% Midwest 8% 11% 6% 25% South 5% 18% 14% 37% West 3% 9% 5% 18% 100% Source(s): EIA, 2003 Commercial Buildings Energy Consumption Survey: Building Characteristics Tables, Oct. 2006, Table A2, p. 3-4

  6. Pressure-induced isostructural phase transition of a metal-organic framework Co2(4,4'-bpy)3(NO3)4·xH2O

    SciTech Connect (OSTI)

    Zhou, Mi; Wang, Kai; Men, Zhiwei; Sun, Chenglin; Li, Zhanlong; Liu, Bingbing; Zou, Guangtian; Zou, Bo

    2014-07-17

    Based on the 4,4'-bipyridine organic linker, metal–organic frameworks of Co2(4,4'-bpy)3(NO3)4·xH2O (CB-MOF) have been prepared. The pressure-dependent structure evolution of CB-MOF has been investigated up to 11 GPa. An isostructural phase transition was observed at about 6 GPa followed by negative compressibility along the b axis.

  7. Spatial potential ripples of azimuthal surface modes in topological insulator Bi2Te3 nanowires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Muñoz Rojo, Miguel; Zhang, Yingjie; Manzano, Cristina V.; Alvaro, Raquel; Gooth, Johannes; Salmeron, Miquel; Martin-Gonzalez, Marisol

    2016-01-11

    Topological insulators (TI) nanowires (NW) are an emerging class of structures, promising both novel quantum effects and potential applications in low-power electronics, thermoelectrics and spintronics. However, investigating the electronic states of TI NWs is complicated, due to their small lateral size, especially at room temperature. Here, we perform scanning probe based nanoscale imaging to resolve the local surface potential landscapes of Bi2Te3 nanowires (NWs) at 300 K. We found equipotential rings around the NWs perimeter that we attribute to azimuthal 1D modes. Along the NW axis, these modes are altered, forming potential ripples in the local density of states, duemore » to intrinsic disturbances. Potential mapping of electrically biased NWs enabled us to accurately determine their conductivity which was found to increase with the decrease of NW diameter, consistent with surface dominated transport. Finally, our results demonstrate that TI NWs can pave the way to both exotic quantum states and novel electronic devices.« less

  8. ITOUGH2 command reference. Version 3.1

    SciTech Connect (OSTI)

    Finsterle, S.

    1997-04-01

    This report contains a detailed description of all ITOUGH2 commands. It complements the ITOUGH2 User`s Guide and the collection of ITOUGH2 sample problems. ITOUGH2 is a program for parameter estimation, sensitivity analysis, and uncertainty propagation analysis. It is based on the TOUGH2 simulator for non-isothermal multiphase flow in fractured and porous media. Extensive experience in using TOUGH2 is a prerequisite for using ITOUGH2. The preparation of an input file for TOUGH2 or its derivatives is described in separate manuals and is not part of this report. The ITOUGH2 user`s guide summarizes the inverse modeling theory pertaining to ITOUGH2, and describes the program output. Furthermore, information about code architecture and installation are given. In Chapter 2 of this report, a brief summary of inverse modeling theory is given to restate the main concepts implemented in ITOUGH2 and to introduce certain definitions. Chapter 3 introduces the basic concepts of the ITHOUGH2 input language and the main structure of an ITOUGH2 input file. Chapter 4, the main part of this report, provides detailed descriptions of each ITOUGH2 command in alphabetical order. It is complemented by a command index in Appendix B in which the commands are given in logical order. The content of Chapter 4 is also available on-line using command it2help. Chapter 5 describes the usage of the UNIX script files for executing, checking, and terminating ITOUGH2 simulations.

  9. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    7 2025 Residential Energy End-Use Expenditure Splits, by Fuel Type ($2010 Billion) (1) Natural Petroleum Gas Distil. LPG Kerosene Total Coal Electricity Total Percent Space Heating (2) 39.7 11.5 7.8 19.9 0.0 15.0 74.5 28.6% Space Cooling (3) 0.0 36.2 36.2 13.9% Water Heating 16.0 1.4 1.3 2.7 17.1 35.9 13.8% Lighting 15.2 15.2 5.8% Refrigeration (4) 15.5 15.5 6.0% Electronics (5) 12.0 12.0 4.6% Wet Cleaning (6) 0.8 9.8 10.5 4.1% Cooking 2.7 0.8 0.8 4.3 7.8 3.0% Computers 7.7 7.7 2.9% Other (7)

  10. 2D?3D polycatenated and 3D?3D interpenetrated metalorganic frameworks constructed from thiophene-2,5-dicarboxylate and rigid bis(imidazole) ligands

    SciTech Connect (OSTI)

    Erer, Hakan; Ye?ilel, Okan Zafer; Ar?c?, Mrsel; Keskin, Seda; Bykgngr, Orhan

    2014-02-15

    Hydrothermal reactions of rigid 1,4-bis(imidazol-1-yl)benzene (dib) and 1,4-bis(imidazol-1-yl)-2,5-dimethylbenzene (dimb) with deprotonated thiophene-2,5-dicarboxylic acid (H{sub 2}tdc) in the presence of Zn(II) and Cd(II) salts in H{sub 2}O produced three new metalorganic frameworks, namely, [Zn(-tdc)(H{sub 2}O)(-dib)]{sub n} (1), [Cd(-tdc)(H{sub 2}O)(-dib)]{sub n} (2), and ([Cd{sub 2}({sub 3}-tdc){sub 2}(-dimb){sub 2}](H{sub 2}O)){sub n}(3). These MOFs were characterized by FT-IR spectroscopy, elemental, thermal (TG, DTA, DTG and DSC), and single-crystal X-ray diffraction analyses. Isomorphous complexes 1 and 2 reveal polycatenated 2D+2D?3D framework based on an undulated (4,4)-sql layer. Complex 3 exhibits a new 4-fold interpenetrating 3D framework with the point symbol of 6{sup 6}. Molecular simulations were used to assess the potentials of the complexes for H{sub 2} storage application. Moreover, these coordination polymers exhibit blue fluorescent emission bands in the solid state at room temperature. - Graphical abstract: In this study, hydrothermal reactions of rigid 1,4-bis(imidazol-1-yl)benzene (dib) and 1,4-bis(imidazol-1-yl)-2,5-dimethylbenzene (dimb) with deprotonated thiophene-2,5-dicarboxylic acid (H{sub 2}tdc) in the presence of Zn(II) and Cd(II) salts in H{sub 2}O produced three new metalorganic frameworks. Isomorphous complexes 1 and 2 reveal polycatenated 2D+2D?3D framework based on an undulated (4,4)-sql layer. Complex 3 exhibits a new 4-fold interpenetrating 3D framework with the point symbol of 6{sup 6}. Molecular simulations were used to assess the potentials of the complexes for H{sub 2} storage application. These coordination polymers exhibit blue fluorescent emission bands in the solid state at room temperature. Display Omitted - Highlights: Complexes 1 and 2 display polycatenated 2D+2D?3D framework. Complex 3 exhibits a new 4-fold interpenetrating 3D framework. Complex 1 adsorbs the highest amount of H{sub 2} at 100 bar and

  11. Thermal Reactions of Uranium Metal, UO2, U3O8, UF4, and UO2F2 with NF3 to Produce UF6

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Scheele, Randall D.; Kozelisky, Anne E.; Edwards, Matthew K.

    2009-11-01

    he objective of this paper is to demonstrate that NF3 fluorinates uranium metal, UO2, UF4, UO3, U3O8, and UO2F22H2O to produce the volatile UF6 at temperatures between 100 and 500?C. Thermogravimetric reaction profiles are described that reflect changes in the uranium oxidation state and discrete chemical speciation. Differences in the onset temperatures for each system indicate that NF3-substrate interactions are important for the temperature at which NF3 reacts: U metal > UO3 > UO2 > UO2F2 > UF4 and in fact may indicate different fluorination mechanisms for these various substrates. These studies demonstrate that NF3 is a potential replacement fluorinating agent in the existing nuclear fuel cycle and in oft-proposed actinide volatility reprocessing.

  12. High thermal stability of La2O3 and CeO2-stabilized tetragonal ZrO2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Shichao; Xie, Hong; Lin, Yuyuan; Poeppelmeier, Kenneth R.; Li, Tao; Winans, Randall E.; Cui, Yanran; Ribeiro, Fabio H.; Canlas, Christian P.; Elam, Jeffrey W.; et al

    2016-02-15

    Catalyst support materials of tetragonal ZrO2, stabilized by either La2O3 (La2O3-ZrO2) or CeO2 (CeO2-ZrO2), were synthesized under hydrothermal conditions at 200 °C with NH4OH or tetramethylammonium hydroxide as the mineralizer. From In Situ synchrotron powder X-ray diffraction and small-angle X-ray scattering measurements, the calcined La2O3-ZrO2 and CeO2-ZrO2 supports were nonporous nanocrystallites that exhibited rectangular shapes with thermal stability up to 1000 °C in air. These supports had an average size of ~10 nm and a surface area of 59-97 m2/g. The catalysts Pt/La2O3-ZrO2 and Pt/CeO2-ZrO2 were prepared by using atomic layer deposition with varying Pt loadings from 6.3-12.4 wt %.more » Mono-dispersed Pt nanoparticles of ~3 nm were obtained for these catalysts. As a result, the incorporation of La2O3 and CeO2 into the t-ZrO2 structure did not affect the nature of the active sites for the Pt/ZrO2 catalysts for the water-gas-shift (WGS) reaction.« less

  13. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    3 Residential Aggregate Energy Expenditures, by Year and Major Fuel Type ($2010 Billion) (1) Electricity Total 1980 158.5 1981 164.0 1982 172.3 1983 176.1 1984 178.5 1985 176.8 1986 169.2 1987 167.1 1988 170.1 1989 172.8 1990 168.2 1991 169.9 1992 166.7 1993 175.6 1994 174.9 1995 172.7 1996 181.8 1997 180.0 1998 173.5 1999 174.0 2000 192.8 2001 203.3 2002 192.1 2003 208.8 2004 215.1 2005 236.7 2006 240.0 2007 246.1 2008 259.6 2009 241.6 2010 251.8 2011 251.3 2012 247.1 2013 240.3 2014 239.4 2015

  14. RF generation in the DARHT Axis-II beam dump

    SciTech Connect (OSTI)

    Ekdahl, Carl A. Jr.

    2012-05-03

    We have occasionally observed radio-frequency (RF) electromagnetic signals in the downstream transport (DST) of the second axis linear induction accelerator (LIA) at the dual-axis radiographic hydrodynamic testing (DARHT) facility. We have identified and eliminated some of the sources by eliminating the offending cavities. However, we still observe strong RF in the range 1 GHz t0 2 GHz occurring late in the {approx}2-{micro}s pulse that can be excited or prevented by varying the downstream tune. The narrow frequency width (<0.5%) and near exponential growth at the dominant frequency is indicative of a beam-cavity interaction, and electro-magnetic simulations of cavity structure show a spectrum rich in resonances in the observed frequency range. However, the source of beam produced RF in the cavity resonance frequency range has not been identified, and it has been the subject of much speculation, ranging from beam-plasma or beam-ion instabilities to unstable cavity coupling.

  15. 3-hydroxy-2(1H)-pyridinone chelating agents

    DOE Patents [OSTI]

    Raymond, K.; Xu, J.

    1999-04-06

    Disclosed is a series of improved chelating agents and the chelates formed from these agents, which are highly effective upon both injection and oral administration. Several of the most effective are of low toxicity. These chelating agents incorporate within their structure 3-hydroxy-2-pyridinone (3,2-HOPO) moieties with a substituted carbamoyl group ortho to the hydroxy group of the hydroxypyridinone ring. The electron-withdrawing carbamoyl group increases the acidity, as well as the chemical stability towards oxidation and reduction, of the hydroxypyridinones. In the metal complexes of the chelating agents, the amide protons form very strong hydrogen bonds with the adjacent HOPO oxygen donor, making these complexes very stable at physiological conditions. The terminal N-substituents provide a certain degree of lipophilicity to the 3,2-HOPO, increasing oral activity. 2 figs.

  16. Method for preparation of 7-hydroxy-1,2,3,4-tetrahydroquinoline from 1,2,3,4-tetrahydroquinoline

    DOE Patents [OSTI]

    Field, G.; Hammond, P.R.

    1994-02-01

    Methods for the efficient preparation of 7-hydroxy-1,2,3,4-tetrahydroquinoline include a first method in which the acylation of m-aminophenol obtains a lactam which is reduced to give the desired quinoline and a second method in which tetrahydroquinoline is nitrated and hydrogenated and then hydrolyzed to obtain the desire quinoline. 7-hydroxy-1,2,3,4-tetrahydroquinoline is used in the efficient synthesis of four lasing dyes of the rhodamine class.

  17. Method for preparation of 7-hydroxy-1,2,3,4-tetrahydroquinoline from 1,2,3,4-tetrahydroquinoline

    DOE Patents [OSTI]

    Field, George; Hammond, Peter R.

    1994-01-01

    Methods for the efficient preparation of 7-hydroxy-1,2,3,4-tetrahydroquinoline include a first method in which the acylation of m-aminophenol obtains a lactam which is reduced to give the desired quinoline and a second method in which tetrahydroquinoline is nitrated and hydrogenated and then hydrolyzed to obtain the desire quinoline. 7-hydroxy-1,2,3,4-tetrahydroquinoline is used in the efficient synthesis of four lasing dyes of the rhodamine class.

  18. 3-hydroxy-2(1H)-pyridinone chelating agents

    DOE Patents [OSTI]

    Raymond, K.N.; Xu, J.

    1997-04-29

    Disclosed is a series of improved metal chelating agents, which are highly effective upon both injection and oral administration; several of the most effective are of low toxicity. These chelating agents incorporate within their structure 1-hydroxy-2-pyridinone (1,2-HOPO) and 3-hydroxy-2-pyridinone (3,2-HOPO) moieties with a substituted carbamoyl group ortho to the hydroxy or oxo groups of the hydroxypyridinone ring. The electron-withdrawing carbamoyl group increases the acidity of the hydroxypyridinones. In the metal complexes of the chelating agents, the amide protons form very strong hydrogen bonds with its adjacent HOPO oxygen donor, making these complexes very stable at physiological conditions. The terminal N-substituents provides a certain degree of lipophilicity to the 3,2-HOPO, increasing oral activity. Also disclosed is a method of making the chelating agents and a method of producing a known compound, 3-hydroxy-1-alkyl-2(1H)pyridinone, used as a precursor to the chelating agent, safely and in large quantities. 2 figs.

  19. Electronic structure, irreversibility line and magnetoresistance of Cu0.3Bi2Se3 superconductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hemian, Yi; Gu, Genda; Chen, Chao -Yu; Sun, Xuan; Xie, Zhuo -Jin; Feng, Ya; Liang, Ai -Ji; Peng, Ying -Ying; He, Shao -Long; Zhao, Lin; et al

    2015-06-01

    CuxBi2Se3 is a superconductor that is a potential candidate for topological superconductors. We report our laser-based angle-resolved photoemission measurement on the electronic structure of the CuxBi2Se3 superconductor, and a detailed magneto-resistance measurement in both normal and superconducting states. We find that the topological surface state of the pristine Bi2Se3 topological insulator remains robust after the Cu-intercalation, while the Dirac cone location moves downward due to electron doping. Detailed measurements on the magnetic field-dependence of the resistance in the superconducting state establishes an irreversibility line and gives a value of the upper critical field at zero temperature of ~4000 Oe formore » the Cu0.3Bi2Se3 superconductor with a middle point Tc of 1.9K. The relation between the upper critical field Hc2 and temperature T is different from the usual scaling relation found in cuprates and in other kinds of superconductors. Small positive magneto-resistance is observed in Cu0.3Bi2Se3 superconductors up to room temperature. As a result, these observations provide useful information for further study of this possible candidate for topological superconductors.« less

  20. Vertical-Axis Wind Turbine Mesh Generator

    SciTech Connect (OSTI)

    2014-01-24

    VAWTGen is a mesh generator for creating a finite element beam mesh of arbitrary vertical-axis wind turbines (VAWT). The software accepts input files specifying tower and blade structural and aerodynamic descriptions and constructs a VAWT using a minimal set of inputs. VAWTs with an arbitrary number of blades can be constructed with or without a central tower. Strut connections between the tower and blades can be specified in an arbitrary manner. The software also facilitates specifying arbitrary joints between structural components and concentrated structural tenns (mass and stiffness). The output files which describe the VAWT configuration are intended to be used with the Offshore Wind ENergy Simulation (OWENS) Toolkit software for structural dynamics analysis of VAWTs. Furthermore, VAWTGen is useful for visualizing output from the OWENS analysis software.

  1. Vertical-Axis Wind Turbine Mesh Generator

    Energy Science and Technology Software Center (OSTI)

    2014-01-24

    VAWTGen is a mesh generator for creating a finite element beam mesh of arbitrary vertical-axis wind turbines (VAWT). The software accepts input files specifying tower and blade structural and aerodynamic descriptions and constructs a VAWT using a minimal set of inputs. VAWTs with an arbitrary number of blades can be constructed with or without a central tower. Strut connections between the tower and blades can be specified in an arbitrary manner. The software also facilitatesmore » specifying arbitrary joints between structural components and concentrated structural tenns (mass and stiffness). The output files which describe the VAWT configuration are intended to be used with the Offshore Wind ENergy Simulation (OWENS) Toolkit software for structural dynamics analysis of VAWTs. Furthermore, VAWTGen is useful for visualizing output from the OWENS analysis software.« less

  2. Two-axis tracking solar collector mechanism

    DOE Patents [OSTI]

    Johnson, K.C.

    1992-12-08

    This invention is a novel solar tracking mechanism incorporating a number of practical features that give it superior environmental resilience and exceptional tracking accuracy. The mechanism comprises a lightweight space-frame assembly supporting an array of point-focus Fresnel lenses in a two-axis tracking structure. The system is enclosed under a glass cover which isolates it from environmental exposure and enhances tracking accuracy by eliminating wind loading. Tracking accuracy is also enhanced by the system's broad-based tracking support. The system's primary intended application would be to focus highly concentrated sunlight into optical fibers for transmission to core building illumination zones, and the system may also have potential for photovoltaic or photothermal solar energy conversion. 16 figs.

  3. Two-axis tracking solar collector mechanism

    DOE Patents [OSTI]

    Johnson, Kenneth C.

    1992-01-01

    This invention is a novel solar tracking mechanism incorporating a number of practical features that give it superior environmental resilience and exceptional tracking accuracy. The mechanism comprises a lightweight space-frame assembly supporting an array of point-focus Fresnel lenses in a two-axis tracking structure. The system is enclosed under a glass cover which isolates it from environmental exposure and enhances tracking accuracy by eliminating wind loading. Tracking accuracy is also enhanced by the system's broad-based tracking support. The system's primary intended application would be to focus highly concentrated sunlight into optical fibers for transmission to core building illumination zones, and the system may also have potential for photovoltaic or photothermal solar energy conversion.

  4. Two-axis tracking solar collector mechanism

    DOE Patents [OSTI]

    Johnson, Kenneth C.

    1990-01-01

    This invention is a novel solar tracking mechanism incorporating a number of practical features that give it superior environmental resilience and exceptional tracking accuracy. The mechanism comprises a lightweight space-frame assembly supporting an array of point-focus Fresnel lenses in a two-axis tracking structure. The system is enclosed under a glass cover which isolates it from environmental exposure and enhances tracking accuracy by eliminating wind loading. Tracking accuracy is also enhanced by the system's broad-based tracking support. The system's primary intended application would be to focus highly concentrated sunlight into optical fibers for transmission to core building illumination zones, and the system may also have potential for photovoltaic or photothermal solar energy conversion.

  5. 3-hydroxy-2(1H)-pyridinone chelating agents

    DOE Patents [OSTI]

    Raymond, Kenneth N.; Xu, Jide

    1997-01-01

    Disclosed is a series of improved metal chelating agents, which are highly effective upon both injection and oral administration; several of the most effective are of low toxicity. These chelating agents incorporate within their structure 1-hydroxy-2-pyridinone (1,2-HOPO) and 3-hydroxy-2-pyridinone (3,2-HOPO) moieties with a substituted carbamoyl group ortho to the hydroxy or oxo groups of the hydroxypyridinone ring. The electron-withdrawing carbamoyl group increases the acidity of the hydroxypyridinones. In the metal complexes of said chelating agents, the amide protons form very strong hydrogen bonds with its adjacent HOPO oxygen donor, making these complexes very stable at physiological conditions. The terminal N-substituents provides a certain degree of lipophilicity to said 3,2-HOPO, increasing oral activity. Also disclosed is a method of making the chelating agents and a method of producing a known compound, 3-hydroxy-1-alkyl-2(1H)pyridinone, used as a precursor to the chelating agent, safely and in large quantities.

  6. Spectral properties of a novel laser crystal Y3(In,Ga)2Ga3O12:Cr(3+)--translation

    SciTech Connect (OSTI)

    Li, Y.; Tang, H.; Hang, Y.; Chen, S.

    1991-11-19

    Spectral properties of a novel phonon terminated laser crystal Yttrium(3)(Indium, Gallium)(2)Gallium(3)Oxygen(12): Chromium(3+) grown by the flux method are reported for the first time. The results show that the spectral properties of this novel crystal are compatible with those of Gadolinium(3)(Selenium, Gallium)(3)Gallium(3)Oxygen(12): Chromium(3+) and is a potential ambient temperature tunable laser crystal. Gadolinium(3)(Scandium, Gallium)(2)Gallium(3)Oxygen(12): Chromium(3+) (shortened to GSGG:CR3+) is a type of phonon-terminated laser crystal with excellent capabilities. It has a relatively weak crystal field and relatively strong electron-phonon coupling. At room temperatures a strong terminal phonon emission spectrum with a half width of about 100 nm can be observed. At the same time, experimentally at room temperatures, a wide band continuous tunable laser emission has been observed. Since it has been reported, a great deal of attention has been paid to it. However, since Scandium is rare and expensive its applications are limited.

  7. Preparation of 3,3'-azobis(6-amino-1,2,4,5-tetrazine)

    DOE Patents [OSTI]

    Hiskey, Michael A.; Chavez, David E.; Naud, Darren

    2002-01-01

    The compound of the structure ##STR1## where a, b, c, d and e are 0 or 1 and a+b+c+d+e is from 0 to 5 is disclosed together with the species 3,3'-azobis(6-amino-1,2,4,5-tetrazine) and a process of preparing such compounds.

  8. Preparation of 1,1'-dinitro-3,3'-azo-1,2,4-triazole

    SciTech Connect (OSTI)

    Lee, Kien-Yin

    1986-01-01

    A new high density composition of matter, 1,1'-dinitro-3,3'-azo-1,2,4-triazole, has been synthesized using inexpensive, commonly available compounds. This compound has been found to be an explosive, and its use as a propellant is anticipated.

  9. Buildings Energy Data Book: 3.2 Commercial Sector Characteristics

    Buildings Energy Data Book [EERE]

    1 Total Commercial Floorspace and Number of Buildings, by Year 1980 50.9 (1) N.A. 3.1 (3) 1990 64.3 N.A. 4.5 (3) 2000 (4) 68.5 N.A. 4.7 (5) 2008 78.8 15% N.A. 2010 81.1 26% N.A. 2015 84.1 34% N.A. 2020 89.2 43% N.A. 2025 93.9 52% N.A. 2030 98.2 60% N.A. 2035 103.0 68% N.A. Note(s): Source(s): EIA, Annual Energy Outlook 1994, Jan. 1994, Table A5, p. 62 for 1990 floorspace; EIA, AEO 2003, Jan. 2003, Table A5, p. 127-128 for 2000 floorspace; EIA, Annual Energy Outlook 2012 Early Release, Jan. 2012,

  10. Thermophysical properties of U3Si2 to 1773K

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    White, Joshua Taylor; Nelson, Andrew Thomas; Dunwoody, John Tyler; Byler, David Darrin; Safarik, Douglas Joseph; McClellan, Kenneth James

    2015-05-08

    Use of U3Si2 in nuclear reactors requires accurate thermophysical property data to capture heat transfer within the core. Compilation of the limited previous research efforts focused on the most critical property, thermal conductivity, reveals extensive disagreement. Assessment of this data is challenged by the fact that the critical structural and chemical details of the material used to provide historic data is either absent or confirms the presence of significant impurity phases. This study was initiated to fabricate high purity U3Si2 to quantify the coefficient of thermal expansion, heat capacity, thermal diffusivity, and thermal conductivity from room temperature to 1773 K.more » Here, the datasets provided in this manuscript will facilitate more detailed fuel performance modeling to assess both current and proposed reactor designs that incorporate U3Si2.« less

  11. 3-hydroxy-2(1H)-pyridinone chelating agents

    DOE Patents [OSTI]

    Raymond, Kenneth; Xu, Jide

    1999-01-01

    Disclosed is a series of improved chelating agents and the chelates formed from these agents, which are highly effective upon both injection and oral administration. Several of the most effective are of low toxicity. These chelating agents incorporate within their structure 3-hydroxy-2-pyridinone (3,2-HOPO) moieties with a substituted carbamoyl group ortho to the hydroxy group of the hydroxypyridinone ring. The electron-withdrawing carbamoyl group increases the acidity, as well as the chemical stability towards oxidation and reduction, of the hydroxypyridinones. In the metal complexes of the chelating agents, the amide protons form very strong hydrogen bonds with the adjacent HOPO oxygen donor, making these complexes very stable at physiological conditions. The terminal N-substituents provide a certain degree of lipophilicity to the 3,2-HOPO, increasing oral activity.

  12. Metastability in the MgAl2O4-Al2O3 System

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wilkerson, Dr. Kelley R.; Smith, Jeffrey D; Hemrick, James Gordon

    2014-01-01

    Aluminum oxide must take a spinel form ( -Al2O3) at elevated temperatures in order for extensive solid solution to form between MgAl2O4 and -Al2O3. The solvus line between MgAl2O4 and Al2O3 has been dened at 79.6 wt% Al2O3 at 1500C, 83.0 wt% Al2O3 at 1600C, and 86.5 wt% Al2O3 at 1700C. A metastable region has been dened at temperatures up to 1700C which could have signicant implications for material processing and properties. Additionally, initial processing could have major implications on nal chemistry. The spinel solid solution region has been extended to form an innite solid solution with Al2O3 at elevatedmore » temperatures. A minimum in melting at 1975C and a chemistry of 96 wt% Al2O3 rather than a eutectic is present, resulting in no eutectic crystal formation during solidication.« less

  13. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    3 2005 Average Household Expenditures, by Census Region ($2010) Item Energy (1) Shelter (2) Food Telephone, water and other public services Household supplies, furnishings and equipment (3) Transportation (4) Healthcare Education Personal taxes (5) Other expenditures Average Annual Income Note(s): Source(s): 1) Average household energy expenditures are calculated from the Residential Energy Consumption Survey (RECS), while average expenditures for other categories are calculated from the

  14. A novel inorganic-organic compound: Synthesis and structural characterization of tin(II) phenylbis(phosphonate), Sn{sub 2}(PO{sub 3}C{sub 6}H{sub 4}PO{sub 3})

    SciTech Connect (OSTI)

    Subbiah, Ayyappan; Bhuvanesh, Nattamai; Clearfield, Abraham . E-mail: clearfield@mail.chem.tamu.edu

    2005-04-15

    A novel tin(II) phenylbis(phosphonate) compound has been synthesized hydrothermally and its structure has been determined by single crystal X-ray diffraction. The structure is monoclinic, space group P2{sub 1}/c (no. 14), a=4.8094(4), b=16.2871(13), c=6.9107(6)A; {beta}=106.292(6){sup o}, V=519.59(7)A{sup 3}, Z=2. The three-dimensional structure consists of 3-coordinated tin and 4-coordinated phosphorus double layers separated (pillared) by phenyl rings. These phenyl rings are placed 4.8A apart along the a-axis in the structure resulting in lower surface area ({approx}14m{sup 2}/g). The porosity has been increased by replacing phenyl groups by methyl groups ({approx}31m{sup 2}/g)

  15. Eight Pulse Performance of DARHT Axis II - Preliminary Results

    SciTech Connect (OSTI)

    Schulze, Martin E.

    2015-12-08

    The DARHT-II accelerator produces a 1.65-kA, 17-MeV beam in a 1600-ns pulse. Standard operation of the DARHT Axis II accelerator involves extracting four short pulses from the 1.6 us long macro-pulse produced by the LIA. The four short pulses are extracted using a fast kicker in combination with a quadrupole septum magnet and then transported for several meters to a high-Z material target for conversion to x-rays for radiography. The ability of the DARHT Axis 2 kicker to produce more than the standard four pulse format has been previously demonstrated. This capability was developed to study potential risks associated with beam transport during an initial commissioning phase at low energy (8 MeV) and low current (1.0 kA).The ability of the kicker to deliver more than four pulses to the target has been realized for many years. This note describes the initial results demonstrating this capability.

  16. Ca2+-Doped CeBr3 Scintillating Materials

    SciTech Connect (OSTI)

    Guss, Paul; Foster, Michael E.; Wong, Bryan M.; Doty, F. Patrick; Shah, Kanai; Squillante, Michael R.; Shirwadkar, Urmila; Hawrami, Rastgo; Tower, Josh; Yuan, Ding

    2014-01-21

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were studied using the density functional theory within the generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

  17. AMO Weekly Announcements 3/2 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AMO Weekly Announcements 3/2 March 2, 2016 - 11:20am Addthis Advanced Manufacturing Office Funded Cyclotron Road Program Announces Second Cohort of Innovators The Cyclotron Road program through Lawrence Berkeley National Laboratory, has announced the selection of nine new members to make up its second cohort of innovators. Several of the new members hold Ph.D.'s in a variety of engineering fields and are all first-time entrepreneurs. This announcement comes after a four month selection process

  18. Algebraic special functions and SO(3,2)

    SciTech Connect (OSTI)

    Celeghini, E.; Olmo, M.A. del

    2013-06-15

    A ladder structure of operators is presented for the associated Legendre polynomials and the sphericas harmonics. In both cases these operators belong to the irreducible representation of the Lie algebra so(3,2) with quadratic Casimir equals to −5/4. As both are also bases of square-integrable functions, the universal enveloping algebra of so(3,2) is thus shown to be homomorphic to the space of linear operators acting on the L{sup 2} functions defined on (−1,1)×Z and on the sphere S{sup 2}, respectively. The presence of a ladder structure is suggested to be the general condition to obtain a Lie algebra representation defining in this way the “algebraic special functions” that are proposed to be the connection between Lie algebras and square-integrable functions so that the space of linear operators on the L{sup 2} functions is homomorphic to the universal enveloping algebra. The passage to the group, by means of the exponential map, shows that the associated Legendre polynomials and the spherical harmonics support the corresponding unitary irreducible representation of the group SO(3,2). -- Highlights: •The algebraic ladder structure is constructed for the associated Legendre polynomials (ALP). •ALP and spherical harmonics support a unitary irreducible SO(3,2)-representation. •A ladder structure is the condition to get a Lie group representation defining “algebraic special functions”. •The “algebraic special functions” connect Lie algebras and L{sup 2} functions.

  19. Anisotropic swelling and microcracking of neutron irradiated Ti3AlC2-Ti5Al2C3 materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ang, Caen K.; Silva, Chinthaka M.; Shih, Chunghao Phillip; Koyanagi, Takaaki; Katoh, Yutai; Zinkle, Steven J.

    2015-12-17

    Mn + 1AXn (MAX) phase materials based on Ti–Al–C have been irradiated at 400 °C (673 K) with fission neutrons to a fluence of 2 × 1025 n/m2 (E > 0.1 MeV), corresponding to ~ 2 displacements per atom (dpa). We report preliminary results of microcracking in the Al-containing MAX phase, which contained the phases Ti3AlC2 and Ti5Al2C3. Equibiaxial ring-on-ring tests of irradiated coupons showed that samples retained 10% of pre-irradiated strength. Volumetric swelling of up to 4% was observed. Phase analysis and microscopy suggest that anisotropic lattice parameter swelling caused microcracking. Lastly, variants of titanium aluminum carbide may bemore » unsuitable materials for irradiation at light water reactor-relevant temperatures.« less

  20. Structural distortions in the spin-gap regime of the quantum antiferromagnet SrCu{sub 2}(BO{sub 3}){sub 2}

    SciTech Connect (OSTI)

    Vecchini, C.; Adamopoulos, O.; Chapon, L.C.; Lappas, A.; Kageyama, H.; Ueda, Y.; Zorko, A.

    2009-12-15

    We report the first crystallographic study within the low-temperature (<40 K) spin-gap region of the two-dimensional frustrated antiferromagnet SrCu{sub 2}(BO{sub 3}){sub 2}. The crystal system does not deviate from the tetragonal I-42m space group symmetry. However, our high-resolution neutron powder diffraction measurements uncover subtle structural modifications below 34 K, concomitant to the formation of the dimer singlet ground state. Intimate spin-lattice coupling leads to negative thermal expansion of the tetragonal structure, which reflects into particular local lattice adjustments. The extracted structural parameters suggest the reduction of the buckling found in the copper-borate planes and the strengthening of the leading, in-plane intra-dimer superexchange interaction. The observed contraction along the c-axis, associated with the inter-dimer exchange in adjacent layers, indicates the involvement of weaker three-dimensional interactions in the magnetic properties. The rules posed by the crystal symmetry do not preclude Dzyaloshinsky-Moriya interactions, which therefore remain as an important source of spin anisotropy necessary to rationalise the ground state behaviour. - Abstract: We report the first crystallographic study within the low-temperature spin-gap region of the two-dimensional frustrated antiferromagnet SrCu{sub 2}(BO{sub 3}){sub 2}. Subtle spin-lattice coupling was unveiled in the low-temperature region. Display Omitted

  1. In situ observation of the orthorhombic-tetragonal phase transformation in YBa sub 2 Cu sub 3 O sub 7 minus. delta

    SciTech Connect (OSTI)

    Monteiro, O.R.; Evans, J.W. ); Johnson, S.M. )

    1991-02-15

    We have carried out {ital in} {ital situ} heat treatments of YBa{sub 2}Cu{sub 3}O{sub 7{minus}{delta}} at temperatures between 25 and 500 {degree}C and oxygen pressure of 10 Torr. It was found that the original orthorhombic ({ital OI} phase) YBa{sub 2}Cu{sub 3}O{sub 7{minus}{delta}} transforms into the {ital OII} phase (still orthorhombic, but with a doubling of the {ital a}-axis, and with a {delta}=0.5) at about 250 {degree}C. As the temperature is increased further, the tetragonal phase of YBa{sub 2}Cu{sub 3}O{sub 7{minus}{delta}} forms. As the tetragonal phase is slowly cooled to room temperature, the orthorhombic phase {ital OI} reappears. Cycling the temperature repeatedly has indicated the regenerability of the {ital OI} phase.

  2. Operating Experience Level 1, 2, and 3 Documents

    Broader source: Energy.gov [DOE]

    Operating Experience Level 1, 2, and 3 documents communicate required actions, information on safety issues or trends of concern, and lessons learned on operating experience to the DOE Complex to prevent adverse operating incidents and to expand the sharing of good work practices.

  3. Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis; Sun, Lei; Surendranath, Yogesh; Dinca, Mircea

    2016-03-08

    Control over the architectural and electronic properties of heterogeneous catalysts poses a major obstacle in the targeted design of active and stable non-platinum group metal electrocatalysts for the oxygen reduction reaction. Here we introduce Ni3(HITP)2 (HITP=2, 3, 6, 7, 10, 11-hexaiminotriphenylene) as an intrinsically conductive metal-organic framework which functions as a well-defined, tunable oxygen reduction electrocatalyst in alkaline solution. Ni3(HITP)2 exhibits oxygen reduction activity competitive with the most active non-platinum group metal electrocatalysts and stability during extended polarization. The square planar Ni-N4 sites are structurally reminiscent of the highly active and widely studied non-platinum group metal electrocatalysts containing M-N4 units.more » Ni3(HITP)2 and analogues thereof combine the high crystallinity of metal-organic frameworks, the physical durability and electrical conductivity of graphitic materials, and the diverse yet well-controlled synthetic accessibility of molecular species. As a result, such properties may enable the targeted synthesis and systematic optimization of oxygen reduction electrocatalysts as components of fuel cells and electrolysers for renewable energy applications.« less

  4. combined_supplemental_hud_multifamily_weatherization_list_3-2A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3-2A.xls combinedsupplementalhudmultifamilyweatherizationlist3-2A.xls combinedsupplementalhudmultifamilyweatherizationlist3-2A.xls More Documents & Publications...

  5. DARHT: Dual-Axis Radiographic Hydrodynamic Test Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DARHT: Dual-Axis Radiographic Hydrodynamic Test Facility DARHT: Dual-Axis Radiographic Hydrodynamic Test Facility DARHT, supports a critical component of LANL's primary mission: to ensure the safety, security, and effectiveness of nuclear weapons in our nation's stockpile. Los Alamos scientists built DARHT, the world's most powerful x-ray machine, to analyze mockups of nuclear weapons. At the Los Alamos National Laboratory (LANL), the Dual-Axis Radiographic Hydrodynamic Test Facility, or DARHT,

  6. Thermodynamic Properties of α-Fe2O3 and Fe3O4 Nanoparticles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Spencer, Elinor C.; Ross, Nancy L.; Olsen, Rebecca E.; Huang, Baiyu; Kolesnikov, Alexander I.; Woodfield, Brian F.

    2015-04-21

    Here we comprehansively assessed the thermodynamic properties of hydrated α-Fe2O3 (hematite) and Fe3O4 (magnetite) nanoparticles. In addition to 9 nm Fe3O4, three α-e2O3nanoparticles samples of different sizes (11, 14, and 25 nm) and bulk α-e2O3 have been evaluated by inelastic neutron scattering methods. The contribution of the two-level magnetic spin flip transition to the heat capacity of the α-e2O3 particles has been determined. The isochoric heat capacity of the water confined on the surface of these two types of iron oxide particles have been calculated from their INS spectra, and is affected by the chemical composition of the underlying particle.more » Furthermore, the heat capacity and dynamics of the particle hydration layers appear to be influenced by a complex array of factors including particle size, water coverage, and possibly the magnetic state of the particle itself.« less

  7. Magnetic structure and phase stability of the van der Waals bonded ferromagnet Fe3-xGeTe2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    May, Andrew F.; Calder, Stuart A.; Cantoni, Claudia; Cao, Huibo; McGuire, Michael A.

    2016-01-08

    The magnetic structure and phase diagram of the layered ferromagnetic compound Fe3GeTe2 have been investigated by a combination of synthesis, x-ray and neutron diffraction, high-resolution microscopy, and magnetization measurements. Single crystals were synthesized by self-flux reactions, and single-crystal neutron diffraction finds ferromagnetic order with moments of 1.11(5)μB/Fe aligned along the c axis at 4 K. These flux-grown crystals have a lower Curie temperature Tc ≈ 150 K than crystals previously grown by vapor transport (Tc = 220 K). The difference is a reduced Fe content in the flux-grown crystals, as illustrated by the behavior observed in a series of polycrystallinemore » samples. As Fe content decreases, so do the Curie temperature, magnetic anisotropy, and net magnetization. Furthermore, Hall-effect and thermoelectric measurements on flux-grown crystals suggest that multiple carrier types contribute to electrical transport in Fe3–xGeTe2 and structurally similar Ni3–xGeTe2.« less

  8. Failure mode analysis for lime/limestone FGD systems. Volume 3. Plant profiles. Part 2

    SciTech Connect (OSTI)

    Kenney, S.M.; Rosenberg, H.S.; Nilsson, L.I.O.; Oxley, J.H.

    1984-08-01

    Plant profiles are given for the following plants: Tombigbee 2, 3; Apache 2, 3; Cholla 1, 2; Four Corners 1, 2, 3; Laramie River 1; Green 1, 2; Duck Creek 1; Craig 1, 2; Conesville 5, 6; Coal Creek 1, 2; Elrama 1, 2, 3, 4; and Phillips 1, 2, 3, 4, 5, 6. (DLC)

  9. Bertram Brockhouse, the Triple-axis Spectrometer, and Neutron...

    Office of Scientific and Technical Information (OSTI)

    Bertram Brockhouse, the Triple-axis Spectrometer, and Neutron Spectroscopy Resources with Additional Information Bertram Brockhouse Courtesy of McMaster University Bertram...

  10. Solasta aka The Eagle Axis | Open Energy Information

    Open Energy Info (EERE)

    Zip: 2458 Sector: Efficiency, Solar Product: Start-up planning to produce high-efficiency solar cells using nanoscale elements. References: Solasta (aka The Eagle Axis)1 This...

  11. MHK Technologies/Horizontal Axis Logarithmic Spiral Turbine ...

    Open Energy Info (EERE)

    Horizontal Axis Logarithmic Spiral Turbine < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage Technology Profile Primary Organization Golden...

  12. Off-Axis Parabola Inserter - Laboratory for Laser Energetics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Axis Parabola Inserter - Laboratory for Laser Energetics Laboratory for Laser Energetics Logo Search Home Around the Lab Past Issues Past Quick Shots About Office of the Director ...

  13. Nonlinear characterization of a single-axis acoustic levitator

    SciTech Connect (OSTI)

    Andrade, Marco A. B.; Ramos, Tiago S.; Okina, Fbio T. A.; Adamowski, Julio C.

    2014-04-15

    The nonlinear behavior of a 20.3 kHz single-axis acoustic levitator formed by a Langevin transducer with a concave radiating surface and a concave reflector is experimentally investigated. In this study, a laser Doppler vibrometer is applied to measure the nonlinear sound field in the air gap between the transducer and the reflector. Additionally, an electronic balance is used in the measurement of the acoustic radiation force on the reflector as a function of the distance between the transducer and the reflector. The experimental results show some effects that cannot be described by the linear acoustic theory, such as the jump phenomenon, harmonic generation, and the hysteresis effect. The influence of these nonlinear effects on the acoustic levitation of small particles is discussed.

  14. Three-axis particle impact probe

    DOE Patents [OSTI]

    Fasching, George E.; Smith, Jr., Nelson S.; Utt, Carroll E.

    1992-01-01

    Three-axis particle impact probes detect particle impact vectors along x-, y-, and z-axes by spherical probe head mounted on the outer end of a shaft that is flexibly mounted in silicone rubber at the top of a housing so as to enable motion imparted to the head upon impact to be transmitted to a grounded electrode secured to the shaft within the housing. Excitable electrodes are mounted in the housing in a fixed position, spaced apart from the ground electrode and forming, with the ground electrode, capacitor pairs. Movement of the ground electrode results in changes in capacitance, and these difference in capacitance are used for measurement or derivation of momentum vectors along each of the three axes. In one embodiment, the ground electrode is mounted at the base of the shaft and is secured to a silicone rubber layer at the top of the housing, providing for cantilevered movement. In another embodiment, the shaft is mounted at its mid point in a flexible bushing so that it undergoes pivotal movement around that point.

  15. Control system for a vertical axis windmill

    DOE Patents [OSTI]

    Brulle, Robert V.

    1983-10-18

    A vertical axis windmill having a rotating structure is provided with a series of articulated vertical blades whose positions are controlled to maintain a constant RPM for the rotating structure, when wind speed is sufficient. A microprocessor controller is used to process information on wind speed, wind direction and RPM of the rotating structure to develop an electrical signal for establishing blade position. The preferred embodiment of the invention, when connected to a utility grid, is designed to generate 40 kilowatts of power when exposed to a 20 mile per hour wind. The control system for the windmill includes electrical blade actuators that modulate the blades of the rotating structure. Blade modulation controls the blade angle of attack, which in turn controls the RPM of the rotor. In the preferred embodiment, the microprocessor controller provides the operation logic and control functions. A wind speed sensor provides inputs to start or stop the windmill, and a wind direction sensor is used to keep the blade flip region at 90.degree. and 270.degree. to the wind. The control system is designed to maintain constant rotor RPM when wind speed is between 10 and 40 miles per hour.

  16. Effects of reagent rotational excitation on the H + CHD{sub 3} → H{sub 2} + CD{sub 3} reaction: A seven dimensional time-dependent wave packet study

    SciTech Connect (OSTI)

    Zhang, Zhaojun; Zhang, Dong H.

    2014-10-14

    Seven-dimensional time-dependent wave packet calculations have been carried out for the title reaction to obtain reaction probabilities and cross sections for CHD{sub 3} in J{sub 0} = 1, 2 rotationally excited initial states with k{sub 0} = 0 − J{sub 0} (the projection of CHD{sub 3} rotational angular momentum on its C{sub 3} axis). Under the centrifugal sudden (CS) approximation, the initial states with the projection of the total angular momentum on the body fixed axis (K{sub 0}) equal to k{sub 0} are found to be much more reactive, indicating strong dependence of reactivity on the orientation of the reagent CHD{sub 3} with respect to the relative velocity between the reagents H and CHD{sub 3}. However, at the coupled-channel (CC) level this dependence becomes much weak although in general the K{sub 0} specified cross sections for the K{sub 0} = k{sub 0} initial states remain primary to the overall cross sections, implying the Coriolis coupling is important to the dynamics of the reaction. The calculated CS and CC integral cross sections obtained after K{sub 0} averaging for the J{sub 0} = 1, 2 initial states with all different k{sub 0} are essentially identical to the corresponding CS and CC results for the J{sub 0} = 0 initial state, meaning that the initial rotational excitation of CHD{sub 3} up to J{sub 0} = 2, regardless of its initial k{sub 0}, does not have any effect on the total cross sections for the title reaction, and the errors introduced by the CS approximation on integral cross sections for the rotationally excited J{sub 0} = 1, 2 initial states are the same as those for the J{sub 0} = 0 initial state.

  17. MHK ISDB/Instruments/CDL MiniRLG2 | Open Energy Information

    Open Energy Info (EERE)

    AirMar 42183 Heading Sensor CDL MiniSense 2-IPS ... further results 3-axis Velocity (Translation) (6) INS CDL MiniPOSNAV Dynamic Motion Sensors 0.05 RMS CDL MiniPOS3 CDL TOGSNav...

  18. The Use of a Beryllium Hopkinson Bar to Characterize In-Axis and Cross-Axis Accelerometer Response in Shock Environments

    SciTech Connect (OSTI)

    Bateman, V.I.; Brown, F.A.

    1999-01-01

    The characteristics of a piezoresistive accelerometer in shock environments have been studied at Sandia National Laboratories in the Mechanical Shock Laboratory. A beryllium Hopkinson bar capability with diameters of 0.75 in. and 2.0 in has been developed to extend our understanding of the piezoresistive accelerometer, in two mechanical configurations, in the high frequency, high shock environments where measurements are being made. The in-axis performance of the piezoresistive accelerometer determined from measurements with a beryllium Hopkinson bar and a certified laser doppler vibrometer as the reference measurement is presented. The cross-axis performance of the accelerometer subjected to static compression on a beryllium cylinder, static strain on a steel beam, dynamic strain on a steel beam (ISA-RP 37.2, Paragraph 6.6), and compressive shocks in a split beryllium Hopkinson bar configuration is also presented. The performance of the accelerometer in a combined in-axis and cross-axis shock environment is shown for one configuration. Finally, a failure analysis conducted in cooperation with ENDEVCO gives a cause for the occasional unexplained failures that have occurred in some applications.

  19. Interactive initialization of 2D/3D rigid registration

    SciTech Connect (OSTI)

    Gong, Ren Hui; Gler, zgr; Krkloglu, Mustafa; Lovejoy, John; Yaniv, Ziv

    2013-12-15

    Purpose: Registration is one of the key technical components in an image-guided navigation system. A large number of 2D/3D registration algorithms have been previously proposed, but have not been able to transition into clinical practice. The authors identify the primary reason for the lack of adoption with the prerequisite for a sufficiently accurate initial transformation, mean target registration error of about 10 mm or less. In this paper, the authors present two interactive initialization approaches that provide the desired accuracy for x-ray/MR and x-ray/CT registration in the operating room setting. Methods: The authors have developed two interactive registration methods based on visual alignment of a preoperative image, MR, or CT to intraoperative x-rays. In the first approach, the operator uses a gesture based interface to align a volume rendering of the preoperative image to multiple x-rays. The second approach uses a tracked tool available as part of a navigation system. Preoperatively, a virtual replica of the tool is positioned next to the anatomical structures visible in the volumetric data. Intraoperatively, the physical tool is positioned in a similar manner and subsequently used to align a volume rendering to the x-ray images using an augmented reality (AR) approach. Both methods were assessed using three publicly available reference data sets for 2D/3D registration evaluation. Results: In the authors' experiments, the authors show that for x-ray/MR registration, the gesture based method resulted in a mean target registration error (mTRE) of 9.3 5.0 mm with an average interaction time of 146.3 73.0 s, and the AR-based method had mTREs of 7.2 3.2 mm with interaction times of 44 32 s. For x-ray/CT registration, the gesture based method resulted in a mTRE of 7.4 5.0 mm with an average interaction time of 132.1 66.4 s, and the AR-based method had mTREs of 8.3 5.0 mm with interaction times of 58 52 s. Conclusions: Based on the authors

  20. Coupled skyrmion sublattices in Cu2OSeO3

    SciTech Connect (OSTI)

    Langner, M.C.; Roy,, S.; Mishra, S. K.; Lee, J. C. T.; Shi,, X. W.; Hossain, M. A.; Chuang, Y.-D.; Seki, S.; Tokura, Y.; Kevan, S. D.; Schoenlein, R. W.

    2014-04-18

    We report the observation of a skyrmion lattice in the chiral multiferroic insulator Cu2OSeO3 using Cu L3-edge resonant soft x-ray diffraction. We observe the unexpected existence of two distinct skyrmion sub-lattices that arise from inequivalent Cu sites with chemically identical coordination numbers but different magnetically active orbitals . The skyrmion sublattices are rotated with respect to each other implying a long wavelength modulation of the lattice. The modulation vector is controlled with an applied magnetic field, associating this Moir'e-like phase with a continuous phase transition. Our findings will open a new class of science involving manipulation of quantum topological states.

  1. Off-axis sawteeth and double-tearing reconnection in reversed magnetic shear plasmas in TFTR

    SciTech Connect (OSTI)

    Chang, Z.; Park, W.; Fredrickson, E.D.

    1996-06-01

    Off-axis sawteeth are often observed in reversed magnetic shear plasmas when the minimum safety factor q is near or below 2. Fluctuations with m/n = 2/1 (m and n are the poloidal and toroidal mode numbers) appear before and after the crashes. Detailed comparison has been made between the measured T{sub e} profile evolution during the crash and a nonlinear numerical magnetohydrodynamics (MHD) simulation. The good agreement between the observation and simulation indicates that the off-axis sawteeth are due to a double-tearing magnetic reconnection process.

  2. 4-(3-Methoxyphenyl)-2,6-dimethylcyclohex-3-enecarboxylic acid

    SciTech Connect (OSTI)

    Xie, Songwen; Nusbaum, Dannette A.; Stein, Holly J.; Pink, Maren

    2012-03-15

    The racemic title compound, C{sub 16}H{sub 20}O{sub 3}, was synthesized to study the hydrogen-bonding interaction of the two enantiomers in the solid state. In the crystal structure, R and S pairs of the racemate are linked by pairs of intermolecular O-H...O hydrogen bonds, producing centrosymmetric R{sub 2}{sup 2}(8) rings.

  3. Mo{sub 2}NiB{sub 2}-type (Gd, Tb, Dy){sub 2}Ni{sub 2.35}Si{sub 0.65} and La{sub 2}Ni{sub 3}-type (Dy, Ho){sub 2}Ni{sub 2.5}Si{sub 0.5} compounds: Crystal structure and magnetic properties

    SciTech Connect (OSTI)

    Morozkin, A.V.; Isnard, O.; Nirmala, R.; Malik, S.K.

    2015-05-15

    The crystal structure of new Mo{sub 2}NiB{sub 2}-type (Gd, Tb, Dy){sub 2}Ni{sub 2.35}Si{sub 0.65} (Immm, No. 71, oI10) and La{sub 2}Ni{sub 3}-type (Dy, Ho){sub 2}Ni{sub 2.5}Si{sub 0.5} (Cmce No. 64, oC20) compounds has been established using powder X-ray diffraction studies. Magnetization measurements show that the Mo{sub 2}NiB{sub 2}-type Gd{sub 2}Ni{sub 2.35}Si{sub 0.65} undergoes a ferromagnetic transition at ~66 K, whereas isostructural Tb{sub 2}Ni{sub 2.35}Si{sub 0.65} shows an antiferromagnetic transition at ~52 K and a field-induced metamagnetic transition at low temperatures. Neutron diffraction study shows that, in zero applied field, Tb{sub 2}Ni{sub 2.35}Si{sub 0.65} exhibits c-axis antiferromagnetic order with propagation vector K=[1/2, 0, 1/2] below its magnetic ordering temperature and Tb magnetic moment reaches a value of 8.32(5) μ{sub B} at 2 K. The La{sub 2}Ni{sub 3}-type Dy{sub 2}Ni{sub 2.5}Si{sub 0.5} exhibits ferromagnetic like transition at ~42 K with coexisting antiferromagnetic interactions and field induced metamagnetic transition below ~17 K. The magnetocaloric effect of Gd{sub 2}Ni{sub 2.35}Si{sub 0.65}, Tb{sub 2}Ni{sub 2.35}Si{sub 0.65} and Dy{sub 2}Ni{sub 2.5}Si{sub 0.5} is calculated in terms of isothermal magnetic entropy change and it reaches a maximum value of −14.3 J/kg K, −5.3 J/kg K and −10.3 J/kg K for a field change of 50 kOe near 66 K, 52 K and 42 K, respectively. Low temperature magnetic ordering with enhanced anisotropic effects in Tb{sub 2}Ni{sub 2.35}Si{sub 0.65} and Dy{sub 2}Ni{sub 2.35}Si{sub 0.65} is accompanied by a positive magnetocaloric effect with isothermal magnetic entropy changes of +12.8 J/kg K and ~+9.9 J/kg K, respectively at 7 K for a field change of 50 kOe. - Graphical abstract: The (Gd, Tb, Dy){sub 2}Ni{sub 2.35}Si{sub 0.65} supplement the series of Mo{sub 2}NiB{sub 2}-type rare earth compounds, whereas the (Dy, Ho){sub 2}Ni{sub 2.5}Si{sub 0.5} supplement the series of La{sub 2}Ni{sub 3}-type rare

  4. Crystal structures of nitrato-(2-[2-(1-pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo) aquacopper and chloro-(2-[2-phenyl(pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo) copper

    SciTech Connect (OSTI)

    Chumakov, Yu. M.; Paholnitcaia, A. Yu.; Petrenko, P. A.; Tsapkov, V. I.; Poirier, D.; Gulea, A. P.

    2015-01-15

    Two crystal modifications of nitrato-(2-[2-(1-pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo) aquacopper (I and II) and two modifications of chloro-(2-[2-phenyl(pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo) copper (III and IV) have been synthesized and studied by X-ray diffraction. In structures I and II, the copper atoms coordinate a monodeprotonated molecule of the organic ligand, nitrate ions, and a water molecule. In crystals of I, the complexes are monomeric, whereas complexes II are linked via nitrate ions to form polymeric chains. In both structures the coordination polyhedron of the copper atom can be described as a distorted tetragonal bipyramid—(4 + 1 + 1) in I and (4 + 2) in II. These coordination polyherdra have different compositions. In structures III and IV, the metal atoms coordinate a monodeprotonated (2-[2-phenyl(pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazole molecule and chloride ions. In III the complex-forming ion has square-planar coordination geometry, whereas structure IV consists of centrosymmetric dimers with two bridging chlorine atoms. It was found that nitrato-(2-[2-(1-pyridine-2-ylethylidene)hydrazine]-1,3-benzothiazolo) aquacopper possesses antitumor activity.

  5. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    4 2005 Average Household Expenditures as Percent of Annual Income, by Census Region ($2010) Item Energy (1) Shelter (2) Food Telephone, water and other public services Household supplies, furnishings and equipment (3) Transportation (4) Healthcare Education Personal taxes (5) Average Annual Expenditures Average Annual Income Note(s): Source(s): 1) Average household energy expenditures are calculated from the Residential Energy Consumption Survey (RECS), while average expenditures for other

  6. Inclusive. chi. (2 P ) production in. Upsilon. (3 S ) decay

    SciTech Connect (OSTI)

    Morrison, R.; Schmidt, D.; Procario, M.; Johnson, D.R.; Lingel, K.; Rankin, P.; Smith, J.G.; Alexander, J.; Artuso, M.; Bebek, C.; Berkelman, K.; Besson, D.; Browder, T.E.; Cassel, D.G.; Cheu, E.; Coffman, D.M.; Drell, P.S.; Ehrlich, R.; Galik, R.S.; Garcia-Sciveres, M.; Geiser, B.; Gittelman, B.; Gray, S.W.; Hartill, D.L.; Heltsley, B.K.; Honscheid, K.; Kandaswamy, J.; Katayama, N.; Kreinick, D.L.; Lewis, J.D.; Ludwig, G.S.; Masui, J.; Mevissen, J.; Mistry, N.B.; Nandi, S.; Ng, C.R.; Nordberg, E.; O'Grady, C.; Patterson, J.R.; Peterson, D.; Pisharody, M.; Riley, D.; Sapper, M.; Selen, M.; Worden, H.; Worris, M.; Avery, P.; Freyberger, A.; Rodriguez, J.; Yelton, J.; Kinoshita, K.; Pipkin, F.; Wilson, R.; Wolinski, J.; Xiao, D.; Sadoff, A.J.; Ammar, R.; Baringer, P.; Coppage, D.; Davis, R.; Haas, P.; Kelly, M.; Kwak, N.; Lam, H.; Ro, S.; Kubota, Y.; Nelson, J.K.; Perticone, D.; Poling, R.; Schrenk, S.; Alam, M.S.; Kim, I.J.; Nemati, B.; Romero, V.; Sun, C.R.; Wang, P.; Zoeller, M.M.; Cr

    1991-09-23

    Using the CsI calorimeter of the CLEO II detector, the spin triplet {chi}{sub {ital b}}(2{ital P}) states are observed in {Upsilon}(3{ital S}) radiative decays with much higher statistics than seen in previous experiments. The observed mass splittings are not described well by theoretical models, while the relative branching ratios agree with predictions that include relativistic corrections to the radiative transition rates.

  7. Buildings Energy Data Book: 3.2 Commercial Sector Characteristics

    Buildings Energy Data Book [EERE]

    8 2003 Average Commercial Building Floorspace, by Principal Building Type and Vintage Building Type 1959 or Prior 1960 to 1989 1990 to 2003 All Education 27.5 26.9 21.7 25.6 Food Sales N.A. N.A. N.A. 5.6 Food Service 6.4 4.4 5.0 5.6 Health Care 18.5 37.1 N.A. 24.5 Inpatient N.A. 243.6 N.A. 238.1 Outpatient N.A. 11.3 11.6 10.4 Lodging 9.9 36.1 36.0 35.9 Retail (Other Than Mall) 6.2 9.3 17.5 9.7 Office 12.4 16.4 14.2 14.8 Public Assembly 13.0 13.8 17.3 14.2 Public Order and Safety N.A. N.A. N.A.

  8. Neutron powder diffraction study of the layer organic-inorganic hybrid iron(II) methylphosphonate-hydrate, Fe[(CD{sub 3}PO{sub 3})(D{sub 2}O)

    SciTech Connect (OSTI)

    Leone, Philippe Bellitto, Carlo; Bauer, Elvira M.; Righini, Guido; Andre, Gilles; Bouree, Francoise

    2008-11-15

    The crystal and magnetic structures of the hybrid organic-inorganic layer compound Fe[(CD{sub 3}PO{sub 3})(D{sub 2}O)] have been studied by neutron powder diffraction as a function of temperature down to 1.5 K. The neutron diffraction pattern recorded at 200 K shows that the fully deuterated compound crystallizes in one of the two known forms of the undeuterated Fe[(CH{sub 3}PO{sub 3})(H{sub 2}O)]. The crystal structure is orthorhombic, space group Pmn2{sub 1}, with the following unit-cell parameters: a=5.7095(1) A, b=8.8053(3) A and c=4.7987(1) A; Z=2. The crystal structure remains unchanged on cooling from 200 to 1.5 K. Moreover, at low temperature, Fe[(CD{sub 3}PO{sub 3})(D{sub 2}O)] shows a commensurate magnetic structure (k=(0,0,0)). As revealed by bulk susceptibility measurements on Fe[(CH{sub 3}PO{sub 3})(H{sub 2}O)], the magnetic structure corresponds to a canted antiferromagnet with a critical temperature T{sub N}=25 K. Neutron powder diffraction reveals that below T{sub N}=23.5 K the iron magnetic moments in Fe[(CD{sub 3}PO{sub 3})(D{sub 2}O)] are antiferromagnetically coupled and oriented along the b-axis, perpendicular to the inorganic layers. No ferromagnetic component is observable in the neutron powder diffraction experiment, due to its too small value (<0.1{mu}{sub B}). - Graphical abstract: Crystal structure and magnetic structure of Fe[(CD{sub 3}PO{sub 3})(D{sub 2}O)].

  9. Magnetic property, Raman spectroscopy and crystal field analysis of Sm{sub 3+} in Sm(BrO{sub 3}){sub 3}⋅9H{sub 2}O

    SciTech Connect (OSTI)

    Mandal, J.; Chakrabarti, P. K.; Purohit, T.; Chattopadhyay, K. N.; Ghosh, M.

    2014-04-24

    Single crystals of Sm(BrO{sub 3}){sub 3}⋅9H{sub 2}O (SmBR) were grown and the principal molar susceptibility perpendicular to c-axis (χ{sub ⊥}) was measured from 300 K down to 14 K and χ{sub ‖}, the parallel susceptibility, anisotropy was measured in the temperature range of 300-120 K. A cross-over between χ{sub ‖} and χ{sub ⊥} was observed at ∼ 120 K i.e., below this temperature χ{sub |||}<χ{sub ‖}. Raman spectra of SmBR were recorded in the wave number range of 10-4000 cm{sup −1} and crystal field (CF) Stark energies were extracted from the spectra. A good theoretical simulation of the observed magnetic susceptibilities and observed CF Stark energies of Sm{sup 3+} in SmBR was achieved using the one electron crystal field (CF) interaction with D{sup 3h} site symmetry. The electronic specific heat along with the quadruple splitting and hyperfine heat capacity were calculated by using the results of CF analysis.

  10. Spin-stabilized magnetic levitation without vertical axis of rotation

    DOE Patents [OSTI]

    Romero, Louis; Christenson, Todd; Aaronson, Gene

    2009-06-09

    The symmetry properties of a magnetic levitation arrangement are exploited to produce spin-stabilized magnetic levitation without aligning the rotational axis of the rotor with the direction of the force of gravity. The rotation of the rotor stabilizes perturbations directed parallel to the rotational axis.

  11. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    5 2005 Households and Energy Expenditures, by Income Level ($2010) Energy Expenditures by Household Income Households (millions) Household Less than $10,000 9.9 9% $10,000 to $14,999 8.5 8% $15,000 to $19,999 8.4 8% $20,000 to $29,999 15.1 14% $30,000 to $39,999 13.6 12% $40,000 to $49,999 11.0 10% $50,000 to $74,999 19.8 18% $75,000 to $99,999 10.6 10% $100,000 or more 14.2 13% Total 111.1 100% Note(s): Source(s): 7% 1) See Table 2.3.15 for more on energy burdens. 2) A household is defined as a

  12. X-ray diffraction on the X-cut of a Ca{sub 3}TaGa{sub 3}Si{sub 2}O{sub 14} single crystal modulated by a surface acoustic wave

    SciTech Connect (OSTI)

    Irzhak, D. Roshchupkin, D.

    2014-06-28

    The result of X-ray diffraction study on a single crystal of the calcium-gallogermanate family Ca{sub 3}TaGa{sub 3}Si{sub 2}O{sub 14} (CTGS) modulated by a surface acoustic wave (SAW) is presented. The power flow angle for SAW propagating along the X{sub 2} axis of the X-cut in CTGS was measured. The rocking curves for the CTGS crystal were recorded at different amplitudes of an input high frequency electric signal on interdigital transducer used to excite a SAW. Based on the data obtained, intensity dependence of diffraction satellites on the amplitude of electric signal exciting a SAW was built. Numerical simulation of the crystal rocking curves and dependence of diffraction satellite intensities on the SAW amplitude enabled the selection of a set of material constants at which the most complete coincidence of experimental and calculated results is observed.

  13. 2,2{prime},4,4{prime},5,5{prime}-hexachlorobiphenyl (2HCB) and 3,3{prime},4,4{prime},5,5{prime}-hexachlorobiphenyl alter plasma thyroxine (T4) levels in rainbow trout (Oncorhynchus mykiss)

    SciTech Connect (OSTI)

    Foster, E.; Curtis, L.; Donohoe, R.

    1995-12-31

    Di-ortho polychlorinated biphenyls (PCBs) are prominent environmental contaminants and their interaction with the thyroidal axis may be more significant in fish than previously thought. Four weeks after ip injection with 50 or 250 mg 2HCB/kg or 5 or 25 mg 3HCB/kg, rainbow trout plasma and liver microsomes were prepared. Plasma T4 levels were increased in 50 but not 250 mg 2HCB/kg treated fish. Plasma T4 levels were unchanged in 3HCB treated fish. Liver microsome ethoxyresorufin deethylase (EROD) activity increased with 2HCB dose. EROD increased after the low but not the high 3HCB dose. Western immunoblotting us 1A trout-anti-rabbit primary antibody showed a 2HCB and 3HCB dose related increase. In another experiment, twelve weeks after ip injection was 25 or 100 mg 3HCB/kg, rainbow trout plasma, thyroidal tissue, and liver microsomes were prepared. Plasma T4 levels were increased in 25 not 100 mg 3HCB/kg treated fish. Thyroid follicle cell height was increased in 25 but not 100 mg 3HCB/kg treated fish. Interaction with the receptor, as measured by cytochrome P450 1A induction, does not correlate with altered T4 plasma levels.

  14. DARHT status and preparations for dual-axis hydrotesting (u)

    SciTech Connect (OSTI)

    Bowman, David W

    2010-01-01

    The status of the DARHT facility, including a history of events that have taken place since the end of the DARHT Second Axis Refurbishment Project, is discussed. Technical and operational enhancements that have been made will be addressed, and recent technical challenges, such as the RF noise in the kicker region, are discussed. Historical data on reliability of the second axis is discussed, as well as operational changes made to enhance reliability. In addition, the path forward for integrating the second axis into overall DARHT operations in preparation for a hydrotest is addressed. Timing integration tests are accompanied by a series of tests to evaluate neutron contamination and cross-axis scatter, with attempts being made to provide adequate shielding to minimize the effects of neutrons and cross-beam scatter. The discussion includes results of the testing performed to-date, and concludes with a discussion of the path forward for dual-axis hydrotesting at DARHT.

  15. Visible Light Assisted Photocatalytic Hydrogen Generation by Ta2O5/Bi2O3, TaON/Bi2O3, and Ta3N5/Bi2O3 Composites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adhikari, Shiba; Hood, Zachary D.; More, Karren Leslie; Ivanov, Ilia N.; Zhang, Lifeng; Gross, Michael; Lachgar, Abdou

    2015-06-15

    Composites comprised of two semiconducting materials with suitable band gaps and band positions have been reported to be effective at enhancing photocatalytic activity in the visible light region of the electromagnetic spectrum. Here, we report the synthesis, complete structural and physical characterizations, and photocatalytic performance of a series of semiconducting oxide composites. UV light active tantalum oxide (Ta2O5) and visible light active tantalum oxynitride (TaON) and tantalum nitride (Ta3N5) were synthesized, and their composites with Bi2O3 were prepared in situ using benzyl alcohol as solvent. The composite prepared using equimolar amounts of Bi2O3 and Ta2O5 leads to the formation ofmore » the ternary oxide, bismuth tantalate (BiTaO4) upon calcination at 1000 °C. The composites and single phase bismuth tantalate formed were characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Brunauer–Emmett–Teller (BET) surface area measurement, scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–Vis diffuse reflectance spectroscopy, and photoluminescence. The photocatalytic activities of the catalysts were evaluated for generation of hydrogen using aqueous methanol solution under visible light irradiation (λ ≥ 420 nm). The results show that as-prepared composite photocatalysts extend the light absorption range and restrict photogenerated charge-carrier recombination, resulting in enhanced photocatalytic activity compared to individual phases. The mechanism for the enhanced photocatalytic activity for the heterostructured composites is elucidated based on observed activity, band positions calculations, and photoluminescence data.« less

  16. Inhibition of fatty acid synthase suppresses U-2 OS cell invasion and migration via downregulating the activity of HER2/PI3K/AKT signaling pathway in vitro

    SciTech Connect (OSTI)

    Wang, Tao Fang; Wang, Heng; Peng, Ai Fen; Luo, Qing Feng; Liu, Zhi Li; Zhou, Rong Ping; Gao, Song; Zhou, Yang; Chen, Wen Zhao

    2013-10-18

    Highlights: •We investigate the relationship between FASN and HER2 or p-HER2 by IHC in OS tissues. •We construct FASN-specific RNAi plasmid. •Inhibiting FASN down-regulates HER2/PI3K/AKT cell signaling in U-2 OS. •Inhibiting FASN blocks U-2 OS cell invasion and migration. -- Abstract: FASN plays an important role in the malignant phenotype of various tumors. Our previous studies show that inhibition FASN could induce apoptosis and inhibit proliferation in human osteosarcoma (OS) cell in vivo and vitro. The aim in this study was to investigate the effect of inhibition FASN on the activity of HER2/PI3K/AKT axis and invasion and migration of OS cell. The expression of FASN, HER2 and p-HER2(Y1248) proteins was detected by immunohistochemistry in OS tissues from 24 patients with pulmonary metastatic disease, and the relationship between FASN and p-HER2 as well as HER2 was investigated. The results showed that there was a positive correlation between FASN and HER2 as well as p-HER2 protein expression. The U-2 OS cells were transfected with either the FASN specific RNAi plasmid or the negative control RNAi plasmid. FASN mRNA was measured by RT-PCR. Western blot assays was performed to examine the protein expression of FASN, HER2, p-HER2(Y1248), PI3K, Akt and p-Akt (Ser473). Migration and invasion of cells were investigated by wound healing and transwell invasion assays. The results showed that the activity of HER2/PI3K/AKT signaling pathway was suppressed by inhibiting FASN. Meanwhile, the U-2OS cells migration and invasion were also impaired by inhibiting the activity of FASN/HER2/PI3K/AKT. Our results indicated that inhibition of FASN suppresses OS cell invasion and migration via down-regulation of the “HER2/PI3K/AKT” axis in vitro. FASN blocker may be a new therapeutic strategy in OS management.

  17. Propellant Containing 3, 6bis(1h-1,2,3,4-Tetrazol-5-Ylamino)-1,2,4,5- Tetrazine Or Salt Thereof

    DOE Patents [OSTI]

    Hiskey, Michael A.; Chavez, David E.; Naud, Darren

    2003-12-02

    The compound 3,6-bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine and its salts are provided together with a propellant composition including an oxidizer, a binder and 3,6-bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine or its salts.

  18. Thermally stable compositions including 2,4,8,10-tetranitro-5H-pyrido[3',2':4,5][1,2,3]triazolo[1,2-a]benzotriazo- l-6-ium, inner salt

    DOE Patents [OSTI]

    Hiskey, Michael A.; Huynh, My Hang

    2010-01-26

    An explosive formulation including 2,4,8,10-tetranitro-5H-pyrido[3',2':4,5][1,2,3]triazolo[1,2-a]benzotriazo- l-6-ium, inner salt and a high temperature binder is disclosed together with a process of preparing 2,4,8,10-tetranitro-5H-pyrido[3',2':4,5][1,2,3]triazolo[1,2-a]benzotriazo- l-6-ium, inner salt.

  19. Plugless Level 2 EV Charging System (3.3 kW) by Evatran Group Inc.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PLUGLESS TM Level 2 EV Charging System (3.3 kW) by Evatran Group Inc. Results from Full System Testing in a Laboratory environment Description / Specifications 1 System Input Voltage operating Voltage 208 to 240 VAC Circuit Breaker Rating 30 A Nominal gap between coils 100 mm Rated maximum power output 3300 watts Parking Pad (Primary Coil system) Shape Approximately Circular Size 559 dia. x 470 long mm Vehicle Adapter (Secondary Coil system) Shape Rectangular Size 464 long x 525 wide mm

  20. The thermodynamic properties of hydrated -Al2O3 nanoparticles

    SciTech Connect (OSTI)

    Spencer, Elinor; Huang, Baiyu; Parker, Stewart F.; Kolesnikov, Alexander I; Ross, Dr. Nancy; Woodfield, Brian

    2013-01-01

    In this paper we report a combined calorimetric and inelastic neutron scattering (INS) study of hydrated -Al2O3 ( -alumina) nanoparticles. These complementary techniques have enabled a comprehensive evaluation of the thermodynamic properties of this technological and industrially important metal oxide to be achieved. The isobaric heat capacity (Cp) data presented herein provide further critical insights into the much-debated chemical composition of -alumina nanoparticles. Furthermore, the isochoric heat capacity (Cv) of the surface water, which is so essential to the stability of all metal-oxides at the nanoscale, has been extracted from the high-resolution INS data and differs significantly from that of ice Ih due to the dominating influence of strong surface-water interactions. This study also encompassed the analysis of four -alumina samples with differing pore diameters [4.5 (1), 13.8 (2), 17.9 (3), and 27.2 nm (4)], and the results obtained allow us to unambiguously conclude that the water content and pore size have no influence on the thermodynamic behaviour of hydrated -alumina nanoparticles.

  1. Synthesis Of [2h, 13c] And [2h3, 13c]Methyl Aryl Sulfides

    DOE Patents [OSTI]

    Martinez, Rodolfo A.; Alvarez, Marc A.; Silks, III, Louis A.; Unkefer, Clifford J.

    2004-03-30

    The present invention is directed to labeled compounds, [.sup.2 H.sub.1, .sup.13 C], [.sup.2 H.sub.2, .sup.13 C] and [.sup.2 H.sub.3, .sup.13 C]methyl aryl sulfides wherein the .sup.13 C methyl group attached to the sulfur of the sulfide includes exactly one, two or three deuterium atoms and the aryl group is selected from the group consisting of 1-naphthyl, substituted 1-naphthyl, 2-naphthyl, substituted 2-naphthyl, and phenyl groups with the structure ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 are each independently, hydrogen, a C.sub.1 -C.sub.4 lower alkyl, a halogen, an amino group from the group consisting of NH.sub.2, NHR and NRR' where R and R' are each a C.sub.1 -C.sub.4 lower alkyl, a phenyl, or an alkoxy group. The present invention is also directed to processes of preparing [.sup.2 H.sub.1, .sup.13 C], [.sup.2 H.sub.2,.sup.13 C] and [.sup.2 H.sub.3, .sup.13 C]methyl aryl sulfides wherein the .sup.13 C methyl group attached to the sulfur of the sulfide includes exactly one, two or three deuterium atoms. The present invention is also directed to the labeled compounds of [.sup.2 H.sub.1, .sup.13 C]methyl iodide and [.sup.2 H.sub.2, .sup.13 C]methyl iodide.

  2. Microsoft Word - MP 5 2 Final Rev 3

    Office of Environmental Management (EM)

    AVAILABLE ONLINE AT: INITIATED BY: http://bellview/cbfo/Procedures/ProcedureManualTOC.htm Director, Office of the National TRU Program CBFO Form 4.1-1 U. S. Department of Energy Carlsbad Field Office MANAGEMENT PROCEDURE CBFO MP 5.2, Rev. 3 Effective: 15 November 2010 SUBJECT: TRU WASTE SITE CERTIFICATION/RECERTIFICATION Manager, Carlsbad Field Office: //signature on file// Date: 11/4/10 1.0 PURPOSE The purpose of this procedure is to define the processes, responsibilities, and controls for the

  3. CMI REPORT ON PROJECT 2.3.2 ACTIVITIES: 09/2013 TO 03/2014 (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: CMI REPORT ON PROJECT 2.3.2 ACTIVITIES: 092013 TO 032014 Citation Details In-Document Search Title: CMI REPORT ON PROJECT 2.3.2 ACTIVITIES: 092013 TO 032014 ...

  4. 2D/3D registration algorithm for lung brachytherapy

    SciTech Connect (OSTI)

    Zvonarev, P. S.; Farrell, T. J.; Hunter, R.; Wierzbicki, M.; Hayward, J. E.; Sur, R. K.

    2013-02-15

    Purpose: A 2D/3D registration algorithm is proposed for registering orthogonal x-ray images with a diagnostic CT volume for high dose rate (HDR) lung brachytherapy. Methods: The algorithm utilizes a rigid registration model based on a pixel/voxel intensity matching approach. To achieve accurate registration, a robust similarity measure combining normalized mutual information, image gradient, and intensity difference was developed. The algorithm was validated using a simple body and anthropomorphic phantoms. Transfer catheters were placed inside the phantoms to simulate the unique image features observed during treatment. The algorithm sensitivity to various degrees of initial misregistration and to the presence of foreign objects, such as ECG leads, was evaluated. Results: The mean registration error was 2.2 and 1.9 mm for the simple body and anthropomorphic phantoms, respectively. The error was comparable to the interoperator catheter digitization error of 1.6 mm. Preliminary analysis of data acquired from four patients indicated a mean registration error of 4.2 mm. Conclusions: Results obtained using the proposed algorithm are clinically acceptable especially considering the complications normally encountered when imaging during lung HDR brachytherapy.

  5. Off-axis illumination direct-to-digital holography

    DOE Patents [OSTI]

    Thomas, Clarence E.; Price, Jeffery R.; Voelkl, Edgar; Hanson, Gregory R.

    2004-06-08

    Systems and methods are described for off-axis illumination direct-to-digital holography. A method of recording an off-axis illuminated spatially heterodyne hologram including spatially heterodyne fringes for Fourier analysis, includes: reflecting a reference beam from a reference mirror at a non-normal angle; reflecting an object beam from an object at an angle with respect to an optical axis defined by a focusing lens; focusing the reference beam and the object beam at a focal plane of a digital recorder to form the off-axis illuminated spatially heterodyne hologram including spatially heterodyne fringes for Fourier analysis; digitally recording the off-axis illuminated spatially heterodyne hologram including spatially heterodyne fringes for Fourier analysis; Fourier analyzing the recorded off-axis illuminated spatially heterodyne hologram including spatially heterodyne fringes by transforming axes of the recorded off-axis illuminated spatially heterodyne hologram including spatially heterodyne fringes in Fourier space to sit on top of a heterodyne carrier frequency defined as an angle between the reference beam and the object beam; applying a digital filter to cut off signals around an original origin; and then performing an inverse Fourier transform.

  6. Electroexcitation of the Δ(1232)3/2+ and Δ(1600)3/2+ in a light-front relativistic quark model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aznauryan, Inna G.; Burkert, Volker D.

    2015-09-30

    The magnetic-dipole form factor and the ratios REM and RSM for the γ* N → Δ(1232)3/2+ transition are predicted within light-front relativistic quark model up to photon virtuality Q2=12 GeV2. Furthermore, we predict the helicity amplitudes of the γ* N → Δ(1600)3/2+ transition assuming the Δ(1600)3/2+ is the first radial excitation of the ground state Delta(1232)3/2+.

  7. TSAR2.3. Temporal Scattering And Response

    SciTech Connect (OSTI)

    McLeod, R.R.; Ray, S.L.; Laguna, G.; Allison, M.; Cabral, B.

    1991-12-01

    TSAR2.3 (Temporal Scattering and Response) is a finite-difference time-domain electromagnetics code suite. TSAR2.3 is a software package for simulating the interactions of electromagnetic waves with linear materials through the use of the finite-difference time-domain method. The code suite contains grid generation, grid verification, input-file creation and post-processing utilities. The physics package, written in Fortran 77, can be pre-processed to run on many different architectures including Cray, Vax and many Unix workstations. Tools are provided to easily port the code to new computers. The physics package is an efficient, flexible electromagnetic simulator. A body under study can be represented as a three-dimensional grid of materials with arbitrary linear properties. This grid can be simulated in a number of ways including incident plane waves, dipoles, and arbitrary incident fields. The grid can be terminated with numerous boundary conditions including free-space radiation, electric conductor, or magnetic conductor. Projection to the far-field in both the time and frequency domains is possible. This distribution includes make files for installing and maintaining the entire code suite.

  8. Yttria-stabilized zirconia buffered silicon to optimize in-plane electrical conductivity of [Ca{sub 2}CoO{sub 3}]{sub 0.62}[CoO{sub 2}] thin films

    SciTech Connect (OSTI)

    Kraus, T.; Griesser, A.; Klein, O.; Fischer, M.; Schreck, M.; Karl, H.

    2014-05-05

    The monolithic integration of thermoelectric generators and magnetoresistive functionality on the basis of misfit cobaltate [Ca{sub 2}CoO{sub 3}]{sub 0.62}[CoO{sub 2}] thin films into silicon technology is a prerequisite for their application in miniaturized electric circuits. Here, we report on [Ca{sub 2}CoO{sub 3}]{sub 0.62}[CoO{sub 2}] thin films grown by pulsed laser deposition on (001)-silicon with a thin epitaxial yttria-stabilized zirconia (YSZ) buffer layer. X-ray diffraction and cross-sectional high resolution transmission electron microscopy analysis reveal that high quality c-axis oriented heteroepitaxial [Ca{sub 2}CoO{sub 3}]{sub 0.62}[CoO{sub 2}] films with a 12-fold in-plane rotational symmetry can be grown, which exhibit remarkable lower electrical resistivity compared to those with random in-plane orientation. This result is explained by energetically preferred epitaxial growth directions of the pseudo hexagonal [CoO{sub 2}] sublayer in monoclinic [Ca{sub 2}CoO{sub 3}]{sub 0.62}[CoO{sub 2}] onto the cubic (001)-YSZ surface leading to a highly symmetric in-plane mutual orientation of the charge transporting CoO{sub 2} sublayer domains.

  9. IMPERMEABLE THIN Al{sub 2}O{sub 3} OVERLAY FOR TBC PROTECTION FROM SULFATE AND VANADATE ATTACK IN GAS TURBINES

    SciTech Connect (OSTI)

    Scott X. Mao

    2004-03-31

    To improve the hot corrosion resistance of YSZ thermal barrier coatings, a 25 {micro}m thick Al{sub 2}O{sub 3} overlay were deposited by HVOF thermal spray, respectively, onto to the surface of YSZ coating. In the next reporting period, we will measure or calculate the residue stress within Al{sub 2}O{sub 3} overlay and YSZ coating to study the mechanism of effect of Al{sub 2}O{sub 3} overlay on spalling of YSZ coating. However, due to the thermal expansion mismatch between YSZ coating and Al{sub 2}O{sub 3} overlay, such surface modification using Al{sub 2}O{sub 3} overlay might deteriorate strain tolerance of the TBC. In the present work, in order to investigate the effect of Al{sub 2}O{sub 3} overlay on residual stress developed in the samples during cooling after hot corrosion at high temperature, Finite Element method (FEM) was employed to determine the detailed stress states in the test specimens after cooling. The results showed that there is no high stress concentration at the interface between the YSZ and the bond coat for TBCs system without Al{sub 2}O{sub 3} overlay. On the other hand, the maximum compressive stress with a value of approximately, -330 MPa occurred within the Al{sub 2}O{sub 3} overlay. The maximum tensile stress in YSZ coat near the Al{sub 2}O{sub 3} overlay is in the range of 10-133 MPa. The maximum compressive stress of approximately -160 MPa occurred near the YSZ-bond coat interface. X axis stress play a dominant role in influencing the coating failure and spalling. In the next reporting period, we will study the thickness of Al{sub 2}O{sub 3} overlay on hot corrosion resistance and spalling of YSZ coating.

  10. Investigation of the La{sub 2}O{sub 3}–Nb{sub 2}O{sub 5}–WO{sub 3} ternary phase diagram: Isolation and crystal structure determination of the original La{sub 3}NbWO{sub 10} material

    SciTech Connect (OSTI)

    Vu, T.D.; Barre, M.; Adil, K.; Jouanneaux, A.; Suard, E.; Goutenoire, F.

    2015-09-15

    In the course of the exploration of the La{sub 2}O{sub 3}–WO{sub 3}–Nb{sub 2}O{sub 5} ternary phase diagram, a new compound with the formula La{sub 3}NbWO{sub 10} was discovered. Its structure was determined from a combination of powder X-ray and neutron diffraction data. It crystallizes in the tetragonal space group P4{sub 2}/nmc (no. 137) with the lattice parameters: a=10.0807(1) Å; c=12.5540(1) Å. The structure is built up from infinite ribbons of octahedra (W/Nb)O{sub 5} which are perpendicular to each other, lanthanum ions being distributed around these ribbons. The electrical properties of this compound were investigated on sintered pellets by means of complex impedance spectroscopy. - Graphical abstract: Projection along the c-axis of cationic and anionic positions of a La{sub 3}NbWO{sub 10} unit cell. - Highlights: • The structure of La{sub 3}NbWO{sub 10} was resolved from the XRD and ND data. • The structure was described in many ways. • The ionic conduction property was studied.

  11. Influence of compensator thickness, field size, and off-axis distance on the effective attenuation coefficient of a cerrobend compensator for intensity-modulated radiation therapy

    SciTech Connect (OSTI)

    Haghparast, Abbas; Hashemi, Bijan; Eivazi, Mohammad Taghi

    2013-04-01

    Intensity-modulated radiation therapy (IMRT) can be performed by using compensators. To make a compensator for an IMRT practice, it is required to calculate the effective attenuation coefficient (?{sub eff}) of its material, which is affected by various factors. We studied the effect of the variation of the most important factors on the calculation of the ?{sub eff} of the cerrobend compensator for 6-MV photon beams, including the field size, compensator thickness, and off-axis distance. Experimental measurements were carried out at 100 cm source-to-surface distance and 10 cm depth for the 6-MV photon beams of an Elekta linac using various field size, compensator thickness, and off-axis settings. The field sizes investigated ranged from 4 4 to 25 25 cm{sup 2} and the cerrobend compensator thicknesses from 0.56 cm. For a fixed compensator thickness, variation of the ?{sub eff} with the field size ranged from 3.76.8%, with the highest value attributed to the largest compensator thickness. At the reference field size of 10 10 cm{sup 2}, the ?{sub eff} varied by 16.5% when the compensator thickness was increased from 0.56 cm. However, the variation of the ?{sub eff} with the off-axis distance was only 0.99% at this field size, whereas for the largest field size, it was more significant. Our results indicated that the compensator thickness and field size have the most significant effect on the calculation of the compensator ?{sub eff} for the 6-MV photon beam. Therefore, it is recommended to consider these parameters when calculating the compensator thickness for an IMRT practice designed for these beams. The off-axis distance had a significant effect on the calculation of the ?{sub eff} only for the largest field size. Hence, it is recommended to consider the effect of this parameter only for field sizes larger than 25 25 cm{sup 2}.

  12. 2013 DOE Bioenergy Technologies Office (BETO) Project Peer Review WBS 3.2.2.27

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    WBS 3.2.2.27 TAN Control of Bio-oil May 22, 2013 Bio-Oil Technology Area Review Yupo Lin and Seth Snyder Argonne National Laboratory This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal/Objective Statement  Goal - Develop conversion enabling technology to remove destabilized components from bio-oil  Objective - Evaluate the application of Resin Wafer Electrodeionization (RW-EDI) technology on acids/salts removal of pyrolysis bio-oil to

  13. The galaxy cluster mid-infrared luminosity function at 1.3 < z < 3.2

    SciTech Connect (OSTI)

    Wylezalek, Dominika; Vernet, Joël; De Breuck, Carlos; Stern, Daniel; Brodwin, Mark; Galametz, Audrey; Gonzalez, Anthony H.; Jarvis, Matt; Hatch, Nina; Seymour, Nick; Stanford, Spencer A.

    2014-05-01

    We present 4.5 μm luminosity functions for galaxies identified in 178 candidate galaxy clusters at 1.3 < z < 3.2. The clusters were identified as Spitzer/Infrared Array Camera (IRAC) color-selected overdensities in the Clusters Around Radio-Loud AGN project, which imaged 420 powerful radio-loud active galactic nuclei (RLAGNs) at z > 1.3. The luminosity functions are derived for different redshift and richness bins, and the IRAC imaging reaches depths of m* + 2, allowing us to measure the faint end slopes of the luminosity functions. We find that α = –1 describes the luminosity function very well in all redshift bins and does not evolve significantly. This provides evidence that the rate at which the low mass galaxy population grows through star formation gets quenched and is replenished by in-falling field galaxies does not have a major net effect on the shape of the luminosity function. Our measurements for m* are consistent with passive evolution models and high formation redshifts (z{sub f} ∼ 3). We find a slight trend toward fainter m* for the richest clusters, implying that the most massive clusters in our sample could contain older stellar populations, yet another example of cosmic downsizing. Modeling shows that a contribution of a star-forming population of up to 40% cannot be ruled out. This value, found from our targeted survey, is significantly lower than the values found for slightly lower redshift, z ∼ 1, clusters found in wide-field surveys. The results are consistent with cosmic downsizing, as the clusters studied here were all found in the vicinity of RLAGNs—which have proven to be preferentially located in massive dark matter halos in the richest environments at high redshift—and they may therefore be older and more evolved systems than the general protocluster population.

  14. Image Appraisal for 2D and 3D Electromagnetic Inversion

    SciTech Connect (OSTI)

    Alumbaugh, D.L.; Newman, G.A.

    1999-01-28

    Linearized methods are presented for appraising image resolution and parameter accuracy in images generated with two and three dimensional non-linear electromagnetic inversion schemes. When direct matrix inversion is employed, the model resolution and posterior model covariance matrices can be directly calculated. A method to examine how the horizontal and vertical resolution varies spatially within the electromagnetic property image is developed by examining the columns of the model resolution matrix. Plotting the square root of the diagonal of the model covariance matrix yields an estimate of how errors in the inversion process such as data noise and incorrect a priori assumptions about the imaged model map into parameter error. This type of image is shown to be useful in analyzing spatial variations in the image sensitivity to the data. A method is analyzed for statistically estimating the model covariance matrix when the conjugate gradient method is employed rather than a direct inversion technique (for example in 3D inversion). A method for calculating individual columns of the model resolution matrix using the conjugate gradient method is also developed. Examples of the image analysis techniques are provided on 2D and 3D synthetic cross well EM data sets, as well as a field data set collected at the Lost Hills Oil Field in Central California.

  15. Determination of Elastic Twist in Horizontal Axis Wind Turbines (HAWTs)

    SciTech Connect (OSTI)

    Stoddard, F.; Nelson, V.; Starcher, K.; Andrews, B.

    2006-06-01

    This report presents the results of a project at the Alternative Energy Institute (AEI) which measured and calculated the elastic twist of three representative composite horizontal-axis blades: Carter 300, Gougeon ESI 54, and UTRC 8 kW.

  16. Roger Road Reservoir Single-Axis Photovoltaic Array

    Broader source: Energy.gov [DOE]

    In this photograph, the Roger Road Reclamation Water Reservoir features a 110-kilowatt (kW) solar array. This system was built on a reservoir deck as its special design allowed for a single-axis...

  17. EIS-0228: Dual Axis Radiographic Hydrodynamic Test (DARHT) Facility

    Broader source: Energy.gov [DOE]

    This EIS evaluates the potential environmental impact of a proposal to construct and operate the Dual Axis Radiographic Hydrodynamic Test (DARHT) facility at Los Alamos National Laboratory (LANL)...

  18. Host cells and methods for producing 3-methyl-2-buten-1-ol, 3-methyl-3-buten-1-ol, and 3-methyl-butan-1-ol

    DOE Patents [OSTI]

    Chou, Howard H.; Keasling, Jay D.

    2011-07-26

    The invention provides for a method for producing a 5-carbon alcohol in a genetically modified host cell. In one embodiment, the method comprises culturing a genetically modified host cell which expresses a first enzyme capable of catalyzing the dephosphorylation of an isopentenyl pyrophosphate (IPP) or dimethylallyl diphosphate (DMAPP), such as a Bacillus subtilis phosphatase (YhfR), under a suitable condition so that 5-carbon alcohol is 3-methyl-2-buten-1-ol and/or 3-methyl-3-buten-1-ol is produced. Optionally, the host cell may further comprise a second enzyme capable of reducing a 3-methyl-2-buten-1-ol to 3-methyl-butan-1-ol, such as a reductase.

  19. Gearbox Reliability Collaborative Phase 3 Gearbox 2 Test Report

    SciTech Connect (OSTI)

    Keller, Jonathan; Wallen, Robb

    2015-06-10

    Many gearboxes in wind turbines have not been achieving their expected design life [1]; they do, however, commonly meet or exceed the design criteria specified in current standards in the gear, bearing, and wind turbine industry as well as third-party certification criteria. The cost of gearbox replacements and rebuilds, as well as the downtime associated with these failures, has elevated the cost of wind energy. In 2006, the U.S. Department of Energy established the National Renewable Energy Laboratory (NREL) Gearbox Reliability Collaborative (GRC). Its key goal is to understand the root causes of premature gearbox failures and improve their reliability [2]. The GRC is examining a hypothesis that the gap between design-estimated and actual wind turbine gearbox reliability is caused by underestimation of loads, inaccurate design tools, the absence of critical elements in the design process, or insufficient testing. This test report describes the recent tests of GRC gearbox (GB) 2 in the National Wind Technology Center (NWTC) dynamometer and documents any modifications to the original test plan [3]. In this manner, it serves as a guide for interpreting the publicly released data sets with brief analyses to illustrate the data. Specific objectives of the test were to assess the effect of dynamic nontorque load (NTL) on the planetary section, generator misalignment on the highspeed shaft (HSS), and field representative conditions on the gearbox in general. Detailed analysis of those test objectives will be presented in subsequent publications.

  20. Three-dimensional Numerical Analysis on Blade Response of Vertical Axis Tidal Current Turbine Under Operational Condition

    SciTech Connect (OSTI)

    Li, Ye; Karri, Naveen K.; Wang, Qi

    2014-04-30

    Tidal power as a large-scale renewable source of energy has been receiving significant attention recently because of its advantages over the wind and other renewal energy sources. The technology used to harvest energy from tidal current is called a tidal current turbine. Though some of the principles of wind turbine design are applicable to tidal current turbines, the design of latter ones need additional considerations like cavitation damage, corrosion etc. for the long-term reliability of such turbines. Depending up on the orientation of axis, tidal current turbines can be classified as vertical axis turbines or horizontal axis turbines. Existing studies on the vertical axis tidal current turbine focus more on the hydrodynamic aspects of the turbine rather than the structural aspects. This paper summarizes our recent efforts to study the integrated hydrodynamic and structural aspects of the vertical axis tidal current turbines. After reviewing existing methods in modeling tidal current turbines, we developed a hybrid approach that combines discrete vortex method -finite element method that can simulate the integrated hydrodynamic and structural response of a vertical axis turbine. This hybrid method was initially employed to analyze a typical three-blade vertical axis turbine. The power coefficient was used to evaluate the hydrodynamic performance, and critical deflection was considered to evaluate the structural reliability. A sensitivity analysis was also conducted with various turbine height-to-radius ratios. The results indicate that both the power output and failure probability increase with the turbine height, suggesting a necessity for optimal design. An attempt to optimize a 3-blade vertical axis turbine design with hybrid method yielded a ratio of turbine height to radius (H/R) about 3.0 for reliable maximum power output.

  1. updated_supplemental_lists_1k-2k-3j-_1-10-2012.xlsx | Department...

    Energy Savers [EERE]

    k-2k-3j-1-10-2012.xlsx updatedsupplementallists1k-2k-3j-1-10-2012.xlsx File updatedsupplementallists1k-2k-3j-1-10-2012.xlsx More Documents & Publications...

  2. updated_supplemental_lists_1j-2j-3i_12-22-2011.xlsx | Department...

    Energy Savers [EERE]

    j-2j-3i12-22-2011.xlsx updatedsupplementallists1j-2j-3i12-22-2011.xlsx File updatedsupplementallists1j-2j-3i12-22-2011.xlsx More Documents & Publications...

  3. Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene from 3,5-dichloroanisole

    DOE Patents [OSTI]

    Ott, D.G.; Benziger, T.M.

    1991-03-05

    Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) from 3,5-dichloroanisole is described. Nitration of 3,5-dichloroanisole under relatively mild conditions gave 3,5-dichloro-2,4,6-trinitroanisole in high yield and purity. Ammonolysis of this latter compound gave the desired TATB. Another route to TATB was through the treatment of the 3,5-dichloro-2,4,6-trinitroanisole with thionyl chloride and dimethylformamide to yield 1,3,5-trichloro-2,4,6-trinitrobenzene. Ammonolysis of this product produced TATB. 8 figures.

  4. Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene from 3,5-dichloroanisole

    DOE Patents [OSTI]

    Ott, Donald G. (Los Alamos, NM); Benziger, Theodore M. (Santa Fe, NM)

    1991-01-01

    Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) from 3,5-dichloroanisole. Nitration of 3,5-dichloroanisole under relatively mild conditions gave 3,5-dichloro-2,4,6-trinitroanisole in high yield and purity. Ammonolysis of this latter compound gave the desired TATB. Another route to TATB was through the treatment of the 3,5-dichloro-2,4,6-trinitroanisole with thionyl chloride and dimethylformamide to yield 1,3,5-trichloro-2,4,6-trinitrobenzene. Ammonolysis of this product produced TATB.

  5. Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene from 3,5-dichloranisole

    DOE Patents [OSTI]

    Ott, Donald G. (Los Alamos, NM); Benziger, Theodore M. (Santa Fe, NM)

    1990-01-01

    Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) from 3,5-dichloroanisole. Nitration of 3,5-dichloroanisole under relatively mild conditions gave 3,5-dichloro-2,4,6-trinitroanisole in high yield and purity. Ammonolysis of this latter compound gave the desired TATB. Another route to TATB was through the treatment of the 3,5-dichloro-2,4,6-trinitroanisole with thionyl chloride and dimethylformamide to yield 1,3,5-trichloro-2,4,6-trinitrobenzene. Ammonolysis of this product produced TATB.

  6. Data Release Report for Source Physics Experiments 2 and 3 (SPE-2 and SPE-3) Nevada National Security Site

    SciTech Connect (OSTI)

    Townsend, Margaret; Obi, Curtis

    2015-04-30

    The second Source Physics Experiment shot (SPE-2) was conducted in Nevada on October 25, 2011, at 1900:00.011623 Greenwich Mean Time (GMT). The explosive source was 997 kilograms (kg) trinitrotoluene (TNT) equivalent of sensitized heavy ammonium fuel oil (SHANFO) detonated at a depth of 45.7 meters (m). The third Source Physics Experiment shot (SPE-3) was conducted in Nevada on July 24, 2012, at 1800:00.44835 GMT. The explosive source was 905 kg TNT equivalent of SHANFO detonated at a depth of 45.8 m. Both shots were recorded by an extensive set of instrumentation that includes sensors both at near-field (less than 100 m) and far-field (100 m or greater) distances. The near-field instruments consisted of three-component accelerometers deployed in boreholes at 15, 46, and 55 m depths around the shot and a set of single-component vertical accelerometers on the surface. The far-field network was composed of a variety of seismic and acoustic sensors, including short-period geophones, broadband seismometers, three-component accelerometers, and rotational seismometers at distances of 100 m to 25 kilometers. This report coincides with the release of these data for analysts and organizations that are not participants in this program. This report describes the second and third Source Physics Experiment shots and the various types of near-field and farfield data that are available.This revised document includes reports on baseline shift corrections for the SPE-2 and SPE-3 shots that were missing from the original January 2015 version.

  7. Synthesis and structure of R{sub 2}[UO{sub 2}(NO{sub 3}){sub 2}(NCS){sub 2}] (R = Rb or Cs)

    SciTech Connect (OSTI)

    Serezhkin, V. N.; Peresypkina, E. V.; Grigor’eva, V. A.; Virovets, A. V.; Serezhkina, L. B.

    2015-01-15

    Crystals Rb{sub 2}[UO{sub 2}(NO{sub 3}){sub 2}(NCS){sub 2}] (I) and Cs{sub 2}[UO{sub 2}(NO{sub 3}){sub 2}(NCS){sub 2}] (II) have been synthesized and studied by IR spectroscopy and X-ray diffraction. Crystals I are monoclinic, with the following parameters: a = 12.2118(5) Å, b = 10.2545(3) Å, c = 11.8754(4) Å, β = 110.287(1)°, sp. gr. C2/c, Z = 4, and R = 0.0523. Crystals II are orthorhombic, with a = 13.7309(3) Å, b = 10.5749(2) Å, c = 10.1891(2) Å, sp. gr. Pnma, Z = 4, and R = 0.0411. The basic structural units of crystals I and II are one-core complexes [UO{sub 2}(NO{sub 3}){sub 2}(NCS){sub 2}]{sup 2−}, which belong to the crystallochemical group cis-AB{sub 2}{sup 01}M{sub 2}{sup 1} (A = UO{sub 2}{sup 2+}, B{sup 01} = NO{sub 3}{sup −}, M{sup 1} = NCS{sup −}), which are combined into a framework via electrostatic interactions with ions of alkaline metals R (R = Rb or Cs). The structural features of crystals I and II, which condition the formation of [UO{sub 2}(NO{sub 3}){sub 2}(NCS){sub 2}]{sup 2−} complexes with a cis rather than a trans position of isothiocyanate ions in the coordination sphere of uranyl ions, are discussed.

  8. Plasma ionization frequency, edge-to-axis density ratio, and density on axis of a cylindrical gas discharge

    SciTech Connect (OSTI)

    Palacio Mizrahi, J. H.

    2014-06-15

    A rigorous derivation of expressions, starting from the governing equations, for the ionization frequency, edge-to-axis ratio of plasma density, plasma density at the axis, and radially averaged plasma density in a cylindrical gas discharge has been obtained. The derived expressions are simple and involve the relevant parameters of the discharge: Cylinder radius, axial current, and neutral gas pressure. The found expressions account for ion inertia, ion temperature, and changes in plasma ion collisionality.

  9. Cytotoxicity, genotoxicity, and mutagenicity of 1-chloro-2-hydroxy-3-butene and 1-chloro-3-buten-2-one, two alternative metabolites of 1,3-butadiene

    SciTech Connect (OSTI)

    Liu, Xin-Jie; Zeng, Fang-Mao; An, Jing; Yu, Ying-Xin; Zhang, Xin-Yu; Elfarra, Adnan A.

    2013-08-15

    The cytotoxicity, genotoxicity, and mutagenicity of 1-chloro-2-hydroxy-3-butene (CHB), a known in vitro metabolite of the human carcinogen 1,3-butadiene, have not previously been investigated. Because CHB can be bioactivated by alcohol dehydrogenases to yield 1-chloro-3-buten-2-one (CBO), a bifunctional alkylating agent that caused globin-chain cross-links in erythrocytes, in the present study we investigated the cytotoxic and genotoxic potential of CHB and CBO in human normal hepatocyte L02 cells using the MTT assay, the relative cloning efficiency assay and the comet assay. We also investigated the mutagenic potential of these compounds with the Ames test using Salmonella strains TA1535 and TA1537. The results provide clear evidence for CHB and CBO being both cytotoxic and genotoxic with CBO being approximately 100-fold more potent than CHB. Interestingly, CHB generated both single-strand breaks and alkali-labile sites on DNA, whereas CBO produced only alkali-labile sites. CHB did not directly result in DNA breaks, whereas CBO was capable of directly generating breaks on DNA. Interestingly, both compounds did not induce DNA cross-links as examined by the comet assay. The Ames test results showed that CHB induced point mutation but not frameshift mutation, whereas the toxic effects of CBO made it difficult to reliably assess the mutagenic potential of CBO in the two strains. Collectively, the results suggest that CHB and CBO may play a role in the mutagenicity and carcinogenicity of 1,3-butadiene. - Highlights: 1-Chloro-2-hydroxy-3-butene (CHB) is cytotoxic and genotoxic in human liver cells. The CHB metabolite, 1-chloro-3-buten-2-one (CBO) is ? 100-fold more toxic than CHB. CHB and CBO cause DNA alkali-labile sites, but only CBO directly causes DNA breaks. CHB is mutagenic in the Ames test, but CBO is too toxic in the assay. The results suggest a role for CHB in 1,3-butadiene genotoxicity and mutagenicity.

  10. Antitumour agents as inhibitors of tryptophan 2,3-dioxygenase

    SciTech Connect (OSTI)

    Pantouris, Georgios; Mowat, Christopher G.

    2014-01-03

    Highlights: •∼2800 National Cancer Institute USA compounds have been screened as potential inhibitors of TDO and/or IDO. •Seven compounds with anti-tumour properties have been identified as potent inhibitors. •NSC 36398 (taxifolin, dihydroquercetin) is selective for TDO with a K{sub i} of 16 M. •This may help further our understanding of the role of TDO in cancer. -- Abstract: The involvement of tryptophan 2,3-dioxygenase (TDO) in cancer biology has recently been described, with the enzyme playing an immunomodulatory role, suppressing antitumour immune responses and promoting tumour cell survival and proliferation. This finding reinforces the need for specific inhibitors of TDO that may potentially be developed for therapeutic use. In this work we have screened ∼2800 compounds from the library of the National Cancer Institute USA and identified seven potent inhibitors of TDO with inhibition constants in the nanomolar or low micromolar range. All seven have antitumour properties, killing various cancer cell lines. For comparison, the inhibition potencies of these compounds were tested against IDO and their inhibition constants are reported. Interestingly, this work reveals that NSC 36398 (dihydroquercetin, taxifolin), with an in vitro inhibition constant of ∼16 μM, is the first TDO-selective inhibitor reported.

  11. IDC RP2 & 3 US Industry Standard Cost Estimate Summary.

    SciTech Connect (OSTI)

    Harris, James M.; Huelskamp, Robert M.

    2015-01-01

    Sandia National Laboratories has prepared a ROM cost estimate for budgetary planning for the IDC Reengineering Phase 2 & 3 effort, using a commercial software cost estimation tool calibrated to US industry performance parameters. This is not a cost estimate for Sandia to perform the project. This report provides the ROM cost estimate and describes the methodology, assumptions, and cost model details used to create the ROM cost estimate. ROM Cost Estimate Disclaimer Contained herein is a Rough Order of Magnitude (ROM) cost estimate that has been provided to enable initial planning for this proposed project. This ROM cost estimate is submitted to facilitate informal discussions in relation to this project and is NOT intended to commit Sandia National Laboratories (Sandia) or its resources. Furthermore, as a Federally Funded Research and Development Center (FFRDC), Sandia must be compliant with the Anti-Deficiency Act and operate on a full-cost recovery basis. Therefore, while Sandia, in conjunction with the Sponsor, will use best judgment to execute work and to address the highest risks and most important issues in order to effectively manage within cost constraints, this ROM estimate and any subsequent approved cost estimates are on a 'full-cost recovery' basis. Thus, work can neither commence nor continue unless adequate funding has been accepted and certified by DOE.

  12. A lightweight high performance dual-axis gimbal for space applications

    SciTech Connect (OSTI)

    Pines, D.J.; Hakala, D.B.; Malueg, R.

    1995-05-05

    This paper describes the design, development and performance of a lightweight precision gimbal with dual-axis slew capability to be used in a closed-loop optical tracking system at Lawrence Livermore National Laboratory-LLNL. The motivation for the development of this gimbal originates from the need to acquire and accurately localize warm objects (T{approximately}500 K) in a cluttered background. The design of the gimbal is centered around meeting the following performance requirements: pointing accuracy with control < 35 {mu}rad-(1-{omega}); slew capability > 0.2 rad/sec; mechanical weight < 5 kg. These performance requirements are derived by attempting to track a single target from multiple satellites in low Earth orbit using a mid-wave infrared camera. Key components in the gimbal hardware that are essential to meeting the performance objectives include a nickel plated beryllium mirro, an accurate lightweight capacitive pickoff device for angular measurement about the elevation axis, a 16-bit coarse/fine resolver for angular measurement about the azimuth axis, a toroidally wound motor with low hysteresis for providing torque about the azimuth axis, and the selection of beryllium parts to insure high stiffness to weight ratios and more efficient thermal conductivity. Each of these elements are discussed in detail to illustrate the design trades performed to meet the tracking and slewing requirements demanded. Preliminary experimental results are also given for various commanded tracking maneuvers.

  13. Static-stress analysis of dual-axis confinement vessel

    SciTech Connect (OSTI)

    Bultman, D.H.

    1992-11-01

    This study evaluates the static-pressure containment capability of a 6-ft-diameter, spherical vessel, made of HSLA-100 steel, to be used for high-explosive (HE) containment. The confinement vessel is designed for use with the Dual-Axis Radiographic Hydrotest Facility (DARHT) being developed at Los Alamos National Laboratory. Two sets of openings in the vessel are covered with x-ray transparent covers to allow radiographic imaging of an explosion as it occurs inside the vessel. The confinement vessel is analyzed as a pressure vessel based on the ASME Boiler and Pressure Vessel Code, Section VIII, Division 1, and the Welding Research Council Bulletin, WRC-107. Combined stresses resulting from internal pressure and external loads on nozzles are calculated and compared with the allowable stresses for HSLA-100 steel. Results confirm that the shell and nozzles of the confinement vessel are adequately designed to safely contain the maximum residual pressure of 1675 psi that would result from an HE charge of 24.2 kg detonated in a vacuum. Shell stresses at the shell-to-nozzle interface, produced from external loads on the nozzles, were less than 400 psi. The maximum combined stress resulting from the internal pressure plus external loads was 16,070 psi, which is less than half the allowable stress of 42,375 psi for HSLA-100 steel.

  14. Request for Duplicate Form W-2 3/2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    my Wage and Tax Statement (Form W-2): Name: Last 4 Digits of Social Security Number: Z Number: Contact Phone: Email: Distribution of W-2 form (due to confidentiality, W-2's will...

  15. Lasing characteristics of ZrO{sub 2}Y{sub 2}O{sub 3}Ho{sub 2}O{sub 3} crystal

    SciTech Connect (OSTI)

    Borik, M A; Lomonova, E E; Kulebyakin, A V; Ushakov, S N; Lyapin, A A; Ryabochkina, P A; Chabushkin, A N

    2013-09-30

    The spectral dependences of the gain cross section of the {sup 5}I{sub 8} ? {sup 5}I{sub 7}, {sup 5}I{sub 7} ? {sup 5}I{sub 8} transition of Ho{sup 3+} ions in the ZrO{sub 2} 13.6 mol % Y{sub 2}O{sub 3} 0.4 mol % Ho{sub 2}O{sub 3} crystal are calculated at different relative population inversions using the absorption and luminescence spectra of the {sup 5}I{sub 8} ? {sup 5}I{sub 7} and {sup 5}I{sub 7} ? {sup 5}I{sub 8} transitions of Ho{sup 3+} ions at T=''300'' K. Lasing of these crystals at the {sup 5}I{sub 7} ? {sup 5}I{sub 8} transition is obtained for the first time under pumping by a Tm : YLiF{sub 4} laser (?{sub p} = 1.905 ?m). The lasing wavelength is 2.17 ?m. (lasers)

  16. Budget Period 2 Summary Report Part 3: Hywind Maine Project

    SciTech Connect (OSTI)

    Driscoll, Frederick; Platt, Andrew; Sirnivas, Senu

    2015-08-15

    This project was performed under the Work for Others—Funds in Agreement FIA-14-1793 between Statoil and the Alliance for Sustainable Energy, manager and operator of the National Renewable Energy Laboratory (NREL). To support the development of a 6-MW spar-mounted offshore wind turbine, NREL performed tasks on behalf of Statoil in the following three categories: 1. Design and analysis 2. Wake modeling 3. Concept resource assessment. This document summarizes the work performed in Work Package (WP) 3, where the spatial variability and influence that relevant parameters have on levelized cost of energy (LCOE) were analyzed. The study allows Statoil to identify areas of interest for floating wind technology and the Hywind concept in particular. This report describes the results of a study that NREL conducted to provide targeted insight into the United States (U.S.) offshore wind resource area that Statoil can use for taking strategic decisions about how to commercialize and market the company’s Hywind technology. The report centers on a new spatio-economic methodology that NREL has developed to assess how variability in spatial parameters can influence levelized cost of energy (LCOE) for different technologies. The method combines wind plant performance modeling, economic modeling, and national geospatial data layers to estimate the cost of potential projects using Hywind technology, considering the following parameters: • Water depth • Possible inshore assembly areas • Wind resource • Existing grid features and potential connection points • Wave regime • Environmentally sensitive areas • Seabed conditions • Competitive use areas • Prospective staging ports The scope of the study covers the major offshore regions within the contiguous United States, including the Atlantic Ocean, Gulf of Mexico, Pacific Ocean, and the Great Lakes. The spatio-economic assessment extends to 92 km (50 nm) off of the nearest land mass, consistent with the available data

  17. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    9 Average Annual Energy Expenditures per Household, by Year ($2010) Year 1980 1,991 1981 1,981 1982 2,058 1983 2,082 1984 2,067 1985 2,012 1986 1,898 1987 1,846 1988 1,849 1989 1,848 1990 1,785 1991 1,784 1992 1,729 1993 1,797 1994 1,772 1995 1,727 1996 1,800 1997 1,761 1998 1,676 1999 1,659 2000 1,824 2001 1,900 2002 1,830 2003 1,978 2004 2,018 2005 2,175 2006 2,184 2007 2,230 2008 2,347 2009 2,173 2010 2,201 2011 2,185 2012 2,123 2013 2,056 2014 2,032 2015 2,030 2016 2,007 2017 1,992 2018

  18. YBa sub 2 Cu sub 3 O sub 7 minus x -Y sub 2 O sub 3 system and in situ deposition of trilayer heterostructures by coevaporation

    SciTech Connect (OSTI)

    Ying, Q.Y.; Hilbert, C.; Kumar, N.; Eichman, D.; Thompson, M.; Kroger, H. , Austin, Texas ); Hwang, D.M. )

    1991-12-02

    We have deposited YBa{sub 2}Cu{sub 3}O{sub 7{minus}{ital x}}-Y{sub 2}O{sub 3}-YBa{sub 2}Cu{sub 3}O{sub 7{minus}{ital x}} heterostuctures by an {ital in} {ital situ} electron-beam coevaporation technique. Physical and chemical properties of Y{sub 2}O{sub 3} were studied. The deposition conditions for Y{sub 2}O{sub 3} and YBa{sub 2}Cu{sub 3}O{sub 7{minus}{ital x}} are completely compatible. The crystal structure of Y{sub 2}O{sub 3} provides a close lattice match with YBa{sub 2}Cu{sub 3}O{sub 7{minus}{ital x}} and allows oxygen diffusion through Y{sub 2}O{sub 3}, so that heteroepitaxy and the tetragonal-orthorhombic structural transformations of YBa{sub 2}Cu{sub 3}O{sub 7{minus}{ital x}} can be achieved. The heterostructures are therefore of high quality. Both the top and the bottom YBa{sub 2}Cu{sub 3}O{sub 7{minus}{ital x}} layers are superconducting above 85 K. Tunneling phenomena on junctions fabricated from these trilayers were observed.

  19. "Table HC3.2 Living Space Characteristics by Owner-Occupied...

    U.S. Energy Information Administration (EIA) Indexed Site

    "2,500 to 2,999",10.3,9.3,8.6,0.5,"Q","Q","Q" "3,000 to 3,499",6.7,6.1,5.8,0.3,"Q","N","N" "3,500 to 3,999",5.2,4.9,4.7,"Q","Q","Q","N" "4,000 or More",13.3,12.6,12,0.5,"Q","Q",...

  20. Electrical generation using a vertical-axis wind turbine

    SciTech Connect (OSTI)

    Clark, R.N.

    1982-12-01

    Traditionally, windmills have been of the propeller or multiblade types, both of which have their rotational axis parallel to the flow of the wind. A vertical-axis wind turbine has its rotational axis perpendicular to the flow of wind and requires no orientation to keep the rotor in the windstream. The vertical-axis wind turbine operates on the same principle as an airfoil and produces lift and drag as any airfoil. A newly designed 100-kW vertical-axis wind turbine has been operated for one year at the USDA Conservation and Production Research Laboratory, Bushland, TX. The turbine has an induction generator and supplies power to a sprinkler irrigation system with excess power being sold to the electric utility. The turbine begins producing power at 5.5 m/s windspeed and reaches its rated output of 100-kW at 15 m/s. The unit has obtained a peak efficiency of 48% at a windspeed of 8 m/s or 81% of theoretical maximum. Using 17 years of windspeed data from the National Weather Service, the annual energy output is estimated at 200,000 kWh. The unit has experienced several operational problems during its initial testing. Guy cables were enlarged to provide greater stiffness to reduce blade stress levels, lightning shorted the main contactor, and the brake system required a complete redesign and modification. The turbine was operational about 60% of the time.

  1. Measurement of a part having a known axis misalignment

    SciTech Connect (OSTI)

    Castleton, R.

    1993-05-01

    It has been shown that undetected misalignment of the axis of a part can lead to unacceptable measurement errors. For this technical note, it is assumed that the axis misalignment has been determined, and that polar sweeps are used to measure the part. The proposed polar sweeps run vertically (ignoring the axis misalignment) between a plane that is parallel to the bottom datum surface of the part and a second such plane that is close to the pole of the part. No attempt is made to correct for axis misalignment by rotation of the part during the measurement sweeps. It is apparent that the distance traveled along the measurement sweep is more than the arc length representing the actual change in elevation in the part coordinate system. It is proposed that the measurement of the part on the vertical path be used as the measurement of the part on the base longitude line. This introduces an error, {delta}{theta}, in the sensitive direction that corresponds to the arc length B-S. It is shown that this error is not significant when the axis misalignment is small.

  2. Impedance spectroscopy study of SiO2-Li2O:Nd2O3 glasses

    SciTech Connect (OSTI)

    Pereia, R.; Gozzo, C B; Guedes, I.; Boatner, Lynn A; Terezo, A J; Costa, M M

    2014-01-01

    In the present study, neodymium-doped lithium silicate glasses have been prepared by the conventional melt-quenching technique. The dielectric properties, electric modulus and electrical conductivity of SiO2-Li2O (SiLi-0Nd) and SiO2-Li2O:Nd2O3 (SiLi-1.35Nd) have been studied from 1 Hz to 1 MHz in the 333 423 K temperature range. At a given temperature and frequency, we observe that the resistivity increases while the conductivity accordingly decreases when neodymium ions are added to the glass matrix. The activation energy of two distinct regions was evaluated from the ln( dc)=f(1/T) plot and was found to be E1(T<363K)=0.61(0.66)eV and E2(T>363K)=1.26(1.09)eV for SiLi-0Nd (SiLi-1,35Nd). The dielectric constant ( Re) decreases while the dielectric loss (tan ( )) increases under Nd2O3 doping. We also observe that for both glasses, Re and tan ( ) tend to increase with increasing temperature and decrease with increasing frequency.

  3. Lattice study of light scalar tetraquarks with I=0,2,1/2,3/2: Are {sigma} and {kappa} tetraquarks?

    SciTech Connect (OSTI)

    Prelovsek, Sasa; Draper, Terrence; Liu, Keh-Fei; Lang, Christian B.; Limmer, Markus; Mathur, Nilmani; Mohler, Daniel

    2010-11-01

    We investigate whether the lightest scalar mesons {sigma} and {kappa} have a large tetraquark component qqqq, as is strongly supported by many phenomenological studies. A search for possible light tetraquark states with J{sup PC}=0{sup ++} and I=0,2,1/2,3/2 on the lattice is presented. We perform the two-flavor dynamical simulation with chirally improved quarks and the quenched simulation with overlap quarks, finding qualitative agreement between both results. The spectrum is determined using the generalized eigenvalue method with a number of tetraquark interpolators at the source and the sink, and we omit the disconnected contractions. The time dependence of the eigenvalues at the finite temporal extent of the lattice is explored also analytically. In all the channels, we unavoidably find the lowest scattering states {pi}(k){pi}(-k) or K(k){pi}(-k) with back-to-back momentum k=0,2{pi}/L,.... However, we find an additional light state in the I=0 and I=1/2 channels, which may be interpreted as the observed resonances {sigma} and {kappa} with a sizable tetraquark component. In the exotic repulsive channels I=2 and I=3/2, where no resonance is observed, we find no light state in addition to the scattering states.

  4. RELAP5/MOD2 assessment simulation of semiscale MOD-2C test S-NH-3

    SciTech Connect (OSTI)

    Megahed, M M

    1987-10-01

    This report documents an evaluation of the RELAP5/MOD2/Cycle 36.05 thermal hydraulic computer code for a simulation of a small-break loss-of-coolant accident transient (SBLOCA). The experimental data base for the evaluation is the results of Test S-NH-3 performed in the Semiscale MOD-2C test facility. The test modeled a 0.5% SBLOCA with an accompanying failure of the high-pressure injection emergency core cooling system. The test facility and RELAP5/MOD2 model used in the calculations are described. Evaluations of the accuracy of the calculations are presented in the form of comparisons of measured and calculated histories of selected parameters associated with the primary and secondary systems. A conclusion was reached that the code is capable of making SBLOCA calculations efficiently. However, some of the SBLOCA-related phenomena were not properly predicted by the code, suggesting a need for code improvement.

  5. Buildings Energy Data Book: 3.2 Commercial Sector Characteristics

    Buildings Energy Data Book [EERE]

    3 Number of Floors and Type of Ownership, as of 2003 (Percent of Total Floorspace) Floors Ownership One 40% Nongovernment Owned 76% Two 25% Owner-Occupied 36% Three 12% Nonowner-Occupied 37% Four to Nine 16% Unoccupied 3% Ten or More 8% Government Owned 24% Total 100% Federal 3% State 5% Local 15% Total 100% Source(s): EIA, Commercial Building Characteristics 2003, June 2006, Table C1

  6. Data Release Report for Source Physics Experiments 2 and 3 (SPE-2 and SPE-3) Nevada National Security Site

    SciTech Connect (OSTI)

    Townsend, Margaret; Obi, Curtis

    2015-01-26

    The second Source Physics Experiment shot (SPE-2) was conducted in Nevada on October 25, 2011, at 1900:00.011623 Greenwich Mean Time (GMT). The explosive source was 997 kilograms (kg) trinitrotoluene (TNT) equivalent of sensitized heavy ammonium fuel oil (SHANFO) detonated at a depth of 45.7 meters (m). The third Source Physics Experiment shot (SPE-3) was conducted in Nevada on July 24, 2012, at 1800:00.44835 GMT. The explosive source was 905 kg TNT equivalent of SHANFO detonated at a depth of 45.8 m. Both shots were recorded by an extensive set of instrumentation that includes sensors both at near-field (less than 100 m) and far-field (100 m or greater) distances. The near-field instruments consisted of three-component accelerometers deployed in boreholes at 15, 46, and 55 m depths around the shot and a set of single-component vertical accelerometers on the surface. The far-field network was composed of a variety of seismic and acoustic sensors, including short-period geophones, broadband seismometers, three-component accelerometers, and rotational seismometers at distances of 100 m to 25 kilometers. This report coincides with the release of these data for analysts and organizations that are not participants in this program. This report describes the second and third Source Physics Experiment shots and the various types of near-field and far-field data that are available.

  7. Microsoft Word - B3 article for web _2_.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NNSANSO Dedicates "Green" Building The National Nuclear Security Administration Nevada Site Office (NNSANSO) has recently completed construction of the B3 administration office. ...

  8. Synthesis of 3-amino-4-hydroxylaminothiazolidine-2-thiones and 2,3-dimethyl-4. cap alpha. ,5-dihydro-7-thioxothiazolo(3,4-b)-1,2,4-triazines

    SciTech Connect (OSTI)

    Epshtein, S.P.; Orlova, T.I.; Rukasov, A.F.; Tashchi, V.P.; Putsykin, Yu. G.

    1987-10-01

    The reaction of dimeric nitroso chlorides of olefins with potassium dithiocarbazate was used to synthesize 3-amino-4-hydroxylaminothiazolidine-2-thiones, which undergo rearrangement to 2-mercapto-1,3,4-thiadiazines on heating and react with butane-2,3-dione to give 2,3-dimethyl-4..cap alpha..,5-dihydro-7-thioxothiazolo(3,4-b)-1,2,4-triazine 4-oxides. The latter are reduced by sodium borohydride to the corresponding 3,4,4..cap alpha..,5-tetrahydro-7-thioxo derivatives. The IR spectra of KBr pellets of the compounds were recorded with a Perkin-Elmer spectrometer. The UV spectra of solutions in ethanol were obtained with a Specord UV spectrophotometer. The PMR spectra of solutions of the compounds in d/sub 6/-DMSO were obtained with a Varian FT-80A spectrometer with tetramethylsilane (TMS) as the internal standard.

  9. Registration of the rotation axis in X-ray tomography

    SciTech Connect (OSTI)

    Yang, Yimeng; Yang, Feifei; Hingerl, Ferdinand F.; Xiao, Xianghui; Liu, Yijin; Wu, Ziyu; Benson, Sally M.; Toney, Michael F.; Andrews, Joy C.; Pianetta, Piero A.

    2015-01-01

    There is high demand for efficient, robust and automated routines for tomographic data reduction, particularly for synchrotron data. Registration of the rotation axis in data processing is a critical step affecting the quality of the reconstruction and is not easily implemented with automation. Existing methods for calculating the center of rotation have been reviewed and an improved algorithm to register the rotation axis in tomographic data is presented. The performance of the proposed method is evaluated using synchrotron-based microtomography data on geological samples with and without artificial reduction of the signal-to-noise ratio. The proposed method improves the reconstruction quality by correcting both the tilting error and the translational offset of the rotation axis. The limitation of this promising method is also discussed.

  10. Superconducting Bi2Te: Pressure-induced universality in the (Bi2)m(Bi2Te3)n series

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stillwell, Ryan L.; Jeffries, Jason R.; Jenei, Zsolt; Weir, Samuel T.; Vohra, Yogesh K.

    2016-03-09

    Using high-pressure magnetotransport techniques we have discovered superconductivity in Bi2Te, a member of the infinitely adaptive (Bi2)m(Bi2Te3)n series, whose end members, Bi and Bi2Te3, can be tuned to display topological surface states or superconductivity. Bi2Te has a maximum Tc = 8.6 K at P = 14.5 GPa and goes through multiple high pressure phase transitions, ultimately collapsing into a bcc structure that suggests a universal behavior across the series. High-pressure magnetoresistance and Hall measurements suggest a semi-metal to metal transition near 5.4 GPa, which accompanies the hexagonal to intermediate phase transition seen via x-ray diffraction measurements. In addition, the linearitymore » of Hc2 (T) exceeds the Werthamer-Helfand-Hohenberg limit, even in the extreme spin-orbit scattering limit, yet is consistent with other strong spin-orbit materials. Furthermore, considering these results in combination with similar reports on strong spin-orbit scattering materials seen in the literature, we suggest the need for a new theory that can address the unconventional nature of their superconducting states.« less

  11. Synthesis and crystal structure of (NH{sub 4}){sub 3}[UO{sub 2}(CH{sub 3}COO){sub 3}]{sub 2}[UO{sub 2}(CH{sub 3}COO)(NCS){sub 2}(H{sub 2}O)

    SciTech Connect (OSTI)

    Serezhkina, L. B.; Peresypkina, E. V.; Virovets, A. V.; Karasev, M. O.

    2010-01-15

    Single crystals of the compound (NH{sub 4}){sub 3}[UO{sub 2}(CH{sub 3}COO){sub 3}]{sub 2}[UO{sub 2}(CH{sub 3}COO)(NCS){sub 2}(H{sub 2}O)] (I) are synthesized, and their structure is investigated using X-ray diffraction. Compound I crystallizes in the monoclinic system with the unit cell parameters a = 18.3414(6) A, b = 16.3858(7) A, c = 12.4183(5) A, {beta} = 92.992(1){sup o}, space group C2/c, Z = 4, V = 3727.1(3) A{sup 3}, and R = 0.0253. The uranium-containing structural units of crystals I are mononuclear complexes of two types with an island structure, i.e., the [UO{sub 2}(CH{sub 3}COO){sub 3}]{sup -} anionic complexes belonging to the crystal-chemical group (AB{sub 3}{sup 01} = UO{sub 2}{sup 2+}, B{sup 01} = CH{sub 3}COO{sup -}) of the uranyl complexes and the [UO{sub 2}(CH{sub 3}COO)(NCS){sub 2}(H{sub 2}O)]{sup -} anionic complexes belonging to the crystal-chemical group AB{sup 01}M{sub 3}{sup 1} (A = UO{sub 2}{sup 2+}, B{sup 01} = CH{sub 3}COO{sup -}, M{sup 1} = NCS{sup -} or H{sub 2}O).

  12. 2D-network of inorganic-organic hybrid material built on Keggin type polyoxometallate and amino acid: [L-C{sub 2}H{sub 6}NO{sub 2}]{sub 3}[(PO{sub 4})Mo{sub 12}O{sub 36}].5H{sub 2}O

    SciTech Connect (OSTI)

    Alizadeh, M.H. Mirzaei, M.; Razavi, H.

    2008-03-04

    A new inorganic-organic hybrid material based on polyoxometallate, [L-C{sub 2}H{sub 6}NO{sub 2}]{sub 3}[(PO{sub 4})Mo{sub 12}O{sub 36}].5H{sub 2}O, has been successfully synthesized and characterized by single-crystal X-ray analysis, elemental analysis, infrared and ultraviolet spectroscopy, proton nuclear magnetic resonance and differential thermal analysis techniques. The title compound crystallizes in the monoclinic space group, P2{sub 1}/c{sub ,} with a = 12.4938 (8) A, b = 19.9326 (12) A, c = 17.9270 (11) A, {beta} = 102.129 (1){sup o}, V = 4364.8 (5) A{sup 3}, Z = 4 and R{sub 1}(wR{sub 2}) = 0.0513, 0.0877. The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like (2D/{infinity} [(PO{sub 4})Mo{sub 12}O{sub 36}]{sup 3-}) which forming via weak Van der Waals interactions along the z axis. The characteristic band of the Keggin anion [(PO{sub 4})Mo{sub 12}O{sub 36}]{sup 3-} appears at 210 nm in the UV spectrum. Thermal analysis indicates that the Keggin anion skeleton begins to decompose at 520 deg. C.

  13. Bifunctional Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+}nanocomposites obtained by the homogeneous precipitation method

    SciTech Connect (OSTI)

    Peng, Hongxia; Cui, Bin; Wang, Yingsai

    2013-05-15

    Graphical abstract: The TEM images reveal clearly the coreshell structures because of the obvious difference in contrast between the central part and the fringe, which indicates the Gd{sub 2}O{sub 3}:Eu{sup 3+} layer had successfully deposited on the magnetite Fe{sub 3}O{sub 4} cores. And Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanoparticles keep the spherical morphology, non-aggregation and rough surface. The images reveal that the average diameters of the Fe{sub 3}O{sub 4} and Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanoparticles are ?200 nm and ?250 nm, respectively. The thickness of Gd{sub 2}O{sub 3}:Eu{sup 3+} layer is ?25 nm. Highlights: ? Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanocomposites were synthesized by homogeneous precipitation method. ? Formation of coreshell nanostructure revealed by transmission electron microscopy. ? Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanocomposites showed magnetic behavior and fluorescence properties. ? Possible applications including bioseparation, drug delivery system, bio-labels, etc. - Abstract: An easy homogeneous precipitation method was developed for the synthesis of bifunctional magnetic-fluorescent nanocomposites with Fe{sub 3}O{sub 4} nanoparticles as the core and europium-doped gadolinium oxide (Gd{sub 2}O{sub 3}:Eu{sup 3+}) as the shell. The nanocomposites showed both strong magnetic behavior and unique Eu-related fluorescence properties with a high emission intensity, which may lead to development of nanocomposites with great potential for applications in drug targeting, biosensors, and diagnostic analysis.

  14. 3D CFD Model of High Temperature H2O/CO2 Co-electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

    2007-06-01

    3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James O’Brien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World

  15. Microsoft Word - L3 THM ITM P3 01 (Rev 2) - Solution Verification...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... obtained by fixing the density and the viscosity values ( 3 1 Kg m and 1 Re ... From a previous study on the same topic both the Smagorinsky and the Dynamic 3 model ...

  16. Three axis vector magnet set-up for cryogenic scanning probe microscopy

    SciTech Connect (OSTI)

    Galvis, J. A.; Herrera, E.; Buendía, A.; Guillamón, I.; Vieira, S.; Suderow, H.; Azpeitia, J.; Luccas, R. F.; Munuera, C.; García-Hernandez, M.; and others

    2015-01-15

    We describe a three axis vector magnet system for cryogenic scanning probe microscopy measurements. We discuss the magnet support system and the power supply, consisting of a compact three way 100 A current source. We obtain tilted magnetic fields in all directions with maximum value of 5T along z-axis and of 1.2T for XY-plane magnetic fields. We describe a scanning tunneling microscopy-spectroscopy (STM-STS) set-up, operating in a dilution refrigerator, which includes a new high voltage ultralow noise piezodrive electronics and discuss the noise level due to vibrations. STM images and STS maps show atomic resolution and the tilted vortex lattice at 150 mK in the superconductor β-Bi{sub 2}Pd. We observe a strongly elongated hexagonal lattice, which corresponds to the projection of the tilted hexagonal vortex lattice on the surface. We also discuss Magnetic Force Microscopy images in a variable temperature insert.

  17. - 1222.2 Construction Schedule_v3

    Broader source: Energy.gov (indexed) [DOE]

    T-Line construction mobilization 3 mons Right-of-way surveys, clearing, erosion control and site prep 18 mons Materials delivered to laydown yard 18 mons Access road construction ...

  18. L3:VUQ.VVDA.P2-2.01 Dan Cacuci NCSU

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Dan Cacuci NCSU Completed: 6/30/11 CASL-U-2011-0055-000 BEST ESTIMATE PLUS REDUCED UNCERTAINTIES (BERU) PREDICTIONS VUQ.Y1.02 Enable generalized data assimilation and model calibration for VERA. 06/30/2011 All VUQ.VVDA.Y1- 2.01 Develop mathematical data assimilation framework 06/30/2011 VUQ.Y1.02 Dan G. Cacuci (April 3, 2011) NOTE: This report is based on the work by : Dan G. Cacuci and Mihaela Ionescu-Bujor, "Model Calibration and Best-Estimate Prediction Through Experimental Data

  19. RAPID/Roadmap/3 (2) | Open Energy Information

    Open Energy Info (EERE)

    (2) < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  20. combined_supplemental_hud_multifamily_weatherization_list_3-2...

    Broader source: Energy.gov (indexed) [DOE]

    lihtc.xls More Documents & Publications list2eligiblemultifamilybuildings10-cfr-440-22b4ii.xls rdmfhlowandverylow.xls hudlist-1...

  1. TEPPC Meeting November 2-3, 2011 San Diego, CA

    Office of Environmental Management (EM)

    BNSF DOE DOD 4. Overarching points in Joint Reply & WIEB's Response to Joint Reply 5. Status 2 The Proposed BNSF Settlement Agreement: Background 1983: DOEDOD sue 21 major ...

  2. CROSSFLOW FILTRATION: EM-31, WP-2.3.6

    SciTech Connect (OSTI)

    Duignan, M.; Nash, C.; Poirier, M.

    2011-02-01

    tests to evaluate methods to improve filter performance. With the proper use of filter flow conditions and filter enhancers, filter flow rates can be increased over rates currently realized today. Experiments that use non-radioactive simulants for actual waste always carry the inherent risk of not eliciting prototypic results; however, they will assist in focusing the scope needed to minimize radioactive testing and thus maximize safety. To that end this investigation has determined: (1) Waste simulant SB6 was found to be more challenging to filtration than a SRS Tank 8F simulant; (2) Higher solids concentration presents a greater challenge to filtration; (3) Filter cake is something that should be properly developed in initial filter operation; (4) Backpulsing is not necessary to maintain a good filter flux with salt wastes; (5) Scouring a filter without cleaning will lead to improved filter performance; (6) The presence of a filter cake can improve the solids separation by an order of magnitude as determined by turbidity; (7) A well developed cake with periodic scouring may allow a good filter flux to be maintained for long periods of time; and (8) Filtrate flux decline is reversible when the concentration of the filtering slurry drops and the filter is scoured.

  3. Critical Updates to the Hydrogen Analysis Production Model (H2A v3)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Critical Updates to the Hydrogen Analysis Production Model (H2A v3) Darlene Steward NREL Thursday, February 9, 2012 3:00 PM - 4:30 PM EST Darlene.steward@nrel.gov (303) 275 3837 NREL/PR-5600-54276 NATIONAL RENEWABLE ENERGY LABORATORY Outline 2 Introduction - Sara Dillich Overview of the H2A Model H2A Version 3 Changes Case Study Walkthrough Resources 1 2 3 4 NATIONAL RENEWABLE ENERGY LABORATORY Outline 3 Introduction - Sara Dillich Overview of the H2A Model H2A Version 3 Changes Case Study

  4. STATISTICAL ANALYSIS OF INTERFEROMETRIC MEASUREMENTS OF AXIS RATIOS FOR CLASSICAL Be STARS

    SciTech Connect (OSTI)

    Cyr, R. P.; Jones, C. E.; Tycner, C.

    2015-01-20

    This work presents a novel method to estimate the effective opening angle of CBe star disks from projected axis ratio measurements, obtained by interferometry using a statistical approach. A Monte Carlo scheme was used to generate a large set of theoretical axis ratios from disk models using different distributions of disk densities and opening angles. These theoretical samples were then compared to observational samples, using a two-sample Kolmogorov-Smirnov test, to determine which theoretical distribution best reproduces the observations. The results suggest that the observed ratio distributions in the K, H, and N band can best be explained by the presence of thin disks, with opening half-angles of the order of 0.°15-4.°0. Results for measurements over the Hα line point toward slightly thicker disks, 3.°7-14°, which is consistent with a flaring disk predicted by the viscous disk model.

  5. Buildings Energy Data Book: 3.2 Commercial Sector Characteristics

    Buildings Energy Data Book [EERE]

    7 Commercial Building Median Lifetimes (Years) Building Type Median (1) 66% Survival (2) 33% Survival (2) Assembly 55 40 75 Education 62 45 86 Food Sales 55 41 74 Food Service 50 35 71 Health Care 55 42 73 Large Office 65 46 92 Mercantile & Service 50 36 69 Small Office 58 41 82 Warehouse 58 41 82 Lodging 53 38 74 Other 60 44 81 Note(s): Source(s): 1) PNNL estimates the median lifetime of commercial buildings is 70-75 years. 2) Number of years after which the building survives. For example,

  6. NERSC Users Group Meeting October 2-3, 2008 Presentations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Richard A. Gerber | Download File: gerber.pdf | pdf | 427 KB Accelerating X Windows with NX* October 2, 2008 | Author(s): Janet Jacbsen | Download File: NXDemo.pdf | pdf | 52 KB...

  7. One-pot solvothermal synthesis of a well-ordered layered sodium aluminoalcoholate complex: a useful precursor for the preparation of porous Al2O3 particles

    SciTech Connect (OSTI)

    Li, XS; Michaelis, VK; Ong, TC; Smith, SJ; McKay, I; Muller, P; Griffin, RG; Wang, EN

    2014-01-01

    One-pot solvothermal synthesis of a robust tetranuclear sodium hexakis(glycolato)tris(methanolato)aluminate complex Na-3[Al-4(OCH3)(3)(OCH2CH2O)(6)] via a modified yet rigorous base-catalyzed transesterification mechanism is presented here. Single crystal X-ray diffraction (SCXRD) studies indicate that this unique Al complex contains three pentacoordinate Al3+ ions, each bound to two bidentate ethylene glycolate chelators and one monodentate methanolate ligand. The remaining fourth Al3+ ion is octahedrally coordinated to one oxygen atom from each of the six surrounding glycolate chelators, effectively stitching the three pentacoordinate Al moieties together into a novel tetranuclear Al complex. This aluminate complex is periodically self-assembled into well-ordered layers normal to the [110] axis with the intra-/inter-layer bonding involving extensive ionic bonds from the three charge-counterbalancing Na+ cations rather than the more typical hydrogen bonding interactions as a result of fewer free hydroxyl groups present in its structure. It can also serve as a valuable precursor toward the facile synthesis of high-surface-area alumina powders using a very efficient rapid pyrolysis technique.

  8. Dual Axis Radiographic Hydrodynamic Test | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration Dual Axis Radiographic Hydrodynamic Test NNSA releases Stockpile Stewardship Program quarterly experiments summary WASHIGTON, DC. - The National Nuclear Security Administration today released its current quarterly summary of experiments conducted as part of its science-based Stockpile Stewardship Program. The experiments carried out within the program are used in combination with complex computational models

  9. Crystal structure of 1-methyl-3-([2,2-dimethyl-4,6-dioxo-1,3-dioxane-5-ylidene]methyl)urea

    SciTech Connect (OSTI)

    Habibi, A. Ghorbani, H. S.; Bruno, G.; Rudbari, H. A.; Valizadeh, Y.

    2013-12-15

    The crystal structure of 1-Methyl-3-([2,2-dimethyl-4,6-dioxo-1,3-dioxane-5-ylidene]methyl)urea (C{sub 9}H{sub 12}N{sub 2}O{sub 5}) has been determined by single crystal X-ray diffraction analysis. The crystals are monoclinic, a = 5.3179(2), b = 18.6394(6), c =10.8124(3) , ? = 100.015(2), Z = 4, sp. gr. P2{sub 1}/c, R = 0.0381 for 2537 reflections with I > 2?(I). Except for C(CH{sub 3}){sub 2} group, the molecule is planar. The structure is stabilized by inter- and intramolecular N-H...O hydrogen bonds and weak C-H...O interactions.

  10. 2,3-Dihydroxybenzoic acid amides of tetraazaalkanes and tetaaza cycloalkanes

    DOE Patents [OSTI]

    Weitl, F.L.; Raymond, K.N.

    1980-01-01

    This disclosure is directed to a compound of the formula given in the patent wherein X is hydrogen or a conventional electron-withdrawing group, particularly --SO[sub 3]H or a salt thereof; n is 2, 3, or 4; m is 2, 3, or 4; and p is 2 or 3. The present compounds are useful as specific sequestering agents for actinide (IV) ions. Also described is a method for the 2,3-dihydroxybenzamidation of azaalkanes. No Drawings

  11. 2,3-Dihydroxybenzoic acid amides of tetraazaalkanes and tetaaza cycloalkanes

    DOE Patents [OSTI]

    Weitl, Frederick L. [Martinez, CA; Raymond, Kenneth N. [Berkeley, CA

    1980-01-01

    A compound of the formula: ##STR1## wherein X is hydrogen or a conventional electron-withdrawing group, particularly --SO.sub.3 H or a salt thereof; n is 2, 3, or 4; m is 2, 3, or 4; and p is 2 or 3. The present compounds are useful as specific sequestering agents for actinide (IV) ions. Also described is a method for the 2,3-dihydroxybenzamidation of azaalkanes.

  12. Process for preparing 2,3-dihydroxybenzoic acid amides of tetraazaalkanes and cycloalkanes

    DOE Patents [OSTI]

    Weitl, Frederick L.; Raymond, Kenneth N.

    1985-01-01

    A compound of the formula: ##STR1## wherein X is hydrogen or a conventional electron-withdrawing group, particularly --SO.sub.3 H or a salt thereof; n is 2, 3, or 4; m is 2, 3, or 4; and p is 2 or 3. The present compounds are useful as specific sequestering agents for actinide (IV) ions. Also described is a method for the 2,3-dihydroxybenzamidation of azaalkanes.

  13. Band alignment and electrical properties of Al{sub 2}O{sub 3}/?-Ga{sub 2}O{sub 3} heterojunctions

    SciTech Connect (OSTI)

    Kamimura, Takafumi Hoi Wong, Man; Krishnamurthy, Daivasigamani; Higashiwaki, Masataka; Sasaki, Kohei; Kuramata, Akito; Yamakoshi, Shigenobu; Masui, Takekazu

    2014-05-12

    The band alignment of Al{sub 2}O{sub 3}/n-Ga{sub 2}O{sub 3} was investigated by x-ray photoelectron spectroscopy (XPS). With a band gap of 6.8??0.2?eV measured for Al{sub 2}O{sub 3}, the conduction and valence band offsets at the interface were estimated to be 1.5??0.2?eV and 0.7??0.2?eV, respectively. The conduction band offset was also obtained from tunneling current in Al{sub 2}O{sub 3}/n-Ga{sub 2}O{sub 3} (2{sup }01) metal-oxide-semiconductor (MOS) diodes using the Fowler-Nordheim model. The electrically extracted value was in good agreement with the XPS data. Furthermore, the MOS diodes exhibited small capacitance-voltage hysteresis loops, indicating the successful engineering of a high-quality Al{sub 2}O{sub 3}/Ga{sub 2}O{sub 3} interface.

  14. Nanoscale elastic changes in 2D Ti3C2Tx (MXene) pseudocapacitive electrodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Come, Jeremy; Xie, Yu; Naguib, Michael; Jesse, Stephen; Kalinin, Sergei V.; Gogotsi, Yury; Kent, Paul R. C.; Balke, Nina

    2016-02-01

    Designing sustainable electrodes for next generation energy storage devices relies on the understanding of their fundamental properties at the nanoscale, including the comprehension of ions insertion into the electrode and their interactions with the active material. One consequence of ion storage is the change in the electrode volume resulting in mechanical strain and stress that can strongly affect the cycle life. Therefore, it is important to understand the changes of dimensions and mechanical properties occurring during electrochemical reactions. While the characterization of mechanical properties via macroscopic measurements is well documented, in-situ characterization of their evolution has never been achieved atmore » the nanoscale. Two dimensional (2D) carbides, known as MXenes, are promising materials for supercapacitors and various kinds of batteries, and understating the coupling between their mechanical and electrochemical properties is therefore necessary. Here we report on in-situ imaging, combined with density functional theory of the elastic changes, of a 2D titanium carbide (Ti3C2Tx) electrode in direction normal to the basal plane during cation intercalation. The results show a strong correlation between the Li+ ions content and the elastic modulus, whereas little effects of K+ ions are observed. Moreover, this strategy enables identifying the preferential intercalation pathways within a single particle.« less

  15. Official Foreign Travel (3-2-12) (Informational Purposes Only)

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2012-03-12

    This draft directive is scheduled for review by the Directives Review Board on 3/15/12. Any questions, comments, or concerns with the proposed directive can be sent to your Directives Review Board representative (https://www.directives.doe.gov/references/directives-review-board-members) through your Directives Point of Contact (https://www.directives.doe.gov/development-review/dpc-corner/2010-10-1.pdf).

  16. Microsoft Word - Showerhead Guidance _3-4__final_ _2_.docx

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Showerhead Enforcement Guidance Issued: March 4, 2011 On February 3, 2011, the Department of Energy withdrew from OMB review, as unwarranted, the draft interpretative rule setting out the Department's views on the definition of a "showerhead" under the Energy Policy Conservation Act (EPCA) - and we formally withdraw that draft interpretive rule from consideration today. Nevertheless, to provide certainty to all stakeholders, the Department has decided to issue this brief enforcement

  17. October 2 & 3, 2013 Meeting of the Electricity Advisory Committee |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy October 2 & 3, 2013 Meeting of the Electricity Advisory Committee October 2 & 3, 2013 Meeting of the Electricity Advisory Committee Note: This meeting has been cancelled The Electricity Advisory Committee meeting scheduled to be held October 2 - October 3 was cancelled due to the uncertainty of continuing operations of the Federal government. Original Date: October 2 & 3, 2013 Meeting of the Electricity Advisory Committee Date: Wednesday, October 2, 2013

  18. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    0 2005 Energy End-Use Expenditures for an Average Household, by Region ($2010) Northeast Midwest South West National Space Heating 1,050 721 371 352 575 Air-Conditioning 199 175 456 262 311 Water Heating 373 294 313 318 320 Refrigerators 194 145 146 154 157 Other Appliances and Lighting 827 665 715 716 725 Total (1) 2,554 1,975 1,970 1,655 2,003 Note(s): 1) Due to rounding, end-uses do not sum to totals. Source(s): EIA, 2005 Residential Energy Consumption Survey, Oct. 2008, Table US-15; EIA,

  19. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    2 2005 Household Energy Expenditures, by Vintage ($2010) | Year | Prior to 1950 887 | 22% 1950 to 1969 771 | 22% 1970 to 1979 736 | 16% 1980 to 1989 741 | 16% 1990 to 1999 752 | 16% 2000 to 2005 777 | 9% | Average 780 | Total 100% Note(s): Source(s): 1.24 2,003 1) Energy expenditures per square foot were calculated using estimates of average heated floor space per household. According to the 2005 Residential Energy Consumption Survey (RECS), the average heated floor space per household in the

  20. Effect of neutron irradiation on defect evolution in Ti3SiC2 and Ti2AlC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tallman, Darin J.; He, Lingfeng; Garcia-Diaz, Brenda L.; Hoffman, Elizabeth N.; Kohse, Gordon; Sindelar, Robert L.; Barsoum, Michel W.

    2015-10-23

    Here, we report on the characterization of defects formed in polycrystalline Ti3SiC2 and Ti2AlC samples exposed to neutron irradiation – up to 0.1 displacements per atom (dpa) at 350 ± 40 °C or 695 ± 25 °C, and up to 0.4 dpa at 350 ± 40 °C. Black spots are observed in both Ti3SiC2 and Ti2AlC after irradiation to both 0.1 and 0.4 dpa at 350 °C. After irradiation to 0.1 dpa at 695 °C, small basal dislocation loops, with a Burgers vector of b = 1/2 [0001] are observed in both materials. At 9 ± 3 and 10 ±more » 5 nm, the loop diameters in the Ti3SiC2 and Ti2AlC samples, respectively, were comparable. At 1 × 1023 loops/m3, the dislocation loop density in Ti2AlC was ≈1.5 orders of magnitude greater than in Ti3SiC2, at 3 x 1021 loops/m3. After irradiation at 350 °C, extensive microcracking was observed in Ti2AlC, but not in Ti3SiC2. The room temperature electrical resistivities increased as a function of neutron dose for all samples tested, and appear to saturate in the case of Ti3SiC2. The MAX phases are unequivocally more neutron radiation tolerant than the impurity phases TiC and Al2O3. Based on these results, Ti3SiC2 appears to be a more promising MAX phase candidate for high temperature nuclear applications than Ti2AlC.« less

  1. Tracking formulas and strategies for a receiver oriented dual-axis tracking toroidal heliostat

    SciTech Connect (OSTI)

    Guo, Minghuan; Wang, Zhifeng; Liang, Wenfeng; Zhang, Xiliang; Zang, Chuncheng; Lu, Zhenwu; Wei, Xiudong

    2010-06-15

    A 4 m x 4 m toroidal heliostat with receiver oriented dual-axis tracking, also called spinning-elevation tracking, was developed as an auxiliary heat source for a hydrogen production system. A series of spinning-elevation tracking formulas have been derived for this heliostat. This included basic tracking formulas, a formula for the elevation angle for heliostat with a mirror-pivot offset, and a more general formula for the biased elevation angle. This paper presents the new tracking formulas in detail and analyzes the accuracy of applying a simplifying approximation. The numerical results show these receiver oriented dual-axis tracking formula approximations are accurate to within 2.5 x 10{sup -6} m in image plane. Some practical tracking strategies are discussed briefly. Solar images from the toroidal heliostat at selected times are also presented. (author)

  2. Vertical-axis wind turbines -- The current status of an old technology

    SciTech Connect (OSTI)

    Berg, D.E.

    1996-12-31

    Vertical-axis wind turbine technology is not well understood, even though the earliest wind machines rotated about a vertical axis. The operating environment of a vertical-axis wind turbine is quite complex, but detailed analysis capabilities have been developed and verified over the last 30 years. Although vertical-axis technology has not been widely commercialized, it exhibits both advantages and disadvantages compared to horizontal-axis technology, and in some applications, it appears to offer significant advantages.

  3. Dimethyl sulfide substituted mixed-metal clusters: Synthesis, structure, and characterization of HRuCo sub 3 (CO) sub 11 (SMe sub 2 ) and (HRuRh sub 3 (CO) sub 9 ) sub 2 (SMe sub 2 ) sub 3

    SciTech Connect (OSTI)

    Rossi, S.; Pursianinen, J.; Ahlgren, M.; Pakkanen, T.A. (Univ. of Joensuu (Finland))

    1990-02-01

    Ligand substitution reactions of dimethyl sulfide with mixed-metal clusters are described. The clusters HRuCo{sub 3}(CO){sub 11}(SMe{sub 2}) (1) and (HRuRh{sub 3}(CO){sub 9}){sub 2}(SMe{sub 2}){sub 3} (2) have been prepared by reactions of SMe{sub 2} with the neutral parent clusters. Their crystal structures have been established: 1, monoclinic, space group P2{sub 1}/n, a = 11.459 (5) {angstrom}, b = 12.484 (4) {angstrom}, c = 14.384 (4) {angstrom}, {beta} = 96.40 (3){degree}, Z = 4; 2, trigonal, space group R3c, a = 13.181 (7) {angstrom}, {alpha} = 75.54 (5){degree}, Z = 2. Dimethyl sulfide coordinates terminally as a two-electron donor on basal cobalt in 1 and as a bridging four-electron donor causing unusual dimerization of clusters in 2. The carbonyl arrangement of the parent clusters was not changed during the ligand substitution, and hydride ligands bridge the three basal metals in both compounds.

  4. Synthesis Of [2h, 13c]M [2h2m 13c], And [2h3,, 13c] Methyl Aryl Sulfones And Sulfoxides

    DOE Patents [OSTI]

    Martinez, Rodolfo A.; Alvarez, Marc A.; Silks, III, Louis A.; Unkefer, Clifford J.; Schmidt, Jurgen G.

    2004-07-20

    The present invention is directed to labeled compounds, [.sup.2 H.sub.1, .sup.13 C], [.sup.2 H.sub.2, .sup.13 C] and [.sup.2 H.sub.3, .sup.13 C]methyl aryl sulfones and [.sup.2 H.sub.1, .sup.13 C], [.sup.2 H.sub.2, .sup.13 C] and [.sup.2 H.sub.3, .sup.13 C]methyl aryl sulfoxides, wherein the .sup.13 C methyl group attached to the sulfur of the sulfone or sulfoxide includes exactly one, two or three deuterium atoms and the aryl group is selected from the group consisting of 1-naphthyl, substituted 1-naphthyl, 2-naphthyl, substituted 2-naphthyl, and phenyl groups with the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each independently, hydrogen, a C.sub.1 -C.sub.4 lower alkyl, a halogen, an amino group from the group consisting of NH.sub.2, NHR and NRR' where R and R' are each a C.sub.1 -C.sub.4 lower alkyl, a phenyl, or an alkoxy group. The present invention is also directed to processes of preparing methyl aryl sulfones and methyl aryl sulfoxides.

  5. Superconducting YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} thin films on polycrystalline ferrite for magnetically tunable microwave components

    SciTech Connect (OSTI)

    Jia, Q.X.; Findikoglu, A.T.; Arendt, P.; Foltyn, S.R.; Roper, J.M.; Groves, J.R.; Coulter, J.Y.; Li, Y.Q.; Dionne, G.F.

    1998-04-01

    Superconducting YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} (YBCO) thin films with a surface resistance of 0.86 m{Omega} at 10 GHz and 76 K have been grown on polycrystalline ferrite yttrium iron garnet (YIG) substrates. The chemical and structural mismatches between YBCO and YIG are solved by using a double buffer layer of biaxially oriented yttria-stabilized zirconia (YSZ) and CeO{sub 2}, where YSZ is deposited by an ion-beam-assisted-deposition technique. The YBCO films are {ital c} axis oriented with an in-plane mosaic spread [full width at half maximum of an x-ray {phi}-scan on (103) reflection] of less than 8{degree}. The films have a superconductive transition temperature above 88 K with a transition width less than 0.3 K, giving a critical current density above 10{sup 6}A/cm{sup 2} in self field at 75 K. At 75 K in an external magnetic field of 1 T perpendicular to the film surface, the films maintain a critical current density over 2{times}10{sup 5}A/cm{sup 2}. {copyright} {ital 1998 American Institute of Physics.}

  6. Built-In Potential in Fe 2 O 3 -Cr 2 O 3 Superlattices for Improved Photoexcited Carrier Separation

    SciTech Connect (OSTI)

    Kaspar, Tiffany C.; Schreiber, Daniel K.; Spurgeon, Steven R.; McBriarty, Martin E.; Carroll, Gerard M.; Gamelin, Daniel R.; Chambers, Scott A.

    2015-12-17

    We demonstrate that the different surface terminations exhibited by α-Fe2O3 (hematite) and α-Cr2O3 (eskolaite) in superlattices (SL) of these materials, synthesized with exquisite control by molecular beam epitaxy, determine the heterojunction interface structure and result in controllable, non-commutative band offset values. Precise atomic control of the interface structure allowed us to vary the valence band offset from 0.35 eV to 0.79 eV. This controllable band alignment can be harnessed to generate a built-in potential in Fe2O3-Cr2O3 SLs. For instance, in a 2.5-period SL, a built-in potential of 0.8 eV was realized as measured by x-ray photoelectron spectroscopy of Ti dopants as probe species. The high quality of the SL structure was confirmed by atom probe tomography and scanning transmission electron microscopy. Enhanced photocurrents were measured for a thick Fe2O3 epitaxial film capped with an (Fe2O3)3-(Cr2O3)3 SL; this enhancement was attributed to efficient electron-hole separation in the SL as a result of the band alignment. The Fe-O-Cr bonds at the SL interfaces also red-shifted the onset of photoconductivity to ~1.6 eV. Exploiting the band alignment and photoabsorption properties of Fe2O3-Cr2O3 SLs has the potential to increase the efficiency of hematite-based photoelectrochemical water splitting.

  7. " East North Central",13.3,13.5,14.3,15.2,16.7,19.1

    U.S. Energy Information Administration (EIA) Indexed Site

    Fuel Consumption, Selected Survey Years (Billion Gallons) " ,"Survey Years" ,1983,1985,1988,1991,1994,2001 "Total",80.3,83.9,82.4,82.8,90.6,113.1 "Household Characteristics"...

  8. In Vitro Metabolism and Stability of the Actinide Chelating Agent 3,4,3-LI(1,2-HOPO)

    SciTech Connect (OSTI)

    Choi, Taylor A.; Furimsky, Anna M.; Swezey, Robert; Bunin, Deborah I.; Byrge, Patricia; Iyer, Lalitha V.; Chang, Polly Y.; Abergel, Rebecca J.

    2015-02-27

    We report that the hydroxypyridinonate ligand 3,4,3-LI(1,2-HOPO) is currently under development for radionuclide chelation therapy. The preclinical characterization of this highly promising ligand comprised the evaluation of its in vitro properties, including microsomal, plasma, and gastrointestinal fluid stability, cytochrome P450 inhibition, plasma protein binding, and intestinal absorption using the Caco-2 cell line. When mixed with active human liver microsomes, no loss of parent compound was observed after 60 minutes, indicating compound stability in the presence of liver microsomal P450. At the tested concentrations, 3,4,3-LI(1,2-HOPO) did not significantly influence the activities of any of the cytochromal isoforms screened. Thus, 3,4,3-LI(1,2-HOPO) is unlikely to cause drug-drug interactions by inhibiting the metabolic clearance of co-administered drugs metabolized by these enzymes. Plasma protein binding assays revealed that the compound is protein-bound in dogs and less extensively in rats and humans. In the plasma stability study, the compound was stable after 1 h at 37°C in mouse, rat, dog, and human plasma samples. Finally, a bi-directional permeability assay demonstrated that 3,4,3-LI(1,2-HOPO) is not permeable across the Caco-2 monolayer, highlighting the need to further evaluate the effects of various compounds with known permeability enhancement properties on the permeability of the ligand in future studies.

  9. In Vitro Metabolism and Stability of the Actinide Chelating Agent 3,4,3-LI(1,2-HOPO)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Choi, Taylor A.; Furimsky, Anna M.; Swezey, Robert; Bunin, Deborah I.; Byrge, Patricia; Iyer, Lalitha V.; Chang, Polly Y.; Abergel, Rebecca J.

    2015-02-27

    We report that the hydroxypyridinonate ligand 3,4,3-LI(1,2-HOPO) is currently under development for radionuclide chelation therapy. The preclinical characterization of this highly promising ligand comprised the evaluation of its in vitro properties, including microsomal, plasma, and gastrointestinal fluid stability, cytochrome P450 inhibition, plasma protein binding, and intestinal absorption using the Caco-2 cell line. When mixed with active human liver microsomes, no loss of parent compound was observed after 60 minutes, indicating compound stability in the presence of liver microsomal P450. At the tested concentrations, 3,4,3-LI(1,2-HOPO) did not significantly influence the activities of any of the cytochromal isoforms screened. Thus, 3,4,3-LI(1,2-HOPO) ismore » unlikely to cause drug-drug interactions by inhibiting the metabolic clearance of co-administered drugs metabolized by these enzymes. Plasma protein binding assays revealed that the compound is protein-bound in dogs and less extensively in rats and humans. In the plasma stability study, the compound was stable after 1 h at 37°C in mouse, rat, dog, and human plasma samples. Finally, a bi-directional permeability assay demonstrated that 3,4,3-LI(1,2-HOPO) is not permeable across the Caco-2 monolayer, highlighting the need to further evaluate the effects of various compounds with known permeability enhancement properties on the permeability of the ligand in future studies.« less

  10. Test documentation for converting TWRS baseline data from RDD-100 V3.0.2.2 to V4.0.3. Revision 1

    SciTech Connect (OSTI)

    Gneiting, B.C.; Johnston, M.E.

    1996-05-03

    This document describes the test documentation required for converting between two versions of the RDD-100 software application, specifically version 3.0.2.2 and version 4.0.3. The area of focus in the successful conversion of the master data set between two versions of the database tool and their corresponding data structures.

  11. Buildings Energy Data Book: 3.2 Commercial Sector Characteristics

    Buildings Energy Data Book [EERE]

    5 Commercial Building Size, as of 2003 (Number of Buildings and Percent of Total Floorspace) Square Foot Range Number of Buildings (thousands) 1,001 to 5,000 10% 5,001 to 10,000 10% 10,001 to 25,000 18% 25,001 to 50,000 13% 50,001 to 100,000 14% 100,001 to 200,000 (1) 14% 200,001 to 500,000 10% Over 500,000 11% Total 100% Note(s): Source(s): 26 8 4,859 1) 35% of commercial floorspace is found in 2.2% of commercial buildings that are larger than 100,000 square feet. EIA, 2003 Commercial Buildings

  12. Magnetic Correlations in the Quasi-2D Semiconducting Ferromagnet CrSiTe3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Williams, Travis J.; Aczel, Adam A.; Lumsden, Mark D.; Nagler, Stephen E.; Stone, Matthew B.; Yan, Jiaqiang; Mandrus, D.

    2015-10-02

    Intrinsic, two-dimensional ferromagnetic semiconductors are an important class of materials for overcoming the limitations of dilute magnetic semiconductors for spintronics applications. CrSiTe3 is a particularly interesting member of this class, since it can likely be exfoliated down to single layers, where Tc is predicted to increase dramatically. Establishing the nature of the magnetism in the bulk is a necessary precursor to understanding the magnetic behavior in thin film samples and the possible applications of this material. In this work, we use elastic and inelastic neutron scattering to measure the magnetic properties of single crystalline CrSiTe3. We find that there ismorea very small single ion anisotropy favoring magnetic ordering along the c-axis and that the measured spin waves fit well to a model where the moments are only weakly coupled along that direction. Finally, we find that both static and dynamic correlations persist within the ab-plane up to at least 300 K, strong evidence of this material's two-dimensional characteristics that are relevant for future studies on thin film and monolayer samples.less

  13. Nuclear Regulatory legislation: 103d Congress. Volume 2, No. 3

    SciTech Connect (OSTI)

    1995-08-01

    This document is a compilation of nuclear regulatory legislation and other relevant material through the 103d Congress, 2d Session. This compilation has been prepared for use as a resource document, which the NRC intends to update at the end of every Congress. The contents of NUREG-0980 include the Atomic Energy Act of 1954, as amended; Energy Reorganization Act of 1974, as amended, Uranium Mill Tailings Radiation Control Act of 1978; Low-Level Radioactive Waste Policy Act; Nuclear Waste Policy Act of 1982; and NRC Authorization and Appropriations Acts. Other materials included are statutes and treaties on export licensing, nuclear non-proliferation, and environmental protection.

  14. Buildings Energy Data Book: 2.3 Residential Sector Expenditures

    Buildings Energy Data Book [EERE]

    1 2005 Energy Expenditures per Household, by Housing Type and Square Footage ($2010) Per Household Single-Family 1.16 Detached 1.16 Attached 1.20 Multi-Family 1.66 2 to 4 units 1.90 5 or more units 1.53 Mobile Home 1.76 All Homes 1.12 Note(s): Source(s): 1) Energy expenditures per square foot were calculated using estimates of average heated floor space per household. According to the 2005 Residential Energy Consumption Survey (RECS), the average heated floor space per household in the U.S. was

  15. The Equation of State of LLM-105 (2,6-diamino-3,5-dinitropyrazine...

    Office of Scientific and Technical Information (OSTI)

    The Equation of State of LLM-105 (2,6-diamino-3,5-dinitropyrazine-1-oxide) Citation Details In-Document Search Title: The Equation of State of LLM-105 (2,6-diamino-3,5-dinitropyraz...

  16. 2-D and 3-D Models of Convective Turbulence and Oscillations...

    Office of Scientific and Technical Information (OSTI)

    2-D and 3-D Models of Convective Turbulence and Oscillations in Intermediate-Mass Main-Sequence Stars Citation Details In-Document Search Title: 2-D and 3-D Models of Convective ...

  17. Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of...

    Office of Environmental Management (EM)

    Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A Lamps Operated in Steady-State Conditions Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A ...

  18. Resonant Level Enhancement of the Thermoelectric Power of Bi2Te3...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Resonant Level Enhancement of the Thermoelectric Power of Bi2Te3 with Tin Resonant Level Enhancement of the Thermoelectric Power of Bi2Te3 with Tin Application to practical p-type...

  19. Cu 2 S 3 complex on Cu(111) as a candidate for mass transport...

    Office of Scientific and Technical Information (OSTI)

    Cu 2 S 3 complex on Cu(111) as a candidate for mass transport enhancement Citation Details In-Document Search Title: Cu 2 S 3 complex on Cu(111) as a candidate for mass transport ...

  20. Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants 2004 Diesel Engine ...

  1. Broken Symmetry in the Pseudogap State of YBa2Cu3O6+x (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Broken Symmetry in the Pseudogap State of YBa2Cu3O6+x Citation Details In-Document Search Title: Broken Symmetry in the Pseudogap State of YBa2Cu3O6+x You are ...

  2. Conversion of 1,3-Propylene Glycol on Rutile TiO2(110) (Journal...

    Office of Scientific and Technical Information (OSTI)

    Conversion of 1,3-Propylene Glycol on Rutile TiO2(110) Citation Details In-Document Search Title: Conversion of 1,3-Propylene Glycol on Rutile TiO2(110) The adsorption of...

  3. Measurement and Modeling of the n=2-3 Emission of O VIII near...

    Office of Scientific and Technical Information (OSTI)

    Conference: Measurement and Modeling of the n2-3 Emission of O VIII near 102 Citation Details In-Document Search Title: Measurement and Modeling of the n2-3 Emission of O VIII ...

  4. Gearbox Reliability Collaborative Phase 3 Gearbox 2 Test Plan

    SciTech Connect (OSTI)

    Link, H.; Keller, J.; Guo, Y.; McNiff, B.

    2013-04-01

    Gearboxes in wind turbines have not been achieving their expected design life even though they commonly meet or exceed the design criteria specified in current design standards. One of the basic premises of the National Renewable Energy Laboratory (NREL) Gearbox Reliability Collaborative (GRC) is that the low gearbox reliability results from the absence of critical elements in the design process or insufficient design tools. Key goals of the GRC are to improve design approaches and analysis tools and to recommend practices and test methods resulting in improved design standards for wind turbine gearboxes that lower the cost of energy (COE) through improved reliability. The GRC uses a combined gearbox testing, modeling and analysis approach, along with a database of information from gearbox failures collected from overhauls and investigation of gearbox condition monitoring techniques to improve wind turbine operations and maintenance practices. Testing of Gearbox 2 (GB2) using the two-speed turbine controller that has been used in prior testing. This test series will investigate non-torque loads, high-speed shaft misalignment, and reproduction of field conditions in the dynamometer. This test series will also include vibration testing using an eddy-current brake on the gearbox's high speed shaft.

  5. Process for the preparation of protected 3-amino-1,2-dihydroxypropane acetal and derivatives thereof

    DOE Patents [OSTI]

    Hollingsworth, Rawle I.; Wang, Guijun

    2000-01-01

    A process for producing protected 3-amino-1,2-dihydroxypropane acetal, particularly in chiral forms, for use as an intermediate in the preparation of various 3-carbon compounds which are chiral. In particular, the present invention relates to the process for preparation of 3-amino-1,2-dihydroxypropane isopropylidene acetal. The protected 3-amino-1,2-dihydroxypropane acetal is a key intermediate to the preparation of chiral 3-carbon compounds which in turn are intermediates to various pharmaceuticals.

  6. Microsoft Word - Citrix_2FA_Authentication_12_3_2009.doc | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Citrix_2FA_Authentication_12_3_2009.doc Microsoft Word - Citrix_2FA_Authentication_12_3_2009.doc Microsoft Word - Citrix_2FA_Authentication_12_3_2009.doc (453.3 KB) More Documents & Publications Citrix_2FA_Authentication_09.09 Using Two-Factor RSA Token with WebVPN User guide for remote access to VDI and Workplace using RSA token

  7. Proceedings of the National Hydrogen Energy Roadmap Workshop: Washington, DC; April 2-3, 2002

    Office of Energy Efficiency and Renewable Energy (EERE)

    Summary of the Proceedings of the National Hydrogen Energy Roadmap Workshop held April 2-3, 2002 in Washington, DC.

  8. Agenda, October 2 & 3, 2013 Meeting of the Electricity Advisory Committee

    Broader source: Energy.gov [DOE]

    Agenda for the U.S. Department of Energy Electricity Advisory Committee Meeting scheduled for October 2 & 3, 2013.

  9. DETECTION OF NONPOLAR IONS IN {sup 2}{Pi}{sub 3/2} STATES BY RADIOASTRONOMY VIA MAGNETIC DIPOLE TRANSITIONS

    SciTech Connect (OSTI)

    Morse, Michael D.; Maier, John P. E-mail: j.p.maier@unibas.ch

    2011-05-10

    The possibility of magnetic dipole-induced pure rotational transitions in the interstellar medium is investi- gated for symmetric Hund's case (a) linear molecules, such as H-C{identical_to}C-H{sup +} (X-tilde {sup 2}{Pi}{sub 3/2u}), CO{sub 2} {sup +} (X-tilde {sup 2}{Pi}{sub 3/2g}), H-C{identical_to}C-C{identical_to}C-H{sup +} (X-tilde {sup 2}{Pi}{sub 3/2g}), and N{sub 3} (X-tilde {sup 2}{Pi}{sub 3/2g}). These species lack an electric dipole moment and therefore cannot undergo pure rotational electric dipole transitions. These species can undergo pure rotational transitions via the parallel component of the magnetic dipole operator, however. The transition moments and Einstein A coefficients for the allowed pure rotational transitions are derived for a general Hund's case (a) linear molecule, and tabulated for the examples of H-C{identical_to}C-H{sup +} ({sup 2}{Pi}{sub 3/2u}) and H-C{identical_to}C-C{identical_to}C-H{sup +} ({sup 2}{Pi}{sub 3/2g}). It is found that the rates of emission are comparable to collision rates in interstellar clouds, suggesting that this decay mechanism may be important in simulating rotational population distributions in diffuse clouds and for detecting these molecules by radioastronomy. Expected line positions for the magnetic dipole-allowed R{sub ef} (J) and R{sub fe} (J) transitions of H-C{identical_to}C-H{sup +} ({sup 2}{Pi}{sub 3/2u}), H-C{identical_to}C-C{identical_to}C-H{sup +} ({sup 2}{Pi}{sub 3/2g}), CO{sub 2}{sup +} ({sup 2}{Pi}{sub 3/2g}), and N{sub 3} ({sup 2}{Pi}{sub 3/2g}) are tabulated to assist in their observation by radioastronomy or in the laboratory.

  10. Gearbox Reliability Collaborative Phase 3 Gearbox 2 Test

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Keller, Jonathan; Robb, Wallen

    2016-05-12

    The National Renewable Energy Laboratory (NREL) Gearbox Reliability Collaborative (GRC) was established by the U.S. Department of Energy in 2006; its key goal is to understand the root causes of premature gearbox failures and improve their reliability. The GRC uses a combined gearbox testing, modeling, and analysis approach disseminating data and results to the industry and facilitating improvement of gearbox reliability. This test data describes the tests of GRC gearbox 2 in the National Wind Technology Center dynamometer and documents any modifications to the original test plan. It serves as a guide to interpret the publicly released data sets with brief analyses to illustrate the data. TDMS viewer and Solidworks software required to view data files.

  11. Photoluminescence Studies of Y2O3:Eu3+ Under High Pressure (Journal...

    Office of Scientific and Technical Information (OSTI)

    DOE Contract Number: DE-AC02-98CH10886 Resource Type: Journal Article Resource Relation: Journal Name: Journal of Applied Physics; Journal Volume: 115; Journal Issue: 2 Research ...

  12. High temperature redox reactions with uranium: Synthesis and characterization of Cs(UO{sub 2})Cl(SeO{sub 3}), Rb{sub 2}(UO{sub 2}){sub 3}O{sub 2}(SeO{sub 3}){sub 2}, and RbNa{sub 5}U{sub 2}(SO{sub 4}){sub 7}

    SciTech Connect (OSTI)

    Babo, Jean-Marie; Albrecht-Schmitt, Thomas E.

    2013-10-15

    Cs(UO{sub 2})Cl(SeO{sub 3}) (1), Rb{sub 2}(UO{sub 2}){sub 3}O{sub 2}(SeO{sub 3}){sub 3} (2), and RbNa{sub 5}U{sub 2}(SO{sub 4}){sub 7} (3) single crystals were synthesized using CsCl, RbCl, and a CuCl/NaCl eutectic mixture as fluxes, respectively. Their lattice parameters and space groups are as follows: P2{sub 1}/n (a=6.548(1) Å, b=11.052(2) Å, c=10.666(2) Å and β=93.897(3)°), P1{sup ¯} (a=7.051(2) Å, b=7.198(2) Å, c=8.314(2) Å, α=107.897(3)°, β=102.687(3)° and γ=100.564(3)°) and C2/c (a=17.862(4) Å, b=6.931(1) Å, c=20.133(4) Å and β=109.737(6)°. The small anionic building units found in these compounds are SeO{sub 3}{sup 2−} and SO{sub 4}{sup 2−} tetrahedra, oxide, and chloride. The crystal structure of the first compound is composed of [(UO{sub 2}){sub 2}Cl{sub 2}(SeO{sub 3}){sub 2}]{sup 2−} chains separated by Cs{sup +} cations. The structure of (2) is constructed from [(UO{sub 2}){sub 3}O{sub 11}]{sup 16−} chains further connected through selenite units into layers stacked perpendicularly to the [0 1 0] direction, with Rb{sup +} cations intercalating between them. The structure of compound (3) is made of uranyl sulfate layers formed by edge and vertex connections between dimeric [U{sub 2}O{sub 16}] and [SO{sub 4}] polyhedra. These layers contain unusual sulfate–metal connectivity as well as large voids. - Graphical abstract: A new family of uranyl selenites and sulfates has been prepared by high-temperature redox reactions. This compounds display new bonding motifs. Display Omitted - Highlights: • Low-dimensional Uranyl Oxoanion compounds. • Conversion of U(IV) to U(VI) at high temperatures. • Dimensional reduction by both halides and stereochemically active lone-pairs.

  13. Hydrothermal synthesis of Y{sub 2}O{sub 3} coated Y{sub 2}O{sub 3}:Eu{sup 3+} nanotubes for enhanced photoluminescence properties

    SciTech Connect (OSTI)

    Gao, Linhui; Wang, Guangfa; Zhu, Hongliang; Zhou, Weijie; Ou, Guofu

    2015-10-15

    Highlights: • Eu{sup 3+} doped Y{sub 2}O{sub 3} nanotubes. • Hydrothermal synthesis of Y{sub 2}O{sub 3} coated Y{sub 2}O{sub 3}:Eu{sup 3+} nanostructures assissted with a further heat treatment. • Tunable coating ratios of Y{sub 2}O{sub 3} coated Y{sub 2}O{sub 3}:Eu{sup 3+} nanophosphor. • Enhanced photoluminescence intensity of Y{sub 2}O{sub 3}:Eu{sup 3+} more than 60% by Y{sub 2}O{sub 3} surface coating. - Abstract: Novel Y{sub 2}O{sub 3} coated Y{sub 2}O{sub 3}:Eu{sup 3+} nanotubes with different coating ratios were synthesized successfully by a facile two-step process, including hydrothermal synthesis of Y(OH){sub 3} coated Y(OH){sub 3}:Eu{sup 3+} as precursors and then calcination of them at 1000 °C for 2 h. X-ray diffraction patterns and field emission scanning electron microscope images indicated these Y{sub 2}O{sub 3} coated Y{sub 2}O{sub 3}:Eu{sup 3+} phosphors possess tubular nanostructures. The photoluminescence properties of Y{sub 2}O{sub 3} coated Y{sub 2}O{sub 3}:Eu{sup 3+} were systematically investigated by photoluminescence spectra, and photoluminescence enhancement was observed after proper coating. In other words, the coating ratio played a crucial role in photoluminescence efficiency. When it was 1/9, the photoluminescence intensity of {sup 5}D{sub 0} → {sup 7}F{sub 2} emission (about 613 nm) was 60% higher than that of Y{sub 2}O{sub 3}: Eu{sup 3+} phosphors under 255 nm excitation. Therefore, surface coating may be an alternative route for enhanced photoluminescence properties of the Y{sub 2}O{sub 3}:Eu{sup 3+} red-emitting phosphor.

  14. Technical Standards, MACCS2, Gap Analysis - May 3, 2004 | Department of

    Office of Environmental Management (EM)

    Energy MACCS2, Gap Analysis - May 3, 2004 Technical Standards, MACCS2, Gap Analysis - May 3, 2004 May 3, 2004 Software Quality Assurance Improvement Plan: MACCS2 Gap Analysis The MACCS2 software, for radiological dispersion and consequence analysis, is one of the codes designated for the toolbox. To determine the actions needed to bring the MACCS2 code into compliance with the SQA qualification criteria, and develop an estimate of the resources required to perform the upgrade, the

  15. Process for manufacturing bis(2-methoxyethyl)-2,3,6,7-tetracyano-1,4,5,8,9,10-hexazaanthracene

    DOE Patents [OSTI]

    Rasmussen, Paul George; Lawton, Richard Graham

    2014-06-03

    A process to manufacture substituted tetracyano-hexaazatricyclics with the substitutions occurring at the 9 and 10 hydrogens. The process begins with 2,3-dichloro-5,6-dicyanopyrazine, which is reacted to form the desired tetracyano-hexaazatricyclic. Different process embodiments enable different reaction paths to the desired tetracyano-hexaazatricyclic. Different tetracyano-hexaazatricyclic embodiments include bis(2-methoxyethyl)-2,3,6,7-tetracyano-1,4,5,8,9,10-hexazaanthracene and bis(2-methoxyethoxyethyl)-2,3,6,7-tetracyano-1,4,5,8,9,10-hexazaanthracen- e.

  16. Synthesis of the Stereoisomeric Clusters 1,2-Os3(CO)10(trans-dpmn) and 1,2-Os3(CO)10(cis-dpmn) [where dpmn = 2,3-bis(diphenylphosphinomethyl)-5-norbornene]: DFT Evaluation of the Isomeric Clusters 1,2-Os3(CO)10(dpmn) and Isomer-Dependent Diphosphine Ligand Activation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Li; Nesterov, Vladimir N.; Wang, Xiaoping; Richmond, Michael G.

    2014-07-23

    The bicyclic diphosphines trans- and cis-2,3-bis(diphenylphosphinomethyl)-5-norbornene (dpmn) react with 1,2-Os3(CO)10(MeCN)2 (1) to furnish the corresponding ligand-bridged clusters Os3(CO)10(trans-dpmn) (2) and Os3(CO)10(cis-dpmn) (3). Both new products have been isolated and the molecular structures established by X-ray diffraction analyses. The dihydroxyl-bridged cluster 1,2-Os3(CO)8(μ-OH)2(cis-dpmn) (4), which accompanied the formation of 3 in one reaction, has been isolated and characterized by mass spectrometry and X-ray crystallography. Whereas cluster 2 is stable in toluene at 373 K, 3 is thermally sensitive under identical conditions and undergoes loss of CO (2 equiv), coupled with the activation of three norbornene C-H bonds and one P-C(phenyl) bond, tomore » furnish the dihydride cluster H2Os3(CO)8[μ3-2-PhPC-3-endo-Ph2PCH2(C7H7)] (5). The solid-state structure of 5 confirms the multiple activation of the cis-dpmn ligand and accompanying formation of the face-capping 2-PhPC-3-endo-Ph2PCH2(C7H7) moiety in the product. DFT calculations on 2 and 3 indicate that the former cluster is the thermodynamically more stable isomer, and the conversion of 3→ 5 + 2CO + benzene is computed to be exergonic by 12.7 kcal/mol and is entropically favored due to the release of the CO and benzene by-products.« less

  17. VERSATILE TWO-AXIS OPEN-LOOP SOLAR TRACKER CONTROLLER*

    SciTech Connect (OSTI)

    Ward, Christina D; Maxey, L Curt; Evans III, Boyd Mccutchen; Lapsa, Melissa Voss

    2008-01-01

    A versatile single-board controller for two-axis solar tracking applications has been developed and tested on operating solar tracking systems with over two years of field experience. The operating experience gained from the two systems and associated modifications are discussed as representative examples of the practical issues associated with implementing a new two-axis solar tracker design. In this research, open and closed loop control methods were evaluated; however, only the open loop method met the 0.125 tracking accuracy requirement and the requirement to maintain pointing accuracy in hazy and scattered cloudy skies. The open loop algorithm was finally implemented in a microcontroller-based tracking system. Methods of applying this controller hardware to different tracker geometries and hardware are discussed along with the experience gained to date.

  18. On the spin-axis dynamics of a Moonless Earth

    SciTech Connect (OSTI)

    Li, Gongjie; Batygin, Konstantin

    2014-07-20

    The variation of a planet's obliquity is influenced by the existence of satellites with a high mass ratio. For instance, Earth's obliquity is stabilized by the Moon and would undergo chaotic variations in the Moon's absence. In turn, such variations can lead to large-scale changes in the atmospheric circulation, rendering spin-axis dynamics a central issue for understanding climate. The relevant quantity for dynamically forced climate change is the rate of chaotic diffusion. Accordingly, here we re-examine the spin-axis evolution of a Moonless Earth within the context of a simplified perturbative framework. We present analytical estimates of the characteristic Lyapunov coefficient as well as the chaotic diffusion rate and demonstrate that even in absence of the Moon, the stochastic change in Earth's obliquity is sufficiently slow to not preclude long-term habitability. Our calculations are consistent with published numerical experiments and illustrate the putative system's underlying dynamical structure in a simple and intuitive manner.

  19. Structural and Mechanistic Analysis through Electronic Spectra: Aqueous Hyponitrite Radical (N2O2-) and Nitrosyl Hyponitrite Anion (N3O3-)

    SciTech Connect (OSTI)

    Valiev, Marat; Lymar, Sergei V.

    2011-11-03

    Aqueous hyponitrite radical (N{sub 2}O{sub 2}{sup -}) and nitrosyl hyponitrite anion (N{sub 3}O{sub 3}{sup -}) species are important intermediates in the reductive chemistry of NO. The structures and absorption spectra of various hydrated isomers of these compounds were investigated in this work using high-level quantum mechanical calculations combined with the explicit classical description of the aqueous environment. For N{sub 2}O{sub 2}{sup -}, comparison of the calculated spectra and energetics with the experimental data reveals that: (1) upon the one-electron oxidation of trans-hyponitrite (ON=NO{sub 2}{sup -}), the trans configuration of the resulting ON=NO{sup -} radical is preserved; (2) although cis- and trans-ON=NO{sup -} are energetically nearly equivalent, the barrier for the trans-cis isomerization is prohibitively high due to the partial double character of the NN bond; (3) the UV spectrum of ON=NO{sup -} was misinterpreted in the earlier pulse radiolysis work and its more recent revision has been justified. For the N{sub 3}O{sub 3}{sup -} ion, the symmetric isomer is the dominant observable species, and the asymmetric isomer contributes little to the experimental spectrum. Coherent analysis of the calculated and experimental data suggests a re-interpretation of the N{sub 2}O{sub 2}{sup -} + NO reaction mechanism, according to which the reaction evenly bifurcates to yield both the symmetric and asymmetric isomers of N{sub 3}O{sub 3}{sup -}. While the latter isomer rapidly decomposes to the final NO{sub 2}{sup -} + N{sub 2}O products, the former isomer is stable toward this decomposition but its formation is reversible with the homolysis equilibrium constant Khom = 2.2 - 10{sup -7} M. Collectively, these results demonstrate that advanced theoretical modeling can be of significant benefit in structural and mechanistic analysis of UV spectra.

  20. CDT 16.01 was set to default on Edison on 2/3/2016

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 was set to default on Edison on 2/3/2016 CDT 16.01 was set to default on Edison on 2/3/2016 February 3, 2016 by Zhengji Zhao The Cray Developer Toolkit (CDT) 16.01 was set to default on 2/3/2016. The following software versions are new default on Edison: craype/2.5.1 cray-ga/5.3.0.5 cray-hdf5/1.8.16 cray-hdf5-parallel/1.8.16 cray-mpich/7.3.1 cray-mpich-abi/7.3.1 cray-shmem/7.3.1 craypkg-gen/1.3.3 cce/8.4.3 The intel compiler default was not changed, it is still intel/15.0.1.133. A new version

  1. High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal-Organic Graphene Analogue

    SciTech Connect (OSTI)

    Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.; Er, Süleyman; Wade, Casey R.; Brozek, Carl K.; Aspuru-Guzik, Alán; Dinc,; #259; Mircea,

    2014-09-22

    Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni3(HITP)2 (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal–organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S·cm–1, respectively, both records for MOFs and among the best for any coordination polymer.

  2. X- And y-axis driver for rotating microspheres

    DOE Patents [OSTI]

    Weinstein, Berthold W.

    1979-01-01

    Apparatus for precise control of the motion and position of microspheres for examination of their interior and/or exterior. The apparatus includes an x- and y-axis driver mechanism controlled, for example, by a minicomputer for selectively rotating microspheres retained between a pair of manipulator arms having flat, smooth end surfaces. The driver mechanism includes an apertured plate and ball arrangement which provided for coupled equal and opposite movement of the manipulator arms in two perpendicular directions.

  3. Bertram Brockhouse, the Triple-axis Spectrometer, and Neutron Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bertram Brockhouse, the Triple-axis Spectrometer, and Neutron Spectroscopy Resources with Additional Information Bertram Brockhouse Courtesy of McMaster University Bertram Brockhouse 'attended the University of British Columbia, from which he graduated in 1947 with first class honours in mathematics and physics. He entered the University of Toronto that same year ... . He obtained his Ph.D. in 1950, with a thesis entitled "The Effect of Stress and Temperature upon the Magnetic Properties of

  4. Lu{sub 2}O{sub 3}:Eu{sup 3+} glass ceramic films: Synthesis, structural and spectroscopic studies

    SciTech Connect (OSTI)

    Carrera Jota, M.L.; Garca Murillo, A.; Morales Ramrez, A. de J.; Rosa Cruz, E. de la; Kassiba, Abdelhadi

    2014-03-01

    Graphical abstract: - Highlights: Lu{sub 2}O{sub 3}:Eu{sup 3+}@SiO{sub 2} films were synthesized by solgel and by dip-coating technique. Effects of incorporating PVP on structural properties were studied. Effects of incorporating silica (SiO{sub 2}) luminescence characteristics were analyzed. X-ray diffraction results showed that Lu{sub 2}O{sub 3}:Eu{sup 3+}@SiO{sub 2} crystallizes at 700 C. The 611 nm emission for the Lu:Si = 8:1 system presented an improvement. - Abstract: For the first time, transparent and crack free europium-doped lutetia silica solgel films were synthesized using the dip-coating technique on silica quartz substrates. In this study, we examined the effects of incorporating polyvinylpyrrolidone (PVP) and silica (SiO{sub 2}) into different precursor solutions for different LuSi molar ratios: 4:1, 6:1, 8:1 and 10:1. Different systems, such as Lu{sub 2}O{sub 3}:Eu{sup 3+}@SiO{sub 2} (using the above Lu:Si molar ratios), were synthesized by solgel and by dip-coating technique, employing acetylacetonate lutetium and tetraethylorthosilicate as Lu and Si precursors, in order to produce Lu{sub 2}O{sub 3}:Eu{sup 3+} (5 mol%)@SiO{sub 2} glassceramic films. The film microstructure was studied by microRaman spectroscopy (MRS) and X-ray diffraction (XRD) for different Lu:Si molar ratios on films annealed at 700 C. X-ray diffraction results showed that the lutetium oxide cubic phase crystallizes in the silica matrix at 700 C, and the crystallite size of Lu{sub 2}O{sub 3}:Eu{sup 3+}@SiO{sub 2} films varies from 5 nm to 17 nm according to the respective Lu:Si molar ratios. Opto-geometrical parameters determined by m-lines spectroscopy using a 632.5 nm HeNe laser showed that the Eu{sup 3+} doped films heat-treated at 700 C presented a thickness and density of 1.7 ?m (8.8 g cm{sup ?3}), 970 nm (9.2 g cm{sup ?3}), 1 ?m (9.3 g cm{sup ?3}) and 1.3 ?m (9.25 g cm{sup ?3}) for the Lu:Si = 4:1, 6:1, 8:1 and 10:1 molar ratio systems, respectively

  5. Influence of structural distortions upon photoluminescence properties of Eu{sup 3+} and Tb{sup 3+} activated Na{sub 3}Ln(BO{sub 3}){sub 2} (Ln=Y, Gd) borates

    SciTech Connect (OSTI)

    Asiri Naidu, S.; Boudin, S.; Varadaraju, U.V.; Raveau, B.

    2012-06-15

    The comparative study of the structure and photoluminescence (PL) properties of the Eu{sup 3+} and Tb{sup 3+} activated Na{sub 3}Ln(BO{sub 3}){sub 2}, with Ln=Y, Gd, showed the important role of the host lattice structure upon PL. Higher emission intensities of Eu{sup 3+} and Tb{sup 3+} are observed for Na{sub 3}Gd(BO{sub 3}){sub 2} than for Na{sub 3}Y(BO{sub 3}){sub 2}, through direct Eu{sup 3+} excitation at 395 nm for Eu{sup 3+} doped borates, and through Gd{sup 3+} excitation around 280 nm for Tb{sup 3+} doped borates. This higher performance for Na{sub 3}Gd(BO{sub 3}){sub 2} is due to the less regular environment of Eu{sup 3+} (Tb{sup 3+}) in the Gd sites than in the Y sites and to energy transfer from Gd{sup 3+} to Eu{sup 3+}(Tb{sup 3+}). The smaller critical concentration in Na{sub 3}Ln{sub 1-x}Tb{sub x}(BO{sub 3}){sub 2} observed for Ln=Gd, x=0.5, compared to x=0.6 for Ln=Y, is explained by shorter Ln-Ln distances (4.11 A for Gd-Gd vs. 4.59 A for Y-Y). Both Na{sub 3}Y{sub 0.4}Tb{sub 0.6}(BO{sub 3}){sub 2} and Na{sub 3}Gd{sub 0.5}Tb{sub 0.5}(BO{sub 3}){sub 2} show intense green emission under UV excitation. - Graphical abstract: The PL properties of Eu{sup 3+} and Tb{sup 3+} are studied in Na{sub 3}Ln(BO{sub 3}){sub 2} (Ln=Y, Gd) borates. Eu{sup 3+} and Tb{sup 3+}exhibits higher emission intensity in Na{sub 3}Gd(BO{sub 3}){sub 2} compared to Na{sub 3}Y(BO{sub 3}){sub 2} due to the less regular environment of the Gd{sup 3+} ion. Energy transfer from Gd{sup 3+} to Tb{sup 3+} is observed. Highlights: Black-Right-Pointing-Pointer Crystal structure of Na{sub 3}Gd(BO{sub 3}){sub 2} by X-ray powder diffraction. Black-Right-Pointing-Pointer Photoluminescence properties of Eu{sup 3+} and Tb{sup 3+} doped Na{sub 3}Ln(BO{sub 3}){sub 2} (Ln=Y, Gd). Black-Right-Pointing-Pointer Higher Eu{sup 3+} and Tb{sup 3+} emission for Na{sub 3}Gd(BO{sub 3}){sub 2} due to an irregular environment of Gd{sup 3+}. Black-Right-Pointing-Pointer Higher Eu{sup 3+} and Tb{sup 3+} emission

  6. Flow augmenters for vertical-axis windmills and turbines

    SciTech Connect (OSTI)

    Evans, F.C.

    1981-03-10

    A windmill is disclosed, the windmill including a vertical shaft mounted for rotation about its longitudinal axis, a number of blades spaced circumferentially around the longitudinal axis, and being disposed generally parallel to the axis of rotation of the vertical shaft, and supporting arms extending radially outwardly from the vertical shaft for supporting the blades. The windmill also includes a first member connected to an upper end of one of the blades and defining a first surface having a leading edge with respect to the direction of movement of the blade and a trailing edge rearward of the leading edge, the leading edge being lower than the trailing edge. The first surface also includes an inside lateral edge and an outer lateral edge spaced radially outwardly from the inside lateral edge, the inside lateral edge being higher than the outer lateral edge. A second member is connected to the lower end of the blade and defines a second surface, the second surface having a leading edge with respect to the direction of movement of the blade and a trailing surface rearward of the second surface leading edge, the second surface leading edge being higher than the trailing edge. The second surface also includes an inside lateral edge and an outer lateral edge spaced radially outwardly from the second surface inside lateral edge, the second surface inside lateral edge being lower than the second surface outside lateral edge.

  7. Sr{sub 9}Ni{sub 6.64}O{sub 21}: A new member (n = 2) of the perovskite-related A{sub 3n+3}A{sub n}{prime}B{sub 3+n}O{sub 9+6n} family

    SciTech Connect (OSTI)

    Campa, J.; Gutierrez-Puebla, E.; Monge, A.

    1996-10-01

    Crystals of a new phase Sr{sub 9}Ni{sub 6.64}O{sub 21} were grown. This compound in the n = 2 member of the A{sub 3n+3}A{sub n}{prime}B{sub n+3}O{sub 6n+9} series. The composition and the crystal structure have been established form X-ray single crystal diffraction data. The structure contains face-shared chains of NiO{sub 6} polyhedra parallel to the c axis and is related with hexagonal 2H polytype perovskite. Sr{sub 9}Ni{sub 6.64}O{sub 21} crystallizes in the space group R3c (No. 167) with a = 9.467(2) {angstrom}, c = 35.87(5) {angstrom}, V = 2784.(4) {angstrom}{sup 3}, and Z = 6. A comparison is made between the structure of the title compound and the other members of the series.

  8. Stabilization of the high coercivity {epsilon}-Fe{sub 2}O{sub 3} phase in the CeO{sub 2}-Fe{sub 2}O{sub 3}/SiO{sub 2} nanocomposites

    SciTech Connect (OSTI)

    Mantlikova, A.; Poltierova Vejpravova, J.; Bittova, B.; Burianova, S.; Niznansky, D.; Ardu, A.; Cannas, C.

    2012-07-15

    We have investigated the processes leading to the formation of the Fe{sub 2}O{sub 3} and CeO{sub 2} nanoparticles in the SiO{sub 2} matrix in order to stabilize the {epsilon}-Fe{sub 2}O{sub 3} as the major phase. The samples with two different concentrations of the Fe were prepared by sol-gel method, subsequently annealed at different temperatures up to 1100 Degree-Sign C, and characterized by the Moessbauer spectroscopy, Transmission Electron Microscopy (TEM), Powder X-ray Diffraction (PXRD), Energy Dispersive X-ray analysis (EDX) and magnetic measurements. The evolution of the different Fe{sub 2}O{sub 3} phases under various conditions of preparation was investigated, starting with the preferential appearance of the {gamma}-Fe{sub 2}O{sub 3} phase for the sample with low Fe concentration and low annealing temperature and stabilization of the major {epsilon}-Fe{sub 2}O{sub 3} phase for high Fe concentration and high annealing temperature, coexisting with the most stable {alpha}-Fe{sub 2}O{sub 3} phase. A continuous increase of the particle size of the CeO{sub 2} nanocrystals with increasing annealing temperature was also observed. - Graphical abstract: The graphical abstract displays the most important results of our work. The significant change of the phase composition due to the variation of preparation conditions is demonstrated. As a result, significant change of the magnetic properties from superparamagnetic {gamma}-Fe{sub 2}O{sub 3} phase with negligible coercivity to the high coercivity {epsilon}-Fe{sub 2}O{sub 3} phase has been observed. Highlights: Black-Right-Pointing-Pointer Research of the stabilization of the high coercivity {epsilon}-Fe{sub 2}O{sub 3} in CeO{sub 2}-Fe{sub 2}O{sub 3}/SiO{sub 2}. Black-Right-Pointing-Pointer Samples with two different concentrations of Fe and three annealing temperatures. Black-Right-Pointing-Pointer Phase transition {gamma}{yields}{epsilon}{yields}({beta}){yields}{alpha} with increasing annealing temperature and

  9. Nuclear and magnetic supercells in the multiferroic candidate: Pb3TeMn3P2O14

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Silverstein, Harlyn J.; Zhao, Haidong; Wiebe, Christopher; Huq, Ashfia

    2015-01-01

    The dugganites, Te6+-containing members of the langasite series, have attracted recent interest due to their complex low-temperature magnetic unit cells, magnetodielectric, and potentially multiferroic properties. For Pb2+-containing dugganites, a large monoclinic supercell was reported and was found to have a profound effect on the low temperature magnetism and spin excitation spectra. Pb3TeMn3P2O14 is another dugganite previously shown to distort away from the canonical P321 langasite unit cell, although this supercell was never fully solved. Here we report the full crystal and magnetic structure solution of Pb3TeMn3P2O14 using synchrotron x-ray and neutron diffraction data: a large trigonal supercell is observed inmore » this material, which is believed to be the first supercell of its kind in the langasite family. Here, the magnetic structure, high-magnetic field behavior, and dielectric properties of Pb3TeMn3P2O14 are presented. In addition to showing weak magnetoelectric behavior similar to other langasites, it was found that a phase transition occurs at 3 T near the antiferromagnetic transition temperature. (C) 2014 Elsevier Inc. All rights reserved.« less

  10. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12∶Ce (GGAG∶Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore »diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  11. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12∶Ce (GGAG∶Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore » diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  12. Ferromagnetism of Fe3Sn and alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sales, Brian C.; Saparov, Bayrammurad; McGuire, Michael A.; Singh, David J.; Parker, David S.

    2014-11-12

    Hexagonal Fe3Sn has many of the desirable properties for a new permanent magnet phase with a Curie temperature of 725 K, a saturation moment of 1.18 MA/m. and anisotropy energy, K1 of 1.8 MJ/m3. However, contrary to earlier experimental reports, we found both experimentally and theoretically that the easy magnetic axis lies in the hexagonal plane, which is undesirable for a permanent magnet material. One possibility for changing the easy axis direction is through alloying. We used first principles calculations to investigate the effect of elemental substitutions. The calculations showed that substitution on the Sn site has the potential tomore » switch the easy axis direction. Transition metal substitutions with Co or Mn do not have this effect. We attempted synthesis of a number of these alloys and found results in accord with the theoretical predictions for those that were formed. However, the alloys that could be readily made all showed an in-plane easy axis. The electronic structure of Fe3Sn is reported, as are some are magnetic and structural properties for the Fe3Sn2, and Fe5Sn3 compounds, which could be prepared as mm-sized single crystals.« less

  13. Electrical properties of In{sub 2}Se{sub 3} single crystals and photosensitivity of Al/In{sub 2}Se{sub 3} Schottky barriers

    SciTech Connect (OSTI)

    Bodnar, I. V.; Ilchuk, G. A.; Petrus', R. Yu.; Rud', V. Yu.; Rud', Yu. V.; Serginov, M.

    2009-09-15

    In{sub 2}Se{sub 3} single crystals {approx}40 mm long and 14 mm in diameter were grown by the Bridgman method. The composition of grown single crystals and their crystal structure were determined. The conductivity ({sigma}) and Hall constant (R) of grown single crystals were measured and the first Schottky barriers Al/n-In{sub 2}Se{sub 3} were fabricated. Rectification and photovoltaic effect were detected in the new structures. Based on the study of the photosensitivity spectra of Al/n-In{sub 2}Se{sub 3} structures, the nature of the interband transitions and band gap of In{sub 2}Se{sub 3} crystals were determined. It was concluded that the new structures can be applied to develop broadband photoconverters of optical radiation.

  14. Fe2O3–TiO2 core–shell nanorod arrays for visible light photocatalytic applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yao, Kun; Basnet, Pradip; Sessions, Henry; Larsen, George K.; Murph, Simona E. Hunyadi; Zhao, Yiping

    2015-11-11

    By using the glancing angle deposition technique and post-deposition annealing, Fe2O3–TiO2 core-shell nanorod arrays with specific crystalline states can be designed and fabricated. The Fe2O3–TiO2 core-shell samples annealed at temperatures greater than 450°C formed α-Fe2O3 and anatase TiO2, and showed higher catalytic efficiency for the degradation of methylene blue (MB) under visible light illumination when compared with pure anatase TiO2 or α-Fe2O3 nanorod arrays. Solar conversion of carbon dioxide and water vapor in the presence of Fe2O3–TiO2 core-shell nanorod arrays was also investigated. Carbon monoxide, hydrogen, methane, and methanol along with other hydrocarbons were produced after only several hours’ exposuremore » under ambient sunlight. It was determined that the core-shell structure showed greater efficiency for solar CO2 conversion than the pure TiO2 nanorod arrays.« less

  15. Kinetics and Mechanism of the Hydrogenation of CpCr(CO)3/[CpCr(CO)3]2 Equilibrium to CpCr(CO)3H

    SciTech Connect (OSTI)

    Norton, Jack R.; Spataru, Tudor; Camaioni, Donald M.; Lee, Suh-Jane; Li, Gang; Choi, Jongwook; Franz, James A.

    2014-05-26

    The kinetics of the hydrogenation of 2 CpCr(CO)3/[CpCr(CO)3]2 to CpCr(CO)3H has been investigated. The reaction is second-order in Cr and first-order in H2, with a rate constant of 45 M 2s 1 at 25 C in benzene. DFT calculations rule out an H2 complex as an intermediate, and suggest (a) end-on approach of H2 to one Cr of [CpCr(CO)3]2 as the Cr-Cr bond undergoes heterolytic cleavage, (b) heterolytic cleavage of the coordinated H2 between O and Cr, and (c) isomerization of the resulting O-protonated CpCr(CO)2(COH) to CpCr(CO)3H. The work at Pacific Northwest National Laboratory (PNNL) was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences; Battelle operates PNNL for DOE.

  16. DOE Announces Nearly $3.2 Million to Help Consumers Better Manage Their

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Consumption | Department of Energy Nearly $3.2 Million to Help Consumers Better Manage Their Energy Consumption DOE Announces Nearly $3.2 Million to Help Consumers Better Manage Their Energy Consumption May 22, 2012 - 2:12pm Addthis Smart Grid Data Access Awards Will Demonstrate How Consumers and Communities Can Benefit from Better Energy Information The Department of Energy announced phase I awards totaling nearly $3.2 million that will encourage utilities, local governments, and

  17. Traf2 interacts with Smad4 and regulates BMP signaling pathway in MC3T3-E1 osteoblasts

    SciTech Connect (OSTI)

    Shimada, Koichi; Ikeda, Kyoko; Ito, Koichi

    2009-12-18

    Bone morphogenetic proteins (BMPs) play important roles in osteoblast differentiation and maturation. In mammals, the BMP-induced receptor-regulated Smads form complexes with Smad4. These complexes translocate and accumulate in the nucleus, where they regulate the transcription of various target genes. However, the function of Smad4 remains unclear. We performed a yeast two-hybrid screen using Smad4 as bait and a cDNA library derived from bone marrow, to indentify the proteins interacting with Smad4. cDNA clones for Tumor necrosis factor (TNF) receptor-associated factor 2 (Traf2) were identified, and the interaction between the endogenous proteins was confirmed in the mouse osteoblast cell line MC3T3-E1. To investigate the function of Traf2, we silenced it with siRNA. The level of BMP-2 protein in the medium, the expression levels of the Bmp2 gene and BMP-induced transcription factor genes, including Runx2, Dlx5, Msx2, and Sp7, and the phosphorylated-Smad1 protein level were increased in cells transfected with Traf2 siRNA. The nuclear accumulation of Smad1 increased with TNF-{alpha} stimulation for 30 min at Traf2 silencing. These results suggest that the TNF-{alpha}-stimulated nuclear accumulation of Smad1 may be dependent on Traf2. Thus, the interaction between Traf2 and Smad4 may play a role in the cross-talk between TNF-{alpha} and BMP signaling pathways.

  18. The Aqueous Ca2+ System, in Comparison with Zn2+, Fe3+, and Al3+: An Ab Initio Molecular Dynamics Study

    SciTech Connect (OSTI)

    Bogatko, Stuart A.; Cauet, Emilie L.; Bylaska, Eric J.; Schenter, Gregory K.; Fulton, John L.; Weare, John H.

    2013-02-21

    Results of Ab Initio Molecular Dynamics (AIMD) simulations of a Ca2+ ion in an aqueous environment (64 waters, 38ps=5ps equilibration + 33ps data collection, 300K) are reported. The 1st hydration shell contains 6-7 waters with d(OH) = 0.97Å (identical to our bulk water estimate) and average tilt angle, I = 32º. The 1st maximum in the radial distribution function occurs at GCaO(r) = 2.45Å. Our results compare well with published experimental structural data from X-Ray Absorption (XAFS) and Neutron Diffraction. We also generate simulated XAFS spectra using a 1st principles MD-XAFS procedure and show quantitative agreement with experimental XAFS data from a 0.2m Ca(ClO4)2 aqueous solution. The Ca2+ 1st shell water dipole moment of 3.1D is identical to our bulk water estimate (3.1D). The structured 2nd hydration shell, composed of ~16.5 waters, has a maximum at GCaO(r) =4.6Å. The average 2nd shell dipole moment = 2.9D, is suppressed relative to bulk water values. Detailed H-bond analysis demonstrates the waters in this shell predominately coordinate 1st shell waters with a trigonally structured H-bond network. Two exchanges between the 1st hydration shell and the bulk were observed. These were consistent with a dissociative and dissociative interchange Eigen-Wilkins ligand exchange mechanism. Many transfers between the 2nd shell and bulk are detected for Ca2+ allowing an estimation of the 2nd shell mean residence time (MRT) of 4.6ps. Comparison of the Ca2+ hydration shell structure and dynamics with those of the recently reported Zn2+, Fe3+ and Al3+ cation species show that the 1st and 2nd hydration shell parameters, d(M-OI) distance, CNII, H-bond d(OI-OII) distance and %Tetrahedral structure are correlated with cation charge density, the ratio of cation charge (Z) and size (Rion). However, important exceptions are d(M-OII) and the 2nd shell Mean Residence Time (MRT). These differences are explained in terms of the 1st shell structure parameters (d(M-OI) distance

  19. A Fundamental Study on the [(μ-Cl)3Mg2(THF)6]+ Dimer Electrolytes for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rechargeable Mg Batteries - Joint Center for Energy Storage Research 5, Research Highlights A Fundamental Study on the [(μ-Cl)3Mg2(THF)6]+ Dimer Electrolytes for Rechargeable Mg Batteries (a) Proposed formation of the Mg-dimer and its equilibrium with Mg-monomers (b) The M/Z isotopic distribution of the [MgCl(THF)3]+ peak in the positive mode of SPIN MS of [(µ-Cl)3Mg2(THF)6]AlPh3Cl. Inset gives the calculated isotopic pattern (c) 25Mg NMR spectra of [(µ-Cl)3Mg2(THF)6]AlPh3Cl in the

  20. IDIQ BS Ex A (Rev. 3.2, 6/14/13) Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2, 6/14/13) Exhibit A General Conditions Page 1 of 19 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) ......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ....... 3 GC-3 INDEPENDENT CONTRACTOR (Jun 2009) ............................................................................ 4 GC-4 SUBCONTRACT INTERPRETATION (Jun

  1. 2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 1 1 1 1 1 1 1 1 1 1 1 1 2 2 Points labeled are part of next coarser grid Points labeled 1 are part of next coarser grid 7 by 7 grid of unknowns 3 by 3 grid of unknowns 1 by 1 grid of unknowns P : 9 by 9 grid of points P : 5 by 5 grid of points P : 3 by 3 grid of points (2) (1) (3) 2 2 2 2 2 FEAP FEAP FEAP FEAP FEAP FEAP FEAP FEAP FEAP Prometheus ParMetis METIS METIS METIS METIS METIS METIS METIS METIS Prometheus . . . . PETSc FEAP input file METIS 50 100 150

  2. Critical Updates to the Hydrogen Analysis Production Model (H2A v3) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Critical Updates to the Hydrogen Analysis Production Model (H2A v3) Critical Updates to the Hydrogen Analysis Production Model (H2A v3) Presentation slides from the February 8, 2012, Fuel Cell Technologies Program webinar, "Critical Updates to the Hydrogen Analysis Production Model (H2A v3)." Critical Updates to the Hydrogen Analysis Production Model (H2A v3) Webinar Slides (1.24 MB) More Documents & Publications H2A Delivery Models and Results Hydrogen

  3. White light generation from Dy{sup 3+}-doped ZnO-B{sub 2}O{sub 3}-P{sub 2}O{sub 5} glasses

    SciTech Connect (OSTI)

    Jayasimhadri, M.; Jang, Kiwan; Lee, Ho Sueb; Chen, Baojiu; Yi, Soung-Soo; Jeong, Jung-Hyun

    2009-07-01

    Dysprosium doped ZnO-B{sub 2}O{sub 3}-P{sub 2}O{sub 5} (ZBP) glasses were prepared by a conventional melt quenching technique in order to study the luminescent properties and their utility for white light emitting diodes (LEDs). X-ray diffraction spectra revealed the amorphous nature of the glass sample. The present glasses were characterized by infrared and Raman spectra to evaluate the vibrational features of the samples. The emission and excitation spectra were reported for the ZBP glasses. Strong blue (484 nm) and yellow (574 nm) emission bands were observed upon various excitations. These two emissions correspond to the {sup 4}F{sub 9/2}->{sup 6}H{sub 15/2} and {sup 4}F{sub 9/2}->{sup 6}H{sub 13/2} transitions of Dy{sup 3+} ions, respectively. Combination of these blue and yellow bands gives white light to the naked eye. First time, it was found that ZnO-B{sub 2}O{sub 3}-P{sub 2}O{sub 5} glasses efficiently emit white light under 400 and 454 nm excitations, which are nearly match with the emissions of commercial GaN blue LEDs and InGaN LED, respectively. CIE chromaticity coordinates also calculated for Dy{sup 3+}: ZBP glasses to evaluate the white light emission.

  4. Structural phase transitions in Bi2Se3 under high pressure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Zhenhai; Gu, Genda; Wang, Lin; Hu, Qingyang; Zhao, Jinggeng; Yan, Shuai; Yang, Ke; Sinogeikin, Stanislav; Mao, Ho -kwang

    2015-11-02

    Raman spectroscopy and angle dispersive X-ray diffraction (XRD) experiments of bismuth selenide (Bi2Se3) have been carried out to pressures of 35.6 and 81.2 GPa, respectively, to explore its pressure-induced phase transformation. The experiments indicate that a progressive structural evolution occurs from an ambient rhombohedra phase (Space group (SG): R-3m) to monoclinic phase (SG: C2/m) and eventually to a high pressure body-centered tetragonal phase (SG: I4/mmm). Evidenced by our XRD data up to 81.2 GPa, the Bi2Se3 crystallizes into body-centered tetragonal structures rather than the recently reported disordered body-centered cubic (BCC) phase. Furthermore, first principles theoretical calculations favor the viewpoint thatmore » the I4/mmm phase Bi2Se3 can be stabilized under high pressure (>30 GPa). Remarkably, the Raman spectra of Bi2Se3 from this work (two independent runs) are still Raman active up to ~35 GPa. Furthermore, it is worthy to note that the disordered BCC phase at 27.8 GPa is not observed here. The remarkable difference in atomic radii of Bi and Se in Bi2Se3 may explain why Bi2Se3 shows different structural behavior than isocompounds Bi2Te3 and Sb2Te3.« less

  5. Vapor-liquid equilibrium of the Mg(NO/sub 3/)/sub 2/-HNO/sub 3/-H/sub 2/O system

    SciTech Connect (OSTI)

    Thompson, B.E.; Derby, J.J.; Stalzer, E.H.

    1983-06-01

    The vapor-liquid equilibrium of the Mg(NO/sub 3/)/sub 2/-HNO/sub 3/-H/sub 2/O system in concentrations of 0 to 70 wt % Mg(NO/sub 3/)/sub 2/ and 0 to 75 wt % HNO/sub 3/ at atmospheric pressure was correlated by two approaches. One was based on a dissociation equilibrium expression in which the activities of the reacting species (HNO/sub 3/, NO/sub 3//sup -/, and H/sup +/) were approximated with mole fractions. The activity coefficients of the undissociated HNO/sub 3/ and H/sub 2/O were correlated as functions of the concentrations of magnesium nitrate and nitric acid by second-order polynomials. The average absolute difference between predicted and experimental values was 8% for the mole fraction of acid in the vapor and 8/sup 0/K for the bubble-point temperature. The second approach was to correlate the mean ionic rational activity coefficient of water with a form of the excess Gibbs energy composed of two terms. One term, a function of the ionic strength, accounts for the coulombic (ionic) interactions; the other term accounts for the non-coulombic (molecular) interactions. The average absolute difference between predicted and experimental values was 9% for the mole fraction of acid in the vapor, and 10/sup 0/K for the bubble-point temperature.

  6. Ordered binary oxide films of V{sub 2}O{sub 3}(0001) on Al{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Guo, Q.; Kim, D.Y.; Street, S.C.; Goodman, D.W.

    1999-07-01

    Ordered binary oxide films of vanadium oxide have been prepared on an aluminum oxide film supported on Mo(110) under ultrahigh vacuum conditions and characterized by various surface analytical techniques. Auger electron spectroscopy, low energy electron diffraction, high-resolution electron loss spectroscopy, x-ray photoelectron spectroscopy and ion scattering spectroscopy indicate that the vanadia films grow epitaxially on the Al{sub 2}O{sub 3}/Mo(110) surface as V{sub 2}O{sub 3}(0001). The results of electronic structural measurements show an increase in the energy of the a{sub 1g} level in the 3{ital d} band at low temperatures, which is a possible explanation for the metal-to-insulator transition in V{sub 2}O{sub 3}. {copyright} {ital 1999 American Vacuum Society.}

  7. Photoluminescence studies of shock-recovered Y{sub 2}O{sub 3}:Eu{sup 3+}

    SciTech Connect (OSTI)

    Kishimura, Hiroaki Hamada, Sho; Aruga, Atsushi; Matsumoto, Hitoshi

    2015-01-05

    A series of shock-recovery experiments on Y{sub 2}O{sub 3}:Eu{sup 3+} powder were conducted involving the impact of a flyer plate accelerated by a single-stage powder-propellant gun. The recovered samples were characterized by X-ray diffraction (XRD) analysis and photoluminescence (PL) spectroscopy. The XRD and PL results of samples shocked at pressures of 13 GPa indicated that a phase transition from a cubic phase to a monoclinic phase occurred. The recovered samples shocked at 21 and 25 GPa consisted of Y{sub 2}O{sub 3}:Eu{sup 3+} with the cubic phase and the monoclinic phase. These results indicated that the shock-induced phase transition was the partial completion of the phase transition.

  8. Dual-Axis Resonance Testing of Wind Turbine Blades - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Return to Search Dual-Axis Resonance Testing of Wind Turbine Blades National Renewable ... of time needed to fatigue test wind turbine blades.
    Dual-axis testing can ...

  9. Sandia Vertical-Axis Wind-Turbine Research Presented at Science...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vertical-Axis Wind-Turbine Research Presented at Science of Making Torque from Wind ... Twitter Google + Vimeo GovDelivery SlideShare Sandia Vertical-Axis Wind-Turbine Research ...

  10. Sandia and Partners Complete Phase I of a Vertical-Axis Deep...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    I of a Vertical-Axis Deep-Water Offshore Turbine Study - Sandia Energy Energy Search Icon ... Sandia and Partners Complete Phase I of a Vertical-Axis Deep-Water Offshore Turbine Study ...

  11. Secreted Frizzled-related protein-2 (sFRP2) augments canonical Wnt3a-induced signaling

    SciTech Connect (OSTI)

    Marschall, Zofia von; Fisher, Larry W.

    2010-09-24

    Research highlights: {yields} sFRP2 enhances the Wnt3a-induced {beta}-catenin stabilization and its nuclear translocation. {yields} sFRP2 enhances LRP6 phosphorylation and Wnt3a/{beta}-catenin transcriptional reporter activity. {yields} Dickkopf-1 (DKK1) fully antagonizes both Wnt3a/sFRP2-induced LRP6 phosphorylation and transcriptional activity. {yields} sFRP2 enhances expression of genes known to be regulated by Wnt3a signaling. -- Abstract: Secreted Frizzled-related proteins (sFRP) are involved in embryonic development as well as pathological conditions including bone and myocardial disorders and cancer. Because of their sequence homology with the Wnt-binding domain of Frizzled, they have generally been considered antagonists of canonical Wnt signaling. However, additional activities of various sFRPs including both synergism and mimicry of Wnt signaling as well as functions other than modulation of Wnt signaling have been reported. Using human embryonic kidney cells (HEK293A), we found that sFRP2 enhanced Wnt3a-dependent phosphorylation of LRP6 as well as both cytosolic {beta}-catenin levels and its nuclear translocation. While addition of recombinant sFRP2 had no activity by itself, Top/Fop luciferase reporter assays showed a dose-dependent increase of Wnt3a-mediated transcriptional activity. sFRP2 enhancement of Wnt3a signaling was abolished by treatment with the Wnt antagonist, Dickkopf-1 (DKK1). Wnt-signaling pathway qPCR arrays showed that sFRP2 enhanced the Wnt3a-mediated transcriptional up-regulation of several genes regulated by Wnt3a including its antagonists, DKK1, and Naked cuticle-1 homolog (NKD1). These results support sFRP2's role as an enhancer of Wnt/{beta}-catenin signaling, a result with biological impact for both normal development and diverse pathologies such as tumorigenesis.

  12. Pressure-enhanced superconductivity in Eu 3 Bi 2 S 4 F 4 (Journal...

    Office of Scientific and Technical Information (OSTI)

    Title: Pressure-enhanced superconductivity in Eu 3 Bi 2 S 4 F 4 The pressure effect on the newly discovered charge-transferred BiS2-based superconductor, Eu3Bi2S4F4, with a Tc of ...

  13. Appendix D.2 Hanford Site-Wide SSHAC Level 3 PSHA Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Appendix D.2 Hanford Site-Wide SSHAC Level 3 PSHA Project April 24, 2014 Hazard Input Document (HID) Final GMC Model Contents Appendix D.2 Hanford Site-Wide SSHAC Level 3 PSHA Project ..................................................... 1 Overview ...................................................................................................................................... 2 Median Motions from Crustal Earthquakes

  14. "Table HC1.2.3 Living Space Characteristics by Average Floorspace...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...357,2492,2103,1096,"Q","Q","Q" "3,000 or 3,499",6.7,6.6,3014,2175,1438,3047,2079,1108,"N","N","N" "3,500 to 3,999",5.2,5.1,3549,2505,1518,"Q","Q","Q","N","N","N" "4,000 or ...

  15. Synthesis, characterization, and crystal structure of 2-amino-7-methyl-5-oxo-4-phenyl-4,5-dihydropyrano[3,2-c] pyran-3-carbonitrile

    SciTech Connect (OSTI)

    Sharma, S.; Banerjee, B.; Brahmachari, G.; Kant, Rajni; Gupta, V. K.

    2015-12-15

    2-Amino-7-methyl-5-oxo-4-phenyl-4,5-dihydropyrano[3,2-c] pyran-3-carbonitrile, C{sub 16}H{sub 12}N{sub 2}O{sub 3} is synthesized via one-pot multi-component reaction at room temperature using commercially available urea as inexpensive and environmentally benign organo-catalyst. Its structure is determined by single-crystal X-ray diffraction technique The crystals are monoclinic, a = 10.7357(12), b = 8.7774(8), c = 15.0759(16) Å, β = 103.575(11)°, Z = 4, sp. gr. P2{sub 1}/n, R = 0.0551 for 1696 observed reflections. The crystal structure is stabilized by N–H···N, C–H···O, and C–H···π interactions.

  16. L3:VUQ.VVDA.P2-2.03 William Rider SNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 William Rider SNL Completed: 3/28/11 CASL-U-2011-0060-000 1 SAND2010-234P Unlimited Release December 2010 Verification, Validation and Uncertainty Quantification Workflow in CASL William J. Rider Computational Shock and MultiPhysics Department James R. Kamm and V. Gregory Weirs Optimization and Uncertainty Quantification Department Sandia National Laboratories P.O. Box 5800 Albuquerque, New Mexico 87185 Dan G. Cacui Department of Nuclear Engineering North Carolina State University Raleigh, NC

  17. H2L3: Hydrogen Learning for Local Leaders | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    L3: Hydrogen Learning for Local Leaders H2L3: Hydrogen Learning for Local Leaders 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ...

  18. Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system...

    Office of Scientific and Technical Information (OSTI)

    Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system Title: Ti3CrCu4: A possible ... Country of Publication: United States Language: English Word Cloud More Like This Free ...

  19. Aqueous phase hydrodeoxygenation of polyols over Pd/WO3-ZrO2...

    Office of Scientific and Technical Information (OSTI)

    Aqueous phase hydrodeoxygenation of polyols over PdWO3-ZrO2: Role of Pd-WO3 interaction and hydrodeoxygenation pathway Citation Details In-Document Search This content will become ...

  20. Synthesis and crystal structure of α,β-unsaturated ketone: 3,3′-[1,2-ethanediylbis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one

    SciTech Connect (OSTI)

    Wang, G.-F. Gong, Q.-J. Sun, H.; Yao, C-Z.

    2013-12-15

    The title compound, C{sub 30}H{sub 24}N{sub 2}O{sub 4}, 3,3′-[1,2-ethanediyl-bis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one] was synthesized and characterized by elemental analysis, FT-IR spectra, {sup 1}H NMR, and X-ray single-crystal diffraction. In the molecule, the pyridine plane and the adjacent phenyl plane are almost coplanar with the dihedral angle of 3.07°, while the dihedral angle between the mean planes of the two asymmetric units is 67.56°. The crystal packing is stabilized by weak intermolecular C-H...N and C-H...O hydrogen bonds, C-H...π and π...π stacking interactions.

  1. A s o f 1 2 / 3 1 / 2 0 1 5

    Wind Powering America (EERE)

    2 0 1 5 Y e a r E n d Wi n d P o w e r C a p a c i t y ( MW)

  2. Search for Stripes in Antiferromagnetic Lightly Hole-Doped YBa2Cu3O6: An Electron Spin Resonance and Infrared Tranmission Study

    SciTech Connect (OSTI)

    Janossy,A.; Nagy, K.; Feher, T.; Mihaly, L.; Erb, A.

    2007-01-01

    We present a series of electron spin resonance (ESR) and infrared transmission experiments in antiferromagnetic (AF), lightly hole-doped YBa{sub 2}Cu{sub 3}O{sub 6} in search for the effect of a spatially inhomogeneous ground state on the magnetic and electric properties. Crystal compositions were Ca{sub x}Gd{sub y}Y{sub 1-x-y}Ba{sub 2}Cu{sub 3}O{sub 6} with x=0 , 0.008, 0.02, and 0.03 and y{approx}0.01 . Gd{sup 3+} ESR satellites from sites with first-neighbor Ca atoms show that holes are not preferentially localized at low temperatures in the vicinity of Ca dopants. We mapped by multifrequency Gd{sup 3+} ESR the AF domain structure as a function of hole concentration, temperature, and magnetic fields up to 8T . We attribute the hole-doping-induced rotation of the magnetic easy axis from collateral to diagonal (with respect to the tetragonal CuO{sub 2} lattice) to the pinning of the AF magnetization to a static modulation or a phase-separated network of the hole density. The dominantly fourfold symmetry of pinning suggests that the hole density network has this symmetry also and is not an array of stripes. At higher temperatures the pinning to the diagonal direction becomes weak and the possibility of domain wall fluctuations is discussed. There is no magnetic field dependence and no in-plane anisotropy of the infrared transmission polarized in the CuO{sub 2} planes in an x=0.02 crystal placed in magnetic fields up to 12T . Thus, the network of holes is rigid and is not affected by magnetic fields that are, however, strong enough to rotate the AF magnetization into a single domain.

  3. Dual Axis Radiographic Hydrodynamic Test Facility | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration | (NNSA) Dual Axis Radiographic Hydrodynamic Test Facility An integral part of the national hydrotest program, the DARHT is the world's most powerful x-ray machine. DARHT consists of two electron accelerators oriented at right angles to one another. Each accelerator creates a powerful electron beam that is focused onto a metal target which converts the kinetic energy of the electron beam into high energy x or gamma-rays. The x-ray dose from one DARHT accelerator is

  4. Torque ripple in a Darrieus, vertical axis wind turbine

    SciTech Connect (OSTI)

    Reuter, R.C. Jr.

    1980-09-01

    Interaction between a steady wind and a rotating, Darrieus, vertical axis wind turbine produces time periodic aerodynamic loads which cause time dependent torque variations, referred to as torque ripple, to occur in the mechanical link between the turbine and the electrical generator. There is concern for the effect of torque ripple upon fatigue life of drive train components and upon power quality. An analytical solution characterizing the phenomenon of torque ripple has been obtained which is based upon a Fourier expansion of the time dependent features of the problem. Numerical results for torque ripple, some experimental data, determination of acceptable levels and methods of controlling it, are presented and discussed.

  5. CRC DEPLETION CALCULATIONS FOR THE NON-RODDED ASSEMBLIES IN BATCHES 1, 2, AND 3 OF CRYSTAL RIVER UNIT 3

    SciTech Connect (OSTI)

    Kenneth D. Wright

    1997-07-29

    The purpose of this design analysis is to document the SAS2H depletion calculations of certain non-rodded fuel assemblies from batches 1, 2, and 3 of the Crystal River Unit 3 pressurized water reactor (PWR) that are required for Commercial Reactor Critical (CRC) evaluations to support development of the disposal criticality methodology. A non-rodded assembly is one which never contains a control rod assembly (CRA) or an axial power shaping rod assembly (APSRA) during its irradiation history. The objective of this analysis is to provide SAS2H generated isotopic compositions for each fuel assembly's depleted fuel and depleted burnable poison materials. These SAS2H generated isotopic compositions are acceptable for use in CRC benchmark reactivity calculations containing the various fuel assemblies.

  6. Structural and Mechanistic Analysis through Electronic Spectra: Aqueous Hyponitrite Radical (N(2)O(2)(-)) and Nitrosyl Hyponitrite Anion (N(3)O(3)(-))

    SciTech Connect (OSTI)

    Lymar S. V.; Valiev M.

    2011-11-03

    Aqueous hyponitrite radical (N{sub 2}O{sub 2}{sup -}) and nitrosyl hyponitrite anion (N{sub 3}O{sub 3}{sup -}) are important intermediates in the reductive chemistry of NO. The structures and absorption spectra of various hydrated isomers of these compounds were investigated in this work using high-level quantum mechanical calculations combined with the explicit classical description of the aqueous environment. For N{sub 2}O{sub 2}{sup -}, comparison of the calculated spectra and energetics with the experimental data reveals that (1) upon the one-electron oxidation of trans-hyponitrite (ON{double_bond}NO{sup 2-}), the trans configuration of the resulting ON{double_bond}NO{sup -} radical is preserved; (2) although cis- and trans-ON{double_bond}NO{sup -} are energetically nearly equivalent, the barrier for the trans-cis isomerization is prohibitively high because of the partial double character of the NN bond; (3) the calculations confirm that the UV spectrum of ONNO{sup -} was misinterpreted in the earlier pulse radiolysis work, and its more recent revision has been justified. For the N{sub 3}O{sub 3}{sup -} ion, the symmetric isomer the dominant observable species, and the asymmetric isomer contributes insignificantly to the experimental spectrum. Coherent analysis of the calculated and experimental data suggests a reinterpretation of the N{sub 2}O{sub 2}{sup -} + NO reaction mechanism according to which the reaction evenly bifurcates to yield both the symmetric and asymmetric isomers of N{sub 3}O{sub 3}{sup -}. While the latter isomer rapidly decomposes to the final NO{sub 2}{sup -} + N{sub 2}O products, the former isomer is stable toward this decomposition, but its formation is reversible with the homolysis equilibrium constant K{sub hom} = 2.2 x 10{sup -7} M. Collectively, these results demonstrate that advanced theoretical modeling can be of significant benefit in structural and mechanistic analysis on the basis of the electronic spectra of aqueous transients.

  7. Obama Administration Announces $3.2 Billion in Funding for Local Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency Improvements | Department of Energy 3.2 Billion in Funding for Local Energy Efficiency Improvements Obama Administration Announces $3.2 Billion in Funding for Local Energy Efficiency Improvements March 26, 2009 - 12:00am Addthis WASHINGTON - Vice President Joe Biden and Energy Secretary Steven Chu today announced plans to invest $3.2 billion in energy efficiency and conservation projects in U.S. cities, counties, states, territories, and Native American tribes. The Energy

  8. Whitestone Power & Communications (TRL 1 2 3 System) - Whitestone Poncelet

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RISEC Project | Department of Energy Whitestone Power & Communications (TRL 1 2 3 System) - Whitestone Poncelet RISEC Project Whitestone Power & Communications (TRL 1 2 3 System) - Whitestone Poncelet RISEC Project Whitestone Power & Communications (TRL 1 2 3 System) - Whitestone Poncelet RISEC Project 32_ponc_wpc_selvaggio.ppt (632.5 KB) More Documents & Publications Vortex Hydro Energy (TRL 5 6 System) - Advanced Integration of Power Take-Off in VIVACE Water Power Program

  9. New determination of the {sup 2}H(d,p){sup 3}H and {sup 2}H(d,n){sup 3}He reaction rates at astrophysical energies

    SciTech Connect (OSTI)

    Tumino, A.; Spart, R.; Spitaleri, C.; Pizzone, R. G.; La Cognata, M.; Rapisarda, G. G.; Romano, S.; Sergi, M. L.; Mukhamedzhanov, A. M.; Typel, S.; Tognelli, E.; Degl'Innocenti, S.; Prada Moroni, P. G.; Burjan, V.; Kroha, V.; Hons, Z.; Mrazek, J.; Piskor, S.; Lamia, L.

    2014-04-20

    The cross sections of the {sup 2}H(d,p){sup 3}H and {sup 2}H(d,n){sup 3}He reactions have been measured via the Trojan Horse method applied to the quasi-free {sup 2}H({sup 3}He,p {sup 3}H){sup 1}H and {sup 2}H({sup 3}He,n {sup 3}He){sup 1}H processes at 18 MeV off the proton in {sup 3}He. For the first time, the bare nucleus S(E) factors have been determined from 1.5 MeV, across the relevant region for standard Big Bang nucleosynthesis, down to the thermal energies of deuterium burning in the pre-main-sequence (PMS) phase of stellar evolution, as well as of future fusion reactors. Both the energy dependence and the absolute value of the S(E) factors deviate by more than 15% from the available direct data and existing fitting curves, with substantial variations in the electron screening by more than 50%. As a consequence, the reaction rates for astrophysics experience relevant changes, with a maximum increase of up to 20% at the temperatures of the PMS phase. From a recent primordial abundance sensitivity study, it turns out that the {sup 2}H(d,n){sup 3}He reaction is quite influential on {sup 7}Li, and the present change in the reaction rate leads to a decrease in its abundance by up to 10%. The present reaction rates have also been included in an updated version of the FRANEC evolutionary code to analyze their influence on the central deuterium abundance in PMS stars with different masses. The largest variation of about 10%-15% pertains to young stars (?1 Myr) with masses ?1 M {sub ?}.

  10. Synthesis, characterization, photocatalytic activity and ethanol-sensing properties of In{sub 2}O{sub 3} and Eu{sup 3+}:In{sub 2}O{sub 3} nanoparticles

    SciTech Connect (OSTI)

    Anand, Kanica; Thangaraj, R.; Kumar, Praveen; Kaur, Jasmeet; Singh, R. C.

    2015-05-15

    In the present endeavor, Indium oxide (In{sub 2}O{sub 3}) and Europium doped In{sub 2}O{sub 3} (In{sub 2}O{sub 3}:0.5%Eu{sup 3+} and In{sub 2}O{sub 3}:5%Eu{sup 3+}) nanoparticles were prepared by co-precipitation method. Synthesized nanoparticles were characterized using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and UV-Visible spectrophotometry (UV-vis). XRD revealed that nanoparticles were of pure bixbyite-type cubic phase and the crystallite size decreased with the Eu{sup 3+} doping. SEM micrographs showed that particles were spherical in shape. Synthesized nanoparticles were used for photo degradation of methylene blue (MB) dye under sunlight and the results clearly showed that In{sub 2}O{sub 3}:5%Eu{sup 3+} nanoparticles exhibited higher activity than pure In{sub 2}O{sub 3} nanoparticles. For gas sensing characteristics, the nanoparticles were applied as thick film onto alumina substrate and tested at different operating temperatures. The results showed that the optimum operating temperature of the gas sensors prepared from synthesized nanoparticles is 300°C. The investigations revealed that the addition of Eu{sup 3+} as a dopant enhanced the sensing response of In{sub 2}O{sub 3} nanoparticles appreciably.

  11. Morphology and Composition cycle of BaO/Al2O3 NSR Catalysts during NO2

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Uptake and Release: A multi spectroscopy and microscopy study | Department of Energy Morphology and Composition cycle of BaO/Al2O3 NSR Catalysts during NO2 Uptake and Release: A multi spectroscopy and microscopy study Morphology and Composition cycle of BaO/Al2O3 NSR Catalysts during NO2 Uptake and Release: A multi spectroscopy and microscopy study 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_kim.pdf (868.73 KB) More Documents &

  12. Organic Molecule Functionalized Zn3P2 Nanowire Inorganic-Organic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Organic Molecule Functionalized Zn3P2 Nanowire Inorganic-Organic Hybrid Thermoelectrics Demonstrates self-catalytic schemes for large-scale synthesis of compound semiconductor ...

  13. Novel high pressure monoclinic Fe[subscript 2]O[subscript 3]...

    Office of Scientific and Technical Information (OSTI)

    Novel high pressure monoclinic Fesubscript 2Osubscript 3 polymorph revealed by single-crystal synchrotron X-ray diffraction studies Citation Details In-Document Search Title: ...

  14. Cell type-specific roles of Jak3 in IL-2-induced proliferative signal transduction

    SciTech Connect (OSTI)

    Fujii, Hodaka . E-mail: hodaka@med.nyu.edu

    2007-03-16

    Binding of interleukin-2 (IL-2) to its specific receptor induces activation of two members of Jak family protein tyrosine kinases, Jak1 and Jak3. An IL-2 receptor (IL-2R)-reconstituted NIH 3T3 fibroblast cell line proliferates in response to IL-2 only when hematopoietic lineage-specific Jak3 is ectopically expressed. However, the mechanism of Jak3-dependent proliferation in the fibroblast cell line is not known. Here, I showed that Jak3 expression is dispensable for IL-2-induced activation of Jak1 and Stat proteins and expression of nuclear proto-oncogenes in the IL-2R-reconstituted fibroblast cell line. Jak3 expression markedly enhanced these IL-2-induced signaling events. In contrast, Jak3 expression was essential for induction of cyclin genes involved in the G1-S transition. These data suggest a critical role of Jak3 in IL-2 signaling in the fibroblast cell line and may provide further insight into the cell type-specific mechanism of cytokine signaling.

  15. Potential thermoelectric performance from optimization of hole-doped Bi2Se3

    SciTech Connect (OSTI)

    Parker, David S; Singh, David J

    2011-01-01

    We present an analysis of the potential thermoelectric performance of hole-doped Bi2Se3, which is commonly considered to show inferior room temperature performance when compared to Bi2Te3. We find that if the lattice thermal conductivity can be reduced by nanostructuring techniques (as have been applied to Bi2Te3) the material may show optimized ZT values of unity or more in the 300 - 500 K temperature range and thus be suitable for cooling and moderate temperature waste heat recovery and thermoelectric solar cell applications. Central to this conclusion are the larger band gap and the relatively heavier valence bands of Bi2Se3.

  16. Morphology and Composition cycle of BaO/Al2O3 NSR Catalysts during...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    spectroscopy and microscopy study Morphology and Composition cycle of BaOAl2O3 NSR Catalysts during NO2 Uptake and Release: A multi spectroscopy and microscopy study 2005 Diesel ...

  17. Pressure-enhanced superconductivity in Eu 3 Bi 2 S 4 F 4 (Journal...

    Office of Scientific and Technical Information (OSTI)

    The pressure effect on the newly discovered charge-transferred BiS2-based superconductor, Eu3Bi2S4F4, with a Tc of 1.5 K at ambient pressure, is investigated by transport and ...

  18. WORKSHOP: HIGH VALUE ROLL TO ROLL MANUFACTURING INNOVATION, DECEMBER 2-3

    Broader source: Energy.gov [DOE]

    The Advanced Manufacturing Office (AMO) is planning to host a workshop at the Westin Alexandria on 2-3 December, 2015. This 2-day workshop will focus on the on the advanced manufacturing technology...

  19. Highly-Selective and Reversible O2 Binding inCr3(1,3,5-benzenetricarb...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soc., 2010, 132 (23), pp 7856-7857 DOI: 10.1021ja1027925 Abstract Image Abstract: Reaction of Cr(CO)6 with trimesic acid in DMF affords the metal-organic framework Cr3(BTC)2*nDMF ...

  20. Luminescence enhancement by energy transfer in melamine-Y{sub 2}O{sub 3}:Tb{sup 3+} nanohybrids

    SciTech Connect (OSTI)

    Stagi, Luigi Chiriu, Daniele; Carbonaro, Carlo M.; Ricci, Pier Carlo; Ardu, Andrea; Cannas, Carla

    2015-09-28

    The phenomenon of luminescence enhancement was studied in melamine-Y{sub 2}O{sub 3}:Tb hybrids. Terbium doped Y{sub 2}O{sub 3} mesoporous nanowires were synthesized by hydrothermal method. X-ray diffraction patterns and Raman scattering spectra testified the realization of a cubic crystal phase. Organic-inorganic melamine-Y{sub 2}O{sub 3}:Tb{sup 3+} hybrid system was successfully obtained by vapour deposition method. Vibration Raman active modes of the organic counterpart were investigated in order to verify the achievement of hybrid system. Photoluminescence excitation and photoluminescence spectra, preformed in the region between 250 and 350 nm, suggest a strong interaction among melamine and Terbium ions. In particular, a remarkable improvement of {sup 5}D{sub 4}→ F{sub J} Rare Earth emission (at about 542 nm) of about 10{sup 2} fold was observed and attributed to an efficient organic-Tb energy transfer. The energy transfer mechanism was studied by the use of time resolved photoluminescence measurements. The melamine lifetime undergoes to a significant decrease when adsorbed to oxide surfaces and it was connected to a sensitization mechanism. The detailed analysis of time decay profile of Terbium radiative recombination shows a variation of double exponential law toward a single exponential one. Its correlation with surface defects and non-radiative recombination was thus discussed.