National Library of Energy BETA

Sample records for avian trv derivation

  1. Thermostatic Radiator Valve (TRV) Demonstration Project. Final report

    SciTech Connect (OSTI)

    1995-09-01

    This research measured the energy savings associated with installing thermostatic radiator valves (TRVs) on one-pipe low-pressure steam systems in New York City multifamily buildings. There were three primary objectives: to determine whether fuel consumption was lower in buildings using TRVs; to determine if occupants would accept the TRVs; and to determine if overheating in apartments could be eliminated using TRVs. Eight buildings, ranging in size from 15 to 26 apartments, were monitored for three years. Each building was audited to determine fuel history and quick-payback energy conservation measures. The project covered three phases; phase-1 consisted of installing low-cost energy conservation measures such as pipe insulation, air vents and burner tune-tips; determining each building`s baseline energy use, and recording baseline apartment temperatures. TRV installations occurred in phases 2 and 3. In phase-2, TRVs were installed in half the apartments in four buildings. In phase-3, TRVs were installed in the remainder of the apartments. Experimental results were conclusive. Buildings with overheated apartments achieved energy savings through the installation of TRVs. The authors research shows an average reduction of 9.45% in space heating energy use occurred with partial installation of TRVs, and savings of 15.5% were achieved after full installation. Buildings with the highest average apartment temperatures during the base year showed the greatest energy savings. Simple payback, based on an installed price of $50 per TRV, averaged 3.1 years.

  2. Avian Flu

    SciTech Connect (OSTI)

    Eckburg, Paul

    2006-11-06

    Since 2003, a severe form of H5N1 avian influenza has rapidly spread throughout Asia and Europe, infecting over 200 humans in 10 countries. The spread of H5N1 virus from person-to-person has been rare, thus preventing the emergence of a widespread pandemic. However, this ongoing epidemic continues to pose an important public health threat. Avian flu and its pandemic potential in humans will be discussed.

  3. Avian Conservation Resources | Open Energy Information

    Open Energy Info (EERE)

    Avian Conservation Resources Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: Avian Conservation ResourcesLegal Abstract Resources and...

  4. Bibliography of Literature for Avian Issues in Solar and Wind...

    Office of Scientific and Technical Information (OSTI)

    Bibliography of Literature for Avian Issues in Solar and Wind Energy and Other Activities Citation Details In-Document Search Title: Bibliography of Literature for Avian Issues in ...

  5. Suggested Practices for Avian Protection on Power Lines | Open...

    Open Energy Info (EERE)

    with federal laws protecting and enhancing avian populations, and maintaining the reliability of electric power networds. Author Avian Power Line Interaction Committee...

  6. Nocturnal Avian Migration Experiment Final Campaign Report

    Office of Scientific and Technical Information (OSTI)

    One solution is the incorporation of collocated acoustic monitoring that can provide ... The Nocturnal Avian Migration Experiment (NAME) took place at the Atmospheric Radiation ...

  7. Gender determination of avian embryo

    DOE Patents [OSTI]

    Daum, Keith A.; Atkinson, David A.

    2002-01-01

    Disclosed is a method for gender determination of avian embryos. During the embryo incubation process, the outer hard shells of eggs are drilled and samples of allantoic fluid are removed. The allantoic fluids are directly introduced into an ion mobility spectrometer (IMS) for analysis. The resulting spectra contain the relevant marker peaks in the positive or negative mode which correlate with unique mobilities which are sex-specific. This way, the gender of the embryo can be determined.

  8. Avian study protocols and wind energy development

    SciTech Connect (OSTI)

    Fisher, K.

    1995-12-01

    This paper identifies the need to develop and use standardized avian study protocols to determine avian impacts at new and existing wind energy facilities. This will allow data collected from various sites to be correlated for better understanding wind energy related avian impacts. Factors contributing to an increased interest in wind energy facilities by electric utilities include: (1) Increased demand for electricity;(2) increased constraints on traditional electrical generating facilities (i.e. hydroelectric and nuclear power plants);(3) improved wind turbine technology. During the 1980`s generous tax credits spawned the development of wind energy facilities, known as wind farms, in California. Commercial scale wind farm proposals are being actively considered in states across the country - Washington, Oregon, Wyoming, Wisconsin, Texas, and Vermont to name a few. From the wind farms in California the unexpected issue of avian impacts, especially to birds-of-prey, or raptor, surfaced and continues to plague the wind industry. However, most of the avian studies did not followed a standardized protocol or methodology and, therefore, data is unavailable to analyze and compare impacts at different sites or with differing technologies and configurations. Effective mitigation can not be designed and applied until these differences are understood. The Bonneville Power Administration is using comparable avian study protocols to collect data for two environmental impact statements being prepared for two separate wind farm proposals. Similar protocol will be required for any other avian impact analysis performed by the agency on proposed or existing wind farms. The knowledge gained from these studies should contribute to a better understanding of avian interactions with wind energy facilities and the identification of effective mitigation measures.

  9. Structure and Receptor Specificity of an Avian Flu Antigen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure and Receptor Specificity of an Avian Flu Antigen Print To date, the H5N1 avian influenza viruses, which are currently circulating in domestic and wild birds on three...

  10. Structure and Receptor Specificity of an Avian Flu Antigen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Receptor Specificity of an Avian Flu Antigen Print To date, the H5N1 avian influenza viruses, which are currently circulating in domestic and wild birds on three continents,...

  11. A quantitative method to analyze the quality of EIA information in wind energy development and avian/bat assessments

    SciTech Connect (OSTI)

    Chang, Tony; Nielsen, Erik; Auberle, William; Solop, Frederic I.

    2013-01-15

    The environmental impact assessment (EIA) has been a tool for decision makers since the enactment of the National Environmental Policy Act (NEPA). Since that time, few analyses have been performed to verify the quality of information and content within EIAs. High quality information within assessments is vital in order for decision makers, stake holders, and the public to understand the potential impact of proposed actions on the ecosystem and wildlife species. Low quality information has been a major cause for litigation and economic loss. Since 1999, wind energy development has seen an exponential growth with unknown levels of impact on wildlife species, in particular bird and bat species. The purpose of this article is to: (1) develop, validate, and apply a quantitative index to review avian/bat assessment quality for wind energy EIAs; and (2) assess the trends and status of avian/bat assessment quality in a sample of wind energy EIAs. This research presents the development and testing of the Avian and Bat Assessment Quality Index (ABAQI), a new approach to quantify information quality of ecological assessments within wind energy development EIAs in relation to avian and bat species based on review areas and factors derived from 23 state wind/wildlife siting guidance documents. The ABAQI was tested through a review of 49 publicly available EIA documents and validated by identifying high variation in avian and bat assessments quality for wind energy developments. Of all the reviewed EIAs, 66% failed to provide high levels of preconstruction avian and bat survey information, compared to recommended factors from state guidelines. This suggests the need for greater consistency from recommended guidelines by state, and mandatory compliance by EIA preparers to avoid possible habitat and species loss, wind energy development shut down, and future lawsuits. - Highlights: Black-Right-Pointing-Pointer We developed, validated, and applied a quantitative index to review

  12. Avian use of Norris Hill Wind Resource Area, Montana

    SciTech Connect (OSTI)

    Harmata, A.; Podruzny, K.; Zelenak, J.

    1998-07-01

    This document presents results of a study of avian use and mortality in and near a proposed wind resource area in southwestern Montana. Data collected in autumn 1995 through summer 1996 represented preconstruction condition; it was compiled, analyzed, and presented in a format such that comparison with post-construction data would be possible. The primary emphasis of the study was recording avian migration in and near the wind resource area using state-of-the-art marine surveillance radar. Avian use and mortality were investigated during the breeding season by employing traditional avian sampling methods, radiotelemetry, radar, and direct visual observation. 61 figs., 34 tabs.

  13. Structure and Receptor Specificity of an Avian Flu Antigen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure and Receptor Specificity of an Avian Flu Antigen Structure and Receptor Specificity of an Avian Flu Antigen Print Wednesday, 25 July 2007 00:00 To date, the H5N1 avian influenza viruses, which are currently circulating in domestic and wild birds on three continents, have only a limited ability to infect humans. However, with continued outbreaks of the virus in poultry and wild birds, the potential for the emergence of a human-adapted H5 virus, either by reassortment (the mixing of

  14. NREL: Photovoltaics Research - Report Targets Data on Avian Issues...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Report Targets Data on Avian Issues at Solar Energy Facilities May 4, 2015 Understanding how birds are affected by utility-scale solar facilities is the focus of a new NREL report...

  15. NREL: Solar Research - Report Targets Data on Avian Issues at...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Report Targets Data on Avian Issues at Solar Energy Facilities May 4, 2015 Understanding how birds are affected by utility-scale solar facilities is the focus of a new NREL report...

  16. Results from Analysis of Avian Retina Oil Droplets

    Office of Scientific and Technical Information (OSTI)

    @T n i: SAND2014-18406PE National Laboratories Avian Retina Oil Droplets 3-26-2014 & 3-27-2014 Sample preparation: Matt Toomey Imaging: Thomas Beechem, Anthony McDonald ...

  17. NREL: Technology Transfer - Report Targets Data on Avian Issues...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Report Targets Data on Avian Issues at Solar Energy Facilities May 4, 2015 Understanding how birds are affected by utility-scale solar facilities is the focus of a new NREL report...

  18. Microsoft Word - S04801_Avian2008 _2_ revised.doc

    Office of Legacy Management (LM)

    ... Swallows were observed throughout the spring and summer. Violet-green, Barn, and Cliff ... Avian Wetland Surveys at Monticello Mill Tailing Site, 2008 U.S. Department of Energy Doc. ...

  19. Structure and Receptor Specificity of an Avian Flu Antigen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure and Receptor Specificity of an Avian Flu Antigen Print To date, the H5N1 avian influenza viruses, which are currently circulating in domestic and wild birds on three continents, have only a limited ability to infect humans. However, with continued outbreaks of the virus in poultry and wild birds, the potential for the emergence of a human-adapted H5 virus, either by reassortment (the mixing of genetic material from similar viruses) or mutation, is seen as a major threat to public

  20. Structure and Receptor Specificity of an Avian Flu Antigen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure and Receptor Specificity of an Avian Flu Antigen Print To date, the H5N1 avian influenza viruses, which are currently circulating in domestic and wild birds on three continents, have only a limited ability to infect humans. However, with continued outbreaks of the virus in poultry and wild birds, the potential for the emergence of a human-adapted H5 virus, either by reassortment (the mixing of genetic material from similar viruses) or mutation, is seen as a major threat to public

  1. Structure and Receptor Specificity of an Avian Flu Antigen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure and Receptor Specificity of an Avian Flu Antigen Print To date, the H5N1 avian influenza viruses, which are currently circulating in domestic and wild birds on three continents, have only a limited ability to infect humans. However, with continued outbreaks of the virus in poultry and wild birds, the potential for the emergence of a human-adapted H5 virus, either by reassortment (the mixing of genetic material from similar viruses) or mutation, is seen as a major threat to public

  2. Structure and Receptor Specificity of an Avian Flu Antigen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Receptor Specificity of an Avian Flu Antigen Print To date, the H5N1 avian influenza viruses, which are currently circulating in domestic and wild birds on three continents, have only a limited ability to infect humans. However, with continued outbreaks of the virus in poultry and wild birds, the potential for the emergence of a human-adapted H5 virus, either by reassortment (the mixing of genetic material from similar viruses) or mutation, is seen as a major threat to public health

  3. PROJECT PROFILE: Addressing Environmental Challenges to Deployment through the Development of an Avian-Solar Science Plan and a Prototype Avian Risk Assessment Tool (SuNLaMP)

    Broader source: Energy.gov [DOE]

    The soft costs associated with solar project development can increase with potential wildlife impacts. Avian impact issues associated with utility scale solar development, in particular avian fatalities, are not well understood. This project will address these issues to help reach SunShot soft cost target goals by better understanding avian issues at utility scale solar facilities and their soft cost implications using a systematic, standardized, science-based approach that could be applied across the industry.

  4. Avian Collisions with Wind Turbines: A Summary of Existing Studies and Comparisons to Other Sources of Avian Collision Mortality in the United States

    SciTech Connect (OSTI)

    Erickson, Wallace P.; Johnson, Gregory D.; Strickland, Dale M.; Young, Jr., David P.; Sernka, Karyn J.; Good, Rhett E.

    2001-08-01

    It has been estimated that from 100 million to well over 1 billion birds are killed annually in the United States due to collisions with human-made structures, including vehicles, buildings and windows, powerlines, communication towers, and wind turbines. Although wind energy is generally considered environmentally friendly (because it generates electricity without emitting air pollutants or greenhouse gases), the potential for avian fatalities has delayed and even significantly contributed to blocking the development of some windplants in the U.S. Given the importance of developing a viable renewable source of energy, the objective of this paper is to put the issue of avian mortality associated with windpower into perspective with other sources of avian collision mortality across the U.S. The purpose of this paper is to provide a detailed summary of the mortality data collected at windplants and put avian collision mortality associated with windpower development into perspective with other significant sources of avian collision mortality across the United States. We provide a summary of data collected at many of the U.S. windplants and provide annual bird fatality estimates and projections for all wind turbines in the U.S. For comparison, we also review studies of avian collision mortality from other major human-made structures and report annual bird fatality estimates for these sources. Other sources also significantly contribute to overall avian mortality. For example, the National Audubon Society estimates avian mortality due to house cats at 100 million birds per year. Pesticide use, oil spills, disease, etc., are other significant sources of unintended avian mortality. Due to funding constraints, the scope of this paper is limited to examining only avian mortality resulting from collisions with human-made obstacles.

  5. Bibliography of Literature for Avian Issues in Solar and Wind Energy and

    Office of Scientific and Technical Information (OSTI)

    Other Activities (Technical Report) | SciTech Connect Bibliography of Literature for Avian Issues in Solar and Wind Energy and Other Activities Citation Details In-Document Search Title: Bibliography of Literature for Avian Issues in Solar and Wind Energy and Other Activities Authors: Walston, Leroy J. ; White, Ellen M. ; Meyers, Stephanie A. ; Turchi, Craig ; Sinclair, Karin Publication Date: 2015-04-01 OSTI Identifier: 1176922 Report Number(s): ANL/EVS-15/3 113904 DOE Contract Number:

  6. Avian Field guide and checklist for Kunsan Air Base, Korea.

    SciTech Connect (OSTI)

    Levenson, J. B.; Environmental Assessment

    2005-11-15

    This report summarizes the results of the avian surveys conducted at Kunsan Air Base (AB). This on-going survey is conducted to comply with requirements of the Environmental Governing Standards (EGS) for the Republic of Korea, the Integrated Natural Resources Management Plan (INRMP) for Kunsan AB, and the 8th Fighter Wing's Bird Aircraft Strike Hazard (BASH) Plan. One hundred sixteen bird species representing 34 families were identified and recorded. Seven species are designated as Cultural Property Monuments, and their protection is accorded by the Korean Ministry of Culture and Tourism. Six species appear on the Korean Association for Conservation of Nature's(KACN's) list of Reserved Wild Species and are protected by the Korean Ministry of Environment. Combined, only ten different species are Republic of Korea (ROK)-protected because the Eurasian Spoonbill, Peregrine Falcon, and Eurasian Oystercatcher are listed by both agencies. The primary objective of the avian survey at Kunsan AB was to determine what species of birds are present on the airfield and their respective habitat requirements during the critical seasons of the year. This requirement is specified in Annex C.4.a.(1-4) of the 8th Fighter Wing BASH Plan(8FWOPLAN 91-202). The second objective was to initiate surveys to determine what bird species are present on Kunsan AB throughout the year, and from the survey results determine if threatened, endangered, or other Korean-listed bird species are present on Kunsan AB. This overall census satisfies Criterion 13-3.e of the EGS for Korea. The final objective was to formulate management strategies within Kunsan AB's operational requirements to protect and enhance habitats of known threatened, endangered, and ROK-protected species in accordance with EGS Criterion 13-3.a and also that are favorable for the reproduction of indigenous species in accordance with the EGS Criterion 13-3.h.

  7. Avian survey and field guide for Osan Air Base, Korea.

    SciTech Connect (OSTI)

    Levenson, J.

    2006-12-05

    This report summarizes the results of the avian surveys conducted at Osan Air Base (AB). This ongoing survey is conducted to comply with requirements of the Environmental Governing Standards (EGS) for the Republic of Korea, the Integrated Natural Resources Management Plan (INRMP) for Osan AB, and the 51st Fighter Wing's Bird Aircraft Strike Hazard (BASH) Plan. One hundred ten bird species representing 35 families were identified and recorded. Seven species are designated as Natural Monuments, and their protection is accorded by the Korean Ministry of Culture and Tourism. Three species appear on the Korean Association for Conservation of Nature's (KACN's) list of Reserved Wild Species and are protected by the Korean Ministry of Environment. Combined, ten different species are Republic of Korea (ROK)-protected. The primary objective of the avian survey at Osan AB was to determine what species of birds are present on the airfield and their respective habitat requirements during the critical seasons of the year. This requirement is specified in Annex J.14.c of the 51st Fighter BASH Plan 91-212 (51 FW OPLAN 91-212). The second objective was to initiate surveys to determine what bird species are present on Osan AB throughout the year and from the survey results, determine if threatened, endangered, or other Korean-listed bird species are present on Osan AB. This overall census satisfies Criterion 13-3.e of the EGS for Korea. The final objective was to formulate management strategies within Osan AB's operational requirements to protect and enhance habitats of known threatened, endangered, and ROK-protected species in accordance with EGS Criterion 13-3.a that are also favorable for the reproduction of indigenous species in accordance with the EGS Criterion 13-3.h.

  8. The Radical Pair Mechanism and the Avian Chemical Compass: Quantum Coherence and Entanglement

    SciTech Connect (OSTI)

    Zhang, Yiteng; Kais, Sabre; Berman, Gennady Petrovich

    2015-02-02

    We review the spin radical pair mechanism which is a promising explanation of avian navigation. This mechanism is based on the dependence of product yields on 1) the hyperfine interaction involving electron spins and neighboring nuclear spins and 2) the intensity and orientation of the geomagnetic field. One surprising result is that even at ambient conditions quantum entanglement of electron spins can play an important role in avian magnetoreception. This review describes the general scheme of chemical reactions involving radical pairs generated from singlet and triplet precursors; the spin dynamics of the radical pairs; and the magnetic field dependence of product yields caused by the radical pair mechanism. The main part of the review includes a description of the chemical compass in birds. We review: the general properties of the avian compass; the basic scheme of the radical pair mechanism; the reaction kinetics in cryptochrome; quantum coherence and entanglement in the avian compass; and the effects of noise. We believe that the quantum avian compass can play an important role in avian navigation and can also provide the foundation for a new generation of sensitive and selective magnetic-sensing nano-devices.

  9. A complex carotenoid palette tunes avian color vision.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Timlin, Jerilyn A.; Toomey, Matthew B.; Collins, Aaron M.; Frederiksen, Rikard; Cornwall, M. Carter; Corbo, Joseph C.

    2015-10-07

    The brilliantly coloured cone oil droplets of the avian retina function as long-pass cut-off filters that tune the spectral sensitivity of the photoreceptors and are hypothesized to enhance colour discrimination and improve colour constancy. Although it has long been known that these droplets are pigmented with carotenoids, their precise composition has remained uncertain owing to the technical challenges of measuring these very small, dense and highly refractile optical organelles. In this study, we integrated results from high-performance liquid chromatography, hyperspectral microscopy and microspectrophotometry to obtain a comprehensive understanding of oil droplet carotenoid pigmentation in the chicken (Gallus gallus). We findmore » that each of the four carotenoid-containing droplet types consists of a complex mixture of carotenoids, with a single predominant carotenoid determining the wavelength of the spectral filtering cut-off. Consistent with previous reports, we find that the predominant carotenoid type in the oil droplets of long-wavelength-sensitive, medium-wavelength-sensitive and short-wavelength-sensitive type 2 cones are astaxanthin, zeaxanthin and galloxanthin, respectively. In addition, the oil droplet of the principal member of the double cone contains a mixture of galloxanthin and two hydroxycarotenoids (lutein and zeaxanthin). Short-wavelength-absorbing apocarotenoids are present in all of the droplet types, providing filtering of light in a region of the spectrum where filtering by hydroxy- and ketocarotenoids may be incomplete. Furthermore, birds rely on a complex palette of carotenoid pigments within their cone oil droplets to achieve finely tuned spectral filtering.« less

  10. A complex carotenoid palette tunes avian color vision.

    SciTech Connect (OSTI)

    Timlin, Jerilyn A.; Toomey, Matthew B.; Collins, Aaron M.; Frederiksen, Rikard; Cornwall, M. Carter; Corbo, Joseph C.

    2015-10-07

    The brilliantly coloured cone oil droplets of the avian retina function as long-pass cut-off filters that tune the spectral sensitivity of the photoreceptors and are hypothesized to enhance colour discrimination and improve colour constancy. Although it has long been known that these droplets are pigmented with carotenoids, their precise composition has remained uncertain owing to the technical challenges of measuring these very small, dense and highly refractile optical organelles. In this study, we integrated results from high-performance liquid chromatography, hyperspectral microscopy and microspectrophotometry to obtain a comprehensive understanding of oil droplet carotenoid pigmentation in the chicken (Gallus gallus). We find that each of the four carotenoid-containing droplet types consists of a complex mixture of carotenoids, with a single predominant carotenoid determining the wavelength of the spectral filtering cut-off. Consistent with previous reports, we find that the predominant carotenoid type in the oil droplets of long-wavelength-sensitive, medium-wavelength-sensitive and short-wavelength-sensitive type 2 cones are astaxanthin, zeaxanthin and galloxanthin, respectively. In addition, the oil droplet of the principal member of the double cone contains a mixture of galloxanthin and two hydroxycarotenoids (lutein and zeaxanthin). Short-wavelength-absorbing apocarotenoids are present in all of the droplet types, providing filtering of light in a region of the spectrum where filtering by hydroxy- and ketocarotenoids may be incomplete. Furthermore, birds rely on a complex palette of carotenoid pigments within their cone oil droplets to achieve finely tuned spectral filtering.

  11. Comparison of Avian Responses to UV-Light-Reflective Paint on Wind Turbines: Subcontract Report, July 1999--December 2000

    SciTech Connect (OSTI)

    Young, D. P., Jr.; Erickson, W. P.; Strickland, M. D.; Good, R. E.; Sernka, K. J.

    2003-01-01

    To reduce the numbers of avian collisions with wind turbines, several measures have been employed with various levels of success. One hypothesis is that painting turbine blades to increase their visibility may reduce avian fatalities. This study examined the effects of painting wind turbine blades with UV-reflective paint on bird use and mortality at the Foote Creek Rim Wind Plant in Carbon County, Wyoming.

  12. Effects of Precommercial Thinning and Midstory Control on Avian and Small Mammal Communities during Longleaf Pine Savanna Restoration.

    SciTech Connect (OSTI)

    Lane, Vanessa R; Kilgo, John C

    2015-01-01

    Abstract - Restoring longleaf pine (Pinus palustris Mill.) savanna is a goal of many southern land managers, and longleaf plantations may provide a mechanism for savanna restoration. However, the effects of silvicultural treatments used in the management of longleaf pine plantations on wildlife communities are relatively unknown. Beginning in 1994, we examined effects of longleaf pine restoration with plantation silviculture on avian and small mammal communities using four treatments in four 8- to 11- year-old plantations within the Savannah River Site in South Carolina. Treatments included prescribed burning every 3 to 5 years, plus: (1) no additional treatment (burn-only control); (2) precommercial thinning; (3) non-pine woody control with herbicides; and (4) combined thinning and woody control. We surveyed birds (1996-2003) using 50-m point counts and small mammals with removal trapping. Thinning and woody control alone had short-lived effects on avian communities, and the combination treatment increased avian parameters over the burn-only control in all years. Small mammal abundance showed similar trends as avian abundance for all three treatments when compared with the burn-only control, but only for 2 years post-treatment. Both avian and small mammal communities were temporarily enhanced by controlling woody vegetation with chemicals in addition to prescribed fire and thinning. Therefore, precommercial thinning in longleaf plantations, particularly when combined with woody control and prescribed fire, may benefit early-successional avian and small mammal communities by developing stand conditions more typical of natural longleaf stands maintained by periodic fire.

  13. Derived Annual Estimates

    U.S. Energy Information Administration (EIA) Indexed Site

    74-1988 For Methodology Concerning the Derived Estimates Total Consumption of Offsite-Produced Energy for Heat and Power by Industry Group, 1974-1988 Total Energy *** Electricity...

  14. Session: Avian migration and implications for wind power development in the Eastern United States

    SciTech Connect (OSTI)

    Mabey, Sarah; Cooper, Brian

    2004-09-01

    This session at the Wind Energy and Birds/Bats workshop consisted of two presentations followed by a discussion/question and answer period. The session was arranged to convey what is known about avian migration, particularly in the eastern US. The first presentation ''Migration Ecology: Issues of Scale and Behavior'' by Sarah Mabey frames the issue of migratory bird interactions with wind energy facilities from an ecological perspective: when, where, and why are migrant bird species vulnerable to wind turbine collision. The second presentation ''Radar Studies of Nocturnal Migration at Wind Sites in the Eastern US'' by Brian Cooper reported on radar studies conducted at wind sites in the eastern US, including Mount Storm, Clipper Wind, and others.

  15. Pushing schedule derivation method

    SciTech Connect (OSTI)

    Henriquez, B.

    1996-12-31

    The development of a Pushing Schedule Derivation Method has allowed the company to sustain the maximum production rate at CSH`s Coke Oven Battery, in spite of having single set oven machinery with a high failure index as well as a heat top tendency. The stated method provides for scheduled downtime of up to two hours for machinery maintenance purposes, periods of empty ovens for decarbonization and production loss recovery capability, while observing lower limits and uniformity of coking time.

  16. Biomonitoring of heavy metals in the Pacific Basin using avian feathers

    SciTech Connect (OSTI)

    Burger, J.; Gochfeld, M.

    1995-07-01

    The authors used avian feathers to biomonitor heavy-metal distribution in several areas in the Pacific Basin including Papua New Guinea, Australia, New Zealand, China, Johnston Atoll, Hawaii, and Costa Rica. This paper is a preliminary synthesis of data gathered by the Pacific Basin Biomonitoring Project. They examined levels of mercury, lead, cadmium, selenium, chromium, and manganese. For sooty terns (Sterna fuscata) and brown noddy (Anous stolidus) mercury levels were lower in the Pacific than in Puerto Rico in the Atlantic, but his was reversed for lead and cadmium. Adult birds had higher metal levels in their feathers than did young birds of the same species from the same area. Cadmium levels were higher in terrestrial species; lead, chromium, and manganese were highest in coastal species; and mercury and selenium were highest in marine species. Mercury levels were lowest in forest species, intermediate in species that eat insects and small vertebrates, and highest in species that eat intermediate to large fish. Lead levels were highest in species feeding in industrialized estuaries of Hong Kong.

  17. Algae Derived Biofuel

    SciTech Connect (OSTI)

    Jahan, Kauser

    2015-03-31

    One of the most promising fuel alternatives is algae biodiesel. Algae reproduce quickly, produce oils more efficiently than crop plants, and require relatively few nutrients for growth. These nutrients can potentially be derived from inexpensive waste sources such as flue gas and wastewater, providing a mutual benefit of helping to mitigate carbon dioxide waste. Algae can also be grown on land unsuitable for agricultural purposes, eliminating competition with food sources. This project focused on cultivating select algae species under various environmental conditions to optimize oil yield. Membrane studies were also conducted to transfer carbon di-oxide more efficiently. An LCA study was also conducted to investigate the energy intensive steps in algae cultivation.

  18. PROJECT PROFILE: Development of Tools, Training, and Outreach to Address Solar Glare and Flux-Related Avian Impacts (SuNLaMP)

    Broader source: Energy.gov [DOE]

    This project reduces soft costs associated with siting, permitting, environmental compliance, and operations and maintenance to address glare and flux-related avian hazards for concentrating solar power (CSP) plants. Enhancements, training, and technical assistance will be provided for the Solar Glare Hazard Analysis Tool (SGHAT), which determines when and where solar glare can occur throughout the year from a user-specified solar array as viewed from user-prescribed observation points. By addressing glare and avian issues, this project will allow for solar projects to be installed on or near airport property in compliance of federal regulations.

  19. Derived Annual Estimates of Manufacturing Energy Consumption...

    U.S. Energy Information Administration (EIA) Indexed Site

    > Derived Annual Estimates - Executive Summary Derived Annual Estimates of Manufacturing Energy Consumption, 1974-1988 Figure showing Derived Estimates Executive Summary This...

  20. Avian community composition in response to high explosive testing operations at Los Alamos National Laboratory in Northern New Mexico

    SciTech Connect (OSTI)

    Keller, David C.; Fresquez, Philip R.; Hansen, Leslie A.; Kaschube, Danielle R.

    2015-12-28

    Breeding bird abundance, species richness, evenness, diversity, composition, productivity, and survivorship were determined near a high-explosive detonation site at Los Alamos National Laboratory, New Mexico, USA, during pre-operation (1997-1999) and operation (2000-2014) periods. The operation periods consisted of detonations (<23 kg in yield and <3 per breeding season) in open air (2000-2002), within foam containment (2003-2006) and within steel vessel containment (2007-2014) systems; the latter two were employed to reduce noise and dispersal of high-explosives residues. A total of 2952 bird captures, representing 80 species, was recorded during 18 years of mist net operations using the Monitoring Avian Productivity and Survivorship protocol. Individuals captured were identified to species, aged, sexed, and banded during May through August of each year. There were no significant differences (p > 0.05) in mean avian abundance and species evenness in any of the operation periods as compared with the pre-operation period. Species richness and diversity were significantly higher (p < 0.05) during the vessel containment period (2007-2014) than the pre-operation period. The time period of this study coincided with a wildfire (2000), a bark beetle infestation (2002), and two periods of drought (Nov 1999-Mar 2004 and Dec 2005-Dec 2014) that affected the study area. Furthermore, analysis of aerial photos determined that the average percent canopy cover of mature ponderosa pines (Pinus ponderosa) within 100 feet of mist net sites declined from 12% to 3% between 1991 and 2014 and the percent cover of shrubs slightly increased.

  1. Avian community composition in response to high explosive testing operations at Los Alamos National Laboratory in Northern New Mexico

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Keller, David C.; Fresquez, Philip R.; Hansen, Leslie A.; Kaschube, Danielle R.

    2015-12-28

    Breeding bird abundance, species richness, evenness, diversity, composition, productivity, and survivorship were determined near a high-explosive detonation site at Los Alamos National Laboratory, New Mexico, USA, during pre-operation (1997-1999) and operation (2000-2014) periods. The operation periods consisted of detonations (<23 kg in yield and <3 per breeding season) in open air (2000-2002), within foam containment (2003-2006) and within steel vessel containment (2007-2014) systems; the latter two were employed to reduce noise and dispersal of high-explosives residues. A total of 2952 bird captures, representing 80 species, was recorded during 18 years of mist net operations using the Monitoring Avian Productivity andmore » Survivorship protocol. Individuals captured were identified to species, aged, sexed, and banded during May through August of each year. There were no significant differences (p > 0.05) in mean avian abundance and species evenness in any of the operation periods as compared with the pre-operation period. Species richness and diversity were significantly higher (p < 0.05) during the vessel containment period (2007-2014) than the pre-operation period. The time period of this study coincided with a wildfire (2000), a bark beetle infestation (2002), and two periods of drought (Nov 1999-Mar 2004 and Dec 2005-Dec 2014) that affected the study area. Furthermore, analysis of aerial photos determined that the average percent canopy cover of mature ponderosa pines (Pinus ponderosa) within 100 feet of mist net sites declined from 12% to 3% between 1991 and 2014 and the percent cover of shrubs slightly increased.« less

  2. A luciferase reporter gene assay and aryl hydrocarbon receptor 1 genotype predict the LD{sub 50} of polychlorinated biphenyls in avian species

    SciTech Connect (OSTI)

    Manning, Gillian E.; Farmahin, Reza; Environment Canada, National Wildlife Research Centre, Ottawa, ON, Canada K1A 0H3 ; Crump, Doug; Jones, Stephanie P.; Klein, Jeff; Konstantinov, Alex; Potter, Dave; Kennedy, Sean W.

    2012-09-15

    Birds differ in sensitivity to the embryotoxic effects of polychlorinated biphenyls (PCBs), which complicates environmental risk assessments for these chemicals. Recent research has shown that the identities of amino acid residues 324 and 380 in the avian aryl hydrocarbon receptor 1 (AHR1) ligand binding domain (LBD) are primarily responsible for differences in avian species sensitivity to selected dibenzo-p-dioxins and furans. A luciferase reporter gene (LRG) assay was developed in our laboratory to measure AHR1-mediated induction of a cytochrome P450 1A5 reporter gene in COS-7 cells transfected with different avian AHR1 constructs. In the present study, the LRG assay was used to measure the concentration-dependent effects of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD), and PCBs 126, 77, 105 and 118 on luciferase activity in COS-7 cells transfected with AHR1 constructs representative of 86 avian species in order to predict their sensitivity to PCB-induced embryolethality and the relative potency of PCBs in these species. The results of the LRG assay indicate that the identity of amino acid residues 324 and 380 in the AHR1 LBD are the major determinants of avian species sensitivity to PCBs. The relative potency of PCBs did not differ greatly among AHR1 constructs. Luciferase activity was significantly correlated with embryolethality data obtained from the literature (R{sup 2} ≥ 0.87, p < 0.0001). Thus, the LRG assay in combination with the knowledge of a species' AHR1 LBD sequence can be used to predict PCB-induced embryolethality in potentially any avian species of interest without the use of lethal methods on a large number of individuals. -- Highlights: ► PCB embryolethality in birds can be predicted from a species' AHR1 genotype. ► The reporter gene assay is useful for predicting species sensitivity to PCBs. ► The relative potency of PCBs does not appear to differ between AHR1 genotypes. ► Contamination of PCB 105 and PCB 118 did not affect their

  3. Derivative

    National Nuclear Security Administration (NNSA)

    Robert C. Jones, Colleen M. Beck, and Barbara A. Holz Division of Earth and Ecosystem Sciences Cultural Resources Technical Report No.102 Desert Research Institute Las Vegas, ...

  4. Sol-gel derived sorbents

    DOE Patents [OSTI]

    Sigman, Michael E.; Dindal, Amy B.

    2003-11-11

    Described is a method for producing copolymerized sol-gel derived sorbent particles for the production of copolymerized sol-gel derived sorbent material. The method for producing copolymerized sol-gel derived sorbent particles comprises adding a basic solution to an aqueous metal alkoxide mixture for a pH.ltoreq.8 to hydrolyze the metal alkoxides. Then, allowing the mixture to react at room temperature for a precalculated period of time for the mixture to undergo an increased in viscosity to obtain a desired pore size and surface area. The copolymerized mixture is then added to an immiscible, nonpolar solvent that has been heated to a sufficient temperature wherein the copolymerized mixture forms a solid upon the addition. The solid is recovered from the mixture, and is ready for use in an active sampling trap or activated for use in a passive sampling trap.

  5. Magnetic cellulose-derivative structures

    DOE Patents [OSTI]

    Walsh, Myles A.; Morris, Robert S.

    1986-09-16

    Structures to serve as selective magnetic sorbents are formed by dissolving a cellulose derivative such as cellulose triacetate in a solvent containing magnetic particles. The resulting solution is sprayed as a fine mist into a chamber containing a liquid coagulant such as n-hexane in which the cellulose derivative is insoluble but in which the coagulant is soluble or miscible. On contact with the coagulant, the mist forms free-flowing porous magnetic microspheric structures. These structures act as containers for the ion-selective or organic-selective sorption agent of choice. Some sorbtion agents can be incorporated during the manufacture of the structure.

  6. Magnetic cellulose-derivative structures

    DOE Patents [OSTI]

    Walsh, M.A.; Morris, R.S.

    1986-09-16

    Structures to serve as selective magnetic sorbents are formed by dissolving a cellulose derivative such as cellulose triacetate in a solvent containing magnetic particles. The resulting solution is sprayed as a fine mist into a chamber containing a liquid coagulant such as n-hexane in which the cellulose derivative is insoluble but in which the coagulant is soluble or miscible. On contact with the coagulant, the mist forms free-flowing porous magnetic microspheric structures. These structures act as containers for the ion-selective or organic-selective sorption agent of choice. Some sorption agents can be incorporated during the manufacture of the structure. 3 figs.

  7. Redox Chemistry of Anthraquinone Derivatives Via Simulations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    August 27, 2014, Research Highlights Redox Chemistry of Anthraquinone Derivatives Via ... S. Assary, Investigation of the Redox Chemistry of Anthraquinone Derivatives Using ...

  8. Binder enhanced refuse derived fuel

    DOE Patents [OSTI]

    Daugherty, Kenneth E.; Venables, Barney J.; Ohlsson, Oscar O.

    1996-01-01

    A refuse derived fuel (RDF) pellet having about 11% or more particulate calcium hydroxide which is utilized in a combustionable mixture. The pellets are used in a particulate fuel bring a mixture of 10% or more, on a heat equivalent basis, of the RDF pellet which contains calcium hydroxide as a binder, with 50% or more, on a heat equivalent basis, of a sulphur containing coal. Combustion of the mixture is effective to produce an effluent gas from the combustion zone having a reduced SO.sub.2 and polycyclic aromatic hydrocarbon content of effluent gas from similar combustion materials not containing the calcium hydroxide.

  9. Synthesis and Comparison of Baseline Avian and Bat Use, Raptor Nesting and Mortality Information from Proposed and Existing Wind Developments: Final Report.

    SciTech Connect (OSTI)

    Erickson, Wallace P.

    2002-12-01

    Primarily due to concerns generated from observed raptor mortality at the Altamont Pass (CA) wind plant, one of the first commercial electricity generating wind plants in the U.S., new proposed wind projects both within and outside of California have received a great deal of scrutiny and environmental review. A large amount of baseline and operational monitoring data have been collected at proposed and existing U.S. wind plants. The primary use of the avian baseline data collected at wind developments has been to estimate the overall project impacts (e.g., very low, low, moderate, and high relative mortality) on birds, especially raptors and sensitive species (e.g., state and federally listed species). In a few cases, these data have also been used for guiding placement of turbines within a project boundary. This new information has strengthened our ability to accurately predict and mitigate impacts from new projects. This report should assist various stakeholders in the interpretation and use of this large information source in evaluating new projects. This report also suggests that the level of baseline data (e.g., avian use data) required to adequately assess expected impacts of some projects may be reduced. This report provides an evaluation of the ability to predict direct impacts on avian resources (primarily raptors and waterfowl/waterbirds) using less than an entire year of baseline avian use data (one season, two seasons, etc.). This evaluation is important because pre-construction wildlife surveys can be one of the most time-consuming aspects of permitting wind power projects. For baseline data, this study focuses primarily on standardized avian use data usually collected using point count survey methodology and raptor nest survey data. In addition to avian use and raptor nest survey data, other baseline data is usually collected at a proposed project to further quantify potential impacts. These surveys often include vegetation mapping and state or

  10. Cytochrome P4501A induction in avian hepatocyte cultures exposed to polychlorinated biphenyls: Comparisons with AHR1-mediated reporter gene activity and in ovo toxicity

    SciTech Connect (OSTI)

    Manning, Gillian E.; Mundy, Lukas J.; Crump, Doug; Jones, Stephanie P.; Chiu, Suzanne; Klein, Jeff; Konstantinov, Alex; Potter, Dave; Kennedy, Sean W.

    2013-01-01

    Avian-specific toxic equivalency factors (TEFs) were developed by the World Health Organization to simplify environmental risk assessments of dioxin-like compounds (DLCs), but TEFs do not account for differences in the toxic and biochemical potencies of DLCs among species of birds. Such variability may be due to differences in species sensitivity to individual DLCs. The sensitivity of avian species to DLCs was recently associated with the identity of amino acids 324 and 380 in the aryl hydrocarbon receptor 1 (AHR1) ligand binding domain. A luciferase reporter gene (LRG) assay, measuring AHR1-mediated induction of a cytochrome P450 1A5 (CYP1A5) reporter gene, in combination with a species' AHR1 ligand binding domain sequence, were also shown to predict avian species sensitivity to polychlorinated biphenyls (PCBs) and PCB relative potency in a given species. The goals of the present study were to (1) characterize the concentration-dependent effects of 2,3,7,8-tetrachlorodibenzo-p-dioxin and PCBs 126, 77, 105 and 118 on induction of ethoxyresorufin O-deethylase (EROD) activity and CYP1A4/5 mRNA in chicken, ring-necked pheasant and Japanese quail embryo hepatocytes and (2) compare these in vitro results to those previously generated by the LRG assay and in ovo toxicity studies. EROD activity and CYP1A4/5 mRNA expression data support and complement the findings of the LRG assay. CYP1A enzyme activity and mRNA expression were significantly correlated both with luciferase activity and in ovo toxicity induced by PCBs. Relative potency values were generally similar between the LRG and EROD assays and indicate that the relative potency of some PCBs may differ among species. -- Highlights: ► The chicken isn't the most sensitive species to CYP1A induction by PCB 105 and 118. ► The relative potency of PCBs differs between avian species. ► EROD activity was correlated with luciferase activity from the LRG assay. ► EROD activity was a better predictor of toxicity than CYP

  11. Total-derivative supersymmetry breaking

    SciTech Connect (OSTI)

    Haba, Naoyuki; Uekusa, Nobuhiro

    2010-05-15

    On an interval compactification in supersymmetric theory, boundary conditions for bulk fields must be treated carefully. If they are taken arbitrarily following the requirement that a theory is supersymmetric, the conditions could give redundant constraints on the theory. We construct a supersymmetric action integral on an interval by introducing brane interactions with which total-derivative terms under the supersymmetry transformation become zero due to a cancellation. The variational principle leads equations of motion and also boundary conditions for bulk fields, which determine boundary values of bulk fields. By estimating mass spectrum, spontaneous supersymmetry breaking in this simple setup can be realized in a new framework. This supersymmetry breaking does not induce a massless R axion, which is favorable for phenomenology. It is worth noting that fermions in hyper-multiplet, gauge bosons, and the fifth-dimensional component of gauge bosons can have zero-modes (while the other components are all massive as Kaluza-Klein modes), which fits the gauge-Higgs unification scenarios.

  12. Tetrahydroquinoline Derivatives as Potent and Selective Factor...

    Office of Scientific and Technical Information (OSTI)

    as Potent and Selective Factor XIa Inhibitors Citation Details In-Document Search Title: Tetrahydroquinoline Derivatives as Potent and Selective Factor XIa Inhibitors Authors: ...

  13. Proceedings of refuse-derived fuel (RDF)

    SciTech Connect (OSTI)

    Saltiel, C. )

    1991-01-01

    This book contains proceedings of Refuse-Derived Fuel (RDF)-Quality. Standards and Processing. Topics covered include: An Overview of RDF Processing Systems: Current Status, Design Features, and Future Trends. The Impact of Recycling and Pre-Combustion Processing of Municipal Solid Waste on Fuel Properties and Steam Combustion. The Changing Role of Standards in the Marketing of RDF. Refuse Derived Fuel Quality Requirements for Firing in Utility, Industrial or Dedicated Boilers. Refuse-Derived Fuel Moisture Effects on Boiler Performance and Operability. Refuse Derived Fuels: Technology, Processing, Quality and Combustion Experiences.

  14. DERIVATION OF STOCHASTIC ACCELERATION MODEL CHARACTERISTICS FOR...

    Office of Scientific and Technical Information (OSTI)

    FOR SOLAR FLARES FROM RHESSI HARD X-RAY OBSERVATIONS Citation Details In-Document Search Title: DERIVATION OF STOCHASTIC ACCELERATION MODEL CHARACTERISTICS FOR SOLAR FLARES ...

  15. Biomass Derivatives Competitive with Heating Oil Costs.

    Energy Savers [EERE]

    Biomass Derivatives Competitive with Heating Oil Costs Transportation fuel Heat or electricity * Data are from literature, except heating oil is adjusted from 2011 winter average * ...

  16. Avian inhalation exposure chamber

    DOE Patents [OSTI]

    Briant, James K.; Driver, Crystal J.

    1992-01-01

    An exposure system for delivering gaseous material ranging in particle size from 0.4 micrometers to 20.0 micrometers uniformly to the heads of experimental animals, primarily birds. The system includes a vertical outer cylinder and a central chimney with animal holding bottles connected to exposure ports on the vertical outer cylinder.

  17. Avian inhalation exposure chamber

    DOE Patents [OSTI]

    Briant, J.K.; Driver, C.J.

    1992-05-05

    An exposure system is designed for delivering gaseous material ranging in particle size from 0.4 micrometers to 20.0 micrometers uniformly to the heads of experimental animals, primarily birds. The system includes a vertical outer cylinder and a central chimney with animal holding bottles connected to exposure ports on the vertical outer cylinder. 2 figs.

  18. ADIFOR: Fortran source translation for efficient derivatives

    SciTech Connect (OSTI)

    Bischof, C.; Corliss, G.; Griewank, A.; Hovland, P. ); Carle, A. . Center for Research on Parallel Computation)

    1992-01-01

    The numerical methods employed in the solution of many scientific computing problems require the computation of derivatives of a function f: R{sup n} {yields} R{sup m}. Both the accuracy and the computational requirements of the derivative computation are usually of critical importance for the robustness and speed of the numerical method. ADIFOR (Automatic Differentiation In FORtran) is a source translation tool implemented using the data abstractions and program analysis capabilities of the ParaScope Parallel Programming Environment. ADIFOR accepts arbitrary Fortran-77 code defining the computation of a function and writes portable Fortran-77 code for the computation of its derivatives. In contrast to previous approaches, ADIFOR views automatic differentiation as a process of source translation that exploits computational context to reduce the cost of derivative computations. Experimental results show that ADIFOR can handle real-life codes, providing exact derivatives with a running time that is competitive with the standard divided-difference approximations of derivatives and which may perform orders of magnitude faster than divided-differences in cases. The computational scientist using ADIFOR is freed from worrying about the accurate and efficient computation of derivatives, even for complicated functions,'' and hence, is able to concentrate on the more important issues of algorithm design or system modeling. 35 refs.

  19. Growing attraction of refuse-derived fuels

    SciTech Connect (OSTI)

    Singh, R.

    1981-09-08

    A review of Dr. Andrew Porteous' book, Refuse Derived Fuels is presented. The escalating price of fossil fuel, particularily oil, together with the high cost of handling and transporting refuse makes the idea of refuse-derived fuel production an attractive and economic proposition. Refuse-derived fuel production is discussed and the various manufacturing processes in the UK and the USA are described. The pyrolysis of refuse for the production of gas, oil or heat and the production of methane and ethyl alcohol or other possibilities for refuse conversion.

  20. SCM Forcing Data Derived from NWP Analyses

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jakob, Christian

    2008-01-15

    Forcing data, suitable for use with single column models (SCMs) and cloud resolving models (CRMs), have been derived from NWP analyses for the ARM (Atmospheric Radiation Measurement) Tropical Western Pacific (TWP) sites of Manus Island and Nauru.

  1. Casimir Energy Associated With Fractional Derivative Field

    SciTech Connect (OSTI)

    Lim, S. C.

    2007-04-28

    Casimir energy associated with fractional derivative scalar massless field at zero and positive temperature can be obtained using the regularization based on generalized Riemann zeta function of Epstein-Hurwitz type.

  2. Tax Credit for Forest Derived Biomass

    Broader source: Energy.gov [DOE]

    Forest-derived biomass includes tree tops, limbs, needles, leaves, and other woody debris leftover from activities such as timber harvesting, forest thinning, fire suppression, or forest health m...

  3. Second derivatives for approximate spin projection methods

    SciTech Connect (OSTI)

    Thompson, Lee M.; Hratchian, Hrant P.

    2015-02-07

    The use of broken-symmetry electronic structure methods is required in order to obtain correct behavior of electronically strained open-shell systems, such as transition states, biradicals, and transition metals. This approach often has issues with spin contamination, which can lead to significant errors in predicted energies, geometries, and properties. Approximate projection schemes are able to correct for spin contamination and can often yield improved results. To fully make use of these methods and to carry out exploration of the potential energy surface, it is desirable to develop an efficient second energy derivative theory. In this paper, we formulate the analytical second derivatives for the Yamaguchi approximate projection scheme, building on recent work that has yielded an efficient implementation of the analytical first derivatives.

  4. Derivative expansion of the effective action

    SciTech Connect (OSTI)

    Cheyette, O.

    1987-04-01

    This paper describes some methods for calculating derivative terms in the one loop effective action for a quantum field theory. The functional approach and background field method are first used to derive the general form of the one loop determinant. Then the determinant is expanded in powers of derivatives of the background fields. The form of this expansion is described for the simple case of an interacting scalar field, and then for the more complicated problem of a non-abelian gauge field. Finally, the expansion is applied to the task of calculating Higgs mass dependent effects in the Glashow-Weinberg-Salam model, and all terms which grow with the Higgs mass M/sub H/ are found in the one loop approximation. The result of this calculation is used to find the dependence of the gauge boson mass ratio rho on M/sub H/, and also to estimate the size of corrections to W and Z scattering theorems.

  5. High ethanol producing derivatives of Thermoanaerobacter ethanolicus

    DOE Patents [OSTI]

    Ljungdahl, Lars G.; Carriera, Laura H.

    1983-01-01

    Derivatives of the newly discovered microorganism Thermoanaerobacter ethanolicus which under anaerobic and thermophilic conditions continuously ferment substrates such as starch, cellobiose, glucose, xylose and other sugars to produce recoverable amounts of ethanol solving the problem of fermentations yielding low concentrations of ethanol using the parent strain of the microorganism Thermoanaerobacter ethanolicus are disclosed. These new derivatives are ethanol tolerant up to 10% (v/v) ethanol during fermentation. The process includes the use of an aqueous fermentation medium, containing the substrate at a substrate concentration greater than 1% (w/v).

  6. High ethanol producing derivatives of Thermoanaerobacter ethanolicus

    DOE Patents [OSTI]

    Ljungdahl, L.G.; Carriera, L.H.

    1983-05-24

    Derivatives of the newly discovered microorganism Thermoanaerobacter ethanolicus which under anaerobic and thermophilic conditions continuously ferment substrates such as starch, cellobiose, glucose, xylose and other sugars to produce recoverable amounts of ethanol solving the problem of fermentations yielding low concentrations of ethanol using the parent strain of the microorganism Thermoanaerobacter ethanolicus are disclosed. These new derivatives are ethanol tolerant up to 10% (v/v) ethanol during fermentation. The process includes the use of an aqueous fermentation medium, containing the substrate at a substrate concentration greater than 1% (w/v).

  7. High speed point derivative microseismic detector

    DOE Patents [OSTI]

    Uhl, James Eugene; Warpinski, Norman Raymond; Whetten, Ernest Blayne

    1998-01-01

    A high speed microseismic event detector constructed in accordance with the present invention uses a point derivative comb to quickly and accurately detect microseismic events. Compressional and shear waves impinging upon microseismic receiver stations disposed to collect waves are converted into digital data and analyzed using a point derivative comb including assurance of quiet periods prior to declaration of microseismic events. If a sufficient number of quiet periods have passed, the square of a two point derivative of the incoming digital signal is compared to a trip level threshold exceeding the determined noise level to declare a valid trial event. The squaring of the derivative emphasizes the differences between noise and signal, and the valid event is preferably declared when the trip threshold has been exceeded over a temporal comb width to realize a comb over a given time period. Once a trial event has been declared, the event is verified through a spatial comb, which applies the temporal event comb to additional stations. The detector according to the present invention quickly and accurately detects initial compressional waves indicative of a microseismic event which typically exceed the ambient cultural noise level by a small amount, and distinguishes the waves from subsequent larger amplitude shear waves.

  8. Constraining higher derivative supergravity with scattering amplitudes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yifan; Yin, Xi

    2015-08-31

    We study supersymmetry constraints on higher derivative deformations of type IIB supergravity by consideration of superamplitudes. Thus, combining constraints of on-shell supervertices and basic results from string perturbation theory, we give a simple argument for the non-renormalization theorem of Green and Sethi, and some of its generalizations.

  9. High speed point derivative microseismic detector

    DOE Patents [OSTI]

    Uhl, J.E.; Warpinski, N.R.; Whetten, E.B.

    1998-06-30

    A high speed microseismic event detector constructed in accordance with the present invention uses a point derivative comb to quickly and accurately detect microseismic events. Compressional and shear waves impinging upon microseismic receiver stations disposed to collect waves are converted into digital data and analyzed using a point derivative comb including assurance of quiet periods prior to declaration of microseismic events. If a sufficient number of quiet periods have passed, the square of a two point derivative of the incoming digital signal is compared to a trip level threshold exceeding the determined noise level to declare a valid trial event. The squaring of the derivative emphasizes the differences between noise and signal, and the valid event is preferably declared when the trip threshold has been exceeded over a temporal comb width to realize a comb over a given time period. Once a trial event has been declared, the event is verified through a spatial comb, which applies the temporal event comb to additional stations. The detector according to the present invention quickly and accurately detects initial compressional waves indicative of a microseismic event which typically exceed the ambient cultural noise level by a small amount, and distinguishes the waves from subsequent larger amplitude shear waves. 9 figs.

  10. Cost Analysis of Bio-Derived Liquids Reforming (Presentation) | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Bio-Derived Liquids Reforming (Presentation) Cost Analysis of Bio-Derived Liquids Reforming (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. 03_dti_cost_analysis_bio-derived_liquids_reforming.pdf (471.59 KB) More Documents & Publications BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) Bio-Derived Liquids to Hydrogen Distributed Reforming Working

  11. Structures of Lung Cancer-Derived EGFR Mutants and Inhibitor...

    Office of Scientific and Technical Information (OSTI)

    Structures of Lung Cancer-Derived EGFR Mutants and Inhibitor Complexes: Mechanism of ... Citation Details In-Document Search Title: Structures of Lung Cancer-Derived EGFR Mutants ...

  12. Low-Emissions Burner Technology using Biomass-Derived Liquid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels This factsheet describes a project that ...

  13. High Temperature/Low Humidity Polymer Electrolytes Derived from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High TemperatureLow Humidity Polymer Electrolytes Derived from Ionic Liquids High TemperatureLow Humidity Polymer Electrolytes Derived from Ionic Liquids Presentation on High ...

  14. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Environmental Management (EM)

    Meeting - November 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting - November 2007 The Bio-Derived Liquids to Hydrogen Distributed Reforming ...

  15. Biomass-derived Hydrogen-evolution catalyst and electrode - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass-derived Hydrogen-evolution catalyst and electrode Brookhaven National Laboratory ... PDF Document Publication Biomass-derived electrocatalytic composites for hydrogen ...

  16. Uncertainty estimates for derivatives and intercepts

    SciTech Connect (OSTI)

    Clark, E.L.

    1994-09-01

    Straight line least squares fits of experimental data are widely used in the analysis of test results to provide derivatives and intercepts. A method for evaluating the uncertainty in these parameters is described. The method utilizes conventional least squares results and is applicable to experiments where the independent variable is controlled, but not necessarily free of error. A Monte Carlo verification of the method is given.

  17. Triamine chelants, their derivatives, complexes and conjugates

    DOE Patents [OSTI]

    Troutner, D.E.; John, C.S.; Pillai, M.R.A.

    1995-03-07

    A group of functionalized triamine chelants and their derivatives that form complexes with radioactive metal ions are disclosed. The complexes can be covalently attached to a protein or an antibody or antibody fragment and used for therapeutic and/or diagnostic purposes. The chelants are of the formula, as shown in the accompanying diagrams, wherein n, m, R, R{sup 1}, R{sup 2} and L are defined in the specification.

  18. Triamine chelants, their derivatives, complexes and conjugates

    DOE Patents [OSTI]

    Troutner, David E.; John, Christy S.; Pillai, Maroor R. A.

    1995-01-01

    A group of functionalized triamine chelants and their derivatives that form complexes with radioactive metal ions are disclosed. The complexes can be covalently attached to a protein or an antibody or antibody fragment and used for therapeutic and/or diagnostic purposes. The chelants are of the formula: ##STR1## wherein n, m, R, R.sup.1, R.sup.2 and L are defined in the specification.

  19. Alternative Fuels Data Center: Hydrogenation-Derived Renewable Diesel

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Emerging Fuels Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogenation-Derived Renewable Diesel to someone by E-mail Share Alternative Fuels Data Center: Hydrogenation-Derived Renewable Diesel on Facebook Tweet about Alternative Fuels Data Center: Hydrogenation-Derived Renewable Diesel on Twitter Bookmark Alternative Fuels Data Center: Hydrogenation-Derived Renewable Diesel on Google Bookmark Alternative Fuels Data Center: Hydrogenation-Derived Renewable

  20. Hydrogen from Bio-Derived Liquids (Presentation) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Bio-Derived Liquids (Presentation) Hydrogen from Bio-Derived Liquids (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. 09_pnnl_h2_from_bio-derived_liquids.pdf (326.2 KB) More Documents & Publications Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team Renewable

  1. Research, Monitoring, and Evaluation of Avian Predation on Salmonid Smolts in the Lower and Mid-Columbia River, 2006 Final Season Summary.

    SciTech Connect (OSTI)

    Roby, Daniel D.; Collis, Ken; Lyons, Donald E.

    2009-06-18

    This study investigates predation by piscivorous waterbirds on juvenile salmonids (Oncorhynchus spp.) from throughout the Columbia River Basin. During 2006, study objectives in the Columbia River estuary, work funded by the Bonneville Power Administration, were to (1) monitor and evaluate previous management initiatives to reduce Caspian tern (Hydroprogne caspia) predation on juvenile salmonids (smolts); (2) measure the impact of double-crested cormorant (Phalacrocorax auritus) predation on smolt survival, and assess potential management options to reduce cormorant predation; and (3) monitor large colonies of other piscivorous waterbirds in the estuary (i.e., glaucous-winged/western gulls [Larus glaucescens/occidentalis]) to determine the potential impacts on smolt survival. Study objectives on the mid-Columbia River, work funded by the Walla Walla District of the U.S. Army Corps of Engineers, were to (1) measure the impact of predation by Caspian terns and double-crested cormorants on smolt survival; and (2) monitor large nesting colonies of other piscivorous waterbirds (i.e., California gulls [L. californicus], ring-billed gulls [L. delawarensis], American white pelicans [Pelecanus erythrorhynchos]) on the mid-Columbia River to determine the potential for significant impacts on smolt survival. Our efforts to evaluate system-wide losses of juvenile salmonids to avian predation indicated that Caspian terns and double-crested cormorants were responsible for the vast majority of smolt losses to avian predators in the Columbia Basin, with most losses occurring in the Columbia River estuary. In 2006, East Sand Island in the Columbia River estuary supported the largest known breeding colonies of Caspian terns and double-crested cormorants in the world. The Caspian tern colony on East Sand Island consisted of about 9,200 breeding pairs in 2006, up slightly (but not significantly so) from the estimate of colony size in 2005 (8,820 pairs). There has not been a

  2. Derivation of an Applied Nonlinear Schroedinger Equation.

    SciTech Connect (OSTI)

    Pitts, Todd Alan; Laine, Mark Richard; Schwarz, Jens; Rambo, Patrick K.; Karelitz, David B.

    2015-01-01

    We derive from first principles a mathematical physics model useful for understanding nonlinear optical propagation (including filamentation). All assumptions necessary for the development are clearly explained. We include the Kerr effect, Raman scattering, and ionization (as well as linear and nonlinear shock, diffraction and dispersion). We explain the phenomenological sub-models and each assumption required to arrive at a complete and consistent theoretical description. The development includes the relationship between shock and ionization and demonstrates why inclusion of Drude model impedance effects alters the nature of the shock operator. Unclassified Unlimited Release

  3. Lignin-Derived Advanced Carbon Materials

    SciTech Connect (OSTI)

    Chatterjee, Sabornie; Saito, Tomonori

    2015-11-16

    Lignin is a highly abundant source of renewable carbon that can be considered as a valuable sustainable source of biobased materials. By applying specific pretreatments and manufacturing methods, it has been found that lignin can be converted into a variety of value-added carbon materials. However, the physical and chemical heterogeneities of lignin complicate its use as a feedstock. Herein, we discuss the lignin manufacturing process, the effects of pretreatments and manufacturing methods on the properties of product lignin, and structure–property relationships in various applications of lignin-derived carbon materials, such as carbon fibers, carbon mats, activated carbons, carbon films, and templated carbon.

  4. ENERGY DERIVATIVES FOR CONFIGURATION INTERACTION WAVEFUNCTIONS

    SciTech Connect (OSTI)

    Dupuis, M.

    1980-09-01

    Equations providing the first and second derivatives of a configuration interaction (CI) energy with respect to an external parameter are provided. We assume no restriction on the form of the CI expansion built from molecular orbitals obtained in a multiconfiguration Hartree-Fock (MCHF) calculation. Also the coupled perturbed multi-configuration Hartree-Fock formalism is presented for a general MCHF wavefunction and provides the first order and second order changes of the molecular orbital expansion coefficients with respect to an external parameter.

  5. Primer on electricity futures and other derivatives

    SciTech Connect (OSTI)

    Stoft, S.; Belden, T.; Goldman, C.; Pickle, S.

    1998-01-01

    Increased competition in bulk power and retail electricity markets is likely to lower electricity prices, but will also result in greater price volatility as the industry moves away from administratively determined, cost-based rates and encourages market-driven prices. Price volatility introduces new risks for generators, consumers, and marketers. Electricity futures and other derivatives can help each of these market participants manage, or hedge, price risks in a competitive electricity market. Futures contracts are legally binding and negotiable contracts that call for the future delivery of a commodity. In most cases, physical delivery does not take place, and the futures contract is closed by buying or selling a futures contract on or near the delivery date. Other electric rate derivatives include options, price swaps, basis swaps, and forward contracts. This report is intended as a primer for public utility commissioners and their staff on futures and other financial instruments used to manage price risks. The report also explores some of the difficult choices facing regulators as they attempt to develop policies in this area.

  6. Waste Segregation Based on Derived Clearance Levels

    SciTech Connect (OSTI)

    Garisto, N.C.; Parhizgari, Z.

    2008-07-01

    This paper describes the methodology and results of a radiological modeling in support of an application to release very low level radiologically contaminated waste from regulatory control and allow its haulage and disposal in a hazardous waste landfill. The Canadian regulatory body responsible for licensing operations involving nuclear materials (the Canadian Nuclear Safety Commission), has not yet formally defined clearance levels for free release of low level radiologically contaminated waste. The IAEA clearance levels have been derived for certain situations and receptor characteristics, which might be too conservative for an actual case. A site-specific pathways analysis was therefore completed to define conditional clearance levels using the concept of de minimis dose limit. Derived Conditional Clearance Levels were calculated for each radionuclide based on the maximally exposed hypothetical individuals to determine whether each waste stream can be 'cleared' from regulatory controls. The results showed that haulage of the waste from the station to the haulage/processing facility and transportation of waste or sludge from the haulage/processing facility to the disposal facility, handling of the waste or sludge at the haulage/processing facility, and incineration and/or disposal of waste or sludge at the disposal facility would not expose the workers to doses above 0.1 {mu}Sv/yr., which is less than the de minimis dose limit of 10 {mu}Sv/yr. (authors)

  7. Lignin-Derived Advanced Carbon Materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chatterjee, Sabornie; Saito, Tomonori

    2015-11-16

    Lignin is a highly abundant source of renewable carbon that can be considered as a valuable sustainable source of biobased materials. By applying specific pretreatments and manufacturing methods, it has been found that lignin can be converted into a variety of value-added carbon materials. However, the physical and chemical heterogeneities of lignin complicate its use as a feedstock. Herein, we discuss the lignin manufacturing process, the effects of pretreatments and manufacturing methods on the properties of product lignin, and structure–property relationships in various applications of lignin-derived carbon materials, such as carbon fibers, carbon mats, activated carbons, carbon films, and templatedmore » carbon.« less

  8. Hydrogen Production: Biomass-Derived Liquid Reforming | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Biomass-Derived Liquid Reforming Hydrogen Production: Biomass-Derived Liquid Reforming Photo of cylindrical reactor vessel and associated piping and equipment in the Thermochemical Process Development Unit at NREL Liquids derived from biomass resources-including ethanol and bio-oils-can be reformed to produce hydrogen in a process similar to natural gas reforming. Biomass-derived liquids can be transported more easily than their biomass feedstocks, allowing for semi-central

  9. Bio-Derived Liquid Distributed Reforming Outcomes Map | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Liquid Distributed Reforming Outcomes Map Bio-Derived Liquid Distributed Reforming Outcomes Map This is a "pre-decisional draft of the Bio-Derived Liquid Distributed Reforming Outcomes Map. biliwg06_schlasner.pdf (36.88 KB) More Documents & Publications Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review Distributed Reforming of Biomass Pyrolysis Oils (Presentation) Bio-Derived Liquids to

  10. Biomass Derivatives Competitive with Heating Oil Costs. | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Derivatives Competitive with Heating Oil Costs. Biomass Derivatives Competitive with Heating Oil Costs. Presentation at the May 9, 2012, Pyrolysis Oil Workship on biomass derivatives competitive with heating oil costs. pyrolysis_levine.pdf (733.32 KB) More Documents & Publications Challenge # 1. Feedstock & Production Thermochemical Conversion Proceeses to Aviation Fuels A Review of DOE Biofuels Program

  11. Jet flames of a refuse derived fuel

    SciTech Connect (OSTI)

    Weber, Roman; Kupka, Tomasz; Zajac, Krzysztof

    2009-04-15

    This paper is concerned with combustion of a refuse derived fuel in a small-scale flame. The objective is to provide a direct comparison of the RDF flame properties with properties of pulverized coal flames fired under similar boundary conditions. Measurements of temperature, gas composition (O{sub 2}, CO{sub 2}, CO, NO) and burnout have demonstrated fundamental differences between the coal flames and the RDF flames. The pulverized coals ignite in the close vicinity of the burner and most of the combustion is completed within the first 300 ms. Despite the high volatile content of the RDF, its combustion extends far into the furnace and after 1.8 s residence time only a 94% burnout has been achieved. This effect has been attributed not only to the larger particle size of fluffy RDF particles but also to differences in RDF volatiles if compared to coal volatiles. Substantial amounts of oily tars have been observed in the RDF flames even though the flame temperatures exceeded 1300 C. The presence of these tars has enhanced the slagging propensity of RDF flames and rapidly growing deposits of high carbon content have been observed. (author)

  12. Derivation of dose conversion factors for tritium

    SciTech Connect (OSTI)

    Killough, G. G.

    1982-03-01

    For a given intake mode (ingestion, inhalation, absorption through the skin), a dose conversion factor (DCF) is the committed dose equivalent to a specified organ of an individual per unit intake of a radionuclide. One also may consider the effective dose commitment per unit intake, which is a weighted average of organ-specific DCFs, with weights proportional to risks associated with stochastic radiation-induced fatal health effects, as defined by Publication 26 of the International Commission on Radiological Protection (ICRP). This report derives and tabulates organ-specific dose conversion factors and the effective dose commitment per unit intake of tritium. These factors are based on a steady-state model of hydrogen in the tissues of ICRP's Reference Man (ICRP Publication 23) and equilibrium of specific activities between body water and other tissues. The results differ by 27 to 33% from the estimate on which ICRP Publication 30 recommendations are based. The report also examines a dynamic model of tritium retention in body water, mineral bone, and two compartments representing organically-bound hydrogen. This model is compared with data from human subjects who were observed for extended periods. The manner of combining the dose conversion factors with measured or model-predicted levels of contamination in man's exposure media (air, drinking water, soil moisture) to estimate dose rate to an individual is briefly discussed.

  13. Nanoscale Reinforced, Polymer Derived Ceramic Matrix Coatings

    SciTech Connect (OSTI)

    Rajendra Bordia

    2009-07-31

    The goal of this project was to explore and develop a novel class of nanoscale reinforced ceramic coatings for high temperature (600-1000 C) corrosion protection of metallic components in a coal-fired environment. It was focused on developing coatings that are easy to process and low cost. The approach was to use high-yield preceramic polymers loaded with nano-size fillers. The complex interplay of the particles in the polymer, their role in controlling shrinkage and phase evolution during thermal treatment, resulting densification and microstructural evolution, mechanical properties and effectiveness as corrosion protection coatings were investigated. Fe-and Ni-based alloys currently used in coal-fired environments do not possess the requisite corrosion and oxidation resistance for next generation of advanced power systems. One example of this is the power plants that use ultra supercritical steam as the working fluid. The increase in thermal efficiency of the plant and decrease in pollutant emissions are only possible by changing the properties of steam from supercritical to ultra supercritical. However, the conditions, 650 C and 34.5 MPa, are too severe and result in higher rate of corrosion due to higher metal temperatures. Coating the metallic components with ceramics that are resistant to corrosion, oxidation and erosion, is an economical and immediate solution to this problem. Good high temperature corrosion protection ceramic coatings for metallic structures must have a set of properties that are difficult to achieve using established processing techniques. The required properties include ease of coating complex shapes, low processing temperatures, thermal expansion match with metallic structures and good mechanical and chemical properties. Nanoscale reinforced composite coatings in which the matrix is derived from preceramic polymers have the potential to meet these requirements. The research was focused on developing suitable material systems and

  14. Methods for deoxygenating biomass-derived pyrolysis oil

    DOE Patents [OSTI]

    Brandvold, Timothy A.

    2015-07-14

    Methods for deoxygenating a biomass-derived pyrolysis oil are provided. A method comprising the steps of diluting the biomass-derived pyrolysis oil with a phenolic-containing diluent to form a diluted pyoil-phenolic feed is provided. The diluted pyoil-phenolic feed is contacted with a deoxygenating catalyst in the presence of hydrogen at hydroprocessing conditions effective to form a low-oxygen biomass-derived pyrolysis oil effluent.

  15. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets (Presentation)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Distributed Reforming Targets Arlene F. Anderson Technology Development Manager, U.S. DOE Office of Energy Efficiency and Renewable Energy Hydrogen, Fuel Cells and Infrastructure Technologies Program Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group and Hydrogen Production Technical Team Review November 6, 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) The Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), launched

  16. Methods for deoxygenating biomass-derived pyrolysis oil

    SciTech Connect (OSTI)

    Baird, Lance Awender; Brandvold, Timothy A.

    2015-06-30

    Methods for deoxygenating a biomass-derived pyrolysis oil are provided. A method for deoxygenating a biomass-derived pyrolysis oil comprising the steps of combining a biomass-derived pyrolysis oil stream with a heated low-oxygen-pyoil diluent recycle stream to form a heated diluted pyoil feed stream is provided. The heated diluted pyoil feed stream has a feed temperature of about 150.degree. C. or greater. The heated diluted pyoil feed stream is contacted with a first deoxygenating catalyst in the presence of hydrogen at first hydroprocessing conditions effective to form a low-oxygen biomass-derived pyrolysis oil effluent.

  17. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  18. DOE Technical Targets for Hydrogen Production from Biomass-Derived...

    Office of Environmental Management (EM)

    for Hydrogen Production from Biomass-Derived Liquid Reforming These tables list the U.S. Department of Energy (DOE) technical targets and example cost contributions for hydrogen ...

  19. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 07anlhighpressuresteamethanolref...

  20. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Broader source: Energy.gov (indexed) [DOE]

    The Working Group is addressing technical challenges to distributed reforming of biomass-derived, renewable liquid fuels to hydrogen, including the reforming, water-gas shift, and ...

  1. Manufacturing Consumption of Energy 1994 - Derived measures of...

    U.S. Energy Information Administration (EIA) Indexed Site

    eialogo Calculation of MECS Energy Measures Reported energy values were used to construct several derived values, which, in turn, were used to prepare the estimates appearing in...

  2. A Comparison of Cirrus Cloud Visible Optical Depth Derived from...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Comparison of Cirrus Cloud Visible Optical Depth Derived from Lidar Lo, Chaomei Pacific Northwest National Laboratory Comstock, Jennifer Pacific Northwest National Laboratory...

  3. Hybrid-state emission in a polythienylenevinylene derivative...

    Office of Scientific and Technical Information (OSTI)

    poly(3-thienylenevinylene) derivative (imidePTV) was studied in film and solution. ... Resource Type: Journal Article Resource Relation: Journal Name: Journal of Chemical Physics; ...

  4. A comparison of cloudiness measures derived from longwave measurements...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A comparison of cloudiness measures derived from longwave measurements and shortwave sky imagers Takara, Ezra Florida State University Ellingson, Robert Florida State University...

  5. Derivative-free optimization for parameter estimation in computational...

    Office of Scientific and Technical Information (OSTI)

    nuclear physics Citation Details In-Document Search Title: Derivative-free optimization for parameter estimation in computational nuclear physics Authors: Wild, S ; ...

  6. Cost Analysis of Bio-Derived Liquids Reforming (Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost Analysis of Bio-Derived Liquids Reforming Brian James Directed Technologies, Inc. 6 November 2007 This presentation does not contain any proprietary, confidential, or ...

  7. Derivative-free optimization for parameter estimation in computational...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Derivative-free optimization for parameter estimation in computational nuclear physics Citation Details ... RADIATION PHYSICS; 97 MATHEMATICS, COMPUTING, AND ...

  8. MISR-Derived Statistics of Cumulus Geometry at TWP Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... We found that the satellite-derived basic statistics are similar to those from ... New directions in earth observing: Scientific applications of multi-angle remote sensing. ...

  9. Agenda for the Derived Liquids to Hydrogen Distributed Reforming...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Production Technical Team Research Review This is the agenda for the ... More Documents & Publications Meeting Action Items and Highlights from the Bio-Derived ...

  10. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets

    Broader source: Energy.gov [DOE]

    Presentation by Arlene Anderson at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  11. Production of Chemical Derivatives from Renewables

    SciTech Connect (OSTI)

    Davison, Brian; Nghiem, John; Donnelly, Mark; Tsai, Shih-Perng; Frye, John; Landucci, Ron; Griffin, Michael

    1996-06-01

    The purpose of this Cooperative Research and Development Agreement (CRADA) between Lockheed Martin Energy Research Corp., (LMER), Argonne National Laboratory (ANL), National Renewable Energy Laboratory (NREL), and Battelle Memorial Institute, operator of Pacific Northwest National Laboratory (PNNL), (collectively referred to as the 'Contractor'), and Applied Carbochemicals, Inc. (Participant) was to scale-up from bench results an economically promising and competitive process for the production of chemical derivatives from biologically produced succinic acid. The products that were under consideration for production from the succinic acid platform included 1,4-butanediol, {gamma}y-butyrolactone, 2-pyrrolidinone and N-methyl pyrrolidinone. Preliminary economic analyses indicated that this platform was competitive with the most recent petrochemical routes. The Contractors and participant are hereinafter jointly referred to as the 'Parties.' Research to date in succinic acid fermentation, separation and genetic engineering resulted in a potentially economical process based on the use of an Escherichia coli strain AFP111 with suitable characteristics for the production of succinic acid from glucose. Economic analysis has shown that higher value commodity chemicals can be economically produced from succinic acid based on preliminary laboratory findings and predicted catalytic parameters. At the time, the current need was to provide the necessary laboratory follow-up information to properly optimize, design and operate a pilot scale process. The purpose of the pilot work was to validate the integrated process, assure 'robustness' of the process, define operating conditions, and provide samples for potential customer evaluation. The data from the pilot scale process was used in design and development of a full scale production facility. A new strain, AFP111 (patented), discovered at ANL was tested and developed for process use at the Oak Ridge National Laboratory (ORNL

  12. Fractional Hamiltonian analysis of higher order derivatives systems

    SciTech Connect (OSTI)

    Baleanu, Dumitru; Muslih, Sami I.; Tas, Kenan

    2006-10-15

    The fractional Hamiltonian analysis of 1+1 dimensional field theory is investigated and the fractional Ostrogradski's formulation is obtained. The fractional path integral of both simple harmonic oscillator with an acceleration-squares part and a damped oscillator are analyzed. The classical results are obtained when fractional derivatives are replaced with the integer order derivatives.

  13. NOVEL SLURRY PHASE DIESEL CATALYSTS FOR COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    Dr. Dragomir B. Bukur; Dr. Ketil Hanssen; Alec Klinghoffer; Dr. Lech Nowicki; Patricia O'Dowd; Dr. Hien Pham; Jian Xu

    2001-01-07

    This report describes research conducted to support the DOE program in novel slurry phase catalysts for converting coal-derived synthesis gas to diesel fuels. The primary objective of this research program is to develop attrition resistant catalysts that exhibit high activities for conversion of coal-derived syngas.

  14. ARM - PI Product - SCM Forcing Data Derived from NWP Analyses

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsSCM Forcing Data Derived from NWP Analyses ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : SCM Forcing Data Derived from NWP Analyses Forcing data, suitable for use with single column models (SCMs) and cloud resolving models (CRMs), have been derived from NWP analyses for the ARM (Atmospheric Radiation Measurement) Tropical Western Pacific (TWP) sites of Manus Island and Nauru. Data Details

  15. Sol-gel-derived Epitaxial Nanocomposite Thin Films with Large...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sol-gel-derived Epitaxial Nanocomposite Thin Films with Large Sharp Magnetoelectric Effect Home Author: B. Liu, T. Sun, J. He, V. P. Dravid Year: 2010 Abstract: Nanostructures of...

  16. Exited-state Dynamics of Water-Soluble Polythiophene Derivatives...

    Office of Scientific and Technical Information (OSTI)

    Dynamics of Water-Soluble Polythiophene Derivatives: Temperature and Side-chain Length Effects Citation Details In-Document Search Title: Exited-state Dynamics of Water-Soluble ...

  17. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 01doebio-derivedliquidstoh2refor...

  18. Agenda for the Derived Liquids to Hydrogen Distributed Reforming...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Anderson o H2A Overview, NREL, Darlene Steward o Bio-Derived Liquids to Hydrogen ... Bio-Oil Reforming, NREL, Darlene Steward o High Pressure Steam Ethanol Reforming, ...

  19. Novel Biosynthetic Pathway for Production of Fatty Acid Derived...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fatty acids and fatty acid derived compounds are secreted from a host cell, such as E. coli. The host cell can be modified to increase fatty acid production or export the desired...

  20. Cost Analysis of Bio-Derived Liquids Reforming (Presentation)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost Analysis of Bio-Derived Liquids Reforming Brian James Directed Technologies, Inc. 6 November 2007 This presentation does not contain any proprietary, confidential, or otherwise restricted information Objective * Assess cost of H 2 from bio-derived liquids * Looking at forecourt scale systems: 100-1500kg/day * Emphasis on Ethanol * Looking at both "conventional" and "advanced" systems * Interaction with the Researchers is bi-directional * Researchers help me with

  1. Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Group (BILIWG) Hydrogen Production Technical Team Research Review | Department of Energy Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review This is the agenda for the working group sessions held in Laurel, Maryland on November 6, 2007. biliwg_agenda.pdf (145.59 KB) More Documents

  2. Higher derivative couplings in theories with sixteen supersymmetries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Ying -Hsuan; Shao, Shu -Heng; Yin, Xi; Wang, Yifan

    2015-12-15

    We give simple arguments for new non-renormalization theorems on higher derivative couplings of gauge theories to supergravity, with sixteen supersymmetries, by considerations of brane-bulk superamplitudes. This leads to some exact results on the effective coupling of D3-branes in type IIB string theory. As a result, we also derive exact results on higher dimensional operators in the torus compactification of the six dimensional (0, 2) superconformal theory.

  3. Project Profile: Polyaromatic Naphthalene Derivatives as Solar Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transfer Fluids | Department of Energy Polyaromatic Naphthalene Derivatives as Solar Heat Transfer Fluids Project Profile: Polyaromatic Naphthalene Derivatives as Solar Heat Transfer Fluids Oak Ridge National Laboratory logo Oak Ridge National Laboratory, under an ARRA CSP Award, is addressing the need for heat transfer fluids (HTFs) for solar power generation that are stable to temperatures approaching 600°C, have good thermal characteristics, and do not react with the vessels in which

  4. Catalysts for Syngas-Derived Alcohol Synthesis - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Catalysts for Syngas-Derived Alcohol Synthesis Improves the conversion of syngas from natural gas, coal, or biomass National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication Pyrochlore-Based Catalysts for Syngas-Derived Alcohol Synthesis (294 KB) Technology Marketing Summary This technology provides an advantageous means to

  5. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group The Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), launched in October 2006, provides a forum for effective communication and collaboration among participants in DOE Fuel Cell Technologies Office (FCT) cost-shared research directed at distributed bio-liquid reforming. The Working Group includes individuals from DOE, the national laboratories, industry, and academia.

  6. Phenylnaphthalene Derivatives as Heat Transfer Fluids for Concentrating

    Office of Scientific and Technical Information (OSTI)

    Solar Power: Loop Experiments and Final Report (Technical Report) | SciTech Connect Technical Report: Phenylnaphthalene Derivatives as Heat Transfer Fluids for Concentrating Solar Power: Loop Experiments and Final Report Citation Details In-Document Search Title: Phenylnaphthalene Derivatives as Heat Transfer Fluids for Concentrating Solar Power: Loop Experiments and Final Report ORNL and subcontractor Cool Energy completed an investigation of higher-temperature, organic thermal fluids for

  7. Cloud properties derived from the High Spectral Resolution Lidar during

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MPACE Cloud properties derived from the High Spectral Resolution Lidar during MPACE Eloranta, Edwin University of Wisconsin Category: Field Campaigns Cloud properties were derived from data acquired with University of Wisconsin High Spectral Resolution Lidar during its 6-week MPACE deployment. This poster presents statistics on: 1) the altitude and temperature distribution of optical depth and cloud phase. 2) the dependence of lidar depolarization and backscatter phase function on

  8. Literature survey of properties of synfuels derived from coal

    SciTech Connect (OSTI)

    Flores, F.

    1982-08-01

    This report contains the results of a literature survey conducted by NASA Lewis Research Center. The survey objective was to systematically assemble existing data on the physical, chemical, and elemental composition and structural characteristics of synthetic fuels (liquids and gases) derived from coal. The report contains the survey results compiled to October 1980. The report includes the following: (1) a general description of fuel properties, with emphasis on those properties required for synfuels to be used in gas-turbine systems for industry and utilities; (2) description of the four major concepts for converting coal into liquid fuels (pyrolysis, solvent extraction, catalytic liquefaction and indirect liquefaction); (3) data obtained from the literature on full range syncrudes and certain distillate cuts for fuels derived by various processes; (4) description of upgrading processes for coal liquids and characterization data for upgraded fuels; (5) data plots illustrating trends in the properties of fuels derived by several processes; (6) description of the most important concepts in coal gasification (fixed bed, fluidized bed, entrained flow and underground gasification) and characterization data for coal-derived gases; (7) a source list and bibliography on syncrude production and upgrading programs; and (8) a listing of some Federal energy contracts for coal-derived synthetic fuels production.

  9. Methods and apparatuses for deoxygenating biomass-derived pyrolysis oil

    DOE Patents [OSTI]

    Baird, Lance Awender; Brandvold, Timothy A.

    2015-10-20

    Embodiments of methods and apparatuses for deoxygenating a biomass-derived pyrolysis oil are provided. In one example, a method comprises the steps of separating a low-oxygen biomass-derived pyrolysis oil effluent into a low-oxygen-pyoil organic phase stream and an aqueous phase stream. Phenolic compounds are removed from the aqueous phase stream to form a phenolic-rich diluent recycle stream. A biomass-derived pyrolysis oil stream is diluted and heated with the phenolic-rich diluent recycle stream to form a heated diluted pyoil feed stream. The heated diluted pyoil feed stream is contacted with a deoxygenating catalyst in the presence of hydrogen to deoxygenate the heated diluted pyoil feed stream.

  10. Non-minimal derivative couplings of the composite metric

    SciTech Connect (OSTI)

    Heisenberg, Lavinia

    2015-11-04

    In the context of massive gravity, bi-gravity and multi-gravity non-minimal matter couplings via a specific composite effective metric were investigated recently. Even if these couplings generically reintroduce the Boulware-Deser ghost, this composite metric is unique in the sense that the ghost reemerges only beyond the decoupling limit and the matter quantum loop corrections do not detune the potential interactions. We consider non-minimal derivative couplings of the composite metric to matter fields for a specific subclass of Horndeski scalar-tensor interactions. We first explore these couplings in the mini-superspace and investigate in which scenario the ghost remains absent. We further study these non-minimal derivative couplings in the decoupling-limit of the theory and show that the equation of motion for the helicity-0 mode remains second order in derivatives. Finally, we discuss preliminary implications for cosmology.

  11. SYNTHESIS OF METHACRYLATES FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    Jang, B.W.L.; Spivey, J.J.; Gogate, M.R.; Zoeller, J.R.; Colberg, R.D.; Choi, G.N.

    1999-12-01

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel have developed a novel process for synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the US Department of Energy/Fossil Energy Technology Center (DOE/FETC). This project has resulted in five US patents (four already published and one pending publication). It has served as the basis for the technical and economic assessment of the production of this high-volume intermediate from coal-derived synthesis gas. The three-step process consists of the synthesis of a propionate from ethylene carbonylation using coal-derived CO, condensation of the propionate with formaldehyde to form methacrylic acid (MAA); and esterification of MAA with methanol to yield MMA. The first two steps, propionate synthesis and condensation catalysis, are the key technical challenges and the focus of the research presented here.

  12. Derivative expansion at small mass for the spinor effective action

    SciTech Connect (OSTI)

    Dunne, Gerald V.; Huet, Adolfo; Hur, Jin; Min, Hyunsoo

    2011-05-15

    We study the small-mass limit of the one-loop spinor effective action, comparing the derivative expansion approximation with exact numerical results that are obtained from an extension to spinor theories of the partial-wave cutoff method. In this approach, one can compute numerically the renormalized one-loop effective action for radially separable gauge field background fields in spinor QED. We highlight an important difference between the small-mass limit of the derivative expansion for spinor and scalar theories.

  13. Stabilization of linear higher derivative gravity with constraints

    SciTech Connect (OSTI)

    Chen, Tai-jun; Lim, Eugene A. E-mail: eugene.a.lim@gmail.com

    2014-05-01

    We show that the instabilities of higher derivative gravity models with quadratic curvature invariant ?R{sup 2}+?R{sub ??}R{sup ??} can be removed by judicious addition of constraints at the quadratic level of metric fluctuations around Minkowski/de Sitter background. With a suitable parameter choice, we find that the instabilities of helicity-0, 1, 2 modes can be removed while reducing the dimensionality of the original phase space. To retain the renormalization properties of higher derivative gravity, Lorentz symmetry in the constrained theory is explicitly broken.

  14. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  15. Financial derivative pricing under probability operator via Esscher transfomation

    SciTech Connect (OSTI)

    Achi, Godswill U.

    2014-10-24

    The problem of pricing contingent claims has been extensively studied for non-Gaussian models, and in particular, Black- Scholes formula has been derived for the NIG asset pricing model. This approach was first developed in insurance pricing{sup 9} where the original distortion function was defined in terms of the normal distribution. This approach was later studied6 where they compared the standard Black-Scholes contingent pricing and distortion based contingent pricing. So, in this paper, we aim at using distortion operators by Cauchy distribution under a simple transformation to price contingent claim. We also show that we can recuperate the Black-Sholes formula using the distribution. Similarly, in a financial market in which the asset price represented by a stochastic differential equation with respect to Brownian Motion, the price mechanism based on characteristic Esscher measure can generate approximate arbitrage free financial derivative prices. The price representation derived involves probability Esscher measure and Esscher Martingale measure and under a new complex valued measure φ (u) evaluated at the characteristic exponents φ{sub x}(u) of X{sub t} we recuperate the Black-Scholes formula for financial derivative prices.

  16. Radiohalogenated thienylethylamine derivatives for evaluating local cerebral blood flow

    DOE Patents [OSTI]

    Goodman, Mark M.; Knapp, Jr., Furn F.

    1990-01-01

    Radiopharmaceuticals useful in brain imaging comprising radiohalogenated thienylethylamine derivatives. The compounds are 5-halo-thiophene-2-isopropyl amines able to cross the blood-brain barrier and be retained for a sufficient length of time to allow the evaluation or regional blood flow by radioimaging of the brain.

  17. Synthesis and characterization of interfacially polymerized films of tetraphenylporphyrin derivatives

    SciTech Connect (OSTI)

    Li, W.; Wamser, C.C.

    1995-10-01

    Thin films of polymeric porphyrins have been made by interfacial polymerization of derivatives of tetraphenyl porphyrins, in particular by condensation of a dichloromethane solution of the acid chloride derivative (TCCPP) with a buffered aqueous solution of either the amine derivative (TAPP) or the phenol derivative (THPP). Spectroscopic and other studies are consistent with cross-linked polyamide or polyester network structures. The polyamide and polyester films display a novel asymmetry of functional groups on opposite sides of the film; excess amine (or hydroxyl) groups appear on one side of the film and excess carboxyl groups on the other. Film thickness can be correlated with the intensity of the UV-visible absorption spectrum, x (in nm) = 120 A{sub max} (at the Soret peak), with typical thicknesses in the range 10-500 nm, easily controlled by reaction time and conditions. Significantly thicker films (up to several {mu}m) can be prepared using an aliphatic diamine orpolyamine as the comonomer with TCCPP. Addition of 2, 6-lutidine to the organic phase substantially increases the rate of polymerization, which is especially useful for TAPP reactions. In addition, control experiments show that TCCPP with lutidine in CH{sub 2}Cl{sub 2} reacts at the interface with an aqueous pH 3 buffer, giving a very thin, easily hydrolyzed film, apparently due to anhydride linkages formed by condensation reactions with partially hydrolyzed TCCPP. 56 refs., 11 figs., 4 tabs.

  18. Triamines and their derivatives as bifunctional chelating agents

    DOE Patents [OSTI]

    Troutner, D.E.; John, C.S.; Pillai, M.R.A.

    1992-03-31

    A group of functionalized triamine chelants and their derivatives that form complexes with radioactive metal ions are disclosed. The complexes can be covalently attached to a protein or an antibody or antibody fragment and used for therapeutic and/or diagnostic purposes. No Drawings

  19. Producing Transportation Fuels via Photosynthetically-derived Ethylene

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3, 2015 Technology Area Review: Algae Principal Investigator: Jianping Yu DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Producing Transportation Fuels via Photosynthetically- derived Ethylene This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement To develop a novel photosynthetic ethylene production technology using cyanobacteria. This technology has potential to produce biofuels and green chemicals (1) at cost

  20. Triamines and their derivatives as bifunctional chelating agents

    DOE Patents [OSTI]

    Troutner, David E.; John, Christy S.; Pillai, Maroor R. A.

    1992-03-31

    A group of functionalized triamine chelants and their derivatives that form complexes with radioactive metal ions are disclosed. The complexes can be covalently attached to a protein or an antibody or antibody fragment and used for therapeutic and/or diagnostic purposes.

  1. Probing the Active Surface Sites for CO Reduction on Oxide-Derived...

    Office of Scientific and Technical Information (OSTI)

    on Oxide-Derived Copper Electrocatalysts Citation Details In-Document Search Title: Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts ...

  2. Cosmological perturbations in non-local higher-derivative gravity

    SciTech Connect (OSTI)

    Craps, Ben; Jonckheere, Tim De; Koshelev, Alexey S. E-mail: Tim.De.Jonckheere@vub.ac.be

    2014-11-01

    We study cosmological perturbations in a non-local higher-derivative model of gravity introduced by Biswas, Mazumdar and Siegel. We extend previous work, which had focused on classical scalar perturbations around a cosine hyperbolic bounce solution, in three ways. First, we point out the existence of a Starobinsky solution in this model, which is more attractive from a phenomenological point of view (even though it has no bounce). Second, we study classical vector and tensor pertuxsxrbations. Third, we show how to quantize scalar and tensor perturbations in a de Sitter phase (for choices of parameters such that the model is ghost-free). Our results show that the model is well-behaved at this level, and are very similar to corresponding results in local f(R) models. In particular, for the Starobinsky solution of non-local higher-derivative gravity, we find the same tensor-to-scalar ratio as for the conventional Starobinsky model.

  3. Deriving cleanup guidelines for radionuclides at Brookhaven National Laboratory

    SciTech Connect (OSTI)

    Meinhold, A.F.; Morris, S.C.; Dionne, B.; Moskowitz, P.D.

    1997-01-01

    Past activities at Brookhaven National Laboratory (BNL) resulted in soil and groundwater contamination. As a result, BNL was designated a Superfund site under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). BNL`s Office of Environmental Restoration (OER) is overseeing environmental restoration activities at the Laboratory. With the exception of radium, there are no regulations or guidelines to establish cleanup guidelines for radionuclides in soils at BNL. BNL must derive radionuclide soil cleanup guidelines for a number of Operable Units (OUs) and Areas of Concern (AOCs). These guidelines are required by DOE under a proposed regulation for radiation protection of public health and the environment as well as to satisfy the requirements of CERCLA. The objective of this report is to propose a standard approach to deriving risk-based cleanup guidelines for radionuclides in soil at BNL. Implementation of the approach is briefly discussed.

  4. Apparatuses and methods for deoxygenating biomass-derived pyrolysis oil

    SciTech Connect (OSTI)

    Kalnes, Tom N.

    2015-12-29

    Apparatuses and methods for deoxygenating a biomass-derived pyrolysis oil are provided herein. In one example, the method comprises of dividing a feedstock stream into first and second feedstock portions. The feedstock stream comprises the biomass-derived pyrolysis oil and has a temperature of about 60.degree. C. or less. The first feedstock portion is combined with a heated organic liquid stream to form a first heated diluted pyoil feed stream. The first heated diluted pyoil feed stream is contacted with a first deoxygenating catalyst in the presence of hydrogen to form an intermediate low-oxygen pyoil effluent. The second feedstock portion is combined with the intermediate low-oxygen pyoil effluent to form a second heated diluted pyoil feed stream. The second heated diluted pyoil feed stream is contacted with a second deoxygenating catalyst in the presence of hydrogen to form additional low-oxygen pyoil effluent.

  5. In situ electrochemical dilatometry of carbide-derived carbons

    SciTech Connect (OSTI)

    Hantel, M M; Presser, Volker; Gogotsi, Yury

    2011-01-01

    The long life durability and extraordinary stability of supercapacitors are ascribed to the common concept that the charge storage is purely based on double-layer charging. Therefore the ideal supercapacitor electrode should be free of charge induced microscopic structural changes. However, recent in-situ investigations on different carbon materials for supercapacitor electrodes have shown that the charge and discharge is accompanied by dimensional changes of the electrode up to several percent. This work studies the influence of the pore size on the expansion behavior of carbon electrodes derived from titanium carbide-derived carbons with an average pore size between 5 and 8 Using tetraethylammonium tetrafluoroborate in acetonitrile, the swelling of the electrodes was measured by in situ dilatometry. The experiments revealed an increased expansion on the negatively charged electrode for pores below 6 , which could be described with pore swelling.

  6. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team | Department of Energy Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team 2007 Annual and Merit Review Reports compiled for the

  7. Massive graviton on arbitrary background: derivation, syzygies, applications

    SciTech Connect (OSTI)

    Bernard, Laura; Deffayet, Cédric; Strauss, Mikael von

    2015-06-23

    We give the detailed derivation of the fully covariant form of the quadratic action and the derived linear equations of motion for a massive graviton in an arbitrary background metric (which were presented in arXiv:1410.8302 [hep-th]). Our starting point is the de Rham-Gabadadze-Tolley (dRGT) family of ghost free massive gravities and using a simple model of this family, we are able to express this action and these equations of motion in terms of a single metric in which the graviton propagates, hence removing in particular the need for a “reference metric' which is present in the non perturbative formulation. We show further how 5 covariant constraints can be obtained including one which leads to the tracelessness of the graviton on flat space-time and removes the Boulware-Deser ghost. This last constraint involves powers and combinations of the curvature of the background metric. The 5 constraints are obtained for a background metric which is unconstrained, i.e. which does not have to obey the background field equations. We then apply these results to the case of Einstein space-times, where we show that the 5 constraints become trivial, and Friedmann-Lemaître-Robertson-Walker space-times, for which we correct in particular some results that appeared elsewhere. To reach our results, we derive several non trivial identities, syzygies, involving the graviton fields, its derivatives and the background metric curvature. These identities have their own interest. We also discover that there exist backgrounds for which the dRGT equations cannot be unambiguously linearized.

  8. GENERAL RELATIVITY DERIVATION OF BEAM REST-FRAME HAMILTONIAN.

    SciTech Connect (OSTI)

    WEI,J.

    2001-06-18

    Analysis of particle interaction in the laboratory frame of storage rings is often complicated by the fact that particle motion is relativistic, and that reference particle trajectory is curved. Rest frame of the reference particle is a convenient coordinate system to work with, within which particle motion is non-relativistic. We have derived the equations of motion in the beam rest frame from the general relativity formalism, and have successfully applied them to the analysis of crystalline beams [1].

  9. Heterogeneous Catalyst for Improved Selectivity of Biomass-Derived

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecules - Energy Innovation Portal Biomass and Biofuels Biomass and Biofuels Advanced Materials Advanced Materials Find More Like This Return to Search Heterogeneous Catalyst for Improved Selectivity of Biomass-Derived Molecules University of Colorado Contact CU About This Technology Publications: PDF Document Publication CU2380B (Heterogenous Catalyst) Marketing Summary (137 KB) Technology Marketing Summary In today's industrial processes, heterogeneous catalysts are widely used because

  10. High-Speed, Stereoselective Polymerization for Renewable, Bio-Derived

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plastics - Energy Innovation Portal Industrial Technologies Industrial Technologies Biomass and Biofuels Biomass and Biofuels Advanced Materials Advanced Materials Find More Like This Return to Search High-Speed, Stereoselective Polymerization for Renewable, Bio-Derived Plastics Colorado State University Contact CSU About This Technology Publications: PDF Document Publication Bioplastic Market Summary.pdf (263 KB) PDF Document Publication 12-008 12-035 csuv_ncs.pdf (272 KB) PDF Document

  11. METHOD FOR PRODUCING ISOTOPIC METHANES AND PARTIALLY HALOGENATED DERIVATIVES THEROF

    DOE Patents [OSTI]

    Frazer, J.W.

    1959-08-18

    A method is given for producing isotopic methanes and/ or partially halogenated derivatives. Lithium hydride, deuteride, or tritide is reacted with a halogenated methane or with a halogenated methane in combination with free halogen. The process is conveniently carried out by passing a halogenated methane preferably at low pressures or in an admixture with an inert gas through a fixed bed of finely divided lithium hydride heated initially to temperatures of 100 to 200 deg C depending upon the halogenated methane used.

  12. Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    William Eleazer, PE Brown and Caldwell Project Design Manager St. Petersburg, FL: Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids U.S Department of Energy - Biomass 2014 John Willis, PE, BCEE Brown and Caldwell Project Technical Supervisor Steven Marshall, PE St. Petersburg City Project Manager Eron Jacobson, PE Brown and Caldwell Gas Upgrade Systems Process Area Manager Project Summary Biogas to Recycled Natural Gas Technology Evaluation and Design Phase Future

  13. Radioisotope power system based on derivative of existing Stirling engine

    SciTech Connect (OSTI)

    Schock, A.; Or, C.T.; Kumar, V.

    1995-12-31

    In a recent paper, the authors presented the results of a system design study of a 75-watt(c) RSG (Radioisotope Stirling Generator) for possible application to the Pluto Fast Flyby mission. That study was based on a Stirling engine design generated by MTI (Mechanical Technology, Inc.). The MTI design was a derivative of a much larger (13 kwe) engine that they had developed and tested for NASA`s LERC. Clearly, such a derivative would be a major extrapolation (downsizing) from what has actually been built and tested. To avoid that, the present paper describes a design for a 75-watt RSG system based on derivatives of a small (11-watt) engine and linear alternator system that has been under development by STC (Stirling Technology Company) for over three years and that has operated successfully for over 15,000 hours as of March 1995. Thus, the STC engines would require much less extrapolation from proven designs. The design employs a heat source consisting of two standard General Purpose Heat Source (GPHS) modules, coupled to four Stirling engines with linear alternators, any three of which could deliver the desired 75-watt(e) output if the fourth should fail. The four engines are coupled to four common radiators with redundant heatpipes for rejecting the engines` waste heat to space. The above engine and radiator redundancies promote system reliability. The paper describes detailed analyses to determine the effect of radiator geometry on system mass and performance, before and after an engine or heatpipe failure.

  14. Evaluation of cement kiln laboratories testing hazardous waste derived fuels

    SciTech Connect (OSTI)

    Nichols, R.E.

    1998-12-31

    Cement kiln operators wishing to burn hazardous waste derived fuels in their kilns must submit applications for Resource Conservation Recovery Act permits. One component of each permit application is a site-specific Waste Analysis Plan. These Plans describe the facilities` sampling and analysis procedures for hazardous waste derived fuels prior to receipt and burn. The Environmental Protection Agency has conducted on-site evaluations of several cement kiln facilities that were under consideration for Resource Conservation Recovery Act permits. The purpose of these evaluations was to determine if the on-site sampling and laboratory operations at each facility complied with their site-specific Waste Analysis Plans. These evaluations covered sampling, laboratory, and recordkeeping procedures. Although all the evaluated facilities were generally competent, the results of those evaluations revealed opportunities for improvement at each facility. Many findings were noted for more than one facility. This paper will discuss these findings, particularly those shared by several facilities (specific facilities will not be identified). Among the findings to be discussed are the ways that oxygen bombs were scrubbed and rinsed, the analytical quality control used, Burn Tank sampling, and the analysis of pH in hazardous waste derived fuels.

  15. Rheological and structural studies of carboxymethyl derivatives of chitosan

    SciTech Connect (OSTI)

    Winstead, Cherese; Katagumpola, Pushpika

    2014-05-15

    The degrees of substitution of chitosan derivatives were varied and the viscoelastic behavior of these biopolymer solutions was studied using rheology. Chitosan is a cationic copolymer of glucosamine and N-acetylglucosamine obtained by alkaline deacetylation of chitin. Due to its inherent non-toxicity, biocompatibility, and biodegradability, chitosan has gained much interest. However, the poor solubility of the biopolymer in water and most common organic solvents limits its applications. Therefore, the focus of this work is the chemical modification of chitosan via carboxymethylation as well as studying the viscoelastic behavior of these polymer solutions. Varying degrees of substitution (DS) of carboxymethyl chitosan derivatives were synthesized by treating chitosan with monochloroacetic acid under alkylated medium varying the reaction time and temperature. The effect of degree of substitution on the rheology of these polymer solutions was studied as a function of concentration. The viscosity of chitosan derivatives sharply increased with increase in degree of substitution. G' and G' dependence on strain and angular frequency were studied and were found to exhibit predominantly viscous behavior. Additional characterization of the derivatized products were further studied using Fourier transform infrared (FT-IR), {sup 1}H Nuclear Magnetic Resonance ({sup 1}H NMR) spectroscopy, X-ray diffraction (XRD), and thermal gravimetric analysis as well as differential scanning calorimetry (DSC). Degree of substitution (DS) was calculated by titrimetric method.

  16. ARM: SIRS: derived, correction of downwelling shortwave diffuse hemispheric measurements using Dutton and full algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Laura Riihimaki

    1997-03-21

    SIRS: derived, correction of downwelling shortwave diffuse hemispheric measurements using Dutton and full algorithm

  17. Commercialization strategies for coal-derived transportation fuels

    SciTech Connect (OSTI)

    Tomlinson, G.; Gray, D.

    1992-12-31

    The objective of this paper is to analyze a program that can stimulate the development of a synthetic liquid transportation fuels from coal industry, by requiring that the products be bought at their true cost of production. These coal-derived liquids will then be assimulated into the nation`s fuel supply system. The cost of this program will be borne by increased cost of all fuels in the marketplace. The justification of the program is the assumption that, because of increasing demand, the world oil price (WOP) will increase to a level that will make coal-derived fuels economical in the relatively near future. However, as noted in the International Energy Outlook of 1990: ``Given current costs and Technologies, it is estimated the cost of crude oil would have to exceed $35 per barrel in 1989 dollars for at least four consecutive years for commercial production, in the range of 100,000 barrels per day, of synthetic liquids to occur. This delayed response of production to price increases reflects the planning and construction time required to complete a coal liquefaction plant``. This program is designed to reduce this time lag so that coal-derived fuels will be available when they are needed. This timely production capability of coal liquids may be able to limit future world oil prices to the actual cost of synthetic alternatives. In addition, the program is structured so that it will provide synthetic fuel producers with a cushion in the event that the WOP continues to remain low.

  18. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  19. Esterification of fermentation-derived acids via pervaporation

    DOE Patents [OSTI]

    Datta, R.; Tsai, S.P.

    1998-03-03

    A low temperature method for esterifying ammonium- and amine-containing salts is provided whereby the salt is reacted with an alcohol in the presence of heat and a catalyst and then subjected to a dehydration and deamination process using pervaporation. The invention also provides for a method for producing esters of fermentation derived, organic acid salt comprising first cleaving the salt into its cationic part and anionic part, mixing the anionic part with an alcohol to create a mixture; heating the mixture in the presence of a catalyst to create an ester; dehydrating the now heated mixture; and separating the ester from the now-dehydrated mixture. 2 figs.

  20. Esterification of fermentation-derived acids via pervaporation

    DOE Patents [OSTI]

    Datta, Rathin; Tsai, Shih-Perng

    1998-01-01

    A low temperature method for esterifying ammonium- and amine-containing salts is provided whereby the salt is reacted with an alcohol in the presence of heat and a catalyst and then subjected to a dehydration and deamination process using pervaporation. The invention also provides for a method for producing esters of fermentation derived, organic acid salt comprising first cleaving the salt into its cationic part and anionic part, mixing the anionic part with an alcohol to create a mixture; heating the mixture in the presence of a catalyst to create an ester; dehydrating the now heated mixture; and separating the ester from the now-dehydrated mixture.

  1. A new approach for deriving pseudovelocity logs from resistivity logs

    SciTech Connect (OSTI)

    Dos Santos, W.L.B.; Ulrych, T.J.; De Lima, O.A.L.

    1988-01-01

    This paper describes a method of generating pseudovelocity logs using measurements of electrical resistivity. A theoretical relation between electrical resistivity and transit time, which is applicable to a wide range of lithologies, has been developed. The application of this relation using a method which defines lithoresistivity zones as lithological intervals related to the same formation and showing small resistivity variations, has been tested in the Reconcavo sedimentary basin in Bahia, Brazil. A comparison of derived pseudovelocity logs with actual sonic logs for five wells shows the validity of the present approach.

  2. A fresh look at coal-derived liquid fuels

    SciTech Connect (OSTI)

    Paul, A.D.

    2009-01-15

    35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

  3. BHR equations re-derived with immiscible particle effects

    SciTech Connect (OSTI)

    Schwarzkopf, John Dennis; Horwitz, Jeremy A.

    2015-05-01

    Compressible and variable density turbulent flows with dispersed phase effects are found in many applications ranging from combustion to cloud formation. These types of flows are among the most challenging to simulate. While the exact equations governing a system of particles and fluid are known, computational resources limit the scale and detail that can be simulated in this type of problem. Therefore, a common method is to simulate averaged versions of the flow equations, which still capture salient physics and is relatively less computationally expensive. Besnard developed such a model for variable density miscible turbulence, where ensemble-averaging was applied to the flow equations to yield a set of filtered equations. Besnard further derived transport equations for the Reynolds stresses, the turbulent mass flux, and the density-specific volume covariance, to help close the filtered momentum and continuity equations. We re-derive the exact BHR closure equations which include integral terms owing to immiscible effects. Physical interpretations of the additional terms are proposed along with simple models. The goal of this work is to extend the BHR model to allow for the simulation of turbulent flows where an immiscible dispersed phase is non-trivially coupled with the carrier phase.

  4. Deriving stellar inclination of slow rotators using stellar activity

    SciTech Connect (OSTI)

    Dumusque, X.

    2014-12-01

    Stellar inclination is an important parameter for many astrophysical studies. Although different techniques allow us to estimate stellar inclination for fast rotators, it becomes much more difficult when stars are rotating slower than ?2-2.5 km s{sup 1}. By using the new activity simulation SOAP 2.0 which can reproduce the photometric and spectroscopic variations induced by stellar activity, we are able to fit observations of solar-type stars and derive their inclination. For HD 189733, we estimate the stellar inclination to be i=84{sub ?20}{sup +6} deg, which implies a star-planet obliquity of ?=4{sub ?4}{sup +18} considering previous measurements of the spin-orbit angle. For ? Cen B, we derive an inclination of i=45{sub ?19}{sup +9}, which implies that the rotational spin of the star is not aligned with the orbital spin of the ? Cen binary system. In addition, assuming that ? Cen Bb is aligned with its host star, no transit would occur. The inclination of ? Cen B can be measured using 40 radial-velocity measurements, which is remarkable given that the projected rotational velocity of the star is smaller than 1.15 km s{sup 1}.

  5. Storage lipid biosynthesis in microspore-derived Brassica napus embryos

    SciTech Connect (OSTI)

    Taylor, D.C.; Underhill, E.W.; Weber, N. ); Pomeroy, M.K. ); Edwards, L. )

    1989-04-01

    Erucic acid, a fatty acid which is confined to the neutral lipids in developing seed cotyledons or rape, was chosen as a marker to study triacylglycerol (TAG) biosynthesis in a Brassica napus L. cv Reston microspore-derived embryo culture system. Accumulation and changes in acyl composition of TAGs during embryogenesis strongly paralleled that observed during seed development. Homogenates of 29-day cultured embryos were examined for the ability to incorporate erucoyl moieties into storage lipids. In the presence of {sup 14}C erucoyl CoA and various acceptors, including glycerol-3-phosphate (G3P), {sup 14}C erucic acid was rapidly incorporated into the TAG fraction. However, in contrast to studies with {sup 14}C oleoyl CoA, there was no measurable radioactivity in any Kennedy Pathway intermediates or within membrane lipid components. Analysis of the radiolabelled TAG species suggested that erucoyl moieties were incorporated into the sn-3 position by a highly active diacylglyercol acyltransferase.

  6. Extracting metal ions with diphosphonic acid, or derivative thereof

    DOE Patents [OSTI]

    Horwitz, E.P.; Gatrone, R.C.; Nash, K.L.

    1994-07-26

    Thermodynamically-unstable complexing agents which are diphosphonic acids and diphosphonic acid derivatives (or sulfur containing analogs), like carboxyhydroxymethanediphosphonic acid and vinylidene-1,1-diphosphonic acid, are capable of complexing with metal ions, and especially metal ions in the II, III, IV, V and VI oxidation states, to form stable, water-soluble metal ion complexes in moderately alkaline to highly-acidic media. However, the complexing agents can be decomposed, under mild conditions, into non-organic compounds which, for many purposes are environmentally-nondamaging compounds thereby degrading the complex and releasing the metal ion for disposal or recovery. Uses for such complexing agents as well as methods for their manufacture are also described. 1 fig.

  7. Photolysis and radiant flash pyrolysis of coal-derived wastes

    SciTech Connect (OSTI)

    Worman, J.J.; Worman, J.J.; Hawthorne, S.B.; Sears, R.E.

    1986-01-01

    It is attractive to think that coal-derived wastes could be converted to useful fuels by irradiation with solar energy. This would eliminate energy-intensive steps in the processing of coal gasification condensate water as well as provide an inexpensive alternate source of energy. Environmental concerns for the distribution of contaminants from biosludge would be minimized. This paper demonstrates that coal gasification condensate water in the presence of photoconductors and varying wavelengths of light can produce useful fuels in addition to lowering the total organic carbon content. Biosludge obtained from the processing of the condensate water can be irradiated in the solid state with a high-intensity xenon flash to give fuel-type products as identified by GC/MS. 13 refs., 2 figs., 4 tabs.

  8. Ecological objectives can be achieved with wood-derived bioenergy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dale, Virginia H.; Kline, Keith L.; Marland, Gregg; Miner, Reid A.

    2015-08-01

    Renewable, biomass-based energy options can reduce the climate impacts of fossil fuels. However, calculating the effects of wood-derived bioenergy on greenhouse gases (GHGs), and thus on climate, is complicated (Miner et al. 2015). To clarify concerns and options about bioenergy, in November 2014, the US Environmental Protection Agency (EPA) produced a second draft of its Framework for Assessing Biogenic CO2 Emissions fromStationary Sources (http://1.usa.gov/1dikgHq), which considers the latest scientific information and input from stakeholders. Furthermore, the EPA is expected to make decisions soon about the use of woody biomass under the Clean Power Plan, which sets targets for carbon pollutionmore » from power plants.« less

  9. Ecological objectives can be achieved with wood-derived bioenergy

    SciTech Connect (OSTI)

    Dale, Virginia H.; Kline, Keith L.; Marland, Gregg; Miner, Reid A.

    2015-08-01

    Renewable, biomass-based energy options can reduce the climate impacts of fossil fuels. However, calculating the effects of wood-derived bioenergy on greenhouse gases (GHGs), and thus on climate, is complicated (Miner et al. 2015). To clarify concerns and options about bioenergy, in November 2014, the US Environmental Protection Agency (EPA) produced a second draft of its Framework for Assessing Biogenic CO2 Emissions fromStationary Sources (http://1.usa.gov/1dikgHq), which considers the latest scientific information and input from stakeholders. Furthermore, the EPA is expected to make decisions soon about the use of woody biomass under the Clean Power Plan, which sets targets for carbon pollution from power plants.

  10. Characterization of ?-carrageenan and its derivative based green polymer electrolytes

    SciTech Connect (OSTI)

    Jumaah, Fatihah Najirah; Mobaraka, Nadhratun Naiim; Ahmad, Azizan; Ramli, Nazaruddin [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor Darul Ehsan (Malaysia)

    2013-11-27

    The new types of green polymer electrolytes based on ?-carrageenan derivative have been prepared. ?-carrageenan act as precursor was reacted with monochloroacetic acid to produce carboxymethyl ?-carrageenan. The powders were characterized by Attenuated Total Reflection Fourier Transform infrared (ATR-FTIR) spectroscopy and {sup 1}H nuclear magnetic resonance (NMR) to confirm the substitution of targeted functional group in ?-carrageenan. The green polymer electrolyte based on ?-carrageenan and carboxymethyl ?-carrageenan was prepared by solution-casting technique. The films were characterized by electrochemical impedance spectroscopy to determine the ionic conductivity. The ionic conductivity ?-carrageenan film were higher than carboxymethyl ?-carrageenan which 4.87 10{sup ?6} S cm{sup ?1} and 2.19 10{sup ?8} S cm{sup ?1}, respectively.

  11. Combustion of refuse derived fuel in a fluidized bed

    SciTech Connect (OSTI)

    Piao, Guilin; Aono, Shigeru; Mori, Shigekatsu; Deguchi, Seiichi; Fujima, Yukihisa; Kondoh, Motohiro; Yamaguchi, Masataka

    1998-12-31

    Power generation from Refuse Derived Fuel (RDF) is an attractive utilization technology of municipal solid waste. To explain the behavior of RDF-fired fluidized bed incinerator, the commercial size RDF was continuously burnt in a 30 x 30 cm bubbling type fluidized-bed combustor. It was found that 12 kg/h of RDF feed rate was too high feed for this test unit and the Co level was higher than 500 ppm. However, 10 kg/h of RDF was a proper feed rate and the Co level was kept under 150 ppm. Secondary air injection and changing air ratio from the pipe grid were effective for the complete combustion of RDE. It was also found that HCl concentration in flue gas was controlled by the calcium component contained in RDF and its level was decreased with decreasing the combustor temperature.

  12. Extracting metal ions with diphosphonic acid, or derivative thereof

    DOE Patents [OSTI]

    Horwitz, Earl P.; Gatrone, Ralph C.; Nash, Kenneth L.

    1994-01-01

    Thermodynamically-unstable complexing agents which are diphosphonic acids and diphosphonic acid derivatives (or sulphur containing analogs), like carboxyhydroxymethanediphosphonic acid and vinylidene-1,1-diphosphonic acid, are capable of complexing with metal ions, and especially metal ions in the II, III, IV, V and VI oxidation states, to form stable, water-soluble metal ion complexes in moderately alkaline to highly-acidic media. However, the complexing agents can be decomposed, under mild conditions, into non-organic compounds which, for many purposes are environmentally-nondamaging compounds thereby degrading the complex and releasing the metal ion for disposal or recovery. Uses for such complexing agents as well as methods for their manufacture are also described.

  13. Antimicrobial nanomaterials derived from natural products—A review

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Ji; Vermerris, Wilfred

    2016-03-30

    Modern medicine has relied heavily on the availability of effective antibiotics to manage infections and enable invasive surgery. With the emergence of antibiotic-resistant bacteria, novel approaches are necessary to prevent the formation of biofilms on sensitive surfaces such as medical implants. Advances in nanotechnology have resulted in novel materials and the ability to create novel surface topographies. This review article provides an overview of advances in the fabrication of antimicrobial nanomaterials that are derived from biological polymers or that rely on the incorporation of natural compounds with antimicrobial activity in nanofibers made from synthetic materials. Furthermore, the availability of thesemore » novel materials will contribute to ensuring that the current level of medical care can be maintained as more bacteria are expected to develop resistance against existing antibiotics.« less

  14. Production of aligned microfibers and nanofibers and derived functional monoliths

    DOE Patents [OSTI]

    Hu, Michael Z.; DePaoli, David W.; Kuritz, Tanya; Omatete, Ogbemi

    2007-08-14

    The present invention comprises a method for producing microfibers and nanofibers and further fabricating derived solid monolithic materials having aligned uniform micro- or nanofibrils. A method for producing fibers ranging in diameter from micrometer-sized to nanometer-sized comprises the steps of producing an electric field and preparing a solid precipitative reaction media wherein the media comprises at least one chemical reactive precursor and a solvent having low electrical conductivity and wherein a solid precipitation reaction process for nucleation and growth of a solid phase occurs within the media. Then, subjecting the media to the electric field to induce in-situ growth of microfibers or nanofibers during the reaction process within the media causing precipitative growth of solid phase particles wherein the reaction conditions and reaction kinetics control the size, morphology and composition of the fibers. The fibers can then be wet pressed while under electric field into a solid monolith slab, dried and consolidated.

  15. Ecological objectives can be achieved with wood-derived bioenergy

    SciTech Connect (OSTI)

    Dale, Virginia H.; Kline, Keith L.; Marland, Gregg; Miner, Reid A.

    2015-08-01

    Renewable, biomass-based energy options can reduce the climate impacts of fossil fuels. However, calculating the effects of wood-derived bioenergy on greenhouse gases (GHGs), and thus on climate, is complicated (Miner et al. 2015). To clarify concerns and options about bioenergy, in November 2014, the US Environmental Protection Agency (EPA) produced a second draft of its Framework for Assessing Biogenic CO2 Emissions fromStationary Sources (http://1.usa.gov/1dikgHq), which considers the latest scientific information and input from stakeholders. In addition, the EPA is expected to make decisions soon about the use of woody biomass under the Clean Power Plan, which sets targets for carbon pollution from power plants.

  16. On consistent kinetic and derivative interactions for gravitons

    SciTech Connect (OSTI)

    Noller, Johannes

    2015-04-17

    The only known fully ghost-free and consistent Lorentz-invariant kinetic term for a graviton (or indeed for any spin-2 field) is the Einstein-Hilbert term. Here we propose and investigate a new candidate family of kinetic interactions and their extensions to derivative interactions involving several spin-2 fields. These new terms generically break diffeomorphism invariance(s) and as a result can lead to the propagation of 5 degrees of freedom for a single spin-2 field — analogous to ghost-free Massive Gravity. We discuss under what circumstances these new terms can be used to build healthy effective field theories and in the process establish the ‘Jordan’ and ‘Einstein’ frame pictures for Massive-, Bi- and Multi-Gravity.

  17. Membrane extraction with thermodynamically unstable diphosphonic acid derivatives

    DOE Patents [OSTI]

    Horwitz, E.P.; Gatrone, R.C.; Nash, K.L.

    1997-10-14

    Thermodynamically-unstable complexing agents which are diphosphonic acids and diphosphonic acid derivatives (or sulphur containing analogs), like carboxyhydroxymethanediphosphonic acid and vinylidene-1,1-diphosphonic acid, are capable of complexing with metal ions, and especially metal ions in the II, III, IV, V and VI oxidation states, to form stable, water-soluble metal ion complexes in moderately alkaline to highly-acidic media. However, the complexing agents can be decomposed, under mild conditions, into non-organic compounds which, for many purposes are environmentally-nondamaging compounds thereby degrading the complex and releasing the metal ion for disposal or recovery. Uses for such complexing agents as well as methods for their manufacture are also described. 1 fig.

  18. Membrane extraction with thermodynamically unstable diphosphonic acid derivatives

    DOE Patents [OSTI]

    Horwitz, Earl Philip; Gatrone, Ralph Carl; Nash, Kenneth LaVerne

    1997-01-01

    Thermodynamically-unstable complexing agents which are diphosphonic acids and diphosphonic acid derivatives (or sulphur containing analogs), like carboxyhydroxymethanediphosphonic acid and vinylidene-1,1-diphosphonic acid, are capable of complexing with metal ions, and especially metal ions in the II, III, IV, V and VI oxidation states, to form stable, water-soluble metal ion complexes in moderately alkaline to highly-acidic media. However, the complexing agents can be decomposed, under mild conditions, into non-organic compounds which, for many purposes are environmentally-nondamaging compounds thereby degrading the complex and releasing the metal ion for disposal or recovery. Uses for such complexing agents as well as methods for their manufacture are also described.

  19. SYNTHESIS OF METHYL METHACRYLATE FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    Makarand R. Gogate; James J. Spivey; Joseph R. Zoeller; Richard D. Colberg; Gerald N. Choi; Samuel S. Tam

    1999-04-21

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. The research team has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, we are currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last quarter (January-March/99), in-situ formaldehyde generation and condensation with methyl propionate were tested over various catalysts and reaction conditions. The patent application is in preparation and the results are retained for future reports.

  20. Pulse transmission transmitter including a higher order time derivate filter

    DOE Patents [OSTI]

    Dress, Jr., William B.; Smith, Stephen F.

    2003-09-23

    Systems and methods for pulse-transmission low-power communication modes are disclosed. A pulse transmission transmitter includes: a clock; a pseudorandom polynomial generator coupled to the clock, the pseudorandom polynomial generator having a polynomial load input; an exclusive-OR gate coupled to the pseudorandom polynomial generator, the exclusive-OR gate having a serial data input; a programmable delay circuit coupled to both the clock and the exclusive-OR gate; a pulse generator coupled to the programmable delay circuit; and a higher order time derivative filter coupled to the pulse generator. The systems and methods significantly reduce lower-frequency emissions from pulse transmission spread-spectrum communication modes, which reduces potentially harmful interference to existing radio frequency services and users and also simultaneously permit transmission of multiple data bits by utilizing specific pulse shapes.

  1. Co-conversion of Biomass, Shale-natural gas, and process-derived...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Co-conversion of Biomass, Shale-natural gas, and process-derived CO2 into Fuels and Chemicals Co-conversion of Biomass, Shale-natural gas, and process-derived CO2 into Fuels and ...

  2. Product evaluation of Fischer-Tropsch derived fuels

    SciTech Connect (OSTI)

    Marano, J.J.; Rogers, S.; Choi, G.N.; Kramer, S.J.

    1994-12-31

    The Clean Air Act Amendments (CAAA) of 1990 have placed stringent requirements on the quality of transportation fuels. Most petroleum refiners are scrambling to meet provisions of the Amendments to be implemented between 1995 and 2000. These requirements will also have significant implications for the production of alternative fuels. These have been examined for Fischer-Tropsch (F-T) derived fuels. This analysis was conducted in conjunction with the U.S. Department of Energy (DOE) sponsored project, Baseline Design/Economics for Advanced Fischer-Tropsch Technology, conducted by Bechtel and Amoco. The goal of this study was to develop a baseline design for indirect liquefaction of Illinois No. 6 coal using gasification, syngas conversion in slurry reactors with iron catalysts, and conventional refinery upgrading of the F-T derived hydrocarbon liquids. One alternative case using ZSM-5 upgrading technology was also considered. This study included complete capital and operating cost estimates for the processes. To perform economic analyses for the different design cases, the products from the liquefaction plant had to be valued relative to conventional transportation fuels. This task was accomplished by developing a Linear Programming (LP) model for a typical midwest refinery, and then feeding the F-T liquids to the refinery. In this way, the breakeven value determined for these materials is indicative of the price they could command if available in the marketplace. Inputs to the LP model include: refinery size, configuration, feedstocks, products, specifications, prices, and operating and capital recovery costs. The model was set up to be representative of conditions anticipated for the turn of the century. This required inclusion of fuel specifications from the CAAA of 1990 which have or will come into force by the year 2000.

  3. Fossil fuel derivatives with reduced carbon. Phase I final report

    SciTech Connect (OSTI)

    Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

    1999-06-30

    This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

  4. Briefing, DOE Order 475.2B, Identifying Classified Information, What Derivative Classifiers Should Know

    Broader source: Energy.gov [DOE]

    This briefing provides Derivative Classifiers with information regarding the changes to the DOE Order on Identifying Classified Information.

  5. Hydrogen Production via Reforming of Bio-Derived Liquids | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Production via Reforming of Bio-Derived Liquids Hydrogen Production via Reforming of Bio-Derived Liquids Presentation by Yong Wang and David King at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting. biliwg06_wang_pnnl.pdf (841.57 KB) More Documents & Publications Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production

  6. Superconvergence of the derivative patch recovery technique and a posteriorii error estimation

    SciTech Connect (OSTI)

    Zhang, Z.; Zhu, J.Z.

    1995-12-31

    The derivative patch recovery technique developed by Zienkiewicz and Zhu for the finite element method is analyzed. It is shown that, for one dimensional problems and two dimensional problems using tensor product elements, the patch recovery technique yields superconvergence recovery for the derivatives. Consequently, the error estimator based on the recovered derivative is asymptotically exact.

  7. Calculation Package: Derivation of Facility-Specific Derived Air Concentration (DAC) Values in Support of Spallation Neutron Source Operations

    SciTech Connect (OSTI)

    McLaughlin, David A

    2009-12-01

    Derived air concentration (DAC) values for 175 radionuclides* produced at the Oak Ridge National Laboratory (ORNL) Spallation Neutron Source (SNS), but not listed in Appendix A of 10 CFR 835 (01/01/2009 version), are presented. The proposed DAC values, ranging between 1 E-07 {micro}Ci/mL and 2 E-03 {micro}Ci/mL, were calculated in accordance with the recommendations of the International Commission on Radiological Protection (ICRP), and are intended to support an exemption request seeking regulatory relief from the 10 CFR 835, Appendix A, requirement to apply restrictive DACs of 2E-13 {micro}Ci/mL and 4E-11 {micro}Ci/mL and for non-listed alpha and non-alpha-emitting radionuclides, respectively.

  8. Isolation of levoglucosan from pyrolysis oil derived from cellulose

    DOE Patents [OSTI]

    Moens, Luc

    1994-01-01

    High purity levoglucosan is obtained from pyrolysis oil derived from cellulose by: mixing pyrolysis oil with water and a basic metal hydroxide, oxide, or salt in amount sufficient to elevate pH values to a range of from about 12 to about 12.5, and adding an amount of the hydroxide, oxide, or salt in excess of the amount needed to obtain the pH range until colored materials of impurities from the oil are removed and a slurry is formed; drying the slurry azeotropically with methyl isobutyl ketone solvent to form a residue, and further drying the residue by evaporation; reducing the residue into a powder; continuously extracting the powder residue with ethyl acetate to provide a levoglucosan-rich extract; and concentrating the extract by removing ethyl acetate to provide crystalline levoglucosan. Preferably, Ca(OH).sub.2 is added to adjust the pH to the elevated values, and then Ca(OH).sub.2 is added in an excess amount needed.

  9. Isolation of levoglucosan from pyrolysis oil derived from cellulose

    DOE Patents [OSTI]

    Moens, L.

    1994-12-06

    High purity levoglucosan is obtained from pyrolysis oil derived from cellulose by: mixing pyrolysis oil with water and a basic metal hydroxide, oxide, or salt in amount sufficient to elevate pH values to a range of from about 12 to about 12.5, and adding an amount of the hydroxide, oxide, or salt in excess of the amount needed to obtain the pH range until colored materials of impurities from the oil are removed and a slurry is formed; drying the slurry azeotropically with methyl isobutyl ketone solvent to form a residue, and further drying the residue by evaporation; reducing the residue into a powder; continuously extracting the powder residue with ethyl acetate to provide a levoglucosan-rich extract; and concentrating the extract by removing ethyl acetate to provide crystalline levoglucosan. Preferably, Ca(OH)[sub 2] is added to adjust the pH to the elevated values, and then Ca(OH)[sub 2] is added in an excess amount needed. 3 figures.

  10. High octane ethers from synthesis gas-derived alcohol

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Bastian, R.D.; DeTavernier, S. . Dept. of Chemistry Lehigh Univ., Bethlehem, PA . Zettlemoyer Center for Surface Studies)

    1991-01-01

    The objective of the proposed research is to synthesize high octane ethers directly from coal-derived synthesis gas via alcohol mixtures that are rich in methanol and isobutanol. The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. Commercial acid and superacid resin catalysts were obtained and tested under one set of conditions to compare the activities and selectivities for forming the unsymmetric methylisobutylether (MIBE) by coupling methanol with isobutanol. It was found that both Nafion-H microsaddles and Amberlyst-15 resins are active for this synthesis reaction. While and the Nafion-H catalyst does form the MIBE product fairly selectively under the reaction conditions utilized, the Amberlyst-15 catalyst formed dimethylether (DME) as the major product. In addition, significantly larger quantities of the C{sub 4} hydrocarbon products were observed over the Amberlyst-15 catalyst at 123{degree}C and 13.6 atm. It has been demonstrated that methyltertiarybutylether (MTBE) MIBE, DME and diisobutylether (DIBE) are separated and quantitatively determined by using the proper analytical conditions. In order to gain insight into the role of superacidity in promoting the selective coupling of the alcohols to form the unsymmetric ether, the strengths of the acid sites on the catalysts are being probed by thermometric titrations in non-aqueous solutions. 18 refs., 20 figs., 4 tabs.

  11. High capacitance of coarse-grained carbide derived carbon electrodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dyatkin, Boris; Gogotsi, Oleksiy; Malinovskiy, Bohdan; Zozulya, Yuliya; Simon, Patrice; Gogotsi, Yury

    2016-01-01

    Here, we report exceptional electrochemical properties of supercapacitor electrodes composed of large, granular carbide-derived carbon (CDC) particles. We synthesized 70–250 μm sized particles with high surface area and a narrow pore size distribution, using a titanium carbide (TiC) precursor. Electrochemical cycling of these coarse-grained powders defied conventional wisdom that a small particle size is strictly required for supercapacitor electrodes and allowed high charge storage densities, rapid transport, and good rate handling ability. Moreover, the material showcased capacitance above 100 F g-1 at sweep rates as high as 250 mV s-1 in organic electrolyte. 250–1000 micron thick dense CDC films withmore » up to 80 mg cm-2 loading showed superior areal capacitances. The material significantly outperformed its activated carbon counterpart in organic electrolytes and ionic liquids. Furthermore, large internal/external surface ratio of coarse-grained carbons allowed the resulting electrodes to maintain high electrochemical stability up to 3.1 V in ionic liquid electrolyte. In addition to presenting novel insights into the electrosorption process, these coarse-grained carbons offer a pathway to low-cost, high-performance implementation of supercapacitors in automotive and grid-storage applications.« less

  12. Derived annual estimates of manufacturing energy consumption, 1974--1988

    SciTech Connect (OSTI)

    Not Available

    1992-08-05

    This report presents a complete series of annual estimates of purchased energy used by the manufacturing sector of the US economy, for the years 1974 to 1988. These estimates interpolate over gaps in the actual data collections, by deriving estimates for the missing years 1982--1984 and 1986--1987. For the purposes of this report, ``purchased`` energy is energy brought from offsite for use at manufacturing establishments, whether the energy is purchased from an energy vendor or procured from some other source. The actual data on purchased energy comes from two sources, the US Department of Commerce Bureau of the Census`s Annual Survey of Manufactures (ASM) and EIA`s Manufacturing Energy Consumption Survey (MECS). The ASM provides annual estimates for the years 1974 to 1981. However, in 1982 (and subsequent years) the scope of the ASM energy data was reduced to collect only electricity consumption and expenditures and total expenditures for other purchased energy. In 1985, EIA initiated the triennial MECS collecting complete energy data. The series equivalent to the ASM is referred to in the MECS as ``offsite-produced fuels.``

  13. Minimizing Glovebox Glove Breaches, Part III: Deriving Service Lifetimes

    SciTech Connect (OSTI)

    Cournoyer, M.E.; Wilson, K.V.; Maestas, M.M.; Schreiber, S.

    2006-07-01

    At the Los Alamos Plutonium Facility, various isotopes of plutonium along with other actinides are handled in a glove box environment. Weapons-grade plutonium consists mainly in Pu-239. Pu-238 is another isotope used for heat sources. The Pu-238 is more aggressive regarding gloves due to its higher alpha-emitting characteristic ({approx}300 times more active than Pu-239), which modifies the change-out intervals for gloves. Optimization of the change-out intervals for gloves is fundamental since Nuclear Materials Technology (NMT) Division generates approximately 4 m{sup 3}/yr of TRU waste from the disposal of glovebox gloves. To reduce the number of glovebox glove failures, the NMT Division pro-actively investigates processes and procedures that minimize glove failures. Aging studies have been conducted that correlate changes in mechanical (physical) properties with degradation chemistry. This present work derives glovebox glove change intervals based on mechanical data of thermally aged Hypalon{sup R}, and Butasol{sup R} glove samples. Information from this study represent an important baseline in gauging the acceptable standards for polymeric gloves used in a laboratory glovebox environment and will be used later to account for possible presence of dose-rate or synergistic effects in 'combined-environment'. In addition, excursions of contaminants into the operator's breathing zone and excess exposure to the radiological sources associated with unplanned breaches in the glovebox are reduced. (authors)

  14. Utilization of refuse derived fuels by the United States Navy

    SciTech Connect (OSTI)

    Lehr, D.L.

    1983-07-01

    The Resource Conservation and Recovery Act and the Safe Drinking Water Act are forcing those in charge of landfills to adhere to more stringent operating standards. This, along with the growing scarcity of landfill availability, makes the use of landfills less desirable for solid waste disposal. As such, new disposal methods that are environmentally safe and economically practical must be found. One alternative, that is not really new but which has gained renewed interest, is incineration. The Resource Conservation and Recovery Act also requires that government agencies should direct their installations to recover as many resources as possible. Therefore if incineration is to be implemented, heat recovery should be incorporated into the system. There are several processes available to convert raw refuse into a fuel for use in a heat recovery system. Refuse derived fuels (RDF) can be in the form of raw refuse, densified refuse, powdered refuse, gas, or pyrolytic oil. The only form of RDF that is economically feasible for systems designed to process less than 200 TPD (tons per day) is raw refuse. Most Navy bases generate far less than 200 TPD of solid waste and therefore the Navy has focused most of its attention on modular heat recovery incinerator (HRI) systems that utilize raw refuse as fuel.

  15. THERMAL INSULATION FROM LIGNIN-DERIVED CARBON FIBERS

    SciTech Connect (OSTI)

    Albers, Tracy; Chen, Chong; Eberle, Cliff; Webb, Daniel C

    2014-01-01

    Oak Ridge National Laboratory (ORNL) and GrafTech International Holdings Inc. (GrafTech) have collaborated to develop and demonstrate the performance of high temperature thermal insulation prototypes made from lignin-based carbon fibers (LBCF). This was the first reported production of LBCF or resulting products at scale > 1 kg. The results will potentially lead to the first commercial application of LBCF. The goal of the commercial application is to replace expensive, foreign-sourced isotropic pitch carbon fibers with lower cost carbon fibers made from a domestically sourced, bio-derived (renewable) feedstock. LBCF can help resolve supply chain vulnerability and reduce the production cost for high temperature thermal insulation as well as create US jobs. The performance of the LBCF prototypes was measured and found to be comparable to that of the current commercial product. During production of the insulation prototypes, the project team demonstrated lignin compounding/pelletization, fiber production, heat treatment, and compositing at scales far surpassing those previously demonstrated in LBCF R&D or production.

  16. High capacitance of coarse-grained carbide derived carbon electrodes

    SciTech Connect (OSTI)

    Dyatkin, Boris; Gogotsi, Oleksiy; Malinovskiy, Bohdan; Zozulya, Yuliya; Simon, Patrice; Gogotsi, Yury

    2016-01-01

    Here, we report exceptional electrochemical properties of supercapacitor electrodes composed of large, granular carbide-derived carbon (CDC) particles. We synthesized 70–250 μm sized particles with high surface area and a narrow pore size distribution, using a titanium carbide (TiC) precursor. Electrochemical cycling of these coarse-grained powders defied conventional wisdom that a small particle size is strictly required for supercapacitor electrodes and allowed high charge storage densities, rapid transport, and good rate handling ability. Moreover, the material showcased capacitance above 100 F g-1 at sweep rates as high as 250 mV s-1 in organic electrolyte. 250–1000 micron thick dense CDC films with up to 80 mg cm-2 loading showed superior areal capacitances. The material significantly outperformed its activated carbon counterpart in organic electrolytes and ionic liquids. Furthermore, large internal/external surface ratio of coarse-grained carbons allowed the resulting electrodes to maintain high electrochemical stability up to 3.1 V in ionic liquid electrolyte. In addition to presenting novel insights into the electrosorption process, these coarse-grained carbons offer a pathway to low-cost, high-performance implementation of supercapacitors in automotive and grid-storage applications.

  17. Development of alternative fuels from coal-derived syngas

    SciTech Connect (OSTI)

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products' laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively benign'' system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE's program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  18. Synthesis of Methyl Methacrylate from Coal-Derived Syngas

    SciTech Connect (OSTI)

    Gerald N. Choi; James J. Spivey; Jospeh R. Zoeller; Makarand R. Gogate; Richard D. Colberg; Samuel S. Tam

    1998-04-17

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. RTI has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, RTI is currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last month, RTI has finalized the design of a fixed-bed microreactor system for DME partial oxidation reactions. RTI incorporated some design changes to the feed blending system, so as to be able to blend varying proportions of DME and oxygen. RTI has also examined the flammability limits of DME-air mixtures. Since the lower flammability limit of DME in air is 3.6 volume percent, RTI will use a nominal feed composition of 1.6 percent in air, which is less than half the lower explosion limit for DME-air mixtures. This nominal feed composition is thus considered operationally safe, for DME partial oxidation reactions. RTI is also currently developing an analytical system for DME partial oxidation reaction system.

  19. The occurrence of tricin and its derivatives in plants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Mi; Pu, Yunqiao; Yoo, Chang Geun; Ragauskas, Arthur J.

    2016-02-02

    Our understanding of the structure and biosynthetic pathway of lignin, a phenylpropanoid heteropolymer, continues to evolve, especially with the discovery of new lignin monomers/structural moieties such as monolignol acetate, hydroxycinnamyl aldehyde/alcohol, and p-hydroxybenzoate in the past decades. Recently, tricin has been reported as a component incorporated into monocot lignin. As a flavonoid compound widely distributed in herbaceous plants, tricin has been extensively studied due to its biological significance in plant growth as well as its potential for pharmaceutical importance. Tricin is biosynthesized as a constituent of plant secondary metabolites through a combination of phenylpropanoid and polyketide pathways. Tricin occurs inmore » plants in either free or conjugated forms such as tricin-glycosides, tricin-lignans, and tricin-lignan-glycosides.The emergence of tricin covalently incorporated with lignin biopolymer implies the possible association of lignification and tricin biosynthesis. This review summarizes the occurrence of tricin and its derivatives in plants. Additionally, synthesis, potential application, and characterization of tricin are discussed.« less

  20. Nocturnal Avian Migration Experiment Final Campaign Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Second, the combined data set of acoustic, radar, lidar, and meteorological observations is, in itself, valuable for aeroecology research on the movement and behavior of migrating ...

  1. Hydrotreating Uinta Basin bitumen-derived heavy oils

    SciTech Connect (OSTI)

    Longstaff, D.C.; Balaji, G.V.; Kim, J.W.

    1995-12-31

    Heavy oils derived from Uinta Basin bitumens have been hydrotreated under varying conditions. The process variables investigated included total reactor pressure (11.0-16.9 MPa), reactor temperature (616-711 K), feed rate (0.29-1.38 WHSV), and catalyst composition. The extent of heteroatom removal and residuum conversion were determined by the feed molecular weight and catalyst selection. Catalytic activity for heteroatom conversion removal was primarily influenced by metal loading. The heteroatom removal activity of the catalysts studied were ranked HDN catalysts > HDM catalysts > HDN-support. Catalytic activity for residuum conversion was influenced by both metal loading and catalyst surface area. The residuum conversion activity of HDN catalysts were always higher than the activity of HDM catalysts and HDN supports. The residuum conversion activity of HDN-supports surpassed the activity of HDM catalyst at higher temperatures. The conversions achieved with HDN catalysts relative to the HDM catalysts indicated that the low metals contents of the Uinta Basin bitumens obviate the need for hydrodemetallation as an initial upgrading step with these bitumens. The upgrading of Uinta Basin bitumens for integration into refinery feed slates should emphasize molecular weight and boiling range reduction first, followed by hydrotreating of the total liquid product produced in the pyrolysis process. Kinetics of residuum conversion can be modeled by invoking a consecutive-parallel mechanism in which native residuum in the feed is rapidly converted to volatile products and to product residuum. Deep conversion of residuum is only achieved when the more refractory product residuum is converted to volatile products.

  2. Promise and Challenges of Microalgal-Derived Biofuels

    SciTech Connect (OSTI)

    Pienkos, P. T.; Darzins, A.

    2009-01-01

    Microalgae offer great promise to contribute a significant portion of the renewable fuels that will be required by the Renewable Fuels Standard described in the 2007 Energy Independence and Security Act of the United States. Algal biofuels would be based mainly on the high lipid content of the algal cell and thus would be an ideal feedstock for high energy density transportation fuels, such as biodiesel as well as green diesel, green jet fuel and green gasoline. A comprehensive research and development program for the development of algal biofuels was initiated by the US Department of Energy (DoE) more than 30 years ago, and although great progress was made, the program was discontinued in 1996, because of decreasing federal budgets and low petroleum costs. Interest in algal biofuels has been growing recently due to increased concern over peak oil, energy security, greenhouse gas emissions, and the potential for other biofuel feedstocks to compete for limited agricultural resources. The high productivity of algae suggests that much of the US transportation fuel needs can be met by algal biofuels at a production cost competitive with the cost of petroleum seen during the early part of 2008. Development of algal biomass production technology, however, remains in its infancy. This perspective provides a brief overview of past algal research sponsored by the DoE, the potential of microalgal biofuels and a discussion of the technical and economic barriers that need to be overcome before production of microalgal-derived diesel-fuel substitutes can become a large-scale commercial reality.

  3. Synthesis of Methyl Methacrylate From Coal-Derived Syngas

    SciTech Connect (OSTI)

    Ben W.-L. Jang; Gerald N. Choi; James J. Spivey; Jospeh R. Zoeller; Richard D. Colberg; Samuel S. Tam

    1998-07-27

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. RTI has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, RTI is currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last quarter(April-June, 1998), RTI has modified the reactor system including a new preheater and new temperature settings for the preheater. Continuous condensation of formaldehyde with propionic acid were carried out over 10% Nb O /SiO at 300°C without 2 5 2 interruption. Five activity and four regeneration cycles have been completed without plugging or material balance problems. The results show that 10% Nb O /SiO deactivates slowly with time 2 5 2 but can be regenerated, at least four times, to 100% of its original activity with 2% O in nitrogen 2 at 400°C. The cycles continue with consistent 90-95% of carbon balance. The reaction is scheduled to complete with 6 activity cycles and 5 regenerations. Used catalysts will be analyzed with TGA and XPS to determine bulk and surface coke content and coke properties. RTI will start the investigation of effects of propionic acid/formaldehyde ratio on reaction activity and product selectivity over 20% Nb O /SiO catalysts.

  4. Synthesis of acrylates and Methacrylates from Coal-Derived Syngas

    SciTech Connect (OSTI)

    1997-05-12

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the U.S. Department of Energy, Federal Energy Technology Center. This three-step process consists of synthesis of a propionate, its condensation with formaldehyde, and esterification of resulting methacrylic acid (MAA) with methanol to produce MMA. Eastman has focused on the propionate synthesis step. The resultant Mo catalysts work efficiently at much less severe conditions (170{degrees}C and 30 atm) than the conventional Ni catalysts (270{degrees} C and 180 atm). Bechtel has performed an extensive cost analysis which shows that Eastman`s propionate synthesis step is competitive with other technologies to produce the anhydride. Eastman and Bechtel have also compared the RTI- Eastman-Bechtel three-step methanol route to five other process routes to MMA. The results show that the product MMA can be produced at 520/lb, for a 250 Mlb/year MMA plant, and this product cost is competitive to all other process routes to MMA, except propyne carbonylation. In the second step, RTI and Eastman have developed active and stable V-SI-P tertiary metal oxide catalysts, Nb/Si0{sub 2}, and Ta/Si0{sub 2} catalysts for condensation of propionic anhydride or propionic acid with formaldehyde. RTI has demonstrated a novel correlation among the catalyst acid-base properties, condensation reaction yield, and long-term catalyst performance. Eastman and Bechtel have used the RTI experimental results of a 20 percent Nb/Si0{sub 2} catalyst, in terms of reactant conversions, MAA selectivities, and MAA yield, for their economic analysis. Recent research focuses on enhancing the condensation reaction yields, a better understanding of the acid-base property correlation and enhancing the catalyst lifetime.

  5. Biomass-Derived Hydrogen from a Thermally Ballasted Gasifier

    SciTech Connect (OSTI)

    Brown, Robert C

    2007-04-06

    The goal of this project is to develop an indirectly heated gasification system that converts switchgrass into hydrogen-rich gas suitable for powering fuel cells. The project includes investigations of the indirectly-heated gasifier, development of particulate removal equipment, evaluation of catalytic methods for upgrading producer gas, development of contaminant measurement and control techniques, modeling of the thermal performance of the ballasted gasifier, and estimation of the cost of hydrogen from the proposed gasification system. Specific technologies investigated include a thermally ballasted gasifier, a moving bed granular filter, and catalytic reactors for steam reforming and water-gas shift reaction. The approach to this project was to employ a pilot-scale (5 ton per day) gasifier to evaluate the thermally ballasted gasifier as a means for producing hydrogen from switchgrass. A slipstream from the gasifier was used to evaluate gas cleaning and upgrading options. Other tests were conducted with laboratory-scale equipment using simulated producer gas. The ballasted gasifier operated in conjunction with a steam reformer and two-stage water-gas shift reactor produced gas streams containing 54.5 vol-% H2. If purge gas to the feeder system could be substantially eliminated, hydrogen concentration would reach 61 vol-%, which closely approaches the theoretical maximum of 66 vol-%. Tests with a combined catalyst/sorbent system demonstrated that steam reforming and water-gas shift reaction could be substantially performed in a single reactor and achieve hydrogen concentrations exceeding 90 vol-%. Cold flow trials with a laboratory-scale moving bed granular filter achieved particle removal efficiencies exceeding 99%. Two metal-based sorbents were tested for their ability to remove H2S from biomass-derived producer gas. The ZnO sorbent, tested at 450° C, was effective in reducing H2S from 200 ppm to less than 2 ppm (>99% reduction) while tests with the MnO sorbent

  6. Synthesis of Acrylates and Methacrylates from Coal-Derived Syngas.

    SciTech Connect (OSTI)

    Gogate, M.R.; Spivey, J.J.; Zoeller, J.R.; Colberg, R.D.; Choi, G.N.; Tam, S.S.

    1997-10-17

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the U.S. Department of Energy/Federal Energy Technology Center (DOE/FETC). This three-step process consists of synthesis of a propionate, its condensation with formaldehyde, and esterification of resulting methacrylic acid (MAA) with methanol to produce MMA. Over the last quarter, RTI carried out activity tests on a pure (99 percent) Nb{sub 2}O{sub 5} catalyst, received from Alfa Aesar, under the following experimental conditions: T=300 C; P=4 atm, 72:38:16:4:220 mmol/h, PA:H{sub 2}0:HCHO:CH{sub 3}0H:N{sub 2}; 5-g catalyst charge. For the pure material, the MAA yields (based on HCHO and PA) were at 8.8 and 1.5 percent, clearly inferior compared to those for a 10-percent Nb{sub 2}O{sub 5}/Si0{sub 2} catalyst (20.1 and 4.5 percent). The X-ray diffraction (XRD) patterns of pure Nb{sub 2}O{sub 5} and 20-percent Nb{sub 2}O{sub 5}/Si0{sub 2} that while pure Nb{sub 2}O{sub 5} is very highly crystalline, Si0{sub 2} support for an amorphous nature of the 20 percent Nb{sub 2}O{sub 5}/Si0{sub 2} catalyst the last quarter, RTI also began research on the use of dimethyl ether (DME), product of methanol dehydrocondensation, as an alternate feedstock in MMA synthesis. As a result, formaldehyde is generated either externally or in situ, from DME, in the process envisaged in the contract extension. The initial work on the DME extension of the contract focuses on a tradeoff analysis that will include a preliminary economic analysis of the DME and formaldehyde routes and catalyst synthesis and testing for DME partial oxidation and condensation reactions. Literature guides exist for DME partial oxidation catalysts; however, there are no precedent studies on catalyst development for DME-methyl propionate (MP) condensation reactions, thereby making DME-MP reaction studies a

  7. SYNTHESIS OF METHYL METHACRYLATE FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    BEN W.-L. JANG; GERALD N. CHOI; JAMES J. SPIVEY; JOSPEH R. ZOELLER; RICHARD D. COLBERG

    1998-10-20

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. RTI has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, RTI is currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last quarter (July-September, 1998), the project team has completed the continuous condensation of formaldehyde with propionic acid over 10% Nb{sub 2}O{sub 5}/SiO{sub 2} at 300 C. Six activity and five regeneration cycles have been completed. The results show that 10% Nb{sub 2}O{sub 5}/SiO{sub 2} deactivates slowly with time but can be regenerated to its original activity with 2% O{sub 2} in nitrogen over night at 400 C. We have investigated the effects of regeneration, propionic acid/formaldehyde ratio (PA/HCHO = 4.5/1 to 1.5/1) and reaction temperature(280-300 C) on reaction activity and product selectivity over 20% Nb{sub 2}O{sub 5}/SiO{sub 2} catalysts. The regeneration effect on 20% Nb{sub 2}O{sub 5}/SiO{sub 2} is similar to the effect on 10% Nb{sub 2}O{sub 5}/SiO{sub 2}. The regeneration can bring the deactivated catalyst to its original activity. However, the selectivity to MAA decreases with regeneration while the selectivity to DEK and CO{sub 2} increases. When PA/HCHO ratio is decreased from 4.5/1 to 2.25/1 then to 1.5/1 at 300 C the MAA yield decreases but the MAA selectivity first increases then decreases. Decreasing the reaction temperature from 300 C to 280 C decreases the MAA yield from 39.5% to 30.7% but increases the MAA selectivity from 73.7% to 82.2%. The

  8. SYNTHESIS OF METHYL METHACRYLATE FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    BEN W.-L. JANG; GERALD N. CHOI; JAMES J. SPIVEY; JOSPEH R. ZOELLER; RICHARD D. COLBERG

    1999-01-20

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. The research team has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, we are currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last quarter(Oct.-Dec./98), we have investigated the condensation between methyl propionate and formaldehyde (MP/HCHO=4.5/1) at various reaction temperatures(280-360EC) over 5%, 10%, and 20% Nb O /SiO catalysts. The conversion of HCHO increases with reaction 2 5 2 temperature and niobium loading. MMA+MAA selectivity goes through a maximum with the temperature over both 10% and 20% Nb O /SiO . The selectivities to MMA+MAA are 67.2%, 2 5 2 72.3%and 58.1% at 320EC over 5%, 10%, 20% Nb O /SiO , respectively. However, the 2 5 2 conversion of formaldehyde decreases rapidly with time on stream. The results suggest that silica supported niobium catalysts are active and selective for condensation of MP with HCHO, but deactivation needs to be minimized for the consideration of commercial application. We have preliminarily investigated the partial oxidation of dimethyl ether(DME) over 5% Nb O /SiO catalyst. Reactant gas mixture of 0.1% DME, 0.1% O and balance nitrogen is 2 5 2 2 studied with temperature ranging from 200°C to 500°C. The conversion of DME first increases with temperature reaching an maximum at 400°C then decreases. The selectivity to HCHO also increases with reaction temperature first. But the selectivity to HCHO decreases at temperature above 350

  9. SYNTHESIS OF METHYL METHACRYLATE FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    Makarand R. Gogate; James J. Spivey; Joseph R. Zoeller; Richard D. Colberg; Gerald N. Choi

    1999-07-19

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. The research team has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, we are currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. During the April-June quarter(04-06/99) the first in-situ formaldehyde generation from DME and condensation with methyl propionate is demonstrated and the results are summarized. The supported niobium catalyst shows better condensation activity, but supported tungsten catalyst has higher formaldehyde selectivity. The project team has also completed a 200-hour long term test of PA-HCHO condensation over 30% Nb{sub 2}O{sub 5}/SiO{sub 2}. Three activity cycles and two regeneration cycles were carried out. 30% Nb{sub 2}O{sub 5}/SiO{sub 2} showed similar MAA yields as 10% Nb{sub 2}O{sub 5}/SiO{sub 2} at 300 C. However, the deactivation appears to be slower with 30% Nb{sub 2}O{sub 5}/SiO{sub 2} than 10% Nb{sub 2}O{sub 5}/SiO{sub 2}. An detailed economic analysis of PA-HCHO condensation process for a 250 million lb/yr MMA plant is currently studied by Bechtel. Using the Amoco data-based azeotropic distillation model as the basis, an ASPEN flow sheet model was constructed to simulate the formaldehyde and propionic acid condensation processing section based on RTI's design data. The RTI MAA effluent azeotropic distillation column was found to be much more difficult to converge. The presence of non-condensible gases along with the byproduct DEK (both of which were not presented in

  10. EERE Success Story-Exploring Hydrogen Generation from Biomass-Derived

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sugar and Sugar Alcohols to Reduce Costs | Department of Energy Exploring Hydrogen Generation from Biomass-Derived Sugar and Sugar Alcohols to Reduce Costs EERE Success Story-Exploring Hydrogen Generation from Biomass-Derived Sugar and Sugar Alcohols to Reduce Costs April 15, 2013 - 12:00am Addthis With support from EERE, researchers at Virent, Inc. in Madison developed new cost-effective methods to produce hydrogen from renewable resources like biomass-derived sugar and sugar alcohols.

  11. DOE Technical Targets for Hydrogen Production from Biomass-Derived Liquid

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reforming | Department of Energy Biomass-Derived Liquid Reforming DOE Technical Targets for Hydrogen Production from Biomass-Derived Liquid Reforming These tables list the U.S. Department of Energy (DOE) technical targets and example cost contributions for hydrogen production from biomass-derived liquid reforming. More information about targets can be found in the Hydrogen Production section of the Fuel Cell Technologies Office's Multi-Year Research, Development, and Demonstration Plan.

  12. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - November 2007 | Department of Energy Meeting - November 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting - November 2007 The Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group participated in a Hydrogen Production Technical Team Research Review on November 6, 2007. The meeting provided the opportunity for researchers to share their experiences in converting bio-derived liquids to hydrogen with members of the Department of Energy Hydrogen

  13. Method for deriving information regarding stress from a stressed ferromagnetic material

    DOE Patents [OSTI]

    Jiles, David C.

    1991-04-30

    A non-destructive evaluation technique for deriving stress in ferromagnetic materials including deriving anhysteretic and hysteresis magnetization curves for the material in both unstressed and stressed states. The anhysteretic curve is expressed as a Langevin function. The stress is expressed as an equivalent magnetic field dependent on stress and change of magnetostriction with magnetization. By measurement of these bulk magnetic properties, stress can be derived.

  14. Method for deriving information regarding stress from a stressed ferromagnetic material

    DOE Patents [OSTI]

    Jiles, D.C.

    1991-04-30

    A nondestructive evaluation technique is disclosed for deriving stress in ferromagnetic materials including deriving anhysteretic and hysteresis magnetization curves for the material in both unstressed and stressed states. The anhysteretic curve is expressed as a Langevin function. The stress is expressed as an equivalent magnetic field dependent on stress and change of magnetostriction with magnetization. By measurement of these bulk magnetic properties, stress can be derived.

  15. Hydrogen Generation from Biomass-Derived Carbohydrates via Aqueous-Phase Reforming

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation by Virent Energy Systems, Inc. at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  16. Meeting Action Items and Highlights from the Bio-Derived Liquids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reforming Working Group (BILIWG) & Hydrogen Production Technical Team Research Review Meeting Action Items and Highlights from the Bio-Derived Liquids to Hydrogen Distributed ...

  17. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation)

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  18. Derivation of Seasonal Cloud Properties at ARM-NSA from Multispectral...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Derivation of Seasonal Cloud Properties at ARM-NSA from Multispectral MODIS Data D. A. ... over the Atmospheric Radiation Measurement (ARM) North Slope of Alaska (NSA) Barrow site. ...

  19. Thiourea derivatives, methods of their preparation and their use in neutron capture therapy of malignant melanoma

    DOE Patents [OSTI]

    Gabel, Detlef

    1991-01-01

    The present invention pertains to boron containing thiouracil derivatives, their method of preparations, and their use in the therapy of malignant melanoma using boron neutron capture therapy.

  20. The Impact of Spatial Resolution on Model-Derived Radiative Heating

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Impact of Spatial Resolution on Model-Derived Radiative Heating W. O'Hirok and C. Gautier Institute for Computational Earth System Science University of California Santa Barbara, ...

  1. Derivatives and Risk Management in the Petroleum, Natural Gas, and Electricity Industries

    Reports and Publications (EIA)

    2002-01-01

    In February 2002 the Secretary of Energy directed the Energy Information Administration (EIA) to prepare a report on the nature and use of derivative contracts in the petroleum, natural gas, and electricity industries. Derivatives are contracts ('financial instruments') that are used to manage risk, especially price risk.

  2. Coal/D-RDF (densified refuse-derived fuel) co-firing project, Milwaukee County, Wisconsin

    SciTech Connect (OSTI)

    Hecklinger, R.S.; Rehm, F.R.

    1985-11-01

    A Research and Development Project was carried out to mix a densified refuse-derived fuel with coal at the fuel-receiving point and to co-fire the mixture in a spreader-stoker fired boiler. Two basic series of test runs were conducted. For the first series, coal was fired to establish a base line condition. For the second series, a mixture of coal and densified refuse-derived fuel was fired. The report describes the equipment used to densify refuse derived fuel, procedures used to prepare and handle the coal and densified refuse derived fuel mixture and the test results. The results include the effect of the coal and densified refuse derived fuel mixture on plant operations, boiler efficiency, stack emissions and EP toxicity.

  3. ADIFOR: Fortran source translation for efficient derivatives. ADIFOR Working Note No. 4

    SciTech Connect (OSTI)

    Bischof, C.; Corliss, G.; Griewank, A.; Hovland, P.; Carle, A.

    1992-07-01

    The numerical methods employed in the solution of many scientific computing problems require the computation of derivatives of a function f: R{sup n} {yields} R{sup m}. Both the accuracy and the computational requirements of the derivative computation are usually of critical importance for the robustness and speed of the numerical method. ADIFOR (Automatic Differentiation In FORtran) is a source translation tool implemented using the data abstractions and program analysis capabilities of the ParaScope Parallel Programming Environment. ADIFOR accepts arbitrary Fortran-77 code defining the computation of a function and writes portable Fortran-77 code for the computation of its derivatives. In contrast to previous approaches, ADIFOR views automatic differentiation as a process of source translation that exploits computational context to reduce the cost of derivative computations. Experimental results show that ADIFOR can handle real-life codes, providing exact derivatives with a running time that is competitive with the standard divided-difference approximations of derivatives and which may perform orders of magnitude faster than divided-differences in cases. The computational scientist using ADIFOR is freed from worrying about the accurate and efficient computation of derivatives, even for complicated ``functions,`` and hence, is able to concentrate on the more important issues of algorithm design or system modeling. 35 refs.

  4. Pulse transmission receiver with higher-order time derivative pulse correlator

    DOE Patents [OSTI]

    Dress, Jr., William B.; Smith, Stephen F.

    2003-09-16

    Systems and methods for pulse-transmission low-power communication modes are disclosed. A pulse transmission receiver includes: a higher-order time derivative pulse correlator; a demodulation decoder coupled to the higher-order time derivative pulse correlator; a clock coupled to the demodulation decoder; and a pseudorandom polynomial generator coupled to both the higher-order time derivative pulse correlator and the clock. The systems and methods significantly reduce lower-frequency emissions from pulse transmission spread-spectrum communication modes, which reduces potentially harmful interference to existing radio frequency services and users and also simultaneously permit transmission of multiple data bits by utilizing specific pulse shapes.

  5. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy held a kick-off meeting for the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) on October 24, 2006, in Baltimore, Maryland. The Working Group is addressing technical challenges to distributed reforming of biomass-derived, renewable liquid fuels to hydrogen, including the reforming, water-gas shift, and hydrogen recovery and purification steps. The meeting provided the opportunity for researchers to share their experiences in converting bio-derived liquids to hydrogen with each other and with members of the DOE Hydrogen Production Technical Team.

  6. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Background Paper

    Broader source: Energy.gov [DOE]

    Paper by Arlene Anderson and Tracy Carole presented at the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group, with a focus on key drivers, purpose, and scope.

  7. On the electric micro-field in plasmas: statistics of the spatial derivatives

    SciTech Connect (OSTI)

    Guerricha, S.; Chihi, S.; Meftah, M. T.

    2008-10-22

    Using the Monte-Carlo simulation we calculated for some specific plasmas, the distribution functions of the derivatives of the micro-field components. Some of them are compared to those calculated earlier by other authors.

  8. Determination of the fuel characteristics of refuse-derived fuels by macroanalysis

    SciTech Connect (OSTI)

    Hecklinger, R.S.; Large, R.M.

    1980-01-01

    There is need for a means of determining the fuel characteristics of refuse-derived fuels to adjust the producer/user contractual relationship for fuel value. The authors discuss efforts to establish a macroanalysis procedure.

  9. Thiourea derivatives, methods of their preparation and their use in neutron capture therapy of malignant melanoma

    DOE Patents [OSTI]

    Gabel, D.

    1991-06-04

    The present invention pertains to boron containing thiouracil derivatives, their method of preparations, and their use in the therapy of malignant melanoma using boron neutron capture therapy. No Drawings

  10. High Temperature/Low Humidity Polymer Electrolytes Derived from Ionic Liquids

    Broader source: Energy.gov [DOE]

    Presentation on High Temperature/Low Humidity Polymer Electrolytes Derived from Ionic Liquids to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  11. Meeting Action Items and Highlights from the Bio-Derived Liquids to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Distributed Reforming Working Group (BILIWG) & Hydrogen Production Technical Team Research Review | Department of Energy Action Items and Highlights from the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) & Hydrogen Production Technical Team Research Review Meeting Action Items and Highlights from the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) & Hydrogen Production Technical Team Research Review This is the

  12. Materials Degradation In Biomass-Derived Oils Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies Office (BETO) Project Peer Review Materials Degradation In Biomass-Derived Oils March 25, 2015 Jim Keiser, Mike Brady, Sam Lewis, Maggie Connatser and Mike Kass Oak Ridge National Laboratory Goals/Objectives The presence of significant concentrations of oxygen-bearing compounds, particularly carboxylic acids and ketones, makes biomass derived oils very corrosive to some common structural materials The goals of this project are: 1) Use conventional and developmental analysis

  13. Emissions from Heavy-Duty Diesel Engine with EGR using Oil Sands Derived

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels | Department of Energy Heavy-Duty Diesel Engine with EGR using Oil Sands Derived Fuels Emissions from Heavy-Duty Diesel Engine with EGR using Oil Sands Derived Fuels 2003 DEER Conference Presentation: National Research Council Canada, Ottawa, Ontario, Canada 2003_deer_neill.pdf (860.57 KB) More Documents & Publications Development of Advanced Combustion Technologies for Increased Thermal Efficiency Biodiesel Research Update Effect of the Composition of Hydrocarbon Streams on HCCI

  14. Catalytic Conversion of Biomass-derived Feedstock (HMF) into Value Added

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemicals and Biofuels - Energy Innovation Portal Industrial Technologies Industrial Technologies Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Catalytic Conversion of Biomass-derived Feedstock (HMF) into Value Added Chemicals and Biofuels Colorado State University Contact CSU About This Technology Technology Marketing Summary A catalytic reaction system by which the biomass-derived feedstock chemical HMF can be upgraded into a higher carbon content

  15. Impacts of supersymmetric higher derivative terms on inflation models in supergravity

    SciTech Connect (OSTI)

    Aoki, Shuntaro; Yamada, Yusuke

    2015-07-14

    We show the effects of supersymmetric higher derivative terms on inflation models in supergravity. The results show that such terms generically modify the effective kinetic coefficient of the inflaton during inflation if the cut off scale of the higher derivative operators is sufficiently small. In such a case, the η-problem in supergravity does not occur, and we find that the effective potential of the inflaton generically becomes a power type potential with a power smaller than two.

  16. Spontaneous and reversible interaction of vanadium(V) oxyanions with amine derivatives

    SciTech Connect (OSTI)

    Crans, D.C.; Shin, P.K.

    1988-05-18

    The interaction between vanadate and tri- or tetradentate ethanolamine derivatives has been studied by using /sup 51/V NMR spectroscopy. The reactions occur spontaneously in aqueous solutions, at ambient temperatures and in the physiological pH range. In addition to one amine group and one hydroxyl group, the ethanolamine derivative should contain a third and/or fourth functionality that is an alcohol, a carboxylic acid, a phosphonium acid, or an amine. The reactions are highly dependent on pH, concentrations of monomeric vanadate, amine. The stability constants for the complexes are minimum orders of magnitude greater than those found for vanadate derivatives of corresponding ether derivatives, and the high stability is associated with the central nitrogen. Only one vanadium complex is formed in substantial amounts in the reaction of ethanolamine derivatives with vanadate, and that complex is mononuclear in vanadium. Several of the ethanolamine derivatives that form complexes are commonly used buffers in biological and biomedical studies in vitro. 22 refs., 10 figs., 7 tabs.

  17. Synthesis and characterization of ester and amide derivatives of titanium(IV) carboxymethylphosphonate

    SciTech Connect (OSTI)

    Melánová, Klára; Beneš, Ludvík; Trchová, Miroslava; Svoboda, Jan; Zima, Vítězslav

    2013-06-15

    A set of layered ester and amide derivatives of titanium(IV) carboxymethylphosphonate was prepared by solvothermal treatment of amorphous titanium(IV) carboxymethylphosphonate with corresponding 1-alkanols, 1,ω-alkanediols, 1-aminoalkanes, 1,ω-diaminoalkanes and 1,ω-amino alcohols and characterized by powder X-ray diffraction, IR spectroscopy and thermogravimetric analysis. Whereas alkyl chains with one functional group form bilayers tilted to the layers, 1,ω-diaminoalkanes and most of 1,ω-alkanediols form bridges connecting the adjacent layers. In the case of amino alcohols, the alkyl chains form bilayer and either hydroxyl or amino group is used for bonding. This simple method for the synthesis of ester and amide derivatives does not require preparation of acid chloride derivative as a precursor or pre-intercalation with alkylamines and can be used also for the preparation of ester and amide derivatives of titanium carboxyethylphosphonate and zirconium carboxymethylphosphonate. - Graphical abstract: Ester and amide derivatives of layered titanium carboxymethylphosphonate were prepared by solvothermal treatment of amorphous solid with alkanol or alkylamine. - Highlights: • Ester and amide derivatives of titanium carboxymethylphosphonate. • Solvothermal treatment of amorphous solid with alkanol or alkylamine. • Ester and amide formation confirmed by IR spectroscopy.

  18. Fundamental gaps with approximate density functionals: The derivative discontinuity revealed from ensemble considerations

    SciTech Connect (OSTI)

    Kraisler, Eli; Kronik, Leeor

    2014-05-14

    The fundamental gap is a central quantity in the electronic structure of matter. Unfortunately, the fundamental gap is not generally equal to the Kohn-Sham gap of density functional theory (DFT), even in principle. The two gaps differ precisely by the derivative discontinuity, namely, an abrupt change in slope of the exchange-correlation energy as a function of electron number, expected across an integer-electron point. Popular approximate functionals are thought to be devoid of a derivative discontinuity, strongly compromising their performance for prediction of spectroscopic properties. Here we show that, in fact, all exchange-correlation functionals possess a derivative discontinuity, which arises naturally from the application of ensemble considerations within DFT, without any empiricism. This derivative discontinuity can be expressed in closed form using only quantities obtained in the course of a standard DFT calculation of the neutral system. For small, finite systems, addition of this derivative discontinuity indeed results in a greatly improved prediction for the fundamental gap, even when based on the most simple approximate exchange-correlation density functional the local density approximation (LDA). For solids, the same scheme is exact in principle, but when applied to LDA it results in a vanishing derivative discontinuity correction. This failure is shown to be directly related to the failure of LDA in predicting fundamental gaps from total energy differences in extended systems.

  19. Processes for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil, and apparatuses for treating biomass-derived pyrolysis oil

    SciTech Connect (OSTI)

    Baird, Lance Awender; Brandvold, Timothy A.

    2015-11-24

    Processes and apparatuses for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil are provided herein. An exemplary process for washing a spent ion exchange bed employed in purification of biomass-derived pyrolysis oil includes the step of providing a ion-depleted pyrolysis oil stream having an original oxygen content. The ion-depleted pyrolysis oil stream is partially hydrotreated to reduce the oxygen content thereof, thereby producing a partially hydrotreated pyrolysis oil stream having a residual oxygen content that is less than the original oxygen content. At least a portion of the partially hydrotreated pyrolysis oil stream is passed through the spent ion exchange bed. Water is passed through the spent ion exchange bed after passing at least the portion of the partially hydrotreated pyrolysis oil stream therethrough.

  20. Human gingiva-derived mesenchymal stem cells are superior to bone marrow-derived mesenchymal stem cells for cell therapy in regenerative medicine

    SciTech Connect (OSTI)

    Tomar, Geetanjali B.; Srivastava, Rupesh K.; Gupta, Navita; Barhanpurkar, Amruta P.; Pote, Satish T.; Jhaveri, Hiral M.; Mishra, Gyan C.; Wani, Mohan R.

    2010-03-12

    Mesenchymal stem cells (MSCs) are capable of self-renewal and differentiation into multiple cell lineages. Presently, bone marrow is considered as a prime source of MSCs; however, there are some drawbacks and limitations in use of these MSCs for cell therapy. In this study, we demonstrate that human gingival tissue-derived MSCs have several advantages over bone marrow-derived MSCs. Gingival MSCs are easy to isolate, homogenous and proliferate faster than bone marrow MSCs without any growth factor. Importantly, gingival MSCs display stable morphology and do not loose MSC characteristic at higher passages. In addition, gingival MSCs maintain normal karyotype and telomerase activity in long-term cultures, and are not tumorigenic. Thus, we reveal that human gingiva is a better source of MSCs than bone marrow, and large number of functionally competent clinical grade MSCs can be generated in short duration for cell therapy in regenerative medicine and tissue engineering.

  1. Role of pigment epithelium-derived factor in the involution of hemangioma: Autocrine growth inhibition of hemangioma-derived endothelial cells

    SciTech Connect (OSTI)

    Kim, Kyung-Jin; Yun, Jang-Hyuk; Heo, Jong-Ik; Lee, Eun Hui; Min, Hye Sook; Choi, Tae Hyun; Cho, Chung-Hyun

    2014-11-14

    Highlights: • PEDF was expressed and induced during the involuting phase of IH. • PEDF inhibited the cell growth of the involuting HemECs in an autocrine manner. • PEDF suppression restored the impaired cell growth of the involuting HemECs. - Abstract: Hemangioma is a benign tumor derived from abnormal blood vessel growth. Unlike other vascular tumor counterparts, a hemangioma is known to proliferate during its early stage but it is followed by a stage of involution where regression of the tumor occurs. The critical onset leading to the involution of hemangioma is currently not well understood. This study focused on the molecular identities of the involution of hemangioma. We demonstrated that a soluble factor released from the involuting phase of hemangioma-derived endothelial cells (HemECs) and identified pigment epithelium-derived factor (PEDF) as an anti-angiogenic factor that was associated with the growth inhibition of the involuting HemECs. The growth inhibition of the involuting HemECs was reversed by suppression of PEDF in the involuting HemECs. Furthermore, we found that PEDF was more up-regulated in the involuting phase of hemangioma tissues than in the proliferating or the involuted. Taken together, we propose that PEDF accelerates the involution of hemangioma by growth inhibition of HemECs in an autocrine manner. The regulatory mechanism of PEDF expression could be a potential therapeutic target to treat hemangiomas.

  2. Properties of the Katugampola fractional derivative with potential application in quantum mechanics

    SciTech Connect (OSTI)

    Anderson, Douglas R.; Ulness, Darin J.

    2015-06-15

    Katugampola [e-print http://arxiv.org/abs/1410.6535 ] recently introduced a limit based fractional derivative, D{sup α} (referred to in this work as the Katugampola fractional derivative) that maintains many of the familiar properties of standard derivatives such as the product, quotient, and chain rules. Typically, fractional derivatives are handled using an integral representation and, as such, are non-local in character. The current work starts with a key property of the Katugampola fractional derivative, D{sup α}[y]=t{sup 1−α}(dy)/(dt) , and the associated differential operator, D{sup α} = t{sup 1−α}D{sup 1}. These operators, their inverses, commutators, anti-commutators, and several important differential equations are studied. The anti-commutator serves as a basis for the development of a self-adjoint operator which could potentially be useful in quantum mechanics. A Hamiltonian is constructed from this operator and applied to the particle in a box model.

  3. Process for removal of mineral particulates from coal-derived liquids

    DOE Patents [OSTI]

    McDowell, William J.

    1980-01-01

    Suspended mineral solids are separated from a coal-derived liquid containing the solids by a process comprising the steps of: (a) contacting said coal-derived liquid containing solids with a molten additive having a melting point of 100.degree.-500.degree. C. in an amount of up to 50 wt. % with respect to said coal-derived liquid containing solids, said solids present in an amount effective to increase the particle size of said mineral solids and comprising material or mixtures of material selected from the group of alkali metal hydroxides and inorganic salts having antimony, tin, lithium, sodium, potassium, magnesium, calcium, beryllium, aluminum, zinc, molybdenum, cobalt, nickel, ruthenium, rhodium or iron cations and chloride, iodide, bromide, sulfate, phosphate, borate, carbonate, sulfite, or silicate anions; and (b) maintaining said coal-derived liquid in contact with said molten additive for sufficient time to permit said mineral matter to agglomerate, thereby increasing the mean particle size of said mineral solids; and (c) recovering a coal-derived liquid product having reduced mineral solids content. The process can be carried out with less than 5 wt. % additive and in the absence of hydrogen pressure.

  4. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-01-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  5. Analytic derivation of the map of null rays passing near a naked singularity

    SciTech Connect (OSTI)

    Tanaka, Takahiro; Singh, T. P.

    2001-06-15

    Recently the energy emission from a naked singularity forming in spherical dust collapse has been investigated. This radiation is due to particle creation in a curved spacetime. In this discussion, the central role is played by the mapping formula between the incoming and the outgoing null coordinates. For the self-similar model, this mapping formula has been derived analytically. But for the model with C{sup {infinity}} density profile, the mapping formula has been obtained only numerically. In the present paper, we argue that the singular nature of the mapping is determined by the local geometry around the point at which the singularity is first formed. If this is the case, it would be natural to expect that the mapping formula can be derived analytically. In the present paper, we analytically rederive the same mapping formula for the model with C{sup {infinity}} density profile that has been earlier derived using a numerical technique.

  6. Synthesis, Consolidation and Characterization of Sol-gel Derived Tantalum-Tungsten Oxide Thermite Composites

    SciTech Connect (OSTI)

    Cervantes, O

    2010-06-01

    Energetic composite powders consisting of sol-gel (SG) derived nanostructured tungsten oxide were produced with various amounts of micrometer-scale tantalum fuel metal. Such energetic composite powders were ignition-tested and results show that the powders are not sensitive to friction, spark and/or impact ignition. Initial consolidation experiments, using the High Pressure Spark Plasma Sintering (HPSPS) technique, on the SG derived nanostructured tungsten oxide produced samples with higher relative density than can be achieved with commercially available tungsten oxide. The SG derived nanostructured tungsten oxide with immobilized tantalum fuel metal (Ta - WO3) energetic composite was consolidated to a density of 9.17 g·cm-3 or 93% relative density. In addition, those samples were consolidated without significant pre-reaction of the constituents, thus retaining their stored chemical energy.

  7. The momentum of an electromagnetic wave inside a dielectric derived from the Snell refraction law

    SciTech Connect (OSTI)

    Torchigin, V.P. Torchigin, A.V.

    2014-12-15

    Author of the paper [M. Testa, Ann. Physics 336 (2013) 1] has derived a conclusion that there is a connection between the Snell refraction law and the Abraham form of the momentum of light in matter. In other words, author derived the Snell law on assumption that the momentum of light in matter decreases by n times as compared with that in free space. The conclusion is derived under assumption that the forces exerted on an optical medium by an electromagnetic field do not distinguish between polarization and free charges. We show that, on the contrary, the Minkowski form of the momentum of light in matter directly follows from the Snell law. No previous assumption is required for this purpose.

  8. Derivative couplings between TDDFT excited states obtained by direct differentiation in the Tamm-Dancoff approximation

    SciTech Connect (OSTI)

    Ou, Qi; Fatehi, Shervin; Alguire, Ethan; Subotnik, Joseph E.; Shao, Yihan

    2014-07-14

    Working within the Tamm-Dancoff approximation, we calculate the derivative couplings between time-dependent density-functional theory excited states by assuming that the Kohn-Sham superposition of singly excited determinants represents a true electronic wavefunction. All Pulay terms are included in our derivative coupling expression. The reasonability of our approach can be established by noting that, for closely separated electronic states in the infinite basis limit, our final expression agrees exactly with the Chernyak-Mukamel expression (with transition densities from response theory). Finally, we also validate our approach empirically by analyzing the behavior of the derivative couplings around the T{sub 1}/T{sub 2} conical intersection of benzaldehyde.

  9. Coal-Derived Liquids to Enable HCCI Technology | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal-Derived Liquids to Enable HCCI Technology Coal-Derived Liquids to Enable HCCI Technology Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). deer07_shade.pdf (117 KB) More Documents & Publications Opportunities for the Early Production of Fischer-Tropsch (F-T) Fuels in the U.S. -- An

  10. Response of Oil Sands Derived Fuels in Diesel HCCI Operation | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Response of Oil Sands Derived Fuels in Diesel HCCI Operation Response of Oil Sands Derived Fuels in Diesel HCCI Operation Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). deer07_bunting.pdf (3.17 MB) More Documents & Publications APBF Effects on Combustion Statistical Overview of

  11. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-04-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

  12. Open-Shell Singlet Character of Stable Derivatives of Nonacene, Hexacene and Teranthene

    SciTech Connect (OSTI)

    Gao, Xingfa; Jiang, Deen; Zhang, Prof. Shengbai; Chen, Zhongfang; Miller, Glen; Hodgson, Jennifer

    2011-01-01

    The electronic ground states of the recently synthesized stable nonacene derivatives (J. Am. Chem. Soc.2010, 132, 1261) are open-shell singlets with a polyradical nature instead of closed-shell singlets as originally assumed, according to the unrestricted broken spin-symmetry density functional theory (UBS-DFT) computations (at B3LYP/6-31G*). It is the bulky protecting groups, not the transfer from the open-shell singlet to closed-shell singlet ground state, that stabilizes these longest characterized acenes. Similar analyses also confirmed the open-shell singlet character of the hexacene and teranthene derivatives.

  13. Low oxygen biomass-derived pyrolysis oils and methods for producing the same

    DOE Patents [OSTI]

    Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

    2013-08-27

    Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

  14. Method for improving the sedimentation and filterability of coal-derived liquids

    DOE Patents [OSTI]

    Katz, Sidney; Rodgers, Billy R.

    1979-01-02

    An improvement in the separation of suspended solids from coal-derived liquids by a separations process in which solids size is a separations parameter is achieved by contacting the coal-derived liquid containing suspended solids with an effective amount of an additive selected from the group of sulfuric acid, phosphoric acid, phosphoric anhydride and salts of sulfuric and phosphoric acid, and maintaining the contacted liquid at a temperature within the range of about 150.degree.-400.degree. C and for a time sufficient to achieve the desired separation rate.

  15. Process for stabilizing the viscosity characteristics of coal derived materials and the stabilized materials obtained thereby

    DOE Patents [OSTI]

    Bronfenbrenner, James C.; Foster, Edward P.; Tewari, Krishna

    1985-01-01

    A process is disclosed for stabilizing the viscosity of coal derived materials such as an SRC product by adding up to 5.0% by weight of a light volatile phenolic viscosity repressor. The viscosity will remain stabilized for a period of time of up to 4 months.

  16. Impact study on the use of biomass-derived fuels in gas turbines for power generation

    SciTech Connect (OSTI)

    Moses, C.A.; Bernstein, H.

    1994-01-01

    This report evaluates the properties of fuels derived from biomass, both gaseous and liquid, against the fuel requirements of gas turbine systems for gernating electrical power. The report attempts to be quantitative rather than merely qualitative to establish the significant variations in the properties of biomass fuels from those of conventional fuels. Three general categories are covered: performance, durability, and storage and handling.

  17. Mathematics, Pricing, Market Risk Management and Trading Strategies for Financial Derivatives (3/3)

    SciTech Connect (OSTI)

    2009-11-06

    IR and Long Term FX Derivatives - Stochastic Martingales for IR Curves - Implied Volatility Along the IR Curve - IR Libor Bonds - Vanilla IR Options: Caplets, Floorlets - Long Term FX Options: Interaction of Stochastic FX and Stochastic IR - $-Yen Bermudan Power Reverse Duals

  18. St. Petersburg, FL: Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids

    Broader source: Energy.gov [DOE]

    Breakout Session 3A—Conversion Technologies III: Energy from Our Waste—Will we Be Rich in Fuel or Knee Deep in Trash by 2025? St. Petersburg, FL: Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids William Eleazer, Supervising Engineer, Brown and Caldwell

  19. Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels

    SciTech Connect (OSTI)

    Gormley, R.J.; Link, D.D.; Baltrus, J.P.; Zandhuis, P.H.

    2008-01-01

    A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber o-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile o-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived fuel as did both the fuel and additive for a synthetic F-T jet fuel additized with benzyl alcohol, but less for the unadditized synthetic fuel. The specific compounds or classes of compounds involved in the partitioning were identified and a semiquantitative comparison of relative partitioning of the compounds of interest was made. The results provide another step forward in improving the confidence level of using additized, fuIly synthetic jet fuel in the place of petroleum-derived fueL

  20. Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels

    SciTech Connect (OSTI)

    Gormley, R.J.; Link, D.D.; Baltrus, J.P.; Zandhuis, P.H.

    2009-01-01

    A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber a-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile a-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived fuel as did both the fuel and additive for a synthetic F-T jet fuel additized with benzyl alcohol, but less for the unadditized synthetic fuel. The specific compounds or classes of compounds involved in the partitioning were identified and a semiquantitative comparison of relative partitioning of the compounds of interest was made. The results provide another step forward in improving the confidence level of using additized, fully synthetic jet fuel in the place of petroleum-derived fuel.

  1. Nickel(II) and copper(II) complexes with humic acid anions and their derivatives

    SciTech Connect (OSTI)

    Ryabova, I.N.

    2008-01-15

    Complexation of Ni(II) and Cu(II) in aqueous solutions with anions of humic acids, extracted from naturally oxidized coal, and with their hydroxymethyl derivatives is studied spectrophotometrically and potentiometrically. The complexation stoichiometry and the stability constants of the complexes are determined.

  2. Mathematics, Pricing, Market Risk Management and Trading Strategies for Financial Derivatives (3/3)

    ScienceCinema (OSTI)

    None

    2011-10-06

    IR and Long Term FX Derivatives - Stochastic Martingales for IR Curves - Implied Volatility Along the IR Curve - IR Libor Bonds - Vanilla IR Options: Caplets, Floorlets - Long Term FX Options: Interaction of Stochastic FX and Stochastic IR - $-Yen Bermudan Power Reverse Duals

  3. SEP Request for Approval Form 2 - Other Derived Energy Sources | Department

    Broader source: Energy.gov (indexed) [DOE]

    of Energy 2_Other-Derived-Energy-Sources.docx (38.18 KB) More Documents & Publications SEP Request for Approval Form 3 - Other Complex Regression Model Rationale Superior Energy Performance Enrollment and Application Forms SEP Request for Approval Form 7 - Other Situations for Consumption Adjustment

  4. Revisiting the chemical reactivity indices as the state function derivatives. The role of classical chemical hardness

    SciTech Connect (OSTI)

    Malek, Ali; Balawender, Robert

    2015-02-07

    The chemical reactivity indices as the equilibrium state-function derivatives are revisited. They are obtained in terms of the central moments (fluctuation formulas). To analyze the role of the chemical hardness introduced by Pearson [J. Am. Chem. Soc. 105, 7512 (1983)], the relations between the derivatives up to the third-order and the central moments are obtained. As shown, the chemical hardness and the chemical potential are really the principal indices of the chemical reactivity theory. It is clear from the results presented here that the chemical hardness is not the derivative of the Mulliken chemical potential (this means also not the second derivative of the energy at zero-temperature limit). The conventional quadratic dependence of energy, observed at finite temperature, reduces to linear dependence on the electron number at zero-temperature limit. The chemical hardness plays a double role in the admixture of ionic states to the reference neutral state energy: it determines the amplitude of the admixture and regulates the damping of its thermal factor.

  5. Renormalization of Supersymmetric Gauge Theories on Orbifolds: Brane Gauge Couplings and Higher Derivative Operators

    SciTech Connect (OSTI)

    Groot Nibbelink, S.; Hillenbach, M.

    2005-12-02

    We review an explicit calculation of the renormalization of a vector multiplet due to hyper multiplets on the orbifolds S1/Z2 and T2/ZN. We find that generically the fixed point gauge couplings renormalize except at Z2 fixed points. In the six dimensional case on T2/ZN also a bulk dimension six higher derivative operator is induced.

  6. Webinar: An Overview of NREL’s Online Data Tool for Fuel Cell System-Derived Contaminants

    Broader source: Energy.gov [DOE]

    The Fuel Cell Technologies Office will present a webinar on the National Renewable Energy Laboratory's online data tool for fuel cell system-derived contaminants.

  7. Indentation-Derived Elastic Modulus of Multilayer Thin Films. Effect of Unloading Induced Plasticity.

    SciTech Connect (OSTI)

    Jamison, Ryan Dale; Shen, Yu-Lin

    2015-08-13

    Nanoindentation is useful for evaluating the mechanical properties, such as elastic modulus, of multilayer thin film materials. A fundamental assumption in the derivation of the elastic modulus from nanoindentation is that the unloading process is purely elastic. In this work, the validity of elastic assumption as it applies to multilayer thin films is studied using the finite element method. The elastic modulus and hardness from the model system are compared to experimental results to show validity of the model. Plastic strain is shown to increase in the multilayer system during the unloading process. Additionally, the indentation-derived modulus of a monolayer material shows no dependence on unloading plasticity while the modulus of the multilayer system is dependent on unloading-induced plasticity. Lastly, the cyclic behavior of the multilayer thin film is studied in relation to the influence of unloading-induced plasticity. Furthermore, it is found that several cycles are required to minimize unloading-induced plasticity.

  8. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-04-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

  9. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-06-30

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the seventh report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 31, 2005. This quarter saw progress in these areas. These areas are: (1) Steam reformer transient response, (2) Heat transfer enhancement, (3) Catalyst degradation, (4) Catalyst degradation with bluff bodies, and (5) Autothermal reforming of coal-derived methanol. All of the projects are proceeding on or slightly ahead of schedule.

  10. Solids precipitation and polymerization of asphaltenes in coal-derived liquids

    DOE Patents [OSTI]

    Kydd, Paul H.

    1984-01-01

    The precipitation and removal of particulate solids from coal-derived liquids by adding a process-derived anti-solvent liquid fraction and continuing the precipitation process at a temperature above the melting point of the mixed liquids for sufficient time to allow the asphaltenes to polymerize and solids to settle at atmospheric pressure conditions. The resulting clarified light hydrocarbon overflow liquid contains less than about 0.02 W % ash and is suitable as turbine fuel or as boiler fuel for burning without particulate emission control equipment. An underflow liquid fraction containing less than about 0.1 W % solids along with low sulfur and nitrogen concentrations is suitable as a boiler fuel with emission control equipment.

  11. Derivation of uranium residual radioactive material guidelines for the former Alba Craft Laboratory site, Oxford, Ohio

    SciTech Connect (OSTI)

    Nimmagadda, M.; Faillace, E.; Yu, C.

    1994-01-01

    Residual radioactive material guidelines for uranium were derived for the former Alba Craft Laboratory site in Oxford, Ohio. This site has been identified for remedial action under the Formerly Utilized Sites Remedial Action Program (FUSRAP) of the US Department of Energy (DOE). Single nuclide and total uranium guidelines were derived on the basis of the requirement that the 50-year committed effective dose equivalent to a hypothetical individual who lives or works in the immediate vicinity of the former Alba Craft Laboratory site should not exceed a dose of 30 mrem/yr following remedial action for the current use and likely future use scenarios or a dose of 100 mrem/yr for less likely future use scenarios (Yu et al. 1993). The DOE residual radioactive material guideline computer code, RESRAD, which implements the methodology described in the DOE manual for implementing residual radioactive material guidelines, was used in this evaluation.

  12. Bone regeneration by implantation of adipose-derived stromal cells expressing BMP-2

    SciTech Connect (OSTI)

    Li Huiwu; Dai Kerong . E-mail: krdai@163.com; Tang Tingting; Zhang Xiaoling; Yan Mengning; Lou Jueren

    2007-05-18

    In this study, we reported that the adipose-derived stromal cells (ADSCs) genetically modified by bone morphogenetic protein 2 (BMP-2) healed critical-sized canine ulnar bone defects. First, the osteogenic and adipogenic differentiation potential of the ADSCs derived from canine adipose tissue were demonstrated. And then the cells were modified by the BMP-2 gene and the expression and bone-induction ability of BMP-2 were identified. Finally, the cells modified by BMP-2 gene were applied to a {beta}-tricalcium phosphate (TCP) carrier and implanted into ulnar bone defects in the canine model. After 16 weeks, radiographic, histological, and histomorphometry analysis showed that ADSCs modified by BMP-2 gene produced a significant increase of newly formed bone area and healed or partly healed all of the bone defects. We conclude that ADSCs modified by the BMP-2 gene can enhance the repair of critical-sized bone defects in large animals.

  13. An Empirical Method for deriving RBE values associated with Electrons, Photons and Radionuclides

    SciTech Connect (OSTI)

    Bellamy, Michael B; Eckerman, Keith F; Hertel, Nolan

    2015-01-01

    There is substantial evidence to justify using relative biological effectiveness (RBE) values greater than one for low-energy electrons and photons. But, in the field of radiation protection, radiation associated with low linear energy transfer (LET) has been assigned a radiation weighting factor $w_R$ of one. This value may be suitable for radiation protection but, for risk considerations, it is important to evaluate the potential elevated biological effectiveness of radiation to improve the quality of risk estimates. RBE values between 2 and 3 for tritium are implied by several experimental measurements. Additionally, elevated RBE values have been found for other similar low-energy radiation sources. In this work, RBE values are derived for electrons based upon the fractional deposition of absorbed dose of energies less than a few keV. Using this empirical method, RBE values were also derived for monoenergetic photons and 1070 radionuclides from ICRP Publication 107 for which photons and electrons are the primary emissions.

  14. Indentation-derived elastic modulus of multilayer thin films: Effect of unloading induced plasticity

    SciTech Connect (OSTI)

    Jamison, Ryan Dale; Shen, Yu -Lin

    2015-08-13

    Nanoindentation is useful for evaluating the mechanical properties, such as elastic modulus, of multilayer thin film materials. A fundamental assumption in the derivation of the elastic modulus from nanoindentation is that the unloading process is purely elastic. In this work, the validity of elastic assumption as it applies to multilayer thin films is studied using the finite element method. The elastic modulus and hardness from the model system are compared to experimental results to show validity of the model. Plastic strain is shown to increase in the multilayer system during the unloading process. Additionally, the indentation-derived modulus of a monolayer material shows no dependence on unloading plasticity while the modulus of the multilayer system is dependent on unloading-induced plasticity. Lastly, the cyclic behavior of the multilayer thin film is studied in relation to the influence of unloading-induced plasticity. Furthermore, it is found that several cycles are required to minimize unloading-induced plasticity.

  15. Method for Implementing Subsurface Solid Derived Concentration Guideline Levels (DCGL) - 12331

    SciTech Connect (OSTI)

    Lively, J.W.

    2012-07-01

    The U.S. Nuclear Regulatory Commission (NRC) and other federal agencies currently approve the Multi-Agency Radiation Site Survey and Investigation Manual (MARSSIM) as guidance for licensees who are conducting final radiological status surveys in support of decommissioning. MARSSIM provides a method to demonstrate compliance with the applicable regulation by comparing residual radioactivity in surface soils with derived concentration guideline levels (DCGLs), but specifically discounts its applicability to subsurface soils. Many sites and facilities undergoing decommissioning contain subsurface soils that are potentially impacted by radiological constituents. In the absence of specific guidance designed to address the derivation of subsurface soil DCGLs and compliance demonstration, decommissioning facilities have attempted to apply DCGLs and final status survey techniques designed specifically for surface soils to subsurface soils. The decision to apply surface soil limits and surface soil compliance metrics to subsurface soils typically results in significant over-excavation with associated cost escalation. MACTEC, Inc. has developed the overarching concepts and principles found in recent NRC decommissioning guidance in NUREG 1757 to establish a functional method to derive dose-based subsurface soil DCGLs. The subsurface soil method developed by MACTEC also establishes a rigorous set of criterion-based data evaluation metrics (with analogs to the MARSSIM methodology) that can be used to demonstrate compliance with the developed subsurface soil DCGLs. The method establishes a continuum of volume factors that relate the size and depth of a volume of subsurface soil having elevated concentrations of residual radioactivity with its ability to produce dose. The method integrates the subsurface soil sampling regime with the derivation of the subsurface soil DCGL such that a self-regulating optimization is naturally sought by both the responsible party and regulator

  16. Fitting FFT-derived spectra: Theory, tool, and application to solar radio spike decomposition

    SciTech Connect (OSTI)

    Nita, Gelu M.; Fleishman, Gregory D.; Gary, Dale E.; Marin, William; Boone, Kristine

    2014-07-10

    Spectra derived from fast Fourier transform (FFT) analysis of time-domain data intrinsically contain statistical fluctuations whose distribution depends on the number of accumulated spectra contributing to a measurement. The tail of this distribution, which is essential for separating the true signal from the statistical fluctuations, deviates noticeably from the normal distribution for a finite number of accumulations. In this paper, we develop a theory to properly account for the statistical fluctuations when fitting a model to a given accumulated spectrum. The method is implemented in software for the purpose of automatically fitting a large body of such FFT-derived spectra. We apply this tool to analyze a portion of a dense cluster of spikes recorded by our FASR Subsystem Testbed instrument during a record-breaking event that occurred on 2006 December 6. The outcome of this analysis is briefly discussed.

  17. Observed galaxy number counts on the lightcone up to second order: II. Derivation

    SciTech Connect (OSTI)

    Bertacca, Daniele; Maartens, Roy; Clarkson, Chris E-mail: roy.maartens@gmail.com

    2014-11-01

    We present a detailed derivation of the observed galaxy number over-density on cosmological scales up to second order in perturbation theory. We include all relativistic effects that arise from observing on the past lightcone. The derivation is in a general gauge, and applies to all dark energy models (including interacting dark energy) and to metric theories of modified gravity. The result will be important for accurate cosmological parameter estimation, including non-Gaussianity, since all projection effects need to be taken into account. It also offers the potential for new probes of General Relativity, dark energy and modified gravity. This paper accompanies Paper I which presents the key results for the concordance model in Poisson gauge.

  18. Validation of Cloud Properties Derived from GOES-9 Over the ARM TWP Region

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Properties Derived from GOES-9 Over the ARM TWP Region M. M. Khaiyer, M. L. Nordeen, D. R. Doelling, and V. Chakrapani Analytical Services and Materials, Inc. Hampton, Virginia P. Minnis and W. L. Smith, Jr. Atmospheric Sciences National Aeronautic and Space Administration Langley Research Center Hampton, Virginia Introduction Satellite data are essential for monitoring clouds and radiative fluxes where ground-based instruments are unavailable. On April 24, 2003, the ninth geostationary

  19. Validation of Satellite-Derived Liquid Water Paths Using ARM SGP Microwave Radiometers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Satellite-Derived Liquid Water Paths Using ARM SGP Microwave Radiometers M. M. Khaiyer and J. Huang Analytical Services & Materials, Inc. Hampton, Virginia P. Minnis, B. Lin, and W. L. Smith, Jr. National Aeronautics and Space Administration Langley Research Center Hampton, Virginia A. Fan Science Applications International Corporation Hampton, Virginia A. Rapp Colorado State University Fort Collins, Colorado Introduction Satellites are useful for monitoring climatological parameters over

  20. Microphysical Properties of Single and Mixed-Phase Arctic Clouds Derived from AERI Observations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microphysical Properties of Single and Mixed-Phase Arctic Clouds Derived from AERI Observations D. D. Turner University of Wisconsin-Madison Madison, Wisconsin and Pacific Northwest National Laboratory Richland, Washington Abstract A novel new approach to retrieve cloud microphysical properties from mixed-phase clouds is presented. This algorithm retrieves cloud optical depth, ice fraction, and the effective size of the water and ice particles from ground-based, high-resolution infrared radiance

  1. Initial operating results of coal-fired steam generators converted to 100% refuse-derived fuel

    SciTech Connect (OSTI)

    Barsin, J.A. ); Graika, P.K. ); Gonyeau, J.A. ); Bloomer, T.M. )

    1988-01-01

    The conversion of Northern States Power Company's (NSP) Red Wing and Wilmarth steam generators to fire refuse-derived fuel (RDF) is discussed. The use of the existing plant with the necessary modifications to the boilers has allowed NSP to effectively incinerate the fuel as required by Washington and Ramsey Counties. This paper covers the six-month start-up of Red Wing No. 1, commencing in May 1987, and the operating results since the plant went commercial in July 1987.

  2. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Pressure Steam Reforming of Bio-Derived Liquids S. Ahmed, S. Lee, D. Papadias, and R. Kumar November 6, 2007 Laurel, MD Research sponsored by the Hydrogen, Fuel Cells, and Infrastructure Technologies Program of DOE's Office of Energy Efficiency and Renewable Energy Rationale and objective Rationale „ Steam reforming of liquid fuels at high pressures can reduce hydrogen compression costs - Much less energy is needed to pressurize liquids (fuel and water) than compressing gases (reformate or

  3. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    DOE Patents [OSTI]

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2016-07-05

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  4. Synthetic Metabolic Pathways for Bioconversion of Lignin Derivatives to Biofuels Presentation for BETO Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Synthetic Metabolic Pathways for Bioconversion of Lignin Derivatives to Biofuels WBS: 2.3.2.104 March 25, 2015 Technology Area Review: Biochemical Conversion Principal Investigator: Adam M. Guss Organization: Oak Ridge National Laboratory 2 Goal Statement * Goal: Develop microbial biocatalysts to convert lignin-rich streams into value-added products * Relevance: Adding value to the lignin fraction of plant biomass will improve the economics of biorefineries to enable a bioeconomy Fuels +

  5. Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels

    SciTech Connect (OSTI)

    2010-07-01

    The University of Alabama will develop fuel-flexible, low-emissions burner technology for the metal processing industry that is capable of using biomass-derived liquid fuels, such as glycerin or fatty acids, as a substitute for natural gas. By replacing a fossil fuel with biomass fuels, this new burner will enable a reduction in energy consumption and greenhouse gas emissions and an increase in fuel flexibility.

  6. Study on third-order nonlinear optical properties of 4-methylsulfanyl chalcone derivatives using picosecond pulses

    SciTech Connect (OSTI)

    D'silva, E.D.; Podagatlapalli, G. Krishna; Venugopal Rao, S.; Dharmaprakash, S.M.

    2012-11-15

    Graphical abstract: Photograph and schematic representation of Z-scan experimental setup used to investigate third order nonlinear properties of the chalcone materials. Highlights: ? Br and NO{sub 2} substituted chalcone derivatives were exposed to picosecond laser pulses. ? Third-order nonlinear optical (NLO) properties were investigated. ? Compounds show promising third-order and optical limiting properties. ? These materials found suitable for electrical and optical applications. -- Abstract: In this paper we present results from the experimental study of third-order nonlinear optical (NLO) properties of three molecules of Br and NO{sub 2} substituted chalcone derivatives namely (2E)-1-(4-bromophenyl)-3-[4(methylsulfanyl)phenyl]prop-2-en-1-one (4Br4MSP), (2E)-1-(3-bromophenyl)-3-[4-(methylsulfanyl) phenyl]prop-2-en-1-one (3Br4MSP) and (2E)-3[4(methylsulfanyl) phenyl]-1-(4-nitrophenyl)prop-2-en-1-one (4N4MSP). The NLO properties have been investigated by Z-scan technique using 2 ps laser pulses at 800 nm. The nonlinear refractive indices, nonlinear absorption coefficient, and the magnitude of third-order susceptibility have been determined. The values obtained are of the order of 10{sup ?7} cm{sup 2}/GW, 10{sup ?3} cm/GW and 10{sup ?14} esu respectively. The molecular second hyperpolarizability for the chalcone derivatives is of the order of 10{sup ?32} esu. The coupling factor, excited state cross section, ground state cross section etc. were determined. The optical limiting (OL) property was studied. The results suggest that the nonlinear properties investigated for present chalcones are comparable with some of the reported chalcone derivatives and can be desirable for NLO applications.

  7. Discrimination of nuclear spin isomers exploiting the excited state dynamics of a quinodimethane derivative

    SciTech Connect (OSTI)

    Obaid, Rana; Kinzel, Daniel; Oppel, Markus González, Leticia

    2014-10-28

    Despite the concept of nuclear spin isomers (NSIs) exists since the early days of quantum mechanics, only few approaches have been suggested to separate different NSIs. Here, a method is proposed to discriminate different NSIs of a quinodimethane derivative using its electronic excited state dynamics. After electronic excitation by a laser field with femtosecond time duration, a difference in the behavior of several quantum mechanical operators can be observed. A pump-probe experimental approach for separating these different NSIs is then proposed.

  8. Posters A Comparison of Model-Simulated Relative Humidity with Satellite-Derived Cloudiness

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Posters A Comparison of Model-Simulated Relative Humidity with Satellite-Derived Cloudiness R. J. Alliss and S. Raman Department of Marine, Earth and Atmospheric Sciences North Carolina State University Raleigh, North Carolina Introduction One of the unresolved problems in climate and numerical weather prediction is the treatment of cloudiness. In the real atmosphere, clouds are interactively linked to dynamical, hydrological, turbulent, and radiative processes over scales ranging from the

  9. Cloud Properties Derived from Visible and Near-infrared Reflectance in the

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Presence of Aerosols Cloud Properties Derived from Visible and Near-infrared Reflectance in the Presence of Aerosols Hofmann, Odele University of Colorado at Boulder Pilewskie, Peter University of Colorado Gore, Warren NASA Ames Research Center Russell, Phil NASA Ames Research Center Livingston, John SRI International Redemann, Jens BAERI/NASA Ames Research Center Bergstrom, Robert Bay Area Environmental Research Institute Platnick, Steven NASA-GSFC Daniel, John NOAA Aeronomy Laboratory

  10. Validation and analysis of microwave-derived rainfall over the tropics. Master's thesis

    SciTech Connect (OSTI)

    Fleishauer, R.P.

    1993-01-01

    A recently developed single channel microwave rain rate retrieval algorithm exists to measure global precipitation over the data-sparse tropical oceans. The objective of this study is to retrieve and validate rainfall using this algorithm, followed by an analysis of the derived rainfall fields. Retrieval consists of applying the algorithm technique to the extraction of four years worth of achieved data from the Electrically Scanning Microwave Radiometer (ESMR) instrument flown aboard the NIMBUS 5 satellite. The Pacific Atoll Raingage Data Set is chosen as a ground truth measure to validate the ESMR-Derived rainfall data against, comparing slope, intercept and correlation between 5 deg x 5 deg area average. Despite limitations imposed by the comparison of point measurements to area-averaged rainfall, results show a 0.80 correlation. Monthly and quarterly climatological mean rainfall estimates are produced, with a consequent analysis of prominent signals, especially in the Intertropical Convergence Zone (ITCZ), South Pacific Convergence Zone (SPCZ) and the Indian monsoon. Latent heat flux is computed, using the ESMR-derived rainfall, and plotted to show qualitatively where seasonal latent thermodynamic energy sources and sinks exist in the atmosphere. A comparison of the summer and winter quarterly composites of the above products with previously compiled climatologies and Outgoing Longwave Radiation (OLR) showed only minor discrepancies in location and intensity, which are discussed in some detail.

  11. Adjusting lidar-derived digital terrain models in coastal marshes based on estimated aboveground biomass density

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Medeiros, Stephen; Hagen, Scott; Weishampel, John; Angelo, James

    2015-03-25

    Digital elevation models (DEMs) derived from airborne lidar are traditionally unreliable in coastal salt marshes due to the inability of the laser to penetrate the dense grasses and reach the underlying soil. To that end, we present a novel processing methodology that uses ASTER Band 2 (visible red), an interferometric SAR (IfSAR) digital surface model, and lidar-derived canopy height to classify biomass density using both a three-class scheme (high, medium and low) and a two-class scheme (high and low). Elevation adjustments associated with these classes using both median and quartile approaches were applied to adjust lidar-derived elevation values closer tomore » true bare earth elevation. The performance of the method was tested on 229 elevation points in the lower Apalachicola River Marsh. The two-class quartile-based adjusted DEM produced the best results, reducing the RMS error in elevation from 0.65 m to 0.40 m, a 38% improvement. The raw mean errors for the lidar DEM and the adjusted DEM were 0.61 ± 0.24 m and 0.32 ± 0.24 m, respectively, thereby reducing the high bias by approximately 49%.« less

  12. Distinct p53 genomic binding patterns in normal and cancer-derived human cells

    SciTech Connect (OSTI)

    Botcheva K.; McCorkle S. R.; McCombie W. R.; Dunn J. J.; Anderson C. W.

    2011-12-15

    We report here genome-wide analysis of the tumor suppressor p53 binding sites in normal human cells. 743 high-confidence ChIP-seq peaks representing putative genomic binding sites were identified in normal IMR90 fibroblasts using a reference chromatin sample. More than 40% were located within 2 kb of a transcription start site (TSS), a distribution similar to that documented for individually studied, functional p53 binding sites and, to date, not observed by previous p53 genome-wide studies. Nearly half of the high-confidence binding sites in the IMR90 cells reside in CpG islands, in marked contrast to sites reported in cancer-derived cells. The distinct genomic features of the IMR90 binding sites do not reflect a distinct preference for specific sequences, since the de novo developed p53 motif based on our study is similar to those reported by genome-wide studies of cancer cells. More likely, the different chromatin landscape in normal, compared with cancer-derived cells, influences p53 binding via modulating availability of the sites. We compared the IMR90 ChIPseq peaks to the recently published IMR90 methylome1 and demonstrated that they are enriched at hypomethylated DNA. Our study represents the first genome-wide, de novo mapping of p53 binding sites in normal human cells and reveals that p53 binding sites reside in distinct genomic landscapes in normal and cancer-derived human cells.

  13. Adjusting lidar-derived digital terrain models in coastal marshes based on estimated aboveground biomass density

    SciTech Connect (OSTI)

    Medeiros, Stephen; Hagen, Scott; Weishampel, John; Angelo, James

    2015-03-25

    Digital elevation models (DEMs) derived from airborne lidar are traditionally unreliable in coastal salt marshes due to the inability of the laser to penetrate the dense grasses and reach the underlying soil. To that end, we present a novel processing methodology that uses ASTER Band 2 (visible red), an interferometric SAR (IfSAR) digital surface model, and lidar-derived canopy height to classify biomass density using both a three-class scheme (high, medium and low) and a two-class scheme (high and low). Elevation adjustments associated with these classes using both median and quartile approaches were applied to adjust lidar-derived elevation values closer to true bare earth elevation. The performance of the method was tested on 229 elevation points in the lower Apalachicola River Marsh. The two-class quartile-based adjusted DEM produced the best results, reducing the RMS error in elevation from 0.65 m to 0.40 m, a 38% improvement. The raw mean errors for the lidar DEM and the adjusted DEM were 0.61 ± 0.24 m and 0.32 ± 0.24 m, respectively, thereby reducing the high bias by approximately 49%.

  14. Spatial disaggregation of satellite-derived irradiance using a high-resolution digital elevation model

    SciTech Connect (OSTI)

    Ruiz-Arias, Jose A.; Tovar-Pescador, Joaquin; Cebecauer, Tomas; Suri, Marcel

    2010-09-15

    Downscaling of the Meteosat-derived solar radiation ({proportional_to}5 km grid resolution) is based on decomposing the global irradiance and correcting the systematic bias of its components using the elevation and horizon shadowing that are derived from the SRTM-3 digital elevation model (3 arc sec resolution). The procedure first applies the elevation correction based on the difference between coarse and high spatial resolution. Global irradiance is split into direct, diffuse circumsolar and diffuse isotropic components using statistical models, and then corrections due to terrain shading and sky-view fraction are applied. The effect of reflected irradiance is analysed only in the theoretical section. The method was applied in the eastern Andalusia, Spain, and the validation was carried out for 22 days on April, July and December 2006 comparing 15-min estimates of the satellite-derived solar irradiance and observations from nine ground stations. Overall, the corrections of the satellite estimates in the studied region strongly reduced the mean bias of the estimates for clear and cloudy days from roughly 2.3% to 0.4%. (author)

  15. Tire-derived carbon composite anodes for sodium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Yunchao; Paranthaman, M. Parans; Akato, Kokouvi; Naskar, Amit K.; Levine, Alan M.; Lee, Richard J.; Kim, Sang-Ok; Zhang, Jinshui; Dai, Sheng; Manthiram, Arumugam

    2016-04-04

    We report that hard-carbon materials are considered as one of the most promising anodes for the emerging sodium-ion batteries. Here, we report a low-cost, scalable waste tire-derived carbon as an anode for sodium-ion batteries (SIBs). The tire-derived carbons obtained by pyrolyzing the acid-treated tire at 1100 °C, 1400 °C and 1600 °C show capacities of 179, 185 and 203 mAh g-1, respectively, after 100 cycles at a current density of 20 mA g-1 in sodium-ion batteries with good electrochemical stability. The portion of the low-voltage plateau region in the charge-discharge curves increases as the heat-treatment temperature increases. The low-voltage plateaumore » is beneficial to enhance the energy density of the full cell. However, this plateau suffers rapid capacity fade at higher current densities. This study provides a new pathway for inexpensive, environmentally benign and value-added waste tire-derived products towards large-scale energy storage applications.« less

  16. Filtering coal-derived oil through a filter media precoated with particles partially solubilized by said oil

    DOE Patents [OSTI]

    Rodgers, Billy R.; Edwards, Michael S.

    1977-01-01

    Solids such as char, ash, and refractory organic compounds are removed from coal-derived liquids from coal liquefaction processes by the pressure precoat filtration method using particles of 85-350 mesh material selected from the group of bituminous coal, anthracite coal, lignite, and devolatilized coals as precoat materials and as body feed to the unfiltered coal-derived liquid.

  17. Sorbents for High Temperature Removal of Arsenic from Coal-Derived Synthesis Gas

    SciTech Connect (OSTI)

    Alptekin, G.O.; Copeland, R.; Dubovik, M.; Gershanovich, Y.

    2002-09-20

    Gasification technologies convert coal and other heavy feedstocks into synthesis gas feed streams that can be used in the production of a wide variety of chemicals, ranging from hydrogen through methanol, ammonia, acetic anhydride, dimethyl ether (DME), methyl tertiary butyl ether (MTBE), high molecular weight liquid hydrocarbons and waxes. Syngas can also be burned directly as a fuel in advanced power cycles to generate electricity with very high efficiency. However, the coal-derived synthesis gas contains a myriad of trace contaminants that may poison the catalysts that are used in the downstream manufacturing processes and may also be regulated in power plant emissions. Particularly, the catalysts used in the conversion of synthesis gas to methanol and other liquid fuels (Fischer-Tropsch liquids) have been found to be very sensitive to the low levels of poisons, especially arsenic, that are present in the synthesis gas from coal. TDA Research, Inc. (TDA) is developing an expendable high capacity, low-cost chemical absorbent to remove arsenic from coal-derived syngas. Unlike most of the commercially available sorbents that physically adsorb arsenic, TDA's sorbent operates at elevated temperatures and removes the arsenic through chemical reaction. The arsenic content in the coal gas stream is reduced to ppb levels with the sorbent by capturing and stabilizing the arsenic gas (As4) and arsenic hydrides (referred to as arsine, AsH3) in the solid state. To demonstrate the concept of high temperature arsenic removal from coal-derived syngas, we carried out bench-scale experiments to test the absorption capacity of a variety of sorbent formulations under representative conditions. Using on-line analysis techniques, we monitored the pre- and post-breakthrough arsine concentrations over different sorbent samples. Some of these samples exhibited pre-breakthrough arsine absorption capacity over 40% wt. (capacity is defined as lb of arsenic absorbed/lb of sorbent), while

  18. Fukushima derived radiocesium in subsistence-consumed northern fur seal and wild celery

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ruedig, Elizabeth; Duncan, Colleen; Dickerson, Bobette; Williams, Michael; Gelatt, Thomas; Bell, Justin; Johnson, Thomas E.

    2015-11-28

    In July 2014, our investigative team traveled to St. Paul Island, Alaska to measure concentrations of radiocesium in wild-caught food products, primarily northern fur seal (Callorhinus ursinus). The 2011 Fukushima Daiichi Nuclear Power Plant accident released radiocesium into the atmosphere and into the western Pacific Ocean; other investigators have detected Fukushima-derived radionuclides in a variety of marine products harvested off the western coast of North America. We tested two subsistence-consumed food products from St. Paul Island, Alaska for Fukushima-derived radionuclides: 54 northern fur seal, and nine putchki (wild celery, Angelica lucida) plants. Individual northern fur seal samples were below minimummore » detectable activity concentrations of 137Cs and 134Cs, but when composited, northern fur seal tissues tested positive for trace quantities of both isotopes. Radiocesium was detected at an activity concentration of 37.2 mBq 134Cs kg-1 f.w. (95% CI: 35.9–38.5) and 141.2 mBq 137Cs kg-1f.w. (95% CI: 135.5–146.8). The measured isotopic ratio, decay-corrected to the date of harvest, was 0.26 (95% CI: 0.25–0.28). The Fukushima nuclear accident released 134Cs and 137Cs in roughly equal quantities, but by the date of harvest in July 2014, this ratio was 0.2774, indicating that this population of seals has been exposed to small quantities of Fukushima-derived radiocesium. Activity concentrations of both 134Cs and 137Cs in putchki were below detection limits, even for composited samples. Northern fur seal is known to migrate between coastal Alaska and Japan and the trace 134Cs in northern fur seal tissue suggests that the population under study had been minimally exposed Fukushima-derived radionuclides. Despite this inference, the radionuclide quantities detected are small and no impact is expected as a result of the measured radiation exposure, either in northern fur seal or human populations consuming this species.« less

  19. Relative performance of rotary and piston engines on synthetic coal-derived gasoline

    SciTech Connect (OSTI)

    Kappos, C.; Rajan, S.

    1989-01-01

    The paper compares the overall power and emissions features and in-cylinder combustion characteristics of a two-rotor Wankel engine and those of a four-cylinder piston engine, with particular reference to thermal efficiency, oxides of nitrogen, unburnt hydrocarbons, exhaust temperature, ignition delay and combustion interval. The study provides insight into the similarities and differences in the mechanisms of pollutant formation and combustion characteristics of rotary and piston engines, while operating on a synthetic coal-derived gasoline. In particular, the shorter ignition delay and longer combustion interval of the rotary engine indicates its suitability for use with lower quality fuels.

  20. Challenges in Catalytic Manufacture of Renewable Pyrrolidinones from Fermentation Derived Succinate

    SciTech Connect (OSTI)

    White, James F.; Holladay, Johnathan E.; Zacher, Alan H.; Frye, John G.; Werpy, Todd A.

    2014-09-05

    Fermentation derived succinic acid ammonium salt is an ideal precursor for manufacture of renewable N-methyl pyrrolidinone (NMP) or 2-pyrrolidinone (2P) via heterogeneous catalysis. However, there are many challenges to making this a practical reality. Chief among the challenges is avoiding catalyst poisoning by fermentation by- and co-products. Battelle / Pacific Northwest National Laboratory (PNNL) have developed an economically effective technology strategy for this purpose. The technology is a combination of purely thermal processing, followed by simple catalytic hydrogenation that together avoids catalyst poisoning from fermentation impurities and provides high selectivity and yields of NMP or 2P.

  1. A review of trace element emissions from the combustion of refuse-derived fuel with coal

    SciTech Connect (OSTI)

    Norton, G.A. )

    1992-05-01

    The effects of cocombusting refuse-derived fuel (RDF) with coal on stack emissions of trace elements in the ash stream were reviewed. The large number of variables and uncertainties involved precluded drawing definitive conclusions regarding many of the trace elements. However, it is evident that cocombustion resulted in increased emissions of Cd, Cu, Hg, Pb, and Zn. Emissions of As and Ni tended to decrease when RDF was fired with coal. Modeling studies indicated that ambient levels of trace elements during cocombustion should be within acceptable limits. However, periodic monitoring of Cd, Hg, and Pb may be warranted in some instances.

  2. Natural gas cofiring in a refuse derived fuel incinerator: Results of a field evaluation. Topical report

    SciTech Connect (OSTI)

    Beshai, R.Z.; Hong, C.C.

    1993-10-01

    An evaluation of emissions reduction and improved operation of a municipal solid waste incinerator through natural gas cofiring is presented. A natural gas cofiring system was retrofitted on a refuse derived fuel combustor of the Columbis Solid Waste Reduction Facility in Columbus, Ohio. The field evaluation, conducted between July 6 and August 5, 1992, showed significant improvements in emissions and boiler operations. Carbon monoxide emissions were reduced from the baseline operations range of 530 to 1,950 parts per million to less than 50 ppm. Emissions of carbon dioxide, sulfur dioxide, hydrocarbons, and polychlorinated dibenzo-p-dioxins and furans were also reduced.

  3. Hydrofining of Athabasca derived heavy gas oil over Ni-W and Co-Mo catalysts

    SciTech Connect (OSTI)

    Mann, R.S.; Diaz-real, R.

    1987-01-01

    The hydrotreatment of heavy gas oil derived from Athabasca bitumen was studied in a trickle bed reactor over Ni-W and Co-Mo zeolite catalyst at 350-425/sup 0/C, 3.55 to 10.44 MPa, and LHSV of 1-4. The effects of temperature and liquid flow rates on the product were investigated. ASTM distillation, aniline point, viscosities and densities of the product oil were measured and correlated with various parameters. Activity of the catalysts for hydrodenitrogenation is compared.

  4. Method for the production of cementitious compositions and aggregate derivatives from said compositions

    DOE Patents [OSTI]

    Minnick, L. John

    1981-01-01

    Method for the production of cementitious compositions and aggregate derivatives of said compositions, and cementitious compositions and aggregates produced by said method, wherein fluidized bed combustion residue and pozzolanic material, such as pulverized coal combustion system fly ash, are incorporated in a cementitious mix. The mix is cast into desired shape and cured. If desired, the shape may then be crushed so as to result in a fluidized bed combustion residue-fly ash aggregate material or the shape may be used by itself.

  5. Fukushima derived radiocesium in subsistence-consumed northern fur seal and wild celery

    SciTech Connect (OSTI)

    Ruedig, Elizabeth; Duncan, Colleen; Dickerson, Bobette; Williams, Michael; Gelatt, Thomas; Bell, Justin; Johnson, Thomas E.

    2015-11-28

    In July 2014, our investigative team traveled to St. Paul Island, Alaska to measure concentrations of radiocesium in wild-caught food products, primarily northern fur seal (Callorhinus ursinus). The 2011 Fukushima Daiichi Nuclear Power Plant accident released radiocesium into the atmosphere and into the western Pacific Ocean; other investigators have detected Fukushima-derived radionuclides in a variety of marine products harvested off the western coast of North America. We tested two subsistence-consumed food products from St. Paul Island, Alaska for Fukushima-derived radionuclides: 54 northern fur seal, and nine putchki (wild celery, Angelica lucida) plants. Individual northern fur seal samples were below minimum detectable activity concentrations of 137Cs and 134Cs, but when composited, northern fur seal tissues tested positive for trace quantities of both isotopes. Radiocesium was detected at an activity concentration of 37.2 mBq 134Cs kg-1 f.w. (95% CI: 35.9–38.5) and 141.2 mBq 137Cs kg-1f.w. (95% CI: 135.5–146.8). The measured isotopic ratio, decay-corrected to the date of harvest, was 0.26 (95% CI: 0.25–0.28). The Fukushima nuclear accident released 134Cs and 137Cs in roughly equal quantities, but by the date of harvest in July 2014, this ratio was 0.2774, indicating that this population of seals has been exposed to small quantities of Fukushima-derived radiocesium. Activity concentrations of both 134Cs and 137Cs in putchki were below detection limits, even for composited samples. Northern fur seal is known to migrate between coastal Alaska and Japan and the trace 134Cs in northern fur seal tissue suggests that the population under study had been minimally exposed Fukushima-derived radionuclides. Despite this inference, the radionuclide quantities detected are small and no impact is expected as a result of the measured radiation

  6. APPSPACK 4.0 : asynchronous parallel pattern search for derivative-free optimization.

    SciTech Connect (OSTI)

    Gray, Genetha Anne; Kolda, Tamara Gibson

    2004-12-01

    APPSPACK is software for solving unconstrained and bound constrained optimization problems. It implements an asynchronous parallel pattern search method that has been specifically designed for problems characterized by expensive function evaluations. Using APPSPACK to solve optimization problems has several advantages: No derivative information is needed; the procedure for evaluating the objective function can be executed via a separate program or script; the code can be run in serial or parallel, regardless of whether or not the function evaluation itself is parallel; and the software is freely available. We describe the underlying algorithm, data structures, and features of APPSPACK version 4.0 as well as how to use and customize the software.

  7. Intrinsic and extrinsic defects in a family of coal-derived graphene quantum dots

    SciTech Connect (OSTI)

    Singamaneni, Srinivasa Rao E-mail: tour@rice.edu; Tol, Johan van; Ye, Ruquan; Tour, James M. E-mail: tour@rice.edu

    2015-11-23

    In this letter, we report on the high frequency (239.2 and 336 GHz) electron spin resonance (ESR) studies performed on graphene quantum dots (GQDs), prepared through a wet chemistry route from three types of coal: (a) bituminous, (b) anthracite, and (c) coke; and from non-coal derived GQDs. The microwave frequency-, power-, and temperature-dependent ESR spectra coupled with computer-aided simulations reveal four distinct magnetic defect centers. In bituminous- and anthracite-derived GQDs, we have identified two of them as intrinsic carbon-centered magnetic defect centers (a broad signal of peak to peak width = 697 (10{sup −4} T), g = 2.0023; and a narrow signal of peak to peak width = 60 (10{sup −4} T), g = 2.003). The third defect center is Mn{sup 2+} ({sup 6}S{sub 5/2}, 3d{sup 5}) (signal width = 61 (10{sup −4} T), g = 2.0023, A{sub iso} = 93(10{sup −4} T)), and the fourth defect is identified as Cu{sup 2+} ({sup 2}D{sub 5/2}, 3d{sup 9}) (g{sub ⊥} = 2.048 and g{sub ‖} = 2.279), previously undetected. Coke-derived and non-coal derived GQDs show Mn{sup 2+} and two-carbon related signals, and no Cu{sup 2+} signal. The extrinsic impurities most likely originate from the starting coal. Furthermore, Raman, photoluminescence, and ESR measurements detected no noticeable changes in the properties of the bituminous GQDs after one year. This study highlights the importance of employing high frequency ESR spectroscopy in identifying the (magnetic) defects, which are roadblocks for spin relaxation times of graphene-based materials. These defects would not have been possible to probe by other spin transport measurements.

  8. Digital Instrumentation and Control Failure Events Derivation and Analysis by Frame-Based Technique

    SciTech Connect (OSTI)

    Hui-Wen Huang; Chunkuan Shih [National Tsing Hua University, 101, Section 2, Kuang-Fu Road, Hsinchu, Taiwan 30013 (China); Swu Yih [DML International, 18F-1 295, Section 2 Kuang Fu Road, Hsinchu, Taiwan (China); Yen-Chang Tzeng; Ming-Huei Chen [Institute of Nuclear Energy Research, No. 1000, Wunhua Rd., Jiaan Village, Longtan Township, Taoyuan County 32546, Taiwan (China)

    2006-07-01

    A frame-based technique, including physical frame, logical frame, and cognitive frame, was adopted to perform digital I and C failure events derivation and analysis for generic ABWR. The physical frame was structured with a modified PCTran-ABWR plant simulation code, which was extended and enhanced on the feedwater system, recirculation system, and steam line system. The logical model is structured with MATLAB, which was incorporated into PCTran-ABWR to improve the pressure control system, feedwater control system, recirculation control system, and automated power regulation control system. As a result, the software failure of these digital control systems can be properly simulated and analyzed. The cognitive frame was simulated by the operator awareness status in the scenarios. Moreover, via an internal characteristics tuning technique, the modified PCTran-ABWR can precisely reflect the characteristics of the power-core flow. Hence, in addition to the transient plots, the analysis results can then be demonstrated on the power-core flow map. A number of postulated I and C system software failure events were derived to achieve the dynamic analyses. The basis for event derivation includes the published classification for software anomalies, the digital I and C design data for ABWR, chapter 15 accident analysis of generic SAR, and the reported NPP I and C software failure events. The case study of this research includes (1) the software CMF analysis for the major digital control systems; and (2) postulated ABWR digital I and C software failure events derivation from the actual happening of non-ABWR digital I and C software failure events, which were reported to LER of USNRC or IRS of IAEA. These events were analyzed by PCTran-ABWR. Conflicts among plant status, computer status, and human cognitive status are successfully identified. The operator might not easily recognize the abnormal condition, because the computer status seems to progress normally. However, a well

  9. Hydroxyimino phosphonates in the synthesis of 3-phosphonoalanine and its derivatives

    SciTech Connect (OSTI)

    Mikityuk, A.D.; Strepikheev, Yu.A.; Kashemirov, B.A.; Khokhlov, P.S.

    1987-07-20

    The reactions of (acetoxyimino)(diethoxyphosphinyl)acetic amides and esters with diazomethane are found to go with the insertion of a methylene group in the C-P bond. They open the way to the preparation of various 3-(diethoxyphosphinyl)propionic derivatives with a nitrogen function in the 2 position and also of phosphonomethylated heterocycles. A full analysis is performed of data obtained from the NMR, IR, and electron-impact mass spectra of the reactants and products. Chemical shifts. spin-spin coupling constants, multiplet structures, molecular-ion peaks, and vibrational states are tabulated.

  10. An Empirical Method for deriving RBE values associated with Electrons, Photons and Radionuclides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bellamy, Michael B; Puskin, J.; Eckerman, Keith F.; Hertel, Nolan

    2015-01-01

    There is substantial evidence to justify using relative biological effectiveness (RBE) values greater than one for low-energy electrons and photons. But, in the field of radiation protection, radiation associated with low linear energy transfer (LET) has been assigned a radiation weighting factor wR of one. This value may be suitable for radiation protection but, for risk considerations, it is important to evaluate the potential elevated biological effectiveness of radiation to improve the quality of risk estimates. RBE values between 2 and 3 for tritium are implied by several experimental measurements. Additionally, elevated RBE values have been found for other similarmore » low-energy radiation sources. In this work, RBE values are derived for electrons based upon the fractional deposition of absorbed dose of energies less than a few keV. Using this empirical method, RBE values were also derived for monoenergetic photons and 1070 radionuclides from ICRP Publication 107 for which photons and electrons are the primary emissions.« less

  11. An Empirical Method for deriving RBE values associated with Electrons, Photons and Radionuclides

    SciTech Connect (OSTI)

    Bellamy, Michael B; Puskin, J.; Eckerman, Keith F.; Hertel, Nolan

    2015-01-01

    There is substantial evidence to justify using relative biological effectiveness (RBE) values greater than one for low-energy electrons and photons. But, in the field of radiation protection, radiation associated with low linear energy transfer (LET) has been assigned a radiation weighting factor wR of one. This value may be suitable for radiation protection but, for risk considerations, it is important to evaluate the potential elevated biological effectiveness of radiation to improve the quality of risk estimates. RBE values between 2 and 3 for tritium are implied by several experimental measurements. Additionally, elevated RBE values have been found for other similar low-energy radiation sources. In this work, RBE values are derived for electrons based upon the fractional deposition of absorbed dose of energies less than a few keV. Using this empirical method, RBE values were also derived for monoenergetic photons and 1070 radionuclides from ICRP Publication 107 for which photons and electrons are the primary emissions.

  12. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-09-30

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  13. Lignin-Derived Carbon Fiber as a Co-Product of Refining Cellulosic Biomass

    SciTech Connect (OSTI)

    Langholtz, Matthew H.; Downing, Mark; Graham, Robin Lambert; Baker, Fred S.; Compere, Alicia L.; William L. Griffith; Boeman, Raymond G.; Keller, Martin

    2014-01-15

    Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg-1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%. Using lignin-derived carbon fiber in 15 million vehicles per year in the US could reduce fossil fuel consumption by 2-5 billion liters year-1, reduce CO2 emissions by about 6.7 million Mg year-1, and realize fuel savings through vehicle lightweighting of $700 to $1,600 per Mg biomass processed. The value of fuel savings from vehicle lightweighting becomes economical at carbon fiber price of $6.60 kg-1 under current fuel prices, or $13.20 kg-1 under fuel prices of about $1.16 l-1.

  14. Indentation-derived elastic modulus of multilayer thin films: Effect of unloading induced plasticity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jamison, Ryan Dale; Shen, Yu -Lin

    2015-08-13

    Nanoindentation is useful for evaluating the mechanical properties, such as elastic modulus, of multilayer thin film materials. A fundamental assumption in the derivation of the elastic modulus from nanoindentation is that the unloading process is purely elastic. In this work, the validity of elastic assumption as it applies to multilayer thin films is studied using the finite element method. The elastic modulus and hardness from the model system are compared to experimental results to show validity of the model. Plastic strain is shown to increase in the multilayer system during the unloading process. Additionally, the indentation-derived modulus of a monolayermore » material shows no dependence on unloading plasticity while the modulus of the multilayer system is dependent on unloading-induced plasticity. Lastly, the cyclic behavior of the multilayer thin film is studied in relation to the influence of unloading-induced plasticity. Furthermore, it is found that several cycles are required to minimize unloading-induced plasticity.« less

  15. Generation of insulin-producing cells from gnotobiotic porcine skin-derived stem cells

    SciTech Connect (OSTI)

    Yang, Ji Hoon; Lee, Sung Ho; Heo, Young Tae; Uhm, Sang Jun; Lee, Hoon Taek

    2010-07-09

    A major problem in the treatment of type 1 diabetes mellitus is the limited availability of alternative sources of insulin-producing cells for islet transplantation. In this study, we investigated the effect of bone morphogenetic protein 4 (BMP-4) treatments of gnotobiotic porcine skin-derived stem cells (gSDSCs) on their reprogramming and subsequent differentiation into insulin-producing cells (IPCs). We isolated SDSCs from the ear skin of a gnotobiotic pig. During the proliferation period, the cells expressed stem-cell markers Oct-4, Sox-2, and CD90; nestin expression also increased significantly. The cells could differentiate into IPCs after treatments with activin-A, glucagon-like peptide-1 (GLP-1), and nicotinamide. After 15 days in the differentiation medium, controlled gSDSCs began expressing endocrine progenitor genes and proteins (Ngn3, Neuro-D, PDX-1, NKX2.2, NKX6.1, and insulin). The IPCs showed increased insulin synthesis after glucose stimulation. The results indicate that stem cells derived from the skin of gnotobiotic pigs can differentiate into IPCs under the appropriate conditions in vitro. Our three-stage induction protocol could be applied without genetic modification to source IPCs from stem cells in the skin of patients with diabetes for autologous transplantation.

  16. Derivative discontinuity and exchange-correlation potential of meta-GGAs in density-functional theory

    SciTech Connect (OSTI)

    Eich, F. G.; Hellgren, Maria

    2014-12-14

    We investigate fundamental properties of meta-generalized-gradient approximations (meta-GGAs) to the exchange-correlation energy functional, which have an implicit density dependence via the Kohn-Sham kinetic-energy density. To this purpose, we construct the most simple meta-GGA by expressing the local exchange-correlation energy per particle as a function of a fictitious density, which is obtained by inverting the Thomas-Fermi kinetic-energy functional. This simple functional considerably improves the total energy of atoms as compared to the standard local density approximation. The corresponding exchange-correlation potentials are then determined exactly through a solution of the optimized effective potential equation. These potentials support an additional bound state and exhibit a derivative discontinuity at integer particle numbers. We further demonstrate that through the kinetic-energy density any meta-GGA incorporates a derivative discontinuity. However, we also find that for commonly used meta-GGAs the discontinuity is largely underestimated and in some cases even negative.

  17. Glionitrin A, an antibiotic-antitumor metabolite derived from competitive interaction between abandoned mine microbes

    SciTech Connect (OSTI)

    Park, H.B.; Kown, H.C.; Lee, C.H.; Yang, H.O.

    2009-02-15

    The nutrient conditions present in abandoned coal mine drainages create an extreme environment where defensive and offensive microbial interactions could be critical for survival and fitness. Coculture of a mine drainage-derived Sphingomonas bacterial strain, KMK-001, and a mine drainage-derived Aspergillus fumigatus fungal strain, KMC-901, resulted in isolation of a new diketopiperazine disulfide, glionitrin A (1). Compound 1 was not detected in monoculture broths of KMK-001 or KMC-901. The structure of 1, a (3S,10aS) diketopiperazine disulfide containing a nitro aromatic ring, was based on analysis of MS, NMR, and circular dichroism spectra and confirmed by X-ray crystal data. Glionitrin A displayed significant antibiotic activity against a series of microbes including methicillin-resistant Staphylococcus aureus. An in vitro MTT cytotoxicity assay revealed that 1 had potent submicromolar cytotoxic activity against four human cancer cell lines: HCT-116, A549, AGS, and DU145. The results provide further evidence that microbial coculture can produce novel biologically relevant molecules.

  18. Refuse derived soluble bio-organics enhancing tomato plant growth and productivity

    SciTech Connect (OSTI)

    Sortino, Orazio; Dipasquale, Mauro; Montoneri, Enzo; Tomasso, Lorenzo; Perrone, Daniele G.; Vindrola, Daniela; Negre, Michele; Piccone, Giuseppe

    2012-10-15

    Highlights: Black-Right-Pointing-Pointer Municipal bio-wastes are a sustainable source of bio-based products. Black-Right-Pointing-Pointer Refuse derived soluble bio-organics promote chlorophyll synthesis. Black-Right-Pointing-Pointer Refuse derived soluble bio-organics enhance plant growth and fruit ripening rate. Black-Right-Pointing-Pointer Sustainable chemistry exploiting urban refuse allows sustainable development. Black-Right-Pointing-Pointer Chemistry, agriculture and the environment benefit from biowaste technology. - Abstract: Municipal bio-refuse (CVD), containing kitchen wastes, home gardening residues and public park trimmings, was treated with alkali to yield a soluble bio-organic fraction (SBO) and an insoluble residue. These materials were characterized using elemental analysis, potentiometric titration, and 13C NMR spectroscopy, and then applied as organic fertilizers to soil for tomato greenhouse cultivation. Their performance was compared with a commercial product obtained from animal residues. Plant growth, fruit yield and quality, and soil and leaf chemical composition were the selected performance indicators. The SBO exhibited the best performance by enhancing leaf chlorophyll content, improving plant growth and fruit ripening rate and yield. No product performance-chemical composition relationship could be assessed. Solubility could be one reason for the superior performance of SBO as a tomato growth promoter. The enhancement of leaf chlorophyll content is discussed to identify a possible link with the SBO photosensitizing properties that have been demonstrated in other work, and thus with photosynthetic performance.

  19. Site-Specific Reference Person Parameters and Derived Concentration Standards for the Savannah River Site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stone, Daniel K.; Higley, Kathryn A.; Jannik, G. Timothy

    2014-05-01

    The U.S. Department of Energy Order 458.1 states that the compliance with the 1 mSv annual dose constraint to a member of the public may be demonstrated by calculating dose to the maximally exposed individual (MEI) or to a representative person. Historically, the MEI concept was used for dose compliance at the Savannah River Site (SRS) using adult dose coefficients and adult male usage parameters. For future compliance, SRS plans to use the representative person concept for dose estimates to members of the public. The representative person dose will be based on the reference person dose coefficients from the U.S.more » DOE Derived Concentration Technical Standard and on usage parameters specific to SRS for the reference and typical person. Usage parameters and dose coefficients were determined for inhalation, ingestion and external exposure pathways. The parameters for the representative person were used to calculate and tabulate SRS-specific derived concentration standards (DCSs) for the pathways not included in DOE-STD-1196-2011.« less

  20. Modeling Anti-HIV Activity of HEPT Derivatives Revisited. Multiregression Models Are Not Inferior Ones

    SciTech Connect (OSTI)

    Basic, Ivan; Nadramija, Damir; Flajslik, Mario; Amic, Dragan; Lucic, Bono

    2007-12-26

    Several quantitative structure-activity studies for this data set containing 107 HEPT derivatives have been performed since 1997, using the same set of molecules by (more or less) different classes of molecular descriptors. Multivariate Regression (MR) and Artificial Neural Network (ANN) models were developed and in each study the authors concluded that ANN models are superior to MR ones. We re-calculated multivariate regression models for this set of molecules using the same set of descriptors, and compared our results with the previous ones. Two main reasons for overestimation of the quality of the ANN models in previous studies comparing with MR models are: (1) wrong calculation of leave-one-out (LOO) cross-validated (CV) correlation coefficient for MR models in Luco et al., J. Chem. Inf. Comput. Sci. 37 392-401 (1997), and (2) incorrect estimation/interpretation of leave-one-out (LOO) cross-validated and predictive performance and power of ANN models. More precise and fairer comparison of fit and LOO CV statistical parameters shows that MR models are more stable. In addition, MR models are much simpler than ANN ones. For real testing the predictive performance of both classes of models we need more HEPT derivatives, because all ANN models that presented results for external set of molecules used experimental values in optimization of modeling procedure and model parameters.

  1. Comparison of optically measured and radar-derived horizontal neutral winds. Master's thesis

    SciTech Connect (OSTI)

    Christie, M.S.

    1990-01-01

    Nighttime thermospheric winds for Sondrestrom, Greenland from 11 nights between 1983 and 1988, have been compared to learn about the O(+)-O collision cross section and the high-latitude atomic oxygen density. The horizontal winds in the magnetic meridian were derived indirectly from incoherent-scatter radar (ISR) measurements on ion velocities antiparallel to the magnetic field and directly from Fabry-Perot interferometer (FPI) measurements of Doppler shifts of the (6300-A) emission of atomic oxygen. In deriving the radar winds, the O(+)-O collision cross section, was scaled by a factor of f what was varied from 0.5 to 5.1. On the basis of several arguments the altitude of the 6300-A emission was assumed to be 230 km. The best agreement between the ISR and FPI winds was obtained when f was increased substantially, to between 1.7 and 3.4. If the average peak emission altitude were higher, these factors would be larger; if it were lower, they would be somewhat smaller. However, if the average altitude were substantially lower it would have been more difficult to have obtained agreement between the two techniques.

  2. Results of emissions testing while burning densified refuse derived fuel, Dordt College, Sioux Center, Iowa

    SciTech Connect (OSTI)

    Not Available

    1989-10-01

    Pacific Environmental Services, Inc. provided engineering and source testing services to the Council of Great Lake Governors to support their efforts in promoting the development and utilization of densified refuse derived fuels (d-RDF) and pelletized wastepaper fuels in small steam generating facilities. The emissions monitoring program was designed to provide a complete air emissions profile while burning various refuse derived fuels. The specific goal of this test program was to conduct air emissions tests at Dordt College located in Sioux Center, Iowa and to identify a relationship between fuel types and emission characteristics. The sampling protocol was carried out June 12 through June 20, 1989 on boiler {number sign}4. This unit had been previously modified to burn d-RDF. The boiler was not equipped with any type of air pollution control device so the emissions samples were collected from the boiler exhaust stack on the roof of the boilerhouse. The emissions that were sampled included: particulates; PM{sub 10} particulates; hydrochloric acid; dioxins; furans; polychlorinated biphenyls (PCB); metals and continuous monitors for CO, CO{sub 2}O{sub 2}SO{sub x}NO{sub x} and total hydrocarbons. Grab samples of the fuels were collected, composited and analyzed for heating value, moisture content, proximate and ultimate analysis, ash fusion temperature, bulk density and elemental ash analysis. Grab samples of the boiler ash were also collected and analyzed for total hydrocarbons total dioxins, total furans, total PCBs and heavy metals. 77 figs., 20 tabs.

  3. Carbide-derived carbons - From porous networks to nanotubes and graphene

    SciTech Connect (OSTI)

    Presser, V.; Heon, M.; Gogotsi, Y.

    2011-02-09

    Carbide-derived carbons (CDCs) are a large family of carbon materials derived from carbide precursors that are transformed into pure carbon via physical (e.g., thermal decomposition) or chemical (e.g., halogenation) processes. Structurally, CDC ranges from amorphous carbon to graphite, carbon nanotubes or graphene. For halogenated carbides, a high level of control over the resulting amorphous porous carbon structure is possible by changing the synthesis conditions and carbide precursor. The large number of resulting carbon structures and their tunability enables a wide range of applications, from tribological coatings for ceramics, or selective sorbents, to gas and electrical energy storage. In particular, the application of CDC in supercapacitors has recently attracted much attention. This review paper summarizes key aspects of CDC synthesis, properties, and applications. It is shown that the CDC structure and properties are sensitive to changes of the synthesis parameters. Understanding of processingstructureproperties relationships facilitates tuning of the carbon material to the requirements of a certain application.

  4. Human umbilical cord blood-derived f-macrophages retain pluripotentiality after thrombopoietin expansion

    SciTech Connect (OSTI)

    Zhao Yong . E-mail: yongzhao@uic.edu; Mazzone, Theodore

    2005-11-01

    We have previously characterized a new type of stem cell from human peripheral blood, termed fibroblast-like macrophage (f-M{phi}). Here, using umbilical cord blood as a source, we identified cells with similar characteristics including expression of surface markers (CD14, CD34, CD45, CD117, and CD163), phagocytosis, and proliferative capacity. Further, thrombopoietin (TPO) significantly stimulated the proliferation of cord blood-derived f-M{phi} (CB f-M{phi}) at low dosage without inducing a megakaryocytic phenotype. Additional experiments demonstrated that TPO-expanded cord blood-derived f-M{phi} (TCB f-M{phi}) retained their surface markers and differentiation ability. Treatment with vascular endothelial cell growth factor (VEGF) gave rise to endothelial-like cells, expressing Flt-1, Flk-1, von Willebrand Factor (vWF), CD31, acetylated low density lipoprotein internalization, and the ability to form endothelial-like cell chains. In the presence of lipopolyssacharide (LPS) and 25 mM glucose, the TCB f-M{phi} differentiated to express insulin mRNA, C-peptide, and insulin. In vitro functional analysis demonstrated that these insulin-positive cells could release insulin in response to glucose and other secretagogues. These findings demonstrate a potential use of CB f-M{phi} and may lead to develop new therapeutic strategy for treating dominant disease.

  5. Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

    SciTech Connect (OSTI)

    Steven Markovich

    2010-06-30

    This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

  6. Deriving Daytime Variables From the AmeriFlux Standard Eddy Covariance Data Set

    SciTech Connect (OSTI)

    van Ingen, Catharine; Agarwal, Deborah A.; Humphrey, Marty; Li, Jie

    2008-12-06

    A gap-filled, quality assessed eddy covariance dataset has recently become available for the AmeriFluxnetwork. This dataset uses standard processing and produces commonly used science variables. This shared dataset enables robust comparisons across different analyses. Of course, there are many remaining questions. One of those is how to define 'during the day' which is an important concept for many analyses. Some studies have used local time for example 9am to 5pm; others have used thresholds on photosynthetic active radiation (PAR). A related question is how to derive quantities such as the Bowen ratio. Most studies compute the ratio of the averages of the latent heat (LE) and sensible heat (H). In this study, we use different methods of defining 'during the day' for GPP, LE, and H. We evaluate the differences between methods in two ways. First, we look at a number of statistics of GPP. Second, we look at differences in the derived Bowen ratio. Our goal is not science per se, but rather informatics in support of the science.

  7. Energy and materials flows in the production of olefins and their derivatives

    SciTech Connect (OSTI)

    Gaines, L.L.; Shen, S.Y.

    1980-08-01

    Production of olefins and their derivatives uses almost 3.5% of the oil and gas consumed annually in the United States. It is estimated that their production requires an input energy of 2 Q, which is 50% of the energy used in the production of all petrochemicals. Substantial amounts of this energy could be recovered through recycling. For example, recycling of a single plastic product, polyester soft drink bottles, could have recovered about 0.014 Q in 1979. (About 1.4 Q is used to produce plastic derivatives of olefins). Petrochemical processes use fuels as feedstocks, as well as for process energy, and a portion of this energy is not foregone and can be recovered through combustion of the products. The energy foregone in the production of ethylene is estimated to be 7800 Btu/lb. The energy foregone in plastics production ranges from 12,100 Btu/lb for the new linear low-density polyethylene to 77,200 Btu/lb for nylon 66, which is about 60% of the total energy input for that product. Further investigation of the following areas could yield both material and energy savings in the olefins industry: (1) recycling of petrochemical products to recover energy in addition to that recoverable through combustion, (2) impact of feedstock substitution on utilization of available national resources, and (3) effective use of the heat embodied in process steam. This steam accounts for a major fraction of the industry's energy input.

  8. Use of bark-derived pyrolysis oils ass a phenol substitute in structural panel adhesives

    SciTech Connect (OSTI)

    Louisiana Pacific Corp

    2004-03-01

    The main objective of this program was to pilot the world's first commercial-scale production of an acceptable phenol formaldehyde (PF) resin containing natural resin (NR) ingredients, for use as an adhesive in Oriented-Strand Board (OSB) and plywood panel products. Natural Resin products, specifically MNRP are not lignin ''fillers''. They are chemically active, natural phenolics that effectively displace significant amounts of phenol in PF resins, and which are extracted from bark-derived and wood-derived bio-oils. Other objectives included the enhancement of the economics of NR (MNRP) production by optimizing the production of certain Rapid Thermal Processing (RTP{trademark}) byproducts, particularly char and activated carbon. The options were to activate the char for use in waste-water and/or stack gas purification. The preliminary results indicate that RTP{trademark} carbon may ultimately serve as a feedstock for activated carbon synthesis, as a fuel to be used within the wood product mill, or a fuel for an electrical power generating facility. Incorporation of the char as an industrial heat source for use in mill operations was L-P's initial intention for the carbon, and was also of interest to Weyerhaeuser as they stepped into in the project.

  9. Separation and characterization of coal derived components. Quarterly report, July 1-September 30, 1983

    SciTech Connect (OSTI)

    Hurtubise, R.J.; Silver, H.F.

    1983-10-17

    The field-ionization mass spectral hydrocarbon data from F-45 (Wyodak coal-derived SRC) and F-51 (Kentucky 9/14 coal-derived SRC) were recalculated so the various hydrocarbon fractions could be compared directly on a weight percent basis. A computer program was developed which allows the field-ionization mass spectral hydrocarbon data to be compared in a three dimensional fashion. This approach provides for a rapid general comparson of all the field-ionization hydrocarbon data. The solubility of preasphaltenes was tested in several solvents. The preasphaltenes-2 were found to be largely soluble in pyridine:chloroform 9:1(v/v) or 7:3(v/v) and pyridine:chloroform:tetrahydrofuran 7:1:2(v/v/v). Experiments were carried out in which Chromasorb T was tested as a replacement for Fluoropak in the Fluoropak-basic alumina procedure. The results indicated Chromasorb T would be an adequate substitute for Fluoropak, but additional experiments will be run to confirm this. The chromatographic characteristics of numerous hydroxyl aromatics, nitrogen heterocycles, and aromatic amines were obtained on several normal-phase and reversed-phase high-performance liquid chromatographic systems. 30 references, 30 figures, 10 tables.

  10. Structural basis for selective targeting of leishmanial ribosomes: Aminoglycoside derivatives as promising therapeutics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shalev, Moran; Rozenberg, Haim; Smolkin, Boris; Nasereddin, Abedelmajeed; Kopelyanskiy, Dmitry; Belakhov, Valery; Schrepfer, Thomas; Schacht, Jochen; Jaffe, Charles L.; Adir, Noam; et al

    2015-08-11

    Leishmaniasis comprises an array of diseases caused by pathogenic species of Leishmania, resulting in a spectrum of mild to life-threatening pathologies. Currently available therapies for leishmaniasis include a limited selection of drugs. This coupled with the rather fast emergence of parasite resistance, presents a dire public health concern. Paromomycin (PAR), a broad-spectrum aminoglycoside antibiotic, has been shown in recent years to be highly efficient in treating visceral leishmaniasis (VL)—the life-threatening form of the disease. While much focus has been given to exploration of PAR activities in bacteria, its mechanism of action in Leishmania has received relatively little scrutiny and hasmore » yet to be fully deciphered. In the present study we present an X-ray structure of PAR bound to rRNA model mimicking its leishmanial binding target, the ribosomal A-site. We evaluate PAR inhibitory actions on leishmanial growth and ribosome function, as well as effects on auditory sensory cells, by comparing several structurally related natural and synthetic aminoglycoside derivatives. The results provide insights into the structural elements important for aminoglycoside inhibitory activities and selectivity for leishmanial cytosolic ribosomes, highlighting a novel synthetic derivative, compound 3, as a prospective therapeutic candidate for the treatment of VL.« less

  11. Structural basis for selective targeting of leishmanial ribosomes: Aminoglycoside derivatives as promising therapeutics

    SciTech Connect (OSTI)

    Shalev, Moran; Rozenberg, Haim; Smolkin, Boris; Nasereddin, Abedelmajeed; Kopelyanskiy, Dmitry; Belakhov, Valery; Schrepfer, Thomas; Schacht, Jochen; Jaffe, Charles L.; Adir, Noam; Baasov, Timor

    2015-08-11

    Leishmaniasis comprises an array of diseases caused by pathogenic species of Leishmania, resulting in a spectrum of mild to life-threatening pathologies. Currently available therapies for leishmaniasis include a limited selection of drugs. This coupled with the rather fast emergence of parasite resistance, presents a dire public health concern. Paromomycin (PAR), a broad-spectrum aminoglycoside antibiotic, has been shown in recent years to be highly efficient in treating visceral leishmaniasis (VL)—the life-threatening form of the disease. While much focus has been given to exploration of PAR activities in bacteria, its mechanism of action in Leishmania has received relatively little scrutiny and has yet to be fully deciphered. In the present study we present an X-ray structure of PAR bound to rRNA model mimicking its leishmanial binding target, the ribosomal A-site. We evaluate PAR inhibitory actions on leishmanial growth and ribosome function, as well as effects on auditory sensory cells, by comparing several structurally related natural and synthetic aminoglycoside derivatives. The results provide insights into the structural elements important for aminoglycoside inhibitory activities and selectivity for leishmanial cytosolic ribosomes, highlighting a novel synthetic derivative, compound 3, as a prospective therapeutic candidate for the treatment of VL.

  12. Site-Specific Reference Person Parameters and Derived Concentration Standards for the Savannah River Site

    SciTech Connect (OSTI)

    Stone, Daniel K.; Higley, Kathryn A.; Jannik, G. Timothy

    2014-05-01

    The U.S. Department of Energy Order 458.1 states that the compliance with the 1 mSv annual dose constraint to a member of the public may be demonstrated by calculating dose to the maximally exposed individual (MEI) or to a representative person. Historically, the MEI concept was used for dose compliance at the Savannah River Site (SRS) using adult dose coefficients and adult male usage parameters. For future compliance, SRS plans to use the representative person concept for dose estimates to members of the public. The representative person dose will be based on the reference person dose coefficients from the U.S. DOE Derived Concentration Technical Standard and on usage parameters specific to SRS for the reference and typical person. Usage parameters and dose coefficients were determined for inhalation, ingestion and external exposure pathways. The parameters for the representative person were used to calculate and tabulate SRS-specific derived concentration standards (DCSs) for the pathways not included in DOE-STD-1196-2011.

  13. Methodology for modeling the devolatilization of refuse-derived fuel from thermogravimetric analysis of municipal solid waste components

    SciTech Connect (OSTI)

    Fritsky, K.J.; Miller, D.L.; Cernansky, N.P.

    1994-09-01

    A methodology was introduced for modeling the devolatilization characteristics of refuse-derived fuel (RFD) in terms of temperature-dependent weight loss. The basic premise of the methodology is that RDF is modeled as a combination of select municipal solid waste (MSW) components. Kinetic parameters are derived for each component from thermogravimetric analyzer (TGA) data measured at a specific set of conditions. These experimentally derived parameters, along with user-derived parameters, are inputted to model equations for the purpose of calculating thermograms for the components. The component thermograms are summed to create a composite thermogram that is an estimate of the devolatilization for the as-modeled RFD. The methodology has several attractive features as a thermal analysis tool for waste fuels. 7 refs., 10 figs., 3 tabs.

  14. Solution-Derived Bi(ZnTi)O3 - BaTiO3 Thin Films with Bulk-like...

    Office of Scientific and Technical Information (OSTI)

    Title: Solution-Derived Bi(ZnTi)O3 - BaTiO3 Thin Films with Bulk-like Permittivity. Abstract not provided. Authors: Meyer, Kelsey Elizabeth ; Kotula, Paul Gabriel ; Brennecka, ...

  15. Inter-Comparison and Synergy Between the Two Long-Term Gloval Aerosol Products Derived from AVHRR and TOMS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inter-Comparison and Synergy Between the Two Long-Term Global Aerosol Products Derived from AVHRR and TOMS M.-J. Jeong and Z. Li Department of Meteorology University of Maryland College Park, Maryland D. A. Chu and S.-C. Tsay National Aeronautics and Space Administration Goddard Flight Center Greenbelt, Maryland Introduction Eighteen years of satellite-based monthly aerosol products have been derived from the advanced very high resolution radiometer (AVHRR) and total ozone mapping experiment

  16. Biomass-derived Syngas Utilization for Fuels and Chemicals - Final Report

    SciTech Connect (OSTI)

    Dayton, David C

    2010-03-24

    Executive Summary The growing gap between petroleum production and demand, mounting environmental concerns, and increasing fuel prices have stimulated intense interest in research and development (R&D) of alternative fuels, both synthetic and bio-derived. Currently, the most technically defined thermochemical route for producing alternative fuels from lignocellulosic biomass involves gasification/reforming of biomass to produce syngas (carbon monoxide [CO] + hydrogen [H2]), followed by syngas cleaning, Fischer-Tropsch synthesis (FTS) or mixed alcohol synthesis, and some product upgrading via hydroprocessing or separation. A detailed techno-economic analysis of this type of process has recently been published [1] and it highlights the need for technical breakthroughs and technology demonstration for gas cleanup and fuel synthesis. The latter two technical barrier areas contribute 40% of the total thermochemical ethanol cost and 70% of the production cost, if feedstock costs are factored out. Developing and validating technologies that reduce the capital and operating costs of these unit operations will greatly reduce the risk for commercializing integrated biomass gasification/fuel synthesis processes for biofuel production. The objective of this project is to develop and demonstrate new catalysts and catalytic processes that can efficiently convert biomass-derived syngas into diesel fuel and C2-C4 alcohols. The goal is to improve the economics of the processes by improving the catalytic activity and product selectivity, which could lead to commercialization. The project was divided into 4 tasks: Task 1: Reactor Systems: Construction of three reactor systems was a project milestone. Construction of a fixed-bed microreactor (FBR), a continuous stirred tank reactor (CSTR), and a slurry bubble column reactor (SBCR) were completed to meet this milestone. Task 2: Iron Fischer-Tropsch (FT) Catalyst: An attrition resistant iron FT catalyst will be developed and tested

  17. Classification of subsurface objects using singular values derived from signal frames

    DOE Patents [OSTI]

    Chambers, David H; Paglieroni, David W

    2014-05-06

    The classification system represents a detected object with a feature vector derived from the return signals acquired by an array of N transceivers operating in multistatic mode. The classification system generates the feature vector by transforming the real-valued return signals into complex-valued spectra, using, for example, a Fast Fourier Transform. The classification system then generates a feature vector of singular values for each user-designated spectral sub-band by applying a singular value decomposition (SVD) to the N.times.N square complex-valued matrix formed from sub-band samples associated with all possible transmitter-receiver pairs. The resulting feature vector of singular values may be transformed into a feature vector of singular value likelihoods and then subjected to a multi-category linear or neural network classifier for object classification.

  18. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-04-01

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

  19. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, James P.; Scahill, John W.; Chum, Helena L.; Evans, Robert J.; Rejai, Bahman; Bain, Richard L.; Overend, Ralph P.

    1996-01-01

    A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

  20. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

    1996-04-02

    A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

  1. XRF and leaching characterization of waste glasses derived from wastewater treatment sludges

    SciTech Connect (OSTI)

    Ragsdale, R.G., Jr

    1994-12-01

    Purpose of this study was to investigate use of XRF (x-ray fluorescence spectrometry) as a near real-time method to determine melter glass compositions. A range of glasses derived from wastewater treatment sludges associated with DOE sites was prepared. They were analyzed by XRF and wet chemistry digestion with atomic absorption/inductively coupled emission spectrometry. Results indicated good correlation between these two methods. A rapid sample preparation and analysis technique was developed and demonstrated by acquiring a sample from a pilot-scale simulated waste glass melter and analyzing it by XRF within one hour. From the results, XRF shows excellent potential as a process control tool for waste glass vitrification. Glasses prepared for this study were further analyzed for durability by toxicity characteristic leaching procedure and product consistency test and results are presented.

  2. Internal curing with lightweight aggregate produced from biomass-derived waste

    SciTech Connect (OSTI)

    Lura, Pietro; Wyrzykowski, Mateusz; Tang, Clarence; Lehmann, Eberhard

    2014-05-01

    Shrinkage of concrete may lead to cracking and ultimately to a reduction of the service life of concrete structures. Among known methods for shrinkage mitigation, internal curing with porous aggregates was successfully utilized in the last couple of decades for decreasing autogenous and drying shrinkage. In this paper, the internal curing performance of pre-saturated lightweight aggregates produced from biomass-derived waste (bio-LWA) was studied. In the first part of this paper, the microstructure of the bio-LWA is investigated, with special focus on their pore structure and on their water absorption and desorption behavior. The bio-LWA has large porosity and coarse pore structure, which allows them to release the entrained water at early age and counteract self-desiccation and autogenous shrinkage. In the second part, the efficiency of internal curing in mortars incorporating the bio-LWA is examined by neutron tomography, internal relative humidity and autogenous deformation measurements.

  3. Development and evaluation of lime enhanced refuse-derived fuel (RDF) pellets

    SciTech Connect (OSTI)

    Ohlsson, O.O.

    1996-12-31

    The disposal of municipal solid waste (MSW) is of increasing concern for municipalities and state governments throughout the US. There are two technologies currently in use for the combustion of MSW: (1) mass burning in which unprocessed MSW is burned in a heat recovery furnace, and (2) a refuse-derived fuel (RDF) product, which consists of the organic (combustible) fraction of MSW which has been processed to produce a more homogeneous fuel product than raw MSW. The RDF is either marketed to outside users or combusted on-site in a dedicated or existing furnace. In an attempt to alleviate the problems encountered with RDF as a feedstock, Argonne National Laboratory (ANL) and the University of North Texas (UNT) under the sponsorship of the US Department of Energy (DOE) began a multi-phase research study to investigate the development of a low-cost binder that would improve the quality of RDF pellets.

  4. Chlorinated organic compounds evolved during the combustion of blends of refuse-derived fuels and coals

    SciTech Connect (OSTI)

    Xiaodong Yang; Napier, J.; Sisk, B.; Wei-Ping Pan; Riley, J.T.; Lloyd, W.G.

    1996-12-31

    The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR and MS systems. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GUMS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic; compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.

  5. Co-firing high sulfur coal with refuse derived fuels. Quarterly report, October - December 1996

    SciTech Connect (OSTI)

    Pan, W.-P.; Riley, J.T.; Lloyd, W.G.

    1996-12-01

    The objectives of this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the effect of S0{sub 2} on the formation of chlorine during combustion processes was examined. To simulate the conditions used in the AFBC system, experiments were conducted in a quartz tube in an electrically heated furnace. The principle analytical technique used for identification of the products from this study was GC/MS. The evolved gas was trapped by an absorbent and analyzed with a GC/MS system. The preliminary results indicate an inhibiting effect of S0{sub 2} on the Deacon Reaction. Secondly, information on the evolution of chlorine, sulfur and organic compounds from coals 95031 and 95011 were studied with the AFBC system. 2 figs., 1 tab.

  6. Sulfur dioxide capture in the combustion of mixtures of lime, refuse-derived fuel, and coal

    SciTech Connect (OSTI)

    Churney, K.L.; Buckley, T.J. . Center for Chemical Technology)

    1990-06-01

    Chlorine and sulfur mass balance studies have been carried out in the combustion of mixtures of lime, refuse-derived fuel, and coal in the NIST multikilogram capacity batch combustor. The catalytic effect of manganese dioxide on the trapping of sulfur dioxide by lime was examined. Under our conditions, only 4% of the chlorine was trapped in the ash and no effect of manganese dioxide was observed. Between 42 and 14% of the total sulfur was trapped in the ash, depending upon the lime concentration. The effect of manganese dioxide on sulfur capture was not detectable. The temperature of the ash was estimated to be near 1200{degrees}C, which was in agreement with that calculated from sulfur dioxide capture thermodynamics. 10 refs., 12 figs., 10 tabs.

  7. Steam gasification of tyre waste, poplar, and refuse-derived fuel: A comparative analysis

    SciTech Connect (OSTI)

    Galvagno, S. Casciaro, G.; Casu, S.; Martino, M.; Mingazzini, C.; Russo, A.; Portofino, S.

    2009-02-15

    In the field of waste management, thermal disposal is a treatment option able to recover resources from 'end of life' products. Pyrolysis and gasification are emerging thermal treatments that work under less drastic conditions in comparison with classic direct combustion, providing for reduced gaseous emissions of heavy metals. Moreover, they allow better recovery efficiency since the process by-products can be used as fuels (gas, oils), for both conventional (classic engines and heaters) and high efficiency apparatus (gas turbines and fuel cells), or alternatively as chemical sources or as raw materials for other processes. This paper presents a comparative study of a steam gasification process applied to three different waste types (refuse-derived fuel, poplar wood and scrap tyres), with the aim of comparing the corresponding yields and product compositions and exploring the most valuable uses of the by-products.

  8. Pulse transmission receiver with higher-order time derivative pulse generator

    DOE Patents [OSTI]

    Dress, Jr., William B.; Smith, Stephen F.

    2003-08-12

    Systems and methods for pulse-transmission low-power communication modes are disclosed. A pulse transmission receiver includes: a front-end amplification/processing circuit; a synchronization circuit coupled to the front-end amplification/processing circuit; a clock coupled to the synchronization circuit; a trigger signal generator coupled to the clock; and at least one higher-order time derivative pulse generator coupled to the trigger signal generator. The systems and methods significantly reduce lower-frequency emissions from pulse transmission spread-spectrum communication modes, which reduces potentially harmful interference to existing radio frequency services and users and also simultaneously permit transmission of multiple data bits by utilizing specific pulse shapes.

  9. Using a derivative-free optimization method for multiple solutions of inverse transport problems

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Armstrong, Jerawan C.; Favorite, Jeffrey A.

    2016-01-14

    Identifying unknown components of an object that emits radiation is an important problem for national and global security. Radiation signatures measured from an object of interest can be used to infer object parameter values that are not known. This problem is called an inverse transport problem. An inverse transport problem may have multiple solutions and the most widely used approach for its solution is an iterative optimization method. This paper proposes a stochastic derivative-free global optimization algorithm to find multiple solutions of inverse transport problems. The algorithm is an extension of a multilevel single linkage (MLSL) method where a meshmore » adaptive direct search (MADS) algorithm is incorporated into the local phase. Furthermore, numerical test cases using uncollided fluxes of discrete gamma-ray lines are presented to show the performance of this new algorithm.« less

  10. Cloud properties derived from two lidars over the ARM SGP site

    SciTech Connect (OSTI)

    Dupont, Jean-Charles; Haeffelin, Martial; Morille, Y.; Comstock, Jennifer M.; Flynn, Connor J.; Long, Charles N.; Sivaraman, Chitra; Newsom, Rob K.

    2011-02-16

    [1] Active remote sensors such as lidars or radars can be used with other data to quantify the cloud properties at regional scale and at global scale (Dupont et al., 2009). Relative to radar, lidar remote sensing is sensitive to very thin and high clouds but has a significant limitation due to signal attenuation in the ability to precisely quantify the properties of clouds with a 20 cloud optical thickness larger than 3. In this study, 10-years of backscatter lidar signal data are analysed by a unique algorithm called STRucture of ATmosphere (STRAT, Morille et al., 2007). We apply the STRAT algorithm to data from both the collocated Micropulse lidar (MPL) and a Raman lidar (RL) at the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site between 1998 and 2009. Raw backscatter lidar signal is processed and 25 corrections for detector deadtime, afterpulse, and overlap are applied. (Campbell et al.) The cloud properties for all levels of clouds are derived and distributions of cloud base height (CBH), top height (CTH), physical cloud thickness (CT), and optical thickness (COT) from local statistics are compared. The goal of this study is (1) to establish a climatology of macrophysical and optical properties for all levels of clouds observed over the ARM SGP site 30 and (2) to estimate the discrepancies induced by the two remote sensing systems (pulse energy, sampling, resolution, etc.). Our first results tend to show that the MPLs, which are the primary ARM lidars, have a distinctly limited range where all of these cloud properties are detectable, especially cloud top and cloud thickness, but even actual cloud base especially during summer daytime period. According to the comparisons between RL and MPL, almost 50% of situations show a signal to noise ratio too low (smaller than 3) for the MPL in order to detect clouds higher than 7km during daytime period in summer. Consequently, the MPLderived annual cycle of cirrus cloud base (top) altitude is

  11. Thermal Properties of Wood-Derived Copper-Silicon Carbide Compsites Fabricated Via Electrodeposition

    SciTech Connect (OSTI)

    Pappacena, Kristen E; Johnson, M. T.; Wang, Hsin; Porter, Wallace D; Faber, K. T.

    2010-01-01

    Copper-silicon carbide composites were fabricated by electrodeposition of copper into pores of wood-derived silicon carbide, a ceramic with a microstructure that can be tailored via the use of different wood precursors. Thermal conductivity values were determined using flash diffusivity at temperatures from 0 to 900 C. Thermal conductivities of up to 202 W/m K at 0 C and 148 W/mK at 900 C were achieved. Object-oriented finite-element analysis (OOF) modeling was used to understand the heat flux distributions throughout the microstructures. OOF was also used to calculate the effective thermal conductivity, which correlated well with experimentally-determined values for axially-oriented composites. In addition, OOF was used to predict effective conductivity values and heat flux distributions for transversely-oriented composites.

  12. The Hydrological Sensitivity to Global Warming and Solar Geoengineering Derived from Thermodynamic Constraints

    SciTech Connect (OSTI)

    Kleidon, Alex; Kravitz, Benjamin S.; Renner, Maik

    2015-01-16

    We derive analytic expressions of the transient response of the hydrological cycle to surface warming from an extremely simple energy balance model in which turbulent heat fluxes are constrained by the thermodynamic limit of maximum power. For a given magnitude of steady-state temperature change, this approach predicts the transient response as well as the steady-state change in surface energy partitioning and the hydrologic cycle. We show that the transient behavior of the simple model as well as the steady state hydrological sensitivities to greenhouse warming and solar geoengineering are comparable to results from simulations using highly complex models. Many of the global-scale hydrological cycle changes can be understood from a surface energy balance perspective, and our thermodynamically-constrained approach provides a physically robust way of estimating global hydrological changes in response to altered radiative forcing.

  13. Trends in characteristics of hazardous waste-derived fuel burned for energy recovery in cement kilns

    SciTech Connect (OSTI)

    Lusk, M.G.; Campbell, C.S.

    1996-12-31

    The Cement Kiln Recycling Coalition (CKRC) is a national trade association representing virtually all the U.S. cement companies involved in the use of waste-derived fuel in the cement manufacturing process as well as those companies involved in the collection, processing, managing, and marketing of such fuel. CKRC, in conjunction with the National Association of Chemical Recyclers (NACR), completed several data collection activities over the past two years to provide the Environmental Protection Agency (EPA) and other interested parties with industry-wide trend analyses. The analyses evaluated the content of specific metals in waste fuels utilized by cement kilns, average Btu value of substitute fuels used by kilns, and provides insight into the trends of these properties. With the exception of the data collected by NACR, the study did not evaluate materials sent to hazardous waste incinerators or materials that are combusted at {open_quotes}on-site{close_quotes} facilities.

  14. A thermogravimetric analysis of catalytic hydroprocessing of a coal-derived liquid

    SciTech Connect (OSTI)

    Song, X.; Lu, S.; Fu, H.; Dalla Lana, I.G.

    1995-12-31

    Thermogravimetric analysis (TGA) has normally been used to study thermal behaviours of solid materials. The extension of this technique to materials in fluid phases is less common. So far there have been very few reports dealing with the application of TGA to solid-catalyzed gas-phase reaction system. Massoth and Cowley described the use of a stirred flow microbalance in studying the catalytic hydrogenation of 1-butane under steady-state reaction conditions. More recently, TGA was combined with techniques such as online MS or GC analysis to study catalytic reactions. However, the use of TGA in studying a solid-catalyzed gas-liquid reaction, especially when the liquid is a relatively non-volatile complex feedstock, is very limited. Results are described on the use of TGA in the hydroprocessing of a coal derived liquid.

  15. System for adjusting frequency of electrical output pulses derived from an oscillator

    DOE Patents [OSTI]

    Bartholomew, David B.

    2006-11-14

    A system for setting and adjusting a frequency of electrical output pulses derived from an oscillator in a network is disclosed. The system comprises an accumulator module configured to receive pulses from an oscillator and to output an accumulated value. An adjustor module is configured to store an adjustor value used to correct local oscillator drift. A digital adder adds values from the accumulator module to values stored in the adjustor module and outputs their sums to the accumulator module, where they are stored. The digital adder also outputs an electrical pulse to a logic module. The logic module is in electrical communication with the adjustor module and the network. The logic module may change the value stored in the adjustor module to compensate for local oscillator drift or change the frequency of output pulses. The logic module may also keep time and calculate drift.

  16. Total Ozone Mapping Spectrometer (TOMS) Derived Data, Global Earth Coverage (GEC) from NASA's Earth Probe Satellite

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    This is data from an external datastream processed through the ARM External Data Center (XDC) at Brookhaven National Laboratory. The XDC identifies sources and acquires data, called "external data", to augment the data being generated within the ARM program. The external data acquired are usually converted from native format to either netCDF or HDF formats. The GEC collection contains global data derived from the Total Ozone Mapping Spectrometer (TOMS) instrument on the Earth Probe satellite, consisting of daily values of aerosol index, ozone and reflectivity remapped into a regular 1x1.25 deg grid. Data are available from July 25, 1996 - December 31, 2005, but have been updated or replaced as of September 2007. See the explanation on the ARM web site at http://www.arm.gov/xds/static/toms.stm and the information at the NASA/TOMS web site: http://toms.gsfc.nasa.gov/ (Registration required)

  17. Evaluation of coal-derived liquids as boiler fuels. Volume 2: boiler test results. Final report

    SciTech Connect (OSTI)

    Not Available

    1985-09-01

    A combustion demonstration using six coal-derived liquid (CDL) fuels was conducted on a utility boiler located at the Plant Sweatt Electric Generating Station of Mississippi Power Company in Meridian, Mississippi. The test program was conducted in two phases. The first phase included the combustion tests of the two conventional fuels (natural gas and No. 6 fuel oil) and three coal-derived liquid fuels (Solvent Refined Coal-II full range distillate, H-Coal heavy distillate and H-Coal blended distillate). The second phase involved the evaluation of three additional CDL fuels (H-Coal light distillate, Exxon Donor Solvent full range distillate and Solvent Refined Coal-II middle distillate). The test boiler was a front wall-fired Babcock and Wilcox unit with a rated steam flow of 425,000 lb/h and a generating capacity of 40 MW. Boiler performance and emissions were evaluated with baseline and CDL fuels at 15, 25, 40 MW loads and at various excess air levels. Low NO/sub x/ (staged) combustion techniques were also implemented. Boiler performance monitoring included measurements for fuel steam and flue gas flow, pressure, temperature, and heat absorption, resulting in a calculated combustion efficiency, boiler efficiency, and heat rate. Emissions measurements included oxygen, carbon dioxide, carbon monoxide, oxides of nitrogen, sulfur dioxide, sulfur trioxide, acid dewpoint, particulate mass, size distribution and morphology, chlorides, and opacity. The test program demonstrated the general suitability of CDL fuels for use in existing oil-fired utility boilers. No significant boiler tube surface modifications will be required. The CDL fuels could be handled similarly to No. 2 oil with appropriate safety procedures and materials compatibility considerations. Volume 2 of a five-volume report contains the detailed boiler test results. 96 figs., 26 tabs.

  18. A comparative theoretical study on core-hole excitation spectra of azafullerene and its derivatives

    SciTech Connect (OSTI)

    Deng, Yunfeng; Department of Physics, Guizhou University, Guiyang 550025 ; Gao, Bin; Centre for Theoretical and Computational Chemistry , Department of Chemistry, University of Tromsø—The Arctic University of Norway, N-9037 Tromsø ; Deng, Mingsen; Luo, Yi; Department of Theoretical Chemistry, School of Biotechnology, Royal Institute of Technology, SE-10691 Stockholm

    2014-03-28

    The core-hole excitation spectra—near-edge x-ray absorption spectroscopy (NEXAFS), x-ray emission spectroscopy (XES), and x-ray photoelectron spectroscopy (XPS) shake-up satellites have been simulated at the level of density functional theory for the azafullerene C{sub 59}N and its derivatives (C{sub 59}N){sup +}, C{sub 59}HN, (C{sub 59}N){sub 2}, and C{sub 59}N–C{sub 60}, in which the XPS shake-up satellites were simulated using our developed equivalent core hole Kohn-Sham (ECH-KS) density functional theory approach [B. Gao, Z. Wu, and Y. Luo, J. Chem. Phys. 128, 234704 (2008)] which aims for the study of XPS shake-up satellites of large-scale molecules. Our calculated spectra are generally in good agreement with available experimental results that validates the use of the ECH-KS method in the present work. The nitrogen K-edge NEXAFS, XES, and XPS shake-up satellites spectra in general can be used as fingerprints to distinguish the azafullerene C{sub 59}N and its different derivatives. Meanwhile, different carbon K-edge spectra could also provide detailed information of (local) electronic structures of different molecules. In particular, a peak (at around 284.5 eV) in the carbon K-edge NEXAFS spectrum of the heterodimer C{sub 59}N–C{sub 60} is confirmed to be related to the electron transfer from the C{sub 59}N part to the C{sub 60} part in this charge-transfer complex.

  19. SL-01, an oral derivative of gemcitabine, inhibited human breast cancer growth through induction of apoptosis

    SciTech Connect (OSTI)

    Li, Yuan-Yuan; Qin, Yi-Zhuo; Wang, Rui-Qi; Li, Wen-Bao; Qu, Xian-Jun

    2013-08-23

    Highlights: •SL-01 is an oral derivative of gemcitabine. •SL-01 possessed activity against human breast cancer growth via apoptotic induction. •SL-01’s activity was more potently than that of gemcitabine. •SL-01 inhibited cancer growth without toxicity to mice. -- Abstract: SL-01 is an oral derivative of gemcitabine that was synthesized by introducing the moiety of 3-(dodecyloxycarbonyl) pyrazine-2-carbonyl at N4-position on cytidine ring of gemcitabine. We aimed to evaluate the efficacy of SL-01 on human breast cancer growth. SL-01 significantly inhibited MCF-7 proliferation as estimated by colorimetric assay. Flow cytometry assay indicated the apoptotic induction and cell cycle arrest in G1 phase. SL-01 modulated the expressions of p-ATM, p53 and p21 and decrease of cyclin D1 in MCF-7 cells. Further experiments were performed in a MCF-7 xenografts mouse model. SL-01 by oral administration strongly inhibited MCF-7 xenografts growth. This effect of SL-01 might arise from its roles in the induction of apoptosis. Immunohistochemistry assay showed the increase of TUNEL staining cells. Western blotting indicated the modulation of apoptotic proteins in SL-01-treated xenografts. During the course of study, there was no evidence of toxicity to mice. In contrast, the decrease of neutrophil cells in peripheral and increase of AST and ALT levels in serum were observed in the gemcitabine-treated mice. Conclusion: SL-01 possessed similar activity against human breast cancer growth with gemcitabine, whereas, with lower toxicity to gemcitabine. SL-01 is a potent oral agent that may supplant the use of gemcitabine.

  20. SL-01, an oral gemcitabine derivative, inhibited human cancer growth more potently than gemcitabine

    SciTech Connect (OSTI)

    Zhao, Cuirong; Yue, Bin; Liu, Huiping; Sun, Cuicui; Li, Wenbao; Qu, Xianjun

    2012-08-01

    SL-01, an oral gemcitabine derivative, was synthesized by introducing the moiety of 3-(dodecyloxycarbonyl)pyrazine-2-carbonyl at the N4-position on the cytidine ring of gemcitabine. Our goal in this study was to evaluate the efficacy of SL-01 on the growth of human cancers with gemcitabine as control. Experiments were performed on human non-small cell lung cancer NCI-H460 and colon cancer HCT-116 both in vitro and in vivo. In vitro assays, SL-01 significantly inhibited the growth of cancer cells as determined by the 3-[4, 5-dimethylthiazol-2-yl]-2, 5-diphenyltetrazolium bromide (MTT) assay. Further studies indicated that SL-01 induced the cancer cells to apoptosis showing chromatin condensation and externalization of phosphatidylserine. In in vivo studies, we evaluated the efficacy of SL-01 in nude mice bearing human cancer xenografts. SL-01 effectively delayed the growth of NCI-H460 and HCT-116 without significant loss of body weight. Molecular analysis indicated that the high efficacy of SL-01 was associated with its ability to induce apoptosis as evidenced by increase of terminal deoxynucleotidyl transferase-mediated dUTP nick end labeling (TUNEL) staining cells, activation of caspase-9, caspase-3 and cleaved poly ADP-ribose polymerase (PARP) in tumor tissues. SL-01 also increased Bax/Bcl-2 ratio in cancer cells. These biological activities of SL-01 were more potential than that of gemcitabine. Based on these in vitro and in vivo results, SL-01 is proposed as a potent oral anticancer agent that may supplant the use of gemcitabine in the clinic. -- Highlights: ► An oral gemcitabine derivative SL-01 was synthesized. ► The effects of SL-01 were evaluated and its efficacy was compared with gemcitabine. ► The biological activities of SL-01 were more potent than that of gemcitabine. ► SL-01 could replace gemcitabine for clinical use.

  1. Effects of hypergravity on adipose-derived stem cell morphology, mechanical property and proliferation

    SciTech Connect (OSTI)

    Tavakolinejad, Alireza; Rabbani, Mohsen; Janmaleki, Mohsen

    2015-08-21

    Alteration in specific inertial conditions can lead to changes in morphology, proliferation, mechanical properties and cytoskeleton of cells. In this report, the effects of hypergravity on morphology of Adipose-Derived Stem Cells (ADSCs) are indicated. ADSCs were repeatedly exposed to discontinuous hypergravity conditions of 10 g, 20 g, 40 g and 60 g by utilizing centrifuge (three times of 20 min exposure, with an interval of 40 min at 1 g). Cell morphology in terms of length, width and cell elongation index and cytoskeleton of actin filaments and microtubules were analyzed by image processing. Consistent changes observed in cell elongation index as morphological change. Moreover, cell proliferation was assessed and mechanical properties of cells in case of elastic modulus of cells were evaluated by Atomic Force Microscopy. Increase in proliferation and decrease in elastic modulus of cells are further results of this study. Staining ADSC was done to show changes in cytoskeleton of the cells associated to hypergravity condition specifically in microfilament and microtubule components. After exposing to hypergravity, significant changes were observed in microfilaments and microtubule density as components of cytoskeleton. It was concluded that there could be a relationship between changes in morphology and MFs as the main component of the cells. - Highlights: • Hypergravity (10 g, 20 g, 40 g and 60 g) affects on adipose derived stem cells (ADSCs). • ADSCs after exposure to the hypergravity are more slender. • The height of ADSCs increases in all test groups comparing their control group. • Hypergravity decreases ADSCs modulus of elasticity and cell actin fiber content. • Hypergravity enhances proliferation rate of ADSCs.

  2. Thermodynamic model for calorimetric and phase coexistence properties of coal derived fluids. Final technical report

    SciTech Connect (OSTI)

    Kabadi, V.N.

    1992-10-01

    The work on this project was initiated on September 1, 1989. The project consisted of three different tasks. 1. A thermodynamic model to predict VLE and calorimetric properties of coal liquids. 2. VLE measurements at high temperature and high pressure for coal model compounds and 3. Chromatographic characterization of coal liquids for distribution of heteroatoms. The thermodynamic model developed is an extension of the previous model developed for VLE of coal derived fluids (DOE Grant no. FG22-86PC90541). The model uses the modified UNIFAC correlation for the liquid phase. Some unavailable UNIFAC interactions parameters have been regressed from experimental VLE and excess enthalpy data. The model is successful in predicting binary VLE and excess enthalpy data. Further refinements of the model are suggested. An apparatus for the high pressure high temperature VLE data measurements has been built and tested. Tetralin-Quinoline is the first binary system selected for data measurements. The equipment was tested by measuring 325{degree}C isotherm for this system and comparing it with literature data. Additional isotherms at 350{degree}C and 370{degree}C have been measured. The framework for a characterization procedure for coal derived liquids has been developed. A coal liquid is defined by a true molecular weight distribution and distribution of heteroatoms as a function of molecular weights. Size exclusions liquid chromatography, elemental analysis and FTIR spectroscopy methods are used to obtain the molecular weight and hetroatom distributions. Further work in this area should include refinements of the characterization procedure, high temperature high pressure VLE data measurements for selective model compound binary systems, and improvement of the thermodynamic model using the new measured data and consistent with the developments in the characterization procedure.

  3. Radiological Modeling for Determination of Derived Concentration Levels of an Area with Uranium Residual Material - 13533

    SciTech Connect (OSTI)

    Perez-Sanchez, Danyl [CIEMAT, Avenida Complutense 40, 28040, Madrid (Spain)] [CIEMAT, Avenida Complutense 40, 28040, Madrid (Spain)

    2013-07-01

    As a result of a pilot project developed at the old Spanish 'Junta de Energia Nuclear' to extract uranium from ores, tailings materials were generated. Most of these residual materials were sent back to different uranium mines, but a small amount of it was mixed with conventional building materials and deposited near the old plant until the surrounding ground was flattened. The affected land is included in an area under institutional control and used as recreational area. At the time of processing, uranium isotopes were separated but other radionuclides of the uranium decay series as Th-230, Ra-226 and daughters remain in the residue. Recently, the analyses of samples taken at different ground's depths confirmed their presence. This paper presents the methodology used to calculate the derived concentration level to ensure that the reference dose level of 0.1 mSv y-1 used as radiological criteria. In this study, a radiological impact assessment was performed modeling the area as recreational scenario. The modelization study was carried out with the code RESRAD considering as exposure pathways, external irradiation, inadvertent ingestion of soil, inhalation of resuspended particles, and inhalation of radon (Rn-222). As result was concluded that, if the concentration of Ra-226 in the first 15 cm of soil is lower than, 0.34 Bq g{sup -1}, the dose would not exceed the reference dose. Applying this value as a derived concentration level and comparing with the results of measurements on the ground, some areas with a concentration of activity slightly higher than latter were found. In these zones the remediation proposal has been to cover with a layer of 15 cm of clean material. This action represents a reduction of 85% of the dose and ensures compliance with the reference dose. (authors)

  4. Asymmetrical-fan tranmission CT on SPECT to derive {mu}-maps for attenuation correction

    SciTech Connect (OSTI)

    Loncaric, S.; Huang, G.; Ni, B. [Rush-Presbyterian-St. Luke`s Medical Center, Chicago, IL (United States)] [and others

    1994-05-01

    For proper attenuation correction of SPECT images, an appropriate {mu}-map properly registered with each imaging slices is needed. Among the many techniques for {mu}-map derivation, simultaneous or sequential fan-beam transmission CT (TCT), on the same SPECT system with the same acquisition settings, have advantages of being practical while ensuring registration. However, the problems are: (1) limited FOV for thoracic imaging, projection would be truncated with a typical size detector, (2) lack of room for placing the transmission source in many SPECT systems. We have developed a new sampling scheme to solve the problems mentioned above. This scheme uses an asymmetrical-fan geometry (AFG), which samples only half of the field, the other half would be sampled after an 180{degrees} detector rotation. This technique completes the minimum sampling requirement in a 360{degrees} detector rotation and yields a relatively large FOV defined by the outside edge of the sampling fan. We have confirmed the feasibility of the AFG sampling on a 3-head SPECT system to provide a large FOV for TCT of most patient. The TCT sampling scheme is achieved with an asymmetrical-fan collimator. We have developed the required new reconstruction algorithms and derived excellent reconstructed images of phantoms and human subjects. We propose to have this technique implemented in a short and fast transmission scan in a multi-head SPECT system, after emission imaging, because the detectors have to be pulled out to make room for the transmission source. The imaging field can even exceed the full field size of the detector. MS would be possible when an obtuse sampling fan is formed by shifting the source outward further, provided the central FOV is properly covered with a supplementary sampling scheme, e.g., using another TCT with a fan-beam collimator on another one of the detectors.

  5. UNBIASED CORRECTION RELATIONS FOR GALAXY CLUSTER PROPERTIES DERIVED FROM CHANDRA AND XMM-NEWTON

    SciTech Connect (OSTI)

    Zhao, Hai-Hui; Li, Cheng-Kui; Chen, Yong; Jia, Shu-Mei; Song, Li-Ming

    2015-01-20

    We use a sample of 62 clusters of galaxies to investigate the discrepancies between the gas temperature and total mass within r {sub 500} from XMM-Newton and Chandra data. Comparisons of the properties show that (1) both the de-projected and projected temperatures determined by Chandra are higher than those of XMM-Newton and there is a good linear relationship for the de-projected temperatures: T {sub Chandra} = 1.25 × T {sub XMM}–0.13. (2) The Chandra mass is much higher than the XMM-Newton mass with a bias of 0.15 and our mass relation is log{sub 10} M {sub Chandra} = 1.02 × log{sub 10} M {sub XMM}+0.15. To explore the reasons for the discrepancy in mass, we recalculate the Chandra mass (expressed as M{sub Ch}{sup mo/d}) by modifying its temperature with the de-projected temperature relation. The results show that M{sub Ch}{sup mo/d} is closer to the XMM-Newton mass with the bias reducing to 0.02. Moreover, M{sub Ch}{sup mo/d} are corrected with the r {sub 500} measured by XMM-Newton and the intrinsic scatter is significantly improved with the value reducing from 0.20 to 0.12. These mean that the temperature bias may be the main factor causing the mass bias. Finally, we find that M{sub Ch}{sup mo/d} is consistent with the corresponding XMM-Newton mass derived directly from our mass relation at a given Chandra mass. Thus, the de-projected temperature and mass relations can provide unbiased corrections for galaxy cluster properties derived from Chandra and XMM-Newton.

  6. Modeling tropical Pacific sea surface temperature with satellite-derived solar radiative forcing

    SciTech Connect (OSTI)

    Seager, R.; Blumenthal, M.B.

    1994-12-01

    Two independent datasets for the solar radiation at the surface derived from satellites are compared. The data derived from the Earth Radiation Budget Experiment (ERBE) is for the net solar radiation at the surface whereas the International Satellite Cloud Climatology Project (ISCCP) data is for the downward flux only and was corrected with a space- and time-varying albedo. The ISCCP net flux is at all times higher than the ERBE flux. The difference can be divided into an offset that decreases with latitude and another component that correlates with high tropical cloud cover. With this latter exception the two datasets provide spatial patterns of solar flux that are very similar. A tropical Pacific Ocean model is forced with these two datasets and observed climatological winds. The upward heat flux is parameterized taking into account separately the longwave radiative, latent, and sensible heat fluxes. Best fit values for the uncertain parameters are found using an optimization procedure that seeks to minimize the difference between model and observed SST by varying the parameters within a reasonable range of uncertainty. The SST field the model produces with the best fit parameters is the best the model can do. If the differences between the model and data are larger than can be accounted for by remaining uncertainties in the heat flux parameterization and forcing data then the ocean model must be held to be at fault. Using this method of analysis, a fundamental model fault is identified. Inadequate treatment of mixed layer/entrainment processes in upwelling regions of the eastern tropical Pacific leads to a large and seasonally varying error in the model SST. Elsewhere the model SST is insufficiently different from observed to be able to identify model errors.

  7. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Kick-Off Meeting Proceedings Hilton Garden Inn-BWI,Baltimore, MD October 24, 2006

    Broader source: Energy.gov [DOE]

    Proceedings from the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  8. Avian and Bat Assessment at the Lewes Wind Turbine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the advisory committee on February 14, 2013. On the call were Genevieve LaRouche (US Fish & Wildlife Service-USFWS), Julie Thompson (USFWS), Holly Niederriter (Delaware ...

  9. Results from Analysis of Avian Retina Oil Droplets. (Conference...

    Office of Scientific and Technical Information (OSTI)

    Close Cite: Bibtex Format Close 0 pages in this document matching the terms "" Search For Terms: Enter terms in the toolbar above to search the full text of this document for ...

  10. Structure and Receptor Specificity of an Avian Flu Antigen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    combined effects could allow the Viet04 virus to escape entrapment by mucins in the lungs and increase binding to susceptible human epithelial cells. These mutations therefore...

  11. EA-1782: Avian and Bat Surveillance and Assessment Plan Timeline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Given that the project would consist of only one turbine, the report noted that a pre-construction flight-use study could not reliably predict risk. However, the evaluation ...

  12. EA-1782: Avian and Bat Assessment Annual Report | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    that documents the number and identity of bird and bat species that fatally collide with ... Featured Publications from the Bats and Wind Energy Cooperative Monitoring bat and bird ...

  13. The Nocturnal Avian Migration Experiment Final Campaign Report...

    Office of Scientific and Technical Information (OSTI)

    In addition, by taking multichannel recordings of these calls, the position of the calling bird can be calculated and linked to collocated radar measurements. Authors: Stepanian, ...

  14. Structure and Receptor Specificity of an Avian Flu Antigen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Publication about this research: J. Stevens, O. Blixt, T.M. Tumpey, J.K. Taubenberger, J.C. Paulson, and I.A. Wilson, "Structure and receptor specificity of the hemagglutinin from ...

  15. Avian Collisions with Wind Turbines: A Summary of Existing Studies...

    Office of Scientific and Technical Information (OSTI)

    Pesticide use, oil spills, disease, etc., are other significant sources of unintended ... GASES; GREENHOUSE GASES; MORTALITY; OIL SPILLS; PESTICIDES; POLLUTANTS; WIND ...

  16. Session: Monitoring wind turbine project sites for avian impacts

    SciTech Connect (OSTI)

    Erickson, Wally

    2004-09-01

    This third session at the Wind Energy and Birds/Bats workshop consisted of one presentation followed by a discussion/question and answer period. The focus of the session was on existing wind projects that are monitored for their impacts on birds and bats. The presentation given was titled ''Bird and Bat Fatality Monitoring Methods'' by Wally Erickson, West, Inc. Sections included protocol development and review, methodology, adjusting for scavenging rates, and adjusting for observer detection bias.

  17. Testing the Effectiveness of an Avian Flight Diverter for Reducing...

    Open Energy Info (EERE)

    California Abstract Distribution power lines are placed high overhead, safely out of human reach; however, for birds, these overhead wires are a potentially fatal obstacle....

  18. Derivation of site-specific relationships between hydraulic parameters and p-wave velocities based on hydraulic and seismic tomography

    SciTech Connect (OSTI)

    Brauchler, R.; Doetsch, J.; Dietrich, P.; Sauter, M.

    2012-01-10

    In this study, hydraulic and seismic tomographic measurements were used to derive a site-specific relationship between the geophysical parameter p-wave velocity and the hydraulic parameters, diffusivity and specific storage. Our field study includes diffusivity tomograms derived from hydraulic travel time tomography, specific storage tomograms, derived from hydraulic attenuation tomography, and p-wave velocity tomograms, derived from seismic tomography. The tomographic inversion was performed in all three cases with the SIRT (Simultaneous Iterative Reconstruction Technique) algorithm, using a ray tracing technique with curved trajectories. The experimental set-up was designed such that the p-wave velocity tomogram overlaps the hydraulic tomograms by half. The experiments were performed at a wellcharacterized sand and gravel aquifer, located in the Leine River valley near Gttingen, Germany. Access to the shallow subsurface was provided by direct-push technology. The high spatial resolution of hydraulic and seismic tomography was exploited to derive representative site-specific relationships between the hydraulic and geophysical parameters, based on the area where geophysical and hydraulic tests were performed. The transformation of the p-wave velocities into hydraulic properties was undertaken using a k-means cluster analysis. Results demonstrate that the combination of hydraulic and geophysical tomographic data is a promising approach to improve hydrogeophysical site characterization.

  19. SITE SPECIFIC REFERENCE PERSON PARAMETERS AND DERIVED CONCENTRATION STANDARDS FOR THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Jannik, T.

    2013-03-14

    The purpose of this report is twofold. The first is to develop a set of behavioral parameters for a reference person specific for the Savannah River Site (SRS) such that the parameters can be used to determine dose to members of the public in compliance with Department of Energy (DOE) Order 458.1 “Radiation Protection of the Public and the Environment.” A reference person is a hypothetical, gender and age aggregation of human physical and physiological characteristics arrived at by international consensus for the purpose of standardizing radiation dose calculations. DOE O 458.1 states that compliance with the annual dose limit of 100 mrem (1 mSv) to a member of the public may be demonstrated by calculating the dose to the maximally exposed individual (MEI) or to a representative person. Historically, for dose compliance, SRS has used the MEI concept, which uses adult dose coefficients and adult male usage parameters. Beginning with the 2012 annual site environmental report, SRS will be using the representative person concept for dose compliance. The dose to a representative person will be based on 1) the SRS-specific reference person usage parameters at the 95th percentile of appropriate national or regional data, which are documented in this report, 2) the reference person (gender and age averaged) ingestion and inhalation dose coefficients provided in DOE Derived Concentration Technical Standard (DOE-STD-1196-2011), and 3) the external dose coefficients provided in the DC_PAK3 toolbox. The second purpose of this report is to develop SRS-specific derived concentration standards (DCSs) for all applicable food ingestion pathways, ground shine, and water submersion. The DCS is the concentration of a particular radionuclide in water, in air, or on the ground that results in a member of the public receiving 100 mrem (1 mSv) effective dose following continuous exposure for one year. In DOE-STD-1196-2011, DCSs were developed for the ingestion of water, inhalation of

  20. Electron density and electron temperature measurement in a bi-Maxwellian electron distribution using a derivative method of Langmuir probes

    SciTech Connect (OSTI)

    Choi, Ikjin; Chung, ChinWook [Department of Electrical Engineering, Hanyang University, 17 Haengdang-dong, Seongdong-gu, Seoul 133-791 (Korea, Republic of)] [Department of Electrical Engineering, Hanyang University, 17 Haengdang-dong, Seongdong-gu, Seoul 133-791 (Korea, Republic of); Youn Moon, Se [High-Enthalpy Plasma Research Center, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju, Jeollabuk-do 561-756 (Korea, Republic of)] [High-Enthalpy Plasma Research Center, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju, Jeollabuk-do 561-756 (Korea, Republic of)

    2013-08-15

    In plasma diagnostics with a single Langmuir probe, the electron temperature T{sub e} is usually obtained from the slope of the logarithm of the electron current or from the electron energy probability functions of current (I)-voltage (V) curve. Recently, Chen [F. F. Chen, Phys. Plasmas 8, 3029 (2001)] suggested a derivative analysis method to obtain T{sub e} by the ratio between the probe current and the derivative of the probe current at a plasma potential where the ion current becomes zero. Based on this method, electron temperatures and electron densities were measured and compared with those from the electron energy distribution function (EEDF) measurement in Maxwellian and bi-Maxwellian electron distribution conditions. In a bi-Maxwellian electron distribution, we found the electron temperature T{sub e} obtained from the method is always lower than the effective temperatures T{sub eff} derived from EEDFs. The theoretical analysis for this is presented.

  1. Derivative expansion of the effective action for quantum electrodynamics in 2+1 and 3+1 dimensions

    SciTech Connect (OSTI)

    Gusynin, V.P.; Shovkovy, I.A.

    1999-11-01

    The derivative expansion of the one-loop effective action in QED{sub 3} and QED{sub 4} (quantum electrodynamics) is considered. The first term in such an expansion is the effective action for a constant electromagnetic field. An explicit expression for the next term containing two derivatives of the field strength F{sub {mu}{nu}}, but exact in the magnitude of the field strength, is obtained. The general results for both fermion and scalar electrodynamics are presented. The cases of pure electric and pure magnetic external fields are considered in detail. The Feynman technique for the perturbative expansion of the one-loop effective action in the number of derivatives is developed. {copyright} {ital 1999 American Institute of Physics.}

  2. Derivation of a Levelized Cost of Coating (LCOC) metric for evaluation of solar selective absorber materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ho, C. K.; Pacheco, J. E.

    2015-06-05

    A new metric, the Levelized Cost of Coating (LCOC), is derived in this paper to evaluate and compare alternative solar selective absorber coatings against a baseline coating (Pyromark 2500). In contrast to previous metrics that focused only on the optical performance of the coating, the LCOC includes costs, durability, and optical performance for more comprehensive comparisons among candidate materials. The LCOC is defined as the annualized marginal cost of the coating to produce a baseline annual thermal energy production. Costs include the cost of materials and labor for initial application and reapplication of the coating, as well as the costmore » of additional or fewer heliostats to yield the same annual thermal energy production as the baseline coating. Results show that important factors impacting the LCOC include the initial solar absorptance, thermal emittance, reapplication interval, degradation rate, reapplication cost, and downtime during reapplication. The LCOC can also be used to determine the optimal reapplication interval to minimize the levelized cost of energy production. As a result, similar methods can be applied more generally to determine the levelized cost of component for other applications and systems.« less

  3. Derivation of a Levelized Cost of Coating (LCOC) metric for evaluation of solar selective absorber materials

    SciTech Connect (OSTI)

    Ho, C. K.; Pacheco, J. E.

    2015-06-05

    A new metric, the Levelized Cost of Coating (LCOC), is derived in this paper to evaluate and compare alternative solar selective absorber coatings against a baseline coating (Pyromark 2500). In contrast to previous metrics that focused only on the optical performance of the coating, the LCOC includes costs, durability, and optical performance for more comprehensive comparisons among candidate materials. The LCOC is defined as the annualized marginal cost of the coating to produce a baseline annual thermal energy production. Costs include the cost of materials and labor for initial application and reapplication of the coating, as well as the cost of additional or fewer heliostats to yield the same annual thermal energy production as the baseline coating. Results show that important factors impacting the LCOC include the initial solar absorptance, thermal emittance, reapplication interval, degradation rate, reapplication cost, and downtime during reapplication. The LCOC can also be used to determine the optimal reapplication interval to minimize the levelized cost of energy production. As a result, similar methods can be applied more generally to determine the levelized cost of component for other applications and systems.

  4. Biological Production of a Hydrocarbon Fuel Intermediate Polyhydroxybutyrate (Phb) from a Process Relevant Lignocellulosic Derived Sugar

    SciTech Connect (OSTI)

    Wang, Wei; Mohagheghi, Ali; Mittal, Ashutosh; Pilath, Heidi; Johnson, David K.

    2015-03-22

    PHAs are synthesized by many microorganisms to serve as intracellular carbon storage molecules. In some bacterial strains, PHB can account for up to 80% of cell mass. In addition to its application in the packaging sector, PHB also has great potential as an intermediate in the production of hydrocarbon fuels. PHB can be thermally depolymerized and decarboxylated to propene which can be upgraded to hydrocarbon fuels via commercial oligomerization technologies. In recent years a great effort has been made in bacterial production of PHB, yet the production cost of the polymer is still much higher than conventional petrochemical plastics. The high cost of PHB is because the cost of the substrates can account for as much as half of the total product cost in large scale fermentation. Thus searching for cheaper and better substrates is very necessary for PHB production. In this study, we demonstrate production of PHB by Cupriavidus necator from a process relevant lignocellulosic derived sugar stream, i.e., saccharified hydrolysate slurry from pretreated corn stover. Good cell growth was observed on slurry saccharified with advanced enzymes and 40~60% of PHB was accumulated in the cells. The mechanism of inhibition in the toxic hydrolysate generated by pretreatment and saccharification of biomass, will be discussed.

  5. Deriving Arctic Cloud Microphysics at Barrow, Alaska. Algorithms, Results, and Radiative Closure

    SciTech Connect (OSTI)

    Shupe, Matthew D.; Turner, David D.; Zwink, Alexander; Thieman, Mandana M.; Mlawer, Eli J.; Shippert, Timothy

    2015-07-01

    Cloud phase and microphysical properties control the radiative effects of clouds in the climate system and are therefore crucial to characterize in a variety of conditions and locations. An Arctic-specific, ground-based, multi-sensor cloud retrieval system is described here and applied to two years of observations from Barrow, Alaska. Over these two years, clouds occurred 75% of the time, with cloud ice and liquid each occurring nearly 60% of the time. Liquid water occurred at least 25% of the time even in the winter, and existed up to heights of 8 km. The vertically integrated mass of liquid was typically larger than that of ice. While it is generally difficult to evaluate the overall uncertainty of a comprehensive cloud retrieval system of this type, radiative flux closure analyses were performed where flux calculations using the derived microphysical properties were compared to measurements at the surface and top-of-atmosphere. Radiative closure biases were generally smaller for cloudy scenes relative to clear skies, while the variability of flux closure results was only moderately larger than under clear skies. The best closure at the surface was obtained for liquid-containing clouds. Radiative closure results were compared to those based on a similar, yet simpler, cloud retrieval system. These comparisons demonstrated the importance of accurate cloud phase classification, and specifically the identification of liquid water, for determining radiative fluxes. Enhanced retrievals of liquid water path for thin clouds were also shown to improve radiative flux calculations.

  6. Quantum theory as a description of robust experiments: Derivation of the Pauli equation

    SciTech Connect (OSTI)

    De Raedt, Hans; Katsnelson, Mikhail I.; Donker, Hylke C.; Michielsen, Kristel

    2015-08-15

    It is shown that the Pauli equation and the concept of spin naturally emerge from logical inference applied to experiments on a charged particle under the conditions that (i) space is homogeneous (ii) the observed events are logically independent, and (iii) the observed frequency distributions are robust with respect to small changes in the conditions under which the experiment is carried out. The derivation does not take recourse to concepts of quantum theory and is based on the same principles which have already been shown to lead to e.g. the Schrödinger equation and the probability distributions of pairs of particles in the singlet or triplet state. Application to Stern–Gerlach experiments with chargeless, magnetic particles, provides additional support for the thesis that quantum theory follows from logical inference applied to a well-defined class of experiments. - Highlights: • The Pauli equation is obtained through logical inference applied to robust experiments on a charged particle. • The concept of spin appears as an inference resulting from the treatment of two-valued data. • The same reasoning yields the quantum theoretical description of neutral magnetic particles. • Logical inference provides a framework to establish a bridge between objective knowledge gathered through experiments and their description in terms of concepts.

  7. Evaluating lignocellulosic biomass, its derivatives, and downstream products with Raman spectroscopy

    SciTech Connect (OSTI)

    Lupoi, Jason S.; Gjersing, Erica; Davis, Mark F.

    2015-04-20

    The creation of fuels, chemicals, and materials from plants can aid in replacing products fabricated from non-renewable energy sources. Before using biomass in downstream applications, it must be characterized to assess chemical traits, such as cellulose, lignin, or lignin monomer content, or the sugars released following an acid or enzymatic hydrolysis. The measurement of these traits allows researchers to gage the recalcitrance of the plants and develop efficient deconstruction strategies to maximize yields. Standard methods for assessing biomass phenotypes often have experimental protocols that limit their use for screening sizeable numbers of plant species. Raman spectroscopy, a non-destructive, non-invasive vibrational spectroscopy technique, is capable of providing qualitative, structural information and quantitative measurements. Applications of Raman spectroscopy have aided in alleviating the constraints of standard methods by coupling spectral data with multivariate analysis to construct models capable of predicting analytes. Hydrolysis and fermentation products, such as glucose and ethanol, can be quantified off-, at-, or on-line. Raman imaging has enabled researchers to develop a visual understanding of reactions, such as different pretreatment strategies, in real-time, while also providing integral chemical information. Finally, this review provides an overview of what Raman spectroscopy is, and how it has been applied to the analysis of whole lignocellulosic biomass, its derivatives, and downstream process monitoring.

  8. Evaluating lignocellulosic biomass, its derivatives, and downstream products with Raman spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lupoi, Jason S.; Gjersing, Erica; Davis, Mark F.

    2015-04-20

    The creation of fuels, chemicals, and materials from plants can aid in replacing products fabricated from non-renewable energy sources. Before using biomass in downstream applications, it must be characterized to assess chemical traits, such as cellulose, lignin, or lignin monomer content, or the sugars released following an acid or enzymatic hydrolysis. The measurement of these traits allows researchers to gage the recalcitrance of the plants and develop efficient deconstruction strategies to maximize yields. Standard methods for assessing biomass phenotypes often have experimental protocols that limit their use for screening sizeable numbers of plant species. Raman spectroscopy, a non-destructive, non-invasive vibrationalmore » spectroscopy technique, is capable of providing qualitative, structural information and quantitative measurements. Applications of Raman spectroscopy have aided in alleviating the constraints of standard methods by coupling spectral data with multivariate analysis to construct models capable of predicting analytes. Hydrolysis and fermentation products, such as glucose and ethanol, can be quantified off-, at-, or on-line. Raman imaging has enabled researchers to develop a visual understanding of reactions, such as different pretreatment strategies, in real-time, while also providing integral chemical information. Finally, this review provides an overview of what Raman spectroscopy is, and how it has been applied to the analysis of whole lignocellulosic biomass, its derivatives, and downstream process monitoring.« less

  9. Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

    DOE Patents [OSTI]

    Moens, L.

    1995-07-11

    A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350 and 375 C to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan. 2 figs.

  10. Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

    DOE Patents [OSTI]

    Moens, Luc

    1995-01-01

    A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350.degree. and 375.degree. C. to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan.

  11. Superheater corrosion in a boiler fired with refuse-derived fuel

    SciTech Connect (OSTI)

    Blough, J.L.; Stanko, G.J.; Bakker, W.T.; Steinbeck, T.

    1995-12-31

    The environment in the superheater of a boiler firing refuse-derived fuel (RDF) is very aggressive. The high wastage rate for the standard T-22 material necessitated a materials testing program. Simples of Types 304H, HR3C, T-22 chromized, 825 and 625 were assembled into tubular test sections and welded into the superheater tubing. After 1,180 hours the test sections were evaluated and the wastage rates calculated for each material. The chlorides contained in the RDF are believed to be the primary corrodent. The chlorine may be interacting with the metal samples as HCl, a low-melting-point eutectic or a combination of these. Of the six materials tested, Alloy 625 exhibited the best resistance--substantially better than the next-best Type 304. Alloy 825 and HR3C corroded approximately 1.5 times the rate of Type 304. The chromized layer on T-22 showed no resistance to the environment and was consumed in large areas.

  12. Gasification of refuse derived fuel in the Battelle high throughput gasification system

    SciTech Connect (OSTI)

    Paisley, M.A.; Creamer, K.S.; Tweksbury, T.L.; Taylor, D.R. )

    1989-07-01

    This report presents the results of an experimental program to demonstrate the suitability of the Battelle High Throughput Gasification Process to non-wood biomass fuels. An extensive data base on wood gasification was generated during a multi-year experimental program. This data base and subsequent design and economic analysis activities led to the discussion to study the gasification character of other fuels. The specific fuel studied was refuse derived fuel (RDF) which is a prepared municipal solid waste (MSW). The use of RDF, while providing a valuable fuel, can also provide a solution to MSW disposal problems. Gasification of MSW provides advantages over land fill or mass burn technology since a more usable form of energy, medium Btu gas, is produced. Land filling of wastes produces no usable products and mass burning while greatly reducing the volume of wastes for disposal can produce only steam. This steam must be used on site or very nearby this limiting the potential locations for mass burn facilities. Such a gas, if produced from currently available supplies of MSW, can contribute 2 quads to the US energy supply. 3 refs., 12 figs., 7 tabs.

  13. Waste tire derived carbon-polymer composite paper as pseudocapacitive electrode with long cycle life

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Boota, M.; Paranthaman, Mariappan Parans; Naskar, Amit K.; Gogotsi, Yury; Li, Yunchao; Akato, Kokouvi

    2015-09-25

    Recycling hazardous wastes to produce value-added products is becoming essential for the sustainable progress of our society. Herein, highly porous carbon (1625 m2/g–1) is synthesized using waste tires as the precursor and used as supercapacitor electrode. The narrow pore size distribution (PSD) and high surface area led to a good charge storage capacity, especially when used as a three-dimensional nanoscaffold to polymerize polyaniline (PANI/TC). The composite film was highly flexible, conductive and exhibited a capacitance of 480 F/g–1 at 1 mV/s–1 with excellent capacitance retention up to 98% after 10,000 charge/discharge cycles. The high capacitance and long cycle life weremore » ascribed to the short diffusional paths, uniform PANI coating and tight confinement of the PANI in the inner pores of the tire-derived carbon via - interactions, which minimized the degradation of the PANI upon cycling. Here, we anticipate that the same strategy can be applied to deposit other pseudocapacitive materials with low-cost TC to achieve even higher electrochemical performance and longer cycle life, a key challenge for redox active polymers.« less

  14. Lithium modified zeolite synthesis for conversion of biodiesel-derived glycerol to polyglycerol

    SciTech Connect (OSTI)

    Ayoub, Muhammad; Abdullah, Ahmad Zuhairi; Inayat, Abrar

    2014-10-24

    Basic zeolite has received significant attention in the catalysis community. These zeolites modified with alkaline are the potential replacement for existing zeolite catalysts due to its unique features with added advantages. The present paper covers the preparation of lithium modified zeolite Y (Li-ZeY) and its activity for solvent free conversion of biodiesel-derived glycerol to polyglycerol via etherification process. The modified zeolite was well characterized by X-ray diffraction (XRD), Scanning Electron Microscope (SEM) and Nitrogen Adsorption. The SEM images showed that there was no change in morphology of modified zeolite structure after lithium modification. XRD patterns showed that the structure of zeolite was sustained after lithium modification. The surface properties of parent and modified zeolite was also observed N{sub 2} adsortion-desorption technique and found some changes in surface area and pore size. In addition, the basic strength of prepared materials was measured by Hammet indicators and found that basic strength of Li-ZeY was highly improved. This modified zeolite was found highly thermal stable and active heterogamous basic catalyst for conversion of solvent free glycerol to polyglycerol. This reaction was conducted at different temperatures and 260 C was found most active temperature for this process for reaction time from 6 to 12 h over this basic catalyst in the absence of solvent.

  15. Derived annual estimates of manufacturing energy consumption, 1974--1988. [Contains glossary

    SciTech Connect (OSTI)

    Not Available

    1992-08-05

    This report presents a complete series of annual estimates of purchased energy used by the manufacturing sector of the US economy, for the years 1974 to 1988. These estimates interpolate over gaps in the actual data collections, by deriving estimates for the missing years 1982--1984 and 1986--1987. For the purposes of this report, purchased'' energy is energy brought from offsite for use at manufacturing establishments, whether the energy is purchased from an energy vendor or procured from some other source. The actual data on purchased energy comes from two sources, the US Department of Commerce Bureau of the Census's Annual Survey of Manufactures (ASM) and EIA's Manufacturing Energy Consumption Survey (MECS). The ASM provides annual estimates for the years 1974 to 1981. However, in 1982 (and subsequent years) the scope of the ASM energy data was reduced to collect only electricity consumption and expenditures and total expenditures for other purchased energy. In 1985, EIA initiated the triennial MECS collecting complete energy data. The series equivalent to the ASM is referred to in the MECS as offsite-produced fuels.''

  16. Gamma-radiolytic stability of new methylated TODGA derivatives for minor actinide recycling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Galan, Hitos; Zarzana, Christopher A.; Wilden, Andreas; Nunez, Ana; Schmidt, Holger; Egberink, Richard J. M.; Leoncini, Andrea; Cobos, Joaquin; Verboom, Willem; Modolo, Giuseppe; et al

    2015-09-15

    The stability against gamma radiation of MeTODGA (methyl tetraoctyldiglycolamide) and Me2TODGA (dimethyl tetraoctyldiglycolamide), derivatives from the well-known extractant TODGA (N,N,N',N';-tetraoctyldiglycolamide), were studied and compared. Solutions of MeTODGA and Me2TODGA in alkane diluents were subjected to 60Co γ-irradiation in the presence and absence of nitric acid and analyzed using LC-MS to determine their rates of radiolytic concentration decrease, as well as to identify radiolysis products. The results of product identification from three different laboratories are compared and found to be in good agreement. The diglycolamide (DGA) concentrations decreased exponentially with increasing absorbed dose. The MeTODGA degradation rate constants (dose constants) weremore » uninfluenced by the presence of nitric acid, but the acid increased the rate of degradation for Me2TODGA. The degradation products formed by irradiation are also initially produced in greater amounts in acid-contacted solution, but products may also be degraded by continued radiolysis. As a result, the identified radiolysis products suggest that the weakest bonds are those in the diglycolamide center of these molecules.« less

  17. Derivation of quantum mechanics from the Boltzmann equation for the Planch aether

    SciTech Connect (OSTI)

    Winterberg, F.

    1995-10-01

    The Planck aether hypothesis assumes that space is densely filled with an equal number of locally interacting positive and negative Planck masses obeying an exactly nonrelativistic law of motion. The Planck masses can be described by a quantum mechanical two-component nonrelativistic operator field equation having the form of a two-component nonlinear Schroedinger equation, with a spectrum of quasiparticles obeying Lorentz invariance as a dynamic symmetry for energies small compared to the Planck energy. We show that quantum mechanics itself can be derived from the Newtonian mechanics of the Planck aether as an approximate solution of Boltzmann`s equation for the locally interacting positive and negative Planck masses, and that the validity of the nonrelativistic Schroedinger equation depends on Lorentz invariance as a dynamic symmetry. We also show how the many-body Schroedinger wave function can be factorized into a product of quasiparticles of the Planck aether with separable quantum potentials. Finally, we present a possible explanation of wave function collapse as a kind of enhanced gravitational collapse in the presence of the negative Planck masses.

  18. Development of carbon-metal oxide supercapacitors from sol-gel derived carbon-ruthenium xerogels

    SciTech Connect (OSTI)

    Lin, C.; Ritter, J.A.; Popov, B.N.

    1999-09-01

    There has been increasing interest in electrochemical capacitors as energy storage systems because of their high power density and long cycle life, compared to battery devices. According to the mechanism of energy storage, there are two types of electrochemical capacitors. One type is based on double layer (dl) formation due to charge separation, and the other type is based on a faradaic process due to redox reactions. Sol-gel derived high surface area carbon-ruthenium xerogels were prepared from carbonized resorcinol-formaldehyde resins containing an electrochemically active form of ruthenium oxide. The electrochemical capacitance of these materials increased with an increase in the ruthenium content indicating the presence of pseudocapacitance associated with the ruthenium oxide undergoing reversible faradaic redox reactions. A specific capacitance of 256 F/g (single electrode) was obtained from a carbon xerogel containing 14 wt% Ru, which corresponded to more than 50% utilization of the ruthenium. The double layer accounted for 40% of this capacitance. This material was also electrochemically stable, showing no change in a cyclic voltammogram for over 2,000 cycles.

  19. Studies on Supercapacitor Electrode Material from Activated Lignin-Derived Mesoporous Carbon

    SciTech Connect (OSTI)

    Saha, Dipendu; Li, Yunchao; Bi, Zhonghe; Chen, Jihua; Keum, Jong Kahk; Hensley, Dale K; Grappe, Hippolyte A.; Meyer III, Harry M; Dai, Sheng; Paranthaman, Mariappan Parans; Naskar, Amit K

    2014-01-01

    We synthesized mesoporous carbon from pre-cross-linked lignin gel impregnated with a surfactant as the pore-forming agent, and then activated the carbon through physical and chemical methods to obtain activated mesoporous carbon. The activated mesoporous carbons exhibited 1.5- to 6-fold increases in porosity with a maximum BET specific surface area of 1148 m2/g and a pore volume of 1.0 cm3/g. Slow physical activation helped retain dominant mesoporosity; however, aggressive chemical activation caused some loss of the mesopore volume fraction. Plots of cyclic voltammetric data with the capacitor electrode made from these carbons showed an almost rectangular curve depicting the behavior of ideal double-layer capacitance. Although the pristine mesoporous carbon exhibited the same range of surface-area-based capacitance as that of other known carbon-based supercapacitors, activation decreased the surface-area-based specific capacitance and increased the gravimetric-specific capacitance of the mesoporous carbons. Surface activation lowered bulk density and electrical conductivity. Warburg impedance as a vertical tail in the lower frequency domain of Nyquist plots supported good supercapacitor behavior for the activated mesoporous carbons. Our work demonstrated that biomass-derived mesoporous carbon materials continue to show potential for use in specific electrochemical applications.

  20. Ex Situ Formation of Metal Selenide Quantum Dots Using Bacterially Derived Selenide Precursors

    SciTech Connect (OSTI)

    Fellowes, Jonathan W.; Pattrick, Richard; Lloyd, Jon; Charnock, John M.; Coker, Victoria S.; Mosselmans, JFW; Weng, Tsu-Chien; Pearce, Carolyn I.

    2013-04-12

    Luminescent quantum dots were synthesized using bacterially derived selenide (SeII-) as the precursor. Biogenic SeII- was produced by the reduction of Se-IV by Veillonella atypica and compared directly against borohydride-reduced Se-IV for the production of glutathione-stabilized CdSe and beta-mercaptoethanol-stabilized ZnSe nanoparticles by aqueous synthesis. Biological SeII- formed smaller, narrower size distributed QDs under the same conditions. The growth kinetics of biologically sourced CdSe phases were slower. The proteins isolated from filter sterilized biogenic SeII- included a methylmalonyl-CoA decarboxylase previously characterized in the closely related Veillonella parvula. XAS analysis of the glutathione-capped CdSe at the S K-edge suggested that sulfur from the glutathione was structurally incorporated within the CdSe. A novel synchrotron based XAS technique was also developed to follow the nucleation of biological and inorganic selenide phases, and showed that biogenic SeII- is more stable and more resistant to beam-induced oxidative damage than its inorganic counterpart. The bacterial production of quantum dot precursors offers an alternative, 'green' synthesis technique that negates the requirement of expensive, toxic chemicals and suggests a possible link to the exploitation of selenium contaminated waste streams.

  1. Comminution phenomena during the fluidized bed combustion of a commercial refuse-derived fuel

    SciTech Connect (OSTI)

    Arena, U.; Cammarota, A.; Chirone, R.; D`Anna, G.

    1995-12-31

    A commercial densified refuse-derived fuel (RDF), obtained as pellets from municipal solid wastes, was burned in two laboratory scale bubbling fluidized bed combustors, having an internal diameter of 41 mm. The apparatus were both batchwise operated at 850 C by injecting batches of RDF particles into a bed of silica sand (300--400 {micro}m as size range) fluidized at a superficial gas velocity of 0.8 m/s. RDF particles with equivalent mean diameter ranging from 4 to 9 mm were used. Different experimental procedures were set up to separately investigate comminution phenomena of fuel particles. Results were compared with those obtained burning a South African bituminous coal. Results pointed out that RDF particles undergo a strong primary fragmentation phenomenon, with a probability of particle breakage equal to 1 for fuel particles larger than 6 mm. Attrition and char fragmentation phenomena are particularly relevant under both inert and oxidizing conditions, generating a large amount of unburned fines which may affect overall combustion efficiency.

  2. Design considerations and operating experience in firing refuse derived fuel in a circulating fluidized bed combustor

    SciTech Connect (OSTI)

    Piekos, S.J.; Matuny, M.

    1997-12-31

    The worldwide demand for cleaner, more efficient methods to dispose of municipal solid waste has stimulated interest in processing solid waste to produce refuse derived fuel (RDF) for use in circulating fluidized bed (CFB) boilers. The combination of waste processing and materials recovery systems and CFB boiler technology provides the greatest recovery of useful resources from trash and uses the cleanest combustion technology available today to generate power. Foster Wheeler Power Systems along with Foster Wheeler Energy Corporation and several other Foster Wheeler sister companies designed, built, and now operates a 1600 tons per day (TPD) (1450 metric tons) municipal waste-to-energy project located in Robbins, Illinois, a suburb of Chicago. This project incorporates waste processing systems to recover recyclable materials and produce RDF. It is the first project in the United States to use CFB boiler technology to combust RDF. This paper will provide an overview of the Robbins, Illinois waste-to-energy project and will examine the technical and environmental reasons for selecting RDF waste processing and CFB combustion technology. Additionally, this paper will present experience with handling and combusting RDF and review the special design features incorporated into the CFB boiler and waste processing system that make it work.

  3. Pilot scale production and combustion of liquid fuels from refuse derived fuel (RDF): Part 2

    SciTech Connect (OSTI)

    Klosky, M.K.

    1996-09-01

    EnerTech is developing a process for producing pumpable slurry fuels, comparable to Coal-Water-Fuels (CWF), from solid Refuse Derived Fuels (RDF). Previous reports have described the characteristics of the enhanced carbonized RDF slurry fuels. This paper summarizes those fuel characteristics and reports on the latest combustion tests performed with the final product fuel. The objective of this research was to determine the boiler and emission performance from the carbonized RDF slurry fuel using statistical screening experiments. Eight combustion tests were performed with a pilot scale pulverized coal/oil boiler simulator, with CO, SO{sub 2}, and NO{sub x} emissions determined on-line. The combustion tests produced simultaneous CO and NO{sub x} emissions well below and SO{sub 2} emissions comparable to the promulgated New Source Performance Standards (NSPS). This research will form the basis for later combustion experiments to be performed with the carbonized RDF slurry fuel, in which dioxin/furan and trace metal emissions will be determined.

  4. Black holes in an asymptotically safe gravity theory with higher derivatives

    SciTech Connect (OSTI)

    Cai, Yi-Fu; Easson, Damien A. E-mail: easson@asu.edu

    2010-09-01

    We present a class of spherically symmetric vacuum solutions to an asymptotically safe theory of gravity containing high-derivative terms. We find quantum corrected Schwarzschild-(anti)-de Sitter solutions with running gravitational coupling parameters. The evolution of the couplings is determined by their corresponding renormalization group flow equations. These black holes exhibit properties of a classical Schwarzschild solution at large length scales. At the center, the metric factor remains smooth but the curvature singularity, while softened by the quantum corrections, persists. The solutions have an outer event horizon and an inner Cauchy horizon which equate when the physical mass decreases to a critical value. Super-extremal solutions with masses below the critical value correspond to naked singularities. The Hawking temperature of the black hole vanishes when the physical mass reaches the critical value. Hence, the black holes in the asymptotically safe gravitational theory never completely evaporate. For appropriate values of the parameters such stable black hole remnants make excellent dark matter candidates.

  5. Waste tire derived carbon-polymer composite paper as pseudocapacitive electrode with long cycle life

    SciTech Connect (OSTI)

    Boota, M.; Paranthaman, Mariappan Parans; Naskar, Amit K.; Gogotsi, Yury; Li, Yunchao; Akato, Kokouvi

    2015-09-25

    Recycling hazardous wastes to produce value-added products is becoming essential for the sustainable progress of our society. Herein, highly porous carbon (1625 m2/g–1) is synthesized using waste tires as the precursor and used as supercapacitor electrode. The narrow pore size distribution (PSD) and high surface area led to a good charge storage capacity, especially when used as a three-dimensional nanoscaffold to polymerize polyaniline (PANI/TC). The composite film was highly flexible, conductive and exhibited a capacitance of 480 F/g–1 at 1 mV/s–1 with excellent capacitance retention up to 98% after 10,000 charge/discharge cycles. The high capacitance and long cycle life were ascribed to the short diffusional paths, uniform PANI coating and tight confinement of the PANI in the inner pores of the tire-derived carbon via - interactions, which minimized the degradation of the PANI upon cycling. Here, we anticipate that the same strategy can be applied to deposit other pseudocapacitive materials with low-cost TC to achieve even higher electrochemical performance and longer cycle life, a key challenge for redox active polymers.

  6. Bioconversion of coal-derived synthesis gas to liquid fuels. [Butyribacterium methylotrophicum

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-01-01

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  7. Intergranular fracture in UO2: derivation of traction-separation law from atomistic simulations

    SciTech Connect (OSTI)

    Yongfeng Zhang; Paul C Millett; Michael R Tonks; Xian-Ming Bai; S Bulent Biner

    2013-10-01

    In this study, the intergranular fracture behavior of UO2 was studied by molecular dynamics simulations using the Basak potential. In addition, the constitutive traction-separation law was derived from atomistic data using the cohesive-zone model. In the simulations a bicrystal model with the (100) symmetric tilt E5 grain boundaries was utilized. Uniaxial tension along the grain boundary normal was applied to simulate Mode-I fracture. The fracture was observed to propagate along the grain boundary by micro-pore nucleation and coalescence, giving an overall intergranular fracture behavior. Phase transformations from the Fluorite to the Rutile and Scrutinyite phases were identified at the propagating crack tips. These new phases are metastable and they transformed back to the Fluorite phase at the wake of crack tips as the local stress concentration was relieved by complete cracking. Such transient behavior observed at atomistic scale was found to substantially increase the energy release rate for fracture. Insertion of Xe gas into the initial notch showed minor effect on the overall fracture behavior.

  8. Chemistry and structure of coal derived asphaltenes and preasphaltenes. Quarterly progress report, April-June 1980

    SciTech Connect (OSTI)

    Yen, T. F.

    1980-01-01

    It is the objective of this project to isolate the asphaltene and preasphaltene fractions from coal liquids from a number of liquefaction processes. These processes consist of in general: catalytic hydrogenation, staged pyrolysis and solvent refining. These asphaltene fractions may be further separated by both gradient elution through column chromatography, and molecular size distribution through gel permeation chromatography. Those coal-derived asphaltene and preasphaltene fractions will be investigated by various chemical and physical methods for characterization of their structures. After the parameters are obtained, these parameters will be correlated with the refining and conversion variables which control a given type of liquefaction process. The effects of asphaltene in catalysis, ash or metal removal, desulfurization and denitrification will also be correlated. It is anticipated that understanding the role of asphaltenes in liquefaction processes will enable engineers to both improve existing processes, and to make recommendations for operational changes in planned liquefaction units in the United States. The objective of Phase 1 was to complete the isolation and separation of coal liquid fractions and to initiate their characterization. The objective of Phase 2 is to continue the characterization of coal asphaltenes and other coal liquid fractions by use of physical and instrumental methods. The structural parameters obtained will be used to postulate hypothetical average structures for coal liquid fractions. The objective of Phase 3 is to concentrate on the characterization of the preasphaltene (benzene insoluble fraction) of coal liquid fraction by the available physical and chemical methods to obtain a number of structural parameters.

  9. A thermogravimetric analysis of catalytic hydroprocessing of a coal-derived liquid

    SciTech Connect (OSTI)

    Song, X.; Lu, S.; Lana, I.G.D.

    1995-12-31

    Catalytic hydroprocessing of a coal-derived liquid (CDL) was studied using thermogravimetric analysis (TGA). Because of high sensitivity of the TGA instrument and complexity of the system studied, strictly controlled operating conditions are essential to obtain reliable and comparable data. The effects of several operating parameters on TGA data of a CDL and of CDL-catalyst mixture samples were systematically investigated, and standardized experimental conditions were established. We found that when a catalyst was present, the weight loss of the CDL as a function of increasing temperature was increased at lower temperatures (<300{degrees}C) and decreased at higher temperatures (>300{degrees}C) irrespective of whether the atmosphere was H{sub 2} or N{sub 2}. On the other hand, a higher CDL weight loss and a lower temperature for the maximum CDL weight loss rate were observed when H{sub 2} was used as the carrier gas irrespective of whether a catalyst was present or not. Our preliminary results suggest that the catalyst most active for hydroprocessing of the CDL is the one exhibiting the greatest CDL weight loss.

  10. Large eddy simulation models for incompressible magnetohydrodynamics derived from the variational multiscale formulation

    SciTech Connect (OSTI)

    Sondak, David; Oberai, Assad A.

    2012-10-15

    Novel large eddy simulation (LES) models are developed for incompressible magnetohydrodynamics (MHD). These models include the application of the variational multiscale formulation of LES to the equations of incompressible MHD. Additionally, a new residual-based eddy viscosity model is introduced for MHD. A mixed LES model that combines the strengths of both of these models is also derived. The new models result in a consistent numerical method that is relatively simple to implement. The need for a dynamic procedure in determining model coefficients is no longer required. The new LES models are tested on a decaying Taylor-Green vortex generalized to MHD and benchmarked against classical LES turbulence models. The LES simulations are run in a periodic box of size [-{pi}, {pi}]{sup 3} with 32 modes in each direction and are compared to a direct numerical simulation (DNS) with 512 modes in each direction. The new models are able to account for the essential MHD physics which is demonstrated via comparisons of energy spectra. We also compare the performance of our models to a DNS simulation by Pouquet et al.['The dynamics of unforced turbulence at high Reynolds number for Taylor-Green vortices generalized to MHD,' Geophys. Astrophys. Fluid Dyn. 104, 115-134 (2010)], for which the ratio of DNS modes to LES modes is 262:144.

  11. The derivation of constraints on the msugra parameter space from the entropy of dark matter halos

    SciTech Connect (OSTI)

    Cabral-Rosetti, L. G.; Mondragon, M.; Nellen, L.; Nunez, D.; Sussmann, R.; Zavala, J.

    2009-04-20

    We derive an expression for the entropy of a present dark matter halo described by a Navarro-Frenk-White modified model with a central core. We obtain an expression for the relic abundance of neutralinos by comparing this entropy of the halo with the value it had during the freeze-out era. Using WMAP observations, we constrain the parameter space for mSUGRA models. Combining our results with the usual abundance criteria, we are able to discriminate clearly among different validity regions for tan {beta} values. For this, we require both criteria to be consistent within a 2{sigma} bound of the WMAP observations for the relic density: 0.112<{omega}h{sup 2}<0.122. We find that for sgn {mu} = +1, small values of tan {beta} are not favored; only for tan {beta}{approx}50 are both criteria significantly consistent. Both criteria allow us to put a lower bound on the neutralino mass, m{sub {chi}}{>=}141 GeV.

  12. Isotopic Tracking of Hanford 300 Area Derived Uranium in the Columbia River

    SciTech Connect (OSTI)

    Christensen, John N.; Dresel, P. Evan; Conrad, Mark E.; Patton, Gregory W.; DePaolo, Donald J.

    2010-10-31

    Our objectives in this study are to quantify the discharge rate of uranium (U) to the Columbia River from the Hanford Site's 300 Area, and to follow that U down river to constrain its fate. Uranium from the Hanford Site has variable isotopic composition due to nuclear industrial processes carried out at the site. This characteristic makes it possible to use high-precision isotopic measurements of U in environmental samples to identify even trace levels of contaminant U, determine its sources, and estimate discharge rates. Our data on river water samples indicate that as much as 3.2 kg/day can enter the Columbia River from the 300 Area, which is only a small fraction of the total load of dissolved natural background U carried by the Columbia River. This very low-level of Hanford derived U can be discerned, despite dilution to < 1 percent of natural background U, 350 km downstream from the Hanford Site. These results indicate that isotopic methods can allow the amounts of U from the 300 Area of the Hanford Site entering the Columbia River to be measured accurately to ascertain whether they are an environmental concern, or are insignificant relative to natural uranium background in the Columbia River.

  13. Synthesis of acrylates and methacrylates from coal-derived syngas. Quarterly report, October--December 1996

    SciTech Connect (OSTI)

    1997-05-02

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the US Department of Energy, Federal Energy Technology Center. This three-step process consists of synthesis of a propionate, its condensation with formaldehyde, and esterification of resulting methacrylic acid (MAA) with methanol to produce MMA. Eastman has focused on the propionate synthesis step. the resultant Mo catalysts work efficiently at much less severe conditions (170{degrees}C and 30 atm) than the conventional Ni catalysts (270{degrees}C and 180 atm). Bechtel has performed an extensive cost analysis which shows that Eastman`s propionate synthesis step is competitive with other technologies to produce the anhydride. In the second step, RTI and Eastman have developed active and stable V-Si-P ternary metal oxide catalysts Nb/SiO{sub 2} and Ta/SiO{sub 2} catalysts for the condensation of propionic anhydride and acid with formaldehyde. RTI has demonstrated a novel correlation among the catalyst acid-base properties, condensation reaction yield, and long-term catalyst activity. Current research focuses on enhancing the condensation reaction yields by better understanding of the acid-base property correlation, in situ condensation in a high-temperature, high- pressure (HTHP) slurry reactor, and alternate formaldehyde feedstocks. Based on Eastman and RTI laboratory data, a cost estimate is also being developed for the integrated process.

  14. Synthesis of methyl methacrylate from coal-derived syngas: Quarterly report,, October 1-December 31, 1997

    SciTech Connect (OSTI)

    1998-09-01

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of three steps of synthesis of a propionate, its condensation with formaldehyde, and esterification of resulting methacrylic acid (MAA) with methanol to produce MMA. Over the last quarter, Eastman developed two new processes which have resulted in two new invention reports. One process deals with carbonylation of benzyl ether which represents a model for coal liquefaction and the second focuses on the acceleration of carbonylation rates for propionic acid synthesis, via use of polar aprotic solvents. These two inventions are major improvements in the novel Mo-catalyzed homogeneous process for propionic acid synthesis technology, developed by Eastman. Over the last quarter, RTI completed three reaction cycles and two regeneration cycles as a part of long-term reaction regeneration cycle study on a 10% Nb{sub 2}O{sub 5}/Si0{sub 2} catalyst, for vapor phase condensation reaction of formaldehyde with propionic acid.

  15. Production of High-Hydrogen Content Coal-Derived Liquids [Part 2 of 3

    SciTech Connect (OSTI)

    Stephen Bergin

    2011-03-30

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal

  16. Production of High-Hydrogen Content Coal-Derived Liquids [Part 3 of 3

    SciTech Connect (OSTI)

    Stephen Bergin

    2011-03-30

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal

  17. Production of High-Hydrogen Content Coal-Derived Liquids [Part 1 of 3

    SciTech Connect (OSTI)

    Stephen Bergin

    2011-03-30

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal

  18. Using Whole-House Field Tests to Empirically Derive Moisture Buffering Model Inputs

    SciTech Connect (OSTI)

    Woods, J.; Winkler, J.; Christensen, D.; Hancock, E.

    2014-08-01

    Building energy simulations can be used to predict a building's interior conditions, along with the energy use associated with keeping these conditions comfortable. These models simulate the loads on the building (e.g., internal gains, envelope heat transfer), determine the operation of the space conditioning equipment, and then calculate the building's temperature and humidity throughout the year. The indoor temperature and humidity are affected not only by the loads and the space conditioning equipment, but also by the capacitance of the building materials, which buffer changes in temperature and humidity. This research developed an empirical method to extract whole-house model inputs for use with a more accurate moisture capacitance model (the effective moisture penetration depth model). The experimental approach was to subject the materials in the house to a square-wave relative humidity profile, measure all of the moisture transfer terms (e.g., infiltration, air conditioner condensate) and calculate the only unmeasured term: the moisture absorption into the materials. After validating the method with laboratory measurements, we performed the tests in a field house. A least-squares fit of an analytical solution to the measured moisture absorption curves was used to determine the three independent model parameters representing the moisture buffering potential of this house and its furnishings. Follow on tests with realistic latent and sensible loads showed good agreement with the derived parameters, especially compared to the commonly-used effective capacitance approach. These results show that the EMPD model, once the inputs are known, is an accurate moisture buffering model.

  19. Carbide-Derived Carbons with Tunable Porosity Optimized for Hydrogen Storage

    SciTech Connect (OSTI)

    Fisher, John E.; Gogotsi, Yury; Yildirim, Taner

    2010-01-07

    On-board hydrogen storage is a key requirement for fuel cell-powered cars and trucks. Porous carbon-based materials can in principle adsorb more hydrogen per unit weight at room temperature than liquid hydrogen at -176 oC. Achieving this goal requires interconnected pores with very high internal surface area, and binding energies between hydrogen and carbon significantly enhanced relative to H2 on graphite. In this project a systematic study of carbide-derived carbons, a novel form of porous carbon, was carried out to discover a high-performance hydrogen sorption material to meet the goal. In the event we were unable to improve on the state of the art in terms of stored hydrogen per unit weight, having encountered the same fundamental limit of all porous carbons: the very weak interaction between H2 and the carbon surface. On the other hand we did discover several strategies to improve storage capacity on a volume basis, which should be applicable to other forms of porous carbon. Further discoveries with potentially broader impacts include Proof that storage performance is not directly related to pore surface area, as had been previously claimed. Small pores (< 1.5 nm) are much more effective in storing hydrogen than larger ones, such that many materials with large total surface areas are sub-par performers. Established that the distribution of pore sizes can be controlled during CDC synthesis, which opens the possibility of developing high performance materials within a common family while targeting widely disparate applications. Examples being actively pursued with other funding sources include methane storage, electrode materials for batteries and supercapacitors with record high specific capacitance, and perm-selective membranes which bind cytokines for control of infections and possibly hemodialysis filters.

  20. Synthesis and characterization of a series of Group 4 phenoxy-thiol derivatives

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Boyle, Timothy J.; Neville, Michael L.; Parkes, Marie V.

    2016-02-11

    In this study, a series of Group 4 phenoxy-thiols were developed from the reaction products of a series of metal tert-butoxides ([M(OBut)4]) with four equivalents of 4-mercaptophenol (H-4MP). The products were found by single crystal X-ray diffraction to adopt the general structure [(HOBut)(4MP)3M(μ-4MP)]2 [where M = Ti (1), Zr (2), Hf (3)] from toluene and [(py)2M(4MP)] where M = Ti (4), Zr (5) and [(py)(4MP)3Hf(μ-4MP)]2 (6) from pyridine (py). Varying the [Ti(OR)4] precursors (OR = iso-propoxide (OPri) or neo-pentoxide (ONep)) in toluene led to [(HOR)(4MP)3Ti(μ-4MP)]2 (OR = OPri (7), ONep (8)), which were structurally similar to 1. Lower stoichiometric reactionsmore » in toluene led to partial substitution by the 4MP ligands yielding [H][Ti(μ-4MP)(4MP)(ONep)3]2 (9). Independent of the stoichiometry, all of the Ti derivatives were found to be red in color, whereas the heavier congeners were colorless. Attempts to understand this phenomenon led to investigation with a series of varied –SH substituted phenols. From the reaction of H-2MP and H-3MP (2-mercaptophenol and 3-mercaptophenol, respectively), the isolated products had identical arrangements: [(ONep)2(2MP)Ti(μ,η2-2MP)]2 (10) and [(HOR)(3MP)M(μ-3MP)]2 (M/OR = Ti/ONep (11); Zr/OBut (12)) with a similar red color. Based on the simulated and observed UV–Vis spectra, it was reasoned that the color was generated due to a ligand-to-metal charge transfer for Ti that was not available for the larger congeners.« less

  1. Carbon attrition during the circulating fluidized bed combustion of a packaging-derived fuel

    SciTech Connect (OSTI)

    Mastellone, M.L.; Arena, U.

    1999-05-01

    Cylindrical pellets of a market-available packaging-derived fuel, obtained from a mono-material collection of polyethylene terephthalate (PET) bottles, were batchwise fed to a laboratory scale circulating fluidized bed (CFB) combustor. The apparatus, whose riser was 41 mm ID and 4 m high, was operated under both inert and oxidizing conditions to establish the relative importance of purely mechanical attrition and combustion-assisted attrition in generating carbon fines. Silica sand particles of two size distributions were used as inert materials. For each run, carbon load and carbon particle size distribution in the riser and rates of attrited carbon fines escaping the combustor were determined as a function of time. A parallel investigation was carried out with a bubbling fluidized bed (BFB) combustor to point out peculiarities of attrition in CFB combustors. After devolatilization, PET pellets generated fragile aggregates of char and sand, which easily crumbled, leading to single particles, partially covered by a carbon-rich layer. The injected fixed carbon was therefore present in the bed in three phases: an A-phase, made of aggregates of sand and char, an S-phase, made of individual carbon-covered sand particles and an F-phase, made of carbon fines, abraded by the surfaces of the A- and S-phases. The effects of the size of inert material on the different forms under which fixed carbon was present in the bed and on the rate of escape of attrited carbon fines from the combustor were investigated. Features of carbon attrition in CFB and BFB combustors are discussed.

  2. Adipose-derived stem cells retain their regenerative potential after methotrexate treatment

    SciTech Connect (OSTI)

    Beane, Olivia S.; Fonseca, Vera C.; Darling, Eric M.

    2014-10-01

    In musculoskeletal tissues like bone, chemotherapy can impair progenitor cell differentiation and proliferation, resulting in decreased bone growth and mineralization throughout a patient's lifetime. In the current study, we investigated the effects of chemotherapeutics on adipose-derived stem cell (ASC) function to determine whether this cell source could be a candidate for repairing, or even preventing, chemotherapy-induced tissue damage. Dose-dependent proliferation rates of ASCs and normal human fibroblasts (NHFs) were quantified after treatment with cytarabine (CY), etoposide (ETO), methotrexate (MTX), and vincristine (VIN) using a fluorescence-based assay. The influence of MTX on the multipotency of ASCs and freshly isolated stromal vascular fraction (SVF) cells was also evaluated using lineage-specific stains and spectrophotometry. ASC and NHF proliferation were equally inhibited by exposure to CY and ETO; however, when treated with MTX and VIN, ASCs exhibited greater resistance. This was especially apparent for MTX-treated samples, with ASC proliferation showing no inhibition for clinically relevant MTX doses ranging from 0.1 to 50 μM. Additional experiments revealed that the differentiation potential of ASCs was not affected by MTX treatment and that upregulation of dihydrofolate reductase possibly contributed to this response. Moreover, SVF cells, which include ASCs, exhibited similar resistance to MTX impairment, with respect to cellular proliferation, clonogenicity, and differentiation capability. Therefore, we have shown that the regenerative properties of ASCs resist the cytotoxicity of MTX, identifying these cells as a potential key for repairing musculoskeletal damage in patients undergoing chemotherapy. - Highlights: • Long-term effects of chemotherapeutics can include musculoskeletal dysfunction. • A screen of common drugs showed disparate effects on ASCs and fibroblasts. • One drug, methotrexate, did not impair ASC growth characteristics

  3. TURBULENT DIFFUSION IN THE PHOTOSPHERE AS DERIVED FROM PHOTOSPHERIC BRIGHT POINT MOTION

    SciTech Connect (OSTI)

    Abramenko, V. I.; Yurchyshyn, V.; Goode, P. R.; Carbone, V.; Lepreti, F.; Capparelli, V.; Vecchio, A.; Stein, R. F.

    2011-12-20

    On the basis of observations of solar granulation obtained with the New Solar Telescope of Big Bear Solar Observatory, we explored proper motion of bright points (BPs) in a quiet-sun area, a coronal hole, and an active region plage. We automatically detected and traced BPs and derived their mean-squared displacements as a function of time (starting from the appearance of each BP) for all available time intervals. In all three magnetic environments, we found the presence of a super-diffusion regime, which is the most pronounced inside the time interval of 10-300 s. Super-diffusion, measured via the spectral index, {gamma}, which is the slope of the mean-squared displacement spectrum, increases from the plage area ({gamma} = 1.48) to the quiet-sun area ({gamma} = 1.53) to the coronal hole ({gamma} = 1.67). We also found that the coefficient of turbulent diffusion changes in direct proportion to both temporal and spatial scales. For the minimum spatial scale (22 km) and minimum time scale (10 s), it is 22 and 19 km{sup 2} s{sup -1} for the coronal hole and the quiet-sun area, respectively, whereas for the plage area it is about 12 km{sup 2} s{sup -1} for the minimum time scale of 15 s. We applied our BP tracking code to three-dimensional MHD model data of solar convection and found the super-diffusion with {gamma} = 1.45. An expression for the turbulent diffusion coefficient as a function of scales and {gamma} is obtained.

  4. Studies on the binding of 5-N-methylated quindoline derivative to human telomeric G-quadruplex

    SciTech Connect (OSTI)

    Xu, Wei; Tan, Jia-Heng; Chen, Shuo-Bin; Hou, Jin-Qiang; Li, Ding; Huang, Zhi-Shu; Gu, Lian-Quan

    2011-03-18

    Research highlights: {yields} Hydrophobic interaction provided an important driving force for the interaction between ligand and G-quadruplex. {yields} Constrained water molecules were released from surface of G-tetrad upon the formation of the complex. {yields} The end-stacking mode for quindoline derivative was validated through UV-vis, ITC, steady-state, and time-resolved fluorescence experiment. {yields} The binding of compound 1 to quadruplex was found to be a temperature-dependent and enthalpy-entropy compensation process. -- Abstract: Quindoline derivatives as telomeric quadruplex ligands have shown good biological activity for telomerase inhibition. In the present study, we used spectroscopic and calorimetric methods to investigate the interactions between a quindoline derivative (5-methyl-11-(2-morpholinoethylamino)-10-H-indolo-[3,2-b]quinolin-5-ium iodide, compound 1) and human telomeric G-quadruplex. The thermodynamic studies using isothermal titration calorimetry (ITC) indicated that their binding process was temperature-dependent and enthalpy-entropy co-driven. The significant negative heat capacity was obtained experimentally from the temperature dependence of enthalpy changes, which was consistent with that from theoretical calculation, and all suggesting significant hydrophobic contribution to the molecular recognition process. Based on the results from UV-vis, ITC, steady-state and time-resolved fluorescence, their binding mode was determined as two ligand molecules stacking on the quartets on both ends of the quadruplex. These results shed light on rational design and development of quindoline derivatives as G-quadruplex binding ligands.

  5. Super critical fluid extraction of a crude oil bitumen-derived liquid and bitumen by carbon dioxide and propane

    SciTech Connect (OSTI)

    Deo, M.D.; Hwang, J.; Hanson, F.V.

    1991-01-01

    Supercritical fluid extraction of complex hydrocarbon mixtures is important in separation processes, petroleum upgrading and enhanced oil recovery. In this study, a paraffinic crude oil, a bitumen- derived liquid and bitumen were extracted at several temperatures and pressures with carbon dioxide and propane to assess the effect of the size and type of compounds that makeup the feedstock on the extraction process. It was observed that the pure solvent density at the extraction conditions was not the sole variable governing extraction, and that the proximity of the extraction conditions to the pure solvent critical point affected the extraction yields and the compositions of the extracts. Heavier compounds reported to the extract phase as the extraction time increased at constant temperature and pressure and as the extraction pressure increased at constant temperature and extraction time for both the paraffin crude-propane and the bitumen-propane systems. This preferential extraction was not observed for the bitumen-derived liquid. The non-discriminatory extraction behavior of the bitumen-derived liquid was attributed to its thermal history and to the presence of the olefins and aromatics in the liquid. Phase behavior calculations using the Peng-Robinson equation of state and component lumping procedures provided reasonable agreement between calculated and experimental results for the crude oil and bitumen extractions, but failed in the prediction of the phase compositions for the bitumen-derived liquid extractions.

  6. Super critical fluid extraction of a crude oil bitumen-derived liquid and bitumen by carbon dioxide and propane

    SciTech Connect (OSTI)

    Deo, M.D.; Hwang, J.; Hanson, F.V.

    1991-12-31

    Supercritical fluid extraction of complex hydrocarbon mixtures is important in separation processes, petroleum upgrading and enhanced oil recovery. In this study, a paraffinic crude oil, a bitumen- derived liquid and bitumen were extracted at several temperatures and pressures with carbon dioxide and propane to assess the effect of the size and type of compounds that makeup the feedstock on the extraction process. It was observed that the pure solvent density at the extraction conditions was not the sole variable governing extraction, and that the proximity of the extraction conditions to the pure solvent critical point affected the extraction yields and the compositions of the extracts. Heavier compounds reported to the extract phase as the extraction time increased at constant temperature and pressure and as the extraction pressure increased at constant temperature and extraction time for both the paraffin crude-propane and the bitumen-propane systems. This preferential extraction was not observed for the bitumen-derived liquid. The non-discriminatory extraction behavior of the bitumen-derived liquid was attributed to its thermal history and to the presence of the olefins and aromatics in the liquid. Phase behavior calculations using the Peng-Robinson equation of state and component lumping procedures provided reasonable agreement between calculated and experimental results for the crude oil and bitumen extractions, but failed in the prediction of the phase compositions for the bitumen-derived liquid extractions.

  7. Derivation of guidelines for uranium residual radioactive material in soil at the New Brunswick Site, Middlesex County, New Jersey

    SciTech Connect (OSTI)

    Dunning, D.; Kamboj, S.; Nimmagadda, M.; Yu, C.

    1996-02-01

    Residual radioactive material guidelines for uranium in soil were derived for the New Brunswick Site, located in Middlesex County, New Jersey. This site has been designated for remedial action under the Formerly Utilized Sites Remedial Action Program of the US Department of Energy (DOE). Residual radioactive material guidelines for individual radionuclides of concern and total uranium were derived on the basis of the requirement that the 50-year committed effective dose equivalent to a hypothetical individual who lives or works in the immediate vicinity of the New Brunswick Site should not exceed a dose of 30 mrem/yr following remedial action for the current-use and likely future-use scenarios or a dose of 100 mrem/yr for less likely future-use scenarios. The DOE residual radioactive material guideline computer code, RESRAD, was used in this evaluation; RESRAD implements the methodology described in the DOE manual for establishing residual radioactive material guidelines. The guidelines derived in this report are intended to apply to the remediation of these remaining residual radioactive materials at the site. The primary radionuclides of concern in these remaining materials are expected to be radium-226 and, to a lesser extent, natural uranium and thorium. The DOE has established generic cleanup guidelines for radium and thorium in soil; however, cleanup guidelines for other radionuclides must be derived on a site-specific basis.

  8. Structure of Mo(VI) complexes. VI. Mo(VI) oxodiperoxo complexes with urea and some of its derivatives

    SciTech Connect (OSTI)

    Timosheva, A.P.; Kazakova, E.K.; Vul`fson, S.G.

    1995-05-20

    Procedures for synthesizing Mo(VI) oxodiperoxo complexes with urea and some of its derivatives have been described. The dipole moment of the peroxo molybdenum complex with hexametapol and urea, [MoO{sub 5}(HMPT)CO(NH{sub 2}){sub 2}], has been determined, and its structure has been proposed. 10 refs.

  9. Removal potential of toxic 2378-substituted PCDD/F from incinerator flue gases by waste-derived activated carbons

    SciTech Connect (OSTI)

    Hajizadeh, Yaghoub; Onwudili, Jude A.; Williams, Paul T.

    2011-06-15

    The application of activated carbons has become a commonly used emission control protocol for the removal or adsorption of persistent organic pollutants from the flue gas streams of waste incinerators. In this study, the 2378-substituted PCDD/F removal efficiency of three types of activated carbons derived from the pyrolysis of refuse derived fuel, textile waste and scrap tyre was investigated and compared with that of a commercial carbon. Experiments were carried out in a laboratory scale fixed-bed reactor under a simulated flue gas at 275 deg. C with a reaction period of four days. The PCDD/F in the solid matrices and exhaust gas, were analyzed using gas chromatography coupled with a triple quadrupole mass spectrometer. In the absence of activated carbon adsorbent, there was a significant increase in the concentration of toxic PCDD/F produced in the reacted flyash, reaching up to 6.6 times higher than in the raw flyash. In addition, there was a substantial release of PCDD/F into the gas phase, which was found in the flue gas trapping system. By application of the different commercial, refuse derived fuel, textile and tyre activated carbons the total PCDD/F toxic equivalent removal efficiencies in the exhaust gas stream were 58%, 57%, 64% and 52%, respectively. In general, the removal of the PCDDs was much higher with an average of 85% compared to PCDFs at 41%. Analysis of the reacted activated carbons showed that there was some formation of PCDD/F, for instance, a total of 60.6 {mu}g I-TEQ kg{sup -1} toxic PCDD/F was formed in the refuse derived fuel activated carbon compared to 34 {mu}g I-TEQ kg{sup -1} in the commercial activated carbon. The activated carbons derived from the pyrolysis of waste, therefore, showed good potential as a control material for PCDD/F emissions in waste incinerator flue gases.

  10. Inhibition of adipogenesis and leptin production in 3T3-L1 adipocytes by a derivative of meridianin C

    SciTech Connect (OSTI)

    Park, Yu-Kyoung; Lee, Tae-Yoon; Choi, Jong-Soon; Hong, Victor Sukbong; Lee, Jinho; Park, Jong-Wook; Jang, Byeong-Churl

    2014-10-03

    Highlights: Compound 7b, a meridianin C derivative, inhibits adipogenesis. Compound 7b inhibits C/EBP-?, PPAR-?, FAS, STAT-3, and STAT-5 in 3T3-L1 adipocytes. Compound 7b inhibits leptin, but not adiponectin, expression in 3T3-L1 adipocytes. Compound 7b thus may have therapeutic potential against obesity. - Abstract: Meridianin C, a marine alkaloid, is a potent protein kinase inhibitor and has anti-cancer activity. We have recently developed a series of meridianin C derivatives (compound 7a7j) and reported their proviral integration Moloney Murine Leukemia Virus (pim) kinases inhibitory and anti-proliferative effects on human leukemia cells. Here we investigated the effect of these meridianin C derivatives on adipogenesis. Strikingly, among the derivatives tested, compound 7b most strongly inhibited lipid accumulation during the differentiation of 3T3-L1 preadipocytes into adipocytes. However, meridianin C treatment was largely cytotoxic to 3T3-L1 adipocytes. On mechanistic levels, compound 7b reduced not only the expressions of CCAAT/enhancer-binding protein-? (C/EBP-?), peroxisome proliferator-activated receptor-? (PPAR-?), and fatty acid synthase (FAS) but also the phosphorylation levels of signal transducer and activator of transcription-3 (STAT-3) and STAT-5 during adipocyte differentiation. Moreover, compound 7b repressed leptin, but not adiponectin, expression during adipocyte differentiation. Collectively, these findings demonstrate that a meridianin C derivative inhibits adipogenesis by down-regulating expressions and/or phosphorylations of C/EBP-?, PPAR-?, FAS, STAT-3 and STAT-5.

  11. Enhancing muconic acid production from glucose and lignin-derived aromatic compounds via increased protocatechuate decarboxylase activity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Christopher W.; Salvachua, Davinia; Khanna, Payal; Smith, Holly; Peterson, Darren J.; Beckham, Gregg T.

    2016-04-22

    The conversion of biomass-derived sugars and aromatic molecules to cis,cis-muconic acid (referred to hereafter as muconic acid or muconate) has been of recent interest owing to its facile conversion to adipic acid, an important commodity chemical. Metabolic routes to produce muconate from both sugars and many lignin-derived aromatic compounds require the use of a decarboxylase to convert protocatechuate (PCA, 3,4-dihydroxybenzoate) to catechol (1,2-dihydroxybenzene), two central aromatic intermediates in this pathway. Several studies have identified the PCA decarboxylase as a metabolic bottleneck, causing an accumulation of PCA that subsequently reduces muconate production. A recent study showed that activity of the PCAmore » decarboxylase is enhanced by co-expression of two genetically associated proteins, one of which likely produces a flavin-derived cofactor utilized by the decarboxylase. Using entirely genome-integrated gene expression, we have engineered Pseudomonas putida KT2440-derived strains to produce muconate from either aromatic molecules or sugars and demonstrate in both cases that co-expression of these decarboxylase associated proteins reduces PCA accumulation and enhances muconate production relative to strains expressing the PCA decarboxylase alone. In bioreactor experiments, co-expression increased the specific productivity (mg/g cells/h) of muconate from the aromatic lignin monomer p-coumarate by 50% and resulted in a titer of >15 g/L. In strains engineered to produce muconate from glucose, co-expression more than tripled the titer, yield, productivity, and specific productivity, with the best strain producing 4.92+/-0.48 g/L muconate. Furthermore, this study demonstrates that overcoming the PCA decarboxylase bottleneck can increase muconate yields from biomass-derived sugars and aromatic molecules in industrially relevant strains and cultivation conditions.« less

  12. Catalytic Process for the Conversion of Coal-derived Syngas to Ethanol

    SciTech Connect (OSTI)

    James Spivery; Doug Harrison; John Earle; James Goodwin; David Bruce; Xunhau Mo; Walter Torres; Joe Allison Vis Viswanathan; Rick Sadok; Steve Overbury; Viviana Schwartz

    2011-07-29

    The catalytic conversion of coal-derived syngas to C{sub 2+} alcohols and oxygenates has attracted great attention due to their potential as chemical intermediates and fuel components. This is particularly true of ethanol, which can serve as a transportation fuel blending agent, as well as a hydrogen carrier. A thermodynamic analysis of CO hydrogenation to ethanol that does not allow for byproducts such as methane or methanol shows that the reaction: 2 CO + 4 H{sub 2} {yields} C{sub 2}H{sub 5}OH + H{sub 2}O is thermodynamically favorable at conditions of practical interest (e.g,30 bar, {approx}< 250 C). However, when methane is included in the equilibrium analysis, no ethanol is formed at any conditions even approximating those that would be industrially practical. This means that undesired products (primarily methane and/or CO{sub 2}) must be kinetically limited. This is the job of a catalyst. The mechanism of CO hydrogenation leading to ethanol is complex. The key step is the formation of the initial C-C bond. Catalysts that are selective for EtOH can be divided into four classes: (a) Rh-based catalysts, (b) promoted Cu catalysts, (c) modified Fischer-Tropsch catalysts, or (d) Mo-sulfides and phosphides. This project focuses on Rh- and Cu-based catalysts. The logic was that (a) Rh-based catalysts are clearly the most selective for EtOH (but these catalysts can be costly), and (b) Cu-based catalysts appear to be the most selective of the non-Rh catalysts (and are less costly). In addition, Pd-based catalysts were studied since Pd is known for catalyzing CO hydrogenation to produce methanol, similar to copper. Approach. The overall approach of this project was based on (a) computational catalysis to identify optimum surfaces for the selective conversion of syngas to ethanol; (b) synthesis of surfaces approaching these ideal atomic structures, (c) specialized characterization to determine the extent to which the actual catalyst has these structures, and (d) testing

  13. Human monoclonal antibodies derived from a patient infected with 2009 pandemic influenza A virus broadly cross-neutralize group 1 influenza viruses

    SciTech Connect (OSTI)

    Pan, Yang; Sasaki, Tadahiro; Du, Anariwa; and others

    2014-07-18

    Highlights: Influenza infection can elicit heterosubtypic antibodies to group 1 influenza virus. Three human monoclonal antibodies were generated from an H1N1-infected patient. The antibodies predominantly recognized ?-helical stem of viral hemagglutinin (HA). The antibodies inhibited HA structural activation during the fusion process. The antibodies are potential candidates for future antibody therapy to influenza. - Abstract: Influenza viruses are a continuous threat to human public health because of their ability to evolve rapidly through genetic drift and reassortment. Three human monoclonal antibodies (HuMAbs) were generated in this study, 1H11, 2H5 and 5G2, and they cross-neutralize a diverse range of group 1 influenza A viruses, including seasonal H1N1, 2009 pandemic H1N1 (H1N1pdm) and avian H5N1 and H9N2. The three HuMAbs were prepared by fusing peripheral blood lymphocytes from an H1N1pdm-infected patient with a newly developed fusion partner cell line, SPYMEG. All the HuMAbs had little hemagglutination inhibition activity but had strong membrane-fusion inhibition activity against influenza viruses. A protease digestion assay showed the HuMAbs targeted commonly a short ?-helix region in the stalk of the hemagglutinin. Furthermore, Ile45Phe and Glu47Gly double substitutions in the ?-helix region made the HA unrecognizable by the HuMAbs. These two amino acid residues are highly conserved in the HAs of H1N1, H5N1 and H9N2 viruses. The HuMAbs reported here may be potential candidates for the development of therapeutic antibodies against group 1 influenza viruses.

  14. A human monoclonal antibody derived from a vaccinated volunteer recognizes heterosubtypically a novel epitope on the hemagglutinin globular head of H1 and H9 influenza A viruses

    SciTech Connect (OSTI)

    Boonsathorn, Naphatsawan; Panthong, Sumolrat; Chittaganpitch, Malinee; Phuygun, Siripaporn; Waicharoen, Sunthareeya; Prachasupap, Apichai; Yasugi, Mayo; Ono, Ken-ichiro; and others

    2014-09-26

    Highlights: A human monoclonal antibody against influenza virus was produced from a volunteer. The antibody was generated from the PBMCs of the volunteer using the fusion method. The antibody neutralized heterosubtypically group 1 influenza A viruses (H1 and H9). The antibody targeted a novel epitope in globular head region of the hemagglutinin. Sequences of the identified epitope are highly conserved among H1 and H9 subtypes. - Abstract: Most neutralizing antibodies elicited during influenza virus infection or by vaccination have a narrow spectrum because they usually target variable epitopes in the globular head region of hemagglutinin (HA). In this study, we describe a human monoclonal antibody (HuMAb), 5D7, that was prepared from the peripheral blood lymphocytes of a vaccinated volunteer using the fusion method. The HuMAb heterosubtypically neutralizes group 1 influenza A viruses, including seasonal H1N1, 2009 pandemic H1N1 (H1N1pdm) and avian H9N2, with a strong hemagglutinin inhibition activity. Selection of an escape mutant showed that the HuMAb targets a novel conformational epitope that is located in the HA head region but is distinct from the receptor binding site. Furthermore, Phe114Ile substitution in the epitope made the HA unrecognizable by the HuMAb. Amino acid residues in the predicted epitope region are also highly conserved in the HAs of H1N1 and H9N2. The HuMAb reported here may be a potential candidate for the development of therapeutic/prophylactic antibodies against H1 and H9 influenza viruses.

  15. Lewis Acid Pairs for the Activation of Biomass-derived Oxygenates in Aqueous Media

    SciTech Connect (OSTI)

    Roman, Yuriy

    2015-09-14

    The objective of this project is to understand the mechanistic aspects behind the cooperative activation of oxygenates by catalytic pairs in aqueous media. Specifically, we will investigate how the reactivity of a solid Lewis acid can be modulated by pairing the active site with other catalytic sites at the molecular level, with the ultimate goal of enhancing activation of targeted functional groups. Although unusual catalytic properties have been attributed to the cooperative effects promoted by such catalytic pairs, virtually no studies exist detailing the use heterogeneous water-tolerant Lewis pairs. A main goal of this work is to devise rational pathways for the synthesis of porous heterogeneous catalysts featuring isolated Lewis pairs that are active in the transformation of biomass-derived oxygenates in the presence of bulk water. Achieving this technical goal will require closely linking advanced synthesis techniques; detailed kinetic and mechanistic investigations; strict thermodynamic arguments; and comprehensive characterization studies of both materials and reaction intermediates. For the last performance period (2014-2015), two technical aims were pursued: 1) C-C coupling using Lewis acid and base pairs in Lewis acidic zeolites. Tin-, zirconium-, and hafnium containing zeolites (e.g., Sn-, Zr-, and Hf-Beta) are versatile solid Lewis acids that selectively activate carbonyl functional groups. In this aim, we demonstrate that these zeolites catalyze the cross-aldol condensation of aromatic aldehydes with acetone under mild reaction conditions with near quantitative yields. NMR studies with isotopically labeled molecules confirm that acid-base pairs in the Si-O-M framework ensemble promote soft enolization through α-proton abstraction. The Lewis acidic zeolites maintain activity in the presence of water and, unlike traditional base catalysts, in acidic solutions. 2) One-pot synthesis of MWW zeolite nanosheets for activation of bulky substrates. Through

  16. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. Emission testing indicates that the coal derived material has more trace metals related to coal than petroleum, as seen in previous runs. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. The co-coking of the runs with the new coal have begun, with the coke yield similar to previous runs, but the gas yield is lower and the liquid yield is higher. Characterization of the products continues. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking.

  17. Steady state estimation of soil organic carbon using satellite-derived canopy leaf area index

    SciTech Connect (OSTI)

    Fang, Yilin; Liu, Chongxuan; Huang, Maoyi; Li, Hongyi; Leung, Lai-Yung R.

    2014-12-02

    Soil organic carbon (SOC) plays a key role in the global carbon cycle that is important for decadal-to-century climate prediction. Estimation of soil organic carbon stock using model-based methods typically requires spin-up (time marching transient simulation) of the carbon-nitrogen (CN) models by performing hundreds to thousands years long simulations until the carbon-nitrogen pools reach dynamic steady-state. This has become a bottleneck for global modeling and analysis, especially when testing new physical and/or chemical mechanisms and evaluating parameter sensitivity. Here we report a new numerical approach to estimate global soil carbon stock that can avoid the long term spin-up of the CN model. The approach uses canopy leaf area index (LAI) from satellite data and takes advantage of a reaction-based biogeochemical module NGBGC (Next Generation BioGeoChemical Module) that was recently developed and incorporated in version 4 of the Community Land Model (CLM4). Although NGBGC uses the same CN mechanisms as used in CLM4CN, it can be easily configured to run prognostic or steady state simulations. In this approach, monthly LAI from the multi-year Moderate Resolution Imaging Spectroradiometer (MODIS) data was used to calculate potential annual average gross primary production (GPP) and leaf carbon for the period of the atmospheric forcing. The calculated potential annual average GPP and leaf C are then used by NGBGC to calculate the steady-state distributions of carbon and nitrogen in different vegetation and soil pools by solving the steady-state reaction-network in NGBGC using the Newton-Raphson method. The new approach was applied at point and global scales and compared with SOC derived from long spin-up by running NGBGC in prognostic mode, and SOC from the empirical data of the Harmonized World Soil Database (HWSD). The steady-state solution is comparable to the spin-up value when the MODIS LAI is close to the LAI from the spin-up solution, and largely

  18. Steady state estimation of soil organic carbon using satellite-derived canopy leaf area index

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fang, Yilin; Liu, Chongxuan; Huang, Maoyi; Li, Hongyi; Leung, Lai-Yung R.

    2014-12-02

    Soil organic carbon (SOC) plays a key role in the global carbon cycle that is important for decadal-to-century climate prediction. Estimation of soil organic carbon stock using model-based methods typically requires spin-up (time marching transient simulation) of the carbon-nitrogen (CN) models by performing hundreds to thousands years long simulations until the carbon-nitrogen pools reach dynamic steady-state. This has become a bottleneck for global modeling and analysis, especially when testing new physical and/or chemical mechanisms and evaluating parameter sensitivity. Here we report a new numerical approach to estimate global soil carbon stock that can avoid the long term spin-up of themore » CN model. The approach uses canopy leaf area index (LAI) from satellite data and takes advantage of a reaction-based biogeochemical module NGBGC (Next Generation BioGeoChemical Module) that was recently developed and incorporated in version 4 of the Community Land Model (CLM4). Although NGBGC uses the same CN mechanisms as used in CLM4CN, it can be easily configured to run prognostic or steady state simulations. In this approach, monthly LAI from the multi-year Moderate Resolution Imaging Spectroradiometer (MODIS) data was used to calculate potential annual average gross primary production (GPP) and leaf carbon for the period of the atmospheric forcing. The calculated potential annual average GPP and leaf C are then used by NGBGC to calculate the steady-state distributions of carbon and nitrogen in different vegetation and soil pools by solving the steady-state reaction-network in NGBGC using the Newton-Raphson method. The new approach was applied at point and global scales and compared with SOC derived from long spin-up by running NGBGC in prognostic mode, and SOC from the empirical data of the Harmonized World Soil Database (HWSD). The steady-state solution is comparable to the spin-up value when the MODIS LAI is close to the LAI from the spin-up solution, and largely

  19. Precursor Derived Nanostructured Si-C-X Materials for Nuclear Applications. Final Report, October 2010 - September 2014

    SciTech Connect (OSTI)

    Bordia, Rajendra; Tomar, Vikas; Henager, Chuck

    2015-04-08

    Polymer derived ceramic route is an attractive approach to make structural materials with unique nanostructures that have very desirable high temperature properties. Processing techniques to make a variety of needed shapes and forms (e.g. coatings, matrices for fiber reinforced composites, porous ceramics) have been developed. With appropriate high temperature processing, the precursors can be converted to nano-crystalline materials. In this collaborative project, we investigated the processing, stability and properties of nanostructured Si-C materials, derived from polymeric precursors, and their performance under conditions appropriate for nuclear energy applications. All the milestones of the project were accomplished. Some of the results are being currently analyzed and additional papers being prepared in which support from NEUP will be acknowledged. So far, eight peer-reviewed papers have been published and one invention disclosure made. In this report, we summarize the major findings of this project.

  20. DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS

    SciTech Connect (OSTI)

    Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

    2012-09-30

    The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

  1. The Spectrum of the Isotropic Diffuse Gamma-Ray Emission Derived From First-Year Fermi Large Area Telescope Data

    SciTech Connect (OSTI)

    Abdo, A. A.

    2011-08-19

    We report on the first Fermi Large Area Telescope (LAT) measurements of the so-called 'extra-galactic' diffuse {gamma}-ray emission (EGB). This component of the diffuse {gamma}-ray emission is generally considered to have an isotropic or nearly isotropic distribution on the sky with diverse contributions discussed in the literature. The derivation of the EGB is based on detailed modelling of the bright foreground diffuse Galactic {gamma}-ray emission (DGE), the detected LAT sources and the solar {gamma}-ray emission. We find the spectrum of the EGB is consistent with a power law with differential spectral index {gamma} = 2.41 {+-} 0.05 and intensity, I(> 100 MeV) = (1.03 {+-} 0.17) x 10{sup -5} cm{sup -2} s{sup -1} sr{sup -1}, where the error is systematics dominated. Our EGB spectrum is featureless, less intense, and softer than that derived from EGRET data.

  2. Expression of WNT genes in cervical cancer-derived cells: Implication of WNT7A in cell proliferation and migration

    SciTech Connect (OSTI)

    Ramos-Solano, Moisés; Meza-Canales, Ivan D.; Torres-Reyes, Luis A.; Alvarez-Zavala, Monserrat; and others

    2015-07-01

    According to the multifactorial model of cervical cancer (CC) causation, it is now recognized that other modifications, in addition to Human papillomavirus (HPV) infection, are necessary for the development of this neoplasia. Among these, it has been proposed that a dysregulation of the WNT pathway might favor malignant progression of HPV-immortalized keratinocytes. The aim of this study was to identify components of the WNT pathway differentially expressed in CC vs. non-tumorigenic, but immortalized human keratinocytes. Interestingly, WNT7A expression was found strongly downregulated in cell lines and biopsies derived from CC. Restoration of WNT7A in CC-derived cell lines using a lentiviral gene delivery system or after adding a recombinant human protein decreases cell proliferation. Likewise, WNT7A silencing in non-tumorigenic cells markedly accelerates proliferation. Decreased WNT7A expression was due to hypermethylation at particular CpG sites. To our knowledge, this is the first study reporting reduced WNT7A levels in CC-derived cells and that ectopic WNT7A restoration negatively affects cell proliferation and migration. - Highlights: • WNT7A is expressed in normal keratinocytes or cervical cells without lesion. • WNT7A is significantly reduced in cervical cancer-derived cells. • Restoration of WNT7A expression in HeLa decreases proliferation and cell migration. • Silencing of WNT7A in HaCaT induces an increased proliferation and migration rate. • Decreased WNT7A expression in this model is due to hypermethylation.

  3. Distribution and Validation of Cloud Cover Derived from AVHRR Data Over the Arctic Ocean During the SHEBA Year

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Validation of Cloud Cover Derived from AVHRR Data Over the Arctic Ocean During the SHEBA Year P. Minnis National Aeronautics and Space Administration Langley Research Center Hampton, Virginia D. A. Spangenberg and V. Chakrapani Analytical Services and Materials, Inc. Hampton, Virginia Introduction Determination of cloud radiation interactions over large areas of the Arctic is possible only with the use of data from polar orbiting satellites. Cloud detection using satellite data is difficult

  4. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 6, January--March 1996

    SciTech Connect (OSTI)

    Pan, W.P.; Riley, J.T.; Lloyd, W.G.

    1996-02-29

    The objectives for this quarter of study on the co-firing of high sulfur coals with refuse derived fuels were two-fold. First, the effects of different experimental parameters such as temperature, flow rates and reaction times on the formation of chlorinated organic compounds were studied using the tubular furnace as a reactor followed by GC/MS analysis. Secondly, the effect of fuel/air ratio on the flue gas composition and combustion efficiency were studied with the AFBC system.

  5. Host cells and methods for producing 1-deoxyxylulose 5-phosphate (DXP) and/or a DXP derived compound

    DOE Patents [OSTI]

    Kirby, James; Fortman, Jeffrey L.; Nishimoto, Minobu; Keasling, Jay D.

    2016-07-05

    The present invention provides for a genetically modified host cell capable of producing 1-deoxyxylulose 5-phosphate or 1-deoxy-D-xylulose 5-phosphate (DXP) (12), and optionally one or more DXP derived compounds, comprising: (a) a mutant RibB, or functional variant thereof, capable of catalyzing xylulose 5-phosphate and/or ribulose 5-phosphate to DXP, or (b) a YajO, or functional variant thereof, and a XylB, or functional variant thereof.

  6. Evaluation of Tropical Cirrus Cloud Properties and Dynamical Processes Derived from ECMWF Model Output and Ground Based Mea...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tropical Cirrus Cloud Properties and Dynamical Processes Derived from ECMWF Model Output and Ground-Based Measurements Over Nauru Island J. M. Comstock and J. H. Mather Pacific Northwest National Laboratory Richland, Washington C. Jakob Bureau of Meteorology Research Centre Melbourne, Australia Introduction Identifying the mechanisms responsible for the formation of cirrus clouds is important in understanding the role of cirrus in the tropical atmosphere. Thin cirrus clouds near the tropical

  7. Integrated Study of MFRSR-derived Parameters of Atmospheric Aerosols and Trace Gases Over the ARM CART Site Extended Facili...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integrated Study of MFRSR-Derived Parameters of Atmospheric Aerosols and Trace Gases Over the ARM CART Site Extended Facilities - Comparison with Satellite and Other Ground-Based Measurements M. D. Alexandrov and B. Cairns Columbia University National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York A. A. Lacis and B. E. Carlson National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York Comparison of SGP MFRSR

  8. Cloud Microphysical and Radiative Properties Derived from MODIS, VIRS, AVHRR, and GMS Data Over the Tropical Western Pacific

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microphysical and Radiative Properties Derived from MODIS, VIRS, AVHRR, and GMS Data Over the Tropical Western Pacific G. D. Nowicki, M. L. Nordeen, P. W. Heck, D. R. Doelling, and M. M. Khaiyer Analytical Services and Materials, Inc. Hampton, Virginia P. Minnis National Aeronautics and Space Administration Atmospheric Sciences Division Langley Research Center Hampton, Virginia S. Sun-Mack Science Applications International Corporation Hampton, Virginia Introduction Utilization of the

  9. Study on reduction and back extraction of Pu(IV) by urea derivatives in nitric acid conditions

    SciTech Connect (OSTI)

    Ye, G.A.; Xiao, S.T.; Yan, T.H.; Lin, R.S.; Zhu, Z.W.

    2013-07-01

    The reduction kinetics of Pu(IV) by hydroxyl-semicarbazide (HSC), hydroxyurea (HU) and di-hydroxyurea (DHU) in nitric acid solutions were investigated separately with adequate kinetic equations. In addition, counter-current cascade experiments were conducted for Pu split from U in nitric acid media using three kinds of reductant, respectively. The results show that urea derivatives as a kind of novel salt-free reductant can reduce Pu(IV) to Pu(III) rapidly in the nitric acid solutions. The stripping experimental results showed that Pu(IV) in the organic phase can be stripped rapidly to the aqueous phase by the urea derivatives, and the separation factors of plutonium /uranium can reach more than 10{sup 4}. This indicates that urea derivatives is a kind of promising salt-free agent for uranium/plutonium separation. In addition, the complexing effect of HSC with Np(IV) was revealed, and Np(IV) can be back-extracted by HSC with a separation factor of about 20.

  10. Comparison of coal/solid recovered fuel (SRF) with coal/refuse derived fuel (RDF) in a fluidised bed reactor

    SciTech Connect (OSTI)

    Wagland, S.T.; Kilgallon, P.; Coveney, R.; Garg, A.; Smith, R.; Longhurst, P.J.; Pollard, S.J.T.; Simms, N.

    2011-06-15

    An experimental study was undertaken to compare the differences between municipal solid waste (MSW) derived solid recovered fuel (SRF) (complying with CEN standards) and refuse derived fuel (RDF). Both fuels were co-combusted with coal in a 50 kW fluidised bed combustor and the metal emissions were compared. Synthetic SRF was prepared in the laboratory by grinding major constituents of MSW such as paper, plastic, textile and wood. RDF was obtained from a local mechanical treatment plant. Heavy metal emissions in flue gas and ash samples from the (coal + 10% SRF) fuel mixture were found to be within the acceptable range and were generally lower than that obtained for coal + 10% RDF fuel mixture. The relative distribution of heavy metals in ash components and the flue gas stream shows the presence of a large fraction (up to 98%) of most of the metals in the ash (except Hg and As). Thermo-gravimetric (TG) analysis of SRF constituents was performed to understand the behaviour of fuel mixtures in the absence and presence of air. The results obtained from the experimental study will enhance the confidence of fuel users towards using MSW-derived SRF as an alternative fuel.

  11. Note: Derivation of two-photon circular dichroism—Addendum to “Two-photon circular dichroism” [J. Chem. Phys. 62, 1006 (1975)

    SciTech Connect (OSTI)

    Friese, Daniel H.

    2015-09-07

    This addendum shows the detailed derivation of the fundamental equations for two-photon circular dichroism which are given in a very condensed form in the original publication [I. Tinoco, J. Chem. Phys. 62, 1006 (1975)]. In addition, some minor errors are corrected and some of the derivations in the original publication are commented.

  12. Interaction of iron-copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal

    SciTech Connect (OSTI)

    Siriwardane, Ranjani V.; Ksepko, Ewelina; Tian, Hanging

    2013-01-01

    The objective of this work was to prepare supported bimetallic Fe–Cu oxygen carriers and to evaluate their performance for the chemical-looping combustion (CLC) process with simulated synthesis gas derived from steam gasification of coal/air. Ten-cycle CLC tests were conducted with Fe–Cu oxygen carriers in an atmospheric thermogravimetric analyzer utilizing simulated synthesis gas derived from the steam gasification of Polish Janina coal and Illinois #6 coal as fuel. The effect of temperature on reaction rates, chemical stability, and oxygen transport capacity were determined. Fractional reduction, fractional oxidation, and global rates of reactions were calculated from the thermogravimetric analysis (TGA) data. The supports greatly affected reaction performance. Data showed that reaction rates and oxygen capacities were stable during the 10-cycle TGA tests for most Fe–Cu/support oxygen carriers. Bimetallic Fe–Cu/support oxygen carriers showed higher reduction rates than Fe-support oxygen carriers. The carriers containing higher Cu content showed better stabilities and better reduction rates. An increase in temperature from 800 °C to 900 °C did not have a significant effect on either the oxygen capacity or the reduction rates with synthesis gas derived from Janina coal. Oxidation reaction was significantly faster than reduction reaction for all supported Fe–Cu oxygen carriers. Carriers with higher Cu content had lower oxidation rates. Ten-cycle TGA data indicated that these oxygen carriers had stable performances at 800–900 °C and might be successfully used up to 900 °C for coal CLC reaction in the presence of steam.

  13. Charge carrier effective mass and concentration derived from combination of Seebeck coefficient and Te125 NMR measurements in complex tellurides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Levin, E. M.

    2016-06-27

    Thermoelectric materials utilize the Seebeck effect to convert heat to electrical energy. The Seebeck coefficient (thermopower), S, depends on the free (mobile) carrier concentration, n, and effective mass, m*, as S ~ m*/n2/3. The carrier concentration in tellurides can be derived from 125Te nuclear magnetic resonance (NMR) spin-lattice relaxation measurements. The NMR spin-lattice relaxation rate, 1/T1, depends on both n and m* as 1/T1~(m*)3/2n (within classical Maxwell-Boltzmann statistics) or as 1/T1~(m*)2n2/3 (within quantum Fermi-Dirac statistics), which challenges the correct determination of the carrier concentration in some materials by NMR. Here it is shown that the combination of the Seebeck coefficientmore » and 125Te NMR spin-lattice relaxation measurements in complex tellurides provides a unique opportunity to derive the carrier effective mass and then to calculate the carrier concentration. This approach was used to study AgxSbxGe50–2xTe50, well-known GeTe-based high-efficiency tellurium-antimony-germanium-silver thermoelectric materials, where the replacement of Ge by [Ag+Sb] results in significant enhancement of the Seebeck coefficient. Thus, values of both m* and n derived using this combination show that the enhancement of thermopower can be attributed primarily to an increase of the carrier effective mass and partially to a decrease of the carrier concentration when the [Ag+Sb] content increases.« less

  14. Efficient myogenic differentiation of human adipose-derived stem cells by the transduction of engineered MyoD protein

    SciTech Connect (OSTI)

    Sung, Min Sun; Biosystems and Bioengineering Program, University of Science and Technology , Daejeon 305-350 ; Mun, Ji-Young; Kwon, Ohsuk; Biosystems and Bioengineering Program, University of Science and Technology , Daejeon 305-350 ; Kwon, Ki-Sun; Oh, Doo-Byoung; Biosystems and Bioengineering Program, University of Science and Technology , Daejeon 305-350

    2013-07-19

    Highlights: •MyoD was engineered to contain protein transduction domain and endosome-disruptive INF7 peptide. •The engineered MyoD-IT showed efficient nuclear targeting through an endosomal escape by INF7 peptide. •By applying MyoD-IT, human adipose-derived stem cells (hASCs) were differentiated into myogenic cells. •hASCs differentiated by applying MyoD-IT fused to myotubes through co-culturing with mouse myoblasts. •Myogenic differentiation using MyoD-IT is a safe method without the concern of altering the genome. -- Abstract: Human adipose-derived stem cells (hASCs) have great potential as cell sources for the treatment of muscle disorders. To provide a safe method for the myogenic differentiation of hASCs, we engineered the MyoD protein, a key transcription factor for myogenesis. The engineered MyoD (MyoD-IT) was designed to contain the TAT protein transduction domain for cell penetration and the membrane-disrupting INF7 peptide, which is an improved version of the HA2 peptide derived from influenza. MyoD-IT showed greatly improved nuclear targeting ability through an efficient endosomal escape induced by the pH-sensitive membrane disruption of the INF7 peptide. By applying MyoD-IT to a culture, hASCs were efficiently differentiated into long spindle-shaped myogenic cells expressing myosin heavy chains. Moreover, these cells differentiated by an application of MyoD-IT fused to myotubes with high efficiency through co-culturing with mouse C2C12 myoblasts. Because internalized proteins can be degraded in cells without altering the genome, the myogenic differentiation of hASCs using MyoD-IT would be a safe and clinically applicable method.

  15. Analysis of Coconut-Derived Biodiesel and Conventional Diesel Fuel Samples from the Philippines: Task 2 Final Report

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Analysis of Coconut-Derived Biodiesel and Conventional Diesel Fuel Samples from the Philippines Task 2 Final Report T.L. Alleman and R.L. McCormick Milestone Report NREL/MP-540-38643 January 2006 National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov Operated for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy by Midwest Research Institute * Battelle Contract No. DE-AC36-99-GO10337 Analysis of Coconut-

  16. Refuse-derived fuels in US Air Force heating and power systems. Final report, June 1982-February 1985

    SciTech Connect (OSTI)

    Joensen, A.W.

    1986-01-01

    This investigation was conducted to document and review all data associated with densified refuse-derived fuel (dRDF)--its preparation and properties, storage and handling, boiler cofiring efficiency and environmental emissions, potential boiler metal wastage, and any other experiences associated with the use of this fuel. The results of this investigation provide the basis for the development of an optimum dRDF fuel specification. These results identify performance characteristics and operating problems of the existing dRDF fuel pellet and contain an economic feasibility assessment of using this fuel.

  17. Room temperature strain rate sensitivity in precursor derived HfO{sub 2}/Si-C-N(O) ceramic nanocomposites

    SciTech Connect (OSTI)

    Sujith, Ravindran; Kumar, Ravi

    2014-01-15

    Investigation on the room temperature strain rate sensitivity using depth sensing nanoindentation is carried out on precursor derived HfO{sub 2}/Si-C-N(O) ceramic nanocomposite sintered using pulsed electric current sintering. Using constant load method the strain rate sensitivity values are estimated. Lower strain rate sensitivity of ? 3.7 10{sup ?3} is observed and the limited strain rate sensitivity of these ceramic nanocomposites is explained in terms of cluster model. It is concluded that presence of amorphous Si-C-N(O) clusters are responsible for the limited flowability in these ceramics.

  18. Combustion characterization of coal/refuse derived fuels using thermogravimetric-fourier transform infrared-mass spectrometry

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Lu, Huagang; Hyatt, J.

    1995-12-31

    The fundamental thermal behavior of five materials (Illinois coal No. 6, Kentucky coal No. 9, polyvinyl chloride, cellulose, newspaper) has been investigated using the TGA/FTIR/MS system under the condition of combustion. The system was used to identify molecular chlorine, along with HCI, CO, CO{sub 2}, H{sub 2}O and various hydrocarbons in the gaseous products of the combustion of PVC resin in air. This is a significant finding that will lead us to examine this combustion step further to look for the formation of chlorinated organic compounds during co-firing of coal with refuse derived fuels.

  19. Coal-firing sulfur coal with refuse derived fuels. Technical progress report {number_sign}7, [April--June 1996

    SciTech Connect (OSTI)

    Pan, Wei-Ping, Riley, J.T.; Lloyd, W.G.

    1996-05-31

    The objectives for this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the organic compounds tentatively identified as combustion products in the previous report were confirmed by comparing retention times with pure samples. Secondly, a reduced amount of unburned carbon in the fly ash and an oxygen concentration at about 3--6% in the flue gases were achieved by the addition of removable heat exchange tubes in the AFBC system.

  20. Assessment of the percent status of burning refuse-derived fuel as a fuel supplement in the cement kiln industry

    SciTech Connect (OSTI)

    1981-09-01

    The purpose of the project was to solicit information on the use of refuse-derived fuel (RDF) in cement kilns by survey, follow up the mailed survey with telephone calls to the recipients, and assemble collected information into a report. A list of companies that had some experience with RFD was compiled and is presented in Appendix A. The procedure for conducting the survey is explained. A copy of the questionnaire is presented in Appendix B. The letters of response are reproduced in Appendix C. Two completed forms were received and clear conclusions are summarized. The effort was terminated and no final report was assembled.

  1. Synthesis of acrylates and methacrylates from coal-derived syngas. Quarterly technical progress report, October 1--December 31, 1994

    SciTech Connect (OSTI)

    Not Available

    1995-03-01

    The objective of Task 1, Synthesis of Propionates, is to develop the technology for a low cost generation of propionate feedstocks (methacrylates, primarily). The process is described and results are summarized for: (a) in-situ spectroscopic probes; (b) by-product determination; and (c) kinetics. A mechanistic proposal is discussed and schemes for the generation of propionic anhydride and generation of 5-ethyl-1-hydro-2-furanone are disclosed. The objective of Task 2, Condensation Catalysis, is the development of an experimental data base for the rapid condensation of formaldehyde, or its derivatives, with acetates and propionates. Plans for the investigation are discussed.

  2. Exome-wide mutation profile in benzo[a]pyrene-derived post-stasis and immortal human mammary epithelial cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Severson, Paul L.; Vrba, Lukas; Stampfer, Martha R.; Futscher, Bernard W.

    2014-11-04

    Genetic mutations are known to drive cancer progression and certain tumors have mutation signatures that reflect exposures to environmental carcinogens. Benzo[a]pyrene (BaP) has a known mutation signature and has proven capable of inducing changes to DNA sequence that drives normal pre-stasis human mammary epithelial cells (HMEC) past a first tumor suppressor barrier (stasis) and toward immortality. We analyzed normal, pre-stasis HMEC, three independent BaP-derived post-stasis HMEC strains (184Aa, 184Be, 184Ce) and two of their immortal derivatives(184A1 and 184BE1) by whole exome sequencing. The independent post-stasis strains exhibited between 93 and 233 BaP-induced mutations in exons. Seventy percent of the mutationsmore » were C:G>A:T transversions, consistent with the known mutation spectrum of BaP. Mutations predicted to impact protein function occurred in several known and putative cancer drivers including p16, PLCG1, MED12, TAF1 in 184Aa; PIK3CG, HSP90AB1, WHSC1L1, LCP1 in 184Be and FANCA, LPP in 184Ce. Biological processes that typically harbor cancer driver mutations such as cell cycle, regulation of cell death and proliferation, RNA processing, chromatin modification and DNA repair were found to have mutations predicted to impact function in each of the post-stasis strains. Spontaneously immortalized HMEC lines derived from two of the BaP-derived post-stasis strains shared greater than 95% of their BaP-induced mutations with their precursor cells. These immortal HMEC had 10 or fewer additional point mutations relative to their post-stasis precursors, but acquired chromosomal anomalies during immortalization that arose independent of BaP. In conclusion, the results of this study indicate that acute exposures of HMEC to high dose BaP recapitulate mutation patterns of human tumors and can induce mutations in a number of cancer driver genes.« less

  3. Audit of Economic Development Grants and a Cooperative Agreement...

    Energy Savers [EERE]

    initiative ETEC 1,500,000 Technical reuse of Departmental facilities ETEC 100,000 Feasibility studies ETEC 100,000 21st century jobs initiative TRV 750,000 Environmental...

  4. Graphene-wrapped sulfur/metal organic framework-derived microporous carbon composite for lithium sulfur batteries

    SciTech Connect (OSTI)

    Chen, Renjie E-mail: chenrj@bit.edu.cn; Zhao, Teng; Tian, Tian; Fairen-Jimenez, David; Cao, Shuai; Coxon, Paul R.; Xi, Kai E-mail: chenrj@bit.edu.cn; Vasant Kumar, R.; Cheetham, Anthony K.

    2014-12-01

    A three-dimensional hierarchical sandwich-type graphene sheet-sulfur/carbon (GS-S/C{sub ZIF8-D}) composite for use in a cathode for a lithium sulfur (Li-S) battery has been prepared by an ultrasonic method. The microporous carbon host was prepared by a one-step pyrolysis of Zeolitic Imidazolate Framework-8 (ZIF-8), a typical zinc-containing metal organic framework (MOF), which offers a tunable porous structure into which electro-active sulfur can be diffused. The thin graphene sheet, wrapped around the sulfur/zeolitic imidazolate framework-8 derived carbon (S/C{sub ZIF8-D}) composite, has excellent electrical conductivity and mechanical flexibility, thus facilitating rapid electron transport and accommodating the changes in volume of the sulfur electrode. Compared with the S/C{sub ZIF8-D} sample, Li-S batteries with the GS-S/C{sub ZIF8-D} composite cathode showed enhanced capacity, improved electrochemical stability, and relatively high columbic efficiency by taking advantage of the synergistic effects of the microporous carbon from ZIF-8 and a highly interconnected graphene network. Our results demonstrate that a porous MOF-derived scaffold with a wrapped graphene conductive network structure is a potentially efficient design for a battery electrode that can meet the challenge arising from low conductivity and volume change.

  5. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  6. Derivation of residual radioactive material guidelines for uranium in soil at the Middlesex Sampling Plant Site, Middlesex, New Jersey

    SciTech Connect (OSTI)

    Dunning, D.E.

    1995-02-01

    Residual radioactive material guidelines for uranium in soil were derived for the Middlesex Sampling Plant (MSP) site in Middlesex, New Jersey. This site has been designated for remedial action under the Formerly Utilized Sites Remedial Action Program (FUSRAP) of the US Department of Energy. The site became contaminated from operations conducted in support of the Manhattan Engineer District (MED) and the Atomic Energy Commission (AEC) between 1943 and 1967. Activities conducted at the site included sampling, storage, and shipment of uranium, thorium, and beryllium ores and residues. Uranium guidelines for single radioisotopes and total uranium were derived on the basis of the requirement that the 50-year committed effective dose equivalent to a hypothetical individual living or working in the immediate vicinity of the MSP site should not exceed a dose of 30 mrem/yr following remedial action for the current-use and likely future-use scenarios or a dose of 100 mrem/yr for less likely future-use scenarios. The RESRAD computer code, which implements the methodology described in the DOE manual for establishing residual radioactive material guidelines, was used in this evaluation. Four scenarios were considered for the site. These scenarios vary regarding future land use at the site, sources of water used, and sources of food consumed.

  7. Lung cancer-derived Dickkopf1 is associated with bone metastasis and the mechanism involves the inhibition of osteoblast differentiation

    SciTech Connect (OSTI)

    Chu, Tianqing; Teng, Jiajun; Jiang, Liyan; Zhong, Hua; Han, Baohui

    2014-01-17

    Highlights: DKK1 level was associated with NSCLC bone metastases. Lung tumor cells derived DKK1 inhibited osteoblast differentiation. Lung tumor cells derived DKK1 modulates ?-catenin and RUNX2. -- Abstract: Wnt/?-catenin signaling and Dickkopf1 (DKK1) play important roles in the progression of lung cancer, which preferably metastasizes to skeleton. But the role of them in bone dissemination is poorly understood. This study aims to define the role of DKK1 in lung cancer bone metastases and investigate the underlying mechanism. Our results demonstrated that DKK1 over-expression was a frequent event in non-small-cell lung cancer (NSCLC) blood samples, and serous DKK1 level was much higher in bone metastatic NSCLC compared to non-bone metastatic NSCLC. We also found that conditioned medium from DKK1 over-expressing lung cancer cells inhibited the differentiation of osteoblast, determined by alkaline phosphatase activity and osteocalcin secretion, whereas the conditioned medium from DKK1 silencing lung cancer cells exhibited the opposite effects. Mechanistically, DKK1 reduced the level of ?-catenin and RUNX2, as well as inhibiting the nuclear translocation of ?-catenin. Taken together, these results suggested that lung cancer-produced DKK1 may be an important mechanistic link between NSCLC and bone metastases, and targeting DKK1 may be an effective method to treat bone metastase of NSCLC.

  8. Conceptual Engine System Design for NERVA derived 66.7KN and 111.2KN Thrust Nuclear Thermal Rockets

    SciTech Connect (OSTI)

    Fittje, James E.; Buehrle, Robert J.

    2006-01-20

    The Nuclear Thermal Rocket concept is being evaluated as an advanced propulsion concept for missions to the moon and Mars. A tremendous effort was undertaken during the 1960's and 1970's to develop and test NERVA derived Nuclear Thermal Rockets in the 111.2 KN to 1112 KN pound thrust class. NASA GRC is leveraging this past NTR investment in their vehicle concepts and mission analysis studies, and has been evaluating NERVA derived engines in the 66.7 KN to the 111.2 KN thrust range. The liquid hydrogen propellant feed system, including the turbopumps, is an essential component of the overall operation of this system. The NASA GRC team is evaluating numerous propellant feed system designs with both single and twin turbopumps. The Nuclear Engine System Simulation code is being exercised to analyze thermodynamic cycle points for these selected concepts. This paper will present propellant feed system concepts and the corresponding thermodynamic cycle points for 66.7 KN and 111.2 KN thrust NTR engine systems. A pump out condition for a twin turbopump concept will also be evaluated, and the NESS code will be assessed against the Small Nuclear Rocket Engine preliminary thermodynamic data.

  9. Synthesis and evaluation of novel [alpha]-heteroaryl-phenylpropanoic acid derivatives as PPAR[alpha/gamma] dual agonists

    SciTech Connect (OSTI)

    Casimiro-Garcia, Agustin; Bigge, Christopher F.; Davis, Jo Ann; Padalino, Teresa; Pulaski, James; Ohren, Jeffrey F.; McConnell, Patrick; Kane, Christopher D.; Royer, Lori J.; Stevens, Kimberly A.; Auerbach, Bruce; Collard, Wendy; McGregor, Christine; Song, Kun; Pfizer

    2010-09-27

    The synthesis of a new series of phenylpropanoic acid derivatives incorporating an heteroaryl group at the {alpha}-position and their evaluation for binding and activation of PPAR{alpha} and PPAR{gamma} are presented in this report. Among the new compounds, (S)-3-{l_brace}4-[3-(5-methyl-2-phenyl-oxazol-4-yl)-propyl]-phenyl{r_brace}-2-1,2,3-triazol-2-yl-propionic acid (17j), was identified as a potent human PPAR{alpha}/{gamma} dual agonist (EC{sub 50} = 0.013 and 0.061 {micro}M, respectively) with demonstrated oral bioavailability in rat and dog. 17j was shown to decrease insulin levels, plasma glucose, and triglycerides in the ZDF female rat model. In the human apolipoprotein A-1/CETP transgenic mouse model 17j produced increases in hApoA1 and HDL-C and decreases in plasma triglycerides. The increased potency for binding and activation of both PPAR subtypes observed with 17j when compared to previous analogs in this series was explained based on results derived from crystallographic and modeling studies.

  10. The influence of time dependent flight and maneuver velocities and elastic or viscoelastic flexibilities on aerodynamic and stability derivatives

    SciTech Connect (OSTI)

    Cochrane, Alexander P.; Merrett, Craig G.; Hilton, Harry H.

    2014-12-10

    The advent of new structural concepts employing composites in primary load carrying aerospace structures in UAVs, MAVs, Boeing 787s, Airbus A380s, etc., necessitates the inclusion of flexibility as well as viscoelasticity in static structural and aero-viscoelastic analyses. Differences and similarities between aeroelasticity and aero-viscoelasticity have been investigated in [2]. An investigation is undertaken as to the dependence and sensitivity of aerodynamic and stability derivatives to elastic and viscoelastic structural flexibility and as to time dependent flight and maneuver velocities. Longitudinal, lateral and directional stabilities are investigated. It has been a well established fact that elastic lifting surfaces are subject to loss of control effectiveness and control reversal at certain flight speeds, which depend on aerodynamic, structural and material properties [5]. Such elastic analyses are extended to linear viscoelastic materials under quasi-static, dynamic, and sudden and gradual loading conditions. In elastic wings one of the critical static parameters is the velocity at which control reversal takes place (V{sub REV}{sup E}). Since elastic formulations constitute viscoelastic initial conditions, viscoelastic reversal may occur at speeds V{sub REV<}{sup ≧}V{sub REV}{sup E}, but furthermore does so in time at 0 < t{sub REV} ≤ ∞. The influence of the twin effects of viscoelastic and elastic materials and of variable flight velocities on longitudinal, lateral, directional and spin stabilities are also investigated. It has been a well established fact that elastic lifting surfaces are subject to loss of control effectiveness and control reversal at certain flight speeds, which depend on aerodynamic, structural and material properties [5]. Such elastic analyses are here extended to linear viscoelastic materials under quasi-static, dynamic, and sudden and gradual loading conditions. In elastic wings the critical parameter is the velocity at

  11. Metal-Organic Framework Derived Hierarchically Porous Nitrogen-Doped Carbon Nanostructures as Novel Electrocatalyst for Oxygen Reduction Reaction

    SciTech Connect (OSTI)

    Fu, Shaofang; Zhu, Chengzhou; Zhou, Yazhou; Yang, Guohai; Jeon, Ju Won; Lemmon, John P.; Du, Dan; Nune, Satish K.; Lin, Yuehe

    2015-10-01

    The hierarchically porous nitrogen-doped carbon materials, derived from nitrogen-containing isoreticular metal-organic framework-3 (IRMOF-3) through direct carbonization, exhibited excellent electrocatalytic activity in alkaline solution for oxygen reduction reaction (ORR). This high activity is attributed to the 10 presence of high percentage of quaternary and pyridinic nitrogen, the high surface area as well as good conductivity. When IRMOF-3 was carbonized at 950 °C (CIRMOF-3-950), it showed four-electron reduction pathway for ORR and exhibited better stability (about 78.5% current density was maintained) than platinum/carbon (Pt/C) in the current durability test. In addition, CIRMOF-3-950 presented high selectivity to cathode reactions compared to commercial Pt/C.

  12. Acetaldehyde as an intermediate in the electroreduction of carbon monoxide to ethanol on oxide-derived copper

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bertheussen, Erlend; Verdaguer-Casadevall, Arnau; Ravasio, Davide; Montoya, Joseph H.; Trimarco, Daniel B.; Roy, Claudie; Meier, Sebastian; Wendland, Jürgen; Nørskov, Jens K.; Stephens, Ifan E. L.; et al

    2015-12-21

    Oxide-derived copper (OD-Cu) electrodes exhibit unprecedented CO reduction performance towards liquid fuels, producing ethanol and acetate with >50 % Faradaic efficiency at -0.3 V (vs. RHE). By using static headspace-gas chromatography for liquid phase analysis, we identify acetaldehyde as a minor product and key intermediate in the electroreduction of CO to ethanol on OD-Cu electrodes. Acetaldehyde is produced with a Faradaic efficiency of ≈5 % at -0.33 V (vs. RHE). We show that acetaldehyde forms at low steady-state concentrations, and that free acetaldehyde is difficult to detect in alkaline solutions using NMR spectroscopy, requiring alternative methods for detection and quantification.more » Our results indicate an important step towards understanding the CO reduction mechanism on OD-Cu electrodes.« less

  13. High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1993

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Menszak, J.; Johansson, M.A.; Feeley, O.C.; Kim, D.

    1993-07-01

    The results shown in Figures 10 and 11 demonstrate that the formation of butenes was very sensitive to the alcohol partial pressure. A small elevation of the alcohol pressure suppressed the formation of butenes rather drastically at both 90 and 117{degree}C. The synthesis rates of DME, MIBE, and MTBE ethers were not significantly affected at 90{degree}C, although there was a trend to increase the space time yield of DME as the alcohol pressure was increased. At the reaction temperature of 117{degree}C, all of the ethers showed increasing productivities as the pressure of the reactants was increased (Figure 11). An isotope labelling experiment was carried out to provide mechanistic insight into the manner in which methanol and isobutanol react together to form DME, MIBE, and MTBE ethers and to determine if MTBE were derived from MIBE.

  14. Construction of an in vitro primary lung co-culture platform derived from New Zealand white rabbits

    SciTech Connect (OSTI)

    Powell, Joshua D.; Hess, Becky M.; Hutchison, Janine R.; Straub, Tim M.

    2015-05-01

    We report the construction of an in vitro three dimensional (3D) co-culture platform consisting of differentiated lung epithelial cells and monocytes from New Zealand white rabbits. Rabbit lung epithelial cells were successfully grown at air-liquid interface, produced mucus, and expressed both sialic acid alpha-2,3 and alpha-2,6. Blood-derived CD14+ monocytes were deposited above the epithelial layer resulting in the differentiation of a subset of monocytes into CD11c+ cells within the co-culture. These proof-of-concept findings provide a convenient means to comparatively study in vitro versus in vivo rabbit lung responses as they relate to inhalation or lung-challenge studies.

  15. Derivation and generalization of the dispersion relation of rising-sun magnetron with sectorial and rectangular cavities

    SciTech Connect (OSTI)

    Shi, Di-Fu; Qian, Bao-Liang; Wang, Hong-Gang; Li, Wei

    2013-12-15

    Field analysis method is used to derive the dispersion relation of rising-sun magnetron with sectorial and rectangular cavities. This dispersion relation is then extended to the general case in which the rising-sun magnetron can be with multi-group cavities of different shapes and sizes, and from which the dispersion relations of conventional magnetron, rising-sun magnetron, and magnetron-like device can be obtained directly. The results show that the relative errors between the theoretical and simulation values of the dispersion relation are less than 3%, the relative errors between the theoretical and simulation values of the cutoff frequencies of ? mode are less than 2%. In addition, the influences of each structure parameter of the magnetron on the cutoff frequency of ? mode and on the mode separation are investigated qualitatively and quantitatively, which may be of great interest to designing a frequency tuning magnetron.

  16. Performance analysis of cofiring densified refuse derived fuel in a military boiler. Final report Aug 80-Sep 81

    SciTech Connect (OSTI)

    Not Available

    1981-12-01

    This report provides an overview of existing densified refuse-derived fuel (dRDF) receiving, storage, handling and combustion equipment at Wright-Patterson Air Foce Base. DRDF is being burned as part of a long term alternative fuel evaluation program to develop design and procurement criteria for multiple fuel boilers. Recommendations are offered for specific equipment, procedural changes, and studies to improve the efficacy of the present configurations of dRDF as a fuel. A discussion of the fuel use criteria is presented. The options for continuing the present dRDF supply arrangement vs. the feasibility of local production of dRDF are presented. Research needs are summarized. A preemptive, integrated local synthetic solid fuel production facility and boiler performance test is recommended as a continuation of the program.

  17. Study of organic compounds evolved during the co-firing of coal and refuse derived fuel using TG/MS

    SciTech Connect (OSTI)

    Puroshothama, Shobha; Lu, R.; Yang, Xiaodong

    1996-10-01

    The evolution of organic compounds during the combustion of carbonaceous fuel coupled with solid waste disposal and limited landfill space has been a cause for concern. Co-firing high sulfur coal with refuse derived fuel seems an attractive alternative technique to tackle the dual problem of controlling SO{sub x} emissions as well as those of the chlorinated organic toxins. The TG serves to emulate the conditions of the fluidized bed combustor and the MS serves as the detector for evolved gases. This versatile combination is used to study the decomposition pathway as well as predict the conditions at which various compounds are formed and may serve as a means of reducing the formation of these chlorinated organic compounds.

  18. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 8, July 1996--August 1996

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

    1996-08-31

    The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GC/MS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.

  19. Magnetic Materials at finite Temperatures: thermodynamics and combined spin and molecular dynamics derived from first principles calculations

    SciTech Connect (OSTI)

    Eisenbach, Markus; Perera, Meewanage Dilina N; Landau, David P; Nicholson, Don M; Yin, Junqi; Brown, Greg

    2015-01-01

    We present a unified approach to describe the combined behavior of the atomic and magnetic degrees of freedom in magnetic materials. Using Monte Carlo simulations directly combined with first principles the Curie temperature can be obtained ab initio in good agreement with experimental values. The large scale constrained first principles calculations have been used to construct effective potentials for both the atomic and magnetic degrees of freedom that allow the unified study of influence of phonon-magnon coupling on the thermodynamics and dynamics of magnetic systems. The MC calculations predict the specific heat of iron in near perfect agreement with experimental results from 300K to above Tc and allow the identification of the importance of the magnon-phonon interaction at the phase-transition. Further Molecular Dynamics and Spin Dynamics calculations elucidate the dynamics of this coupling and open the potential for quantitative and predictive descriptions of dynamic structure factors in magnetic materials using first principles derived simulations.

  20. Hydrogen Generation from Biomass-Derived Surgar Alcohols via the Aqueous-Phase Carbohydrate Reforming (ACR) Process

    SciTech Connect (OSTI)

    Randy Cortright

    2006-06-30

    This project involved the investigation and development of catalysts and reactor systems that will be cost-effective to generate hydrogen from potential sorbitol streams. The intention was to identify the required catalysts and reactors systems as well as the design, construction, and operation of a 300 grams per hour hydrogen system. Virent was able to accomplish this objective with a system that generates 2.2 kgs an hour of gas containing both hydrogen and alkanes that relied directly on the work performed under this grant. This system, funded in part by the local Madison utility, Madison, Gas & Electric (MGE), is described further in the report. The design and development of this system should provide the necessary scale-up information for the generation of hydrogen from corn-derived sorbitol.

  1. User`s manual for TMY2s: Derived from the 1961--1990 National Solar Radiation Data Base

    SciTech Connect (OSTI)

    Marion, W.; Urban, K.

    1995-06-01

    This report is a user`s manual that describes typical meteorological year (TMY) data sets derived from the 1961-1990 National Solar Radiation Data Base. The TMY is a data set of hourly values of solar radiation and meteorological elements for a 1-year period. The intended use if for computer simulations of solar energy conversion systems and building systems. Section 1 of the manual provides general information about the TMYs; Section 2 lists the stations and provides station identifying information and classification; Section 3 details the contents of the TMY2 files and provides the hourly records of data values; Section 4 compares TMY2 with 30-year data sets; Appendices provide procedures used to develop TMYs and a table to convert SI data to other units.

  2. Acetaldehyde as an intermediate in the electroreduction of carbon monoxide to ethanol on oxide-derived copper

    SciTech Connect (OSTI)

    Bertheussen, Erlend; Verdaguer-Casadevall, Arnau; Ravasio, Davide; Montoya, Joseph H.; Trimarco, Daniel B.; Roy, Claudie; Meier, Sebastian; Wendland, Jürgen; Nørskov, Jens K.; Stephens, Ifan E. L.; Chorkendorff, Ib

    2015-12-21

    Oxide-derived copper (OD-Cu) electrodes exhibit unprecedented CO reduction performance towards liquid fuels, producing ethanol and acetate with >50 % Faradaic efficiency at -0.3 V (vs. RHE). By using static headspace-gas chromatography for liquid phase analysis, we identify acetaldehyde as a minor product and key intermediate in the electroreduction of CO to ethanol on OD-Cu electrodes. Acetaldehyde is produced with a Faradaic efficiency of ≈5 % at -0.33 V (vs. RHE). We show that acetaldehyde forms at low steady-state concentrations, and that free acetaldehyde is difficult to detect in alkaline solutions using NMR spectroscopy, requiring alternative methods for detection and quantification. Our results indicate an important step towards understanding the CO reduction mechanism on OD-Cu electrodes.

  3. Apparatus and method for pumping hot, erosive slurry of coal solids in coal derived, water immiscible liquid

    DOE Patents [OSTI]

    Ackerman, Carl D.

    1983-03-29

    An apparatus for and method of pumping hot, erosive slurry of coal solids in a coal derived, water immiscible liquid to higher pressure involves the use of a motive fluid which is miscible with the liquid of the slurry. The apparatus includes a pump 12, a remote check valve 14 and a chamber 16 between and in fluid communication with the pump 12 and check valve 14 through conduits 18,20. Pump 12 exerts pressure on the motive fluid and thereby on the slurry through a concentration gradient of coal solids within chamber 16 to alternately discharge slurry under pressure from the outlet port of check valve 14 and draw slurry in through the inlet port of check valve 14.

  4. Studies of the combustion of coal/refuse derived fuels using thermogravimetric-Fourier transform infrared-mass spectrometry

    SciTech Connect (OSTI)

    Lu, Huagang; Li, Jigui; Lloyd, W.G.

    1995-11-01

    According to a report of the Environmental Protection Agency (EPA), `Characterization of Municipal Solid Waste (MSW) in the United States`, the total MSW produced in the U.S. increased from 179 million tons in 1988 to 195 million tons in 1990. The EPA predicted that the country would produce about 216 million tons of garbage in the year 2000. The amount of waste generated and the rapidly declining availability of sanitary landfills has forced most municipalities to evaluate alternative waste management technologies for reducing the volume of waste sent to landfills. The fraction of MSW that is processed by such technologies as separation and recycling, composting, and waste-to-energy was forecast to increase from a few percent today to 30-40% by the year 2000. Waste-to-energy conversion of MSW can appear to be attractive because of the energy recovered, the economic value of recycled materials, and the cost savings derived from reduced landfill usage. However, extra care needs to be taken in burning MSW or refuse-derived fuel (RDF) to optimize the operating conditions of a combustor so that the combustion takes place in an environmentally acceptable manner. For instance, polychlorinated dibenzodioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) have been found in the precipitator fly ash and flue gas of some incinerator facilities in the United States and Europe. The amount of PCDDs and PCDFs occurs only in the parts-per-billion to parts-per-trillion range, but these chlorinated organics exhibit very high toxicity (LD{sub 50} < 10 {mu}g/Kg). The compound 2,3,7,8-tetrachlorodibenzodioxin has been found to be acnegenic, carcinogenic, and teratogenic. This has slowed or even stopped the construction and operation of waste-to-energy plants.

  5. Derived Concentration Technical Standard

    Broader source: Energy.gov (indexed) [DOE]

    ... parameters of americium are assigned to actinium and those of thorium to protactinium. ... M (b) , S Praseodymium (c) F (d) , M, S Thorium F, M, S (b) Cobalt F, M (b) , S Neodymium ...

  6. Derived Annual Estimates

    U.S. Energy Information Administration (EIA) Indexed Site

    robert.adler@eia.doe.gov Robert Adler Survey Manager Phone: 202-586-1134 Fax: (202) 586-0018 thomas.lorenz@eia.doe.gov Thomas Lorenz Operations Research Analyst Phone: 202-586-3442...

  7. Derived Concentration Technical Standard

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2011-05-05

    This standard supports the implementation of Department of Energy (DOE) Order 458.1, Radiation Protection of the Public and the Environment. It also establishes the numerical values of DCSs in a manner reflecting the current state of knowledge and practice in radiation protection

  8. Aerogel derived catalysts

    SciTech Connect (OSTI)

    Reynolds, J. G., LLNL

    1996-12-11

    Aerogels area class of colloidal materials which have high surface areas and abundant mesoporous structure. SiO{sub 2} aerogels show unique physical, optical and structural properties. When catalytic metals are incorporated in the aerogel framework, the potential exists for new and very effective catalysts for industrial processes. Three applications of these metal-containing SiO{sub 2} aerogels as catalysts are briefly reviewed in this paper--NO{sub x} reduction, volatile organic compound destruction, and partial oxidation of methane.

  9. A steady state thermal duct model derived by fin-theory approach and applied on an unglazed solar collector

    SciTech Connect (OSTI)

    Stojanovic, B.; Hallberg, D.; Akander, J.

    2010-10-15

    This paper presents the thermal modelling of an unglazed solar collector (USC) flat panel, with the aim of producing a detailed yet swift thermal steady-state model. The model is analytical, one-dimensional (1D) and derived by a fin-theory approach. It represents the thermal performance of an arbitrary duct with applied boundary conditions equal to those of a flat panel collector. The derived model is meant to be used for efficient optimisation and design of USC flat panels (or similar applications), as well as detailed thermal analysis of temperature fields and heat transfer distributions/variations at steady-state conditions; without requiring a large amount of computational power and time. Detailed surface temperatures are necessary features for durability studies of the surface coating, hence the effect of coating degradation on USC and system performance. The model accuracy and proficiency has been benchmarked against a detailed three-dimensional Finite Difference Model (3D FDM) and two simpler 1D analytical models. Results from the benchmarking test show that the fin-theory model has excellent capabilities of calculating energy performances and fluid temperature profiles, as well as detailed material temperature fields and heat transfer distributions/variations (at steady-state conditions), while still being suitable for component analysis in junction to system simulations as the model is analytical. The accuracy of the model is high in comparison to the 3D FDM (the prime benchmark), as long as the fin-theory assumption prevails (no 'or negligible' temperature gradient in the fin perpendicularly to the fin length). Comparison with the other models also shows that when the USC duct material has a high thermal conductivity, the cross-sectional material temperature adopts an isothermal state (for the assessed USC duct geometry), which makes the 1D isothermal model valid. When the USC duct material has a low thermal conductivity, the heat transfer course of

  10. MUTZ-3 derived Langerhans cells in human skin equivalents show differential migration and phenotypic plasticity after allergen or irritant exposure

    SciTech Connect (OSTI)

    Kosten, Ilona J.; Spiekstra, Sander W.; Gruijl, Tanja D. de; Gibbs, Susan

    2015-08-15

    After allergen or irritant exposure, Langerhans cells (LC) undergo phenotypic changes and exit the epidermis. In this study we describe the unique ability of MUTZ-3 derived Langerhans cells (MUTZ-LC) to display similar phenotypic plasticity as their primary counterparts when incorporated into a physiologically relevant full-thickness skin equivalent model (SE-LC). We describe differences and similarities in the mechanisms regulating LC migration and plasticity upon allergen or irritant exposure. The skin equivalent consisted of a reconstructed epidermis containing primary differentiated keratinocytes and CD1a{sup +} MUTZ-LC on a primary fibroblast-populated dermis. Skin equivalents were exposed to a panel of allergens and irritants. Topical exposure to sub-toxic concentrations of allergens (nickel sulfate, resorcinol, cinnamaldehyde) and irritants (Triton X-100, SDS, Tween 80) resulted in LC migration out of the epidermis and into the dermis. Neutralizing antibody to CXCL12 blocked allergen-induced migration, whereas anti-CCL5 blocked irritant-induced migration. In contrast to allergen exposure, irritant exposure resulted in cells within the dermis becoming CD1a{sup −}/CD14{sup +}/CD68{sup +} which is characteristic of a phenotypic switch of MUTZ-LC to a macrophage-like cell in the dermis. This phenotypic switch was blocked with anti-IL-10. Mechanisms previously identified as being involved in LC activation and migration in native human skin could thus be reproduced in the in vitro constructed skin equivalent model containing functional LC. This model therefore provides a unique and relevant research tool to study human LC biology in situ under controlled in vitro conditions, and will provide a powerful tool for hazard identification, testing novel therapeutics and identifying new drug targets. - Highlights: • MUTZ-3 derived Langerhans cells integrated into skin equivalents are fully functional. • Anti-CXCL12 blocks allergen-induced MUTZ-LC migration.

  11. Data Qualification Report: Calculated Porosity and Porosity-Derived Values for Lithostratigraphic Units for use on the Yucca Mountain Project

    SciTech Connect (OSTI)

    P. Sanchez

    2001-05-30

    The qualification is being completed in accordance with the Data Qualification Plan DQP-NBS-GS-000006, Rev. 00 (CRWMS M&O 2001). The purpose of this data qualification activity is to evaluate for qualification the unqualified developed input and porosity output included in Data Tracking Number (DTN) M09910POROCALC.000. The main output of the analyses documented in DTN M09910POROCALC.000 is the calculated total porosity and effective porosity for 40 Yucca Mountain Project boreholes. The porosity data are used as input to Analysis Model Report (AMR) 10040, ''Rock Properties Model'' (MDL-NBS-GS-000004, Rev. 00), Interim Change Notice [ICN] 02 (CRWMS M&O 2000b). The output from the rock properties model is used as input to numerical physical-process modeling within the context of a relationship developed in the AMR between hydraulic conductivity, bound water and zeolitic zones for use in the unsaturated zone model. In accordance with procedure AP-3.15Q, the porosity output is not used in the direct calculation of Principal Factors for post-closure safety or disruptive events. The original source for DTN M09910POROCALC.000 is a Civilian Radioactive Waste Management System (CRWMS) Management and Operating Contractor (M&O) report, ''Combined Porosity from Geophysical Logs'' (CRWMS M&O 1999a and hereafter referred to as Rael 1999). That report recalculated porosity results for both the historical boreholes covered in Nelson (1996), and the modern boreholes reported in CRWMS M&O (1996a,b). The porosity computations in Rael (1999) are based on density-porosity mathematical relationships requiring various input parameters, including bulk density, matrix density and air and/or fluid density and volumetric water content. The main output is computed total porosity and effective porosity reported on a foot-by-foot basis for each borehole, although volumetric water content is derived from neutron data as an interim output. This qualification report uses technical assessment and

  12. Preclinical and first-in-human evaluation of PRX-105, a PEGylated, plant-derived, recombinant human acetylcholinesterase-R

    SciTech Connect (OSTI)

    Atsmon, Jacob; Brill-Almon, Einat; Nadri-Shay, Carmit; Chertkoff, Raul; Alon, Sari; Shaikevich, Dimitri; Volokhov, Inna; Haim, Kirsten Y.; Bartfeld, Daniel; Shulman, Avidor; Ruderfer, Ilya; Ben-Moshe, Tehila; Shilovitzky, Orit; Soreq, Hermona; Shaaltiel, Yoseph

    2015-09-15

    PRX-105 is a plant-derived recombinant version of the human ‘read-through’ acetylcholinesterase splice variant (AChE-R). Its active site structure is similar to that of the synaptic variant, and it displays the same affinity towards organophosphorus (OP) compounds. As such, PRX-105 may serve as a bio-scavenger for OP pesticides and chemical warfare agents. To assess its potential use in prophylaxis and treatment of OP poisoning we conducted several preliminary tests, reported in this paper. Intravenous (IV) PRX-105 was administered to mice either before or after exposure to an OP toxin. All mice who received an IV dose of 50 nmol/kg PRX-105, 2 min before being exposed to 1.33 × LD{sub 50} and 1.5 × LD{sub 50} of toxin and 10 min after exposure to 1.5 × LD{sub 50} survived. The pharmacokinetic and toxicity profiles of PRX-105 were evaluated in mice and mini-pigs. Following single and multiple IV doses (50 to 200 mg/kg) no deaths occurred and no significant laboratory and histopathological changes were observed. The overall elimination half-life (t{sub ½}) in mice was 994 (± 173) min. Additionally, a first-in-human study, to assess the safety, tolerability and pharmacokinetics of the compound, was conducted in healthy volunteers. The t{sub ½} in humans was substantially longer than in mice (average 26.7 h). Despite the small number of animals and human subjects who were assessed, the fact that PRX-105 exerts a protective and therapeutic effect following exposure to lethal doses of OP, its favorable safety profile and its relatively long half-life, renders it a promising candidate for treatment and prophylaxis against OP poisoning and warrants further investigation. - Highlights: • PRX-105 is a PEGylated plant-derived recombinant human acetylcholinesterase-R. • PRX-105 is a promising bio-scavenger for organophosphorous toxins at lethal doses. • PRX-105 was shown to protect animals both prophylactically and post-poisoning. • First-in-human study

  13. Can we derive Tully's surface-hopping algorithm from the semiclassical quantum Liouville equation? Almost, but only with decoherence

    SciTech Connect (OSTI)

    Subotnik, Joseph E. Ouyang, Wenjun; Landry, Brian R.

    2013-12-07

    In this article, we demonstrate that Tully's fewest-switches surface hopping (FSSH) algorithm approximately obeys the mixed quantum-classical Liouville equation (QCLE), provided that several conditions are satisfied some major conditions, and some minor. The major conditions are: (1) nuclei must be moving quickly with large momenta; (2) there cannot be explicit recoherences or interference effects between nuclear wave packets; (3) force-based decoherence must be added to the FSSH algorithm, and the trajectories can no longer rigorously be independent (though approximations for independent trajectories are possible). We furthermore expect that FSSH (with decoherence) will be most robust when nonadiabatic transitions in an adiabatic basis are dictated primarily by derivative couplings that are presumably localized to crossing regions, rather than by small but pervasive off-diagonal force matrix elements. In the end, our results emphasize the strengths of and possibilities for the FSSH algorithm when decoherence is included, while also demonstrating the limitations of the FSSH algorithm and its inherent inability to follow the QCLE exactly.

  14. Bone marrow-derived osteoblast progenitor cells in circulating blood contribute to ectopic bone formation in mice

    SciTech Connect (OSTI)

    Otsuru, Satoru; Tamai, Katsuto . E-mail: tamai@gts.med.osaka-u.ac.jp; Yamazaki, Takehiko; Yoshikawa, Hideki; Kaneda, Yasufumi

    2007-03-09

    Recent studies have suggested the existence of osteoblastic cells in the circulation, but the origin and role of these cells in vivo are not clear. Here, we examined how these cells contribute to osteogenesis in a bone morphogenetic protein (BMP)-induced model of ectopic bone formation. Following lethal dose-irradiation and subsequent green fluorescent protein-transgenic bone marrow cell-transplantation (GFP-BMT) in mice, a BMP-2-containing collagen pellet was implanted into muscle. Three weeks later, a significant number of GFP-positive osteoblastic cells were present in the newly generated ectopic bone. Moreover, peripheral blood mononuclear cells (PBMNCs) from the BMP-2-implanted mouse were then shown to include osteoblast progenitor cells (OPCs) in culture. Passive transfer of the PBMNCs isolated from the BMP-2-implanted GFP-mouse to the BMP-2-implanted nude mouse led to GFP-positive osteoblast accumulation in the ectopic bone. These data provide new insight into the mechanism of ectopic bone formation involving bone marrow-derived OPCs in circulating blood.

  15. Role of Calcination Temperature on the Hydrotalcite Derived MgO–Al2O3 in Converting Ethanol to Butanol

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Gray, Michel; Job, Heather; Santosa, Daniel; Li, Xiaohong Shari; Devaraj, Arun; Karkamkar, Abhi; Wang, Yong

    2015-10-09

    In the base catalyzed ethanol condensation reactions, the calcined MgO-Al2O3 derived hydrotalcites used broadly as catalytic material and the calcination temperature plays a big role in determining the catalytic activity. The characteristic of the hydrotalcite material treated between catalytically relevant temperatures 450ºC and 800ºC have been studied with respect to the physical, chemical, and structural properties and compared with catalytic activity testing. With the increasing calcination temperature, the total measured catalytic basicity dropped linearly with the calcination temperature and the total measured acidity stayed the same for all the calcination temperatures except 800ºC. However, the catalyst activity testing does not show any direct correlation between the measured catalytic basicity and the catalyst activity to the ethanol condensation reaction to form 1-butanol. The highest ethanol conversion of 44 percent with 1-butanol selectivity of 50 percent was achieved for the 600ºC calcined hydrotalcite material.

  16. High performance organic integrated device with ultraviolet photodetective and electroluminescent properties consisting of a charge-transfer-featured naphthalimide derivative

    SciTech Connect (OSTI)

    Wang, Hanyu; Wang, Xu; Yu, Junsheng E-mail: jsyu@uestc.edu.cn; Zhou, Jie; Lu, Zhiyun E-mail: jsyu@uestc.edu.cn

    2014-08-11

    A high performance organic integrated device (OID) with ultraviolet photodetective and electroluminescent (EL) properties was fabricated by using a charge-transfer-featured naphthalimide derivative of 6-(3,5-bis-[9-(4-t-butylphenyl)-9H-carbazol-3-yl]-phenoxy)-2- (4-t-butylphenyl)-benzo[de]isoquinoline-1,3-dione (CzPhONI) as the active layer. The results showed that the OID had a high detectivity of 1.5 × 10{sup 11} Jones at −3 V under the UV-350 nm illumination with an intensity of 0.6 mW/cm{sup 2}, and yielded an exciplex EL light emission with a maximum brightness of 1437 cd/m{sup 2}. Based on the energy band diagram, both the charge transfer feature of CzPhONI and matched energy level alignment were responsible for the dual ultraviolet photodetective and EL functions of OID.

  17. Liquefaction process wherein solvents derived from the material liquefied and containing increased concentrations of donor species are employed

    DOE Patents [OSTI]

    Fant, B. T.; Miller, John D.; Ryan, D. F.

    1982-01-01

    An improved process for the liquefaction of solid carbonaceous materials wherein a solvent or diluent derived from the solid carbonaceous material being liquefied is used to form a slurry of the solid carbonaceous material and wherein the solvent or diluent comprises from about 65 to about 85 wt. % hydroaromatic components. The solvent is prepared by first separating a solvent or diluent distillate fraction from the liquefaction product, subjecting this distillate fraction to hydrogenation and then extracting the naphthenic components from the hydrogenated product. The extracted naphthenic components are then dehydrogenated and hydrotreated to produce additional hydroaromatic components. These components are combined with the solvent or diluent distillate fraction. The solvent may also contain hydroaromatic constituents prepared by extracting naphthenic components from a heavy naphtha, dehydrogenating the same and then hydrotreating the dehydrogenated product. When the amount of solvent produced in this manner exceeds that required for steady state operation of the liquefaction process a portion of the solvent or diluent distillated fraction will be withdrawn as product.

  18. A thermodynamic model for C-(N-)A-S-H gel: CNASH{sub s}s. Derivation and validation

    SciTech Connect (OSTI)

    Myers, Rupert J.; Bernal, Susan A.; Provis, John L.

    2014-12-15

    The main reaction product in Ca-rich alkali-activated cements and hybrid Portland cement (PC)-based materials is a calcium (alkali) aluminosilicate hydrate (C-(N-)A-S-H) gel. Thermodynamic models without explicit definitions of structurally-incorporated Al species have been used in numerous past studies to describe this gel, but offer limited ability to simulate the chemistry of blended PC materials and alkali-activated cements. Here, a thermodynamic model for C-(N-)A-S-H gel is derived and parameterised to describe solubility data for the CaO–(Na{sub 2}O,Al{sub 2}O{sub 3})–SiO{sub 2}–H{sub 2}O systems and alkali-activated slag (AAS) cements, and chemical composition data for C-A-S-H gels. Simulated C-(N-)A-S-H gel densities and molar volumes are consistent with the corresponding values reported for AAS cements, meaning that the model can be used to describe chemical shrinkage in these materials. Therefore, this model can provide insight into the chemistry of AAS cements at advanced ages, which is important for understanding the long-term durability of these materials.

  19. Design, operation, and performance of a modern air pollution control system for a refuse derived fuel combustion facility

    SciTech Connect (OSTI)

    Weaver, E.H.; Azzinnari, C.

    1997-12-01

    The Robbins, Illinois refuse derived fuel combustion facility was recently placed into service. Large and new, the facility is designed to process 1600 tons of waste per day. Twenty-five percent of the waste, or 400 tons per day, is separated out in the fuel preparation process. The remaining 1200 tons per day is burned in two circulating fluidized bed boilers. The system is designed to meet new source performance standards for municipal waste combustion facilities, including total particulate, acid gases (HCl, SO{sub 2}, HF), heavy metals (including mercury), and dioxins. The system utilizes semi-dry scrubbers with lime and activated carbon injected through dual fluid atomizers for control of acid gases. Final polishing of acid gas emissions, particulate control, heavy metals removal, and control of dioxins is accomplished with pulse jet fabric filters. This paper discusses the design of the facility`s air pollution control system, including all auxiliary systems required to make it function properly. Also discussed is the actual operation and emissions performance of the system.

  20. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 5, [October--December 1995

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

    1995-11-30

    Studies involving the tubular furnace are in the process of identifying the ideal experimental coal-to-refuse derived fuel(RDF) ratio for use in the AFBC system. A series of experiments with this furnace has been performed to determine the possible chemical pathway for formation of chlorinated organic compounds during the combustion of various RDF sources. Phenol and chlorine appear to be likely reactants necessary for the formation of these compounds. The main goal of these experiment is to determine the exact experimental conditions for the formation of chlorinated organic compounds, as well as methods to inhibit their development. Work on the fluidized bed combustor has involved five combustion runs, in which a combustion efficiency of greater than 96% and with a consistent CO{sub 2} concentration of approximately 13% was obtained. Modifications responsible for these improvements include the addition of the underbed fuel feed system and revision of the flue gas sampling system. New methods of determining combustion efficiency and percentage of SO{sub 2} capture using TG techniques to analyze combustion products are being developed. The current outlook using this TGA/FTIR method is very promising, since previously obscured reactions are being studied. the analysis of combustion products is revealing a more complete picture of the combustion process within the AFBC system.